WorldWideScience

Sample records for ratio infrared spectrometer

  1. Development and Airborne Operation of a Compact Water Isotope Ratio Infrared Spectrometer

    Science.gov (United States)

    Iannone, Rosario Q.; Kassi, Samir; Jost, Hans-Juerg; Chenevier, Marc; Romanini, Daniele; Meijer, Harro A. J.; Dhaniyala, Suresh; Snels, Marcel; Kerstel, Erik R. T.

    2009-01-01

    A sensitive laser spectrometer, named IRIS (water isotope ratio infrared spectrometer), was developed for the in situ detection of the isotopic composition of water vapour in the upper troposphere and the lower stratosphere. Isotope ratio measurements can be used to quantify troposphere stratosphere exchange, and to study the water chemistry in the stratosphere. IRIS is based on the technique of optical feedback cavity-enhanced absorption spectroscopy. It uses a room temperature near-infrared laser, and does not require cryogenic cooling of laser or detectors. The instrument weighs 51 kg including its support structure. Airborne operation was demonstrated during three flights aboard the European M55-Geophysica stratospheric research aircraft, as part of the AMMA/SCOUT-03 (African Monsoon Multidisciplinary Analysis/Stratospheric Climate links with emphasis on the Upper Troposphere and lower stratosphere) campaign in Burkina Faso in August 2006. The data are discussed with reference to a Rayleigh distillation model. As expected, there is no indication of non-mass-dependent fractionation (also known as mass-independent fractionation) in the troposphere. Furthermore, improvements to the thermal management system and a move to a (cryogen-free) longer-wavelength laser source are discussed, which together should result in approximately two orders of magnitude improvement of the sensitivity

  2. On-site isotopic analysis of dissolved inorganic carbon using an isotope ratio infrared spectrometer

    Science.gov (United States)

    Stoltmann, Tim; Mandic, Magda; Stöbener, Nils; Wapelhorst, Eric; Aepfler, Rebecca; Hinrichs, Kai-Uwe; Taubner, Heidi; Jost, Hj; Elvert, Marcus

    2016-04-01

    An Isotope Ratio Infrared Spectrometer (IRIS) has been adapted to perform measurements of δ13C of dissolved inorganic carbon (DIC) in marine pore waters. The resulting prototype allowed highly automated analysis of δ13C isotopic ratios and CO2 concentration. We achieved a throughput of up to 70 samples per day with DIC contents as low as 1.7 μmol C. We achieved an internal precision of 0.066 ‰ and an external precision of 0.16 ‰, which is comparable to values given for Isotope Ratio Mass Spectrometers (IRMS). The prototype instrument is field deployable, suitable for shipboard analysis of deep sea core pore waters. However, the validation of the prototype was centered around a field campaign in Eckernförde Bay, NW- Baltic Sea. As a proof of concept, a shallow site within an area of submarine groundwater discharge (SGD) and a site outside this area was investigated. We present profiles of δ13C of DIC over 50 cm exhibiting well understood methane turnover processes (anaerobic oxidation of methane). At the lowest point below the seafloor, microbial reduction of CO2 to CH4 dominates. 12CO2 is reduced preferentially over 13CO2, leading to more positive δ13C values in the remaining DIC pool; in layers closer to the surface, the oxidation of CH4 to CO2 becomes more prominent. Since the CH4 pool is enriched in 12C a shift to more negative δ13C can be observed in the DIC pool. In the upper 15 cm, the pore water DIC mixes with the sea water DIC, increasing δ13C again. Finally, we will present recent developments to further improve performance and future plans for deployments on research cruises.

  3. A Widely Tunable Infrared Laser Spectrometer for Measurements of Isotopic Ratios of Carbon Cycle Gases

    Energy Technology Data Exchange (ETDEWEB)

    Joanne H. Shorter; J. Barry McManus; David D. Nelson; Charles E. Kolb; Mark S. Zahniser; Ray Bambha; Uwe Lehmann; Tomas Kulp; Stanley C. Tyler

    2005-01-31

    The atmospheric abundances of carbon dioxide and methane have increased dramatically during the industrial era. Measurements of the isotopic composition of these gases can provide a powerful tool for quantifying their sources and sinks. This report describes the development of a portable instrument for isotopic analysis CO{sub 2} and CH{sub 4} using tunable infrared laser absorption spectroscopy. This instrument combines novel optical design and signal processing methods with a widely tunable mid-infrared laser source based on difference frequency generation (DFG) which will can access spectral regions for all the isotopes of CO{sub 2} and CH{sub 4} with a single instrument. The instrument design compensates for the large difference in concentration between major and minor isotopes by measuring them with path lengths which differ by a factor of 100 within the same multipass cell. During Phase I we demonstrated the basic optical design and signal processing by determining {sup 13}CO{sub 2} isotopic ratios with precisions as small as 0.2{per_thousand} using a conventional lead salt diode laser. During Phase II, the DFG laser source was coupled with the optical instrument and was demonstrated to detect {sup 13}CH{sub 4}/{sup 12}CH{sub 4} ratios with a precision of 0.5{per_thousand} and an averaging time of 20 s using concentrated methane in air with a mixing ratio of 2700 ppm. Methods for concentrating ambient air for isotopic analysis using this technique have been evaluated. Extensions of this instrument to other species such as {sup 13}CO{sub 2}, C{sup 18}OO, and CH{sub 3}D are possible by substituting lasers at other wavelengths in the DFG source module. The immediate commercial application of this instrument will be to compete with existing mass spectrometric isotope instruments which are expensive, large and relatively slow. The novel infrared source developed in this project can be applied to the measurement of many other gas species and will have wide

  4. The Composite Infrared Spectrometer

    Science.gov (United States)

    Calcutt, Simon; Taylor, Fredric; Ade, Peter; Kunde, Virgil; Jennings, Donald

    1992-01-01

    The Composite Infrared Spectrometer (CIRS) is a remote sensing instrument to be flown on the Cassini orbiter. It contains two Fourier transform spectrometers covering wavelengths of 7-1000 microns. The instrument is expected to have higher spectral resolution, smaller field of view, and better signal-to-noise performance than its counterpart, IRIS, on the Voyager missions. These improvements allow the study of the variability of the composition and temperature of the atmospheres of both Saturn and Titan with latitude, longitude and height, as well as allowing the possibility of discovery of previously undetected chemical species in these atmospheres. The long wavelengths accessible to CIRS allow sounding deeper into both atmospheres than was possible with IRIS.

  5. Using Isotope Ratio Infrared Spectrometer to determine δ13C and δ18O of carbonate samples

    Science.gov (United States)

    Smajgl, Danijela; Stöbener, Nils; Mandic, Magda

    2017-04-01

    The isotopic composition of calcifying organisms is a key tool for reconstruction past seawater temperature and water chemistry. Therefore stable carbon and oxygen isotopes (δ13C and δ18O) in carbonates have been widely used for reconstruction of paleoenvironments. Precise and accurate determination of isotopic composition of carbon (13C) and oxygen (18O) from carbonate sample with proper referencing and data evaluation algorithm presents a challenge for scientists. Mass spectrometry was the only widely used technique for this kind of analysis, but recent advances make laser based spectroscopy a viable alternative. The Thermo Scientific Delta Ray Isotope Ratio Infrared Spectrometer (IRIS) analyzer with the Universal Reference Interface (URI) Connect is one of those alternatives and with TELEDYNE Cetac ASX-7100 autosampler extends the traditional offerings with a system of high precision and throughput of samples. To establish precision and accuracy of measurements and also to develop optimal sample preparation method for measurements with Delta Ray IRIS and URI Connect, IAEA reference materials were used. Preparation is similar to a Gas Bench II method. Carbonate material is added into the vials, flushed with CO2 free synthetic air and acidified with few droplets of 104% H3PO4. Sample amount used for analysis can be as low as 200 μg. Samples are measured after acidification and equilibration time of one hour at 70°C. The CO2 gas generated by reaction is flushed into the variable volume inside the URI Connect through the Nafion based built-in water trap. For this step, carrier gas (CO2 free air) is used to flush the gas from the vial into the variable volume with a maximum volume of 100 ml. A small amount of the sample is then used for automatic concentration determination present in the variable volume. The Thermo Scientific Qtegra Software automatically adjusts any additional dilution of the sample to achieve the desired concentration (usually 400 ppm) in the

  6. Mid infrared MEMS FTIR spectrometer

    Science.gov (United States)

    Erfan, Mazen; Sabry, Yasser M.; Mortada, Bassem; Sharaf, Khaled; Khalil, Diaa

    2016-03-01

    In this work we report, for the first time to the best of our knowledge, a bulk-micromachined wideband MEMS-based spectrometer covering both the NIR and the MIR ranges and working from 1200 nm to 4800 nm. The core engine of the spectrometer is a scanning Michelson interferometer micro-fabricated using deep reactive ion etching (DRIE) technology. The spectrum is obtained using the Fourier Transform techniques that allows covering a very wide spectral range limited by the detector responsivity. The moving mirror of the interferometer is driven by a relatively large stroke electrostatic comb-drive actuator. Zirconium fluoride (ZrF4) multimode optical fibers are used to connect light between the white light source and the interferometer input, as well as the interferometer output to a PbSe photoconductive detector. The recorded signal-to-noise ratio is 25 dB at the wavelength of 3350 nm. The spectrometer is successfully used in measuring the absorption spectra of methylene chloride, quartz glass and polystyrene film. The presented solution provides a low cost method for producing miniaturized spectrometers in the near-/mid-infrared.

  7. Static Fourier transform infrared spectrometer.

    Science.gov (United States)

    Schardt, Michael; Murr, Patrik J; Rauscher, Markus S; Tremmel, Anton J; Wiesent, Benjamin R; Koch, Alexander W

    2016-04-01

    Fourier transform spectroscopy has established itself as the standard method for spectral analysis of infrared light. Here we present a robust and compact novel static Fourier transform spectrometer design without any moving parts. The design is well suited for measurements in the infrared as it works with extended light sources independent of their size. The design is experimentally evaluated in the mid-infrared wavelength region between 7.2 μm and 16 μm. Due to its large etendue, its low internal light loss, and its static design it enables high speed spectral analysis in the mid-infrared.

  8. Long-Wave Infrared Dyson Spectrometer

    Science.gov (United States)

    Johnson, William R.; Hook, Simon J.; Mouroulis, Pantazis Z.; Wilson, Daniel W.; Gunapala, Sarath D.; Hill, Cory J.; Mumolo, Jason M.; Eng, Bjorn T.

    2008-01-01

    Preliminary results are presented for an ultra compact long-wave infrared slit spectrometer based on the dyson concentric design. The dyson spectrometer has been integrated in a dewar environment with a quantum well infrared photodetecor (QWIP), concave electron beam fabricated diffraction grating and ultra precision slit. The entire system is cooled to cryogenic temperatures to maximize signal to noise ratio performance, hence eliminating thermal signal from transmissive elements and internal stray light. All of this is done while maintaining QWIP thermal control. A general description is given of the spectrometer, alignment technique and predicated performance. The spectrometer has been designed for optimal performance with respect to smile and keystone distortion. A spectral calibration is performed with NIST traceable targets. A 2-point non-uniformity correction is performed with a precision blackbody source to provide radiometric accuracy. Preliminary laboratory results show excellent agreement with modeled noise equivalent delta temperature and detector linearity over a broad temperature range.

  9. Fourier-Transform Infrared Spectrometer

    Science.gov (United States)

    Schindler, R. A.

    1986-01-01

    Fourier-transform spectrometer provides approximately hundredfold increase in luminosity at detector plane over that achievable with older instruments of this type. Used to analyze such weak sources as pollutants and other low-concentration substances in atmosphere. Interferometer creates fringe patterns on two distinct arrays of light detectors, which observe different wavelength bands. Objective lens focuses scene on image plane, which contains optical chopper. To make instrument less susceptible to variations in scene under observation, field and detector lenses focus entrance aperture, rather that image, onto detector array.

  10. Broadband Infrared Heterodyne Spectrometer: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Stevens, C G; Cunningham, C T; Tringe, J W

    2010-12-16

    This report summarizes the most important results of our effort to develop a new class of infrared spectrometers based on a novel broadband heterodyne design. Our results indicate that this approach could lead to a near-room temperature operation with performance limited only by quantum noise carried by the incoming signal. Using a model quantum-well infrared photodetector (QWIP), we demonstrated key performance features of our approach. For example, we directly measured the beat frequency signal generated by superimposing local oscillator (LO) light of one frequency and signal light of another through a spectrograph, by injecting the LO light at a laterally displaced input location. In parallel with the development of this novel spectrometer, we modeled a new approach to reducing detector volume though plasmonic resonance effects. Since dark current scales directly with detector volume, this ''photon compression'' can directly lead to lower currents. Our calculations indicate that dark current can be reduced by up to two orders of magnitude in an optimized ''superlens'' structure. Taken together, our spectrometer and dark current reduction strategies provide a promising path toward room temperature operation of a mid-wave and possibly long-wave infrared spectrometer.

  11. The Berkeley tunable far infrared laser spectrometers

    Science.gov (United States)

    Blake, G. A.; Laughlin, K. B.; Cohen, R. C.; Busarow, K. L.; Gwo, D.-H.

    1991-01-01

    A detailed description is presented for a tunable far infrared laser spectrometer based on frequency mixing of an optically pumped molecular gas laser with tunable microwave radiation in a Schottky point contact diode. The system has been operated on over 30 laser lines in the range 10-100/cm and exhibits a maximum absorption sensitivity near one part in a million. Each laser line can be tuned by + or - 110 GHz with first-order sidebands.

  12. Composite Infrared Spectrometer (CIRS) on Cassini

    Science.gov (United States)

    Jennings, Donald E.; Flasar, F. M.; Kunde, V. G.; Nixon, C. A.; Segura, M. E.; Romani, P. N.; Gorius, N.; Albright, S.; Brasunas, J. C.; Carlson, R. C.; hide

    2017-01-01

    The Cassini spacecraft orbiting Saturn carries the composite infrared spectrometer (CIRS) designed to study thermal emission from Saturn and its rings and moons. CIRS, a Fourier transform spectrometer, is an indispensable part of the payload providing unique measurements and important synergies with the other instruments. It takes full advantage of Cassini's 13-year-long mission and surpasses the capabilities of previous spectrometers on Voyager 1 and 2. The instrument, consisting of two interferometers sharing a telescope and a scan mechanism, covers over a factor of 100 in wavelength in the mid and far infrared. It is used to study temperature, composition, structure, and dynamics of the atmospheres of Jupiter, Saturn, and Titan, the rings of Saturn, and surfaces of the icy moons. CIRS has returned a large volume of scientific results, the culmination of over 30 years of instrument development, operation, data calibration, and analysis. As Cassini and CIRS reach the end of their mission in 2017, we expect that archived spectra will be used by scientists for many years to come.

  13. Using Isotope Ratio Infrared Spectrometer to determine δ13C of CaCO3 carbonate and DIC samples and δ18O of water

    Science.gov (United States)

    Mandic, M.; Stöbener, N.; Mandic, L.; Smajgl, D.; Jost, H. J. H.

    2016-12-01

    Precise and accurate determination of isotopic composition of carbon (13C) and oxygen (18O) from carbonate or DIC sample with proper referencing and data evaluation algorithm presents a challenge for scientists. Mass spectrometry was the only widely used technique for this kind of analysis, but recent advances make laser based isotope ratio infrared spectroscopy (IRIS) a viable alternative. To analyze discrete samples, the Universal Reference Interface (URI) Connect was developed. CO2 free syntethic air is used to flush out the contents of a sample container into a variable volume. If necessary, the sample is further diluted before entering the analysis chamber. Reference gas measurements are automatically performed at the same concentration as sample measurements to compensate for instrument drifts and non linearity. The URI Connect can handle about 100 samples per day from an autosampler, or samples can be injected one at a time through a septum on the front of the instrument. Gas samples collected in flasks, bags, syringes, or vials can be analyzed. The system only needs the equivalent of about 80µg - or 40µL - of pure CO2 gas to complete an analysis. Due to it's small weight and robustness, sample analysis can be performed in the field, e.g. aboard a research vessel. To demonstrate the performance, a test experiment with 1% CO2 in 12 ml vials was performed. We achieved an internal precision of better than 0.07‰ and 0.1‰ for δ13C and δ18O, respectively. Analyses with sample amounts as low as 200 μg of carbonate can also be performed reliably with IRIS. We present measurements of three international reference materials, and one of them treated as an unknown. Five samples each of approximately 1mg each were acidified using a few droplets of 43% H3PO4 and left for equilibration overnight at 25°C. The standard deviation was less than 0.1‰ δ13C and the accuracy <0.01‰ As another example of head space analysis in 12 ml vials, we determined δ18O of

  14. TIRSPEC : TIFR Near Infrared Spectrometer and Imager

    CERN Document Server

    Ninan, J P; Ghosh, S K; D'Costa, S L A; Naik, M B; Poojary, S S; Sandimani, P R; Meshram, G S; Jadhav, R B; Bhagat, S B; Gharat, S M; Bakalkar, C B; Prabhu, T P; Anupama, G C; Toomey, D W

    2014-01-01

    We describe the TIFR Near Infrared Spectrometer and Imager (TIRSPEC) designed and built in collaboration with M/s. Mauna Kea Infrared LLC, Hawaii, USA, now in operation on the side port of the 2-m Himalayan Chandra Telescope (HCT), Hanle (Ladakh), India at an altitude of 4500 meters above mean sea level. The TIRSPEC provides for various modes of operation which include photometry with broad and narrow band filters, spectrometry in single order mode with long slits of 300" length and different widths, with order sorter filters in the Y, J, H and K bands and a grism as the dispersing element as well as a cross dispersed mode to give a coverage of 1.0 to 2.5 microns at a resolving power R of ~1200. The TIRSPEC uses a Teledyne 1024 x 1024 pixel Hawaii-1 PACE array detector with a cutoff wavelength of 2.5 microns and on HCT, provides a field of view of 307" x 307" with a plate scale of 0.3"/pixel. The TIRSPEC was successfully commissioned in June 2013 and the subsequent characterization and astronomical observatio...

  15. Tables of wavenumbers for the calibration of infrared spectrometers

    CERN Document Server

    Cole, ARH

    1977-01-01

    Tables of Wavenumbers for the Calibration of Infrared Spectrometers, Second Edition is a compilation of tables of wavenumber values for the calibration of infrared spectrometers. It makes the best use of high resolution results and integrates the far infrared data with the higher frequency values. This book is organized in two parts, one for high to medium-resolution spectrometers used by physical chemists and physicists, and the other for medium to low-resolution instruments employed by organic and inorganic chemists. The first part includes tables of wavenumber of infrared absorption lines

  16. Stratospheric ozone measurement with an infrared heterodyne spectrometer

    Science.gov (United States)

    Abbas, M. M.; Kostiuk, T.; Mumma, M. J.; Buhl, D.; Kunde, V. G.; Brown, L. W.

    1978-01-01

    Measurements of a stratospheric ozone concentration profile are made by detecting infrared absorption lines with a heterodyne spectrometer. The infrared spectrometer is based on a line-by-line tunable CO2 lasers, a liquid-nitrogen cooled HgCdTe photomixer, and a 64-channel spectral line receiver. The infrared radiation from the source is mixed with local-oscillator radiation. The difference frequency signal in a bandwidth above and below the local-oscillator frequency is detected. The intensity in each sideband is found by subtracting sideband contributions. It is found that absolute total column density is 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio at about 24 km. The (7,1,6)-(7,1,7) O3 line center frequency is identified as 1043.1772/cm. Future work will involve a number of ozone absorption lines and measurements of diurnal variation. Completely resolved stratospheric lines may be inverted to yield concentration profiles of trace constituents and stratospheric gases.

  17. TIRCIS: thermal infrared compact imaging spectrometer for small satellite applications

    Science.gov (United States)

    Wright, Robert; Lucey, Paul; Crites, Sarah; Garbeil, Harold; Wood, Mark; Pilger, Eric; Gabrieli, Andrea; Honniball, Casey

    2016-10-01

    Measurements of reflectance or emittance in tens of narrow, contiguous wavebands, allow for the derivation of laboratory quality spectra remotely, from which the chemical composition and physical properties of targets can be determined. Although spaceborne (e.g. EO-1 Hyperion) hyperspectral data in the 0.4-2.5 micron (VSWIR) region are available, the provision of equivalent data in the log-wave infrared has lagged behind, there being no currently operational high spatial resolution LWIR imaging spectrometer on orbit. TIRCIS (Thermal Infra-Red Compact Imaging Spectrometer), uses a Fabry-Perot interferometer, an uncooled microbolometer array, and push-broom scanning to acquire hyperspectral image data. Radiometric calibration is provided by blackbody targets while spectral calibration is achieved using monochromatic light sources. The instrument has a mass of <15 kg and dimensions of 53 cm × 25 cm ♢ 22 cm, and has been designed to be compatible with integration into a micro-satellite platform. (A precursor to this instrument was launched onboard a 55 kg microsatellite in October 2015). The optical design yields a 120 m ground sample size given an orbit of 500 km. Over the wavelength interval of 7.5 to 14 microns up to 50 spectral samples are possible. Measured signal-to-noise ratios range from peak values of 500:1 to 1500:1, for source temperature of 10 to 100°C.

  18. Infrared Spectroscopy with a Cavity Ring-Down Spectrometer

    Science.gov (United States)

    2014-08-01

    Fourier transform infrared spectroscopy ( FTIR ) measures the transmission of the excitation source and then calculates the absorption from that measured...laser FTIR Fourier transform infrared spectroscopy HgCdTe mercury, cadmium, tellurium I absorbed light intensity I0 initial light intensity l...Infrared Spectroscopy with a Cavity Ring-Down Spectrometer by Logan S Marcus, Ellen L Holthoff, and Paul M Pellegrino ARL-TR-7031 August

  19. NIRS3: The Near Infrared Spectrometer on Hayabusa2

    Science.gov (United States)

    Iwata, Takahiro; Kitazato, Kohei; Abe, Masanao; Ohtake, Makiko; Arai, Takehiko; Arai, Tomoko; Hirata, Naru; Hiroi, Takahiro; Honda, Chikatoshi; Imae, Naoya; Komatsu, Mutsumi; Matsunaga, Tsuneo; Matsuoka, Moe; Matsuura, Shuji; Nakamura, Tomoki; Nakato, Aiko; Nakauchi, Yusuke; Osawa, Takahito; Senshu, Hiroki; Takagi, Yasuhiko; Tsumura, Kohji; Takato, Naruhisa; Watanabe, Sei-ichiro; Barucci, Maria Antonietta; Palomba, Ernesto; Ozaki, Masanobu

    2017-03-01

    NIRS3: The Near Infrared Spectrometer is installed on the Hayabusa2 spacecraft to observe the target C-type asteroid 162173 Ryugu at near infrared wavelengths of 1.8 to 3.2 μm. It aims to obtain reflectance spectra in order to detect absorption bands of hydrated and hydroxide minerals in the 3 μm-band. We adopted a linear-image sensor with indium arsenide (InAs) photo diodes and a cooling system with a passive radiator to achieve an optics temperature of 188 K ( -85°C), which enables to retaining sufficient sensitivity and noise level in the 3 μm wavelength region. We conducted ground performance tests for the NIRS3 flight model (FM) to confirm its baseline specifications. The results imply that the properties such as the signal-to-noise ratio (SNR) conform to scientific requirements to determine the degree of aqueous alteration, such as CM or CI chondrite, and the stage of thermal metamorphism on the asteroid surface.

  20. NIRS3: The Near Infrared Spectrometer on Hayabusa2

    Science.gov (United States)

    Iwata, Takahiro; Kitazato, Kohei; Abe, Masanao; Ohtake, Makiko; Arai, Takehiko; Arai, Tomoko; Hirata, Naru; Hiroi, Takahiro; Honda, Chikatoshi; Imae, Naoya; Komatsu, Mutsumi; Matsunaga, Tsuneo; Matsuoka, Moe; Matsuura, Shuji; Nakamura, Tomoki; Nakato, Aiko; Nakauchi, Yusuke; Osawa, Takahito; Senshu, Hiroki; Takagi, Yasuhiko; Tsumura, Kohji; Takato, Naruhisa; Watanabe, Sei-ichiro; Barucci, Maria Antonietta; Palomba, Ernesto; Ozaki, Masanobu

    2017-07-01

    NIRS3: The Near Infrared Spectrometer is installed on the Hayabusa2 spacecraft to observe the target C-type asteroid 162173 Ryugu at near infrared wavelengths of 1.8 to 3.2 μm. It aims to obtain reflectance spectra in order to detect absorption bands of hydrated and hydroxide minerals in the 3 μm-band. We adopted a linear-image sensor with indium arsenide (InAs) photo diodes and a cooling system with a passive radiator to achieve an optics temperature of 188 K (-85°C), which enables to retaining sufficient sensitivity and noise level in the 3 μm wavelength region. We conducted ground performance tests for the NIRS3 flight model (FM) to confirm its baseline specifications. The results imply that the properties such as the signal-to-noise ratio (SNR) conform to scientific requirements to determine the degree of aqueous alteration, such as CM or CI chondrite, and the stage of thermal metamorphism on the asteroid surface.

  1. Dedicated monolithic infrared spectrometer for process monitoring

    Science.gov (United States)

    Chadha, Suneet; Kyle, William; Bolduc, Roy A.; Curtiss, Lawrence E.

    1999-12-01

    Foster-Miller has leveraged its innovations in IR fiber- optic probes and the recent development of a miniature spectrometer to build a novel IR sensor system for process applications. The developed sensor systems is a low-cost alternative to process FTIR and filter based systems. A monolithic wedge-grating optic provides the spectral dispersion with low cost thermopile point or array detectors picking off the diffracted wavelengths from the optic. The integrated optic provides spectral discrimination between 3- 12 micrometers with resolution at 8 cm-1 or better and high overall optical throughput. The device has a fixed cylindrical grating uniquely bonded to the edge of a ZnSe conditioning 'wedge'. The conditioning optic overcomes limitations of concave gratings as it accepts high angle light at the narrow end of the wedge and progressively conditions it to be near normal to the grating. On return, the diffracted wavelengths are concentrated on the discrete or array detector elements by the wedge, providing throughput comparable to that of an FTIR. The miniature spectrometer coupled to flow through liquid cells or multipass gas cells provides significant cost advantage over conventional sampling methodologies. Currently, we are investigating process applications for the petroleum and dairy markets. The sensor system eliminates the cost, complexity, reliability and bandwidth/resolution problems associated with either Fabry Perot or Michelson Interferometer based approaches for low-cost process applications.

  2. Silicates on Iapetus from Cassini's Composite Infrared Spectrometer

    CERN Document Server

    Young, Cindy L; Clark, Roger N; Spencer, John R; Jennings, Donald E; Hand, Kevin P; Poston, Michael J; Carlson, Robert W

    2015-01-01

    We present the first spectral features obtained from Cassini's Composite Infrared Spectrometer (CIRS) for any icy moon. The spectral region covered by CIRS focal planes (FP) 3 and 4 is rich in emissivity features, but previous studies at these wavelengths have been limited by low signal to noise ratios (S/Rs) for individual spectra. Our approach is to average CIRS FP3 spectra to increase the S/R and use emissivity spectra to constrain the composition of the dark material on Iapetus. We find an emissivity feature at ~855 cm-1 and a possible doublet at 660 and 690 cm-1 that do not correspond to any known instrument artifacts. We attribute the 855 cm-1 feature to fine-grained silicates, similar to those found in dust on Mars and in meteorites, which are nearly featureless at shorter wavelengths. Silicates on the dark terrains of Saturn's icy moons have been suspected for decades, but there have been no definitive detections until now. Serpentines reported in the literature at ambient temperature and pressure hav...

  3. Isomeric ratio measurements with the ILL LOHENGRIN spectrometer

    OpenAIRE

    Chebboubi A.; Kessedjian G.; Litaize O.; Serot O.; Faust H.; Bernard D.; Blanc A.; Köster U.; Méplan O.; Mutti P.; Sage C.

    2016-01-01

    The modelling of γ heating and neutron damage inside a nuclear reactor is essential to design the next generation of nuclear reactors. The determination of the fission fragment momentum is a key element to perform accurate calculations of the γ heating. One way to assess this information is to look at the isomeric ratio of different nuclei. According to the lifetime of the isomeric state, different experimental techniques were developed at the LOHENGRIN spectrometer. A focus on the measuremen...

  4. Ratio-model for the simulation of infrared spectra of pollution gases in complicated background

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A ratio-model for the computer simulation of infrared spectra of pollution gases in complicated background is proposed. The characteristic spectrum of the hazardous pollution gas is simulated with background spectra which are measured by passive Fourier transform infrared spectrometer. The simulated results agree well with the experimental results.

  5. [Biological Process Oriented Online Fourier Transform Infrared Spectrometer].

    Science.gov (United States)

    Xie, Fei; Wu, Qiong-shui; Zeng, Li-bo

    2015-08-01

    An online Fourier Transform Infrared Spectrometer and an ATR (Attenuated Total Reflection) probe, specifically at the application of real time measurement of the reaction substrate concentration in biological processes, were designed. (1) The spectrometer combined the theories of double cube-corner reflectors and flat mirror, which created a kind of high performance interferometer system. The light path folding way was utilized to makes the interferometer compact structure. Adopting double cube-corner reflectors, greatly reduces the influence of factors in the process of moving mirror movement such as rotation, tilt, etc. The parallelogram oscillation flexible support device was utilized to support the moving mirror moves. It cancelled the friction and vibration during mirror moving, and ensures the smooth operation. The ZnSe splitter significantly improved the hardware reliability in high moisture environment. The method of 60° entrance to light splitter improves the luminous flux. (2) An ATR in situ measuring probe with simple structure, large-flux, economical and practical character was designed in this article. The transmission of incident light and the light output utilized the infrared pipe with large diameter and innerplanted-high plating membrane, which conducted for the infrared transmission media of ATR probe. It greatly reduced the energy loss of infrared light after multiple reflection on the inner wall of the light pipe. Therefore, the ATR probe obtained high flux, improved the signal strength, which make the signal detected easily. Finally, the high sensitivity of MCT (Mercury Cadmium Telluride) detector was utilized to realize infrared interference signal collection, and improved the data quality of detection. The test results showed that the system yields the advantages of perfect moisture-proof performance, luminous flux, online measurement, etc. The designed online Fourier infrared spectrometer can real-time measured common reactant substrates

  6. Mid-Infrared Frequency Comb Fourier Transform Spectrometer

    CERN Document Server

    Adler, Florian; Foltynowicz, Aleksandra; Cossel, Kevin C; Briles, Travis C; Hartl, Ingmar; Ye, Jun

    2010-01-01

    Optical frequency-comb-based-high-resolution spectrometers offer enormous potential for spectroscopic applications. Although various implementations have been demonstrated, the lack of suitable mid-infrared comb sources has impeded explorations of molecular fingerprinting. Here we present for the first time a frequency-comb Fourier transform spectrometer operating in the 2100-to-3700-cm-1 spectral region that allows fast and simultaneous acquisitions of broadband absorption spectra with up to 0.0056 cm-1 resolution. We demonstrate part-per-billion detection limits in 30 seconds of integration time for various important molecules including methane, ethane, isoprene, and nitrous oxide. Our system enables precise concentration measurements even in gas mixtures that exhibit continuous absorption bands, and it allows detection of molecules at levels below the noise floor via simultaneous analysis of multiple spectral features. This system represents a near real-time, high-resolution, high-bandwidth mid-infrared sp...

  7. Miniature high-performance infrared spectrometer for space applications

    Science.gov (United States)

    Kruzelecky, Roman V.; Haddad, Emile; Wong, Brian; Lafrance, Denis; Jamroz, Wes; Ghosh, Asoke K.; Zheng, Wanping; Phong, Linh

    2004-06-01

    Infrared spectroscopy probes the characteristic vibrational and rotational modes of chemical bonds in molecules to provide information about both the chemical composition and the bonding configuration of a sample. The significant advantage of the Infrared spectral technique is that it can be used with minimal consumables to simultaneously detect a large variety of chemical and biochemical species with high chemical specificity. To date, relatively large Fourier Transform (FT-IR) spectrometers employing variations of the Michelson interferometer have been successfully employed in space for various IR spectroscopy applications. However, FT-IR systems are mechanically complex, bulky (> 15 kg), and require considerable processing. This paper discusses the use of advanced integrated optics and smart optical coding techniques to significantly extend the performance of miniature IR spectrometers by several orders of magnitude in sensitivity. This can provide the next-generation of compact, high-performance IR spectrometers with monolithically integrated optical systems for robust optical alignment. The entire module can weigh under 3 kg to minimize the mass penalty for space applications. Miniaturized IR spectrometers are versatile and very convenient for small and micro satellite based missions. They can be dedicated to the monitoring of the CO2 in an Earth Observation mission, to Mars exobiology exploration, as well as to vital life support in manned space system; such as the cabin air quality and the quality of the recycled water supply.

  8. An Airborne Infrared Spectrometer for Solar Eclipse Observations

    Science.gov (United States)

    Samra, Jenna; DeLuca, Edward E.; Golub, Leon; Cheimets, Peter; Philip, Judge

    2016-05-01

    The airborne infrared spectrometer (AIR-Spec) is an innovative solar spectrometer that will observe the 2017 solar eclipse from the NSF/NCAR High-Performance Instrumented Airborne Platform for Environmental Research (HIAPER). AIR-Spec will image five infrared coronal emission lines to determine whether they may be useful probes of coronal magnetism.The solar magnetic field provides the free energy that controls coronal heating, structure, and dynamics. Energy stored in coronal magnetic fields is released in flares and coronal mass ejections and ultimately drives space weather. Therefore, direct coronal field measurements have significant potential to enhance understanding of coronal dynamics and improve solar forecasting models. Of particular interest are observations of field lines in the transitional region between closed and open flux systems, providing important information on the origin of the slow solar wind.While current instruments routinely observe only the photospheric and chromospheric magnetic fields, AIR-Spec will take a step toward the direct observation of coronal fields by measuring plasma emission in the infrared at high spatial and spectral resolution. During the total solar eclipse of 2017, AIR-Spec will observe five magnetically sensitive coronal emission lines between 1.4 and 4 µm from the HIAPER Gulfstream V at an altitude above 14.9 km. The instrument will measure emission line intensity, width, and Doppler shift, map the spatial distribution of infrared emitting plasma, and search for waves in the emission line velocities.AIR-Spec consists of an optical system (feed telescope, grating spectrometer, and infrared detector) and an image stabilization system, which uses a fast steering mirror to correct the line-of-sight for platform perturbations. To ensure that the instrument meets its research goals, both systems are undergoing extensive performance modeling and testing. These results are shown with reference to the science requirements.

  9. Isomeric ratio measurements with the ILL LOHENGRIN spectrometer

    Directory of Open Access Journals (Sweden)

    Chebboubi A.

    2016-01-01

    Full Text Available The modelling of γ heating and neutron damage inside a nuclear reactor is essential to design the next generation of nuclear reactors. The determination of the fission fragment momentum is a key element to perform accurate calculations of the γ heating. One way to assess this information is to look at the isomeric ratio of different nuclei. According to the lifetime of the isomeric state, different experimental techniques were developed at the LOHENGRIN spectrometer. A focus on the measurement of isomeric ratios of 136I in neutron induced fission of 241Pu is presented. A discussion with the current assumptions used in the evaluation process for isomeric ratio is also shown.

  10. SILICATES ON IAPETUS FROM CASSINI’S COMPOSITE INFRARED SPECTROMETER

    Energy Technology Data Exchange (ETDEWEB)

    Young, Cindy L.; Wray, James J. [School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA (United States); Clark, Roger N. [Planetary Science Institute, Tucson, AZ (United States); Spencer, John R. [Southwest Research Institute, Boulder, CO (United States); Jennings, Donald E. [NASA Goddard Space Flight Center, Greenbelt, MD (United States); Hand, Kevin P.; Carlson, Robert W. [Jet Propulsion Laboratory, Pasadena, CA (United States); Poston, Michael J. [Caltech, Pasadena, CA (United States)

    2015-10-01

    We present the first spectral features obtained from Cassini’s Composite Infrared Spectrometer (CIRS) for any icy moon. The spectral region covered by CIRS focal planes (FP) 3 and 4 is rich in emissivity features, but previous studies at these wavelengths have been limited by low signal-to-noise ratios (S/Ns) for individual spectra. Our approach is to average CIRS FP3 spectra to increase the S/N and use emissivity spectra to constrain the composition of the dark material on Iapetus. We find an emissivity feature at ∼855 cm{sup −1} and a possible doublet at 660 and 690 cm{sup −1} that do not correspond to any known instrument artifacts. We attribute the 855 cm{sup −1} feature to fine-grained silicates, similar to those found in dust on Mars and in meteorites, which are nearly featureless at shorter wavelengths. Silicates on the dark terrains of Saturn’s icy moons have been suspected for decades, but there have been no definitive detections until now. Serpentines reported in the literature at ambient temperature and pressure have features near 855 and 660 cm{sup −1}. However, peaks can shift depending on temperature and pressure, so measurements at Iapetus-like conditions are necessary for more positive feature identifications. As a first investigation, we measured muscovite at 125 K in a vacuum and found that this spectrum does match the emissivity feature near 855 cm{sup −1} and the location of the doublet. Further measurements are needed to robustly identify a specific silicate, which would provide clues regarding the origin and implications of the dark material.

  11. Near-infrared imaging spectrometer onboard NEXTSat-1

    Science.gov (United States)

    Jeong, Woong-Seob; Park, Sung-Joon; Moon, Bongkon; Lee, Dae-Hee; Pyo, Jeonghyun; Park, Won-Kee; Park, Youngsik; Kim, Il-Joong; Ko, Kyeongyeon; Lee, Dukhang; Kim, Min Gyu; Kim, Minjin; Ko, Jongwan; Shin, Goo-Hwan; Chae, Jangsoo; Matsumoto, Toshio

    2016-07-01

    The NISS (Near-infrared Imaging Spectrometer for Star formation history) is the near-infrared instrument optimized to the first next generation of small satellite (NEXTSat-1) in Korea. The spectro-photometric capability in the near-infrared range is a unique function of the NISS. The major scientific mission is to study the cosmic star formation history in local and distant universe. For those purposes, the NISS will perform the large areal imaging spectroscopic survey for astronomical objects and low background regions. We have paid careful attention to reduce the volume and to increase the total throughput. The newly implemented off-axis optics has a wide field of view (2° x 2°) and a wide wavelength range from 0.9 to 3.8μm. The mechanical structure is designed to consider launching conditions and passive cooling of the telescope. The compact dewar after relay-lens module is to operate the infrared detector and spectral filters at 80K stage. The independent integration of relay-lens part and primary-secondary mirror assembly alleviates the complex alignment process. We confirmed that the telescope and the infrared sensor can be cooled down to around 200K and 80K, respectively. The engineering qualification model of the NISS was tested in the space environment including the launch-induced vibration and shock. The NISS will be expected to demonstrate core technologies related to the development of the future infrared space telescope in Korea.

  12. Imaging telescope-spectrometer for infrared sky surveys

    Science.gov (United States)

    Maslov, Igor A.; Sholomitskii, Gennadii B.; Kuznetsov, Arkadii E.; Patrashin, Michail A.; Olejnikov, Leonid S.

    1995-06-01

    A new type of imaging telescope-spectrometer for surviving the sky aboard a satellite is described. A static Michelson interferometer in front of an objective with 2D-arrays in its focal plane is capable of providing interferograms both for point and extended sources. As an example, the telescope-spectrometer based on the 15-cm telescope of the IKON project and a plane-parallel Ge plate as a beamsplitter may have approximately equals 30 cm(superscript -1 spectral resolution in the range 3 - 20 micrometers . For higher resolution, such an objective interferometer has advantage over a dispersion spectrometer in the signal-to-noise ratio and is free from the disadvantage of an objective prism not providing spectra of extended sources.

  13. The Cosmic Infrared Background Experiment (CIBER): the Narrow Band Spectrometer

    CERN Document Server

    Korngut, P M; Arai, T; Battle, J; Bock, J; Brown, S W; Cooray, A; Hristov, V; Keating, B; Kim, M G; Lanz, A; Lee, D H; Levenson, L R; Lykke, K R; Mason, P; Matsumoto, T; Matsuura, S; Nam, U W; Shultz, B; Smith, A W; Sullivan, I; Tsumura, K; Wada, T; Zemcov, M

    2013-01-01

    We have developed a near-infrared spectrometer designed to measure the absolute intensity of the Solar 854.2 nm CaII Fraunhofer line, scattered by interplanetary dust, in the Zodiacal light spectrum. Based on the known equivalent line width in the Solar spectrum, this measurement can derive the Zodiacal brightness, testing models of the Zodiacal light based on morphology that are used to determine the extragalactic background light in absolute photometry measurements. The spectrometer is based on a simple high-resolution tipped filter placed in front of a compact camera with wide-field refractive optics to provide the large optical throughput and high sensitivity required for rocket-borne observations. We discuss the instrument requirements for an accurate measurement of the absolute Zodiacal light brightness, the measured laboratory characterization, and the instrument performance in flight.

  14. Analysis and System Design Framework for Infrared Spatial Heterodyne Spectrometers

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, B.J.; Smith, B.W.; Laubscher, B.E.; Villeneuve, P.V.; Briles, S.D.

    1999-04-05

    The authors present a preliminary analysis and design framework developed for the evaluation and optimization of infrared, Imaging Spatial Heterodyne Spectrometer (SHS) electro-optic systems. Commensurate with conventional interferometric spectrometers, SHS modeling requires an integrated analysis environment for rigorous evaluation of system error propagation due to detection process, detection noise, system motion, retrieval algorithm and calibration algorithm. The analysis tools provide for optimization of critical system parameters and components including : (1) optical aperture, f-number, and spectral transmission, (2) SHS interferometer grating and Littrow parameters, and (3) image plane requirements as well as cold shield, optical filtering, and focal-plane dimensions, pixel dimensions and quantum efficiency, (4) SHS spatial and temporal sampling parameters, and (5) retrieval and calibration algorithm issues.

  15. A new generation of MEMS middle-infrared spectrometers

    Science.gov (United States)

    Otto, Thomas; Saupe, Ray; Stock, Volker; Seider, Thomas; Gessner, Thomas

    2014-03-01

    Mid infrared spectroscopy has been developed to a powerful and essential method of material analysis, with a steadily increasing number of industrial and scientific application fields. The so called spectral fingerprint range enables identification of chemical compounds by their unique spectral pattern. To provide a suitable miniaturized and portable MIR spectrometer solution at an affordable price, an existing MEMS NIR spectrometer module which already bases on micro system technology has been expanded in its wavelength range. The developed spectrometer belongs to the category of scanning grating spectrometers. Main component is a fast oscillating micro-mirror which moves sinusoidal with high mechanical precision enabling a high stability of according wavelength axis. This is supported by a highly precise optical tracking of the actual motion. Mono-crystalline silicon guarantees a long-life operation with no wear even under harsh environmental conditions. Spectral signal acquisition is realized by using a TE-cooled MCT single element detector assisted by low noise trans-impedance amplifier. With the help of integrated logic components a data pre-processing takes place, such as averaging, offset subtraction, detector transfer characteristic correction and noise shaping. Due the compact and flexible setup, the spectrometer is suitable for the use in various applications, such as process control in chemical industry, gas mixture analysis or liquid verification. The portability of the device opens up new application possibilities in mobile environment. The advances of the promising technology and its specific applications will be described in this paper. Advanced performance issues of the device be reviewed in detail.

  16. A high-resolution Fourier-transform infrared spectrometer.

    Science.gov (United States)

    Johnson, H. L.; Forbes, F. F.; Thompson, R. I.; Steinmetz , D. L.; Harris, O.

    1973-01-01

    We have developed a Fourier-transform infrared spectrometer having a resolution of 0.5/cm over the range of wavelength from 1 to 5.5 microns. It has been used to observe the sun over this wavelength range from a Lear Jet flying at an altitude of 14 km, and to observe a number of stars from the ground, using the 229-cm telescope of the Steward Observatory and the 152-cm aluminum-mirror telescope at the Observatorio Astronomico Nacional in the Sierra de San Pedro Martir, Baja California, Mexico. The solar spectrum is given here, while the ground-based spectra are being published separately.

  17. The Cosmic Infrared Background Experiment (CIBER): The Low Resolution Spectrometer

    CERN Document Server

    Tsumura, K; Battle, J; Bock, J; Brown, S; Cooray, A; Hristov, V; Keating, B; Kim, M G; Lee, D H; Levenson, L R; Lykke, K; Mason, P; Matsumoto, T; Matsuura, S; Murata, K; Nam, U W; Renbarger, T; Smith, A; Sullivan, I; Suzuki, K; Wada, T; Zemcov, M

    2011-01-01

    Absolute spectrophotometric measurements of diffuse radiation at 1 \\mu m to 2 \\mu m are crucial to our understanding of the radiative content of the Universe from nucleosynthesis since the epoch of reionization, the composition and structure of the Zodiacal dust cloud in our solar system, and the diffuse galactic light arising from starlight scattered by interstellar dust. The Low Resolution Spectrometer (LRS) on the rocket-borne Cosmic Infrared Background Experiment (CIBER) is a \\lambda / \\Delta \\lambda \\sim 15-30 absolute spectrophotometer designed to make precision measurements of the absolute near-infrared sky brightness between 0.75 \\mu m < \\lambda < 2.1 \\mu m. This paper presents the optical, mechanical and electronic design of the LRS, as well as the ground testing, characterization and calibration measurements undertaken before flight to verify its performance. The LRS is shown to work to specifications, achieving the necessary optical and sensitivity performance. We describe our understanding a...

  18. Near-Infrared Grating Spectrometer for Mobile Phone Applications.

    Science.gov (United States)

    Pügner, Tino; Knobbe, Jens; Grüger, Heinrich

    2016-05-01

    Near-infrared (NIR) spectroscopy is a well-established technique for the chemical analysis of organic and inorganic matter. Accordingly, spectroscopic instrumentation of different complexity has been developed and is currently commercially available. However, there are an increasing number of new mobile applications that have come into focus and that cannot be addressed by the existing technology due to size and cost. Therefore, a new miniaturized scanning grating spectrometer for NIR spectroscopy has been developed at Fraunhofer IPMS. It is based on micro-electro-mechanical systems (MEMS) technology, and has been designed to meet the requirements for mobile application, regarding spectral range, resolution, overall size, robustness, and cost. The MEMS spectrometer covers a spectral range from 950 nm to 1900 nm at a resolution of 10 nm. The instrument is extremely small and has a volume of only 2.1 cm(3) Therefore, it is well suited for integration, even into a mobile phone. A first sample of the new spectrometer has been manufactured and put into operation. The results of a series of test measurements are in good agreement with the requirements and specifications.

  19. Exploration of the Saturn System by the Cassini Mission: Observations with the Cassini Infrared Spectrometer

    Science.gov (United States)

    Abbas, Mian M.

    2014-01-01

    Outline: Introduction to the Cassini mission, and Cassini mission Objectives; Cassini spacecraft, instruments, launch, and orbit insertion; Saturn, Rings, and Satellite, Titan; Composite Infrared Spectrometer (CIRS); and Infrared observations of Saturn and titan.

  20. Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Instrument Handbook

    Energy Technology Data Exchange (ETDEWEB)

    Flynn, Connor J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Atmospheric Radiation Measurement (ARM) Program

    2016-03-01

    The Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) measures the absolute infrared (IR) spectral radiance (watts per square meter per steradian per wavenumber) of the sky directly above the instrument. More information about the instrument can be found through the manufacturer’s website. The spectral measurement range of the instrument is 3300 to 520 wavenumbers (cm-1) or 3-19.2 microns for the normal-range instruments and 3300 to 400 cm-1 or 3-25 microns, for the extended-range polar instruments. Spectral resolution is 1.0 cm-1. Instrument field-of-view is 1.3 degrees. Calibrated sky radiance spectra are produced on cycle of about 141 seconds with a group of 6 radiance spectra zenith having dwell times of about 14 seconds each interspersed with 55 seconds of calibration and mirror motion. The ASSIST data is comparable to the Atmospheric Emitted Radiance Interferometer (AERI) data and can be used for 1) evaluating line-by-line radiative transport codes, 2) detecting/quantifying cloud effects on ground-based measurements of infrared spectral radiance (and hence is valuable for cloud property retrievals), and 3) calculating vertical atmospheric profiles of temperature and water vapor and the detection of trace gases.

  1. The Cosmic Infrared Background Experiment (CIBER): The Low Resolution Spectrometer

    Science.gov (United States)

    Tsumura, K.; Arai, T.; Battle, J.; Bock, J.; Brown, S.; Cooray, A.; Hristov, V.; Keating, B.; Kim, M. G.; Lee, D. H.; Levenson, L. R.; Lykke, K.; Mason, P.; Matsumoto, T.; Matsuura, S.; Murata, K.; Nam, U. W.; Renbarger, T.; Smith, A.; Sullivan, I.; Suzuki, K.; Wada, T.; Zemcov, M.

    2013-08-01

    Absolute spectrophotometric measurements of diffuse radiation at 1 μm to 2 μm are crucial to our understanding of the radiative content of the universe from nucleosynthesis since the epoch of reionization, the composition and structure of the zodiacal dust cloud in our solar system, and the diffuse galactic light arising from starlight scattered by interstellar dust. The Low Resolution Spectrometer (LRS) on the rocket-borne Cosmic Infrared Background Experiment is a λ/Δλ ~ 15-30 absolute spectrophotometer designed to make precision measurements of the absolute near-infrared sky brightness between 0.75 μm <λ < 2.1 μm. This paper presents the optical, mechanical, and electronic design of the LRS, as well as the ground testing, characterization, and calibration measurements undertaken before flight to verify its performance. The LRS is shown to work to specifications, achieving the necessary optical and sensitivity performance. We describe our understanding and control of sources of systematic error for absolute photometry of the near-infrared extragalactic background light.

  2. THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE LOW RESOLUTION SPECTROMETER

    Energy Technology Data Exchange (ETDEWEB)

    Tsumura, K.; Arai, T.; Matsumoto, T.; Matsuura, S.; Murata, K. [Department of Space Astronomy and Astrophysics, Institute of Space and Astronoutical Science (ISAS), Japan Aerospace Exploration Agency (JAXA), Sagamihara, Kanagawa 252-5210 (Japan); Battle, J.; Bock, J. [Jet Propulsion Laboratory (JPL), National Aeronautics and Space Administration (NASA), Pasadena, CA 91109 (United States); Brown, S.; Lykke, K.; Smith, A. [Optical Technology Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Cooray, A. [Center for Cosmology, University of California, Irvine, Irvine, CA 92697 (United States); Hristov, V.; Levenson, L. R.; Mason, P. [Department of Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Keating, B.; Renbarger, T. [Department of Physics, University of California, San Diego, San Diego, CA 92093 (United States); Kim, M. G. [Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Lee, D. H.; Nam, U. W. [Korea Astronomy and Space Science Institute (KASI), Daejeon 305-348 (Korea, Republic of); Sullivan, I., E-mail: tsumura@ir.isas.jaxa.jp [Department of Physics, The University of Washington, Seattle, WA 98195 (United States); and others

    2013-08-15

    Absolute spectrophotometric measurements of diffuse radiation at 1 {mu}m to 2 {mu}m are crucial to our understanding of the radiative content of the universe from nucleosynthesis since the epoch of reionization, the composition and structure of the zodiacal dust cloud in our solar system, and the diffuse galactic light arising from starlight scattered by interstellar dust. The Low Resolution Spectrometer (LRS) on the rocket-borne Cosmic Infrared Background Experiment is a {lambda}/{Delta}{lambda} {approx} 15-30 absolute spectrophotometer designed to make precision measurements of the absolute near-infrared sky brightness between 0.75 {mu}m <{lambda} < 2.1 {mu}m. This paper presents the optical, mechanical, and electronic design of the LRS, as well as the ground testing, characterization, and calibration measurements undertaken before flight to verify its performance. The LRS is shown to work to specifications, achieving the necessary optical and sensitivity performance. We describe our understanding and control of sources of systematic error for absolute photometry of the near-infrared extragalactic background light.

  3. THIS: a tuneable heterodyne infrared spectrometer for SOFIA

    Science.gov (United States)

    Schieder, R.; Sonnabend, G.; Sornig, M.; Kroetz, P.; Stupar, D.

    2007-09-01

    The THIS instrument (Tuneable Heterodyne Infrared Spectrometer) is a versatile heterodyne receiver with a sensitivity close to theoretical prediction. It uses a Quantum Cascade Laser (QCL) as local oscillator and a HgCdTe photo-voltaic detector as mixer. The IF-spectrum is analyzed by means of a new broadband Acousto-Optical Spectrometer (AOS) with 3 GHz bandwidth and 1 MHz resolution. A dual sideband (DSB) system noise temperature has been measured with 2300 K at 10 μm wavelength, which is only 60% above the quantum limit. The stability of the system has been determined at an Allan variance minimum time of 50 seconds. Below this integration time the performance is purely radiometric. Also, the frequency stability has been measured with 1 MHz rms error within several hours. The quality of the instrument has been demonstrated by a few observing campaigns at the McMath-Pierce observatory on Kitt Peak. Measurements of Winds on Mars and Venus have been carried out and molecular line signals in sunspots have been detected. We propose to develop THIS as a second generation instrument for future astronomical observations on SOFIA.

  4. Development of Real-Time Image Stabilization and Control Systems for an Airborne Infrared Spectrometer

    OpenAIRE

    2016-01-01

    The total solar eclipse of August 21, 2017 offers a unique opportunity for study of the infrared solar corona. The Airborne Infrared Spectrometer (AIR-Spec), currently under development, is an infrared telescope and spectrometer that will search for several magnetically sensitive coronal emission lines between 1.4 and 4 micrometers.  This instrument will be the first to observe several of these lines, and the measurement campaign will determine whether any lines may be useful for future direc...

  5. SW-MW infrared spectrometer for lunar mission

    Science.gov (United States)

    Banerjee, Arup; Biswas, Amiya; Joshi, Shaunak; Kumar, Ankush; Rehman, Sami; Sharma, Satish; Somani, Sandip; Bhati, Sunil; Karelia, Jitendra; Saxena, Anish; Chowdhury, Arup R.

    2016-04-01

    SW-MW Imaging Infrared Spectrometer, the Hyperspectral optical imaging instrument is envisaged to map geomorphology and mineralogy of lunar surface. The instrument is designed to image the electro-magnetic energy emanating from moon's surface with high spectral and spatial resolution for the mission duration from an altitude of 100 km. It is designed to cover 0.8 to 5 μm in 250 spectral bands with GSD 80m and swath 20km. Primarily, there are three basic optical segments in the spectrometer. They are fore optics, dispersing element and focusing elements. The payload is designed around a custom developed multi-blaze convex grating optimized for system throughput. The considerations for optimization are lunar radiation, instrument background, optical throughput, and detector sensitivity. HgCdTe (cooled using a rotary stirling cooler) based detector array (500x256 elements, 30μm) is being custom developed for the spectrometer. Stray light background flux is minimized using a multi-band filter cooled to cryogenic temperature. Mechanical system realization is being performed considering requirements such as structural, opto-mechanical, thermal, and alignment. The entire EOM is planned to be maintained at 240K to reduce and control instrument background. Al based mirror, grating, and EOM housing is being developed to maintain structural requirements along with opto- mechanical and thermal. Multi-tier radiative isolation and multi-stage radiative cooling approach is selected for maintaining the EOM temperature. EOM along with precision electronics packages are planned to be placed on the outer and inner side of Anti-sun side (ASS) deck. Power and Cooler drive electronics packages are planned to be placed on bottom side of ASS panel. Cooler drive electronics is being custom developed to maintain the detector temperature within 100mK during the imaging phase. Low noise detector electronics development is critical for maintaining the NETD requirements at different target

  6. Mako airborne thermal infrared imaging spectrometer: performance update

    Science.gov (United States)

    Hall, Jeffrey L.; Boucher, Richard H.; Buckland, Kerry N.; Gutierrez, David J.; Keim, Eric R.; Tratt, David M.; Warren, David W.

    2016-09-01

    The Aerospace Corporation's sensitive Mako thermal infrared imaging spectrometer, which operates between 7.6 and 13.2 microns at a spectral sampling of 44 nm, and flies in a DeHavilland DHC-6 Twin Otter, has undergone significant changes over the past year that have greatly increased its performance. A comprehensive overhaul of its electronics has enabled frame rates up to 3255 Hz and noise reductions bringing it close to background-limited. A replacement diffraction grating whose peak efficiency was tuned to shorter wavelength, coupled with new AR coatings on certain key optics, has improved the performance at the short wavelength end by a factor of 3, resulting in better sensitivity for methane detection, for example. The faster frame rate has expanded the variety of different scan schemes that are possible, including multi-look scans in which even sizeable target areas can be scanned multiple times during a single overpass. Off-nadir scanning to +/-56.4° degrees has also been demonstrated, providing an area scan rate of 33 km2/minute for a 2-meter ground sampling distance (GSD) at nadir. The sensor achieves a Noise Equivalent Spectral Radiance (NESR) of better than 0.6 microflicks (μf, 10-6 W/sr/cm2/μm) in each of the 128 spectral channels for a typical airborne dataset in which 4 frames are co-added. An additional improvement is the integration of a new commercial 3D stabilization mount which is significantly better at compensating for aircraft motions and thereby maintains scan performance under quite turbulent flying conditions. The new sensor performance and capabilities are illustrated.

  7. Multi-collector Isotope Ratio Mass Spectrometer -- Operational Performance Report

    Energy Technology Data Exchange (ETDEWEB)

    Appelhans, Anthony D; Olson, John E; Watrous, Matthew G; Ward, Michael B.; Dahl, David A.

    2010-12-01

    This report describes the operational testing of a new magnetic sector mass spectrometer that utilizes seven full-sized discrete dynode electron multipliers operating simultaneously. The instrument includes a newly developed ion dispersion lens that enables the mass dispersed individual isotope beams to be separated sufficiently to allow a full-sized discrete dynode pulse counting multiplier to be used to measure each isotope beam. The performance of the instrument was measured using SRM 996 (244Pu spike) at loadings of 2.4 and 12 fg on resin beads and with SRM 4350B Columbia River Sediment samples. The measured limit of detection (3s) for 240Pu was 3.4 attograms for SRM 996. The limit of quantitation (LOQ), defined as 10 s, was 11.2 attograms. The measured concentration of 239Pu in the CRS standard was 152 ± 6 fg/g.

  8. Infrared fiber coupled acousto-optic tunable filter spectrometer

    Science.gov (United States)

    Levin, K. H.; Kindler, E.; Ko, T.; Lee, F.; Tran, D. C.; Tapphorn, R. M.

    A spectrometer design is introduced which combines an acoustooptic tunable filter (AOTF) and IR-transmitting flouride-glass fibers. The AOTF crystal is fabricated from TeO2 and permits random access to any wavelength in less than 50 microseconds, and the resulting spectrometer is tested for the remote analysis of gases and hydrocarbons. The AOTF spectrometer, when operated with a high-speed frequency synthesizer and optimized algorithms, permits accurate high-speed spectroscopy in the mid-IR spectral region.

  9. Ims: The Infrared Mapping Spectrometer of The Bepicolombo Mission

    Science.gov (United States)

    Erard, S.

    The IR Spectrometer on board BepiColomboSs Planetary Orbiter aims at investigating the 0.8-2.8 micron range, where the absorption bands of major rock-forming miner- als are found. Spatial resolution values on the order of 100 m are needed for regolith mixing studies (~200U300 m mixing scale), while moderate spectral resolution only is required (~20-40 nm spectral sampling). Requirement for signal to noise ratio is * 100 in the whole spectral range. The baseline for the model payload is presented here. The optical system has a FOV of 256 mrad, and a focal length of 32 mm. The dis- persion system is a grating, feeding the radiation onto a 512x512 array. Line binning is performed by 4 in the spectral dimension to obtain 128 channels, with resulting IFOV of 0.5 mrad. The instrument works in pushbroom mode, with spectral disper- sion along the lines of the matrix, and spatial information along the other direction. A cryo-interface has to be provided to cool down the detector in the U153/-73C range. A complete low-resolution coverage of the planet is performed in 6 months, and repre- sents 30 Gbits with a data compression rate of 8 (lossy). A similar data rate is reserved for high-resolution observations from pericenter, so that the overall continuous trans- fer rate ranges from 4 to 12 kb/s, depending on compression rate. The main critical issues currently have to do with thermal control and marginally with data rates. A pos- sible approach is to set a cut-off at 2.8 micron to reduce the thermal load down to~0.29 W (external heat load on aperture). Filtering the visible range could also help reduce the thermal load on the detector by another factor of 2.

  10. Exploring the Saturn System in the Thermal Infrared: The Composite Infrared Spectrometer

    Science.gov (United States)

    Flasar, F. M.; Kunde, V. g.; Abbas, M. M.; Achterberg, R. K.; Ade, P.; Barucci, A.; Bezard, B.; Bjoraker, G. L.; Brasunas, J. C.; Calcutt, S.

    2004-01-01

    The Composite Inbred Spectrometer (CIRS) is a remote-sensing Fourier Transform Spectrometer on the Cassini orbiter that measures thermal radiation over two decades in wave number, from 10 to 1400 cm (1 mm to 7pm), with a spectral resolution that can be set from 0.5 to 20 cm. The far in portion of the spectrum (10 - 600 cm) is measured with a polarizing interferometer having thermopile detectors with a common 4-mrad field of view. The middle infrared portion is measured with a traditional Michelson interferometer having two focal planes (600 - 1100cm, 1100-1400 cm). Each focal plane is composed of a 1x10 array of HgCdTe detectors, each detector having a 0.3-mrad field of view. CIRS observations will provide three-dimensional maps of temperature, gas composition, and aerosols/condensates of the atmospheres of Titan and Saturn with good vertical and horizontal resolution, from deep in their tropospheres to high in their mesospheres. CIRS ability to observe atmospheres in the limb viewing mode (in addition to nadir) offers the opportunity to provide accurate and highly resolved vertical profiles of these atmospheric variables. The ability to observe with high-spectral resolution should facilitate the identification of new constituents. CIRS will also map the thermal and compositional properties of the surfaces of Saturn's icy satellites. It will similarly map Saturn's rings, characterizing their formation and evolution. The combination of broad spectral range, programmable spectral resolution, the small detector fields of view, and an orbiting spacecraft platform will allow CIRS to observe the Saturnian system in the thermal infrared at a level of detail not previously achieved.

  11. Magnetic suspension based Fourier Transform Infrared Spectrometer mechanism (FTIS)

    Science.gov (United States)

    Köker, Ingo; Langenbach, Harald; Schmid, Manfred; Lautier, Jean-Michel

    2005-07-01

    In the frame of an ESTEC technology contract the development of a Magnetically Suspended Fourier Transform Spectrometer Mechanism (FTIS) was carried out. The aim of the development is to avoid the issues found in mechanically suspended systems and to provide an active alignment and disturbance rejection capability for spectrometer applications. In the frame of FTIS an actively controlled suspension system based on the use of magnetic bearings was defined, developed and built as a demonstration model.

  12. Development of a near-infrared/mid-infrared dual-region spectrometer for online process analysis.

    Science.gov (United States)

    Genkawa, Takuma; Watari, Masahiro; Nishii, Takashi; Ozaki, Yukihiro

    2012-07-01

    A near-infrared (NIR) and mid-infrared (mid-IR) dual-region spectrometer having two immersion probes, a transmission probe for NIR, and an attenuated total reflection (ATR) probe for mid-IR has been developed for highly reliable process monitoring and deep process understanding. This spectrometer facilitates sequential acquisition of both NIR (10,000-4000 cm(-1)) and mid-IR (5000-1200 cm(-1)) spectra by switching the light path leading to the probes without the need for probe replacement. The use of a single light source and a single beam splitter enables achievement of a permanent alignment of the optical system and sequential data acquisition. The transmission NIR and ATR mid-IR probes designed and developed in the present study facilitate the acquisition of NIR/mid-IR spectra with optimized absorption intensities in both regions by simply placing the probes into a sample solution. The performance of the developed spectrometer was demonstrated in monitoring the ethanol fermentation process. NIR/mid-IR spectra of the fermentation solution with multiplicative scatter correction (MSC) represent the relative changes in the concentrations of glucose and ethanol in both regions. Principal component analysis (PCA) was performed on the MSC-treated spectra in the regions 6300-5650 cm(-1), 4850-4300 cm(-1), and 3500-2880 cm(-1) to detect the end-point of the fermentation as an example of process monitoring. For all the regions, the score plot of the first principal component (PC) indicates that the fermentation progresses with the fermentation time and stops after 210 minutes and thus the end-point of the fermentation exists at around 210 minutes. The loading plot indicates that all of the first PCs are the relative changes in the concentrations of glucose and ethanol. This result reveals that the same chemical changes are observed in both transmission NIR and ATR mid-IR spectra. Multiple and simultaneous analysis was also performed, and intensity change in light

  13. The (new) Mid-Infrared Spectrometer and Imager (MIRSI) for the NASA Infrared Telescope Facility

    Science.gov (United States)

    Hora, Joseph L.; Trilling, David; Mommert, Michael; Smith, Howard A.; Moskovitz, Nicholas; Marscher, Alan P.; Tokunaga, Alan; Bergknut, Lars; Bonnet, Morgan; Bus, Schelte J.; Connelly, Michael; Rayner, John; Watanabe, Darryl

    2015-11-01

    The Mid-Infrared Spectrometer and Imager (MIRSI) was developed at Boston University and has been in use since 2002 on the Infrared Telescope Facility (IRTF), making observations of asteroids, planets, and comets in the 2 - 25 μm wavelength range. Recently the instrument has been unavailable due to electronics issues and the high cost of supplying liquid helium on Maunakea. We have begun a project to upgrade MIRSI to a cryocooler-based system with new array readout electronics and a dichroic and optical camera to simultaneously image the science field for image acquisition and optical photometry. The mechanical cryocooler will enable MIRSI to be continuously mounted on the IRTF multiple instrument mount (MIM) along with the other facility instruments, making it available to the entire community for multi-wavelength imaging and spectral observations. We will propose to use the refurbished MIRSI to measure the 10 μm flux from Near Earth Objects (NEOs) and determine their diameters and albedos through the use of a thermal model. We plan to observe up to 750 NEOs over the course of a three year survey, most of whose diameters will be under 300 meters. Here we present an overview of the MIRSI upgrade and give the current status of the project.This work is funded by the NASA Solar System Observations/NEOO program.

  14. Cross contamination in dual inlet isotope ratio mass spectrometers

    NARCIS (Netherlands)

    Meijer, H.A.J.; Neubert, R.E.M.; Visser, G.H.

    2000-01-01

    Since the early days of geochemical isotope ratio mass spectrometry there has always been the problem of cross contamination, i.e. the contamination of the sample gas with traces of reference gas land vice versa) in a dual inlet system and the analyzer itself. This was attributable to valve leakages

  15. Dualband infrared imaging spectrometer: observations of the moon

    Science.gov (United States)

    LeVan, Paul D.; Beecken, Brian P.; Lindh, Cory

    2008-08-01

    We reported previously on full-disk observations of the sun through a layer of black polymer, used to protect the entrance aperture of a novel dualband spectrometer while transmitting discrete wavelength regions in the MWIR & LWIR1. More recently, the spectrometer was used to assess the accuracy of recovery of unknown blackbody temperatures2. Here, we briefly describe MWIR observations of the full Moon made in Jan 2008. As was the case for the solar observations, the Moon was allowed to drift across the spectrometer slit by Earth's rotation. A detailed sensor calibration performed prior to the observations accounts for sensor non-uniformities; the spectral images of the Moon therefore include atmospheric transmission features. Our plans are to repeat the observations at liquid helium temperatures, thereby allowing both MWIR & LWIR spectral coverage.

  16. Short-Wave Near-Infrared Spectrometer for Alcohol Determination and Temperature Correction

    Directory of Open Access Journals (Sweden)

    Qingbo Fu

    2012-01-01

    Full Text Available A multichannel short-wave near-infrared (SW-NIR spectrometer module based on charge-coupled device (CCD detection was designed. The design relied on a tungsten lamp enhanced by light emitting diodes, a fixed grating monochromator and a linear CCD array. The main advantages were high optical resolution and an optimized signal-to-noise ratio (0.24 nm and 500, resp. in the whole wavelength range of 650 to 1100 nm. An application to alcohol determination using partial least squares calibration and the temperature correction was presented. It was found that the direct transfer method had significant systematic prediction errors due to temperature effect. Generalized least squares weighting (GLSW method was utilized for temperature correction. After recalibration, the RMSEP found for the 25°C model was 0.53% v/v and errors of the same order of magnitude were obtained at other temperatures (15, 35 and 40°C. And an 2 better than 0.99 was achieved for each validation set. The possibility and accuracy of using the miniature SW-NIR spectrometer and GLSW transfer calibration method for alcohol determination at different temperatures were proven. And the analysis procedure was simple and fast, allowing a strict control of alcohol content in the wine industry.

  17. An optically detected magnetic resonance spectrometer with tunable laser excitation and wavelength resolved infrared detection

    CERN Document Server

    Negyedi, M; Gyüre, B; Dzsaber, S; Kollarics, S; Rohringer, P; Pichler, T; Simon, F

    2016-01-01

    We present the development and performance of an optically detected magnetic resonance (ODMR) spectrometer. The spectrometer represents advances over similar instruments in three areas: i) the exciting light is a tunable laser source which covers much of the visible light range, ii) the optical signal is analyzed with a spectrograph, iii) the emitted light is detected in the near-infrared domain. The need to perform ODMR experiments on single-walled carbon nanotubes motivated the present development and we demonstrate the utility of the spectrometer on this material. The performance of the spectrometer is critically compared to similar instruments. The present development opens the way to perform ODMR studies on various new materials such as molecules and luminescent quantum dots where the emission is in the near-infrared range and requires a well-defined excitation wavelength and analysis of the scattered light.

  18. A graphene-based Fabry-Pérot spectrometer in mid-infrared region

    Science.gov (United States)

    Wang, Xiaosai; Chen, Chen; Pan, Liang; Wang, Jicheng

    2016-08-01

    Mid-infrared spectroscopy is of great importance in many areas and its integration with thin-film technology can economically enrich the functionalities of many existing devices. In this paper we propose a graphene-based ultra-compact spectrometer (several micrometers in size) that is compatible with complementary metal-oxide-semiconductor (CMOS) processing. The proposed structure uses a monolayer graphene as a mid-infrared surface waveguide, whose optical response is spatially modulated using electric fields to form a Fabry-Pérot cavity. By varying the voltage acting on the cavity, we can control the transmitted wavelength of the spectrometer at room temperature. This design has potential applications in the graphene-silicon-based optoelectronic devices as it offers new possibilities for developing new ultra-compact spectrometers and low-cost hyperspectral imaging sensors in mid-infrared region.

  19. Development and Deployment of Retrofit PolarisQ Ion Trap Mass Spectrometer for Isotope Ratio Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Cyril V. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Whitten, William B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-11-01

    This report describes Oak Ridge National Laboratory’s (ORNL) FY15 progress in support of National Nuclear Security Administration’s (NNSA) Portable Mass Spectrometer project. A retrofit PolarisQ ion trap mass spectrometer (RPMS) has been assembled from components of two PolarisQ ion trap mass spectrometers used in previous isotope ratio programs. The retrofit mass spectrometer includes a custom Hastelloy vacuum chamber which is about ¼ the size of the standard aluminum vacuum chamber and reduces the instrument weight from the original by nine pounds. In addition, the new vacuum chamber can be independently heated to reduce impurities such as water, which reacts with UF6 to produce HF in the vacuum chamber. The analyzer and all components requiring service are mounted on the chamber lid, facilitating quick and easy replacement of consumable components such as the filament and electron multiplier.

  20. FAR-INFRARED LINE SPECTRA OF SEYFERT GALAXIES FROM THE HERSCHEL-PACS SPECTROMETER

    Energy Technology Data Exchange (ETDEWEB)

    Spinoglio, Luigi; Pereira-Santaella, Miguel; Busquet, Gemma [Istituto di Astrofisica e Planetologia Spaziali, INAF, Via Fosso del Cavaliere 100, I-00133 Roma (Italy); Dasyra, Kalliopi M. [Observatoire de Paris, LERMA (CNRS:UMR8112), 61 Av. de l' Observatoire, F-75014, Paris (France); Calzoletti, Luca [Agenzia Spaziale Italiana (ASI) Science Data Center, I-00044 Frascati (Roma) (Italy); Malkan, Matthew A. [Astronomy Division, University of California, Los Angeles, CA 90095-1547 (United States); Tommasin, Silvia, E-mail: luigi.spinoglio@iaps.inaf.it [Weizmann Institute of Science, Department of Neurobiology, Rehovot 76100 (Israel)

    2015-01-20

    We observed the far-IR fine-structure lines of 26 Seyfert galaxies with the Herschel-PACS spectrometer. These observations are complemented with Spitzer Infrared Spectrograph and Herschel SPIRE spectroscopy. We used the ionic lines to determine electron densities in the ionized gas and the [C I] lines, observed with SPIRE, to measure the neutral gas densities, while the [O I] lines measure the gas temperature, at densities below ∼10{sup 4} cm{sup –3}. Using the [O I]145 μm/63 μm and [S III]33/18 μm line ratios, we find an anti-correlation of the temperature with the gas density. Various fine-structure line ratios show density stratifications in these active galaxies. On average, electron densities increase with the ionization potential of the ions. The infrared lines arise partly in the narrow line region, photoionized by the active galactic nucleus (AGN), partly in H II regions photoionized by hot stars, and partly in photo-dissociated regions. We attempt to separate the contributions to the line emission produced in these different regions by comparing our observed emission line ratios to theoretical values. In particular, we tried to separate the contribution of AGNs and star formation by using a combination of Spitzer and Herschel lines, and we found that besides the well-known mid-IR line ratios, the line ratio of [O III]88 μm/[O IV]26 μm can reliably discriminate the two emission regions, while the far-IR line ratio of [C II]157 μm/[O I]63 μm is only able to mildly separate the two regimes. By comparing the observed [C II]157 μm/[N II]205 μm ratio with photoionization models, we also found that most of the [C II] emission in the galaxies we examined is due to photodissociation regions.

  1. Pocket-size near-infrared spectrometer for narcotic materials identification

    Science.gov (United States)

    Pederson, Christopher G.; Friedrich, Donald M.; Hsiung, Chang; von Gunten, Marc; O'Brien, Nada A.; Ramaker, Henk-Jan; van Sprang, Eric; Dreischor, Menno

    2014-05-01

    While significant progress has been made towards the miniaturization of Raman, mid-infrared (IR), and near-infrared (NIR) spectrometers for homeland security and law enforcement applications, there remains continued interest in pushing the technology envelope for smaller, lower cost, and easier to use analyzers. In this paper, we report on the use of the MicroNIR Spectrometer, an ultra-compact, handheld near infrared (NIR) spectrometer, the, that weighs less than 60 grams and measures heroin, oxycodone, diazepam), as well as synthetic cathinones (also known as bath salts), and synthetic cannabinoids. A library of the materials was created from a master MicroNIR spectrometer. A set of 25 unknown samples were then identified with three other MicroNIRs showing: 1) the ability to correctly identify the unknown with a very low rate of misidentification, and 2) the ability to use the same library with multiple instruments. In addition, we have shown that through the use of innovative chemometric algorithms, we were able to identify the individual compounds that make up an unknown mixture based on the spectral library of the individual compounds only. The small size of the spectrometer is enabled through the use of high-performance linear variable filter (LVF) technology.

  2. User Guide to the PDS Dataset for the Cassini Composite Infrared Spectrometer (CIRS)

    Science.gov (United States)

    Nixon, Conor A.; Kaelberer, Monte S.; Gorius, Nicolas

    2012-01-01

    This User Guide to the Cassini Composite Infrared Spectrometer (CIRS) has been written with two communities in mind. First and foremost, scientists external to the Cassini Project who seek to use the CIRS data as archived in the Planetary Data System (PDS). In addition, it is intended to be a comprehensive reference guide for those internal to the CIRS team.

  3. Postdispersion system for astronomical observations with Fourier transform spectrometers in the thermal infrared

    Science.gov (United States)

    Wiedermann, Guenter; Jennings, D. E.; Hanel, R. H.; Kunde, V. G.; Moseley, S. H.

    1989-01-01

    A postdispersion system for astronomical observations with Fourier transform spectrometers in the thermal infrared has been developed which improves the sensitivity of radiation noise limited observations by reducing the spectral range incident on the detector. Special attention is given to the first-generation blocked impurity band detector. Planetary, solar, and stellar observations are reported.

  4. Investigate the relationship between multiwavelength lidar ratios and aerosol size distributions using aerodynamic particle sizer spectrometer

    Science.gov (United States)

    Zhao, Hu; Hua, Dengxin; Mao, Jiandong; Zhou, Chunyan

    2017-02-01

    The real aerosol size distributions were obtained by aerodynamic particle sizer spectrometer (APS) in China YinChuan. The lidar ratios at wavelengths of 355 nm, 532 nm and 1064 nm were calculated using Mie theory. The effective radius of aerosol particles reff and volume C/F ratio (coarse/fine) Vc/f were retrieved from the real aerosol size distributions. The relationship between multiwavelength lidar ratios and particle reff and Vc/f were investigated. The results indicate that the lidar ratio is positive correlated to the particle reff and Vc/f. The lidar ratio is more sensitive to the coarse particles. The short wavelength lidar ratio is more sensitive to the particle Vc/f and the long wavelength lidar ratio is more sensitive to the particle reff. The wavelength dependency indicated that the lidar ratios decrease with increasing the wavelength. The lidar ratios are almost irrelevant to the shape and total particles of aerosol size distributions.

  5. Aircraft laser infrared absorption spectrometer (ALIAS) for polar ozone studies

    Science.gov (United States)

    Webster, C. R.; May, R. D.

    1991-01-01

    The ALIAS instrument is a very high resolution (0.0003/cm) scanning, tunable diode laser spectrometer designed to make direct, simultaneous measurements of NO2, HNO3, HCl, CH4, and either O3 or N2O (including vertical profiles of CH4 and N2O) in the polar stratosphere at sub-part-per-billion level sensitivities over integration times from 3 to 30 s. Unique features include a sample inlet/throttle system designed to achieve near-isokinetic sampling, in PSC events, an in-flight wavelength reference cell rack, mechanical fringe-spoilers, a four-laser/four-detector dewar with 24-hr hold-time operating at a fixed temperature without electrical regulation, and in-flight fast correlation routines for spectral drift compensation prior to spectral addition. Instrument design and test flight results are discussed in the light of ALIAS's role in the Winter 1991 Arctic aircraft stratospheric ozone campaigns out of Fairbanks, Alaska, and Bangor, Maine.

  6. [Design and implementation of a long wavelength near infrared spectrometer based on MEMS scanning mirror].

    Science.gov (United States)

    Ye, Kun-Tao; Dong, Tai-Yuan; He, Wen-Xi; Li, Yu-Xiao; Cheng, Xian-Ming; Li, Guang-Yong; Li, Hao-Yu; Xu, Hao-Yu

    2014-10-01

    Long Wavelength Near InfraRed (LW-NIR) spectrometer has wide applications. Miniaturization and low-cost are two major goals of the development of LW-NIR spectrometer in the industrial or research community. Under the background that having a trend of spectrometer miniaturization and integration, method and main problems involved in miniaturization of LW-NIR spectrometer through MEMS scanning mirror, such as the design strategy of the light-splitting optical system, selection considerations of the MEMS scanning mirror, design method of the preamplifier circuit, etc, have been presented in detail. A prototype of miniaturized LW-NIR spectrometer, with the spectrum range of detection of 900-2,055 nm, is designed and implemented using MEMS scanning mirror, InGaAs single detector unit with high sensitivity. Littrow optical layout is used for its light-splitting optical system, and the spectral resolution is between 9.4-16 nm at 1,000-1,965 nm detection wavelength range. The prototype is successfully applied in LW-NIR spectrum measurement on pure water and ethanol aqueous solution, and a forecast analysis on ethanol aqueous solution concentration is also demonstrated. Through adopting MEMS scanning mirror into the spectrometer system, the complexity of the mechanical scanning fixtures and its controlling mechanism is greatly reduced therefore the size of the spectrometer is reduced. Furthermore, due to MEMS scanning mirror technology, LW-NIR spectrometer with single InGaAs detector is achieved, thus the cost reduction of the NIR spectrometer system is also realized because the expensive InGaAs arrays are avoided.

  7. The Cosmic Infrared Background Experiment: Flight Characterization Of The Ciber Narrow Band Spectrometer.

    Science.gov (United States)

    Levenson, Louis R.; Battle, J.; Bock, J. J.; Cooray, A.; Hristov, V.; Keating, B.; Lee, D.; Mason, P.; Matsumoto, T.; Matsuura, S.; Nam, U. W.; Renbarger, T.; Sullivan, I.; Suzuki, K.; Wada, T.; Zemcov, M.

    2011-01-01

    Subtraction of the Zodiacal light foreground is the dominant source of uncertainty in absolute photometric measurements of the extra-galactic background at near-infrared to optical wavelengths. The second flight of the Cosmic Infrared Background ExpeRiment (CIBER) occurred on July 10th, 2010. CIBER is a NASA sounding rocket experiment carrying four co-aligned instruments including two imaging telescopes with wide passbands centered at 1 and 1.6 microns, respectively, as well as a low resolution spectrometer and a narrow-band spectrometer. THE CIBER spectrometers are absolutely calibrated in collaboration with NIST. The narrow-band spectrometer filter is centered on the Ca II solar Fraunhofer line at 854.2 nm and is designed to measure the equivalent width of the solar line reflected by the interplanetary dust in order to obtain an absolute measurement of the Zodiacal contribution to the infrared sky at that wavelength. In conjunction with measured low resolution spectrum from 700 to 1900 nm, this will provide an accurate independent check of the DIRBE Zodiacal light models. Here we describe the NBS instrument, calibration and in-flight characterization.

  8. Widely tunable rapid-scanning mid-infrared laser spectrometer for industrial gas process stream analysis.

    Science.gov (United States)

    Bamford, Douglas J; Cook, David J; Sharpe, Scott J; Van Pelt, Aaron D

    2007-07-01

    A mid-infrared spectrometer with a tuning range of >400 cm(-1) in the C-H stretching region of the spectrum has been designed and constructed. The spectrometer is based on the difference-frequency generation of two tunable diode lasers in periodically poled lithium niobate waveguides. Tuning is achieved by varying a single parameter, the wavelength of one of the near-infrared input lasers. The instrument can be tuned over the entire tuning range in less than 1 s. By taking advantage of the wide tuning range, the instrument has been used to analyze a mixture of methane, ethylene, and propylene. Each of these major components was measured with an accuracy of better than 2% (where the error is defined as a percentage of the measured value) in a single 30 s long scan. When optimized, the spectrometer has the potential to meet both the performance requirements and the practical requirements for real-time process control in petrochemical manufacturing. The general principles for the design of mid-infrared spectrometers with wide tuning ranges are explained, including the use of variable waveguide fabrication recipes to create broad phase-matching resonances (which lead to broad tuning) in the desired location.

  9. Reproducible quantification of ethanol in gasoline via a customized mobile near-infrared spectrometer.

    Science.gov (United States)

    Lutz, Oliver M D; Bonn, Günther K; Rode, Bernd M; Huck, Christian W

    2014-05-15

    This work describes the modification of an InGaAs diode array detector equipped miniaturized near-infrared (NIR) spectrometer enabling the reliable quantification of ethanol blended gasoline. A transflectance measurement cell is presented, utilizing a thermoelectric cooling (TEC) appliance ensuring thermostatic measurement conditions and a gold-coated spherical mirror as a reflector superior to conventional Spectralon(®). In total, four measurement modes (Spectralon(®) reflector, gold reflector and either reflectors with employed TEC) are discussed, enabling a straightforward comparison of the results. The test-set validated multivariate partial least squares regression (PLSR) model of the measurement mode involving both gold mirror and TEC yielded an Rval(2) value of 0.997, a limit of detection (LOD) of 0.68% w/w, a limit of quantification (LOQ) of 2.04% w/w, a standard error of prediction (SEP) of 0.21% w/w and a ratio performance deviation (RPD) of 15.2 while utilizing a single latent variable (LV). The NIR band assignment in this work has been established by employing the vibrational self-consistent field second order perturbative treatment (PT2-VSCF) and the computationally derived absorption maxima are compared to the experimentally observed data.

  10. Detection of fatty product falsifications using a portable near infrared spectrometer

    Science.gov (United States)

    Kalinin, A. V.; Krasheninnikov, V. N.

    2016-12-01

    Spreading sales of counterfeited fatty-oil foods leads to a development of portable and operational analyzer of typical fatty acids (FA) which may be a near infrared (NIR) spectrometer. In this work the calibration models for prediction of named FA were built with the spectra of FT-NIR spectrometer for different absorption bands of the FA. The best parameters were obtained for the wavelength sub-band 1.0-1.8 μ, which includes the 2nd and 3rd overtones of C-H stretching vibrations (near 1.7 and 1.2 μ) and the combination band (1.42 μ). Applicability of the portable spectrometer based on linear NIR array photosensor for the quality analysis of spread, butter and fish oil by the typical FA has been tested.

  11. Detection of fatty product falsifications using a portable near infrared spectrometer

    Science.gov (United States)

    Kalinin, A. V.; Krasheninnikov, V. N.

    2017-01-01

    Spreading sales of counterfeited fatty-oil foods leads to a development of portable and operational analyzer of typical fatty acids (FA) which may be a near infrared (NIR) spectrometer. In this work the calibration models for prediction of named FA were built with the spectra of FT-NIR spectrometer for different absorption bands of the FA. The best parameters were obtained for the wavelength sub-band 1.0-1.8 μ, which includes the 2nd and 3rd overtones of C-H stretching vibrations (near 1.7 and 1.2 μ) and the combination band (1.42 μ). Applicability of the portable spectrometer based on linear NIR array photosensor for the quality analysis of spread, butter and fish oil by the typical FA has been tested.

  12. Spaceborne infrared Fourier-transform spectrometers for temperature and humidity sounding of the Earth's atmosphere

    Science.gov (United States)

    Golovin, Yu. M.; Zavelevich, F. S.; Nikulin, A. G.; Kozlov, D. A.; Monakhov, D. O.; Kozlov, I. A.; Arkhipov, S. A.; Tselikov, V. A.; Romanovskii, A. S.

    2014-12-01

    A spaceborne Fourier-transform infrared (FTIR) spectrometer was designed for measuring the spectra of the outgoing Earth's atmosphere radiation and serves for providing for the needs of online meteorology and climatology with regard to obtaining the following kinds of data: vertical profiles of temperature and humidity profiles in the troposphere and the lower stratosphere, the general and altitudinal ozone distribution, concentrations of small gaseous constituents, temperature of the underlying surface, etc. At present, works are underway at the Keldysh Research Centre for creating IKFS-series FTIR spectrometers for satellites in Sun-synchronous orbits: the IKFS-2 instrument for the Meteor-M spacecraft no. 2 of the Meteor-3M space complex (developed and supplied for testing together with the spacecraft) and an advanced IKFS-3 instrument for the Meteor-MP fourth-generation hydrometeorological and oceanographic space complex for Earth monitoring (at the developmental stage). The composition, functional diagram, and technical specifications of the FTIR spectrometers are presented.

  13. Compact diode-laser spectrometer ISOWAT for highly sensitive airborne measurements of water-isotope ratios

    Science.gov (United States)

    Dyroff, C.; Fütterer, D.; Zahn, A.

    2010-02-01

    The tunable diode-laser absorption spectrometer ISOWAT for airborne measurements of the water-isotope ratios 18O/16O and D/H is described. The spectrometer uses a distributed feedback (DFB) diode laser to probe fundamental rovibrational water-absorption lines at around 2.66 μm. Very-low-noise system components along with signal averaging allow for a detection limit of 1.2 and 4.5 ‰ for measurements of 18O/16O and D/H, respectively, for a water-vapour mixing ratio of 100 ppmv and an averaging time of 60 s. This corresponds to a minimum detectable absorbance of ˜5×10-6 or ˜6.6×10-10 cm-1 when normalized to pathlength. In addition to its high sensitivity, the spectrometer is highly compact (19-inch rack at a height of 35 cm, excluding pump and calibration unit) and light weight (automated. ISOWAT will be calibrated during flight with known water-isotope ratios using a compact calibration-gas source.

  14. THIS -- next-generation mid-infrared remote sensing of planetary atmospheres using a tuneable heterodyne infrared spectrometer

    Science.gov (United States)

    Sonnabend, G.; Wirtz, D.; Vetterle, V.; Schieder, R.

    2003-12-01

    The Cologne spectrometer THIS (Tuneable Heterodyne Infrared Spectrometer) opens the mid-infrared wavelength region from 8 to 17 microns to ultra-high-resolution spectroscopy. The main scientific goal of THIS is to analyze highly resolved lineshape data of molecules (e.g. O3, NH3, CH4, N2O, HxCy etc.) to deduce physical parameters like wind velocities or height profiles of gases in either the Earth's or other planetary atmospheres. Also astronomical observations of non-solar-system IR-sources like IRC+10216 as well as the measurement of pure rotational transitions of H2 in the interstellar-medium from ground based telescopes are planned in the near future. THIS is a proposed second-generation instrument for the stratospheric observatory SOFIA. With a system noise temperature of less than three times the quantum limit THIS is the first widely tuneable and transportable infrared heterodyne receiver having a sensitivity equivalent to CO2-laser based heterodyne systems. A quantum-cascade-laser is used as local oscillator. Its radiation is superimposed to that from the signal by use of a Fabry-Perot ring-resonator to provide optimum efficiency. The frequency mixing is done by a Mercury-Cadmium-Telluride photomixer and spectral analysis with a resolution of up to 3x107 is performed by means of an Acousto-Optical spectrometer. We report on THIS' successful first observing run performed at the west auxiliary telescope at McMath-Pierce solar observatory on Kitt Peak/Arizona in 11/2002. Very weak non-LTE CO2 emission from the atmosphere of Venus have been observed as well as trace gases in Earth's atmosphere and molecular features in sunspots.

  15. Near-infrared transmission spectroscopy of aqueous solutions: The influence of optical pathlength on signal-to-noise ratio

    DEFF Research Database (Denmark)

    Jensen, P.S.; Bak, J.

    2002-01-01

    The optimal choice of optical pathlength, source intensity, and detector for near-infrared transmission measurements of trace components in aqueous solutions depends on the strong absorption of water. In this study we examine under which experimental circumstances one may increase the pathlength...... to obtain a measurement with higher signal-to-noise ratio. The noise level of measurements at eight different pathlengths from 0.2 to 2.0 mm of pure water and of 1 g/dL aqueous glucose signals were measured using a Fourier transform near-infrared spectrometer and a variable pathlength transmission cell...

  16. Authentication of Whey Protein Powders by Portable Mid-Infrared Spectrometers Combined with Pattern Recognition Analysis.

    Science.gov (United States)

    Wang, Ting; Tan, Siow Ying; Mutilangi, William; Aykas, Didem P; Rodriguez-Saona, Luis E

    2015-10-01

    The objective of this study was to develop a simple and rapid method to differentiate whey protein types (WPC, WPI, and WPH) used for beverage manufacturing by combining the spectral signature collected from portable mid-infrared spectrometers and pattern recognition analysis. Whey protein powders from different suppliers are produced using a large number of processing and compositional variables, resulting in variation in composition, concentration, protein structure, and thus functionality. Whey protein powders including whey protein isolates, whey protein concentrates and whey protein hydrolysates were obtained from different suppliers and their spectra collected using portable mid-infrared spectrometers (single and triple reflection) by pressing the powder onto an Attenuated Total Reflectance (ATR) diamond crystal with a pressure clamp. Spectra were analyzed by soft independent modeling of class analogy (SIMCA) generating a classification model showing the ability to differentiate whey protein types by forming tight clusters with interclass distance values of >3, considered to be significantly different from each other. The major bands centered at 1640 and 1580 cm(-1) were responsible for separation and were associated with differences in amide I and amide II vibrations of proteins, respectively. Another important band in whey protein clustering was associated with carboxylate vibrations of acidic amino acids (∼1570 cm(-1)). The use of a portable mid-IR spectrometer combined with pattern recognition analysis showed potential for discriminating whey protein ingredients that can help to streamline the analytical procedure so that it is more applicable for field-based screening of ingredients. A rapid, simple and accurate method was developed to authenticate commercial whey protein products by using portable mid-infrared spectrometers combined with chemometrics, which could help ensure the functionality of whey protein ingredients in food applications. © 2015

  17. SNR analysis and Hadamard mask modification of DMD Hadamard Transform Near-Infrared spectrometer

    Science.gov (United States)

    Xu, Jia-lin; Liu, Hua; Lin, Chun-bo; Sun, Qiang

    2017-01-01

    The noise of Hadamard Transform (HT) Near Infrared (NIR) spectrometer includes not only the detector circuit noise but also the illumination noise. Hadamard Transform reduces the detector noise while increases the illumination noise. If the relative power intensity is large, the noise of Hadamard method will be greater than that of scanning method. This will lose the significance of Hadamard Transform. In this paper the SNRs of the Hadamard method and scanning method are analyzed. The condition of boosting SNR of spectrometer by Hadamard transform is given. When the condition is not matched, a Hadamard mask of variable height stripes is proposed which the SNR of Hadamard method can be improved. In this paper a HT NIR spectrometer based on 0.45-inch DMD is designed with the spectrum range from 1350 nm to 2500 nm. Several experiments are done with the designed spectrometer. It is shown that with the Hadamard mask of variable height stripes the average SNR is improved by a factor of 2.2 at the short wavelength band and by a factor of 2.8 on the long wavelength band, and the minimum SNR on the whole wavelength band is improved by a factor of 2.3.

  18. The Cosmic Infrared Background Experiment (CIBER): The Narrow-Band Spectrometer

    Science.gov (United States)

    Korngut, P. M.; Renbarger, T.; Arai, T.; Battle, J.; Bock, J.; Brown, S. W.; Cooray, A.; Hristov, V.; Keating, B.; Kim, M. G.; Lanz, A.; Lee, D. H.; Levenson, L. R.; Lykke, K. R.; Mason, P.; Matsumoto, T.; Matsuura, S.; Nam, U. W.; Shultz, B.; Smith, A. W.; Sullivan, I.; Tsumura, K.; Wada, T.; Zemcov, M.

    2013-08-01

    We have developed a near-infrared spectrometer designed to measure the absolute intensity of the solar 854.2 nm Ca II Fraunhofer line, scattered by interplanetary dust, in the zodiacal light (ZL) spectrum. Based on the known equivalent line width in the solar spectrum, this measurement can derive the zodiacal brightness, testing models of the ZL based on morphology that are used to determine the extragalactic background light in absolute photometry measurements. The spectrometer is based on a simple high-resolution tipped filter placed in front of a compact camera with wide-field refractive optics to provide the large optical throughput and high sensitivity required for rocket-borne observations. We discuss the instrument requirements for an accurate measurement of the absolute ZL brightness, the measured laboratory characterization, and the instrument performance in flight.

  19. THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE NARROW-BAND SPECTROMETER

    Energy Technology Data Exchange (ETDEWEB)

    Korngut, P. M.; Bock, J. [Jet Propulsion Laboratory (JPL), National Aeronautics and Space Administration (NASA), Pasadena, CA 91109 (United States); Renbarger, T.; Keating, B. [Department of Physics, University of California, San Diego, San Diego, CA 92093 (United States); Arai, T.; Matsumoto, T.; Matsuura, S. [Department of Space Astronomy and Astrophysics, Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA), Sagamihara, Kanagawa 252-5210 (Japan); Battle, J.; Hristov, V.; Lanz, A.; Levenson, L. R.; Mason, P. [Department of Physics, California Institute of Technology, Pasadena, CA 91125 (United States); Brown, S. W.; Lykke, K. R.; Smith, A. W. [Sensor Science Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Cooray, A. [Center for Cosmology, University of California, Irvine, Irvine, CA 92697 (United States); Kim, M. G. [Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Lee, D. H.; Nam, U. W. [Korea Astronomy and Space Science Institute (KASI), Daejeon 305-348 (Korea, Republic of); Shultz, B., E-mail: pkorngut@caltech.edu [Materion Barr Precision Optics and Thin Film Coatings, Westford, MA 01886 (United States); and others

    2013-08-15

    We have developed a near-infrared spectrometer designed to measure the absolute intensity of the solar 854.2 nm Ca II Fraunhofer line, scattered by interplanetary dust, in the zodiacal light (ZL) spectrum. Based on the known equivalent line width in the solar spectrum, this measurement can derive the zodiacal brightness, testing models of the ZL based on morphology that are used to determine the extragalactic background light in absolute photometry measurements. The spectrometer is based on a simple high-resolution tipped filter placed in front of a compact camera with wide-field refractive optics to provide the large optical throughput and high sensitivity required for rocket-borne observations. We discuss the instrument requirements for an accurate measurement of the absolute ZL brightness, the measured laboratory characterization, and the instrument performance in flight.

  20. High resolution infrared spectroscopy of planetary molecules using diode lasers and Fourier transform spectrometers

    Science.gov (United States)

    Jennings, Donald E.

    1990-01-01

    Modern observations of infrared molecular lines in planets are performed at spectral resolutions which are as high as those available in the laboratory. Analysis of such data requires laboratory measurements at the highest possible resolution, which also yield accurate line positions and intensities. For planetary purposes the spectrometer must be coupled to sample cells which can be reduced in temperature and varied in pressure. An approach which produces the full range of required molecular line parameters uses a combination of tunable diode lasers and Fourier transform spectrometers (FTS). The FTS provides board spectral coverage and good calibration accuracy, while the diode laser can be used to study those regions which are not resolved by the FTS.

  1. JIRAM, the image spectrometer in the near infrared on board the Juno mission to Jupiter.

    Science.gov (United States)

    Adriani, Alberto; Coradini, Angioletta; Filacchione, Gianrico; Lunine, Jonathan I; Bini, Alessandro; Pasqui, Claudio; Calamai, Luciano; Colosimo, Fedele; Dinelli, Bianca M; Grassi, Davide; Magni, Gianfranco; Moriconi, Maria L; Orosei, Roberto

    2008-06-01

    The Jovian InfraRed Auroral Mapper (JIRAM) has been accepted by NASA for inclusion in the New Frontiers mission "Juno," which will launch in August 2011. JIRAM will explore the dynamics and the chemistry of Jupiter's auroral regions by high-contrast imaging and spectroscopy. It will also analyze jovian hot spots to determine their vertical structure and infer possible mechanisms for their formation. JIRAM will sound the jovian meteorological layer to map moist convection and determine water abundance and other constituents at depths that correspond to several bars pressure. JIRAM is equipped with a single telescope that accommodates both an infrared camera and a spectrometer to facilitate a large observational flexibility in obtaining simultaneous images in the L and M bands with the spectral radiance over the central zone of the images. Moreover, JIRAM will be able to perform spectral imaging of the planet in the 2.0-5.0 microm interval of wavelengths with a spectral resolution better than 10 nm. Instrument design, modes, and observation strategy will be optimized for operations onboard a spinning satellite in polar orbit around Jupiter. The JIRAM heritage comes from Italian-made, visual-infrared imaging spectrometers dedicated to planetary exploration, such as VIMS-V on Cassini, VIRTIS on Rosetta and Venus Express, and VIR-MS on the Dawn mission.

  2. Calibration of the AKARI Far-Infrared Imaging Fourier Transform Spectrometer

    CERN Document Server

    Murakami, Noriko; Takahashi, Hidenori; Okada, Yoko; Yasuda, Akiko; Ootsubo, Takafumi; Kaneda, Hidehiro; Matsuo, Hiroshi; Baluteau, Jean-Paul; Davis-Imhof, Peter; Gom, Brad G; Naylor, David A; Zavagno, Annie; Yamamura, Issei; Matsuura, Shuji; Shirahata, Mai; Doi, Yasuo; Nakagawa, Takao; Shibai, Hiroshi

    2010-01-01

    The Far-Infrared Surveyor (FIS) onboard the AKARI satellite has a spectroscopic capability provided by a Fourier transform spectrometer (FIS-FTS). FIS-FTS is the first space-borne imaging FTS dedicated to far-infrared astronomical observations. We describe the calibration process of the FIS-FTS and discuss its accuracy and reliability. The calibration is based on the observational data of bright astronomical sources as well as two instrumental sources. We have compared the FIS-FTS spectra with the spectra obtained from the Long Wavelength Spectrometer (LWS) of the Infrared Space Observatory (ISO) having a similar spectral coverage. The present calibration method accurately reproduces the spectra of several solar system objects having a reliable spectral model. Under this condition the relative uncertainty of the calibration of the continuum is estimated to be $\\pm$ 15% for SW, $\\pm$ 10% for 70-85 cm^(-1) of LW, and $\\pm$ 20% for 60-70 cm^(-1) of LW; and the absolute uncertainty is estimated to be +35/-55% for...

  3. The Airborne Visible / Infrared Imaging Spectrometer AVIS: Design, Characterization and Calibration

    Directory of Open Access Journals (Sweden)

    Wolfram Mauser

    2007-09-01

    Full Text Available The Airborne Visible / Infrared imaging Spectrometer AVIS is a hyperspectralimager designed for environmental monitoring purposes. The sensor, which wasconstructed entirely from commercially available components, has been successfullydeployed during several experiments between 1999 and 2007. We describe the instrumentdesign and present the results of laboratory characterization and calibration of the system’ssecond generation, AVIS-2, which is currently being operated. The processing of the datais described and examples of remote sensing reflectance data are presented.

  4. Design and fabrication of step mirrors used in space-modulated Fourier transform infrared spectrometer.

    Science.gov (United States)

    Zheng, Ying; Liang, Jingqiu; Liang, Zhongzhu

    2013-01-14

    A model of miniaturized space-modulated Fourier transform infrared spectrometer (FTIR) is given. The two step mirrors as the key components are designed and a lithography-electroplating technique used to fabricate the small step mirror is proposed. We analyze the effect of the experiment results resulted from fabricating technics on the recovery spectrum in theory, and demonstrate that the lithography-electroplating technique is an effective method to fabricate the step mirror, which make miniaturized FTIR realized. We believe that the performances of FTIR can be better realized by optimizing experimental conditions to make this fabricating method more attractive.

  5. Planetary infrared astronomy using a cryogenic postdisperser on Fourier transform spectrometers

    Science.gov (United States)

    Jennings, D. E.; Kunde, V. G.; Hanel, R. A.; Maguire, W. C.; Lamb, G. M.

    1986-01-01

    High resolution infrared spectra of planets from ground-based observatories were analyzed and instrumentation to improve sensitivity was developed. A cryogenic postdisperser (a narrow bandpass spectral filter) for use with Fourier transform spectrometers (FTS's) at facility observatories was constructed. This instrument has improved the sensitivity of FTS observations at 8 to 20 microns by about an order of magnitude. Spectra of Jupiter, Saturn and Comet Halley were obtained using the postdisperser with FTS facilities at the Kitt Peak 4-meter and McMath telescopes. Spectral resolution as high as 0.01/cm was achieved.

  6. Design of spatio-temporally modulated static infrared imaging Fourier transform spectrometer.

    Science.gov (United States)

    Wang, WenCong; Liang, JingQiu; Liang, ZhongZhu; Lü, JinGuang; Qin, YuXin; Tian, Chao; Wang, WeiBiao

    2014-08-15

    A novel static medium wave infrared (MWIR) imaging Fourier transform spectrometer (IFTS) is conceptually proposed and experimentally demonstrated. In this system, the moving mirror in traditional temporally modulated IFTS is replaced by multi-step micro-mirrors to realize the static design. Compared with the traditional spatially modulated IFTS, they have no slit system and are superior with larger luminous flux and higher energy efficiency. The use of the multi-step micro-mirrors can also make the system compact and light.

  7. Infrared Supernova Remnants and their Infrared to X-ray Flux Ratios

    CERN Document Server

    Koo, Bon-Chul; Jeong, Il-Gyo; Seok, Ji Yeon; Kim, Hyun-Jeong

    2016-01-01

    Recent high-resolution infrared space missions have revealed supernova remnants (SNRs) of diverse morphology in infrared (IR) dust emission that is often very different from their X-ray appearance. The observed range of infrared-to-X-ray (IRX) flux ratios of SNRs are also wide. For a sample of 20 Galactic SNRs, we obtain their IR and X-ray properties and investigate the physical causes for such large differences. We find that the observed IRX flux ratios ($R_{IRX.obs}$) are related to the IRX morphology, with SNRs with the largest $R_{IRX,obs}$ showing anticorrelated IRX morphology. By analyzing the relation of $R_{IRX,obs}$ to X-ray and IR parameters, we show that the $R_{IRX,obs}$ of some SNRs agree with theoretical ratios of SNR shocks in which dust grains are heated and destroyed by collisions with plasma particles. For the majority of SNRs, however, $R_{IRX,obs}$ values are either significantly smaller or significantly larger than the theoretical ratios. The latter SNRs have relatively low dust temperatu...

  8. Infrared line ratios revealing starburst conditions in galaxies

    CERN Document Server

    Viegas, S M M; Contini, T; Viegas, Sueli M.; Contini, Marcella; Contini, Thierry

    1999-01-01

    The physical conditions in typical starburst galaxies are investigated through critical infrared (IR) line ratios, as previously suggested by Lutz et al. (1998, A&A, 333, L75). The calculations by a composite model which consistently accounts for the coupled effect of shock and photoionization by hot stars definitely fit the observed line ratios of single objects and explain the observed relation between [OIV]/([NeII]+0.44[NeIII]) and [NeIII]/[NeII]. The shock velocity and the gas density are the critical parameters. Most of the shocks are produced in low density-velocity (n_0 = 100 cm-3 and V_s = 50 - 100 km/s) clouds which represent the bulk of the ionized gas in starburst galaxies. However, though they are by many orders less numerous, high-velocity (= 400 - 600 km/s) shocks in dense (= 500 - 800 cm-3) clouds are necessary to reproduce the critical IR line ratios observed in the low-excitation Starburst Nucleus Galaxies (SBNGs: M82, M83, NGC 253, NGC 3256, NGC 3690, and NGC 4945). These model predictio...

  9. CROMOS A cryogenic near-infrared, multi-object spectrometer for the VLT

    CERN Document Server

    Genzel, R; Tomono, D; Thatte, N; Eisenhauer, F; Lehnert, M; Tecza, M; Bender, R

    2001-01-01

    We discuss a cryogenic, multi-object near-infrared spectrometer as a second generation instrument for the VLT. The spectrometer combines 20 to 40 independent integral eld units (IFUs), which can be positioned by a cryogenic robot over the entire unvignetted eld of the VLT (~7'). Each IFU consists of a contiguous cluster of 20 to 30 pixels (0.15 to 0.25" per pixel). The individual IFUs have cold fore-optics and couple into the spectrograph with integrated bers-microlenses. The spectrometer has lambda/d-lambda~4000 and simultaneously covers the J-, H-, and K-bands with three HAWAII 2 detectors. The system is designed for operation both in seeing limited and MCAO modes. Its speed is approximately 3500 times greater than that of ISAAC and 60 times greater than NIRMOS (in H-band). The proposed instrument aims at a wide range of science, ranging from studies of galaxies/clusters in the high-z Universe (dynamics and star formation in z>1 galaxies, evolution of ellipticals, properties of distant, obscured far-IR and ...

  10. Lunar Infrared Spectrometer to Characterize the Hydration of Regolith in the Vicinity of a Lander

    Science.gov (United States)

    Ivanov, Andrey; Fedorova, Anna; Korablev, Oleg; Mantsevich, Sergey; Stepanov, Alexander; Kalinnikov, Yury

    Lunar Infrared Spectrometer (LIS) is an experiment onboard Luna-Globe (Luna 25) and Luna-Resurce (Luna 27) Russian surface missions. It is a pencil-beam spectrometer to be pointed by a robotic arm of the landing module, and is intended for study of the lunar surface composition in the vicinity of the lander. The instrument’s field of view (FOV) of 1(°) is co-aligned with the FOV (45(°) ) of a stereo TV camera. The spectrometer will provide measurements of selected surface areas in the spectral range of 1.15-3.3 mum. The spectral selection is provided by acousto-optic tunable filter (AOTF), which scans the spectral range sequentially. Electrical command of the AOTF allows selecting the spectral sampling, and permits a random access if needed. The spectral resolution is better than 25 cm (-1) . The instrument’s mass is 1.3 kg. The primary goal of the experiment is to detect the regolith hydration at 3mum, identifying its form from the shape of the spectrum, and to follow its changes during the day/shadow pattern. Also, LIS will allow to study the mineralogical composition from mineral signatures within the spectral range, and will serve for selection of samples to be analyzed by other instruments.

  11. Exploration of the Saturn System by the Cassini Mission: Observations with the Cassini Infrared Spectrometer

    Science.gov (United States)

    Abbas, Mian M.

    2014-01-01

    The Cassini mission is a joint NASA-ESA international mission, launched on October 17, 1997 with 12 instruments on board, for exploration of the Saturn system. A composite Infrared Spectrometers is one of the major instruments. Successful insertion of the spacecraft in Saturn's orbit for an extended orbital tour occurred on July 1, 2004. The French Huygens-Probe on board, with six instruments was programmed for a soft landing on Titan's surface occurred in January 2005. The broad range scientific objectives of the mission are: Exploration of the Saturn system for investigations of the origin, formation, & evolution of the solar system, with an extensive range of measurements and the analysis of the data for scientific interpretations. The focus of research dealing with the Cassini mission at NASA/MSFC in collaboration with the NASA/Goddard Space Flight Center, JPL, as well as the research teams at Oxford/UK and Meudon Observatory/France, involves the Infrared observations of Saturn and its satellites, for measurements of the thermal structure and global distributions of the atmospheric constituents. A brief description of the Cassini spacecraft, the instruments, the objectives, in particular with the infrared observations of the Saturn system will be given. The analytical techniques for infrared radiative transfer and spectral inversion programs, with some selected results for gas constituent distributions will be presented.

  12. Fiber-coupled high resolution infrared array spectrometer for the Kuiper Airborne Observatory

    Science.gov (United States)

    Glenar, D. A.; Reuter, D.; Mumma, M. J.; Chin, G.; Wiedemann, G.; Jennings, D.

    1990-01-01

    A novel cryogenic grating spectrometer (FCAS) is being designed for observations of volatiles in cometary and planetary atmospheres, and in newly forming planetary systems. The instrument features two-dimensional detector arrays coupled to a high-dispersion echelle by infrared fibers, and will achieve a spectral resolving power of about 40,000. The primary observational platform for this instrument will be the Kuiper Airborne Observatory, but it will also be configured for use at ground-based observatories. Initially, the spectrometer will use a 58 x 62, 1- to 5-micron InSb array. Larger-format IR arrays and arrays of different composition, will later be incorporated as they become available. The instrument will be used in two modes. The first uses a large format IR array in the spectral image plane for the customary one-dimensional spectral-one-dimensional spatial coverage. In the second mode, a massive, coherent bundle of infrared transmitting ZrF4 fibers will be installed after the dispersive element, to reformat the two-dimensional array into an elongated one-dimensional array for wide spectral coverage, allowing multiple lines to be measured in a single integration with high sensitivity. The overall instrument design is discussed, and the system sensitivity is estimated.

  13. Spectra Transfer Between a Fourier Transform Near-Infrared Laboratory and a Miniaturized Handheld Near-Infrared Spectrometer.

    Science.gov (United States)

    Hoffmann, Uwe; Pfeifer, Frank; Hsuing, Chang; Siesler, Heinz W

    2016-05-01

    The aim of this contribution is to demonstrate the transfer of spectra that have been measured on two different laboratory Fourier transform near-infrared (FT-NIR) spectrometers to the format of a handheld instrument by measuring only a few samples with both spectrometer types. Thus, despite the extreme differences in spectral range and resolution, spectral data sets that have been collected and quantitative as well as qualitative calibrations that have been developed thereof, respectively, over a long period on a laboratory instrument can be conveniently transferred to the handheld system. Thus, the necessity to prepare completely new calibration samples and the effort required to develop calibration models when changing hardware platforms is minimized. The enabling procedure is based on piecewise direct standardization (PDS) and will be described for the data sets of a quantitative and a qualitative application case study. For this purpose the spectra measured on the FT-NIR laboratory spectrometers were used as "master" data and transferred to the "target" format of the handheld instrument. The quantitative test study refers to transmission spectra of three-component liquid solvent mixtures whereas the qualitative application example encompasses diffuse reflection spectra of six different current polymers. To prove the performance of the transfer procedure for quantitative applications, partial least squares (PLS-1) calibrations were developed for the individual components of the solvent mixtures with spectra transferred from the master to the target instrument and the cross-validation parameters were compared with the corresponding parameters obtained for spectra measured on the master and target instruments, respectively. To test the retention of the discrimination ability of the transferred polymer spectra sets principal component analyses (PCAs) were applied exemplarily for three of the six investigated polymers and their identification was demonstrated by

  14. Micro-spec: an Integrated Direct-detection Spectrometer for Far-infrared Space Telescopes

    Science.gov (United States)

    Cataldo, Giuseppe; Hsieh, Wen-Ting; Huang, Wei-Chung; Moseley, S. Harvey; Stevenson, Thomas R.; Wollack, Edward J.

    2014-01-01

    The far-infrared and submillimeter portions of the electromagnetic spectrum provide a unique view of the astrophysical processes present in the early universe. Our ability to fully explore this rich spectral region has been limited, however, by the size and cost of the cryogenic spectrometers required to carry out such measurements.Micro-Spec (µ-Spec) is a high-sensitivity, direct-detection spectrometer concept working in the 450-1000 (micrometers) wavelength range which will enable a wide range of flight missions that would otherwise be challenging due tothe large size of current instruments with the required spectral resolution and sensitivity. The spectrometer design utilizes two internal antenna arrays, one for transmitting and one for receiving, superconducting microstrip transmission lines for power division and phase delay, and an array of microwave kinetic inductance detectors (MKIDs) to achieve these goals. The instrument will be integrated on a approximately 10 sq cm silicon chip and can therefore become an important capability under the low background conditions accessible via space and high-altitude borne platforms. In this paper, an optical design methodology for micro-Spec is presented, with particular attention given to its two-dimensional diffractive region, where the light of different wavelengths is focused on the different detectors. The method is based on the maximization of the instrument resolving power and minimization of the RMS phase error on the instrument focal plane. This two-step optimization can generate geometrical configurations given specific requirements on spectrometer size, operating spectral range and performance.Two point designs with resolving power of 260 and 520 and an RMS phase error less than approximately 0.004 radians were developed for initial demonstration and will be the basis of future instruments with resolving power up to about 1200.

  15. Micro-Spec: an Integrated, Direct-Detection Spectrometer for Far-Infrared and Submillimeter Astronomy

    Science.gov (United States)

    Cataldo, Giuseppe

    2014-01-01

    The far-infrared and submillimeter portions of the electromagnetic spectrum provide a unique view of the astrophysical processes present in the early universe. Our ability to fully explore this rich spectral region has been limited, however, by the size and cost of the cryogenic spectrometers required to carry out such measurements. Micro-Spec (u-Spec) is a high-sensitivity, direct-detection spectrometer concept working in the 450-1000 micromillimeter wavelength range which will enable a wide range of flight missions that would otherwise be challenging due to the large size of current instruments with the required spectral resolution and sensitivity. The spectrometer design utilizes two internal antenna arrays, one for transmitting and one for receiving, superconducting microstrip transmission lines for power division and phase delay, and an array of microwave kinetic inductance detectors (MKIDs) to achieve these goals. The instrument will be integrated on a approximately 10 square cm silicon chip and can therefore become an important capability under the low background conditions accessible via space and high-altitude borne platforms. In this paper, an optical design methodology for Micro-Spec is presented, with particular attention given to its twodimensional diffractive region, where the light of different wavelengths is focused on the different detectors. The method is based on the maximization of the instrument resolving power and minimization of the RMS phase error on the instrument focal plane. This two-step optimization can generate geometrical configurations given specific requirements on spectrometer size, operating spectral range and performance. A point design with resolving power of 257, an RMS phase error less than 0.1 radians and four stigmatic points was developed for initial demonstration and will be the basis of future instruments with resolving power up to about 1200.

  16. Multi-channel up-conversion infrared spectrometer and method of detecting a spectral distribution of light

    DEFF Research Database (Denmark)

    2015-01-01

    A multi-channel infrared spectrometer for detecting an infrared spectrum of light received from an object. The spectrometer comprises a wavelength converter system comprising a nonlinear material and having an input side and an output side. The wavelength converter system comprises at least a first...... on the first side into light in a second output wavelength range output on the second side. The spectrometer further comprises a demultiplexer configured for demultiplexing light in the first up-conversion channel and light in the second up-conversion channel. The demultiplexer is located on the first side...... or the second side of the wavelength converter system. Finally, the spectrometer comprises a spatially resolved detector arranged in the image plane to detect light in the first output wavelength range and second output wavelength range output of the wavelength converter system....

  17. Development of Real-Time Image Stabilization for an Airborne Infrared Spectrometer

    Science.gov (United States)

    Fedeler, Samuel; Samra, Jenna; Guth, Giora

    2017-01-01

    The total solar eclipse of August 21, 2017 offers a unique opportunity for study of the infrared solar corona. The Airborne Infrared Spectrometer (AIR-Spec), currently under development, is an infrared telescope and spectrometer that will search for several magnetically sensitive coronal emission lines between 1.4 and 4 micrometers. This instrument will be the first to observe several of these lines, and the measurement campaign will determine whether any lines may be useful for future direct observations of the coronal magnetic field. AIR-Spec will be mounted on an NSF/NCAR Gulfstream V jet and will observe the eclipse from an altitude greater than 14.9 km, above the bulk of IR-absorbing atmospheric water vapor.To ensure that the images taken for analysis have adequate spatial resolution, the AIR-Spec line-of-sight must be stabilized to 1.9 arc-seconds RMS over a 1 second exposure time. Image stabilization is achieved by using a fiber-optic gyroscope to measure aircraft rotation and a fast-steering mirror to adjust the line-of-sight accordingly. The stabilization algorithm runs in a programmable automation controller, which interfaces with the gyroscope and mirror. Software was developed to implement the stabilization algorithm in the controller and to integrate the controller with a user interface, allowing for data display and logging, user guided attitude calibration, and manual control of the fast-steering mirror. The current system stabilizes images to 1.9 arc-seconds in 60 percent of 1 second camera exposures under laboratory conditions. This software will be operational during test flights in Fall 2016 and Spring 2017, and will be optimized for the eclipse flight in Summer 2017.

  18. Mid-Infrared Spectroscopy of Uranus from the Spitzer Infrared Spectrometer: 2. Determination of the Mean Composition of the Upper Troposphere and Stratosphere

    CERN Document Server

    Orton, Glenn S; Fletcher, Leigh N; Mainzer, Amy K; Hines, Dean; Hammel, Heidi B; Martin-Torres, Javier; Burgdorf, Martin; Merlet, Cecile; Line, Michael R

    2014-01-01

    Mid-infrared spectral observations Uranus acquired with the Infrared Spectrometer (IRS) on the Spitzer Space Telescope are used to determine the abundances of C2H2, C2H6, CH3C2H, C4H2, CO2, and tentatively CH3 on Uranus at the time of the 2007 equinox. For vertically uniform eddy diffusion coefficients in the range 2200-2600 cm2 s-1, photochemical models that reproduce the observed methane emission also predict C2H6 profiles that compare well with emission in the 11.6-12.5 micron wavelength region, where the nu9 band of C2H6 is prominent. Our nominal model with a uniform eddy diffusion coefficient Kzz = 2430 cm2 sec-1 and a CH4 tropopause mole fraction of 1.6x10-5 provides a good fit to other hydrocarbon emission features, such as those of C2H2 and C4H2, but the model profile for CH3C2H must be scaled by a factor of 0.43, suggesting that improvements are needed in the chemical reaction mechanism for C3Hx species. The nominal model is consistent with a CH3D/CH4 ratio of 3.0+-0.2x10-4. From the best-fit scaling...

  19. Development of long wavelength semiconductor diode lasers near 28 microns for use in infrared heterodyne spectrometers

    Science.gov (United States)

    Linden, K. J.

    1984-01-01

    The development of tunable diode lasers operating in the 28 micrometers spectral region for use in infrared heterodyne spectrometers is reported. A process capable of yielding lasers emitting 500 micron W of multimode power, 112 micron W in a true single mode and true single mode operation at laser currents of up to 35% above threshold was developed. Results were obtained from narrow mesastripe (20 micrometer wide) short cavity (120 micrometer length) laser configurations. Six stripe geometry lasers, with a variety of cavity widths and lengths were delivered. The techniques to fabricate such devices was obtained and the long term reliability of such lasers by reproducible electrical and optical output characteristics fabrication from lasers are demonstrated.

  20. Short wavelength spectrometer for the Infrared Space Observatory (ISO). A proposal to the European Space Agency

    Science.gov (United States)

    A spectrometer for the Infrared Space Observatory, designed to operate in the wavelength region from 3 to 50 microns with resolutions ranging from 3000 to 100,000 is proposed. It can study interstellar matter, star formation and evolution, extragalactic systems, and the solar system. The wide wavelength range includes numerous atomic, ionic and molecular transitions as well as diffuse features. They provide tools for studies of the physical and chemical processes of regions optically hidden by interstellar dust. The high resolving power allows probing of kinematic processes objects ranging from galactic nuclei to planetary atmospheres. Line studies of extragalactic objects, out to distances equal to the Virgo cluster, can be carried out. Direct observation of ground state molecular hydrogen in the interstellar medium can be attempted.

  1. Instrument performance for IIP Tropospheric Infrared Mapping Spectrometers (TIMS) for vertically resolved CO

    Science.gov (United States)

    Roche, A. E.; Kumer, J. B.; Rairden, R. L.; Jamieson, T. H.; Mergenthaler, J. L.

    2008-12-01

    The NASA Earth Science Technology Office (ESTO) Instrument Incubator Program (IIP) Tropospheric Infrared Mapping Spectrometers (TIMS) have been developed to demonstrate measurement capability, when deployed in space, for multi-layer retrieval of CO from spectral measurements acquired in the solar reflective band ~ 4281 to 4301 cm-1 and in the thermal band ~ 2110 to 2165 cm-1. The presentation will describe [a] the top level designs [b] measured instrument performance parameters including spectral and spatial resolution, spectral quality and noise performance, [c] comparisons of the performance (spectral, spatial, noise) with instrument modeling and [d] calibration procedures and results for spectral registration, spectral response, flat fielding, zero level determination and radiometric. Good comparison with demonstration instrument performance and modeling gives a high level of confidence for instrument performance in the space based case. Lessons learned will be described. These are very valuable for the space deployed application. The TIMS are well suited for either LEO or GEO application.

  2. Application of support vector machine and particle swarm optimization in micro near infrared spectrometer

    Science.gov (United States)

    Xiong, Yuhong; Liu, Yunxiang; Shu, Minglei

    2016-10-01

    In the process of actual measurement and analysis of micro near infrared spectrometer, genetic algorithm is used to select the wavelengths and then partial least square method is used for modeling and analyzing. Because genetic algorithm has the disadvantages of slow convergence and difficult parameter setting, and partial least square method in dealing with nonlinear data is far from being satisfactory, the practical application effect of partial least square method based on genetic algorithm is severely affected negatively. The paper introduces the fundamental principles of particle swarm optimization and support vector machine, and proposes a support vector machine method based on particle swarm optimization. The method can overcome the disadvantage of partial least squares method based on genetic algorithm to a certain extent. Finally, the method is tested by an example, and the results show that the method is effective.

  3. The GIS data model of the Visible and Infrared mapping spectrometer (VIR) onboard NASA/Dawn

    Science.gov (United States)

    Frigeri, Alessandro; De Sanctis, Maria Cristina; Ammannito, Eleonora; Capaccioni, Fabrizio; VIR Team

    2016-10-01

    The spectrometer onboard Dawn mission to Vesta and Ceres (Russell et al., Earth Moon Planet (2007) 101:65-91) is a hyperspectral spectrometer with imaging capability which returns data useful for the determination of the mineral composition of surface materials in their geologic context. The VIR Spectrometer—covering the range from the near UV (0.25 μm) to the near IR (5.0 μm) and having moderate to high spectral resolution and imaging capabilities—is the appropriate instrument for the determination of Vesta's and Ceres' global and local properties (De Sanctis et al., SSR 2011). VIR combines two data channels in one compact instrument. The visible channel covers 0.25-1.05 μm and the infrared channel covers 1-5.0 μm. VIR is inherited from the VIRTIS mapping spectrometer (Coradini et al. in Planet. Space Sci. 46:1291-1304, 1998; Reininger et al. in Proc. SPIE 2819:66-77, 1996) on board the ESA Rosetta mission.Since the beginning of the scientific campaign, VIR calibrated data have been converted into a Geographic Information System (GIS) compatible format. Here we present the GIS data model we developed for VIR, which presents some unique peculiarities due to the specific NASA/Dawn mission design. The model has been developed starting from an object oriented modeling. This object oriented design gives the flexibility which is necessary to face, time to time, the unexpected aspects of remote sensing over planetary surfaces unobserved before with this kind of instruments.

  4. Validation of MOPITT carbon monoxide using ground-based Fourier transform infrared spectrometer data from NDACC

    Science.gov (United States)

    Buchholz, Rebecca R.; Deeter, Merritt N.; Worden, Helen M.; Gille, John; Edwards, David P.; Hannigan, James W.; Jones, Nicholas B.; Paton-Walsh, Clare; Griffith, David W. T.; Smale, Dan; Robinson, John; Strong, Kimberly; Conway, Stephanie; Sussmann, Ralf; Hase, Frank; Blumenstock, Thomas; Mahieu, Emmanuel; Langerock, Bavo

    2017-06-01

    The Measurements of Pollution in the Troposphere (MOPITT) satellite instrument provides the longest continuous dataset of carbon monoxide (CO) from space. We perform the first validation of MOPITT version 6 retrievals using total column CO measurements from ground-based remote-sensing Fourier transform infrared spectrometers (FTSs). Validation uses data recorded at 14 stations, that span a wide range of latitudes (80° N to 78° S), in the Network for the Detection of Atmospheric Composition Change (NDACC). MOPITT measurements are spatially co-located with each station, and different vertical sensitivities between instruments are accounted for by using MOPITT averaging kernels (AKs). All three MOPITT retrieval types are analyzed: thermal infrared (TIR-only), joint thermal and near infrared (TIR-NIR), and near infrared (NIR-only). Generally, MOPITT measurements overestimate CO relative to FTS measurements, but the bias is typically less than 10 %. Mean bias is 2.4 % for TIR-only, 5.1 % for TIR-NIR, and 6.5 % for NIR-only. The TIR-NIR and NIR-only products consistently produce a larger bias and lower correlation than the TIR-only. Validation performance of MOPITT for TIR-only and TIR-NIR retrievals over land or water scenes is equivalent. The four MOPITT detector element pixels are validated separately to account for their different uncertainty characteristics. Pixel 1 produces the highest standard deviation and lowest correlation for all three MOPITT products. However, for TIR-only and TIR-NIR, the error-weighted average that includes all four pixels often provides the best correlation, indicating compensating pixel biases and well-captured error characteristics. We find that MOPITT bias does not depend on latitude but rather is influenced by the proximity to rapidly changing atmospheric CO. MOPITT bias drift has been bound geographically to within ±0.5 % yr-1 or lower at almost all locations.

  5. Integration, Testing and Performance of the Infrared Multi-Object Spectrometer

    Science.gov (United States)

    Ohl, Raymond G.; Connelly, Joseph A.; Boyle, Robert F.; Derro, Rebecca J.; Greenhouse, Matthew A.; Madison, Timothy J.; Mentzell, J. Eric; Sparr, Leroy M.; Hylan, Jason E.; Ray, Knute

    2003-01-01

    The Infrared Multi-Object Spectrometer (IRMOS) is a principle investigator-class instrument for the Kitt Peak National Observatory 2.1 m and Mayall 3.8 m telescopes. IRMOS is a near-IR (0.8 - 2.5 micron) spectrometer with low-to mid-resolving power (R = lambda/delta lambda = 300 - 3000). On the 3.8 m telescope, IRMOS produces simultaneous spectra of approximately 100 objects in its approximately 3 x 2 arcmin field of view using a commercial micro electro-mechanical systems (MEMS) digital micro-mirror device (DMD) from Texas Instruments. The multi-mirror array DMD operates as a real-time programmable slit mask. The all-reflective optical design consists of two imaging subsystems. The focal reducer images the focal plane of the telescope onto the DMD field stop, and the spectrograph images the DMD onto a large-format detector. The instrument operates at approximately 80 K, cooled by a single electro-mechanical cryocooler. The bench and all components are made from aluminum 6061-T651. There are three cryogenic mechanisms. We describe laboratory integration and test of IRMOS before shipment to Kitt Peak. We give an overview of the optical alignment technique and integration of optical, mechanical, electrical and cryogenic subsystems. We compare optical test results to model predictions of point spread function size and morphology, contrast, and stray light. We discuss some lessons learned and conclude with a prediction for performance on the telescope.

  6. Absolutely nondestructive discrimination of Huoshan Dendrobium nobile species with miniature near-infrared (NIR) spectrometer engine.

    Science.gov (United States)

    Hu, Tian; Yang, Hai-Long; Tang, Qing; Zhang, Hui; Nie, Lei; Li, Lian; Wang, Jin-Feng; Liu, Dong-Ming; Jiang, Wei; Wang, Fei; Zang, Heng-Chang

    2014-10-01

    As one very precious traditional Chinese medicine (TCM), Huoshan Dendrobium has not only high price, but also significant pharmaceutical efficacy. However, different species of Huoshan Dendrobium exhibit considerable difference in pharmaceutical efficacy, so rapid and absolutely non-destructive discrimination of Huoshan Dendrobium nobile according to different species is crucial to quality control and pharmaceutical effect. In this study, as one type of miniature near-infrared (NIR) spectrometer, MicroNIR 1700 was used for absolutely nondestructive determination of NIR spectra of 90 batches of Dendrobium from five species of differ- ent commodity grades. The samples were intact and not smashed. Soft independent modeling of class analogy (SIMCA) pattern recognition based on principal component analysis (PCA) was used to classify and recognize different species of Dendrobium samples. The results indicated that the SIMCA qualitative models established with pretreatment method of standard normal variate transformation (SNV) in the spectra range selected by Qs method had 100% recognition rates and 100% rejection rates. This study demonstrated that a rapid and absolutely non-destructive analytical technique based on MicroNIR 1700 spectrometer was developed for successful discrimination of five different species of Huoshan Dendrobium with acceptable accuracy.

  7. Micro-Spec: An Ultracompact, High-sensitivity Spectrometer for Far-Infrared and Submillimeter Astronomy

    Science.gov (United States)

    Cataldo, Giuseppe; Hsieh, Wen-Ting; Huang, Wei-Chung; Moseley, S. Harvey; Stevenson, Thomas R.; Wollack, Edward J.

    2014-01-01

    High-performance, integrated spectrometers operating in the far-infrared and submillimeter ranges promise to be powerful tools for the exploration of the epochs of reionization and initial galaxy formation. These devices, using high-efficiency superconducting transmission lines, can achieve the performance of a meter-scale grating spectrometer in an instrument implemented on a 4 inch silicon wafer. Such a device, when combined with a cryogenic telescope in space, provides an enabling capability for studies of the early universe. Here, the optical design process for Micro-Spec (micron-Spec) is presented, with particular attention given to its two-dimensional diffractive region, where the light of different wavelengths is focused on the different detectors. The method is based on the stigmatization and minimization of the light path function in this bounded region, which results in an optimized geometrical configuration. A point design with an efficiency of (is) approximately 90% has been developed for initial demonstration and can serve as the basis for future instruments. Design variations on this implementation are also discussed, which can lead to lower efficiencies due to diffractive losses in the multimode region.

  8. Portable Gas Analyzer Based on Fourier Transform Infrared Spectrometer for Patrolling and Examining Gas Exhaust

    Directory of Open Access Journals (Sweden)

    Yuntao Liang

    2015-01-01

    Full Text Available Aimed at monitoring emission of organic gases such as CH4, C2H6, C3H8, iso-C4H10, n-C4H10, C2H4, C3H6, C2H2, CO, and CO2, from coal mines, petroleum refineries, and other plants, a Fourier Transform Infrared (FT-IR spectrometer was used to develop a portable gas analyzer for patrolling and examining gas exhaust. Firstly, structure of the instrument was introduced. Then, a spectral analysis approach was presented. Finally, instrument was tested with standard gases and with actual gases emitted from a petroleum refinery. For the latter test, a gas chromatograph (GC was used as a reference instrument. The test results showed that the detection limit of every component of analyte was less than 10 × 10−6. The maximum test error of every analyte was less than 15 × 10−6 when its practical concentration was no more than 500 × 10−6. A final comparison showed that the result curves of analytes obtained with FT-IR spectrometer almost overlapped with those obtained with GC, and their resulting noise was less than 6.4% when the practical gas concentration was above 100 × 10−6. As a result, our instrument was suitable to be used as a portable instrument for monitoring exhaust gases.

  9. Scientific objectives and selection of targets for the SMART-1 Infrared Spectrometer (SIR)

    Science.gov (United States)

    Basilevsky, A. T.; Keller, H. U.; Nathues, A.; Mall, U.; Hiesinger, H.; Rosiek, M.

    2004-12-01

    The European SMART-1 mission to the Moon, primarily a testbed for innovative technologies, was launched in September 2003 and will reach the Moon in 2005. On board are several scientific instruments, including the point-spectrometer SMART-1 Infrared Spectrometer (SIR). Taking into account the capabilities of the SMART-1 mission and the SIR instrument in particular, as well as the open questions in lunar science, a selection of targets for SIR observations has been compiled. SIR can address at least five topics: (1) Surface/regolith processes; (2) Lunar volcanism; (3) Lunar crust structure; (4) Search for spectral signatures of ices at the lunar poles; and (5) Ground truth and study of geometric effects on the spectral shape. For each topic we will discuss specific observation modes, necessary to achieve our scientific goals. The majority of SIR targets will be observed in the nadir-tracking mode. More than 100 targets, which require off-nadir pointing and off-nadir tracking, are planned. It is expected that results of SIR observations will significantly increase our understanding of the Moon. Since the exact arrival date and the orbital parameters of the SMART-1 spacecraft are not known yet, a more detailed planning of the scientific observations will follow in the near future.

  10. Five-Channel Infrared Laser Absorption Spectrometer for Combustion Product Monitoring Aboard Manned Spacecraft

    Science.gov (United States)

    Briggs, Ryan M.; Frez, Clifford; Borgentun, Carl E.; Bagheri, Mahmood; Forouhar, Siamak; May, Randy D.

    2014-01-01

    Continuous combustion product monitoring aboard manned spacecraft can prevent chronic exposure to hazardous compounds and also provides early detection of combustion events. As future missions extend beyond low-Earth orbit, analysis of returned environmental samples becomes impractical and safety monitoring should be performed in situ. Here, we describe initial designs of a five-channel tunable laser absorption spectrometer to continuously monitor combustion products with the goal of minimal maintenance and calibration over long-duration missions. The instrument incorporates dedicated laser channels to simultaneously target strong mid-infrared absorption lines of CO, HCl, HCN, HF, and CO2. The availability of low-power-consumption semiconductor lasers operating in the 2 to 5 micron wavelength range affords the flexibility to select absorption lines for each gas with maximum interaction strength and minimal interference from other gases, which enables the design of a compact and mechanically robust spectrometer with low-level sensitivity. In this paper, we focus primarily on absorption line selection based on the availability of low-power single-mode semiconductor laser sources designed specifically for the target wavelength range.

  11. On-line near-infrared spectrometer to monitor urea removal in real time during hemodialysis.

    Science.gov (United States)

    Cho, David S; Olesberg, Jonathon T; Flanigan, Michael J; Arnold, Mark A

    2008-08-01

    The ex vivo removal of urea during hemodialysis treatments is monitored in real time with a noninvasive near-infrared spectrometer. The spectrometer uses a temperature-controlled acousto optical tunable filter (AOFT) in conjunction with a thermoelectrically cooled extended wavelength InGaAs detector to provide spectra with a 20 cm(-1) resolution over the combination region (4000-5000 cm(-1)) of the near-infrared spectrum. Spectra are signal averaged over 15 seconds to provide root mean square noise levels of 24 micro-absorbance units for 100% lines generated over the 4600-4500 cm(-1) spectral range. Combination spectra of the spent dialysate stream are collected in real-time as a portion of this stream passes through a sample holder constructed from a 1.1 mm inner diameter tube of Teflon. Real-time spectra are collected during 17 individual dialysis sessions over a period of 10 days. Reference samples were extracted periodically during each session to generate 87 unique samples with corresponding reference concentrations for urea, glucose, lactate, and creatinine. A series of calibration models are generated for urea by using the partial least squares (PLS) algorithm and each model is optimized in terms of number of factors and spectral range. The best calibration model gives a standard error of prediction (SEP) of 0.30 mM based on a random splitting of spectra generated from all 87 reference samples collected across the 17 dialysis sessions. PLS models were also developed by using spectra collected in early sessions to predict urea concentrations from spectra collected in subsequent sessions. SEP values for these prospective models range from 0.37 mM to 0.52 mM. Although higher than when spectra are pooled from all 17 sessions, these prospective SEP values are acceptable for monitoring the hemodialysis process. Selectivity for urea is demonstrated and the selectivity properties of the PLS calibration models are characterized with a pure component selectivity

  12. A Static Imaging Fourier Transform Spectrometer (SIFTS) for infrared remote sensing

    Science.gov (United States)

    Mortimer, Hugh; Hussain, Ali

    2017-04-01

    A Static Imaging Fourier Transform Spectrometer, SIFTS, has been developed for hyperspectral remote sensing in the infrared. The compact instrument has no moving components and so is insensitive to vibration. It has been optimised for operation from the Near (3 microns) to Mid Infrared (15 microns) through the use of an uncooled, wideband microbolometer detector array. The resolution across this spectral range has been shown to be 8cm-1. This instrument is inherently imaging, whereby spectral information is recorded along the of the detector array whilst imaging information is recorded down the column of the detector array. The Connes advantage, inherent to the Michelson spectrometer Fourier Transform Spectrometer (FTS), whereby the spectral wavelength accuracy is referenced to a stabilised laser has also been demonstrated in the SIFTS instrument. This has been implemented through the use of an expanded internal laser diode with Distributed Bragg Reflector (DFB) which acts as the calibration source used to maintain the wavelength stability of the SIFTS instrument. As there are no moving components, the instrument is compact, light and insensitive to mechanical vibration, additionally the speed of measurement is determined by the frame rate of the detector array. Thus, this instrument has a temporal advantage over common Michelson FTIR instruments. The novel optical design has reduced the optics to only 3 optical components, and the detector array, to generate and measure the interferogram. The experimental performance of the SIFTS instrument is demonstrated in measurements against theoretical and The technique is based on a static optical configuration whereby light is split into two paths and made to recombine along a focal plane producing an interference pattern. The spectral information is returned using a detector array to digitally capture the interferogram which can then be processed into a spectrum by applying a Fourier transform. As there are no moving

  13. A collinear tandem time-of-flight mass spectrometer for infrared photodissociation spectroscopy of mass-selected ions

    Institute of Scientific and Technical Information of China (English)

    WANG GuanJun; CHI ChaoXian; XING XiaoPeng; DING ChuanFan; ZHOU MingFei

    2014-01-01

    An apparatus based on collinear tandem time-of-flight mass spectrometer has been designed for the measurement of infrared photodissociation spectroscopy of mass-selected ions in the gas phase.The ions from a pulsed laser vaporization supersonic ion source are skimmed and mass separated by a Wiley-McLaren time-of-flight mass spectrometer.The ion of interest is mass selected,decelerated and dissociated by a tunable IR laser.The fragment and parent ions are reaccelerated and mass analyzed by the second time-of-flight mass spectrometer.A simple new assembly integrated with mass gate,deceleration and reacceleration ion optics was designed,which allows us to measure the infrared spectra of mass selected ions with high sensitivity and easy timing synchronization.

  14. A Novel Miniaturised Infrared Imaging Spectrometer for the Measurement of Atmospheric Trace Gases

    Science.gov (United States)

    Mortimer, A. H.

    2012-04-01

    A novel, ultra-compact Static Imaging Fourier Transform Spectrometer, SIFTS, with no moving parts has been developed for the remote and in-situ detection of atmospheric gases. This technique has previously been demonstrated in the visible spectral region (400 to 1100nm) using a CCD detector. This paper the author presents the results of the infrared version of the SIFTS instrument, which uses an uncooled microbolometer detector array to measure infrared spectra (7 to 14μm) with a resolution of up 4 cm-1 and temporal resolution of 30Hz. The technique is based on a static optical configuration whereby light is split into two paths and made to recombine along a focal plane producing an interference pattern. The spectral information is returned using a detector array to digitally capture the interferogram which can then be processed into a spectrum by the application of a Fourier transform. The novel optical design has reduced the optics required to only 3 optical components and the detector array, to generate and measure the interferogram. The experimental performance of the SIFTS instrument has verified the theoretical models, which has shown that the spectral resolution is for the infrared instrument is 4cm-1. The Connes advantage, inherent to the Michelson spectrometer Fourier Transform Spectrometer (FTS), whereby the spectral wavelength accuracy is referenced to a stabilised laser has also been demonstrated in the SIFTS instrument. This has been implemented through the use of an expanded internal laser diode with Distributed Bragg Reflector (DFB) which acts as the calibration source used to maintain the wavelength stability of the SIFTS instrument. As there are no moving components, the instrument is compact, light and insensitive to mechanical vibration, additionally the speed of measurement is determined by the frame rate of the detector array. Thus, this instrument has a temporal advantage over common Michelson FTIR instruments. For example, this technique has

  15. Alignment and Polarization Sensitivity Study for the Cassini-Composite InfraRed Spectrometer (CIRS) Far InfraRed (FIR) Interferometer

    Science.gov (United States)

    Crooke, Julie A.; Hagopian, John G.

    1998-01-01

    The Composite InfraRed Spectrometer (CIRS) instrument flying on the Cassini spacecraft to Saturn is a cryogenic spectrometer with far-infrared (FIR) and mid-infrared (MIR) channels. The CIRS FIR channel is a polarizing interferometer that contains three polarizing grid components. These components are an input polarizer, a polarizing beamsplitter, and an output polarizer/analyzer. They consist of a 1.5 micron thick mylar substrate with 2 gm wide copper wires, with 2 gm spacing (4 micron pitch) photolithographically deposited on the substrate. This paper details the polarization sensitivity studies performed on the output polarizer/analyzer, and the alignment sensitivity studies performed on the input polarizer and beamsplitter components in the FIR interferometer.

  16. Similarity ratio analysis for early stage fault detection with optical emission spectrometer in plasma etching process.

    Science.gov (United States)

    Yang, Jie; McArdle, Conor; Daniels, Stephen

    2014-01-01

    A Similarity Ratio Analysis (SRA) method is proposed for early-stage Fault Detection (FD) in plasma etching processes using real-time Optical Emission Spectrometer (OES) data as input. The SRA method can help to realise a highly precise control system by detecting abnormal etch-rate faults in real-time during an etching process. The method processes spectrum scans at successive time points and uses a windowing mechanism over the time series to alleviate problems with timing uncertainties due to process shift from one process run to another. A SRA library is first built to capture features of a healthy etching process. By comparing with the SRA library, a Similarity Ratio (SR) statistic is then calculated for each spectrum scan as the monitored process progresses. A fault detection mechanism, named 3-Warning-1-Alarm (3W1A), takes the SR values as inputs and triggers a system alarm when certain conditions are satisfied. This design reduces the chance of false alarm, and provides a reliable fault reporting service. The SRA method is demonstrated on a real semiconductor manufacturing dataset. The effectiveness of SRA-based fault detection is evaluated using a time-series SR test and also using a post-process SR test. The time-series SR provides an early-stage fault detection service, so less energy and materials will be wasted by faulty processing. The post-process SR provides a fault detection service with higher reliability than the time-series SR, but with fault testing conducted only after each process run completes.

  17. Similarity ratio analysis for early stage fault detection with optical emission spectrometer in plasma etching process.

    Directory of Open Access Journals (Sweden)

    Jie Yang

    Full Text Available A Similarity Ratio Analysis (SRA method is proposed for early-stage Fault Detection (FD in plasma etching processes using real-time Optical Emission Spectrometer (OES data as input. The SRA method can help to realise a highly precise control system by detecting abnormal etch-rate faults in real-time during an etching process. The method processes spectrum scans at successive time points and uses a windowing mechanism over the time series to alleviate problems with timing uncertainties due to process shift from one process run to another. A SRA library is first built to capture features of a healthy etching process. By comparing with the SRA library, a Similarity Ratio (SR statistic is then calculated for each spectrum scan as the monitored process progresses. A fault detection mechanism, named 3-Warning-1-Alarm (3W1A, takes the SR values as inputs and triggers a system alarm when certain conditions are satisfied. This design reduces the chance of false alarm, and provides a reliable fault reporting service. The SRA method is demonstrated on a real semiconductor manufacturing dataset. The effectiveness of SRA-based fault detection is evaluated using a time-series SR test and also using a post-process SR test. The time-series SR provides an early-stage fault detection service, so less energy and materials will be wasted by faulty processing. The post-process SR provides a fault detection service with higher reliability than the time-series SR, but with fault testing conducted only after each process run completes.

  18. Multidimensional spectrometer

    Science.gov (United States)

    Zanni, Martin Thomas; Damrauer, Niels H.

    2010-07-20

    A multidimensional spectrometer for the infrared, visible, and ultraviolet regions of the electromagnetic spectrum, and a method for making multidimensional spectroscopic measurements in the infrared, visible, and ultraviolet regions of the electromagnetic spectrum. The multidimensional spectrometer facilitates measurements of inter- and intra-molecular interactions.

  19. ISIS Cartographic Tools for the Dawn Framing Camera and Visual and Infrared Spectrometer

    Science.gov (United States)

    Anderson, J.; Becker, K. J.; Titus, T. N.; De sanctis, M.; Nathues, A.; Tosi, F.; Schroeder, S.; Le Corre, L.; Kelley, M. S.; Raymond, C. A.; Russell, C. T.

    2011-12-01

    Launched in September 2007, the Dawn spacecraft houses two imaging instruments: the framing camera (FC) and the Visual and Infrared Spectrometer (VIR) [1]. The spacecraft began orbiting asteroid 4 Vesta in July 2011 and over the course of one year will systematically map the body with both instruments. Camera model software and Dawn FC and VIR readers have been developed in the USGS Integrated Software for Imager and Spectrometers (ISIS) [2]. The readers, "dawnfc2isis" and "dawnvir2isis", convert both Planetary Data System (PDS) raw Experiment Data Records (EDRs) and calibrated Reduced Data Records (RDRs) into the native ISIS3 cube format. The ISIS camera models allow for orthorectification of the Vesta FC and VIR cubes to a variety of cartographic map projections using the long-standing "cam2map" application. Other standard tools such as "qview" for visualization and photometric processing applications (e.g.,"photomet" and "phocube") are available for use because of the integration of the new readers and camera models into ISIS [3]. These tools for Dawn cartographic and scientific analysis of Dawn data will be available for download in the October 2011 release of ISIS. The software release is timely as the Dawn image EDR data will be publicly released to the science community by the PDS within 90 days after each acquisition phase. Therefore, raw Vesta approach images will be available in November 2011. Raw images for other acquisition phases including survey, high altitude (HAMO) and low altitude (LAMO) mapping orbits will be delivered throughout 2012 [4]. Currently, there are no plans to include radiometric processing software for FC or VIR into ISIS. However, radiometrically calibrated PDS images (RDRs) will be publicly released six months after Vesta departure. [1] Russell, C.T., et al. (2007) Exploring the asteroid belt with ion propulsion: Dawn mission history, status and plans, Advances in Space Research, Volume 40, Issue 2, pages 193-201. [2] Anderson, J

  20. Infrared hyperspectral tunable filter imaging spectrometer for remote leak detection, chemical speciation, and stack/vent analysis applications

    Science.gov (United States)

    Hinnrichs, Michele

    2002-02-01

    With support from the Department of Energy, the State of California and the Gas Technology Institute, Pacific Advanced Technology is developing a small field portable infrared imaging spectrometer (Sherlock) based on the advances in hyperspectral tunable filter technology, that will be applied to the detection of fugitive gas leaks. This imaging spectrometer uses the Image Multi-spectral Sensing (IMSS) diffractive optic tunable filter invented by Pacific Advanced Technology . The Sherlock has an embedded digital signal processor for real time detection of the gas leak while surrounded by severe background noise. The infrared sensor engine is a 256 x 320 midwave cooled focal plane array which spans the spectral range from 3 to 5 microns, ideal for most hydrocarbon leaks. The technology is by no means limited to this spectral region, and can just as easily work in the longwave infrared from 8 to 12 microns for chemical detection applications. This paper will present the design of the Sherlock camera as well as processed data collected at a gas processing plant and an instrumented kiln at LSU using the prototype camera. The processed data shows that the IMSS imaging spectrometer, using an all passive approach, has the sensitivity to detect methane gas leaks at short range with a flow rate as low as 0.01 scfm2. In addition, the IMSS imaging spectrometer can measure hot gas plumes at longer ranges. As will be shown in this paper the IMSS can detect and image warm species gas additives of methane and propane in the Kiln exhaust stack. The methane injected gas with a concentration of 72 ppm and the propane with a concentration of 49 ppm (as seen by the IMSS sensor) at a range of 60 meters. The atmospheric path was a stressing environment, being hot and humid, for any imaging infrared spectrometer.

  1. Characterizing a Quantum Cascade Tunable Infrared Laser Differential Absorption Spectrometer (QC-TILDAS for measurements of atmospheric ammonia

    Directory of Open Access Journals (Sweden)

    R. A. Ellis

    2009-12-01

    Full Text Available A compact, fast-response Quantum Cascade Tunable Infrared Laser Differential Absorption Spectrometer (QC-TILDAS for measurements of ammonia has been evaluated under both laboratory and field conditions. Absorption of radiation from a pulsed, thermoelectrically cooled QC laser occurs at reduced pressure in a 0.5 L multiple pass absorption cell with an effective path length of 76 m. Detection is achieved using a thermoelectrically cooled Mercury Cadmium Telluride (HgCdTe infrared detector. A novel sampling inlet was used, consisting of a short, heated, quartz tube with a hydrophobic coating to minimize the adsorption of ammonia to surfaces. The inlet contains a critical orifice that reduces the pressure, a virtual impactor for separation of particles, and additional ports for delivering ammonia-free background air and calibration gas standards. This instrument has been found to have a detection limit of 0.23 ppb at 1 Hz. The sampling technique has been compared to the results of a conventional lead salt Tunable Diode Laser Absorption Spectrometer (TDLAS during a laboratory intercomparison. The effect of humidity and heat on the surface interaction of ammonia with sample tubing was investigated at mixing ratios ranging from 30–1000 ppb. Humidity was seen to worsen the ammonia time response and considerable improvement was observed when using a heated sampling line. A field intercomparison of the QC-TILDAS with a modified Thermo 42CTL chemiluminescence based analyzer was also performed at Environment Canada's Centre for Atmospheric Research Experiments (CARE in the rural town of Egbert, ON between May–July 2008. Background tests and calibrations using two different permeation tube sources and an ammonia gas cylinder were regularly carried out throughout the study. Results indicate a very good correlation with 1 min time resolution (R2=0.93 between the two instruments at the beginning of the study, when regular background

  2. Characterizing a Quantum Cascade Tunable Infrared Laser Differential Absorption Spectrometer (QC-TILDAS for measurements of atmospheric ammonia

    Directory of Open Access Journals (Sweden)

    R. A. Ellis

    2010-03-01

    Full Text Available A compact, fast-response Quantum Cascade Tunable Infrared Laser Differential Absorption Spectrometer (QC-TILDAS for measurements of ammonia (NH3 has been evaluated under both laboratory and field conditions. Absorption of radiation from a pulsed, thermoelectrically cooled QC laser occurs at reduced pressure in a 0.5 L multiple pass absorption cell with an effective path length of 76 m. Detection is achieved using a thermoelectrically-cooled Mercury Cadmium Telluride (HgCdTe infrared detector. A novel sampling inlet was used, consisting of a short, heated, quartz tube with a hydrophobic coating to minimize the adsorption of NH3 to surfaces. The inlet contains a critical orifice that reduces the pressure, a virtual impactor for separation of particles, and additional ports for delivering NH3-free background air and calibration gas standards. The level of noise in this instrument has been found to be 0.23 ppb at 1 Hz. The sampling technique has been compared to the results of a conventional lead salt Tunable Diode Laser Absorption Spectrometer (TDLAS during a laboratory intercomparison. The effect of humidity and heat on the surface interaction of NH3 with sample tubing was investigated at mixing ratios ranging from 30–1000 ppb. Humidity was seen to worsen the NH3 time response and considerable improvement was observed when using a heated sampling line. A field intercomparison of the QC-TILDAS with a modified Thermo 42CTL chemiluminescence-based analyzer was also performed at Environment Canada's Centre for Atmospheric Research Experiments (CARE in the rural town of Egbert, ON between May–July 2008. Background tests and calibrations using two different permeation tube sources and an NH3 gas cylinder were regularly carried out throughout the study. Results indicate a very good correlation at 1 min time resolution (R2 = 0.93 between the two instruments at the

  3. TIRCIS: Hyperspectral Thermal Infrared Imaging Using a Small-Satellite Compliant Fourier-Transform Imaging Spectrometer, for Natural Hazard Applications

    Science.gov (United States)

    Wright, R.; Lucey, P. G.; Crites, S.; Garbeil, H.; Wood, M.

    2015-12-01

    Many natural hazards, including wildfires, volcanic eruptions, and, from the perspective of climate-related hazards, urban heat islands, could be better quantified via the routine availability of hyperspectral thermal infrared remote sensing data from orbit. However, no sensors are currently in operation that provide such data at high-to-moderate spatial resolution (e.g. Landsat-class resolution). In this presentation we will describe a prototype instrument, developed using funding provided by NASA's Instrument Incubator Program, that can make these important measurements. Significantly, the instrument has been designed such that its size, mass, power, and cost are consistent with its integration into small satellite platforms, or deployment as part of small satellite constellations. The instrument, TIRCIS (Thermal Infra-Red Compact Imaging Spectrometer), uses a Fabry-Perot interferometer, an uncooled microbolometer array, and push-broom scanning to acquire hyperspectral image data cubes. Radiometric calibration is provided by blackbody targets while spectral calibration is achieved using monochromatic light sources. Neither the focal plane nor the optics need to be cooled, and the instrument has a mass of <10 kg and dimensions of 53 cm × 25 cm × 22 cm. Although the prototype has four moving parts, this can easily be reduced to one. The current optical design yields a 120 m ground sample size given an orbit of 500 km. Over the wavelength interval of 7.5 to 14 microns up to 90 spectral samples are possible, by varying the physical design of the interferometer. Our performance model indicates signal-to-noise ratios of the order of about 200 to 300:1. In this presentation we will provide an overview of the instrument design, fabrication, results from our initial laboratory characterization, and some of the application areas in which small-satellite-ready instruments such as TIRCIS could make a valuable contribution to the study of natural hazards.

  4. Double beam near-infrared spectrometer for compensation of background water absorption and instrumental drift in intensity

    Institute of Scientific and Technical Information of China (English)

    CHANG Min; PENG Dan; XU Ke-xin

    2007-01-01

    A double beam near-infrared spectrometer is developed to compensate the water absorption and instrumental drift in intensity. The spectrometer maybe used for both single and double beam measurements, and the two operation modes are compared. The results show that the double beam technique eliminates instrumental drift in the single beam measurement and therefore the stability of the system increases by more than 20%. The compensation of the double beam system on water absorption is verified by the measurement of fat content in milk. The results show that the spectrum data based on double beam mode get better calibration model and lower prediction error than traditional single beam mode.

  5. Infrared ion spectroscopy in a modified quadrupole ion trap mass spectrometer at the FELIX free electron laser laboratory

    Science.gov (United States)

    Martens, Jonathan; Berden, Giel; Gebhardt, Christoph R.; Oomens, Jos

    2016-10-01

    We report on modifications made to a Paul-type quadrupole ion trap mass spectrometer and discuss its application in infrared ion spectroscopy experiments. Main modifications involve optical access to the trapped ions and hardware and software coupling to a variety of infrared laser sources at the FELIX infrared free electron laser laboratory. In comparison to previously described infrared ion spectroscopy experiments at the FELIX laboratory, we find significant improvements in efficiency and sensitivity. Effects of the trapping conditions of the ions on the IR multiple photon dissociation spectra are explored. Enhanced photo-dissociation is found at lower pressures in the ion trap. Spectra obtained under reduced pressure conditions are found to more closely mimic those obtained in the high-vacuum conditions of an Fourier transform ion cyclotron resonance mass spectrometer. A gas-mixing system is described enabling the controlled addition of a secondary gas into helium buffer gas flowing into the trap and allows for ion/molecule reactions in the trap. The electron transfer dissociation (ETD) option of the mass spectrometer allows for IR structure characterization of ETD-generated peptide dissociation products.

  6. Prospects for measuring the fuel ion ratio in burning ITER plasmas using a DT neutron emission spectrometer

    Science.gov (United States)

    Hellesen, C.; Skiba, M.; Dzysiuk, N.; Weiszflog, M.; Hjalmarsson, A.; Ericsson, G.; Conroy, S.; Andersson-Sundén, E.; Eriksson, J.; Binda, F.

    2014-11-01

    The fuel ion ratio nt/nd is an essential parameter for plasma control in fusion reactor relevant applications, since maximum fusion power is attained when equal amounts of tritium (T) and deuterium (D) are present in the plasma, i.e., nt/nd = 1.0. For neutral beam heated plasmas, this parameter can be measured using a single neutron spectrometer, as has been shown for tritium concentrations up to 90%, using data obtained with the MPR (Magnetic Proton Recoil) spectrometer during a DT experimental campaign at the Joint European Torus in 1997. In this paper, we evaluate the demands that a DT spectrometer has to fulfill to be able to determine nt/nd with a relative error below 20%, as is required for such measurements at ITER. The assessment shows that a back-scattering time-of-flight design is a promising concept for spectroscopy of 14 MeV DT emission neutrons.

  7. Chromatic aberration short-wave infrared spectroscopy: nanoparticle spectra without a spectrometer.

    Science.gov (United States)

    Streit, Jason K; Bachilo, Sergei M; Weisman, R Bruce

    2013-02-05

    A new method is described for measuring the short-wave infrared (SWIR) emission wavelengths of numerous individual nanoparticles without using a dedicated spectrometer. Microscope objectives designed for use at visible wavelengths often show severe axial chromatic aberration in the SWIR. This makes coplanar objects emitting at different SWIR wavelengths appear to focus at different depths. After this aberration has been calibrated for a particular objective lens, the depth at which an emissive nanoparticle appears brightest and best focused can be used to deduce its peak emission wavelength. The method is demonstrated using a dilute, structurally polydisperse sample of single-walled carbon nanotubes deposited onto a microscope slide. Discrete emission centers in this sample have different peak wavelengths corresponding to specific nanotube structural species. A set of images was recorded at stepped focus settings and analyzed to find the sharpest focus depth of each nanotube. The chromatic aberration calibration curve converted these depths into peak emission wavelengths with a spectral resolution better than 3 nm, allowing identification of each nanotube's structure. Chromatic aberration spectroscopy is a practical tool for using existing microscopic equipment to extract significant spectral information on coplanar nanoparticle samples that emit or scatter light.

  8. Analysis of Index Gases of Coal Spontaneous Combustion Using Fourier Transform Infrared Spectrometer

    Directory of Open Access Journals (Sweden)

    Xiaojun Tang

    2014-01-01

    Full Text Available Analysis of the index gases of coal for the prevention of spontaneous combustion is of great importance for the enhancement of coal mine safety. In this work, Fourier Transform Infrared Spectrometer (FTIRS is presented to be used to analyze the index gases of coal in real time to monitor spontaneous combustion conditions. Both the instrument parameters and the analysis method are introduced at first by combining characteristics of the absorption spectra of the target analyte with the analysis requirements. Next, more than ten sets of the gas mixture containing ten components (CH4, C2H6, C3H8, iso-C4H10, n-C4H10, C2H4, C3H6, C2H2, CO, and CO2 are included and analyzed with a Spectrum Two FTIRS made by Perkin Elmer. The testing results show that the detection limit of most analytes is less than 2×10-6. All the detection limits meet the monitoring requirements of coal spontaneous combustion in China, which means that FTIRS may be an ideal instrument and the analysis method used in this paper is sufficient for spontaneous combustion gas monitoring on-line and even in situ, since FTIRS has many advantages such as fast analysis, being maintenance-free, and good safety.

  9. A lightweight near-infrared spectrometer for the detection of trace atmospheric species.

    Science.gov (United States)

    Gardiner, T; Mead, M I; Garcelon, S; Robinson, R; Swann, N; Hansford, G M; Woods, P T; Jones, R L

    2010-08-01

    This paper describes the development and deployment of a lightweight in situ near-infrared tunable diode laser absorption spectrometer (TDLAS) for balloon-borne measurements of trace species such as methane in the upper troposphere and stratosphere. The key feature of the instrument design is its ability to provide high sensitivity measurements with better than 1 part in 10(6) Hz(-1/2) optical sensitivity in a lightweight package weighing as little as 6 kg, and maintaining this level of performance over the wide range of conditions experienced during field measurements. The absolute accuracy for methane measurements is approximately 10% limited by uncertainties in determining the gas temperature in the measurement volume. The high sensitivity and high temporal resolution (2.3 s measurement period) enables details of the fine-scale structure in the atmosphere to be measured. The TDLAS instrument has been used on a number of major international measurement campaigns. Intercomparison with other instruments during these campaigns have confirmed the comparability of the results from this instrument with measurements made by a range of other techniques, and demonstrated the instruments suitability for studies of atmospheric dynamics, transport, and mixing processes.

  10. A prototype stationary Fourier transform spectrometer for near-infrared absorption spectroscopy.

    Science.gov (United States)

    Li, Jinyang; Lu, Dan-feng; Qi, Zhi-mei

    2015-09-01

    A prototype stationary Fourier transform spectrometer (FTS) was constructed with a fiber-coupled lithium niobate (LiNbO3) waveguide Mach-Zehnder interferometer (MZI) for the purpose of rapid on-site spectroscopy of biological and chemical measurands. The MZI contains push-pull electrodes for electro-optic modulation, and its interferogram as a plot of intensity against voltage was obtained by scanning the modulating voltage from -60 to +60 V in 50 ms. The power spectrum of input signal was retrieved by Fourier transform processing of the interferogram combined with the wavelength dispersion of half-wave voltage determined for the MZI used. The prototype FTS operates in the single-mode wavelength range from 1200 to 1700 nm and allows for reproducible spectroscopy. A linear concentration dependence of the absorbance at λmax = 1451 nm for water in ethanolic solution was obtained using the prototype FTS. The near-infrared spectroscopy of solid samples was also implemented, and the different spectra obtained with different materials evidenced the chemical recognition capability of the prototype FTS. To make this prototype FTS practically applicable, work on improving its spectral resolution by increasing the maximum optical path length difference is in progress.

  11. Spectral analysis of Ahuna Mons from Dawn mission's visible-infrared spectrometer

    Science.gov (United States)

    Zambon, F.; Raponi, A.; Tosi, F.; De Sanctis, M. C.; McFadden, L. A.; Carrozzo, F. G.; Longobardo, A.; Ciarniello, M.; Krohn, K.; Stephan, K.; Palomba, E.; Pieters, C. M.; Ammannito, E.; Russell, C. T.; Raymond, C. A.

    2017-01-01

    Ahuna Mons is the highest mountain on Ceres. A unique complex in terms of size, shape, and morphology, Ahuna is bordered by flanks of the talus around its summit. Recent work by Ruesch et al. based on Dawn's Framing Camera images shed light on the possible origin of Ahuna Mons. According to Ruesch et al. (2016), Ahuna Mons is formed by a volcanic process involving the ascent of cryomagma and extrusion onto the surface followed by dome development and subsequent spreading. Here we analyzed in detail the composition of Ahuna Mons, using data acquired by the visible and infrared spectrometer aboard Dawn. The spectral analysis reveals a relatively high abundance of carbonates and a nonhomogeneous variation in carbonate composition and abundance along Ahuna's flanks, associated with a lower amount of the Ceres's ubiquitous NH4-phyllosilicates over a large portion of the flanks. The grain size is coarser on the flanks than in the surrounding regions, suggesting the presence of fresher material, also compatible with a larger abundance of carbonates. Thermal variations are seen in Ahuna, supporting the evidence of different compactness of the surface regolith in specific locations. Results of the spectral analysis are consistent with a possible cryovolcanic origin which exposed fresher material that slid down on the flanks.

  12. [Rapid discriminating hogwash oil and edible vegetable oil using near infrared optical fiber spectrometer technique].

    Science.gov (United States)

    Zhang, Bing-Fang; Yuan, Li-Bo; Kong, Qing-Ming; Shen, Wei-Zheng; Zhang, Bing-Xiu; Liu, Cheng-Hai

    2014-10-01

    In the present study, a new method using near infrared spectroscopy combined with optical fiber sensing technology was applied to the analysis of hogwash oil in blended oil. The 50 samples were a blend of frying oil and "nine three" soybean oil according to a certain volume ratio. The near infrared transmission spectroscopies were collected and the quantitative analysis model of frying oil was established by partial least squares (PLS) and BP artificial neural network The coefficients of determina- tion of calibration sets were 0.908 and 0.934 respectively. The coefficients of determination of validation sets were 0.961 and 0.952, the root mean square error of calibrations (RMSEC) was 0.184 and 0.136, and the root mean square error of predictions (RMSEP) was all 0.111 6. They conform to the model application requirement. At the same time, frying oil and qualified edible oil were identified with the principal component analysis (PCA), and the accurate rate was 100%. The experiment proved that near infrared spectral technology not only can quickly and accurately identify hogwash oil, but also can quantitatively detect hog- wash oil. This method has a wide application prospect in the detection of oil.

  13. Infrared limb sounding of Titan with the Cassini Composite InfraRed Spectrometer: effects of the mid-IR detector spatial responses.

    Science.gov (United States)

    Nixon, Conor A; Teanby, Nicholas A; Calcutt, Simon B; Aslam, Shahid; Jennings, Donald E; Kunde, Virgil G; Flasar, F Michael; Irwin, Patrick G; Taylor, Fredric W; Glenar, David A; Smith, Michael D

    2009-04-01

    The composite infrared spectrometer (CIRS) instrument on board the Cassini Saturn orbiter employs two 1x10 HgCdTe detector arrays for mid-infrared remote sensing of Titan's and Saturn's atmospheres. In this paper we show that the real detector spatial response functions, as measured in ground testing before launch, differ significantly from idealized "boxcar" responses. We further show that neglecting this true spatial response function when modeling CIRS spectra can have a significant effect on interpretation of the data, especially in limb-sounding mode, which is frequently used for Titan science. This result has implications not just for CIRS data analysis but for other similar instrumental applications.

  14. TOTAL COLUMN METHANE RETRIEVALS USING THE TROPOSPHERIC INFRARED MAPPING SPECTROMETER OVER SUNGLINT

    Directory of Open Access Journals (Sweden)

    N. Larsen

    2012-07-01

    Full Text Available Because it is a greenhouse gas, the detection of methane concentrations is a global issue. Additionally, the presence of methane is indicative of potential valuable petroleum and natural gas deposits. Therefore methane seep detection is useful for petroleum exploration around the world. The detection of methane, and other absorbing gases, over water is an issue for passive systems because one is seeking to detect an absorbing gas over an absorbing surface. The solution to this dilemma is to use the sun/sensor geometry for sun glint off of water to measure the absorbing gas over a reflecting surface, and therefore significantly increase the signal to noise of the measurement being taken. In September of 2010 Lockheed Martin performed a proof of concept by demonstrating from an airship over San Francisco Bay the capability of the Tropospheric Infrared Mapping Spectrometer's (TIMS hyper spectral sensor to passively measure methane, CO, and water vapor over sunglint water. The Lockheed Martin prototype TIMS sensor system is a hyper spectral grating spectrometer instrument that operates in the 2.3 micron spectral region at 0.25 cm-1 resolution. The Lockheed Martin retrieval algorithm developed applies the kCARTA (kCompressed Atmospheric Radiative Transfer Algorithm with Jacobians, with the HITRAN 2008 lineshape parameters, to retrieve the total column amount of atmospheric species along with the calibrated TIMS sensors radiometric input. A cell with known amount of methane was placed into the input to the TIMS to simulate atmospheric enhancements near the water surface. The amount in the cell was retrieved well within the uncertainty of 1% of the amount in the cell. Multi frame retrievals on data in which the cell was not placed into the input beam demonstrated 1% precision. In addition, in situ surface measurements were done over a landfill park, where measurements of methane were taken over known hotspots. This research allows for the future

  15. Correlation spectrometer

    Science.gov (United States)

    Sinclair, Michael B.; Pfeifer, Kent B.; Flemming, Jeb H.; Jones, Gary D.; Tigges, Chris P.

    2010-04-13

    A correlation spectrometer can detect a large number of gaseous compounds, or chemical species, with a species-specific mask wheel. In this mode, the spectrometer is optimized for the direct measurement of individual target compounds. Additionally, the spectrometer can measure the transmission spectrum from a given sample of gas. In this mode, infrared light is passed through a gas sample and the infrared transmission signature of the gasses present is recorded and measured using Hadamard encoding techniques. The spectrometer can detect the transmission or emission spectra in any system where multiple species are present in a generally known volume.

  16. Current instrument status of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS)

    Science.gov (United States)

    Eastwood, Michael L.; Sarture, Charles M.; Chrien, Thomas G.; Green, Robert O.; Porter, Wallace M.

    1991-01-01

    An upgraded version of AVIRIS, an airborne imaging spectrometer based on a whiskbroom-type scanner coupled via optical fibers to four dispersive spectrometers, that has been in operation since 1987 is described. Emphasis is placed on specific AVIRIS subsystems including foreoptics, fiber optics, and an in-flight reference source; spectrometers and detector dewars; a scan drive mechanism; a signal chain; digital electronics; a tape recorder; calibration systems; and ground support requirements.

  17. Effects of spectrometer band pass, sampling, and signal-to-noise ratio on spectral identification using the Tetracorder algorithm

    Science.gov (United States)

    Swayze, G.A.; Clark, R.N.; Goetz, A.F.H.; Chrien, T.H.; Gorelick, N.S.

    2003-01-01

    Estimates of spectrometer band pass, sampling interval, and signal-to-noise ratio required for identification of pure minerals and plants were derived using reflectance spectra convolved to AVIRIS, HYDICE, MIVIS, VIMS, and other imaging spectrometers. For each spectral simulation, various levels of random noise were added to the reflectance spectra after convolution, and then each was analyzed with the Tetracorder spectra identification algorithm [Clark et al., 2003]. The outcome of each identification attempt was tabulated to provide an estimate of the signal-to-noise ratio at which a given percentage of the noisy spectra were identified correctly. Results show that spectral identification is most sensitive to the signal-to-noise ratio at narrow sampling interval values but is more sensitive to the sampling interval itself at broad sampling interval values because of spectral aliasing, a condition when absorption features of different materials can resemble one another. The band pass is less critical to spectral identification than the sampling interval or signal-to-noise ratio because broadening the band pass does not induce spectral aliasing. These conclusions are empirically corroborated by analysis of mineral maps of AVIRIS data collected at Cuprite, Nevada, between 1990 and 1995, a period during which the sensor signal-to-noise ratio increased up to sixfold. There are values of spectrometer sampling and band pass beyond which spectral identification of materials will require an abrupt increase in sensor signal-to-noise ratio due to the effects of spectral aliasing. Factors that control this threshold are the uniqueness of a material's diagnostic absorptions in terms of shape and wavelength isolation, and the spectral diversity of the materials found in nature and in the spectral library used for comparison. Array spectrometers provide the best data for identification when they critically sample spectra. The sampling interval should not be broadened to

  18. A method to correct sampling ghosts in historic near-infrared Fourier Transform Spectrometer (FTS measurements

    Directory of Open Access Journals (Sweden)

    S. Dohe

    2013-04-01

    Full Text Available The Total Carbon Column Observing Network (TCCON has been established to provide ground-based remote sensing measurements of the column-average dry air mole fractions of key greenhouse gases. To ensure the network wide consistency, biases between Fourier Transform spectrometers at different sites have to be well controlled. In this study we investigate a fundamental correction scheme for errors in the sampling of the interferogram. This is a two-step procedure in which the laser sampling error (LSE is quantified using a subset of suitable interferograms and then used to resample all the interferograms in the timeseries. Timeseries of measurements acquired at the TCCON sites Izaña and Lauder are used to demonstrate the method. At both sites the sampling error histories show changes in LSE due to instrument interventions. Estimated LSE are in good agreement with sampling errors inferred from lamp measurements of the ghost to parent ratio (Lauder. The LSE introduce retrieval biases which are minimised when the interferograms are resampled. The original timeseries of Xair and XCO2 at both sites show discrepancies of 0.2–0.5% due to changes in the LSE associated with instrument interventions or changes in the measurement sample rate. After resampling discrepancies are reduced to 0.1% at Lauder and 0.2% at Izaña. In the latter case, coincident changes in interferometer alignment may also contribute to the residual difference.

  19. Spectral calibration for deriving surface mineralogy of Asteroid (25143) Itokawa from Hayabusa Near-Infrared Spectrometer (NIRS) Data

    CERN Document Server

    Bhatt, Megha; Corre, Lucille Le; Sanchez, Juan A; Dunn, Tasha; Izawa, Matthew R M; Li, Jian-Yang; Becker, Kris J; Weller, Lynn

    2015-01-01

    We present spectral calibration equations for determining mafic silicate composition of near-Earth asteroid (25143) Itokawa from visible/near-infrared spectra measured using the Near Infrared Spectrometer (NIRS), on board the Japanese Hayabusa spacecraft. Itokawa was the target of the Hayabusa sample return mission and has a surface composition similar to LL-type ordinary chondrites. Existing laboratory spectral calibrations use a spectral wavelength range that is wider (0.75-2.5 microns) than that of the NIRS instrument (0.85-2.1 microns) making them unfit for interpreting the Hayabusa spectral data currently archived in the Planetary Data System. We used laboratory measured near-infrared reflectance spectra of ordinary (H, L and LL) chondrites from the study of Dunn et al. (2010), which we resampled to the NIRS wavelength range. Using spectral parameters extracted from these resampled spectra we established a relationship between band parameters and their mafic silicate composition (olivine and low-Ca pyrox...

  20. Level 2 processing for the imaging Fourier transform spectrometer GLORIA: derivation and validation of temperature and trace gas volume mixing ratios from calibrated dynamics mode spectra

    Directory of Open Access Journals (Sweden)

    J. Ungermann

    2015-06-01

    Full Text Available The Gimballed Limb Observer for Radiance Imaging of the Atmosphere (GLORIA is an airborne infrared limb imager combining a two-dimensional infrared detector with a Fourier transform spectrometer. It was operated aboard the new German Gulfstream G550 High Altitude LOng Range (HALO research aircraft during the Transport And Composition in the upper Troposphere/lowermost Stratosphere (TACTS and Earth System Model Validation (ESMVAL campaigns in summer 2012. This paper describes the retrieval of temperature and trace gas (H2O, O3, HNO3 volume mixing ratios from GLORIA dynamics mode spectra that are spectrally sampled every 0.625 cm−1. A total of 26 integrated spectral windows are employed in a joint fit to retrieve seven targets using consecutively a fast and an accurate tabulated radiative transfer model. Typical diagnostic quantities are provided including effects of uncertainties in the calibration and horizontal resolution along the line of sight. Simultaneous in situ observations by the Basic Halo Measurement and Sensor System (BAHAMAS, the Fast In-situ Stratospheric Hygrometer (FISH, an ozone detector named Fairo, and the Atmospheric chemical Ionization Mass Spectrometer (AIMS allow a validation of retrieved values for three flights in the upper troposphere/lowermost stratosphere region spanning polar and sub-tropical latitudes. A high correlation is achieved between the remote sensing and the in situ trace gas data, and discrepancies can to a large extent be attributed to differences in the probed air masses caused by different sampling characteristics of the instruments. This 1-D processing of GLORIA dynamics mode spectra provides the basis for future tomographic inversions from circular and linear flight paths to better understand selected dynamical processes of the upper troposphere and lowermost stratosphere.

  1. An evaluation method of reflectance spectra to be obtained by Hayabusa2 Near-Infrared Spectrometer (NIRS3) based on laboratory measurements of carbonaceous chondrites

    Science.gov (United States)

    Matsuoka, Moe; Nakamura, Tomoki; Osawa, Takahito; Iwata, Takahiro; Kitazato, Kohei; Abe, Masanao; Nakauchi, Yusuke; Arai, Takehiko; Komatsu, Mutsumi; Hiroi, Takahiro; Imae, Naoya; Yamaguchi, Akira; Kojima, Hideyasu

    2017-09-01

    We conducted ground-based performance evaluation tests of the Near-Infrared Spectrometer (NIRS3) onboard Hayabusa2 spacecraft in November 2013 and from April to May 2014 and established a method for evaluating its measured reflectance spectra. Reflectance spectra of nine powdered carbonaceous chondrite samples were measured by both NIRS3 and a Fourier transform infrared (FT-IR) spectrometer. We have established two methods for correcting the NIRS3 data by comparing them with the corresponding FT-IR data because raw data obtained by NIRS3 underwent spectral distortion caused by systematic offsets in sensitivity of individual pixels. The corrected NIRS3 spectra of carbonaceous chondrite samples are comparable with their FT-IR spectra. The depth of each band component D λ is defined for each wavelength λ (μm) to characterize the absorption bands in NIRS3 spectra. It is suggested that the relationship between the D 2.72/ D 2.79 ratio and the D 2.76/ D 2.90 ratio would be useful for estimating the degree of heating of the asteroid surface, if contributions of terrestrial adsorbed water on D 2.79 and D 2.90 are properly corrected. The degrees of heating and space weathering are also comprehensively evaluated by the relationship between D 2.90 and the D 2.76/ D 2.90 ratio. Reflectance spectra of asteroid Ryugu, the target asteroid of Hayabusa2, to be recorded by the NIRS3 instrument are expected to reveal the characteristics of the surface materials by using the evaluation technique proposed in this paper. Such information will be used for choosing the touchdown points for sampling and also for investigating the distribution of the materials similar to the returned samples on Ryugu.[Figure not available: see fulltext.

  2. DLP NIRscan Nano: an ultra-mobile DLP-based near-infrared Bluetooth spectrometer

    Science.gov (United States)

    Gelabert, Pedro; Pruett, Eric; Perrella, Gavin; Subramanian, Sreeram; Lakshminarayanan, Aravind

    2016-02-01

    The DLP NIRscan Nano is an ultra-portable spectrometer evaluation module utilizing DLP technology to meet lower cost, smaller size, and higher performance than traditional architectures. The replacement of a linear array detector with DLP digital micromirror device (DMD) in conjunction with a single point detector adds the functionality of programmable spectral filters and sampling techniques that were not previously available on NIR spectrometers. This paper presents the hardware, software, and optical systems of the DLP NIRscan Nano and its design considerations on the implementation of a DLP-based spectrometer.

  3. Coherent-radiation spectroscopy of few-femtosecond electron bunches using a middle-infrared prism spectrometer.

    Science.gov (United States)

    Maxwell, T J; Behrens, C; Ding, Y; Fisher, A S; Frisch, J; Huang, Z; Loos, H

    2013-11-01

    Modern, high-brightness electron beams such as those from plasma wakefield accelerators and free-electron laser linacs continue the drive to ever-shorter bunch durations. In low-charge operation (~20 pC), bunches shorter than 10 fs are reported at the Linac Coherent Light Source (LCLS). Though suffering from a loss of phase information, spectral diagnostics remain appealing as compact, low-cost bunch duration monitors suitable for deployment in beam dynamics studies and operations instrumentation. Progress in middle-infrared (MIR) imaging has led to the development of a single-shot, MIR prism spectrometer to characterize the corresponding LCLS coherent beam radiation power spectrum for few-femtosecond scale bunch length monitoring. In this Letter, we report on the spectrometer installation as well as the temporal reconstruction of 3 to 60 fs-long LCLS electron bunch profiles using single-shot coherent transition radiation spectra.

  4. Coherent-Radiation Spectroscopy of Few-Femtosecond Electron Bunches Using a Middle-Infrared Prism Spectrometer

    Science.gov (United States)

    Maxwell, T. J.; Behrens, C.; Ding, Y.; Fisher, A. S.; Frisch, J.; Huang, Z.; Loos, H.

    2013-11-01

    Modern, high-brightness electron beams such as those from plasma wakefield accelerators and free-electron laser linacs continue the drive to ever-shorter bunch durations. In low-charge operation (˜20pC), bunches shorter than 10 fs are reported at the Linac Coherent Light Source (LCLS). Though suffering from a loss of phase information, spectral diagnostics remain appealing as compact, low-cost bunch duration monitors suitable for deployment in beam dynamics studies and operations instrumentation. Progress in middle-infrared (MIR) imaging has led to the development of a single-shot, MIR prism spectrometer to characterize the corresponding LCLS coherent beam radiation power spectrum for few-femtosecond scale bunch length monitoring. In this Letter, we report on the spectrometer installation as well as the temporal reconstruction of 3 to 60 fs-long LCLS electron bunch profiles using single-shot coherent transition radiation spectra.

  5. Ultrasensitive Mid-Infrared In Situ Spectrometer for Planetary Atmospheric Analysis Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Small Business Innovative Research Phase I proposal seeks to develop a compact, robust in situ spectrometer capable of detecting multiple gas-phase species in...

  6. Ultrasensitive Mid-Infrared In Situ Spectrometer for Planetary Atmospheric Analysis Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Small Business Innovative Research Phase I proposal seeks to develop a compact, robust in situ spectrometer capable of detecting multiple gas-phase species in...

  7. A method to correct sampling ghosts in historic near-infrared Fourier transform spectrometer (FTS measurements

    Directory of Open Access Journals (Sweden)

    S. Dohe

    2013-08-01

    Full Text Available The Total Carbon Column Observing Network (TCCON has been established to provide ground-based remote sensing measurements of the column-averaged dry air mole fractions (DMF of key greenhouse gases. To ensure network-wide consistency, biases between Fourier transform spectrometers at different sites have to be well controlled. Errors in interferogram sampling can introduce significant biases in retrievals. In this study we investigate a two-step scheme to correct these errors. In the first step the laser sampling error (LSE is estimated by determining the sampling shift which minimises the magnitude of the signal intensity in selected, fully absorbed regions of the solar spectrum. The LSE is estimated for every day with measurements which meet certain selection criteria to derive the site-specific time series of the LSEs. In the second step, this sequence of LSEs is used to resample all the interferograms acquired at the site, and hence correct the sampling errors. Measurements acquired at the Izaña and Lauder TCCON sites are used to demonstrate the method. At both sites the sampling error histories show changes in LSE due to instrument interventions (e.g. realignment. Estimated LSEs are in good agreement with sampling errors inferred from the ratio of primary and ghost spectral signatures in optically bandpass-limited tungsten lamp spectra acquired at Lauder. The original time series of Xair and XCO2 (XY: column-averaged DMF of the target gas Y at both sites show discrepancies of 0.2–0.5% due to changes in the LSE associated with instrument interventions or changes in the measurement sample rate. After resampling, discrepancies are reduced to 0.1% or less at Lauder and 0.2% at Izaña. In the latter case, coincident changes in interferometer alignment may also have contributed to the residual difference. In the future the proposed method will be used to correct historical spectra at all TCCON sites.

  8. A method to correct sampling ghosts in historic near-infrared Fourier transform spectrometer (FTS) measurements

    Science.gov (United States)

    Dohe, S.; Sherlock, V.; Hase, F.; Gisi, M.; Robinson, J.; Sepúlveda, E.; Schneider, M.; Blumenstock, T.

    2013-08-01

    The Total Carbon Column Observing Network (TCCON) has been established to provide ground-based remote sensing measurements of the column-averaged dry air mole fractions (DMF) of key greenhouse gases. To ensure network-wide consistency, biases between Fourier transform spectrometers at different sites have to be well controlled. Errors in interferogram sampling can introduce significant biases in retrievals. In this study we investigate a two-step scheme to correct these errors. In the first step the laser sampling error (LSE) is estimated by determining the sampling shift which minimises the magnitude of the signal intensity in selected, fully absorbed regions of the solar spectrum. The LSE is estimated for every day with measurements which meet certain selection criteria to derive the site-specific time series of the LSEs. In the second step, this sequence of LSEs is used to resample all the interferograms acquired at the site, and hence correct the sampling errors. Measurements acquired at the Izaña and Lauder TCCON sites are used to demonstrate the method. At both sites the sampling error histories show changes in LSE due to instrument interventions (e.g. realignment). Estimated LSEs are in good agreement with sampling errors inferred from the ratio of primary and ghost spectral signatures in optically bandpass-limited tungsten lamp spectra acquired at Lauder. The original time series of Xair and XCO2 (XY: column-averaged DMF of the target gas Y) at both sites show discrepancies of 0.2-0.5% due to changes in the LSE associated with instrument interventions or changes in the measurement sample rate. After resampling, discrepancies are reduced to 0.1% or less at Lauder and 0.2% at Izaña. In the latter case, coincident changes in interferometer alignment may also have contributed to the residual difference. In the future the proposed method will be used to correct historical spectra at all TCCON sites.

  9. Continuous Measurements of Dissolved Ne, Ar, Kr, and Xe Ratios with a Field-Deployable Gas Equilibration Mass Spectrometer.

    Science.gov (United States)

    Manning, Cara C; Stanley, Rachel H R; Lott, Dempsey E

    2016-03-15

    Noble gases dissolved in natural waters are useful tracers for quantifying physical processes. Here, we describe a field-deployable gas equilibration mass spectrometer (GEMS) that provides continuous, real-time measurements of Ne, Ar, Kr, and Xe mole ratios in natural waters. Gas is equilibrated with a membrane contactor cartridge and measured with a quadrupole mass spectrometer, after in-line purification with reactive metal alloy getters. We use an electron energy of 35 V for Ne to eliminate isobaric interferences, and a higher electron energy for the other gases to improve sensitivity. The precision is 0.7% or better and 1.0% or better for all mole ratios when the instrument is installed in a temperature-controlled environment and a variable-temperature environment, respectively. In the lab, the accuracy is 0.9% or better for all gas ratios using air as the only calibration standard. In the field (and/or at greater levels of disequilbrium), the accuracy is 0.7% or better for Ne/Kr, Ne/Ar, and Ar/Kr, and 2.5% or better for Ne/Xe, Ar/Xe, and Kr/Xe using air as the only calibration standard. The field accuracy improves to 0.6% or better for Ne/Xe, Ar/Xe, and Kr/Xe when the data is calibrated using discrete water samples run on a laboratory-based mass spectrometer. The e-folding response time is 90-410 s. This instrument enables the collection of a large number of continuous, high-precision and accuracy noble gas measurements at substantially reduced cost and labor compared to traditional methods.

  10. On-Chip Micro-Electro-Mechanical System Fourier Transform Infrared (MEMS FT-IR) Spectrometer-Based Gas Sensing.

    Science.gov (United States)

    Erfan, Mazen; Sabry, Yasser M; Sakr, Mohammad; Mortada, Bassem; Medhat, Mostafa; Khalil, Diaa

    2016-05-01

    In this work, we study the detection of acetylene (C2H2), carbon dioxide (CO2) and water vapor (H2O) gases in the near-infrared (NIR) range using an on-chip silicon micro-electro-mechanical system (MEMS) Fourier transform infrared (FT-IR) spectrometer in the wavelength range 1300-2500 nm (4000-7692 cm(-1)). The spectrometer core engine is a scanning Michelson interferometer micro-fabricated using a deep-etching technology producing self-aligned components. The light is free-space propagating in-plane with respect to the silicon chip substrate. The moving mirror of the interferometer is driven by a relatively large stroke electrostatic comb-drive actuator corresponding to about 30 cm(-1) resolution. Multi-mode optical fibers are used to connect light between the wideband light source, the interferometer, the 10 cm gas cell, and the optical detector. A wide dynamic range of gas concentration down to 2000 parts per million (ppm) in only 10 cm length gas cell is demonstrated. Extending the wavelength range to the mid-infrared (MIR) range up to 4200 nm (2380 cm(-1)) is also experimentally demonstrated, for the first time, using a bulk micro-machined on-chip MEMS FT-IR spectrometer. The obtained results open the door for an on-chip optical gas sensor for many applications including environmental sensing and industrial process control in the NIR/MIR spectral ranges.

  11. Determining the clay/organic carbon ratio by visible near infrared spectroscopy

    DEFF Research Database (Denmark)

    Knadel, Maria; Peng, Yi; Hermansen, Cecilie

    /OC ratio directly would be valuable. Visible near infrared spectroscopy (vis-NIRS) is a cost-effective method for soil analysis and was tested here for the prediction of clay/OC ratio. Soil samples from two agricultural fields in Denmark (N=115) were analyzed. Partial Least Squares regression (full cross...

  12. Infrared heterodyne spectrometer measurements of vertical profile of tropospheric ammonia and ozone. [using dual carbon dioxide laser

    Science.gov (United States)

    Peyton, B. J.; Lange, R. A.; Savage, M. G.; Seals, R. K.; Allario, F.

    1977-01-01

    Remote sensing of the concentration and vertical distribution of atmospheric gases has been carried out using a dual CO2 laser multichannel infrared heterodyne spectrometer (IHS). The high specificity and nearly quantum-noise-limited sensitivity of the IHS provide the capability of scanning individual signature lines of selected atmospheric constituents in the 9 to 11 micron region. A comprehensive investigation of the spectral overlap between CO2 laser local oscillator transitions and selected atmospheric constituents was performed; measurements of the atmospheric absorption of solar radiation from the ground were carried out at selected laser transitions for ammonia and ozone.

  13. Geometric and radiometric preprocessing of airborne visible/infrared imaging spectrometer (AVIRIS) data in rugged terrain for quantitative data analysis

    Science.gov (United States)

    Meyer, Peter; Green, Robert O.; Staenz, Karl; Itten, Klaus I.

    1994-01-01

    A geocoding procedure for remotely sensed data of airborne systems in rugged terrain is affected by several factors: buffeting of the aircraft by turbulence, variations in ground speed, changes in altitude, attitude variations, and surface topography. The current investigation was carried out with an Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) scene of central Switzerland (Rigi) from NASA's Multi Aircraft Campaign (MAC) in Europe (1991). The parametric approach reconstructs for every pixel the observation geometry based on the flight line, aircraft attitude, and surface topography. To utilize the data for analysis of materials on the surface, the AVIRIS data are corrected to apparent reflectance using algorithms based on MODTRAN (moderate resolution transfer code).

  14. Geometric and radiometric preprocessing of airborne visible/infrared imaging spectrometer (AVIRIS) data in rugged terrain for quantitative data analysis

    Science.gov (United States)

    Meyer, Peter; Green, Robert O.; Staenz, Karl; Itten, Klaus I.

    1994-01-01

    A geocoding procedure for remotely sensed data of airborne systems in rugged terrain is affected by several factors: buffeting of the aircraft by turbulence, variations in ground speed, changes in altitude, attitude variations, and surface topography. The current investigation was carried out with an Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) scene of central Switzerland (Rigi) from NASA's Multi Aircraft Campaign (MAC) in Europe (1991). The parametric approach reconstructs for every pixel the observation geometry based on the flight line, aircraft attitude, and surface topography. To utilize the data for analysis of materials on the surface, the AVIRIS data are corrected to apparent reflectance using algorithms based on MODTRAN (moderate resolution transfer code).

  15. Airborne Laser Absorption Spectrometer Measurements of CO2 Column Mixing Ratios: Source and Sink Detection in the Atmospheric Environment

    Directory of Open Access Journals (Sweden)

    Menzies Robert T.

    2016-01-01

    Full Text Available The JPL airborne Laser Absorption Spectrometer instrument has been flown several times in the 2007-2011 time frame for the purpose of measuring CO2 mixing ratios in the lower atmosphere. The four most recent flight campaigns were on the NASA DC-8 research aircraft, in support of the NASA ASCENDS (Active Sensing of CO2 Emissions over Nights, Days, and Seasons mission formulation studies. This instrument operates in the 2.05-μm spectral region. The Integrated Path Differential Absorption (IPDA method is used to retrieve weighted CO2 column mixing ratios. We present key features of the CO2LAS signal processing, data analysis, and the calibration/validation methodology. Results from flights in various U.S. locations during the past three years include observed mid-day CO2 drawdown in the Midwest, also cases of point-source and regional plume detection that enable the calculation of emission rates.

  16. Airborne Laser Absorption Spectrometer Measurements of CO2 Column Mixing Ratios: Source and Sink Detection in the Atmospheric Environment

    Science.gov (United States)

    Menzies, Robert T.; Spiers, Gary D.; Jacob, Joseph C.

    2016-06-01

    The JPL airborne Laser Absorption Spectrometer instrument has been flown several times in the 2007-2011 time frame for the purpose of measuring CO2 mixing ratios in the lower atmosphere. The four most recent flight campaigns were on the NASA DC-8 research aircraft, in support of the NASA ASCENDS (Active Sensing of CO2 Emissions over Nights, Days, and Seasons) mission formulation studies. This instrument operates in the 2.05-μm spectral region. The Integrated Path Differential Absorption (IPDA) method is used to retrieve weighted CO2 column mixing ratios. We present key features of the CO2LAS signal processing, data analysis, and the calibration/validation methodology. Results from flights in various U.S. locations during the past three years include observed mid-day CO2 drawdown in the Midwest, also cases of point-source and regional plume detection that enable the calculation of emission rates.

  17. Methods for Retrievals of CO2 Mixing Ratios from JPL Laser Absorption Spectrometer Flights During a Summer 2011 Campaign

    Science.gov (United States)

    Menzies, Robert T.; Spiers, Gary D.; Jacob, Joseph C.

    2013-01-01

    The JPL airborne Laser Absorption Spectrometer instrument has been flown several times in the 2007-2011 time frame for the purpose of measuring CO2 mixing ratios in the lower atmosphere. This instrument employs CW laser transmitters and coherent detection receivers in the 2.05- micro m spectral region. The Integrated Path Differential Absorption (IPDA) method is used to retrieve weighted CO2 column mixing ratios. We present key features of the evolving LAS signal processing and data analysis algorithms and the calibration/validation methodology. Results from 2011 flights in various U.S. locations include observed mid-day CO2 drawdown in the Midwest and high spatial resolution plume detection during a leg downwind of the Four Corners power plant in New Mexico.

  18. Hydrated salt minerals on Europa's Surface from the Galileo near-infrared mapping spectrometer (NIMS) investigation

    Science.gov (United States)

    McCord, T.B.; Hansen, G.B.; Matson, D.L.; Johnson, T.V.; Crowley, J.K.; Fanale, F.P.; Carlson, R.W.; Smythe, W.D.; Martin, P.D.; Hibbitts, C.A.; Granahan, J.C.; Ocampo, A.

    1999-01-01

    We reported evidence of heavily hydrated salt minerals present over large areas of Europa's surface from analysis of reflectance spectra returned by the Galileo mission near infrared mapping spectrometer (NIMS) [McCord et al., 1997a, b, 1998a, b]. Here we elaborate on this earlier evidence, present spatial distributions of these minerals, examine alternate water-ice interpretations, expand on our hydrated-salts interpretation, consider salt mineral stability on Europa, and discuss the implications. Extensive well-defined areas on Europa show distinct, asymmetric water-related absorption bands in the 1 to 2.5-??m region. Radiative transfer modeling of water ice involving different particle sizes and layers at Europa temperatures does not reproduce the distinctive Europa water bands. However, ice near its melting temperature, such as in terrestrial environments, does have some characteristics of the Europa spectrum. Alternatively, some classes of heavily hydrated minerals do exhibit such water bands. Among plausible materials, heavily hydrated salt minerals, such as magnesium and sodium sulfates, sodium carbonate and their mixtures, are preferred. All Europa spectral features are present in some salt minerals and a very good match to the Europa spectrum can be achieved by mixing several salt spectra. However, no single or mix of salt mineral spectra from the limited library available has so far been found to perfectly match the Europa spectrum in every detail. The material is concentrated at the lineaments and in chaotic terrain, which are technically disrupted areas on the trailing side. Since the spectrum of the material on Europa is nearly the same everywhere so-far studied, the salt or salt-mixture composition may be nearly uniform. This suggests similar sources and processes over at least a near-hemispheric scale. This would suggest that an extensive subsurface ocean containing dissolved salts is the source, and several possible mechanisms for deposit

  19. A broadband ultrafast transient absorption spectrometer covering the range from near-infrared (NIR) down to green.

    Science.gov (United States)

    Schmidhammer, Uli; Jeunesse, Pierre; Stresing, Gerhard; Mostafavi, Mehran

    2014-01-01

    We present a new development for pump-probe absorption spectroscopy that allows the simultaneous measurement from the green part of the visible spectrum (510 nm) over the whole near-infrared range to >1600 nm, corresponding to 0.77-2.40 eV. The system is based on a sub-picosecond supercontinuum generated in bulk material used as a broadband probe that is dispersed with a custom-made prism spectrometer and detected by an InGaAs array with extended sensitivity to the visible. Two versions, with and without probe referencing, are implemented for operation at laser repetition rates of a few hertz and kilohertz, respectively. After presentation of the optical configuration of the spectrometer, its performance is characterized and further illustrated on two time scales, with the ultrafast radiolysis of isopropanol induced by a picosecond electron pulse and with the instantaneous response of a BK7 plate to a femtosecond light pulse. The photophysics of the dye IR-140 is resolved from the femto- to picosecond regime. Stable and easy day-to-day routine use of the spectrometer also can be achieved in non-optical laboratory surroundings. For operation in a hazardous environment, the optical probe beams can be transported to the detector unit by optical fibers.

  20. A review on the applications of portable near-infrared spectrometers in the agro-food industry.

    Science.gov (United States)

    dos Santos, Cláudia A Teixeira; Lopo, Miguel; Páscoa, Ricardo N M J; Lopes, João A

    2013-11-01

    Industry has created the need for a cost-effective and nondestructive quality-control analysis system. This requirement has increased interest in near-infrared (NIR) spectroscopy, leading to the development and marketing of handheld devices that enable new applications that can be implemented in situ. Portable NIR spectrometers are powerful instruments offering several advantages for nondestructive, online, or in situ analysis: small size, low cost, robustness, simplicity of analysis, sample user interface, portability, and ergonomic design. Several studies of on-site NIR applications are presented: characterization of internal and external parameters of fruits and vegetables; conservation state and fat content of meat and fish; distinguishing among and quality evaluation of beverages and dairy products; protein content of cereals; evaluation of grape ripeness in vineyards; and soil analysis. Chemometrics is an essential part of NIR spectroscopy manipulation because wavelength-dependent scattering effects, instrumental noise, ambient effects, and other sources of variability may complicate the spectra. As a consequence, it is difficult to assign specific absorption bands to specific functional groups. To achieve useful and meaningful results, multivariate statistical techniques (essentially involving regression techniques coupled with spectral preprocessing) are therefore required to extract the information hidden in the spectra. This work reviews the evolution of the use of portable near-infrared spectrometers in the agro-food industry.

  1. The Thermal Infrared Compact Imaging Spectrometer (TIRCIS): a follow-on to the Space Ultra Compact Hyperspectral Imager (SUCHI)

    Science.gov (United States)

    Crites, S. T.; Wright, R.; Lucey, P. G.; Chan, J.; Gabrieli, A.; Garbeil, H.; Horton, K. A.; Imai-Hong, A. K. R.; Pilger, E. J.; Wood, M.; Yoneshige, L.

    2015-05-01

    The Thermal Infrared Compact Imaging Spectrometer (TIRCIS) is a long wave infrared (LWIR, 8-14 microns) hyperspectral imager designed as the follow-on to the University of Hawaii's SUCHI (Space Ultra Compact Hyperspectral Imager). SUCHI is a low-mass (transform spectrometer with images collected by a commercial off-the-shelf microbolometer contained inside a 1-atm sealed vessel. The sensor has been fully integrated with the HiakaSat microsatellite and is awaiting launch in 2015. The TIRCIS instrument is based on the same principles but takes lessons learned from SUCHI and applies them to a new design with improvements in spatial resolution, spectral resolution and spectral responsivity. The TIRCIS instrument is based on an uncooled microbolometer array with custom detector coatings to enhance responsivity towards 7 microns. Like SUCHI, TIRCIS utilizes a variable-gap Fabry Perot interferometer to create the spectra, but three different interferometer wedges with varying slopes resulting in spectral resolution ranging from 44 cm-1 to 6.5 cm-1 will be tested to explore tradeoffs between spectral resolution and sensitivity. TIRCIS is designed to achieve 120 m spatial resolution, compared with 230 m for SUCHI, from a theoretical 500 km orbit. It will be used for ground and aircraft data collection but will undergo environmental testing to demonstrate its relevance to the space environment. TIRCIS has been fully designed and is entering fabrication, with an operational instrument to be delivered in October, 2015.

  2. An airborne infrared laser spectrometer for in-situ trace gas measurements: application to tropical convection case studies

    Directory of Open Access Journals (Sweden)

    V. Catoire

    2015-09-01

    Full Text Available A three-channel laser absorption spectrometer called SPIRIT (SPectromètre InfraRouge In situ Toute altitude has been developed for airborne measurements of trace gases in the troposphere and lower stratosphere. More than three different species can be measured simultaneously with high time resolution (each 1.6 s using three individual CW-DFB-QCLs (Continuous Wave Distributed FeedBack Quantum Cascade Lasers coupled to a single Robert multipass optical cell. The lasers are operated in a time-multiplexed mode. Absorption of the mid-infrared radiations occur in the cell (2.8 L with effective path lengths of 134 to 151 m at reduced pressure, with detection achieved using a HgCdTe detector cooled by Stirling cycle. The performances of the instrument are described, in particular precisions of 1, 1 and 3 %, and volume mixing ratio (vmr sensitivities of 0.4, 6 and 2.4 ppbv are determined at 1.6 s for CO, CH4 and N2O, respectively (at 1σ confidence level. Estimated accuracies without calibration are about 6 %. Dynamic measuring ranges of about four decades are established. The first deployment of SPIRIT was realized aboard the Falcon-20 research aircraft operated by DLR (Deutsches Zentrum für Luft- und Raumfahrt within the frame of the SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere European project in November-December 2011 over Malaysia. The convective outflows from two large convective systems near Borneo Island (6.0° N–115.5° E and 5.5° N–118.5° E were sampled above 11 km in altitude on 19 November and 9 December, respectively. Correlated enhancements in CO and CH4 vmr were detected when the aircraft crossed the outflow anvil of both systems. These enhancements were interpreted as the fingerprint of transport from the boundary layer up through the convective system and then horizontal advection in the outflow. Using these observations, the fraction of boundary layer air contained in fresh convective outflow was

  3. Fabrication of High Aspect Ratio SU-8 Structures for Integrated Spectrometers

    DEFF Research Database (Denmark)

    Anhøj, Thomas Aarøe

    2007-01-01

    of photolithography. Successful fabrication of re ection gratings requires a high degree of precision in the photolithographic process. The fabrication process has thus been optimized by optimizing the photolithographic process for fabrication of high aspect ratio structures, i.e. structures with details...... that are small compared to the height of the structure. A decisive factor is the ability of the process to separate closely- spaced structures. The primary measure of quality is thus the aspect ratio of the narrowest trench which it is possible to resolve in the lithographic process. The optimization...

  4. The mid-infrared instrument for the James Webb Space telescope, VI: the medium resolution spectrometer

    NARCIS (Netherlands)

    Wells, M.; Pel, J.W.; Glasse, A.; Wright, G.S.; Aitink-Kroes, G.; Azzollini, R.; Beard, S.; Brandl, B.R.; Gallie, A.; Geers, V.C.; Glauser, A.M.; Hastings, P.; Henning, T.; Jager, R.; Justtanont, K.; Kruizinga, B.; Lahuis, F.; Lee, D.; Martinez-Delgado, I.; Martínez-Galarza, J.R.; Meijers, M.; Morrison, J.E.; Müller, F.; Nakos, T.; O’Sullivan, B.; Oudenhuysen, A.; Parr-Burman, P.; Pauwels, E.; Rohloff, R.R.; Schmalzl, E.; Sykes, J.; Thelen, M.P.; Dishoeck, E.F. van; Vandenbussche, B.; Venema, L.B.; Visser, H.; Waters, L.B.F.M.; Wright, D.

    2015-01-01

    We describe the design and performance of the Medium Resolution Spectrometer (MRS) for the JWST-MIRI instrument. The MRS incorporates four coaxial spectral channels in a compact opto-mechanical layout that generates spectral images over fields of view up to 7.7 × 7.7″ in extent and at spectral resol

  5. The Mid-Infrared Instrument for the James Webb Space Telescope, VI: The Medium Resolution Spectrometer

    NARCIS (Netherlands)

    Wells, M.; Pel, J.-W.; Glasse, A.; Wright, G.S.; Aitink-Kroes, G.; Azzollini, R.; Beard, S.; Brandl, B.R.; Gallie, A.; Geers, V.C.; Glauser, A.M.; Hastings, P.; Henning, Th.; Jager, R.; Justtanont, K.; Kruizinga, B.; Lahuis, F.; Lee, D.; Martinez-Delgado, I.; Martínez-Galarza, J.R.; Meijers, M.; Morrison, J.E.; Müller, F.; Nakos, T.; O'Sullivan, B.; Oudenhuysen, A.; Parr-Burman, P.; Pauwels, E.; Rohloff, R.R.; Schmalzl, E.; Sykes, J.; Thelen, M.P.; van Dishoeck, E.F.; Vandenbussche, B.; Venema, L.B.; Visser, H.; Waters, L.B.F.M.; Wright, D.

    2015-01-01

    We describe the design and performance of the Medium Resolution Spectrometer (MRS) for the JWST-MIRI instrument. The MRS incorporates four coaxial spectral channels in a compact opto-mechanical layout that generates spectral images over fields of view up to 7.7 × 7.7'' in extent and at spectral reso

  6. Measurement of surface temperature and emissivity by a multitemperature method for Fourier-transform infrared spectrometers

    DEFF Research Database (Denmark)

    Clausen, Sønnik; Morgenstjerne, Axel; Rathmann, Ole

    1996-01-01

    Surface temperatures are estimated with high precision based on a multitemperature method for Fourier-transform spectrometers. The method is based on Planck's radiation law and a nonlinear least-squares fitting algorithm applied to two or more spectra at different sample temperatures and a single...

  7. Thermal infrared spectrometer for earth science remote sensing applications : instrument modifications and measurement procedures

    NARCIS (Netherlands)

    Hecker, C.; Hook, S.; Meijde, M. van der; Bakker, W.H.; Werff, H.M.A. van der; Wilbrink, H.J.; Ruitenbeek, F.J.A. van; Smeth, J.B. de; Meer, F.D. van der

    2011-01-01

    In this article we describe a new instrumental setup at the University of Twente Faculty ITC with an optimized processing chain to measure absolute directional-hemispherical reflectance values of typical earth science samples in the 2.5 to 16 μm range. A Bruker Vertex 70 FTIR spectrometer was chosen

  8. High-pressure-low-temperature cryostat designed for use with fourier transform infrared spectrometers and time-resolved infrared spectroscopy.

    Science.gov (United States)

    Calladine, James A; Love, Ashley; Fields, Peter A; Wilson, Richard G M; George, Michael W

    2014-01-01

    The design for a new high-pressure-low-temperature infrared (IR) cell for performing experiments using conventional Fourier transform infrared or fast laser-based time-resolved infrared spectroscopy, in a range of solvents, is described. The design builds upon a commercially available compressor and cold end (Polycold PCC(®) and CryoTiger(®)), which enables almost vibration-free operation, ideal for use with sensitive instrumentation. The design of our cell and cryostat allows for the study of systems at temperatures from 77 to 310 K and at pressures up to 250 bar. The CaF2 windows pass light from the mid-IR to the ultraviolet (UV), enabling a number of experiments to be performed, such as Raman, UV-visible absorption spectroscopy, and time-resolved techniques where sample excitation/probing using continuous wave or pulsed lasers is required. We demonstrate the capabilities of this cell by detailing two different applications: (i) the reactivity of a range of Group V-VII organometallic alkane complexes using time-resolved spectroscopy on the millisecond timescale and (ii) the gas-to-liquid phase transition of CO2 at low temperature, which is applicable to measurements associated with transportation issues related to carbon capture and storage.

  9. Freeform lens collimating spectrum-folded Hadamard transform near-infrared spectrometer

    Science.gov (United States)

    Wang, Xiaoduo; Liu, Hua; Juschkin, Larissa; Li, Yunpeng; Xu, Jialin; Quan, Xiangqian; Lu, Zhenwu

    2016-12-01

    A novel Hadamard transform spectrometer collimated by a freeform lens has been designed, which doubles the working spectral range while the spectral resolution is maintained. The freeform lens is designed to redistribute the broadband spectra of the source from 800 nm to 2400 nm into two collimated beams with different wavelengths and different tilting angles, to achieve the folding of spectra on the digital micro-mirror devices (DMD). It is constructed by solving two partial differential equations. The grating diffraction efficiency of the two split beams are more uniform and higher compared with the traditional method. The simulation results show that the bandwidth of the spectrometer is doubled and the spectral resolution is better than 10 nm. The optical system becomes more compact, and the energy efficiency is improved by 11.98% by folding the spectra with one freeform lens and one grating.

  10. Miniature, Low-Power, Waveguide Based Infrared Fourier Transform Spectrometer for Spacecraft Remote Sensing

    Science.gov (United States)

    Hewagama, TIlak; Aslam, Shahid; Talabac, Stephen; Allen, John E., Jr.; Annen, John N.; Jennings, Donald E.

    2011-01-01

    Fourier transform spectrometers have a venerable heritage as flight instruments. However, obtaining an accurate spectrum exacts a penalty in instrument mass and power requirements. Recent advances in a broad class of non-scanning Fourier transform spectrometer (FTS) devices, generally called spatial heterodyne spectrometers, offer distinct advantages as flight optimized systems. We are developing a miniaturized system that employs photonics lightwave circuit principles and functions as an FTS operating in the 7-14 micrometer spectral region. The inteferogram is constructed from an ensemble of Mach-Zehnder interferometers with path length differences calibrated to mimic scan mirror sample positions of a classic Michelson type FTS. One potential long-term application of this technology in low cost planetary missions is the concept of a self-contained sensor system. We are developing a systems architecture concept for wide area in situ and remote monitoring of characteristic properties that are of scientific interest. The system will be based on wavelength- and resolution-independent spectroscopic sensors for studying atmospheric and surface chemistry, physics, and mineralogy. The self-contained sensor network is based on our concept of an Addressable Photonics Cube (APC) which has real-time flexibility and broad science applications. It is envisaged that a spatially distributed autonomous sensor web concept that integrates multiple APCs will be reactive and dynamically driven. The network is designed to respond in an event- or model-driven manner or reconfigured as needed.

  11. Step-scan Fourier transform infrared (FTIR) spectrometer for investigating chemical reactions of energy-related materials. Final report, April 1, 1995--March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Eyring, E.M.

    1997-11-04

    Two step-scan Fourier transform infrared (FTIR) spectrometers were purchased with URI-DOE funds by the University of Utah. These infrared spectrometers have been used to carry out the following investigations: the determination of strength of adsorption of organic molecules at the liquid-solid interface of coated attenuated total reflectance (ATR) elements, the kinetic study of the photoinitiated polymerization of a dental resin, the exploration of the kinetics of photochemical reactions of organic molecules in solution, and the development of a stopped-flow FTIR interface for measuring rates and mechanisms of reactions in solution that are not photoinitiated and do not have convenient ultraviolet-visible spectral features.

  12. Performance of the Imaging Fourier Transform Spectrometer with Photoconductive Detector Arrays: An Application for the AKARI Far-Infrared Instrument

    CERN Document Server

    Kawada, Mitsunobu; Murakami, Noriko; Matsuo, Hiroshi; Okada, Yoko; Yasuda, Akiko; Matsuura, Shuji; Shirahata, Mai; Doi, Yasuo; Kaneda, Hidehiro; Ootsubo, Takafumi; Nakagawa, Takao; Shibai, Hiroshi

    2008-01-01

    We have developed an imaging Fourier transform spectrometer (FTS) for space-based far-infrared astronomical observations. The FTS employs a newly developed photoconductive detector arrays with a capacitive trans-impedance amplifier, which makes the FTS a completely unique instrument. The FTS was installed as a function of the far-infrared instrument (FIS: Far-Infrared Surveyor) on the Japanese astronomical satellite, AKARI, which was launched on February 21, 2006 (UT) from the Uchinoura Space Center. The FIS-FTS had been operated for more than one year before liquid helium ran out on August 26, 2007. The FIS-FTS was operated nearly six hundreds times, which corresponds to more than one hundred hours of astronomical observations and almost the same amount of time for calibrations. As expected from laboratory measurements, the FIS-FTS performed well and has produced a large set of astronomical data for valuable objects. Meanwhile, it becomes clear that the detector transient effect is a considerable factor for ...

  13. The mid-infrared instrument for the James Webb Space Telescope: performance and operation of the Low-Resolution Spectrometer

    Science.gov (United States)

    Kendrew, Sarah; Scheithauer, Silvia; Bouchet, Patrice; Amiaux, Jerome; Azzollini, Ruymán.; Bouwman, Jeroen; Chen, Christine; Dubreuil, Didier; Fischer, Sebastian; Fox, Ori D.; Glasse, Alistair; Gordon, Karl; Greene, Tom; Hines, Dean C.; Lagage, Pierre-Olivier; Lahuis, Fred; Ronayette, Samuel; Wright, David; Wright, Gillian S.

    2016-07-01

    We describe here the performance and operational concept for the Low Resolution Spectrometer (LRS) of the mid-infrared instrument (MIRI) for the James Webb Space Telescope. The LRS will provide R˜100 slit and slitless spectroscopy from 5 to 12 micron, and its design is optimised for observations of compact sources, such as exoplanet host stars. We provide here an overview of the design of the LRS, and its performance as measured during extensive test campaigns, examining in particular the delivered image quality, dispersion, and resolving power, as well as spectrophotometric performance. The instrument also includes a slitless spectroscopy mode, which is optimally suited for transit spectroscopy of exoplanet atmospheres. We provide an overview of the operational procedures and the differences ahead of the JWST launch in 2018.

  14. Micro-Spec: An Ultra-Compact, High-Sensitivity Spectrometer for Far-Infrared and Sub-Millimeter Astronomy

    Science.gov (United States)

    Cataldo, Giuseppe; Hsieh, Wen-Ting; Huang, Wei-Chung; Moseley, S. Harvey; Stevenson, Thomas R.; Wollack, Edward J.

    2013-01-01

    High-performance, integrated spectrometers operating in the far-infrared and sub-millimeter promise to be powerful tools for the exploration of the epochs of reionization and initial galaxy formation. These devices, using high-efficiency superconducting transmission lines, can achieve the performance of a meter-scale grating spectrometer in an instrument implemented on a four-inch silicon wafer. Such a device, when combined with a cryogenic telescope in space, provides an enabling capability for studies of the early universe. Here, the optical design process for Micro-Spec (mu-Spec) is presented, with particular attention given to its two-dimensional diffractive region, where the light of different wavelengths is focused on the different detectors. The method is based on the stigmatization and minimization of the light path function in this bounded region, which results in an optimized geometrical configuration. A point design with an efficiency of approx. 90% has been developed for initial demonstration, and can serve as the basis for future instruments. Design variations on this implementation are also discussed, which can lead to lower efficiencies due to diffractive losses in the multimode region.

  15. Using a near-infrared spectrometer to estimate the age of Anopheles mosquitoes exposed to pyrethroids

    Science.gov (United States)

    We report on the accuracy of using near-infrared spectroscopy (NIRS) to predict the age of Anopheles mosquitoes reared from wild larvae and a mixed age-wild adult population collected from pit traps after exposure to pyrethroids. The mosquitoes reared from wild larvae were estimated as ,7 or $7 d ol...

  16. The SOFIA/SAFIRE Far-Infrared Spectrometer: Highlighting Submillimeter Astrophysics and Technology

    Science.gov (United States)

    Benford, Dominic J.

    2009-01-01

    The Submillimeter and Far-InfraRed Experiment (SAFIRE) on the SOFIA airborne observatory is an imaging spectrometer for wavelengths between 28 microns and 440 microns. Our design is a dual-band long-slit grating spectrometer, which provides broadband (approx. 4000 km/s) observations in two lines simultaneously over a field of view roughly 10" wide by 320" long. The low backgrounds in spectroscopy require very sensitive detectors with noise equivalent powers of order 10(exp -18) W/square root of Hz. We are developing a kilopixel, filled detector array for SAFIRE in a 32 x 40 format. The detector consists of a transition edge sensor (TES) bolometer array, a per-pixel broadband absorbing backshort array, and a NIST SQUID multiplexer readout array. This general type of array has been used successfully in the GISMO instrument, so we extrapolate to the sensitivity needed for airborne spectroscopy. Much of the cryogenic, electronics, and software infrastructure for SAFIRE have been developed. I provide here an overview of the progress on SAFIRE.

  17. Wide-Field InfraRed Survey Telescope (WFIRST) slitless spectrometer: design, prototype, and results

    Science.gov (United States)

    Gong, Qian; Content, David A.; Dominguez, Margaret; Emmett, Thomas; Griesmann, Ulf; Hagopian, John; Kruk, Jeffrey; Marx, Catherine; Pasquale, Bert; Wallace, Thomas; Whipple, Arthur

    2016-07-01

    The slitless spectrometer plays an important role in the WFIRST mission for the survey of emission-line galaxies. This will be an unprecedented very wide field, HST quality 3D survey of emission line galaxies1. The concept of the compound grism as a slitless spectrometer has been presented previously. The presentation briefly discusses the challenges and solutions of the optical design, and recent specification updates, as well as a brief comparison between the prototype and the latest design. However, the emphasis of this paper is the progress of the grism prototype: the fabrication and test of the complicated diffractive optical elements and powered prism, as well as grism assembly alignment and testing. Especially how to use different tools and methods, such as IR phase shift and wavelength shift interferometry, to complete the element and assembly tests. The paper also presents very encouraging results from recent element tests to assembly tests. Finally we briefly touch the path forward plan to test the spectral characteristic, such as spectral resolution and response.

  18. The Mid-Infrared Instrument for the James Webb Space Telescope, VI: The Medium Resolution Spectrometer

    CERN Document Server

    Wells, Martyn; Glasse, Alistair; Wright, G S; Aitink-Kroes, Gabby; Azzollini, Ruyman; Beard, Steven; Brandl, B R; Gallie, Angus; Geers, V C; Glauser, A M; Hastings, Peter; Henning, Th; Jager, Rieks; Justtanont, K; Kruizinga, Bob; Lahuis, Fred; Lee, David; Martinez-Delgado, I; Martinez-Galarza, J R; Meijers, M; Morrison, Jane E; Mueller, Friedrich; Nakos, Thodori; O'Sullivan, Brian; Oudenhuysen, Ad; Parr-Burman, P; Pauwels, Evert; Rohloff, R -R; Schmalzl, Eva; Sykes, Jon; Thelen, M P; van Dishoeck, E F; Vandenbussche, Bart; Venema, Lars B; Visser, Huib; Waters, L B F M; Wright, David

    2015-01-01

    We describe the design and performance of the Medium Resolution Spectrometer (MRS) for the JWST-MIRI instrument. The MRS incorporates four coaxial spectral channels in a compact opto-mechanical layout that generates spectral images over fields of view up to 7.7 X 7.7 arcseconds in extent and at spectral resolving powers ranging from 1,300 to 3,700. Each channel includes an all-reflective integral field unit (IFU): an 'image slicer' that reformats the input field for presentation to a grating spectrometer. Two 1024 X 1024 focal plane arrays record the output spectral images with an instantaneous spectral coverage of approximately one third of the full wavelength range of each channel. The full 5 to 28.5 micron spectrum is then obtained by making three exposures using gratings and pass-band-determining filters that are selected using just two three-position mechanisms. The expected on-orbit optical performance is presented, based on testing of the MIRI Flight Model and including spectral and spatial coverage an...

  19. Dynamics and Evolution of SO2 Gas Condensation Around Prometheus-like Volcanic Plumes on Io as Seen by the Near Infrared Mapping Spectrometer

    Science.gov (United States)

    Doute, S.; Lopes-Gautier, R.; Smythe, W. D.; Kamp, L. W.; Carlson, R.

    2001-01-01

    Near Infrared Mapping Spectrometer data acquired during the I24, 25, and 27 Io's Fly-bys by Galileo are analyzed to map the SO2 frost abundance and granularity. This allows a better understanding of the dynamics and evolution of gas condensation around volcanic plumes. Additional information is contained in the original extended abstract.

  20. Non-collinear upconversion of incoherent light: designing infrared spectrometers and imaging systems

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Hu, Qi; Pedersen, Christian

    2014-01-01

    for each angle of propagation. Non-collinear phase matching has been an area of limited attention for many years due to inherent incompatibility with tightly focused laser beams typically used for most second order processes in order to achieve acceptable conversion efficiency. The development......Upconversion of incoherent mid-infrared radiation to near visible wavelengths, offers very attractive sensitivity compared to conventional means of infrared detection. Incoherent light, focused into a nonlinear crystal, results in noncollinear phase matching of a narrow range of wavelengths...... of periodically poled crystals have allowed for non-critical collinear phase matching of most wavelengths, virtually eliminating the need for non-collinear phase matching. When considering upconversion of thermal light, spectral radiance is limited due to the finite temperature of the Planck radiation source...

  1. The Mid-Infrared Instrument for the James Webb Space Telescope: IV. The Low Resolution Spectrometer

    CERN Document Server

    Kendrew, S; Bouchet, P; Amiaux, J; Azzolini, R; Bouwman, J; Chen, C; Dubreuil, D; Fischer, S; Glasse, A; Greene, T; Lagage, P -O; Lahuis, F; Ronayette, S; Wright, D; Wright, G S

    2015-01-01

    The Low Resolution Spectrometer of the MIRI, which forms part of the imager module, will provide R~100 long-slit and slitless spectroscopy from 5 to 12 micron. The design is optimised for observations of compact sources, such as exoplanet host stars. We provide here an overview of the design of the LRS, and its performance as measured during extensive test campaigns, examining in particular the delivered image quality, dispersion, and resolving power, as well as spectrophotometric performance, flatfield accuracy and the effects of fringing. We describe the operational concept of the slitless mode, which is optimally suited to transit spectroscopy of exoplanet atmospheres. The LRS mode of the MIRI was found to perform consistently with its requirements and goals.

  2. C/O abundance ratios, iron depletions, and infrared dust features in Galactic planetary nebulae

    CERN Document Server

    Delgado-Inglada, Gloria

    2014-01-01

    We study the dust present in 56 Galactic planetary nebulae (PNe) through their iron depletion factors, their C/O abundance ratios (in 51 objects), and the dust features that appear in their infrared spectra (for 33 objects). Our sample objects have deep optical spectra of good quality, and most of them also have ultraviolet observations. We use these observations to derive the iron abundances and the C/O abundance ratios in a homogeneous way for all the objects. We compile detections of infrared dust features from the literature and we analyze the available Spitzer/IRS spectra. Most of the PNe have C/O ratios below one and show crystalline silicates in their infrared spectra. The PNe with silicates have C/O < 1, with the exception of Cn 1-5. Most of the PNe with dust features related to C-rich environments (SiC or the 30 {\\mu}m feature usually associated to MgS) have C/O $\\gtrsim$ 0.8. PAHs are detected over the full range of C/O values, including 6 objects that also show silicates. Iron abundances are low...

  3. Using a near-infrared spectrometer to estimate the age of anopheles mosquitoes exposed to pyrethroids.

    Science.gov (United States)

    Sikulu, Maggy T; Majambere, Silas; Khatib, Bakar O; Ali, Abdullah S; Hugo, Leon E; Dowell, Floyd E

    2014-01-01

    We report on the accuracy of using near-infrared spectroscopy (NIRS) to predict the age of Anopheles mosquitoes reared from wild larvae and a mixed age-wild adult population collected from pit traps after exposure to pyrethroids. The mosquitoes reared from wild larvae were estimated as 8 d for both susceptible and resistant groups. The age structure of wild-collected mosquitoes was not significantly different for the pyrethroid-susceptible and pyrethroid-resistant mosquitoes (P = 0.210). Based on these findings, NIRS chronological age estimation technique for Anopheles mosquitoes may be independent of insecticide exposure and the environmental conditions to which the mosquitoes are exposed.

  4. Miniaturized infrared-spectrometers for monitoring oil condition in offshore wind turbines; Miniaturisierte Infrarot-Spektrometer zur Oelzustandsueberwachung in Offshore-Windkraftgetriebe

    Energy Technology Data Exchange (ETDEWEB)

    Wiesent, Benjamin R.; Dorigo, Daniel G.; Simsek, Oezlem; Koch, Alexander W. [Technische Univ. Muenchen (Germany). Lehrstuhl fuer Messsystem- und Sensortechnik

    2012-07-01

    Infrared-based oil condition sensors provide valuable information about the condition of gears and thus permit long-term planning of maintenance work. Currently available systems are mainly based on non-dispersive methods providing information about one single oil condition parameter only. In many cases they are even adapted to only one type of oil. Miniaturized infrared spectrometers offer the possibility to simultaneously acquire a wealth of relevant oil condition parameters and are also applicable to a broad range of oil types. In this paper we present a method for selecting an appropriate spectral apparatus based on a multivariate calibration. We also show and discuss limitations of the respective spectral apparatus in terms of spectral bandwidth, resolution, and SNR on the quality of spectral data analysis. In addition, the realization and measurement results of a miniaturized infrared spectrometer are shown based on a linear variable filter (LVF) for gear oil monitoring of offshore wind turbine gearboxes.

  5. Novel Fourier transform infrared spectrometer architecture based on cascaded Fabry-Perot interferometers

    Science.gov (United States)

    Eltagoury, Yomna M.; Sabry, Yasser M.; Khalil, Diaa A.

    2016-03-01

    In this work, we present a novel architecture for Fourier transform spectrometers based on cascaded low-finesse FP interferometers. One of the interferometers has fixed path length while the second is a scanning one using a relatively large stroke electrostatic comb-drive actuator. The fixed interferometer results in a spectrum modulation and, hence, a shifted version of the interferogram away from the point of the zero spacing between the two mirrors. The shifted interferogram can then be used with the Fourier transform algorithm to obtain the spectrum of the measured light. This cascaded FP configuration results in a simple arrangement of mirrors on a line, which makes it much tolerant to misalignment errors. The proposed configuration is implemented using the MEMS DRIE technology on an SOI wafer with a simple MEMS process flow without metallization or dielectric coating of the vertical optical surface. The fabricated compact structure is measured with both a laser source with narrow spectrum at 1550 nm and a wide spectrum source composed of an SLED and the ASE of a semiconductor optical amplifier source. The obtained results validate the concept of the new configuration.

  6. C/O abundance ratios, iron depletions, and infrared dust features in galactic planetary nebulae

    Energy Technology Data Exchange (ETDEWEB)

    Delgado-Inglada, Gloria; Rodríguez, Mónica, E-mail: gdelgado@astro.unam.mx, E-mail: mrodri@inaoep.mx [Instituto Nacional de Astrofísica, Óptica y Electrónica (INAOE), Apdo. Postal 51 y 216, 72000 Puebla, Pue. (Mexico)

    2014-04-01

    We study the dust present in 56 Galactic planetary nebulae (PNe) through their iron depletion factors, their C/O abundance ratios (in 51 objects), and the dust features that appear in their infrared spectra (for 33 objects). Our sample objects have deep optical spectra of good quality, and most of them also have ultraviolet observations. We use these observations to derive the iron abundances and the C/O abundance ratios in a homogeneous way for all the objects. We compile detections of infrared dust features from the literature and we analyze the available Spitzer/IRS spectra. Most of the PNe have C/O ratios below one and show crystalline silicates in their infrared spectra. The PNe with silicates have C/O <1, with the exception of Cn 1-5. Most of the PNe with dust features related to C-rich environments (SiC or the 30 μm feature usually associated to MgS) have C/O ≳ 0.8. Polycyclic aromatic hydrocarbons are detected over the full range of C/O values, including 6 objects that also show silicates. Iron abundances are low in all the objects, implying that more than 90% of their iron atoms are deposited into dust grains. The range of iron depletions in the sample covers about two orders of magnitude, and we find that the highest depletion factors are found in C-rich objects with SiC or the 30 μm feature in their infrared spectra, whereas some of the O-rich objects with silicates show the lowest depletion factors.

  7. Mid-Infrared Selected Quasars I: Virial Black Hole Mass and Eddington Ratios

    CERN Document Server

    Dai, Y Sophia; Bergeron, Jacqueline; Fazio, Giovanni G; Huang, Jia-Sheng; Wilkes, Belinda J; Willmer, Christopher N A; Omont, Alain; Papovich, Casey

    2014-01-01

    We provide a catalog of 391 mid-infrared-selected (MIR, 24$\\mu$m) broad-emission-line (BEL, type 1) quasars in the 22 deg$^2$ SWIRE Lockman Hole field. This quasar sample is selected in the MIR from Spitzer MIPS with $S_{\\rm 24} > 400\\mu$Jy, jointly with an optical magnitude limit of r (AB) $ 19.1$. We then investigate the continuum luminosity and line profiles of these MIR quasars, and estimate their virial black hole masses and the Eddington ratios. The SMBH mass shows evidence of downsizing, though the Eddington ratios remain constant at $1 < z < 4$. Compared to point sources in the same redshift range, extended sources at $z < 1$ show systematically lower Eddington ratios. The catalog and spectra are publicly available online.

  8. Using a near-infrared spectrometer to estimate the age of anopheles mosquitoes exposed to pyrethroids.

    Directory of Open Access Journals (Sweden)

    Maggy T Sikulu

    Full Text Available We report on the accuracy of using near-infrared spectroscopy (NIRS to predict the age of Anopheles mosquitoes reared from wild larvae and a mixed age-wild adult population collected from pit traps after exposure to pyrethroids. The mosquitoes reared from wild larvae were estimated as <7 or ≥7 d old with an overall accuracy of 79%. The age categories of Anopheles mosquitoes that were not exposed to the insecticide papers were predicted with 78% accuracy whereas the age categories of resistant, susceptible and mosquitoes exposed to control papers were predicted with 82%, 78% and 79% accuracy, respectively. The ages of 85% of the wild-collected mixed-age Anopheles were predicted by NIRS as ≤8 d for both susceptible and resistant groups. The age structure of wild-collected mosquitoes was not significantly different for the pyrethroid-susceptible and pyrethroid-resistant mosquitoes (P = 0.210. Based on these findings, NIRS chronological age estimation technique for Anopheles mosquitoes may be independent of insecticide exposure and the environmental conditions to which the mosquitoes are exposed.

  9. Mid-Infrared Spectroscopy of Uranus from the Spitzer Infrared Spectrometer: 1. Determination of the Mean Temperature Structure of the Upper Troposphere and Stratosphere

    CERN Document Server

    Orton, Glenn S; Moses, Julianne I; Mainzer, Amy K; Hines, Dean; Hammel, Heidi B; Martin-Torres, F Javier; Burgdorf, Martin; Merlet, Cecile; Line, Michael R

    2014-01-01

    On 2007 December 16-17, spectra were acquired of the disk of Uranus by the Spitzer Infrared Spectrometer (IRS) when its equator was close to the sub-earth point. This spectrum provides the highest-resolution broad-band spectrum ever obtained for Uranus from space, allowing a determination of the disk-averaged temperature and molecule composition to a greater degree of accuracy than ever before. The temperature profiles derived from the Voyager radio occultation experiments that match these data best are those that assume a high abundance of methane in the deep atmosphere, but none of these models provides a satisfactory fit over the full spectral range. This be the result of spatial differences between global and low-latitudinal regions, changes in time, missing continuum opacity sources such as stratospheric hazes or unknown tropospheric constituents, or undiagnosed systematic problems with either the radio-occultation or the Spitzer IRS data sets. The spectrum is compatible with the stratospheric temperatur...

  10. CLOUD AND HAZE IN THE WINTER POLAR REGION OF TITAN OBSERVED WITH VISUAL AND INFRARED MAPPING SPECTROMETER ON BOARD CASSINI

    Energy Technology Data Exchange (ETDEWEB)

    Rannou, P. [GSMA, UMR CNRS 7331, Universite de Reims Champagne-Ardenne (France); Le Mouelic, S. [LPGN, UMR CNRS 6112, Universite de Nantes (France); Sotin, C. [JPL, California Institute of Technology, PA (United States); Brown, R. H., E-mail: pascal.rannou@univ-reims.fr [LPL, University of Arizona, Tucson, AZ (United States)

    2012-03-20

    A large cloud in the north polar region of Titan was first observed by the Visual and Infrared Mapping Spectrometer (VIMS) in 2005 and then in 2006. This cloud, confined beyond the latitude 62 Degree-Sign N, is surrounded by a mixture of aerosol and mist probably lying in the low stratosphere and troposphere. Subsequent images of this region of Titan show a gradual vanishing of this cloud which was reported previously. In this paper, we characterize the physical properties of this cloud, haze, and mist as well as their time evolutions. We note several details on the images such as a secondary cloud above the main cloud and latitudes beyond 70 Degree-Sign N. We also show that the cloud disappearance leaves the polar region poorly loaded in aerosols, yielding an annular zone of aerosols between 50 Degree-Sign N and 65 Degree-Sign N. Our analysis suggests that this structure observed by VIMS in the near-IR is an annular structure observed by ISS on board Voyager one Titan year ago in 1980.

  11. Using an extractive Fourier transform infrared spectrometer for improving cleanroom air quality in a semiconductor manufacturing plant.

    Science.gov (United States)

    Li, Shou-Nan; Chang, Chin-Ta; Shih, Hui-Ya; Tang, Andy; Li, Alen; Chen, Yin-Yung

    2003-01-01

    A mobile extractive Fourier transform infrared (FTIR) spectrometer was successfully used to locate, identify, and quantify the "odor" sources inside the cleanroom of a semiconductor manufacturing plant. It was found that ozone (O(3)) gas with a peak concentration of 120 ppm was unexpectedly releasing from a headspace of a drain for transporting used ozonized water and that silicon tetrafluoride (SiF(4)) with a peak concentration of 3 ppm was off-gassed from silicon wafers after dry-etching processing. When the sources of the odors was pinpointed by the FTIR, engineering control measures were applied. For O(3) control, a water-sealed pipeline was added to prevent the O(3) gas (emitting from the ozonized water) from entering the mixing unit. A ventilation system also was applied to the mixing unit in case of O(3) release. For SiF(4) mitigation, before the wafer-out chamber was opened, N(2) gas with a flow rate of 150 L/min was used for 100 sec to purge the wafer-out chamber, and a vacuum system was simultaneously activated to pump away the purging N(2). The effectiveness of the control measures was assured by using the FTIR. In addition, the FTIR was used to monitor the potential hazardous gas emissions during preventative maintenance of the semiconductor manufacturing equipment.

  12. Optical Design of a Broadband Infrared Spectrometer for Bunch Length Measurement at the Linac Coherent Light Source

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Kiel; /SLAC

    2012-09-07

    The electron pulses generated by the Linac Coherent Light Source at the SLAC National Accelerator Laboratory occur on the order of tens of femtoseconds and cannot be directly measured by conventional means. The length of the pulses can instead be reconstructed by measuring the spectrum of optical transition radiation emitted by the electrons as they move toward a conducting foil. Because the emitted radiation occurs in the mid-infrared from 0.6 to 30 microns a novel optical layout is required. Using a helium-neon laser with wavelength 633 nm, a series of gold-coated off-axis parabolic mirrors were positioned to direct a beam through a zinc selenide prism and to a focus at a CCD camera for imaging. Constructing this layout revealed a number of novel techniques for reducing the aberrations introduced into the system by the off-axis parabolic mirrors. The beam had a recorded radius of less than a millimeter at its final focus on the CCD imager. This preliminary setup serves as a model for the spectrometer that will ultimately measure the LCLS electron pulse duration.

  13. Applicability of a Diffuse Reflectance Infrared Fourier Transform handheld spectrometer to perform in situ analyses on Cultural Heritage materials.

    Science.gov (United States)

    Arrizabalaga, Iker; Gómez-Laserna, Olivia; Aramendia, Julene; Arana, Gorka; Madariaga, Juan Manuel

    2014-08-14

    This work studies the applicability of a Diffuse Reflectance Infrared Fourier Transform handheld device to perform in situ analyses on Cultural Heritage assets. This portable diffuse reflectance spectrometer has been used to characterise and diagnose the conservation state of (a) building materials of the Guevara Palace (15th century, Segura, Basque Country, Spain) and (b) different 19th century wallpapers manufactured by the Santa Isabel factory (Vitoria-Gasteiz, Basque Country, Spain) and by the well known Dufour and Leroy manufacturers (Paris, France), all of them belonging to the Torre de los Varona Castle (Villanañe, Basque Country, Spain). In all cases, in situ measurements were carried out and also a few samples were collected and measured in the laboratory by diffuse reflectance spectroscopy (DRIFT) in order to validate the information obtained by the handheld instrument. In the analyses performed in situ, distortions in the diffuse reflectance spectra can be observed due to the presence of specular reflection, showing the inverted bands caused by the Reststrahlen effect, in particular on those IR bands with the highest absorption coefficients. This paper concludes that the results obtained in situ by a diffuse reflectance handheld device are comparable to those obtained with laboratory diffuse reflectance spectroscopy equipment and proposes a few guidelines to acquire good spectra in the field, minimising the influence caused by the specular reflection.

  14. Infrared absorption of gaseous CH2BrOO detected with a step-scan Fourier-transform absorption spectrometer.

    Science.gov (United States)

    Huang, Yu-Hsuan; Lee, Yuan-Pern

    2014-10-28

    CH2BrOO radicals were produced upon irradiation, with an excimer laser at 248 nm, of a flowing mixture of CH2Br2 and O2. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record temporally resolved infrared (IR) absorption spectra of reaction intermediates. Transient absorption with origins at 1276.1, 1088.3, 961.0, and 884.9 cm(-1) are assigned to ν4 (CH2-wagging), ν6 (O-O stretching), ν7 (CH2-rocking mixed with C-O stretching), and ν8 (C-O stretching mixed with CH2-rocking) modes of syn-CH2BrOO, respectively. The assignments were made according to the expected photochemistry and a comparison of observed vibrational wavenumbers, relative IR intensities, and rotational contours with those predicted with the B3LYP/aug-cc-pVTZ method. The rotational contours of ν7 and ν8 indicate that hot bands involving the torsional (ν12) mode are also present, with transitions 7(0)(1)12(v)(v) and 8(0)(1)12(v)(v), v = 1-10. The most intense band (ν4) of anti-CH2BrOO near 1277 cm(-1) might have a small contribution to the observed spectra. Our work provides information for directly probing gaseous CH2BrOO with IR spectroscopy, in either the atmosphere or laboratory experiments.

  15. Infrared absorption of gaseous CH2BrOO detected with a step-scan Fourier-transform absorption spectrometer

    Science.gov (United States)

    Huang, Yu-Hsuan; Lee, Yuan-Pern

    2014-10-01

    CH2BrOO radicals were produced upon irradiation, with an excimer laser at 248 nm, of a flowing mixture of CH2Br2 and O2. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record temporally resolved infrared (IR) absorption spectra of reaction intermediates. Transient absorption with origins at 1276.1, 1088.3, 961.0, and 884.9 cm-1 are assigned to ν4 (CH2-wagging), ν6 (O-O stretching), ν7 (CH2-rocking mixed with C-O stretching), and ν8 (C-O stretching mixed with CH2-rocking) modes of syn-CH2BrOO, respectively. The assignments were made according to the expected photochemistry and a comparison of observed vibrational wavenumbers, relative IR intensities, and rotational contours with those predicted with the B3LYP/aug-cc-pVTZ method. The rotational contours of ν7 and ν8 indicate that hot bands involving the torsional (ν12) mode are also present, with transitions 7_0^1 12_v^v and 8_0^1 12_v^v, v = 1-10. The most intense band (ν4) of anti-CH2BrOO near 1277 cm-1 might have a small contribution to the observed spectra. Our work provides information for directly probing gaseous CH2BrOO with IR spectroscopy, in either the atmosphere or laboratory experiments.

  16. Observations in the Saturn system during approach and orbital insertion, with Cassini's visual and infrared mapping spectrometer (VIMS)

    Science.gov (United States)

    Brown, R.H.; Baines, K.H.; Bellucci, G.; Buratti, B.J.; Capaccioni, F.; Cerroni, P.; Clark, R.N.; Coradini, A.; Cruikshank, D.P.; Drossart, P.; Formisano, V.; Jaumann, R.; Langevin, Y.; Matson, D.L.; McCord, T.B.; Mennella, V.; Nelson, R.M.; Nicholson, P.D.; Sicardy, B.; Sotin, C.; Baugh, N.; Griffith, C.A.; Hansen, G.B.; Hibbitts, C.A.; Momary, T.W.; Showalter, M.R.

    2006-01-01

    The Visual and Infrared Mapping Spectrometer observed Phoebe, Iapetus, Titan and Saturn's rings during Cassini's approach and orbital insertion. Phoebe's surface contains water ice, CO2, and ferrous iron. lapetus contains CO2 and organic materials. Titan's atmosphere shows methane fluorescence, and night-side atmospheric emission that may be CO2 and CH3D. As determined from cloud motions, the winds at altitude 25-30 km in the south polar region of Titan appear to be moving in a prograde direction at velocity ???1 m s-1. Circular albedo features on Titan's surface, seen at 2.02 ??m, may be palimpsests remaining from the rheological adjustment of ancient impact craters. As such, their long-term persistence is of special interest in view of the expected precipitation of liquids and solids from the atmosphere. Saturn's rings have changed little in their radial structure since the Voyager flybys in the early 1980s. Spectral absorption bands tentatively attributed to Fe2+ suggest that iron-bearing silicates are a source of contamination of the C ring and the Cassini Division. ?? ESO 2006.

  17. Thermal Emission Variability of Zamama, Culann and Tupan on Io Using Galileo Near-Infrared Mapping Spectrometer (NIMS) Data

    Science.gov (United States)

    Ennis, M. E.; Davies, A. G.

    2005-01-01

    The Jovian satellite Io is the most volcanically active body in the Solar System. Previous analyses [e.g., 1-4] indicate the presence of high-temperature silicate volcanism on Io, similar to silicate volcanism occurring on Earth. Instruments onboard the Galileo spacecraft, especially the Near Infrared Mapping Spectrometer (NIMS) and the Solid State Imager (SSI), provided much data of Io s active volcanoes throughout the duration of the Galileo mission (June 1996-September 2003). NIMS data is particularly sensitive to thermal emission from active and cooling lava over cooling times of seconds to a few years. The objective of this ongoing study of Io s volcanism is to determine the variability of thermal emission from volcanoes on Io s surface, in order to better understand the styles of eruption, and to constrain the volumes of material erupted. Ultimately, this will help to constrain the contribution of active volcanism to Io s thermal budget. Data have been analyzed for the volcano Zamama, located at 173 W, 21 N, and the power output of Zamama, the volumes of lava being erupted, and the eruption rate determined. Culann and Tupan have also been analysed in this way. This abstract primarily concentrates on Zamama.

  18. [Miniature near-infrared fibre optic spectrometer for the quantitative detection of protein and fat in milk powder].

    Science.gov (United States)

    Zhang, Zhong-Wei; Wen, Zhi-Yu; Zeng, Tian-Ling; Wei, Kang-Lin; Liang, Yu-Qian

    2013-07-01

    The method based on miniature near-infrared spectrometer combined with Y fiber optic probe to detect the protein and fat in milk powder by diffuse reflectance spectroscopy in the wavelength range of 900-1 700 nm was proposed. By selecting the appropriate spectral bands, the correction models of protein and fat were established with partial least squares algorithm using Unscrambler 9.7 Chemometrics software. The determination coefficients R2 of the correction modes are 0.987 and 0.986 for protein and fat respectively, and the root mean square errors RMSEC are 0.385 and 0.419 respectively. Using these correction models to predict the protein and fat contents with 30 sets of forecast sample data, the prediction standard deviation is SEP(Protein) = 0.751 for protein, and is SEP(Fat) = 1.109 for fat. The results indicate that these correction models have prediction capability with unknown samples and meet the on line requirements.

  19. A Multi-Channel THz and Infrared Spectrometer for Femtosecond Electron Bunch Diagnostics by Single-Shot Spectroscopy of Coherent Radiation

    CERN Document Server

    Wesch, S; Behrens, C; Delsim-Hashemi, H; Schmüser, P

    2011-01-01

    The high peak current required in free-electron lasers (FELs) is realized by longitudinal compression of the electron bunches to sub-picosecond length. In this paper, a frequency-domain diagnostic method is described that is capable of resolving structures in the femtosecond regime. A novel in-vacuum spectrometer has been developed for spectroscopy of coherent radiation in the THz and infrared range. The spectrometer is equipped with five consecutive dispersion gratings and 120 parallel readout channels; it can be operated either in short wavelength mode (5 - 44 um) or in long wavelength mode (45 - 430 um). Fast parallel readout permits the spectroscopy of coherent radiation from single electron bunches. Test measurements at the soft X-ray free-electron laser FLASH, using coherent transition radiation, demonstrate excellent performance of the spectrometer. The high sensitivity down to a few micrometers allows study of short bunch features caused for example by microbunching effects in magnetic chicanes. The d...

  20. Mimir: A Near-Infrared Wide-Field Imager, Spectrometer and Polarimeter

    Science.gov (United States)

    Clemens, D. P.; Sarcia, D.; Grabau, A.; Tollestrup, E. V.; Buie, M. W.; Dunham, E.; Taylor, B.

    2007-12-01

    Mimir, a new facility-class near-infrared instrument for the 1.8 m Perkins telescope on Anderson Mesa outside Flagstaff, Arizona, was commissioned and has been operating for three years. Mimir is multifunction, performing wide-field (F/5) and narrow-field (F/17) imaging, long-slit spectroscopy, and imaging polarimetry. The F/5 mode images at 0.59" per pixel onto the 1024 × 1024 pixel ALADDIN III InSb array detector, giving a 10' × 10' field of view. In the F/17 mode, the plate scale is 0.18" per pixel. Optically, Mimir is a refractive reimager for the F/17.5 Perkins beam. A six-lens collimator produces an achromatic 25 mm pupil, which is imaged by a five-lens camera (F/5), a four-lens camera (F/17), or a two-lens pupil viewer onto the detector. Three filter wheels precede the pupil, one follows the pupil. The wheels contain a rotating half-wave plate, broadband filters, narrowband filters, grisms, long-pass filters, a wire grid, and thermal IR blockers. The first telescope focus is within Mimir, where a slit and decker unit, consisting of two linear motion cars, selects one of 13 slit scenes. The slit and decker cars, the four filter wheels, the half-wave plate rotation, and the camera selector are all driven by stepper motors within the cold vacuum space. Cooling is provided by a CTI 1050 two-stage, closed-cycle helium refrigerator, keeping the optics, filters, and internal surfaces between 65 and 75 K and the detector at 33.5 K. Switching between Mimir's different modes takes only a few seconds, making it a versatile tool for conducting a wide range of investigations and for quickly reacting to changing observing conditions. Mimir on the Perkins telescope achieves imaging sensitivities 2-4 mag deeper than 2MASS, moderate resolution (R ˜ 700) JHK spectra of virtually any 2MASS source, high-precision wide-field imaging polarimetry, and L' and M' band imaging and spectroscopy.

  1. [A review of Dyson optical system in the measure of infrared imaging spectrum].

    Science.gov (United States)

    Liu, Yu-juan; Tang, Yu-guo; Bayanheshig; Cui, Ji-cheng; Qi, Xiang-dong

    2012-02-01

    It is difficult for the traditional infrared imaging spectrometers to satisfy the requirement of high signal to noise ratio (SNR) and small size simultaneously. The new infrared remote sensing imaging spectrometers based on Dyson concentric optical configuration have the advantages of high aperture, high SNR, simpleness small volume and low weight. The Dyson imaging spectrometers can achieve high SNR, which is difficult for the traditional imaging spectrometers for infrared imaging spectrum. The present review introduces the beginning, the development and the present research of the Dyson imaging spectrometers, especially illustrates the principle of Dyson concentric spectrometer, difficulty during its manufacture and the application in the high-performance infrared remote sensing imaging spectrometers, providing a reference for the high-performance research of infrared remote sensing imaging spectrometers.

  2. For geological investigations with airborne thermal infrared multispectral images: Transfer of calibration from laboratory spectrometer to TIMS as alternative for removing atmospheric effects

    Science.gov (United States)

    Edgett, Kenneth S.; Anderson, Donald L.

    1995-01-01

    This paper describes an empirical method to correct TIMS (Thermal Infrared Multispectral Scanner) data for atmospheric effects by transferring calibration from a laboratory thermal emission spectrometer to the TIMS multispectral image. The method does so by comparing the laboratory spectra of samples gathered in the field with TIMS 6-point spectra for pixels at the location of field sampling sites. The transference of calibration also makes it possible to use spectra from the laboratory as endmembers in unmixing studies of TIMS data.

  3. Details of assessing information content of the Tropospheric Infrared Mapping Spectrometers (TIMS) GEO-CAPE instrument concept when applied for several infrared ozone bands

    Science.gov (United States)

    Rairden, R. L.; Kumer, J. B.; Roche, A. E.; Desouza-Machado, S. G.; Chatfield, R. B.; Blatherwick, R.

    2009-12-01

    With support of NASA ESTO Instrument Incubator Program (IIP) Tropospheric Infrared Mapping Spectrometers (TIMS) have been demonstrated for multi-layer retrieval of Atmospheric CO. Two TIMS units operating in spectral regions centered at 2.33 and 4.68 µm were developed for this demonstration. Here we present the details of scaling the characteristics of the demonstration measurements including spectral range, sample spacing and resolution, and noise per sample to the scenario of GEO-CAPE mission and to several additional wave length regions. This includes the detail of expanding to more than two spectral regions. It includes an example of scaling the noise as demonstrated by the demonstration measurements to the space case, and to other spectral regions. Common with our oral presentation, methods based on these scaled instrument characteristics for estimating vertical information content are reviewed. The methods are applied and estimated vertical information content of measurements in ozone bands near 9.4, 4.7, 3.6 and 3.3 µm and in various combinations of these bands is presented. A simple simultaneous retrieval of humidity and ozone from atmospheric spectral absorption data in the 3.3 and 3.6 µm regions that was obtained by a solar viewing FTS is briefly presented. This is partially analogous to the retrieval of ozone from the earth’s surface diffuse reflection of sunlight as viewed from space. It supports the premise that these space borne measurements can contribute to the quality of the GEO-CAPE ozone measurements.

  4. Search for and limits on plume activity on Mimas, Tethys, and Dione with the Cassini Visual Infrared Mapping Spectrometer (VIMS)

    Science.gov (United States)

    Buratti, B.J.; Faulk, S.P.; Mosher, J.; Baines, K.H.; Brown, R.H.; Clark, R.N.; Nicholson, P.D.

    2011-01-01

    Cassini Visual Infrared Mapping Spectrometer (VIMS) observations of Mimas, Tethys, and Dione obtained during the nominal and extended missions at large solar phase angles were analyzed to search for plume activity. No forward scattered peaks in the solar phase curves of these satellites were detected. The upper limit on water vapor production for Mimas and Tethys is one order of magnitude less than the production for Enceladus. For Dione, the upper limit is two orders of magnitude less, suggesting this world is as inert as Rhea (Pitman, K.M., Buratti, B.J., Mosher, J.A., Bauer, J.M., Momary, T., Brown, R.H., Nicholson, P.D., Hedman, M.M. [2008]. Astrophys. J. Lett. 680, L65-L68). Although the plumes are best seen at ???2.0. ??m, Imaging Science Subsystem (ISS) Narrow Angle Camera images obtained at the same time as the VIMS data were also inspected for these features. None of the Cassini ISS images shows evidence for plumes. The absence of evidence for any Enceladus-like plumes on the medium-sized saturnian satellites cannot absolutely rule out current geologic activity. The activity may below our threshold of detection, or it may be occurring but not captured on the handful of observations at large solar phase angles obtained for each moon. Many VIMS and ISS images of Enceladus at large solar phase angles, for example, do not contain plumes, as the active "tiger stripes" in the south pole region are pointed away from the spacecraft at these times. The 7-year Cassini Solstice Mission is scheduled to gather additional measurements at large solar phase angles that are capable of revealing activity on the saturnian moons. ?? 2011 Elsevier Inc.

  5. Mapped minerals at Questa, New Mexico, using airborne visible-infrared imaging spectrometer (AVIRIS) data -- Preliminary report

    Science.gov (United States)

    Livo, K. Eric; Clark, Roger N.

    2002-01-01

    This preliminary study for the First Quarterly Report has spectrally mapped hydrothermally altered minerals useful in assisting in assessment of water quality of the Red River. Airborne Visible-Infrared Imaging Spectrometer (AVIRIS) data was analyzed to characterize mined and unmined ground at Questa, New Mexico. AVIRIS data covers the Red River drainage north of the river, from between the town of Questa on the west, to east of the town of Red River. The data was calibrated and analyzed using U.S. Geological Survey custom software and spectral mineral library. AVIRIS data was tested for spectral features that matched similar features in the spectral mineral library. Goodness-of-fit and band-depth were calculated for each comparison of spectral features and used to identify surface mineralogy. Mineral distribution, mineral associations, and AVIRIS pixel spectra were examined. Mineral maps show the distribution of iron hydroxides, iron sulfates, clays, micas, carbonates, and other minerals. Initial results show a system of alteration suites that overprint each other. Quartz-sericite-pyrite (QSP) alteration grading out to propylitic alteration (epidote and calcite) was identified at the Questa Mine (molybdenum porphyry) and a similar alteration pattern was mapped at the landslide (?scar?) areas. Supergene weathering overprints the altered rock, as shown by jarosite, kaolinite, and gypsum. In the spectral analysis, hydrothermally altered ground appears to be more extensive at the unmined Goat Hill Gulch and the mined ground, than the ?scars? to the east. Though the ?scars? have similar overall altered mineral suites, there are differences between the ?scars? in sericite, kaolinite, jarosite, gypsum, and calcite abundance. Fieldwork has verified the results at the central unmined ?scar? areas.

  6. Fast In Situ Airborne Measurement of Ammonia Using a Mid-Infrared Off-Axis ICOS Spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Leen, J. Brian; Yu, Xiao-Ying; Gupta, Manish; Baer, Douglas S.; Hubbe, John M.; Kluzek, Celine D.; Tomlinson, Jason M.; Hubbell, Mike R.

    2013-08-23

    A new ammonia (NH3) analyzer was developed based on off-axis integrated cavity output spectroscopy. Its feasibility was demonstrated by making tropospheric measurements in flights aboard the Department of Energy Gulfstream-1 aircraft. The ammonia analyzer consists of an optical cell, quantum-cascade laser, gas sampling system, control and data acquisition electronics, and analysis software. The NH3 mixing ratio is determined from high-resolution absorption spectra obtained by tuning the laser wavelength over the NH3 fundamental vibration band near 9.67 μm. Excellent linearity is obtained over a wide dynamic range (0–101 ppbv) with a response rate (1/e) of 2 Hz and a precision of ±90 pptv (1σ in 1 s). Two research flights were conducted over the Yakima Valley in Washington State. In the first flight, the ammonia analyzer was used to identify signatures of livestock from local dairy farms with high vertical and spatial resolution under low wind and calm atmospheric conditions. In the second flight, the analyzer captured livestock emission signals under windy conditions. Finally, our results demonstrate that this new ammonia spectrometer is capable of providing fast, precise, and accurate in situ observations of ammonia aboard airborne platforms to advance our understanding of atmospheric compositions and aerosol formation.

  7. Visible–Near-Infrared Spectroscopy Can Predict the Clay/Organic Carbon and Mineral Fines/Organic Carbon Ratios

    DEFF Research Database (Denmark)

    Hermansen, Cecilie; Knadel, Maria; Møldrup, Per;

    2016-01-01

    The ratios of mineral fines (... of preferential flow, water repellency, and chemical adsorption. Conventional texture and OC measurements are time consuming and expensive, and visible–near-infrared (vis-NIR) spectroscopy may provide a fast and inexpensive alternative for obtaining the n- and m-ratios. In this study, a total of 480 soil samples...

  8. Efficacy of using multiple open-path Fourier transform infrared (OP-FTIR) spectrometers in an odor emission episode investigation at a semiconductor manufacturing plant.

    Science.gov (United States)

    Tsao, Yung-Chieh; Wu, Chang-Fu; Chang, Pao-Erh; Chen, Shin-Yu; Hwang, Yaw-Huei

    2011-08-01

    This study evaluated the efficacy of simultaneously employing three open-path Fourier transform infrared (OP-FTIR) spectrometers with 3-day consecutive monitoring, using an odor episode as an example. The corresponding monitoring paths were allocated among the possible emission sources of a semiconductor manufacturing plant and the surrounding optoelectronic and electronic-related factories, which were located in a high-tech industrial park. There was a combined total odor rate of 43.9% for the three monitoring paths, each comprised of 736 continuous 5-minute monitoring records and containing detectable odor compounds, such as ammonia, ozone, butyl acetate, and propylene glycol monomethyl ether acetate (PGMEA). The results of the logistic regression model indicated that the prevailing south wind and the OP-FTIR monitoring path closest to the emission source in down-wind direction resulted in a high efficacy for detecting odorous samples with odds ratios (OR) of 3.8 (95% confidence interval (CI): 2.9-5.0) and 5.1 (95% CI: 3.6-7.2), respectively. Meanwhile, the odds ratio for detecting ammonia odorous samples was 7.5 for Path II, which was downwind closer to the possible source, as compared to Path III, downwind far away from the possible source. PGMEA could not be monitored at Path II but could be at Path III, indicating the importance of the monitoring path and flow ejection velocities inside the stacks on the monitoring performance of OP-FTIR. Besides, an odds ratio of 5.1 for odorous sample detection was obtained with south prevailing wind comprising 65.0% of the monitoring time period. In general, it is concluded that OP-FTIR operated with multiple paths simultaneously shall be considered for investigation on relatively complicated episodes such as emergency of chemical release, multiple-source emission and chemical monitoring for odor in a densely populated plant area to enhance the efficacy of OP-FTIR monitoring. Copyright © 2011 Elsevier B.V. All rights

  9. Analysis on Infrared Spectrometer System Specification for Atmospheric Composition Detecting%大气成分探测红外光谱仪系统指标分析

    Institute of Scientific and Technical Information of China (English)

    齐卫红; 尉昊赟; 阴丽娜

    2013-01-01

    由温室气体引起的全球气候变化和环境污染已经受到全世界的广泛关注。进行大气成分探测,对于更好地了解温室效应产生的细节、大气分子的光化学性质对臭氧层的影响以及大气污染机制都具有重要意义。由于大气成分种类较多,其红外吸收光谱密集且复杂,因此大气成分探测仪器需要有较高的光谱分辨能力和信噪比。文章进行了大气成分探测的总体指标需求分析,并据此确定了大气成分探测红外光谱仪的主要技术指标。为了满足指标要求,该光谱仪采用傅里叶变换红外光谱仪的总体方案。通过仪器性能影响因素分析和系统优化,使得该仪器的最终设计结果满足指标要求。%Global climate change and environmental pollution caused by greenhouse gases has received ex-tensive attention all over the world. Detecting atmospheric composition is especial important for a better under-standing of the detail of the green house effect, the influences on the ozonosphere of atmospheric photochemistry, as well as the mechanism of the air pollution. Because the kinds of atmospheric composition and their infrared absorption spectral lines are very dense and complex, atmospheric composition instruments need to have high spectral resolution and high signal-to-noise ratio (SNR). This report briefly introduced the specification require-ment analysis for space atmospheric detecting, and the main specifications of the instrument for space atmospher-ic detecting are defined. For realizing the main specifications, the overall scheme of the instrument adopts Fourier Transform Infrared Spectrometer (FTIRS). The final design of the instrument meets the specifications through influence factor analysis and system optimization. Finally, the measurement result was given.

  10. Influence of spectral resolution, spectral range and signal-to-noise ratio of Fourier transform infra-red spectra on identification of high explosive substances.

    Science.gov (United States)

    Banas, Krzysztof; Banas, Agnieszka M; Heussler, Sascha P; Breese, Mark B H

    2018-01-05

    In the contemporary spectroscopy there is a trend to record spectra with the highest possible spectral resolution. This is clearly justified if the spectral features in the spectrum are very narrow (for example infra-red spectra of gas samples). However there is a plethora of samples (in the liquid and especially in the solid form) where there is a natural spectral peak broadening due to collisions and proximity predominately. Additionally there is a number of portable devices (spectrometers) with inherently restricted spectral resolution, spectral range or both, which are extremely useful in some field applications (archaeology, agriculture, food industry, cultural heritage, forensic science). In this paper the investigation of the influence of spectral resolution, spectral range and signal-to-noise ratio on the identification of high explosive substances by applying multivariate statistical methods on the Fourier transform infra-red spectral data sets is studied. All mathematical procedures on spectral data for dimension reduction, clustering and validation were implemented within R open source environment. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. Quantitative investigations of geologic surfaces utilizing airborne visible/infrared imaging spectrometer (AVIRIS) and polarimetric radar (AIRSAR) data for Death Valley, California

    Science.gov (United States)

    Kierein-Young, Kathryn S.; Kruse, Fred A.

    1991-01-01

    Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and polarimetric radar (AIRSAR) data were collected over Death Valley, California, USA, in September 1989. These two data sets were used to quantitatively characterize both the mineralogy and surface structure of the valley floor. Field mapping and characterization of the salt flats across the valley identified 16 separate units. The AVIRIS data were calibrated using the 'empirical line' method, and spectra extracted for the 16 units. A water vapor map was generated from the AVIRIS data and showed spatial variations in its distribution due to evaporation of surface water. Unmixing of the 16 spectral units produced maps of endmember abundance.

  12. Quantitative investigations of geologic surfaces utilizing airborne visible/infrared imaging spectrometer (AVIRIS) and polarimetric radar (AIRSAR) data for Death Valley, California

    Science.gov (United States)

    Kierein-Young, Kathryn S.; Kruse, Fred A.

    1991-01-01

    Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and polarimetric radar (AIRSAR) data were collected over Death Valley, California, USA, in September 1989. These two data sets were used to quantitatively characterize both the mineralogy and surface structure of the valley floor. Field mapping and characterization of the salt flats across the valley identified 16 separate units. The AVIRIS data were calibrated using the 'empirical line' method, and spectra extracted for the 16 units. A water vapor map was generated from the AVIRIS data and showed spatial variations in its distribution due to evaporation of surface water. Unmixing of the 16 spectral units produced maps of endmember abundance.

  13. Mars Atmospheric Escape Recorded by H, C and O Isotope Ratios in Carbon Dioxide and Water Measured by the Sam Tunable Laser Spectrometer on the Curiosity Rover

    Science.gov (United States)

    Webster, C. R.; Mahaffy, P. R.; Leshin, L. A.; Atreya, S. K.; Flesch, G. J.; Stern, J.; Christensen, L. E.; Vasavada, A. R.; Owen, T.; Niles, P. B.; Jones, J. H.; Franz, H.

    2013-01-01

    Stable isotope ratios in C, H, N, O and S are powerful indicators of a wide variety of planetary geophysical processes that can identify origin, transport, temperature history, radiation exposure, atmospheric escape, environmental habitability and biological activity [2]. For Mars, measurements to date have indicated enrichment in all the heavier isotopes consistent with atmospheric escape processes, but with uncertainty too high to tie the results with the more precise isotopic ratios achieved from SNC meteoritic analyses. We will present results to date of H, C and O isotope ratios in CO2 and H2O made to high precision (few per mil) using the Tunable Laser Spectrometer (TLS) that is part of the Sample Analysis at Mars (SAM) instrument suite on MSL s Curiosity Rover.

  14. High Precision 2.0 μm Photoacoustic Spectrometer for Determination of the ^{13}CO_{2}/^{12}CO_{2} Isotope Ratio

    Science.gov (United States)

    Reed, Zachary; Hodges, Joseph T.

    2017-06-01

    We have developed a portable photoacoustic spectrometer for high precision measurements of the ^{13}CO_{2}/^{12}CO_{2} isotope ratio and the absolute molar concentration of each isotope. The spectrometer extends on our previous work at 1.57 μm [1], and now employs two separate intensity modulated distributed feedback lasers and a fiber amplifier, operating in the 2.0 μm wavelength region. Each DFB is selected to probe individual spectrally isolated ro-vibrational transitions for ^{12}CO_{2} and ^{13}CO_{2}. The spectrometer is actively temperature controlled, mitigating variations in the two spectral line intensities and the temperature dependent system response. For measurements of ambient concentrations of carbon dioxide at nominally natural abundance in dry air, we demonstrate a measurement precision of 140 ppb for ^{12}CO_{2} with a 1 s averaging time and 10 ppb for ^{13}CO_{2} with a 60 s averaging time. Precision in δ13C of better than 0.1 permil is demonstrated. The analyzer response is calibrated in terms of certified gas mixtures and compared to characterization by cavity ringdown spectroscopy. We also investigate how water vapor affects the photoacoustic signals by promoting collisional relaxation for each isotope. [1] Z.D. Reed, B. Sperling, et al. App. Phys. B. 117, 645-657, 2014

  15. A multi-channel THz and infrared spectrometer for femtosecond electron bunch diagnostics by single-shot spectroscopy of coherent radiation

    Energy Technology Data Exchange (ETDEWEB)

    Wesch, Stephan; Schmidt, Bernhard; Behrens, Christopher; Delsim-Hashemi, Hossein; Schmueser, Peter

    2011-08-15

    The high peak current required in free-electron lasers (FELs) is realized by longitudinal compression of the electron bunches to sub-picosecond length. In this paper, a frequency-domain diagnostic method is described that is capable of resolving structures in the femtosecond regime. A novel in-vacuum spectrometer has been developed for spectroscopy of coherent radiation in the THz and infrared range. The spectrometer is equipped with five consecutive dispersion gratings and 120 parallel readout channels; it can be operated either in short wavelength mode (5-44 {mu}m) or in long wavelength mode (45-430 {mu}m). Fast parallel readout permits the spectroscopy of coherent radiation from single electron bunches. Test measurements at the soft X-ray free-electron laser FLASH, using coherent transition radiation, demonstrate excellent performance of the spectrometer. The high sensitivity down to a few micrometers allows study of short bunch features caused for example by microbunching e ects in magnetic chicanes. The device is planned for use as an online bunch profile monitor during regular FEL operation. (orig.)

  16. A Digital Micromirror Device-Based Hadamard Transform Near Infrared Spectrometer%基于数字微镜技术的阿达玛变换近红外光谱仪

    Institute of Scientific and Technical Information of China (English)

    刘佳; 陈奋飞; 廖乘胜; 许谦; 曾立波; 吴琼水

    2011-01-01

    构建了一个基于数字微镜技术的新型阿达玛变换近红外光谱仪.光学信号采用光纤引入,以光栅作为分光元件,利用数字微镜代替传统的机械式阿达玛模板进行光学编码调制,使用单点InGaAs红外探测器检测调制后的光信号,通过快速阿达玛解码还原出原始光谱.通过实验检验了光谱仪的分辨率、信噪比、稳定性以及谱图获取速度等指标.实验结果表明,所研制的光谱仪灵敏度高,信噪比高,响应速度快,体积小巧,其在油品检测、食品安全等行业有着广泛的应用前景.%A Hadamard transform near infrared spectrometer based on a digital micromirror device was constructed. The optical signal was collected by optical fiber, a grating was used for light diffraction, a digital micromirror device (DMD) was applied instead of traditional mechanical Hadamard masks for optical modulation, and an InGaAs near infrared detector was used as the optic sensor. The original spectrum was recovered by fast Hadamard transform algrithms. The advantages of the spectrometer, such as high resolution, signal-noise-ratio, stability, sensitivity and response speed were proved by experiments, which indicated that it is very suitable for oil and food-safety applications.

  17. Emission Ratios for Ammonia and Formic Acid and Observations of Peroxy Acetyl Nitrate (PAN and Ethylene in Biomass Burning Smoke as Seen by the Tropospheric Emission Spectrometer (TES

    Directory of Open Access Journals (Sweden)

    Vivienne H. Payne

    2011-11-01

    Full Text Available We use the Tropospheric Emission Spectrometer (TES aboard the NASA Aura satellite to determine the concentrations of the trace gases ammonia (NH3 and formic acid (HCOOH within boreal biomass burning plumes, and present the first detection of peroxy acetyl nitrate (PAN and ethylene (C2H4 by TES. We focus on two fresh Canadian plumes observed by TES in the summer of 2008 as part of the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS-B campaign. We use TES retrievals of NH3 and HCOOH within the smoke plumes to calculate their emission ratios (1.0% ± 0.5% and 0.31% ± 0.21%, respectively relative to CO for these Canadian fires. The TES derived emission ratios for these gases agree well with previous aircraft and satellite estimates, and can complement ground-based studies that have greater surface sensitivity. We find that TES observes PAN mixing ratios of ~2 ppb within these mid-tropospheric boreal biomass burning plumes when the average cloud optical depth is low ( < 0.1 and that TES can detect C2H4 mixing ratios of ~2 ppb in fresh biomass burning smoke plumes.

  18. Construction of a newly designed small-size mass spectrometer for helium isotope analysis: toward the continuous monitoring of (3)he/(4)he ratios in natural fluids.

    Science.gov (United States)

    Bajo, Ken-Ichi; Sumino, Hirochika; Toyoda, Michisato; Okazaki, Ryuji; Osawa, Takahito; Ishihara, Morio; Katakuse, Itsuo; Notsu, Kenji; Igarashi, George; Nagao, Keisuke

    2012-01-01

    The construction of a small-size, magnetic sector, single focusing mass spectrometer (He-MS) for the continuous, on-site monitoring of He isotope ratios ((3)He/(4)He) is described. The instrument is capable of measuring (4)He/(20)Ne ratios dissolved in several different types of natural fluids of geochemical interest, such as groundwater and gas from hot springs, volcanoes and gas well fields. The ion optics of He-MS was designed using an ion trajectory simulation program "TRIO," which permits the simultaneous measurement of (3)He and (4)He with a double collector system under a mass resolution power (M/ΔM) of >700. The presently attained specifications of He-MS are; (1) a mass resolving power of ca. 430, sufficient to separate (3)He(+) from interfering ions, HD(+) and H3 (+), (2) ultra-high vacuum conditions down to 3×10(-8) Pa, and (3) a sufficiently high sensitivity to permit amounts of (3)He to be detected at levels as small as 10(-13) cm(3) STP (3×10(6) atoms). Long term stability for (3)He/(4)He analysis was examined by measuring the (3)He/(4)He standard gas (HESJ) and atmospheric He, resulting in ∼3% reproducibility and ≤5% experimental error for various amounts of atmospheric He from 0.3 to 2.3×10(-6) cm(3) STP introduced into the instrument. A dynamic range of measurable (3)He/(4)He ratios with He-MS is greater than 10(3) which was determined by measuring various types of natural fluid samples from continental gas (with a low (3)He/(4)He ratio down to 2×10(-8)) to volcanic gas (with a high (3)He/(4)He ratio up to 3×10(-5)). The accuracy and precision of (3)He/(4)He and (4)He/(20)Ne ratios were evaluated by comparing the values with those measured using well established noble gas mass spectrometers (modified VG5400/MS-III and -IV) in our laboratory, and were found to be in good agreement within analytical errors. Usefulness of the selective extraction of He from water/gas using a high permeability of He through a silica glass wall at high

  19. The local stellar luminosity function and mass-to-light ratio in the near-infrared

    Science.gov (United States)

    Just, A.; Fuchs, B.; Jahreiß, H.; Flynn, C.; Dettbarn, C.; Rybizki, J.

    2015-07-01

    A new sample of stars, representative of the solar neighbourhood luminosity function (LF), is constructed from the Hipparcos catalogue and the Fifth Catalogue of Nearby Stars. We have cross-matched to sources in the Two Micron All Sky Survey catalogue so that for all stars individually determined near-infrared (NIR) photometry is available on a homogeneous system (typically Ks). The spatial completeness of the sample has been carefully determined by statistical methods, and the NIR LF of the stars has been derived by direct star counts. We find a local volume luminosity of 0.121 ± 0.004 LK⊙ pc-3, corresponding to a volumetric mass-to-light ratio (M/L) of M/L_K = 0.31 ± 0.02 {M}_{⊙}/L_{K⊙}, where giants contribute 80 per cent to the light but less than 2 per cent to the stellar mass. We derive the surface brightness of the solar cylinder with the help of a vertical disc model. We find a surface brightness of 99 LK⊙ pc-2 with an uncertainty of approximately 10 per cent. This corresponds to an M/L for the solar cylinder of M/L_K = 0.34 {M}_{⊙}/L_{K⊙}. The M/L for the solar cylinder is only 10 per cent larger than the local value despite the fact that the local population has a much larger contribution of young stars. It turns out that the effective scaleheights of the lower main sequence carrying most of the mass is similar to that of the giants, which are dominating the NIR light. The corresponding colour for the solar cylinder is V - K = 2.89 mag compared to the local value of V - K = 2.46 mag. An extrapolation of the local surface brightness to the whole Milky Way yields a total luminosity of MK = -24.2 mag. The Milky Way falls in the range of K band Tully-Fisher relations from the literature.

  20. Characterising the Far-infrared Properties of Distant X-ray Detected AGNs: Evidence for Evolution in the Infrared--X-ray Luminosity Ratio

    CERN Document Server

    Mullaney, J R; Huynh, M; Goulding, A D; Frayer, D

    2009-01-01

    (Abridged) We investigate the far-infrared properties of X-ray sources detected in the Chandra Deep Field-South (CDF-S) survey using the ultra-deep 70um and 24um Spitzer observations taken in this field. We rely on stacking analyses of the 70um data to characterise the average 70um properties of the X-ray sources. Using Spitzer-IRS data of the Swift-BAT sample of z~0 active galactic nuclei (hereafter, AGNs), we show that the 70um/24um flux ratio can distinguish between AGN-dominated and starburst-dominated systems out to z~1.5. From stacking analysis we find that both high redshift and z~0 AGNs follow the same tendency toward warmer 70um/24um colours with increasing X-ray luminosity (L_X). We also show that the 70um flux can be used to determine the infrared (8-1000um) luminosities of high redshift AGNs. We use this information to show that L_X=10^{42-43} erg/s AGNs at high redshifts (z=1-2) have infrared to X-ray luminosity ratios (hereafter, L_IR/L_X) that are, on average, 4.7_{-2.0}^{+10.2} and 12.7^{+7.1}...

  1. FieldSpec: A field portable mass spectrometer prototype for high frequency measurements of δ (2) H and δ (18) O ratios in water

    Science.gov (United States)

    López Días, Veneranda; Quang Hoang, Hung; Martínez-Carreras, Núria; Barnich, François; Wirtz, Tom; Pfister, Laurent; McDonnell, Jeffrey

    2016-04-01

    Hydrological studies relying on stable water isotopes to better understand water sources, flowpaths and transit times are currently limited by the coarse temporal resolution of sampling and analysis protocols. At present, two kinds of lab-based instruments are used : (i) the standard isotope ratio mass spectrometers (IRMS) [1] and (ii) the laser-based instruments [2, 3]. In both cases, samples need to be collected in the field and then transferred to the laboratory for the water isotopic ratio measurements (even further complex sample preparation is required for the IRMS). Hence, past and ongoing research targets the development of field deployable instruments for measuring stable water isotopes at high temporal frequencies. While recent studies have demonstrated that laser-based instruments may be taken to the field [4, 5], their size and power consumption still restrict their use to sites equipped with mains power or generators. Here, we present progress on the development of a field portable mass spectrometer (FieldSpec) for direct high frequency measurements of δ2H and δ18O ratios in water. The FieldSpec instrument is based upon the use of a double focusing magnetic sector mass spectrometer in combination with an electron impact ion source and a membrane dual inlet system. The instrument directly collects liquid water samples in the field, which are then converted into water vapour before being injected into the mass spectrometer for the stable isotope analysis. δ2H and δ18O are derived from the measured mass spectra. All the components are arranged in a vacuum case having a suit case type dimension with portable electronics and battery. Proof-of-concept experiments have been carried out to characterize the instrument. The results show that the FieldSpec instrument has good linearity (R2 = 0.99). The reproducibility of the instrument ranges between 1 and 4 ‰ for δ2H and between 0.1 and 0.4 ‰ for δ18O isotopic ratio measurements. A measurement

  2. Assessment of Transition Element Speciation in Glasses Using a Portable Transmission Ultraviolet-Visible-Near-Infrared (UV-Vis-NIR) Spectrometer.

    Science.gov (United States)

    Hunault, Myrtille; Lelong, Gérald; Gauthier, Michel; Gélébart, Frédéric; Ismael, Saindou; Galoisy, Laurence; Bauchau, Fanny; Loisel, Claudine; Calas, Georges

    2016-05-01

    A new low-cost experimental setup based on two compact dispersive optical spectrometers has been developed to measure optical absorption transmission spectra over the 350-2500 nm energy range. We demonstrate how near-infrared (NIR) data are essential to identify the coloring species in addition to ultraviolet visible data. After calibration with reference glasses, the use of an original sample stage that maintains the window panel in the vertical position enables the comparison of ancient and modern glasses embedded in a panel from the Sainte-Chapelle of Paris, without any sampling. The spectral resolution enables to observe fine resonances arising in the absorption bands of Cr(3+), and the complementary information obtained in the NIR enables to determine the contribution of Fe(2+), a key indicator of glassmaking conditions. © The Author(s) 2016.

  3. From a single encapsulated detector to the spectrometer for INTEGRAL satellite: predicting the peak-to-total ratio at high gamma-energies

    CERN Document Server

    Kshetri, Ritesh

    2012-01-01

    In two recent papers (R. Kshetri, JINST 2012 7 P04008; ibid., P07006), a probabilistic formalism was introduced to predict the response of encapsulated type composite germanium detectors like the SPI (spectrometer for INTEGRAL satellite). Predictions for the peak-to-total and peak-to-background ratios are given at 1.3 MeV for the addback mode of operation. The application of the formalism to clover germanium detector is discussed in two separate papers (R. Kshetri, JINST 2012 7 P07008; ibid., P08015). Using the basic approach developed in those papers, for the first time we present a procedure for calculating the peak-to-total ratio of the cluster detector for gamma-energies up to 8 MeV. Results are shown for both bare and suppressed detectors as well as for the single crystal and addback modes of operation. We have considered the experimental data of (i) peak-to-total ratio at 1.3 MeV, and (ii) single detector efficiency and addback factor for other energies up to 8 MeV. Using this data, an approximate metho...

  4. Angular acceptance analysis of an infrared focal plane array with a built-in stationary Fourier transform spectrometer.

    Science.gov (United States)

    Gillard, Frédéric; Ferrec, Yann; Guérineau, Nicolas; Rommeluère, Sylvain; Taboury, Jean; Chavel, Pierre

    2012-06-01

    Stationary Fourier transform spectrometry is an interesting concept for building reliable field or embedded spectroradiometers, especially for the mid- and far- IR. Here, a very compact configuration of a cryogenic stationary Fourier transform IR (FTIR) spectrometer is investigated, where the interferometer is directly integrated in the focal plane array (FPA). We present a theoretical analysis to explain and describe the fringe formation inside the FTIR-FPA structure when illuminated by an extended source positioned at a finite distance from the detection plane. The results are then exploited to propose a simple front lens design compatible with a handheld package.

  5. Rapid and non-destructive determination of quality parameters in the 'Tommy Atkins' mango using a novel handheld near infrared spectrometer.

    Science.gov (United States)

    Marques, Emanuel José Nascimento; de Freitas, Sérgio Tonetto; Pimentel, Maria Fernanda; Pasquini, Celio

    2016-04-15

    The objective of this study was to evaluate the potential of a new handheld ultra-compact near infrared (NIR) spectrometer, based on the linear-variable filter (LVF) technology for rapid and non-destructive quality control analysis of the 'Tommy Atkins' mango. Multivariate calibration models were built using the Partial Least Squares (PLS) regression method to determine soluble solids (SS), dry matter (DM), titratable acidity (TA) and pulp firmness (PF). Different spectral pre-processing techniques were tested. Coefficient of determination and root mean square errors of prediction (RMSEP) values were, respectively: 0.92 and 0.55°Brix for SS, 0.67 and 0.51% for DM, 0.50 and 0.17% citric acid for TA, 0.72 and 12.2N for PF. The predictive models allowed monitoring physico-chemical changes in each fruit during ripening. The results show the feasibility of using the new NIR handheld spectrometer to determine quality parameters in the 'Tommy Atkins' mango. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Performance of a long-wave infrared Fourier Transform imaging spectrometer using a corner-cube Michelson interferometer and an uncooled microbolometer array

    Science.gov (United States)

    Wang, Nan; Wu, Jianghui; Meng, Hemin; Gao, Jiaobo; Fan, Zhe; Zhang, Mingxuan; Li, Yu; Li, Jianjun

    2015-10-01

    Interference imaging spectroscopy is the advanced subject among the infrared remote sensing, and it has become an important technique to detect spatial information and spectral information of targets. It has the advantages of high flux, high spectral resolution and high spatial resolution that can be used for detecting more details of the spectral and spatial information. Based on a Michelson interferometer with its mirrors replaced by corner-cubes, principles of a hand-held, static, long-wave infrared Fourier Transform(FT) imaging spectrometer using an uncooled microbolometer array are introduced. Because in such FT-based spectral imager, the interferogram is acquired over the whole field of the camera while the scene of interest scans the path difference range, vignetting should be strongly limited while keep the size of the interferometer as small as possible. Interferometer size is given and interferential light path is verified through TracePro software. First results of field and laboratory measurements using the spectral imager are presented. Remotely obtained spectrums collected with this instrument and with those of high precise Michelson spectrometer are compared, and the measured values turned out to be closely corresponded. The results, in turn, verified the feasibility of the systematic working mode. The resulting system tested here provides datacubes of up to 640×480 pixels over the 7.7~13μm spectral range, this wavelength range reveals important information about scenes such as gas or landmine detection, and the instrument has a spectral resolution of about 8cm-1 that fulfils the requirement for most targeted applications. Examples of sky and buildings detection are shown.

  7. Improving Atmospheric Correction for Visible/Short Wave Infrared (VSWIR) Imaging Spectrometers with Iterative Fitting of Absorption By Three Phases of Water

    Science.gov (United States)

    Pennington, E. A.; Thompson, D. R.; Green, R. O.; Gao, B. C.

    2014-12-01

    Airborne imaging spectrometers like the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) offer valuable insight into the Earth's terrestrial and ocean ecosystems, mineralogy, and land use. Estimating surface reflectance requires accounting for atmospheric absorption, which is sensitive to the local abundance of water vapor. Analysts typically estimate water vapor concentrations using the depths of absorption features, which can be inaccurate by up to 50% over surface features containing liquid water or ice. This can bias the retrieved water vapor maps and create atmospheric artifacts in reflectance spectra. A new retrieval method offers significant accuracy improvements over plant canopies or ice by estimating the path lengths of all three phases of water simultaneously, adjusting absorptions to best fit the measurement over a broader spectral interval. This paper assesses the remaining sources of error for the three-phase retrieval technique. We analyze retrievals for synthetic data when the 940 and 1140 nm wavelength features are fitted, for initial vapor path estimates ranging from 0 to ±50% accuracy. These tests indicate that most error comes from inaccuracy in the initial path estimate used to obtain vapor absorption coefficients. We evaluate a modified algorithm that uses multiple iterations to refine this estimate. Error is found to approach a constant value, demonstrating improved robustness to initialization conditions. We also assess the new iterative method using corrected AVIRIS data over various environments. The iterative method yields significantly better water vapor maps, reducing spurious correlations between vegetation canopy water and vapor estimates. The new iterative method offers accuracy improvements over traditional Visible/Short Wave Infrared (VSWIR) atmospheric correction methods, at modest computational cost.

  8. Design and airborne application of a tunable diode laser spectrometer for in-situ measurements of isotope ratios (δ18O, δD) in water

    Science.gov (United States)

    Dyroff, Christoph; Zahn, Andreas; Fütterer, Daniel

    2010-05-01

    The measurement of isotope ratios in water vapor (H2O) can significantly enhance our understanding of many crucial processes in which atmospheric water is involved. The H2O-isotope ratios collect and conserve the H2O evaporation and condensation history prior to sampling. They thus contain supplementary information on the hydrological atmospheric cycle which H2O-concentration measurements cannot provide. Furthermore, due to the considerable temperature-dependent isotope fractionation, H2O-isotope ratios of cloud particles are a measure of the supersaturation present during cloud formation. While a number of satellite measurements have recently been realized [1-4], they only provide a global picture. Airborne in-situ measurements - which can provide the often necessary high spatial resolution - have very scarcely been performed, and only about four instruments exist worldwide, one of which is the tunable diode-laser spectrometer ISOWAT [5]. In this presentation we discuss the design and performance characteristics of our compact and fully automated airborne spectrometer. ISOWAT will regularly (once per month) be deployed aboard the CARIBIC passenger aircraft (Lufthansa A340-600) [6] as of spring 2010, and we examine the importance and potential of our measurements based on the first in-flight data. Finally we give an outlook to further developments, which will even improve the performance of this instrument. Keywords: Water; Isotope Ratio; Laser Spectroscopy; Airborne Instrumentation References [1] A. E. Dessler, T. F. Hanisco, and S. Fueglistaler, J. Geophys. Res. 112, D18309, 2007. [2] J. Steinwagner, M. Milz, T. von Clarmann, N. Glatthor, U. Grabowski, M. Höpfner, G. P. Stiller, and T. Röckmann, Atmos. Chem. Phys. 7, 2601-2615, 2007. [3] V. H. Payne, D. Noone, A. Dudhia, C. Piccolo, and R. G. Grainger, Q. J. R. Meteorol. Soc. 133, 1459-1471, 2007. [4] D. Brown, J. Worden, and D. Noone, J. Geophys. Res. 113, D15124, 2008. [5] C. Dyroff, D. Fütterer, and A. Zahn

  9. Analysis of the Intrinsic Mid-Infrared L-band to Visible--Near-Infrared Flux Ratios in Spectral Synthesis Models of Composite Stellar Populations

    CERN Document Server

    Kim, Duho; Windhorst, Rogier A

    2016-01-01

    We analyze the intrinsic flux ratios of various visible--near-infrared filters with respect to 3.5micron for simple and composite stellar populations, and their dependence on age, metallicity and star formation history. UV/optical light from stars is reddened and attenuated by dust, where different sightlines across a galaxy suffer varying amounts of extinction. Tamura et al. (2009) developed an approximate method to correct for dust extinction on a pixel-by-pixel basis, dubbed the "beta_V" method, by comparing the observed flux ratio to an empirical estimate of the intrinsic ratio of visible and ~3.5micron data. Through extensive modeling, we aim to validate the "beta_V" method for various filters spanning the visible through near-infrared wavelength range, for a wide variety of simple and composite stellar populations. Combining Starburst99 and BC03 models, we built spectral energy distributions (SEDs) of simple (SSP) and composite (CSP) stellar populations for various realistic star formation histories (SF...

  10. Characterizing Exoplanets in the Visible and Infrared: A Spectrometer Concept for the EChO Space Mission

    CERN Document Server

    Glauser, A M; Krause, O; Henning, Th; Benneke, B; Bouwman, J; Cubillos, P E; Crossfield, I J M; Detre, Ö H; Ebert, M; Grözinger, U; Güdel, M; Harrington, J; Justtanont, K; Klaas, U; Lenzen, R; Madhusudhan, N; Meyer, M R; Mordasini, C; Müller, F; Ottensamer, R; Plesseria, J -Y; Quanz, S P; Reiners, A; Renotte, E; Rohloff, R -R; Scheithauer, S; Schmid, H M; Schrader, J -R; Seemann, U; Stam, D; Vandenbussche, B; Wehmeier, U

    2013-01-01

    Transit-spectroscopy of exoplanets is one of the key observational techniques to characterize the extrasolar planet and its atmosphere. The observational challenges of these measurements require dedicated instrumentation and only the space environment allows an undisturbed access to earth-like atmospheric features such as water or carbon-dioxide. Therefore, several exoplanet-specific space missions are currently being studied. One of them is EChO, the Exoplanet Characterization Observatory, which is part of ESA's Cosmic Vision 2015-2025 program, and which is one of four candidates for the M3 launch slot in 2024. In this paper we present the results of our assessment study of the EChO spectrometer, the only science instrument onboard this spacecraft. The instrument is a multi-channel all-reflective dispersive spectrometer, covering the wavelength range from 400 nm to 16 microns simultaneously with a moderately low spectral resolution. We illustrate how the key technical challenge of the EChO mission - the high...

  11. Wavelength calibration of dispersive near-infrared spectrometer using relative k-space distribution with low coherence interferometer

    Science.gov (United States)

    Kim, Ji-hyun; Han, Jae-Ho; Jeong, Jichai

    2016-05-01

    The commonly employed calibration methods for laboratory-made spectrometers have several disadvantages, including poor calibration when the number of characteristic spectral peaks is low. Therefore, we present a wavelength calibration method using relative k-space distribution with low coherence interferometer. The proposed method utilizes an interferogram with a perfect sinusoidal pattern in k-space for calibration. Zero-crossing detection extracts the k-space distribution of a spectrometer from the interferogram in the wavelength domain, and a calibration lamp provides information about absolute wavenumbers. To assign wavenumbers, wavelength-to-k-space conversion is required for the characteristic spectrum of the calibration lamp with the extracted k-space distribution. Then, the wavelength calibration is completed by inverse conversion of the k-space into wavelength domain. The calibration performance of the proposed method was demonstrated with two experimental conditions of four and eight characteristic spectral peaks. The proposed method elicited reliable calibration results in both cases, whereas the conventional method of third-order polynomial curve fitting failed to determine wavelengths in the case of four characteristic peaks. Moreover, for optical coherence tomography imaging, the proposed method could improve axial resolution due to higher suppression of sidelobes in point spread function than the conventional method. We believe that our findings can improve not only wavelength calibration accuracy but also resolution for optical coherence tomography.

  12. Quantitative analysis of melamine in milk powders using near-infrared hyperspectral imaging and band ratio

    Science.gov (United States)

    Since 2008, the detection of the adulterant melamine (2,4,6-triamino-1,3,5-triazine) in food products has become the subject of research due to several food safety scares. Near-infrared (NIR) hyperspectral imaging offers great potential for food safety and quality research because it combines the fe...

  13. Exploration on Experimental Reform and Management Mode of Fourier Transform Infrared Spectrometer Teaching%傅里叶红外光谱仪教学及管理模式探究

    Institute of Scientific and Technical Information of China (English)

    刘荣军; 罗志辉; 韦庆敏; 曾楚杰

    2015-01-01

    对傅里叶红外光谱仪在教学和管理中存在的问题进行了详细地分析,然后探讨了红外光谱仪的教学管理模式,包括实验教学方法、教学模式和管理模式。通过改革其教学方法和教学模式,使学生快速熟练地掌握了红外光谱仪的操作过程,提高了红外光谱仪实验教学效果;通过改革管理模式,减轻了仪器管理员工作强度,提高了仪器的使用率,并且降低了仪器的故障率。%This paper analyses the current existing problems of Fourier Transform Infrared Spectrometer in teaching and management, discusses the model and method of Fourier Transform Infrared Spectrometer teaching and managing. By reforming the teaching methods and teaching mode, we help students quickly master infrared spectrometer operating process, thus improving the effect of the infrared spectrometer experiment teaching. Through the reform of the management pattern, we reduce the instrument administrator working strength, improve the efficiency of the instrument, and reduce the failure rate of the instrument.

  14. Determination of the concentration of nitrogenous bio-organic compounds using an isotope ratio mass spectrometer operating in continuous flow mode.

    Science.gov (United States)

    Tea, Illa; Kosieradzka, Katarzyna; Antheaume, Ingrid; Gentil, Emmanuel; Robins, Richard J

    2011-09-01

    The quality of the determination of compound-specific isotopic content at natural abundance by gas chromatography-isotope ratio measurement-mass spectrometry (GC-irm-MS) relies on the stability of the voltage generated by the ion detector Faraday cages. The application of GC-irm-MS to the determination of δ(13)C (‰) and δ(15)N (‰) is now routine. However, for numerous applications, it is necessary to determine both the isotope content (δ(15)N) and the quantity (in micromoles) of analyte present. We now show that it is possible for nitrogen-containing compounds to measure how much analyte is present with an irm mass spectrometer linked to a GC by exploiting the integrated N(2) total ion current intensity (Vs) generated by measuring the (15)N/(14)N isotope ratio. The method is validated over a range of concentration (2-70 mmol/L) and δ(15)N (-70 to +50‰) values for six molecules of diverse chemical nature and functionality (nortropine, norpseudotropine, nortropinone, cysteine, taurine, glutathione). It is shown that once the ion current is calibrated, the quantitative values are of a comparable quality to those obtained from GC with flame ionization detection (GC-FID). In addition, it is demonstrated that over a definable range, the δ(15)N (‰) value is independent of the quantity of analyte introduced, confirming the validity of this method.

  15. Spherical grating spectrometers

    Science.gov (United States)

    O'Donoghue, Darragh; Clemens, J. Christopher

    2014-07-01

    We describe designs for spectrometers employing convex dispersers. The Offner spectrometer was the first such instrument; it has almost exclusively been employed on satellite platforms, and has had little impact on ground-based instruments. We have learned how to fabricate curved Volume Phase Holographic (VPH) gratings and, in contrast to the planar gratings of traditional spectrometers, describe how such devices can be used in optical/infrared spectrometers designed specifically for curved diffraction gratings. Volume Phase Holographic gratings are highly efficient compared to conventional surface relief gratings; they have become the disperser of choice in optical / NIR spectrometers. The advantage of spectrometers with curved VPH dispersers is the very small number of optical elements used (the simplest comprising a grating and a spherical mirror), as well as illumination of mirrors off axis, resulting in greater efficiency and reduction in size. We describe a "Half Offner" spectrometer, an even simpler version of the Offner spectrometer. We present an entirely novel design, the Spherical Transmission Grating Spectrometer (STGS), and discuss exemplary applications, including a design for a double-beam spectrometer without any requirement for a dichroic. This paradigm change in spectrometer design offers an alternative to all-refractive astronomical spectrometer designs, using expensive, fragile lens elements fabricated from CaF2 or even more exotic materials. The unobscured mirror layout avoids a major drawback of the previous generation of catadioptric spectrometer designs. We describe laboratory measurements of the efficiency and image quality of a curved VPH grating in a STGS design, demonstrating, simultaneously, efficiency comparable to planar VPH gratings along with good image quality. The stage is now set for construction of a prototype instrument with impressive performance.

  16. CONSTRAINING MASS RATIO AND EXTINCTION IN THE FU ORIONIS BINARY SYSTEM WITH INFRARED INTEGRAL FIELD SPECTROSCOPY

    Energy Technology Data Exchange (ETDEWEB)

    Pueyo, Laurent [Johns Hopkins University, Department of Physics and Astronomy, 366 Bloomberg Center 3400 N. Charles Street, Baltimore, MD 21218 (United States); Hillenbrand, Lynne; Hinkley, Sasha; Dekany, Richard; Roberts, Jenny [Department of Astronomy, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Vasisht, Gautam; Roberts, Lewis C. Jr.; Shao, Mike; Burruss, Rick; Cady, Eric [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Oppenheimer, Ben R.; Brenner, Douglas; Zimmerman, Neil [American Museum of Natural History, Central Park West at 79th Street, New York, NY 10024 (United States); Monnier, John D. [Department of Astronomy, University of Michigan, 941 Dennison Building, 500 Church Street, Ann Arbor, MI 48109-1090 (United States); Crepp, Justin [Department of Physics, 225 Nieuwland Science Hall, University of Notre Dame, Notre Dame, IN 46556 (United States); Parry, Ian [University of Cambridge, Institute of Astronomy, Madingley Road, Cambridge, CB3, OHA (United Kingdom); Beichman, Charles [NASA Exoplanet Science Institute, 770 South Wilson Avenue, Pasadena, CA 91225 (United States); Soummer, Remi [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States)

    2012-09-20

    We report low-resolution near-infrared spectroscopic observations of the eruptive star FU Orionis using the Integral Field Spectrograph (IFS) Project 1640 installed at the Palomar Hale telescope. This work focuses on elucidating the nature of the faint source, located 0.''5 south of FU Ori, and identified in 2003 as FU Ori S. We first use our observations in conjunction with published data to demonstrate that the two stars are indeed physically associated and form a true binary pair. We then proceed to extract J- and H-band spectro-photometry using the damped LOCI algorithm, a reduction method tailored for high contrast science with IFS. This is the first communication reporting the high accuracy of this technique, pioneered by the Project 1640 team, on a faint astronomical source. We use our low-resolution near-infrared spectrum in conjunction with 10.2 {mu}m interferometric data to constrain the infrared excess of FU Ori S. We then focus on estimating the bulk physical properties of FU Ori S. Our models lead to estimates of an object heavily reddened, A{sub V} = 8-12, with an effective temperature of {approx}4000-6500 K. Finally, we put these results in the context of the FU Ori N-S system and argue that our analysis provides evidence that FU Ori S might be the more massive component of this binary system.

  17. Euclid Near Infrared Spectrometer and Photometer instrument concept and first test results obtained for different breadboards models at the end of phase C

    Science.gov (United States)

    Maciaszek, Thierry; Ealet, Anne; Jahnke, Knud; Prieto, Eric; Barbier, Rémi; Mellier, Yannick; Beaumont, Florent; Bon, William; Bonnefoi, Anne; Carle, Michael; Caillat, Amandine; Costille, Anne; Dormoy, Doriane; Ducret, Franck; Fabron, Christophe; Febvre, Aurélien; Foulon, Benjamin; Garcia, Jose; Gimenez, Jean-Luc; Grassi, Emmanuel; Laurent, Philippe; Le Mignant, David; Martin, Laurent; Rossin, Christelle; Pamplona, Tony; Sanchez, Patrice; Vives, Sébastien; Clémens, Jean Claude; Gillard, William; Niclas, Mathieu; Secroun, Aurélia; Serra, Benoit; Kubik, Bogna; Ferriol, Sylvain; Amiaux, Jérôme; Barrière, Jean Christophe; Berthe, Michel; Rosset, Cyrille; Macias-Perez, Juan Francisco; Auricchio, Natalia; De Rosa, Adriano; Franceschi, Enrico; Guizzo, Gian Paolo; Morgante, Gianluca; Sortino, Francesca; Trifoglio, Massimo; Valenziano, Luca; Patrizii, Laura; Chiarusi, T.; Fornari, F.; Giacomini, F.; Margiotta, A.; Mauri, N.; Pasqualini, L.; Sirri, G.; Spurio, M.; Tenti, M.; Travaglini, R.; Dusini, Stefano; Dal Corso, F.; Laudisio, F.; Sirignano, C.; Stanco, L.; Ventura, S.; Borsato, E.; Bonoli, Carlotta; Bortoletto, Favio; Balestra, Andrea; D'Alessandro, Maurizio; Medinaceli, Eduardo; Farinelli, Ruben; Corcione, Leonardo; Ligori, Sebastiano; Grupp, Frank; Wimmer, Carolin; Hormuth, Felix; Seidel, Gregor; Wachter, Stefanie; Padilla, Cristóbal; Lamensans, Mikel; Casas, Ricard; Lloro, Ivan; Toledo-Moreo, Rafael; Gomez, Jaime; Colodro-Conde, Carlos; Lizán, David; Diaz, Jose Javier; Lilje, Per B.; Toulouse-Aastrup, Corinne; Andersen, Michael I.; Sørensen, Anton N.; Jakobsen, Peter; Hornstrup, Allan; Jessen, Niels-Christian; Thizy, Cédric; Holmes, Warren; Israelsson, Ulf; Seiffert, Michael; Waczynski, Augustyn; Laureijs, René J.; Racca, Giuseppe; Salvignol, Jean-Christophe; Boenke, Tobias; Strada, Paolo

    2016-07-01

    The Euclid mission objective is to understand why the expansion of the Universe is accelerating through by mapping the geometry of the dark Universe by investigating the distance-redshift relationship and tracing the evolution of cosmic structures. The Euclid project is part of ESA's Cosmic Vision program with its launch planned for 2020 (ref [1]). The NISP (Near Infrared Spectrometer and Photometer) is one of the two Euclid instruments and is operating in the near-IR spectral region (900- 2000nm) as a photometer and spectrometer. The instrument is composed of: - a cold (135K) optomechanical subsystem consisting of a Silicon carbide structure, an optical assembly (corrector and camera lens), a filter wheel mechanism, a grism wheel mechanism, a calibration unit and a thermal control system - a detection subsystem based on a mosaic of 16 HAWAII2RG cooled to 95K with their front-end readout electronic cooled to 140K, integrated on a mechanical focal plane structure made with molybdenum and aluminum. The detection subsystem is mounted on the optomechanical subsystem structure - a warm electronic subsystem (280K) composed of a data processing / detector control unit and of an instrument control unit that interfaces with the spacecraft via a 1553 bus for command and control and via Spacewire links for science data This presentation describes the architecture of the instrument at the end of the phase C (Detailed Design Review), the expected performance, the technological key challenges and preliminary test results obtained for different NISP subsystem breadboards and for the NISP Structural and Thermal model (STM).

  18. Molecular Dynamics at Electrical- and Optical-Driven Phase Transitions: Time-Resolved Infrared Studies Using Fourier-Transform Spectrometers

    Science.gov (United States)

    Peterseim, Tobias; Dressel, Martin

    2017-01-01

    The time-dependent optical properties of molecular systems are investigated by step-scan Fourier-transform spectroscopy in order to explore the dynamics at phase transitions and molecular orientation in the milli- and microsecond range. The electrical switching of liquid crystals traced by vibrational spectroscopy reveals a rotation of the molecules with a relaxation time of 2 ms. The photo-induced neutral-ionic transition in TTF-CA takes place by a suppression of the dimerization in the ionic phase and creation of neutral domains. The time-dependent infrared spectra, employed to investigate the domain-wall dynamics, depend on temperature and laser pulse intensity; the relaxation of the spectra follows a stretched-exponential decay with relaxation times in the microsecond range strongly dependent on temperature and laser intensity. We present all details of the experimental setups and thoroughly discuss the technical challenges.

  19. The Micro Fourier Transform Interferometer (muFTIR) - A New Field Spectrometer for Acquisition of Infrared Data of Natural Surfaces

    Science.gov (United States)

    Hook, Simon J.

    1995-01-01

    A lightweight, rugged, high-spectral-resolution interferometer has been built by Designs and Prototypes based on a set of specifications provided by the Jet Propulsion Laboratory and Dr. J. W. Salisbury (Johns Hopkins University). The instrument, the micro Fourier Transform Interferometer (mFTIR), permits the acquisition of infrared spectra of natural surfaces. Such data can be used to validate low and high spectral resolution data acquired remotely from aircraft and spacecraft in the 3-5 mm and 8-14 mm atmospheric window. The instrument has a spectral resolutions of 6 wavenumbers, weighs 16 kg including batteries and computer, and can be operated easily by two people in the field. Laboratory analysis indicates the instrument is spectrally calibrated to better than 1 wavenumber and the radiometric accuracy is <0.5 K if the radiances from the blackbodies used for calibration bracket the radiance from the sample.

  20. FIRAS optical alignment and performance during vibration qualification and cryogenic cycling. [Far InfraRed Absolute Spectrometer

    Science.gov (United States)

    Hagopian, John G.

    1989-01-01

    NASA's Cosmic Background Explorer (COBE) is designed to investigate the Cosmic Background Radiation (CBR), that permeates the universe as a consequence of the Big Bang. This 3 degree Kelvin radiation is a fossil that contains much information about the early universe. The Far Infrared Absolute Spectrophotometer (FIRAS), will investigate the spectral isotropy of this ancient remnant and look for clues as to the subsequent evolution of the universe. The instrument is a cryogenically cooled, modified Michelson interferometer which operates in the 1 cm to 100 micron wavelength range. FIRAS is designed to provide absolute spectral information, therefore, all possible perturbations to the instrument response must be investigated to minimize distortions of the data. This paper discusses the methodology and resultant variations in the instrument performance noted during room temperature, and liquid nitrogen, (LN2) temperature vibration qualification. Reference alignment shifts in critical components such as the instrument wire-grid beamsplitter are correlated to changes in the instrument spectral response.

  1. Near-infrared analysis of fennel (Foeniculum vulgare Miller) on different spectrometers--basic considerations for a reliable network.

    Science.gov (United States)

    Steuer, Boris; Schulz, Hartwig

    2003-01-01

    The aim of this study was to investigate the accuracy and transferability of near-infrared (NIR) calibrations for estimating the content and composition of the volatile fraction in fennel fruits (Foeniculum vulgare Miller) as an example of medicinal and spice plants. A master calibration with spectra obtained on a scanning monochromator was generated using 345 samples from three different harvests (1997-1999). A subset of 70 samples from 1999 was also measured on a dispersive grating and a scanning diode array system to gain an insight into the influence of sample presentation and scanning techniques. For all instruments, calibrations with standard errors in the range of the reference method were achieved. Furthermore the influence of storage on NIR spectra and, additionally, the potential of transferring spectra between both scanning monochromators was studied.

  2. Molecular Dynamics at Electrical- and Optical-Driven Phase Transitions: Time-Resolved Infrared Studies Using Fourier-Transform Spectrometers

    Science.gov (United States)

    Peterseim, Tobias; Dressel, Martin

    2016-06-01

    The time-dependent optical properties of molecular systems are investigated by step-scan Fourier-transform spectroscopy in order to explore the dynamics at phase transitions and molecular orientation in the milli- and microsecond range. The electrical switching of liquid crystals traced by vibrational spectroscopy reveals a rotation of the molecules with a relaxation time of 2 ms. The photo-induced neutral-ionic transition in TTF-CA takes place by a suppression of the dimerization in the ionic phase and creation of neutral domains. The time-dependent infrared spectra, employed to investigate the domain-wall dynamics, depend on temperature and laser pulse intensity; the relaxation of the spectra follows a stretched-exponential decay with relaxation times in the microsecond range strongly dependent on temperature and laser intensity. We present all details of the experimental setups and thoroughly discuss the technical challenges.

  3. Micro Hadamard Transform Near-Infrared Spectrometer%微型MOEMS阿达玛变换近红外光谱仪

    Institute of Scientific and Technical Information of China (English)

    张智海; 莫祥霞; 郭媛君; 王伟

    2011-01-01

    提出一种运用微光机电系统(micro-opto-electro-mechanical systems,MOEMS)闪耀光栅,动态产生阿达玛变换模版的微型近红外光谱仪.它具有体积小、价格低、扫描速度快等突出优点.分析了这种新型近红外光谱仪的结构和工作原理,通过对MOEMS闪耀光栅编程,动态生成了 63阶阿达玛模版.实验得到的光谱波形与岛津光谱仪测量结果吻合.检测波长范围为900~1 500nm,分辨率为19nm,单次扣描时间2.4s,信噪比为44.67:1,光路尺寸为70 mm×130 mm,总体重量<1kg,符合实时、便携的要求.%A new type micro Hadanard transform (HT) near-infrared (NIR) spectrometer is proposed in the present paper. It has a MOEMS (Micro-Opto-Electro-Mechanical Systems) blazed grating HT mask. It has merits of compactness, agility of dynamic mask generation and high scan speed. The structure and theory of this spectrometer are analyzed. The 63-order Hadarmard-S matrix and mask are designed. The mask is dynamically generated by program of MOEMS blazed gratings. The spectrum is in agreement with that measured by Shimadzu spectrometer in experiments. It has a wavelength range between 900 and 1 700 nm, spectral resolution of 19 nm, single scan time of 2.4 s, SNR of 44. 67 : 1, optical path of 70 mm× 130 mm, and weight under 1 kg. It can meet the requirement of real time detection and portable application.

  4. Near infrared spectroscopy of M dwarfs. IV. A preliminary survey on the carbon isotopic ratios in M dwarfs

    CERN Document Server

    Tsuji, Takashi

    2016-01-01

    Based on the medium resolution near infrared spectra of 13CO (3,1) band, carbon isotopic ratios are estimated in 48 M dwarfs, for which we had determined the carbon and oxygen abundances from CO and H2O lines, respectively. We find clear evidence for the presence of a 13CO feature for the first time in the spectra of M dwarfs. The spectral resolution of our observed data, however, is not high enough to analyze the 13CO feature directly. Instead, we compare observed spectrum with synthetic spectra assuming 12C/13C = 10, 25, 50, 100, and 200 for each of 48 M dwarfs and estimate the best possible 12C/13C ratio by the chi-square analysis. The resulting 12C/13C ratios in M dwarfs distribute from 39 to a lower limit of 200. The mean value of 31 M dwarfs for which 12C/13C ratios are determined is 12C/13C = 87 +- 21 (p.e.), and that of 48 M dwarfs including those with the lower limit of 200 is 12C/13C > 127 +- 41 (p.e.). These results are somewhat larger than the 12C/13C ratio of the present interstellar matter (ISM)...

  5. An experimental study of HF photodissociation: Spin{endash}orbit branching ratio and infrared alignment

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, J.; Riehn, C.W.; Dulligan, M.; Wittig, C. [Department of Chemistry, University of Southern California, Los Angeles, California 90089-0482 (United States)

    1996-05-01

    Single rotational levels of HF ({ital v}=3) were prepared by using overtone excitation and these molecules were then photodissociated by ultraviolet (UV) radiation at 193.3 nm. Time-of-flight spectra of the hydrogen atom fragment provided the spin{endash}orbit state distribution of the fluorine fragment. Changing the UV photolysis laser polarization confirmed an {ital A}{sup 1}{Pi}{l_arrow}{ital X}{sup 1}{Sigma}{sup +} electronic transition in the photodissociation step. Photodissociation of HF at 121.6 nm is also reported. Infrared (IR) induced alignment of the diatom was studied by monitoring the IR laser polarization dependence of the H-atom product angular distribution. Depolarization due to hyperfine interaction was studied by using the {ital R}(0) transition. Agreement with theory is excellent. {copyright} {ital 1996 American Institute of Physics.}

  6. An experimental study of HF photodissociation: Spin-orbit branching ratio and infrared alignment

    Science.gov (United States)

    Zhang, J.; Riehn, C. W.; Dulligan, M.; Wittig, C.

    1996-05-01

    Single rotational levels of HF (v=3) were prepared by using overtone excitation and these molecules were then photodissociated by ultraviolet (UV) radiation at 193.3 nm. Time-of-flight spectra of the hydrogen atom fragment provided the spin-orbit state distribution of the fluorine fragment. Changing the UV photolysis laser polarization confirmed an A 1Π←X 1Σ+ electronic transition in the photodissociation step. Photodissociation of HF at 121.6 nm is also reported. Infrared (IR) induced alignment of the diatom was studied by monitoring the IR laser polarization dependence of the H-atom product angular distribution. Depolarization due to hyperfine interaction was studied by using the R(0) transition. Agreement with theory is excellent.

  7. Optimized data analysis algorithm for on-site chemical identification using a hand-held attenuated total reflection Fourier transform infrared (ATR FT-IR) spectrometer.

    Science.gov (United States)

    Ron, Izhar; Zaltsman, Amalia; Kendler, Shai

    2013-12-01

    On-site identification of organic compounds in the presence of interfering materials using a field-portable attenuated total reflection Fourier transform infrared (ATR FT-IR) spectrometer is presented. Identification is based on an algorithm that compares the analyte's infrared absorption spectrum with the reference spectra. The comparison is performed at several predetermined frequencies, and a similarity value (distance) between the measured and the reference spectra is calculated either at each frequency individually, or, alternatively, the average distance for all frequencies is calculated. The examined frequencies are selected to give the best contrast between the target materials of interest. In this study, the algorithm was optimized to identify three common chemical warfare agents (CWAs): O-ethyl S-[2-(diisopropylamino)ethyl] methylphosphonothioic acid (VX), sarin (GB), and sulfur mustard (bis(2-chloroethyl) sulfide) (HD), in the presence of field-related interfering materials (fuels, water, and dust). Receiver operating characteristics analysis was performed in order to determine the probabilities for detection (PD) and for false alerts (PF). Challenging the algorithm with a set of data that contains mixtures of CWAs and interfering materials resulted in PD of 90% and PF of 0%, 0%, and 1% for VX, GB, and HD, respectively, using the average distance approach, which was found to be much more effective than analyzing each frequency individually. This finding was validated for all possible combinations of 2-7 peaks per material. It is suggested that this algorithm provides a reliable mean for the identification of a predetermined set of target analytes and interfering materials.

  8. Dusty Gas Accretion onto Massive Black Holes and Infrared Diagnosis of the Eddington Ratio

    Science.gov (United States)

    Yajima, Hidenobu; Ricotti, Massimo; Park, KwangHo; Sugimura, Kazuyuki

    2017-09-01

    Evidence for dust around supermassive black holes (SMBHs) in the early universe is strongly suggested by recent observations. However, the accretion mechanism of SMBHs in dusty gas is not well understood yet. We investigate the growth of intermediate-mass black holes (IMBHs) of ˜ {10}4{--}{10}6 {M}⊙ in dusty clouds by using one-dimensional radiative-hydrodynamics simulations. We find that the accretion of dusty gas onto IMBHs proceeds gently with small fluctuations of the accretion rate, whereas that of pristine gas causes more violent periodic bursts. At dust-to-gas mass ratios similar to the solar neighborhood, the time-averaged luminosity becomes smaller than that for primordial gas by one order of magnitude and the time-averaged Eddington ratio ranges from ˜ {10}-4 to ˜ {10}-2 in clouds with initial gas densities of {n}{{H}}=10{--}1000 {{cm}}-3. Our calculations show that the effect of dust opacity alone is secondary compared to the radiation pressure on dust in regulating the BH growth. We also derive spectral energy distributions at IR bands by calculating dust thermal emission and show that the flux ratio between λ ≲ 20 μ {{m}} and ≳ 100 μ {{m}} is closely related to the Eddington ratio. Thermal emission from hot dust near the BH dominates only during the phase of high accretion, producing higher flux density at ≲ 20 μ {{m}}. Therefore, we suggest that a combination of mid-IR observations by the James Webb Space Telescope and far-IR observations by ALMA or Spitzer can be used to estimate the Eddington ratio of massive BHs. We also extend our simple modeling to SMBHs of {10}8{--}{10}9 {M}⊙ and show that ALMA can detect SMBHs of ˜ {10}9 {M}⊙ at z≳ 5.

  9. Development of Multi-Membrane Near-Infrared Diode Mass Spectrometer for Field Analysis of Aromatic Hydrocarbons

    Science.gov (United States)

    Mach, Phillip M.; Wright, Kenneth C.; Verbeck, Guido F.

    2015-02-01

    Membrane Inlet Mass Spectrometry (MIMS) is a technique that incorporates a semi-permeable membrane selective for differing organic molecules and chemistries. This eliminates the need for time-consuming sample preparation and facilitates near instantaneous analysis. This study will examine how the front end of MIMS incorporates three dual inlet ports, allowing for differing MIMS materials and selectivity for specific environments. Polydimethylsiloxane (PDMS) membranes have proven to be selective of benzene, toluene, and xylene (BTX) as well as aromatic hydrocarbons that are common in petroleum products while remaining selective against the aliphatic chains. PDMS has proven to be a successful choice of membrane with high permeability in atmospheric environments. In addition, polycyclic aromatic hydrocarbons (PAHs) such as acenaphthene, acenapthylene, naphthalene, and fluorene have recently been detected to the 5 ppb level in a nitrogen atmosphere with our current configuration. This preliminary work provides proof of concept using near-infrared laser diodes that act upon the membrane to increase its permeability and provide higher sensitivity of aromatic samples.

  10. Application Fourier transform near infrared spectrometer in rapid estimation of soluble solids content of intact citrus fruits

    Institute of Scientific and Technical Information of China (English)

    LU Hui-shan; XU Hui-rong; YING Yi-bin; FU Xia-ping; YU Hai-yan; TIAN Hai-qing

    2006-01-01

    Nondestructive method of measuring soluble solids content (SSC) of citrus fruits was developed using Fourier transform near infrared reflectance (FT-NIR) measurements collected through optics fiber. The models describing the relationship between SSC and the NIR spectra of citrus fruits were developed and evaluated. Different spectra correction algorithms (standard normal variate (SNV), multiplicative signal correction (MSC)) were used in this study. The relationship between laboratory SSC and FT-NIR spectra of citrus fruits was analyzed via principle component regression (PCR) and partial least squares (PLS) regression method. Models based on the different spectral ranges were compared in this research. The first derivative and second derivative were applied to all spectra to reduce the effects of sample size, light scattering, instrument noise, etc. Different baseline correction methods were applied to improve the spectral data quality. Among them the second derivative method after baseline correction produced best noise removing capability and yielded optimal calibration models. A total of 170 NIR spectra were acquired; 135 NIR spectra were used to develop the calibration model; the remaining spectra were used to validate the model. The developed PLS model describing the relationship between SSC and NIR reflectance spectra could predict SSC of 35 samples with correlation coefficient of 0.995 and RMSEP of 0.79°Brix.

  11. A 100 kHz Time-Resolved Multiple-Probe Femtosecond to Second Infrared Absorption Spectrometer.

    Science.gov (United States)

    Greetham, Gregory M; Donaldson, Paul M; Nation, Charlie; Sazanovich, Igor V; Clark, Ian P; Shaw, Daniel J; Parker, Anthony W; Towrie, Michael

    2016-04-01

    We present a dual-amplifier laser system for time-resolved multiple-probe infrared (IR) spectroscopy based on the ytterbium potassium gadolinium tungstate (Yb:KGW) laser medium. Comparisons are made between the ytterbium-based technology and titanium sapphire laser systems for time-resolved IR spectroscopy measurements. The 100 kHz probing system provides new capability in time-resolved multiple-probe experiments, as more information is obtained from samples in a single experiment through multiple-probing. This method uses the high repetition-rate probe pulses to repeatedly measure spectra at 10 µs intervals following excitation allowing extended timescales to be measured routinely along with ultrafast data. Results are presented showing the measurement of molecular dynamics over >10 orders of magnitude in timescale, out to 20 ms, with an experimental time response of <200 fs. The power of multiple-probing is explored through principal component analysis of repeating probe measurements as a novel method for removing noise and measurement artifacts.

  12. Micro spatial modulation Fourier transform infrared spectrometer%空间调制微型傅里叶变换红外光谱仪研究

    Institute of Scientific and Technical Information of China (English)

    梁静秋; 梁中翥; 吕金光; 秦余欣; 田超; 王维彪

    2015-01-01

    According to the urgent requirement to the microminiature, lightweight, and staticize on Fourier transform infrared spectrometer in the field of environment, medical treatment, space exploration, meteorolo-gy, military and security, a spatial modulation Fourier transform infrared spectrometer based on MOEMS micro multi-step mirrors( MMSMs) was proposed.In theory, the physical model and the optical principle of spatial modulation Fourier transform infrared spectrometer was built and researched.A method of leaving extra pat-ches in the boundary to suppress diffraction noise was put forward, and an algorithm based on the least-squares approximation was proposed to correct sampling error.According to the analyzing on the fabrication accuracy of MMSMs, the dispersion characteristics and the transmission efficiency of the beam splitter, the design method and the technical parameters were determined.In the core technology, three different kinds of manufacture method of MMSMs were put forward.By ways of analyzing the origin of the error, the tolerance of two MMSMs was given.The two MMSMs were completed by the method of electroform, positioning of the growth multilayer film, and inclined plane method respectively.In the system design, the infrared collimation system and ima-ging system were designed and manufactured.According to modeling simulation of the whole machine system, the source of stray light noise was analyzed.In the interferogram processing, using zero crossing sampling model and image segmentation algorithm, the sampling sequence was obtained.By interpolation, zero filling, continuation and convolution of the interference sequence, the phase error of spectrum was corrected.After that, the spectrum was obtained from the interferogram via discrete Fourier transform.Finally, the integration and coupling technology of the system were researched.The characteristics of infrared spectrometer developed in this project were as follows:Firstly, the moving mirror driven

  13. Preliminary validation of column-averaged volume mixing ratios of carbon dioxide and methane retrieved from GOSAT short-wavelength infrared spectra

    Directory of Open Access Journals (Sweden)

    I. Morino

    2010-12-01

    Full Text Available Column-averaged volume mixing ratios of carbon dioxide and methane retrieved from the Greenhouse gases Observing SATellite (GOSAT Short-Wavelength InfraRed observation (GOSAT SWIR XCO2 and XCH4 were compared with the reference data obtained by ground-based high-resolution Fourier Transform Spectrometers (g-b FTSs participating in the Total Carbon Column Observing Network (TCCON.

    Through calibrations of g-b FTSs with airborne in-situ measurements, the uncertainty of XCO2 and XCH4 associated with the g-b FTS was determined to be 0.8 ppm (~0.2% and 4 ppb (~0.2%, respectively. The GOSAT products are validated with these calibrated g-b FTS data. Preliminary results are as follows: The GOSAT SWIR XCO2 and XCH4 (Version 01.xx are biased low by 8.85 ± 4.75 ppm (2.3 ± 1.2% and 20.4 ± 18.9 ppb (1.2 ± 1.1%, respectively. The precision of the GOSAT SWIR XCO2 and XCH4 is considered to be about 1%. The latitudinal distributions of zonal means of the GOSAT SWIR XCO2 and XCH4 show similar features to those of the g-b FTS data.

  14. Hydrogen Isotopic Composition of Arctic and Atmospheric CH4 Determined by a Portable Near-Infrared Cavity Ring-Down Spectrometer with a Cryogenic Pre-Concentrator

    Science.gov (United States)

    Chen, Y.; Lehmann, Kevin K.; Peng, Y.; Pratt, L. M.; White, J. R.; Cadieux, S. B.; Sherwood Lollar, B.; Lacrampe-Couloume, G.; Onstott, T. C.

    2016-10-01

    In this study, near-infrared continuous wave cavity ring-down spectroscopy was applied to the measurement of the δ2H of methane (CH4). The cavity ring-down spectrometer (CRDS) system consisted of multiple DFB laser diodes to optimize selection of spectral line pairs. By rapidly switching measurements between spectral line peaks and the baseline regions, the long-term instrumental drift was minimized, substantially increasing measurement precision. The CRDS system coupled with a cryogenic pre-concentrator measured the δ2H of terrestrial atmospheric CH4 from 3 standard liters of air with a precision of ±1.7‰. The rapidity with which both C and H isotopic measurements of CH4 can be made with the CRDS will enable hourly monitoring of diurnal variations in terrestrial atmospheric CH4 signatures that can be used to increase the resolution of global climate models for the CH4 cycle. Although the current instrument is not capable of measuring the δ2H of 10 ppbv of martian CH4, current technology does exist that could make this feasible for future spaceflight missions. As biological and abiotic CH4 sources have overlapping carbon isotope signatures, dual-element (C and H) analysis is key to reliable differentiation of these sources. Such an instrument package would therefore offer improved ability to determine whether or not the CH4 recently detected in the martian atmosphere is biogenic in origin.

  15. Temperature-Dependent Refractive Index Measurements of Caf2, Suprasil 3001, and S-FTM16 for the Euclid Near Infrared Spectrometer and Photometer

    Science.gov (United States)

    Leviton, Douglas B.; Miller, Kevin H.; Quijada, Manuel A.; Grupp, Frank D.

    2015-01-01

    Using the Cryogenic High Accuracy Refraction Measuring System (CHARMS) at NASA's Goddard Space Flight Center, we measured absolute refractive indices at temperatures from 100 to 310 K at wavelengths from 0.42 to 3.6 microns for CaF2, Suprasil 3001 fused silica, and S-FTM16 glass in support of lens designs for the Near Infrared Spectrometer and Photometer (NISP) for ESA's Euclid dark energy mission. We report absolute refractive index, dispersion (dn/d?), and thermo-optic coefficient (dn/dT) for these materials. In this study, materials from different melts were procured to understand index variability in each material. We provide temperature-dependent Sellmeier coefficients based on our data to allow accurate interpolation of index to other wavelengths and temperatures. For calcium fluoride (CaF2) and S-FTM16, we compare our current measurements with CHARMS measurements of these materials made in the recent past for other programs. We also compare Suprasil 3001's indices to those of other forms of fused silica we have measured in CHARMS.

  16. Retrospective assessment of macrophytic communities in southern Lake Garda (Italy from in situ and MIVIS (Multispectral Infrared and Visible Imaging Spectrometer data

    Directory of Open Access Journals (Sweden)

    Claudia Giardino

    2012-01-01

    Full Text Available In situ and hyperspectral MIVIS (Multispectral Infrared and Visible Imaging Spectrometer images acquired over a period of 13 years are used to assess changes in macrophyte colonization patterns in the coastal zones of the Sirmione Peninsula in the southern part of Lake Garda (Italy. In situ data (abundance, cover density and diversity of macrophyte communities and MIVIS-derived maps of colonized substrates are analyzed by considering the variability of the main hydrological and physicochemical variables in order to indicate the main factors that explain the spatiotemporal variability of macrophyte communities. The results show a considerable modification in terms of macrophyte structural complexity and colonized areas. Almost 98% of macrophyte meadows (in particular communities with a density of over 70% are lost and subsequently replaced by moderate to extremely rare communities with density from 10% to 40%. Well-established submerged macrophytes are replaced by de-structured communities characterized by moderate to scarce density: on average lower than 30%. The study indicates that macrophyte distribution along the littoral zone of the Sirmione Peninsula is certainly linked to water transparency and water level fluctuation. The results also indicate that the worsening of eutrophication may be associated with the gradual disappearance of macrophyte meadows, but may also be accelerated by herbivorous aquatic birds grazing there. Lastly, the increasing frequency and number of catamaran tours could be considered a threat for the stability of these valuable communities.

  17. Configurable slit-mask unit of the Multi-Object Spectrometer for Infra-Red Exploration for the Keck telescope: integration and tests

    Science.gov (United States)

    Spanoudakis, Peter; Giriens, Laurent; Henein, Simon; Lisowski, Leszek; O'Hare, Aidan; Onillon, Emmanuel; Schwab, Philippe; Theurillat, Patrick

    2008-07-01

    A Configurable Slit Unit (CSU) has been developed for the Multi-Object Spectrometer for Infra-Red Exploration (MOSFIRE) instrument to be installed on the Keck 1 Telescope on Mauna Kea, Hawaii. MOSFIRE will provide NIR multi-object spectroscopy over a field of view of 6.1' x 6.1'. The reconfigurable mask allows the formation of 46 optical slits in a 267 x 267 mm2 field of view. The mechanism is an evolution of a former prototype designed by CSEM and qualified for the European Space Agency (ESA) as a candidate for the slit mask on NIRSpec for the James Webb Space Telescope (JWST). The CSU is designed to simultaneously displace masking bars across the field-of-view (FOV) to mask unwanted light. A set of 46 bar pairs are used to form the MOSFIRE focal plane mask. The sides of the bars are convoluted so that light is prevented from passing between adjacent bars. The slit length is fixed (5.1 mm) but the width is variable down to 200 μm with a slit positioning accuracy of +/- 18 μm. A two-bar prototype mechanism was designed, manufactured and cryogenically tested to validate the modifications from the JWST prototype. The working principle of the mechanism is based on an improved "inch-worm" stepping motion of 92 masking bars forming the optical mask. Original voice coil actuators are used to drive the various clutches. The design makes significant use of flexure structures.

  18. A comparison of minor trace gas retrievals from the Tropospheric Emission Spectrometer (TES) and the Infrared Atmospheric Sounding Interferometer (IASI)

    Science.gov (United States)

    Cady-Pereira, K. E.; Shephard, M. W.; Henze, D. K.; Millet, D. B.; Gombos, D.; Van Damme, M.; Clarisse, L.; Coheur, P. F.; Pommier, M.; Clerbaux, C.

    2014-12-01

    The advent of hyperspectral infrared instruments orbiting the Earth has allowed for detecting and measuring numerous trace gas species that play important roles in atmospheric chemistry and impact air quality, but for which there is a dearth of information on their distribution and temporal variability. Here we will present global and regional comparisons of measurements from the NASA TES and the European MetOp IASI instruments of three of these gases: ammonia (NH3), formic acid (HCOOH) and methanol (CH3OH). Ammonia is highly reactive and thus very variable in space and time, while the sources and sinks of methanol and formic acid are poorly quantified: thus space-based measurements have the potential of significantly increasing our knowledge of the emissions and distributions of these gases. IASI and TES have many similarities but some significant differences. TES has significantly higher spectral resolution (0.06 cm-1), and its equator crossing times are ~1:30 am and 1:30 pm, local time, while IASI has lower resolution (0.5 cm-1) and an earlier equator crossing time (9:30 am and 9:30 pm), which leads to lower thermal contrast; however IASI provides much greater temporal and spatial coverage due to its cross-track scanning. Added to the instrumental differences are the differences in retrieval algorithms. The IASI team uses simple but efficient methods to estimate total column amounts of the species above, while the TES team performs full optimal estimation retrievals. We will compare IASI and TES total column measurements averaged on a 2.5x2.5 degree global grid for each month in 2009, and we will examine the seasonal cycle in some regions of interest, such as South America, eastern China, and the Midwest and the Central Valley in the US. In regions where both datasets are in agreement this analysis will provide confidence that the results are robust and reliable. In regions where there is disagreement we will look for the causes of the discrepancies, which will

  19. Design of a Pushbroom Imaging Spectrometer that Exceeds AVIRIS Performance

    Science.gov (United States)

    Green, Robert O.

    2004-01-01

    This slide presentation reviews the design of a Pushbroom Imaging Spectrometer, that will exceed the performance of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). The approach for the AVIRIS-II instrument is reviewed as are the specifications for the new spectrometer. Even though the pushbroom spectrometer is inherently non-uniform, the design of the AVIRIS-II provides for uniformity. Spot diagrams at the slit and at the detector inside the 27micron box are presented. A few of the challenges in the mechanical design and the making of the slit are discussed. The specifications of the 6604A detector array are reviewed. Slides showing the expected Signal to Noise Ratio performance are presented.

  20. 傅里叶变换红外成像光谱仪非均匀性在线定标与校正研究%Study on Nonuniformity Online Calibration and Correction of Fourier Transform Infrared Imaging Spectrometer

    Institute of Scientific and Technical Information of China (English)

    殷世民; 应小凡; 陈洪波; 陈真诚; 相里斌

    2014-01-01

    Due to the particular structure of Fourier transform infrared imaging spectrometer, its nonuniformity online calibration and correction is always a technical problem that has not been solved in engineering. Based on brief review to the principle and algorithm of nonuniformity correction of IRFPA, through in-depth analysis of principle and structure of time modulation, space modulation type and time and space combined modulation type Fourier transform infrared imaging spectrometer, it is given that online method for non-uniformity calibration and correction of three types of Fourier transform infrared imaging spectrometer, which should establish a good technical foundation to on-orbit nonuniformity calibration and correction for Fourier transform infrared imaging spectrometer on satellite.%由于傅里叶变换红外成像光谱仪结构的特殊性,其非均匀性在线定标与校正在工程上一直没有得到有效解决。首先对IRFPA非均匀性校正的原理与算法进行了简要阐述,在此基础上,通过对时间调制型、空间调制型及时间空间联合调制型傅里叶变换红外成像光谱仪原理结构的深入分析,针对这三种制式的光谱仪,分别研究出了相应的非均匀性在线定标与校正的方法,为星载傅里叶变换红外成像光谱仪非均匀性的在轨定标奠定了良好的技术基础。

  1. Monolithic spectrometer

    Science.gov (United States)

    Rajic, Slobodan; Egert, Charles M.; Kahl, William K.; Snyder, Jr., William B.; Evans, III, Boyd M.; Marlar, Troy A.; Cunningham, Joseph P.

    1998-01-01

    A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays.

  2. Compact Grism Spectrometer

    Science.gov (United States)

    Teare, S. W.

    2003-05-01

    Many observatories and instrument builders are retrofitting visible and near-infrared spectrometers into their existing imaging cameras. Camera designs that reimage the focal plane and have the optical filters located in a pseudo collimated beam are ideal candidates for the addition of a spectrometer. One device commonly used as the dispersing element for such spectrometers is a grism. The traditional grism is constructed from a prism that has had a diffraction grating applied on one surface. The objective of such a design is to use the prism wedge angle to select the desired "in-line" or "zero-deviation" wavelength that passes through on axis. The grating on the surface of the prism provides much of the dispersion for the spectrometer. A grism can also be used in a "constant-dispersion" design which provides an almost linear spatial scale across the spectrum. In this paper we provide an overview of the development of a grism spectrometer for use in a near infrared camera and demonstrate that a compact grism spectrometer can be developed on a very modest budget that can be afforded at almost any facility. The grism design was prototyped using visible light and then a final device was constructed which provides partial coverage in the near infrared I, J, H and K astronomical bands using the appropriate band pass filter for order sorting. The near infrared grism presented here provides a spectral resolution of about 650 and velocity resolution of about 450 km/s. The design of this grism relied on a computer code called Xspect, developed by the author, to determine the various critical parameters of the grism. This work was supported by a small equipment grant from NASA and administered by the AAS.

  3. Greenhouse Observations of the Stratosphere and Troposphere (GHOST): a novel shortwave infrared spectrometer developed for the Global Hawk unmanned aerial vehicle

    Science.gov (United States)

    Humpage, Neil; Boesch, Hartmut; Palmer, Paul; Parr-Burman, Phil; Vick, Andy; Bezawada, Naidu; Black, Martin; Born, Andy; Pearson, David; Strachan, Jonathan; Wells, Martyn

    2014-05-01

    The tropospheric distribution of greenhouse gases (GHGs) is dependent on surface flux variations, atmospheric chemistry and transport processes over a wide range of spatial and temporal scales. Errors in assumed atmospheric transport can adversely affect surface flux estimates inferred from surface, aircraft or satellite observations of greenhouse gas concentrations using inverse models. We present a novel, compact shortwave infrared spectrometer (GHOST) for installation on the NASA Global Hawk unmanned aerial vehicle to provide tropospheric column observations of CO2, CO, CH4, H2O and HDO over the ocean to address the need for large-scale, simultaneous, finely resolved measurements of key GHGs. These species cover a range of lifetimes and source processes, and measurements of their tropospheric columns will reflect the vertically integrated signal of their vertical and horizontal transport within the troposphere. The primary science objectives of GHOST are to: 1) provide observations which can be used to test atmospheric transport models; 2) validate satellite observations of GHG column observations over oceans, thus filling a critical gap in current validation capabilities; and 3) complement in-situ tropopause transition layer tracer observations from other instrumentation on board the Global Hawk to provide a link between upper and lower troposphere concentration measurements. The GHOST spectrometer system comprises a target acquisition module (TAM), a fibre slicer and feed system, and a multiple order spectrograph. The TAM design utilises a gimbal behind an optical dome, which is programmed to direct solar radiation reflected by the ocean surface into a fibre optic bundle. The fibre slicer and feed system then splits the light into the four spectral bands using order sorting filters. The fibres corresponding to each band are arranged with a small sideways offset to correctly centre each spectrum on the detector array. The spectrograph design is unique in that a

  4. Facile and high spatial resolution ratio-metric luminescence thermal mapping in microfluidics by near infrared excited upconversion nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yu; Li, Shunbo; Wen, Weijia, E-mail: phwen@ust.hk [Department of Physics, KAUST-HKUST Joint Micro/Nanofluidic Laboratory, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Cao, Wenbin [Nano Science and Technology Program, Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

    2016-02-01

    A local area temperature monitor is important for precise control of chemical and biological processes in microfluidics. In this work, we developed a facile method to realize micron spatial resolution of temperature mapping in a microfluidic channel quickly and cost effectively. Based on the temperature dependent fluorescence emission of NaYF{sub 4}:Yb{sup 3+}, Er{sup 3+} upconversion nanoparticles (UCNPs) under near-infrared irradiation, ratio-metric imaging of UCNPs doped polydimethylsiloxane can map detailed temperature distribution in the channel. Unlike some reported strategies that utilize temperature sensitive organic dye (such as Rhodamine) to achieve thermal sensing, our method is highly chemically inert and physically stable without any performance degradation in long term operation. Moreover, this method can be easily scaled up or down, since the spatial and temperature resolution is determined by an optical imaging system. Our method supplied a simple and efficient solution for temperature mapping on a heterogeneous surface where usage of an infrared thermal camera was limited.

  5. Evaluation of infrared spectra analyses using a likelihood ratio approach: A practical example of spray paint examination.

    Science.gov (United States)

    Muehlethaler, Cyril; Massonnet, Geneviève; Hicks, Tacha

    2016-03-01

    Depending on the forensic disciplines and on the analytical techniques used, Bayesian methods of evaluation have been applied both as a two-step approach (first comparison, then evaluation) and as a continuous approach (comparison and evaluation in one step). However in order to use the continuous approach, the measurements have to be reliably summarized as a numerical value linked to the property of interest, which occurrence can be determined (e.g., refractive index measurement of glass samples). For paint traces analyzed by Fourier transform infrared spectroscopy (FTIR) however, the statistical comparison of the spectra is generally done by a similarity measure (e.g., Pearson correlation, Euclidean distance). Although useful, these measures cannot be directly associated to frequencies of occurrence of the chemical composition (binders, extenders, pigments). The continuous approach as described above is not possible, and a two-step evaluation, 1) comparison of the spectra and 2) evaluation of the results, is therefore the common practice reported in most of the laboratories. Derived from a practical question that arose during casework, a way of integrating the similarity measure between spectra into a continuous likelihood ratio formula was explored. This article proposes the use of a likelihood ratio approach with the similarity measure of infrared spectra of spray paints based on distributions of sub-populations given by the color and composition of spray paint cans. Taking into account not only the rarity of paint composition, but also the "quality" of the analytical match provides a more balanced evaluation given source or activity level propositions. We will demonstrate also that a joint statistical-expertal methodology allows for a more transparent evaluation of the results and makes a better use of current knowledge. Copyright © 2015 The Chartered Society of Forensic Sciences. Published by Elsevier Ireland Ltd. All rights reserved.

  6. The [CII]/[NII] far-infrared line ratio at z>5: extreme conditions for “normal” galaxies

    Science.gov (United States)

    Pavesi, Riccardo; Riechers, Dominik; Capak, Peter L.; Carilli, Chris Luke; Sharon, Chelsea E.; Stacey, Gordon J.; Karim, Alexander; Scoville, Nicholas; Smolcic, Vernesa

    2017-01-01

    Thanks to the Atacama Large (sub-)Millimeter Array (ALMA), observations of atomic far-infrared fine structure lines are a very productive way of measuring physical properties of the interstellar medium (ISM) in galaxies at high redshift, because they provide an unobscured view into the physical conditions of star formation. While the bright [CII] line has become a routine probe of the dynamical properties of the gas, its intensity needs to be compared to other lines in order to establish the physical origin of the emission. [NII] selectively traces the emission coming from the ionized fraction of the [CII]-emitting gas, offering insight into the phase structure of the ISM. Here we present ALMA measurements of [NII] 205 μm fine structure line emission from a representative sample of galaxies at z=5-6 spanning two orders of magnitude in star formation rate (SFR). Our results show at least two different regimes of ionized gas properties for galaxies in the first billion years of cosmic time, separated by their L[CII]/L[NII] ratio. First, we find extremely low [NII] emission compared to [CII] from a “typical” Lyman Break Galaxy (LBG-1), likely due to low dust content and reminiscent of local dwarfs. Second, the dusty Lyman Break Galaxy HZ10 and the extreme starburst AzTEC-3 show ionized gas fractions typical of local star-forming galaxies and show hints of spatial variations in their [CII]/[NII] line ratio. These observations of far-infrared lines in “normal” galaxies at z>5 yield some of the first constraints on ISM models for young galaxies in the first billion years of cosmic time and shed light on the observed evolution of the dust and gas properties.

  7. Comparison of laboratory calibrations of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) at the beginning and end of the first flight season

    Science.gov (United States)

    Vane, Gregg; Chrien, Thomas G.; Reimer, John H.; Green, Robert O.; Conel, James E.

    1988-01-01

    Spectral and radiometric calibrations of AVIRIS are described together with changes in instrument characteristics that occurred during the flight season. These changes include detachment of the optical fibers to two of the four AVIRIS spectrometers, degradation in the optical alignment of the spectrometers due to thermally induced and mechanical warpage, and breakage of a thermal blocking filter in one of the spectrometers. Means of improving the instrument are discussed.

  8. Infrared absorption of gaseous CH{sub 2}BrOO detected with a step-scan Fourier-transform absorption spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Yu-Hsuan [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Lee, Yuan-Pern, E-mail: yplee@mail.nctu.edu.tw [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China)

    2014-10-28

    CH{sub 2}BrOO radicals were produced upon irradiation, with an excimer laser at 248 nm, of a flowing mixture of CH{sub 2}Br{sub 2} and O{sub 2}. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record temporally resolved infrared (IR) absorption spectra of reaction intermediates. Transient absorption with origins at 1276.1, 1088.3, 961.0, and 884.9 cm{sup −1} are assigned to ν{sub 4} (CH{sub 2}-wagging), ν{sub 6} (O–O stretching), ν{sub 7} (CH{sub 2}-rocking mixed with C–O stretching), and ν{sub 8} (C–O stretching mixed with CH{sub 2}-rocking) modes of syn-CH{sub 2}BrOO, respectively. The assignments were made according to the expected photochemistry and a comparison of observed vibrational wavenumbers, relative IR intensities, and rotational contours with those predicted with the B3LYP/aug-cc-pVTZ method. The rotational contours of ν{sub 7} and ν{sub 8} indicate that hot bands involving the torsional (ν{sub 12}) mode are also present, with transitions 7{sub 0}{sup 1}12{sub v}{sup v} and 8{sub 0}{sup 1}12{sub v}{sup v}, v = 1–10. The most intense band (ν{sub 4}) of anti-CH{sub 2}BrOO near 1277 cm{sup −1} might have a small contribution to the observed spectra. Our work provides information for directly probing gaseous CH{sub 2}BrOO with IR spectroscopy, in either the atmosphere or laboratory experiments.

  9. Measuring oxygen yields of a thermal conversion/elemental analyzer-isotope ratio mass spectrometer for organic and inorganic materials through injection of CO.

    Science.gov (United States)

    Yin, Xijie; Chen, Zhigang

    2014-12-01

    The thermal conversion/elemental analyzer-isotope ratio mass spectrometer (TC/EA-IRMS) is widely used to measure the δ(18) O value of various substances. A premise for accurate δ(18) O measurement is that the oxygen in the sample can be converted into carbon monoxide (CO) quantitatively or at least proportionally. Therefore, a precise method to determine the oxygen yield of TC/EA-IRMS measurements is needed. Most studies have used the CO peak area obtained from a known amount of a solid reference material (for example, benzoic acid) to calibrate the oxygen yield of the sample. Although it was assumed that the oxygen yield of the solid reference material is 100%, no direct evidence has been provided. As CO is the analyte gas for δ(18) O measurement by IRMS, in this study, we use a six-port valve to inject CO gas into the TC/EA. The CO is carried to the IRMS by the He carrier gas and the CO peak area is measured by the IRMS. The CO peak area thus obtained from a known amount of the injected CO is used to calibrate the oxygen yield of the sample. The oxygen yields of commonly used organic and inorganic reference materials such as benzoic acid (C6 H5 COOH), silver phosphate (Ag3 PO4 ), calcium carbonate (CaCO3 ) and silicon dioxide (SiO2 ) are investigated at different reactor temperatures and sample sizes. We obtained excellent linear correlation between the peak area for the injected CO and its oxygen atom amount. C6 H5 COOH has the highest oxygen yield, followed by Ag3 PO4 , CaCO3 and SiO2 . The oxygen yields of TC/EA-IRMS are less than 100% for both organic and inorganic substances, but the yields are relatively stable at the specified reactor temperature and for a given quantity of sample. Copyright © 2014 John Wiley & Sons, Ltd.

  10. Implementation of intensity ratio change and line-of-sight rate change algorithms for imaging infrared trackers

    Science.gov (United States)

    Viau, C. R.

    2012-06-01

    The use of the intensity change and line-of-sight (LOS) change concepts have previously been documented in the open-literature as techniques used by non-imaging infrared (IR) seekers to reject expendable IR countermeasures (IRCM). The purpose of this project was to implement IR counter-countermeasure (IRCCM) algorithms based on target intensity and kinematic behavior for a generic imaging IR (IIR) seeker model with the underlying goal of obtaining a better understanding of how expendable IRCM can be used to defeat the latest generation of seekers. The report describes the Intensity Ratio Change (IRC) and LOS Rate Change (LRC) discrimination techniques. The algorithms and the seeker model are implemented in a physics-based simulation product called Tactical Engagement Simulation Software (TESS™). TESS is developed in the MATLAB®/Simulink® environment and is a suite of RF/IR missile software simulators used to evaluate and analyze the effectiveness of countermeasures against various classes of guided threats. The investigation evaluates the algorithm and tests their robustness by presenting the results of batch simulation runs of surface-to-air (SAM) and air-to-air (AAM) IIR missiles engaging a non-maneuvering target platform equipped with expendable IRCM as self-protection. The report discusses how varying critical parameters such track memory time, ratio thresholds and hold time can influence the outcome of an engagement.

  11. Near-infrared spectroscopy of M dwarfs. IV. A preliminary survey on the carbon isotopic ratio in M dwarfs*

    Science.gov (United States)

    Tsuji, Takashi

    2016-10-01

    Carbon isotopic ratios are estimated in 48 M dwarfs based on the medium resolution near infrared spectra (λ/Δ λ ≈ 20000) of the 13CO (3,1) band. We find clear evidence for the presence of a 13CO feature for the first time in the spectra of M dwarfs. Spectral resolution of our observed data, however, is not high enough to analyze the 13CO feature directly. Instead, we compare the observed spectrum with synthetic spectra assuming 12C/13C = 10, 25, 50, 100, and 200 for each of 48 M dwarfs and estimate the best possible 12C/13C ratio by chi-square analysis. The resulting 12C/13C ratios in M dwarfs distribute from 39 to a lower limit of 200. The mean value of 31 M dwarfs for which 12C/13C ratios are determined (i.e., excluding those with the lower limit only) is (12C/13C)dM = 87 ± 21 (p.e.), and that of 48 M dwarfs including those with the lower limit of 200 is (12C/13C)dM > 127 ± 41 (p.e.). These results are somewhat larger than the 12C/13C ratio of the present interstellar matter (ISM) determined from the molecular lines observed in the millimeter and optical wavelength regions. Since the amount of 13C in the ISM has increased with time due to mass loss from evolved stars, the 12C/13C ratios in M dwarfs, reflecting those of the past ISM, should be larger than those of the present ISM. In M dwarfs, log 13C/12C plotted against log AC shows a large scatter without clear dependence on the metallicity. This result shows a marked contrast to log 16O/12C (= log AO/AC) plotted against log AC, which shows a rather tight correlation with a larger value at the lower metallicity. Such a contrast can be a natural consequence of 16O and 12C being primary products in stellar nuclear synthesis while 13C is a secondary product, at least partly.

  12. Infrared

    Science.gov (United States)

    Vollmer, M.

    2013-11-01

    'Infrared' is a very wide field in physics and the natural sciences which has evolved enormously in recent decades. It all started in 1800 with Friedrich Wilhelm Herschel's discovery of infrared (IR) radiation within the spectrum of the Sun. Thereafter a few important milestones towards widespread use of IR were the quantitative description of the laws of blackbody radiation by Max Planck in 1900; the application of quantum mechanics to understand the rotational-vibrational spectra of molecules starting in the first half of the 20th century; and the revolution in source and detector technologies due to micro-technological breakthroughs towards the end of the 20th century. This has led to much high-quality and sophisticated equipment in terms of detectors, sources and instruments in the IR spectral range, with a multitude of different applications in science and technology. This special issue tries to focus on a few aspects of the astonishing variety of different disciplines, techniques and applications concerning the general topic of infrared radiation. Part of the content is based upon an interdisciplinary international conference on the topic held in 2012 in Bad Honnef, Germany. It is hoped that the information provided here may be useful for teaching the general topic of electromagnetic radiation in the IR spectral range in advanced university courses for postgraduate students. In the most general terms, the infrared spectral range is defined to extend from wavelengths of 780 nm (upper range of the VIS spectral range) up to wavelengths of 1 mm (lower end of the microwave range). Various definitions of near, middle and far infrared or thermal infrared, and lately terahertz frequencies, are used, which all fall in this range. These special definitions often depend on the scientific field of research. Unfortunately, many of these fields seem to have developed independently from neighbouring disciplines, although they deal with very similar topics in respect of the

  13. Determination of enhancement ratios of HCOOH relative to CO in biomass burning plumes by the Infrared Atmospheric Sounding Interferometer (IASI)

    Science.gov (United States)

    Pommier, Matthieu; Clerbaux, Cathy; Coheur, Pierre-Francois

    2017-09-01

    Formic acid (HCOOH) concentrations are often underestimated by models, and its chemistry is highly uncertain. HCOOH is, however, among the most abundant atmospheric volatile organic compounds, and it is potentially responsible for rain acidity in remote areas. HCOOH data from the Infrared Atmospheric Sounding Interferometer (IASI) are analyzed from 2008 to 2014 to estimate enhancement ratios from biomass burning emissions over seven regions. Fire-affected HCOOH and CO total columns are defined by combining total columns from IASI, geographic location of the fires from Moderate Resolution Imaging Spectroradiometer (MODIS), and the surface wind speed field from the European Centre for Medium-Range Weather Forecasts (ECMWF). Robust correlations are found between these fire-affected HCOOH and CO total columns over the selected biomass burning regions, allowing the calculation of enhancement ratios equal to 7.30 × 10-3 ± 0.08 × 10-3 mol mol-1 over Amazonia (AMA), 11.10 × 10-3 ± 1.37 × 10-3 mol mol-1 over Australia (AUS), 6.80 × 10-3 ± 0.44 × 10-3 mol mol-1 over India (IND), 5.80 × 10-3 ± 0.15 × 10-3 mol mol-1 over Southeast Asia (SEA), 4.00 × 10-3 ± 0.19 × 10-3 mol mol-1 over northern Africa (NAF), 5.00 × 10-3 ± 0.13 × 10-3 mol mol-1 over southern Africa (SAF), and 4.40 × 10-3 ± 0.09 × 10-3 mol mol-1 over Siberia (SIB), in a fair agreement with previous studies. In comparison with referenced emission ratios, it is also shown that the selected agricultural burning plumes captured by IASI over India and Southeast Asia correspond to recent plumes where the chemistry or the sink does not occur. An additional classification of the enhancement ratios by type of fuel burned is also provided, showing a diverse origin of the plumes sampled by IASI, especially over Amazonia and Siberia. The variability in the enhancement ratios by biome over the different regions show that the levels of HCOOH and CO do not only depend on the fuel types.

  14. Uncertainty Evaluation of the Ratioes of Uranium Isotope Adundances Measured by Thermal Ionization Mass Spectrometer MAT-261%MAT261热表面电离质谱计测量数据不确定度评定

    Institute of Scientific and Technical Information of China (English)

    徐江; 朱凤蓉; 李志明

    2004-01-01

    The data of uranium isotope abundance ratios measured by thermal ionization mass spectrometer MAT-261 were analyzed in the three aspects including distribution function, correlation and uncertainty. The measurement data were confirmed to be normal distribution. Uncertainty and correlation of the isotope abundance ratios measured by MAT-261 in the certified uranium sample were investigated. The conclusion obtained indicated that, the correlation only between abundance ratios R5/8 and R4/8 is strong, but the others is weak for the enriched uranium sample; For the natural uranium sample, the correlation among all abundance ratios is weak. On this base, the uncertainty of all abundance ratios measured by MAT-261 had been evaluated.

  15. Image Monitoring of Pharmaceutical Blending Processes and the Determination of an End Point by Using a Portable Near-Infrared Imaging Device Based on a Polychromator-Type Near-Infrared Spectrometer with a High-speed and High-Resolution Photo Diode Array Detector

    Directory of Open Access Journals (Sweden)

    Kodai Murayama

    2015-03-01

    Full Text Available In the present study we have developed a new version (ND-NIRs of a polychromator-type near-infrared (NIR spectrometer with a high-resolution photo diode array detector, which we built before (D-NIRs. The new version has four 5 W halogen lamps compared with the three lamps for the older version. The new version also has a condenser lens with a shorter focal point length. The increase in the number of the lamps and the shortening of the focal point of the condenser lens realize high signal-to-noise ratio and high-speed NIR imaging measurement. By using the ND-NIRs we carried out the in-line monitoring of pharmaceutical blending and determined an end point of the blending process. Moreover, to determinate a more accurate end point, a NIR image of the blending sample was acquired by means of a portable NIR imaging device based on ND-NIRs. The imaging result has demonstrated that the mixing time of 8 min is enough for homogeneous mixing. In this way the present study has demonstrated that ND-NIRs and the imaging system based on a ND-NIRs hold considerable promise for process analysis.

  16. Spectral analysis software improves confidence in plant and soil water stable isotope analyses performed by isotope ratio infrared spectroscopy (IRIS).

    Science.gov (United States)

    West, A G; Goldsmith, G R; Matimati, I; Dawson, T E

    2011-08-30

    Previous studies have demonstrated the potential for large errors to occur when analyzing waters containing organic contaminants using isotope ratio infrared spectroscopy (IRIS). In an attempt to address this problem, IRIS manufacturers now provide post-processing spectral analysis software capable of identifying samples with the types of spectral interference that compromises their stable isotope analysis. Here we report two independent tests of this post-processing spectral analysis software on two IRIS systems, OA-ICOS (Los Gatos Research Inc.) and WS-CRDS (Picarro Inc.). Following a similar methodology to a previous study, we cryogenically extracted plant leaf water and soil water and measured the δ(2)H and δ(18)O values of identical samples by isotope ratio mass spectrometry (IRMS) and IRIS. As an additional test, we analyzed plant stem waters and tap waters by IRMS and IRIS in an independent laboratory. For all tests we assumed that the IRMS value represented the "true" value against which we could compare the stable isotope results from the IRIS methods. Samples showing significant deviations from the IRMS value (>2σ) were considered to be contaminated and representative of spectral interference in the IRIS measurement. Over the two studies, 83% of plant species were considered contaminated on OA-ICOS and 58% on WS-CRDS. Post-analysis, spectra were analyzed using the manufacturer's spectral analysis software, in order to see if the software correctly identified contaminated samples. In our tests the software performed well, identifying all the samples with major errors. However, some false negatives indicate that user evaluation and testing of the software are necessary. Repeat sampling of plants showed considerable variation in the discrepancies between IRIS and IRMS. As such, we recommend that spectral analysis of IRIS data must be incorporated into standard post-processing routines. Furthermore, we suggest that the results from spectral analysis be

  17. Detection of Internal Leaf Structure Deterioration Using a New Spectral Ratio Index in the Near-Infrared Shoulder Region

    Institute of Scientific and Technical Information of China (English)

    LIU Liang-yun; HUANG Wen-jiang; PU Rui-liang; WANG Ji-hua

    2014-01-01

    Spectral relfectance in the near-infrared (NIR) shoulder (750-900 nm) region is affected by internal leaf structure, but it has rarely been investigated. In this study, a dehydration treatment and three paraquat herbicide applications were conducted to explore how spectral relfectance and shape in the NIR shoulder region responded to various stresses. A new spectral ratio index in the NIR shoulder region (NSRI), deifned by a simple ratio of relfectance at 890 nm to relfectance at 780 nm, was proposed for assessing leaf structure deterioration. Firstly, a wavelength-independent increase in spectral relfectance in the NIR shoulder region was observed from the mature leaves with slight dehydration. An increase in spectral slope in the NIR shoulder would be expected only when water stress developed sufifciently to cause severe leaf dehydration resulting in an alteration in cell structure. Secondly, the alteration of leaf cell structure caused by Paraquat herbicide applications resulted in a wavelength-dependent variation of spectral relfectance in the NIR shoulder region. The NSRI in the NIR shoulder region increased signiifcantly under an herbicide application. Although the dehydration process also occurred with the herbicide injury, NSRI is more sensitive to herbicide injury than the water-related indices (water index and normalized difference water index) and normalized difference vegetation index. Finally, the sensitivity of NSRI to stripe rust in winter wheat was examined, yielding a determination coefifcient of 0.61, which is more signiifcant than normalized difference vegetation index (NDVI), water index (WI) and normalized difference water index (NDWI), with a determination coefifcient of 0.45, 0.36 and 0.13, respectively. In this study, all experimental results demonstrated that NSRI will increase with internal leaf structure deterioration, and it is also a sensitive spectral index for herbicide injury or stripe rust in winter wheat.

  18. Ground-based Measurements of Vertical Profiles and Columns of Atmospheric Trace Gases Over Toronto Using a New High-Resolution Fourier Transform Infrared Spectrometer

    Science.gov (United States)

    Wiacek, A.; Yashcov, D.; Strong, K.; Boudreau, L.; Rochette, L.; Roy, C.

    2002-12-01

    The University of Toronto Atmospheric Observatory (TAO) has recently been established at Toronto, Canada. TAO includes several instruments, with a DA8 Fourier Transform Spectrometer (DA8 FTS, manufactured by ABB Bomem Inc., Québec, Canada) serving as the primary instrument at the facility. The geographic position of TAO (43.66°N, 79.40°W) makes it well suited for long-term measurements of mid-latitude stratospheric ozone and related species, while its urban setting enables measurements of tropospheric pollution. The DA8 FTS is based on a Michelson interferometer with a maximum optical path difference of 250 cm, providing a maximum unapodized resolution of 0.0026 cm-1. It is currently equipped with KBr and CaF2 beamsplitters, and InSb and HgCdTe detectors, for coverage of the spectral range from 700 to 4100 cm-1. A new heliostat (manufactured by Aim Controls Inc., California, USA) provides active solar tracking, collecting the incoming solar radiation and directing it into the FTS. The TAO DA8 FTS incorporates a new optical design recently developed by ABB Bomem Inc., which results in a fixed optical axis through the beamsplitter (and a fixed focal point on the detector) as well as a more stable modulation efficiency. The new instrument optics will be discussed. Next, the performance of the instrument will be examined in the context of standard NDSC (Network for the Detection of Stratospheric Change) trace gas column and vertical profile retrieval techniques, which use least squares fitting algorithms (SFIT, SFIT2). TAO has been operational (weather permitting) since October 2001. We have been retrieving columns and vertical profiles of HCl, HF, CH4, OCS, C2H6, CO, N2O and NO2 since May 2002. A detailed error analysis of retrieved columns and vertical profiles has been undertaken for the above species. Future plans for the TAO FTS include comparing our measurements with satellite measurements made by MOPITT, OSIRIS, and the upcoming ACE and MAESTRO instruments

  19. Determination of enhancement ratios of HCOOH relative to CO in biomass burning plumes by the Infrared Atmospheric Sounding Interferometer (IASI

    Directory of Open Access Journals (Sweden)

    M. Pommier

    2017-09-01

    Full Text Available Formic acid (HCOOH concentrations are often underestimated by models, and its chemistry is highly uncertain. HCOOH is, however, among the most abundant atmospheric volatile organic compounds, and it is potentially responsible for rain acidity in remote areas. HCOOH data from the Infrared Atmospheric Sounding Interferometer (IASI are analyzed from 2008 to 2014 to estimate enhancement ratios from biomass burning emissions over seven regions. Fire-affected HCOOH and CO total columns are defined by combining total columns from IASI, geographic location of the fires from Moderate Resolution Imaging Spectroradiometer (MODIS, and the surface wind speed field from the European Centre for Medium-Range Weather Forecasts (ECMWF. Robust correlations are found between these fire-affected HCOOH and CO total columns over the selected biomass burning regions, allowing the calculation of enhancement ratios equal to 7.30  ×  10−3 ± 0.08  ×  10−3 mol mol−1 over Amazonia (AMA, 11.10  ×  10−3 ± 1.37  ×  10−3 mol mol−1 over Australia (AUS, 6.80  ×  10−3 ± 0.44  ×  10−3 mol mol−1 over India (IND, 5.80  ×  10−3 ± 0.15  ×  10−3 mol mol−1 over Southeast Asia (SEA, 4.00  ×  10−3 ± 0.19  ×  10−3 mol mol−1 over northern Africa (NAF, 5.00  ×  10−3 ± 0.13  ×  10−3 mol mol−1 over southern Africa (SAF, and 4.40  ×  10−3 ± 0.09  ×  10−3 mol mol−1 over Siberia (SIB, in a fair agreement with previous studies. In comparison with referenced emission ratios, it is also shown that the selected agricultural burning plumes captured by IASI over India and Southeast Asia correspond to recent plumes where the chemistry or the sink does not occur. An additional classification of the enhancement ratios by type of fuel burned is also provided, showing a diverse

  20. Sensitive measurements of trace gas of formaldehyde using a mid-infrared laser spectrometer with a compact multi-pass cell

    Science.gov (United States)

    Tanaka, Kotaro; Miyamura, Kai; Akishima, Kazushi; Tonokura, Kenichi; Konno, Mitsuru

    2016-11-01

    A compact multi-pass cell with a pair of cylindrical mirrors for sensitive detection of trace gases in emission from combustion was constructed. The cell path-length was 9.8 m and its volume was 0.13 L. Each mirror shape was a square with a side length of 25.4 mm and the mirrors were placed 100 mm apart. The cell was applied to detection of formaldehyde (HCHO), which is formed during fuel combustion and is harmful to the environment. The direct absorption spectrum in the range 2979.06-2981.2 cm-1 was recorded with a mid-infrared distributed feedback (DFB) interband cascade laser. The recorded spectrum of HCHO was in good agreement with a spectrum simulated using the HITRAN 2012 database. An absorption line at 2979.663 cm-1 (4.26 × 10-21 cm2 molecule-1 cm-1, ν5, 1184-1073), which showed the strongest absorption in the emission frequency range of the DFB interband cascade laser, was selected for HCHO detection. We also confirmed that there were no interferences of absorption peaks of major combustion products in the selected HCHO absorption peaks. At a signal-to-noise ratio of two and 3 kPa using 2f wavelength modulation spectroscopy at less than 1 MHz bandwidth, the limit of detection for HCHO was 73 ppb by volume.

  1. Progress on characterization of a dualband IR imaging spectrometer

    Science.gov (United States)

    Beecken, Brian P.; LeVan, Paul D.; Lindh, Cory; Johnson, Randall S.

    2008-04-01

    A dualband infrared focal plane array is the central component of a compact, low mass, multispectral imaging spectrometer with perfect spectral registration. The prototype spectrometer design uses a grating blaze chosen to be efficient over both 3.75-6.05 and 7.5-12.1 μm, although the mercury cadmium telluride focal plane array limits the bandwidths with cutoff wavelengths near 5.2 and 10.5 μm. The spectrometer has been spectrally calibrated with flooded blackbody illumination and offset and gain corrections have been performed. The wavelength resolution is +/-0.024 μm in the MWIR and +/-0.083 μm in the LWIR, however this limitation is caused by the calibration method and not by the design. The potential for determining the temperature of a blackbody or greybody from the ratio of two narrow wavebands has been demonstrated.

  2. A STUDY ON CARBON ISOTOPE OF CO2 AND CH4 IN WESTERN DIENG PLATEU BY GAS CHROMATOGRAPHY- ISOTOPE RATIO MASS SPECTROMETER (GC-IRMS

    Directory of Open Access Journals (Sweden)

    Hanik Humaida

    2010-06-01

    Full Text Available The carbon isotope can be used to evaluate volcanism phenomenon of volcano. The study of carbon isotope of CO2 and CH4 was carried out in western Dieng Plateau by mass-spectrometer. Before analysis, sampel was separated by gas chromatography using a Porapak-Q column and a FID (Flame Ionization Detector detector. The gas was oxidized by copper oxide at 850oC before being ionized in mass-spectrometer for isotope analysis. The CO2 content in Candradimuka crater (-4.10 O/OO, indicated that the gas may be as volcanic gas. The other CO2 from Sumber and western Gua Jimat, had isotope value  of -10.05 and -12.07 O/OO, respectively, indicating contamination from crustal and subduction material. The carbon isotope of CH4 gas from Pancasan village was -63.42 O/OO, that may be categorized as biogenic gas.   Keywords: isotope, CO2, CH4, Dieng.

  3. Non-Contact Measurement of the Spectral Emissivity through Active/Passive Synergy of CO₂ Laser at 10.6 µm and 102F FTIR (Fourier Transform Infrared) Spectrometer.

    Science.gov (United States)

    Zhang, Ren-Hua; Su, Hong-Bo; Tian, Jing; Mi, Su-Juan; Li, Zhao-Liang

    2016-06-24

    In the inversion of land surface temperature (LST) from satellite data, obtaining the information on land surface emissivity is most challenging. How to solve both the emissivity and the LST from the underdetermined equations for thermal infrared radiation is a hot research topic related to quantitative thermal infrared remote sensing. The academic research and practical applications based on the temperature-emissivity retrieval algorithms show that directly measuring the emissivity of objects at a fixed thermal infrared waveband is an important way to close the underdetermined equations for thermal infrared radiation. Based on the prior research results of both the authors and others, this paper proposes a new approach of obtaining the spectral emissivity of the object at 8-14 µm with a single-band CO₂ laser at 10.6 µm and a 102F FTIR spectrometer. Through experiments, the spectral emissivity of several key samples, including aluminum plate, iron plate, copper plate, marble plate, rubber sheet, and paper board, at 8-14 µm is obtained, and the measured data are basically consistent with the hemispherical emissivity measurement by a Nicolet iS10 FTIR spectrometer for the same objects. For the rough surface of materials, such as marble and rusty iron, the RMSE of emissivity is below 0.05. The differences in the field of view angle and in the measuring direction between the Nicolet FTIR method and the method proposed in the paper, and the heterogeneity in the degree of oxidation, polishing and composition of the samples, are the main reasons for the differences of the emissivities between the two methods.

  4. Non-Contact Measurement of the Spectral Emissivity through Active/Passive Synergy of CO2 Laser at 10.6 µm and 102F FTIR (Fourier Transform Infrared) Spectrometer

    Science.gov (United States)

    Zhang, Ren-Hua; Su, Hong-Bo; Tian, Jing; Mi, Su-Juan; Li, Zhao-Liang

    2016-01-01

    In the inversion of land surface temperature (LST) from satellite data, obtaining the information on land surface emissivity is most challenging. How to solve both the emissivity and the LST from the underdetermined equations for thermal infrared radiation is a hot research topic related to quantitative thermal infrared remote sensing. The academic research and practical applications based on the temperature-emissivity retrieval algorithms show that directly measuring the emissivity of objects at a fixed thermal infrared waveband is an important way to close the underdetermined equations for thermal infrared radiation. Based on the prior research results of both the authors and others, this paper proposes a new approach of obtaining the spectral emissivity of the object at 8–14 µm with a single-band CO2 laser at 10.6 µm and a 102F FTIR spectrometer. Through experiments, the spectral emissivity of several key samples, including aluminum plate, iron plate, copper plate, marble plate, rubber sheet, and paper board, at 8–14 µm is obtained, and the measured data are basically consistent with the hemispherical emissivity measurement by a Nicolet iS10 FTIR spectrometer for the same objects. For the rough surface of materials, such as marble and rusty iron, the RMSE of emissivity is below 0.05. The differences in the field of view angle and in the measuring direction between the Nicolet FTIR method and the method proposed in the paper, and the heterogeneity in the degree of oxidation, polishing and composition of the samples, are the main reasons for the differences of the emissivities between the two methods. PMID:27347964

  5. Digital filter method of oversampling Fourier transform infrared spectrometer%过采样型傅里叶红外光谱仪的数字滤波方法

    Institute of Scientific and Technical Information of China (English)

    任利兵; 尉昊赟; 李岩

    2012-01-01

    The frequency response range of infrared detector in Fourier transform infrared spectrometer extends from dozens of Hz to some MHz generally. Because of wide frequency response, the measured signal will be easily blurred by lower and higher frequency noise from ambient. Noise can deform the real infrared interference signal. Compared with traditional Fourier transform infrared spectrometer, the oversampling one seems like to put the equal-spacing sampling procedure into computer. Therefore, it will be possible to lay a digital filter after the oversampling infrared interference signal. Based on evaluation of effective frequency response range of infrared interference signal, the design method of a Buttworth bandpass digital filter was illustrated. With this designed filter, the noise of oversampling infrared interference signal could be filtered. The experimental results show that the designed filter can effectively filter higher and lower noise to keep real spectral signal. Additionally, the digital filter is easier and more flexible to design than analog one.%傅里叶红外光谱仪使用的红外探测器频率响应范围通常为几十Hz到数MHz,这使得探测器直接接收的干涉信号中很容易混入环境噪声,引起真实干涉信号的畸变.过采样型傅里叶红外光谱仪等同于将传统光谱仪的等光程间隔采样过程“搬移”到计算机内,因此,理论上允许使用数字滤波器代替模拟滤波器对红外干涉信号降噪.在分析过采样型傅里叶红外光谱仪红外干涉信号有效频率范围的基础上,详述了适用于过采样型傅里叶红外光谱仪的巴特沃斯数字带通滤波器的设计方法,并应用设计的滤波器对过采样的红外干涉信号进行了降噪研究.结果表明:数字滤波的方法能有效去除红外干涉信号中的高、低频噪声,保留真实的光谱信号,在使用上也比模拟滤波更加灵活、便捷.

  6. Development of a reflectron time-of-flight mass spectrometer for non-destructive analysis of isotope ratios in irradiated B4C pellets--Test measurements on an unirradiated control rod pellet

    Science.gov (United States)

    Manoravi, P.; Joseph, M.; Sivakumar, N.

    2008-09-01

    A laser mass spectrometric facility is developed using a home-built reflectron time-of-flight mass spectrometer (RTOFMS) to analyze the boron isotopic ratio 10B/11B in the irradiated B4C pellets of the FBTR control rod. Compared to other mass spectrometry-based methods, the present method is practically non-destructive and makes it relatively easier to handle irradiated (radioactive) B4C pellets through remote operation. The results with inactive samples indicate that the method yields 10B percentage values, accurate to within ±1%.

  7. Comparative Variable Temperature Studies of Polyamide II with a Benchtop Fourier Transform and a Miniature Handheld Near-Infrared Spectrometer Using 2D-COS and PCMW-2D Analysis.

    Science.gov (United States)

    Unger, Miriam; Pfeifer, Frank; Siesler, Heinz W

    2016-07-01

    The main objective of this communication is to compare the performance of a miniaturized handheld near-infrared (NIR) spectrometer with a benchtop Fourier transform near-infrared (FT-NIR) spectrometer. Generally, NIR spectroscopy is an extremely powerful analytical tool to study hydrogen-bonding changes of amide functionalities in solid and liquid materials and therefore variable temperature NIR measurements of polyamide II (PAII) have been selected as a case study. The information content of the measurement data has been further enhanced by exploiting the potential of two-dimensional correlation spectroscopy (2D-COS) and the perturbation correlation moving window two-dimensional (PCMW2D) evaluation technique. The data provide valuable insights not only into the changes of the hydrogen-bonding structure and the recrystallization of the hydrocarbon segments of the investigated PAII but also in their sequential order. Furthermore, it has been demonstrated that the 2D-COS and PCMW2D results derived from the spectra measured with the miniaturized NIR instrument are equivalent to the information extracted from the data obtained with the high-performance FT-NIR instrument.

  8. Optical Design of Spaceborne Shortwave Infrared Imaging Spectrometer with Wide Field of View%星载大视场短波红外成像光谱仪光学设计

    Institute of Scientific and Technical Information of China (English)

    薛庆生; 林冠宇; 宋克非

    2011-01-01

    Based on the requirements of shotwave infrared imaging spectrometer with wide field of view,considering the restrictive off-the-shelf detectors, a split field of view (FOV) method was developed. The principle of split field of view was analyzed. A spaceborne shortwave infrared imaging spectrometer with wide field of view was designed using the method. The imaging spectrometer are composed of a 11.42°telecentric off-axis three-mirror anastigmatic telescope and two offner convex grating spectral imaging system. Ray tracing, optimization and analyzing were performed by CODE V and ZEMAX software. The analyzed results demonstrate that the modulation transfer function for different spectral band is more than 0.7 which satisfies the pre-designed requirement.%根据大视场短波红外成像光谱仪的要求,考虑到市售探测器的限制,提出了视场分离的方法,分析了视场分离方法的原理.利用此方法设计了一个星载大视场短波红外成像光谱仪光学系统,该系统由11.42°远心离轴三反消像散前置望远系统和2个Offner凸面光栅光谱成像系统组成,运用光学设计软件CODE V和ZEMAX对成像光谱仪光学系统进行了光线追迹和优化,并对设计结果进行了分析,分析结果表明,光学系统在各个谱段的光学传递函数均达到0.7以上,完全满足设计指标要求.

  9. DESIGN, FABRICATION, ASSEMBLY AND BENCH TESTING OF A TEXACO INFRARED RATIO PYROMETER SYSTEM FOR THE MEASUREMENT OF REACTION CHAMBER TEMPERATURE

    Energy Technology Data Exchange (ETDEWEB)

    Tom Leininger

    2001-03-31

    Reliable measurement of gasifier reaction chamber temperature is important for the proper operation of slagging, entrained-flow gasification processes. Historically, thermocouples have been used as the main measurement technique, with the temperature inferred from syngas methane concentration being used as a backup measurement. While these have been sufficient for plant operation in many cases, both techniques suffer from limitations. The response time of methane measurements is too slow to detect rapid upset conditions, and thermocouples are subject to long-term drift, as well as slag attack, which eventually leads to failure of the thermocouple. Texaco's Montebello Technology Center (MTC) has developed an infrared ratio pyrometer system for measuring gasifier reaction chamber temperature. This system has a faster response time than both methane and thermocouples, and has been demonstrated to provide reliable temperature measurements for longer periods of time when compared to thermocouples installed in the same MTC gasifier. In addition, the system can be applied to commercial gasifiers without any significant scale-up issues. The major equipment items, the purge system, and the safety shutdown system in a commercial plant are essentially identical to the prototypes at MTC. The desired result of this DOE program is ''a bench-scale prototype, either assembled or with critical components (laboratory) tested in a convincing manner.'' The prototype of the pyrometer system (including gasifier optical access port) that was designed, assembled and tested for this program, has had previous prototypes that have been built and successfully tested under actual coal and coke gasification conditions in three pilot units at MTC. It was the intent of the work performed under the auspices of this program to review and update the existing design, and to fabricate and bench test an updated system that can be field tested in one or more commercial gasifiers

  10. Uncooled near- and mid-IR spectrometer engine. Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Agiltron proposes to develop an extremely compact and high sensitivity uncooled near- and mid-infrared (NMIR) spectrometer engine for planetary compositional...

  11. Imaging spectrometer for fugitive gas leak detection

    Science.gov (United States)

    Hinnrichs, Michele

    1999-12-01

    Under contract to the U.S. Air Force and Navy, Pacific Advanced Technology has developed a very sensitive infrared imaging spectrometer that can perform remote imaging and spectro-radiometry. One of the most exciting applications for this technology is in the remote monitoring of smoke stack emissions and fugitive leaks. To date remote continuous emission monitoring (CEM) systems have not been approved by the EPA, however, they are under consideration. If the remote sensing technology is available with the sensitivity to monitor emission at the required levels and man portable it can reduce the cost and improve the reliability of performing such measurements. Pacific Advanced Technology (PAT) believes that it currently has this technology available to industry. This paper will present results from a field test where gas vapors during a refueling process were imaged and identified. In addition images of propane from a leaking stove will be presented. We at PAT have developed a real time image processing board that enhances the signal to noise ratio of low contrast gases and makes them easily viewable using the Image Multispectral Sensing (IMSS) imaging spectrometer. The IMSS imaging spectrometer is the size of a camcorder. Currently the data is stored in a Notebook computer thus allowing the system to be easily carried into power plants to look for fugitive leaks. In the future the IMSS will have an embedded processor and DSP and will be able to transfer data over an Ethernet link.

  12. A transportable spectrometer for in situ and local measurements of iodine monoxide at mixing ratios in the 10-14 range

    Science.gov (United States)

    Méjean, Guillaume; Grilli, Roberto; Abd Alrahman, Chadi; Ventrillard, Irène; Kassi, Samir; Romanini, Daniele

    2012-06-01

    We present a robust, compact, and transportable instrument that measures the iodine monoxide atmospheric radical at extremely low concentration, down to 40 ppqv (parts per quadrillion by volume, 1:1015). As nitrogen dioxide is strongly absorbed in the same spectral region it could be simultaneously measured down to 4 pptv (parts per trillion by volume, 1:1012). Relying on "mode locked cavity-enhanced absorption spectroscopy," the instrument makes use of a free-running commercial femtosecond Titane Saphir laser. We demonstrate that this multiplex detection scheme provides shot noise limited spectra for acquisition times as long as 5 min. Moreover, this instrument is very versatile as it can be potentially tuned from the infrared to the ultraviolet (1080-340 nm) to reach various molecular absorptions. It has been recently deployed at the Station Biologique de Roscoff on the North West Atlantic coast of France.

  13. Spectrometer gun

    Science.gov (United States)

    Waechter, David A.; Wolf, Michael A.; Umbarger, C. John

    1985-01-01

    A hand-holdable, battery-operated, microprocessor-based spectrometer gun includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

  14. First real-time measurement of the evolving H-2/H-1 ratio during water evaporation from plant leaves

    NARCIS (Netherlands)

    Kerstel, ERT; van der Wel, LG; Meijer, HAJ

    We have studied the temporal behaviour of the deuterium isotope ratio of water vapour emerging from a freshly cut plant leaf placed in a dry nitrogen atmosphere. The leaf material was placed directly inside the sample gas cell of the stable isotope ratio infrared spectrometer. At the reduced

  15. The source issue in infrared microspectroscopy

    CERN Document Server

    Smith, T I

    2002-01-01

    Infrared spectroscopy using a Fourier Transform Infrared (FTIR) spectrometer is routine. These instruments are sophisticated and mature, and generally use a blackbody radiator as their infrared source. However, because the brightness of a thermal source is limited, the signal-to-noise ratio of these instruments begins to degrade at spatial resolutions not much better than 1 mm and they are rarely useful at resolutions smaller than 20 mu m. Synchrotrons provide much brighter infrared beams than thermal sources, and Free-Electron Lasers (FELs) provide even brighter beams than synchrotrons. We will discuss the limitations of thermal sources, and show that a synchrotron is an excellent source for infrared spectroscopy at spatial resolutions on the order of the wavelength (lambda). Even better spatial resolution, about lambda/10, can be expected if an FEL is used as a source.

  16. Development of a tunable Fabry-Perot etalon-based near-infrared interference spectrometer for measurement of the HeI 2{sup 3}S-2{sup 3}P spectral line shape in magnetically confined torus plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Ogane, S.; Shikama, T., E-mail: shikama@me.kyoto-u.ac.jp; Hasuo, M. [Department of Mechanical Engineering and Science, Graduate School of Engineering, Kyoto University, Kyoto 615-8540 (Japan); Zushi, H. [Research Institute for Applied Mechanics, Kyushu University, Fukuoka 816-8580 (Japan)

    2015-10-15

    In magnetically confined torus plasmas, the local emission intensity, temperature, and flow velocity of atoms in the inboard and outboard scrape-off layers can be separately measured by a passive emission spectroscopy assisted by observation of the Zeeman splitting in their spectral line shape. To utilize this technique, a near-infrared interference spectrometer optimized for the observation of the helium 2{sup 3}S–2{sup 3}P transition spectral line (wavelength 1083 nm) has been developed. The applicability of the technique to actual torus devices is elucidated by calculating the spectral line shapes expected to be observed in LHD and QUEST (Q-shu University Experiment with Steady State Spherical Tokamak). In addition, the Zeeman effect on the spectral line shape is measured using a glow-discharge tube installed in a superconducting magnet.

  17. The Spectrometer

    Science.gov (United States)

    Greenslade, Thomas B., Jr.

    2012-01-01

    In the fall of 1999 I was shown an Ocean Optics spectrometer-in-the-computer at St. Patricks College at Maynooth, Ireland, and thought that I had seen heaven. Of course, it could not resolve the sodium D-lines (I had done that many years before with a homemade wire diffraction grating), and I began to realize that inside was some familiar old…

  18. Simultaneous delta15N, delta13C and delta34S measurements of low-biomass samples using a technically advanced high sensitivity elemental analyzer connected to an isotope ratio mass spectrometer.

    Science.gov (United States)

    Hansen, T; Burmeister, A; Sommer, U

    2009-11-01

    Conventional simultaneous CNS stable isotope abundance measurements of solid samples usually require high sample amounts, up to 1 mg carbon, to achieve exact analytical results. This rarely used application is often impaired by high C:S element ratios when organic samples are analyzed and problems such as incomplete conversion into sulphur dioxide occur during analysis. We introduce, as a technical innovation, a high sensitivity elemental analyzer coupled to a conventional isotope ratio mass spectrometer, with which CNS-stable isotope ratios can be determined simultaneously in samples with low carbon content (<40 microg C corresponding to approximately 100 microg dry weight). The system includes downsized reactors, a temperature program-controlled gas chromatography (GC) column and a cryogenic trap to collect small amounts of sulphur dioxide. This modified application allows for highly sensitive measurements in a fully automated operation with standard deviations better than +/-0.47 per thousand for delta15N and delta34S and +/-0.12 per thousand for delta13C (n = 127). Samples collected from one sampling site in a Baltic fjord within a short time period were measured with the new system to get a first impression of triple stable isotope signatures. The results confirm the potential of using delta34S as a stable isotope tracer in combination with delta15N and delta13C measurements to improve discrimination of food sources in aquatic food webs.

  19. Refinement of the Compton–Rayleigh scatter ratio method for use on the Mars Science Laboratory alpha particle X-ray spectrometer: II – Extraction of invisible element content

    Energy Technology Data Exchange (ETDEWEB)

    Perrett, Glynis M. [Guelph-Waterloo Physics Institute, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); Campbell, John L., E-mail: icampbel@uoguelph.ca [Guelph-Waterloo Physics Institute, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); Gellert, Ralf [Guelph-Waterloo Physics Institute, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); King, Penelope L. [Research School of Earth Sciences, Australian National University, Canberra, ACT 0200 (Australia); Nield, Emily; O’Meara, Joanne M.; Pradler, Irina [Guelph-Waterloo Physics Institute, University of Guelph, Guelph, Ontario N1G 2W1 (Canada)

    2016-02-01

    The intensity ratio C/R between Compton and Rayleigh scatter peaks of the exciting Pu L X-rays in the alpha particle X-ray spectrometer (APXS) is strongly affected by the presence of very light elements such as oxygen which cannot be detected directly by the APXS. C/R values are determined along with element concentrations by fitting APXS spectra of geochemical reference materials (GRMs) with the GUAPX code. A quantity K is defined as the ratio between the C/R value determined by Monte Carlo simulation based on the measured element concentrations and the fitted C/R value from the spectrum. To ensure optimally accurate K values, the choice of appropriate GRMs is explored in detail, with attention paid to Rb and Sr, whose characteristic Kα X-ray peaks overlap the Pu Lα scatter peaks. The resulting relationship between the ratio K and the overall oxygen fraction is linear. This provides a calibration from which the concentration of additional light invisible constituents (ALICs) such as water may be estimated in unknown rock and conglomerate samples. Several GRMs are used as ‘unknowns’ in order to evaluate the accuracy of ALIC concentrations derived in this manner.

  20. Headspace-solid phase microextraction coupled to gas chromatography-combustion-isotope ratio mass spectrometer and to enantioselective gas chromatography for strawberry flavoured food quality control.

    Science.gov (United States)

    Schipilliti, Luisa; Dugo, Paola; Bonaccorsi, Ivana; Mondello, Luigi

    2011-10-21

    Authenticity assessment of flavoured strawberry foods was performed using headspace-solid phase microextraction (HS-SPME) coupled to gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). An authenticity range was achieved, investigating on the carbon isotope ratio of numerous selected aroma active volatile components (methyl butanoate, ethyl butanoate, hex-(2E)-enal, methyl hexanoate, buthyl butanoate, ethyl hexanoate, hexyl acetate, linalool, hexyl butanoate, octyl isovalerate, γ-decalactone and octyl hexanoate) of organic Italian fresh strawberries. To the author's knowledge, this is the first time that all these components were investigated simultaneously by GC-C-IRMS on the same sample. The results were compared, when applicable, with those obtained by analyzing the HS-SPME extracts of commercial flavoured food matrices. In addition, one Kenyan pineapple and one fresh Italian peach were analyzed to determine the δ(13)C(VPDB) of the volatile components common to strawberry. The δ(13)C(VPDB) values are allowed to differentiate between different biogenetic pathways (C(3) and CAM plants) and more interestingly between plants of the same CO(2) fixation group (C(3) plants). Additional analyses were performed on all the samples by means of Enantioselective Gas Chromatography (Es-GC), measuring the enantiomeric distribution of linalool and γ-decalactone. It was found that GC-C-IRMS and Es-GC measurements were in agreement to detect the presence of non-natural strawberry aromas in the food matrices studied. Copyright © 2011 Elsevier B.V. All rights reserved.

  1. SYSTEMATIC VARIATIONS IN CO{sub 2}/H{sub 2}O ICE ABUNDANCE RATIOS IN NEARBY GALAXIES FOUND WITH AKARI NEAR-INFRARED SPECTROSCOPY

    Energy Technology Data Exchange (ETDEWEB)

    Yamagishi, M.; Kaneda, H.; Ishihara, D.; Oyabu, S. [Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602 (Japan); Onaka, T. [Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Shimonishi, T. [Graduate School of Science, Kobe University, 1-1 Rokkodai, Nada-ku, Kobe 657-8501 (Japan); Suzuki, T., E-mail: yamagishi@u.phys.nagoya-u.ac.jp [SRON Netherlands Institute for Space Research, Sorbonnelaan 2, 3584 CA Utrecht (Netherlands)

    2015-07-01

    We report CO{sub 2}/H{sub 2}O ice abundance ratios in seven nearby star-forming galaxies based on the AKARI near-infrared (2.5–5.0 μm) spectra. The CO{sub 2}/H{sub 2}O ice abundance ratios show clear variations between 0.05 and 0.2 with the averaged value of 0.14 ± 0.01. The previous study on M82 revealed that the CO{sub 2}/H{sub 2}O ice abundance ratios strongly correlate with the intensity ratios of the hydrogen recombination Brα line to the polycyclic aromatic hydrocarbon (PAH) 3.3 μm feature. In the present study, however, we find no correlation for the seven galaxies as a whole due to systematic differences in the relation between CO{sub 2}/H{sub 2}O ice abundance and Brα/PAH 3.3 μm intensity ratios from galaxy to galaxy. This result suggests that there is another parameter that determines the CO{sub 2}/H{sub 2}O ice abundance ratios in a galaxy in addition to the Brα/PAH 3.3 μm ratios. We find that the CO{sub 2}/H{sub 2}O ice abundance ratios positively correlate with the specific star formation rates of the galaxies. From these results, we conclude that CO{sub 2}/H{sub 2}O ice abundance ratios tend to be high in young star-forming galaxies.

  2. The GRAVITY spectrometers: optical qualification

    Science.gov (United States)

    Yazici, Senol; Straubmeier, Christian; Wiest, Michael; Wank, Imke; Fischer, Sebastian; Horrobin, Matthew; Eisenhauer, Frank; Perrin, Guy; Perraut, Karine; Brandner, Wolfgang; Amorim, Antonio; Schöller, Markus; Eckart, Andreas

    2014-07-01

    GRAVITY1 is a 2nd generation Very Large Telescope Interferometer (VLTI) operated in the astronomical K-band. In the Beam Combiner Instrument2 (BCI) four Fiber Couplers3 (FC) will feed the light coming from each telescope into two fibers, a reference channel for the fringe tracking spectrometer4 (FT) and a science channel for the science spectrometer4 (SC). The differential Optical Path Difference (dOPD) between the two channels will be corrected using a novel metrology concept.5 The metrology laser will keep control of the dOPD of the two channels. It is injected into the spectrometers and detected at the telescope level. Piezo-actuated fiber stretchers correct the dOPD accordingly. Fiber-fed Integrated Optics6 (IO) combine coherently the light of all six baselines and feed both spectrometers. Assisted by Infrared Wavefront Sensors7 (IWS) at each Unit Telescope (UT) and correcting the path difference between the channels with an accuracy of up to 5 nm, GRAVITY will push the limits of astrometrical accuracy to the order of 10 μas and provide phase-referenced interferometric imaging with a resolution of 4 mas. The University of Cologne developed, constructed and tested both spectrometers of the camera system. Both units are designed for the near infrared (1.95 - 2.45 μm) and are operated in a cryogenic environment. The Fringe Tracker is optimized for highest transmission with fixed spectral resolution (R = 22) realized by a double-prism.8 The Science spectrometer is more diverse and allows to choose from three different spectral resolutions8 (R = [22, 500, 4000]), where the lowest resolution is achieved with a prism and the higher resolutions are realized with grisms. A Wollaston prism in each spectrometer allows for polarimetric splitting of the light. The goal for the spectrometers is to concentrate at least 90% of the ux in 2 × 2 pixel (36 × 36 μm2) for the Science channel and in 1 pixel (24 × 24 μm) in the Fringe Tracking channel. In Section 1, we present

  3. IIP Tropospheric Infrared Mapping Spectrometers (TIMS) demonstration of CO retrieval, including multi-layer, from atmospheric data acquired simultaneously in the solar reflective region near 2.3 um and the thermal emissive region near 4.7 um

    Science.gov (United States)

    Mergenthaler, J. L.; Kumer, J.; Roche, A. E.; Rairden, R. L.; Blatherwick, R.; Hawat, T.; Desouza-Machado, S.; Hannon, S.; Chatfield, R. B.

    2008-12-01

    The NASA Earth Science Technology Office (ESTO) Instrument Incubator Program (IIP) Tropospheric Infrared Mapping Spectrometers (TIMS) have been developed to demonstrate measurement capability, when deployed in space, for multi-layer retrieval of CO from spectral measurements acquired in the solar reflective (SR) region ~ 4281 to 4301 cm-1 and in the thermal InfraRed (TIR) region ~ 2110 to 2165 cm-1. We describe joint deployment at Denver University (DU) with co-investigators there of the TIMS, and of the DU colleagues FTS, to acquire simultaneous measurements of atmospheric spectra in the SR and the TIR. The FTS provided validation radiance data for the TIMS. The TIMS retrievals of CO, H2O and CH4 agreed well with validation vs these as retrieved from the DU data, AIRS retrieval, standard models and ECMWF. The TIMS CO retrievals included column retrieved from the just the SR data, column retrieved from just the TIR data, and a simple two-layer retrieval from the combined data sets. The data were acquired in an operational mode that mimicked the operations in a conceptual application that would provide footprints, coverage, refresh time as in the Decadal Survey GEO-CAPE mission statement. Very encouraging CO precisions were achieved, e.g., the TIMS CO column retrieval from the SR data demonstrated better than the 10% precision requirement as listed on slide 32 of the GEO-CAPE Reference document http://geo- cape.larc.nasa.gov/docs/GEOMAC_FinalReport_no_costs.ppt

  4. IR spectrometer project for the BTA telescope

    Science.gov (United States)

    Afanasiev, V. L.; Emelianov, E. V.; Murzin, V. A.; Vdovin, V. F.

    2013-07-01

    We introduce a project of new cooled infrared spectrometer-photometer for 6-m telescope BTA (Special Astrophysical Observatory of Russian Science Academy). The device would extend the wavelength range accessible for observations on the 6-m BTA telescope toward near infrared (0.8-2.5 um).

  5. IR Spectrometer Project for the BTA Telescope

    OpenAIRE

    Afanasiev, V. L.; Emelianov, E. V.; Murzin, V. A.; Vdovin, V. F.

    2013-01-01

    We introduce a project of new cooled infrared spectrometer-photometer for 6-m telescope BTA (Special Astrophysical Observatory of Russian Science Academy). The device would extend the wavelength range accessible for observations on the 6-m BTA telescope toward near infrared (0.8-2.5 um).

  6. MASS SPECTROMETER

    Science.gov (United States)

    White, F.A.

    1960-08-23

    A mass spectrometer is designed with a first adjustable magnetic field for resolving an ion beam into beams of selected masses, a second adjustable magnetic field for further resolving the ion beam from the first field into beams of selected masses, a thin foil disposed in the path of the beam between the first and second magnets to dissociate molecular ions incident thereon, an electrostatic field for further resolving the ion beam from the second field into beams of selected masses, and a detector disposed adjacent to the electrostatic field to receive the ion beam.

  7. Projective rectification of infrared images from air-cooled condenser temperature measurement by using projection profile features and cross-ratio invariability.

    Science.gov (United States)

    Xu, Lijun; Chen, Lulu; Li, Xiaolu; He, Tao

    2014-10-01

    In this paper, we propose a projective rectification method for infrared images obtained from the measurement of temperature distribution on an air-cooled condenser (ACC) surface by using projection profile features and cross-ratio invariability. In the research, the infrared (IR) images acquired by the four IR cameras utilized are distorted to different degrees. To rectify the distorted IR images, the sizes of the acquired images are first enlarged by means of bicubic interpolation. Then, uniformly distributed control points are extracted in the enlarged images by constructing quadrangles with detected vertical lines and detected or constructed horizontal lines. The corresponding control points in the anticipated undistorted IR images are extracted by using projection profile features and cross-ratio invariability. Finally, a third-order polynomial rectification model is established and the coefficients of the model are computed with the mapping relationship between the control points in the distorted and anticipated undistorted images. Experimental results obtained from an industrial ACC unit show that the proposed method performs much better than any previous method we have adopted. Furthermore, all rectified images are stitched together to obtain a complete image of the whole ACC surface with a much higher spatial resolution than that obtained by using a single camera, which is not only useful but also necessary for more accurate and comprehensive analysis of ACC performance and more reliable optimization of ACC operations.

  8. Mid-infrared microlensing of accretion disc and dusty torus in quasars: effects on flux ratio anomalies

    CERN Document Server

    Sluse, D; Anguita, T; Wucknitz, O; Wambsganss, J

    2013-01-01

    Multiply-imaged quasars and AGNs observed in the mid-infrared (MIR) range are commonly assumed to be unaffected by the microlensing produced by the stars in their lensing galaxy. In this paper, we investigate the validity domain of this assumption. Indeed, that premise disregards microlensing of the accretion disc in the MIR range, and does not account for recent progress in our knowledge of the dusty torus. To simulate microlensing, we first built a simplified image of the quasar composed of an accretion disc, and of a larger ring-like torus. The mock quasars are then microlensed using an inverse ray-shooting code. We simulated the wavelength and size dependence of microlensing for different lensed image types and fraction of compact objects projected in the lens. This allows us to derive magnification probabilities as a function of wavelength, as well as to calculate the microlensing-induced deformation of the spectral energy distribution of the lensed images. We find that microlensing variations as large a...

  9. In-situ Iberian pig carcass classification using a micro-electro-mechanical system (MEMS)-based near infrared (NIR) spectrometer.

    Science.gov (United States)

    Zamora-Rojas, E; Pérez-Marín, D; De Pedro-Sanz, E; Guerrero-Ginel, J E; Garrido-Varo, A

    2012-03-01

    Iberian pig (IP) products are gourmet foods highly appreciated at international markets, reaching high prices, because of its exquisite flavors. At present, there aren't practical and affordable analytical methods which can authenticate every single piece put on the market. This paper reports on the performance of a handheld micro-electro-mechanical system (MEMS)-based spectrometer (1600-2400nm) for authentication-classification of individual IP carcasses into different commercial categories. Performance (accuracy and instrumental design) of the instrument was compared with that of high-resolution NIRS monochromators (400-2500nm). A total of 300 carcasses of IPs raised under different feeding regimes ("Acorn", "Recebo" and "Feed") were analyzed in three modes (intact fat in the carcass, skin-free subcutaneous fat samples and melted fat samples). The best classification results for the MEMS instrument were: 93.9% "Acorn" carcasses correctly classified, 96.4% "Feed" and 60.6% "Recebo", respectively. Evaluation of model performance confirmed the suitability of the handheld device for individual, fast, non-destructive, low-cost analysis of IP carcasses on the slaughterhouse line.

  10. Computer Spectrometers

    Science.gov (United States)

    Dattani, Nikesh S.

    2017-06-01

    Ideally, the cataloguing of spectroscopic linelists would not demand laborious and expensive experiments. Whatever an experiment might achieve, the same information would be attainable by running a calculation on a computer. Kolos and Wolniewicz were the first to demonstrate that calculations on a computer can outperform even the most sophisticated molecular spectroscopic experiments of the time, when their 1964 calculations of the dissociation energies of H_2 and D_{2} were found to be more than 1 cm^{-1} larger than the best experiments by Gerhard Herzberg, suggesting the experiment violated a strict variational principle. As explained in his Nobel Lecture, it took 5 more years for Herzberg to perform an experiment which caught up to the accuracy of the 1964 calculations. Today, numerical solutions to the Schrödinger equation, supplemented with relativistic and higher-order quantum electrodynamics (QED) corrections can provide ro-vibrational spectra for molecules that we strongly believe to be correct, even in the absence of experimental data. Why do we believe these calculated spectra are correct if we do not have experiments against which to test them? All evidence seen so far suggests that corrections due to gravity or other forces are not needed for a computer simulated QED spectrum of ro-vibrational energy transitions to be correct at the precision of typical spectrometers. Therefore a computer-generated spectrum can be considered to be as good as one coming from a more conventional spectrometer, and this has been shown to be true not just for the H_2 energies back in 1964, but now also for several other molecules. So are we at the stage where we can launch an array of calculations, each with just the atomic number changed in the input file, to reproduce the NIST energy level databases? Not quite. But I will show that for the 6e^- molecule Li_2, we have reproduced the vibrational spacings to within 0.001 cm^{-1} of the experimental spectrum, and I will

  11. Dual waveband compact catadioptric imaging spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Chrisp, Michael P.

    2012-12-25

    A catadioptric dual waveband imaging spectrometer that covers the visible through short-wave infrared, and the midwave infrared spectral regions, dispersing the visible through shortwave infrared with a zinc selenide grating and midwave infrared with a sapphire prism. The grating and prism are at the cold stop position, enabling the pupil to be split between them. The spectra for both wavebands are focused onto the relevant sections of a single dual waveband detector. Spatial keystone distortion is controlled to less than one tenth of a pixel over the full wavelength range, facilitating the matching of the spectra in the midwave infrared with the shorter wavelength region.

  12. [Current status and prospects of portable NIR spectrometer].

    Science.gov (United States)

    Yu, Xin-Yang; Lu, Qi-Peng; Gao, Hong-Zhi; Peng, Zhong-Qi

    2013-11-01

    Near-infrared spectroscopy (NIRS) is a reliable, rapid, and non-destructive analytical method widely applied in as a number of fields such as agriculture, food, chemical and oil industry. In order to suit different applications, near-infrared spectrometers are now varied. Portable near-infrared spectrometers are needed for rapid on-site identification and analysis. Instruments of this kind are rugged, compact and easy to be transported. In this paper, the current states of portable near-infrared spectrometers are reviewed. Portable near-infrared spectrometers are built of different monochromator systems: filter, grating, Fourier-transform methods, acousto-optic tunable filter (AOTF) and a large number of new methods based on micro-electro-mechanical systems (MEMS). The first part focuses on working principles of different monochromator systems. Advantages and disadvantages of different systems are also briefly mentioned. Descriptions of each method are given in turn. Typical spectrometers of each kind are introduced, and some parameters of these instruments are listed. In the next part we discuss sampling adapters, display, power supply and some other parts, which are designed to make the spectrometer more portable and easier to use. In the end, the current states of portable near-infrared spectrometers are summarized. Future trends of development of portable near-infrared spectrometers in China and abroad are discussed.

  13. Determination of technical readiness for an atmospheric carbon imaging spectrometer

    Science.gov (United States)

    Mobilia, Joseph; Kumer, John B.; Palmer, Alice; Sawyer, Kevin; Mao, Yalan; Katz, Noah; Mix, Jack; Nast, Ted; Clark, Charles S.; Vanbezooijen, Roel; Magoncelli, Antonio; Baraze, Ronald A.; Chenette, David L.

    2013-09-01

    The geoCARB sensor uses a 4-channel push broom slit-scan infrared imaging grating spectrometer to measure the absorption spectra of sunlight reflected from the ground in narrow wavelength regions. The instrument is designed for flight at geostationary orbit to provide mapping of greenhouse gases over continental scales, several times per day, with a spatial resolution of a few kilometers. The sensor provides multiple daily maps of column-averaged mixing ratios of CO2, CH4, and CO over the regions of interest, which enables flux determination at unprecedented time, space, and accuracy scales. The geoCARB sensor development is based on our experience in successful implementation of advanced space deployed optical instruments for remote sensing. A few recent examples include the Atmospheric Imaging Assembly (AIA) and Helioseismic and Magnetic Imager (HMI) on the geostationary Solar Dynamics Observatory (SDO), the Space Based Infrared System (SBIRS GEO-1) and the Interface Region Imaging Spectrograph (IRIS), along with sensors under development, the Near Infared camera (NIRCam) for James Webb (JWST), and the Global Lightning Mapper (GLM) and Solar UltraViolet Imager (SUVI) for the GOES-R series. The Tropospheric Infrared Mapping Spectrometer (TIMS), developed in part through the NASA Instrument Incubator Program (IIP), provides an important part of the strong technological foundation for geoCARB. The paper discusses subsystem heritage and technology readiness levels for these subsystems. The system level flight technology readiness and methods used to determine this level are presented along with plans to enhance the level.

  14. An airborne amplitude-modulated 1.57 μm differential laser absorption spectrometer: simultaneous measurement of partial column-averaged dry air mixing ratio of CO2 and target range

    Directory of Open Access Journals (Sweden)

    O. Uchino

    2013-02-01

    Full Text Available Simultaneous measurements of the partial column-averaged dry air mixing ratio of CO2 (XCO2 and target range were demonstrated using airborne amplitude-modulated 1.57 μm differential laser absorption spectrometer (LAS. The LAS system is useful for discriminating between ground and cloud return signals and has a demonstrated ability to suppress the impact of integrated aerosol signals on atmospheric CO2 measurements. A high correlation coefficient (R of 0.987 between XCO2 observed by LAS and XCO2 calculated from in situ measurements was obtained. The averaged difference in XCO2 obtained from LAS and validation data was within 1.5 ppm for all spiral measurements. An interesting vertical profile was observed for both XCO2LAS and XCO2val, in which lower altitude CO2 decreases compared to higher altitude CO2 attributed to the photosynthesis over grassland in the summer. In the case of an urban area where there are boundary-layer enhanced CO2 and aerosol in the winter, the difference of XCO2LAS to XCO2val is a negative bias of 1.5 ppm, and XCO2LAS is in agreement with XCO2val within the measurement precision of 2.4 ppm (1 SD.

  15. Performance characteristics of a passively locked cavity-enhanced absorption spectrometer with wideband-tunable multimode near-infrared light source

    Science.gov (United States)

    Someya, Ryuta; Imamura, Takeshi; Okamoto, Tetsushi; Hatano, Hiroshi; Toyoshima, Naoko; Tei, Kazuyoku; Yamaguchi, Shigeru

    2016-03-01

    A trace material detection system was developed on the basis of cavity-enhanced absorption spectroscopy (CEAS) using a fiber-coupled passively locked external cavity diode laser (PLEC-DL) in the near-infrared (NIR) wavelength region. The oscillation range of an antireflection-coated diode laser (AR-DL) coupled into an external cavity could be simply selected with a narrowband bandpass filter (1 nm), resulting in a stable wavelength oscillation in the wideband tunability between 1640 and 1680 nm. The external cavity acts as a trace material sensor that exhibits excellent flexibility because it is free from the DL source and is carefully designed with mirrors having reflectivities of ca. 99.995 and 99.99%. Trace-level detection was successfully demonstrated with the developed sensor having a minimum detectable absorption coefficient of 2.4 × 10-8 cm-1, which corresponds to 0.15 ppm for CH4 concentration without interference from H2O absorption lines under atmospheric pressure.

  16. Biological Process Oriented Online Fourier Transform Infrared Spectrometer%面向生物过程的在线式傅里叶变换红外光谱仪

    Institute of Scientific and Technical Information of China (English)

    谢非; 吴琼水; 曾立波

    2015-01-01

    An online Fourier Transform Infrared Spectrometer and an ATR (Attenuated Total Reflection) probe ,specifically at the application of real time measurement of the reaction substrate concentration in biological processes ,were designed .(1) The spectrometer combined the theories of double cube‐corner reflectors and flat mirror ,which created a kind of high performance in‐terferometer system .The light path folding way was utilized to makes the interferometer compact structure .Adopting double cube‐corner reflectors ,greatly reduces the influence of factors in the process of moving mirror movement such as rotation ,tilt , etc .The parallelogram oscillation flexible support device was utilized to support the moving mirror moves .It cancelled the fric‐tion and vibration during mirror moving ,and ensures the smooth operation .The ZnSe splitter significantly improved the hard‐ware reliability in high moisture environment .The method of 60° entrance to light splitter improves the luminous flux .(2)An ATR in situ measuring probe with simple structure ,large‐flux ,economical and practical character was designed in this article . The transmission of incident light and the light output utilized the infrared pipe with large diameter and innerplanted‐high plating membrane ,which conducted for the infrared transmission media of ATR probe .It greatly reduced the energy loss of infrared light after multiple reflection on the inner wall of the light pipe .Therefore ,the ATR probe obtained high flux ,improved the sig‐nal strength ,which make the signal detected easily .Finally ,the high sensitivity of MCT (Mercury Cadmium Telluride) detector was utilized to realize infrared interference signal collection ,and improved the data quality of detection .The test results showed that the system yields the advantages of perfect moisture‐proof performance ,luminous flux ,online measurement ,etc .The de‐signed online Fourier infrared spectrometer can real‐time measured

  17. Ultra Compact Imaging Spectrometer (UCIS)

    Science.gov (United States)

    Blaney, Diana L.; Green, Robert; Mouroulis, Pantazis; Cable, Morgan; Ehlmann, Bethany; Haag, Justin; Lamborn, Andrew; McKinley, Ian; Rodriguez, Jose; van Gorp, Byron

    2016-10-01

    The Ultra Compact Imaging Spectrometer (UCIS) is a modular visible to short wavelength infrared imaging spectrometer architecture which could be adapted to a variety of mission concepts requiring low mass and low power. Imaging spectroscopy is an established technique to address complex questions of geologic evolution by mapping diagnostic absorption features due to minerals, organics, and volatiles throughout our solar system. At the core of UCIS is an Offner imaging spectrometer using M3 heritage and a miniature pulse tube cryo-cooler developed under the NASA Maturation of Instruments for Solar System Exploration (MatISSE) program to cool the focal plane array. The TRL 6 integrated spectrometer and cryo-cooler provide a basic imaging spectrometer capability that is used with a variety of fore optics to address lunar, mars, and small body science goals. Potential configurations include: remote sensing from small orbiters and flyby spacecraft; in situ panoramic imaging spectroscopy; and in situ micro-spectroscopy. A micro-spectroscopy front end is being developed using MatISSE funding with integration and testing planned this summer.

  18. SPECIES: a multi-channel infrared laser spectrometer with optical-feedback cavity-enhanced absorption for in-situ balloon-borne and airborne measurements

    Science.gov (United States)

    Jacquet, Patrick; Catoire, Valery; Chartier, Michel; Robert, Claude; Krysztofiak, Gisele; Huret, Nathalie; Romanini, Daniele

    2017-04-01

    Over the last decades, thanks to significant technological advances in measurement techniques, our understanding of the chemistry and dynamics of the upper troposphere and stratosphere has progressed significantly. However some key questions remain unsolved and new ones arise in the climate change context. The full recovery of the ozone layer in a period of halogens decrease and N2O increase (and the delay of this recovery), the impact of the climate change on the stratosphere and the role of this one as a feedback are very uncertain. To address these challenges, one needs instruments able to measure a wide variety of trace gases simultaneously with a wide vertical range, combined to chemical and dynamical modelling at different scales. LPC2E and LIPHY laboratories are developing a new balloon-borne and airborne instrument: SPECIES (SPECtromètre Infrarouge à lasErs in Situ). Based on the Optical Feedback Cavity Enhanced Spectroscopy (OF-CEAS) technique combined with mid-infrared quantum or interband cascade lasers (QCLs or ICLs), this instrument will offer unprecedented performances in terms of vertical extent of the measurements, from ground to the middle stratosphere, and number of molecular species simultaneously measured with sub-ppb detection limits (e.g. O3, N2O, HNO3, NH3, H2O2, HCl, HOCl,CF2O, CH4, CH2O, CO, CO2, OCS, SO2). Due to high frequency measurement (>0.5 Hz) it shall offer very high spatial resolution (a few meters).

  19. Infrared Astronomy with Arrays: The Next Generation; Sunset Village, Los Angeles, CA, Oct. 1993

    Science.gov (United States)

    Mclean, Ian S.

    1994-01-01

    Conference papers on infrared array techniques and methods for infrared astronomy are presented. Topics covered include the following: infrared telescopes; infrared spectrometers; spaceborne astronomy; astronomical observatories; infrared cameras; imaging techniques; sky surveys; infrared photography; infrared photometry; infrared spectroscopy; equipment specifications; data processing and analysis; control systems; cryogenic equipment; adaptive optics; image resolution; infrared detector materials; and focal plane arrays.

  20. Measurement of glass transition temperature, residual heat of reaction and mixing ratio of epoxy resins using near infrared spectroscopy: a preliminary study

    DEFF Research Database (Denmark)

    Houmøller, Lars Plejdrup; Laursen, Peter Clemen

    2003-01-01

    variables, using differential scanning calorimetry (DSC) as the reference method. The epoxy under study was a commercial system consisting of the resin, trimethylolpropanetriglycidylether, and the hardener, 3-aminomethyl-3,5,5,-trimethylcyclohexylamine. Using samples cured under different conditions......As a measure of the degree of curing of epoxy resins, the glass transition temperature, Tg, and the residual heat of reaction, DeltaHr, are often used. In this study, near infrared spectroscopy and multivariate calibration (partial least squares regression (PLSR)) have been used to monitor the two......, calibrations resulted in root mean square errors of cross-validation (RMSECV) of 18 J/g for DeltaHr (range for Hr: 6.1-231.3 J/g) and 7.2ºC for Tg (range for Tg: 41.5-98.8ºC). Also, a PLSR model for mixing ratio of hardener and resin was obtained, resulting in a RMSECV of 0.0040 (range for mixing ratio: 0.180-0.380)...

  1. A Pulsed Spectrometer Designed for Feedback NQR

    Science.gov (United States)

    Schiano, J. L.; Ginsberg, M. D.

    2000-02-01

    A pulsed NQR spectrometer specifically designed to facilitate real-time tuning of pulse sequence parameters is described. A modular approach based on the interconnection of several rack-mounted blocks provides easy access to all spectrometer signals and simplifies the task of modifying the spectrometer design. We also present experimental data that demonstrates the ability of the spectrometer to increase the signal to noise ratio of NQR measurements by automatically adjusting the pulse width in the strong off-resonant comb pulse sequence.

  2. Development of Miniature Spectrometers

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhi-guo

    2007-01-01

    Spectrometer is an essential and necessary optical element used for measuring the chemical components and content of the matter.The development of miniature spectrometers can be traced back to 1980s.The development state and different manufacturing methods of micro-spectrometers are presented.Finally,we analyze the miniaturization trend of spectrometers.Some groundwork for the scientific research is offered by introducing micro-spectrometers development.

  3. Infrared absorption of methanethiol clusters (CH3SH)n, n = 2-5, recorded with a time-of-flight mass spectrometer using IR depletion and VUV ionization.

    Science.gov (United States)

    Fu, Lung; Han, Hui-Ling; Lee, Yuan-Pern

    2012-12-21

    We investigated IR spectra in the CH- and SH-stretching regions of size-selected methanethiol clusters, (CH(3)SH)(n) with n = 2-5, in a pulsed supersonic jet using infrared (IR)-vacuum ultraviolet (VUV) ionization. VUV emission at 132.50 nm served as the source of ionization in a time-of-flight mass spectrometer. Clusters were dissociated with light from a tunable IR laser before ionization. The variations in intensity of methanethiol cluster ions (CH(3)SH)(n)(+) were monitored as the IR laser light was tuned across the range 2470-3100 cm(-1). In the SH-stretching region, the spectrum of (CH(3)SH)(2) shows a weak band near 2601 cm(-1), red-shifted only 7 cm(-1) from that of the monomer. In contrast, all spectra of (CH(3)SH)(n), n = 3-5, show a broad band near 2567 cm(-1) with much greater intensity. In the CH-stretching region, absorption bands of (CH(3)SH)(2) are located near 2865, 2890, 2944, and 3010 cm(-1), red-shifted by 3-5 cm(-1) from those of CH(3)SH. These red shifts increase slightly for larger clusters and bands near 2856, 2884, 2938, and 3005 cm(-1) were observed for (CH(3)SH)(5). These spectral results indicate that the S-H[middle dot][middle dot][middle dot]S hydrogen bond plays an important role in clusters with n = 3-5, but not in (CH(3)SH)(2), in agreement with theoretical predictions. The absence of a band near 2608 cm(-1) that corresponds to absorption of the non-hydrogen-bonded SH moiety and the large width of observed feature near 2567 cm(-1) indicate that the dominant stable structures of (CH(3)SH)(n), n = 3-5, have a cyclic hydrogen-bonded framework.

  4. Measurement of delta13C and delta18O Isotopic Ratios of CaCO3 by a Thermoquest Finnigan GasBench II Delta Plus XL Continous Flow Isotope Ratio Mass Spectrometer with Application to Devils Hole Core DH-11 Calcite

    Science.gov (United States)

    Revesz, Kinga M.; Landwehr, Jurate Maciunas; Keybl, Jaroslav Edward

    2001-01-01

    A new method was developed to analyze the stable carbon and oxygen isotope ratios of small samples (400?20 ?g) of calcium carbonate. This new method streamlines the classical phosphoric acid - calcium carbonate (H3PO4 - CaCO3) reaction method by making use of a Thermoquest-Finnigan GasBench II preparation device and a Delta Plus XL continuous flow isotope ratio mass spectrometer. To obtain reproducible and accurate results, optimal conditions for the H3PO4 - CaCO3 reaction had to be determined. At the acid-carbonate reaction temperature suggested by the equipment manufacturer, the oxygen isotope ratio results were unsatisfactory (standard deviation () greater than 1.5 per mill), probably because of a secondary reaction. When the acid-carbonate reaction temperature was lowered to 26?C and the reaction time was increased to 24 hours, the precision of the carbon and oxygen isotope ratios for duplicate analyses improved to 0.1 and 0.2 per mill, respectively. The method was tested by analyzing calcite from Devils Hole, Nevada, which was formed by precipitation from ground water onto the walls of a sub-aqueous cavern during the last 500,000 years. Isotope-ratio values previously had been obtained by the classical method for Devils Hole core DH-11. The DH-11 core had been recently re-sampled, and isotope-ratio values were obtained using this new method. The results were comparable to those obtained by the classical method. The consistency of the isotopic results is such that an alignment offset could be identified in the re-sampled core material, a cutting error that was then independently confirmed. The reproducibility of the isotopic values is demonstrated by a correlation of approximately 0.96 for both isotopes, after correcting for an alignment offset. This result indicates that the new method is a viable alternative to the classical method. In particular, the new method requires less sample material permitting finer resolution and allows automation of some processes

  5. The HELLAS2XMM survey. V. Near-Infrared observations of X-ray sources with extreme X/O ratios

    CERN Document Server

    Mignoli, M; Comastri, A; Brusa, M; Ciliegi, P; Cocchia, F; Fiore, F; La Franca, F; Maiolino, R; Matt, G; Molendi, S; Perola, G C; Puccetti, S; Severgnini, P; Vignali, C

    2004-01-01

    We present the results of deep near-infrared observations of 11 hard X-ray selected sources in the Hellas2XMM survey, with faint optical magnitude (R>24) and high X-ray-to-optical flux ratio. All but one of the sources have been detected in the Ks band, with bright counterparts (Ks5), therefore belonging to the ERO population. A detailed analysis of the surface brightness profiles permits us to classify all of the NIR counterparts. There are 2 point-like objects, 7 elliptical galaxies and one source with a disky profile. None of the extended sources shows any evidence for the presence of a central unresolved object tracing the putative X-ray emitting AGN. Using both the R-K colors and the morphological information, we have estimated for all the sources a ``minimum photometric redshift'', ranging between 0.8 and 2.4; the elliptical hosts have zmin=0.9-1.4. We computed the X-ray properties using these redshifts: most of the sources have NH>10^{22}, with unabsorbed X-ray luminosities up to 10^{45}erg s^{-1}. The...

  6. Compact, Dual Channel, Mid-IR Laser Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Small Business Innovative Research Phase II proposal seeks to develop a dual channel, compact mid-infrared laser spectrometer for planetary atmosphere...

  7. Spatial Heterodyne Spectrometer for Aviation Hazard Detection Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Physical Sciences Inc (PSI) proposes the development of a longwave infrared (LWIR) imaging spatial heterodyne spectrometer (I-SHS) for standoff detection of clear...

  8. Compact, Dual Channel, Mid-IR Laser Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Small Business Innovative Research Phase I proposal seeks to develop a dual channel, compact mid-infrared laser spectrometer for planetary atmosphere...

  9. Demonstration of an ethane spectrometer for methane source identification.

    Science.gov (United States)

    Yacovitch, Tara I; Herndon, Scott C; Roscioli, Joseph R; Floerchinger, Cody; McGovern, Ryan M; Agnese, Michael; Pétron, Gabrielle; Kofler, Jonathan; Sweeney, Colm; Karion, Anna; Conley, Stephen A; Kort, Eric A; Nähle, Lars; Fischer, Marc; Hildebrandt, Lars; Koeth, Johannes; McManus, J Barry; Nelson, David D; Zahniser, Mark S; Kolb, Charles E

    2014-07-15

    Methane is an important greenhouse gas and tropospheric ozone precursor. Simultaneous observation of ethane with methane can help identify specific methane source types. Aerodyne Ethane-Mini spectrometers, employing recently available mid-infrared distributed feedback tunable diode lasers (DFB-TDL), provide 1 s ethane measurements with sub-ppb precision. In this work, an Ethane-Mini spectrometer has been integrated into two mobile sampling platforms, a ground vehicle and a small airplane, and used to measure ethane/methane enhancement ratios downwind of methane sources. Methane emissions with precisely known sources are shown to have ethane/methane enhancement ratios that differ greatly depending on the source type. Large differences between biogenic and thermogenic sources are observed. Variation within thermogenic sources are detected and tabulated. Methane emitters are classified by their expected ethane content. Categories include the following: biogenic (gas (1-6%), wet gas (>6%), pipeline grade natural gas (natural gas liquids (>30%). Regional scale observations in the Dallas/Fort Worth area of Texas show two distinct ethane/methane enhancement ratios bridged by a transitional region. These results demonstrate the usefulness of continuous and fast ethane measurements in experimental studies of methane emissions, particularly in the oil and natural gas sector.

  10. Near-Infrared Properties of Moderate-Redshift Galaxy Clusters: Halo Occupation Number, Mass-to-Light Ratios and Omega(M)

    Energy Technology Data Exchange (ETDEWEB)

    Muzzin, Adam; Yee, H.K.C.; /Toronto U., Astron. Dept.; Hall, Patrick B.; /York U., Canada; Lin, Huan; /Fermilab

    2007-03-01

    Using K-band imaging for 15 of the Canadian Network for Observational Cosmology (CNOC1) clusters we examine the near-infrared properties of moderate-redshift (0.19 < z < 0.55) galaxy clusters. We find that the number of K-band selected cluster galaxies within R{sub 500} (the Halo Occupation Number, HON) is well-correlated with the cluster dynamical mass (M{sub 500}) and X-ray Temperature (T{sub x}); however, the intrinsic scatter in these scaling relations is 37% and 46% respectively. Comparison with clusters in the local universe shows that the HON-M{sub 500} relation does not evolve significantly between z = 0 and z {approx} 0.3. This suggests that if dark matter halos are disrupted or undergo significant tidal-stripping in high-density regions as seen in numerical simulations, the stellar mass within the halos is tightly bound, and not removed during the process. The total K-band cluster light (L{sub 200},K) and K-band selected richness (parameterized by B{sub gc,K}) are also correlated with both the cluster T{sub x} and M{sub 200}. The total (intrinsic) scatter in the L{sub 200,K}-M{sub 200} and B{sub gc,K}-M{sub 200} relations are 43%(31%) and 35%(18%) respectively and indicates that for massive clusters both L{sub 200,K} and B{sub gc,K} can predict M{sub 200} with similar accuracy as T{sub x}, L{sub x} or optical richness (B{sub gc}). Examination of the mass-to-light ratios of the clusters shows that similar to local clusters, the K-band mass-to-light ratio is an increasing function of halo mass. Using the K-band mass-to-light ratios of the clusters, we apply the Oort technique and find {Omega}{sub m,0} = 0.22 {+-} 0.02, which agrees well with recent combined concordance cosmology parameters, but, similar to previous cluster studies, is on the low-density end of preferred values.

  11. 高深宽比金属光栅制备及中红外波段传感特性%Fabrication and application of high aspect ratio metallic gratings for sensing in the mid-infrared region

    Institute of Scientific and Technical Information of China (English)

    郑改革; 陈云云; 徐林华; 赖敏

    2013-01-01

    A method for fabricating high aspect ratio (HAR) metallic gratings using nanoimprint together with sputtering and reactive-ion etching (RIE) was introduced. The reflection spectrum is measured by Fourier transform infrared (FT-IR) spectrometer in the mid-infrared (Mid-IR) region. The reflection peaks will appear just when the p-polarized light incident normally to the grating vector direction, which is very similar to the phenomenon of surface plasmon resonance. This is the so-called spoof surface plasmon resonance (SSPR). Theoretical analysis based on rigorous coupled wave showed that spoof surface plasmon resonance is very sensitive to the change of refractive index in the surface of the metal. Thus this phenomenon has its potential use as a refractive index sensor. In addition, the shift of resonance wavelength with the refractive index of the metal surface is completely linear. The refractive index sensitivity of the Mid-IR SPR sensor are predicted to be 1600 nm per refractive index unit (1600 nm/RIU) and 5000 nm/RIU for the positive and negative order diffractive waves, respectively. The corresponding figure of merits of the whole system is predicted to be 20 RIU -1 and 60 RIU-1, respectively. The list of applicable target materials will certainly expand greatly if mid-IR SPR-based sensors are developed.%利用纳米压印结合溅射和反应离子刻蚀工艺制备了具有高深宽比的金光栅,使用傅里叶变换红外光谱仪测得了反射谱线.测量结果显示,只在p偏振光垂直于光栅矢量方向入射条件下才存在共振反射峰,证明了“伪表面等离子体激元波”的存在.基于严格耦合波分析理论计算了金属光栅的反射率,研究了其作为中红外波段波长调制型表面等离子体共振传感器的可行性.数值计算表明负级次衍射光波对应的共振反射峰的移动能获得较高的波长灵敏度.对于深宽比为10的金光栅结构,+1级次和-3级次衍射光波对应

  12. Diode laser absorption spectrometry for (CO2)-C-13/(CO2)-C-12 isotope ratio analysis : Investigation on precision and accuracy levels

    NARCIS (Netherlands)

    Castrillo, A; Casa, G; Kerstel, E; Gianfrani, L

    2005-01-01

    Near-infrared laser spectroscopy is used to measure the C-13/C-12 isotope abundance ratio in gas phase carbon dioxide. The spectrometer, developed expressly for field applications, is based on a 2 mu m distributed feedback diode laser in combination with sensitive wavelength modulation detection. It

  13. Diode laser absorption spectrometry for (CO2)-C-13/(CO2)-C-12 isotope ratio analysis : Investigation on precision and accuracy levels

    NARCIS (Netherlands)

    Castrillo, A; Casa, G; Kerstel, E; Gianfrani, L

    2005-01-01

    Near-infrared laser spectroscopy is used to measure the C-13/C-12 isotope abundance ratio in gas phase carbon dioxide. The spectrometer, developed expressly for field applications, is based on a 2 mu m distributed feedback diode laser in combination with sensitive wavelength modulation detection. It

  14. Hyperspectral Thermal Emission Spectrometer: Engineering Flight Campaign

    Science.gov (United States)

    Johnson, William R.; Hook, Simon J.; Shoen, Steven S.; Eng, Bjorn T.

    2013-01-01

    The Hyperspectral Thermal Emission Spectrometer (HyTES) successfully completed its first set of engineering test flights. HyTES was developed in support of the Hyperspectral Infrared Imager (HyspIRI). HyspIRI is one of the Tier II Decadal Survey missions. HyTES currently provides both high spectral resolution (17 nm) and high spatial resolution (2-5m) data in the thermal infrared (7.5-12 micron) part of the electromagnetic spectrum. HyTES data will be used to help determine the optimum band positions for the HyspIRI Thermal Infrared (TIR) sensor and provide antecedent data for HyspIRI related studies.

  15. A SSS Spectrometer

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The SSS spectrometer, so called simple scintillation spectrometer, is made by BTI (Bubble Technology Industries). The spectrometer can be used in the neutron energy range from 4.0 to 17 MeV. The SSS includes two sections: A probe and an analyzer module

  16. ALMA HCN and HCO+ J=3-2 observations of optical Seyfert and luminous infrared galaxies -- Confirmation of elevated HCN-to-HCO+ flux ratios in AGNs --

    CERN Document Server

    Imanishi, Masatoshi; Izumi, Takuma

    2016-01-01

    We present the results of our ALMA observations of three AGN-dominated nuclei in optical Seyfert 1 galaxies (NGC 7469, I Zw 1, and IC 4329 A) and eleven luminous infrared galaxies (LIRGs) with various levels of infrared estimated energetic contributions by AGNs at the HCN and HCO+ J=3-2 emission lines. The HCN and HCO+ J=3-2 emission lines are clearly detected at the main nuclei of all sources, except for IC 4329 A. The vibrationally excited (v2=1f) HCN J=3-2 and HCO+ J=3-2 emission lines are simultaneously covered, and HCN v2=1f J=3-2 emission line signatures are seen in the main nuclei of two LIRGs, IRAS 12112+0305 and IRAS 22491-1808, neither of which show clear buried AGN signatures in the infrared. If the vibrational excitation is dominated by infrared radiative pumping, through the absorption of infrared 14 um photons, primarily originating from AGN-heated hot dust emission, then these two LIRGs may contain infrared-elusive, but (sub)millimeter-detectable, extremely deeply buried AGNs. These vibrational...

  17. 红外双波段点目标双色比分析与处理%Analysis and processing of infrared dual waveband radiation ratio based point target

    Institute of Scientific and Technical Information of China (English)

    王文博; 王英瑞

    2015-01-01

    Infrared dual waveband radiation ratio can denote the blackbody’s temperature information, and can be used for temperature measurement. When using infrared dual waveband radiation ratio to measure the temperature of point target, it is difficult to achieve high-accuracy because of various kinds of noises. The recurrence plot theory was used to analyze the non-station of infrared dual waveband radiation ratio. According to the non-station of infrared dual waveband radiation ratio, the target’s response signal in IR single waveband was processed by moving average filter. The IR dual waveband radiation ratio was processed by wavelet soft-threshold filter. Experimental result indicate that, when the SNR>12, 1 K temperature accuracy can be achieved with above processing method for static point target, and 2 K temperature accuracy can be achieved for slow moving point target.%红外双色比能够表征目标的温度信息,但点目标双色比受噪声、探测器盲闪元以及跨像元因素干扰,难以准确测量,影响测温精度。应用递归图法定性分析和判断了点目标双色比的非平稳性。针对这一特性,先对点目标信号应用移动平均滤波做预处理,再通过小波软阈值去噪对双色比进行降噪处理。试验结果表明,在信噪比大于12的条件下,该方法可以实现静态点目标1 K温度分辨率,慢速动态点目标2K温度分辨率。

  18. Infrared heterodyne spectroscopy in astronomy

    Science.gov (United States)

    Betz, A.

    1980-01-01

    A heterodyne spectrometer was constructed and applied to problems in infrared astronomical spectroscopy. The instrument offers distinct observational advantages for the detection and analysis of individual spectral lines at Doppler-limited resolution. Observations of carbon dioxide in planetary atmospheres and ammonia in circumstellar environments demonstrate the substantial role that infrared heterodyne techniques will play in the astronomical spectroscopy of the future.

  19. Design of a miniaturized integrated spectrometer for spectral tissue sensing

    Science.gov (United States)

    Belay, Gebirie Yizengaw; Hoving, Willem; Ottevaere, Heidi; van der Put, Arthur; Weltjens, Wim; Thienpont, Hugo

    2016-04-01

    Minimally-invasive image-guided procedures become increasingly used by physicians to obtain real-time characterization feedback from the tissue at the tip of their interventional device (needle, catheter, endoscopic or laparoscopic probes, etc…) which can significantly improve the outcome of diagnosis and treatment, and ultimately reduce cost of the medical treatment. Spectral tissue sensing using compact photonic probes has the potential to be a valuable tool for screening and diagnostic purposes, e.g. for discriminating between healthy and tumorous tissue. However, this technique requires a low-cost broadband miniature spectrometer so that it is commercially viable for screening at point-of-care locations such as physicians' offices and outpatient centers. Our goal is therefore to develop a miniaturized spectrometer based on diffractive optics that combines the functionalities of a visible/near-infrared (VIS/NIR) and shortwave-infrared (SWIR) spectrometer in one very compact housing. A second goal is that the hardware can be produced in high volume at low cost without expensive time consuming alignment and calibration steps. We have designed a miniaturized spectrometer which operates both in the visible/near-infrared and shortwave-infrared wavelength regions ranging from 400 nm to 1700 nm. The visible/near-infrared part of the spectrometer is designed for wavelengths from 400 nm to 800 nm whereas the shortwave-infrared segment ranges from 850 nm to 1700 nm. The spectrometer has a resolution of 6 nm in the visible/near-infrared wavelength region and 10 nm in the shortwave-infrared. The minimum SNR of the spectrometer for the intended application is about 151 in the VIS/NIR range and 6000 for SWIR. In this paper, the modelling and design, and power budget analysis of the miniaturized spectrometer are presented. Our work opens a door for future affordable micro- spectrometers which can be integrated with smartphones and tablets, and used for point

  20. A rapid method for creating qualitative images indicative of thick oil emulsion on the ocean's surface from imaging spectrometer data

    Science.gov (United States)

    Kokaly, Raymond F.; Hoefen, Todd M.; Livo, K. Eric; Swayze, Gregg A.; Leifer, Ira; McCubbin, Ian B.; Eastwood, Michael L.; Green, Robert O.; Lundeen, Sarah R.; Sarture, Charles M.; Steele, Denis; Ryan, Thomas; Bradley, Eliza S.; Roberts, Dar A.; ,

    2010-01-01

    This report describes a method to create color-composite images indicative of thick oil:water emulsions on the surface of clear, deep ocean water by using normalized difference ratios derived from remotely sensed data collected by an imaging spectrometer. The spectral bands used in the normalized difference ratios are located in wavelength regions where the spectra of thick oil:water emulsions on the ocean's surface have a distinct shape compared to clear water and clouds. In contrast to quantitative analyses, which require rigorous conversion to reflectance, the method described is easily computed and can be applied rapidly to radiance data or data that have been atmospherically corrected or ground-calibrated to reflectance. Examples are shown of the method applied to Airborne Visible/Infrared Imaging Spectrometer data collected May 17 and May 19, 2010, over the oil spill from the Deepwater Horizon offshore oil drilling platform in the Gulf of Mexico.

  1. Photo ion spectrometer

    Science.gov (United States)

    Gruen, Dieter M.; Young, Charles E.; Pellin, Michael J.

    1989-01-01

    A method and apparatus for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected autoionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy.

  2. Study on real-time spectrum recovery system on a FPGA chip for Fourier transform infrared imaging spectrometer%傅里叶变换红外成像光谱仪实时光谱复原FPGA芯片系统研究

    Institute of Scientific and Technical Information of China (English)

    殷世民; 梁永波; 朱健铭; 梁晋涛; 陈真诚

    2015-01-01

    In view of the real-time data processing requirements of Fourier transform infrared imaging spectrometer, a real-time spectrum recovery system on a FPGA chip for the spectrometer was studied which integrates the functions of interferogram nonuniformity correction, spectrum recovery and spectral radiation calibration. The system has made a standardized design of the input signals. It can be run in line way, output target's spectrum in real-time and be embedded in the real-time data processing system for various types of infrared/visible Fourier transform imaging spectrometer which has some specialties such as small volume, fast computing speed, good stability, high reliability and easy to upgrade. The system can establish a good technical foundation for the real-time target recognition based on the spectral characteristics.%针对傅里叶变换红外成像光谱仪实时数据处理技术的要求,研究了一种基于FPGA的集干涉图非均匀性校正、光谱复原、光谱辐射定标于一体的傅里叶变换红外成像光谱仪实时光谱复原芯片系统.该系统对输入信号做了标准化设计,以流水线方式输出目标的复原光谱信息,可嵌入到各种类型的红外/可见光傅里叶变换成像光谱仪的实时数据处理系统中,具有体积小、运算速度快、稳定可靠及易于升级等优点,为基于光谱特征的目标实时识别奠定了良好的技术基础.

  3. ISLA: An Isochronous Spectrometer with Large Acceptances

    Energy Technology Data Exchange (ETDEWEB)

    Bazin, D., E-mail: bazin@nscl.msu.edu; Mittig, W.

    2013-12-15

    A novel type of recoil mass spectrometer and separator is proposed for the future secondary radioactive beams of the ReA12 accelerator at NSCL/FRIB, inspired from the TOFI spectrometer developed at the Los Alamos National Laboratory for online mass measurements. The Isochronous Spectrometer with Large Acceptances (ISLA) is able to achieve superior characteristics without the compromises that usually plague the design of large acceptance spectrometers. ISLA can provide mass-to-charge ratio (m/q) measurements to better than 1 part in 1000 by using an optically isochronous time-of-flight independent of the momentum vector of the recoiling ions, despite large acceptances of 20% in momentum and 64 msr in solid angle. The characteristics of this unique design are shown, including requirements for auxiliary detectors around the target and the various types of reactions to be used with the re-accelerated radioactive beams of the future ReA12 accelerator.

  4. Non-Contact Measurement of the Spectral Emissivity through Active/Passive Synergy of CO₂ Laser at 10.6 µm and 102F FTIR (Fourier Transform Infrared) Spectrometer

    National Research Council Canada - National Science Library

    Zhang, Ren-Hua; Su, Hong-Bo; Tian, Jing; Mi, Su-Juan; Li, Zhao-Liang

    2016-01-01

    ... is an important way to close the underdetermined equations for thermal infrared radiation. Based on the prior research results of both the authors and others, this paper proposes a new approach of obtaining the spectral...

  5. Non-Contact Measurement of the Spectral Emissivity through Active/Passive Synergy of CO2 Laser at 10.6 µm and 102F FTIR (Fourier Transform Infrared) Spectrometer

    National Research Council Canada - National Science Library

    Ren-Hua Zhang; Hong-Bo Su; Jing Tian; Su-Juan Mi; Zhao-Liang Li

    2016-01-01

    ... is an important way to close the underdetermined equations for thermal infrared radiation. Based on the prior research results of both the authors and others, this paper proposes a new approach of obtaining the spectral...

  6. The SAGE spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Pakarinen, J.; Papadakis, P. [University of Liverpool, Department of Physics, Oliver Lodge Laboratory, Liverpool (United Kingdom); University of Jyvaeskylae, Department of Physics, Jyvaeskylae (Finland); Sorri, J.; Greenlees, P.T.; Jones, P.; Julin, R.; Konki, J.; Rahkila, P.; Sandzelius, M. [University of Jyvaeskylae, Department of Physics, Jyvaeskylae (Finland); Herzberg, R.D.; Butler, P.A.; Cox, D.M.; Cresswell, J.R.; Mistry, A.; Page, R.D.; Parr, E.; Sampson, J.; Seddon, D.A.; Thornhill, J.; Wells, D. [University of Liverpool, Department of Physics, Oliver Lodge Laboratory, Liverpool (United Kingdom); Coleman-Smith, P.J.; Lazarus, I.H.; Letts, S.C.; Pucknell, V.F.E.; Simpson, J. [STFC Daresbury Laboratory, Warrington (United Kingdom)

    2014-03-15

    The SAGE spectrometer has been constructed for in-beam nuclear structure studies. SAGE combines a Ge-detector array and an electron spectrometer for detection of γ-rays and internal conversion electrons, respectively, and allows simultaneous observation of both electrons and γ-rays emitted from excited nuclei. SAGE is set up in the Accelerator Laboratory of the University of Jyvaeskylae and works in conjunction with the RITU gas-filled recoil separator and the GREAT focal-plane spectrometer allowing the use of the recoil-decay tagging method. (orig.)

  7. Precision Measurement of the Boron to Carbon Flux Ratio in Cosmic Rays from 1.9 GV to 2.6 TV with the Alpha Magnetic Spectrometer on the International Space Station

    Science.gov (United States)

    Aguilar, M.; Ali Cavasonza, L.; Ambrosi, G.; Arruda, L.; Attig, N.; Aupetit, S.; Azzarello, P.; Bachlechner, A.; Barao, F.; Barrau, A.; Barrin, L.; Bartoloni, A.; Basara, L.; Başeǧmez-du Pree, S.; Battarbee, M.; Battiston, R.; Becker, U.; Behlmann, M.; Beischer, B.; Berdugo, J.; Bertucci, B.; Bindel, K. F.; Bindi, V.; Boella, G.; de Boer, W.; Bollweg, K.; Bonnivard, V.; Borgia, B.; Boschini, M. J.; Bourquin, M.; Bueno, E. F.; Burger, J.; Cadoux, F.; Cai, X. D.; Capell, M.; Caroff, S.; Casaus, J.; Castellini, G.; Cervelli, F.; Chae, M. J.; Chang, Y. H.; Chen, A. I.; Chen, G. M.; Chen, H. S.; Cheng, L.; Chou, H. Y.; Choumilov, E.; Choutko, V.; Chung, C. H.; Clark, C.; Clavero, R.; Coignet, G.; Consolandi, C.; Contin, A.; Corti, C.; Creus, W.; Crispoltoni, M.; Cui, Z.; Dai, Y. M.; Delgado, C.; Della Torre, S.; Demakov, O.; Demirköz, M. B.; Derome, L.; Di Falco, S.; Dimiccoli, F.; Díaz, C.; von Doetinchem, P.; Dong, F.; Donnini, F.; Duranti, M.; D'Urso, D.; Egorov, A.; Eline, A.; Eronen, T.; Feng, J.; Fiandrini, E.; Finch, E.; Fisher, P.; Formato, V.; Galaktionov, Y.; Gallucci, G.; García, B.; García-López, R. J.; Gargiulo, C.; Gast, H.; Gebauer, I.; Gervasi, M.; Ghelfi, A.; Giovacchini, F.; Goglov, P.; Gómez-Coral, D. M.; Gong, J.; Goy, C.; Grabski, V.; Grandi, D.; Graziani, M.; Guo, K. H.; Haino, S.; Han, K. C.; He, Z. H.; Heil, M.; Hoffman, J.; Hsieh, T. H.; Huang, H.; Huang, Z. C.; Huh, C.; Incagli, M.; Ionica, M.; Jang, W. Y.; Jinchi, H.; Kang, S. C.; Kanishev, K.; Kim, G. N.; Kim, K. S.; Kirn, Th.; Konak, C.; Kounina, O.; Kounine, A.; Koutsenko, V.; Krafczyk, M. S.; La Vacca, G.; Laudi, E.; Laurenti, G.; Lazzizzera, I.; Lebedev, A.; Lee, H. T.; Lee, S. C.; Leluc, C.; Li, H. S.; Li, J. Q.; Li, J. Q.; Li, Q.; Li, T. X.; Li, W.; Li, Y.; Li, Z. H.; Li, Z. Y.; Lim, S.; Lin, C. H.; Lipari, P.; Lippert, T.; Liu, D.; Liu, Hu; Lordello, V. D.; Lu, S. Q.; Lu, Y. S.; Luebelsmeyer, K.; Luo, F.; Luo, J. Z.; Lv, S. S.; Machate, F.; Majka, R.; Mañá, C.; Marín, J.; Martin, T.; Martínez, G.; Masi, N.; Maurin, D.; Menchaca-Rocha, A.; Meng, Q.; Mikuni, V. M.; Mo, D. C.; Morescalchi, L.; Mott, P.; Nelson, T.; Ni, J. Q.; Nikonov, N.; Nozzoli, F.; Oliva, A.; Orcinha, M.; Palmonari, F.; Palomares, C.; Paniccia, M.; Pauluzzi, M.; Pensotti, S.; Pereira, R.; Picot-Clemente, N.; Pilo, F.; Pizzolotto, C.; Plyaskin, V.; Pohl, M.; Poireau, V.; Putze, A.; Quadrani, L.; Qi, X. M.; Qin, X.; Qu, Z. Y.; Räihä, T.; Rancoita, P. G.; Rapin, D.; Ricol, J. S.; Rosier-Lees, S.; Rozhkov, A.; Rozza, D.; Sagdeev, R.; Sandweiss, J.; Saouter, P.; Schael, S.; Schmidt, S. M.; Schulz von Dratzig, A.; Schwering, G.; Seo, E. S.; Shan, B. S.; Shi, J. Y.; Siedenburg, T.; Son, D.; Song, J. W.; Sun, W. H.; Tacconi, M.; Tang, X. W.; Tang, Z. C.; Tao, L.; Tescaro, D.; Ting, Samuel C. C.; Ting, S. M.; Tomassetti, N.; Torsti, J.; Türkoǧlu, C.; Urban, T.; Vagelli, V.; Valente, E.; Vannini, C.; Valtonen, E.; Vázquez Acosta, M.; Vecchi, M.; Velasco, M.; Vialle, J. P.; Vitale, V.; Vitillo, S.; Wang, L. Q.; Wang, N. H.; Wang, Q. L.; Wang, X.; Wang, X. Q.; Wang, Z. X.; Wei, C. C.; Weng, Z. L.; Whitman, K.; Wienkenhöver, J.; Wu, H.; Wu, X.; Xia, X.; Xiong, R. Q.; Xu, W.; Yan, Q.; Yang, J.; Yang, M.; Yang, Y.; Yi, H.; Yu, Y. J.; Yu, Z. Q.; Zeissler, S.; Zhang, C.; Zhang, J.; Zhang, J. H.; Zhang, S. D.; Zhang, S. W.; Zhang, Z.; Zheng, Z. M.; Zhu, Z. Q.; Zhuang, H. L.; Zhukov, V.; Zichichi, A.; Zimmermann, N.; Zuccon, P.; AMS Collaboration

    2016-12-01

    Knowledge of the rigidity dependence of the boron to carbon flux ratio (B/C) is important in understanding the propagation of cosmic rays. The precise measurement of the B /C ratio from 1.9 GV to 2.6 TV, based on 2.3 million boron and 8.3 million carbon nuclei collected by AMS during the first 5 years of operation, is presented. The detailed variation with rigidity of the B /C spectral index is reported for the first time. The B /C ratio does not show any significant structures in contrast to many cosmic ray models that require such structures at high rigidities. Remarkably, above 65 GV, the B /C ratio is well described by a single power law RΔ with index Δ =-0.333 ±0.014 (fit ) ±0.005 (syst ) , in good agreement with the Kolmogorov theory of turbulence which predicts Δ =-1 /3 asymptotically.

  8. Effect of spiking strategy and ratio on calibration of on-line visible and near infrared soil sensor for measurement in European farms

    OpenAIRE

    Kuang, Boyan Y.; Mouazen, Abdul Mounem

    2013-01-01

    A previously developed on-line visible and near infrared (vis-NIR) spectroscopy-based soil measurement system was implemented for the measurement of soil organic carbon (OC), total nitrogen (TN) and moisture content (MC) in three fields at three European farms. The on-line sensor platform was coupled with a mobile, fibre type, vis-NIR spectrophotometer (AgroSpec from tec5 Technology for Spectroscopy, Germany), with a measurement range of 305-2200 nm, to acquire soil spectra in diffuse reflect...

  9. Improved Mass Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Improved Mass Spectrometer project will develop system requirements and analyze the path to space qualification.   The results of this project...

  10. Fourier Transform Spectrometer System

    Science.gov (United States)

    Campbell, Joel F. (Inventor)

    2014-01-01

    A Fourier transform spectrometer (FTS) data acquisition system includes an FTS spectrometer that receives a spectral signal and a laser signal. The system further includes a wideband detector, which is in communication with the FTS spectrometer and receives the spectral signal and laser signal from the FTS spectrometer. The wideband detector produces a composite signal comprising the laser signal and the spectral signal. The system further comprises a converter in communication with the wideband detector to receive and digitize the composite signal. The system further includes a signal processing unit that receives the composite signal from the converter. The signal processing unit further filters the laser signal and the spectral signal from the composite signal and demodulates the laser signal, to produce velocity corrected spectral data.

  11. [The principle and analysis of micro-Fourier transform spectrometer based on MEMS micro-mirror].

    Science.gov (United States)

    Chen, Jian-Jun; Zhu, Yong; Liu, Bo; Wei, Wei; Zhang, Jie; Wang, Ning

    2012-11-01

    The present paper puts forward a novel micro-Fourier transform infrared spectrometer based on programmable MEMS micro-mirror. This design uses a MEMS micro-mirror and a slantwise reflector to replace the moving mirror system on traditional spectrometer. This paper analyzes the operating principle of this spectrometer and gives the simulation result to prove the feasibility of this method. The results show that the spectral resolution is less than 5 nm in near-infrared wave band, the wave-length accuracy is approximately 1 nm and the sampling period of this spectrometer is approximately 50 ms. This method can use Hadamard transform to improve the SNR.

  12. Artificial intelligence for geologic mapping with imaging spectrometers

    Science.gov (United States)

    Kruse, F. A.

    1993-01-01

    This project was a three year study at the Center for the Study of Earth from Space (CSES) within the Cooperative Institute for Research in Environmental Science (CIRES) at the University of Colorado, Boulder. The goal of this research was to develop an expert system to allow automated identification of geologic materials based on their spectral characteristics in imaging spectrometer data such as the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). This requirement was dictated by the volume of data produced by imaging spectrometers, which prohibits manual analysis. The research described is based on the development of automated techniques for analysis of imaging spectrometer data that emulate the analytical processes used by a human observer. The research tested the feasibility of such an approach, implemented an operational system, and tested the validity of the results for selected imaging spectrometer data sets.

  13. Study of neutron spectrometers for ITER

    Energy Technology Data Exchange (ETDEWEB)

    Kaellne, Jan

    2005-11-15

    A review is presented of the developments in the field of neutron emission spectrometry (NES) which is of relevance for identifying the role of NES diagnostics on ITER and selecting suitable instrumentation. Neutron spectrometers will be part of the ITER neutron diagnostic complement and this study makes a special effort to examine which performance characteristics the spectrometers should possess to provide the best burning plasma diagnostic information together with neutron cameras and neutron yield monitors. The performance of NES diagnostics is coupled to how much interface space can be provided which has lead to an interest to find compact instruments and their NES capabilities. This study assesses all known spectrometer types of potential interest for ITER and makes a ranking of their performance (as demonstrated or projected), which, in turn, are compared with ITER measurement requirements as a reference; the ratio of diagnostic performance to interface cost for different spectrometers is also discussed for different spectrometer types. The overall result of the study is an assessment of which diagnostic functions neutron measurements can provide in burning plasma fusion experiments on ITER and the role that NES can play depending on the category of instrument installed. Of special note is the result that much higher quality diagnostic information can be obtained from neutron measurements with total yield monitors, profile flux cameras and spectrometers when the synergy in the data is considered in the analysis and interpretation.

  14. Thermal stabilization of static single-mirror Fourier transform spectrometers

    Science.gov (United States)

    Schardt, Michael; Schwaller, Christian; Tremmel, Anton J.; Koch, Alexander W.

    2017-05-01

    Fourier transform spectroscopy has become a standard method for spectral analysis of infrared light. With this method, an interferogram is created by two beam interference which is subsequently Fourier-transformed. Most Fourier transform spectrometers used today provide the interferogram in the temporal domain. In contrast, static Fourier transform spectrometers generate interferograms in the spatial domain. One example of this type of spectrometer is the static single-mirror Fourier transform spectrometer which offers a high etendue in combination with a simple, miniaturized optics design. As no moving parts are required, it also features a high vibration resistance and high measurement rates. However, it is susceptible to temperature variations. In this paper, we therefore discuss the main sources for temperature-induced errors in static single-mirror Fourier transform spectrometers: changes in the refractive index of the optical components used, variations of the detector sensitivity, and thermal expansion of the housing. As these errors manifest themselves in temperature-dependent wavenumber shifts and intensity shifts, they prevent static single-mirror Fourier transform spectrometers from delivering long-term stable spectra. To eliminate these shifts, we additionally present a work concept for the thermal stabilization of the spectrometer. With this stabilization, static single-mirror Fourier transform spectrometers are made suitable for infrared process spectroscopy under harsh thermal environmental conditions. As the static single-mirror Fourier transform spectrometer uses the so-called source-doubling principle, many of the mentioned findings are transferable to other designs of static Fourier transform spectrometers based on the same principle.

  15. Precision Measurement of the Boron to Carbon Flux Ratio in Cosmic Rays from 1.9 GV to 2.6 TV with the Alpha Magnetic Spectrometer on the International Space Station.

    Science.gov (United States)

    Aguilar, M; Ali Cavasonza, L; Ambrosi, G; Arruda, L; Attig, N; Aupetit, S; Azzarello, P; Bachlechner, A; Barao, F; Barrau, A; Barrin, L; Bartoloni, A; Basara, L; Başeğmez-du Pree, S; Battarbee, M; Battiston, R; Becker, U; Behlmann, M; Beischer, B; Berdugo, J; Bertucci, B; Bindel, K F; Bindi, V; Boella, G; de Boer, W; Bollweg, K; Bonnivard, V; Borgia, B; Boschini, M J; Bourquin, M; Bueno, E F; Burger, J; Cadoux, F; Cai, X D; Capell, M; Caroff, S; Casaus, J; Castellini, G; Cervelli, F; Chae, M J; Chang, Y H; Chen, A I; Chen, G M; Chen, H S; Cheng, L; Chou, H Y; Choumilov, E; Choutko, V; Chung, C H; Clark, C; Clavero, R; Coignet, G; Consolandi, C; Contin, A; Corti, C; Creus, W; Crispoltoni, M; Cui, Z; Dai, Y M; Delgado, C; Della Torre, S; Demakov, O; Demirköz, M B; Derome, L; Di Falco, S; Dimiccoli, F; Díaz, C; von Doetinchem, P; Dong, F; Donnini, F; Duranti, M; D'Urso, D; Egorov, A; Eline, A; Eronen, T; Feng, J; Fiandrini, E; Finch, E; Fisher, P; Formato, V; Galaktionov, Y; Gallucci, G; García, B; García-López, R J; Gargiulo, C; Gast, H; Gebauer, I; Gervasi, M; Ghelfi, A; Giovacchini, F; Goglov, P; Gómez-Coral, D M; Gong, J; Goy, C; Grabski, V; Grandi, D; Graziani, M; Guo, K H; Haino, S; Han, K C; He, Z H; Heil, M; Hoffman, J; Hsieh, T H; Huang, H; Huang, Z C; Huh, C; Incagli, M; Ionica, M; Jang, W Y; Jinchi, H; Kang, S C; Kanishev, K; Kim, G N; Kim, K S; Kirn, Th; Konak, C; Kounina, O; Kounine, A; Koutsenko, V; Krafczyk, M S; La Vacca, G; Laudi, E; Laurenti, G; Lazzizzera, I; Lebedev, A; Lee, H T; Lee, S C; Leluc, C; Li, H S; Li, J Q; Li, J Q; Li, Q; Li, T X; Li, W; Li, Y; Li, Z H; Li, Z Y; Lim, S; Lin, C H; Lipari, P; Lippert, T; Liu, D; Liu, Hu; Lordello, V D; Lu, S Q; Lu, Y S; Luebelsmeyer, K; Luo, F; Luo, J Z; Lv, S S; Machate, F; Majka, R; Mañá, C; Marín, J; Martin, T; Martínez, G; Masi, N; Maurin, D; Menchaca-Rocha, A; Meng, Q; Mikuni, V M; Mo, D C; Morescalchi, L; Mott, P; Nelson, T; Ni, J Q; Nikonov, N; Nozzoli, F; Oliva, A; Orcinha, M; Palmonari, F; Palomares, C; Paniccia, M; Pauluzzi, M; Pensotti, S; Pereira, R; Picot-Clemente, N; Pilo, F; Pizzolotto, C; Plyaskin, V; Pohl, M; Poireau, V; Putze, A; Quadrani, L; Qi, X M; Qin, X; Qu, Z Y; Räihä, T; Rancoita, P G; Rapin, D; Ricol, J S; Rosier-Lees, S; Rozhkov, A; Rozza, D; Sagdeev, R; Sandweiss, J; Saouter, P; Schael, S; Schmidt, S M; Schulz von Dratzig, A; Schwering, G; Seo, E S; Shan, B S; Shi, J Y; Siedenburg, T; Son, D; Song, J W; Sun, W H; Tacconi, M; Tang, X W; Tang, Z C; Tao, L; Tescaro, D; Ting, Samuel C C; Ting, S M; Tomassetti, N; Torsti, J; Türkoğlu, C; Urban, T; Vagelli, V; Valente, E; Vannini, C; Valtonen, E; Vázquez Acosta, M; Vecchi, M; Velasco, M; Vialle, J P; Vitale, V; Vitillo, S; Wang, L Q; Wang, N H; Wang, Q L; Wang, X; Wang, X Q; Wang, Z X; Wei, C C; Weng, Z L; Whitman, K; Wienkenhöver, J; Wu, H; Wu, X; Xia, X; Xiong, R Q; Xu, W; Yan, Q; Yang, J; Yang, M; Yang, Y; Yi, H; Yu, Y J; Yu, Z Q; Zeissler, S; Zhang, C; Zhang, J; Zhang, J H; Zhang, S D; Zhang, S W; Zhang, Z; Zheng, Z M; Zhu, Z Q; Zhuang, H L; Zhukov, V; Zichichi, A; Zimmermann, N; Zuccon, P

    2016-12-02

    Knowledge of the rigidity dependence of the boron to carbon flux ratio (B/C) is important in understanding the propagation of cosmic rays. The precise measurement of the B/C ratio from 1.9 GV to 2.6 TV, based on 2.3 million boron and 8.3 million carbon nuclei collected by AMS during the first 5 years of operation, is presented. The detailed variation with rigidity of the B/C spectral index is reported for the first time. The B/C ratio does not show any significant structures in contrast to many cosmic ray models that require such structures at high rigidities. Remarkably, above 65 GV, the B/C ratio is well described by a single power law R^{Δ} with index Δ=-0.333±0.014(fit)±0.005(syst), in good agreement with the Kolmogorov theory of turbulence which predicts Δ=-1/3 asymptotically.

  16. Antiproton Flux, Antiproton-to-Proton Flux Ratio, and Properties of Elementary Particle Fluxes in Primary Cosmic Rays Measured with the Alpha Magnetic Spectrometer on the International Space Station.

    Science.gov (United States)

    Aguilar, M; Ali Cavasonza, L; Alpat, B; Ambrosi, G; Arruda, L; Attig, N; Aupetit, S; Azzarello, P; Bachlechner, A; Barao, F; Barrau, A; Barrin, L; Bartoloni, A; Basara, L; Başeǧmez-du Pree, S; Battarbee, M; Battiston, R; Bazo, J; Becker, U; Behlmann, M; Beischer, B; Berdugo, J; Bertucci, B; Bindi, V; Boella, G; de Boer, W; Bollweg, K; Bonnivard, V; Borgia, B; Boschini, M J; Bourquin, M; Bueno, E F; Burger, J; Cadoux, F; Cai, X D; Capell, M; Caroff, S; Casaus, J; Castellini, G; Cernuda, I; Cervelli, F; Chae, M J; Chang, Y H; Chen, A I; Chen, G M; Chen, H S; Cheng, L; Chou, H Y; Choumilov, E; Choutko, V; Chung, C H; Clark, C; Clavero, R; Coignet, G; Consolandi, C; Contin, A; Corti, C; Coste, B; Creus, W; Crispoltoni, M; Cui, Z; Dai, Y M; Delgado, C; Della Torre, S; Demirköz, M B; Derome, L; Di Falco, S; Dimiccoli, F; Díaz, C; von Doetinchem, P; Dong, F; Donnini, F; Duranti, M; D'Urso, D; Egorov, A; Eline, A; Eronen, T; Feng, J; Fiandrini, E; Finch, E; Fisher, P; Formato, V; Galaktionov, Y; Gallucci, G; García, B; García-López, R J; Gargiulo, C; Gast, H; Gebauer, I; Gervasi, M; Ghelfi, A; Giovacchini, F; Goglov, P; Gómez-Coral, D M; Gong, J; Goy, C; Grabski, V; Grandi, D; Graziani, M; Guerri, I; Guo, K H; Habiby, M; Haino, S; Han, K C; He, Z H; Heil, M; Hoffman, J; Hsieh, T H; Huang, H; Huang, Z C; Huh, C; Incagli, M; Ionica, M; Jang, W Y; Jinchi, H; Kang, S C; Kanishev, K; Kim, G N; Kim, K S; Kirn, Th; Konak, C; Kounina, O; Kounine, A; Koutsenko, V; Krafczyk, M S; La Vacca, G; Laudi, E; Laurenti, G; Lazzizzera, I; Lebedev, A; Lee, H T; Lee, S C; Leluc, C; Li, H S; Li, J Q; Li, J Q; Li, Q; Li, T X; Li, W; Li, Z H; Li, Z Y; Lim, S; Lin, C H; Lipari, P; Lippert, T; Liu, D; Liu, Hu; Lu, S Q; Lu, Y S; Luebelsmeyer, K; Luo, F; Luo, J Z; Lv, S S; Majka, R; Mañá, C; Marín, J; Martin, T; Martínez, G; Masi, N; Maurin, D; Menchaca-Rocha, A; Meng, Q; Mo, D C; Morescalchi, L; Mott, P; Nelson, T; Ni, J Q; Nikonov, N; Nozzoli, F; Nunes, P; Oliva, A; Orcinha, M; Palmonari, F; Palomares, C; Paniccia, M; Pauluzzi, M; Pensotti, S; Pereira, R; Picot-Clemente, N; Pilo, F; Pizzolotto, C; Plyaskin, V; Pohl, M; Poireau, V; Putze, A; Quadrani, L; Qi, X M; Qin, X; Qu, Z Y; Räihä, T; Rancoita, P G; Rapin, D; Ricol, J S; Rodríguez, I; Rosier-Lees, S; Rozhkov, A; Rozza, D; Sagdeev, R; Sandweiss, J; Saouter, P; Schael, S; Schmidt, S M; Schulz von Dratzig, A; Schwering, G; Seo, E S; Shan, B S; Shi, J Y; Siedenburg, T; Son, D; Song, J W; Sun, W H; Tacconi, M; Tang, X W; Tang, Z C; Tao, L; Tescaro, D; Ting, Samuel C C; Ting, S M; Tomassetti, N; Torsti, J; Türkoğlu, C; Urban, T; Vagelli, V; Valente, E; Vannini, C; Valtonen, E; Vázquez Acosta, M; Vecchi, M; Velasco, M; Vialle, J P; Vitale, V; Vitillo, S; Wang, L Q; Wang, N H; Wang, Q L; Wang, X; Wang, X Q; Wang, Z X; Wei, C C; Weng, Z L; Whitman, K; Wienkenhöver, J; Willenbrock, M; Wu, H; Wu, X; Xia, X; Xiong, R Q; Xu, W; Yan, Q; Yang, J; Yang, M; Yang, Y; Yi, H; Yu, Y J; Yu, Z Q; Zeissler, S; Zhang, C; Zhang, J; Zhang, J H; Zhang, S D; Zhang, S W; Zhang, Z; Zheng, Z M; Zhu, Z Q; Zhuang, H L; Zhukov, V; Zichichi, A; Zimmermann, N; Zuccon, P

    2016-08-26

    A precision measurement by AMS of the antiproton flux and the antiproton-to-proton flux ratio in primary cosmic rays in the absolute rigidity range from 1 to 450 GV is presented based on 3.49×10^{5} antiproton events and 2.42×10^{9} proton events. The fluxes and flux ratios of charged elementary particles in cosmic rays are also presented. In the absolute rigidity range ∼60 to ∼500  GV, the antiproton p[over ¯], proton p, and positron e^{+} fluxes are found to have nearly identical rigidity dependence and the electron e^{-} flux exhibits a different rigidity dependence. Below 60 GV, the (p[over ¯]/p), (p[over ¯]/e^{+}), and (p/e^{+}) flux ratios each reaches a maximum. From ∼60 to ∼500  GV, the (p[over ¯]/p), (p[over ¯]/e^{+}), and (p/e^{+}) flux ratios show no rigidity dependence. These are new observations of the properties of elementary particles in the cosmos.

  17. CrossRef Antiproton Flux, Antiproton-to-Proton Flux Ratio, and Properties of Elementary Particle Fluxes in Primary Cosmic Rays Measured with the Alpha Magnetic Spectrometer on the International Space Station

    CERN Document Server

    Aguilar, M; Alpat, B; Ambrosi, G; Arruda, L; Attig, N; Aupetit, S; Azzarello, P; Bachlechner, A; Barao, F; Barrau, A; Barrin, L; Bartoloni, A; Basara, L; Başeǧmez-du Pree, S; Battarbee, M; Battiston, R; Bazo, J; Becker, U; Behlmann, M; Beischer, B; Berdugo, J; Bertucci, B; Bindi, V; Boella, G; de Boer, W; Bollweg, K; Bonnivard, V; Borgia, B; Boschini, M  J; Bourquin, M; Bueno, E  F; Burger, J; Cadoux, F; Cai, X  D; Capell, M; Caroff, S; Casaus, J; Castellini, G; Cernuda, I; Cervelli, F; Chae, M  J; Chang, Y  H; Chen, A  I; Chen, G  M; Chen, H  S; Cheng, L; Chou, H  Y; Choumilov, E; Choutko, V; Chung, C  H; Clark, C; Clavero, R; Coignet, G; Consolandi, C; Contin, A; Corti, C; Coste, B; Creus, W; Crispoltoni, M; Cui, Z; Dai, Y  M; Delgado, C; Della Torre, S; Demirköz, M  B; Derome, L; Di Falco, S; Dimiccoli, F; Díaz, C; von Doetinchem, P; Dong, F; Donnini, F; Duranti, M; D'Urso, D; Egorov, A; Eline, A; Eronen, T; Feng, J; Fiandrini, E; Finch, E; Fisher, P; Formato, V; Galaktionov, Y; Gallucci, G; García, B; García-López, R  J; Gargiulo, C; Gast, H; Gebauer, I; Gervasi, M; Ghelfi, A; Giovacchini, F; Goglov, P; Gómez-Coral, D  M; Gong, J; Goy, C; Grabski, V; Grandi, D; Graziani, M; Guerri, I; Guo, K  H; Habiby, M; Haino, S; Han, K  C; He, Z  H; Heil, M; Hoffman, J; Hsieh, T  H; Huang, H; Huang, Z  C; Huh, C; Incagli, M; Ionica, M; Jang, W  Y; Jinchi, H; Kang, S  C; Kanishev, K; Kim, G  N; Kim, K  S; Kirn, Th; Konak, C; Kounina, O; Kounine, A; Koutsenko, V; Krafczyk, M  S; La Vacca, G; Laudi, E; Laurenti, G; Lazzizzera, I; Lebedev, A; Lee, H  T; Lee, S  C; Leluc, C; Li, H  S; Li, J  Q; Li, Q; Li, T  X; Li, W; Li, Z  H; Li, Z  Y; Lim, S; Lin, C  H; Lipari, P; Lippert, T; Liu, D; Liu, Hu; Lu, S  Q; Lu, Y  S; Luebelsmeyer, K; Luo, F; Luo, J  Z; Lv, S  S; Majka, R; Mañá, C; Marín, J; Martin, T; Martínez, G; Masi, N; Maurin, D; Menchaca-Rocha, A; Meng, Q; Mo, D  C; Morescalchi, L; Mott, P; Nelson, T; Ni, J  Q; Nikonov, N; Nozzoli, F; Nunes, P; Oliva, A; Orcinha, M; Palmonari, F; Palomares, C; Paniccia, M; Pauluzzi, M; Pensotti, S; Pereira, R; Picot-Clemente, N; Pilo, F; Pizzolotto, C; Plyaskin, V; Pohl, M; Poireau, V; Putze, A; Quadrani, L; Qi, X  M; Qin, X; Qu, Z  Y; Räihä, T; Rancoita, P  G; Rapin, D; Ricol, J  S; Rodríguez, I; Rosier-Lees, S; Rozhkov, A; Rozza, D; Sagdeev, R; Sandweiss, J; Saouter, P; Schael, S; Schmidt, S  M; Schulz von Dratzig, A; Schwering, G; Seo, E  S; Shan, B  S; Shi, J  Y; Siedenburg, T; Son, D; Song, J  W; Sun, W  H; Tacconi, M; Tang, X  W; Tang, Z  C; Tao, L; Tescaro, D; Ting, Samuel C  C; Ting, S  M; Tomassetti, N; Torsti, J; Türkoğlu, C; Urban, T; Vagelli, V; Valente, E; Vannini, C; Valtonen, E; Vázquez Acosta, M; Vecchi, M; Velasco, M; Vialle, J  P; Vitale, V; Vitillo, S; Wang, L  Q; Wang, N  H; Wang, Q  L; Wang, X; Wang, X  Q; Wang, Z  X; Wei, C  C; Weng, Z  L; Whitman, K; Wienkenhöver, J; Willenbrock, M; Wu, H; Wu, X; Xia, X; Xiong, R  Q; Xu, W; Yan, Q; Yang, J; Yang, M; Yang, Y; Yi, H; Yu, Y  J; Yu, Z  Q; Zeissler, S; Zhang, C; Zhang, J; Zhang, J  H; Zhang, S  D; Zhang, S  W; Zhang, Z; Zheng, Z  M; Zhu, Z  Q; Zhuang, H  L; Zhukov, V; Zichichi, A; Zimmermann, N; Zuccon, P

    2016-01-01

    A precision measurement by AMS of the antiproton flux and the antiproton-to-proton flux ratio in primary cosmic rays in the absolute rigidity range from 1 to 450 GV is presented based on 3.49×105 antiproton events and 2.42×109 proton events. The fluxes and flux ratios of charged elementary particles in cosmic rays are also presented. In the absolute rigidity range ∼60 to ∼500  GV, the antiproton p¯, proton p, and positron e+ fluxes are found to have nearly identical rigidity dependence and the electron e− flux exhibits a different rigidity dependence. Below 60 GV, the (p¯/p), (p¯/e+), and (p/e+) flux ratios each reaches a maximum. From ∼60 to ∼500  GV, the (p¯/p), (p¯/e+), and (p/e+) flux ratios show no rigidity dependence. These are new observations of the properties of elementary particles in the cosmos.

  18. Antiproton Flux, Antiproton-to-Proton Flux Ratio, and Properties of Elementary Particle Fluxes in Primary Cosmic Rays Measured with the Alpha Magnetic Spectrometer on the International Space Station

    Science.gov (United States)

    Aguilar, M.; Ali Cavasonza, L.; Alpat, B.; Ambrosi, G.; Arruda, L.; Attig, N.; Aupetit, S.; Azzarello, P.; Bachlechner, A.; Barao, F.; Barrau, A.; Barrin, L.; Bartoloni, A.; Basara, L.; Başeǧmez-du Pree, S.; Battarbee, M.; Battiston, R.; Bazo, J.; Becker, U.; Behlmann, M.; Beischer, B.; Berdugo, J.; Bertucci, B.; Bindi, V.; Boella, G.; de Boer, W.; Bollweg, K.; Bonnivard, V.; Borgia, B.; Boschini, M. J.; Bourquin, M.; Bueno, E. F.; Burger, J.; Cadoux, F.; Cai, X. D.; Capell, M.; Caroff, S.; Casaus, J.; Castellini, G.; Cernuda, I.; Cervelli, F.; Chae, M. J.; Chang, Y. H.; Chen, A. I.; Chen, G. M.; Chen, H. S.; Cheng, L.; Chou, H. Y.; Choumilov, E.; Choutko, V.; Chung, C. H.; Clark, C.; Clavero, R.; Coignet, G.; Consolandi, C.; Contin, A.; Corti, C.; Coste, B.; Creus, W.; Crispoltoni, M.; Cui, Z.; Dai, Y. M.; Delgado, C.; Della Torre, S.; Demirköz, M. B.; Derome, L.; Di Falco, S.; Dimiccoli, F.; Díaz, C.; von Doetinchem, P.; Dong, F.; Donnini, F.; Duranti, M.; D'Urso, D.; Egorov, A.; Eline, A.; Eronen, T.; Feng, J.; Fiandrini, E.; Finch, E.; Fisher, P.; Formato, V.; Galaktionov, Y.; Gallucci, G.; García, B.; García-López, R. J.; Gargiulo, C.; Gast, H.; Gebauer, I.; Gervasi, M.; Ghelfi, A.; Giovacchini, F.; Goglov, P.; Gómez-Coral, D. M.; Gong, J.; Goy, C.; Grabski, V.; Grandi, D.; Graziani, M.; Guerri, I.; Guo, K. H.; Habiby, M.; Haino, S.; Han, K. C.; He, Z. H.; Heil, M.; Hoffman, J.; Hsieh, T. H.; Huang, H.; Huang, Z. C.; Huh, C.; Incagli, M.; Ionica, M.; Jang, W. Y.; Jinchi, H.; Kang, S. C.; Kanishev, K.; Kim, G. N.; Kim, K. S.; Kirn, Th.; Konak, C.; Kounina, O.; Kounine, A.; Koutsenko, V.; Krafczyk, M. S.; La Vacca, G.; Laudi, E.; Laurenti, G.; Lazzizzera, I.; Lebedev, A.; Lee, H. T.; Lee, S. C.; Leluc, C.; Li, H. S.; Li, J. Q.; Li, J. Q.; Li, Q.; Li, T. X.; Li, W.; Li, Z. H.; Li, Z. Y.; Lim, S.; Lin, C. H.; Lipari, P.; Lippert, T.; Liu, D.; Liu, Hu; Lu, S. Q.; Lu, Y. S.; Luebelsmeyer, K.; Luo, F.; Luo, J. Z.; Lv, S. S.; Majka, R.; Mañá, C.; Marín, J.; Martin, T.; Martínez, G.; Masi, N.; Maurin, D.; Menchaca-Rocha, A.; Meng, Q.; Mo, D. C.; Morescalchi, L.; Mott, P.; Nelson, T.; Ni, J. Q.; Nikonov, N.; Nozzoli, F.; Nunes, P.; Oliva, A.; Orcinha, M.; Palmonari, F.; Palomares, C.; Paniccia, M.; Pauluzzi, M.; Pensotti, S.; Pereira, R.; Picot-Clemente, N.; Pilo, F.; Pizzolotto, C.; Plyaskin, V.; Pohl, M.; Poireau, V.; Putze, A.; Quadrani, L.; Qi, X. M.; Qin, X.; Qu, Z. Y.; Räihä, T.; Rancoita, P. G.; Rapin, D.; Ricol, J. S.; Rodríguez, I.; Rosier-Lees, S.; Rozhkov, A.; Rozza, D.; Sagdeev, R.; Sandweiss, J.; Saouter, P.; Schael, S.; Schmidt, S. M.; Schulz von Dratzig, A.; Schwering, G.; Seo, E. S.; Shan, B. S.; Shi, J. Y.; Siedenburg, T.; Son, D.; Song, J. W.; Sun, W. H.; Tacconi, M.; Tang, X. W.; Tang, Z. C.; Tao, L.; Tescaro, D.; Ting, Samuel C. C.; Ting, S. M.; Tomassetti, N.; Torsti, J.; Türkoǧlu, C.; Urban, T.; Vagelli, V.; Valente, E.; Vannini, C.; Valtonen, E.; Vázquez Acosta, M.; Vecchi, M.; Velasco, M.; Vialle, J. P.; Vitale, V.; Vitillo, S.; Wang, L. Q.; Wang, N. H.; Wang, Q. L.; Wang, X.; Wang, X. Q.; Wang, Z. X.; Wei, C. C.; Weng, Z. L.; Whitman, K.; Wienkenhöver, J.; Willenbrock, M.; Wu, H.; Wu, X.; Xia, X.; Xiong, R. Q.; Xu, W.; Yan, Q.; Yang, J.; Yang, M.; Yang, Y.; Yi, H.; Yu, Y. J.; Yu, Z. Q.; Zeissler, S.; Zhang, C.; Zhang, J.; Zhang, J. H.; Zhang, S. D.; Zhang, S. W.; Zhang, Z.; Zheng, Z. M.; Zhu, Z. Q.; Zhuang, H. L.; Zhukov, V.; Zichichi, A.; Zimmermann, N.; Zuccon, P.; AMS Collaboration

    2016-08-01

    A precision measurement by AMS of the antiproton flux and the antiproton-to-proton flux ratio in primary cosmic rays in the absolute rigidity range from 1 to 450 GV is presented based on 3.49 ×1 05 antiproton events and 2.42 ×1 09 proton events. The fluxes and flux ratios of charged elementary particles in cosmic rays are also presented. In the absolute rigidity range ˜60 to ˜500 GV , the antiproton p ¯, proton p , and positron e+ fluxes are found to have nearly identical rigidity dependence and the electron e- flux exhibits a different rigidity dependence. Below 60 GV, the (p ¯/p ), (p ¯/e+), and (p /e+) flux ratios each reaches a maximum. From ˜60 to ˜500 GV , the (p ¯/p ), (p ¯/e+), and (p /e+) flux ratios show no rigidity dependence. These are new observations of the properties of elementary particles in the cosmos.

  19. Usage and routine maintenance of TENSON 27 Fourier transform infrared spectrometer%T ENSOR27傅里叶变换红外光谱仪的使用与日常维护

    Institute of Scientific and Technical Information of China (English)

    张远方

    2014-01-01

    介绍了T ENSON 27型傅立叶变换红外光谱仪的特点和工作原理,以及在安装使用过程中注意事项和日常维护,同时还介绍了样品测试及样品制备的方法。%This paper mainly introduces the characteristics and operational principle of TENSON 27 FT-IR spectrometer ,and discusses the attentions of routine maintenance .The methods of sample testing and sample preparation are described at same time .

  20. OH-asterisk (7-5) Meinel band dayglow and nightglow measured by the SME limb scanning near infrared spectrometer - Comparison of the observed seasonal variability with two-dimensional model simulations

    Science.gov (United States)

    Le Texier, H.; Solomon, S.; Thomas, R. J.; Garcia, R. R.

    1989-01-01

    Seasonal variations of the OH-asterisk (7-5) mesospheric hydroxyl emission at 1.89 microns observed by the SME near-IR spectrometer are compared with the theoretical predictions of a two-dimensional dynamical/chemical model. The good agreement found at low latitudes for both dayglow and nightglow provides support for the model assumption that breaking gravity waves induce seasonal and latitudinal variations in diffusion. The seasonal behavior of atomic hydrogen in the upper mesosphere (related to vertical transport) and/or uncertainties in the OH Meinel band parameters are proposed as possible explanations for the discrepancy noted between model and observational data for the middle latitudes.

  1. A micromachined mass spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Petzold, G.; Siebert, P.; Mueller, J. [Technische Univ. Hamburg-Harburg, Hamburg (Germany). Dept. of Microsystemtechnology

    2001-07-01

    This paper presents the concept, the processing and the simulated and measured characteristics of a miniaturised mass spectrometer, with dimensions of approximately only a few cm{sup 3}. The mass spectrometer consists of three main parts to be manufactured by micro structuring: an electron source, an ionisation chamber including accelerating and focusing units and a mass analyser with detector. Its fabrication is based on techniques used in micro-system processing and in particular anisotropic etching, thin film deposition, electroplating, and anodic bonding. The aim of the concept for this micro mass spectrometer is not only to scale down a macroscopic system but it also takes advantage of the added features of a micro system, i.e. a high Knudsen number of about 3 at a pressure of a few Pascal, and high field strengths at a relatively low voltage. Therefore, the demands on the vacuum systems and the electrical circuits are much more simple compared to a macroscopic mass spectrometer. In the presented design of the micro mass spectrometer the resolution is in the range of 10 to 20 at a sensitivity of several tens of ppm. (orig.)

  2. Use of a Fourier transform spectrometer on a balloon-borne telescope and at the multiple mirror telescope (MMT)

    Science.gov (United States)

    Traub, W. A.; Chance, K. V.; Brasunas, J. C.; Vrtilek, J. M.; Carleton, N. P.

    1982-01-01

    The design and use of an infrared Fourier transform spectrometer which has been used for observations of laboratory, stratospheric, and astronomical spectra are described. The spectrometer has a spectral resolution of 0.032/cm and has operated in the mid-infrared (12 to 13 microns) as well as the far-infrared (40 to 140 microns), using both bolometer and photoconductor cryogenic detectors. The spectrometer is optically sized to accept an f/9 beam from the multi-mirror telescope (MMT). The optical and electronic design are discussed, including remote operation of the spectrometer on a balloon-borne 102-cm telescope. The performance of the laser-controlled, screw-driven moving cat's-eye mirror is discussed. Segments of typical far-infrared balloon flight spectra, lab spectra, and mid-infrared MMT spectra are presented. Data reduction, interferogram processing, artifact removal, wavelength calibration, and intensity calibration methods are discussed. Future use of the spectrometer is outlined.

  3. HyTES: Thermal Imaging Spectrometer Development

    Science.gov (United States)

    Johnson, William R.; Hook, Simon J.; Mouroulis, Pantazis; Wilson, Daniel W.; Gunapala, Sarath D.; Realmuto, Vincent; Lamborn, Andy; Paine, Chris; Mumolo, Jason M.; Eng, Bjorn T.

    2011-01-01

    The Jet Propulsion Laboratory has developed the Hyperspectral Thermal Emission Spectrometer (HyTES). It is an airborne pushbroom imaging spectrometer based on the Dyson optical configuration. First low altitude test flights are scheduled for later this year. HyTES uses a compact 7.5-12 micrometer m hyperspectral grating spectrometer in combination with a Quantum Well Infrared Photodetector (QWIP) and grating based spectrometer. The Dyson design allows for a very compact and optically fast system (F/1.6). Cooling requirements are minimized due to the single monolithic prism-like grating design. The configuration has the potential to be the optimal science-grade imaging spectroscopy solution for high altitude, lighter-than-air (HAA, LTA) vehicles and unmanned aerial vehicles (UAV) due to its small form factor and relatively low power requirements. The QWIP sensor allows for optimum spatial and spectral uniformity and provides adequate responsivity which allows for near 100mK noise equivalent temperature difference (NEDT) operation across the LWIR passband. The QWIP's repeatability and uniformity will be helpful for data integrity since currently an onboard calibrator is not planned. A calibration will be done before and after eight hour flights to gage any inconsistencies. This has been demonstrated with lab testing. Further test results show adequate NEDT, linearity as well as applicable earth science emissivity target results (Silicates, water) measured in direct sunlight.

  4. The GRIFFIN spectrometer

    Science.gov (United States)

    Svensson, C. E.; Garnsworthy, A. B.

    2014-01-01

    Gamma-Ray Infrastructure For Fundamental Investigations of Nuclei (GRIFFIN) is an advanced new high-efficiency γ-ray spectrometer being developed for use in decay spectroscopy experiments with low-energy radioactive ion beams provided by TRIUMF's Isotope Separator and Accelerator (ISAC-I) radioactive ion beam facility. GRIFFIN will be comprised of sixteen large-volume clover-type high-purity germanium (HPGe) γ-ray detectors coupled to custom digital signal processing electronics and used in conjunction with a suite of auxiliary detection systems. This article provides an overview of the GRIFFIN spectrometer and its expected performance characteristics.

  5. Miniaturised TOF mass spectrometer

    Science.gov (United States)

    Rohner, U.; Wurz, P.; Whitby, J.

    2003-04-01

    For the BepiColombo misson of ESA to Mercury, we built a prototype of a miniaturised Time of Flight mass spectrometer with a low mass and low power consumption. Particles will be set free form the surface and ionized by short laser pluses. The mass spectrometer is dedicated to measure the elemental and isotopic composition of almost all elements of Mercurys planetary surface with an adequate dynamique range, mass range and mass resolution. We will present first results of our prototype and future designs.

  6. The Geostationary Fourier Transform Spectrometer

    Science.gov (United States)

    Key, Richard; Sander, Stanley; Eldering, Annmarie; Blavier, Jean-Francois; Bekker, Dmitriy; Manatt, Ken; Rider, David; Wu, Yen-Hung

    2012-01-01

    The Geostationary Fourier Transform Spectrometer (GeoFTS) is an imaging spectrometer designed for a geostationary orbit (GEO) earth science mission to measure key atmospheric trace gases and process tracers related to climate change and human activity. GEO allows GeoFTS to continuously stare at a region of the earth for frequent sampling to capture the variability of biogenic fluxes and anthropogenic emissions from city to continental spatial scales and temporal scales from diurnal, synoptic, seasonal to interannual. The measurement strategy provides a process based understanding of the carbon cycle from contiguous maps of carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), and chlorophyll fluorescence (CF) collected many times per day at high spatial resolution (2.7kmx2.7km at nadir). The CO2/CH4/CO/CF measurement suite in the near infrared spectral region provides the information needed to disentangle natural and anthropogenic contributions to atmospheric carbon concentrations and to minimize uncertainties in the flow of carbon between the atmosphere and surface. The half meter cube size GeoFTS instrument is based on a Michelson interferometer design that uses all high TRL components in a modular configuration to reduce complexity and cost. It is self-contained and as independent of the spacecraft as possible with simple spacecraft interfaces, making it ideal to be a "hosted" payload on a commercial communications satellite mission. The hosted payload approach for measuring the major carbon-containing gases in the atmosphere from the geostationary vantage point will affordably advance the scientific understating of carbon cycle processes and climate change.

  7. Determination of noise-free optical constants in the infrared by Kramers-Kronig transformation of the reflectance ratio in s- and p-polarization.

    Science.gov (United States)

    Gilli, Eduard; Schennach, Robert

    2010-06-01

    A method for Kramers-Kronig transformation of the reflectance ratio of s- and p-polarized light is discussed. The method is well suited for the determination of the optical constants of isotropic samples such as pellets prepared from powders. An algorithm is given that performs the transformation, including extrapolation at the data margins and an automated data fitting routine, that can handle very complex spectra of, e.g., biomacromolecules such as cellulose to obtain noise free spectra. Criteria for evaluation of the quality of the obtained data are given, and experimental data for cellulose II and xylane are presented.

  8. Development of Experimental Teaching New Pattern of Instrumental Analysis——Taking the Teaching of Fourier Transform Infrared Spectrometer as an Example%仪器分析实验教学新模式开发——以傅里叶红外光谱仪教学为例

    Institute of Scientific and Technical Information of China (English)

    杨士春

    2012-01-01

    Instrumental analysis course was opened by Tianjin Agricultural University for cultivating students' ability of grasping accurately and using advanced instrument.Taking fourier transform infrared spectrum experimental teaching as an example.Reform of content,model,method of fourier transform infrared spectrometer teaching,making students improve their experimental skills,cultivate good quality of the experiment and rigorous research style.%天津农学院为了培养学生准确掌握和使用先进分析仪器的能力,开设了仪器分析课程。以傅里叶红外光谱仪教学为例,探讨了改革傅里叶红外光谱仪的实验教学内容、教学模式、教学方法,使学生的实验技能得到提高,培养学生良好的实验素质和严谨的科研作风。

  9. Development and commissioning of a double-prism spectrometer for the diagnosis of femtosecond electron bunches

    Energy Technology Data Exchange (ETDEWEB)

    Wunderlich, Steffen

    2016-12-15

    Free-electron lasers as accelerator-driven light sources and wakefield-based acceleration in plasmas require the knowledge of the longitudinal extension and the longitudinal current profile of the involved electron bunches. These bunches can yield lengths below 10 μm, or durations shorter than approx. 33 fs, as well as charges less than 30 pC. During this work, transition radiation from relativistic electron bunches was investigated in the mid-infrared wavelength regime. A spectrometer using an arrangement of two consecutive zinc selenide prisms was developed, built and commissioned. The instrument covers the spectral range from 2 μm to 18 μm in a single shot. Measurements with the double-prism spectrometer were conducted at the FEL facilities FLASH at DESY in Hamburg, Germany and FELIX at the Radboud Universiteit in Nijmegen, The Netherlands. The assessment of the spectrometer and comparative studies with established diagnostic devices at FLASH show high signal-to-noise ratios at bunch charges below 10 pC and confirm the obtained results.

  10. Thermostatic system of sensor in NIR spectrometer based on PID control

    Science.gov (United States)

    Wang, Zhihong; Qiao, Liwei; Ji, Xufei

    2016-11-01

    Aiming at the shortcomings of the primary sensor thermostatic control system in the near infrared (NIR) spectrometer, a novel thermostatic control system based on proportional-integral-derivative (PID) control technology was developed to improve the detection precision of the NIR spectrometer. There were five parts including bridge amplifier circuit, analog-digital conversion (ADC) circuit, microcontroller, digital-analog conversion (DAC) circuit and drive circuit in the system. The five parts formed a closed-loop control system based on PID algorithm that was used to control the error between the temperature calculated by the sampling data of ADC and the designed temperature to ensure the stability of the spectrometer's sensor. The experimental results show that, when the operating temperature of sensor is -11°, compared with the original system, the temperature control precision of the new control system is improved from ±0.64° to ±0.04° and the spectrum signal to noise ratio (SNR) is improved from 4891 to 5967.

  11. The MIRI Medium Resolution Spectrometer calibration pipeline

    CERN Document Server

    Labiano, A; Bailey, J I; Beard, S; Dicken, D; García-Marín, M; Geers, V; Glasse, A; Glauser, A; Gordon, K; Justtanont, K; Klaassen, P; Lahuis, F; Law, D; Morrison, J; Müller, M; Rieke, G; Vandenbussche, B; Wright, G

    2016-01-01

    The Mid-Infrared Instrument (MIRI) Medium Resolution Spectrometer (MRS) is the only mid-IR Integral Field Spectrometer on board James Webb Space Telescope. The complexity of the MRS requires a very specialized pipeline, with some specific steps not present in other pipelines of JWST instruments, such as fringe corrections and wavelength offsets, with different algorithms for point source or extended source data. The MRS pipeline has also two different variants: the baseline pipeline, optimized for most foreseen science cases, and the optimal pipeline, where extra steps will be needed for specific science cases. This paper provides a comprehensive description of the MRS Calibration Pipeline from uncalibrated slope images to final scientific products, with brief descriptions of its algorithms, input and output data, and the accessory data and calibration data products necessary to run the pipeline.

  12. Compact High-Resolution Broad-Band Terahertz Fabry-Perot Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Our objective is to develop a compact scanning Fabry-Perot spectrometer, for satellite far-infrared astronomy and Earth remote sensing, that operates at wavelengths...

  13. The Omega spectrometer

    CERN Multimedia

    1972-01-01

    The Omega spectrometer which came into action during the year. An array of optical spark chambers can be seen withdrawn from the magnet aperture. In the 'igloo' above the magnet is located the Plumbicon camera system which collects information from the spark chambers.

  14. Speckle-based spectrometer

    DEFF Research Database (Denmark)

    Chakrabarti, Maumita; Jakobsen, Michael Linde; Hanson, Steen Grüner

    2015-01-01

    A novel spectrometer concept is analyzed and experimentally verified. The method relies on probing the speckle displacement due to a change in the incident wavelength. A rough surface is illuminated at an oblique angle, and the peak position of the covariance between the speckle patterns observed...

  15. In Situ Mass Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The In Situ Mass Spectrometer projects focuses on a specific subsystem to leverage advanced research for laser-based in situ mass spectrometer development...

  16. Electro-optic imaging Fourier transform spectrometer

    Science.gov (United States)

    Chao, Tien-Hsin (Inventor); Znod, Hanying (Inventor)

    2009-01-01

    An Electro-Optic Imaging Fourier Transform Spectrometer (EOIFTS) for Hyperspectral Imaging is described. The EOIFTS includes an input polarizer, an output polarizer, and a plurality of birefringent phase elements. The relative orientations of the polarizers and birefringent phase elements can be changed mechanically or via a controller, using ferroelectric liquid crystals, to substantially measure the spectral Fourier components of light propagating through the EIOFTS. When achromatic switches are used as an integral part of the birefringent phase elements, the EIOFTS becomes suitable for broadband applications, with over 1 micron infrared bandwidth.

  17. Time delay and excitation mode induced tunable red/near-infrared to green emission ratio of Er doped BiOCl

    Science.gov (United States)

    Avram, Daniel; Florea, Mihaela; Tiseanu, Ion; Tiseanu, Carmen

    2015-09-01

    Herein, we report on the emission color tunability of Er doped BiOCl measured under up—conversion as well as x-ray excitation modes. The dependence of red (670 nm) to green emission (543 nm) ratio on Er concentration (1 and 5%), excitation wavelength into different (656.4, 802 and 976 nm) or across single Er absorption levels (965 ÷ 990 nm) and delay after the laser pulse (0.001 ÷ 1 ms) is discussed in terms of ground state absorption/excited state absorption and energy transfer up-conversion mechanisms. A first example of extended Er x-ray emission measured in the range of 500 to 1700 nm shows comparable emission intensities corresponding to 543 nm and 1500 nm based transitions. The present results together with our earlier report on the upconversion emission of Er doped BiOCl excited at 1500 nm, suggest that Er doped BiOCl may be considered an attractive system for optical and x-ray imaging applications.

  18. The investigations of changes in mineral-organic and carbon-phosphate ratios in the mixed saliva by synchrotron infrared spectroscopy

    Science.gov (United States)

    Seredin, Pavel; Goloshchapov, Dmitry; Kashkarov, Vladimir; Ippolitov, Yuri; Bambery, Keith

    The objective of this study was to investigate the efficiency of the saturation of mixed saliva by mineral complexes and groups necessary for the remineralisation of tooth enamel using exogenous and endogenous methods of caries prevention. Using IR spectroscopy and high-intensity synchrotron radiation, changes in the composition of the human mixed saliva were identified when exogenous and endogenous methods of caries prevention are employed. Based on the calculations of mineral/organic and carbon/phosphate ratios, changes in the composition of the human mixed saliva depending on a certain type of prevention were identified. It is shown that the use of a toothpaste (exogenous prevention) alone based on a multi-mineral complex including calcium glycerophosphate provides only a short-term effect of saturating the oral cavity with mineral complexes and groups. Rinsing of the oral cavity with water following the preventive use of a toothpaste completely removes the effect of the saturation of the mixed saliva with mineral groups and complexes. The use of tablets of a multi-mineral complex with calcium glycerophosphate (endogenous prevention) in combination with exogenous prevention causes an average increase of ∼10% in the content of mineral groups and complexes in the mixed saliva and allows long-term saturation of the oral fluid by them. This method outperforms the exogenous one owing to a long-term effect of optimal concentrations of endogenous and biologically available derivatives of phosphates on the enamel surface.

  19. Wide-angle, high-extinction-ratio, infrared polarizing beam splitters using frustrated total internal reflection by an embedded centrosymmetric multilayer

    Science.gov (United States)

    Perla, Siva R.; Azzam, R. M. A.

    2007-07-01

    A centrosymmetric multilayer stack of two transparent thin-film materials, which is embedded in a high-index prism, is designed to function as an efficient polarizer or polarizing beam splitter (PBS) under conditions of frustrated total internal reflection over an extended range of incidence angles. The S(LH)kLHL(HL)kS multilayer structure consists of a high-index center layer H sandwiched between two identical low-index films L and high-index-low-index bilayers repeated (k times) on both sides of the central trilayer maintaining the symmetry of the entire stack. For a given set of refractive indices, all possible solutions for the thicknesses of the layers that suppress the reflection of p-polarized light at a specified angle, and the associated reflectance of the system for the orthogonal s polarization, are determined. The angular and spectral sensitivities of polarizing multilayer stacks employing 3, 7, 11, 15, and 19 layers of BaF2 and PbTe thin films embedded in a ZnS prism, operating at λ=10.6 μm, are presented. The 15- and 19-layer stack designs achieve extinction ratios (ER) >30 dB in both reflection and transmission over a 46°-56° field of view inside the prism. Spectral analysis reveals additional discrete polarizing wavelengths other than the design wavelength (λ=10.6 μm). The 11-, 15-, and 19-layer designs function as effective s-reflection polarizers (|Rs|2>99%) over a 2-3 μm bandwidth. The effect of decreasing the refractive index contrast between the H and L layers on the resulting ER is also considered.

  20. Optical and physical properties of stratospheric aerosols from balloon measurements in the visible and near-infrared domains. 1. Analysis of aerosol extinction spectra from the AMON and SALOMON balloonborne spectrometers.

    Science.gov (United States)

    Berthet, Gwenaël; Renard, Jean-Baptiste; Brogniez, Colette; Robert, Claude; Chartier, Michel; Pirre, Michel

    2002-12-20

    Aerosol extinction coefficients have been derived in the 375-700-nm spectral domain from measurement in the stratosphere since 1992, at night, at mid- and high latitudes from 15 to 40 km, by two balloonborne spectrometers, Absorption par les Minoritaires Ozone et NO(chi) (AMON) and Spectroscopie d'Absorption Lunaire pour l'Observation des Minoritaires Ozone et NO(chi) (SALOMON). Log-normal size distributions associated with the Mie-computed extinction spectra that best fit the measurements permit calculation of integrated properties of the distributions. Although measured extinction spectra that correspond to background aerosols can be reproduced by the Mie scattering model by use of monomodal log-normal size distributions, each flight reveals some large discrepancies between measurement and theory at several altitudes. The agreement between measured and Mie-calculated extinction spectra is significantly improved by use of bimodal log-normal distributions. Nevertheless, neither monomodal nor bimodal distributions permit correct reproduction of some of the measured extinction shapes, especially for the 26 February 1997 AMON flight, which exhibited spectral behavior attributed to particles from a polar stratospheric cloud event.

  1. Optical and physical properties of stratospheric aerosols from balloon measurements in the visible and near-infrared domains. I. Analysis of aerosol extinction spectra from the AMON and SALOMON balloonborne spectrometers

    Science.gov (United States)

    Berthet, Gwenaël; Renard, Jean-Baptiste; Brogniez, Colette; Robert, Claude; Chartier, Michel; Pirre, Michel

    2002-12-01

    Aerosol extinction coefficients have been derived in the 375-700-nm spectral domain from measurements in the stratosphere since 1992, at night, at mid- and high latitudes from 15 to 40 km, by two balloonborne spectrometers, Absorption par les Minoritaires Ozone et NOx (AMON) and Spectroscopie d'Absorption Lunaire pour l'Observation des Minoritaires Ozone et NOx (SALOMON). Log-normal size distributions associated with the Mie-computed extinction spectra that best fit the measurements permit calculation of integrated properties of the distributions. Although measured extinction spectra that correspond to background aerosols can be reproduced by the Mie scattering model by use of monomodal log-normal size distributions, each flight reveals some large discrepancies between measurement and theory at several altitudes. The agreement between measured and Mie-calculated extinction spectra is significantly improved by use of bimodal log-normal distributions. Nevertheless, neither monomodal nor bimodal distributions permit correct reproduction of some of the measured extinction shapes, especially for the 26 February 1997 AMON flight, which exhibited spectral behavior attributed to particles from a polar stratospheric cloud event.

  2. Adaptive Controller for Compact Fourier Transform Spectrometer with Space Applications

    Science.gov (United States)

    Keymeulen, D.; Yiu, P.; Berisford, D. F.; Hand, K. P.; Carlson, R. W.; Conroy, M.

    2014-12-01

    Here we present noise mitigation techniques developed as part of an adaptive controller for a very compact Compositional InfraRed Interferometric Spectrometer (CIRIS) implemented on a stand-alone field programmable gate array (FPGA) architecture with emphasis on space applications in high radiation environments such as Europa. CIRIS is a novel take on traditional Fourier Transform Spectrometers (FTS) and replaces linearly moving mirrors (characteristic of Michelson interferometers) with a constant-velocity rotating refractor to variably phase shift and alter the path length of incoming light. The design eschews a monochromatic reference laser typically used for sampling clock generation and instead utilizes constant time-sampling via internally generated clocks. This allows for a compact and robust device, making it ideal for spaceborne measurements in the near-IR to thermal-IR band (2-12 µm) on planetary exploration missions. The instrument's embedded microcontroller is implemented on a VIRTEX-5 FPGA and a PowerPC with the aim of sampling the instrument's detector and optical rotary encoder in order to construct interferograms. Subsequent onboard signal processing provides spectral immunity from the noise effects introduced by the compact design's removal of a reference laser and by the radiation encountered during space flight to destinations such as Europa. A variety of signal processing techniques including resampling, radiation peak removal, Fast Fourier Transform (FFT), spectral feature alignment, dispersion correction and calibration processes are applied to compose the sample spectrum in real-time with signal-to-noise-ratio (SNR) performance comparable to laser-based FTS designs in radiation-free environments. The instrument's FPGA controller is demonstrated with the FTS to characterize its noise mitigation techniques and highlight its suitability for implementation in space systems.

  3. Surface Plasmon Based Spectrometer

    Science.gov (United States)

    Wig, Andrew; Passian, Ali; Boudreaux, Philip; Ferrell, Tom

    2008-03-01

    A spectrometer that uses surface plasmon excitation in thin metal films to separate light into its component wavelengths is described. The use of surface plasmons as a dispersive medium sets this spectrometer apart from prism, grating, and interference based variants and allows for the miniaturization of this device. Theoretical and experimental results are presented for two different operation models. In the first case surface plasmon tunneling in the near field is used to provide transmission spectra of different broad band-pass, glass filters across the visible wavelength range with high stray-light rejection at low resolution as well as absorption spectra of chlorophyll extracted from a spinach leaf. The second model looks at the far field components of surface plasmon scattering.

  4. Galileo Ultraviolet Spectrometer experiment

    Science.gov (United States)

    Hord, C. W.; Mcclintock, W. E.; Stewart, A. I. F.; Barth, C. A.; Esposito, L. W.; Thomas, G. E.; Sandel, B. R.; Hunten, D. M.; Broadfoot, A. L.; Shemansky, D. E.

    1992-01-01

    The Galileo ultraviolet spectrometer experiment uses data obtained by the Ultraviolet Spectrometer (UVS) mounted on the pointed orbiter scan platform and from the Extreme Ultraviolet Spectrometer (EUVS) mounted on the spinning part of the orbiter with the field of view perpendicular to the spin axis. The UVS is a Ebert-Fastie design that covers the range 113-432 nm with a wavelength resolution of 0.7 nm below 190 and 1.3 nm at longer wavelengths. The UVS spatial resolution is 0.4 deg x 0.1 deg for illuminated disk observations and 1 deg x 0.1 deg for limb geometries. The EUVS is a Voyager design objective grating spectrometer, modified to cover the wavelength range from 54 to 128 nm with wavelength resolution 3.5 nm for extended sources and 1.5 nm for point sources and spatial resolution of 0.87 deg x 0.17 deg. The EUVS instrument will follow up on the many Voyager UVS discoveries, particularly the sulfur and oxygen ion emissions in the Io torus and molecular and atomic hydrogen auroral and airglow emissions from Jupiter. The UVS will obtain spectra of emission, absorption, and scattering features in the unexplored, by spacecraft, 170-432 nm wavelength region. The UVS and EUVS instruments will provide a powerful instrument complement to investigate volatile escape and surface composition of the Galilean satellites, the Io plasma torus, micro- and macro-properties of the Jupiter clouds, and the composition structure and evolution of the Jupiter upper atmosphere.

  5. Miniaturized Ion Mobility Spectrometer

    Science.gov (United States)

    Kaye, William J. (Inventor); Stimac, Robert M. (Inventor)

    2015-01-01

    By utilizing the combination of a unique electronic ion injection control circuit in conjunction with a particularly designed drift cell construction, the instantly disclosed ion mobility spectrometer achieves increased levels of sensitivity, while achieving significant reductions in size and weight. The instant IMS is of a much simpler and easy to manufacture design, rugged and hermetically sealed, capable of operation at high temperatures to at least 250.degree. C., and is uniquely sensitive, particularly to explosive chemicals.

  6. ALICE photon spectrometer crystals

    CERN Multimedia

    Maximilien Brice

    2006-01-01

    Members of the mechanical assembly team insert the last few crystals into the first module of ALICE's photon spectrometer. These crystals are made from lead-tungstate, a crystal as clear as glass but with nearly four times the density. When a high-energy particle passes through one of these crystals it will scintillate, emitting a flash of light allowing the energy of photons, electrons and positrons to be measured.

  7. Development of Neutron Spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Chang Hee; Lee, J. S.; Seong, B. S. (and others)

    2007-06-15

    Neutron spectrometers which are used in the basic researches such as physics, chemistry and materials science and applied in the industry were developed at the horizontal beam port of HANARO reactor. In addition, the development of core components for neutron scattering and the upgrade of existing facilities are also performed. The vertical neutron reflectometer was fabricated and installed at ST3 beam port. The performance test of the reflectometer was completed and the reflectometer was opened to users. The several core parts and options were added in the polarized neutron spectrometer. The horizontal neutron reflectometer from Brookhaven National Laboratory was moved to HANARO and installed, and the performance of the reflectometer was examined. The HIPD was developed and the performance test was completed. The base shielding for TAS was fabricated. The soller collimator, Cu mosaic monochromator, Si BPC monochromator and position sensitive detector were developed and applied in the neutron spectrometer as part of core component development activities. In addition, the sputtering machine for mirror device are fabricated and the neutron mirror is made using the sputtering machine. The FCD was upgraded and the performance of the FCD are improved over the factor of 10. The integration and upgrade of the neutron detection system were also performed.

  8. A Fourier transform spectrometer for visible and near ultra-violet measurements of atmospheric absorption

    Science.gov (United States)

    Parsons, C. L.; Gerlach, J. C.; Whitehurst, M.

    1982-01-01

    The development of a prototype, ground-based, Sun-pointed Michelson interferometric spectrometer is described. Its intended use is to measure the atmospheric amount of various gases which absorb in the near-infrared, visible, and near-ultraviolet portions of the electromagnetic spectrum. Preliminary spectra which contain the alpha, 0.8 micrometer, and rho sigma tau water vapor absorption bands in the near-infrared are presented to indicate the present capability of the system. Ultimately, the spectrometer can be used to explore the feasible applications of Fourier transform spectroscopy in the ultraviolet where grating spectrometers were used exclusively.

  9. Infrared retina

    Science.gov (United States)

    Krishna, Sanjay; Hayat, Majeed M.; Tyo, J. Scott; Jang, Woo-Yong

    2011-12-06

    Exemplary embodiments provide an infrared (IR) retinal system and method for making and using the IR retinal system. The IR retinal system can include adaptive sensor elements, whose properties including, e.g., spectral response, signal-to-noise ratio, polarization, or amplitude can be tailored at pixel level by changing the applied bias voltage across the detector. "Color" imagery can be obtained from the IR retinal system by using a single focal plane array. The IR sensor elements can be spectrally, spatially and temporally adaptive using quantum-confined transitions in nanoscale quantum dots. The IR sensor elements can be used as building blocks of an infrared retina, similar to cones of human retina, and can be designed to work in the long-wave infrared portion of the electromagnetic spectrum ranging from about 8 .mu.m to about 12 .mu.m as well as the mid-wave portion ranging from about 3 .mu.m to about 5 .mu.m.

  10. Mass spectrometers: instrumentation

    Science.gov (United States)

    Cooks, R. G.; Hoke, S. H., II; Morand, K. L.; Lammert, S. A.

    1992-09-01

    Developments in mass spectrometry instrumentation over the past three years are reviewed. The subject is characterized by an enormous diversity of designs, a high degree of competition between different laboratories working with either different or similar techniques and by extremely rapid progress in improving analytical performance. Instruments can be grouped into genealogical charts based on their physical and conceptual interrelationships. This is illustrated using mass analyzers of different types. The time course of development of particular instrumental concepts is illustrated in terms of the s-curves typical of cell growth. Examples are given of instruments which are at the exponential, linear and mature growth stages. The prime examples used are respectively: (i) hybrid instruments designed to study reactive collisions of ions with surfaces: (ii) the Paul ion trap; and (iii) the triple quadrupole mass spectrometer. In the area of ion/surface collisions, reactive collisions such as hydrogen radical abstraction from the surface by the impinging ion are studied. They are shown to depend upon the chemical nature of the surface through the use of experiments which utilize self-assembled monolayers as surfaces. The internal energy deposited during surface-induced dissociation upon collision with different surfaces in a BEEQ instrument is also discussed. Attention is also given to a second area of emerging instrumentation, namely technology which allows mass spectrometers to be used for on-line monitoring of fluid streams. A summary of recent improvements in the performance of the rapidly developing quadrupole ion trap instrument illustrates this stage of instrument development. Improvements in resolution and mass range and their application to the characterization of biomolecules are described. The interaction of theory with experiment is illustrated through the role of simulations of ion motion in the ion trap. It is emphasized that mature instruments play a

  11. Transient two-dimensional IR spectrometer for probing nanosecond temperature-jump kinetics.

    Science.gov (United States)

    Chung, Hoi Sung; Khalil, Munira; Smith, Adam W; Tokmakoff, Andrei

    2007-06-01

    We have developed a Fourier transform two-dimensional infrared (2D IR) spectrometer to probe chemical reactions and biophysical processes triggered by a nanosecond temperature jump (T jump). The technical challenges for such a spectrometer involve (1) synchronization of a nanosecond T-jump laser and femtosecond laser system, (2) overcoming the decreased signal-to-noise ratio from low repetition rate data acquisition, and (3) performing an interferometric measurement through a sample with a density and index of refraction that varies with time delay after the T jump. The first challenge was overcome by synchronizing the two lasers to a clock derived from the Ti:sapphire oscillator, leading to timing accuracy of 2 ns for delays up to 50 ms. The data collection time is reduced by using undersampling with the improved signal-to-noise ratio obtained from a balanced detection scheme with a dual stripe array detector. Transient dispersed vibrational echo and 2D IR spectroscopy are applied to N-methylacetamide and ubiquitin, as examples, and the spectral responses by a temperature elevation and by structural changes of the protein are compared. The synchronization of 2D IR spectroscopy with a nanosecond temperature jump without losing its sensitivity at a low repetition rate opens a new applicability of the nonlinear spectroscopy to probe a variety of molecular structure changes induced by a nanosecond perturbation.

  12. Study of the CH2I + O2 Reaction with a Step-Scan Fourier-Transform Infrared Absorption Spectrometer: Spectra of the Criegee Intermediate CH2OO and DIOXIRANE(?)

    Science.gov (United States)

    Huang, Yu-Hsuan; Lee, Yuan-Pern

    2014-06-01

    The Criegee intermediates are carbonyl oxides that play key roles in ozonolysis of unsaturated organic compounds. This mechanism was first proposed by Criegee in 1949, but the first direct observation of the simplest Criegee intermediate CH2OO in the gaseous phase has been reported only recently using photoionization mass spectrometry. Our group has reported the low-resolution IR spectra of CH2OO, produced from the reaction of CH2I + O2, with a second-generation step-scan Fourier-transfom IR absorption spectrometer. The spectral assignments were based on comparison of observed vibrational wavenumbers and rotational contours with theoretical predictions. Here, we report the IR absorption spectra of CH2OO at a resolution of 0.32 wn, showing partially rotationally-resolved structures. The origins of the νb{3}, νb{4}, νb{6}, and νb{8} vibrational modes of CH2OO are determined to be 1434.1, 1285.7, 909.2, and 847.3 wn, respectively. With the analysis of the vibration-rotational spectra, we provide a definitive assignment of these bands to CH2OO. The observed vibrational wavenumbers indicate a zwitterionic contribution to this singlet biradical showing a strengthened C-O bond and a weakened O-O bond. This zwitterionic character results to an extremely rapid self reaction via a cyclic dimer to form 2H2CO + O2 (1Δg). Another group of weak transient IR bands centered at 1231.5, 1213.3, and 899.8 wn are also observed. These bands might be contributed from dioxirane, which was postulated to be another important intermediate that might be isomerized from the Criegee intermediate in the reaction of O3 with 1-alkenes. O. Welz, J. D. Savee, D. L. Osborn, S. S.Vasu, C. J. Percival, D. E. Shallcross, and C. A. Taatjes, Science 335, 204 (2012). Y.-T. Su, Y.-H. Huang, H. A.Witek, and Y.-P. Lee, Science 340, 174 (2013).

  13. Ultra-compact MEMS FTIR spectrometer

    Science.gov (United States)

    Sabry, Yasser M.; Hassan, Khaled; Anwar, Momen; Alharon, Mohamed H.; Medhat, Mostafa; Adib, George A.; Dumont, Rich; Saadany, Bassam; Khalil, Diaa

    2017-05-01

    Portable and handheld spectrometers are being developed and commercialized in the late few years leveraging the rapidly-progressing technology and triggering new markets in the field of on-site spectroscopic analysis. Although handheld devices were commercialized for the near-infrared spectroscopy (NIRS), their size and cost stand as an obstacle against the deployment of the spectrometer as spectral sensing components needed for the smart phone industry and the IoT applications. In this work we report a chip-sized microelectromechanical system (MEMS)-based FTIR spectrometer. The core optical engine of the solution is built using a passive-alignment integration technique for a selfaligned MEMS chip; self-aligned microoptics and a single detector in a tiny package sized about 1 cm3. The MEMS chip is a monolithic, high-throughput scanning Michelson interferometer fabricated using deep reactive ion etching technology of silicon-on-insulator substrate. The micro-optical part is used for conditioning the input/output light to/from the MEMS and for further light direction to the detector. Thanks to the all-reflective design of the conditioning microoptics, the performance is free of chromatic aberration. Complemented by the excellent transmission properties of the silicon in the infrared region, the integrated solution allows very wide spectral range of operation. The reported sensor's spectral resolution is about 33 cm-1 and working in the range of 1270 nm to 2700 nm; upper limited by the extended InGaAs detector. The presented solution provides a low cost, low power, tiny size, wide wavelength range NIR spectral sensor that can be manufactured with extremely high volumes. All these features promise the compatibility of this technology with the forthcoming demand of smart portable and IoT devices.

  14. MASS SPECTROMETER LEAK

    Science.gov (United States)

    Shields, W.R.

    1960-10-18

    An improved valve is described for precisely regulating the flow of a sample fluid to be analyzed, such as in a mass spectrometer, where a gas sample is allowed to "leak" into an evacuated region at a very low, controlled rate. The flow regulating valve controls minute flow of gases by allowing the gas to diffuse between two mating surfaces. The structure of the valve is such as to prevent the corrosive feed gas from contacting the bellows which is employed in the operation of the valve, thus preventing deterioration of the bellows.

  15. Bulk and integrated acousto-optic spectrometers for radio astronomy

    Science.gov (United States)

    Chin, G.; Buhl, D.; Florez, J. M.

    1981-01-01

    The development of sensitive heterodyne receivers (front end) in the centimeter and millimeter range, and the construction of sensitive RF spectrometers (back end) enable the spectral lines of interstellar molecules to be detected and identified. A technique was developed which combines acoustic bending of a collimated coherent light beam by a Bragg cell followed by detection by a sensitive array of photodetectors (thus forming an RF acousto-optic spectrometer (AOS). An AOS has wide bandwidth, large number of channels, and high resolution, and is compact, lightweight, and energy efficient. The thrust of receiver development is towards high frequency heterodyne systems, particularly in the millimeter, submillimeter, far infrared, and 10 micron spectral ranges.

  16. The SPEDE electron spectrometer

    CERN Document Server

    O'Neill, George

    This thesis presents SPEDE (SPectrometer for Electron DEtection) and documents its construction, testing and performance during commissioning at Jyvaskyla, Finland, before deployment at the HIE-ISOLDE facility at CERN coupled with the MINIBALL array to perform in-beam electron-gamma spectroscopy using post-accelerated radioactive ion beams. Commissioning experiments took place in two two-day stints during spring 2015, coupled with several JUROGAMII gamma-detectors. This spectrometer will help aid in fully understanding exotic regions of the nuclear chart such as regions with a high degree of octupole deformation, and in those nuclei exhibiting shape coexistence. For the rst time, electron spectroscopy has been performed at the target position from states populated in accelerated nuclei via Coulomb excitation. The FWHM of SPEDE is approximately 7 keV at 320 keV, and Doppler correction was possible to improve Doppler broadened peaks. The results are intended to give the reader a full understanding of the dete...

  17. Prototype Neutron Energy Spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Mitchell, Sanjoy Mukhopadhyay, Richard Maurer, Ronald Wolff

    2010-06-16

    The project goals are: (1) Use three to five pressurized helium tubes with varying polyethylene moderators to build a neutron energy spectrometer that is most sensitive to the incident neutron energy of interest. Neutron energies that are of particular interest are those from the fission neutrons (typically around 1-2 MeV); (2) Neutron Source Identification - Use the neutron energy 'selectivity' property as a tool to discriminate against other competing processes by which neutrons are generated (viz. Cosmic ray induced neutron production [ship effect], [a, n] reactions); (3) Determine the efficiency as a function of neutron energy (response function) of each of the detectors, and thereby obtain the composite neutron energy spectrum from the detector count rates; and (4) Far-field data characterization and effectively discerning shielded fission source. Summary of the presentation is: (1) A light weight simple form factor compact neutron energy spectrometer ready to be used in maritime missions has been built; (2) Under laboratory conditions, individual Single Neutron Source Identification is possible within 30 minutes. (3) Sources belonging to the same type of origin viz., (a, n), fission, cosmic cluster in the same place in the 2-D plot shown; and (4) Isotopes belonging to the same source origin like Cm-Be, Am-Be (a, n) or Pu-239, U-235 (fission) do have some overlap in the 2-D plot.

  18. Simulation of the SAGE spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Cox, D.M.; Herzberg, R.D. [University of Liverpool, Department of Physics, Oliver Lodge Laboratory, Liverpool (United Kingdom); Konki, J.; Greenlees, P.T.; Pakarinen, J.; Papadakis, P.; Rahkila, P.; Sandzelius, M.; Sorri, J. [University of Jyvaeskylae, Department of Physics, Jyvaeskylae (Finland); Hauschild, K. [Universite Paris-Sud, CSNSM-IN2P3-CNRS, Orsay (France)

    2015-06-15

    The SAGE spectrometer combines a Ge-detector array with a Si detector to allow simultaneous detection of γ-rays and electrons. A comprehensive GEANT4 simulation package of the SAGE spectrometer has been developed with the ability to simulate the expected datasets based on user input files. The measured performance of the spectrometer is compared to the results obtained from the simulations. (orig.)

  19. Spatial heterodyne spectrometer for FLEX

    Science.gov (United States)

    Scott, Alan; Zheng, Sheng-Hai; Brown, Stephen; Bell, Andrew

    2007-10-01

    A spatial heterodyne spectrometer (SHS) has significant advantages for high spectral resolution imaging over narrow pre-selected bands compared to traditional solutions. Given comparable optical étendue at R~6500, a field-widened SHS will have a throughput-resolution product ~170 x larger than an air-spaced etalon spectrometer, and ~1000 x larger than a standard grating spectrometer. The monolithic glass Michelson design and lack of moving parts allows maximum stability of spectral calibration over the mission life. For these reasons, SHS offers considerable advantages for the core spectrometer instrument in the European Space Agency's (ESA) Fluorescence Explorer (FLEX) mission.

  20. Non-intrusive measurement of emission indices. A new approach to the evaluation of infrared spectra emitted by aircraft engine exhaust gases

    Energy Technology Data Exchange (ETDEWEB)

    Lindermeir, E.; Haschberger, P.; Tank, V. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Wessling (Germany). Inst. fuer Optoelektronik

    1997-12-31

    A non-intrusive method is used to determine the emission indices of a research aircraft`s engine in-flight. The principle is based on the Fourier Transform Infrared Spectrometer MIROR which was specifically designed and built for operation aboard aircrafts. This device measures the spectrum of the infrared radiation emitted by the hot exhaust gas under cruise conditions. From these spectra mixing ratios and emission indices can be derived. An extension to previously applied evaluation schemes is proposed: Whereas formerly the plume was assumed a homogeneous layer of gas, temperature and concentration profiles are now introduced to the evaluation procedure. (author) 5 refs.

  1. Ultra-Wideband Optical Modulation Spectrometer (OMS) Development

    Science.gov (United States)

    Gardner, Jonathan (Technical Monitor); Tolls, Volker

    2004-01-01

    The optical modulation spectrometer (OMS) is a novel, highly efficient, low mass backend for heterodyne receiver systems. Current and future heterodyne receiver systems operating at frequencies up to a few THz require broadband spectrometer backends to achieve spectral resolutions of R approximately 10(exp 5) to 10(exp 6) to carry out many important astronomical investigations. Among these are observations of broad emission and absorption lines from extra-galactic objects at high redshifts, spectral line surveys, and observations of planetary atmospheres. Many of these lines are pressure or velocity broadened with either large half-widths or line wings extending over several GHz. Current backend systems can cover the needed bandwidth only by combining the output of several spectrometers, each with typically up to 1 GHz bandwidth, or by combining several frequency-shifted spectra taken with a single spectrometer. An ultra-wideband optical modulation spectrometer with 10 - 40 GHz bandwidth will enable broadband ob- servations without the limitations and disadvantages of hybrid spectrometers. Spectrometers like the OMS will be important for both ground-based observatories and future space missions like the Single Aperture Far-Infrared Telescope (SAFIR) which might carry IR/submm array heterodyne receiver systems requiring a spectrometer for each array pixel. Small size, low mass and small power consumption are extremely important for space missions. This report summarizes the specifications developed for the OMS and lists already identified commercial parts. The report starts with a review of the principle of operation, then describes the most important components and their specifications which were derived from theory, and finishes with a conclusion and outlook.

  2. Evaluating Field Spectrometer Performance with Transmission Standards: Examples from the USGS Spectral Library and Research Databases

    Science.gov (United States)

    Hoefen, T. M.; Kokaly, R. F.; Swayze, G. A.; Livo, K. E.

    2015-12-01

    Collection of spectroscopic data has expanded with the development of field-portable spectrometers. The most commonly available spectrometers span one or several wavelength ranges: the visible (VIS) and near-infrared (NIR) region from approximately 400 to 1000 nm, and the shortwave infrared (SWIR) region from approximately 1000-2500 nm. Basic characteristics of spectrometer performance are the wavelength position and bandpass of each channel. Bandpass can vary across the wavelength coverage of an instrument, due to spectrometer design and detector materials. Spectrometer specifications can differ from one instrument to the next for a given model and between manufacturers. The USGS Spectroscopy Lab in Denver has developed a simple method to evaluate field spectrometer wavelength accuracy and bandpass values using transmission measurements of materials with intense, narrow absorption features, including Mylar* plastic, praseodymium-doped glass, and National Institute of Standards and Technology Standard Reference Material 2035. The evaluation procedure has been applied in laboratory and field settings for 19 years and used to detect deviations from cited manufacturer specifications. Tracking of USGS spectrometers with transmission standards has revealed several instances of wavelength shifts due to wear in spectrometer components. Since shifts in channel wavelengths and differences in bandpass between instruments can impact the use of field spectrometer data to calibrate and analyze imaging spectrometer data, field protocols to measure wavelength standards can limit data loss due to spectrometer degradation. In this paper, the evaluation procedure will be described and examples of observed wavelength shifts during a spectrometer field season will be presented. The impact of changing wavelength and bandpass characteristics on spectral measurements will be demonstrated and implications for spectral libraries will be discussed. *Any use of trade, firm, or product names

  3. Optical design of MWIR imaging spectrometer with a cold slit

    Science.gov (United States)

    Zhou, Shiyao; Wang, Yueming; Qian, Liqun; Yuan, Liyin; Wang, Jianyu

    2016-05-01

    MWIR imaging spectrometer is promising in detecting spectral signature of high temperature object such as jet steam, guided missile and explosive gas. This paper introduces an optical design of a MWIR imaging spectrometer with a cold slit sharply reducing the stray radiation from exterior environment and interior structure. The spectrometer is composed of a slit, a spherical prism as disperser, two concentric spheres and a correction lens. It has a real entrance pupil to match the objective and for setting the infrared cold shield near the slit and a real exit pupil to match the cold shield of the focal plane array (FPA). There are two cooled parts, one includes the aperture stop and slit, and the other is the exit pupil and the FPA with two specially positioned cooled shields. A detailed stray radiation analysis is represented which demonstrates the outstanding effect of this system in background radiation restraint.

  4. Assessing polarization effects for the Airborne imaging spectrometer APEX

    Directory of Open Access Journals (Sweden)

    U. Böttger

    2006-01-01

    Full Text Available In the scope of hyperspectral airborne imaging spectrometer (APEX design activities, the acceptable sensitivity of linear polarization of the spectrometer is analyzed by assessing the amount of polarization of reflected light in the atmosphere-surface system. A large number of calculations is performed for a wide variaty of viewing geometries to study the influences of aerosol models, natural surfaces and flight altitudes over the spectral range from the near-UV to the short-wave infrared (SWIR. Thereinafter the design of the imaging spectrometer is outlined accounting for these requirements and a method of partially correcting the instrument polarization sensitivity is briefly introduced. APEX design and post-processing capabilities will enable to reduce the influence of polarization sensitivity of at-sensor radiance and its higher-level products generated for most of the observation conditions.

  5. Compact Reconnaissance Imaging Spectrometer Observations of Water Vapor and Carbon Monoxide

    Science.gov (United States)

    Smith, Michael D.; Wolff, Michael J.; Clancy, R. Todd; Murchie, Scott L.

    2009-01-01

    The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) onboard the Mars Reconnaissance Orbiter (MRO) spacecraft began taking observations in September 2006 and has now collected more than a full Martian year of data. Retrievals performed using the near-infrared spectra obtained by CRISM are used to characterize the seasonal and spatial variation of the column abundance of water vapor and the column-averaged mixing ratio of carbon monoxide. CRISM retrievals show nominal behavior in water vapor during northern hemisphere spring and summer with maximum abundance reaching 50 precipitable micrometers. Water vapor abundance during the southern hemisphere spring and summer appears significantly reduced compared to observations by other instruments taken during previous years. The CRISM retrievals show the seasonally and globally averaged carbon monoxide mixing ratio to be 700 ppm, but with strong seasonal variations at high latitudes. The summertime near-polar carbon monoxide mixing ratio falls to 200 ppm in the south and 400 ppm in the north as carbon dioxide sublimates from the seasonal polar ice caps and dilutes noncondensable species including carbon monoxide. At low latitudes, the carbon monoxide mixing ratio varies in response to the mean seasonal cycle of surface pressure.

  6. Thermal Infrared Spectroscopy of Saturn and Titan from Cassini

    Science.gov (United States)

    Jennings, Donald E.; Brasunas, J. C.; Carlson, R. C.; Flasar, F. M.; Kunde, V. G.; Mamoutkine, A. A.; Nixon, A.; Pearl, J. C.; Romani, P. N.; Simon-Miller, A. A.; Bjoraker, G. L.

    2009-01-01

    The Cassini spacecraft completed its nominal mission at Saturn in 2008 and began its extended mission. Cassini carries the Composite Infrared Spectrometer (CIRS); a Fourier transform spectrometer that measures the composition, thermal structure and dynamics of the atmospheres of Saturn and Titan, and also the temperatures of other moons and the rings.

  7. A tunable diode laser absorption spectrometer for formaldehyde atmospheric measurements validated by simulation chamber instrumentation.

    Science.gov (United States)

    Catoire, V; Bernard, F; Mébarki, Y; Mellouki, A; Eyglunent, G; Daële, V; Robert, C

    2012-01-01

    A tunable diode laser absorption spectrometer (TDLAS) for formaldehyde atmospheric measurements has been set up and validated through comparison experiments with a Fourier transform infrared spectrometer (FT-IR) in a simulation chamber. Formaldehyde was generated in situ in the chamber from reaction of ethene with ozone. Three HCHO ro-vibrational line intensities (at 2909.71, 2912.09 and 2914.46 cm(-1)) possibly used by TDLAS were calibrated by FT-IR spectra simultaneously recorded in the 1600-3200 cm(-1) domain during ethene ozonolysis, enabling the on-line deduction of the varying concentration for HCHO in formation. The experimental line intensities values inferred confirmed the calculated ones from the updated HITRAN database. In addition, the feasibility of stratospheric in situ HCHO measurements using the 2912.09 cm(-1) line was demonstrated. The TDLAS performances were also assessed, leading to a 2sigma detection limit of 88 ppt in volume mixing ratio with a response time of 60 sec at 30 Torr and 294 K for 112 m optical path. As part of this work, the room-temperature rate constant of this reaction and the HCHO formation yield were found to be in excellent agreement with the compiled literature data.

  8. A tunable diode laser absorption spectrometer for formaldehyde atmospheric measurements validated by simulation chamber instrumentation

    Institute of Scientific and Technical Information of China (English)

    V. Catoire; F. Bernard; Y. MébarKi; A. Mellouki; G. Eyglunent; V. Da(e)le; C. Robert

    2012-01-01

    A tunable diode laser absorption spectrometer (TDLAS) for formaldehyde atmospheric measurements has been set up and validated through comparison experiments with a Fourier transform infrared spectrometer (FT-IR) in a simulation chamber.Formaldehyde was generated in situ in the chamber from reaction of ethene with ozone.Three HCHO ro-vibrational line intensities (at 2909.71,2912.09and 2914.46 cm-1) possibly used by TDLAS were calibrated by FT-IR spectra simultaneously recorded in the 1600-3200 cm-1 domain during ethene ozonolysis,enabling the on-line deduction of the varying concentration for HCHO in formation.The experimental line intensities values inferred confirmed the calculated ones from the updated HITRAN database.In addition,the feasibility of stratospheric in situ HCHO measurements using the 2912.09 cm-1 line was demonstrated.The TDLAS performances were also assessed,leading to a 2σ detection limit of 88 ppt in volume mixing ratio with a response time of 60 see at 30 Torr and 294 K for 112 m optical path.As part of this work,the room-temperature rate constant of this reaction and the HCHO formation yield were found to be in excellent agreement with the compiled literature data.

  9. The NOMAD Spectrometer Suite on ExoMars Trace Gas Orbiter

    Science.gov (United States)

    Carine Vandaele, Ann; Lopez-Moreno, Jose-Juan; Patel, Manish R.; Bellucci, Giancarlo; Neefs, Eddy; Thomas, Ian R.; Drummond, Rachel; Rodriguez-Gomez, Julio; Daerden, Frank

    2016-04-01

    NOMAD (Nadir and Occultation for MArs Discovery) is a suite of three high-resolution spectrometers on-board the ExoMars Trace Gas Orbiter. The instrument will be able to detect and map a wide variety of Martian gases in unprecedented detail. NOMAD's three spectrometers cover the UV-visible (UVIS channel - 200-650nm) and infrared ranges (SO and LNO channels - 2.2-4.3μm), operating in solar occultation, limb and nadir-viewing modes, generating a huge dataset of Martian atmospheric observations during the mission across a wide spectral range. NOMAD has the resolving power to identify many trace gases that exhibit absorption features within the spectral range of the three channels. The order-of-magnitude increase in spectral resolution over previous instruments will enable spatial and temporal mapping of several isotopologues of methane and water, providing important measurements of the Martian D/H and methane isotope ratios globally. Sensitivity studies have shown that, using expected SNR values, NOMAD should have the ability to measure methane concentrations NOMAD will also continue to monitor the major seasonal cycles on Mars, extending existing datasets made by successive space missions in the past decade.

  10. 便携式近红外仪检测牛奶中脂肪、蛋白质及干物质含量%Determination of Fat, Protein and DM in Raw Milk by Portable Short-Wave Near Infrared Spectrometer

    Institute of Scientific and Technical Information of China (English)

    李晓云; 王加华; 黄亚伟; 韩东海

    2011-01-01

    Near infrared diffuse reflectance spectroscopy calibrations of fat, protein and DM in raw milk were studied with partial least-squares (PLS) regression using portable short-wave near infrared spectrometer. The results indicated that good calibrations of fat and DM were found, the correlation coefficients were all 0.98, the RMSEC were 0.187 and 0.217, RMSEP were 0.187 and 0.296, the RPDs were 5.02 and 3.20 respectively; the calibration of protein needed to be improved but can be used for practice, the correlation coefficient was 0.95, RMSEC was 0.105, RMSEP was 0.120, and RPD was 2.60. Furthermore, the measuring accuracy was improved by analyzing the correction relation of fat and DM in raw milk. This study will probably provide a new on-site method for nondestructive and rapid measurement of milk.%采用便携式近红外光谱仪,结合偏最小二乘回归法,研究了牛奶脂肪、蛋白质和干物质含量的测定方法,建立了近红外漫反射定最分析模型.结果显示,脂肪、蛋白质和干物质模型相关系数(R2)分别为0.98,0.95,0.98,建模集标准残差(RMSEC)分别为0.187,0.105,0.217,验证集标准残差(RMSEP)分别为0.187,0.120,0.296,相对分析误差(RPD)分别为5.02,2.60,3.20.同时探讨了各成分间的相关性,发现脂肪与干物质间具有很好相关性(R2=0.921),因此可通过脂肪模型预测来计算干物质含量,提高了干物质的检测精度.研究表明,采用便携式近红外漫反射模式可为牛奶成分的现场检测提供一种无损、快速的新方法.

  11. Aerosol mobility size spectrometer

    Science.gov (United States)

    Wang, Jian; Kulkarni, Pramod

    2007-11-20

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  12. VEGAS: VErsatile GBT Astronomical Spectrometer

    Science.gov (United States)

    Bussa, Srikanth; VEGAS Development Team

    2012-01-01

    The National Science Foundation Advanced Technologies and Instrumentation (NSF-ATI) program is funding a new spectrometer backend for the Green Bank Telescope (GBT). This spectrometer is being built by the CICADA collaboration - collaboration between the National Radio Astronomy Observatory (NRAO) and the Center for Astronomy Signal Processing and Electronics Research (CASPER) at the University of California Berkeley.The backend is named as VErsatile GBT Astronomical Spectrometer (VEGAS) and will replace the capabilities of the existing spectrometers. This backend supports data processing from focal plane array systems. The spectrometer will be capable of processing up to 1.25 GHz bandwidth from 8 dual polarized beams or a bandwidth up to 10 GHz from a dual polarized beam.The spectrometer will be using 8-bit analog to digital converters (ADC), which gives a better dynamic range than existing GBT spectrometers. There will be 8 tunable digital sub-bands within the 1.25 GHz bandwidth, which will enhance the capability of simultaneous observation of multiple spectral transitions. The maximum spectral dump rate to disk will be about 0.5 msec. The vastly enhanced backend capabilities will support several science projects with the GBT. The projects include mapping temperature and density structure of molecular clouds; searches for organic molecules in the interstellar medium; determination of the fundamental constants of our evolving Universe; red-shifted spectral features from galaxies across cosmic time and survey for pulsars in the extreme gravitational environment of the Galactic Center.

  13. Spectrometers and Polyphase Filterbanks in Radio Astronomy

    CERN Document Server

    Price, Danny C

    2016-01-01

    This review gives an introduction to spectrometers and discusses their use within radio astronomy. While a variety of technologies are introduced, particular emphasis is given to digital systems. Three different types of digital spectrometers are discussed: autocorrelation spectrometers, Fourier transform spectrometers, and polyphase filterbank spectrometers. Given their growing ubiquity and significant advantages, polyphase filterbanks are detailed at length. The relative advantages and disadvantages of different spectrometer technologies are compared and contrasted, and implementation considerations are presented.

  14. Electro-Optical Imaging Fourier-Transform Spectrometer

    Science.gov (United States)

    Chao, Tien-Hsin; Zhou, Hanying

    2006-01-01

    An electro-optical (E-O) imaging Fourier-transform spectrometer (IFTS), now under development, is a prototype of improved imaging spectrometers to be used for hyperspectral imaging, especially in the infrared spectral region. Unlike both imaging and non-imaging traditional Fourier-transform spectrometers, the E-O IFTS does not contain any moving parts. Elimination of the moving parts and the associated actuator mechanisms and supporting structures would increase reliability while enabling reductions in size and mass, relative to traditional Fourier-transform spectrometers that offer equivalent capabilities. Elimination of moving parts would also eliminate the vibrations caused by the motions of those parts. Figure 1 schematically depicts a traditional Fourier-transform spectrometer, wherein a critical time delay is varied by translating one the mirrors of a Michelson interferometer. The time-dependent optical output is a periodic representation of the input spectrum. Data characterizing the input spectrum are generated through fast-Fourier-transform (FFT) post-processing of the output in conjunction with the varying time delay.

  15. Water Vapor in Titan’s Stratosphere from Cassini CIRS Far-infrared Spectra

    Science.gov (United States)

    Cottini, Valeria; Nixon, C. A.; Jennings, D. E.; Anderson, C. M.; Gorius, N.; Bjoraker, G. L.; Coustenis, A.; Teanby, N. A.; Achterberg, R. K.; Bézard, B.; de Kok, R.; Lellouch, E.; Irwin, P. G. J.; Flasar, F. M.; Bampasidis, G.

    2012-10-01

    We will report the measurement of water vapor in Titan’s stratosphere (Cottini et al. 2012), using the Cassini Composite Infrared Spectrometer (CIRS, Flasar et al. 2004). CIRS senses water emissions in the far infrared spectral region near 50 microns, which we have modeled using a radiative transfer code (NEMESIS, Irwin et al. 2008). From the analysis of nadir spectra we have derived a mixing ratio of 0.14 ± 0.05 ppb at an altitude of 97 km, which corresponds to an integrated (from 0 to 600 km) surface normalized column abundance of 3.7±1.3 × 1014 molecules/cm2. In the latitude range 80°S to 30°N we see no evidence for latitudinal variations in these abundances within the error bars. Using limb observations, we obtained mixing ratios of 0.13 ± 0.04 ppb at an altitude of 115 km and 0.45 ± 0.15 ppb at an altitude of 230 km, confirming that the water abundance has a positive vertical gradient as predicted by previous photochemical models. We have also fitted our data using scaling factors of 0.1-0.6 to these photochemical model profiles, indicating that the models over-predict the water abundance in Titan’s lower stratosphere. Valeria Cottini is supported by the NASA Postdoctoral Program. References Cottini V. et al., 2012. Detection of water vapor in Titan’s atmosphere from Cassini/CIRS infrared spectra. Icarus, 220, 2, 855-862 Flasar, F.M., and 44 colleagues, 2004. Exploring the Saturn system in the thermal infrared: The Composite Infrared Spectrometer. Space Sci. Rev., 115, 169-297 Irwin, P.G.J., et al., 2008. The NEMESIS planetary atmosphere radiative transfer and retrieval tool. J. Quant. Spectrosc. Radiat. Trans., 109, 1136-1150.

  16. Simulation of the peak efficiency for a stacked NaI(Tl) spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, H.; Murohka, H.; Anami, K.; Nohtomi, A.; Uozumi, Y.; Sakae, T.; Matoba, M. [Kyushu Univ., Fukuoka (Japan). Faculty of Engineering; Koori, N.; Maki, T.

    1996-07-01

    A stacked NaI(Tl) spectrometer has been developed to measure proton spectra in wide energy range. In the measurement of charged particles with intermediate energy, the detecting efficiency of the spectrometer decreases considerably due to nuclear reactions or out-scattering in the detector material. A Monte Carlo simulation code has been developed to estimate the peak efficiency (peak-to-total ratio) of the spectrometer. The calculated efficiency for intermediate energy is in good agreement with the experimental one. (author)

  17. Detection of marine methane emissions with AVIRIS band ratios

    Science.gov (United States)

    Bradley, Eliza S.; Leifer, Ira; Roberts, Dar A.; Dennison, Philip E.; Washburn, Libe

    2011-05-01

    The relative source contributions of methane (CH4) have high uncertainty, creating a need for local-scale characterization in concert with global satellite measurements. However, efforts towards methane plume imaging have yet to provide convincing results for concentrated sources. Although atmospheric CH4 mapping did not motivate the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) design, recent studies suggest its potential for studying concentrated CH4 sources such as the Coal Oil Point (COP) seep field (˜0.015 Tg CH4 yr-1) offshore Santa Barbara, California. In this study, we developed a band ratio approach on high glint COP AVIRIS data and demonstrate the first successful local-scale remote sensing mapping of natural atmospheric CH4 plumes. Plume origins closely matched surface and sonar-derived seepage distributions, with plume characteristics consistent with wind advection. Imaging spectrometer data may also be useful for high spatial-resolution characterization of concentrated, globally-significant CH4 emissions from offshore platforms and cattle feedlots.

  18. Novel Micro Fourier Transform Spectrometers

    Institute of Scientific and Technical Information of China (English)

    KONG Yan-mei; LIANG Jing-qiu; LIANG Zhong-zhu; WANG-Bo; ZHANG Jun

    2008-01-01

    The miniaturization of spectrometer opens a new application area with real-time and on-site measurements. The Fourier transform spectrometer(FTS) is much attractive considering its particular advantages among the approaches. This paper reviews the current status of micro FTS in worldwide and describes its developments; In addition, analyzed are the key problems in designing and fabricating FTS to be settled during the miniaturization. Finally, a novel model of micro FTS with no moving parts is proposed and analyzed, which may provide new concepts for the design of spectrometers.

  19. Adaptive Computed Tomography Imaging Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The present proposal describes the development of an adaptive Computed Tomography Imaging Spectrometer (CTIS), or "Snapshot" spectrometer which can "instantaneously"...

  20. PANDA: Cold three axes spectrometer

    Directory of Open Access Journals (Sweden)

    Astrid Schneidewind

    2015-08-01

    Full Text Available The cold three axes spectrometer PANDA, operated by JCNS, Forschungszentrum Jülich, offers high neutron flux over a large dynamic range keeping the instrumental background comparably low.

  1. Automated Nuclear Quadruple Resonance Spectrometer

    Directory of Open Access Journals (Sweden)

    IVANCHUK, M.

    2008-06-01

    Full Text Available Improvement of an autodyne Nuclear quadruple resonance spectrometer is offered. The change of frequency of oscillatory LC circuit of the spectrometer is carried out in two ways: by varicap and variable capacitor. A processor module for the capacitor and varicap control is developed. The unit allows to scan and measure the level and frequency of the NQR-signal. The unit is controlled by the personal computer.

  2. Automated Nuclear Quadruple Resonance Spectrometer

    OpenAIRE

    2008-01-01

    Improvement of an autodyne Nuclear quadruple resonance spectrometer is offered. The change of frequency of oscillatory LC circuit of the spectrometer is carried out in two ways: by varicap and variable capacitor. A processor module for the capacitor and varicap control is developed. The unit allows to scan and measure the level and frequency of the NQR-signal. The unit is controlled by the personal computer.

  3. Compact high-resolution micro-spectrometer on chip: spectral calibration and first spectrum

    Science.gov (United States)

    Diard, Thomas; de la Barrière, Florence; Ferrec, Yann; Guérineau, Nicolas; Rommeluère, Sylvain; Le Coarer, Etienne; Martin, Guillermo

    2016-05-01

    Compact and hand-held spectrometers may be very interesting for the measurement of spectral signatures of chemicals or objects. To achieve this goal, ONERA and IPAG have developed a new on chip Fourier Transform Spectrometer operating in the visible spectral range with a high spectral resolution (near 2 cm-1), named visible HR SPOC (visible High Resolution Spectrometer On Chip). It is directly inspired from the MICROSPOC infrared spectrometer, studied at ONERA in the past years. This spectrometer is made of a stair-step two-wave interferometer directly glued on a CMOS detector making it a very compact prototype. After calibrating the optical path difference, measurements of experimental spectra are presented.

  4. MEOS Microsatellite Earth Observation using Miniature Integrated-Optic IR Spectrometers

    Science.gov (United States)

    Kruzelecky, Roman

    future, the MEOS Miniature Earth Observing Satellite will innovatively combine remote atmospheric/land-cover measurements with ecosystem modelling in near real-time to obtain simultaneous variations in lower tropospheric GHG mixing ratios and the resulting responses of surface ecosystems. MEOS will provide lower tropospheric CO2 , CH4 , CO, N2 O, H2 O and aerosol mixing ratios over natural sources and sinks using two kinds of synergistic observations; a forward limb measurement and a follow-on nadir measurement over the same geographical tangent point. The measurements will be accomplished using separate limb and nadir suites of miniature lineimaging spectrometers and will be spatially coordinated such that the same air mass is observed in both views within a few minutes. The limb data will consist of 16-pixel vertical spectral line imaging to provide 2.5-km vertical resolution, while the corresponding nadir measurements will view sixteen 5 by 10 km2 ground pixels with a 160-km East-West swath width. The separate limb and nadir instrument suites each feature two complementary NIR miniature spectrometers that will operate in parallel, alternating the collected optical signal between the high-resolution Fabry-Perot guided-wave FP-IOSPEC spectrometer with simultaneous multiple microchannels at 0.03 FWHM with SNR>400 and the 1220 to 2450 nm broad-band spectrometer with 1.2 nm FWHM such that one undergoes the illuminated segment of the processing while the other spectrometer undergoes its dark signal processing. This spectral region provides several harmonic optical absorption bands associated with CO2 , CH4 , CO, H2 O and N2 O. The innovative data synergy of the coarse resolution broad-band spectra with the scanned spectral measurements of the trace-gas fine features at 0.03 nm FWHM in multiple microchannels will be used to improve the accuracy of the trace gas retrievals relative to current missions. In addition, the mission will retrieve cloud top pressures to better than

  5. EXPERIMENTAL STUDIES IN THE FOURIER TRANSFORM-IMAGING SPECTROMETERS IN THE VISIBLE AND NEAR-IR

    Directory of Open Access Journals (Sweden)

    N. K. Artiukhina

    2014-01-01

    Full Text Available The paper considers basic model parameters of a static imaging Fourier spectrometer for Earth remote sensing from space. Design of the imaging spectrometer model has been developed and images have been obtained in the paper. The images have made it possible to determine such parameters as ratio of signal/ noise, frequency/contrast characteristic and spectral coincidence of reconstructed images.

  6. AOTF near-IR spectrometers for study of Lunar and Martian surface composition

    Science.gov (United States)

    Ivanov, A.; Korablev, O.; Mantsevich, S.; Vyazovetskiy, N.; Fedorova, A.; Evdokimova, N.; Stepanov, A.; Titov, A.; Kalinnikov, Y.; Kuzmin, R.; Kiselev, A.; Bazilevsky, A.; Bondarenko, A.; Dokuchaev, I.; Moiseev, P.; Victorov, A.; Berezhnoy, A.; Skorov, Y.; Bisikalo, D.; Velikodsky, Y.

    2014-04-01

    The series of the AOTF near-IR spectrometers is developed in Moscow Space Research Institute for study of Lunar and Martian surface composition in the vicinity of a lander or a rover. Lunar Infrared Spectrometer (LIS) is an experiment onboard Luna-Glob (launch in 2017) and Luna- Resurs (launch in 2019) Russian surface missions. It's a pencil-beam spectrometer to be pointed by a robotic arm of the landing module. The instrument's field of view (FOV) of 1° is co-aligned with the FOV(45°) of a stereo TV camera. Infrared Spectrometer for ExoMars (ISEM) is an experiment onboard ExoMars (launch in 2018) ESARoscosmos rover. It's spectrometer based on LIS with required redesign for ExoMars mission. The ISEM instrument is mounted on the rover's mast coaligned with the FOV (5°) of High Resolution camera (HRC). Spectrometers and are intended for study of the surface composition in the vicinity of the lander and rover. The spectrometers will provide measurements of selected surface areas in the spectral range of 1.15-3.3 μm. The spectral selection is provided by acoustooptic tunable filter (AOTF), which scans the spectral range sequentially. Electrical command of the AOTF allows selecting the spectral sampling, and permits a random access if needed.

  7. Compact high-speed MWIR spectrometer applied to monitor CO2 exhaust dynamics from a turbojet engine

    Science.gov (United States)

    Linares-Herrero, R.; Vergara, G.; Gutiérrez Álvarez, R.; Fernández Montojo, C.; Gómez, L. J.; Villamayor, V.; Baldasano Ramírez, A.; Montojo, M. T.; Archilla, V.; Jiménez, A.; Mercader, D.; González, A.; Entero, A.

    2013-05-01

    Dfgfdg Due to international environmental regulations, aircraft turbojet manufacturers are required to analyze the gases exhausted during engine operation (CO, CO2, NOx, particles, unburned hydrocarbons (aka UHC), among others).Standard procedures, which involve sampling the gases from the exhaust plume and the analysis of the emissions, are usually complex and expensive, making a real need for techniques that allow a more frequent and reliable emissions measurements, and a desire to move from the traditional gas sampling-based methods to real time and non-intrusive gas exhaust analysis, usually spectroscopic. It is expected that the development of more precise and faster optical methods will provide better solutions in terms of performance/cost ratio. In this work the analysis of high-speed infrared emission spectroscopy measurements of plume exhaust are presented. The data was collected during the test trials of commercial engines carried out at Turbojet Testing Center-INTA. The results demonstrate the reliability of the technique for studying and monitoring the dynamics of the exhausted CO2 by the observation of the infrared emission of hot gases. A compact (no moving parts), high-speed, uncooled MWIR spectrometer was used for the data collection. This device is capable to register more than 5000 spectra per second in the infrared band ranging between 3.0 and 4.6 microns. Each spectrum is comprised by 128 spectral subbands with aband width of 60 nm. The spectrometer operated in a passive stand-off mode and the results from the measurements provided information of both the dynamics and the concentration of the CO2 during engine operation.

  8. Comparison between IASI and GOSAT retrievals in the thermal infrared

    Science.gov (United States)

    Payan, S.; Camy-peyret, C.; Bureau, J.; Shiomi, K.

    2012-04-01

    GOSAT (Greenhouse Gases Observing SATellite) is a satellite dedicated to the study of greenhouses gases. It carries an infrared Fourier transform spectrometer (The Thermal and Near Infrared Sensor for Carbon Observation Fourier-Transform Spectrometer or TANSO-FTS), which acquires spectra in 4 bands, located in the Near-Infrared (NIR), ShortWave Infrared (SWIR) and Thermal Infrared (TIR). An imager (CAI: Cloud and Aerosols imager) enables to gain information on clouds and aerosols, and this information is used to improve the quality of CO2 and CH4 retrievals. IASI (Infrared Atmospheric Sounding Interferometer) designed by CNES for Eumetsat is carried by the MetOp-A satellite. It is used for operational meteorology and is also interesting for greenhouse gases as well as for atmospheric chemistry and climate. We looked for close spatial and temporal coincidences between IASI and TANSO-FTS nadir spectra. Due to the respective orbits of MetOp-A and GOSAT, this is only achieved at high latitudes. We compared the surface temperature, CO2, CH4, N2O and O3 mixing ratios retrieved from TANSO-FTS and from IASI spectra. We used the [940;980] cm-1 window for CO2 (laser band), [1240;1320] cm-1 for CH4, [1140;1200] cm-1 for N2O, and [980;1100] cm-1 for O3. Since IASI is considered as a reference for radiometric calibrations, we compared the surface temperatures retrieved by GOSAT and IASI in these different windows to assess the GOSAT radiometric calibration. The GOSAT/IASI comparison is done on surface temperature rather than on raw radiances because the different instrumental noise and spectral resolution of these instruments make a direct comparison of the radiances more difficult. The use of different spectral windows enabled us to explore the spectral dependence of the TANSO-FTS radiometric calibration. Cloud-free and spatially homogenous fields of view (IFOVs) were selected using CAI images. Finally, we will show the potential to further improve the results using the

  9. An infrared study of Be stars based on ISO SWS01 spectra

    Institute of Scientific and Technical Information of China (English)

    Pin Zhang; Zai-Qi Fu

    2009-01-01

    The Infrared Space Observatory (ISO) Short-Wavelength Spectrometer (SWS) spectra of 10 Be stars are presented. It can be seen that the Be stars show a diversity in their ISO SWS01 spectral classifications by Kraemer et al., from naked stars, stars associated with dust, stars with warm dust shells, stars with cool dust shells to very red sources. In addition, the Brc/HI(14-6) line flux ratio derived for the sample stars is compared with that of P Cyg, and it is found that the line ratio of Be stars which were investigated show not only lower values as suggested by Waters et al., but also larger values. Therefore, the line ratio cannot he used to judge whether a star is a Be star or not.

  10. The impact of infrared arrays on 1-5 microns spectroscopy

    Science.gov (United States)

    Tokunaga, Alan

    1987-01-01

    The use of two-dimensional infrared arrays for astronomical imaging and spectroscopy is now occurring and immensely changing the field. In view of this 'revolution' in infrared astronomy, some of the implications for future infrared spectroscopy are discussed in this paper. A method is presented for comparing the infrared background to future spectrometers at 1-5 microns. Some of the current developments in infrared spectroscopy at Mauna Kea are discussed.

  11. Miniature Near-Infrared Fibre Optic Spectrometer for the Quantitative Detection of Protein and Fat in Milk Powder%微型近红外光纤光谱仪用于奶粉中蛋白质脂肪的定量检测研究

    Institute of Scientific and Technical Information of China (English)

    张中卫; 温志渝; 曾甜玲; 魏康林; 梁玉前

    2013-01-01

    提出利用微型近红外光谱仪、结合Y型光纤探头,在900~1 700 nm范围内对奶粉中蛋白质、脂肪含量进行快速、无损检测的漫反射光谱检测方法.基于Unscrambler 9.7化学计量学软件,选择合适的光谱波段,通过PLS算法分别建立了蛋白质、脂肪的校正模型,得到蛋白质、脂肪校正模型的决定系数R2分别为0.987和0.986,均方根误差RMSC分别为0.385和0.419.利用所建模型对预测样本数据集进行预测验证,得到蛋白质的标准差SEPProtein=0.768、脂肪的标准差SEPFat =1.109,表明所建模型具有较高的预测能力,已基本达到实用化要求.%The method based on miniature near-infrared spectrometer combined with Y fiber optic probe to detect the protein and fat in milk powder by diffuse reflectance spectroscopy in the wavelength range of 900~1700 nm was proposed.By selecting the appropriate spectral bands,the correction models of protein and fat were established with partial least squares algorithm using Unscrambler 9.7 Chemometrics software.The determination coefficients R2 of the correction modes are 0.987 and 0.986 for protein and fat respectively,and the root mean square errors RMSEC are 0.385 and 0.419 respectively.Using these correction models to predict the protein and fat contents with 30 sets of forecast sample data,the prediction standard deviation is SEPprotein=0.751 for protein,and is SEPFat =1.109 for fat.The results indicate that these correction models have prediction capability with unknown samples and meet the on line requirements.

  12. Application of handheld and portable spectrometers for screening acrylamide content in commercial potato chips.

    Science.gov (United States)

    Ayvaz, Huseyin; Rodriguez-Saona, Luis E

    2015-05-01

    The most common methods for acrylamide analysis in foods require the use of LC-MS/MS and GC-MS. Although these methods have great analytical performance, they need intensive sample preparation, highly specialised instrumentation, and are time consuming. In this study, portable and handheld infrared spectrometers were evaluated as rapid methods for screening acrylamide in potato chips and their performances were compared to those of benchtop infrared systems. The acrylamide content of 64 commercial potato chips (169-2453 μg/kg) was determined by LC-MS/MS. Spectral data were collected using mid-infrared (MIR) and near-infrared (NIR) spectrometers. Partial least squares regression (PLSR) calibration models were developed to predict acrylamide levels. Overall, good linear correlation was found between the predicted acrylamide levels and actual measured acrylamide concentrations by LC-MS/MS (rPred > 0.90 and SEP acrylamide analysis in potato chips. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. MONSTER: a TOF Spectrometer for β-delayed Neutron Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Martínez, T., E-mail: trino.martinez@ciemat.es [Centro de Investigaciones Energéticas, MedioAmbientales y Tecnológicas, CIEMAT, Madrid 28040 (Spain); Cano-Ott, D.; Castilla, J.; Garcia, A.R.; Marin, J.; Martinez, G.; Mendoza, E.; Santos, C.; Tera, F.J.; Villamarin, D. [Centro de Investigaciones Energéticas, MedioAmbientales y Tecnológicas, CIEMAT, Madrid 28040 (Spain); Agramunt, J.; Algora, A.; Domingo, C.; Jordan, M.D.; Rubio, B.; Taín, J.L. [Instituto de Física Corpuscular, CSIC-Universidad de Valencia (Spain); Bhattacharya, C.; Banerjee, K.; Bhattacharya, S.; Roy, P. [Variable Energy Cyclotron Centre (VECC), Kolkata (India); and others

    2014-06-15

    β-delayed neutron (DN) data, including emission probabilities, Pn, and energy spectrum, play an important role in our understanding of nuclear structure, nuclear astrophysics and nuclear technologies. A MOdular Neutron time-of-flight SpectromeTER (MONSTER) is being built for the measurement of the neutron energy spectra and branching ratios. The TOF spectrometer will consist of one hundred liquid scintillator cells covering a significant solid angle. The MONSTER design has been optimized by using Monte Carlo (MC) techniques. The response function of the MONSTER cell has been characterized with mono-energetic neutron beams and compared to dedicated MC simulations.

  14. MONSTER: a TOF Spectrometer for β-delayed Neutron Spectroscopy

    Science.gov (United States)

    Martínez, T.; Cano-Ott, D.; Castilla, J.; Garcia, A. R.; Marin, J.; Martinez, G.; Mendoza, E.; Santos, C.; Tera, F. J.; Villamarin, D.; Agramunt, J.; Algora, A.; Domingo, C.; Jordan, M. D.; Rubio, B.; Taín, J. L.; Bhattacharya, C.; Banerjee, K.; Bhattacharya, S.; Roy, P.; Meena, J. K.; Kundu, S.; Mukherjee, G.; Ghosh, T. K.; Rana, T. K.; Pandey, R.; Saxena, A.; Behera, B.; Penttilä, H.; Jokinen, A.; Rinta-Antila, S.; Guerrero, C.; Ovejero, M. C.

    2014-06-01

    β-delayed neutron (DN) data, including emission probabilities, Pn, and energy spectrum, play an important role in our understanding of nuclear structure, nuclear astrophysics and nuclear technologies. A MOdular Neutron time-of-flight SpectromeTER (MONSTER) is being built for the measurement of the neutron energy spectra and branching ratios. The TOF spectrometer will consist of one hundred liquid scintillator cells covering a significant solid angle. The MONSTER design has been optimized by using Monte Carlo (MC) techniques. The response function of the MONSTER cell has been characterized with mono-energetic neutron beams and compared to dedicated MC simulations.

  15. MONSTER: a TOF Spectrometer for beta-delayed Neutron Spetroscopy

    CERN Document Server

    Martinez, T; Castilla, J; Garcia, A R; Marin, J; Martinez, G; Mendoza, E; Santos, C; Tera, F; Jordan, M D; Rubio, B; Tain, J L; Bhattacharya, C; Banerjee, K; Bhattacharya, S; Roy, P; Meena, J K; Kundu, S; Mukherjee, G; Ghosh, T K; Rana, T K; Pandey, R; Saxena, A; Behera, B; Penttila, H; Jokinen, A; Rinta-Antila, S; Guerrero, C; Ovejero, M C; Villamarin, D; Agramunt, J; Algora, A

    2014-01-01

    Beta-delayed neutron (DN) data, including emission probabilities, P-n, and energy spectrum, play an important role in our understanding of nuclear structure, nuclear astrophysics and nuclear technologies. A MOdular Neutron time-of-flight SpectromeTER (MONSTER) is being built for the measurement of the neutron energy spectra and branching ratios. The TOF spectrometer will consist of one hundred liquid scintillator cells covering a significant solid angle. The MONSTER design has been optimized by using Monte Carlo (MC) techniques. The response function of the MONSTER cell has been characterized with mono-energetic neutron beams and compared to dedicated MC simulations.

  16. [Effect of spectrum distortion on modulation transfer function in imaging fiber-optic spectrometer].

    Science.gov (United States)

    Cheng, Xin; Wang, Jing; Zhang, Bao; Hong, Yong-Feng

    2011-10-01

    Imaging fiber bundles were introduced to dispersion imaging spectrometer and substituted for slit, connecting the telescope and spectrometer to yield the imaging fiber-optic spectrometer. It is a double sampling system, the misalignment between image of optical fiber and detector pixel has arisen because of the spectrum distortion of spectrometer, which affected the second sampling process, and the modulation transfer function (MTF) therefore degraded. Optical transfer function of sampling process was derived from line spread function. The effect of spectrum distortion on system MTF was analyzed, and a model evaluating the MTF of imaging fiber-optic spectrometer was developed. Compared to the computation model of MTF of slit imaging spectrometer, a MTF item of sampling by optical fiber and a MTF item of misalignment arising from spectrum distortion were added in this model. Employing this, the MTF of an airborne imaging fiber-optic spectrometer for visible near infrared band was evaluated. The approach ro deriving and developing the MTF model has a reference signification for the computation of MTF of double sampling system, which can direct the design of imaging fiber-optic spectrometer also.

  17. CMOS-compatible silicon nitride spectrometers for lab-on-a-chip spectral sensing

    Science.gov (United States)

    Ryckeboer, Eva; Nie, Xiaomin; Subramanian, Ananth Z.; Martens, Daan; Bienstman, Peter; Clemmen, Stephane; Severi, Simone; Jansen, Roelof; Roelkens, Gunther; Baets, Roel

    2016-05-01

    We report on miniaturized optical spectrometers integrated on a photonic integrated circuit (PIC) platform based on silicon nitride waveguides and fabricated in a CMOS-compatible approach. As compared to a silicon- on-insulator PIC-platform, the usage of silicon nitride allows for operation in the visible and near infrared. Furthermore, the moderately high refractive index contrast in silicon-nitride photonic wire waveguides provides a valuable compromise between compactness, optical loss and sensitivity to phase error. Three generic types of on-chip spectrometers are discussed: the arrayed waveguide grating (AWG) spectrometer, the echelle grating or planar concave grating (PCG) spectrometer and the stationary Fourier transform spectrometer (FTS) spectrometer. Both the design as well as experimental results are presented and discussed. For the FTS spectrometer a specific design is described in detail leading to an ultra-small (0.1 mm2) footprint device with a resolution of 1 nm and a spectral range of 100nm. Examples are given of the usage of these spectrometers in refractive index biosensing, absorption spectroscopy and Raman spectroscopy.

  18. Excited triplet state spectroscopy in the infrared

    Science.gov (United States)

    Baiardo, Joseph; Mukherjee, Ranajit; Vala, Martin

    1982-03-01

    A new method for the investigation of the infrared spectra of metastable excitedelectronic states is presented. With a Fourier Transform infrared spectrometer as the probe and a CW Xe lamp source as the pump, the infrared spectrum of the lowest triplet state of triphenylene isolated in a N 2 matrix at 15K has been examined. CH out-of-plane wagging modes are prominent and shifted from their ground state frequencies. It is expected that when fully developed this method will provide important information on excited state force constants and potential energy surfaces.

  19. Portable smartphone optical fibre spectrometer

    Science.gov (United States)

    Hossain, Md. Arafat; Canning, John; Cook, Kevin; Jamalipour, Abbas

    2015-09-01

    A low cost, optical fibre based spectrometer has been developed on a smartphone platform for field-portable spectral analysis. Light of visible wavelength is collected using a multimode optical fibre and diffracted by a low cost nanoimprinted diffraction grating. A measurement range over 300 nm span (λ = 400 to 700 nm) is obtained using the smartphone CMOS chip. The spectral resolution is Δλ ~ 0.42 nm/screen pixel. A customized Android application processed the spectra on the same platform and shares with other devices. The results compare well with commercially available spectrometer.

  20. JPL Fourier transform ultraviolet spectrometer

    Science.gov (United States)

    Cageao, R. P.; Friedl, R. R.; Sander, Stanley P.; Yung, Y. L.

    1994-01-01

    The Fourier Transform Ultraviolet Spectrometer (FTUVS) is a new high resolution interferometric spectrometer for multiple-species detection in the UV, visible and near-IR. As an OH sensor, measurements can be carried out by remote sensing (limb emission and column absorption), or in-situ sensing (long-path absorption or laser-induced fluorescence). As a high resolution detector in a high repetition rate (greater than 10 kHz) LIF system, OH fluorescence can be discriminated against non-resonant background emission and laser scatter, permitting (0, 0) excitation.

  1. A high-throughput neutron spectrometer

    Science.gov (United States)

    Stampfl, Anton; Noakes, Terry; Bartsch, Friedl; Bertinshaw, Joel; Veliscek-Carolan, Jessica; Nateghi, Ebrahim; Raeside, Tyler; Yethiraj, Mohana; Danilkin, Sergey; Kearley, Gordon

    2010-03-01

    A cross-disciplinary high-throughput neutron spectrometer is currently under construction at OPAL, ANSTO's open pool light-water research reactor. The spectrometer is based on the design of a Be-filter spectrometer (FANS) that is operating at the National Institute of Standards research reactor in the USA. The ANSTO filter-spectrometer will be switched in and out with another neutron spectrometer, the triple-axis spectrometer, Taipan. Thus two distinct types of neutron spectrometers will be accessible: one specialised to perform phonon dispersion analysis and the other, the filter-spectrometer, designed specifically to measure vibrational density of states. A summary of the design will be given along with a detailed ray-tracing analysis. Some preliminary results will be presented from the spectrometer.

  2. Waveguide-integrated photonic crystal spectrometer with camera readout

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Fan; Shiue, Ren-Jye; Li, Luozhou; Nie, Jing; Harris, Nicholas C.; Chen, Edward H.; Schröder, Tim; Englund, Dirk, E-mail: englund@mit.edu [Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology (MIT), Cambridge, Massachusetts 02139 (United States); Wan, Noel [Department of Physics, Columbia University, New York, New York 10027 (United States); Pervez, Nadia [Chromation Partners LLC, 18 Bridge Street Suite 2J, Brooklyn, New York 11201 (United States); Kymissis, Ioannis [Chromation Partners LLC, 18 Bridge Street Suite 2J, Brooklyn, New York 11201 (United States); Department of Electrical Engineering, Columbia University, New York, New York 10027 (United States)

    2014-08-04

    We demonstrate an infrared spectrometer based on waveguide-coupled nanocavity filters in a planar photonic crystal structure. The input light is coupled into the waveguide, from which spectral components are dropped into the cavities and radiated off-chip for detection on a commercial InGaAs camera. The spectrometer has a footprint of only 60 μm by 8 μm. The spectral resolution is about 1 nm in the operation bandwidth of 1522–1545 nm. By substituting the membrane material and structure parameters, this design can be easily extended into the visible regime and developed for a variety of highly efficient, miniature photonic applications.

  3. Infrared astronomy - Scientific/military thrusts and instrumentation; Proceedings of the Meeting, Washington, DC, April 21, 22, 1981

    Science.gov (United States)

    Boggess, N. W. (Editor); Stears, H. J.

    1981-01-01

    A series of papers on infrared astronomy is presented. Among the topics discussed are those concerning programs, such as NASA's planning, the Cosmic Background Explorer and a cryogenic infrared radiance instrument for the Space Shuttle. Articles on infrared astronomy technology include those on an infrared camera for 10-micron astronomy, bulk and integrated acousto-optic spectrometers for molecular astronomy with heterodyne spectrometers, and airborne measurements of infrared atmospheric radiance and sky noise. Several papers on infrared astronomy spectroscopy are included, such as infrared heterodyne spectroscopy and infrared lines from shocked galactic gases. Among the articles on infrared astronomy catalogues and operations are discussions of groundbased infrared measurements using the AMOS/MOTIF facility and the prediction of infrared celestial source counts.

  4. Miniature Tunable Laser Spectrometers for Quantifying Atmospheric Trace Gases, Water Resources, Earth Back-Contamination, and In Situ Resource Utilization

    Science.gov (United States)

    Webster, Chris; Blacksberg, Jordana; Flesch, Greg; Keymeulen, Didier; Christensen, Lance; Forouhar, Siamak

    2012-01-01

    The Tunable Laser Spectrometers (TLS) technique has seen wide applicability in gas measurement and analysis for atmospheric analysis, industrial, commercial and health monitoring and space applications. In Earth science using balloons and aircraft over 2 decades, several groups (JPL, NASA Langley & Ames, NOAA, Harvard U., etc) have demonstrated the technique for ozone hole studies, lab kinetics measurements, cloud physics and transport, climate change in the ice record. The recent availability of high-power (mW) room temperature lasers (TDL, IC, QC) has enabled miniaturized, high-sensitivity spectrometers for industry and space (1) Mars, Titan, Venus, Saturn, Moon (2) Commercial isotope ratio spectrometers are replacing bulkier, complex isotope ratio mass spectrometers.

  5. Comb-locked Lamb-dip spectrometer

    Science.gov (United States)

    Gatti, Davide; Gotti, Riccardo; Gambetta, Alessio; Belmonte, Michele; Galzerano, Gianluca; Laporta, Paolo; Marangoni, Marco

    2016-06-01

    Overcoming the Doppler broadening limit is a cornerstone of precision spectroscopy. Nevertheless, the achievement of a Doppler-free regime is severely hampered by the need of high field intensities to saturate absorption transitions and of a high signal-to-noise ratio to detect tiny Lamb-dip features. Here we present a novel comb-assisted spectrometer ensuring over a broad range from 1.5 to 1.63 μm intra-cavity field enhancement up to 1.5 kW/cm2, which is suitable for saturation of transitions with extremely weak electric dipole moments. Referencing to an optical frequency comb allows the spectrometer to operate with kHz-level frequency accuracy, while an extremely tight locking of the probe laser to the enhancement cavity enables a 10-11 cm-1 absorption sensitivity to be reached over 200 s in a purely dc direct-detection-mode at the cavity output. The particularly simple and robust detection and operating scheme, together with the wide tunability available, makes the system suitable to explore thousands of lines of several molecules never observed so far in a Doppler-free regime. As a demonstration, Lamb-dip spectroscopy is performed on the P(15) line of the 01120-00000 band of acetylene, featuring a line-strength below 10-23 cm/mol and an Einstein coefficient of 5 mHz, among the weakest ever observed.

  6. Infrared thermography

    CERN Document Server

    Meola, Carosena

    2012-01-01

    This e-book conveys information about basic IRT theory, infrared detectors, signal digitalization and applications of infrared thermography in many fields such as medicine, foodstuff conservation, fluid-dynamics, architecture, anthropology, condition monitoring, non destructive testing and evaluation of materials and structures.

  7. The smallsat TIR spectrometer MIBS

    NARCIS (Netherlands)

    Leijtens, J.A.P.; Court, A.J.; Lucas, J.W.

    2005-01-01

    In frame of the ESA Earthcare MSI study, TNO Science and Industry has developed a compact spectrometer which is optimized for operation in the 7 to 14 μm wavelength region. By optimizing the throughput of the system, and using the advantages of modern manufacturing technologies to the largest extend

  8. Inside the ETH spectrometer magnet

    CERN Multimedia

    1974-01-01

    The ETH spectrometer magnet being prepared for experiment S134, which uses a frozen spin polarized target to study the associated production of a kaon and a lambda by negative pions interacting with protons (CERN-ETH, Zurich-Helsinki-Imperial College, London-Southampton Collaboration). (See Photo Archive 7406316)

  9. Alpha proton x ray spectrometer

    Science.gov (United States)

    Rieder, Rudi; Waeke, H.; Economou, T.

    1994-01-01

    Mars Pathfinder will carry an alpha-proton x ray spectrometer (APX) for the determination of the elemental chemical composition of Martian rocks and soils. The instrument will measure the concentration of all major and some minor elements, including C, N, and O at levels above typically 1 percent.

  10. Inventory Control: Multiport Student Spectrometer.

    Science.gov (United States)

    Bishop, Carl B.

    1989-01-01

    Described is a spectrometer that can be used simultaneously by seven students to observe a single spectrum emitted by an element or compound in a single light tube against a calibrated screen. Included is a list of materials, directions for assembly, and procedures for use. (CW)

  11. An add-on system including a micro-reactor for an atr-ir spectrometer

    DEFF Research Database (Denmark)

    2014-01-01

    The invention relates to an add-on system for an attenuated total reflectance infrared (ATR-IR) spectrometer, the add-on system allowing for time-resolved in situ IR measurements of heterogeneous mixtures. The add-on device comprises a micro-reactor (300A) forming a sample cavity (305) when...

  12. Mapping of methane from Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY)

    Science.gov (United States)

    Tan, K. C.; Lim, H. S.; MatJafri, M. Z.

    2012-11-01

    Among all the greenhouse gases, methane is the most dynamic and abundant greenhouse gas in the atmosphere. The global concentrations of atmospheric methane has increased more than doubled since pre-industrial times, with a current globally-averaged mixing ratio of ~ 1750 ppbv. Due to its high growth rate, methane brings significant effects on climate and atmospheric chemistry. There has a significant gap for variables between anthropogenic and natural sources and sinks of methane. Satellite observation of methane has been identified that it can provide the precise and accurate data globally, which sensitive to the small regional biases. We present measurements from Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) included on the European environmental satellite ENVISAT, launched on 1st of March 2002. Main objective of this study is to examine the methane distribution over Peninsular Malaysia using SCIAMACHY level-3 data. They are derived from the near-infrared nadir observations of the SCIAMACHY at the University of Bremen through scientific WFM-DOAS retrieval algorithm version 2.0.2.Maps of time averaged (yearly, tri-monthly) methane was generated and analyzed over Peninsular Malaysia for the year 2003 using PCI Geomatica 10.3 image processing software. The maps show dry-air column averaged mixing ratios of methane (denoted XCH4). It was retrieved using the interpolation technique. The concentration changes within boundary layer at all altitude levels are equally sensitive through the SCIAMACHY near-infrared nadir observations. Hence, we can make observation of methane at surface source region. The results successfully identify the area with highest and lowest concentration of methane at Peninsular Malaysia using SCIAMACHY data. Therefore, the study is suitable to examine the distribution of methane at tropical region.

  13. Herschel Observations of Far-Infrared Cooling Lines in intermediate Redshift (Ultra)-luminous Infrared Galaxies

    CERN Document Server

    Rigopoulou, D; Magdis, G E; Thatte, N; Swinyard, B M; Farrah, D; Huang, J-S; Alonso-Herrero, A; Bock, J J; Clements, D; Cooray, A; Griffin, M J; Oliver, S; Pearson, C; Riechers, D; Scott, D; Smith, A; Vaccari, M; Valtchanov, I; Wang, L

    2014-01-01

    We report the first results from a spectroscopic survey of the [CII] 158um line from a sample of intermediate redshift (0.210^11.5 Lsun), using the SPIRE-Fourier Transform Spectrometer (FTS) on board the Herschel Space Observatory. This is the first survey of [CII] emission, an important tracer of star-formation, at a redshift range where the star-formation rate density of the Universe increases rapidly. We detect strong [CII] 158um line emission from over 80% of the sample. We find that the [CII] line is luminous, in the range (0.8-4)x10^(-3) of the far-infrared continuum luminosity of our sources, and appears to arise from photodissociation regions on the surface of molecular clouds. The L[CII]/LIR ratio in our intermediate redshift (U)LIRGs is on average ~10 times larger than that of local ULIRGs. Furthermore, we find that the L[CII]/LIR and L[CII]/LCO(1-0) ratios in our sample are similar to those of local normal galaxies and high-z star-forming galaxies. ULIRGs at z~0.5 show many similarities to the prop...

  14. Research on self-calibration error ratio method of infrared thermometer%红外线测温仪自校准误差比对方法的研究

    Institute of Scientific and Technical Information of China (English)

    肖艳红

    2012-01-01

    红外线测温仪由于长期用于生产一线进行现场测试,使用环境恶劣,以及日常维护保养不当,可能导致栓定有效期内的红外线测温仪不能准确测量甚至设备故障,导致测量失准,影响电网安全稳定运行。根据红外测温原理研究了运行中的红外线测温仪自校准方法,使用者可用简易自制设备随时对红外线测温仪进行定性测试分析,方法简单易行。确保红外线测温仪处于良好工作状态,准确测量,减少安全隐患。%Infrared thermometer is usually used for testing in the production field. Because of harsh environment as well as improper maintenance, the Infrared thermometer in the test within the validity period can not be accurately measured , even equipment failure and measurement inaccurate , the power grid security and stabilityoperation are also affected. The operation of the infrared thermometer calibration method based on its principle is researched. It can be qualitatively tested and analysed in simple homemade device at any time. It make sure that the infrared thermometer is in good working condition and accurately measuring. The security risks are reduced.

  15. C-12/C-13 Ratio in Ethane on Titan and Implications for Methane's Replenishment

    Science.gov (United States)

    Jennings, Donald E.; Romani, Paul N.; Bjoraker, Gordon L.; Sada, Pedro V.; Nixon, Conor A.; Lunsford, Allen W.; Boyle, Robert J.; Hesman, Brigette E.; McCabe, George H.

    2009-01-01

    The C-12/C-13 abundance ratio in ethane in the atmosphere of Titan has been measured at 822 cm(sup -1) from high spectral resolution ground-based observations. The value 89(8), coincides with the telluric standard and also agrees with the ratio seen in the outer planets. It is almost identical to the result for ethane on Titan found by the composite infrared spectrometer (CIRS) on Cassini. The C-12/C-13 ratio for ethane is higher than the ratio measured in atmospheric methane by Cassini/Huygens GCMS, 82.3(l), representing an enrichment of C-12 in the ethane that might be explained by a kinetic isotope effect of approximately 1.1 in the formation of methyl radicals. If methane is being continuously resupplied to balance photochemical destruction, then we expect the isotopic composition in the ethane product to equilibrate at close to the same C-12/C-13 ratio as that in the supply. The telluric value of the ratio in ethane then implies that the methane reservoir is primordial.

  16. Symmetrical Processing of Interferogram and Spectrum Reconstruction in Interference Spectrometer

    Institute of Scientific and Technical Information of China (English)

    楚建军; 赵达尊

    2003-01-01

    Because of its all-reflective layout based on the Fresnel double-mirror interference system, the newly developed Fourier transform imaging spectrometer has a very large spectral bandwidth ranged from a cut-off wavelength (related to the cut-off wave number σmax) to far infrared. According to the signal's symmetry and wide-band characteristics, a simple method that can efficiently weaken the low frequency noise in the reconstructed spectrum is presented. Also, according to the symmetry, the eigenvector method is applied to the reconstruction of the spectrum.

  17. Data processing assessment for the Lunar Geoscience Observer imaging spectrometer

    Science.gov (United States)

    Irigoyen, R. E.; Liaw, H. M.

    1988-01-01

    On the Lunar Geoscience Observer project, a Visible and Infrared Mapping Spectrometer instrument has been proposed. This instrument will have science data input rates in the hundreds of kilobits per second (kbps) and an average telemetry output data rate of 4 kbps. Techniques that can be used to reduce the throughput of the instrument are editing, summing and averaging, data compression, data preprocessing, pattern recognition and snapshot data taking. Due to instrument limitations in the buffer memory size and processing speeds, a careful selection of the available techniques must be made.

  18. A cryogenic scan mechanism for use in Fourier transform spectrometers

    Science.gov (United States)

    Hakun, Claef F.; Blumenstock, Kenneth A.

    1995-01-01

    This paper describes the requirements, design, assembly and testing of the linear Scan Mechanism (SM) of the Composite Infrared Spectrometer (CIRS) Instrument. The mechanism consists of an over constrained flexible structure, an innovative moving magnet actuator, passive eddy current dampers, a Differential Eddy Current (DEC) sensor, Optical Limit Sensors (OLS), and a launch lock. Although all the components of the mechanism are discussed, the flexible structure and the magnetic components are the primary focus. Several problems encountered and solutions implemented during the development of the scan mechanism are also described.

  19. The Cosmic Infrared Background Experiment

    CERN Document Server

    Bock, J; Cooray, A R; Kawada, M; Keating, B; Lange, A; Lee, D H; Matsumoto, T; Matsuura, S; Pak, S; Renbarger, T; Sullivan, I; Tsumura, K; Wada, T; Watabe, T; Bock, James; Battle, John; Cooray, Asantha; Kawada, Mitsunobu; Keating, Brian; Lange, Andrew; Lee, Dae-Hea; Matsumoto, Toshio; Matsuura, Shuji; Pak, Soojong; Renbarger, Tom; Sullivan, Ian; Tsumura, Kohji; Wada, Takehiko; Watabe, Toyoki

    2006-01-01

    We are developing a rocket-borne instrument (the Cosmic Infrared Background ExpeRiment, or CIBER) to search for signatures of primordial galaxy formation in the cosmic near-infrared extra-galactic background. CIBER consists of a wide-field two-color camera, a low-resolution absolute spectrometer, and a high-resolution narrow-band imaging spectrometer. The cameras will search for spatial fluctuations in the background on angular scales from 7 arcseconds to 2 degrees over a range of angular scales poorly covered by previous experiments. CIBER will determine if the fluctuations reported by the IRTS arise from first-light galaxies or have a local origin. In a short rocket flight CIBER has sensitivity to probe fluctuations 100 times fainter than IRTS/DIRBE. By jointly observing regions of the sky studied by Spitzer and ASTRO-F, CIBER will build a multi-color view of the near-infrared background, accurately assessing the contribution of local (z = 1-3) galaxies to the observed background fluctuations, allowing a de...

  20. Nonlinear infrared spectroscopy free from spectral selection

    Science.gov (United States)

    Paterova, Anna; Lung, Shaun; Kalashnikov, Dmitry A.; Krivitsky, Leonid A.

    2017-02-01

    Infrared (IR) spectroscopy is an indispensable tool for many practical applications including material analysis and sensing. Existing IR spectroscopy techniques face challenges related to the inferior performance and the high cost of IR-grade components. Here, we develop a new method, which allows studying properties of materials in the IR range using only visible light optics and detectors. It is based on the nonlinear interference of entangled photons, generated via Spontaneous Parametric Down Conversion (SPDC). In our interferometer, the phase of the signal photon in the visible range depends on the phase of an entangled IR photon. When the IR photon is traveling through the media, its properties can be found from observations of the visible photon. We directly acquire the SPDC signal with a visible range CCD camera and use a numerical algorithm to infer the absorption coefficient and the refraction index of the sample in the IR range. Our method does not require the use of a spectrometer and a slit, thus it allows achieving higher signal-to-noise ratio than the earlier developed method.

  1. Electron spectrometer for gas-phase spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Bozek, J.D.; Schlachter, A.S. [Ernest Orlando Lawrence Berkeley National Lab., CA (United States)

    1997-04-01

    An electron spectrometer for high-resolution spectroscopy of gaseous samples using synchrotron radiation has been designed and constructed. The spectrometer consists of a gas cell, cylindrical electrostatic lens, spherical-sector electron energy analyzer, position-sensitive detector and associated power supplies, electronics and vacuum pumps. Details of the spectrometer design are presented together with some representative spectra.

  2. Advanced Mass Spectrometers for Hydrogen Isotope Analyses

    Energy Technology Data Exchange (ETDEWEB)

    Chastagner, P.

    2001-08-01

    This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

  3. Acquisition of HPLC-Mass Spectrometer

    Science.gov (United States)

    2015-08-18

    31-Jan-2015 Approved for Public Release; Distribution Unlimited Final Report: Acquisition of HPLC -Mass Spectrometer The views, opinions and/or findings...published in peer-reviewed journals: Final Report: Acquisition of HPLC -Mass Spectrometer Report Title The acquisition of the mass spectrometer has been a

  4. New schemes of static mass spectrometers

    Energy Technology Data Exchange (ETDEWEB)

    Baisanov, O.A. [Military Institute of Air Defense Forces, Aktobe (Kazakhstan); Doskeyev, G.A. [Aktobe State University named after K. Zhubanov, Aktobe (Kazakhstan); Spivak-Lavrov, I.F., E-mail: baisanov@mail.ru [Aktobe State University named after K. Zhubanov, Aktobe (Kazakhstan)

    2011-07-21

    Different possibilities to increase the 'quality', or Q-quantity, of static mass spectrometers by expanding the ion beam before it enters the magnetic field are analyzed. The design of mass spectrometers using a cone-shaped achromatic prism is discussed. Different variants of achromatic mass spectrometers using electrostatic prisms and sector magnetic fields are also considered.

  5. The Cosmic Infrared Background Experiment

    Science.gov (United States)

    Bock, James; Battle, J.; Cooray, A.; Hristov, V.; Kawada, M.; Keating, B.; Lee, D.; Matsumoto, T.; Matsuura, S.; Nam, U.; Renbarger, T.; Sullivan, I.; Tsumura, K.; Wada, T.; Zemcov, M.

    2009-01-01

    We are developing the Cosmic Infrared Background ExpeRiment (CIBER) to search for signatures of first-light galaxy emission in the extragalactic background. The first generation of stars produce characteristic signatures in the near-infrared extragalactic background, including a redshifted Ly-cutoff feature and a characteristic fluctuation power spectrum, that may be detectable with a specialized instrument. CIBER consists of two wide-field cameras to measure the fluctuation power spectrum, and a low-resolution and a narrow-band spectrometer to measure the absolute background. The cameras will search for fluctuations on angular scales from 7 arcseconds to 2 degrees, where the first-light galaxy spatial power spectrum peaks. The cameras have the necessary combination of sensitivity, wide field of view, spatial resolution, and multiple bands to make a definitive measurement. CIBER will determine if the fluctuations reported by Spitzer arise from first-light galaxies. The cameras observe in a single wide field of view, eliminating systematic errors associated with mosaicing. Two bands are chosen to maximize the first-light signal contrast, at 1.6 um near the expected spectral maximum, and at 1.0 um; the combination is a powerful discriminant against fluctuations arising from local sources. We will observe regions of the sky surveyed by Spitzer and Akari. The low-resolution spectrometer will search for the redshifted Lyman cutoff feature in the 0.7 - 1.8 um spectral region. The narrow-band spectrometer will measure the absolute Zodiacal brightness using the scattered 854.2 nm Ca II Fraunhofer line. The spectrometers will test if reports of a diffuse extragalactic background in the 1 - 2 um band continues into the optical, or is caused by an under estimation of the Zodiacal foreground. We report performance of the assembled and tested instrument as we prepare for a first sounding rocket flight in early 2009. CIBER is funded by the NASA/APRA sub-orbital program.

  6. Early Science with SOFIA, the Stratospheric Observatory for Infrared Astronomy

    CERN Document Server

    Young, E T; Marcum, P M; Roellig, T L; De Buizer, J M; Herter, T L; Güsten, R; Dunham, E W; Temi, P; Andersson, B -G; Backman, D; Burgdorf, M; Caroff, L J; Casey, S C; Davidson, J A; Erickson, E F; Gehrz, R D; Harper, D A; Harvey, P M; Helton, L A; Horner, S D; Howard, C D; Klein, R; Krabbe, A; McLean, I S; Meyer, A W; Miles, J W; Morris, M R; Reach, W T; Rho, J; Richter, M J; Roeser, H -P; Sandell, G; Sankrit, R; Savage, M L; Smith, E C; Shuping, R Y; Vacca, W D; Vaillancourt, J E; Wolf, J; Zinnecker, H; 10.1088/2041-8205/749/2/L17

    2012-01-01

    The Stratospheric Observatory for Infrared Astronomy (SOFIA) is an airborne observatory consisting of a specially modified Boeing 747SP with a 2.7-m telescope, flying at altitudes as high as 13.7 km (45,000 ft). Designed to observe at wavelengths from 0.3 micron to 1.6 mm, SOFIA operates above 99.8 % of the water vapor that obscures much of the infrared and submillimeter. SOFIA has seven science instruments under development, including an occultation photometer, near-, mid-, and far-infrared cameras, infrared spectrometers, and heterodyne receivers. SOFIA, a joint project between NASA and the German Aerospace Center DLR, began initial science flights in 2010 December, and has conducted 30 science flights in the subsequent year. During this early science period three instruments have flown: the mid-infrared camera FORCAST, the heterodyne spectrometer GREAT, and the occultation photometer HIPO. This article provides an overview of the observatory and its early performance.

  7. Heavy ozone distribution in the stratosphere from far-infrared observations

    Science.gov (United States)

    Abbas, M. M.; Guo, J.; Carli, B.; Mencaraglia, F.; Carlotti, M.; Nolt, I. G.

    1987-01-01

    The distribution of isotopically heavy ozone in the stratosphere has been obtained from analysis of balloon-based high-resolution thermal emission spectra in the far infrared. The mixing ratio profiles of (O-16)(O-16)(O-18) and (O-16)(O-18)(O-16), retrieved from inversion of several limb sequences of a number of spectral lines in the 39-76/cm region, indicate enhancements over the expected values in the 25- to 37-km altitude range. The ratio of total heavy isotopic ozone (10-50)3 to normal (O-48)3 shows enhancements of about 45 percent at 37 km, decreasing to a minimum of about 13 percent at 29 km, and increasing to about 18 percent at 25 km. The results from this work are compared with Mauersberger's (1987) in situ mass spectrometer measurements.

  8. Holographic Fabry-Perot spectrometer.

    Science.gov (United States)

    Martínez-Matos, O; Rodrigo, José A; Vaveliuk, P; Calvo, M L

    2011-02-15

    We propose a spectrum analyzer based on the properties of a hologram recorded with the field transmitted by a Fabry-Perot etalon. The spectral response of this holographic Fabry-Perot spectrometer (HFPS) is analytically investigated in the paraxial approximation and compared with a conventional Fabry-Perot etalon of similar characteristics. We demonstrate that the resolving power is twice increased and the free spectral range (FSR) is reduced to one-half. The proposed spectrometer could improve the operational performance of the etalon because it can exhibit high efficiency and it would be insensible to environmental conditions such as temperature and vibrations. Our analysis also extends to another variant of the HFPS based on holographic multiplexing of the transmitted field of a Fabry-Perot etalon. This device increases the FSR, keeping the same HFPS performance.

  9. On-Chip Random Spectrometer

    CERN Document Server

    Redding, Brandon; Sarma, Raktim

    2013-01-01

    Light scattering in disordered media has been studied extensively due to its prevalence in natural and artificial systems [1]. In the field of photonics most of the research has focused on understanding and mitigating the effects of scattering, which are often detrimental. For certain applications, however, intentionally introducing disorder can actually improve the device performance, e.g., in photovoltaics optical scattering improves the efficiency of light harvesting [2-5]. Here, we utilize multiple scattering in a random photonic structure to build a compact on-chip spectrometer. The probe signal diffuses through a scattering medium generating wavelength-dependent speckle patterns which can be used to recover the input spectrum after calibration. Multiple scattering increases the optical pathlength by folding the paths in a confined geometry, enhancing the spectral decorrelation of speckle patterns and thus increasing the spectral resolution. By designing and fabricating the spectrometer on a silicon wafe...

  10. On-chip spiral spectrometer

    CERN Document Server

    Redding, Brandon; Bromberg, Yaron; Sarma, Raktim; Cao, Hui

    2016-01-01

    We designed an on-chip spectrometer based on an evanescently-coupled multimode spiral waveguide. Interference between the modes in the waveguide forms a wavelength-dependent speckle pattern which can be used as a fingerprint to identify the input wavelength after calibration. Evanescent coupling between neighboring arms of the spiral enhances the temporal spread of light propagating through the spiral, leading to a dramatic increase in the spectral resolution. Experimentally, we demonstrated that a 250 {\\mu}m radius spiral spectrometer provides a resolution of 0.01 nm at a wavelength of 1520 nm. Spectra containing 40 independent spectral channels can be recovered simultaneously and the operation bandwidth can be increased further when measuring sparse spectra.

  11. Exploiting a Transmission Grating Spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Ronald E. Bell

    2004-12-08

    The availability of compact transmission grating spectrometers now allows an attractive and economical alternative to the more familiar Czerny-Turner configuration for many high-temperature plasma applications. Higher throughput is obtained with short focal length refractive optics and stigmatic imaging. Many more spectra can be obtained with a single spectrometer since smaller, more densely packed optical input fibers can be used. Multiple input slits, along with a bandpass filter, can be used to maximize the number of spectra per detector, providing further economy. Curved slits can correct for the strong image curvature of the short focal length optics. Presented here are the governing grating equations for both standard and high-dispersion transmission gratings, defining dispersion, image curvature, and desired slit curvature, that can be used in the design of improved plasma diagnostics.

  12. On-chip plasmonic spectrometer.

    Science.gov (United States)

    Tsur, Yuval; Arie, Ady

    2016-08-01

    We report a numerical and experimental study of an on-chip optical spectrometer, utilizing propagating surface plasmon polaritons in the telecom spectral range. The device is based on two holographic gratings, one for coupling, and the other for decoupling free-space radiation with the surface plasmons. This 800 μm×100 μm on-chip spectrometer resolves 17 channels spectrally separated by 3.1 nm, spanning a freely tunable spectral window, and is based on standard lithography fabrication technology. We propose two potential applications for this new device; the first employs the holographic control over the amplitude and phase of the input spectrum, for intrinsically filtering unwanted frequencies, like pump radiation in Raman spectroscopy. The second prospect utilizes the unique plasmonic field enhancement at the metal-dielectric boundary for the spectral analysis of very small samples (e.g., Mie scatterers) placed between the two gratings.

  13. Infrared Imaging

    Science.gov (United States)

    Danchi, W.; Lawson, P.; Absil, O.; Akeson, R.; Bally, J.; Barry, R.; Beichman, C.; Belu, A.; Boyce, M.; Breckinridge, J.; Burrows, A.; Chen, C.; Cole, D.; Crisp, D.; Danner, R.; Deroo, P.; Coudé du Foresto, V.; Defrère, D.; Ebbets, D.; Falkowski, P.; Gappinger, R.; Haugabook, I.; Hanot, C.; Henning, T.; Hinz, P.; Hollis, J.; Hunyadi, S.; Hyland, D.; Johnston, K.; Kaltenegger, L.; Kasting, J.; Kenworthy, M.; Ksendzov, A.; Lane, B.; Laughlin, G.; Lay, O.; Liseau, R.; Lopez, B.; Millan-Gabet, R.; Martin, S.; Mawet, D.; Mennesson, B.; Monnier, J.; Murakami, N.; Noecker, C.; Nishikawa, J.; Pesesen, M.; Peters, R.; Quillen, A.; Ragland, S.; Rinehart, S.; Rottgering, H.; Scharf, D.; Serabyn, G.; Tamura, M.; Tehrani, M.; Traub, W.; Unwin, S.; Wilner, D.; Woilliez, J.; Woolf, N.; Zhao, M.

    2009-03-01

    A mid-infrared mission would enable the detection of biosignatures of Earth-like exoplanets around more than 150 nearby stars. The mid-infrared spectral region is attractive for characterizing exoplanets because contrast with the parent star brightness is more favorable than in the visible (10 million vs. 10 billion), and because mid-infrared light probes deep into a planet's troposphere. Furthermore, the mid-infrared offers access to several strong molecular features that are key signs of life, and also provides a measure of the effective temperature and size of a planet. Taken together, an infrared mission plus a visible one would provide a nearly full picture of a planet, including signs of life; with a measure of mass from an astrometric mission, we would have a virtually complete picture. A small infrared mission would have several telescopes that are rigidly connected, with a science return from the detection and characterization of super-Earth sized to larger planets near the HZ, plus a direct measure of the exozodi brightness in the HZ. In a large infrared mission, with formation-flying telescopes, planets from an Earth-twin and upwards in mass could be detected and characterized, as well as the exozodi. If proceeded by an astrometric mission, the detection phase could be skipped and the mission devoted to characterization, as in the visible case; lacking an astrometric mission, an infrared one could proceed alone, as was discussed for a visible coronograph, and with similar caveats. The technology needed for a large formation-flying mission is similar to that for a small connected-element one (e.g., cryogenics and detectors), with the addition of formationflying technology. The technology is now in hand to implement a probe-scale mission; starlight suppression has even been demonstrated to meet the requirements of a flagship mission. However, additional development of formation-flying technology is needed, particularly in-space testing of sensors and

  14. Design and performance analysis of a compact magnetic proton recoil spectrometer for DT neutrons

    Institute of Scientific and Technical Information of China (English)

    QI Jian-Min; ZHOU Lin; JIANG Shi-Lun

    2011-01-01

    A magnetic proton recoil (MPR) spectrometer is a novel instrument with superior performance, including high energy resolution, high count rate and good signal-to-noise ratio (SNR) for measurements of neutron spectra from inertial confinement fusion (ICF) experiments and high power Tokomaks. In this work, the design of a compact MPR spectrometer (cMPR) was evaluated for deuteron-tritium (DT) neutron spectroscopy. The characteristics of the spectrometer were analyzed using 2-D beam transport simulations, 3-D particle transport calculations and Monte-Carlo simulations. Based on the theoretical results, an instrument design that satisfies special experimental requirements is proposed. The energy resolution and efficiency of the spectrometer are also evaluated. The results indicate that the proposed cMPR spectrometer would achieve a detection efficiency and energy resolution of approximately 10 and 4%, respectively, for DT neutrons.

  15. Two RICH Detectors as Velocity Spectrometers in the CKM Experiment

    CERN Document Server

    Engelfried, J; Morelos, A; Torres, I

    2003-01-01

    We present the design of two velocity spectrometers, to be used in the recently approved CKM experiment. CKM's main goal is the measurement of the branching ratio of K+ -> pi+ nu nu with a precision of 10%, via decays in flight of the K+. The design of both RICH detectors is based on the SELEX Phototube RICH. We will discuss the design and the expected performance, based on studies with SELEX data and Monte Carlo Simulations.

  16. International Cooperation of the Cosmic Infrared Background Experiment

    Science.gov (United States)

    Lee, D.-H.; Nam, U.-W.; Lee, S.; Jin, H.; Yuk, I.-S.; Kim, K.-H.; Pak, S.

    2006-12-01

    A Korean team (Korea Astronomy and Space Science Institute, Korea Basic Science Institute, and Kyung Hee University) takes part in an international cooperation project called CIBER (Cosmic Infrared Background ExpeRiment), which has begun with Jet Propulsion Laboratory (JPL) in USA and Institute of Space and Astronautical Science (ISAS) in Japan. CIBER is a rocket-borne instrument, of which the scientific goal is to measure the cosmic near-infrared extra-galactic background to search for signatures of primordial galaxy formation. CIBER consists of a wide-field two-color camera, a low-resolution absolute spectrometer, and a high-resolution narrow-band imaging spectrometer. The Korean team is in charge of the ground support electronics and manufacturing of optical parts of the narrow-band spectrometer, which will provide excellent opportunities for science and technology to Korean infrared groups.

  17. Modification of fourier transform infrared spectrometer electrical system by CPLD and USB technique combining with embedded computer%基于CPLD和嵌入式微机技术的傅立叶变换红外光谱仪的电气系统

    Institute of Scientific and Technical Information of China (English)

    刘志国

    2012-01-01

    This text using embedded computer, combining with CPLD and USB technique have improved the spectrometer electrical system. Old CPU and chips were replaced by new models, a large number of logic circuits and counters were integrated in CPLD chips, So that the normal production of the spectrometer is guaranted, and the volume of the electric box is reduced, as well as the debugging steps are simplified. Old LAN communication pattern was replaced by USB. The results showed that all of the features of the new spectrometer are same as or better than the old one's. It is completely a new spectrometer with our technique property. The some cost performance of it is higher than inward instruments.%本文利用嵌入式微机(PC104),结合CPLD技术、USB技术对傅立叶变换红外光谱仪的电气系统进行了改造.实现了CPU及旧器件的更新换代,用CPLD芯片集成了大量逻辑电路和计数器,这样,既保证了仪器的正常生产、缩小了电路板,又简化了调试步骤,用USB的通讯方式取代了老的LAN的通讯方式.仪器的各项技术指标达到或超过了原光谱仪的水平.

  18. Quantitative Determination of Germinability of Puccinia striiformis f. sp. tritici Urediospores Using Near Infrared Spectroscopy Technology

    Directory of Open Access Journals (Sweden)

    Yaqiong Zhao

    2015-01-01

    Full Text Available Stripe rust caused by Puccinia striiformis f. sp. tritici (Pst is an important disease on wheat. In this study, quantitative determination of germinability of Pst urediospores was investigated by using near infrared reflectance spectroscopy (NIRS combined with quantitative partial least squares (QPLS and support vector regression (SVR. The near infrared spectra of the urediospore samples were acquired using FT-NIR MPA spectrometer and the germination rate of each sample was measured using traditional spore germination method. The best QPLS model was obtained with vector correction as the preprocessing method of the original spectra and 4000–12000 cm−1 as the modeling spectral region while the modeling ratio of the training set to the testing set was 4 : 1. The best SVR model was built when vector normalization was used as the preprocessing method, the modeling ratio was 5 : 1 and the modeling spectral region was 8000–11000 cm−1. The results showed that the effect of the best model built using QPLS or SVR was satisfactory. This indicated that quantitative determination of germinability of Pst urediospores using near infrared spectroscopy technology is feasible. A new method based on NIRS was provided for rapid, automatic, and nondestructive determination of germinability of Pst urediospores.

  19. A setup for simultaneous measurement of infrared spectra and light scattering signals: Watching amyloid fibrils grow from intact proteins

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yang; Maurer, Jürgen; Roth, Andreas; Vogel, Vitali; Winter, Ernst; Mäntele, Werner, E-mail: maentele@biophysik.uni-frankfurt.de [Institut für Biophysik, Goethe-Universität Frankfurt am Main, Max-von Laue-Straße 1, D-60438 Frankfurt am Main (Germany)

    2014-08-15

    A setup for the simultaneous measurement of mid-infrared spectra and static light scattering is described that can be used for the analysis of the formation of nanoscale and microscopic aggregates from smaller molecules to biopolymers. It can be easily integrated into sample chambers of infrared spectrometers or combined with laser beams from tunable infrared lasers. Here, its use for the analysis of the formation of amyloid fibrils from intact proteins is demonstrated. The formation of amyloid fibrils or plaques from proteins is a widespread and pathogenetic relevant process, and a number of diseases are caused and correlated with the deposition of amyloid fibrils in cells and tissues. The molecular mechanisms of these transformations, however, are still unclear. We report here the simultaneous measurement of infrared spectra and static light scattering for the analysis of fibril formation from egg-white lysozyme. The transformation of the native form into non-native forms rich in β-sheet structure is measured by analysis of the amide I spectral region in the infrared spectra, which is sensitive for local structures. At the same time, light scattering signals at forward direction as well as the forward/backward ratio, which are sensitive for the number of scattering centers and their approximate sizes, respectively, are collected for the analysis of fibril growth. Thermodynamic and kinetic parameters as well as mechanistic information are deduced from the combination of the two complementary techniques.

  20. Ion Mobility Spectrometer / Mass Spectrometer (IMS-MS).

    Energy Technology Data Exchange (ETDEWEB)

    Hunka, Deborah E; Austin, Daniel

    2005-10-01

    The use of Ion Mobility Spectrometry (IMS)in the Detection of Contraband Sandia researchers use ion mobility spectrometers for trace chemical detection and analysis in a variety of projects and applications. Products developed in recent years based on IMS-technology include explosives detection personnel portals, the Material Area Access (MAA) checkpoint of the future, an explosives detection vehicle portal, hand-held detection systems such as the Hound and Hound II (all 6400), micro-IMS sensors (1700), ordnance detection (2500), and Fourier Transform IMS technology (8700). The emphasis to date has been on explosives detection, but the detection of chemical agents has also been pursued (8100 and 6400).Combining Ion Mobility Spectrometry (IMS) with Mass Spectrometry (MS)The IMS-MS combination overcomes several limitations present in simple IMS systems. Ion mobility alone is insufficient to identify an unknown chemical agent. Collision cross section, upon which mobility is based, is not sufficiently unique or predictable a priori to be able to make a confident peak assignment unless the compounds present are already identified. Molecular mass, on the other hand, is much more readily interpreted and related to compounds. For a given compound, the molecular mass can be determined using a pocket calculator (or in one's head) while a reasonable value of the cross-section might require hours of computation time. Thus a mass spectrum provides chemical specificity and identity not accessible in the mobility spectrum alone. In addition, several advanced mass spectrometric methods, such as tandem MS, have been extensively developed for the purpose of molecular identification. With an appropriate mass spectrometer connected to an ion mobility spectrometer, these advanced identification methods become available, providing greater characterization capability.3 AcronymsIMSion mobility spectrometryMAAMaterial Access AreaMSmass spectrometryoaTOForthogonal acceleration time

  1. Ion mobility spectrometer / mass spectrometer (IMS-MS).

    Energy Technology Data Exchange (ETDEWEB)

    Hunka Deborah Elaine; Austin, Daniel E.

    2005-07-01

    The use of Ion Mobility Spectrometry (IMS) in the Detection of Contraband Sandia researchers use ion mobility spectrometers for trace chemical detection and analysis in a variety of projects and applications. Products developed in recent years based on IMS-technology include explosives detection personnel portals, the Material Area Access (MAA) checkpoint of the future, an explosives detection vehicle portal, hand-held detection systems such as the Hound and Hound II (all 6400), micro-IMS sensors (1700), ordnance detection (2500), and Fourier Transform IMS technology (8700). The emphasis to date has been on explosives detection, but the detection of chemical agents has also been pursued (8100 and 6400). Combining Ion Mobility Spectrometry (IMS) with Mass Spectrometry (MS) is described. The IMS-MS combination overcomes several limitations present in simple IMS systems. Ion mobility alone is insufficient to identify an unknown chemical agent. Collision cross section, upon which mobility is based, is not sufficiently unique or predictable a priori to be able to make a confident peak assignment unless the compounds present are already identified. Molecular mass, on the other hand, is much more readily interpreted and related to compounds. For a given compound, the molecular mass can be determined using a pocket calculator (or in one's head) while a reasonable value of the cross-section might require hours of computation time. Thus a mass spectrum provides chemical specificity and identity not accessible in the mobility spectrum alone. In addition, several advanced mass spectrometric methods, such as tandem MS, have been extensively developed for the purpose of molecular identification. With an appropriate mass spectrometer connected to an ion mobility spectrometer, these advanced identification methods become available, providing greater characterization capability.

  2. The mechanical and thermal setup of the GLORIA spectrometer

    Directory of Open Access Journals (Sweden)

    C. Piesch

    2014-11-01

    Full Text Available The novel airborne Gimballed Limb Observer for Radiance Imaging of the Atmosphere (GLORIA measures infrared emission of atmospheric trace constituents. GLORIA comprises a cooled imaging Fourier transform spectrometer which is operated in unpressurized aircraft compartments at ambient temperature. The whole spectrometer is pointed by the gimbal towards the atmospheric target. In order to reach the required sensitivity for atmospheric emission measurements the spectrometer optics needs to operate at a temperature below 220 K. A lightweight and compact design is mandatory due to limited space and high agility requirements. The cooled optical system needs to withstand high pressure and temperature gradients, humidity, and vibrations. A new cooling system based on carbon dioxide and liquid nitrogen combined with high-performance insulation has been developed to meet the mechanical, thermal, and logistical demands. The challenging mechanical and spatial requirements lead to the development of a novel rigid linear slide design in order to achieve the large optical path difference for high spectral resolution. This paper describes the mechanical and thermal setup of GLORIA and presents the performance results on two different research aircrafts.

  3. The mechanical and thermal setup of the GLORIA spectrometer

    Science.gov (United States)

    Piesch, C.; Sartorius, C.; Friedl-Vallon, F.; Gulde, T.; Heger, S.; Kretschmer, E.; Maucher, G.; Nordmeyer, H.; Barthel, J.; Ebersoldt, A.; Graf, F.; Hase, F.; Kleinert, A.; Neubert, T.; Schillings, H. J.

    2015-04-01

    The novel airborne Gimballed Limb Observer for Radiance Imaging of the Atmosphere (GLORIA) measures infrared emission of atmospheric trace constituents. GLORIA comprises a cooled imaging Fourier transform spectrometer, which is operated in unpressurized aircraft compartments at ambient temperature. The whole spectrometer is pointed by the gimbal towards the atmospheric target. In order to reach the required sensitivity for atmospheric emission measurements, the spectrometer optics needs to operate at a temperature below 220 K. A lightweight and compact design is mandatory due to limited space and high agility requirements. The cooled optical system needs to withstand high pressure and temperature gradients, humidity, and vibrations. A new cooling system based on carbon dioxide and liquid nitrogen combined with high-performance insulation has been developed to meet the mechanical, thermal, and logistical demands. The challenging mechanical and spatial requirements lead to the development of a novel rigid linear slide design in order to achieve the large optical path difference for high spectral resolution. This paper describes the mechanical and thermal setup of GLORIA and presents the performance results on two different research aircrafts.

  4. High-resolution wide-band Fast Fourier Transform spectrometers

    CERN Document Server

    Klein, Bernd; Krämer, Ingo; Bell, Andreas; Meyer, Klaus; Güsten, Rolf

    2012-01-01

    We describe the performance of our latest generations of sensitive wide-band high-resolution digital Fast Fourier Transform Spectrometer (FFTS). Their design, optimized for a wide range of radio astronomical applications, is presented. Developed for operation with the GREAT far infrared heterodyne spectrometer on-board SOFIA, the eXtended bandwidth FFTS (XFFTS) offers a high instantaneous bandwidth of 2.5 GHz with 88.5 kHz spectral resolution and has been in routine operation during SOFIA's Basic Science since July 2011. We discuss the advanced field programmable gate array (FPGA) signal processing pipeline, with an optimized multi-tap polyphase filter bank algorithm that provides a nearly loss-less time-to-frequency data conversion with significantly reduced frequency scallop and fast sidelobe fall-off. Our digital spectrometers have been proven to be extremely reliable and robust, even under the harsh environmental conditions of an airborne observatory, with Allan-variance stability times of several 1000 se...

  5. Plant species discrimination using emissive thermal infrared imaging spectroscopy

    Science.gov (United States)

    Rock, Gilles; Gerhards, Max; Schlerf, Martin; Hecker, Christoph; Udelhoven, Thomas

    2016-12-01

    Discrimination of plant species in the optical reflective domain is somewhat limited by the similarity of their reflectance spectra. Spectral characteristics in the visible to shortwave infrared (VSWIR) consist of combination bands and overtones of primary absorption bands, situated in the Thermal Infrared (TIR) region and therefore resulting in broad spectral features. TIR spectroscopy is assumed to have a large potential for providing complementary information to VSWIR spectroscopy. So far, in the TIR, plants were often considered featureless. Recently and following advances in sensor technology, plant species were discriminated based on specific emissivity signatures by Ullah et al. (2012) using directional-hemispherical reflectance (DHR) measurements in the laboratory. Here we examine if an accurate discrimination of plant species is equally possible using emissive thermal infrared imaging spectroscopy, an explicit spatial technique that is faster and more flexible than non-imaging measurements. Hyperspectral thermal infrared images were acquired in the 7.8⿿11.56 μm range at 40 nm spectral resolution (@10 μm) using a TIR imaging spectrometer (Telops HyperCam-LW) on seven plants each, of eight different species. The images were radiometrically calibrated and subjected to temperature and emissivity separation using a spectral smoothness approach. First, retrieved emissivity spectra were compared to laboratory reference spectra and then subjected to species discrimination using a random forest classifier. Second, classification results obtained with emissivity spectra were compared to those obtained with VSWIR reflectance spectra that had been acquired from the same leaf samples. In general, the mean emissivity spectra measured by the TIR imaging spectrometer showed very good agreement with the reference spectra (average Nash-Sutcliffe-Efficiency Index = 0.64). In species discrimination, the resulting accuracies for emissivity spectra are highly dependent on

  6. Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS): Imaging and Tracking Capability

    Science.gov (United States)

    Zhou, D. K.; Larar, A. M.; Liu, Xu; Reisse, R. A.; Smith, W. L.; Revercomb, H. E.; Bingham, G. E.; Zollinger, L. J.; Tansock, J. J.; Huppi, Ronald J.

    2007-01-01

    The geosynchronous-imaging Fourier transform spectrometer (GIFTS) engineering demonstration unit (EDU) is an imaging infrared spectrometer designed for atmospheric soundings. It measures the infrared spectrum in two spectral bands (14.6 to 8.8 microns, 6.0 to 4.4 microns) using two 128 128 detector arrays with a spectral resolution of 0.57/cm with a scan duration of approx. 11 seconds. From a geosynchronous orbit, the instrument will have the capability of taking successive measurements of such data to scan desired regions of the globe, from which atmospheric status, cloud parameters, wind field profiles, and other derived products can be retrieved. The GIFTS EDU provides a flexible and accurate testbed for the new challenges of the emerging hyperspectral era. The EDU ground-based measurement experiment, held in Logan, Utah during September 2006, demonstrated its extensive capabilities and potential for geosynchronous and other applications (e.g., Earth observing environmental measurements). This paper addresses the experiment objectives and overall performance of the sensor system with a focus on the GIFTS EDU imaging capability and proof of the GIFTS measurement concept.

  7. DISTRIBUTION OF CO{sub 2} IN SATURN'S ATMOSPHERE FROM CASSINI/CIRS INFRARED OBSERVATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Abbas, M. M.; LeClair, A. [NASA-Marshall Space Flight Center, Huntsville, AL 35812 (United States); Woodard, E.; Young, M.; Stanbro, M. [University of Alabama in Huntsville, Huntsville, AL 35899 (United States); Flasar, F. M.; Achterberg, R. K.; Bjoraker, G.; Brasunas, J.; Jennings, D. E. [NASA-Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Kunde, V. G., E-mail: Mian.M.Abbas@nasa.gov, E-mail: Andre.C.LeClair@nasa.gov, E-mail: eaw0009@uah.edu, E-mail: mcs0001@uah.edu, E-mail: youngmm@uah.edu, E-mail: f.m.flasar@nasa.gov, E-mail: virgil.g.kunde@gsfc.nasa.gov [University of Maryland, College Park, MD 20742 (United States); Collaboration: and the Cassini/CIRS team

    2013-10-20

    This paper focuses on the CO{sub 2} distribution in Saturn's atmosphere based on analysis of infrared spectral observations of Saturn made by the Composite Infrared Spectrometer aboard the Cassini spacecraft. The Cassini spacecraft was launched in 1997 October, inserted in Saturn's orbit in 2004 July, and has been successfully making infrared observations of Saturn, its rings, Titan, and other icy satellites during well-planned orbital tours. The infrared observations, made with a dual Fourier transform spectrometer in both nadir- and limb-viewing modes, cover spectral regions of 10-1400 cm{sup –1}, with the option of variable apodized spectral resolutions from 0.53 to 15 cm{sup –1}. An analysis of the observed spectra with well-developed radiative transfer models and spectral inversion techniques has the potential to provide knowledge of Saturn's thermal structure and composition with global distributions of a series of gases. In this paper, we present an analysis of a large observational data set for retrieval of Saturn's CO{sub 2} distribution utilizing spectral features of CO{sub 2} in the Q-branch of the ν{sub 2} band, and discuss its possible relationship to the influx of interstellar dust grains. With limited spectral regions available for analysis, due to low densities of CO{sub 2} and interference from other gases, the retrieved CO{sub 2} profile is obtained as a function of a model photochemical profile, with the retrieved values at atmospheric pressures in the region of ∼1-10 mbar levels. The retrieved CO{sub 2} profile is found to be in good agreement with the model profile based on Infrared Space Observatory measurements with mixing ratios of ∼4.9 × 10{sup –10} at atmospheric pressures of ∼1 mbar.

  8. Design of and data reduction from compact Thomson parabola spectrometers

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, J. T.; Willis, C.; Freeman, R. R.; Van Woerkom, L. [Physics Department, Ohio State University, Columbus, Ohio 43210 (United States)

    2011-03-15

    Thomson parabola spectrometers are used to characterize MeV ion beams produced in high intensity laser interactions. These spectrometers disperse multiple ion species according to their charge to mass ratio through the use of parallel electric and magnetic fields. Analytical solutions for ion deflection in electric and magnetic fields have been used to extract ion spectra with the assumption that fringing effects are negligible. Experimental space restrictions and dynamic range requirements necessitate designs that stress the analytical assumptions. Depending on design parameters, the error in the analytical assumption can be comparable to the energy resolution. Estimates are provided to approximate the error on the total ion deflection. A method for modeling ion trajectories including fringing effects is presented using software freely available or in common use. The magnetostatic fields are modeled in 3D, including material properties of nearby magnetic materials using RADIA. Electrostatic fields are modeled in 2D for a spectrometer implementing angled plates using the partial differential equation toolbox in MATLAB. Using these models to calculate the ion trajectory allows for analysis of a Thomson parabola spectrometer with an arbitrary field configuration.

  9. Design of and data reduction from compact Thomson parabola spectrometers.

    Science.gov (United States)

    Morrison, J T; Willis, C; Freeman, R R; Van Woerkom, L

    2011-03-01

    Thomson parabola spectrometers are used to characterize MeV ion beams produced in high intensity laser interactions. These spectrometers disperse multiple ion species according to their charge to mass ratio through the use of parallel electric and magnetic fields. Analytical solutions for ion deflection in electric and magnetic fields have been used to extract ion spectra with the assumption that fringing effects are negligible. Experimental space restrictions and dynamic range requirements necessitate designs that stress the analytical assumptions. Depending on design parameters, the error in the analytical assumption can be comparable to the energy resolution. Estimates are provided to approximate the error on the total ion deflection. A method for modeling ion trajectories including fringing effects is presented using software freely available or in common use. The magnetostatic fields are modeled in 3D, including material properties of nearby magnetic materials using RADIA. Electrostatic fields are modeled in 2D for a spectrometer implementing angled plates using the partial differential equation toolbox in MATLAB(®). Using these models to calculate the ion trajectory allows for analysis of a Thomson parabola spectrometer with an arbitrary field configuration.

  10. NEWS: the near-infrared Echelle for wideband spectroscopy

    Science.gov (United States)

    Veyette, Mark J.; Muirhead, Philip S.; Hall, Zachary J.; Taylor, Brian; Ye, Jimmy

    2016-08-01

    We present an updated optical and mechanical design of NEWS: the Near-infrared Echelle for Wide-band Spectroscopy (formerly called HiJaK: the High-resolution J, H and K spectrometer), a compact, high-resolution, near-infrared spectrometer for 5-meter class telescopes. NEWS provides a spectral resolution of 60,000 and covers the full 0.8-2.5 μm range in 5 modes. We adopt a compact, lightweight, monolithic design and have developed NEWS to be mounted to the instrument cube at the Cassegrain focus of the new 4.3-meter Discovery Channel Telescope.

  11. NEWS: the near-infrared Echelle for wideband spectroscopy

    CERN Document Server

    Veyette, Mark; Hall, Zachary; Taylor, Brian; Ye, Jimmy

    2016-01-01

    We present an updated optical and mechanical design of NEWS: the Near-infrared Echelle for Wide-band Spectroscopy (formerly called HiJaK: the High-resolution J, H and K spectrometer), a compact, high-resolution, near-infrared spectrometer for 5-meter class telescopes. NEWS provides a spectral resolution of 60,000 and covers the full 0.8-2.5 micron range in 5 modes. We adopt a compact, lightweight, monolithic design and developed NEWS to be mounted to the instrument cube at the Cassegrain focus of the the new 4.3-meter Discovery Channel Telescope.

  12. Low-Resolution Near-infrared Stellar Spectra Observed by the Cosmic Infrared Background Experiment (CIBER)

    Science.gov (United States)

    Kim, Min Gyu; Lee, Hyung Mok; Arai, Toshiaki; Bock, James; Cooray, Asantha; Jeong, Woong-Seob; Kim, Seong Jin; Korngut, Phillip; Lanz, Alicia; Lee, Dae Hee; Lee, Myung Gyoon; Matsumoto, Toshio; Matsuura, Shuji; Nam, Uk Won; Onishi, Yosuke; Shirahata, Mai; Smidt, Joseph; Tsumura, Kohji; Yamamura, Issei; Zemcov, Michael

    2017-02-01

    We present near-infrared (0.8–1.8 μm) spectra of 105 bright ({m}J < 10) stars observed with the low-resolution spectrometer on the rocket-borne Cosmic Infrared Background Experiment. As our observations are performed above the Earth's atmosphere, our spectra are free from telluric contamination, which makes them a unique resource for near-infrared spectral calibration. Two-Micron All-Sky Survey photometry information is used to identify cross-matched stars after reduction and extraction of the spectra. We identify the spectral types of the observed stars by comparing them with spectral templates from the Infrared Telescope Facility library. All the observed spectra are consistent with late F to M stellar spectral types, and we identify various infrared absorption lines.

  13. The Pickup Ion Composition Spectrometer

    Science.gov (United States)

    Gilbert, Jason A.; Zurbuchen, Thomas H.; Battel, Steven

    2016-06-01

    Observations of newly ionized atoms that are picked up by the magnetic field in the expanding solar wind contain crucial information about the gas or dust compositions of their origins. The pickup ions (PUIs) are collected by plasma mass spectrometers and analyzed for their density, composition, and velocity distribution. In addition to measurements of PUIs from planetary sources, in situ measurements of interstellar gas have been made possible by spectrometers capable of differentiating between heavy ions of solar and interstellar origin. While important research has been done on these often singly charged ions, the instruments that have detected many of them were designed for the energy range and ionic charge states of the solar wind and energized particle populations, and not for pickup ions. An instrument optimized for the complete energy and time-of-flight characterization of pickup ions will unlock a wealth of data on these hitherto unobserved or unresolved PUI species. The Pickup Ion Composition Spectrometer (PICSpec) is one such instrument and can enable the next generation of pickup ion and isotopic mass composition measurements. By combining a large-gap time-of-flight-energy sensor with a -100 kV high-voltage power supply for ion acceleration, PUIs will not only be above the detection threshold of traditional solid-state energy detectors but also be resolved sufficiently in time of flight that isotopic composition can be determined. This technology will lead to a new generation of space composition instruments, optimized for measurements of both heliospheric and planetary pickup ions.

  14. Development of high resolution arrayed waveguide grating spectrometers for astronomical applications: first results

    CERN Document Server

    Gatkine, Pradip; Hu, Yiwen; Zhu, Tiecheng; Meng, Yang; Bland-Hawthorn, Joss; Dagenais, Mario

    2016-01-01

    Astrophotonics is the next-generation approach that provides the means to miniaturize near-infrared (NIR) spectrometers for upcoming large telescopes and make them more robust and inexpensive. The target requirements for our spectrograph are: a resolving power of about 3000, wide spectral range (J and H bands), free spectral range of about 30 nm, high on-chip throughput of about 80% (-1dB) and low crosstalk (high contrast ratio) between adjacent on-chip wavelength channels of less than 1% (-20dB). A promising photonic technology to achieve these requirements is Arrayed Waveguide Gratings (AWGs). We have developed our first generation of AWG devices using a silica-on-silicon substrate with a very thin layer of silicon-nitride in the core of our waveguides. The waveguide bending losses are minimized by optimizing the geometry of the waveguides. Our first generation of AWG devices are designed for H band and have a resolving power of around 1500 and free spectral range of about 10 nm around a central wavelength ...

  15. An off Axis Cavity Enhanced Absorption Spectrometer and a Rapid Scan Spectrometer with a Room-Temperature External Cavity Quantum Cascade Laser

    Science.gov (United States)

    Liu, Xunchen; Kang, Cheolhwa; Xu, Yunjie

    2009-06-01

    Quantum cascade laser (QCL) is a new type of mid-infrared tunable diode lasers with superior output power and mode quality. Recent developments, such as room temperature operation, wide frequency tunability, and narrow line width, make QCLs an ideal light source for high resolution spectroscopy. Two slit jet infrared spectrometers, namely an off-axis cavity enhanced absorption (CEA) spectrometer and a rapid scan spectrometer with an astigmatic multi-pass cell assembly, have been coupled with a newly purchased room temperature tunable mod-hop-free QCL with a frequency coverage from 1592 cm^{-1} to 1698 cm^{-1} and a scan rate of 0.1 cm^{-1}/ms. Our aim is to utilize these two sensitive spectrometers, that are equipped with a molecular jet expansion, to investigate the chiral molecules-(water)_n clusters. To demonstrate the resolution and sensitivity achieved, the rovibrational transitions of the static N_2O gas and the bending rovibrational transitions of the Ar-water complex, a test system, at 1634 cm^{-1} have been measured. D. Hofstetter and J. Faist in High performance quantum cascade lasers and their applications, Vol.89 Springer-Verlag Berlin & Heidelberg, 2003, pp. 61-98. Y. Xu, X. Liu, Z. Su, R. M. Kulkarni, W. S. Tam, C. Kang, I. Leonov and L. D'Agostino, Proc. Spie, 2009, 722208 (1-11). M. J. Weida and D. J. Nesbitt, J. Chem. Phys. 1997, 106, 3078-3089.

  16. The Alpha Magnetic Spectrometer (AMS)

    Energy Technology Data Exchange (ETDEWEB)

    Alcaraz, J.; Alpat, B.; Ambrosi, G.; Anderhub, H.; Ao, L.; Arefiev, A.; Azzarello, P.; Babucci, E.; Baldini, L.; Basile, M.; Barancourt, D.; Barao, F.; Barbier, G.; Barreira, G.; Battiston, R.; Becker, R.; Becker, U.; Bellagamba, L.; Bene, P.; Berdugo, J.; Berges, P.; Bertucci, B.; Biland, A.; Bizzaglia, S.; Blasko, S.; Boella, G.; Boschini, M.; Bourquin, M.; Brocco, L.; Bruni, G.; Buenerd, M.; Burger, J.D.; Burger, W.J.; Cai, X.D.; Camps, C.; Cannarsa, P.; Capell, M.; Casadei, D.; Casaus, J.; Castellini, G.; Cecchi, C.; Chang, Y.H.; Chen, H.F.; Chen, H.S.; Chen, Z.G.; Chernoplekov, N.A.; Chiueh, T.H.; Chuang, Y.L.; Cindolo, F.; Commichau, V.; Contin, A. E-mail: contin@bo.infn.it; Crespo, P.; Cristinziani, M.; Cunha, J.P. da; Dai, T.S.; Deus, J.D.; Dinu, N.; Djambazov, L.; DAntone, I.; Dong, Z.R.; Emonet, P.; Engelberg, J.; Eppling, F.J.; Eronen, T.; Esposito, G.; Extermann, P.; Favier, J.; Fiandrini, E.; Fisher, P.H.; Fluegge, G.; Fouque, N.; Galaktionov, Yu.; Gervasi, M.; Giusti, P.; Grandi, D.; Grimm, O.; Gu, W.Q.; Hangarter, K.; Hasan, A.; Hermel, V.; Hofer, H.; Huang, M.A.; Hungerford, W.; Ionica, M.; Ionica, R.; Jongmanns, M.; Karlamaa, K.; Karpinski, W.; Kenney, G.; Kenny, J.; Kim, W.; Klimentov, A.; Kossakowski, R.; Koutsenko, V.; Kraeber, M.; Laborie, G.; Laitinen, T.; Lamanna, G.; Laurenti, G.; Lebedev, A.; Lee, S.C.; Levi, G.; Levtchenko, P.; Liu, C.L.; Liu, H.T.; Lopes, I.; Lu, G.; Lu, Y.S.; Luebelsmeyer, K.; Luckey, D.; Lustermann, W.; Mana, C.; Margotti, A.; Mayet, F.; McNeil, R.R.; Meillon, B.; Menichelli, M.; Mihul, A.; Mourao, A.; Mujunen, A.; Palmonari, F.; Papi, A.; Park, I.H.; Pauluzzi, M.; Pauss, F.; Perrin, E.; Pesci, A.; Pevsner, A.; Pimenta, M.; Plyaskin, V.; Pojidaev, V.; Postolache, V.; Produit, N.; Rancoita, P.G.; Rapin, D.; Raupach, F.; Ren, D.; Ren, Z.; Ribordy, M.; Richeux, J.P.; Riihonen, E.; Ritakari, J.; Roeser, U.; Roissin, C.; Sagdeev, R.; Sartorelli, G.; Schultz von Dratzig, A.; Schwering, G.; Scolieri, G.; Seo, E.S.; Shoutko, V.

    2002-02-01

    The Alpha Magnetic Spectrometer (AMS) is a large acceptance (0.65 sr m{sup 2}) detector designed to operate in the International Space Station (ISS) for three years. The purposes of the experiment are to search for cosmic antimatter and dark matter and to study the composition and energy spectrum of the primary cosmic rays. A 'scaled-down' version has been flown on the Space Shuttle Discovery for 10 days in June 1998. The complete AMS is programmed for installation on the ISS in October 2003 for an operational period of 3 yr. This contribution reports on the experimental configuration that will be installed on the ISS.

  17. The Alpha Magnetic Spectrometer (AMS)

    CERN Document Server

    Alcaraz, J; Ambrosi, G; Anderhub, H; Ao, L; Arefev, A; Azzarello, P; Babucci, E; Baldini, L; Basile, M; Barancourt, D; Barão, F; Barbier, G; Barreira, G; Battiston, R; Becker, R; Becker, U; Bellagamba, L; Bene, P; Berdugo, J; Berges, P; Bertucci, B; Biland, A; Bizzaglia, S; Blasko, S; Bölla, G; Boschini, M; Bourquin, Maurice; Brocco, L; Bruni, G; Buénerd, M; Burger, J D; Burger, W J; Cai, X D; Camps, C; Cannarsa, P; Capell, M; Casadei, D; Casaus, J; Castellini, G; Cecchi, C; Chang, Y H; Chen, H F; Chen, H S; Chen, Z G; Chernoplekov, N A; Tzi Hong Chiueh; Chuang, Y L; Cindolo, F; Commichau, V; Contin, A; Crespo, P; Cristinziani, M; Cunha, J P D; Dai, T S; Deus, J D; Dinu, N; Djambazov, L; Dantone, I; Dong, Z R; Emonet, P; Engelberg, J; Eppling, F J; Eronen, T; Esposito, G; Extermann, P; Favier, Jean; Fiandrini, E; Fisher, P H; Flügge, G; Fouque, N; Galaktionov, Yu; Gervasi, M; Giusti, P; Grandi, D; Grimm, O; Gu, W Q; Hangarter, K; Hasan, A; Hermel, V; Hofer, H; Huang, M A; Hungerford, W; Ionica, M; Ionica, R; Jongmanns, M; Karlamaa, K; Karpinski, W; Kenney, G; Kenny, J; Kim, W; Klimentov, A; Kossakowski, R; Koutsenko, V F; Kraeber, M; Laborie, G; Laitinen, T; Lamanna, G; Laurenti, G; Lebedev, A; Lee, S C; Levi, G; Levchenko, P M; Liu, C L; Liu, H T; Lopes, I; Lu, G; Lü, Y S; Lübelsmeyer, K; Luckey, D; Lustermann, W; Maña, C; Margotti, A; Mayet, F; McNeil, R R; Meillon, B; Menichelli, M; Mihul, A; Mourao, A; Mujunen, A; Palmonari, F; Papi, A; Park, I H; Pauluzzi, M; Pauss, Felicitas; Perrin, E; Pesci, A; Pevsner, A; Pimenta, M; Plyaskin, V; Pozhidaev, V; Postolache, V; Produit, N; Rancoita, P G; Rapin, D; Raupach, F; Ren, D; Ren, Z; Ribordy, M; Richeux, J P; Riihonen, E; Ritakari, J; Röser, U; Roissin, C; Sagdeev, R; Sartorelli, G; Schwering, G; Scolieri, G; Seo, E S; Shoutko, V; Shoumilov, E; Siedling, R; Son, D; Song, T; Steuer, M; Sun, G S; Suter, H; Tang, X W; Ting, Samuel C C; Ting, S M; Tornikoski, M; Torsti, J; Ulbricht, J; Urpo, S; Usoskin, I; Valtonen, E; Vandenhirtz, J; Velcea, F; Velikhov, E P; Verlaat, B; Vetlitskii, I; Vezzu, F; Vialle, J P; Viertel, Gert M; Vitè, Davide F; Gunten, H V; Wallraff, W; Wang, B C; Wang, J Z; Wang, Y H; Wiik, K; Williams, C; Wu, S X; Xia, P C; Yan, J L; Yan, L G; Yang, C G; Yang, M; Ye, S W; Yeh, P; Xu, Z Z; Zhang, H Y; Zhang, Z P; Zhao, D X; Zhu, G Y; Zhu, W Z; Zhuang, H L; Zichichi, A; Zimmermann, B

    2002-01-01

    The Alpha Magnetic Spectrometer (AMS) is a large acceptance (0.65 sr m sup 2) detector designed to operate in the International Space Station (ISS) for three years. The purposes of the experiment are to search for cosmic antimatter and dark matter and to study the composition and energy spectrum of the primary cosmic rays. A 'scaled-down' version has been flown on the Space Shuttle Discovery for 10 days in June 1998. The complete AMS is programmed for installation on the ISS in October 2003 for an operational period of 3 yr. This contribution reports on the experimental configuration that will be installed on the ISS.

  18. FPGA based pulsed NQR spectrometer

    Science.gov (United States)

    Hemnani, Preeti; Rajarajan, A. K.; Joshi, Gopal; Motiwala, Paresh D.; Ravindranath, S. V. G.

    2014-04-01

    An NQR spectrometer for the frequency range of 1 MHz to 5 MHZ has been designed constructed and tested using an FPGA module. Consisting of four modules viz. Transmitter, Probe, Receiver and computer controlled (FPGA & Software) module containing frequency synthesizer, pulse programmer, mixer, detection and display, the instrument is capable of exciting nuclei with a power of 200W and can detect signal of a few microvolts in strength. 14N signal from NaNO2 has been observed with the expected sign