High Prandtl number effect on Rayleigh-Bénard convection heat transfer at high Rayleigh number
Ma, Li; Li, Jing; Ji, Shui; Chang, Huajian
2017-02-01
This paper represents results of the Rayleigh-Bénard convection heat transfer in silicon oil confined by two horizontal plates, heated from below, and cooled from above. The Prandtl numbers considered as 100-10,000 corresponding to three types of silicon oil. The experiments covered a range of Rayleigh numbers from 2.14·109 to 2.27·1013. The data points that the Nusselt number dependents on the Rayleigh number, which is asymptotic to a 0.248 power. Furthermore, the experiment results can fit the data in low Rayleigh number well.
High Rayleigh number convection numerical experiments
Verzicco, Roberto
2002-03-01
Numerical experiments on the flow developing in a cylindrical cell of aspect ratio Γ = 1/2 heated from below and cooled from above, are conducted for Rayleigh numbers (Ra) ranging from 2 x 10^6 up to 2 x 10^11. The aim of the present study is to numerically replicate the experiments by Roche et al. (2001) and Niemela et al. (2000) performed using gaseous helium close to the critical point as working fluid (Pr = 0.7). The numerical simulation permitted us to generate a large data base which was validated by the experimental results and, on the other hand, provided physical insights which are missed by the experimental approaches usually limited to pointwise temperature and global heat exchange measurements. Attention is focussed on the presence of large-scale structures whose characterization is important owing to the introduction of constant `winds' sweeping the plates and generating viscous and thermal boundary layers. The analysis of instantaneous snapshots clearly indicates that the topology of the recirculating large scale structures is quite different with respect to what is commonly observed in Γ = 1 cells where a unique large scale recirculation structure completely fills the fluid volume (e.g. Verzicco & Camussi, 1999). It is shown that a transition occurs at about Ra = 10^9; at lower Ra the flow is characterized by the presence of two counter-rotating toroidal rings attached to the horizontal plates. At larger Ra, in contrast, the most intense structure consists of two counter-rotating rolls of unitary aspect ratio. The two types of flow, which co-exists in the range 10^9 < Ra < 10^10, determine different properties of both the thermal and the viscous boundary layers. Indeed, even if the limited range of Ra analyzed in the present simulation does not allow the presence of a transition to be clearly observed in the Nu vs Ra diagram, the proposed scenario is confirmed by the direct analysis of the boundary layer thicknesses and of the kinetic energy and
Rotating thermal convection at very large Rayleigh numbers
Weiss, Stephan; van Gils, Dennis; Ahlers, Guenter; Bodenschatz, Eberhard
2016-11-01
The large scale thermal convection systems in geo- and astrophysics are usually influenced by Coriolis forces caused by the rotation of their celestial bodies. To better understand the influence of rotation on the convective flow field and the heat transport at these conditions, we study Rayleigh-Bénard convection, using pressurized sulfur hexaflouride (SF6) at up to 19 bars in a cylinder of diameter D=1.12 m and a height of L=2.24 m. The gas is heated from below and cooled from above and the convection cell sits on a rotating table inside a large pressure vessel (the "Uboot of Göttingen"). With this setup Rayleigh numbers of up to Ra =1015 can be reached, while Ekman numbers as low as Ek =10-8 are possible. The Prandtl number in these experiment is kept constant at Pr = 0 . 8 . We report on heat flux measurements (expressed by the Nusselt number Nu) as well as measurements from more than 150 temperature probes inside the flow. We thank the Deutsche Forschungsgemeinschaft (DFG) for financial support through SFB963: "Astrophysical Flow Instabilities and Turbulence". The work of GA was supported in part by the US National Science Foundation through Grant DMR11-58514.
Convection in an ideal gas at high Rayleigh numbers.
Tilgner, A
2011-08-01
Numerical simulations of convection in a layer filled with ideal gas are presented. The control parameters are chosen such that there is a significant variation of density of the gas in going from the bottom to the top of the layer. The relations between the Rayleigh, Peclet, and Nusselt numbers depend on the density stratification. It is proposed to use a data reduction which accounts for the variable density by introducing into the scaling laws an effective density. The relevant density is the geometric mean of the maximum and minimum densities in the layer. A good fit to the data is then obtained with power laws with the same exponent as for fluids in the Boussinesq limit. Two relations connect the top and bottom boundary layers: The kinetic energy densities computed from free fall velocities are equal at the top and bottom, and the products of free fall velocities and maximum horizontal velocities are equal for both boundaries.
Structure of Flame Balls at Low Lewis-Number
Weiland, Karen J.; Ronney, Paul
1998-01-01
The Structure of Flame Balls at Low Lewis-Number (SOFBALL) experiment explored the behavior of a newly discovered flame phenomena called "flame balls." These spherical, stable, stationary flame structures, observed only in microgravity, provide a unique opportunity to study the interactions of the two most important processes necessary for combustion (chemical reaction and heat and mass transport) in the simplest possible configuration. The previously unobtainable experimental data provided a comparison with models of flame stability and flame propagation limits that are crucial both in assessing fire safety and in designing efficient, clean-burning combustion engines.
Numerical simulation of Martian historical dynamo: Impact of the Rayleigh number on the dynamo state
WANG TianYuan; KUANG WeiJia; MA ShiZhuang
2009-01-01
The observed Mars remnant magnetism suggests that there was an active dynamo in the Martian core.We use the MoSST core dynamics model to simulate the Martian historical dynamo,focusing on the variation of the dynamo states with the Rayleigh number Ra (a non-dimensional parameter describing the buoyancy force in the core).Our numerical results show that the mean field length scale does not vary monotonically with the Rayleigh number,and the field morphology at the core mantle boundary changes with Rayleigh number.In particular,it drifts westward with a speed decreasing with Rayleigh number.
Numerical simulation of Martian historical dynamo:Impact of the Rayleigh number on the dynamo state
无
2009-01-01
The observed Mars remnant magnetism suggests that there was an active dynamo in the Martian core. We use the MoSST core dynamics model to simulate the Martian historical dynamo, focusing on the variation of the dynamo states with the Rayleigh number Ra (a non-dimensional parameter describing the buoyancy force in the core). Our numerical results show that the mean field length scale does not vary monotonically with the Rayleigh number, and the field morphology at the core mantle boundary changes with Rayleigh number. In particular, it drifts westward with a speed decreasing with Rayleigh number.
Critical Magnetic Number in the MHD Rayleigh-Taylor instability
Wang, Yanjin
2010-01-01
We reformulate in Lagrangian coordinates the two-phase free boundary problem for the equations of Magnetohydrodynamics in a infinite slab, which is incompressible, viscous and of zero resistivity, as one for the Navier-Stokes equations with a force term induced by the fluid flow map. We study the stabilized effect of the magnetic field for the linearized equations around the steady-state solution by assuming that the upper fluid is heavier than the lower fluid, $i. e.$, the linear Rayleigh-Taylor instability. We identity the critical magnetic number $|B|_c$ by a variational problem. For the cases $(i)$ the magnetic number $\\bar{B}$ is vertical in 2D or 3D; $(ii)$ $\\bar{B}$ is horizontal in 2D, we prove that the linear system is stable when $|\\bar{B}|\\ge |B|_c$ and is unstable when $|\\bar{B}|<|B|_c$. Moreover, for $|\\bar{B}|<|B|_c$ the vertical $\\bar{B}$ stabilizes the low frequency interval while the horizontal $\\bar{B}$ stabilizes the high frequency interval, and the growth rate of growing modes is bou...
Reynolds and Atwood Numbers Effects on Homogeneous Rayleigh Taylor Instability
Aslangil, Denis; Livescu, Daniel; Banerjee, Arindam
2015-11-01
The effects of Reynolds and Atwood numbers on turbulent mixing of a heterogeneous mixture of two incompressible, miscible fluids with different densities are investigated by using high-resolution Direct Numerical Simulations (DNS). The flow occurs in a triply periodic 3D domain, with the two fluids initially segregated in random patches, and turbulence is generated in response to buoyancy. In turn, stirring produced by turbulence breaks down the scalar structures, accelerating the molecular mixing. Statistically homogeneous variable-density (VD) mixing, with density variations due to compositional changes, is a basic mixing problem and aims to mimic the core of the mixing layer of acceleration driven Rayleigh Taylor Instability (RTI). We present results covering a large range of kinematic viscosity values for density contrasts including small (A =0.04), moderate (A =0.5), and high (A =0.75 and 0.9) Atwood numbers. Particular interest will be given to the structure of the turbulence and mixing process, including the alignment between various turbulence and scalar quantities, as well as providing fidelity data for verification and validation of mix models. Arindam Banerjee acknowledges support from NSF CAREER award # 1453056.
Gonzalez, C. M.; Sanchez, D. A.; Yuen, D. A.; Wright, G. B.; Barnett, G. A.
2010-12-01
As computational modeling became prolific throughout the physical sciences community, newer and more efficient ways of processing large amounts of data needed to be devised. One particular method for processing such large amounts of data arose in the form of using a graphics processing unit (GPU) for calculations. Computational scientists were attracted to the GPU as a computational tool as the performance, growth, and availability of GPUs over the past decade increased. Scientists began to utilize the GPU as the sole workhorse for their brute force calculations and modeling. The GPUs, however, were not originally designed for this style of use. As a result, difficulty arose when trying to find a use for the GPU from a scientific standpoint. A lack of parallel programming routines was the main culprit behind the difficulty in programming with a GPU, but with time and a rise in popularity, NVIDIA released a proprietary architecture named Fermi. The Fermi architecture, when used in conjunction with development tools such as CUDA, allowed the programmer easier access to routines that made parallel programming with the NVIDIA GPUs an ease. This new architecture enabled the programmer full access to faster memory, double-precision support, and large amounts of global memory at their fingertips. Our model was based on using a second-order, spatially correct finite difference method and a third order Runge-Kutta time-stepping scheme for studying the 2D Rayleigh-Benard code. The code extensively used the CUBLAS routines to do the heavy linear algebra calculations. The calculations themselves were completed using a single GPU, the NVDIA C2070 Fermi, which boasts 6 GB of global memory. The overall scientific goal of our work was to apply the Tesla C2070's computing potential to achieve an onset of flow reversals as a function of increasing large Rayleigh numbers. Previous investigations were successful using a smaller grid size of 1000x1999 and a Rayleigh number of 10^9. The
Rayleigh Number Criterion for Formation of A-Segregates in Steel Castings and Ingots
Rad, M. Torabi; Kotas, Petr; Beckermann, C.
2013-01-01
A Rayleigh number-based criterion is developed for predicting the formation of A-segregates in steel castings and ingots. The criterion is calibrated using available experimental data for ingots involving 27 different steel compositions. The critical Rayleigh number above which A-segregates can...... be expected to form is found to be 17 ± 8. The primary source of uncertainty in this critical value is the dendrite arm spacing. The Rayleigh number criterion of the current study is implemented in a casting simulation code and used to predict A-segregates in three case studies involving steel sand castings......, the primary reason for this over-prediction is persumed to be the presence of a central zone of equiaxed grains in the casting sections. A-segregates do not form when the grain structure is equiaxed. © The Minerals, Metals & Materials Society and ASM International 2013...
Optimal Prandtl number for heat transfer in rotating Rayleigh-Bénard convection
Stevens, Richard Johannes Antonius Maria; Clercx, H.J.H.; Lohse, Detlef
2010-01-01
Numerical data for the heat transfer as a function of the Prandtl (Pr)and Rossby (Ro) numbers in turbulent rotating Rayleigh–Bénard convection are presented for Rayleigh number Ra = 10 8 When Ro is xed, the heat transfer enhancement with respect to the non-rotating value shows a maximum as a functi
Microsegregation and Rayleigh number variation during the solidification of superalloy Inconel 718
Ling Wang; Jianxin Dong; Yuliang Tian; Lei Zhang
2008-01-01
The microstructure and composition of the residual liquid at different temperatures were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray spectrometer (EDX) associated with the Thermo-calc software calculation of the equilibrium phase diagrams of Inconel 718 and segregated liquid. The liquid density difference and Rayleigh number variation dur-ing solidification were estimated as well. It is found that the heavy segregation of Nb in liquid prompts the precipitation of δ and Laves phase directly from liquid and the resultant quenched liquid microstructure consists of pro-eutectic γ+eutectic, or complete eutectic according to the content of Nb from low to high. The liquid density increases with decreasing temperature during the solidi-fication of Inconel 718 and the liquid density difference is positive. The largest relative Rayleigh number occurs at 1320℃ when the liquid fraction is about 40vol%.
Wang Ling
2009-08-01
Full Text Available The interdendritic segregation along the mushy zone of directionally solidifi ed superalloy Inconel 718 has been measured by scanning electron microscope (SEM and energy dispersion analysis spectrometry (EDAXtechniques and the corresponding liquid composition profile was presented. The liquid density and Rayleigh number (Ra profi les along the mushy zone were calculated as well. It was found that the liquid density difference increased from top to bottom in the mushy zone and there was no density inversion due to the segregation of Nb and Mo. However carbide formation in the freezing range and the preferred angle of the orientated dendrite array could prompt the fl uid fl ow in the mushy zone although there was no liquid density inversion. The largest relative Rayleigh number appeared at 1,326 篊 for Inconel 718 where the fl uid fl ow most easily occurred.
Wang Ling; Dong Jianxin; Liu Lin; Zhang Lei
2009-01-01
The interdendritic segregation along the mushy zone of directionally solidified superalloy Inconel 718has been measured by scanning electron microscope (SEM) and energy dispersion analysis spectrometry (EDAX)techniques and the corresponding liquid composition profile was presented. The liquid density and Rayleigh number (Ra) profiles along the mushy zone were calculated as well. It was found that the liquid density difference increased from top to bottom in the mushy zone and there was no density inversion due to the segregation of Nb and Mo. However carbide formation in the freezing range and the preferred angle of the odentated dendrite array could prompt the fluid flow in the mushy zone although there was no liquid density inversion. The largest relative Rayleigh number appeared at 1,326℃ for Inconel 718 where the fluid flow most easily occurred.
Optimal Prandtl number for heat transfer in rotating Rayleigh-Benard convection
Stevens, Richard J A M; Lohse, Detlef
2009-01-01
Numerical data for the heat transfer as a function of the Prandtl (Pr) and Rossby (Ro) numbers in turbulent rotating Rayleigh-Benard convection are presented for Rayleigh number Ra = 10^8. When Ro is fixed the heat transfer enhancement with respect to the non-rotating value shows a maximum as function of Pr. This maximum is due to the reduced efficiency of Ekman pumping when Pr becomes too small or too large. When Pr becomes small, i.e. for large thermal diffusivity, the heat that is carried by the vertical vortices spreads out in the middle of the cell, and Ekman pumping thus becomes less efficient. For higher Pr the thermal boundary layers (BLs) are thinner than the kinetic BLs and therefore the Ekman vortices do not reach the thermal BL. This means that the fluid that is sucked into the vertical vortices is colder than for lower Pr which limits the efficiency of the upwards heat transfer.
Kumar, Arvind; Dutta, Pradip [Department of Mechanical Engineering, Indian Institute of Science, Bangalore 560012 (India)], E-mail: pradip@mecheng.iisc.ernet.in
2008-08-07
Movement of solid crystals in the form of dendrite fragments causes severe macro-segregation in solidified products. Dendrite fragmentation in the developing mushy zone occurs as a result of remelting (causing dissolution) and subsequent breakage of dendritic side arms from the dendritic stalks. An understanding of the mechanisms of dendrite fragmentation is essential for predicting the transport of fragmented solid crystals for possible control of macro-segregation. In this work, a Rayleigh number based fragmentation criterion is developed for detachment of dendrites from the developing mushy zone, which determines the conditions favourable for fragmentation of dendrites. The Rayleigh number, defined in this paper, measures the ratio of the driving buoyancy force for the flow in the mushy zone to the retarding frictional force associated with the permeability of the mush. The criterion developed is a function of the concentration difference, liquid fraction, permeability, growth rate of mushy layer and thermophysical properties of the material.
Johnston, Stephen; Fonda, Enrico; Sreenivasan, Katepalli R.; Ranjan, Devesh
2016-11-01
Both experiments and simulations on Rayleigh-Bénard convection with fluids of Prandtl numbers 5 and below have shown that the container shape influences the flow structure. Here, we investigate similar dependences of convection of fluids with Prandtl numbers of up to 104. The convection cells have aspect ratio of order unity, and we use cubic and cylindrical shapes. Visual analysis using a noninvasive photochromic dye technique indicates the distinct large-scale flow patterns in both square and cylindrical test cells. The stability of these flow patterns is explored. Also presented are results on the Nusselt-Rayleigh scaling for moderate Rayleigh numbers.
The sensitivity of rotating Rayleigh-Bénard convection to the Ekman number
Plumley, Meredith; Julien, Keith; Marti, Philippe; Stellmach, Stephan; Aurnou, Jonathan; Hawkins, Emily
2016-11-01
Many geophysical and astrophysical applications of rotating Rayleigh-Bénard convection require no-slip boundaries. These boundaries lead to Ekman pumping, which has a dominant impact on the heat transport and affects the transfer of energy within the system. Here I present the 2D surface of the Nusselt number as a function of the Rayleigh number (Ra) and the Ekman number (E) for no-slip boundaries, generated through a combination of results from experiments, DNS, rescaled DNS, and asymptotic simulations. The Ra - E space is mapped from the transition of the weakly-rotating into the rotation-dominated regime (E 10-7) to lower E in the rapidly-rotating regime (E 10-11). This exploration provides insight into the sensitivity of the flow to the Ekman number, specifically the effect of the boundaries on the types and ranges of flow structures and the difference between stress-free and no-slip boundaries at low E, a regime of interest for modeling planetary interiors.
Critical Rayleigh number of for error function temperature profile with a quasi-static assumption
Kerr, Oliver S
2016-01-01
When a semi-infinite body is heated from below by a sudden increase in temperature (or cooled from above) an error function temperature profile grows as the heat diffuses into the fluid. The stability of such a profile is investigated using a large-wavelength asymptotic expansion under the quasi-static, or frozen-time, approximation. The critical Rayleigh number for this layer is found to be $Ra=\\pi^{1/2}$ based on the length-scale $(\\kappa t)^{1/2}$ where $\\kappa$ is the thermal diffusivity and $t$ the time since the onset of heating.
Temperature variance profiles of turbulent thermal convection at high Rayleigh numbers
He, Xiaozhou; Bodenschatz, Eberhard; Ahlers, Guenter
2016-11-01
We present measurements of the Nusselt number Nu , and of the temperature variance σ2 as a function of vertical position z, in turbulent Rayleigh-Bénard convection of two cylindrical samples with aspect ratios (diameter D/height L) Γ = 0 . 50 and 0 . 33 . Both samples had D = 1 . 12 m but different L. We used compressed SF6 gas at pressures up to 19 bars as the fluid. The measurements covered the Rayleigh-number range 1013 < Ra < 5 ×1015 at a Prandtl number Pr = 0 . 80 . Near the side wall we found that σ2 is independent of Ra when plotted as a function of z / λ where λ ≡ L / (2 Nu) is a thermal boundary-layer thickness. The profiles σ2 (z / λ) for the two Γ values overlapped and followed a logarithmic function for 20 z / λ 120 . With the observed "-1"-scaling of the temperature power spectra and on the basis of the Perry-Townsend similarity hypothesis, we derived a fitting function σ2 =p1 ln (z / λ) +p2 +p3(z / λ) - 0 . 5 which describes the σ2 data up to z / λ = 1500 . Supported by the Max Planck Society, the Volkswagenstiftung, the DFD Sonderforschungsbereich SFB963, and NSF Grant DMR11-58514.
Homoclinic bifurcations in low-Prandtl-number Rayleigh-B\\'{e}nard convection with uniform rotation
Maity, P; Pal, P
2014-01-01
We present results of direct numerical simulations on homoclinic gluing and ungluing bifurcations in low-Prandtl-number ($ 0 \\leq Pr \\leq 0.025 $) Rayleigh-B\\'{e}nard system rotating slowly and uniformly about a vertical axis. We have performed simulations with \\textit{stress-free} top and bottom boundaries for several values of Taylor number ($5 \\leq Ta \\leq 50$) near the instability onset. We observe a single homoclinic ungluing bifurcation, marked by the spontaneous breaking of a larger limit cycle into two limit cycles with the variation of the reduced Rayleigh number $r$ for smaller values of $Ta (< 25)$. A pair of homoclinic bifurcations, instead of one bifurcation, is observed with variation of $r$ for slightly higher values of $Ta$ ($25 \\leq Ta \\leq 50$) in the same fluid dynamical system. The variation of the bifurcation threshold with $Ta$ is also investigated. We have also constructed a low-dimensional model which qualitatively captures the dynamics of the system near the homoclinic bifurcations...
Turbulent convection experiment at high Rayleigh number to support CAP1400 IVR strategy
Ma, Li, E-mail: mali@snptrd.com [State Nuclear Hua Qing(Beijing) Nuclear Power Technology R& D Centre Co., Ltd, Building A, State Nuclear Power Research Institute, Future Science & Technology Park, Changping Dist., Beijing 102209 (China); Li, Jing, E-mail: lijing@snptrd.com [State Nuclear Hua Qing(Beijing) Nuclear Power Technology R& D Centre Co., Ltd, Building A, State Nuclear Power Research Institute, Future Science & Technology Park, Changping Dist., Beijing 102209 (China); Ji, Shui, E-mail: jishui@snptrd.com [State Nuclear Hua Qing(Beijing) Nuclear Power Technology R& D Centre Co., Ltd, Building A, State Nuclear Power Research Institute, Future Science & Technology Park, Changping Dist., Beijing 102209 (China); Chang, Huajian, E-mail: changhuajian@snptrd.com [State Nuclear Hua Qing(Beijing) Nuclear Power Technology R& D Centre Co., Ltd, Building A, State Nuclear Power Research Institute, Future Science & Technology Park, Changping Dist., Beijing 102209 (China); Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)
2015-10-15
Highlights: • The facility reached high Ra number at 10{sup 12} of CAP1400 working condition. • The fitting formula Nu = 0.085 × Ra{sup 0.315} was established to calculate the heat flux in the metal layer at high Ra for the CAP1400. • The coupling method can accurately and safely predict the heat flow distribution of metal layer in high Ra number conditions. • The experiment results will predict the relationship between axial and radial heat transfer well. - Abstract: The characteristics of the heat transfer and the calculation of heat flux in metal layer are both the critical problems for in-vessel retention (IVR) strategy. Turbulent convection occurs in the metal layer when the Rayleigh number (Ra) becomes sufficient high. The Globe–Dropkin (G–D) correlation (Globe and Dropkin, 1959) and Chu–Churchill (C–C) correlation (Churchill and Chu, 1975) have been widely used to calculate the heat flux in the metal layer, where the valid range of the Ra is from 1.5 × 10{sup 5} to 6.8 × 10{sup 8} in G–D correlation and less than 10{sup 12} in C–C correlation. However, with the increase of reactor power, both the Rayleigh number and the rate of heat transfer below the bottom of metal layer of the molten pool will increase, and in this case the Rayleigh number even can reach 10{sup 11} for the China Advanced Passive Plant CAP1400. Accordingly, the G–D correlation is not suitable for the CAP1400. Therefore, our experiment purposes are to establish the appropriate correlation at high Ra for the CAP1400 and predict the axial and radial distribution of the heat transfer in the metal layer with the heat transfer behavior of metal layer experiment (HELM) facility. The experiments are divided into two parts. Each part concerns 39 runs and 47 experimental conditions. Its corresponding results are obtained at middle Prandtl number (Pr = 7 for water) and the Nusselt number is found to be proportional to Ra{sup 0.315} in the range 3.93 × 10{sup 8} < Ra < 3.57
Measurements of Molecular Mixing in a High Schmidt Number Rayleigh-Taylor Mixing Layer
Mueschke, N J; Schilling, O; Youngs, D L; Andrews, M
2007-12-03
Molecular mixing measurements are performed for a high Schmidt number (Sc {approx} 10{sup 3}), small Atwood number (A {approx} 7.5 x 10{sup -4}) buoyancy-driven turbulent Rayleigh-Taylor mixing layer in a water channel facility. Salt was added to the top stream to create the desired density difference. The degree of molecular mixing was measured as a function of time by monitoring a diffusion-limited chemical reaction between the two fluid streams. The pH of each stream was modified by the addition of acid or alkali such that a local neutralization reaction occurred as the two fluids molecularly mixed. The progress of this neutralization reaction was tracked by the addition of phenolphthalein - a pH-sensitive chemical indicator - to the acidic stream. Accurately calibrated backlit optical techniques were used to measure the average concentration of the colored chemical indicator. Comparisons of chemical product formation for pre-transitional buoyancy- and shear-driven mixing layers are given. It is also shown that experiments performed at different equivalence ratios (acid/alkali concentration) can be combined to obtain a mathematical relationship between the colored product formed and the density variance. This relationship was used to obtain high-fidelity, quantitative measures of the degree of molecular mixing which are independent of probe resolution constraints. The dependence of such mixing parameters on the Schmidt and Reynolds numbers is examined by comparing the current Sc {approx} 10{sup 3} measurements with Sc = 0.7 gas-phase and Pr = 7 liquid-phase measurements. This comparison indicates that the Schmidt number has a large effect on the bulk quantity of mixed fluid at small Reynolds numbers Re{sub h} < 10{sup 3}. At late times, all mixing parameters indicated a greater degree of molecular mixing and a decreased Schmidt number dependence. Implications for the development and quantitative assessment of turbulent transport and mixing models appropriate for
Experimental investigation of late time Rayleigh-Taylor mixing at high Atwood number
Suchandra, Prasoon; Mikhaeil, Mark; Ranjan, Devesh
2016-11-01
Dynamics of late time, high Reynolds number (Re >20000) Rayleigh-Taylor (RT) mixing is studied using statistically steady experiments performed in a multi-layer gas tunnel. The density ratio of air and air-Helium mixture used in the present experiment results in an Atwood number 0.73. Three types of diagnostics - back-lit visualization, hot-wire anemometry and stereo particle image velocimetry (S-PIV) - are employed to obtain mixing width, velocity and density fields, with S-PIV employed for the first time for such experimental conditions. Velocity and density statistics, and their correlations (u', v', w',ρ' ,ρ'v') are presented. Calculations of probability density functions (p.d.f.s) and energy spectra are made to provide further insight into the flow physics. Energy budget of the flow is also discussed.
Stability of High Rayleigh-Number Equilibrium Solutions of the Darcy-Oberbeck-Boussinesq Equations
Wen, Baole; Corson, Lindsey; Chini, Gregory
2013-11-01
There has been significant renewed interest in dissolution-driven convection in porous layers owing to the potential impact of this process on carbon dioxide storage in terrestrial aquifers. In this talk, we present some numerically-exact equilibrium solutions to the porous medium convection problem in small laterally-periodic domains at high Rayleigh number Ra . The ``uni-cellular'' equilibrium solutions first found by Corson and Chini (2011) by solving the steady Darcy-Oberbeck-Boussinesq equations are recovered and, in the interior (i.e. away from upper and lower boundary layers), are shown to have the same horizontal-mean structure as the ``heat-exchanger'' solutions identified by Hewitt et al. (2012). Secondary stability analysis of the steady solutions is performed, and implications for high-Ra porous medium convection are discussed. Funding from NSF Award 0928098 is gratefully acknowledged.
Italia, Matteo; Croccolo, Fabrizio; Scheffold, Frank; Vailati, Alberto
2014-10-01
Convection in an inclined layer of fluid is affected by the presence of a component of the acceleration of gravity perpendicular to the density gradient that drives the convective motion. In this work we investigate the solutal convection of a colloidal suspension characterized by a negative Soret coefficient. Convection is induced by heating the suspension from above, and at large solutal Rayleigh numbers (of the order of 10(7)-10(8)) convective spoke patterns form. We show that in the presence of a marginal inclination of the cell as small as 19 mrad the isotropy of the spoke pattern is broken and the convective patterns tend to align in the direction of the inclination. At intermediate inclinations of the order of 33 mrad ordered square patterns are obtained, while at inclination of the order of 67 mrad the strong shear flow determined by the inclination gives rise to ascending and descending sheets of fluid aligned parallel to the direction of inclination.
Ground Boundary Conditions for Thermal Convection Over Horizontal Surfaces at High Rayleigh Numbers
Hanjalić, K.; Hrebtov, M.
2016-07-01
We present "wall functions" for treating the ground boundary conditions in the computation of thermal convection over horizontal surfaces at high Rayleigh numbers using coarse numerical grids. The functions are formulated for an algebraic-flux model closed by transport equations for the turbulence kinetic energy, its dissipation rate and scalar variance, but could also be applied to other turbulence models. The three-equation algebraic-flux model, solved in a T-RANS mode ("Transient" Reynolds-averaged Navier-Stokes, based on triple decomposition), was shown earlier to reproduce well a number of generic buoyancy-driven flows over heated surfaces, albeit by integrating equations up to the wall. Here we show that by using a set of wall functions satisfactory results are found for the ensemble-averaged properties even on a very coarse computational grid. This is illustrated by the computations of the time evolution of a penetrative mixed layer and Rayleigh-Bénard (open-ended, 4:4:1 domain) convection, using 10 × 10 × 100 and 10 × 10 × 20 grids, compared also with finer grids (e.g. 60 × 60 × 100), as well as with one-dimensional treatment using 1 × 1 × 100 and 1 × 1 × 20 nodes. The approach is deemed functional for simulations of a convective boundary layer and mesoscale atmospheric flows, and pollutant transport over realistic complex hilly terrain with heat islands, urban and natural canopies, for diurnal cycles, or subjected to other time and space variations in ground conditions and stratification.
The Spectral Amplitude of Stellar Convection and Its Scaling in the High-Rayleigh-number Regime
Featherstone, Nicholas A.; Hindman, Bradley W.
2016-02-01
Convection plays a central role in the dynamics of any stellar interior, and yet its operation remains largely hidden from direct observation. As a result, much of our understanding concerning stellar convection necessarily derives from theoretical and computational models. The Sun is, however, exceptional in that regard. The wealth of observational data afforded by its proximity provides a unique test bed for comparing convection models against observations. When such comparisons are carried out, surprising inconsistencies between those models and observations become apparent. Both photospheric and helioseismic measurements suggest that convection simulations may overestimate convective flow speeds on large spatial scales. Moreover, many solar convection simulations have difficulty reproducing the observed solar differential rotation owing to this apparent overestimation. We present a series of three-dimensional stellar convection simulations designed to examine how the amplitude and spectral distribution of convective flows are established within a star’s interior. While these simulations are nonmagnetic and nonrotating in nature, they demonstrate two robust phenomena. When run with sufficiently high Rayleigh number, the integrated kinetic energy of the convection becomes effectively independent of thermal diffusion, but the spectral distribution of that kinetic energy remains sensitive to both of these quantities. A simulation that has converged to a diffusion-independent value of kinetic energy will divide that energy between spatial scales such that low-wavenumber power is overestimated and high-wavenumber power is underestimated relative to a comparable system possessing higher Rayleigh number. We discuss the implications of these results in light of the current inconsistencies between models and observations.
A Validated All-Pressure Fluid Drop Model and Lewis Number Effects for a Binary Mixture
Harstad, K.; Bellan, J.
1999-01-01
The differences between subcritical liquid drop and supercritical fluid drop behavior are discussed. Under subcritical, evaporative high emission rate conditions, a film layer is present in the inner part of the drop surface which contributes to the unique determination of the boundary conditions; it is this film layer which contributes to the solution's convective-diffusive character. In contrast, under supercritical condition as the boundary conditions contain a degree of arbitrariness due to the absence of a surface, and the solution has then a purely diffusive character. Results from simulations of a free fluid drop under no-gravity conditions are compared to microgravity experimental data from suspended, large drop experiments at high, low and intermediary temperatures and in a range of pressures encompassing the sub-and supercritical regime. Despite the difference between the conditions of the simulations and experiments (suspension vs. free floating), the time rate of variation of the drop diameter square is remarkably well predicted in the linear curve regime. The drop diameter is determined in the simulations from the location of the maximum density gradient, and agrees well with the data. It is also shown that the classical calculation of the Lewis number gives qualitatively erroneous results at supercritical conditions, but that an effective Lewis number previously defined gives qualitatively correct estimates of the length scales for heat and mass transfer at all pressures.
NASA Lewis Stirling SPRE testing and analysis with reduced number of cooler tubes
Wong, W.A.; Cairelli, J.E.; Swec, D.M.; Doeberling, T.J.; Lakatos, T.F. [National Aeronautics and Space Administration, Cleveland, OH (United States). Lewis Research Center; Madi, F.J. [Sverdrup Technology, Inc., Cleveland, OH (United States). Lewis Research Center Group
1994-09-01
Free-piston Stirling power converters are a candidate for high capacity space power applications. The Space Power Research Engine (SPRE), a free-piston Stirling engine coupled with a linear alternator, is being tested at the NASA Lewis Research Center in support of the Civil Space Technology Initiative. The SPRE is used as a test bed for evaluating converter modifications which have the potential to improve converter performance and for validating computer code predictions. Reducing the number of cooler tubes on the SPRE has been identified as a modification with the potential to significantly improve power and efficiency. This paper describes experimental tests designed to investigate the effects of reducing the number of cooler tubes on converter power, efficiency and dynamics. Presented are test results from the converter operating with a reduced number of cooler tubes and comparisons between this data and both baseline test data and computer code predictions.
NASA Lewis Stirling SPRE testing and analysis with reduced number of cooler tubes
Wong, Wayne A.; Cairelli, James E.; Swec, Diane M.; Doeberling, Thomas J.; Lakatos, Thomas F.; Madi, Frank J.
1992-08-01
Free-piston Stirling power converters are candidates for high capacity space power applications. The Space Power Research Engine (SPRE), a free-piston Stirling engine coupled with a linear alternator, is being tested at the NASA Lewis Research Center in support of the Civil Space Technology Initiative. The SPRE is used as a test bed for evaluating converter modifications which have the potential to improve the converter performance and for validating computer code predictions. Reducing the number of cooler tubes on the SPRE has been identified as a modification with the potential to significantly improve power and efficiency. Experimental tests designed to investigate the effects of reducing the number of cooler tubes on converter power, efficiency and dynamics are described. Presented are test results from the converter operating with a reduced number of cooler tubes and comparisons between this data and both baseline test data and computer code predictions.
Understanding the impact of initial condition on low Atwood number Rayleigh-Taylor driven flows
Kuchibhatla, Sarat Chandra; Ranjan, Devesh
2012-11-01
Experimental investigation of the effects of initial conditions on Rayleigh-Taylor instability was performed using the Water Channel facility at Texas A&M University. Hot and cold water (with a temperature difference of ~7-8 degrees C) selected as working fluids were unstably stratified using a splitter plate resulting in a low Atwood number of ~0.0015. Using a servo controlled flapper system the effect of initial conditions is studied using different diagnostics such as optical imaging, thermocouples and hot-wire anemometry. A parametric study comprising of up to 10 modes of the initial condition was performed by varying the number of modes as well as modal composition (i . e . ratio of wavenumbers and phase differences). Variation of density, temperature and velocity field in the linear and non-linear stages of RT growth was recorded and analyzed. At non-dimensional time, t* = t (At g /H)0.5= 1.3, where t is the time, H is the width of the Channel, and g is the acceleration due to gravity, power spectra of the non-dimensional density showed fine-scale components that are dependent upon the initial condition. Plots of scalar dissipation and mixing rate indicate greater dissipation rate at early times that tends to asymptote to the order of kinematic viscosity at late times.
1987-01-01
studies, in general, have been much more limited. This thesis concentrates on the high Rayleigh number/small- gap flow regime. It has been found that...just prior to it. Analytical approaches, especially with regard to the high Rayleigh number/small- gap flow regime, have been virtually unexplored. To
Direct numerical simulation of a small Atwood number Rayleigh-Taylor instability-driven mixing layer
Mueschke, Nicholas; Schilling, Oleg; Andrews, Malcolm
2005-11-01
A direct numerical simulation (DNS) of a small Atwood number Rayleigh-Taylor mixing layer was performed using a spectral/compact-difference scheme. The initial conditions were parameterized from interfacial and velocity perturbations measured from water channel experiments at Texas A&M University. Turbulence and mixing statistics, as well as energy spectra, obtained from experimental measurements are compared with those from the DNS to validate the use of experimental measurements as computational initial conditions. The experimental and numerical data are used to examine the transitional dynamics of the mixing layer. The DNS results indicate that initial conditions including both interfacial and velocity perturbations are required to accurately simulate the flow. This research was sponsored by the U.S. DOE National Nuclear Security Administration under the Stewardship Science Academic Alliances program through DOE Research Grant #DE-FG03- 02NA00060. This work was also performed under the auspices of the U.S. Department of Energy by the University of California, Lawrence Livermore National Laboratory under Contract No. W- 7405-Eng-48. UCRL-ABS-214352.
Detailed Measurements of Turbulent Rayleigh-Taylor Mixing at Large and Small Atwood Numbers
Malcolm J. Andrews, Ph.D.
2004-12-14
This project has two major tasks: Task 1. The construction of a new air/helium facility to collect detailed measurements of Rayleigh-Taylor (RT) mixing at high Atwood number, and the distribution of these data to LLNL, LANL, and Alliance members for code validation and design purposes. Task 2. The collection of initial condition data from the new Air/Helium facility, for use with validation of RT simulation codes at LLNL and LANL. Also, studies of multi-layer mixing with the existing water channel facility. Over the last twelve (12) months there has been excellent progress, detailed in this report, with both tasks. As of December 10, 2004, the air/helium facility is now complete and extensive testing and validation of diagnostics has been performed. Currently experiments with air/helium up to Atwood numbers of 0.25 (the maximum is 0.75, but the highest Reynolds numbers are at 0.25) are being performed. The progress matches the project plan, as does the budget, and we expect this to continue for 2005. With interest expressed from LLNL we have continued with initial condition studies using the water channel. This work has also progressed well, with one of the graduate Research Assistants (Mr. Nick Mueschke) visiting LLNL the past two summers to work with Dr. O. Schilling. Several journal papers are in preparation that describe the work. Two MSc.'s have been completed (Mr. Nick Mueschke, and Mr. Wayne Kraft, 12/1/03). Nick and Wayne are both pursuing Ph.D.s' funded by this DOE Alliances project. Presently three (3) Ph.D. graduate Research Assistants are supported on the project, and two (2) undergraduate Research Assistants. During the year two (2) journal papers and two (2) conference papers have been published, ten (10) presentations made at conferences, and three (3) invited presentations.
Effects of non-unity Lewis number of gas-phase species in turbulent nonpremixed sooting flames
Attili, Antonio
2016-02-13
Turbulence statistics from two three-dimensional direct numerical simulations of planar n-heptane/air turbulent jets are compared to assess the effect of the gas-phase species diffusion model on flame dynamics and soot formation. The Reynolds number based on the initial jet width and velocity is around 15, 000, corresponding to a Taylor scale Reynolds number in the range 100 ≤ Reλ ≤ 150. In one simulation, multicomponent transport based on a mixture-averaged approach is employed, while in the other the gas-phase species Lewis numbers are set equal to unity. The statistics of temperature and major species obtained with the mixture-averaged formulation are very similar to those in the unity Lewis number case. In both cases, the statistics of temperature are captured with remarkable accuracy by a laminar flamelet model with unity Lewis numbers. On the contrary, a flamelet with a mixture-averaged diffusion model, which corresponds to the model used in the multi-component diffusion three-dimensional DNS, produces significant differences with respect to the DNS results. The total mass of soot precursors decreases by 20-30% with the unity Lewis number approximation, and their distribution is more homogeneous in space and time. Due to the non-linearity of the soot growth rate with respect to the precursors\\' concentration, the soot mass yield decreases by a factor of two. Being strongly affected by coagulation, soot number density is not altered significantly if the unity Lewis number model is used rather than the mixture-averaged diffusion. The dominant role of turbulent transport over differential diffusion effects is expected to become more pronounced for higher Reynolds numbers. © 2016 The Combustion Institute.
Jiao, Anjun; Zhang, Yuwen; Ma, Hongbin; Critser, John
2009-03-01
Heat and mass transfer in a circular tube subject to the boundary condition of the third kind is investigated. The closed form of temperature and concentration distributions, the local Nusselt number based on the total external heat transfer and convective heat transfer inside the tube, as well as the Sherwood number were obtained. The effects of Lewis number and Biot number on heat and mass transfer were investigated.
Enjilela, Vali; Salimi, Davood; Tavasoli, Ali; Lotfi, Mohsen
2016-02-01
In the present work, the meshless local Petrov-Galerkin vorticity-stream function (MLPG-VF) method is extended to solve two-dimensional laminar fluid flow and heat transfer equations for high Reynolds and Rayleigh numbers. The characteristic-based split (CBS) scheme which uses unity test function is employed for discretization, and the moving least square (MLS) method is used for interpolation of the field variables. Four test cases are considered to evaluate the present algorithm, namely lid-driven cavity flow with Reynolds numbers up to and including 104, flow over a backward-facing step at Reynolds number of 800, natural convection in a square cavity for Rayleigh numbers up to and including 108, and natural convection in a concentric square outer cylinder and circular inner cylinder annulus for Rayleigh numbers up to and including 107. In each case, the result obtained using the proposed algorithm is either compared with the results from the literatures or with those obtained using conventional numerical techniques. The present algorithm shows stable results at lower or equal computational cost compared to the other upwinding schemes usually employed in the MLPG method. Close agreements between the compared results as well as higher accuracy of the proposed method show the ability of this stabilized algorithm.
Goloviznin, V. M.; Korotkin, I. A.; Finogenov, S. A.
2016-12-01
Some numerical results for the two- and three-dimensional de Vahl Davis benchmark are presented. This benchmark describes thermal convection in a square (cubic) cavity with vertical heated walls in a wide range of Rayleigh numbers (104 to 1014), which covers both laminar and highly turbulent f lows. Turbulent f lows are usually described using a turbulence model with parameters that depend on the Rayleigh number and require adjustment. An alternative is Direct Numerical Simulation (DNS) methods, but they demand extremely large computational grids. Recently, there has been an increasing interest in DNS methods with an incomplete resolution, which, in some cases, are able to provide acceptable results without resolving Kolmogorov scales. On the basis of this approach, the so-called parameter-free computational techniques have been developed. These methods cover a wide range of Rayleigh numbers and allow computing various integral properties of heat transport on relatively coarse computational grids. In this paper, a new numerical method based on the CABARET scheme is proposed for solving the Navier-Stokes equations in the Boussinesq approximation. This technique does not involve a turbulence model or any tuning parameters and has a second-order approximation scheme in time and space on uniform and nonuniform grids with a minimal computational stencil. Testing the technique on the de Vahl Davis benchmark and a sequence of refined grids shows that the method yields integral heat f luxes with a high degree of accuracy for both laminar and highly turbulent f lows. For Rayleigh numbers up to 1014, a several percent accuracy is achieved on an extremely coarse grid consisting of 20 × 20 cells refined toward the boundary. No definite or comprehensive explanation of this computational phenomenon has been given. Cautious optimism is expressed regarding the perspectives of using the new method for thermal convection computations at low Prandtl numbers typical of liquid metals.
Kassemi, Siavash A.
1988-01-01
High Rayleigh number convection in a rectangular cavity with insulated horizontal surfaces and differentially heated vertical walls was analyzed for an arbitrary aspect ratio smaller than or equal to unity. Unlike previous analytical studies, a systematic method of solution based on linearization technique and analytical iteration procedure was developed to obtain approximate closed-form solutions for a wide range of aspect ratios. The predicted velocity and temperature fields are shown to be in excellent agreement with available experimental and numerical data.
Wen, Baole
Buoyancy-driven convection in fluid-saturated porous media is a key environmental and technological process, with applications ranging from carbon dioxide storage in terrestrial aquifers to the design of compact heat exchangers. Porous medium convection is also a paradigm for forced-dissipative infinite-dimensional dynamical systems, exhibiting spatiotemporally chaotic dynamics if not "true" turbulence. The objective of this dissertation research is to quantitatively characterize the dynamics and heat transport in two-dimensional horizontal and inclined porous medium convection between isothermal plane parallel boundaries at asymptotically large values of the Rayleigh number Ra by investigating the emergent, quasi-coherent flow. This investigation employs a complement of direct numerical simulations (DNS), secondary stability and dynamical systems theory, and variational analysis. The DNS confirm the remarkable tendency for the interior flow to self-organize into closely-spaced columnar plumes at sufficiently large Ra (up to Ra ≃ 105), with more complex spatiotemporal features being confined to boundary layers near the heated and cooled walls. The relatively simple form of the interior flow motivates investigation of unstable steady and time-periodic convective states at large Ra as a function of the domain aspect ratio L. To gain insight into the development of spatiotemporally chaotic convection, the (secondary) stability of these fully nonlinear states to small-amplitude disturbances is investigated using a spatial Floquet analysis. The results indicate that there exist two distinct modes of instability at large Ra: a bulk instability mode and a wall instability mode. The former usually is excited by long-wavelength disturbances and is generally much weaker than the latter. DNS, strategically initialized to investigate the fully nonlinear evolution of the most dangerous secondary instability modes, suggest that the (long time) mean inter-plume spacing in
Wright, G. B.; Barnett, G. A.; Yuen, D. A.
2009-12-01
We present an efficient method based on fourth order compact finite-differences for simulating three dimensional mantle convection (i.e. Rayleigh-Bénard convection in the infinite Prandtl number limit) with constant viscosity in a rectangular box. In the high Rayleigh number regime, this thermal convection model has recently been shown to exhibit many of the features of turbulent flow that are typically identified with high Reynolds number flow [1]. High order compact finite schemes are known to be particularly good for simulating turbulent flows because of their spectral like resolution [2], which ameliorates dispersion and anisotropy errors. They have also been shown to be much less susceptible than second order schemes to spurious oscillations for transient convection diffusion equations at large Péclet number (as occurs for the temperature equation in the mantle convection model at high Rayleigh number). Finally, high order schemes have been shown to be more efficient than low order methods in terms of degrees of freedom required to attain a specified error level, which is important for reducing memory requirements so simulations can be performed on emerging low-cost high performance computational platforms like graphics processing units (GPUs). We demonstrate the capabilities of our compact fourth order scheme at accurately capturing such phenomena as transient periods of double layered convection[3] (see Figure 1) and flow reversals using far fewer degrees of freedom than required for traditional second order methods. Finally, we discuss the computational cost of the scheme and its efficient implementation on GPUs. References: [1] M. Breuer and U. Hansen, Turbulent convection in the zero Reynolds number limit, EPL, 86, 24004, 2009. [2] S. K. Lele, Compact finite difference schemes with spectral-like resolution, J. Comput. Phys., 103, 16, 1992. [3] A. P. Boss and I. S. Sacks, Time-dependent models of single- and double-layer mantle convection, Nature, 308
Puragliesi, R., E-mail: riccardo.puragliesi@psi.ch [Nuclear Energy and Safety Research Department, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland); Laboratoire d' Ingenierie Numerique, Ecole Polytechnique Federale de Lausanne, Station 9, CH-1015 Lausanne (Switzerland); Dehbi, A., E-mail: abdel.dehbi@psi.ch [Nuclear Energy and Safety Research Department, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland); Leriche, E., E-mail: emmanuel.leriche@univ-st-etienne.fr [Universite de Lyon, F-42023 Saint-Etienne, LMFA-UJM St-Etienne, CNRS UMR 5509 Universite de St-Etienne, 23 rue Docteur Paul Michelon, F-42023 Saint-Etienne (France); Soldati, A., E-mail: soldati@uniud.it [Dipartimento di Energetica e Macchine, Universita di Udine, Via delle Scienze 208, IT-33100 Udine (Italy); Deville, M.O., E-mail: michel.deville@epfl.ch [Laboratoire d' Ingenierie Numerique, Ecole Polytechnique Federale de Lausanne, Station 9, CH-1015 Lausanne (Switzerland)
2011-10-15
Highlights: > 2D study of micro-size particle depletion driven by chaotic natural convective flows in square domains. > Description of velocity and temperature first and second moments with changing in the Rayleigh number. > Strong decoupling between the turbulent kinetic energy and the dissipation rate. > Particle recirculation sustained by the vertical hot boundary layer. > Deposition mostly induced by gravity, thermophoretic and lift forces are negligible. - Abstract: In this work we investigate numerically particle deposition in the buoyancy driven flow of the differentially heated cavity (DHC). We consider two values of the Rayleigh number (Ra = 10{sup 9}, 10{sup 10}) and three values of the particle diameter (d{sub p} = 15, 25, 35 [{mu}m]). We consider the cavity filled with air and particles with the same density of water {rho}{sub w} = 1000 [kg/m{sup 3}] (aerosol). We use direct numerical simulations (DNS) for the continuous phase, and we solve transient Navier-Stokes and energy transport equations written in an Eulerian framework, under the Boussinesq approximation, for the viscous incompressible Newtonian fluid with constant Prandtl number (Pr = 0.71). First- and second-order statistics are presented for the continuous phase as well as important quantities like turbulent kinetic energy (TKE) and temperature variance with the associated production and dissipation fields. The TKE production shows different behaviour at the two Rayleigh numbers. The Lagrangian approach has been chosen for the dispersed phase description. The forces taken into account are drag, gravity, buoyancy, lift and thermophoresis. A first incursion in the sedimentation mechanisms is presented. Current results indicate that the largest contribution to particle deposition is caused by gravitational settling, but a strong recirculating zone, which liftoffs and segregates particles, contributes to decrease settling. Deposition takes place mostly at the bottom wall. The influence of lift
Mueschke, N J; Andrews, M J; Schilling, O
2006-03-24
The initial multi-mode interfacial velocity and density perturbations present at the onset of a small Atwood number, incompressible, miscible, Rayleigh-Taylor instability-driven mixing layer have been quantified using a combination of experimental techniques. The streamwise interfacial and spanwise interfacial perturbations were measured using high-resolution thermocouples and planar laser-induced fluorescence (PLIF), respectively. The initial multi-mode streamwise velocity perturbations at the two-fluid density interface were measured using particle-image velocimetry (PIV). It was found that the measured initial conditions describe an initially anisotropic state, in which the perturbations in the streamwise and spanwise directions are independent of one another. The evolution of various fluctuating velocity and density statistics, together with velocity and density variance spectra, were measured using PIV and high-resolution thermocouple data. The evolution of the velocity and density statistics is used to investigate the early-time evolution and the onset of strongly-nonlinear, transitional dynamics within the mixing layer. The early-time evolution of the density and vertical velocity variance spectra indicate that velocity fluctuations are the dominant mechanism driving the instability development. The implications of the present experimental measurements on the initialization of Reynolds-averaged turbulent transport and mixing models and of direct and large-eddy simulations of Rayleigh-Taylor instability-induced turbulence are discussed.
Mueschke, N J; Andrews, M J; Schilling, O
2005-09-26
The initial multi-mode interfacial velocity and density perturbations present at the onset of a small Atwood number, incompressible, miscible, Rayleigh-Taylor instability-driven mixing layer have been quantified using a combination of experimental techniques. The streamwise interfacial and spanwise interfacial perturbations were measured using high-resolution thermocouples and planar laser-induced fluorescence (PLIF), respectively. The initial multi-mode streamwise velocity perturbations at the two-fluid density interface were measured using particle-image velocimetry (PIV). It was found that the measured initial conditions describe an initially anisotropic state, in which the perturbations in the streamwise and spanwise directions are independent of one another. The evolution of various fluctuating velocity and density statistics, together with velocity and density variance spectra, were measured using PIV and high-resolution thermocouple data. The evolution of the velocity and density statistics is used to investigate the early-time evolution and the onset of strongly-nonlinear, transitional dynamics within the mixing layer. The early-time evolution of the density and vertical velocity variance spectra indicate that velocity fluctuations are the dominant mechanism driving the instability development. The implications of the present experimental measurements on the initialization of Reynolds-averaged turbulent transport and mixing models and of direct and large-eddy simulations of Rayleigh-Taylor instability-induced turbulence are discussed.
Great (Flame) Balls of Fire! Structure of Flame Balls at Low Lewis-number-2 (SOFBALL-2)
Ronney, Paul; Weiland, Karen J.; Over, Ann (Technical Monitor)
2002-01-01
Everyone knows that an automobile engine wastes fuel and energy when it runs with a fuel-rich mixture. 'Lean' burning, mixing in more air and less fuel, is better for the environment. But lean mixtures also lead to engine misfiring and rough operation. No one knows the ultimate limits for lean operation, for 'weak' combustion that is friendly to the environment while still moving us around. This is where the accidental verification of a decades-old prediction may have strong implications for designing and running low-emissions engines in the 21st century. In 1944, Soviet physicist Yakov Zeldovich predicted that stationary, spherical flames are possible under limited conditions in lean fuel-air mixtures. Dr. Paul Ronney of the University of Southern California accidentally discovered such 'flame balls' in experiments with lean hydrogen-air mixtures in 1984 during drop-tower experiments that provided just 2.2 seconds of near weightlessness. Experiments aboard NASA's low-g aircraft confirmed the results, but a thorough investigation was hampered by the aircraft's bumpy ride. And stable flame balls can only exist in microgravity. The potential for investigating combustion at the limits of flammability, and the implications for spacecraft fire safety, led to the Structure of Flame Balls at Low Lewis-number (SOFBALL) experiment flown twice aboard the Space Shuttle on the Microgravity Sciences Laboratory-1 (MSL-1) in 1997. Success there led to the planned reflight on STS-107. Flame balls are the weakest fires yet produced in space or on Earth. Typically each flame ball produced only 1 watt of thermal power. By comparison, a birthday candle produces 50 watts. The Lewis-number measures the rate of diffusion of fuel into the flame ball relative to the rate of diffusion of heat away from the flame ball. Lewis-number mixtures conduct heat poorly. Hydrogen and methane are the only fuels that provide low enough Lewis-numbers to produce stable flame balls, and even then only for
Shiels, C.; Butler, S. L.
2015-09-01
Mantle convection models with a low viscosity asthenosphere and high viscosity surface plates have been shown to produce very large aspect ratio convection cells like those inferred to exist in Earth's mantle and to exhibit two asthenospheric flow regimes. When the surface plate is highly mobile, the plate velocity exceeds the flow velocities in the asthenosphere and the plate drives a Couette-type flow in the asthenospheric channel. For sluggish plates, the flow velocities in the asthenosphere exceed the plate velocity and the asthenospheric flow is more Poiseuille-like. It has been shown that under certain circumstances, flows become increasingly Couette-like as the aspect ratio of the plate is increased in numerical simulations. These models also show an increase in the average surface heat flux with aspect ratio which is counterintuitive, as one would expect that large aspect ratio models would result in older and colder oceanic lithosphere. Previous investigations have used single internal heating rates and Rayleigh numbers and a plate formulation that did not preclude significant deformation within the plate. In this paper, we investigate the conditions necessary for Couette and Poiseuille asthenospheric flows and for surface heat flux to increase with plate aspect ratio by varying the internal heating rate, the Rayleigh number and the representation of surface plates in 2D mantle convection models Plates are represented as a high viscosity layer with (1) a free-slip top surface boundary condition and (2) a force-balance boundary condition that imposes a constant surface velocity within the plate. We find that for models with a free-slip surface boundary condition, the internal heating rate and Rayleigh number do not strongly affect the dominance of Couette or Poiseuille flows in the asthenosphere but the increase in surface heat flux with model aspect ratio in the Poiseuille asthenospheric flow regime increases with internal heating rate. For models using
Mohamed A. Teamah
2011-12-01
Full Text Available Double-diffusive convective flow in an inclined rectangular enclosure with the shortest sides being insulated and impermeable is investigated numerically. Constant temperatures and concentration are imposed along the longest sides of the enclosure. In addition, a uniform magnetic field is applied in a horizontal direction. Laminar regime is considered under steady state condition. The transport equations for continuity, momentum, energy and species transfer are solved using the finite volume technique. The validity of the numerical code used is ascertained and good agreement was found with published results. The numerical results are reported for the effect of thermal Rayleigh number on the contours of streamline, temperature, and concentration. In addition, results for the average Nusselt and Sherwood numbers are presented and discussed for various parametric conditions. This study was done for constant Prandtl number, Pr = 0.7, aspect ratio, A = 2, Lewis number, Le = 2, the buoyancy ratio, N = 1, Hartmann number, Ha = 10 and the dimensionless heat generation, Φ = 1. Computations are carried out for RaT ranging from 103 to 5 * 105 and inclination angle range of 0° ⩽ γ ⩽ 180°.
Mohit Katragadda
2012-01-01
Full Text Available The performance of algebraic flame surface density (FSD models has been assessed for flames with nonunity Lewis number (Le in the thin reaction zones regime, using a direct numerical simulation (DNS database of freely propagating turbulent premixed flames with Le ranging from 0.34 to 1.2. The focus is on algebraic FSD models based on a power-law approach, and the effects of Lewis number on the fractal dimension D and inner cut-off scale ηi have been studied in detail. It has been found that D is strongly affected by Lewis number and increases significantly with decreasing Le. By contrast, ηi remains close to the laminar flame thermal thickness for all values of Le considered here. A parameterisation of D is proposed such that the effects of Lewis number are explicitly accounted for. The new parameterisation is used to propose a new algebraic model for FSD. The performance of the new model is assessed with respect to results for the generalised FSD obtained from explicitly LES-filtered DNS data. It has been found that the performance of the most existing models deteriorates with decreasing Lewis number, while the newly proposed model is found to perform as well or better than the most existing algebraic models for FSD.
Morgan, Brandon; Olson, Britton; White, Justin; McFarland, Jacob
2016-11-01
High-fidelity large eddy simulation (LES) of a low-Atwood number (A = 0.05) Rayleigh-Taylor mixing layer is performed using the tenth-order compact difference code Miranda. An initial multimode perturbation spectrum is specified in Fourier space as a function of mesh resolution such that a database of results is obtained in which each successive level of increased grid resolution corresponds approximately to one additional doubling of the mixing layer width, or generation. The database is then analyzed to determine approximate requirements for self-similarity, and a new metric is proposed to quantify how far a given simulation is from the limit of self-similarity. It is determined that the present database reaches a high degree of self-similarity after approximately 4.5 generations. Finally, self-similar turbulence profiles from the LES database are compared with one-dimensional simulations using the k- L- a and BHR-2 Reynolds-averaged Navier-Stokes (RANS) models. The k- L- a model, which is calibrated to reproduce a quadratic turbulence kinetic energy profile for a self-similar mixing layer, is found to be in better agreement with the LES than BHR-2 results. This work was preformed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344.
Arabi, Pouria; Jafarpur, Khosrow
2016-08-01
In the present study, effect of different flow regimes on free convection heat transfer has been examined. In the light of this, a novel analytical method is developed to calculate free convection heat transfer from isothermal convex bodies with arbitrary shape over all range of Rayleigh number in fluids with any Prandtl number. The crux of this method is based on the concept of dynamic behaviors existing in natural convection flow. In the previous models the Body Gravity Function (BGF) and Turbulent Function (TF) have been taken as constant values. In this study, BGF accounts for the effect of body shape and orientation with respect to gravity vector in laminar free convection. Besides, TF accounts for the impact of Prandtl number, body shape and orientation with regard to gravity vector in turbulent free convection. By contrast, it is shown that these two parameters undergo a change through the variation of Rayleigh number and cannot be considered as a constant. These two parameters are modeled based upon the thermal resistance concept. Moreover, two transition criteria happening in free convection heat transfer will be obtained according to this new analytical method (conduction-laminar and laminar-turbulent transitions). Finally, three models (models 1, 2 and 3) are proposed for calculation free convection heat transfer and present results for ten isothermal convex bodies with various aspect ratios (0.298 ≤ √ A /P ≤ 2.470) have been compared with the available experimental and numerical data. Here, the results of model 2 are almost equal to those of model 3. Also, the results of model 1 are more precise than those of model 3 while the parameters computation of model 1 is more intricate in comparison with model 3. On the one hand, the model 1 has an average difference <6 % vis-à-vis numerical data in entire range of Rayleigh number (laminar and turbulent). On the other hand, the average difference of model 1 is not more than 8 % versus experimental data
McDowell, Mark; Gray, Elizabeth
2008-01-01
Stereo Imaging Velocimetry (SIV) is a NASA Glenn Research Center (GRC) developed fluid physics technique for measuring threedimensional (3-D) velocities in any optically transparent fluid that can be seeded with tracer particles. SIV provides a means to measure 3-D fluid velocities quantitatively and qualitatively at many points. This technique provides full-field 3-D analysis of any optically clear fluid or gas experiment using standard off-the-shelf CCD cameras to provide accurate and reproducible 3-D velocity profiles for experiments that require 3-D analysis. A flame ball is a steady flame in a premixed combustible atmosphere which, due to the transport properties (low Lewis-number) of the mixture, does not propagate but is instead supplied by diffusive transport of the reactants, forming a premixed flame. This flame geometry presents a unique environment for testing combustion theory. We present our analysis of flame ball phenomena utilizing SIV technology in order to accurately calculate the 3-D position of a flame ball(s) during an experiment, which can be used as a direct comparison of numerical simulations.
Mi, XiaoCheng; Goroshin, Samuel; Bergthorson, Jeffrey M
2015-01-01
The dynamics of flame propagation in systems with infinite Lewis number and spatially discretized sources of heat release is examined, which is applicable to the combustion of suspensions of fuel particles in air. The system is analyzed numerically using a one-dimensional heat equation with a source term for the reaction progress variable, which is specified to have zero diffusivity, and the model reveals a spectrum of flame-propagation regimes. For the case of a switch-type reaction rate and homogeneous media (continuous regime), the flame propagates steadily at a velocity in agreement with analytical solutions. As the sources are spatially concentrated into {\\delta}-function-like sources, propagation approaches the discrete regime with a fixed period between ignition of the sources, for which an analytic solution is also available for validation. When the source term is governed by an Arrhenius rate and the activation energy is increased beyond the stability boundary, the flame begins to exhibit a long-wave...
Blue Skies, Coffee Creamer, and Rayleigh Scattering
Liebl, Michael
2010-01-01
The first physical explanation of Earths blue sky was fashioned in 1871 by Lord Rayleigh. Many discussions of Rayleigh scattering and approaches to studying it both in and out of the classroom are available. Rayleigh scattering accounts for the blue color of the sky and the orange/red color of the Sun near sunset and sunrise, and a number of…
Blue Skies, Coffee Creamer, and Rayleigh Scattering
Liebl, Michael
2010-01-01
The first physical explanation of Earths blue sky was fashioned in 1871 by Lord Rayleigh. Many discussions of Rayleigh scattering and approaches to studying it both in and out of the classroom are available. Rayleigh scattering accounts for the blue color of the sky and the orange/red color of the Sun near sunset and sunrise, and a number of…
Ahlers, Guenter; He, Xiaozhou
2014-01-01
We report on experimental determinations of the temperature field in the interior (bulk) of turbulent Rayleigh-Benard convection for a cylindrical sample with aspect ratio (diameter over height) of 0.50, both in the classical and in the ultimate state. The Prandtl number was close to 0.8. We find a "logarithmic layer" in which the temperature varies as A*ln(z/L) + B with the distance z from the bottom plate of the sample. The amplitude A varies with radial position r. In the classical state these results are in good agreement with direct numerical simulations (DNS); in the ultimate state there are as yet no DNS. A close analogy between the temperature field in the classical state and the "Law of the Wall" for the time-averaged down-stream velocity in shear flow is discussed.
Liu, Wanhai; Yu, Changping; Jiang, Hongbin; Li, Xinliang
2017-02-01
Based on the harmonic analysis [Liu et al., Phys. Plasmas 22, 112112 (2015)], the analytical investigation on the harmonic evolution in Rayleigh-Taylor instability (RTI) at a spherical interface has been extended to the general case of arbitrary Atwood numbers by using the method of the formal perturbation up to the third order in a small parameter. Our results show that the radius of the initial interface [i.e., Bell-Plessett (BP) effect] dramatically influences the harmonic evolution for arbitrary Atwood numbers. When the initial radius approaches infinity compared against the initial perturbation wavelength, the amplitudes of the first four harmonics will recover those in planar RTI. The BP effect makes the amplitudes of the zeroth, second, and third harmonics increase faster for a larger Atwood number than smaller one. The BP effect reduces the third-order negative feedback to the fundamental mode for a smaller Atwood number, and strengthens it for a larger one. Hence, the BP effect helps the fundamental mode grow faster for a smaller Atwood number.
Ronney, Paul D.; Wu, Ming-Shin; Pearlman, Howard G.; Weiland, Karen J.
1998-01-01
Results from the Structure Of Flame Balls At Low Lewis-number (SOFBALL) space flight experiment conducted on the MSL-1 Space Shuttle missions are reported. Several new insights were obtained, including: much lower buoyancy-induced drift speed than anticipated pre-flight; repulsion of adjacent flame balls due to their mutual interaction; remarkable sensitivity of flame balls to small accelerations resulting from Orbiter attitude control maneuvers; and very similar net heat release for all flame balls in all mixtures tested. Comparison of experimental results to computational predictions reveals limitations in current models of H2-02 chemistry for very lean mixtures. It is discussed how the results of these space experiments may provide an improved understanding of the interactions of the two most important phenomena in combusting materials, namely chemical reaction and transport processes, in the unequivocally simplest possible configuration.
Roth, J. R.
1976-01-01
Parametric variation of independent variables which may affect the characteristics of bumpy torus plasma have identified those which have a significant effect on the plasma current, ion kinetic temperature, and plasma number density, and those which do not. Empirical power law correlations of the plasma current, and the ion kinetic temperature and number density were obtained as functions of potential applied to the midplane electrode rings, the background neutral gas pressure, and the magnetic field strength. Additional parameters studied included the type of gas, the polarity of the midplane electrode rings, the mode of plasma operation, and the method of measuring the plasma number density. No significant departures from the scaling laws appear to occur at the highest ion kinetic temperatures or number densities obtained to date.
Roth, J. R.
1977-01-01
The degree of toroidal symmetry of the plasma, the number of midplane electrode rings, the configuration of electrode rings, and the location of the diagnostic instruments with respect to the electrode rings used to generate the plasma are discussed. Impurities were deliberately introduced into the plasma, and the effects of the impurity fraction on ion kinetic temperature and electron number density were observed. It is concluded that, if necessary precautions are taken, the plasma communicates extremely well along the magnetic field lines and displays a high degree of symmetry from sector to sector for a wide range of electrode ring configurations and operating conditions. Finally, some characteristic data taken under nonoptimized conditions are presented, which include the highest electron number density and the longest particle containment time (1.9 msec) observed. Also, evidence from a paired comparison test is presented which shows that the electric field acting along the minor radius of the toroidal plasma improves the plasma density and the calculated containment time more than an order of magnitude if the electric field points inward, relative to the values observed when it points (and pushes ions) radially outward.
Korucu, Ayse; Miller, Richard
2016-11-01
Direct numerical simulations (DNS) of temporally developing shear flames are used to investigate both equation of state (EOS) and unity-Lewis (Le) number assumption effects in hydrocarbon flames at elevated pressure. A reduced Kerosene / Air mechanism including a semi-global soot formation/oxidation model is used to study soot formation/oxidation processes in a temporarlly developing hydrocarbon shear flame operating at both atmospheric and elevated pressures for the cubic Peng-Robinson real fluid EOS. Results are compared to simulations using the ideal gas law (IGL). The results show that while the unity-Le number assumption with the IGL EOS under-predicts the flame temperature for all pressures, with the real fluid EOS it under-predicts the flame temperature for 1 and 35 atm and over-predicts the rest. The soot mass fraction, Ys, is only under-predicted for the 1 atm flame for both IGL and real gas fluid EOS models. While Ys is over-predicted for elevated pressures with IGL EOS, for the real gas EOS Ys's predictions are similar to results using a non-unity Le model derived from non-equilibrium thermodynamics and real diffusivities. Adopting the unity Le assumption is shown to cause misprediction of Ys, the flame temperature, and the mass fractions of CO, H and OH.
M. Wolstencroft
2011-12-01
Full Text Available We investigate the influence on mantle convection of the negative Clapeyron slope ringwoodite to perovskite and ferro-periclase mantle phase transition, which is correlated with the seismic discontinuity at 660 km depth. In particular, we focus on understanding the influence of the magnitude of the Clapeyron slope (as measured by the Phase Buoyancy parameter, P and the vigour of convection (as measured by the Rayleigh number, Ra on mantle convection. We have undertaken 76 simulations of isoviscous mantle convection in spherical geometry, varying Ra and P. Three domains of behaviour were found: layered convection for high Ra and more negative P, whole mantle convection for low Ra and less negative P, and transitional behaviour in an intervening domain. The boundary between the layered and transitional domain was fit by a curve P = α Ra^{β} where α = −1.05, and β = −0.1, and the fit for the boundary between the transitional and whole mantle convection domain was α = −4.8, and β = −0.25. These two curves converge at Ra ≈ 2.5 × 10^{4} (well below Earth mantle vigour and P ≈ −0.38. Extrapolating to high Ra, which is likely earlier in Earth history, this work suggests a large transitional domain. It is therefore likely that convection in the Archean would have been influenced by this phase change, with Earth being at least in the transitional domain, if not the layered domain.
M. Wolstencroft
2011-08-01
Full Text Available We investigate the influence on mantle convection of the negative Clapeyron slope ringwoodite to perovskite and ferro-periclase mantle phase transition, which is correlated with the seismic discontinuity at 660 km depth. In particular, we focus on understanding the influence of the magnitude of the Clapeyron slope (as measured by the Phase Buoyancy parameter, P and the vigour of convection (as measured by the Rayleigh number, Ra on mantle convection. We have undertaken 76 simulations of isoviscous mantle convection in spherical geometry varying Ra and P. Three domains of behaviour were found: layered convection for high Ra and more negative P, whole mantle convection for low Ra and less negative P and transitional behaviour in an intervening domain. The boundary between the layered and transitional domain was fit by a curve P = αRa^{β} where α = −1.05, and β = −0.1, and the fit for the boundary between the transitional and whole mantle convection domain was α = −4.8, and β = −0.25. These two curves converge at Ra≈2.5×10^{4} and P≈−0.38. Extrapolating to high Ra, which is likely earlier in Earth history, this work suggests a large transitional domain. It is therefore likely that convection in the Archean would have been influenced by this phase change, with Earth being at least in the transitional domain, if not the layered domain.
Lewy body disease is one of the most common causes of dementia in the elderly. Dementia is the loss ... enough to affect normal activities and relationships. Lewy body disease happens when abnormal structures, called Lewy bodies, ...
Multiphase Rayleigh-Bénard convection
Oresta, P.; Fornarelli, F.; Prosperetti, Andrea
2014-01-01
Numerical simulations of two-phase Rayleigh-Bénard convection in a cylindrical cell with particles or vapor bubbles suspended in the fluid are described. The particles or bubbles are modeled as points, the Rayleigh number is 2×106 and the fluids considered are air, for the particle case, and
戴传山; 王珏
2015-01-01
采用铂丝自测流体温度的实验方法，利用50×10−6 m2·s−1硅油对低Rayleigh数下水平与竖直热线外自然对流传热的机理进行了研究，对比实验测得的实验数据和Tsubouchi、Fand的实验数据发现，实验结果与Tsubouchi的拟合曲线吻合度较高，低Ra下水平热线外的Nu高于竖直热线，但均远高于数值模拟的预测值。为了解释该现象，进行了低振动Re下的自然对流数值模拟，发现在低于某一振动Re下，Nu将与Re无关，但此时Nu与实验测的Nu基本一致，与Tsubouchi的数据偏差也在5%以内，说明微尺度铂丝外自然对流可能存在振动的作用机理。%The mechanism of natural convection around horizontal and vertical heated microwires in silicon oil is studied by using the wire itself for temperature measurement. The comparison between present measured Nusselt numbers and those in literature shows that the present data agreed better with those of Tsubouchi than those of Fand. The horizontal microwire presents a larger Nu than the vertical one at low Rayleigh number. However, all of these experimental Nu are much larger than the numerically simulated values. In order to give a theoretical explanation on this phenomenon, heated microwire with weak vibration was used in the numerical simulations. The simulated Nu shows a perfect match with the measured data and are in agreement with the correlation of Tsubouchi with a deviation less than 5%. Therefore, an enhanced heat transfer mode due to weak wire vibration is proposed, to fill the gap between simulated and experimental results.
Pogoreltsev, Alla; Tulchinsky, Yuri; Fridman, Natalia; Gandelman, Mark
2017-03-22
Being a major conception of chemistry, Lewis acids have found countless applications throughout chemical enterprise. Although many chemical elements can serve as the central atom of Lewis acids, nitrogen is usually associated with Lewis bases. Here, we report on the first example of robust and modifiable Lewis acids centered on the nitrogen atom, which provide stable and well-characterized adducts with various Lewis bases. On the basis of the reactivity of nitrogen Lewis acids, we prepared, for the first time, cyclic triazanes, a class of cyclic organic compounds sequentially bearing three all-saturated nitrogen atoms (N-N-N motif). Reactivity abilities of these N-Lewis acids were explained by theoretical calculations. Properties and future applications of nitrogen Lewis acids are intriguing.
Lewy Body Dementia Association
... promoting scientific advances. Featured LBD Stories & Tributes Dad's Dementia Journey It's been years since my father passed ... I received an email from the Lewy Body Dementia Association about a benefit... Read Story The Lewy ...
Rotating Rayleigh-Taylor turbulence
Boffetta, G.; Mazzino, A.; Musacchio, S.
2016-09-01
The turbulent Rayleigh-Taylor system in a rotating reference frame is investigated by direct numerical simulations within the Oberbeck-Boussinesq approximation. On the basis of theoretical arguments, supported by our simulations, we show that the Rossby number decreases in time, and therefore the Coriolis force becomes more important as the system evolves and produces many effects on Rayleigh-Taylor turbulence. We find that rotation reduces the intensity of turbulent velocity fluctuations and therefore the growth rate of the temperature mixing layer. Moreover, in the presence of rotation the conversion of potential energy into turbulent kinetic energy is found to be less effective, and the efficiency of the heat transfer is reduced. Finally, during the evolution of the mixing layer we observe the development of a cyclone-anticyclone asymmetry.
Andersen, Kurt Munk
1997-01-01
Rayleigh's principle expresses that the smallest eigenvalue of a regular Sturm-Liouville problem with regular boundary conditions is the minimum value of a certain functional, the so called Rayleigh's quotient, and that this value is attained at the corresponding eigenfunctions only. This can...... be proved by means of more advanced methods. However, it turns out that there is an elementary proof, which is presented in the report....
... a new treatment for hallucinations in Parkinson’s disease. Symptoms Differ in Alzheimer's when Lewy Bodies are Present June, 2015 - Lewy ... distinguish the underlying cause or causes of dementia symptoms. The diagnostic ... Alzheimer’s disease pathology alone versus those who have both ...
Universality of energy spectrum in turbulent Rayleigh-Benard convection
Bai, Kunlun; Hoeller, Judith; Brown, Eric
2016-11-01
We present study of energy spectrum in turbulent Rayleigh-Benard convection, in both cylindrical and cubic containers, tilting and non-tilting conditions, and with Rayleigh number ranging from 0 . 5 ×109 to 1 ×1010 . For these different conditions of geometry, tilt, and Rayleigh number, the temperature spectra measured on the system side walls are significantly different from each other. Even for the same condition, the spectrum varies depending on whether the sensors locate in the path of large-scale circulations. However, quite interestingly, once the signals of large-scale circulations are subtracted from the raw temperature, all spectra display a universal shape, regardless of system geometry, tilt, Rayleigh number, and location of sensors. It suggests that one could model the large-scale circulations and small-scale fluctuations separately in turbulent Rayleigh-Benard convection.
W. R. G. Gibb
1990-01-01
Full Text Available In cortical Lewy body dementia the distribution of Lewy bodies in the nervous system follows that of Parkinson's disease, except for their greater profusion in the cerebral cortex. The cortical tangles and plaques of Alzheimer pathology are often present, the likely explanation being that Alzheimer pathology provokes dementia in many patients. Pure cortical Lewy body dementia without Alzheimer pathology is uncommon. The age of onset reflects that of Parkinson's disease, and clinical features, though not diagnostic, include aphasias, apraxias, agnosias, paranoid delusions and visual hallucinations. Parkinsonism may present before or after the dementia, and survival duration is approximately half that seen in Parkinson's disease without dementia.
Løkkegaard, Annemette; Korbo, Lise
2017-01-01
Dementia with Lewy bodies and Parkinson disease dementia share the same pathophysiology. Together they are called Lewy body dementias and are the second most common type of dementia. Lewy body dementias receive little attention, and patients are often misdiagnosed, leading to less than ideal...... management. In this article, diagnostic criteria combined with imaging and other biomarkers as well as current treatment recommendations are summarized, and some of the challenges for the future are outlined. Refinement of diagnosis and clarification of the pathogenesis are required in search for disease...
Kaufer, D
Consensus diagnostic criteria for dementia with Lewy bodies (DLB) proposed in 1996 have provided a useful foundation for research in the field. As a clinicopathologically defined entity, DLB has overlapping features of both Alzheimer s disease (AD) and Parkinson's disease (PD). Consensus criteria for DLB distinguish it from PD dementia by the earlier appearance of motor signs in the latter. Studies evaluating the standardized clinical diagnostic criteria for DLB have generally found them to be highly predictive of Lewy body pathology. However, many cases with Lewy body pathology and concomitant pathological features of AD elude clinical detection. Emerging data suggests that AD pathological features mask the clinical expression of concomitant Lewy body pathology, and that DLB and PD dementia may be more similar than distinct.
Rayleigh imaging in spectral mammography
Berggren, Karl; Danielsson, Mats; Fredenberg, Erik
2016-03-01
Spectral imaging is the acquisition of multiple images of an object at different energy spectra. In mammography, dual-energy imaging (spectral imaging with two energy levels) has been investigated for several applications, in particular material decomposition, which allows for quantitative analysis of breast composition and quantitative contrast-enhanced imaging. Material decomposition with dual-energy imaging is based on the assumption that there are two dominant photon interaction effects that determine linear attenuation: the photoelectric effect and Compton scattering. This assumption limits the number of basis materials, i.e. the number of materials that are possible to differentiate between, to two. However, Rayleigh scattering may account for more than 10% of the linear attenuation in the mammography energy range. In this work, we show that a modified version of a scanning multi-slit spectral photon-counting mammography system is able to acquire three images at different spectra and can be used for triple-energy imaging. We further show that triple-energy imaging in combination with the efficient scatter rejection of the system enables measurement of Rayleigh scattering, which adds an additional energy dependency to the linear attenuation and enables material decomposition with three basis materials. Three available basis materials have the potential to improve virtually all applications of spectral imaging.
Malcolm J. Andrews
2006-04-14
This project had two major tasks: Task 1. The construction of a new air/helium facility to collect detailed measurements of Rayleigh-Taylor (RT) mixing at high Atwood number, and the distribution of these data to LLNL, LANL, and Alliance members for code validation and design purposes. Task 2. The collection of initial condition data from the new Air/Helium facility, for use with validation of RT simulation codes at LLNL and LANL. This report describes work done in the last twelve (12) months of the project, and also contains a summary of the complete work done over the three (3) life of the project. As of April 1, 2006, the air/helium facility (Task 1) is now complete and extensive testing and validation of diagnostics has been performed. Initial condition studies (Task 2) is also comp lete. Detailed experiments with air/helium with Atwood numbers up to 0.1 have been completed, and Atwood numbers of 0.25. Within the last three (3) months we have been able to successfully run the facility at Atwood numbers of 0.5. The progress matches the project plan, as does the budget. We have finished the initial condition studies using the water channel, and this work has been accepted for publication on the Journal of Fluid Mechanics (the top fluid mechanics journal). Mr. Nick Mueschke and Mr. Wayne Kraft are continuing with their studies to obtain PhDs in the same field, and will also continue their collaboration visits to LANL and LLNL. Over its three (3) year life the project has supported two(2) Ph.D.’s and three (3) MSc’s, and produced nine (9) international journal publications, twenty four (24) conference publications, and numerous other reports. The highlight of the project has been our close collaboration with LLNL (Dr. Oleg Schilling) and LANL (Drs. Dimonte, Ristorcelli, Gore, and Harlow).
Modifications to Ivor Lewis esophagectomy.
David, Elizabeth A; Marshall, M Blair
2010-11-01
The surgical approach to esophagectomy is variable. A number of factors are considered when determining the optimal approach to esophagectomy: location and extent of disease, fibrosis, additional patient factors and surgeon preference. One of the disadvantages to some approaches is the need for a change in position, which increases operative time. Also, because typically the abdomen is initially explored, patients may later be deemed unresectable at thoracotomy. We describe time saving modifications to the standard Ivor Lewis esophagectomy that eliminate the need for repositioning and facilitate a stapled end-to-end anastomosis.
Heat transfer and large scale dynamics in turbulent Rayleigh-Bénard convection
Ahlers, Guenter; Grossmann, Siegfried; Lohse, Detlef
2009-01-01
The progress in our understanding of several aspects of turbulent Rayleigh-Bénard convection is reviewed. The focus is on the question of how the Nusselt number and the Reynolds number depend on the Rayleigh number Ra and the Prandtl number Pr, and on how the thicknesses of the thermal and the kinet
Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.
Möricke, Jennifer; Wibbeling, Birgit; Daniliuc, Constantin G; Kehr, Gerald; Erker, Gerhard
2017-08-28
The conjugated dienamine 4 selectively adds Piers' borane [HB(C6F5)2] to give the enamine/borane system 5, which features a boratirane structure by internal enamine carbon Lewis base to boron Lewis acid interaction. Compound 5 behaves as a C/B frustrated Lewis pair and undergoes typical addition reactions to benzaldehyde, several nitriles and to sulfur dioxide.This article is part of the themed issue 'Frustrated Lewis pair chemistry'. © 2017 The Author(s).
王玲; 蔡文静; 刘林
2012-01-01
用扫描电镜和能谱仪研究分析了Inconel 718合金定向凝固过程中枝晶间的偏析和二次枝晶角度对合金Rayleigh数的影响.结果表明,Inconel 718合金凝固过程中的主要偏析元素是Nb和Mo,合金的Rayleigh数在液相线下10℃值最高,形成黑斑趋势最大；Inconel 718合金糊状区内,二次枝晶角度对Rayleigh数值具有显著的影响.%The effects of the segregation of interdendritic liquid and the orientation of the secondary dendrites in the mushy zone of superalloy Inconel 718 during directional solidification on Rayleigh number were investigated by SEM and ED AX techniques. It was found that the segregation elements in solidification process of Inconel 718 alloy mainly are Nb and Mo. The Rayleigh number is highest at 10 ℃ below liquidus temperature, which indicates that the trends of forming freckles is the maximum. The relative Rayleigh number is significantly affected by the orientation of the secondary dendrites.
Yun Ji Hong; Sang Mee Hwang; Taek Soo Kim; Eun Young Song; Kyoung Un Park; Junghan Song; Kyou-Sup Han
2014-01-01
Lewis phenotypes using various types of specimen were compared with the Lewis phenotype predicted from Lewis and Secretor genotypes. This is the first logical step in explaining the association between the Lewis expression and Helicobacter pylori. We performed a study of the followings on 209 patients who underwent routine gastroscopy: erythrocyte and saliva Lewis phenotyping, gastric Lewis phenotyping by the tissue array, and the Lewis and Secretor genes genotyping. The results of phenotypin...
Beating Rayleigh's Curse by Imaging Using Phase Information
Tham, Weng-Kian; Ferretti, Hugo; Steinberg, Aephraim M.
2017-02-01
Every imaging system has a resolution limit, typically defined by Rayleigh's criterion. Given a fixed number of photons, the amount of information one can gain from an image about the separation between two sources falls to zero as the separation drops below this limit, an effect dubbed "Rayleigh's curse." Recently, in a quantum-information-inspired proposal, Tsang and co-workers found that there is, in principle, infinitely more information present in the full electromagnetic field in the image plane than in the intensity alone, and suggested methods for extracting this information and beating the Rayleigh limit. In this Letter, we experimentally demonstrate a simple scheme that captures most of this information, and show that it has a greatly improved ability to estimate the distance between a pair of closely separated sources, achieving near-quantum-limited performance and immunity to Rayleigh's curse.
Whitehead, Jared P
2011-01-01
Rigorous upper limits on the vertical heat transport in two dimensional Rayleigh-Benard convection between stress-free isothermal boundaries are derived from the Boussinesq approximation of the Navier-Stokes equations. The Nusselt number Nu is bounded in terms of the Rayleigh number Ra according to $Nu \\leq 0.2295 Ra^{5/12}$ uniformly in the Prandtl number Pr. This Nusselt number scaling challenges some theoretical arguments regarding the asymptotic high Rayleigh number heat transport by turbulent convection.
Lewis Acid Catalyzed Benzylic Bromination
Shibatomi, Kazutaka; Zhang, Yanhua; Yamamoto, Hisashi
2008-01-01
Lewis acid catalyzed bromination on aromatic side chain was achieved efficiently by using 1,3-dibromo-5,5-dimethylhydantoin (DBDMH) as a bromination reagent under mild conditions. Zirconium(IV) chloride showed the highest catalytic activity for the benzylic bromination. It was revealed that the present Lewis acid catalysis proceeds via the radical generation pathway. In contrast to Lewis acid catalysis, Brønsted acid promoted aromatic ring bromination without any benzylic bromination. Monobro...
McKeith, Ian G; Burn, David J; Ballard, Clive G; Collerton, Daniel; Jaros, Evelyn; Morris, Chris M; McLaren, Andrew; Perry, Elaine K; Perry, Robert; Piggott, Margaret A; O'Brien, John T
2003-01-01
The objective was to summarize recent findings about the clinical features, diagnosis and investigation of dementia with Lewy (DLB) bodies, together with its neuropathology, neurochemistry and genetics. Dementia with Lewy bodies (DLB) is a primary, neurodegenerative dementia sharing clinical and pathological characteristics with both Parkinson's disease (PD) and Alzheimer's disease (AD). Antiubiquitin immunocytochemical staining, developed in the early 1990s, allowed the frequency and distribution of cortical LBs to be defined. More recently, alpha-synuclein antibodies have revealed extensive neuritic pathology in DLB demonstrating a neurobiological link with other "synucleinopathies" including PD and multiple system atrophy (MSA). The most significant correlates of cognitive failure in DLB appear to be with cortical LB and Lewy neurites (LNs) rather than Alzheimer type pathology. Clinical diagnostic criteria for DLB, published in 1996, have been subjected to several validation studies against autopsy findings. These conclude that although diagnostic specificity is high (range 79- 100%, mean 92%), sensitivity is lower (range 0- 83 %, mean, 49%). Improved methods of case detection are therefore required. Fluctuating impairments in attention, visual recognition and construction are more indicative of DLB than AD. Relative preservation of medial temporal lobe volume on structural MRI and the use of SPECT tracers for regional blood flow and the dopamine transporter are the most reliable current biomarkers for DLB. There are no genetic or CSF tests recommended for the diagnosis of DLB at present. Between 15 and 20% of all elderly demented cases reaching autopsy have DLB, making it the most common cause of degenerative dementia after AD. Exquisite, not infrequently fatal, sensitivity to neuroleptic drugs and encouraging reports of the effects of cholinesterase inhibitors on cognitive, psychiatric and neurological features, mean that an accurate diagnosis of DLB is more
A simple analytic approximation to the Rayleigh-Bénard stability threshold
Prosperetti, Andrea
2011-01-01
The Rayleigh-Bénard linear stability problem is solved by means of a Fourier series expansion. It is found that truncating the series to just the first term gives an excellent explicit approximation to the marginal stability relation between the Rayleigh number and the wave number of the perturbatio
Lewis base activation of Lewis acids: development of a Lewis base catalyzed selenolactonization.
Denmark, Scott E; Collins, William R
2007-09-13
The concept of Lewis base activation of Lewis acids has been applied to the selenolactonization reaction. Through the use of substoichiometric amounts of Lewis bases with "soft" donor atoms (S, Se, P) significant rate enhancements over the background reaction are seen. Preliminary mechanistic investigations have revealed the resting state of the catalyst as well as the significance of a weak Brønsted acid promoter.
Yun Ji Hong
2014-01-01
, and le59 alleles was 74.6%, 21.3%, 3.1%, and 1.0%, respectively, among 418 alleles. The saliva Lewis phenotype was completely consistent with the Lewis phenotype inferred from Lewis and Secretor genotypes, but that of gastric mucosa could not be predicted from genotypes. Lewis phenotyping using erythrocytes is only adequate for transfusion needs. Saliva testing for the Lewis phenotype is a more reliable method for determining the peripheral Lewis phenotype of an individual and the gastric Lewis phenotype must be used for the study on the association between Helicobacter pylori and the Lewis phenotype.
A Biography of Distinguished Scientist Gilbert Newton Lewis (by Edward S. Lewis)
Harris, Reviewed By Harold H.
1999-11-01
until 1904, when he accepted a position that would not be considered a shrewd career move: Superintendent of Weights and Measures in Manila, Philippines! He was there only one year, but it was apparently a productive time, both in a minimally equipped laboratory and with the possible nascence of some of his ideas about bonding. In 1905, Lewis accepted a staff position at MIT, under A. A. Noyes, where he remained until 1912. At MIT, he continued his experimental work on thermodynamic systems and the development of modern thermodynamics, following the lead of J. W. Gibbs, whose work was being largely ignored by other chemists. As Noyes moved increasingly into administrative responsibilities, Lewis took over more and more of the supervision of scientific work in the laboratory. It was the capable job that he did for Noyes that led to his being offered a Professorship and Chair of the College of Chemistry at the University of California, Berkeley. The same spirit of adventure that took Lewis to Manila may be what led to his moving to scientifically backward California. In 1912, there was no serious science going on the Left Coast, and Berkeley was isolated from the nearest civilization (Chicago) by days of travel. Lewis initiated the expansion of great science westward, not only to Berkeley, but also to Caltech (in those days Throop Institute), UCLA, and Stanford. By dint of his contributions to thermodynamics and bonding theory (suggesting that electrons bond in pairs, long before there was quantum mechanical justification for such a strange idea), and his organizational and leadership talents, he turned the Berkeley Chemistry Department from a nonentity into one of the finest anywhere. Later in his career, he contributed to the understanding of the role of isotopes in chemistry and physics. This biography includes a useful listing of Lewis's 168 scientific publications. In an age when many renowned scientists have multiples of this number, it is perhaps good to be
Organometallic frustrated Lewis pair chemistry.
Erker, Gerhard
2011-08-07
Frustrated Lewis pairs are playing an increasingly important role in organometallic chemistry. Examples are presented and discussed where organometallic systems themselves serve as the Lewis base or Lewis acid components in frustrated Lewis pair chemistry, mostly through their attached functional groups. Activation of dihydrogen takes place easily in many of these systems. This may lead to the generation of novel catalyst systems but also in many cases to the occurrence of specific reactions at the periphery of the organometallic frameworks. Increasingly, FLP reactions are used to carry out functional group conversions in organometallic systems under mild reaction conditions. The limits of typical FLP reactivity are explored with selected organometallic examples, a discussion that points toward new developments, such as the discovery of facile new 1,1-carboboration reactions. Learning more and more about the broad spectrum of frustrated Lewis pair chemistry helps us to find novel reactions and applications.
Elm, Jonas; Norman, Patrick; Bilde, Merete;
2014-01-01
and hyperpolarizability β tensors. Using density functional theory, we elucidate the effect of cluster morphology on the scattering properties using a combinatorial sampling approach. We find that the Rayleigh scattering intensity depends quadratically on the number of water molecules in the cluster and that a single......The Rayleigh and hyper Rayleigh scattering properties of the binary (H 2SO4)(H2O)n and ternary (H 2SO4)(NH3)(H2O)n clusters are investigated using a quantum mechanical response theory approach. The molecular Rayleigh scattering intensities are expressed using the dipole polarizability α...
Simulation of Rayleigh-Bénard convection using lattice Boltzmann method
Shan, X
1996-01-01
Rayleigh-Bénard convection is numerically simulated in two- and three-dimensions using a recently developed two-component lattice Boltzmann equation (LBE) method. The density field of the second component, which evolves according to the advection-diffusion equation of a passive-scalar, is used to simulate the temperature field. A body force proportional to the temperature is applied, and the system satisfies the Boussinesq equation except for a slight compressibility. A no-slip, isothermal boundary condition is imposed in the vertical direction, and periodic boundary conditions are used in horizontal directions. The critical Rayleigh number for the onset of the Rayleigh-Bénard convection agrees with the theoretical prediction. As the Rayleigh number is increased higher, the steady two-dimensional convection rolls become unstable. The wavy instability and aperiodic motion observed, as well as the Nusselt number as a function of the Rayleigh number, are in good agreement with experimental observations and the...
Banquet Speech Some Sketches Of Rayleigh
Howard, John N.
1985-11-01
Several short sketches are presented of Lord Rayleigh, to show his method of working and his interaction with his fellow scientists. The topics discussed are: his research on the blue of the sky (Rayleigh scattering); his rescue of Waterston from near-oblivion; his research on surface acoustic waves (Rayleigh waves); his collaboration with Agnes Pockels; his research on blackbody radiation (the Rayleigh-Jeans Law).
Hong, Yun Ji; Hwang, Sang Mee; Kim, Taek Soo; Song, Eun Young; Park, Kyoung Un; Song, Junghan; Han, Kyou-Sup
2014-01-01
Lewis phenotypes using various types of specimen were compared with the Lewis phenotype predicted from Lewis and Secretor genotypes. This is the first logical step in explaining the association between the Lewis expression and Helicobacter pylori. We performed a study of the followings on 209 patients who underwent routine gastroscopy: erythrocyte and saliva Lewis phenotyping, gastric Lewis phenotyping by the tissue array, and the Lewis and Secretor genes genotyping. The results of phenotyping were as follows [Le(a-b-), Le(a+b-), Le(a-b+), and Le(a+b+), respectively, in order]: erythrocyte (12.4%, 25.8%, 61.2%, and 0.5%); saliva (2.4%, 27.3%, 70.3%, and 0.0%); gastric mucosa (8.1%, 6.7%, 45.5%, and 39.7%). The frequency of Le, le (59/508) , le (59/1067) , and le (59) alleles was 74.6%, 21.3%, 3.1%, and 1.0%, respectively, among 418 alleles. The saliva Lewis phenotype was completely consistent with the Lewis phenotype inferred from Lewis and Secretor genotypes, but that of gastric mucosa could not be predicted from genotypes. Lewis phenotyping using erythrocytes is only adequate for transfusion needs. Saliva testing for the Lewis phenotype is a more reliable method for determining the peripheral Lewis phenotype of an individual and the gastric Lewis phenotype must be used for the study on the association between Helicobacter pylori and the Lewis phenotype.
Symptoms of Lewy Body Dementia
... Treatment Options Join the fight against LBD! Donate Symptoms Lewy body dementia symptoms and diagnostic criteria Every person with LBD is ... or Dementia plus one or more suggestive features. Symptoms Explained In this section we'll discuss each ...
Lozniewski, Alain; Haristoy, Xavier; Rasko, David A.; Hatier, Renée; Plénat, François; Diane E Taylor; Angioi-Duprez, Karine
2003-01-01
The role of Helicobacter pylori lipopolysaccharide (LPS) Lewis antigens in infection is still not well known. We investigated the influence of Lewis antigen expression by H. pylori on its internalization by AGS cells and the epithelium of human gastric xenografts in nude mice using isogenic mutants in LPS biosynthetic genes. In vivo, colonization rates were unaffected by the change in H. pylori Lewis antigen expression, whereas the number of viable intracellular bacteria was significantly hig...
HUANG Lin; JIAN Guang-de; QIU Xiao-ming
2007-01-01
The synergistic stabilizing effect of gyroviscosity and sheared axial flow on the Rayleigh-Taylor instability in Z-pinch implosions is studied by means of the incompressible viscid magneto-hydrodynamic equations. The gyroviscosity (or finite Larmor radius) effects are introduced in the momentum equation through an anisotropic ion stress tensor. Dispersion relation with the effect of a density discontinuity is derived. The results indicate that the short-wavelength modes of the Rayleigh-Taylor instability are easily stabilized by the gyroviscosity effects. The long wavelength modes are stabilized by the sufficient sheared axial flow. However, the synergistic effects of the finite Larmor radius and sheared axial flow can heavily mitigate the Rayleigh-Taylor instability. This synergistic effect can compress the Rayleigh-Taylor instability to a narrow wave number region. Even with a sufficient gyroviscosity and large enough flow velocity, the synergistic effect can completely suppressed the Rayleigh-Taylor instability in whole wave number region.
AN EFFICIENT SIMULATION OF MULTIPLE CORRELATED RAYLEIGH FADING ENVELOPES
Zhou Ke; Cao Shike; Song Rongfang
2008-01-01
In order to better assess the performance of wireless communication systems,it is desirable to produce multiple Rayleigh fading envelopes with specified correlations. In this paper,we analyze theoretically a procedure which generates correlated Gaussian random variables from independent Gaussian random variables and give a physical explanation for the limitation of this procedure. Then,based on some uncorrelated Rayleigh fading envelopes,a simple but efficient procedure for generating an arbitrary number of cross-correlated Rayleigh fading envelopes is proposed. Simulation results and computational complexity analysis are presented,which show that the proposed method has some advantages,such as high accuracy,low computational complexity and easy implementation,over the conventional simulation method.
Anelastic Rayleigh-Taylor mixing layers
Schneider, N.; Gauthier, S.
2016-07-01
Anelastic Rayleigh-Taylor mixing layers for miscible fluids are investigated with a recently built model (Schneider and Gauthier 2015 J. Eng. Math. 92 55-71). Four Chebyshev-Fourier-Fourier direct numerical simulations are analyzed. They use different values for the compressibility parameters: Atwood number (the dimensionless difference of the heavy and light fluid densities) and stratification (accounts for the vertical variation of density due to gravity). For intermediate Atwood numbers and finite stratification, compressibility effects quickly occurs. As a result only nonlinear behaviours are reached. The influence of the compressibility parameters on the growth speed of the RTI is discussed. The 0.1—Atwood number/0.4—stratification configuration reaches a turbulent regime. This turbulent mixing layer is analyzed with statistical tools such as moments, PDFs, anisotropy indicators and spectra.
The limits and robustness of reinforcement learning in Lewis signalling games
Catteeuw, David; Manderick, Bernard
2014-04-01
Lewis signalling games are a standard model to study the emergence of language. We introduce win-stay/lose-inaction, a random process that only updates behaviour on success and never deviates from what was once successful, prove that it always ends up in a state of optimal communication in all Lewis signalling games, and predict the number of interactions it needs to do so: N3 interactions for Lewis signalling games with N equiprobable types. We show three reinforcement learning algorithms (Roth-Erev learning, Q-learning, and Learning Automata) that can imitate win-stay/lose-inaction and can even cope with errors in Lewis signalling games.
Superstructures in Rayleigh-Benard convection
Stevens, Richard; Verzicco, Roberto; Lohse, Detlef
2016-11-01
We study the heat transfer and the flow structures in Rayleigh-Bénard convection as function of the Rayleigh number Ra and the aspect ratio. We consider three-dimensional direct numerical simulations (DNS) in a laterally periodic geometry with aspect ratios up to Γ =Lx /Lz =Ly /Lz = 64 at Ra =108 , where Lx and Ly indicate the horizontal domain sizes and Lz the height. We find that the heat transport convergences relatively quickly with increasing aspect ratio. In contrast, we find that the large scale flow structures change significantly with increasing aspect ratio due to the formation of superstructures. For example, at Ra =108 we find the formation of basically only one large scale circulation roll in boxes with an aspect ratio up to 8. For larger boxes we find the formation of multiple of these extremely large convection rolls. We illustrate this by movies of horizontal cross-section of the bulk and the boundary layer and analyze them by using spectra in the boundary layer and the bulk. In addition, we study the effect of the large scale flow structures on the mean and higher order temperature and velocity statistics in the boundary layer and the bulk by comparing the simulation results obtained in different aspect ratio boxes. Foundation for fundamental Research on Matter (FOM), Netherlands Center for Multiscale Catalytic Energy Conversion (MCEC), SURFsara, Gauss Large Scale project.
Covariant Lyapunov vectors of chaotic Rayleigh-Bénard convection.
Xu, M; Paul, M R
2016-06-01
We explore numerically the high-dimensional spatiotemporal chaos of Rayleigh-Bénard convection using covariant Lyapunov vectors. We integrate the three-dimensional and time-dependent Boussinesq equations for a convection layer in a shallow square box geometry with an aspect ratio of 16 for very long times and for a range of Rayleigh numbers. We simultaneously integrate many copies of the tangent space equations in order to compute the covariant Lyapunov vectors. The dynamics explored has fractal dimensions of 20≲D_{λ}≲50, and we compute on the order of 150 covariant Lyapunov vectors. We use the covariant Lyapunov vectors to quantify the degree of hyperbolicity of the dynamics and the degree of Oseledets splitting and to explore the temporal and spatial dynamics of the Lyapunov vectors. Our results indicate that the chaotic dynamics of Rayleigh-Bénard convection is nonhyperbolic for all of the Rayleigh numbers we have explored. Our results yield that the entire spectrum of covariant Lyapunov vectors that we have computed are tangled as indicated by near tangencies with neighboring vectors. A closer look at the spatiotemporal features of the Lyapunov vectors suggests contributions from structures at two different length scales with differing amounts of localization.
How Do Lipids Localize in Lewy Bodies?
Chaudhary, Himanshu; Subramaniam, Vinod; Claessens, Mireille
2014-01-01
Lewy bodies are the pathological hallmark of Parkinson's disease (PD). While fibrillar α-synuclein (αS) is the main protein component of Lewy bodies, these structures also contain lipids. To elucidate the presence of lipids in Lewy bodies, we investigated the interaction of lipids with monomeric and
Lewis and Clark as Naturalists.
Smithsonian Institution, Washington, DC. National Museum of Natural History.
Intended for use in elementary and high school education, this Web site includes a teacher's guide and three lesson plans. The site contains images of museum specimens, scientific drawings, and field photos of the plant and animal species observed by Meriwether Lewis and William Clark, along with journal excerpts, historical notes, and references…
Asymptotic Rayleigh instantaneous unit hydrograph
Troutman, B.M.; Karlinger, M.R.
1988-01-01
The instantaneous unit hydrograph for a channel network under general linear routing and conditioned on the network magnitude, N, tends asymptotically, as N grows large, to a Rayleigh probability density function. This behavior is identical to that of the width function of the network, and is proven under the assumption that the network link configuration is topologically random and the link hydraulic and geometric properties are independent and identically distributed random variables. The asymptotic distribution depends only on a scale factor, {Mathematical expression}, where ?? is a mean link wave travel time. ?? 1988 Springer-Verlag.
Study of Rayleigh scattering for visualization of helium-air mixing at Mach 6
Shirinzadeh, B.; Balla, R. J.; Hillard, M. E.; Anders, J. B.; Exton, R. J.; Waitz, I. A.
1991-01-01
Using an ArF excimer laser, planar Rayleigh scattering measurements were performed to investigate helium mixing into air at supersonic speeds. These experiments were conducted in the Mach 6, high-Reynolds-number facility at NASA Langley Research Center. The capability of the Rayleigh scattering technique for flow visualization of a turbulent environment was demonstrated. The qualitative agreement between the averaged Rayleigh results and the reduced mean-mass-densities obtained from probe measurements substantiate that careful application of the technique, even in the presence of clusters, can give very useful results. It was also demonstrated that planar, quantitative measurements can be made in the absence of clusters.
Retrieval of Rayleigh Wave Ellipticity from Ambient Vibration Recordings
Maranò, Stefano; Hobiger, Manuel; Fäh, Donat
2017-01-01
The analysis of ambient vibrations is a useful tool in microzonation and geotechnical investigations. Ambient vibrations are composed to a large part of surface waves, both Love and Rayleigh waves. One reason to analyse surface waves is that they carry information about the subsurface. The dispersion curve of Rayleigh waves and Love waves can be retrieved using array processing techniques. The Rayleigh wave ellipticity, including the sense of rotation of the particle motion, can also be retrieved using array techniques. These quantities are used in an inversion procedure aimed at obtaining a structural model of the subsurface. The focus of this work is the retrieval of Rayleigh wave ellipticity. We show applications of the (ML) method presented in Maranó et al. (2012) to a number of sites in Switzerland. The sites examined are chosen to reflect a wide range of soil conditions that are of interest in microzonation studies. Using a synthetic wavefield with known structural model, we compare our results with theoretical ellipticity curves and we show the accuracy of the considered algorithm. The sense of rotation of the particle motion (prograde vs. retrograde) is also estimated. In addition, we show that by modelling the presence of both Love and Rayleigh waves it is possible to mitigate the disruptive influence of Love waves on the estimation of Rayleigh wave ellipticity. Using recordings from several real sites, we show that it is possible to retrieve the ellipticity curve over a broad range of frequencies. Fundamental modes and higher modes are retrieved. Singularities of the ellipticity, corresponding to a change of the sense of rotation from prograde to retrograde (or vice versa), are detected with great accuracy. Knowledge of Rayleigh wave ellipticity, including the sense of rotation, is useful in several ways. The ellipticity angle allows us to pinpoint accurately the frequency of singularities (i.e., peaks and zeros of the H/V representation of the
Remarks on the Rayleigh-Benard Convection on Spherical Shells
Wang, Shouhong
2011-01-01
The main objective of this article is to study the effect of spherical geometry on dynamic transitions and pattern formation for the Rayleigh-Benard convection. The study is mainly motivated by the importance of spherical geometry and convection in geophysical flows. It is shown in particular that the system always undergoes a continuous (Type-I) transition to a $2l_c$-dimensional sphere $S^{2lc}$, where lc is the critical wave length corresponding to the critical Rayleigh number. Furthermore, it has shown in [12] that it is critical to add nonisotropic turbulent friction terms in the momentum equation to capture the large-scale atmospheric and oceanic circulation patterns. We show in particular that the system with turbulent friction terms added undergoes the same type of dynamic transition, and obtain an explicit formula linking the critical wave number (pattern selection), the aspect ratio, and the ratio between the horizontal and vertical turbulent friction coefficients.
Beating Rayleigh's Curse by Imaging Using Phase Information
Tham, Weng Kian; Steinberg, Aephraim M
2016-01-01
Any imaging device such as a microscope or telescope has a resolution limit, a minimum separation it can resolve between two objects or sources; this limit is typically defined by "Rayleigh's criterion", although in recent years there have been a number of high-profile techniques demonstrating that Rayleigh's limit can be surpassed under particular sets of conditions. Quantum information and quantum metrology have given us new ways to approach measurement ; a new proposal inspired by these ideas has now re-examined the problem of trying to estimate the separation between two poorly resolved point sources. The "Fisher information" provides the inverse of the Cramer-Rao bound, the lowest variance achievable for an unbiased estimator. For a given imaging system and a fixed number of collected photons, Nair and Tsang observed that the Fisher information carried by the intensity of the light in the image-plane (the only information available to traditional techniques, including previous super-resolution approaches...
Importance sampling the Rayleigh phase function
Frisvad, Jeppe Revall
2011-01-01
Rayleigh scattering is used frequently in Monte Carlo simulation of multiple scattering. The Rayleigh phase function is quite simple, and one might expect that it should be simple to importance sample it efficiently. However, there seems to be no one good way of sampling it in the literature. Thi....... This paper provides the details of several different techniques for importance sampling the Rayleigh phase function, and it includes a comparison of their performance as well as hints toward efficient implementation.......Rayleigh scattering is used frequently in Monte Carlo simulation of multiple scattering. The Rayleigh phase function is quite simple, and one might expect that it should be simple to importance sample it efficiently. However, there seems to be no one good way of sampling it in the literature...
Nonlinear diffusion model for Rayleigh-Taylor mixing.
Boffetta, G; De Lillo, F; Musacchio, S
2010-01-22
The complex evolution of turbulent mixing in Rayleigh-Taylor convection is studied in terms of eddy diffusivity models for the mean temperature profile. It is found that a nonlinear model, derived within the general framework of Prandtl mixing theory, reproduces accurately the evolution of turbulent profiles obtained from numerical simulations. Our model allows us to give very precise predictions for the turbulent heat flux and for the Nusselt number in the ultimate state regime of thermal convection.
Nonlinear diffusion model for Rayleigh-Taylor mixing
Boffetta, G; Musacchio, S
2010-01-01
The complex evolution of turbulent mixing in Rayleigh-Taylor convection is studied in terms of eddy diffusiviy models for the mean temperature profile. It is found that a non-linear model, derived within the general framework of Prandtl mixing theory, reproduces accurately the evolution of turbulent profiles obtained from numerical simulations. Our model allows to give very precise predictions for the turbulent heat flux and for the Nusselt number in the ultimate state regime of thermal convection.
Sialyl Lewis x expression in cervical scrapes of premalignant lesions
Noé Velázquez-Márquez; Gerardo Santos López; Lucio Jiménez Aranda; Julio Reyes Leyva; Verónica Vallejo Ruiz
2012-12-01
Sialylated oligosaccharides of glycoproteins and glycolipids have been implicated in tumour progression and metastases. Altered expression of glycosidic antigens has been reported in cervical cancer. In cervix premalignant lesions, an increased expression of sialic acid has been reported. In the present study we determined the expression profiles of the glycosidic antigens Tn, sialyl Tn (sTn), Lewis a (Lea), sialyl Lewis a (sLea), Lewis x (Lex) and sialyl Lewis x (sLex) in cervical scrapes with cytological diagnoses of normal, low-grade squamous intraepithelial lesions (LGSIL) and high-grade squamous intraepithelial lesions (HGSIL). Cervical scrapings were collected to detect tumour antigens expressions by flow cytometry using monoclonal antibodies. Cytometry analysis of Tn, sTn, Lea and Lex did not reveal differences at the expression level among groups. The number of positive cells to sLea antigen increased in the HGSIL group with respect to the normal group (=0.0495). The number of positive cells to sLex antigen in the samples increased with respect to the grade of squamous intraepithelial lesion (SIL) ( < 0.001, Mann–Whitney U test). The intensity of expression of this antigen increased in the HGSIL samples with respect to normal samples ( < 0.0068). sLex antigen could be a candidate to be used as biomarker for the early diagnosis of cervical cancer.
Frustrated Lewis pairs: Design and reactivity
Sanjoy Mukherjee; Pakkirisamy Thilagar
2015-02-01
The interaction of a Lewis acid with a Lewis base results in the formation of a Lewis acid–base adduct. Understanding Lewis acids and bases is central to conceptualizing chemical interactions and constitutes a major portion of metal–ligand chemistry. Sterically encumbered/constrained Lewis pairs cannot form acid–base adducts, but such ‘Frustrated Lewis Pairs’ (FLPs), with their unquenched electronic demands can be elegantly used to simultaneously react with a third species, resulting in unusual reactivity of small molecules. Such unusual reactions, explored only in the last few years, have found several applications, e.g., heterolytic splitting of H2, activation of small molecules (CO2, N2O, etc.). FLPs have opened new opportunities in synthetic chemistry, covering organic, main group as well as transition metal chemistry. The design strategies adopted for FLP systems and their unique reactivity are discussed here.
Direct Numerical Simulation of the Rayleigh-Taylor Instability with the Spectral Element Method
ZHANG Xu; TAN Duo-Wang
2009-01-01
A novel method is proposed to simulate Rayleigh-Taylor instabilities using a specially-developed unsteady threedimensional high-order spectral element method code.The numerical model used consists of Navier-Stokes equations and a transport-diffusive equation.The code is first validated with the results of linear stability perturbation theory.Then several characteristics of the Rayleigh-Taylor instabjJjties are studied using this three-dimensional unsteady code,inducling instantaneous turbulent structures and statistical turbulent mixing heights under different initial wave numbers.These results indicate that turbulent structures ofRayleigh-Taylor instabilities are strongly dependent on the initial conditions.The results also suggest that a high-order numerical method should provide the capability of sir.ulating small scale fluctuations of Rayleigh-Taylor instabilities of turbulent flows.
Superconducting Microwave Electronics at Lewis Research Center
Warner, Joseph D.; Bhasin, Kul B.; Leonard, Regis F.
1991-01-01
Over the last three years, NASA Lewis Research Center has investigated the application of newly discovered high temperature superconductors to microwave electronics. Using thin films of YBa2Cu3O7-delta and Tl2Ca2Ba2Cu3Ox deposited on a variety of substrates, including strontium titanate, lanthanum gallate, lanthanum aluminate and magnesium oxide, a number of microwave circuits have been fabricated and evaluated. These include a cavity resonator at 60 GHz, microstrip resonators at 35 GHz, a superconducting antenna array at 35 GHz, a dielectric resonator at 9 GHz, and a microstrip filter at 5 GHz. Performance of some of these circuits as well as suggestions for other applications are reported.
Seismic Rayleigh Wave Digital Processing Technology
Jie, Li
2013-04-01
In Rayleigh wave exploration, the digital processing of data plays a very important position. This directly affects the interpretation of ground effect. Therefore, the use of accurate processing software and effective method in the Rayleigh wave exploration has important theoretical and practical significance. Previously, Rayleigh wave dispersion curve obtained by the one-dimensional phase analysis. This method requires channel spacing should be less than the effective wavelength. And minimal phase error will cause great changes in the phase velocity of Rayleigh wave. Damped least square method is a local linear model. It is easy to cause that inversion objective function cannot find the global optimal solution. Therefore, the method and the technology used in the past are difficult to apply the requirements of the current Rayleigh wave exploration. This study focused on the related technologies and algorithms of F-K domain dispersion curve extraction and GA global non-linear inversion, and combined with the impact of Rayleigh wave data acquisition parameters and the characteristics. Rayleigh wave exploration data processing software design and process technology research is completed. Firstly, the article describes the theoretical basis of Rayleigh wave method. This is also part of the theoretical basis of following treatment. The theoretical proof of existence of Rayleigh wave Dispersive in layered strata. Secondly, F-K domain dispersion curve extraction tests showed that the method can overcome the one-dimensional digital processing technology deficiencies, and make full use of multi-channel Rayleigh wave data record information. GA global non-linear inversion indicated that the inversion is not easy getting into local optimal solution. Thirdly, some examples illustrate each mode Rayleigh wave dispersion curve characteristics in the X-T domain. Tests demonstrated the impact on their extraction of dispersion curves. Parameters change example (including the X
Spectra and probability distributions of thermal flux in turbulent Rayleigh-B\\'{e}nard convection
Pharasi, Hirdesh K; Kumar, Krishna; Bhattacharjee, Jayanta K
2016-01-01
The spectra of turbulent heat flux $\\mathrm{H}(k)$ in Rayleigh-B\\'{e}nard convection with and without uniform rotation are presented. The spectrum $\\mathrm{H}(k)$ scales with wave number $k$ as $\\sim k^{-2}$. The scaling exponent is almost independent of the Taylor number $\\mathrm{Ta}$ and Prandtl number $\\mathrm{Pr}$ for higher values of the reduced Rayleigh number $r$ ($ > 10^3$). The exponent, however, depends on $\\mathrm{Ta}$ and $\\mathrm{Pr}$ for smaller values of $r$ ($<10^3$). The probability distribution functions of the local heat fluxes are non-Gaussian and have exponential tails.
Overview of Rayleigh-Taylor instability
Sharp, D.H.
1983-01-01
The aim of this talk is to survey Rayleigh-Taylor instability, describing the phenomenology that occurs at a Taylor unstable interface, and reviewing attempts to understand these phenomena quantitatively.
Rayleigh-Taylor mixing in supernova experiments
Swisher, N. C.; Abarzhi, S. I., E-mail: snezhana.abarzhi@gmail.com [Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); Kuranz, C. C. [University of Michigan, Ann Arbor, Michigan 48109 (United States); Arnett, D. [University of Arizona, Tucson, Arizona 85721 (United States); Hurricane, O.; Remington, B. A.; Robey, H. F. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)
2015-10-15
We report a scrupulous analysis of data in supernova experiments that are conducted at high power laser facilities in order to study core-collapse supernova SN1987A. Parameters of the experimental system are properly scaled to investigate the interaction of a blast-wave with helium-hydrogen interface, and the induced Rayleigh-Taylor instability and Rayleigh-Taylor mixing of the denser and lighter fluids with time-dependent acceleration. We analyze all available experimental images of the Rayleigh-Taylor flow in supernova experiments and measure delicate features of the interfacial dynamics. A new scaling is identified for calibration of experimental data to enable their accurate analysis and comparisons. By properly accounting for the imprint of the experimental conditions, the data set size and statistics are substantially increased. New theoretical solutions are reported to describe asymptotic dynamics of Rayleigh-Taylor flow with time-dependent acceleration by applying theoretical analysis that considers symmetries and momentum transport. Good qualitative and quantitative agreement is achieved of the experimental data with the theory and simulations. Our study indicates that in supernova experiments Rayleigh-Taylor flow is in the mixing regime, the interface amplitude contributes substantially to the characteristic length scale for energy dissipation; Rayleigh-Taylor mixing keeps order.
Nonlinear Laplacian spectral analysis of Rayleigh-Bénard convection
Brenowitz, N. D.; Giannakis, D.; Majda, A. J.
2016-06-01
The analysis of physical datasets using modern methods developed in machine learning presents unique challenges and opportunities. These datasets typically feature many degrees of freedom, which tends to increase the computational cost of statistical methods and complicate interpretation. In addition, physical systems frequently exhibit a high degree of symmetry that should be exploited by any data analysis technique. The classic problem of Rayleigh Benárd convection in a periodic domain is an example of such a physical system with trivial symmetries. This article presents a technique for analyzing the time variability of numerical simulations of two-dimensional Rayleigh-Bénard convection at large aspect ratio and intermediate Rayleigh number. The simulated dynamics are highly unsteady and consist of several convective rolls that are distributed across the domain and oscillate with a preferred frequency. Intermittent extreme events in the net heat transfer, as quantified by the time-weighted probability distribution function of the Nusselt number, are a hallmark of these simulations. Nonlinear Laplacian Spectral Analysis (NLSA) is a data-driven method which is ideally suited for the study of such highly nonlinear and intermittent dynamics, but the trivial symmetries of the Rayleigh-Bénard problem such as horizontal shift-invariance can mask the interesting dynamics. To overcome this issue, the vertical velocity is averaged over parcels of similar temperature and height, which substantially compresses the size of the dataset and removes trivial horizontal symmetries. This isothermally averaged dataset, which is shown to preserve the net convective heat-flux across horizontal surfaces, is then used as an input to NLSA. The analysis generates a small number of orthogonal modes which describe the spatiotemporal variability of the heat transfer. A regression analysis shows that the extreme events of the net heat transfer are primarily associated with a family of
Energy budget in Rayleigh-Bénard convection.
Kerr, R M
2001-12-10
It is shown using three series of Rayleigh number simulations of varying aspect ratio AR and Prandtl number Pr that the normalized dissipation at the wall, while significantly greater than 1, approaches a constant dependent upon AR and Pr. It is also found that the peak velocity, not the mean square velocity, obeys the experimental scaling of Ra(0.5). The scaling of the mean square velocity is closer to Ra(0.46), which is shown to be consistent with experimental measurements and the numerical results for the scaling of Nu and the temperature if there are strong correlations between the velocity and temperature.
Numerical investigation of the influence of gravity on the Rayleigh-Plateau jet instability
Rosello, M.; Maîtrejean, G.; Roux, D. C. D.; Jay, P.
2016-12-01
Controlled jet breakup processes are commonly used in many fields of industrial applications, such as inkjet printing, spray painting, and fuel injection. Most of these applications rely on the accurate prediction of the size of droplets resulting from breakup. While many parameters influence the droplets’ size, the present study focuses on the influence of the Bond number. This dimensionless number measures the influence of body forces compared with surface tension, which usually drives the Rayleigh-Plateau instability. The present work uses numerical simulation to assess the influence of the Bond number on both main droplets and satellites issuing from the Rayleigh-Plateau instability jet.
Drawing Lewis Structures without Anticipating Octets.
Carroll, James Allen
1986-01-01
After noting the grounds for labelling structures as incorrect, the guidelines for selecting which Lewis structures are most important for a molecule are introduced. Several examples of appropriate Lewis structures and the fine structural predictions that are possible are included. (JN)
Modeling of Rayleigh wave dispersion in Iberia
José Badal
2011-01-01
Full Text Available Phase and group velocities of 15–70 s Rayleigh waves propagating across the Iberian Peninsula have been transformed into local dispersion curves by linear inversion of travel times. The procedure permits that the waveform dispersion to be obtained as a continuous period-dependent velocity function at grid points belonging to the area probed by the waves, thus providing phase- and group-velocity contour maps for several periods within the interval of interest. The regionalization process rests on a homogeneous initial data set in which the number of observations remains almost constant for all periods of reference. Damped least-squares inversion of the local dispersion curves for shear-wave velocity structure is performed to obtain depth-dependent S-wave velocity profiles at the grid points covering the model region. The reliability of the results should improve significantly owing to the use of phase and group velocities simultaneously. On this basis, we have built horizontal depth sections that give an updated view of the seismic velocity structure of the peninsula at lithospheric and upper mantle depths (20–200 km. After averaging all the pure-path S-wave velocities previously determined at each grid point, the velocity-depth models so obtained for major tectonic units allow the comparison between the Hercynian basement and other areas of Mesozoic folding and Tertiary basins.
Feedback control and heat transfer measurements in a Rayleigh-Bénard convection cell
Vial, M.; Hernández, R. H.
2017-07-01
We report experimental results on the heat transfer and instability onset of a Rayleigh-Bénard convection cell of aspect ratios 6:3:1 filled with a high Prandtl aqueous solution of glycerol under feedback control. We investigate the transient and stationary response of both local temperature readings and heat transfer fluxes on the Rayleigh Bénard cell in both conductive and convective states when we perform two independent feedback control actions on both hot and cold walls. We evaluate the performance of both controllers to maintain a temperature gradient independently if the system is below or above the convection threshold. As the convection cell can be rotated at 180° about the shorter axis of the cell, it was possible to perform transitions between thermal conduction and convection regimes and vice versa under a constant temperature difference maintained by both independent controllers. The experimental setup provided an accurate measurement of the critical Rayleigh number and the evolution of the Nusselt number as a function of the Rayleigh number in the moderately supercritical regime (R a convection pattern formed by 6 transverse rolls throughout the range of Rayleigh numbers.
Cloud patterns and mixing properties in shallow moist Rayleigh-Benard convection
Weidauer, Thomas; Schumacher, Joerg [Institut fuer Thermo- und Fluiddynamik, Postfach 100565, Technische Universitaet Ilmenau, D-98684 Ilmenau (Germany); Pauluis, Olivier, E-mail: thomas.weidauer@tu-ilmenau.d, E-mail: pauluis@cims.nyu.ed, E-mail: joerg.schumacher@tu-ilmenau.d [Courant Institute of Mathematical Sciences, New York University, 251 Mercer Street, New York, NY 10012-1185 (United States)
2010-10-15
Three-dimensional direct numerical simulations of idealized moist turbulent Rayleigh-Benard convection are presented. The thermodynamics of moist air is linearized close to the phase boundary between water vapor and liquid water. This formulation allows for a simplified saturation condition for the cloud formation, but omits supersaturation and rain. The sensitivity of this problem to changes of the Rayleigh number, the aspect ratio of the convection layer and the water vapor concentration is studied. The Rayleigh number is found to impact the behavior of the system in multiple ways. First, the relaxation time toward a well-mixed turbulent state increases with the Rayleigh number. Similarly, the flow exhibits a higher spatial and temporal intermittency at higher Rayleigh number. This is in line with an enhanced intermittency of the upward buoyancy flux, which we quantify by a multifractal analysis. In addition, phase transition introduces an asymmetry in the distribution of the thermodynamic properties of the well-mixed state. This asymmetry is most pronounced in layers where clouds are partially present. Furthermore, the geometrical properties of the cloud formations averaged with respect to the height of the layer are studied. Similar to isocontours in scalar mixing, the boundaries of isolated clouds show no strict (mono-)fractal behavior. The results of the perimeter-area analysis of the largest isolated clouds agree well with those of large eddy simulations of cumulus convection. This perimeter-area scaling is also similar to that of percolation processes in a plane.
On the concept of frustrated Lewis pairs.
Fontaine, Frédéric-Georges; Stephan, Douglas W
2017-08-28
In this concept article, we consider the notion of 'frustrated Lewis pairs' (FLPs). While the original use of the term referred to steric inhibition of dative bond formation in a Lewis pair, work in the intervening decade demonstrates the limitation of this simplistic view. Analogies to known transition metal chemistry and the applications in other areas of chemistry are considered. In the light of these findings, we present reflections on the criteria for a definition of the term 'frustrated Lewis pair'. Segregation of the Lewis acid and base and the kinetic nature of FLP reactivity are discussed. We are led to the conclusion that, while an all-inclusive definition of FLP is challenging, the notion of 'FLP chemistry' is more readily recognized.This article is part of the themed issue 'Frustrated Lewis pair chemistry'. © 2017 The Author(s).
Thioarsenides: A case for long-range Lewis acid-base-directed van der Waals interactions
Gibbs, Gerald V.; Wallace, Adam F.; Downs, R. T.; Ross, Nancy L.; Cox, David F.; Rosso, Kevin M.
2011-04-01
Electron density distributions, bond paths, Laplacian and local energy density properties have been calculated for a number of As4Sn (n = 3,4,5) thioarsenide molecular crystals. On the basis of the distributions, the intramolecular As-S and As-As interactions classify as shared bonded interactions and the intermolecular As-S, As-As and S-S interactions classify as closed-shell van der Waals bonded interactions. The bulk of the intermolecular As-S bond paths link regions of locally concentrated electron density (Lewis base regions) with aligned regions of locally depleted electron density (Lewis acid regions) on adjacent molecules. The paths are comparable with intermolecular paths reported for several other molecular crystals that link aligned Lewis base and acid regions in a key-lock fashion, interactions that classified as long range Lewis acid-base directed van der Waals interactions. As the bulk of the intermolecular As-S bond paths (~70%) link Lewis acid-base regions on adjacent molecules, it appears that molecules adopt an arrangement that maximizes the number of As-S Lewis acid-base intermolecular bonded interactions. The maximization of the number of Lewis acid-base interactions appears to be connected with the close-packed array adopted by molecules: distorted cubic close-packed arrays are adopted for alacránite, pararealgar, uzonite, realgar and β-AsS and the distorted hexagonal close-packed arrays adopted by α- and β-dimorphite. A growth mechanism is proposed for thioarsenide molecular crystals from aqueous species that maximizes the number of long range Lewis acid-base vdW As-S bonded interactions with the resulting directed bond paths structuralizing the molecules as a molecular crystal.
Visual Hallucinations in PD and Lewy Body Dementias: Old and New Hypotheses
M. Onofrj
2013-01-01
Full Text Available Visual Hallucinations (VH are a common non-motor symptom of Parkinson’s Disease (PD and the Lewy body dementias (LBD of Parkinson's disease with dementia (PDD and Dementia with Lewy Bodies (DLB. The origin of VH in PD and LBD is debated: earlier studies considered a number of different possible mechanisms underlying VH including visual disorders, Rapid Eye Movement (REM Sleep Intrusions, dysfunctions of top down or bottom up visual pathways, and neurotransmitter imbalance.
Quantification of Lewis acid induced Brønsted acidity of protogenic Lewis bases.
Lathem, A Paige; Heiden, Zachariah M
2017-05-09
Proton transfer promoted by the coordination of protogenic Lewis bases to a Lewis acid is a critical step in catalytic transformations. Although the acidification of water upon coordination to a Lewis acid has been known for decades, no attempts have been made to correlate the Brønsted acidity of the coordinated water molecule with Lewis acid strength. To probe this effect, the pKa's (estimated error of 1.3 pKa units) in acetonitrile of ten protogenic Lewis bases coordinated to seven Lewis acids containing Lewis acidities varying 70 kcal mol(-1), were computed. To quantify Lewis acid strength, the ability to transfer a hydride (hydride donor ability) from the respective main group hydride was used. Coordination of a Lewis acid to water increased the acidity of the bound water molecule between 20 and 50 pKa units. A linear correlation exhibiting a 2.6 pKa unit change of the Lewis acid-water adduct per ten kcal mol(-1) change in hydride donor ability of the respective main group hydride was obtained. For the ten protogenic Lewis bases studied, the coordinated protogenic Lewis bases were acidified between 10 and 50 pKa units. On average, a ten kcal mol(-1) change in hydride donor ability of the respective main group hydride resulted in about a 2.8 pKa unit change in the Brønsted acidity of the Lewis acid-Lewis base adducts. Since attempts to computationally investigate the pKa of main group dihydrogen complexes were unsuccessful, experimental determination of the first reported pKa of a main group dihydrogen complex is described. The pKa of H2-B(C6F5)3 was determined to be 5.8 ± 0.2 in acetonitrile.
Rayleigh--Taylor spike evaporation
Schappert, G. T.; Batha, S. H.; Klare, K. A.; Hollowell, D. E.; Mason, R. J.
2001-09-01
Laser-based experiments have shown that Rayleigh--Taylor (RT) growth in thin, perturbed copper foils leads to a phase dominated by narrow spikes between thin bubbles. These experiments were well modeled and diagnosed until this '' spike'' phase, but not into this spike phase. Experiments were designed, modeled, and performed on the OMEGA laser [T. R. Boehly, D. L. Brown, R. S. Craxton , Opt. Commun. 133, 495 (1997)] to study the late-time spike phase. To simulate the conditions and evolution of late time RT, a copper target was fabricated consisting of a series of thin ridges (spikes in cross section) 150 {mu}m apart on a thin flat copper backing. The target was placed on the side of a scale-1.2 hohlraum with the ridges pointing into the hohlraum, which was heated to 190 eV. Side-on radiography imaged the evolution of the ridges and flat copper backing into the typical RT bubble and spike structure including the '' mushroom-like feet'' on the tips of the spikes. RAGE computer models [R. M. Baltrusaitis, M. L. Gittings, R. P. Weaver, R. F. Benjamin, and J. M. Budzinski, Phys. Fluids 8, 2471 (1996)] show the formation of the '' mushrooms,'' as well as how the backing material converges to lengthen the spike. The computer predictions of evolving spike and bubble lengths match measurements fairly well for the thicker backing targets but not for the thinner backings.
Heat transport measurements in turbulent rotating Rayleigh-Benard convection
Ecke, Robert E [Los Alamos National Laboratory; Liu, Yuanming [Los Alamos National Laboratory
2008-01-01
We present experimental heat transport measurements of turbulent Rayleigh-Benard convection with rotation about a vertical axis. The fluid, water with Prandtl number ({sigma}) about 6, was confined in a cell which had a square cross section of 7.3 cm x 7.3 cm and a height of 9.4 cm. Heat transport was measured for Rayleigh numbers 2 x 10{sup 5} < Ra < 5 x 10{sup 8} and Taylor numbers 0 < Ta < 5 x 10{sup 9}. We show the variation of normalized heat transport, the Nusselt number, at fixed dimensional rotation rate {Omega}{sub D}, at fixed Ra varying Ta, at fixed Ta varying Ra, and at fixed Rossby number Ro. The scaling of heat transport in the range 10{sup 7} to about 10{sup 9} is roughly 0.29 with a Ro dependent coefficient or equivalently is also well fit by a combination of power laws of the form a Ra{sup 1/5} + b Ra{sup 1/3} . The range of Ra is not sufficient to differentiate single power law or combined power law scaling. The overall impact of rotation on heat transport in turbulent convection is assessed.
Spatial correlation of temperature in turbulent Rayleigh-Bénard convection.
Haramina, T; Tilgner, A
2006-12-01
A cubic Rayleigh-Bénard cell is operated at a Rayleigh number of 1.5x10(9) and a Prandtl number of 6.1. The cell is equipped with thermistors placed along the vertical line through the center of the cell. The spatial correlation of temperature is deduced from simultaneous temperature recordings from these thermistors. The correlation function is well fitted by the sum of two exponentials. There is no cascade in the temperature field as only two characteristic length scales appear. The direct measurement of spatial correlations allows us to test the validity of Taylor's hypothesis in this flow.
Boundary layers in turbulent Rayleigh-B\\'enard convection in air
Puits, Ronald du; Resagk, Christian; Thess, André
2012-01-01
The boundary layer flow in a Rayleigh-B\\'enard convection cell of rectangular shape has been visualized in this fluid dynamics video. The experiment has been undertaken in air at a Rayleigh number $Ra=1.3\\times 10^{10}$ and a Prandtl number $Pr=0.7$. Various sequences captured at selected positions of the heating plate show that the boundary layer is a very transient flow region characterized by coherent structures that permanently evolve. It becomes fully turbulent in the areas where the large-scale circulation impinge or leave the bottom plate.
Transient growth in Rayleigh-B\\'enard-Poiseuille/Couette convection
Jerome, J John Soundar; Huerre, Patrick
2016-01-01
An investigation of the effect of a destabilizing cross-stream temperature gradient on the transient growth phenomenon of plane Poiseuille flow and plane Couette flow is presented. Only the streamwise-uniform and nearly streamwise-uniform disturbances are highly influenced by the Rayleigh number Ra and Prandtl number Pr. The maximum optimal transient growth G max of streamwise-uniform disturbances increases slowly with increasing Ra and decreasing Pr. For all Ra and Pr, at moderately large Reynolds numbersRe, the supremum of G max is always attained for streamwise-uniform perturbations (or nearly streamwise-uniform perturbations, in the case of plane Couette flow) which produce large streamwise streaks and Rayleigh-B\\'enard convection rolls (RB). The optimal growth curves retain the same large-Reynolds-number scaling as in pure shear flow. A 3D vector model of the governing equations demonstrates that the short-time behavior is governed by the classical lift-up mechanism and that the influence of Ra on this m...
Chromo-Rayleigh Interactions of Dark Matter
Bai, Yang
2015-01-01
For a wide range of models, dark matter can interact with QCD gluons via chromo-Rayleigh interactions. We point out that the Large Hadron Collider (LHC), as a gluon machine, provides a superb probe of such interactions. In this paper, we introduce simplified models to UV-complete two effective dark matter chromo-Rayleigh interactions and identify the corresponding collider signatures, including four jets or a pair of di-jet resonances plus missing transverse energy. After performing collider studies for both the 8 TeV and 14 TeV LHC, we find that the LHC can be more sensitive to dark matter chromo-Rayleigh interactions than direct detection experiments and thus provides the best opportunity for future discovery of this class of models.
Moist turbulent Rayleigh-Benard convection with Neumann and Dirichlet boundary conditions
Weidauer, Thomas
2012-01-01
Turbulent Rayleigh-Benard convection with phase changes in an extended layer between two parallel impermeable planes is studied by means of three-dimensional direct numerical simulations for Rayleigh numbers between 10^4 and 1.5\\times 10^7 and for Prandtl number Pr=0.7. Two different sets of boundary conditions of temperature and total water content are compared: imposed constant amplitudes which translate into Dirichlet boundary conditions for the scalar field fluctuations about the quiescent diffusive equilibrium and constant imposed flux boundary conditions that result in Neumann boundary conditions. Moist turbulent convection is in the conditionally unstable regime throughout this study for which unsaturated air parcels are stably and saturated air parcels unstably stratified. A direct comparison of both sets of boundary conditions with the same parameters requires to start the turbulence simulations out of differently saturated equilibrium states. Similar to dry Rayleigh-Benard convection the differences...
V Ganesh; M Subbiah
2013-05-01
We generalize Tollmien’s solutions of the Rayleigh problem of hydrodynamic stability to the case of arbitrary channel cross sections, known as the extended Rayleigh problem. We prove the existence of a neutrally stable eigensolution with wave number $k_s>0$; it is also shown that instability is possible only for $0 < k < k_s$ and not for $k>k_s$. Then we generalize the Tollmien–Lin perturbation formula for the behavior of $c_i$, the imaginary part of the phase velocity as the wave number $k→ k_s$ − to the extended Rayleigh problem and subsequently, we use this formula to demonstrate the instability of a particular shear flow.
Bivariate Rayleigh Distribution and its Properties
Ahmad Saeed Akhter
2007-01-01
Full Text Available Rayleigh (1880 observed that the sea waves follow no law because of the complexities of the sea, but it has been seen that the probability distributions of wave heights, wave length, wave induce pitch, wave and heave motions of the ships follow the Rayleigh distribution. At present, several different quantities are in use for describing the state of the sea; for example, the mean height of the waves, the root mean square height, the height of the “significant waves” (the mean height of the highest one-third of all the waves the maximum height over a given interval of the time, and so on. At present, the ship building industry knows less than any other construction industry about the service conditions under which it must operate. Only small efforts have been made to establish the stresses and motions and to incorporate the result of such studies in to design. This is due to the complexity of the problem caused by the extensive variability of the sea and the corresponding response of the ships. Although the problem appears feasible, yet it is possible to predict service conditions for ships in an orderly and relatively simple manner Rayleigh (1980 derived it from the amplitude of sound resulting from many independent sources. This distribution is also connected with one or two dimensions and is sometimes referred to as “random walk” frequency distribution. The Rayleigh distribution can be derived from the bivariate normal distribution when the variate are independent and random with equal variances. We try to construct bivariate Rayleigh distribution with marginal Rayleigh distribution function and discuss its fundamental properties.
Reflectometry using longitudinal, shear and Rayleigh waves.
Chen, W; Wu, J
2000-09-01
A new technique of reflectometry using longitudinal, shear and Rayleigh waves is presented. Reflection coefficient as a function of angle incidence of an ultrasound beam with a finite beamwidth was measured for water-aluminum, water-brass, and water-glass interfaces. The measured values have matched very favorably with the results of numerical calculations based on the angular spectrum of waves method. It has been shown that the speeds of longitudinal, shear and Rayleigh waves of a solid can be determined very accurately by measuring a spectacularly reflected signal versus angle of incidence.
Optical results with Rayleigh quotient discrimination filters
Juday, Richard D.; Rollins, John M.; Monroe, Stanley E., Jr.; Morelli, Michael V.
1999-03-01
We report experimental laboratory results using filters that optimize the Rayleigh quotient [Richard D. Juday, 'Generalized Rayleigh quotient approach to filter optimization,' JOSA-A 15(4), 777-790 (April 1998)] for discriminating between two similar objects. That quotient is the ratio of the correlation responses to two differing objects. In distinction from previous optical processing methods it includes the phase of both objects -- not the phase of only the 'accept' object -- in the computation of the filter. In distinction from digital methods it is explicitly constrained to optically realizable filter values throughout the optimization process.
Alboussiere, Thierry
2016-01-01
The linear stability threshold of the Rayleigh-Benard configuration is analyzed with compressible effects taken into account. It is assumed that the fluid obeys a Newtonian rheology and Fourier's law of thermal transport with constant, uniform (dynamic) viscosity and thermal conductivity in a uniform gravity field. Top and bottom boundaries are maintained at different constant temperatures and we consider here boundary conditions of zero tangential stress and impermeable walls. Under these conditions, and with the Boussinesq approximation, Rayleigh (1916) first obtained analytically the critical value 27pi^4/4 for a dimensionless parameter, now known as the Rayleigh number, at the onset of convection. This manuscript describes the changes of the critical Rayleigh number due to the compressibility of the fluid, measured by the dimensionless dissipation parameter D and due to a finite temperature difference between the hot and cold boundaries, measured by a dimensionless temperature gradient a. Different equati...
Peripheral Lewy body pathology in Parkinson's disease and incidental Lewy body disease: four cases.
Del Tredici, Kelly; Duda, John E
2011-11-15
The accumulation of Lewy pathology (LP) within autonomic nervous system tissues has received increased attention recently as a possible induction site for Lewy neurodegeneration and a possible source of biopsy material for biomarkers of early Parkinson's disease (PD). Here, we describe LP accumulation within various tissues involving peripheral autonomic nervous system neurons in three PD cases and one case of incidental Lewy body disease. Findings highlight the value of examining pathology within functional neuroanatomical systems and particularly the importance of Lewy neurites (LNs) in the pathophysiology of PD.
Abegg, Lewis, Langmuir, and the Octet Rule.
Jensen, William B.
1984-01-01
Discusses major events leading to the development of the octet rule. Three conclusions based on the work of Mendeleev, Abegg, Thompson, Kossel, Lewis, and Langmuir are considered as is the debate over the rule's validity. (JN)
Boundary layer structure in turbulent Rayleigh-Benard convection
Shi, Nan; Schumacher, Joerg
2012-01-01
The structure of the boundary layers in turbulent Rayleigh-Benard convection is studied by means of three-dimensional direct numerical simulations. We consider convection in a cylindrical cell at an aspect ratio one for Rayleigh numbers of Ra=3e+9 and 3e+10 at fixed Prandtl number Pr=0.7. Similar to the experimental results in the same setup and for the same Prandtl number, the structure of the laminar boundary layers of the velocity and temperature fields is found to deviate from the prediction of the Prandtl-Blasius-Pohlhausen theory. Deviations decrease when a dynamical rescaling of the data with an instantaneously defined boundary layer thickness is performed and the analysis plane is aligned with the instantaneous direction of the large-scale circulation in the closed cell. Our numerical results demonstrate that important assumptions which enter existing classical laminar boundary layer theories for forced and natural convection are violated, such as the strict two-dimensionality of the dynamics or the s...
Optimal Heat Transport in Rayleigh-B\\'enard Convection
Sondak, David; Waleffe, Fabian
2015-01-01
Steady flows that optimize heat transport are obtained for two-dimensional Rayleigh-B\\'enard convection with no-slip horizontal walls for a variety of Prandtl numbers $Pr$ and Rayleigh number up to $Ra\\sim 10^9$. Power law scalings of $Nu\\sim Ra^{\\gamma}$ are observed with $\\gamma\\approx 0.31$, where the Nusselt number $Nu$ is a non-dimensional measure of the vertical heat transport. Any dependence of the scaling exponent on $Pr$ is found to be extremely weak. On the other hand, the presence of two local maxima of $Nu$ with different horizontal wavenumbers at the same $Ra$ leads to the emergence of two different flow structures as candidates for optimizing the heat transport. For $Pr \\lesssim 7$, optimal transport is achieved at the smaller maximal wavenumber. In these fluids, the optimal structure is a plume of warm rising fluid which spawns left/right horizontal arms near the top of the channel, leading to downdrafts adjacent to the central updraft. For $Pr > 7$ at high-enough Ra, the optimal structure is a...
75 FR 27845 - Tennessee Disaster Number TN-00038
2010-05-18
..., Hardin, Jackson, Lauderdale, Lawrence, Lewis, Macon, Robertson, Smith, Stewart, Trousdale, Wayne, Wilson... Assistance Numbers 59002 and 59008) James E. Rivera, Associate Administrator for Disaster Assistance. [FR...
75 FR 27846 - Tennessee Disaster Number TN-00039
2010-05-18
..., Lewis, Macon, Robertson, Smith, Stewart, Trousdale, Wayne, Wilson. Contiguous Counties: (Economic Injury... declaration remains unchanged. (Catalog of Federal Domestic Assistance Numbers 59002 and 59008) James...
Neurophysiological biomarkers for Lewy body dementias
Cromarty, Ruth A.; Elder, Greg J.; Graziadio, Sara; Baker, Mark; Bonanni, Laura; Onofrj, Marco; O’Brien, John T.; Taylor, John-Paul
2016-01-01
Objective Lewy body dementias (LBD) include both dementia with Lewy bodies (DLB) and Parkinson’s disease with dementia (PDD), and the differentiation of LBD from other neurodegenerative dementias can be difficult. Currently, there are few biomarkers which might assist early diagnosis, map onto LBD symptom severity, and provide metrics of treatment response. Traditionally, biomarkers in LBD have focussed on neuroimaging modalities; however, as biomarkers need to be simple, inexpensive and non-...
Lewis acidity enhancement of triarylborane by appended phosphine oxide groups.
Kwak, Jaewoo; Nghia, Nguyen Van; Lee, Junseong; Kim, Hyoseok; Park, Myung Hwan; Lee, Min Hyung
2015-03-14
A series of mono-, di-, and tri-phosphine oxide substituted triarylboranes, Mes2BAr (1), MesBAr2 (2), and BAr3 (3) (Ar = 4-(Ph2PO)-2,6-Me2-C6H2) were prepared to investigate the effect of a phosphine oxide group (Ph2PO) on Lewis acidity enhancement of triarylboranes. The X-ray crystal structure of 3 revealed peripheral decoration of Ph2PO groups with a C3-axis perpendicular to the trigonal boron center. UV/Vis absorption and PL spectra indicated a significant contribution of π(Mes or phenylene) → pπ(B) charge transfer in the lower-energy electronic transition. The reduction potential measured by cyclic voltammetry showed apparent LUMO stabilization by introduction of phosphine oxide groups, the extent of which gradually increased with the increasing number of phosphine oxide groups. Lewis acidity enhancement was also supported by the gradual increase in fluoride ion affinity in the order 3 > 2 > 1. Theoretical calculations suggest that introduction of a Ph2PO group into a triarylborane significantly enhances the Lewis acidity of the boron center via an inductive electron-withdrawing effect and this effect is additive for multiple phosphine oxide groups.
Slovene critics on Sinclair Lewis's novels
Vanja Avsenak
2010-12-01
Full Text Available The purpose of this article is to present the reception of Sinclair Lewis's novels by Slovene critics. Initially, the article focuses on the life and workof Sinclair Lewis, giving special emphasis to social influences that made the author a representative figure in the literary and social world. Thus his works are nowadays to be understood primarily as fiction, but on the other hand also as sociological documents of a social and political situation of the period between the two world wars. Generally, the effect they produce is one of a critical discussion of the nation of the United States. When speaking of the social relevance that Lewis's novels have, it is obvious that his works are the portrayals of Americans and their deficiencies. At the time of their publication Lewis's novels received unfavourable criticism on accountof his overly open pro-European attitude and Slovene critics of the period before World War II emphasise this in much detail. It was precisely this anti-American propaganda in the novels themselves and sincerity on the part of the novelist that won the European critics as well as the readers whenit came to appreciating his works. However, Lewis's view of the Americans, as presented throughout his works, only enhanced his literary credibility as a modern writer. That is why the articles by Slovene critics that appeared after the Second World War, and even more significantly after Lewis's death, almost minutely reflect a more favourable attitude to Sinclair Lewis, which was also the case with foreign literary criticism of the post-war period. Critics still discuss the qualities and flaws of Lewis's novels, but being more lenient they no longer profess that the novels lack in artistic value. They remain, however, primarily relevant as social documents of the pre- and post-war era, which fully presented the American middle-class mentality in America and elsewhere. For this reason, the Nobel Prize for Literature awarded to
Multiplicity of steady states in cylindrical Rayleigh-Bénard convection.
Ma, Dong-Jun; Sun, De-Jun; Yin, Xie-Yuan
2006-09-01
Three-dimensional steady Rayleigh-Bénard convection in a vertical cylinder is investigated by numerical simulation and bifurcation analysis. The complex pattern formation beyond the onset of the convection is presented by a bifurcation diagram. The coexistence of multiple stable states is observed near the threshold of the first bifurcation and two group symmetries are summarized for the corresponding primary branches. The first stable target pattern originates through a subcritical bifurcation. A multiplicity of flow states for the Rayleigh number of 14200 is validated numerically in comparison with the experiment, and a four-spoke pattern is observed.
Ramos, I C
2015-01-01
We present the adaptation to non--free boundary conditions of a pseudospectral method based on the (complex) Fourier transform. The method is applied to the numerical integration of the Oberbeck--Boussinesq equations in a Rayleigh--B\\'enard cell with no-slip boundary conditions for velocity and Dirichlet boundary conditions for temperature. We show the first results of a 2D numerical simulation of dry air convection at high Rayleigh number ($R\\sim10^9$). These results are the basis for the later study, by the same method, of wet convection in a solar still.
Rayleigh-Taylor instability of viscous fluids with phase change
Kim, Byoung Jae; Kim, Kyung Doo
2016-04-01
Film boiling on a horizontal surface is a typical example of the Rayleigh-Taylor instability. During the film boiling, phase changes take place at the interface, and thus heat and mass transfer must be taken into consideration in the stability analysis. Moreover, since the vapor layer is not quite thick, a viscous flow must be analyzed. Existing studies assumed equal kinematic viscosities of two fluids, and/or considered thin viscous fluids. The purpose of this study is to derive the analytical dispersion relation of the Rayleigh-Taylor instability for more general conditions. The two fluids have different properties. The thickness of the vapor layer is finite, but the liquid layer is thick enough to be nearly semi-infinite in view of perturbation. Initially, the vapor is in equilibrium with the liquid at the interface, and the direction of heat transfer is from the vapor side to the liquid side. In this case, the phase change has a stabilizing effect on the growth rate of the interface. When the vapor layer is thin, there is a coupled effect of the vapor viscosity, phase change, and vapor thickness on the critical wave number. For the other limit of a thick vapor, both the liquid and vapor viscosities influence the critical wave number. Finally, the most unstable wavelength is investigated. When the vapor layer is thin, the most unstable wavelength is not affected by phase change. When the vapor layer is thick, however, it increases with the increasing rate of phase change.
Ferrocene-based Lewis acids and Lewis pairs: Synthesis and structural characterization
Pagidi Sudhakar; Pakkirisamy Thilagar
2013-01-01
Optically active Lewis acids and Lewis pairs were synthesized and characterized by multinuclear NMR, UV/Vis spectroscopy and elemental analysis. Optical rotation measurements were carried out and the absolute configuration of the new chiral molecules confirmed by single crystal X-ray diffraction.
Effect of plumes on measuring the large scale circulation in turbulent Rayleigh-Bénard convection
Stevens, Richard Johannes Antonius Maria; Clercx, H.J.H.; Lohse, Detlef
2011-01-01
We studied the properties of the large-scale circulation (LSC) in turbulent Rayleigh-Bénard (RB) convection by using results from direct numerical simulations in which we placed a large number of numerical probes close to the sidewall. The LSC orientation is determined by either a cosine or a
Experimental study of 3D Rayleigh-Taylor convection between miscible fluids in a porous medium
Nakanishi, Yuji; Hyodo, Akimitsu; Wang, Lei; Suekane, Tetsuya
2016-11-01
The natural convection of miscible fluids in porous media has applications in several fields, such as geoscience and geoengineering, and can be employed for the geological storage of CO2. In this study, we used X-ray computer tomography to visualize 3D fingering structures associated with the Rayleigh-Taylor instability between miscible fluids in a porous medium. In the early stages of the onset of the Rayleigh-Taylor instability, a fine crinkling pattern gradually appeared at the interface. As the wavelength and amplitude increased, descending fingers formed on the interface and extended vertically downward; in addition, ascending and highly symmetric fingers formed. The adjacent fingers were cylindrical in shape and coalesced to form large fingers. The fingers appearing on the interface tended to become finer with increasing Rayleigh number, which is consistent with linear perturbation theory. When the Péclet number exceeded 10, transverse dispersion increased the finger diameter and enhanced the finger coalescence, strongly impacting the decrease in finger number density. When mechanical dispersion was negligible, the finger-extension velocity and the dimensionless mass-transfer rate scaled with the characteristic velocity and the Rayleigh number with an appropriate length scale. Mechanical dispersion not only reduced the onset time but also enhanced the mass transport.
Scales of Lewis basicities toward C-centered Lewis acids (carbocations).
Mayr, Herbert; Ammer, Johannes; Baidya, Mahiuddin; Maji, Biplab; Nigst, Tobias A; Ofial, Armin R; Singer, Thomas
2015-02-25
Equilibria for the reactions of benzhydryl cations (Ar2CH(+)) with phosphines, tert-amines, pyridines, and related Lewis bases were determined photometrically in CH2Cl2 and CH3CN solution at 20 °C. The measured equilibrium constants can be expressed by the sum of two parameters, defined as the Lewis Acidity (LA) of the benzhydrylium ions and the Lewis basicity (LB) of the phosphines, pyridines, etc. Least-squares minimization of log K = LA + LB with the definition LA = 0 for (4-MeOC6H4)2CH(+) gave a Lewis acidity scale for 18 benzhydrylium ions covering 18 orders of magnitude in CH2Cl2 as well as Lewis basicities (with respect to C-centered Lewis acids) for 56 bases. The Lewis acidities correlated linearly with the quantum chemically calculated (B3LYP/6-311++G(3df,2pd)//B3LYP/6-31G(d,p) level) methyl anion affinities of the corresponding benzhydrylium ions, which can be used as reference compounds for characterizing a wide variety of Lewis bases. The equilibrium measurements were complemented by isothermal titration calorimetry studies. Rates of SN1 solvolyses of benzhydryl chlorides, bromides, and tosylates derived from E(13-33)(+), i.e., from highly reactive carbocations, correlate excellently with the corresponding Lewis acidities and the quantum chemically calculated methyl anion affinities. This correlation does not hold for solvolyses of derivatives of the better stabilized amino-substituted benzhydrylium ions E(1-12)(+). In contrast, the correlation between electrophilic reactivities and Lewis acidities (or methyl anion affinities) is linear for all donor-substituted benzhydrylium ions E(1-21)(+), while the acceptor-substituted benzhydrylium ions E(26-33)(+) react more slowly than expected from their thermodynamic stabilities. The boundaries of linear rate-equilibrium relationships were thus defined.
Wang, Xu; Wang, Ping-fan; Yuan, Wu-ying
2014-12-01
We sought to find the biological effects of MicroRNA-2 in suppressing Lewis lung cancer cells proliferation, invasion, and migration in tumor-bearing mice. MicroRNA-2 was transfected into Lewis lung cancer cells of tumor-bearing mice by gene transient transfection technique and these Lewis-microRNA-2 cells were taken as MicroRNA transfection group. At the same time, Lewis cells were taken as control group and Lewis-EGFP cells as empty plasmid group. The growth curves of cells in the three groups were drawn by manual counting method, while the invasiveness of cells in the three groups was compared by transmembrane cell invasion assay. The three kinds of cells were seeded into BALB/Nude SPF level nude mice to detect the formation of tumors and the number of metastases by Xenograft experiments. The result showed that the MicroRNA transfection group has the lowest vitality of cells proliferation, fewest cells passed through matrigel matrix protein layer, and lowest cells invasive rate. Mice with Lewis-microRNA-2 cells apparently had a longer time of tumor formation. The average tumor mass and the number of metastases were significantly lower than the other two groups. MicroRNA-2 significantly inhibited Lewis lung cancer cell proliferation, invasion and migration in tumor-bearing mice, which may be associated with the regulation of target genes PLK1 and TGF-β.
Flow structure in turbulent rotating Rayleigh-Bénard convection
Kunnen, Rudie; Corre, Yoann; Clercx, Herman
2012-11-01
Turbulent Rayleigh-Bénard convection is usually studied in an upright cylinder. The addition of axial rotation has profound effects on the flow structuring. The well-known large-scale circulation (LSC) of the non-rotating case is still found at low rotation rates but is replaced by an irregular array of vertically aligned vortical plumes at higher rotation rates. We report PIV measurements of turbulent rotating convection in a cylindrical cell of diameter-to-height aspect ratio Γ = 1 / 2 at Rayleigh number Ra = 4 . 5 ×109 and at many rotation rates covering both the LSC and the vortical-plume regime. We focus on: (i) the azimuthal precession of the LSC, (ii) collective motions of the vortical plumes, and (iii) the sidewall boundary layers. With these results we can clarify remarkable differences between the Γ = 1 and Γ = 1 / 2 cases reported recently in the literature. Traineeship project carried out in Eindhoven as part of Master's Degree at Université Paris-Sud, France.
Sidewall effects in Rayleigh-B\\'enard convection
Stevens, Richard J A M; Verzicco, Roberto
2014-01-01
We investigate the influence of the temperature boundary conditions at the sidewall on the heat transport in Rayleigh-B\\'enard (RB) convection using direct numerical simulations. For relatively low Rayleigh numbers Ra the heat transport is higher when the sidewall is isothermal, kept at a temperature $T_c+\\Delta/2$ (where $\\Delta$ is the temperature difference between the horizontal plates and $T_c$ the temperature of the cold plate), than when the sidewall is adiabatic. The reason is that in the former case part of the heat current avoids the thermal resistance of the fluid layer by escaping through the sidewall that acts as a short-circuit. For higher Ra the bulk becomes more isothermal and this reduces the heat current through the sidewall. Therefore the heat flux in a cell with an isothermal sidewall converges to the value obtained with an adiabatic sidewall for high enough Ra ($\\simeq 10^{10}$). However, when the sidewall temperature deviates from $T_c+\\Delta/2$ the heat transport at the bottom and top p...
Ergodicity in randomly forced Rayleigh-Bénard convection
Földes, J.; Glatt-Holtz, N. E.; Richards, G.; Whitehead, J. P.
2016-11-01
We consider the Boussinesq approximation for Rayleigh-Bénard convection perturbed by an additive noise and with boundary conditions corresponding to heating from below. In two space dimensions, with sufficient stochastic forcing in the temperature component and large Prandtl number Pr > 0, we establish the existence of a unique ergodic invariant measure. In three space dimensions, we prove the existence of a statistically invariant state, and establish unique ergodicity for the infinite Prandtl Boussinesq system. Throughout this work we provide streamlined proofs of unique ergodicity which invoke an asymptotic coupling argument, a delicate usage of the maximum principle, and exponential martingale inequalities. Lastly, we show that the background method of Constantin and Doering (1996 Nonlinearity 9 1049-60) can be applied in our stochastic setting, and prove bounds on the Nusselt number relative to the unique invariant measure.
EVALUATION OF MIMO SYSTEM CAPACITY OVER RAYLEIGH FADING CHANNEL
Emad. Mohamed
2015-06-01
Full Text Available High transmission data rate, spectral efficiency and reliability are essential for future wireless communications systems. MIMO (multi-input multi-output diversity technique is a band width efficient system achieving high data transmission which eventually establishing a high capacity communication system. Without needing to increase the transmitted power or the channel bandwidth, gain in capacity can be considerably improved by varying the number of antennas on both sides. Correlated and uncorrelated channels MIMO system was considered in this paper for different number of antennas and different SNR over Rayleigh fading channel. At the transmitter both CSI(channel state information technique and Water filling power allocation principle was also considered in this paper
Qualitative and quantitative features of Rayleigh-Taylor mixing dynamics
Ramaprabhu, Praveen; Karkhanis, Varad; Lawrie, Andrew; Bhowmick, Aklant; Abarzhi, Snezhana; RTI Collaboration
2015-11-01
We consider dynamics of Rayleigh-Taylor (RT) flow in a large aspect ratio three-dimensional domain with square symmetry in the plane for fluids with contrasting densities. In order to quantify the interface evolution from a small amplitude single-mode initial perturbation to advanced stage of RT mixing, we apply numerical simulations using the MOBILE code, theoretical analyses, including group theory and momentum model, as well as parameters describing the interplay between acceleration and turbulence. We find: In RT flow, the fluid motion is intense near the interface and is negligible far from the interface. At late times the growth rates of RT bubbles and spikes may increase without a corresponding increase of length-scales in the direction normal to acceleration. The parameters describing the interplay between acceleration and turbulence in RT mixing are shown to scale well with the flow Reynolds number and Froude number.
Rayleigh reflections and nonlinear acoustics of solids
Breazeale, M. A.
1980-10-01
Schlierken studies of ultrasonic waves, and nonlinear acoustics of solids are addressed. A goniometer for use in a Schlieren system for visualization of ultrasonic waves in liquids is described. The goniometer is used to obtain Schlieren photographs of leaky Rayleigh waves excited on an Al2O3 layer on a stainless steel reflector immersed in water, showing that the Rayleigh wave velocity in this case is less than that of either a water Al203 layer or a water stainless steel layer. Also investigated are: (1) nonlinearity parameters and third order elastic constants of copper between 300 and 3 K; (2) measurement of nonlinearity parameters in small solid samples by the harmonic generation technique; (3) relationship between solid nonlinearity parameters and thermodynamic Gruneisen parameters; and (4) quantum mechanical theory of nonlinear interaction of ultrasonic waves.
Modulational instability arising from collective Rayleigh scattering.
Robb, G R M; McNeil, B W J
2003-02-01
It is shown that under certain conditions a collection of dielectric Rayleigh particles suspended in a viscous medium and enclosed in a bidirectional ring cavity pumped by a strong laser field can produce a new modulational instability transverse to the wave-propagation direction. The source of the instability is collective Rayleigh scattering i.e., the spontaneous formation of periodic longitudinal particle-density modulations and a backscattered optical field. Using a linear stability analysis a dispersion relation is derived which determines the region of parameter space in which modulational instability of the backscattered field and the particle distribution occurs. In the linear regime the pump is modulationally stable. A numerical analysis is carried out to observe the dynamics of the interaction in the nonlinear regime. In the nonlinear regime the pump field also becomes modulationally unstable and strong pump depletion occurs.
ALE simulation of Rayleigh-Taylor instability
Anbarlooei, H.R. [Univ. of Science and Technology, Dept. of Mechanical Engineering, Tehran (Iran, Islamic Republic of); Mazaheri, K. [Univ. of Tarbiyat Modares, Dept. of Mechanical Engineering, Tehran, (Iran, Islamic Republic of)]. E-mail: Kiumars@modares.ac.ir; Bidabadi, M. [Univ. of Science and Technology, Dept. of Mechanical Engineering, Tehran (Iran, Islamic Republic of)
2004-07-01
This paper investigates the use of an Arbitrary Lagrangian-Eulerian (ALE) technique for the simulation of a single mode Rayleigh-Taylor instability. A compatible Lagrangian algorithm is used on a simply connected quadrilateral grid in Lagrangian Phase. This algorithm includes subzonal pressures, which are used to control spurious grid motion, and an edge centered artificial viscosity. We use Reference Jacobians optimization based rezone algorithm in the rezoning phase of ALE method. Also a second order sign preserving method is used for remapping. To force monotonocity in remapping phase a Repair algorithm is used. Finally, for remapping of nodal variables we used a second order transformer to transfer these data to cell centers. It is shown that the usage of these algorithms for an ALE method can improve the simulation of a single mode Rayleigh-Taylor Instability. (author)
High-Frequency Rayleigh-Wave Method
Jianghai Xia; Richard D Millerg; Xu Yixian; Luo Yinhe; Chen Chao; Liu Jiangping; Julian Ivanov; Chong Zeng
2009-01-01
High-frequency (≥2 Hz) Rayleigh-wave data acquired with a multichannei recording sys-tem have been utilized to determine shear (S)-wave velocities in near-surface geophysics since the early 1980s. This overview article discusses the main research results of high-frequency surface-wave tech-niques achieved by research groups at the Kansas Geological Survey and China University of Geosciences in the last 15 years. The multichannel analysis of surface wave (MASW) method is a nou-iuvasive acoustic approach to estimate near-surface S-wave velocity. The differences between MASW results and direct borehole measurements are approximately 15% or less and random. Studies show that simultaneous inversion with higher modes and the fundamental mode can increase model resolution and an investigation depth. The other important seismic property, quality factor (Q), can also be estimated with the MASW method by inverting attenuation coefficients of Rayleigh waves. An inverted model (S-wave velocity or Q) obtained using a damped least-squares method can be assessed by an optimal damping vector in a vicinity of the inverted model determined by an objective function, which is the trace of a weighted sum of model-resolution and model-covariance matrices. Current developments include modeling high-frequency Rayleigh-waves in near-surface media, which builds a foundation for shallow seismic or Rayleigh-wave inversion in the time-offset domain; imaging dispersive energy with high resolution in the frequency-velocity domain and possibly with data in an arbitrary acquisition geometry, which opens a door for 3D surface-wave techniques; and successfully separating surface-wave modes, which provides a valuable tool to perform S-wave velocity profiling with high-horizontal resolution.
Transient growth in Rayleigh-Bénard-Poiseuille/Couette convection
John Soundar Jerome, J.; Chomaz, Jean-Marc; Huerre, Patrick
2012-04-01
An investigation of the effect of a destabilizing cross-stream temperature gradient on the transient growth phenomenon of plane Poiseuille flow and plane Couette flow is presented. Only the streamwise-uniform and nearly streamwise-uniform disturbances are highly influenced by the Rayleigh number Ra and Prandtl number Pr. The maximum optimal transient growth Gmax of streamwise-uniform disturbances increases slowly with increasing Ra and decreasing Pr. For all Ra and Pr, at moderately large Reynolds numbers Re, the supremum of Gmax is always attained for streamwise-uniform perturbations (or nearly streamwise-uniform perturbations, in the case of plane Couette flow) which produce large streamwise streaks and Rayleigh-Bénard convection rolls (RB). The optimal growth curves retain the same large-Reynolds-number scaling as in pure shear flow. A 3D vector model of the governing equations demonstrates that the short-time behavior is governed by the classical lift-up mechanism and that the influence of Ra on this mechanism is secondary and negligible. The optimal input for the largest long-time response is given by the adjoint of the dominant eigenmode with respect to the energy scalar product: the RB eigenmode without its streamwise velocity component. These short-time and long-time responses depict, to leading order, the optimal transient growth G(t). At moderately large Ra (or small Pr at a fixed Ra), the dominant adjoint mode is a good approximation to the optimal initial condition for all time. Over a general class of norms that can be considered as growth functions, the results remain qualitatively similar, for example, the dominant adjoint eigenmode still approximates the maximum optimal response.
Grooms, Ian
2014-01-01
The non-hydrostatic, quasigeostrophic approximation for rapidly rotating Rayleigh-B\\'enard convection admits a class of exact `single mode' solutions. These solutions correspond to steady laminar convection with a separable structure consisting of a horizontal planform characterized by a single wavenumber multiplied by a vertical amplitude profile, with the latter given as the solution of a nonlinear boundary value problem. The heat transport associated with these solutions is studied in the regime of strong thermal forcing (large reduced Rayleigh number $\\widetilde{Ra}$). It is shown that the Nusselt number $Nu$, a nondimensional measure of the efficiency of heat transport by convection, for this class of solutions is bounded below by $Nu\\gtrsim \\widetilde{Ra}^{3/2}$, independent of the Prandtl number, in the limit of large reduced Rayleigh number. Matching upper bounds include only logarithmic corrections, showing the accuracy of the estimate. Numerical solutions of the nonlinear boundary value problem for ...
Complexation of Nitrous Oxide by Frustrated Lewis Pairs
Otten, Edwin; Neu, Rebecca C.; Stephan, Douglas W.
2009-01-01
Frustrated Lewis pairs comprised of a basic yet sterically encumbered phosphine with boron Lewis acids bind nitrous oxide to give intact PNNOB linkages. The synthesis, structure, and bonding of these species are described.
Dynamics of large-scale quantities in Rayleigh-B\\'enard convection
Pandey, Ambrish; Chatterjee, Anando G; Verma, Mahendra K
2016-01-01
In this paper we estimate the relative strengths of various terms of the Rayleigh-B\\'enard equations. Based on these estimates and scaling analysis, we derive a general formula for the large-scale velocity, $U$, or the P\\'eclet number that is applicable for arbitrary Rayleigh number $\\mathrm{Ra}$ and Prandtl number $\\mathrm{Pr}$. Our formula fits reasonably well with the earlier simulation and experimental results. Our analysis also shows that the wall-bounded convection has enhanced viscous force compared to free turbulence. We also demonstrate how correlations deviate the Nusselt number scaling from the theoretical prediction of $\\mathrm{Ra}^{1/2}$ to the experimentally observed scaling of nearly $\\mathrm{Ra}^{0.3}$.
Teaching Beginning Chemistry Students Simple Lewis Dot Structures
Nassiff, Peter; Czerwinski, Wendy A.
2015-01-01
Students beginning their initial study of chemistry often have a difficult time mastering simple Lewis dot structures. Textbooks show students how to manipulate Lewis structures by moving valence electron dots around the chemical structure so each atom has an octet or duet. However, an easier method of teaching Lewis structures for simple…
Lawrence, Elliot J; Clark, Ewan R; Curless, Liam D; Courtney, James M; Blagg, Robin J; Ingleson, Michael J; Wildgoose, Gregory G
2016-04-21
Whilst hydrogen is a potentially clean fuel for energy storage and utilisation technologies, its conversion to electricity comes at a high energetic cost. This demands the use of rare and expensive precious metal electrocatalysts. Electrochemical-frustrated Lewis pairs offer a metal-free, CO tolerant pathway to the electrocatalysis of hydrogen oxidation. They function by combining the hydrogen-activating ability of frustrated Lewis pairs (FLPs) with electrochemical oxidation of the resultant hydride. Here we present an electrochemical-FLP approach that utilises two different Lewis acids - a carbon-based N-methylacridinium cation that possesses excellent electrochemical attributes, and a borane that exhibits fast hydrogen cleavage kinetics and functions as a "hydride shuttle". This synergistic interaction provides a system that is electrocatalytic with respect to the carbon-based Lewis acid, decreases the required potential for hydrogen oxidation by 1 V, and can be recycled multiple times.
Lewis Mumford and the Ecology of Technics.
Strate, Lance; Lum, Casey Man Kong
2000-01-01
Examines Lewis Mumford's scholarship and his contribution to the emergence of media ecology as both an intellectual tradition and a theoretical perspective on the study of technology, media, and culture. Focuses on Mumford's epochal historiography of technology, the techno-organicism in his thinking about technology and human development, and his…
In situ Characterization of Nanoparticles Using Rayleigh Scattering
Biswajit Santra; Shneider, Mikhail N; Roberto Car
2017-01-01
We report a theoretical analysis showing that Rayleigh scattering could be used to monitor the growth of nanoparticles under arc discharge conditions. We compute the Rayleigh scattering cross sections of the nanoparticles by combining light scattering theory for gas-particle mixtures with calculations of the dynamic electronic polarizability of the nanoparticles. We find that the resolution of the Rayleigh scattering probe is adequate to detect nanoparticles as small as C60 at the expected co...
Brooks, David J
2009-01-01
Although Parkinson's disease with later dementia (PDD) and dementia with Lewy bodies (DLB) are pathologically characterized by the presence of intraneuronal Lewy inclusion bodies, amyloid deposition is also associated to varying degrees with both these disorders. Fibrillar amyloid load can now be quantitated in vivo with positron emission tomography (PET) using imaging biomarkers. Here the reported findings of 11C-PIB PET studies concerning the amyloid load associated with PD and its influence on dementia are reviewed. It is concluded that the presence of amyloid acts to accelerate the dementia process in Lewy body disorders, though has little influence on its nature. Anti-amyloid strategies could be a relevant approach for slowing dementia in a number of DLB and PDD cases.
Transitions in turbulent rotating Rayleigh-B\\'enard convection
Schmitz, S
2010-01-01
Numerical simulations of rotating Rayleigh-B\\'enard convection are presented for both no slip and free slip boundaries. The goal is to find a criterion distinguishing convective flows dominated by the Coriolis force from those nearly unaffected by rotation. If one uses heat transport as an indicator of which regime the flow is in, one finds that the transition between the flow regimes always occurs at the same value of a certain combination of Reynolds, Prandtl and Ekman numbers for both boundary conditions. If on the other hand one uses the helicity of the velocity field to identify flows nearly independent of rotation, one finds the transition at a different location in parameter space.
Outage Probability for Multi-Cell Processing under Rayleigh Fading
Garcia, Virgile; Lebedev, Nikolai
2010-01-01
Multi-cell processing, also called Coordinated Multiple Point (CoMP), is a very promising distributed multi-antennas technique that uses neighbour cell's antennas. This is expected to be part of next generation cellular networks standards such as LTE-A. Small cell networks in dense urban environment are mainly limited by interferences and CoMP can strongly take advantage of this fact to improve cell-edge users' throughput. This paper provides an analytical derivation of the capacity outage probability for CoMP experiencing fast Rayleigh fading. Only the average received power (slow varying fading) has to be known, and perfect Channel State Information (CSI) is not required. An optimisation of the successfully received data-rate is then derived with respect to the number of cooperating stations and the outage probability, illustrated by numerical examples.
Rotating non-Boussinesq Rayleigh-Benard convection
Moroz, Vadim Vladimir
This thesis makes quantitative predictions about the formation and stability of hexagonal and roll patterns in convecting system unbounded in horizontal direction. Starting from the Navier-Stokes, heat and continuity equations, the convection problem is then reduced to normal form equations using equivariant bifurcation theory. The relative stabilities of patterns lying on a hexagonal lattice in Fourier space are then determined using appropriate amplitude equations, with coefficients obtained via asymptotic expansion of the governing partial differential equations, with the conducting state being the base state, and the control parameter and the non-Boussinesq effects being small. The software package Mathematica was used to calculate amplitude coefficients of the appropriate coupled Ginzburg-Landau equations for the rigid-rigid and free-free case. A Galerkin code (initial version of which was written by W. Pesch et al.) is used to determine pattern stability further from onset and for strongly non-Boussinesq fluids. Specific predictions about the stability of hexagon and roll patterns for realistic experimental conditions are made. The dependence of the stability of the convective patterns on the Rayleigh number, planform wavenumber and the rotation rate is studied. Long- and shortwave instabilities, both steady and oscillatory, are identified. For small Prandtl numbers oscillatory sideband instabilities are found already very close to onset. A resonant mode interaction in hexagonal patterns arising in non-Boussinesq Rayleigh-Benard convection is studied using symmetry group methods. The lowest-order coupling terms for interacting patterns are identified. A bifurcation analysis of the resulting system of equations shows that the bifurcation is transcritical. Stability properties of resulting patterns are discussed. It is found that for some fluid properties the traditional hexagon convection solution does not exist. Analytical results are supported by numerical
Camacho, Jorge F.; Rodríguez, Rosalío F.
2017-02-01
The fluctuating hydrodynamic treatment developed in the previous article for a nematic liquid crystal under the influence of a thermal gradient α and a uniform gravity field g, is used to calculate its Rayleigh light scattering spectrum. We find that the dissipative thermal gradient force enhances the Rayleigh-line intensity which varies as k -4 with the fluctuations of the wave number k. The Rayleigh line consists of three central Lorentzians, two of which are determined by the visco-heat modes coupling the entropy and director fluctuations, which is a pure non-equilibrium effect. The third Lorentzian is due only to director fluctuations. We find that the former peaks contain the Rayleigh wings owing to the orientational fluctuations of the aniosotropic molecules. It is also shown that the obtained spectrum reduces to the known equilibrium spectrum of a nematic and to that of a simple fluid. For the particular case in which the decay rates are diffusive, we calculate and plot the amplitudes of non-equilibrium fluctuations of the dynamic structure factor as a function of | α|2/ k 4, and also, the intermediate function in the equilibrium and non-equilibrium states.
Imaging Rayleigh wave attenuation with USArray
Bao, Xueyang; Dalton, Colleen A.; Jin, Ge; Gaherty, James B.; Shen, Yang
2016-07-01
The EarthScope USArray provides an opportunity to obtain detailed images of the continental upper mantle at an unprecedented scale. The majority of mantle models derived from USArray data to date contain spatial variations in seismic-wave speed; however, in many cases these data sets do not by themselves allow a non-unique interpretation. Joint interpretation of seismic attenuation and velocity models can improve upon the interpretations based only on velocity and provide important constraints on the temperature, composition, melt content, and volatile content of the mantle. The surface wave amplitudes that constrain upper-mantle attenuation are sensitive to factors in addition to attenuation, including the earthquake source excitation, focusing and defocusing by elastic structure, and local site amplification. Because of the difficulty of isolating attenuation from these other factors, little is known about the attenuation structure of the North American upper mantle. In this study, Rayleigh wave traveltime and amplitude in the period range 25-100 s are measured using an interstation cross-correlation technique, which takes advantage of waveform similarity at nearby stations. Several estimates of Rayleigh wave attenuation and site amplification are generated at each period, using different approaches to separate the effects of attenuation and local site amplification on amplitude. It is assumed that focusing and defocusing effects can be described by the Laplacian of the traveltime field. All approaches identify the same large-scale patterns in attenuation, including areas where the attenuation values are likely contaminated by unmodelled focusing and defocusing effects. Regionally averaged attenuation maps are constructed after removal of the contaminated attenuation values, and the variations in intrinsic shear attenuation that are suggested by these Rayleigh wave attenuation maps are explored.
Leaky Rayleigh wave investigation on mortar samples.
Neuenschwander, J; Schmidt, Th; Lüthi, Th; Romer, M
2006-12-01
Aggressive mineralized ground water may harm the concrete cover of tunnels and other underground constructions. Within a current research project mortar samples are used to study the effects of sulfate interaction in accelerated laboratory experiments. A nondestructive test method based on ultrasonic surface waves was developed to investigate the topmost layer of mortar samples. A pitch and catch arrangement is introduced for the generation and reception of leaky Rayleigh waves in an immersion technique allowing the measurement of their propagation velocity. The technique has been successfully verified for the reference materials aluminium, copper, and stainless steel. First measurements performed on mortar specimens demonstrate the applicability of this new diagnostic tool.
Global study of Rayleigh-Duffing oscillators
Chen, Hebai; Zou, Lan
2016-04-01
In this paper we investigate the global dynamics of Rayleigh-Duffing oscillators with global parameters, including equilibria at both finity and infinity, existences and coexistence of limit cycles and homoclinic loops. In fact, this oscillator will occur Hopf bifurcations, homoclinic bifurcations and double limit cycle bifurcations. Moreover, we find that the homoclinic bifurcation of this oscillator is special which is a gluing bifurcation. The global bifurcation diagram and all phase portrait are given, and numerical simulations are shown to verify our analysis finally.
Decoherence due to elastic rayleigh scattering
Uys, H
2010-11-01
Full Text Available in this manuscript now enables an accurate calculation of Rayleigh decoherence for these low-field trapped ion as well as other coherent-control experiments. We thank W.M. Itano, J. P. Britton, D. Hanneke, and M. J. Holland for useful suggestions.M. J. B.... acknowledges support from Georgia Tech and IARPA. D.M. is supported by NSF. This work was supported by the DARPA OLE program and by IARPA. This manuscript is the contribution of NIST and is not subject to U.S. copyright. *huys@csir.co.za †john...
Compressible, inviscid Rayleigh-Taylor instability
Guo, Yan
2009-01-01
We consider the Rayleigh-Taylor problem for two compressible, immiscible, inviscid, barotropic fluids evolving with a free interface in the presence of a uniform gravitational field. After constructing Rayleigh-Taylor steady-state solutions with a denser fluid lying above the free interface with the second fluid, we turn to an analysis of the equations obtained from linearizing around such a steady state. By a natural variational approach, we construct normal mode solutions that grow exponentially in time with rate like $e^{t \\sqrt{\\abs{\\xi}}}$, where $\\xi$ is the spatial frequency of the normal mode. A Fourier synthesis of these normal mode solutions allows us to construct solutions that grow arbitrarily quickly in the Sobolev space $H^k$, which leads to an ill-posedness result for the linearized problem. Using these pathological solutions, we then demonstrate ill-posedness for the original non-linear problem in an appropriate sense. More precisely, we use a contradiction argument to show that the non-linear...
Short Rayleigh length free electron lasers
W. B. Colson
2006-03-01
Full Text Available Conventional free electron laser (FEL oscillators minimize the optical mode volume around the electron beam in the undulator by making the resonator Rayleigh length about one third to one half of the undulator length. This maximizes gain and beam-mode coupling. In compact configurations of high-power infrared FELs or moderate power UV FELs, the resulting optical intensity can damage the resonator mirrors. To increase the spot size and thereby reduce the optical intensity at the mirrors below the damage threshold, a shorter Rayleigh length can be used, but the FEL interaction is significantly altered. We model this interaction using a coordinate system that expands with the rapidly diffracting optical mode from the ends of the undulator to the mirrors. Simulations show that the interaction of the strongly focused optical mode with a narrow electron beam inside the undulator distorts the optical wave front so it is no longer in the fundamental Gaussian mode. The simulations are used to study how mode distortion affects the single-pass gain in weak fields, and the steady-state extraction in strong fields.
Ermakov–Lewis invariants and Reid systems
Mancas, Stefan C., E-mail: stefan.mancas@erau.edu [Department of Mathematics, Embry-Riddle Aeronautical University, Daytona Beach, FL 32114-3900 (United States); Rosu, Haret C., E-mail: hcr@ipicyt.edu.mx [IPICyT, Instituto Potosino de Investigacion Cientifica y Tecnologica, Camino a la presa San José 2055, Col. Lomas 4a Sección, 78216 San Luis Potosí, S.L.P. (Mexico)
2014-06-13
Reid's mth-order generalized Ermakov systems of nonlinear coupling constant α are equivalent to an integrable Emden–Fowler equation. The standard Ermakov–Lewis invariant is discussed from this perspective, and a closed formula for the invariant is obtained for the higher-order Reid systems (m≥3). We also discuss the parametric solutions of these systems of equations through the integration of the Emden–Fowler equation and present an example of a dynamical system for which the invariant is equivalent to the total energy. - Highlights: • Reid systems of order m are connected to Emden–Fowler equations. • General expressions for the Ermakov–Lewis invariants both for m=2 and m≥3 are obtained. • Parametric solutions of the Emden–Fowler equations related to Reid systems are obtained.
Rendezvous, un juego de Lewis Carroll
José Manuel Sánchez Muñoz
2011-10-01
Full Text Available Todos en mayor o menor medida asociamos el nombre de Lewis Carrolla la literatura, sobre todo a la de temática infantil, con títulos a sus espaldas como Alicia en el País de las Maravillas, Alicia a través del espejo, o La Caza del Snark. Pero además de literato, Lewis Carrol fue un hombre con bastantes inquietudes en torno a la matemática, la lógica y el pensamiento ﬁlosóﬁco. Pero no todo el mundo es conocedor de su faceta como creativo en el campo de los juegos. Rendezvous es una de sus más sorprendentes invenciones,un juego de inteligencia para todos los públicos, cuyas directrices hacen de él un entretenimiento bastante original.
Rendezvous, un juego de Lewis Carroll
José Manuel Sánchez Muñoz
2011-01-01
Todos en mayor o menor medida asociamos el nombre de Lewis Carrolla la literatura, sobre todo a la de temática infantil, con títulos a sus espaldas como Alicia en el País de las Maravillas, Alicia a través del espejo, o La Caza del Snark. Pero además de literato, Lewis Carrol fue un hombre con bastantes inquietudes en torno a la matemática, la lógica y el pensamiento ﬁlosóﬁco. Pero no todo el mundo es conocedor de su faceta como creativo en el campo de los juegos. Rendezvous es una de sus más...
Sub-Rayleigh limit imaging via intensity correlation measurements
姚旭日; 李龙珍; 刘雪峰; 俞文凯; 翟光杰
2015-01-01
We demonstrate sub-Rayleigh limit imaging of an object via intensity correlation measurements. The image com-pletely unaffected by the disturbance of diffraction-limit is achieved under the condition that the imaging system has an appropriate field of view. The resolution of this sub-Rayleigh limit imaging system is only tied to the lateral resolution of the illumination light.
Shearing box simulations in the Rayleigh unstable regime
Nauman, Farrukh; Blackman, Eric G.
2015-01-01
We study the stability properties of Rayleigh unstable flows both in the purely hydrodynamic and magnetohydrodynamic (MHD) regimes for two different values of the shear $q=2.1, 4.2$ ($q = - d\\ln\\Omega / d\\ln r$) and compare it with the Keplerian case $q=1.5$. The Rayleigh stability criterion states...
Estimating Rayleigh wave particle motion from three-component array analysis of ambient vibrations
Poggi, Valerio; Fäh, Donat
2010-01-01
Several methods have been proposed in the past years to extract the Rayleigh wave ellipticity from horizontal-to-vertical spectral ratios of single station ambient noise recordings. The disadvantage of this set of techniques is the difficulty in clearly identifying and separating the contribution of higher modes. In most cases, only the fundamental mode of ellipticity can be identified. Moreover, it is generally difficult to correct for the energy of SH and Love waves present in the horizontal components of the ambient vibration wavefield. We introduce a new methodology to retrieve Rayleigh wave ellipticity using high-resolution frequency-wavenumber array analysis. The technique is applied to the three components of motion and is based on the assumption that an amplitude maximum in the f-k cross-spectrum must represent the true power amplitude of the corresponding signal. In the case of Rayleigh waves, therefore, the ratio between maxima obtained from the horizontal (radial-polarized) and vertical components of motion will also represent the frequency-dependent ellipticity function. Consequently, if we can identify the Rayleigh dispersion curves of several modes on the f-k plane, then the corresponding modal ellipticity patterns can also be separated and extracted. To test the approach, synthetic and real data sets were processed. In all tested cases, a reliable estimation of segments of the fundamental mode ellipticity was obtained. The identification of higher modes is possible in most cases. The quality of results depends on the selected array geometry and the signal-to-noise ratio, with a major improvement achieved by increasing the number of receivers employed during the survey. An experiment conducted in the town of Visp (Switzerland) allowed the retrieval of portions of ellipticity curves up to the second Rayleigh higher mode, using two concentric circular array configurations of 14 and 11 receivers each.
Linking Rayleigh-Rice theory with near linear shift invariance in light scattering phenomena
Stover, John C.; Schroeder, Sven; Staats, Chris; Lopushenko, Vladimir; Church, Eugene
2016-09-01
Understanding topographic scatter has been the subject of many publications. For optically smooth surfaces that scatter only from roughness (and not from contamination, films or bulk defects) the Rayleigh-Rice relationship resulting from a rigorous electromagnetic treatment has been successfully used for over three decades and experimentally proven at wavelengths ranging from the X-Ray to the far infrared (even to radar waves). The "holy grail" of roughness-induced scatter would be a relationship that is not limited to just optically smooth surfaces, but could be used for any surface where the material optical constants and the surface power spectral density function (PSD) are known. Just input these quantities and calculate the BRDF associated with any source incident angle, wavelength and polarization. This is an extremely challenging problem, but that has not stopped a number of attempts. An intuitive requirement on such general relationships is that they must reduce to the simple Rayleigh-Rice formula for sufficiently smooth surfaces. Unfortunately that does not always happen. Because most optically smooth surfaces also scatter from non-topographic features, doubt creeps in about the accuracy of Rayleigh-Rice. This paper investigates these issues and explains some of the confusion generated in recent years. The authors believe there are measurement issues, scatter source issues and rough surface derivation issues, but that Rayleigh- Rice is accurate as formulated and should not be "corrected." Moreover, it will be shown that the empirically observed near shift invariance of surface scatter phenomena is a direct consequence of the Rayleigh-Rice theory.
The Critical Reception of Lewis Nordan
Bjerre, Thomas Ærvold
2010-01-01
The essay covers the critical reception of Mississippi-writer Lewis Nordan from his debut in 1983 to the boost in scholarly attention in the new millennium. The essay covers newspaper reviews but pays particular attention to the many academic essays that have placed Nordan as a writer in the sout...... in the southern literary tradition and have highlighted themes such as magical realism, the grotesque, race relations, music, and gender....
Two-Stage Indicators to Assess Learning Curves for Minimally Invasive Ivor Lewis Esophagectomy.
Wang, Qi; Wu, Zixiang; Chen, Gang; Zhang, Sai; Shen, Gang; Wu, Ming
2016-10-05
Background Minimally invasive esophagectomy (MIE) Ivor Lewis has been increasingly performed over the last two decades. To guide the implementation of this technically demanding procedure, a comprehensive assessment of MIE-Ivor Lewis learning curves should include both the general competence to accomplish the procedure and the ability to generate oncological benefits. These objectives are believed to be associated with different phases of the learning curve. Methods A retrospective review of the first 109 patients who underwent MIE-Ivor Lewis by a single qualified surgeon was conducted. Relevant variables were collected and assessed by regression analysis to identify suitable indicators for patient stratification and learning curve assessment. Thereafter, the differential analysis was performed among groups to validate the learning curve model. Results Two variables, intrathoracic gastroesophageal anastomosis time and bilateral recurrent laryngeal nerve (RLN) lymphadenectomy number, which plateaued, respectively, after the 26th and 88th cases, were selected as meaningful indicators to identify different competence levels. Therefore, 109 patients were chronologically subcategorized into three groups (the first 26 MIEs as the early group, the next 62 cases as the middle group, and 21 most recent cases as the late group). Perioperative data were compared between groups with positive results to indicate a three-phase model for a learning curve for MIE-Ivor Lewis. Conclusions An MIE-Ivor Lewis learning curve should include three discrete phases that indicate, successively, unskilled operation (general competence to accomplish, less proficiency), surgical proficiency, and oncological efficacy. Intrathoracic anastomosis time and bilateral RLN lymphadenectomy were identified as suitable indicators delineate the different stages of an MIE-Ivor Lewis learning curve.
Thermal boundary layer profiles in turbulent Rayleigh-B\\'enard convection in a cylindrical sample
Stevens, Richard J A M; Grossmann, Siegfried; Verzicco, Roberto; Xia, Ke-Qing; Lohse, Detlef
2011-01-01
We numerically investigate the structures of the near-plate temperature profiles close to the bottom and top plates of turbulent Rayleigh-B\\'{e}nard flow in a cylindrical sample at Rayleigh numbers $Ra=10^8$ to $Ra=2\\times10^{12}$ and Prandtl numbers Pr=6.4 and Pr=0.7 thus extending previous results for quasi-2-dimensional systems to 3D systems for the first time. The results show that the instantaneous temperature profiles scaled by the dynamical frame method [Q. Zhou and K.-Q. Xia, Phys. Rev. Lett. 104, 104301 (2010)] agree well with the classical Prandtl-Blasius laminar boundary layer (BL) profiles, especially for low Ra and high Pr. The agreement is slightly less, but still good, for lower Pr, where the thermal BL is more exposed to the bulk fluctuations due to the thinner kinetic BL, and higher Ra, where more plumes are passing the measurement location.
Conjugate Heat Transfer in Rayleigh-Bénard Convection in a Square Enclosure
Habibis Saleh
2014-01-01
Full Text Available Conjugate natural convection-conduction heat transfer in a square enclosure with a finite wall thickness is studied numerically in the present paper. The governing parameters considered are the Rayleigh number 5×103≤Ra≤106, the wall-to-fluid thermal conductivity ratio 0.5≤Kr≤10, and the ratio of wall thickness to its height 0.2≤D≤0.4. The staggered grid arrangement together with MAC method was employed to solve the governing equations. It is found that the fluid flow and the heat transfer can be controlled by the thickness of the bottom wall, the thermal conductivity ratio, and the Rayleigh number.
Conjugate heat transfer in Rayleigh-Bénard convection in a square enclosure.
Saleh, Habibis; Hashim, Ishak
2014-01-01
Conjugate natural convection-conduction heat transfer in a square enclosure with a finite wall thickness is studied numerically in the present paper. The governing parameters considered are the Rayleigh number (5 × 10(3) ≤ Ra ≤ 10(6)), the wall-to-fluid thermal conductivity ratio (0.5 ≤ Kr ≤ 10), and the ratio of wall thickness to its height (0.2 ≤ D ≤ 0.4). The staggered grid arrangement together with MAC method was employed to solve the governing equations. It is found that the fluid flow and the heat transfer can be controlled by the thickness of the bottom wall, the thermal conductivity ratio, and the Rayleigh number.
Distributed chaos and Rayleigh-Benard turbulence at very high Ra
Bershadskii, A
2016-01-01
It is shown, by the means of distributed chaos approach and using the experimental data, that at very large Rayleigh number $Ra > 10^{14}$ and Prandtl number $Pr \\sim 1$ the Rayleigh-B\\'{e}nard turbulence can undergo a transition related to spontaneous breaking of the fundamental Lagrangian relabeling symmetry. Due to the Noether's theorem helicity plays central role in this process. After the transition the temperature spectrum has a stretched exponential form $E (k) \\propto \\exp(-k/k_{\\beta})^{\\beta}$ with $\\beta =2/5$ both at the cell midplain and at the near-wall (low boundary) regions. There is a similarity between this phenomenon and the effects of polymer additives.
Wheeler, A. A.; Mcfadden, G. B.; Murray, B. T.; Coriell, S. R.
1991-01-01
The effect of vertical, sinusoidal, time-dependent gravitational acceleration on the onset of solutal convection during directional solidification is analyzed in the limit of large modulation frequency. When the unmodulated state is unstable, the modulation amplitude required to stabilize the system is determined by the method of averaging. When the unmodulated state is stable, resonant modes of instability occur at large modulation amplitude. These are analyzed using matched asymptotic expansions to elucidate the boundary-layer structure for both the Rayleigh-Benard and directional solidification configurations. Based on these analyses, a thorough examination of the dependence of the stability criteria on the unmodulated Rayleigh number, Schmidt number, and distribution coefficient, is carried out.
Dual Lewis Acid/Lewis Base Catalyzed Acylcyanation of Aldehydes: A Mechanistic Study.
Laurell Nash, Anna; Hertzberg, Robin; Wen, Ye-Qian; Dahlgren, Björn; Brinck, Tore; Moberg, Christina
2016-03-07
A mechanistic investigation, which included a Hammett correlation analysis, evaluation of the effect of variation of catalyst composition, and low-temperature NMR spectroscopy studies, of the Lewis acid-Lewis base catalyzed addition of acetyl cyanide to prochiral aldehydes provides support for a reaction route that involves Lewis base activation of the acyl cyanide with formation of a potent acylating agent and cyanide ion. The cyanide ion adds to the carbonyl group of the Lewis acid activated aldehyde. O-Acylation by the acylated Lewis base to form the final cyanohydrin ester occurs prior to decomplexation from titanium. For less reactive aldehydes, the addition of cyanide is the rate-determining step, whereas, for more reactive, electron-deficient aldehydes, cyanide addition is rapid and reversible and is followed by rate-limiting acylation. The resting state of the catalyst lies outside the catalytic cycle and is believed to be a monomeric titanium complex with two alcoholate ligands, which only slowly converts into the product. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Lewis' Educational and Research Collaborative Internship Program
Heyward, Ann; Gott, Susan (Technical Monitor)
2004-01-01
The Lewis Educational and Research Collaborative Internship Program (LERCIP) is a collaborative undertaking by the Office of Educational Programs at NASA Glenn Research Center at Lewis Field (formerly NASA Lewis Research Center) and the Ohio Aerospace Institute. This program provides 10-week internships in addition to summer and winter extensions if funding is available and/or is requested by mentor (no less than 1 week no more than 4 weeks) for undergraduate/graduate students and secondary school teachers. Students who meet the travel reimbursement criteria receive up to $500 for travel expenses. Approximately 178 interns are selected to participate in this program each year and begin arriving the fourth week in May. The internships provide students with introductory professional experiences to complement their academic programs. The interns are given assignments on research and development projects under the personal guidance of NASA professional staff members. Each intern is assigned a NASA mentor who facilitates a research assignment. In addition to the research assignment, the summer program includes a strong educational component that enhances the professional stature of the participants. The educational activities include a research symposium and a variety of workshops, and lectures. An important aspect of the program is that it includes students with diverse social, cultural and economic backgrounds. The purpose of this report is to document the program accomplishments for 2004.
Rayleigh scattering: blue sky thinking for future CMB observations
Lewis, Antony
2013-01-01
Rayleigh scattering from neutral hydrogen during and shortly after recombination causes the CMB anisotropies to be significantly frequency dependent at high frequencies. This may be detectable with Planck, and would be a strong signal at in any future space-based CMB missions. The later peak of the Rayleigh visibility compared to Thomson scattering gives an increased large-scale CMB polarization signal that is a greater than 4% effect for observed frequencies greater than 500GHz. There is a similar magnitude suppression on small scales from additional damping. Due to strong correlation between the Rayleigh and primary signal, measurement of the Rayleigh component is limited by noise and foregrounds, not cosmic variance of the primary CMB, and should observable over a wide range of angular scales at frequencies between roughly 200GHz and 800GHz. I give new numerical calculations of the temperature and polarization power spectra, and show that future CMB missions could measure the temperature Rayleigh cross-spe...
Dynamics and Selection of Giant Spirals in Rayleigh-Benard Convection
Plapp, B B; Bodenschatz, E; Pesch, W; Plapp, Brendan B.; Egolf, David A.; Bodenschatz, Eberhard; Pesch, Werner
1998-01-01
For Rayleigh-Benard convection of a fluid with Prandtl number \\sigma \\approx 1, we report experimental and theoretical results on a pattern selection mechanism for cell-filling, giant, rotating spirals. We show that the pattern selection in a certain limit can be explained quantitatively by a phase-diffusion mechanism. This mechanism for pattern selection is very different from that for spirals in excitable media.
Contrasting Frustrated Lewis Pair Reactivity with Selenium- and Boron-Based Lewis Acids.
Wilkins, Lewis C; Günther, Benjamin A R; Walther, Melanie; Lawson, James R; Wirth, Thomas; Melen, Rebecca L
2016-09-05
The activation of π-bonds in diynyl esters has been investigated by using soft and hard Lewis acids. In the case of the soft selenium Lewis acid PhSeCl, sequential activation of the alkyne bonds leads initially to an isocoumarin (1 equiv PhSeCl) and then to a tetracyclic conjugated structure with the isocoumarin subunit fused to a benzoselenopyran (3 equiv PhSeCl). Conversely, the reaction with the hard Lewis acidic borane B(C6 F5 )3 initiates a cascade reaction to yield a complex π-conjugated system containing phthalide and indene subunits. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Stability analysis of Rayleigh-Bénard convection in a cylinder with internal heat generation
Wang, Bo-Fu; Zhou, Lin; Wan, Zhen-Hua; Ma, Dong-Jun; Sun, De-Jun
2016-07-01
The flow instabilities of Rayleigh-Bénard convection in a cylinder with effect of uniform internal heat source are investigated numerically. The instabilities of the static state and of axisymmetric flows are investigated by linear stability analysis. The convection threshold depends on the strength of internal heat source q and the aspect ratio of the cylinder Γ . The stability of axisymmetric flows is strongly affected by these two parameters, as well as the Prandtl number Pr. Depending on the value of q , three regimes are identified: weak internal heating, moderate internal heating, and strong internal heating regime. In a weak internal heating regime, the instability characteristics are similar to Rayleigh-Bénard convection. In a moderate internal heating regime, intense interaction of buoyancy instability and hydrodynamic instability result in complex instability curves. When q is large enough, the internal heating effect overwhelms the boundary heating effect. Specifically, the influence of Pr on instability is studied at a moderate internal heat strength q =6.4 . An extremely multivalued stability curve is observed. At most five critical Rayleigh numbers can be determined for the axisymmetry-breaking instability at a certain Prandtl number. An axisymmetric unsteady instability mode is observed as well. By nonlinear simulation, the oscillatory flow patterns are obtained, and the axisymmetry-breaking bifurcation of the unsteady toroidal flow is studied.
Stability analysis of Rayleigh-Bénard convection in a cylinder with internal heat generation.
Wang, Bo-Fu; Zhou, Lin; Wan, Zhen-Hua; Ma, Dong-Jun; Sun, De-Jun
2016-07-01
The flow instabilities of Rayleigh-Bénard convection in a cylinder with effect of uniform internal heat source are investigated numerically. The instabilities of the static state and of axisymmetric flows are investigated by linear stability analysis. The convection threshold depends on the strength of internal heat source q and the aspect ratio of the cylinder Γ. The stability of axisymmetric flows is strongly affected by these two parameters, as well as the Prandtl number Pr. Depending on the value of q, three regimes are identified: weak internal heating, moderate internal heating, and strong internal heating regime. In a weak internal heating regime, the instability characteristics are similar to Rayleigh-Bénard convection. In a moderate internal heating regime, intense interaction of buoyancy instability and hydrodynamic instability result in complex instability curves. When q is large enough, the internal heating effect overwhelms the boundary heating effect. Specifically, the influence of Pr on instability is studied at a moderate internal heat strength q=6.4. An extremely multivalued stability curve is observed. At most five critical Rayleigh numbers can be determined for the axisymmetry-breaking instability at a certain Prandtl number. An axisymmetric unsteady instability mode is observed as well. By nonlinear simulation, the oscillatory flow patterns are obtained, and the axisymmetry-breaking bifurcation of the unsteady toroidal flow is studied.
Rayleigh-type parametric chemical oscillation.
Ghosh, Shyamolina; Ray, Deb Shankar
2015-09-28
We consider a nonlinear chemical dynamical system of two phase space variables in a stable steady state. When the system is driven by a time-dependent sinusoidal forcing of a suitable scaling parameter at a frequency twice the output frequency and the strength of perturbation exceeds a threshold, the system undergoes sustained Rayleigh-type periodic oscillation, wellknown for parametric oscillation in pipe organs and distinct from the usual forced quasiperiodic oscillation of a damped nonlinear system where the system is oscillatory even in absence of any external forcing. Our theoretical analysis of the parametric chemical oscillation is corroborated by full numerical simulation of two well known models of chemical dynamics, chlorite-iodine-malonic acid and iodine-clock reactions.
Technical Report: Rayleigh Scattering Combustion Diagnostic
Adams, Wyatt [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Hecht, Ethan [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
2015-07-29
A laser Rayleigh scattering (LRS) temperature diagnostic was developed over 8 weeks with the goal of studying oxy-combustion of pulverized coal char in high temperature reaction environments with high concentrations of carbon dioxide. Algorithms were developed to analyze data collected from the optical diagnostic system and convert the information to temperature measurements. When completed, the diagnostic will allow for the kinetic gasification rates of the oxy-combustion reaction to be obtained, which was previously not possible since the high concentrations of high temperature CO_{2} consumed thermocouples that were used to measure flame temperatures inside the flow reactor where the combustion and gasification reactions occur. These kinetic rates are important for studying oxycombustion processes suitable for application as sustainable energy solutions.
Rayleigh-type parametric chemical oscillation
Ghosh, Shyamolina; Ray, Deb Shankar, E-mail: pcdsr@iacs.res.in [Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India)
2015-09-28
We consider a nonlinear chemical dynamical system of two phase space variables in a stable steady state. When the system is driven by a time-dependent sinusoidal forcing of a suitable scaling parameter at a frequency twice the output frequency and the strength of perturbation exceeds a threshold, the system undergoes sustained Rayleigh-type periodic oscillation, wellknown for parametric oscillation in pipe organs and distinct from the usual forced quasiperiodic oscillation of a damped nonlinear system where the system is oscillatory even in absence of any external forcing. Our theoretical analysis of the parametric chemical oscillation is corroborated by full numerical simulation of two well known models of chemical dynamics, chlorite-iodine-malonic acid and iodine-clock reactions.
Phosphorus Lewis acids: emerging reactivity and applications in catalysis.
Bayne, J M; Stephan, D W
2016-02-21
Part of the renaissance in main group chemistry has been a result of the focus on reactivity. This has led to the development of applications in stoichiometric reactivity and catalysis. In this tutorial review, we focus attention on the role of phosphorus-based Lewis acids in such advances. While early literature recognizes the role of P(iii) and P(v) electrophiles in coordination chemistry, it has generally been more recent studies that have focused on applications of this Lewis acidity. Applications of these novel P-based Lewis acids in stoichiometric reactivity, Lewis acid catalysis and frustrated Lewis pair (FLP) reactivity are reviewed. These advances demonstrate that P-based Lewis acids are a powerful tool for further developments in metal-free catalysis.
Jian Guangde; Huang Lin; Qiu Xiaoming
2005-01-01
The assembling stabilizing effect of the finite Larmor radius (FLR) and the sheared axial flow (SAF) on the Rayleigh-Taylor instability in Z-pinch implosions is studied by means of the incompressible finite Larmor radius magnetohydrodynamic (MHD) equations. The finite Larmor radius effects are introduced in the momentum equation with the sheared axial flow through an anisotropic ion stress tensor. In this paper a linear mode equation is derived that is valid for arbitrary kL, where k is the wave number and L is the plasma shell thickness. Numerical solutions are presented. The results indicate that the short-wavelength modes of the RayleighTaylor instability are easily stabilized by the individual effect of the finite Larmor radius or the sheared axial flow. The assembling effects of the finite Larmor radius and sheared axial flow can heavily mitigate the Rayleigh-Taylor instability, and the unstable region can be compressed considerably.
Visual signs and symptoms of dementia with Lewy bodies
Armstrong, Richard A.
2012-01-01
Dementia with Lewy bodies ('Lewy body dementia' or 'diffuse Lewy body disease') (DLB) is the second most common form of dementia to affect elderly people, after Alzheimer's disease. A combination of the clinical symptoms of Alzheimer's disease and Parkinson's disease is present in DLB and the disorder is classified as a 'parkinsonian syndrome', a group of diseases which also includes Parkinson's disease, progressive supranuclear palsy, corticobasal degeneration and multiple system atrophy. Ch...
QUADRO: A SUPERVISED DIMENSION REDUCTION METHOD VIA RAYLEIGH QUOTIENT OPTIMIZATION.
Fan, Jianqing; Ke, Zheng Tracy; Liu, Han; Xia, Lucy
We propose a novel Rayleigh quotient based sparse quadratic dimension reduction method-named QUADRO (Quadratic Dimension Reduction via Rayleigh Optimization)-for analyzing high-dimensional data. Unlike in the linear setting where Rayleigh quotient optimization coincides with classification, these two problems are very different under nonlinear settings. In this paper, we clarify this difference and show that Rayleigh quotient optimization may be of independent scientific interests. One major challenge of Rayleigh quotient optimization is that the variance of quadratic statistics involves all fourth cross-moments of predictors, which are infeasible to compute for high-dimensional applications and may accumulate too many stochastic errors. This issue is resolved by considering a family of elliptical models. Moreover, for heavy-tail distributions, robust estimates of mean vectors and covariance matrices are employed to guarantee uniform convergence in estimating non-polynomially many parameters, even though only the fourth moments are assumed. Methodologically, QUADRO is based on elliptical models which allow us to formulate the Rayleigh quotient maximization as a convex optimization problem. Computationally, we propose an efficient linearized augmented Lagrangian method to solve the constrained optimization problem. Theoretically, we provide explicit rates of convergence in terms of Rayleigh quotient under both Gaussian and general elliptical models. Thorough numerical results on both synthetic and real datasets are also provided to back up our theoretical results.
Spiral defect chaos in a model of Rayleigh-Benard convection
Xi, H; Viñals, J; Xi, Hao-wen; Vinals., Jorge
1993-01-01
A numerical solution of a generalized Swift-Hohenberg equation in two dimensions reveals the existence of a spatio-temporal chaotic state comprised of a large number of rotating spirals. This state is observed for a reduced Rayleigh number $\\epsilon=0.25$. The power spectrum of the state is isotropic, and the spatial correlation function decays exponentially, with an estimated decay length $\\xi \\approx 2.5 \\lambda_{c}$, where $\\lambda_{c}$ is the critical wavelength near the onset of convection. Our study suggests that this spiral defect state occurs for low Prandtl numbers and large aspect ratios.
I. C. Ramos
2015-10-01
Full Text Available We present the adaptation to non-free boundary conditions of a pseudospectral method based on the (complex Fourier transform. The method is applied to the numerical integration of the Oberbeck-Boussinesq equations in a Rayleigh-Bénard cell with no-slip boundary conditions for velocity and Dirichlet boundary conditions for temperature. We show the first results of a 2D numerical simulation of dry air convection at high Rayleigh number (. These results are the basis for the later study, by the same method, of wet convection in a solar still. Received: 20 Novembre 2014, Accepted: 15 September 2015; Edited by: C. A. Condat, G. J. Sibona; DOI:http://dx.doi.org/10.4279/PIP.070015 Cite as: I C Ramos, C B Briozzo, Papers in Physics 7, 070015 (2015
Study on Electrohydrodynamic Rayleigh-Taylor Instability with Heat and Mass Transfer
Mukesh Kumar Awasthi
2014-01-01
Full Text Available The linear analysis of Rayleigh-Taylor instability of the interface between two viscous and dielectric fluids in the presence of a tangential electric field has been carried out when there is heat and mass transfer across the interface. In our earlier work, the viscous potential flow analysis of Rayleigh-Taylor instability in presence of tangential electric field was studied. Here, we use another irrotational theory in which the discontinuities in the irrotational tangential velocity and shear stress are eliminated in the global energy balance. Stability criterion is given by critical value of applied electric field as well as critical wave number. Various graphs have been drawn to show the effect of various physical parameters such as electric field, heat transfer coefficient, and vapour fraction on the stability of the system. It has been observed that heat transfer and electric field both have stabilizing effect on the stability of the system.
Thermal evidence for Taylor columns in turbulent rotating Rayleigh-Bénard convection.
King, Eric M; Aurnou, Jonathan M
2012-01-01
We investigate flow structures in rotating Rayleigh-Bénard convection experiments in water using thermal measurements. We focus on correlations between time series measurements of temperature in the top and bottom boundaries. Distinct anticorrelations are observed for rapidly rotating convection, which are argued to attest to heat transport by convective Taylor columns. In support of this argument, these quasigeostrophic flow structures are directly observed in flow visualizations, and their thermal signature is qualitatively reproduced by a simple model of heat transport by columnar flow. Weakly rotating and nonrotating convection produces positively correlated temperature changes across the layer, indicative of heat transport by large-scale circulation. We separate these regimes using a transition parameter that depends on the Rayleigh and Ekman numbers, RaE3/2.
Numerical simulation of 3-dimensional Rayleigh-Benard system by particle method
Watanabe, Tadashi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
1997-05-01
As one of representative non-equilibrium thermal fluid system, there is a fluid system maintained at lower and higher temperatures at upper and lower faces, respectively, and Rayleigh-Benard (RB) system. On temperature difference between both faces smaller than a critical value, flow into the system is not developed to realize a thermal conductive state, while on that larger than a critical value, macroscopic convection vortex forms to realize a conventional thermal conductive state. A transition process from thermal conduction to convection is well-known for RB unstability and also the convection state is done for RB convection. In this paper, a transition process from thermal conduction to convection was simulated systematically by changing temperature difference at both faces using DSMC method known for one of statistical methods, to investigate the critical Rayleigh number in response to temperature difference at beginning point of the convection, variations and correlative function at proximity of the critical Rayleigh number, pattern formation of the convection and so forth. (G.K.)
Power, John H T; Shannon, John M; Blumbergs, Peter C; Gai, Wei-Ping
2002-09-01
Nonselenium glutathione peroxidase (NSGP) is a new member of the antioxidant family. Using antibodies to recombinant NSGP we have examined the distribution of this enzyme in normal, Parkinson's disease (PD), and dementia with Lewy body disease (DLB) brains. We have also co-localized this enzyme with alpha-synuclein as a marker for Lewy bodies. In normal brains there was a very low level of NSGP staining in astrocytes. In PD and DLB there were increases in the number and staining intensity of NSGP-positive astrocytes in both gray and white matter. Cell counting of NSGP cells in PD and DLB frontal and cingulated cortices indicated there was 10 to 15 times more positive cells in gray matter and three times more positive cells in white matter than in control cortices. Some neurons were positive for both alpha-synuclein and NSGP in PD and DLB, and double staining indicated that NSGP neurons contained either diffuse cytoplasmic alpha-synuclein deposits or Lewy bodies. In concentric Lewy bodies, alpha-synuclein staining was peripheral whereas NSGP staining was confined to the central core. Immunoprecipitation indicated there was direct interaction between alpha-synuclein and NSGP. These results suggest oxidative stress conditions exist in PD and DLB and that certain cells have responded by up-regulating this novel antioxidant enzyme.
Heat Transport by Coherent Rayleigh-B\\'enard Convection
Waleffe, Fabian; Smith, Leslie M
2015-01-01
Steady but generally unstable solutions of the 2D Boussinesq equations are obtained for no-slip boundary conditions and Prandtl number 7. The primary solution that bifurcates from the conduction state at Rayleigh number $Ra \\approx 1708$ has been calculated up to $Ra\\approx 5. 10^6$ and shows heat flux $Nu \\sim 0.143\\, Ra^{0.28}$ with a delicate spiral structure in the temperature field. Another solution that maximizes $Nu$ over the horizontal wavenumber has been calculated up to $Ra=10^9$ and its heat flux scales as $Nu \\sim 0.115\\, Ra^{0.31}$ for $10^7 < Ra \\le 10^9$, quite similar to 3D turbulent data. The latter is a simple yet multi-scale coherent solution whose horizontal wavenumber scales as $0.133 \\, Ra^{0.217}$ in that range. That optimum solution is unstable to larger scale perturbations and in particular to mean shear flows, yet it appears to be relevant as a backbone for turbulent solutions, possibly setting the scale, strength and spacing of elemental plumes.
DSMC Simulations of the Rayleigh-Taylor Instability in Gases
Gallis, Michael; Koehler, Timothy; Torczynski, John; Plimpton, Steven
2015-11-01
The Direct Simulation Monte Carlo (DSMC) method of molecular gas dynamics is applied to simulate the Rayleigh-Taylor instability (RTI) in atmospheric-pressure monatomic gases (e.g., argon and helium). The computational domain is a 1 mm × 4 mm rectangle divided into 50-nm square cells. Each cell is populated with 1000 computational molecules, and time steps of 0.1 ns are used. Simulations are performed to quantify the growth of a single-mode perturbation on the interface as a function of the Atwood number and the gravitational acceleration. The DSMC results qualitatively reproduce all observed features of the RTI and are in reasonable quantitative agreement with existing theoretical and empirical models. Consistent with previous work in this field, the DSMC simulations indicate that the growth of the RTI follows a universal behavior. For cases with multiple-mode perturbations, the numbers of bubble-spike pairs that eventually appear are found to be in agreement with theoretical results for the most unstable wavelength. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.
On a Misconception Involving Point Collocation and the Rayleigh Hypothesis
Christiansen, Søren; Kleinman, Ralph E.
1996-01-01
It is shown that the Rayleigh hypothesis does notgovern convergence of the simple point collocationapproach to the numerical solutions of scatteringby a sinusoidal grating. A recently developed numerical technique, interval arithmetic, is employed to perform some decisive numerical experiments wh...
Rayleigh scattering in the atmospheres of hot stars
Fišák, Jakub; Munzar, Dominik; Kubát, Jiří
2016-01-01
Rayleigh scattering is a result of an interaction of photons with bound electrons. Rayleigh scattering is mostly neglected in calculations of hot star model atmospheres because most of the hydrogen atoms are ionized and the heavier elements have a lower abundance than hydrogen. In atmospheres of some chemically peculiar stars, helium overabundant regions containing singly ionized helium are present and Rayleigh scattering can be a significant opacity source. We evaluate the contribution of Rayleigh scattering by neutral hydrogen and singly ionized helium in the atmospheres of hot stars with solar composition and in the atmospheres of helium overabundant stars. We computed several series of model atmospheres using the TLUSTY code and emergent fluxes using the SYNSPEC code. These models describe atmospheres of main sequence B-type stars with different helium abundance. We used an existing grid of models for atmospheres with solar chemical composition and we calculated an additional grid for helium-rich stars wi...
Generalized Rayleigh and Jacobi Processes and Exceptional Orthogonal Polynomials
Chou, C.-I.; Ho, C.-L.
2013-09-01
We present four types of infinitely many exactly solvable Fokker-Planck equations, which are related to the newly discovered exceptional orthogonal polynomials. They represent the deformed versions of the Rayleigh process and the Jacobi process.
Rayleigh-Lagrange formalism for classical dissipative systems.
Virga, Epifanio G
2015-01-01
It is often believed that the Rayleigh-Lagrange formalism for classical dissipative systems is unable to encompass forces described by nonlinear functions of the velocities. Here we show that this is indeed a misconception.
Carnap and Lewis on the External World
Ivan Ferreira da Cunha
2014-08-01
Full Text Available This paper compares the claims about our knowledge of the external world presented by Rudolf Carnap, in the book known as the Aufbau, to those of Clarence Irving Lewis, in Mind and the World-Order. This comparison is made in terms of the opposition to Kantian epistemology that both books establish; the Aufbau is regarded as the peak of the logicist tradition and Mind and the World-Order is taken in continuity with pragmatism. It is found that both books present knowledge of the external world as a consequence of a structural organization of human experience. However, there is an important point of divergence: the concept of verification each author adopts is different, such a concept was even a matter of discussion between Lewis and the Vienna Circle. This paper shows this disagreement but also shows how Carnap changed his point of view in the decade after the Aufbau was published, towards a standpoint which is much closer to Lewis’s ideas. In that process, nevertheless, Carnap changed his focus and did not deal with the problem of the external world anymore. This paper also seeks to draw attention to some features of the relation between Carnap and the pragmatist tradition which have only recently started to attract interest.
Heshmat, Mojgan; Privalov, Timofei
2017-07-06
By using transition-state (TS) calculations, we examined how Lewis acid (LA) complexation activates carbonyl compounds in the context of hydrogenation of carbonyl compounds by H2 in Lewis basic (ethereal) solvents containing borane LAs of the type (C6 F5 )3 B. According to our calculations, LA complexation does not activate a ketone sufficiently enough for the direct addition of H2 to the O=C unsaturated bond; but, calculations indicate a possibly facile heterolytic cleavage of H2 at the activated and thus sufficiently Lewis acidic carbonyl carbon atom with the assistance of the Lewis basic solvent (i.e., 1,4-dioxane or THF). For the solvent-assisted H2 splitting at the carbonyl carbon atom of (C6 F5 )3 B adducts with different ketones, a number of TSs are computed and the obtained results are related to insights from experiment. By using the Born-Oppenheimer molecular dynamics with the DFT for electronic structure calculations, the evolution of the (C6 F5 )3 B-alkoxide ionic intermediate and the proton transfer to the alkoxide oxygen atom were investigated. The results indicate a plausible hydrogenation mechanism with a LA, that is, (C6 F5 )3 B, as a catalyst, namely, 1) the step of H2 cleavage that involves a Lewis basic solvent molecule plus the carbonyl carbon atom of thermodynamically stable and experimentally identifiable (C6 F5 )3 B-ketone adducts in which (C6 F5 )3 B is the "Lewis acid promoter", 2) the transfer of the solvent-bound proton to the oxygen atom of the (C6 F5 )3 B-alkoxide intermediate giving the (C6 F5 )3 B-alcohol adduct, and 3) the SN 2-style displacement of the alcohol by a ketone or a Lewis basic solvent molecule. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Bayes Estimation for Inverse Rayleigh Model under Different Loss Functions
Guobing Fan
2015-04-01
Full Text Available The inverse Rayleigh distribution plays an important role in life test and reliability domain. The aim of this article is study the Bayes estimation of parameter of inverse Rayleigh distribution. Bayes estimators are obtained under squared error loss, LINEX loss and entropy loss functions on the basis of quasi-prior distribution. Comparisons in terms of risks with the estimators of parameter under three loss functions are also studied. Finally, a numerical example is used to illustrate the results.
Stability of Rayleigh-Taylor Vortices in Dusty Plasma
MA Jun; CHEN Yin-Hua; GAN Bao-Xia; WANG Fei-Hu; WANG Dong
2006-01-01
@@ The evolution of Rayleigh-Taylor mode in dusty plasma with vortex-flow is investigated. Based on fluid theory and Bayly's method, we derive the coupling equations describing the Rayleigh-Taylor mode in the core of vortex,and research the evolution characteristics of the perturbation amplitude with time numerically. It is shown that the eccentric of vortex and the content of dust have considerable effects on the amplitude evolutions.
Otugen, M. Volkan
1997-01-01
Non-intrusive techniques for the dynamic measurement of gas flow properties such as density, temperature and velocity, are needed in the research leading to the development of new generation high-speed aircraft. Accurate velocity, temperature and density data obtained in ground testing and in-flight measurements can help understand the flow physics leading to transition and turbulence in supersonic, high-altitude flight. Such non-intrusive measurement techniques can also be used to study combustion processes of hydrocarbon fuels in aircraft engines. Reliable, time and space resolved temperature measurements in various combustor configurations can lead to a better understanding of high temperature chemical reaction dynamics thus leading to improved modeling and better prediction of such flows. In view of this, a research program was initiated at Polytechnic University's Aerodynamics Laboratory with support from NASA Lewis Research Center through grants NAG3-1301 and NAG3-1690. The overall objective of this program has been to develop laser-based, non-contact, space- and time-resolved temperature and velocity measurement techniques. In the initial phase of the program a ND:YAG laser-based dual-line Rayleigh scattering technique was developed and tested for the accurate measurement of gas temperature in the presence of background laser glare. Effort was next directed towards the development of a filtered, spectrally-resolved Rayleigh/Mie scattering technique with the objective of developing an interferometric method for time-frozen velocity measurements in high-speed flows utilizing the uv line of an ND:YAG laser and an appropriate molecular absorption filter. This effort included both a search for an appropriate filter material for the 266 nm laser line and the development and testing of several image processing techniques for the fast processing of Fabry-Perot images for velocity and temperature information. Finally, work was also carried out for the development of
Interview with Smithsonian NASM Spacesuit Curator Dr. Cathleen Lewis
Lewis, Cathleen; Wright, Rebecca
2012-01-01
Dr. Cathleen Lewis was interviewed by Rebecca Wright during the presentation of an "Interview with Smithsonian NASM Spacesuit Curator Dr. Cathleen Lewis" on May 14, 2012. Topics included the care, size, and history of the spacesuit collection at the Smithsonian and the recent move to the state-of-the-art permanent storage facility at the Udvar-Hazy facility in Virginia.
Impairments of Speech Fluency in Lewy Body Spectrum Disorder
Ash, Sharon; McMillan, Corey; Gross, Rachel G.; Cook, Philip; Gunawardena, Delani; Morgan, Brianna; Boller, Ashley; Siderowf, Andrew; Grossman, Murray
2012-01-01
Few studies have examined connected speech in demented and non-demented patients with Parkinson's disease (PD). We assessed the speech production of 35 patients with Lewy body spectrum disorder (LBSD), including non-demented PD patients, patients with PD dementia (PDD), and patients with dementia with Lewy bodies (DLB), in a semi-structured…
Dalgarno-Lewis perturbation theory for scattering states
Amore, Paolo [Facultad de Ciencias, Universidad de Colima, Bernal Diaz del Castillo 340, Colima, Colima Mexico (Mexico)]. E-mail: paolo@ucol.mx; Fernandez, Francisco M. [INIFTA (Conicet, UNLP), Division Quimica Teorica, Diag. 113 y 64 S/N, Sucursal 4, Casilla de Correo 16, 1900 La Plata (Argentina)]. E-mail: fernande@quimica.unlp.edu.ar
2007-07-23
We apply the method of Dalgarno and Lewis to scattering states and discuss the choice of the unperturbed model in order to have a convergent perturbation series for the phase shift. We show that a recently proposed approach is a particular case of the method of Dalgarno and Lewis.
Rayleigh scattering in the atmospheres of hot stars
Fišák, J.; Krtička, J.; Munzar, D.; Kubát, J.
2016-05-01
Context. Rayleigh scattering is a result of an interaction of photons with bound electrons. Rayleigh scattering is mostly neglected in calculations of hot star model atmospheres because most of the hydrogen atoms are ionized and the heavier elements have a lower abundance than hydrogen. In atmospheres of some chemically peculiar stars, helium overabundant regions containing singly ionized helium are present and Rayleigh scattering can be a significant opacity source. Aims: We evaluate the contribution of Rayleigh scattering by neutral hydrogen and singly ionized helium in the atmospheres of hot stars with solar composition and in the atmospheres of helium overabundant stars. Methods: We computed several series of model atmospheres using the TLUSTY code and emergent fluxes using the SYNSPEC code. These models describe atmospheres of main sequence B-type stars with different helium abundance. We used an existing grid of models for atmospheres with solar chemical composition and we calculated an additional grid for helium-rich stars with N(He)/N(H) = 10. Results: Rayleigh scattering by neutral hydrogen can be neglected in atmospheres of hot stars, while Rayleigh scattering by singly ionized helium can be a non-negligible opacity source in some hot stars, especially in helium-rich stars.
Rayleigh-Taylor instability simulations with CRASH
Chou, C.-C.; Fryxell, B.; Drake, R. P.
2012-03-01
CRASH is a code package developed for the predictive study of radiative shocks. It is based on the BATSRUS MHD code used extensively for space-weather research. We desire to extend the applications of this code to the study of hydrodynamically unstable systems. We report here the results of Rayleigh-Taylor instability (RTI) simulations with CRASH, as a necessary step toward the study of such systems. Our goal, motivated by the previous comparison of simulations and experiment, is to be able to simulate the magnetic RTI with self-generated magnetic fields produced by the Biermann Battery effect. Here we show results for hydrodynamic RTI, comparing the effects of different solvers and numerical parameters. We find that the early-time behavior converges to the analytical result of the linear theory. We observe that the late-time morphology is sensitive to the numerical scheme and limiter beta. At low-resolution limit, the growth of RTI is highly dependent on the setup and resolution, which we attribute to the large numerical viscosity at low resolution.
Kinetic Simulations of Rayleigh-Taylor Instabilities
Sagert, Irina; Colbry, Dirk; Howell, Jim; Staber, Alec; Strother, Terrance
2014-01-01
We report on an ongoing project to develop a large scale Direct Simulation Monte Carlo code. The code is primarily aimed towards applications in astrophysics such as simulations of core-collapse supernovae. It has been tested on shock wave phenomena in the continuum limit and for matter out of equilibrium. In the current work we focus on the study of fluid instabilities. Like shock waves these are routinely used as test-cases for hydrodynamic codes and are discussed to play an important role in the explosion mechanism of core-collapse supernovae. As a first test we study the evolution of a single-mode Rayleigh-Taylor instability at the interface of a light and a heavy fluid in the presence of a gravitational acceleration. To suppress small-wavelength instabilities caused by the irregularity in the separation layer we use a large particle mean free path. The latter leads to the development of a diffusion layer as particles propagate from one fluid into the other. For small amplitudes, when the instability is i...
Optical switching by stimulated thermal Rayleigh scattering
Peterson, Lauren M.
1986-06-01
Preliminary experiments were conducted whose ultimate goal is to develop all-optical control functions useful in an all-optical or optical-electronic hybrid digital computer or for optical interconnects. Stimulated thermal Rayleigh scattering (STRS) based upon generator experiments was pursued for scattering angles of 90 deg and 180 deg (backscattering). A pulsed nitrogen laser pumped dye laser served as the radiation source and the interaction medium was a liquid to which an absorbing dye was added. STRS amplifier experiments were successful and gain was observed and studied parametrically using eosine dye in ethanol. The gain was found to increase (although the gain coefficient decreased) with increasing pump power and the gain was found to be a maximum at an absorption coefficient of about 2.6 per cm. The generator experiments did not lead to stimulated scattering due to the limited output power of the laser and its multi-longitudinal spectral mode content. These studies will be continued along with analytical modeling in order to characterize the interaction and to enable the optimization of the scattering process.
Direct numerical simulations of type Ia supernovae flames II: The Rayleigh-Taylor instability
Bell, J.B.; Day, M.S.; Rendleman, C.A.; Woosley, S.E.; Zingale, M.
2004-01-12
A Type Ia supernova explosion likely begins as a nuclear runaway near the center of a carbon-oxygen white dwarf. The outward propagating flame is unstable to the Landau-Darrieus, Rayleigh-Taylor, and Kelvin-Helmholtz instabilities, which serve to accelerate it to a large fraction of the speed of sound. We investigate the Rayleigh-Taylor unstable flame at the transition from the flamelet regime to the distributed-burning regime, around densities of 10e7 gm/cc, through detailed, fully resolved simulations. A low Mach number, adaptive mesh hydrodynamics code is used to achieve the necessary resolution and long time scales. As the density is varied, we see a fundamental change in the character of the burning--at the low end of the density range the Rayleigh-Taylor instability dominates the burning, whereas at the high end the burning suppresses the instability. In all cases, significant acceleration of the flame is observed, limited only by the size of the domain we are able to study. We discuss the implications of these results on the potential for a deflagration to detonation transition.
Adams, Colin Stuart [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of New Mexico, Albuquerque, NM (United States)
2015-01-15
The Rayleigh-Taylor instability causes mixing in plasmas throughout the universe, from micron-scale plasmas in inertial confinement fusion implosions to parsec-scale supernova remnants. The evolution of this interchange instability in a plasma is influenced by the presence of viscosity and magnetic fields, both of which have the potential to stabilize short-wavelength modes. Very few experimental observations of Rayleigh-Taylor growth in plasmas with stabilizing mechanisms are reported in the literature, and those that are reported are in sub-millimeter scale plasmas that are difficult to diagnose. Experimental observations in well-characterized plasmas are important for validation of computational models used to make design predictions for inertial confinement fusion efforts. This dissertation presents observations of instability growth during the interaction between a high Mach-number, initially un-magnetized plasma jet and a stagnated, magnetized plasma. A multi-frame fast camera captures Rayleigh-Taylor-instability growth while interferometry, spectroscopy, photodiode, and magnetic probe diagnostics are employed to estimate plasma parameters in the vicinity of the collision. As the instability grows, an evolution to longer mode wavelength is observed. Comparisons of experimental data with idealized magnetohydrodynamic simulations including a physical viscosity model suggest that the observed instability evolution is consistent with both magnetic and viscous stabilization. These data provide the opportunity to benchmark computational models used in astrophysics and fusion research.
Saeedi, Khodabakhsh; Bhat, Rama B.; Stiharu, Ion [Concordia University, Montreal (Canada); Leo, Alfin [2Parker Filtration Canada, Laval (Canada)
2012-05-15
The free vibration of a circular plate with multiple perforations is analyzed by using the Rayleigh-Ritz method. Admissible functions are assumed to be separable functions of radial and tangential coordinates. Trigonometric functions are assumed in the circumferential direction. The radial shape functions are the boundary characteristic orthogonal polynomials generated following the Gram-Schmidt recurrence scheme. The assumed functions are used to estimate the kinetic and the potential energies of the plate depending on the number and the position of the perforations. The eigenvalues, representing the dimensionless natural frequencies, are compared with the results obtained using Bessel functions, where the exact solution is available. Moreover, the eigenvectors, which are the unknown coefficients of the Rayleigh-Ritz method, are used to present the mode shapes of the plate. To validate the analytical results of the plates with multiple perforations, experimental investigations are also performed. Two unique case studies that are not addressed in the existing literature are considered. The results of the Rayleigh-Ritz method are found to be in good agreement with those from the experiments. Although the method presented can be employed in the vibration analysis of plates with different boundary conditions and shapes of the perforations, circular perforations that are free on the edges are studied in this paper. The results are presented in terms of dimensionless frequencies and mode shapes.
Adams, Colin Stuart [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of New Mexico, Albuquerque, NM (United States); Univ. of Washington, Seattle, WA (United States)
2015-01-15
The Rayleigh-Taylor instability causes mixing in plasmas throughout the universe, from micron-scale plasmas in inertial confinement fusion implosions to parsec-scale supernova remnants. The evolution of this interchange instability in a plasma is influenced by the presence of viscosity and magnetic fields, both of which have the potential to stabilize short-wavelength modes. Very few experimental observations of Rayleigh-Taylor growth in plasmas with stabilizing mechanisms are reported in the literature, and those that are reported are in sub-millimeter scale plasmas that are difficult to diagnose. Experimental observations in well-characterized plasmas are important for validation of computational models used to make design predictions for inertial confinement fusion efforts. This dissertation presents observations of instability growth during the interaction between a high Mach-number, initially un-magnetized plasma jet and a stagnated, magnetized plasma. A multi-frame fast camera captures Rayleigh-Taylor-instability growth while interferometry, spectroscopy, photodiode, and magnetic probe diagnostics are employed to estimate plasma parameters in the vicinity of the collision. As the instability grows, an evolution to longer mode wavelength is observed. Comparisons of experimental data with idealized magnetohydrodynamic simulations including a physical viscosity model suggest that the observed instability evolution is consistent with both magnetic and viscous stabilization. These data provide the opportunity to benchmark computational models used in astrophysics and fusion research.
LEWIS BINFORD AND HIS MORAL MAJORITY (Lewis Binford y su mayoría moral
Alice Beck Kehoe
2011-06-01
Full Text Available This essay looks at the late Lewis Binford’s career from the standpoint of sociology of science. His thinking and manner reflect his socialization in Virginia Baptist subculture. As convinced of his authority on science as Jerry Falwell was of his authority on Biblical morality, Lewis Binford and his third wife Sally Rosen Binford excited a group of 1960s students to follow Lewis in an outmoded version of science (hypothetico-deductive and in trusting statistics. The “frames of reference” he laboriously constructed are naïve on environmental interpretation and, because he expressed contempt for “political” aspects of archaeology, fail to take into account effects of colonialism. His work is often scientistic, in the “modern” mode that historian Dorothy Ross describes as characteristic of twentieth-century American social sciences. ESPAÑOL: En este ensayo se analiza la etapa final de la carrera de Lewis Binford desde el punto de vista de la sociología de la ciencia. Su pensamiento refleja su socialización en el seno de la subcultura de la Virginia baptista. Tan convencido de su autoridad en la ciencia como Jerry Falwell lo fuera sobre la moralidad bíblica, Lewis Binford y su tercera esposa Sally Rosen Binford animaron a un grupo estudiantes de los sesenta a seguir a Lewis a través de una versión anticuada de la ciencia (hipotético-deductiva y a confiar en la estadística. Los “marcos de referencia” que laboriosamente construyó son ingenuos en la interpretación del medio ambiente y, como expresó el desprecio por los aspectos “políticos” de la arqueología, no tienen en cuenta los efectos del colonialismo. Su trabajo es a menudo cientificista, en el sentido “moderno” que la historiadora Dorothy Ross describe como una característica de las ciencias sociales norteamericanas del siglo XX.
Niharika, Pedireddi; Ramulu, Bokka Venkat; Satyanarayana, Gedu
2014-07-07
Lewis acid (FeCl3) mediated dual bond (C-C and C-O) formation for synthesis of 3,4-dihydrocoumarins is presented. This method has successfully delivered a number of dihydrocoumarins containing dense functionalities on the aromatic ring. Significantly, the present method enabled achieving dihydrocoumarins with tertiary as well as quaternary carbon atoms at the benzylic position. Gratifyingly, the novel spiro-tetracyclic lactones have also been dextrously prepared using this process.
Assessment of DoD Wounded Warrior Matters -- Joint Base Lewis-McChord
2013-05-31
Matters - Joint Base Lewis-McChord Report Documentation Page Form ApprovedOMB No. 0704-0188 Public reporting burden for the collection of...NUMBER OF PAGES 104 19a. NAME OF RESPONSIBLE PERSON a. REPORT unclassified b. ABSTRACT unclassified c. THIS PAGE unclassified Standard Form 298...RECOMMENDATION 0 .. 2.: Commander, Madigan Afmy Medical Centercondt, Jct an analysis to determine o’bstacles to access ahd delays encountered and
Substrate constraint modifies the Rayleigh spectrum of vibrating sessile drops.
Chang, Chun-Ti; Bostwick, Joshua B; Steen, Paul H; Daniel, Susan
2013-08-01
In this work, we study the resonance behavior of mechanically oscillated, sessile water drops. By mechanically oscillating sessile drops vertically and within prescribed ranges of frequencies and amplitudes, a rich collection of resonance modes are observed and their dynamics subsequently investigated. We first present our method of identifying each mode uniquely, through association with spherical harmonics and according to their geometric patterns. Next, we compare our measured resonance frequencies of drops to theoretical predictions using both the classical theory of Lord Rayleigh and Lamb for free, oscillating drops, and a prediction by Bostwick and Steen that explicitly considers the effect of the solid substrate on drop dynamics. Finally, we report observations and analysis of drop mode mixing, or the simultaneous coexistence of multiple mode shapes within the resonating sessile drop driven by one sinusoidal signal of a single frequency. The dynamic response of a deformable liquid drop constrained by the substrate it is in contact with is of interest in a number of applications, such as drop atomization and ink jet printing, switchable electronically controlled capillary adhesion, optical microlens devices, as well as digital microfluidic applications where control of droplet motion is induced by means of a harmonically driven substrate.
Tuning transitions in rotating Rayleigh-Bénard convection
Joshi, Pranav; Kunnen, Rudie; Clercx, Herman
2015-11-01
Turbulent rotating Rayleigh-Bénard convection, depending on the system parameters, exhibits multiple flow states and transitions between them. The present experimental study aims to control the transitions between the flow regimes, and hence the system heat transfer characteristics, by introducing particles in the flow. We inject near-neutrally buoyant silver coated hollow ceramic spheres (~100 micron diameter) and measure the system response, i.e. the Nusselt number, at different particle concentrations and rotation rates. Both for rotating and non-rotating cases, most of the particles settle on the top and bottom plates in a few hours following injection. This rapid settling may be a result of ``trapping'' of particles in the laminar boundary layers at the horizontal walls. These particle layers on the heat-transfer surfaces reduce their effective conductivity, and consequently, lower the heat transfer rate. We calculate the effective system parameters by estimating, and accounting for, the temperature drop across the particle layers. Preliminary analysis suggests that the thermal resistance of the particle layers may affect the flow structure and delay the transition to the ``geostrophic'' regime. Financial support from Foundation for Fundamental Research on Matter.
Substrate constraint modifies the Rayleigh spectrum of vibrating sessile drops
Chang, Chun-Ti; Bostwick, Joshua B.; Steen, Paul H.; Daniel, Susan
2013-08-01
In this work, we study the resonance behavior of mechanically oscillated, sessile water drops. By mechanically oscillating sessile drops vertically and within prescribed ranges of frequencies and amplitudes, a rich collection of resonance modes are observed and their dynamics subsequently investigated. We first present our method of identifying each mode uniquely, through association with spherical harmonics and according to their geometric patterns. Next, we compare our measured resonance frequencies of drops to theoretical predictions using both the classical theory of Lord Rayleigh and Lamb for free, oscillating drops, and a prediction by Bostwick and Steen that explicitly considers the effect of the solid substrate on drop dynamics. Finally, we report observations and analysis of drop mode mixing, or the simultaneous coexistence of multiple mode shapes within the resonating sessile drop driven by one sinusoidal signal of a single frequency. The dynamic response of a deformable liquid drop constrained by the substrate it is in contact with is of interest in a number of applications, such as drop atomization and ink jet printing, switchable electronically controlled capillary adhesion, optical microlens devices, as well as digital microfluidic applications where control of droplet motion is induced by means of a harmonically driven substrate.
Nandukumar, Yada
2015-01-01
We investigate oscillatory instability and routes to chaos in Rayleigh-B\\'enard convection of electrically conducting fluids in presence of external horizontal magnetic field. Three dimensional direct numerical simulations (DNS) of the governing equations are performed for the investigation. DNS shows that oscillatory instability is inhibited by the magnetic field. The supercritical Rayleigh number for the onset of oscillation is found to scale with the Chandrasekhar number $\\mathrm{Q}$ as $\\mathrm{Q}^{\\alpha}$ in DNS with $\\alpha = 1.8$ for low Prandtl numbers ($\\mathrm{Pr}$). Most interestingly, DNS shows $\\mathrm{Q}$ dependent routes to chaos for low Prandtl number fluids like mercury ($\\mathrm{Pr} = 0.025$). For low $\\mathrm{Q}$, period doubling routes are observed, while, quasiperiodic routes are observed for high $\\mathrm{Q}$. The bifurcation structure associated with $\\mathrm{Q}$ dependent routes to chaos is then understood by constructing a low dimensional model from the DNS data. The model also shows...
Mixed insulating and conducting boundary conditions in Rayleigh-Bénard convection
Bakhuis, Dennis; Ostilla Mónico, Rodolfo; van der Poel, Erwin; Verzicco, Roberto; Lohse, Detlef
2015-11-01
We report the results of 3D direct numerical simulations of a rectangular doubly periodic Rayleigh-Bénard system. These results are an extension of earlier 2D work by Ripesi et al. (Journal of Fluid Mechanics 742, 636, 2014). The Rayleigh number is between 107 and 109 and the Prandtl number is set to unity. The bottom plate is homogeneously heated and the cold top plate of this setup has been split into conducting and insulating regions. While keeping both areas equal the pattern has been varied and multiple characteristics like the Nusselt number and bulk temperature have been recorded. When the top plate was divided into one conducting and insulating halves, we see that the Nusselt number is about two thirds of the fully conducting case. However, when we now increase the number of divisions, the Nusselt number slowly approaches that of the fully conducting case. This is a surprising result, as even though only half of the effective area can conduct heat, the same heat transport as a fully conducting cold plate is achieved.
Suzuki, Kosuke; Sugawa, Midori; Kikukawa, Yuji; Kamata, Keigo; Yamaguchi, Kazuya; Mizuno, Noritaka
2012-06-18
Efficient polyoxometalate (POM)-based Lewis acid-base catalysts of the rare-earth-metal-containing POMs (TBA(6)RE-POM, RE = Y(3+), Nd(3+), Eu(3+), Gd(3+), Tb(3+), or Dy(3+)) were designed and synthesized by reactions of TBA(4)H(4)[γ-SiW(10)O(36)] (TBA = tetra-n-butylammonium) with RE(acac)(3) (acac = acetylacetonato). TBA(6)RE-POM consisted of two silicotungstate units pillared by two rare-earth-metal cations. Nucleophilic oxygen-enriched surfaces of negatively charged POMs and the incorporated rare-earth-metal cations could work as Lewis bases and Lewis acids, respectively. Consequently, cyanosilylation of carbonyl compounds with trimethylsilyl cyanide ((TMS)CN) was efficiently promoted in the presence of the rare-earth-metal-containing POMs via the simultaneous activation of coupling partners on the same POM molecules. POMs with larger metal cations showed higher catalytic activities for cyanosilylation because of the higher activation ability of C═O bonds (higher Lewis acidities) and sterically less hindered Lewis acid sites. Among the POM catalysts examined, the neodymium-containing POM showed remarkable catalytic performance for cyanosilylation of various kinds of structurally diverse ketones and aldehydes, giving the corresponding cyanohydrin trimethylsilyl ethers in high yields (13 substrates, 94-99%). In particular, the turnover frequency (714,000 h(-1)) and the turnover number (23,800) for the cyanosilylation of n-hexanal were of the highest level among those of previously reported catalysts.
Stuendl, Anne; Kunadt, Marcel; Kruse, Niels; Bartels, Claudia; Moebius, Wiebke; Danzer, Karin M; Mollenhauer, Brit; Schneider, Anja
2016-02-01
Extracellular α-synuclein has been proposed as a crucial mechanism for induction of pathological aggregate formation in previously healthy cells. In vitro, extracellular α-synuclein is partially associated with exosomal vesicles. Recently, we have provided evidence that exosomal α-synuclein is present in the central nervous system in vivo. We hypothesized that exosomal α-synuclein species from patients with α-synuclein related neurodegeneration serve as carriers for interneuronal disease transmission. We isolated exosomes from cerebrospinal fluid from patients with Parkinson's disease, dementia with Lewy bodies, progressive supranuclear palsy as a non-α-synuclein related disorder that clinically overlaps with Parkinson's disease, and neurological controls. Cerebrospinal fluid exosome numbers, α-synuclein protein content of cerebrospinal fluid exosomes and their potential to induce oligomerization of α-synuclein were analysed. The quantification of cerebrospinal fluid exosomal α-synuclein showed distinct differences between patients with Parkinson's disease and dementia with Lewy bodies. In addition, exosomal α-synuclein levels correlated with the severity of cognitive impairment in cross-sectional samples from patients with dementia with Lewy bodies. Importantly, cerebrospinal fluid exosomes derived from Parkinson's disease and dementia with Lewy bodies induce oligomerization of α-synuclein in a reporter cell line in a dose-dependent manner. Our data suggest that cerebrospinal fluid exosomes from patients with Parkinson's disease and dementia with Lewy bodies contain a pathogenic species of α-synuclein, which could initiate oligomerization of soluble α-synuclein in target cells and confer disease pathology.
The development of Lewis Henry Morgan's evolutionism.
Kuper, A
1985-01-01
Lewis Henry Morgan never used the term evolution in any of his major sociological works. If he may be labeled an evolutionist, the specificity of his views must be taken into account. The main "evolutionist" issue that concerned him was that of the unity or diversity of the human species. This was an urgent political and theological issue in the America of his day, and it impinged also on research on the American Indians. Morgan's first major study was designed to demonstrate the unity of origin of the American aborigines and their "Asian" origins. His methods were derived from the tradition of Indo-European philology. It was virtually as an afterthought that he added a social evolutionary component to what he conceived of as an exercise in philology. Later he came under the direct influence of the English evolutionists, and this was crucial for the conception of Ancient Society.
Dementia with Lewy bodies: current concepts.
Buracchio, Teresa; Arvanitakis, Zoe; Gorbien, Martin
2005-01-01
As life expectancy continues to increase over time, dementia is becoming an increasingly more common problem and a major cause of disability in older persons. It is now more important than ever to identify and manage common causes of dementia given variations in disease course, treatments and the possibility for modification of risk factors. Dementia with Lewy bodies (DLB) is a dementia syndrome characterized by progressive cognitive decline, with fluctuating cognition, recurrent detailed and well-formed hallucinations, and parkinsonism. This article aims to provide an overview of current concepts of DLB, including a description of the key clinical features and neuropathology, neurochemistry, and genetics of DLB, then a discussion of the relationship of DLB with Alzheimer's disease and Parkinson's disease, and, finally, a summary of current management strategies available for this disorder.
Aluminium Diphosphamethanides: Hidden Frustrated Lewis Pairs.
Styra, Steffen; Radius, Michael; Moos, Eric; Bihlmeier, Angela; Breher, Frank
2016-07-04
The synthesis and characterisation of two aluminium diphosphamethanide complexes, [Al(tBu)2 {κ(2) P,P'-Mes*PCHPMes*}] (3) and [Al(C6 F5 )2 {κ(2) P,P'-Mes*PCHPMes*}] (4), and the silylated analogue, Mes*PCHP(SiMe3 )Mes* (5), are reported. The aluminium complexes feature four-membered PCPAl core structures consisting of diphosphaallyl ligands. The silylated phosphine 5 was found to be a valuable precursor for the synthesis of 4 as it cleanly reacts with the diaryl aluminium chloride [(C6 F5 )2 AlCl]2 . The aluminium complex 3 reacts with molecular dihydrogen at room temperature under formation of the acyclic σ(2) λ(3) ,σ(3) λ(3) -diphosphine Mes*PCHP(H)Mes* and the corresponding dialkyl aluminium hydride [tBu2 AlH]3 . Thus, 3 belongs to the family of so-called hidden frustrated Lewis pairs.
NASA Lewis Meshed VSAT Workshop meeting summary
Ivancic, William
1993-11-01
NASA Lewis Research Center's Space Electronics Division (SED) hosted a workshop to address specific topics related to future meshed very small-aperture terminal (VSAT) satellite communications networks. The ideas generated by this workshop will help to identify potential markets and focus technology development within the commercial satellite communications industry and NASA. The workshop resulted in recommendations concerning these principal points of interest: the window of opportunity for a meshed VSAT system; system availability; ground terminal antenna sizes; recommended multifrequency for time division multiple access (TDMA) uplink; a packet switch design concept for narrowband; and fault tolerance design concepts. This report presents a summary of group presentations and discussion associated with the technological, economic, and operational issues of meshed VSAT architectures that utilize processing satellites.
Zhang, Yuetao; Miyake, Garret M; John, Mallory G; Falivene, Laura; Caporaso, Lucia; Cavallo, Luigi; Chen, Eugene Y-X
2012-08-14
Classical and frustrated Lewis pairs (LPs) of the strong Lewis acid (LA) Al(C(6)F(5))(3) with several Lewis base (LB) classes have been found to exhibit exceptional activity in the Lewis pair polymerization (LPP) of conjugated polar alkenes such as methyl methacrylate (MMA) as well as renewable α-methylene-γ-butyrolactone (MBL) and γ-methyl-α-methylene-γ-butyrolactone (γ-MMBL), leading to high molecular weight polymers, often with narrow molecular weight distributions. This study has investigated a large number of LPs, consisting of 11 LAs as well as 10 achiral and 4 chiral LBs, for LPP of 12 monomers of several different types. Although some more common LAs can also be utilized for LPP, Al(C(6)F(5))(3)-based LPs are far more active and effective than other LA-based LPs. On the other hand, several classes of LBs, when paired with Al(C(6)F(5))(3), can render highly active and effective LPP of MMA and γ-MMBL; such LBs include phosphines (e.g., P(t)Bu(3)), chiral chelating diphosphines, N-heterocyclic carbenes (NHCs), and phosphazene superbases (e.g., P(4)-(t)Bu). The P(4)-(t)Bu/Al(C(6)F(5))(3) pair exhibits the highest activity of the LP series, with a remarkably high turn-over frequency of 9.6 × 10(4) h(-1) (0.125 mol% catalyst, 100% MMA conversion in 30 s, M(n) = 2.12 × 10(5) g mol(-1), PDI = 1.34). The polymers produced by LPs at RT are typically atactic (P(γ)MMBL with ∼47% mr) or syndio-rich (PMMA with ∼70-75% rr), but highly syndiotactic PMMA with rr ∼91% can be produced by chiral or achiral LPs at -78 °C. Mechanistic studies have identified and structurally characterized zwitterionic phosphonium and imidazolium enolaluminates as the active species of the current LPP system, which are formed by the reaction of the monomer·Al(C(6)F(5))(3) adduct with P(t)Bu(3) and NHC bases, respectively. Kinetic studies have revealed that the MMA polymerization by the (t)Bu(3)P/Al(C(6)F(5))(3) pair is zero-order in monomer concentration after an initial
Zhang, Yuetao
2012-01-01
Classical and frustrated Lewis pairs (LPs) of the strong Lewis acid (LA) Al(C 6F 5) 3 with several Lewis base (LB) classes have been found to exhibit exceptional activity in the Lewis pair polymerization (LPP) of conjugated polar alkenes such as methyl methacrylate (MMA) as well as renewable α-methylene-γ-butyrolactone (MBL) and γ-methyl- α-methylene-γ-butyrolactone (γ-MMBL), leading to high molecular weight polymers, often with narrow molecular weight distributions. This study has investigated a large number of LPs, consisting of 11 LAs as well as 10 achiral and 4 chiral LBs, for LPP of 12 monomers of several different types. Although some more common LAs can also be utilized for LPP, Al(C 6F 5) 3-based LPs are far more active and effective than other LA-based LPs. On the other hand, several classes of LBs, when paired with Al(C 6F 5) 3, can render highly active and effective LPP of MMA and γ-MMBL; such LBs include phosphines (e.g., P tBu 3), chiral chelating diphosphines, N-heterocyclic carbenes (NHCs), and phosphazene superbases (e.g., P 4- tBu). The P 4- tBu/Al(C 6F 5) 3 pair exhibits the highest activity of the LP series, with a remarkably high turn-over frequency of 9.6 × 10 4 h -1 (0.125 mol% catalyst, 100% MMA conversion in 30 s, M n = 2.12 × 10 5 g mol -1, PDI = 1.34). The polymers produced by LPs at RT are typically atactic (P γMMBL with ∼47% mr) or syndio-rich (PMMA with ∼70-75% rr), but highly syndiotactic PMMA with rr ∼91% can be produced by chiral or achiral LPs at -78 °C. Mechanistic studies have identified and structurally characterized zwitterionic phosphonium and imidazolium enolaluminates as the active species of the current LPP system, which are formed by the reaction of the monomer·Al(C 6F 5) 3 adduct with P tBu 3 and NHC bases, respectively. Kinetic studies have revealed that the MMA polymerization by the tBu 3P/ Al(C 6F 5) 3 pair is zero-order in monomer concentration after an initial induction period, and the polymerization
Li, Zheng; Zhang, Yuwen
2016-01-01
The purposes of this paper are testing an efficiency algorithm based on LBM and using it to analyze two-dimensional natural convection with low Prandtl number. Steady state or oscillatory results are obtained using double multiple-relaxation-time thermal lattice Boltzmann method. The velocity and temperature fields are solved using D2Q9 and D2Q5 models, respectively. With different Rayleigh number, the tested natural convection can either achieve to steady state or oscillatory. With fixed Rayleigh number, lower Prandtl number leads to a weaker convection effect, longer oscillation period and higher oscillation amplitude for the cases reaching oscillatory solutions. At fixed Prandtl number, higher Rayleigh number leads to a more notable convection effect and longer oscillation period. Double multiple-relaxation-time thermal lattice Boltzmann method is applied to simulate the low Prandtl number fluid natural convection. Rayleigh number and Prandtl number effects are also investigated when the natural convection...
Heat transport in the geostrophic regime of rotating Rayleigh-B{\\'e}nard convection
Ecke, Robert E
2013-01-01
We report experimental measurements of heat transport in rotating Rayleigh-B{\\'e}nard convection in a cylindrical convection cell with aspect ratio $\\Gamma = 1/2$. The fluid was helium gas with Prandtl number Pr = 0.7. The range of control parameters was Rayleigh number $4 \\times 10^9 < {\\rm Ra} < 4 \\times 10^{11}$ and Ekman number $2 \\times 10^{-7} < {\\rm Ek} < 3 \\times 10^{-5}$(corresponding to Taylor number $4 \\times 10^9 < {\\rm Ta} < 1 \\times 10^{14}$ and convective Rossby number $0.07 < {\\rm Ro} < 5$). We determine the crossover from weakly rotating turbulent convection to rotation dominated geostrophic convection through experimental measurements of the normalized heat transport Nu. The heat transport for the rotating state in the geostrophic regime, normalized by the zero-rotation heat transport, is consistent with scaling of $({\\rm RaEk}^{-7/4})^\\beta$ with $\\beta \\approx 1$. A phase diagram is presented that encapsulates measurements on the potential geostrophic turbulence reg...
Visual hallucinations in PD and Lewy body dementias: old and new hypotheses.
Onofrj, M; Taylor, J P; Monaco, D; Franciotti, R; Anzellotti, F; Bonanni, L; Onofrj, V; Thomas, A
2013-01-01
Visual Hallucinations (VH) are a common non-motor symptom of Parkinson's Disease (PD) and the Lewy body dementias (LBD) of Parkinson's disease with dementia (PDD) and Dementia with Lewy Bodies (DLB). The origin of VH in PD and LBD is debated: earlier studies considered a number of different possible mechanisms underlying VH including visual disorders, Rapid Eye Movement (REM) Sleep Intrusions, dysfunctions of top down or bottom up visual pathways, and neurotransmitter imbalance. More recently newer hypotheses introduce, among the possible mechanisms of VH, the role of attention networks (ventral and dorsal) and of the Default Mode Network (DMN) a network that is inhibited during attentional tasks and becomes active during rest and self referential imagery. Persistent DMN activity during active tasks with dysfunctional imbalance of dorsal and ventral attentional networks represents a new hypothesis on the mechanism of VH. We review the different methods used to classify VH and discuss reports supporting or challenging the different hypothetical mechanisms of VH.
[Effects of green tea on growth inhibition and immune regulation of Lewis lung cancer in mice].
Zhu, M; Gong, Y; Ge, G
1997-11-01
C57/BL6J mice were inoculated with Lewis lung cancer cells as an experimental model to study the effects of green tea on cancer prevention, inhibition of tumor growth and immune regulation in mice with tumor. Results showed that weight of thymus in C57/BL6J mice and its index declined, proportion of positive CD4 subgroup of T lymphocyte and ratio of CD4+, to CD8+ reduced, baseline chemilumi-nescence decreased in peripheral white blood cells, yeast zymosan stimulated chemiluminescence increased, and number of immunoglobulin M formation cells decreased. It indicated that green tea had obvious inhibition in Lewis lung cancer and protective effects, to various extent, on adverse changes of above indices.
Rayleigh scattering in few-mode optical fibers
Wang, Zhen; Wu, Hao; Hu, Xiaolong; Zhao, Ningbo; Mo, Qi; Li, Guifang
2016-01-01
The extremely low loss of silica fibers has enabled the telecommunication revolution, but single-mode fiber-optic communication systems have been driven to their capacity limits. As a means to overcome this capacity crunch, space-division multiplexing (SDM) using few-mode fibers (FMF) has been proposed and demonstrated. In single-mode optical fibers, Rayleigh scattering serves as the dominant mechanism for optical loss. However, to date, the role of Rayleigh scattering in FMFs remains elusive. Here we establish and experimentally validate a general model for Rayleigh scattering in FMFs. Rayleigh backscattering not only sets the intrinsic loss limit for FMFs but also provides the theoretical foundation for few-mode optical time-domain reflectometry, which can be used to probe perturbation-induced mode-coupling dynamics in FMFs. We also show that forward inter-modal Rayleigh scattering ultimately sets a fundamental limit on inter-modal-crosstalk for FMFs. Therefore, this work not only has implications specifically for SDM systems but also broadly for few-mode fiber optics and its applications in amplifiers, lasers, and sensors in which inter-modal crosstalk imposes a fundamental performance limitation. PMID:27775003
Rayleigh scattering in few-mode optical fibers
Wang, Zhen; Wu, Hao; Hu, Xiaolong; Zhao, Ningbo; Mo, Qi; Li, Guifang
2016-10-01
The extremely low loss of silica fibers has enabled the telecommunication revolution, but single-mode fiber-optic communication systems have been driven to their capacity limits. As a means to overcome this capacity crunch, space-division multiplexing (SDM) using few-mode fibers (FMF) has been proposed and demonstrated. In single-mode optical fibers, Rayleigh scattering serves as the dominant mechanism for optical loss. However, to date, the role of Rayleigh scattering in FMFs remains elusive. Here we establish and experimentally validate a general model for Rayleigh scattering in FMFs. Rayleigh backscattering not only sets the intrinsic loss limit for FMFs but also provides the theoretical foundation for few-mode optical time-domain reflectometry, which can be used to probe perturbation-induced mode-coupling dynamics in FMFs. We also show that forward inter-modal Rayleigh scattering ultimately sets a fundamental limit on inter-modal-crosstalk for FMFs. Therefore, this work not only has implications specifically for SDM systems but also broadly for few-mode fiber optics and its applications in amplifiers, lasers, and sensors in which inter-modal crosstalk imposes a fundamental performance limitation.
Brauckmann, Hannes; Schumacher, Joerg
2016-01-01
Rayleigh-Benard convection and Taylor-Couette flow are two canonical flows that have many properties in common. We here compare the two flows in detail for parameter values where the Nusselt numbers, i.e. the thermal transport and the angular momentum transport normalized by the corresponding laminar values, coincide. We study turbulent Rayleigh-Benard convection in air at Rayleigh number Ra=1e7 and Taylor-Couette flow at shear Reynolds number Re_S=2e4 for two different mean rotation rates but the same Nusselt numbers. For individual pairwise related fields and convective currents, we compare the probability density functions normalized by the corresponding root mean square values and taken at different distances from the wall. We find one rotation number for which there is very good agreement between the mean profiles of the two corresponding quantities temperature and angular momentum. Similarly, there is good agreement between the fluctuations in temperature and velocity components. For the heat and angula...
Brauckmann, Hannes J.; Eckhardt, Bruno; Schumacher, Jörg
2017-03-01
Rayleigh-Bénard convection and Taylor-Couette flow are two canonical flows that have many properties in common. We here compare the two flows in detail for parameter values where the Nusselt numbers, i.e. the thermal transport and the angular momentum transport normalized by the corresponding laminar values, coincide. We study turbulent Rayleigh-Bénard convection in air at Rayleigh number Ra=107 and Taylor-Couette flow at shear Reynolds number ReS=2×104 for two different mean rotation rates but the same Nusselt numbers. For individual pairwise related fields and convective currents, we compare the probability density functions normalized by the corresponding root mean square values and taken at different distances from the wall. We find one rotation number for which there is very good agreement between the mean profiles of the two corresponding quantities temperature and angular momentum. Similarly, there is good agreement between the fluctuations in temperature and velocity components. For the heat and angular momentum currents, there are differences in the fluctuations outside the boundary layers that increase with overall rotation and can be related to differences in the flow structures in the boundary layer and in the bulk. The study extends the similarities between the two flows from global quantities to local quantities and reveals the effects of rotation on the transport.
Statistics of velocity and temperature fluctuations in two-dimensional Rayleigh-Bénard convection
Zhang, Yang; Huang, Yong-Xiang; Jiang, Nan; Liu, Yu-Lu; Lu, Zhi-Ming; Qiu, Xiang; Zhou, Quan
2017-08-01
We investigate fluctuations of the velocity and temperature fields in two-dimensional (2D) Rayleigh-Bénard (RB) convection by means of direct numerical simulations (DNS) over the Rayleigh number range 106≤Ra≤1010 and for a fixed Prandtl number Pr=5.3 and aspect ratio Γ =1 . Our results show that there exists a counter-gradient turbulent transport of energy from fluctuations to the mean flow both locally and globally, implying that the Reynolds stress is one of the driving mechanisms of the large-scale circulation in 2D turbulent RB convection besides the buoyancy of thermal plumes. We also find that the viscous boundary layer (BL) thicknesses near the horizontal conducting plates and near the vertical sidewalls, δu and δv, are almost the same for a given Ra, and they scale with the Rayleigh and Reynolds numbers as ˜Ra-0.26±0.03 and ˜Re-0.43±0.04 . Furthermore, the thermal BL thickness δθ defined based on the root-mean-square (rms) temperature profiles is found to agree with Prandtl-Blasius predictions from the scaling point of view. In addition, the probability density functions of turbulent energy ɛu' and thermal ɛθ' dissipation rates, calculated, respectively, within the viscous and thermal BLs, are found to be always non-log-normal and obey approximately a Bramwell-Holdsworth-Pinton distribution first introduced to characterize rare fluctuations in a confined turbulent flow and critical phenomena.
Zhou, Quan
2010-01-01
We present a systematic experimental study of geometric and statistical properties of thermal plumes in turbulent Rayleigh-B\\'{e}nard convection using the thermochromic-liquid-crystal (TLC) technique. The experiments were performed in three water-filled cylindrical convection cells with aspect ratios 2, 1, and 0.5 and over the Rayleigh-number range $5\\times10^7 \\leq Ra \\leq 10^{11}$. TLC thermal images of horizontal plane cuts at various depths below the top plate were acquired. Three-dimensional images of thermal plumes were then reconstructed from the two-dimensional slices of the temperature field. The results show that the often-called sheetlike plumes are really one-dimensional structures and may be called rodlike plumes. We find that the number densities for both sheetlike/rodlike and mushroomlike plumes have power-law dependence on $Ra$ with scaling exponents of $\\sim 0.3$, which is close to that between the Nusselt number $Nu$ and $Ra$. This result suggests that it is the plume number that primarily d...
Bounds on Heat Transport in Rapidly Rotating Rayleigh-B\\'{e}nard Convection
Grooms, Ian
2014-01-01
The heat transport in rotating Rayleigh-B\\'enard convection is considered in the limit of rapid rotation (small Ekman number $E$) and strong thermal forcing (large Rayleigh number $Ra$). The analysis proceeds from a set of asymptotically reduced equations appropriate for rotationally constrained dynamics; the conjectured range of validity for these equations is $Ra \\lesssim E^{-8/5}$. A rigorous bound on heat transport of $Nu \\le 20.56Ra^3E^4$ is derived in the limit of infinite Prandtl number using the background method. We demonstrate that the exponent in this bound cannot be improved on using a piece-wise monotonic background temperature profile like the one used here. This is true for finite Prandtl numbers as well, i.e. $Nu \\lesssim Ra^3$ is the best upper bound for this particular setup of the background method. The feature that obstructs the availability of a better bound in this case is the appearance of small-scale thermal plumes emanating from (or entering) the thermal boundary layer.
Turbulent Rayleigh-Bénard convection with polymers: Understanding how heat flux is modified
Benzi, Roberto; Ching, Emily S. C.; De Angelis, Elisabetta
2016-12-01
We study how polymers affect the heat flux in turbulent Rayleigh-Bénard convection at moderate Rayleigh numbers using direct numerical simulations with polymers of different relaxation times. We find that heat flux is enhanced by polymers and the amount of heat enhancement first increases and then decreases with the Weissenberg number, which is the ratio of the polymer relaxation time to the typical time scale of the flow. We show that this nonmonotonic behavior of the heat flux enhancement is the combined effect of the decrease in the viscous energy dissipation rate due to the viscosity of the Newtonian fluid and the increase in the energy dissipation rate due to polymers when Weissenberg number is increased. We explain why the viscous energy dissipation rate decreases with the Weissenberg number. Then by carrying out a generalized boundary layer analysis supplemented by a space-dependent effective viscosity from the numerical simulations, we provide a theoretical understanding of the change of the heat flux when the viscous energy dissipation rate is held constant. Our analysis thus provides a physical way to understand the numerical results.
Nataro, Chip; Ferguson, Michelle A.; Bocage, Katherine M.; Hess, Brian J.; Ross, Vincent J.; Swarr, Daniel T.
2004-01-01
An experiment to prepare a deuterium labeled adduct of a Lewis acid and Lewis base, to use computational methods allowing students to visualize the LUMO of Lewis acids, the HOMO of Lewis bases and the molecular orbitals of the adduct that is formed is developed. This allows students to see the interplay between calculated and experimental results.
Rayleigh-Bénard convection instability in the presence of temperature variation at the lower wall
Jovanović Miloš M.
2012-01-01
Full Text Available This paper analyzes the two-dimensional viscous fluid flow between two parallel plates, where the lower plate is heated and the upper one is cooled. The temperature difference between the plates is gradually increased during a certain time period, and afterwards it is temporarily constant. The temperature distribution on the lower plate is not constant in x-direction, and there is longitudinal sinusoidal temperature variation imposed on the mean temperature. We investigate the wave number and amplitude influence of this variation on the stability of Rayleigh-Benard convective cells, by direct numerical simulation of 2-D Navier-Stokes and energy equation.
A Practical Adaptive TuCM Scheme for Rayleigh Flat Fading Channels
伍守豪; 宋文涛
2004-01-01
A practical adaptive turbo coded modulation (TuCM) scheme was proposed and its adaptive method was described. With some hardware considerations, a suboptimal optimization algorithm that the number of fading regions is variable was put forward. Furthermore, the cutoff fade depth of power adaptation was modified to reduce the interruption probability. The results show that the proposed adaptive TuCM comes within 3 dB of Rayleigh fading channel capacity, and exhibits about 3 dB power gain relative to the conventional adaptive trellis-coded modulation (TCM), and is easy to realize by hardware.
Combined effect of horizontal magnetic field and vorticity on Rayleigh Taylor instability
Banerjee, Rahul
2016-01-01
In this research, the height, curvature and velocity of the bubble tip in Rayleigh-Taylor instability at arbitrary Atwood number with horizontal magnetic field are investigated. To support the earlier simulation and experimental results, the vorticity generation inside the bubble is introduced. It is found that, in early nonlinear stage, the temporal evolution of the bubble tip parameters depend essentially on the strength and initial perturbation of the magnetic field, although the asymptotic nature coincides with the non magnetic case. The model proposed here agrees with the previous linear, nonlinear and simulation observations.
Quantum Effects on Rayleigh-Taylor Instability of Incompressible Plasma in a Vertical Magnetic Field
G.A.Hoshoudy
2010-01-01
@@ Quantum effects on Rayleigh-Taylor instability of a stratified incompressible plasmas layer under the influence of vertical magnetic field are investigated.The solutions of the linearized equations of motion together with the boundary conditions lead to deriving the relation between square normalized growth rate and square normalized wawe number in two algebraic equations and are numerically analyzed.In the case of the real solution of these two equations,they can be combined to generate a single equation.The results show that the presence of vertical magnetic field beside the quantum effect will bring about more stability on the growth rate of unstable configuration.
Propagation of Rayleigh waves in anisotropic layer overlying a semi-infinite sandy medium
P.C. Pal
2015-06-01
Full Text Available The present investigation deals with the propagation of Rayleigh waves in anisotropic layer overlying a sandy medium. Anisotropic material is in the nature of most general case i.e. of triclinic crystal and sandy medium is of alluvial soil type. The solutions for layer and half-space are obtained analytically. The displacement components in x and z directions are obtained for both the media. The dispersion relation is obtained subjected to certain boundary conditions. The special cases are considered. The numerical results are presented in the form of wave number and phase velocity (k − c analytical curves.
Reckinger, Scott James [Montana State Univ., Bozeman, MT (United States); Livescu, Daniel [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vasilyev, Oleg V. [Univ. of Colorado, Boulder, CO (United States)
2016-09-02
A comprehensive numerical methodology has been developed that handles the challenges introduced by considering the compressive nature of Rayleigh-Taylor instability (RTI) systems, which include sharp interfacial density gradients on strongly stratified background states, acoustic wave generation and removal at computational boundaries, and stratification-dependent vorticity production. The computational framework is used to simulate two-dimensional single-mode RTI to extreme late-times for a wide range of flow compressibility and variable density effects. The results show that flow compressibility acts to reduce the growth of RTI for low Atwood numbers, as predicted from linear stability analysis.
In situ Characterization of Nanoparticles Using Rayleigh Scattering
Santra, Biswajit; Shneider, Mikhail N.; Car, Roberto
2017-01-01
We report a theoretical analysis showing that Rayleigh scattering could be used to monitor the growth of nanoparticles under arc discharge conditions. We compute the Rayleigh scattering cross sections of the nanoparticles by combining light scattering theory for gas-particle mixtures with calculations of the dynamic electronic polarizability of the nanoparticles. We find that the resolution of the Rayleigh scattering probe is adequate to detect nanoparticles as small as C60 at the expected concentrations of synthesis conditions in the arc periphery. Larger asymmetric nanoparticles would yield brighter signals, making possible to follow the evolution of the growing nanoparticle population from the evolution of the scattered intensity. Observable spectral features include characteristic resonant behaviour, shape-dependent depolarization ratio, and mass-dependent line shape. Direct observation of nanoparticles in the early stages of growth with unobtrusive laser probes should give insight on the particle formation mechanisms and may lead to better-controlled synthesis protocols.
In situ Characterization of Nanoparticles Using Rayleigh Scattering.
Santra, Biswajit; Shneider, Mikhail N; Car, Roberto
2017-01-10
We report a theoretical analysis showing that Rayleigh scattering could be used to monitor the growth of nanoparticles under arc discharge conditions. We compute the Rayleigh scattering cross sections of the nanoparticles by combining light scattering theory for gas-particle mixtures with calculations of the dynamic electronic polarizability of the nanoparticles. We find that the resolution of the Rayleigh scattering probe is adequate to detect nanoparticles as small as C60 at the expected concentrations of synthesis conditions in the arc periphery. Larger asymmetric nanoparticles would yield brighter signals, making possible to follow the evolution of the growing nanoparticle population from the evolution of the scattered intensity. Observable spectral features include characteristic resonant behaviour, shape-dependent depolarization ratio, and mass-dependent line shape. Direct observation of nanoparticles in the early stages of growth with unobtrusive laser probes should give insight on the particle formation mechanisms and may lead to better-controlled synthesis protocols.
Eun Joo Chung
2015-05-01
Full Text Available Lewy body-related disorders are characterized by the presence of Lewy bodies and Lewy neurites, which have abnormal aggregations of α-synuclein in the nigral and extranigral areas, including in the heart. 123I-metaiodobenzylguanidine (MIBG scintigraphy is a well-known tool to evaluate cardiac sympathetic denervation in the Lewy body-related disorders. MIBG scintigraphy showed low uptake of MIBG in the Lewy body-related disorders, including Parkinson’s disease, dementia with Lewy bodies, pure autonomic failure and rapid eye movement sleep behavior disorder. This review summarizes previous results on the diagnostic applications of MIBG scintigraphy in Lewy body-related disorders.
Hydrogen activation using a novel tribenzyltin Lewis acid.
Cooper, Robert T; Sapsford, Joshua S; Turnell-Ritson, Roland C; Hyon, Dong-Hun; White, Andrew J P; Ashley, Andrew E
2017-08-28
Over the last decade there has been an explosion in the reactivity and applications of frustrated Lewis pair (FLP) chemistry. Despite this, the Lewis acids (LAs) in these transformations are often boranes, with heavier p-block elements receiving surprisingly little attention. The novel LA Bn3SnOTf (1) has been synthesized from simple, inexpensive starting materials and has been spectroscopically and structurally characterized. Subtle modulation of the electronics at the tin centre has led to an increase in its Lewis acidity in comparison with previously reported R3SnOTf LAs, and has facilitated low temperature hydrogen activation and imine hydrogenation. Deactivation pathways of the R3Sn(+) LA core have also been investigated.This article is part of the themed issue 'Frustrated Lewis pair chemistry'. © 2017 The Authors.
Is It Lewy Body Dementia or Something Else?
... Options Join the fight against LBD! Donate Is It LBD or Something Else? Early and accurate diagnosis ... dementia with Lewy bodies’ (DLB). Symptoms that differentiate it from Alzheimer’s include unpredictable levels of cognitive ability, ...
Graphene-coated rayleigh SAW resonators for NO2 detection
Thomas, Stephen M.; Cole, Marina; De Luca, A; Torrisi, F.; Ferrari, A. C.; Udrea, Florin; Gardner, J. W.
2014-01-01
This paper describes the development of a novel low-cost Rayleigh Surface Acoustic Wave Resonator (SAWR) device coated with a graphene layer that is capable of detecting PPM levels of NO2 in air. The sensor comprises two 262 MHz ST-cut quartz based Rayleigh SAWRs arranged in a dual oscillator configuration; where one resonator is coated with gas-sensitive graphene, and the other left uncoated to act as a reference. An array of NMP-dispersed exfoliated reduced graphene oxide dots was deposited...
Passive retrieval of Rayleigh waves in disordered elastic media.
Larose, Eric; Derode, Arnaud; Clorennec, Dominique; Margerin, Ludovic; Campillo, Michel
2005-10-01
When averaged over sources or disorder, cross correlation of diffuse fields yields the Green's function between two passive sensors. This technique is applied to elastic ultrasonic waves in an open scattering slab mimicking seismic waves in the Earth's crust. It appears that the Rayleigh wave reconstruction depends on the scattering properties of the elastic slab. Special attention is paid to the specific role of bulk to Rayleigh wave coupling, which may result in unexpected phenomena, such as a persistent time asymmetry in the diffuse regime.
Ergodic channel capacity of the spatial correlated rayleigh MIMO channel
ZHANG Hui-ping; WU Ping; LIU Ai-jun
2007-01-01
The theoretical capacity of the spatial correlated Rayleigh multiple input multiple output (MIMO) channel is an important issue in MIMO technology. In this article, an ergodic channel capacity formula of the spatial correlated rayleigh MIMO channel is provided, which is deduced when two antennas exist at either the transmitter or the receiver. The multi-dimensional least-squares fit algorithm is employed to narrow the difference between the theoretical formula capacity and the practical capacity. Simulation results show that the theoretical capacity approaches the practical one closely.
Impact of predatory threat on fear extinction in Lewis rats
Goswami, Sonal; Cascardi, Michele; Rodríguez-Sierra, Olga E.; Duvarci, Sevil; Paré, Denis
2010-01-01
Humans with post-traumatic stress disorder (PTSD) are deficient at extinguishing conditioned fear responses. A study of identical twins concluded that this extinction deficit does not predate trauma but develops as a result of trauma. The present study tested whether the Lewis rat model of PTSD reproduces these features of the human syndrome. Lewis rats were subjected to classical auditory fear conditioning before or after exposure to a predatory threat that mimics a type of traumatic stress ...
DatSCAN In Differential Diagnostics of Lewy Body Disease.
Luzny, Jan; Ivanova, Katerina
2016-06-01
Differential diagnosis between Lewy body disease and Alzheimer´s disease might be difficult because of similarities of clinical symptoms in both neurodegenerative diseases. DatSCAN is a modern functional neuroimmaging method which differentiates between this similar diseases and helps in correct treatment strategy. We report our positive experience with DatSCAN in differentiating Lewy body disease from Alzheimer´s disease. This is a case report of a woman with Lewy body disease, initially diagnosed as Alzheimer´s disease. DatSCAN neuroimmaging method was used in differential diagnosis of dementia. Memory impairment, impaired activities of daily living, sleep and behavioral disturbances were present in our case. Donepezil was well tolerated, but haloperidol administration was followed by development of severe dystonia. DatSCAN showed deficient dopaminergic presynaptic transport in substantia nigra and striatum. This finding is typical for Lewy body disease not for Alzheimer´s disease. DatSCAN neuroimmaging is a suitable method for differentiating Lewy body disease from Alzheimer´s disease. Deficient dopaminergic presynaptic transport in substantia nigra and striatum is typical for Lewy body disease.
New subgrid-scale models for large-eddy simulation of Rayleigh-Bénard convection
Dabbagh, F.; Trias, F. X.; Gorobets, A.; Oliva, A.
2016-09-01
At the crossroad between flow topology analysis and the theory of turbulence, a new eddy-viscosity model for Large-eddy simulation has been recently proposed by Trias et al.[PoF, 27, 065103 (2015)]. The S3PQR-model has the proper cubic near-wall behaviour and no intrinsic limitations for statistically inhomogeneous flows. In this work, the new model has been tested for an air turbulent Rayleigh-Benard convection in a rectangular cell of aspect ratio unity and n span-wise open-ended distance. To do so, direct numerical simulation has been carried out at two Rayleigh numbers Ra = 108 and 1010, to assess the model performance and investigate a priori the effect of the turbulent Prandtl number. Using an approximate formula based on the Taylor series expansion, the turbulent Prandtl number has been calculated and revealed a constant and Ra-independent value across the bulk region equals to 0.55. It is found that the turbulent components of eddy-viscosity and eddy-diffusivity are positively prevalent to maintain a turbulent wind essentially driven by the mean buoyant force at the sidewalls. On the other hand, the new eddy-viscosity model is preliminary tested for the case of Ra = 108 and showed overestimation of heat flux within the boundary layer but fairly good prediction of turbulent kinetics at this moderate turbulent flow.
Lewis-Sumner syndrome and multifocal motor neuropathy.
Verschueren, Annie; Azulay, Jean Philippe; Attarian, Shahram; Boucraut, José; Pellissier, Jean François; Pouget, Jean
2005-01-01
We compared the clinical, electrophysiological, laboratory, and pathological features of 13 patients with Lewis-Sumner syndrome (LSS) with those of 20 patients with multifocal motor neuropathy (MMN). LSS and MMN patients have several common clinical features: age at onset, weakness in the distribution of individual peripheral nerves, mild wasting, cramps and fasciculations, partial areflexia, and frequent stepwise disease course. Cerebrospinal fluid protein level was normal or slightly elevated, but always less than 100 mg/dl. Conduction blocks are the electrophysiological hallmarks of these two neuropathies, and no differences in distribution and number of blocks were found. Contrary to MMN, lower-limb involvement at onset was frequent in LSS but extension to the upper limbs was a frequent later feature of the disease. Cranial nerve involvement was noted in 4 LSS patients during relapses and absent in all MMN patients. The major distinguishing features were the clinical and electrophysiological sensory involvement in LSS, and the lack of anti-GM1 antibodies in LSS, whereas IgM anti-GM1 were found in 40% of MMN patients. Some LSS patients responded to steroid therapy, whereas this was ineffective in MMN. From these features, LSS can be considered an entity distinct from MMN, with its own clinical, laboratory, and electrophysiological characteristics, and as an intermediate link between chronic inflammatory demyelinating polyneuropathy and MMN.
Comparison of risk factor profiles in incidental Lewy body disease and Parkinson disease.
Frigerio, Roberta; Fujishiro, Hiroshige; Maraganore, Demetrius M; Klos, Kevin J; DelleDonne, Anthony; Heckman, Michael G; Crook, Julia E; Josephs, Keith A; Parisi, Joseph E; Boeve, Bradley F; Dickson, Dennis W; Ahlskog, J Eric
2009-09-01
To explore whether associations of potential risk factors for incidental Lewy body disease (iLBD) are similar to those for Parkinson disease (PD). Brain autopsy study (1988-2004) of subjects without evidence of neurodegenerative disease or tremor who were evaluated by at least 1 physician within 1 year of death. Researchers analyzed incidental Lewy pathology blinded to clinical abstraction. Olmsted County, Minnesota. Subjects Residents of Olmsted County and the immediate vicinity aged older than 60 years. Whether risk factors previously associated with PD in Olmsted County are also associated with iLBD. Of 235 subjects, 34 had iLBD (14.5%). The overall risk factor profiles for iLBD and PD were fairly similar between the 2 sets of odds ratio (OR) estimates, with 11 of 16 ORs in the same direction. Prior Olmsted County studies documented 7 risk factors with statistically significant associations with PD; for physician occupation and caffeine intake, the ORs for iLBD were in the same direction and statistically significant, whereas for education, head injury, and number of children, they were in the same direction but not significant; they were in the opposite direction but not statistically significant for depression and anxiety. Incidental Lewy body disease was not associated with various end-of-life conditions or causes of death, though these patients were slightly older and more likely cachectic. Based on this exploratory study, iLBD and PD appear to have similar risk factor profiles. Thus, at least some cases of iLBD could represent preclinical PD, arrested PD, or a partial syndrome due to a lesser burden of causative factors. Incidental Lewy body disease is not explained by nonspecific end-of-life brain insults.
Million, M; Wang, L; Martinez, V; Taché, Y
2000-09-22
The responsiveness of hypothalamic CRF to various stressors is reduced in the young female Lewis relative to the histocompatible Fischer rat. Whether such a difference impacts the brain-gut response to water avoidance stress was investigated by monitoring Fos immunoreactivity in the brain and sacral spinal cord and fecal pellet output. Exposure for 60 min to water avoidance stress increased the number of Fos positive cells in the paraventricular nucleus of the hypothalamus (PVN), nucleus tractus solitarius (NTS), and the parasympathetic nucleus of the lumbo-sacral spinal cord (L6-S1) in both Lewis and Fischer rats compared with non stress groups. The Fos response was lower by 32.0% in the PVN, and 63% in sacral parasympathetic nucleus in Lewis compared with Fischer rats while similar Fos expression was observed in the NTS. Stress-induced defecation was reduced by 52% in Lewis compared with Fischer rats while colonic motor response to CRF injected intracisternally resulted in a similar pattern and magnitude of defecation in both strains. The CRF receptor antagonist [D-Phe12,Nle(21,38)C(a)MeLeu(37)]-CRF(12-41) injected intracisternally antagonized partly the defecation response in Lewis and Fischer rats. These data indicate that a lower activation of PVN and sacral parasympathetic nuclei in Lewis compared with Fisher rats may contribute to the differential colonic motor response and that the blunted CRF hypothalamic response to stress, unlike responsiveness to central CRF plays a role.
Field-Correlation Effects on Rayleigh-Enhanced Nondegenerate Four-Wave Mixing
王延帮; 姜谦; 米辛; 俞祖和; 傅盘铭
2002-01-01
We study Rayleigh-enhanced nondegenerate four-wave mixing (NFWM) with time-delayed, correlated fluctuating fields. The importance of the field correlation is revealed in the Rayleigh-enhanced NFWM spectrum when the time delay is varied. The Rayleigh-enhanced NFWM is employed to study the ultrafast processes in the frequency domain. A relaxation time as short as 220 fs was deduced in the Rayleigh-enhanced NFWM experiments in carbon disulphide.
Denmark, Scott E; Heemstra, John R
2007-07-20
The generality of Lewis base catalyzed, Lewis acid mediated, enantioselective vinylogous aldol addition reactions has been investigated. The combination of silicon tetrachloride and chiral phosphoramides is a competent catalyst for highly selective additions of a variety of alpha,beta-unsaturated ketone-, 1,3-diketone-, and alpha,beta-unsaturated amide-derived dienolates to aldehydes. These reactions provided high levels of gamma-site selectivity for a variety of substitution patterns on the dienyl unit. Both ketone- and morpholine amide-derived dienol ethers afforded high enantio- and diastereoselectivity in the addition to conjugated aldehydes. Although alpha,beta-unsaturated ketone-derived dienolate did not react with aliphatic aldehydes, alpha,beta-unsaturated amide-derived dienolates underwent addition at reasonable rates affording high yields of vinylogous aldol product. The enantioselectivities achieved with the morpholine derived-dienolate in the addition to aliphatic aldehydes was the highest afforded to date with the silicon tetrachloride-chiral phosphoramide system. Furthermore, the ability to cleanly convert the morpholine amide to a methyl ketone was demonstrated.
A Simple Capacity Formula for Correlated Diversity Rayleigh Fading Channels
CHENG Xing-qing; SU Shu-chun; LI Dao-ben
2004-01-01
Abstract: The system capacity can be considerably increased if we appropriately exploit the randomness of multipath propagation. A simple average capacity formula is derived for correlated diversity Rayleigh fading channels through linear transformation method.Numerical results that illustrate the effect of correlation parameter and diversity order on the diversitycapacity are also presented.
Heat transfer mechanisms in bubbly Rayleigh-Bénard convection
Oresta, Paolo; Verzicco, Roberto; Lohse, Detlef; Presperetti, Andrea
2009-01-01
The heat transfer mechanism in Rayleigh-Bénard convection in a liquid with a mean temperature close to its boiling point is studied through numerical simulations with pointlike vapor bubbles, which are allowed to grow or shrink through evaporation and condensation and which act back on the flow both
A Rayleigh Doppler Frequency Estimator Derived from Maximum Likelihood Theory
Hansen, Henrik; Affes, Sofiene; Mermelstein, Paul
1999-01-01
Reliable estimates of Rayleigh Doppler frequency are useful for the optimization of adaptive multiple access wireless receivers.The adaptation parameters of such receivers are sensitive to the amount of Doppler and automatic reconfiguration to the speed of terminalmovement can optimize cell...
PALM and STORM: what hides beyond the Rayleigh limit?
Henriques, R
2009-06-01
Full Text Available -1 Biotechnol. J. 2009, 4, 846?857 Review PALM and STORM: What hides beyond the Rayleigh limit? Ricardo Henriques1 and Musa M. Mhlanga1,2 1 Gene Expression and Biophysics Unit, Instituto de Medicina Molecular, Faculdade de Medicina Universidade de...
A COMPARATIVE STUDY UNDER PROGRESSIVELY FIRST FAILURE CENSORED RAYLEIGH DATA
Gyan Prakash
2015-06-01
Full Text Available A comparative study presented in this article for two different asymmetric loss functions is based on simulation. Two-parameter Rayleigh model is considered here as the underline model for evaluating the properties of Bayes estimators under progressive first failure censored data. Known and unknown both cases of location parameter are considered here for Bayes estimation of scale parameter.
Attenuation of Rayleigh Surface Waves in a Porous Material
DEBBOUB Salima; BOUMA(I)ZA Youcef; BOUDOUR Amar; TAHRAOUI Tarek
2012-01-01
Using acoustic microscopy at higher frequency,we show the velocity evolutions of surface acoustic waves,in particular Rayleigh waves that depend on porosity for a mesoporous silicon layer.The velocities are obtained from different V(z) curves,which are determined experimentally at a frequency of 600MHz.The analysis of V(z) data yields attenuation that is directly dependent on porosity.On the other hand,αN attenuation has been modeled and allows us to investigate its influence on the velocity VR of the propagation for Rayleigh waves.%Using acoustic microscopy at higher frequency, we show the velocity evolutions of surface acoustic waves, in particular Rayleigh waves that depend on porosity for a mesoporous silicon layer. The velocities are obtained from different V(z) curves, which are determined experimentally at a frequency of 600 MHz. The analysis of V(z) data yields attenuation that is directly dependent on porosity. On the other hand, αN attenuation has been modeled and allows us to investigate its influence on the velocity VR of the propagation for Rayleigh waves.
Spatial sub-Rayleigh imaging analysis via speckle laser illumination
Wang, Yunlong; Liu, Ruifeng; Chen, Dongxu; Gao, Hong; Zhang, Pei; Li, Fuli
2016-01-01
It is commonly accepted that optical sub-Rayleigh imaging has potential application in many fields. In this Letter, by confining the divergence of the optical field, as well as the size of the illumination source, we show that the first-order averaged intensity measurement via speckle laser illumina- tion can make an actual breakthrough on the Rayleigh limit. For a high-order algorithm, it has been reported that the autocorrelation function can be utilized to achieve the sub-Rayleigh feature. However, we find that this sub- Rayleigh feature for the high-order algorithm is limited only to binary objects, and the image will be distorted when a gray object is placed. This property encourages us to find the physics behind the high-order correlation imaging algo- rithm. We address these explanations in this Letter and find that for different types of high-order algorithm, there is always a seat in the right place from the cross-correlation function.
mitants of Order Statistics from Bivariate Inverse Rayleigh Distribution
Muhammad Aleem
2006-01-01
Full Text Available The probability density function (pdf of the rth, 1 r n and joint pdf of the rth and sth, 1 rRayleigh Distribution and their moments, product moments are obtained. Its percentiles are also obtained.
A Rayleigh Doppler frequency estimator derived from maximum likelihood theory
Hansen, Henrik; Affes, Sofiéne; Mermelstein, Paul
1999-01-01
Reliable estimates of Rayleigh Doppler frequency are useful for the optimization of adaptive multiple access wireless receivers. The adaptation parameters of such receivers are sensitive to the amount of Doppler and automatic reconfiguration to the speed of terminal movement can optimize cell cap...
Exponential stabilization of a Rayleigh beam using collocated control
Weiss, George; Curtain, Ruth F.
We consider a hinged elastic beam described by the Rayleigh beam equation on the interval [0, pi]. We assume the presence of two sensors: one measures the angular velocity of the beam at a point xi is an element of [0, pi] and the other measures the bending (curvature) of the beam at the same point.
Elk Monitoring Protocol for Lewis and Clark National Historical Park, Version 1.0
Jenkins, Kurt J.; Griffin, Paul C.; Boetsch, John R.; Cole, Carla
2011-01-01
Maintaining elk (Cervus elaphus roosevelti) herds that frequent Lewis and Clark National Historical Park (NHP) is central to the park’s purpose of preserving the historic, cultural, scenic, and natural resources. Elk were critical to sustaining the members of the Lewis and Clark expedition by providing food and clothing over the winter of 1805-1806. Today, elk viewing opportunities in the park and surrounding region generate broad appeal with the visiting public, which number over 250,000 per year at the Fort Clatsop visitor center. This protocol describes procedures for monitoring trends in the use of the Fort Clatsop area by Roosevelt elk. Specific objectives of elk monitoring in Lewis and Clark NHP are to measure the relative use and proportion of area used by elk during winter in the Fort Clatsop Unit of the park, and the rate at which elk are sighted from roads in and around the park. Relative use and the proportion of area used by elk are determined from elk fecal pellet surveys conducted every other year in the Fort Clatsop park unit. Pairs of observers visit a systematic array of permanent plots in the fall to clear them of elk fecal pellets, and return to the plots in late winter to count elk fecal pellets that have accumulated during winter. Half of the subplots are counted by two independent observers, which allows for the estimation of relative use and proportion of area occupied by elk with analyses of detection biases that account for unseen elk pellet groups. Standardized road surveys are conducted in and near the Fort Clatsop park unit three or four times monthly during alternate months. Data from road surveys are used to quantify the rate that park visitors would be expected to see elk, when driving the selected set of routes. The monitoring protocol is based on three field seasons of development and testing. The protocol narrative describes the background, rationale, sampling design, field methods, analytical methods, data management, reporting
Neuroimaging characteristics of dementia with Lewy bodies.
Mak, Elijah; Su, Li; Williams, Guy B; O'Brien, John T
2014-01-01
This review summarises the findings and applications from neuroimaging studies in dementia with Lewy bodies (DLB), highlighting key differences between DLB and other subtypes of dementia. We also discuss the increasingly important role of imaging biomarkers in differential diagnosis and outline promising areas for future research in DLB. DLB shares common clinical, neuropsychological and pathological features with Parkinson's disease dementia and other dementia subtypes, such as Alzheimer's disease. Despite the development of consensus diagnostic criteria, the sensitivity for differential diagnosis of DLB in clinical practice remains low and many DLB patients will be misdiagnosed. The importance of developing accurate imaging markers in dementia is highlighted by the potential for treatments targeting specific molecular abnormalities as well as the responsiveness to cholinesterase inhibitors and marked neuroleptic sensitivity of DLB. We review various brain imaging techniques that have been applied to investigate DLB, including the characteristic nigrostriatal degeneration in DLB using positron emission tomography (PET) and single-photon emission computed tomography (SPECT) tracers. Dopamine transporter loss has proven to reliably differentiate DLB from other dementias and has been incorporated into the revised clinical diagnostic criteria for DLB. To date, this remains the 'gold standard' for diagnostic imaging of DLB. Regional cerebral blood flow, 18 F-fluorodeoxygluclose-PET and SPECT have also identified marked deficits in the occipital regions with relative sparing of the medial temporal lobe when compared to Alzheimer's disease. In addition, structural, diffusion, and functional magnetic resonance imaging techniques have shown alterations in structure, white matter integrity, and functional activity in DLB. We argue that the multimodal identification of DLB-specific biomarkers has the potential to improve ante-mortem diagnosis and contribute to our
Kilkenny, J.D.
1994-08-04
As shown elsewhere an ablatively imploded shell is hydrodynamically unstable, the dominant instability being the well known Rayleigh-Taylor instability with growth rate {gamma} = {radical}Akg where k = 2{pi}/{lambda} is the wave number, g is the acceleration and A the Attwood number ({rho}{sub hi} {minus} {rho}{sub lo})/({rho}{sub hi} + {rho}{sub lo}) where {rho}{sub hi} is the density of the heavier fluid and {rho}{sub lo} is the density of the lighter fluid. A theoretical understanding of ablative stabilization has gradually evolved, confirmed over the last five years by experiments. The linear growth is very well understood with excellent agreement between experiment and simulation for planar geometry with wavelengths in the region of 30--100{mu}m. There is an accurate, albeit phenomenological dispersion relation. The non-linear growth has been measured and agrees with calculations. In this lecture, the authors go into the fundamentals of the Rayleigh-Taylor instability and the experimental measurements that show it is stabilized sufficiently by ablation in regimes relevant to ICF.
Search for the ``ultimate state" in turbulent Rayleigh-B'enard convection
Ahlers, Guenter; Funfschilling, Denis; Bodenschatz, Eberhard
2009-11-01
Measurements of the Nusselt number Nu will be reported for turbulent Rayleigh-B'enard convection of a cylindrical sample. They cover the Rayleigh-number range 10^11 Ra 2x10^15 using N2 (Pr = 0.72) and SF6 (Pr = 0.79 to 0.84) at pressures up to 19 bars and near-ambient temperatures. The sample had a height L=2.24m and diameter D = 1.12m and utilized the high-pressure vessel known as the ``Uboot of G"ottingen" at the Max Planck Institute for Dynamics and Self-Organization in G"ottingen, Germany. For Ra 4x10^13 the data yielded Nu Ra^γeff with γeff= 0.308 and did not show the transition near Ra = 10^11 to an ``ultimate regime" that was reported by Chavanne et al. At Ra = 4x10^13 there is a well defined but continuous transition to a regime where γeff is smaller than 0.30.
Thermal Rayleigh-Marangoni convection in a three-layer liquid-metal-battery model
Köllner, Thomas; Boeck, Thomas; Schumacher, Jörg
2017-05-01
The combined effects of buoyancy-driven Rayleigh-Bénard convection (RC) and surface tension-driven Marangoni convection (MC) are studied in a triple-layer configuration which serves as a simplified model for a liquid metal battery (LMB). The three-layer model consists of a liquid metal alloy cathode, a molten salt separation layer, and a liquid metal anode at the top. Convection is triggered by the temperature gradient between the hot electrolyte and the colder electrodes, which is a consequence of the release of resistive heat during operation. We present a linear stability analysis of the state of pure thermal conduction in combination with three-dimensional direct numerical simulations of the nonlinear turbulent evolution on the basis of a pseudospectral method. Five different modes of convection are identified in the configuration, which are partly coupled to each other: RC in the upper electrode, RC with internal heating in the molten salt layer, and MC at both interfaces between molten salt and electrode as well as anticonvection in the middle layer and lower electrode. The linear stability analysis confirms that the additional Marangoni effect in the present setup increases the growth rates of the linearly unstable modes, i.e., Marangoni and Rayleigh-Bénard instability act together in the molten salt layer. The critical Grashof and Marangoni numbers decrease with increasing middle layer thickness. The calculated thresholds for the onset of convection are found for realistic current densities of laboratory-sized LMBs. The global turbulent heat transfer follows scaling predictions for internally heated RC. The global turbulent momentum transfer is comparable with turbulent convection in the classical Rayleigh-Bénard case. In summary, our studies show that incorporating Marangoni effects generates smaller flow structures, alters the velocity magnitudes, and enhances the turbulent heat transfer across the triple-layer configuration.
On Multiple Users Scheduling Using Superposition Coding over Rayleigh Fading Channels
Zafar, Ammar
2013-02-20
In this letter, numerical results are provided to analyze the gains of multiple users scheduling via superposition coding with successive interference cancellation in comparison with the conventional single user scheduling in Rayleigh blockfading broadcast channels. The information-theoretic optimal power, rate and decoding order allocation for the superposition coding scheme are considered and the corresponding histogram for the optimal number of scheduled users is evaluated. Results show that at optimality there is a high probability that only two or three users are scheduled per channel transmission block. Numerical results for the gains of multiple users scheduling in terms of the long term throughput under hard and proportional fairness as well as for fixed merit weights for the users are also provided. These results show that the performance gain of multiple users scheduling over single user scheduling increases when the total number of users in the network increases, and it can exceed 10% for high number of users
Large-scale vortices in rapidly rotating Rayleigh-B\\'enard convection
Guervilly, Céline; Jones, Chris A
2014-01-01
Using numerical simulations of rapidly rotating Boussinesq convection in a Cartesian box, we study the formation of long-lived, large-scale, depth-invariant coherent structures. These structures, which consist of concentrated cyclones, grow to the horizontal size of the box, with velocities significantly larger than the convective motions. We vary the rotation rate, the thermal driving and the aspect ratio in order to determine the domain of existence of these large-scale vortices (LSV). We find that two conditions are required for their formation. First, the Rayleigh number, a meaure of the thermal driving, must be several times its value at the linear onset of convection; this corresponds to Reynolds numbers, based on the convective velocity and the box depth, $\\gtrsim 100$. Second, the rotational constraint on the convection structures must be strong. This requires that the local Rossby number, based on the convective velocity and the horizontal convective scale, $\\lesssim 0.15$. Simulations in which certa...
Large-scale inhomogeneity in sapphire test masses revealed by Rayleigh scattering imaging
Yan, Zewu; Ju, Li; Eon, François; Gras, Slawomir; Zhao, Chunnong; Jacob, John; Blair, David G.
2004-03-01
Rayleigh scattering in test masses can introduce noise and reduce the sensitivity of laser interferometric gravitational wave detectors. In this paper, we present laser Rayleigh scattering imaging as a technique to investigate sapphire test masses. The system provides three-dimensional Rayleigh scattering mapping of entire test masses and quantitative evaluation of the Rayleigh scattering coefficient. Rayleigh scattering mapping of two sapphire samples reveals point defects as well as inhomogeneous structures in the samples. We present results showing significant non-uniform scattering within two 4.5 kg sapphire test masses manufactured by the heat exchanger method.
Common Textbook and Teaching Misrepresentations of Lewis Structures
Suidan, Laila; Badenhoop, Jay K.; Glendening, Eric D.; Weinhold, Frank
1995-07-01
Current freshman chemistry textbooks commonly advise the drawing of Lewis structures with much emphasis on the reduction of formal charge and little on the preservation of the octet rule. This currently accepted method produces structures different from the original Lewis structures, which rarely had expanded valence shells on central atoms. Computational results from Gaussian 92 have shown us that the leading resonance structures cited in freshman chemistry textbooks are often not the most accurate to represent the molecules and are, at best, minor resonance structures, whose presentation is not worth the confusion that it causes for many first-year students. Instead, the Lewis structures that most accurately represent these molecules are the original Lewis structures, which generally abide by the octet rule. If the octet rule is more strongly stressed in the teaching of Lewis structures-thus avoiding the many complications and sources of confusion related to valence-shell expansion and reduction of formal charge-freshman chemistry students will be able to rest a little easier at night.
Ogawa, Y., E-mail: y.ogawa@ap.titech.ac.jp [Department of Physics, Tokyo Institute of Technology, Oh-Okayama 2-12-1, Tokyo 152-8551 (Japan); Takahashi, S.; Nakajima, D.; Minami, F. [Department of Physics, Tokyo Institute of Technology, Oh-Okayama 2-12-1, Tokyo 152-8551 (Japan)
2013-01-15
Surface plasmon polariton (SPP) propagation on a Au thin film has been observed by tip-enhanced Rayleigh scattering. The interference pattern has been observed around the edge of the film. The interference is due to the near-field scattering light at the tip and SPP radiation from the edge of the film. From the interference width, we evaluated the wave number of SPP on the Au film. By changing the wavelength of the incidence light, we have obtained the dispersion relation of the SPP. The experimentally obtained dispersion relation is well corresponding to the calculated one using bulk Au parameters. - Highlights: Black-Right-Pointing-Pointer We observed surface plasmon polariton propagation on Au film by tip-enhanced Rayleigh scattering. Black-Right-Pointing-Pointer The dispersion relation was obtained by changing the wavelength of the incidence light. Black-Right-Pointing-Pointer The dispersion relation is well corresponding to the calculated one using bulk Au parameters.
Thierry Paquot, Lewis Mumford, Lewis Mumford. Pour une juste plénitude
Denoun, Martin
2015-01-01
La collection « Les précurseurs de la décroissance » des éditions du Passager clandestin s’étoffe rapidement et couvre une période historique très large, d’Épicure ou Lao-Tseu à Murray Bookchin ou André Gorz. L’objectif de la collection est de rendre visible la continuité de thématiques appelées aujourd’hui « décroissantes » chez des auteurs aux traditions a priori hétérogènes. Lewis Mumford, historien autodidacte des villes et des techniques, entre aujourd’hui dans cette bibliothèque décrois...
Compressibility Effect on the Rayleigh-Taylor Instability with Sheared Magnetic Fields
Ruderman, M. S.
2017-04-01
We study the effect of plasma compressibility on the Rayleigh-Taylor instability of a magnetic interface with a sheared magnetic field. We assume that the plasma is ideal and the equilibrium quantities are constant above and below the interface. We derive the dispersion equation. Written in dimensionless variables, it contains seven dimensionless parameters: the ratio of plasma densities above and below the interface ζ, the ratio of magnetic field magnitude squared χ, the shear angle α, the plasma beta above and below the interface, β2 and β1, the angle between the perturbation wave number and the magnetic field direction above the interface φ, and the dimensionless wave number κ. Only six of these parameters are independent because χ, β1, and β2 are related by the condition of total pressure continuity at the interface. Only perturbations with the wave number smaller than the critical wave number are unstable. The critical wave number depends on φ, but it is independent of β1 and β2, and is the same as that in the incompressible plasma approximation. The dispersion equation is solved numerically with ζ= 100, χ= 1, and β1 = β2 = β. We obtain the following results. When β decreases, so does the maximum instability increment. However, the effect is very moderate. It is more pronounced for high values of α. We also calculate the dependence on φ of the maximum instability increment with respect to κ. The instability increment takes its maximum at φ= φm. Again, the decrease of β results in the reduction of the instability increment. This reduction is more pronounced for high values of |φ- φm|. When both α and |φ- φm| are small, the reduction effect is practically negligible. The theoretical results are applied to the magnetic Rayleigh-Taylor instability of prominence threads in the solar atmosphere.
Late-time quadratic growth in single-mode Rayleigh-Taylor instability.
Wei, Tie; Livescu, Daniel
2012-10-01
The growth of the two-dimensional single-mode Rayleigh-Taylor instability (RTI) at low Atwood number (A=0.04) is investigated using Direct Numerical Simulations. The main result of the paper is that, at long times and sufficiently high Reynolds numbers, the bubble acceleration becomes stationary, indicating mean quadratic growth. This is contrary to the general belief that single-mode Rayleigh-Taylor instability reaches a constant bubble velocity at long times. At unity Schmidt number, the development of the instability is strongly influenced by the perturbation Reynolds number, defined as Rep≡λsqrt[Agλ/(1+A)]/ν. Thus, the instability undergoes different growth stages at low and high Rep. A new stage, chaotic development, was found at sufficiently high Rep values, after the reacceleration stage. During the chaotic stage, the instability experiences seemingly random acceleration and deceleration phases, as a result of complex vortical motions, with strong dependence on the initial perturbation shape (i.e., wavelength, amplitude, and diffusion thickness). Nevertheless, our results show that the mean acceleration of the bubble front becomes constant at late times, with little influence from the initial shape of the interface. As Rep is lowered to small values, the later instability stages, chaotic development, reacceleration, potential flow growth, and even the exponential growth described by linear stability theory, are subsequently no longer reached. Therefore, the results suggest a minimum Reynolds number and a minimum development time necessary to achieve all stages of single-mode RTI development, requirements which were not satisfied in the previous studies of single-mode RTI.
The Role of Naturalness in Lewis's Theory of Meaning
Brian Weatherson
2013-05-01
Full Text Available Many writers have held that in his later work, David Lewis adopted a theory of predicate meaning such that the meaning of a predicate is the most natural property that is (mostly consistent with the way the predicate is used. That orthodox interpretation is shared by both supporters and critics of Lewis's theory of meaning, but it has recently been strongly criticised by Wolfgang Schwarz. In this paper, I accept many of Schwarze's criticisms of the orthodox interpretation, and add some more. But I also argue that the orthodox interpretation has a grain of truth in it, and seeing that helps us appreciate the strength of Lewis's late theory of meaning.
Development of a metastatic fluorescent Lewis Lung carcinoma mouse model
Rask, Lene; Fregil, Marianne; Høgdall, Estrid;
2013-01-01
models. To examine the mechanisms involved in tumor metastasis, we first generated a stably transfected Lewis Lung carcinoma cell line expressing a far-red fluorescent protein, called Katushka. After in vivo growth in syngeneic mice, two fluorescent Lewis Lung cancer subpopulations were isolated from...... primary tumors and lung metastases. The metastasis-derived cells exhibited a significant improvement in in vitro invasive activity compared to the primary tumor-derived cells, using a quantitative invasion chamber assay. Moreover, expression levels of 84 tumor metastasis-related mRNAs, 88 cancer......-related microRNAs as well as Dicer and Drosha were determined using RT-qPCR. Compared to the primary Lewis Lung carcinoma subculture, the metastasis-derived cells exhibited statistically significantly increased mRNA levels for several matrix metalloproteinases as well as hepatocyte growth factor (HGF...
Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates.
Fukuzumi, Shunichi; Ohkubo, Kei; Lee, Yong-Min; Nam, Wonwoo
2015-12-01
Redox-inactive metal ions and Brønsted acids that function as Lewis acids play pivotal roles in modulating the redox reactivity of metal-oxygen intermediates, such as metal-oxo and metal-peroxo complexes. The mechanisms of the oxidative CH bond cleavage of toluene derivatives, sulfoxidation of thioanisole derivatives, and epoxidation of styrene derivatives by mononuclear nonheme iron(IV)-oxo complexes in the presence of triflic acid (HOTf) and Sc(OTf)3 have been unified as rate-determining electron transfer coupled with binding of Lewis acids (HOTf and Sc(OTf)3 ) by iron(III)-oxo complexes. All logarithms of the observed second-order rate constants of Lewis acid-promoted oxidative CH bond cleavage, sulfoxidation, and epoxidation reactions of iron(IV)-oxo complexes exhibit remarkably unified correlations with the driving forces of proton-coupled electron transfer (PCET) and metal ion-coupled electron transfer (MCET) in light of the Marcus theory of electron transfer when the differences in the formation constants of precursor complexes were taken into account. The binding of HOTf and Sc(OTf)3 to the metal-oxo moiety has been confirmed for Mn(IV) -oxo complexes. The enhancement of the electron-transfer reactivity of metal-oxo complexes by binding of Lewis acids increases with increasing the Lewis acidity of redox-inactive metal ions. Metal ions can also bind to mononuclear nonheme iron(III)-peroxo complexes, resulting in acceleration of the electron-transfer reduction but deceleration of the electron-transfer oxidation. Such a control on the reactivity of metal-oxygen intermediates by binding of Lewis acids provides valuable insight into the role of Ca(2+) in the oxidation of water to dioxygen by the oxygen-evolving complex in photosystem II. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
On the MIMO Capacity for Distributed System under Composite Rayleigh/Rician Fading and Shadowing
Santiago González-Aurioles
2015-01-01
Full Text Available Wireless channels are commonly affected by short-term fading and long-term fading (shadowing. The shadowing effects must be taken into account also when mobility is present in the wireless scenario. Using a composite fading model, the total channel capacity can be studied for a scenario with short-term Rayleigh fading along with shadowing. This work provides quantitative results for these kinds of scenarios with Rayleigh fading and shadowing, considering also multiple-input and multiple-output systems, which have not been previously reported. In addition, the channel capacity has been studied in depth in its relation with the shadowing level, signal to noise ratio, and the number of elements in the multiple-input and multiple-output system. Moreover, the channel performance with shadowing has been compared to the one without it. Furthermore, Rician model with shadowing is studied and its results are reported. In addition, correlated and experimental results are provided. It is identified that the distributed MIMO systems can benefit from shadowing in Rician channels. This advantage has not been reported previously. This type of fading is proposed for massive MIMO by others and our results open the door to emulate massive MIMO on a reverberation chamber.
ERASED-CHASE DECODING FOR RS-CODED MPSK SIGNALING OVER A RAYLEIGH FADING CHANNEL
Xu Chaojun; Sun Yue; Wang Xinmei
2007-01-01
In this paper,a novel dual-metric,the maximum and minimum Squared Euclidean Distance Increment(SEDI)brought by changing the hard decision symbol,is introduced to measure the reliability of the received M-ary Phase Shift Keying(MPSK)symbols over a Rayleigh fading channel.Based on the dual-metric,a Chase-type soft decoding algorithm,which is called erased-Chase algorithm,is developed for Reed-Solomon(RS)coded MPSK schemes.The proposed algorithm treats the unreliable symbols with small maximum SEDI as erasures,and tests the non-erased unreliable symbols with small minimum SEDI as the Chase-2 algorithm does.By introducing optimality test into the decoding procedure,much more reduction in the decoding complexity can be achieved.Simulation results of the RS(63,42,22)-coded 8-PSK scheme over a Rayleigh fading channel show that the proposed algorithm provides a very efficient tradeoff between the decoding complexity and the error performance.Finally,an adaptive scheme for the number of erasures is introduced into the decoding algorithm.
BER Performance Analysis of Rake Receiver in Rayleigh Fading Channel for UMTS environment
Pravindra Kumar
2010-06-01
Full Text Available The goal for the third generation of mobile communications system is to integrate a wide variety of communication services such as high speed data, video and multimedia traffic as well as voice signals. Under the Universal Mobile Telecommunication System (UMTS environment the Third Generation (3G has many advantages such as highly efficient spectrum utilisation and variable user data rates. In this paper, we present the bit error rate (BER performance analysis of Rake Receiver under UMTS environment with BPSK modulation technique and the convolutional coding at the transmitter and viterbi decoding at the receiver side. The Standard Gaussian Approximation (SGA is used to evaluate the performance of Rake Receiver over a frequency selective Rayleigh fading channel. The data is modulated, encoded, spread and transmitted through a frequency selective Rayleigh fading channel. The transmitted signal is corrupted by multiple access interference, and is further corrupted by AWGNat the receiver. In the receiver, dispreading, decoded and demodulated. Rake Receiver, directive antenna are employed to improve the system performance. We examined the BER performance of Rake Receiver with, varying the number of users, spreading factor, Rake fingers, Interfering Cells, and the value of directivity of antenna at base Station. From the results we have seen that the BER performance of Rake Receiver is affected by varying these parameters and gives useful results.
Mokler, Matthew; Roberts, Michael; Jacobs, Jeffrey
2011-11-01
Incompressible Rayleigh-Taylor instability experiments are presented in which two stratified miscible liquids having Atwood number of 0.2 are accelerated in a vertical linear induction motor driven drop tower. A test sled having only vertical freedom of motion contains the experiment tank and visualization equipment. The sled is positioned at the top of the tower within the linear motors and accelerated downward causing the initially stable interface to be unstable and allowing the Rayleigh-Taylor instability to develop. Experiments are presented with and without forced initial perturbations produced by vertically oscillating the test sled prior to the start of acceleration. The interface is visualized using a 445nm laser light source that illuminates a fluorescent dye mixed in one of the fluids. The resulting fluorescent images are recorded using a monochromatic high speed video camera. The laser beam is synchronously swept across the fluorescent fluid, at the frame rate of the camera, exposing a single plane of the interface allowing for the measurement of spike and bubble mixing layer growth rates.
Mokler, Matthew; Roberts, Michael; Jacobs, Jeffrey
2013-11-01
Incompressible Rayleigh-Taylor instability experiments are presented in which two stratified liquids having Atwood number of 0.2 are accelerated in a vertical linear induction motor driven drop tower. A test sled having only vertical freedom of motion contains the experiment tank and visualization equipment. The sled is positioned at the top of the tower within the linear induction motors and accelerated downward causing the initially stable interface to be unstable and allowing the Rayleigh-Taylor instability to develop. Forced and unforced experiments are conducted using both immiscible and miscible liquid combinations. Forced initial perturbations are produced by vertically oscillating the test sled prior to the start of acceleration. The interface is visualized using a 445 nm laser light source that illuminates a fluorescent dye mixed in one of the fluids. The resulting fluorescent images are recorded using a monochromatic high speed video camera. The laser beam is synchronously swept across the fluorescent fluid, at the frame rate of the camera, exposing a single plane of the interface allowing for the measurement of spike and bubble growth. Comparisons between miscible and immiscible mixing layer distributions are made from the resulting interface concentration profiles.
Simulations of Rayleigh Taylor Instabilities in the presence of a Strong Radiative shock
Trantham, Matthew; Kuranz, Carolyn; Shvarts, Dov; Drake, R. P.
2016-10-01
Recent Supernova Rayleigh Taylor experiments on the National Ignition Facility (NIF) are relevant to the evolution of core-collapse supernovae in which red supergiant stars explode. Here we report simulations of these experiments using the CRASH code. The CRASH code, developed at the University of Michigan to design and analyze high-energy-density experiments, is an Eulerian code with block-adaptive mesh refinement, multigroup diffusive radiation transport, and electron heat conduction. We explore two cases, one in which the shock is strongly radiative, and another with negligible radiation. The experiments in all cases produced structures at embedded interfaces by the Rayleigh Taylor instability. The weaker shocked environment is cooler and the instability grows classically. The strongly radiative shock produces a warm environment near the instability, ablates the interface, and alters the growth. We compare the simulated results with the experimental data and attempt to explain the differences. This work is funded by the NNSA-DS and SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas, Grant Number DE-NA0002956.
Heat transport in boiling turbulent Rayleigh-B\\'{e}nard convection
Lakkaraju, Rajaram; Oresta, Paolo; Verzicco, Roberto; Lohse, Detlef; Prosperetti, Andrea
2014-01-01
Boiling is an extremely effective way to promote heat transfer from a hot surface to a liquid due to several mechanisms many of which are not understood in quantitative detail. An important component of the overall process is that the buoyancy of the bubbles compounds with that of the liquid to give rise to a much enhanced natural convection. In this paper we focus specifically on this enhancement and present a numerical study of the resulting two-phase Rayleigh-B\\'enard convection process. We make no attempt to model other aspects of the boiling process such as bubble nucleation and detachment. We consider a cylindrical cell with a diameter equal to its height. The cell base and top are held at temperatures above and below the boiling point of the liquid, respectively. By keeping the temperature difference constant and changing the liquid pressure we study the effect of the liquid superheat in a Rayleigh number range that, in the absence of boiling, would be between $2\\times10^6$ and $5\\times10^9$. We find a...
Analytical modeling of magnetic Rayleigh-Taylor instabilities in compressible fluids
Liberatore, Stéphane; Bouquet, Serge
2008-11-01
The magnetic Rayleigh-Taylor instability (MRTI) is investigated in the case of compressible plasmas. The goal of this work is highlighting the influence of both the magnetic field and the compressibility of the material on the growth rate of the Rayleigh-Taylor instability, compared to the classical growth rate derived for incompressible fluids. Our analytical linear models are derived in the framework of the ideal magnetohydrodynamics theory. Three general dispersion relations are obtained: (1) Two for stratified fluids, including compressible (denoted CS∥ when the wave vector k is parallel to the equilibrium magnetic field B0 and CS⊥ when k ⊥B0) and incompressible (denoted IS∥ and IS⊥) and (2) one for incompressible uniform density fluids, including finite mass (denoted Ifm) and infinite (denoted IU). For k ⊥B0, Ifm, IU, and IS⊥ are unmagnetized cases. Comparisons of those various configurations are performed and several differences are pointed out. The main results are as follows: Stratification weakens the MRTI while compressibility has a destabilizing effect. The magnetic field enhances these phenomena. The CS∥ and IU configurations have an identical cutoff wave number. The upper fluid (also called heavy fluid) is more sensitive to compressibility than the light one when k ∥B0. Finally, the CS∥ case is more sensitive than the CS⊥ one to physical variations.
Bennet, Euan; Mahony, Charles M. O.; Potts, Hugh E.; Everest, Paul; Rutherford, David; Askari, Sadegh; Kelsey, Colin; Perez-Martin, Fatima; Hamilton, Neil; McDowell, David A.; Mariotti, Davide; Maguire, Paul; Diver, Declan A.
2015-09-01
In this paper we describe a novel method for delivering a precise, known amount of electric charge to a micron-sized solid target. Aerosolised microparticles passed through a plasma discharge will acquire significant electric charge. The fluid stability under evaporative stress is a key aspect that is core to the research. Initially stable charged aerosols subject to evaporation (i.e. a continually changing radius) may encounter the Rayleigh stability limit. This limit arises from the electrostatic and surface tension forces and determines the maximum charge a stable droplet can retain, as a function of radius. We demonstrate that even if the droplet charge is initially much less than the Rayleigh limit, the stability limit will be encountered as the droplet evaporates. The instability emission mechanism is strongly linked to the final charge deposited on the target, providing a mechanism that can be used to ensure a predictable charge deposit on a known encapsulated microparticle. The authors gratefully acknowledge support from EPSRC via Grant Numbers EP/K006142/1 and EP/K006088/1.
Chaudhuri, Joydip; Timung, Seim; Dandamudi, Chola Bhargava; Mandal, Tapas Kumar; Bandyopadhyay, Dipankar
2017-01-01
Numerical simulations supplemented by experiments together uncovered that strategic integration of discrete electric fields in a non-invasive manner could substantially miniaturize the droplets into smaller parts in a pressure driven oil-water flow inside microchannels. The Maxwell's stress generated from the electric field at the oil-water interface could deform, stretch, neck, pin, and disintegrate a droplet into many miniaturized daughter droplets, which eventually ushered a one-step method to form water-in-oil microemulsion employing microchannels. The interplay between electrostatic, inertial, capillary, and viscous forces led to various pathways of droplet breaking, namely, fission, cascade, or Rayleigh modes. While a localized electric field in the fission mode could split a droplet into a number of daughter droplets of smaller size, the cascade or the Rayleigh mode led to the formation of an array of miniaturized droplets when multiple electrodes generating different field intensities were ingeniously assembled around the microchannel. The droplets size and frequency could be tuned by varying the field intensity, channel diameter, electrode locations, interfacial tension, and flow ratio. The proposed methodology shows a simple methodology to transform a microdroplet into an array of miniaturized ones inside a straight microchannel for enhanced mass, energy, and momentum transfer, and higher throughput. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
A molecular Rayleigh scattering setup to measure density fluctuations in thermal boundary layers
Panda, J.
2016-12-01
A Rayleigh scattering-based density fluctuation measurement system was set up inside a low-speed wind tunnel of NASA Ames Research Center. The immediate goal was to study the thermal boundary layer on a heated flat plate. A large number of obstacles had to be overcome to set up the system, such as the removal of dust particles using air filters, the use of photoelectron counting electronics to measure low intensity light, an optical layout to minimize stray light contamination, the reduction in tunnel vibration, and an expanded calibration process to relate photoelectron arrival rate to air density close to the plate surface. To measure spectra of turbulent density fluctuations, a two-PMT cross-correlation system was used to minimize the shot noise floor. To validate the Rayleigh measurements, temperature fluctuations spectra were calculated from density spectra and then compared with temperature spectra measured with a cold-wire probe operated in constant current mode. The spectra from the downstream half of the plate were found to be in good agreement with cold-wire probe, whereas spectra from the leading edge differed. Various lessons learnt are discussed. It is believed that the present effort is the first measurement of density fluctuations spectra in a boundary layer flow.
Three-Dimensional Single-Mode Nonlinear Ablative Rayleigh-Taylor Instability
Yan, R.; Betti, R.; Sanz, J.; Liu, B.; Frank, A.
2015-11-01
The nonlinear evolution of the ablative Rayleigh-Taylor (ART) instability is studied in three dimensions for conditions relevant to inertial confinement fusion targets. The simulations are performed using our newly developed code ART3D and an astrophysical code AstroBEAR. The laser ablation can suppress the growth of the short-wavelength modes in the linear phase but may enhance their growth in the nonlinear phase because of the vortex-acceleration mechanism. As the mode wavelength approaches the cutoff of the linear spectrum (short-wavelength modes), it is found that the bubble velocity grows faster than predicted in the classical 3-D theory. When compared to 2-D results, 3-D short-wavelength bubbles grow faster and do not reach saturation. The unbounded 3-D bubble acceleration is driven by the unbounded accumulation of vorticity inside the bubble. The vorticity is transferred by mass ablation from the Rayleigh-Taylor spikes into the ablated plasma filling the bubble volume. A density plateau is observed inside a nonlinear ART bubble and the plateau density is higher for shorter-wavelength modes. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.
Amelioration of experimental autoimmune uveitis by leflunomide in Lewis rats.
Cheng-bo Fang
Full Text Available PURPOSE: To investigate the efficacy of leflunomide in experimental autoimmune uveitis (EAU in rats. METHODS: Lewis rats were immunized with interphotoreceptor retinoid-binding peptide (IRBP in order to generate EAU. Rats received three dose of leflunomide through intragastric administration (prevention or treatment protocols after immunization at three separate doses (3 mg/kg/d; 6 mg/kg/d; 12 mg/kg/d. Cyclosporin A was administered as a positive control. Rats were euthanized during peak disease activity (day 14 or 15. Treatment effectiveness was evaluated in vivo using clinical EAU scoring (d14 and histopathological evaluation of enucleated eyes after experimental termination. The expression levels of inflammatory cytokines in the serum were quantified by ELISA. Eyeball of rats were harvested and mRNA expression of interleukin 17 (IL17 and IFN-γ were quantified through RT-PCR. Intracellular expression of interleukin (IL-17 in the activated CD4(+ T cells was assessed by flow cytometry. The effects of leflunomide inhibition on immune responses in rats were investigated in isolated lymphocytes. RESULTS: Histopathological and clinical data revealed severe intraocular inflammation in the immunized rat. Inflammation reached its peak on day 14 in this EAU model. Treatment with leflunomide significantly prevented and treated EAU-induced ocular inflammation and decreased clinical and pathological scores compared to vehicle-treated eyes. Gene expression of IL17 and IFN-γ was markedly reduced in leflunomide-treated eyes. Leflunomide significantly decreased the serum levels of IL17 and IFN-γ. The study of IL17+ T cells in peripheral blood and spleen by flow cytometry showed a decreased number of Th17 cell in rats of leflunomide prevented group. Lymphocytes from animals treated with leflunomide had decreased antigen-specific proliferation in vitro compared with lymphocytes from untreated animals. CONCLUSIONS: Oral administration of leflunomide
Fugle og andre observationer på Lewis og Harris
Provencal, Philippe
2017-01-01
En beskrivelse af observationer af især fugle men også nogle få pattedyr på øen Lewis and Harris i de Ydre Hebrider. Observationerne fandt sted fra den 19. til den 23- april 2017.......En beskrivelse af observationer af især fugle men også nogle få pattedyr på øen Lewis and Harris i de Ydre Hebrider. Observationerne fandt sted fra den 19. til den 23- april 2017....
Gear and Transmission Research at NASA Lewis Research Center
Townsend, Dennis P.
1997-01-01
This paper is a review of some of the research work of the NASA Lewis Research Center Mechanical Components Branch. It includes a brief review of the NASA Lewis Research Center and the Mechanical Components Branch. The research topics discussed are crack propagation of gear teeth, gear noise of spiral bevel and other gears, design optimization methods, methods we have investigated for transmission diagnostics, the analytical and experimental study of gear thermal conditions, the analytical and experimental study of split torque systems, the evaluation of several new advanced gear steels and transmission lubricants and the evaluation of various aircraft transmissions. The area of research needs for gearing and transmissions is also discussed.
Comparison of two- and three-dimensional simulations of miscible Rayleigh-Taylor instability
Cabot, W
2006-02-23
A comparison of two-dimensional and three-dimensional high-resolution numerical large-eddy simulations of planar, miscible Rayleigh-Taylor instability flows are presented. The resolution of the three-dimensional simulation is sufficient to attain a fully turbulent state. A number of different statistics from the mixing region (e.g., growth rates, PDFs, mixedness measures, and spectra) are used to demonstrate that two-dimensional flow simulations differ substantially from the three-dimensional one. It is found that the two-dimensional flow grows more quickly than its three-dimensional counterpart at late times, develops larger structures, and is much less well mixed. These findings are consistent with the concept of inverse cascade in two-dimensional flow, as well as the influence of a reduced effective Atwood number on miscible flow.
Metzler, Adam M; Siegmann, William L; Collins, Michael D
2012-02-01
The parabolic equation method with a single-scattering correction allows for accurate modeling of range-dependent environments in elastic layered media. For problems with large contrasts, accuracy and efficiency are gained by subdividing vertical interfaces into a series of two or more single-scattering problems. This approach generates several computational parameters, such as the number of interface slices, an iteration convergence parameter τ, and the number of iterations n for convergence. Using a narrow-angle approximation, the choices of n=1 and τ=2 give accurate solutions. Analogous results from the narrow-angle approximation extend to environments with larger variations when slices are used as needed at vertical interfaces. The approach is applied to a generic ocean waveguide that includes the generation of a Rayleigh interface wave. Results are presented in both frequency and time domains.
Performance of equal gain combining with quantized phases in rayleigh fading channels
Rizvi, Umar H.
2011-01-01
In this paper, we analyze the error probability of equal gain combining with quantized channel phase compensation for binary phase shift keying signalling over Rayleigh fading channels. The probability density and characteristic functions of the combined signal amplitude are derived and used to compute the analytic expressions for the bit error probability in dependance of the number of quantization levels L, the number of diversity branches N-R and the average received signal-to-noise ratio. The analysis is utilized to outline the trade-off between N-R and L and to compare the performance with non-coherent binary frequency shift keying and differential binary phase shift keying schemes under diversity reception. © 2011 IEEE.
A Rayleigh-Brillouin scattering spectrometer for ultraviolet wavelengths
Gu, Ziyu; van Duijn, Eric-Jan; Ubachs, Wim; 10.1063/1.4721272
2012-01-01
A spectrometer for the measurement of spontaneous Rayleigh-Brillouin scattering line profiles at ultraviolet wavelengths from gas phase molecules has been developed, employing a high-power frequency-stabilized UV laser with narrow bandwidth (2 MHz). The UV light from a frequency-doubled titanium:sapphire laser is further amplified in an enhancement cavity, delivering a 5 Watt UV-beam propagating through the interaction region inside a scattering cell. The design of the RB-scattering cell allows for measurements at gas pressures in the range 0-4 bar and at stably controlled temperatures from -30 to 70 degree Celsius. A scannable Fabry-Perot analyzer with instrument resolution of 232 MHz probes the Rayleigh-Brillouin profiles. Measurements on N2 and SF6 gases demonstrate the high signal-to-noise ratio achievable with the instrument, at the 1% level at the peak amplitude of the scattering profile.
Theoretical Analysis of Rayleigh Backscattering Noise in Fiber Raman Amplifiers
无
2005-01-01
In this paper, a new theoretical model for Rayleigh backscattering (RB) analysis of fiber Raman amplifiers is proposed. The model includes all the interactions among the pumps, signals, and all orders of RB. The results show that the higher order RB has a negligible influence on the performance of the amplifier. The co-propagating and counterpropagating RB power of the signal grow quadratically with the net-gain of the amplifier. The signal to double Rayleigh backscattering noise ratio (OSNRDRB ) of backward-pumped FRAs is better than that of the forward-pumped ones at high net-gain level (＞ 13 dB), while at low net-gain level the OSNRDrb of the forward-pumped FRAs is slightly better than that of the backward-pumped ones.
Polarized Rayleigh back-scattering from individual semiconductor nanowires
Zhang Duming; Wu Jian; Lu Qiujie; Gutierrez, Humberto R; Eklund, Peter C, E-mail: hur3@psu.edu [Department of Physics, Pennsylvania State University, University Park, PA 16802 (United States)
2010-08-06
A complete understanding of the interaction between electromagnetic radiation and semiconductor nanowires (NWs) is required in order to further develop a new generation of opto-electronic and photonic devices based on these nanosystems. The reduced dimensionality and high aspect ratio of nanofilaments can induce strong polarization dependence of the light absorption, emission and scattering, leading in some cases to the observation of optical antenna effects. In this work we present the first systematic study of polarized Rayleigh back-scattering from individual crystalline semiconductor NWs with known crystalline structure, orientation and diameters. To explain our experimental Rayleigh polar patterns, we propose a simple theory that relies on a secondary calculation of the volume-averaged internal electromagnetic fields inside the NW. These results revealed that the internal and emitted field can be enhanced depending on the polarization with respect to the NW axis; we also show that this effect strongly depends on the NW diameter.
GENERALIZATION OF RAYLEIGH MAXIMUM LIKELIHOOD DESPECKLING FILTER USING QUADRILATERAL KERNELS
S. Sridevi
2013-02-01
Full Text Available Speckle noise is the most prevalent noise in clinical ultrasound images. It visibly looks like light and dark spots and deduce the pixel intensity as murkiest. Gazing at fetal ultrasound images, the impact of edge and local fine details are more palpable for obstetricians and gynecologists to carry out prenatal diagnosis of congenital heart disease. A robust despeckling filter has to be contrived to proficiently suppress speckle noise and simultaneously preserve the features. The proposed filter is the generalization of Rayleigh maximum likelihood filter by the exploitation of statistical tools as tuning parameters and use different shapes of quadrilateral kernels to estimate the noise free pixel from neighborhood. The performance of various filters namely Median, Kuwahura, Frost, Homogenous mask filter and Rayleigh maximum likelihood filter are compared with the proposed filter in terms PSNR and image profile. Comparatively the proposed filters surpass the conventional filters.
Seismic metasurfaces: Sub-wavelength resonators and Rayleigh wave interaction
Colquitt, D J; Craster, R V; Roux, P; Guenneau, S R L
2016-01-01
We consider the canonical problem of an array of rods, which act as resonators, placed on an elastic substrate; the substrate being either a thin elastic plate or an elastic half-space. In both cases the flexural plate, or Rayleigh surface, waves in the substrate interact with the resonators to create interesting effects such as effective band-gaps for surface waves or filters that transform surface waves into bulk waves; these effects have parallels in the field of optics where such sub-wavelength resonators create metamaterials, and metasurfaces, in the bulk and at the surface respectively. Here we carefully analyse this canonical problem by extracting the dispersion relations analytically thereby examining the influence of both the flexural and compressional resonances on the propagating wave. For an array of resonators atop an elastic half-space we augment the analysis with numerical simulations. Amongst other effects, we demonstrate the striking effect of a dispersion curve that transitions from Rayleigh...
Nonlinear mixing of laser generated narrowband Rayleigh surface waves
Bakre, Chaitanya; Rajagopal, Prabhu; Balasubramaniam, Krishnan
2017-02-01
This research presents the nonlinear mixing technique of two co-directionally travelling Rayleigh surface waves generated and detected using laser ultrasonics. The optical generation of Rayleigh waves on the specimen is obtained by shadow mask method. In conventional nonlinear measurements, the inherently small higher harmonics are greatly influenced by the nonlinearities caused by coupling variabilities and surface roughness between the transducer and specimen interface. The proposed technique is completely contactless and it should be possible to eliminate this problem. Moreover, the nonlinear mixing phenomenon yields not only the second harmonics, but also the sum and difference frequency components, which can be used to measure the acoustic nonlinearity of the specimen. In this paper, we will be addressing the experimental configurations for this technique. The proposed technique is validated experimentally on Aluminum 7075 alloy specimen.
Asymptotic Solution to the Rayleigh Problem of Dynamic Soaring
Bousquet, Gabriel D; Slotine, Jean-Jacques E
2015-01-01
It is believed that albatrosses power their flight through dynamic soaring, a technique where energy is extracted from horizontally blowing shear winds. The Rayleigh model of dynamic soaring, also called the two layer model, makes a 2-dimensional approximation of the wind field and glider trajectory. This note considers the "Rayleigh problem" of finding the minimum wind necessary for the existence of energy neutral gliding cycles. We utilize a 3-degree of freedom glider model with quadratic drag. Asymptotic solutions in the limit of large glide ratios are obtained. The optimal motion is a traveling trajectory constituted of a succession of small partial turns. It is over 50% more efficient at preserving airspeed than full half-turn based trajectories.
Suppression of Rayleigh-scattering-induced noise in OEOs.
Okusaga, Olukayode; Cahill, James P; Docherty, Andrew; Menyuk, Curtis R; Zhou, Weimin; Carter, Gary M
2013-09-23
Optoelectronic oscillators (OEOs) are hybrid RF-photonic devices that promise to be environmentally robust high-frequency RF sources with very low phase noise. Previously, we showed that Rayleigh-scattering-induced noise in optical fibers coupled with amplitude-to-phase noise conversion in photodetectors and amplifiers leads to fiber-length-dependent noise in OEOs. In this work, we report on two methods for the suppression of this fiber-length-dependent noise: altering the amplitude-dependent phase delay of the OEO loops and suppressing the Rayleigh-scattering-induced noise in optical fibers. We report a 20 dB reduction in the flicker phase noise of a 6 km OEO via these suppression techniques.
Clark, Ewan R; Ingleson, Michael J
2014-10-13
N-methylacridinium salts are Lewis acids with high hydride ion affinity but low oxophilicity. The cation forms a Lewis adduct with 4-(N,N-dimethylamino)pyridine but a frustrated Lewis pair (FLP) with the weaker base 2,6-lutidine which activates H2, even in the presence of H2O. Anion effects dominate reactivity, with both solubility and rate of H2 cleavage showing marked anion dependency. With the optimal anion, a N-methylacridinium salt catalyzes the reductive transfer hydrogenation and hydrosilylation of aldimines through amine-boranes and silanes, respectively. Furthermore, the same salt is active for the catalytic dehydrosilylation of alcohols (primary, secondary, tertiary, and ArOH) by silanes with no observable over-reduction to the alkanes. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fast sampling model for X-ray Rayleigh scattering
Grichine, V M
2013-01-01
A simple model for X-ray Rayleigh scattering is discussed in terms of the process total cross-section and the angular distribution of scattered X-ray photons. Comparisons with other calculations and experimental data are presented. The model is optimized for the simulation of X-ray tracking inside experimental setups with complex geometry where performance and memory volume are issues to be optimized. (C) 2013 Elsevier B.V. All rights reserved.
Rayleigh-Ritz variation method and connected-moments expansions
Amore, Paolo [Facultad de Ciencias, Universidad de Colima, Bernal DIaz del Castillo 340, Colima (Mexico); Fernandez, Francisco M [INIFTA (UNLP, CCT La Plata-CONICET), Division Quimica Teorica, Blvd 113 S/N, Sucursal 4, Casilla de Correo 16, 1900 La Plata (Argentina)], E-mail: fernande@quimica.unlp.edu.ar
2009-11-15
We compare the connected-moments expansion (CMX) with the Rayleigh-Ritz variational method in the Krylov space (RRK). As a benchmark model we choose the same two-dimensional anharmonic oscillator already treated earlier by means of the CMX. Our results show that the RRK converges more smoothly than the CMX. We also discuss the fact that the CMX is size consistent while the RRK is not.
Parametrics Resonances of a Forced Modified Rayleigh-Duffing Oscillator
Miwadinou, C H; Chabi, J B
2013-01-01
We investigate in this paper the superharmonic and subharmonic resonances of forced modified Rayleigh-Duffing oscillator. We analyse this equation by method of multiple scales and we obtain superharmonic and subharmonic resonances order-two and order-three. We obtain also regions where steady-state subharmonic responses exist. Finally, we use the amplitude-frequency curve for demonstrate the effect of various parameters on the response of the system.
Size Determination of Argon Clusters from a Rayleigh Scattering Experiment
LEI An-Le; ZHAI Hua-Jin; LIU Bing-Chen; LI Zhong; NI Guo-Yuan; XU Zhi-Zhan
2000-01-01
Argon clusters are produced in the process of adiabatic expansion of a high backing pressure gas into vacuum through a nozzle. The cluster size is determined by a Rayleigh scattering measurement. The scattered signal measured is proportional to the 2.78th power of gas stagnation pressure. The average cluster sizes vary from 100 to more than 12000 atoms/cluster with the argon gas backing pressures ranging between 3 to 45 atm.
Statistically steady measurements of Rayleigh-Taylor mixing in a gas channel
Banerjee, Arindam
A novel gas channel experiment was constructed to study the development of high Atwood number Rayleigh-Taylor mixing. Two gas streams, one containing air and the other containing helium-air mixture, flow parallel to each other separated by a thin splitter plate. The streams meet at the end of a splitter plate leading to the formation of an unstable interface and of buoyancy driven mixing. This buoyancy driven mixing experiment allows for long data collection times, short transients and was statistically steady. The facility was designed to be capable of large Atwood number studies of At ˜ 0.75. We describe work to measure the self similar evolution of mixing at density differences corresponding to 0.035 hot-wire anemometer, and high resolution digital image analysis. The hot-wire probe gives velocity, density and velocity-density statistics of the mixing layer. Two different multi-position single-wire techniques were used to measure the velocity fluctuations in three mutually perpendicular directions. Analysis of the measured data was used to explain the mixing as it develops to a self-similar regime in this flow. These measurements are to our knowledge, the first use of hot-wire anemometry in the Rayleigh-Taylor community. Since the measurement involved extensive calibration of the probes in a binary gas mixture of air and helium, a new convective heat transfer correlation was formulated to account for variable-density low Reynolds number flows past a heated cylinder. In addition to the hot-wire measurements, a digital image analysis procedure was used to characterize various properties of the flow and also to validate the hot-wire measurements. A test of statistical convergence was performed and the study revealed that the statistical convergence was a direct consequence of the number of different large three-dimensional structures that were averaged over the duration of the run.
Leakage predictions for Rayleigh-step, helium-purge seals
Proctor, Margaret P.
1988-01-01
Rayleigh-step, helium purge, annular shaft seals, studied for use in liquid oxygen turbopumps, generate a hydrodynamic force that enables the seal to follow shaft perturbations. Hence, smaller clearances can be used to reduce seal leakage. FLOWCAL, a computer code developed by Mechanical Technology Incorporated, predicts gas flow rate through an annular seal with an axial pressure gradient. Analysis of a 50-mm Rayleigh-step, helium-purge, annular seal showed the flow rate increased axial pressure gradient, downstream pressure, and eccentricity ratio. Increased inlet temperature reduced leakage. Predictions made at maximum and minimum clearances (due to centrifugal and thermal growths, machining tolerances and + or - 2 percent uncertainty in the clearance measurement) placed wide boundaries on expected flow rates. The widest boundaries were set by thermal growth conditions. Predicted flow rates for a 50-mm Rayleigh-step, helium-purge, annular seal underestimated measured flow rates by three to seven times. However, the analysis did accurately predict flow rates for choked gas flow through annular seals when compared to flow rates measured in two other independent studies.
Guest-responsive function of a dynamic metal-organic framework with a π Lewis acidic pore surface.
Joarder, Biplab; Mukherjee, Soumya; Chaudhari, Abhijeet K; Desai, Aamod V; Manna, Biplab; Ghosh, Sujit K
2014-11-17
A 3D dynamic coordination framework with an electron-deficient pore surface has been synthesized by using Zn(II) (having a variable coordination number) and a predesigned flexible π-electron-deficient core-based ligand, exhibiting chemical separations based on pore surface functionalization (π Lewis acidic pore surfaces and open metal sites) and framework flexibility, giving rise to a unique smart guest-responsive material.
Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch
Parker, Christian Richard; Tortzen, Christian Gregers; Broman, Søren Lindbæk
2011-01-01
Mild Lewis acids enhance the rate of the thermal conversion of vinylheptafulvene (VHF) to dihydroazulene (DHA). In the absence of light, stronger Lewis acids promote the otherwise photoinduced DHA to VHF conversion.......Mild Lewis acids enhance the rate of the thermal conversion of vinylheptafulvene (VHF) to dihydroazulene (DHA). In the absence of light, stronger Lewis acids promote the otherwise photoinduced DHA to VHF conversion....
G. Baumgarten
2010-11-01
Full Text Available A direct detection Doppler lidar for measuring wind speed in the middle atmosphere up to 80 km with 2 h resolution was implemented in the ALOMAR Rayleigh/Mie/Raman lidar (69° N, 16° E. The random error of the line of sight wind is about 0.6 m/s and 10 m/s at 49 km and 80 km, respectively. We use a Doppler Rayleigh Iodine Spectrometer (DoRIS at the iodine line 1109 (~532.260 nm. DoRIS uses two branches of intensity cascaded channels to cover the dynamic range from 10 to 100 km altitude. The wind detection system was designed to extend the existing multi-wavelength observations of aerosol and temperature performed at wavelengths of 355 nm, 532 nm and 1064 nm. The lidar uses two lasers with a mean power of 14 W at 532 nm each and two 1.8 m diameter tiltable telescopes. Below about 49 km altitude the accuracy and time resolution is limited by the maximum count rate of the detectors used and not by the number of photons available. We report about the first simultaneous Rayleigh temperature and wind measurements by lidar in the strato- and mesosphere on 17 and 23 January 2009.
Analysis of group-velocity dispersion of high-frequency Rayleigh waves for near-surface applications
Luo, Y.; Xia, J.; Xu, Y.; Zeng, C.
2011-01-01
The Multichannel Analysis of Surface Waves (MASW) method is an efficient tool to obtain the vertical shear (S)-wave velocity profile using the dispersive characteristic of Rayleigh waves. Most MASW researchers mainly apply Rayleigh-wave phase-velocity dispersion for S-wave velocity estimation with a few exceptions applying Rayleigh-wave group-velocity dispersion. Herein, we first compare sensitivities of fundamental surface-wave phase velocities with group velocities with three four-layer models including a low-velocity layer or a high-velocity layer. Then synthetic data are simulated by a finite difference method. Images of group-velocity dispersive energy of the synthetic data are generated using the Multiple Filter Analysis (MFA) method. Finally we invert a high-frequency surface-wave group-velocity dispersion curve of a real-world example. Results demonstrate that (1) the sensitivities of group velocities are higher than those of phase velocities and usable frequency ranges are wider than that of phase velocities, which is very helpful in improving inversion stability because for a stable inversion system, small changes in phase velocities do not result in a large fluctuation in inverted S-wave velocities; (2) group-velocity dispersive energy can be measured using single-trace data if Rayleigh-wave fundamental-mode energy is dominant, which suggests that the number of shots required in data acquisition can be dramatically reduced and the horizontal resolution can be greatly improved using analysis of group-velocity dispersion; and (3) the suspension logging results of the real-world example demonstrate that inversion of group velocities generated by the MFA method can successfully estimate near-surface S-wave velocities. ?? 2011 Elsevier B.V.
Afsar Ali; Amit P Singh; Rajeev Gupta
2010-05-01
This paper presents the recent developments in designing multi-component structures including metal-organic frameworks containing Lewis acidic metal ions. The emphasis has been given to understand the design elements adopted to synthesize such structures bearing Lewis acidic metal ion. Further, few important Lewis acidic metal catalysed organic transformation reactions have been discussed demonstrating the importance of such materials for practical purposes.
File list: Unc.Lng.50.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Unc.Lng.50.AllAg.Carcinoma,_Lewis_Lung mm9 Unclassified Lung Carcinoma, Lewis Lung ...http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Unc.Lng.50.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: Pol.Lng.05.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Pol.Lng.05.AllAg.Carcinoma,_Lewis_Lung mm9 RNA polymerase Lung Carcinoma, Lewis Lun...g http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Pol.Lng.05.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: Oth.Lng.20.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Oth.Lng.20.AllAg.Carcinoma,_Lewis_Lung mm9 TFs and others Lung Carcinoma, Lewis Lun...g http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.Lng.20.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: Unc.Lng.10.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Unc.Lng.10.AllAg.Carcinoma,_Lewis_Lung mm9 Unclassified Lung Carcinoma, Lewis Lung ...http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Unc.Lng.10.AllAg.Carcinoma,_Lewis_Lung.bed ...
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File list: His.Lng.20.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
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File list: DNS.Lng.50.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available DNS.Lng.50.AllAg.Carcinoma,_Lewis_Lung mm9 DNase-seq Lung Carcinoma, Lewis Lung htt...p://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/DNS.Lng.50.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: His.Lng.10.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
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File list: Pol.Lng.50.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Pol.Lng.50.AllAg.Carcinoma,_Lewis_Lung mm9 RNA polymerase Lung Carcinoma, Lewis Lun...g http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Pol.Lng.50.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: Pol.Lng.20.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
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File list: Oth.Lng.10.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Oth.Lng.10.AllAg.Carcinoma,_Lewis_Lung mm9 TFs and others Lung Carcinoma, Lewis Lun...g http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.Lng.10.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: DNS.Lng.20.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available DNS.Lng.20.AllAg.Carcinoma,_Lewis_Lung mm9 DNase-seq Lung Carcinoma, Lewis Lung htt...p://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/DNS.Lng.20.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: His.Lng.05.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
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File list: Oth.Lng.05.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Oth.Lng.05.AllAg.Carcinoma,_Lewis_Lung mm9 TFs and others Lung Carcinoma, Lewis Lun...g http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.Lng.05.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: Unc.Lng.20.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
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File list: Pol.Lng.10.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Pol.Lng.10.AllAg.Carcinoma,_Lewis_Lung mm9 RNA polymerase Lung Carcinoma, Lewis Lun...g http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Pol.Lng.10.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: DNS.Lng.10.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available DNS.Lng.10.AllAg.Carcinoma,_Lewis_Lung mm9 DNase-seq Lung Carcinoma, Lewis Lung htt...p://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/DNS.Lng.10.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: His.Lng.50.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available His.Lng.50.AllAg.Carcinoma,_Lewis_Lung mm9 Histone Lung Carcinoma, Lewis Lung SRX10...91778,SRX1091782,SRX1091784,SRX1091780,SRX1091781,SRX1091785,SRX1091779,SRX1091783 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/His.Lng.50.AllAg.Carcinoma,_Lewis_Lung.bed ...
File list: Oth.Lng.50.AllAg.Carcinoma,_Lewis_Lung [Chip-atlas[Archive
Full Text Available Oth.Lng.50.AllAg.Carcinoma,_Lewis_Lung mm9 TFs and others Lung Carcinoma, Lewis Lun...g http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.Lng.50.AllAg.Carcinoma,_Lewis_Lung.bed ...
Frustrated Lewis pairs-assisted reduction of carbonyl compounds
Marek, Ales; Pedersen, Martin Holst Friborg
2015-01-01
An alternative and robust method for the reduction of carbonyl groups by frustrated Lewis pairs (FLPs) is reported in this paper. With its very mild reaction conditions, good to excellent yields, absolute regioselectivity and the non-metallic character of the reagent, it provides an excellent too...
Probability without certainty : foundationalism and the Lewis-Reichenbach debate
Atkinson, David; Peijnenburg, Jeanne
2006-01-01
Like many discussions on the pros and cons of epistemic foundationalism, the debate between C. I. Lewis and H. Reichenbach dealt with three concerns: the existence of basic beliefs, their nature, and the way in which beliefs are related. In this paper we concentrate on the third matter, especially o
Daniel Day-Lewis - veri peab voolama / Kristiina Davidjants
Davidjants, Kristiina, 1974-
2008-01-01
Iiri-juudi näitleja Daniel Day-Lewis, kes võitis oma rolliga P.T. Andersoni filmis "Veri hakkab voolama" parima meespeaosatäitja Oscari. Tema põhjalikust tööst rollidega läbi tema filmiloomingu
Impact of Predatory Threat on Fear Extinction in Lewis Rats
Goswami, Sonal; Cascardi, Michele; Rodriguez-Sierra, Olga E.; Duvarci, Sevil; Pare, Denis
2010-01-01
Humans with post-traumatic stress disorder (PTSD) are deficient at extinguishing conditioned fear responses. A study of identical twins concluded that this extinction deficit does not predate trauma but develops as a result of trauma. The present study tested whether the Lewis rat model of PTSD reproduces these features of the human syndrome.…
Californian Genius: Lewis Terman's Gifted Child in Regional Perspective
Beauvais, Clémentine
2016-01-01
This article pays attention to the regional embeddedness of early research on giftedness, looking principally at the works of Lewis Terman and his peers, between the 1910s and 1930s. The rhetoric, ideology, and aesthetics of giftedness in those early works were, I argue, stamped by the context and imaginary of Progressive-Era California and shaped…
Telling Lewis Hine's Story: Russell Freedman's "Kids at Work."
Zarnowski, Myra
In "Kids at Work," Russell Freedman explores the world of child labor during the years 1908-1918 when Lewis Hine, "teacher-crusader," worked as an investigative photographer for the National Child Labor Committee (NCLC). Hine's writing and the photos he gathered from across the country revealed a "shocking reality that…
Californian Genius: Lewis Terman's Gifted Child in Regional Perspective
Beauvais, Clémentine
2016-01-01
This article pays attention to the regional embeddedness of early research on giftedness, looking principally at the works of Lewis Terman and his peers, between the 1910s and 1930s. The rhetoric, ideology, and aesthetics of giftedness in those early works were, I argue, stamped by the context and imaginary of Progressive-Era California and shaped…
Modified NASA-Lewis Chemical Equilibrium Code for MHD applications
Sacks, R. A.; Geyer, H. K.; Grammel, S. J.; Doss, E. D.
1979-12-01
A substantially modified version of the NASA-Lewis Chemical Equilibrium Code has recently been developed. The modifications were designed to extend the power and convenience of the Code as a tool for performing combustor analysis for MHD systems studies. This report describes the effect of the programming details from a user point of view, but does not describe the Code in detail.
Probability without certainty : foundationalism and the Lewis-Reichenbach debate
Atkinson, David; Peijnenburg, Jeanne
Like many discussions on the pros and cons of epistemic foundationalism, the debate between C. I. Lewis and H. Reichenbach dealt with three concerns: the existence of basic beliefs, their nature, and the way in which beliefs are related. In this paper we concentrate on the third matter, especially
Daniel Day-Lewis - veri peab voolama / Kristiina Davidjants
Davidjants, Kristiina, 1974-
2008-01-01
Iiri-juudi näitleja Daniel Day-Lewis, kes võitis oma rolliga P.T. Andersoni filmis "Veri hakkab voolama" parima meespeaosatäitja Oscari. Tema põhjalikust tööst rollidega läbi tema filmiloomingu
Tribute to Erwin Felix Lewy-Bertaut; Hommage a Erwin Felix Lewy-Bertaut
NONE
2006-07-01
Erwin Lewy (alias Felix Bertaut) was born in 1913 in Germany, he emigrated to France where he undertook graduate studies in chemistry. Then, he joined the powder central laboratory where he learnt how to use international tables for structure determination. His thesis work was the X-ray study of the statistical distribution of the size of iron grains. The method Bertaut developed is still a reference in powder granulometry. Bertaut was also interested in the nascent neutron diffraction method and he flew to the United-States to improve his knowledge on this topic. Felix Bertaut created the neutron diffraction laboratory in the atomic research center in Grenoble and later he headed the CNRS' crystallography laboratory till 1982. Felix Bertaut and his laboratories became internationally renowned in crystallography, neutron diffraction and magnetism. He favored the scientific cooperation between France and Germany that led to the creation of the Laue-Langevin Institute (ILL). The ILL became European and was a key partner for building the European Synchrotron Facility (ESRF) in Grenoble. Bertaut was elected as a full member of the French Academy of Sciences in 1979, he died in 2003. (A.C.)
LRRK2 in Parkinson's disease and dementia with Lewy bodies
Zhu Xiongwei
2006-11-01
Full Text Available Abstract Background Mutations in LRRK2 encoding leucine-rich repeat kinase 2 are thus far the most frequent genetic cause associated with autosomal dominant and idiopathic Parkinson's disease (PD. To examine whether LRRK2 is directly associated with neuropathology of PD and other related disorders, we analyzed LRRK2 in brains of patients affected by PD and dementia with Lewy bodies (DLB using highly specific antibodies to LRRK2. Results We demonstrated that anti-LRRK2 antibodies strongly labelled brainstem and cortical Lewy bodies, the pathological hallmarks of PD and DLB, respectively. In addition, anti-LRRK2 also labelled brain vasculature, axons, and neuronal cell bodies. Interestingly, the immunocytochemical profile of LRRK2 varied with different antibodies depending upon specific antigenic sites along the LRRK2 protein. All anti-LRRK2 antibodies tested that were raised against various regions of LRRK2, were found to be immunoreactive to recombinant LRRK2 on Western blots. However, only the antibodies raised against the N-terminal and C-terminal regions of LRRK2, but not the regions containing folded protein domains, were positive in immunolabeling of Lewy bodies, suggesting a differential exposure of specific antigenic sites of LRRK2 on tissue sections. Conclusion We conclude that LRRK2 is a component of Lewy bodies in both PD and DLB, and therefore plays an important role in the Lewy body formation and disease pathogenesis. Information on the cellular localization of LRRK2 under normal and pathological conditions will deepen our understanding of its functions and molecular pathways relevant to the progression of PD and related disorders.
Comentarios sobre dos ensayos de sir Arthur Lewis
Currie Lauchlin
1999-06-01
Full Text Available
Es un texto inédito del Profesor Lauchlin Currie, escrito en 1980 cuando todavía ocupaba su oficina en el Departamento Nacional de Planeación, En lo esencial, se trata de una crítica de algunos argumentos expuestos por Lewis en su breve libro
The Evolution of the International Economic Order, publicado en inglés en 1978 y dos años más tarde en castellano por el Colegio de México. El problema central de este libro es el de por qué algunos países son ricos y otros son pobres. La respuesta de Lewis no dejó satisfecho al profesor Currie. A lo largo de este comentario, se observa un contrapunteo entre dos enfoques teóricos de la economía del desarrollo: la de Lewis -inicialmente expuesta en su celebre artículo sobre el desarrollo económico con oferta ilimitada de trabajo-que enfatiza la necesidad de generar un excedente agrícola como punto de partida del proceso; y la de Currie, que señala la posibilidad del crecimiento desequlibrado liderado por la actividad económica urbana, específicamente por el sector de la construcción. Aunque el profesor Currie destaca sus diferencias con Lewis, las conclusiones de ambos autores tienden a converger en torno de un punto que se resume en una frase del ensayo de Lewis, no citada en el comentario: "El motor del crecimiento debe ser el cambio tecnológico, y el comercio internacional debe servir como lubricante y no como combustible". Como bien señala el profesor Currie en su análisis, a la larga es irrelevante cuál sea el sector donde se presente ese cambio tecnológico.
Two-dimensional temperature determination in sooting flames by filtered Rayleigh scattering
Hoffman, D.; Münch, K.-U.; Leipertz, A.
1996-04-01
We present what to our knowledge are the first filtered Rayleigh scattering temperature measurements and use them in sooting flame. This new technique for two-dimensional thermography in gas combustion overcomes some of the major disadvantages of the standard Rayleigh technique. It suppresses scattered background light from walls or windows and permits detection of two-dimensional Rayleigh intensity distributions of the gas phase in the presence of small particles by spectral filtering of the scattered light.
Analysis of Solidification in the Presence of High Rayleigh Number Convection in an Enclosure
无
1994-01-01
A simple and convenient analysis of the process of time-dependent solidification in an enclosed liquid cooled from the side in the presence of natural convection is presented.the influence of each parameter on the process of solidification is carried out systematically,The accuracy of this model is justified by comparing its predicting values with the previous results.
The Spectral Amplitude of Stellar Convection and its Scaling in the High-Rayleigh-Number Regime
Featherstone, Nicholas A
2015-01-01
Convection plays a central role in the dynamics of any stellar interior, and yet its operation remains largely-hidden from direct observation. As a result, much of our understanding concerning stellar convection necessarily derives from theoretical and computational models. The Sun is, however, exceptional in that regard. The wealth of observational data afforded by its proximity provides a unique testbed for comparing convection models against observations. When such comparisons are carried out, surprising inconsistencies between those models and observations become apparent. Both photospheric and helioseismic measurements suggest that convection simulations may overestimate convective flow speeds on large spatial scales. Moreover, many solar convection simulations have difficulty reproducing the observed solar differential rotation due to this apparent overestimation. We present a series of 3-dimensional (3-D) stellar convection simulations designed to examine how the amplitude and spectral distribution of ...
Nödling, Alexander R; Möckel, Robert; Tonner, Ralf; Hilt, Gerhard
2016-09-05
The effect of several Lewis acids on the CBS catalyst (named after Corey, Bakshi and Shibata) was investigated in this study. While (2) H NMR spectroscopic measurements served as gauge for the activation capability of the Lewis acids, in situ FT-IR spectroscopy was employed to assess the catalytic activity of the Lewis acid oxazaborolidine complexes. A correlation was found between the Δδ((2) H) values and rate constants kDA , which indicates a direct translation of Lewis acidity into reactivity of the Lewis acid-CBS complexes. Unexpectedly, a significant deviation was found for SnCl4 as Lewis acid. The SnCl4 -CBS adduct was much more reactive than the Δδ((2) H) values predicted and gave similar reaction rates to those observed for the prominent AlBr3 -CBS adduct. To rationalize these results, quantum mechanical calculations were performed. The frontier molecular orbital approach was applied and a good correlation between the LUMO energies of the Lewis acid-CBS-naphthoquinone adducts and kDA could be found. For the SnCl4 -CBS-naphthoquinone adduct an unusual distortion was observed leading to an enhanced Lewis acidity. Energy decomposition analysis with natural orbitals for chemical valence (EDA-NOCV) calculations revealed the relevant interactions and activation mode of SnCl4 as Lewis acid in Diels-Alder reactions. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Kulkarni, Akshay K
2008-01-01
We present results of 3D simulations of MHD instabilities at the accretion disk-magnetosphere boundary. The instability is Rayleigh-Taylor, and develops for a fairly broad range of accretion rates and stellar rotation rates and magnetic fields. It produces tall, thin tongues of plasma that penetrate the magnetosphere in the equatorial plane. The shape and number of the tongues changes with time on the inner-disk dynamical timescale. In contrast with funnel flows, which deposit matter mainly in the polar region, the tongues deposit matter much closer to the stellar equator. The instability appears for relatively small misalignment angles, $\\Theta\\lesssim30^\\circ$, between the star's rotation and magnetic axes, and is associated with higher accretion rates. The hot spots and light curves during accretion through instability are generally much more chaotic than during stable accretion. The unstable state of accretion has possible implications for quasi-periodic oscillations and intermittent pulsations from accre...
Kulkarni, Akshay K
2008-01-01
We present results of 3D simulations of MHD instabilities at the accretion disk-magnetosphere boundary. The instability is Rayleigh-Taylor, and develops for a fairly broad range of accretion rates and stellar rotation rates and magnetic fields. It manifests itself in the form of tall, thin tongues of plasma that penetrate the magnetosphere in the equatorial plane. The shape and number of the tongues changes with time on the inner-disk dynamical timescale. In contrast with funnel flows, which deposit matter mainly in the polar region, the tongues deposit matter much closer to the stellar equator. The instability appears for relatively small misalignment angles, $\\Theta\\lesssim30^\\circ$, between the star's rotation and magnetic axes, and is associated with higher accretion rates. The hot spots and light curves during accretion through instability are generally much more chaotic than during stable accretion. The unstable state of accretion has possible implications for quasi-periodic oscillations and intermitten...
Direct simulation Monte Carlo investigation of the Rayleigh-Taylor instability
Gallis, M. A.; Koehler, T. P.; Torczynski, J. R.; Plimpton, S. J.
2016-08-01
The Rayleigh-Taylor instability (RTI) is investigated using the direct simulation Monte Carlo (DSMC) method of molecular gas dynamics. Here, fully resolved two-dimensional DSMC RTI simulations are performed to quantify the growth of flat and single-mode perturbed interfaces between two atmospheric-pressure monatomic gases as a function of the Atwood number and the gravitational acceleration. The DSMC simulations reproduce many qualitative features of the growth of the mixing layer and are in reasonable quantitative agreement with theoretical and empirical models in the linear, nonlinear, and self-similar regimes. In some of the simulations at late times, the instability enters the self-similar regime, in agreement with experimental observations. For the conditions simulated, diffusion can influence the initial instability growth significantly.
Analysis and Simulation of CDMA QAM-16 for AWGN and RAYLEIGH Channel
Arun Kumar
2014-07-01
Full Text Available In a Code Division Multiple Access (CDMA system, a lot of users use concurrently the entire frequency band to transmit their data and users’ data is separated on the basis of their unique spreading code. The aim of Communication System i.e. Communication at anytime, anywhere and by anybody is still not fulfilled but the technology like CDMA can fulfill the aim of communication system if it is properly analyzed. For a downlink transmission Quadrature Amplitude Modulation (QAM, Quadrature Phase Shift Keying (QPSK and Binary Phase Shift Keying (BPSK modulation Techniques are considered in a Wideband Code Division Multiple Access System. The work design and evaluate CDMA Transmitter and Receiver for QAM-16 modulation Scheme and deal with BER performance of WCDMA, when the design is subjected to a number of users as well as noise and interference in the AWGN channel and Rayleigh Fading channel
The Rayleigh-Taylor instability of Newtonian and non-Newtonian fluids
Doludenko, A. N.; Fortova, S. V.; Son, E. E.
2016-10-01
Along with Newtonian fluids (for example, water), fluids with non-Newtonian rheology are widespread in nature and industry. The characteristic feature of a non-Newtonian fluid is the non-linear dependence between the shear stress and shear rate tensors. The form of this relation defines the types of non-Newtonian behavior: viscoplastic, pseudoplastic, dilatant and viscoelastic. The present work is devoted to the study of the Rayleigh-Taylor instability in pseudoplastic fluids. The main aim of the work is to undertake a direct three-dimensional numerical simulation of the mixing of two media with various rheologies and obtain the width of the mixing layer and the kinetic energy spectra, depending on the basic properties of the shear thinning liquids and the Atwood number. A theoretical study is carried out on the basis of the Navier-Stokes equation system for weakly compressible media.
Absolute scaling law for temperature data in Rayleigh-Benard convection
无
2009-01-01
In addition to the hierarchical-structure (H-S) model, this paper further explores the most intensive intermittent structure of Rayleigh-Bénard convection at the high Ra numbers proportional to temperature. With respect to the discovery and by means of the scale, both of Bolgiano, there are two regions of the structure holding the absolute scaling law given by Ching’s paper. Through theoretic analysis of data, this paper indicates that the regions act as two local intensive intermittent structures, by which the statistical absolute scaling performance of region is induced, rather than the statistical result of the entire time series in belief since 1941. In terms of statistical theory, the local structure in fluid, therefore, is the essence governing the absolute scaling performance of region, especially in high intensity.
Rayleigh-Plateau instability of slipping viscous filaments in v-shaped grooves
Brinkmann, Martin; Chan, Tak Shing; Seemann, Ralf
2016-11-01
Since the seminal works of Rayleigh and Plateau on the break-up of free-standing liquid jets, a large number of studies have addressed capillary instability of cylindrical interfaces in various settings. Here, we report the numerical results of a linear stability analysis of cylindrical liquid filament wetting v-shaped grooves employing a boundary element formalism. It is found that slip affects the wavelength λmax of the fastest growing mode whenever the transverse dimension W of the filaments is comparable, or smaller than the Navier slip-length B. The corresponding timescale of the decay, τmax, grows logarithmically with increasing B / W . In the opposite limit B / W > 1 are in good agreement with the numerical results only for contact angles 0 < θ - Ψ << 1 where the neutrally stable wavelength λ* <λmax is large compared to the transverse filament dimension W.
Magneto-Rayleigh-Taylor, Sausage And Kink Mode In Cylindrical Liners
Lau, Y. Y.; Zhang, Peng; Weis, Matthew; Gilgenbach, Ronald; Hess, Mark; Peterson, Kyle
2014-10-01
This paper analyzes the coupling of magneto-Rayleigh-Taylor (MRT), sausage (azimuthal mode number m = 0) and kink mode (m = 1) in an imploding cylindrical liner, using ideal MHD. A uniform axial magnetic field of arbitrary value is included in each region: liner, its interior, and its exterior. The dispersion relation, the feedthrough factor, and the temporal evolution of perturbations were solved exactly, for arbitrary values of g (= gravity), k (= axial wavenumber), m, aspect ratio, and equilibrium quantities in each region. For small k, a positive g (inward radial acceleration in the lab frame) tends to stabilize the sausage mode, but destabilize the kink mode. For large k, a positive g destabilizes both the kink and sausage mode. This analysis might shed lights into some puzzling features in Harris' classic paper, and in the recent cylindrical liner experiments on MRT. M. R. Weis was supported by the Sandia National Laboratories.
Revisiting the Effects of Compressibility on the Rayleigh-Taylor Instability
ZHOU Qianhong; LI Ding
2007-01-01
The effects of compressibility on the Rayleigh-Taylor instability(RTI)are investigated.It is shown that the controversy over compressibility effects in the previous studies is due to improper comparison,in which the density varying effect obscures the real role of compressibility.After eliminating the density varying effect,it is found that the compressibility destabilizes RTI in both the cases of constant density and exponentially varying density when M<1.This destabilizing effect is more important at smaller values of the Atwood number AT or greater values of gravity g,and the increment in the growth rate produced by compressibility depends inversely on the pressure p or the ratio of specific heat I.
Borońska, Katarzyna
2009-01-01
A large number of flows with distinctive patterns have been observed in experiments and simulations of Rayleigh-Benard convection in a water-filled cylinder whose radius is twice the height. We have adapted a time-dependent pseudospectral code, first, to carry out Newton's method and branch continuation and, second, to carry out the exponential power method and Arnoldi iteration to calculate leading eigenpairs and determine the stability of the steady states. The resulting bifurcation diagram contains 17 branches of stable and unstable steady states. These can be classified geometrically as roll states containing two, three, and four rolls; axisymmetric patterns with one or two tori; three-fold symmetric patterns called mercedes, mitubishi, marigold and cloverleaf; trigonometric patterns called dipole and pizza; and asymmetric patterns called CO and asymmetric three-rolls. The convective branches are connected to the conductive state and to each other by 16 primary and secondary pitchfork bifurcations and tur...
Modeling of the thermal boundary layer in turbulent Rayleigh-Bénard convection
Emran, Mohammad; Shishkina, Olga
2016-11-01
We report modeling of the thermal boundary layer in turbulent Rayleigh-Bénard convection (RBC), which incorporates the effect of turbulent fluctuations. The study is based on the thermal boundary layer equation from Shishkina et al., and new Direct Numerical Simulations (DNS) of RBC in a cylindrical cell of the aspect ratio 1, for the Prandtl number variation of several orders of magnitude. Our modeled temperature profiles are found to agree with the DNS much better than those obtained with the classical Prandtl-Blasius or Falkner-Skan approaches. The work is supported by the Deutsche Forschungsgemeinschaft (DFG) under the Grant Sh405/4 - Heisenberg fellowship and SFB963, Project A06.
Coexisting Raman- and Rayleigh-Enhanced Four-Wave Mixing in Femtosecond Polarization Beats
NIE Zhi-Qiang; ZHAO Yan; ZHANG Yan-Peng; GAN Chen-Li; ZHENG Huai-Sin; LI Chang-Biao; LU Ke-Qing
2009-01-01
Based on the polarization interference of Raman- and Rayleigh-enhanced four-wave mixing processes,heterodyne detection of the Raman,Rayleigh and coexisting Raman and Rayleigh femtosecond difference-frequency polarization beats is investigated in the cw and the three Markovian stochastic models,respectively.These two processes exhibit asymmetric and symmetric spectra,respectively,and the thermal effect in them can be suppressed by a field-correlation method.Such studies of coexisting Raman- and Rayleigh-enhanced four-wave mixing processes can have important applications in coherence quantum control,and quantum information processing.
Wang, Menghua
2016-05-30
To understand and assess the effect of the sensor spectral response function (SRF) on the accuracy of the top of the atmosphere (TOA) Rayleigh-scattering radiance computation, new TOA Rayleigh radiance lookup tables (LUTs) over global oceans and inland waters have been generated. The new Rayleigh LUTs include spectral coverage of 335-2555 nm, all possible solar-sensor geometries, and surface wind speeds of 0-30 m/s. Using the new Rayleigh LUTs, the sensor SRF effect on the accuracy of the TOA Rayleigh radiance computation has been evaluated for spectral bands of the Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi National Polar-orbiting Partnership (SNPP) satellite and the Joint Polar Satellite System (JPSS)-1, showing some important uncertainties for VIIRS-SNPP particularly for large solar- and/or sensor-zenith angles as well as for large Rayleigh optical thicknesses (i.e., short wavelengths) and bands with broad spectral bandwidths. To accurately account for the sensor SRF effect, a new correction algorithm has been developed for VIIRS spectral bands, which improves the TOA Rayleigh radiance accuracy to ~0.01% even for the large solar-zenith angles of 70°-80°, compared with the error of ~0.7% without applying the correction for the VIIRS-SNPP 410 nm band. The same methodology that accounts for the sensor SRF effect on the Rayleigh radiance computation can be used for other satellite sensors. In addition, with the new Rayleigh LUTs, the effect of surface atmospheric pressure variation on the TOA Rayleigh radiance computation can be calculated precisely, and no specific atmospheric pressure correction algorithm is needed. There are some other important applications and advantages to using the new Rayleigh LUTs for satellite remote sensing, including an efficient and accurate TOA Rayleigh radiance computation for hyperspectral satellite remote sensing, detector-based TOA Rayleigh radiance computation, Rayleigh radiance calculations for high altitude
Rayleigh-maximum-likelihood bilateral filter for ultrasound image enhancement.
Li, Haiyan; Wu, Jun; Miao, Aimin; Yu, Pengfei; Chen, Jianhua; Zhang, Yufeng
2017-04-17
Ultrasound imaging plays an important role in computer diagnosis since it is non-invasive and cost-effective. However, ultrasound images are inevitably contaminated by noise and speckle during acquisition. Noise and speckle directly impact the physician to interpret the images and decrease the accuracy in clinical diagnosis. Denoising method is an important component to enhance the quality of ultrasound images; however, several limitations discourage the results because current denoising methods can remove noise while ignoring the statistical characteristics of speckle and thus undermining the effectiveness of despeckling, or vice versa. In addition, most existing algorithms do not identify noise, speckle or edge before removing noise or speckle, and thus they reduce noise and speckle while blurring edge details. Therefore, it is a challenging issue for the traditional methods to effectively remove noise and speckle in ultrasound images while preserving edge details. To overcome the above-mentioned limitations, a novel method, called Rayleigh-maximum-likelihood switching bilateral filter (RSBF) is proposed to enhance ultrasound images by two steps: noise, speckle and edge detection followed by filtering. Firstly, a sorted quadrant median vector scheme is utilized to calculate the reference median in a filtering window in comparison with the central pixel to classify the target pixel as noise, speckle or noise-free. Subsequently, the noise is removed by a bilateral filter and the speckle is suppressed by a Rayleigh-maximum-likelihood filter while the noise-free pixels are kept unchanged. To quantitatively evaluate the performance of the proposed method, synthetic ultrasound images contaminated by speckle are simulated by using the speckle model that is subjected to Rayleigh distribution. Thereafter, the corrupted synthetic images are generated by the original image multiplied with the Rayleigh distributed speckle of various signal to noise ratio (SNR) levels and
Triazole-linked fluorescent bisboronic acid capable of selective recognition of the Lewis Y antigen.
Wang, Yan'en; Rong, Ruixue; Chen, Hua; Zhu, Mengyuan; Wang, Binghe; Li, Xiaoliu
2017-05-01
Cell surface carbohydrates of the Lewis blood group antigens, Lewis X (Le(x)), Lewis Y (Le(y)), Lewis A (Le(a)), and their sialylated derivatives, such as sialy Lewis X (sLe(x)) and sialy Lewis A (sLe(a)), play important roles in various recognition processes. These cell surface carbohydrates have also been associated with the development and progression of many types of cancers. Recently, we synthesized four anthracene-based fluorescent bisboronic acid sensors (compounds 2a-d) linked by 'click' chemistry with tethers of different lengths to match the epitope of various Lewis group of sugars. Among the four compounds, 2a appears to have both high sensitivity and selectivity for Le(y) among other carbohydrate antigens. Copyright © 2017 Elsevier Ltd. All rights reserved.
On Lamb and Rayleigh wave convergence in viscoelastic tissues
Nenadic, Ivan Z; Urban, Matthew W; Aristizabal, Sara; Mitchell, Scott A; Humphrey, Tye C; Greenleaf, James F, E-mail: Nenadic.Ivan@mayo.edu [Department of Biomedical Engineering, Mayo Clinic College of Medicine, Rochester, MN, 55905 (United States)
2011-10-21
Characterization of the viscoelastic material properties of soft tissue has become an important area of research over the last two decades. Our group has been investigating the feasibility of using a shear wave dispersion ultrasound vibrometry (SDUV) method to excite Lamb waves in organs with plate-like geometry to estimate the viscoelasticity of the medium of interest. The use of Lamb wave dispersion ultrasound vibrometry to quantify the mechanical properties of viscoelastic solids has previously been reported. Two organs, the heart wall and the spleen, can be readily modeled using plate-like geometries. The elasticity of these two organs is important because they change in pathological conditions. Diastolic dysfunction is the inability of the left ventricle (LV) of the heart to supply sufficient stroke volumes into the systemic circulation and is accompanied by the loss of compliance and stiffening of the LV myocardium. It has been shown that there is a correlation between high splenic stiffness in patients with chronic liver disease and strong correlation between spleen and liver stiffness. Here, we investigate the use of the SDUV method to quantify the viscoelasticity of the LV free-wall myocardium and spleen by exciting Rayleigh waves on the organ's surface and measuring the wave dispersion (change of wave velocity as a function of frequency) in the frequency range 40-500 Hz. An equation for Rayleigh wave dispersion due to cylindrical excitation was derived by modeling the excised myocardium and spleen with a homogenous Voigt material plate immersed in a nonviscous fluid. Boundary conditions and wave potential functions were solved for the surface wave velocity. Analytical and experimental convergence between the Lamb and Rayleigh waves is reported in a finite element model of a plate in a fluid of similar density, gelatin plate and excised porcine spleen and left-ventricular free-wall myocardium.
On Lamb and Rayleigh Wave Convergence in Viscoelastic Tissues
Nenadic, Ivan Z.; Urban, Matthew W.; Aristizabal, Sara; Mitchell, Scott A.; Humphrey, Tye C.; Greenleaf, James F.
2012-01-01
Characterization of the viscoelastic material properties of soft tissue has become an important area of research over the last two decades. Our group has been investigating the feasibility of using Shearwave Dispersion Ultrasound Vibrometry (SDUV) method to excite Lamb waves in organs with plate-like geometry to estimate the viscoelasticity of the medium of interest. The use of Lamb wave Dispersion Ultrasound Vibrometry (LDUV) to quantify mechanical properties of viscoelastic solids has previously been reported. Two organs, the heart wall and the spleen, can be readily modeled using plate-like geometries. The elasticity of these two organs is important because they change in pathological conditions. Diastolic dysfunction is the inability of the left ventricle (LV) of the heart to supply sufficient stroke volumes into the systemic circulation and is accompanied by the loss of compliance and stiffening of the LV myocardium. It has been shown that there is a correlation between high splenic stiffness in patients with chronic liver disease and strong correlation between spleen and liver stiffness. Here, we investigate the use of the SDUV method to quantify viscoelasticity of the LV free-wall myocardium and spleen by exciting Rayleigh waves on the organ’s surface and measuring the wave dispersion (change of wave velocity as a function of frequency) in the frequency range 40–500 Hz. An equation for Rayleigh wave dispersion due to cylindrical excitation was derived by modeling the excised myocardium and spleen with a homogenous Voigt material plate immersed in a nonviscous fluid. Boundary conditions and wave potential functions were solved for the surface wave velocity. Analytical and experimental convergence between the Lamb and Rayleigh waves is reported in a finite element model of a plate in a fluid of similar density, gelatin plate and excised porcine spleen and left-ventricular free-wall myocardium. PMID:21970846
Rayleigh-Wave Group-Velocity Tomography of Saudi Arabia
Tang, Zheng; Mai, P. Martin; Chang, Sung-Joon; Zahran, Hani
2017-04-01
We use surface-wave tomography to investigate the lithospheric structure of the Arabian plate, which is traditionally divided into the Arabian shield in the west and the Arabian platform in the east. The Arabian shield is a complicated mélange of crustal material, composed of several Proterozoic terrains separated by ophiolite-bearing suture zones and dotted by outcropping Cenozoic volcanic rocks. The Arabian platform is primarily covered by very thick Paleozoic, Mesozoic and Cenozoic sediments. We develop high-resolution tomographic images from fundamental-mode Rayleigh-wave group-velocities across Saudi Arabia, utilizing the teleseismic data recorded by the permanent Saudi National Seismic Network (SNSN). Our study extends previous efforts on surface wave work by increasing ray path density and improving spatial resolution. Good quality dispersion measurements for roughly 3000 Rayleigh-wave paths have been obtained and utilized for the group-velocity tomography. We have applied the Fast Marching Surface Tomography (FMST) scheme of Rawlinson (2005) to obtain Rayleigh-wave group-velocity images for periods from 8 s to 40 s on a 0.8° 0.8° grid and at resolutions approaching 2.5° based on the checkerboard tests. Our results indicate that short-period group-velocity maps (8-15 s) correlate well with surface geology, with slow velocities delineating the main sedimentary features including the Arabian platform, the Persian Gulf and Mesopotamia. For longer periods (20-40 s), the velocity contrast is due to the differences in crustal thickness and subduction/collision zones. The lower velocities are sensitive to the thicker continental crust beneath the eastern Arabia and the subduction/collision zones between the Arabian and Eurasian plate, while the higher velocities in the west infer mantle velocity.
On Lamb and Rayleigh wave convergence in viscoelastic tissues.
Nenadic, Ivan Z; Urban, Matthew W; Aristizabal, Sara; Mitchell, Scott A; Humphrey, Tye C; Greenleaf, James F
2011-10-21
Characterization of the viscoelastic material properties of soft tissue has become an important area of research over the last two decades. Our group has been investigating the feasibility of using a shear wave dispersion ultrasound vibrometry (SDUV) method to excite Lamb waves in organs with plate-like geometry to estimate the viscoelasticity of the medium of interest. The use of Lamb wave dispersion ultrasound vibrometry to quantify the mechanical properties of viscoelastic solids has previously been reported. Two organs, the heart wall and the spleen, can be readily modeled using plate-like geometries. The elasticity of these two organs is important because they change in pathological conditions. Diastolic dysfunction is the inability of the left ventricle (LV) of the heart to supply sufficient stroke volumes into the systemic circulation and is accompanied by the loss of compliance and stiffening of the LV myocardium. It has been shown that there is a correlation between high splenic stiffness in patients with chronic liver disease and strong correlation between spleen and liver stiffness. Here, we investigate the use of the SDUV method to quantify the viscoelasticity of the LV free-wall myocardium and spleen by exciting Rayleigh waves on the organ's surface and measuring the wave dispersion (change of wave velocity as a function of frequency) in the frequency range 40–500 Hz. An equation for Rayleigh wave dispersion due to cylindrical excitation was derived by modeling the excised myocardium and spleen with a homogenous Voigt material plate immersed in a nonviscous fluid. Boundary conditions and wave potential functions were solved for the surface wave velocity. Analytical and experimental convergence between the Lamb and Rayleigh waves is reported in a finite element model of a plate in a fluid of similar density, gelatin plate and excised porcine spleen and left-ventricular free-wall myocardium.
Rayleigh scattering and nonlinear inversion of elastic waves
Gritto, R.
1995-12-01
Rayleigh scattering of elastic waves by an inclusion is investigated and the limitations determined. In the near field of the inhomogeneity, the scattered waves are up to a factor of 300 stronger than in the far field, excluding the application of the far field Rayleigh approximation for this range. The investigation of the relative error as a function of parameter perturbation shows a range of applicability broader than previously assumed, with errors of 37% and 17% for perturbations of {minus}100% and +100%, respectively. The validity range for the Rayleigh limit is controlled by large inequalities, and therefore, the exact limit is determined as a function of various parameter configurations, resulting in surprisingly high values of up to k{sub p}R = 0.9. The nonlinear scattering problem can be solved by inverting for equivalent source terms (moments) of the scatterer, before the elastic parameters are determined. The nonlinear dependence between the moments and the elastic parameters reveals a strong asymmetry around the origin, which will produce different results for weak scattering approximations depending on the sign of the anomaly. Numerical modeling of cross hole situations shows that near field terms are important to yield correct estimates of the inhomogeneities in the vicinity of the receivers, while a few well positioned sources and receivers considerably increase the angular coverage, and thus the model resolution of the inversion parameters. The pattern of scattered energy by an inhomogeneity is complicated and varies depending on the object, the wavelength of the incident wave, and the elastic parameters involved. Therefore, it is necessary to investigate the direction of scattered amplitudes to determine the best survey geometry.
Rayleigh-type Surface Quasimodes in General Linear Elasticity
Hansen, Sönke
2010-01-01
Rayleigh-type surface waves correspond to the characteristic variety, in the elliptic boundary region, of the displacement-to-traction map. In this paper, surface quasimodes are constructed for the reduced elastic wave equation, anisotropic in general, with traction-free boundary. Assuming a global variant of a condition of Barnett and Lothe, the construction is reduced to an eigenvalue problem for a selfadjoint scalar first order pseudo-differential operator on the boundary. The principal and the subprincipal symbol of this operator are computed. The formula for the subprincipal symbol seems to be new even in the isotropic case.
Rayleigh-Brillouin spectrum in special relativistic hydrodynamics.
Garcia-Perciante, A L; Garcia-Colin, L S; Sandoval-Villalbazo, A
2009-06-01
In this paper we calculate the Rayleigh-Brillouin spectrum for a relativistic simple fluid according to three different versions available for a relativistic approach to nonequilibrium thermodynamics. An outcome of these calculations is that Eckart's version predicts that such spectrum does not exist. This provides an argument to question its validity. The remaining two results, which differ one from another, do provide a finite form for such spectrum. This raises the rather intriguing question as to which of the two theories is a better candidate to be taken as a possible version of relativistic nonequilibrium thermodynamics. The answer will clearly require deeper examination of this problem.
The Rayleigh-Brillouin Spectrum in Special Relativistic Hydrodynamics
García-Perciante, A L; Sandoval-Villalbazo, A
2009-01-01
In this paper we calculate the Rayleigh-Brillouin spectrum for a relativistic simple fluid according to three different versions available for a relativistic approach to non-equilibrium thermodynamics. An outcome of these calculations is that Eckart's version predicts that such spectrum does not exist. This provides an argument to question its validity. The remaining two results, which differ one from another, do provide a finite form for such spectrum. This raises the rather intriguing question as to which of the two theories is a better candidate to be taken as a possible version of relativistic non-equilibrium thermodynamics. The answer will clearly require deeper examination of this problem.
RAYLEIGH LAMB WAVES IN MICROPOLAR ISOTROPIC ELASTIC PLATE
Rajneesh Kumar; Geeta Partap
2006-01-01
The propagation of waves in a homogeneous isotropic micropolar elastic cylindrical plate subjected to stress free conditions is investigated. The secular equations for symmetric and skew symmetric wave mode propagation are derived. At short wave limit,the secular equations for symmetric and skew symmetric waves in a stress free circular plate reduces to Rayleigh surface wave frequency equation. Thin plate results are also obtained. The amplitudes of displacements and microrotation components are obtained and depicted graphically. Some special cases are also deduced from the present investigations. The secular equations for symmetric and skew symmetric modes are also presented graphically.
Statistics and scaling in turbulent Rayleigh-Bénard convection
Ching, Emily SC
2013-01-01
This Brief addresses two issues of interest of turbulent Rayleigh-Bénard convection. The first issue is the characterization and understanding of the statistics of the velocity and temperature fluctuations in the system. The second issue is the revelation and understanding of the nature of the scaling behavior of the velocity temperature structure functions. The problem under the Oberbeck-Boussinesq approximation is formulated. The statistical tools, including probability density functions (PDF) and conditional statistics, for studying fluctuations are introduced, and implicit PDF formulae for
A generalised Rayleigh-Taylor condition for the Muskat problem
Escher, Joachim; Matioc, Bogdan-Vasile
2010-01-01
In this paper we consider the evolution of two fluid phases in a porous medium. The fluids are separated from each other and also the wetting phase from air by interfaces which evolve in time. We reduce the problem to an abstract evolution equation. A generalised Rayleigh-Taylor condition characterizes the parabolicity regime of the problem and allows us to establish a general well-posedness result and to study stability properties of flat steady-states. When considering surface tension effects at the interface between the fluids and if the more dense fluid lies above, we find bifurcating finger-shaped equilibria which are all unstable.
Dynamic stabilization of Rayleigh-Taylor instability in ablation fronts
Piriz A.R.
2013-11-01
Full Text Available Dynamic stabilization of Rayleigh-Taylor instability in an ablation front is studied by considering the simplest possible modulations in the acceleration. Explicit analytical expressions for the instability growth rate and for the boundaries of the stability region are obtained by considering a sequence of Dirac deltas. Besides, general square waves allow for studying the effect of the driving asymmetries on the stability region as well as the optimization process. The essential role of compressibility is phenomenologically addressed in order to find the constraints it imposes on the stability region.
Phenomenological Theory for Spatiotemporal Chaos in Rayleigh-Benard Convection
Li, Xiao-jun; Xi, Hao-wen; Gunton, J. D.
1997-01-01
We present a phenomenological theory for spatiotemporal chaos (STC) in Rayleigh-Benard convection, based on the generalized Swift-Hohenberg model. We apply a random phase approximation to STC and conjecture a scaling form for the structure factor $S(k)$ with respect to the correlation length $\\xi_2$. We hence obtain analytical results for the time-averaged convective current $J$ and the time-averaged vorticity current $\\Omega$. We also define power-law behaviors such as $J \\sim \\epsilon^\\mu$,...
Theoretical and Experimental Studies of Magneto-Rayleigh-Taylor Instabilities
Lau, Yue Ying [University of Michigan, Ann Arbor, MI (United States); Gilgenbach, Ronald [University of Michigan, Ann Arbor, MI (United States)
2013-07-07
Magneto-Rayleigh-Taylor instability (MRT) is important to magnetized target fusion, wire-array z-pinches, and equation-of-state studies using flyer plates or isentropic compression. It is also important to the study of the crab nebula. The investigators performed MRT experiments on thin foils, driven by the mega-ampere linear transformer driver (LTD) facility completed in their laboratory. This is the first 1-MA LTD in the USA. Initial experiments on the seeding of MRT were performed. Also completed was an analytic study of MRT for a finite plasma slab with arbitrary magnetic fields tangential to the interfaces. The effects of magnetic shear and feedthrough were analyzed.
Analytical evaluation of atomic form factors: application to Rayleigh scattering
Safari, L; Amaro, P; Jänkälä, K; Fratini, F
2014-01-01
Atomic form factors are widely used for the characterization of targets and specimens, from crystallography to biology. By using recent mathematical results, here we derive an analytical expression for the atomic form factor within the independent particle model constructed from nonrelativistic screened hydrogenic wavefunctions. The range of validity of this analytical expression is checked by comparing the analytically obtained form factors with the ones obtained within the Hartee-Fock method. As an example, we apply our analytical expression for the atomic form factor to evaluate the differential cross section for Rayleigh scattering off neutral atoms.
RAYLEIGH WAVE STUDIES OF CATHODIC H-CHARGING OF Fe
Lunarska, E.; Fiore, N.
1981-01-01
The attenuation of 2-6 MHz Rayleigh waves /RW/ was measured in sheet samples of Fe which were undergoing electrolytic charging with H. The cathodic polarization and As2O3 addition into electrolyte were found to effect the attenuation and velocity of the surface waves. The attenuation changes were retarded by the deposition of a thin /2µm/ layer of Cu on the Fe surface, with the Cu acting as a H-permeation barrier. The decrease in attenuation was caused by the entry of H into solid solution at...
Turbo Detection in Rayleigh flat fading channel with unknown statistics
Paul Fortier
2010-11-01
Full Text Available The turbo detection of turbo coded symbols over correlated Rayleigh flat fading channels generatedaccording to Jakes’ model is considered in this paper. We propose a method to estimate the channelsignal-to-noise ratio (SNR and the maximum Doppler frequency. These statistics are required bythe linear minimum mean squared error (LMMSE channel estimator. To improve the system convergence,we redefine the channel reliability factor by taking into account the channel estimationerror statistics. Simulation results for rate 1=3 turbo code and two different normalized fading ratesshow that the use of the new reliability factor greatly improves the performance. The improvementis more substantial when channel statistics are unknown.
Rayleigh-Brillouin Scattering in Binary Gas Mixtures
Gu, Ziyu; van de Water, Willem; Marques, Wilson
2015-01-01
Precise measurements are performed on spectral lineshapes of spontaneous Rayleigh-Brillouin scattering in mixtures of the noble gases Ar and Kr, with He. Admixture of a light He atomic fraction results in marked changes of the spectra, although in all experiments He is merely a spectator atom: it affects the relaxation of density fluctuations of the heavy constituent, but its contribution to the scattered light intensity is negligibly small. The results are compared to a theory for the spectral lineshape without adjustable parameters, yielding excellent agreement for the case of binary mono-atomic gases, signifying a step towards modeling and understanding of light scattering in more complex molecular media.
Instantaneous Rayleigh scattering from excitons localized in monolayer islands
Langbein, Wolfgang; Leosson, Kristjan; Jensen, Jacob Riis;
2000-01-01
We show that the initial dynamics of Rayleigh scattering from excitons in quantum wells can be either instantaneous or delayed, depending on the exciton ensemble studied. For excitation of the entire exciton resonance, a finite rise time given by the inverse inhomogeneous broadening: of the exciton...... resonance is observed. Instead, when exciting only a subsystem of the exciton resonance, in our case excitons localized in quantum well regions of a specific monolayer thickness, the rise has an instantaneous component. This is due to the spatial nonuniformity of the initially excited exciton polarization...
Selective Manipulation of Microscopic Particles with Precursor Swirling Rayleigh Waves
Riaud, Antoine; Baudoin, Michael; Bou Matar, Olivier; Becerra, Loic; Thomas, Jean-Louis
2017-02-01
Contactless manipulation of microparticles is demonstrated with single-beam acoustical tweezers based on precursor swirling Rayleigh waves. These surface waves degenerate into acoustical vortices when crossing a stack made of a fluid layer and its solid support, hence creating a localized acoustical trap in a fluid cavity. They can be synthesized with a single interdigitated transducer whose spiraling shape encodes the phase of the field like a hologram. For applications, these tweezers have many attractive features: they are selective, flat, easily integrable, and compatible with disposable substrates.
Low-dimensional model of turbulent Rayleigh-Benard convection in a Cartesian cell with square domain
Bailon-Cuba, Jorge
2011-01-01
A low-dimensional model (LDM) for turbulent Rayleigh-Benard convection in a Cartesian cell with square domain, based on the Galerkin projection of the Boussinesq equations onto a finite set of empirical eigenfunctions, is presented. The empirical eigenfunctions are obtained from a joint Proper Orthogonal Decomposition (POD) of the velocity and temperature fields using the Snapshot Method on the basis of a direct numerical simulation (DNS). The resulting LDM is a quadratic inhomogeneous system of coupled ordinary differential equations which we use to describe the long-time temporal evolution of the large-scale mode amplitudes for a Rayleigh number of 1e5 and a Prandtl number of 0.7. The truncation to a finite number of degrees of freedom, that does not exceed a number of 310 for the present, requires the additional implementation of an eddy viscosity-diffusivity to capture the missing dissipation of the small-scale modes. The magnitude of this additional dissipation mechanism is determined by requiring statis...
Next-generation sequencing reveals substantial genetic contribution to dementia with Lewy bodies.
Geiger, Joshua T; Ding, Jinhui; Crain, Barbara; Pletnikova, Olga; Letson, Christopher; Dawson, Ted M; Rosenthal, Liana S; Pantelyat, Alexander; Gibbs, J Raphael; Albert, Marilyn S; Hernandez, Dena G; Hillis, Argye E; Stone, David J; Singleton, Andrew B; Hardy, John A; Troncoso, Juan C; Scholz, Sonja W
2016-10-01
Dementia with Lewy bodies (DLB) is the second most common neurodegenerative dementia after Alzheimer's disease. Although an increasing number of genetic factors have been connected to this debilitating condition, the proportion of cases that can be attributed to distinct genetic defects is unknown. To provide a comprehensive analysis of the frequency and spectrum of pathogenic missense mutations and coding risk variants in nine genes previously implicated in DLB, we performed exome sequencing in 111 pathologically confirmed DLB patients. All patients were Caucasian individuals from North America. Allele frequencies of identified missense mutations were compared to 222 control exomes. Remarkably, ~25% of cases were found to carry a pathogenic mutation or risk variant in APP, GBA or PSEN1, highlighting that genetic defects play a central role in the pathogenesis of this common neurodegenerative disorder. In total, 13% of our cohort carried a pathogenic mutation in GBA, 10% of cases carried a risk variant or mutation in PSEN1, and 2% were found to carry an APP mutation. The APOE ε4 risk allele was significantly overrepresented in DLB patients (p-value <0.001). Our results conclusively show that mutations in GBA, PSEN1, and APP are common in DLB and consideration should be given to offer genetic testing to patients diagnosed with Lewy body dementia.
Rayleigh-Taylor instability under curved substrates: An optimal transient growth analysis
Balestra, Gioele; Brun, P.-T.; Gallaire, François
2016-12-01
We investigate the stability of thin viscous films coated on the inside of a horizontal cylindrical substrate. In such a case, gravity acts both as a stabilizing force through the progressive drainage of the film and as a destabilizing force prone to form droplets via the Rayleigh-Taylor instability. The drainage solution, derived from lubrication equations, is found asymptotically stable with respect to infinitesimally small perturbations, although in reality, droplets often form. To resolve this paradox, we perform an optimal transient growth analysis for the first-order perturbations of the liquid's interface, generalizing the results of Trinh et al. [Phys. Fluids 26, 051704 (2014), 10.1063/1.4876476]. We find that the system displays a linear transient growth potential that gives rise to two different scenarios depending on the value of the Bond number (prescribing the relative importance of gravity and surface tension forces). At low Bond numbers, the optimal perturbation of the interface does not generate droplets. In contrast, for higher Bond numbers, perturbations on the upper hemicircle yield gains large enough to potentially form droplets. The gain increases exponentially with the Bond number. In particular, depending on the amplitude of the initial perturbation, we find a critical Bond number above which the short-time linear growth is sufficient to trigger the nonlinear effects required to form dripping droplets. We conclude that the transition to droplets detaching from the substrate is noise and perturbation dependent.
Y.G. Cao; W.K. Chow; N.K. Fong
2011-01-01
With a self-similar parameter b（At） = Hi/λi, where At is the Atwood number, Hi and λi are the a.mplluae and wavelength of bubble （i = 1） and spike （i = 2） respectively, we derive analytically the solutions to the buoyancy-drag equation recently proposed for dynamical evolution of Rayleigh-Taylor and Richtmyer-Meshkov mixing zone. Numerical solutions are obtained with a simple form ofb（At）--- 1/（1 ＋ At） and comparisons with recent LEM （linear electric motor） experiments are made, and an agreement is found with properly chosen initial conditions.
SOLUTION OF THE RAYLEIGH PROBLEM FOR A POWER-LAW NON-NEWTONIAN CONDUCTING FLUID VIA GROUP METHOD
Mina B.Abd-el-Malek; Nagwa A.Badran; Hossam S.Hassan
2002-01-01
An investigation is made of the magnetic Rayleigh problem where a semi-infinite plate is given an impulsive motion and thereafter moves with constant velocity in a nonNewtonian power law fluid of infinite extent. The solution of this highly non-linear problem is obtained by means of the transformation group theoretic approach. The one-parameter group transformation reduces the number of independent variables by one and the governing partial differential equation with the boundary conditions reduce to an ordinary differential equation with the appropriate boundary conditions. Effect of the some parameters on the velocity u ( y, t) has been studied and the results are plotted.
From Bidentate Gallium Lewis Acids to Supramolecular Complexes.
Horstmann, Jan; Hyseni, Mentor; Mix, Andreas; Neumann, Beate; Stammler, Hans-Georg; Mitzel, Norbert W
2017-05-22
Bidentate gallium Lewis acids were prepared by the reaction of diethynyldiphenylsilane with neat trimethyl- or triethylgallium. Bis[(dimethylgallyl)ethynyl]diphenylsilane (1) and diethylgallyl derivative 2 were characterized as Et2 O or pyridine adducts by NMR spectroscopy; 2⋅2Py was isolated. Lewis acids 1 and 2 form host-guest adducts with bidentate nitrogen bases, but defined cyclic 1:1 adducts are only formed between 1 and bases with matching N⋅⋅⋅N distances: 4,4'-dimethyl-3,3'-bipyridinylacetylene (3), bis[(pyridin-3-yl)ethynyl]diphenylsilane (4), and bis[(2-methylpyridin-5-yl)ethynyl]diphenylsilane (5). The structures of adducts 1⋅3, 1⋅4, and 1⋅5 were established by X-ray diffraction experiments. 2⋅2Py reacts with DABCO to afford polymeric (DABCO-2-)n . © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Chemical Inventory Management at NASA Lewis Research Center
Kraft, Shirley S.; Homan, Joseph R.; Bajorek, Michael J.; Dominguez, Manuel B.; Smith, Vanessa L.
1997-01-01
The Chemical Management System (CMS) is a client/server application developed with Power Builder and Sybase for the Lewis Research Center (LeRC). Power Builder is a client-server application development tool, Sybase is a Relational Database Management System. The entire LeRC community can access the CMS from any desktop environment. The multiple functions and benefits of the CMS are addressed.
C.S.Lewis: The Chronicles of Narnia and imagination
Gojkošek, Monika
2015-01-01
The thesis entitled C. S. Lewis: The Chronicles of Narnia and imagination primarily focuses on the term fantastic novel, its development in Slovene literature and the definition of the term itself which changed during time. Since J. J. Kenda places The Chronicles of Narnia among fantasy literature a special emphasis is also given to the latter term. The second part of the thesis deals with the stories of The Chronicles of Narnia and the circumstances of their origin. An important part of the...
Thermal degradation of polystyrene by Lewis acids in solution
2002-01-01
The degradation of polystyrene in various Lewis acids [aluminum chloride, ferric chloride, borontriflouride etherate, and tin(IV) chloride] at different temperatures (75-125 degreesC) has been studied in this work. The evolution of the molecular weight distribution (MWD) has been modeled using continuous distribution kinetics with a stoichiometric kernel for random chain scission. The degradation rate was the highest in the presence of aluminum chloride. The reactions were also carried out at...
Rayleigh wave inversion using heat-bath simulated annealing algorithm
Lu, Yongxu; Peng, Suping; Du, Wenfeng; Zhang, Xiaoyang; Ma, Zhenyuan; Lin, Peng
2016-11-01
The dispersion of Rayleigh waves can be used to obtain near-surface shear (S)-wave velocity profiles. This is performed mainly by inversion of the phase velocity dispersion curves, which has been proven to be a highly nonlinear and multimodal problem, and it is unsuitable to use local search methods (LSMs) as the inversion algorithm. In this study, a new strategy is proposed based on a variant of simulated annealing (SA) algorithm. SA, which simulates the annealing procedure of crystalline solids in nature, is one of the global search methods (GSMs). There are many variants of SA, most of which contain two steps: the perturbation of model and the Metropolis-criterion-based acceptance of the new model. In this paper we propose a one-step SA variant known as heat-bath SA. To test the performance of the heat-bath SA, two models are created. Both noise-free and noisy synthetic data are generated. Levenberg-Marquardt (LM) algorithm and a variant of SA, known as the fast simulated annealing (FSA) algorithm, are also adopted for comparison. The inverted results of the synthetic data show that the heat-bath SA algorithm is a reasonable choice for Rayleigh wave dispersion curve inversion. Finally, a real-world inversion example from a coal mine in northwestern China is shown, which proves that the scheme we propose is applicable.
Experimental Study of Rayleigh-Taylor Instability Using Paramagnetic Fluids
Tsiklashvili, Vladimer; Likhachev, Oleg; Jacobs, Jeffry
2009-11-01
Experiments that take advantage of the properties of paramagnetic liquids are used to study Rayleigh-Taylor instability. A gravitationally unstable combination of a paramagnetic salt solution and a nonmagnetic solution is initially stabilized by a magnetic field gradient that is produced by the contoured pole-caps of a large electromagnet. Rayleigh-Taylor instability originates with the rapid removal of current from the electromagnet, which results in the heavy liquid falling into the light liquid due to gravity and, thus, mixing with it. The mixing zone is visualized by back-lit photography and is recorded with a digital video camera. For visualization purposes, a blue-green dye is added to the magnetic fluid. The mixing rate of the two liquids is determined from an averaged dye concentration across the mixing layer by means of the Beer-Lambert law. After removal of the suspending magnetic field, the initially flat interface between the two liquids develops a random surface pattern with the dominant length scale well approximated by the fastest growing wavelength in accordance with the viscous linear stability theory. Several combinations of paramagnetic and nonmagnetic solutions have been considered during the course of the research. A functional dependence of the mixing layer growth constant, α, on the properties of the liquids is a primary subject of the present study.
Experimental and theoretical study of Rayleigh-Lamb wave propagation
Rogers, Wayne P.; Datta, Subhendu K.; Ju, T. H.
1990-01-01
Many space structures, such as the Space Station Freedom, contain critical thin-walled components. The structural integrity of thin-walled plates and shells can be monitored effectively using acoustic emission and ultrasonic testing in the Rayleigh-Lamb wave frequency range. A new PVDF piezoelectric sensor has been developed that is well suited to remote, inservice nondestructive evaluation of space structures. In the present study the new sensor was used to investigate Rayleigh-Lamb wave propagation in a plate. The experimental apparatus consisted of a glass plate (2.3 m x 25.4 mm x 5.6 mm) with PVDF sensor (3 mm diam.) mounted at various positions along its length. A steel ball impact served as a simulated acoustic emission source, producing surface waves, shear waves and longitudinal waves with dominant frequencies between 1 kHz and 200 kHz. The experimental time domain wave-forms were compared with theoretical predictions of the wave propagation in the plate. The model uses an analytical solution for the Green's function and the measured response at a single position to predict response at any other position in the plate. Close agreement was found between the experimental and theoretical results.
Optical trapping of metallic Rayleigh particle by combined beam
CHENG Ke; ZHONG Xian-qiong; XIANG An-ping
2012-01-01
Radiation forces and trapping stability of metallic (i.e.gold) Rayleigh particle by combined beam are analyzed,and the combined beam is formed by superimposing two partially coherent off-axis fiat-topped beams.The dependences of radiation forces on off-axis distance parameter,correlation length and particle radius are illustrated by numerical examples.The results show that there exist critical values d0,cand σ0,c for the combined beam.For 0＜d ≤ d0,c or 0＜σ0 ≤σ0,c the Gaussianlike intensity profile takes place at the geometrical focal plane,so that the transverse gradient force can act as restoring force.As the off-axis distance parameter increases or the correlation length decreases,the maximal intensity,the radiation force and trapping stiffness become smaller,while the transverse and longitudinal trapping ranges become larger.In comparison with a single beam,the combined beam is more favourable for trapping metallic Rayleigh particle owing to the stronger trapping stiffness and the larger trapping range.
Development of Fluorous Lewis Acid-Catalyzed Reactions
Joji Nishikido
2006-08-01
Full Text Available Organic synthetic methodology in the 21st century aims to conform to the principles of green sustainable chemistry (GSC and we may expect that in the future, the realization of GSC will be an important objective for chemical industries. An important aim of synthetic organic chemistry is to implement waste-free and environmentally-benign industrial processes using Lewis acids as versatile as aluminum choride. A key technological objective of our work in this area has been to achieve a Ã¢Â€Âœcatalyst recycling system that utilizes the high activity and structural features of fluorous Lewis acid catalystsÃ¢Â€Â. Thus, we have developed a series of novel fluorous Lewis acid catalysts, namely the ytterbium(III, scandium(III, tin(IV or hafnium(IV bis(perfluoroalkanesulfonylamides or tris(perfluoro- alkanesulfonylmethides. Our catalysts are recyclable and effective for acylations of alcohols and aromatics, Baeyer-Villiger reactions, direct esterifications and transesterifications in a fluorous biphasic system (FBS, in supercritical carbon dioxide and on fluorous silica gel supports.
Diagnosis and management of dementia with Lewy bodies
Boeve, Bradley F.; Dickson, Dennis W.; Halliday, Glenda; Taylor, John-Paul; Weintraub, Daniel; Aarsland, Dag; Galvin, James; Attems, Johannes; Ballard, Clive G.; Bayston, Ashley; Beach, Thomas G.; Blanc, Frédéric; Bohnen, Nicolaas; Bonanni, Laura; Bras, Jose; Brundin, Patrik; Burn, David; Chen-Plotkin, Alice; Duda, John E.; El-Agnaf, Omar; Feldman, Howard; Ferman, Tanis J.; ffytche, Dominic; Fujishiro, Hiroshige; Galasko, Douglas; Goldman, Jennifer G.; Gomperts, Stephen N.; Graff-Radford, Neill R.; Honig, Lawrence S.; Iranzo, Alex; Kantarci, Kejal; Kaufer, Daniel; Kukull, Walter; Lee, Virginia M.Y.; Leverenz, James B.; Lewis, Simon; Lippa, Carol; Lunde, Angela; Masellis, Mario; Masliah, Eliezer; McLean, Pamela; Mollenhauer, Brit; Montine, Thomas J.; Moreno, Emilio; Mori, Etsuro; Murray, Melissa; O'Brien, John T.; Orimo, Sotoshi; Postuma, Ronald B.; Ramaswamy, Shankar; Ross, Owen A.; Salmon, David P.; Singleton, Andrew; Taylor, Angela; Thomas, Alan; Tiraboschi, Pietro; Toledo, Jon B.; Trojanowski, John Q.; Tsuang, Debby; Walker, Zuzana; Yamada, Masahito; Kosaka, Kenji
2017-01-01
The Dementia with Lewy Bodies (DLB) Consortium has refined its recommendations about the clinical and pathologic diagnosis of DLB, updating the previous report, which has been in widespread use for the last decade. The revised DLB consensus criteria now distinguish clearly between clinical features and diagnostic biomarkers, and give guidance about optimal methods to establish and interpret these. Substantial new information has been incorporated about previously reported aspects of DLB, with increased diagnostic weighting given to REM sleep behavior disorder and 123iodine-metaiodobenzylguanidine (MIBG) myocardial scintigraphy. The diagnostic role of other neuroimaging, electrophysiologic, and laboratory investigations is also described. Minor modifications to pathologic methods and criteria are recommended to take account of Alzheimer disease neuropathologic change, to add previously omitted Lewy-related pathology categories, and to include assessments for substantia nigra neuronal loss. Recommendations about clinical management are largely based upon expert opinion since randomized controlled trials in DLB are few. Substantial progress has been made since the previous report in the detection and recognition of DLB as a common and important clinical disorder. During that period it has been incorporated into DSM-5, as major neurocognitive disorder with Lewy bodies. There remains a pressing need to understand the underlying neurobiology and pathophysiology of DLB, to develop and deliver clinical trials with both symptomatic and disease-modifying agents, and to help patients and carers worldwide to inform themselves about the disease, its prognosis, best available treatments, ongoing research, and how to get adequate support. PMID:28592453
Lewis' Educational and Research Collaborative Intership Program Grant Closeout Report
2003-01-01
The Lewis' Educational and Research Collaborative Internship Program (LERCIP) is a collaborative undertaking by the Office of Educational Programs at NASA Glenn Research Center at Lewis Field (formerly NASA Lewis Research Center) and the Ohio Aerospace Institute. This program provides 10-week internships and 10 or 12-week fellowships for undergraduate/graduate students and secondary school teachers. Approximately 130 interns are selected to participate in this program each year and begin arriving the second week in May. The internships provide students with introductory professional experiences to complement their academic programs. The interns are given assignments on research and development projects under the personal guidance of NASA professional staff members. Each intern is assigned a NASA mentor who facilitates a research assignment. In addition to the research assignment, the summer program includes a strong educational component that enhances the professional stature of the participants. The educational activities include a research symposium and a variety of workshops, lectures and short courses. An important aspect of the program is that it includes students with diverse social, cultural and economic backgrounds.
Fullerene–Carbene Lewis Acid–Base Adducts
Li, Huaping
2011-08-17
The reaction between a bulky N-heterocylic carbene (NHC) and C60 leads to the formation of a thermally stable zwitterionic Lewis acid-base adduct that is connected via a C-C single bond. Low-energy absorption bands with weak oscillator strengths similar to those of n-doped fullerenes were observed for the product, consistent with a net transfer of electron density to the C60 core. Corroborating information was obtained using UV photoelectron spectroscopy, which revealed that the adduct has an ionization potential ∼1.5 eV lower than that of C60. Density functional theory calculations showed that the C-C bond is polarized, with a total charge of +0.84e located on the NHC framework and -0.84e delocalized on the C 60 cage. The combination of reactivity, characterization, and theoretical studies demonstrates that fullerenes can behave as Lewis acids that react with C-based Lewis bases and that the overall process describes n-doping via C-C bond formation. © 2011 American Chemical Society.
Roberts, Michael Scott
The Rayleigh-Taylor instability is a buoyancy driven instability that takes place in a stratified fluid system with a constant acceleration directed from the heavy fluid into the light fluid. In this study, both experimental data and numerical simulations are presented. Experiments are performed primarily using a lithium-tungstate aqueous solution as the heavy liquid, but sometimes a calcium nitrate aqueous solution is used for comparison purposes. Experimental data is obtained for both miscible and immiscible fluid combinations. For the miscible experiments the light liquid is either ethanol or isopropanol, and for the immiscible experiments either silicone oil or trans-anethole is used. The resulting Atwood number is either 0.5 when the lithium-tungstate solution is used or 0.2 when the calcium nitrate solution is used. These fluid combinations are either forced or left unforced. The forced experiments have an initial perturbation imposed by vertically oscillating the liquid containing tank to produce Faraday waves at the interface. The unforced experiments rely on random interfacial fluctuations, due to background noise, to seed the instability. The liquid combination is partially enclosed in a test section that is accelerated downward along a vertical rail system causing the Rayleigh-Taylor instability. Accelerations of approximately 1g (with a weight and pulley system) or 10g (with a linear induction motor system) are experienced by the liquids. The tank is backlit and digitally recorded with high speed video cameras. These experiments are then simulated with the incompressible, Navier-Stokes code Miranda. The main focus of this study is the growth parameter (α) of the mixing region produced by the instability after it has become apparently self-similar and turbulent. The measured growth parameters are compared to determine the effects of miscibility and initial perturbations (of the small wavelength, finite bandwidth type used here). It is found that while
Adaptive Channel Equalization Using Multiplicative Neural Network for Rayleigh Faded Channel
P. Sivakumar
2011-01-01
Full Text Available Problem statement: Digital transmission over band-limited communication channel largely suffers from ISIS and various noise sources. The presence of ISI and noise causes bit errors in the received signal. Equalization is necessary at the receiver to overcome these channel impairment to recover the original transmitted sequence. Traditionally equalization is considered as equivalent to inverse filtering and implemented using linear-perform under severe distortion conditions when Signal to Noise Ratio (SNR is poor. Equalization can be considered as a non-linear classification problem and optimum solution is given by Bayesian solution. Non-linear techniques like Artificial Neutral Networks (ANN are very good choice for non-linear classification problems. Several non-lines are equalizers have been implemented using ANN which outperformed LTE and solved the problem of equalization to the varying degree of sources. Approach: Forward neural network architecture with optimum number of nodes was used to achieve adaptive channel equalization. Summation at each node was replaced by multiplications which result in powerful mapping. The equalizer was tested on Rayleigh fading channel with a BPSK signal. Results: Results showed that proposed equalizer provides simplified architecture and improvement in the bit error rate at various levels of signal to noise ratio for Rayleigh faded channel. Conclusion: A high order feed forward network equalizer with multiplicative neuron is proposed in this study. Use of Multiplication allows direct computing of polynomial inputs and approximation with fewer nodes. Performance comparison in terms of network architecture and BER performance suggest the better classification capability of the proposed MNN equalizer over RRBF.
A general purpose exact Rayleigh scattering look-up table for ocean color remote sensing
无
2006-01-01
The current exact Rayleigh scattering calculation of ocean color remote sensing uses the look-up table (LUT), which is usually created for a special remote sensor and cannot be applied to other sensors. For practical application, a general purpose Rayleigh scattering LUT which can be applied to all ocean color remote sensors is generated. An adding-doubling method to solve the vector radiative transfer equation in the plane-parallel atmosphere is deduced in detail. Compared with the exact Rayleigh scattering radiance derived from the MODIS exact Rayleigh scattering LUT, it is proved that the relative error of Rayleigh scattering calculation with the adding-doubling method is less than 0.25%, which meets the required accuracy of the atmospheric correction of ocean color remote sensing. Therefore,the adding-doubling method can be used to generate the exact Rayleigh scattering LUT for the ocean color remote sensors. Finally, the general purpose exact Rayleigh scattering LUT is generated using the adding-doubling method. On the basis of the general purpose LUT, the calculated Rayleigh scattering radiance is tested by comparing with the LUTs of MODIS, SeaWiFS and the other ocean color sensors, showing that the relative errors are all less than 0.5%, and this general purpose LUT can be applied to all ocean color remote sensors.
Tao, Meilin; Xue, Lifang; Sun, Zhong; Wang, Shengtian; Wang, Xiaohong; Shi, Junyou
2015-09-01
In order to investigate the influences of Lewis metals on acidic properties and catalytic activities, a series of Keggin heteropolyacid (HPA) catalysts, HnPW11MO39 (M = TiIV, CuII, AlIII, SnIV, FeIII, CrIII, ZrIV and ZnII; for Ti and Zr, the number of oxygen is 40), were prepared and applied in the esterification and transesterification reactions. Only those cations with moderate Lewis acidity had a higher impact. Ti Substituted HPA, H5PW11TiO40, posse lower acid content compared with TixH3-4xPW12O40 (Ti partial exchanged protons in saturated H3PW12O40), which demonstrated that the Lewis metal as an addenda atom (H5PW11TiO40) was less efficient than those as counter cations (TixH3-4xPW12O40). On the other hand, the highest conversion reached 92.2% in transesterification and 97.4% in esterification. Meanwhile, a good result was achieved by H5PW11TiO40 in which the total selectivity of DAG and TGA was 96.7%. In addition, calcination treatment to H5PW11TiO40 make it insoluble in water which resulted in a heterogeneous catalyst feasible for reuse.
Noble, Florence; Benturquia, Nadia; Crete, Dominique; Canestrelli, Corinne; Mas Nieto, Magdalena; Wilson, Jodie; Roques, Bernard P
2012-05-01
A great number of studies have shown the presence of physiological interactions between brain neurotransmitter systems in behavioural responses. This is the case for opioid, cholecystokinin (CCK) and dopamine systems. However, so far the role that the CCK system may play in vulnerability to consumption of drugs of abuse is not clear. This was investigated in this study using Lewis rats that are more sensitive to the reinforcing properties of drugs of abuse than Fischer rats. The extraneuronal CCK(8) levels and brain CCK(2) receptors were found higher in Fischer than in Lewis rats in the nucleus accumbens, one of the most important structures involved in drug consumption. Moreover, pharmacological modulation of the CCK system by administration of a selective CCK(2) agonist blocked, in the conditioned place preference, the reinforcing effects of morphine in Lewis rats, whereas a selective CCK(2) antagonist revealed reinforcing effects of the alkaloid in Fischer rats. These results obtained following systemic administrations of the CCK ligands were confirmed following microinjection into the nucleus accumbens. Thus, a low level of CCK efflux in the nucleus accumbens could be one of the many factors involved in drug reinforcing effects, whereas a high level of CCK efflux could attenuate it.
Benabid, F.; Notcutt, M.; Ju, L.; Blair, D. G.
1999-10-01
We present the level of noise induced by Rayleigh-scattered light from sapphire test mass, the limit of scattering loss on build-up power inside the interferometer and finally the tolerable absorption loss in order to meet the specification of the interferometer sensitivity. The results show that the Rayleigh scattering induced noise remains below h˜10 -25 Hz -1/2 and a higher tolerance on the absorption level in sapphire substrate compared with silica substrate.
Lewis acid catalyzed transformations of Z-ligustilide
Rios, Maria Yolanda [Universidad Autonoma del Estado de Morelos, Cuernavaca, Morelos (Mexico); Delgado, Guillermo [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)
1999-08-01
Some Lewis acid mediated reactions of Z-ligustilide (1), a bioactive constituent of the medicinal species Ligusticum porteri, were investigated. These reactions provided varying mixtures of Z-butylidenephthalide (7), E-butylidenephthalide (8), n-butyphthalide (13), and novel linear dimeric phthalides (9-12) as the main products. The formation of the dimers occurred in low yields and with regio and situ-selectivity. Initial competitive O- and C- complexation of the Lewis acid with Z-ligustilide promoted the formation of the dimers occurred in low yields and with regio and situ- selectivity. Initial competitive O- and C- complexation of the Lewis acid with Z-ligustilide promoted the formation of carbocations at C(8), C(6) and C(7), which were stabilized by the addition of the C(6')-C(7') olefin of a second unit of the starting material, to provide cations at C(6') and C(7'). Subsequent isomerizations and elimination of the catalyst afforded the dimeric products 9-12. The yields and structure of the products are quite dependent on variations of the reaction conditions and the catalyst employed. [Spanish] Se investigaron algunas reacciones de Z-ligustilidas (1), un constituyente bioactivo de la planta medicinal Ligusticum porteri, catalizadas por acidos de Lewis. Estas reacciones produjeron mezclas variables de Z-butilidenftalida (7), E-butilidenftalida (8), n-butilftalida (13), y ftalidos dimetricos lineales novedosos (9-12) como productos principales. La formacion de los dimeros procedio en rendimientos bajos y con regio- y situ-selectividad. La O- y C- complejacion competitiva inicial del acido de Lewis con Z-lingustilida promueve la formacion de cationes en C(8), C(6) y C(7), los cuales son estabilizados por la adicion de la olefina C(6')-C(7') de una segunda unidad de la materia prima para generar los cationes en C(6')-C(7'). Isomerizaciones subsecuentes y la eliminacion del catalizador conducen a los productos dimericos 9
Rayleigh-type waves in nonlocal micropolar solid half-space.
Khurana, Aarti; Tomar, S K
2017-01-01
Propagation of Rayleigh type surface waves in nonlocal micropolar elastic solid half-space has been investigated. Two modes of Rayleigh-type waves are found to propagate under certain approximations. Frequency equations of these Rayleigh type modes and their conditions of existence have been derived. These frequency equations are found to be dispersive in character due to the presence of micropolarity and nonlocality parameters in the medium. One of the frequency equations is a counterpart of the classical Rayleigh waves and the other is new and has appeared due to micropolarity of the medium. Phase speeds of these waves are computed numerically for Magnesium crystal and their variation against wavenumber are presented graphically. Comparisons have been made between the phase speeds of Rayleigh type waves through nonlocal micropolar, local micropolar and elastic solid half-spaces. Copyright © 2016 Elsevier B.V. All rights reserved.
The propagation dynamics of ultraviolet light filament with Rayleigh scattering in air
Zhang Hua
2005-01-01
In this paper we present for the first time the effects of Rayleigh scattering on the long distance propagation of ultraviolet (UV) light filament in air based on the stationary analysis. The simulation results show that the effects of Rayleigh scattering on the propagation of UV laser filaments may not be ignored. These influences are slightly dependent on the laser wavelength. We also compare the UV filament propagations at different input powers in the presence and the absence of the Rayleigh scattering and discuss the mechanisms of power loss and beam defocusing.In the absence of Rayleigh scattering, the filament propagation is determined by the oscillating behaviour of the beam size. In the presence of the scattering, the propagation lengths of filament are close to each other at different initial powers and determined by the Rayleigh scattering.
Caffagni, Enrico; Cattaneo, Marco; Bordoni, Paola
2016-04-01
Spectral ratio techniques, such as the Horizontal-to-Vertical (HV) and Standard (SSR) may exhibit different trends in specific frequency bands when conducted in alluvial basins. A possible explanation of this discrepancy can be provided by the presence of Rayleigh oscillations, that are considered responsible of an amplification of the vertical component with respect to the horizontal. We propose a new methodology for the identification of Rayleigh waves arrivals, to test on small-size basins. With this procedure, candidate Rayleigh waves are localized in time-frequency domain on an instantaneous polarization plane which is constructed by defining the instantaneous maximum vertical and horizontal spectral amplitudes. Validation of the candidate Rayleigh arrivals is performed by evaluating the instantaneous ellipticity. This step yields to a quantitative measure of the polarization, providing an indicator of the Rayleigh contribution to ground motion. We tested this methodology in the Norcia basin (central Italy) using a 18 selected earthquakes (2.0 L'Aquila sequence (2009). We demonstrate the robustness of our methodology by localizing evidences of Rayleigh wave arrivals immediately from (1 s) up to 30 s after the first S-wave group, even for low-magnitude events (Ml < 3.0). The generation of the detected Rayleigh waves analyzed in time-frequency range, appears to be magnitude-dependent and in function of the location in the basin. Our quantitative estimate of the Rayleigh polarization resulted to be comparable to the HV response value in specific frequency bands, for example in deamplification, demonstrating a plausible connection with Rayleigh oscillations. The authors encourage the usage or implementation of similar procedures conducted in basin studies, in order to determine quantitatively the Rayleigh contribution to ground motion, for a better characterization of the local seismic response.
The Göttingen rotating turbulent Rayleigh-Bénard convection facility
Bodenschatz, Eberhard; van Gils, Dennis; He, Xiaozhou; Ahlers, Guenter; International CollaborationTurbulence Research, EuHIT Collaboration
2015-11-01
This presentation will focus on the newly commissioned rotating RBC facility at the Max Planck Institute for Dynamics and Self-Organization (MPIDS). The MPIDS has a pressure vessel, called the Uboot of Göttingen, which can house different RBC cells. By pressurizing the Uboot with sulfur hexafluoride, nitrogen, or helium up to 19 bars one can obtain Rayleigh numbers spanning 109 Uboot, on top of which the current RBC cell of aspect ratio 0.50 can be installed. The accessible parameter space is 0 . 02 < Ro-1 < 20 for the inverse Rossby number and 10-8 < Ek <10-3 for the Ekman number. At strong rotation (small Ek) but still turbulently convective (large Ra) one enters the geostrophic turbulent regime. Recent experiments involve measuring in and near this regime of which preliminary results will be shown and discussed. We thank the Max Planck Society, the German Science Foundation SFB 963, the NSF grant DMR11-58514, and EuHIT for generous support.
Effective Pincer Cobalt Precatalysts for Lewis Acid Assisted CO2 Hydrogenation.
Spentzos, Ariana Z; Barnes, Charles L; Bernskoetter, Wesley H
2016-08-15
The pincer ligand MeN[CH2CH2(P(i)Pr2)]2 ((iPr)PNP) was employed to support a series of cobalt(I) complexes, which were crystallographically characterized. A cobalt monochloride species, ((iPr)PNP)CoCl, served as a precursor for the preparation of several cobalt precatalysts for CO2 hydrogenation, including a cationic dicarbonyl cobalt complex, [((iPr)PNP)Co(CO)2](+). When paired with the Lewis acid lithium triflate, [((iPr)PNP)Co(CO)2](+) affords turnover numbers near 30 000 (at 1000 psi, 45 °C) for CO2-to-formate hydrogenation, which is a notable increase in activity from previously reported homogeneous cobalt catalysts. Though mechanistic information regarding the function of the precatalysts remains limited, multiple experiments suggest the active species is a molecular, homogeneous [((iPr)PNP)Co] complex.
Combined Lewis acid and Brønsted acid-mediated reactivity of glycosyl trichloroacetimidate donors.
Gould, Nathan D; Liana Allen, C; Nam, Brandon C; Schepartz, Alanna; Miller, Scott J
2013-12-15
Biomimetic conditions for a synthetic glycosylation reaction, inspired by the highly conserved functionality of carbohydrate active enzymes, were explored. At the outset, we sought to generate proof of principle for this approach to developing catalytic systems for glycosylation. However, control reactions and subsequent kinetic studies showed that a stoichiometric, irreversible reaction of the catalyst and glycosyl donor was occurring, with a remarkable rate variance depending upon the structure of the carboxylic acid. It was subsequently found that a combination of Brønsted acid (carboxylic acid) and Lewis acid (MgBr2) was unique in catalyzing the desired glycosylation reaction. Thus, it was concluded that the two acids act synergistically to catalyze the desired transformation. The role of the catalytic components was tested with a number of control reactions and based on these studies a mechanism is proposed herein. Copyright © 2013 Elsevier Ltd. All rights reserved.
Ernst, Beat; Müller, Dieter R.; Richter, Wilhelm J.
1997-01-01
Formation of "false" sugar sequence ions from branched tetrasaccharides of the sialyl-Lewis-type by migration of fucose towards sialic acid residues is shown to occur in [M + H]+ and [M + NH4]+ ions produced by electrospray ionization and subjected to low energy collision induced dissociation (CID). For the verification of their composition and sequence, such irregular ions were produced in the orifice region of the ion source, mass selected in Q1, and subjected to a second CID step in Q2 of a triple quadrupole analyser. When produced and analysed in the same "double CID" fashion, the branched B3 ions still containing all four sugar subunits show such migration to only a minor extent. The analysis of Bn fragment ions with high numbers for n may thus have advantages over the analysis of M-like species
Frustrated Lewis Pair Behavior of Intermolecular Annine/B(C6F5)(3) Pairs
Voss, Tanja; Mahdi, Tayseer; Otten, Edwin; Froehlich, Roland; Kehr, Gerald; Stephan, Douglas W.; Erker, Gerhard
2012-01-01
Reactions of N,N-dimethylaniline, N-isopropyl-aniline, 1,4-C6H4(CH(2)NHtBu)(2), and benzyldimethylamine with the Lewis acid B(C6F5)(3) have been studied. In the case of N,N-dirnethylaniline the combination of the Lewis acid and base forms an almost completely noninteracting frustrated Lewis pair, wh
Spectral Ratios for Crack Detection Using P and Rayleigh Waves
Enrique Olivera-Villaseñor
2012-01-01
Full Text Available We obtain numerical results to help the detection and characterization of subsurface cracks in solids by the application of P and Rayleigh elastic waves. The response is obtained from boundary integral equations, which belongs to the field of elastodynamics. Once the implementation of the boundary conditions has been done, a system of Fredholm integral equations of the second kind and order zero is found. This system is solved using the method of Gaussian elimination. Resonance peaks in the frequency domain allow us to infer the presence of cracks using spectral ratios. Several models of cracked media were analyzed, where effects due to different crack orientations and locations were observed. The results obtained are in good agreement with those published in the references.
Performance of Multicarrier CDMA Rake System over Rayleigh Fading Channel
SONG Li-xin; HUANG Tian-shu; DING Yao-ming
2005-01-01
Based on the theory of multicarrier (MC) technique and the Rake receiver, a multicarrier DSCDMA Rake system is proposed, where a data sequence multiplied by a spreading sequence modulates multiple carriers. The receiver provides a Rake for each subcarrier, and the outputs of the Rakes are combined by a maximal-ratio combiner. The average probability of error of the system is derived from an uncorrelated subcarrier and frequency-selective fading channel model. The system performances are evaluated over Rayleigh fading channel with an exponential multipath intensity profile(MIP) and with a rectangular MIP, respectively,when multipath interference is present. It is found that this kind of model has larger superiority in an exponential MIP than in a rectangular MIP.
Plasma transport driven by the Rayleigh-Taylor instability
Ma, X.; Delamere, P. A.; Otto, A.
2016-06-01
Two important differences between the giant magnetospheres (i.e., Jupiter's and Saturn's magnetospheres) and the terrestrial magnetosphere are the internal plasma sources and the fast planetary rotation. Thus, there must be a radially outward flow to transport the plasma to avoid infinite accumulation of plasma. This radial outflow also carries the magnetic flux away from the inner magnetosphere due to the frozen-in condition. As such, there also must be a radial inward flow to refill the magnetic flux in the inner magnetosphere. Due to the similarity between Rayleigh-Taylor (RT) instability and the centrifugal instability, we use a three-dimensional RT instability to demonstrate that an interchange instability can form a convection flow pattern, locally twisting the magnetic flux, consequently forming a pair of high-latitude reconnection sites. This process exchanges a part of the flux tube, thereby transporting the plasma radially outward without requiring significant latitudinal convection of magnetic flux in the ionosphere.
The magnetic Rayleigh-Taylor instability in astrophysical discs
Contopoulos, I.; Kazanas, D.; Papadopoulos, D. B.
2016-10-01
This is our first study of the magnetic Rayleigh-Taylor instability at the inner edge of an astrophysical disc around a central back hole. We derive the equations governing small-amplitude oscillations in general relativistic ideal magnetodydrodynamics and obtain a criterion for the onset of the instability. We suggest that static disc configurations where magnetic field is held by the disc material are unstable around a Schwarzschild black hole. On the other hand, we find that such configurations are stabilized by the space-time rotation around a Kerr black hole. We obtain a crude estimate of the maximum amount of poloidal magnetic flux that can be accumulated around the centre, and suggest that it is proportional to the black hole spin. Finally, we discuss the astrophysical implications of our result for the theoretical and observational estimations of the black hole jet power.
Coherent Rayleigh-Brillouin scattering as a flow diagnostic technique
Graul, J. S.; Lilly, T. C. [Department of Mechanical and Aerospace Engineering, University of Colorado Colorado Springs, 1420 Austin Bluffs Parkway, Colorado Springs, CO 80918 (United States)
2014-12-09
Broadband coherent Rayleigh-Brillouin scattering (CRBS) was used to measure translational gas temperatures for nitrogen at the ambient pressure of 0.8 atm using a purpose-built Fabry-Perot etalon spectrometer. Temperatures derived from the CRBS spectral analysis were compared with experimentally-measured temperatures, and were found to be, on average, within 2% of the experimentally-measured value. Axial flow velocities from a double jet at a pressure ratio of 0.38 were also measured by looking at the Doppler shift of the CRBS line shape. With recent developments in chirped laser technology and the capacity of CRBS to simultaneously provide thermodynamic and bulk flow information, the CRBS line shape acquisition and analysis technique presented here may allow for future time-resolved, characterization of aerospace flows.
Internally heated convection and Rayleigh-Bénard convection
Goluskin, David
2016-01-01
This Brief describes six basic models of buoyancy-driven convection in a fluid layer: three configurations of internally heated convection and three configurations of Rayleigh-Bénard convection. The author discusses the main quantities that characterize heat transport in each model, along with the constraints on these quantities. This presentation is the first to place the various models in a unified framework, and similarities and differences between the cases are highlighted. Necessary and sufficient conditions for convective motion are given. For the internally heated cases only, parameter-dependent lower bounds on the mean fluid temperature are proven, and results of past simulations and laboratory experiments are summarized and reanalyzed. The author poses several open questions for future study.
Performance of LTE ADVANCED Uplink in a Flat Rayleigh Channel
Edward Kasem
2013-01-01
Full Text Available This paper describes the performance of LTE advanced uplink transmission in a flat Rayleigh channel. The uplink is simulated using a modified version of the Vienna uplink link level matlab code simulator. This modified version supports two transmission antennas instead of one. Moreover, it includes two extra processes; layer mapping and precoding. In addition, the demodulation reference signal is presented and employed to allow channel estimation. In this paper, the structure of the LTE advanced system is described. Furthermore, we present generation of the demodulation reference signal. Four combinations of two distinct channel estimation and two signal detection methods are used to provide the simulation results of performance evaluation in term of the BER and throughput curves for selected scenarios.
Rayleigh-Taylor instability in accelerated solid media
Piriz, A. R.; Sun, Y. B.; Tahir, N. A.
2017-01-01
A linear study of the Rayleigh-Taylor instability based on momentum conservation and the consideration of an irrotational velocity field for incompressible perturbations is discussed. The theory allows for a very appealing physical picture and for a relatively simple description of the main features of the instability. As a result, it is suitable for the study of the very complex problem of the instability of accelerated solids with non-linear elastic-plastic constitutive properties, which cannot be studied by the usual normal modes approach. The elastic to plastic transition occurring early in the instability process determines the entire evolution and makes the instability exhibit behavior that cannot be captured by an asymptotic analysis.
Rayleigh-Taylor instability in soft elastic layers
Riccobelli, D.; Ciarletta, P.
2017-04-01
This work investigates the morphological stability of a soft body composed of two heavy elastic layers attached to a rigid surface and subjected only to the bulk gravity force. Using theoretical and computational tools, we characterize the selection of different patterns as well as their nonlinear evolution, unveiling the interplay between elastic and geometric effects for their formation. Unlike similar gravity-induced shape transitions in fluids, such as the Rayleigh-Taylor instability, we prove that the nonlinear elastic effects saturate the dynamic instability of the bifurcated solutions, displaying a rich morphological diagram where both digitations and stable wrinkling can emerge. The results of this work provide important guidelines for the design of novel soft systems with tunable shapes, with several applications in engineering sciences. This article is part of the themed issue 'Patterning through instabilities in complex media: theory and applications.'
THE RAYLEIGH-TAYLOR INSTABILITY IN SMALL ASPECT RATIO CONTAINERS
RIVERA, MICHAEL K. [Los Alamos National Laboratory; ECKE, ROBERT E. [Los Alamos National Laboratory
2007-01-22
We present experimental measurements of density and velocity obtained from the mixing zone of buoyancy driven turbulence initiated by the Rayleigh-Taylor instability in a small aspect ration chamber (a chamber who's vertical height is significantly larger than its lateral dimesion). The mixing front propogates at a slightly slower rate than the expected t{sup 2} behavior obtained from earlier experiments and numerics. Once the front has propogated significantly far away, we observe that the mixing zone develops to a statistically stationary state. In this stationary state, the spectral distributions of energy and density deviate from the familiar k{sup -5/3} ubiquitous to turbulence in three dimensions.
DSMC simulation of Rayleigh-Brillouin scattering in binary mixtures
Bruno, Domenico; Frezzotti, Aldo; Ghiroldi, Gian Pietro
2016-11-01
Rayleigh-Brillouin scattering spectra (RBS) in dilute gas mixtures have been simulated by the Direct Simulation Monte Carlo method (DSMC). Different noble gas binary mixtures have been considered and the spectra have been simulated adopting the hard sphere collision model. It is suggested that DSMC simulations can be used in the interpretation of light scattering experiments in place of approximate kinetic models. Actually, the former have a firmer physical ground and can be readily extended to treat gas mixtures of arbitrary complexity. The results obtained confirm the capability of DSMC to predict experimental spectra and clears the way towards the simulation of polyatomic gas mixtures of interest for actual application (notably, air) where tractable kinetic model equations are still lacking.
Non-stationary Rayleigh-Taylor instability in supernovae ejecta
Ribeyre, X; Tikhonchuk, V T; Bouquet, S; Sanz, J; Ribeyre, Xavier; Hallo, Ludovic; Tikhonchuk, Vladimir; Bouquet, Serge; Sanz, Javier
2005-01-01
The Rayleigh-Taylor instability plays an important role in the dynamics of several astronomical objects, in particular, in supernovae (SN) evolution. In this paper we develop an analytical approach to study the stability analysis of spherical expansion of the SN ejecta by using a special transformation in the co-moving coordinate frame. We first study a non-stationary spherical expansion of a gas shell under the pressure of a central source. Then we analyze its stability with respect to a no radial, non spherically symmetric perturbation of the of the shell. We consider the case where the polytropic constant of the SN shell is $\\gamma=5/3$ and we examine the evolution of a arbitrary shell perturbation. The dispersion relation is derived. The growth rate of the perturbation is found and its temporal and spatial evolution is discussed. The stability domain depends on the ejecta shell thickness, its acceleration, and the perturbation wavelength.
Rayleigh-Taylor instability in partially ionized prominence plasma
Khomenko, E; de Vicente, A; Collados, M; Luna, M
2013-01-01
We study Rayleigh-Taylor instability (RTI) at the coronal-prominence boundary by means of 2.5D numerical simulations in a single-fluid MHD approach including a generalized Ohm's law. The initial configuration includes a homogeneous magnetic field forming an angle with the direction in which the plasma is perturbed. For each field inclination we compare two simulations, one for the pure MHD case, and one including the ambipolar diffusion in the Ohm's law, otherwise identical. We find that the configuration containing neutral atoms is always unstable. The growth rate of the small-scale modes in the non-linear regime is larger than in the purely MHD case.
The cylindrical magnetic Rayleigh-Taylor instability for viscous fluids
Chambers, K.; Forbes, L. K. [School of Mathematics and Physics, University of Tasmania, Private Bag 37-Hobart, Tasmania 7005 (Australia)
2012-10-15
This paper considers a cylindrical Rayleigh-Taylor instability, in which a heavy fluid surrounds a light fluid, and gravity is directed radially inwards. A massive object is located at the centre of the light fluid, and it behaves like a line dipole both for fluid flow and magnetic field strength. The initially circular interface between the two conducting fluids evolves into plumes, dependent on the magnetic and fluid dipole strengths and the nature of the initial disturbance to the interface. A spectral method is presented to solve the time-dependent interface shapes, and results are presented and discussed. Bipolar solutions are possible, and these are of particular relevance to astrophysics. The solutions obtained resemble structures of some HII regions and nebulae.
Rayleigh-Taylor stabilization by material strength at Mbar pressures
Remington, Bruce; Park, Hye-Sook; Lorenz, Thomas; Cavallo, Robert; Pollaine, Stephen; Prisbrey, Shon; Rudd, Robert; Becker, Richard; Bernier, Joel
2009-11-01
We present experiments on the Rayleigh-Taylor (RT) instability in the plastic flow regime of solid-state vanadium (V) foils at 1 Mbar pressures and strain rates of 1.e6-1.e8 1/s, using a laser based, ramped-pressure acceleration technique. High pressure material strength causes strong stabilization of the RT instability at short wavelengths. Comparisons with 2D simulations utilizing models of high pressure strength show that the V strength increases by factors of 3-4 at peak pressure, compared to its ambient strength. An effective lattice viscosity of 400 poise would have a similar effect. [1] Constitutive models, and theoretical implications of these experiments will be discussed. [1] H.S. Park, B.A. Remington et al., submitted for publication (July, 2009).
Rayleigh wave scattering at the foot of a mountain
P. S. Deshwal
1987-01-01
Full Text Available A theoretical study of scattering of seismic waves at the foot of a mountain is discussed here. A mountain of an arbitrary shape and of width a (0≤x≤a, z=0 in the surface of an elastic solid medium (z≥0 is hit by a Rayleigh wave. The method of solution is the technique of Wiener and Hopf. The reflected, transmitted and scattered waves are obtained by inversion of Fourier transforms. The scattered waves behave as decaying cylindrical waves at distant points and have a large amplitude near the foot of the mountain. The transmitted wave decreases exponentially as its distance from the other end of the mountain increases.
Magneto-Rayleigh-Taylor growth and feedthrough in cylindrical liners
Weis, Matthew; Lau, Y. Y.; Gilgenbach, Ronald; Peterson, Kyle; Hess, Mark
2013-10-01
Cylindrical liner implosions in the MagLIF concept are susceptible to the magneto-Rayleigh-Taylor instability (MRT). The linearized ideal MHD equations are solved, including the presence of an axial magnetic field and the effects of sausage and kink modes. The eigenmode solution, using appropriate equilibrium profiles, allows an assessment of the local MRT growth rate and of the instantaneous feedthrough factor during the entire implosion process. Of particular interest will be the high convergence/stagnation phase, which is difficult to image experimentally. Strong axial magnetic fields can mitigate feedthrough and MRT growth, which may be useful at the fuel/liner interface during this phase of the MagLIF implosion. For the MRT growth rate and feedthrough factors, the LLNL code, HYDRA, is used to benchmark with the analytic theory, and with experiments on the Z-machine. This work was supported by DoE and NSF.
The Magnetic Rayleigh-Taylor Instability in Astrophysical Discs
Contopoulos, I.; Kazanas, D.; Papadopoulos, D. B.
2016-01-01
This is our first study of the magnetic Rayleigh-Taylor instability at the inner edge of an astrophysical disc around a central back hole. We derive the equations governing small-amplitude oscillations in general relativistic ideal magnetodydrodynamics and obtain a criterion for the onset of the instability. We suggest that static disc configurations where magnetic field is held by the disc material are unstable around a Schwarzschild black hole. On the other hand, we find that such configurations are stabilized by the space-time rotation around a Kerr black hole. We obtain a crude estimate of the maximum amount of poloidal magnetic flux that can be accumulated around the centre, and suggest that it is proportional to the black hole spin. Finally, we discuss the astrophysical implications of our result for the theoretical and observational estimations of the black hole jet power.
Collisional effects on Rayleigh-Taylor-induced magnetic fields
Manuel, M. J.-E. [University of Michigan, Ann Arbor, Michigan 48109 (United States); Flaig, M.; Plewa, T. [Florida State University, Tallahassee, Florida 32306 (United States); Li, C. K.; Séguin, F. H.; Frenje, J. A.; Casey, D. T.; Petrasso, R. D. [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Hu, S. X.; Betti, R.; Hager, J.; Meyerhofer, D. D.; Smalyuk, V. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)
2015-05-15
Magnetic-field generation from the Rayleigh-Taylor (RT) instability was predicted more than 30 years ago, though experimental measurements of this phenomenon have only occurred in the past few years. These pioneering observations demonstrated that collisional effects are important to B-field evolution. To produce fields of a measurable strength, high-intensity lasers irradiate solid targets to generate the nonaligned temperature and density gradients required for B-field generation. The ablation process naturally generates an unstable system where RT-induced magnetic fields form. Field strengths inferred from monoenergetic-proton radiographs indicate that in the ablation region diffusive effects caused by finite plasma resistivity are not negligible. Results from the first proof-of-existence experiments are reviewed and the role of collisional effects on B-field evolution is discussed in detail.
Lewis Carrol: la lógica de la imaginación
Cadavid, Jorge Hernando; Pontificia Universidad Javeriana, Bogotá
2014-01-01
Lewis Carroll es el seudónimo del autor de Alice 's Adventures in Wonderland! (Las aventuras de Alicia en el País de !as Maravillas), cyo nombre real era Charles Lutwidge Dodgson. El seudommo fue construido con los nombresde pila: Lutwidge-Lewis y Charles-Carroll (los tradujo primero al latín: Carolus yLudovico; invirtió el orden y volvió a traducirlos al inglés: Lewis Carroll). En verdad,Lewis Carroll era su alter ego: un domesticador de serpientes y sapos, prestidigitador(por arte de birlib...
Yazaki, Ryo; Kumagai, Naoya; Shibasaki, Masakatsu
2010-04-21
We report that a hard Lewis base substantially affects the reaction efficiency of direct catalytic asymmetric gamma-addition of allyl cyanide (1a) to ketones promoted by a soft Lewis acid/hard Brønsted base catalyst. Mechanistic studies have revealed that Cu/(R,R)-Ph-BPE and Li(OC(6)H(4)-p-OMe) serve as a soft Lewis acid and a hard Brønsted base, respectively, allowing for deprotonative activation of 1a as the rate-determining step. A ternary catalytic system comprising a soft Lewis acid/hard Brønsted base and an additional hard Lewis base, in which the basicity of the hard Brønsted base Li(OC(6)H(4)-p-OMe) was enhanced by phosphine oxide (the hard Lewis base) through a hard-hard interaction, outperformed the previously developed binary soft Lewis acid/hard Brønsted base catalytic system, leading to higher yields and enantioselectivities while using one-tenth the catalyst loading and one-fifth the amount of 1a. This second-generation catalyst allows efficient access to highly enantioenriched tertiary alcohols under nearly ideal atom-economical conditions (0.5-1 mol % catalyst loading and a substrate molar ratio of 1:2).
Reduced CSF CART in dementia with Lewy bodies
Schultz, Kristofer; Wiehager, Sara; Nilsson, Karin
2009-01-01
Dementia with Lewy bodies (DLB) is the second most common form of neurodegenerative dementia after Alzheimer's disease (AD). The underlying neurobiological mechanism of DLB is not fully understood and no generally accepted biomarkers are yet available for the diagnosis of DLB. In a recent MRI study......, DLB patients displayed hypothalamic atrophy whereas this region was not affected in AD patients. Cocaine and amphetamine regulated transcript (CART) is a neuropeptide expressed selectively in neurons in the hypothalamus. Here, we found that CSF CART levels were significantly reduced by 30% in DLB...
Telecommuting (Work-At-Home) at NASA Lewis Research Center
Srinidhi, Saragur M.
1994-01-01
This report presents a study in evaluating the viability of providing a work-at-home (telecommuting) program for Lewis Research Center's corporate employees using Integrated Services Digital Network (ISDN). Case studies have been presented for a range of applications from casual data access to interactive access. The network performance of telemedia applications were studied against future requirements for such level of remote connectivity. Many of the popular ISDN devices were characterized for network and service functionality. A set of recommendations to develop a telecommuting policy have been proposed.
Feminine Hypostases in Epic Fantasy: Tolkien, Lewis, Rowling
Măcineanu Laura
2015-12-01
Full Text Available The paper identifies the types of female figures present in the works of three well-known fantasy writers, J.R.R. Tolkien, C.S. Lewis and J.K. Rowling, discussing the ways in which these characters are presented, their relationship with other characters, and their role in the economy of the novel, which is more important than may appear from a first reading. It also tries to explain the reasons that prompted the above-mentioned authors to choose these female hypostases.
Sub-Rayleigh ghost imaging via sparsity constraints based on a digital micro-mirror device
Chen, Jie; Gong, Wenlin, E-mail: gongwl@siom.ac.cn; Han, Shensheng, E-mail: sshan@mail.shcnc.ac.cn
2013-10-30
In a diffraction-limited system, the imaging resolution limit is given by Rayleigh criterion. When both the image's sparsity and the point spread function determined by the optical system's Rayleigh diffraction limit are taken as popular a priori, sub-Rayleigh ghost imaging, which is backed up by numerical simulation and experiments, is achieved by modulating the thermal light with a digital micro-mirror device (DMD). The differences between this approach and former ghost imaging without considering the optical system's point spread function are also discussed.
Zhan-Wu Yu; Ying-Hua Ju; Cheng-Liang Yang; Han-Bing Yu; Quan Luo; Ye-Gang Ma; Yong-Yu Liu
2015-01-01
Objective:To observe the antitumor effect and mechanism of recombinant human endostatin (Endostar) injection in tumor combined with intraperitoneal injection of cisplatin on subcutaneous transplanted Lewis lung cancer in rats.Methods:A total of 30 C57 rats were selected, and the monoplast suspension of Lewis lung cancer was injected into the left axilla to prepare the subcutaneous transplanted tumor models in the axilla of right upper limb. The models were randomly divided into Groups A, B, and C. Medication was conducted when the tumor grew to 400 mm3. Group A was the control group without any interventional treatment. Group B was injected with Endostar 5 mg.kg-1.d for 10 d. Group C was given the injection of Endostar 5 mg.kg-1.d combined with intraperitoneal injection of cisplatin 5 mg.kg-1.d for 10 d. All the rats in three groups were executed the day after the 10-d medication and the tumor was taken off for measurement of volume and mass changes and calculation of antitumor rate, after which the vascular endothelial growth factor (VEGF) concentration in rats’plasma was determined by ELISA. The tumor tissues were cut for the preparation of conventional biopsies. After hematoxylin-eosin staining, the pathologic histology was examined to observe the structures of tumor tissues, VEGF score and microvessel density (MVD) in each group. Results:The volume and mass of tumor in Groups B and C were significantly lower than Group A (P< 0.05) while the tumor volume and mass in Group C were significantly lower than Group B (P < 0.05). The antitumor rate in Group C was significantly higher than Group B (P < 0.05), but the tumor VEGF score, MVD and plasma VEGF level in Group C were significantly lower than Groups A and B (P < 0.05). In Group B, the tumor VEGF score, MVD and plasma VEGF level were significantly lower than Group A (P < 0.05). The microscopic image of Group C showed that its number of active tumor cells and the blood capillary around tumor was significantly
Apparatus for real-time acoustic imaging of Rayleigh-Bénard convection
Kuehn, Kerry, K.
2008-10-28
We have successfully designed, built and tested an experimental apparatus which is capable of providing the first real-time ultrasound images of Rayleigh-B\\'{e}nard convection in optically opaque fluids confined to large aspect ratio experimental cells. The apparatus employs a modified version of a commercially available ultrasound camera to capture images (30 frames per second) of flow patterns in a fluid undergoing Rayleigh Bénard convection. The apparatus was validated by observing convection rolls in 5cSt polydimethylsiloxane (PDMS) polymer fluid. Our first objective, after having built the apparatus, was to use it to study the sequence of transitions from diffusive to time--dependent heat transport in liquid mercury. The aim was to provide important information on pattern formation in the largely unexplored regime of very low Prandtl number fluids. Based on the theoretical stability diagram for liquid mercury, we anticipated that straight rolls should be stable over a range of Rayleigh numbers, between 1708 and approximately 1900. Though some of our power spectral densities were suggestive of the existence of weak convection, we have been unable to unambiguously visualize stable convection rolls above the theoretical onset of convection in liquid mercury. Currently, we are seeking ways to increase the sensitivity of our apparatus, such as (i) improving the acoustic impedance matching between our materials in the ultrasound path and (ii) reducing the noise level in our acoustic images due to turbulence and cavitation in the cooling fluids circulating above and below our experimental cell. If we are able to convincingly improve the sensitivity of our apparatus, and we still do not observe stable convection rolls in liquid mercury, then it may be the case that the theoretical stability diagram requires revision. In that case, either (i) straight rolls are not stable in a large aspect ratio cell at the Prandtl numbers associated with liquid mercury, or (ii
Transitional boundary layers in low-Prandtl-number convection
Schumacher, Jörg; Bandaru, Vinodh; Pandey, Ambrish; Scheel, Janet D.
2016-12-01
The boundary layer structure of the velocity and temperature fields in turbulent Rayleigh-Bénard flows in closed cylindrical cells of unit aspect ratio is revisited from a transitional and turbulent viscous boundary layer perspective. When the Rayleigh number is large enough, the dynamics at the bottom and top plates can be separated into an impact region of downwelling plumes, an ejection region of upwelling plumes, and an interior region away from the side walls. The latter is dominated by the shear of the large-scale circulation (LSC) roll, which fills the whole cell and continuously varies its orientation. The working fluid is liquid mercury or gallium at a Prandtl number Pr=0.021 for Rayleigh numbers 3 ×105≤Ra≤4 ×108 . The generated turbulent momentum transfer corresponds to macroscopic flow Reynolds numbers with 1.8 ×103≤Re≤4.6 ×104 . In highly resolved spectral element direct numerical simulations, we present the mean profiles of velocity, Reynolds stress, and temperature in inner viscous units and compare our findings with convection experiments and channel flow data. The complex three-dimensional and time-dependent structure of the LSC in the cell is compensated by a plane-by-plane symmetry transformation which aligns the horizontal velocity components and all its derivatives with the instantaneous orientation of the LSC. As a consequence, the torsion of the LSC is removed, and a streamwise direction in the shear flow can be defined. It is shown that the viscous boundary layers for the largest Rayleigh numbers are highly transitional and obey properties that are directly comparable to transitional channel flows at friction Reynolds numbers Reτ≲102 . The transitional character of the viscous boundary layer is also underlined by the strong enhancement of the fluctuations of the wall stress components with increasing Rayleigh number. An extrapolation of our analysis data suggests that the friction Reynolds number Reτ in the velocity boundary
Chelli, Ali
2014-11-01
In this paper, we study the performance of hybrid automatic repeat request (HARQ) with incremental redundancy over double Rayleigh channels, a common model for the fading amplitude of vehicle-to-vehicle communication systems. We investigate the performance of HARQ from an information theoretic perspective. Analytical expressions are derived for the \\\\epsilon-outage capacity, the average number of transmissions, and the average transmission rate of HARQ with incremental redundancy assuming a maximum number of HARQ rounds. Moreover, we evaluate the delay experienced by Poisson arriving packets for HARQ with incremental redundancy. We provide analytical expressions for the expected waiting time, the packet\\'s sojourn time in the queue, the average consumed power, and the energy efficiency. In our study, the communication rate per HARQ round is adjusted to the average signal-to-noise ratio (SNR) such that a target outage probability is not exceeded. This setting conforms with communication systems in which a quality of service is expected regardless of the channel conditions. Our analysis underscores the importance of HARQ in improving the spectral efficiency and reliability of communication systems. We demonstrate as well that the explored HARQ scheme achieves full diversity. Additionally, we investigate the tradeoff between energy efficiency and spectral efficiency.
Zaitsev, V. V.; Kronshtadtov, P. V.; Stepanov, A. V.
2016-11-01
Within the framework of the long-standing so-called "number problem" in the physics of solar flares, we consider the excitation of a super-Dreicer electric field at the leading edge of the electric current pulse that occurs at the chromospheric legs of a coronal magnetic loop as a result of the magnetic Rayleigh-Taylor instability. It is shown that for a sufficiently strong electric current, I0 ≥ 10^{10} A, the current pulse propagates in the non-linear mode and generates a strong longitudinal electric field Ez, which strongly depends on the current (Ez ∝ I03) and can exceed the Dreicer field (Ez > ED). In this case, the bulk of electrons in the site of the current pulse is in a runaway mode, and the energy release rate in the chromosphere increases significantly. Super-Dreicer electric fields also provide injection of protons into the regime of acceleration by Langmuir turbulence generated by fast electrons at the leading edge of the electric current pulse. The electric field at the pulse edge can exceed the Dreicer field starting from the chromosphere level with the number density n ≈ 10^{13} cm^{-3}. At a lower current I0 < 10^{10} A, a super-Dreicer mode at the higher levels of the chromosphere with n < 10^{12} cm^{-3} occurs.
Zaitsev, V. V.; Kronshtadtov, P. V.; Stepanov, A. V.
2016-09-01
Within the framework of the long-standing so-called "number problem" in the physics of solar flares, we consider the excitation of a super-Dreicer electric field at the leading edge of the electric current pulse that occurs at the chromospheric legs of a coronal magnetic loop as a result of the magnetic Rayleigh-Taylor instability. It is shown that for a sufficiently strong electric current, I0 ≥ 10^{10} A, the current pulse propagates in the non-linear mode and generates a strong longitudinal electric field Ez, which strongly depends on the current ( Ez ∝ I03) and can exceed the Dreicer field ( Ez > ED). In this case, the bulk of electrons in the site of the current pulse is in a runaway mode, and the energy release rate in the chromosphere increases significantly. Super-Dreicer electric fields also provide injection of protons into the regime of acceleration by Langmuir turbulence generated by fast electrons at the leading edge of the electric current pulse. The electric field at the pulse edge can exceed the Dreicer field starting from the chromosphere level with the number density n ≈ 10^{13} cm^{-3}. At a lower current I0 < 10^{10} A, a super-Dreicer mode at the higher levels of the chromosphere with n < 10^{12} cm^{-3} occurs.
On hot-wire diagnostics in Rayleigh-Taylor mixing layers
Kraft, Wayne N. [Texas A and M University, Department of Mechanical Engineering, College Station, TX (United States); Banerjee, Arindam [Missouri University of Science and Technology, Department of Mechanical and Aerospace Engineering, Rolla, MO (United States); Andrews, Malcolm J. [Texas A and M University, Department of Mechanical Engineering, College Station, TX (United States); Los Alamos National Laboratory, NM (United States)
2009-07-15
Two hot-wire flow diagnostics have been developed to measure a variety of turbulence statistics in the buoyancy driven, air-helium Rayleigh-Taylor mixing layer. The first diagnostic uses a multi-position, multi-overheat (MPMO) single wire technique that is based on evaluating the wire response function to variations in density, velocity and orientation, and gives time-averaged statistics inside the mixing layer. The second diagnostic utilizes the concept of temperature as a fluid marker, and employs a simultaneous three-wire/cold-wire anemometry technique (S3WCA) to measure instantaneous statistics. Both of these diagnostics have been validated in a low Atwood number (A{sub t}{<=} 0.04), small density difference regime, that allowed validation of the diagnostics with similar experiments done in a hot-water/cold-water water channel facility. Good agreement is found for the measured growth parameters for the mixing layer, velocity fluctuation anisotropy, velocity fluctuation p.d.f behavior, and measurements of molecular mixing. We describe in detail the MPMO and S3WCA diagnostics, and the validation measurements in the low Atwood number regime (A{sub t}{<=} 0.04). We also outline the advantages of each technique for measurement of turbulence statistics in fluid mixtures with large density differences. (orig.)
Viscous effects on the Rayleigh-Taylor instability with background temperature gradient
Gerashchenko, S
2016-01-01
The growth rate of the compressible Rayleigh-Taylor instability is studied in the presence of a background temperature gradient, $\\Theta$, using a normal mode analysis. The effect of $\\Theta$ variation is examined for three interface types corresponding to combinations of the viscous properties of the fluids (inviscid-inviscid, viscous-viscous and viscous-inviscid) at different Atwood numbers, $At$, and, when at least one of the fluids' viscosity is non-zero, as a function of the Grashof number. For the general case, the resulting ordinary differential equations are solved numerically; however, dispersion relations for the growth rate are presented for several limiting cases. An analytical solution is found for the inviscid-inviscid interface and the corresponding dispersion equation for the growth rate is obtained in the limit of a large $\\Theta$. For the viscous-inviscid case, a dispersion relation is derived in the incompressible limit and $\\Theta=0$. Compared to $\\Theta=0$ case, the role of $\\Theta0$ (col...
Scaling of large-scale quantities in Rayleigh-B\\'enard convection
Pandey, Ambrish
2016-01-01
We derive a formula for the P\\'eclet number ($\\mathrm{Pe}$) by estimating the relative strengths of various terms of the momentum equation. Using direct numerical simulations in three dimensions we show that in the turbulent regime, the fluid acceleration is dominated by the pressure gradient, with relatively small contributions arising from the buoyancy and the viscous term, in the viscous regime, acceleration is very small due to a balance between the buoyancy and the viscous term. Our formula for $\\mathrm{Pe}$ describes the past experiments and numerical data quite well. We also show that the ratio of the nonlinear term and the viscous term is $\\mathrm{Re} \\mathrm{Ra}^{-0.14}$, where $\\mathrm{Re}$ and $\\mathrm{Ra}$ are Reynolds and Rayleigh numbers respectively, and that the viscous dissipation rate $\\epsilon_u = (U^3/d) \\mathrm{Ra}^{-0.21}$, where $U$ is the root mean square velocity and $d$ is the distance between the two horizontal plates. The aforementioned decrease in nonlinearity compared to free tur...
Adjoint-based approach to Enhancing Mixing in Rayleigh-Taylor Turbulence
Kord, Ali; Capecelatro, Jesse
2016-11-01
A recently developed adjoint method for multi-component compressible flow is used to measure sensitivity of the mixing rate to initial perturbations in Rayleigh-Taylor (RT) turbulence. Direct numerical simulations (DNS) of RT instabilities are performed at moderate Reynolds numbers. The DNS are used to provide an initial prediction, and the corresponding space-time discrete-exact adjoint provides a sensitivity gradient for a specific quantity of interest (QoI). In this work, a QoI is defined based on the time-integrated scalar field to quantify the mixing rate. Therefore, the adjoint solution is used to measure sensitivity of this QoI to a set of initial perturbations, and inform a gradient-based line search to optimize mixing. We first demonstrate the adjoint approach in the linear regime and compare the optimized initial conditions to the expected values from linear stability analysis. The adjoint method is then used in the high Reynolds number limit where theory is no longer valid. Finally, chaos is known to contaminate the accuracy of the adjoint gradient in turbulent flows when integrated over long time horizons. We assess the influence of chaos on the accuracy of the adjoint gradient to guide the work of future studies on adjoint-based sensitivity of turbulent mixing. PhD Student, Department of Mechanical Engineering, University of Michigan, Ann Arbor, MI.
Three-Dimensional DSMC Simulations of the Rayleigh-Taylor Instability in Gases
Koehler, T. P.; Gallis, M. A.; Torczynski, J. R.; Plimpton, S. J.
2016-11-01
The Direct Simulation Monte Carlo (DSMC) method of molecular gas dynamics is applied to simulate the Rayleigh-Taylor instability (RTI) in atmospheric-pressure monatomic gases (e.g., argon and helium). The computational domain is a 1-mm by 1-mm by 4-mm cuboid uniformly divided into 62.5 billion cubical cells. A total of 1 trillion computational molecules are used, and time steps of 0.1 ns are used. Simulations are performed to quantify the growth of perturbations on an initially flat interface as a function of the Atwood number. The DSMC results reproduce many features of the RTI and are in reasonable agreement with theoretical and empirical models. Consistent with previous work, the DSMC simulations indicate that the growth of the RTI follows a universal behavior. The numbers of bubble-spike pairs that eventually appear agree with theoretical values based on the most unstable wavelength and are independent of the statistical representation of the gas. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.