Sample records for rb-sr isotope systematics

  1. Rb-Sr Isotopic Systematics of Alkali-Rich Fragments in the Yamato-74442 LL-Chondritic Breccia (United States)

    Yokoyama, T.; Misawa, K.; Okano, O.; Shih, C.-Y.; Nyquist, L. E.; Simo, J. I.; Tappa, M. J.; Yoneda, S.


    Alkali-rich igneous fragments were identified in the brecciated LL-chondrites, Kr henberg (LL5)], Bhola (LL3-6) and Yamato (Y)-74442 (LL4), and show characteristic fractionation patterns of alkaline elements. The K-Rb-Cs-rich fragments in Kr henberg, Bhola, and Y-74442 are very similar in mineralogy and petrography (olivine + pyroxene + glass), suggesting that they could have come from related precursor materials. We have undertaken Rb-Sr isotopic studies on alkali-rich fragments in Y-74442 to precisely determine their crystallization ages and the isotopic signatures of their precursor material(s).

  2. Evaluating crustal contributions to enriched shergottites from the petrology, trace elements, and Rb-Sr and Sm-Nd isotope systematics of Northwest Africa 856 (United States)

    Ferdous, J.; Brandon, A. D.; Peslier, A. H.; Pirotte, Z.


    The origin of the incompatible trace element (ITE) characteristics of enriched shergottites has been critical for examining two contradicting scenarios to explain how these Martian meteorites form. The first scenario is that it reflects ITE enrichment in an early-formed mantle reservoir whereas the second scenario attributes it to assimilation of ancient Martian crust (∼4-4.5 Ga) by ITE-depleted magmas. Strongly differentiated shergottite magmas may yield added constraints for determining which scenario can best explain this signature in enriched shergottites. The meteorite Northwest Africa (NWA) 856 is a basaltic shergottite that, unlike many enriched shergottites, lacks olivine and has undergone extensive differentiation from more primitive parent magma. In similarity to other basaltic shergottites, NWA 856 is comprised primarily of compositionally zoned clinopyroxenes (45% pigeonite and 23% augite), maskelynite (23%) and accessory minerals such as ulvöspinel, merrillite, Cl-apatite, ilmenite, pyrrhotite, baddeleyite and silica polymorph. The CI-chondrite normalized rare earth element (REE) abundance patterns for its maskelynite, phosphates, and its whole rock are flat with corresponding light-REE depletions in clinopyroxenes. The 87Rb-87Sr and 147Sm-143Nd internal isochron ages are 162 ± 14 (all errors are ±2σ) Ma and 162.7 ± 5.5 Ma, respectively, with an initial εNdI = -6.6 ± 0.2. The Rb-Sr isotope systematics are affected by terrestrial alteration resulting in larger scatter and a less precise internal isochron age. The whole rock composition is used in MELTS simulations to model equilibrium and fractional crystallization sequences to compare with the crystallization sequence from textural observations and to the mineral compositions. These models constrain the depth of initial crystallization to a pressure range of 0.4-0.5 GPa (equivalent to 34-42 km) in anhydrous conditions at the Fayalite-Magnetite-Quartz buffer, and consistently reproduce the

  3. Sm-Nd and Rb-Sr Isotopic Systematics of a Heavily Shocked Martian Meteorite Tissint and Petrogenesis of Depleted Shergottites (United States)

    Shih, C.-Y.; Nyquist, L. E.; Park, J.; Agee, Carl B.


    Tissint is a very fresh Martian meteorite that fell near the town of Tissint in Morocco on July 18, 2011. It contains abundant olivine megacrysts (23%) in a fine-grained matrix of pyroxene (55%), maskelynitized plagioclase (15%), opaques (4%) and melt pockets (3%) and is petrographically similar to lithologies A and C of picritic shergottite EETA 79001 [1,2]. The presence of 2 types of shock-induced glasses and all 7 high-pressure mineral phases that were ever found in melt pockets of Martian meteorites suggests it underwent an intensive shock metamorphism of 25 GPa and 2000 C localized in melt pockets [2]. Mineral textures suggest that olivines, pyroxenes and plagioclases probably did not experience such hightemperature. Earlier determinations of its age yielded 596+/-23 Ma [3] and 616+/-67 Ma [4], respectively, for the Sm-Nd system and 583+/-86 Ma for the Lu-Hf system [4], in agreement with the 575+/-18 Ma age of the oldest olivine-phyric depleted shergottite Dho 019 [5]. However, the exposure ages of Tissint (1 Ma [1, 6, 7]) and Dho 019 (20 Ma [8]) are very different requiring two separate ejection events. These previously determined Sm-Nd and Lu-Hf ages are older than the Ar-Ar maskelynite plateau age of 524+/-15 Ma [9], reversing the pattern usually observed for Martian meteorites. In order to clarify these age issues and place models for Tissint's petrogenesis on a firm basis, we present new Rb-Sr and Sm- Nd isotopic results for Tissint, and discuss (a) the shock effects on them and the Ar-Ar chronometer, (b) correlation of the determined ages with those of other depleted shergottites, and (c) the petrogenesis of depleted shergottites. Since the meteorite is a recent fall, terrestrial contamination is expected to be minimal, but, the strong shock metamorphism might be expected to compromise the equilibrium of the isotopic systems.

  4. Derivation of Apollo 14 High-Al Basalts at Discrete Times: Rb-Sr Isotopic Constraints (United States)

    Hui. Hejiu; Neal, Clive, R.; Shih, Chi-Yu; Nyquist, Laurence E.


    Pristine Apollo 14 (A-14) high-Al basalts represent the oldest volcanic deposits returned from the Moon [1,2] and are relatively enriched in Al2O3 (>11 wt%) compared to other mare basalts (7-11 wt%). Literature Rb-Sr isotopic data suggest there are at least three different eruption episodes for the A-14 high-Al basalts spanning the age range approx.4.3 Ga to approx.3.95 Ga [1,3]. Therefore, the high-Al basalts may record lunar mantle evolution between the formation of lunar crust (approx.4.4 Ga) and the main basin-filling mare volcanism (basalts were originally classified into five compositional groups [5,6], and then regrouped into three with a possible fourth comprising 14072 based on the whole-rock incompatible trace element (ITE) ratios and Rb-Sr radiometric ages [7]. However, Rb-Sr ages of these basalts from different laboratories may not be consistent with each other because of the use of different 87Rb decay constants [8] and different isochron derivation methods over the last four decades. This study involved a literature search for Rb-Sr isotopic data previously reported for the high-Al basalts. With the re-calculated Rb-Sr radiometric ages, eruption episodes of A-14 high-Al basalts were determined, and their petrogenesis was investigated in light of the "new" Rb-Sr isotopic data and published trace element abundances of these basalts.

  5. Decoupled Rb-Sr and Sm-Nd isotopic evolution of the continental crust (United States)

    Goldstein, S. L.


    Evidence was presented that the Rb-Sr and Sm-Nd isotopic systems are decoupled in crust-mantle evolution. Rare earth element (including Sm and Nd) residue principally in silicates, and are resistant to mobilization by weathering and metamorphism. In contrast, Rb and Sr are easily fractionated by crustal processes and residue in carbonates as well as in silicates. As a result, continental Sr, but not Nd, can be recycled into the mantle by exchange of seawater with basalt at spreading ridges and by subduction of carbonates associated with ridge processes. These effects result in mean Rb-Sr ages of the continental crust and of the upper mantle that are too young. Crustal growth curves based largely on Rb-Sr data, such that of Hurley and Rand, are therefore incorrect.

  6. Derivation of Apollo 14 High-Al Basalts at Discrete Times: Rb-Sr Isotopic Constraints (United States)

    Hui, H.; Neal, C. R.; Shih, C.-Y.; Nyquist, L. E.


    Four eruption episodes were identified for A-14 high-Al basalts. Rb-Sr isotopic data and ITE ratios show that their parental melt compositions of are correlated through mixing of evolved components with a relatively primitive magma ocean cumulate.

  7. Rb-Sr and Sm-Nd Isotope Systematics of Shergottite NWA 856: Crystallization Age and Implications for Alteration of Hot Desert SNC Meteorites (United States)

    Brandon, A. D.; Nyquist, L. E.; Shih, C.-Y.; Wiesmann, H.


    Nakhlite NWA 998 was discovered in Algeria in 2001, and is unique among the six known members of this group of Martian meteorites in containing significant modal orthopyroxene. Initial petrologic and isotopic data were reported by Irving et al. This 456 gram stone consists mainly of sub-calcic augite with subordinate olivine and minor orthopyroxene, titanomagnetite, pyrrhotite, chlorapatite, and intercumulus An(sub 35) plagioclase. We report here preliminary results of radiogenic isotopic analyses conducted on fragmental material from the main mass.

  8. Rb-Sr and Sm-Nd Isotopic Studies of Lunar Green and Orange Glasses (United States)

    Shih, C.-Y.; Nyquist, L. E.; Reese, Y.


    Lunar volcanic glassy beads have been considered as quenched basaltic magmas derived directly from deep lunar mantle during fire-fountaining eruptions [1]. Since these sub-mm size glassy melt droplets were cooled in a hot gaseous medium during free flight [2], they have not been subject to mineral fractionations. Thus, they represent primary magmas and are the best samples for the investigation of the lunar mantle. Previously, we presented preliminary Rb- Sr and Sm-Nd isotopic results for green and orange glassy samples from green glass clod 15426,63 and orange soil 74220,44, respectively [3]. Using these isotopic data, initial Sr-87/Sr-86 and Nd ratios for these pristine mare glass sources can be calculated from their respective crystallization ages previously determined by other age-dating techniques. These isotopic data were used to evaluate the mineralogy of the mantle sources. In this report, we analyzed additional glassy samples in order to further characterize isotopic signatures of their source regions. Also, we'll postulate a relationship between these two major mare basalt source mineralogies in the context of lunar magma ocean dynamics.

  9. A combined Sm-Nd, Rb-Sr, and U-Pb isotopic study of Mg-suite norite 78238: Further evidence for early differentiation of the Moon

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    Edmunson, J; E.Borg, L; Nyquist, L E; Asmerom, Y


    Lunar Mg-suite norite 78238 was dated using the Sm-Nd, Rb-Sr, and U-Pb isotopic systems in order to constrain the age of lunar magma ocean solidification and the beginning of Mg-suite magmatism, as well as to provide a direct comparison between the three isotopic systems. The Sm-Nd isotopic system yields a crystallization age for 78238 of 4334 {+-} 37 Ma and an initial {var_epsilon}{sub Nd}{sup 143} value of -0.27 {+-} 0.74. The age-initial {var_epsilon}{sub Nd}{sup 143} (T-I) systematics of a variety of KREEP-rich samples, including 78238 and other Mg-suite rocks, KREEP basalts, and olivine cumulate NWA 773, suggest that lunar differentiation was completed by 4492 {+-} 61 Ma assuming a Chondritic Uniform Reservoir bulk composition for the Moon. The Rb-Sr isotopic systematics of 78238 were disturbed by post-crystallization processes. Nevertheless, selected data points yield two Rb-Sr isochrons. One is concordant with the Sm-Nd crystallization age, 4366 {+-} 53 Ma. The other is 4003 {+-} 95 Ma and is concordant with an Ar-Ar age for 78236. The {sup 207}Pb-{sup 206}Pb age of 4333 {+-} 59 Ma is concordant with the Sm-Nd age. The U-Pb isotopic systematics of 78238 yield linear arrays equivalent to younger ages than the Pb-Pb system, and may reflect fractionation of U and Pb during sample handling. Despite the disturbed nature of the U-Pb systems, a time-averaged {mu} ({sup 238}U/{sup 204}Pb) value of the source can be estimated at 27 {+-} 30 from the Pb-Pb isotopic systematics. Because KREEP-rich samples are likely to be derived from source regions with the highest U/Pb ratios, the relatively low {mu} value calculated for the 78238 source suggests the bulk Moon does not have an exceedingly high {mu} value.

  10. Rb, Sr and strontium isotopic composition, K/Ar age and large ion lithophile trace element abundances in rocks and glasses from the Wanapitei Lake impact structure (United States)

    Winzer, S. R.; Lum, R. K. L.; Schuhmann, S.


    Shock metamorphosed rocks and shock-produced melt glasses from the Wanapitei Lake impact structure have been examined petrographically and by electron microprobe. Eleven clasts exhibiting varying degrees of shock metamorphism and eight impact-produced glasses have been analyzed for Rb, Sr and Sr isotopic composition. Five clasts and one glass have also been analyzed for large ion lithophile (LIL) trace element abundances including Li, Rb, Sr, and Ba and the REE's. The impact event forming the Wanapitei Lake structure occurred 37 m.y. ago based on K/Ar dating of glass and glassy whole-rock samples. Rb/Sr isotopic dating failed to provide a meaningful whole-rock or internal isochron. The isotopic composition of the glasses can be explained by impact-produced mixing and melting of metasediments.

  11. Rb-Sr, Sm-Nd, K-Ca, O, and H isotopic study of Cretaceous-Tertiary boundary sediments, Caravaca, Spain: Evidence for an oceanic impact site

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    DePaolo, D.J.; Kyte, F.T.; Marshall, B.D.; O' Neil, J.R.; Smit, J.


    Isotopic ratios and trace element abundances were measured on samples of IR-enriched clay at the Cretaceous-Tertiary boundary, and in carbonate and marl from 5 cm below and 3 cm above the boundary. Samples were leached with acetic acid to remove carbonate, and with hydrochloric acid. Leachates and residues were measured. The Sr, Nd, O and H isotopic compositions of the boundary clay residues are distinct from those of the stratigraphically neighboring materials. The data indicate that most of the clay material was derived from a terrestrial source with relatively low /sup 87/Sr//sup 86/Sr and high /sup 143/Nd//sup 144/Nd ratios. The delta/sup 18/O data suggest that the detritus has been modified by submarine weathering. K-Ca and Rb-Sr systematics, as well as O isotope ratios of K-feldspar spherules within the boundary clay, suggest that they are predominantly authigenic and may have formed after the time of deposition. However, Sm-Nd and Rb-Sr isotopic data indicate that the spherules contain relict material that provides information on the nature of the original detritus. The isotopic evidence for foreign terrestrial detritus in the boundary clay, the low rare earth element concentrations and high Ni concentration, support the hypothesis of a terminal Cretaceous asteroidal impact that produced a global layer of fallout. The data are most easily explained if the impact sites was on oceanic crust rather than continental crust, and if a substantial fraction of the fallout was derived from relatively deep within the lithosphere (> 3 km). This would probably require a single large impactor. 60 references.

  12. Rb-Sr and Sm-Nd isotope geochemistry and chronology of cherts from the Onverwacht Group (3.5 AE), South Africa (United States)

    Weis, D.; Wasserburg, G. J.


    An Rb-Sr and Sm-Nd isotopic analysis of Archean chert samples from the Onverwacht Group, South Africa is presented, showing the same characteristic Rb and Sr concentrations as Phanerozoic cherts, with a very large range of Rb-87/Sr-86 ratios. A good correlation line in the Rb-87 to Sr-87 evolution diagram, corresponding to an age of about 2119 My and an initial Sr-87/Sr-86 ratio of about 0.72246, is derived which may be interpreted as reflecting the age of rehomogenization of the Sr in the protolith and the recrystallization of these cherts due to circulating hydrothermal fluids during regional metamorphism about 1.4 AE after deposition of the Onverwacht Group. The Sm-Nd systematics reflect an ancient source age of about 3.5 AE.

  13. Rb-Sr and Nd-Sr isotope geochemistry and petrogenesis of the Misho Mountains mafic dikes (NW Iran

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    Maryam Ahankoub


    Full Text Available Introduction There are some theories about the Paleotethys event during the Paleozoic that have been proposed by geologists (Metcalfe, 2006. Some scientist offered some pieces of evidence about the northern margin of Gondwana (Zhu et al., 2010. The Paleotethys Ocean and Hercynian orogenic report first in Iran, have been Offered from the Morrow and Misho Mountain (Eftekharnejad, 1981. Misho Mountains is located between the north and south Misho faults and cause the formation of a positive flower structure (Moayyed and Hossainzade, 2011. There is theory about Misho southern fault as the best candidate of the Paleotethys suture zone (Moayyed and Hossainzade, 2011. Geochemistry and Sr –Nd isotopic data of the A2 granitic and Synite rocks of the East Misho, indicate that the magmatism post collision has occurred in the active continental margin by extensional zones of the following the closure of the Paleotethys (Ahankoub, 2012. Granite and syenite rocks have been cut by mafic dikes. Mafic dikes are often formed in extensional tectonic settings related to mantle plume or continental break –up (Zhu et al., 2009. In this paper, we use the geochemistry and Nd-Sr isotope data to determined petrogenesis, tectono-magmatic setting and age of Misho mafic dikes. Materials and methods After petrography study of 30 thin sections of mafic dike rocks, 8 samples were selected for whole-rock chemical analyses using ICP-MS and ICP-AES instruments by ACME Company in Vancouver, Canada. We prepared 6 sample For Sm-Nd and Rb-Sr analysis. Sr and Nd isotope ratios were measured with a thermal ionization mass spectrometer, VG Sector 54–30 at the Nagoya University. The isotope abundances of Rb, Sr, Nd, and Sm were measured by the ID method with a Finnigan MAT Thermoquad THQ thermal ionization quadrupole mass spectrometer at the Nagoya University. NBS987 and JNdi-1 were measured as natural Sr and Nd isotope ratio standards (Tanaka et al., 2000. Averages and 2σ errors

  14. Nd isotopic disequilibrium be- tween minerals and Rb-Sr age of the secondary phengite in eclogite from the Yangkou area, Qingdao, eastern China

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    There are two generations of white micas in retrograded coesite-bearing eclogite from the Yangkou area near Qingdao, eastern China. The secondary phengite developed along the folliations in eclogite is the majority of the white micas. Nd and Sr isotopic disequilibriums between garnet and retrograded omphacite as well as secondary phengite have been observed. Consequently, the Rb-Sr ages ((193 ± 4) Ma―(195 ± 4) Ma) given by the tie lines of the secondary phengite + garnet or whole rock may predate the formation time of the phengite. The Rb-Sr age of (183 ± 4) Ma given by the secondary phengite + retrograde omphacite is much closer to the formation time of the phengite indicating the retrograde age of eclogite instead of a cooling age of eclogite at 500℃.

  15. Sm-Nd and Rb-Sr Isotopic Studies of Meteorite Kalahari 009: An Old VLT Mare Basalt (United States)

    Shih, C.-Y.; Nyquist, L. E.; Reese, Y.; Bischoff, A.


    Lunar meteorite Kalahari 009 is a fragmental basaltic breccia contain ing various very-low-Ti (VLT) mare basalt clasts embedded in a fine-g rained matrix of similar composition. This meteorite and lunar meteorite Kalahari 008, an anorthositic breccia, were suggested to be paired mainly due to the presence of similar fayalitic olivines in fragment s found in both meteorites. Thus, Kalahari 009 probably represents a VLT basalt that came from a locality near a mare-highland boundary r egion of the Moon, as compared to the typical VLT mare basalt samples collected at Mare Crisium during the Luna-24 mission. The concordant Sm-Nd and Ar-Ar ages of such a VLT basalt (24170) suggest that the extrusion of VLT basalts at Mare Crisium occurred 3.30 +/- 0.05 Ga ag o. Previous age results for Kalahari 009 range from approximately 4.2 Ga by its Lu-Hf isochron age to 1.70?0.04 Ga of its Ar-Ar plateau ag e. However, recent in-situ U-Pb dating of phosphates in Kalahari 009 defined an old crystallization age of 4.35+/- 0.15 Ga. The authors su ggested that Kalahari 009 represents a cryptomaria basalt. In this r eport, we present Sm-Nd and Rb-Sr isotopic results for Kalahari 009, discuss the relationship of its age and isotopic characteristics to t hose of other L-24 VLT mare basalts and other probable cryptomaria ba salts represented by Apollo 14 aluminous mare basalts, and discuss it s petrogenesis.

  16. Sm-Nd and Rb-Sr isotopic data on the sanukitoid intrusions of the Karelia, Baltic Shield (United States)

    Kovalenko, A. V.; Savatenkov, V. M.


    Sanukitoid intrusions from the Baltic Shield form post-tectonic differentiated intrusions 2.74-2.72 Ga old (Chekulaev, 1999, Lobach-Zhuchenko et al., 2000). They are represented by alkaline and calc-alkaline types which have high mg# (up to 0.6), strong LREE enrichment (Ce(N)=80-150, Yb(N)=4-7, Ce(N)/Yb(N)>20), high Sr, Ba (>1000 ppm), P2O5 (up to 1.5%) and Cr, Ni concentrations. Some intrusions contain rocks varying from ultramafite to quartz syenite. All sanukitoids are intruded by lamprophyre dykes having similar geochemical signatures. In this study we focus on the Karelian greenstone terrain within the Baltic Shield, in which sanukitoids are restricted to the younger western and central domains (2.7-2.9 Ga). Sanukitoids appear to be absent from the older Vodlozero domain (>3.0 Ga) in eastern Karelia (Lobach-Zhuchenko et al., 2000, Lobach-Zhuchenko et al., in press). About 70 Sm-Nd isotopic data on the sanukitoids of the Karelia were obtained. There is the regional distinction of the isotope composition of the rocks between the Central and West Karelian domains. The initial Epsilon Nd values and TDM range from +1.1 to +2.0 and 2.70-2.85 Ga accordingly in the youngest Central Karelian domain. The West Karelian intrusions yield an initial Epsilon Nd of -0.3- +0.7 and give the older TDM of about 2.82-2.92 Ga. It is to be noted that some intrusions of the Central Karelia domain, occurred closely to the ancient Vodlozero domain, also exhibit a similar range of initial Epsilon Nd and TDM to the intrusions of the West Karelia. There are narrow Nd isotopic compositional ranges within the individual intrusions. Rb-Sr isotopic system was studied in sanukitoids and lamprophyres of differentiated Panozero intrusion, Central Karelia. The initial 87Sr/86Sr isotope ratios range from 0.7000 to 0.7021 in these rocks indicating the derivation of these magmas from depleted mantle. Very low initial 87Sr/86Sr isotope ratios of the sanukitoids confirm the Nd isotopic characteristics

  17. Rb-Sr and Sm-Nd Ages of Zagami DML and SR Isotopic Heterogeneity in Zagami (United States)

    Nyquist, L.aurenceE.; Shih, C.-Y.; Reese, Y. D.


    Zagami contains lithologic heterogeneity suggesting that it did not form in a homogeneous, thick lava flow [1]. We have previously investigated the Sr and Nd isotopic systematics of Coarse-Grained (CG) and Fine-Grained (FG) lithologies described by [2]. Both appear to belong to Normal Zagami (NZ) [1,3], but their initial Sr-isotopic compositions differ [4,5]. Here we report new analyses of the Dark Mottled Lithology (DML, [3]) that show its age and initial Sr and Nd isotopic compositions to be identical within error limits with those of CG, but Sr initial isotopic compositions differ from those of FG.

  18. Rb-Sr, Sm-Nd, K-Ca, O, and H isotopic study of Cretaceous-Tertiary boundary sediments, Caravaca, Spain Evidence for an oceanic impact site

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    Depaolo, D.J.; Kyte, F.T.; Marshall, B.D.


    The results of isotopic and trace-element-abundance analyses of Ir-enriched Cretaceous-Tertiary-boundary clay sediments from Caravaca, Spain, and of adjacent carbonate and marl layers, are presented. Acetic-acid and HCl leachates and residues were analyzed by isotope dilution to determine K, Rb, Sr, Sm, and Nd concentrations and Sr-87/Sr-86 and Nd-143/Nd-144 ratios. The stable isotope ratios delta-D, delta-(C-13), and delta-(0-18) were also determined. The results are presented in tables and graphs and compared with published data on the Caravaca sediments and on samples from other locations. The boundary clay is found to be distinguished from the adjacent layers by its isotopic ratios and to be of mainly terrestrial, lithospheric (deeper than 3-km) origin. Although submarine-weathering effects are evident and difficult to quantify, the degree of variation in Ni, Ir, Sr, and REE concentrations is considered too large to be attributed to postdepositional processes alone. These findings are seen as evidence for the ocean impact of a large single asteroid producing a worldwide blanket of ejecta, a large injection of water vapor into the atmosphere, and perhaps a gigantic tsunami, at the end of the Cretaceous period.

  19. Erosion of the Alps: use of Rb-Sr isotopic data from molassic sediments to identify the ages of the metamorphism recorded by the eroded rocks; Erosion des Alpes: histoire metamorphique des roches erodees par l`analyse du couple Rb-Sr des sediments molassiques

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    Henry, P.; Deloule, E. [Centre National de la Recherche Scientifique (CNRS), 54 - Nancy (France). Centre de Recherches Petrographiques et Geochimiques; Michard, A. [Aix-Marseille-3 Univ., 13 - Marseille (France)


    Rb-Sr isotopic data from Oligocene and Miocene peri-alpine molassic sediments allow us to identify the different periods for which the eroded rocks have or have not recorded an alpine metamorphism. The Chattian and the Burdigalian sediments result from the erosion of rocks for which the latest metamorphic event was variscan, while the Stampian, Aquitanian and ``Helvetian`` sediments show evidence for the erosion of rocks which have recorded alpine metamorphic events. The application of this method to old detrital sediments could permit determination of the ages of the tectonic events which occurred in the sediment source regions. (authors). 18 refs., 6 figs.

  20. Rb-Sr and Sm-Nd Studies of Olivine-Phyric Shergottites RBT 04262 and LAR 06319: Isotopic Evidence for Relationship to Enriched Basaltic Shergottites (United States)

    Nyquist, L.E.; Shih, C.-Y.; Reese, Y.


    RBT 04262 and LAR 06319 are two Martian meteorites recently discovered in Antarctica. Both contain abundant olivines, and were classified as olivine-phyric shergottites. A detailed petrographic study of RBT 04262 suggested it should be reclassified as a lherzolitic shergottite. However, the moderately LREE-depleted REE distribution pattern indicated that it is closely related to enriched basaltic shergottites like Shergotty, Zagami, Los Angeles, etc. In earlier studies of a similarly olivinephyric shergottite NWA 1068 which contains 21% modal olivine, it was shown that it probably was produced from an enriched basaltic shergottite magma by olivine accumulation . As for LAR 06319, recent petrographic studies suggested that it is different from either lherzolitic shergottites or the highly LREE-depleted olivine-phyric shergottites. We performed Rb-Sr and Sm-Nd isotopic analyses on RBT 04262 and LAR 06319 to determine their crystallization ages and Sr and Nd isotopic signatures, and to better understand the petrogenetic relationships between them and other basaltic, lherzolitic and depleted olivine-phyric shergottites.

  1. Dating and source determination of volcanic rocks from Khunik area (South of Birjand, South Khorasan using Rb-Sr and Sm-Nd isotopes

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    Somayeh Samiee


    Full Text Available The Khunik area is located in the south of Birjand, Khorasan province, in the eastern margin of Lut block. Tertiary volcanic rocks have andesite to trachy-andesite composition. Dating analyzing by Rb-Sr method on plagioclase and hornblende as well as whole-rock isochron method was performed on pyroxene-hornblende andesite rock unit. On this basis the emplacement age is Upper Paleocene (58±11 Ma. These rocks have initial 87Sr/86Sr and εNd 0.7046-0.7049 and 2.16-3.12, respectively. According to isotopic data, volcanic rocks originated from depleted mantle and have the least crust contamination while it was fractionated. Geochemically, Khunik volcanic rocks have features typical of calk-alkaline to shoshonite and are metaluminous. Enrichment in LILEs and typical negative anomalies of Nb and Ti are evidences that the volcanic rocks formed in a subduction zone and active continental margin. Modeling suggests that these rocks were derived dominantly from 1–5% partial melting of a mainly spinel garnet lherzolite mantle source that is metasomatized by slab-derived fluid.

  2. Rb-Sr isotopic composition of granites in the Western Krušné hory/Erzgebirge pluton, Central Europe: record of variations in source lithologies, mafic magma input and postmagmatic hydrothermal events (United States)

    Dolejš, David; Bendl, Jiří; Štemprok, Miroslav


    The late Variscan (327-318 Ma) Western Krušné hory/Erzgebirge pluton (Czech Republic and Germany) represents a multiply emplaced intrusive sequence ranging from low-F biotite monzogranites (with rare minor bodies of gabbrodiorites and granodiorites) to high-F topaz-zinnwaldite alkali-feldspar granites. This granite suite is characterized by progressively increasing concentrations of incompatible elements (Li, Rb, F), monotonous decrease in mafic components and compatible elements (FeOtot, MgO, TiO2, CaO, Sr) with increasing silica. Consequently, this leads to extreme variations in the Rb/Sr ratios (0.52 to 59), which impose highly variable 87Rb/86Sr and 87Sr/86Sr signatures. The low-F biotite monzogranites represent isotopically heterogeneous mixture with (87Sr/86Sr)323 = 0.707-0.709 between partial melts from the Saxothuringian metasediments and mantle-derived mafic precursors. The medium-F two-mica microgranites show variable (87Sr/86Sr)323 = 0.708-0.714, indicating involvement of multiple precursors and more mature crustal protoliths. The evolved high-F topaz-zinnwaldite alkali-feldspar granites were derived from a precursor with (87Sr/86Sr)320 = 0.707-0.708 at 324-317 Ma by differentiation, which produced the extreme Rb/Sr enrichment and variations. The Li/Rb ratios remain nearly constant (~0.5), thus insensitive to the degree of geochemical differentiation. In comparison to terrestrial variations, the high Li/Rb values indicate derivation of granitic magmas from predominantly sedimentary precursors, in accord with 7Li-6Li and 143Nd-144Nd isotope composition reported previously. The Rb-Sr element variations in each granite unit are sligthly different and indicate ascent and emplacement of separate magma batches, which do not form a single liquid line of descent. We consider the enrichment of granites in incompatible elements (Li, Rb, F) and compatible depletion of ferromagnesian components, CaO and Sr as a combined effect of multiple precursors, changes in

  3. Behaviour of the Sm-Nd and Rb-Sr systems of the mafic-ultramafic layered sequence from Ribeirao dos Motas (Archaean), meridional craton Sao Francisco: evidences of mantle source enrichment and isotopic fractionation; Comportamento dos sistemas Sm-Nd e Rb-Sr da sequencia acamadada mafico-ultramafico Ribeirao dos Motas (Arqueano), craton Sao Francisco Meridional: evidencias de enriquecimento mantelico e fracionamento isotopico

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    Carneiro, Mauricio Antonio; Carvalho Junior, Irneu Mendes de; Oliveira, Arildo Henrique de [Ouro Preto Univ., (UFOP), MG (Brazil). Dept. de Geologia]. E-mail:; Teixeira, Wilson [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias. Dept. de Mineralogia e Geotectonica; Pimentel, Marcio Martins [Brasilia Univ., DF (Brazil). Inst. de Geociencias. Lab. de Geocronologia


    The Ribeirao dos Motas layered sequence (SARM) crops out in the southern part of the Sao Francisco Craton, Brazil. This sequence comprises phaneritic meta ultramafic and metamafic rocks, which, although slightly deformed and metamorphosed, retain primary igneous layers. Porphyritic rocks with idiomorphic pyroxene crystals and heteradcumulate and adcumulate textures are also present. Eighteen isotopic analyses were performed in the SARM, comprising rocks with primary (relict) textures, as well as rocks in amphibolite facies and retro-metamorphosed to green-schist facies. Seven samples yield a Sm/Nd isochron age of 2.79 +- 0.30 Ga (MSWD=1.2 e epsilon {sub Ndt}=+0.48), constraining the accretion time of the SARM rocks. The positive epsilon {sub Ndt} value coupled with the Rb/Sr evidence is consistent with mantle source relatively enriched in Nd and Sr isotopes. Nevertheless, some SARM samples display isotopic fractionation and disturbance, which can be ascribed to the following processes or their combinations: a) mobilization of the incompatible elements due to regional high grade metamorphism; b) isotopic changes during upper amphibolite facies overprint; c) isotopic resetting by low-grade fluids associated to the Claudio Shear zone, which is located nearby the SARM. (author)

  4. Rb-Sr and Sm-Nd study of granite-charnockite association in the Pudukkottai region and the link between metamorphism and magmatism in the Madurai Block (United States)

    Sekaran, M. Chandra; Bhutani, Rajneesh; Balakrishnan, S.


    Pudukkottai region in the northeastern part of the Madurai Block exposes the garnetiferous pink granite that intruded the biotite gneiss. Charnockite patches are associated with both the rock types. Rb-Sr biotite and Sm-Nd whole-rock isochron ages indicate a regional uplift and cooling at ˜550 Ma. The initial Nd isotope ratios (\\varepsilon _{ {Nd}}t=-20 to -22) and Nd depleted-mantle model ages (TDM = 2.25 to 2.79 Ga) indicate a common crustal source for the pink-granite and associated charnockite, while the biotite gneiss and the charnockite within it represent an older crustal source (\\varepsilon _{ {Nd}}t= -29 and TDM = > 3.2 Ga). The Rb-Sr whole-rock data and initial Sr-Nd isotope ratios also help demonstrate the partial but systematic equilibration of Sr isotope and Rb/Sr ratios during metamorphic mineral-reactions resulting in an `apparent whole-rock isochron'. The available geochronological results from the Madurai Block indicate four major periods of magmatism and metamorphism: Neoarchaean-Paleoproterozoic, Mesoproterozoic, mid-Neoproterozoic and late-Neoproterozoic. We suggest that the high-grade and ultrahigh-temperature metamorphism was preceded by magmatism which `prepared' the residual crust to sustain the high P- T conditions. There also appears to be cyclicity in the tectono-magmatic events and an evolutionary model for the Madurai Block should account for the cyclicity in the preserved records.

  5. Single grain Rb-Sr dating of euhedral and cataclastic pyrite from the Qiyugou gold deposit in western Henan,central China

    Institute of Scientific and Technical Information of China (English)

    HAN YiGui; LI XiangHui; ZHANG ShiHong; ZHANG YuanHou; CHEN FuKun


    The Rb-Sr isotopic dating of pyrite mineral from ore deposits can directly provide mineralization age. However,many geological factors may affect the Rb-Sr isotopic system,which baffles application of this method. Employing ultra-low procedural blank Rb-Sr method,we have dated pyrites separated from the No. 4 breccia pipe of the Qiyugou gold deposit,western Henan Province. Single grains of euhedral pyrite crystal with few micro-cracks yield an isochron age of 126 ± 11 Ma,which represents time of the main mineralization stage of the deposit. Pyrite grains of cataclastic type show nevertheless scattered Rb-Sr isotopic composition and no reasonable isochron can be defined. Crystal morphology and mineral inclusion studies reveal that Rb and Sr of pyrite mineral probably are preserved mainly in biotite,K-feldspar,and sericite mineral inclusions. The dating results likely suggest that cataclastic pyrite is not suitable for the Rb-Sr dating due to modification of the Rb-Sr isotopic system by later hydrothermal activity of fluid.

  6. Rb-Sr and Sm-Nd chronology and genealogy of mare basalts from the Sea of Tranquility (United States)

    Papanastassiou, D. A.; Depaolo, D. J.; Wasserburg, G. J.


    Rb-Sr and Sm-Nd ages of two Apollo 11 mare basalts, high-K basalt 10072 and low-K basalt 10062, are reported. Rb-Sr, Sm-Nd, and Ar-40-Ar-39 ages are in good agreement and indicate an extensive time interval for filling of the Sea of Tranquility, presumably by thin lava flows, in agreement with similar observations for the Ocean of Storms. Initial Sr and Nd isotopic compositions on Apollo 11 basalts reveal at least two parent sources producing basalts. The Sm-Nd isotopic data demonstrate that low-K and high-Ti basalts from Apollo 11 and 17 derived from distinct reservoirs, while low-Ti Apollo 15 mare basalt sources have Sm/Nd similar to the sources of Apollo 11 basalts. Groupings of mare basalt based on Ti content and on isotopic data do not coincide.

  7. Rb-Sr And Sm-Nd Ages, and Petrogenesis of Depleted Shergottite Northwest Africa 5990 (United States)

    Shih, C. Y.; Nyquist, L. E.; Reese, Y.; Irving, A. J.


    Northwest Africa (NWA) 5990 is a very fresh Martian meteorite recently found on Hamada du Draa, Morocco and was classified as an olivine-bearing diabasic igneous rock related to depleted shergottites [1]. The study of [1] also showed that NWA 5990 resembles QUE 94201 in chemical, textural and isotopic aspects, except QUE 94201 contains no olivine. The depleted shergottites are characterized by REE patterns that are highly depleted in LREE, older Sm-Nd ages of 327-575 Ma and highly LREE-depleted sources with Nd= +35+48 [2-7]. Age-dating these samples by Sm-Nd and Rb-Sr methods is very challenging because they have been strongly shocked and contain very low abundances of light rare earth elements (Sm and Nd), Rb and Sr. In addition, terrestrial contaminants which are commonly present in desert meteorites will compromise the equilibrium of isotopic systems. Since NWA 5990 is a very fresh meteorite, it probably has not been subject to significant desert weathering and thus is a good sample for isotopic studies. In this report, we present Rb-Sr and Sm-Nd isotopic results for NWA 5990, discuss the correlation of the determined ages with those of other depleted shergottites, especially QUE 94201, and discuss the petrogenesis of depleted shergottites.

  8. Isotopic evidence for the retention of Sr-90 inferred from excess Zr-90 in the Oklo natural fission reactors: Implication for geochemical behaviour of fissiogenic Rb, Sr, Cs and Ba (United States)

    Hidaka, Hiroshi; Sugiyama, Takeshi; Ebihara, Mitsuru; Holliger, Philippe


    In order to investigate the mobility of fissiogenic Sr-90 in the geological environment, the Zr isotopic compositions of seven samples from one of the newly formed Oklo natural reactor zones (i.e., reactor core and adjacent rocks (10, SF84)) in the Republic of Gabon were determined with an inductively coupled plasma mass spectrometer (ICP-MS). Zr isotopes in uraninite grains from different reactor zones were also measured by secondary ion mass spectrometry (SIMS). Fissiogenic Zr isotopic abundances of three samples from the reactor core have excess Zr-90, which has never before been formed in previous Oklo samples. In this paper, the geochemical behaviour of Zr-90 is discussed by making use of the relative retentivity inferred from the isotopic abundance of Sr. The excess in Zr-90 suggests dependence on the degree of retention/migration of Sr-90, the precursor of Zr-90 in the fission chain. In the aqueous phase, chemical fractionation between Sr and Zr could have occurred before radioactive Sr-90 decayed. Considering the halflife of Sr-90 (t(sub 1/2) = 29.1 y), considerable amounts of the latter have been produced during criticality. Sr and Zr (including Zr-90) could have been redistributed between the reactor core and its vicinity. The retentivity of fissiogenic Zr-90 in reactor core 10 is not homogeneous. In addition, the distributions of Rb, Cs and Ba is also heterogeneous.

  9. Disturbed Sr and Nd Isotope Systematics in Zircons With Concordant SHRIMP U-Pb Ages (United States)

    Weaver, K. L.; Bennett, V. C.; Depaolo, D. J.; Mundil, R.


    Little is known about the Sr- and Nd-isotopic systematics of zircon. With slow diffusion rates and a high resistance to weathering, zircon should preserve accurate age information and initial Sr and Nd isotopic ratios. As a common accessory mineral, it could provide petrogenetic information for rocks that have been altered, weathered, or metamorphosed. We have investigated the Sm-Nd and Rb-Sr systematics of zircons from unmetamorphosed granitic rocks that have yielded concordant U-Pb SHRIMP (Sensitive High Resolution Ion Microprobe) ages and have depleted mantle signatures for Nd and Sr isotopes. Zircon populations from mantle-derived igneous rocks with ages of 0.1, 1.7, and 3.8 Ga were chosen for Sr and Nd isotopic analysis. Low concentrations (Sr, 4 to 8 ppm and Nd, 6 to 12 ppm) and small grain size necessitate the use of multigrain aliquots. Meaningful results can be obtained only if all of the zircons in the rock are a coherent population with homogeneous ages throughout and among grains. Zircon U-Pb ages were characterized using the SHRIMP RG, and trace element concentrations were measured by LA-ICPMS. The populations are homogeneous and the material ablated by the ion beam ( ˜~20 μ m spot size) shows little evidence of lead loss. Results on zircons of 100 Ma and 1700 Ma indicate that both the Rb-Sr and Sm-Nd systems have been severely disturbed. For the 1700 Ma granitic rocks from the Yavapai sequence of Arizona, zircon Sm-Nd apparent ages are ca. 1000 Ma! Leaching was used to remove contributions from adhering or included minerals, but leached residues that presumably most closely approximate the composition of the pure zircon (e.g. have high Sm/Nd) are no less disturbed than unleached samples. Despite the U-Pb SHRIMP ages indicating a closed system, the zircons have failed to preserve a reasonable age or initial isotopic composition for Sr and Nd, indicating that parts of the crystal might be severely affected by radiation damage resulting in disturbed

  10. Rb-Sr whole-rock and mineral ages, K-Ar, 40Ar/39Ar, and U-Pb mineral ages, and strontium, lead, neodymium, and oxygen isotopic compositions for granitic rocks from the Salinian Composite Terrane, California: (United States)

    Kistler, R.W.; Champion, D.E.


    This report summarizes new and published age and isotopic data for whole-rocks and minerals from granitic rocks in the Salinian composite terrane, California. Rubidium-strontium whole-rock ages of plutons are in two groups, Early Cretaceous (122 to 100 Ma) and Late Cretaceous (95 to 82 Ma). Early Cretaceous plutons occur in all granitic rock exposures from Bodega Head in the north to those from the Santa Lucia and Gabilan Ranges in the central part of the terrane. Late Cretaceous plutons have been identified in the Point Reyes Peninsula, the Santa Lucia and the Gabilan Ranges, and in the La Panza Range in the southern part of the terrane. Ranges of initial values of isotopic compositions are 87Sr/86Sr, 0.7046-0.7147, δ18O, +8.5 to +12.5 per mil, 206Pb/204Pb, 18.901-19.860, 207Pb/204Pb, 15.618-15.814, 208Pb/204Pb, 38.569- 39.493, and εNd, +0.9 to -8.6. The initial 87Sr/86Sr=0.706 isopleth is identified in the northern Gabilan Range and in the Ben Lomond area of the Santa Cruz Mountains, in Montara Mountain, in Bodega Head, and to the west of the Farallon Islands on the Cordell Bank. This isotopic boundary is offset about 95 miles (160km) by right-lateral displacements along the San Gregorio-Hosgri and San Andreas fault systems.

  11. Overview of the geochemistry and Rb/Sr, Sm/Nd isotopes of Middle Jurassic and Tertiary granitoid intrusions: a new insight on tectono-magmatism and mineralization of this period in Iran

    Directory of Open Access Journals (Sweden)

    Mohammad Ali Jazi


    Full Text Available One of the most intensive occurrences of magmatism in Iran was in the middle Jurassic period. Among the granitoid intrusions in this period as discrete bodies or complexes can be pointed to Aligoodarz, Alvand, Astaneh, Boroujerd, Malayer, and Chah-Dozdan in the Sanandaj-Sirjan zone; Shir-kuh and Ayrakan in the Central Iran zone; Shah-kuh, Sorkh-kuh and Kalateh-Ahani in the Lut Block. These granitoids are mostly peraluminous and belong to high-K calc-alkaline series. CaO/Na2O ratios (0.12 to 8.37 mostly suggest a clay-free source for formation of the intrusive rocks magma. Chondrite-normalized Rare Earth Elements (REEs diagram do not display high enrichment of Light Rare Earth Elements (LREEs than Heavy Rare Earth Elements (HREEs and general pattern is relatively flat. In addition, diagram shows Eu negative anomaly, which can be attributed to indicate reducing conditions in formation of magma and/or magma derived from plagioclase depth as source. The lower continental crust-normalized spider diagram indicates enrichment in LILE (Rb, Cs, and K and LREE (La and Ce and depletion in Ba, Nb, Ta, Sr, and Ti. Initial 87Sr/86Sr ratios are 0.70609 to 0.71938 and initial εNd values are negative (from -6.51 to -1.1 indicating that magma derived from continental crust. Geochemical and isotopic evidence of the intrusive rocks shows continental crust origin (S-type granitoid and due to continental collision. Geological findings such as stop in sedimentation, regional metamorphism, ophiolite displacement, and continental collision-related mineralization confirm continental collision between Iranian and Arabian plates in the Middle Jurassic period.

  12. Spatial and temporal changes of summer monsoon on the Loess Plateau of Central China during the last 130 ka inferred from Rb/Sr ratios

    Institute of Scientific and Technical Information of China (English)

    陈旸; 陈骏; 刘连文; 季峻峰; 张建新


    The Rb/Sr ratios for samples from six loess-paleosol sections on the Chinese Loess Plateau during the last glacial-interglacial cycle, and for samplesfrom 18 modern surface soils, have been analyzed. The six sections are along north-south and west-east transects respectively. The results show that the spatial distribution of Rb/Sr is characterized by a remarkable increase from north to south while Rb/Sr ratio changes little from west to east, whose latitude indicates shift of summer monsoon intensity. A regression equation between Rb/Sr ratiosand mean annual precipitation(MAP) has been constructed through statistical analysis for the modern surface soils. Paleorainfall during the last 130 ka is estimated for the six sections based on the regression equation. It is evident thatprecipitation increased remarkably during marine isotope stages 3 and 5, exhibiting the high and similar gradients of variation with latitude. This demonstrates that the environmental effect is more prominent in the south of the Loess Plateau than in the north during the dominance of summer monsoon.

  13. Rb-Sr, Pb-Pb, U-Pb dating in the Bandja plutonic series of Western Cameroon. Donnees geochronologiques (Rb-Sr, Pb-Pb, U-Pb) sur le complexe plutonique de Bandja (Centre-Ouest Cameroun)

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    Tchankam, C.N. (Nancy-1 Univ., 54 (France)); Vialette, Y. (Clermont-Ferrand-2 Univ., 63 - Aubiere (France))


    The results of U-Pb zircon and Pb-Pb on minerals and whole rocks are reported on a charnockite syn-D1 from the Bandja series in the western Cameroon. Data are interpreted as representing a plutonic emplacement at 640 Ma. A syn- to post-tectonic pluton is dated at 557 [+-] 8 Ma (Rb-Sr whole rocks isochron). These results confirm the Pan-African age of the charnockitic intrusive body. Initial isotopic [sup 87]Sr/[sup 86]Sr ratios of charnockite (0.709) and granite (0.7089) show the importance of crustal imprint in the magma genesis. (authors).

  14. Rb-Sr middle Devonian age of cordierite bearing migmatites from Lyonnais area (French Massif Central). Age Rb-Sr, Devonien moyen des migmatites a cordierite du Lyonnais (Massif central Francais)

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    Duthou, J.L. (Clermont-Ferrand-2 Univ., 63 - Aubiere (France)); Chenevoy, M.; Gay, M. (Lyon-1 Univ., 69 - Villeurbanne (France))


    On the basis of Rb-Sr whole rock data, a middle Devonian age (384[+-]16 Ma) is ascribed to the cordierite bearing migmatites (gneiss d'Aubusson) in the Lyonnais area. In the barrovian domain, this anatexis is therefore synchronous throughout the northern part of the french ''Massif Central''. Rb and Sr concentrations were determined by X-ray fluorescence analysis, and isotopic compositions by mass spectrometry. (A.B.). 28 refs., 2 figs. 1 tab.

  15. Rb-Sr age of Gaik granite, Ladakh Batholith, northwest Himalaya

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    Trivedi, J.R.; Gopalan, K. (Physical Research Lab., Ahmedabad (India)); Sharma, K.K.; Gupta, K.R.; Choubey, V.M. (Wadia Inst. of Himalayan Geology, Dehra Dun (India))


    The Gaik Granite is a part of Ladakh batholith outcropping between Gaik and Kiari in NW Himalaya. This is a pink porphyritic granite rich in biotite and poor in hornblende. Rb-Sr analyses have been made on six whole-rock samples of the Gaik Granite. Though the samples are poorly enriched in radiogenic Sr, they define a reliable isochron corresponding to an age of 235+-13(2sigma) m.y. and initial /sup 87/Sr//sup 86/Sr ratio of 0.7081+-0.0004 (2sigma), Biotite, plagioclase and potash feldspar fractions separated from two of the samples have yielded a much younger mineral isochron at 30+-1.5 m.y. indicating a nearly complete redistribution of Sr isotopes between mineral phases at a time much later than the primary emplacement of the granite. The present results show that at least some components of the Ladakh batholith are of Permo-Triassic aqe. These rocks were isotopically re-equilibrated on a mineral scale during Upper Oligocene in response to the Himalayan orogeny.

  16. Sm-Nd, Rb-Sr, and Mn-Cr Ages of Yamato 74013 (United States)

    Nyquist, L. E.; Shih, C.- Y.; Reese, Y.D.


    Yamato 74013 is one of 29 paired diogenites having granoblastic textures. The Ar-39 - Ar-40 age of Y-74097 is approximately 1100 Ma. Rb-Sr and Sm-Nd analyses of Y-74013, -74037, -74097, and -74136 suggested that multiple young metamorphic events disturbed their isotopic systems. Masuda et al. reported that REE abundances were heterogeneous even within the same sample (Y-74010) for sample sizes less than approximately 2 g. Both they and Nyquist et al. reported data for some samples showing significant LREE enrichment. In addition to its granoblastic texture, Y-74013 is characterized by large, isolated clots of chromite up to 5 mm in diameter. Takeda et al. suggested that these diogenites originally represented a single or very small number of coarse orthopyroxene crystals that were recrystallized by shock processes. They further suggested that initial crystallization may have occurred very early within the deep crust of the HED parent body. Here we report the chronology of Y-74013 as recorded in chronometers based on long-lived Rb-87 and Sm-147, intermediate- lived Sm-146, and short-lived Mn-53.

  17. Rb-Sr geochronological study on Tatehira granodiorite, Oshima Peninsula, Southwest Hokkaido, Japan

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    Iizumi, Shigeru; Kobayashi, Hideo; Toyoda, Minoru


    It has been known that Tatehira granodiorite, a pluton which occurs sporadically in the southwest region of Hokkaido, is related with Kanoite formation. The radiometric age of this granodiorite still remains unknown. The Tatehira granodiorite intrudes into late Paleozoic or early Mesozoic Matsumae group, and is overlain by Miocene Usubetsu formation unconformably. It occurs as several separated small plutons. The samples for Rb-Sr analysis were collected from one of the plutons in southern part. The determination of the isochron age of rock-minerals and the initial Sr isotopic ratio of Tatehira granodiorite were carried out. This granodiorite is able to be classified into two phases, namely melanocratic (WRM) and leucocratic (WRL) phases. The samples of WRM and WRL were powdered and subjected to X-ray analysis. It was found that the chemical compositions were similar except slight differences in FeO + Fe2O3, CaO and K2O. The Sr isotopic ratio was determined with a MAT 261 mass spectrometer, and the results were analyzed statistically. The Rb and Sr concentrations and the Sr isotopic ratio of WRM, WRL, and PRF (plagio-clase rich fraction) and BRF (biotite rich fraction) separated from the WRL were determined, and the age of 102.5 +- 0.3 Ma and the initial ratio of 0.70538 +- 0.00001 were obtained. The ratio of Tatehira granodiorite is comparable to that of Okushiri Island. Comparing with the data obtained from other region, the granodiorites of Tatehira and Okushiri Island should be related with the granitoids of Abukuma granite province.

  18. 山东微山稀土矿矿床成因:来自云母Rb-Sr年龄、激光Nd同位素及流体包裹体的证据%Genesis of the Weishan REE deposit, Shandong Province: Evidences from Rb-Sr isochron age, LA-MC-ICPMS Nd isotopic compositions and fluid inclusions

    Institute of Scientific and Technical Information of China (English)

    蓝廷广; 范宏瑞; 胡芳芳; 杨奎锋; 王永


    Weishan REE deposit, a pegmatite-type REE deposit related to alkaline rocks, is located in Luxi Block, southeastern North China Craton. Muscovite Rb-Sr isochron yields an age of 119.5 Ma, which belonged to the Early Cretaceous large-scale mineralization in the North China Craton. LA-ICPMS Nd isotopic compositions of bastnaesite and monazite indicate that the source of the REE deposit is the enriched lithospheric mantle. Four types of fluid inclusions have been identified in quartz, fluorite and barite, including (1) H2O inclusions (H), (2) pure CO2 inclusions (C), (3) H2O+CO2 inclusions (HC) and (4) H2O+CO2+daughter mineral inclusions (HCD). The H inclusions are secondary while others are primary. The daughter minerals in HCD inclusions include thenardite, barite, celestine, calcite, aphthitalite and glauberite. The homogenization and capture pressures of HC and HCD inclusions range from 205-433 ℃ and 120-200 Mpa, respectively. Coupled with the existence of abundant daughter minerals and S stable isotopic compositions, it can be deduced that the initial ore-forming fluidswere high-temperature, moderate-pressure and high-concentration orthomagmatic fluids, which were characterized by enrichment of HCO-3/CO2-3, SO2-4 and F~ and multi-component (e.g., Na+, K+, Ca+, Ba2+, Sr2+ and REE3+). The coexistence of C, HC and HCD inclusions and the wide range of liquid/vapor ratios between these inclusions suggest that fluid unmixing may have occurred during ore-forming process. REE were most probably transported as [REEF]2+ and precipitated through fluid unmixing. Fluids mixing, which contributed little to the REE precipitation, also happened in the late stage of the ore-forming process.%微山稀土矿位于华北克拉通东南缘的鲁西地块,为与碱性岩相关的伟晶岩型稀土矿床.根据单颗粒云母Rb-Sr定年,其形成于119.5 Ma,属于华北克拉通早白垩世大规模成矿事件的一部分.稀土矿物氟碳铈矿和独居石的激光Nd同位素研

  19. K-Ca and Rb-Sr Dating of Lunar Granite 14321 Revisited (United States)

    Simon, Justin I.; Shih, C.-Y.; Nyquist, L. E.


    K-Ca and Rb-Sr age determinations were made for a bulk feldspar-rich portion of an Apollo rock fragment of the pristine lunar granite clast (14321,1062), an acid-leached split of the sample, and the leachate. K-Ca and Rb-Sr data were also obtained for a whole rock sample of Apollo ferroan anorthosite (FAN, 15415). The recent detection [1] of widespread intermediate composition plagioclase indicates that the generation of a diversity of evolved lunar magmas maybe more common and therefore more important to our understanding of crust formation than previously believed. Our new data strengthen the K-Ca and Rb-Sr internal isochrons of the well-studied Apollo sample 14321 [2], which along with a renewed effort to study evolved lunar magmas will provide an improved understanding of the petrogenetic history of evolved rocks on the Moon.

  20. Pb-, Sr- and Nd-Isotopic systematics and chemical characteristics of cenozoic basalts, Eastern China (United States)

    Peng, Z.C.; Zartman, R.E.; Futa, K.; Chen, D.G.


    Forty-eight Paleogene, Neogene and Quaternary basaltic rocks from northeastern and east-central China have been analyzed for major-element composition, selected trace-element contents, and Pb, Sr and Nd isotopic systematics. The study area lies entirely within the marginal Pacific tectonic domain. Proceeding east to west from the continental margin to the interior, the basalts reveal an isotopic transition in mantle source material and/or degree of crustal interaction. In the east, many of the rocks are found to merge both chemically and isotopically with those previously reported from the Japanese and Taiwan island-arc terrains. In the west, clear evidence exists for component(s) of Late Archean continental lithosphere to be present in some samples. A major crustal structure, the Tan-Lu fault, marks the approximate boundary between continental margin and interior isotopic behaviors. Although the isotopic signature of the western basalts has characteristics of lower-crustal contamination, a subcrustal lithosphere, i.e. an attached mantle keel, is probably more likely to be the major contributor of their continental "flavor". The transition from continental margin to interior is very pronounced for Pb isotopes, although Sr and Nd isotopes also combine to yield correlated patterns that deviate strikingly from the mid-ocean ridge basalt (MORB) and oceanic-island trends. The most distinctive chemical attribute of this continental lithosphere component is its diminished U Pb as reflected in the Pb isotopic composition when compared to sources of MORB, oceanic-island and island-arc volcanic rocks. Somewhat diminished Sm Nd and elevated Rb Sr, especially in comparison to the depleted asthenospheric mantle, are also apparent from the Nd- and Sr-isotopic ratios. ?? 1986.

  1. Dating fault-generated pseudotachylytes: comparison of 40Ar/39Ar stepwise-heating, laser-ablation and Rb-Sr microsampling analyses (United States)

    Müller, Wolfgang; Kelley, Simon; Villa, Igor


    Three different geochronological techniques (stepwise-heating, laser-ablation 40Ar/39Ar, Rb-Sr microsampling) have been evaluated for dating fault-generated pseudotachylytes sampled along the Periadriatic Fault System (PAF) of the Alps. Because pseudotachylytes are whole-rock systems composed of melt, clast and alteration phases, chemical control from both Ar isotopes (Cl/K, Ca/K ratios) and EMPA analyses is crucial for their discrimination. When applied to stepwise-heating 40Ar/39Ar analyses, this approach yields accurate melt-related ages, even for complex age spectra. The spatial resolution of laser-ablation 40Ar/39Ar analyses is capable of contrasting melt, clast and alteration phases in situ, provided the clasts are not too fine grained, the latter of which results in integrated "mixed" ages without geological information. Elevated Cl/K and Ca/K ratios were found to be an invaluable indicator for the presence of clast admixture or inherited 40Ar. Due to incomplete isotopic resetting during frictional melting, Rb-Sr microsampling dating did not furnish geologically meaningful ages. On the basis of isotopic disequilibria among pseudotachylyte matrix phases, and independent Rb-Sr microsampling dating of cogenetic (ultra)mylonites, the concordant 40Ar/39Ar pseudotachylyte ages are interpreted as formation ages. The investigated pseudotachylytes altogether reveal a Cretaceous to Miocene history for the entire PAF, consistent with independent geological evidence. Individual faults, however, consistently reveal narrower intervals of enhanced activity lasting a few million years. Electronic supplementary material to this paper can be obtained by using the Springer LINK server at

  2. Sm-Nd and Rb-Sr Ages for Northwest Africa 2977, A Young Lunar Gabbro from the PKT (United States)

    Nyquist, L. E.; Shih, C.-Y.; Reese, Y. D.; Irving, A. J.


    Northwest Africa (NWA) 2977 is an olivine gabbro cumulate equivalent to one of the lithologies in lunar mare breccia NWA 773 [1,2,3]. The Ar-39-Ar-40 age is 2.77+/-0.04 Ga based on the last approx.57% of the gas release [4], similar to results for NWA 773 [5]. A Sm-Nd age (T) of 2.865+/-0.031 Ga and Epsilon(sub Nd) = -7.84+/-0.22 for the NWA 773 gabbro reported by [6] has been revised to T = 2.993+/-=0.032 Ga, Epsilon(sub Nd) -4.5+/-0.3 [7]. Sm-147-Nd-143 isochron for NWA 2977: Whole rock, pyroxene, olivine, plagioclase, whole rock leachate (approx.phosphate) and the combined leachates from the mineral separates yield a well defined Sm-Nd isochron for an age T = 3.10+/-0.05 Ga and Epsilon(sub Nd-CHUR) = -3.74+/-0.26 [8], or Epsilon(sub Nd-HEDR) = -4.61+/-0.26 [9]. Rb-87-Sr-87 isochron: NWA 2977 contains only a modest amount of Rb and/or Sr contamination. The Sr-isotopic composition of the contaminant closely resembles that of seawater. The whole rock residue after leaching combined with leach residues for plagioclase and pyroxene define an isochron age of 3.29+/-0.11 Ga for initial Sr-87/Sr-86 = 0.70287+/-18. The olivine residue, with lower Sr abundance of approx 1.5 ppm, is only slightly displaced from the isochron. The relatively small uncertainties of the Rb-Sr isochron parameters and near-concordancy with the Sm-Nd age indicate that both the Rb-Sr and the Sm-Nd ages are reliable.

  3. An In-Situ Rb-Sr Dating & Organics Characterization Instrument For A MER+ Sized Rover (United States)

    Anderson, F.; Whitaker, T.; Nowicki, K.; Zacny, K.; Pierce, J.


    We posit that a Mars in-situ geochronology mission that will triage and validate samples for Mars Sample Return (MSR) is technically feasible in the 2018-2022 time frame and addresses the competing scientific, political, and fiscal requirements for flight in this decade.The mission must be responsive to the astrobiological and chronological science goals of the MEPAG, Decadal Survey (DS), and E2E-iSAG, and avoid the MSR appearance of long term political commitment and cost. These requirements can best be accomplished by a rover with a coring drill. JPL has reassessed the MER landing system performance, and determined that the system is capable of significantly higher landed mass (~40-60 kg plus reserve), allowing more sophisticated instruments to be carried. The instrument package is comprised of a time of flight (TOF) mass spectrometer combined with a laser desorption resonance ionization source to sensitively measure isobar free Rb-Sr isotopes for geochronology and organics characterization. The desorption laser is also used with a μRaman/LIBS for mineral characterization, which in combination with the TOF, will additionally provide measurements of K-Ar isotopes for a second form of radiometric dating. The laser desorption resonance ionization mass spectrometry (LDRIMS) technique avoids the interference and mass resolution issues associated with geochronology measurements, and has miniaturization potential. A sample is placed in the TOF mass spectrometer and surface atoms, molecules, and ions are desorbed with a 213 nm laser. Ions are suppressed by an electric field and the plume of expanding particles is present for many μs, during which it is first illuminated with laser light tuned to ionize only Sr, and then 1-3 μs later, for Rb. We have partially miniaturized the instrument, including Sr lasers, ablation laser, and mass spectrometer, and will soon to start using the instrument for field measurements. Our current prototype can measure the isotope ratio of

  4. Ar-Ar and Rb-Sr Ages of the Tissint Olivine-phyric Martian Shergottite (United States)

    Park, J.; Herzog, G. F.; Nyquist, L. E.; Shih, C.-Y.; Turin, B.; Lindsay, F. N.; Delaney, J. S.; Swisher, C. C., III; Agee, C.


    The fifth martian meteorite fall, Tissint, is an olivine-phyric shergottite that contains olivine macrocrysts (approximately 1.5 mm) [1]. [2] reported the Sm-Nd age of Tissint as 596 plus or minus 23 Ma along with Rb-Sr data that defined no isochron. [3] reported Lu-Hf and Sm-Nd ages of 583 plus or minus 86 Ma and 616 plus or minus 67 Ma, respectively. The cosmic-ray exposure ages of Tissint are 1.10 plus or minus 0.15 Ma based on 10Be [4], and 1.0-1.1 Ma, based on 3He, 21Ne, and 38Ar [5,6].We report Ar-Ar ages and Rb-Sr data.

  5. Dating Melt Rock 63545 By Rb-Sr and Sm-Nd: Age of Imbrium; Spa Dress Rehearsal (United States)

    Nyquist, L. E.; Shih, C. Y.; Reese, Y. D.


    Apollo 16 sample 63545 was initially described as one of a group of 19 generally rounded, fine-grained, crystalline rocks that were collected as rake samples [1]. This 16 g "rocklet" was collected at Station 13 on the ejecta blanket of North Ray Crater at the foot of Smoky Mountain [2]. Originally classified as a Very High Alumina (VHA) basalt on geochemical grounds [3], it was later argued to be an impact melt rock [4]. Here we report a Rb-Sr and Sm-Nd isotopic study that shows that some portions of the rock failed to reach isotopic equilibrium on last melting in agreement with the impact melt rock interpretation. Nevertheless, by omitting mineral fractions that are discordant with the majority of the data, we arrive at the time of last melting as 3.88 plus or minus 0.05 Ga ago. This age is in agreement with the Ar-39/Ar-40 plateau age of 3839 plus or minus 23 Ma [5], if the latter is adjusted for the 1.4-1.8% revision in the age of the hornblende monitor [6]. This investigation was undertaken in part as proof-of-concept for SPA-basin sample return.

  6. Rb-Sr and Sm-Nd Study of Asuka 881394: Evidence of "Late" Metamorphism (United States)

    Nyquist, L. E.; Shih, C.-Y.; Reese, Y.; Takeda, H.


    The Asuka 881394 achondrite contains fossil Al-26 and Mn-53 [1,2,3] and has a Pb-207/Pb-206 age of 4566.5 plus or minus 0.2 Ma [3], the oldest for an achondrite. Preliminary results showed initial Sm-146/Sm-144 = (7.4 plus or minus 1.2) x 10(exp -3), indicative of an ancient age, but Rb-87 - Sr-87 and Sm-147 - Nd-143 ages of 4370 plus or minus 60 and 4490 plus or minus 20 Ma, resp. [1], were younger than expected from the presence of short-lived nuclides. We revisit the Rb-Sr and Sm-Nd chronology of A881394 in an attempt to establish whether late metamorphism led to inconsistency in its apparent ages.

  7. New Rb-Sr mineral ages temporally link plume events with accretion at the margin of Gondwana (United States)

    Flowerdew, M.J.; Daly, J.S.; Riley, T.R.


    Five of six Rb-Sr muscovite mineral isochron ages from the Scotia Metamorphic Complex of the South Orkney Islands, West Antarctica, average 190 ± 4 Ma. The muscovite ages are interpreted to date foliation-formation and thus also accretion and subduction at the Gondwana margin. Coincident picrite and ferropicrite magmatism, indicative of melts from deep-seated depleted mantle, permits a causative link between accretion and the arrival of the Karoo – Ferrar – Chon Aike mantle plume in the Early Jurassic. Three biotite Rb-Sr mineral isochron ages are consistently younger and average 176 ± 5 Ma. The biotite ages may record post-metamorphic cooling or more likely retrogressive metamorphic effects during uplift.

  8. Sm-Nd and Initial Sr-87/Sr-86 Isotopic Systematics of Asuka 881394 and Cumulate Eucrites Yamato 980318/433 Compared (United States)

    Nyquist, L. E.; Shih, C-Y; Young, Y. D.; Takeda, H.


    The Asuka 881394 achondrite contains fossil Al-26 and Mn-53 and has a Pb-206/Pb-207 age of 4566.5 +/- 0.2 Ma, the oldest for an achondrite. Recent re-investigation of A881394 yielded revised initial Sm-146/Sm-144 = (9.1 +/- 1.4) x 10(exp -3), a Sm-147-Nd-143 age of 4525 +/- 58 Ma, a Rb-87-Sr-87 age of 4490 +/- 130 Ma, and initial Sr-87/Sr-86 = 0.698991 +/- 19, respectively. The relatively large uncertainties in the Sm-Nd and Rb-Sr ages are due to disturbances of the isotopic systematics of tridymite and other minor phases. A preliminary value for the Sm-147-Nd-143 age of the Yamato 980318 cumulate eucrite of 4560 +/- 150 Ma was refined in later work to 4567 +/- 24 Ma as reported orally at LPSC 35. Similarly, a preliminary value for Sm-146/Sm-144 = (7.7 +/- 1.2) x 10 (exp -3) was refined to (6.0 +/- 0.3) x 10(exp -3). For Yamato 980433, a Sm-147-Nd-143 age of 4542 +/-42 Ma and Sm-146/Sm-144 = (5.7 +/- 0.5) x 10(exp -3) has been reported. Because these two cumulate eucrites are paired, we consider them to represent one igneous rock and present their combined isotopic data here.


    Institute of Scientific and Technical Information of China (English)


    <正>20040631 Chen Jiangfeng (School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui) ; Xie Zhi Relationships Between Rb-Sr, Ar - Ar Geochronometers and Oxygen Isotopic Equilibrium of Intrusions from Eastern Anhui Province, China (Geological Journal of China Universities, ISSN 1006 - 7493, CN 32 -

  10. Cretaceous high-pressure metamorphism and low pressure overprint in the Sistan Suture Zone, eastern Iran: Additional temperature estimates for eclogites, geological significance of U-Pb zircon ages and Rb-Sr constraints on the timing of exhumation (United States)

    Kurzawa, Timon; Bröcker, Michael; Fotoohi Rad, Gholamreza; Berndt, Jasper; Lisker, Frank


    The Sistan Suture Zone, eastern Iran, includes blocks and lenses of eclogite-, blueschist- and/or epidote amphibolite-facies rocks that provide an excellent opportunity to examine the exhumation history of oceanic HP/LT rocks and their retrograde derivatives. Zr-in-rutile thermometry of eclogites corroborates previous interpretations suggesting metamorphic temperatures of ca. 550-600 °C during the HP stage in the Sistan area. Flat HREE distribution patterns and Ti-in-zircon temperatures of ca. 500-600 °C document that zircon in eclogite is of metamorphic origin. REE patterns of zircon from felsic meta-igneous rocks do not allow to distinguish between a magmatic or metamorphic origin, but relatively low temperatures indicated by Ti-in-zircon thermometry (ca. 500-600 °C) and the close similarity of zircon (U-Pb) and white mica (Rb-Sr, Ar-Ar) ages favor a metamorphic zircon origin. Previously published isotopic ages of the felsic rocks cannot unambiguously be linked to the eclogite- and/or blueschist-facies P-T conditions due to the absence of unequivocal mineralogical and petrological evidence. Instead, these rocks may record contemporaneous metamorphic processes that took place at a different depth within the subduction complex, or may indicate active ridge subduction and/or melt formation in the subduction zone at relatively low pressures. Biotite-based internal Rb-Sr isochrons of newly dated epidote amphibolite and biotite-albite gneisses indicate ages of ca. 74-80 Ma, either dating fluid-infiltration-induced formation of biotite during relatively fast uplift, or the time of final passage through the effective biotite closure temperature. Rb-Sr ages of phengite from both an epidote amphibolite and a biotite-albite gneiss yield ages that correspond to the HP/LT stage. This outcome, combined with textural evidence for derivation from eclogitic precursors documents that white mica ages of some strongly overprinted Sistan rocks are compromised by inheritance and do

  11. Extreme heterogeneity in Sr isotope systematic in the Himalayan leucogranites: A possible mechanism of partial melting based on thermal modeling

    Indian Academy of Sciences (India)

    Dilip K Mukhopadhyay


    The small leucogranite plutons occurring in linear belts in the Higher Himalayas have formed due to post-collision partial melting within the Himalayan crust. Several studies have documented that the Sr isotopic ratios in the granite bodies show chaotic variation and meaningful Rb-Sr isochron ages are difficult, if not impossible, to obtain. In tectonically overthickened crust, the depth-temperature profile (geotherm) remains strongly transient for the first tens of millions of years. It is proposed here that the intersecting relations between the transient geotherms and activity-dependent solidus/melting curves may generate small pods of magma at di erent depths and at di erent times. Each of these pods will have its unique Sr isotopic ratios. Coalescence of these small pods of magma without any e ective homogenization due to deformation-induced fast segregation, ascent and emplacement may lead to pluton-wide extreme heterogeneity in Sr isotopic ratios.

  12. Utilisation of Rb/Sr as proxy for mass wasting events in peat records from the Romanian Carpathians (United States)

    Longman, Jack; Ersek, Vasile; Veres, Daniel; Salzmann, Ulrich


    Mass wasting events, including landslides, avalanches and flooding related to heavy rains can have a major impact on the local environment. Due to their association to extreme precipitation and glacial retreat, their occurrence is likely to increase as the climate changes in the future. As such, understanding their causation, and predicting their future impact is of paramount importance. To make such predictions, understanding of the relationship between the climate and the mass-wasting event is key. For this to happen, we must use historical records of mass wasting and climate to tie the two together. As a result, a reliable, quick and easy method for determining these events in the sedimentological record must be developed. The Rb/Sr ratio has been suggested as one indicator of mass wasting events, particularly based on lake sediment research in glaciated terrain. Our work was initially developed upon the behaviour of the two elements during weathering, considering that Rb commonly substitutes for K in mineral lattices and Sr commonly for Ca, due to similar ionic radii. Minerals containing K are much more resistant than Ca-bearing ones, and so there is enrichment in weathering products of Ca, and therefore Sr. As a result, Sr should be enriched in weathered material, resulting in a lowering of the Rb/Sr ratio. This assumption has been proven as reliable in similar research involving aeolian deposits and lake sediments. Here we present the first Holocene record based on this proxy from a peat archive from a raised mountain bog in the Romanian Carpathians, nested at the foot of an avalanche-prone glacial cirque. Our geochemical assessments are based on complete digestion of samples, and analysis via ICP-OES, rather than based only on core scanning. Initial results look promising, with the peat core below the active layer (acrotelm) and above the minerogenically-influenced zone producing strong correlation to the estimates of the minerogenic input over the bog based

  13. Rb-Sr and single - zircon grain 207Pb / 206Pb chronology of the Monesterio granodiorite and related migmatites. Evidence of a Late Cambrian melting event in the Ossa-Morena Zone, Iberian Massif

    Directory of Open Access Journals (Sweden)

    Bea, F.


    Full Text Available The Monesterio granodiorite, a small granodioritic body placed in a migmatitic complex in the SW of the Olivenza-Monesterio antiform, is a key plutonic body to understanding the relationships among the magmatism, metamorphism, and deformation in the Ossa-Morena Zone, SW Iberian Massif. We dated the granodiorite with the single zircon stepwise-evaporation 207Pb/206Pb method, and the related migmatization event with the Rb-Sr method on leucosomes. Our results indicate that the Monesterio granodiorite crystallised at 510 ± 7 Ma and its protolith had a component with Upper Proterozoic zircons with a minimum age of 1696 Ma. Leucosomes give a Rb-Sr age of 511 ± 40 Ma (MSWD =1,7 with initial 87Sr/86Sr =0.70914 ± 0.00048. The lower initial 87Sr/86Sr of the granodiorite and its calc-alkaline chemistry precludes it from having derived from the same protolith as the migmatites. The existence of different magmatic bodies in the Ossa-Morena Zone with ages clustering around 500-510 Ma reveals the existence of a significant melting event during the Late Cambrian that involved protoliths with very different geochemical and isotopic signatures.La granodiorita de Monesterio es un pequeño cuerpo emplazado en un complejo migmatítico en el SO del antiforme Olivenza-Monesterio, importante para entender las relaciones entre magmatismo, metamorfismo y deformación en la Zona de Ossa-Morena. Se ha datado la granodiorita por el método de evaporación secuencial de 207Pb/206Pb en cristal único de circón y los leucosomes de las migmatitas circundantes por el método Rb-Sr. Los datos indican una edad de cristalización de la granodiorita de 510 ± 4 Ma y un posible protolito Proterozoico Superior con una edad mínima de ∼1.700 Ma, obtenida a partir de núcleos heredados de los circones analizados. Los leucosomes dan una edad Rb-Sr de 511 ± 40 Ma, con una relación 87Sr/86Sr=0,70914 ± 0,00048. La relación inicial de 87Sr/86Sr en la granodiorita (

  14. Nuclear geochronology. Chapter 6: Sedimentary rocks dating by the Rubidium-Strontium (Rb/Sr) and Potassium-Argon (K/Ar) radiometric methods; Geocronologia nuclear. Capitulo 6: Datacao de rochas sedimentares pelos metodos radiometricos rubidio-estroncio (Rb/Sr) e potassio-argonio (K/Ar)

    Energy Technology Data Exchange (ETDEWEB)

    Thomaz Filho, Antonio [Universidade do Estado, Rio de Janeiro, RJ (Brazil). Inst. de Geociencias; Mizusaki, Ana Maria Pimentel [Rio Grande do Sul Univ., Porto Alegre, RS (Brazil). Inst. de Geociencias; Kawashita, Koji [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias; Torquato, Joaquim Raul [Ceara Univ., Fortaleza, CE (Brazil). Dept. de Geologia


    The paper deals with the Rubidium/Strontium (Rb/Sr) and Potassium/Argon (K/Ar) radiometric methods application in the sedimentary rocks dating, including the methodology, the method restrictions and the ages meaning. The work concludes that the sedimentary rocks radiometric dating, by the Rb/Sr method is possible, furnishing results geologically significant. The {sup 87} Sr/{sup 86} Sr of marine carbonates has propitiated, mainly in the last years, the dating possibility of sedimentary rocks. The K/Ar radiometric method has been applied to determine the diagenetic events age of the sedimentary rocks, including its application in mesozoic and recent rocks, where the RB/Sr radiometric method presents some limitations 71 refs., 18 figs.

  15. Disturbance of isotope systematics in meteorites during shock and thermal metamorphism and implications for shergottite chronology

    Energy Technology Data Exchange (ETDEWEB)

    Gaffney, A M; Borg, L E; Asmerom, Y


    Shock and thermal metamorphism of meteorites from differentiated bodies such as the Moon and Mars have the potential to disturb chronometric information contained in these meteorites. In order to understand the impact-related mechanisms and extent of disturbance to isochrons, we undertook experiments to shock and heat samples of 10017, a 3.6 billion year old lunar basalt. One sub-sample was shocked to 55 GPa, a second subsample was heated to 1000 C for one week, and a third sub-sample was maintained as a control sample. Of the isotope systems analyzed, the Sm-Nd system was the least disturbed by shock or heat, followed by the Rb-Sr system. Ages represented by the {sup 238}U-{sup 206}Pb isotope system were degraded by shock and destroyed with heating. In no case did either shock or heating alone result in rotated or reset isochrons that represent a spurious age. In some cases the true crystallization age of the sample was preserved, and in other cases age information was degraded or destroyed. Although our results show that neither shock nor thermal metamorphism alone can account for the discordant ages represented by different isotope systems in martian meteorites, we postulate that shock metamorphism may render a meteorite more susceptible than unshocked material to subsequent disturbance during impact-related heating or aqueous alteration on Mars or Earth. The combination of these processes may result in the disparate chronometric information preserved in some meteorites.

  16. Single crystal U-Pb zircon age and Sr-Nd isotopic composition of impactites from the Bosumtwi impact structure, Ghana: Comparison with country rocks and Ivory Coast tektites. (United States)

    Ferrière, Ludovic; Koeberl, Christian; Thöni, Martin; Liang, Chen


    The 1.07 Myr old Bosumtwi impact structure (Ghana), excavated in 2.1-2.2 Gyr old supracrustal rocks of the Birimian Supergroup, was drilled in 2004. Here, we present single crystal U-Pb zircon ages from a suevite and two meta-graywacke samples recovered from the central uplift (drill core LB-08A), which yield an upper Concordia intercept age of ca. 2145 ± 82 Ma, in very good agreement with previous geochronological data for the West African Craton rocks in Ghana. Whole rock Rb-Sr and Sm-Nd isotope data of six suevites (five from inside the crater and one from outside the northern crater rim), three meta-graywacke, and two phyllite samples from core LB-08A are also presented, providing further insights into the timing of the metamorphism and a possibly related isotopic redistribution of the Bosumtwi crater rocks. Our Rb-Sr and Sm-Nd data show also that the suevites are mixtures of meta-greywacke and phyllite (and possibly a very low amount of granite). A comparison of our new isotopic data with literature data for the Ivory Coast tektites allows to better constrain the parent material of the Ivory Coast tektites (i.e., distal impactites), which is thought to consist of a mixture of metasedimentary rocks (and possibly granite), but with a higher proportion of phyllite (and shale) than the suevites (i.e., proximal impactites). When plotted in a Rb/Sr isochron diagram, the sample data points (n = 29, including literature data) scatter along a regression line, whose slope corresponds to an age of 1846 ± 160 Ma, with an initial Sr isotope ratio of 0.703 ± 0.002. However, due to the extensive alteration of some of the investigated samples and the lithological diversity of the source material, this age, which is in close agreement with a possible "metamorphic age" of ∼ 1.8-1.9 Ga tentatively derived from our U-Pb dating of zircons, is difficult to consider as a reliable metamorphic age. It may perhaps reflect a common ancient source whose Rb-Sr isotope

  17. Ground and excited state properties of the polar and paramagnetic RbSr molecule: a comparative study

    CERN Document Server

    Żuchowski, Piotr S; Dulieu, Olivier


    This paper deals with the electronic structure of RbSr, a molecule possessing both a permanent magnetic and electric dipole moment in its own frame allowing its manipulation with external fields. Two complementary ab-initio approaches are used for the ground and lowest excited states: first, an approach relying on optimized effective core potentials with core polarization potentials based on a full configuration interaction involving three valence electrons, and second, an approach using a small-size effective core potential with 19 correlated electrons in the framework of coupled-cluster theory. We have found excellent agreement between these two approaches for the ground state properties including the permanent dipole moment. We have focused on studies of excited states correlated to the two lowest asymptotes Rb(5p)+Sr(5s) and Rb(5s)+Sr(5s5p) relevant for ongoing experiments on quantum degenerate gases. We present also the Hund c) case potential curves obtained using atomic spin-orbit constants. These poten...

  18. Systematic Study on Triaxial Superdeformed Bands of Hf Isotopes

    Institute of Scientific and Technical Information of China (English)

    ZHANG Da-Li; DING Bin-Gang


    Properties of the triaxial superdeformed (TSD) bands of Hf isotopes are investigated systematically within the supersymmetry scheme including many-body interactions and a perturbation possessing the SO(5) (or SU(5)) symmetry on the rotational symmetry. Quantitatively good results of the γ-ray energies, the dynamical moments of inertia,and the spin of the TSD bands in Hf isotopes are obtained. It shows that this approach is quite powerful in describing the properties of the triaxial superdeformation in Hf isotopes.

  19. Estimating the distribution of strontium isotope ratios (87Sr/86Sr in the Precambrian of Finland

    Directory of Open Access Journals (Sweden)

    Lars Kaislaniemi


    Full Text Available A method to estimate the 87Sr/86Sr ratio of a rock based on its age and Rb/Sr ratio is presented. This method, together with data from the Rock Geochemical Database of Finland (n=6544 is used to estimate the 87Sr/86Sr ratios in the Precambrian of Finland and in its different major units. A generalization to cover the whole area of Finland is achieved by smoothing of estimation points. The estimation method is evaluated by comparing its results to published Rb-Sr isotope analyses (n=138 obtained on the Finnish Precambrian. The results show correspondence to different geological units of Finland,but no systematic difference between Archaean and younger areas is evident. Evaluation of the method shows that most of the estimates are reliable and accurate to be used as background material for provenance studies in archaeology, paleontology and sedimentology. However, some granitic rocks may have large (>1.0 % relative errors.Strontium concentration weighted average of the estimates differs only by 0.001 from the average 87Sr/86Sr ratio (0.730 of the rivers on the Fennoscandian shield.

  20. Magnesium isotope systematics in Martian meteorites (United States)

    Magna, Tomáš; Hu, Yan; Teng, Fang-Zhen; Mezger, Klaus


    Magnesium isotope compositions are reported for a suite of Martian meteorites that span the range of petrological and geochemical types recognized to date for Mars, including crustal breccia Northwest Africa (NWA) 7034. The δ26Mg values (per mil units relative to DSM-3 reference material) range from -0.32 to -0.11‰; basaltic shergottites and nakhlites lie to the heavier end of the Mg isotope range whereas olivine-phyric, olivine-orthopyroxene-phyric and lherzolitic shergottites, and chassignites have slightly lighter Mg isotope compositions, attesting to modest correlation of Mg isotopes and petrology of the samples. Slightly heavier Mg isotope compositions found for surface-related materials (NWA 7034, black glass fraction of the Tissint shergottite fall; δ26Mg > -0.17‰) indicate measurable Mg isotope difference between the Martian mantle and crust but the true extent of Mg isotope fractionation for Martian surface materials remains unconstrained. The range of δ26Mg values from -0.19 to -0.11‰ in nakhlites is most likely due to accumulation of clinopyroxene during petrogenesis rather than garnet fractionation in the source or assimilation of surface material modified at low temperatures. The rather restricted range in Mg isotope compositions between spatially and temporally distinct mantle-derived samples supports the idea of inefficient/absent major tectonic cycles on Mars, which would include plate tectonics and large-scale recycling of isotopically fractionated surface materials back into the Martian mantle. The cumulative δ26Mg value of Martian samples, which are not influenced by late-stage alteration processes and/or crust-mantle interactions, is - 0.271 ± 0.040 ‰ (2SD) and is considered to reflect δ26Mg value of the Bulk Silicate Mars. This value is robust taking into account the range of lithologies involved in this estimate. It also attests to the lack of the Mg isotope variability reported for the inner Solar System bodies at current

  1. Iron isotope systematics of the Skaergaard intrusion

    DEFF Research Database (Denmark)

    Lesher, Charles; Lundstrom, C.C.; Barfod, Gry

    report the results of a broad study of the iron isotope compositions of gabbros within the layered and upper border series of the Skaergaard intrusion, pegmatite and granophyre associated with these gabbroic rocks, and the sandwich horizon thought to represent the product of extreme differentiation and/or...... crystallization on non-traditional stable isotope systems, particularly iron. FeTi oxide minerals (titanomagnetite and ilmenite) appear after ~60% of the magma had solidified. This was a significant event affecting the liquid line of descent and potentially accompanied by iron isotope fractionation. Here we...... liquid immiscibility. Forty-eight whole rock samples from well-constrained stratigraphic levels in the intrusion were crushed, powdered and dissolved, followed by iron separation by ion chromatography. Purified solutions were analyzed by MC- ICPMS in high-resolution mode using the sample-std bracket...

  2. Iron isotope systematics of the Skaergaard intrusion

    DEFF Research Database (Denmark)

    Lesher, Charles; Lundstrom, C.C.; Barfod, Gry

    crystallization on non-traditional stable isotope systems, particularly iron. FeTi oxide minerals (titanomagnetite and ilmenite) appear after ~60% of the magma had solidified. This was a significant event affecting the liquid line of descent and potentially accompanied by iron isotope fractionation. Here we...... report the results of a broad study of the iron isotope compositions of gabbros within the layered and upper border series of the Skaergaard intrusion, pegmatite and granophyre associated with these gabbroic rocks, and the sandwich horizon thought to represent the product of extreme differentiation and....../or liquid immiscibility. Forty-eight whole rock samples from well-constrained stratigraphic levels in the intrusion were crushed, powdered and dissolved, followed by iron separation by ion chromatography. Purified solutions were analyzed by MC- ICPMS in high-resolution mode using the sample-std bracket...

  3. Iron isotope systematics in planetary reservoirs (United States)

    Sossi, Paolo A.; Nebel, Oliver; Foden, John


    Iron is the only polyvalent major element, and controls reduction-oxidation (redox) reactions in a host of geologic processes and reservoirs, from the mineral- to planetary-scale, on Earth and in space. Mass transfer of Fe is often accompanied by changes in bonding environment, meaning the resultant variation in bond-strength in crystals, liquids and gases induces stable isotope fractionation, even at high temperatures. In the absence of iron exchange, electron transfer can also affect iron's valence state and calculated oxygen fugacity (fO2), however its isotope composition remains unchanged. Thus, iron isotopes are a powerful tool to investigate processes that involve mass transfer, redox reactions and changes in bonding environment in planetary systems. Primitive chondritic meteorites show remarkable isotopic homogeneity, δ57 Fe = - 0.01 ± 0.01 ‰ (2SE), over a wide range of Fe/Mg vs Ni/Mg, a proxy for fO2 in the solar nebula. In chondrites, there are iron isotope differences between metal and silicates that become more pronounced at higher metamorphic grades. However, on a planetary scale, Mars and Vesta overlap with chondrites, preserving no trace of core formation or volatile depletion on these bodies. Upon assessment of pristine lherzolites, the Bulk Silicate Earth is heavier than chondrites (δ57 Fe = + 0.05 ± 0.01 ‰; 2SE), and similar to or slightly lighter than the Moon. That the mantles of some differentiated inner solar system bodies extend to heavier compositions (+ 0.2 ‰) than chondrites may principally result from volatile depletion either at a nebular or late accretion stage. Within terrestrial silicate reservoirs, iron isotopes provide insight into petrogenetic and geodynamic processes. Partial melting of the upper mantle produces basalts that are heavier than their sources, scaling with degree of melting and driving the increasingly refractory peridotite to lighter compositions. Mid-Ocean Ridge Basalts (MORBs) are homogeneous to δ57 Fe

  4. An Ldrims Instrument for Portable Rb-Sr Dating with Accuracy of Better than ±150 MA for the MARS-2020 Rover (United States)

    Anderson, F. Scott; Whitaker, Tom; Hamilton, Victoria; Nowicki, Keith


    Using a laser desorption resonance ionization mass spectrometer (LDRIMS), we can now demonstrate repeatable dates with portable hardware that could be carried on MER- or MSL-sized rovers. This is important because NASA is developing science requirements for a Mars 2020 rover mission based on MSL hardware, and for Mars, the National Research Council Decadal Survey (NRC DS) specifically supports: "...long-term development of instruments ... focusing on the most important future in situ measurements... [including] ... in situ geochronology experiments". The LDRIMS instrument can produce these science measurements today, and in so doing, triage samples for Mars Sample Return. The LDRIMS technique can be miniaturized and avoids the mass interference issues requiring unwieldy chemical separation for traditional geochronology techniques. With LDRIMS sample is placed in a time-of-flight (TOF) mass spectrometer and surface atoms, molecules, and ions are desorbed with a 213 nm laser. Ions are suppressed by an electric field and the plume of expanding particles is present for many μs, during which it is first illuminated with laser light tuned to ionize only Sr, and then 1-3 μs later, for Rb. This eliminates isobars for Rb and Sr, insures that the measured atoms come from the same ablation event, and hence target materials, and reduces the total number of measurements required. The LDRIMS system has demonstrated a sensitivity of 300 parts-per-trillion, and isotope ratio precisions of ±0.3 to ±0.1% in 3000-5000 ablations of one spot on a sample in 3-5 minutes. The bench top prototype has been tested on the Boulder Creek Granite (BCG) from Elephant Butte, Colorado, comprised primarily of a gneissic quartz monzonite and granodiorite. Whole rock Rb-Sr TIMS measurements of the BCG, and our own preliminary micro-drill TIMS measurements of individual minerals, are consistent with an age of 1700±40 Ma. To obtain a LDRIMS date using the BCG sample, we measured hundreds of spots

  5. Predicting the Isotopic Composition of Subduction-Filtered Subducted Oceanic Crust and Sediment (United States)

    White, W. M.


    The chemical and isotopic character of mantle plumes, which produce oceanic island volcanoes, are widely thought to reflect the presence of recycled oceanic crust and sediment. Isotopic systematics suggest the “cycle time” for this process is 1 Ga or longer, but it should be possible to use a simple mass balance approach to discern how the presently operating subduction zone filter affects the ratios of radioactive parent to radiogenic daughter isotopes. Simple uniformitarian assumptions can then be used to predict the present isotopic composition of anciently subducted lithosphere. Our underlying assumption in deciphering the subduction zone filter is that the flux of an element into the deep mantle is simply equal to the flux of element into the subduction zone less the flux of that element into subduction zone magmas. The former is readily calculated from published data. The latter can be calculated by estimating parental magma compositions, arc accretion rates, and the assumption that arc magma compositions differ from MORB only because of material derived from subducting crust and sediment. Using this approach for 8 intra-oceanic subduction zones, we find 73% of Th and Pb, 79% of U, 80% of Rb and Sr, 93% of Nd and 98% of Sm survive the subduction zone filter. The subduction zone filter systematically increases Sm/Nd ratios in all subduction zones, but the effect is small, with a weighted mean increase of 1.5%. The effect of subduction is to decrease the Sm/Nd of the mantle, but only slightly. The effect of subduction is to increase the Rb/Sr of the mantle, but the subduction zone filter does not have a systematic effect on Rb/Sr ratios: it significantly increases in Rb/Sr in 3 subduction zones and significantly decreases it in one; the weighted mean shows no significant change. The effect of the subduction zone filter on U/Pb is also not systematic. U/Pb ratios in the mantle fluxes are bimodal, with values equal to or lower than the bulk Earth value in 4

  6. Geología y geocronología Rb-Sr de granitoides de Sierra Grande, provincia de Río Negro

    Directory of Open Access Journals (Sweden)

    Ricardo Varela


    Full Text Available Al este de Sierra Grande la unidad más antigua es la Ectinita El Jagüelito, metagrauvacas y pizarras, cortadas por granitoides ordovícicos (Rb-Sr en roca total 467 ± 16 Ma; U-Pb en circón 476 ± 4 Ma. Ectinitas y granitoides son cubiertos discordantemente por sedimentitas clásticas fosilíferas silúricas de la Formación Sierra Grande y el total de unidades deformado por pliegues y fallas. Al sur de Sierra Grande, Mina Hiparsa, afloran la Ectinita El Jagüelito, la Formación Sierra Grande y granitoides, en un contexto de fuerte deformación tectónica. Desde mitad de siglo pasado se discute si los granitoides constituyen el basamento de la Formación Sierra Grande o si son intrusivos en la misma. La Formación Sierra Grande está afectada por metamorfismo térmico. Datos radimétricos previos de granitoides son discordantes (Rb-Sr en roca total 252 ± 5 Ma; 363 ± 57 Ma; 318 ± 28 Ma; U-Pb SHRIMP en circón 476 ± 6 Ma. Se efectuaron nuevos análisis Rb-Sr en roca total y minerales y se propone la existencia de dos unidades graníticas. En granitoides del noroeste de la mina, Granito Mina Hiparsa, se obtuvieron dos isocronas (262 ± 6 Ma, 87Sr/86Sr inicial = 0,7162 ± 0,0003 y 263 ± 9 Ma, 87Sr/86Sr inicial = 0,7149 ± 0,0009. En los granitoides al oeste de la Mina Hiparsa, Granodiorita Laguna Medina, se efectuó una isocrona (260 ± 3 Ma, 87Sr/86Sr Inicial = 0,7078 ± 0,0012. Las rocas estudiadas son el producto de plutonismo ordovícico temprano y pérmico tardío-temprano. Las tres isocronas roca total-minerales son pérmicas, pero dos por metamorfismo y reseteo de rocas ordovícicas (87Sr/86Sr inicial ~ 0,7150 y una por cristalización (87Sr/86Sr inicial ~ 0,7080.

  7. Late Archaean mantle metasomatism below eastern Indian craton: Evidence from trace elements, REE geochemistry and Sr-Nd-O isotope systematics of ultramafic dykes

    Indian Academy of Sciences (India)

    Abhijit Roy; A Sarkar; S Jeyakumar; S K Aggrawal; M Ebihara; H Satoh


    Trace, rare earth elements (REE), Rb-Sr, Sm-Nd and O isotope studies have been carried out on ultramafic (harzburgite and lherzolite) dykes belonging to the newer dolerite dyke swarms of eastern Indian craton. The dyke swarms were earlier considered to be the youngest mafic magmatic activity in this region having ages not older than middle to late Proterozoic. The study indicates that the ultramafic members of these swarms are in fact of late Archaean age (Rb-Sr isochron age 2613 ± 177 Ma, Sri ∼0.702 ± 0.004) which attests that out of all the cratonic blocks of India, eastern Indian craton experienced earliest stabilization event. Primitive mantle normalized trace element plots of these dykes display enrichment in large ion lithophile elements (LILE), pronounced Ba, Nb and Sr depletions but very high concentrations of Cr and Ni. Chondrite normalised REE plots exhibit light REE (LREE) enrichment with nearly flat heavy REE (HREE; ( HREE)N ∼ 2-3 times chondrite, (Gd/Yb)N∼1). The Nd(t) values vary from +1.23 to −3.27 whereas 18O values vary from +3.16‰ to +5.29‰ (average +3.97‰ ± 0.75‰) which is lighter than the average mantle value. Isotopic, trace and REE data together indicate that during 2.6 Ga the nearly primitive mantle below the eastern Indian Craton was metasomatised by the fluid (±silicate melt) coming out from the subducting early crust resulting in LILE and LREE enriched, Nb depleted, variable Nd, low Sri(0.702) and low 18O bearing EMI type mantle. Magmatic blobs of this metasomatised mantle were subsequently emplaced in deeper levels of the granitic crust which possibly originated due to the same thermal pulse.

  8. Minor-element and Sr-isotope geochemistry of tertiary stocks, Colorado mineral belt (United States)

    Simmons, E.C.; Hedge, C.E.


    Rocks of the northeast portion of the Colorado mineral belt form two petrographically, chemically and geographically distinct rock suites: (1) a silica oversaturated granodiorite suite; and (2) a silica saturated, high alkali monzonite suite. Rocks of the granodiorite suite generally have Sr contents less than 1000 ppm, subparallel REE patterns and initial 87Sr/ 86Sr ratios greater than 0.707. Rocks of the monzonite suite are restricted to the northeast part of the mineral belt, where few rocks of the granodiorite suite occur, and generally have Sr contents greater than 1000 ppm, highly variable REE patterns and 87Sr/86Sr initial ratios less than 0.706. Despite forming simple, smooth trends on major element variation diagrams, trace element data for rocks of the granodiorite suite indicate that they were not derived from a single magma. These rocks were derived from magmas having similar REE patterns, but variable Rb and Sr contents, and Rb/Sr ratios. The preferred explanation for these rocks is that they were derived by partial melting of a mixed source, which yielded pyroxene granulite or pyroxenite residues. The monzonite suite is chemically and petrographically more complex than the granodiorite suite. It is subdivided here into alkalic and mafic monzonites, and quartz syenites, based on the textural relations of their ferromagnesian phases and quartz. The geochemistry of these three rock types require derivation from separate and chemically distinct magma types. The preferred explanation for the alkalic monzonites is derivation from a heterogeneous mafic source, leaving a residue dominated by garnet and clinopyroxene. Early crystallization of sphene from these magmas was responsible for the severe depletion of the REE observed in the residual magmas. The lower Sr content and higher Rb/Sr ratios of the mafic monzonites requires a plagioclase-bearing source. The Sr-isotope systematics of the majority of these rocks are interpreted to be largely primary, and not

  9. Unlocking the zinc isotope systematics of iron meteorites (United States)

    Bridgestock, L. J.; Williams, H.; Rehkämper, M.; Larner, F.; Giscard, M. D.; Hammond, S.; Coles, B.; Andreasen, R.; Wood, B. J.; Theis, K. J.; Smith, C. L.; Benedix, G. K.; Schönbächler, M.


    Zinc isotope compositions (δ66Zn) and concentrations were determined for metal samples of 15 iron meteorites across groups IAB, IIAB, and IIIAB. Also analyzed were troilite and other inclusions from the IAB iron Toluca. Furthermore, the first Zn isotope data are presented for metal-silicate partitioning experiments that were conducted at 1.5 GPa and 1650 K. Three partitioning experiments with run durations of between 10 and 60 min provide consistent Zn metal-silicate partition coefficients of ∼0.7 and indicate that Zn isotope fractionation between molten metal and silicate is either small (at less than about ±0.2‰) or absent. Metals from the different iron meteorite groups display distinct ranges in Zn contents, with concentrations of 0.08-0.24 μg/g for IIABs, 0.8-2.5 μg/g for IIIABs, and 12-40 μg/g for IABs. In contrast, all three groups show a similar range of δ66Zn values (reported relative to ‘JMC Lyon Zn’) from +0.5‰ to +3.0‰, with no clear systematic differences between groups. However, distinct linear trends are defined by samples from each group in plots of δ66Zn vs. 1/Zn, and these correlations are supported by literature data. Based on the high Zn concentration and δ66Zn ≈ 0 determined for a chromite-rich inclusion of Toluca, modeling is employed to demonstrate that the Zn trends are best explained by segregation of chromite from the metal phase. This process can account for the observed Zn-δ66Zn-Cr systematics of iron meteorite metals, if Zn is highly compatible in chromite and Zn partitioning is accompanied by isotope fractionation with Δ66Znchr-met≈-1.5‰. Based on these findings, it is likely that the parent bodies of the IAB complex, IIAB and IIIAB iron meteorites featured δ66Zn values of about -1.0 to +0.5‰, similar to the Zn isotope composition inferred for the bulk silicate Earth and results obtained for chondritic meteorites. Together, this implies that most solar system bodies formed with similar bulk Zn isotope

  10. Hydrogen Isotopic Systematics of Nominally Anhydrous Phases in Martian Meteorites (United States)

    Tucker, Kera

    Hydrogen isotope compositions of the martian atmosphere and crustal materials can provide unique insights into the hydrological and geological evolution of Mars. While the present-day deuterium-to-hydrogen ratio (D/H) of the Mars atmosphere is well constrained (~6 times that of terrestrial ocean water), that of its deep silicate interior (specifically, the mantle) is less so. In fact, the hydrogen isotope composition of the primordial martian mantle is of great interest since it has implications for the origin and abundance of water on that planet. Martian meteorites could provide key constraints in this regard, since they crystallized from melts originating from the martian mantle and contain phases that potentially record the evolution of the H 2O content and isotopic composition of the interior of the planet over time. Examined here are the hydrogen isotopic compositions of Nominally Anhydrous Phases (NAPs) in eight martian meteorites (five shergottites and three nakhlites) using Secondary Ion Mass Spectrometry (SIMS). This study presents a total of 113 individual analyses of H2O contents and hydrogen isotopic compositions of NAPs in the shergottites Zagami, Los Angeles, QUE 94201, SaU 005, and Tissint, and the nakhlites Nakhla, Lafayette, and Yamato 000593. The hydrogen isotopic variation between and within meteorites may be due to one or more processes including: interaction with the martian atmosphere, magmatic degassing, subsolidus alteration (including shock), and/or terrestrial contamination. Taking into consideration the effects of these processes, the hydrogen isotope composition of the martian mantle may be similar to that of the Earth. Additionally, this study calculated upper limits on the H2O contents of the shergottite and nakhlite parent melts based on the measured minimum H2O abundances in their maskelynites and pyroxenes, respectively. These calculations, along with some petrogenetic assumptions based on previous studies, were subsequently used

  11. Comparative behavior of Sr, Nd and Hf isotopic systems during fluid-related deformation at middle crust levels (United States)

    Luais, Béatrice; Le Carlier de Veslud, Christian; Géraud, Yves; Gauthier-Lafaye, François


    We have carried out a comparative Rb-Sr, Sm-Nd and Lu-Hf isotopic study of a progressively deformed hercynian leucogranite from the French Massif Central, belonging to the La Marche ductile shear zone, in order to investigate the respective perturbation of these geochronometers with fluid induced deformation. The one-meter wide outcrop presents a strongly deformed and mylonitized zone at the center, and an asymmetric deformation pattern with a higher deformation gradient on the northern side of the zone. Ten samples have been carefully collected every 10 cm North and South away from the strongest deformed mylonitic zone. They have been analyzed for a complete major, trace element data set, oxygen isotopes, Rb-Sr, Sm-Nd and Lu-Hf isotopic systematics. We show that most of major and trace elements except SiO 2, alkaline elements (K 2O, Rb), and some metal transition elements (Cu), are progressively depleted with increasing deformation. This depletion includes REE + Y, but also HFS elements (Ti, Hf, Zr, Nb) which are commonly considered as immobile elements during upper level processes. Variations in elemental ratios with deformation, e.g. decrease in LREE/MREE- HREE, Nd/Hf, Th/Sr, increase in Rb/Sr, U/Th and constant Sr/Nd, lead to propose the following order of element mobility: U ≫ Th > Sr = Nd ≫ Hf + HREE. We conclude in agreement with previous tectonic and metallogenic studies that trace element patterns across the shear zone result from circulation of oxidizing F-rich hydrothermal fluids associated with deformation. A temperature of the fluid of 470-480 °C can be deduced from the δ 18O equilibrium between quartz-muscovite pairs. Elemental fractionation induces perturbation of the Rb-Sr geochronometer. The well-defined 87Rb/ 86Sr- 87Sr/ 86Sr correlation gives an apparent age of 294 ± 19 Ma, slightly younger than the 323 ± 4 Ma age of leucogranites in this area. This apparent age is interpreted as dating event of intense deformation and fluid circulation

  12. Algumas idades Rb-Sr e K-Ar de rochas granitóides da região de Vilarinho da Castanheira-Foz do Sabor (Carrazeda de Anciães-Nordeste de Portugal)


    Silva, Antero Ferreira da; KAWASHITA,KOJI


    Neste trabalho apresentam-se algumas determinações isotópicas Rb/Sr e K/Ar de idades absolutas em rochas granitóides do antiforma de Alijó-Carviçais, correspondente à região es-sudeste de Carrazeda de Anciães (Vilarinho da Castanheira-Foz do Sabor). A rocha total de duas amostras dos granitos de Castedo-Cabanas de Cima e Zêdes-Cabeça Boa-Especiarias, indiferenciados localmente, proporcionaram as idades convencionais Rb/Sr de 361.1±23.8 e 404.7±22.3M.a., com razão inicial (87Sr/86S...

  13. Re-Os isotopic system and formation age of subcontinental lithosphere mantle

    Institute of Scientific and Technical Information of China (English)


    The determination of the formation age of subcontinental Lithosphere Mantle (SCLM) is a widely concerned issue in mantle geochemistry. It is difficult to obtain the formation age of SCLM using lithophile isotopic systems such as Rb-Sr, Sm-Nd, U-Th-Pb, etc., but as siderophile elements, the Re-Os isotopic system provides a powerful tool for that work. Here a comprehensive review on the recent development in Re-Os dating for SCLM has been given.

  14. Systematic Osmium Isotope Binary Mixing Arrays in Arc Volcanism (United States)

    Alves, S.; Alves, S.; Schiano, P.; Capmas, F.; Allegre, C. J.


    Isotopic and geochemical studies on subduction-related lavas aim at constraining the nature of their mantle sources and the respective roles of source heterogeneity and petrogenetic processes in their compositions. Many components are potentially involved in producing the geochemical signatures of arc lavas: depleted mantle, subducted oceanic crust and sediments, and the overlying continental or oceanic crust. A further complication in characterizing mantle sources of arc lavas is complex mixing of some component parts via derivative fluids or melts released from the slab. Os isotope ratios are potential tracers of slab contribution in arc lavas because 1) subducted sediments are very radiogenic in Os compared to the upper mantle, and 2) Re behaves as a moderately incompatible element during mantle partial melting, whereas Os is highly compatible. Therefore, MORB have much higher Re/Os ratios than peridotites. Consequently, old oceanic crust is likely to be extremely more radiogenic than the depleted upper mantle so that recycled basaltic components should be identified by their elevated 187Os/188Os ratios. Os isotope ratios and Os and Re concentrations have been measured in 55 lavas coming from 10 different subduction zones. Samples span a large range of major element concentrations (from basalts to dacites) and Mg# (from 0.32 to 0.81). The 10 subduction zones, namely the Lesser Antilles, Java, Papua-New Guinea, the Philippines, Izu-Bonin, Kamchatka, the Aleutians, Mexico, Colombia and Peru-Chile, have a range of basement nature and thickness, as well as a range of age and sediment cover of the subducting plate. Measured 187Os/188Os ratios range from 0.130 to 1.524 and Os concentrations range from 0.048 to 46 ppt. Re concentrations range from 37 to 915 ppt. Os initial isotope ratios are systematically positively and linearly correlated with the inverse of Os concentrations in arc lavas from a given volcano, indicating that the Os isotopic compositions always

  15. Single Variable and Multivariate Analysis of Remote Laser-Induced Breakdown Spectra for Prediction of Rb, Sr, Cr, Ba, and V in Igneous Rocks

    Energy Technology Data Exchange (ETDEWEB)

    Clegg, Samuel M [Los Alamos National Laboratory; Wiens, Roger C. [Los Alamos National Laboratory; Speicher, Elly A [MT HOLYOKE COLLEGE; Dyar, Melinda D [MT HOLYOKE COLLEGE; Carmosino, Marco L [MT HOLYOKE COLLEGE


    Laser-induced breakdown spectroscopy (LIBS) will be employed by the ChemCam instrument on the Mars Science Laboratory rover Curiosity to obtain UV, VIS, and VNIR atomic emission spectra of surface rocks and soils. LIBS quantitative analysis is complicated by chemical matrix effects related to abundances of neutral and ionized species in the resultant plasma, collisional interactions within plasma, laser-to-sample coupling efficiency, and self-absorption. Atmospheric composition and pressure also influence the intensity of LIBS plasma. These chemical matrix effects influence the ratio of intensity or area of a given emission line to the abundance of the element producing that line. To compensate for these complications, multivariate techniques, specifically partial least-squares regression (PLS), have been utilized to predict major element compositions (>1 wt.% oxide) of rocks, PLS methods regress one or multiple response variables (elemental concentrations) against multiple explanatory variables (intensity at each pixel of the spectrometers). Because PLS utilizes all available explanatory variable and eliminates multicollinearity, it generally performs better than univariate methods for prediction of major elements. However, peaks arising from emissions from trace elements may be masked by peaks of higher intensities from major elements. Thus in PLS regression, wherein a correlation coefficient is determined for each elemental concentration at each spectrometer pixel, trace elements may show high correlation with more intense lines resulting from optical emissions of other elements. This could result in error in predictions of trace element concentrations. Here, results of simple linear regression (SLR) and multivariate PLS-2 regression for determination of trace Rb, Sr, Cr, Ba, and V in igneous rock samples are compared. This study focuses on comparisons using only line intensities rather than peak areas to highlight differences between SLR and PLS.

  16. Isotopic constraints on the age and early differentiation of the Earth. (United States)

    McCulloch, M T


    The Earth's age and early differentiation history are re-evaluated using updated isotopic constraints. From the most primitive terrestrial Pb isotopic compositions found at Isua Greenland, and the Pilbara of Western Australia, combined with precise geochronology of these localities, an age 4.49 +/- 0.02 Ga is obtained. This is interpreted as the mean age of core formation as U/Pb is fractionated due to sequestering of Pb into the Earth's core. The long-lived Rb-Sr isotopic system provides constraints on the time interval for the accretion of the Earth as Rb underwent significant depletion by volatile loss during accretion of the Earth or its precursor planetesimals. A primitive measured 87Sr/86Sr initial ratio of 0.700502 +/- 10 has been obtained for an early Archean (3.46 Ga) barite from the Pilbara Block of Western Australia. Using conservative models for the evolution of Rb/Sr in the early Archean mantle allows an estimate to be placed on the Earth's initial Sr ratio at approximately 4.50 Ga, of 0.69940 +/- 10. This is significantly higher than that measured for the Moon (0.69900 +/- 2) or in the achondrite, Angra dos Reis (0.69894 +/- 2) and for a Rb/Sr ratio of approximately 1/2 of chondrites corresponds to a mean age for accretion of the Earth of 4.48 + /- 0.04 Ga. The now extinct 146Sm-142Nd (T1/2(146)=103 l0(6)yrs) combined with the long-lived 147Sm-143Nd isotopic systematics can also be used to provide limits on the time of early differentiation of the Earth. High precision analyses of the oldest (3.8-3.9 Ga) Archean gneisses from Greenland (Amitsoq and Akilia gneisses), and Canada (Acasta gneiss) do not show measurable (> +/- l0ppm) variations of 142Nd, in contrast to the 33 ppm 142Nd excess reported for an Archean sample. The general lack of 142Nd variations, combined with the presence of highly positive epsilon 143 values (+4.0) at 3.9 Ga, indicates that the record of large-scale Sm/Nd fractionation events was not preserved in the early-Earth from 4

  17. Calculations of S$_{2n}$ and $\\delta<$r$^{2}>$ on long series of Kr, Rb, Sr and Xe, Cs, Ba isotopes

    CERN Document Server

    Epherre-Rey-Campagnolle, Marcelle; Campi, X


    The density dependent Hartree-Fock method has been used to study the variation of the two neutron separation energies (S/sub 2n/) and of the mean square charge radii ( delta (r/sup 2/)). Correlations between anomalous S/sub 2n/, delta (r/sup 2/) and deformations have been analyzed. (5 refs).

  18. Cooling age of the Birimian juvenile crust in West Africa. U-Pb, Rb-Sr and K-Ar data on the 2. 1 Ga granite-greenstone terrains from SW-Niger. Age de refroidissement de la croute juvenile birimienne d'Afrique de l'Ouest. Donnees U-Pb, Rb-Sr et K-Ar sur les formations a 2. 1 Ga du SW-Niger

    Energy Technology Data Exchange (ETDEWEB)

    Lama, C.; Dautel, D.; Zimmermann, J.L. (Centre National de la Recherche Scientifique (CNRS), 54 - Nancy (France). Centre de Recherches Petrographiques et Geochimiques); Barbey, P. (Nancy-1 Univ., 54 (France)); Cheilletz, A. (Centre National de la Recherche Scientifique (CNRS), 54 - Nancy (France). Centre de Recherches Petrographiques et Geochimiques Ecole Nationale Superieure de Geologie Appliquee et de Prospection Miniere, 54 - Nancy (France)); Pons, J. (Orleans Univ., 45 (France))


    A comparison between zircon U-Pb, whole-rock Rb-Sr and biotite-amphibole K-Ar data on Birimian granite-greenstone terrains from SW-Niger indicates that the youngest granitic plutons were emplaced at 2.115 [+-] 5 Ma and that both the plutons and the surrounding greenstones yield cooling ages around 2.118 Ma. The age similarity between the end of the plutonism and the cooling of plutons and surrounding greenstone further suggests rapid cooling at the end of the plutonic event and, thus, corroborates a model of greenstone metamorphism linked to the thermal effect of the plutons. (authors).

  19. Isotopic dating of the Chengjiang Fauna-bearing horizon in Central Yunnan Province, China

    Institute of Scientific and Technical Information of China (English)


    Twenty black shale samples, which are free from the influence of weathering, were collected from the Chengjiang Fauna-bearing horizon, central Yunnan Province, yielding a Pb-Pb isochron age of 534±60 Ma. Although this age is younger than both the Rb-Sr isochron age and 40Ar-39Ar age, it should represent the lower isotopic age limit of the Chengjiang Fauna.

  20. Tracing crustal evolution in the NW Iberian Peninsula through the Rb---Sr and U---Pb systematics of Palaeozoic granitoids: a review

    NARCIS (Netherlands)

    Priem, H.N.A.; Tex, E. den


    The abundant granitoids in the Palaeozoic basement of the northwestern Iberian Peninsula include 470-440 Ma old suites (Early-Middle Ordovician, now present as orthogneisses) and several Variscan suites. The age data presently available suggest that the latter have been generated in three separate t

  1. Major element, REE, and Pb, Nd and Sr isotopic geochemistry of Cenozoic volcanic rocks of eastern China: implications for their origin from suboceanic-type mantle reservoirs (United States)

    Basu, A.R.; Wang, Junwen; Huang, Wankang; Xie, Guanghong; Tatsumoto, M.


    Major- and rare-earth-element (REE) concentrations and UThPb, SmNd, and RbSr isotope systematics are reported for Cenozoic volcanic rocks from northeastern and eastern China. These volcanic rocks, characteristically lacking the calc-alkaline suite of orogenic belts, were emplaced in a rift system which formed in response to the subduction of the western Pacific plate beneath the eastern Asiatic continental margin. The rocks sampled range from basanite and alkali olivine basalt, through olivine tholeiite and quartz tholeiite, to potassic basalts, alkali trachytes, pantellerite, and limburgite. These rock suites represent the volcanic centers of Datong, Hanobar, Kuandian, Changbaishan and Wudalianchi in northeastern China, and Mingxi in the Fujian Province of eastern China. The major-element and REE geochemistry is characteristic of each volcanic suite broadly evolving through cogenetic magmatic processes. Some of the outstanding features of the isotopic correlation arrays are as follows: (1) NdSr shows an anticorrelation within the field of ocean island basalts, extending from the MORB end-member to an enriched, time-averaged high Rb Sr and Nd Sr end-member (EM1), (2) SrPb also shows an anticorrelation, similar to that of Hawaiian and walvis Ridge basalts, (3) NdPb shows a positive correlation, and (4) the 207Pb 204Pb vs 206Pb 204Pb plot shows linear arrays parallel to the general trend (NHRL) for MORB on both sides of the geochron, although in the 208Pb 204Pb vs 206Pb 204Pb plot the linear array is significantly displaced above the NHRL in a pattern similar to that of the oceanic island basalts that show the Dupal signatures. In all isotope correlation patterns, the data arrays define two different mantle components-a MORB-like component and an enriched mantle component. The isotopic data presented here clearly demonstrate the existence of Dupal compositions in the sources of the continental volcanic rocks of eastern China. We suggest that the subcontinental mantle

  2. U/Pb (SHRIMP), {sup 207}Pb/{sup 206}Pb, Rb/Sr, Sm/Nd e K/Ar geochronology of granite-greenstone terrains of Gaviao Block: implications for the Proterozoic and Archean evolution of Sao Francisco Craton, Brazil; Geocronologia U/Pb (SHRIMP), {sup 207}Pb/{sup 206}Pb, Rb/Sr, Sm/Nd e K/Ar dos terrenos granito-greenstone do Bloco do Gaviao: implicacoes para a evolucao arqueana e proterozoica do craton do Sao Francisco, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Leal, Luiz Rogerio Bastos


    The Gaviao Block (GB) in the northern portion of the Sao Francisco Craton-Northeast of Brazil, constitutes one of the oldest Archean fragments of the South American Platform Archean crust. GB underwent several events of juvenile accretion and reworking of continental crust along its evolutionary history, notably between the Archean and the Paleoproterozoic. {sup 207}Pb/{sup 206}Pb isotopic analyses were carried out in two zircons populations from strongly migmatized TTG terranes found in the proximity of Brumado: the first population (7 crystals) is taken as representative of the crystallization period of the TTG terranes at 3300 {+-} 45 Ma; the second (2 crystals) represents the age of the first even of metamorphism/migmatization at 2910 {+-} 10 Ma. {sup 207} Pb/{sup 206} Pb analyses in zircons from an outcrop of non-migmatized TTG in the area yielded a 3202 {+-} 15 Ma age (4 crystals), interpreted to be the crystallization period of the gneiss protolith. Sm/Nd analyses on the TTG rocks of the Brumado region yielded T{sub DM} model ages varying between 3.26 and 3.36 Ga and {epsilon}{sub Nd}{sup (t)} between -3.5 and +0.7. These data suggest the occurrence of juvenile accretions to the continental crust during the Archean, with differential involvement of crustal materials. The geochemical data of rare earth elements corresponding to the TTG terranes revealed moderate LRRE contents (La{sub N}=83,5), low HREE contents (La{sub N}=2,5) and a fairly fractionated pattern (La/Yb){sub N}=34, besides lack of negative Eu anomaly, showing that these rocks have similar compositions to those TTG terranes of cratonic continents, as well as some Archean rocks from CSF (e.g. Sete Voltas, Boa Vista). Finally, the youngest ages present in GB rocks (ca. 1.2-0.45 Ga) represent the role played by tectono thermal events, which produced partial or total rejuvenation of the Rb/Sr and K/Ar isotopic systems during the Espinhaco and Brasiliano cycles. In particular, K/Ar ages illustrate the

  3. Lead Isotopes in Olivine-Phyric Shergottite Tissint: Implications for the Geochemical Evolution of the Shergottite Source Mantle (United States)

    Moriwaki, R.; Usui, T.; Simon, J. I.; Jones, J. H.; Yokoyama, T.


    Geochemically-depleted shergottites are basaltic rocks derived from a martian mantle source reservoir. Geochemical evolution of the martian mantle has been investigated mainly based on the Rb-Sr, Sm-Nd, and Lu-Hf isotope systematics of the shergottites [1]. Although potentially informative, U-Th- Pb isotope systematics have been limited because of difficulties in interpreting the analyses of depleted meteorite samples that are more susceptible to the effects of near-surface processes and terrestrial contamination. This study conducts a 5-step sequential acid leaching experiment of the first witnessed fall of the geochemically-depleted olivinephyric shergottite Tissint to minimize the effect of low temperature distrubence. Trace element analyses of the Tissint acid residue (mostly pyroxene) indicate that Pb isotope compositions of the residue do not contain either a martian surface or terrestrial component, but represent the Tissint magma source [2]. The residue has relatively unradiogenic initial Pb isotopic compositions (e.g., 206Pb/204Pb = 10.8136) that fall within the Pb isotope space of other geochemically-depleted shergottites. An initial µ-value (238U/204Pb = 1.5) of Tissint at the time of crystallization (472 Ma [3]) is similar to a time-integrated mu- value (1.72 at 472 Ma) of the Tissint source mantle calculated based on the two-stage mantle evolution model [1]. On the other hand, the other geochemically-depleted shergottites (e.g., QUE 94201 [4]) have initial µ-values of their parental magmas distinctly lower than those of their modeled source mantle. These results suggest that only Tissint potentially reflects the geochemical signature of the shergottite mantle source that originated from cumulates of the martian magma ocean

  4. Rubidium isotopes in primitive chondrites: Constraints on Earth's volatile element depletion and lead isotope evolution (United States)

    Nebel, O.; Mezger, K.; van Westrenen, W.


    The bulk silicate Earth (BSE) shows substantial deficits in volatile elements compared to CI-chondrites and solar abundances. These deficits could be caused by pre-accretionary depletion in the solar nebula during condensation of solids, or by later heat-driven evaporation during collision of small bodies that later accreted to form the Earth. The latter is considered to result in isotope fractionation for elements with low condensation temperatures that correlates with the degree of depletion. Here, we report first high-precision isotope ratio measurements of the moderately volatile and lithophile trace element Rb. Data from seventeen chondrite meteorites show that their Rb isotope abundances are nearly indistinguishable from Earth, not deviating more than 1 per mil in their 87Rb/85Rb. The almost uniform solar system Rb isotope pool suggests incomplete condensation or evaporation in a single stage is unlikely to be the cause of the volatile element deficit of the Earth. As Rb and Pb have similar condensation temperatures, we use their different degrees of depletion in the BSE to address the mechanisms and timing of terrestrial volatile depletion. The Rb isotope data are consistent with a scenario in which the volatile budget of the Earth was generated by a mixture of a highly volatile-element depleted early Proto-Earth with undepleted material in the course of terrestrial accretion. Observed Pb and Rb abundances and U-Pb and Rb-Sr isotope systematics suggest that volatile addition occurred at approximately the same time at which last core-mantle equilibration was achieved. In line with previous suggestions, this last equilibration involved a second stage of Pb (but not Rb) depletion from the BSE. The timing of this second Pb loss event can be constrained to ~ 110 Ma after the start of the solar system. This model supports a scenario with core storage of Pb in the aftermath of a putative Moon forming giant impact that also delivered the bulk of the volatile

  5. Triple oxygen isotope systematics of structurally bonded water in gypsum (United States)

    Herwartz, Daniel; Surma, Jakub; Voigt, Claudia; Assonov, Sergey; Staubwasser, Michael


    The triple oxygen isotopic composition of gypsum mother water (gmw) is recorded in structurally bonded water in gypsum (gsbw). Respective fractionation factors have been determined experimentally for 18O/16O and 17O/16O. By taking previous experiments into account we suggest using 18αgsbw-gmw = 1.0037; 17αgsbw-gmw = 1.00195 and θgsbw-gmw = 0.5285 as fractionation factors in triple oxygen isotope space. Recent gypsum was sampled from a series of 10 ponds located in the Salar de Llamara in the Atacama Desert, Chile. Total dissolved solids (TDS) in these ponds show a gradual increase from 23 g/l to 182 g/l that is accompanied by an increase in pond water 18O/16O. Gsbw falls on a parallel curve to the ambient water from the saline ponds. The offset is mainly due to the equilibrium fractionation between gsbw and gmw. However, gsbw represents a time integrated signal biased towards times of strong evaporation, hence the estimated gmw comprises elevated 18O/16O compositions when compared to pond water samples taken on site. Gypsum precipitation is associated with algae mats in the ponds with lower salinity. No evidence for respective vital effects on the triple oxygen isotopic composition of gypsum hydration water is observed, nor are such effects expected. In principle, the array of δ18Ogsbw vs. 17Oexcess can be used to: (1) provide information on the degree of evaporation during gypsum formation; (2) estimate pristine meteoric water compositions; and (3) estimate local relative humidity which is the controlling parameter of the slope of the array for simple hydrological situations. In our case study, local mining activities may have decreased deep groundwater recharge, causing a recent change of the local hydrology.

  6. Helium isotopic systematics of oceanic islands and mantle heterogeneity

    Energy Technology Data Exchange (ETDEWEB)

    Kurz, M.D.; Jenkins, W.J. (Woods Hole Oceanographic Institution, MA (USA)); Hart, S.R. (Massachusetts Inst. of Tech., Cambridge (USA). Dept. of Earth and Planetary Sciences)


    The results of helium isotopic analyses in basaltic phenocrysts from the islands of Gough and Tristan da Cunha are reported which seem to indicate that the mantle beneath these islands are not primitive or undepleted relative to mid-ocean ridge basalt (MORB). New analyses from Loihi Seamount are also reported which do indicate a more primitive source. When these data are combined with values for MORBs previously obtained and plotted with respect to /sup 87/Sr//sup 86/Sr, the observed trends offer insight into the different source regions for oceanic island basalts and the nature of mantle heterogeneity.

  7. High-precision Mg isotopic systematics of bulk chondrites (United States)

    Schiller, Martin; Handler, Monica R.; Baker, Joel A.


    Variations of the mass-independent abundance of 26Mg ( δ26Mg*) and stable Mg ( δ25Mg) isotope composition of chondrites are important because they constrain the homogeneity of 26Al and Mg isotopes in the proto-planetary disc and the validity of the short-lived 26Al-to- 26Mg chronometer applied to meteorites. We present high-precision Mg isotope data and Al/Mg ratios of chondrites representing nearly all major chondrite classes, including a step-leaching experiment on the CM2 chondrite Murchison. δ26Mg* variations in leachates of Murchison representing acid soluble material are ≤ 30 times smaller than reported for neutron-rich isotopes of Ti and Cr and do not reveal resolvable deficits in δ26Mg* (-0.002 to + 0.118‰). Very small variations in δ26Mg* anomalies in bulk chondrites (-0.006 to + 0.019‰) correlate with increasing 27Al/ 24Mg ratios and δ50Ti, reflecting the variable presence of calcium-aluminium-rich inclusions (CAIs) in some types of carbonaceous chondrites. Similarly, release of radiogenic 26Mg produced by 26Al decay from CAI material in the step-leaching of Murchison best explains the high δ26Mg* observed in the last, aggressive, leaching steps of this experiment. Overall, the observed variations in δ26Mg* are small and potential differences beyond that which result from the presence of CAI-like material cannot be detected within the analytical uncertainties of this study (± 0.004‰). The results do not allow radical heterogeneity of 26Al (≥±30%) or measurable Mg nucleosynthetic heterogeneity (≥±0.005‰) to have existed on a planetesimal scale in the proto-planetary disc. Combined with published δ26Mg* data for CAIs, the bulk chondrite data yield a precise initial ( 26Al/ 27Al) 0 = (5.21 ± 0.06) × 10 -5 and δ26Mg* = -0.0340 ± 0.0016‰ for the Solar System. However, it is not possible with the currently available data to determine with certainty whether CAIs and the material from which planetesimals accreted including


    Directory of Open Access Journals (Sweden)

    Marco Natale


    Full Text Available We present the geochemical composition and the stable isotope signature (18O/16O and 2H/1H of waters sampled from six lakes (Caldonazzo, Levico, Lases, Santa Colomba, Lamar and Santo located in the Province of Trento. The chemical compositions invariably revealed a HCO3-Ca hydrochemical facies; however slight differences were observed among the lakes, in relation to the lithologies distinguishing each lakes’drainage basin. Elemental ratios and in particular the Rb/Sr provide a discriminative tool to recognize the rocks that have been weathered; for example this ratio is high in water that interacted with volcanic ignimbrites (rhyolites, and low in rocks that interacted with carbonate rocks. Many other trace elements were analyzed, thus providing baseline data, and only arsenic displayed concentrations higher than the legislative threshold defined for drinking water (10mg/l, especially in Lake Levico (10-19 mg/l. As concerns the stable isotopes δD and δ18O, the obtained results approach the meteoric signature for waters sampled during the 2012 winter season. The waters sampled during two summers (2011 and 2012 displayed distinctive trends, reflecting the significant influence of evaporative processes. We emphasize that the annual differences recorded in the isotopic composition of distinct years are plausibly related to temperature changes and type of precipitation that recharged the lakes. In this light, the peculiar isotopic signature recorded in the year 2011 is possibly related to a significant snowy period, which greatly contributed to the lakes’ water budget. Interestingly, waters from Lake Santa Colomba were systematically different from all the other samples, possibly due to more effective evaporative processes, or to the involvement of deep underground recharge including fossil waters.

  9. Constraints from Li isotope systematics on subduction recycling, arc magmatism, and continent growth: An overview (United States)

    Leeman, W. P.; Lee, C. A.; Chan, L. H.


    Great expectations that Li isotopic systematics can uniquely constrain many fluid-mitigated geologic processes have met with mixed success for a variety of reasons. On a local scale (some volcanic arc segments) Li composition can be highly correlated with other geochemical tracers of subduction fluids whereas, globally, such correlations tend to be disappointingly poor. The utility of Li isotopes as a tracer is limited in part by extensive overlap between mantle and subduction inputs, by limited understanding of equilibrium isotopic fractionation effects, and by apparent departures from equilibrium behavior. On the other hand, Li elemental systematics provide important constraints on global recycling processes because major litho-tectonic reservoirs have distinctive enrichments or depletions with respect to Nb or other HFSEs. Such chemical fractionations can be understood in terms of differential solubility of these elements in aqueous fluids vs. silicate melts, as well as the roles of weathering, dehydration, metamorphic or melting processes. For example, arc lavas are are systematically enriched in Li compared to those from other settings and typically have Li/Nb greater than BSE (consistent with addition of Li-rich fluids to their sources). In contrast, bulk continental crust and orogenic granitoids tend to have lower Li/Nb than BSE or arc lavas. Moreover, mass balance implies that the residual mantle (DM) produced by segregation of crust has higher Li/Nb than BSE. However, if continental crust is ultimately derived by subduction related magmatism, high Li/Nb would be expected for the crust and low Li/Nb for the upper mantle. This interesting conundrum is easiest explained in terms of selective Li removal from crustal protolith rocks via chemical weathering and erosion, which also is consistent with Li isotopic compositions of crust, mantle and seawater reservoirs. Thus, Li elemental and isotopic systematics (and relevant proxies) provide complementary

  10. Systematic measurement of beta-decay half-lives of short-lived isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Hirose, T.; Yamamoto, H.; Kawade, K. [Nagoya Univ. (Japan); Iida, T.; Takahashi, A.; Kasugai, Y.; Ikeda, Y.


    We have measured the half-lives of short-lived isotopes for past decade and deduced the half-lives of 6 isotopes further. These results demonstrated that most of the literature values shorter than 10 min systematically deviated from our measurement ones. The cause seems to be that a large number of the previous half-life studies were performed with scintillation counters before 1970 and they had a difficulty in distinguishing the interest {gamma}-ray from the contamination and correcting for pile-up and dead-time losses. Moreover, the deviated data found to be quoted for evaluation. (author)

  11. Carbon and nitrogen isotope systematics in diamond: Different sensitivities to isotopic fractionation or a decoupled origin? (United States)

    Hogberg, K.; Stachel, T.; Stern, R. A.


    Using stable isotope data obtained on multiple aliquots of diamonds from worldwide sources, it has been argued that carbon and nitrogen in diamond are decoupled. Here we re-investigate the carbon-nitrogen relationship based on the most comprehensive microbeam data set to date of stable isotopes and nitrogen concentrations in diamonds (n = 94) from a single locality. Our diamond samples, derived from two kimberlites in the Chidliak Field (NE Canada), show large variability in δ13C (- 28.4 ‰ to - 1.1‰, mode at - 5.8‰), δ15N (- 5.8 to + 18.8‰, mode at - 3.0‰) and nitrogen contents ([N]; 3800 to less than 1 at.ppm). In combination, cathodoluminescence imaging and microbeam analyses reveal that the diamonds grew from multiple fluid pulses, with at least one major hiatus documented in some samples that was associated with a resorption event and an abrupt change from low δ13C and [N] to mantle-like δ13C and high [N]. Overall, δ13C appears to be uncorrelated to δ15N and [N] on both the inter- and intra-diamond levels. Co-variations of δ15N-log[N], however, result in at least two parallel, negatively correlated linear arrays, which are also present on the level of the individual diamonds falling on these two trends. These arrays emerge from the two principal data clusters, are characterized by slightly negative and slightly positive δ15N (about - 3 and + 2‰, respectively) and variable but overall high [N]. Using published values for the diamond-fluid nitrogen isotope fractionation factor and nitrogen partition coefficient, these trends are perfectly reproduced by a Rayleigh fractionation model. Overall, three key elements are identified in the formation of the diamond suite studied: (1.) a low δ13C and low [N] component that possibly is directly associated with an eclogitic diamond substrate or introduced during an early stage fluid event. (2.) Repeated influx of a variably nitrogen-rich mantle fluid (mildly negative δ13C and δ15N). (3.) In waning

  12. Oxygen isotope equilibration systematics between quartz and water

    Energy Technology Data Exchange (ETDEWEB)

    Matthews, A. (Hebrew Univ., Jerusalem, Israel); Beckinsale, R.D.


    The /sup 18/O//sup 16/O fractionation accompanying the hydrothermal crystallization of quartz from silicic acid at 265/sup 0/ to 465/sup 0/C has been studied in order to assess the influences of (a) rate of quartz formation, (b) the nature of the reaction mechanism, and (c) temperature. At 360/sup 0/ and 465/sup 0/C, there are no indications of rate effects influencing isotope partitioning, but at 265/sup 0/C (where fractionation factors show an unusally large scatter) the evidence is inconclusive in this respect. All reaction appears to occur through solution-precipitation processes, with the intermediate phases, cristobalite and silica K, giving identical fractionation factors (within experimental errors) to quartz samples formed at the same temperature. The temperature-dependence of fractionation in the range 265/sup 0/ to 465/sup 0/C is given by the equation 10/sup 3/ ln ..cap alpha..(SiO/sub 2/--H/sub 2/O) = 3.05 x 10/sup 6/T/sup -2/ - 2.09. The data are in good agreement with other experimental calibrations of the quartz-water fractionation.

  13. Carbon and Nitrogen Isotope Systematics in a Sector-Zoned Diamond from the Mir Kimberlite, Yakutia (United States)

    Hauri, E.; Bulanova, G.; Pearson, G.; Griffin, B.


    A single Yakutian octahedral diamond, displaying striking cubic and octahedral growth sectors surrounded by an octahedral rim, has been analysed for carbon and nitrogen isotopic compositions by SIMS and for nitrogen concentration (by SIMS and FTIR) and nitrogen aggregation state (FTIR). A graphite "seed" inclusion identified within the diamond, enriched in K, Ca, Ti, Rb and Sr, provides evidence that the diamond may have grown from a carbonate melt/fluid interacting with upper mantle rocks. Carbon and nitrogen isotope compositions become progressively heavier from the core region (d13C = -7 to -5 and d15N= -3) towards the inner rim zones (d13C = -3 and d15N = +8.9 to +5) of the diamond. Nitrogen concentration and aggregation measurements show corresponding decreases that generally correlate with the isotopic variations. These systematic variations within the core and intermediate regions of the diamond are consistent with their formation during diamond growth from CO2-rich fluids as a continuous event, accompanied by slight progressive isotopic fractionation of carbon and nitrogen. However, the observed isotope and nitrogen abundance trends are not those predicted from thermodynamic modelling of fluid-solid equilibria in a C-N-O-H-bearing system due to changes in parameters such as fO2 (Deines, 1980; Deines et al 1989). Within the finely-zoned octahedral rim region, non-systematic variations in nitrogen abundance, nitrogen aggregation, and nitrogen and carbon isotope ratios were observed. Several interpretations are given for this phenomenon, including kinetic effects during growth of the diamond rim under different conditions from those of the core-intermediate regions, or rapidly changing fluid sources during the growth. No fractionation of nitrogen isotopes between cubic and octahedral growth zones was identified within the studied diamond, in contrast with the fractionation phenomena found in synthetic diamonds of mixed growth. Our results illustrate the

  14. Blueschist-facies high-Si phengites record the timing of greenschist-facies overprinting: a Rb-Sr and Ar-ar study of marbles from the Cyclades, Greece (United States)

    Bieling, D.; Bröcker, M.; Hacker, B.; Gans, P.


    In the Attic-Cycladic crystalline belt (Greece), white mica geochronology (Rb-Sr, K-Ar, Ar-Ar) has established time constraints for at least two metamorphic events: well-preserved high-pressure/low-temperature rocks yielded Eocene ages (c. 50-40 Ma); their greenschist-facies counterparts provided Oligocene-Miocene dates (c. 25-20 Ma). Previous studies indicated that the ages recorded by high-Si phengites may not correspond to the high-pressure stage but to the subsequent greenschist-facies overprint. This hypothesis is based on the observation that the range in Si-contents and the modal proportion of phengites with a specific Si-value are not significantly different between Eocene HP rocks and Oligocene-Miocene greenschists. The possibility that the barometric information and the geochronological record might be decoupled is of general importance for interpretation of phengite ages from polymetamorphic rocks. In order to look in more detail into this problem, we have studied marbles from Tinos and Sifnos. On both islands, HP rocks are best preserved in the upper parts of the metamorphic succession. Towards the base, the degree of greenschist overprinting increases. Phengite populations of blueschist- and greenschist facies rocks mostly show a considerable range in Si-values. However, in marbles which are either associated with HP or strongly retrogressed rocks, homogeneous high-Si phengite populations (>3.5 pfu) were recognized. On Tinos, Rb-Sr and Ar-Ar white mica dating of such samples yielded ages between 40 to 24 Ma. Of special interest are samples which yielded ages of c. 24 Ma. If the earlier metamorphic history is not taken into account, such datasets may suggest the erroneous conclusion of Miocene HP metamorphism. Recent studies [1] have reported large displacements (> 100km) for detachment faults in the Aegean. The critical parameter for such models is the age of HP metamorphism as deduced from white mica dating [1,2]. In the light of the complexities

  15. Iron Isotope Systematics of the Bushveld Complex, South Africa: Initial Results (United States)

    Stausberg, N.; Lesher, C. E.; Hoffmann-Barfod, G.; Glessner, J. J.; Tegner, C.


    Iron isotopes show systematic changes in igneous rocks that have been ascribed to fractional crystallization, partial melting, as well as, diffusion effects. Layered mafic intrusions, such as the Paleoproterozoic Bushveld Igneous Complex, are ideally suited to investigate stable isotope fractionation arising principally by fractional crystallization. The upper 2.1km of the Bushveld Complex (Upper and Upper Main Zone, UUMZ) crystallized from a basaltic magma produced by a major recharge event, building up a sequence of tholeiitic, Fe-rich, gabbroic cumulate rocks that display systematic variations in mineralogy and mineral compositions consistent with fractional crystallization. Within this sequence, magnetite joins the liquidus assemblage at ˜260m, followed by olivine at 460m and apatite at 1000m. Here, we present iron isotope measurements of bulk cumulate rocks from the Bierkraal drill core of UUMZ of the western limb. Iron was chemically separated from its matrix and analyzed for δ56Fe (relative to IRMM- 014) with a Nu plasma MC-ICPMS at the University of California, Davis, using (pseudo-) high resolution and sample-standard bracketing. The δ56Fe values for Bushveld cumulates span a range from 0.04‰ to 0.36‰, and systematically correlate with the relative abundance of pyroxene + olivine, magnetite and plagioclase. Notably, the highest δ56Fe values are found in plagioclase-rich cumulates that formed prior to magnetite crystallization. δ56Fe is also high in magnetite-rich cumulates at the onset of magnetite crystallization, while subsequent cumulates exhibit lower and variable δ56Fe principally reflecting fractionation of and modal variations in magnetite, pyroxene and fayalitic olivine. The overall relationships for δ56Fe are consistent with positive mineral - liquid Fe isotope fractionation factors for magnetite and plagioclase, and negative to near zero values for pyroxene and olivine. These initial results are being integrated into a forward model of

  16. Isotopic evidence of Middle Proterozoic magmatism from Bombay High Field: Implications to crustal evolution of western offshore of India

    Indian Academy of Sciences (India)

    S S Rathore; A R Vijan; M P Singh; B N Prabhu; Anand Sahu


    Precambrian granitic basement rocks obtained from well BH-36 of Bombay High Field, western offshore of India has been studied both by Rb-Sr and K-Ar dating methods. Seven basement samples chosen from two cores have yielded whole rock Rb-Sr isochron age of 1446 ± 67Ma with an initial 87Sr/86Sr ratio of 0.7062 ± 0.0012. This age has been interpreted as the formation/emplacement time of the granite. Two biotite fractions of different grain size separated from a sample CC6B2T have yielded Rb-Sr mineral isochron age of 1385 ± 21 Ma. However, these fractions when studied by K-Ar dating method have yielded slightly higher but mutually consistent ages of 1458 ± 43Ma and 1465 ± 43Ma, respectively. Further, two biotites separated from additional samples CC5B9T and CC6B3B have yielded K-Ar ages of 1452 ± 42Ma and 1425 ± 40Ma with an overall mean age of 1438 ± 19Ma. This mean K-Ar age is indistinguishable from whole rock Rb-Sr isochron as well as mineral isochron age within experimental error. The similarity in the whole rock and biotite ages obtained by different isotopic methods suggests that no thermal disturbance has occurred in these rocks after their emplacement/formation around 1450Ma ago. The present study provides the evidence for the existence of an important Middle Proterozoic magmatic event around 1400-1450Ma on the western offshore of India which, hitherto, was thought to be mainly confined to the eastern Ghats, Satpura and Delhi fold belt of India. This finding may have an important bearing on the reconstruction of Proterozoic crustal evolution of western Indian shield.

  17. Rb-Sr age and content of potassium, rubidium strontium, barium, and rare earths in surface material from the Sea of Fertility (United States)

    Allegre, C. J.; Birck, J. L.; Loubet, M.; Provost, A.


    The Luna 16 automatic station returned from the Sea of Fertility a 35 cm long column of lunar surface material. 1 g of the Luna 16 lunar surface material, taken at a depth of 22 cm, consists of fine material: surface material and fine fragments of rocks from 1 to 4 mm in diameter. Analyses made on 17 mg of the fine lunar surface material are presented. The results obtained for the Luna 16 surface material are plotted on the diagram of the isotopic evolution of strontium and show that this surface material is most depleted of radiogenic Sr-87 of all the known lunar surface materials and that the point characterizing Lunar 16 lies somewhat to the right of the line corresponding to an age of 4.6 billion years.

  18. Rb-Sr and Sm-Nd geochronology of the Cana Brava layered mafic-ultramafic intrusion, Brazil, and considerations regarding its tectonic evolution

    Energy Technology Data Exchange (ETDEWEB)

    Correia, Ciro Teixeira; Girardi, Vicente A.V.; Tassinari, Colombo C.G. [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias; Jost, Hardy [Brasilia Univ., DF (Brazil). Dept. de Geociencias


    The Cana Brava complex is an anorogenic stratiform complex, whose layers dip from 30{sup 0} to 50{sup 0} NW. The massif is made up of five units composed of layers containing several associations of cumulus phases and variable amounts of inter-cumulus minerals. Transition between units are characterized by abrupt changes in the composition of these phases. From base to top, the sequence consists of amphibolites (PICB1), overlain by serpentinites (PICB2), metawebsterites (PICB3), and metagabbros (PICB4 and PICB5). This sequence was originally formed by microgabbros, peridotites, websterites, and gabbros. Isotopic data indicate that the parental magma of the Cana Brava complex evolved as follows: mantle derivation at about 2.5 Ga and subsequent retention at subcrustal levels; intrusion within the Palmeiropolis volcano-sedimentary sequence and igneous crystallization at about 2.0 Ga; (c) Metamorphism and ductile-ruptile deformation under compression at about 1.3 Ga; and (d) Further metamorphic reequilibration during the Brasiliano Cycle at about 0.77 Ga. (Author) 27 refs., 7 figs., 2 tabs.

  19. Kalkkop Crater, Cape Province, South Africa: Confirmation of impact origin using osmium isotope systematics (United States)

    Koeberl, Christian; Reimold, Wolf Uwe; Shirey, Steven B.; le Roux, F. G.


    The Kalkkop structure, a circular depression with a diameter of 640 m, is situated in the Eastern Cape Province, South Africa. In 1992, a bore hole was drilled in the center of the crater to a depth of 151.8 m. To assess a possible impact origin of this structure, the abundances and isotopic ratios of osmium and rhenium were measured in breccias and in sandstones and shales derived from the basement. The basement rocks show rhenium and osmium abundances and isotopic compositions of osmium and neodymium ( 187Os /188Os = 0.61 to 0.92 and ɛNd = -6 to-7) that are typical for continental crust. One of the breccia samples shows a significantly elevated osmium content and a much lower ( 187Os /188Os ratio of about 0.215 (( 187Os /188Os ratio = 1.79 ). This ratio is much closer to meteoritic compositions than to crust, indicating the presence of about 0.05% of an extraterrestrial component in the breccia. This is the first time that osmium isotope systematics have been used to confirm the impact origin of a crater structure, and demonstrates their sensitivity for impact studies.

  20. The impact of (n,$\\gamma$) cross section uncertainties of unstable isotopes near N=50 on nucleosynthesis models of the i process in He-shell flash white dwarfs

    CERN Document Server

    Denissenkov, Pavel; Pignatari, Marco; Jones, Samuel; Nikas, Stylianos; Perdikakis, Georgios; Schatz, Hendrik; Spyrou, Artemis; Goebel, Kathrin; Thomas, Benedikt; Herwig, Falk


    The first peak s-process elements Rb, Sr, Y and Zr in the post-AGB star Sakurai's object (V4334 Sagittarii) are the result of i-process nucleosynthesis in a post-AGB very-late thermal pulse event. The remaining discrepancies between the observed and predicted elemental abundance distributions may be due to uncertain nuclear physics data used in the simulations. We identify the unstable isotopes of Br, Kr, Rb, Sr, Y and Zr whose (n,$\\gamma$) cross section uncertainties will affect simulation predictions. We show that simple, but fast, one-zone simulations can be used instead of more realistic multi-zone stellar simulations for extensive nuclear sensitivity and uncertainty studies, provided that the one-zone setup is first calibrated using the multi-zone simulations. We find that among the 52 unstable isotopes selected for our analysis only uncertainties in the (n,$\\gamma$) cross sections of $^{85}$Br, $^{88}$Kr and $^{89}$Kr have significant effects on the predicted abundances of Rb, Sr, Y and Zr. A further an...

  1. A systematic regional trend in helium isotopes across the northernbasin and range province, Western North America

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, B. Mack; van Soest, Matthijs C.


    An extensive study of helium isotopes in fluids collectedfrom surface springs, fumaroles and wells across the northern Basin andRange Province reveals a systematic trend of decreasing 3He/4He ratiosfrom west to east. The western margin of the Basin and Range ischaracterized by mantle-like ratios (6-8 Ra) associated with active orrecently active crustal magma systems (e.g., Coso, Long Valley,Steamboat, and the Cascade volcanic complex). Moving towards the east,the ratios decline systematically to a background value of ~;0.1 Ra. Theregional trend is consistent with extensive mantle melting concentratedalong the western margin and is coincident with an east-to-west increasein the magnitude of northwest strain. The increase in shear strainenhances crustal permeability resulting in high vertical fluid flow ratesthat preserve the high helium isotope ratios at the surface. Superimposedon the regional trend are "helium spikes," local anomalies in the heliumisotope composition. These "spikes" reflect either local zones of mantlemelting or locally enhanced crustal permeability. In the case of theDixie Valley hydrothermal system, it appears to be a combination ofboth.

  2. Preliminary Report on U-Th-Pb Isotope Systematics of the Olivine-Phyric Shergottite Tissint (United States)

    Moriwaki, R.; Usui, T.; Yokoyama, T.; Simon, J. I.; Jones, J. H.


    Geochemical studies of shergottites suggest that their parental magmas reflect mixtures between at least two distinct geochemical source reservoirs, producing correlations between radiogenic isotope compositions, and trace element abundances.. These correlations have been interpreted as indicating the presence of a reduced, incompatible-element- depleted reservoir and an oxidized, incompatible-element-rich reservoir. The former is clearly a depleted mantle source, but there has been a long debate regarding the origin of the enriched reservoir. Two contrasting models have been proposed regarding the location and mixing process of the two geochemical source reservoirs: (1) assimilation of oxidized crust by mantle derived, reduced magmas, or (2) mixing of two distinct mantle reservoirs during melting. The former clearly requires the ancient martian crust to be the enriched source (crustal assimilation), whereas the latter requires a long-lived enriched mantle domain that probably originated from residual melts formed during solidification of a magma ocean (heterogeneous mantle model). This study conducts Pb isotope and U-Th-Pb concentration analyses of the olivine-phyric shergottite Tissint because U-Th-Pb isotope systematics have been intensively used as a powerful radiogenic tracer to characterize old crust/sediment components in mantle- derived, terrestrial oceanic island basalts. The U-Th-Pb analyses are applied to sequential acid leaching fractions obtained from Tissint whole-rock powder in order to search for Pb isotopic source components in Tissint magma. Here we report preliminary results of the U-Th-Pb analyses of acid leachates and a residue, and propose the possibility that Tissint would have experienced minor assimilation of old martian crust.

  3. Hydrogen and carbon isotope systematics in hydrogenotrophic methanogenesis under H2-limited and H2-enriched conditions: implications for the origin of methane and its isotopic diagnosis (United States)

    Okumura, Tomoyo; Kawagucci, Shinsuke; Saito, Yayoi; Matsui, Yohei; Takai, Ken; Imachi, Hiroyuki


    Hydrogen and carbon isotope systematics of H2O-H2-CO2-CH4 in hydrogenotrophic methanogenesis and their relation to H2 availability were investigated. Two H2-syntrophic cocultures of fermentatively hydrogenogenic bacteria and hydrogenotrophic methanogens under conditions of pure cultures of hydrogenotrophic methanogens under conditions of 105 Pa-H2 were tested. Carbon isotope fractionation between CH4 and CO2 during hydrogenotrophic methanogenesis was correlated with pH2, as indicated in previous studies. The hydrogen isotope ratio of CH4 produced during rapid growth of the thermophilic methanogen Methanothermococcus okinawensis under high pH2 conditions ( 105 Pa) was affected by the isotopic composition of H2, as concluded in a previous study of Methanothermobacter thermautotrophicus. This " {δ D}_{{H}_2} effect" is a possible cause of the diversity of previously reported values for hydrogen isotope fractionation between CH4 and H2O examined in H2-enriched culture experiments. Hydrogen isotope fractionation between CH4 and H2O, defined by (1000 + {δ D}_{{CH}_4} )/(1000 + {δ D}_{{H}_2O} ), during hydrogenotrophic methanogenesis of the H2-syntrophic cocultures was in the range 0.67-0.69. The hydrogen isotope fractionation of our H2-syntrophic dataset overlaps with those obtained not only from low- pH2 experiments reported so far but also from natural samples of "young" methane reservoirs (0.66-0.74). Conversely, such hydrogen isotope fractionation is not consistent with that of "aged" methane in geological samples (≥0.79), which has been regarded as methane produced via hydrogenotrophic methanogenesis from the carbon isotope fractionation. As a possible process inducing the inconsistency in hydrogen isotope signatures between experiments and geological samples, we hypothesize that the hydrogen isotope signature of CH4 imprinted at the time of methanogenesis, as in the experiments and natural young methane, may be altered by diagenetic hydrogen isotope exchange

  4. Ce isotope systematics of island arc lavas from the Lesser Antilles (United States)

    Bellot, Nina; Boyet, Maud; Doucelance, Régis; Pin, Christian; Chauvel, Catherine; Auclair, Delphine


    The La-Ce systematics has one of the longest half-lifes (T1/2 = 292.5 Ga) of radioactive decay systems used in isotope geochemistry. Variations of the 138Ce/142Ce ratio are expected to be small and the use of Ce as isotopic tracer requires a very precise measurement. Compared to Sm-Nd studies, the La-Ce decay system can provide additional information about the nature of sediments recycled in subduction zones, because unusually large Ce anomalies relative to the neighboring rare earth elements exist in marine sediments such as fish teeth or hydrothermal deposits. Here, we present a chemical purification technique for Ce, and mass spectrometric technique to perform accurate and reproducible analyses of Ce isotopes of natural samples. We report a large set of Ce isotope data including analysis of 2 Ce reference material solutions (AMES and JMC-304), 2 rock standards (BCR-2 and BHVO-2), 2 chondrites (the carbonaceous chondrite Allende and the enstatite chondrite Sahara 97072), 4 mid-ocean ridge basalts, 30 arc lavas from the Martinique Island and 5 oceanic sediments from DSDP-site 144 drilled on the Demerara rise. The long-term, external precision obtained on the AMES reference material is 80 ppm (2 s.d., 138Ce/142Ce = 0.0225732 ± 18, n = 89). However, we note an evolution of isotopic ratios measured in static mode over the duration of this study (33 months). When the reproducibility is calculated from the AMES reference material measured during the same analytical session, it averages 40 ppm. All the 138Ce/142Ce ratios have been normalized to the AMES value of 0.0225746 (measured in session 7, 2 s.d. = 14 ppm, n = 8), a session during which the chondritic value has been defined and the peak tailing was negligible. The 138Ce/142Ce ratio measured for the JMC-304 Ce reference reagent is 0.0225706 ± 9 (2 s.d. = 38 ppm, n = 10). The analytical precision on natural samples is improved by a factor of about 4 in relation to previous studies on island arcs (Tanaka et al

  5. Correlations Among Microstructure, Morphology, Chemistry, and Isotopic Systematics of Hibonite in CM Chondrites (United States)

    Han, J.; Liu, M.-C..; Keller, L. P.; Davis, A. M.


    Introduction: Hibonite is a primary refractory phase occurring in many CAIs, typically with spinel and perovskite. Our microstructural studies of CAIs from carbonaceous chondrites reveal a range of stacking defect densities and correlated non-stoichiometry in hibonite. We also conducted a series of annealing experiments, demonstrating that the Mg-Al substitution stabilized the formation of defect-structured hibonite. Here, we continue a detailed TEM analysis of hibonite-bearing inclusions from CM chondrites that have been well-characterized isotopically. We examine possible correlations of microstructure, morphology, mineralogy, and chemical and isotopic systematics of CM hibonites in order to better understand the formation history of hibonite in the early solar nebula. Methods: Fifteen hibonite-bearing inclusions from the Paris CM chondrite were analyzed using a JEOL 7600F SEM and a JEOL 8530F electron microprobe. In addition to three hibonite-bearing inclusions from the Murchison CM chondrite previously reported, we selected three inclusions from Paris, Pmt1-6, 1-9, and 1-10, representing a range of 26Al/27Al ratios and minor element concentrations for a detailed TEM study. We extracted TEM sections from hibonite grains using a FEI Quanta 3D field emission gun SEM/FIB. The sections were then examined using a JEOL 2500SE field-emission scanning TEM equipped with a Thermo-Noran thin window EDX spectrometer. Results and Discussion: A total of six hibonite-bearing inclusions, including two platy hibonite crystals (PLACs) and four spinel-hibonite inclusions (SHIBs), were studied. There are notable differences in chemical and isotopic compositions between the inclusions (Table 1), indicative of their different formation environment or timing. Our TEM observations show perfectly-ordered, stoichiometric hibonite crystals without stacking defects in two PLACs, 2-7-1 and 2-8-2, and in three SHIBs, Pmt1-6, 1-9, and 1-10. In contrast, SHIB 1-9-5 hibonite grains contain a

  6. Systematic investigation of projectile fragmentation using beams of unstable B and C isotopes (United States)

    Thies, R.; Heinz, A.; Adachi, T.; Aksyutina, Y.; Alcantara-Núñes, J.; Altstadt, S.; Alvarez-Pol, H.; Ashwood, N.; Aumann, T.; Avdeichikov, V.; Barr, M.; Beceiro-Novo, S.; Bemmerer, D.; Benlliure, J.; Bertulani, C. A.; Boretzky, K.; Borge, M. J. G.; Burgunder, G.; Camaño, M.; Caesar, C.; Casarejos, E.; Catford, W.; Cederkäll, J.; Chakraborty, S.; Chartier, M.; Chulkov, L. V.; Cortina-Gil, D.; Crespo, R.; Datta, U.; Díaz Fernández, P.; Dillmann, I.; Elekes, Z.; Enders, J.; Ershova, O.; Estradé, A.; Farinon, F.; Fraile, L. M.; Freer, M.; Freudenberger, M.; Fynbo, H. O. U.; Galaviz, D.; Geissel, H.; Gernhäuser, R.; Göbel, K.; Golubev, P.; Gonzalez Diaz, D.; Hagdahl, J.; Heftrich, T.; Heil, M.; Heine, M.; Henriques, A.; Holl, M.; Ickert, G.; Ignatov, A.; Jakobsson, B.; Johansson, H. T.; Jonson, B.; Kalantar-Nayestanaki, N.; Kanungo, R.; Knöbel, R.; Kröll, T.; Krücken, R.; Kurcewicz, J.; Kurz, N.; Labiche, M.; Langer, C.; Le Bleis, T.; Lemmon, R.; Lepyoshkina, O.; Lindberg, S.; Machado, J.; Marganiec, J.; Maroussov, V.; Mostazo, M.; Movsesyan, A.; Najafi, A.; Nilsson, T.; Nociforo, C.; Panin, V.; Paschalis, S.; Perea, A.; Petri, M.; Pietri, S.; Plag, R.; Prochazka, A.; Rahaman, A.; Rastrepina, G.; Reifarth, R.; Ribeiro, G.; Ricciardi, M. V.; Rigollet, C.; Riisager, K.; Röder, M.; Rossi, D.; Sanchez del Rio, J.; Savran, D.; Scheit, H.; Simon, H.; Sorlin, O.; Stoica, V.; Streicher, B.; Taylor, J. T.; Tengblad, O.; Terashima, S.; Togano, Y.; Uberseder, E.; Van de Walle, J.; Velho, P.; Volkov, V.; Wagner, A.; Wamers, F.; Weick, H.; Weigand, M.; Wheldon, C.; Wilson, G.; Wimmer, C.; Winfield, J. S.; Woods, P.; Yakorev, D.; Zhukov, M. V.; Zilges, A.; Zuber, K.; R3B Collaboration


    Background: Models describing nuclear fragmentation and fragmentation fission deliver important input for planning nuclear physics experiments and future radioactive ion beam facilities. These models are usually benchmarked against data from stable beam experiments. In the future, two-step fragmentation reactions with exotic nuclei as stepping stones are a promising tool for reaching the most neutron-rich nuclei, creating a need for models to describe also these reactions. Purpose: We want to extend the presently available data on fragmentation reactions towards the light exotic region on the nuclear chart. Furthermore, we want to improve the understanding of projectile fragmentation especially for unstable isotopes. Method: We have measured projectile fragments from 10,12 -18C and B-1510 isotopes colliding with a carbon target. These measurements were all performed within one experiment, which gives rise to a very consistent data set. We compare our data to model calculations. Results: One-proton removal cross sections with different final neutron numbers (1 p x n ) for relativistic 10,12 -18C and B-1510 isotopes impinging on a carbon target. Comparing model calculations to the data, we find that the epax code is not able to describe the data satisfactorily. Using abrabla07 on the other hand, we find that the average excitation energy per abraded nucleon needs to be decreased from 27 MeV to 8.1 MeV. With that decrease abrabla07 describes the data surprisingly well. Conclusions: Extending the available data towards light unstable nuclei with a consistent set of new data has allowed a systematic investigation of the role of the excitation energy induced in projectile fragmentation. Most striking is the apparent mass dependence of the average excitation energy per abraded nucleon. Nevertheless, this parameter, which has been related to final-state interactions, requires further study.

  7. Os-He Isotope Systematics of Iceland Picrites: Evidence for a Deep Origin of the Iceland Plume (United States)

    Brandon, Alan D.; Graham, David W.; Waight, Tod; Gautason, Bjarni


    Recent work on the origin of the Iceland hotspot suggests that it may result from upwelling upper mantle material rather than a deep plume. To constrain the depths of origins of Iceland mantle sources, Os and He isotope systematics were obtained on a suite picrites that span the compositional range observed within the neovolcanic zones.

  8. Sr, Nd, and Pb isotopes of ultramafic xenoliths in volcanic rocks of Eastern China: enriched components EMI and EMII in subcontinental lithosphere (United States)

    Tatsumoto, M.; Basu, A.R.; Wankang, H.; Junwen, W.; Guanghong, X.


    The UThPb, SmNd, and RbSr isotopic systematics of mafic and ultramafic xenolithic rocks and associated megacrystic inclusions of aluminous augite and garnet, that occur in three alkalic volcanic suites: Kuandian in eastern Liaoning Province, Hanluoba in Hebei Province, and Minxi in western Fujian Province, China are described. In various isotopic data plots, the inclusion data invariably fall outside the isotopic ranges displayed by the host volcanic rocks, testifying to the true xenolithic nature of the inclusions. The major element partitioning data on Ca, Mg, Fe, and Al among the coexisting silicate minerals of the xenoliths establish their growth at ambient mantle temperatures of 1000-1100??C and possible depths of 70-80 km in the subcontinental lithosphere. Although the partitioning of these elements reflects equilibrium between coexisting minerals, equilibria of the Pb, Nd, and Sr isotopic systems among the minerals were not preserved. The disequilibria are most notable with respect to the 206Pb 204Pb ratios of the minerals. On a NdSr isotopic diagram, the inclusion data plot in a wider area than that for oceanic basalts from a distinctly more depleted component than MORB with higher 143Nd 144Nd and a much broader range of 87Sr 86Sr values, paralleling the theoretical trajectory of a sea-water altered lithosphere in NdSr space. The garnets consistently show lower ?? and ?? values than the pyroxenes and pyroxenites, whereas a phlogopite shows the highest ?? and ?? values among all the minerals and rocks studied. In a plot of ??207 and ??208, the host basalts for all three areas show lower ??207 and higher ??208 values than do the xenoliths, indicating derivation of basalts from Th-rich (relative to U) sources and xenoliths from U-rich sources. The xenolith data trends toward the enriched mantle components, EMI and EMII-like, characterized by high 87Sr 86Sr and ??207 values but with slightly higher 143Nd 144Nd. The EMI trend is shown more distinctly by the host

  9. Age and isotopic marks of K-rich Manning Massif trachybasalts: an evidence for Lambert-Amery rift-system initiation (East Antarctica) (United States)

    Leitchenkov, German; Belyatsky, Boris; Lepekhina, Elena; Antonov, Anton; Krymsky, Robert; Andronikov, Alex; Sergeev, Sergey


    source of contamination was an ancient material (> 2.4 Ga) and/or with high μ (26.5). The initial isotope characteristics of the studied basalts are the same for different individual flows: ɛNd=-3.4±0.4; 87Sr/86Sri=0.7061±0.0003, 206Pb/204Pbi=18.421±0.001; 207Pb/204Pbi=15.667±0.001; 208Pb/204Pbi=39.845±0.001; 187Os/186Osi = 0.2012±0.0004 and reflect minimal influence of host-rock contamination during or after melts crystallization and correspond to enriched mantle source signatures akin to plume-like. Thus the Manning Massif K-rich basalts correlate with the time of formation of the Late-Paleozoic coal-bearing sediments of the Lambert Glacier Rift and basic dykes of Jetty Peninsula [Mikhalsky, Sheraton, 1993] and can be interpreted to mark the earliest, Lower Carboniferous stage of the rifting. This event corresponds to the initial intracontinental stretching in the Eastern Gondwana wich was previously detected only in Perth Basin of western Australia. The research was done under financial support by RSF grant N 16-17-10139. References: Andronikov A.V., Foley S.F., Beliatsky B.V. 1998. Sm-Nd and Rb-Sr isotopic systematics of the East Antarctic Manning Massif alkaline trachybasalts and the development of the mantle beneath the Lambert-Amery rift. Mineral. Petrol. 63. 243-261. Mikhalsky E.V., Sheraton J.W. 1993. Association of dolerite and lamprophyre dykes, Jetty Peninsula (Prince Charles Mountains, East Antarctica). Antarctic Sciences. 5(3). 297-307.

  10. Sr Isotope Constraints on the Age and Source of Ore—Forming Materials of Gold Deposits,Southwestern Hunan

    Institute of Scientific and Technical Information of China (English)

    彭建堂; 戴塔根; 等


    We have measured Rb and Sr concentrations in fluid inclusions of quartz in gold deposits,southwestern Hunan,The Rb-Sr isochron ages of 435±9Ma and 412±33Ma are respectively determined,revealing that gold mineralization in this area took place in the Caledonian period rather than in the Wuling-Xuefeng period as traditionalyy considered.Sr isotope geochemistry of the hydrothermal fluid indicates that the ore-forming materials are of crust origin,derived largely from the ore-hositng strata rather than from the basic dikes.

  11. Sulfur isotope composition of metasomatised mantle xenoliths from the Bultfontein kimberlite (Kimberley, South Africa): Contribution from subducted sediments and the effect of sulfide alteration on S isotope systematics (United States)

    Giuliani, Andrea; Fiorentini, Marco L.; Martin, Laure A. J.; Farquhar, James; Phillips, David; Griffin, William L.; LaFlamme, Crystal


    Sulfur isotopes are a powerful geochemical tracer in high-temperature processes, but have rarely been applied to the study of mantle metasomatism. In addition, there are very limited S isotope data on sub-continental lithospheric mantle (SCLM) material. For cratonic regions, these data are restricted to sulfide inclusions in diamonds. To provide new constraints on the S isotope composition of the SCLM and on the source(s) of mantle metasomatic fluids beneath the diamondiferous Kimberley region (South Africa), we investigated the S isotope systematics of five metasomatised mantle xenoliths from the Bultfontein kimberlite. Pentlandite and chalcopyrite in these xenoliths were analysed by in situ secondary-ion mass spectrometry (SIMS), with bulk-rock material measured by gas source isotope ratio mass spectrometry techniques. Based on previous studies, the xenoliths experienced different types of metasomatism to one another at distinct times (∼180 and ∼90-80 Ma). Contained pentlandite grains show variable alteration to heazlewoodite (i.e. Ni sulfide) + magnetite. The in situ S isotope analyses of pentlandite exhibit a relatively restricted range between -5.9 and - 1.4 ‰δ34 S (compared to VCDT), with no statistically meaningful differences between samples. Chalcopyrite only occurs in one sample and shows δ34 S values between -5.4 and - 1.0 ‰. The bulk-rock Ssulfide isotope analyses vary between -3.4 and + 0.8 ‰δ34 S. Importantly, the only sample hosting dominantly fresh sulfides shows a bulk-rock δ34 S value consistent with the mean value for the sulfides, whereas the other samples exhibit higher bulk 34S/32S ratios. The differences between bulk-rock and average in situδ34 S values are directly correlated with the degree of sulfide alteration. This evidence indicates that the elevated 34S/32S ratios in the bulk samples are not due to the introduction of heavy S (commonly as sulfates) and are best explained by isotopic fractionation coupled with the removal

  12. Evaluation of strontium isotope abundance ratios in combination with multi-elemental analysis as a possible tool to study the geographical origin of ciders

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Ruiz, Silvia [Department of Physical and Analytical Chemistry, University of Oviedo, Julian Claveria 8, 33006 Oviedo (Spain); Moldovan, Mariella [Department of Physical and Analytical Chemistry, University of Oviedo, Julian Claveria 8, 33006 Oviedo (Spain); Fortunato, Giuseppino [Swiss Federal Laboratories for Materials Testing and Research EMPA, 9014 St. Gallen (Switzerland); Wunderli, Samuel [Swiss Federal Laboratories for Materials Testing and Research EMPA, 9014 St. Gallen (Switzerland); Garcia Alonso, J. Ignacio [Department of Physical and Analytical Chemistry, University of Oviedo, Julian Claveria 8, 33006 Oviedo (Spain)]. E-mail:


    In order to evaluate alternative analytical methodologies to study the geographical origin of ciders, both multi-elemental analysis and Sr isotope abundance ratios in combination with multivariate statistical analysis were estimated in 67 samples from England, Switzerland, France and two Spanish regions (Asturias and the Basque Country). A methodology for the precise and accurate determination of the {sup 87}Sr/{sup 86}Sr isotope abundance ratio in ciders by multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) was developed. Major elements (Na, K, Ca and Mg) were measured by ICP-AES and minor and trace elements (Li, Be, B, Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Y, Mo, Cd, Sn, Sb, Cs, Ba, La, Ce, W, Tl, Pb, Bi, Th and U) were measured by ICP-MS using a collision cell instrument operated in multitune mode. An analysis of variance (ANOVA test) indicated that group means for B, Cr, Fe, Ni, Cu, Se, Cd, Cs, Ce, W, Pb, Bi and U did not show any significant differences at the 95% confidence level, so these elements were rejected for further statistical analysis. Another group of elements (Li, Be, Sc, Co, Ga, Y, Sn, Sb, La, Tl, Th) was removed from the data set because concentrations were close to the limits of detection for many samples. Therefore, the remaining elements (Na, Mg, Al, K, Ca, Ti, V, Mn, Zn, As, Rb, Sr, Mo, Ba) together with {sup 87}Sr/{sup 86}Sr isotope abundance ratio were considered for principal component analysis (PCA) and linear discriminant analysis (LDA). Finally, LDA was able to classify correctly 100% of cider samples coming from different Spanish regions, France, England and Switzerland when considering Na, Mg, Al, K, Ca, Ti, V, Mn, Zn, As, Rb, Sr, Mo, Ba and {sup 87}Sr/{sup 86}Sr isotope abundance ratio as original variables.

  13. Osmium-Isotope and Platinum-Group-Element Systematics of Impact-Melt Rocks, Chesapeake Bay Impact Structure, Virginia, USA (United States)

    Lee, Seung Ryeol; Wright Horton, J., Jr.; Walker, Richard J.


    Osmium (Os) isotopes and platinum-group elements (PGEs) are useful for geochemically identifying a meteoritic component within impact structures, because meteorites are typically characterized by low (187)Os/(188)Os ratios and high PGE concentrations. In contrast, most types of crustal target rocks have high radiogenic Os and very low PGE concentrations. We have examined Os isotope and PGE systematics of impact-melt rocks and pre-impact target rocks from a 2004 test hole in the late Eocene Chesapeake Bay impact structure and from nearby coreholes. Our goal is to determine the proportion of the projectile component in the melt rock Additional information is included in the original extended abstract.

  14. Li and B Isotope Systematics of Ultrahigh-pressure Metamorphic Rocks from the Chinese Continental Scientific Drilling Program

    Institute of Scientific and Technical Information of China (English)

    Yilin Xiao; Rolf L. Romer; Jochen Hoefs; Anette Meixner; Zeming Zhang


    @@ 1 Introduction Recent improvements in the precision of Li and B isotope measurements have demonstrated the potential of these elements in tracing a wide range of geological processes. The Li and B isotope systematics of ultrahigh-pressure (UHP) metamorphic rocks provides a unique opportunity to investigate the behaviour of Li and B during fluid-rock interaction at high temperatures and very high pressures and to constrain the fluid budget and the recycling of subducted crustal materials into the mantle during UHP metamorphism.

  15. Additional Sr Isotopic Heterogeneity in Zagami Olivine-Rich Lithology (United States)

    Misawa, K.; Niihara, T.; Shih, C.-Y; Reese, Y. D.; Nyquist, L. E.; Yoneda, S.; Yamashita, H.


    Prior isotopic analyses of Zagami have established differing initial Sr-87/Sr-86 (ISr) ratios of among Zagami lithologies, fine-grained (FG), coarse-grained (CG), and dark mottled lithologies (DML)]. The Zagami sample (KPM-NLH000057) newly allocated from the Kanagawa Prefectural Museum of Natural History contained DML and the Ol-rich lithology which included more ferroan olivines (Ol-rich: Fa(sub 97- 99) vs late-stage melt pockets: Fa(sub 90-97)]). We have combined mineralogy-petrology and Rb-Sr isotopic studies on the Kanagawa Zagami sample, which will provide additional clues to the genesis of enriched shergottites and to the evolution of Martian crust and mantle

  16. Probing Archean lithosphere using the Lu-Hf isotope systematics of peridotite xenoliths from Somerset Island kimberlites, Canada (United States)

    Schmidberger, Stefanie S.; Simonetti, Antonio; Francis, Don; Gariépy, Clément


    A knowledge of the Hf isotopic composition of the subcontinental lithosphere beneath Archean cratons is essential to constrain the Hf isotope budget of the Earth's mantle. Hf isotopic measurements were obtained by MC-ICP-MS for a suite of refractory peridotite xenoliths and constituent garnets from the Nikos kimberlite (100 Ma) on Somerset Island in order to constrain the isotopic composition and age of the lithosphere beneath the northern Canadian craton. The low-temperature Nikos peridotites (Somerset lithosphere, are characterized by higher 176Lu/ 177Hf ratios (0.03-0.05) and Hf isotopic values ( 176Hf/ 177Hf (0.1Ga)=0.28296-0.28419) than the deep-seated high-temperature peridotites (>1100°C; 0.004-0.03, 0.28265-0.28333, respectively). These differences in Hf isotope signatures suggest that shallow and deep subcontinental lithosphere beneath Somerset Island represent isotopically distinct domains and do not share a common petrogenetic history. The Lu-Hf isotope systematics of the shallow low-temperature peridotites define a positively sloped line that plot along a 2.8 Ga reference isochron. A number of these peridotites are characterized by highly radiogenic Hf isotopic compositions suggestive of long-term radiogenic ingrowth (billions of years). These findings are consistent with an interpretation that the shallow Somerset lithosphere (to depths of ˜150 km) stabilized in the Archean. The majority of the high-temperature peridotites plot closer to the composition of the host kimberlite. Although the observed isotopic variation may be attributed in part to kimberlite-related Hf addition, it is possible that these deep-seated xenoliths represent younger mantle. The superchondritic 176Lu/ 177Hf ratios observed for a number of the shallow low-temperature peridotites indicate strong fractionation of Lu and Hf, suggesting mantle root formation in the garnet stability field (depths >80 km). The Hf isotope compositions for the Somerset low-temperature peridotites

  17. Clumped-Isotope Thermometry and Oxygen Isotope Systematics in Speleothem Calcite From a Near Cave-Entrance Environment (United States)

    Carlson, P. E.; Banner, J.; Breecker, D.; Affek, H. P.


    Speleothems that grow in well-ventilated zones of caves have not been widely used in paleoclimate studies, yet may provide paleotemperature records. These zones are characterized by low CO2 concentrations year-round and, in temperate climates, large seasonal temperature fluctuations. They are typically avoided for paleoclimate reconstruction due to concerns about kinetic isotope effects (KIE). However, speleothems in general seem to be sensitive to KIE, even in non-ventilated areas and can nonetheless provide useful paleoclimate records. At Westcave Preserve (Westcave), a shallow, well-ventilated cave in central Texas, we have found seasonal temperature differences recorded in both the oxygen isotope and clumped isotope compositions of speleothem calcite grown on glass-plate substrates harvested from active drips. Although growth rates in this cave are relatively rapid, speleothem analogs in Westcave are growing near oxygen-isotopic equilibrium with their drip waters (between the calibrations of Kim and O'Neil, 1997 and Coplen, 2007). We have tested the compatibility of the Zaarur et al. (2013) clumped isotope bulk solution thermometer calibration to glass-substrate calcite in the cave collected during various months. This technique can provide absolute temperatures, but is sensitive to kinetic isotope effects, often significantly overestimating growth temperatures of speleothems. When this thermometer was applied to calcite collected from near where the plates were impacted by drip water, it overestimated measured temperatures by 7.7 ± 4.3°C, showing moderate KIE. When applied to calcite away from the drip impact, it overestimated temperatures by 18.7 ± 4.2°C, showing KIE increasing away from the drip. Measured monthly average temperatures in the cave ranged seasonally between 8 and 28°C, and daily temperatures vary significantly. At Westcave, calcite growth rates increase with temperature, and the calcite may therefore preferentially record warmer daily or

  18. Re-Os isotopic systematics of primitive lavas from the Lassen region of the Cascade arc, California (United States)

    Borg, L.E.; Brandon, A.D.; Clynne, M.A.; Walker, R.J.


    Rhenium-osmium isotopic systematics of primitive calc-alkaline lavas from the Lassen region appear to be controlled by mantle wedge processes. Lavas with a large proportion of slab component have relatively low Re and Os abundances, and have radiogenic Os and mid ocean ridge basalt-like Sr and Pb isotopic compositions. Lavas with a small proportion of slab component have higher Re and Os elemental abundances and display mantle-like Os, Sr, Nd, and Pb isotopic compositions. Assimilation with fractional crystallization can only generate the Re-Os systematics of the Lassen lavas from a common parent if the distribution coefficient for Re in sulfide is ~40-1100 times higher than most published estimates and if most incompatible element abundances decrease during differentiation. High Re/Os ratios in mid ocean ridge basalts makes subducted oceanic crust a potential source of radiogenic Os in volcanic arcs. The slab beneath the southernmost Cascades is estimated to have 187Os/188Os ratios as high as 1.4. Mixing between a slab component and mantle wedge peridotite can generate the Os isotopic systematics of the Lassen lavas provided the slab component has a Sr/Os ratio of ~7.5X105 and Os abundances that are 100-600 times higher than mid ocean ridge basalts. For this model to be correct, Os must be readily mobilized and concentrated in the slab component, perhaps as a result of high water and HCl fugacities in this subduction environment. Another possible mechanism to account for the correlation between the magnitude of the subduction geochemical signature and Os isotopic composition involves increasing the stability of an Os-bearing phase in mantle wedge peridotites as a result of fluxing with the slab component. Melting of such a source could yield low Os magmas that are more susceptible to crustal contamination, and hence have more radiogenic Os isotopic compositions, than magmas derived from sources with a smaller contribution from the slab. Thus, the addition of the

  19. Systematic of Nuclear Ground State Properties in Sr Isotope by Covariant Density Functional Theory

    Institute of Scientific and Technical Information of China (English)

    TIAN; Yuan


    <正>The hyperfine structure and isotope shifts of Sr-isotopes, both even-even and odd-even nuclei, are studied in the covariant density functional theory (DFT) with the new parameter set DD-PC1. Pairing correlation is treated by using the Bogoliubov with a separable form of the pairing interaction. Spin-parity,

  20. IODP Expedition 345: Characterizing Hydrothermal Alteration of Fast-Spreading EPR Lower Crust using O, Sr and Nd isotopics (United States)

    Marks, N.; Gillis, K. M.; Lindvall, R. E.; Schorzman, K.


    The Integrated Ocean Drilling Program (IODP) Expedition 345 sampled lower crustal primitive gabbroic rocks that formed at the fast-spreading East Pacific Rise (EPR) and are exposed at the Hess Deep Rift. The metamorphic mineral assemblages in the rocks recovered at Site U1415 record the cooling of primitive gabbroic lithologies from magmatic (>1000°C) to zeolite facies conditions (exposure onto the seafloor. The dominant alteration assemblage is characterized by lower grade greenschist (talc, serpentine, or clay minerals, and is commonly accompanied by prehnite microveins in plagioclase. The intensity of alteration varies with igneous lithology, in particular, the modal abundance of olivine, as well as proximity to zones of brittle fracturing and cataclasis. We have attempted to characterize the nature and extent of isotopic exchange associated alteration and cooling and present a record of variations in O, Sr, and Nd isotopic compositions in altered rocks from the lower plutonic crust at Hess Deep. The Rb-Sr and 18O/16O systems exhibit sensitivity to hydrothermal interactions with seawater; whereas the Sm-Nd system appears essentially undisturbed by the minimal alteration experienced by the rocks drilled at Site U1415. The 87Sr/86Sr isotopic compositions of olivine gabbros (Mg# 0.81-0.89) range from 0.702536-0.703950 (±0.000008). Higher 87Sr/86Sr ratios are strongly correlated with percentage of hydrous minerals, and are higher in samples with a greater modal abundance of olivine. These rocks have somewhat higher 87Sr/86Sr ratios than upper plutonic rocks from the Northern Escarpment at Hess Deep (Kirchner and Gillis, 2012), although their percentage of hydrous phases is apparently similar. The d18O in these rocks ranges from 0.23‰ to 4.65‰ (±0.67); troctolites have systematically lower d18O than the gabbro and gabbronorites. Preliminary Nd isotopic data appears to be consistent with previous measurements from the Site 894 gabbros, implying derivation from

  1. Lithium isotope systematics in a forested granitic catchment (Strengbach, Vosges Mountains, France) (United States)

    Lemarchand, Emmanuel; Chabaux, François; Vigier, Nathalie; Millot, Romain; Pierret, Marie-Claire


    Over the last decade it has become apparent that Li isotopes may be a good proxy to trace silicate weathering. However, the exact mechanisms which drive the behaviour of Li isotopes in surface environments are not totally understood and there is a need to better calibrate and characterize this proxy. In this study, we analysed the Li concentrations and isotopic compositions in the various surface reservoirs (soils, rocks, waters and plants) of a small forested granitic catchment located in the Vosges Mountains (Strengbach catchment, France, OHGE Li fluxes were calculated in both soil profiles and at the basin scale and it was found that even in this forested basin, atmospheric inputs and litter fall represented a minor flux compared to input derived from the weathering of rocks and soil minerals (which together represent a minimum of 70% of dissolved Li). Li isotope ratios in soil pore waters show large depth dependent variations. Average dissolved δ 7Li decreases from -1.1‰ to -14.4‰ between 0 and -30 cm, but is +30.7‰ at -60 cm. This range of Li isotopic compositions is very large and it encompasses almost the entire range of terrestrial Li isotope compositions that have been previously reported. We interpret these variations to result from both the dissolution and precipitation of secondary phases. Large isotopic variations were also measured in the springs and stream waters, with δ 7Li varying from +5.3‰ to +19.6‰. δ 7Li increases from the top to the bottom of the basin and also covaries with discharge at the outlet. These variations are interpreted to reflect isotopic fractionations occurring during secondary phase precipitation along the water pathway through the rocks. We suggest that the dissolved δ 7Li increases with increasing residence time of waters through the rocks, and so with increasing time of interaction between waters and solids. A dissolution precipitation model was used to fit the dissolved Li isotopic

  2. Systematic study of the (n,p) and (n,n'p) reactions on titanium isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Avrigeanu, M.; Ivascu, M.; Avrigeanu, V.


    Geometry-dependent hybrid and Hauser-Feshbach model calculations were performed for (n,p), (n,n'p) and (n,2n) reaction cross-sections for stable titanium isotopes in the energy range from threshold to 20 MeV. A consistent set of input parameters was established. The single-particle level density used in the pre-equilibrium emission calculation was related to the level density parameter of the Hauser-Feshbach calculations, including its energy dependence. Consequently, lower pre-equilibrium emission fractions were obtained. Systematics of the pre-equilibrium and statistical contributions to (n,p) reaction cross-sections are analysed in connection with the isotope effect put into evidence by the titanium data.

  3. Isotopic characterization of metabasites and amphibolites of the Acungui and Setuva Groups at the southern portion of de Ribeira Belt; Caracterizacao isotopica de metabasitos e anfibolitos dos Grupos Acungui e Setuva na porcao sul da Faixa Ribeira

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Marcos Aurelio Farias de; Daitx, Elias Carneiro [Universidade Estadual Paulista (UNESP), Rio Claro, SP (Brazil). Dept. de Petrologia e Metalogenia; Maniesi, Vanderlei [Universidade Federal de Rondonia (UNIR), Porto Velho (Brazil); Teixeira, Wilson [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias. Centro de Pesquisas Geocronologicas


    Pb, Rb, Sr, Sm and Nd isotope analyses were carried out on amphibolitic rocks from Campo Largo (PR), Rio Branco do Sul (PR) and Adrianopolis (PR) and for the metabasite from Adrianopolis and Apiai (SP), all belonging to the Acungui and Setuva Groups, southern portion of the Ribeira Belt. These occurrences were chosen because each exhibits geochemical data indicative of a mantle source, having different signatures. Geochronologic determinations are available only for the Apiai metagabro with Neoproterozoic ages of 617 +- 4 Ma (U/Pb in zircon) and 839 +- 85 Ma (Rb/Sr, whole rock). Age determinations by Sm/Nd mineral isochron using whole rock, plagioclase and pyroxene yield values of 885 +- 53 Ma for the Apiai metagabro and 820 +- 84 Ma for the Adrianopolis metabasite. These results agree within error with the Rb/Sr isochron of 839 +- 85 Ma may possibly be interpreted as the time of extraction of the magma from the mantle, as suggested by positive epsilon{sub Nd(850)} values (+2,76) from an Adrianopolis sample. An epsilon{sub Nd} values versus 87 Sr/86 Sr diagram shows that each studied occurrence plots in a different position, following approximately the mantle array trend, the most primitive being the metabasite of Adrianopolis, near the MORB field, and the most enriched being the amphibolite from the same region, near the enriched mantle and or crustal contamination field. The distinct difference in isotopic signatures between the amphibolite and metabasite suggest derivation from different mantle sources, as supported by available geochemical data. Nevertheless, some of the samples show isotopic evidence of the action of metamorphism, crustal contamination and weathering. (author)

  4. New isotopic ages and the timing of orogenic events in the Cordillera Darwin, southernmost Chilean Andes (United States)

    Hervé, F.; Nelson, E.; Kawashita, K.; Suárez, M.


    The Cordillera Darwin, a structural culmination in the Andes of Tierra del Fuego, exposes an orogenic core zone that has undergone polyphase deformation and metamorphism. Some of the classic problems of orogenic zones have remained unanswered in the Cordillera Darwin: the age of deformed plutonic rocks, the distinction of structurally reactivated basement and metamorphosed cover rocks, and the timing of orogenic events. This study addresses and partially answers these questions. A well-constrained Rb-Sr isochron age of157±8m.y. and an initial 87Sr/ 86Sr ratio of 0.7087 obtained from a pre-tectonic granitic suite suggest a genetic relation between this suite and Upper Jurassic silicic volcanic rocks in the cover sequence (Tobifera Formation), and also suggest involvement of continental crust in formation of these magmas. A poorly constrained Rb-Sr isochron age of240±40m.y. obtained from supposed basement schists is consistent with field relations in the area which suggest a late Paleozoic/early Mesozoic metamorphism for these pre-Late Jurassic rocks. However, because of scatter in the data and the uncertainties involved in dating metasedimentary rocks, the significance of the isotopic age is dubious. Compilation of previously published ages in the area [9] with new mineral ages reported here indicate that "early Andean" orogenic events occurred between 100 and 84 m.y. ago, and that subduction-related magmatism has contributed, probably discontinuously, to the crustal evolution of the region throughout the Mesozoic.

  5. The Role of Accessory Phases in the Sm-Nd Isotope Systematics of the Acasta Gneiss Complex (United States)

    Bauer, A.; Fisher, C. M.; Vervoort, J. D.; Bowring, S. A.


    The Acasta Gneiss Complex (AGC) of the Slave Craton in the Northwest Territories, Canada, contains some of Earth's oldest continental crust. It is characterized by a range of compositionally diverse gneisses with crystallization ages of 3.3 to > 4.0 Ga1-5. The AGC has undergone a multistage history of metamorphism and deformation. Given these post-crystallization processes, the extent of Nd isotope heterogeneity suggested by published4-7 whole rock Sm-Nd analyses of these rocks has been called into question. Criticisms include the likelihood of mixed lithologies at the hand-sample scale and the potential for open-system behavior of the Sm-Nd isotopic system in these rocks. We obtained whole rock compositional, Sm-Nd and Lu-Hf isotope data paired with Hf in zircon and Nd in titanite and apatite data to further evaluate the isotope record, and use U-Pb and Lu-Hf of zircon as a basis for identifying mixed or complex samples. Preferential preservation of Lu-Hf over Sm-Nd isotope systematics in multiply deformed, complex rocks may be controlled by the minerals that dominate the Hf and Nd budgets, with the majority of the Hf effectively sheltered in zircon and the Nd largely hosted in accessory phases such as apatite and titanite. This composite dataset enables us to evaluate the possibility that Hf and Nd isotopic systematics have been decoupled in these samples that have such critical bearing on our understanding of early crust-forming processes. [1]Bowring and Williams (1999). CoMP, 134(1), 3-16. [2]Iizuka, T. et al. (2006) Geology, 34(4), 245-248. [3]Iizuka et al (2007). Precambrian Res, 153(3), 179-208. [4]Bowring et al. 1989. Nature, 340: 222-225. [5]Mojzsis et al. (2014). GCA, 133, 68-96. [6]Bowring and Housh (1995) Science 269, 1535-1540. [7]Moorbath et al (1997) Chem. Geol. 135, 213-231.

  6. Oxygen isotope systematics of chondrules in the Allende CV3 chondrite: High precision ion microprobe studies

    Digital Repository Service at National Institute of Oceanography (India)

    Rudraswami, N.G.; Ushikubo, T.; Nakashima, D.; Kita, N.T.

    chondrules range from -5 ppt to 0 ppt, indicating that not all BO chondrules plot near the terrestrial fractionation line as suggested by previous bulk chondrule analyses. Based on these data, we suggest the presence of multiple oxygen isotope reservoirs...

  7. Sr isotope evolution during chemical weathering of granites -- impact of relative weathering rates of minerals

    Institute of Scientific and Technical Information of China (English)

    MA; Yingjun


    [1]Ma, Y. J., Liu, C. Q., Geochemistry of strontium isotopes in the crust weathering system, Acta Mineralogica Sinica (in Chinese), 1998, 18(3): 350.[2]Ma, Y. J., Liu, C. Q., Using strontium isotopes to trace nutrient element circulation and hydrochemical evolution within an ecosystem, Advance in Earth Sciences (in Chinese), 1999, 14 (4): 377.[3]Brantley, S. L., Chesley, J. T., Stillings, L. L., Isotopic ratios and release rates of strontium from weathering feldspars, Geochim. Cosmochim. Acta, 1998, 62(9): 1493.[4]Blum, J. D., Erel, Y., A silicate weathering mechanism linking increases in marine 87Sr/86Sr with global glaciation, Nature, 1995, 373: 415.[5]Blum, J. D., Erel, Y., Rb-Sr isotope systematics of granitic soil chronosequence: The importance of biotite weathering, Geochim. Cosmochim. Acta, 1997, 61(15): 3193.[6]Bullen, T., Krabbenhoft, D., Kendall, C., Kinetic and mineralogic controls on the evolution of groundwater chemistry and 87Sr/86Sr in a sandy silicate aquifer, northern Wisconsin, USA, Geochim. Cosmochim. Acta, 1996, 60: 1807.[7]Bullen, T., White, A., Blum, A. et al., Chemical weathering of a soil chronosequence on granitoid alluvium: Ⅱminer-alogic and isotopic constraints on the behavior of strontium, Geochim. Cosmochim. Acta, 1997, 61: 291.[8]Blum, J. D., Erel, Y., Brown, K., 87Sr/86Sr ratios of Sierra Nevada stream waters: Implications for relative mineral weath-ering rates, Geochim. Cosmochim. Acta, 1993, 57: 5019.[9]Ma Yingjun, Trace element and strontium isotope geochemistry during chemical weathering, Ph. D. Dissertation, 1999, Institute of Geochemistry, Chinese Academy of Sciences.[10]Nesbitt, H. W., Markovics, G., Price, R. C., Chemical processes affecting alkalis and alkaline earths during continental weathering, Geochim. Cosmochim. Acta, 1980, 44: 1659.[11]Clauer, N., Strontium and argon isotopes in naturally weathered biotites, muscovites and feldspars, Chem. Geol., 1981, 31: 325.[12

  8. Zn and Ni Isotope Systematics in the Black Sea, an Analogue for Past Ocean Anoxia (United States)

    Little, S. H.; Vance, D.; Cameron, V.; Rijkenberg, M. J. A.; Andersen, M. B.; Lyons, T. W.


    Organic rich sediments, indicators of low bottom water oxygen, are often enriched in trace metals. Their concentrations in such sediments are thus used to probe past Earth surface conditions. Enrichment mechanisms are difficult to distinguish from concentrations alone, however. A range of processes fractionate metal stable isotopes, offering the potential to unpick these controls. The Black Sea is the classic modern analogue for past euxinia. Deep euxinic waters (dissolved sulfide ≤380mM) underlie a surface oxic layer and redoxcline at 80-250m. It is an ideal starting point to explore the behaviour of metal stable isotopes in low oxygen conditions. We report water column and sedimentary Zn and Ni data. A maximum in dissolved Zn (~3nM) occurs at the upper boundary of the redoxcline, probably reflecting cellular uptake above and sulfide co-precipitation below. Water column dissolved Ni concentrations remain within a narrow range throughout (9-12nM), with subtle variations in the redoxcline associated with Fe-Mn cycling and interaction with sulfide. Significant Zn and Ni isotopic variation (ca 1.5‰) is observed associated with these concentration variations. In the strongly sulfidic deep waters, Zn and Ni are homogeneous and isotopically heavy: [Zn] = 0.40 ± 0.05nM, δ66Zn = 0.96 ± 0.05‰, [Ni] = 10.7 ± 0.7nM, δ58Ni = 1.86 ± 0.16‰ (n=6, 1sd), suggesting preferential removal of light isotopes to the particulate phase. Sediments underlying oxic waters show no authigenic enrichment and isotope ratios close to crustal values (δ60Ni ~ 0.2‰, δ66Zn ~ 0.3‰). In contrast, Ni and Zn are enriched in sediments underlying the euxinic portion of the water column (by factors of 2-3). Authigenic Ni isotope values are light (δ60Niauth = 0.30 ± 0.21‰, n=13, 1sd) compared to the deep Black Sea water column, consistent with removal of light isotopes to the particulate phase. This may reflect sorption to Mn oxides, or co-precipitation with sulfide. Authigenic Zn

  9. Sr-O isotope systematics in the Campi Flegrei magma systems (United States)

    Wörner, Gerhard; Iovine, Raffaella; Carmine Mazzeo, Fabio; D'Antonio, Massimo; Arienzo, Ilenia; Civetta, Lucia; Orsi, Giovanni


    Combined radiogenic Sr- and stable O-isotopes are a powerful tool to distinguish between (a) contamination of mantle magma sources by fluids and subducted sediment and (b) assimilation of magmas during ascent through the crust. Advance in laser fluorination mass spectrometry permits to measure small samples and single mineral grains. This allows to directly link Sr- and O-isotope measurements practically for the same sample material. Although isotopic heterogeneity remains a problem even at this level, this approach avoids problems of weathering and mineral-melt disequilibria. We analysed mineral separates (feldspar, Fe-cpx, Mg-cpx, magnetite, olivine) from 37 samples covering the stratigraphic sequence of the Campi Flegrei volcanic field: Pre-Campanian Ignimbrite (Pre CI; >39.28 ka), Campanian Ignimbrite (CI; 39.28 ka), Post Campanian Ignimbrite/Pre Neapolitan Yellow Tuff (Post CI/pre NYT; 14.90 ka), Neapolitan Yellow Tuff (NYT; 14.90 ka), and Post-Neapolitan Yellow Tuff (Post NYT; 12.8 ka-1538 A.D.) deposits. Sr isotopic compositions were determined using standard cation-exchange methods on separated hand-picked feldspar, clinopyroxene and olivine phenocrysts (~300mg) and on whole rocks, in case of not enough amount of crystals. By infrared laser fluorination was, instead, measured the oxygen isotopic composition of ~0.3 mg of hand-picked phenocrysts. Recalculating measured mineral O-isotope values to magmatic values to account for mineral-melt 18O/16O-fractionation at various SiO2-contens of the melt should provide a data set that better constrains magma isotope compositions and magma sources. Sr-isotopes span a range from 0.7069 to 0.7082 that exceed the variations in the bulk rock samples (0.7071-0.7081). However, these ranges vary significantly between eruptive periods. For example the Sr-isotope variation in the Neapolitan Yellow Tuff is only between 0.70750 and 0.70754 for minerals and whole rocks. Similarly, recalculated δ18O-melt values show a large

  10. Open system models of isotopic evolution in Earth's silicate reservoirs: Implications for crustal growth and mantle heterogeneity (United States)

    Kumari, Seema; Paul, Debajyoti; Stracke, Andreas


    An open system evolutionary model of the Earth, comprising continental crust (CC), upper and lower mantle (UM, LM), and an additional isolated reservoir (IR) has been developed to study the isotopic evolution of the silicate Earth. The model is solved numerically at 1 Myr time steps over 4.55 Gyr of Earth history to reproduce both the present-day concentrations and isotope ratios of key radioactive decay systems (Rb-Sr, Sm-Nd, and U-Th-Pb) in these terrestrial reservoirs. Various crustal growth scenarios - continuous versus episodic and early versus late crustal growth - and their effect on the evolution of Sr-Nd-Pb isotope systematics in the silicate reservoirs have been evaluated. Modeling results where the present-day UM is ∼60% of the total mantle mass and a lower mantle that is non-primitive reproduce the estimated geochemical composition and isotope ratios in Earth's silicate reservoirs. The isotopic evolution of the silicate Earth is strongly affected by the mode of crustal growth; only an exponential crustal growth pattern with crustal growth since the early Archean satisfactorily explains the chemical and isotopic evolution of the crust-mantle system and accounts for the so-called Pb paradoxes. Assuming that the OIB source is located in the deeper mantle, our model could, however, not reproduce its target ɛNd of +4.6 for the UM, which has been estimated from the average isotope ratios of 32 individual ocean island localities. Hence, either mantle plumes sample the LM in a non-representative way, or the simplified model set-up does not capture the full complexity of Earth's lower mantle (Nd isotope) evolution. Compared to the results obtained for a 4.55 Ga Earth, a model assuming a protracted U-Pb evolution of silicate Earth by ca. 100 Myr reproduces a slightly better fit for the Pb isotope ratios in Earth's silicate reservoirs. One notable feature of successful models is the early depletion of incompatible elements (as well as rapid decrease in Th/U) in

  11. Independent isotopic yields in 25 MeV and 50 MeV proton-induced fission of {sup nat}U

    Energy Technology Data Exchange (ETDEWEB)

    Penttilae, H.; Gorelov, D.; Elomaa, V.V.; Eronen, T.; Hager, U.; Hakala, J.; Jokinen, A.; Kankainen, A.; Karvonen, P.; Moore, I.D.; Parkkonen, J.; Pohjalainen, I.; Rahaman, S.; Rinta-Antila, S.; Rissanen, J.; Saastamoinen, A.; Simutkin, V.; Sonoda, T.; Weber, C.; Voss, A.; Aeystoe, J. [Department of Physics, University of Jyvaskylae (Finland); Peraejaervi, K. [STUK - Radiation and Nuclear Safety Authority, Helsinki (Finland); Rubchenya, V.A. [Department of Physics, University of Jyvaskylae (Finland); V.G. Khlopin Radium Institute, St. Petersburg (Russian Federation)


    Independent isotopic yields for elements from Zn to La in the 25 MeV proton-induced fission of {sup nat}U were determined with the JYFLTRAP facility. In addition, isotopic yields for Zn, Ga, Rb, Sr, Zr, Pd and Xe in the 50 MeV proton-induced fission of {sup nat}U were measured. The deduced isotopic yield distributions are compared with a Rubchenya model, the GEF model with universal parameters and the semi-empirical Wahl model. Of these, the Rubchenya model gives the best overall agreement with the obtained data. Combining the isotopic yield data with mass yield data to obtain the absolute independent yields was attempted. The result depends on the mass yield distribution. (orig.)

  12. A Systematic Regional Trend in Helium Isotopes Across the NorthernBasin and Range Province, Western North America

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, B. Mack; van Soest, Matthijs C.


    An extensive study of helium isotopes in fluids collectedfrom surface springs, fumaroles and wells across the northern Basin andRange Province reveals a systematic trend of decreasing 3He/4He ratiosfrom west to east. The western margin of the Basin and Range ischaracterized by mantle-like ratios (6-8 Ra) associated with active orrecently active crustal magma systems (e.g. Coso, Long Valley, Steamboat,and the Cascade volcanic complex). Moving towards the east, the ratiosdecline systematically to a background value of ~;0.1 Ra. The regionaltrend is consistent with extensive mantle melting concentrated along thewestern margin and is coincident with an east-to-west increase in themagnitude of northwest strain. The increase in shear strain enhancescrustal permeability resulting in high vertical fluid flow rates thatpreserve the high helium isotope ratios at the surface. Superimposed onthe regional trend are "helium spikes", local anomalies in the heliumisotope composition. These "spikes" reflect either local zones of mantlemelting or locally enhanced crustal permeability. In the case of theDixie Valley hydrothermal system, it appears to be a combination ofboth.

  13. Study on strontium isotope abundance-ratio measurements by using a 13-MeV proton beam (United States)

    Jeong, Cheol-Ki; Jang, Han; Lee, Goung-Jin


    The Rb-Sr dating method is used in dating Paleozoic and Precambrian rocks. This method measures the 87Rb and the 87Sr concentrations by using thermal ionization mass spectrometry (TIMS) [J. Hefne et al., Inter. J. Phys. Sci. 3(1), 28 (2008)]. In addition, it calculates the initial 87Sr/86Sr ratio to increase the reliability of Rb-Sr dating. In this study, the 87Sr/86Sr ratio was measured by using a 13-MeV proton accelerator. Proton kinetic energies are in the range of tens of megaelectronvolts, and protons have large absorption cross-sections for ( p, n) reactions with most substances. After absorbing a proton with such a high kinetic energy, an element is converted into a nuclide with its atomic number increased by one via nuclear transmutation. These nuclides usually have short half-lives and return to the original state through radioactive decay. When a strontium sample is irradiated with protons, nuclear transmutation occurs; thus, the strontium isotope present in the sample changes to a yttrium isotope, which is an activated radioisotope. Based on this, the 87Sr/86Sr ratio was calculated by analyzing the gamma-rays emitted by each yttrium isotope. The KIRAMS-13 cyclotron at the Cyclotron Center of Chosun University, where 13-MeV protons can be extracted, was utilized in our experiment. The 87Sr/86Sr isotope ratio was computed for samples irradiated with these protons, and the result was similar to the isotope ratio for the Standard Reference Material, i.e., 98.2 ± 3.4%. As part of the analysis, proton activation analyses were performed using 13-MeV protons, and the experimental results of this research suggest a possible approach for measuring the strontium-isotope abundance ratio of samples.

  14. Lead isotope systematics of some igneous rocks from the Egyptian Shield (United States)

    Gillespie, J. G.; Dixon, T. H.


    Lead isotope data on whole-rock samples and two feldspar separates for a variety of Pan-African (late Precambrian) igneous rocks for the Egyptian Shield are presented. It is pointed out that the eastern desert of Egypt is a Late Precambrian shield characterized by the widespread occurrence of granitic plutons. The lead isotope ratios may be used to delineate boundaries between Late Precambrian oceanic and continental environments in northeastern Africa. The samples belong to three groups. These groups are related to a younger plutonic sequence of granites and adamellites, a plutonic group consisting of older tonalites to granodiorites, and the Dokhan volcanic suite.

  15. Chromium stable isotope systematic – implications for the redox evolution of the earth

    DEFF Research Database (Denmark)

    Døssing, Lasse Nørbye

    The isotopic composition of chromium (Cr) holds great promise as a paleo-redox proxy.Whereas the reduction of oxidized Cr(VI) to Cr(III) yields a well-defined kineticfractionation, the fractionation imparted during oxidative weathering is only described theoretically. This thesis demonstrates...

  16. Tracking seasonal subglacial drainage evolution of alpine glaciers using radiogenic Nd and Sr isotope systematics: Lemon Creek Glacier, Alaska (United States)

    Clinger, A. E.; Aciego, S.; Stevenson, E. I.; Arendt, C. A.


    The transport pathways of water beneath a glacier are subject to change as melt seasons progress due to variability in the balance between basal water pressure and water flux. Subglacial hydrology has been well studied, but the understanding of spatial distribution is less well constrained. Whereas radiogenic isotopic tracers have been traditionally used as proxies to track spatial variability and weathering rates in fluvial and riverine systems, these techniques have yet to be applied extensively to the subglacial environment and may help resolve ambiguity in subglacial hydrology. Research has shown the 143Nd/144Nd values can reflect variation in source provenance processes due to variations in the age of the continental crust. Correlating the 143Nd/144Nd with other radiogenic isotope systematics such as strontium (87Sr/86Sr) provides important constraints on the role of congruent and incongruent weathering processes. Our study presents the application of Nd and Sr systematics using isotopic ratios to the suspended load of subglacial meltwater collected over a single melt season at Lemon Creek Glacier, USA (LCG). The time-series data show an average ɛNd ~ -6.83, indicating a young bedrock (~60 MYA). Isotopic variation helps track the seasonal expansion of the subglacial meltwater channels and subsequent return to early season conditions due to the parabolic trend towards less radiogenic Nd in June and towards more radiogenic Nd beginning in mid-August. However, the high variability in July and early August may reflect a mixture of source as the channels diverge and derive sediment from differently aged lithologies. We find a poor correlation between 143Nd/144Nd and 87Sr/86Sr (R2= 0.38) along with a slight trend towards more radiogenic 87Sr/86Sr values with time ((R2= 0.49). This may indicate that, even as the residence time decreases over the melt season, the LCG subglacial system is relatively stable and that the bedrock is congruently weathered. Our study

  17. The Early Differentiation History of Mars from W-182-Nd-142 Isotope Systematics in the SNC Meteorites (United States)

    Foley, C. Nicole; Wadhwa, M.; Borg, L. E.; Janney, P. E.; Hines, R.; Grove, T. L.


    We report here the results of an investigation of W and Nd isotopes in the SNC (Shergottite-Nakhlite-Chassignite (martian)) meteorites. We have determined that epsilon W-182 values in the nakhlites are uniform within analytical uncertainties and have an average value of approx. 3. Also, while epsilon W-182 values in the shergottites have a limited range (from 0.3-0.7), their epsilon Nd-142 values vary considerably (from -0.2-0.9). There appears to be no correlation between epsilon W-182 and epsilon Nd-142 in the nakhlites and shergottites. These results shed new light on early differentiation processes on Mars, particularly on the timing and nature of fractionation in silicate reservoirs. Assuming a two-stage model, the metallic core is estimated to have formed at approx. 12 Myr after the beginning of the solar system. Major silicate differentiation established the nakhlite source reservoir before approx. 4542 Ma and the shergottite source reservoirs at 4525 [sup +19 sub -21] Ma. These ages imply that, within the uncertainties afforded by the Hf-182-W-182 and Sm-146-Nd-142 chronometers, the silicate differentiation events that established the source reservoirs of the nakhlites and shergottites may have occurred contemporaneously, possibly during crystallization of a global magma ocean. The distinct W-182-Nd-142 isotope systematics in the nakhlites and the shergottites imply the presence of at least three isotopically distinct silicate reservoirs on Mars, two of which are depleted in incompatible lithophile elements relative to chondrites, and the third is enriched. The two depleted silicate reservoirs most likely reside in the Martian mantle, while the enriched reservoir could be either in the crust or the mantle. Therefore, the W-182-Nd-142 isotope systematics indicate that the nakhlites and the shergottites originated from distinct source reservoirs and cannot be petrogenetically related. A further implication is that the source reservoirs of the nakhlites and

  18. Single crystal U–Pb zircon age and Sr–Nd isotopic composition of impactites from the Bosumtwi impact structure, Ghana: Comparison with country rocks and Ivory Coast tektites (United States)

    Ferrière, Ludovic; Koeberl, Christian; Thöni, Martin; Liang, Chen


    The 1.07 Myr old Bosumtwi impact structure (Ghana), excavated in 2.1–2.2 Gyr old supracrustal rocks of the Birimian Supergroup, was drilled in 2004. Here, we present single crystal U–Pb zircon ages from a suevite and two meta-graywacke samples recovered from the central uplift (drill core LB-08A), which yield an upper Concordia intercept age of ca. 2145 ± 82 Ma, in very good agreement with previous geochronological data for the West African Craton rocks in Ghana. Whole rock Rb–Sr and Sm–Nd isotope data of six suevites (five from inside the crater and one from outside the northern crater rim), three meta-graywacke, and two phyllite samples from core LB-08A are also presented, providing further insights into the timing of the metamorphism and a possibly related isotopic redistribution of the Bosumtwi crater rocks. Our Rb–Sr and Sm–Nd data show also that the suevites are mixtures of meta-greywacke and phyllite (and possibly a very low amount of granite). A comparison of our new isotopic data with literature data for the Ivory Coast tektites allows to better constrain the parent material of the Ivory Coast tektites (i.e., distal impactites), which is thought to consist of a mixture of metasedimentary rocks (and possibly granite), but with a higher proportion of phyllite (and shale) than the suevites (i.e., proximal impactites). When plotted in a Rb/Sr isochron diagram, the sample data points (n = 29, including literature data) scatter along a regression line, whose slope corresponds to an age of 1846 ± 160 Ma, with an initial Sr isotope ratio of 0.703 ± 0.002. However, due to the extensive alteration of some of the investigated samples and the lithological diversity of the source material, this age, which is in close agreement with a possible “metamorphic age” of ∼ 1.8–1.9 Ga tentatively derived from our U–Pb dating of zircons, is difficult to consider as a reliable metamorphic age. It may perhaps reflect a common ancient source

  19. SIMS zircon ages and Nd isotope systematics of the 2.2 Ga mafic intrusions in northern and eastern Finland

    Directory of Open Access Journals (Sweden)

    Eero Hanski


    Full Text Available Using the SIMS, ID-TIMS and Sm-Nd isotopic methods and the electron microprobe, we have studied several differentiated mafic intrusions of the c. 2.2 Ga gabbro-wehrlite association (GWA from four Paleoproterozoic schist belts and the Archean Kuhmo Greenstone Belt. Back-scattered electron images and electron microprobe analyses revealed that zircon crystals vary from well-preserved to turbid and highly altered with individual grains often displaying irregular, hydrated, CaO-bearing domains. In the most pristine domains, suitable for establishing the crystallization ages, SIMS 207Pb/206Pb ages fall in the range of 2210–2220 Ma, which is consistent with the most concordant ID-TIMS UPb ages. One of the studied intrusions that had previously yielded a conventional U-Pb date of less than 2.0 Ga, could be shown by spot analysis to belong to the 2.2 Ga family. In contrast to the well-preserved zircon domains, altered domains exhibit a variable and often strong U-Pb discordance up to 70 % and have distinctly lower 207Pb/206Pb ages. Some zircon grains record isotopic resetting at the time of the Svecofennian orogeny(ca. 1.8–1.9 Ga, while the most discordant ones project in the concordia diagram to late Paleozoic lower intercept ages indicating a relative recent Pb loss. The mineral chemistry of zircon suggests that the leakage of radiogenic Pb can be ascribed to an opensystembehavior related to hydrothermal alteration via action of CaCl2-bearing fluids.Common albitization of plagioclase in the GWA intrusions has caused this mineral to behave as an open system with regard to the Sm-Nd isotopic systematics. Despite this uncertainty, our Nd isotopic data indicate that the magma that produced the GWA intrusions in various parts of northern and eastern Finland was isotopically homogeneousand had an initial εNd(2220 Ma value of c. +0.6 precluding significant upper crustal contamination upon emplacement and subsequent fractional crystallization.

  20. Systematic study of heavy cluster emission from {210-226}^Ra isotopes

    CERN Document Server

    Santhosh, K P; Priyanka, B; Unnikrishnan, M S


    The half lives for various clusters lying in the cold reaction valleys of {210-226}^Ra isotopes are computed using our Coulomb and proximity potential model (CPPM). The computed half lives of 4^He and 14^C clusters from {210-226}^Ra isotopes are in good agreement with experimental data. Half lives are also computed using the Universal formula for cluster decay (UNIV) of Poenaru et al., and are found to be in agreement with CPPM values. Our study reveals the role of doubly magic 208^Pb daughter in cluster decay process. Geiger - Nuttall plots for all clusters up to 62^Fe are studied and are found to be linear with different slopes and intercepts. {12,14}^C emission from 220^Ra; 14^C emission from {222,224}^Ra; 14^C and 20^O emission from 226^Ra are found to be most favourable for measurement and this observation will serve as a guide to the future experiments.

  1. Systematic investigation of projectile fragmentation using beams of unstable B and C isotopes

    CERN Document Server

    Thies, R; Adachi, T; Aksyutina, Y; Alcantara-Núñes, J; Altstadt, S; Alvarez-Pol, H; Ashwood, N; Aumann, T; Avdeichikov, V; Barr, M; Beceiro-Novo, S; Bemmerer, D; Benlliure, J; Bertulani, C A; Boretzky, K; Borge, M J G; Burgunder, G; Caamano, M; Caesar, C; Casarejos, E; Catford, W; Cederkäll, J; Chakraborty, S; Chartier, M; Chulkov, L V; Cortina-Gil, D; Crespo, R; Datta, U; Fernández, P Díaz; Dillmann, I; Elekes, Z; Enders, J; Ershova, O; Estradé, A; Farinon, F; Fraile, L M; Freer, M; Freudenberger, M; Fynbo, H O U; Galaviz, D; Geissel, H; Gernhäuser, R; Göbel, K; Golubev, P; Diaz, D Gonzalez; Hagdahl, J; Heftrich, T; Heil, M; Heine, M; Henriques, A; Holl, M; Ickert, G; Ignatov, A; Jakobsson, B; Johansson, H T; Jonson, B; Kalantar-Nayestanaki, N; Kanungo, R; Kelic-Heil, A; Knöbel, R; Kröll, T; Krücken, R; Kurcewicz, J; Kurz, N; Labiche, M; Langer, C; Bleis, T Le; Lemmon, R; Lepyoshkina, O; Lindberg, S; Machado, J; Marganiec, J; Maroussov, V; Mostazo, M; Movsesyan, A; Najafi, A; Nilsson, T; Nociforo, C; Panin, V; Paschalis, S; Perea, A; Petri, M; Pietri, S; Plag, R; Prochazka, A; Rahaman, A; Rastrepina, G; Reifarth, R; Ribeiro, G; Ricciardi, M V; Rigollet, C; Riisager, K; Röder, M; Rossi, D; del Rio, J Sanchez; Savran, D; Scheit, H; Simon, H; Sorlin, O; Stoica, V; Streicher, B; Taylor, J T; Tengblad, O; Terashima, S; Togano, Y; Uberseder, E; Van de Walle, J; Velho, P; Volkov, V; Wagner, A; Wamers, F; Weick, H; Weigand, M; Wheldon, C; Wilson, G; Wimmer, C; Winfield, J S; Woods, P; Yakorev, D; Zhukov, M V; Zilges, A; Zuber, K


    Background: Models describing nuclear fragmentation and fragmentation-fission deliver important input for planning nuclear physics experiments and future radioactive ion beam facilities. These models are usually benchmarked against data from stable beam experiments. In the future, two-step fragmentation reactions with exotic nuclei as stepping stones are a promising tool to reach the most neutron-rich nuclei, creating a need for models to describe also these reactions. Purpose: We want to extend the presently available data on fragmentation reactions towards the light exotic region on the nuclear chart. Furthermore, we want to improve the understanding of projectile fragmentation especially for unstable isotopes. Method: We have measured projectile fragments from 10,12-18C and 10-15B isotopes colliding with a carbon target. These measurements were all performed within one experiment, which gives rise to a very consistent dataset. We compare our data to model calculations. Results: One-proton removal cross sec...

  2. Pb, Nd, Sr and Os isotopic systematics of Brazilian cretaceous potassic rocks

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Ana Lucia Novaes; Sichel, Susanna Eleonora [Universidade Federal Fluminense, Niteroi, RJ (Brazil). Inst. de Geociencias. Laboratorio de Geologia Marinha (LAGEMAR)]. E-mail:; Gaspar, Jose Carlos; Costa, Vicente Sergio [Brasilia Univ., DF (Brazil). Inst. de Geociencias; Carlson, Richard Walter [Carnegie Institution of Washington, Washington, DC (United States). DTM; Teixeira, Noevaldo Araujo [NTX Consultoria, Brasilia, DF (Brazil)


    Mafic potassic rocks of the Alto Paranaiba (Minas Gerais), Juina (Mato Grosso), and Pimenta BUeno (Mato Grosso) belong to a large lineament of rocks that crosses from western to southeastern Brazil and have been associated to a hot spot track by several authors. These provinces intruded the Neoproterozoic Brasilia and Paraguay fold belts (Alto Paranaiba, Paranatinga), and the Mesoproterozoic Rio Negro-Jurema belt (Juina, Pimenta Vueno). Pb isotopic compositions of the studied provinces show a wide variation. {sup 206} Pb/{sup 204} Pb of kimberlites (18.47-19.23) and kamafugities (17.79-18.71) from the Alto Paranaiba Province are close to the Tristaan/Walvis Ridge composition. The {sup 206} Pb/{sup 204} Pb of the paranatinga (19.38-19.87) and Pimenta Bueno (19.78-21.00) provinces are similar to the South African Group I Kimberlite compositional fields, while Juina is displaced to higher Pb isotopic ratios (, close to those shown ny HIMU ocean island +(OIB).Although the Pb isotopic composition of the more northern alkalic provinces ranges towards the values seen for HIMU OIB, the Sr andNd isotopic composition of these samples is not like HIMU, nor in combination with Pb, like any other ocean island basalt. With the exception of the limberlites from the Alto Paranaiba, which range to quite unradiogenic compositions, most of the samples have {sup 187} Os/{sup 188} Os between 0.13 and 0.15. The Nd model ages of Juina kimberlites vary from 1.70-1.73 Ga, and could be indicating a prior accretion period into the mobile belt. Nd model ages for paranatinga kimberlites vary between 0.56 and 0.64 Ga and Pimenta Bueno kimberlites from 0.72 to 1.05 Ga. Minimum Re depletion model ages for Paranatinga kimberlites vary between 0.74 and 0.93 and Pimenta Bueno kimberlites from 0.9 to 1.3 Ga, indicating that the Nd isotopic signartures could have been affected by metasomatic overprint in Neoroterozoic. (author)

  3. Coupled Pb isotopic and trace element systematics of the Tissint meteorite: Geochemical signatures of the depleted shergottite source mantle (United States)

    Moriwaki, Ryota; Usui, Tomohiro; Simon, Justin I.; Jones, John H.; Yokoyama, Tetsuya; Tobita, Minato


    The application of Martian meteorite U-Th-Pb isotope systematics to track the geochemical evolution of the Martian mantle has had limited success because of the difficulty in discriminating an indigenous magmatic Pb component from secondary near-surface components that have additionally been overprinted by terrestrial contamination. To mitigate this challenge, a successive acid-leaching experiment was conducted on the Tissint meteorite, the freshest, witnessed fall of a primitive, olivine-bearing Martian basalt. Trace element concentration analyses of acid leachates and residues indicate that secondary terrestrial contaminants were effectively removed by the early steps in the leaching experiments and that the acid residues contain pristine Pb from Tissint. The acid residue, which shows the most depleted REE signature, also has the least radiogenic Pb isotopic composition (206Pb/204Pb = 10.948, 207Pb/204Pb = 11.187, 208Pb/204Pb = 30.228). A two-stage mantle evolution model based on this composition indicates that the Tissint mantle has the lowest μ-value (238U/204Pb = 1.62 ± 0.09) among the shergottite sources.

  4. Hafnium isotope variations in oceanic basalts (United States)

    Patchett, P. J.; Tatsumoto, M.


    Hafnium isotope ratios generated by the beta(-) decay of Lu-176 are investigated in volcanic rocks derived from the suboceanic mantle. Hf-176/Hf-177 and Lu/Hf ratios were determined to precisions of 0.01-0.04% and 0.5%, respectively, by routine, low-blank chemistry. The Hf-176/Hf-177 ratio is found to be positively correlated with the Nd-143/Nd-144 ratio and negatively correlated with the Sr-87/Sr-86 and Pb-206/Pb-204 ratios, and to increase southwards along the Iceland-Reykjanes ridge traverse. An approximate bulk earth Hf-176/Hf-177 ratio of 0.28295 is inferred from the bulk earth Nd-143/Nd-144 ratio, which requires a bulk earth Lu/Hf ratio of 0.25, similar to the Juvinas eucrite. Midocean ridge basalts are shown to account for 60% of the range of Hf isotope ratios, and it is suggested that Lu-Hf fractionation is decoupled from Sm-Nd and Rb-Sr fractionation in very trace-element-depleted source regions as a result of partial melting.

  5. Determination of the geographic origin of rice by chemometrics with strontium and lead isotope ratios and multielement concentrations. (United States)

    Ariyama, Kaoru; Shinozaki, Miyuki; Kawasaki, Akira


    The objective of this study was to develop a technique for determining the country of origin of rice in the Japanese market. The rice samples included a total of 350 products grown in Japan (n = 200), the United States (n = 50), China (n = 50), and Thailand (n = 50). In this study, (87)Sr/(86)Sr and Pb isotope ((204)Pb, (206)Pb, (207)Pb, and (208)Pb) ratios and multielement concentrations (Al, Fe, Co, Ni, Cu, Rb, Sr, and Ba) were determined by high-resolution inductively coupled plasma mass spectrometry. By combining three chemometric techniques based on different principles and determination criteria, the countries of origin of rice were determined. The predictions made by 10-fold cross-validation were around 97% accurate. The presented method demonstrated the effectiveness of determining the geographic origin of an agricultural product by combining several chemometric techniques using heavy element isotope ratios and multielement concentrations.

  6. Sr, Ca, and C isotope systematic in small tropical catchments, La Selva, Costa Rica (United States)

    Wiegand, B. A.; Schwendenmann, L.


    Sr, Ca, and C isotopes were analyzed to assess sources and biogeochemical processes affecting surface and groundwater composition of four small catchments located at La Selva Biological Station, Costa Rica. 87Sr/86Sr ratios were employed to quantify inputs from mineral weathering and atmospheric sources. δ13C values of dissolved organic carbon (DOC) and δ44Ca values provide information on biological processes that affect water chemistry. Sr2+ and Ca2+ concentrations of surface and groundwater show large variations due to intermixture of bedrock groundwater with local groundwater [1]. Low 87Sr/86Sr ratios suggest weathering of volcanic rocks as the primary solute source in bedrock groundwater, while atmospheric and in situ weathering contributions are predominant in local groundwater. Contributions of bedrock groundwater constitute > 60 % in the Salto, Saltito and Arboleda catchments, whereas the Taconazo catchment receives atmospheric inputs of > 95 % in addition to local weathering contributions. Surface water and groundwater wells show δ13C-DOC values between -24 ‰ and -30 ‰ due to transfer of organic carbon from the soil zone. δ44Ca values of dissolved Ca2+ in surface and groundwater are considerably fractionated from the input sources rainwater and bedrock groundwater. Light δ44Ca values are preferentially distributed in stream water and shallow groundwater horizons and contrast with heavy Ca isotopes in deeper groundwater wells. Biological processes including plant uptake and decomposition in combination with cation exchange processes in the soils may explain the fractionation of Ca isotopes. [1]Genereux et al., 2009. Water Resour. Res, 45, W08413, doi:10.1029/2008WR007630

  7. Surface water?groundwater interactions in an alluvial plain: Chemical and isotopic systematics (United States)

    Négrel, Ph.; Petelet-Giraud, E.; Barbier, J.; Gautier, E.


    Our work on the Loire River forms part of a French National Research Program dedicated to wetlands and aims to better understand the global functioning of the system from the hydrological, geochemical, ecological and sociological aspects. The present study, using a coupled hydrological and geochemical (stable and Sr isotopes) approach, focuses on the 'Soulangy' site with its secondary anastomosing channels just below the confluence of the Loire and Allier rivers, and also on the 'Dorna``nt' site with two unconnected oxbow lakes 50 km upstream of the confluence. The stable isotopes of water ( δ18O, δ2H) show that the alluvial (or riverbank) aquifer feeds the Loire River during the summer, but is not recharged by the river during flood periods in the winter; the alluvial groundwater thus has a purely local origin from precipitation. The major elements reveal an anthropogenic input of Cl and more importantly of NO 3, especially near farms. The 87Sr/ 86Sr isotopes identify different groundwater layers in the alluvium, i.e. an upper and a lower alluvial aquifer, and a perched aquifer at Dornant, that have relatively complex relationships with the surface water. The two main rivers (Loire and Allier) present distinct geochemical characteristics reflecting the different lithologies that they drain upstream. In addition, the secondary channels, lying parallel to the Loire main stream at the Soulangy site, give different geochemical signatures, which shows that they are not fed by the same overflows of the Loire; they are more-or-less well connected to the upper level of the alluvial plain, and a longitudinal study of one of these channels has revealed a Loire River influence progressively replaced by a water contribution from the upper alluvial aquifer. Similarly, the two oxbow lakes at the Dornant site are not supplied by the same water during the summer months. A conceptual scheme of the Loire hydrosystem based on δ18O and 87Sr/ 86Sr suggests that the isotopic

  8. Systematic study of proton capture rates for Mo and Cd isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Bajpeyi, Awanish; Shukla, A. [Rajiv Gandhi Institute of Petroleum Technology, Department of Physics, Raebareli (India); Koning, A.J. [Nuclear Research and Consultancy Group NRG, Petten (Netherlands); Aaberg, Sven [Lund University, Mathematical Physics, P.O. Box 118, Lund (Sweden)


    Proton capture reactions play a very important role in the understanding of nucleosynthesis. In the present work, p-capture reactions have been studied coherently with nuclear structure for the nuclei under consideration. We have calculated proton capture cross sections and S-factor for relevant isotopes of molybdenum and cadmium in the energy range 2.0 to 4.5 Mev. Calculated results for nuclear structure as well reaction rates are compared with the available experimental and theoretical results and are found to be in good agreement. (orig.)

  9. Oxygen isotope systematics in an evolving geothermal system: Coso Hot Springs, California (United States)

    Etzel, Thomas M.; Bowman, John R.; Moore, Joseph N.; Valley, John W.; Spicuzza, Michael J.; McCulloch, Jesse M.


    Oxygen isotope and clay mineralogy studies have been made on whole rock samples and feldspar separates from three wells along the high temperature West Flank of the Coso geothermal system, California. The reservoir rocks have experienced variable 18O/16O depletion, with δ18O values ranging from primary values of + 7.5‰ down to - 4.6‰. Spatial patterns of clay mineral distributions in the three wells are not closely correlated with the distributions expected from measured, pre-production temperature profiles, but do correlate with spatial patterns of 18O/16O depletion, indicating that the stability of clay minerals in the three wells is a function of fluid-rock interaction in addition to temperature. Detailed δ18O measurements in the three wells identify a limited number of localized intervals of extensive 18O/16O depletion. These intervals document localized zones of higher permeability in the geothermal system that have experienced significant fluid infiltration, water-rock interaction and oxygen isotopic exchange with the geothermal fluids. The local zones of maximum 18O/16O depletion in each well correspond closely with current hot water production zones. Most feldspar separates have measured δ18O values too high to have completely attained oxygen isotope exchange equilibrium with the reservoir fluid at pre-production temperatures. In general, the lower the δ18O value of the feldspar, the closer the feldspar approaches exchange equilibrium with the geothermal fluid. This correlation suggests that fracture-induced increases in permeability increase both fluid infiltration and the surface area of the host rock exposed to geothermal fluid, promoting fluid-rock interaction and oxygen isotope exchange. The two most 18O/16O-depleted feldspar samples have δ18O values too low to be in exchange equilibrium with the pre-production reservoir fluid at pre-production temperatures. These discrepancies suggest that the reservoir fluid in the West Flank of the Coso

  10. Systematic study of heavy cluster emission from {sup 210-226}Ra isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Santhosh, K.P., E-mail: [School of Pure and Applied Physics, Kannur University, Payyanur Campus, Payyanur 670 327 (India); Sahadevan, Sabina; Priyanka, B.; Unnikrishnan, M.S. [School of Pure and Applied Physics, Kannur University, Payyanur Campus, Payyanur 670 327 (India)


    The half lives for various clusters lying in the cold reaction valleys of {sup 210-226}Ra isotopes are computed using our Coulomb and proximity potential model (CPPM). The computed half lives of {sup 4}He and {sup 14}C clusters from {sup 210-226}Ra isotopes are in good agreement with experimental data. Half lives are also computed using the universal formula for cluster decay (UNIV) of Poenaru et al., and are found to be in agreement with CPPM values. Our study reveals the role of doubly magic {sup 208}Pb daughter in cluster decay process. Geiger-Nuttall plots for all clusters up to {sup 62}Fe are studied and are found to be linear with different slopes and intercepts. {sup 12,14}C emission from {sup 220}Ra; {sup 14}C emission from {sup 222,224}Ra; {sup 14}C and {sup 20}O emission from {sup 226}Ra are found to be most favourable for measurement and this observation will serve as a guide to the future experiments.

  11. Carbon Isotope Systematics in Mineral-Catalyzed Hydrothermal Organic Synthesis Processes at High Temperature and Pressures (United States)

    Fu, Qi; Socki, R. A.; Niles, Paul B.


    Observation of methane in the Martian atmosphere has been reported by different detection techniques. Reduction of CO2 and/or CO during serpentization by mineral surface catalyzed Fischer-Tropsch Type (FTT) synthesis may be one possible process responsible for methane generation on Mars. With the evidence a recent study has discovered for serpentinization in deeply buried carbon rich sediments, and more showing extensive water-rock interaction in Martian history, it seems likely that abiotic methane generation via serpentinization reactions may have been common on Mars. Experiments involving mineral-catalyzed hydrothermal organic synthesis processes were conducted at 750 C and 5.5 Kbars. Alkanes, alcohols and carboxylic acids were identified as organic compounds. No "isotopic reversal" of delta C-13 values was observed for alkanes or carboxylic acids, suggesting a different reaction pathway than polymerization. Alcohols were proposed as intermediaries formed on mineral surfaces at experimental conditions. Carbon isotope data were used in this study to unravel the reaction pathways of abiotic formation of organic compounds in hydrothermal systems at high temperatures and pressures. They are instrumental in constraining the origin and evolution history of organic compounds on Mars and other planets.

  12. Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin (United States)

    Giuliani, Gaston; Fallick, Anthony; Rakotondrazafy, Michel; Ohnenstetter, Daniel; Andriamamonjy, Alfred; Ralantoarison, Théogène; Rakotosamizanany, Saholy; Razanatseheno, Marie; Offant, Yohann; Garnier, Virginie; Dunaigre, Christian; Schwarz, Dietmar; Mercier, Alain; Ratrimo, Voahangy; Ralison, Bruno


    The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (18O/16O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ18O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ18O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ18O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ18O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ18O values for gem corundum from secondary deposits have a wide spread between -0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ18O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ18O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ18O values between -0.3 and 16.5‰, and their origin is debated. A

  13. Stable isotope systematics of surface water bodies in the Himalayan and trans-Himalayan (Kashmir) region

    Indian Academy of Sciences (India)

    Kanchan Pandey; J T Padia; R Ramesh; K K Sharma


    Stable hydrogen (D) and oxygen (18O) isotope ratios of the headwaters of the Indus and its tributaries, surface ice in glaciers, saline and fresh water lakes and thermal springs in the Himalayan and Trans- Himalayan (Kashmir) region are reported. The D-18O relationship for the river samples shows a slope of 9.12 ± 0.29 which agrees well with the estimate of 8.99 ± 0.33 based on a simple Rayleigh fractionation model. The unique signature of a higher deuterium excess (d) of the `Western Disturbance' is preserved in these samples. An altitude effect of -0.9 per mil/km is observed in the 18O of Indus waters. At a lower altitude (Beas) the altitude effect is almost double, indicating that the altitude effect decreases with elevation in this region.

  14. Rhenium-osmium concentration and isotope systematics in group IIAB iron meteorites (United States)

    Morgan, J.W.; Horan, M.F.; Walker, R.J.; Grossman, J.N.


    Rhenium and osmium abundances, and osmium isotopic compositions were measured by negative thermal ionization mass spectrometry in thirty samples, including replicates, of five IIA and eight IIB iron meteorites. Log plots of Os vs. Re abundances for IIA and IIB irons describe straight lines that approximately converge on Lombard, which has the lowest Re and Os abundances and highest 187Re/188Os measured in a IIA iron to date. The linear IIA trend may be exactly reproduced by fractional crystallization, but is not well fitted using variable partition coefficients. The IIB iron trend, however, cannot be entirely explained by simple fractional crystallization. One explanation is that small amounts of Re and Os were added to the asteroid core during the final stages of crystallization. Another possibility is that diffusional enrichment of Os may have occurred in samples most depleted in Re and Os. -from Authors

  15. Systematic Study of Tensor Force Effect on Pseudospin Orbital Splittings in Sn Isotopes

    Institute of Scientific and Technical Information of China (English)

    WANG; Yan-zhao; YU; Guo-liang; LI; Zhen-yu; GU; Jian-zhong


    <正>The tensor force is a noncentral and nonlocal spin-spin coupling term of the nucleon-nucleon interaction whose effect on the nuclear structure has been discussed in the framework of the self-consistent mean field approaches and the shell model in the past a few years. Based on the Skyrme Hartree-Fock-Bogoliubov approach, we systematically investigated the role of the tensor force on the

  16. Isotopic ages of Lentiira – Kuhmo – Kostomuksha olivine lamproite - Group II kimberlites

    Directory of Open Access Journals (Sweden)

    Hugh O’Brien


    Full Text Available The Lentiira-Kuhmo-Kostomuksha triangle, along the Finland – Russian border and within the central part of the Archean Karelian craton, contains numerous examples of phlogopiterich, ultramafic, mantle-xenocryst-bearing and, in some cases, diamond-bearing dike rocks.Laser probe Ar-Ar data on phlogopite from 3 dike rocks on the Finnish side (Lentiira, Kuhmo all gave ages within error of each other, 1202±3 Ma (2σ, 1199±3 Ma (2σ and 1204±4 Ma (2σ while a fourth sample produced mixed ages. Published Rb-Sr dates on mineralogically and chemically similar dikes from the Russian side (Kostomuksha are 1232±5 Ma. The question remains open whether these represent two distinct age populations or whether differences in isotopic system behavior are the reason for the 30 m.y. age difference.

  17. Isotope geochronology of Dapingzhang spilite-keratophyre formation in Yunnan Province and its geological significance

    Institute of Scientific and Technical Information of China (English)

    钟宏; 胡瑞忠; 叶造军; 涂光炽


    On the basis of the geological field investigations and isotope geochronological studies the Sm-Nd isochron age (513 Ma?0 Ma), Rb-Sr isochron age (511 Ma? Ma) and K-Ar age (312-317 Ma) of the Dapingzhang spilite-keratophyre formation in Yunnan Province are presented. From these geochronological data it is evidenced that this suite of volcanic rocks was formed in the Cambrian and the parent magma was derived from a depleted mantle, which was influenced by crustal contamination and/or seawater hydrothermal alteration. During the Late Carboniferous the volcanic rocks experienced relatively strong geological reworking. This study provides geochronological evidence for the occurrence of Cambrian volcanic rocks in the Sanjiang (three-river) area.

  18. Isotope geochronology of Dapingzhang spilite-keratophyre formation in Yunnan Province and its geological significance

    Institute of Scientific and Technical Information of China (English)


    On the basis of the geological field investigations and isotope geochronological studies the Sm-Nd isochron age (513 Ma±40 Ma),Rb-Sr isochron age (511 Ma±8 Ma) and K-Ar age (312-317 Ma) of the Dapingzhang spilite-keratophyre formation in Yunnan Province are presented.From these geochronological data it is evidenced that this suite of volcanic rocks was formed in the Cambrian and the parent magma was derived from a depleted mantle,which was influenced by crustal contamination and/or seawater hydrothermal alteration.During the Late Carboniferous the volcanic rocks experienced relatively strong geological reworking.This study provides geochronological evidence for the occurrence of Cambrian volcanic rocks in the Sanjiang (three-river) area.

  19. Sulfur isotope systematics of microbial mats in shallow-sea hydrothermal vents, Milos Island, Greece (United States)

    Gilhooly, W. P.; Fike, D. A.; Amend, J. P.; Price, R. E.; Druschel, G.


    Milos is an island arc volcano venting submarine magmatic fluids directly into overlying seawater. Our study sites are located in an extensive shallow-water hydrothermal vent field less than 200 m offshore of Paleochori Bay in 5 m water depth. The vent fluids are highly sulfidic (> 3mM), at high-temperature (50-115C), and acidic (pH 5). The seafloor vent features include large patches (> 1 m2) of white microbial mats, patches of yellow elemental sulfur, and sediments stained orange by arsenic sulfides. The microbial communities that populate the shallow-sea hydrothermal vents stand in stark contrast to other nearshore environments typically found at wave base and within the photic zone. We explore sulfur isotope patterns along sharp environmental gradients established between ambient seawater and the efflux of vent fluids in the effort to better understand resource exploitation by microbial mat communities living in extreme conditions. Pore water samples, push-cores, biofilms, and water column samples were collected by SCUBA along sampling transects radiating out from the center of white mats into background sediments. We analyzed these samples for δ34S of dissolved sulfate, sulfide, elemental sulfur, and mineral sulfides (iron monosulfides and pyrite). Free gas sulfides collected directly from vents had δ34S values ranging +2.1 to +2.8%. Pore water sulfide, collected from below white mats with δ34S values ranging +1.9 to +2.9%, was isotopically similar to free gas samples. High pore water sulfate concentrations (8-25 mM) coupled with 34S-enriched pore water sulfides are not geochemical signatures indicative of dissimilatory sulfate reduction (where δ34Ssulfide <<0%). The δ34S of pore water sulfates collected across one dive site show a mixing trend, ranging from +18% in the center, +20% mid-transect, and +21% in sediments outside of the mat. This trend may be caused by oxidation of vent sulfides by entrained seawater (δ34S = +21.2%). We continue to target

  20. Boron isotope systematics during magma-carbonate interaction: an experimental study from Merapi (Indonesia) and Vesuvius (Italy) (United States)

    Deegan, F. M.; Jolis, E. M.; Troll, V. R.; Freda, C.; Whitehouse, M.


    Carbonate assimilation is increasingly recognized as an important process affecting the compositional evolution of magma and its inherent ability to erupt explosively due to release of carbonate-derived CO2 [e.g., 1, 2, 3]. In order to gain insights into this process, we performed short time-scale carbonate dissolution experiments in silicate melt using natural starting materials from Merapi and Vesuvius volcanoes at magmatic pressure and temperature [2, 4]. The experiments enable us to resolve in detail the timescales, textures and chemical features of carbonate assimilation. Three compositionally distinct glass domains have been defined: i) Ca-normal glass, similar in composition to the starting material; ii) Ca-rich, contaminated glass; and iii) a diffusional glass interface between the Ca-normal and Ca-rich glass, characterized by steady interchange between SiO2 and CaO. Here we present new boron isotope data for the experimental products obtained by SIMS. The glasses show distinct and systematic variation in their δ11B (%) values. The contaminated glasses generally show extremely negative δ11B values (down to -41 %) relative to both the uncontaminated experimental glass and fresh arc volcanics (-7 to +7 % [5]). Considering that carbonates have δ11B values of +9 to +26 [6], the data cannot be explained by simple mixing processes between the end-members alone. This implies that the δ11B of the original contaminant was drastically modified before being incorporated into the melt, which can be explained by B isotope fractionation during breakdown and degassing of the carbonate. Our data represents the first B isotope analyses of experimental products of carbonate assimilation. They provide novel and well constrained insights into the behavior of boron upon degassing of carbonate. This, in turn, has implications for both i) late stage contamination and volatile addition to hazardous volcanic systems located over carbonate basement (cf. [7]) and ii) studies of

  1. Highly Siderophile Elements and Osmium Isotope Systematics in Ureilites: Are the Carbonaceous Veins Primary Components? (United States)

    Rankenburg, K.; Brandon, A. D.; Humayun, M.


    Ureilites are an enigmatic group of primitive carbon-bearing achondrites of ultramafic composition. The majority of the 143 ureilite meteorites consist primarily of olivine and pyroxene (and occasionally chromite) [1]. They are coarse-grained, slowly cooled, and depleted in incompatible lithophile elements. Minor amounts of dark interstitial material consisting of carbon, metal, sulfides, and fine-grained silicates occur primarily along silicate grain boundaries, but also intrude the silicates along fractures and cleavage planes. Variable degrees of impact shock features have also been imparted on ureilites. The prevailing two origins proposed for these rocks are either as melting residues of carbonaceous chondritic material [2], [3], or alternatively, derivation as mineral cumulates from such melts [4], [5], [6]. It has recently been proposed that ureilites are the residues of a smelting event, i.e. residues of a partial melting event under highly reducing conditions, where a solid Fe-bearing phase reacts with a melt and carbon to form Fe metal and carbon monoxide [7]. Rapid, localized extraction and loss of the basaltic component into space resulting from high eruption velocities could preserve unequilibrated oxygen isotopes and produce the observed olivine-pyroxene residues via 25-30% partial melting of chondritic-like precursor material.

  2. Tracing slab dehydration using neon and argon isotope systematics in high pressure minerals (United States)

    Smye, A.; Jackson, C.; Parman, S. W.; Kelley, S. P.


    Mounting evidence suggests that noble gases are transported from Earth's surface reservoirs back into the mantle during subduction of oceanic lithosphere [e.g. 1]. Recent experiments [2] show that noble gases are relatively soluble in ring-structured minerals, such as amphibole, highlighting the potential for hydrated oceanic crust to control the input flux of noble gases into subduction zones. However, it is unclear whether the return flux of noble gases is controlled by mineral solubility alone or whether diffusive loss during subduction is important. Here, we address this issue by combining the solubility data with recently acquired He and Ne [3], and previously published Ar [4], diffusivity measurements in amphibole to parameterize a diffusion-solubility model, simulating noble gas fractionation during subduction. The model predicts that the light noble gases, He and Ne, are efficiently extracted from hot slabs at depths shallower than 50 km, whereas Ar and, by implication, Kr and Xe are retained in the slab past sub-arc depths. Conversely, cold slabs with low porosity volume fractions have the potential to recycle Ne. Our modelling shows that the Ne/Ar elemental ratio of slab minerals is strongly influenced by thermal regime and grain boundary porosity. We test these predictions against a new laser fusion dataset of Ne and Ar isotopic measurements in high-pressure minerals from a suite of exhumed high-pressure rocks that have experienced varying degrees of subduction and dehydration. Refs: [1] Holland, G. and Ballentine, C. (2006). Nature 441, 186-191. [2] Jackson et al. (2013). Nat.Geosci. 6, 562-565. [3] Jackson et al. submitted. [4] Harrison, T.M. (1981). CMP 78, 324-331.

  3. Hafnium isotope results from mid-ocean ridges and Kerguelen. (United States)

    Patchett, P.J.


    176Hf/177Hf ratios are presented for oceanic volcanic rocks representing both extremes of the range of mantle Hf-Nd-Sr isotopic variation. Hf from critical mid-ocean ridge basalts shows that 176Hf/177Hf does indeed have a greater variability than 143Nd/144Nd and 87Sr/86Sr in the depleted mantle. This extra variation is essentially of a random nature, and can perhaps be understood in terms of known Rb/Sr-Sm/Nd-Lu/Hf fractionation relationships. At the other extreme of mantle isotopic compositions, 176Hf/177Hf ratios for igneous rocks from the Indian Ocean island of Kerguelen show a closely similar variation to published 143Nd/144Nd ratios for the same samples. Comparison of Hf-Nd-Sr isotopic relatonships for Tristan da Cunha, Kerguelen and Samoa reveals divergences in the mantle array for ocean-island magma sources, and perhaps suggests that these irregularities are largely the result of an extra component of 87Sr/86Sr variation.-G.R.

  4. Systematization of cross sections for the production of residual nuclei on separated tin isotopes in reactions induced by various-energy protons

    Energy Technology Data Exchange (ETDEWEB)

    Balabekyan, A. R., E-mail:; Danagulyan, A. S. [Yerevan State University (Armenia); Drnoyan, J. R.; Demekhina, N. A. [Joint Institute for Nuclear Research (Russian Federation); Hovhannisyan, G. H.; Simonyan, A. E. [Yerevan State University (Armenia); Adam, J.; Solnishkin, A. A.; Tsoupko-Sytnikov, V. M. [Joint Institute for Nuclear Research (Russian Federation)


    Cross sections for the production of residual nuclei on the isotopes {sup 112,118,120,124}Sn irradiated with 0.66-, 1.0-, 3.65-, and 8.1-GeV proton beams were investigated. A ten-parameter semiempirical formula was used to systematize the cross sections in question. A comparative analysis of parameter values obtained at different proton energies was performed.

  5. Osmium isotope and highly siderophile element systematics of the lunar crust (United States)

    Day, James M. D.; Walker, Richard J.; James, Odette B.; Puchtel, Igor S.


    Coupled 187Os/ 188Os and highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, and Re) abundance data are reported for pristine lunar crustal rocks 60025, 62255, 65315 (ferroan anorthosites, FAN) and 76535, 78235, 77215 and a norite clast in 15455 (magnesian-suite rocks, MGS). Osmium isotopes permit more refined discrimination than previously possible of samples that have been contaminated by meteoritic additions and the new results show that some rocks, previously identified as pristine, contain meteorite-derived HSE. Low HSE abundances in FAN and MGS rocks are consistent with derivation from a strongly HSE-depleted lunar mantle. At the time of formation, the lunar floatation crust, represented by FAN, had 1.4 ± 0.3 pg g - 1 Os, 1.5 ± 0.6 pg g - 1 Ir, 6.8 ± 2.7 pg g - 1 Ru, 16 ± 15 pg g - 1 Pt, 33 ± 30 pg g - 1 Pd and 0.29 ± 0.10 pg g - 1 Re (˜ 0.00002 × CI) and Re/Os ratios that were modestly elevated ( 187Re/ 188Os = 0.6 to 1.7) relative to CI chondrites. MGS samples are, on average, characterised by more elevated HSE abundances (˜ 0.00007 × CI) compared with FAN. This either reflects contrasting mantle-source HSE characteristics of FAN and MGS rocks, or different mantle-crust HSE fractionation behaviour during production of these lithologies. Previous studies of lunar impact-melt rocks have identified possible elevated Ru and Pd in lunar crustal target rocks. The new results provide no supporting evidence for such enrichments. If maximum estimates for HSE in the lunar mantle are compared with FAN and MGS averages, crust-mantle concentration ratios ( D-values) must be ≤ 0.3. Such D-values are broadly similar to those estimated for partitioning between the terrestrial crust and upper mantle, with the notable exception of Re. Given the presumably completely different mode of origin for the primary lunar floatation crust and tertiary terrestrial continental crust, the potential similarities in crust-mantle HSE partitioning for the Earth and Moon are

  6. Osmium isotope and highly siderophile element systematics of the lunar crust (United States)

    Day, J.M.D.; Walker, R.J.; James, O.B.; Puchtel, I.S.


    Coupled 187Os/188Os and highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, and Re) abundance data are reported for pristine lunar crustal rocks 60025, 62255, 65315 (ferroan anorthosites, FAN) and 76535, 78235, 77215 and a norite clast in 15455 (magnesian-suite rocks, MGS). Osmium isotopes permit more refined discrimination than previously possible of samples that have been contaminated by meteoritic additions and the new results show that some rocks, previously identified as pristine, contain meteorite-derived HSE. Low HSE abundances in FAN and MGS rocks are consistent with derivation from a strongly HSE-depleted lunar mantle. At the time of formation, the lunar floatation crust, represented by FAN, had 1.4 ?? 0.3 pg g- 1 Os, 1.5 ?? 0.6 pg g- 1 Ir, 6.8 ?? 2.7 pg g- 1 Ru, 16 ?? 15 pg g- 1 Pt, 33 ?? 30 pg g- 1 Pd and 0.29 ?? 0.10 pg g- 1 Re (??? 0.00002 ?? CI) and Re/Os ratios that were modestly elevated (187Re/188Os = 0.6 to 1.7) relative to CI chondrites. MGS samples are, on average, characterised by more elevated HSE abundances (??? 0.00007 ?? CI) compared with FAN. This either reflects contrasting mantle-source HSE characteristics of FAN and MGS rocks, or different mantle-crust HSE fractionation behaviour during production of these lithologies. Previous studies of lunar impact-melt rocks have identified possible elevated Ru and Pd in lunar crustal target rocks. The new results provide no supporting evidence for such enrichments. If maximum estimates for HSE in the lunar mantle are compared with FAN and MGS averages, crust-mantle concentration ratios (D-values) must be ??? 0.3. Such D-values are broadly similar to those estimated for partitioning between the terrestrial crust and upper mantle, with the notable exception of Re. Given the presumably completely different mode of origin for the primary lunar floatation crust and tertiary terrestrial continental crust, the potential similarities in crust-mantle HSE partitioning for the Earth and Moon are somewhat

  7. Reassessment and new chronological data (Ar/Ar, Rb/Sr and Sm/Nd) from the Pelotas batholith, Rio Grande do Sul state: petrogenesis implications and reactivation age of the shear zones; Reavaliacao e novos dados geocronologicos (Ar/Ar, Rb/Sr e Sm/Nd) do batolito Pelotas, no Rio Grande do Sul: implicacoes petrogeneticas e idade de reativacao das zonas de cisalhamento

    Energy Technology Data Exchange (ETDEWEB)

    Philipp, Ruy Paulo; Chemale Junior, Farid [Rio Grande do Sul Univ., Porto Alegre (Brazil). Inst. de Geociencias. Centro de Estudos em Petrologia e Geoquimica]. E-mail:; Machado, Romulo [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias. Dept. de Mineralogia e Geotectonica


    SHRIMP and conventional U-Pb and Pb/Pb evaporation dating of zircon from the Pelotas batholith indicates one group of ages between 625 and 633 Ma for the Pinheiro Machado suite, and another group between 575 and 599 Ma for the Viamao, Encruzilhada do Sul and Dom Feliciano suites. Sr 87/Sr 86 isotopic ratios of 0.7060-0.7016, epsilon{sub Nd} values of -5 and -10, and Nd T{sub DM} model ages between 2200 and 1600 Ma suggest that the suites were mainly derived by melting of Paleoproterozoic crust formed during the Tranzamazonic Cycle. Basic magmatism and heterogeneous magma mixing in the Pinheiro Machado, Viamao, Encruzilhada do Sul and Dom Feliciano suite and the Piquiri alkaline magmatism, with Pb/Pb zircon evaporation ages between 610 and 615 Ma, suggest that a mantle component also contributed to the formation of the Pelotas batholith. 39 Ar/40 Ar determinations in micas from mylonitic rocks of high- and low-dip shear zones showed ages between 540 and 530 Ma, which show that important tectonic events occurred after the emplacement of the batholith. This event developed in a transpressive regime, was responsible for the reactivation of older shear zones, and was probably contemporaneous with the development of the Camaqua basin. (author)

  8. Nanoscale variations in 187Os isotopic composition and HSE systematics in a Bultfontein peridotite (United States)

    Wainwright, A. N.; Luguet, A.; Schreiber, A.; Fonseca, R. O. C.; Nowell, G. M.; Lorand, J.-P.; Wirth, R.; Janney, P. E.


    Understanding the mineralogical controls on radiogenic chronometers is a fundamental aspect of all geochronological tools. As with other common dating tools, it has become increasingly clear that the Re-Os system can be impacted by multiple mineral formation events. The accessory and micrometric nature of the Re-Os-bearing minerals has made assessing this influence complex. This is especially evident in cratonic peridotites, where long residence times and multiple metasomatic events have created a complex melting and re-enrichment history. Here we investigate a harzburgitic peridotite from the Bultfontein kimberlite (South Africa) which contains sub-micron Pt-Fe-alloy inclusions within base metal sulphides (BMS). Through the combination of the focused ion beam lift-out technique and low blank mass spectrometry we were able to remove and analyse the Pt-Fe-alloy inclusions for their Re-Os composition and highly siderophile element (HSE) systematics. Six repeats of the whole-rock yield 187Os/188Os compositions of 0.10893-0.10965, which correspond to Re depletion model ages (TRD) of 2.69-2.79 Ga. The Os, Ir and Pt concentrations are slightly variable across the different digestions, whilst Pd and Re remain constant. The resulting HSE pattern is typical of cratonic peridotites displaying depleted Pt and Pd. The Pt-Fe-alloys have PUM-like 187Os/188Os compositions of 0.1294 ± 24 (2-s.d.) and 0.1342 ± 38, and exhibit a saw-tooth HSE pattern with enriched Re and Pt. In contrast, their BMS hosts have unradiogenic 187Os/188Os of 0.1084 ± 6 and 0.1066 ± 3, with TRD ages of 2.86 and 3.09 Ga, similar to the whole-rock systematics. The metasomatic origin of the BMS is supported by (i) the highly depleted nature of the mantle peridotite and (ii) their Ni-rich sulphide assemblage. Occurrence of Pt-Fe-alloys as inclusions within BMS grains demonstrates the genetic link between the BMS and Pt-Fe-alloys and argues for formation during a single but continuous event of silicate melt

  9. Geology and D-O-C Isotope Systematics of the Tieluping Silver Deposit,Henan,China:Implications for Ore Genesis

    Institute of Scientific and Technical Information of China (English)

    CHEN Yanjing; Franco PIRAJNO; SUI Yinghui


    The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xiong'er terrane, is part of an important Mesozoic orogenic-type Ag-Pb and Au belt recently discovered. Ore formation includes three stages: Early (E), Middle (M) and Late (L), which include quartz-pyrite (E),polymetallic sulfides (M) and carbonates (L), respectively. The E-stage fluids are characterized by δD=-90‰,δ13Cco2=2.0‰ and δ18O=9‰ at 373℃, and are deeply sourced; the L-stage fluids, with δD=-70‰,δ13Cco2=-1.3‰ and δ18O=-2‰, are shallow-sourced meteoric water; whereas the M-stage fluids, with δD=-109‰,δ13Cco2=0.1‰ and δ18O=2‰, are a mix of deep-sourced and shallow-sourced fluids. Comparisons of the D-O-C isotopic systematics of the Estage ore-forming fluids with the fluids derived from Mesozoic granites, Archean-Paleoproterozoic metamorphic basement and Paleo-Mesoproterozoic Xiong'er Group, show that these units cannot generate fluids with the measured isotopic composition (high δ18O and δ13C ratios and low δD ratios) characteristic of the ore-forming fluids. This suggests that the E-stage ore-forming fluids originated from metamorphic devolatilization of a carbonate-shale-chert lithological association, locally rich in organic matter, which could correspond to the Meso-Neoproterozoic Guandaokou and Luanchuan Groups, rather than to geologic units in the Xiong'er terrane, the lower crust and the mantle. This supports the view that the rocks of the Guandaokou and Luanchuan Groups south of the Machaoying fault might be the favorable sources. A tectonic model that combines collisional orogeny, metallogeny and hydrothermal fluid flow is proposed to explain the formation of the Tieluping silver deposit. During the Mesozoic collision between the South and North China paleocontinents, a crustal slab containing a lithological association consisting of carbonate-shale-chert, locally rich in organic matter (carbonaceous

  10. Sm-Nd dating and Nd-Sr isotopic characteristics of the Shimian ophiolite suite, Sichuan Province

    Institute of Scientific and Technical Information of China (English)


    By measuring the Sm-Nd and Rb-Sr isotopic compositions of harzburgite and gabbro from Shimian ophiolite suite, we got the whole rock Sm-Nd isochron age of (938±30) Ma (2?), and the ??Nd of 7.6±0.8 (2?), which shows that the ophiolite was formed at the Early Neoproterozoic. The obvious change (0.70209-0.70708) of ISr values of the ophiolite is caused by the meteoric hydrothermal alteration. The high ? Nd values indicate that the primitive magma was derived from the intense depleted mantle reservoir. It is suggested that this area was in a back-arc basin environment during the Early Neoproterozic.

  11. Sources of granite magmatism in the Embu Terrane (Ribeira Belt, Brazil): Neoproterozoic crust recycling constrained by elemental and isotope (Sr-Nd-Pb) geochemistry (United States)

    Alves, Adriana; Janasi, Valdecir de Assis; Campos Neto, Mario da Costa


    Whole rock elemental and Sr-Nd isotope geochemistry and in situ K-feldspar Pb isotope geochemistry were used to identify the sources involved in the genesis of Neoproterozoic granites from the Embu Terrane, Ribeira Belt, SE Brazil. Granite magmatism spanned over 200 Ma (810-580 Ma), and is dominated by crust-derived relatively low-T (850-750 °C, zircon saturation) biotite granites to biotite-muscovite granites. Two Cryogenian plutons show the least negative εNdt (-8 to -10) and highest mg# (30-40) of the whole set. Their compositions are strongly contrasted, implying distinct sources for the peraluminous (ASI ∼ 1.2) ∼660 Ma Serra do Quebra-Cangalha batholith (metasedimentary rocks from relatively young upper crust with high Rb/Sr and low Th/U) and the metaluminous (ASI = 0.96-1.00) ∼ 630 Ma Santa Catarina Granite. Although not typical, the geochemical signature of these granites may reflect a continental margin arc environment, and they could be products of a prolonged period of oceanic plate consumption started at ∼810 Ma. The predominant Ediacaran (595-580 Ma) plutons have a spread of compositions from biotite granites with SiO2 as low as ∼65% (e.g., Itapeti, Mauá, Sabaúna and Lagoinha granites) to fractionated muscovite granites (Mogi das Cruzes, Santa Branca and Guacuri granites; up to ∼75% SiO2). εNdT are characteristically negative (-12 to -18), with corresponding Nd TDM indicating sources with Paleoproterozoic mean crustal ages (2.0-2.5 Ga). The Guacuri and Santa Branca muscovite granites have the more negative εNdt, highest 87Sr/86Srt (0.714-0.717) and lowest 208Pb/206Pb and 207Pb/206Pb, consistent with an old metasedimentary source with low time-integrated Rb/Sr. However, a positive Nd-Sr isotope correlation is suggested by data from the other granites, and would be consistent with mixing between an older source predominant in the Mauá granite and a younger, high Rb/Sr source that is more abundant in the Lagoinha granite sample. The

  12. Development of an on-line flow injection Sr/matrix separation method for accurate, high-throughput determination of Sr isotope ratios by multiple collector-inductively coupled plasma-mass spectrometry. (United States)

    Galler, Patrick; Limbeck, Andreas; Boulyga, Sergei F; Stingeder, Gerhard; Hirata, Takafumi; Prohaska, Thomas


    This work introduces a newly developed on-line flow injection (FI) Sr/Rb separation method as an alternative to the common, manual Sr/matrix batch separation procedure, since total analysis time is often limited by sample preparation despite the fast rate of data acquisition possible by inductively coupled plasma-mass spectrometers (ICPMS). Separation columns containing approximately 100 muL of Sr-specific resin were used for on-line FI Sr/matrix separation with subsequent determination of (87)Sr/(86)Sr isotope ratios by multiple collector ICPMS. The occurrence of memory effects exhibited by the Sr-specific resin, a major restriction to the repetitive use of this costly material, could successfully be overcome. The method was fully validated by means of certified reference materials. A set of two biological and six geological Sr- and Rb-bearing samples was successfully characterized for its (87)Sr/(86)Sr isotope ratios with precisions of 0.01-0.04% 2 RSD (n = 5-10). Based on our measurements we suggest (87)Sr/(86)Sr isotope ratios of 0.713 15 +/- 0.000 16 (2 SD) and 0.709 31 +/- 0.000 06 (2 SD) for the NIST SRM 1400 bone ash and the NIST SRM 1486 bone meal, respectively. Measured (87)Sr/(86)Sr isotope ratios for five basalt samples are in excellent agreement with published data with deviations from the published value ranging from 0 to 0.03%. A mica sample with a Rb/Sr ratio of approximately 1 was successfully characterized for its (87)Sr/(86)Sr isotope signature to be 0.718 24 +/- 0.000 29 (2 SD) by the proposed method. Synthetic samples with Rb/Sr ratios of up to 10/1 could successfully be measured without significant interferences on mass 87, which would otherwise bias the accuracy and uncertainty of the obtained data.

  13. Consistent evaluations of (n,2n) and (n,np) reaction excitation functions for some even-even isotopes using empirical systematics

    Energy Technology Data Exchange (ETDEWEB)

    Manokhin, Vassily N. [Russian Nuclear Data Center, Institute of Physics and Power Engineering, Obninsk (Russian Federation); Odano, Naoteru; Hasegawa, Akira [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment


    An approach for consistent evaluation of (n,2n) and (n,np) reaction excitation functions for some even-even isotopes with the (n,np) reaction thresholds lower than (n,2n) reaction ones is described. For determination of cross sections in the maximum of the (n,2n) and (n,np) reaction excitation functions some empirical systematics developed by Manokhin were used together with trends in dependence of gaps between the (n,2n) and (n,np) thresholds on atomic mass number A. The shapes of the (n,2n) and (n,np) reaction excitation functions were calculated using the normalized functions from the Manokhin's systematics. Excitation functions of (n,2n) and (n,np) reactions were evaluated for several nuclei by using the systematics and it was found that the approach used for the present study gives reasonable results. (author)

  14. Strontium and neodymium isotope systematics of target rocks and impactites from the El'gygytgyn impact structure: Linking impactites and target rocks (United States)

    Wegner, Wencke; Koeberl, Christian


    The 3.6 Ma El'gygytgyn structure, located in northeastern Russia on the Chukotka Peninsula, is an 18 km diameter complex impact structure. The bedrock is formed by mostly high-silica volcanic rocks of the 87 Ma old Okhotsk-Chukotka Volcanic Belt (OCVB). Volcanic target rocks and impact glasses collected on the surface, as well as drill core samples of bedrock and impact breccias have been investigated by thermal ionization mass spectrometry (TIMS) to obtain new insights into the relationships between these lithologies in terms of Nd and Sr isotope systematics. Major and trace element data for impact glasses are added to compare with the composition of target rocks and drill core samples. Sr isotope data are useful tracers of alteration processes and Nd isotopes reveal characteristics of the magmatic sources of the target rocks, impact breccias, and impact glasses. There are three types of target rocks mapped on the surface: mafic volcanics, dacitic tuff and lava of the Koekvun' Formation, and dacitic to rhyolitic ignimbrite of the Pykarvaam Formation. The latter represents the main contributor to the impact rocks. The drill core is divided into a suevite and a bedrock section by the Sr isotope data, for which different postimpact alteration regimes have been detected. Impact glasses from the present-day surface did not suffer postimpact hydrothermal alteration and their data indicate a coherent alteration trend in terms of Sr isotopes with the target rocks from the surface. Surprisingly, the target rocks do not show isotopic coherence with the Central Chukotka segment of the OCVB or with the Berlozhya magmatic assemblage (BMA), a late Jurassic felsic volcanic suite that crops out in the eastern part of the central Chukotka segment of the OCVB. However, concordance for these rocks exists with the Okhotsk segment of the OCVB. This finding argues for variable source magmas having contributed to the build-up of the OCVB.

  15. Isotope and trace element systematics in a spinel-lherzolite-bearing suite of basanitic volcanic rocks from San Luis Potosi, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Pier, J.E.G.


    Lherzolite-bearing basanitic magmas of Quaternary age have erupted to form maars, lava/cinder cones and lava flows in two volcanic fields (Ventura and Santo Domingo) in the central Mexican state of San Luis Potosi. The systematics of the radiogenic isotopes of Sr, Nd, and Pb and the relationship between these parameters and elemental compositions are used to investigate the petrogenesis of the volcanic rocks and the nature of their mantle sources. Sr and Nd isotopic data are presented for 19 basanitic rocks, 5 kaersutites, and 6 lherzolitic xenoliths; Pb data presented for the same 19 volcanic rocks and 4 of the 5 kaersutites. The isotopic compositions for all of these samples fall within the mantle range defined by MORBs and OIBs. The basanites generally plot within the OIB field on isotopic diagrams; most of the kaersutites are displaced to slightly more-depleted (i.e. MORB-like) values than the volcanic samples and the xenoliths, with one exception, are significantly more-depleted than either of these sample-types. As crustal contamination is considered unlikely for most of the volcanic samples, these trends are thought to arise from mixing multiple mantle components. The absence of similar isotopic elemental relationships for Epsilon Nd and the lack of correlation between {sup 206}Pb/{sup 204}Pb and the other Pb isotopes require a mixture of at least three mantle reservoirs: a depleted reservoir analogous to that of the MORBs, a St. Helena-type component, and a third component, which primarily affects Sr and {sup 208}Pb/{sup 204}Pb composition. This third component carries relatively radiogenic Sr and {sup 208}Pb/{sup 204}Pb and appears to be correlated with the degree of melting.

  16. Identification of Marchfeld asparagus using Sr isotope ratio measurements by MC-ICP-MS. (United States)

    Swoboda, S; Brunner, M; Boulyga, S F; Galler, P; Horacek, M; Prohaska, T


    This work focuses on testing and application of Sr isotope signatures for the fast and reliable authentication and traceability of Asparagus officinalis originating from Marchfeld, Austria, using multicollector inductively coupled plasma mass spectrometry after optimised Rb/Sr separation. The major sample pool comprises freeze-dried and microwave-digested asparagus samples from Hungary and Slovakia which are compared with Austrian asparagus originating from the Marchfeld region, which is a protected geographical indication. Additional samples from Peru, The Netherlands and Germany were limited in number and allowed therefore only restricted statistical evaluation. Asparagus samples from Marchfeld were harvested within two subsequent years in order to investigate the annual variation. The results show that the Sr isotope ratio is consistent within these 2 years of investigation. Moreover, the Sr isotope ratio of total Sr in soil was found to be significantly higher than in an NH4NO3 extract, reflecting the mobile (bioavailable) phase. The isotope composition in the latter extract corresponds well to the range found in the asparagus samples in Marchfeld, even though the concentration of Sr in asparagus shows no direct correlation to the concentration of Sr in the mobile phase of the soil. The major question was whether the 'Marchfelder Spargel' can be distinguished from samples from the neighbouring countries of Hungary and Slovakia. According to our findings, they can be clearly (100%) singled out from the Hungarian samples and can be distinguished from the Slovakian asparagus samples with a probability of more than 80%.

  17. Evaluation of the age related systematic patterns of stable oxygen and carbon isotope values of Swiss stone pine (Pinus cembra L.) Eastern Carpathians, Romania (United States)

    Nagavciuc, Viorica; Popa, Ionel; Persoiu, Aurel; Kern, Zoltán


    Tree-ring derived stable isotope time series are becoming increasingly important parameters in investigation of past environmental changes. However, potential age related trend-bias on these parameters, and the proper handling of it, is still not well understood. We here present measurements on a new multicentennial data set of annually resolved stable oxygen (δ18O) and carbon (δ13C) isotope compositions from 3 living and 4 subfossil Stone pine (Pinus cembra) samples collected at a timberline habitat in the Eastern Carpathians (Romania) to evaluate any potential systematic ontogenetic pattern on their δ18O and δ13C data. Oldest analyzed ring represented 129th, 135th and 142th cambial year in the living and 115th, 130th, 165th and 250th cambial year in the subfossil samples. The fact that Stone pine samples are backbone of the longest dendrochronological series both in the Alps and the Carpathians arouses special interest concerning their potential in stable isotope dendroclimatological research. Whole-ring samples were prepared to alpha-cellulose by the modified Jayme-Wise method. Cellulose samples were analyzed by a high-temperature pyrolysis system (Thermo Quest TC-EA) coupled to an isotope ratio mass spectrometer (Thermo Finningan Delta V). A ring by ring (i.e., non-pooled) approach was followed since age-related trends are by definition intrinsic to individual tree-ring series so pooling of rings may distort the detection of the trends. Raw measured δ13C values have been corrected for changes in the atmospheric CO2 regarding both its stable isotope signature and mixing ratio. Neither isotopic parameter showed any age related variance bias suggesting a homoscedastic character. Alignment of the δ13C data by cambial age revealed a relatively short period (~40 years) of systematic behaviour manifested in a ~1‰ enrichment in 13C over a moderate but persistent positive trend (~0.33‰ per 100years, p<10-10) can be observed for carbon discrimination afterwards

  18. Determining Carbon and Oxygen Stable Isotope Systematics in Brines at Elevated p/T Conditions to Enhance Monitoring of CO2 Induced Processes in Carbon Storage Reservoirs (United States)

    Becker, V.; Myrttinen, A.; Mayer, B.; Barth, J. A.


    Stable carbon isotope ratios (δ13C) are a powerful tool for inferring carbon sources and mixing ratios of injected and baseline CO2 in storage reservoirs. Furthermore, CO2 releasing and consuming processes can be deduced if the isotopic compositions of end-members are known. At low CO2 pressures (pCO2), oxygen isotope ratios (δ18O) of CO2 usually assume the δ18O of the water plus a temperature-dependent isotope fractionation factor. However, at very high CO2 pressures as they occur in CO2 storage reservoirs, the δ18O of the injected CO2 may in fact change the δ18O of the reservoir brine. Hence, changing δ18O of brine constitutes an additional tracer for reservoir-internal carbon dynamics and allows the determination of the amount of free phase CO2 present in the reservoir (Johnson et al. 2011). Further systematic research to quantify carbon and oxygen isotope fractionation between the involved inorganic carbon species (CO2, H2CO3, HCO3-, CO32-, carbonate minerals) and kinetic and equilibrium isotope effects during gas-water-rock interactions is necessary because p/T conditions and salinities in CO2 storage reservoirs may exceed the boundary conditions of typical environmental isotope applications, thereby limiting the accuracy of stable isotope monitoring approaches in deep saline formations (Becker et al. 2011). In doing so, it is crucial to compare isotopic patterns observed in laboratory experiments with artificial brines to similar experiments with original fluids from representative field sites to account for reactions of dissolved inorganic carbon (DIC) with minor brine components. In the CO2ISO-LABEL project, funded by the German Ministry for Education and Research, multiple series of laboratory experiments are conducted to determine the influence of pressure, temperature and brine composition on the δ13C of DIC and the δ18O of brines in water-CO2-rock reactions with special focus placed on kinetics and stable oxygen and carbon isotope fractionation

  19. Isotopic Systematics (U, nitrate and Sr) of the F-Area Acidic Contamination Plume at the Savannah River Site: Clues to Contaminant History and Mobility (United States)

    Christensen, J. N.; Conrad, M. E.; Bill, M.; Denham, M.; Wan, J.; Rakshit, S.; Stringfellow, W. T.; Spycher, N.


    reduction processes. In detail, the variation in the isotopic composition of F-Area nitrate does not support biologic denitrification within the plume. However, the isotopic composition of a surface water sample is consistent with denitrification occurring along the flow path between the plume seep-line and the surface stream. Strontium from F-Area groundwater samples covers a wide range in concentration (<<20 to 145 ppb) and 87Sr/86Sr (0.7096 to 0.7133). There is no systematic relationship between 87Sr/86Sr & 90Sr or 1/[Sr] suggesting possible Sr exchange with clays minerals. The isotopic compositions of groundwater and porewater samples vary systematically with sampling depth below the water table as illustrated by U isotopic data for depth discrete porewater samples and the δ15N of well samples. There appears to be a shallow zone within the top 10 ft of the aquifer, defined by reversals in the trends of U isotopic data and nitrate δ18O.

  20. Geochemical, isotopic and geochronological characterization of listvenite from the Upper Unit on Tinos, Cyclades, Greece (United States)

    Hinsken, Tim; Bröcker, Michael; Strauss, Harald; Bulle, Florian


    We describe a largely unknown listvenite deposit from Tinos, Cyclades, Greece and combine field observations with petrographic, bulk-rock geochemical, isotope (Sr, O, C), and Rb-Sr geochronological data. The volumetrically small listvenite occurrences are associated with metabasic phyllites, talc schists, meta-gabbros, ophicalcites and serpentinites of the Upper Unit. Geochemical characteristics (high Mg#, Cr, Ni), as well as preserved relic Cr-spinel and the typical mesh-texture of serpentinized Mg-silicates, document derivation from ultramafic precursors. Judging from field and textural observations it is very likely that carbonation affected serpentinite and not unaltered meta-peridotite. The direct contact or transition zones to ultramafic rocks are not preserved, but serpentinites that escaped carbonation are closely associated. The listvenites occur near a low-angle normal fault that probably focused fluid infiltration and distribution. The carbonation is associated with the influx of CO2-rich, K-bearing fluids that led to the formation of ferroan magnesite, quartz and Cr-bearing white mica (fuchsite), but otherwise the transformation of serpentinized peridotite into listvenite had been a largely isochemical process. The studied rocks do not contain elevated concentrations of precious metals (Au, Pt, Pd). Field relationships suggest that the listvenite-bearing occurrences most likely represent the same tectonostratigraphic level as Upper Unit rocks that had been thermally overprinted in the contact aureole of Miocene granitoids at ca. 15 Ma. Accordingly the intrusion depth provides a minimum pressure constraint for the somewhat older carbonation. Pressure estimates for thermally overprinted rocks and the granitoids suggest an intrusion depth of ca. 7-10 km that corresponds to a pressure of ca. 2-3 kbar. Chlorite thermometry applied to the Tinos listvenites mostly indicates temperatures of ca. 250 °C during carbonation. Internal Rb-Sr mineral isochrons

  1. Isotope systematics of a juvenile intraplate volcano: Pb, Nd, and srisotope ratios of basalts from Loihi Seamount, Hawaii

    Energy Technology Data Exchange (ETDEWEB)

    Staudigel, H. (Columbia Univ., Palisades, NY (USA). Lamont-Doherty Geological Observatory; Scripps Institution of Oceanography, La Jolla, CA (USA)); Zindler, A.; Leslie, T. (Columbia Univ., Palisades, NY (USA). Lamont-Doherty Geological Observatory); Hart, S.R.; Chen, C.Y. (Massachusetts Inst. of Tech., Cambridge (USA). Dept. of Earth and Planetary Sciences); Clague, D. (Geological Survey, Menlo Park, CA (USA))


    Sr, Nd, and Pb isotope ratios for a representative suite of 15 basanites, alkali basalts, transitional basalts and tholeiites from Loihi Seamount, Hawaii, display unusually large variations for a single volcano, but lie within known ranges for Hawaiian basalts. Nd isotope ratios in alkali basalts show the largest relative variation (0.51291 - 0.51305), and include the nearly constant tholeiite value (approx.= 0.51297). Pb isotope ratios show similarly large ranges for tholeiites and alkali basalts and continue Tatsumoto's (31) 'Loa' trend towards higher /sup 206/Pb//sup 204/Pb, ratios, resulting in a substantial overlap with the 'Kea' trend. /sup 206/Pb//sup 204/Pb ratios for Loihi and other volcanoes along the Loa and Kea trends (31) are observed to correlate with the age of the underlying lithosphere suggesting lithosphere involvement in the formation of Hawaiian tholeiites. Loihi lavas display no correlation of Nd, Sr, or Pb isotope ratios with major element compositions or eruptive age, in contrast with observations of some other Hawaiian volcanoes. Isotope data for Loihi, as well as average values for Hawaiian volcanoes, are not adequately explained by previously proposed two-end-member models; new models for the origin and the development of Hawaiian volcanoes must include mixing of at least three geochemically distinct source regions and allow for the involvement of heterogeneous oceanic lithosphere.

  2. Microscopic study of low-lying yrast spectra and deformation systematics in neutron-rich 98−106Sr isotopes

    Indian Academy of Sciences (India)

    Anil Chandan; Suram Singh; Arun Bharti; S K Khosa


    Variation-after-projection (VAP) calculations in conjunction with Hartree–Bogoliubov (HB) ansatz have been carried out for = 98–106 strontium isotopes. In this framework, the yrast spectra with ≥ 10+, (2) transition probabilities, quadrupole deformation parameter and occupation numbers for various shell model orbits have been obtained. The results of the calculation for yrast spectra give an indication that it is important to include the hexadecapole–hexadecapole component of the two-body interaction for obtaining various nuclear structure quantities in Sr isotopes. Besides this, it is also found that the simultaneous polarization of 3/2 and 5/2 proton subshells is a significant factor in making a sizeable contribution to the deformation in neutron-rich Sr isotopes.

  3. Isotope hydrology of the Chalk River Laboratories site, Ontario, Canada (United States)

    Peterman, Zell; Neymark, Leonid; King-Sharp, K.J.; Gascoyne, Mel


    This paper presents results of hydrochemical and isotopic analyses of groundwater (fracture water) and porewater, and physical property and water content measurements of bedrock core at the Chalk River Laboratories (CRL) site in Ontario. Density and water contents were determined and water-loss porosity values were calculated for core samples. Average and standard deviations of density and water-loss porosity of 50 core samples from four boreholes are 2.73 ± 12 g/cc and 1.32 ± 1.24 percent. Respective median values are 2.68 and 0.83 indicating a positive skewness in the distributions. Groundwater samples from four deep boreholes were analyzed for strontium (87Sr/86Sr) and uranium (234U/238U) isotope ratios. Oxygen and hydrogen isotope analyses and selected solute concentrations determined by CRL are included for comparison. Groundwater from borehole CRG-1 in a zone between approximately +60 and −240 m elevation is relatively depleted in δ18O and δ2H perhaps reflecting a slug of water recharged during colder climatic conditions. Porewater was extracted from core samples by centrifugation and analyzed for major dissolved ions and for strontium and uranium isotopes. On average, the extracted water contains 15 times larger concentration of solutes than the groundwater. 234U/238U and correlation of 87Sr/86Sr with Rb/Sr values indicate that the porewater may be substantially older than the groundwater. Results of this study show that the Precambrian gneisses at Chalk River are similar in physical properties and hydrochemical aspects to crystalline rocks being considered for the construction of nuclear waste repositories in other regions.

  4. Shell Model Embedded in the Continuum for Binding Systematics in Neutron-Rich Isotopes of Oxygen and Fluor

    CERN Document Server

    Luo, Y; Ploszajczak, M; Michel, N


    Continuum coupling correction to binding energies in the neutron rich oxygen and fluorine isotopes is studied using the Shell Model Embedded in the Continuum. We discuss the importance of different effects, such as the position of one-neutron emission threshold, the effective interaction or the number of valence particles on the magnitude of this correction.

  5. Sr-Nd-Pb-Hf isotope systematics of the Hugo Dummett Cu-Au porphyry deposit (Oyu Tolgoi, Mongolia) (United States)

    Dolgopolova, A.; Seltmann, R.; Armstrong, R.; Belousova, E.; Pankhurst, R. J.; Kavalieris, I.


    Major and trace element geochemistry including Sr-Nd-Pb-Hf isotopic data are presented for a representative sample suite of Late Devonian to Early Carboniferous plutonic and volcanic rocks from the Hugo Dummett deposit of the giant Oyu Tolgoi porphyry Cu-Au district in South Gobi, Mongolia. Sr and Nd isotopes (whole-rock) show restricted ranges of initial compositions, with positive ɛNdt mainly between + 3.4 and + 7.4 and (87Sr/86Sr)t predominantly between 0.7037 and 0.7045 reflecting magma generation from a relatively uniform juvenile lithophile-element depleted source. Previously dated zircons from the plutonic rocks exhibit a sample-averaged range of ɛHft values of + 11.6 to + 14.5. Depleted-mantle model ages of 420-830 (Nd) and 320-730 Ma (zircon Hf) limit the involvement of pre-Neoproterozoic crust in the petrogenesis of the intermediate to felsic calc-alkaline magmas to, at most, a minor role. Pb isotopes (whole-rock) show a narrow range of unradiogenic initial compositions: 206Pb/204Pb 17.40-17.94, 207Pb/204Pb 15.43-15.49 and 208Pb/204Pb 37.25-37.64, in agreement with Sr-Nd-Hf isotopes indicating the dominance of a mantle component. All four isotopic systems suggest that the magmas from which the large Oyu Tolgoi porphyry system was generated originated predominantly from juvenile material within the subduction-related setting of the Gurvansayhan terrane.

  6. Halogen and Cl isotopic systematics in Martian phosphates: Implications for the Cl cycle and surface halogen reservoirs on Mars (United States)

    Bellucci, J. J.; Whitehouse, M. J.; John, T.; Nemchin, A. A.; Snape, J. F.; Bland, P. A.; Benedix, G. K.


    The Cl isotopic compositions and halogen (Cl, F, Br, and I) abundances in phosphates from eight Martian meteorites, spanning most rock types and ages currently available, have been measured in situ by Secondary Ion Mass Spectrometry (SIMS). Likewise, the distribution of halogens has been documented by x-ray mapping. Halogen concentrations range over several orders of magnitude up to some of the largest concentrations yet measured in Martian samples or on the Martian surface, and the inter-element ratios are highly variable. Similarly, Cl isotope compositions exhibit a larger range than all pristine terrestrial igneous rocks. Phosphates in ancient (>4 Ga) meteorites (orthopyroxenite ALH 84001 and breccia NWA 7533) have positive δ37Cl anomalies (+1.1 to + 2.5 ‰). These samples also exhibit explicit whole rock and grain scale evidence for hydrothermal or aqueous activity. In contrast, the phosphates in the younger basaltic Shergottite meteorites (<600 Ma) have negative δ37Cl anomalies (-0.2 to - 5.6 ‰). Phosphates with the largest negative δ37Cl anomalies display zonation in which the rims of the grains are enriched in all halogens and have significantly more negative δ37Cl anomalies suggestive of interaction with the surface of Mars during the latest stages of basalt crystallization. The phosphates with no textural, major element, or halogen enrichment evidence for mixing with this surface reservoir have an average δ37Cl of - 0.6 ‰, supporting a similar initial Cl isotope composition for Mars, the Earth, and the Moon. Oxidation and reduction of chlorine are the only processes known to strongly fractionate Cl isotopes, both positively and negatively, and perchlorate has been detected in weight percent concentrations on the Martian surface. The age range and obvious mixing history of the phosphates studied here suggest perchlorate formation and halogen cycling via brines, which have been documented on the Martian surface, has been active throughout Martian

  7. Carbon isotope systematics of a mantle 'hotspot': A comparison of Loihi Seamount and MORB glasses

    Energy Technology Data Exchange (ETDEWEB)

    Exley, R.A.; Mattey, D.P.; Pillinger, C.T.; Clague, D.A.


    The carbon isotope geochemistry of glasses from Loihi Seamount has been compared with that of MORB glasses. Stepped heating shows two carbon components in both sample suites: 1. isotopically light carbon (avg. delta/sup 13/C=-26.3per mille) released <600/sup 0/C, ascribed to surficial contamination, and 2. isotopically heavy carbon released >600/sup 0/C, regarded as indigenous. The high-temperature component in MORB samples varied from 52 to 169 ppm C, average delta/sup 13/C=-6.6per mille, consistent with previous studies (overall MORB average delta/sup 13/C=-6.4 +- 0.9per mille), and new results for Indian Ocean glasses are similar to Atlantic and Pacific Ocean samples. Carbon release profiles produced by stepped heating may be typical of locality, but there are no significant differences in delta/sup 13/C values between MORB samples from different areas. Lower yields (17-110 ppm C) correlated with depth in the Loihi samples suggest that they are partially degassed. This degassing has not affected delta/sup 13/C values significantly (avg. -5.8per mille). Loihi tholeiites have higher delta/sup 13/C (avg. -5.6per mille) than the alkali basalts (avg. -7.1per mille). Carbon abundances correlate well with He concentration data. Comparison of the delta/sup 13/C values with trace element and He, Sr, Nd, and Pb isotope data from the literature suggests that the Loihi samples with highest delta/sup 13/C have high /sup 3/He//sup 4/He and possibly the least depleted /sup 143/Nd//sup 144/Nd and /sup 87/Sr//sup 86/Sr. The carbon isotope data are consistent with previous models for Loihi involving several mantle sources, lithospheric contamination, and mixing. The slightly higher delta/sup 13/C of Loihi tholeiites suggests that the undegassed ''plume'' component manifested by high /sup 3/He//sup 4/He values might have delta/sup 13/C about 1per mille higher than the MORB average.

  8. ReOs isotope systematics of NiCu sulfide ores, Sudbury Igneous Complex, Ontario: evidence for a major crustal component (United States)

    Walker, R.J.; Morgan, J.W.; Naldrett, A.J.; Li, C.; Fassett, J.D.


    Sudbury Igneous Complex sublayer ores from the Levack West, Falconbridge and Strathcona mines were analyzed for their Re and Os concentrations and Os isotopic compositions. The ReOs isotope systematics of three ores from the different mines give isochron ages of 1840 ?? 60 Ma, 1770 ?? 60 Ma and 1780 ?? 110 Ma, suggesting that the ReOs system became closed at the time of, or soon after the 1850 ?? 1 Ma crystallization age of the complex. The Os isotopic compositions of different portions of the complex at the time of crystallization varied considerably, with initial 187Os 186Os1850 ranging from 4.64 at Levack West to 7.55 at Strathcona. These heterogeneities require that the Os, and probably also the other platinum-group elements contained in the ores, were derived from at least two sources. In addition, the high initial 187Os 186Os ratios indicate that the Os was derived predominantly from ancient crust. Previous studies have suggested that the complex either crystallized from a mixture of mantle-derived basaltic melt and ancient continental crust, or was derived exclusively from the fusion of ancient continental crust resulting from a meteorite impact. Results of modelling suggest that if a contemporaneous mantle-derived basaltic melt was involved in the origin of the SIC, it likely contributed < 50% of the Os to all three ores. The large percentage of ancient crust involved in the production of the ores is most consistent with an interpretation of substantial crustal fusion resulting from meteorite impact. ?? 1991.

  9. Zircon LA-ICP-MS U-Pb dating and Sr-Nd isotope study of the Guposhan granite complex, Guangxi, China

    Institute of Scientific and Technical Information of China (English)

    GU Shengyan; HUA Renmin; QI Huawen


    Zircon U-Pb dating by the LA-ICP-MS method was applied to determining the ages of different units of the Guposhan granite complex, among which the East Guposhan unit is 160.8±1.6 Ma, the West Guposhan unit is 165.0±1.9 Ma, and the Lisong unit is 163.0±1.3 Ma in age. Much similarity in ages of the three units has thus proved that the whole Guposhan granite complex was formed in the same period of time. They were the products of large-scale granitic magmatism through crust-remelting in the first stage of the Middle Yanshanian in South China. However, the three units have differences both in petrology and in geochemistry. Besides the differences in major, trace and rare-earth elements, they are distinct in their Rb-Sr and Sm-Nd isotopic compositions. The East Guposhan unit and Lisong unit and its enclaves have a similar (87Sr/86Sr)i value of 0.7064 with an average of εNd(t)=-3.03, indicating that more mantle material was evolved in the magma derivation; whereas the West Guposhan unit has a higher (87Sr/86Sr)i value of 0.7173 but a lower εNd(t) value of -5.00, and is characterized by strong negative Eu anomalies and higher Rb/Sr ratios, suggesting that its source materials were composed of relatively old crust components and new mantle-derived components. In addition, an inherited zircon grain in the East Guposhan unit (GP-1) yielded a 206Pb/238U age of 806.4 Ma, which is similar to the ages of the Jiulin cordierite granite in northern Jiangxi and of the Yinqiao migmatic granite in Guangxi in the HZH granite zone. All this may provide new evidence for Late Proterozoic magmatism in the HZH granite zone.

  10. Sulfur and oxygen isotopic systematics of the 1982 eruptions of El Chichón Volcano, Chiapas, Mexico (United States)

    Rye, R.O.; Luhr, J.F.; Wasserman, M.D.


    Thermometers based on sulfur and oxygen isotopic compositions of anhydrite, pyrrhotite, titanomagnetite, and plagioclase crystals from fresh pumices of the 1982 eruptions of El Chichón Volcano indicate a pre-eruption temperature of 810 ± 40°C, confirming textural evidence that the anhydrite precipitated directly from the melt. The isotopic composition of sulfate leached from fresh ashfall samples shows it to be a mixture of anhydrite microphenocrysts and adsorbed sulfate derived from oxidized sulfur (SO2) in the eruption plume. The leachate data show no evidence for rapid oxidation of significant amounts of H2S in the eruption cloud even though the fugacity ratio of H2S/SO2 in the gas phase of the magma was >400. This may indicate kinetic inhibition of H2S to SO2 conversion in the eruption cloud. Prior to eruption, the magma contained an estimated 2.6 wt. % sulfur (as SO3). The estimated δ 34S of the bulk magma is 5.8‰. Such a high value may reflect assimilation of 34S-enriched evaporites or the prior loss of 34S-depleted H2S to a fluid or gas phase during formation of a small prophyry-type hydrothermal system or ore deposit. In either case, the original magma must have been very sulfur rich. It is likely that the initial high sulfur content of the magma and at least some of its 34S enrichment reflects involvement of subducted volcanogenic massive sulfides deposits during Benioff-zone partial melting. Isotopic data on mineralized, accidental lithic fragments support the possible development of a porphyry-type system at El Chichón.

  11. Sulfur and oxygen isotopic systematics of the 1982 eruptions of El Chichón Volcano, Chiapas, Mexico (United States)

    Rye, R. O.; Luhr, J. F.; Wasserman, M. D.


    Thermometers based on sulfur and oxygen isotopic compositions of anhydrite, pyrrhotite, titanomagnetite, and plagioclase crystals from fresh pumices of the 1982 eruptions of El Chichón Volcano indicate a pre-eruption temperature of 810 ± 40°C, confirming textural evidence that the anhydrite precipitated directly from the melt. The isotopic composition of sulfate leached from fresh ashfall samples shows it to be a mixture of anhydrite microphenocrysts and adsorbed sulfate derived from oxidized sulfur (SO 2) in the eruption plume. The leachate data show no evidence for rapid oxidation of significant amounts of H 2S in the eruption cloud even though the fugacity ratio of H 2S/SO 2 in the gas phase of the magma was >400. This may indicate kinetic inhibition of H 2S to SO 2 conversion in the eruption cloud. Prior to eruption, the magma contained an estimated 2.6 wt. % sulfur (as SO 3). The estimated δ 34S of the bulk magma is 5.8‰. Such a high value may reflect assimilation of 34S-enriched evaporites or the prior loss of 34S-depleted H 2S to a fluid or gas phase during formation of a small prophyry-type hydrothermal system or ore deposit. In either case, the original magma must have been very sulfur rich. It is likely that the initial high sulfur content of the magma and at least some of its 34S enrichment reflects involvement of subducted volcanogenic massive sulfides deposits during Benioff-zone partial melting. Isotopic data on mineralized, accidental lithic fragments support the possible development of a porphyry-type system at El Chichón.

  12. Carbon isotope systematics and CO2 sources in The Geysers-Clear Lake region, northern California, USA (United States)

    Bergfeld, D.; Goff, F.; Janik, C.J.


    Carbon isotope analyses of calcite veins, organic carbon, CO2 and CH4 from 96 rock and 46 gas samples show that metamorphic calcite veins and disseminated, organically-derived carbon from Franciscan Complex and Great Valley Sequence rocks have provided a primary carbon source for geothermal fluids during past and present hydrothermal activity across The Geysers-Clear Lake region. The stable isotope compositions of calcite veins vary widely on a regional scale, but overall they document the presence of 13C-poor fluids in early subduction-related vein-precipitating events. ??13C values of calcite veins from the SB-15-D corehole within The Geysers steam field indicate that carbon-bearing fluids in the recent geothermal system have caused the original diverse ??13C values of the veins to be reset. Across The Geysers-Clear Lake region the carbon isotope composition of CO2 gas associated with individual geothermal reservoirs shows a general increasing trend in ??13C values from west to east. In contrast, ??13C values of CH4 do not exhibit any spatial trends. The results from this study indicate that regional variations in ??13C-CO2 values result from differences in the underlying lithologies. Regional CO2 contains significant amounts of carbon related to degradation of organic carbon and dissolution of calcite veins and is not related to equilibrium reactions involving CH4. CO2 from degassing of underlying magma chambers is not recognizable in this region. Published by Elsevier Science Ltd on behalf of CNR.

  13. Re-Os isotope measurements of single sulfide inclusions in a Siberian diamond and its nitrogen aggregation systematics (United States)

    Pearson, D. G.; Shirey, S. B.; Bulanova, G. P.; Carlson, R. W.; Milledge, H. J.


    We have measured the Re-Os isotopic compositions of individual syngenetic sulfide inclusions from three different growth zones within a central cross section plate cut from a single Siberian diamond. Individual sulfides in their diamond host were isolated by laser cutting. The sulfides, and hence the different growth zones of the diamond have been suggested to differ in age by up to 2 Ga on the basis of their Pb isotope compositions. Re-Os model ages of the four inclusions range from 3.1 ± 0.3 to 3.5 ± 0.3 Ga and suggest a Middle Archaean age for the diamond. A sulfide inclusion in the rim of the diamond is very different in elemental composition from those of the core and intermediate zones. It is enriched in Os, Re, Pb, and Zn and has more radiogenic Os and Pb isotopes. The inclusion is connected to the surface of the diamond by a healed crack, revealed by cathodoluminescence. The compositional distinction may be caused either by postformational interaction between an ancient sulfide and a fluid, possibly at the time of kimberlite eruption, or later stage growth of new diamond plus sulfide. Such chemical complexities, and the presence of healed fractures within the host diamond, emphasize the desirability of analyzing individual inclusions from well-characterized diamonds if isotope data for inclusions are to be better understood. Nitrogen contents and aggregation state in the core and intermediate zone of the host diamond closely approximate theoretically calculated isotherms based on consideration of experimentally determined nitrogen aggregation kinetics. The nitrogen content of the rim diamond is too low to obtain spectra that allow accurate deconvolution of relative aggregation levels for use in residence time calculations. The aggregation state of nitrogen in the core and intermediate growth zones is compatible with a long, ca. 3 Ga mantle residence time at normal lithospheric temperatures. The similarity of the sulfide inclusion Re-Os model ages to the

  14. Archean Lithosphere Beneath Arctic Canada: Lu-Hf Isotope Systematics for Kimberlite-Hosted Garnet-Peridotites From Somerset Island (United States)

    Schmidberger, S. S.; Simonetti, A.; Francis, D.; Gariepy, C.


    Knowledge of the age of lithospheric mantle underlying the continents provides valuable constraints for the timing of formation and stabilization of Archean cratons. This study reports Lu-Hf isotopic data for garnet-peridotites, and their constituent garnets, from the Nikos kimberlite (100 Ma) on Somerset Island in the Canadian Arctic obtained using a Micromass IsoProbe multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) at GEOTOP-UQAM. The low temperature peridotites (1100 C; 160-190 km) and their 176Hf/177Hf(0.1Ga) isotopic compositions (0.28265-0.28333; \\epsilonHf(0.1Ga)=-2 to +22) are less radiogenic than those of the shallow xenoliths. A Lu-Hf isochron for six peridotites yields a mid Archean age of 3.4\\pm0.3 Ga and an initial 176Hf/177Hf ratio of 0.28101\\pm24. The remaining peridotites (n=9), in contrast, are characterized by extremely high (+35) initial \\epsilonHf(3.4Ga) values, which correlate negatively with their 176Lu/177Hf ratios, suggesting addition of Hf as a result of metasomatic interaction with the host kimberlite. The garnets from the low temperature (3.4 Ga old) peridotites are characterized by high 176Lu/177Hf ratios and define an errorchron age of 1.4\\pm0.2 Ga, which may reflect re-equilibration of Hf during kimberlite magmatism.

  15. Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana, USA (United States)

    Peterman, Zell E.; Thamke, Joanna N.; Futa, Kiyoto; Preston, Todd


    Groundwater, surface water, and soil in the Goose Lake oil field in northeastern Montana have been affected by Cl−-rich oil-field brines during long-term petroleum production. Ongoing multidisciplinary geochemical and geophysical studies have identified the degree and local extent of interaction between brine and groundwater. Fourteen samples representing groundwater, surface water, and brine were collected for Sr isotope analyses to evaluate the usefulness of 87Sr/86Sr in detecting small amounts of brine. Differences in Sr concentrations and 87Sr/86Sr are optimal at this site for the experiment. Strontium concentrations range from 0.13 to 36.9 mg/L, and corresponding 87Sr/86Sr values range from 0.71097 to 0.70828. The local brine has 168 mg/L Sr and a 87Sr/86Sr value of 0.70802. Mixing relationships are evident in the data set and illustrate the sensitivity of Sr in detecting small amounts of brine in groundwater. The location of data points on a Sr isotope-concentration plot is readily explained by an evaporation-mixing model. The model is supported by the variation in concentrations of most of the other solutes.

  16. Using trace element content and lead isotopic composition to assess sources of PM in Tijuana, Mexico (United States)

    Salcedo, D.; Castro, T.; Bernal, J. P.; Almanza-Veloz, V.; Zavala, M.; González-Castillo, E.; Saavedra, M. I.; Perez-Arvízu, O.; Díaz-Trujillo, G. C.; Molina, L. T.


    PM2.5 samples were collected at two urban sites (Parque Morelos (PQM) and CECyTE (CEC)) in Tijuana during the Cal-Mex campaign from May 24 to June 5, 2010. Concentration of trace elements (Mg, Al, Ti, V, Mn, Fe, Co, Ni, Zn, Cu, Ga, As, Se, Rb, Sr, Mo, Cd, Sn, Sb, Ba, La, Ce, and Pb), and Pb isotopic composition were determined in order to study the sources of PM impacting each site. Other chemical analysis (gravimetric, elemental and organic carbon (EC/OC), and polycyclic aromatic hydrocarbons (PAHs)), were also performed. Finally, back-trajectories were calculated to facilitate the interpretation of the chemical data. Trace elements results show that CEC is a receptor site affected by mixed regional sources: sea salt, mineral, urban, and industrial. On the other hand, PQM seems to be impacted mainly by local sources. In particular, Pb at CEC is of anthropogenic, as well as crustal origin. This conclusion is supported by the lead isotopic composition, whose values are consistent with a combination of lead extracted from US mines, and lead from bedrocks in the Mexican Sierras. Some of the time variability observed can be explained using the back-trajectories.

  17. Production of krypton and xenon isotopes in thick stony and iron targets isotropically irradiated with 1600 MeV protons

    CERN Document Server

    Gilabert, E; Lavielle, B; Leya, I; Michel, R; Neumann, S


    Two spherical targets made of gabbro with a radius of 25 cm and of steel with a radius of 10 cm were irradiated isotropically with 1600 MeV protons at the SATURNE synchrotron at Laboratoire National Saturne (LNS)/CEN Saclay, in order to simulate the production of nuclides in meteorites induced by galactic cosmic-ray protons in space. These experiments supply depth-dependent production rate data for a wide range of radioactive and stable isotopes in up to 28 target elements. In this paper, we report results for /sup 78/Kr, /sup 80-86/Kr isotopes in Rb, Sr, Y and Zr and for /sup 124/Xe, /sup 126/Xe, /sup 128-132/Xe, /sup 134/Xe, /sup 136/Xe isotopes in Ba and La. Krypton and xenon concentrations have been measured at different depths in the spheres by using conventional mass spectrometry. Based on Monte-Carlo techniques, theoretical production rates are calculated by folding depth-dependent spectra of primary and secondary protons and secondary neutrons with the excitation functions of the relevant nuclear reac...

  18. Systematic study of the isotopic dependence of fusion dynamics for neutron- and proton-rich nuclei using a proximity formalism

    CERN Document Server

    Ghodsi, O N; Lari, F


    The behaviors of barrier characteristics and fusion cross sections are analyzed by changing neutron over wide range of colliding systems. For this purpose, we have extended our previous study (Eur. Phys. J. A \\textbf{48}, 21 (2012), it is devoted to the colliding systems with neutron-rich nuclei) to 125 isotopic systems with condition of $0.5\\leq N/Z \\leq 1.6$ for their compound nuclei. The AW 95, Bass 80, Denisov DP and Prox. 2010 potentials are used to calculate the nuclear part of interacting potential. The obtained results show that the trend of barrier heights $V_B$ and positions $R_B$ as well as nuclear $V_N$ and Coulomb $V_C$ potentials (at $R=R_B$) as a function of ($N/Z-1$) quantity are non-linear (second-order) whereas the fusion cross sections follow a linear-dependence.

  19. Boron isotope systematics of tourmaline formation in the Sullivan Pb-Zn-Ag deposit, British Columbia, Canada (United States)

    Jiang, S.-Y.; Palmer, M.R.; Slack, J.F.; Shaw, D.R.


    We report here the results of 54 boron isotope analyses of tourmaline associated with the giant Sullivan Pb-Zn-Ag deposit in southeastern British Columbia, Canada. The ??11B values range from -11.1 to -2.9???, which is almost as great as the range found worldwide in tourmalines from 33 massive sulfide deposits and tourmalinites in dominantly clastic metasedimentary terranes. The major control on the overall ??11B values of the Sullivan tourmalinites is the boron source. Potential controls over the large range of the data also include: (1) differences in formation temperatures of the tourmalinites, (2) different stages of tourmaline formation, (3) variations in the proportions of dissolved boron incorporated into the tourmaline (Rayleigh fractionation), (4) seawater entrainment, and (5) post-depositional metamorphism. The boron isotope data at Sullivan are consistent with boron derivation from leaching of footwall clastic sediments. However, the great abundance of tourmaline in the Sullivan deposit suggests that the local clastic sediments were not the sole source of boron, and we argue that non-marine evaporites, buried deep below the orebody, are the most viable source of this additional boron. It is likely that some of the variation in tourmaline ??11B values reflect mixing of boron from these two sources. Comparison of the potential effects of these controls with geologic and other geochemical evidence suggests that major causes for the wide range of ??11B values measured at Sullivan are seawater entrainment and Rayleigh fractionation, although in places, post-depositional alteration and thermal metamorphism were important in determining ??11B values of some of the recrystallized tourmalinites.

  20. Simultaneous spectroscopy of $\\gamma$- rays and conversion electrons: Systematic study of EO transitions and intruder states in close vicinity of mid-shell point in odd-Au isotopes

    CERN Multimedia

    Venhart, M; Grant, A F; Petrik, K

    This proposal focuses on detailed systematic studies of the $\\beta$ /EC-decays of $^{179,181,183,185}$Hg leading to excited states in the neutron-deficient Au isotopes in the vicinity of the N=104 midshell. $\\gamma$-ray, X-ray and conversion electron de-excitations of odd-A Au isotopes will be studied simultaneously. These studies will address important structural questions such as the excitation energies of coexisting states, properties of multiple intruder states (i.e. intruder particles coupled to intruder cores) and mixing of coexisting structures. The unique combination of Hg beam purity and yields make ISOLDE a unique facility for these experiments.

  1. Search for a meteoritic component in impact-melt rocks from the Lonar crater, India - Evidence from osmium isotope systematics (United States)

    Schulz, T.; Luguet, A.; Koeberl, C.


    Introduction: The Lonar crater in western India (Maharashtra) is a bowl-shaped simple impact structure of 1830 m diameter and a depth of 120 m below the rim crest. The crater formed 0.656 × 0.081 Ma ago on the 65 Ma old basaltic lava flows of the Deccan Traps (Jourdan et al. 2010) and is one of the few terrestrial impact structures to have formed in basaltic host-rocks. In the absence of actual meteorite fragments, the impact origin of this structure was supported by the identification of a variety of shock metamorphic features (e.g. Fredriksson et al. 1973). However, clear indications of an extraterrestrial component in impactites based on geochemical studies are absent or remained ambiguous so far (e.g. Osae et al. 2005). As the Os isotope tool has the potential to provide firm constraints on the presence or absence of even very small (meteoritic matter to impactite lithologies (e.g. Koeberl et al. 2002), we conduct a detailed Os isotope study of a variety of unshocked host-basalts (target rocks) and impactites (impact-melt rocks) from the Lonar crater. Samples and Method: All samples analyzed in this study were collected in 2000 and 2001 and were geochemically characterized by Osae et al. (2005). Osmium (and additional PGE) analyses were performed on about 2 g whole rock powders, which were spiked with a mixed 190Os,185Re,191Ir,194Pt tracer, and digested via high pressure Asher using inverse aqua regia. Osmium solvent extraction and microdistillation were performed as described by Cohen and Waters (1996). Osmium isotopic compositions were measured using a TRITON N-TIMS at the Department of Lithospheric Research in Vienna. Results and Discussion: Osmium data on seven target and nine impact melt rocks reveal 187Os/188Os ratios ranging from ~0.38 to ~2.23 for the target rocks and from ~0.22 to ~0.59 for the nine analyzed impact melt rocks, whereas Os concentrations range from ~7.1 to ~31.6 ppt and ~7.2 to ~134 ppt, respectively. Although in the typical range for

  2. Provenance and sedimentary environments of the Proterozoic São Roque Group, SE-Brazil: Contributions from petrography, geochemistry and Sm-Nd isotopic systematics of metasedimentary rocks (United States)

    Henrique-Pinto, R.; Janasi, V. A.; Tassinari, C. C. G.; Carvalho, B. B.; Cioffi, C. R.; Stríkis, N. M.


    The Proterozoic metasedimentary sequences exposed in the São Roque Domain (Apiaí Terrane, Ribeira Belt, southeast Brazil) consist of metasandstones and meta-felspathic wackes with some volcanic layers of within-plate geochemical signature (Boturuna Formation), a passive margin turbidite sequence of metawackes and metamudstones (Piragibu Formation), and volcano-sedimentary sequences with MORB-like basalts (Serra do Itaberaba Group; Pirapora do Bom Jesus Formation). A combination of zircon provenance studies in metasandstones, whole-rock geochemistry and Sm-Nd isotopic systematics in metamudstones was used to understand the provenance and tectonic significance of these sequences, and their implications to the evolution of the Precambrian crust in the region. Whole-rock geochemistry of metamudstones, dominantly from the Piragibu Formation, points to largely granitic sources (as indicated for instance by LREE-rich moderately fractionated REE patterns and subtle negative Eu anomalies) with some mafic contribution (responding for higher contents of Fe2O3, MgO, V, and Cr) and were subject to moderate weathering (CIA - 51 to 85). Sm-Nd isotope data show three main peaks of Nd TDM ages at ca. 1.9, 2.1 and 2.4 Ga; the younger ages define an upper limit for the deposition of the unit, and reflect greater contributions from sources younger than the >2.1 Ga basement. The coincident age peaks of Nd TDM and U-Pb detrital zircons at 2.1-2.2 Ga and 2.4-2.5 Ga, combined with the possible presence of a small amount of zircons derived from mafic (gabbroid) sources with the same ages, as indicated by a parallel LA-ICPMS U-Pb dating study in metapsammites, are suggestive that these were major periods of crustal growth in the sources involving not only crust recycling but also some juvenile addition. A derivation from similar older Proterozoic sources deposited in a passive margin basin is consistent with the main sedimentary sequences in the São Roque Domain being broadly coeval and

  3. Systematical study of high-spin rotational bands in neutron-deficient Kr isotopes by the extended projected shell model (United States)

    Wu, Xin-Yi; Ghorui, S. K.; Wang, Long-Jun; Kaneko, K.; Sun, Yang


    We analyze the high-spin structure of the even-even 72-80Kr isotopes using the Projected Shell Model (PSM). With the help of the Pfaffian formulas, we have vigorously extended the quasi-particle (qp) basis of the PSM code and applied in this mass region for the first time. We consider a sufficiently large multi-qp configuration space in order to describe high-spin rotational behavior. The results show that the calculation can reproduce most of the known rotational bands with positive- or negative-parity. Moreover, some side bands appearing in the near-yrast region are predicted. The main structure for each band is discussed in terms of multi-qp configurations. The variations in moment of inertia with spin are explained in terms of successive band crossings among the 2-qp, 4-qp, 6-qp, and 8-qp states. The B (E 2) transition probabilities in these bands are also calculated. To further understand the high-spin behavior of these neutron-deficient nuclei and to confirm predictions of the present work, good high-spin data, especially for B (E 2) transitions, are called for.

  4. Chemical and Isotopic Heterogeneities in the Deep Earth:Importance of Lower Mantle Carbonate-rich Melts (United States)

    Collerson, K. D.; Williams, Q.; Murphy, D.


    Pb isotopic compositions. HIMU appears to be the residue of LM melting, and thus is indicative of a buoyant deeply-derived component. Thus, U/Pb, Th/Pb, Rb/Sr, and Sm/Nd ratios of kimberlite and carbonatite likely reflect mode of the LM mineral assemblage being melted, as well as the buoyancy of melts and residues. The CO2-rich nature of kimberlite and carbonatite magmas is clearly important for melt transport in LM- derived plumes. Carbonate phases are stable at high pressures [e.g., 12] and available elastic and density data on carbonate and C-bearing melts show that LM CO2-rich melts are less dense than their source, and are able to migrate, in contrast to LM silicate melts. C-enrichment thus allows extraction of deep mantle melts. Escape of these LM-derived melts provides a mechanism to explain transfer of mantle isotope heterogeneity, as well as the rare gas isotope systematics of plume magmas. [1] Zindler, A. & Hart, S., 1986. AREPS. 14: 493-571. [2] Bell, K. & Tilton, G.R., 2001. J. Pet. 42: 1927-1945. [3] Murphy, D., Collerson, K.D. & Kamber, B.S., 2002. J. Pet. 43: 981-1001. [4] Smith, C.B., 1983. Nature, 304: 51-54. [5] Kamber, B.S. & Collerson, K.D., 1999. JGR, 104: 25479-25491. [6] Tachibana, Y. et al., 2006. Geology, 34:273-276. [7] Sasada, T. et al., 1997. GCA, 61: 4219-4228. [8] Tolstikhin, I.N. et al., 2002. GCA, 66: 881-901. [9] Yokochi, R. & Marty, B. 2004. EPSL, 225, 77-88. [10] Fukao, Y. et al., 2001. Rev. Geophys., 39: 291-323. [11] Hayman, P.C. et al., 2005. CMP. 149 430-445 [12] Isshiki M. et al., 2003. Nature, 427, 60-63.

  5. The Late Devonian Frasnian-Famennian (F/F) biotic crisis: Insights from δ13C carb, δ13C org and 87Sr / 86Sr isotopic systematics (United States)

    Chen, Daizhao; Qing, Hairuo; Li, Renwei


    A severe biotic crisis occurred during the Late Devonian Frasnian-Famennian (F/F) transition (± 367 Myr). Here we present δ13C carb, δ13C org and 87Sr / 86Sr isotopic systematics, from identical samples of two sections across F/F boundary in South China, which directly demonstrate large and frequent climatic fluctuations (˜200 kyr) from warming to cooling during the F/F transition. These climate fluctuations are interpreted to have been induced initially by increased volcanic outgassing, and subsequent enhanced chemical weathering linked to the rapid expansion of vascular plants on land, which would have increased riverine delivery to oceans and primary bioproductivity, and subsequent burial of organic matter, thereby resulting in climate cooling. Such large and frequent climatic fluctuations, together with volcanic-induced increases in nutrient (e.g., biolimiting Fe), toxin (sulfide) and anoxic water supply, and subsequent enhanced riverine fluxes and microbial bloom, were likely responsible for the stepwise faunal demise of F/F biotic crisis.

  6. Re-Os isotope systematics in black shales from the Lesser Himalaya: their chronology and role in the 187Os/ 188Os evolution of seawater (United States)

    Singh, Sunil K.; Trivedi, J. R.; Krishnaswami, S.


    Re and Os abundances and Os isotope systematics have been measured in a number of black shales sampled from outcrops and two underground phosphorite mines, Maldeota and Durmala, in the Lesser Himalaya. The Re and Os concentrations in these samples exhibit wide range, 0.2 to 264 ng/g and 0.02 to 13.5 ng/g, respectively, with a mean Re/Os of ˜25. The 187Os/ 188Os of these samples also show a broad range 1.02 to 11.6, with many of them far more radiogenic than the currently eroding continental crust. The black shales from the Maldeota and Durmala mines, collected a few meters above the Krol-Tal (Pc-C) boundary and occurring in the same stratigraphic horizon, yield 187Re- 187Os isochron ages of 554 ± 16 and 552 ± 22 Ma, respectively, consistent with fossil evidences and those assigned for the Pc-C boundary at various other locations. These results indicate closed system behaviour of Re and Os in these mine samples and reaffirm the validity of 187Re- 187Os pair to date organic-rich sediments. The age of these mine samples from the outer belt seems to be a few hundred millions of years younger than the preliminary Re-Os age of 839 ± 138 Ma for black shales from Theog, collected from the inner belt. These initial results lean toward the hypothesis that the inner belt sediments were deposited earlier than the outer belt; however, more analyses of black shales are needed to confirm this. The role of weathering black shales from the Himalaya in contributing to the Os isotope evolution of seawater over the past ˜25 Ma was assessed using a simple budget model for seawater Os and assuming values for Os fluxes and 187Os/ 188Os based on the available limited data on Os concentration and its 187Os/ 188Os in rivers and oceans. These calculations indicate that the required contributions from black shale weathering to account for the entire increase in oceanic 187Os/ 188Os over the past ˜16 Ma is difficult to satisfy by varying only the Os flux from HTP rivers ( 187Os/ 188Os

  7. Saltpan impact crater, South Africa: Geochemistry of target rocks, breccias, and impact glasses, and osmium isotope systematics (United States)

    Koeberl, Christian; Reimold, Wolf Uwe; Shirey, Steven B.


    The Pretoria Saltpan crater is a well-preserved 220,000 year-old, 1.13 km-diameter, simple impact crater. The crater was formed in Nebo granites of the Bushveld Complex. Some minor intrusions thought to be younger than the Nebo granite are present at the crater and have earlier been believed to support a volcanic origin of the structure, but recent geological studies showed them to be part of the regional geology and of Proterozoic age. We studied the petrology and geochemistry of fourteen target granite samples, three suevitic breccias, nine intrusive rocks, as well as melt agglutinates, handpicked impact glass fragments and sulfide spherules from the Saltpan impact crater. Unconsolidated suevitic breccias recovered from different depths in the crater were found to contain abundant evidence of shock metamorphism. The target rock granites show only limited compositional variability. The major and trace element composition of the bulk breccia is very similar to that of average basement granite. Impact glass fragments recovered from the unconsolidated suevitic breccia have a CIPW normative composition similar to that of the basement granites. No evidence for admixture from any of the minor intrusions was found. The similarity of trace element abundances and ratios, and REE patterns between impact glasses and granites favors derivation of the glasses from the granites. The impact glass fragments show considerable enrichments of Mg, Cr, Fe, Co, Ni, and Ir, compared to the basement granites. The abundances of these elements in the glasses (after correction for indigenous concentrations) can be explained by admixture of about ≤ 10% of a chondritic component. High Ir concentrations (≈ 100 ppb) have been found in sulfide spherule samples, which may complement the (lower) Ir abundances in the glasses and could indicate some fractionation during impact. Re-Os isotopic studies were applied to further investigate the presence of a meteoritic component in the suevitic

  8. Identification of Marchfeld asparagus using Sr isotope ratio measurements by MC-ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Swoboda, S.; Brunner, M.; Boulyga, S.F.; Galler, P.; Prohaska, T. [University of Natural Resources and Applied Life Sciences, Department of Chemistry-VIRIS Project, Vienna (Austria); Horacek, M. [Austrian Research Centers GmbH, Seibersdorf (Austria)


    This work focuses on testing and application of Sr isotope signatures for the fast and reliable authentication and traceability of Asparagus officinalis originating from Marchfeld, Austria, using multicollector inductively coupled plasma mass spectrometry after optimised Rb/Sr separation. The major sample pool comprises freeze-dried and microwave-digested asparagus samples from Hungary and Slovakia which are compared with Austrian asparagus originating from the Marchfeld region, which is a protected geographical indication. Additional samples from Peru, the Netherlands and Germany were limited in number and allowed therefore only restricted statistical evaluation. Asparagus samples from Marchfeld were harvested within two subsequent years in order to investigate the annual variation. The results show that the Sr isotope ratio is consistent within these 2 years of investigation. Moreover, the Sr isotope ratio of total Sr in soil was found to be significantly higher than in an NH{sub 4}NO{sub 3} extract, reflecting the mobile (bioavailable) phase. The isotope composition in the latter extract corresponds well to the range found in the asparagus samples in Marchfeld, even though the concentration of Sr in asparagus shows no direct correlation to the concentration of Sr in the mobile phase of the soil. The major question was whether the 'Marchfelder Spargel' can be distinguished from samples from the neighbouring countries of Hungary and Slovakia. According to our findings, they can be clearly (100%) singled out from the Hungarian samples and can be distinguished from the Slovakian asparagus samples with a probability of more than 80%. (orig.)

  9. Oxygen isotope systematics in the aragonite-CO2-H2O-NaCl system up to 0.7 mol/kg ionic strength at 25 °C (United States)

    Kim, Sang-Tae; Gebbinck, Christa Klein; Mucci, Alfonso; Coplen, Tyler B.


    To investigate the oxygen isotope systematics in the aragonite-CO2-H2O-NaCl system, witherite (BaCO3) was precipitated quasi-instantaneously and quantitatively from Na-Cl-Ba-CO2 solutions of seawater-like ionic strength (I = 0.7 mol/kg) at two pH values (~7.9 and ~10.6) at 25 °C. The oxygen isotope composition of the witherite and the dissolved inorganic carbon speciation in the starting solution were used to estimate the oxygen isotope fractionations between HCO3¯ and H2O as well as between CO3 2 and H2O. Given the analytical error on the oxygen isotope composition of the witherite and uncertainties of the parent solution pH and speciation, oxygen isotope fractionation between NaHCO3° and HCO3¯, as well as between NaCO3¯ and CO3 2, is negligible under the experimental conditions investigated. The influence of dissolved NaCl concentration on the oxygen isotope fractionation in the aragonite-CO2-H2O-NaCl system also was investigated at 25 °C. Aragonite was precipitated from Na-Cl-Ca-Mg-(B)-CO2 solutions of seawater-like ionic strength using passive CO2 degassing or constant addition methods. Based upon our new experimental observations and published experimental data from lower ionic strength solutions by Kim et al. (2007b), the equilibrium aragonite-water oxygen isotope fractionation factor is independent of the ionic strength of the parent solution up to 0.7 mol/kg. Hence, our study also suggests that the aragonite precipitation mechanism is not affected by the presence of sodium and chloride ions in the parent solution over the range of concentrations investigated.

  10. Study of the argillaceous fraction of sedimentary sequences of Meuse and Gard. Reconstitution of the diagenetic history and of the physico-chemical characteristics of the targets. Mineralogical, geochemical and isotopic aspects; Etude de la fraction argileuse de sequences sedimentaires de la Meuse et du Gard. Reconstitution de l'histoire diagenetique et des caracteristiques physico-chimiques des cibles. Aspects mineralogiques, geochimiques et isotopiques

    Energy Technology Data Exchange (ETDEWEB)

    Rousset, D


    Very low permeable argillaceous rocks like Callovo-Oxfordian clay-stones or Vraconian siltstones were chosen to host a research laboratory built to determine the physico-chemical properties of the host formations for a potential underground disposal of radioactive waste. Knowledge and understanding of post-sedimentary modifications are of prime importance for definition of these properties; evaluation and quantification of the post-sedimentary changes represent the aim of this study, focused specifically on the clay material of the sequences. Samples were taken from two drillings (HTM102 and MAR501). In the HTM102 core samples, illite and mixed-layers illite/smectite are the dominant clay components of most clay fractions. Systematic SEM and TEM observations and isotopic K-Ar and Rb-Sr analyses pointed to diagenetic neo-formations of carbonates (calcite, dolomite) and clays. For instance, veils and laths of authigenic clay particles around old detrital ones can distinctly be observed. The epoch, duration and extent of the diagenetic activity(ies) are difficult to evaluate because of an overall detrital contribution even in the finest granulometric fractions. However; analysis of a bentonite layer in the sequence provides a diagenetic reference for the authigenic clay material. Correlation between relative sea level and authigenesis of smectite-rich mineral has been outlined. Chemistry of diagenetic fluids also seems to be reliable with sea level variations. These observations argue in favour of diagenetic activities limited in restricted rock volumes. The case study of MAR501 is close to the HTM102 one: smectite-rich illite/smectite mixed-layers represent the major component of the clay fraction and K-Ar values argue ire the sense of a mixing between detrital and younger clay populations. Diagenetic glauconites in the sequence yield are age close to 93,7 {+-}0,3 Ma for Vraconian level, in agreement with stratigraphical data. The case study of a clay-filled fault

  11. The estuarine chemistry and isotope systematics of 234,238U in the Amazon and Fly Rivers (United States)

    Swarzenski, P.; Campbell, P.; Porcelli, D.; McKee, B.


    Natural concentrations of 238U and ??234U values were determined in estuarine surface waters and pore waters of the Amazon and Fly (Papua New Guinea) Rivers to investigate U transport phenomena across river-dominated land-sea margins. Discharge from large, tropical rivers is a major source of dissolved and solid materials transported to the oceans, and are important in defining not only oceanic mass budgets, but also terrestrial weathering rates. On the Amazon shelf, salinity-property plots of dissolved organic carbon, pH and total suspended matter revealed two vastly contrasting water masses that were energetically mixed. In this mixing zone, the distribution of uranium was highly non-conservative and exhibited extensive removal from the water column. Uranium removal was most pronounced within a salinity range of 0-16.6, and likely the result of scavenging and flocculation reactions with inorganic (i.e., Fe/Mn oxides) and organic colloids/particles. Removal of uranium may also be closely coupled to exchange and resuspension processes at the sediment/water interface. An inner-shelf pore water profile indicated the following diagenetic processes: extensive (???1 m) zones of Fe(III) - and, to a lesser degree, Mn(IV) - reduction in the absence of significant S(II) concentrations appeared to facilitate the formation of various authigenic minerals (e.g., siderite, rhodocrosite and uraninite). The pore water dissolved 238U profile co-varied closely with Mn(II). Isotopic variations as evidenced in ??234U pore waters values from this site revealed information on the origin and history of particulate uranium. Only after a depth of about 1 m did the ??234U value approach unity (secular equilibrium), denoting a residual lattice bound uranium complex that is likely an upper-drainage basin weathering product. This suggests that the enriched ??234U values represent a riverine surface complexation product that is actively involved in Mn-Fe diagenetic cycles and surface

  12. Effect of Wood Aging on Wine Mineral Composition and (87)Sr/(86)Sr Isotopic Ratio. (United States)

    Kaya, Ayse D; Bruno de Sousa, Raúl; Curvelo-Garcia, António S; Ricardo-da-Silva, Jorge M; Catarino, Sofia


    The evolution of mineral composition and wine strontium isotopic ratio (87)Sr/(86)Sr (Sr IR) during wood aging were investigated. A red wine was aged in stainless steel tanks with French oak staves (Quercus sessiliflora Salisb.), with three industrial scale replicates. Sampling was carried out after 30, 60, and 90 days of aging, and the wines were evaluated in terms of general analysis, phenolic composition, total polysaccharides, multielement composition, and Sr IR. Li, Be, Mg, Al, Sc, Ti, V, Mn, Co, Ni, Cu, Zn, Ga, Ge, As, Rb, Sr, Y, Zr, Mo, Sb, Cs, Ba, Pr, Nd, Sm, Eu, Dy, Ho, Er, Yb, Lu, Tl, and Pb elements and (87)Sr/(86)Sr were determined by quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS) and Na, K, Ca, and Fe by flame atomic absorption spectrometry (FAAS). Two-way ANOVA was applied to assess wood aging and time effect on Sr IR and mineral composition. Wood aging resulted in significantly higher concentrations of Mg, V, Co, Ni, and Sr. At the end of the aging period, wine exhibited statistically identical Sr IR compared to control. Study suggests that wood aging does not affect (87)Sr/(86)Sr, not precluding the use of this parameter for wine traceability purposes.

  13. Characterisation and origin of New Zealand nephrite jade using its strontium isotopic signature (United States)

    Adams, C. J.; Beck, R. J.; Campbell, H. J.


    Nephrite jade occurs in three terranes (Dun Mountain-Maitai, Caples and Torlesse) in New Zealand, where it is associated with ultramafic and ophiolitic rocks in narrow metasomatic reaction zones at the margins of serpentinite (having harzburgite/gabbro/dolerite precursors) with silicic metasediments and metavolcanics. True nephrite fabrics are developed only locally where marginal shearing is intense, and late in the metamorphic history. 87Sr/ 86Sr values of these nephrites do not display the primitive values of their gabbro/dolerite precursor component i.e. 0.7030-0.7035, as expected if formed during serpentinisation. Rather, the nephrites have more evolved 87Sr/ 86Sr values inherited from the metasediment component at a later stage, and which fall within particular terrane groups: Dun Mountain-Maitai 0.7045-0.7060, Caples 0.7058-0.7075 and Torlesse 0.7085-0.7110. Rb-Sr ages and initial 87Sr/ 86Sr ratios of the metasediment component from in situ nephrite localities, when compared with their counterparts throughout the host terrane, show that nephrite Sr isotopic compositions are characteristic of the host terrane.

  14. Lead isotopic evidence for selective uptake of radium in illite

    Energy Technology Data Exchange (ETDEWEB)

    Hidaka, H.; Horie, K. [Department of Earth and Planetary Systems Science, Hiroshima University Higashi-Hiroshima 739-8526 (Japan); Gauthier-Lafaye, F. [Centre de Geochimie de la Surface, UMR7517-CNRS-ULP, 67084 Strasbourg (France)


    Full text of publication follows: Radium has no stable isotopes. {sup 226}Ra having the longest half-life (T{sub 1/2} = 1600 year) among radium radioisotopes exists as a precursor of decay product from {sup 238}U in nature, and finally decays to the stable isotope {sup 206}Pb. Long-lived nuclides such as {sup 226}Ra may be profoundly fractionated from their parents in association with intense geochemical events in the terrestrial environments. Enrichment of Ra resulted from vegetation cycle and selective uptake into clay minerals has been reported [1,2]. It is of particular interest to understand the geochemical behaviors of Ra from the viewpoint of long-termed repository safety of radio-nuclear waste. We report here geochemical evidence of selective uptake of Ra ({sup 226}Ra) into clay minerals studied from the Pb isotopic compositions. The sample from sandstone layer at underground drift close to natural reactor zone 13 at the Oklo uranium deposits, Gabon. Several tiny illite grains sized about 100 {mu}m were found in fine calcite veins with 0.1 to 2 mm width in quartz matrix texture. Isotopic analyses of Pb and some related elements (U, Rb, Sr, Cs and Ba) in individual minerals were carried out by a Sensitive High Resolution Ion Microprobe (SHRIMP) at Hiroshima University. The Pb isotopic data of quartz and calcite in the sample provide the geochronological information corresponding to the formation of 2.15 billion year-old basement rocks and the occurrence of later hydrothermal activity in this region at 0.88 billion years, respectively. On the other hand, illite shows high enrichment of {sup 206}Pb, which cannot be explained simply from normal U decays. {sup 206}Po-enriched illite grains also show a strong enrichment of Ba. Such an enrichment of Ba is not observed in the neighboring minerals of illite grains. Considering that Ba has been used as a chemical tracer of {sup 226}Ra because of the chemical similarities between Ba and Ra, our result strongly


    Directory of Open Access Journals (Sweden)

    Riccardo Petrini


    Full Text Available O, H, B and Sr isotopes were identified from surface-waters, ground-waters and waters percolating in soils at the Pialassa Baiona lagoon and nearby inland areas. The preliminary data demonstrate the occurrence of both conservative mixtures between seawater and freshwaters and cation exchange at the salt/fresh water interface during the intrusion. The O and H isotopes indicate that the freshwater component in the binary mixing had the isotopic features of the rainwater from Apennine catchments. Coupled O-H-B isotopes also show that the major contribution of the moving seawater was confined to the deeper aquifers and some of the soil waters. The Sr isotopes highlight the role of cation exchanges when seawater flushes freshwater aquifers, and allow the recognition of the different components of the solute. Deviations from these processes as revealed by B isotopes are interpreted as the evidence of possible anthropogenic inputs.

  16. Chemical and isotopic relationship of mafic and felsic magmas in a sub-volcanic reservoir: The Guadalupe Igneous Complex (GIC), Sierra Nevada, California (United States)

    Ratschbacher, B. C.; Paterson, S. R.; Putirka, K. D.


    It is commonly believed that the interaction of mafic and felsic melts in the form of mixing/mingling as well as their genetic link in the form of fractionation play an important role in the formation of continental crust. The combination of whole rock major element content and isotopic signature, as presented in this study, is a powerful tool to identify the origin and genetic relation of mafic and felsic melts in magmatic arc settings where new material is added to the crust. The GIC is part of the Jurassic Sierran magmatic arc exposed in the Western Metamorphic Belt and contains two main units consisting of mafic (up to 9 wt. % MgO and 49 to 56 wt. % SiO2) and felsic (around 75 wt. % SiO2) rocks, which locally mingled and mixed to different proportions at a shallow emplacement level. In the lower parts of the GIC, fine-grained gabbros gradually evolve into the overlying diorite to meladiorite unit. A mingling zone separates these mafic rocks from granites, granophyres and overlying rhyolites in the upper part of the complex. Major element whole rock analyses show that the GIC is bimodal with gabbros and granitoids acting as endmembers in SiO2, MgO and CaO contents. For Al2O3, Na2O and other element oxides, the different units strongly overlap in compositions. Recent work using single grain zircon U-Pb dating found ages for both the gabbros and the felsic part of the complex of 151 Ma within uncertainty (Saleeby et al., 1989; Ernst et al., 2009, and unpublished data from this study). These ages are in agreement with Rb-Sr data from each unit, which fall on a 152×7 Ma isochron and therefore imply closed-system evolution. Major oxide data show that assimilation of the exposed surrounding host rocks is unlikely and cannot serve as an assimilant to reproduce the observed felsic compositions from the gabbroic rocks. Sri, Nd and Pb systematics show that all units except for capping granophyres and rhyolites plot close together implying a shared parental melt, which is

  17. Resilience of cold-water scleractinian corals to ocean acidification: Boron isotopic systematics of pH and saturation state up-regulation (United States)

    McCulloch, Malcolm; Trotter, Julie; Montagna, Paolo; Falter, Jim; Dunbar, Robert; Freiwald, André; Försterra, Günter; López Correa, Matthias; Maier, Cornelia; Rüggeberg, Andres; Taviani, Marco


    The boron isotope systematics has been determined for azooxanthellate scleractinian corals from a wide range of both deep-sea and shallow-water environments. The aragonitic coral species, Caryophyllia smithii, Desmophyllum dianthus, Enallopsammia rostrata, Lophelia pertusa, and Madrepora oculata, are all found to have relatively high δ11B compositions ranging from 23.2‰ to 28.7‰. These values lie substantially above the pH-dependent inorganic seawater borate equilibrium curve, indicative of strong up-regulation of pH of the internal calcifying fluid (pHcf), being elevated by ˜0.6-0.8 units (ΔpH) relative to ambient seawater. In contrast, the deep-sea calcitic coral Corallium sp. has a significantly lower δ11B composition of 15.5‰, with a corresponding lower ΔpH value of ˜0.3 units, reflecting the importance of mineralogical control on biological pH up-regulation. The solitary coral D. dianthus was sampled over a wide range of seawater pHT and shows an approximate linear correlation with ΔpHDesmo = 6.43 - 0.71pHT (r2 = 0.79). An improved correlation is however found with the closely related parameter of seawater aragonite saturation state, where ΔpHDesmo = 1.09 - 0.14Ωarag (r2 = 0.95), indicating the important control that carbonate saturation state has on calcification. The ability to up-regulate internal pHcf, and consequently Ωcf, of the calcifying fluid is therefore a process present in both azooxanthellate and zooxanthellate aragonitic corals, and is attributed to the action of Ca2+-ATPase in modulating the proton gradient between seawater and the site of calcification. These findings also show that the boron isotopic compositions (δ11Bcarb) of aragonitic corals are highly systematic and consistent with direct uptake of the borate species within the biologically controlled extracellular calcifying medium. We also show that the relatively strong up-regulation of pH and consequent elevation of the internal carbonate saturation state (Ωcf ˜8

  18. Constraining the role of iron in environmental nitrogen transformations. Dual stable isotope systematics of abiotic NO2- reduction by Fe(II) and its production of N2O

    Energy Technology Data Exchange (ETDEWEB)

    Johnston, David [Harvard Univ., Cambridge, MA (United States); Wankel, Scott David [Woods Hole Oceanographic Inst., MA (United States); Buchwald, Carolyn [Woods Hole Oceanographic Inst., MA (United States); Hansel, Colleen [Woods Hole Oceanographic Inst., MA (United States)


    Redox reactions involving nitrogen and iron have been shown to have important implications for mobilization of priority contaminants. Thus, an understanding of the linkages between their biogeochemical cycling is critical for predicting subsurface mobilization of radionuclides such as uranium. Despite mounting evidence for biogeochemical interactions between iron and nitrogen, our understanding of their environmental importance remains limited. Here we present an investigation of abiotic nitrite (NO2-) reduction by Fe(II) or ‘chemodenitrification,’ and its relevance to the production of nitrous oxide (N2O), specifically focusing on dual (N and O) isotope systematics under a variety of environmentally relevant conditions. We observe a range of kinetic isotope effects that are regulated by reaction rates, with faster rates at higher pH (~8), higher concentrations of Fe(II) and in the presence of mineral surfaces. A clear non-linear relationship between rate constant and kinetic isotope effects of NO2- reduction was evident (with larger isotope effects at slower rates) and is interpreted as reflecting the dynamics of Fe(II)-N reaction intermediates. N and O isotopic composition of product N2O also suggests a complex network of parallel and/or competing pathways. Our findings suggest that NO2- reduction by Fe(II) may represent an important abiotic source of environmental N2O, especially in iron-rich environments experiencing dynamic redox variations. This study provides a multi-compound, multi-isotope framework for evaluating the environmental occurrence of abiotic NO2- reduction and N2O formation, helping future studies constrain the relative roles of abiotic and biological N2O production pathways.

  19. Sulfur Isotope Systematics and the Link Between Fluctuating Sulfate Levels and P Recycling in a Low Sulfate, Permanently Anoxic Lake (Lake McCarrons, MN): Implications for the Precambrian Rise of Oxygen (United States)

    Gomes, M. L.; Hurtgen, M. T.


    Seawater sulfate concentrations have been used to track the rise of oxygen in the Precambrian ocean-atmosphere system because the primary mode of sulfate delivery to the ocean is the oxidative weathering of sulfides on land. Ancient seawater sulfate concentrations have been inferred from the extent of sulfur (S) isotope fractionation incurred during bacterial sulfate reduction (BSR) where organisms preferentially utilize 32S (over 34S) in the process of reducing of sulfate to sulfide. Within this context, increased variability in δ34Spyrite values in Proterozoic (~2.3 Ga) sediments—along with a corresponding increase in the isotopic difference between sulfate and pyrite (Δ34S)—has been attributed to an increase in seawater sulfate concentrations (from 1 mM) and inferentially Earth-surface oxygen levels. However, most S isotope studies have been calibrated using modern marine sediments that contain sulfate-reducing bacteria that are adapted to the high concentration of sulfate in the modern ocean (~28mM). In order to better understand S isotope systematics within a low sulfate system and to improve our interpretive construct for S isotope results generated from ancient strata, we explore the magnitude of S isotope fractionations associated with microbial activity in the water column and sediments of a low sulfate (isotope difference between surface water sulfate and bottom water sulfide is ~5‰ (Δ34S) while in situ S isotope fractionations associated with BSR at the sediment-water interface approach 35‰; (3) sulfate reduction rates in the upper 3 cm of organic carbon rich sediment are ~0.1 µM cm-3 d-1, an order of magnitude lower than those recorded under higher (modern marine) sulfate concentrations; and (4) sulfate concentrations influence the efficiency of P recycling (as determined via bag incubation experiments). Here, we suggest that an increase in sulfate levels at ~2.3 Ga, as indicated by larger Δ34S values recorded in strata of this age

  20. Petrogenesis and significance of the Hongshan syenitic pluton,South Taihang: zircon SHRIMP U-Pb age, chemical compositions and Sr-Nd isotopes

    Institute of Scientific and Technical Information of China (English)


    The Hongshan syenitic pluton (South Taihang) is mainly made up of hornblende syenite and minor granite. SHRIMP zircon dating yields a U-Pb age of 135 ± 2.7 Ma for the emplacement of the pluton, while biotite Rb-Sr isotopic data give an isochron of 120.3 ± 2.4 Ma. Hongshan syenites show low silica, high alkalis and LILE such as Sr, and exhibit negligible Eu anomalies or slightly positive anomalies in the REE patterns. The syenites show quite enriched isotopic compositions with Isr from 0. 7052 to 0. 7102 and εNd( t ) from - 7.5 to - 11. 1. Petrogenesis of the pluton can be that partial melting of an enriched lithospheric mantle gave birth to an alkali basaltic magma, which subsequently underplated in the lower crust and experienced a coupled fractionation of ferromagnesian phases like pyroxene and hornblende and minor ( < 10 % ) contamination of lower continental crust, producing the Hongshan syenites that partially evolved into granite through combined fractionation of hornblende and feldspar. Our data are not in agreement with a previous model that the syenites originated from melting of lower crust in a thickened crust circumstance, and thus do not support the speculation of "East China Plateau" in the Mesozoic.

  1. Origin and time-space distribution of hydrothermal systems in east-central Australian sedimentary basins: Constraints from illite geochronology and isotope geochemistry. (United States)

    Uysal, I. Tonguç


    Some well-known precious mineral deposits and hydrocarbon resources occur extensively in east-central Australian sedimentary Basins. The metal occurrences are abundant in northwestern and eastern part of Queensland, whereas no significant deposits are known in large areas further south, which may, however, be hidden beneath the Jurassic-Cretaceous sedimentary basins. Important hydrocarbon resources exist within the Jurassic-Cretaceous sedimentary rocks at relatively shallow depths, of which the distribution represent zones of high paleo-geothermal gradients. This study examines the time-space distribution in relation to the regional tectonic history of concealed metal deposits and areas of high paleo-geothermal gradient leading to hydrocarbon maturation. To this end, authigenic illitic clay minerals representing various locations and stratigraphic depths in east-central Australia were investigated, of which the Rb-Sr and Ar-Ar geochronology and stable isotope geochemistry assist in delineating zones of hydrothermal systems responsible for hydro-carbon maturation/migration and potentially ore deposition. The Late Carboniferous - Early Permian crustal extension that affected large areas of eastern Australia and led to the epithermal mineralisations (e.g., the Drummond Basin) is also recorded in northern South Australia and southwest Queensland. A Late Triassic - Early Jurassic tectonic event being responsible for coal maturation and gas generation in the Bowen Basin and the epithermal mineralisation in the North Arm goldfield in SE Queensland likewise affected the areas much further west in Queensland. Some illites from the basement in outback Queensland and fault gouges from the Demon Fault in NE New South Wales yield younger Rb-Sr and Ar-Ar ages indicating the effect of hydrothermal processes as a result of a Middle-Upper Jurassic tectonic event. The majority of illite samples from the crystalline basement rocks, Permian Cooper Basin, and Jurassic

  2. Isotopic (U-Pb, Nd) and geochemical constraints on the origins of the Aileu and Gondwana sequences of Timor (United States)

    Boger, S. D.; Spelbrink, L. G.; Lee, R. I.; Sandiford, M.; Maas, R.; Woodhead, J. D.


    Detrital zircon U-Pb age data collected from the argillitic sedimentary rocks of the Timorese Aileu Complex and Gondwana Sequence indicate that both units were derived from a common source containing 200-600 Ma, 900-1250 Ma and 1450-1900 Ma zircon. The modally most significant age population within this range of ages dates to c. 260 Ma. The observed spectrum of ages can be traced to the eastern active margin of Pangaea and its immediate foreland, which today is best exposed along the northeast coast of Australia. Compared to the relative homogeneity of the detrital zircon age data, geochemical and Nd isotopic data show that the mudstones of the Aileu Complex are on average more siliceous, have higher K2O/Na2O, Rb/Sr, Th/Sc and yield notably older Nd TDM model ages when compared to those from the Gondwana Sequence. These data are interpreted to suggest that, although both sequences share a common east Pangaea provenance, they were eroded from different sections of this active margin and deposited in spatially separated basins. The present proximity of these units is a result of their tectonic juxtaposition during the Pliocene to Recent collision between the northern edge of the Indo-Australia plate and the Banda Arc.

  3. Deformation of C isotopes

    CERN Document Server

    Kanada-Enyo, Y


    Systematic analysis of the deformations of proton and neutron densities in even-even C isotopes was done based on the method of antisymmetrized molecular dynamics. The $E2$ transition strength was discussed in relation to the deformation. We analyze the $B(E2;2^+_1\\to 0^+_1)$ in $^{16}$C, which has been recently measured to be abnormally small. The results suggest the difference of the deformations between proton and neutron densities in the neutron-rich C isotopes. It was found that stable proton structure in C isotopes plays an important role in the enhancement the neutron skin structure as well as in the systematics of $B(E2)$ in the neutron-rich C.

  4. Geochemistry and chronology of Se' ertengshan greenstone, Inner Mongolia

    Institute of Scientific and Technical Information of China (English)

    LIU Jianzhong; WANG Lili; ZHANG Fuqin; LI Chunlai; ZOU Yongliao; OUYANG Ziyuan; XU Lin


    This paper deals with the meta-mafic volcanic rocks of the Gongyiming iron deposit at Baotou, Inner Mongolia. The major and trace elements and REE data indicate that the meta-mafic volcanic rocks occurred in the environment similar to a modern continental rift. Sm-Nd and Rb-Sr isotopic studies indicated that the meta-basic rocks were formed during the Early Neoarchean from 2800 Ma to 2900 Ma and reworked during the Late Neoarchean (2500 Ma) by metamorphism. Because of the separation of the North China Craton from the Siberia Craton during the Middle Proterozoic ( 1600 Ma), the Rb-Sr systematics of the rocks has been changed. The Se' ertengshan greenstone seems to occur during the Middle Archean. A stable continental crust may have existed during the Paleoarchean.

  5. Perchlorate isotope forensics (United States)

    Böhlke, J.K.; Sturchio, N.C.; Gu, B.; Horita, J.; Brown, G.M.; Jackson, W.A.; Batista, J.; Hatzinger, P.B.


    Perchlorate has been detected recently in a variety of soils, waters, plants, and food products at levels that may be detrimental to human health. These discoveries have generated considerable interest in perchlorate source identification. In this study, comprehensive stable isotope analyses ( 37Cl/35Cl and 18O/17O/ 16O) of perchlorate from known synthetic and natural sources reveal systematic differences in isotopic characteristics that are related to the formation mechanisms. In addition, isotopic analyses of perchlorate extracted from groundwater and surface water demonstrate the feasibility of identifying perchlorate sources in contaminated environments on the basis of this technique. Both natural and synthetic sources of perchlorate have been identified in water samples from some perchlorate occurrences in the United States by the isotopic method. ?? 2005 American Chemical Society.

  6. An Updated Interpretation to the Position of the Kula-Farallon Ridge Against North America During the Late Cretaceous: Isotopic Evidence. (United States)

    Guerrero-Garcia, J. C.; Herrero-Bervera, E.


    The initial break-up of the Pacific plate about 85 Ma ago into the Izanagi, Pacific, Kula and Farallon plates proposed by Woods and Davies [1982], has been documented by Engebretson et al., [1985] based on the absolute movement of the plates with respect to fixed Hot Spots (Hawaii and Yellowstone). Due to the lack of data from the oceanic crust that has already been subducted at the trench, in their corresponding reconstruction at 80 Ma ago, the uncertainty exists as to whether the crest was abutting against North America in southern Guatemala or north of Vancouver, an uncertainty of about 4500 km. Isotopic ages of crystalline rocks along the Pacific coast of Mexico from the state of Jalisco and the state of Oaxaca, a stripe 1,100 Km long, indicate a systematic decrease in Rb/Sr mineral ages, from 80 Ma in Jalisco to 11 Ma in Oaxaca, apparently related to the migration of the Chortis block (Honduras and Nicaragua) being detached from Mexico and transported by the Farallon plate toward the southeast. These results agree with previous published results. At Puerto Vallarta, Jalisco, the biotite mineral age obtained is 80 Ma, soon after the fragmentation of the Pacific plate proposed by Woods and Davies [1982]. This change in tectonic regime from a subduction zone to a transform margin is documented in that part of Mexico by a magmatic hiatus lasting roughly 25 Ma that initiates about 80 Ma ago, as well [Pantoja-Alor, 1983]. These data suggest that the Kula-Farallon ridge had to be located somewhere north of Puerto Vallarta, at the time of fragmentation of the Pacific plate 85 Ma ago. The counterclockwise paleomagnetic rotations reported from both the Pacific coast of Mexico and Honduras support these conclusions. On the other hand, the analyses of paleomagnetic data and field geology from British Columbia [Umhoefer, 1987] indicates a large displacement of that region along the Pacific margin of North America, of the order of 2,400 Km, from the present- day position of

  7. Combined Whole-Rock to Nano-Scale Investigations Reveal Contrasting Response of Pt-Os and Re-Os Isotope Systematics During Magmatic and Post-Magmatic Processes (United States)

    Coggon, J. A.; Luguet, A.; Lorand, J. P.; Fonseca, R.; Wainwright, A.; Appel, P.; Hoffmann, J. E.; Nowell, G. M.


    Advances in single-grain and micro- and nano-analytical techniques in recent years have been particularly important to the study of highly siderophile elements (HSE) and have contributed significantly to our knowledge and understanding of their host phases and behaviour. Furthermore, whole-rock- to nano-scale studies provide new perspectives for investigation of HSE isotope systematics. Recent multi-scale 187Re-187Os and 190Pt-186Os studies facilitate comparison, to a previously unattainable degree, of the differing responses of these two decay systems to magmatic and post-magmatic processes. It is well established that mafic-ultramafic melts are sensitive to disturbance of their Re-Os isotope systematics by crustal assimilation, due to the incompatibility and resulting enrichment of Re in crustal lithologies. In contrast the very long half-life and extremely low atomic abundance of 190Pt, combined with relatively low Pt concentrations in crustal rocks, generally render the Pt-Os isotope system insensitive to modification during assimilation. However, using new single chromite grain data (Coggon et al., 2015) from the >3.811 Ga Ujaragssuit nunât layered ultramafic body, Greenland, we show that it is possible to distinguish two distinct episodes of 187Os/188Os modification; Country rock contamination of the parent melt was followed by later metamorphic disturbance of the isotope system. The Pt-Os data (Coggon et al., 2013) from the same samples show no evidence of crustal assimilation, but preserve signatures of mantle melting at ~4.1 Ga as well as disturbance during metamorphism. Macro- to micro-petrographic study clearly demonstrates that Pt, Re and Os are hosted by different mineral phases, of different origins, in these samples. This, together with the physical parameters of the decay systems reported above, leads to the dissimilar behaviour and response of the 187Re-187Os and 190Pt-186Os isotope systems during both magmatic and post-magmatic processes and

  8. Evaporative fractionation of volatile stable isotopes and their bearing on the origin of the Moon. (United States)

    Day, James M D; Moynier, Frederic


    The Moon is depleted in volatile elements relative to the Earth and Mars. Low abundances of volatile elements, fractionated stable isotope ratios of S, Cl, K and Zn, high μ ((238)U/(204)Pb) and long-term Rb/Sr depletion are distinguishing features of the Moon, relative to the Earth. These geochemical characteristics indicate both inheritance of volatile-depleted materials that formed the Moon and planets and subsequent evaporative loss of volatile elements that occurred during lunar formation and differentiation. Models of volatile loss through localized eruptive degassing are not consistent with the available S, Cl, Zn and K isotopes and abundance data for the Moon. The most probable cause of volatile depletion is global-scale evaporation resulting from a giant impact or a magma ocean phase where inefficient volatile loss during magmatic convection led to the present distribution of volatile elements within mantle and crustal reservoirs. Problems exist for models of planetary volatile depletion following giant impact. Most critically, in this model, the volatile loss requires preferential delivery and retention of late-accreted volatiles to the Earth compared with the Moon. Different proportions of late-accreted mass are computed to explain present-day distributions of volatile and moderately volatile elements (e.g. Pb, Zn; 5 to >10%) relative to highly siderophile elements (approx. 0.5%) for the Earth. Models of early magma ocean phases may be more effective in explaining the volatile loss. Basaltic materials (e.g. eucrites and angrites) from highly differentiated airless asteroids are volatile-depleted, like the Moon, whereas the Earth and Mars have proportionally greater volatile contents. Parent-body size and the existence of early atmospheres are therefore likely to represent fundamental controls on planetary volatile retention or loss.

  9. K-Ca Dating of Alkali-Rich Fragments in the Y-74442 and Bhola LL-Chondritic Breccias (United States)

    Yokoyama, T; Misawa, K.; Okano, O; Shih, C. -Y.; Nyquist, L. E.; Simon, J. I.; Tappa, M. J.; Yoneda, S.


    Alkali-rich igneous fragments in the brecciated LL-chondrites, Krahenberg (LL5) [1], Bhola (LL3-6) [2], Siena (LL5) [3] and Yamato (Y)-74442 (LL4) [4-6], show characteristic fractionation patterns of alkali and alkaline elements [7]. The alkali-rich fragments in Krahenberg, Bhola and Y-74442 are very similar in mineralogy and petrography, suggesting that they could have come from related precursor materials [6]. Recently we reported Rb-Sr isotopic systematics of alkali-rich igneous rock fragments in Y-74442: nine fragments from Y-74442 yield the Rb-Sr age of 4429 plus or minus 54 Ma (2 sigma) for lambda(Rb-87) = 0.01402 Ga(exp -1) [8] with the initial ratio of Sr-87/Sr-86 = 0.7144 plus or minus 0.0094 (2 sigma) [9]. The Rb-Sr age of the alkali-rich fragments of Y-74442 is younger than the primary Rb-Sr age of 4541 plus or minus 14 Ma for LL-chondrite whole-rock samples [10], implying that they formed after accumulation of LL-chondrite parental bodies, although enrichment may have happened earlier. Marshall and DePaolo [11,12] demonstrated that the K-40 - Ca-40 decay system could be an important chronometer as well as a useful radiogenic tracer for studies of terrestrial rocks. Shih et al. [13,14] and more recently Simon et al. [15] determined K-Ca ages of lunar granitic rocks, and showed the application of the K-Ca chronometer for K-rich planetary materials. Since alkali-rich fragments in the LL-chondritic breccias are highly enriched in K, we can expect enhancements of radiogenic Ca-40. Here, we report preliminary results of K-Ca isotopic systematics of alkali-rich fragments in the LL-chondritic breccias, Y-74442 and Bhola.

  10. Systematics of a Clumped Isotope-Based Reconstruction of Temperature and Precipitation Water δ18O from Late Pleistocene and Holocene Archives of the Chinese Loess Plateau (United States)

    Bricker, H. L.; Mitsunaga, B.; Mering, J. A.; Eagle, R.; Li, G.; Tripati, A. K.


    The Chinese Loess Plateau lies at the terminus of the East Asian Monsoon, a massive meteorological phenomenon that provides water to up to a quarter of the world's population. This event has been hypothesized to exhibit shifts in intensity and location over geologic time in response to changes in glaciation and climate forcing, including associated abrupt events, during glacial-interglacial cycles, and over longer (>106) year timescales. We propose to reconstruct and evaluate processes that affect carbonate δ18O and carbonate "clumped" isotope thermometry signatures of archives from the Loess Plateau. We will examine modern and Holocene (5,000-10,000 year old) snail specimens (Sp. Cathaica) from four locations within the Plateau: Yichuan, Xifeng, Mangshan, and Lingtai. We will additionally employ the evaporative flux balance model of Balakrishnan (2005) to analyze snail aragonite crystallization in oxygen isotope equilibrium as a proxy measurement for δ18O evaporation. We will then compare these measurements with empirical, modern-day meteoric δ18O and temperature data from local weather stations and the Global Network of Isotopes in Precipitation (GNIP), as well as data from in situ carbonate nodular loess concretions. These comparisons will allow us to assess the seasonality of growth and determine if non-climatological parameters (e.g., kinetic effects) dominate isotopic signatures, in order to assess if these proxies represent. If the clumped isotope data conforms to these independently-derived measurements, clumped isotope thermometry may be a valid and robust method for characterizing past environmental changes, and we can extend this procedure to proxy materials.

  11. Chlorine isotopes potential as geo-chemical tracers

    Digital Repository Service at National Institute of Oceanography (India)

    Shirodkar, P.V.; Pradhan, U.K.; Banerjee, R.

    The potential of chlorine isotopes as tracers of geo-chemical processes of earth and the oceans is highlighted based on systematic studies carried out in understanding the chlorine isotope fractionation mechanism, its constancy in seawater and its...

  12. Calcium isotope systematics in small upland catchments affected by spruce dieback in the period of extreme acid rain (1970-1990) (United States)

    Novak, Martin; Farkas, Juraj; Holmden, Chris; Hruska, Jakub; Curik, Jan; Stepanova, Marketa; Prechova, Eva; Veselovsky, Frantisek; Komarek, Arnost


    Recently, new isotope tools have become available to study the behavior of nutrients in stressed ecosystems. In this study, we focus on changes in the abundance ratio of calcium (Ca) isotopes accompanying biogeochemical processes in small forested catchments. We monitored del44Ca values in ecosystem pools and fluxes in four upland sites situated in the Czech Republic, Central Europe. A heavily acidified site in the Eagle Mts. (northern Czech Republic) experienced 13 times higher atmospheric Ca inputs, compared to the other three sites, which were less affected by forest decline. Industrial dust was responsible for the elevated Ca input. Del44Ca values of individual poos/fluxes were used to identify Ca sources for the bioavailable Ca soil reservoir and for runoff. The bedrock of the study sites differed (leucogranite, orthogneiss vs. serpentinite and amphibolite). Across the sites, mean del44Ca values increased in the order: spruce bark < fine roots < needles < soil < bedrock < canopy throughfall < open-area precipitation < runoff < soil water. Plant preferentially took up isotopically light Ca, while residual isotopically heavy Ca was sorbed to soil particles or exported via runoff. Even at sites with a low del44Ca values of bedrock, runoff had a high del44Ca value. At the base-poor site, most runoff came from atmospheric deposition and residual Ca following plant uptake. It appeared that bedrock weathering did not supply enough Ca to replenish the bioavailable Ca pool in the soil. Currently, we are analyzing Ca isotope composition of individual rock-forming minerals to better assess the effect of different weathering rates of minerals with low/high radiogenic 40Ca contents on runoff del44Ca.

  13. Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada, and Inyo County, California (United States)

    Paces, James B.; Peterman, Zell E.; Futo, Kiyoto; Oliver, Thomas A.; Marshall, Brian D.


    Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values

  14. Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California.

    Energy Technology Data Exchange (ETDEWEB)

    James B. Paces; Zell E. Peterman; Kiyoto Futa; Thomas A. Oliver; and Brian D. Marshall.


    Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to

  15. Nd-Sr-Pb Isotopic Compositions of Cordierite Granite on Southern Margin of the Qaidam Block, NW China, and Constraints on Its Petrogenesis,Tectonic Affinity of Source Region and Tectonic Implications%柴南缘堇青石花岗岩的Nd-Sr-Pb同位素组成及其对岩石成因、源区构造属性和构造演化的启示

    Institute of Scientific and Technical Information of China (English)

    巴金; 陈能松; 王勤燕; 王新宇; 张璐; 王树庆


    The Jinshuikou cordierite granite (JCG) is the only strong peraluminous granite pluton discovered so far on northwestern margin of the Tibetan plateau. This cordierite granite contains mafic minerals of cordierite, garnet and biotite. Characterizing mafic peraluminous granite. However, more comprehensive investigations of its genetic mechanism and implications for affinity and tectonic evolution of the basement of the Qaidam block is needed. This paper studies systematically on major and trace elements and Nd-Sr-Pb isotopic geochemistry of the JCG following the geology and petrographical observatioa The JCG pluton shows A/CNK=1. 12-2. 05, K2O/Na2O=0. 44-2. 99, Rb/Sr=0. 42-1. 23, Nb/Ta=11. 88-15. 30, and is enriched in Rb, Th and U, but depleted in Sr and Ba, significant negative Eu anomalies (δEu=0. 41 - 1. 01, average at 0. 62), Isr =0.711 4-0.750 3 and εNd(t) =-9. 30 to -13.32. These data suggest that magma for the JCG was derived from partial melting of biotite-bearing metagreywacke in the upper continental crust, and that the melting conditions featuring high temperature but shallow depth level suggest existence of an extra heat source, implying that deep processes of subducted plate delami-nation. Asthenospheric mantle upwelling, mafic magma intrusion and underplating might occurred at southern margin of the Qaidam block in the late Caledonian. The JCG pluton has Nd model age (TDMZ) of 1. 9 -2. 2 Ga and initial Pb isotope ratios 206Pb/204Pb of 18. 181-18. 389, 207Pb/204Pb values of 15. 582-15.632 and 208Pb/204Pb values of 37. 914-38. 243, suggesting that the basement of the Qaidam block is geochemically akin to that of the Yangtze block.%金水口堇青石花岗岩是迄今在青藏高原东北缘发现的唯一的一个强过铝质花岗岩岩体,含堇青石、石榴子石和黑云母等镁铁质矿物,属于镁铁质过铝质花岗岩.但目前对该岩体的成因机制及其对基底源区的构造属性和构造演化意义尚缺乏深入研究.为

  16. Paleoproterozoic basement beneath the southern Jiangxi Province: Evidence from U-Pb ages and Lu-Hf isotopes in zircons from the Doushui Iamprophyre

    Institute of Scientific and Technical Information of China (English)

    YU JinHai; WANG LiJuan; O'REILLY S Y; SHU LiangShu; UN Tao


    This paper presents geochemical analyses of a lamprophyre intruding the Caledonian Doushui granite body in Shangyou County, southern Jiangxi Province. U-Pb dating and Hf-isotope analyses are especially carried out for zircons from it. Petrological and geochemical features show that the lamprophyre belongs to a high-K, weakly alkaline pyroxene-biotite iamprophyre. It is characterized by high Mg# (0.74),Ni (253 μg/g) and Cr (893 μg/g) contents, and also enriched in incompatible elements, such as REE, Rb, Sr, Ba and K. It is suggested that its primitive melt probably derived from enriched mantle metasomatized by non-crust-derived agent. Morphology and LAM-ICPMS dating results of zircons in the lam prophyre indicate that they are xenocrysts captured from deep crustal rocks. Most xenocrystic zircons formed at -1.86 Ga, and a few in different Phanerozoic periods. The Paleoproterozoic zircons are of magmatic origin and have similar 176Hf/177Hf and 176Lu/177Hf ratios, indicating that they probably are from the same igneous basement rock. The ages and Hf-isotope compositions of zircons from this basement rock are similar to those of Paleoproterozoic Danzhu granite in the southern Zhejiang Province, but extremely distinguished from the Nanling basement, suggesting that the study area probably is a westward extension part of Paleoproterozoic Wuyishan terrane in the eastern Cathaysia Block. These Paleoproterozoic zircons have low Hf-isotope compositions, characteristic of crustal source. Hf model ages of these zircons and the presence of older inherited cores within them, coupled with available other data reported by previous studies, suggest that the source of Paleoproterozoic magma is Neoarchaean crust, implying the existence of older basement in the Wuyishan terrane. U-Pb ages and Hf isotopes of five Phanerozoic zircons indicate that Paleoproterozoic basement underwent multi-reworking occurring in Caledonian, Indosinian and early Yanshanian, respectively. The Caledonian

  17. Small scale heterogeneity of Phanerozoic lower crust: evidence from isotopic and geochemical systematics of mid-Cretaceous granulite gneisses, San Gabriel Mountains, southern California (United States)

    Barth, A.P.; Wooden, J.L.; May, D.J.


    An elongate belt of mid-Cretaceous, compositionally banded gneisses and granulites is exposed in Cucamonga terrane, in the southeastern foothills of the San Gabriel Mountains of southern California. Banded gneisses include mafic granulites of two geochemical types: type 1 rocks are similar to high Al arc basalts and andesites but have higher HFSE (high-field-strength-element) abundances and extremely variable LILE (largeion-lithophile-element) abundances, while type 2 rocks are relatively low in Al and similar to alkali rich MOR (midocean-ridge) or intraplate basalts. Intercalated with mafic granulites are paragneisses which include felsic granulites, aluminous gneisses, marble, and calc-silicate gneisses. Type 1 mafic granulites and calcic trondhjemitic pegmatites also oceur as cross-cutting, synmetamorphic dikes or small plutons. Small-scale heterogeneity of deep continental crust is indicated by the lithologic and isotopic diversity of intercalated ortho-and paragneisses exposed in Cucamonga terrane. Geochemical and isotopic data indicate that K, Rb, and U depletion and Sm/Nd fractionation were associated with biotite +/- muscovite dehydration reactions in type 1 mafic granulites and aluminous gneisses during high-grade metamorphism. Field relations and model initial isotopic ratios imply a wide range of protolith ages, ranging from Early Proterozoic to Phanerozoic. ?? 1992 Springer-Verlag.

  18. Systematic decay studies of even-even $132-138$^Nd, $144-158$^Gd, $176-196$^Hg and $192-198$^Pb isotopes

    CERN Document Server

    Santhosh, K P


    The alpha and cluster decay properties of the $132-138$^Nd, $144-158$^Gd, $176-196$^Hg and $192-198$^Pb even-even isotopes in the two mass regions A = 130-158 and A = 180-198 are analysed using the Coulomb and Proximity Potential Model. On examining the clusters at corresponding points in the cold valleys (points with same A_2) of the various isotopes of a particular nucleus we find that at certain mass numbers of the parent nuclei, the clusters emitted are getting shifted to the next lower atomic number. It is interesting to see that the change in clusters appears at those isotopes where a change in shape is occurring correspondingly. Such a change of clusters with shape change is studied for the first time in cluster decay. The alpha decay half lives of these nuclei are computed and these are compared with the available experimental alpha decay data. It is seen that the two are in good agreement. On making a comparison of the alpha half lives of the normal deformed and super deformed nuclei, it can be seen ...

  19. He-Ar Isotopic Systematics of Fluid Inclusions in Pyrites from PGE-polymetallic Deposits in Lower Cambrian Black Rock Series, South China

    Institute of Scientific and Technical Information of China (English)

    SUN Xiaoming; WANG Min; XUE Ting; MA Mingyang; LI Yinhe


    He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGEpolymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43x10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of airsaturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was expelled and migrated laterally along strata because of the pressure generated by overlying sediments. The basinal hot brine ascended along faults, mixed with sea water and finally deposited ore minerals.

  20. Complexity of In-situ zircon U-Pb-Hf isotope systematics during arc magma genesis at the roots of a Cretaceous arc, Fiordland, New Zealand (United States)

    Milan, L. A.; Daczko, N. R.; Clarke, G. L.; Allibone, A. H.


    Zircons from seventeen samples of Western Fiordland Orthogneiss (WFO) diorites and three samples of country rock (two schists and one Darran Suite diorite) from the lowermost exposed sections of the Median Batholith, Fiordland, New Zealand, were analysed for in-situ U-Pb and Hf-isotopes. The WFO represents the deeper levels of Early Cretaceous continental arc magmatism on the Pacific margin of Gondwana, marking the final stage of long-lived arc magmatism on the margin spanning the Palaeozoic. The WFO plutons were emplaced at high-P (mid to deep crust at c. 8-12 kbar) between 124 and 114 Ma. Minor very high-P (c. 18 kbar) WFO eclogite and omphacite granulite facies orthogneiss (Breaksea Orthogneiss) are inferred to have crystallised in the base of thickened crust at c. 124 Ma. Zircons from the Breaksea Orthogneiss are considered to be variably affected by Pb-loss due to emplacement of the adjacent (Malaspina) Pluton at c. 114 Ma. By identifying Pb-loss, magmatic ages were able to be inferred in respect to apparent Pb-loss ages. Hf isotope data for the WFO define an excursion to less radiogenic Hf isotope ratios with time, reflecting increased recycling of an old source component. Peaks at c. 555, 770 and 2480 Ma, determine the age spectra of inherited populations of zircons within the WFO. This contrasts with detrital zircon patterns in country rocks of the Takaka terrane, which include peaks at c. 465 Ma, and 1250-900 Ma that are absent in the WFO inheritance pattern. These results indicate a previously unrecognised Precambrian lower crustal component of New Zealand. Recycling of this lower crust became increasingly important as a source for the final stage or Mesozoic arc magmatism along this segment of the palaeo-Pacific margin of Gondwana.

  1. Ediacaran Palaeozoic tectonic evolution of the Ossa Morena and Central Iberian zones (SW Iberia) as revealed by Sm Nd isotope systematics (United States)

    López-Guijarro, Rafael; Armendáriz, Maider; Quesada, Cecilio; Fernández-Suárez, Javier; Murphy, J. Brendan; Pin, Christian; Bellido, Felix


    Sm-Nd isotopic analyses of Palaeozoic sedimentary and igneous rocks in the southwest Iberian Massif (western end of the European Variscan Belt) are presented in order to unravel its complex poly-orogenic evolution during the closure of the Rheic Ocean and the amalgamation of Pangea. The Gondwanan margin in southwest Iberia SW Iberia is subdivided into the Ossa Morena and Central Iberian zones, separated by the Badajoz-Córdoba Shear Zone which represents a cryptic suture zone between these terranes. The relationships between these terranes, and between units preserved within the suture zone (e.g. the Sierra Albarrana Group) during the Palaeozoic and Neoproterozoic are controversial. Sm-Nd isotopic studies of representative sedimentary sequences covering the entire pre-Variscan record of the Ossa Morena and Central Iberian zones show very similar characteristics from the uppermost Ediacaran onwards. These data indicate that their accretion to one another must have been completed by the Late Neoproterozoic-Ediacarin that time (an event assigned to Cadomian orogeny) and that they never separated substantially from each other since that time. The Sm-Nd isotopic composition of the Sierra Albarrana Group metasedimentary rocks is similar to that of the pre-Cadomian sequences of the Ossa Morena Zone (Serie Negra), suggesting derivation from a common source. The common provenance of the Palaeozoic sequences in the two zones is identical to that of the pre-Cadomian Serie Negra of the Ossa Morena Zone, which in accordance with the data presented herein and published U-Pb zircon data indicates a West African affinity.

  2. Genesis and open-system evolution of Quaternary magmas beneath southeastern margin of Tibet: Constraints from Sr-Nd-Pb-Hf isotope systematics (United States)

    Zou, Haibo; Ma, Mingjia; Fan, Qicheng; Xu, Bei; Li, Shuang-Qing; Zhao, Yongwei; King, David T.


    Post-collisional volcanic rocks on the Tibetan Plateau and its margins contain valuable information about the geodynamic processes associated with this Cenozoic continent-continent collision. The Quaternary Tengchong volcanic field at the southeastern margin of the Tibetan Plateau formed high-potassium calc-alkaline volcanic rocks. Herein, we present comprehensive Nd-Sr-Pb-Hf isotopic and elemental data for trachybasalts, basaltic trachyandesites, and trachyandesites from four Quaternary Tengchong volcanoes (Maanshan, Dayingshan, Heikongshan, and Laoguipo) in order to understand their magma genesis and evolution as well as tectonic significance. Good correlations between SiO2 content and the ratios 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, and 177Hf/176Hf for these Quaternary volcanics strongly suggest that the combined assimilation and fractional crystallization (AFC) was an important process in the origin of basaltic trachyandesites and trachyandesites. High Y and Yb contents and low Sr/Y ratios of these basaltic trachyandesites and trachyandesites are uncharacteristic of adakites that formed by partial melting of eclogitic lower crust or partial melting of basaltic oceanic crust with eclogite as a restite. A combined assimilation-fractional crystallization model is proposed for these basaltic trachyandesites and trachyandesites. Nd-Sr-Pb-Hf isotopes for the uncontaminated Tengchong magma (trachybasalts with SiO2 5.5% wt.%) reflect a heterogeneous enriched mantle source. High Th/U, Th/Ta, and Rb/Nb ratios and Nd-Sr-Pb-Hf isotope characteristics of the uncontaminated magmas suggest that the enriched mantle beneath Tengchong formed as a result of subduction of clay-rich sediments, which probably came from the Indian continental plate. Partial melting of the enriched mantle was generated by deep continental subduction coupled with recent regional extension in the Tengchong area.

  3. PGE, Re-Os, and Mo isotope systematics in Archean and early Proterozoic sedimentary systems as proxies for redox conditions of the early Earth (United States)

    Siebert, C.; Kramers, J. D.; Meisel, Th.; Morel, Ph.; Nägler, Th. F.


    Re-Os data and PGE concentrations as well as Mo concentrations and isotope data are reported for suites of fine clastic sediments and black shales from the Barberton Greenstone Belt, South Africa (Fig Tree and Moodies Groups, 3.25-3.15 Ga), the Belingwe Greenstone Belt, Zimbabwe (Manjeri Formation, ca. 2.7 Ga) and shales from the Witwatersrand, Ventersdorp and Transvaal Supergroups, South Africa ranging from 2.95 to 2.2 Ga. Moderately oxidizing conditions are required to mobilize Re and Mo in the environment, Mo fractionation only occurs in solution, and these parameters thus have potential use as paleoredox proxies for the early Earth. PGE + Re abundance patterns of Barberton Greenstone Belt sediments are uniform and very similar in shape to those of komatiites. This indicates (1) that the PGE came from a source of predominantly ultramafic composition and, (2) that PGE were transported and deposited essentially in particulate form. Sediments from the younger Belingwe Greenstone Belt show more fractionated PGE + Re patterns and have Re/Os ratios 10 to 100× higher than those of Barberton sediments. Their PGE abundance patterns and Re/Os ratios are intermediate between those of the mid-Archean shales and Neoproterozoic to Recent black shales. They reflect scavenging of Re from solution in the sedimentary environment. δ 98/95Mo values of black shales of all ages correlate with their concentrations. The Barberton Greenstone Belt samples have ˜1-3 ppm Mo, similar to a granitoid-basaltic source. This Mo has δ 98/95Mo between -1.9 and -2.4‰ relative to present day mean ocean water molybdenum, MOMO and is thus not isotopically fractionated relative to such a source. Similar to the PGE this indicates transport in solid form. Sediments from the Belingwe Greenstone Belt show in part enhanced Mo concentrations (up to 6 ppm) and Mo isotope fractionation (δ 98/95Mo up to -1.4‰ relative to MOMO). The combined PGE + Re and Mo data show mainly reducing conditions in the

  4. The reliability of ∼2.9 Ga old Witwatersrand banded iron formations (South Africa) as archives for Mesoarchean seawater: Evidence from REE and Nd isotope systematics (United States)

    Viehmann, Sebastian; Bau, Michael; Smith, Albertus J. B.; Beukes, Nicolas J.; Dantas, Elton L.; Bühn, Bernhard


    Pure marine chemical sediments, such as (Banded) Iron Formations, (B)IFs, are archives of geochemical proxies for the composition of Precambrian seawater and may provide information about the ancient hydrosphere-atmosphere system. We here present rare earths and yttrium (REY) and high precision Sm-Nd isotope data of ∼2.90 Ga old Superior-type BIFs from the Witwatersrand Supergroup, South Africa, and compare those with data for near-contemporaneous BIFs from the correlative Pongola Supergroup (Superior-type BIF) and from the Pietersburg Greenstone Belt (Algoma-type IF), respectively. All Witwatersrand samples studied display the typical general REY distribution of Archean seawater, but their REY anomalies are less pronounced and their immobile element concentrations are higher than those of other pure (B)IFs. These observations indicate the presence of significant amounts of detrital aluminosilicates in the Witwatersrand BIFs and question the reliability of the Contorted Bed and Water Tower BIFs (Parktown Formation, West Rand Group) as archives of Mesoarchean seawater. Significant post-depositional alteration of the REY budget and the Sm-Nd isotope system is not observed. The Nd isotopic compositions of the purest BIF samples, i.e. the most reliable archives for Witwatersrand seawater, show initial εNd values between -3.95 and -2.25. This range is more negative than what is observed in ambient shales, indicating a decoupling of suspended and dissolved loads in the "near-shore" Witwatersrand Basin seawater. However, εNd range overlaps with that of the correlative Pongola BIF (Alexander et al., 2008). The deeper-water Algoma-type Pietersburg BIF shows more positive (i.e. more mantle-like) εNd2.9Ga values, supporting the hypothesis that a significant amount of its REY inventory was derived from black smoker-style, high-temperature hydrothermal fluids that had altered seafloor basalts. In marked contrast, the dissolved REY budgets (including the Nd isotopic

  5. C, O, Sr and Nd isotope systematics of carbonates of Papaghni sub-basin, Andhra Pradesh, India: Implications for genesis of carbonate-hosted stratiform uranium mineralisation and geodynamic evolution of the Cuddapah basin (United States)

    Absar, Nurul; Nizamudheen, B. M.; Augustine, Sminto; Managave, Shreyas; Balakrishnan, S.


    The Cuddapah basin (CB) is one of a series of Proterozoic basins that overlie the Archaean cratons of India, and contains a unique stratiform carbonate-hosted uranium mineralisation. In the present work, we discuss stable (C, O) and radiogenic (Nd, Sr) isotope systematics of carbonates of the Papaghni sub-basin in order to understand uranium ore forming processes and geodynamic evolution of the CB. Uranium mineralised dolomites (UMDs) of the basal Vempalle Formation show a significantly lighter (~ 1.5‰) C-isotope signature compared to that of open-marine stromatolitic sub-tidal facies, suggesting input of isotopically lighter carbon through in situ remineralisation of organic matter (OM). This implies deposition in a hydrologically-restricted, redox-stratified lagoonal basin wherein exchange with open oceanic dissolved inorganic carbon (DIC) was limited. Persistent bottom water anoxia was created and maintained through consumption of dissolved oxygen (DO) by decaying OM produced in oxidised surface water zone. Significantly more radiogenic εNd(t) of UMD (- 6.31 ± 0.54) compared to that of Dharwar upper crust (- 8.64 ± 3.11) indicates that dissolved constituents did not originate from the Dharwar craton, rather were derived from more juvenile exotic sources - possibly from a continental arc. Dissolved uranyl ions (U+ 6) were introduced to the basin through fluvial run-off and were reduced to immobile uranous ions (U+ 4) at the redox interface resulting in precipitation of pitchblende and coffinite. Carbonate horizons of upper Vempalle Formation and Tadpatri Formation show progressively more radiogenic Nd isotope compositions signifying increased juvenile arc contribution to the Papaghni sub-basin through time, which is also corroborated by the presence of younger zircons (1923 ± 22 Ma) in Pulivendla quartzites. We propose that the Papaghni sub-basin opened as a back-arc extensional basin at ~ 2 Ga as a result of westerly-directed subduction of oceanic crust

  6. Confirmation of a meteoritic component in impact-melt rocks of the Chesapeake Bay impact structure, Virginia, USA - Evidence from osmium isotopic and PGE systematics (United States)

    Lee, Seung Ryeol; Horton, J. Wright; Walker, Richard J.


    The osmium isotope ratios and platinum-group element (PGE) concentrations of impact-melt rocks in the Chesapeake Bay impact structure were determined. The impact-melt rocks come from the cored part of a lower-crater section of suevitic crystalline-clast breccia in an 823 m scientific test hole over the central uplift at Cape Charles, Virginia. The 187Os/188Os ratios of impact-melt rocks range from 0.151 to 0.518. The rhenium and platinum-group element (PGE) concentrations of these rocks are 30-270× higher than concentrations in basement gneiss, and together with the osmium isotopes indicate a substantial meteoritic component in some impact-melt rocks. Because the PGE abundances in the impact-melt rocks are dominated by the target materials, interelemental ratios of the impact-melt rocks are highly variable and nonchondritic. The chemical nature of the projectile for the Chesapeake Bay impact structure cannot be constrained at this time. Model mixing calculations between chondritic and crustal components suggest that most impact-melt rocks include a bulk meteoritic component of 0.01-0.1% by mass. Several impact-melt rocks with lowest initial 187Os/188Os ratios and the highest osmium concentrations could have been produced by additions of 0.1%-0.2% of a meteoritic component. In these samples, as much as 70% of the total Os may be of meteoritic origin. At the calculated proportions of a meteoritic component (0.01-0.1% by mass), no mixtures of the investigated target rocks and sediments can reproduce the observed PGE abundances of the impact-melt rocks, suggesting that other PGE enrichment processes operated along with the meteoritic contamination. Possible explanations are 1) participation of unsampled target materials with high PGE abundances in the impact-melt rocks, and 2) variable fractionations of PGE during syn- to post-impact events.

  7. U-Pb zircon geochronology and Nd-Hf-O isotopic systematics of the Neoproterozoic Hadb adh Dayheen ring complex, Central Arabian Shield, Saudi Arabia (United States)

    Ali, Kamal A.; Jeon, Heejin; Andresen, Arild; Li, Shuang-Qing; Harbi, Hesham M.; Hegner, Ernst


    A combined study of single zircon U-Pb dating, Hf-O zircon isotopic analyses and whole-rock Nd isotopic compositions was carried out to infer the magma sources of Neoproterozoic post-collisional A-type granitoids in Saudi Arabia. U-Pb zircon dating of magmatic zircons of two samples from the Hadb adh Dayheen ring complex yielded ages of 625 ± 11 Ma for a hornblende-biotite granite sample, and 613 ± 4 Ma for a monzogranite sample. The granitic rocks show initial εNd values of + 4.1 to + 5.3 and εHf of + 4.5 to + 8.4 that are lower than those of a model depleted mantle (εHf ~+ 14 and εNd ~+ 6.5) and consistent with melting of subduction-related crustal protoliths that were formed during the Neoproterozoic assembly of the Arabian-Nubian Shield (ANS). Crustal-model ages (Hf-tNC) of 0.81 to 1.1 Ga are inconsistent with depleted-mantle Nd model ages of 0.71 to 0.81 Ga and indicate that the post-collisional Hadb adh Dayheen granites were derived mostly from juvenile crust formed in Neoproterozoic time. Single zircons data show a wide range in δ18O values from + 3.2‰ to + 6.4‰, possibly indicating crystallization of zircon from magma derived from magmatic rocks altered by meteoric water in a magma chamber-caldera system.

  8. Target rocks, impact glasses, and melt rocks from the Lonar crater, India: Highly siderophile element systematics and Sr-Nd-Os isotopic signatures (United States)

    Schulz, Toni; Luguet, Ambre; Wegner, Wencke; Acken, David; Koeberl, Christian


    The Lonar crater is a ~0.57-Myr-old impact structure located in the Deccan Traps of the Indian peninsula. It probably represents the best-preserved impact structure hosted in continental flood basalts, providing unique opportunities to study processes of impact cratering in basaltic targets. Here we present highly siderophile element (HSE) abundances and Sr-Nd and Os isotope data for target basalts and impactites (impact glasses and impact melt rocks) from the Lonar area. These tools may enable us to better constrain the interplay of a variety of impact-related processes such as mixing, volatilization, and contamination. Strontium and Nd isotopic compositions of impactites confirm and extend earlier suggestions about the incorporation of ancient basement rocks in Lonar impactites. In the Re-Os isochron plot, target basalts exhibit considerable scatter around a 65.6 Myr Re-Os reference isochron, most likely reflecting weathering and/or magma replenishment processes. Most impactites plot at distinctly lower 187Re/188Os and 187Os/188Os ratios compared to the target rocks and exhibit up to two orders of magnitude higher abundances of Ir, Os, and Ru. Moreover, the impactites show near-chondritic interelement ratios of HSE. We interpret our results in terms of an addition of up to 0.03% of a chondritc component to most impact glasses and impact melt rocks. The magnitude of the admixture is significantly lower than the earlier reported 12-20 wt% of extraterrestrial component for Lonar impact spherules, reflecting the typical difference in the distribution of projectile component between impact glass spherules and bulk impactites.

  9. SHRIMP-RG U-Pb isotopic systematics of zircon from the Angel Lake orthogneiss, East Humboldt Range, Nevada: Is this really archean crust? (United States)

    Premo, Wayne R.; Castineiras, Pedro; Wooden, Joseph L.


    New SHRIMP-RG (sensitive high-resolution ion microprobe-reverse geometry) data confirm the existence of Archean components within zircon grains of a sample from the orthogneiss of Angel Lake, Nevada, United States, previously interpreted as a nappe of Archean crust. However, the combined evidence strongly suggests that this orthogneiss is a highly deformed, Late Cretaceous monzogranite derived from melting of a sedimentary source dominated by Archean detritus. Zircon grains from the same sample used previously for isotope dilution-thermal ionization mass spectrometry (ID-TIMS) isotopic work were analyzed using the SHRIMP-RG to better define the age and origin of the orthogneiss. Prior to analysis, imaging revealed a morphological variability and intragrain, polyphase nature of the zircon population. The SHRIMP-RG yielded 207Pb/206Pb ages between ca. 2430 and 2580 Ma (a best-fit mean 207Pb/206Pb age of 2531 ± 19 Ma; 95% confidence) from mostly rounded to subrounded zircons and zircon components (cores). In addition, several analyses from rounded to subrounded cores or grains yielded discordant 207Pb/206Pb ages between ca. 1460 and ca. 2170 Ma, consistent with known regional magmatic events. All cores of Proterozoic to latest Archean age were encased within clear, typically low Th/U (206Pb/238U ages between 72 and 91 Ma, consistent with magmatic ages from Lamoille Canyon to the south. An age of ca. 90 Ma is suggested, the younger 206Pb/238U ages resulting from Pb loss. The Cretaceous and Precambrian zircon components also have distinct trace element characteristics, indicating that these age groups are not related to the same igneous source. These results support recent geophysical interpretations and negate the contention that the Archean-Proterozoic boundary extends into the central Great Basin area. They further suggest that the world-class gold deposits along the Carlin Trend are not underlain by Archean cratonal crust, but rather by the Proterozoic Mojave

  10. Subduction erosion of forearc mantle wedge implicated in the genesis of the South Sandwich Island (SSI) arc: Evidence from boron isotope systematics (United States)

    Tonarini, Sonia; Leeman, William P.; Leat, Phil T.


    The South Sandwich volcanic arc is sited on a young oceanic crust, erupts low-K tholeiitic rocks, is characterized by unexotic pelagic and volcanogenic sediments on the down-going slab, and simple tectonic setting, and is ideal for assessing element transport through subduction zones. As a means of quantifying processes attending transfer of subduction-related fluids from the slab to the mantle wedge, boron concentrations and isotopic compositions were determined for representative lavas from along the arc. The samples show variable fluid-mobile/fluid-immobile element ratios and high enrichments of B/Nb (2.7 to 55) and B/Zr (0.12 to 0.57), similar to those observed in western Pacific arcs. δ11B values are among the highest so far reported for mantle-derived lavas; these are highest in the central part of the arc (+ 15 to + 18‰) and decrease toward the southern and northern ends (+ 12 to + 14‰). δ11B is roughly positively correlated with B concentrations and with 87Sr/86Sr ratios, but poorly coupled with other fluid-mobile elements such as Rb, Ba, Sr and U. Peridotites dredged from the forearc trench also have high δ11B (ca. + 10‰) and elevated B contents (38-140 ppm). Incoming pelagic sediments sampled at ODP Site 701 display a wide range in δ11B (+ 5 to - 13‰; average = - 4.1‰), with negative values most common. The unusually high δ11B values inferred for the South Sandwich mantle wedge cannot easily be attributed to direct incorporation of subducting slab materials or fluids derived directly therefrom. Rather, the heavy B isotopic signature of the magma sources is more plausibly explained by ingress of fluids derived from subduction erosion of altered frontal arc mantle wedge materials similar to those in the Marianas forearc. We propose that multi-stage recycling of high-δ11B and high-B serpentinite (possibly embellished by arc crust and volcaniclastic sediments) can produce extremely 11B-rich fluids at slab depths beneath the volcanic arc

  11. Systematic sulfur stable isotope and fluid inclusion studies on veinlet groups in the Sarcheshmeh porphyry copper deposit: based on new data

    Directory of Open Access Journals (Sweden)

    Mohammad Maanijou


    Full Text Available Mineralization occurred by intrusion of granodioritic stock of middle Miocene in volcano–sedimenrary rocks in Sarcheshmeh of early Tertiary age. This research is based on samples of new drilled boreholes and benches of 2500m elevation. Based on mineralogy and crosscutting relationships, at least four groups of veinlets pertaining to four stages of mineralization were recognized. Sulfur isotope studies in the Sarcheshmeh porphyry copper deposit were conducted on pyrite, chalcopyrite, molybdenite and anhydrites of four groups of veinlets. The δ34S values in the sulfides and sulfates range from -2.2 to 1.27‰ and from 10.2 to 14.5 ‰, respectively. The average δ34S value in the sulfides is 1‰ and that for the sulfates is about 13‰. Considering these results, it can be concluded that the sulfides made up of a fluid that its sulfur has a magmatic origin. Also, fluid inclusions of different veinlet groups were studied, showing high temperature, high salinity and the occurrence of boiling in the mineralizing fluids. Moreover, these studies indicate presence of three types of fluids including magmatic, meteoritic and mixture of these two fluids in alteration and mineralizion processes.

  12. Leatherback Isotopes (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — SWFSC is currently working on a project identifying global marine isotopes using leatherback turtles (Dermochelys coriacea) as the indicator species. We currently...

  13. Isotopic chirality

    Energy Technology Data Exchange (ETDEWEB)

    Floss, H.G. [Univ. of Washington, Seattle, WA (United States)


    This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.

  14. Isotopic Paleoclimatology (United States)

    Bowen, R.

    Paleotemperature scales were calculated by H. C. Urey and others in the 1950s to assess past temperatures, and later work using the stable isotopes of oxygen, hydrogen, and carbon employed standards such as Peedee belemnite (PDB) and Standard Mean Ocean Water (SMOW). Subsequently, subjects as diverse as ice volume and paleotemperatures, oceanic ice and sediment cores, Pleistocene/Holocene climatic changes, and isotope chronostratigraphy extending back to the Precambrian were investigated.

  15. Preliminary Sr-Nd isotope study of the Hadong-Sanchung anorthositic rocks in Korea: Implication for their origin and for the Precambrian tectonics%韩国Hadong-Sanchung地区斜长岩Sr-Nd同位素初步研究--成因和前寒武纪构造意义

    Institute of Scientific and Technical Information of China (English)



    斜长岩呈长条带出露于朝鲜半岛南部,侵入到年代约为2.0 Ga的Yeongnam前寒武纪基底岩石中,虽然岩石类型简单(斜长岩和辉长岩质斜长岩),但可以同世界已知块状类型斜长岩相对比.这些斜长岩具有几个重要的差别,例如呈层状构造,镁铁相成分是角闪石而不是辉石,并且不具斜方辉石巨晶.应用Rb-Sr和Sm-Nd同位素系统研究这些岩石的年龄和成因,测定出一种页理化辉长岩质斜长岩矿物的Sm-Nd等时线年龄为1 678±90 Ma,推断其为侵位年龄,因为中生代绿岩相变质期间这些岩石的Sm-Nd同位素体系呈封闭状态.这一年龄和过去曾报道的元古宙块状斜长岩的年龄范围(1.1~1.7 Ga)相吻合.认为斜长岩成因可以用所谓元古宙斜长岩事件来解释.斜长岩的岩浆活动对朝鲜半岛南部前寒武纪基底岩石的构造历史有重要意义.全岩εNd(t)值范围-1.6~-5.2,而87Sr/86Sr初始值变化于0.704~0.706之间,据此可解释地幔成因的斜长岩岩浆是在其结晶作用期间吸收了地壳物质的结果.然而不能排除是下地壳源的可能性.%The anorthositic rocks in southern part of Korean peninsula occur as a long belt, intruding the ca. 2.0 Ga old Precambrianbasement rocks of the Yeongnam massif. Although they have simple rock types (anorthosite and gabbroic anorthosite) comparable towell known massif-type anorthosites worldwide, they possess several important differences such as layered structure, amphibole ratherthan pyroxene as a mafic phase, and no orthopyroxene megacrysts. The age of intrusion was not available previously. We have appliedRb-Sr and Sm-Nd isotope systematics to investigate the age and origin of these rocks. One foliated gabbroic anorthosite defines a Sm-Nd mineral isochron age of 1678 ± 90 Ma. This age is tentatively interpreted as the emplacement age because of apparently closed-sys-tem behavior of Sm-Nd system in these rocks during greenschist

  16. Subduction—Modified Subcontinental Mantle in South China:Trace Element and Isotope Evidence in Basalts from Hainan Island

    Institute of Scientific and Technical Information of China (English)

    张明; 解广轰; 等


    Cenozoic lavas from Hainan Island,South China,comprise quartz tholeiite,olivine tholeiite,alkali basalt,and basanite and form a continuous,tholeiite-dominated,compositional spectrum.Highly incompatible elements and their relationships with isotopes in these lavas are shown to be useful in evaluating mantle-source composition,whereas modeling suggests that ratios of elements with bulk partition coefficients significantly larger than those of Nb and Ta may be sensitive to partial melting.Th/Ta and La/Nb ratios of alkali basalts are lower than those of tholeiites,and they are all lower than those of the primitive mantle,These ratios correlate positively with 207Pb/204Pb and 87Sr/86Sr ratios.Such relationships can be explained by mixing of depleted and enriched source components.A depleted component is indicated by alkali basalt compositions and is similar to some depleted OIB (PREMA).The enriched component,similar to sediment compositions,is indicated by tholeiites with high LILE/HFSE,207Pb/204Pb,and 87Sr/86Sr ratios.In general,basalts from Hainan and the South China Basin(SCB)share common geochemical characters.e.g.high Rb/Sr,Th/Ta,207Pb/206Pb,and low Ba/Th ratios.Such a geochemical trend is comparable to that of EMII-type OIB and best explained as the result of subduction.Occurrence of these characteristics in both continental Hainan basalts and SCB seamout basalts indicates the presence of a South China geochemical domain that exists in the mantle region below the lithosphere.

  17. Osmium isotope and highly siderophile element systematics of lunar impact melt breccias: Implications for the late accretion history of the Moon and Earth (United States)

    Puchtel, Igor S.; Walker, Richard J.; James, Odette B.; Kring, David A.


    To characterize the compositions of materials accreted to the Earth-Moon system between about 4.5 and 3.8 Ga, we have determined Os isotopic compositions and some highly siderophile element (HSE: Re, Os, Ir, Ru, Pt, and Pd) abundances in 48 subsamples of six lunar breccias. These are: Apollo 17 poikilitic melt breccias 72395 and 76215; Apollo 17 aphanitic melt breccias 73215 and 73255; Apollo 14 polymict breccia 14321; and lunar meteorite NWA482, a crystallized impact melt. Plots of Ir versus other HSE define excellent linear correlations, indicating that all data sets likely represent dominantly two-component mixtures of a low-HSE target, presumably endogenous component, and a high-HSE, presumably exogenous component. Linear regressions of these trends yield intercepts that are statistically indistinguishable from zero for all HSE, except for Ru and Pd in two samples. The slopes of the linear regressions are insensitive to target rock contributions of Ru and Pd of the magnitude observed; thus, the trendline slopes approximate the elemental ratios present in the impactor components contributed to these rocks. The 187Os/188Os and regression-derived elemental ratios for the Apollo 17 aphanitic melt breccias and the lunar meteorite indicate that the impactor components in these samples have close affinities to chondritic meteorites. The HSE in the Apollo 17 aphanitic melt breccias, however, might partially or entirely reflect the HSE characteristics of HSE-rich granulitic breccia clasts that were incorporated in the impact melt at the time of its creation. In this case, the HSE characteristics of these rocks may reflect those of an impactor that predated the impact event that led to the creation of the melt breccias. The impactor components in the Apollo 17 poikilitic melt breccias and in the Apollo 14 breccia have higher 187Os/188Os, Pt/Ir, and Ru/Ir and lower Os/Ir than most chondrites. These compositions suggest that the impactors they represent were chemically

  18. Pb isotopes during mingling and melting

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Lesher, Charles E.


    Pb isotopic data are presented for hybrid rocks formed by mingling between mantle-derived tholeiitic magma of the Eocene Miki Fjord macrodike (East Greenland) and melt derived from the adjacent Precambrian basement. Bulk mixing and AFC processes between end-members readily identified in the field...... fail to model the Pb isotope systematics. Selective contamination during diffusional exchange, which can explain the complex Sr and Nd isotope compositions of the hybrid rocks (Blichert-Toft et al., 1992), cannot fully account for the variability of the Pb isotopic data using the identified crustal end......-members. The crustal anatectic end-member, although similar in Sr and Nd isotope composition, has a markedly different Pb isotopic composition than its source gneiss. The differences are consistent with preferential incorporation of radiogenic Pb from accessory phases such as metamict zircon or loosely-bound Pb from...

  19. Syn-orogenic high-temperature crustal melting: Geochronological and Nd-Sr-Pb isotope constraints from basement-derived granites (Central Damara Orogen, Namibia) (United States)

    Ostendorf, Jörg; Jung, Stefan; Berndt-Gerdes, Jasper; Hauff, Folkmar


    Major and trace element and Nd, Sr and Pb isotope data from c. 550 Ma-old gray granites and c. 510 Ma-old red leucogranites of the high-grade central part of the Damara orogen (Namibia) indicate a dominantly deep crustal origin. Moderately peraluminous gray granites are isotopically evolved (initial ɛNd: c. - 17) and were likely derived from meta-igneous sources with late Archean to Paleoproterozoic crustal residence ages. Based on a comparison with experimental results, the granites were derived by partial melting of a granodioritic biotite gneiss at c. 900-950 °C and less than 10 kbar. Slightly peraluminous red leucogranites are also isotopically evolved (initial ɛNd: - 15 to - 18) but have undergone extensive crystal fractionation coupled with minor contamination of mid crustal meta-pelitic material. Major and trace element data do not support closed-system fractional crystallization processes for all samples, however, some chemical features underline the importance of crystal fractionation processes especially for the leucogranites. Isotope data do not support mixing of different crust-derived melts or assimilation of crustal rocks by a mafic magma on a large scale. For the gray granites, unradiogenic Pb isotope compositions with substantial variation in 207Pb/204Pb at almost constant 206Pb/204Pb, strongly negative ɛNd values and moderately radiogenic Sr isotope compositions argue for an undepleted nature of the source. High Rb/Sr ratios of the red leucogranites permit a comparison with the gray granites but similar initial ɛNd values indicate that the source of these granites is not fundamentally different to the source of the gray granites. The most acceptable model for both granite types involves partial melting of meta-igneous basement rocks of Archean to Proterozoic age. The consistency of the chemical data with a crustal anatectic origin and the observation that the gray granites intruded before the first peak of high-grade regional metamorphism

  20. Magma sources and mixing for the Coastal Batholith in southern Peru: insights from new elemental and isotopic data and from comparison with California batholithic rocks (United States)

    Clausen, B. L.; Martinez, A. M.; Gonzalez, L. U.; Poma, O.; Paterson, S. R.; Ianno, A.


    Seventy granitoid samples recently collected from the Arequipa segment of the Cretaceous Coastal Batholith near Ica, Peru are made up of a combination of diorites, tonalites, monzonites, and granodiorites previously divided into super-units from west to east as: Linga, Pampahuasi, Tiabaya, and Incahuasi. A few associated earlier gabbros are also included. Elemental and isotopic data and petrographic analyses from these new samples along with previous data from the same area provides a data set of about one hundred samples. They yield new insights into across-arc geochemical variation, when compared with data from California batholithic rocks in the Sierra Nevada Mountains and in the Peninsular and Transverse Ranges and Mojave Desert. >>Of the 26 new Rb-Sr isotope data points from Peru: nineteen lie on previous isochrons for the four super-units that yield ages of 80-100 Ma; six lie above the isochrons, two of which match a Pampahuasi data cluster previously interpreted as due to magma mixing; one Linga data point lies below the isochrons as part of a 140 Ma apparent isochron previously interpreted as due to mixing. >>Based on principal component analysis (PCA) of data from California and Peru, the data can be summarized in terms of four factors related to: (1) extent of differentiation and/or mixing using a MgO Harker diagram, (2) relative contributions of mantle and lower crustal input using the Nb/Yb ratio and Nd-Sr and Pb isotope plots, (3) magma source depth using Sr/Y and Gd/Yb ratios, and (4) calc-alkalinity using a K2O Harker diagram and a Rb-Sr bivariate plot. Two other plots of Al2O3 content and TiO2/Fe2O3 ratios assess alumina saturation and ilmenite/magnetite variation. >>Comparison with the two thousand California data points is impractical individually and requires a grouping of the samples, so that only mean and standard deviation of California data groups are plotted. The baseline for comparing the PCA factors [least crustal contamination, shallowest

  1. Sr-Nd-Pb-C-O isotope systematics of carbonated ultramafic xenoliths from Mafu, Taiwan: Evidence for an extremely enriched lithospheric mantle source beneath the extended margin of the South China block (United States)

    Smith, A. D.; Wen, D.; Chung, S.; Wang, K.; Chiang, H.; Tsai, C.


    Deep-seated carbonate melt is widely proposed as an effective agent to metasomatize the lithospheric mantle. However, such carbonate melts may have a great diversity of composition and a mantle or recycled origin remains unclear. Here we present the evidence for unique carbonate metasomatism of the continental lithospheric mantle (CLM) beneath the extended southeast margin of the South China block from severely replaced spinel peridotite xenoliths from Mafu, northwestern Taiwan. The metasomatic calcitic carbonates and whole carbonated xenoliths from Mafu have unusually low trace element abundances (total REE abundance residue (86Sr/87Sr = 0.7041; ɛ Nd = +4.9, one residual sample up to +12; 206Pb/204Pb = 18.3), the Sr-Nd-Pb-C-O isotope systematics of the carbonates (86Sr/87Sr = 0.7044-0.7045; ɛ Nd = -6.9 to -7.7; 206Pb/204Pb = 18.5; δ13C = -4.5 to -5.7; δ18O = +21.8 to +22.9) reveal an extremely enriched and heterogeneous CLM. According to the Nd model age, the enriched component evolved for at least 1 Gyrs after isolation from the depleted CLM, before the Late Miocene entrapment. Coupled with high Sr/Nd, Ba/Th, La/Yb, Zr/Hf, and low Nb/U, Ce/Pb, Th/U, Ti/Eu ratios, this EM1-like metasomatic agent may be one of the most efficient percolating melt to cause disequlibrium interaction or Sr-Nd isotope decoupling. To a broader interpretation, it offers an alternative to account for some enriched signatures in mantle lithosphere, such as the extreme components of the Hawaiian plume. Instead of the "ghost plagioclase" (Sobolev et al., 2000), melting of depleted lithosphere which was metasomatized by this kind of enriched carbonate melt with high Sr, Ba, Pb but low Al and REE contents, may even better explain the geochemical features observed from the melt inclusions in Mauna Loa olivines.

  2. A model for osmium isotopic evolution of metallic solids at the core-mantle boundary

    National Research Council Canada - National Science Library

    Munir Humayun


      Radiogenic and unradiogenic Os isotopes require a new physical model A cumulate pile model of the CMB provides a suitable explanation Other isotope systematics are consistent with this model Some...

  3. Multiconfiguration calculations of electronic isotope shift factors in Al I

    CERN Document Server

    Filippin, Livio; Ekman, Jörgen; Fritzsche, Stephan; Godefroid, Michel; Jönsson, Per


    The present work reports results from systematic multiconfiguration Dirac-Hartree-Fock calculations of electronic isotope shift factors for a set of transitions between low-lying states in neutral aluminium. These electronic quantities together with observed isotope shifts between different pairs of isotopes provide the changes in mean-square charge radii of the atomic nuclei. Two computational approaches are adopted for the estimation of the mass- and field shift factors. Within these approaches, different models for electron correlation are explored in a systematic way to determine a reliable computational strategy and estimate theoretical uncertainties of the isotope shift factors.

  4. Exploring the isotopic niche: isotopic variance, physiological incorporation, and the temporal dynamics of foraging

    Directory of Open Access Journals (Sweden)

    Justin Douglas Yeakel


    Full Text Available Consumer foraging behaviors are dynamic, changing in response to prey availability, seasonality, competition, and even the consumer's physiological state. The isotopic composition of a consumer is a product of these factors as well as the isotopic `landscape' of its prey, i.e. the isotopic mixing space. Stable isotope mixing models are used to back-calculate the most likely proportional contribution of a set of prey to a consumer's diet based on their respective isotopic distributions, however they are disconnected from ecological process. Here we build a mechanistic framework that links the ecological and physiological processes of an individual consumer to the isotopic distribution that describes its diet, and ultimately to the isotopic composition of its own tissues, defined as its `isotopic niche’. By coupling these processes, we systematically investigate under what conditions the isotopic niche of a consumer changes as a function of both the geometric properties of its mixing space and foraging strategies that may be static or dynamic over time. Results of our derivations reveal general insight into the conditions impacting isotopic niche width as a function of consumer specialization on prey, as well as the consumer's ability to transition between diets over time. We show analytically that moderate specialization on isotopically unique prey can serve to maximize a consumer's isotopic niche width, while temporally dynamic diets will tend to result in peak isotopic variance during dietary transitions. We demonstrate the relevance of our theoretical findings by examining a marine system composed of nine invertebrate species commonly consumed by sea otters. In general, our analytical framework highlights the complex interplay of mixing space geometry and consumer dietary behavior in driving expansion and contraction of the isotopic niche. Because this approach is established on ecological mechanism, it is well-suited for enhancing the

  5. 皖西前寒武纪变质岩系地质年代学研究

    Institute of Scientific and Technical Information of China (English)



    Isotopic ages of Precambrian metamorphic rocks from western Anhui have beeu determined, giving, a whole-rock Rb-Sr isochron age of 2.7 b.y. and two groups of mineral Rb-Sr isochron ages ranging from 2.3 to 2.2 and 1.8 to 1.4 b.y. respectively. These ages represent the time of cooling of the rocks affected by thermal events. U-Th-Pb ages indicate that the U-Pb isotopic system was disturbed during metamorphism. But Th-Pb, Pb-Pb and whole-rock Rb-Sr ages are relatively concordant while K-At and Rb-Sr ages are all the same. Initial 87Sr/86Sr ratios in the metamorphic rocks are within the range of 0.704---0.707.This shows that these rocks contain significant amounts of sialic materials.

  6. Primary magmas and mantle sources of Emeishan basalts constrained from major element, trace element and Pb isotope compositions of olivine-hosted melt inclusions (United States)

    Ren, Zhong-Yuan; Wu, Ya-Dong; Zhang, Le; Nichols, Alexander R. L.; Hong, Lu-Bing; Zhang, Yin-Hui; Zhang, Yan; Liu, Jian-Qiang; Xu, Yi-Gang


    Olivine-hosted melt inclusions within lava retain important information regarding the lava's primary magma compositions and mantle sources. Thus, they can be used to infer the nature of the mantle sources of large igneous provinces, which is still not well known and of the subject of debate. We have analysed the chemical compositions and Pb isotopic ratios of olivine-hosted melt inclusions in the Dali picrites, Emeishan Large Igneous Province (LIP), SW China. These are the first in-situ Pb isotope data measured for melt inclusions found in the Emeishan picrites and allow new constraints to be placed on the source lithology of the Emeishan LIP. The melt inclusions show chemical compositional variations, spanning low-, intermediate- and high-Ti compositions, while their host whole rocks are restricted to the intermediate-Ti compositions. Together with the relatively constant Pb isotope ratios of the melt inclusions, the compositional variations suggest that the low-, intermediate- and high-Ti melts were derived from compositionally similar sources. The geochemical characteristics of melt inclusions, their host olivines, and whole-rocks from the Emeishan LIP indicate that Ca, Al, Mn, Yb, and Lu behave compatibly, and Ti, Rb, Sr, Zr, and Nb behave incompatibly during partial melting, requiring a pyroxenite source for the Emeishin LIP. The wide range of Ti contents in the melt inclusions and whole-rocks of the Emeishan basalts reflects different degrees of partial melting in the pyroxenite source at different depths in the melting column. The Pb isotope compositions of the melt inclusions and the OIB-like trace element compositions of the Emeishan basalts imply that mixing of a recycled ancient oceanic crust (EM1-like) component with a peridotite component from the lower mantle (FOZO-like component) could have underwent solid-state reaction, producing a secondary pyroxenite source that was subsequently partially melted to form the basalts. This new model of pyroxenite

  7. Contrasting Cu-Au and Sn-W Granite Metallogeny through the Zircon Geochemical and Isotopic Record (United States)

    Gardiner, Nicholas; Hawkesworth, Chris; Robb, Laurence; Whitehouse, Martin; Roberts, Nick; Kirkland, Chris


    Magmatic genesis and evolution - mediated by geodynamic setting - exert a primary control on the propensity of granites to be metal fertile. A revolution in our understanding of these petrogenetic processes has been made through a range of mineral-based tools, most notably the common accessory mineral zircon. There is consequently considerable interest in whether the geochemical and isotopic compositions of zircon can be applied to metallogenic problems. The paired magmatic belts of Myanmar have broadly contrasting metallogenic affinities (Sn-W versus Cu-Au), and are interpreted to have formed on the accretionary margin of the subducting Neo-Tethys Ocean. They therefore present the opportunity to geochemically compare and contrast the zircon compositions in two end-member types of granite-hosted mineral deposits generated in collisional settings. We present an integrated zircon isotope (U-Pb, Lu-Hf, O) and trace element dataset that fingerprint: (a) source; (b) redox conditions; and (c) degree of fractionation. These variables all impact on magma fertility, and our key question to address is whether they can be reliably traced and calibrated within the Myanmar zircon record. Granitoid-hosted zircons from the I-type copper arc have juvenile ɛHf (+7 to +12) and mantle-like δ18O (5.3 ‰), whereas zircons from the S-type tin belt have low ɛHf (-7 to -13) and heavier δ18O (6.2-7.7 ‰). Plotting Hf versus U/Yb reaffirms that the tin belt magmas contain greater crustal contributions than the copper arc rocks. Links between whole rock Rb/Sr and zircon Eu/Eu* highlights that the latter can be used to monitor magma fractionation in systems that crystallize plagioclase (low Sr/Y). Ce/Ce* and Eu/Eu* in zircon are thus sensitive to redox and fractionation respectively, and can be used to evaluate the sensitivity of zircons to the metallogenic affinity of their host rocks. Tin contents that exceed the solubility limit are required in order to make a magmatic

  8. The terrestrial uranium isotope cycle. (United States)

    Andersen, Morten B; Elliott, Tim; Freymuth, Heye; Sims, Kenneth W W; Niu, Yaoling; Kelley, Katherine A


    Changing conditions on the Earth's surface can have a remarkable influence on the composition of its overwhelmingly more massive interior. The global distribution of uranium is a notable example. In early Earth history, the continental crust was enriched in uranium. Yet after the initial rise in atmospheric oxygen, about 2.4 billion years ago, the aqueous mobility of oxidized uranium resulted in its significant transport to the oceans and, ultimately, by means of subduction, back to the mantle. Here we explore the isotopic characteristics of this global uranium cycle. We show that the subducted flux of uranium is isotopically distinct, with high (238)U/(235)U ratios, as a result of alteration processes at the bottom of an oxic ocean. We also find that mid-ocean-ridge basalts (MORBs) have (238)U/(235)U ratios higher than does the bulk Earth, confirming the widespread pollution of the upper mantle with this recycled uranium. Although many ocean island basalts (OIBs) are argued to contain a recycled component, their uranium isotopic compositions do not differ from those of the bulk Earth. Because subducted uranium was probably isotopically unfractionated before full oceanic oxidation, about 600 million years ago, this observation reflects the greater antiquity of OIB sources. Elemental and isotope systematics of uranium in OIBs are strikingly consistent with previous OIB lead model ages, indicating that these mantle reservoirs formed between 2.4 and 1.8 billion years ago. In contrast, the uranium isotopic composition of MORB requires the convective stirring of recycled uranium throughout the upper mantle within the past 600 million years.

  9. Laser Spectroscopy of Neutron Rich Bismuth Isotopes

    CERN Multimedia


    %IS344 :\\\\ \\\\ The aim of the experiment is to measure the optical isotope shifts and hyperfine structures of bismuth isotopes across the N=126 shell closure in order to extract the change in mean square charge radii ($\\delta\\langle r^{2}\\rangle$) and static moments. These include the first isotones of lead to be measured directly above the shell closure and will provide new information on the systematics of the kink ($\\delta\\langle r^{2}\\rangle)$ seen in the lead isotopic chain. After two very successful runs the programme has been extended to include the neutron deficient isotopes below $^{201}$Bi to study the systematics across the $i_{13/2}$ neutron sub-shell closure at N=118.\\\\ \\\\ During the initial 2 runs (9 shifts) the isotope shifts and hyperfine structures of three new isotopes, $ ^{210,212,213}$Bi and the 9$^{-}$ isomer of $^{210}$Bi have been measured. The accuracy of the previous measurements of $^{205,206,208}$Bi have been greatly improved. The samples of $ ^{208,210,210^{m}}$Bi were prepared by c...

  10. Heavy ion isotope resolution with polymer detectors


    Vidal-Quadras Roca, Alejo; Ortega Girón, Manuel; Fernández Moreno, Francisco; Font Garcia, Josep Lluís; Casas Ametller, Montserrat; Baixeras Divar, Carmen; Gonzalo Cestero, Miguel


    The heavy ion mass resolution power of polymer detectors Lexan and cellulose nitrate is systematically studied both for accelerator and for cosmic ions. It is concluded that a satisfactory isotopic discrimination, better than 1 u, is hardly attainable with these detectors. Peer Reviewed

  11. In situ Sr isotope analysis of apatite by LA-MC-ICPMS: constraints on the evolution of ore fluids of the Yinachang Fe-Cu-REE deposit, Southwest China (United States)

    Zhao, Xin-Fu; Zhou, Mei-Fu; Gao, Jian-Feng; Li, Xiao-Chun; Li, Jian-Wei


    Apatite is a ubiquitous accessory mineral in a variety of rocks and hydrothermal ores. Strontium isotopes of apatite are well known to retain petrogenetic information and have been widely used to investigate the origin of igneous rocks, but such attempts have rarely been made to constrain ore-forming processes of hydrothermal systems. We here report in situ LA-MC-ICPMS Sr isotope data of apatite from the ~1660-Ma Yinachang Fe-Cu-REE deposit, Southwest China. The formation of this deposit was coeval to the emplacement of regionally distributed doleritic intrusions within a continental-rift setting. The deposit has a paragenetic sequence consisting of sodic alteration (stage I), magnetite mineralization (stage II), Cu sulfide and REE mineralization (stage III), and final barren calcite veining (stage IV). The stage II and III assemblages contain abundant apatite, allowing to investigate the temporal evolution of the Sr isotopic composition of the ore fluids. Apatite of stage II (Apt II) is associated with fluorite, magnetite, and siderite, whereas apatite from stage III (Apt III) occurs intimately intergrown with ankerite and Cu sulfides. Apt II has 87Sr/86Sr ratios varying from 0.70377 to 0.71074, broadly compatible with the coeval doleritic intrusions (0.70592 to 0.70692), indicating that ore-forming fluids responsible for stage II magnetite mineralization were largely equilibrated with mantle-derived mafic rocks. In contrast, Apt III has distinctly higher 87Sr/86Sr ratios from 0.71021 to 0.72114, which are interpreted to reflect external radiogenic Sr, likely derived from the Paleoproterozoic strata. Some Apt III crystals have undergone extensive metasomatism indicated by abundant monazite inclusions. The metasomatized apatite has much higher 87Sr/86Sr ratios up to 0.73721, which is consistent with bulk-rock Rb-Sr isotope analyses of Cu ores with 87Sr/86Sri from 0.71906 to 0.74632. The elevated 87Sr/86Sr values of metasomatized apatite and bulk Cu ores indicate

  12. Stable isotope studies

    Energy Technology Data Exchange (ETDEWEB)

    Ishida, T.


    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  13. Barren Miocene granitoids in the Central Andean metallogenic belt, Chile: Geochemistry and Nd-Hf and U-Pb isotope systematics Granitoides estériles del Mioceno en la franja metalogénica de los Andes Centrales, Chile: geoquímica e isotopía de Nd-Hf y U-Pb

    Directory of Open Access Journals (Sweden)

    Katja Deckart


    Full Text Available Four Middle-to-Late Miocene barren plutonic complexes that occur between the giant porphyry copper deposits of the central Chilean Andes were selected for U-Pb LA-ICPMS geochronology and Hf-isotope systematics on single zircon grains. Major and trace elements and Sr-Nd-Hf isotope whole rock geochemical studies were under-taken to compare with slightly younger or coeval barren and fertile intrusive rocks between 32° and 34°S. The studied granitoids yield resolvable crystallization ages of 11.3±0.1 Ma (Cerro Mesón Alto massif, 10.3±0.2 Ma (La Gloria pluton, 14.9±0.2 Ma/14.9±0.1 Ma (Yerba Loca stock and 11.2±0.1 Ma/14.7±0.1 Ma (San Francisco Batholith. Major and trace elements discard an adakitic signature as suggested for coeval porphyric intrusions at 32°S, slightly younger mineralized porphyries at Río Blanco-Los Bronces deposit and other Cenozoic adakites. Volcanic host rocks are less fractionated than the intrusive rock units. The same observation can be made for the unmineralized northern plutons compared to the southern ones. Initial Sr-Nd isotope data show insignificant variation (0.703761-0.704118 and 0.512758-0.512882, plotting in the mantle array. Trace element enrichment can be explained by addition of subducted-slab fluids and/or terrigenous sediments to the mantle wedge prior to and/or slight crustal input during magma ascent. Zircon grains separated from these barren intrusives share a similar initial εHf i-data variation for the younger age group (10-12 Ma; 7.04-9.54 and show a more scattered range for the older one (14-15 Ma; 8.50-15.34; both sets plot between the DM and CLTUR evolution lines. There is evidence that magma evolution was slightly distinct through time from older to younger barren magmatism, compared to a few fertile porphyritic rocks from Río Blanco-Los Bronces porphyry copper deposit. It is suggested that chronological inconsistencies within these complexes might be related to differential shortening

  14. Stable C, O and clumped isotope systematics and 14C geochronology of carbonates from the Quaternary Chewaucan closed-basin lake system, Great Basin, USA: Implications for paleoenvironmental reconstructions using carbonates (United States)

    Hudson, Adam M.; Quade, Jay; Ali, Guleed; Boyle, Douglas; Bassett, Scott; Huntington, Katharine W.; De los Santos, Marie G.; Cohen, Andrew S.; Lin, Ke; Wang, Xiangfeng


    Isotopic compositions of lacustrine carbonates are commonly used for dating and paleoenvironmental reconstructions. Here we use carbonate δ13C and δ18O, clumped (Δ47), and 14C compositions to better understand the carbonate isotope system in closed-basin lakes and trace the paleohydrologic and temperature evolution in the Chewaucan closed-basin lake system, northern Great Basin, USA, over the Last Glacial/Holocene transition. We focus on shorezone tufas to establish that they form in isotopic equilibrium with lake water and DIC, they can be dated reliably using 14C, and their clumped isotope composition can be used to reconstruct past lake temperature. Calculations of the DIC budget and reservoir age for the lake indicate residence time is short, and dominated by exchange with atmospheric CO2 at all past lake levels. Modern lake DIC and shorezone tufas yield δ13C and 14C values consistent with isotopic equilibrium with recent fossil fuel and bomb-influenced atmospheric CO2, supporting these calculations. δ13C values of fossil tufas are also consistent with isotopic equilibrium with pre-industrial atmospheric CO2 at all shoreline elevations. This indicates that the 14C reservoir effect for this material is negligible. Clumped isotope (Δ47) results indicate shorezone tufas record mean annual lake temperature. Modern (average 13 ± 2 °C) and 18 ka BP-age tufas (average 6 ± 2 °C) have significantly different temperatures consistent with mean annual temperature lowering of 7 ± 3 °C (1 SE) under full glacial conditions. For shorezone tufas and other lake carbonates, including spring mounds, mollusk shells, and ostracod tests, overall δ13C and δ18O values co-vary according to the relative contribution of spring and lacustrine end member DIC and water compositions in the drainage system, but specific isotope values depend strongly upon sample context and are not well correlated with past lake depth. This contrasts with the interpretation that carbonate

  15. Stable C, O and clumped isotope systematics and 14C geochronology of carbonates from the Quaternary Chewaucan closed-basin lake system, Great Basin, USA: Implications for paleoenvironmental reconstructions using carbonates (United States)

    Hudson, Adam; Quade, Jay; Ali, Guleed; Boyle, Douglas P.; Bassett, Scott; Huntington, Katharine W.; De los Santos, Marie G.; Cohen, Andrew S.; Lin, Ke; Wang, Xiangfeng


    Isotopic compositions of lacustrine carbonates are commonly used for dating and paleoenvironmental reconstructions. Here we use carbonate δ13C and δ18O, clumped (Δ47), and 14C compositions to better understand the carbonate isotope system in closed-basin lakes and trace the paleohydrologic and temperature evolution in the Chewaucan closed-basin lake system, northern Great Basin, USA, over the Last Glacial/Holocene transition. We focus on shorezone tufas to establish that they form in isotopic equilibrium with lake water and DIC, they can be dated reliably using 14C, and their clumped isotope composition can be used to reconstruct past lake temperature. Calculations of the DIC budget and reservoir age for the lake indicate residence time is short, and dominated by exchange with atmospheric CO2 at all past lake levels. Modern lake DIC and shorezone tufas yield δ13C and 14C values consistent with isotopic equilibrium with recent fossil fuel and bomb-influenced atmospheric CO2, supporting these calculations. δ13C values of fossil tufas are also consistent with isotopic equilibrium with pre-industrial atmospheric CO2 at all shoreline elevations. This indicates that the 14C reservoir effect for this material is negligible. Clumped isotope (Δ47) results indicate shorezone tufas record mean annual lake temperature. Modern (average 13 ± 2 °C) and 18 ka BP-age tufas (average 6 ± 2 °C) have significantly different temperatures consistent with mean annual temperature lowering of 7 ± 3 °C (1 SE) under full glacial conditions. For shorezone tufas and other lake carbonates, including spring mounds, mollusk shells, and ostracod tests, overall δ13C and δ18O values co-vary according to the relative contribution of spring and lacustrine end member DIC and water compositions in the drainage system, but specific isotope values depend strongly upon sample context and are not well correlated with past lake depth. This contrasts with the interpretation that carbonate

  16. The anomalous quadrupole collectivity in Te isotopes

    CERN Document Server

    Qi, Chong


    We present systematic calculations on the spectroscopy and transition properties of even-even Te isotopes by using the large-scale configuration interaction shell model approach with a realistic interaction. These nuclei are of particular interest since their yrast spectra show a vibrational-like equally-spaced pattern but the few known E2 transitions show anomalous rotational-like behavior, which cannot be reproduced by collective models. Our calculations reproduce well the equally-spaced spectra of those isotopes as well as the constant behavior of the $B(E2)$ values in $^{114}$Te. The calculated $B(E2)$ values for neutron-deficient and heavier Te isotopes show contrasting different behaviors along the yrast line. The $B(E2)$ of light isotopes can exhibit a nearly constant bevavior upto high spins. We show that this is related to the enhanced neutron-proton correlation when approaching $N=50$.

  17. Development of proliferation resistant isotope separation technology

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Doyoung; Ko, Kwanghoon; Kim, Taeksoo; Park, Hyunmin; Lim, Gwon; Cha, Yongho; Han, Jaemin; Baik, Sunghoon; Cha, Hyungki


    This project was accomplished with an aim of establishing the industrial facilities for isotope separation in Korea. The experiment for the measurement of neutrino mass that has been an issue in physics, needs very much of enriched calcium-48 isotope. However, calcium-48 isotope can be produced only by the electro-magnetic method and, thus, its price is very expensive. Therefore, we expect that ALSIS can replace the electro-magnetic method for calcium-48 isotope production. In this research stage, the research was advanced systematically with core technologies, such as atomic vapor production, the measurement of vapor characteristics and stable and powerful laser development. These researches will be the basis of the next research stages. In addition, the international research trends and cooperation results are reported in this report.

  18. High-spin study of {sup 128}Ce and systematics of quasiparticle pair alignment[21.10.Re; 27.60+q; 23.20.Lv.; Nuclear reactions: 32S+100Mo at 155, 160 MeV; Enriched targets; Euroball spectrometer of Compton-suppressed HPGe detectors; Measured E{gamma}, I{gamma}; Comparison of alignment properties with neighbouring isotopes and isotones; Comparison with Woods-Saxon cranking calculations

    Energy Technology Data Exchange (ETDEWEB)

    Paul, E.S.; Bednarczyk, P.; Boston, A.J.; Chiara, C.J.; Foin, C.; Fossan, D.B.; Genevey, J.; Gizon, A.; Gizon, J.; Jenkins, D.G.; Kelsall, N.; Kintz, N.; Koike, T.; LaFosse, D.R.; Nolan, P.J.; Nyako, B.M.; Parry, C.M.; Sampson, J.A.; Semple, A.T.; Starosta, K.; Timar, J.; Wadsworth, R.; Wilson, A.N.; Zolnai, L


    High-spin states have been studied in {sup 128}Ce, produced in the {sup 100}Mo({sup 32}S,4n) reaction, using the EUROBALL {gamma}-ray spectrometer. A quadruples analysis ({gamma}{sup 4}) of the data has extended several bands to high spin. Systematics of quasiparticle alignments in cerium isotopes and relevant isotonic chains are discussed and compared to Woods-Saxon cranking calculations.

  19. High-spin study of sup 1 sup 2 sup 8 Ce and systematics of quasiparticle pair alignment 21.10.Re; 27.60+q; 23.20.Lv.; Nuclear reactions: 32S+100Mo at 155, 160 MeV; Enriched targets; Euroball spectrometer of Compton-suppressed HPGe detectors; Measured E gamma, I gamma; Comparison of alignment properties with neighbouring isotopes and isotones; Comparison with Woods-Saxon cranking calculations

    CERN Document Server

    Paul, E S; Boston, A J; Chiara, C J; Foin, C; Fossan, D B; Genevey, J; Gizon, A; Gizon, J; Jenkins, D G; Kelsall, N; Kintz, N; Koike, T; Lafosse, D R; Nolan, P J; Nyakó, B M; Parry, C M; Sampson, J A; Semple, A T; Starosta, K; Timar, J; Wadsworth, R; Wilson, A N; Zolnai, L


    High-spin states have been studied in sup 1 sup 2 sup 8 Ce, produced in the sup 1 sup 0 sup 0 Mo( sup 3 sup 2 S,4n) reaction, using the EUROBALL gamma-ray spectrometer. A quadruples analysis (gamma sup 4) of the data has extended several bands to high spin. Systematics of quasiparticle alignments in cerium isotopes and relevant isotonic chains are discussed and compared to Woods-Saxon cranking calculations.

  20. Age determination and development of experimental methods for quaternary fault and formation

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kwang Sik; Choi, M. S.; Kim, J. M. [Korea Basic Science Institute, Daejeon (Korea, Republic of)] (and others)


    Late cretaceous to early tertiary movement ages were constrained by Rb-Sr and K-Ar dating of fault rocks near the Uljin Nuclear Power Plants. These ages are well reproducible and consistent with geologic context. Tectonic evolution of the northeastern Yeongnam massif, the site of the Uljin Nuclear Power Plants, was investigated on the basis of Rb-Sr, Sm-Nd and Pb isotopic systematics and geochemistry of precambrian basement rocks including the Hosanri Formation, Buncheon granite gneiss, biotite granite gneiss, and Hongjesa granite. The optical ages from the Suryum fault outcrop represent the younger limit of sedimentation timing because they are simply based upon the present-day water content. The lower, Qt{sub 2} terrace at about 18m elevation is correlated with Marine Isotopic Stage (MIS) 5a, although its apparent optical age was consistently reported from 71 to 48 ka. Correlation of shoreline elevations indicates the correspondence of the Qt{sub 3a} terrace to MIS 5e, which is supported by stratigraphically concordant optical ages for aeolian sand dunes at the north of the Suryum site. This time scale yields an uplift rate of 0.266 m/ka, requiring the revision of conventional view that the Korean peninsula is tectonically very stable.

  1. Rb–Sr and Sm–Nd isotope systematics and geochemical studies on metavolcanic rocks from Peddavura greenstone belt: Evidence for presence of Mesoarchean continental crust in easternmost part of Dharwar Craton, India

    Indian Academy of Sciences (India)

    M Rajamanickam; S Balakrishnan; R Bhutani


    Linear, north–south trending Peddavura greenstone belt occurs in easternmost part of the Dharwar Craton. It consists of pillowed basalts, basaltic andesites, andesites (BBA) and rhyolites interlayered with ferruginous chert that were formed under submarine condition. Rhyolites were divided into type-I and II based on their REE abundances and HREE fractionation. Rb–Sr and Sm–Nd isotope studies were carried out on the rock types to understand the evolution of the Dharwar Craton. Due to source heterogeneity Sm–Nd isotope system has not yielded any precise age. Rb–Sr whole-rock isochron age of 2551 ± 19 (MSWD = 1.16) Ma for BBA group could represent time of seafloor metamorphism after the formation of basaltic rocks. Magmas representing BBA group of samples do not show evidence for crustal contamination while magmas representing type-II rhyolites had undergone variable extents of assimilation of Mesoarchean continental crust (< 3.3 Ga) as evident from their initial Nd isotope values. Trace element and Nd isotope characteristics of type I rhyolites are consistent with model of generation of their magmas by partial melting of mixed sources consisting of basalt and oceanic sediments with continental crustal components. Thus this study shows evidence for presence of Mesoarchean continental crust in Peddavura area in eastern part of Dharwar Craton.

  2. Palaeoproterozoic continental arc magmatism, and Neoproterozoic metamorphism in the Aravalli-Delhi orogenic belt, NW India: New constraints from in situ zircon U-Pb-Hf isotope systematics, monazite dating and whole-rock geochemistry (United States)

    Kaur, Parampreet; Zeh, Armin; Chaudhri, Naveen


    Presently, the extent, origin and petrogenesis of late Palaeoproterozoic (ca. 1.85 Ga) magmatism in the north-central Aravalli-Delhi orogenic belt, NW India and subsequent metamorphic overprints are poorly constrained. Results of new in situ zircon U-Pb-Hf isotope analyses in combination with whole-rock elemental and isotopic data provide the first hard evidence that granitoid magmatism occurred in a continental magmatic arc setting between 1.86 and 1.81 Ga. The Hf-Nd model ages of 3.0-2.6 Ga and inherited zircon grains of 3.3-2.5 Ga indicate abundant reworking of Archaean crust. Flat HREE patterns with negative Eu anomalies furthermore reveal that the granitoids were generated from garnet-free and plagioclase-rich sources at shallow depths. Significant isotope variation among granitoid samples (εHft = -3.7 to -9.0; εNdt = -4.8 to -7.9) indicate that the reworked Archaean crust was not completely homogenised during the Palaeoproterozoic. This is best reflected by zircon Hf-isotope variation of ca. 9.5 epsilon units within the oldest granitoid sample. Zircon grains from this sample define three discrete Hf-isotope groups at εHf1.86Ga = -8.9, -4.8 and -1.6. These are interpreted to result from mixing of zircon-saturated magmas derived from three distinct sources within the crust prior to solidification. A monazite U-Pb isochron age of 868 ± 4 Ma from one of the granitoid samples furthermore indicates that the Aravalli fold belt was affected by an important post-magmatic overprint, perhaps related to the widespread metasomatic, granulite metamorphic and/or magmatic events during the same time span.

  3. Calcium isotopes in wine (United States)

    Holmden, C. E.


    The δ 44/40Ca values of bottled wine vary between -0.76% to -1.55% on the seawater scale and correlate weakly with inverse Ca concentration and Mg/Ca ratio, such that the lowest δ 44/40Ca values have the highest Ca concentrations and lowest Mg/Ca ratios. The correlation is notable in the sense that the measured wines include both whites and reds sampled from different wine growing regions of the world, and cover a wide range of quality. Trends among the data yield clues regarding the cause of the observed isotopic fractionation. White wines, and wines generally perceived to be of lower quality, have lower δ 44/40Ca values compared to red wines and wines of generally perceived higher quality. Quality was assessed qualitatively through sensory evaluation, price, and scores assigned by critics. The relationship between δ 44/40Ca and wine quality was most apparent when comparing wines of one varietal from one producer from the same growing region. In the vineyard, wine quality is related to factors such as the tonnage of the crop and the ripeness of the grapes at the time of harvesting, the thickness of the skins for reds, the age of the vines, as well as the place where the grapes were grown (terroir). Quality is also influenced by winemaking practices such as fermentation temperature, duration of skin contact, and barrel ageing. Accordingly, the relationship between δ 44/40Ca and wine quality may originate during grape ripening in the vineyard or during winemaking in the cellar. We tested the grape ripening hypothesis using Merlot grapes sampled from a vineyard in the Okanagan, British Columbia, using sugar content (degrees Brix) as an indicator of ripeness. The grapes were separated into pulp, skin, and pip fractions and were analyzed separately. Thus far, there is no clear evidence for a systematic change in δ 44/40Ca values associated with progressive ripening of grapes in the vineyard. On the day of harvesting, the δ 44/40Ca value of juice squeezed from

  4. Isotope Geochronology: Technique and Application%同位素地质年龄测定技术及应用

    Institute of Scientific and Technical Information of China (English)

    陈文; 万渝生; 李华芹; 张宗清; 戴檀谟; 施泽恩; 孙敬博


    了困扰,有时不能给出正确可信的年龄.⑤Re-Os法:是目前能够直接测定金属矿床矿化年龄的唯一成熟方法.但在实验技术和应用方面还存在不少问题:a.近年来发现有些金属矿床辉钼矿的Re-Os年龄高于其赋矿围岩的年龄,原因不明;b.黄铁矿等多数硫化物矿物含Re量很低,并含有一定程度的普通Os,对样品化学制备过程中低本底的要求很高,一般实验室难以达到,普通Os也难以准确扣除;c.后期的热液活动有时可以使Os同位素发生重置,因此,金属硫化物Re-Os同位素体系封闭温度及其影响因素是一个亟待解决的问题.⑥(U-Th)/He法:(U-Th)/He同位素系统的优势是其封闭温度是已有同位素体系中最低的,能够记录地质体经历较低温度范围的时代与温度信息.该方法在矿床年代学研究中也具有可观应用前景.其不足之处是因为封闭温度很低,在用于地质体定年时要特别关注冷却速率和再加热作用的影响.%Isotope geochronology is a newly developed interdisciplinary science which combines geoscience, physics, chemistry and technical sciences, and is a young and energetic branch of earth science. The decay of radioactive isotopes is used to determine the formation age of geological body and the age of geological events, with aiming to study the formation history and evolution of earth and planetary materials. This paper presents brief introduction and summary of relative high-precise isotope dating methods in terms of theory, experiment techniques, application scope, precautions for use, in hope of providing a useful reference to geologist. Main isotope dating methods involved s are U-Pb, Ar-Ar, Rb-Sr, Sm-Nd, Re-Os and (U-Th)/He methods. (l)U-Pb method: It is one of the earliest radioactive methods for determination of geological age as well as the most important isotope dating method in China so far. In the past 10 years, the introduction of zircon U-Pb dating technique

  5. Petrographic, geochemical and isotopic evidence of crustal assimilation processes in the Ponte Nova alkaline mafic-ultramafic massif, SE Brazil (United States)

    Azzone, Rogério Guitarrari; Montecinos Munoz, Patricio; Enrich, Gaston Eduardo Rojas; Alves, Adriana; Ruberti, Excelso; Gomes, Celsode Barros


    be responsible for the increse in the K2O/Na2O, Ba/Sr and Rb/Sr ratios. This enrichment was associated with the relevant role of biotite breakdown in the assimilated host rock partial melts. The petrological model for the Ponte Nova massif is explained as repeated influxes of antecryst-laden basanite magmas that deposited most of their suspended crystals on the floor of the upper-crust magma chamber. Each intrusion is representative of relatively primitive olivine- and clinopyroxene-phyric basanites that had assimilated different degrees of partial melts of heterogeneous host rocks. This study reveals the relevant role of crustal assimilation processes in the magmatic evolution of nepheline-normative rocks, especially in upper-crust chamber environments.

  6. Geology of Precambrian rocks and isotope geochemistry of shear zones in the Big Narrows area, northern Front Range, Colorado (United States)

    Abbott, Jeffrey T.


    Rocks within the Big Narrows and Poudre Park quadrangles located in the northern Front Range of Colorado are Precambrian metasedimentary and metaigneous schists and gneisses and plutonic igneous rocks. These are locally mantled by extensive late Tertiary and Quaternary fluvial gravels. The southern boundary of the Log Cabin batholith lies within the area studied. A detailed chronology of polyphase deformation, metamorphism and plutonism has been established. Early isoclinal folding (F1) was followed by a major period of plastic deformation (F2), sillimanite-microcline grade regional metamorphism, migmatization and synkinematic Boulder Creek granodiorite plutonism (1.7 b.y.). Macroscopic doubly plunging antiformal and synformal structures were developed. P-T conditions at the peak of metamorphism were probably about 670?C and 4.5 Kb. Water pressures may locally have differed from load pressures. The 1.4 b.y. Silver Plume granite plutonism was post kinematic and on the basis of petrographic and field criteria can be divided into three facies. Emplacement was by forcible injection and assimilation. Microscopic and mesoscopic folds which postdate the formation of the characteristic mineral phases during the 1.7 b.y. metamorphism are correlated with the emplacement of the Silver Plume Log Cabin batholith. Extensive retrograde metamorphism was associated with this event. A major period of mylonitization postdates Silver Plume plutonism and produced large E-W and NE trending shear zones. A detailed study of the Rb/Sr isotope geochemistry of the layered mylonites demonstrated that the mylonitization and associated re- crystallization homogenized the Rb87/Sr 86 ratios. Whole-rock dating techniques applied to the layered mylonites indicate a probable age of 1.2 b.y. Petrographic studies suggest that the mylonitization-recrystallization process produced hornfels facies assemblages in the adjacent metasediments. Minor Laramide faulting, mineralization and igneous activity


    Spevack, J.S.


    An isotope concentration process is described which consists of exchanging, at two or more different temperature stages, two isotopes of an element between substances that are physically separate from each other and each of which is capable of containing either of the isotopes, and withdrawing from a point between at least two of the temperatare stages one of the substances containing an increased concentration of the desired isotope.

  8. Pre-metamorphic melt infiltration in metasediments: geochemical, isotopic (Sr, Nd, and Pb), and field evidence from Serie dei Laghi (Southern Alps, Italy) (United States)

    Pinarelli, L.; Bergomi, M. A.; Boriani, A.; Giobbi, E.


    Gradual transitions from K-feldspar free gneisses to K-feldspar bearing augengneisses are sometimes observed in metamorphic terranes. They have been explained with metasomatic porphyroblastic growth connected with regional metamorphism, or with pre-metamorphic presence of magmatic megacrysts. A transition of this kind can be observed in the Serie dei Laghi (Southern Alps, Italy), where coarse-grained meta-arenites ( Cenerigneiss) grade into Ceneri augengneisses with large K-feldspar porphyroclasts, and banded amphibolites of the “Strona Ceneri Border Zone” grade into Hbl augengneisses rich in K-feldspar. The Ceneri augengneisses are chemically indistinguishable from the Cenerigneiss, but have higher 87Sr/86Sr (0.7256 0.7258 vs. 0.7215 0.7233), similar to those of the Ordovician granites that were intruded, before the regional metamorphism, into the protoliths of both Cenerigneiss and amphibolites. The Cenerigneiss contains two types of zircons: (1) highly luminescent, rounded grains or fragments, yielding U Pb SHRIMP ages from 0.43 to 1.0 Ga; (2) euhedral grains with oscillatory zoning (magmatic), with U Pb SHRIMP concordant ages of 466 ± 13 Ma. This age coincides with the Rb Sr whole rock emplacement age of the Ordovician granitoids (466 ± 5 Ma). The Hbl augengneisses form three groups with distinct geochemical patterns, whose distributions on inter-element diagrams trend towards the Ordovician metagranites and meta-aplites. In addition, the Hbl augengneisses have higher 87Sr/86Sr (0.7132 0.7147 vs. 0.7031 0.7046) and lower 143Nd/144Nd (0.51214 0.51219 vs. 0.51273 0.51297) than the amphibolites, suggesting the addition of an isotopically evolved component. The observed chemical and isotope patterns, as well as the vicinity of the augen gneisses to the Ordovician intrusions, lead us to conclude that the Ceneri augengneisses and Hbl augengneisses are the result of infiltration of residual hydrous magmas into the protolith of both the Cenerigneiss and the

  9. Geological and isotopic evidence for magmatic-hydrothermal origin of the Ag-Pb-Zn deposits in the Lengshuikeng District, east-central China (United States)

    Wang, Changming; Zhang, Da; Wu, Ganguo; Santosh, M.; Zhang, Jing; Xu, Yigan; Zhang, Yaoyao


    The Lengshuikeng ore district in east-central China has an ore reserve of ˜43 Mt with an average grade of 204.53 g/t Ag and 4.63 % Pb + Zn. Based on contrasting geological characteristics, the mineralization in the Lengshuikeng ore district can be divided into porphyry-hosted and stratabound types. The porphyry-hosted mineralization is distributed in and around the Lengshuikeng granite porphyry and shows a distinct alteration zoning including minor chloritization and sericitization in the proximal zone; sericitization, silicification, and carbonatization in the peripheral zone; and sericitization and carbonatization in the distal zone. The stratabound mineralization occurs in volcano-sedimentary rocks at ˜100-400 m depth without obvious zoning of alterations and ore minerals. Porphyry-hosted and stratabound mineralization are both characterized by early-stage pyrite-chalcopyrite-sphalerite, middle-stage acanthite-native silver-galena-sphalerite, and late-stage pyrite-quartz-calcite. The δ34S values of pyrite, sphalerite, and galena in the ores range from -3.8 to +6.9‰ with an average of +2.0‰. The C-O isotope values of siderite, calcite, and dolomite range from -7.2 to -1.5‰ with an average of -4.4‰ (V-PDB) and from +10.9 to +19.5‰ with an average of +14.8‰ (V-SMOW), respectively. Hydrogen, oxygen, and carbon isotopes indicate that the hydrothermal fluids were derived mainly from meteoric water, with addition of minor amounts of magmatic water. Geochronology employing LA-ICP-MS analyses of zircons from a quartz syenite porphyry yielded a weighted mean 206Pb/238U age of 136.3 ± 0.8 Ma considered as the emplacement age of the porphyry. Rb-Sr dating of sphalerite from the main ore stage yielded an age of 126.9 ± 7.1 Ma, marking the time of mineralization. The Lengshuikeng mineralization classifies as an epithermal Ag-Pb-Zn deposit.

  10. Statistical clumped isotope signatures

    NARCIS (Netherlands)

    Röckmann, T.; Popa, M. E.; Krol, M. C.; Hofmann, M. E. G.


    High precision measurements of molecules containing more than one heavy isotope may provide novel constraints on element cycles in nature. These so-called clumped isotope signatures are reported relative to the random (stochastic) distribution of heavy isotopes over all available isotopocules of a m

  11. Systematic of dipole excitations in the stable sup 1 sup 3 sup 4 sup , sup 1 sup 3 sup 5 sup , sup 1 sup 3 sup 6 sup , sup 1 sup 3 sup 7 sup , sup 1 sup 3 sup 8 Ba isotopes

    CERN Document Server

    Scheck, M; Brentano, P V


    In this contribution the focus is on the systematic study of [2 sup + x3 sup -] sub 1 -two-phonon excitations around the Z = 50 and N = 82 shell closures. The results for the Sn and Ba isotope chains will be shown in a general framework of all available data obtained by nuclear resonance fluorescence experiments. The photon scattering experiments referred to in this work were performed at the Bremsstrahlung facility of the 4.3 MV Stuttgart Dynamitron accelerator. NRF experiments are suitable for the determination of excitation energies, spins, lifetimes and transition strengths of low-spin states. The even-even isotopes show strong 1 sup - excitations close to the sum energy of the 2 sup + and 3 sup - phonons, interpreted as [2 sup + x3 sup -] sub 1 -two phonon excitations. The behaviour of these [2 sup + x 3 sup -] sub 1 -states in even-even nuclei can be explained by the so-called DCP effect. Furthermore, the coupling of a single nucleon to this collective excitation in the neighbouring odd-mass nuclei is i...

  12. The influence of intruder states in even-even Po isotopes

    Energy Technology Data Exchange (ETDEWEB)

    García-Ramos, J. E., E-mail: [Departamento de Física Aplicada, Universidad de Huelva, 21071 Huelva (Spain); Heyde, K., E-mail: [Department of Physics and Astronomy, Ghent University, Proeftuinstraat 86, B-9000 Gent (Belgium)


    We study the role of intruder states and shape coexistence in the even-even {sup 190–206}Po isotopes, through an interacting boson model with configuration mixing calculation. We analyzed the results in the light of known systematics on various observable in the Pb region, paying special attention to the unperturbed energy systematics and quadrupole deformation. We find that shape coexistence in the Po isotopes behaves in very much the same way as in the Pt isotopes, i.e., it is somehow hidden, contrary to the situation in the Pb and the Hg isotopes.

  13. Generation of Radixenon Isotopes

    Energy Technology Data Exchange (ETDEWEB)

    McIntyre, Justin I.; Bowyer, Ted W.; Hayes, James C.; Heimbigner, Tom R.; Morris, Scott J.; Panisko, Mark E.; Pitts, W. K.; Pratt, Sharon L.; Reeder, Paul L.; Thomas, Charles W.


    Pacific Northwest National Laboratory has developed an automated system for separating Xe from air and can detect the following radioxenon isotopes, 131mXe, 133mXe, 133Xe, and 135Xe. This report details the techniques used to generate the various radioxenon isotopes that are used for the calibration of the detector as well as other isotopes that have the potential to interfere with the fission produced radioxenon isotopes. Fission production is covered first using highly enriched uranium followed by a description and results from an experiment to produce radioxenon isotopes from neutron activation of ambient xenon.

  14. Isotopes in heterogeneous catalysis

    CERN Document Server

    Hargreaves, Justin SJ


    The purpose of this book is to review the current, state-of-the-art application of isotopic methods to the field of heterogeneous catalysis. Isotopic studies are arguably the ultimate technique in in situ methods for heterogeneous catalysis. In this review volume, chapters have been contributed by experts in the field and the coverage includes both the application of specific isotopes - Deuterium, Tritium, Carbon-14, Sulfur-35 and Oxygen-18 - as well as isotopic techniques - determination of surface mobility, steady state transient isotope kinetic analysis, and positron emission profiling.

  15. Sourcing explosives: a multi-isotope approach. (United States)

    Widory, David; Minet, Jean-Jacques; Barbe-Leborgne, Martine


    Although explosives are easily identified with current instrumental techniques, it is generally impossible to distinguish between sources of the same substance. To alleviate this difficulty, we present a multi-stable isotope (delta13C, delta15N, delta18O, deltaD) approach for appraising the possibility of discriminating explosives. The results from 30 distinct PETN, TNT and ANFO samples show that the different families of explosives are clearly differentiated by both their specific isotope signatures and their combination with corresponding element concentrations. Coupling two or more of the studied isotope systematics yields an even more precise differentiation on the basis of their raw-material origin and/or manufacturing process.

  16. Stable water isotope patterns in a climate change hotspot: the isotope hydrology framework of Corsica (western Mediterranean). (United States)

    van Geldern, Robert; Kuhlemann, Joachim; Schiebel, Ralf; Taubald, Heinrich; Barth, Johannes A C


    The Mediterranean is regarded as a region of intense climate change. To better understand future climate change, this area has been the target of several palaeoclimate studies which also studied stable isotope proxies that are directly linked to the stable isotope composition of water, such as tree rings, tooth enamel or speleothems. For such work, it is also essential to establish an isotope hydrology framework of the region of interest. Surface waters from streams and lakes as well as groundwater from springs on the island of Corsica were sampled between 2003 and 2009 for their oxygen and hydrogen isotope compositions. Isotope values from lake waters were enriched in heavier isotopes and define a local evaporation line (LEL). On the other hand, stream and spring waters reflect the isotope composition of local precipitation in the catchment. The intersection of the LEL and the linear fit of the spring and stream waters reflect the mean isotope composition of the annual precipitation (δP) with values of-8.6(± 0.2) ‰ for δ(18)O and-58(± 2) ‰ for δ(2)H. This value is also a good indicator of the average isotope composition of the local groundwater in the island. Surface water samples reflect the altitude isotope effect with a value of-0.17(± 0.02) ‰ per 100 m elevation for oxygen isotopes. At Vizzavona Pass in central Corsica, water samples from two catchments within a lateral distance of only a few hundred metres showed unexpected but systematic differences in their stable isotope composition. At this specific location, the direction of exposure seems to be an important factor. The differences were likely caused by isotopic enrichment during recharge in warm weather conditions in south-exposed valley flanks compared to the opposite, north-exposed valley flanks.

  17. A preliminary bioavailable strontium isotope soil map of Europe. (United States)

    Hoogewerff, Jurian; Reimann, Clemens; Ueckermann, Henriette; Frei, Robert; Frei, Karin; van Aswegen, Thalita; Stirling, Claudine; Reid, Malcolm; Clayton, Aaron; Gemas Project Team


    (XRF) element (R=0.33), which initially might hint at the influence of seaspray as it is often hypothesized that seaspray is a major source of 87Sr/86Sr variation in coastal regions. To test this hypothesis the distances to the coast in the major north-westerly wind direction in Europe and the shortest distance to any coast were calculated. Neither distance measure provided any significant correlation with 87Sr/86Sr values, indicating that the cause of the Na-Sr correlation is not likely to be seaspray, which would agree with poor correlation with presumably mobile Na in the Aqua Regia extracts. In concordance with observations of other authors5 modeling accuracy is improved by creating separate models for contrasting lithologies; igneous, marine limestones and other types. Igneous parent material provided the most convincing model using parameters like age, Rb/Sr ratio and 206Pb/208Pb. Attempts to model 87Sr/86Sr of soil on marine limestones with the LOWESS version 36 87Sr/86Sr vs. age curve were not convincing although some pattern similarity could be observed. Uranium and sodium content combined with pH are reasonable predictors of 87Sr/86Sr in soils on marine limestone parent material. The 87Sr/86Sr dataset with coordinates and models will be available from the main author after publication later in 2017. Reimann, C., et al., (2014). Geologisches Jahrbuch (Reihe B 102), Schweizerbarth, Hannover. Voerkelius S. et al., (2010). Food Chemistry. 118 (4), pp. 933-940. Asch, K., (2003). Geologisches Jahrbuch, SA 3, Schweizerbarth. Hannover. Hartmann, J., and N. Moosdorf (2012), Geochem. Geophys. Geosyst., 13, Q12004. Bataille, C. P. and G. J. Bowen. 2012. Chemical Geology 304-305:39- 52. J. M. McArthur, et al., Journal of Geology, 2001, volume 109, p. 155-170

  18. Fractionation of Oxygen Isotopes by Thermal Ionization Mass Spectrometry Inferred from Simultaneous Measurement of (17)O/(16)O and (18)O/(16)O Ratios and Implications for the (182)Hf-(182)W Systematics. (United States)

    Trinquier, Anne


    Accurate (182)Hf-(182)W chronology of early planetary differentiation relies on highly precise and accurate tungsten isotope measurements. WO3(-) analysis by negative thermal ionization mass spectrometry requires W(17)O(16)O2(-), W(17)O2(16)O(-), W(18)O(16)O2(-), W(17)O3(-), W(17)O(18)O(16)O(-), and W(18)O2(16)O(-) isotopologue interference corrections on W(16)O3(-) species ( Harper et al. Geochim. Cosmochim. Acta 1996 , 60 , 1131 ; Quitté et al. Geostandard. Newslett. 2002 , 26 , 149 ; Trinquier et al. Anal. Chem. 2016 , 88 , 1542 ; Touboul et al. Nature 2015 , 520 , 530 ; Touboul et al. Int. J. Mass Spectrom. 2012 , 309 , 109 ). In addition, low ion beam intensity counting statistics combined with Faraday cup detection noise limit the precision on the determination of (18)O/(16)O and (17)O/(16)O relative abundances. Mass dependent variability of (18)O/(16)O over the course of an analysis and between different analyses calls for oxide interference correction on a per integration basis, based on the in-run monitoring of the (18)O/(16)O ratio ( Harper et al. Geochim. Cosmochim. Acta 1996 , 60 , 1131 ; Quitté et al. Geostandard. Newslett. 2002 , 26 , 149 ; Trinquier et al. Anal. Chem. 2016 , 88 , 1542 ). Yet, the (17)O/(16)O variation is normally not being monitored and, instead, inferred from the measured (18)O/(16)O variation, assuming a δ(17)O-δ(18)O Terrestrial Fractionation Line ( Trinquier et al. Anal. Chem. 2016 , 88 , 1542 ). The purpose of the present study is to verify the validity of this assumption. Using high resistivity amplifiers, (238)U(17)O2 and (238)U(18)O2 ion beams down to 1.6 fA have been monitored simultaneously with (235,238)U(16)O2 species in a uranium certified reference material. This leads to a characterization of O isotope fractionation by thermal ionization mass spectrometry in variable loading and running conditions (additive-to-sample ratio, PO2 pressure, presence of ionized metal and oxide species). Proper determination of O

  19. Systematic decay studies of even-even {sup 132-138}Nd, {sup 144-158}Gd, {sup 176-196}Hg and {sup 192-198}Pb isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Santhosh, K.P., E-mail: [School of Pure and Applied Physics, Kannur University, Payyanur Campus, Payyanur 670 327 (India); Sahadevan, Sabina [School of Pure and Applied Physics, Kannur University, Payyanur Campus, Payyanur 670 327 (India)


    The alpha and cluster decay properties of the {sup 132-138}Nd, {sup 144-158}Gd, {sup 176-196}Hg and {sup 192-198}Pb even-even isotopes in the two mass regions A=130-158 and A=180-198 are analyzed using the Coulomb and Proximity Potential Model. On examining the clusters at corresponding points in the cold valleys (points with same A{sub 2}) of the various isotopes of a particular nucleus we find that at certain mass numbers of the parent nuclei, the clusters emitted are getting shifted to the next lower atomic number. It is interesting to see that the change in clusters appears at those isotopes where a change in shape is occurring correspondingly. Such a change of clusters with shape change is studied for the first time in cluster decay. The alpha decay half lives of these nuclei are computed and these are compared with the available experimental alpha decay data. It is seen that the two are in good agreement. On making a comparison of the alpha half lives of the normal deformed and superdeformed nuclei, it can be seen that the normal deformed {sup 132}Nd, {sup 176-188}Hg and {sup 192}Pb nuclei are found to be better alpha emitters than the superdeformed (in excited state) {sup 134,136}Nd, {sup 190-196}Hg and {sup 194}Pb nuclei. The cluster decay studies reveal that as the atomic number of the parent nuclei increases the N{ne}Z cluster emissions become equally or more probable than the N=Z emissions. On the whole the alpha and cluster emissions are more probable from the parents in the heavier mass region (A=180-198) than from the parents in the lighter mass region (A=130-158). The effect of quadrupole ({beta}{sub 2}) and hexadecapole ({beta}{sub 4}) deformations of parent and fragments on half life times are also studied.

  20. Modelling of stable water isotopes in Central Europe with COSMOiso (United States)

    Christner, Emanuel; Pfahl, Stephan; Schädler, Gerd


    Atmospheric water in form of vapor or clouds is responsible for ˜75 % of the natural greenhouse effect and carries huge amounts of latent heat. For this reason, a best possible description of the hydrological cycle is a prerequisite for reliable climate modelling. As the stable isotopes H216O, H218O and HDO differ in vapor pressure, they are fractionated during phase changes and contain information about the formation of precipitation, evaporation from the ground, etc. Therefore, the isotopic composition of atmospheric water is an useful tracer to test and improve our understanding of the extremely complex and variable hydrological cycle in Earth's atmosphere. Within the project PalMod the isotope-enabled limited-area model COSMOiso will be used for high-resolution isotope simulations of paleo-climates. For validation with modern observations we compare 12 years of modelled isotope ratios from Central Europe to observations of the Global Network of Isotopes in Precipitation (GNIP) and to observations of isotope ratios of water vapor at different locations in Germany. We find a good agreement of modelled and observed isotope ratios in summer. In winter, we observe a systematic overestimation of modelled isotope ratios in precipitation and low-level water vapor. We relate those differences to specific circulation regimes with predominantly easterly moisture transport and the corresponding strong dependence of modelled isotope ratios on lateral boundary data. Furthermore, we investigate the dependence of modelled isotope ratios in winter on the type of isotope fractionation during surface evaporation at skin temperatures close to the freezing point.

  1. Tracing source pollution in soils using cadmium and lead isotopes. (United States)

    Cloquet, C; Carignan, J; Libourel, G; Sterckeman, T; Perdrix, E


    Tracing the source of heavy metals in the environment is of key importance for our understanding of their pollution and natural cycles in the surface Earth reservoirs. Up to now, most exclusively Pb isotopes were used to effectively trace metal pollution sources in the environment. Here we report systematic variations of Cd isotope ratios measured in polluted topsoils surrounding a Pb-Zn refinery plant in northern France. Fractionated Cd was measured in soil samples surrounding the refinery, and this fractionation can be attributed to the refining processes. Despite the Cd isotopic ratios being precisely measured, the obtained uncertainties are still large compared to the total isotopic variation. Nevertheless, for the first time, Cd isotopically fractionated by industrial processes may be traced in the environment. On the same samples, Pb isotope systematics suggested that materials actually used by the refinery were not the major source of Pb in soils, probably because refined ore origins changed over the 100 years of operation. On the other hand, Cd isotopes and concentrations measured in topsoils allowed identification of three main origins (industrial dust and slag and agriculture), assuming that all Cd ores are not fractionated, as suggested by terrestrial rocks so far analyzed, and calculation of their relative contributions for each sampling point. Understanding that this refinery context was an ideal situation for such a study, our results lead to the possibility of tracing sources of anthropogenic Cd and better constrain mixing processes, fluxes, transport, and phasing out of industrial input in nature.

  2. Melt evolution beneath a rifted craton edge: 40Ar/39Ar geochronology and Sr-Nd-Hf-Pb isotope systematics of primitive alkaline basalts and lamprophyres from the SW Baltic Shield (United States)

    Tappe, Sebastian; Smart, Katie A.; Stracke, Andreas; Romer, Rolf L.; Prelević, Dejan; van den Bogaard, Paul


    A new high-precision 40Ar/39Ar anorthoclase feldspar age of 176.7 ± 0.5 Ma (2-sigma) reveals that small-volume alkaline basaltic magmatism occurred at the rifted SW margin of the Baltic Shield in Scania (southern Sweden), at a time of global plate reorganization associated with the inception of Pangea supercontinent break-up. Our combined elemental and Sr-Nd-Hf-Pb isotope dataset for representative basanite and nephelinite samples (>8 wt.% MgO) from 16 subvolcanic necks of the 30 by 40 km large Jurassic volcanic field suggests magma derivation from a moderately depleted mantle source (87Sr/86Sri = 0.7034-0.7048; εNdi = +4.4 to +5.2; εHfi = +4.7 to +8.1; 206Pb/204Pbi = 18.8-19.5). The mafic alkaline melts segregated from mixed peridotite-pyroxenite mantle with a potential temperature of ∼1400 °C at 2.7-4.2 GPa (∼90-120 km depths), which places ultimate melt generation within the convecting upper mantle, provided that the lithosphere-asthenosphere boundary beneath the southern Baltic Shield margin was at ⩽100 km depth during Mesozoic-Cenozoic rifting. Isotopic shifts and incompatible element enrichment relative to Depleted Mantle reflect involvement of at least 20% recycled oceanic lithosphere component (i.e., pyroxenite) with some minor continent-derived sediment during partial melting of well-stirred convecting upper mantle peridotite. Although pargasitic amphibole-rich metasomatized lithospheric mantle is excluded as the main source of the Jurassic magmas from Scania, hydrous ultramafic veins (i.e., hornblendite) may have caused subtle modifications to the compositions of passing sublithospheric melts. For example, modeling suggests that the more radiogenic Hf (εHfi = +6.3 to +8.1) and Pb (206Pb/204Pbi = 18.9-19.5) isotopic compositions of the more sodic and H2O-rich nephelinites, compared with relatively homogenous basanites (εHfi = +4.7 to +6.1; 206Pb/204Pbi = 18.8-18.9), originate from minor interactions between rising asthenospheric melts and

  3. Sr-Isotope Composition of Feldspar: Implication for age and Evolution of Gabbros from Uralian-Alaskan Type Complexes in the Ural Mountains, Russia (United States)

    Bruegmann, G. E.; Krause, J.; Pushkarev, E.


    concentrations (>3000 ppm) than silica undersaturated gabbros (Plag: 800-1000 ppm). These features imply the gabbros are derived from distinct parental magmas. However, no significant differences in Sr isotopic composition could be deciphered. Silica saturated gabbros from different parts of the Kytlym complex have similar 87Sr/86Sr of 0.70406±8 (2SD) and pseudoleucite-bearing rocks have 87Sr/86Sr of 0.70408±5. Interestingly, the Sr isotopic composition of the gabbros from Kytlym and Nizhnii Tagil is also similar. Thus despite their spatial separation and very different magmatic lineage the parental magmas appear to sample a homogenous mantle source. K-Feldspar in the pseudoleucite-bearing gabbros has high 87SRb/86Sr (0.2-0.4) and high 87Sr/86Sr (0.7050-0.7059) due to radiogenic ingrowth. Using the plagioclase and K-feldspar analyses of one polished section and correcting the 87Rb/86Sr for the different analytical sensitivities of Sr and Rb, the data define an isochron giving an age of 348±23 Ma and initial isotopic composition of 0.70406±4 (MSWD=1.14). This result is in very good agreement with Rb-Sr whole rock data of Pushkarev et al. (2003) studying the same rocks at the Kytlym complex.

  4. Discovery of the Cobalt Isotopes


    Szymanski, T.; Thoennessen, M.


    Twenty-six cobalt isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  5. Discovery of the Arsenic Isotopes

    CERN Document Server

    Shore, A; Heim, M; Schuh, A; Thoennessen, M


    Twenty-nine arsenic isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  6. Intracellular Cadmium Isotope Fractionation (United States)

    Horner, T. J.; Lee, R. B.; Henderson, G. M.; Rickaby, R. E.


    Recent stable isotope studies into the biological utilization of transition metals (e.g. Cu, Fe, Zn, Cd) suggest several stepwise cellular processes can fractionate isotopes in both culture and nature. However, the determination of fractionation factors is often unsatisfactory, as significant variability can exist - even between different organisms with the same cellular functions. Thus, it has not been possible to adequately understand the source and mechanisms of metal isotopic fractionation. In order to address this problem, we investigated the biological fractionation of Cd isotopes within genetically-modified bacteria (E. coli). There is currently only one known biological use or requirement of Cd, a Cd/Zn carbonic anhydrase (CdCA, from the marine diatom T. weissfloggii), which we introduce into the E. coli genome. We have also developed a cleaning procedure that allows for the treating of bacteria so as to study the isotopic composition of different cellular components. We find that whole cells always exhibit a preference for uptake of the lighter isotopes of Cd. Notably, whole cells appear to have a similar Cd isotopic composition regardless of the expression of CdCA within the E. coli. However, isotopic fractionation can occur within the genetically modified E. coli during Cd use, such that Cd bound in CdCA can display a distinct isotopic composition compared to the cell as a whole. Thus, the externally observed fractionation is independent of the internal uses of Cd, with the largest Cd isotope fractionation occurring during cross-membrane transport. A general implication of these experiments is that trace metal isotopic fractionation most likely reflects metal transport into biological cells (either actively or passively), rather than relating to expression of specific physiological function and genetic expression of different metalloenzymes.

  7. Impact of mineral fertility and bedrock erosion on single-mineral detrital studies: insights from trace-element and Nd-isotope systematics of detrital apatite from the Po River catchment (United States)

    Malusa', Marco Giovanni; Wang, Jiangang; Garzanti, Eduardo; Villa, Igor M.; Wittman, Hella


    The detrital record provides an archive of mountain erosion that preserves key information for paleotectonic and paleoclimatic reconstructions. Detrital studies are often based on single-mineral analyses (e.g., geo/thermochronologic analyses on apatite and zircon). Their geologic interpretation can be challenging, because the impact of each eroding source on the detrital record is controlled by a range of factors including the rate of erosion and the fertility of chosen minerals in eroded bedrock. Here, we combine (i) a state-of-the art dataset of trace element and Nd isotope fingerprints of detrital apatite, (ii) a comprehensive dataset of apatite-fertility measurements (Malusà et al. 2016), (iii) fission-track data, and (iv) cosmogenic-derived erosion rates from the Po River catchment (Wittmann et al. 2016), to test the impact of mineral fertility and bedrock erosion on the single-mineral detrital signal preserved in the final sediment sink. Our results show that the information provided by accessory minerals, when complemented with accurate mineral fertility measurements, are fully consistent with information provided by the analysis of more abundant framework minerals. We found that trace element and Nd isotope analyses provide a reliable tool to disentangle the complex single-mineral record of orogenic erosion, and demonstrate that such a record is largely determined by high-fertility source rocks exposed within the drainage. Detrital thermochronology studies based on the lag-time approach should thus preferably include independent provenance discriminations and a full mineral fertility characterization of the potential source areas, in order to ensure a correct identification of the sediment sources and of the exogenic and endogenic processes monitored in the stratigraphic archive. Malusà M.G., Resentini A., Garzanti E., 2016. Hydraulic sorting and mineral fertility bias in detrital geochronology. Gondwana Res., 31, 1-19 Wittmann H., Malusà M.G., Resentini

  8. Mass-dependent fractionation of nickel isotopes in meteoritic metal (United States)

    Cook, David L.; Wadhwa, Meenakshi; Clayton, Robert N.; Dauphas, Nicolas; Janney, Philip E.; Davis, Andrew M.

    We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC-ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non-magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ≈0.4‰ amu-1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (≈0.0 to ≈0.3‰ amu-1) and chondrites (≈0.0 to ≈0.2‰ amu-1) are similar, whereas the range in pallasite metal (≈-0.1 to 0.0‰ amu-1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (≈0.0 to ≈0.3‰ amu-1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ≈0.4‰ amu-1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe-Ni alloy and the development of the Widmanstätten pattern.

  9. $^{110,116}$Cd($\\alpha,\\alpha$)$^{110,116}$Cd elastic scattering and systematic investigation of elastic $\\alpha$ scattering cross sections along the $Z$ = 48 isotopic and $N$ = 62 isotonic chains

    CERN Document Server

    Kiss, G G; Fülöp, Zs; Gyürky, Gy; Elekes, Z; Farkas, J; Somorjai, E; Yalcin, C; Galaviz, D; Güray, R T; Özkan, N; Görres, J


    The elastic scattering cross sections for the reactions $^{110,116}$Cd($\\alpha,\\alpha$)$^{110,116}$Cd at energies above and below the Coulomb barrier are presented to provide a sensitive test for the alpha-nucleus optical potential parameter sets. Additional constraints for the optical potential are taken from the analysis of elastic scattering excitation functions at backward angles which are available in literature. Moreover, the variation of the elastic alpha scattering cross sections along the $Z = 48$ isotopic and $N = 62$ isotonic chain is investigated by the study of the ratios of the of $^{106,110,116}$Cd($\\alpha,\\alpha$)$^{106,110,116}$Cd scattering cross sections at E$_{c.m.} \\approx$ 15.6 and 18.8 MeV and the ratio of the $^{110}$Cd($\\alpha,\\alpha$)$^{110}$Cd and $^{112}$Sn($\\alpha,\\alpha$)$^{112}$Sn reaction cross sections at E$_{c.m.} \\approx$ 18.8 MeV, respectively. These ratios are sensitive probes for the alpha-nucleus optical potential parameterizations. The potentials under study are a basic...

  10. Chromium isotope variations

    DEFF Research Database (Denmark)

    D'Arcy, Joan Mary

    is incorporated into carbonates. Hence, ancient carbonates can potentially record the Cr isotopic composition (δ53Cr ‰) of seawater in the geological past. Reliable application and interpretation of this proxy requires a detailed knowledge about processes that fractionate Cr on the Earth’s surface...... deposited during the Early Ordovician — a time of known redox instability in ancient oceans – exhibit a significant positive Cr isotope excursion of +0.5‰. This excursion is interpreted as the reductive drawn down of dissolved Cr in seawater in response to the development of a proximal anoxic sink......, and the quantification the Cr isotope composition of major Cr fluxes into and out of ocean. This thesis adds to the current knowledge of the Cr isotope system and is divided into two studies. The focus of the first study was to determine what processes control the Cr isotopic compositionof river water and to quantify...

  11. Isotopes in Greenland Precipitation

    DEFF Research Database (Denmark)

    Faber, Anne-Katrine

    Greenland ice cores offer a unique opportunity to investigate the climate system behaviour. The objective of this PhD project is to investigate isotope modelling of present- day conditions and conduct model-data comparison using Greenland ice cores. Thus this thesis investigates how the integration...... of model and data can be used to improve the understanding of climate changes. This is done through analysis of isotope modelling, observations and ice core measurements. This dissertation comprises three projects: (1) Modelling the isotopic response to changes in Arctic sea surface conditions, (2......) Constructing a new Greenland database of observations and present-day ice core measurements, and (3) Performance test of isotope-enabled CAM5 for Greenland. The recent decades of rapid Arctic sea ice decline are used as a basis for an observational-based model experiment using the isotope-enabled CAM model 3...

  12. Systematic review

    DEFF Research Database (Denmark)

    Enggaard, Helle


    Title: Systematic review a method to promote nursing students skills in Evidence Based Practice Background: Department of nursing educate students to practice Evidence Based Practice (EBP), where clinical decisions is based on the best available evidence, patient preference, clinical experience...... with systematic review is used to develop didactic practice end evidence based teaching in different part of the education. Findings: The poster will present how teacher’s training and experiences with systematic review contribute to the nursing education in relation to didactic, research methodology and patient...... sources of evidence influence EBP. Furthermore teachers skills in systematic review will be used to develop systematic reviews on topics in the education where there aren’t any in order to promote Evidence Based Teaching....

  13. Resetting of Mg isotopes between calcite and dolomite during burial metamorphism: Outlook of Mg isotopes as geothermometer and seawater proxy (United States)

    Hu, Zhongya; Hu, Wenxuan; Wang, Xiaomin; Lu, Yizhou; Wang, Lichao; Liao, Zhiwei; Li, Weiqiang


    Magnesium isotopes are an emerging tool to study the geological processes recorded in carbonates. Calcite, due to its ubiquitous occurrence and the large Mg isotope fractionation associated with the mineral, has attracted great interests in applications of Mg isotope geochemistry. However, the fidelity of Mg isotopes in geological records of carbonate minerals (e.g., calcite and dolomite) against burial metamorphism remains poorly constrained. Here we report our investigation on the Mg isotope systematics of a dolomitized Middle Triassic Geshan carbonate section in eastern China. Magnesium isotope analysis was complemented by analyses of Sr-C-O isotopic compositions, major and trace element concentrations, and petrographic and mineralogical features. Multiple lines of evidence consistently indicated that post-depositional diagenesis of carbonate minerals occurred to the carbonate rocks. Magnesium isotope compositions of the carbonate rocks closely follow a mixing trend between a high δ26Mg dolomite end member and a low δ26Mg calcite end member, irrespective of sample positions in the section and calcite/dolomite ratio in the samples. By fitting the measured Mg isotope data using a two-end member mixing model, an inter-mineral Δ26Mgdolomite-calcite fractionation of 0.72‰ was obtained. Based on the experimentally derived Mg isotope fractionation factors for dolomite and calcite, a temperature of 150-190 °C was calculated to correspond to the 0.72‰ Δ26Mgdolomite-calcite fractionation. Such temperature range matches with the burial-thermal history of the local strata, making a successful case of Mg isotope geothermometry. Our results indicate that both calcite and dolomite had been re-equilibrated during burial metamorphism, and based on isotope mass balance of Mg, the system was buffered by dolomite in the section. Therefore, burial metamorphism may reset Mg isotope signature of calcite, and Mg isotope compositions in calcite should be dealt with caution in

  14. Hydrogen isotope systematics in C3 and C4 saltmarsh plants: the importance of biochemical processes in controlling interspecies variation in n-alkane 2H/1H composition (United States)

    Eley, Y.; Pedentchouk, N.


    Palaeohydrological studies have increasingly utilised the 2H/1H composition of leaf wax n-alkyl lipids to extract information from the geological record. Interpretation of the sedimentary biomarker δ2H signal, however, requires detailed understanding of the mechanisms controlling hydrogen isotope fractionation between source water and n-alkyl lipids (ɛl/w). The existence of large ranges in published n-alkyl δ2H and ɛl/w among modern plant species growing at a single location suggests that the lipid signal incorporated into the sedimentary record could be sensitive to relatively small-scale changes in vegetation assemblages. The mechanisms responsible for these interspecies differences are currently poorly constrained. Previous research has had limited success explaining n-alkyl δ2H by reference to physical processes controlling the movement of water inside/outside and within the leaf, while the relative importance of biochemical processes remains largely unexplored. This project aims to identify the mechanisms controlling interspecies variation in n-alkane 2H/1H among a range of C3 and C4 plants from a Norfolk saltmarsh in the UK. To distinguish between environmental, physical and biochemical controls, we conducted 2H/1H analysis of soil, xylem, and leaf waters and n-alkanes (i) across multiple sampling sites within the marsh, (ii) throughout the 2012 growth season, and (iii) at different times of the day. We also measured the 2H/1H of chloroplast phytol in 7 samples collected at the end of 2012. Leaf wax n-alkane δ2H varied among the sampled species by over 100‰ throughout the 2012 growth season. Environmental processes that could influence control source water 2H/1H did not fully account for this interspecies variation - soil water 2H/1H varied by only 35‰ with marsh sub-environment and exhibited site-specific seasonal shifts by no more than 31‰. Maximum interspecies variation in xylem water was 38‰, while leaf waters differed by only 29‰. We

  15. Shape of Te isotopes in mean-field formalism

    Indian Academy of Sciences (India)

    T Bayram; A H Yilmaz


    The systematic investigation of ground-state shape evolution from -unstable (6) to spherical (5) for even−even 112-134Te has been presented by using the quadrupole momentconstrained Hartree–Fock–Bogoliubov (HFB) method. By examining potential energy curves of Te isotopes, it has been suggested that 124Te nucleus may hold (5) symmetry.

  16. Measurement system analysis (MSA) of the isotopic ratio for uranium isotope enrichment process control

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros, Josue C. de; Barbosa, Rodrigo A.; Carnaval, Joao Paulo R., E-mail:, E-mail:, E-mail: [Industrias Nucleares do Brasil (INB), Rezende, RJ (Brazil)


    Currently, one of the stages in nuclear fuel cycle development is the process of uranium isotope enrichment, which will provide the amount of low enriched uranium for the nuclear fuel production to supply 100% Angra 1 and 20% Angra 2 demands. Determination of isotopic ration n({sup 235}U)/n({sup 238}U) in uranium hexafluoride (UF{sub 6} - used as process gas) is essential in order to control of enrichment process of isotopic separation by gaseous centrifugation cascades. The uranium hexafluoride process is performed by gas continuous feeding in separation unit which uses the centrifuge force principle, establishing a density gradient in a gas containing components of different molecular weights. The elemental separation effect occurs in a single ultracentrifuge that results in a partial separation of the feed in two fractions: an enriched on (product) and another depleted (waste) in the desired isotope ({sup 235}UF{sub 6}). Industrias Nucleares do Brasil (INB) has used quadrupole mass spectrometry (QMS) by electron impact (EI) to perform isotopic ratio n({sup 235}U)/n({sup 238}U) analysis in the process. The decision of adjustments and change te input variables are based on the results presented in these analysis. A study of stability, bias and linearity determination has been performed in order to evaluate the applied method, variations and systematic errors in the measurement system. The software used to analyze the techniques above was the Minitab 15. (author)

  17. Major element composition of an Early Enriched Reservoir: constraints from 142Nd/144Nd isotope systematics in the early Earth and high-pressure melting experiments of a primitive peridotite (United States)

    Kondo, Nozomi; Yoshino, Takashi; Matsukage, Kyoko N.; Kogiso, Tetsu


    The Accessible Silicate Earth (ASE) has a higher 142Nd/144Nd ratio than most chondrites. Thus, if the Earth is assumed to have formed from these chondrites, a complement low-142Nd/144Nd reservoir is needed. Such a low-142Nd/144Nd reservoir is believed to have been derived from a melt in the early Earth and is called the Early Enriched Reservoir (EER). Although the major element composition of the EER is crucial for estimating its chemical and physical properties (e.g., density) and is also essential for understanding the origin and fate of the EER, which are both major factors that determine the present composition of the Earth, it has not yet been robustly established. In order to determine the major element composition of the EER, we estimated the age and pressure-temperature conditions to form the EER that would best explain its Nd isotopic characteristics, based on Sm-Nd partitioning and its dependence on pressure, temperature, and melting phase relations. Our estimate indicates that the EER formed within 33.5 Myr of Solar System formation and at near-solidus temperatures and shallow upper-mantle pressures. We then performed high-pressure melting experiments on primitive peridotite to determine the major element composition of the EER at estimated temperature at 7 GPa and calculated the density of the EER. The result of our experiments indicates that the near-solidus melt is iron-rich komatiite. The estimated density of the near-solidus melt is lower than that of the primitive peridotite, suggesting that the EER melt would have ascended in the mantle to form an early crust. Given that high mantle potential temperatures are assumed to have existed in the Hadean, it follows that the EER melt was generated at high pressure and, therefore, its composition would have been picritic to komatiitic. As the formation age of the EER estimated in our study precedes the last giant, lunar-forming impact, the picritic to komatiitic crust (EER) would most likely have been

  18. Stable isotopic signature of Australian monsoon controlled by regional convection (United States)

    Zwart, C.; Munksgaard, N. C.; Kurita, N.; Bird, M. I.


    The aim of this study was to identify the main meteorological drivers of rainfall isotopic variation in north Australia in order to improve the interpretation of isotopic proxy records in this region. An intense monitoring program was conducted during two monsoonal events that showed significant and systematic isotopic change over time. The results showed a close link between isotopic variation in precipitation and variability in monsoon conditions, associated with the presence of large convective envelopes propagating through the study site. The largest negative amplitudes in the isotopic signal were observed when eastward and westward moving precipitation systems within the convective envelope merged over the measurement site. This suggests that the amplitude of the isotopic signal is related to the size and activity of the convective envelope. The strong correlation between rainfall isotopic variation, regional outgoing longwave radiation and regional rainfall amount supports this conclusion. This is further strengthened by the strong relationship between isotopic variation and the integrated rainfall history of air masses prior to arriving at the measurement locations. A local amount effect was not significant and these findings support the interpretation of δ18O as proxy for regional climatic conditions rather than local rainfall amount. Meteorological parameters that characterize intra-seasonal variability of monsoon conditions were also found to be strongly linked to inter-seasonal variability of the monthly based δ18O values in the Global Network of Isotopes in Precipitation (GNIP) database. This leads to the conclusion that information about the Australian monsoon variability can likely be inferred from the isotopic proxy record in North Australia on short (intra seasonal) and long (inter seasonal or longer) timescales.

  19. Isotopes in Greenland Precipitation

    DEFF Research Database (Denmark)

    Faber, Anne-Katrine

    the Arctic Ocean. A comprehensive database is created based on ice core and weather station data from Greenland within the period 1890-2014. Present day annual and seasonal mean values are computed for 326 locations in Greenland. Parameterization of the spatial distribution of temperature and δ18O are used...... of model and data can be used to improve the understanding of climate changes. This is done through analysis of isotope modelling, observations and ice core measurements. This dissertation comprises three projects: (1) Modelling the isotopic response to changes in Arctic sea surface conditions, (2......) Constructing a new Greenland database of observations and present-day ice core measurements, and (3) Performance test of isotope-enabled CAM5 for Greenland. The recent decades of rapid Arctic sea ice decline are used as a basis for an observational-based model experiment using the isotope-enabled CAM model 3...

  20. Isotope Production Facility (IPF) (United States)

    Federal Laboratory Consortium — The Los Alamos National Laboratory has produced radioactive isotopes for medicine and research since the mid 1970s, when targets were first irradiated using the 800...

  1. Calcium stable isotope geochemistry

    Energy Technology Data Exchange (ETDEWEB)

    Gausonne, Nikolaus [Muenster Univ. (Germany). Inst. fuer Mineralogie; Schmitt, Anne-Desiree [Strasbourg Univ. (France). LHyGeS/EOST; Heuser, Alexander [Bonn Univ. (Germany). Steinmann-Inst. fuer Geologie, Mineralogie und Palaeontologie; Wombacher, Frank [Koeln Univ. (Germany). Inst. fuer Geologie und Mineralogie; Dietzel, Martin [Technische Univ. Graz (Austria). Inst. fuer Angewandte Geowissenschaften; Tipper, Edward [Cambridge Univ. (United Kingdom). Dept. of Earth Sciences; Schiller, Martin [Copenhagen Univ. (Denmark). Natural History Museum of Denmark


    This book provides an overview of the fundamentals and reference values for Ca stable isotope research, as well as current analytical methodologies including detailed instructions for sample preparation and isotope analysis. As such, it introduces readers to the different fields of application, including low-temperature mineral precipitation and biomineralisation, Earth surface processes and global cycling, high-temperature processes and cosmochemistry, and lastly human studies and biomedical applications. The current state of the art in these major areas is discussed, and open questions and possible future directions are identified. In terms of its depth and coverage, the current work extends and complements the previous reviews of Ca stable isotope geochemistry, addressing the needs of graduate students and advanced researchers who want to familiarize themselves with Ca stable isotope research.

  2. Isotopically controlled semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Haller, E.E.


    A review of recent research involving isotopically controlled semiconductors is presented. Studies with isotopically enriched semiconductor structures experienced a dramatic expansion at the end of the Cold War when significant quantities of enriched isotopes of elements forming semiconductors became available for worldwide collaborations. Isotopes of an element differ in nuclear mass, may have different nuclear spins and undergo different nuclear reactions. Among the latter, the capture of thermal neutrons which can lead to neutron transmutation doping, can be considered the most important one for semiconductors. Experimental and theoretical research exploiting the differences in all the properties has been conducted and will be illustrated with selected examples. Manuel Cardona, the longtime editor-in-chief of Solid State Communications has been and continues to be one of the major contributors to this field of solid state physics and it is a great pleasure to dedicate this review to him.

  3. Isotopes through the looking glass (United States)

    Mårtensson Pendrill, Ann Marie


    Nuclear distributions affect many aspects of atomic spectra. As an example, recent experimental results for the hyperfine anomaly in Fr isotopes are considered. These depend on nuclear charge and magnetization distributions. The variations in charge radii for these isotopes were studied earlier by measuring optical isotope shifts. The hyperfine anomalies for the odd-odd isotopes involve the neutron distributions, of interest for studies of parity nonconserving effects along a chain of isotopes.

  4. Methods of isotopic geochronology (United States)

    Gorokhov, I. M.; Levchenkov, O. A.

    Papers are presented on such topics as the age of the chemical elements; the age of meteorites, the moon, and the earth; isotopic ages of the most ancient terrestrial formations; and the Archean evolution of Enderby Land in the Antarctic as evidenced by isotopic dating. Consideration is also given to a uranium-lead geochronology technique for investigating Precambrian ore deposits, a Pb-Pb technique of zircon dating, and the potentials and limitations of Sm-Nd geochronology.

  5. Oxygen Isotopes in Meteorites (United States)

    Clayton, R. N.


    Oxygen isotope abundance variations in meteorites are very useful in elucidating chemical and physical processes that occurred during the formation of the solar system (Clayton, 1993). On Earth, the mean abundances of the three stable isotopes are 16O: 99.76%, 17O: 0.039%, and 18O: 0.202%. It is conventional to express variations in abundances of the isotopes in terms of isotopic ratios, relative to an arbitrary standard, called SMOW (for standard mean ocean water), as follows:The isotopic composition of any sample can then be represented by one point on a "three-isotope plot," a graph of δ17O versus δ18O. It will be seen that such plots are invaluable in interpreting meteoritic data. Figure 1 shows schematically the effect of various processes on an initial composition at the center of the diagram. Almost all terrestrial materials lie along a "fractionation" trend; most meteoritic materials lie near a line of "16O addition" (or subtraction). (4K)Figure 1. Schematic representation of various isotopic processes shown on an oxygen three-isotope plot. Almost all terrestrial materials plot along a line of "fractionation"; most primitive meteoritic materials plot near a line of "16O addition." The three isotopes of oxygen are produced by nucleosynthesis in stars, but by different nuclear processes in different stellar environments. The principal isotope, 16O, is a primary isotope (capable of being produced from hydrogen and helium alone), formed in massive stars (>10 solar masses), and ejected by supernova explosions. The two rare isotopes are secondary nuclei (produced in stars from nuclei formed in an earlier generation of stars), with 17O coming primarily from low- and intermediate-mass stars (shielding in the UV photodissociation of CO (van Dishoeck and Black, 1988). This process results from the large differences in abundance between C16O, on the one hand, and C17O and C18O on the other. Photolysis of CO occurs by absorption of stellar UV radiation in the

  6. New petrographic, geochemical and geochronological data for the Reguengos de Monsaraz pluton (Ossa Morena Zone, SW Iberian Massif, Portugal)

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, A.; Santos, J. F.; Azevedo, M. R.; Mendez, M. H.; Ribeiro, S.


    The Reguengos de Monsaraz pluton is a late to post-tectonic Variscan intrusion occurring in the Ossa Morena Zone (Iberian Variscan Chain). The dominant lithological types are tonalites and granodiorites, but the internal area of the massif is composed of gabbro-dioritic rocks. Field evidence shows that the intrusion is heterogeneous at mesoscopic scale suggesting that the emplacement of mafic and felsic magmas was contemporaneous. Petrographic and geochemical studies reveal that the different lithologic types define a continuous sequence with compositions varying from metaluminous to slightly peraluminous and a typical calc-alkaline signature. In Harker variation diagrams, it is possible to observe systematic rectilinear correlations pointing to the involvement of magma mingling/mixing processes in the petrogenesis of this sequence. Rb-Sr isotopic data, using a mineral-mineral pair from a granodiorite sample, yielded an age of 298 Ma, interpreted as a cooling age after igneous crystallization. (Author) 13 refs.

  7. Interpretation of Ferroan Anorthosite Ages and Implications for the Lunar Magma Ocean (United States)

    Neal, C. R.; Draper, D. S.


    Ferroan Anorthosites (FANs) are considered to have purportedly crystallized directly from the lunar magma ocean (LMO) as a flotation crust. LMO modeling suggests that such anorthosites started to form only after greater than 70 percent of the LMO had crystallized. Recent age dates for FANs have questioned this hypothesis as they span too large of an age range. This means a younger age for the Moon-forming giant impact or the LMO hypothesis is flawed. However, FANs are notoriously difficult to age-date using the isochron method. We have proposed a mechanism for testing the LMO hypothesis through using plagioclase trace element abundances to calculate equilibrium liquids and compare them with LMO crystallization models. We now examine the petrography of the samples that have Sm-Nd (Samarium-Neodymium) age dates (Rb-Sr (Rubidium-Strontium) isotopic systematics may have been disturbed) and propose a relative way to age date FANs.

  8. Zircon ages, geochemistry and Nd isotopic systematics for the Palaeoproterozoic 2.3-1.8 Ga Kuilyu Complex, East Kyrgyzstan - The oldest continental basement fragment in the Tianshan orogenic belt (United States)

    Kröner, A.; Alexeiev, D. V.; Kovach, V. P.; Rojas-Agramonte, Y.; Tretyakov, A. A.; Mikolaichuk, A. V.; Xie, H.; Sobel, E. R.


    Precambrian microcontinents represent key tectonic units in the accretionary collages of the western Central Asian Orogenic Belt (CAOB), and their geological history is reasonably well established since the Mesoproterozoic but remains weakly constrained for older epochs due to a scarcity of exposed Palaeoproterozoic and Archaean rocks. Early Precambrian rocks were previously reported from several metamorphic complexes in the Kyrgyz Tianshan orogenic belt, mainly based on multigrain conventional zircon dating, but the present study only confirmed such rocks at one site, namely in the Kuilyu Complex of eastern Kyrgyzstan. New single grain SHRIMP II zircon ages, geochemical data, and whole-rock Nd isotopic compositions for granitoid gneisses of the Kuilyu Complex elucidate the age, origin and tectonic settings of this oldest continental fragment in the Tianshan. The Kuilyu Complex is part of the basement in the Ishim - Middle Tianshan microcontinent. It consist of a strongly deformed and metamorphosed supracrustal assemblage of paragneisses and schists which are tectonically interlayered with amphibolites, migmatites and granitoid gneisses. Our zircon dating indicates that the Kuilyu Complex contains two suites of Palaeoproterozoic granitoid gneisses with magmatic protolith ages of ca. 2.32-2.33 Ga and 1.85 Ga. Granitoid magmatism at 1.85 Ga was almost immediately followed by amphibolite-facies metamorphism at ca 1.83 Ga, evidenced by growth of metamorphic zircon rims. The older, ca 2.3 Ga granitoid gneisses chemically correspond to calc-alkaline, metaluminous, I-type magnesian quartz diorite and granodiorite. The protolith of the younger, ca. 1.85 Ga granite-gneiss is an alkalic-calcic, metaluminous to peraluminous, ferroan medium-grained porphyric granite with chemical features resembling A-type granites. The 2.3 Ga and 1.85 Ga granitoid gneisses have slightly to distinctly negative initial εNd values of -1.2 and -6.6, and similar depleted mantle Nd model ages of 2

  9. A Review of Mg Isotope Analytical Methods by MC-ICP-MS

    Institute of Scientific and Technical Information of China (English)

    Yajun An; Fang Huang


    Application of multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) has led to big breakthrough of analytical methods for metal stable isotopes, resulting in rapid progresses in non-traditional stable isotope geochemistry. As a new geological tracer, Mg isotopes have been widely applied in studies of almost all important disciplines of geochemistry. High precision Mg isotope data measured by MC-ICP-MS are now available with precision about 0.05‰ amu-1 (2SD) or better. Because mass bias caused by chemical procedure and instrument can easily cause significant analytical error, it is still a challenge to obtain accurate Mg isotope data for natural samples. In this paper, we systematically review the development of analytical technique of Mg isotopes, with a detailed description of a series of important techniques used in the measurement process, including calibration of instrumental mass-bias, chemical purification process, matrix effect, and pitfalls for high precision isotope analyses. We compare standard data from different labs and establish a guideline for Mg iso-tope analysis procedure. Additionally, we briefly discuss the behaviors of Mg isotopes during geological processes including equilibrium and kinetic Mg isotope fractionations, such as magma differentiation, chemical and thermal diffusion, and continental weathering. Finally, we propose some future prospects for Mg isotope geochemistry in both high and low temperature geological processes.

  10. Phanerozoic and Neoproterozoic Negative Carbon Isotope Excursions, Diagenesis and Terrestrialization (United States)

    Paul, K.; Kennedy, M. J.


    Comprehensive data sets of Phanerozoic and late Precambrian carbon isotope data derived from carbonate rocks show a similar positive relation when cross-plotted with oxygen isotope values. The range and slope between the time periods is identical and the processes responsible for the relation have been well documented in Quaternary sediments. These processes include the stabilization of isotope values to ambient meteoric water values during shallow burial and flushing of carbonate sediments. Both data sets show strongly depleted carbon (-9 per mil PDB) and oxygen isotope values that retain seemingly systematic stratigraphic patterns with the Quaternary and Phanerozoic examples that demonstrably record meteroric water values. Similar values and patterns in the Precambrian are interpreted as primary marine in origin with significant implications for an ocean carbon mass balance not possible in the Phanerozoic carbon cycle. A similar compilation of carbonates older than one billion years do not show a relation between carbon and oxygen isotopes, lacking the negative carbon values evident in the younger record. We hypothesize that this difference records the onset of significant organic carbon on the land surface and the alteration of meteoric waters toward Phanerozoic values. We demonstrate the meteoric affinities of Neoproterozoic carbonates containing prominent negative isotope excursions recorded in the Shuram and Wonoka Formations of Oman and South Australia commonly attributed to whole ocean isotope variation. The conspicuous absence of negative carbon isotope values with normal marine oxygenisotope values in the Phanerozoic and Neoproterozic identifies a consistent relation between these time intervals and suggests that, as well accepted in the Phanerozoic, negative carbon isotope excursions less than -3 per mil are not a record of marine processes, but rather the later terrestrial biotic influence on meteoric water values.

  11. Systematic measurements of the Bohr-Weisskopf effect at ISOLDE

    CERN Multimedia

    Nojiri, Y; Matsuki, S; Ragnarsson, I; Neugart, R; Redi, O; Stroke, H H; Duong, H T; Marescaux, D; Pinard, J; Juncar, P; Ekstrom, C; Pellarin, M; Vialle, J-L; Inamura, T


    The " Bohr-Weisskopf " effect, or " hyperfine structure (hfs) anomaly ", which results from the effect of the distribution of nuclear magnetization on the electro-nuclear interaction, will be measured systematically at the PS Booster ISOLDE, first for a long chain of radioactive cesium isotopes, analogously to previous isotope shift and hfs studies. In addition to the direct measurement of magnetic moment values, the results are expected to provide independent data for testing nuclear wavefunctions, these will be of importance for interpreting systematic parity non-conservation experiments, complementary to the single isotope study which requires a high precision knowledge of the electron wavefunction. Substantial progress in these calculations has been achieved recently. Precision measurements of the hfs splittings and nuclear magnetic moments are required, with sensitivity adequate for the radioactive isotopes produced. A triple resonance atomic beam magnetic resonance apparatus with optical pumping state s...

  12. Clumped Isotope Composition of Cold-Water Corals: A Role for Vital Effects? (United States)

    Spooner, P.; Guo, W.; Robinson, L. F.


    Measurements on a set of cold-water corals (mainly Desmophyllum dianthus) have suggested that their clumped isotope composition could serve as a promising proxy for reconstructing paleocean temperatures. Such measurements have also offered support for certain isotope models of coral calcification. However, there are differences in the clumped isotope compositions between warm-water and cold-water corals, suggesting that different kinds of corals could have differences in their biocalcification processes. In order to understand the systematics of clumped isotope variations in cold-water corals more fully, we present clumped isotope data from a range of cold-water coral species from the tropical Atlantic and the Southern Ocean.Our samples were either collected live or recently dead (14C ages biocalcification may not apply equally well to all corals. Clumped isotope vital effects may be present in certain cold-water corals as they are in warm-water corals, complicating the use of this paleoclimate proxy.

  13. Evidence of fissiogenic Cs estimated from Ba isotopic deviations in an Oklo natural reactor zone (United States)

    Hidaka, Hiroshi; Holliger, Philippe; Masuda, Akimasa


    Isotopic studies of many elements from the uranium ore natural nuclear reactors at Oklo provide useful information on the migration of radioactive nuclides. The fissiogenic isotopic composition of Ba is particularly interesting, as it is an important indication in the search for fissiogenic Cs. In this report we detail the detection of remarkable isotopic deviations of Ba in the Oklo samples and estimate the geochemical behaviour of fissiogenic Cs from excess Ba isotopes. Six samples systematically collected from borehole SF84 (zone 10) at the Oklo uranium mine have been analyzed. Isotopic deviations of Ba indicate the existence of fissiogenic Cs and Ba. A good correlation between the elemental abundance of Cs and isotopic abundances of excess 135Ba and 137Ba suggests that fissiogenic 135Ba and 137Ba behaved as Cs rather than Ba.

  14. Carbon isotopes of graphite: Implications on fluid history

    Directory of Open Access Journals (Sweden)

    F.J. Luque


    Full Text Available Stable carbon isotope geochemistry provides important information for the recognition of fundamental isotope exchange processes related to the movement of carbon in the lithosphere and permits the elaboration of models for the global carbon cycle. Carbon isotope ratios in fluid-deposited graphite are powerful tools for unravelling the ultimate origin of carbon (organic matter, mantle, or carbonates and help to constrain the fluid history and the mechanisms involved in graphite deposition. Graphite precipitation in fluid-deposited occurrences results from CO2- and/or CH4-bearing aqueous fluids. Fluid flow can be considered as both a closed (without replenishment of the fluid or an open system (with renewal of the fluid by successive fluid batches. In closed systems, carbon isotope systematics in graphite is mainly governed by Rayleigh precipitation and/or by changes in temperature affecting the fractionation factor between fluid and graphite. Such processes result in zoned graphite crystals or in successive graphite generations showing, in both cases, isotopic variation towards progressive 13C or 12C enrichment (depending upon the dominant carbon phase in the fluid, CO2 or CH4, respectively. In open systems, in which carbon is episodically introduced along the fracture systems, the carbon systematics is more complex and individual graphite crystals may display oscillatory zoning because of Rayleigh precipitation or heterogeneous variations of δ13C values when mixing of fluids or changes in the composition of the fluids are the mechanisms responsible for graphite precipitation.

  15. Isotope geochemistry. Biological signatures in clumped isotopes of O₂. (United States)

    Yeung, Laurence Y; Ash, Jeanine L; Young, Edward D


    The abundances of molecules containing more than one rare isotope have been applied broadly to determine formation temperatures of natural materials. These applications of "clumped" isotopes rely on the assumption that isotope-exchange equilibrium is reached, or at least approached, during the formation of those materials. In a closed-system terrarium experiment, we demonstrate that biological oxygen (O2) cycling drives the clumped-isotope composition of O2 away from isotopic equilibrium. Our model of the system suggests that unique biological signatures are present in clumped isotopes of O2—and not formation temperatures. Photosynthetic O2 is depleted in (18)O(18)O and (17)O(18)O relative to a stochastic distribution of isotopes, unlike at equilibrium, where heavy-isotope pairs are enriched. Similar signatures may be widespread in nature, offering new tracers of biological and geochemical cycling.

  16. Argon isotope fractionation induced by stepwise heating (United States)

    Trieloff, Mario; Falter, Martina; Buikin, Alexei I.; Korochantseva, Ekaterina V.; Jessberger, Elmar K.; Altherr, Rainer


    Noble gas isotopes are widely used to elucidate the history of the rocks in which they have been trapped, either from distinct reservoirs or by accumulation following radioactive decay. To extract noble gases from their host rocks, stepwise heating is the most commonly used technique to deconvolve isotopically different components, e.g., atmospheric, in situ radiogenic, or excess radiogenic from mantle or crustal reservoirs. The accurate determination of the isotopic composition of these different components is of crucial importance, e.g., for ages obtained by 40Ar- 39Ar stepheating plateaus. However, diffusion theory-based model calculations predict that the stepwise thermal extraction process from mineral phases induces isotope fractionation and, hence, adulterates the original composition. Such effects are largely unconsidered, as they are small and a compelling experimental observation is lacking. We report the first unequivocal evidence for significant mass fractionation of argon isotopes during thermal extraction, observed on shungite, a carbon-rich Precambrian sedimentary rock. The degree of fractionation, as monitored by 38Ar/ 36Ar and 40Ar/ 36Ar ratios, very well agrees with theoretical predictions assuming an inverse square root dependence of diffusion coefficient and atomic mass, resulting in easier extraction of lighter isotopes. Hence, subatmospheric 40Ar/ 36Ar ratios obtained for argon extracted at low temperatures may not represent paleoatmospheric argon. Shungite argon resembles modern atmospheric composition, but constraints on the timing of trapping appear difficult to obtain, as shungites are multicomponent systems. In 40Ar- 39Ar stepwise heating, the isotope fractionation effect could cause systematic underestimations of plateau ages, between 0.15 and 0.4% depending on age, or considerably higher if samples contain appreciable atmospheric Ar. The magnitude of this effect is similar to the presently achieved uncertainties of this increasingly

  17. Systematic review

    DEFF Research Database (Denmark)

    Lødrup, Anders Bergh; Reimer, Christina; Bytzer, Peter


    in getting off acid-suppressive medication and partly explain the increase in long-term use of PPI. A number of studies addressing this issue have been published recently. The authors aimed to systematically review the existing evidence of clinically relevant symptoms caused by acid rebound following PPI...

  18. Stable isotopes. Applications and production; Les isotopes stables. Applications - production

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, S.; Louvet, P.; Soulie, E. [eds.


    This conference presents 46 communications concerning stable isotope production, utilization and application, grouped in 6 sessions and posters. The various themes are: biological applications (pharmacology, medical diagnosis, metabolism and protein studies, toxicity and response studies, labelled compounds), analysis procedures (NMR analysis for macromolecules, tracer studies), nuclear applications (utilization of stable isotopes in nuclear reactors), biological, physical and chemical applications (mass transfer, mobility, crystallography, isotopic exchange), stable isotope production (ion chromatography, ion cyclotron resonance, cryogenic distillation).

  19. New geochemical and isotopic constraints on the genesis of the Oliveira Azeméis granitoid melts (Porto-Tomar Shear Zone, Iberian Variscan Chain, Central-Western Portugal) (United States)

    Santos, J. F.; Mendes, M. H.; Gonçalves, A. C.; Moita, P.


    The Porto-Tomar Shear Zone (PTSZ) is a very important tectonic structure that separates, in central-western Portugal, two of the major tectonic units of the Iberian Variscan Chain: the Ossa-Morena Zone, to the west, and the Central Iberian Zone, to the east. The Oliveira de Azeméis area lies in the northern sector of the PTZC and it is characterized by the occurrence of strongly deformed granitoids. Country rocks are dominantly pelitic metasediments which, according to recent geological mapping (Pereira et al., 2007), belong to the Precambrian Lourosa Formation and the Ordovician São João de Ver Formation. Using Rb-Sr whole-rock isotopic data, Pinto (1979) proposed an age of 379±12 Ma for the Oliveira de Azeméis granitoids. In this work, new results were obtained on these granitoids in the area between the villages of Travanca and Curval, especially in the Sacramento quarry. In this critical outcrop, strongly deformed two-mica granite (displaying S-C structures, with dextral NNW-SSE shear planes) pass into diatexites and metatexites with garnet, cordierite and sillimanite-bearing melanosomes. Leucosomes seem to have mainly granitic s.s. compositions, but cm-thick bands of leucotonalite were also found. Major element geochemistry of granite samples shows the following ranges: 71.4% ≤ SiO2 ≤ 74.2%; 0.74% ≤Fe2O3t ≤ 2.48%; 0.35% ≤ MgO ≤ 0.60%; 0.49% ≤ CaO ≤ 1.32%; 2.90% ≤ Na2O ≤ 3.11%; 4.70% ≤ K2O ≤ 5.47%; 1.17 ≤ ASI ≤ 1.36. Trace element data reveal a strong fractionation between highly incompatible LILE and less incompatible HFSE (248 ≤ PM normalized Rb/Y ≤ 671) and between LREE and HREE (18.6 ≤ PM normalized La/Lu ≤ 54.7). These features, in particular the peraluminous composition, the high K contents and the distinct rare-earth fractionation suggest that the Oliveira de Azeméis granites are mostly the result of partial melting of metasediments with a large pelitic component and that garnet is a likely residual phase

  20. Mother-embryo isotope (δ 15 N, δ 13 C) fractionation and mercury (Hg) transfer in aplacental deep-sea sharks : aplacental shark isotope fractionation and hg


    Le Bourg, B.; Kiszka, J.; Bustamante, P.


    Stable carbon (δ13C) and nitrogen (δ15N) isotopic values and total mercury (Hg) concentrations were analysed in muscle and liver of mothers and embryos of two aplacental shark species, Squalus megalops and Centrophorus moluccensis. Embryos of the two species had similar or lower isotopic values than their respective mothers, the only exception being for δ13C, which was higher in the liver of C. moluccensis embryos than in their mothers. Hg concentrations were systematically lower in embryos c...

  1. Isotopes in Condensed Matter

    CERN Document Server

    G Plekhanov, Vladimir


    This book provides a concise introduction to the newly created sub-discipline of solid state physics isotopetronics. The role of isotopes in materials and their properties are describe  in this book. The problem of the enigma of the atomic mass in microphysics is briefly discussed.  The range of the applications of isotopes is wide: from biochemical process in living organisms to modern technical applications in quantum information. Isotopetronics promises to improve nanoelectronic and optoelectronic devices. With numerous illustrations this book is useful to researchers, engineers and graduate students.

  2. Atomic Weights and Isotopic Compositions (United States)

    SRD 144 Atomic Weights and Isotopic Compositions (Web, free access)   The atomic weights are available for elements 1 through 111, and isotopic compositions or abundances are given when appropriate.

  3. Re-partitioning of Cu and Zn isotopes by modified protein expression

    Directory of Open Access Journals (Sweden)

    Ragnarsdottir K Vala


    Full Text Available Abstract Cu and Zn have naturally occurring non radioactive isotopes, and their isotopic systematics in a biological context are poorly understood. In this study we used double focussing mass spectroscopy to determine the ratios for these isotopes for the first time in mouse brain. The Cu and Zn isotope ratios for four strains of wild-type mice showed no significant difference (δ65Cu -0.12 to -0.78 permil; δ66Zn -0.23 to -0.48 permil. We also looked at how altering the expression of a single copper binding protein, the prion protein (PrP, alters the isotope ratios. Both knockout and overexpression of PrP had no significant effect on the ratio of Cu isotopes. Mice brains expressing mutant PrP lacking the known metal binding domain have δ65Cu isotope values of on average 0.57 permil higher than wild-type mouse brains. This implies that loss of the copper binding domain of PrP increases the level of 65Cu in the brain. δ66Zn isotope values of the transgenic mouse brains are enriched for 66Zn to the wild-type mouse brains. Here we show for the first time that the expression of a single protein can alter the partitioning of metal isotopes in mouse brains. The results imply that the expression of the prion protein can alter cellular Cu isotope content.

  4. Discoveries of isotopes by fission

    Indian Academy of Sciences (India)

    M Thoennessen


    Of the about 3000 isotopes presently known, about 20% have been discovered in fission. The history of fission as it relates to the discovery of isotopes as well as the various reaction mechanisms leading to isotope discoveries involving fission are presented.

  5. Systematic Avocating

    Directory of Open Access Journals (Sweden)

    Jan Green


    Full Text Available Feeling obliged to undertake complex research tasks outside core working hours is a common occurrence in academia. Detailed and timely research projects are expected; the creation and defence of sufficient intervals within a crowded working schedule is one concern explored in this short version paper. Merely working longer hours fails to provide a satisfactory solution for individuals experiencing concerns of this nature. Personal effort and drive are utilised and requires the application of mental mustering and systematic procedures. The attitude to research work is treating the task as a hobby conceptualised as avocating. Whilst this provides a personal solution through immersion in the task, this approach should raise concerns for employers. The flexibility of grounded theory is evident and the freedom to draw on various bodies of knowledge provides fresh insight into a problem that occurs in organizations in many sectors experiencing multiple priorities. The application of the core category, systematic avocating, may prove beneficial.

  6. Zinc Isotopic Signatures of the Upper Continental Crust (United States)

    Xia, Y.; Zhang, X.; Zhang, H.; Huang, F.


    To examine the Zn isotope systematics within the Upper Continental Crust (UCC), and isotope fractionation during chemical weathering in large spatial and temporal scales, we analyzed Zn isotopic compositions of loess, glacial diamictites, river sediments, and igneous rocks (samples in total 77). The Zn isotopic compositions (δ66Zn relative to JMC-Lyon) of loess display a limited variation (0.17‰ to 0.29‰), which is negatively correlated with Zn content and proxies for chemical weathering (e.g. CIA values), reflect the impact of chemical weathering. Glacial diamictites have more variable δ66Zn (0.09‰ to 0.48‰), but the average δ66Zn (0.29±0.03‰, 2SD) is similar to loess. δ66Zn of glacial diamictites correlate roughly negatively with CIA values, but have no correlation with Zn content, implying source heterogeneity and effect from chemical weathering. δ66Zn of A-type (0.39‰ to 0.45‰) and S-type (0.28‰ to 0.35‰) granites are both homogeneous, but the latter have systematically lighter δ66Zn. This may reflect no Zn isotopic fractionation during magmatic processes and involvement of isotopically light meta-sedimentary into the sources of S-type granites. Furthermore, δ66Zn in riverine sediments display a small variation from 0.23‰ to 0.37‰, while δ66Zn of the the shales vary from 0.14‰ to 0.53‰, which could result from a combination of processes, such as biological cycling and chemical weathering. Overall, our data suggest that incipient chemical weathering can fractionate Zn isotopes significantly, meanwhile, during this process, heavy Zn are released preferentially. The UCC is estimated to have an average δ66Zn of 0.30 ±0.03‰ (2SD) with data collected in this study, which is similar to the estimated value of Bulk Silicate Earth (0.28±0.05‰)[1] and mean dissolved riverine flux (0.33‰)[2], but distinctly lighter than the bulk composition of dissolved Zn in the ocean (0.51‰)[2]. [1] Chen et al., Zinc isotope fractionation


    Institute of Scientific and Technical Information of China (English)


    <正>20090432 Zhou Shuqing (School of Energy Resources, China University of Geosciences Beijing 100083, China); Huang Haiping Stable Isotopic Records vs. Important Events in Life Evolution and the Concurrent Environment (Geological Review, ISSN0371-5736, CN11-1952, 54(2), 2008, p.225-231, 3 illus., 1 table, 77 refs.)


    Institute of Scientific and Technical Information of China (English)


    <正>20141014Wang Hairan(State Key Laboratory of Continental Dynamics,Department of Geology,Northwest University,Xi’an710069,China);Zhao Hongge Theory and Application of Zircon U-Pb Isotope Dating Technique(Geology and Resources,ISSN1671-1947,CN21-1458/P,22(3),2013,p.229


    Institute of Scientific and Technical Information of China (English)


    <正>20072750 Huang Sijing(State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China);Pei Changrong Age Calibration for the Boundary between Lower and Middle Triassic by Strontium Isotope Stratigraphy in Eastern Sichuan Province


    Institute of Scientific and Technical Information of China (English)


    <正>20070454 Bao Zengkuan (Institute of High Energy Physics, CAS, Beijing 100049, China); Yuan Wanming Apatite (U-Th)/He Dating and Its Application (Acta Petrologica et Mineralogica, ISSN1000-6524, CN11-1966/P, 24(2), 2005, p.126-132, 2 illus., 25 refs.) Key words: isotopic geochronology

  11. Isotopic Implicit Surface Meshing

    NARCIS (Netherlands)

    Boissonnat, Jean-Daniel; Cohen-Steiner, David; Vegter, Gert


    This paper addresses the problem of piecewise linear approximation of implicit surfaces. We first give a criterion ensuring that the zero-set of a smooth function and the one of a piecewise linear approximation of it are isotopic. Then, we deduce from this criterion an implicit surface meshing algor

  12. Isotope hydrograph separation

    Energy Technology Data Exchange (ETDEWEB)

    Fritz, P. [UFZ-Umweltforschungszentrum, Centre of Environmental Research Leipzig-Halle, Leipzig (Germany)


    Storm-runoff thus reflects the complex hydraulic behaviour of drainage basins and water-links of such systems. Water of different origin may participate in the events and in this lecture, the application of isotope techniques to separate storm hydrographs into different components will be presented.

  13. Forensic Stable Isotope Biogeochemistry (United States)

    Cerling, Thure E.; Barnette, Janet E.; Bowen, Gabriel J.; Chesson, Lesley A.; Ehleringer, James R.; Remien, Christopher H.; Shea, Patrick; Tipple, Brett J.; West, Jason B.


    Stable isotopes are being used for forensic science studies, with applications to both natural and manufactured products. In this review we discuss how scientific evidence can be used in the legal context and where the scientific progress of hypothesis revisions can be in tension with the legal expectations of widely used methods for measurements. Although this review is written in the context of US law, many of the considerations of scientific reproducibility and acceptance of relevant scientific data span other legal systems that might apply different legal principles and therefore reach different conclusions. Stable isotopes are used in legal situations for comparing samples for authenticity or evidentiary considerations, in understanding trade patterns of illegal materials, and in understanding the origins of unknown decedents. Isotope evidence is particularly useful when considered in the broad framework of physiochemical processes and in recognizing regional to global patterns found in many materials, including foods and food products, drugs, and humans. Stable isotopes considered in the larger spatial context add an important dimension to forensic science.

  14. Isotopic composition of Pb and Th in interplinian volcanics from Somma-Vesuvius volcano, Italy (United States)

    Cortini, M.; Ayuso, R.A.; de Vivo, B.; Holden, P.; Somma, R.


    We present a detailed isotopic study of volcanic rocks emitted from Somma-Vesuvius volcano during three periods of interplinian activity: "Protohistoric" (3550 y B.P. to 79 A.D.), "Ancient Historic" (79 to 472 A.D.) and "Medieval" (472 to 1631 A.D.). Pb isotopic compositions of two acid leached fractions and whole rock residues of 37 whole rock samples (determined by Somma et al., 2001) show that each of the three interplinian periods is distinguished by small, systematic, and unique uranogenic and thorogenic Pb isotopic trends. This key and novel feature is compatible with the notion that the Pb isotopic data reflect small-scale source heterogeneity operating over relatively short periods of time. From this representative group of samples, a selected set of nine whole rocks were analysed for Th isotopes. 232Th/238U ratios in the source can be obtained independently from Pb and from Th isotopes. Those obtained from Pb isotopes represent source ratios, time-integrated over the whole age of the Earth; they range from 3.9 to 4.1. 232Th/238U obtained from Th isotopes are those of the present source. They are lower, and cluster around 3.5; this difference probably indicates recent U enrichment of the present source. The behaviour of Pb, as inferred by its isotopic ratios, is quite distinct from that of Sr and Nd isotopes: Pb isotope variations are not correlated to Sr or Nd isotope variations. The isotopic contrast is compatible with the idea that the isotopes were decoupled during magmatic production, evolution, and ascent through the crust. Thus, the Pb isotopes do not reflect the effects of the same processes as in the case of the Sr and Nd isotopes, or, as we also favor, they do not necessarily reflect the same source contributions into the magmas. Moreover, the Pb isotopic evolution of the interplinian rocks chiefly reflects mixing, driven by processes that are superimposed on, and independent of, other source contributions that determine the isotopic compositions

  15. Geochronological and palaeomagnetic reconnaissance survey in parts of Central and Southern Sweden

    NARCIS (Netherlands)

    Priem, H.N.A.; Mulder, F.G.; Boelrijk, N.A.I.M.; Hebeda, E.H.; Verschure, R.H.; Verdurmen, E.A.Th.


    Palaeomagnetic investigations and isotopic age determinations were made on various Precambrian and Palaeozoic rocks from southern and central Sweden. (1) In Dalarna (central Sweden), Rb-Sr determinations show that the Upper Dala volcanics and the Dala “Garberg granite” have a Gothian age of 1405 ± 3

  16. Water isotopes in desiccating lichens (United States)

    Cuntz, Matthias; Máguas, Cristina; Lakatos, Michael


    The stable isotopic composition of water is routinely used as a tracer to study water exchange processes in vascular plants and ecosystems. To date, no study has focussed on isotope processes in non-vascular, poikilohydric organisms such as lichens and bryophytes. To understand basic isotope exchange processes of non-vascular plants, thallus water isotopic composition was studied in various green-algal lichens exposed to desiccation. The study indicates that lichens equilibrate with the isotopic composition of surrounding water vapour. A model was developed as a proof of concept that accounts for the specific water relations of these poikilohydric organisms. The approach incorporates first their variable thallus water potential and second a compartmentation of the thallus water into two isotopically distinct but connected water pools. Moreover, the results represent first steps towards the development of poikilohydric organisms as a recorder of ambient vapour isotopic composition. PMID:19888598

  17. Isotope scaling of the H mode power threshold on JET (United States)

    Righi, E.; Bartlett, D. V.; Christiansen, J. P.; Conway, G. D.; Cordey, J. G.; Eriksson, L.-G.; DeEsch, H. P. L.; Fishpool, G. M.; Gowers, C. W.; de Haas, J. C. M.; Harbour, P. J.; Hawkes, N. C.; Jacquinot, J.; Jones, T. T. C.; Kerner, W.; King, Q. A.; Lowry, C. G.; Monk, R. D.; Nielsen, P.; Rimini, F. G.; Saibene, G.; Sartori, R.; Schunke, B.; Sips, A. C. C.; Smith, R. J.; Stamp, M. F.; Start, D. F. H.; Thomsen, K.; Tubbing, B. J. D.; Zornig, N.


    Results are presented from a series of dedicated experiments carried out on JET in tritium, DT, deuterium and hydrogen plasmas to determine the dependence of the H mode power threshold on the plasma isotopic mass. The Pthr propto Aeff-1 scaling is established over the whole isotopic range. This result makes it possible for a fusion reactor with a 50:50 DT mixture to access the H mode regime with about 20% less power than that needed in a DD mixture. Results on the first systematic measurements of the power necessary for the transition of the plasma to the type I ELM regime, which occurs after the transition to H mode, are also in agreement with the Aeff-1 scaling. For a subset of discharges, measurements of Te and Ti at the top of the profile pedestal have been obtained, indicating a weak influence of the isotopic mass on the critical edge temperature thought to be necessary for the H mode transition.

  18. Diversity of sulfur isotope fractionations by sulfate-reducing prokaryotes

    DEFF Research Database (Denmark)

    Detmers, Jan; Brüchert, Volker; Habicht, K S


    Batch culture experiments were performed with 32 different sulfate-reducing prokaryotes to explore the diversity in sulfur isotope fractionation during dissimilatory sulfate reduction by pure cultures. The selected strains reflect the phylogenetic and physiologic diversity of presently known...... sulfate reducers and cover a broad range of natural marine and freshwater habitats. Experimental conditions were designed to achieve optimum growth conditions with respect to electron donors, salinity, temperature, and pH. Under these optimized conditions, experimental fractionation factors ranged from 2.......0 to 42.0 per thousand. Salinity, incubation temperature, pH, and phylogeny had no systematic effect on the sulfur isotope fractionation. There was no correlation between isotope fractionation and sulfate reduction rate. The type of dissimilatory bisulfite reductase also had no effect on fractionation...

  19. Expanding the isotopic toolbox: Applications of hydrogen and oxygen stable isotope ratios to food web studies

    Directory of Open Access Journals (Sweden)

    Hannah B Vander Zanden


    Full Text Available The measurement of stable carbon (δ13C and nitrogen (δ15N isotopes in tissues of organisms has formed the foundation of isotopic food web reconstructions, as these values directly reflect assimilated diet. In contrast, stable hydrogen (δ2H and oxygen (δ18O isotope measurements have typically been reserved for studies of migratory origin and paleoclimate reconstruction based on systematic relationships between organismal tissue and local environmental water. Recently, innovative applications using δ2H and, to a lesser extent, δ18O values have demonstrated potential for these elements to provide novel insights in modern food web studies. We explore the advantages and challenges associated with three applications of δ2H and δ18O values in food web studies. First, large δ2H differences between aquatic and terrestrial ecosystem end members can permit the quantification of energy inputs and nutrient fluxes between these two sources, with potential applications for determining allochthonous vs. autochthonous nutrient sources in freshwater systems and relative aquatic habitat utilization by terrestrial organisms. Next, some studies have identified a relationship between δ2H values and trophic position, which suggests that this marker may serve as a trophic indicator, in addition to the more commonly used δ15N values. Finally, coupled measurements of δ2H and δ18O values are increasing as a result of reduced analytical challenges to measure both simultaneously and may provide additional ecological information over single element measurements. In some organisms, the isotopic ratios of these two elements are tightly coupled, whereas the isotopic disequilibrium in other organisms may offer insight into the diet and physiology of individuals. Although a coherent framework for interpreting δ2H and δ18O data in the context of food web studies is emerging, many fundamental uncertainties remain. We highlight directions for targeted research that

  20. Chromium Isotopes in Marine Carbonates - an Indicator for Climatic Change? (United States)

    Frei, R.; Gaucher, C.


    Chromium (Cr) stable isotopes experience an increased interest as a tracer of Cr (VI) reduction in groundwater and thus showed their potential as a monitor of remediation of anthropogenic and natural contamination in water (Berna et al., 2009; Izbicki et al., 2008). Chromium stable isotopes in Fe-rich chemical sediments (BIFs and Fe-cherts) have recently also been used as a tracer for Earth's atmospheric oxygenation through time (Frei et al., 2009). We have applied the Cr isotope system to organic-rich carbonates from a late Ediacaran succession in Uruguay (Polanco Formation), from which we have previously analyzed BIFs with extremely fractionated (δ53Cr up to 5.0 ‰) Cr isotope signatures that are part of an underlying deep water clastic sediment (shale-dominated) sequence (Yerbal Formation) deposited in a glacio-marine environment (Gaucher et al.,2004). δ53Cr values of organic rich carbonates correlate with positive and negative carbon isotope excursions (δ13C PDB between -3 and +3 ‰) and with systematic changes in strontium isotope compositions, commonly interpreted as to reflect fluctuations in organic (photosynthetic algae) production related to fluctuations in atmospheric oxygen and weathering intensities, respectively. Slightly positively fractioned δ53Cr values (up to +0.25‰), paralleling positive (δ13C PDB and 87Sr/86Sr ratio excursions would thereby trace elevated atmospheric oxygen levels/pulses possibly related to glacier retreat/melting stages that caused bioproductivity to increase. While the causal link between these multiple isotopic tracers and the mechanisms of Cr stripping into carbonates has to be further investigated in detail, the first indications from this study point to a potentially promising use of stable Cr isotopes in organic-rich carbonates to monitor fluctuations of atmospheric oxygen, particularly over the Neoproterozoic and Phanerozoic ice age periods. E.C. Berna et al. (2010) Cr stable isotopes as indicators of Cr

  1. Early Disk dynamics Inferred from Isotope Systematics of Individual Chrondules

    DEFF Research Database (Denmark)

    Bollard, Jean Francois André

    to different reservoirs. Lastly, a reduced abundance of 26Al relative to 27Al in inner Solar System objects implies that asteroid accretion must have occurred very early in the Solar System’s formation, to allow melting and differentiation driven by 26Al decay. With respect to our Pb-Pb chondrule chronology...

  2. Early Disk dynamics Inferred from Isotope Systematics of Individual Chrondules

    DEFF Research Database (Denmark)

    Bollard, Jean Francois André

    to different reservoirs. Lastly, a reduced abundance of 26Al relative to 27Al in inner Solar System objects implies that asteroid accretion must have occurred very early in the Solar System’s formation, to allow melting and differentiation driven by 26Al decay. With respect to our Pb-Pb chondrule chronology...

  3. Chronologic implications for slow cooling of troctolite 76535 and temporal relationships between the Mg-suite and the ferroan anorthosite suite (United States)

    Borg, Lars E.; Connelly, James N.; Cassata, William S.; Gaffney, Amy M.; Bizzarro, Martin


    Ages have been obtained using the 87Rb-87Sr, 147Sm-143Nd, and 146Sm-142Nd isotopic systems for one of the most slowly cooled lunar rocks, Apollo 17 Mg-suite troctolite 76535. The 147Sm-143Nd, 146Sm-142Nd, and Rb-Sr ages derived from plagioclase, olivine, and pyroxene mineral isochrons yield concordant ages of 4307 ± 11 Ma, 4299+29/-35 Ma, and 4279 ± 52 Ma, respectively. These ages are slightly younger than the age determined on ferroan anorthosite suite (FAS) rock 60025 and are therefore consistent with the traditional magma ocean model of lunar differentiation in which the Mg-suite is intruded into the anorthositic crust. However, the Sm-Nd ages record when the rock passed below the closing temperature of the Sm-Nd system in this rock at ∼825 °C, whereas the Rb-Sr age likely records the closure temperature of ∼650 °C. A cooling rate of 3.9 °C/Ma is determined using the ages reported here and in the literature and calculated closure temperatures for the Ar-Ar, Pb-Pb, Rb-Sr, and Sm-Nd systems. This cooling rate is in good agreement with cooling rates estimated from petrographic observations. Slow cooling can lower apparent Sm-Nd crystallization ages by up to ∼80 Ma in the slowest cooled rocks like 76535, and likely accounts for some of the variation of ages reported for lunar crustal rocks. Nevertheless, slow cooling cannot account for the overlap in FAS and Mg-suite rock ages. Instead, this overlap appears to reflect the concordance of Mg-suite and FAS magmatism in the lunar crust as indicated by ages calculated for the solidus temperature of 76535 and 60025 of 4384 ± 24 Ma and 4383 ± 17, respectively. Not only are the solidus ages of 76535 and 60025 nearly concordant, but the Sm-Nd isotopic systematics suggest they are derived from reservoirs that were minimally differentiated prior to ∼4.38 Ga. Although the Sr isotopic composition of 60025 indicates its source was minimally differentiated, the Sr isotopic composition of 76535 indicates it underwent

  4. Modelling of mercury isotope separation in CP stellar atmospheres: results and problems

    CERN Document Server

    Sapar, A; Sapar, L; Poolamäe, R; 10.1016/j.newar.2009.08.010


    Formation of anomalous isotope abundances in the atmospheres of chemically peculiar (CP) stars can be explained by light-induced drift (LID). This effect is additional to the radiative acceleration and appears due to systematic asymmetry of radiative flux in partly overlapping isotopic spectral line profiles. LID causes levitation of an isotope with a red-shifted spectral line and sinking of an isotope with a blue-shifted line, generating thus diffusive separation of isotopes. We have studied diffusion of mercury as a typical well-studied isotope-rich heavy metal. Our model computations show that in mercury-rich quiescent atmospheres of CP stars LID causes levitation of the heavier mercury isotopes and sinking of the lighter ones. Precise quantitative modelling of the process of isotope separation demands very high-resolution computations and the high-precision input data, including data on hyperfine and isotopic splitting of spectral lines, adequate line profiles and impact cross-sections. Presence of microt...

  5. Chromium isotope variations

    DEFF Research Database (Denmark)

    D'Arcy, Joan Mary

    is incorporated into carbonates. Hence, ancient carbonates can potentially record the Cr isotopic composition (δ53Cr ‰) of seawater in the geological past. Reliable application and interpretation of this proxy requires a detailed knowledge about processes that fractionate Cr on the Earth’s surface...... deposited during the Early Ordovician — a time of known redox instability in ancient oceans – exhibit a significant positive Cr isotope excursion of +0.5‰. This excursion is interpreted as the reductive drawn down of dissolved Cr in seawater in response to the development of a proximal anoxic sink...... of ancient marine sediments can be a useful tool for understanding the cycling of redox sensitive elements on a local scale....

  6. Collectivity of the neutron-deficient odd yttrium isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Bucurescu, D.; Cata, G.; Ivascu, M.; Zamfir, N.V.; Liang, C.F.; Paris, P.


    Multishell IBFM-1 calculations are reported for the neutron-deficient odd yttrium isotopes (79-85), which give a good description of both the positive and negative parity levels known experimentally. An exchange force whose intensity varies with the mass number is required. This phenomenological variation reflects qualitatively the microscopic origin of the exchange term, and also points to possible systematics of the model parameters in the ALPHA approx. = 80 region of the Nsub(p)Nsub(n) type.


    Institute of Scientific and Technical Information of China (English)


    <正>20050934 Chen Zhihong (Chinese Academy of Geological Sciences, Beijing 100037, China); Lu Songnian Age of the Fushui Intermediate-Mafic Intrusive Complex in the Qinling Orogen, New Zircon U - Pb and Whole -Rock Sm and Nd Isotope Chronological Evidence (Geological Bulletin of China, ISSN 1671-2552, CN11-4648/P, 23(4), 2004, p. 322-328, 3 illus. , 3 tables, 10 refs. )


    Institute of Scientific and Technical Information of China (English)


    <正>20131727 Huang Xiaowen(State Key Laboratory of Ore Deposit Geochemistry,Institute of Geochemistry,Chinese Academy of Sciences,Guiyang 550002,China);Qi Liang Preliminary Study on Sample-Preparation for Re-Os Isotopic Dating of Pyrite(Geochimica,ISSN0379-1726,CN44-1398/P,41(4),2012,p.380-386,3illus.,2tables,25refs)Key words:pyrite,Re-Os dating


    Institute of Scientific and Technical Information of China (English)


    <正>20132601 Cui Yurong(Tianjin Institute of Geology and Mineral Resources,China Geological Survey,Tianjin 300170,China);Zhou Hongying In Situ LA-MC-ICP-MS U-Pb Isotopic Dating of Monazite(Acta Geoscientica Sinica,ISSN0375-5444,CN11-1856/P,33(6),2012,p.865-876,6illus.,4tables,41refs.)Key words:monazite,U-Pb dating


    Energy Technology Data Exchange (ETDEWEB)



    The use of isotope labels has had a fundamentally important role in the determination of mechanisms of homogeneously catalyzed reactions. Mechanistic data is valuable since it can assist in the design and rational improvement of homogeneous catalysts. There are several ways to use isotopes in mechanistic chemistry. Isotopes can be introduced into controlled experiments and followed where they go or don't go; in this way, Libby, Calvin, Taube and others used isotopes to elucidate mechanistic pathways for very different, yet important chemistries. Another important isotope method is the study of kinetic isotope effects (KIEs) and equilibrium isotope effect (EIEs). Here the mere observation of where a label winds up is no longer enough - what matters is how much slower (or faster) a labeled molecule reacts than the unlabeled material. The most careti studies essentially involve the measurement of isotope fractionation between a reference ground state and the transition state. Thus kinetic isotope effects provide unique data unavailable from other methods, since information about the transition state of a reaction is obtained. Because getting an experimental glimpse of transition states is really tantamount to understanding catalysis, kinetic isotope effects are very powerful.

  11. Isotope-geochemical Nd-Sr evidence of Palaeoproterozoic plume magmatism in Fennoscandia and mantle-crust interaction on stages of layered intrusions formation (United States)

    Serov, Pavel; Bayanova, Tamara; Kunakkuzin, Evgeniy; Steshenko, Ekaterina


    Palaeoproterozoic Fennoscandian layered intrusions belong to the pyroxenite-gabbronorite-anorthosite formation and spread on a vast area within the Baltic Shield. Based on isotope U-Pb, Sm-Nd, Rb-Sr and Re-Os data the duration of this formation can be to 100-130 Ma (2.53-2.40 Ga) [Serov et. al., 2008; Bayanova et. al., 2009]. We have studied rocks of layered PGE-bearing Fedorovo-Pansky, Monchetundra, Burakovsky, Olanga group intrusions and Penikat intrusion. According to recent and new complex Nd-Sr-REE data magma source of the vast majority of these intrusions was a mantle reservoir with unusual characteristics: negative values of ɛNd (from 0 to -4) and ISr = 0.702-0.706, flat spectra of REE (value of (La/Yb)N ~ 1.0-5.8) with positive Eu-anomalies [Bayanova et. al., 2009; Bayanova et. al., 2014]. However, the distribution of REE for ore-bearing gabbronorite intrusions Penikat (Sm-Nd age is 2426 ± 38 Ma [Ekimova et. al., 2011]) has a negative Eu-anomalies. This may be due to the formation of plagioclase and its removal from the magma chamber. One of the aims of isotope geochemical investigations is to establish the contribution of mantle components in the formation of layered intrusions rocks and the degrees of contamination of the magma source by crustal material. To calculate the proportion of mantle component model binary mixture was used [Jahn et. al., 2000]. As the mantle components we used data for CHUR: ɛNd = 0, [Nd] = 1.324 [Palm, O'Neil, 2003] and for crustal components were used host-rocks Nd-data. The proportion of mantle component for the studied intrusions was 77-99%. Also, data were obtained for the Monchetundra dike complex and amphibolized gabbro, for which the proportion of mantle material was 20-40%. For these rocks a significant crustal contamination is most likely. This process resulted in low values of ɛNd, a direct relationship between ɛNd and Nd concentration, and significant differences between the U-Pb and Sm-Nd model ages. A

  12. Nuclear physics and stable isotopes; Physique nucleaire et isotopes stables

    Energy Technology Data Exchange (ETDEWEB)

    Goutte, D. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Dept. d`Astrophysique, de la Physique des Particules, de la Physique Nucleaire et de l`Instrumentation Associee


    The aim of this paper is to show that fundamental research in nuclear physics requires utilization of stable isotopes; stable isotopes are essential as target material since a large quantity of nucleus have to be studied in order to appreciate all the complexity of the nuclear structure, but also as a tool, such as beams, for the same purpose. Examples are given with samarium, tin and germanium isotopes. 7 figs.

  13. Stable isotopes of transition and post-transition metals as tracers in environmental studies (United States)

    Bullen, Tomas D.; Baskaran, Mark


    The transition and post-transition metals, which include the elements in Groups 3–12 of the Periodic Table, have a broad range of geological and biological roles as well as industrial applications and thus are widespread in the environment. Interdisciplinary research over the past decade has resulted in a broad understanding of the isotope systematics of this important group of elements and revealed largely unexpected variability in isotope composition for natural materials. Significant kinetic and equilibrium isotope fractionation has been observed for redox sensitive metals such as iron, chromium, copper, molybdenum and mercury, and for metals that are not redox sensitive in nature such as cadmium and zinc. In the environmental sciences, the isotopes are increasingly being used to understand important issues such as tracing of metal contaminant sources and fates, unraveling metal redox cycles, deciphering metal nutrient pathways and cycles, and developing isotope biosignatures that can indicate the role of biological activity in ancient and modern planetary systems.

  14. Dynamic isotope effects on relaxation of quadrupolar nuclei in 12 simple organic molecules

    Institute of Scientific and Technical Information of China (English)

    毛希安; andM.Holz


    Dynamic isotope effects on relaxation rate of quadrupolar nuclei are preliminarily reported. The relaxation rates of 17O and 14N in 12 simple organic molecules and their 18 corresponding deuterated species have been systematically measured. The principal components of the molecular inertia tensors have been calculated. The results show that there is an intrinsic correlation between the dynamic isotope effects of the relaxation rate and the static isotope effects of the molecular inertia. The concepts of molecular collision frequency and translation-rotation coupling have been introduced into the NMR relaxation theory. Therefore, a reasonable explanation of the experimental results has been given.

  15. Nickel isotopes and methanogens (United States)

    Neubeck, A.; Ivarsson, M.


    Methanogens require Ni for their growth and as a consequence the microbial fractionation of Ni isotopes can be used as a biomarker for activity of methanogenic communities1. Anaerobic laboratory experiments was performed using methanogens to investigate methanogenic growth in a modified nutrient media2 with olivine Fo91 (5g/l) added as an additional mineral nutrient source and as the only H2 provider. One of the investigated methanogens showed an increased growth in the experiments with added olivine. There were also a close relationship between the mobilized Ni and the growth of the methanogen. Ni is an element that previously has been neglected in the study of fossilized microorganisms and their interaction with mineral substrates and, thus, there are no records or published data of Ni in association with microfossils. However, we have detected enrichments of Ni in fossilized microorganisms and ichno-fossils, respectively, from three separate locations. Ni is not present in the host rock in any of the samples. Thus, Ni is present in association with fossilized microorganisms from environments and more extensive analysis is required to understand the magnitude, uptake, preservation and fractionation of Ni in microfossils. In order to analyze Ni isotope fractionation from microbe-mineral interaction, we plan to use a high-resolution Laser-Ablation Time-of-Flight Mass Spectrometer (LMS)3. In situ profile ablation will provide detailed and localized data on fractionation patterns between microfossils and their host rock. Also, this technique will allow us to identify the change in Ni isotopic fractionation in rock samples caused by abiotic and biogenic processes in a faster and easier way and with less risk for contamination compared to the wet chemistry analyses of Ni isotopes. 1. Cameron, V., Vance, D., Archer, C. & House, C. H. A biomarker based on the stable isotopes of nickel. Proceedings of the National Academy of Sciences 106, 10944-10948 (2009). 2. Schn

  16. Systematic review

    DEFF Research Database (Denmark)

    Borup, H; Kirkeskov, L; Hanskov, Dorte Jessing Agerby


    of airway obstruction among workers in the construction industry. The authors independently assessed studies to determine their eligibility and performed a quality assessment of the included papers. Results: Twelve studies were included. Nine studies found a statistically significant association between......: To assess the occurrence of COPD among construction workers. Methods: We performed a systematic search in PubMed and Embase between 1 January 1990 and 31 August 2016 in order to identify epidemiological studies with a risk estimate for either COPD morbidity/mortality or a spirometry-based definition......Background: Between 15 and 20% of prevalent cases of chronic obstructive pulmonary disease (COPD) have been attributed to occupational exposures to vapours, gases, dusts and fumes. Dust at construction sites is still a challenge, but no overview exists of COPD among construction workers. Aims...

  17. Therapeutic use of radioactive isotopes

    CERN Multimedia

    Caroline Duc


    In December, researchers from ISOLDE-CERN, the Paul Scherrer Institute (PSI) and the Institut Laue-Langevin (ILL) published the results of an in vivo study which successfully proved the effectiveness of four terbium isotopes for diagnosing and treating cancerous tumours.   Four terbium isotopes suitable for clinical purposes. “ISOLDE is the only installation capable of supplying terbium isotopes of such purity and intensity in the case of three out of the four types used in this study,” explains Karl Johnson, a physicist at ISOLDE.  “Producing over a thousand different isotopes, our equipment offers the widest choice of isotopes in the world!” Initially intended for fundamental physics research, ISOLDE has diversified its activities over time to invest in various projects in the materials science, biochemistry and nuclear medicine fields. The proof-of-concept study has confirmed that the four terbium isotopes 149Tb, 152Tb, 155Tb produ...

  18. Technical Note: Silica stable isotopes and silicification in a carnivorous sponge \\textit{Asbestopluma} sp.

    Directory of Open Access Journals (Sweden)

    K. R. Hendry


    Full Text Available The stable isotope composition of benthic sponge spicule silica is a potential source of palaeoceanographic information about past deep seawater chemistry. The silicon isotopic composition of spicules has been shown to relate to the silicic acid concentration of ambient water, although existing calibrations do exhibit a degree of scatter in the relationship. Less is known about how the oxygen isotope composition of sponge spicule silica relates to environmental conditions during growth. Here, we investigate the biological vital effects on silica silicon and oxygen isotope composition in a carnivorous sponge, Asbestopluma sp., from the Southern Ocean. We find significant variations in silicon and oxygen isotopic composition within the specimen that appear related to unusual spicule silicification. The largest variation in both isotope systems was associated to the differential distribution of an unconventional, hypersilicified spicule type (desma along the sponge body. The absence of an internal canal in the desmas suggests an unconventional silicification pattern leading to an unusually heavy isotopic signature. Additional internal variability derives from a systematic offset between the peripheral skeleton of the body having systematically a higher isotopic composition than the internal skeleton. A simplified silicon isotope fractionation model, in which desmas were excluded, suggests that the lack of a system for seawater pumping in carnivorous sponges favours a low replenishment of dissolved silicon within the internal tissues, causing kinetic fractionation during silicification that impacts the isotopic signature of the internal skeleton. Analysis of multiple spicules should be carried out to "average out" any artefacts in order to produce more robust downcore measurements.

  19. IUPAC Periodic Table of Isotopes for the Educational Community

    Energy Technology Data Exchange (ETDEWEB)

    Holden N. E.; Holden,N.E.; Coplen,T.B.


    John Dalton first proposed the concept of atomic weights of the elements in the first decade of the nineteenth century. These atomic weights of the chemical elements were thought of as constants of nature, similar to the speed of light. Dmitri Mendeleev arranged the atomic weights of the elements in ascending order of value and used the systematic variation of their chemical properties to produce his Periodic Table of the Elements in 1869. Measurement of atomic weight values became an important chemical activity for a century and a half. Theodore Richards received a Noble Prize for his work in this area. In 1913, Fredrick Soddy found a species of radium, which had an atomic weight value of 228, compared to the familiar radium gas value of 226. Soddy coined the term 'isotope' (Greek for 'in the same place') to account for this second atomic weight value in the radium position of the Periodic Table. Both of these isotopes of radium are radioactive. Radioactive isotopes are energetically unstable and will decay (disintegrate) over time. The time it takes for one half of a sample of a given radioactive isotope to decay is the half-life of that isotope. In addition to having different atomic weight values, radium-226 and radium-228 also have different half-life values. Around the same time as Soddy's work, J.J. Thomson (discoverer of the electron) identified two stable (non-radioactive) isotopes of the same element, neon. Over the next 40 years, the majority of the known chemical elements were found to have two or more stable (or long-lived radioactive isotopes that contribute significantly to the determination of the atomic weights of the elements).

  20. Lithium isotope separation by laser

    Energy Technology Data Exchange (ETDEWEB)

    Arisawa, T.; Maruyama, Y.; Suzuki, Y.; Shiba, K.


    A lithium isotope separation was performed using a laser isotope separation method. It was found that the lithium atoms with a natural isotopic abundance enhanced its /sup 6/Li concentration up to over 90% by tuning the laser wavelength to the /sup 2/Psub(1/2) of /sup 6/Li. Too high power, however, leads to a loss of enrichment due to the power broadening effect which was analysed by the equation of motion of density matrices.

  1. Systematic Measurements of the Bohr-Weisskopf Effect at ISOLDE

    CERN Multimedia


    Nuclear electric and magnetic structure properties are measurable by high-resolution atomic spectroscopy through isotope shifts and the Bohr-Weisskopf effect (hyperfine structure anomalies). \\\\ \\\\ The greatest value of these measurements is when made systematically over a large number of isotopes. This has been done in the case of isotopes shifts most extensively by the experiment at ISOLDE. To date the magnetic distribution studies are few and isolated. Here we propose to intitiate a program at ISOLDE to measure hfs anomalies systematically. The experiments, requiring high-precision data on magnetic dipole constants as well as on nuclear g-factors, will be done by atomic-beam magnetic resonance with the use of laser excitation for polarization of the beam and a sixpole magnet acting as an analyser. \\\\ \\\\ The heavy alkali elements are the most promising candidates for hfs anomaly studies because of the large effect expected, the high production yields at ISOLDE and most importantly, the interesting variations...

  2. Pb isotopes during crustal melting and magma mingling - A cautionary tale from the Miki Fjord macrodike, central east Greenland

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Lesher, Charles


    Pb isotopic data are presented for hybrid rocks formed by mingling between mantle-derived tholeiitic magma of the Eocene Miki Fjord macrodike (East Greenland) and melt derived from the adjacent Precambrian basement. Bulk mixing and AFC processes between end-members readily identified in the field...... fail to model the Pb isotope systematics. Selective contamination during diffusional exchange, which can explain the complex Sr and Nd isotope compositions of the hybrid rocks (Blichert-Toft et al., 1992), cannot fully account for the variability of the Pb isotopic data using the identified crustal end......-members. The crustal anatectic end-member, although similar in Sr and Nd isotope composition, has a markedly different Pb isotopic composition than its source gneiss. The differences are consistent with preferential incorporation of radiogenic Pb from accessory phases such as metamict zircon or loosely-bound Pb from...

  3. Pb isotopes during crustal melting and magma mingling - A cautionary tale from the Miki Fjord macrodike, central east Greenland

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Lesher, Charles


    Pb isotopic data are presented for hybrid rocks formed by mingling between mantle-derived tholeiitic magma of the Eocene Miki Fjord macrodike (East Greenland) and melt derived from the adjacent Precambrian basement. Bulk mixing and AFC processes between end-members readily identified in the field...... fail to model the Pb isotope systematics. Selective contamination during diffusional exchange, which can explain the complex Sr and Nd isotope compositions of the hybrid rocks (Blichert-Toft et al., 1992), cannot fully account for the variability of the Pb isotopic data using the identified crustal end......-members. The crustal anatectic end-member, although similar in Sr and Nd isotope composition, has a markedly different Pb isotopic composition than its source gneiss. The differences are consistent with preferential incorporation of radiogenic Pb from accessory phases such as metamict zircon or loosely-bound Pb from...

  4. Cold regions isotope applications

    Energy Technology Data Exchange (ETDEWEB)

    Perrigo, L.D.; Divine, T.E.


    Pacific Northwest Laboratories (PNL) started the Cold Regions Isotope Applications Program in FY-1975 to identify special conditions in the Arctic and similar geographic areas (Cold Regions) where radioisotope power, heater, or sterilization systems would be desirable and economically viable. Significant progress was made in the first year of this program and all objectives for this initial 12-month period were achieved. The major conclusions and recommendations resulting for this effort are described below. The areas of interest covered include: radiosterilization of sewage; heating of septic tanks; and radioisotope thermoelectric generators as power sources for meteorological instruments and navigational aids. (TFD)

  5. Controls on the stable isotope compositions of travertine from hyperalkaline springs in Oman: Insights from clumped isotope measurements (United States)

    Falk, E. S.; Guo, W.; Paukert, A. N.; Matter, J. M.; Mervine, E. M.; Kelemen, P. B.


    Carbonate formation at hyperalkaline springs is typical of serpentinization in peridotite massifs worldwide. These travertines have long been known to exhibit large variations in their carbon and oxygen isotope compositions, extending from apparent equilibrium values to highly depleted values. However, the exact causes of these variations are not well constrained. We analyzed a suite of well-characterized fresh carbonate precipitates and travertines associated with hyperalkaline springs in the peridotite section of the Samail ophiolite, Sultanate of Oman, and found their clumped isotope compositions vary systematically with formation environments. Based on these findings, we identified four main processes controlling the stable isotope compositions of these carbonates. These include hydroxylation of CO2, partial isotope equilibration of dissolved inorganic carbon, mixing between isotopically distinct carbonate end-members, and post-depositional recrystallization. Most notably, in fresh crystalline films on the surface of hyperalkaline springs and in some fresh carbonate precipitates from the bottom of hyperalkaline pools, we observed large enrichments in Δ47 (up to ∼0.2‰ above expected equilibrium values) which accompany depletions in δ18O and δ13C, yielding about 0.01‰ increase in Δ47 and 1.1‰ decrease in δ13C for every 1‰ decrease in δ18O, relative to expected equilibrium values. This disequilibrium trend, also reflected in preserved travertines ranging in age from modern to ∼40,000 years old, is interpreted to arise mainly from the isotope effects associated with the hydroxylation of CO2 in high-pH fluids and agrees with our first-order theoretical estimation. In addition, in some fresh carbonate precipitates from the bottom of hyperalkaline pools and in subsamples of one preserved travertine terrace, we observed additional enrichments in Δ47 at intermediate δ13C and δ18O, consistent with mixing between isotopically distinct carbonate end

  6. Do foraminifera accurately record seawater neodymium isotope composition? (United States)

    Scrivner, Adam; Skinner, Luke; Vance, Derek


    Palaeoclimate studies involving the reconstruction of past Atlantic meridional overturning circulation increasingly employ isotopes of neodymium (Nd), measured on a variety of sample media (Frank, 2002). In the open ocean, Nd isotopes are a conservative tracer of water mass mixing and are unaffected by biological and low-temperature fractionation processes (Piepgras and Wasserburg, 1987; Lacan and Jeandel, 2005). For decades, benthic foraminifera have been widely utilised in stable isotope and geochemical studies, but have only recently begun to be exploited as a widely distributed, high-resolution Nd isotope archive (Klevenz et al., 2008), potentially circumventing the difficulties associated with other methods used to recover past deep-water Nd isotopes (Klevenz et al., 2008; Rutberg et al., 2000; Tachikawa et al., 2004). Thus far, a single pilot study (Klevenz et al., 2008) has indicated that core-top sedimentary benthic foraminifera record a Nd isotope composition in agreement with the nearest available bottom seawater data, and has suggested that this archive is potentially useful on both millennial and million-year timescales. Here we present seawater and proximal core-top foraminifer Nd isotope data for samples recovered during the 2008 "RETRO" cruise of the Marion Dufresne. The foraminifer samples comprise a depth-transect spanning 3000m of the water column in the Angola Basin and permit a direct comparison between high-resolution water column and core-top foraminiferal Nd isotope data. We use these data to assess the reliability of both planktonic and benthic foraminifera as recorders of water column neodymium isotope composition. Frank, M., 2002. Radiogenic isotopes: Tracers of past ocean circulation and erosional input, Rev. Geophys., 40 (1), 1001, doi:10.1029/2000RG000094. Klevenz, V., Vance, D., Schmidt, D.N., and Mezger, K., 2008. Neodymium isotopes in benthic foraminifera: Core-top systematics and a down-core record from the Neogene south Atlantic

  7. Large-scale tectonic cycles in Europe revealed by distinct Pb isotope provinces (United States)

    Blichert-Toft, Janne; Delile, Hugo; Lee, Cin-Ty; Stos-Gale, Zofia; Billström, Kjell; Andersen, Tom; Hannu, Huhma; Albarède, Francis


    Lead isotopic systematics of U-poor minerals, such as sulfides and feldspars, can provide unique insights into the origin and evolution of continents because these minerals "freeze in" the Pb isotopic composition of the crust during major tectonothermal events, allowing the history of a continent to be told through Pb isotopes. Lead model ages constrain the timing of crust formation while time-integrated U/Pb, Th/Pb, and Th/U ratios shed light onto key geochemical processes associated with continent formation. Using ˜6800 Pb isotope measurements of primarily lead ores and minor K-feldspar, we mapped out the Pb isotope systematics across Europe and the Mediterranean. Lead model ages define spatially distinct age provinces, consistent with major tectonic events ranging from the Paleozoic to the Proterozoic and latest Archean. However, the regions defined by time-integrated U/Pb and Th/Pb ratios cut across the boundaries of age provinces, with high U/Pb systematics characterizing most of southern Europe. Magmatic influx, followed by segregation of dense sulfide-rich mafic cumulates, resulted in foundering of U- and Th-poor lower crust, thereby changing the bulk composition of the continental crust and leading to distinct time-integrated U-Th/Pb provinces. We show that the tectonic assembly of small crustal fragments leaves the crust largely undifferentiated, whereas the formation of supercontinents results in fundamental changes in the composition of the crust, identifiable in time and space by means of Pb isotope systematics. Observations based on Pb isotopes open up a new perspective on possible relationships between crustal thickness and geodynamic processes, in particular the role of crustal foundering into the mantle and the mechanisms responsible for the existence of cratons.

  8. Isotopic disproportionation during hydrogen isotopic analysis of nitrogen-bearing organic compounds (United States)

    Nair, Sreejesh; Geilmann, Heike; Coplen, Tyler B.; Qi, Haiping; Gehre, Matthias; Schimmelmann, Arndt; Brand, Willi A.


    Rationale High-precision hydrogen isotope ratio analysis of nitrogen-bearing organic materials using high-temperature conversion (HTC) techniques has proven troublesome in the past. Formation of reaction products other than molecular hydrogen (H2) has been suspected as a possible cause of incomplete H2 yield and hydrogen isotopic fractionation. Methods The classical HTC reactor setup and a modified version including elemental chromium, both operated at temperatures in excess of 1400 °C, have been compared using a selection of nitrogen-bearing organic compounds, including caffeine. A focus of the experiments was to avoid or suppress hydrogen cyanide (HCN) formation and to reach quantitative H2 yields. The technique also was optimized to provide acceptable sample throughput. Results The classical HTC reaction of a number of selected compounds exhibited H2 yields from 60 to 90 %. Yields close to 100 % were measured for the experiments with the chromium-enhanced reactor. The δ2H values also were substantially different between the two types of experiments. For the majority of the compounds studied, a highly significant relationship was observed between the amount of missing H2and the number of nitrogen atoms in the molecules, suggesting the pyrolytic formation of HCN as a byproduct. A similar linear relationship was found between the amount of missing H2 and the observed hydrogen isotopic result, reflecting isotopic fractionation. Conclusions The classical HTC technique to produce H2 from organic materials using high temperatures in the presence of glassy carbon is not suitable for nitrogen-bearing compounds. Adding chromium to the reaction zone improves the yield to 100 % in most cases. The initial formation of HCN is accompanied by a strong hydrogen isotope effect, with the observed hydrogen isotope results on H2 being substantially shifted to more negative δ2H values. The reaction can be understood as an initial disproportionation leading to H2 and HCN

  9. Interstellar sulfur isotopes and stellar oxygen burning

    CERN Document Server

    Chin, Y N; Whiteoak, J B; Langer, N; Churchwell, E B; Chin, Y N


    A 12C32S, 13C32S, 12C34S, and 12C33S J = 2 - 1 line survey has been made to study interstellar 32S/34S and 34S/33S ratios from the galactic disk. The four CS isotopomers were detected in 20 star forming regions with galactocentric distances between 3 and 9 kpc. From a comparison of line velocities, the C33S J = 2 - 1 rest frequency is about 250 kHz below the value given in the Lovas (1992) catalog. Taking 12C/13C ratios from Wilson & Rood (1994) and assuming equal 12C32S and 13C32S excitation temperatures and beam filling factors, 12C32S opacities are in the range 3 to 15; average 32S/34S and 34S/33S isotope ratios are 24.4 +/- 5.0 and 6.27 +/- 1.01, respectively. While no systematic variation in the 34S/33S isotope ratio is found, the 32S/34S ratio increases with galactocentric distance when accounting for the 12C/13C gradient of the galactic disk. A fit to the unweighted data yields 32S/34S = 3.3 +/- 0.5 (dGC/kpc) + 4.1 +/- 3.1 with a correlation coefficient of 0.84. Since the interstellar sulfur (S) is...

  10. Si Isotopes of Brownleeite (United States)

    Nakamura-Messenger, K.; Messenger, Scott R.; Ito, M.; Keller, L. P.; Clemett, S. J.; Jones, J. H.; Tatsuoka, H.; Zolensky, M. E.; Tatsuoka, H.


    Brownleeite is a manganese silicide, ideally stoichiometric MnSi, not previously observed in nature until its discovery within an interplanetary dust particle (IDP) that likely originated from a comet [1]. Three discrete brownleeite grains in the IDP L2055 I3 (4 microns in size, hereafter IDP I3) were identified with maximum dimensions of 100, 250 and 600 nm and fully analyzed using scanning-transmission electron microscopy (STEM) [1]. One of the grains (100 nm in size) was poikilitically enclosed by low-Fe, Mn-enriched (LIME) olivine. LIME olivine is epitaxial to the brownleeite with the brownleeite (200) parallel to the olivine c* [1]. LIME olivine is an enigmatic phase first reported from chondritic porous IDPs and some unequilibrated ordinary chondrites [ 2], that is commonly observed in chondritic-porous IDPs. Recently, LIME olivine has been also found in comet Wild-2 (Stardust) samples [3], indicating that LIME olivine is a common mineral component of comets. LIME olivine has been proposed to form as a high temperature condensate in the protosolar nebula [2]. Brownleeite grains also likely formed as high-temperature condensates either in the early Solar System or in the outflow of an evolved star or supernova explosion [1]. The isotopic composition of the brownleeite grains may strongly constrain their ultimate source. To test this hypothesis, we performed isotopic analyses of the brownleeite and the associated LIME olivine, using the NASA/JSC NanoSIMS 50L ion microprobe.

  11. Oxygen and Chlorine Isotopic Fractionation During Microbial Reduction of Perchlorate (United States)

    Beloso, A. D.; Sturchio, N. C.; Böhlke, J. K.; Streger, S. H.; Heraty, L. J.; Hatzinger, P. B.


    Perchlorate is a widespread environmental contaminant that has both anthropogenic and natural sources. Stable isotope ratios of O and Cl in perchlorate have been used recently to distinguish perchlorate of different origins. Isotopic ratios may also be useful for identifying the occurrence and extent of biodegradation of perchlorate in natural environments, information that is critical for assessing natural attenuation of this contaminant. For this approach to be useful, however, the extent of isotopic fractionation of both Cl and O by bacteria must be determined, and the influence of environmental variables on this process must be defined. During this laboratory study, the O and Cl isotope ratios of perchlorate were monitored as a function of degradation by two separate bacterial species (Azospira suillum JPLRND and Dechlorospirillum sp. FBR2) at both 10 °C and 22 °C with acetate as the electron donor. Perchlorate was completely degraded by both strains within 280 hr at 22 °C and 615 hr at 10 °C. Measured values of isotopic fractionation factors were ɛ18O = -36.6 to -29.0 ‰ and ɛ37Cl = -14.5 to - 11.5 ‰, and these showed no apparent systematic variation with either temperature or bacterial strain. One experiment using 18O-enriched water (δ18O = 200‰) gave results indistinguishable from those observed in isotopically normal water, indicating little or no isotopic exchange between perchlorate and water during biodegradation. The fractionation factor ratio ɛ18O/ɛ37Cl was nearly invariant in all experiments at 2.50 ± 0.04. These data indicate that isotopic analysis will be useful for documenting perchlorate biodegradation in soils and groundwater. The establishment of a microbial fractionation factor ratio (ɛ18O/ɛ37Cl) also has significance for forensic studies, as these data indicate that fractionation via biodegradation will not cause the reported mass-dependent Cl and O isotopic signatures of synthetic and natural perchlorate to overlap.

  12. Titanium stable isotopic variations in chondrites, achondrites and lunar rocks (United States)

    Greber, Nicolas D.; Dauphas, Nicolas; Puchtel, Igor S.; Hofmann, Beda A.; Arndt, Nicholas T.


    Titanium isotopes are potential tracers of processes of evaporation/condensation in the solar nebula and magmatic differentiation in planetary bodies. To gain new insights into the processes that control Ti isotopic variations in planetary materials, 25 komatiites, 15 chondrites, 11 HED-clan meteorites, 5 angrites, 6 aubrites, a martian shergottite, and a KREEP-rich impact melt breccia have been analyzed for their mass-dependent Ti isotopic compositions, presented using the δ49Ti notation (deviation in permil of the 49Ti/47Ti ratio relative to the OL-Ti standard). No significant variation in δ49Ti is found among ordinary, enstatite, and carbonaceous chondrites, and the average chondritic δ49Ti value of +0.004 ± 0.010‰ is in excellent agreement with the published estimate for the bulk silicate Earth, the Moon, Mars, and the HED and angrite parent-bodies. The average δ49Ti value of komatiites of -0.001 ± 0.019‰ is also identical to that of the bulk silicate Earth and chondrites. OL-Ti has a Ti isotopic composition that is indistinguishable from chondrites and is therefore a suitable material for reporting δ49Ti values. Previously published isotope data on another highly refractory element, Ca, show measurable variations among chondrites. The decoupling between Ca and Ti isotope systematics most likely occurred during condensation in the solar nebula. Aubrites exhibit significant variations in δ49Ti, from -0.07 to +0.24‰. This is likely due to the uniquely reducing conditions under which the aubrite parent-body differentiated, allowing chalcophile Ti3+ and lithophile Ti4+ to co-exist. Consequently, the observed negative correlation between δ49Ti values and MgO concentrations among aubrites is interpreted to be the result of isotope fractionation driven by the different oxidation states of Ti in this environment, such that isotopically heavy Ti4+ was concentrated in the residual liquid during magmatic differentiation. Finally, KREEPy impact melt breccia

  13. Zircon U-Pb age and Hf isotopic systematics of Late Paleozoic volcanic from the western margin of east Junggar and tectonic implication%东准噶尔西缘晚古生代火山岩的锆石U-Pb年龄和Hf同位素特征及构造意义

    Institute of Scientific and Technical Information of China (English)

    史基安; 唐相路; 张顺存; 张宏福; 肖燕


    Two sections,namely Baijiangou and Zhangpenggo,in the western margin of east Junggar, where expose a large number of Paleozoic volcanic rocks, are the favorable areas to study the tectonic evolution of the east Junggar. LA-MC-ICP-MS zircon U-Pb dating and Hf isotopic systematics study of igneous rocks( basalt,basaltic andesite,rhyolite and keratophyre with minor tuff and syenite-porphyry) , using geochrony technology, suggests that they were formed during Early Devonian to Late Carboniferous (400 ~ 307 Ma). Basalts and basaltic andesites are more likely output as dikes, and they display age-range from 435 Ma to 300 Ma and show positive em(t) values(+0. 7 ~ +15.4) , which suggests that the east Junggar terrane is controled by juvenile crust and that the Precambrian crystalline rocks must be very limited, if there is any. The Zhangpenggou rhyolite and keratophyre, zircon U-Pb ages of 332 Ma and 336 Ma respectively, were formed in a volcanic arc environment or a environment which was mixed with part of island arc. The Baijiangou syenite-porphyries with positive sa((t) values in Late Carboniferous( 307 Ma and 315 Ma) indicate a vertical accretion of crustal materials. The Baijiangou rhyolites which show positive sH[(t) values and zircon U-Pb ages of 315 Ma and 323 Ma suggests a lateral accretion of crustal materials. Therefore, the east Junggar is mainly accretionary prism undering extensional settings of post-collisional period, and it's considered today to be a Paleozoic Mariana-type intra-oceanic island arc.%白碱沟和帐篷沟剖面位于东准噶尔西缘,出露有大量古生代火山岩,是研究东准噶尔古生代火山岩及构造演化的有利区域.本文利用LA-MC-ICP-MS锆石U-Pb定年法和Hf同位素系统对该区中的玄武岩、玄武质安山岩、流纹岩、角斑岩以及少量的凝灰岩和正长斑岩进行了地质年代学研究,认为它们形成于早泥盆世至晚石炭世之间(400~307 Ma).玄武岩和玄武质安山岩

  14. Isotope and fluid inclusion studies of geological and hydrothermal processes, northern Peru

    Energy Technology Data Exchange (ETDEWEB)

    MacFarlane, A.W. [Florida International Univ., Miami, FL (United States); Prol-Ledesma, R.M. [Cd. Universitaria, Coyoacan (Mexico); Conrad, M.E. [Lawrence Berkeley Lab., CA (United States)


    Mineralization in the Hualgayoc district of northern Peru occurs in altered Miocene felsic intrusions and in mid-Cretaceous platform sedimentary rocks of the Goyllarisquizga, Inca, and Chulec formations. The ores occur both as stratiform and stratabound pyritiferous base-metal deposits (mantos), and as steeply dipping, sedimentary and intrusive rock-hosted base-metal veins. Igneous rocks in the district are affected by propylytic, sericitic-argillic, sericitic, potassic, and acid-sulfate alteration. K-Ar and Rb-Sr dating and geological evidence indicate multiple stages of intrusive activity and hydrothermal alteration, including close spatial emplacement of two or more separate Miocene magmatic-hydrothermal systems. K-Ar dates on sericite, hydrothermal biotite, and alunite indicate that the most important hydrothermal episodes in the district took place {approx}13.24 and 12.4 Ma. Other K-Ar dates on altered rocks in the district may reflect various amounts of resetting by the emplacement of the 9.05 {+-} 0.2 Ma Hualgayoc rhyodacite. A five-point Rb-Sr isochron for the San Miguel intrusion at Cerro Coymolache yields an age of 45 {+-} 3.4 Ma, which indicates much earlier magmatic activity in this area than recognized previously. Fluid inclusion and paragenetic studies reveal a clear temporal evolution of fluid temperature and chemistry in the San Agustin area at Hualgayoc. Gradually, ore formation shifted to precipitation of vein minerals in the brittle fractures as the mantos became less permeable and were sealed off. Vein formation continued from progressively cooler and more diluted fluids (down to {approx}150{degrees}C and 4.3 wt% NaCl equivalent) as the system waned. No evidence for phase separation is observed in the fluids until the very last paragenetic stage, which contributed no economic mineralization. 53 refs., 15 figs., 7 tabs.

  15. Natural variations in the rhenium isotopic composition of meteorites (United States)

    Liu, R.; Hu, L.; Humayun, M.


    Rhenium is an important element with which to test hypotheses of isotope variation. Historically, it has been difficult to precisely correct the instrumental mass bias in thermal ionization mass spectrometry. We used W as an internal standard to correct mass bias on the MC-ICP-MS, and obtained the first precise δ187Re values ( ±0.02‰, 2SE) for iron meteorites and chondritic metal. Relative to metal from H chondrites, IVB irons are systematically higher in δ187Re by 0.14 ‰. δ187Re for other irons are similar to H chondritic metal, although some individual samples show significant isotope fractionation. Since 185Re has a high neutron capture cross section, the effect of galactic cosmic-ray (GCR) irradiation on δ187Re was examined using correlations with Pt isotopes. The pre-GCR irradiation δ187Re for IVB irons is lower, but the difference in δ187Re between IVB irons and other meteoritic metal remains. Nuclear volume-dependent fractionation for Re is about the right magnitude near the melting point of iron, but because of the refractory and compatible character of Re, a compelling explanation in terms of mass-dependent fractionation is elusive. The magnitude of a nucleosynthetic s-process deficit for Re estimated from Mo and Ru isotopes is essentially unresolvable. Since thermal processing reduced nucleosynthetic effects in Pd, it is conceivable that Re isotopic variations larger than those in Mo and Ru may be present in IVBs since Re is more refractory than Mo and Ru. Thus, the Re isotopic difference between IVBs and other irons or chondritic metal remains unexplained.

  16. Competition from Isotopic Modelling

    Directory of Open Access Journals (Sweden)

    Virginie Fabre


    Full Text Available During later MOIS3, in Europe two populations were present, autochthonous Neanderthals and modern humans. Ecological competition between these two populations has often been evoked but never demonstrated. Our aim is to establish whether resource competition occurred. In this paper, in order to examine the possibility of ecological competition between these two populations, 599 isotopic data were subjected to rigorous statistical treatment and analysis through mixing models. The aim of this paper was to compare dietary strategies of Neanderthals and modern humans over time. Our conclusions suggest that Neanderthals and modern humans shared dietary habits in the particular environmental context of MOIS3 characterised in Europe by climatic deterioration. In this environmental context, the resource competition between Neanderthals and modern humans may have accelerated the disappearance of the Neanderthal population.

  17. Magnesium Isotopic Composition of Subducting Marine Sediments (United States)

    Hu, Y.; Teng, F. Z.; Plank, T. A.; Huang, K. J.


    Subducted marine sediments have recently been called upon to explain the heterogeneous Mg isotopic composition (δ26Mg, ‰) found in mantle wehrlites (-0.39 to +0.09 [1]) in the context of a homogeneous mantle (-0.25 ± 0.07 [2]). However, no systematic measurements of δ26Mg on marine sediments are currently available to provide direct support to this model. To characterize the Mg inputs to global subduction zones, we measured δ26Mg data for a total of 90 marine sediments collected from 12 drill sites outboard of the world's major subduction zones. These sediments span a 1.73‰ range in δ26Mg. The detritus-dominated sediments have δ26Mg (-0.59 to +0.53) comparable to those of weathered materials on continents (e.g. -0.52 to +0.92 [3]), while the calcareous oozes yield δ26Mg (as light as -1.20) more similar to the seawater value (-0.83 [4]). The negative correlation between δ26Mg and CaO/Al2O3 in these sediments indicates the primary control of mineralogy over the Mg isotopic distribution among different sediment types, as carbonates are enriched in light Mg isotopes (-5.10 to -0.40 [5]) whereas clay-rich weathering residues generally have heavier δ26Mg (e.g. up to +0.65 in saprolite [6]). In addition, chemical weathering and grain-size sorting drive sediments to a heavier δ26Mg, as indicated by the broad positive trends between δ26Mg with CIA (Chemical Index of Alteration [7]) and Al2O3/SiO2, respectively. Collectively, the arc systems sampled in this study represent ~30% of global arc length and the extrapolated global Mg flux of subducting marine sediments accounts for ~9% of the yearly Mg riverine input with a flux-weighted average δ26Mg at -0.26. Subduction of these heterogeneous sediments may not cause significant mantle heterogeneity on a global scale, but the highly variable Mg fluxes and δ26Mg of sediments delivered to different trenches are capable of producing local mantle variations. Volcanic rocks sourced from these mantle domains are thus

  18. Alkali elemental and potassium isotopic compositions of Semarkona chondrules (United States)

    Alexander, C.M. O'D.; Grossman, J.N.


    We report measurements of K isotope ratios in 28 Semarkona chondrules with a wide range of petrologic types and bulk compositions as well as the compositions of CPX-mesostasis pairs in 17 type I Semarkona chondrules, including two chondrules with radial alkali zonation and 19 type II chondrules. Despite the wide range in K/Al ratios, no systematic variations in K isotopic compositions were found. Semarkona chondrules do not record a simple history of Rayleigh-type loss of K. Experimentally determined evaporation rates suggest that considerable alkali evaporation would have occurred during chondrule formation. Nevertheless, based on Na CPX-mesostasis distribution coefficients, the alkali contents of the cores of most chondrules in Semarkona were probably established at the time of final crystallization. However, Na CPX-mesostasis distribution coefficients also show that alkali zonation in type I Semarkona chondrules was produced by entry of alkalis after solidification, probably during parent body alteration. This alkali metasomatism may have gone to completion in some chondrules. Our preferred explanation for the lack of systematic isotopic enrichments, even in alkali depleted type I chondrule cores, is that they exchanged with the ambient gas as they cooled. ?? The Meteoritical Society, 2005.

  19. On the isotopic composition of magmatic carbon in SNC meteorites (United States)

    Wright, I. P.; Grady, M. M.; Pillinger, C. T.


    SNC meteorites are thought, from many lines of evidence, to come from Mars. A line of investigation which has been pursued in our laboratory over the years involves measurement of the stable isotopic composition of carbon, in its various forms, in SNC meteorites. In order to establish a firm basis for studying the isotopic systematics of carbon in the martian surface environment, it is first necessary to try and constrain the delta C-13 of bulk Mars. Taking all of the available information, it would seem that the delta C-13 of the Earth's mantle lies somewhere in the range of -5 to -7 percent. Preliminary assessment of magnetic carbon in SNC meteorites, would tend to suggest a delta C-13 of 20 to 30 percent, which is conspicuously different from that of the terrestrial mantle. It is not obvious why there should be such a difference between the two planets, although many explanations are possible. One of these possibilities, that previous delta C-13 measurements for magnetic carbon in SNC meteorites are in error to some degree, is being actively investigated. The most recent results seem to constrain the theta C-13 of the magnetic carbon in SNC meteorites to about -20 percent, which is not at odds with previous estimates. As such, it is considered that a detailed investigation of the carbon isotopic systematics of martian surface materials does have the necessary information with which to proceed.

  20. Isotope geochemistry of the Amazon Basin: A reconnaissance

    Energy Technology Data Exchange (ETDEWEB)

    Longinelli, A.; Edmond, J.M.


    On the transects of the Amazon River made by the Alpha Helix in 1976 and 1977, an extensive suite of samples was collected for isotopic analyses. The water isotopes (/sup 18/O//sup 16/O, D/H) were determined in atmospheric water vapour and in river, rain, and leaf waters. /sup 13/C//sup 12/C ratios were measured in the dissolved and atmospheric CO/sub 2/. Determinations were made of /sup 34/S//sup 32/S and oxygen isotopes in dissolved sulphate. The effect of 'continentality' on the water isotopes is minor reflecting the large scale recycling by evapotranspiration from the huge area of forest within the basin. Variations in the isotopic abundances between 1976 (June--July, dry season) and 1977 (May--June, end of wet season) are consistent with the changes in meteorological conditions. The isotopic composition of the CO/sub 2/, both atmospheric and dissolved, is dominated by biological effects. In 1976 the dissolved CO/sub 2/ showed downstream variations from -14X at Iquitos in Peru to -22X in the lower reaches. In 1977, no systematic trend was apparent, the data ranging around -19X. The values for atmospheric CO/sub 2/ decrease inland from marine values at the mouth to around -15X at Manaus. During the dry season (1976) the values in the interior, western basin were homogeneous at -20X. In the wet season there were considerable variations reflecting atmospheric instabilities with the average value being about -13X. The sulphur isotopic composition of the dissolved sulphate is remarkably uniform at around 7X. In 1977 the /sup 18/O values in the sulphate decreased systematically downstream from 8X in Peru to 3X at the mouth, consistent with a progressive redox-mediated exchange with water and dissolved oxygen. In 1977 the values increased to over 11X, apparently indicating exchange with a highly fractionated reservoir of dissolved oxygen perhaps in the semireducing environment of the flood plain lakes.

  1. Isotope evidence for N2-fixation in Sphagnum peat bogs (United States)

    Novak, Martin; Jackova, Ivana; Buzek, Frantisek; Stepanova, Marketa; Veselovsky, Frantisek; Curik, Jan; Prechova, Eva


    Waterlogged organic soils store as much as 30 % of the world's soil carbon (C), and 15 % of the world's soil nitrogen (N). In the era of climate change, wetlands are vulnerable to increasing temperatures and prolonged periods of low rainfall. Higher rates of microbial processes and/or changing availability of oxygen may lead to peat thinning and elevated emissions of greenhouse gases (mostly CO2, but also CH4 and N2O). Biogeochemical cycling of C and N in peat bogs is coupled. Under low levels of pollution by reactive nitrogen (NO3-, NH4+), increasing N inputs may positively affect C storage in peat. Recent studies in North America and Scandinavia have suggested that pristine bogs are characterized by significant rates of microbial N2 fixation that augments C storage in the peat substrate. We present a nitrogen isotope study aimed at corroborating these findings. We conducted an isotope inventory of N fluxes and pools at two Sphagnum-dominated ombrotrophic peat bogs in the Czech Republic (Central Europe). For the first time, we present a time-series of del15N values of atmospheric input at the same locations as del15N values of living Sphagnum and peat. The mean del15N values systematically increased in the order: input NH4+ (-10.0 ‰) < input NO3- (-7.9 ‰) < peat porewater (-5.6 ‰) < Sphagnum (-5.0 ‰) < shallow peat (-4.2 ‰) < deep peat (-2.2 ‰) < runoff (-1.4 ‰) < porewater N2O (1.4 ‰). Importantly, N of Sphagnum was isotopically heavier than N of the atmospheric input (p < 0.001). If partial incorporation of reactive N from the atmosphere into Sphagnum was isotopically selective, the residual N would have to be isotopically extremely light. Such N, however, was not identified anywhere in the ecosystem. Alternatively, Sphagnum may have contained an admixture of isotopically heavier N from atmospheric N2 (del15N N2 = 0 ‰). We conlude that the N isotope systematics at the two Czech sites is consistent with the concept of significant N2 fixation

  2. Isotope Effects in ESR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Werner Herrmann


    Full Text Available In order to present the relationship between ESR spectroscopy and isotope effects three levels are considered: (i ESR spectroscopy is described on a general level up to the models for interpretation of the experimental spectra, which go beyond the usually used time and mass independent spin-Hamilton operator, (ii the main characteristics of the generalized isotope effects are worked out, and finally (iii the basic, mainly quantum mechanical effects are used to describe the coupling of electron spins with the degrees of freedom, which are accessible under the selected conditions, of the respective paramagnetic object under investigation. The ESR parameters and the respective models are formalized so far, that they include the time and mass depending influences and reflect the specific isotope effects. Relations will be established between the effects in ESR spectra to spin relaxation, to spin exchange, to the magnetic isotope effect, to the Jahn-Teller effects, as well as to the influence of zero-point vibrations. Examples will be presented which demonstrate the influence of isotopes as well as the kind of accessible information. It will be differentiated with respect to isotope effects in paramagnetic centres itself and in the respective matrices up to the technique of ESR imaging. It is shown that the use of isotope effects is indispensable in ESR spectroscopy.

  3. F-rich strongly peraluminous A-type magmatism in the pre-Andean foreland Sierras Pampeanas, Argentina: Geochemical, geochronological, isotopic constraints and petrogenesis (United States)

    Morales Cámera, Matías M.; Dahlquist, Juan A.; Basei, Miguel A. S.; Galindo, Carmen; da Costa Campos Neto, Mario; Facetti, Nicolás


    The petrogenetic nature of A-type granites is a controversial problem. The Vinquis batholith in the Sierras Pampeanas of Argentina contains unusual F-rich and strongly peraluminous A-type monzogranites. A new LA-MC-ICP-MS U-Pb zircon crystallization age of 355 ± 7 Ma indicates emplacement in latest Devonian or earliest Carboniferous time, overlapping with extensive metaluminous A-type magmatism in the area. The monzogranites have a restricted range of SiO2 content (71.5-74.8 %), they are poor in Ca (0.54-1.4% CaO) and rich in FeOt, with relatively high FeOt/(FeOt+MgO) values ranging from 0.77 to 0.86 (average = 0.80) Both [FeOt/ (FeOt+MgO)] vs. SiO2 and [(Na2O+K2O)-CaO] vs. SiO2 plots indicate ferroan and alkali-calcic signatures typical of A-type granitoids. The samples have MgO/TiO2 > 1.2 and are moderately enriched in total alkalis (average 8.18%), with high K2O/Na2O values of 1.40-2.24. The granites are strongly peraluminous, with ASI (molar Al2O3/[CaO + Na2O + K2O]) values of 1.2 to 1.3. The high P2O5 content (0.23-0.37%) is distinctive and close to values reported for other Paleozoic F-rich peraluminous A-type granites in the Sierras Pampeanas. They have moderate contents of high field strength elements (e.g., Zr, Nb, Th, Y, etc.) and moderately fractionated to flat REE patterns [(La/Yb)N in the range 4.8-19.6] showing significant negative Eu anomalies (Eu/Eu* = 0.41). Biotite has a distinctive composition, with relatively high Fe2 +/(Fe2 + + Mg) ratios (0.61-0.74) and high F (0.55-1.42 wt.%) content. Together with the whole-rock chemistry this may be useful in identifying strongly peraluminous A-type granites. In addition, the Rb/Sr vs. Th + Zr + Ce diagram may be an appropriate discriminant between metaluminous and peralkaline A-type granites, strongly peraluminous A-type granites and strongly peraluminous orogenic granites. The geochemical evidence indicates that differentiation of the granitic rocks occurred by mineral fractionation from a F

  4. Reconstructing fluid-flow events in Lower-Triassic sandstones of the eastern Paris Basin by elemental tracing and isotopic dating of nanometric illite crystals (United States)

    Blaise, Thomas; Clauer, Norbert; Cathelineau, Michel; Boiron, Marie-Christine; Techer, Isabelle; Boulvais, Philippe


    Lower- to Middle-Triassic sandstones from eastern Paris Basin were buried to a maximum depth of 2500 m at a paleo-temperature of about 100 °C. They contain extensive amounts of authigenic platy and filamentous illite particles similar to those reported in reservoirs generally buried at 3000 to -5000 m and subjected to temperatures of 120 to -150 °C. To evaluate this unexpected occurrence, such sandstones were collected from drill cores between 1825 and 2000 m depth, and nanometric-sized sub-fractions were separated. The illite crystals were identified by XRD, observed by SEM and TEM, analyzed for their major, trace, rare-earth elements and oxygen isotope compositions, and dated by K-Ar and Rb-Sr. Illite particles display varied growth features in the rock pore-space and on authigenic quartz and adularia that they postdate. TEM-EDS crystal-chemical in situ data show that the illite lath/fiber and platelet morphologies correspond at least to two populations with varied interlayer charges: between 0.7 and 0.9 for the former and between 0.8 and 1.0 for the latter, the Fe/Fe + Mg ratio being higher in the platelets. Except for the deeper conglomerate, the PAAS-normalized REE patterns of the illite crystals are bell-shaped, enriched in middle REEs. Ca-carbonates and Ca-phosphates were detected together with illite in the separates. These soluble components yield 87Sr/86Sr ratios that are not strictly in chemical equilibrium with the illite crystals, suggesting successive fluids flows with different chemical compositions. The K-Ar data of finer <0.05 μm illite separates confirm two crystallization events at 179.4 ± 4.5 and 149.4 ± 2.5 Ma during the Early and Late Jurassic. The slightly coarser fractions contain also earlier crystallized or detrital K-bearing minerals characterized by lower δ18O values. The δ18O of the finest authigenic illite separates tends to decrease slightly with depth, from 18.2 (±0.2) to 16.3 (±0.2)‰, suggesting different but

  5. Single-molecule fluorescence autocorrelation experiments on pentacene : The dependence of intersystem crossing on isotopic composition

    NARCIS (Netherlands)

    Brouwer, A.C.J.; Köhler, J.; Oijen, A.M. van; Groenen, E.J.J.; Schmidt, J.


    Single pentacene molecules containing 13C or 1H in a pentacene-d14 doped p-terphenyl crystal have been studied by fluorescence autocorrelation. The triplet dynamics has been analyzed and a systematic dependence of the S1→T1 intersystem crossing rate on isotopic composition was found. This variation

  6. Radii and Binding Energies in Oxygen Isotopes: A Challenge for Nuclear Forces. (United States)

    Lapoux, V; Somà, V; Barbieri, C; Hergert, H; Holt, J D; Stroberg, S R


    We present a systematic study of both nuclear radii and binding energies in (even) oxygen isotopes from the valley of stability to the neutron drip line. Both charge and matter radii are compared to state-of-the-art ab initio calculations along with binding energy systematics. Experimental matter radii are obtained through a complete evaluation of the available elastic proton scattering data of oxygen isotopes. We show that, in spite of a good reproduction of binding energies, ab initio calculations with conventional nuclear interactions derived within chiral effective field theory fail to provide a realistic description of charge and matter radii. A novel version of two- and three-nucleon forces leads to considerable improvement of the simultaneous description of the three observables for stable isotopes but shows deficiencies for the most neutron-rich systems. Thus, crucial challenges related to the development of nuclear interactions remain.

  7. Experimental determination of isotope enrichment factors – bias from mass removal by repetitive sampling

    DEFF Research Database (Denmark)

    Buchner, Daniel; Jin, Biao; Ebert, Karin


    Application of compound-specific stable isotope approaches often involves comparisons of isotope enrichment factors (ε). Experimental determination of ε-values is based on the Rayleigh equation, which relates the change in measured isotope ratios to the decreasing substrate fractions and is valid...... to account for mass removal and for volatilization into the headspace. In this study we use both synthetic and experimental data to demonstrate that the determination of ε-values according to current correction methods is prone to considerable systematic errors even in well-designed experimental setups....... In response, we present novel, adequate methods to eliminate systematic errors in data evaluation. A model-based sensitivity analysis serves to reveal the most crucial experimental parameters and can be used for future experimental design to obtain correct ε-values allowing mechanistic interpretations....

  8. Radii and binding energies in oxygen isotopes: a puzzle for nuclear forces

    CERN Document Server

    Lapoux, V; Barbieri, C; Hergert, H; Holt, J D; Stroberg, R


    We present a systematic study of both nuclear radii and binding energies in (even) oxygen isotopes from the valley of stability to the neutron drip line. Both charge and matter radii are compared to state-of-the-art {\\it ab initio} calculations along with binding energy systematics. Experimental matter radii are obtained through a complete evaluation of the available elastic proton scattering data of oxygen isotopes. We show that, in spite of a good reproduction of binding energies, {\\it ab initio} calculations with conventional nuclear interactions derived within chiral effective field theory fail to provide a realistic description of charge and matter radii. A novel version of two- and three-nucleon forces leads to considerable improvement of the simultaneous description of the three observables for stable isotopes, but shows deficiencies for the most neutron-rich systems. Thus, crucial challenges related to the development of nuclear interactions remain.

  9. The early bird gets the shrimp: Confronting assumptions of isotopic equilibrium and homogeneity in a wild bird population (United States)

    Wunder, Michael B.; Jehl, Joseph R.; Stricker, Craig A.


    1. Because stable isotope distributions in organic material vary systematically across energy gradients that exist in ecosystems, community and population structures, and in individual physiological systems, isotope values in animal tissues have helped address a broad range of questions in animal ecology. It follows that every tissue sample provides an isotopic profile that can be used to study dietary or movement histories of individual animals. Interpretations of these profiles depend on the assumption that metabolic pools are isotopically well mixed and in equilibrium with dietary resources prior to tissue synthesis, and they extend to the population level by assuming isotope profiles are identically distributed for animals using the same proximal dietary resource. As these assumptions are never fully met, studying structure in the variance of tissue isotope values from wild populations is informative. 2. We studied variation in δ13C, δ15N, δ2H and δ18O data for feathers from a population of eared grebes (Podiceps nigricollis) that migrate to Great Salt Lake each fall to moult feathers. During this time, they cannot fly and feed almost exclusively on superabundant brine shrimp (Artemia franciscana). The ecological simplicity of this situation minimized the usual spatial and trophic complexities often present in natural studies of feather isotope values. 3. Ranges and variances of isotope values for the feathers were larger than those from previously published studies that report feather isotopic variance, but they were bimodally distributed in all isotope dimensions. Isotope values for proximal dietary resources and local surface water show that some of the feathers we assumed to have been grown locally must have been grown before birds reached isotopic equilibrium with local diet or immediately prior to arrival at Great Salt Lake. 4. Our study provides novel insights about resource use strategies in eared grebes during migration. More generally, it

  10. Rb-Sr Geochronology and Geochemical Characteristics of Mafic Dikes in the Nova Lacerda and Conquista D´Oeste Region, Mato Grosso, SW Amazonian Craton

    Directory of Open Access Journals (Sweden)

    Amarildo Salina Ruiz


    Full Text Available In the Nova Lacerda and Conquista D’Oeste regions, Mato Grosso State, SW part of the Amazonian Craton, mafi c dikestrending NNW intrude the Nova Lacerda Granite (1462 ± 12 Ma, within the Jauru Domain, in the Rondonia-San IgnacioProvince (1.55 - 1.3 Ga. The mafi c swarm comprises diabases, metadiabases and amphibolites. Metadiabases originatedfrom uralitization of diabases. These rocks have tholeiitic affi nity and predominant basaltic composition. Some samples are andesi-basalts. The ages of diabases and metabasites are 1380 ± 32 Ma and 1330 ± 120 Ma respectively. Geochemical data indicate that the compositional variation of diabases and metadiadases is due to fractional crystallization of evolved tholeiitic magmas. The origin of the basaltic magmas is related to a heterogeneous mantle source.

  11. Geology, mineralization, Rb-Sr & Sm-Nd geochemistry, and U–Pb zircon geochronology of Kalateh Ahani Cretaceous intrusive rocks, southeast Gonabad

    Directory of Open Access Journals (Sweden)

    Mohammad Hassan Karimpour


    Full Text Available Kalateh Ahani is located 27 km southeast of Gonabad within the Khorasan Razavi province. The area is part of Lut Block. Sub-volcanic monzonitic rocks intruded regional metamorphosed Shemshak Formation (Jurassic age. Magnetic susceptibility of less altered monzonitic rocks is 0.6%., As, Pb and Zn > 1%, Au up to 150 ppb and Sn = 133 ppm. The Sn content of vein in the northern part of Kalateh Ahani (Rud Gaz is > 1%. Based on mineralization, alteration and geochemistry, it seems that Sn mineralization is associated with the Cretaceous monzonitic rocks. Zircon U–Pb dating indicates that the age of the monzonitic rocks associated with mineralization is 109 Ma (Lower Cretaceous. Based on (87Sr/86Sri = 0.71089-0.710647 and (143Nd/144Ndi = 0.512113-0.51227 of the monzonitic rocks, the magma for these rocks were originated from the continental crust. This research has opened new window with respect to Sn-Cu mineralization and exploration within the Lut Block which is associated with Cretaceous granitoid rocks (reduced type, ilmenite series originated from the continental crust.

  12. Isotope-edited infrared spectroscopy. (United States)

    Buchner, Ginka S; Kubelka, Jan


    Isotope-edited infrared (IR) spectroscopy is a powerful tool for studying structural and dynamical properties of peptides and proteins with site-specific resolution. Labeling of selected amide carbonyls with (13)C results in detectable sidebands of amide I' vibrations, which provide information about local conformation and/or solvent exposure without structural perturbation to the protein. Incorporation of isotopically labeled amino acids at specific positions is achieved by the chemical synthesis of the studied proteins. We describe the basic procedures for synthesis of (13)C isotopically edited protein samples, experimental IR spectroscopic measurements, and analysis of the site-specific structural changes from the thermal unfolding IR data.

  13. Compelling Research Opportunities using Isotopes

    Energy Technology Data Exchange (ETDEWEB)



    Isotopes are vital to the science and technology base of the US economy. Isotopes, both stable and radioactive, are essential tools in the growing science, technology, engineering, and health enterprises of the 21st century. The scientific discoveries and associated advances made as a result of the availability of isotopes today span widely from medicine to biology, physics, chemistry, and a broad range of applications in environmental and material sciences. Isotope issues have become crucial aspects of homeland security. Isotopes are utilized in new resource development, in energy from bio-fuels, petrochemical and nuclear fuels, in drug discovery, health care therapies and diagnostics, in nutrition, in agriculture, and in many other areas. The development and production of isotope products unavailable or difficult to get commercially have been most recently the responsibility of the Department of Energy's Nuclear Energy program. The President's FY09 Budget request proposed the transfer of the Isotope Production program to the Department of Energy's Office of Science in Nuclear Physics and to rename it the National Isotope Production and Application program (NIPA). The transfer has now taken place with the signing of the 2009 appropriations bill. In preparation for this, the Nuclear Science Advisory Committee (NSAC) was requested to establish a standing subcommittee, the NSAC Isotope Subcommittee (NSACI), to advise the DOE Office of Nuclear Physics. The request came in the form of two charges: one, on setting research priorities in the short term for the most compelling opportunities from the vast array of disciplines that develop and use isotopes and two, on making a long term strategic plan for the NIPA program. This is the final report to address charge 1. NSACI membership is comprised of experts from the diverse research communities, industry, production, and homeland security. NSACI discussed research opportunities divided into three areas: (1

  14. Carbon isotope geochemistry and geobiology (United States)

    Desmarais, D.


    Carbon isotope fractionation values were used to understand the history of the biosphere. For example, plankton analyses confirmed that marine extinctions at the end of the Cretaceous period were indeed severe (see Hsu's article in Sundquist and Broeker, 1984). Variations in the isotopic compositions of carbonates and evaporitic sulfates during the Paleozoic reflect the relative abundances of euxinic (anoxic) marine environments and organic deposits from terrestrial flora. The carbon isotopic composition of Precambrian sediments suggest that the enzyme ribulose bisphosphate carboxylase has existed for perhaps 3.5 billion years.

  15. Isotope Geochemistry of the Dongchuan Copper Deposit,Yunnan,SW China: Stratigraphic Chronology and Application of Lead Isotopes in Geochemical Exploration

    Institute of Scientific and Technical Information of China (English)

    常向阳; 朱炳泉


    In this paper the Pb-Pb isochron method was used to determine the isotopic ages of te Luoxue Formation dolomites(1716±56Ma),th Heishan Formation carbonaceous slated (1607±128Ma) of the middle sub-group of the Kunyang Group and the Dayingpan Formation carbonaceous slates(1258±Ma) of the upper sub-group of the Kunyang Group.The age of the middle sub-group of the Kunyang Group is about 1800-1600Ma,belonging to the Late Paleo-Proterozoic,and that of the Dayingpan Formation in the upper sub-group of the Kunyang Group is about 1200-1300Ma, belonging to the Middle Poroterozoic.In addition,the Pb isotope chemical exploration techniques were used to study systematically the Pb isotopic compositions of rocks and ores across the No.14 vein in the middle segment of the No.1 pit of the Tangdan copper deposit and the result showed that the Pb isotope V1 values are neatively correlated with the copper contents.In is the first trial to use the systematic section method to conduct Pb isotope chemical exploration.

  16. Isotope Geochemistry of the Dongchuan Copper Deposit, Yunnan, SW China:Stratigraphic Chronology and Application of Lead Isotopes in Geochemical Exploration

    Institute of Scientific and Technical Information of China (English)

    常向阳; 朱炳泉


    In this paper the Pb-Pb isochron method was used to determine the isotopic ages of the Luoxue Formation dolomites (1716 ± 56 Ma), the Heishan Formation carbonaceous slates(1607 ± 128 Ma) of the middle sub-group of the Kunyang Group and the Dayingpan Formation carbonaceous slates ( 1258 ± 70Ma) of the upper sub-group of the Kunyang Group. The age of the middle sub-group of the Kunyang Group is about 1800 - 1600 Ma, belonging to the Late Paleo-Proterozoic, and that of the Dayingpan Formation in the upper sub-group of the Kunyang Group is about 1200 - 1300 Ma, belonging to the Middle Proterozoic. In addition, the Pb isotope chemical exploration techniques were used to study systematically the Pb isotopic compositions of rocks and ores across the No. 14 vein in the middle segment of the No. 1 pit of the Tangdan copper deposit and the result showed that the Pb isotope V1 values are negatively correlated with the copper contents. It is the first trial to use the systematic section method to conduct Pb isotope chemical exploration.

  17. Apparatus and process for separating hydrogen isotopes (United States)

    Heung, Leung K; Sessions, Henry T; Xiao, Xin


    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  18. Determining the geochemical structure of the mantle from surface isotope distribution patterns? Insights from Ne and He isotopes and abundance ratios (United States)

    Stroncik, N.; Niedermann, S.; Schnabel, E.; Erzinger, J.


    It is a common procedure among geochemists to use surface distribution patterns of e.g. Sr, Nd, Pb or He isotopes of lavas erupted at oceanic islands to map the geochemical structure of the Earth's mantle. Advances in noble gas mass spectrometry within the last decade resulting in an increasing availability of Ne isotope data sets allow us to test the strength of this approach. 4He and 21Ne are coupled through the same parent nuclides and therefore should show analogous isotope distribution patterns. Here we present He and Ne fusion data of fresh olivines derived from Big Island, Hawaii, together with He and Ne fusion data of fresh glasses from the Easter Seamount Chain (ESC), indicating that the observed isotope distribution patterns are mainly controlled by melting and shallow mixing processes. He isotopic ratios of the investigated olivines vary from MORB-like (8 ± 1 RA) to ratios more typical for a primitive mantle source (up to 20 and 26 RA for Hawaii and the ESC, respectively; RA = atmospheric 3He/4He ratio of 1.39 x 10-6). In contrast, all Ne isotope data plot within error limits along the Loihi-Kilauea line in a Ne three-isotope diagram. The Loihi-Kilauea line is regarded to be typical for a primitive mantle source. Thus, the Ne isotope data are inconsistent with any kind of zoned plume model or even a heterogeneous mantle source. The combined He and Ne data show that these He and Ne isotope systematics are produced by a pre-degassing fractionation process and subsequent melt mixing. Basically, this process causes a He deficit in melts generated by the plume, as shown by 3He/22NeS below current estimates of solar or planetary composition and 4He/21Ne* lower than the production ratio, making the He isotopic composition more susceptible to changes than the Ne isotopic composition. This can best be explained by a model in which He is fractionated from Ne during formation of melts from a plume (or enriched parts of a plume) at low melting degrees, which

  19. Systematic comparison of δ13C measurements of testosterone and derivative steroids in a freeze-dried urine candidate reference material for sports drug testing by gas chromatography/combustion/isotope ratio mass spectrometry and uncertainty evaluation using four different metrological approaches. (United States)

    Munton, Ellaine; Murby, John; Hibbert, D Brynn; Santamaria-Fernandez, Rebeca


    An alternative calibration procedure for use when performing carbon isotope ratio measurements by gas chromatography/combustion/isotope ratio mass spectrometry (GC/C/IRMS) has been developed. This calibration procedure does not rely on the corrections in-built in the instrument software, as the carbon isotope ratios of a sample are calculated from the measured raw peak areas. The method was developed for the certification of a urine reference material for sports drug testing, as the estimation of measurement uncertainty is greatly simplified. To ensure that the method is free from bias arising from the choice of calibration material and instrument, the carbon isotope ratios of steroids in urine extracts were measured using two different instruments in different laboratories, and three different reference materials (CU/USADA steroid standards from Brenna Laboratory, Cornell University; NIST RM8539 mineral oil; methane calibrated against NIST RM8560 natural gas). The measurements were performed at LGC and the Australian National Measurement Institute (NMI). It was found that there was no significant difference in measurement results when different instruments and reference materials were used to measure the carbon isotope ratio of the major testosterone metabolites androsterone and etiocholanolone, or the endogenous reference compounds pregnanediol, 11- ketoetiocholanolone and 11β-hydroxyandrosterone. Expanded measurement uncertainties at the 95% coverage probability ranged from 0.21‰ to 1.4‰, depending on analyte, instrument and reference material. The measurement results of this comparison were used to estimate a measurement uncertainty of δ(13)C for the certification of the urine reference material being performed on a single instrument using a single reference material at NMI.

  20. River Valley pluton, Ontario - A late-Archean/early-Proterozoic anorthositic intrusion in the Grenville Province (United States)

    Ashwal, Lewis D.; Wooden, Joseph L.


    This paper presents Nd, Sr, and Pb isotopic data indicating a late-Archean/early-Proterozoic age for the River Valley anorthositic pluton of the southwestern Grenville Province of Sudbury, Ontario. Pb-Pb isotopic data on 10 whole-rock samples ranging in composition from anorthosite to gabbro yield an age of 2560 + or - 155 Ma. The River Valley pluton is thus the oldest anorthositic intrusive yet recognized within the Grenville Province. The Sm-Nd isotopic system records an age of 2377 + or - 68 Ma. High Pb-208/Pb-204 of deformed samples relative to igneous-textured rocks implies Th introduction and/or U loss during metamorphism in the River Valley area. Rb-Sr data from igneous-textured and deformed samples and from mineral separates give an age of 2185 + or - 105 Ma, indicating substantial disturbance of the Rb-Sr isotopic system.

  1. Neutron-rich 104,106,108Mo Isotopes in the Generalized Collective Model

    Institute of Scientific and Technical Information of China (English)


    The Generalized Collective Model (GCM) is applied to the even-even neutron-rich 104,106,108Mo isotopes. With GCM the energy spectra, absolute B(E2) values, some B(E2) branching ratios and Potential Energy Surfaces (PES) for the 104,106,108Mo isotopes are calculated. The PES of all these isotopes show a prolate minimum which becomes more pronounced in 106Mo. The results are in agreement with the recent experimental report but are different from the viewpoint of the triaxial rotors, or γ-soft deformation. Through a systematic study of PES, it is suggested that the even-even neutron-rich 104,106,108Mo isotopes have prolate deformation.

  2. Shell-model configuration-interaction description of quadrupole collectivity in Te isotopes (United States)

    Qi, Chong


    Systematic calculations on the spectroscopy and transition properties of even-even Te isotopes are carried out by using the large-scale shell-model configuration-interaction approach with a realistic interaction. These nuclei are of particular interest since their yrast spectra show a vibrational-like equally spaced pattern whereas the few known E 2 transitions show rotational-like behavior. This cannot be explained by available collective models. My calculations reproduce well the equally spaced spectra of those isotopes as well as the constant behavior for the B (E 2 ) values of 114Te. The calculated B (E 2 ) values of neutron-deficient and heavier Te isotopes show contrasting different behaviors along the yrast line. The B (E 2 ) of light isotopes can exhibit a nearly constant behavior up to high spins. It is shown that this is related to the enhanced neutron-proton correlation when approaching N =50 .

  3. Cu Isotopic Composition in Surface Environments and in Biological Systems: A Critical Review

    Directory of Open Access Journals (Sweden)

    Zhuhong Wang


    Full Text Available Copper (Cu is a transition metal and an essential micronutrient for organisms, but also one of the most widespread toxic inorganic contaminants at very high content. The research on Cu isotopes has grown rapidly in the last decade. Hitherto, a large number of studies have been published on the theoretical fractionation mechanisms, experimental data and natural variations of Cu isotopes in variable environments and ecosystems. These studies reported a large variation of δ65Cu (−16.49 to +20.04‰ in terrestrial samples and showed that Cu isotopes could be fractionated by various biogeochemical processes to different extent. Several papers have previously reviewed the coupling of Cu and Zn isotope systematics, and we give here a tentative review of the recent publications only on Cu isotopesin variable surface repositories, animals and human beings, with a goal to attract much attention to research on Cu (and other metals behaviors in the environment and biological systems.

  4. Study of polonium isotopes ground state properties by simultaneous atomic- and nuclear-spectroscopy

    CERN Multimedia

    Koester, U H; Kalaninova, Z; Imai, N


    We propose to systematically study the ground state properties of neutron deficient $^{192-200}$Po isotopes by means of in-source laser spectroscopy using the ISOLDE laser ion source coupled with nuclear spectroscopy at the detection setup as successfully done before by this collaboration with neutron deficient lead isotopes. The study of the change in mean square charge radii along the polonium isotope chain will give an insight into shape coexistence above the mid-shell N = 104 and above the closed shell Z = 82. The hyperfine structure of the odd isotopes will also allow determination of the nuclear spin and the magnetic moment of the ground state and of any identifiable isomer state. For this study, a standard UC$_{x}$ target with the ISOLDE RILIS is required for 38 shifts.

  5. Measurements of interaction cross sections for 22–35Na isotopes

    Directory of Open Access Journals (Sweden)

    Suzuki S.


    Full Text Available Interaction cross sections (σI for 22−35Na isotopes from the stability line to the vicinity of the neutron drip line have been measured at around 240 MeV/nucleon. The σI for 33−35Na were measured for the first time. Enhancement in cross sections is clearly observed from the systematics for stable nuclei, for isotopes with large mass numbers. From the known values of the nuclear-deformation parameters β2 of 22−31Na, these enhancement can be mainly ascribed to the nuclear deformation. Large enhancement in heavier isotopes suggest that these nuclei are strongly deformed. The root-mean-square (RMS nuclear matter radii were deduced from the σI by using Glauber-type calculation. Furthermore, a monotonic growth of the neutron-skin thickness has been deduced with increasing neutron number for Na isotopes.

  6. Silicon isotopes reveal recycled altered oceanic crust in the mantle sources of Ocean Island Basalts (United States)

    Pringle, Emily A.; Moynier, Frédéric; Savage, Paul S.; Jackson, Matthew G.; Moreira, Manuel; Day, James M. D.


    The study of silicon (Si) isotopes in Ocean Island Basalts (OIB) has the potential to discern between different models for the origins of geochemical heterogeneities in the mantle. Relatively large (∼several per mil per atomic mass unit) Si isotope fractionation occurs in low-temperature environments during biochemical and geochemical precipitation of dissolved Si, where the precipitate is preferentially enriched in the lighter isotopes relative to the dissolved Si. In contrast, only a limited range (∼tenths of a per mil) of Si isotope fractionation has been observed from high-temperature igneous processes. Therefore, Si isotopes may be useful as tracers for the presence of crustal material within OIB mantle source regions that experienced relatively low-temperature surface processes in a manner similar to other stable isotope systems, such as oxygen. Characterizing the isotopic composition of the mantle is also of central importance to the use of the Si isotope system as a basis for comparisons with other planetary bodies (e.g., Moon, Mars, asteroids). Here we present the first comprehensive suite of high-precision Si isotope data obtained by MC-ICP-MS for a diverse suite of OIB. Samples originate from ocean islands in the Pacific, Atlantic, and Indian Ocean basins and include representative end-members for the EM-1, EM-2, and HIMU mantle components. On average, δ30Si values for OIB (-0.32 ± 0.09‰, 2 sd) are in general agreement with previous estimates for the δ30Si value of Bulk Silicate Earth (-0.29 ± 0.07‰, 2 sd; Savage et al., 2014). Nonetheless, some small systematic variations are present; specifically, most HIMU-type (Mangaia; Cape Verde; La Palma, Canary Islands) and Iceland OIB are enriched in the lighter isotopes of Si (δ30Si values lower than MORB), consistent with recycled altered oceanic crust and lithospheric mantle in their mantle sources.

  7. Alignments in the nobelium isotopes

    Institute of Scientific and Technical Information of China (English)

    ZHENG Shi-Zie; XU Fu-Rong; YUAN Cen-Xi; QI Chong


    Total-Routhian-Surface calculations have been performed to investigate the deformation and align-ment properties of the No isotopes. It is found that normal deformed and superdeformed states in these nuclei can coexist at low excitation energies. In neutron-deficient No isotopes, the superdeformed shapes can even become the ground states. Moreover, we plotted the kinematic moments of inertia of the No isotopes, which follow very nicely available experimental data. It is noted that, as the rotational frequency increases, align-ments develop at hω=0.2-0.3 MeV. Our calculations show that the occupation of the vj orbital plays an important role in the alignments of the No isotopes.

  8. Isotope-based quantum information

    CERN Document Server

    G Plekhanov, Vladimir


    The present book provides to the main ideas and techniques of the rapid progressing field of quantum information and quantum computation using isotope - mixed materials. It starts with an introduction to the isotope physics and then describes of the isotope - based quantum information and quantum computation. The ability to manipulate and control electron and/or nucleus spin in semiconductor devices provides a new route to expand the capabilities of inorganic semiconductor-based electronics and to design innovative devices with potential application in quantum computing. One of the major challenges towards these objectives is to develop semiconductor-based systems and architectures in which the spatial distribution of spins and their properties can be controlled. For instance, to eliminate electron spin decoherence resulting from hyperfine interaction due to nuclear spin background, isotopically controlled devices are needed (i.e., nuclear spin-depleted). In other emerging concepts, the control of the spatial...

  9. Isotopic Changes During Digestion: Protein (United States)

    Tuross, N.


    Nutrient and hydrological inputs traverse a complicated route of pH, enzymatic and cellular processes in digestion in higher animals. The end products of digestion are the starting products for biosynthesis that are often used to interpret past life-ways. Using an artificial gut system, the isotopic changes (dD, d18O, d13C and d15N) of protein are documented. Three separate protein sources are subjected to the conditions, chemical and enzymatic, found in the stomach and upper small intestine with only a small shift in the oxygen isotopic composition of the proteins observed. Middle to lower small intestine parameters produced both greater isotopic effects and significantly lower molecular weight products. The role of the gastric enterocyte and the likely involvement of the internal milieu of this cell in the isotopic composition of amino acids that are transported to the liver are reported.

  10. The iron isotope composition of enstatite meteorites: Implications for their origin and the metal/sulfide Fe isotopic fractionation factor (United States)

    Wang, Kun; Savage, Paul S.; Moynier, Frédéric


    due to intensive impact-induced shearing stress, or the ultimate destruction of the Shallowater parent body. Analysis of separated enstatite meteorite mineral phases show that the magnetic phase (Fe metal) is systematically enriched in the heavier Fe isotopes when compared to non-magnetic phases (Fe hosted in troilite), which agrees with previous experimental observations and theoretical calculations. The difference between magnetic and non-magnetic phases from enstatite achondrites provides an equilibrium metal-sulfide Fe isotopic fractionation factor of Δ56Femetal-troilite = δ56Femetal - δ56Fetroilite of 0.129 ± 0.060‰ (2 SE) at 1060 ± 80 K, which confirms the predictions of previous theoretical calculations.

  11. Descriptions of carbon isotopes within the energy density functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Ismail, Atef [Fundamental and Applied Sciences Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak, Malaysia and Department of Physics, Al-Azhar University, 71524 Assiut (Egypt); Cheong, Lee Yen; Yahya, Noorhana [Fundamental and Applied Sciences Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia); Tammam, M. [Department of Physics, Al-Azhar University, 71524 Assiut (Egypt)


    Within the energy density functional (EDF) theory, the structure properties of Carbon isotopes are systematically studied. The shell model calculations are done for both even-A and odd-A nuclei, to study the structure of rich-neutron Carbon isotopes. The EDF theory indicates the single-neutron halo structures in {sup 15}C, {sup 17}C and {sup 19}C, and the two-neutron halo structures in {sup 16}C and {sup 22}C nuclei. It is also found that close to the neutron drip-line, there exist amazing increase in the neutron radii and decrease on the binding energies BE, which are tightly related with the blocking effect and correspondingly the blocking effect plays a significant role in the shell model configurations.

  12. Oxygen isotope constraints on the alteration temperatures of CM chondrites (United States)

    Verdier-Paoletti, Maximilien J.; Marrocchi, Yves; Avice, Guillaume; Roskosz, Mathieu; Gurenko, Andrey; Gounelle, Matthieu


    We report a systematic oxygen isotopic survey of Ca-carbonates in nine different CM chondrites characterized by different degrees of alteration, from the least altered known to date (Paris, 2.7-2.8) to the most altered (ALH 88045, CM1). Our data define a continuous trend that crosses the Terrestrial Fractionation Line (TFL), with a general relationship that is indistinguishable within errors from the trend defined by both matrix phyllosilicates and bulk O-isotopic compositions of CM chondrites. This bulk-matrix-carbonate (BMC) trend does not correspond to a mass-dependent fractionation (i.e., slope 0.52) as it would be expected during fluid circulation along a temperature gradient. It is instead a direct proxy of the degree of O-isotopic equilibration between 17,18O-rich fluids and 16O-rich anhydrous minerals. Our O-isotopic survey revealed that, for a given CM, no carbonate is in O-isotopic equilibrium with its respective surrounding matrix. This precludes direct calculation of the temperature of carbonate precipitation. However, the O-isotopic compositions of alteration water in different CMs (inferred from isotopic mass-balance calculation and direct measurements) define another trend (CMW for CM Water), parallel to BMC but with a different intercept. The distance between the BMC and CMW trends is directly related to the temperature of CM alteration and corresponds to average carbonates and serpentine formation temperatures of 110 °C and 75 °C, respectively. However, carbonate O-isotopic variations around the BMC trend indicate that they formed at various temperatures ranging between 50 and 300 °C, with 50% of the carbonates studied here showing precipitation temperature higher than 100 °C. The average Δ17O and the average carbonate precipitation temperature per chondrite are correlated, revealing that all CMs underwent similar maximum temperature peaks, but that altered CMs experienced protracted carbonate precipitation event(s) at lower temperatures than

  13. The clumped isotopic record of Neoproterozoic carbonates, Sultanate of Oman (United States)

    Bergmann, K. D.; Eiler, J. M.; Fischer, W. W.; Osburn, M. R.; Grotzinger, J. P.


    The Huqf Supergroup of the Sultanate of Oman records several important events in latest Precambrian time, including two glaciations in the Abu Mahara Group (ca. 725 - isotope excursion in the Nafun Group (ca. isotopic excursions, hypothesized to record perturbations of the surficial Earth carbon cycle or post-depositional diagenetic processes. Rigorous interpretation of these records requires a more thorough assessment of diagenetic processes. To better understand the significance and cause of these large amplitude isotopic excursions, we employed carbonate clumped isotope thermometry. This method allows us to estimate the absolute temperature of carbonate precipitation, including recrystallization, based on the temperature dependent abundance of carbonate ions containing both 13C and 18O. These estimates are accompanied by a measurement of carbonate δ18O, which in conjunction with temperature, can be used to calculate the oxygen isotopic composition of the fluid from which the carbonate precipitated. We analyzed stratigraphically constrained samples from a range of paleoenvironments with differing burial histories (1 - >10km maximum burial depth) to constrain the temperature and fluid composition of recrystallization. Clumped isotope temperatures from Huqf Supergroup samples range from 35-175°C. The isotopic composition of the fluid these rocks equilibrated with ranges from -3.7 to 15.7% VSMOW. This large range in temperature and fluid composition separates into distinct populations that differ systematically with independent constraints on petrography, stratigraphy and burial history. The data indicate the Abu Mahara, Nafun and Ara groups have unique diagenetic histories. In central Oman, the post-glacial Abu Mahara cap dolostone shows high temperature, rock buffered diagenesis (Tavg = 176°C; δ18Ofluid = 15% VSMOW), the Nafun Group generally experienced lower temperature, fluid buffered diagenesis (Tavg = 69°C; δ18Ofluid = 1% VSMOW) and the Ara Group

  14. Experimental determination of magnesium isotope fractionation during higher plant growth (United States)

    Bolou-Bi, Emile B.; Poszwa, Anne; Leyval, Corinne; Vigier, Nathalie


    Two higher plant species (rye grass and clover) were cultivated under laboratory conditions on two substrates (solution, phlogopite) in order to constrain the corresponding Mg isotope fractionations during plant growth and Mg uptake. We show that bulk plants are systematically enriched in heavy isotopes relative to their nutrient source. The Δ 26Mg plant-source range from 0.72‰ to 0.26‰ for rye grass and from 1.05‰ to 0.41‰ for clover. Plants grown on phlogopite display Mg isotope signatures (relative to the Mg source) ˜0.3‰ lower than hydroponic plants. For a given substrate, rye grass display lower δ 26Mg (by ˜0.3‰) relative to clover. Magnesium desorbed from rye grass roots display a δ 26Mg greater than the nutrient solution. Adsorption experiments on dead and living rye grass roots also indicate a significant enrichment in heavy isotopes of the Mg adsorbed on the root surface. Our results indicate that the key processes responsible for heavy isotope enrichment in plants are located at the root level. Both species also exhibit an enrichment in light isotopes from roots to shoots (Δ 26Mg leaf-root = -0.65‰ and -0.34‰ for rye grass and clover grown on phlogopite respectively, and Δ 26Mg leaf-root of -0.06‰ and -0.22‰ for the same species grown hydroponically). This heavy isotope depletion in leaves can be explained by biological processes that affect leaves and roots differently: (1) organo-Mg complex (including chlorophyll) formation, and (2) Mg transport within plant. For both species, a positive correlation between δ 26Mg and K/Mg was observed among the various organs. This correlation is consistent with the link between K and Mg internal cycles, as well as with formation of organo-magnesium compounds associated with enrichment in heavy isotopes. Considering our results together with the published range for δ 26Mg of natural plants and rivers, we estimate that a significant change in continental vegetation would induce a change of

  15. Controlling factors of rainwater and water vapor isotopes at Bangalore, India: Constraints from observations in 2013 Indian monsoon (United States)

    Rahul, P.; Ghosh, Prosenjit; Bhattacharya, S. K.; Yoshimura, Kei


    Isotopic ratios of rainwaters are believed to decrease with the amount of rainfall. However, analyses of the isotopic composition of rainwater and water vapor samples collected from Bangalore during the monsoon period of 2013 fail to show any simple relationship with the local meteorological parameters whereas show good correlation with the regional integrated convective activity. The correlation is particularly high when the averaging is done over the preceding 8 to 15 days, showing the influence of mixing or residence time scale of atmospheric moisture. This observation emphasizes the role of regional atmospheric circulation driving the isotopic values. A comparison between observed isotope ratios in water vapor and rainwater with Isotope-enabled Global Spectral Model shows discrepancies between the two. The observed values are relatively enriched, indicating a systematic bias in the model values. The higher observed values suggest underestimation of the evaporation in the model, which we estimate to be about 28 ± 15% on average. Simultaneous analyses of rainwater and water vapor isotopic composition again show definitive presence of raindrop evaporation (31 ± 14%). We also documented a distinct pattern of isotopic variation in six samples collected at Bangalore due to mixing of vapor from a cyclonic system in close proximity that originated from the Bay of Bengal. It seems that large-scale isotopic depletion occurs during cyclones caused by Rayleigh fractionation due to massive rainout. These results demonstrate the power of rainwater and water vapor isotope monitoring to elucidate the genesis and dynamics of water recycling within synoptic-scale monsoon systems.

  16. Natural variation of magnesium isotopes in mammal bones and teeth from two South African trophic chains (United States)

    Martin, Jeremy E.; Vance, Derek; Balter, Vincent


    Isotopic fractionations accompanying element transfer through terrestrial ecosystems have the potential to shed light on ecological interactions between primary producers and consumers, but with the exception of carbon and nitrogen this potential has barely been exploited. Here, the magnesium stable isotope composition of bones and teeth of extant mammals from Kruger National Park (KNP) and Western Cape (WC), South Africa was measured for the first time. The nature of the geological substrate proves to be a major determinant of the ecosystem isotope baseline, as indicated by the lighter magnesium isotope ratios measured in WC mammals (ranging from -1.58‰ to -0.79‰) compared to those from KNP mammals (ranging from -1.01‰ to -0.04‰). Therefore, comparisons between the isotope signatures of taxa must be restricted to a pre-defined geographic area with a homogeneous substrate. In both parks, Mg shows slight enrichment in heavier isotopes from herbivores to carnivores. Plant remains trapped in the dentition of herbivores provide direct evidence of dietary source and, when available, were measured. In KNP only, δ26Mg of plant remains is systematically lighter than the values for herbivore teeth. These results invite further exploration of the variability of Mg isotopes in vertebrate ecosystems in order to test whether magnesium, a bio-essential element present in relatively large proportions in bone and teeth apatite, may serve as an additional trophic tracer to nitrogen, which is a constituent of collagen that rapidly degrades after burial.

  17. A review of isotopic composition as an indicator of the natural and anthropogenic behavior of mercury (United States)

    Ridley, W.I.; Stetson, S.J.


    There are seven stable isotopes of Hg that can be fractionated as a result of inorganic and organic interactions. Important inorganic reactions involve speciation changes resulting from variations in environmental redox conditions, and phase changes resulting from variations in temperature and/or atmospheric pressure. Important organic reactions include methylation and demethylation, reactions that are bacterially mediated, and complexing with organic anions in soils. The measurement of Hg isotopes by multi-collector-inductively coupled plasma-mass spectrometry (MC-ICP-MS) is now sufficiently precise and sensitive that it is potentially possible to develop the systematics of Hg isotopic fractionation. This provides an opportunity to evaluate the utility of Hg isotopes in identifying source processes, transport mechanisms, and sinks. New values are provided for, 201Hg/198Hg, 200Hg/198Hg, 199Hg/198Hg for three standard materials (IRMM-AE639, SRM 1641c, SRM 3133) that can be used to make inter-laboratory data comparisons, and these values are tabulated with published isotopic information. Overall, the isotopic data for these standards agree to approximately 0.2???. The paper reviews Hg isotope studies that deal with hydrothermal ore deposits, sediments, coal and organic complexing. ?? 2006 Elsevier Ltd. All rights reserved.

  18. Isotope and ion selectivity in reverse osmosis desalination: geochemical tracers for man-made freshwater. (United States)

    Kloppmann, Wolfram; Vengosh, Avner; Guerrot, Catherine; Millot, Romain; Pankratov, Irena


    A systematic measurement of ions and 2H/1H, 7Li/6Li, 11B/10B, 18O/ 16O, and 87Sr/86Sr isotopes in feed-waters, permeates, and brines from commercial reverse osmosis (RO) desalination plants in Israel (Ashkelon, Eilat, and Nitzana) and Cyprus (Larnaca) reveals distinctive geochemical and isotopic fingerprints of fresh water generated from desalination of seawater (SWRO) and brackish water (BWRO). The degree of isotope fractionation during the passage of water and solutes through the RO membranes depends on the medium (solvent-water vs. solutes), chemical speciation of the solutes, their charge, and their mass difference. O, H, and Sr isotopes are not fractionated during the RO process. 7Li is preferentially rejected in low pH RO, and B isotope fractionation depends on the pH conditions. Under low pH conditions, B isotopes are not significantly fractionated, whereas at high pH, RO permeates are enriched by 20 per thousand in 11B due to selective rejection of borate ion and preferential permeation of 11B-enriched boric acid through the membrane. The specific geochemical and isotopic fingerprints of SWRO provide a unique tool for tracing "man-made" fresh water as an emerging recharge component of natural water resources.

  19. Unexpected variations in the triple oxygen isotope composition of stratospheric carbon dioxide. (United States)

    Wiegel, Aaron A; Cole, Amanda S; Hoag, Katherine J; Atlas, Elliot L; Schauffler, Sue M; Boering, Kristie A


    We report observations of stratospheric CO2 that reveal surprisingly large anomalous enrichments in (17)O that vary systematically with latitude, altitude, and season. The triple isotope slopes reached 1.95 ± 0.05(1σ) in the middle stratosphere and 2.22 ± 0.07 in the Arctic vortex versus 1.71 ± 0.03 from previous observations and a remarkable factor of 4 larger than the mass-dependent value of 0.52. Kinetics modeling of laboratory measurements of photochemical ozone-CO2 isotope exchange demonstrates that non-mass-dependent isotope effects in ozone formation alone quantitatively account for the (17)O anomaly in CO2 in the laboratory, resolving long-standing discrepancies between models and laboratory measurements. Model sensitivities to hypothetical mass-dependent isotope effects in reactions involving O3, O((1)D), or CO2 and to an empirically derived temperature dependence of the anomalous kinetic isotope effects in ozone formation then provide a conceptual framework for understanding the differences in the isotopic composition and the triple isotope slopes between the laboratory and the stratosphere and between different regions of the stratosphere. This understanding in turn provides a firmer foundation for the diverse biogeochemical and paleoclimate applications of (17)O anomalies in tropospheric CO2, O2, mineral sulfates, and fossil bones and teeth, which all derive from stratospheric CO2.

  20. Absolute Isotopic Abundance Ratios and the Accuracy of Δ47 Measurements (United States)

    Daeron, M.; Blamart, D.; Peral, M.; Affek, H. P.


    Conversion from raw IRMS data to clumped isotope anomalies in CO2 (Δ47) relies on four external parameters: the (13C/12C) ratio of VPDB, the (17O/16O) and (18O/16O) ratios of VSMOW (or VPDB-CO2), and the slope of the triple oxygen isotope line (λ). Here we investigate the influence that these isotopic parameters exert on measured Δ47 values, using real-world data corresponding to 7 months of measurements; simulations based on randomly generated data; precise comparisons between water-equilibrated CO2 samples and between carbonate standards believed to share quasi-identical Δ47 values; reprocessing of two carbonate calibration data sets with different slopes of Δ47 versus T. Using different sets of isotopic parameters generally produces systematic offsets as large as 0.04 ‰ in final Δ47 values. What's more, even using a single set of isotopic parameters can produce intra- and inter-laboratory discrepancies in final Δ47 values, if some of these parameters are inaccurate. Depending on the isotopic compositions of the standards used for conversion to "absolute" values, these errors should correlate strongly with either δ13C or δ18O, or more weakly with both. Based on measurements of samples expected to display identical Δ47 values, such as 25°C water-equilibrated CO2 with different carbon and oxygen isotope compositions, or high-temperature standards ETH-1 and ETH-2, we conclude that the isotopic parameters used so far in most clumped isotope studies produces large, systematic errors controlled by the relative bulk isotopic compositions of samples and standards, which should be one of the key factors responsible for current inter-laboratory discrepancies. By contrast, the isotopic parameters of Brand et al. [2010] appear to yield accurate Δ47 values regardless of bulk isotopic composition. References:Brand, Assonov and Coplen [2010]

  1. Paleoproxies: Heavy Stable Isotope Perspectives (United States)

    Nagler, T. F.; Hippler, D.; Siebert, C.; Kramers, J. D.


    Recent advances in isotope ratio mass spectrometry, namely multiple collector ICP-MS and refined TIMS techniques, will significantly enhance the ability to measure heavy stable isotope fractionation, which will lead to the development of a wide array of process-identifying (bio)-geochemical tools. Thus far research in this area is not easily assessable to scientists outside the isotope field. This is due to the fact that analyzing heavy stable isotopes does not provide routine numbers which are per se true (the preciser the truer) but is still a highly experimental field. On the other hand resolving earth science problems requires specialists familiar with the environment being studied. So what is in there for paleoceanographers? In a first order approach, relating isotope variations to physical processes is straightforward. A prominent example are oxygen isotope variations with temperature. The total geological signal is of course far more complicated. At low temperatures, heavy stable isotopes variations have been reported for e.g. Ca, Cr, Fe, Cu, Zn, Mo and Tl. Fractionation mechanisms and physical parameters responsible for the observed variations are not yet resolved for most elements. Significant equilibrium isotope fractionation is expected from redox reactions of transition metals. However a difference in coordination number between two coexisting speciations of an element in the same oxidation state can also cause fractionation. Protonation of dissolved Mo is one case currently discussed. For paleoceanography studies, a principal distinction between transition metals essential for life (V to Zn plus Mo) or not will be helpful. In case of the former group, distinction between biogenic and abiogenic isotope fractionation will remain an important issue. For example, abiotic Fe redox reactions result in isotope fractionations indistinguishable in direction and magnitude from microbial effects. Only a combination of different stable isotope systems bears the

  2. Integrating isotopic fingerprinting with petrology: how do igneous rocks evolve? (United States)

    Davidson, J. P.


    magma storage and delivery system; 3) 87Sr/86Sr variations within feldspars from a single ignimbrite exceed the entire rhyolite bulk rock range of 87Sr/86Sr recorded from the Taupo volcanic zone, New Zealand; arguing that the isotopic heterogeneity encountered during differentiation is greater than that erupted; and 4) Gabbros from the Rum intrusion (NW Scotland) exhibit inter and intra-grain isotopic heterogeneity arguing that accumulation involved mixing of crystal populations which evolved in different domains of an open system magma chamber. These studies suggest that isotopic modification of magmas in the crust (according to P-T estimates of plagiocalse stability) is the rule rather than the exception. Although it is conceivable that isotopic signatures are all inherited from mantle-derived melts which interacted before, during and after crystal growth, it is more likely that the isotopic diversity reflects contamination and mixing which obscures the signature of the mantle contributions. Furthermore, it is perhaps unrealistic to think of the evolution of a particular igneous rock. Rather each rock appears to be an aggregate of components with separate evolutionary histories. Because isotopic composition is leveraged by the mass balance of these components (Sr is typically concentrated in plagioclase, Nd in glass and accessories, Hf in zircon, Pb in feldspar and glass), the isotopic systematics of bulk rocks can become decoupled from each other. Thus the isotope characteristics of the rock components give a more faithful record of evolution processes than the bulk rock itself.

  3. C-isotope composition of fossil sedges and grasses (United States)

    Kurschner, Wolfram M.


    C4 plants differ from C3 plants regarding their anatomy and their C-isotope composition. Both features can be used in the geological record to determine the presence of C4 plants. Yet, the evolution of the C4 pathway in the fossil record is enigmatic as palaeobotanical and geological evidence for C4 plants is sparse. The oldest structural evidence for Kranz anatomy has been found in Late Miocene permineralized grass leaf remains. But studies on the C-isotope composition of sedimentary organic matter indicate that abundant C4 biomass was present in N-America and Asia throughout the Miocene in expanding savannahs and grasslands. The success of C4 plants appears to be related also to an increasing seasonal aridity in the tropical climate belts and the co-evolution of grazers. However, C- isotope composition of palaeosols or vertebrate teeth only allows to estimate the abundance of C4 plant biomass in the vegetation or in the diet without further taxonomical specification which plant groups would have had C4 metabolism. In this contribution the first extensive C-isotope analysis of fossil seeds of sedges and a few grasses are presented. The age of the carpological material ranges from Late Eocene to Pliocene and was collected from several central European brown coal deposits. The 52 different taxa studied include several species of Carex, Cladiocarya, Eriopherum, Eleocharis, Scirpus, Sparganium. Most of them representing herbaceous elements of a (sub)tropical vegetation growing near the edge of a lake. The C-isotope composition of the fossil seeds varies between -30 and -23 o/oo indicating C3 photosynthesis. This first systematic inventory shows that C4 plants were absent in the European (sub)tropical brown coal forming wetland vegetation during the Tertiary. These preliminary data are in agreement with phylogenetic studies which predict the origin of C4 plants outside the European realm.

  4. Calcium Isotope Analysis by Mass Spectrometry (United States)

    Boulyga, S.; Richter, S.


    The variations in the isotopic composition of calcium caused by fractionation in heterogeneous systems and by nuclear reactions can provide insight into numerous biological, geological, and cosmic processes, and therefore isotopic analysis finds a wide spectrum of applications in cosmo- and geochemistry, paleoclimatic, nutritional, and biomedical studies. The measurement of calcium isotopic abundances in natural samples has challenged the analysts for more than three decades. Practically all Ca isotopes suffer from significant isobaric interferences, whereas low-abundant isotopes can be particularly affected by neighboring major isotopes. The extent of natural variations of stable isotopes appears to be relatively limited, and highly precise techniques are required to resolve isotopic effects. Isotope fractionation during sample preparation and measurements and instrumental mass bias can significantly exceed small isotope abundance variations in samples, which have to be investigated. Not surprisingly, a TIMS procedure developed by Russell et al. (Russell et al., 1978. Geochim Cosmochim Acta 42: 1075-1090) for Ca isotope measurements was considered as revolutionary for isotopic measurements in general, and that approach is used nowadays (with small modifications) for practically all isotopic systems and with different mass spectrometric techniques. Nevertheless, despite several decades of calcium research and corresponding development of mass spectrometers, the available precision and accuracy is still not always sufficient to achieve the challenging goals. This presentation discusses figures of merits of presently used analytical methods and instrumentation, and attempts to critically assess their limitations. Additionally, the availability of Ca isotope reference materials will be discussed.

  5. Geochemistry: how well can Pb isotopes date core formation? (United States)

    Kamber, Balz S; Kramers, Jan D


    Timescale and the physics of planetary core formation are essential constraints for models of Earth's accretion and early differentiation. Wood and Halliday use the apparent mismatch in core-formation dates determined from tungsten (W) and lead (Pb) chrono-meters to argue for a two-stage core formation, involving an early phase of metal segregation followed by a protracted episode of sulphide melt addition. However, we show here that crust-;mantle Pb isotope systematics do not require diachronous core formation. Our observations indicate that very early (< or = 35 Myr) core formation and planet accretion remain the most plausible scenario.

  6. Average radiation widths of levels in natural xenon isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Noguere, G., E-mail: [CEA, DEN, Cadarache, F-13108 Saint Paul les Durance (France); Litaize, O.; Archier, P.; De Saint Jean, C. [CEA, DEN, Cadarache, F-13108 Saint Paul les Durance (France); Mutti, P. [Institut Laue-Langevin, F-38042 Grenoble (France)


    Average radiation widths <{Gamma}{sub {gamma}>} for the stable xenon isotopes have been estimated using neutron resonance spectroscopic information deduced from high-resolution capture and transmission data measured at the electron linear accelerator GELINA of the Institute for Reference Materials and Measurements (IRMM) in Geel, Belgium. The combination of conventional Neutron Resonance Shape Analysis techniques (NRSA) with high-energy model calculations in a simple Bayesian learning method permit to calculate a consistent local systematic in the xenon's mass region (Z=54) from A=124 to A=136.

  7. The systematization of practice

    DEFF Research Database (Denmark)

    Vidal, Rene Victor Valqui


    this paper presents an approach for the systematization of practical experiences whitin Operations Research, Community work, Systems Sciences, Action Research, etc. A case study is presented: the systematization of the activities of a development center in Denmark.......this paper presents an approach for the systematization of practical experiences whitin Operations Research, Community work, Systems Sciences, Action Research, etc. A case study is presented: the systematization of the activities of a development center in Denmark....

  8. Isotopes a very short introduction

    CERN Document Server

    Ellam, Rob


    An isotope is a variant form of a chemical element, containing a different number of neutrons in its nucleus. Most elements exist as several isotopes. Many are stable while others are radioactive, and some may only exist fleetingly before decaying into other elements. In this Very Short Introduction, Rob Ellam explains how isotopes have proved enormously important across all the sciences and in archaeology. Radioactive isotopes may be familiar from their use in nuclear weapons, nuclear power, and in medicine, as well as in carbon dating. They have been central to establishing the age of the Earth and the origins of the solar system. Combining previous and new research, Ellam provides an overview of the nature of stable and radioactive isotopes, and considers their wide range of modern applications. ABOUT THE SERIES: The Very Short Introductions series from Oxford University Press contains hundreds of titles in almost every subject area. These pocket-sized books are the perfect way to get ahead in a new subjec...

  9. Exotic Structure of Carbon Isotopes

    CERN Document Server

    Suzuki, T; Hagino, K; Suzuki, Toshio; Sagawa, Hiroyuki; Hagino, Kouichi


    We studied firstly the ground state properties of C-isotopes using a deformed Hartree-Fock (HF)+ BCS model with Skyrme interactions. Shallow deformation minima are found in several neutron$-$rich C-isotopes. It is shown also that the deformation minima appear in both the oblate and the prolate sides in $^{17}$C and $^{19}$C having almost the same binding energies. Secondly, we carried out shell model calculations to study electromagnetic moments and electric dipole transitions of the C-isotopes. We point out the clear configuration dependence of the quadrupole and magnetic moments in the odd C-isotopes, which will be useful to find out the deformations and the spin-parities of the ground states of these nuclei. We studied electric dipole states of C-isotopes focusing on the interplay between low energy Pigmy strength and giant dipole resonances. Reasonable agreement is obtained with available experimental data for the photoreaction cross sections both in the low energy region below $\\hbar \\omega $=14 MeV and ...

  10. Handbook of environmental isotope geochemistry

    Energy Technology Data Exchange (ETDEWEB)

    Baskaran, Mark (ed.) [Wayne State Univ., Detroit, MI (United States). Dept. Geology


    Applications of radioactive and stable isotopes have revolutionized our understanding of the Earth and near-earth surface processes. The utility of the isotopes are ever-increasing and our sole focus is to bring out the applications of these isotopes as tracers and chronometers to a wider audience so that they can be used as powerful tools to solve environmental problems. New developments in this field remain mostly in peer-reviewed journal articles and hence our goal is to synthesize these findings for easy reference for students, faculty, regulators in governmental and non-governmental agencies, and environmental companies. While this volume maintains its rigor in terms of its depth of knowledge and quantitative information, it contains the breadth needed for wide variety problems and applications in the environmental sciences. This volume presents all of the newer and older applications of isotopes pertaining to the environmental problems in one place that is readily accessible to readers. This book not only has the depth and rigor that is needed for academia, but it has the breadth and case studies to illustrate the utility of the isotopes in a wide variety of environments (atmosphere, oceans, lakes, rivers and streams, terrestrial environments, and sub-surface environments) and serves a large audience, from students and researchers, regulators in federal, state and local governments, and environmental companies. (orig.)

  11. Influence of liquid structure on diffusive isotope separation in molten silicates and aqueous solutions (United States)

    Watkins, James M.; DePaolo, Donald J.; Ryerson, Frederick J.; Peterson, Brook T.


    Molecular diffusion in natural volcanic liquids discriminates between isotopes of major ions (e.g., Fe, Mg, Ca, and Li). Although isotope separation by diffusion is expected on theoretical grounds, the dependence on mass is highly variable for different elements and in different media. Silicate liquid diffusion experiments using simple liquid compositions were carried out to further probe the compositional dependence of diffusive isotopic discrimination and its relationship to liquid structure. Two diffusion couples consisting of the mineral constituents anorthite (CaAl 2Si 2O 8; denoted AN), albite (NaAlSi 3O 8; denoted AB), and diopside (CaMgSi 2O 6; denoted DI) were held at 1450 °C for 2 h and then quenched to ambient pressure and temperature. Major-element as well as Ca and Mg isotope profiles were measured on the recovered quenched glasses. In both experiments, Ca diffuses rapidly with respect to Si. In the AB-AN experiment, D Ca/ D Si ≈ 20 and the efficiency of isotope separation for Ca is much greater than in natural liquid experiments where D Ca/ D Si ≈ 1. In the AB-DI experiment, D Ca/ D Si ≈ 6 and the efficiency of isotope separation is between that of the natural liquid experiments and the AB-AN experiment. In the AB-DI experiment, D Mg/ D Si ≈ 1 and the efficiency of isotope separation for Mg is smaller than it is for Ca yet similar to that observed for Mg in natural liquids. The results from the experiments reported here, in combination with results from natural volcanic liquids, show clearly that the efficiency of diffusive separation of Ca isotopes is systematically related to the solvent-normalized diffusivity - the ratio of the diffusivity of the cation ( D Ca) to the diffusivity of silicon ( D Si). The results on Ca isotopes are consistent with available data on Fe, Li, and Mg isotopes in silicate liquids, when considered in terms of the parameter D cation/ D Si. Cations diffusing in aqueous solutions display a similar relationship

  12. Modification of the Continental Crust by Subduction Zone Magmatism and Vice-Versa: Across-Strike Geochemical Variations of Silicic Lavas from Individual Eruptive Centers in the Andean Central Volcanic Zone

    Directory of Open Access Journals (Sweden)

    Gary S. Michelfelder


    Full Text Available To better understand the origin of across-strike K2O enrichments in silicic volcanic rocks from the Andean Central Volcanic Zone, we compare geochemical data for Quaternary volcanic rocks erupted from three well-characterized composite volcanoes situated along a southeast striking transect between 21° and 22° S latitude (Aucanquilcha, Ollagüe, and Uturuncu. At a given SiO2 content, lavas erupted with increasing distance from the arc front display systematically higher K2O, Rb, Th, Y, REE and HFSE contents; Rb/Sr ratios; and Sr isotopic ratios. In contrast, the lavas display systematically lower Al2O3, Na2O, Sr, and Ba contents; Ba/La, Ba/Zr, K/Rb, and Sr/Y ratios; Nd isotopic ratios; and more negative Eu anomalies toward the east. We suggest that silicic magmas along the arc front reflect melting of relatively young, mafic composition amphibolitic source rocks and that the mid- to deep-crust becomes increasingly older with a more felsic bulk composition in which residual mineralogies are progressively more feldspar-rich toward the east. Collectively, these data suggest the continental crust becomes strongly hybridized beneath frontal arc localities due to protracted intrusion of primary, mantle-derived basaltic magmas with a diminishing effect behind the arc front because of smaller degrees of mantle partial melting and primary melt generation.

  13. Photonuclear reactions on titanium isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Belyshev, S. S. [Moscow State University (Russian Federation); Dzhilavyan, L. Z. [Russian Academy of Sciences, Institute for Nuclear Research (Russian Federation); Ishkhanov, B. S.; Kapitonov, I. M. [Moscow State University (Russian Federation); Kuznetsov, A. A., E-mail:; Orlin, V. N.; Stopani, K. A. [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)


    The photodisintegration of titanium isotopes in the giant-dipole-resonance energy region is studied by the photon-activation method. Bremsstrahlung photons whose spectrum has the endpoint energy of 55 MeV is used. The yields and integrated cross sections are determined for photoproton reactions on the titanium isotopes {sup 47,48,49,50}Ti. The respective experimental results are compared with their counterparts calculated on the basis of the TALYS code and a combined photonucleon-reaction model. The TALYS code disregards the isospin structure of the giant dipole resonance and is therefore unable to describe the yield of photoproton reactions on the heavy titanium isotopes {sup 49,50}Ti.

  14. Barium isotopes reveal role of ocean circulation on barium cycling in the Atlantic (United States)

    Bates, Stephanie L.; Hendry, Katharine R.; Pryer, Helena V.; Kinsley, Christopher W.; Pyle, Kimberley M.; Woodward, E. Malcolm S.; Horner, Tristan J.


    We diagnose the relative influences of local-scale biogeochemical cycling and regional-scale ocean circulation on Atlantic barium cycling by analysing four new depth profiles of dissolved Ba concentrations and isotope compositions from the South and tropical North Atlantic. These new profiles exhibit systematic vertical, zonal and meridional variations that reflect the influence of both local-scale barite cycling and large-scale ocean circulation. Epipelagic decoupling of dissolved Ba and Si reported previously in the tropics is also found to be associated with significant Ba isotope heterogeneity. As such, we contend that this decoupling originates from the depth segregation of opal and barite formation but is exacerbated by weak vertical mixing. Zonal influence from isotopically-'heavy' water masses in the western North Atlantic evidence the advective inflow of Ba-depleted Upper Labrador Sea Water, which is not seen in the eastern basin or the South Atlantic. Meridional variations in Atlantic Ba isotope systematics below 2000 m appear entirely controlled by conservative mixing. Using an inverse isotopic mixing model, we calculate the Ba isotope composition of the Ba-poor northern end-member as +0.45 ‰ and the Ba-rich southern end-member +0.26 ‰, relative to NIST SRM 3104a. The near-conservative behaviour of Ba below 2000 m indicates that Ba isotopes can serve as an independent tracer of the provenance of northern- versus southern-sourced water masses in the deep Atlantic Ocean. This finding may prove useful in palaeoceanographic studies, should appropriate sedimentary archives be identified, and offers new insights into the processes that cycle Ba in seawater.

  15. Isotope Effect on Electron-Phonon Coupling in Multiband Superconductor MgB2 (United States)

    Mou, Daixiang; Taufour, Valentin; Wu, Yun; Huang, Lunan; Bud'Ko, Serguei; Canfield, Paul; Kaminski, Adam

    We systematically investigate the isotope effect of electron-phonon coupling in multi-band superconductor MgB2 by laser based Angle Resolved Photoemission Spectroscopy. The kink structure around 70 meV on two σ bands, which is caused by electron coupling to E2 g phonon mode, is shifted to higher binding energy in Mg10B2 than that in Mg11B2. The measured shifting energy of 3.5 meV is consistent with theoretical calculation based on harmonic phonon in MgB2. Our temperature dependent measurement also indicates the isotope effect of kink structure is not dependent on superconducting transition.

  16. Investigation of Even-Even Ru Isotopes in Interacting Boson Model-2

    Institute of Scientific and Technical Information of China (English)

    A.H. Yilmaz; M. Kuruoglu


    The interacting boson model of Arima, Iachello, and co-workers is applied to the even ruthenium isotopes,96 Ru ~ 116Ru. Excitation energies, electromagnetic transition strengths, quadrupole and magnetic dipole moments, and △(E2/M1) mixing ratios have been described systematically. Mixed symmetry states are investigated. It is seen that the properties of low-lying levels in these isotopes, for which the comparison between experiment and theory is possible,can be satisfactorily characterized by the Interacting Boson Model-2.

  17. Unexpected variations in the triple oxygen isotope composition of stratospheric carbon dioxide


    Wiegel, Aaron A.; Cole, Amanda S.; Hoag, Katherine J.; Atlas, Elliot L.; Schauffler, Sue M.; Boering, Kristie A.


    We report observations of stratospheric CO2 that reveal surprisingly large anomalous enrichments in 17O that vary systematically with latitude, altitude, and season. The triple isotope slopes reached 1.95 ± 0.05(1σ) in the middle stratosphere and 2.22 ± 0.07 in the Arctic vortex versus 1.71 ± 0.03 from previous observations and a remarkable factor of 4 larger than the mass-dependent value of 0.52. Kinetics modeling of laboratory measurements of photochemical ozone–CO2 isotope exchange demonst...

  18. First measurement of beta decay half-lives in neutron-rich Tl and Bi isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Benzoni, G., E-mail: [Istituto Nazionale di Fisica Nucleare, Sezione di Milano, Milano (Italy); Morales, A.I. [Istituto Nazionale di Fisica Nucleare, Sezione di Milano, Milano (Italy); Valiente-Dobon, J.J. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Legnaro, Legnaro (Italy); Gottardo, A. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Legnaro, Legnaro (Italy); Dipartimento di Fisica dell' Universita degli Studi di Padova, Padova (Italy); Bracco, A.; Camera, F.; Crespi, F.C.L.; Corsi, A.M.; Leoni, S. [Istituto Nazionale di Fisica Nucleare, Sezione di Milano, Milano (Italy); Dipartimento di Fisica dell' Universita degli Studi di Milano, Milano (Italy); Million, B. [Istituto Nazionale di Fisica Nucleare, Sezione di Milano, Milano (Italy); Nicolini, R. [Istituto Nazionale di Fisica Nucleare, Sezione di Milano, Milano (Italy); Dipartimento di Fisica dell' Universita degli Studi di Milano, Milano (Italy); Wieland, O. [Istituto Nazionale di Fisica Nucleare, Sezione di Milano, Milano (Italy); Gadea, A. [Instituto de Fisica Corpuscular, CSIC-Universitat de Valencia, Valencia (Spain); Lunardi, S. [Istituto Nazionale di Fisica Nucleare, Sezione di Padova, Padova (Italy); Dipartimento di Fisica dell' Universita degli Studi di Padova, Padova (Italy); Boutachkov, P. [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Bruce, A.M. [School of Computing, Engineering and Mathematics, University of Brighton, Brighton (United Kingdom); Gorska, M. [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Grebosz, J. [Niewodniczanski Institute of Nuclear Physics, Polish Academy of Science, Krakow (Poland); and others


    Neutron-rich isotopes around lead, beyond N=126, have been studied exploiting the fragmentation of an uranium primary beam at the FRS-RISING setup at GSI. For the first time {beta}-decay half-lives of {sup 219}Bi and {sup 211,212,213}Tl isotopes have been derived. The half-lives have been extracted using a numerical simulation developed for experiments in high-background conditions. Comparison with state of the art models used in r-process calculations is given, showing a systematic underestimation of the experimental values, at variance from close-lying nuclei.

  19. Non-linear Isotope Effects

    DEFF Research Database (Denmark)

    Schmidt, Johan Albrecht

    The isotopic fractionation associated with photodissociation of N2O, OCS and CO2, at different altitudes in Earth’s atmosphere, is investigated theoretically using constructed quantum mechanical models of the dissociation processes (i.e. potential energy surfaces and relevant coupling elements...... or moderate, and overall sulfur fractionation in the stratosphere is very weak which does not exclude OCS from being an acceptable background the Stratospheric Sulfate Aerosol layer. (iii) CO2 photolysis in the upper stratosphere and lower mesosphere is highly fractionating in both isotopes, enriching...

  20. The separation of stable isotopes of carbon (United States)

    Oziashvili, E. D.; Egiazarov, A. S.


    The present state of work on the separation of carbon isotopes by diffusion, fractional distillation, chemical isotopic ex