Common extraction of Tc, Pd and Eu by phosphorylated calixarenes

International Nuclear Information System (INIS)

Babain, V.; Smirnov, I.; Kvasnitskiy, I.; Karavan, M.; Boiko, V.; Miroshnichenko, V.; Klimchuk, O.; Kalchenko, V.

2003-01-01

The present work is aimed at studying the extraction systems based on neutral organophosphorus extractants - phosphorylated calixarenes for recovery of Pd and Tc together with Am and Cm from high-level radioactive wastes. Extraction of Pd, Tc and Eu (Am) was studied for phosphorylated calixarenes in meta-nitrobenzotrifluoride (NBTF). Main results are presented in Table. On the basis of available data one can suggest that type and position of phosphor-organic substituents are not so important for extraction of Tc and Pd, as for Eu and Am extraction. The phosphorylated at upper rim calix[4]arenas with small alkyl substituents at phosphorus atom are of prime interest for joint recovery of europium, americium, technetium and palladium. (authors)

Radioactive waste programme in Latvia

International Nuclear Information System (INIS)

Salmins, A.

2000-01-01

An overview is made on the use of radioactive sources and waste management in Latvia. Brief overview of the development of national legal documents - the framework law of environmental protection; international agreements; the new law on radiation safety and nuclear safety; regulation of the Cabinet of Ministers - is given. The regulatory infrastructure in the nearest future is outlined. The institutional framework for radioactive waste management is described. Basic design of the repository and radioactive waste inventory are also given. The activities on the EU DG Environment project CASIOPEE are reported

Strategy on radioactive waste management in Lithuania

International Nuclear Information System (INIS)

Poskas, P.; Adomaitis, J.E.

2003-01-01

In Lithuania about 70-80% of all electricity is generated at a single power station, Ignalian NPP which has two non-upgradable RBMK-1500 type reactors. The unit 1 will be closed by 2005. The decision on unit 2 should be made in Lithuanian Parliament very soon taking into consideration substantial long-term financial assistance from the EU, G7 and other states as well as international institutions. The Government approved the Strategy on Radioactive Waste Management in 2002. Objectives of this strategy are to develop the radioactive waste management infrastructure based on modern technologies and provide for the set of practical actions that shall bring management of radioactive waste in Lithuania in compliance with radioactive waste management principles of IAEA and with good practices in force in EU Member States. Ignalina NPP is undertaking a program of decommissioning support projects, financed by grants from the International Ignalina Decommissioning Support Fund, administered by the European Bank for Reconstruction and Development. This program comprises also the implementation of investment projects in a number of pre-decommissioning facilities including the management of radioactive waste and spent nuclear fuel. (orig.)

Estimation of radioactive contamination of soils from the "Balapan" and the "Experimental field" technical areas of the Semipalatinsk nuclear test site.

Science.gov (United States)

Evseeva, T; Belykh, E; Geras'kin, S; Majstrenko, T

2012-07-01

In spite of the long history of the research, radioactive contamination of the Semipalatinsk nuclear test site (SNTS) in the Republic of Kazakhstan has not been adequately characterized. Our cartographic investigation has demonstrated highly variable radioactive contamination of the SNTS. The Cs-137, Sr-90, Eu-152, Eu-154, Co-60, and Am-241 activity concentrations in soil samples from the "Balapan" site were 42.6-17646, 96-18250, 1.05-11222, 0.6-4865, 0.23-4893, and 1.2-1037 Bq kg(-1), correspondingly. Cs-137 and Sr-90 activity concentrations in soil samples from the "Experimental field" site were varied from 87 up to 400 and from 94 up to 1000 Bq kg(-1), respectively. Activity concentrations of Co-60, Eu-152, and Eu-154 were lower than the minimum detectable activity of the method used. Concentrations of naturally occurring radionuclides (K-40, Ra-226, U-238, and Th-232) in the majority of soil samples from the "Balapan" and the "Experimental field" sites did not exceed typical for surrounding of the SNTS areas levels. Estimation of risks associated with radioactive contamination based on the IAEA clearance levels for a number of key radionuclides in solid materials shows that soils sampled from the "Balapan" and the "Experimental field" sites might be considered as radioactive wastes. Decrease in specific activity of soil from the sites studied up to safety levels due to Co-60, Cs-137, Sr-90, Eu-152, Eu-154 radioactive decay and Am-241 accumulation-decay will occur not earlier than 100 years. In contrast, soils from the "Experimental field" and the "Balapan" sites (except 0.5-2.5 km distance from the "Chagan" explosion point) cannot be regarded as the radioactive wastes according safety norms valid in Russia and Kazakhstan. Copyright © 2012 Elsevier Ltd. All rights reserved.

Photoluminescence studies on Eu doped TiO2 nanoparticles

International Nuclear Information System (INIS)

Ningthoujam, R.S.; Sudarsan, V.; Vatsa, R.K.; Kadam, R.M.; Jagannath; Gupta, A.

2009-01-01

Eu 3+ doped TiO 2 nanoparticles were prepared by urea hydrolysis in ethylene glycol medium at low temperature of 150 deg. C. X-ray diffraction study showed that anatase phase of tetragonal structure was formed below 500 deg. C; and above this temperature, additional peaks due to rutile phase were also observed. From luminescence study, it was found that as prepared nanoparticles showed the enhanced luminescence intensity due to energy transfer from host to europium ions. However, photoluminescence from these nanoparticles was found to disappear when the samples were heated above 900 deg. C. We established the origin of the reduction in the luminescence intensity from Eu 3+ when doped in TiO 2 and heated at 900 deg. C. Based on detailed studies at different heat-treatment temperatures using techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, electron paramagnetic resonance, Raman spectroscopy, and Moessbauer spectroscopy, it has been established that formation of Eu 2 Ti 2 O 7 phase, wherein Eu 3+ ions occupy high symmetric environment (D 3d ) and also reduced distance between Eu 3+ and Eu 3+ ions is responsible for the decrease/loss in the luminescence intensity.

Optical studies on Eu3+ doped boro-tellurite glasses

Science.gov (United States)

Maheshvaran, K.; Marimuthu, K.

2012-06-01

Eu3+ doped boro-tellurite glasses with the chemical composition (39-x)B2O3+30TeO2+15MgO+15K2O +xEu2O3 (where x = 0.01, 0.1, 1, 2 and 3 wt%) have been prepared by following conventional melt quenching technique. Spectroscopic properties of the Eu3+ doped boro-tellurite glasses have been studied by recording the optical absorption and luminescence measurements. Through the optical absorption spectra, bonding parameters (β¯, δ) have been calculated to identify the ionic/covalent nature of the glasses. Judd-Ofelt (JO) analysis have been carried out using the luminescence spectra. The JO parameters (Ωλ = 2, 4 and 6) were used to calculate the radiative properties for the 5D0 → 7FJ (J = 1, 2, 3 and 4) emission transitions of the Eu3+ ions. The change in optical properties with the variation of Eu3+ ion concentration have been studied and discussed with similar studies.

Use of almond endocarp shell in sorption of radioactive 152+154Europium from waste solutions

International Nuclear Information System (INIS)

Dakroury, G.A.; Khalil, T.; Abou El-Nour, F.H.

2007-01-01

In an attempt to remove radioactive ( 152 + 154 )Eu from waste solutions, the present study was tried to explore the possibility of using a natural by-product. Almond endocarp (AEC) shell produced from Sinai (El-Arish area) was selected as agricultural by-product in treatment of waste solutions containing ( 152 + 154 )Eu through a batch technique. The different physico-chemical characteristics of AEC such as specific surface area, total pore volume, average pore diameter, apparent density, porosity and pore size distribution were calculated. The adsorption process was described by a Freundlich type isotherm. The uptake percent of the metal ion was determined for the sorbent material as a function of contact time, pH-value, mass of the sorbent material, metal ion concentration and the effect of competing ions on the sorption process. The obtained data were analyzed and showed that almond endocarp shell powder can be considered as an efficient natural material to be used for sorption of radioactive ( 152 + 154 )Eu from their radioactive waste solutions

Kinetic Study on the Sorption of Te (IV), Ce (III) and Eu (III) on some Inorganic Ion Exchangers

International Nuclear Information System (INIS)

El-Sweify, F.H.; Shehata, M.K.K.; El-Shazly, E.A.A.

2008-01-01

The sorption behaviour of Te (IV), Ce (III) and Eu (III) on zirconium phosphate (Zr P) and ceric tungstate under various conditions was studied. Some factors affecting the sorption kinetics of the aforementioned metal ions on both ion exchangers were investigated. These factors were: hydrogen ion concentration in the absence of complexing agents, contact time, particle size of the two mentioned ion exchangers, metal in concentration and temperature. Radioactive isotopes were used for tracing the corresponding elements. Some physical parameters related to the sorption process were calculated from the obtained data

Nuclear and x-ray spectroscopy with radioactive sources

International Nuclear Information System (INIS)

Fink, R.W.

1977-01-01

Research in nuclear chemistry for 1977 is reviewed. The greatest part of the effort was directed to nuclear spectroscopy (systematics, models, experimental studies), but some work was also done involving fast neutrons and x rays from radioactive sources. Isotopes of Tl, Hg, Au, and Eu were studied in particular. Personnel and publications lists are also included. 5 figures, 1 table

Electrochemical behaviour of the Eu3+/Eu2+ system in propionic media studied by cyclic chrono potentiometry

International Nuclear Information System (INIS)

Brotto, M.E.

1989-01-01

The electrochemical behaviour of the Eu 3 + / Eu 2 + system in propionic media was studied by means of current reversal chrono potentiometry and cyclic chrono potentiometry. Sodium perchlorate was employed as supporting electrolyte. The experiments were carried out at (25.0 ± 0.1) 0 C. The studied variables were the concentration of the electro active species, the composition of the solution and the current density. The cyclic chrono potentiometry results reveal that the charge transfer reaction is followed by the (H 3 O) + ion assisted irreversible catalytic reaction in which the Eu 3 + species is regenerated. (author)

Estimation of radioactive contamination of soils from the “Balapan” and the “Experimental field” technical areas of the Semipalatinsk nuclear test site

International Nuclear Information System (INIS)

Evseeva, T.; Belykh, E.; Geras’kin, S.; Majstrenko, T.

2012-01-01

In spite of the long history of the research, radioactive contamination of the Semipalatinsk nuclear test site (SNTS) in the Republic of Kazakhstan has not been adequately characterized. Our cartographic investigation has demonstrated highly variable radioactive contamination of the SNTS. The Cs-137, Sr-90, Eu-152, Eu-154, Co-60, and Am-241 activity concentrations in soil samples from the “Balapan” site were 42.6–17646, 96–18250, 1.05–11222, 0.6–4865, 0.23–4893, and 1.2–1037 Bq kg −1 , correspondingly. Cs-137 and Sr-90 activity concentrations in soil samples from the “Experimental field” site were varied from 87 up to 400 and from 94 up to 1000 Bq kg −1 , respectively. Activity concentrations of Co-60, Eu-152, and Eu-154 were lower than the minimum detectable activity of the method used. Concentrations of naturally occurring radionuclides (K-40, Ra-226, U-238, and Th-232) in the majority of soil samples from the “Balapan” and the “Experimental field” sites did not exceed typical for surrounding of the SNTS areas levels. Estimation of risks associated with radioactive contamination based on the IAEA clearance levels for a number of key radionuclides in solid materials shows that soils sampled from the 'Balapan' and the “Experimental field” sites might be considered as radioactive wastes. Decrease in specific activity of soil from the sites studied up to safety levels due to Co-60, Cs-137, Sr-90, Eu-152, Eu-154 radioactive decay and Am-241 accumulation-decay will occur not earlier than 100 years. In contrast, soils from the “Experimental field” and the “Balapan” sites (except 0.5–2.5 km distance from the “Chagan” explosion point) cannot be regarded as the radioactive wastes according safety norms valid in Russia and Kazakhstan. - Highlights: ► Distribution of radionuclides in soil of Semipalatinsk test site was mapped. ► The main contributors into soil radioactive contamination were 137 Cs and 90 Sr. ► Soils

School version of ESTE EU

International Nuclear Information System (INIS)

Carny, P.; Suchon, D.; Chyly, M.; Smejkalova, E.; Fabova, V.

2008-01-01

ESTE EU is information system and software for radiological impacts assessment to the territory of the country in case of radiation accident inside/outside of the country .The program enables to model dispersion of radioactive clouds in small-scale and meso-scale. The system enables the user to estimate prediction of the source term (release to the atmosphere ) for any point of radiation/nuclear accident in Europe (for any point of the release, but especially for the sites of European power reactors ). The system enables to utilize results of real radiological monitoring in the process of source term estimation. Radiological impacts of release to the atmosphere are modelled and calculated across the Europe and displayed in the geographical information system (GIS). The school version of ESTE EU is intended for students of the universities which are interested in or could work in the field of emergency response, radiological and nuclear accidents, dispersion modelling, radiological impacts calculation and urgent or preventive protective measures implementation. The school version of ESTE EU is planned to be donated to specialized departments of faculties in Slovakia, Czech Republic, etc. System can be fully operated in Slovak, Czech or English language. (authors)

School version of ESTE EU

International Nuclear Information System (INIS)

Carny, P.; Suchon, D.; Chyly, M.; Smejkalova, E.; Fabova, V.

2009-01-01

ESTE EU is information system and software for radiological impacts assessment to the territory of the country in case of radiation accident inside/outside of the country .The program enables to model dispersion of radioactive clouds in small-scale and meso-scale. The system enables the user to estimate prediction of the source term (release to the atmosphere ) for any point of radiation/nuclear accident in Europe (for any point of the release, but especially for the sites of European power reactors ). The system enables to utilize results of real radiological monitoring in the process of source term estimation. Radiological impacts of release to the atmosphere are modelled and calculated across the Europe and displayed in the geographical information system (GIS). The school version of ESTE EU is intended for students of the universities which are interested in or could work in the field of emergency response, radiological and nuclear accidents, dispersion modelling, radiological impacts calculation and urgent or preventive protective measures implementation. The school version of ESTE EU is planned to be donated to specialized departments of faculties in Slovakia, Czech Republic, etc. System can be fully operated in Slovak, Czech or English language. (authors)

Selective separation of Eu3+ using polymer-enhanced ultrafiltration

International Nuclear Information System (INIS)

Norton, M.V.

1994-03-01

A process to selectively remove 241 Am from liquid radioactive waste was investigated as an actinide separation method applicable to Hanford and other waste sites. The experimental procedures involved removal of Eu, a nonradioactive surrogate for Am, from aqueous solutions at pH 5 using organic polymers in conjunction with ultrafiltration. Commercially available polyacrylic acid (60,000 MW) and Pacific Northwest Laboratory's (PNL) synthesized E3 copolymer (∼10,000 MW) were tested. Test solutions containing 10 μg/mL of Eu were dosed vath each polymer at various concentrations in order to bind Eu (i.e., by complexation and/or cation exchange) for subsequent rejection by an ultrafiltration coupon. Test solutions were filtered with and without polymer to determine if enhanced Eu separation could be achieved from polymer treatment. Both polymers significantly increased Eu removal. Optimum concentrations were 20 μg/mL of polyacrylic acid and 100 μg/mL of E3 for 100% Eu rejection by the Amicon PM10 membrane at 55 psi. In addition to enhancement of removal, the polymers selectively bound Eu over Na, suggesting that selective separation of Eu was possible. This suggests that polymer-enhanced ultrafiltration is a potential process for separation of 241 Am from Hanford tank waste, further investigation of binding agents and membranes effective under very alkaline and high ionic strength is warranted. This process also has potential applications for selective separation of toxic metals from industrial process streams

Recent EU institutional developments in the nuclear field: outlook positive

International Nuclear Information System (INIS)

Ivens, Richard

2008-01-01

The main topics presented and discussed are:European Nuclear Energy Forum (ENEF); European Nuclear Installations Safety Standards (ENISS); High Level Group on Safety and Radioactive Waste (HLG); Sustainable Nuclear Energy Technology Platform (SNETP); Strategic Energy Technology Plan (SETP); EP report on Conventional Energies Forthcoming EU developments

Mg-Al layered double hydroxide intercalated with sodium lauryl sulfate as a sorbent for 152+154Eu from aqueous solutions

International Nuclear Information System (INIS)

Mahmoud, M.R.; Someda, H.H.

2012-01-01

In the present study, Mg-Al layered double hydroxide intercalated with nitrate anions (LDH-NO 3 ) was synthesized, modified with the anionic surfactant, sodium lauryl sulfate, and applied for the removal of 152+154 Eu from aqueous solutions. Modification of the as-synthesized Mg-Al layered double hydroxide was carried out at surfactant concentration of 0.01 M (the organo-LDH produced denoted LDH-NaLS). The as-synthesized and surfactant-intercalated LDHs were characterized by FT-IR and energy-dispersive X-ray spectroscopy techniques. The effect of some variables such as solution pH, contact time and sorbate concentration on removal of 152+154 Eu was investigated. The kinetic data obtained were well fitted by the pseudo-second-order kinetic model rather than the pseudo-first-order model. Intraparticle diffusion model showed that sorption of 152+154 Eu proceed by intraparticle diffusion together with boundary layer diffusion. Experimental isotherm data were well described by Langmuir model. Organo-LDH was found to have higher capacity (156.45 mg g -1 ) for europium than the as-synthesized LDH-NO 3 (119.56 mg g -1 ). Comparing LDHs capacities obtained for Eu(III) in the present work with other sorbents reported in literature indicated that LDHs have the highest capacities. Application of the developed process for removal of 152+154 Eu(III) from radioactive process wastewaters was also studied and the obtained results revealed that these LDHs are promising materials for treatment of radioactive wastewaters. (author)

Competitive effect of metallic canister and clay barrier on the sorption of Eu3+ under subcritical conditions

International Nuclear Information System (INIS)

El Mrabet, Said; Castro, Miguel A.; Orta, M. Mar; Pazos, M. Carolina; Alba, Maria D.; Astudillo, Julio; Rueda, Silvia; Hurtado, Santiago; Villa, Mara

2012-01-01

Document available in extended abstract form only. The disposal of high level radioactive wastes (HLW) such as spent fuel or reprocessing waste resulting from the operation and dismantling of nuclear reactors is one of the most problems facing the worlds because of its long half life and radionuclide migration to the biosphere. For long term performance assessment of radioactive waste disposal, knowledge concerning radionuclide retention processes on materials composing the engineered barrier (clay and container waste) is required. Steel waste containers and bentonite have been proposed as candidate materials for overpack and buffer respectively in most of the proposed repositories designs for nuclear waste disposal. This contribution aims to study the competitiveness of the bentonite and the metallic canister in the retention process of some kinds of radioactive waste such as 152 Eu. The europium was chosen because it is a toxic metal and usually taken as a simulator of the trivalent high level radioactive waste. In order to elucidate the mechanisms involved in the retention processes of europium by both bentonite and metallic canister, a cylindrical steel mini-reactor was designed and prepared from the same material as the steel reactor AISI-316L. The bentonite was then introduced and compacted within the mini-reactor forming a set mini-reactor- bentonite. The system mini-reactor -bentonite was then subjected to hydrothermal treatments at 300 deg. C for 4.5 days. The morphology and chemical composition of both steel and bentonite were analyzed by XRD and SEM. SEM and XRD results revealed that both the bentonite and the metallic canister were involved in sorption mechanism of europium by the formation of insoluble phases of europium silicates originated from the mixed solution of bentonite, Eu 3+ and canister. The pH-Redox potential (Eh) indicated that the interlayer cations of bentonite were replaced by Eu 3+ with higher acidity and Eh which means that the active

Radioactive materials in ashes from peat fired plants

International Nuclear Information System (INIS)

Erlandsson, B.; Hedvall, R.

1984-11-01

Measurements of the gamma radiation have been used for determination of radioactive materials in peat ashes from five Swedish heating plants. The results show that the amount of radioactive materials was almost the same in all samples. The concentration of 125 Sb, 137 Cs, 144 Cs and 155 Eu were in good conformity with the concentrations found in the environment. The 235 U-concentration was hardly possible to measure. (Edv)

Treatment of radioactive waste - Routine or challenge? Proceedings

International Nuclear Information System (INIS)

2003-01-01

The seminar had the following topics: Proposal for new legislation covering radioactive waste management in the EU, new requirements preparations for the later repository, efficient and cost effective treatment of radioactive waste water, intermediate level waste cementation, incineration of spent ion exchange resins in a triphasic mixture, application of THOR-technology on resins, new development for transportation and storage of reactor vessel parts, and conditioning of nuclear fuel containing wastes. (uke)

Radioactivity in Trinitite six decades later

International Nuclear Information System (INIS)

Parekh, Pravin P.; Semkow, Thomas M.; Torres, Miguel A.; Haines, Douglas K.; Cooper, Joseph M.; Rosenberg, Peter M.; Kitto, Michael E.

2006-01-01

The first nuclear explosion test, named the Trinity test, was conducted on July 16, 1945 near Alamogordo, New Mexico. In the tremendous heat of the explosion, the radioactive debris fused with the local soil into a glassy material named Trinitite. Selected Trinitite samples from ground zero (GZ) of the test site were investigated in detail for radioactivity. The techniques used included α spectrometry, high-efficiency γ-ray spectrometry, and low-background β counting, following the radiochemistry for selected radionuclides. Specific activities were determined for fission products ( 9 Sr, 137 Cs), activation products ( 6 Co, 133 Ba, 152 Eu, 154 Eu, 238 Pu, 241 Pu), and the remnants of the nuclear fuel ( 239 Pu, 24 Pu). Additionally, specific activities of three natural radionuclides ( 4 K, 232 Th, 238 U) and their progeny were measured. The determined specific activities of radionuclides and their relationships are interpreted in the context of the fission process, chemical behavior of the elements, as well as the nuclear explosion phenomenology

EU Studies in Denmark and Sweden

DEFF Research Database (Denmark)

Garski, Salla; Jørgensen, Knud Erik; Manners, Ian

2012-01-01

In this brief chapter we take stock of Danish and Swedish scholarship on the European Union (EU). We intend to analyze and evaluate Danish and Swedish scholarship on EU issues, using a mixed methodology integrated into the analysis of this chapter. The method integrates a secondary analysis...

Intrinsic radioactivity of KSr{sub 2}I{sub 5}:Eu{sup 2+}

Energy Technology Data Exchange (ETDEWEB)

Rust, M.; Melcher, C.; Lukosi, E., E-mail: elukosi@utk.edu

2016-10-11

A current need in nuclear security is an economical, yet high energy resolution (near 2%), scintillation detector suitable for gamma-ray spectroscopy. For current scintillators on the market, there is an inverse relationship between scintillator energy resolution and cost of production. A new promising scintillator, KSr{sub 2}I{sub 5}:Eu{sup 2+}, under development at the University of Tennessee, has achieved an energy resolution of 2.4% at 662 keV at room temperature, with potential growth rates exceeding several millimeters per hour. However, the internal background due to the {sup 40}K content could present a hurdle for effective source detection/identification in nuclear security applications. As a first step in addressing this question, this paper reports on a computational investigation of the intrinsic differential pulse height spectrum (DPHS) generated by {sup 40}K within the KSr{sub 2}I{sub 5}:Eu{sup 2+} scintillator as a function of crystal geometry. It was found that the DPHS remains relatively equal to a constant multiplicative factor of the negatron emission spectrum with a direct increase of the 1.46 MeV photopeak relative height to the negatron spectrum with volume. Further, peak pileup does not readily manifest itself for practical KSr{sub 2}I{sub 5}:Eu{sup 2+} volumes.

European legislation on radioactive waste management - opportunities and areas of uncertainty in case of shared competence

International Nuclear Information System (INIS)

Borisova, O.

2013-01-01

The aim of this study is to establish the regularities characterizing the European legislative framework for the radioactive waste management, the basic principles, legislative mechanism and relevant alternative methods of co-regulation and self-regulation, as well as characterization of areas of uncertainty in the radioactive waste management in case of shared competence and capabilities to improve the system involved in management of dangerous to health and the environment wastes from nuclear applications. Subject of study is the EU legislative framework on the management of radioactive waste, in particular the possibilities of existing mechanisms to achieve balance in the distribution of powers between the Community and national legislation regarding the responsibilities related to the radioactive waste management

EU Think Tank Fora as Transaction Cost Reducers: A Study of Informal Interest Intermediation in the EU

Directory of Open Access Journals (Sweden)

Marybel Perez

2014-05-01

Full Text Available By examining the organisational structure of EU think tank fora (seminars, workshops and conferences, this article proposes that fora can play the role of transaction cost reducers in EU policymaking. I argue that certain aspects of EU policymaking, including i controlled processes of consultation, ii diminishing costs of management, and iii the risk of state capture, incentivise EU institutions to outsource part of the consultation activity to policy actors that can help EU institutions fulfil their informational and legitimacy needs. I argue that think tanks are able to play this role because they i reduce information asymmetries by connecting a wide variety of policy actors and ii act as intermediaries that mitigate opportunistic behaviour. The empirical assessment reveals that the dimensions characterising transactions are present in EU think tank fora. It shows that policy actors that do not usually participate in formal consultation processes frequently attend fora where they meet representatives of EU institutions, particularly Parliament and Commission representatives.

The ETSON study on treatment processes for the sustainable management of radioactive waste

International Nuclear Information System (INIS)

Besnus, Francois; Metcalf, Phil; Wasselin-Trupin, Virginie; Pfingsten, Wilfred; Smidts, Olivier; Miksova, Jitka; Tokaresvski, Oleksei

2016-01-01

ETSON (European Technical Safety Organisation Network): • European association of nuclear assessment bodies; • Objective: - develop and promote best practice in nuclear safety assessment; - foster the convergence of technical nuclear safety practices within the EU and beyond; - assist with planning of nuclear safety research programmes; - facilitate the application of the European directives on nuclear, radiation and radioactive waste and spent fuel safety. • ETSON Activities: - forum for voluntary exchange on both analyses and R&D in the fields of nuclear, radiation and radioactive waste safety; - Issue technical and scientific opinions; - 13 expert groups; one dedicated to Waste management and decommissioning issues (WM&D Group); • WM&D work programme: - Elaborate a common position on decommissioning strategies; - Prepare elements for technical guidance on the operational safety of underground disposal facilities; - Organise an international workshop on sustainable waste management processes prior to disposal

Formation of nanostructures in Eu3+ doped glass-ceramics: an XAS study.

Science.gov (United States)

Pellicer-Porres, J; Segura, A; Martínez-Criado, G; Rodríguez-Mendoza, U R; Lavín, V

2013-01-16

We describe the results of x-ray absorption experiments carried out to deduce structural and chemical information in Eu(3+) doped, transparent, oxyfluoride glass and nanostructured glass-ceramic samples. The spectra were measured at the Pb and Eu-L(III) edges. The Eu environment in the glass samples is observed to be similar to that of EuF(3). Complementary x-ray diffraction experiments show that thermal annealing creates β-PbF(2) type nanocrystals. X-ray absorption indicates that Eu ions act as seeds in the nanocrystal formation. There is evidence of interstitial fluorine atoms around Eu ions as well as Eu dimers. X-ray absorption at the Pb-L(III) edge shows that after the thermal treatment most lead atoms form a PbO amorphous phase and that only 10% of the lead atoms remain available to form β-PbF(2) type nanocrystals. Both x-ray diffraction and absorption point to a high Eu content in the nanocrystals. Our study suggests new approaches to the oxyfluoride glass-ceramic synthesis in order to further improve their properties.

Summing coincidence errors using Eu-152 lungs to calibrate a lung-counting system: are they significant?

International Nuclear Information System (INIS)

Kramer, Gary H.; Lynch, Timothy P.; Lopez, Maria A.; Hauck, Brian

2004-01-01

The use of a lung phantom containing 152Eu/241Am activity can provide a sufficient number of energy lines to generate an efficiency calibration for the in vivo measurements of radioactive materials in the lungs. However, due to the number of energy lines associated with 152Eu, coincidence summing occurs and can present a problem when using such a phantom for calibrating lung-counting systems. A Summing Peak Effect Study was conducted at three laboratories to determine the effect of using an efficiency calibration based on a 152Eu/241Am lung phantom. The measurement data at all three laboratories showed the presence of sum peaks. However, two of the three laboratories found only small biases (<5%) when using the 152Eu/241Am calibration. The third facility noted a 25% to 30% positive bias in the 140-keV to 190-keV energy range that prevents the use of the 152Eu/241Am lung phantom for routine calibrations. Although manufactured by different vendors, the three facilities use similar types of detectors (38 cm2 by 25 mm thick or 38 cm2 by 30 mm thick) for counting. These study results underscore the need to evaluate the coincidence summing effect when using a nuclide such as 152Eu for the calibration of low energy lung counting systems

Does EU emissions trading bite? An event study

International Nuclear Information System (INIS)

Jong, Thijs; Couwenberg, Oscar; Woerdman, Edwin

2014-01-01

The aim of this paper is to examine whether shareholders consider the EU Emissions Trading Scheme (EU ETS) as value-relevant for the participating firms. An analysis is conducted of the share prices changes as caused by the first publication of compliance data in April, 2006, which disclosed an over-allocation of emission allowances. Through an event study, it is shown that share prices actually increased as a result of the allowance price drop when firms have a lower carbon-intensity of production and larger allowance holdings. There was no significant value impact from firms' allowance trade activity or from the pass-through of carbon-related production costs (carbon leakage). The conclusion is that the EU ETS does ‘bite’. The main impact on the share prices of firms arises from their carbon-intensity of production. The EU ETS is thus valued as a restriction on pollution. - Highlights: • Firms are more positively valued with lower carbon-intensities of production. • Firms are more negatively valued with smaller holdings of allowances. • The stock market does not value the firms' allowance trade activity. • The stock market does not seem to value the pass-through of carbon costs in product prices

EU Budgetary Dynamics

DEFF Research Database (Denmark)

Citi, Manuele

2013-01-01

In this article I study the long-term evolution of the main categories of expenditure of the European Union (EU) budget (1984-2011). The aim is to assess the extent to which the EU is affected by a structural form of policy inertia, and to investigate the general pattern of policy stability...... and change in the EU in light of the two models of policy dynamics currently existing in the literature: the incrementalist model and the punctuated equilibrium model. The analysis of long series of original data extracted from the EU budget shows that EU policies do not evolve following an incrementalist...

Charge breeding of intense radioactive beams

CERN Document Server

Kester, O

2001-01-01

The efficient transformation of radioactive beams by charge breeding devices will critically influence the lay-out of the post accelerator of presently built first generation radioactive ion beam (RIB) facilities as well as new second generation facilities. The size of the post-accelerator needed to bring the unstable nuclei to the energies required to study nuclear reactions depends on the charge state of the radioactive ions. The capability to raise that charge state from 1+ to n+, where n may correspond to a charge-to- mass ratio of 0.15 or higher, will therefore produce an enormous reduction in cost as well as the possibility to accelerate heavier masses. Thus the efficiency of the charge breeding scheme in comparison to the stripping scheme will be explored in the frame of the EU-network charge breeding. The two possible charge breeding schemes using either an Electron Beam Ion Source (EBIS) or an Electron Cyclotron Resonance Ion Source (ECRIS), the demands to the sources and the present status of existi...

Impact of Eu(III) on mammalian cells as a function of its speciation

Energy Technology Data Exchange (ETDEWEB)

Sachs, Susanne; Heller, Anne; Geipel, Gerhard; Bernhard, Gert [Helmholtz-Zentrum Dresden-Rossendorf, Institute of Resource Ecology, Bautzner Landstr. 400, 01328 Dresden (Germany)

2014-07-01

In the case of the accidental release of long-lived radionuclides, e.g., actinides, into the environment, knowledge of their behavior in bio-systems is necessary to asses and to prevent radiological and chemical induced adverse health effects. This includes knowledge of the bioavailability and chemo-/radio-toxicity of these elements for/onto cells, which are governed to a large extent by their speciation [1,2]. In order to gain a better process understanding, we study the interaction of trivalent actinides/lanthanides with mammalian cells on a cellular level combining biochemical and analytical methods. Results of these studies can contribute to the estimation of low dose effects and the development of new decontamination strategies. The cellular tolerance of FaDu cells (human squamous cell carcinoma cell line) toward Eu(III) as an analog for trivalent actinides as well as its uptake into the cells has been studied as a function of the Eu(III) concentration and nutrient composition. To differentiate between chemo-toxic and radio-toxic effects of Eu(III), {sup 152}Eu (β{sup -}, ε) was applied as radioactive tracer besides europium with natural isotope composition. The Eu(III) speciation in the cell culture media has been investigated by time-resolved laser-induced fluorescence spectroscopy as well as by solubility studies in combination with ultrafiltration, ultracentrifugation, cation and anion analysis. These results are used to correlate cytotoxicity and uptake of Eu(III) on/into the cells with its chemical speciation in the nutrient. Presently, we are studying the interaction of Eu(III) with NRK-52E cells (rat kidney epithelial-like cells). The results of these studies will be discussed and compared to those obtained with FaDu cells. From the studies with FaDu cells it was concluded that the Eu(III) cytotoxicity onto these cells depends on the Eu(III) concentration and is influenced by its chemical speciation. This was also reported, for instance, for the

Rebalancing EU Interest Representation? Assocative Democracy and EU funding of Civil Society Organizations

NARCIS (Netherlands)

Sanchez Salgado, R.

2014-01-01

European Union (EU) funding of civil society organizations (CSOs) is a substantial and important part of EU governance, but study of such funding is scarce and theoretically underdeveloped. To fill this gap, this article analyzes the main features of EU funding of CSOs and its effects on the EU

Ex-ante Study of a Possible Modernisation of the EU-Chile Association Agreement

NARCIS (Netherlands)

Henry de Frahan, Bruno; Hartwell, Christopher; Kuik, O.J.; Lirette, Paul; Mirecka, Katarzyna; Nolan Garcia, Kimberly; Pellandra, Andrea; Polanco, Rodrigo; Schmidt-Hebbel, Klaus; Shuvaieva, Iryna; Sidlo, Kataryna; Teresinski, Jan; Torrent, Ramon; Valdes, Albert

This study provides an ex-ante impact assessment of the possible modernisation of the EU-Chile Association Agreement. Since the current agreement entered into force in 2003, Chilean exports of agricultural/food products and services to the EU have nearly tripled while EU exports to Chile have

Optically active centers in Eu implanted, Eu in situ doped GaN, and Eu doped GaN quantum dots

International Nuclear Information System (INIS)

Bodiou, L.; Braud, A.; Doualan, J.-L.; Moncorge, R.; Park, J. H.; Munasinghe, C.; Steckl, A. J.; Lorenz, K.; Alves, E.; Daudin, B.

2009-01-01

A comparison is presented between Eu implanted and Eu in situ doped GaN thin films showing that two predominant Eu sites are optically active around 620 nm in both types of samples with below and above bandgap excitation. One of these sites, identified as a Ga substitutional site, is common to both types of Eu doped GaN samples despite the difference in the GaN film growth method and in the doping technique. High-resolution photoluminescence (PL) spectra under resonant excitation reveal that in all samples these two host-sensitized sites are in small amount compared to the majority of Eu ions which occupy isolated Ga substitutional sites and thus cannot be excited through the GaN host. The relative concentrations of the two predominant host-sensitized Eu sites are strongly affected by the annealing temperature for Eu implanted samples and by the group III element time opening in the molecular beam epitaxy growth. Red luminescence decay characteristics for the two Eu sites reveal different excitation paths. PL dynamics under above bandgap excitation indicate that Eu ions occupying a Ga substitutional site are either excited directly into the 5 D 0 level or into higher excited levels such as 5 D 1 , while Eu ions sitting in the other site are only directly excited into the 5 D 0 level. These differences are discussed in terms of the spectral overlap between the emission band of a nearby bound exciton and the absorption bands of Eu ions. The study of Eu doped GaN quantum dots reveals the existence of only one type of Eu site under above bandgap excitation, with Eu PL dynamics features similar to Eu ions in Ga substitutional sites

Radiation consequences of combatant radioactive substances tests on the Semipalatinsk Test Site

International Nuclear Information System (INIS)

Strilchuk, Yu.G.; Osintsev, A.Yu.; Kuzin, D.E.; Bryantseva, N.V.; Bozhko, V.V.; Tonevitskaya, O.V.; Panitskaya, D.S.; Lukashenko, S.N.; Georgievskij, V.; Murley, R.; Wells, D.

2008-01-01

Nuclear explosions were not the only type of tests carried out on the STS territory. In 1953 - 1957 the STS territory was the area of testing of combatant radioactive substances (CRS). Combatant radioactive substances were liquid or powder-like combatment radioactive mixtures manufactured either from the wastes of radiochemical industry or by neutron irradiation of specally selected substances in nuclear reactor. Their specific activity ranged from tenths of Curie to several Curie per liter. CRS tests were made on testing grounds ''4'' and ''4A'' situated near northern outpost beyond the Opytnoye Pole (Experimental field). Dispersion of CRS was achieved by blasting of individual shells, bombardment of the area by mortar shells, bombardment from aircraft bombers or dispersion of CRS from airplanes. Investigations carried out in the past years on the territory of the testing grounds discovered fragments of metal products used in the CRS tests and over 30 areas of local radioactive contamination. 90 Sr was the main radioactive pollutant, whose specific activity in upper soil is as high as 5*10 8 Bq/kg; other radionuclides are presented by isotopes: 239+240 Pu, 152 Eu, 154 Eu, 137 Cs, 241 Am, 60 Co. The areas of radioactively-contaminated soil range from hundreds to hundreds of thousands of square meters with some of them expanding to distances of several kilometers. Concentration of radionuclides in soil and vegetation may be compared with that of radioactive waste

The use of nuclear prospecting measurements for characterizing the radioactive status of Al-Bayyarat and Sabkhet Mouh areas, southern Palmyrides, Syria

International Nuclear Information System (INIS)

Asfahani, J.; Al-Hent, R.; Aissa, M.

2014-01-01

Al-Bayyarat and Sabkhet Mouh areas in southern Palmyride have been radioactively characterized by using different nuclear prospecting measurements. Those measurements include the application of airborne, carborne spectrometric gamma, radon emanation and borehole techniques. The merging of airborne, carborne spectrometric gamma data enables to establish the normalized eU, eTh, and K% maps in the study area. Radon emanation and spectrometric gamma measurements have been applied only in Al- Bayyarat area, where radioactive anomalous zone has been observed. The radioactive characteristics of the study area has been explained through studying and analyzing a profile of 30 Km long, where a plausible geo-radioactive model has been proposed for the uranium leaching and its transport. - Highlights: • Determine the radioactive characteristics of the study area. • Explain the radioactive anomaly observed in Al-Bayarat area. • Analysis of a profile of 30 Km and propose a plausible geo-radioactive model. • Discus the radioactive disequilibrium occurred in the study area

Diffusion of Na(I), Cs(I), Sr(II) and Eu(III) in smectite rich natural clay.

Science.gov (United States)

Kasar, Sharayu; Kumar, Sumit; Bajpai, R K; Tomar, B S

2016-01-01

Diffusion of Na(I), Cs(I), Sr(II) and Eu(III) in smectite rich natural clay, proposed as a backfill material in the Indian geological repository, was studied using the out-diffusion method. Radiotracers (22)Na, (137)Cs, (85)Sr and (154)Eu were used; the first three are carrier-free enabling experimental work at sub-micromolar metal ion concentration, and Eu(III) tracer (154)Eu was used at sub millimolar concentration. An out-diffusion methodology, wherein a thin planar source of radioactivity placed between two clay columns diffuses out, was used to obtain the apparent diffusion coefficient (Da) values. This methodology enabled determination of diffusion coefficient even for strongly sorbing (154)Eu. Da values for (22)Na, (137)Cs, (85)Sr and (154)Eu were 2.35 (±0.14) × 10(-11), 2.65 (±0.09) × 10(-12), 3.32 (±0.15) × 10(-11) and 1.23 (±0.15) × 10(-13) m(2) s(-1), respectively. Da values were found to be in fair agreement with literature data reported for similar mineralogical sediments. Sorption of radionuclides on the clay was also determined in the present study and differences in Da values were rationalized on the basis of sorption data. Distribution ratios (Kd) for Cs(I) and Eu(III) were higher than that for Sr(II), which in turn was higher than that for Na(I). Copyright © 2015 Elsevier Ltd. All rights reserved.

NMR studies of the helical antiferromagnetic compound EuCo2P2

Science.gov (United States)

Higa, N.; Ding, Q.-P.; Kubota, F.; Uehara, H.; Yogi, M.; Furukawa, Y.; Sangeetha, N. S.; Johnston, D. C.; Nakamura, A.; Hedo, M.; Nakama, T.; Ōnuki, Y.

2018-05-01

In EuCo2P2, 4f electron spins of Eu2+ ions order antiferromagnetically below a Néel temperature TN = 66.5 K . The magnetic structure below TN was reported to be helical with the helix axis along the c-axis from the neutron diffraction study. We report the results of 153Eu, 59Co and 31P nuclear magnetic resonance (NMR) measurements on EuCo2P2 using a single crystal and a powdered sample. In the antiferromagnetic (AFM) state, we succeeded in observing 153Eu, 59Co and 31P NMR spectra in zero magnetic field. The sharp 153Eu zero field NMR (ZF NMR) lines indicate homogeneous Eu ordered moment. The 59Co and 31P ZF NMR spectra showed an asymmetric spectral shape, indicating a distribution of the internal magnetic induction at each nuclear position. The AFM propagation vector k characterizing the helical AFM state can be determined from the internal magnetic induction at Co site. We have determined the model-independent value of the AFM propagation vector k distributed from (0, 0, 0.86)2π/c to (0, 0, 0.73)2π/c, where c is the lattice parameter.

Highly luminescent Eu{sup 3+}-doped benzenetricarboxylate based materials

Energy Technology Data Exchange (ETDEWEB)

Silva, Ivan G.N. [Departamento de Química Fundamental, Instituto de Química da Universidade de São Paulo, Av. Prof. Lineu Prestes 748, São Paulo 05508-900, SP (Brazil); Mustafa, Danilo, E-mail: dmustafa@iq.usp.br [Departamento de Química Fundamental, Instituto de Química da Universidade de São Paulo, Av. Prof. Lineu Prestes 748, São Paulo 05508-900, SP (Brazil); Andreoli, Bruno [Departamento de Química Fundamental, Instituto de Química da Universidade de São Paulo, Av. Prof. Lineu Prestes 748, São Paulo 05508-900, SP (Brazil); Felinto, Maria C.F.C. [Centro de Química do Meio Ambiente, Instituto de Pesquisas Energéticas e Nucleares, Av. Prof. Lineu Prestes 2242, São Paulo 05508-000, SP (Brazil); Malta, Oscar L. [Departamento de Química Fundamental, Universidade Federal de Pernambuco, Av. Prof. Moraes Rego, 1235, Recife 50670-90, PE (Brazil); Brito, Hermi F., E-mail: hefbrito@iq.usp.br [Departamento de Química Fundamental, Instituto de Química da Universidade de São Paulo, Av. Prof. Lineu Prestes 748, São Paulo 05508-900, SP (Brazil)

2016-02-15

[RE(TMA)] anhydrous complexes (RE{sup 3+}: Y, Gd and Lu) present high red emission intensity with a quantum efficiency (~45%) for the [Y(TMA):Eu{sup 3+}] complexes, due to the absence of non-radioactive decay pathways mediated by water molecules. The complexes were prepared in mild conditions. All the compounds are crystalline and thermostable up to 460 °C. Phosphorescence data of the complexes with Y, Gd and Lu show that the T{sub 1} state of the TMA{sup 3−} anion has energy higher than the {sup 5}D{sub 0} emitting level of the Eu{sup 3+} ion, indicating that the ligand can act as an intramolecular energy sensitizer. The photoluminescence properties of the doped materials were studied based on the excitation and emission spectra and luminescence decay curves. The experimental intensity parameters (Ω{sub λ}), lifetimes (τ), radiative (A{sub rad}) and non-radiative (A{sub nrad}) decay rates were determined and discussed. - Highlights: • Highly luminescent Europium doped anhydrous complexes. • Efficient monochromatic red light conversion molecular devices (LCMDs). • High emission quantum efficiencies.

Lattice dynamic studies from {sup 151}Eu-Moessbauer spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Katada, Motomi [Tokyo Metropolitan Univ., Hachioji (Japan). Faculty of Science

1997-03-01

New complexes {l_brace}(Eu(napy){sub 2}(H{sub 2}O){sub 3})(Fe(CN){sub 6})4H{sub 2}O{r_brace}{sub x}, bpy({l_brace}(Eu(bpy)(H{sub 2}O){sub 4})(Fe(CN){sub 6})1.5bpy4H{sub 2}O{r_brace}{sub x}) and ({l_brace}(Eu(phen){sub 2}(H{sub 2}O){sub 2})(Fe(CN){sub 6})2phen{r_brace}{sub x}) etc were synthesized using phenanthroline and bipyridine. Lattice dynamic behaviors of Eu and Fe atom in the complexes were investigated by Moessbauer spectroscopy. By {sup 151}Eu-Moessbauer spectrum and parameters of new complexes, bpy complex showed the largest quadrupole splitting value, indicating bad symmetry of Eu ligand in the environment. Molecular structure of napy, bpy and phen complex were shown. These complexes are consisted of Eu atom coordinated with ligand and water molecule, of which (Fe(CN){sub 6}){sup 3-} ion formed one dimentional polymer chain and naphthyridines formed stacking structure. New complexes were observed by {sup 57}Fe-Moessbauer spectroscopy, too. The quadrupole splitting values were very different each other, indicating change of symmetry of Fe atom in the environment and three valence low spin state of Fe in the complex. (S.Y.)

Chemical Interaction between U(VI) and Eu(III) ions on a Silica Surface

International Nuclear Information System (INIS)

Park, K. K.; Cha, W. S.; Cho, H. R.; Im, H. J.; Jung, E. C.

2010-01-01

Understanding the chemical behavior of actinide in groundwater flow is important for assessing the possibility of its migration with water flow in the radioactive waste disposal site. Precipitation/ dissolution in groundwater and adsorption/desorption onto a geological solid surface would determine its migration. The sorption in a geochemical system was expected to be a reaction on a naturally equilibrated surface. However, the construction of a waste disposal facility could disturb this equilibrium state, induce a new reaction environment and affect a nanoscopic surface reaction of actinide. Uranium is ubiquitous in the natural environment and a representative element in a nuclear fuel cycle and in a high level radioactive waste. In oxic environments, it is typically present as uranyl oxocation (UO 2 2+ ), which is easily adsorbed and thereby removed from a solution in the near neutral pH range. This adsorption would form a new surface condition to give an unexpected adsorption behavior for other actinide ions. Eu(III) frequently is used as a chemical analogue of Am(III) and Cm(III) in migration chemistry. The adsorption phenomena has been interpreted with the help of a SCM(surface complexation model). Some spectroscopic techniques such as EPR (Electron Paramagnetic Resonance), IR (InfraRed), EXAFS (Extended X-ray Absorption Fine Structure) and TRLFS (Time Resolved Laser Fluorescence Spectroscopy) have been used for the identification of a modeled adsorbing species. In the case of fluorescence elements, TRLFS has advantages over other techniques for its high sensitivity being proportional to laser source intensity and good selectivity depending on specific transition and lifetime. This technique can be applied to a species on a solid surface not absorbing light such as silica. U(VI) and Eu(III) have fluorescente properties reflecting their coordination structure. In this study, the interaction between U(VI) and Eu(III) on a silica surface was studied by a

Management of Spent Sealed Radioactive Sources in Bulgaria, Latvia, Lithuania, Romania and Slovakia

International Nuclear Information System (INIS)

Angus, M.; Cowley, M.; Moreton, T.; Wells, D.

2003-01-01

This study has been performed to consider the situation relating to the regulation and management of spent sealed radioactive sources (SSRS) in five of the Central and Eastern European (C and EE) countries that are being considered for admission to the EU, namely, Bulgaria, Latvia, Lithuania, Romania and Slovakia. Two previous studies have considered the situation in the current EU member states(1) and in the Czech Republic, Estonia, Hungary, Poland and Slovenia(2). The general aim of this study has been to acquire a thorough understanding of the management of SSRS in the five countries, in order to recommend improvements in management schemes and to establish whether the application of common disposal criteria would be advantageous. This report is structured in the following manner; following the Introduction (Section 1), there is a description of the current and proposed regulatory requirements in the EU, together with a summarised comparison of the regulatory systems in the five countries with EU standards (Section 2). Sections 3 to 7 are dedicated to each of the five countries. Each of these sections is similarly sub-divided to enable country-by-country and topic-by-topic comparison. In each of Sections 3 to 7 there is an overview, description of the sealed source inventory, regulations, current management practices, retrieval of unregistered (sometimes known as lost or orphan sources) SSRS, conclusions and a description of possible future technical assistance projects. In addition, there is a description in each of Sections 3 to 7 of the management of 226 Ra sources, which is receiving special attention in many countries (Table I provides a summary and comparison of the management of 226 Ra in the five countries).both country-specific and generic recommendations. A common concern in the five countries and many other countries, including the EU member states, is the problem of accidental inclusion of SSRS in consignments of scrap metal. The detection of

Luminescence properties of different Eu sites in LiMgPO4:Eu2+, Eu3+

International Nuclear Information System (INIS)

Baran, A; Mahlik, S; Grinberg, M; Cai, P; Kim, S I; Seo, H J

2014-01-01

The effect of temperature on the luminescence properties of LiMgPO 4 doped with Eu 3+ and Eu 2+ are presented. Depending on the excitation wavelength, luminescence spectra consist of two distinct broad emission bands peaking at 380 nm and 490 nm related to 4f 6 5d 1  → 4f 7 ( 8 S 7/2 ) luminescence of Eu 2+ and to europium-trapped exciton, respectively, and/or several sharp lines between the 580 nm and 710 nm region, ascribed to the 5 D 0  →  7 F J (J = 0, 1, 2, 3 and 4) transitions in Eu 3+ . To explain all the features of the Eu 2+ and Eu 3+ luminescence we discussed the existence of two different Eu sites substituting for Li + , with short and long distance compensation. The evident effect of increasing the intensity of the Eu 2+ luminescence with increasing temperature was observed. It was considered that the charge compensation mechanism for Eu 3+ and Li + as well as Eu 2+ replacing Li + in the LiMgPO 4 is a long distance compensation that allows for the existence of some of the europium ions either as Eu 3+ at low temperature or as Eu 2+ at high temperature. We concluded that Eu 2+ in the Li + site with long distance compensation yields only 4f 6 5d 1  → 4f 7 luminescence, whereas Eu 2+ in the Li + site with short distance compensation yields 4f 6 5d 1  → 4f 7 luminescence and europium-trapped exciton emission. (paper)

Study of band structure of some odd proton Eu isotopes

International Nuclear Information System (INIS)

Pandit, Rakesh K.; Rani Devi; Khosa, S.K.

2016-01-01

Much work has been done on the odd-Z, odd-A nuclei in the rare earth region because of occurrence of fascinating variety of structures of nuclei in this mass region. The Eu nuclei are in the transitional deformation region and it provides an opportunity to investigate theoretically the deformation changes with mass number and excitation energy besides to study the structure of their excited states. The 153 Eu nucleus has been well studied over the last two decades. The aim of the present work is to study in detail the band structure of some odd-Z nuclei

Energy Transfer between U(VI) and Eu(III) Ions Adsorbed on a Silica Surface

Energy Technology Data Exchange (ETDEWEB)

Park, K. K.; Cha, W.; Cho, H. R.; Im, H. J.; Jung, E. C.; Song, K. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2011-05-15

Understanding of chemical behavior of actinide in a groundwater flow is important for assessing the possibility of their migration with water flows in a radioactive waste disposal site. Uranium is ubiquitous in the environment and a major actinide in a nuclear fuel cycle. Americium and curium having isotopes of long half life are minor actinides in a spent fuel. If a minor actinide coexists with uranium in a groundwater flow, some interactions between them could be expected such as minor actinide adsorption onto uranium precipitates and competition with each other for an adsorption to a mineral surface site. Eu(III) ion is frequently used as a chemical analogue of Am(III) and Cm(III) ions in a migration chemistry. The luminescent spectra of U(VI) and Eu(III) ions show a dependency on the coordination symmetry around them, and the changes in intensity or bandwidth of spectra can yield valuable information on their local environment. The luminescent lifetime also strongly depends on the coordination environment, and its measurement is valuable in probe studies on micro-heterogeneous systems. The excited U(VI) ion can be quenched through Stern.Volmer process, hydrolysis of excited species, exciplex formation, electron transfer or energy transfer. In case of U(VI)-Eu(III) system, the interaction between two ions can be studied by measuring the effect of Eu(III) ion on the quenching of U(VI) ion luminescence. There are only a few investigations on the interaction between an excited U(VI) ion and a lanthanide(III) ion. In perchlorate solution, the energy transfer to Eu(III) ion occurred only in solutions of pH>3.87. In this study, the quenching of U(VI) luminescence by Eu(III) on a silica surface was measured. The results will be discussed on the basis of a chemical interaction between them

Interactions of Eu(III) with biogenic CaCO{sub 3} studied with TRLFS

Energy Technology Data Exchange (ETDEWEB)

Johnstone, Erik V.; Schmidt, Moritz [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Div. Surface Processes; Cherkouk, Andrea [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Div. Biogeochemistry

2016-07-01

The interactions of Eu(III) with CaCO{sub 3} arising from biogenic origin was investigated by Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLFS). Biologically-induced precipitation via ureolysis was studied with the bacteria Sporosarcina pasteurii in the presence of Eu(III). Biomineralization occurred forming mixed phases of vaterite and calcite after one day that transformed over two weeks to pure calcite. Eu(III) was quantitatively removed from solution during mineral formation. TRLFS results show that after one day the Eu{sup 3+} is located in the vaterite phase. After one week, the Eu{sup 3+} was found primarily in the vaterite, despite calcite now being the predominant mineral, and a transition species was also formed. In the calcite two incorporated Eu{sup 3+} species were present: one substitutes at the Ca{sup 2+} site in the crystal lattice and the other is speculated to be associated with the organicmineral matrix.

From EuCARD to EuCARD-2

CERN Multimedia

Chaudron, M

2013-01-01

The one word that best describes the spirit of the EuCARD ’13 event (see here) that took place from 10 to 14 June at CERN is "collaboration". The event brought together more than 180 accelerator specialists from all over the world to celebrate the conclusion of the EuCARD project and to kick off its successor, EuCARD-2.   EuCARD-2 brings a global view to particle accelerator research in order to address challenges for future generations of accelerators. The project officially began on 1 May 2013 and will run for four years. With a total budget of €23.4 million, including an €8 million EU contribution, it will build upon the success of EuCARD and push it into an even more innovative regime. EuCARD-2 aims to significantly enhance multidisciplinary R&D for European accelerators and will actively contribute to the development of a European Research Area in accelerator science. This will be accomplished by promoting complementary expertise, cross-d...

EU Udbudsretten

DEFF Research Database (Denmark)

Poulsen, Sune Troels; Jakobsen, Peter Stig; Kalsmose-Hjelmborg, Simon Evers

I bogen, som er en 2. udgave, analyseres EU udbudsdirektiv for offentlige myndigheder og EU's forsyningsvirksomhedsdirektiv. I analyserne inddrages EU-domstolens domme, afgørelser fra Kalgenævnet for Udbud, domme fra danske domstole samt litteratur på dansk og engelsk.......I bogen, som er en 2. udgave, analyseres EU udbudsdirektiv for offentlige myndigheder og EU's forsyningsvirksomhedsdirektiv. I analyserne inddrages EU-domstolens domme, afgørelser fra Kalgenævnet for Udbud, domme fra danske domstole samt litteratur på dansk og engelsk....

The effects of Eu-concentrations on the luminescent properties of SrF2:Eu nanophosphor

International Nuclear Information System (INIS)

Yagoub, M.Y.A.; Swart, H.C.; Noto, L.L.; O’Connel, J.H.; Lee, M.E.; Coetsee, E.

2014-01-01

SrF 2 :Eu nanophosphors were successfully synthesized by the hydrothermal method. The structure of the nanophosphors was investigated with x-ray diffraction. The average crystallite size calculated using the Scherrer equation was in the range of 7.0 nm. The photoluminescence of Eu doped as-prepared SrF 2 nanophosphors were studied using different excitation sources. The samples showed emission from both the Eu oxidation states, Eu 2+ and Eu 3+ . At low Eu concentrations the emission from Eu 2+ centered at 416 nm was more dominant. While the narrow band of Eu 3+ emission intensity increased with an increase in the Eu concentration. High resolution x-ray photoelectron spectroscopy results indicated that the Eu was indeed in both Eu 2+ and Eu 3+ valance states. The presence of Eu 2+ and Eu 3+ in the system largely enhanced the response of the Eu 3+ under ultraviolet excitation. The time of flight-secondary ion mass spectrometry results suggested that the energy transfer between two ions was likely to occur. The relative photoluminescence intensity of the Eu 2+ rapidly decreased with an increasing laser beam irradiating time. This result would make the current Eu 2+ doped SrF 2 samples unsuitable candidates for several applications, such as white light-emitting diodes and wavelength conversion films for silicon photovoltaic cells. - Highlights: • SrF 2 : Eu nanophosphors were successfully synthesised (hydrothermal technique). • PL and XPS results showed enhanced absorption response of Eu 3+ UV excitation. • Eu concentrations more than 5 mol% improved fluorescence emission. • TOF-SIMS results suggested that the energy transfer from Eu 2+ to Eu 3+ is dominant

Neutron Scattering from Heisenberg Ferromagnets EuO and EuS

DEFF Research Database (Denmark)

Als-Nielsen, Jens Aage; Dietrich, O. W.; Passell, L.

1976-01-01

Neutron scattering has been used to study the magnetic ordering process in the isotropic exchange coupled ferromagnets EuO and EuS. Quantities investigated include the critical coefficients B and F+ and the critical exponents β, ν, and γ describing respectively the temperature dependence...

A study of Eu incorporated ZnO thin films: An application of Al/ZnO:Eu/p-Si heterojunction diode

Energy Technology Data Exchange (ETDEWEB)

Turgut, G. [Department of Basic Sciences, Faculty of Science, Erzurum Technical University, Erzurum, 25240 (Turkey); Duman, S., E-mail: sduman@atauni.edu.tr [Department of Physics, Faculty of Science, Ataturk University, Erzurum, 25240 (Turkey); Sonmez, E. [Department of Physics, Faculty of K.K. Education, Ataturk University, Erzurum, 25240 (Turkey); Ozcelik, F.S. [Department of Physics, Faculty of Science, Ataturk University, Erzurum, 25240 (Turkey)

2016-04-15

Highlights: • Eu incorporated ZnO thin films were grown by sol–gel spin coating. • The influence of Eu contribution on features of ZnO was investigated. • Al/ZnO:Eu/p-Si heterojunction diodes were also fabricated. • The diode parameters were calculated from I–V measurements. - Abstract: In present work, the pure and europium (Eu) incorporated zinc oxide (ZnO) thin films were deposited with sol-gel spin coating by using zinc acetate dehydrate and Eu (III) chloride salts. The coated films were examined by means of XRD, AFM and UV/VIS spectrophotometer. The ZnO hexagonal wurtzite nanoparticles with (002) preferential direction were observed for all films. The values of crystallite size, micro-strain and surface roughness continuously increased from 21 nm, 1.10 × 10{sup −3} and 2.43 nm to the values of 35.56 nm, 1.98 × 10{sup −3} and 28.99 nm with Eu doping, respectively. The optical band gap value of the pure ZnO initially increased from 3.296 eV to 3.328 eV with Eu doping up to 2 at.% doping level, then it started to decrease with more Eu content. The electrical features of Al/n-ZnO:Eu/p-Si heterojunction diodes were inquired by current-voltage (I–V) measurements at the room temperature.

Radioactive Waste Management - Community Policy and Research Initiatives. The sixth international conference on the management and disposal of radioactive waste - Euradwaste '04

Energy Technology Data Exchange (ETDEWEB)

Forsstroem, Hans [Research Directorate Energy, Nuclear Fission and Radiation Protection, European Commission, MO-75 5/37, 200 avenue de la Loi, B-1049 Brussels (Belgium); Ruiz, P Fernandez [DG Research, Energy, Consejo de Seguridad Nuclear, CSN, C/ Justo Dorado, 11, E-28040 Madrid (Spain)

2004-07-01

The sixth international conference on the management and disposal of radioactive waste organized be European Commission, held on 29-31 March 2004 in Luxembourg aimed to cover the following objectives: - To present EC policy in waste management, in particular the proposed 'Directive on the Management of Spent Nuclear Fuel and Radioactive Waste' and to discuss relating issues such as the effect on national programmes, site selection, EU added value, the case for EU safety standards, and various socio-political aspects; - To highlight the main results of the Fifth Framework Programme (FP5) of EURATOM for 'Nuclear Energy, Fission Research and Training Activities' in the field of waste in spent fuel management and disposal, and partitioning and transmutation; - To present examples of activities under FP5 and to discuss further research European integration through FP6. The program was divided into two main groups: 1. 'Community Policy and Socio-Political Aspects' which included sessions on community policy initiatives, disposal option, common safety standards and public involvement and acceptance; 2. 'Community Research Activities - FP5' which included sessions on partitioning and transmutation, geological disposal and research networking. There were 29 oral presentations and 36 poster presentations which, for the latter, allowed detailed presentations of the results of the EU-funded research projects. The conference was attended by some 240 participants from 27 countries.

Participation of CASSIOPEE in the EU technical assistance programmes to Eastern countries

International Nuclear Information System (INIS)

Beceiro, A.R.; Vico, E.; Deconinck, J.M.

2000-01-01

CASSIOPEE, established in 1993, is a European Economic Interest Group formed by ANDRA (France), COVRA (the Netherlands), DBE (Germany), ENRESA (Spain), NIREX (United Kingdom) and ONDRAF/NIRAS (Belgium). CASSIOPEE provides assistance to the Central and Eastern European countries and to the New Independent States through the EU Programmes in two different ways: developing radioactive waste management strategies and advising on the implementation of adequate engineering resources.The advisory role of CASSIOPEE in the EU assistance programmes and main projects defined and/or developed by CASSIOPEE are presented. The activities in the area of low and intermediate level waste related to safety assessment of existing repositories, site selection, waste acceptance criteria ect. are given

Gaps in EU Foreign Policy

DEFF Research Database (Denmark)

Larsen, Henrik

of Capability-Expectations Gap in the study of European foreign policy. Through examples from relevant literature, Larsen not only demonstrates how this concept sets up standards for the EU as a foreign policy actor (that are not met by most other international actors) but also shows how this curtails analysis...... of EU foreign policy. The author goes on to discuss how the widespread use of the concept of ‘gap' affects the way in which EU foreign policy has been studied; and that it always produces the same result: the EU is an unfulfilled actor outside the realm of “normal” actors in IR. This volume offers new...... perspectives on European foreign policy research and advice and serves as an invaluable resource for students of EU foreign policy and, more broadly, European Studies....

Economic impacts of EU climate policy until 2020; EU:n ilmastopolitiikan talousvaikutukset vuoteen 2020

Energy Technology Data Exchange (ETDEWEB)

Rantala, O. E-mail: olavi.rantala@etla.fi

2012-07-01

The study evaluates the impacts of EU climate policy on the emission allowance price, electricity prices, the competitiveness of industry and macroeconomic developments in the third EU emission trading period 2013-2020. The economic impacts of climate policy on Finland are compared to the impacts on the entire EU area. It turns out that due to its cold climate and heating energy demand, higher export intensity of the economy and higher energy intensity of the industry Finland pays a higher price for EU climate policy in terms of output and employment losses than the EU on average. The study examines the macroeconomic effects of climate policy also in the more distant future, assuming that climate policy is tightened further in the 2020s. Climate policy implemented by emission trading means that the long-term economic growth in the EU area depends essentially on emission-free electricity production, and no longer on other growth factors, such as the labour supply and productivity growth. (orig.)

Radiological Risk Assessment and Survey of Radioactive Contamination for Foodstuffs

International Nuclear Information System (INIS)

Lee, W.R.; Lee, C.W.; Choi, K.S.

2007-11-01

After the Chernobyl nuclear accident in 1986, a radiological dose assessment and a survey of a radioactive contamination for foodstuffs have been investigated by many countries such as EU, Japan, USA. In the case of Japan which is similar to our country for the imported regions of foodstuffs, there were some instances of the excess for regulation on the maximum permitted levels of radioactive contamination among some imported foodstuffs. Concerns about the radioactive contamination of foodstuffs are increased because of the recently special situation (Nuclear test of North Korea). The purpose of this study is a radiological dose assessment and a survey of a radioactive contamination for foodstuffs in order to reduce the probability of intake of contaminated foodstuffs. Analytical results of the collected samples are below MDA. In this project, the model of radiological dose assessment via the food chain was also developed and radiological dose assessment was conducted based on surveys results of a radioactive contamination for foodstuffs in the Korean open markets since 2002. The results of radiological dose assessment are far below international reference level. It shows that public radiation exposure via food chain is well controlled within the international guide level. However, the radioactive contamination research of imported foodstuffs should be continuous considering the special situation(nuclear test of North Korea). These results are used to manage the radioactive contamination of the imported foodstuffs and also amend the regulation on the maximum permitted levels of radioactive contamination of foodstuffs

Radioactive Waste Management - Community Policy and Research Initiatives. The sixth international conference on the management and disposal of radioactive waste - Euradwaste '04

Energy Technology Data Exchange (ETDEWEB)

Forsstroem, Hans [Research Directorate Energy, Nuclear Fission and Radiation Protection, European Commission, MO-75 5/37, 200 avenue de la Loi, B-1049 Brussels (Belgium); Ruiz, P. Fernandez (ed.) [DG Research, Energy, Consejo de Seguridad Nuclear, CSN, C/ Justo Dorado, 11, E-28040 Madrid (Spain)

2004-07-01

The sixth international conference on the management and disposal of radioactive waste organized be European Commission, held on 29-31 March 2004 in Luxembourg aimed to cover the following objectives: - To present EC policy in waste management, in particular the proposed 'Directive on the Management of Spent Nuclear Fuel and Radioactive Waste' and to discuss relating issues such as the effect on national programmes, site selection, EU added value, the case for EU safety standards, and various socio-political aspects; - To highlight the main results of the Fifth Framework Programme (FP5) of EURATOM for 'Nuclear Energy, Fission Research and Training Activities' in the field of waste in spent fuel management and disposal, and partitioning and transmutation; - To present examples of activities under FP5 and to discuss further research European integration through FP6. The program was divided into two main groups: 1. 'Community Policy and Socio-Political Aspects' which included sessions on community policy initiatives, disposal option, common safety standards and public involvement and acceptance; 2. 'Community Research Activities - FP5' which included sessions on partitioning and transmutation, geological disposal and research networking. There were 29 oral presentations and 36 poster presentations which, for the latter, allowed detailed presentations of the results of the EU-funded research projects. The conference was attended by some 240 participants from 27 countries.

Study of the nuclear structure of 155Eu

International Nuclear Information System (INIS)

Genezini, Frederico Antonio

2004-01-01

The 155 Eu nuclide was investigated by the directional angular correlation technique following the β decay of 155 Sm. The angular correlation measurements were carried out using a setup with 4 Ge detectors and a multi parametric data acquisition system. To perform the data analysis a new methodology was developed . The multipole mixing ratios of twenty sixty γ- transitions were determined. Seven of them agreed with the results of earlier angular correlation studies and nineteen obtained for the first time confirmed the multipolarity suggested in earlier electron capture studies. Besides, the spin of the level at 1106.83 keV as well as the parity of the level at 1301.41 keV have also been suggested. The nuclear structure of 155 Eu was discussed successfully in terms of the single particle model using a deformed Woods-Saxon potential plus residual pairing interaction permitting the description of the rotational quasi-proton band heads. (author)

The effects of Eu-concentrations on the luminescent properties of SrF{sub 2}:Eu nanophosphor

Energy Technology Data Exchange (ETDEWEB)

Yagoub, M.Y.A.; Swart, H.C.; Noto, L.L. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein ZA9300 (South Africa); O’Connel, J.H.; Lee, M.E. [Department of Physics and Centre for HRTEM, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth ZA6031 (South Africa); Coetsee, E., E-mail: CoetseeE@ufs.ac.za [Department of Physics, University of the Free State, PO Box 339, Bloemfontein ZA9300 (South Africa)

2014-12-15

SrF{sub 2}:Eu nanophosphors were successfully synthesized by the hydrothermal method. The structure of the nanophosphors was investigated with x-ray diffraction. The average crystallite size calculated using the Scherrer equation was in the range of 7.0 nm. The photoluminescence of Eu doped as-prepared SrF{sub 2} nanophosphors were studied using different excitation sources. The samples showed emission from both the Eu oxidation states, Eu{sup 2+} and Eu{sup 3+}. At low Eu concentrations the emission from Eu{sup 2+} centered at 416 nm was more dominant. While the narrow band of Eu{sup 3+} emission intensity increased with an increase in the Eu concentration. High resolution x-ray photoelectron spectroscopy results indicated that the Eu was indeed in both Eu{sup 2+} and Eu{sup 3+} valance states. The presence of Eu{sup 2+} and Eu{sup 3+} in the system largely enhanced the response of the Eu{sup 3+} under ultraviolet excitation. The time of flight-secondary ion mass spectrometry results suggested that the energy transfer between two ions was likely to occur. The relative photoluminescence intensity of the Eu{sup 2+} rapidly decreased with an increasing laser beam irradiating time. This result would make the current Eu{sup 2+} doped SrF{sub 2} samples unsuitable candidates for several applications, such as white light-emitting diodes and wavelength conversion films for silicon photovoltaic cells. - Highlights: • SrF{sub 2}: Eu nanophosphors were successfully synthesised (hydrothermal technique). • PL and XPS results showed enhanced absorption response of Eu{sup 3+} UV excitation. • Eu concentrations more than 5 mol% improved fluorescence emission. • TOF-SIMS results suggested that the energy transfer from Eu{sup 2+} to Eu{sup 3+} is dominant.

EU Industrial Policy

DEFF Research Database (Denmark)

Pellegrin, Julie; Giorgetti, Maria Letizia; Jensen, Camilla

Following disregard in the 1980s, industrial policy has recently attracted policy attention at EU level. The objective of this study provided by Policy Department A at the request of the ITRE Committee, is to establish the state of the art of a coordinated and integrated EU industrial policy...

EuO and Gd-doped EuO thin films. Epitaxial growth and properties

International Nuclear Information System (INIS)

Sutarto, Ronny

2009-01-01

Europium oxide (EuO) based materials exhibit a wealth of spectacular phenomena, including half-metallic ferromagnetism, metal-insulator transition, colossal magneto-resistance, large magneto-optical Kerr effect, tunable ferromagnetic ordering temperatures, and large and long-lived photo-induced conductivity. These extraordinary properties make EuO an ideal candidate for implementation in device applications, in particular, for spintronics. Most of the work in the past has been carried out on bulk EuO, but for device applications it is preferred to have the EuO in thin lm form. A urry of studies have therefore emerged in the last decade in order to explore a wide variety of preparation routes and to investigate the properties of the resulting EuO thin films. A recent highlight is the demonstration that doped EuO films can be fabricated on Si and GaN, thereby exhibiting the expected spin-polarized transport effects. Nevertheless, it is still far from a trivial task to prepare EuO thin films with well de ned properties. For bulk EuO, it is already known that stoichiometry is the key issue, and that the presence of small amounts of defects or impurities quickly lead to very large deviations of the material properties. In fact, to make bulk EuO to be stoichiometric one needs temperatures as high as 1800 C. It is obvious that such high temperatures are not compatible with device engineering processes. The preparation of thin films must therefore involve much lower temperatures, preferably not higher than 400-500 C. The consequences are very dear. It turned out that many of the recent studies on EuO thin films are suffering from sample quality problems, due to the presence of, e.g., trivalent Eu species (Eu 3 O 4 , Eu 2 O 3 ), oxygen vacancies, or even Eu metal clusters. Controlled doping of the EuO with trivalent rare-earth ions is also not trivial, since most often even the actual doping concentrations were not known. In fact, one could also question in this respect the

EuO and Gd-doped EuO thin films. Epitaxial growth and properties

Energy Technology Data Exchange (ETDEWEB)

Sutarto, Ronny

2009-07-06

Europium oxide (EuO) based materials exhibit a wealth of spectacular phenomena, including half-metallic ferromagnetism, metal-insulator transition, colossal magneto-resistance, large magneto-optical Kerr effect, tunable ferromagnetic ordering temperatures, and large and long-lived photo-induced conductivity. These extraordinary properties make EuO an ideal candidate for implementation in device applications, in particular, for spintronics. Most of the work in the past has been carried out on bulk EuO, but for device applications it is preferred to have the EuO in thin lm form. A urry of studies have therefore emerged in the last decade in order to explore a wide variety of preparation routes and to investigate the properties of the resulting EuO thin films. A recent highlight is the demonstration that doped EuO films can be fabricated on Si and GaN, thereby exhibiting the expected spin-polarized transport effects. Nevertheless, it is still far from a trivial task to prepare EuO thin films with well de ned properties. For bulk EuO, it is already known that stoichiometry is the key issue, and that the presence of small amounts of defects or impurities quickly lead to very large deviations of the material properties. In fact, to make bulk EuO to be stoichiometric one needs temperatures as high as 1800 C. It is obvious that such high temperatures are not compatible with device engineering processes. The preparation of thin films must therefore involve much lower temperatures, preferably not higher than 400-500 C. The consequences are very dear. It turned out that many of the recent studies on EuO thin films are suffering from sample quality problems, due to the presence of, e.g., trivalent Eu species (Eu{sub 3}O{sub 4}, Eu{sub 2}O{sub 3}), oxygen vacancies, or even Eu metal clusters. Controlled doping of the EuO with trivalent rare-earth ions is also not trivial, since most often even the actual doping concentrations were not known. In fact, one could also question in

The EU agencies’ role in policy diffusion beyond the EU

DEFF Research Database (Denmark)

Chatzopoulou, Sevasti

and health quality within the risk assessment. This paper shows that the EU agencies develop various entrepreneurial methods and that they actively promote policy diffusion beyond the EU through socialisation and learning within international arrangements and collaborations. However, variations......The extensive literature on the EU agencies has mainly focused on their role in the harmonisation and expansion of regulatory standards within the EU. This paper joins this literature and investigates the role of EU agencies in policy diffusion beyond the EU borders. To operationalise this...

Effects of the material composition in the TL curves of alkaline halides with Eu{sup 2+} exposed to {beta} radiation; Efectos de la composicion del material en las curvas de TL de halogenuros alcalinos con Eu{sup 2+} expuestos a radiacion {beta}

Energy Technology Data Exchange (ETDEWEB)

Perez S, R.; Piters, T.; Aceves, R.; Rodriguez M, R. [Dpto. de Investigacion en Fisica, Universidad de Sonora, 83190 Hermosillo, Sonora (Mexico)

2006-07-01

The solid state dosemeters plays a very important paper in the growing use of the ionizing radiation. When being increased the use of the radioactive isotopes in the medicine and in the industry, the necessity to have materials but adapted in each case it has increased. To synthesize such materials, it is necessary to enlarge the knowledge on the paper that its play the physical characteristics of the crystals such as the crystalline structure, the lattice constant, imbibed nano structures, dislocations, ions size, electronic states of the ions, etc., on the effects of the ionizing radiation. In the past its have been carried out many studies approaching these problems in some materials, but we consider that its are insufficient before the challenges of the applications. To contribute to the understanding of these effects, we present a study focused to alkaline halide crystals impurified with Eu{sup 2+} ions, making an analysis on the paper that its play a) the ions concentration of Eu{sup 2+} in KBr: Eu{sup 2+}, b) the different sites of trapping of electrons and holes in KBr: Eu{sup 2+}, KCl: Eu{sup 2+}, RbBr:Eu{sup 2+}, RbCl: Eu{sup 2+} and c) the composition of the crystalline solid solutions KCl{sub x}Br{sub 1-X}: Eu{sup 2+} and RbCI{sub x}KBr{sub 1-x}: Eu{sup 2+} on the thermoluminescence curve when these materials are exposed to small dose of {beta} irradiation. The increase in the concentration of Eu{sup 2+} ions produces a smaller relative intensity of the emissions of high temperature for a given dose and it is found that in a RbCl{sub x}KBr{sub 1-x}: Eu{sup 2+} with the greater/smaller concentration of Cl{sup -} ions, the temperature of the characteristic emission is near to the 453/373 K. The composition x of halogenous ions and not the one of alkaline in the crystalline solid solution dominates the landslide of the temperature of the emission. (Author)

Energy transfer between the Eu2+ dipole and aggregate centers in CsBr:Eu crystals

International Nuclear Information System (INIS)

Zorenko, Yu.; Turchak, R.; Voznjak, T.

2007-01-01

The energy transfer between the Eu 2+ -V Cs dipole centers and presumable CsEuBr 3 aggregate centers has been studied in CsBr:Eu crystals by means of investigation of their time-resolved emission spectra and luminescence decay kinetics at 300 K

First-principles study on electronic structures and magnetic properties of Eu-doped phosphorene

Science.gov (United States)

Luan, Zhaohui; Zhao, Lei; Chang, Hao; Sun, Dan; Tan, Changlong; Huang, Yuewu

2017-11-01

The structural, electronic and magnetic properties of Eu-doped phosphorene with different doping concentrations were investigated by first-principles calculations for the first time. The calculations show that Eu-doped phosphorene systems are stable and have the large magnetic moments of more than 6 μB by 2.7, 6.25 and 12.5 at.% doping concentrations. The major contribution to the magnetic moment stems from the 4f states of Eu-doped atom. Meanwhile, Eu-doped atom introduces the impurity bands which can be changed by different doping concentrations. In order to determine the magnetic interaction, the different configurations for two Eu atoms doping in 3 × 3 × 1 phosphorene supercell were studied, which reveals that all of the configurations tend to form ferromagnetic. These results can provide references for inducing large magnetism of two-dimensional phosphorene, which are valuable for their applications in spintronic devices and novel semiconductor materials.

Determination of the radioactive nature of a waste. Situation and practices in various EU member states. Final report + synthesis

International Nuclear Information System (INIS)

Strasser, F.; Huclier, S.; Mokili, M.; Chardon, P.; Landesman, C.

2005-12-01

Security in waste treatment sites is apprehended in different ways in the four states of the European Union that have been compared for the purpose of this study. France and Germany are the field of two opposed situations: in France all waste treatment sites are equipped with radioactivity detection portals, whereas Germany considers that waste containing radioactive traces is managed in a specific way and cannot infiltrated normal waste flows due to extensive use of selective waste sorting. Radioactivity control for the waste management sites is no matter of discussion in Germany. The procedures to follow for waste containing radioactive traces is elaborated at the level of the Laender. In Belgium and in the Netherlands, the situations are somewhere in between these two extreme approaches. In the Wallonie Region of Belgium, a regulation in force since February 2003 requires landfills operators to equip their sites with radioactivity detector systems.. In Flanders three incinerators are equipped with detection systems on a voluntary base, in order to protect their installations and reassure the surrounding population. One of the three incinerators is involved in a pilot study meant to come up with solutions for waste site protection and prevention from radioactive contamination. In the Netherlands, a regulation from January 2003 requires scrap metal dealers to perform a control on the metal waste they collect or receive at their site. (authors)

QSPR study of solvent quenching of the 5D 0 → 7F 2 emission of Eu(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate) 3

Science.gov (United States)

Mercader, Andrew G.; Duchowicz, Pablo R.; Fernández, Francisco M.; Castro, Eduardo A.; Wolcan, Ezequiel

2008-09-01

We performed a predictive analysis, based on quantitative structure-property relationships (QSPR), of the luminescence lifetime ( τ) of Eu(fod) 3 in different solvents. The Eu(fod) 3 luminescent properties have been helpful as replacements for radioactivity, alternatives to standard fluorescent dyes and donors in energy transfer experiments, and are gaining expanding applications in wide variety of bioanalytical assays. Our best QSPR linear model constructed from 23 molecular structures combines four molecular descriptors, selected from more than a thousand geometrical, topological, quantum-mechanical and electronic types of descriptors.

Fifth Situation Report - Radioactive Waste Management in the Enlarged European Union

International Nuclear Information System (INIS)

Webster, S.

2003-02-01

The present report is the fifth in the series of reports on radioactive waste management in the European Union (EU). It presents, in the form of tables, the status in current EU Member States and in Candidate Countries of Central and Eastern Europe at the end of the year 2000. The fourth situation report was published in January 1999 and contained an in-depth evaluation of the situation and prospects for radioactive waste management in the Community, including such topics as waste generation, financing, transport, research and social issues. The report contains a comprehensive set of tables of waste generation, storage, disposal and predicted trends in the various waste categories, based on the status at the end of 1994. In comparison, the present report is an interim re-evaluation only and concentrates on waste quantities at the end of the year 2000, though it also presents a summary of national strategies and other pertinent information. (author)

Effects of the material composition in the TL curves of alkaline halides with Eu2+ exposed to β radiation

International Nuclear Information System (INIS)

Perez S, R.; Piters, T.; Aceves, R.; Rodriguez M, R.

2006-01-01

The solid state dosemeters plays a very important paper in the growing use of the ionizing radiation. When being increased the use of the radioactive isotopes in the medicine and in the industry, the necessity to have materials but adapted in each case it has increased. To synthesize such materials, it is necessary to enlarge the knowledge on the paper that its play the physical characteristics of the crystals such as the crystalline structure, the lattice constant, imbibed nano structures, dislocations, ions size, electronic states of the ions, etc., on the effects of the ionizing radiation. In the past its have been carried out many studies approaching these problems in some materials, but we consider that its are insufficient before the challenges of the applications. To contribute to the understanding of these effects, we present a study focused to alkaline halide crystals impurified with Eu 2+ ions, making an analysis on the paper that its play a) the ions concentration of Eu 2+ in KBr: Eu 2+ , b) the different sites of trapping of electrons and holes in KBr: Eu 2+ , KCl: Eu 2+ , RbBr:Eu 2+ , RbCl: Eu 2+ and c) the composition of the crystalline solid solutions KCl x Br 1-X : Eu 2+ and RbCI x KBr 1-x : Eu 2+ on the thermoluminescence curve when these materials are exposed to small dose of β irradiation. The increase in the concentration of Eu 2+ ions produces a smaller relative intensity of the emissions of high temperature for a given dose and it is found that in a RbCl x KBr 1-x : Eu 2+ with the greater/smaller concentration of Cl - ions, the temperature of the characteristic emission is near to the 453/373 K. The composition x of halogenous ions and not the one of alkaline in the crystalline solid solution dominates the landslide of the temperature of the emission. (Author)

Technology transfer on long-term radioactive waste management - a feasible option for small nuclear programmes?

International Nuclear Information System (INIS)

Mele, I.; Mathieson, J.

2007-01-01

The EU project CATT - Co-operation and technology transfer on long-term radioactive waste management for Member States with small nuclear programmes investigated the feasibility of countries with small nuclear programmes implementing long-term radioactive waste management solutions within their national borders, through collaboration on technology transfer with those countries with advanced disposal concepts. The main project objective was to analyse the existing capabilities of technology owning Member States and the corresponding requirements of potential technology acquiring Member States and, based on the findings, to develop a number of possible collaboration models and scenarios that could be used in a technology transfer scheme. The project CATT was performed as a specific support action under the EU sixth framework programme and it brought together waste management organisations from six EU Member States: UK, Bulgaria, Germany, Lithuania, Slovenia and Sweden. In addition, the EC Joint Research Centre from the Netherlands also participated as a full partner. The paper summarises the analyses performed and the results obtained within the project. (author)

Intra-EU Direct Investment and Enlargement

Directory of Open Access Journals (Sweden)

Festa Andrea

2015-03-01

Full Text Available This paper examines the determinants of the intra-EU direct investment (IDI into the New Member States (NMS using a panel dataset of bilateral capital flows for the period 1993-2013. It is found out by using a simple gravity model that EU membership is the most important determinant. Unlike previous studies including non-EU countries, the distance is insignificant, which is caused by proximity of these countries to one another. A separate analysis focused on subgroups of accession countries gives some evidence that even when size of their economy, distance, institutional quality and EU accession are taken into account, Central European countries receive more IDI than the Baltic and the Balkan states. On the contrary to that, the analysis restricted to the Balkan countries which have joined the EU shows the inexistence of a negative Balkans effect in attracting foreign investment. This finding is relevant because previous studies demonstrate a persistent negative Balkans effect for non-EU Balkan countries and suggests a crucial impact of the EU accession in determining the intra-EU capital flows.

Study of electron vibrational interaction parameters in chlorophosphate activated with Eu2+ ion

International Nuclear Information System (INIS)

Bhoyar, Priyanka D.; Dhoble, S.J.

2014-01-01

We present the results of theoretical study of photoluminescence of Eu 2+ ions activated chlorophosphate M 5.17 (PO 4 ) 3 Cl 5 :Eu 2+ with M = Ca, Sr and Ba estimating electron-vibrational interaction (EVI) parameters such as Huang–Rhys factor, effective phonon energy, Stokes shift and zero phonon line position. Validity of the calculated result was established by modeling the emission line which was found to be in good agreement with the measured photoluminescence spectrum of Eu 2+ doped chorophosphates. - Highlights: • The EVI parameters such as Huang–Rhys factor, effective phonon energy and zero phonon line position were estimated. • Eu 2+ ion emission observed in chlorophosphate. • Material analyzed in this work have intermediate Huang–Rhys factor, high Stokes shift and low effective phonon energy

Study of the nuclear structure of {sup 155}Eu; Estudo da estrutura nuclear do {sup 155}Eu

Energy Technology Data Exchange (ETDEWEB)

Genezini, Frederico Antonio

2004-07-01

The {sup 155}Eu nuclide was investigated by the directional angular correlation technique following the {beta} decay of {sup 155}Sm. The angular correlation measurements were carried out using a setup with 4 Ge detectors and a multi parametric data acquisition system. To perform the data analysis a new methodology was developed . The multipole mixing ratios of twenty sixty {gamma}- transitions were determined. Seven of them agreed with the results of earlier angular correlation studies and nineteen obtained for the first time confirmed the multipolarity suggested in earlier electron capture studies. Besides, the spin of the level at 1106.83 keV as well as the parity of the level at 1301.41 keV have also been suggested. The nuclear structure of {sup 155}Eu was discussed successfully in terms of the single particle model using a deformed Woods-Saxon potential plus residual pairing interaction permitting the description of the rotational quasi-proton band heads. (author)

Electrochemical reduction study of Eu3+ in perchlorid media by cyclic chronopotentiometry

International Nuclear Information System (INIS)

Brotto, M.E.; Rabockai, T.

1990-01-01

The electrochemical reduction of Eu 3+ in perchloric media was studied by means of cyclic chronopotentiometry. It is shown that the charge transfer reaction is followed by a chemical reaction in which Eu 2+ ion reoxydized to the trivalent ion (catalytic reaction scheme). The mean value of the homogeneous reaction rate constant is (2,43 +- 0,24) x 10 -2 dm 3 .mol -1 . (author)

Transportforskning i EU

DEFF Research Database (Denmark)

Leleur, Steen

1996-01-01

Artiklen giver en gennemgang af aktuelle EU transportforskningsemner samt nogle synspunkter og erfaringer baseret på deltagelse i EU forskningsprojekter.......Artiklen giver en gennemgang af aktuelle EU transportforskningsemner samt nogle synspunkter og erfaringer baseret på deltagelse i EU forskningsprojekter....

Growth, optical and EPR studies of {sup 151}Eu{sup 2+}:YAG single crystals

Energy Technology Data Exchange (ETDEWEB)

Petrosyan, A.G., E-mail: pet@ipr.sci.am [Institute for Physical Research, National Academy of Sciences, Ashtarak, 0203 (Armenia); Asatryan, H.R. [Ioffe Physical-Technical Institute, Politekhnicheskaya ul. 26, St. Petersburg, 194021 (Russian Federation); Hovhannesyan, K.L.; Derdzyan, M.V. [Institute for Physical Research, National Academy of Sciences, Ashtarak, 0203 (Armenia); Feofilov, S.P. [Ioffe Physical-Technical Institute, Politekhnicheskaya ul. 26, St. Petersburg, 194021 (Russian Federation); Eganyan, A.V.; Sargsyan, R.S. [Institute for Physical Research, National Academy of Sciences, Ashtarak, 0203 (Armenia)

2017-01-01

Single crystals of {sup 151}Eu:YAG were grown by the vertical Bridgman method using Eu{sub 2}O{sub 3} with isotopic enrichment of {sup 151}Eu of 97.5%. Additional Hf{sup 4+}or Si{sup 4+} ions were introduced to favor a high concentrations of Eu{sup 2+}. As compared to Eu:YAG with natural isotope composition, the EPR spectra of YAG doped with {sup 151}Eu isotope show a reduced number of hyperfine structure components and a well-resolved structure of a bigger number of electronic transitions. Optical properties of obtained crystals and the effects of heat treatments under oxidizing and reducing conditions are reported. Based on the analysis of Eu{sup 3+} distribution in oxidized Eu,Hf:YAG, in comparison to that in Eu:YAG, the concentration of Eu{sup 2+} in as-grown Eu,Hf:YAG is determined. - Highlights: • YAG:Eu,Hf single crystals containing only {sup 151}Eu isotopes were prepared. • isotopic enriched crystals gave a well-resolved EPR hyperfine structure of Eu{sup 2+} centers. • the redox ratio was followed through the Eu{sup 2+} associated absorption band at 250 nm. • the band intensities at 378 nm correlate with the Eu{sup 2+} concentration.

Distribution of residual long-lived radioactivity in the inner concrete walls of a compact medical cyclotron vault room.

Science.gov (United States)

Fujibuchi, Toshioh; Nohtomi, Akihiro; Baba, Shingo; Sasaki, Masayuki; Komiya, Isao; Umedzu, Yoshiyuki; Honda, Hiroshi

2015-01-01

Compact medical cyclotrons have been set up to generate the nuclides necessary for positron emission tomography. In accelerator facilities, neutrons activate the concrete used to construct the vault room; this activation increases with the use of an accelerator. The activation causes a substantial radioactive waste management problem when facilities are decommissioned. In the present study, several concrete cores from the walls, ceiling and floor of a compact medical cyclotron vault room were samples 2 years after the termination of operations, and the radioactivity concentrations of radionuclides were estimated. Cylindrical concrete cores 5 cm in diameter and 10 cm in length were bored from the concrete wall, ceiling and floor. Core boring was performed at 18 points. The gamma-ray spectrum of each sample was measured using a high-purity germanium detector. The degree of activation of the concrete in the cyclotron vault room was analyzed, and the range and tendency toward activation in the vault room were examined. (60)Co and (152)Eu were identified by gamma-ray spectrometry of the concrete samples. (152)Eu and (60)Co are produced principally from the stable isotopes of europium and cobalt by neutron capture reactions. The radioactivity concentration did not vary much between the surface of the concrete and at a depth of 10 cm. Although the radioactivity concentration near the target was higher than the clearance level for radioactive waste indicated in IAEA RS-G-1.7, the mean radioactivity concentration in the walls and floor was lower than the clearance level. The radioactivity concentration of the inner concrete wall of the medical cyclotron vault room was not uniform. The areas exceeding the clearance level were in the vicinity of the target, but most of the building did not exceed the clearance levels.

The Normality of EU Sport Policy Studies: Disciplinary Locus in Political Science, Sport Science or Elsewhere?

Directory of Open Access Journals (Sweden)

Jacob Kornbeck

2014-05-01

Full Text Available The Normality of EU Sport Policy Studies: Disciplinary Locus in Political Science, Sport Science or Elsewhere? Mainstream European integration research has shown that research on the EU tends to follow the conjunctures of European integration itself. This realisation has led to some debate on which branch of political science – international relations or government – or indeed other academic disciplines is/are the most appropriate locus for such research. The paper takes these debates one step further by looking at the occurrence of ‘EU & sport’ studies within the wider field of EU studies. The main material used comes from the ECLAS database. Findings lead to a discussion of whether ‘EU & sport’ studies should rather be for EU specialists or for sport specialists and a plea for disciplinary normalisation whereby sport science would need to get more directly involved (without necessarily overwriting political science. Some ideas are added regarding the need for a mapping of Central & Eastern European scholarship. Normalita politických studií EU v oblasti sportu: místo v oborech politologie, sportovních vědách či jinde? Hlavní integrační proudy v evropském výzkumu dokumentují, že výzkum v EU má tendenci zkoumat evropskou integraci jako takovou. Toto poznání vedlo k diskusi, v kterém oboru politologie – mezinárodní vztahy či vláda – nebo i v jiných akademických disciplínách je nejvhodnější místo pro takový výzkum. Stať se pokouší posunout tyto diskuse o krok dále tím, že studie o „EU a sportu“ se posuzují v širším záběru EU studií. Hlavní informační zdroje pocházejí z databáze ECLAS. Naše zjištění vedou k diskusi o problematice „EU a sportu“ v tom smyslu, zda by tyto studie měly být spíše určeny odborníkům EU, nebo sportovním specialistům. Důležitá je otázka disciplinární začlenění této problematiky, s širším zapojením sportovních věd (aniž by

152Eu decay

International Nuclear Information System (INIS)

Artamonova, K.P.; Vinogradov, V.M.; Grigor'ev, E.P.; Zolotavin, A.V.; Makarov, V.M.; Sergeev, V.O.; Usynko, T.M.

1978-01-01

The purpose of this paper is the measurement of the relative intensities of the most intensive conversion lines of 152 Eu, the determination of as reliable as possible magnitudes of the intensities of γ-quanta using all the available data on γ-radiation of 152 Eu, the measurement of the interval conversion coefficients (ICC) for the most intensive γ-transitions, the determination of the probabilities of the 152 Eu β-decays to the 152 Sm and 152 Gd levels. The conversion lines of the most intensive γ-transitions in the 152 Eu decay are studied and the corresponding ICC are measured on the beta-spectrometers of π√2 and UMB type. The balance for the γ-transitions in the 152 Sm and 152 Gd daughter nuclei are presented. This balance is used to determine the absolute intensities of γ-rays (in terms of the percentage of the 152 Eu decays) and the probabilities of β-transitions to the levels of daughter nuclei. More accurate data on γ-rays and conversion electrons obtained can be used for the calibration of gamma and beta spectrometers

Studies on radioactivity distribution and radioactive mineral identification in uranium ores from Espinharas (PB), Brazil

International Nuclear Information System (INIS)

Oliveira, G.N.M. de.

1979-01-01

Studies about the identification of radioactive minerals in uranium bearing rocks from Espinharas (PB), Brazil are presented. Autoradiography with α-sensitive nuclear emulsions was utilized for determining radioctivity distributions and for localizing radioactive minerals, in combination with microscopy, X-ray diffractometry, PIXE and eletron microprobe analysis for its identification. Mineralized gneisse and feldspatic rock, the two principal samples studied, show distinct differences in radioactive distribution patterns, however the main carriers for U and Th seem to be the same. Microanalysis shows that elements are associated with Si, Ca, Fe and Al an some trace elements like Y, Zr, Ti, etc. U and Th are distributed uniformly in feldspatic rock and inhomogeneously in mineralized gneisse, indicating that the zonary structure of the radioactive cristals, frequently observed in gneisse, could be due to variable U:Th ratios. Chemical analysis, X-ray diffraction datas and microscopic studies indicates that the principal carrier for radioactivity in the rocks of Espinharas is a silicate mineral of U and Th, probably situaded in the series of transition: Coffinite -> uraninite, thorogummite -> thorianite. Some additional experiments about leachability of uranium with diluted sulfuric acid are reported, which confirm the different nature of radioactivity distribution in feldspatic and gneissic rocks. (author) [pt

National system for radioactive waste management in Lithuania and its harmonization with the European Union legislation

International Nuclear Information System (INIS)

Adomaitis, J. E.; Poshkas, P.

1999-01-01

Radioactive waste management philosophies and technologies are still emerging, and there is therefore a need to reorganize and improve the national system for radioactive waste management in Lithuania. Lithuania's Law on Radioactive Waste Management and the new regulations will be harmonized with the European Union legislation in this field, with the IAEA general principles and with the obligations of the Republic of Lithuania under the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management. Different organizational and financial schemes available in the EU countries for radioactive waste management are described and analyzed. The most important aspects needed to establish the Lithuania's Radioactive Waste Management Agency and Fund are defined and developed. (author)

The LAW Library -- A multigroup cross-section library for use in radioactive waste analysis calculations

International Nuclear Information System (INIS)

Greene, N.M.; Arwood, J.W.; Wright, R.Q.; Parks, C.V.

1994-08-01

The 238-group LAW Library is a new multigroup neutron cross-section library based on ENDF/B-V data, with five sets of data taken from ENDF/B-VI ( 14 N 7 , 15 N 7 , 16 O 8 , 154Eu 63 , and 155 Eu 63 ). These five nuclides are included because the new evaluations are thought to be superior to those in Version 5. The LAW Library contains data for over 300 materials and will be distributed by the Radiation Shielding Information Center, located at Oak Ridge National Laboratory. It was generated for use in neutronics calculations required in radioactive waste analyses, although it has equal utility in any study requiring multigroup neutron cross sections

Fermi Surface Properties of Eu-Divalent and Eu-Trivalent Electronic States with the AuCu3-type Cubic Structure

International Nuclear Information System (INIS)

Nakamura, Ai; Takeuchi, Tetsuya; Tatetsu, Yasutomi; Maehira, Takahiro; Hedo, Masato; Nakama, Takao; Ōnuki, Yoshichika; Harima, Hisatomo

2015-01-01

The electronic states in EuBi 3 and EuPd 3 are known to be Eu-divalent and Eu- trivalent, respectively, from the previous studies using polycrystal samples. In the present study, we succeeded in growing high-quality single crystals, and carried out the de Haas-van Alphen (dHvA) measurements and energy band calculations to clarify the Fermi surface properties

Cathodoluminescence properties of yttrium aluminum garnet doped with Eu2+ and Eu3+ ions

International Nuclear Information System (INIS)

Trofimov, A. N.; Petrova, M. A.; Zamoryanskaya, M. V.

2007-01-01

Yttrium aluminium garnet (YAG) doped with Eu 2+ and Eu 3+ ions is very interesting as a phosphor for conversion of light-emitting diode light for white light sources. The europium ion occupies the structural position of yttrium in yttrium aluminium garnet and has valence state Eu 3+ . Our sample was doped with Zr 4+ , which is why some of the europium ions had valence state Eu 2+ . As a rule, luminescence of Eu 3+ ions is observed in the orange and red range of spectrum. The luminescence of Eu 2+ in yttrium aluminum garnet is characterized by an intensive broad band with maximum of intensity at about 560 nm (green color). In this work, we studied the intensity and decay time dependences on europium concentration, and the influence of excitation power density on the cathodoluminescence of the sample. The most interesting result is the change of visible cathodoluminescence color in dependence on the density of the exciting power

Perspectives for environmental radiation protection in EU radiation protection legislation

International Nuclear Information System (INIS)

Janssens, A.

2000-01-01

The basis of EU radiation protection legislation is the EURATOM Trealy. It is discussed whether the Treaty offers a legal basis for the protection of the natural environment. The incorporation of provisions pertaining to the nuclear fuel cycle or to radioactive substances in general environmental legislation is explained, as well as the possible implications of international conventions subscribed by the European Union. The European Commission is in the process of developing an overall approach to risk analysis for the protection of health, consumer interests, and the environment. It is examined to what extent the consideration of the impact of radiation on the natural environment fits in the overall framework and whether the principles underlying classical radiation protection are applicable to biota. Specific attention is given to situations where high levels of environmental radioactivity would require intervention. (Author)

Study on serious road traffic injuries in the EU.

NARCIS (Netherlands)

Aarts, L.T. Commandeur, J.J.F. Welsh, R. Niesen, S. Lerner, M. Thomas, P. Bos, N. & Davidse, R.J.

2016-01-01

It is the ambition of the EU to reduce the number of killed and seriously injured on the roads over time. It has turned out that, especially in relation to serious injuries, there is still a significant knowledge gap on how to reduce these numbers in the EU. The Commission is therefore committed to

Sources of ionizing radiation, radioactive or nuclear materials out of control. National system of response in Slovakia

International Nuclear Information System (INIS)

Auxtova, L.; Adamek, P.; Moravecb, R.; Melich, M.

2003-01-01

In this paper authors deals with the Customs inspection of radioactive materials - present situation as well as with situation after accession of the Slovak Republic process to European Union (EU). he actual response system to incidents with orphan sources or radioactive material occurring in metal scrap, illicit trafficking and disused sources out of control is laid down on the following scheme. The national strategy is aimed to establish a more effective responding system preventing further illegal trafficking with regard to the acceding process which will require for new member states joining EU proper arrangements in improving the safety of radiation sources over the life-cycle to ensure the effective functioning in the conditions of the Slovak Republic's membership in the European Union

151Eu nuclear resonant inelastic scattering of Eu3Pd20Ge6

International Nuclear Information System (INIS)

Tsutsui, S.; Yoda, Y.; Kobayashi, Y.; Higashitaniguchi, S.; Seto, M.; Kitagawa, J.; Takabatake, T.

2010-01-01

151 Eu nuclear resonant inelastic scattering of Eu 3 Pd 20 Ge 6 . The Eu partial phonon density of states (DOS) in Eu 3 Pd 20 Ge 6 are investigated using 151 Eu nuclear resonance inelastic scattering (NRIS). 151 Eu NRIS was carried out at BL09XU of SPring-8. Significant temperature dependence was found in the partial phonon DOS. Judging from the valence change at the Eu 4a site and the comparison with the ab initio calculation of Eu 3 Pd 20 Ge 6 , the change of the Eu DOS is caused by the electronic states. On the other hand, significant acoustic contribution was found even at the guest site of the Eu ones. In addition, slower average velocity than transverse sound velocity was obtained by Eu partial phonon DOS. Considering that heat is carried by the acoustic phonon in materials, the present results demonstrate that the moderate thermal insulation in Eu 3 Pd 20 Ge 6 is connected with the observation of slow average sound velocity at the Eu sites. (K.F.)

Behavior of rare earth elements in fractured aquifers: an application to geological disposal criteria for radioactive waste

International Nuclear Information System (INIS)

Lee, Seung Gu; Kim, Yong Je; Lee, Kil Yong; Kim, Kun Han

2003-01-01

An understanding of the geochemistry of potential host rocks is very important in the site evaluation for construction of an underground geologic repository for radioactive waste. Because of similar valence and ionic radii and high similarity in electronic structure with trivalent actinides (such as Am 3+ and Cm 3+ ), the rare earth elements (REEs) have been used to predict the behavior of actinide-series elements in solution (Runde et al., 1992). For Am and Cm, which occur only in the trivalent states in most waste-disposal repository environments, the analogy with the REEs is particularly relevant. In order to discuss the behavior of REEs in geological media and to deduce the behavior of actinides in geological environments based on the REE abundance, and to provide an useful tool in deciding an optimum geological condition for radioactive disposal, we estimated the REE abundance from various kinds of fractured rock type. In fractured granitic aquifer, chondrite-normalized REE pattern show Eu positive anomaly due to fracture-filling calcite precipitation. However, in fractured meta-basaltic and volcanic tuffaceous aquifer, REE pattern do not show the change of Eu anomaly due to fracture-filling calcite precipitation. Eu shows very similar properties such as cohesive energy, ionic radii with coordination number compared to Am. Therefore, if we consider the Eu behavior in fractured rocks and the similar physical/chemical properties of Eu and Am, together, our results strongly suggest that Eu is a very useful analogue for predicting the behavior of Am in geological environment

Electrochemical reduction of Eu (III) in propionic media

International Nuclear Information System (INIS)

Brotto, M.E.; Rabockai, T.

1988-01-01

Some chronopotentiometric studies of Eu (III) electro-reducion in propionic media that suggests the presence of two parallel rections: Eu (III) → Eu (II) and Eu (III) → Eu (II) → Y are presented. Some experimental data, such Eu (III) reducion, electrolysis of solutions and ionic power of the system are discussed. (M.J.C.) [pt

Total cross section measurement of radioactive isotopes with a thin beam neutron spectrometer

International Nuclear Information System (INIS)

Razbudej, V.F.; Vertebnyj, V.P.; Padun, G.S.; Muravitskij, A.V.

1975-01-01

The method for measuring the neutron total cross sections of radioactive isotopes by a time-of-flight spectrometer with a narrow (0.17 mm in diameter) beam of thermal neutrons is described. The distinguishing feature of this method is the use of capillary samples with a small amount of substance (0.05-1.0 mg). The energy range is 0.01-0.3 eV. The total cross sections of irradiated samples of sub(153)Eu and sub(151)Eu are measured. From them are obtained the cross sections of sub(152)Eu (Tsub(1/2)=12.4 g) and of sub(154)E (Tsub(1/2)=8.6 yr); they equal 11400+-1400 and 1530+-190 barn at E=0.0253 eV. The cross section of the sub(152)Eu absorption for the thermal spectrum (T=333 K) is determined by the activation method; it is 8900+-1200 barn

Metrological tests of a 200 L calibration source for HPGE detector systems for assay of radioactive waste drums

International Nuclear Information System (INIS)

Boshkova, T.; Mitev, K.

2016-01-01

In this work we present test procedures, approval criteria and results from two metrological inspections of a certified large volume "1"5"2Eu source (drum about 200 L) intended for calibration of HPGe gamma assay systems used for activity measurement of radioactive waste drums. The aim of the inspections was to prove the stability of the calibration source during its working life. The large volume source was designed and produced in 2007. It consists of 448 identical sealed radioactive sources (modules) apportioned in 32 transparent plastic tubes which were placed in a wooden matrix which filled the drum. During the inspections the modules were subjected to tests for verification of their certified characteristics. The results show a perfect compliance with the NIST basic guidelines for the properties of a radioactive certified reference material (CRM) and demonstrate the stability of the large volume CRM-drum after 7 years of operation. - Highlights: • Large (200 L) volume drum source designed, produced and certified as CRM in 2007. • Source contains 448 identical sealed radioactive "1"5"2Eu sources (modules). • Two metrological inspections in 2011 and 2014. • No statistically significant changes of the certified characteristics over time. • Stable calibration source for HPGe-gamma radioactive waste assay systems.

The total neutron cross-sections of 151Eu, 153Eu and Eu below 1 eV

International Nuclear Information System (INIS)

Adib, M.; Maayouf, R.M.A.; Abdel-Kawy, A.; Ashry, A.; Hamouda, I.

1980-12-01

Total neutron cross-section measurements have been carried out for natural Eu and its stable isotopes in the energy range from 3 meV-1 eV. The measurements were performed using two time-of-flight spectrometers installed in front of two of the horizontal channels of the ET-RR-1 reactor. The following results have been obtained: sigmasub(α)( 151 Eu) = 9180+-150 b at 0.0253 eV; sigmasub(α)( 153 Eu) = 375+-20 b at 0.0253 eV; sigmasub(α)(Eu) = 4600+-120 b at 0.0253 eV

The EU electricity disclosure from the business perspective-A study from Norway

International Nuclear Information System (INIS)

Aasen, M.; Westskog, H.; Wilhite, H.; Lindberg, M.

2010-01-01

The EU Electricity Directive requires that consumers be provided information about the sources from which the electricity is produced, as well as about the CO 2 emissions and the radioactive waste resulting from production sources. In this paper we examine the effectiveness of this information strategy based on a case study focusing on Norwegian enterprises. We explore the views of selected companies on the electricity disclosure scheme. We examine how effective the disclosure scheme is in informing and stimulating companies to buy green electricity products, and link this to what we know about the effects of information disclosure from the literature. Our results show that the information disclosed does to a little extent reach the businesses, and that firms express distrust in the system of Guarantees of Origin (GoO), which leads to distrust in the relevance of the information given through the disclosure scheme. - Research highlights: →The information disclosed does to a little extent reach the businesses and catch their interest. →Firms express distrust in the Guarantees of Origin System (GoO), which leads to distrust in the relevance of the information given through the disclosure system. →Many firms point out that the absence of a mechanism to convert GoO revenue to investment in new green production weakens the legitimacy of the disclosure system.

Survey of radioactive contamination for foodstuffs

International Nuclear Information System (INIS)

Lee, Wan No; Lee, Chang Wu; Choi, Geun Sik; Cho, Yeong Hyeon; Kang, Mun Ja; Cheong, Geun Ho; Kim, Hui Ryeong; Park, Du Won; Park, Hyo Guk; Kwak, Ji Yeon

2006-11-01

After the Chernobyl nuclear accident in 1986, a lot of countries including EU, Japan, USA are to strengthen survey of radioactive contamination for foodstuffs. Our country has also surveyed radioactive contamination of the imported foodstuffs and started to check continuously the radioactivity contamination of the open market foodstuffs since 2003. In this year, imported foodstuffs(130 samples) and domestic foodstuffs(10 samples) are analyzed to investigate the radioactive contamination. Sampled foodstuffs items are collected from the open markets; one group is the imported foodstuffs and the other group is the domestic foodstuffs producted around nuclear facilities and northeast of Sokcho city concerning recent situations. Samples are usually bought from traditional markets, mart, department store or the Internet. After pretreatments such as drying, ashing, and homogenization, all samples were analyzed by gamma spectrometer system for survey and assessment of radioactive contamination. The 131 I radionuclide isn't detected among all foodstuffs(imported and domestic). The 137 Cs radionuclide among the regulation radionuclides( 137 Cs, 13 4 C s, 131 I) of food code is only detected at the imported foodstuffs but its level is far below the maximum permitted level. For the improvement of measurement confidence, the developed analysis method is tested by the participation of the national and international intercomparison. The developed method based on test results and international standard would be used at radioactive analysis as well as an education of relative workers. It could be applied as the basis data for amending the analysis method of food code. It is technically supported for radioactive analysis of commercial company and the government including KFDA. Finally these results would be used to solve an ambiguous anxiety of a people for radiation exposure by foodstuffs intake and help the KFDA to manage systematically the radioactive contamination and to give

Concentration depolarization of luminescence of Eu3+-doped glasses

International Nuclear Information System (INIS)

Bodunov, E.N.; Lebedev, V.P.; Malyshev, V.A.; Przheuskij, A.K.

1989-01-01

Experimental study of concentrational depolarization luminescence (CDL) of phosphate and germanate glasses, containing Eu 3+ ions, has been carried out. On the basis of three-body self-consistent approximation the theory of CDL is conceived, which takes into account Eu-Eu interaction of higher multipolarities. By comparing the theory with the experiment energy transfer radii for Eu-Eu dipole-dipole, dipole-quadrupole and quadrupole-quadrupole interactions are determined. The attempt to discriminate Eu-Eu interaction types in the studied range of Eu 3+ ion concentration change has failed owing to law accuracy of luminescence emittance anisotropy measurement

Magnetization study of interlayer exchange in semiconductor EuS-PbS ferromagnetic wedge multilayers

International Nuclear Information System (INIS)

Kowalczyk, L.; Osinniy, V.; Chernyshova, M.; Dziawa, P.; Boratynski, A.; Story, T.; Smits, C.J.P.; Swagten, H.J.M.; Sipatov, A.Yu.; Volobuev, V.V.

2006-01-01

Interlayer coupling was experimentally studied in semiconductor EuS-PbS ferromagnetic superlattice wedge structures grown on KCl (0 0 1) substrates with the wedges covering the semiconductor nonmagnetic PbS spacer layer thickness from 0.3 to 6 nm. Structural parameters of the wedges were examined by X-ray diffraction analysis of EuS-PbS superlattice period. Measurements of magnetic hysteresis loops of EuS-PbS structures were performed by both SQUID (for small terminal parts of the wedge) and MOKE (magneto-optical analysis along the wedge) magnetometry. A strong decrease of magnetic remanence and an increase of saturation field observed for EuS-PbS structures with the PbS spacer thickness decreasing below about 1.5 nm is discussed in terms of the influence of antiferromagnetic interlayer coupling

Antiprotonic Radioactive Atom for Nuclear Structure Studies

International Nuclear Information System (INIS)

Wada, M.; Yamazaki, Y.

2005-01-01

A future experiment to synthesize antiprotonic radioactive nuclear ions is proposed for nuclear structure studies. Antiprotonic radioactive nuclear atom can be synthesized in a nested Penning trap where a cloud of antiprotons is prestored and slow radioactive nuclear ions are bunch-injected into the trap. By observing of the ratio of π+ and π- produced in the annihilation process, we can deduce the different abundance of protons and neutrons at the surface of the nuclei. The proposed method would provide a unique probe for investigating the nuclear structure of unstable nuclei

Study of the on line radioactive multicharged ion production

International Nuclear Information System (INIS)

Lecesne, N.

1997-01-01

This work is directly related to the SPIRAL project (Systeme de Production d'Ions Radioactifs Acceleres en Ligne) which will start at GANIL at the end of 1998. The aim of the thesis was to study the on line radioactive multicharged ion beam production stages, i.e. the production and diffusion of the radioactive nuclei in a thick target, their possible transfer up to an ECR ion source and their ionisation. Production cross sections of radioactive neutron rich nuclei, formed by fragmentation of a heavy ion beam in a thick target, were measured. An external target-ECR source system, dedicated to the radioactive noble gases production, and two internal target-ECR source systems, dedicated to the radioactive condensable element production, were built and tested on the SIRa tests bench (Separateur d'Ions Radioactifs). Different detection configurations were elaborated in order to identify the radioactive nuclei and estimate their production yields. Finally, a new method for measuring the overall efficiency of the separator was developed and allowed to study the diffusion properties of radioactive noble gases in various targets. (author)

Phosphor thermometry: On the synthesis and characterisation of Y{sub 3}Al{sub 5}O{sub 12}:Eu (YAG:Eu) and YAlO{sub 3}:Eu (YAP:Eu)

Energy Technology Data Exchange (ETDEWEB)

Kissel, T. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Brübach, J., E-mail: bruebach@ekt.tu-darmstadt.de [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Euler, M. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Frotscher, M.; Litterscheid, C.; Albert, B. [Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Petersenstraße 18, 64287 Darmstadt (Germany); Dreizler, A. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany)

2013-07-15

With regard to phosphor thermometry, the materials Y{sub 3}Al{sub 5}O{sub 12}:Eu (YAG:Eu) and YAlO{sub 3}:Eu (YAP:Eu) were synthesised and characterised in order to substitute the commonly used thermographic phosphor Y{sub 2}O{sub 3}:Eu, whose temperature sensitive luminescence lifetime exhibits a strong and most often undesirable cross-sensitivity to the oxygen concentration of the surrounding gas phase. The synthesis is outlined in detail and the crystallographic structure was characterised by X-ray diffraction. In a second step, the luminescence properties following pulsed UV laser excitation were determined. In this context, the emission spectra and the temperature lifetime characteristics were monitored. For Y{sub 3}Al{sub 5}O{sub 12}:Eu and YAlO{sub 3}:Eu, temperature sensitive ranges of 1000 K–1470 K and 850 K–1300 K were identified. Contrary to Y{sub 2}O{sub 3}:Eu, both materials do show much lower cross-sensitivities to the oxygen concentration of the surrounding gas phase. - Highlights: ► Y{sub 3}Al{sub 5}O{sub 12}:Eu and YAlO{sub 3}:Eu were synthesised and characterised. ► The synthesis is outlined and the crystallographic structure was characterised. ► Emission spectra and the temperature lifetime characteristics were monitored. ► Compared to Y{sub 2}O{sub 3}:Eu lower sensitivities to the oxyg. conc. of the gas phase emerged.

European Dimension of Legal Education. A comparative study of the Romanian Law Curricula and EU Law Syllabus

Directory of Open Access Journals (Sweden)

Brinduşa Camelia Gorea

2012-05-01

Full Text Available Our purpose is to provide a detailed view on the European legal education system in Romania.There are few papers on EU legal education policy in Romania. We try to fill this gap in some extend, as apart of a larger research we conducted in the past 3 years. Our sources of evidence were: the Romanianlegislation; a representative number of law curricula and EU law syllabus and a research survey of Romanianstudents, EU law professors and legal practitioners. We found out that the “traditional” Law specialization ismore desired by the potential students than the European Law specialization. Nevertheless, Romanian lawschools have enough discretion to introduce more EU law disciplines. By targeting the weak parts of the EUlegal education system, our study may reveal its benefits to law professors, legal researchers, responsiblefactors within the Romanian law departments and even to the Romanian legislator. This paper provides ashort explanation of the ascension and development of EU legal studies in Romania, an overview of the keyissues in the law curricula and the EU law syllabus and recommendations on the reforming the EU legaleducation in Romania.

EU Energy Law. Volume 4. The EU Greenhouse Gas Emissions Trading Scheme

International Nuclear Information System (INIS)

Delbeke, J.; Hartridge, O.; Lefevere, J.; Meadows, D.; Runge-Metzger, A.; Slingenberg, Y.; Vainio, M.; Vis, P.; Zapfel, P.

2006-06-01

Gives valuable insights in the why's, how's, trade-offs, and critical design choices of the Emission Trading System of the European Union (EU ETS). The chapters deal with (1) The EU ETS: the result of a decade of policy action on the economic dimension of EU environmental policy; (2) The international climate policy developments of the 1990s: UNFCCC, the Kyoto Protocol, the Marrakech Agreements and the EU's Kyoto ratification decision; (3) Emissions trading: What is it? Design options and misconceptions; (4) The EU ETS Directive 2003/87/EEC explained; (5) The EU ETS Linking Directive explained; (6) The economic efficiency benefits of the EU ETS; (7) The NAP I experience; (8) The key importance of the Registry Regulation and of solid monitoring and verification; and (9) The potential role of the EU ETS for the elaboration of the post-2012 international climate regime. Conclusions are in chapter 10

Progresses in proton radioactivity studies

Energy Technology Data Exchange (ETDEWEB)

Ferreira, L. S., E-mail: flidia@ist.utl.pt [Center of Physics and Engineering of Advanced Materials, CeFEMA and Departamento de Física, Instituto Superior Técnico, Universidade de Lisboa, Avenida Rovisco Pais, P1049-001 Lisbon (Portugal); Maglione, E. [Dipartimento di Fisica e Astronomia “G. Galilei”, Via Marzolo 8, I-35131 Padova, Italy and Istituto Nazionale di Fisica Nucleare, Padova (Italy)

2016-07-07

In the present talk, we will discuss recent progresses in the theoretical study of proton radioactivity and their impact on the present understanding of nuclear structure at the extremes of proton stability.

Present developmental conditions petroleum substituting energies in the EU; Sekiyu daitai energy kaihatsu no genjo (EU)

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-03-01

This report outlines the policy of development and introduction of petroleum substituting energies, and its diffusion situation in the EU. On the policy, development, introduction and diffusion of petroleum substituting energies in the EU, based on the new EU energy white paper issued in fiscal 1996, the policy of energy and environment in every EU country is first outlined. The policy of and practical approach to petroleum substituting energies in every EU country are next described. In particular, since ALTENER which has been continuously promoted by the EU for 3 years as main control measures against CO2 is newly moving toward the second plan, the trend of ALTENER and the new SAVE2 plan are presented. The content of JOULE-THERMIE is also precisely presented which is the new energy program of the 4th framework R & D program. In relation to the developmental trend of alternative energies to oil in the EU until 2020, its prediction result is presented on the basis of the latest study promoted by EC committee in the ALTENER plan. 10 tabs.

Study on radioactivity in consumer goods

International Nuclear Information System (INIS)

1976-01-01

Consumer goods containing radionuclides are increasingly utilized, sometimes for having chemical or technological properties which nonradioactive materials cannot fulfill (e.g. uranium paints) or it may be that radioactivity is especially required (e.g. fluorescent paints, fire-alarm-boxes, electronic instruments). The present study makes a compilation of consumer goods containing radioactive substances which are available to the general public in the nine countries of the Community, carries out a medium and long term study to assess how accumulated radiation from these goods could affect the population as a whole, and proposes measures to minimize the effects of such accumulation

Luminescence study of Eu3+ doped GdVO4 nanoparticles: Concentration, particle size, and core/shell effects

Science.gov (United States)

Singh, N. Shanta; Ningthoujam, R. S.; Devi, L. Romila; Yaiphaba, N.; Sudarsan, V.; Singh, S. Dorendrajit; Vatsa, R. K.; Tewari, R.

2008-11-01

Nanoparticles of GdVO4 doped with Eu3+ and core/shell of GdVO4:Eu3+/GdVO4 are prepared by urea hydrolysis method using ethylene glycol as capping agent as well as reaction medium at 130 °C. Unit cell volume increases when GdVO4 is doped with Eu3+ indicating the substitution of Gd3+ lattice sites by Eu3+. From luminescence study, it is confirmed that there is no particle size effect on emission positions of Eu3+. Optimum luminescence intensity is found to be in 5-10 at. % Eu3+. Above these concentrations, luminescence intensity decreases due to concentration quenching effect. There is an enhancement in luminescence intensity of core/shell nanoparticles. This has been attributed to the reduction in surface inhomogenities of Eu3+ surroundings by bonding to GdVO4 shell. The lifetime for D50 level increases with annealing and core/shell formation.

Residual radioactivity in the soil of the Semipalatinsk Nuclear Test Site in the former USSR.

Science.gov (United States)

Yamamoto, M; Tsukatani, T; Katayama, Y

1996-08-01

This paper deals with our efforts to survey residual radioactivity in the soil sampled at the Semipalatinsk Nuclear Test Site and at off-site areas in Kazakhstan. The soil was sampled at the hypocenter where the first Soviet nuclear explosion was carried out on 29 August 1949, and at the bank of the crater called "Bolapan," which was formed by an underground nuclear detonation on 15 January 1965 along the Shagan River. As a comparison, other soil was also sampled in the cities of Kurchatov and Almaty. These data have allowed a preliminary evaluation of the contemporary radioactive contamination of the land in and around the test site. At the first nuclear explosion site and at Bolapan, higher than background levels of 239,240Pu with weapons-grade plutonium were detected together with fission and activation products such as 137Cs, 60Co, 152Eu, and 154Eu.

Benchmark studies of induced radioactivity and remanent dose rates produced in LHC materials

International Nuclear Information System (INIS)

Brugger, M.; Mayer, S.; Roesler, S.; Ulrici, L.; Khater, H.; Prinz, A.; Vincke, H.

2005-01-01

Samples of materials that will be used for elements of the LHC machine as well as for shielding and construction components were irradiated in the stray radiation field of the CERN-EU high-energy Reference Field facility. The materials included various types of steel, copper, titanium, concrete and marble as well as light materials such as carbon composites and boron nitride. Emphasis was put on an accurate recording of the irradiation conditions, such as irradiation profile and intensity, and on a detailed determination of the elemental composition of the samples. After the irradiation, the specific activity induced in the samples as well as the remanent dose rate were measured at different cooling times ranging from about 20 minutes to two months. Furthermore, the irradiation experiment was simulated using the FLUKA Monte Carlo code and specific activities. In addition, dose rates were calculated. The latter was based on a new method simulating the production of various isotopes and the electromagnetic cascade induced by radioactive decay at a certain cooling time. In general, solid agreement was found, which engenders confidence in the predictive power of the applied codes and tools for the estimation of the radioactive nuclide inventory of the LHC machine as well as the calculation of remanent doses to personnel during interventions. (authors)

Educational and training needs in radioactive waste management

International Nuclear Information System (INIS)

Mele, I.; Mavko, B.; Jencic, I.

2005-01-01

For further safe use of nuclear technology it is highly important to maintain the achieved level of knowledge and expertise. The risk of losing nuclear knowledge accumulated in the past is being increasingly discussed in many countries. As part of this debate the knowledge of radioactive waste management is also being closely watched. The current position and future needs of education and training in radioactive waste management were investigated within the coordination action CETRAD as part of the 6 th Framework Programme of the EU. Twenty partners from 17 European countries, including Slovenia, took part in this investigation. The review focused on geological disposal. It has considered the training and education needs of national radioactive waste management organisations, regulatory and government advisory organisations, and other nuclear industry organisations employing staff in this area, and also the provision of education and training by university and non-university organisations to address these needs. The results and conclusions of this research are presented in this paper. Emphasis is given to the national survey results and estimations of our E and T needs in radioactive waste management. (author)

The total neutron cross-sections of 151Eu, 153Eu and Eu below 1 eV

International Nuclear Information System (INIS)

Adib, M.; Maayouf, R.M.A.; Abdel-Kawy, A.; Ashry, A.; Hamouda, I.

1981-01-01

Total neutron cross-section measurements have been carried out for natural Eu and its stable isotopes in the energy range from 3 meV to 1 eV. The measurements were performed using two time-of-flight spectrometers installed in front of two of the horizontal channels of the ET-RR-1 reactor. The following results have been obtained: sigmasub(a) ( 151 Eu) = (9180 +- 150) b at 0.0253 eV, sigmasub(s) ( 153 Eu) = (375 +- 20) b at 0.0253 eV, sigmasub(d) (Eu) = (4600 +- 120) b at 0.0253 eV. The contribution of the resonance to the total neutron cross-sections, in the thermal region, was calculated using the single-level Breit-Wigner formula. (orig.)

Assessing EU perception in Kazakhstan's mass media

Directory of Open Access Journals (Sweden)

Bakyt Ospanova

2017-01-01

Our main findings suggest that Kazakhstan's mass media positively perceives the role of the EU in the region. Moreover, they tend to portray the EU mainly as an economic powerhouse. Our findings support some suggestions by similar studies of the EU's external perception.

Mineralogy and Radioactivity of Some Pegmatite Bodies, Southeastern Sinai, Egypt

International Nuclear Information System (INIS)

Elnahas, H.A.

2012-01-01

The area under consideration constitutes the extreme eastern part of the Kid metamorphic belt in Sinai Peninsula. The Neoproterozoic rock units exposed there comprise gneisses, migmatites, old granitoids and monzogranites. Most of the pegmatite bodies encountered in the monzogranite rocks occur as plug-like bodies and veins of variable dimensions. These studied pegmatites are mainly of the simple unzoned type. They are composed of intergrowths of smoky quartz and pink K-feldspar with some accumulations of micas which host most of radioactive mineralizations. Radiomertrically, the concentration of eU ranges between 41 and 117ppm with an average of 73ppm, while eTh varies between 160 and 433ppm with an average of 223ppm. The Ra content reaches up to 94ppm with an average of 62ppm. The radioelements variation diagrams illustrate that the distribution of radioelements is due to both magmatic origin and hydrothermal redistribution. The high level of radioactivity in the studied granitic pegmatites is mainly resulted from the presence of ishikawaite, thorite, uranothorite, thorianite, zircon, fiptafite and fluorite. Most of the studied radioactive minerals commonly occur in the metamict state. Other accessory minerals like anatase, hematite and magnetite are also recorded. The study reports for the first time the presence of Ishikawaite-Th, where Th prevails U. Ishikawaite-Th grains contain exsolution intergrowths of ishikawaite-U and thorianite.

Luminescence study on Eu3+ doped Y2O3 nanoparticles: particle size, concentration and core-shell formation effects

International Nuclear Information System (INIS)

Singh, L Robindro; Ningthoujam, R S; Sudarsan, V; Srivastava, Iti; Singh, S Dorendrajit; Dey, G K; Kulshreshtha, S K

2008-01-01

Nanoparticles of Eu 3+ doped Y 2 O 3 (core) and Eu 3+ doped Y 2 O 3 covered with Y 2 O 3 shell (core-shell) are prepared by urea hydrolysis for 3 h in ethylene glycol medium at a relatively low temperature of 140 deg. C, followed by heating at 500 and 900 deg. C. Particle sizes determined from x-ray diffraction and transmission electron microscopic studies are 11 and 18 nm for 500 and 900 deg. C heated samples respectively. Based on the luminescence studies of 500 and 900 deg. C heated samples, it is confirmed that there is no particle size effect on the peak positions of Eu 3+ emission, and optimum luminescence intensity is observed from the nanoparticles with a Eu 3+ concentration of 4-5 at.%. A luminescence study establishes that the Eu 3+ environment in amorphous Y (OH) 3 is different from that in crystalline Y 2 O 3 . For a fixed concentration of Eu 3+ doping, there is a reduction in Eu 3+ emission intensity for core-shell nanoparticles compared to that of core nanoparticles, and this has been attributed to the concentration dilution effect. Energy transfer from the host to Eu 3+ increases with increase of crystallinity

Synthesis and tunable luminescent properties of Eu-doped Ca2NaSiO4F – Coexistence of the Eu2+ and Eu3+ centers

Directory of Open Access Journals (Sweden)

Mubiao Xie

Full Text Available Novel phosphors Ca2NaSiO4F:Eu were synthesized successfully by the conventional solid-state method in CO atmosphere, and their spectroscopic properties in UV−vis region were investigated. The photoluminescence properties show that Eu3+ ions were partially reduced to Eu2+ in Ca2NaSiO4F. As a result of radiation and re-absorption energy transfer from Eu2+ to Eu3+, both Eu2+ bluish-green emission at around 520 nm and Eu3+ red emission are observed in the emission spectra under the n-UV light excitation. Furthermore, the ratio between Eu2+ and Eu3+ emissions varies with increasing content of overall Eu. Because relative intensity of the red component from Eu3+ became systematically stronger, white light emission can be realized by combining the emission of Eu2+ and Eu3+ in a single host lattice under n-UV light excitation. These results indicate that the Ca2NaSiO4F:Eu phosphors have potential applications as a n-UV convertible phosphor for light-emitting diodes. Keywords: Phosphors, Luminescence, White LED, Optical materials

TRLIFS study of Eu(III) spectroscopic properties to obtain structural and thermodynamic informations on lanthanide-malonamide complexes in the Eu(III)/NaNO3/tetraethylmalonamide system

International Nuclear Information System (INIS)

Couston, L.; Charbonnel, M.C.; Flandin, J.L.; Rancier, F.; Moulin, C.

2004-01-01

Improvement of the nuclear fuel reprocessing involves separating the minor actinides (Am(III) and Cm(III)) from the fission products. In the French strategy, the first step consists in the separation of the trivalent actinides and lanthanides from high-level liquid waste, for which malonamides RR'NCO(CHR '' )CONRR' are promising ligands. These molecules have been optimized for reprocessing but still require basic chemical studies to describe the complexation mechanisms at a molecular scale. This paper discusses a thermodynamic and structural study of a Ln(III)-malonamide complex formed with the hydrosoluble tetraethylmalonamide ligand (TEMA = (C 2 H 5 ) 2 NCOCH 2 CON(C 2 H 5 ) 2 ) dissolved in a nitrate medium. Despite the simplified chemical system obtained with TEMA, its weak chemical affinity and its physical properties pushed the analytical techniques to their limits. The sensitivity of time-resolved laser-induced fluorescence spectroscopy (TRLIFS) combined with the major luminescent spectroscopic properties of Eu(III) (hypersensitive band and fluorescence lifetime) were successfully used to determine the equilibrium constant and hydration number in the Eu(III), TEMA, and NO 3 - system. Fluorescence lifetimes, connected with the first coordination sphere of the solvated metal, clearly show the inner-sphere location of nitrate in the Eu(NO 3 ) 2+ complex, the outer-sphere location of TEMA in the Eu(TEMA) 3+ complex, and the outer-sphere location of both ligands in the Eu(NO 3 )(TEMA) 2+ complex. (orig.)

The Uptake of Eu(III) and Th(IV) by Calcite under Hyperalkaline Conditions

International Nuclear Information System (INIS)

Tits, J.; Wieland, E.; Bradbury, M.H.; Eckert, P.; Schaible, A.

2002-10-01

Calcite is an important component of Valanginian marl, a potential host rock for a low and intermediate level radioactive waste (L/ILW) repository in Switzerland. This mineral also forms an important component of the disturbed zone around a repository, as it remains largely unaffected by the hyperalkaline waters migrating out of the cementitious repository . The sorption behaviour of Eu(III) and Th(IV) on Merck calcite in an artificial cement pore water (ACW) at pH 13.3 has been studied in batch-type sorption experiments. In addition, the effect of α-isosaccharinic acid (ISA) and gluconic acid (GLU) on the sorption of these two cations has been investigated. In the absence of ISA and GLU, a strong interaction of Eu(III) and Th(IV) with Merck calcite was observed. Eu(III) and Th(IV) sorption kinetics were fast and the isotherms indicated a linear adsorption behaviour over the experimentally accessible concentration range. In the case of Eu(III), a decrease of the R d value with increasing solid to liquid (S:L) ratio was observed indicating that, along with adsorption, other processes might influence the immobilisation of this cation by Merck calcite under ACW conditions. In the case of Th(IV), however, changes in the S:L ratio had no effect on the sorption behaviour . High ISA and GLU concentrations in solution significantly affected the sorption of both Eu(III) and Th(IV): R d values for Eu(III) decreased significantly at ISA concentrations higher than 10 -5 M and at GLU concentrations higher than 10 -7 M. The sorption of Th(IV) was reduced at ISA concentrations above 2.10 -5 M and at GLU concentrations above 10 -6 M. The effects of ISA and GLU on the immobilisation of Eu(III) and Th(IV) were interpreted in terms of complex formation in solution. In the case of Eu(III) the metal ligand complexes were found to have a 1 : 1 stoichiometry. Complexation constants derived for the aqueous Eu(III)-ISA. and Eu(III)GLU complexes were determined to be logβ 0 EulSA = -31.1�

Strategic neighbourhood: EU-Europe versus EU-East

OpenAIRE

Rahr, Alexander

2004-01-01

"Russia and the EU are the strongest actors on the European continent of the 21st century. Will the strategic partnership between the EU and Russia unite the entire continent under a 'common European home' or will the continent be split in two? Russia joining the rest of Europe is set to proceed initially through the Energy Alliance." (author's abstract)

SPERA 98: radioactivity and the environment, environmental radioactivity and its application in environmental studies: conference papers

International Nuclear Information System (INIS)

1998-01-01

The 1998 workshop of the South Pacific Environmental Radioactivity Association (SPERA) was held in Christchurch, New Zealand. Presentations were grouped around the themes of soil erosion, waste disposal and treatment, atmospheric studies, radioactivity in water, human exposure pathways and foodchains, sediment studies and atmospheric radon. This volume contains extended abstracts. A list of participants is also included

Tipping the scale? Social media’s influences on EU attitudes and vote choice in the Danish 2015 EU referendum

DEFF Research Database (Denmark)

Ohme, Jakob

Citizens’ media use can be an important predictor of attitudes towards the European Union; those attitudes, in turn, can affect EU-related vote decisions. Elementary changes in the media environment and the increasing pressure on the EU in recent referendums may therefore be connected (e.g. Denmark...... in a referendum. Using a two-wave survey design (n=675), the study investigates if political social media use reinforces existing attitudes towards the EU. Subsequently, positive and negative polarization tendencies are connected to the ‘yes or no’ vote of Danish citizens in the 2015 EU referendum. The study...

Distribution of K, eU and Th and evaluation of annual radiation dose in the region of the Serra do Carambei Granite - PR; Distribuicao de K, eU e eTh e avaliacao da dose anual de radiacao na regiao do Granito Serra do Carambei - PR

Energy Technology Data Exchange (ETDEWEB)

Godoy, Luiz C., E-mail: luizcgodoy@brturbo.com.br [Departamento de Geociencias, Universidade Estadual de Ponta Grossa, PR (Brazil); Bittencourt, Andre V.L., E-mail: andre@ufpr.br [Laboratorio de Pesquisas Hidrogeologicas - LPH, Departamento de Geologia, Universidade Federal do Parana, Centro Politecnico, Curitiba, PR (Brazil); Santos, Leonardo J.C., E-mail: santos@ufpr.br [Laboratorio de Biogeografia e Solos - LABS, Departamento de Geografia, Universidade Federal do Parana, Centro Politecnico, Curitiba, PR (Brazil); Ferreira, Francisco J.F., E-mail: francisco.ferreira@ufpr.br [Laboratorio de Pesquisas em Geofisica Aplicada - LPGA, Departamento de Geologia, Universidade Federal do Parana, Centro Politecnico, Curitiba, PR (Brazil)

2011-04-15

is study was conducted in an area of 14 km in length oriented in the NNE direction by 7.3 km wide, covering the totality of the Serra do Carambei Granite and adjacent units. Located in the northern region of the Alagados dam, Parana State, this granite contains relatively high concentrations of K, eU and eTh, known since the 1970s through airborne and terrestrial gamma-ray spectrometry surveys. Recent radiochemical tests conducted on 61 samples of geological materials such as rocks (17 samples) and material of the weathering mantle and alluvial deposits (44 samples), confirmed the occurrence of radioactive anomalies in this granite, especially in thorium and uranium. The contents of K, eU and eTh obtained in gamma-ray spectrometry survey and radiochemical tests, converted to annual radiation dose (ARD), allowed to evaluate the intensity of natural radiation, whose levels relatively high in certain regions of the study area, can offer hazard to the local populations. The analysis and interpretation of data, as well the preparation of contour maps of K, eU and eTh were fundamental to understand the behavior and mobility of radionuclides in different environmental compartments of the area. (author)

Semiconductor studies by radioactive probe atoms

International Nuclear Information System (INIS)

Wichert, Thomas

2003-01-01

There are a growing number of experimental techniques that have in common the usage of radioactive isotopes for the characterization of semiconductors. These techniques deliver atomistic information about identity, formation, lattice environment, and electronic structure, as well as dynamics of defects and defect complexes. The results obtained by different hyperfine techniques are discussed in context with the study of intrinsic and extrinsic defects, i.e. of vacancies or self-interstitials and dopant or impurity atoms, respectively. In addition, the employment of electrical and optical techniques in combination with radioactive isotopes is presented

Radiation sources in the EU. A review of steps in the European Union

International Nuclear Information System (INIS)

Ciani, V.

1999-01-01

This article reviews the role and activities of the European Union concerning safety of radiation sources. A brief presentation is given of the results from a recent study of the management of radiation sources in EU Member Sates. A Number of legal texts which apply to radiation sources are cited as well. In 1998, the EC co-sponsored together with the IAEA, the International Criminal Police Organization and the World Customs Organization, a Conference on the safety of radiation Sources and the Security of Radioactive Materials in France. Commission supports follow-up actions to that Conference and welcomes the IAEA initiative to develop an action plan that would address the international dimensions of the safety of radiation sources

Synthesis and luminescent properties of Eu{sup 3+}/Eu{sup 2+} co-doped calcium aluminosilicate glass–ceramics

Energy Technology Data Exchange (ETDEWEB)

Bouchouicha, H. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Panczer, G., E-mail: gerard.panczer@univ-lyon1.fr [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Ligny, D. de [Universität Erlangen-Nürnberg, Department Werkstoffwissenschaften, Lehrstuhl für Glas und Keramik, D-91058 Erlangen (Germany); Guyot, Y. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Baesso, M.L. [Departemento de Fisica, Universidade Estadual de Maringa, 87020-900 Maringa, PR (Brazil); Andrade, L.H.C.; Lima, S.M. [Grupo de Espectroscopia Óptica e Fototérmica, Universidade Estadual de Mato Grosso do Sul – UEMS, C.P. 351, Dourados, MS (Brazil); Ternane, R. [Laboratoire d' Application de la Chimie aux Ressources et Substances Naturelles et à l' Environnement (LACReSNE), Université de Carthage, Faculté des Sciences de Bizerte, 7021 Zarzouna, Bizerte (Tunisia)

2016-01-15

Eu{sup 3+} and Eu{sup 2+} co-doped calcium aluminosilicate glass–ceramics have been prepared by devitrification of calcium aluminosilicate glass using heat-treatment. Control of crystallization in the glass–ceramics was studied by X-ray diffraction (XRD) and Raman spectroscopy. The results showed that crystalline phases in glass–ceramic belong to the family of melilite Ca{sub 2}Mg{sub 0.25}Al{sub 1.5}Si{sub 1.25}O{sub 7} as the major phase and anorthite CaAl{sub 2}Si{sub 2}O{sub 8} as the minor phase. Luminescent properties were investigated by emission; lifetime and the color points were calculated. Emission spectra showed that Eu{sup 2+} entered into the crystalline phase in a two steps mechanism: first as Eu{sup 3+} which is then reduced to Eu{sup 2+}. This incorporation in the crystal enhanced Eu{sup 2+} emission with increasing time of heat-treatment and therefore crystallization. - Highlights: • Crystallization of doped glass–ceramics by heat-treatment controlled by microRaman. • Crystalline phases consist of melilite and anorthite. • Eu{sup 3+} and Eu{sup 2+} emissions characterized by their lifetime and color indexes. • Crystallization process modified efficiently the emission color point.

Rotational states of odd Z rare earth proton emitter 131Eu

International Nuclear Information System (INIS)

Aggarwal, Mamta

2013-01-01

Recent observation of proton radioactivity and rotational bands in 131 Eu and 141 Ho with large deformations β ≈ 0.3 and γ softness have already proven the study of excited states of deformed proton emitters a source of valuable information on the structure of proton decaying states and response of proton emitters on the stress of rotation. The rare earth nuclei below the N = 82 shell closure form one of the few regions of the nuclear chart where nuclear shapes are expected to change rapidly with coexistence of oblate and prolate shapes in some nuclei. We evaluate shapes and deformation of 131 Eu by combining classical collective properties of the liquid drop model with the quantum corrections due to shell effects via Strutinsky formalism adequately described in. Excited states are treated using statistical theory. Nuclear shapes and deformation are traced by minimizing free energy (F = E-TS) w.r.t. deformation parameters β from 0 to 0.4 in steps of 0.01 and γ from -180° (oblate with symmetry axis parallel to the rotation axis) to -120° (prolate with symmetry axis perpendicular to rotation axis) and then to -60° (oblate collective) to 0° (prolate non-collective)

Study on serious road traffic injuries in the EU.

OpenAIRE

Aarts, L.T. Commandeur, J.J.F. Welsh, R. Niesen, S. Lerner, M. Thomas, P. Bos, N. & Davidse, R.J.

2016-01-01

It is the ambition of the EU to reduce the number of killed and seriously injured on the roads over time. It has turned out that, especially in relation to serious injuries, there is still a significant knowledge gap on how to reduce these numbers in the EU. The Commission is therefore committed to develop a particular focus on the serious road traffic injuries, to better understand their causes and effects. One of the first actions the Commission has undertaken is to develop a common definit...

Can EU Act as a Democracy Promoter? Analysing the Democratization Demand and Supply in Turkey - EU Relations

Directory of Open Access Journals (Sweden)

Çiğdem Üstün

2017-06-01

Full Text Available The EU’s role to assist Turkey in its democratization efforts has been debated during Turkey’s candidacy. However, in the second decade of the 21st century, this role of the EU lost its visibility while Turkey seemed to lose its interest in reform movements. This paper, inspired by Pevehouse, defines the EU as a supplier of democratization mechanisms and Turkey as an actor in need. Although lack of enthusiasm and disengagement have come to characterize Turkey-EU relations, this study aims to demonstrate that there are differences between the governing and the opposition actors’ views on the EU and its role in the democratization of Turkey. Data collected from the speeches of opposition parties’ parliamentarians between 1 January 2011 and 31 August 2016 demonstrates the similarities observed in these parties’ concerns regarding democratic practices and the perception of the EU as an actor strengthening democracy, while indicating that the EU, as a supplier, overlooked their concerns during the process.

ASSESSMENT OF RADIOACTIVE AND NON-RADIOACTIVE CONTAMINANTS FOUND IN LOW LEVEL RADIOACTIVE WASTE STREAMS

International Nuclear Information System (INIS)

R.H. Little, P.R. Maul, J.S.S. Penfoldag

2003-01-01

This paper describes and presents the findings from two studies undertaken for the European Commission to assess the long-term impact upon the environment and human health of non-radioactive contaminants found in various low level radioactive waste streams. The initial study investigated the application of safety assessment approaches developed for radioactive contaminants to the assessment of nonradioactive contaminants in low level radioactive waste. It demonstrated how disposal limits could be derived for a range of non-radioactive contaminants and generic disposal facilities. The follow-up study used the same approach but undertook more detailed, disposal system specific calculations, assessing the impacts of both the non-radioactive and radioactive contaminants. The calculations undertaken indicated that it is prudent to consider non-radioactive, as well as radioactive contaminants, when assessing the impacts of low level radioactive waste disposal. For some waste streams with relatively low concentrations of radionuclides, the potential post-closure disposal impacts from non-radioactive contaminants can be comparable with the potential radiological impacts. For such waste streams there is therefore an added incentive to explore options for recycling the materials involved wherever possible

Study of radio-active ions in the atmosphere

International Nuclear Information System (INIS)

Renoux, A.

1965-01-01

A comparative study is made of active, deposits of radon and thoron in suspension in the atmosphere by means of α radiation counting, using ZELENY tubes, scattering equipment, filter papers or membranes. It has been possible to show the existence of small and large ions which are negative and positive, as well as of neutral radio-active nuclei; their properties are studied. A theoretical interpretation of the results is presented. The average content of radon (using the Ra A concentration) and of Th B in the air has been determined. The radioactive equilibrium between radon and its daughter products in atmospheric air are examined. The techniques developed for active radon and thoron deposits are applied to the study of artificial radio-activity, the analyses being carried out by means of γ spectrometry. (author) [fr

Sm isotope composition and Sm/Eu ratio determination in an irradiated 153Eu sample by ion exchange chromatography-quadrupole inductively coupled plasma mass spectrometry combined with double spike isotope dilution technique

International Nuclear Information System (INIS)

Bourgeois, M.; Isnard, H.; Gourgiotis, A.; Stadelmann, G.; Gautier, C.; Mialle, S.; Nonell, A.; Chartier, F.

2011-01-01

Within the framework of the research undertaken by the French Atomic Energy Commission on transmutation of long-lived radionuclides, targets of highly enriched actinides and fission products were irradiated in the fast neutron reactor Phenix. Precise and accurate measurements of the isotopic and elemental composition of the enriched elements are therefore required. In order to obtain the uncertainties of several per mil and to reduce handling time and exposure to analyst on radioactive material, the on-line coupling of ion exchange chromatography with quadrupole inductively coupled plasma mass spectrometry has been associated with the technique of the double spike isotope dilution. We present in this paper the results obtained on an irradiated sample of Europium oxide powder (enriched at 99.13% in 153 Eu). After irradiation of around 5 mg of Eu 2 O 3 powder the theoretical calculations predict the formation of several micrograms of gadolinium and samarium isotopes. In relation to the very high activity of the sample after irradiation and the very low quantity of Sm formed, the on-line ion exchange chromatography separation of Gd, Sm and Eu before Sm isotope ratio measurements has been developed for the quantification of the 152 Sm/ 153 Eu ratio. These on-line measurements were associated with the double spike isotope dilution technique after calibration of a 147 Sm/ 151 Eu spike solution. The external reproducibility of Sm isotopic ratios was determined to be around 0.5% (2 σ) resulting in a final uncertainty on the 152 Sm/ 153 Eu ratio of around 1% (2 σ). These on-line measurements present therefore a robust and high-throughput alternative to the thermal-ionisation mass spectrometry technique used so far in combination with off-line chromatographic separation, particularly in nuclear applications where characterisation of high activity sample solutions is required. (authors)

Enlarging the EU's internal energy market: Why would third countries accept EU rule export?

International Nuclear Information System (INIS)

Prange-Gstoehl, Heiko

2009-01-01

Why would countries without a membership perspective seek integration into the EU's internal energy market? One major element of the EU's external energy policy is the export of EU energy norms and regulations to neighbourhood countries and beyond. A core legal instrument the EU uses in this context is the Energy Community Treaty (ECT). The ECT goes both geographically and regarding its depth significantly beyond neighbourhood or association policies, addressing potentially also countries in the 'far neighbourhood' and aiming at the creation of a Single Market for energy with these countries. While, however, EU candidate countries are obliged to adopt the 'acquis' before accessing the EU and therefore comply to EU rules already before they enter the Club, I argue that countries with no or only a vague membership perspective - i.e. countries where the EU cannot apply the 'conditionality' - approach (e.g., ENP countries)-aim at deeper integration with the EU because they are either eager to demonstrate their capability and potential to become part of the Club, they seek greater independence from a regional hegemon or they envisage significant economic gains as common norms, rules and standards are likely to increase economic exchange with the EU.

Carbon pricing in the EU: Evaluation of different EU ETS reform options

International Nuclear Information System (INIS)

Brink, Corjan; Vollebergh, Herman R.J.; Werf, Edwin van der

2016-01-01

This paper studies various options to support allowance prices in the EU Emissions Trading System (ETS), such as adjusting the cap, an auction reserve price, and fixed and variable carbon taxes in addition to the EU ETS. We use a dynamic computable general equilibrium model that explicitly allows for allowance banking and for a detailed cost-effectiveness analysis at the EU Member State level. We find that tightening the cap provides an ad hoc solution to the fundamental issue of the robustness of the effective carbon price, while introducing a price component to the ETS brings structural carbon price support in times of negative demand shocks for emission allowances. These price-based policies still benefit from the intertemporal flexibility through the banking provision in the EU ETS by re-allocating emissions over time with stronger emission reductions in early years and emission increases in later years. A higher emission price has a larger negative impact on the new Member States' economies than on other Member States. Furthermore, introducing a carbon tax in addition to the EU ETS decreases the price of allowances, resulting in welfare gains for net buyers of allowances while net sellers are worse off. - Highlights: • We analyse reform options for European Union Emission Trading System (EU ETS) with a CGE model. • Variable carbon tax and auction reserve price support carbon price at least cost. • Price-based reforms decrease early emissions but increase later emissions through banking. • New Member States' economies are affected more than others by higher CO_2 prices. • Lower allowance prices due to a carbon tax are unfavourable to net sellers of allowances.

Total neutron cross-sections of /sup 151/Eu, /sup 153/Eu and Eu below 1 eV

Energy Technology Data Exchange (ETDEWEB)

Adib, M.; Maayouf, R.M.A.; Abdel-Kawy, A.; Ashry, A.; Hamouda, I.

1981-01-01

Total neutron cross-section measurements have been carried out for natural Eu and its stable isotopes in the energy range from 3 meV to 1 eV. The measurements were performed using two time-of-flight spectrometers installed in front of two of the horizontal channels of the ET-RR-1 reactor. The following results have been obtained: sigmasub(a) (/sup 151/Eu) = (9180 +- 150) b at 0.0253 eV, sigmasub(s) (/sup 153/Eu) = (375 +- 20) b at 0.0253 eV, sigmasub(d) (Eu) = (4600 +- 120) b at 0.0253 eV. The contribution of the resonance to the total neutron cross-sections, in the thermal region, was calculated using the single-level Breit-Wigner formula.

Survey of radioactive contamination of foodstuffs

International Nuclear Information System (INIS)

Lee, W. R.; Lee, C. W.; Choi, G. S.; Cho, Y. H.; Kang, M. J.; Cheong, K. H.; Kim, H. R.; Kwak, J. Y.

2005-11-01

The purpose of this study is to survey and assess radioactive contamination of foodstuffs in order to reduce the probability of intake of contaminated foodstuffs. Based on survey and assessment, final goal is to improve the public health by radiation protection. Sampled foodstuffs items are collected from the markets : one group are imported foodstuffs and the other group are domestic foodstuffs producted around nuclear facilities. After pretreatments such as drying, ashing, and homogenization, all samples were analyzed by gamma spectrometer system. The 137 Cs radionuclide was only measured among the regulation radionuclides ( 137 Cs, 134 Cs, 131 I) of food code. All radionuclides of the domestic foodstuffs collected around nuclear facilities were below Minimum Detectable Activity (MDA). But the activity concentrations of Inonotus obliquus (Chaga mushooms) from Russia ranged up to 171.27 (average value : 36.65) Bq/kg-fresh. In the case of blueberry jam, the radioactivity of 137 Cs is higher than expected value. Other samples are below MDA except some spices. Based on the previous and present results, it should be strengthen to survey for Inontus obliquus (Chaga mushooms), of which the radioactivity shows the range from MDA up to 800.01 Bq/kg-fresh. It should assess the public radiation exposure via food chain because it has the excess provability of the maximum permitted level of food code, which is regulation of KFDA. The development method based on international standard would be used at radioactive analysis as well as education of practical workers and it could be applied as the basis data for amending the analysis method of food code. Our country only surveys gamma emitting radionuclides till now but international organization or foreign countries for example EU survey alpha and beta emitting radionuclides as well as gamma emitting radionuclides. So our country should also research necessity of survey for alpha and beta emitting radionuclides

Structural and photoluminescence studies of pure and Eu3+ doped Y2O3 oxide nanoparticles

International Nuclear Information System (INIS)

Packiyaraj, P.; Thangadurai, P.

2013-01-01

Pure and Eu 3+ doped Y 2 O 3 nanoparticles were synthesized by a hydrolysis assisted co-precipitation method. Structural characterization was carried out by X-ray diffraction. The as-prepared Eu:Y 2 O 3 was amorphous yttrium hydroxides in nature and become crystalline Y 2 O 3 once annealed at 600℃ and 900℃. The particle size (13-23 nm) was dependent on annealing temperatures and Eu 3+ ion concentration. Photoluminescence studies showed weak emission bands at 581, 587, 593, and 599 nm, corresponding to the 5 D 0 → 7 F 1 transitions, and sharp peaks with a maximum intensity occurring at 611 nm, due to the 5 D 0 → 7 F 2 transitions of Eu 3+ . (author)

Eestimaa.eu kuulub lätlasele ja riik.eu hollandlasele / Mikk Salu

Index Scriptorium Estoniae

Salu, Mikk, 1975-

2006-01-01

Zone Medias eu domeeninimesid registreeriva Jaanus Puttingu hinnangul on Eesti riik olnud passiivne EL-i domeeninime .eu sisaldavate lehekülgede kaitsmisel, sajad Eestile olulised domeeninimed on juba nii siinsete kui ka piiritaguste inimeste käes. Lisa: Rahvaliit.eu kuulub kinnisvaraportaalile

Preparation of EuSe nanoparticles from Eu(III) complex containing selenides

International Nuclear Information System (INIS)

Adachi, Taka-aki; Tanaka, Atsushi; Hasegawa, Yasuchika; Kawai, Tsuyoshi

2008-01-01

The EuSe nanoparticles were prepared by the thermal reduction of Europium nitrate with new organic selenium compound, tetraphenylphosphonium diphenylphosphinediselenide (PPh 4 )(Se 2 P(C 6 H 5 ) 2 ), for the first time. EuSe nanoparticles were identified by the X-ray diffraction (XRD), the transmission electron microscope (TEM) and the energy dispersive X-ray spectroscopy (EDX) measurements. The average size of the EuSe nanoparticles was found to be 19 nm. The energy gap in EuSe nanoparticles of 19 nm was estimated by edge of absorption band, giving the energy gap of 1.86 eV

Energy transfer mechanism in CsI:Eu crystal

International Nuclear Information System (INIS)

Yakovlev, V.; Trefilova, L.; Karnaukhova, A.; Ovcharenko, N.

2014-01-01

This paper studies the scintillation process in CsI:Eu crystal exposed to the pulse electron irradiation (E=0.25 MeV, t 1/2 =15 ns and W=0.003 J/cm 2 ). It has been proved that the energy transfer from the lattice to Eu 2+ ions in CsI:Eu occurs through the re-absorption of STE emission. The proposed model rests on the following experimental facts: (1) the activator emission at 2.68 eV rises gradually after the decay of the excitation pulse even at temperature lower than 90 K when V k centers are immobile; (2) the rise time of 2.68 eV emission and the decay time of STE emission have the same temperature dependences at T=78–300 K; (3) the excitation spectrum of 2.68 eV emission overlaps the emission spectrum of STE. -- Highlights: • The scintillation process in CsI:Eu was studied under pulsed electron irradiation. • A model of the energy transfer from the lattice to Eu 2+ ions in CsI:Eu was proposed. • Eu 2+ ions in CsI:Eu reabsorb the π-emission of self-trapped excitons

Extraction Separation of Am(III) and Eu(III) with Thermo-sensitive Gel introducing TPEN Derivatives

International Nuclear Information System (INIS)

Kenji Takeshita; Yoshio Nakano; Tatsuro Matsumura; Atsunori Mori

2008-01-01

A thermal-swing chromatographic process using a thermo-sensitive gel co-polymerized with NIPA (N-isopropyl-acrylamide) and TPPEN (N,N,N',N'-tetrakis(4-propenyl-oxy-2-pyridyl-methyl)ethylenediamine) was studied for the separation of Am(III) from Eu(III). First, the radiolysis of the TPPEN-NIPA gel was tested by the γ-ray irradiation and the α nuclide adsorption. The extraction separation of Am(III) was not influenced in the radioactive environment of the proposed process. Next, the TPPEN-NIPA gel was immobilized in porous silica particles and the applicability of the gel-immobilized silica to the proposed process was tested. Am(III) was extracted selectively in the gel-immobilized silica at 5 deg. C and the separation factor of Am(III) over Eu(III) was evaluated to be 3.7. The distribution ratio of Am(III) was reduced to less than 1/20 by increasing temperature from 5 deg. C to 40 deg. C. These results indicate that the TPPEN-NIPA gel is applicable to the thermal-swing chromatographic process for the minor actinide recovery. (authors)

Induced spin-polarization of EuS at room temperature in Ni/EuS multilayers

Energy Technology Data Exchange (ETDEWEB)

Poulopoulos, P., E-mail: poulop@upatras.gr [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Materials Science Department, University of Patras, 26504 Patras (Greece); Goschew, A.; Straub, A.; Fumagalli, P. [Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Kapaklis, V.; Wolff, M. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process and Energy Resources Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Wilhelm, F.; Rogalev, A. [European Synchrotron Radiation Facility (ESRF), B.P.220, 38043 Grenoble (France); Pappas, S. D. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden)

2014-03-17

Ni/EuS multilayers with excellent multilayer sequencing are deposited via e-beam evaporation on the native oxide of Si(100) wafers at 4 × 10{sup −9} millibars. The samples have very small surface and interface roughness and show sharp interfaces. Ni layers are nanocrystalline 4–8 nm thick and EuS layers are 2–4 nm thick and are either amorphous or nanocrystalline. Unlike for Co/EuS multilayers, all Eu ions are in divalent (ferromagnetic) state. We show a direct antiferromagnetic coupling between EuS and Ni layers. At room temperature, the EuS layers are spin-polarized due to the proximity of Ni. Therefore, Ni/EuS is a candidate for room-temperature spintronics applications.

Thermodynamic assessment of EuBr2 unary and LiBr-EuBr2 and NaBr-EuBr2 binary systems

International Nuclear Information System (INIS)

Gong, Weiping; Gaune-Escard, Marcelle

2009-01-01

As a basis for the design and development of molten salt mixtures, thermodynamic calculations of the phase diagrams and thermodynamic properties were carried out on the EuBr 2 unary and LiBr-EuBr 2 and NaBr-EuBr 2 binary systems over a wide temperature and composition range, respectively. The Gibbs energy of EuBr 2 was evaluated using an independent polynomial to fit the experimental heat capacity, the thermodynamic parameters for each phase in the LiBr-EuBr 2 and NaBr-EuBr 2 systems were optimized by using available experimental information on phase diagrams. A regular substitutional solution model for the liquid phase and Neumann-Kopp rule for the stoichiometric compound LiEu 2 Br 5 were adopted to reproduce the experimental data with reasonable excess Gibbs energy. Comparisons between the calculated phase diagrams and thermodynamic quantities show that all reliable experimental information is satisfactorily accounted for by the present thermodynamic description. Some thermodynamic properties were predicted to check the suitability of the present calculation.

Radioactive and geological analysis of airborne gamma spectrometric data for locating favorable traps for uranium prospecting in the Syrian desert (Area-1), Syria

International Nuclear Information System (INIS)

Asfahani, J.; Al-Hent, R.; Aissa, M.

2012-01-01

Statistical analysis has been applied to the airborne spectrometric data for the Syrian desert (Area-1), Syria in order to characterize and isolate the anomalous uranium radioactive zones. Equivalent uranium eU values vary between a minimum of 0.01 and a maximum of 32.74 ppm. Uranium prospecting methodology recently proposed is successfully applied in order to explain the origin of the radioactive anomalies related to Area-1. The dominant geological conditions effectively contributing to the uranium radioactive anomalies in the study area have been determined through the analysis of five radioactive-geological profiles. Different favorable traps have been identified and localized for uranium prospecting. Those uranium traps merit further detailed exploration for determining their uranium potential with depth. - Highlights: ► Determine the radioactive characteristics of Area-1. ► Apply a uranium prospecting methodology for guiding uranium exploration activities in Area-1. ► Explain the origin of the radioactive anomalies in Area-1. ► Relate the structural and geological conditions with the anomalous radioactive occurrences.

ENHANCING EU-TAIWAN ECONOMIC COOPERATION AGREEMENT

Directory of Open Access Journals (Sweden)

Chung-hung Cho

2018-01-01

Full Text Available The EU’s 2015 new trade strategy: Trade for all: toward a more responsible trade and investment policy, highlights its key role in keeping markets open worldwide and lists the Asia-Pacific region as the priority party for signing Regional Trade Arrangements (RTAs with the EU. The new strategy allows the EU and its member states to initiate talks on economic cooperation agreement (ECA with Taiwan. This article takes the EU-Asia interregional cooperation as a case study while exploring the role of Taiwan in the region. The first section describes the shift in EU’s trade policies and the special features of the types of interregionalism between the EU and Asia. The second section explores the bilateral trade relations. The third section evaluates the opportunities and the internal and external challenges and limitations of an EU-Taiwan ECA, emphasizing the factor of mainland China. The final section provides conclusions on the influence of an EU-Taiwan ECA on the relations of EUTaiwan considering economic and non-economic factor

Byg EU om

DEFF Research Database (Denmark)

Nedergaard, Peter

2017-01-01

Der argumenteres for en række påstande vedrørende en mulig ombygning af EU med henblik på at håndtere den krise, som unionen står i. Grundlæggende for dem alle er, at enten ombygges EU på disse områder, eller også smuldrer samarbejdet. Et internationalt samarbejde som EU kollapser ikke; det mister...

Photophysical study of blue-light excitable ternary Eu(III) complexes and their encapsulation into polystyrene nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Räsänen, Markus, E-mail: mpvras@utu.fi [Department of Chemistry, University of Turku, FIN-20014 Turku (Finland); Takalo, Harri [DHR Finland Oy, Innotrac Diagnostics, Biolinja 12, FIN-20750 Turku (Finland); Soukka, Tero [Department of Biochemistry/Biotechnology, University of Turku, FIN-20014 Turku (Finland); Haapakka, Keijo; Kankare, Jouko [Department of Chemistry, University of Turku, FIN-20014 Turku (Finland)

2015-04-15

In this work, 14 ternary Eu(III) complexes were studied by means of spectroscopy. The studied Eu(III) complexes consisted of Lewis bases (4′-(4-diethylaminophenyl)-2,2′:6′,2″-terpyridine (L{sup 8}) or 1,10-phenanthroline (L{sup 9})) and differently substituted β-diketones. The ternary complexes with L{sup 8} show the excitation peak at 405 nm and the quantum yield even 76%. The brightest ternary complex at the 405 nm excitation was Eu(L{sup 3}){sub 3}L{sup 8} while Eu(L{sup 7}){sub 3}L{sup 8} (HL{sup 3}=4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione, HL{sup 7}=1-(9-ethyl-9H-carbazol-3-yl)-4,4,5,5,5-pentafluoro-1,3-pentanedione) was found to be the brightest at the ligand-centred excitation maximum. The ternary complexes were studied mainly in toluene as the model environment for the polystyrene nanoparticle cavities. The complexes were successfully loaded into the polystyrene nanoparticles enabling their bioanalytical application in aqueous environment. The encapsulation of the complexes preserved, or even enhanced, their good photophysical features. - Highlights: • Ternary Eu{sup 3+} complexes with some β-diketone and substituted terpyridine were studied. • Ternary complexes with substituted terpyridine showed blue-light excitability. • Ternary complexes were successfully loaded into the polystyrene nanoparticles. • Encapsulation of the complexes preserved their good photophysical features.

EU Enlargement

DEFF Research Database (Denmark)

Pedersen, Peder J.; Pytlikova, Mariola

We look at migration flows from 8 Central and Eastern European Countries (CEECs) to 5 Nordic countries over the years 1985 - 2005 and we can exploit a natural experiment that arose from the fact that while Sweden opened its labour market from the day one of the 2004 EU enlargement, the other Nordic...... countries chose a transition period in relation to the "new" EU members. We employ a differences-in-differences estimator in our analysis. The results show that the estimated effect of the opening of Swedish labour market in 2004 on migration is insignificantly different from zero. Further, we...... are interested in the overall effect of the "EU entry" on migration. Therefore we look at migration flows from CEECs during the first round EU enlargement towards CEECs in 2004 and compare them with migration flows from Bulgaria and Romania. We again used a DD estimator in our analysis. The estimated effect...

Financial Integration into EU: The Romanian Case

Directory of Open Access Journals (Sweden)

Ibrahim Bozkurt

2016-05-01

Full Text Available The aim of this study is to investigate the determinants of integration between stock market of Romania and other stock markets of European Union (EU countries. Correlations between the stock returns represent the level of integration between the stock markets. Empirical analysis are performed with daily stock returns of 24 EU members including Romania for 2002-2012 period using panel data gravity models and correlations are investigated. Findings reveal that the following factors have significant and robust effects on the financial integration process of Romania with other 23 EU members; (i EU membership, (ii bilateral trade, (iii GDP per capita, (iv 2012 sovereign debt crisis and (v East European location. The results emphasize that intensifying economic relations with EU members can contribute the integration of Romanian stock market with other EU members. designed & hoste

The europium(II) oxide halides Eu{sub 2}OBr{sub 2} and Eu{sub 2}OI{sub 2}; Die Europium(II)-Oxidhalogenide Eu{sub 2}OBr{sub 2} und Eu{sub 2}OI{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Rudolph, Daniel; Schleid, Thomas [Stuttgart Univ. (Germany). Inst. fuer Anorganische Chemie

2017-07-01

The syntheses and crystal structures of the two isotypic europium(II) oxide halides Eu{sub 2}OBr{sub 2} and Eu{sub 2}OI{sub 2} are reported. They crystallize orthorhombically in the space group Ibam (Z=4; Eu{sub 2}OBr{sub 2}: a=709.86(5), b=1200.34(9), c=628.71(4) pm; Eu{sub 2}OI{sub 2}: a=739.78(5), b=1295.13(9), c=644.82(4) pm). The unit cell parameters presented here, and thus the interatomic distances of Eu{sub 2}OI{sub 2}, are significantly smaller than the ones reported in the literature, which is explained by the substitution of europium with larger barium cations due to the synthesis route described in the early study. Central building blocks of both crystal structures are trans-edge-connected [OEu{sub 4}]{sup 6+} tetrahedra forming straight {sup 1}{sub ∞}{[OEu"e_4_/_2]"2"+} chains running parallel to the [001] direction. Bundled like a hexagonal rod packing, their interaction is achieved by Br{sup -} or I{sup -} anions for charge compensation.

Marine radioactivity studies in the World Oceans (MARS)

International Nuclear Information System (INIS)

Povinec, P.P.; Togawa, O.

1999-01-01

The International Atomic Energy Agency's Marine Environment Laboratory is carrying out from 1996 a project with international participation 'Marine Radioactivity Studies in the World Oceans (MARS)'. The main objectives of the project are to provide new data on marine radioactivity and to develop a better understanding of the present radionuclide distribution in the open ocean. Within the framework of the project, various research activities are being carried out to fulfill the objectives: Coordinated Research Programme (CRP), scientific expeditions to the open ocean, development of a database for marine radioactivity, evaluation of radionuclide distributions and dose assessments. (author)

The Uptake of Eu(III) and Th(IV) by Calcite under Hyperalkaline Conditions

Energy Technology Data Exchange (ETDEWEB)

Tits, J.; Wieland, E.; Bradbury, M.H.; Eckert, P.; Schaible, A

2002-10-01

Calcite is an important component of Valanginian marl, a potential host rock for a low and intermediate level radioactive waste (L/ILW) repository in Switzerland. This mineral also forms an important component of the disturbed zone around a repository, as it remains largely unaffected by the hyperalkaline waters migrating out of the cementitious repository . The sorption behaviour of Eu(III) and Th(IV) on Merck calcite in an artificial cement pore water (ACW) at pH 13.3 has been studied in batch-type sorption experiments. In addition, the effect of {alpha}-isosaccharinic acid (ISA) and gluconic acid (GLU) on the sorption of these two cations has been investigated. In the absence of ISA and GLU, a strong interaction of Eu(III) and Th(IV) with Merck calcite was observed. Eu(III) and Th(IV) sorption kinetics were fast and the isotherms indicated a linear adsorption behaviour over the experimentally accessible concentration range. In the case of Eu(III), a decrease of the R{sub d} value with increasing solid to liquid (S:L) ratio was observed indicating that, along with adsorption, other processes might influence the immobilisation of this cation by Merck calcite under ACW conditions. In the case of Th(IV), however, changes in the S:L ratio had no effect on the sorption behaviour . High ISA and GLU concentrations in solution significantly affected the sorption of both Eu(III) and Th(IV): R{sub d} values for Eu(III) decreased significantly at ISA concentrations higher than 10{sup -5} M and at GLU concentrations higher than 10{sup -7} M. The sorption of Th(IV) was reduced at ISA concentrations above 2.10{sup -5} M and at GLU concentrations above 10{sup -6} M. The effects of ISA and GLU on the immobilisation of Eu(III) and Th(IV) were interpreted in terms of complex formation in solution. In the case of Eu(III) the metal ligand complexes were found to have a 1 : 1 stoichiometry. Complexation constants derived for the aqueous Eu(III)-ISA. and Eu(III)GLU complexes were

The quest for a European civic culture : The EU and EU Citizenship in policies and practices of citizenship education in seven EU member states

NARCIS (Netherlands)

Bakker, W.E.; van der Kolk, M.; Berkeley, Dominic; Koska, Viktor

2017-01-01

Since the Treaty of Maastricht (1992) all nationals of EU member states hold EU citizenship too. EU citizens hold EU citizenship rights in addition to their national rights. These rights include civil, social, economic and political rights. Holding these rights does not guarantee actual

The Limits of Conditionality: Turkey – EU Taxation Negotiations

Directory of Open Access Journals (Sweden)

Hakan Cavlak

2015-10-01

Full Text Available Conditionality is mostly defined as the EU policy engendered for candidate countries. However, the mere use of conditionality by the EU does not essentially explain transferring of policies and EU rules towards the candidate countries. EU conditionality may be considered as a comprising approach but in certain policy areas or countries it might not be as successful as it was on other ones. The EU conditionality basically defined as a bargaining policy of affecting through reward, under which the EU provides inducements to candidate or neighbor countries to aligning with the conditions of the EU. In this study the explanatory power of conditionality would be questioned; so the main question will be “to what extent does the EU have influence on policy convergence in a candidate country that does not have a clear membership perspective? Taxation chapter in accession negotiations between Turkey and the EU has been chosen as the case of this research as providing to have an answer on this question. The main objective of this paper is ‘analyzing the extent of EU conditionality on Turkish taxation policy.’ Furthermore, it is argued in this study that “without a concrete incentive, European Union’s impact on a candidate country would be limited.”  

Defect Engineering by Codoping in KCaI3 :Eu2 + Single-Crystalline Scintillators

Science.gov (United States)

Wu, Yuntao; Li, Qi; Jones, Steven; Dun, Chaochao; Hu, Sheng; Zhuravleva, Mariya; Lindsey, Adam C.; Stand, Luis; Loyd, Matthew; Koschan, Merry; Auxier, John; Hall, Howard L.; Melcher, Charles L.

2017-09-01

Eu2 + -doped alkali or alkali earth iodide scintillators with energy resolutions ≤3 % at 662 keV promise the excellent discrimination ability for radioactive isotopes required for homeland-security and nuclear-nonproliferation applications. To extend their applications to x-ray imaging, such as computed tomography scans, the intense afterglow which delays the response time of such materials is an obstacle that needs to be overcome. However, a clear understanding of the origin of the afterglow and feasible solutions is still lacking. In this work, we present a combined experimental and theoretical investigation of the physical insights of codoping-based defect engineering which can reduce the afterglow effectively in KCaI3:Eu2 + single-crystal scintillators. We illustrate that Sc3 + codoping greatly suppresses the afterglow, whereas Y3 + , Gd3 + , or La3 + codoping enhances the afterglow. Meanwhile, a light yield of 57 000 photons / MeV and an energy resolution of 3.4% at 662 keV can be maintained with the appropriate concentration of Sc3 + codoping, which makes the material promising for medical-imaging applications. Through our thermoluminescence techniques and density-functional-theory calculations, we are able to identify the defect structures and understand the mechanism by which codoping affects the scintillation performance of KCaI3:Eu2 + crystals. The proposed defect-engineering strategy is further validated by achieving afterglow suppression in Mg2 + codoped KCaI3:Eu2 + single crystals.

Electronic Structure of Eu6C60

Institute of Scientific and Technical Information of China (English)

WANG Xiao-Xiong; LI Hong-Nian; XU Ya-Bo; WANG Peng; ZHANG Wen-Hua; XU Fa-Qiang

2009-01-01

We study the valence band of Eu-intercalated C60 by synchrotron radiation photoelectron spectroscopy to un-derstand the ferromagnetism (FM) and the giant magnetoresistance (GMR) of Eu6C60. The results reveal the semiconducting property and the remarkable 5d6s-π hybridization. Eu-C60 bonding has both ionic and covalent contributions. No more than half the 5d6s electrons transfer from Eu to the LUMO derived band of C60, and the LUMO+1 derived band is not filled. The remaining valence electrons of Eu, together with some π (LUMO, HOMO and HOMO-1) electrons, constitute the covalent bond. The electronic structure implies that the magnetic coupling in Eu6C60 should be through the intra-atomic f-sd exchange and the medium of the π electrons. The possibility of the GMR being tunnelling magnetoresistance is ruled out.

Poland - Electricity and gas marked development study and practical guidelines for using EU funds. Practical guidelines for using EU funds for energy projects

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-12-01

The present report is prepared as part of the project 'Poland - Electricity and gas market development study and practical guidelines for using EU - funds'. The EU structural and cohesion funds are presently considered the most relevant funds concerning support to energy projects. In general, the Polish administration of the EU structural funds is strongly decentralized. The eligible project types to be supported from the various structural funds are described in a number of sector programmes. The sector programmes are described in vertical view, meaning that it is difficult to assess what kind of energy projects are eligible for support and, if eligible, then under which programme. This report presents a horizontal view of the various programmes in order to give an overview of the possibilities of support to energy related projects. The background for this report is a study of the following sector programmes: 1. Improvement of the competitiveness of enterprises. 2. Human resources development. 3. Restructuring and modernization of food sector and rural development. 4. Fisheries and fish processing. 5. Transport - maritime economy. 6. Integrated regional operational programme. 7. Technical assistance. Based on this review, it can be stated that energy projects in general have a low priority but can be supported under various measures within the programmes. (BA)

2002 electricity statistics: EU and EU+

International Nuclear Information System (INIS)

Anon.

2003-01-01

Electricity generation in the European Union (EU) decreased by 0,7% in the period of 2001 to 2002, reaching 2521,3 billion kWh. Developments varied in different countries. Conventional thermal power plants generated 1340,1 billion kWh, which corresponds to a 53.0% share in the total generation and an increase by 2.7% over the level in the previous year. Generation in nuclear power plants increased by 2.7% to 855.5 billion kWh, which corresponds to a 33,8% share in EU-wide generation. Hydroelectric plants and other plants supplied 15.2% less electricity. Eurostat statistics do not differentiate these data any further. The volume of 332.2 kWh is tantamount to a 13.1% share. In the new EU member countries and the candidate countries, electricity generation showed a moderate increase by 0.4% and 2.1%, respectively. While generation both in conventional power plants and in other plants decreased, a considerable increase is shown for nuclear power generation of +13.5% and +10.6%, respectively [de

Densification, characterization and oxidation studies of novel TiB{sub 2}+EuB{sub 6} compounds

Energy Technology Data Exchange (ETDEWEB)

Murthy, T.S.R.Ch., E-mail: murthi@barc.gov.in [Materials Group, Bhabha Atomic Research Centre, Mumbai (India); Sonber, J.K.; Vishwanadh, B. [Materials Group, Bhabha Atomic Research Centre, Mumbai (India); Nagaraj, A. [Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Mumbai (India); Sairam, K.; Bedse, R.D.; Chakravartty, J.K. [Materials Group, Bhabha Atomic Research Centre, Mumbai (India)

2016-06-15

TiB{sub 2}+EuB{sub 6} ceramic samples with different EuB{sub 6} contents were fabricated using hot -pressing technique. The introduction of EuB{sub 6} promoted the sinterability, fracture toughness and oxidation resistance of TiB{sub 2}. 98.7% TD achieved by adding 2.5% EuB{sub 6} to TiB{sub 2} by hot pressing at a relatively low temperature of 1750 °C, 35 MPa, 1h. Formation of complete solid solution of TiB{sub 2}+EuB{sub 6} observed for all the samples by XRD, EDS and EBSD. Hardness of all samples is measured in the range of 24–27 GPa ∼50% higher fracture toughness value of 5.2 MPa m{sup 1/2} was obtained in the 2.5% EuB{sub 6} contained sample compared to monolithic TiB{sub 2}. Enhancement of oxidation resistance of TiB{sub 2} was observed by EuB{sub 6} addition due to the formation of EuBO{sub 3} and Eu{sub 2}O{sub 3}. Oxidized cross section of TiB{sub 2}+EuB{sub 6} sample was measured as 340 μm, which is ∼35% less than that of monolithic TiB{sub 2} (520 μm), after oxidation at 1400 °C for 8h. - Highlights: • 98.7% TD achieved by adding 2.5% EuB{sub 6} to TiB{sub 2}. • Formation of complete solid solution of TiB{sub 2}+EuB{sub 6} observed. • Fracture toughness value of 5.2 MPa m{sup 1/2} was obtained in the TiB{sub 2}+2.5% EuB{sub 6}. • EuBO{sub 3} and Eu{sub 2}O{sub 3} are enhanced the oxidation resistance of TiB{sub 2} + EuB{sub 6} compound. • Oxide layer thicknesses of TiB{sub 2} and TiB{sub 2}+EuB{sub 6} are 520 μm and 340 μm respectively.

A first-principles study of B2 NiAl alloyed with rare earth elements Pr, Pm, Sm, and Eu

Institute of Scientific and Technical Information of China (English)

He Jun-Qi; Wang You; Yan Mu-Fu; Pan Zhao-Yi; Guo Li-Xin

2013-01-01

The structural,elastic,and electronic properties of NiAl alloyed with rare earth elements Pr,Pm,Sm,and Eu are investigated by using density functional theory (DFT).The study suggests that Pr,Pm,Sm,and Eu all tend to be substituted for an Al site.Ni8Al7Pm possesses the largest ductility.Only the hardness and ductility of Ni8Al7Eu are enhanced simultaneously.The covalency strength of the Ni-Al bond in Ni8Al7Pm is higher than that in Ni8Al7Eu.The covalency strength of an Al-Al bond and that of a Ni-Ni bond in Ni8Al7Eu are higher than that in Ni8Al7Pm.The Ni-Pm bond and the Ni-Eu bond are covalent,and the covalency strength of the Ni-Pm bond is greater.The Al-Pm bond and the Al-Eu bond show great covalency strength and ionicity,respectively.

Modelling Eu(III) speciation in a Eu(III)/PAHA/α-Al2O3 ternary system

International Nuclear Information System (INIS)

Janot, Noemie; Reiller, Pascal E.; Benedetti, Marc F.

2013-01-01

In this work, modelling of Eu(III) speciation in a ternary system, i.e., in presence of purified Aldrich humic acid (PAHA) and α-Al 2 O 3 , is presented. First, the mineral surface charge is measured by potentiometric titrations and then described using the CD-MUSIC model. This model is also used to describe Eu(III) binding to the α-Al 2 O 3 surface at different pH values, ionic strength and mineral concentrations. Time resolved luminescence spectroscopy (TRLS) is then used to study the binding of Eu(III) to PAHA at pH 4 with different humic acid concentrations. The spectra are used to calculate a spectroscopic 'titration curve', used to determine Eu(III)/PAHA binding parameters in the NICA-Donnan model. Following a previous study (Janot et al., Water Res. 46, 731-740), modelling of the ternary system is based upon the definition of two PAHA pools where one fraction remains in solution and the other is adsorbed onto the mineral surface, with each possessing different proton and metal binding parameters. The modification of protonation behaviour for both fractions is examined using spectrophotometric titrations of the non adsorbed PAHA fraction at different organic/mineral ratios. These data are then used to describe Eu(III) interactions in the ternary system: Eu(III) re-partitioning in the ternary system is calculated for different pH, ionic strength and PAHA concentrations, and results are compared to experimental observations. The model is in good agreement with experimental data, except at high PAHA fractionation rates. Results show that organic complexation dominates over a large pH range, with the predominant species existing as the surface-bound fraction. Above pH 8, Eu(III) seems to be mostly complexed to the mineral surface, which is in agreement with previous spectroscopic observations (Janot et al., Environ. Sci. Technol. 45, 3224-3230). (authors)

Comparative study on Climate Change Policies in the EU and China

Science.gov (United States)

Bray, M.; Han, D.

2012-04-01

environment change, formation mechanism and prediction theory of major climate and weather disasters in China, technologies of efficient use of clean energy, energy conservation and improvement of energy efficiency, development and utilisation technology of renewable energy and new energy. The EU recognises that developing countries, such as China and India, need to strengthen their economies through industrialisation. However this needs to be achieved at the same time as protecting the environment and sustainable use of energy. The EU has committed itself to assisting developing countries to achieve their goals in four priority areas: 1) raising the policy profile of climate change; 2) support for adaption to climate change; 3) support for mitigation of climate change; and 4) capacity development. This comparative study is part of the EU funded SPRING project which seeks to understand and assess Chinese and European competencies, with the aim of facilitating greater cooperation in future climate and environment research.

Future radioactive liquid waste streams study

Energy Technology Data Exchange (ETDEWEB)

Rey, A.S.

1993-11-01

This study provides design planning information for the Radioactive Liquid Waste Treatment Facility (RLWTF). Predictions of estimated quantities of Radioactive Liquid Waste (RLW) and radioactivity levels of RLW to be generated are provided. This information will help assure that the new treatment facility is designed with the capacity to treat generated RLW during the years of operation. The proposed startup date for the RLWTF is estimated to be between 2002 and 2005, and the life span of the facility is estimated to be 40 years. The policies and requirements driving the replacement of the current RLW treatment facility are reviewed. Historical and current status of RLW generation at Los Alamos National Laboratory are provided. Laboratory Managers were interviewed to obtain their insights into future RLW activities at Los Alamos that might affect the amount of RLW generated at the Lab. Interviews, trends, and investigation data are analyzed and used to create scenarios. These scenarios form the basis for the predictions of future RLW generation and the level of RLW treatment capacity which will be needed at LANL.

Future radioactive liquid waste streams study

International Nuclear Information System (INIS)

Rey, A.S.

1993-11-01

This study provides design planning information for the Radioactive Liquid Waste Treatment Facility (RLWTF). Predictions of estimated quantities of Radioactive Liquid Waste (RLW) and radioactivity levels of RLW to be generated are provided. This information will help assure that the new treatment facility is designed with the capacity to treat generated RLW during the years of operation. The proposed startup date for the RLWTF is estimated to be between 2002 and 2005, and the life span of the facility is estimated to be 40 years. The policies and requirements driving the replacement of the current RLW treatment facility are reviewed. Historical and current status of RLW generation at Los Alamos National Laboratory are provided. Laboratory Managers were interviewed to obtain their insights into future RLW activities at Los Alamos that might affect the amount of RLW generated at the Lab. Interviews, trends, and investigation data are analyzed and used to create scenarios. These scenarios form the basis for the predictions of future RLW generation and the level of RLW treatment capacity which will be needed at LANL

Studies on shallow traps in Li2B4O7:Eu,Mn

International Nuclear Information System (INIS)

Drozdowski, Winicjusz; Brylew, Kamil; Kaczmarek, Sławomir M.; Piwowarska, Danuta; Nakai, Yosuke; Tsuboi, Taiju; Huang, Wei

2014-01-01

Li 2 B 4 O 7 (LTB) single crystals doped with 0.5 mol% Mn and 0.005 mol% Eu have been grown by the Czochralski method. The presence of Eu 3+ has been confirmed by photoluminescence spectra of non-irradiated crystals, whereas the presence of Mn 2+ by absorption spectra of gamma-irradiated ones, as well as by EPR measurements. Unlike in most thermoluminescence studies on pure and doped LTB, performed usually above 300 K, glow curves have been recorded between 10 and 300 K in order to focus the attention on shallow traps. A broad, intense glow peak is observed around 80 K, with three weaker peaks at 205, 255, and 280 K. Based on supplementary T max  − T stop experiments, the trap parameters have been derived assuming that the glow curve is in fact formed by a superposition of a double Gaussian band related to a quasi-continuous distribution of trapping levels, and several glow peaks produced by discrete traps. The nature of the traps is also discussed. - Highlights: • Radioluminescence spectra of LTB:Eu,Mn have been measured at various temperatures. • Glow curves of LTB:Eu,Mn have been recorded between 10 and 300 K. • Thermoluminescence studies have been extended with the T max  − T stop method. • Trap parameters related to particular glow peaks have been derived. • Besides discrete traps a quasi-continuous distribution has been found

EU emissions trading: Distinctive behavior of small companies

OpenAIRE

Naegele, Helene; Zaklan, Aleksandar

2016-01-01

The EU Emissions Trading System (EU ETS) is the cornerstone of the European Union's climate policy and covers just under half of the EU's greenhouse gas emissions. More than ten years since the EU ETS was first introduced, there continues to be substantial research interest regarding its functioning and the behavior of participating companies. DIW Berlin conducted three econometric studies based on microdata at company and/or installation level. The findings suggest that, overall, there are o...

Can EU Act as a Democracy Promoter? Analysing the Democratization Demand and Supply in Turkey - EU Relations

OpenAIRE

Çiğdem Üstün

2017-01-01

The EU’s role to assist Turkey in its democratization efforts has been debated during Turkey’s candidacy. However, in the second decade of the 21st century, this role of the EU lost its visibility while Turkey seemed to lose its interest in reform movements. This paper, inspired by Pevehouse, defines the EU as a supplier of democratization mechanisms and Turkey as an actor in need. Although lack of enthusiasm and disengagement have come to characterize Turkey-EU relations, this study aims to ...

First-principles studies of Ce and Eu doped inorganic scintillator gamma ray detectors

Science.gov (United States)

Canning, Andrew; Chaudhry, Anurag; Boutchko, Rostyslav; Derenzo, Stephen

2011-03-01

We have performed DFT based band structure calculations for new Ce and Eu doped wide band gap inorganic materials to determine their potential as candidates for gamma ray scintillator detectors. These calculations are based on determining the 4f ground state level of the Ce and Eu relative to the valence band of the host as well as the position of the Ce and Eu 5d excited state relative to the conduction band of the host. Host hole and electron traps as well as STEs (self trapped excitons) can also limit the transfer of energy from the host to the Ce or Eu site and therefore limit the light output. We also present calculations for host hole traps and STEs to compare the energies to the Ce and Eu excited states. The work was supported by the U.S. Department of Homeland Security and carried out at the Lawrence Berkeley National Laboratory under U.S. Department of Energy Contract No. DE-AC02- 05CH11231.

EuCARD final project report

CERN Document Server

Koutchouk, J P

2014-01-01

After four years of activity, EuCARD has most of its objectives fulfilled, with some new objectives added and a few others on excellent tracks while requiring additional time. The management has been active in reinforcing the collaborative links between partners and projects, contributing to the preparation of FP7-EuCARD2, initiating FP7-HiLumi-LHC Design Study, to favour sustained collaborations beyond EuCARD. An out-of-contract network has been successfully launched on laser plasma acceleration, to combine forces between accelerator, laser and plasma communities. Communication and dissemination activities have led to two highlights: Accelerating News, an accelerator R&D newsletter initiated by EuCARD and now common to all FP7 accelerator projects (over 1000 subscribers) and a series of monographs on accelerator sciences that is progressively finding its public. The scientific networks have more than fulfilled their initial objectives: roadmaps are defined for neutrino facilities, submitted to the Europe...

Creating EU law judges

DEFF Research Database (Denmark)

Mayoral Diaz-Asensio, Juan Antonio; Jaremba, Urszula; Nowak, Tobias

2014-01-01

The judicial protection system in the European Union (EU) is premised on the fact that national judges are supposed to act as decentralized EU judges. This role is exercised through tools enshrined in, inter alia, primacy, direct and indirect effect of EU law, and the preliminary ruling procedure...

X-ray excited optical luminescence, photoluminescence, photostimulated luminescence and x-ray photoemission spectroscopy studies on BaFBr:Eu

CERN Document Server

Subramanian, N; Govinda-Rajan, K; Mohammad-Yousuf; Santanu-Bera; Narasimhan, S V

1997-01-01

The results of x-ray excited optical luminescence (XEOL), photoluminescence (PL), photostimulated luminescence (PSL) and x-ray photoemission spectroscopy (XPS) studies on the x-ray storage phosphor BaFBr:Eu are presented in this paper. Analyses of XEOL, PL and PSL spectra reveal features corresponding to the transitions from 4f sup 6 td sup 1 to 4f sup 7 configurations in different site symmetries of Eu sup 2 sup +. Increasing x-ray dose is seen to lead to a red shift in the maximum of the PL excitation spectrum for the 391 nm emission. The XEOL and XPS spectra do not show any signature of Eu sup 3 sup + in the samples studied by us, directly raising doubts about the model of Takahashi et al in which Eu sup 2 sup + is expected to ionize to Eu sup 3 sup + upon x-ray irradiation and remain stable until photostimulation. XEOL and PSL experiments with simultaneous x-ray irradiation and He - Ne laser excitation as well as those with sequential x-ray irradiation and laser stimulation bring out the competition betwe...

Valence behavior of Eu-ions in intermetallic compound Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5}

Energy Technology Data Exchange (ETDEWEB)

Pandey, Abhishek, E-mail: apandey@ameslab.gov [Experimental Condensed Matter Physics Division, Saha Institute of Nuclear Physics, 1/AF, Bidhannagar, Kolkata 700064 (India); S.N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India); Mazumdar, Chandan, E-mail: chandan.mazumdar@saha.ac.in [S.N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India); Ranganathan, R. [S.N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India); Raghavendra Reddy, V.; Gupta, Ajay [UGC-DAE Consortium for Scientific Research, University Campus, Khandawa Road, Indore (India)

2011-12-15

We have studied the valence behavior of rare-earth ions, in particular Eu-ions, in a cubic intermetallic compound Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5} which is a homogeneous solid solution of two mixed-valent compounds CePd{sub 3} and EuPd{sub 3}B. Results of {sup 151}Eu Moessbauer spectroscopic measurements show that two different valence states, i.e., divalent- and trivalent-like states of Eu-ions exist in the compound. The possible reason for the observed heterogeneous valency vis-a-vis the variation in the chemical environment and the number of nearest-neighbor B atoms surrounding the Eu-ions has been discussed. Our results demonstrate that B incorporation in such Eu-based cubic intermetallic compounds leads to a situation where heterogeneous-valence state of Eu-ions is an energetically favorable ground state. - Highlights: > Intermetallic compound Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5} crystallizes in a single phase. > Eu-ions in Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5} are charge-ordered compared to +2.3 valency in Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}. > B incorporation makes charge-ordered state of Eu-ions energetically more favorable. > Nearest-neighbor chemical environment affects the Eu valency.

The Eu as a strategic global policy actor

DEFF Research Database (Denmark)

Chatzopoulou, Sevasti; Ansell, Christopher

that shapes and is being shaped by the EU strategic choices. This process is facilitated by the existing EU institutions and structures, the administrative and technical expertise capacity when it responds to the internal and external challenges (environment, sustainable development climate and circular......This article aims to complement the existing literature on the EU as a global actor and demonstrates that the EU’s entrepreneurship on policy, ideas and knowledge production contributes to the evolution of the EU as a strategic global policy actor. While the number of significant studies on the EU...... as a global actor proliferated the last decades, these studies concentrate on the EU’s role in a fragmented manner, focusing either on specific normative or more economic and trade issues, and thus often competing between themselves. This article acknowledges these contributions and aims to take them further...

Optical measurements on iron pnictides containing Eu

Energy Technology Data Exchange (ETDEWEB)

Neubauer, David; Baumgartner, Andreas; Merz, Johannes; Zapf, Sina; Dressel, Martin [1. Physikalisches Institut, Universitaet Stuttgart (Germany); Aswartham, Saicharan [University of Kentucky, Lexington (United States); Wurmehl, Sabine [IFW, Dresden (Germany); Jiao, Wen-He; Cao, Guang-Han [Zhejiang University, Hangzhou (China)

2015-07-01

The interplay of magnetism with superconductivity is a fascinating, highly debated field of research and many questions still remain unsolved. Members of the EuFe{sub 2}As{sub 2} family are a perfectly suited playground for investigations concerning this topic, due to the peculiarity of strong local magnetism of the europium (T{sub N}∼ 20K), which is a unique feature among the 122 iron pnictides. Optical studies of the parent compound have already revealed that the spin density wave formation deviates from the other 122 pnictides. To get more insight into the superconducting properties of the EuFe{sub 2}As{sub 2} family we carried out an optical study on differently doped samples. We compare Eu(Fe{sub 1-x}Ir{sub x}){sub 2}As{sub 2} where electron doping takes place directly in the conducting iron layer, with EuFe{sub 2}(As{sub 1-x}P{sub x}){sub 2} which corresponds to isovalent substitution at atomic positions out of the Fe-plane. The influence of the Eu is furthermore investigated by placing data we obtained on Ba{sub 0.6}Eu{sub 0.4}(Fe{sub 1-x}Co{sub x}){sub 2}As{sub 2} in juxtaposition to the already highly investigated pure Ba analogue.

MANAGING RENEWABLE ENERGY IN THE EU10 REGION

Directory of Open Access Journals (Sweden)

BUCUREAN Mirela

2011-07-01

Full Text Available The problems of renewable energy and regional development have gained a global dimension, as well as the concerns about the economic growth. Therefore, this study investigates the issue of managing renewable energy in the EU10 region, within the context of recovery and anticipated growth of the region. The findings of this study disclose that an important source of economic growth in the EU10 region's countries may be to start some new investments in renewable energy. In order to develop the field of renewable energy may be used EU funds, and may be envisaged different public-private partnership models, that may contribute to lower societal costs and increased deployment rates. The study was conducted by combining a wide variety of sources, such as statistics, reports and articles. The results reported in this study could be used for further research in the area of implementing green energy projects in the EU10 region. Another direction for further research could be to identify the most attractive countries for different renewable energy investment projects in the EU10 region.

EU-Russia Cultural Relations

Directory of Open Access Journals (Sweden)

Elena Sidorova

2014-05-01

Full Text Available This article analyzes the link between culture and diplomacy between Russia and the European Union, and shows the importance of cultural relations. It examines the common space of science, education and culture introduced at the 2003 EU-Russia Summit in St. Petersburg and the application of the principles of this concept that were established at the 2005 EU-Russia Summit in Moscow. It then considers EU-Russia collaboration on humanitarian action and the challenges that both parties face in this sphere. It also explains the formation of EU domestic and foreign cultural policy, and the role of European institutions and states in cultural affairs and diplomacy, as well as key elements and mechanisms of contemporary Russian foreign cultural policy. In addition, the article focuses on the European side of post-Soviet EU-Russia cultural relations. This cultural collaboration is defined as a competitive neighbourhood. EU and Russian interests collide: while Europeans try to promote their values, norms and standards within the framework of the European Neighbourhood Policy, Russia seeks to culturally influence and engage in this region for geostrategic and historical reasons. Finally, the article assesses the prospects for the EU-Russia cultural relations and emphasizes the role of ideology in improving such relations.

EU's lille sikkerhedsnet

DEFF Research Database (Denmark)

Rangvid, Jesper

2014-01-01

I forrige uge indgik EU-kommissionen og EU-Parlamentet en aftale om en fælles afviklingsmekanisme i bank-unionen (Single Resolution Mechanism; SRM). ... Så på trods af mere kapital, nye bail-in regler og afviklingsfonden tror jeg ikke, at det kan udelukkes, at fremtidige "bankredninger" kan...... nødvendigøre statslige midler. Hertil er fonden trods alt for begrænset. ... Proceduren er, at ECB indstiller til SRM's bestyrelse, at en bank skal afvikles, hvorefter EU-kommissionen og nationale tilsynsmyndigheder involveres....

Antidumping duties, undertakings and foreign direct investment in the EU

NARCIS (Netherlands)

Belderbos, R.A.; Vandenbussche, H.; Veugelers, R.

2004-01-01

We study the effects of EU antidumping policy when foreign firms can ‘jump’ antidumping duties through foreign direct investment (FDI) in the EU. We show that duty jumping or duty pre-empting FDI occurs if the EU administration has broader objectives than protecting EU industry's profitability and

Complexation of Cucurbit(7)uril with Eu(III)

International Nuclear Information System (INIS)

Kar, Aishwarya; Rawat, Neetika; Rao, Ankita; Tomar, B.S.; Nayak, S.K.; Ray, Alok

2014-01-01

Cucurbiturils (CBs) CB(n)s are macrocyclic molecules with carbonyl groups at the portals, which bind cations through ion dipole interactions and the cavity which stabilize hydrophobic moieties. The size of the portal and the volume of the interior cavities of CB(n)s are dependent on the number of glycoluril units present in CBs. CBs are widely used as supramolecular host systems in applications, such as formation of supramolecular hydrogels, drug delivery systems. Though the binding of CBs with organic guest molecules have been studied extensively where as metal complexation studies are very few. In the present work, complexation studies of Cucurbit(7)uril (with seven glycouril units, CB7) with Eu(III) were carried out using fluorescence, UV-vis spectrophotometry. The stability constant for 1:1 complex CB7-Eu(III) complex determined by monitoring the change in CB7 UV- vis absorption spectra on addition of Eu(III) was found to be 2.99 ± 0.08. The fluorescence spectra of increasing ligand to metal ratio exhibited the increase in the intensity ratio of peak at 616 and 592 which is the measure of complexation of Eu(III) with CB7 and was used to deduce the stability constant and the value (2.82 ± 0.07) obtained was in good agreement with that obtained from UV vis spectroscopy. Further, the life time of Eu(III) ion, which increased with CB7 to Eu(III) ratio, was used to deduce number of water molecules around Eu(III) metal ion which were found to decrease from 9 to 3 thereby suggesting inner sphere complexation. The stability constant of CB7 with Eu(III) is one order of magnitude less than CB5, derived in separate study by authors. The smaller cavity of CB5 (2.4 A 0 ) favors its interactions with Eu(III) ion of comparable diameter (2.16 A 0 ) leading to higher stability constant compared to CB7 (5.4 A 0 ) having larger cavity

National Courts and EU Law

DEFF Research Database (Denmark)

approaches and theories originating from law, political science, sociology and economics. The first section addresses issues relating to judicial dialogue and EU legal mandates, the second looks at the topic of EU law in national courts and the third considers national courts’ roles in protecting fundamental......, National Courts and EU Law will hold strong appeal for scholars and students in the fields of EU law, social sciences and humanities. It will also be of use to legal practitioners interested in the issue of judicial application of EU law....

Spectroscopy Study on the Location and Distribution of Eu3+ Ions in TiO2 Nanoparticles

Science.gov (United States)

Tsuboi, Taiju; Setiawati, Elly; Kawano, Katsuyasu

2008-09-01

Eu3+- and non-doped TiO2 nanoparticles were synthesized by the sol-gel method at sintering temperatures of 500 or 900 °C. The photoluminescence spectra of these nanoparticles have been investigated at various temperatures between 290 and 12 K. Two kinds of Eu3+ photoluminescence spectra were observed. One spectrum consists of sharp lines; the other consists of broad bands. The former was obtained by indirect excitation into Eu3+ with light of wavelengths shorter than 330 nm, while the latter was obtained by direct excitation into Eu3+ with light of wavelengths longer than 380 nm which correspond to the Eu3+ absorption bands. In the latter case, different spectra were obtained depending on the excitation wavelength even in the same absorption band. It is suggested that the sharp line spectrum is caused by Eu3+ ions substituted for Ti4+ but with some distortion around the Eu3+ ions in the matrix of TiO2 due to the large difference in ionic radius between the Ti4+ and Eu3+ ions, which are mainly present in the interior region of the nanoparticle. The broad band spectrum is caused by the disordered Eu3+ ions with Eu-O-Ti bonds which are predominantly present in the near surface region.

Utilization of natural hematite as reactive barrier for immobilization of radionuclides from radioactive liquid waste.

Science.gov (United States)

El Afifi, E M; Attallah, M F; Borai, E H

2016-01-01

Potential utilization of hematite as a natural material for immobilization of long-lived radionuclides from radioactive liquid waste was investigated. Hematite ore has been characterized by different analytical tools such as Fourier transformer infrared (FTIR), X-ray fluorescence (XRF), powder X-ray diffraction (XRD), thermogravimetry (TG) and differential thermal (DT) analysis, scanning electron microscopy (SEM) and BET-surface area. In this study, europium was used as REEs(III) and as a homolog of Am(III)-isotopes (such as (241)Am of 432.6 y, (242m)Am of 141 y and (243)Am of 7370 y). Micro particles of the hematite ore were used for treatment of radioactive waste containing (152+154)Eu(III). The results indicated that 96% (4.1 × 10(4) Bq) of (152+154)Eu(III) was efficiently retained onto hematite ore. Kinetic experiments indicated that the processes could be simulated by a pseudo-second-order model and suggested that the process may be chemisorption in nature. The applicability of Langmuir, Freundlich and Temkin models was investigated. It was found that Langmuir isotherm exhibited the best fit with the experimental results. It can be concluded that hematite is an economic and efficient reactive barrier for immobilization of long-lived radio isotopes of actinides and REEs(III). Copyright © 2015 Elsevier Ltd. All rights reserved.

Study of the effect of anions and mixed solvents on the kinetics of reduction of Eu(III)

International Nuclear Information System (INIS)

Chandrasekaran, V.R.; Sundaram, A.K.

1983-01-01

The kinetics of reduction of Eu(III) to Eu(II) in aqueous solutions of perchlorate, chloride, sulphate, acetate and lactate anions and water-methanol and water-acetone mixtures containing potassium chloride as the inert electrolyte is reported and the effect of anions and solvent on the kinetics is studied. (author)

EU Food Health Law

DEFF Research Database (Denmark)

Edinger, Wieke Willemijn Huizing

to human health because of other factors, such as their nutritional composition. The growing prevalence of obesity and non-communicable diseases are examples of contemporary health challenges that are difficult to fit into the rather narrow concept of food safety risks in the GFL. The conclusion is that EU...... of harmonising measures that could facilitate a better consumer protection from non-safety health risks at the EU level. The EU legislature should use this legislative competence to fill in the regulatory grey area. Two possible ways forward to better integrate food health into the EU food law framework...

Predicting the uptake of Cs, Co, Ni, Eu, Th and U on argillaceous rocks using sorption models for illite

International Nuclear Information System (INIS)

Marques Fernandes, Maria; Vér, Nóra; Baeyens, Bart

2015-01-01

Highlights: • Contaminant retention in argillaceous rocks controlled by sorption on clay minerals. • Cs, Ni, Co, Eu, Th and UO 2 sorption isotherm measurements on Boda and Opalinus Clay. • Boda and Opalinus Clay exhibit different mineralogies and porewater compositions. • Blind predictions using quasi-mechanistic sorption models developed for illite. • Good agreement between measurements and blind predictions. - Abstract: Reliable predictions of radiocontaminant migration are a requirement for the establishment of radioactive waste repositories. Parametrization of the necessary sorption models seems to be, however, extremely challenging given the multi-mineralic composition of the lithosphere. In this study it is shown for two argillaceous rocks – Boda and Opalinus Clay relevant for the Hungarian and Swiss repository concepts, respectively – that this task can be substantially simplified by taking into account only the most sorptive mineral fraction, namely the 2:1 clay minerals illite and illite/smectite mixed layers. Two different models were required to blind predict the sorption isotherms of Cs, Co, Ni, Eu, Th and UO 2 measured on the two clay rock samples in a synthetic porewater. Cs sorption was modelled with the generalised Cs (GCs) sorption model and the sorption of the other cations with the 2site protolysis non electrostatic surface complexation and cation exchange (2SPNE SC/CE) model. The 2SPNE SC/CE model for illite was extended with surface complexation reactions on weak sites for Co, Ni, Eu, UO 2 and on strong sites for Eu-carbonato complexes. Complementary to the sorption measurements and modelling, extended X-ray absorption fine structure (EXAFS) spectroscopy was used to probe the retention mechanism of Ni on illite, Boda and Opalinus Clay at higher loadings. The reliable blind predictions of the selected metal cations, which are representative for monovalent alkaline metals, divalent transition metals, lanthanides, and trivalent

An electrochemical approach for removal of radionuclidic contaminants of Eu from 153Sm for effective use in metastatic bone pain palliation.

Science.gov (United States)

Chakravarty, Rubel; Chakraborty, Sudipta; Khan, Mohammed Sahiralam; Ram, Ramu; Sarma, Haladhar Dev; Dash, Ashutosh

2018-03-01

Thermal neutron activation of 152 Sm [ 152 Sm(n,γ) 153 Sm] using natural or isotopically enriched (by 152 Sm) samarium target is the established route for production of 153 Sm used for preparation of 153 Sm-EDTMP for pain palliation in cancer patients with disseminated bone metastases. However, some long-lived radionuclidic contaminants of Eu, such as, 154 Eu (t ½ =8.6y) are also produced during the target activation process. This leads to detectable amount of Eu radionuclidic contaminants in patients' skeleton even years after administration with therapeutic doses of 153 Sm-EDTMP. Further, the presence of such contaminants in 153 Sm raises concerns related to radioactive waste management. The aim of the present study was to develop and demonstrate a viable method for large-scale purification of 153 Sm from radionuclidic contaminants of Eu. A radiochemical separation procedure adopting electroamalgamation approach has been critically evaluated. The influence of different experimental parameters for the quantitative removal radionuclidic contaminants of Eu from 153 Sm was investigated and optimized. The effectiveness of the method was demonstrated by purification of ~37 GBq of 153 Sm in several batches. As a proof of concept, 153 Sm-EDTMP was administered in normal Wistar rats and ex vivo γ-spectrometry of bone samples were carried out. After carrying out the electrolysis under the optimized conditions, the radionuclidic contaminants of Eu could not be detected in purified 153 Sm solution by γ-spectrometry. The overall yield of 153 Sm obtained after the purification process was >85%. The reliability of this approach was amply demonstrated in several batches, wherein the performance remained consistent. Ex vivo γ-spectrometry of bone samples of Wistar rats administered with 153 Sm-EDTMP (prepared using electrochemically purified 153 Sm) did not show photo peaks corresponding to radionuclidic contaminants of Eu. A viable electrochemical strategy for the large

Radioactive aerosols

International Nuclear Information System (INIS)

Chamberlain, A.C.

1991-01-01

Radon. Fission product aerosols. Radioiodine. Tritium. Plutonium. Mass transfer of radioactive vapours and aerosols. Studies with radioactive particles and human subjects. Index. This paper explores the environmental and health aspects of radioactive aerosols. Covers radioactive nuclides of potential concern to public health and applications to the study of boundary layer transport. Contains bibliographic references. Suitable for environmental chemistry collections in academic and research libraries

High-Precision Measurement of Eu/Eu* in Geological Glasses via LA-ICP-MS Analysis

Science.gov (United States)

Tang, Ming; McDonough, William F.; Arevalo, Ricardo, Jr.

2014-01-01

Elemental fractionation during laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis has been historically documented between refractory and volatile elements. In this work, however, we observed fractionation between light rare earth elements (LREEs) and heavy rare earth elements (HREEs) when using ablation strategies involving large spot sizes (greater than 100 millimeters) and line scanning mode. In addition: (1) ion yields decrease when using spot sizes above 100 millimeters; (2) (Eu/Eu*)(sub raw) (i.e. Europium anomaly) positively correlates with carrier gas (He) flow rate, which provides control over the particle size distribution of the aerosol reaching the ICP; (3) (Eu/Eu*)(sub raw) shows a positive correlation with spot size, and (4) the changes in REE signal intensity, induced by the He flow rate change, roughly correlate with REE condensation temperatures. The REE fractionation is likely driven by the slight but significant difference in their condensation temperatures. Large particles may not be completely dissociated in the ICP and result in preferential evaporation of the less refractory LREEs and thus non-stoichiometric particle-ion conversion. This mechanism may also be responsible for Sm-Eu-Gd fractionation as Eu is less refractory than Sm and Gd. The extent of fractionation depends upon the particle size distribution of the aerosol, which in turn is influenced by the laser parameters and matrix. Ablation pits and lines defined by low aspect ratios produce a higher proportion of large particles than high aspect ratio ablation, as confirmed by measurements of particle size distribution in the laser induced aerosol. Therefore, low aspect ratio ablation introduces particles that cannot be decomposed and/or atomized by the ICP and thus results in exacerbated elemental fractionation. Accurate quantification of REE concentrations and Eu/Eu* requires reduction of large particle production during laser ablation. For the reference

Raman spectroscopic study of the oxidation state of Eu in molten LiCl-KCl

Energy Technology Data Exchange (ETDEWEB)

Park, Seung; Yun, Jong-Il [KAIST, Daejeon(Korea, Republic of)

2016-10-15

Spectroscopy can provide high reliability for the quantitative analysis of such system. The molar absorptivity of Eu(II) at 325 nm is reported as about 1645 M{sup -1}cm{sup -1}, which is too high to apply to higher concentration. A high-temperature Raman spectroscopy has been set and employed for analyzing the molecular structure and coordination complex and investigating the oxidation state of europium in molten LiCl-KCl. Europium can be present in divalent state while many other lanthanides exist in trivalent state. The thermodynamic properties of europium ions have been studied using electrochemical methods, spectroscopic methods, and EPR technique. Although there has been discrepancy of the reduced amount of europium in previous works, the majority of Eu(III) is thought to be reduced to Eu(II) in molten LiCl-KCl spontaneously at relatively low concentration (< 7.5 × 10{sup -4} M). Raman spectroscopy was employed to investigate the oxidation state of EuClx in LiCl-KCl at 500 .deg. C. The Raman scattering results suggest the majority of trivalent europium is reduced to divalent state with the composition change by vaporization. The Raman bands show highly asymmetric structure, quite different from regular octahedral structure.

Ex-ante evaluation of EU ETS during 2013–2030: EU-internal abatement

International Nuclear Information System (INIS)

Hu, Jing; Crijns-Graus, Wina; Lam, Long; Gilbert, Alyssa

2015-01-01

This study investigates CO 2 emission reduction within the EU resulting from the Emissions Trading Scheme (ETS) up to 2030. This is performed by constructing a baseline scenario without the ETS and assessing the impacts of the ETS, as currently designed. The results indicate that the ETS will start to impact emissions primarily after 2025 due to the prevalence of a sizable allowance surplus. The impact of approved (i.e. back-loading and 2.2% linear reduction factor (LRF)) and proposed (i.e. market stability reserve (MSR)) policy interventions and the inclusion of aviation, could accelerate the exhaustion of surplus and increase emission reductions during the investigated period. However, these measures would be insufficient to restore the scarcity of allowances and the corresponding carbon price before the start of ETS Phase IV, and the effectiveness of EU-internal abatement cannot be guaranteed until 2023. The effectiveness could be further reduced in the case of the economic shocks or the exclusion of international aviation. To restore the scarcity of allowances, other reform options are necessary. This paper extends the reasoning for the early removal of the back-loaded 900 Mtonne allowances by 2020 and broadening the scope of ETS to other sectors with potential high demand for allowances. - Highlights: • Quantification of CO 2 emission abatement in the EU resulting from the ETS up to 2030. • The impact of policy interventions and the inclusion of aviation is quantified. • The effectiveness of EU ETS in EU-internal abatement is limited until 2023

EU import restrictions on genetically modified feeds: impacts on Spanish, EU and global livestock sectors

Energy Technology Data Exchange (ETDEWEB)

Philippidis, G.

2010-07-01

Over the last decade, much controversy has surrounded the usage of genetically modified organism (GMO) technology in commercial agriculture. More specifically, it is feared that GMOs may introduce new allergens into the food chain or contribute to antibiotic resistance. At the current time, the European Union (EU) adopts a zero tolerance policy toward non-approved GMO imports, whilst the approval process has not kept pace with the proliferation of new GMO varieties. In the EU livestock sectors, this apparent mis-match threatens to interrupt supplies of high protein feed inputs (e.g., soy meal) from countries with more relaxed regulations regarding GMOs. Employing a well known multi-region computable general equilibrium framework, this study quantitatively assesses the impact of a hypothetical EU import ban on unapproved GMO varieties of soybean and maize imports on livestock, meat and dairy sectors. The model code is heavily modified to improve the characterisation of the agricultural sectors and land usage, whilst a realistic baseline is employed to update the global database to 2008, the year the hypothetical ban is implemented. In the worst case scenario, there are significant competitive losses in EU livestock, meat and dairy sectors. In Spain, the negative impacts are particularly pronounced given the importance of pig production in agriculture. In contrast, all non-EU regions trade balances improve, with notable trade gains in the USA and Brazil. To conclude, the EU must urgently find a long term strategy for GMOs if it is to reconcile political expediency with pragmatic economic concerns. (Author) 21 refs.

Development of integrated radioactive waste packaging and conditioning solutions in the UK

Energy Technology Data Exchange (ETDEWEB)

Sibley, Peter; Butter, Kevin; Zimmerman, Ian [EnergySolutions EU Ltd., Swindon, Wiltshire (United Kingdom); Viermann, Joerg [GNS Gesellschaft fur Nuklear-Service mbH, Essen (Germany); Messer, Matthias [GNS Gesellschaft fur Nuklear-Service mbH, Bristol (United Kingdom)

2013-07-01

In order to offer a more cost effective, safer and efficient Intermediate Level Waste (ILW) management service, EnergySolutions EU Ltd. and Gesellschaft fur Nuklear-Service mbH (GNS) have been engaged in the development of integrated radioactive waste retrieval, packaging and conditioning solutions in the UK. Recognising the challenges surrounding regulatory endorsement and on-site implementation in particular, this has resulted in an alternative approach to meeting customer, safety regulator and disposability requirements. By working closely with waste producers and the organisation(s) responsible for endorsing radioactive waste management operations in the UK, our proposed solutions are now being implemented. By combining GNS' off-the-shelf, proven Ductile Cast Iron Containers (DCICs) and water removal technologies, with EnergySolutions EU Ltd.'s experience and expertise in waste retrieval, safety case development and disposability submissions, a fully integrated service offering has been developed. This has involved significant effort to overcome technical challenges such as onsite equipment deployment, active commissioning, conditioning success criteria and disposability acceptance. Our experience in developing such integrated solutions has highlighted the importance of working in collaboration with all parties to achieve a successful and viable outcome. Ultimately, the goal is to ensure reliable, safe and effective delivery of waste management solutions. (authors)

Luminescence of Eu:Y3Al5O12, Eu:Lu3Al5O12, and Eu:GdAlO3 Nanocrystals Synthesized by Solution Combustion

Science.gov (United States)

Vilejshikova, E. V.; Khort, A. A.; Podbolotov, K. B.; Loiko, P. A.; Shimanski, V. I.; Shashkov, S. N.; Yumashev, K. V.

2017-11-01

Nanocrystals of rare-earth garnets Y3Al5O12 and Lu3Al5O12 and perovskite GdAlO3 highly doped (10-20 at%) with Eu3+ are synthesized by the solution combustion technique and subsequent annealing in air at 800 and 1300oC. Their structure, morphology, and phase composition are studied. These materials exhibit intense red luminescence under UV excitation. Eu:GdAlO3 luminescence has CIE 1931 color coordinates (0.632, 0.368); dominant wavelength, 599.6 nm; and color purity, >99%. Judd-Ofelt parameters, luminescence branching ratios, and lifetimes of the Eu3+ 5D0 state are determined. The luminescence quantum yield for Eu:GdAlO3 (10 at%) reaches 74% with a lifetime of 1.4 ms for the 5D0 state. The synthesized materials are promising for red ceramic phosphors.

OpenLaws.eu

NARCIS (Netherlands)

Wass, C.; Dini, P.; Eiser, T.; Heistracher, T.J.; Lampoltshammer, T.J.; Marcon, G.; Sageder, C.; Tsiavos, P.; Winkels, R.; Schweighofer, E.; Kummer, F.; Hötzendorfer, W.

2013-01-01

The OPENLAWS.eu project aims to linking existing laws, cases and legal literature throughout the EU and member states and potentially worldwide and at adding new user-friendly functionality for a higher productivity. Furthermore, the project should make it possible to easily publish new legal

EU Transparency Register

NARCIS (Netherlands)

Mańko, R.; Thiel, M.; Bauer, E.

2014-01-01

Widespread lobbying in the EU institutions has led to criticism regarding the transparency and accountability of the EU's decision-making process. In response to these concerns, the Parliament set up its transparency register in 1995, followed by the Commission in 2008. The two institutions merged

Diffusion of strongly sorbing cations (60Co and 152Eu) in compacted Febex bentonite

International Nuclear Information System (INIS)

Garcia-Gutierrez, M.; Missana, T.; Alonso, U.; Mingarro, M.; Cormenzana, J.L.

2010-01-01

Document available in extended abstract form only. Compacted bentonite is used as an engineered barrier in high-level radioactive waste (HLRW) repositories because is a swelling clay of very low permeability and high sorption capability for many solutes. The transport of radionuclides through compacted bentonite is a diffusion-controlled process retarded by sorption. Performance assessment calculations of a repository need diffusion coefficients data of relevant radionuclides. Several studies on diffusion behaviour of neutral, anionic and weakly sorbing elements on clay exist while very few studies are available for moderately sorbing elements, and almost no studies for Eu, a highly sorbing element are reported. In this study, diffusion experiments with strongly sorbing radionuclides, as 60 Co and 152 Eu, have been performed through compacted FEBEX bentonite. Diffusion essays with these strongly sorbing radionuclides are not straightforward to carry out because they are very time consuming essays, but also because sorption on the diffusion cells, tubing, filters and reservoirs, typically used in the classical through-diffusion or in-diffusion methods make hard the interpretation of the experimental results and the calculation of the diffusion coefficients. FEBEX bentonite was selected as Spanish reference buffer materials, and used in many national and international projects. The clay comes from the Cortijo de Archidona deposit (Almeria, Spain), and has a smectite content greater than 90% (93 ± 2%), with quartz (2 ± 1%), plagioclase (3 ± 1%), cristobalite (2 ± 1%), potassic feldspar, calcite, and trydimite as accessory minerals. The specific weight of the FEBEX bentonite is 2.7 g/cm 3 . Diffusion experiments were performed using the instantaneous plane source method. In this setup, a paper filter tagged with a tracer is introduced between two compacted tablets, avoiding contact between the tracer and the experimental vessels. The tracer can diffuse into both

Negative pressure driven valence instability of Eu in cubic Eu0.4La0.6Pd3

International Nuclear Information System (INIS)

Pandey, Abhishek; Mazumdar, Chandan; Ranganathan, R

2009-01-01

We report the change in the valency of Eu-ions in the binary intermetallic cubic compound EuPd 3 induced by La doping at rare-earth sites. Doping of La generates negative chemical pressure in the lattice, resulting in a significant increase of the lattice parameter without altering the simple-cubic structure of the compound. Results of dc-magnetic measurements suggest that this increase in the lattice parameter is associated with the valence transition of Eu-ions from Eu 3+ to a mixed-valent state. As Eu 2+ -ions possess a large magnetic moment, this valence transition significantly modifies the magnetic behavior of the compound. In contrast to introducing boron at the vacant body center site of the unit cell to change the valency of Eu-ions, as in the case of EuPd 3 B, our results suggest it can also be altered by doping a rare-earth ion of larger size at the lattice site of Eu in EuPd 3 .

Study of the spectroscopy properties of uranium matrix doped with europium. Energy transfer between UO22+ and Eu3+

International Nuclear Information System (INIS)

Luiz, Jose Eduardo Monteiro de Sa

2007-01-01

Uranyl compounds (UO 2 2+ ) present a great potential as luminescent materials, for instance, applied in technology laser, luminescent probes, cells for conversion of energy, etc. In this work it is studied the efficiency of energy transfer in the compound Eu 3+ doped in UO 2 (MS) 2 .(H 2 O)n matrix and UO 2 2+ in Eu(MS) 3 (H 2 O)n for to be used as efficient Light Conversion Molecular Devices (LCMD) and/or in solar cells for energy conversion. It is also described the synthesis, characterization and spectroscopic study of the matrix Eu(MS) 3 .(H 2 O)n.(x%mol) UO 2 2+ and UO 2 (MS) 2 .(H 2 O)n.(x%mol) Eu 3+ (where x= 1, 3, 5 and 10). The compounds obtained was characterized by elementary analyses for determine the U 6+ concentration, infrared spectra, thermal analyses and luminescence spectra. The IR data suggest that the MS ligand acts as bidentate one. The emission spectra of Eu 3+ doped in UO 2 (MS) 2 .(H 2 O) 2 matrix showed characteristic fluorescence bands of the uranyl ion, attributed to the transition of 3 Π u -> 1 Σ g + of the uranium matrix. For the UO 2 2+ in Eu(MS) 3 (H 2 O) 6 the transitions of D o -> 7 F J (J=0 ->4 ) are predominant in the spectra. The intense europium luminescence associated with uranyl sensitising is registered in emission spectra of Eu 3+ ions in the range of 420-720 nm. The quenching rate constant of UO 2 2+ fluorescence with Eu 3+ is also determined. (author)

Comparative study of the thermoluminescence between the materials α-Al2O3:C, KCl:Eu2+, KBr: Eu2+ and VYCOR

International Nuclear Information System (INIS)

Pedroza M, M.; Melendrez, R.; Perez S, R.; Aceves, R.; Piters, T.M.; Barboza F, M.

1999-01-01

It is presented some investigation results related to the thermoluminescence curves (Tl), Tl emission and the spectra of excitation of thermoluminescence in the ultraviolet region of 190 to 250 nm in the materials α-Al 2 O 3 :C, KCl: Eu 2+ , KBr: Eu 2+ and the Vycor glass. It was able to be observed that the Tl emission for the first three materials exists around 420 nm and in the case of Vycor the emission consists of two Tl peaks where the most low temperature is a band more wide centered in 460 nm and the other band of high temperature emits in 470 nm. In the excitation curves of Tl were obtained centered bands around 230 nm for KCl: Eu 2+ , 235 nm for KBr: Eu 2+ , 220 nm for the alumina and 195 nm for the Vycor. From the results it was able to be appreciated that this last has a minor relative intensity with respect to the others materials but also the region in which works there was an alone band between the 190 to 205 nm. This fact makes the material be very selective in the ultraviolet region of greatest energy. (Author)

Survey of radioactive contamination of foodstuffs

Energy Technology Data Exchange (ETDEWEB)

Lee, W. R.; Lee, C. W.; Choi, G. S.; Cho, Y. H.; Kang, M. J.; Cheong, K. H.; Kim, H. R.; Kwak, J. Y

2005-11-15

The purpose of this study is to survey and assess radioactive contamination of foodstuffs in order to reduce the probability of intake of contaminated foodstuffs. Based on survey and assessment, final goal is to improve the public health by radiation protection. Sampled foodstuffs items are collected from the markets : one group are imported foodstuffs and the other group are domestic foodstuffs producted around nuclear facilities. After pretreatments such as drying, ashing, and homogenization, all samples were analyzed by gamma spectrometer system. The {sup 137}Cs radionuclide was only measured among the regulation radionuclides ({sup 137}Cs, {sup 134}Cs, {sup 131}I) of food code. All radionuclides of the domestic foodstuffs collected around nuclear facilities were below Minimum Detectable Activity (MDA). But the activity concentrations of Inonotus obliquus (Chaga mushooms) from Russia ranged up to 171.27 (average value : 36.65) Bq/kg-fresh. In the case of blueberry jam, the radioactivity of {sup 137}Cs is higher than expected value. Other samples are below MDA except some spices. Based on the previous and present results, it should be strengthen to survey for Inontus obliquus (Chaga mushooms), of which the radioactivity shows the range from MDA up to 800.01 Bq/kg-fresh. It should assess the public radiation exposure via food chain because it has the excess provability of the maximum permitted level of food code, which is regulation of KFDA. The development method based on international standard would be used at radioactive analysis as well as education of practical workers and it could be applied as the basis data for amending the analysis method of food code. Our country only surveys gamma emitting radionuclides till now but international organization or foreign countries for example EU survey alpha and beta emitting radionuclides as well as gamma emitting radionuclides. So our country should also research necessity of survey for alpha and beta emitting

Diglycolic acid modified zirconium phosphate and studies on the extraction of Am(III) and Eu(III) from dilute nitric acid medium

Energy Technology Data Exchange (ETDEWEB)

Selvan, B. Robert; Suneesh, A.S.; Venkatesan, K.A.; Antony, M.P. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India). Fuel Chemistry Division; Dasthaiah, K.; Gardas, R.L. [Indian Institute of Technology - Madras, Chennai (India). Dept. of Chemistry

2017-06-01

Diglycolic acid modified zirconium phosphate (ZrP-DGA) was prepared and studied for the extraction of Am(III) and Eu(III) from dilute nitric acid medium. The distribution coefficient (K{sub d}, mL.g{sup -1}) of Am(III) and Eu(III) was measured as a function of time, pH and concentration of Eu(III) ion etc. The K{sub d} of Am(III) and Eu(III) increased with increase of pH, reached a maximum value of distribution coefficient at pH 1.5 - 2, followed by decrease in K{sub d} values. Rapid extraction of Am(III) and Eu(III) in ZrP-DGA was observed followed by the establishment of equilibrium occurred in 100 min. Kinetics of extraction was fitted in to pseudo second order rate equation. The amount of Eu(III) loaded in ZrP-DGA increased with increase in the concentration of Eu(III) ion in aqueous phase and the isotherm was fitted in to Langmuir and Freundlich adsorption models. The extraction of Am(III) in ZrP-DGA was higher as compared to Eu(III) and the interference of Eu(III) on the extraction of Am(III) was studied. The distribution coefficient of some lanthanides in ZrP-DGA was measured and the K{sub d} of lanthanides increased across the lanthanide series. The extracted trivalent metal ions were recovered in three contacts of loaded ZrP-DGA with 0.5 M nitric acid.

The Determination of γ and X Rays Variation in Radioactivity Measurement of Eu-152 Using Merlin Gerin Ionization Chamber

International Nuclear Information System (INIS)

Gatot-Wurdiyanto; Tuti-Budiantari, C; Ermi-Juita; Hermawan-Candra; Eni-Suswantini; Holnisar; Wahyudi

2001-01-01

Activity measurement of Eu-152 was carried out by using dose calibrator Merlin Gerin. Four samples having their solution factors was prepared for the measurement. The activities of each sample were determined with four variations of γ-rays and X-rays, namely all of γ-rays, all of γ rays and all of X-rays; 15 greater γ-rays intensities; 15 greater γ-rays intensities and all of X-rays. The reference of the measurement is the measurement result using γ-spectrometry methods. The result of the measurement is fairly good, meanwhile the best measurement of Eu-152 is based on all of γ-rays and X-rays which its difference of under 0.5 %. (author)

Synthesis and characterization of a liquid Eu precursor (EuCppm2) allowing for valence control of Eu ions doped into GaN by organometallic vapor phase epitaxy

International Nuclear Information System (INIS)

Mitchell, Brandon; Koizumi, Atsushi; Nunokawa, Takumi; Wakamatsu, Ryuta; Lee, Dong-gun; Saitoh, Yasuhisa; Timmerman, Dolf; Kuboshima, Yoshinori; Mogi, Takayuki; Higashi, Shintaro; Kikukawa, Kaoru; Ofuchi, Hironori; Honma, Tetsuo; Fujiwara, Yasufumi

2017-01-01

A liquid Eu precursor, bis(normal-propyl-tetramethylcyclopentadienyl)europium has been synthesized. This precursor exists as a liquid at temperatures higher than 49 °C, has a moderately high vapor pressure, contains no oxygen in its molecular structure, and can be distilled to high purity. These properties make it ideal for doping using a chemical vapor or atomic layer deposition method, and provide a degree of control previously unavailable. As a precursor the Eu exists in the divalent valance state, however, once doped into GaN by organometallic vapor phase epitaxy, the room-temperature photoluminescence of the Eu-doped GaN exhibited the typical red emission due to the intra-4f shell transition of trivalent Eu. After variation of the growth temperature, it was found that divalent Eu could be stabilized in the GaN matrix. By tuning the Fermi level through donor doping, the ratio of Eu 2+ to Eu 3+ could be controlled. The change in valence state of the Eu ions was confirmed using X-ray absorption near-edge structure. - Highlights: • A liquid Eu precursor was synthesized and its properties were characterized. • Precursor has a low melting point and a moderately high vapor pressure. • Does not contain oxygen in its molecular structure. • Eu can changed its valance state when incorporated into GaN. • Valence state of Eu in GaN can be controlled by donor doping.

Status of the EU test blanket systems safety studies

International Nuclear Information System (INIS)

Panayotov, Dobromir; Poitevin, Yves; Ricapito, Italo; Zmitko, Milan

2015-01-01

Highlights: • TBS safety demonstration files. • Safety functions and related design features – detailed TBS components classifications. • Nuclear analyses, radiation shielding and protection. • TBS radiological waste management strategy and categorization. • Selection and definition of reference accidents scenarios and accidents analyses. - Abstract: The European joint undertaking for ITER and the development of fusion energy (‘Fusion for Energy’ – F4E) provides the European contributions to the ITER international fusion energy research project. Among others it includes also the development, design, technological demonstration and implementation of the European test blanket systems (TBS) in ITER. Currently two EU TBS designs are in the phase of conceptual design – helium-cooled lithium-lead (HCLL) and helium-cooled pebble-bed (HCPB). Safety demonstration is an important part of the work devoted to the achievement of the next key project milestone the conceptual design review. The paper reveals the details of the work on EU TBS safety performed in the last couple of years: update of the TBS safety demonstration files; safety functions and related design features; detailed TBS components classifications; nuclear analyses, radiation shielding and protection; TBS radiological waste management strategy and categorization; selection and definition of reference accidents scenarios, and accidents analyses. Finally the authors share the information on on-going and planned future EU TBS safety activities.

Status of the EU test blanket systems safety studies

Energy Technology Data Exchange (ETDEWEB)

Panayotov, Dobromir, E-mail: dobromir.panayotov@f4e.europa.eu; Poitevin, Yves; Ricapito, Italo; Zmitko, Milan

2015-10-15

Highlights: • TBS safety demonstration files. • Safety functions and related design features – detailed TBS components classifications. • Nuclear analyses, radiation shielding and protection. • TBS radiological waste management strategy and categorization. • Selection and definition of reference accidents scenarios and accidents analyses. - Abstract: The European joint undertaking for ITER and the development of fusion energy (‘Fusion for Energy’ – F4E) provides the European contributions to the ITER international fusion energy research project. Among others it includes also the development, design, technological demonstration and implementation of the European test blanket systems (TBS) in ITER. Currently two EU TBS designs are in the phase of conceptual design – helium-cooled lithium-lead (HCLL) and helium-cooled pebble-bed (HCPB). Safety demonstration is an important part of the work devoted to the achievement of the next key project milestone the conceptual design review. The paper reveals the details of the work on EU TBS safety performed in the last couple of years: update of the TBS safety demonstration files; safety functions and related design features; detailed TBS components classifications; nuclear analyses, radiation shielding and protection; TBS radiological waste management strategy and categorization; selection and definition of reference accidents scenarios, and accidents analyses. Finally the authors share the information on on-going and planned future EU TBS safety activities.

Spin-resolved tunneling studies of the exchange field in EuS/Al bilayers.

Science.gov (United States)

Xiong, Y M; Stadler, S; Adams, P W; Catelani, G

2011-06-17

We use spin-resolved electron tunneling to study the exchange field in the Al component of EuS/Al bilayers, in both the superconducting and normal-state phases of the Al. Contrary to expectation, we show that the exchange field H(ex) is a nonlinear function of applied field, even in applied fields that are well beyond the EuS coercive field. Furthermore, the magnitude H(ex) is unaffected by the superconducting phase. In addition, H(ex) decreases significantly with increasing temperature in the temperature range of 0.1-1 K. We discuss these results in the context of recent theories of generalized spin-dependent boundary conditions at a superconductor-ferromagnet interface.

Impacts of market liberalisation on the EU gas industry

International Nuclear Information System (INIS)

Van Oostvoorn, F.; Boots, M.G.

1999-10-01

The paper presents an analysis of tbc effects of tbc European Union (EU) Gas Directive on the EU natural gas industry in the next ten years. First, it briefly reviews the current driving factors for increasing competition in the EU gas markets. Second, the different directions of implementation of EU Gas Directive are discussed. Finally we give an assessment of impacts of the different directions of implementation of the Gas Directive, thereby focusing on structural changes of the gas industry and the scope for reduction of consumer gas prices. Note that our assessment of the impacts is partly based on an analysis of recent trends in the EU gas market and partly on calculations with a recently developed model of the EU gas market on company level. The paper summarises the main observations of a study conducted by the Netherlands Energy Research Foundation (ECN) last year in the framework of a larger scenario study for the European Committee, Directorate-General 17, in the Shared Analysis Project, 'Economic Foundations for Energy Policy in Europe to 2020' managed by FhG-ISI. For the complete results of the ECN study, see report 'Impacts of Market Liberalisation on the EU Gas Industry', September 1999, forthcoming. Note that the analysis is limited to the gas market and does not include other impacts, i.c. on energy conservation, emissions, etc. 21 refs

Differences and similarities between the EU and non-EU citizens

Directory of Open Access Journals (Sweden)

Iris Dhamo

2017-03-01

Full Text Available Initially, the European Union had a purely economic connotation, as his intent was the free movement of factors of production, in order to create a competitive internal market and achieving a rational distribution of resources. For this reason, the individual was seen simply as a worker and for this purpose the first aspects that are disciplined within the EU are those contained in this sphere. In the Treaty of Rome, which established the European Economic Community (EEC, the freedom of free movement was reserved for only a few special categories of workers, who were active subjects economically, since what resulted essential at the time was the creation of an internal market. Later the Maastricht Treaty, on one side marks the transition from the EEC to the EU, on the other presents for the first time the "European citizenship", making the free movement an autonomous right of every citizen belonging to a Member State. In this way the free movement is exercised not only for the economic purposes of the Treaties. In December 2000 the Charter of Fundamental Rights or the Charter of Nice was compiled and signed, which defines that the EU seeks to promote a balanced development and ensures free movement of persons, goods, services and capital, and also the freedom of residence. Main objective of this manuscript is an analysis of the differences and similarities between the EU and non-EU citizens.

Contribution of Eu ions on the precipitation of silver nanoparticles in Ag-Eu co-doped borate glasses

International Nuclear Information System (INIS)

Jiao, Qing; Qiu, Jianbei; Zhou, Dacheng; Xu, Xuhui

2014-01-01

Graphical abstract: - Highlights: • Silver nanoparticles are precipitated from the borate glasses during the melting process without any further heat treatment. • The reduction of Eu 3+ ions to Eu 2+ ions is presented in this material. • The intensity of Ag + luminescence. • The introduction of Eu ions accelerated the reaction between Eu 2+ ions and silver ions inducing the silver clusters formation. - Abstract: Ag + doped sodium borate glasses with different Eu ions concentration were prepared by the melt-quenching method. The absorption at about 410 nm which was caused by the surface plasmon resonance (SPR) of Ag nanoparticles (NPs) is promoted with increasing of Eu ions concentration. Meanwhile, the luminescent spectra showed that the emission intensity of Ag + decreased while that of the Ag aggregates increased simultaneously. The results indicated that the Ag ions intend to form the high-polymeric state such as Ag aggregates and nanoparticles with increasing of europium ions. Owing to the self-reduction of Eu 3+ to Eu 2+ in our glass system, it revealed that Ag + has been reduced by the neighboring Eu 2+ which leads to the formation of Ag aggregates and the precipitation of Ag NPs in the matrix. In addition, energy transfer (ET) process from Ag + /Ag aggregates to the Eu 3+ was investigated for the enhancement of Eu 3+ luminescence

Paradigms for EU Law and the Limits of Delegation. The Case of EU Agencies

OpenAIRE

Simoncini Marta

2017-01-01

This article questions the idea that the EU is a pure regulatory power based on supranational delegation of competence from the Member States. It claims the insufficiency of this single paradigm to explain the developments of EU law and the need to integrate it with recognition of the constitutional foundations of EU law.

Radionuclide monitoring in foodstuff: overview of the current implementation in the EU countries

International Nuclear Information System (INIS)

Borbala Mate; Katarzyna Sobiech-Matura; Timotheos Altzitzoglou

2015-01-01

The Member States (MS) of the European Union (EU) are obliged to monitor the radioactivity in the environment since the signature of the Euratom Treaty (Treaty establishing the European Atomic Energy Community). Numerous secondary legislations derived from the Treaty can be found stating restrictions and maximum permitted levels of radionuclides in foodstuff. But to that purpose, no common integrated measurement methods are used with well-defined measurands. The present work consists of two parts. First, the current European regulations in force were collected, and then the food monitoring results, provided by the MS, were analysed. (author)

Search for unobserved transitions in "1"4"2Eu

International Nuclear Information System (INIS)

Ali, Sajad; Rajbanshi, S.; Bisoi, Abhijit

2016-01-01

In order to understand the excitation mechanisms responsible for the generation of high spin states in this mass region we have studied "1"4"2Eu nucleus. The high spin states of the "1"4"2Eu was reported earlier by M. Piiparinen et al. Based on this experimental data, they have proposed a level scheme of "1"4"2Eu. The motivation of current work is to remove the remaining incompleteness of the previously reported level scheme of "1"4"2Eu

Quantitative study of energy-transfer mechanism in Eu,O-codoped GaN by time-resolved photoluminescence spectroscopy

Science.gov (United States)

Inaba, Tomohiro; Kojima, Takanori; Yamashita, Genki; Matsubara, Eiichi; Mitchell, Brandon; Miyagawa, Reina; Eryu, Osamu; Tatebayashi, Jun; Ashida, Masaaki; Fujiwara, Yasufumi

2018-04-01

In order to investigate the excitation processes in Eu,O-codoped GaN (GaN:Eu,O), the time-resolved photoluminescence signal including the rising part is analyzed. A rate equation is developed based upon a model for the excitation processes in GaN:Eu to fit the experimental data. The non-radiative recombination rate of the trap state in the GaN host, the energy transfer rate between the Eu3+ ions and the GaN host, the radiative transition probability of Eu3+ ion, as well as the ratio of the number of luminescent sites (OMVPE 4α and OMVPE 4β), are simultaneously determined. It is revealed and quantified that radiative transition probability of the Eu ion is the bottleneck for the enhancement of light output from GaN:Eu. We also evaluate the effect of the growth conditions on the luminescent efficiency of GaN:Eu quantitatively, and find the correlation between emission intensity of GaN:Eu and the fitting parameters introduced in our model.

Studying the induced radioactivity of a varian clinac 2100C/D accelerator

International Nuclear Information System (INIS)

Lu Feng; Li Hailiang; Deng Daping; Shang Yunying; Jing Zhongjun

2008-01-01

Objective: To Study the influences of dose, time, distance and irradiation mode on induced radioactivity by measuring a Varian Clinac 2100C/D accelerator. Methods: The induced radioactivity was measured in different dose, time, distance and irradiation mode by using of 450P model dosemeter. The results was analysed. Results: The induced radioactivity is direct ratio with dose, inverse ratio with time and distance. In different irradiation mode, the induced radioactivity is different. Conclusion: The induced radioactivity level of accelerator is related with dose, time, distance and irradiation mode. (authors)

EU 2004 Declaration. EU policy workshop development of offshore wind energy. Background document

International Nuclear Information System (INIS)

De Bruijne, R.

2004-09-01

Participants of the Dutch EU Presidency's 'EU Policy Workshop on the development of offshore wind energy' published this Declaration that called for action at the EU Transport, Energy and Telecom Council on November 29, 2004. The Declaration lists a series of action points on three main issues relating to the development of offshore wind energy in Europe: market development; environment; and grid integration of large scale offshore wind

The EU Arbitration Convention : An evaluating assessment of the governance and functioning of the EU Arbitration Convention

NARCIS (Netherlands)

Pit, Harm Mark

2017-01-01

The EU Arbitration Convention An evaluating assessment of the governance and functioning of the EU Arbitration Convention Summary for non-experts The EU Arbitration Convention is a convention between EU Member States to eliminate double taxation arising from – for tax purposes – transfer pricing

Road-map to successful implementation of geological disposal in the EU

International Nuclear Information System (INIS)

Patrakka, Eero

2010-01-01

In the conclusions from its first meeting in Bratislava (2007), the European Nuclear Energy Forum (ENEF) identified the management of spent fuel and radioactive waste as an important subject to be looked into with the objective 'to encourage Member States and industry to swiftly implement adequate nuclear waste disposal facilities, in particular deep geological repositories for high level waste'. To this end the Sub-Working Group 'Waste Management' (SWG-WM) was created in the context of the ENEF Working Group 'Risks'. As a first task, the SWG-WM was requested to compile a road-map that includes the essential elements of what is required at national level to foster the implementation of geological disposal for high level waste and spent fuel. In October 2009, a 'Road-map to Successful Implementation of Geological Disposal in the EU' was endorsed. The aim of this document is to provide guidance to EU Member States that are starting out or are at an early stage on the decades-long process leading towards the implementation of geological repositories for high level radioactive wastes or spent nuclear fuel, if this is deemed to be a waste. The guidance is based to a large extent on the positive progress that has been made in a number of Member States. Small and new nuclear states may take a long time to reach such a position - but a strong message of this Road-map is that the process should be initiated as soon as possible. The Road-map is intended to be generic enough to be applicable to all Member States, independently of their current position; the national Road-maps to be developed should be compatible with this, but will differ in the specifics of approach and of timing. (authors)

Paradigms for EU Law and the Limits of Delegation. The Case of EU Agencies

Directory of Open Access Journals (Sweden)

Simoncini Marta

2017-11-01

Full Text Available This article questions the idea that the EU is a pure regulatory power based on supranational delegation of competence from the Member States. It claims the insufficiency of this single paradigm to explain the developments of EU law and the need to integrate it with recognition of the constitutional foundations of EU law.

Studies in crystal structure and luminescence properties of Eu3+-doped metal tungstate phosphors for white LEDs

International Nuclear Information System (INIS)

Lee, Gwan-Hyoung; Kang, Shinhoo

2011-01-01

The correlation between the crystal structure and luminescent properties of Eu 3+ -doped metal tungstate phosphors for white LEDs was investigated. Red-emitting A 4-3x (WO 4 ) 2 :Eu x 3+ (A=Li, Na, K) and B (4-3x)/2 (WO 4 ) 2 :Eu x 3+ (B=Mg, Ca, Sr) phosphors were synthesized by solid-state reactions. The findings confirmed that these phosphors exhibited a strong absorption in the near UV to green range, due to the intra-configurational 4f-4f electron transition of Eu 3+ ions. The high doping concentration of Eu 3+ enhanced the absorption of near UV light and red emission without any detectable concentration quenching. Based on the results of a Rietveld refinement, it was attributed to the unique crystal structure. In the crystal structure of the Eu 3+ -doped metal tungstate phosphor, the critical energy transfer distance is larger than 5 A so that exchange interactions between Eu 3+ ions would occur with difficulty, even at a high doping concentration. The energy transfer between Eu 3+ ions, which causes a decrease in red emission with increasing concentration of Eu 3+ , appears to be due to electric multi-polar interactions. In addition, the Eu-O distance in the host lattice affected the shape of emission spectrum by splitting of emission peak at the 5 D 0 → 7 F 2 transition of Eu 3+ . - Highlights: → Eu 3+ -doped metal tungstate was synthesized as a red phosphor for white LEDs. → Crystal structure is tetragonal with a space group of I4 1 /c. → A strong absorption in the near UV to green range was observed. → High doping of Eu 3+ enhanced the absorption of near UV light and red emission.

Spectroscopic studies of Eu(III) Keggin's and Dawson's polyoxotungstates substituted by acetato and oxalato ligands

International Nuclear Information System (INIS)

But, Slawomir; Lis, Stefan

2008-01-01

Eu(III) Keggin's and Dawson's type of polyoxometalates (POM) complexes were synthesized and spectroscopically characterized. This work presents results obtained for chosen hybrids of acetato K 12 [{Eu(SiMo x W 11-x O 39 )(H 2 O)} 2 (CH 3 COO) 2 ].nH 2 O, K 16 [{Eu(CH 3 COO)(H 2 O) 2 (P 2 W 17 O 61 )} 2 ].nH 2 O and oxalato (NH 4 ) 29 K 5 [{Eu(P 2 W 17 O 61 )} 4 (C 2 O 4 ) 3 (H 2 O) 4 ].nH 2 O, where x = 0, 1. The solid state compositions of the hybrids were characterized by using elemental and ICP-AES analysis, derivatography and FTIR spectroscopy. Luminescence characteristics (intensity, quantum yields, luminescence lifetimes and excitation spectra in the range of the 5 D 0 7 F 0 transition) of the synthesized Eu(III) acetato and oxalato complexes were determined in the solid phase and in solution, and they were compared to their parent Eu(III):POM complexes of 1:1 stoichiometry (ML)

Comparison of Eu(NO3)3 and Eu(acac)3 precursors for doping luminescent silica nanoparticles

International Nuclear Information System (INIS)

Enrichi, F.; Ricco, R.; Scopece, P.; Parma, A.; Mazaheri, A. R.; Riello, P.; Benedetti, A.

2010-01-01

In this study, we report the comparison between Eu 3+ -doped silica nanoparticles synthesized by Stoeber method using Eu(NO 3 ) 3 or Eu(acac) 3 as precursors. The impact of different europium species on the properties of the final silica nanospheres is investigated in details in terms of size, morphology, reachable doping amount, and luminescence efficiency. Moreover, the results obtained for different thermal treatments are presented and discussed. It is shown that the organic complex modify the silica growing process, leading to bigger and irregular nanoparticles (500-800 nm) with respect to the perfectly spherical ones (400 nm) obtained by the nitrate salt, but their luminescence intensity and lifetime is significantly higher when 800-900 o C annealing is performed.

International scale implementation of the CNOSSOS-EU road traffic noise prediction model for epidemiological studies

International Nuclear Information System (INIS)

Morley, D.W.; Hoogh, K. de; Fecht, D.; Fabbri, F.; Bell, M.; Goodman, P.S.; Elliott, P.; Hodgson, S.; Hansell, A.L.; Gulliver, J.

2015-01-01

The EU-FP7-funded BioSHaRE project is using individual-level data pooled from several national cohort studies in Europe to investigate the relationship of road traffic noise and health. The detailed input data (land cover and traffic characteristics) required for noise exposure modelling are not always available over whole countries while data that are comparable in spatial resolution between different countries is needed for harmonised exposure assessment. Here, we assess the feasibility using the CNOSSOS-EU road traffic noise prediction model with coarser input data in terms of model performance. Starting with a model using the highest resolution datasets, we progressively introduced lower resolution data over five further model runs and compared noise level estimates to measurements. We conclude that a low resolution noise model should provide adequate performance for exposure ranking (Spearman's rank = 0.75; p < 0.001), but with relatively large errors in predicted noise levels (RMSE = 4.46 dB(A)). - Highlights: • The first implementation of CNOSSOS-EU for national scale noise exposure assessment. • Road traffic noise model performance with varying resolution of inputs is assessed. • Model performance is good with low resolution inputs (r_s = 0.75). • This model will be applied in epidemiological studies of European cohorts. - The CNOSSOS-EU road traffic noise model estimates can be used for international scale exposure assessment when parameterised with freely available low resolution covering a large geographic area.

An ab-initio study of mechanical, dynamical and electronic properties of MgEu intermetallic

Science.gov (United States)

Kumar, S. Ramesh; Jaiganesh, G.; Jayalakshmi, V.

2018-04-01

The theoretical investigation on the mechanical, dynamical and electronic properties of MgEu in CsCl-type structure has been carried out through the ab-initio calculations within the framework of the density functional theory and the density functional perturbation theory. For the purpose, Vienna Ab initio Simulation Package and Phonopy packages were used. Our calculated ground-state properties of MgEu are in good agreement with other available results. Our computed elastic constants and phonon spectrum results suggest that MgEu is mechanically and dynamically stable up to 5 GPa. The thermodynamic quantities as a function of temperatures are also reported and discussed. The band structure, density of states and charge density also calculated to understand the electronic properties of MgEu.

Sorption behaviour of some radioactive isotopes on treated fly ash. Vol. 3

Energy Technology Data Exchange (ETDEWEB)

Abdel Raouf, M W; El-Dessouky, M I; Aly, H F [Hot Laboratories Center, Atomic Energy Authority, Cairo, (Egypt)

1996-03-01

Fly ash is obtained as a by-product from burning mazoute (high molecular weight hydrocarbon) at Northern Cairo Electric Power Generator, was ordinarily disposed in land fill. The carbonaceous material of fly ash was investigated as a possible sorbent for some fission products radionuclides: Cs{sup 134}, Co{sup 60}, and Eu{sup 142+154} at room temperature. The original fly ash was prepared for adsorption studies by sieving to different particle sizes (fractions), and repeated washing by tap water to neutral PH. Some fractions were further treated (after neutralization) by dilute HCl or ethyl alcohol and other fractions were heated at 200, 500, and 800 degree C. The results obtained from sorption on treated fly ash revealed that the percentage uptake (%U) was in accordance with the valency of the cation used: Eu{sup 3+}>Co{sup 2+}>>Cs{sup +} at medium hydrogen ion concentrations. The heated samples at different temperatures showed that % U obeyed the order: 800 degree C >200 degree C. Comparative studies were conducted with pyrolysis residue of domestic waste showed analogous trend in sorption studies. The feasibility of fly ash as a very cheap material in the removal of different fission products from liquid radioactive waste was assessed.

Core shell structured nanoparticles of Eu3+ doped SnO2 with SiO2 shell: luminescence studies

International Nuclear Information System (INIS)

Ningthoujam, R.S.; Sudarsan, V.; Kulshreshtha, S.K.

2005-01-01

Re dispersible SnO 2 nanoparticles with and without Eu 3+ doping nanoparticles were prepared at 185 deg C by the urea hydrolysis of Sn 4+ in ethylene glycol medium. X-ray diffraction and 119 Sn MAS NMR studies of these particles revealed that these nanoparticles are crystalline with Cassiterite structure having an average crystallite size of 7 nm. Undoped SnO 2 gave a emission peak centered around 470 nm characteristic of the traps present in the nanoparticles. For Eu 3+ doped samples, emission around 590 and 615 nm was observed on both direct excitation as well as indirect excitation through traps, indicating that there is an energy transfer between the traps present in the nanoparticles and Eu 3+ ions. The asymmetric ratio of luminescence (relative intensity ratio of 590 to 615 nm transitions) has been found to be 1.2. For SnO 2 :Eu(5%)-SiO 2 nanoparticles, the asymmetric ratio of luminescence change significantly indicating the formation of nanoparticles with SnO 2 :Eu(5%) core covered with SiO 2 shell. (author)

EC Study: Radioactive waste and spent fuel data collection, reporting, record keeping and knowledge transfer by EU Member States

International Nuclear Information System (INIS)

Hilden, Wolfgang; )

2012-01-01

Preservation of RK and M starts in the pre-closure phase. A comprehensive waste inventory is required which needs to be maintained over significantly long time spans before RWM has reached the step of disposal. Since long term management solutions are often not clearly defined, disposal acceptance criteria are and cannot be known beforehand, at least not in early stages of disposal programs. Thus a Preservation of RK and M should therefore be approached within the rationale of life cycle analysis. There is a wide variety of approaches with regard to waste inventories at EU level, and retrieving data is often lengthy and difficult. The Commission dedicated a study to identify good practices and formulate recommendations. There are two main issues; firstly waste data collection, recording and reporting, and secondly record keeping and knowledge transfer. One concerns the present time, while the other is concerned with long periods of time. With regard to the analysis of data requirements, it was found that they depend on the context of their use, be it safe treatment, storage and disposal, policy making and capacity planning or funding. The study identifies for each use relevant data sets. Thus, the question of the purpose of RK and M preservation heavily influences the question of which records need to be maintained (cf. the RK and M Vision Document). This is also true with regard to the potential need to cope with changes of the regulatory system or overall RWM policy, which requires to preserve raw data in continuously accessible form. On the other hand the contextualization of data is needed, for which the safety case may be a useful tool. With regard to legacy waste, re-assessment or re-conditioning campaigns should aim at maximum information gain. Agreements on how to coherently account for the total volume of the waste need to be made. A balance needs to be found between completeness and overload (watch out for 'Keep everything, find nothing'). Data security

25 years of European Union (EU) quality schemes for agricultural products and foodstuffs across EU Member States.

Science.gov (United States)

Albuquerque, Tânia G; Oliveira, M Beatriz Pp; Costa, Helena S

2018-05-01

Consumers are increasingly turning their attention to the quality and origin of products that they consume. European Union (EU) quality schemes are associated with a label, which was introduced to allow consumers to perform an informed choice and to protect producers from unfair practices. This present study provides an overview of the last 25 years of EU quality schemes [Protected Designations of Origin (PDO), Protected Geographical Indications (PGI) and Traditional Specialities Guaranteed (TSG)] on agricultural products and foodstuffs across the 28 EU Member States. According to the results, it was possible to conclude that Southern European countries have the highest number of registered products. The most used EU quality scheme is PGI, followed by PDO. Concerning the analysis of the evolution in the last 25 years, the number of registered products among EU Member States has increased significantly. The fruit, vegetables and cereals (fresh or processed) category is the one that accounts for the highest percentage (26.8%) of registered products, followed by cheeses and meat products (cooked, salted, smoked) categories, with 17.2% and 13.5%, respectively. Further investigations should address consumer preferences, knowledge and attitudes, especially Northern European countries with a lower number of registered products. Moreover, the investigation and registration of products should be encouraged among all EU Member States to allow the maintenance of important elements of the history, culture and heritage of the local areas, regions and countries. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Laboratory determination of migration of Eu(III) in compacted bentonite–sand mixtures as buffer/backfill material for high-level waste disposal

International Nuclear Information System (INIS)

Zhou, Lang; Zhang, Huyuan; Yan, Ming; Chen, Hang; Zhang, Ming

2013-01-01

For the safety assessment of geological disposal of high-level radioactive waste (HLW), the migration of Eu(III) through compacted bentonite–sand mixtures was measured under expected repository conditions. Under the evaluated conditions, advection and dispersion is the dominant migration mechanism. The role of sorption on the retardation of migration was also evaluated. The hydraulic conductivities of compacted bentonite–sand mixtures were K=2.07×10 −10 –5.23×10 −10 cm/s, The sorption and diffusion of Eu(III) were examined using a flexible wall permeameter for a solute concentration of 2.0×10 −5 mol/l. The effective diffusion coefficients and apparent diffusion coefficients of Eu(III) in compacted bentonite–sand mixtures were in the range of 1.62×10 –12 –4.87×10 –12 m 2 /s, 1.44×10 –14 –9.41×10 –14 m 2 /s, respectively, which has a very important significance to forecast the relationship between migration length of Eu(III) in buffer/backfill material and time and provide a reference for the design of buffer/backfill material for HLW disposal in China. - Highlights: • The migration progress of Eu(III) in compacted bentonite–sand mixtures was researched. • The hydraulic conductivity of cominpacted bentonite–sand mixtures was measured. • The migration length of Eu(III) in buffer/backfill material after a certain period of time was forecasted

Characteristics and follow-up of postmarketing studies of conditionally authorized medicines in the EU

NARCIS (Netherlands)

Hoekman, Jarno; Klamer, Thea T.; Mantel-Teeuwisse, Aukje K.; Leufkens, Hubert G M; De Bruin, Marie L.

2016-01-01

Aim: The aim of the present study was to provide an insight into the characteristics and follow-up of postmarketing studies of medicines that were conditionally authorized in the European Union (EU). Methods: We compiled a list of all postmarketing studies attached as specific obligations to the

Direct employment in the wind energy sector: An EU study

Energy Technology Data Exchange (ETDEWEB)

Blanco, Maria Isabel [Department of Economic Analysis, University of Alcala de Henares, 28802 Alcala de Henares (Spain)], E-mail: isabel.blanco@ewea.org; Rodrigues, Gloria [Department of Economic Analysis, University of Alcala de Henares, 28802 Alcala de Henares (Spain)

2009-08-15

Wind energy is often said to have positive effects on employment, but few studies have systematically dealt with this matter. This article presents estimates of direct wind energy employment in all EU countries, gathered for the first time. By using a thematic survey, the authors have been able to analyse aspects such as gender distribution, company profiles and the shortage of skilled workers reported by wind energy companies. The outcomes show that wind energy deployment creates a significant number of jobs (over 104,000 in 2008), and does so at a time when other energy sectors are shrinking. There is a clear relationship between MW installed and number of jobs, but the use of a single EU job/MW ratio is not feasible, due to differences in the export/import capacity. Wind turbine manufacturers-including major sub-components-are responsible for the lion's share of the jobs, and there is a marked prevalence of males in the workforce. The scarcity of specialist roles-project managers, engineers and O and M technicians-is not likely to be solved unless a series of educational, mobility and dissemination measures are put into practice.

Direct employment in the wind energy sector. An EU study

Energy Technology Data Exchange (ETDEWEB)

Blanco, Maria Isabel; Rodrigues, Gloria [Department of Economic Analysis, University of Alcala de Henares, 28802 Alcala de Henares (Spain)

2009-08-15

Wind energy is often said to have positive effects on employment, but few studies have systematically dealt with this matter. This article presents estimates of direct wind energy employment in all EU countries, gathered for the first time. By using a thematic survey, the authors have been able to analyse aspects such as gender distribution, company profiles and the shortage of skilled workers reported by wind energy companies. The outcomes show that wind energy deployment creates a significant number of jobs (over 104,000 in 2008), and does so at a time when other energy sectors are shrinking. There is a clear relationship between MW installed and number of jobs, but the use of a single EU job/MW ratio is not feasible, due to differences in the export/import capacity. Wind turbine manufacturers - including major sub-components - are responsible for the lion's share of the jobs, and there is a marked prevalence of males in the workforce. The scarcity of specialist roles - project managers, engineers and O and M technicians - is not likely to be solved unless a series of educational, mobility and dissemination measures are put into practice. (author)

Direct employment in the wind energy sector: An EU study

International Nuclear Information System (INIS)

Blanco, Maria Isabel; Rodrigues, Gloria

2009-01-01

Wind energy is often said to have positive effects on employment, but few studies have systematically dealt with this matter. This article presents estimates of direct wind energy employment in all EU countries, gathered for the first time. By using a thematic survey, the authors have been able to analyse aspects such as gender distribution, company profiles and the shortage of skilled workers reported by wind energy companies. The outcomes show that wind energy deployment creates a significant number of jobs (over 104,000 in 2008), and does so at a time when other energy sectors are shrinking. There is a clear relationship between MW installed and number of jobs, but the use of a single EU job/MW ratio is not feasible, due to differences in the export/import capacity. Wind turbine manufacturers-including major sub-components-are responsible for the lion's share of the jobs, and there is a marked prevalence of males in the workforce. The scarcity of specialist roles-project managers, engineers and O and M technicians-is not likely to be solved unless a series of educational, mobility and dissemination measures are put into practice.

Role of Eu"2"+ on the blue‐green photoluminescence of In_2O_3:Eu"2"+ nanocrystals

International Nuclear Information System (INIS)

Devi, Konsam Reenabati; Meetei, Sanoujam Dhiren; Singh, Shougaijam Dorendrajit

2016-01-01

Blue‐green light emitting undoped and europium doped indium oxide nanocrystal were synthesized by simple precipitation method. X-ray diffraction (XRD) pattern confirmed the cubic phase of undoped and europium doped samples. Further, transmission electron microscopy (TEM), scanning electron microscopy (SEM) , energy dispersive analysis of X-rays (EDAX), Fourier transform infra-red (FT-IR), photoluminescence (PL), electron paramagnetic resonance (EPR) studies were performed to characterise the samples. PL analysis of the samples is the core of the present research. It includes excitation, emission and CIE (Commission Internationale de l’e´ clairage) studies of the samples. On doping europium to In_2O_3 lattice, ln"3"+ site is substituted by Eu"2"+ thereby increasing the concentration of singly ionized oxygen vacancy and hence blue–green emission from the host is found to increase. Further, this increase in blue–green emission after doping may also be attributed to 4f → 5d transitions of Eu"2"+. However, the blue–green PL emission is found to decrease after an optimum dopant concentration (Eu"2"+ = 4%) due to luminescence and size quenching. CIE co-ordinates of the samples are calculated to know colour of light emitted from the samples. It suggests that this blue–green light emitting In_2O_3: Eu"2"+ nanocrystals may find application in lighting such as in generation of white light. - Highlight: • XRD and TEM study confirms the synthesis of cubic doped and europium doped nanocrystals. • EPR study reveals the doped europium is in + 2 oxidation state. • Enhance PL emission intensity of host material due to increase in singly ionized oxygen vacancy and 4f–5d transitions of Eu"2"+ • CIE co-ordinates suggest the blue–green colour of the samples.

Precision Lifetime Measurements Using LaBr3 Detectors With Stable and Radioactive Beams

Directory of Open Access Journals (Sweden)

Regan P.H.

2013-12-01

Full Text Available A range of high resolution gamma-ray spectroscopy measurements have been carried out using arrays which include a number of Cerium-doped Lanthanum-Tribromide (LrBr3(Ce scintillation detectors used in conjunction with high-resolution hyper-pure germanium detectors. Examples of the spectral and temporal responses of such set-ups, using both standard point radioactive sources 152Eu and 56Co, and in-beam fusionevaporation reaction experiments for precision measurements of nuclear excited states in 34P and 138Ce are presented. The current and future use of such arrays at existing (EURICA at RIKEN and future (NUSTAR at FAIR secondary radioactive beam facilities for precision measurements of excited nuclear state lifetimes in the 10 ps to 10 ns regime are also discussed.

Trade in Value Added (TiVA in EU New Member States (EU NMS

Directory of Open Access Journals (Sweden)

Ines Kersan-Škabić

2017-01-01

Full Text Available Contemporary trade analysis indicates the necessity of calculating trade in value added (TiVA which is created through global value chains (GVCs. This paper aims to determine the characteristics and importance of GVC trade in the EU new member states (EU NMS with special emphasis placed on the industry level. The results demonstrate different levels of GVC participation of the EU NMS, where Hungary is the most integrated country and Croatia the least integrated. Regional GVCs exist because a huge part of value added (VA comes from EU member states, as in gross export as well as in final demand (Europe as a hub. The most important source countries are Germany and Italy and there is also evidence of geographical and historical relations between the countries. The domination of backward participation has been found in the analysis made on the industrial level, i.e. the EU NMS are highly dependent on the import of intermediates for the production and export of final products. Strong interconnections between imports of intermediate products and exports of final products have been found in the manufacture of computers, electronics and optical products; manufacture of wood, paper, printing and reproduction. This research has contributed to the scarce literature concerning GVC (TiVA in EU NMS and has opened up new possibilities for further research and analysis.

Anti-tumor activity of self-charged (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles

International Nuclear Information System (INIS)

Lin, Cao; Cong, Wang; De'An, Pan; Jiexin, Cao; Ping, Che; Volinsky, Alex A.

2012-01-01

Non-stoichiometric (Eu,Ca):WO 3 and Eu:CaWO 4 nanoparticles with anti-tumor activity are synthesized in a sol-gel method by adding excessive Eu 3+ and Ca 2+ ions to tungsten oxide crystal structure. Colorimetric assay shows that 10 nm (Eu,Ca):WO 3 and Eu:CaWO 4 nanoparticles can effectively inhibit growth of mammary cancer cells without any harm to normal cells. Nanoparticles are characterized by X-ray diffraction, high resolution transmission electron microscopy and fluorescence optical spectrometry. Nanomaterials, insoluble in synthesized water, have complicated self-charging surfaces that trap mammary cancer cells. Surface self-charging effect is suggested as the inhibition mechanism. (author)

Experimental and numerical study of the degradation of radioactive measurements in the filters of airborne radioactive surveillance systems

International Nuclear Information System (INIS)

Geryes, Tony

2009-01-01

The measurement of radioactivity in the filters of airborne radioactive surveillance systems is a major metrology difficulty due to the fact that the absorption of a radiation in the filter media and the mass of aerosols accumulated distort the nuclear counting response. This thesis focuses on the determination of correction factors for the radioactivity loss in the survey filters. In a first step, radioactive filters representing the atmospheric samples have been prepared using the nuclear test bench ICARE. The experimental study on reference filters provided a database to determine correction factors for various filtration conditions. The second part proposes a new numerical method developed to determine the correction factors. It consists of coupling GeoDict for particles filtration simulations and MCNPX simulations for a transport in matter. The good agreement obtained by comparing the numerical and experimental correction factors has permitted to validate the numerical model

Brasov people’s fears after EU accession. Study carried out at the level of Brasov Municipality

Directory of Open Access Journals (Sweden)

Claudiu COMAN

2012-01-01

Full Text Available This study is part of a wider research, a compared type based sociological survey using the questionnaire, applied in Brasov during January 2010 and June 2010: "Effects of the EU integration perceived at the level of Brasov community and its implications on life quality and styles." By trying to explain precisely these effects of European integration (as research objective it was found that, in the scientific literature, the subject of the EU integration effort was oriented by means of the utilitarian theory (Gabel, 1998. Other international studies have also put in evidence that public opinion on EU integration matters, is determined by economic considerations and personal calculations such as cost-benefit (Anderson, 1995; Eichenberg and Dalton, 1993; Gabel, 1998. Using secondary analysis of the 2010 database and by following the proposed model of Ioan Mărginean, Iuliana PrecupeŃu and Ana Maria Preoteasa (2004 regarding the development of a measurement model of the post-accession EU fears, adapted to the Brasov realities and based on three dimensions (the sphere of private life, the sphere of social life and the relationship between the individual and the society, the statistical analysis provides new clues upon the types, the categories and the attitudinal fears profiles found in Brasov and their correlation with a new global factor - the economic crisis.

Further development of the EU Emissions Trading Scheme in Germany and the European Union under consideration of experiences in other EU Member States; Weiterentwicklung des Emissionshandels - national und auf EU-Ebene

Energy Technology Data Exchange (ETDEWEB)

Wartmann, S; Klaus, S; Scharte, M; Harnisch, J [Ecofys GmbH, Nuernberg (Germany); Heilmann, S; Bertenrath, R [FiFo Koeln (Germany)

2008-02-15

The study analyses options for further development of the EU Emissions Trading Scheme (EU-ETS) after 2012. The first analysis focuses on the effects of the EU-ETS on companies, power prices, competitiveness and employment. It is followed by an analysis of overlaps or lacking coverage regarding the climate policies EU-ETS, Eco-Tax (Oekosteuer) resp. Energy Tax, the Renewable Energy Sources Act and the Combined Heat and Powert Act. These instruments are analysed with regards to their coherence. As a next step, the national allocation plans of France, The Netherlands, the United Kingdom and Poland are evaluated and recommendations are developed. Best practice recommendations for further developing the EU-ETS after 2012 both at the European and the national level are developed from the comparison of these European national allocation plans. Finally, design features of certificate systems relevant for international linking of such systems are addressed. In the analysis such design features are identified and approaches for problems potentially arising when certificate systems are linked, are developed. (orig.)

Designing the emerging EU pesticide policy: A literature review

NARCIS (Netherlands)

Skevas, T.; Oude Lansink, A.G.J.M.; Stefanou, S.E.

2013-01-01

A European Union (EU) wide pesticide tax scheme is among the future plans of EUpolicy makers. This study examines the information needs for applying an optimal pesticidepolicy framework at the EU level. Damage control specification studies, empirical results from pesticide demand elasticity, issues

New limits on 2β processes in 40Ca and 46Ca by using low radioactive CaF2(Eu) crystal scintillators

International Nuclear Information System (INIS)

Belli, P.; Bernabei, R.; Dai, C.J.

2001-01-01

The development of highly radiopure CaF 2 (Eu) crystal scintillators has been performed aiming at a substantial sensitivity enhancement of the 2β decay investigation and of the search for dark matter particles with spin-dependent (SD) interaction. The results of CaF 2 (Eu) background measurements and simulation are presented. New and highly improved T 1/2 limits on the 2β decay of 46 Ca and the double electron capture of 40 Ca are obtained

Quadrupole splitting and Eu partial lattice dynamics in europium orthophosphate EuPO {sub 4}

Energy Technology Data Exchange (ETDEWEB)

Klobes, B., E-mail: b.klobes@fz-juelich.de [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany); Arinicheva, Y., E-mail: y.arinicheva@fz-juelich.de; Neumeier, S., E-mail: s.neumeier@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-6) Nuclear Waste Management and Reactor Safety (Germany); Simon, R. E., E-mail: r.simon@fz-juelich.de; Jafari, A., E-mail: a.jafari@fz-juelich.de [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany); Bosbach, D., E-mail: d.bosbach@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-6) Nuclear Waste Management and Reactor Safety (Germany); Hermann, R. P., E-mail: hermannrp@ornl.gov [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany)

2016-12-15

Hyperfine interactions in europium orthophosphate EuPO{sub 4} were investigated using {sup 151}Eu Mössbauer spectroscopy from 6 to 300 K. The value of the quadrupole splitting and the asymmetry parameter were refined and further substantiated by nuclear forward scattering data obtained at room temperature. The temperature dependence of the relative absorption was modeled with an Eu specific Debye temperature of 221(1) K. Eu partial lattice dynamics were probed by means of nuclear inelastic scattering and the mean force constant, the Lamb-Mössbauer factor, the internal energy, the vibrational entropy, the average phonon group velocity were calculated using the extracted density of phonon states. In general, Eu specific vibrations are characterized by rather small phonon energies and contribute strongly to the total entropy of the system. Although there is no classical Debye like behavior at low vibrational energies, the average phonon group velocity can be reasonably approximated using a linear fit.

EU Energy Law and Policy Issues. Volume 3

Energy Technology Data Exchange (ETDEWEB)

Delvaux, B.; Hunt, M.; Talus, K. (eds.)

2011-12-15

This third volume of EU Energy Law and Policy Issues presents an overview of some of the most recent developments taking place in the EU energy sector at a time when the Third Energy Package is likely to be or has been implemented in the EU Member States. In this respect, the reader will find a number of contributions which offer detailed and critical views on some of the main issues tackled by the Third Energy Package. Aside from this, the relationship between sector specific regulation and the rules of general competition law is examined in the second section of the book. This part also contains particular contributions on access regimes in gas and electricity markets as well as an innovating analysis on the methods for allocating allowances under the EU Emissions trading scheme and the interaction of such methods with EU state aid rules. Just like the previous volumes of the book, section III offers a deep insight into the external aspects of EU energy policy. Accordingly, the role of the Lisbon Treaty in promoting EU energy policy in the international arena is scrutinized in addition to the most recent evolutions on the topical issue of the Energy Charter Treaty. This section is completed with a daring contribution about the need to adopt a comprehensive theory of legal harmonization between the EU and third partners, which is presented using the specific case of the EU-Russia Energy Dialogue. Last but not least, some fundamental issues regarding the environmental aspects of EU Energy policy undergo an in-depth study in the final section of the book. Not only is the legal regime of energy efficiency in energy-related products examined, but also the issue of carbon constraining policies under WTO law. Finally, the electricity's industry viewpoint on the 2020 targets rounds off this third volume of EU Energy Law and Policy Issues with judicious comments.

EU Energy Law and Policy Issues. Volume 3

International Nuclear Information System (INIS)

Delvaux, B.; Hunt, M.; Talus, K.

2011-12-01

This third volume of EU Energy Law and Policy Issues presents an overview of some of the most recent developments taking place in the EU energy sector at a time when the Third Energy Package is likely to be or has been implemented in the EU Member States. In this respect, the reader will find a number of contributions which offer detailed and critical views on some of the main issues tackled by the Third Energy Package. Aside from this, the relationship between sector specific regulation and the rules of general competition law is examined in the second section of the book. This part also contains particular contributions on access regimes in gas and electricity markets as well as an innovating analysis on the methods for allocating allowances under the EU Emissions trading scheme and the interaction of such methods with EU state aid rules. Just like the previous volumes of the book, section III offers a deep insight into the external aspects of EU energy policy. Accordingly, the role of the Lisbon Treaty in promoting EU energy policy in the international arena is scrutinized in addition to the most recent evolutions on the topical issue of the Energy Charter Treaty. This section is completed with a daring contribution about the need to adopt a comprehensive theory of legal harmonization between the EU and third partners, which is presented using the specific case of the EU-Russia Energy Dialogue. Last but not least, some fundamental issues regarding the environmental aspects of EU Energy policy undergo an in-depth study in the final section of the book. Not only is the legal regime of energy efficiency in energy-related products examined, but also the issue of carbon constraining policies under WTO law. Finally, the electricity's industry viewpoint on the 2020 targets rounds off this third volume of EU Energy Law and Policy Issues with judicious comments.

Synchrotron radiation studies on luminescence of Eu2+-doped LaCl3 microcrystals embedded in a NaCl matrix

International Nuclear Information System (INIS)

Savchyn, P.V.; Vistovskyy, V.V.; Pushak, A.S.; Voloshinovskii, A.S.; Gektin, A.V.; Pankratov, V.; Popov, A.I.

2012-01-01

LaCl 3 :Eu 2+ microcrystals dispersed in the NaCl matrix have been obtained in the NaCl–LaCl 3 (1 mol.%)–EuCl 3 (0.1 mol.%) crystalline system. The low-temperature luminescent properties of these microcrystals have been studied upon the VUV and UV excitation by the synchrotron radiation. The spectroscopic parameters as well as decay time constants of Eu 2+ -doped LaCl 3 host have been established. The excitation mechanism of divalent europium centers through energy transfer and reabsorption is discussed.

Overlever EU?

DEFF Research Database (Denmark)

Østergaard, Uffe

2015-01-01

Det bliver stadig tydeligere at EU i kraft af den styrkede nationalisme i øst, vest og nord og kombineret med de nye regionale krav om national selvstændighed vil bevæge sig i retning af et mellemstatsligt samarbejde, støttet af en retsorden beskyttet af en domstol, bliver stadig tydeligere. Det ...... mindre sikkert, om den nationale egoisme vil ende med at opløse samarbejdet. EU vil sandsynligvis overleve, men det bliver snarere ligesom det Tysk-Romerske Rige, hvis institutioner overlevede helt til 1804....

Antiferromagnetism in EuPdGe{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Albedah, Mohammed A. [Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5 (Canada); Al-Qadi, Khalid [Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5 (Canada); Department of Mathematics, Statistics and Physics, Qatar University, P.O. Box 2713, Doha (Qatar); Stadnik, Zbigniew M., E-mail: stadnik@uottawa.ca [Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5 (Canada); Przewoźnik, Janusz [Solid State Physics Department, Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, 30-059 Kraków (Poland)

2014-11-15

Highlights: • We show that EuPdGe{sub 3} crystallizes in the BaNiSn{sub 3}-type structure with the lattice constants a = 4.4457(1) Å and c = 10.1703(2). • We demonstrate that EuPdGe{sub 3} is an antiferromagnet with the Néel temperature T{sub N} = 12.16(1) K. • The temperature dependence of the hyperfine magnetic field follows a S = 7/2 Brillouin function. • We find that the Debye temperature of the studied compound is 199(2) K. - Abstract: The results of X-ray diffraction, magnetic susceptibility and magnetization, and {sup 151}Eu Mössbauer spectroscopy measurements of polycrystalline EuPdGe{sub 3} are reported. EuPdGe{sub 3} crystallizes in the BaNiSn{sub 3}-type tetragonal structure (space group I4mm) with the lattice constants a=4.4457(1)Å and c=10.1703(2)Å. The results are consistent with EuPdGe{sub 3} being an antiferromagnet with the Néel temperature T{sub N}=12.16(1)K and with the Eu spins S=7/2 in the ab plane. The temperature dependence of the magnetic susceptibility above T{sub N} follows the modified Curie-Weiss law with the effective magnetic moment of 7.82(1) μ{sub B} per Eu atom and the paramagnetic Curie temperature of -5.3(1)K indicative of dominant antiferromagnetic interactions. The M(H) isotherms for temperatures approaching T{sub N} from above are indicative of dynamical short-range antiferromagnetic ordering in the sample. The temperature dependence of the hyperfine magnetic field follows a S=7/2 Brillouin function. The principal component of the electric field gradient tensor is shown to increase with decreasing temperature and is well described by a T{sup 3/2} power-law relation. The Debye temperature of EuPdGe{sub 3} determined from the Mössbauer data is 199(2) K.

Pesticide authorization in the EU-environment unprotected?

Science.gov (United States)

Stehle, Sebastian; Schulz, Ralf

2015-12-01

Pesticides constitute an integral part of high-intensity European agriculture. Prior to their authorization, a highly elaborated environmental risk assessment is mandatory according to EU pesticide legislation, i.e., Regulation (EC) No. 1107/2009. However, no field data-based evaluation of the risk assessment outcome, i.e., the regulatory acceptable concentrations (RACs), and therefore of the overall protectiveness of EU pesticide regulations exists. We conducted here a comprehensive meta-analysis using peer-reviewed literature on agricultural insecticide concentrations in EU surface waters and evaluated associated risks using the RACs derived from official European pesticide registration documents. As a result, 44.7 % of the 1566 cases of measured insecticide concentrations (MICs) in EU surface waters exceeded their respective RACs. It follows that current EU pesticide regulations do not protect the aquatic environment and that insecticides threaten aquatic biodiversity. RAC exceedances were significantly higher for insecticides authorized using conservative tier-I RACs and for more recently developed insecticide classes, i.e., pyrethroids. In addition, we identified higher risks, e.g., for smaller surface waters that are specifically considered in the regulatory risk assessment schemes. We illustrate the shortcomings of the EU regulatory risk assessment using two case studies that contextualize the respective risk assessment outcomes to field exposure. Overall, our meta-analysis challenges the field relevance and protectiveness of the regulatory environmental risk assessment conducted for pesticide authorization in the EU and indicates that critical revisions of related pesticide regulations and effective mitigation measures are urgently needed to substantially reduce the environmental risks arising from agricultural insecticide use.

Studies of the coagulation flotation of bentonite and its application to the removal of Co2+ ions and fission products, Ce and Eu

International Nuclear Information System (INIS)

Kobayashi, Koichi; Sato, Hiroshi; Kachi, Kosei; Nakamura, Masao; Sasaki, Tsunetaka

1975-01-01

The regions of dispersion, coagulation precipitation, coagulation flotation, and redispersion were determined for aqueous bentonite-cationic surfactant and bentonite-cationic surfactant-polyacrylamide(PAA) systems. The region of coagulation flotation was markedly extended by the addition of PAA to both the lower and higher concentration regions of the cationic surfactant, hexadecyldimethylbenzylammonium chloride(HDBAC), and to the lower concentration region of bentonite. The phenomenon of coagulation flotation was investigated in detail and was applied to the removal of Co 2+ ions and nuclear fission products, 144 Ce and 155 Eu, from an aqueous solution. The composition of the reagents for the maximum efficiency of bentonite flotation corresponded to that of the maximum efficiency of Co 2+ -ion flotation. The effect of the pH on the flotation efficiency was studied in particular. The maximum flotation efficiency of 96% was obtained at pH 11 for Co 2+ ions, 86% at pH 9.7 for 144 Ce, and 93% at pH 10.5 for 155 Eu. These radioactive elements were almost completely adsorbed on the surface of bentonite particles and were floated with them in the pH region of the maximum flotation efficiency. It was confirmed that Co 2+ ions could be floated also from an extremely low concentration (10 -9 mol/l) of Co 2+ ions with nearly the same efficiency of flotation and with the additives in the same condition. Co 2+ ions could also be effectively removed by using the step-by-step flotation, showing as high a flotation efficiency as 99.8%. (auth.)

Essentials of EU law

CERN Document Server

Reinisch, August

2012-01-01

This book explores the history and institutions of the EU, examines the interplay of its main bodies in its legislative process and illustrates the role played by the EU Courts and the importance of fundamental rights. The student is also introduced to the key principles of the internal market, in particular the free movement of goods and the free movement of workers. In addition a number of other EU policies, such as the Common Agricultural Policy, Environmental Protection and Social Policy are outlined, while a more detailed inquiry is made into European competition law.

Development of EU Environmental Regulation

DEFF Research Database (Denmark)

Klemmensen, Børge

2007-01-01

En tematiseret gennemgang af udviklingstrinene i EU's miljøpolitik fra de allerførste skirdt i 1970-72, der måtte basere sig på EU-traktatens generalklausul i Artikel 235, over declarationen på EU-topmødet i Paris i 1972, der kædede økonomisk udvikling sammen med et krav om hensyntagen til miljøet...

Study Circles as a Method of Informing the Adult Population on Radioactivity

International Nuclear Information System (INIS)

Kralj, M.

2002-01-01

Public acceptance of the radioactive waste disposal facilities is difficult to achieve. Analysis of the reasons that underlie public rejection of radioactive waste disposal facilities shows that people are not adequately informed about the proposal. They also have a lot of prejudices due to the lack of knowledge and understanding about basic facts on radioactivity and environmental processes. ARAO has proposed that the topic of radioactivity and radioactive waste be included in the program of study circles in order to promote knowledge and understanding of these issues among the adult population in several Slovenian communities. Study circles are self-organized adult learning groups in the local community environment. Two study circles were initially proposed: one in Krsko, the community with a nuclear facility, and one in Radovljica, a community without a nuclear facility. Because of troubles with the unexpected politicization of nuclear issues, the study circle in Krsko was postponed to the later term, so that only the study circle in the community without the nuclear installation was active. The members were found by personal invitations. They worked on different issues dealing with radiation, mainly with the application of radiation and radioactive substances in medicine. Through the study circle activities the interest in radiation issues increased. The members reported that they disseminated their interest and acquired knowledge to their family members and friends. Our experience shows that self-learning in small groups, promoting discussions and the confrontation of different opinions, results in an increase in objective knowledge. Therefore, study circles can provide a good basis for confidence building in the nuclear technology.(author)

Study of the interactions between Eu(III) and Al2O3 particles in the presence of phenolic acids

International Nuclear Information System (INIS)

Moreau, P.

2012-01-01

In the framework of environmental pollution by radionuclides, this work was focused on the interactions occurring in systems containing europium(III) - as a chemical analogue for the actinides Am(III) and Cm(III) -, phenolic acids - lignin degradation products and anti-fungi, naturally occurring in soils, and alumina - representative of sorption sites found in the environment. This study was conducted at different scales of description: the macroscopic scale - to quantify Eu(III) and/or phenolic acids adsorption onto the mineral surface -, and the microscopic scale - to study the chemical environment of Eu(III) using Time-Resolved Luminescence Spectroscopy (TRLS). First, the binary systems, i.e. systems containing only two entities among the three previously cited, were characterized. Complexation constants of Eu(III) by three phenolic acids (4-hydroxybenzoic, 3,4-dihydroxybenzoic, and 3,4,5-trihydroxybenzoic acids) were determined and quantum calculations (DFT) were carried out on La(III)-acid complex analogues. Sorption of the acids onto aluminol sites was modelled using surface complexation concepts. Analyses of two ternary systems (containing 4-hydroxybenzoic and 3,4-dihydroxybenzoic acids) revealed synergistic processes for Eu(III) and phenolic acids sorption onto Al 2 O 3 . A spectral fingerprint of ternary complex involving Eu(III)/4-hydroxybenzoic acid/Al 2 O 3 surface sites was evidenced. (author) [fr

Radioactivity studies in the Romanian national repository for radioactive waste - Baita, Bihor region, during 14 years of resource development

International Nuclear Information System (INIS)

Dragolici, F.; Rotarescu, G.; Luca, A.; Peic, T.; Postelnicu, C.; Dragolici, A.C.

2000-01-01

The main objective of the study is focused on active surveillance, by periodic measurements of the radioactivity and the possible migration, during the last 14 years, of the radioactive elements stored at the Romanian National Repository for Radioactive Waste-Baita, Bihor region. Hence, water, soil and vegetation samples were collected every three months, from 57 points, chosen in agreement with the National Commission for Nuclear Activities Control and with the local Public Health Institutions. After the sample collection, radiometric measurements were made. The main steps of the study were: the collection of the samples, radiometric measurements, radiochemical analysis of the uranium and progeny, processing and the interpretation of the obtained data; detection of any gamma radionuclides using gamma spectrometry; and the processing, interpretation and intercomparison of the results. Throughout the 14 years of surveillance, it was demonstrated that the National Repository for Radioactive Waste activity has had no negative impact on the operator staff, environment and population. Also, no migration of the deposited radionuclides was detected throughout the whole area. (author)

Role of quantitative and dynamic radioactive studies in renal testing

International Nuclear Information System (INIS)

Raynaud, C.

1977-01-01

Many dynamic and quantitative radioactive tests are at present used in studying renal function. Whether involving dynamic morphological tests such as sequential images, dynamic quantitative tests such as the renogram or quantitative static tests such as radioactive clearances, their effective and original contribution is rather unimportant. Only one provides original data, the Hg renal uptake test but it is generally avoided due to the radiation dose absorbed by the kidney in children. A study of the causes of this lack of effectiveness leads to the observation that such tests are not well adapted to the needs of kidneys specialists. They are for the most part based on replacing a 'cold' indicator by radioactive indicator and the advantages anticipated from using radionuclide are not evident. In fact, they are often cancelled by the shortcomings of external detection. For the future, it seems indispensable to abandon some traditional concepts which lead us to consider that the only exploitable renal function is represented by excretion. The kidney has other functions; one of the most interesting seems to be the function of uptake of heavy metals and toxic substances, a study of which is only possible using radionuclides. A new generation of radioactive tests based on a study of uptake and also on a study of other renal functions may provide dynamic or quantitative data which physician urgently need

Electron-spin polarization in tunnel junctions with ferromagnetic EuS barriers

International Nuclear Information System (INIS)

Hao, X.; Moodera, J.S.; Meservey, R.

1989-01-01

The authors report here spin-polarized tunneling experiments using non-ferromagnetic electrodes and ferromagnetic EuS barriers. Because of the conduction band in EuS splits into spin-up and spin-down subbands when the temperature is below 16.7 K, the Curie temperature of EuS, the tunnel barrier for electrons with different spin directions is different, therefore giving rise to tunnel current polarization. The spin-filter effect, as it may be called, was observed earlier, directly or indirectly, by several groups: Esaki et al. made a tunneling study on junctions having EuS and EuSe barriers; Thompson et al. studied Schottky barrier tunneling between In and doped EuS; Muller et al. and Kisker et al. performed electron field emission experiments on EuS-coated tungsten tips. The field emission experiments gave a maximum polarization of (89 + 7)% for the emitted electrons. Although the previous tunneling studies did not directly show electron polarization, their results were explained by the same spin- filter effect. This work uses the spin-polarized tunneling technique to show directly that tunnel current is indeed polarized and polarization can be as high as 85%

Multichannel Luminescence Properties of Mixed-Valent Eu2+/Eu3+ Coactivated SrAl3BO7 Nanocrystalline Phosphors for Near-UV LEDs.

Science.gov (United States)

Liu, Xiaoming; Xie, Weijie; Lü, Ying; Feng, Jingchun; Tang, Xinghua; Lin, Jun; Dai, Yuhua; Xie, Yu; Yan, Liushui

2017-11-20

Up to now, orchestrating the coexistence of Eu 2+ and Eu 3+ activators in a single host lattice has been an extremely difficult task, especially for the appearance of the characteristic emission of Eu 2+ and Eu 3+ in order to generate white light. Nevertheless, here we demonstrate a new Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphor with abundant and excellent multichannel luminescence properties. A series of Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphors were prepared through a Pechini-type sol-gel method followed by a reduction process. With excitation of UV/NUV light, the prepared SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphors show not only the characteristic f-f transitions of Eu 3+ ion ( 5 D J → 7 F J,J' , J, J' = 0-3), but also the 5d → 4f transitions of Eu 2+ ion with comparable intensity from 400 to 700 nm in the whole visible spectral region. The luminescence color of the SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor can be tuned from blue, blue-green, white, and orange to orange-red by changing the excitation wavelength, the overall doping concentration of europium ions (Eu 2+ , Eu 3+ ), and the relative ratio of Eu 2+ to Eu 3+ ions to some extent. A single-phase white-light emission has been realized in SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor. The obtained SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor has potential application in the area of NUV white-light-emitting diodes.

The Impact of the Explosion of EU News on Voter Choice in the 2014 EU Elections

Directory of Open Access Journals (Sweden)

Jan Kleinnijenhuis

2016-02-01

Full Text Available The European elections in 2014 were the first to be held after a long period in which EU-related news was prominent in the media. They were held after years of daily news about the euro crisis and after months of news about the popular uprising in the Ukraine against president Yanukovych, who had refused to sign the association agreement with the EU. This could have invited political parties to overcome the usual problem of low salience of EU issues by strongly profiling themselves on EU issues. Turnout at the 2014 EU elections, however, remained low, hinting that parties were unable to convert the attention for European issues into enthusiasm for their party at the European elections. This paper asks how vote choice was influenced by party campaigning on EU related issues. A news effects analysis based on a content analysis of Dutch newspapers and television, and on a panel survey among Dutch voters revealed that EU issues functioned as wedge issues: the more strongly parties were associated in the news with the euro crisis and the Ukraine, the less they succeeded in mobilizing voters.

Worldwide marine radioactivity studies assessing the picture

International Nuclear Information System (INIS)

Povinec, P.P.; Togawa, O.

1998-01-01

A growing number of sources of radioactivity from human activities are found in the marine environment. They are known to include global nuclear fallout following atmospheric weapons tests, the Chernobyl accident, discharges of radionuclides from nuclear installations, past dumping of radioactive wastes, nuclear submarine accidents, contributions from nuclear testing sites, loss of radioactive sources, and the burn-up of satellites using radioisotopes as power sources. Overall, the world's marine environment contains radionuclides that differ from one region to another. Differences are due to dynamic marine environmental processes and the particular source of radionuclides in a region. Scientific assessments of marine radioactivity, therefore, require knowledge of both the source terms and oceanic processes. Radioactivity now is deposited unevenly over the world's oceans. Global fallout is known to be mainly due to nuclear weapon tests carried out in the 1960s. On the other hand, discharges from nuclear fuel reprocessing plants or past dumping of liquid and solid radioactive wastes generally are confined to more localized areas. Even so, soluble radionuclides have been transported over long distances by prevailing ocean currents. To estimate radionuclide inputs from local sources, scientists need to better understand the distribution of radionuclides throughout the world's oceans and seas. The understanding is important for analysing the results from scientific investigations of localized areas, such as part dumping sites, which then can be reviewed more thoroughly. As a contribution to fuller understanding of the marine environment, the IAEA's Marine Environment Laboratory (MEL) started a five-year project in 1996 entitled ''Research on Worldwide Marine Radioactivity (MARS)''. The work is supported by Japan's Science and Technology Agency (STA). This article briefly review this project, and describes related research activities and scientific investigations of MEL

Ab initio study of metastability of Eu{sup 3+} defect complexes in GaN

Energy Technology Data Exchange (ETDEWEB)

Ouma, Cecil N.M., E-mail: Cecil.Ouma@up.ac.za; Meyer, Walter E.

2014-04-15

Density functional theory (DFT) within the generalized gradient approximation (GGA) has been used to study the structural and electronic properties of Eu{sup 3+} defect complexes in GaN under Ga-rich conditions. Two distinct configurations of the Eu{sub Ga}V{sub N} defect complex, the axial and basal configuration, have been investigated. We report two forms of metastable defects namely; the Negative U defect in the lower half of the GaN band-gap and a metastable defect with two distinct configurations each with levels at E{sub C} −0.46 eV and −0.56 eV in the upper half of the GaN band-gap.

Synthesis and characterization of a liquid Eu precursor (EuCp{sup pm}{sub 2}) allowing for valence control of Eu ions doped into GaN by organometallic vapor phase epitaxy

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Brandon, E-mail: bmitchell@wcupa.edu [Department of Physics, West Chester University, West Chester, PA, 19383 (United States); Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan); Koizumi, Atsushi; Nunokawa, Takumi; Wakamatsu, Ryuta; Lee, Dong-gun; Saitoh, Yasuhisa; Timmerman, Dolf [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan); Kuboshima, Yoshinori; Mogi, Takayuki; Higashi, Shintaro; Kikukawa, Kaoru [Kojundo Chemical Laboratory Co., Ltd., 5-1-28 Chiyoda, Sakado, Saitama, 350-0284 (Japan); Ofuchi, Hironori; Honma, Tetsuo [Japan Synchrotron Radiation Research Institute (JASRI/SPring-8), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 (Japan); Fujiwara, Yasufumi, E-mail: fujiwara@mat.eng.osaka-u.ac.jp [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan)

2017-06-01

A liquid Eu precursor, bis(normal-propyl-tetramethylcyclopentadienyl)europium has been synthesized. This precursor exists as a liquid at temperatures higher than 49 °C, has a moderately high vapor pressure, contains no oxygen in its molecular structure, and can be distilled to high purity. These properties make it ideal for doping using a chemical vapor or atomic layer deposition method, and provide a degree of control previously unavailable. As a precursor the Eu exists in the divalent valance state, however, once doped into GaN by organometallic vapor phase epitaxy, the room-temperature photoluminescence of the Eu-doped GaN exhibited the typical red emission due to the intra-4f shell transition of trivalent Eu. After variation of the growth temperature, it was found that divalent Eu could be stabilized in the GaN matrix. By tuning the Fermi level through donor doping, the ratio of Eu{sup 2+} to Eu{sup 3+} could be controlled. The change in valence state of the Eu ions was confirmed using X-ray absorption near-edge structure. - Highlights: • A liquid Eu precursor was synthesized and its properties were characterized. • Precursor has a low melting point and a moderately high vapor pressure. • Does not contain oxygen in its molecular structure. • Eu can changed its valance state when incorporated into GaN. • Valence state of Eu in GaN can be controlled by donor doping.

Pressure-induced valence change and moderate heavy fermion state in Eu-compounds

Science.gov (United States)

Honda, Fuminori; Okauchi, Keigo; Sato, Yoshiki; Nakamura, Ai; Akamine, Hiromu; Ashitomi, Yosuke; Hedo, Masato; Nakama, Takao; Takeuchi, Tetsuya; Valenta, Jaroslav; Prchal, Jiri; Sechovský, Vladimir; Aoki, Dai; Ōnuki, Yoshichika

2018-05-01

A pressure-induced valence transition has attracted much attention in Eu-compounds. Among them, EuRh2Si2, EuNi2Ge2, and EuCo2Ge2 reveal the valence transition around 1, 2, and 3 GPa, respectively. We have succeeded in growing single crystals of EuT2X2 (T: transition metal, X: Si, Ge) and studied electronic properties under pressure. EuRh2Si2 indicates a first-order valence transition between 1 and 2 GPa, with a large and prominent hysteresis in the electrical resistivity. At higher pressures, the first-order valence transition changes to a cross-over regime with an intermediate valence state. Tuning of the valence state with pressure is reflected in a drastic change of the temperature dependence of the electrical resistivity in EuRh2Si2 single crystals. Effect of pressure on the valence states on EuRh2Si2, EuIr2Si2, EuNi2Ge2, and EuCo2Ge2, as well as an isostructural related compound EuGa4, are reviewed.

The EU's cybercrime and cyber-security rulemaking: mapping the internal and external dimensions of EU security

NARCIS (Netherlands)

Fahey, E.

2014-01-01

By taking the EU Cyber Strategy as a case in point, this contribution examines how the distinction between external and internal security in contemporary EU law manifests itself in large-scale risk regulation and in particular, how the EU relies upon external norms to regulate risk. This article

The innovation of EU environmental policy

DEFF Research Database (Denmark)

actors involved. The seven case-study chapters, written from a variety of perspectives, focus on such topics as the impact of formal and informal institutional factors on policy innovation, the potential influence of new members on EU environmental policy-making, the role of cross-national networks...... and alliances, the shifting balance between leader and laggard members, and the ongoing problem integrating the environment into other policy fields. The book also draws on theoretical approaches ranging from institutional to policy network analyses and examines such pertinent contemporary issues as packaging......Inspired by the recent accession of three environmentally progressive member states to the European Union (EU), this book explores the process of environmental policy innovation in the EU, the forces behind the introduction of new issues and policy approaches, and the roles played by the major...

Dependence of photoluminescence (PL) emission intensity on Eu3+ and ZnO concentrations in Y2O3:Eu3+ and ZnO·Y2O3:Eu3+ nanophosphors

CSIR Research Space (South Africa)

Mhlongo, GH

2011-08-01

Full Text Available Y2O3:Eu3+ and ZnO·Y2O3:Eu3+ nanophosphor powders with different concentrations of Eu3+ ions were synthesized by a sol–gel method and their luminescence properties were investigated. The red photoluminescence (PL) from Eu3+ ions with the main...

The photoluminescence/excitation (PL/E) spectroscopy of Eu-implanted GaN

KAUST Repository

O'Donnell, Kevin Peter

2011-05-01

Several distinct luminescent centres form in GaN samples doped with Eu. One centre, Eu2, recently identified as the isolated, substitutional Eu impurity, EuGa, is dominant in ion-implanted samples annealed under very high pressures (1 GPa) of N2. According to structural determinations, such samples exhibit an essentially complete removal of lattice damage caused by the implantation process. A second centre, Eu1, probably comprising EuGa in association with an intrinsic lattice defect, produces a more complex emission spectrum. In addition there are several unidentified features in the 5D0 to 7F2 spectral region near 620 nm. We can readily distinguish Eu1 and Eu2 by their excitation spectra, in particular through their different sensitivities to above-gap and below-gap excitation. The present study extends recent work on photoluminescence/ excitation (PL/E) spectroscopy of Eu1 and Eu2 to arrive at an understanding of these mechanisms in terms of residual optically active defect concentrations. We also report further on the \\'host-independent\\' excitation mechanism that is active in the case of a prominent minority centre. The relevance of this work to the operation of the red GaN:Eu light-emitting diode is discussed. © 2010 Elsevier B.V. All rights reserved.

The photoluminescence/excitation (PL/E) spectroscopy of Eu-implanted GaN

KAUST Repository

O'Donnell, Kevin Peter; Roqan, Iman S.; Wang, Ke; Lorenz, Katharina; Alves, Eduardo Jorge; Boćkowski, Michał X.

2011-01-01

Several distinct luminescent centres form in GaN samples doped with Eu. One centre, Eu2, recently identified as the isolated, substitutional Eu impurity, EuGa, is dominant in ion-implanted samples annealed under very high pressures (1 GPa) of N2. According to structural determinations, such samples exhibit an essentially complete removal of lattice damage caused by the implantation process. A second centre, Eu1, probably comprising EuGa in association with an intrinsic lattice defect, produces a more complex emission spectrum. In addition there are several unidentified features in the 5D0 to 7F2 spectral region near 620 nm. We can readily distinguish Eu1 and Eu2 by their excitation spectra, in particular through their different sensitivities to above-gap and below-gap excitation. The present study extends recent work on photoluminescence/ excitation (PL/E) spectroscopy of Eu1 and Eu2 to arrive at an understanding of these mechanisms in terms of residual optically active defect concentrations. We also report further on the 'host-independent' excitation mechanism that is active in the case of a prominent minority centre. The relevance of this work to the operation of the red GaN:Eu light-emitting diode is discussed. © 2010 Elsevier B.V. All rights reserved.

High-pressure luminescence spectroscopy of EuAl2O4 phosphor

International Nuclear Information System (INIS)

Zorenko, Yu.; Gorbenko, V.; Grinberg, M.; Turos-Matysiak, R.; Kuklinski, B.

2007-01-01

EuAl 2 O 4 powder phosphor was prepared by solid-state reaction of EuO and Al 2 O 3 oxides in vacuum. The influence of conditions of preparation on spectral lineshape of Eu 2+ emission was analyzed. It was found that the fluorescence spectra of vacuum-prepared EuAl 2 O 4 samples at 300 K present the superposition of three bands peaked at 430, 500 and 528 nm, corresponding to the 4f 6 5d 1 →4f 7 ( 8 S 7/2 ) transition of Eu 2+ ions in the different sites of EuAl 2 O 4 lattice. The luminescence of Eu 2+ centers in EuAl 2 O 4 host was also studied using the high-pressure spectroscopy up to 67 kbar. It was found that the bright green-yellow fluorescence of EuAl 2 O 4 at 300 K in the band peaked at 520-530nm range can be presented by superposition of two Gaussian sub-bands. The different pressure shifts -23 and -27cm -1 /kbar for two sub-bands were found. Such a structure of the emission spectrum was attributed to the existence of two different Eu 2+ centers in the Eu II 2+ sites of EuAl 2 O 4 lattice with higher coordination number

Management of Spent Sealed Radioactive Sources in Central and Eastern Europe (Czech Rep., Estonia, Hungary, Poland and Slovenia)

International Nuclear Information System (INIS)

Angus, M.J.; Moreton, A.D.; Wells, D.A.

2001-04-01

This study has been performed to consider the situation relating to the regulation and management of spent sealed radioactive sources (SSRS) in five central and Eastern European (C and EE) countries currently being considered for admission to the EU: the Czech Republic, Estonia, Hungary, Poland and Slovenia. The general aim of this study has been to acquire a thorough understanding of the management of SSRS in these five countries, in order to recommend improvements in management schemes and to establish whether the application of common disposal criteria would be advantageous. This report is structured in the following manner; following the Introduction (Section 1), there is description of current and proposed regulatory requirements in the EU, together with a summarised comparison of the regulatory systems in C and EE countries with EU standards in Section 2. Sections 3 to 7 are dedicated to the situation in each of the five countries. Each of these sections is similarly sub-divided to enable country-by-country and topic-by-topic comparison. In each of Sections 3 to 7 there is an overview, description of the sealed source inventory, regulations, current management practices, retrieval of unregistered SSRS, conclusions and a description of possible future technical assistance projects. Section 8 brings together a summary of the situation in each country, with conclusions and both country-specific and generic recommendations. A common concern in the five countries and also in existing EU member states is the problem of accidental inclusion of SSRS in consignments of scrap-metal. The detection of radioactive material at entrances to scrap metal facilities and at national borders has therefore received considerable attention in recent years. Practical issues regarding the detection of SSRS in scrap metal are described in Appendix A. None of the five countries considered in this report have any plans to develop regional disposal facilities and no specific common

Study on Environmental Fiscal Reform Potential in 14 EU Member States: Main Report & Appendices

DEFF Research Database (Denmark)

Hogg, Dominic; Andersen, Mikael Skou; Elliott, Timothy

2015-01-01

Environment Agency between 2010 and 2013 on the potential for environmental fiscal reform in four EU Member States affected by the economic crisis. As with the last study for the European Commission, the intention of this study is to indicate where this potential may lie, and to demonstrate the order...

Consequences of EU air quality directives for spatial development plans in various EU countries

International Nuclear Information System (INIS)

Koelemeijer, R.B.A.; Blom, W.F.; Bouwman, A.A.; Hammingh, P.; Backes, C.W.

2005-01-01

Over the past few years, the highest Dutch court of justice has rejected many building plans for new homes, roads and businesses because of reasons related to EU air quality limit values. This has made it clear that detailed impact assessments are necessary to having plans approved for permits, and that failure to achieve limit values can be a reason to reject a plan. An investigation to see whether such issues have also played a role in other EU countries has proven the contrary. Only a few similar court cases have taken place in other countries, while air quality limit values are breached in other EU countries as well. The reason is that the Netherlands has implemented the first EU Daughter Directive in a relatively strict manner in comparison to other countries, in particular: Adopting a strict legal coupling of air quality and spatial planning policies, with many types of plans being subject to an air quality impact assessment; Perceiving limit values as absolute limit values, whereas in many other countries a need to meet a limit value is weighted with other interests in granting permits; Applying limit values to the whole country. Although this application is, in principle, valid for all EU member states, some member states apply limit values only to locations where people can be exposed; Since air quality assessment is detailed in the Netherlands, many locations are appointed where air quality limit values are breached. Clearly, the role of limit values in granting permits for plans differs considerably among the EU countries, while the underlying EU legislation is the same, and while limit values are breached in other countries as well [nl

Magnetic oxide heterostructures. EuO on cubic oxides and on silicon

International Nuclear Information System (INIS)

Caspers, Christian

2013-01-01

strained EuO thin film shows a Poisson ratio of ν EuO ∼ 0. The tensile strain reduces the Curie temperature significantly by 12.3 K. The MCD effect provides an advanced magnetic characterization: the MCD asymmetries in Eu core-level photoemission reveal a larger reduction due to the tensile strain than obtained from bulk-averaging SQUID measurements. Thus, the mechanism of tensile strain on intra-atomic exchange (indicated by MCD) is significantly different than on the spin order of the 4f 7 shell (indicated by SQUID). Experiments on EuO by MCD, thereby, reveal exciting perspectives for studying fundamental magnetic properties of EuO. In the second part of this thesis, we explore how to integrate EuO directly with Si (001). We focus on interface engineering of structural and chemical properties of the EuO/Si (001) spin-functional heterointerface. In response to the extremely high chemical reactivity and pronounced surface kinetics of Eu, EuO, and Si during EuO synthesis at elevated temperatures, we initially conduct a thermodynamic analysis of the EuO/Si interface. In this way, we decide to investigate three in situ passivation techniques for the Si (001) surface, in order to prevent metallic and oxide contaminations at the EuO/Si interface. both being main antagonists for spin-selective tunneling. We conduct a comprehensive optimization study of the EuO/Si heterointerface by tuning the passivation parameters of the Si (001) surface and the growth parameters of EuO. Using HAXPES, we evaluate Si and Eu core-level spectra and determine the minimum of interface contaminants as d opt (SiO x ) = 0.69 nm concomitant with d opt (EuSi 2 ) = 0.20 nm, both of which are clearly in the subnanometer regime. In conclusion, our ultrathin EuO/Si (001) heterostructures reveal a high chemical quality of the spinfunctional interface, combined with magnetic properties of the EuO layer akin to bulk. By selected interface passivation methods, we achieve a reduction of residual contaminations

Spectroscopic investigations on the complexation of Cm(III) and Eu(III) with organic model ligands and their binding mode in human urine (in vitro); Spektroskopische Untersuchungen zur Komplexbildung von Cm(III) und Eu(III) mit organischen Modellliganden sowie ihrer chemischen Bindungsform in menschlichem Urin (in vitro)

Energy Technology Data Exchange (ETDEWEB)

Heller, Anne

2011-10-26

In case of incorporation, trivalent actinides (An(III)) and lanthanides (Ln(III)) pose a serious health risk to humans. An(III) are artificial, highly radioactive elements which are mainly produced during the nuclear fuel cycle in nuclear power plants. Via hazardous accidents or nonprofessional storage of radioactive waste, they can be released in the environment and enter the human food chain. In contrast, Ln(III) are nonradioactive, naturally occurring elements with multiple applications in technique and medicine. Consequently it is possible that humans get in contact and incorporate both, An(III) and Ln(III). Therefore, it is of particular importance to elucidate the behaviour of these elements in the human body. While macroscopic processes such as distribution, accumulation and excretion are studied quite well, knowledge about the chemical binding form (speciation) of An(III) and Ln(III) in various body fluids is still sparse. In the present work, for the first time, the speciation of Cm(III) and Eu(III) in natural human urine (in vitro) has been investigated spectroscopically and the formed complex identified. For this purpose, also basic investigations on the complex formation of Cm(III) and Eu(III) in synthetic model urine as well as with the urinary relevant, organic model ligands urea, alanine, phenylalanine, threonine and citrate have been performed and the previously unknown complex stability constants determined. Finally, all experimental results were compared to literature data and predictions calculated by thermodynamic modelling. Since both, Cm(III) and Eu(III), exhibit unique luminescence properties, particularly the suitability of time-resolved laser-induced fluorescence spectroscopy (TRLFS) could be demonstrated as a method to investigate these metal ions in untreated, complex biofluids. The results of this work provide new scientific findings on the biochemical reactions of An(III) and Ln(III) in human body fluids on a molecular scale and

Radioactivity Monitoring of the Irish Environment 2010-2011

International Nuclear Information System (INIS)

McGinnity, P.; Currivan, L.; Dowdall, A.; Hanley, O.; Kelleher, K.; McKittrick, L.; Pollard, D.; Somerville, S.; Wong, J.; McMahon, C.

2012-11-01

This report presents the results of the environmental radioactivity monitoring programme carried out by the Radiological Protection Institute of Ireland RPII during 2010 and 2011. The RPII has routinely monitored levels of radioactivity in the Irish environment since 1982 and this is the latest in the RPII's series of environmental monitoring reports. The RPII reviews and updates its environmental programme annually to ensure it remains relevant and continues to focus on the most important sources of radioactivity in the environment. The data presented in this report confirm that while the levels of artificial radioactivity in the Irish environment are detectable, they are low. They do not pose a significant risk to the human health of the Irish population. Trace amounts of radioactive isotopes consistent with the Fukushima nuclear accident were detected in air, rainwater and milk samples during the period March to May 2011. These increases in levels of radioactivity were not of concern from a public health point of view. For the remainder of the reporting period, activity concentrations of radionuclides in airborne particles were low and consistent with measurements made in recent years. Radioactivity levels in milk, mixed diet and a wide range of foodstuffs were low and, for the majority of samples, below the detection limits. All drinking waters tested were found to be in compliance with the total indicative dose defined in national and EU legislation. The doses incurred by the Irish public in 2010 and 2011 as a result of artificial radioactivity in the marine environment are small when compared to dose limits or to natural radiation doses received by the Irish public. The doses to the most exposed individuals, members of the oyster and mussel farmers critical group, were approximately 0.02 per cent and 0.05 per cent of the annual dose limit of 1000 microsieverts for members of the public from practices involving controllable sources of radiation in 2010 and

Radioactive wastes

International Nuclear Information System (INIS)

Teillac, J.

1988-01-01

This study of general interest is an evaluation of the safety of radioactive waste management and consequently the preservation of the environment for the protection of man against ionizing radiations. The following topics were developed: radiation effects on man; radioactive waste inventory; radioactive waste processing, disposal and storage; the present state and future prospects [fr

Tendances Carbone no. 104. Towards a re-calibrated EU ETS for 2030: assessment of the legislative proposal to revise the EU ETS Directive

International Nuclear Information System (INIS)

Jalard, Matthieu; Alberola, Emilie

2015-07-01

Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. Beside some statistical figures about energy production/consumption and carbon markets, this issue specifically addresses the following points: - EU ETS -Directive: On July 15, the EU Commission released a legislative proposal to revise the EU ETS Directive post-2020, translating into legislation the October 2014 Council Conclusions. - EU ETS carbon leakages provisions: The legislative proposal includes a 43% share of free allocation from 2021 to 2030, a new Carbon leakage list representing 93% of industrial emissions, an update of production levels and benchmarks every five years

Public Integrity, Economic Freedom and Governance Performance. A Comparative Study for the EU Member States and Acceding Countries

Directory of Open Access Journals (Sweden)

Ani MATEI

2010-11-01

Full Text Available The studies concerning the impact of corruption on the effectiveness of governance are numerous, valorising profound approaches, based on criteria and standards related to good governance, organizational behaviour. The concepts and mechanisms specific for econometrics and statistics provide the quantitative support for qualitative analyses, substantiating public policies, in view to assure effectiveness in performance measurement. For EU Member States and acceding countries, the level of development and social organization determines specific ethical behaviours. In this context, the current paper aims a comparative economic and social evaluation of the correlations between corruption, performance and economic freedom in the states mentioned, following the various significant stages of the EU enlargement. The working hypotheses turn into consideration the following issues:# Corruption holds national specific character and the statistic, econometric or sociologic analyses reveal that it is stable during time.# The climate of economic freedom and the intensity of corruption influence powerfully the economic performance.# The EU membership, “seniority” in EU, regional context determine different attitudes and perceptions on the corruption phenomena.# For the newer EU states or the acceding countries, the strategies of integrity have mimetic character and the National Integrity Systems have structured powerful connections aimed at determining an action focused on public integrity.In the analyses achieved, the EU is approached globally, at least from statistic point of view, and the conclusions aim situations specific to the groups of states that have been or will be the beneficiaries of the EU enlargement. The quantitative analyses use both own results of the researches carried out by the authors and public results of World Bank or Heritage Foundation, as well as results of authorities responsible for national statistics. The paper uses the

Decontamination of radioactive materials (part II)

Energy Technology Data Exchange (ETDEWEB)

Akashi, Makoto; Shimomura, Satoshi; Hachiya, Misao [National Inst. of Radiological Sciences, Chiba (Japan)

1998-06-01

Drifting agents accelerate the exchange process and thus promote to eliminate radioactive materials from human body. The earlier is the administration of the agent, the more effective is the elimination. Against the uptake of radioiodine by thyroid, anti-thyroid drug like NaI, Lugol`s iodine solution, propylthiouracil and methimazole are recommended. Ammonium chloride can be a solubilizer of radioactive strontium. Diuretics may be useful for excretion of radioisotopes of sodium, chlorine, potassium and hydrogen through diuresis. Efficacy of expectorants and inhalants is not established. Parathyroid extract induces decalcification and thus is useful for elimination of 32P. Steroids are used for compensating adrenal function and for treatment of inflammation and related symptoms. Chelating agents are useful for removing cations and effective when given early after contamination. EDTA and, particularly, DTPA are useful for elimination of heavy metals. For BAL (dimercaprol), its toxicity should be taken into consideration. Penicillamine is effective for removing copper and deferoxamine, for iron. Drugs for following radioisotopes are summarized: Am, As, Ba, Br, Ca, Cf, C, Ce, Cs, Cr, Co, Cm, Eu, fission products, F, Ga, Au, H, In, I, Fe, Kr, La, PB, Mn, Hg, Np, P, Pu, Po, K, Pm, Ra, Rb, Ru, Sc, Ag, Na, Sr, S, Tc, Th, U, Y, Zn and Zr. Lung and bronchia washing are effective for treatment of patients who inhaled insoluble radioactive particles although their risk-benefit should be carefully assessed. The present review is essentially based of NCRP Report No.65. (K.H.) 128 refs.

Study of proton radioactivities

Energy Technology Data Exchange (ETDEWEB)

Davids, C.N.; Back, B.B.; Henderson, D.J. [and others

1995-08-01

About a dozen nuclei are currently known to accomplish their radioactive decay by emitting a proton. These nuclei are situated far from the valley of stability, and mark the very limits of existence for proton-rich nuclei: the proton drip line. A new 39-ms proton radioactivity was observed following the bombardment of a {sup 96}Ru target by a beam of 420-MeV {sup 78}Kr. Using the double-sided Si strip detector implantation system at the FMA, a proton group having an energy of 1.05 MeV was observed, correlated with the implantation of ions having mass 167. The subsequent daughter decay was identified as {sup 166}Os by its characteristic alpha decay, and therefore the proton emitter is assigned to the {sup 167}Ir nucleus. Further analysis showed that a second weak proton group from the same nucleus is present, indicating an isomeric state. Two other proton emitters were discovered recently at the FMA: {sup 171}Au and {sup 185}Bi, which is the heaviest known proton radioactivity. The measured decay energies and half-lives will enable the angular momentum of the emitted protons to be determined, thus providing spectroscopic information on nuclei that are beyond the proton drip line. In addition, the decay energy yields the mass of the nucleus, providing a sensitive test of mass models in this extremely proton-rich region of the chart of the nuclides. Additional searches for proton emitters will be conducted in the future, in order to extend our knowledge of the location of the proton drip line.

Radioautographic studies of the radioactive ashes obtained from the No. 5 Fukuryu Maru

Energy Technology Data Exchange (ETDEWEB)

Kikuchi, T; Akagi, H; Goto, H; Wakisaka, G

1954-01-01

Radioautographic studies have been made of the radioactive ashes obtained from the ship by use of x-ray film, radioautographic stripping plates, and plates of ..cap alpha..-emitters. The radioactivity was found not proportional to the size of the particle, and the distribution of radioactivity in each particle was not uniform.

Reforming the EU Budget

DEFF Research Database (Denmark)

Citi, Manuele

The marginal involvement of the EU in redistributive policies and its limited fiscal resources have led to a lack of attention to the EU budget and its determinants. In this paper I analyse an original dataset containing yearly data on the main macrocategories of expenditure and how they have...

Dy:Eu doped CaBAl glasses for white light applications

Science.gov (United States)

Lodi, T. A.; Sandrini, M.; Medina, A. N.; Barboza, M. J.; Pedrochi, F.; Steimacher, A.

2018-02-01

The combination of Eu3+ and Dy3+ in co-doped glassy materials provides interesting applicability for white light emission devices. In this work, Dy:Eu doped Calcium Boroaluminate (CaBAl) glasses were prepared by conventional melting quenching, with 3 wt% of Dy2O3 and Eu2O3 content varying from 0 to 3 wt%, and results of absorption spectra, photoluminescence and photoluminescence lifetime are discussed in terms of Eu2O3 content. The photoluminescence of the samples was studied under excitation of 365 and 405 nm light source. The 365 nm excitation shows favor to the Dy3+ ion emission. The results of photoluminescence lifetime at 575 nm (Dy3+) shows a decrease due to Eu2O3 addition, which suggests an energy transfer from Dy3+ (donor) to the Eu3+ (acceptor). On the other hand, under excitation of 405 nm, the photoluminescence lifetime at 575 nm (Dy3+) shows no significant changes due to Eu2O3 amount, which indicates that the energy transfer from Dy3+ to Eu3+ (under λexc = 405 nm) is negligible. However, the results of photoluminescence under 405 nm excitation present a white yellowish emission in the CIE diagram, which shifts to red with Eu2O3 addition. The combination of a Blue LED (BL) emission with the emission of the samples was also studied in the CIE diagram, in order to improve light emission and to obtain ideal White Light (WL). The results show that by modifying the emission intensity of BL, it is possible to achieve a route for smart lighting, close to the circadian light cycle.

EU Labour Law

DEFF Research Database (Denmark)

Nielsen, Ruth

The focus in this book is upon EU labour law and its interaction with national and international labour law. The book provides an analysis of the framework and sources of European labour law. It covers a number of substantive topics, notably collective labour law, individual employment contracts......, discrimination on grounds of sex and on other grounds, free movement of persons, restructuring of enterprises, working environment and enforcement of rights derived from EU labour law....

Varying Eu2+ magnetic order by chemical pressure in EuFe2(As1-xPx)2

Science.gov (United States)

Zapf, S.; Wu, D.; Bogani, L.; Jeevan, H. S.; Gegenwart, P.; Dressel, M.

2011-10-01

Based on low-field magnetization measurements on a series of single crystals, we present a scheme of the Eu2+ spin alignment in EuFe2(As1-xPx)2. We explain observations of the Eu2+ ordering previously reported, reconciling different existing phase diagrams. The magnetic moments of the Eu2+ ions are slightly canted, yielding a ferromagnetic contribution along the c direction that becomes stronger with pressure, until superconductivity sets in. The spin-density wave as well as the superconducting phase coexist with an antiferromagnetic interlayer coupling of the canted spins. Reducing the interlayer distance finally leads to a ferromagnetic Eu2+ interlayer coupling and to the suppression of superconductivity.

Optical and Piezoelectric Study of KNN Solid Solutions Co-Doped with La-Mn and Eu-Fe

Directory of Open Access Journals (Sweden)

Jesús-Alejandro Peña-Jiménez

2016-09-01

Full Text Available The solid-state method was used to synthesize single phase potassium-sodium niobate (KNN co-doped with the La3+–Mn4+ and Eu3+–Fe3+ ion pairs. Structural determination of all studied solid solutions was accomplished by XRD and Rietveld refinement method. Electron paramagnetic resonance (EPR studies were performed to determine the oxidation state of paramagnetic centers. Optical spectroscopy measurements, excitation, emission and decay lifetime were carried out for each solid solution. The present study reveals that doping KNN with La3+–Mn4+ and Eu3+–Fe3+ at concentrations of 0.5 mol % and 1 mol %, respectively, improves the ferroelectric and piezoelectric behavior and induce the generation of optical properties in the material for potential applications.

Key challenges in the combat of human trafficking : Evaluating the EU trafficking strategy and EU trafficking directive

NARCIS (Netherlands)

Bosma, Alice; Rijken, Conny

2016-01-01

The problem of trafficking in human beings (THB) is still omnipresent in Europe, despite the numerous preventive and retributive actions taken. This article evaluates the two most important EU-instruments to combat trafficking: the EU Directive and the EU Strategy. Based on secondary analysis of

Synthesis, characterization and luminescence study of Eu3+ doped Y2Sn2O7 nano-particles

International Nuclear Information System (INIS)

Nigam, Sandeep; Sudarsan, V.; Vatsa, R.K.

2011-01-01

In recent years, advanced materials derived from Pyrochlore-type oxides (A 2 B 2 O 7 ), have been of extensive scientific and technological interest. Chemical substitution of A or B sites of pyrochlore oxide by rare earth ions is a widely used approach to prepare thermally stable, lanthanide ion doped luminescent materials. The present study deals with the synthesis and characterization of Eu 3+ doped Y 2 Sn 2 O 7 : nanoparticles prepared by the hydrolysis of Y 3+ , Sn 4+ , and Eu 3+ in ethylene glycol medium followed by heating at 700 deg C for 4 hours. As prepared samples are amorphous in nature and 700 deg C heated sample showed well crystalline pyrochlore structure in XRD studies. Average particle size is calculated from the width of the X-ray diffraction peaks and found to t be around 5 nm. Luminescence measurements were carried out for as prepared and 700 deg C heated samples. The undoped as prepared sample showed a broad emission peak around 420 nm after excitation at 285 nm. While for 700 deg C undoped heated sample, the peak maxima was shifted to 435 nm. The emission spectrum for doped as prepared samples is characterized by both host emission around 420 nm along with the characteristic Eu 3+ emission peaks in the visible region. However, very poor Eu 3+ emission from heated sample was observed

The innovation impact of EU emission trading. Findings of company case studies in the German power sector

Energy Technology Data Exchange (ETDEWEB)

Rogge, Karoline S. [Fraunhofer-Institut fuer Systemtechnik und Innovationsforschung (ISI), Karlsruhe (Germany); Swiss Federal Inst. of Technology Zurich (ETH Zurich) (Switzerland). Dept. of Management, Technology, and Economics; Schneider, Malte; Hoffmann, Volker H. [Swiss Federal Inst. of Technology Zurich (ETH Zurich) (Switzerland). Dept. of Management, Technology, and Economics

2010-05-01

This paper provides a comprehensive analysis of how the European Emission Trading System (EU ETS) as the core climate policy instrument of the European Union has impacted innovation. Towards this end, we investigate the impact of the EU ETS on research, development, and demonstration (RD and D), adoption, and organizational change. In doing so, we pay particular attention to the rela-tive influences of context factors (policy mix, market factors, public acceptance) as well as firm characteristics (value chain position, technology portfolio, size, vision). Empirically, our analysis is based on multiple case studies with 19 power generators, technology providers, and project developers in the German power sector which we conducted from June 2008 until June 2009. We find that the innovation impact of the EU ETS has remained limited so far because of the scheme's initial lack in stringency and predictability and the relatively greater importance of context factors. Additionally, the impact varies tremendously across technologies, firms, and innovation dimensions, and is most pronounced for RD and D on carbon capture technologies and corporate procedural change. Our analysis suggests that the EU ETS by itself may not provide sufficient incentives for fundamental changes in corporate climate innovation activities at a level adequate for reaching political long-term targets. Based on the study's findings, we derive a set of policy and research recommendations. (orig.)

Spectroscopic study and enhanced thermostability of combustion-derived BaMgAl10O17:Eu2+ blue phosphors for solid-state lighting

Science.gov (United States)

Pradal, Nathalie; Potdevin, Audrey; Chadeyron, Geneviève; Bonville, Pierre; Caillier, Bruno; Mahiou, Rachid

2017-02-01

Blue-emitting BaMgAl10O17:Eu2+ (BAM:Eu), suitable for applications in a next generation of Hg-free lamps based on UV LEDs, was prepared by a microwave induced solution combustion synthesis, using urea as combustion fuel and nitrates as oxidizers. Purity control of the as-synthesized blue phosphor was undertaken by a washing step followed by a reduction one. Structural and morphological properties of the outcoming phosphors have been considered. Synthesis process allows producing a well-crystallized and nanostructured BAM phase within only few minutes. The influence of reduction treatment on the relative amounts of Eu2+/Eu3+ in our samples has been investigated through an original study by magnetization and Mössbauer spectroscopy. Furthermore, a complete optical study has been carried out and allowed us to determine the europium localization in the three possible sites in BAM matrix. The percentage of Eu2+ increased twofold after the reduction treatment, entailing an increase in the luminescence efficiency upon UV excitation. Finally, temperature-dependent luminescence of combustion-derived powders has been studied till 170 °C and compared to that of commercial BAM:Eu. MISCS-derived phosphors present a higher thermal stability than commercial one: whereas the emission efficiency of this last was reduced by 64%, the one of combustion-derived BAM:Eu experienced an only 12% decline. Furthermore, while commercial BAM suffered from a severe blue-shift with increasing temperature, our phosphors keep its color quality with a good stability of the photometric parameters.

Safety disposal studies of radioactive and hazardous wastes using cement

International Nuclear Information System (INIS)

Aly, M.M.E.

2000-01-01

radioactive waste is generated from the production of nuclear energy and from the use of radioactive materials applications, agriculture and medicine. the important of safe management of radioactive waste for the protection of human health and the environment has long been recognized. conditioning of radioactive waste is the transform of radioactive waste into a suitable form for storage and disposal. common immobilization methods include solidification of low radioactive waste in cement or bitumen.in order to improve cement properties to decrease the release of liquid radioactive waste into the environment and its dispersion to a level where the risks to individuals, population and the environment

EU's hær skal tale tyrkisk

DEFF Research Database (Denmark)

Adler-Nissen, Rebecca

2009-01-01

For at kunne udleve sine accelererende forsvarsambitioner har EU brug for at låne Tyrkiets 600.000 soldater. Hvis Tyrkiet ikke kan blive EU-medlem, må svaret være at give tyrkerne 'associeret medlemskab' af EU's sikkerhedspolitik. Sker det, vil Tyrkiet med ét være bedre integreret i EU-forsvaret ...

Are EU Banks Safe?

NARCIS (Netherlands)

R.J. Theissen (Roel)

2013-01-01

markdownabstract__Abstract__ What exactly are the rules banks are subject to, and are they fit for purpose? These are the two questions addressed in this book ‘Are EU banks safe?’ and its descriptive companion book ‘EU banking supervision’. The full rulebook on banks is difficult to find

Structural and optical studies on Eu3+ doped boro-tellurite glasses

Science.gov (United States)

Maheshvaran, K.; Veeran, P. K.; Marimuthu, K.

2013-03-01

Eu3+ doped boro-tellurite glasses (69 - x)B2O3 + xTeO2 + 15Na2CO3 + 15NaF + 1Eu2O3 (where x = 0, 10, 20, 30 and 40 wt%) have been prepared and their structural and optical properties were studied through XRD, FTIR, absorption, luminescence and decay time measurements. The FTIR spectra reveal the presence of B-O-B bond bending vibrations and Te-O-Te or O-Te-O linkage bending vibrations in the prepared glasses. The absorption spectral measurements were used to calculate the bonding parameters (β¯, δ). The direct, indirect allowed band gap (Eopt), band tail parameter (B) and Urbach energy (ΔE) values of the prepared glasses have also been determined from the absorption spectral measurements. The phonon sideband is observed from the excitation spectra on the higher energy side of the 7F0 → 5D2 transition. The phonon energy (hω) and the electron-phonon coupling constant (g) were also derived from the phonon sideband spectra. Through the luminescence spectra, Judd-Ofelt (JO) intensity parameters (Ωλ, λ = 2, 4 and 6) and the luminescence intensity ratio (R) have been determined. The JO parameters have also been used to calculate the radiative properties like transition probability (A), stimulated emission cross-section (σPE), radiative lifetime (τrad), and branching ratios (βR) for the 5D0 → 7FJ (J = 0, 1, 2, 3 and 4) emission transitions of the Eu3+ ions. The experimental lifetime of the 5D0 level is found to be single exponential for all the prepared glasses. The obtained results were discussed and reported in the present work.

The EU sustainable energy policy indicators framework.

Science.gov (United States)

Streimikiene, Dalia; Sivickas, Gintautas

2008-11-01

The article deals with indicators framework to monitor implementation of the main EU (European Union) directives and other policy documents targeting sustainable energy development. The main EU directives which have impact on sustainable energy development are directives promoting energy efficiency and use of renewable energy sources, directives implementing greenhouse gas mitigation and atmospheric pollution reduction policies and other policy documents and strategies targeting energy sector. Promotion of use of renewable energy sources and energy efficiency improvements are among priorities of EU energy policy because the use of renewable energy sources and energy efficiency improvements has positive impact on energy security and climate change mitigation. The framework of indicators can be developed to establish the main targets set by EU energy and environmental policies allowing to connect indicators via chain of mutual impacts and to define policies and measures necessary to achieve established targets based on assessment of their impact on the targeted indicators representing sustainable energy development aims. The article discusses the application of indicators framework for EU sustainable energy policy analysis and presents the case study of this policy tool application for Baltic States. The article also discusses the use of biomass in Baltic States and future considerations in this field.

Radioactivity in the oil industry - how much is it and is it of any concern

International Nuclear Information System (INIS)

Thingvoll, J.T.

1996-01-01

Oil producing countries around the North Sea generate annually around 200 tons of naturally occurring radioactive waste materials. This paper deals with the health risk from radiation doses received by workers and the public from handling and processing LSA (Low Specific Activity) scale. The values of specific activity (Bq/g) and the total becquerel (Bq) activity of the scale exceeds the exemption levels suggested in the EU (European Union) directive on ionizing radiation (1994 revision). If the proposed EU directive comes into force the consequences will be large and mostly negative in terms of public image and cost. The improvements in radiological protection for the workers and public in general are anticipated to be minor. A few recommendations to address these problems have been suggested. 19 refs., 8 tabs

Radioactivity in the oil industry - how much is it and is it of any concern

Energy Technology Data Exchange (ETDEWEB)

Thingvoll, J.T. [Norske Stats Oljeselskap A.S., Stavanger (Norway)

1996-12-31

Oil producing countries around the North Sea generate annually around 200 tons of naturally occurring radioactive waste materials. This paper deals with the health risk from radiation doses received by workers and the public from handling and processing LSA (Low Specific Activity) scale. The values of specific activity (Bq/g) and the total becquerel (Bq) activity of the scale exceeds the exemption levels suggested in the EU (European Union) directive on ionizing radiation (1994 revision). If the proposed EU directive comes into force the consequences will be large and mostly negative in terms of public image and cost. The improvements in radiological protection for the workers and public in general are anticipated to be minor. A few recommendations to address these problems have been suggested. 19 refs., 8 tabs.

EU agricultural reform fails on biodiversity

NARCIS (Netherlands)

Pe'er, G.; Dicks, L.V.; Visconti, A.; Arlettaz, R.; Baldi, A.; Kleijn, D.; Scott, A.V.

2014-01-01

In December 2013, the European Union (EU) enacted the reformed Common Agricultural Policy (CAP) for 2014–2020, allocating almost 40% of the EU's budget and influencing management of half of its terrestrial area. Many EU politicians are announcing the new CAP as “greener,” but the new environmental

Biomass supply in EU27 from 2010 to 2030

International Nuclear Information System (INIS)

Panoutsou, Calliope; Eleftheriadis, John; Nikolaou, Anastasia

2009-01-01

With biomass staying high in the EU political agenda and most of the recent documents acknowledging that it has the potential to make a very significant contribution to reaching the 20% target [], the issue of supply in terms of feedstock types, availability constraints and costs in different Member States is set to determine the future technology uptake and market deployment prospects. This paper is based on one of the initial studies, 'Bioenergy's role in the EU market. A view of developments until 2020', and presents a structured review for EU biomass resources, aiming to map technical potentials and provide detailed information on availability, costs and future trends for biomass potentials of different residual feedstocks in EU27. (author)

Public information on radioactive waste: a study of an emerging issue

International Nuclear Information System (INIS)

Bronfman, L.M.; Bronfman, B.H.; Regens, J.L.

1979-10-01

Through an analysis of information provided in the printed media on the topic of radioactive waste, the study analyzes the emergence of radioactive waste as a public issue in the press. Over eight hundred articles printed in both specialized and non-specialized sources from 1973 to 1978 have been content-analyzed in order to describe how the problem of radioactive waste is defined and what dimensions of the problems are receiving attention. Between 1973 and 1978, there was a substantial increase in the amount of information on the topic of radioactive waste available to the public through a variety of popular and specialized media sources. This increase coincides with documented public concern with the problem of radioactive waste. Discussions of radioactive waste have focused for all sources more frequently on themes not directly related to the technical problems of radioactive waste storage or isolation. A substantial amount of the information available to a variety of segments of the public is composed of discussions of real or perceived risk related to the existence of waste or to methods of disposing of it. In addition to risk, a substantial proportion of the discussions deal with institutional themes. Over time, the total amount of information on most dimensions of the radioactive waste problem has increased substantially. Institutional themes have gained relative to other issues over the three time periods. National and local press sources infrequently specify the form of waste being discussed thus providing evidence that the quality of technical information available to some members of the public is very low

Femtosecond laser-induced reduction in Eu-doped sodium borate glasses

Energy Technology Data Exchange (ETDEWEB)

Lim, Ki-Soo [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of)]. E-mail: kslim@chungbuk.ac.kr; Lee, Sunkyun [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Trinh, Minh-Tuan [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Kim, Suk-Ho [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Lee, Myeongkyu [Departent of Materials Science and Engineering, Yonsei University, 134 Shinchon-dong, Seoul 120-749 (Korea, Republic of); Hamilton, Douglas S. [Department of Physics, University of Connecticut, Storrs, CT 06269 (United States); Gibson, George N. [Department of Physics, University of Connecticut, Storrs, CT 06269 (United States)

2007-01-15

In this work, we report permanent reduction of Eu{sup 3+} to Eu{sup 2+} in sodium borate glasses by irradiation of near-infrared femtosecond laser. Glass composition of sodium borate was 85B{sub 2}O{sub 3}-15Na{sub 2}O. The glasses were doped with 0.05, 0.1, and 0.5 mol% Eu{sub 2}O{sub 3}. Absorption and fluorescence dynamics were studied to investigate valence state change of europium ions and the energy transfer between Eu{sup 2+} and Eu{sup 3+} ions. As the femtosecond laser intensity or exposure time increases, the emission band at 400 nm becomes stronger. However, the photoreduction efficiency decreases as the dopant concentration increases. We discuss the photoreduction mechanism under multiphoton absorption.

Measuring health literacy among low literate people: an exploratory feasibility study with the HLS-EU questionnaire.

Science.gov (United States)

Storms, Hannelore; Claes, Neree; Aertgeerts, Bert; Van den Broucke, Stephan

2017-05-19

Health literacy (HL) is defined as necessary competencies to make well-informed decisions. As patients' decision making is a key element of patient-centered health care, insight in patients' HL might help healthcare professionals to organize their care accordingly. This is particularly true for people in a vulnerable situation, potentially with limited HL, who are, for instance, at greater risk of having limited access to care [1, 2]. As HL correlates with education, instruments should allow inclusion of low literate people. To that end, the relatively new instrument, HLS-EU-Q47, was subjected to a comprehensibility test, its shorter version, HLS-EU-Q16, was not. Therefore, the goal of this study was to examine feasibility of HLS-EU-Q16 (in Dutch) for use in a population of people with low literacy. Purposive sampling of adults with low (yearly) income (literacy. However, to facilitate the use and interpretation, some questions would benefit from minor adjustments: by simplifying wording or providing explanatory, contextual information.

Development of BaSO4:Eu thermoluminescence phosphor

International Nuclear Information System (INIS)

Madhusoodanan, U.; Jose, M.T.; Lakshmanan, A.R.

1999-01-01

A highly sensitive thermoluminescence (TL) phosphor based on BaSO 4 :Eu was developed following the coprecipitation technique and firing in argon atmosphere at 1123 K. Photoluminescence studies confirm that firing in argon atmosphere instead of air increased the incorporation of Eu ions in 2+ valence state. At low γ-ray doses, its TL sensitivity is nearly 2 to 3 times higher than that of CaSO 4 :Dy phosphor. The other salient features of this BaSO 4 :Eu TL phosphor are a constant glow curve shape and a nearly linear γ-ray dose response

Studies of Eu2O3 - Bi2O3 - B2O3 glasses using Raman and IR spectroscopy

International Nuclear Information System (INIS)

Pop, Lidia; Culea, Eugen N.; Bratu, I.

2004-01-01

The bismuth borate (3Bi 2 O 3 ·B 2 O 3 ) glasses were prepared with different concentrations of Eu 3+ . The structure of these systems were investigated by Raman and IR spectroscopy. The structural study reveals that the glasses contain BiO 3 , BiO 6 , BO 3 , BO 4 and Eu-O structural units. For the samples with a higher content of Eu 2 O 3 , the spectra became very large indicating a more disordered structure. The hygroscopic character of the 3Bi 2 O 3 ·B 2 O 3 glass matrix and the progressive decrease of this behaviour with increasing the Eu 2 O 3 content was observed. Therefore, we conclude that the europium oxide acts as a network modifier in these glasses. (authors)

Structure-composition sensitivity in 'Metallic' Zintl phases: A study of Eu(Ga1-xTtx)2 (Tt=Si, Ge, 0≤x≤1)

International Nuclear Information System (INIS)

You, Tae-Soo; Zhao Jingtai; Poettgen, Rainer; Schnelle, Walter; Burkhardt, Ulrich; Grin, Yuri; Miller, Gordon J.

2009-01-01

Two isoelectronic series, Eu(Ga 1-x Tt x ) 2 (Tt=Si, Ge, 0≤x≤1), have been synthesized and characterized by powder and single-crystal X-ray diffraction, physical property measurements, and electronic structure calculations. In Eu(Ga 1-x Si x ) 2 , crystal structures vary from the KHg 2 -type to the AlB 2 -type, and, finally, the ThSi 2 -type structure as x increases. The hexagonal AlB 2 -type structure is identified for compositions 0.18(2)≤x 3 nets. As smaller Si atoms replace Ga atoms while the number of valence electrons increases, the lattice parameters, unit cell volumes, and Ga-Si distances in this phase region decrease significantly. Although aspects of X-ray diffraction results suggest puckering of the 6 3 nets for the Si-richest example of the AlB 2 -type Eu(Ga 1-x Si x ) 2 , the complete experimental evidence remains inconclusive. On the other hand, in Eu(Ga 1-x Ge x ) 2 , six different structural types were observed as x varies. In addition to EuGa 2 (KHg 2 -type; space group Imma) and EuGe 2 (own structure type, space group P3-barm1), the ternary phases studied show four different structures: the AlB 2 -type for Ga-rich compositions; the YPtAs-type structure for EuGaGe; and two new structures, which are intergrowths of the YPtAs-type EuGaGe and EuGe 2 , for Ge-rich compositions. These two Ge-rich phases include: (1) Eu(Ga 0.45(2) Ge 0.55(2) ) 2 containing two YPtAs-type motifs of EuGaGe plus one EuGe 2 motif; and (2) Eu(Ga 0.40(2) Ge 0.60(2) ) 2 containing one YPtAs-type motif alternating with a split site at x=2/3 ,y=1/3 and z=0.4798(2) with ca. 50% site occupancy by Ga and Ge along the c-axis. Magnetic susceptibilities of three Eu(Ga 1-x Ge x ) 2 compounds display Curie-Weiss behavior above ca. 100 K, and show effective magnetic moments indicative of divalent Eu with a 4f 7 electronic configuration, consistent with. X-ray absorption spectra (XAS). Density of states (DOS) and crystal orbital Hamilton population (COHP) analyses, based on first

EU Climate Change Exhibition Held

Institute of Scientific and Technical Information of China (English)

2008-01-01

<正>On April 25, the CPAFFC, the China-EU Association (CEUA) and the Delegation of the European Commission to China jointly held the opening ceremony for the EU Exhibition on Climate Change in the CPAFFC. He Luli, former vice chairperson of the NPC Standing Committee and honorary president of the CEUA, Jose Manuel Barroso, president of the European Commission, and Li Jianping, vice president of the CPAFFC, attended the opening ceremony and made speeches. Honorary President He Luli highly praised the achievements made by China and the EU in their longtime cooperation of mutual benefits in various fields including environmental protection. She said, for many years China and EU have both committed to the development of all-round strategic partnership and establishment of a multi-level mechanism of political dialogue. She expressed, with increasing enthusiasm the CEUA would continue to actively carry out nongovernmental exchanges between China and the EU, and promote cooperation between the two sides in the fields of economy, society, environmental protection, science and technology, culture, etc.

Den brede, folkelige debat om EU

DEFF Research Database (Denmark)

Dosenrode, Søren

2005-01-01

I Danmark er EUropa noget fjernt på trods af, at EU er rammen om dansk politik, både udenrigs og indenrigs. Danmark er medlem af en de facto føderation, men de brede folkelige debater om hvordan EU skal gestaltes har manglet.......I Danmark er EUropa noget fjernt på trods af, at EU er rammen om dansk politik, både udenrigs og indenrigs. Danmark er medlem af en de facto føderation, men de brede folkelige debater om hvordan EU skal gestaltes har manglet....

Radioactivity distribution of the fruit trees ascribable to radioactive fall out. A study on stone fruits cultivated in low level radioactivity region

International Nuclear Information System (INIS)

Takata, Daisuke; Yasunaga, Eriko; Nakanishi, Tomoko M.; Sasaki, Haruto; Oshita, Seiichi; Tanoi, Keitaro

2012-01-01

After the accident of Fukushima Daiichi Nuclear Power Plant, radioactivity of fruit trees grown at an experimental farm of Nishi-Tokyo City in Tokyo, which was located about 230 km away from the power plant, was measured. Each organ of Japanese apricot and peach trees was taken at harvesting stage, respectively, and the radioactivity of 134 Cs and 137 Cs was measured. Although radioactivity of orchard soil and tree each organ were low generally, that of bark sampled from 3-old-year branch was as high as 1570 Bq/kg-dry weight. The total radioactivity of 134 Cs and 137 Cs in edible portion was far lower than that of the regulation level. (author)

Measuring health literacy among low literate people: an exploratory feasibility study with the HLS-EU questionnaire

Directory of Open Access Journals (Sweden)

Hannelore Storms

2017-05-01

Full Text Available Abstract Background Health literacy (HL is defined as necessary competencies to make well-informed decisions. As patients’ decision making is a key element of patient-centered health care, insight in patients’ HL might help healthcare professionals to organize their care accordingly. This is particularly true for people in a vulnerable situation, potentially with limited HL, who are, for instance, at greater risk of having limited access to care [1, 2]. As HL correlates with education, instruments should allow inclusion of low literate people. To that end, the relatively new instrument, HLS-EU-Q47, was subjected to a comprehensibility test, its shorter version, HLS-EU-Q16, was not. Therefore, the goal of this study was to examine feasibility of HLS-EU-Q16 (in Dutch for use in a population of people with low literacy. Methods Purposive sampling of adults with low (yearly income (< €16,965.47 and limited education (maximum high school, with Dutch language proficiency. Exclusion criteria were: psychiatric, neurodegenerative diseases or impairments. To determine suitability (length, comprehension and layout participants were randomly distributed either HLS-EU-Q16 or a modified version and were interviewed directly afterwards by one researcher. To determine feasibility a qualitative approach was chosen: cognitive interviews were carried out using the verbal probing technique. Results Thirteen participants completed HLS-EU-Q16 (n = 7 or the modified version (n = 6. Questions about ‘disease prevention’ or ‘appraisal’ of information are frequently reported to be incomprehensible. Difficulties are attributed to vocabulary, sentence structure and the decision process (abstraction, distinguishing ‘appraising’ from ‘applying’ information, indecisive on the appropriate response. Conclusions HLS-EU-Q16 is a suitable instrument to determine HL in people with limited literacy. However, to facilitate the use and interpretation, some

Radioactivity of uranium production cycle facilities in the Czech Republic compared to the natural environment

International Nuclear Information System (INIS)

Matolin, M.

2002-01-01

Forty-five years (1946-1990) of intensive uranium exploration and exploitation in the Czech Republic led to mining at 64 uranium deposits. These mining and milling activities left numerous accumulations of waste rock material in the landscape. The radioactivity of these man-made accumulations was measured and compared to the natural radiation environment. Waste rock dumps at the uranium deposits Pribram, Rozna, Jachymov, Straz-Hamr and deposits in the Zelezne Hory area show surface gamma dose rates mostly in the range of 200-1000 nGy/h, with a uranium concentration 10-100 ppm eU. An extremely high radioactivity of 3000-4200 nGy/h was detected at the extensive uranium processing tailings impoundments at Straz. Terrestrial gamma dose rate of regional geological units in the Czech Republic is in the range of 6-245 nGy/h. Reclamation and recultivation of dumps, control of their radioactivity and restriction of their accessibility are the major measures introduced to protect the public. (author)

Tendances Carbone no. 101. Will anybody dare resuscitating the EU ETS?

International Nuclear Information System (INIS)

Schleicher, Stefan

2015-04-01

Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. Beside some statistical figures about energy production/consumption and carbon markets, this issue specifically addresses the following points: - EU ETS - MSR timetable: The first Trilogue meeting between EU institutions took place on 30 March. The second is scheduled on 5 May. The Committee of Permanent Representatives of the Member States approved an implementation of the MSR in 2021. - EU's INDC: On 6 March, the EU Environment Council approved the EU's intended nationally determined contribution to achieve at least 40% domestic reduction in GHG emissions by 2030 compared to 1990 levels. - Consultations: On 26 March, the EU Commission launched two parallel consultations running until 18 June on the development of 2030 climate and energy policies in the sectors not covered by the EU ETS

Negative pressure driven valence instability of Eu in cubic Eu{sub 0.4}La{sub 0.6}Pd{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Pandey, Abhishek [S N Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata-700098 (India); Mazumdar, Chandan; Ranganathan, R [Experimental Condensed Matter Physics Division, Saha Institute of Nuclear Physics, 1/AF, Bidhannagar, Kolkata-700064 (India)], E-mail: abhishek.phy@gmail.com, E-mail: chandan.mazumar@saha.ac.in

2009-05-27

We report the change in the valency of Eu-ions in the binary intermetallic cubic compound EuPd{sub 3} induced by La doping at rare-earth sites. Doping of La generates negative chemical pressure in the lattice, resulting in a significant increase of the lattice parameter without altering the simple-cubic structure of the compound. Results of dc-magnetic measurements suggest that this increase in the lattice parameter is associated with the valence transition of Eu-ions from Eu{sup 3+} to a mixed-valent state. As Eu{sup 2+}-ions possess a large magnetic moment, this valence transition significantly modifies the magnetic behavior of the compound. In contrast to introducing boron at the vacant body center site of the unit cell to change the valency of Eu-ions, as in the case of EuPd{sub 3}B, our results suggest it can also be altered by doping a rare-earth ion of larger size at the lattice site of Eu in EuPd{sub 3}.

The IAEA and Control of Radioactive Sources

International Nuclear Information System (INIS)

Dodd, B.

2004-01-01

, recovering and disposal of orphan or vulnerable sources. Future problems should be prevented by legal and regulatory infrastructure, code of conduct, strengthening or regaining control with a national strategy, increasing security of sources and legal and regulatory controls. The code of conduct on safety and security of radioactive sources is a high level document to governments and regulatory authorities to serve as 'guidance for the development and harmonization of policies, laws and regulations on the safety and security of radioactive sources'; over 60 countries, G8 and EU have endorsed the Code. Its objective is to achieve and maintain a high level of safety and security of radioactive sources and to prevent the malicious use of radioactive sources to cause harm to individuals, society or the environment through the development, harmonization and enforcement of national policies, laws and regulations, and through the fostering of international co-operation. The Code focuses on sealed, high-risk radioactive sources, defined in the IAEA Categorization of Radioactive Sources, TECDOC-1344; it excludes nuclear materials, as defined in the Convention on Physical Protection of Nuclear Materials and excludes radioactive sources within the military or defence programs. The TECDOC 1388 helps strengthening control over radioactive sources in authorized use and regaining control over orphan sources. The IAEA has developed interim guidance on source security, TECDOC-1355, which provides methodologies and includes measures to deter, detect and delay theft

Photoluminescent and Thermoluminescent Studies of Dy3+ and Eu3+ Doped Y2O3 Phosphors.

Science.gov (United States)

Verma, Tarkeshwari; Agrawal, Sadhana

2018-01-01

Eu 3+ doped and Dy 3+ codoped yttrium oxide (Y 2 O 3 ) phosphors have been prepared using solid-state reaction technique (SSR). The prepared phosphors were characterized by X-ray diffractometer (XRD), energy dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM) and Fourier transforms infrared spectroscopy (FTIR) techniques. Photoluminescence (PL) and Thermoluminescence (TL) properties were studied in detail. PL emission spectra were recorded for prepared phosphors under excitation wavelength 254 nm, which show a high intense peak at 613 nm for Y 2 O 3 :Dy 3+ , Eu 3+ (1:1.5 mol %) phosphor. The correlated color temperature (CCT) and CIE analysis have been performed for the synthesized phosphors. TL glow curves were recorded for Eu 3+ doped and Dy 3+ codoped phosphors to study the heating rate effect and dose response. The kinetic parameters were calculated using peak shape method for UV and γ exposures through computerized glow curve deconvolution (CGCD) technique. The phosphors show second order kinetics and activation energies varying from 5.823 × 10 - 1 to 18.608 × 10 - 1  eV.

Self-aggregation of magnetic semiconductor EuS nanocrystals

International Nuclear Information System (INIS)

Tanaka, Atsushi; Hasegawa, Yasuchika; Kamikubo, Hironari; Kataoka, Mikio; Kawai, Tsuyoshi

2009-01-01

Controlled formation of aggregates having organized structure of cube-shaped EuS nanocrystals is reported. The EuS aggregates in liquid media (methanol) were obtained by means of van der Waals interaction between EuS nanocrystals. The packing structure of the EuS aggregates is characterized with transmission electron microscopy (TEM) and small angle X-ray scattering measurements (SAXS). TEM image indicates the EuS nanocrystals form self-aggregated 2D orthogonal lattice structure. The diffraction peak of (111) of SAXS profile shows that the cube-shaped EuS form 3D cubic superlattice. We successfully demonstrated that the aggregates of cube-shaped EuS nanocrystals formed cubic stacking structure.

Study on patient-induced radioactivity during proton treatment in hengjian proton medical facility

International Nuclear Information System (INIS)

Wu, Qingbiao; Wang, Qingbin; Liang, Tianjiao; Zhang, Gang; Ma, Yinglin; Chen, Yu; Ye, Rong; Liu, Qiongyao; Wang, Yufei; Wang, Huaibao

2016-01-01

At present, increasingly more proton medical facilities have been established globally for better curative effect and less side effect in tumor treatment. Compared with electron and photon, proton delivers more energy and dose at its end of range (Bragg peak), and has less lateral scattering for its much larger mass. However, proton is much easier to produce neutron and induced radioactivity, which makes radiation protection for proton accelerators more difficult than for electron accelerators. This study focuses on the problem of patient-induced radioactivity during proton treatment, which has been ignored for years. However, we confirmed it is a vital factor for radiation protection to both patient escort and positioning technician, by FLUKA’s simulation and activation formula calculation of Hengjian Proton Medical Facility (HJPMF), whose energy ranges from 130 to 230 MeV. Furthermore, new formulas for calculating the activity buildup process of periodic irradiation were derived and used to study the relationship between saturation degree and half-life of nuclides. Finally, suggestions are put forward to lessen the radiation hazard from patient-induced radioactivity. - Highlights: • A detailed study on patient-induced radioactivity was conducted by adopting Monte Carlo code FLUKA and activation formula. • New formulas for calculating the activity build-up process of periodic irradiation were derived and extensively studied. • Patient induced radioactivity, which has been ignored for years, is confirmed as a vital factor for radiation protection. • The induced radioactivity from single short-time treatment and long-time running (saturation) were studied and compared. • Some suggestions on how to reduce the hazard of patient’s induced radioactivity were given.

Intended long term performances of cementitious engineered barriers for future storage and disposal facilities for radioactive wastes in Romania

Directory of Open Access Journals (Sweden)

Sociu F.

2013-07-01

Full Text Available Considering the EU statements, Romania is engaged to endorse in the near future the IAEA relevant publications on geological repository (CNCANa, to update the Medium and Long Term National Strategy for Safe Management of Radioactive Waste and to approve the Road Map for Geological Repository Development. Currently, for example, spent fuel is wet stored for 6 years and after this period it is transported to dry storage in MACSTOR-200 (a concrete monolithic module where it is intended to remain at least 50 years. The present situation for radioactive waste management in Romania is reviewed in the present paper. Focus will be done on existent disposal facilities but, also, on future facilities planned for storage / disposal of radioactive wastes. Considering specific data for Romanian radioactive waste inventory, authors are reviewing the advance in the radioactive waste management in Romania considering its particularities. The team tries to highlight the expected limitations and unknown data related with cementitious engineered barriers that has to be faced in the near future incase of interim storage or for the upcoming long periods of disposal.

A study of the local structure around Eu3+ ions in oxide glasses using Moessbauer spectroscopy

International Nuclear Information System (INIS)

Todoroki, S.; Hirao, K.; Soga, N.

1993-01-01

The local structure around Eu 3+ ions in several oxide glasses (silicate, germanate and borophosphate glasses) was investigated by using 151 Eu Moessbauer spectroscopy. It was found that the isomer shift (IS) of silicate and borophosphate glasses was independent of the sodium content, but that of germanate glasses was not. This means the first coordination sphere around Eu 3+ ions in silicate glasses is insensitive to the composition of the glass matrix. It is assumed that, regardless of the sodium content, Eu 3+ ions in silicate glasses attract a certain amount of nonbridging oxygen (NBO, Si-O direct difference ) when incorporated stably into silicate glass matrix, because NBO is the only species donating negative charge. For germanate glasses, the behavior of IS is considered to be related to the resence of GeO 6/2 octahedra. On the basis of experimental results, the coordination models of Eu 3+ in these systems are proposed. (orig.)

Mechano-luminescence studies of nano ZnMgAl10O17:Eu phosphor under UV irradiation

Science.gov (United States)

Verma, Akshkumar; Verma, Ashish; Panda, Maheswar

2018-05-01

ZnMgAl10O17:Eu nano phosphors were prepared successfully, using the combustion route by employing urea as a fuel. The structural, and Morphological, properties were measured using x-ray diffraction (XRD) Scanning electron microscopy (SEM) transition electron microscopy. The BET surface area of sample were found to be of ˜13.92 m2/g. The ML (Mechano-luminescence) were measured to the home made instrument. The phosphor showed more strong and high ML intensity to the without UV irradiated material. Therefore ZnMgAl10O17:Eu2+ phosphor may use as a damage sensor and dosimetry material. The ML emission spectra of the Zn0.99MgAl10O17:Eu0.01 phosphor showed the characteristic Eu2+ emission peaks ˜453nm (blue) originating from the transitions 4f65d1→4f7, Therefore ZnMgAl10O17:Eu2+ phosphor may use as a blue phosphor material.

Plastic scintillators with {beta}-diketone Eu complexes for high ionizing radiation detection

Energy Technology Data Exchange (ETDEWEB)

Adadurov, A.F., E-mail: adadurov@isma.kharkov.ua [Institute for Scintillating Materials, NAN of Ukraine, Lenin Avenue 60, 61001 Kharkov (Ukraine); Zhmurin, P.N.; Lebedev, V.N.; Kovalenko, V.N. [Institute for Scintillating Materials, NAN of Ukraine, Lenin Avenue 60, 61001 Kharkov (Ukraine)

2011-10-15

Luminescent and scintillation properties of polystyrene-based plastic scintillators with {beta}-diketone Eu complexes are investigated. A scintillator with dibenzoylmethane Eu complex containing two phenyl groups demonstrates the maximum scintillating efficiency. It is shown that plastic scintillators efficiency is dramatically decreased if {beta}-diketone derivatives contain no phenyl groups as substituents. This fact can be explained by exciplex mechanism of energy transfer from a matrix to Eu complex. - Highlights: > Fluorescent properties of polystyrene scintillators with {beta}-diketone complexes of Eu were studied. > Scintillating efficiency is increased with the number of phenyl groups in Eu complex. > This is related to exciplex mechanism of energy transfer from a polymer matrix to Eu complex.

COMPARATIVE STUDY ON INDIRECT TAXES AT EU LEVEL

Directory of Open Access Journals (Sweden)

HARALAMBIE GEORGE ALIN

2015-06-01

Full Text Available The economic downturn, affecting lately the states all over the world, imposed their governments to take measures in fiscal and budget plan in order to reduce the budget deficit, by reducing spending and increasing the revenue mobilized to the budget, especially tax revenues, by increasing the tax burden both for the individuals and legal entities. Reforming the tax system at European level involved widening the tax base both for the income earned by individual taxpayers and those made by companies to the detriment of effective tax rates increase. The share in GDP of mandatory levies is uneven across the EU. In the year 2012, it range from 30% in Lithuania with 50% to Denmark. Fiscal consolidation in the member states aimed reforms in the field of indirect taxation (by increasing VAT- 1% for the Czech Republic, Slovakia, Italy, Poland and Finland to 7% in Hungary with 5%, Romania, 4%, excise duties and environmental taxes and a downward trend in the rate of taxation in the case of direct taxes through progressive taxation of personal income, which led to increased revenue due compulsory levies in most countries of the European Union. 13 EU countries have acted to increase the VAT rate between 2010-2014.

Radioactive waste containment - a literature study

International Nuclear Information System (INIS)

Mohiuddin, G.

1985-01-01

One of the basic requirements of safe radioactive waste disposal is isolation of the radioactive substances to prevent leakage into the biosphere. The multi-barrier concept has been developed to meet this requirement. Within the framework of the concept, barriers can be either natural or man-made. Natural barriers, i.e. geologic formations,have been investigated for their suitability, with host rock and their different properties being determined and compared. It has been found that the qualification of a proposed repository medium cannot be defined on the basis of physical, chemical, and mineralogical criteria alone, but that these data have to be completed by a global evaluation of the entire system consisting of waste products and waste forms, host rock, and surrounding rock. The study in hand reviews the reports and also lists the studies made on engineered barriers, as e.g. immobilisation barriers, container and package barriers, of various waste forms. A review of the studies dealing with the various waste disposal techniques shows that the sub-surface waste disposal and the deep underground disposal in mines are the best developed techniques currently. A review of ultimate disposal concepts adopted abroad shows that most countries favour the mining technology approach, with the exception of Denmark where R and D work in this field is focused on deep well disposal. (orig./HP) [de

Composition dependence of the optical and structural properties of Eu-doped oxyfluoride glasses

International Nuclear Information System (INIS)

Zhu, Chaofeng; Wu, Dongqun; Zhang, Yanfei; Zhang, Meimei; Yue, Yuanzheng

2015-01-01

Highlights: • Eu doped oxyfluoride glasses for LED applications are studied. • Conversion of Eu 3+ to Eu 2+ is realized in the glasses prepared in air atmosphere. • CaF 2 crystals formed during melt cooling enhance the conversion of Eu 3+ to Eu 2+ . • Content of CaF 2 crystals can be controlled by adjusting base glass compositions. - Abstract: Europium doped oxyfluoride glasses were prepared by the melt quenching method for the light emitting diodes applications. The optical and structural properties of these glasses were studied by means of photoluminescence spectra, Commission Internationale de L’Eclairage chromaticity coordinates, X-ray diffraction, and Fourier transform infrared spectra. We find that the spontaneous reduction of Eu 3+ to Eu 2+ is realized by Eu 3+ ions occupying the sites of Ca 2+ in the glasses prepared in air atmosphere. The Eu 3+ to Eu 2+ conversion efficiency, optical performances and structure of the glasses strongly depend on the base glass compositions. For certain base glass compositions, CaF 2 crystals can form during the melt cooling process, and thereby enhance the conversion from Eu 3+ to Eu 2+ . The formation of CaF 2 crystals can be suppressed by adding CaO, Al 2 O 3 and B 2 O 3 , but enhanced by adding Na 2 O and K 2 O in glass compositions. Finally, we propose a mechanism to explain how the glass structure affects the reduction of Eu ions as well as optical properties of the glasses

Moessbauer spectroscopy of 151Eu and 153Eu. Applications to structural chemistry and electronic properties of rare-earth compounds

International Nuclear Information System (INIS)

Meyer, Marc.

1975-01-01

The decrease of the 151 Eu isomer shift on hydrogenation of a dilute EuPd alloy (2.5at% Eu) is discussed in term of the volume effect on the charge density at the nucleus. It is shown from 153 Eu Moessbauer spectroscopy in rare earth titanates that a vibrational anisotropy lead to the observation of a Goldanskii-Karyagin effect [fr

NMR study of magnetic properties in filled skutterudite compound EuRu4P12

International Nuclear Information System (INIS)

Magishi, Ko-ichi; Iwahashi, Yoshinori; Horimoto, Takuji; Sugawara, Hitoshi; Saito, Takahito; Koyama, Kuniyuki

2007-01-01

We report the results of 31 P NMR measurements on a Eu-based filled skutterudite phosphide EuRu 4 P 12 with ferromagnetic transition at T C =18K in order to investigate the magnetic properties from a microscopic point of view. The temperature dependence of the Knight shift is similar to that of the magnetic susceptibility. Also, the nuclear spin-lattice relaxation rate 1/T 1 is practically constant at higher temperatures above 50K due to the interaction of the 31 P nucleus with fluctuating local moments at the Eu 2+ sites, but decreases rapidly at low temperatures below T C , indicating the supression of the spin fluctuations by magnetic ordering

Thermal expansion studies on europium titanate (Eu2TiO5)

International Nuclear Information System (INIS)

Panneerselvam, G.; Subramanian, G.G.S.; Antony, M.P.

2008-01-01

The lattice thermal expansion characteristics of europium titanate (Eu 2 TiO 5 ) have been studied by measuring the lattice parameter by high temperature X-ray diffraction technique (HT-XRD) in the temperature range 298-1573K. Percentage linear thermal expansion and mean linear thermal expansion coefficients were computed from the lattice parameter data. The percentage linear thermal expansion in the temperature range 298-1573 K along a, b and c axes are 1.05, 1.15 and 0.95 respectively. (author)

EU ligger i Danmark!

DEFF Research Database (Denmark)

Adler-Nissen, Rebecca

2007-01-01

EU må ikke reduceres til et spørgsmål om folkeafstemninger. Den virkelige udfordring handler om, hvordan EU-beslutninger om alt fra dyretransporter til terrorbekæmpelse kan kontrolleres på en demokratisk måde. De beslutninger, der bliver truffet i Bruxelles er i højeste grad en del af den nationa...

Development of the EU Ecolabel Criteria and Revision of the EU Green Public Procurement Criteria for Cleaning Services

OpenAIRE

DE ALMEIDA FERREIRA NETO BELMIRA; WOLF Oliver; FIELD Bethany; JENKIN Nicola; TAM Max; BENJAMIN Oscar

2016-01-01

The objective of this project is to develop a new EU Ecolabel and revise the existing EU Green Public Procurement (GPP) criteria for professional cleaning services (hereafter referred to as cleaning services). This preliminary report investigates the market, operational and sustainability aspects of cleaning services, with a goal to develop a robust evidence base and prioritise key environmental and social issues to support the development of EU Ecolabel criteria and the revision of the EU GP...

EU agricultural domestic support in GTAP

DEFF Research Database (Denmark)

Boulanger, Pierre; Philippidis, George; Jensen, Hans Grinsted

The engagement of JRC IPTS in the GTAP contributing team to the EU domestic support has opened up the opportunity to use the CATS database when compiling EU domestic support payments by member state, which are subsequently calibrated into the GTAP database. To maintain consistency, the GTAP version...... 9 includes EU domestic support which follows the approach adopted in the previous releases (Jensen, 2009, 2010). The difference is for pillar 1 support for which the CATS data are used (in previous GTAP database releases, pillar 1 support was based on EAGF financial reports). All together EU...

Natural atmospheric radioactivity

International Nuclear Information System (INIS)

Renoux, A.

1986-01-01

After having summed up the different old or new units, used in radioactivity and radioprotection, the origins of atmospheric radioactivity are reported. Next the authors deal with the air content in radon, thoron and their radioactive descendants, insisting on the variations of the radon air content and on the radioactive balance between radon and its descendants. Then a few notions concerning the natural radioactive aerosol are developed: electric charge state, granulometric distribution. The possible effects of natural atmospheric radioactivity on man are studied with a distinction between inner irradiation and outer irradiation, an average assessment is shown. Finally the important problem of radon in inhabitations is approached [fr

The expanding EU

DEFF Research Database (Denmark)

Zank, Wolfgang

In this paper I try to explore whether the EU can go on expanding and thereby become culturally ever more diversified, and at the same retain its stability. The answer is, in principle, affirmative. Europe has always been much diversified, and therefore it is not possible to define a European...... identity in terms of particular cultural traditions. However, in spite of their diversity, the EU-member countries are united by their adherence to the principles of democracy, rule by law and human rights. Countries which do not share this basic consensus would not be accepted as members, nor is it likely...... that they would apply for it. An essential part is the willingness of member states to accept a reduction of national sovereignty on some important policy fields. The EU project is basically about lifting the principles of democracy and rule by law on the international level, most and foremost among the member...

Temperature-induced valence transition in EuNi2(Si0.20Ge0.80)2 studied by hard X-ray photoemission spectroscopy

International Nuclear Information System (INIS)

Yamamoto, Kazuya; Kamakura, Nozomu; Taguchi, Munetaka; Chainani, Ashish; Takata, Yasutaka; Horiba, Koji; Shin, Shik; Ikenaga, Eiji; Mimura, Kojiro; Shiga, Masayuki; Wada, Hirofumi; Namatame, Hirofumi; Taniguchi, Masaki; Awaji, Mitsuhiro; Takeuchi, Akihisa; Nishino, Yoshinori; Miwa, Daigo; Tamasaku, Kenji; Ishikawa, Tetsuya; Kobayashi, Keisuke

2005-01-01

The temperature-induced mixed valence transition in EuNi 2 (Si 0.20 Ge 0.80 ) 2 has been investigated by hard X-ray (5940 eV) photoemission spectroscopy (HX-PES) for fractured surfaces, with a probing depth larger than 5 nm. The Eu 3d core-level states are studied below and above the critical valence transition temperature, T v = 80 K. The HX-PES spectra at 40 and 120 K show the mixed valence transition, with clear changes in the divalent and trivalent Eu 3d chemically shifted features. The Eu 3d HX-PES spectra indicate a mean valence of 2.70 ± 0.03 at 40 K which changes to 2.40 ± 0.03 at 120 K, in good accordance with the results of bulk Eu III -edge X-ray absorption spectroscopy measurements

THE ROMANIAN ASPECT OF THE E.U. GOVERNANCE CASE STUDIES: EDUCATUION POLICY AND ENVIRONMENTAL POLICY

Directory of Open Access Journals (Sweden)

OANA-ANDREEA ION

2011-04-01

Full Text Available This paper belongs to the domestic studies which try to connect the Romanian research to the current debates within the EU studies. The authors' aim is to analyze the aspects and the implications of the EU governance at the Member States' domestic policies level, as most of these policies are currently facing the challenges brought by the Europeanization process. Therefore, the theoretical framework selected is the theory of governance, focusing on the explanatory and analytical opportunities of two components – multi-level governance and governance networks; in this way, it is underlined the separation from the classic model of relation between the (multiplied levels of political authority (supranational, national, subnational and the exponential increase in the number and types of actors participating at the decisional process and implementation of European public policy. Within the selected case studies (environmental policy and education policy, the authors advance a research structure with the aims (a to identify the relevant actors involved in the policy-making process of these policies, at all stages of its cycle; (b to offer an explanation of the types of interactions between these actors, and (c to identify the influence these interactions exert on the communitarization pronounced tendency of some EU policy sectors. The analysis is performed in terms of the Treaty of Lisbon (the selected policies being part of distinct categories of the Union competences and it is oriented towards the national level of the making process of these policies.

Gender Perspective on Access to Energy in the EU

NARCIS (Netherlands)

Clancy, Joy S.; Daskalova, Victoria Ivanova; Feenstra, Mariëlle Henriëtte; Franceschelli, Nicolo

2017-01-01

This study, commissioned by the European Parliament Policy Department for Citizens' Rights and Constitutional Affairs, presents an overview of the situation within the EU with regard to the way energy poverty is experienced by women and men and explores through a gender lens existing EU legislation

Assessing gas transit risks: Russia vs. the EU

International Nuclear Information System (INIS)

Le Coq, Chloé; Paltseva, Elena

2012-01-01

This paper proposes a Transit Risk Index (TRI) designed to assess the riskiness of pipeline gas imports and to study the effect of introducing new gas routes. TRI controls for gas dependency, transit route diversification, political risks of transit, pipeline rupture probability, and the balance of power between supplying and consuming countries along the transit route. Evaluating TRI for the EU-Russia gas trade, we show that the introduction of the Nord Stream pipeline would further widen already large disparities in gas risk exposure across the EU Member States. The gas risk exposure of the Member States served by Nord Stream would decline. In contrast, EU countries not connected to Nord Stream, but sharing other Russian gas transit routes with the Nord Stream countries, would face greater gas risk exposure. We discuss the implications of our analysis for the design of the common energy policy in the EU.

Environmental control policy change in the EU between ideas and reality; Umweltpolitischer Steuerungswechsel in der EU zwischen Ideen und Realitaet

Energy Technology Data Exchange (ETDEWEB)

Heumader, Katja

2014-07-01

The study on the environmental policy change in the EU covers the following issues: theoretical frame work: the scientific policy debate on political control and governance; boom of ideas: development in the discussion on European environmental policy; discrepancies: the change of political control between intention and realization; case studies: EU policy concerning the enhancement of energy efficiency, the groundwater guideline, waste policy and waste stream priorities, the European emission trading system, access to jurisdiction for environmental issues, the soil protection guideline.

Tb3+ and Eu3+ luminescence in imidazolium ionic liquids

International Nuclear Information System (INIS)

Hopkins, Todd; Goldey, Matt

2009-01-01

The luminescence properties of Tb 3+ and Eu 3+ dissolved in ionic liquids are studied. Solutes in this study include simple lanthanide compounds (e.g., EuBr 3 , TbCl 3 ) and lanthanide complexes (e.g., Eu(dpa) 3 3- where dpa = 2,6 pyridine dicarboxylate dianion) dissolved in a 1-butyl-3-methylimidazolium bromide(BMIBr)/water mixture. Emission, excitation, and time-resolved emission measurements are utilized to characterize the spectroscopic properties. It is well established in the literature that the solubility and spectroscopic properties of lanthanides in ionic liquids are highly dependent upon environmental factors including purity, and water content [K. Binnemans, Chemical Reviews (2007); I. Billard, S. Mekki, C. Gaillard, P. Hesemann, C. Mariet, G. Moutiers, A. Labet, J.-C.G. Buenzli, European Journal of Inorganic Chemistry 6 (2004) 1190-1197; S. Samikkanu, K. Mellem, M. Berry, P.S. May, Inorganic Chemistry 46 (2007) 7121-7128]. The water in this ionic liquid system acts as a co-solvent to facilitate solubility of Tb 3+ and Eu 3+ compounds. The observed spectroscopic properties of Eu 3+ and Tb 3+ salts are expectedly impacted by the high water content, but unexpectedly impacted by the BMIBr ionic liquid. However, the spectroscopy of Eu(dpa) 3 3- is unaffected by the presence of BMIBr.

Structural and spectroscopic diagnosis of Eu:ZnO and Eu:Yb:ZnO glass and ceramics.

Science.gov (United States)

Bahadur, A; Dwivedi, Y; Rai, S B

2012-06-01

Eu and Eu:Yb codoped ZnO nanocrystals embedded in B(2)O(3) glass matrix were synthesized and their structural, optical properties were discussed. On excitation with 532 nm laser radiation intense orange/red emissions from Eu(3+) ions were observed. The fluorescence intensity was found to enhance on annealing. Frequency upconversion emissions from Eu(3+) ions were observed in presence of Yb(3+) ions on excitation with NIR (976 nm) laser. The enhancement in emission intensity was explained and the photo-physics involved is linked with the unique structural properties of the crystallites formed. Ion interactions and the different energy transfer parameters were also calculated. Copyright © 2012 Elsevier B.V. All rights reserved.

Plastic scintillators with β-diketone Eu complexes for high ionizing radiation detection

International Nuclear Information System (INIS)

Adadurov, A.F.; Zhmurin, P.N.; Lebedev, V.N.; Kovalenko, V.N.

2011-01-01

Luminescent and scintillation properties of polystyrene-based plastic scintillators with β-diketone Eu complexes are investigated. A scintillator with dibenzoylmethane Eu complex containing two phenyl groups demonstrates the maximum scintillating efficiency. It is shown that plastic scintillators efficiency is dramatically decreased if β-diketone derivatives contain no phenyl groups as substituents. This fact can be explained by exciplex mechanism of energy transfer from a matrix to Eu complex. - Highlights: → Fluorescent properties of polystyrene scintillators with β-diketone complexes of Eu were studied. → Scintillating efficiency is increased with the number of phenyl groups in Eu complex. → This is related to exciplex mechanism of energy transfer from a polymer matrix to Eu complex.

Cross-Border Assessment of Environmental Radioactivity in the Euro-Arctic Region

Energy Technology Data Exchange (ETDEWEB)

Nalbandyan, Anna; Gwynn, Justin P.; Moeller, Bredo [Norwegian Radiation Protection Authority (NRPA), Section High North, 9296 Tromsoe (Norway); Leppaenen, Ari-Pekka; Rasilainen, Tiina [STUK Radiation and Nuclear Safety Authority, Regional Laboratory in Northern Finland, 96400 Rovaniemi (Finland); Kasatkina, Nadezhda; Usiagina, Irina [Murmansk Marine Biological Institute (MMBI), 183010 Murmansk (Russian Federation)

2014-07-01

The Euro-Arctic region is currently experiencing rapid changes in environmental, social and economic conditions. The issue of environmental radioactivity is of special concern to the Arctic region due to numerous existing and potential sources of radioactive pollution in the immediate and adjacent areas. Due to cross-border nature of any potential radioactive contamination and common challenges in border countries, one should consider risks related to radioactivity, monitoring and protection at a regional and international level. This research presents results of cross-border cooperation between Norway, Finland and Russia and joint assessment of the status of terrestrial radioactivity in the Euro-Arctic region and in particular across Troms and Finnmark (Norway), Lapland (Finland) and Murmansk Oblast (Russia). To assess current environmental radioactivity levels in the terrestrial environment, environmental samples were collected in each country in 2010-2012. The main focus was comparison of radioactivity levels in the natural food products such as berries, mushrooms and freshwater fish. The results showed that large variations in activity concentrations exist between species and sampling areas. However, activity concentrations of {sup 137}Cs in all berries and mushrooms in Northern Norway, Finland and Russia were below the national limits set for commercial retail and well below the national limits for freshwater fish from Northern Norway and Finland. The sampled species from three countries were analysed in order to find out reference species available for further monitoring and data comparison. The doses to man arising from consumption of berries, mushrooms and freshwater fish were calculated. To compare overall terrestrial radioactivity levels in the Euro-Arctic region, partners exchanged long-term monitoring data available in the three countries such as data for soil, vegetation, berries, mushrooms, lichens, reindeer meat, freshwater fish, whole body counting

Gender Influence on Part-time Working: An Empirical Study Upon the EU and Turkey

Directory of Open Access Journals (Sweden)

Aslı Beyhan Acar

2014-04-01

Full Text Available In this empirical study, it’s investigated differences of part-time working rates between men and women in the period of 2000-2012. 17 members of the EU and Turkey -as a candidate country- are participated in the study. Turkey is participated into the study too, because Turkey must adapt the most of the regulations of EU as a candidate member of the Union. The data are collected from OECD and World Bank statistics web site. Beyond that many database indicate part-time employment rates for both common and national definition of part-time working for statistical purpose. According to this it’s aimed to determine whether there is a significant difference between part-time working rates that are based on common and national definition. In the literature, there are some studies that investigate fertility rates and part-time employment rates of women. The correlation of these two variables that are belonged the years 2000-2012 is tested and the findings are indicated in the study. Furthermore, it’s analyzed the rate differences of part-time working for men and women in the period of 2000-2012.

Gender Influence on Part-time Working: An Empirical Study upon the EU and Turkey

Directory of Open Access Journals (Sweden)

Aslı Beyhan Acar

2016-01-01

Full Text Available In this empirical study, it’s investigated differences of part-time working rates between men and women in the period of 2000-2012. 17 members of the EU and Turkey -as a candidate country- are participated in the study. Turkey is participated into the study too, because Turkey must adapt the most of the regulations of EU as a candidate member of the Union. The data are collected from OECD and World Bank statistics web site. Beyond that many database indicate part-time employment rates for both common and national definition of part-time working for statistical purpose. According to this it’s aimed to determine whether there is a significant difference between part-time working rates that are based on common and national definition. In the literature, there are some studies that investigate fertility rates and part-time employment rates of women. The correlation of these two variables that are belonged the years 2000-2012 is tested and the findings are indicated in the study. Furthermore, it’s analyzed the rate differences of part-time working for men and women in the period of 2000-2012.

The Determinants of European Union (EU Foreign Direct Investments in the EU Countries from Central and Eastern Europe During 1994–2012

Directory of Open Access Journals (Sweden)

Tang Donny

2017-03-01

Full Text Available This study examines whether the CEECs’ financial market development can explain the EU FDI in the CEECs during 1994–2012. The higher bank credit flows had a positive effect on the FDI in 2005–2012. This can be attributed to the major banking sector reforms undertaken before the CEECs’ EU accession. Second, the stock market size had a positive effect in 1997–2004. This is due to the fact that the EU membership announcement facilitated deeper stock market integration. Third, the higher country income, in interaction with a higher bank credit flow, had only a small positive effect in 2005–2012. The higher income CEECs have pursued much deeper bank liberalization through large-scale privatization of state-owned banks. Finally, the higher country income, in interaction with a larger stock market size, had a negative effect in 2005–2012. A possible reason for this is that the EU countries have started to divert their new FDI to the non-EU countries.

Governing EU employment policy

DEFF Research Database (Denmark)

Sørensen, Eva; Triantafillou, Peter; Damgaard, Bodil

2015-01-01

In the European Union (EU), employment policy is a prerogative of the member states. Therefore the EU's ability to govern in this area depends on its capability to involve national governments and relevant stakeholders in a collaborative effort to formulate and implement shared policy objectives....... of collaboration, the implementation phase mainly consists in the less demanding forms of cooperation and coordination....

Experimental studies with radioactive ion beams

International Nuclear Information System (INIS)

Sastry, D.L.; Sree Krishna Murty, G.; Chandrasekhar Rao, M.V.S.

1991-01-01

The sources of information presented are essentially taken from the papers reported at several international seminars and those appeared in the Journal of Nuclear Instruments and Methods in Physics Research. Production and usage of radioactive ion beams (RIB) in research have received the attention of scientists all over the world during the past six years. The first radioactive ion beams ( 19 Ne) were produced at Bevalac for the purpose of medical research using a primary beam of energy 800 MeV/a.m.u. (author). 19 refs., 2 figs., 3 tabs

6. Analisis Implementasi Cyber Security Di Uni Eropa: Studi Kasus Carbon Credits Hacking Dalam European Union Emission Trading Scheme (EU ETS) Tahun 2010-2013

OpenAIRE

Aisya, Naila Sukma; Putranti, Ika Riswanti; Wahyudi, Fendy Eko

2017-01-01

Since the last two decades in the 20th century, the European Union (EU) has presented itself as a leader in climate change issues. The leadership manifested in the formation of the European Union Emission Trading Scheme (EU ETS) as an effort to fulfill the commitments of the Kyoto Protocol to reduce emissions in the region. But the existence of the EU ETS has been challenged by the emergence of carbon credits hacking case in some national registration systems in the EU ETS. This study discuss...

Disposal Options for Low and Intermediate-Level Radioactive Waste: Comparative Study

International Nuclear Information System (INIS)

Abdellatif, M.M.

2013-01-01

This study presents the status of current disposal options for Low and Intermediate- Level Radioactive Waste (LILRW) generated in different countries and outlines the potential for future disposal option/s of these wastes in Egypt. Since approaches used in other countries may provide useful lessons for managing Egyptian radioactive wastes. This study was based on data for19 countries repositories and we focused on 6 countries, which considered as leaders in the field of disposal of rad waste. Several countries have plans for repositories which are sufficiently advanced that it was based on their own of their extensive experience with nuclear power generation and with constructing and operating LLRW disposal facilities. On the other hand, our programme for site selection and host rock characterization for low and intermediate level radioactive waste disposal is under study. We are preparing our criteria for selecting a national repository for LIL rad waste.

Turkey’s Population Dynamics As A Candidate Country For EU Membership

Directory of Open Access Journals (Sweden)

Harun Uçak

2011-01-01

Full Text Available Literally, it has been accepted that one of the major obstacles to Turkey’s EU membership is in population term. There has not been any enlargement process as large as Turkey’s population as a single state in EU history before. The enlargement in 2004 which includes 10 states involved 74 million people as whole member states while Turkey’s population is 72 million inhabitants in 2007 data which is only lower than Germany’s population in all EU member states. Thus, Turkey's accession would be different from previous enlargements because of the combined impact of high population. This study compares the population dynamics, working conditions, minimum wage rates and main macroeconomic indicators between Turkey and EU member states. Turkey has young generations compared to EU countries. In the comparison of age groups proportion in total population, 0-19 age group %21,9 in EU 27 and %36,5 in Turkey, 20-39 age group is %28 in EU 27 and %34,3 in Turkey, 40-59 age group is %27,9 in EU and %20,9 in Turkey, 60 and above age group is %22,1 in EU and %9,5 in Turkey. Thus, population dynamics of Turkey could make a contribution to offsetting the ageing of EU 27 societies if the membership would occur in the future. However, minimum wage rates in Turkey are lower than many EU member states but generally higher than EU member states located in Central and Eastern Europe. Thus, immigration possibilities from Turkey can be expected to Western European Countries, but not the same direction to Central and Eastern Europe Countries. Furthermore, the process in macroeconomic indicators will be a determinant in immigration expectations while Turkey’s GDP has been grown faster than EU level recently.

Prevalence of nickel allergy in Europe following the EU Nickel Directive - a review

DEFF Research Database (Denmark)

Ahlström, Malin G; Thyssen, Jacob P; Menné, Torkil

2017-01-01

.4% versus 19.8%) (p = 0.02), in female dermatitis patients aged ≤17 years (14.3% versus 29.2%) (p women: 20.2% versus 36.6%) (p men: 4.9% versus 6.6%) (p ..., and generally remained high, affecting 8-18% of the general population. A consistent pattern of decreasing prevalence of nickel allergy in some EU countries was observed, although the prevalence among young women remains high. Steps should be taken for better prevention of nickel allergy in EU countries.......Nickel contact allergy remains a problem in EU countries, despite the EU Nickel Directive. To study the prevalence of nickel allergy in EU countries following the implementation of the EU Nickel Directive, we performed a systematic search in PubMed for studies that examined the prevalence of nickel...

Reference values on safety regulation of land disposal of low level radioactive solid waste (the second interim report) and its incorporation into legal regulations

International Nuclear Information System (INIS)

Aoki, Terumi

1994-01-01

Safety regulation of land disposal of low level radioactive solid waste in Japan is based on 'the basic philosophy on the safety regulation of land disposal of low level radioactive solid waste' determined by the Nuclear safety Committee (October 1985). The basic philosophy on the upper limit of radioactivity of disposed wastes was published as the reference values in the interim report (February 1987) and in the second interim report (June 1992). In the second interim report, the upper limits of radioactivity are established for three types of solid radioactive wastes: 1) metals, incombustible or flame resistant wastes generated nuclear reactor facilities and solidified in vessels, 2) large metallic structures generated from decommissioning of reactor facilities and difficult to solidify in vessels, and 3) radioactive concrete waste generated from decommissioning of reactor facilities. The upper limits of radioactivity are presented for C-14, Co-60, Ni-63, Sr-90, Cs-137, alfa-emmitters, Ca-41 (for concrete) and Eu-152 (for concrete). Related laws and regulations in Japan on safe disposal of low level wastes are explained. (T.H.)

Radiological safety methodology in radioactive tracer applications for hydrodynamics and environmental studies

International Nuclear Information System (INIS)

Suarez, R.; Badano, A.; Dellepere, A.; Artucio, G.; Bertolotti, A.

1995-01-01

The use of radioactive tracer techniques as control sewage disposal contamination in Montevideo Estuarine and Carrasco beach has been studied for the Nuclear Technology National Direction. Hydrodynamic models simulation has been introduced as work methodology. As well as radiological safety and radioactive material applications in the environmental studies has been evaluated mainly in the conclusions and recommendations in this report. maps

Should the EU climate policy framework be reformed?

Directory of Open Access Journals (Sweden)

David ELLISON

2011-12-01

Full Text Available Though to-date the European Union (EU has played the most significant leadership role in international negotiations to reduce greenhouse gas (GHG emissions, the emission-reducing performance of individual EU Member states has for many been less than stellar. Several EU15 Member states continue to raise rather than lower emissions. Analysing the most successful policy instruments, this paper argues EU policy efforts could benefit from three important innovations. The following strategies – the adoption of an EU-wide FIT (feed-in tariff, an EU-wide carbon tax and more flexibility in the trading of carbon credits – could significantly improve emission reductions, their relative cost-efficiency and spread burden-sharing more evenly across technologies and Member states. This raises important questions, both about the effectiveness of EU and Kyoto-style commitments, as well as the EU Emission Trading Scheme (ETS. The commitment strategy, and in particular the EU ETS mechanism, have had the smallest impact on emission reductions. The proposed set of strategies could make a far greater contribution to future EU efforts and potentially lock in the impressive progress already made. Such a policy shift, if successful, would also greatly enhance the EU’s already significant credibility and bargaining power in international climate negotiations.

Study of association of Eu(III) β-diketonato-1,10-phenanthroline complexes in silica-based hybrid materials

Energy Technology Data Exchange (ETDEWEB)

Fadieiev, Yevhen M.; Smola, Sergii S. [A.V. Bogatsky Physico-chemical Institute, National Academy of Sciences of Ukraine, 86, Lustdorfskaya doroga, 65080 Odessa (Ukraine); Malinka, Elena V. [Odessa National Academy of Food Technology, 112, Kanatna Street, 65039 Odessa (Ukraine); Rusakova, Nataliia V., E-mail: lanthachem@ukr.net [A.V. Bogatsky Physico-chemical Institute, National Academy of Sciences of Ukraine, 86, Lustdorfskaya doroga, 65080 Odessa (Ukraine)

2017-03-15

Hybrid organic-inorganic materials based on silica and mixed-ligand complexes of Eu(III) with β-diketones and 1,10-phenanthroline with covalent and non-covalent attachment to matrix were obtained by a sol-gel route. Luminescent study of obtained systems allowed to propose spectral criteria for estimation of the uniformity of complex distribution in amorphous silica matrix. Thus, such criteria are the broadening of Eu(III) 4f-luminescence bands, emission decay and the shape of plot of the emission intensity vs. concentration of complex in the materials. Full width of {sup 5}D{sub 0}→{sup 7}F{sub 2} band at its half maximum and the ratio of the {sup 5}D{sub 0}→{sup 7}F{sub 2} and {sup 5}D{sub 0}→{sup 7}F{sub 1} bands intensities were used as quantitative measures of spectral changes and the bands broadening in Eu(III) emission spectra. - Highlights: • Modification of Eu(III) β-diketonates by an anchor fragments was carried out. • The degree of association of molecules was estimated based on emission spectra. • Covalent anchoring of complexes promotes their uniform distribution in matrix. • Non-covalently grafted complexes are prone to association in amorphous silica.

Comparative analysis of Fiber-to-the-Home market liberalization in the EU

DEFF Research Database (Denmark)

Williams, Idongesit

2017-01-01

The penetration of Fiber-to-the-Home (FTTH) in the EU is low. This is because deploying FTTH is capital intensive. The liberalization of the FTTH market in three EU countries is studied in this paper. The aim is to identify the challenges that affect the growth of FTTH in the EU. This is a qualit......The penetration of Fiber-to-the-Home (FTTH) in the EU is low. This is because deploying FTTH is capital intensive. The liberalization of the FTTH market in three EU countries is studied in this paper. The aim is to identify the challenges that affect the growth of FTTH in the EU......, this paper concludes that competition at the wholesale market aspect of the FTTH market should be given more priority than competition at the retail section of the Fiber-to-the-Home market. This prioritization in regulating competition will enable greater market penetration of Fiber...

Problems and management of radioactive sources and measures against illicit trafficking of nuclear materials in Bulgaria

International Nuclear Information System (INIS)

Strezov, A.

1998-01-01

Illicit trafficking of nuclear materials continues to pose a danger to public health and safety and to nuclear non proliferation efforts. The majority of cases so far have involved only small amounts of fissile materials or mainly radioactive sources in Bulgaria. A proper scheme for analysis of seized nuclear materials will be developed based on existing equipment for NDA analysis of nuclear materials supplemented by new system through PHARE project assistance by EU experts. (author)

Laboratory experiments on materials for radioactive labelling of blast furnace hearth

International Nuclear Information System (INIS)

Staicu, L.; Lucaciu, A.; Bascoveanu, I.; Plapceanu, C.

1994-01-01

Currently, the monitoring of refractory lining wear of hearth blast furnace uses for labelling of locations inside brick-work only two radionuclides 110m Ag and 60 Co. Consequently a great zone of hearth being unlabelled escapes to monitoring, leading to possible dangerous perforations. For augmentation of labelled hearth surface we have initiated research on 133 Ba, 134 Ce, 152+154 Eu, 204 Cl, and 65 Zn. It is known that it is not recommendable to use for labelling these elements in pure state because these are very reactive i.e. they are unstable, except for thallium. Moreover, at hearth and crucible temperatures they are volatile. Therefore, a major aspect that we took into consideration is the radioisotope chemical form which is used for radioactive labelling. In Ba or Eu case, oxides can be used being more stable but in Cs and Tl case, oxides are not useful; it is more suitable to employ simple or double silicates. Samples containing a mixture of pig iron, slag and silicates of the hearth furnace labelling elements have been prepared. After separation the samples were crushed and analysed by activation analysis. The obtained gamma spectra have shown the presence of Ba, Cs, and Eu separately in the slag sample into which they have been melt. (author) 2 tabs., 8 refs

Could EU herbal monographs contribute to Malta's treatment armamentarium?

Science.gov (United States)

Micallef, B; Attard, E; Serracino-Inglott, A; Borg, J J

2015-03-15

Ten years have passed since Directive 2004/24/EC regulating herbal medicinal products across the EU were published. The directive created the Committee on Herbal Medicinal Products within the European Medicines Agency whose remit includes the creation and publishing of official EU monographs on herbal medicinal products. These monographs include the official uses of the products and their evidence for efficacy and safety. To this effect, we are interested in analysing the potential impact herbal product EU monographs could have on the therapeutic treatment options available for prescribers in Malta. Therefore our aim was two-fold. First, to rationalise the spread of indications of the herbal substances listed in the community herbal monograph inventory and subsequently determine if these herbal substances could potentially contribute to the treatment options available in our local scenario (Malta). 128 EU monographs were analysed resulting in a total of 230 indications which subsequently codified into 42 unique ATC codes. The Malta Medicines List contains 1456 unique ATC codes. Comparative analysis of the Malta Medicines List revealed that the 21 therapeutic areas had 4 or less pharmaceutically used substances (5th level ATC codes) registered and therefore in our opinion are areas with limited therapeutic choice. The following 4 therapeutic areas, A05 bile and liver therapy, A13 tonics, A15 appetite stimulants and D03 preparations for treatment of wounds and ulcers, could potentially benefit from the registration of herbal medicinal products according to the EU herbal monographs. If such registration is effected the aforementioned areas would no longer be considered limited because more than 4 therapeutic choices would be available to prescribers. This study is the first study across the EU to analyse the potential impact of published EU herbal monographs on therapeutic coverage in an EU member state and confirms the notion that herbal products could potentially

EuAuGe type indides RAgIn (R = Ca, Sr, La, Eu)

Energy Technology Data Exchange (ETDEWEB)

Stein, Sebastian; Schmolke, Kai Heinz; Block, Theresa; Heletta, Lukas; Hoffmann, Rolf-Dieter; Poettgen, Rainer [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster (Germany)

2017-08-03

The equiatomic intermetallic phases CaAgIn [a = 482.75(7), b = 750.0(1), c = 835.5(1) pm], SrAgIn [a = 495.86(5), b = 794.71(9), c = 851.89(9) pm], LaAgIn [a = 489.99(5), b = 767.93(9), c = 837.53(9) pm], and EuAgIn [a = 493.02(7), b = 781.6(1), c = 844.2(1) pm] were synthesized from the elements in sealed niobium containers. They crystallize with the EuAuGe type structure, space group Imm2. The four structures were refined from single-crystal X-ray data. The silver and indium atoms build up orthorhombically distorted, puckered Ag{sub 3}In{sub 3} hexagons, which are stacked in AA' sequence, leading to direct Ag-Ag and In-In interlayer bonding (e.g. 303 and 304 pm in CaAgIn). Temperature dependent magnetic susceptibility measurements show a magnetic moment of 7.40(1) μ{sub B} per europium atom. EuAgIn orders antiferromagnetically at 5.7(5) K. The divalent nature of europium is also evident from {sup 151}Eu Moessbauer spectra: δ = -10.50(1) mm.s{sup -1} at 78 K. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Costs of compliance with EU regulations and competitiveness of the EU dairy sector

NARCIS (Netherlands)

Bezlepkina, I.; Jongeneel, R.; Brouwer, F.M.; Dillen, K.; Meister, A.; Winsten, J.; Roest, de K.; Demont, M.

2008-01-01

The introduction of cross-compliance mechanism in the European Union with its 2003 CAPreform might affect the costs of production and thus competitiveness of the EU. Little evidence is available to asses the costs of compliance with regulations and it implication for trade. In this study a farm

Correlation Theory Applied to the Static and Dynamic Properties of EuO and EuS

DEFF Research Database (Denmark)

Lindgård, Per-Anker

1982-01-01

was used previously in the correlation theory2) primarily to calculate static properties. Self‐consistent dynamic and static calculations have here been performed for EuO, which is an ideal Heisenberg magnet with significant second‐nearest‐neighbor interaction (J2 = J1/5). The two‐pole approximation...... a cutoff of the spectrum at high frequencies, which cannot be seen experimentally, but which significantly influences the frequency moments. It was found that the finite J2 has significant importance for a comparison between theory and experiment. It is concluded that the calculation for a simple cubic n.......n. magnet by Hubbard3) does not describe the EuO data accurately, neither with respect to line shape nor frequency scale. Significant differences are to be expected between EuO and EuS having opposite sign for J2....

A Comparative Study of Er3+, Er3+-Eu3+, Er3+-Tb3+, and Er3+-Eu3+-Tb3+ Codoped Y2O3 Nanoparticles as Optical Heaters

Directory of Open Access Journals (Sweden)

G. A. Sobral

2015-01-01

Full Text Available Fluorescence intensity ratio (FIR technique, based on the thermal coupling of H11/22 and S3/24 energy levels of erbium ions, was used to study the optical heating behavior of rare earth doped yttrium oxide nanophosphors (Y2O3:Er3+, Y2O3:Er3+-Eu3+, Y2O3:Er3+-Tb3+, and Y2O3:Er3+-Eu3+-Tb3+ synthesized via PVA-assisted sol-gel route. The samples were optically heated by an 800 nm CW diode laser, while the upconverted green emissions were used to measure their temperatures in real time. The experimental results indicate that the studied nanoparticles are promising candidates to applications such as photothermal treatments and hyperthermia.

LCA of a condensing boiler according to EuP Directive

International Nuclear Information System (INIS)

Tremonti, M.; Breedvelt, L.; Padovan, G.; Bosio, S.; Corsini, M.

2008-01-01

In the light of the EuP Directive (2005/32/EC), producers of Energy using Product (EuP) are obliged to initiate eco design activities. Fourteen product groups are currently under study, one being the preparatory EC study Eco Boiler, and will result in a EuP Working Plan. The LCA of a condensing boiler, commissionated by an Italian SME in the Lombardy Region, has been conducted to support its environmental strategy and communication, to start implementing eco design activities and to anticipate implications to the EuP Directive. In line with the Eco Boiler study, no detailed LCA has been applied, instead a simplified LCA proves to be a strategic tool to support the company environmental objectives. Specifically, the condensing boiler (the option with the best environmental performance and the lowest life cycle costs for the final consumer) has been internally compared to other boilers, resulting in useful eco design recommendations

EU, Eastern Europe and Values Imperialism

Directory of Open Access Journals (Sweden)

Stephen White

2014-01-01

Full Text Available This paper proposes an idea of'values imperialism'as a helpful way of conceptualising the relationship between the EU and the states that came within its sphere of influence after the end of the Cold War, particularly its 'neighbours' in Eastern Europe. Values imperialism places its emphasis on the 'superstructure', including norms, laws and social practices. EU larger objective was that the assumptions about government and ownership that were favoured by the dominant powers (EU and the West in the broad term should be absorbed and recapitulated by those countries that were subordinate. The broad framework ofsubordination was established by the Partnership and Cooperation Agreements that began to be concluded from 1994 onwards. Patterns of'values imperialism'could also be discovered in the EU Common Strategies on Russia and Ukraine that were adopted in 1999. Article also points out several cases when the EU intervened directly in the domestic affairs of the Eastern Europe countries in a manner that was not always compatible with the provisions on state sovereignty: a 'European Instrument for Democracy and Human Rights', launched in 2006, interventions ofEU representatives in the work of local courts and organisation of exit polls, which could be used to discredit the official election results and in this way to undermine the position of local governments. Finally, the author concludes that the EU used 'values imperialism'practices in order to extend its influence, particularly in the Eastern Europe.

Practices in norm industries. Some remarks and questions on the implementation of the EU-BSS; Taetigkeiten in Norm-Industrien. Anmerkungen und Fragestellungen zur Umsetzung der EU-BSS

Energy Technology Data Exchange (ETDEWEB)

Flesch, K. [Saechsisches Landesamt fuer Umwelt, Landwirtschaft und Geologie, Dresden (Germany); Deutsch-Schweizerischer Fachverband fuer Strahlenschutz e.V., Juelich (Germany). Arbeitskreis ' ' Natuerliche Radioaktivitaet' ' (AKNAT)

2015-07-01

The expert group ''Natural radioactivity'' (AKNAT) of the ''German-Swiss Fachverband fuer Strahlenschutz e.V.'' (FS) has assessed the practicability of individual facts of provisions in the EU BSS (Council Directive 2013/59/Euratom) for protection against natural radiation sources with regard to its implementation into the laws and administrative provisions. Therefore the topics concerning NORM industries, radon, contaminated sites and commodities with NORM were identified to that the AKNAT commented from the technical point of view in preparation for implementing to a German radiation protection law. This presentation focuses on the topic of NORM industries. The AKNAT can provide its expert knowledge in practical radiation protection in terms of objections or suggestions for the implementation of the EU BSS into German radiation protection legislation. This relates to terminologies that are established or will be introduced, to the integration on the protection against natural radiation sources in the new concept of exposure situations and to the application on the principle of justification. This is as well connected to the modified methodology with the new concept of a 'graded approach' for NORM industries. Furthermore, some aspects will be discussed in connection with the new list of NORM industries, with the dose limits of occupational exposure as well as the dose limits for public exposure from all authorised practices.

Radioactive materials

International Nuclear Information System (INIS)

Sugiura, Yoshio; Shimizu, Makoto.

1975-01-01

The problems of radioactivity in the ocean with marine life are various. Activities in this field, especially the measurements of the radioactivity in sea water and marine life are described. The works first started in Japan concerning nuclear weapon tests. Then the port call to Japan by U.S. nuclear-powered naval ships began. On the other hand, nuclear power generation is advancing with its discharge of warm water. The radioactive pollution of sea water, and hence the contamination of marine life are now major problems. Surveys of the sea areas concerned and study of the radioactivity intake by fishes and others are carried out extensively in Japan. (Mori, K.)

Europium(II)heptaphosphide EuP/sub 7/

Energy Technology Data Exchange (ETDEWEB)

von Schnering, H G; Wittmann, M

1980-07-01

The novel polyphosphide, EuP/sub 7/, was prepared under controlled conditions by reaction of the elements in salt melts at 750-800 K. EuP/sub 7/ forms black prismatic crystals not attacked by dilute mineral acids and bases. The thermal decomposition yields EuP/sub 3/ at 700 K and in further steps EuP/sub 2/, Eu/sub 3/P/sub 4/ and EuP, respectively. According to the crystal structure as well as the electrical, optical and magnetic properties, EuP/sub 7/ is a semiconductor (Esub(G) = 0.9 eV; Esub(G) (vert) = 1.1 eV) with divalent europium (..mu.. = 7.55 B.M.). The compound crystallizes in the monoclinic space group P 2/sub 1//n with a = 1148.8(7) pm, b = 570.0(3) pm, c = 1061.0(6) pm, and ..beta.. = 106.08/sup 0/(5); (X-ray diffraction data; 1479 hkl; R = 0.031). The P-atoms are connected ((P-P) = 218.0-223.5 pm) to a 2-dimensional infinite polyanionic structure 2sub(infinity)(P/sub 7//sup 2 -/) with homonuclear 3-bonded and 2-bonded P-atoms in the ratio 5 : 2. The polyanionic network contains P/sub 6/-rings (chair conformation) as well as P/sub 8/-rings and P/sub 10/-rings. The Eu-atoms are bonded to 9 P-atoms (1,4,4-polyhedra) with bond distances ranging from 306.6 to 326.6 pm. The Eu-atoms complete the tetrahedral environment of the P-atoms.

EuCARD-HFM dipole model design options

CERN Document Server

Bruchon, Mélanie; Durante, Maria; Karppinen, Mikko; Kircher, François; Manil, Pierre; Milanese, Attilio; Oberli, Luc; Perez, Juan Carlos; Rifflet, Jean-Michel; Rondeaux, Françoise; Todesco, Ezio

2010-01-01

The EuCARD-HFM task aims at realizing a 13 T dipole magnet with an aperture of 100 mm, which is a challenging step towards very high field accelerator magnets. This dipole, utilizing Nb$_{3}$Sn superconductor, will be used in the Fresca test facility at CERN. A preliminary design study has compared two possible design layouts for the EuCARD-HFM magnet: the cos-θ and the block. This report summarizes the conclusions of this study and justifies, on the base of quantitative and qualitative arguments, our decision to pursue the detailed design with the block layout.

MTU engines for locomotives satisfying the EU stage IIIB emission standard; MTU-Lokomotivantriebe fuer die Emissionsstufe EU IIIB

Energy Technology Data Exchange (ETDEWEB)

Wintruff, Ingo; Reich, Christian; Geiselmann, Wolfgang; Gottschalch, Harald; Jansen, Eddy [MTU Friedrichshafen GmbH, Friedrichshafen (Germany)

2011-07-01

The emission limits for diesel locomotives inside the European Union are included within the scope of Directive 97/68/EC, which is sometimes referred to as the ''non-road directive''. The pollutants limited by it are NO{sub x}, particulates, CO and HCs. The aim, through the directive, is to reduce railway emissions by a factor of ten by the year 2020. The EU stage IIIB standard is due to take effect on 1 January 2012. This envisages a further drastic reduction in limit values compared with EU stage IIIA, which is applicable today. For diesel locomotives, EU stage IIIA only came into force as recently as 2009. The manufacturers of engines and locomotives are thus having to face up to the huge challenge of getting the technologies needed for EU stage IIIB ready for the production line within a period of only three years. MTU has succeeded in developing engines for diesel locomotives that comply with the EU stage IIIB emission standard, which appreciably lower emissions compared with engines satisfying EU stage IIIA, thanks to the incorporation of the most modern technologies available, and has even gone as far as preparing them for the EU stage IV, the next one to come into force. (orig.)

Sintering process of Eu doped luminescent glass prepared from porous glass

International Nuclear Information System (INIS)

Akai, T; Murakami, M; Yamashita, M; Okajima, T; Umesaki, N

2011-01-01

Eu doped high silica glass prepared by sintering porous glass exhibits blue luminescence with high quantum efficiency. In this work, we studied effects of sintering temperature on valance state of europium ion. To investigate a change of valance state of Eu, X-ray absorption near edge structure (XANES) spectroscopy measurements were carried out. Intensity of blue emission at around 430nm drastically increases when the sintering temperature is above 1000 deg. C. From XANES spectra, it is found that almost all the Eu exist as Eu 3+ in a samples sintered below 900 deg. C, while more than 70% of Eu exist as Eu 2+ in the sample sintered at 1050 deg. C and 1100 deg. C. The drastic change of oxidation state of europium ion between 900 and 1050 deg. C is discussed in relation to the structural change probed by infrared (IR) spectroscopy.

Photoswitchable Faraday effect in EuS-Au nanosystems

Energy Technology Data Exchange (ETDEWEB)

Kawashima, Akira; Nakanishi, Takayuki; Kitagawa, Yuichi; Fushimi, Koji; Hasegawa, Yasuchika [Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, North-13 West-8, Kita-ku, 060-8628, Sapporo (Japan)

2016-01-15

Effective photoswitchable europium sulfide nanocrystals with gold nanoparticles using dithiol (DDT: 1,10-decanedithiol) joint molecules, EuS-Au nanosystems, are demonstrated. The TEM image indicates the formation of EuS-Au nanosystems composed of cube-shaped EuS nanocrystals and spherical Au nanoparticles. Under visible-light irradiation, a drastic change of absorption band of EuS-Au nanosystems at around 600 nm was observed. The Faraday effects of EuS-Au nanosystems were estimated using magnetic circular dichroism (MCD) measurements. The effective change of the MCD spectra of EuS-Au nanosystems under visible-light irradiation was successfully observed at around 670 nm for the first time. The effective reversible changes in MCD spectra with the alternative irradiation cycles of visible light (>440 nm) and dark are also presented. The decrease rate of rotation angle at 670 nm of EuS-Au nanosystems is larger than that of absorbance. These results indicate that the effective change of MCD spectra of EuS-Au nanosystems would be dominated not only by a drastic change of absorption band related to enhanced LSPR of Au nanoparticles but also by specific interaction between EuS and Au in nanosystem under irradiation. Illustration of photoswitch and TEM image of EuS-Au nanosystems. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Legal aspects of the EU policy on irregular immigration

Directory of Open Access Journals (Sweden)

Voinikov Vadim

2015-12-01

Full Text Available This article addresses the issues pertaining to the adoption and development of legislation on irregular migration in the context of uncontrolled growth in the number of immigrants from North Africa and the Middle East to the EU. The article attempts at studying the EU legislation on irregular migration, classifying it, and analysing the prospects of EU migration legislation in the light of an increase in irregular immigration into the EU. The author systematises, classifies the current EU legislation on irregular immigration, and analyses the conditions, in which this legislation was developed. Using the legislation analysis method, the author proposes the following system of EU legislation on irregular immigration: rules preventing assistance to irregular immigration, rules preventing employment of irregular immigrants, rules on the return of irregular migrants and readmission, rules on border control, and rules on collaboration with third countries. The author pays special attention to analysing the current state of irregular immigration to the EU, which was dubbed the ‘greatest migration crisis in Europe’. The conclusion is that the European Union succeeded in the development of pioneering legislation on irregular immigration, which can serve as the basis for reception by other states. However, changes in the political and economic situation in the EU’s southern borderlands made the current legal mechanisms incapable of withstanding new threats. It necessitates a radical reform of the legislation on irregular immigration.

Alpha-induced reaction cross section measurements on 151Eu for the astrophysical γ-process

International Nuclear Information System (INIS)

Gyuerky, Gy.; Elekes, Z.; Farkas, J.; Fueloep, Zs.; Halasz, Z.; Kiss, G.G.; Somorjai, E.; Szuecs, T.; Gueraya, R.T.; Oezkana, N.

2010-01-01

Compete text of publication follows. The astrophysical γ-process is the main production mechanism of the p-isotopes, the heavy, proton-rich nuclei not produced by neutron capture reactions in the astrophysical sand r-processes. The γ-process is a poorly known process of nucleosynthesis, the models are not able to reproduce well the p-isotope abundances observed in nature. Experimental data on nuclear reactions involved in γ-process reaction networks are clearly needed to provide input for a more reliable γ-process network calculation. As a continuation of our systematic study of reactions relevant for the γ-process, the cross sections of the 151 Eu(α, γ) 155 Tb and 151 Eu(α,n) 154 Tb reactions have been measured. These reactions have been chosen because α-induced cross section data in the region of heavy p-isotopes are almost completely missing although the calculations show a strong influence of these cross section on the resulting abundances. Since the reaction products of both reactions are radioactive, the cross sections have been measured using the activation technique. The targets have been prepared by evaporating Eu 2 O 3 enriched to 99.2% in 151 Eu onto thin Al foils. The target thicknesses have been measured by weighing and Rutherford Backscattering Spectroscopy. The targets have been irradiated by typically 1-2 μA intensity α-beams from the cyclotron of ATOMKI. The investigated energy range between 12 and 17 MeV was covered with 0.5 MeV steps. This energy range is somewhat higher than the astrophysically relevant one, but the cross section at astrophysical energies is so low that the measurements are not possible there. The γ- activity of the reaction products has been measured by a shielded HPGe detector. The absolute efficiency of the detector was measured with several calibration sources. Since 154 Tb has two long lived isomeric states, partial cross sections of the 151 Eu(α,n) 154 Tb reaction leading to the ground and isomeric states

Solvent extraction of Cs(I), Zn(II), Eu(III) and Am(III) by 2-heptyl-2-methyl-nonanoic acid (Ha) from nitrate solutions

International Nuclear Information System (INIS)

Ramadan, A.; Elnaggar, H.A.; Souka, N.; Abdelfattah, A.

1994-01-01

The present work is devoted to study the extraction behavior of caesium, zinc, europium and americium radioactive isotopes using a new extractant C H 3 (C H 2 ) 6 . C(C 7 H 1 5) (C H 3 ). COOH (Ha) dissolved in benzene from aqueous nitrate media of constant ionic strength (0.1 M) using HNO 3 -Na NO 3 mixtures. The effect temperature on the extraction of these elements was also investigated to evaluate the thermodynamic functions as well as the equilibrium constant of each reaction. The extraction mechanisms were postulated on the light of the available data and the extracted species were formulated in the proposed stoichiometric equation for the extraction of each element individually and these species were suggested to be Cs (A); Zn OH(A) and Zn(A) 2 ; Eu No 3 (A) 2 and Am(A) 3 and for Cs(I), Zn(II), Eu(III) and Am(III), respectively. The thermodynamic parameters show exothermic enthalpy for all the reactions and negative entropy values reflecting very good ordering extraction mechanisms. 10 figs, 1 tab

Prediction of response to antiretroviral therapy by human experts and by the EuResist data-driven expert system (the EVE study).

Science.gov (United States)

Zazzi, M; Kaiser, R; Sönnerborg, A; Struck, D; Altmann, A; Prosperi, M; Rosen-Zvi, M; Petroczi, A; Peres, Y; Schülter, E; Boucher, C A; Brun-Vezinet, F; Harrigan, P R; Morris, L; Obermeier, M; Perno, C-F; Phanuphak, P; Pillay, D; Shafer, R W; Vandamme, A-M; van Laethem, K; Wensing, A M J; Lengauer, T; Incardona, F

2011-04-01

The EuResist expert system is a novel data-driven online system for computing the probability of 8-week success for any given pair of HIV-1 genotype and combination antiretroviral therapy regimen plus optional patient information. The objective of this study was to compare the EuResist system vs. human experts (EVE) for the ability to predict response to treatment. The EuResist system was compared with 10 HIV-1 drug resistance experts for the ability to predict 8-week response to 25 treatment cases derived from the EuResist database validation data set. All current and past patient data were made available to simulate clinical practice. The experts were asked to provide a qualitative and quantitative estimate of the probability of treatment success. There were 15 treatment successes and 10 treatment failures. In the classification task, the number of mislabelled cases was six for EuResist and 6-13 for the human experts [mean±standard deviation (SD) 9.1±1.9]. The accuracy of EuResist was higher than the average for the experts (0.76 vs. 0.64, respectively). The quantitative estimates computed by EuResist were significantly correlated (Pearson r=0.695, Pexperts. However, the agreement among experts was only moderate (for the classification task, inter-rater κ=0.355; for the quantitative estimation, mean±SD coefficient of variation=55.9±22.4%). With this limited data set, the EuResist engine performed comparably to or better than human experts. The system warrants further investigation as a treatment-decision support tool in clinical practice. © 2010 British HIV Association.

The 'primacy' and 'direct effect' of EU international agreements

DEFF Research Database (Denmark)

Gáspár-Szilágyi, Szilárd

2015-01-01

The rules on invoking EU norms before the Court of Justice and Member State courts are at the core of EU constitutional law. International agreements binding on the EU form an integral part of EU law and have primacy over inconsistent secondary EU legislation. Moreover, they also have primacy over...

Gamma-spectrometric and total alpha-beta counting methods for radioactivity analysis of deuterium depleted water

International Nuclear Information System (INIS)

Ferdes, Ov. S.; Mladin, C.; Vladu, Mihaela; Bulubasa, G.; Bidica, N.

2008-01-01

According to national regulations, as well as to the EU directive on the quality of drinking water, the radionuclide concentrations represent some of the drinking water quality parameters. Among the most important radioactivity content parameters are: the total alpha and total beta concentration (Bq/l); K-40 content, and the gamma-nuclides volume activities. The paper presents the measuring methods for low-level total alpha and/or beta counting of volume samples, as well as the high-resolution gamma-ray spectrometric method used to measure the volume activity of nuclides in drinking water. These methods are applied to monitor the radioactivity content and quality of the QLARIVIA brand of Deuterium depleted water (DDW). There are discussed the performances of these applied methods as well as some preliminary results. (authors)

Studies on radioactivities of dust samples in the air at high altitudes

International Nuclear Information System (INIS)

Kohara, Eri; Muronoi, Naohiro

2015-01-01

The radioactivity concentrations of airborne dust samples were studied. The samples had been collected at high altitude by the Japan Air Self-Defense Force from April 2013 to March 2014. The obtained data were used for gross beta radioactivity analysis and gamma nuclide analysis. It is shown that cesium 137 was mainly detected at the 10 km and 3 km altitude of central area of Japan in several samples. Gaseous radioiodine was not detected in all the samples. Radioactive xenon was detected but the concentration did not show significant difference to the background level. (author)

Study of casks shielded with heavy metal to transport highly radioactive substances

International Nuclear Information System (INIS)

Lucchesi, R.F.; Hara, D.H.S.; Martinez, L.G.; Mucsi, C.S.; Rossi, J.L.

2014-01-01

Nowadays, Brazil relies on casks produced abroad for transportation in its territory of substances that are sources of high radioactivity, especially the Mo-99. The product of the radioactive decay of the Mo-99 is the Tc-99m, which is used in nuclear medicine for administration to humans in the form of injectable radioactive drugs for the image diagnosis of numerous pathologies. This paper aims to study the existing casks in order to propose materials for the construction of the core part as shielding against gamma radiation. To this purpose, the existing literature on the subject was studied, as well as evaluation of existing and available casks. The study was focused on the core of which is made of heavy metals, especially depleted uranium for shielding the emitted radiation. (author)

Radioactivity Monitoring of the Irish Environment 2009

International Nuclear Information System (INIS)

McGinnity, P.; Currivan, L.; Dowdall, A.; Fegan, M.; Hanley, O.; Kelleher, K.; McKittrick, L.; Somerville, S.; Wong, J.; Pollard, D.

2010-12-01

This report presents the results of the environmental radioactivity monitoring programme carried out by the Radiological Protection Institute of Ireland (RPII) during 2009. The RPII has routinely monitored levels of radioactivity in the environment since 1982 and this is the latest in the RPII's series of environmental monitoring reports. The RPII reviews and updates its environmental programme annually so as to ensure it remains relevant and continues to focus on the most important sources of radioactivity in the environment. The principal aims of the RPII's monitoring programme are; to assess the level of radioactivity to which the Irish population is exposed as a result of radioactivity in the environment; to study trends and establish the geographical distribution of contaminating radionuclides so as to better understand the long term behaviour of artificial radioactivity in the food chain and the environment; to ensure that any increase in radiation levels resulting from an accidental release of radioactivity to the environment is detected and assessed rapidly. During 2009 radioactivity was measured in a wide range of foods and environmental materials including: air, water, milk, seafood, foodstuffs and complete meals. The most significant source of artificial radioactivity in the Irish marine environment is the discharge of low level liquid radioactive waste from the Sellafield Nuclear Fuel Reprocessing Plant on the north east coast of England. In order to assess the exposure arising from the source extensive sampling of fish and shellfish landed at ports along the north east coast of Ireland is undertaken. The most exposed group of individuals to discharges from Sellafield have been identified as commercial oyster and mussel farmers working along the north east coastline and their families. Manmade radioactivity is also present in the terrestrial environment due primarily to residual global fallout arising primarily from atmospheric testing of nuclear

Radioactivity Monitoring of the Irish Environment 2008

International Nuclear Information System (INIS)

Fegan, M.; Currivan, L.; Dowdall, A.; Hanley, O.; Hayden, E.; Kelleher, K.; Long, S.; McKittrick, L.; Somerville, S.; Wong, J.; Pollard, D.

2010-01-01

This report presents the results of the environmental radioactivity monitoring programme carried out by the Radiological Protection Institute of Ireland (RPII) during 2008. The RPII has routinely monitored levels of radioactivity in the environment since 1982 and this is the latest in the RPII's series of environmental monitoring reports. The RPII reviews and updates its environmental programme annually so as to ensure it remains relevant and continues to focus on the most important sources of radioactivity in the environment. The principal aims of the RPII's monitoring programme are; to assess the level of radioactivity to which the Irish population is exposed as a result of radioactivity in the environment; to study trends and establish the geographical distribution of contaminating radionuclides so as to better understand the long term behaviour of artificial radioactivity in the food chain and the environment; to ensure that any increase in radiation levels resulting from an accidental release of radioactivity to the environment is detected and assessed rapidly. During 2008 radioactivity was measured in a wide range of foods and environmental materials including: air, water, milk, seafood, foodstuffs and complete meals. The most significant source of artificial radioactivity in the Irish marine environment is the discharge of low level liquid radioactive waste from the Sellafield Nuclear Fuel Reprocessing Plant on the north east coast of England. In order to assess the exposure arising from the source extensive sampling of fish and shellfish landed at ports along the north east coast of Ireland is undertaken. The most exposed group of individuals to discharges from Sellafield have been identified as commercial oyster and mussel farmers working along the north east coastline and their families. Manmade radioactivity is also present in the terrestrial environment due primarily to residual global fallout arising primarily from atmospheric testing of nuclear

New reddish-orange and greenish-yellow light emitting phosphors: Eu3+ and Tb3+/Eu3+ in sodium germanate glass

International Nuclear Information System (INIS)

Álvarez, E.; Zayas, Ma. E.; Alvarado-Rivera, J.; Félix-Domínguez, F.; Duarte-Zamorano, R.P.; Caldiño, U.

2014-01-01

A spectroscopic analysis of sodium germanate glasses activated with Eu 3+ , Tb 3+ and Eu 3+ /Tb 3+ is performed from their photoluminescence spectra and decay times. In the Eu 3+ -singly doped glass reddish-orange light emission, with x=0.64 and y=0.35 CIE1931 chromaticity coordinates, is obtained upon Eu 3+ excitation at 393 nm. Such chromaticity coordinates are close to those (0.67, 0.33) proposed by the National Television Standard Committee for the red phosphor. When the sodium germanate glass is co-doped with Tb 3+ and Eu 3+ greenish-yellow light emission, with (0.41, 0.46) CIE1931 chromaticity coordinates, is obtained upon Tb 3+ excitation at 344 nm. Such greenish-yellow luminescence is due mainly to the terbium 5 D 4 → 7 F 6,5 and europium 5 D 0 → 7 F 1,2 emissions, Eu 3+ being sensitized by Tb 3+ through a non-radiative energy transfer. The non-radiative nature of this energy transfer is inferred from the increase in the decay rate of the Tb 3+ emission when the glass is co-doped with Eu 3+ . From an analysis of the Tb 3+ emission decay time curves it is inferred that such energy transfer might take place between Tb 3+ and Eu 3+ clusters through a short-range interaction mechanism. - Highlights: • Sodium germanate glasses are optically activated with Eu 3+ (GNE) and Tb 3+ /Eu 3+ (GNTE). • Reddish-orange light (0.64, 0.35) is generated by GNE pumped with 393 nm light. • Greenish-yellow light (0.41, 0.46) is generated by GNTE pumped with 344 nm light. • Non-radiative energy transfer Tb 3+ →Eu 3+ takes place in GNTE

EU trade in the time of financial crisis

Directory of Open Access Journals (Sweden)

Fojtíková, L.

2010-12-01

Full Text Available The paper is focused on the European Union (EU trade and trade policy in the time of global financial and economic crisis. The analysis of the EU exports and imports points out that the financial crisis has had a negative impact on the intra as well as on the extra-EU trade in the period 2007-2009, but differences among the EU member states have existed. Although the EU tries to support trade development in the world and remove barriers to trade, some protectionist tendencies were recorded in the time of the economic crisis. The last part of the paper gives emphasis to the EU trade policy and some trade measures which have been taken in the EU and its member states to support trade development or vice versa, to protect domestic industries. The results of the analysis show that, although some protectionist tendencies have been recorded both in extra and intra-EU trade, trade relations which are provided among member states are of significant importance all the time.

Radioactive wastes of Nuclear Industry

International Nuclear Information System (INIS)

1995-01-01

This conference studies the radioactive waste of nuclear industry. Nine articles and presentations are exposed here; the action of the direction of nuclear installations safety, the improvement of industrial proceedings to reduce the waste volume, the packaging of radioactive waste, the safety of radioactive waste disposal and environmental impact studies, a presentation of waste coming from nuclear power plants, the new waste management policy, the international panorama of radioactive waste management, the international transport of radioactive waste, finally an economic analysis of the treatment and ultimate storage of radioactive waste. (N.C.)

Analysis of rail accident frequencies and severities for the assessment of radioactive material transport risk - Summary report

International Nuclear Information System (INIS)

Heywood, J.D.; Schwartz, G.; Fett, J.

2001-01-01

This shortened version of the final contractual report to the European Commission DGXVII summarises the work performed and the conclusions drawn from consideration, comparison and analysis of transport accident frequency and severity assessment methods for radioactive material transport by rail. This paper aims to provide an introduction to the study whose final report is 155 pages in length. The findings are based on a comprehensive review of transport risk assessment methods and related databases available to EU member states. The emphasis has been on the probabilistic accident severity and frequency assessment methodologies developed and used by the organisations involved in this EU-funded research project - AEA Technology and GRS. The results should be of major assistance in the understanding and development of standardised quantitative risk assessment models. Further work is suggested to underpin the development of a harmonised accident methodology including the collection of more detailed rail data and analysis on a year by year basis as well as further consideration of the assumptions made for fire accident scenarios. (author)

Eu-emission quenching by electron screening in VO2 thin films

International Nuclear Information System (INIS)

Liu, H.; Lysenko, S.; Rua, A.; Vikhnin, V.; Vasquez, O.; Fernandez, F.E.

2006-01-01

As a kind of phase transition functional material, Vanadium dioxide (VO 2 ) thin films deposited on fused quartz substrate were fabricated using pulsed laser deposition (PLD) technique. Europium was introduced for structure study. By laser excitation at 526 nm, VO 2 thin film undergoes a reversible and ultrafast phase transition from semiconductor to metallic state, which results in a change of optical properties. In fluorescence measurement, Eu emission was found severely quenched in all as-grown thin films. After annealing the sample in air, a red Eu-emission appeared. The emission spectrum is characterized by a pronounced twin peak, centered at 617 nm ( 5 D - 7 F 2 ), surrounded by a set of broad, but relatively weaker bands (emission from 5 D to 7 F j manifold). The emission lifetime increased when the sample annealed at higher temperature for longer time. Each spectral component is actually a doublet which is the spectral overlap of emissions from Eu 3+ situated in two sites with different configurations. One is a linear h-Eu 3+ -h, where h stands for holes. Another is a right-angle configuration of h-Eu 3+ -h with Eu 3+ in the corner. In as-grown VO 2 film, Eu 3+ ions can either substitute V 4+ , leaving a negative charge around (Eu 3+ -O) - , or substitute V 5+ , leaving two negative charges around (Eu 3+ -O) -- . Due to trapped electrons in a large radius state, it covers Eu 3+ V 4+ -V 5+ complexes. It suggests that the screening by degenerate electronic gas may result in switching off the Eu-related optical response for a wide spectral region, causing emission quenching in VO 2 films

EU's tiltræden til EMRK - et sisyfosarbejde?

DEFF Research Database (Denmark)

Bang Fuglsang Madsen Sørensen, Henning

2015-01-01

EU-Domstolen afviste med opinion 2/13 den 18. december 2014 at lade EU tiltræde EMRK på grundlag af et udkast til en tiltrædelsesaftale. I artiklen behandles baggrunden for og det konkrete indhold i EU-Domstolens afvisning, hvorefter det undersøges, i hvilket omfang EMD fremover kan forventes...... at respektere EU-rettens forrang og dermed undlade at holde medlemsstaterne ansvarlige for påståede krænkelser som følge af medlemsstaternes forpligtelser efter EU-retten....

Development of BaSO sub 4 :Eu thermoluminescence phosphor

CERN Document Server

Madhusoodanan, U; Lakshmanan, A R

1999-01-01

A highly sensitive thermoluminescence (TL) phosphor based on BaSO sub 4 :Eu was developed following the coprecipitation technique and firing in argon atmosphere at 1123 K. Photoluminescence studies confirm that firing in argon atmosphere instead of air increased the incorporation of Eu ions in 2+ valence state. At low gamma-ray doses, its TL sensitivity is nearly 2 to 3 times higher than that of CaSO sub 4 :Dy phosphor. The other salient features of this BaSO sub 4 :Eu TL phosphor are a constant glow curve shape and a nearly linear gamma-ray dose response.

GENERAL OVERWIEV ON EU ECONOMY

Directory of Open Access Journals (Sweden)

NICOLETA GEORGETA PANAIT

2013-05-01

Full Text Available The impact of the international economic crisis on new EU member states has proven to be more severe than the first estimates of the economic analysts. The situation is different for each Member State, the nature and the dimension of the challenges faced are not identical, and the pace of reform is not the same. The economic crisis has prompted intense and sustained action by the EU's national governments, the European Central Bank and the Commission. All have been working closely together to support growth and employment, ensure financial stability, and put in place a better governance system for the future. Sustainable development in the future is the common responsibility of all Member States and EU institutions, because our economies are closely interlinked, and the EU economic governance now reconfigured to provide more effective responses at the policy level, to give a good reaction to the present and the future challenges.

Influence of hydroxybenzoic acids on the adsorption of Eu(III) onto α,γ-Al_2O_3 particles in mildly acidic conditions: A macroscopic and spectroscopic study

International Nuclear Information System (INIS)

Moreau, Pauline; Colette-Maatouk, Sonia; Gareil, Pierre; Reiller, Pascal E.

2016-01-01

The influence of hydroxybenzoic acids (HAH_n), namely p-hydroxybenzoic acid (4-hydroxybenzoic acid, HPhbH) and protocatechuic acid (3,4-dihydroxybenzoic acid, HProtoH_2), on the adsorption of europium(III) onto α,γ-Al_2O_3 particles is studied as a function of acid concentration. After measuring the adsorption edge of the Eu(III)/α,γ-Al_2O_3 binary system, and using the previously studied binary component system Eu(III)/HAH_n—Moreau et al. (2015) Inorg. Chim. Acta432, 81—, and HAH_n/α,γ-Al_2O_3—Moreau et al. (2013) Colloids Surf. A435, 97—, it is evidenced that HPhbH does not enhance Eu(III) adsorption onto α,γ-Al_2O_3 in the Eu(III)/HPhbH/α,γ-Al_2O_3 ternary system. Conversely, HProtoH_2 enhances Eu(III) adsorption onto α,γ-Al_2O_3 in the Eu(III)/HProtoH_2/α,γ-Al_2O_3 ternary system. Adsorption of the acids are also found higher in the Eu(III)/acid/α,γ-Al_2O_3 ternary systems as compared with the corresponding binary systems assessing synergetic effects. For high HPhbH concentrations, a ternary surface species involving ≡AlOH surface sites, Eu(III), and PhbH"– is evidenced by time-resolved luminescence spectroscopy (TRLS). However, in the Eu(III)/HProtoH_2/α,γ-Al_2O_3 ternary system, chemical environment of Eu(III) is found to be very close to that in the Eu(III)/HProtoH_2 binary system. Ternary surface species could not be evidenced in the Eu(III)/HProtoH_2/α,γ-Al_2O_3 ternary system with TRLS because of the very short decay time of Eu(III) in the presence of protocatechuic acid. - Highlights: • Adsorption in the Eu(III) – hydroxybenzoic acid – alumina system is studied. • Adsorption is quantified and luminescence parameters are obtained independently. • Synergistic effect of organic acids adsorption are evidenced in the ternary systems. • A ternary species is clearly shown for the p-hydrobenzoic acid.

EU Nuclear vs. Fukushima

International Nuclear Information System (INIS)

Poncelet, Jean-Pol

2011-01-01

Conclusions: • The Fukushima-Daiichi accident represents an opportunity for the nuclear industry to demonstrate its ability to learn from experience through “a continuous improvement strategy”; • Inside the EU: which legal framework for nuclear safety - harmonisation of licensing procedures - EU-level reactor design clearance?; • No way forward without public support: how to address, explain, convince?; • Greater cooperation between industry and international organizations: FORATOM available to contribute

The EU's Normative Power in Changing World Politics

DEFF Research Database (Denmark)

Manners, Ian

2009-01-01

global order: 1) what is the concept of normative power in world politics?; 2) what is an effective EU toolbox for tackling new challenges?; 3) how does the EU go beyond self-perception and rhetoric?; 4) what is the raison d'etre of the EU?; and 5) how might normative power in EU external policies lead...

Calling the EU's bluff. Who are the real champions of biodiversity and traditional knowledge in the EU-Central American and EU-Community of Andean Nations Association Agreements?

International Nuclear Information System (INIS)

Hall, R.

2009-12-01

Global Europe and the EU's Raw Materials Initiative are designed to bolster the EU's economic position - whatever the cost - in the face of fierce global competition for both markets and resources, especially from emerging economies such as China and India. The EU also fears losing trade to the US, which has already secured trade and investment concessions from countries in the Western hemisphere, through the Dominican Republic-Central American Free Trade Agreement (DR-CAFTA) and other bilateral trade agreements.

The safety case for deep geological disposal of radioactive waste

International Nuclear Information System (INIS)

Kwong, Gloria

2014-01-01

The concept of a 'safety case' for a deep geological repository for radioactive waste was first introduced by the NEA Expert Group on Integrated Performance Assessment (IPAG). It was further developed in the NEA report entitled Confidence in the Long-term Safety of Deep Geological Repositories (1999), and since then it has been taken up in international safety standards as promulgated by the International Atomic Energy Agency (IAEA, 2006, 2011) and more recently in recommendations by the International Commission on Radiological Protection on the application of the system of radiological protection in geological disposal (ICRP, 2013). Many national radioactive waste disposal programmes and regulatory guides are also applying this concept. The NEA has used the safety case as a guide in several international peer reviews of national repository programmes and safety documentation. In Europe, the EU Directive 2011/70/ Euratom (EU, 2011) establishes a framework to ensure responsible and safe management of spent fuel and radioactive waste by member states that, inter alia, requires a decision-making process based on safety evidence and arguments that mirror the safety case concept. In 2007, the NEA, the IAEA and the European Commission (EC) organised a symposium on Safety Cases for the Deep Disposal of Radioactive Waste: Where Do We Stand? Since this time, however, there have been some major developments in a number of national geological disposal programmes and significant experience in preparing and reviewing cases for the operational and long-term safety of proposed and operating geological repositories. A symposium on The Safety Case for Deep Geological Disposal of Radioactive Waste: 2013 State of the Art was thus organised to assess developments since 2007 in the practice, understanding and roles of the safety case, as applied internationally at all stages of repository development, including the interplay of technical, regulatory and societal issues. The symposium

The EU as an international security provider

DEFF Research Database (Denmark)

Rodt, Annemarie Peen; Wolff, Stefan; Whitman, Richard

2015-01-01

This contribution develops a framework of analysis that covers the actors involved in the policy making process of international security provision, the dynamics of this process itself, its outcomes (concrete strategies and policies) and their impact. Our efforts to establish such a framework...... of analysis, which could serve as the foundation for a mid-range theory of the EU as an international security provider, will examine the relevance of, and apply, existing theories of international relations/international security and foreign policy analysis to the specific case of the EU. The framework...... that will emerge from this analysis will then be tested and applied empirically in the following contributions that focus on how particular policies are formulated and implemented, and that analyse, in single and comparative case studies, the impact and effectiveness of the EU as an international security provider....

A study for natural radioactivity levels in some soil samples using gamma spectrometry

International Nuclear Information System (INIS)

Mohamed, Yousif Hassab El Rasoul

1997-05-01

The purpose of this study was to investigate a few selected soil samples and to study their natural radioactivity using gamma spectrometry. The first sample was a rock phosphate from Nuba mountains region which is being considered as a low cost fertilizer. Another sample came from Miri lake area (Nuba mountains) which is known to have elevated natural radioactivity level. The other four samples came from different other regions in Sudan for comparison. The idea was to identify the radioactive nuclides present in these soil samples, to trace their sources and to determine the activity present in them. (Author)

Study of the radiation and radioactivity in dairy formulas

International Nuclear Information System (INIS)

Mireles G, F.; Pinedo V, J.L.; Quirino T, L.L.; Davila R, J.I.; Rios M, C.; Leal A, B.; Lopez del Rio, H.

2006-01-01

The radiation and natural radioactivity is present in the man's food chain, like it is the case of the milk, and it comes from the natural series of radioactive decay of the 238 U, 235 U and 232 Th, and of the 40 K radioisotope. Since the radioisotopes can be found in floor of where its are transferred to the grasses and in the water that serve as food and of drinking to the cows, then to enter the milk and its derived to the human consumption. In this work it is presented the study of the radiation and gamma radioactivity of 40 samples of dairy formulas of the trademarks and presentations more sold in the market of the private and public sectors. The measurements of the gamma ray spectra were carried out with a spectrometry system based on an Hyper pure Germanium detector (HPGe). The detector has a resolution (FWHM) of 1.9 keV for an energy of the gamma ray of 1.332 keV of the 60 Co. This study presents the results of the concentration in activity of dairy formulations of the radioisotopes of interest. Also, the results are related with possible damages to the health. (Author)

Effect of Eu magnetism on the electronic properties of the candidate Dirac material EuMnBi2

Science.gov (United States)

May, Andrew F.; McGuire, Michael A.; Sales, Brian C.

2014-08-01

The crystal structure and physical properties of the layered material EuMnBi2 have been characterized by measurements on single crystals. EuMnBi2 is isostructural with the Dirac material SrMnBi2 based on single-crystal x-ray diffraction, crystallizing in the I4/mmm space group (No. 139). Magnetic susceptibility measurements suggest antiferromagnetic (AFM) ordering of moments on divalent Eu ions near TN=22 K. For low fields, the ordered Eu moments are aligned along the c axis, and a spin flop is observed near 5.4 T at 5 K. The moment is not saturated in an applied field of 13 T at 5 K, which is uncommon for compounds containing Eu2+. The magnetic behavior suggests an anisotropy enhancement via interaction between Eu and the Mn moments that appear to be ordered antiferromagnetically below ≈310 K. A large increase in the magnetoresistance is observed across the spin flop, with absolute magnetoresistance reaching ≈650% at 5 K and 12 T. Hall effect measurements reveal a decrease in the carrier density below TN, which implies a manipulation of the Fermi surface by magnetism on the sites surrounding the Bi square nets that lead to Dirac cones in this family of materials.

Management of radioactive waste

International Nuclear Information System (INIS)

Neerdael, B.; Marivoet, J.; Put, M.; Van Iseghem, P.; Volckaert, G.; Wacquier, W.

1998-09-01

The document gives an overview of of different aspects of radioactive waste management in Belgium. The document discusses the radioactive waste inventory in Belgium, the treatment and conditioning of radioactive waste as well as activities related to the characterisation of different waste forms. A separate chapter is dedicated to research and development regarding deep geological disposal of radioactive waste. In the Belgian waste management programme, particular emphasis is on studies for disposal in clay. Main results of these studies are highlighted and discussed

Acupuncture meridians demythified. A study using the radioactive tracer method

International Nuclear Information System (INIS)

Simon, J.; Esquerre, J.P.; Guiraud, R.; Guiraud, G.; Lazorthes, Y.

1988-01-01

Radioactive trajectories can be visualized by injecting a radioactive tracer, technetium 99 m, at the site of acupuncture points. To determine the exact nature of these trajectories we performed several experiments on healthy volunteers, and our results may be summarized as follows. The target organs of technetium 99 m, and notably the thyroid gland, were always visualized. The circulating radioactivity, visible on scintiscans and confirmed by venous blood counts, was not negligible. The radioactive trajectories we observed were often divided at their starting point and did not extend along the whole length of the acupuncture meridians they might have made visible. The radioactive trajectories disappeared after venous blockade to reappear when the blockade was lifted. Finally, the radioactive trajectories obtained were very similar after injection at the acupuncture point and at a control point. These findings indicate a lymphatic and venous drainage of the radioactive tracer at the site of injection followed by transportation through the veins, rather than visualization of acupuncture meridians as suggested by some authors [fr

Acupuncture meridians demythified. A study using the radioactive tracer method

Energy Technology Data Exchange (ETDEWEB)

Simon, J.; Esquerre, J.P.; Guiraud, R.; Guiraud, G.; Lazorthes, Y.

1988-07-01

Radioactive trajectories can be visualized by injecting a radioactive tracer, technetium 99 m, at the site of acupuncture points. To determine the exact nature of these trajectories we performed several experiments on healthy volunteers, and our results may be summarized as follows. The target organs of technetium 99 m, and notably the thyroid gland, were always visualized. The circulating radioactivity, visible on scintiscans and confirmed by venous blood counts, was not negligible. The radioactive trajectories we observed were often divided at their starting point and did not extend along the whole length of the acupuncture meridians they might have made visible. The radioactive trajectories disappeared after venous blockade to reappear when the blockade was lifted. Finally, the radioactive trajectories obtained were very similar after injection at the acupuncture point and at a control point. These findings indicate a lymphatic and venous drainage of the radioactive tracer at the site of injection followed by transportation through the veins, rather than visualization of acupuncture meridians as suggested by some authors.

Blue emission in photoluminescence spectra of the red phosphor CaAlSiN3:Eu2+ at low Eu2+ concentration

Science.gov (United States)

Suda, Yoriko; Kamigaki, Yoshiaki; Yamamoto, Hajime

2018-04-01

In red phosphor CaAlSiN3:Eu2+, unintentional blue emission occurs with increasing intensity at low Eu2+ concentrations and also at low measurement temperatures. Time-resolved photoluminescence measurements were used to confirm the decrease in red emission and increase in blue emission with the decreasing Eu2+ concentration. The peak timing of blue emission occurred faster than that of red emission, and long lasting luminescence of red emission was observed as well as that of blue emission. The Eu2+ concentration dependences of the red and blue emissions were similar to those of the g values 4.75 (Eu2+) and 2.0025 (nitrogen vacancies), respectively, which were observed from electron spin resonance (ESR) measurements. The origin of the blue emission is proposed to be nitrogen vacancy defects, which had about the same ESR signal intensity as that of Eu2+ ions in CaAlSiN3:Eu2+ containing 0.01 at. % Eu2+. The possibility of red emission also arising from excited electron tunneling or thermal pathways via nitrogen vacancies is discussed. Long lasting red emission was observed, which is proposed to involve trapped electrons remaining at nitrogen vacancies, yielding blue emission and inducing red emission from Eu2+ ions.

Fighting windmills? EU industrial interest and global climate negotiations

International Nuclear Information System (INIS)

Steiner Brand, U.; Tinggaard Svendsen, G.

2003-01-01

Why has the EU been so eager to continue the climate negotiations? Can it be solely attributed to the EU feeling morally obliged to be the main initiator of continued progress on the climate change negotiations, or can industrial interests in the EU, at least partly, explain the behaviour of the EU? We suggest that the EU has a rational economic interest in forcing the technological development of renewable energy sources to get a fast-mover advantage, which will only pay if a sufficient number of countries implement sufficiently stringent GHG reductions. The Kyoto Protocol, which imposes binding reductions on 38 OECD countries, implies that, as a first-mover, the EU will be to sell the necessary new renewable technologies, most prominently wind mills, to other countries, when they ratify and implement the Kyoto target levels. In the latest EU proposal made in Johannesburg, the EU pushed for setting a target of 15% of all energy to come from sources such as windmills, solar panels and waves by 2015. Such a target would further the EU's interests globally, and could explain, in economic terms, why the EU eagerly promotes GHG trade at a global level whereas the US has left the Kyoto agreement to save the import costs of buying the EU's renewable systems. (au)

Study of two different radioactive sources for prostate brachytherapy treatment

International Nuclear Information System (INIS)

Pereira Neves, Lucio; Perini, Ana Paula; Souza Santos, William de; Caldas, Linda V.E.; Belinato, Walmir

2015-01-01