WorldWideScience

Sample records for quaternary period

  1. The geological characteristics during the quaternary period around Japan island

    Energy Technology Data Exchange (ETDEWEB)

    Hagiwara, Shigeru [Chuo Kaihatsu Corp., Enterprises Promotion Bureau, Tokyo (Japan); Sakamoto, Yoshiaki; Ogawa, Hiromichi; Nakayama, Shinichi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2002-11-01

    Radioactive wastes arising from radioisotope facilities and nuclear research facilities should be disposed of in the surface of the earth, the shallow underground, the adequate depth and the deep underground according to radioactivity concentrations, and should be managed during several hundreds years. The earth scientific phenomena observed in Japan island at present occurred continuously from the past, and the same phenomena at the future should occur in the similar factor. Therefore, for the purpose to get the fundamental data for the selection of disposal site, this report reviewed on the genesis and classification of the sediments, earth scientific phenomena observed in Japan island and the feature of each place (10 districts) concerning to the Quaternary period in the newest geological time unit. (author)

  2. The Quaternary Pan-lake (Overflow) Period and Paleoclimate on the Qinghai-Tibet Plateau

    Institute of Scientific and Technical Information of China (English)

    ZHENG Mianping; YUAN Heran; ZHAO Xitao; LIU Xifang

    2005-01-01

    Lake geomorphology and high-level lacustrine deposits since the mid-late Pleistocene are well preserved in lakes of the Qinghai-Tibet Plateau. According to geological surveys of 17 lake districts in different locations of the plateau,combined with interpretations of satellite images and topographic maps, the authors studied the timing of formation and scopes of the pan-lake areas of the plateau and their paleoclimate. The latest two high lake levels (overflow surfaces) on the Qinghai-Tibet Plateau in the Quaternary occurred at ~40 to 30/35 ka and ~65 to 53 ka respectively. In these time intervals, the plateau was covered by huge interconnected pan-lake systems with a total area of ~36 km2 and a total volume of lake water of >530 million km2, which are about 38 times and 659 times larger than those of the modem lakes respectively. Before this pan-lake period in the late Pleistocene, there had been three high lake levels that occurred at ~132-112 ka, 110-95 ka and 91-72/~83-75 ka respectively, suggesting that the late Quaternary climate on the plateau was unstable and changed rapidly. The ~40-30 ka high lake level also appeared in the Tengger desert north of the plateau,suggesting that there existed very strong summer monsoons from South Asia then; the variation in solar radiation with a 20,000 precessional period has special importance for the high-altitude Qinghai-Tibet Plateau in the low-latitude zone of the Earth. Around 30 ka, the pan-lakes at the peripheries of the Qinghai-Tibet Plateau drained out suddenly with rapid uplift of the plateau and cooling. In a short time the huge amount of cold lake water emptied into the Indian Ocean and Western Pacific. The draining event of the pan-lakes brought about the environmental changes of rivers and lakes at peripheries of the plateau.

  3. Interpretation and preliminary simulation of the 40 ka periodicity of the Quaternary glaciation

    Institute of Scientific and Technical Information of China (English)

    LI Nan; CHEN Xing

    2007-01-01

    More and more proxy records approved that the periodicity of the glacial cycles is about 40 ka before MPT (middle Pleistocene transition) as early as late Tertiary from 3.0 Ma to 0.9 Ma, whereas it changes to about 100 ka after MPT.Summer insolation at high latitude in Northern Hemisphere, usually considered as the main external force for the ice age, is dominated by the 23 ka precession period, which does not match the period of the glacial cycles.In this paper, we define an energy index C and its threshold Ct that indicate the net energy supply and the overall response of the climate system.The difference between these two parameters determines whether the ice sheet melts or not, and accordingly the start and termination of the interglacial stages, as well as the periodicity of glacial oscillations.Based on the energy threshold hypothesis, the preliminary simulation experiments are made to test the period of the glacial cycles and driven factors from a conceptual model.The results indicate that energy index C and threshold Ct can interpret not only the 40 ka periodicity before MPT, but also the quasi-100 ka periodicity after MPT to some extent, and the 40 ka is the basic period of the glacial cycles, which discloses the inherent continuity of climatic change before and after MPT.

  4. Occurrences of warm-adapted mammals in north China over the Quaternary Period and their paleo-environmental significance

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    of warm-adapted mammals during that span were the most frequent and most widespread. It means that the climate of the Late Pleistocene experienced the most frequent fluctuation over the whole period of Quaternary.

  5. Using speleothem growth periods to constrain Quaternary evolution of Siberian permafrost

    Science.gov (United States)

    Vaks, A.; Gutareva, O.; Breitenbach, S.; Osinzev, A.; Henderson, G. M.

    2010-12-01

    We have used speleothems from three caves along a north-south transect in Eastern Siberia to track the evolution of permafrost during the last ~650 ky. Speleothems form in caves only when the cave temperature (which approximates the mean annual surface air temperature) is above 0°C and meteoric waters can penetrate into the cave. Periods of speleothem deposition therefore provide a tracer for presence or absence of the permafrost. The northernmost cave used in this study, the Lenskaya Ledyanaya Cave (Icy Cave of Lena), is located at 60°22’N - 116°56’E, on the southern boundary of the continuous permafrost zone, with no present-day water seepage in the cave and large amounts of ice partially filling its inner chambers. Botovskaya Cave system (55°18'N; 105°21'E) is located in the discontinuous permafrost zone with water seepage and speleothem growth occurring only in a limited area of the cave. Okhotnichya Cave (52°07’N; 105°27’E), near southern Lake Baikal, is located in the zone of island permafrost, with water seepage and speleothem growth occurring in all parts of the cave. The mean annual temperatures vary from -7°C in the area of Lenskaya Ledyanaya Cave, to ~0°C in the Okhotnichya cave region, and the present-day vegetation in the area is sub-arctic taiga forest. More than 60 horizons from 15 speleothems from these three caves were dated by U-Th method. The high initial 234U/238U activity ratios in Siberian speleothems (3-6) extend the dateable range of the U-Th method to more than 650 ky. The youngest speleothem age in the Lenskaya Ledyanaya Cave was 626 ± 46 ky, probably corresponding to interglacial Marine Isotopic Stage (MIS) 15, whereas the other 11 other horizons in 6 additional speleothems from this cave were older than the dating limit. In Botovskaya and Okhotnichya caves speleothem ages clustered into warmest intervals of the interglacial periods at ~500 ky (MIS-13), 420-370 ky (MIS-11), 207-199 ky (MIS-7.2), 131-120 ky (MIS-5.5) and

  6. Dynamics of Late Quaternary sapropel periods documented by micropaleontological and sedimentological data from North Aegean Sea

    Science.gov (United States)

    Gkaniatsa, Georgia; Kontakiotis, George; Antonarakou, Assimina; Drinia, Hara; Anastasakis, George

    2017-04-01

    Located at the interface of the mid/high latitude climate system and affected by the North Atlantic Oscillation and the monsoonal system over Africa, the Mediterranean Sea has a unique potential to record the occurrence and phasing of climatic changes in both systems. In particular, the eastern Mediterranean Sea is more sensitive and faster responding to external forcing than the open ocean due to smaller size and partial isolation. A manifestation of the high sensitivity of the eastern Mediterranean sedimentary environment to climatic forcing is the periodic deposition of dark colored and organic matter rich sediments, termed "sapropels". In particular their formation is closely correlated with the reduction in ventilation, due to low salinity surface water layer, leading to anoxia at the bottom and preservation of organic matter, and/or the increase in primary productivity in the photic zone. To address which factor is more responsible for the sapropel's formation, a high-resolution study of planktonic foraminiferal abundances in two cores from North Aegean was carried out. Their response reflects the essential information about the paleoceanographic evolution in the water column in terms of stratification and productivity during the different sapropel events covering the last 90 kyrs. Cores M 22-67 and M22-68 were recovered from the water depths of 175 and 305 m respectively in the Chios Basin (North Aegean Sea). Both cores approximately span the last 90 ka, exposing the most recent S1 and the older S3 sapropels. They particularly exposed at very high resolution compared to most occurrences throughout the eastern Mediterranean, because of the highest sediment accumulation rates occurred in the study basin. Application of this information to the study hemipelagic sediment cores, through the planktonic foraminiferal analyses, suggests that we further contribute to existing evidence of climatic instability during sapropel deposition in eastern Mediterranean Sea

  7. The global stratotype section and point (GSSP) for the base of the holocene series/epoch (Quaternary System/Period) in the NGRIP ice core

    DEFF Research Database (Denmark)

    Walker, Mike; Johnsen, Sigfus Johann; Rasmussen, Sune Olander;

    2008-01-01

    The Greenland ice core from NorthGRIP (NGRIP) contains a proxy climate record across the Pleistocene–Holocene boundary of unprecedented clarity and resolution. Analysis of an array of physical and chemical parameters within the ice enables the base of the Holocene, as reflected in the first signs...... of climatic warming at the end of the Younger Dryas/Greenland Stadial 1 cold phase, to be located with a high degree of precision. This climatic event is most clearly reflected in an abrupt shift in deuterium excess values, accompanied by more gradual changes in d18O, dust concentration, a range of chemical...... the Global Stratotype Section and Point (GSSP) for the base of the Holocene Series/Epoch (Quaternary System/Period)....

  8. The Nonlinear Response of the Equatorial Pacific Ocean-Atmosphere System to Periodic Variations in Insolation and its Association with the Abrupt Climate Transitions during the Quaternary.

    Science.gov (United States)

    Lopes, P. G.

    2015-12-01

    The evidences of climate changes during the Quaternary are abundant but the physical mechanisms behind the climate transitions are controversial. The theory of Milankovitch takes into account the periodic orbital variations and the solar radiation received by the Earth as the main explanation for the glacial-interglacial cycles. However, some gaps in the theory still remain. In this study, we propose elucidating some of these gaps by approaching the Equatorial Pacific Ocean as a large oscillator, capable of triggering climate changes in different temporal scales. A mathematical model representing El Ninõ-like phenomena, based on Duffing equation and modulated by the astronomical cycle of 100 ka, was used to simulate the variability of the equatorial Pacific climate system over the last 2 Ma. The physical configuration of the Pacific Ocean, expressed in the equation, explains the temporal limit of the glacial-interglacial cycles. According to the simulation results, consistent with paleoclimate records, the amplification of the effects of the gradual variation of the Earth's orbit eccentricity - another unclear question - is due to the feedback mechanism of the Pacific ocean-atmosphere system, which responds non-linearly to small variations in insolation forcing and determines the ENSO-like phase (warm or cold) at different time scales and different intensities. The approach proposed here takes into account that the abrupt transitions between the ENSO-like phases, and the consequent changes in the sea surface temperature (SST) along the Equatorial Pacific Ocean, produce reactions that act as secondary causes of the temperature fluctuations that result in a glaciation (or deglaciation) - as the drastic change on the rate of evaporation/precipitation around the globe, and the increase (or decrease) of the atmospheric CO2 absorption by the phytoplankton. The transitional behavior between the warm and the cold phases, according to the presented model, is enhanced as

  9. The last interglacial period at Guantanamo Bay, Cuba and an estimate of late Quaternary tectonic uplift rate in a strike-slip regime

    Science.gov (United States)

    Schweig, E. S.; Muhs, D. R.; Simmons, K. R.; Halley, R. B.

    2015-12-01

    Guantanamo Bay, Cuba is an area dominated by a strike-slip tectonic regime and is therefore expected to have very low Quaternary uplift rates. We tested this hypothesis by study of an unusually well preserved emergent reef terrace around the bay. Up to 12 m of unaltered, growth-position reef corals are exposed at about 40 sections examined around ˜40 km of coastline. Maximum reef elevations in the protected, inner part of the bay are ˜11-12 m, whereas outer-coast shoreline angles of wave-cut benches are as high as ˜14 m. Fifty uranium-series analyses of unrecrystallized corals from six localities yield ages ranging from ˜134 ka to ˜115 ka, when adjusted for small biases due to slightly elevated initial 234U/238U values. Thus, ages of corals correlate this reef to the peak of the last interglacial period, marine isotope stage (MIS) 5.5. Previously, we dated the Key Largo Limestone to the same high-sea stand in the tectonically stable Florida Keys. Estimates of paleo-sea level during MIS 5.5 in the Florida Keys are ~6.6 to 8.3 m above present. Assuming a similar paleo-sea level in Cuba, this yields a long-term tectonic uplift rate of 0.04-0.06 m/ka over the past ~120 ka. This estimate supports the hypothesis that the tectonic uplift rate should be low in this strike-slip regime. Nevertheless, on the southeast coast of Cuba, east of our study area, we have observed flights of multiple marine terraces, suggesting either (1) a higher uplift rate or (2) an unusually well-preserved record of pre-MIS 5.5 terraces not observed at Guantanamo Bay.

  10. Periodic isolation of the southern coastal plain of South Africa and the evolution of modern humans over late Quaternary glacial to interglacial cycles

    Science.gov (United States)

    Compton, J. S.

    2012-04-01

    Humans evolved in Africa, but where in Africa and by what mechanisms remain unclear. The evolution of modern humans over the last million years is associated with the onset of major global climate fluctuations, glacial to interglacial cycles, related to the build up and melting of large ice sheets in the Northern Hemisphere. During interglacial periods, such as today, warm and wet climates favored human expansion but during cold and dry glacial periods conditions were harsh and habitats fragmented. These large climate fluctuations periodically expanded and contracted African ecosystems and led to human migrations to more hospitable glacial refugia. Periodic isolation of relatively small numbers of humans may have allowed for their rapid evolutionary divergence from the rest of Africa. During climate transitions these divergent groups may have then dispersed and interbred with other groups (hybridization). Two areas at the opposite ends of Africa stand out as regions that were periodically isolated from the rest of Africa: North Africa (the Maghreb) and the southern coastal plain (SCP) of South Africa. The Maghreb is isolated by the Sahara Desert which periodically greens and is reconnected to the rest of Africa during the transition from glacial to interglacial periods. The SCP of South Africa is isolated from the rest of Africa by the rugged mountains of the Cape Fold Belt associated with inedible vegetation and dry climates to the north. The SCP is periodically opened when sea level falls by up to 130 m during glacial maxima to expose the present day submerged inner continental shelf. A five-fold expansion of the SCP receiving more rainfall in glacial periods may have served as a refuge to humans and large migratory herds. The expansive glacial SCP habitat abruptly contracts, by as much as one-third in 300 yr, during the rapid rise in sea level associated with glacial terminations. Rapid flooding may have increased population density and competition on the SCP to

  11. QUATERNARY GEOLOGY & GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20112526Bai Daoyuan (Hunan Institute of Geology Survey,Changsha 410011,China); Liu Bo Quaternary Tectonic-Sedimentary Characteristics and Environmental Evolution of Linli Sag,Dongting Basin (Journal of

  12. QUATERNARY GEOLOGY & GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111129 Bai Daoyuan(Hunan Institute of Geological Survey,Changsha 410011,China);Li Chang’an Quaternary Tectonic-Sedimentary Characteristics and Environmental Evolution of Anxiang Sag in Dongting Basin and Its West Periphery(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,32(2),2010,p.120-129,6 illus.,1 table,48 refs.)Key words:Quaternary,sedimentary environment,structural evolution,Dongtinghu Basin Detailed geologic mapping and bore data was conducted to study on the Quaternary tectonic and sedimentary characteristics and environmental evolution of Anxiang Sag and its west periphery of Dongting Basin,which provided new materials for Quaternary geology of Jianghan-Dongting Basin.The sag trends north-south direction and is surrounded by normal faults.The thickness of Quaternary deposits in the sag is commonly 100~220 m with maximun thickness of 300 m,and from lower to upper,the Quaternary strata is composed of Early Pleistocene Huatian Formation and Miluo Formation,Middle Pleistocene Dongtinghu Formation

  13. Uranium-series ages of corals, sea level history, and palaeozoogeography, Canary Islands, Spain: an exploratory study for two Quaternary interglacial periods

    Science.gov (United States)

    Muhs, Daniel R.; Meco, Joaquín; Simmons, Kathleen R.

    2014-01-01

    We present the first U-series ages of corals from emergent marine deposits on the Canary Islands. Deposits at + 20 m are 481 ± 39 ka, possibly correlative to marine isotope stage (or MIS) 11, while those at + 12 and + 8 m are 120.5 ± 0.8 ka and 130.2 ± 0.8 ka, respectively, correlative to MIS 5.5. The age, elevations, and uplift rates derived from MIS 5.5 deposits on the Canary Islands allow calculations of hypothetical palaeo-sea levels during the MIS 11 high sea stand. Estimates indicate that the MIS 11 high sea stand likely was at least + 9 m (relative to present sea level) and could have been as high as + 24 m. The most conservative estimates of palaeo-sea level during MIS 11 would require an ice mass loss equivalent to all of the modern Greenland and West Antarctic ice sheets; the more extreme estimates would require additional ice mass loss from the East Antarctic ice sheet. Extralimital southern species of mollusks, found in both MIS 11 and MIS 5.5 deposits on the Canary Islands, imply warmer-than-modern sea surface temperatures during at least a part of MIS 11 and much warmer sea surface temperatures during at least a part of MIS 5.5. Both MIS 11 and MIS 5.5 marine deposits on the Canary Islands contain extralimital northern species of mollusks as well, indicating cooler-than-present waters at times during these interglacial periods. We hypothesize that the co-occurrence of extralimital southern and northern species of marine invertebrates in the fossil record of the Canary Islands reflects its geographic location with respect to major synoptic-scale controls on climate and ocean currents. Previous interglacials may have been characterized by early, insolation-forced warming, along with northward migration of the intertropical convergence zone (ITCZ), accompanied by weakened trade winds and diminished upwelling. This allowed the arrival of extralimital southern taxa from the tropical Senegalese faunal province. During later parts of the MIS 11 and 5

  14. Second Quaternary dating workshop

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    The second Quaternary dating methods workshop was held at Lucas Heights and sponsored by ANSTO and AINSE. Topics covered include, isotope and thermoluminescence dating, usage of accelerator and thermal ionisation mass spectrometry in environmental studies emphasizing on the methodologies used and sample preparation

  15. Extensive Quaternary glaciations in eastern Turkey

    Science.gov (United States)

    Yeşilyurt, Serdar; Akçar, Naki; Doǧan, Uǧur; Yavuz, Vural; Ivy-Ochs, Susan; Vockenhuber, Christof; Schlunegger, Fritz; Schlüchter, Christian

    2016-04-01

    During cold periods in the Quaternary, global ice volume increased and as a result valley glaciers advanced and the vice versa occurred during the warm periods. Quaternary glacier fluctuations had been also recorded in the Turkish mountains. Recently, the chronology of Late Quaternary advances in the northern and western Turkish mountains was reconstructed by surface exposure dating. However, these advances in the eastern Turkey are not dated yet. In this study, we investigated paleoglaciations in Kavuşşahap Mountains, which is located to the south of Lake Van in eastern Turkey. These mountains are one of the extensively glaciated areas in Turkey. Glacial activity is evidenced by more than 20 U-shaped valleys. For instance, one of the prominent and well-preserved glacial landscapes of Turkey is situated in the Narlıca valley system. Lateral and terminal moraines in the valley system indicate more than 10 glacial advances. To build their chronology, 39 erratic carbonaceous boulders were sampled for surface exposure dating with cosmogenic 36Cl. We also reconstructed the ice margin reconstruction of the Narlıca paleoglacier using the accumulation area ratio and area-altitude balance ratio approaches. We estimated an equilibrium line altitude (ELA) of ca. 2900 m above sea level based on the maximum ice extend, which implied ca. 800 m decrease in the ELA during the Late Quaternary in comparison to the lower bound of the modern ELA estimate. The first results of the surface exposure dating will be presented.

  16. QUATERNARY GEOLOGY & GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    <正>20050939 An Chengbang (Key Lab. of Western Chinese Environment System, Ministry of Education, Lanzhou University, Lanzhou, Gansu 730000, China); Feng Zhaodong Humid Climate During 9-3. 8 KaBP in the Western Part of Chinese Loess Plateau (Marine Geology & Quaternary Geology, ISSN0256-1492, CN37-1117/P, 24 (3), 2004, p. 111-116, 3 illus. , 1 table, 40 refs. , with English abstract)

  17. Partitioning the Quaternary

    Science.gov (United States)

    Gibbard, Philip L.; Lewin, John

    2016-11-01

    We review the historical purposes and procedures for stratigraphical division and naming within the Quaternary, and summarize the current requirements for formal partitioning through the International Commission on Stratigraphy (ICS). A raft of new data and evidence has impacted traditional approaches: quasi-continuous records from ocean sediments and ice cores, new numerical dating techniques, and alternative macro-models, such as those provided through Sequence Stratigraphy and Earth-System Science. The practical usefulness of division remains, but there is now greater appreciation of complex Quaternary detail and the modelling of time continua, the latter also extending into the future. There are problems both of commission (what is done, but could be done better) and of omission (what gets left out) in partitioning the Quaternary. These include the challenge set by the use of unconformities as stage boundaries, how to deal with multiphase records in ocean and terrestrial sediments, what happened at the 'Early-Mid- (Middle) Pleistocene Transition', dealing with trends that cross phase boundaries, and the current controversial focus on how to subdivide the Holocene and formally define an 'Anthropocene'.

  18. Cyanines Bearing Quaternary Azaaromatic Moieties

    OpenAIRE

    Sbliwa, Wanda; Matusiak, Grazyna; Bachowska, Barbara

    2006-01-01

    Selected cyanines bearing quaternary azaaromatic moieties are presented, showing their monomers, dimers and polymers, as well as their possible applications. Cyanines having NLO properties are also briefly described.

  19. Comparative analyses of quaternary arrangements in homo-oligomeric proteins in superfamilies: Functional implications.

    Science.gov (United States)

    Sudha, Govindarajan; Srinivasan, Narayanaswamy

    2016-09-01

    A comprehensive analysis of the quaternary features of distantly related homo-oligomeric proteins is the focus of the current study. This study has been performed at the levels of quaternary state, symmetry, and quaternary structure. Quaternary state and quaternary structure refers to the number of subunits and spatial arrangements of subunits, respectively. Using a large dataset of available 3D structures of biologically relevant assemblies, we show that only 53% of the distantly related homo-oligomeric proteins have the same quaternary state. Considering these homologous homo-oligomers with the same quaternary state, conservation of quaternary structures is observed only in 38% of the pairs. In 36% of the pairs of distantly related homo-oligomers with different quaternary states the larger assembly in a pair shows high structural similarity with the entire quaternary structure of the related protein with lower quaternary state and it is referred as "Russian doll effect." The differences in quaternary state and structure have been suggested to contribute to the functional diversity. Detailed investigations show that even though the gross functions of many distantly related homo-oligomers are the same, finer level differences in molecular functions are manifested by differences in quaternary states and structures. Comparison of structures of biological assemblies in distantly and closely related homo-oligomeric proteins throughout the study differentiates the effects of sequence divergence on the quaternary structures and function. Knowledge inferred from this study can provide insights for improved protein structure classification and function prediction of homo-oligomers. Proteins 2016; 84:1190-1202. © 2016 Wiley Periodicals, Inc.

  20. Quaternary Tipping Points in Tropical Northern Australia

    Science.gov (United States)

    Moss, Patrick; Dunbar, Gavin; Croke, Jacky; Katunar, Rosie

    2016-04-01

    Tropical northern Queensland, particularly the volcanic Atherton Tableland, contains some of the most detailed and longest terrestrial palaeoenvironmental archives in Australia and when combined with adjacent marine sediment records provides key insight into potential environmental 'tipping points' for the entire Quaternary period and beyond. This presentation will provide an overview of some of the key tipping points (i.e. significant landscape transformation) that have occurred within the tropical northern Australian region over the Quaternary, as well as discussing potential causes and subsequent impacts of these transformation episodes. These events include the development of the Great Barrier Reef, transition from obliquity to eccentricity dominated glacial-interglacial cycles, the Mid-Brunhes event, the Oxygen Isotope Stage 6 episode, the arrival of people into the region, Last Glacial-Interglacial Transition and European settlement.

  1. Late Quaternary changes in climate

    Energy Technology Data Exchange (ETDEWEB)

    Holmgren, K.; Karlen, W. [Stockholm Univ. (Sweden). Dept. of Physical Geography

    1998-12-01

    This review concerns the Quaternary climate with an emphasis on the last 200 000 years. The present state of art in this field is described and evaluated. The review builds on a thorough examination of classic and recent literature. General as well as detailed patterns in climate are described and the forcing factors and feed-back effects are discussed. Changes in climate occur on all time-scales. During more than 90% of the Quaternary period earth has experienced vast ice sheets, i.e. glaciations have been more normal for the period than the warm interglacial conditions we face today. Major changes in climate, such as the 100 000 years glacial/interglacial cycle, are forced by the Milankovitch three astronomical cycles. Because the cycles have different length climate changes on earth do not follow a simple pattern and it is not possible to find perfect analogues of a certain period in the geological record. Recent discoveries include the observation that major changes in climate seem to occur at the same time on both hemispheres, although the astronomical theory implies a time-lag between latitudes. This probably reflects the influence of feed-back effects within the climate system. Another recent finding of importance is the rapid fluctuations that seem to be a normal process. When earth warmed after the last glaciation temperature jumps of up to 10 deg C occurred within less than a decade and precipitation more than doubled within the same time. The forcing factors behind these rapid fluctuations are not well understood but are believed to be a result of major re-organisations in the oceanic circulation. Realizing that nature, on its own, can cause rapid climate changes of this magnitude put some perspective on the anthropogenic global warming debate, where it is believed that the release of greenhouse gases will result in a global warming of a few C. To understand the forcing behind natural rapid climate changes appears as important as to understand the role

  2. Magnetism of quaternary sediments

    Science.gov (United States)

    Heller, Friedrich

    Magnetism of Quaternary sediments was the topic of a well-attended symposium held during the 13th INQUA (International Union of Quaternary Research) congress in Beijing, China, August 2-9. More than 40 papers were delivered by scientists from Belgium, England, France, Germany, Japan, New Zealand, Sweden, Switzerland, Taiwan, the United States, the Soviet Union, Yugoslavia, and other countries. The host country contributed to a productive session that was part of the first large scientific meeting to take place in Beijing after the June 4, 1989, upheaval.Nearly half of the studies focused on paleomagnetic and rock magnetic properties of loess in Alaska, Central Asia, China, and New Zealand. Magnetostratigraphic polarity dating was done at some sections in the western (Shaw et al.) and central Chinese loess plateau (Bai and Hus; Wang and Evans; Yue). The interpretation of the polarity pattern found in the western loess plateau still is not unambiguous. In the central part, certain polarity boundaries, such as the Brunhes/Matuyama (B/M) boundary, are found in slightly different stratigraphic positions (Hus et al.; Yue). In deep-sea sediments the lock-in depth of natural remanent magnetization (NRM) at the B/M boundary seems to be a linear function of sedimentation rate (de Menocal et al.). Although the magnetization process in the Chinese loess is not well understood, detailed records of polarity transitions have been reported for the B/M and the Jaramillo R→N transition (Ma et al.; Rolph).

  3. Origin of Quaternary Red Clay of Southern Anhui Province

    Institute of Scientific and Technical Information of China (English)

    HUXUEFENG; YUANGUODONG; 等

    1998-01-01

    The particle-size distribution,heavy mineral constituents and rare earth elements(REE) characteristics of the Quaternary red clay of southern Anhui Province were studied to explore the origin of the clay.The results showed that the clay had some properties of areolian deposits,which could be compared with,those of the loess in North China ;and its chondrite-normalized curves of REE were similar to those of the Xiashu loess implying tha they shared the same orighin.It was concluded in combination with the results rported by other researchers that the Quaternary red clay of southern Anhui Province originated from aolian deposts, and this could reveal the cycles of warm and cold climates in the area during the Quaternary period.

  4. Proposal to redefine the Quaternary

    Institute of Scientific and Technical Information of China (English)

    BradPillans

    2004-01-01

    The following proposal has been circulated, via the Executive of the International Union for Quaternary Research (INQUA), to all INQUA members for discussion. It also appears on the ICS web site (www.stratigraphy.org). Comments may be sent to John Clague, President of INQUA (jclague@sfu.ca), and Brad Pillans(brad.pillans@anu.edu.au).

  5. Late Quaternary climate change shapes island biodiversity.

    Science.gov (United States)

    Weigelt, Patrick; Steinbauer, Manuel Jonas; Cabral, Juliano Sarmento; Kreft, Holger

    2016-04-07

    Island biogeographical models consider islands either as geologically static with biodiversity resulting from ecologically neutral immigration-extinction dynamics, or as geologically dynamic with biodiversity resulting from immigration-speciation-extinction dynamics influenced by changes in island characteristics over millions of years. Present climate and spatial arrangement of islands, however, are rather exceptional compared to most of the Late Quaternary, which is characterized by recurrent cooler and drier glacial periods. These climatic oscillations over short geological timescales strongly affected sea levels and caused massive changes in island area, isolation and connectivity, orders of magnitude faster than the geological processes of island formation, subsidence and erosion considered in island theory. Consequences of these oscillations for present biodiversity remain unassessed. Here we analyse the effects of present and Last Glacial Maximum (LGM) island area, isolation, elevation and climate on key components of angiosperm diversity on islands worldwide. We find that post-LGM changes in island characteristics, especially in area, have left a strong imprint on present diversity of endemic species. Specifically, the number and proportion of endemic species today is significantly higher on islands that were larger during the LGM. Native species richness, in turn, is mostly determined by present island characteristics. We conclude that an appreciation of Late Quaternary environmental change is essential to understand patterns of island endemism and its underlying evolutionary dynamics.

  6. QUATERNARY GEOLOGY& GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    20160466Cao Fugen(No.1Geological Survey Team,Xinjiang Bureau of Geology and Mineral Resources and Development,Urumqi830013,China);Zhao Shuming Geological Characteristics and Significance of the Nanhua Period Tillite from Northern Yamansu Area in Eastern Tianshan,Xinjiang(Xinjiang Geology,ISSN1000-8845,CN65-1092/P,33

  7. Synthesis of Chitosan Quaternary Ammonium Salts

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A series of N-alkyl or N-aryl chitosan quaternary ammonium salts were prepared via Schiffs base intermediates. Quaternization of N-substituted chitosan derivatives was carried out using methyl iodide to produce water-soluble cationic chitosan quaternary ammonium salt. The products were characterized by IR, 1HNMR and elemental analysis. The degree of substitution of chitosan quaternary ammonium salt was calculated by elemental analysis.

  8. Novel Quaternary Quantum Decoder, Multiplexer and Demultiplexer Circuits

    Science.gov (United States)

    Haghparast, Majid; Monfared, Asma Taheri

    2017-05-01

    Multiple valued logic is a promising approach to reduce the width of the reversible or quantum circuits, moreover, quaternary logic is considered as being a good choice for future quantum computing technology hence it is very suitable for the encoded realization of binary logic functions through its grouping of 2-bits together into quaternary values. The Quaternary decoder, multiplexer, and demultiplexer are essential units of quaternary digital systems. In this paper, we have initially designed a quantum realization of the quaternary decoder circuit using quaternary 1-qudit gates and quaternary Muthukrishnan-Stroud gates. Then we have presented quantum realization of quaternary multiplexer and demultiplexer circuits using the constructed quaternary decoder circuit and quaternary controlled Feynman gates. The suggested circuits in this paper have a lower quantum cost and hardware complexity than the existing designs that are currently used in quaternary digital systems. All the scales applied in this paper are based on Nanometric area.

  9. Novel Quaternary Quantum Decoder, Multiplexer and Demultiplexer Circuits

    Science.gov (United States)

    Haghparast, Majid; Monfared, Asma Taheri

    2017-02-01

    Multiple valued logic is a promising approach to reduce the width of the reversible or quantum circuits, moreover, quaternary logic is considered as being a good choice for future quantum computing technology hence it is very suitable for the encoded realization of binary logic functions through its grouping of 2-bits together into quaternary values. The Quaternary decoder, multiplexer, and demultiplexer are essential units of quaternary digital systems. In this paper, we have initially designed a quantum realization of the quaternary decoder circuit using quaternary 1-qudit gates and quaternary Muthukrishnan-Stroud gates. Then we have presented quantum realization of quaternary multiplexer and demultiplexer circuits using the constructed quaternary decoder circuit and quaternary controlled Feynman gates. The suggested circuits in this paper have a lower quantum cost and hardware complexity than the existing designs that are currently used in quaternary digital systems. All the scales applied in this paper are based on Nanometric area.

  10. Shift in detrital sedimentation in the eastern Bay of Bengal during the late Quaternary

    Digital Repository Service at National Institute of Oceanography (India)

    PrakashBabu, C.; Pattan, J.N.; Dutta, K.; Basavaiah, N.; Prasad, G.V.K.; Ray, D.K.; Govil, P.

    the late Quaternary period. Units 2 (43-24 cm) and 1 (24-0 cm) represent enhanced and reduced supply of coarse-grained detrital sediments from the Ganges River during early and late Holocene period, respectively. Increased terrigenous supply dilutes calcium...

  11. A Quaternary Geomagnetic Instability Time Scale

    Science.gov (United States)

    Singer, B. S.

    2013-12-01

    . Rather, during the Quaternary period, they occur nearly three times as often as full polarity reversals. I will address analytical issues, including the size and consistency of system blanks, that have led to the recognition of minor (1%) discrepencies between the 40Ar/39Ar age for a particular reversal or excursion and the best astrochronologic estimates from ODP sediment cores. For example, re-analysis of lava flows from Haleakala volcano, Maui that record in detail the Matuyama-Brunhes polarity reversal have been undertaken with blanks an order of magntitude smaller and more stable than was common a decade ago. Using the modern astrochronologic calibration of 28.201 Ma for the age of the Fish Canyon sanidine standard, results thus far yield an 40Ar/39Ar age of 772 × 11 ka for the reversal that is identical to the most precise and accurate astrochronologic age of 773 × 2 ka for this reversal from ODP cores. Similarly, new dating of sanidine in the Cerro Santa Rosa I rhyolite dome, New Mexico reveals an age of 932 × 5 ka for the excursion it records, in perfect agreement with astrochronologically dated ODP core records. Work underway aims at refining the 40Ar/39Ar ages that underpin the entire GITS by further eliminating the bias between the radioisotopic and astrochronologically determined ages for several reversals and excursions.

  12. Quaternary geology of the Channeled Scabland and adjacent areas

    Science.gov (United States)

    Baker, V. R.

    1978-01-01

    The quaternary history of the channeled scabland is characterized by discrete episodes of catastrophic flooding and prolonged periods of loess accumulation and soil formation. The loess sequence was correlated with Richmond's Rocky Mountain glacial chronology. At least five major catastrophic flood events occurred in the general vicinity of the channeled scabland. The earliest episode occurred prior to the extensive deposition of the Palouse formation. The last major episode of flooding occurred between about 18,000 and 13,000 years ago. It probably consisted of two outbursts from glacial Lake Missoula.

  13. PRN 88-2: Clustering of Quaternary Ammonium Compounds

    Science.gov (United States)

    This Notice announces that EPA has clustered the Quaternary Ammonium Compounds into four groups for the purpose of testing chemicals to build a database that will support continued registration of the entire family of quaternary ammonium compounds

  14. PROGRESS IN QUATERNARY AEOLIAN ENVIRONMENT RESEARCH

    Institute of Scientific and Technical Information of China (English)

    LU Rui-jie; CHEN Yuan; HASI Eerdun; YUE Xing-ling

    2005-01-01

    Quaternary aeolian environment researches were mainly conducted by analyzing the information carri-ers, extracting valuable evidences about aeolian environment changes, so to presume and reconstruct paleoenviron-ments. This paper formulated progress in Quaternary aeolian environment research using dune-morphological records,sedimentological records and bio-fossils records, as well as advances about chronology; presented that people shouldpay more attention to further synthetic study of multi-types of records including dune morphology, size, formationtime, sediment supply, and their relations with wind regime in future, especially the research on dating method.

  15. Catalytic enantioselective synthesis of quaternary carbon stereocentres

    Science.gov (United States)

    Quasdorf, Kyle W.; Overman, Larry E.

    2014-12-01

    Quaternary carbon stereocentres--carbon atoms to which four distinct carbon substituents are attached--are common features of molecules found in nature. However, before recent advances in chemical catalysis, there were few methods of constructing single stereoisomers of this important structural motif. Here we discuss the many catalytic enantioselective reactions developed during the past decade for the synthesis of single stereoisomers of such organic molecules. This progress now makes it possible to incorporate quaternary stereocentres selectively in many organic molecules that are useful in medicine, agriculture and potentially other areas such as flavouring, fragrances and materials.

  16. Climate predictors of late quaternary extinctions

    DEFF Research Database (Denmark)

    Nogués-Bravo, David; Ohlemüller, Ralf; Batra, Persaram

    2010-01-01

    Between 50,000 and 3,000 years before present (BP) 65% of mammal genera weighing over 44 kg went extinct, together with a lower proportion of small mammals. Why species went extinct in such large numbers is hotly debated. One of the arguments proposes that climate changes underlie Late Quaternary...... extinctions, but global quantitative evidence for this hypothesis is still lacking. We test the potential role of global climate change on the extinction of mammals during the Late Quaternary. Our results suggest that continents with the highest climate footprint values, in other words, with climate changes...

  17. 21 CFR 172.165 - Quaternary ammonium chloride combination.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Quaternary ammonium chloride combination. 172.165... HUMAN CONSUMPTION Food Preservatives § 172.165 Quaternary ammonium chloride combination. The food additive, quaternary ammonium chloride combination, may be safely used in food in accordance with...

  18. Palladium-Catalyzed Asymmetric Quaternary Stereocenter Formation

    NARCIS (Netherlands)

    Gottumukkala, Aditya L.; Matcha, Kiran; Lutz, Martin; de Vries, Johannes G.; Minnaard, Adriaan J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of beta,beta-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and pr

  19. Palladium-catalyzed asymmetric quaternary stereocenter formation

    NARCIS (Netherlands)

    Gottumukkala, A.L.; Matcha, K.; Lutz, M.; de Vries, J.G.; Minnaard, A.J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of β,β-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and provides

  20. Palladium-catalyzed asymmetric quaternary stereocenter formation

    NARCIS (Netherlands)

    Gottumukkala, A.L.; Matcha, K.; Lutz, M.|info:eu-repo/dai/nl/304828971; de Vries, J.G.; Minnaard, A.J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of β,β-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and provides

  1. Palladium-Catalyzed Asymmetric Quaternary Stereocenter Formation

    NARCIS (Netherlands)

    Gottumukkala, Aditya L.; Matcha, Kiran; Lutz, Martin; de Vries, Johannes G.; Minnaard, Adriaan J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of beta,beta-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and pr

  2. Geomorphology and Quaternary geology of the Dakhla Oasis Region, Egypt

    Science.gov (United States)

    Brookes, Ian A.

    Dakhla Oasis (25.5°N, 29°E) occupies a structurally localized depression at 90-140 m above sea level, ˜1200 km 2 in area, below a 300 m escarpment bordering the Libyan Plateau, Western Desert of Egypt. Semi-arid intervals of the Quaternary period generated eight sedimentary formations, separated by erosion during hyper-arid intervals. Sediments comprise three generations of colluvial/fluvial fanglomerates, two generations of tabular spring-laid clastic and chemical sediments, two generations of mound springs and basinal sediments. of fluvio-lacustrine, evaporitic, pluvio-aeolian and aeolian origins. Discussion of these sediments is organized according to geomorphic region, from north to south, plateau, scarp and piedmont, lowland and cuesta plain. Chronological evidence is restricted to many radiocarbon dates of Holocene cultural material associated with playa sediments (9-4.5 ka), a {Th}/{U} isochron age of ˜62.0 ±7.6 ka for basinal evaporites, and two {Th}/{U} ages of ˜176 and ˜170 ka for a boulder of derived travertine. The regional Quaternary sequence is reconstructed from stratigraphic and geomorphic relationships of the sediments and erosion surfaces. It is broadly similar to sequences earlier reconstructed in the topographically similar Kharga Oasis region 150 km to the east, and Kurkur Oasis, 400 km to the south-southeast. Speculations on chronology and driving mechanism are offered in conclusion.

  3. European quaternary refugia: a factor in large carnivore extinction?

    Science.gov (United States)

    O'Regan, Hannah J.; Turner, Alan; Wilkinson, David M.

    2002-12-01

    The extinction of large carnivores in Europe during the Quaternary is reviewed and the potential role of glacial refugia in these extinctions is investigated using the VORTEX model for population viability analysis. A model was built for a medium sized big cat similar to the extinct Panthera gombaszoegensis utilising life history data from the modern jaguar Panthera onca. This approach highlighted the potential importance of glacial refugia in the extinction process. Even model refugia the size of the Italian peninsula did not guarantee persistence of a population over a 1000 yr time span, illustrating the role of chance in survival in such a refugium. An area the size of the largest Mediterranean island was unable to support a big cat population for a period of 1000 yr. The models also demonstrated the importance of inbreeding as a mechanism for extinction in refugia. It is suggested that repeated genetic bottlenecks during successive glaciations would tend to remove lethal recessive alleles from the population, increasing the probability of survival in refugia in subsequent glaciations. The history of extinction of large carnivores in the European Quaternary is interpreted in the light of these results.

  4. [Quaternary prevention: containment as an ethical necessity].

    Science.gov (United States)

    Martínez González, C; Riaño Galán, I; Sánchez Jacob, M; González de Dios, J

    2014-12-01

    The growing capacity of medicine to generate more iatrogenic events than ever, and the risk of unsustainability of health systems have led to new prevention concept: quaternary prevention aimed at restraining medicalization. Quaternary prevention is essential in the phenomenon called disease mongering, which could be translated as commercialization of disease. Encouraging this sort of prevention and halting the consequences of disease mongering requires the development of all the institutional potential for prevention, as well as all the personal willingness for restraint; it involves separating us from the unnecessary auspices of industry, being critical of our work, not being maleficent, respecting the principle of justice as managers of the limited public resources and making ourselves feel responsible for the social cost resulting from medical decisions. From this point of view, this work analyses neonatal screening, developments in the area of neonatology and primary health care.

  5. Efficient cellulose solvent: quaternary ammonium chlorides.

    Science.gov (United States)

    Kostag, Marc; Liebert, Tim; El Seoud, Omar A; Heinze, Thomas

    2013-10-01

    Pure quaternary tetraalkylammonium chlorides with one long alkyl chain dissolved in various organic solvents constitute a new class of cellulose solvents. The electrolytes are prepared in high yields and purity by Menshutkin quaternization, an inexpensive and easy synthesis route. The pure molten tetraalkylammonium chlorides dissolve up to 15 wt% of cellulose. Cosolvents, including N,N-dimethylacetamide (DMA), may be added in large excess, leading to a system of decreased viscosity. Contrary to the well-established solvent DMA/LiCl, cellulose dissolves in DMA/quaternary ammonium chlorides without any pretreatment. Thus, the use of the new solvent avoids some disadvantages of DMA/LiCl and ionic liquids, the most extensively employed solvents for homogeneous cellulose chemistry.

  6. The influence of climate on species distribution over time and space during the late Quaternary

    Science.gov (United States)

    Carotenuto, F.; Di Febbraro, M.; Melchionna, M.; Castiglione, S.; Saggese, F.; Serio, C.; Mondanaro, A.; Passaro, F.; Loy, A.; Raia, P.

    2016-10-01

    Understanding the effect of climate on the composition of communities and its change over time and space is one of the major aims in ecology and paleoecology. Herein, we tackled on this issue by studying late Quaternary large mammal paleocommunities of Eurasia. The late Quaternary was a period of strong environmental instability, especially characterized by the occurrence of the last glacial maximum (LGM). We used community phylogenetics and joint species distribution models in order to understand the factors determining paleocommunity composition in the late Quaternary. Our results support the existence of strong climatic selection operating on the LGM fauna, both through the disappearance of warm-adapted species such as Elephas antiquus, Hippopothamus amphibious, and Stephanorhinus hemitoechus, and by setting the stage for the existence of a community characterized by cold-adapted large mammals. Patterns of abundance in the fossil record, co-occurrence between species pairs, and the extent of climatic forcing on faunal composition, differ between paleocommunities, but not between extinct and extant species, which is consistent with the idea that climate change, rather than the presence of humans, exerted a major effect on the survival of the late Quaternary megafauna.

  7. PCA for predicting quaternary structure of protein

    Institute of Scientific and Technical Information of China (English)

    Tong WANG; Hongbin SHEN; Lixiu YAO; Jie YANG; Kuochen CHOU

    2008-01-01

    The number and arrangement of subunits that form a protein are referred to as quaternary structure. Knowing the quaternary structure of an uncharacterized protein provides clues to finding its biological function and interaction process with other molecules in a biological system. With the explosion of protein sequences generated in the Post-Genomic Age, it is vital to develop an automated method to deal with such a challenge. To explore this prob-lem, we adopted an approach based on the pseudo position-specific score matrix (Pse-PSSM) descriptor, proposed by Chou and Shen, representing a protein sample. The Pse-PSSM descriptor is advantageous in that it can combine the evolution information and sequence-correlated informa-tion. However, incorporating all these effects into a descriptor may cause 'high dimension disaster'. To over-come such a problem, the fusion approach was adopted by Chou and Shen. A completely different approach, linear dimensionality reduction algorithm principal component analysis (PCA) is introduced to extract key features from the high-dimensional Pse-PSSM space. The obtained dimension-reduced descriptor vector is a compact repre-sentation of the original high dimensional vector. The jack-knife test results indicate that the dimensionality reduction approach is efficient in coping with complicated problems in biological systems, such as predicting the quaternary struc-ture of proteins.

  8. Synthesis of novel quaternary ammonium surfactants containing adamantane

    Institute of Scientific and Technical Information of China (English)

    Jian Wei Guo; Xing Zhong; Hua Zhu; Li Juan Feng; Ying De Cui

    2012-01-01

    A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamantanecarboxylic acid.The structures of target surfactants were confirmed by 1H NMR,elements analysis and FTIR.Surface properties of these surfactants were investigated.Due to the lipophilicity of adamantane,the critical micelle concentration (CMC) and C20 values of the synthesized quaternary ammonium surfactants are lower than that of conventional quaternary ammonium surfactants.

  9. Quaternary history and contemporary patterns in a currently expanding species

    Science.gov (United States)

    Kerdelhué, Carole; Zane, Lorenzo; Simonato, Mauro; Salvato, Paola; Rousselet, Jérôme; Roques, Alain; Battisti, Andrea

    2009-01-01

    Background Quaternary climatic oscillations had dramatic effects on species evolution. In northern latitudes, populations had to survive the coldest periods in refugial areas and recurrently colonized northern regions during interglacials. Such a history usually results in a loss of genetic diversity. Populations that did not experience glaciations, in contrast, probably maintained most of their ancestral genetic diversity. These characteristics dramatically affected the present-day distribution of genetic diversity and may influence the ability of species to cope with the current global changes. We conducted a range-wide study of mitochondrial genetic diversity in the pine processionary moth (Thaumetopoea pityocampa/T. wilkinsoni complex, Notodontidae), a forest pest occurring around the Mediterranean Basin and in southern Europe. This species is responding to the current climate change by rapid natural range expansion and can also be accidentally transported by humans. Our aim was to assess if Quaternary climatic oscillations had a different effect across the species' range and to determine if genetic footprints of contemporary processes can be identified in areas of recent introduction. Results We identified three main clades that were spatially structured. In most of Europe, the genetic diversity pattern was typical for species that experienced marked glaciation cycles. Except in refugia, European populations were characterized by the occurrence of one main haplotype and by a strong reduction in genetic diversity, which is expected in regions that were rapidly re-colonized when climatic conditions improved. In contrast, all other sub-clades around the Mediterranean Basin occurred in limited parts of the range and were strongly structured in space, as is expected in regions in which the impact of glaciations was limited. In such places, genetic diversity was retained in most populations, and almost all haplotypes were endemic. This pattern was extreme on remote

  10. Quaternary history and contemporary patterns in a currently expanding species

    Directory of Open Access Journals (Sweden)

    Rousselet Jérôme

    2009-09-01

    Full Text Available Abstract Background Quaternary climatic oscillations had dramatic effects on species evolution. In northern latitudes, populations had to survive the coldest periods in refugial areas and recurrently colonized northern regions during interglacials. Such a history usually results in a loss of genetic diversity. Populations that did not experience glaciations, in contrast, probably maintained most of their ancestral genetic diversity. These characteristics dramatically affected the present-day distribution of genetic diversity and may influence the ability of species to cope with the current global changes. We conducted a range-wide study of mitochondrial genetic diversity in the pine processionary moth (Thaumetopoea pityocampa/T. wilkinsoni complex, Notodontidae, a forest pest occurring around the Mediterranean Basin and in southern Europe. This species is responding to the current climate change by rapid natural range expansion and can also be accidentally transported by humans. Our aim was to assess if Quaternary climatic oscillations had a different effect across the species' range and to determine if genetic footprints of contemporary processes can be identified in areas of recent introduction. Results We identified three main clades that were spatially structured. In most of Europe, the genetic diversity pattern was typical for species that experienced marked glaciation cycles. Except in refugia, European populations were characterized by the occurrence of one main haplotype and by a strong reduction in genetic diversity, which is expected in regions that were rapidly re-colonized when climatic conditions improved. In contrast, all other sub-clades around the Mediterranean Basin occurred in limited parts of the range and were strongly structured in space, as is expected in regions in which the impact of glaciations was limited. In such places, genetic diversity was retained in most populations, and almost all haplotypes were endemic. This

  11. Monsoon triggered formation of Quaternary alluvial megafans in the interior of Oman

    Science.gov (United States)

    Blechschmidt, Ingo; Matter, Albert; Preusser, Frank; Rieke-Zapp, Dirk

    2009-09-01

    A vast bajada consisting of coalescing low-gradient (veneer of weakly cemented Quaternary gravels. A combination of remote sensing, lithological analyses and luminescence dating is used to interpret the complex aggradation history of the Quaternary alluvial fans from the interior of Oman in the context of independent regional climate records. From satellite imagery and clast analysis four fans can be discerned in the study area. While two early periods of fan formation are tentatively correlated to the Miocene-Pliocene and the Early Pleistocene, luminescence dating allows the distinction of five phases of fan aggradation during the Middle-Late Pleistocene. These phases are correlated with pluvial periods from Marine Isotope Stage (MIS) 11 through 3, when southern Arabia was affected by monsoonal precipitation. It is concluded that the aggradation of the alluvial fans was triggered by the interplay of increased sediment production during arid periods and high rainfall with enhanced erosion of hillslopes and transport rates during strong monsoon phases. However, the lack of fine-grained sediments, bioturbation and organic material implies that although the Quaternary fans are sourced by monsoonal rains they formed in a semi-arid environment. Thus, it appears that, in contrast to the Oman Mountains, the interior was not directly affected by monsoonal precipitation.

  12. Palladium-catalyzed asymmetric quaternary stereocenter formation.

    Science.gov (United States)

    Gottumukkala, Aditya L; Matcha, Kiran; Lutz, Martin; de Vries, Johannes G; Minnaard, Adriaan J

    2012-05-29

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of β,β-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl(2), PhBOX, and AgSbF(6), and provides products in up to 99% enantiomeric excess, with good yields. Based on this strategy, (-)-α-cuparenone has been prepared in only two steps. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. THE BINARY IMAGE OF THE DUAL OF QUATERNARY GOETHALS CODE

    Institute of Scientific and Technical Information of China (English)

    崔杰

    2002-01-01

    The 2-adic representations of codewords of the dual of quaternary Goethals code are given. By the 2-adic representations, the binary image of the dual of quaternary Goethals code under the Gray map is proved to be the nonlinear code constructed by Goethals in 1976.

  14. Paleoenvironmental changes during the late Quaternary as inferred from foraminifera assemblages in the Laizhou Bay

    Institute of Scientific and Technical Information of China (English)

    YAO Jing; YU Hongjun; XU Xingyong; YI Liang; CHEN Guangquan; SU Qiao

    2014-01-01

    Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exists about the time when the transgressions occurred separately. In order to find out the process of the paleoenvironmental changes around the Bohai Sea in the late Quaternary, the foraminifera assemblages from a new borehole Lz908 in the southern coast of the Laizhou Bay were studied, and then the transgressive strata were indentified. Combined with accelerator mass spectrometry radiocarbon 14C (AMS14C) and opti-cally stimulated luminescence (OSL) ages, the occurrence time of these transgressions were re-determined. The result showed that three major large-scale transgressions occurred separately at the beginning of ma-rine isotopic stage 7 (MIS7), the last interglacial period (MIS5) and the Holocene. In addition, a small-scale transgression occurred in the mid-MIS6, and the corresponding transgressive stratum was deposited. The transgressive deposition of MIS3 was also discovered in this study. However, the characteristics of the fora-minifera indicated the environment during this period was colder than that in the MIS5. By comparison with the global sea-level changes, the paleoenvironmental changes around the Bohai Sea in the late Quaternary can be consistent with the global climate changes.

  15. Quaternary geologic map of the Boston 4 degrees x 6 degrees quadrangle, United States and Canada

    Science.gov (United States)

    State compilations by Hartshorn, Joseph H.; Thompson, W.B.; Chapman, W.F.; Black, R.F.; Richmond, Gerald Martin; Grant, D.R.; Fullerton, David S.; edited and integrated by Richmond, Gerald Martin

    1991-01-01

    The Quaternary Geologic Map of the Boston 4 deg x 6 deg Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  16. Principles of assembly reveal a periodic table of protein complexes.

    Science.gov (United States)

    Ahnert, Sebastian E; Marsh, Joseph A; Hernández, Helena; Robinson, Carol V; Teichmann, Sarah A

    2015-12-11

    Structural insights into protein complexes have had a broad impact on our understanding of biological function and evolution. In this work, we sought a comprehensive understanding of the general principles underlying quaternary structure organization in protein complexes. We first examined the fundamental steps by which protein complexes can assemble, using experimental and structure-based characterization of assembly pathways. Most assembly transitions can be classified into three basic types, which can then be used to exhaustively enumerate a large set of possible quaternary structure topologies. These topologies, which include the vast majority of observed protein complex structures, enable a natural organization of protein complexes into a periodic table. On the basis of this table, we can accurately predict the expected frequencies of quaternary structure topologies, including those not yet observed. These results have important implications for quaternary structure prediction, modeling, and engineering. Copyright © 2015, American Association for the Advancement of Science.

  17. Absolute age determination of quaternary faults

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Chang Sik; Lee, Seok Hoon; Choi, Man Sik [Korea Basic Science Institute, Seoul (Korea, Republic of)] (and others)

    2000-03-15

    To constrain the age of neotectonic fault movement, Rb-Sr, K-Ar, U-series disequilibrium, C-14 and Be-10 methods were applied to the fault gouges, fracture infillings and sediments from the Malbang, Ipsil, Wonwonsa faults faults in the Ulsan fault zone, Yangsan fault in the Yeongdeog area and southeastern coastal area. Rb-Sr and K-Ar data imply that the fault movement of the Ulan fault zone initiated at around 30 Ma and preliminary dating result for the Yang san fault is around 70 Ma in the Yeongdeog area. K-Ar and U-series disequilibrium dating results for fracture infillings in the Ipsil fault are consistent with reported ESR ages. Radiocarbon ages of quaternary sediments from the Jeongjari area are discordant with stratigraphic sequence. Carbon isotope data indicate a difference of sedimentry environment for those samples. Be-10 dating results for the Suryum fault area are consistent with reported OSL results.

  18. Paleomagnetic research on Black Sea Quaternary sediments

    Science.gov (United States)

    Kalcheva, V.; Nozharov, P.; Kovacheva, M.; Shopov, V.

    1990-10-01

    The paper reports the first paleomagnetic study of a Black Sea Quaternary sediment core made by a Bulgarian research group. The experimental results show an important difference in magnetic behaviour between the samples from the Holocene part and those from the Pleistocene part of the core. Suggestions are made for the character of the remanent magnetization and the main carriers of it. The presence of greigite (Fe 3S 4) and pyrite (FeS 2) is discussed. A rough correlation is established between the variation of inclination for the Holocene part of the sediment and for the Bulgarian archeomagnetic curve. On the basis of the comparison of inclination data obtained from the Pleistocene part of the core and previously studied Black Sea core (related to the absolute time scale), it is suggested that the lower boundary of the Pleistocene part is ˜ 16000 years old (BP).

  19. Suggested terminology for Quaternary dating methods

    Science.gov (United States)

    Colman, Steven M.; Pierce, K.L.; Birkeland, P.W.

    1987-01-01

    Classification of Quaternary dating methods should be based on the level of quantitative information and the degree of confidence contained in the age estimates produced by the dating methods. We recommend the use of the terms numerical-age, calibrated-age, relative-age, and correlated-age to describe these levels. We also classify dating methods by type into sideral, isotopic, radiogenic, chemical and biological, geomorphic, and correlation methods. The use of "absolute" is inappropriate for most dating methods, and should be replaced by "numerical." The use of "date" should be minimized in favor of "age" or "age estimate." We recommend use of the abbreviations ka and Ma for most ages; calender dates can be used where appropriate and yr B.P. can be used for radiocarbon ages. ?? 1987.

  20. Quaternary ammonium compounds – New occupational hazards

    Directory of Open Access Journals (Sweden)

    Agnieszka Lipińska-Ojrzanowska

    2014-10-01

    Full Text Available Quaternary ammonium compounds (QACs, quats belong to organic ionic chemical agents which display unique properties of both surfactants and disinfectants. Their wide distribution in the work environment and also in private households brings about new occupational hazards. This paper reviews reports about the health effects of QACs. QACs could play a role of sensitizers and irritants to the skin and mucous membranes. It is suspected that particular QACs can display an immunologic crossreactivity between each other and with other chemical compounds containing ammonium ion, such as muscle relaxants widely used in anesthesia. They may promote the development of airway allergy, however, the background mechanisms are still unclear and need to be further investigated. Until now, a few cases of occupational asthma induced by QACs have been described and their involvement in contact dermatitis has been documented. The possibility of anaphylaxis due to QACs cannot be excluded as well. Med Pr 2014;65(5:675–682

  1. Biosedimentology of Quaternary stromatolites in intertropical Africa

    Science.gov (United States)

    Casanova, J.

    Mineralizations of microbial origin constitute a non-negligeable part of Quaternary limestones in intertropical Africa. Stromatolites have colonized a wide range of environments corresponding to different hydroclimatic situations: travertines in fluviatile environments, oncolites in flood plains, encrustations in sebkha areas and shorelines of deep, fresh water lakes. The developed morphologies represent a complete catalogue of the microbial carbonated mineralizations: oncolites, chemneys, pool-rim dams, biocherms, planar or cylindrical encrustations. The building organisms may be either pure bacterial colonies (hydrothermal and lacustrine environments), cyanophyte associations (fluviatile and lacustrine environments) or complex microbial biocoenoses. Stromatolites have recorded the hydrologic, climatic and sedimentologic evolution of the continental environment in intertropical Africa for the past 240 000 years.

  2. Hydration Structure of the Quaternary Ammonium Cations

    KAUST Repository

    Babiaczyk, Wojtek Iwo

    2010-11-25

    Two indicators of the hydropathicity of small solutes are introduced and tested by molecular dynamics simulations. These indicators are defined as probabilities of the orientation of water molecules\\' dipoles and hydrogen bond vectors, conditional on a generalized distance from the solute suitable for arbitrarily shaped molecules. Using conditional probabilities, it is possible to distinguish features of the distributions in close proximity of the solute. These regions contain the most significant information on the hydration structure but cannot be adequately represented by using, as is usually done, joint distance-angle probability densities. Our calculations show that using our indicators a relative hydropathicity scale for the interesting test set of the quaternary ammonium cations can be roughly determined. © 2010 American Chemical Society.

  3. Energy consumption maps for quaternary distillation sequences

    DEFF Research Database (Denmark)

    Gomez-Castro, F.I.; Ramírez-Vallejo, N.E.; Segovia-Hernandez, J.G.

    2016-01-01

    of the solutions space. For the separation of ternary mixtures, Tedder and Rudd (1978) presented a composition map for which thermally coupled systems allowed energy savings. However, the scenario is different for quaternary mixtures, since no similar information is available. Therefore, in this work, energy...... be generated for the separation of multicomponent mixtures. This fact is an advantage, since a wide portfolio of alternatives can be used to separate a specific mixture; however, this is also a disadvantage since a lot of alternatives must be explored in order to find the optimal one. The optimal configuration......, for a given mixture, depends on the nature of the mixture, usually quantified for ternary mixtures through the ease of separation index (ESI), and also on the feed composition. As can be noticed, the size of the design and optimization problem increases when these variables are considered in the generation...

  4. Late Quaternary temperature change velocity in Mesoamerica

    Science.gov (United States)

    Correa-Metrio, A.; Lozano, S.; Sosa-Nájera, S.; Bush, M. B.

    2013-05-01

    Quaternary climate has been highly variable, and yet few quantitative continental reconstructions are available for tropical areas. Quantitative records of temperature change during the Quaternary are especially relevant for putting modern climate change into a historic context. Within this perspective, two aspects are of singular relevance: i) Identifying and quantifying past climatic variability, and ii) Providing a means to estimate the seed at which climate change happened in the past. Here we show temperature reconstructions and temperature change velocity calculations for two locations in northern tropical America. Temperature reconstruction was based on two sedimentary records form Lake Chalco (30,000 years), central Mexican highlands, and Lake Petén-Itzá, Guatemalan lowlands (86,000 years). Temperature reconstruction was based on the analysis of fossil pollen on the light of pollen-temperature transfer functions. These functions were calibrated through an extensive survey of modern pollen samples covering an elevational gradient from 0 to 4,218 m asl. Derived temperature profiles show a parallel long-term trend and a similar cooling of approximately 5 oC during the Last Glacial Maximum in the lowlands and highlands of Mexico and Guatemala. Using a digital elevation model, we ere able to reconstruct the velocity at which isotherms displaced to produce the observed temperature anomalies. Spatial velocities of temperature change in the studied areas were at least four times slower than values reported for the last 50 years, but also at least twice as fast as those obtained from recent models. This study demonstrates that modern temperature change has no precedent within the last 86,000 years, but also that tropical climate has been more variable than it has been assumed to date.

  5. Human Dispersals Along the African Rift Valley in the Late Quaternary

    Science.gov (United States)

    Tryon, C. A.; Faith, J. T.; Peppe, D. J.

    2014-12-01

    Climate- and tectonic-driven environmental dynamics of the East African Rift System (EARS) during the Quaternary played an important role in the demographic history of early Homo sapiens, including expansions of modern humans across and out of Africa. Human forager population size, geographic range, and behaviors such as hunting strategies and residential mobility likely varied in response to changes in the local and regional environment. Throughout the Quaternary, floral and faunal change was linked at least in part to variations in moisture availability, temperature, and atmospheric CO2, which in addition to uplift and faulting, contributed to the expansion and contraction of a number of large lakes that served as biogeographic barriers to many taxa. This is particularly clear for the Lake Victoria basin, where biogeographic, geological, and paleontological evidence documents repeated expansion and contraction of the ranges of species in response to lake level and vegetation change. Across much of eastern Africa, the topography of the rift facilitated north-south dispersals, the timing of which may have depended in part on the expansion and contraction of the equatorial forest belt. Dispersal potential likely increased during the more arid periods of the late Quaternary, when the roles of lakes and forests as dispersal barriers was reduced and the extent of low net primary productivity dry grasslands increased, the latter requiring large home ranges for human foragers, conditions suitable for range expansions within H. sapiens.

  6. Quaternary Logic and Applications Using Multiple Quantum Well Based SWSFETs

    Directory of Open Access Journals (Sweden)

    P. Gogna

    2012-11-01

    Full Text Available This paper presents Spatial Wavefunction-Switched Field-Effect Transistors (SWSFET to implement efficient quaternary logic and arithmetic functions. Various quaternary logic gates and digital building blocks are presented using SWSFETs. In addition, arithmetic operation with full adder using novel logic algebra is also presented. The SWSFET based implementation of digital logic, cache and arithmetic block results in up to 75% reduction in transistor count and up to 50% reduction in data interconnect densities. Simulations of quaternary logic gates using the BSIM equivalent models for SWSFET channels are also described.

  7. Antimicrobial Polymeric Materials with Quaternary Ammonium and Phosphonium Salts

    Directory of Open Access Journals (Sweden)

    Yan Xue

    2015-02-01

    Full Text Available Polymeric materials containing quaternary ammonium and/or phosphonium salts have been extensively studied and applied to a variety of antimicrobial-relevant areas. With various architectures, polymeric quaternary ammonium/phosphonium salts were prepared using different approaches, exhibiting different antimicrobial activities and potential applications. This review focuses on the state of the art of antimicrobial polymers with quaternary ammonium/phosphonium salts. In particular, it discusses the structure and synthesis method, mechanisms of antimicrobial action, and the comparison of antimicrobial performance between these two kinds of polymers.

  8. The grain-size characteristics of Quaternary deposits at Xingshan near Siping in Jilin province, China

    Institute of Scientific and Technical Information of China (English)

    Maxwell A Boateng; Xikui Wang

    2006-01-01

    This research paper analyses the grain-size characteristics of the Quaternary deposits at Xingshan near Siping, Jilin province in China by employing graphic measures to study the grain size distribution and its mode of transport and deposition. The Quaternary deposits at Xingshan lie unconformable on Cretaceous rocks made of siltstone, mudstone and sandstone. The average grain size is between 8.06 to 8.55Φ (0.002 6 ~0.003 7 mm). The Quaternary deposits at Xingshan mainly compose of very fine silt to clay. The compositions of the grade are clay 63% and silt 37%. The clay size components are weathered debris transported and deposited by flowing water from the SE highlands or hills to the low lying NW Xingshan plains whereas the silty components accumulated by aoelian process. The Quaternary deposits at Xingshan accumulated in the middle and late Pleistocene interglacial periods from (459.12~39.03) ka to (88.92~7.56) ka. The standard deviation ranged from 0.96 to 1.36Φ, indicating that the sediments are moderately to poorly sorted, Coefficient of skewness ranged from 0.16~0.31 with an average skewness of 0.218, (Positively skewed towards fine). Kurtosis values (0.84~1.05) from the grain size distribution and visual inspection of the frequency curves indicate platykurtic to mesokurtic curves and unimodal to bimodal grain-size distribution. The type of deposit formation is sand dune and the source is at a distal from its provenance.

  9. Late Quaternary stratigraphic development in the lower Luni, Mahi and Sabarmati river basins, western India

    Indian Academy of Sciences (India)

    M Jain; S K Tandon; S C Bhatt

    2004-09-01

    This study reviews the Quaternary alluvial stratigraphy in three semi-arid river basins of western India i.e., lower Luni (Rajasthan), and Mahi and Sabarmati (Gujarat alluvial plains). On the basis of OSL chronologies, it is shown that the existing intra-valley lithostratigraphic correlations require a revision. The sand, gravel and mud facies are present during various times in the three basins, however, the fluvial response to climate change, and the resulting facies associations, was different in the Thar desert as compared to that at the desert margin; this makes purely lithostratigraphic correlations unviable. It is further shown that the rivers in the Thar desert were more sensitive to climate change and had small response times and geomorphic thresholds as compared to the desert-margin rivers. This is illustrated during the early OIS 1, when the Luni river in the Thar desert was dynamic and showed frequent variations in fluvial styles such as gravel bedload braided streams, sand-bed ephemeral streams and meandering streams, all followed by incision during the early Holocene. The coeval deposits in Sabarmati, however, only show a meandering, floodplain-dominated river. Late Quaternary alluvial deposits in these basins unconformably overlie some older deposits that lack any absolute chronology. Based on the facies types and their associations, and the composition and architecture of the multistoried gravel sheets in the studied sections, it is suggested that older deposits are of pre-Quaternary age. This hypothesis implies the presence of a large hiatus incorporating much of the Quaternary period in the exposed sections.

  10. Quaternary ammonium sulfanilamide: a membrane-impermeant carbonic anhydrase inhibitor

    Energy Technology Data Exchange (ETDEWEB)

    Henry, R.P.

    1987-05-01

    A novel carbonic anhydrase (CA) inhibitor, quaternary ammonium sulfanilamide (QAS), was tested for potency as a CA inhibitor and for its ability to be excluded from permeating biological membranes. Inhibitor titration plots of QAS vs. pure bovine CA II and CA from the gills of the blue crab, Callinectes sapidus, yielded K/sub i/ values of approx. 15 ..mu..M; thus QAS is a relatively weak but effective CA inhibitor. Permeability of the QAS was directly tested by two independent methods. The inhibitor was excluded from human erythrocytes incubated in 5 mM QAS for 24 h as determined using an /sup 18/O-labeled mass spectrometer CA assay for intact cells. Also QAS injected into the hemolymph of C. sapidus (1 or 10 mM) did not cross the basal membrane of the gill. The compound was cleared from the hemolymph by 96 h after injection, and at no time during that period could the QAS be detected in homogenates of gill tissue. Total branchial CA activity was only slightly reduced following the QAS injection. These data indicate that QAS is a CA inhibitor to which biological membranes are impermeable and that can be used in vivo and in vitro in the study of membrane-associated CA.

  11. Responses of Quaternary rainforest vertebrates to climate change in Australia

    Science.gov (United States)

    Hocknull, Scott A.; Zhao, Jian-xin; Feng, Yue-xing; Webb, Gregory E.

    2007-12-01

    A new middle Pleistocene vertebrate fossil record from eastern Australia, dated by U disequilibrium series, records the first Quaternary record of an Australian tropical rainforest fauna. This exceptionally rich fauna underwent extinction after a long period of relative faunal stability, spanning several glacial cycles, and persisted probably until 280 000 years ago. Some time between 280 000 and 205 000 years ago the rainforest fauna was replaced by a xeric-adapted fauna. Since that time, the xeric-adapted fauna was replaced by a mesic-adapted fauna which was established by the Holocene. This is the first vertebrate faunal evidence in Australia of the middle Pleistocene Mid-Brunhes Climatic Event (MBE), a major climatic reorganisation that led to increased aridity in northern Australia from around 300 000 years ago. Several independent palaeoclimate proxies suggest that the climatic shift to aridity was due to increased climatic variability and weakened northern monsoons, which may be manifested in the extinction of the aseasonal rainforest fauna and its replacement by an arid-adapted fauna. We extend the temporal ranges of several taxa from the Pliocene into the middle Pleistocene. We also reveal a longer palaeobiogeographic connection of rainforest taxa and lineages shared between New Guinea and Australia than was previously thought and show that their extinction on mainland Australia occurred sometime after 280 000 years ago.

  12. Quaternary Fault and Fold Database of the United States

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Quaternary Fault and Fold Database contains the results of thousands of scientific assessments of faults and associated folds in the United States that...

  13. Quaternary phosphorites off the southeast coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, V.P.; Michard, A.; Naqvi, S.W.A.; Boettcher, M.E.; Krishnaswamy, R.; Thamban, M.; Natarajan, R.; Borole, D.V.

    Detailed petrological, mineralogical, geochemical and radiogenic (U, Sr, Nd) and stable isotope (C, O, S) studies have been carried out on the Quaternary phosphorites of the continental margin off Chennai, southeast coast of India...

  14. Quaternary alluvial stratigraphy and palaeoclimatic reconstruction at the Thar margin

    DEFF Research Database (Denmark)

    Jain, M.; Tandon, S.K.

    2003-01-01

    Quaternary alluvial record at the Thar desert margin has been examined using the exposed succession along Mahudi, Sabarmati river, Western India. Different alluvial facies, their associations and granulometry have been studied for palaeoenvironmental reconstruction. Clay mineral indices smectite/...

  15. Late Quaternary record of pteropod preservation from the Andaman Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Sijinkumar, A.V.; Nath, B.N.; Guptha, M.V.S.

    . Millennial/centennial-scale thermocline ventilation changes in the Indian Ocean as reflected by aragonite preservation and geochemical variations in Arabian Sea sediments. Geochimica et Cosmochimica Acta 73, 6771–6788. Brown, B.E., 2007. Coral reefs... Quaternary millennial-scale variability in pelagic aragonite preservation off Somalia. Marine Micropaleontology 59, 171- 183. Klöcker, R., Henrich, R., 2006. Recent and Late Quaternary pteropod preservation on the Pakistan shelf and continental slope...

  16. ARE QUATERNARY AMMONIUM ANTIBACTERIALS SUITABLE FOR DENTAL COMPOSITE RESINS?

    Directory of Open Access Journals (Sweden)

    Iman MOHAMMADZADEH

    2016-06-01

    Full Text Available The objective of this study was to answer the following question: are quaternary ammonium antibacterials suitable for dental materials? Reviewing the literature on quaternary ammonium compounds evidenced that this type of compounds is soluble in water. Our own findings also showed that they are well soluble in water and that their application as dental composites requires to check their solubility level in water.

  17. Known and suggested quaternary faulting in the midcontinent United States

    Science.gov (United States)

    Wheeler, R.L.; Crone, A.J.

    2001-01-01

    The midcontinent United States between the Appalachian and Rocky Mountains contains 40 known faults or other potentially tectonic features for which published geologic information shows or suggests Quaternary tectonic faulting. We report results of a systematic evaluation of published and other publicly available geologic evidence of Quaternary faulting. These results benefit seismic-hazard assessments by (1) providing some constraints on the recurrence intervals and magnitudes of large, prehistoric earthquakes, and (2) identifying features that warrant additional study. For some features, suggested Quaternary tectonic faulting has been disproved, whereas, for others, the suggested faulting remains questionable. Of the 40 features, nine have clear geologic evidence of Quaternary tectonic faulting associated with prehistoric earthquakes, and another six features have evidence of nontectonic origins. An additional 12 faults, uplifts, or historical seismic zones lack reported paleoseismological evidence of large. Quaternary earthquakes. The remaining 13 features require further paleoseismological study to determine if they have had Quaternary earthquakes that were larger than any known from local historical records; seven of these 13 features are in or near urbanized areas where their study could affect urban hazard estimates. These seven are: (1) the belt of normal faults that rings the Gulf of Mexico from Florida to Texas. (2) the Northeast Ohio seismic zone, (3) the Valmont and (4) Goodpasture faults of Colorado. (5) the Champlain lowlands normal faults of New York State and Vermont, and (6) the Lexington and (7) Kentucky River fault systems of eastern Kentucky. Published by Elsevier Science B.V.

  18. Mutagenicity of quaternary ammonium salts containing carbohydrate moieties

    Energy Technology Data Exchange (ETDEWEB)

    Dmochowska, Barbara [Department of Carbohydrate Chemistry, University of Gdansk, Sobieskiego 18, 80-952 Gdansk (Poland); Piosik, Jacek; Woziwodzka, Anna [Intercollegiate Faculty of Biotechnology, University of Gdansk and Medical University of Gdansk, Kladki 24, 80-822 Gdansk (Poland); Sikora, Karol; Wisniewski, Andrzej [Department of Carbohydrate Chemistry, University of Gdansk, Sobieskiego 18, 80-952 Gdansk (Poland); Wegrzyn, Grzegorz, E-mail: wegrzyn@biotech.univ.gda.pl [Department of Molecular Biology, University of Gdansk, Kladki 24, 80-822 Gdansk (Poland)

    2011-10-15

    Highlights: {yields} A series of quaternary ammonium salts containing carbohydrate moieties, with configuration D-galacto, D-gluco and D-manno, was synthesized and characterized. {yields} The quaternary ammonium salts containing carbohydrate moieties revealed potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. {yields} The N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. {yields} We suggest that quaternary ammonium salts may be more hazardous than previously supposed. - Abstract: Quaternary ammonium salts are widely used in industrial, agricultural, healthcare and domestic applications. They are believed to be safe compounds, with little or no health hazard to humans. However, in this report, we demonstrate that a series of newly synthesized quaternary ammonium salts containing carbohydrate moieties reveal potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. D-Gluco- and D-galacto-derivatives were found to have a higher mutagenic potential than D-manno-derivatives. Among the former groups of compounds, the N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. These results suggest that the safety of quaternary ammonium salts may be lower than previously supposed, indicating a need for testing such compounds for their mutagenicity.

  19. Geochemistry and petrogenesis of Quaternary volcanism from the islets in the eastern Beibu Gulf:evidence for Hainan plume

    Institute of Scientific and Technical Information of China (English)

    LI Naisheng; YAN Quanshu; CHEN Zhihua; SHI Xuefa

    2013-01-01

    Some of the islets in the eastern Beibu Gulf are covered by Quaternary volcano strata. The rock samples from these islets mainly consist of quartz tholeiites (at Shenjiandao), olivine tholeiites (at Linshidao and Xieyang-dao) and alkali basalts (at Yangpubi and Jianshidao), and basically represent four periods of the Quaternary volcanism of Hainan Island and its adjacent regions. Except for the samples from Shenjiandao, most of the Quaternary volcanics of these islets belong to alkali magma series. The trace element characteristics of all of these samples show they are OIB (oceanic island basalt)-like, which implies that their deep geodynamic setting may be related to a mantle plume. The Sr-Nd-Pb isotopic compositions show that the mantle source beneath the Quaternary strata can be regarded as a result of binary mixing between a depleted, DMM (de-pleted MORB mantle)-like source and an enriched mantle type 2 (EM2). The EM2 may be originated from the Hainan mantle plume, and has been metasomatized by carbonaceous fluids released from ancient re-cycled oceanic crust at an asthenospheric mantle level. These features, together with typical trace element ratios, reflect that the parent magma was not subjected to crustal contamination during its ascent to the surface. This study provides further petrological and geochemical evidence for the existence of the Hainan mantle plume.

  20. Stable isotopes reflect the ecological stability of two high-elevation mammals from the late Quaternary of Colorado

    Science.gov (United States)

    McLean, Bryan S.; Emslie, Steven D.

    2012-05-01

    The vertebrate fossil record of Cement Creek Cave, Colorado, spans from > 45,000 yr ago to the present and represents the richest stratified series of high-elevation (> 2900 m) mammal remains known from the late Quaternary of North America. Stable carbon and oxygen isotope analyses of tooth enamel were used to assess potential ecological responses of two species found commonly throughout the cave, Yellow-bellied marmots (Marmota flaviventris) and Bushy-tailed woodrats (Neotoma cinerea), to late Quaternary climate and environmental changes of the Southern Rocky Mountains. Results indicate that despite such perturbations, the dietary ecologies of both species were maintained across this period. Neither taxon shifted to consuming C4 taxa or different C3 functional groups; similarly, no significant shifts in surface water use were detected. Variations in enamel δ13C were observed, however, that represent the physiological responses of high-elevation plants to changing levels of late Quaternary atmospheric CO2. While our findings extend both the geographic and elevational record of this plant CO2 response, they simultaneously highlight the ecological stability of high-elevation M. flaviventris and N. cinerea during climate changes of late Quaternary magnitude.

  1. Paleovalley systems: Insights from Quaternary analogs and experiments

    Science.gov (United States)

    Blum, M.; Martin, J.; Milliken, K.; Garvin, M.

    2013-01-01

    Ancient fluvial valley systems are long recognized as important features in the stratigraphic record, but emerged as a specific focus of attention with publication of first-generation sequence-stratigraphic concepts. This paper reviews current understanding of paleovalley systems from the perspective of Quaternary analogs and experimental studies. Paleovalley systems can include distinct mixed bedrock-alluvial, coastal-plain, and cross-shelf segments. Mixed bedrock-alluvial segments are long-lived, cut across bedrock of significantly older age, and have an overall degradational architecture. By contrast, coastal-plain and cross-shelf segments are non-equilibrium responses to high-frequency cycles of relative sea-level change: most coastal-plain and cross-shelf segments form as a geometric response to relative sea-level fall, as river systems cut through coastal-plain and inner shelf clinothems, and extend basinward to track the shoreline. After incision and cross-shelf extension, lateral channel migration and contemporaneous channel-belt deposition creates a valley-scale feature. Coastal-plain and cross-shelf paleovalley widths are set by the number of channel-belt sandbodies deposited during this time. Paleovalley systems play a key role in source-to-sink sediment routing. Early views included the model of incision and complete sediment bypass in response to relative sea-level fall. However, this model does not stand up to empirical, theoretical, or experimental scrutiny. Instead, there is a complex dynamic between incision, deposition, and sediment export from an evolving valley: periods of incision correspond with sediment export minima, whereas periods of lateral migration and channel-belt construction result in increased flux to the river mouth. Sediment export from evolving valleys, and merging of drainages during cross-shelf transit, play key roles in sediment transfer to the shelf-margin and genetically-linked slope to basin-floor systems. Connection

  2. Of ice and water: Quaternary fluvial response to glacial forcing

    Science.gov (United States)

    Cordier, Stéphane; Adamson, Kathryn; Delmas, Magali; Calvet, Marc; Harmand, Dominique

    2017-06-01

    Much research, especially within the framework of the Fluvial Archives Group, has focused on river response to climate change in mid-latitude non-glaciated areas, but research into the relationships between Quaternary glacial and fluvial dynamics remains sparse. Understanding glacial-fluvial interactions is important because glaciers are able to influence river behaviour significantly, especially during glacial and deglacial periods: (1) when they are located downstream of a pre-existing fluvial system and disrupt its activity, leading to hydrographical, hydrosedimentary and isostatic adjustments, and (2) when they are located upstream, which is a common scenario in mid-latitude mountains that were glaciated during Pleistocene cold periods. In these instances, glaciers are major water and sediment sources. Their role is particularly significant during deglaciation, when meltwater transfer towards the fluvial system is greatly increased while downstream sediment evacuation is influenced by changes to glacial-fluvial connectivity and basin-wide sediment storage. This means that discharge and sediment flux do not always respond simultaneously, which can lead to complex fluvial behaviour involving proglacial erosion and sedimentation and longer-term paraglacial reworking. These processes may vary spatially and temporally according to the position relative to the ice margin (ice-proximal versus ice-distal). With a focus on the catchments of Europe, this paper aims to review our understanding of glacial impacts on riversystem behaviour. We examine the methods used to unravel fluvial response to 'glacial forcing', and propose a synthesis of the behaviour of glacially-fed rivers, opening perspectives for further research.

  3. A Quaternary Fault Database for Central Asia

    Directory of Open Access Journals (Sweden)

    S. Mohadjer

    2015-09-01

    Full Text Available Earthquakes represent the highest risk in terms of potential loss of lives and economic damage for Central Asian countries. Knowledge of fault location and behavior is essential in calculating and mapping seismic hazard. Previous efforts in compiling fault information for Central Asia have generated a large amount of data that are published in limited-access journals with no digital maps publicly available, or are limited in their description of important fault parameters such as slip rates. This study builds on previous work by improving access to fault information through a web-based interactive map and an online database with search capabilities that allow users to organize data by different fields. The data presented in this compilation include fault location, its geographic, seismic and structural characteristics, short descriptions, narrative comments and references to peer-reviewed publications. The interactive map displays 1196 fault segments and 34 000 earthquake locations on a shaded-relief map. The online database contains attributes for 122 faults mentioned in the literature, with Quaternary and geodetic slip rates reported for 38 and 26 faults respectively, and earthquake history reported for 39 faults. This work has implications for seismic hazard studies in Central Asia as it summarizes important fault parameters, and can reduce earthquake risk by enhancing public access to information. It also allows scientists and hazard assessment teams to identify structures and regions where data gaps exist and future investigations are needed.

  4. Quaternary stratigraphy and palaeogeography of Poland

    Science.gov (United States)

    Marks, Leszek; Dzierżek, Jan; Janiszewski, Robert; Kaczorowski, Jarosław; Lindner, Leszek; Majecka, Aleksandra; Makos, Michał; Szymanek, Marcin; Tołoczko-Pasek, Anna; Woronko, Barbara

    2016-09-01

    Though the stratigraphical and palaeogeographical framework of the Quaternary in Poland is still to be completed, several crucial points have been confirmed recently. The preglacial series, accepted for years as belonging to the Lower Pleistocene, is undoubtedly of Early Pliocene age, with a huge hiatus above almost until the uppermost Lower Pleistocene. The earliest glaciation in Poland (Nidanian) occurred at about 900 ka BP when the ice sheet reached the mid-southern part of the country. The following Podlasian Interglacial embraced the Brunhes/Matuyama boundary in the middle, in a similar fashion to the corresponding Cromerian Complex in Western Europe. The late Early and early Middle Pleistocene interglacials in Poland comprised 2-3 optima each, whereas every one of the younger interglacials was characterised by a single optimum only. The Late Vistulian ice sheet was most extensive in the western part of Poland (Leszno Phase) whereas the younger Poznań Phase was more extensive in the central and eastern part of the country. This was due to the varied distance from the glaciation center in Scandinavia, making the ice sheet margin reach a terminal position in different times. Palaeoclimatological research in the Tatra Mountains has provided new evidence for the atmospheric circulation over Europe. During cold phases of the Pleistocene in Poland a continental climate extended further westwards, quite the opposite that occurring during warmer intervals.

  5. A Quaternary Fault Database for Central Asia

    Science.gov (United States)

    Mohadjer, S.; Ehlers, T. A.; Bendick, R.; Stübner, K.; Strube, T.

    2015-09-01

    Earthquakes represent the highest risk in terms of potential loss of lives and economic damage for Central Asian countries. Knowledge of fault location and behavior is essential in calculating and mapping seismic hazard. Previous efforts in compiling fault information for Central Asia have generated a large amount of data that are published in limited-access journals with no digital maps publicly available, or are limited in their description of important fault parameters such as slip rates. This study builds on previous work by improving access to fault information through a web-based interactive map and an online database with search capabilities that allow users to organize data by different fields. The data presented in this compilation include fault location, its geographic, seismic and structural characteristics, short descriptions, narrative comments and references to peer-reviewed publications. The interactive map displays 1196 fault segments and 34 000 earthquake locations on a shaded-relief map. The online database contains attributes for 122 faults mentioned in the literature, with Quaternary and geodetic slip rates reported for 38 and 26 faults respectively, and earthquake history reported for 39 faults. This work has implications for seismic hazard studies in Central Asia as it summarizes important fault parameters, and can reduce earthquake risk by enhancing public access to information. It also allows scientists and hazard assessment teams to identify structures and regions where data gaps exist and future investigations are needed.

  6. A Quaternary fault database for central Asia

    Science.gov (United States)

    Mohadjer, Solmaz; Ehlers, Todd Alan; Bendick, Rebecca; Stübner, Konstanze; Strube, Timo

    2016-02-01

    Earthquakes represent the highest risk in terms of potential loss of lives and economic damage for central Asian countries. Knowledge of fault location and behavior is essential in calculating and mapping seismic hazard. Previous efforts in compiling fault information for central Asia have generated a large amount of data that are published in limited-access journals with no digital maps publicly available, or are limited in their description of important fault parameters such as slip rates. This study builds on previous work by improving access to fault information through a web-based interactive map and an online database with search capabilities that allow users to organize data by different fields. The data presented in this compilation include fault location, its geographic, seismic, and structural characteristics, short descriptions, narrative comments, and references to peer-reviewed publications. The interactive map displays 1196 fault traces and 34 000 earthquake locations on a shaded-relief map. The online database contains attributes for 123 faults mentioned in the literature, with Quaternary and geodetic slip rates reported for 38 and 26 faults respectively, and earthquake history reported for 39 faults. All data are accessible for viewing and download via http://www.geo.uni-tuebingen.de/faults/. This work has implications for seismic hazard studies in central Asia as it summarizes important fault parameters, and can reduce earthquake risk by enhancing public access to information. It also allows scientists and hazard assessment teams to identify structures and regions where data gaps exist and future investigations are needed.

  7. Estimates of late Quaternary mode and intermediate water silicic acid concentration in the Pacific Southern Ocean

    Science.gov (United States)

    Rousseau, Jonathon; Ellwood, Michael J.; Bostock, Helen; Neil, Helen

    2016-04-01

    The Southern Ocean plays a critical role in the exchange of carbon between the ocean and atmosphere over glacial-interglacial timescales. Hypotheses used to explain late Quaternary variations in atmospheric carbon dioxide (CO2) implicate changes in the nutrient dynamics and circulation of the Southern Ocean. Here we present silicon isotope (δ30Si) records of late Quaternary sponges and diatoms from the NZ-sector of the Southern Ocean. Analysis of our sponge δ30Si records strongly suggests that the silicic acid concentration at mode and intermediate depths was higher during the LGM and the deglacial period compared to the present day. Our diatom δ30Si record suggests biological productivity near of the Polar Front was greater during the deglacial period, but not significantly different during the LGM compared to the present day. Taking our dataset in context with other regional paleoceanographic records, we interpret the predicted elevation in LGM and deglacial silicic acid concentration to reflect a shoaling of water masses during the LGM and 'leakage' of excess Southern Ocean dissolved silicon during the deglacial period.

  8. Period Cramps

    Science.gov (United States)

    ... Too Tall or Too Short All About Puberty Period Cramps KidsHealth > For Kids > Period Cramps Print A ... re a girl who gets them. What Are Period Cramps? Lots of girls experience cramps before or ...

  9. Quaternary Evolution of Karliova Triple Junction

    Science.gov (United States)

    Sançar, Taylan; Zabcı, Cengiz; Akyüz, H. Serdar

    2013-04-01

    The arguments to explain Quaternary evolution of Karlıova Triple Junction (KTJ) depends upon two different analogue models. The compressional type of Prandtl Cell Model (PCM) and 60 km wide shear zone with concomitant counter clockwise block rotation used to modelled for west and east of the KTJ respectively. The data for the model of west of the KTJ acquired by extensive field studies, and quantified geomorphic features. Compressional PCM put forward that behavior of slip lines controlled by boundary faults. But the model is not enough to explain slip distribution, age relation of them. At west of the KTJ boundary faults presented by eastern most segments of the North Anatolian Fault Zone (NAFZ) and the East Anatolian Fault Zone (EAFZ). Slip lines, however, presented by Bahçeli and Toklular faults. Both field studies and morphometric analyses undisputedly set forth that there are two different fault types between the NAFZ and EAFZ. The most strain loaded fault type, which are positioned near the NAFZ, start as a strike-slip fault and when it turn to SE its sense of motion change to oblique normal due to changing orientation of principal stress axes. The new orientation of stress axes exposed in the field as a special kind of caprock -cuesta-. The younger slip lines formed very close to junction point and accommodate less slip. Even though slip trajectories started from the boundary faults in compressional PCM, at the west of KTJ, right lateral trajectories more clearly formed close the NAFZ and left lateral trajectories, relatively less strain loaded fault type, are poorly formed close the EAFZ . We think that, this differences between KTJ and compressional PCM result from the distinction of velocity of boundary faults. East of the KTJ governed by completely different mechanism. The region controlled two main fault systems. The Varto Fault Zone (VFZ), the eastern branch of the KTJ, and Murat Fault (MF) delimited the region from north and south respectively. The

  10. Quaternary Magmatism in the Cascades - Geologic Perspectives

    Science.gov (United States)

    Hildreth, Wes

    2007-01-01

    Foreward The Cascade magmatic arc is a belt of Quaternary volcanoes that extends 1,250 km from Lassen Peak in northern California to Meager Mountain in Canada, above the subduction zone where the Juan de Fuca Plate plunges beneath the North American Plate. This Professional Paper presents a synthesis of the entire volcanic arc, addressing all 2,300 known Quaternary volcanoes, not just the 30 or so visually prominent peaks that comprise the volcanic skyline. Study of Cascade volcanoes goes back to the geological explorers of the late 19th century and the seminal investigations of Howel Williams in the 1920s and 1930s. However, major progress and application of modern scientific methods and instrumentation began only in the 1970s with the advent of systematic geological, geophysical, and geochemical studies of the entire arc. Initial stimulus from the USGS Geothermal Research Program was enhanced by the USGS Volcano Hazards Program following the 1980 eruption of Mount St. Helens. Together, these two USGS Programs have provided more than three decades of stable funding, staffing, and analytical support. This Professional Paper summarizes the resultant USGS data sets and integrates them with the parallel contributions of other investigators. The product is based upon an all-encompassing and definitive geological database, including chemical and isotopic analyses to characterize the rocks and geochronology to provide the critical time constraints. Until now, this massive amount of data has not been summarized, and a systematic and uniform interpretation firmly grounded in geological fact has been lacking. Herein lies the primary utility of this Cascade volume. It not only will be the mandatory starting point for new workers, but also will provide essential geological context to broaden the perspectives of current investigators of specific Cascade volcanoes. Wes Hildreth's insightful understanding of volcanic processes and his uncompromising scientific integrity make him

  11. The isotope hydrology of Quaternary climate change.

    Science.gov (United States)

    Darling, W G

    2011-04-01

    Understanding the links between climate change and human migration and culture is an important theme in Quaternary archaeology. While oxygen and hydrogen stable isotopes in high-latitude ice cores provide the ultimate detailed record of palaeoclimate extending back to the Middle Pleistocene, groundwater can act as a climate archive for areas at lower latitudes, permitting a degree of calibration for proxy records such as lake sediments, bones, and organic matter. Not only can oxygen and hydrogen stable isotopes be measured on waters, but the temperature of recharge can be calculated from the amount of the atmospheric noble gases neon, argon, krypton, and xenon in solution, while residence time can be estimated from the decay of the radioisotopes carbon-14, chlorine-36, and krypton-81 over timescales comparable to the ice core record. The Pleistocene-Holocene transition is well characterised in aquifers worldwide, and it is apparent that isotope-temperature relationships of the present day are not necessarily transferable to past climatic regimes, with important implications for the interpretation of proxy isotope data. Groundwaters dating back to one million years, i.e., to beyond the Middle Pleistocene, are only found in major aquifer basins and information is relatively sparse and of low resolution. Speleothem fluid inclusions offer a way of considerably increasing this resolution, but both speleothem formation and large-scale groundwater recharge requires humid conditions, which may be relatively infrequent for areas currently experiencing arid climates. Both types of record therefore require caution in their interpretation when considering a particular archaeological context.

  12. Late Quaternary geology of the Lower Central Plain, Thailand

    Science.gov (United States)

    Sinsakul, Sin

    2000-08-01

    The Lower Central Plain or Chao Phraya Plain, located in the upper Gulf of Thailand, has an average elevation of 2 m above the present mean sea level. It is a fault bounded basin developed in the Plio-Pleistocene epoch. Consequently, the basin has been filled with Quaternary sediment reaching a thickness of almost 2000 m, of which only the upper 300 m is known. The Pleistocene deposits of the Lower Central Plain represent a complex interplay of alluvial, fluvial and deltaic environments of the Chao Phraya River and its tributaries. The upper sequence of sand and stiff clay with iron-oxide concretions on the surface was deposited in a fluviatile environment subjected to a regressive period in the late Pleistocene. The term "Chao Phraya delta" is used to define the landform where the Chao Phraya River interacted with marine processes as the sea level changed during the Holocene transgression. These strata indicated that the Holocene sea reached its maximum height of 4 m above the present mean sea level around 6000 years B.P.; from then on sea level fluctuated until it reached its present level around 1500 years B.P. This complex sea level history has caused the progradation of tidal flat, and tide-dominated delta deposits, consisting of soft marine clay, that covered the Lower Central Plain to an average depth of 15 m in the Bangkok area. The soft marine clay or Bangkok clay is the most important unit in the stratigraphic sequence in terms of land subsidence in the Lower Central Plain. Evidence of coastal erosion is also considerable in the low tidal flat area on the west bank of the Chao Phraya River mouth and adjacent coast.

  13. Late Quaternary sackungen in the highest mountains of the Carpathians

    Science.gov (United States)

    Pánek, Tomáš; Mentlík, Pavel; Engel, Zbyněk; Braucher, Règis; Zondervan, Albert

    2017-03-01

    Sackungen represents a common mode of deep-seated rock-slope failures in alpine landscapes, but proof of their temporal and causal relationship to extrinsic factors such as climatic changes, glacier retreat or seismic activity remains elusive. Based on the terrestrial cosmogenic nuclide (TCN) dating of 18 sackung scarps supported by one radiocarbon-dated scarp, we reconstructed the post-glacial chronology of sackungen in the Tatra Mts. (central Europe, Slovakia and Poland), the highest part of the Carpathians. The obtained ages (∼15.7-4.3 ka) indicate that sackungen post-date the regional LGM and some of them originated soon after the glacier withdrawal from adjacent valleys. Furthermore, systematic decrease of scarp ages with their increasing altitude suggests a direct link between sackung origin and post-LGM glacier thinning. However, substantial lag (>5 ka) of some sackungen in respect to glacier retreat implies complex relationships between sackung onset and deglaciation where retreat of glaciers acted predominantly as a preparatory, not a triggering factor during the genesis of these slope deformations. They originated either as a consequence of stress relaxation within the rock mass lasting several ka or alternatively could be triggered by climatic processes or seismicity. Indeed, a significant part of sackung activity took place during predominantly warmer and more humid periods, with some dates coinciding with the Bølling-Allerød chronozone, but especially with the onset of the Holocene and the Holocene Climatic Optimum. Earthquake triggering is less probable, as the Tatra Mts. lack significant modern and historic seismic activity and there is no geomorphic evidence of fault offsets on the Late Quaternary landforms. In concert with other recent studies, we propose that large rock slope failures in high mountains seldom react immediately to glacier withdrawal, but could display temporal delay lasting up to several millennia.

  14. Absolute age determination of quaternary fault and formation

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Chang Sik; Lee, Kwang Sik; Choi, Man Sik [Korea Basic Science Institute, Seoul (Korea, Republic of)] (and others)

    2002-04-15

    The annual ('01-'01) objective of this project is to data the fault activity for the presumed quaternary fault zones to the western part of the Ulsam fault system and southeastern coastal area near the Wolseong Nuclear Power Plant. Rb-Sr, K-Ar, OSL, C-14 and U-series disequilibrium methods were applied to the fault rocks, organic matter and quaternary formations collected from the Pyeonghae, Bogyeongsa, Yugyeri, Byegkye, Gacheon-1 and Joil outcrops of the Yangsan fault system, the Baenaegol outcrop of the Moryang fault system, the Susyongji(Madong-2), Singye, Hwalseongri, Ipsil and Wonwonsa outcrops of the Ulsan fault system and from quaternary marine terraces (Oryoo and Kwangseong sites) in the southeastern coastal area. The experimental procedure of the OSL SAR protocol was reexamined to get more reliable dating results.

  15. Atmospheric effects on Quaternary polarization encoding for free space communication

    Science.gov (United States)

    Soorat, Ram; Vudayagiri, Ashok

    2016-10-01

    We have simulated atmospheric effects such as fog and smoke in laboratory environment to simulate depolarisation due to atmospheric effects during a free space optical communi- cation. This has been used to study noise in two components of quaternary encoding for polarization shift keying. Individual components of a Quaternary encoding, such as vertical and horizontal as well as 45$^\\circ$ and 135$^\\circ$ , are tested separately and indicates that the depo- larization effects are different for these two situation. However, due to a differential method used to extract information bits, the protocol shows extremely low bit error rates. The information obtained is useful during deployment of a fully functional Quaternary encoded PolSK scheme in free space.

  16. The biological activity of quaternary ammonium salts (QASs

    Directory of Open Access Journals (Sweden)

    Ewa Obłąk

    2010-04-01

    Full Text Available Quaternary ammonium salts (QASs, especially those of cationic surfactant character, are applied as antibacterial and antifungal disinfectants. QASs affect lipid-enveloped viruses, including human immunodeficiency virus (HIV and hepatitis B virus (HBV, but not non-enveloped viruses. These compounds are extensively used in domestic (as ingredients of shampoos, hair conditioners, agricultural (as fungicides, pesticides, insecticides, healthcare (as medications, and industrial applications (as biocides, fabric softeners, corrosion inhibitors. The extensive use of quaternary ammonium disinfectants in recent years has led to the development of resistance in microorganisms to these drugs. Thus [i]Staphylococcus[/i] [i]aureus[/i] strains contain the plasmid-carrying genes [i]qacA[/i] and [i]qacB [/i]encoding resistance to quaternary ammonium compounds and acriflavine. The membrane proteins QacA and QacB confer multidrug resistance by exporting the compound by the proton motive force which is generated by the transmembrane electrochemical proton gradient.

  17. [The biological activity of quaternary ammonium salts (QASs)].

    Science.gov (United States)

    Obłak, Ewa; Gamian, Andrzej

    2010-04-19

    Quaternary ammonium salts (QASs), especially those of cationic surfactant character, are applied as antibacterial and antifungal disinfectants. QASs affect lipid-enveloped viruses, including human immunodeficiency virus (HIV) and hepatitis B virus (HBV), but not non-enveloped viruses. These compounds are extensively used in domestic (as ingredients of shampoos, hair conditioners), agricultural (as fungicides, pesticides, insecticides), healthcare (as medications), and industrial applications (as biocides, fabric softeners, corrosion inhibitors). The extensive use of quaternary ammonium disinfectants in recent years has led to the development of resistance in microorganisms to these drugs. Thus Staphylococcus aureus strains contain the plasmid-carrying genes qacA and qacB encoding resistance to quaternary ammonium compounds and acriflavine. The membrane proteins QacA and QacB confer multidrug resistance by exporting the compound by the proton motive force which is generated by the transmembrane electrochemical proton gradient.

  18. Quaternary naltrexone reverses radiogenic and morphine-induced locomotor hyperactivity

    Energy Technology Data Exchange (ETDEWEB)

    Mickley, G.A.; Stevens, K.E.; Galbraith, J.A.; White, G.A.; Gibbs, G.L.

    1984-04-01

    The present study attempted to determine the relative role of the peripheral and central nervous system in the production of morphine-induced or radiation-induced locomotor hyperactivity of the mouse. Toward this end, we used a quaternary derivative of an opiate antagonist (naltrexone methobromide), which presumably does not cross the blood-brain barrier. Quaternary naltrexone was used to challenge the stereotypic locomotor response observed in these mice after either an i.p. injection of morphine or exposure to 1500 rads /sup 60/Co. The quaternary derivative of naltrexone reversed the locomotor hyperactivity normally observed in the C57BL/6J mouse after an injection of morphine. It also significantly attenuated radiation-induced locomotion. The data reported here support the hypothesis of endorphin involvement in radiation-induced and radiogenic behaviors. However, these conclusions are contingent upon further research which more fully evaluates naltrexone methobromide's capacity to cross the blood-brain barrier.

  19. Electrochemical oxidation of quaternary ammonium electrolytes : Unexpected side reactions in organic electrochemistry

    NARCIS (Netherlands)

    Nouri Nigjeh, Eslam; de Vries, Marcel; Bruins, Andries P.; Bischoff, Rainer; Permentier, Hjalmar P.

    2012-01-01

    Quaternary ammonium salts are among the most widely used electrolytes in organic electrochemistry, but there is little known about their unwanted side oxidation reactions. We have, therefore, studied the constant potential oxidation products of quaternary ammonium electrolytes using mass spectrometr

  20. Antibacterial activity of reactive quaternary ammonium compounds in solution and in nonleachable coatings

    NARCIS (Netherlands)

    Gozzelino, G.; Romero Tobar, D.E.; Chaitiemwong, N.; Hazeleger, W.C.; Beumer, R.R.

    2011-01-01

    Antibacterial polymers suitable for coating applications without leaching of the biocidal component have been obtained by UV copolymerization of acrylic resins with acrylic monomers containing quaternary ammonium moieties. Suitable reactive biocides, based on quaternary ammonium monomers (QAMs), end

  1. Electrochemical oxidation of quaternary ammonium electrolytes : Unexpected side reactions in organic electrochemistry

    NARCIS (Netherlands)

    Nouri Nigjeh, Eslam; de Vries, Marcel; Bruins, Andries P.; Bischoff, Rainer; Permentier, Hjalmar P.

    Quaternary ammonium salts are among the most widely used electrolytes in organic electrochemistry, but there is little known about their unwanted side oxidation reactions. We have, therefore, studied the constant potential oxidation products of quaternary ammonium electrolytes using mass

  2. Kinetic Study of MOCVD Ⅲ-Ⅴ Quaternary Antimonides

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    The kinetics of MOCVD GaInAsSb and AlGaAsSb was studied by the growth rate as a function of growth temperature and partial pressure of Ⅲ and Ⅴ MO species. The diffusion theory was used to explain the mass transport processes in MOCVD Ⅲ-Ⅴ quaternary antimonides. On the basis of the discussion about their growth kinetics and epilayer properties, the good quality multi-epilayers of these two quaternary antimonides and their photodetectors and arrays with wavelength of 1.8~2.3 μm and detectivities of D*>109 cm Hz1/2 W-1 were obtained.

  3. Quaternary Structure Analyses of an Essential Oligomeric Enzyme.

    Science.gov (United States)

    Soares da Costa, Tatiana P; Christensen, Janni B; Desbois, Sebastien; Gordon, Shane E; Gupta, Ruchi; Hogan, Campbell J; Nelson, Tao G; Downton, Matthew T; Gardhi, Chamodi K; Abbott, Belinda M; Wagner, John; Panjikar, Santosh; Perugini, Matthew A

    2015-01-01

    Here, we review recent studies aimed at defining the importance of quaternary structure to a model oligomeric enzyme, dihydrodipicolinate synthase. This will illustrate the complementary and synergistic outcomes of coupling the techniques of analytical ultracentrifugation with enzyme kinetics, in vitro mutagenesis, macromolecular crystallography, small angle X-ray scattering, and molecular dynamics simulations, to demonstrate the role of subunit self-association in facilitating protein dynamics and enzyme function. This multitechnique approach has yielded new insights into the molecular evolution of protein quaternary structure.

  4. Stereocontrolled Introduction of the Quaternary Stereogenic Centre in Lyngbyatoxin A

    DEFF Research Database (Denmark)

    Tønder, Janne Ejrnæs; Tanner, David Ackland

    In our study of the enantioselective total synthesis of Lyngbyatoxin A, we have focused first on the stereocontrolled introduction of the quaternary stereogenic centre. The key step in the synthesis involves an enantiospecific Lewis-acid mediated rearrangement of chiral vinyl epoxides, a methodol......In our study of the enantioselective total synthesis of Lyngbyatoxin A, we have focused first on the stereocontrolled introduction of the quaternary stereogenic centre. The key step in the synthesis involves an enantiospecific Lewis-acid mediated rearrangement of chiral vinyl epoxides...

  5. Quaternary ammonium biocides as antimicrobial agents protecting historical wood and brick.

    Science.gov (United States)

    Rajkowska, Katarzyna; Koziróg, Anna; Otlewska, Anna; Piotrowska, Małgorzata; Nowicka-Krawczyk, Paulina; Brycki, Bogumił; Kunicka-Styczyńska, Alina; Gutarowska, Beata

    2016-01-01

    Quaternary ammonium compounds (QACs) are widely used in disinfection of water, surfaces and instruments as well as in textile, leather and food industries because of their relatively low toxicity, broad antimicrobial spectrum, non-volatility and chemical stability. Due to these advantages, QACs are also used in restoration and can be applied on historical material. The aim of this study was to determine the usefulness of biocides based on quaternary ammonium salts and containing various excipients in the protection of historical materials against microbial growth. The study determined the antimicrobial activity of three biocides against bacteria: Pseudomonas fluorescens, Staphylococcus equorum, Bacillus cereus, Bacillus muralis, Sporosarcina aquimarina and Rhodococcus fascians, and moulds: Chaetomium globosum, Penicillium citreonigrum, Cladosporium cladosporioides I, Acremonium strictum, Aspergillus fumigatus and Cladosporium cladosporioides II, all isolated from historical wood and brick. Staphylococcus equorum, Bacillus cereus, Sporosarcina aquimarina and Rhodococcus fascians bacteria, and Cladosporium cladosporioides I and Acremonium strictum moulds showed high sensitivity to quaternary ammonium biocides. Historical wood can be effectively disinfected by three applications of biocide A (30% v/v) containing dodecyl dimethyl ammonium chloride (DDAC), citric acid, propiconazole and propanol. Disinfection of historical brick can be carried out by three applications of 6% v/v solutions of biocide B (based on DDAC and ethylenediaminetetraacetic acid - EDTA) or biocide C (containing a non-ionic surfactant, DDAC and EDTA). Effective protection of historical building materials against microbial growth for a period of seven days can be achieved by the application of biocide A (30% v/v) on the wood surface and biocide B (6% v/v) on the brick surface.

  6. Quaternary disappearance of tree taxa from Southern Europe: Timing and trends

    Science.gov (United States)

    Magri, Donatella; Di Rita, Federico; Aranbarri, Josu; Fletcher, William; González-Sampériz, Penélope

    2017-05-01

    A hundred pollen and plant macrofossil records from the Iberian Peninsula, Southern France, the Italian Peninsula, Greece and the Aegean, and the southwestern Black Sea area formed the basis for a review of the Quaternary distribution and extirpation of tree populations from Southern Europe. Following a discussion of the caveats/challenges about using pollen data, the Quaternary history of tree taxa has been reconstructed with attention to Taxodium/Glyptostrobus, Sciadopitys, Cathaya, Cedrus, Tsuga, Eucommia, Engelhardia, Carya, Pterocarya, Parrotia, Liquidambar, and Zelkova. The timing of extinction, distributed over the whole Quaternary, appears very diverse from one region to the other, in agreement with current biodiversity in Southern Europe. The geographical patterns of persistence/disappearance of taxa show unexpected trends and rule out a simple North to South and/or West to East trend in extirpations. In particular, it is possible to detect disjunct populations (Engelhardia), long-term persistence of taxa in restricted regions (Sciadopitys), distinct populations/species/genera in different geographical areas (Taxodium type). Some taxa that are still widespread in Europe have undergone extirpation in Mediterranean areas in the lateglacial period and Holocene (Buxus, Carpinus betulus, Picea); they provide an indication of the modes of disappearance of tree populations that may be useful to evaluate correctly the vulnerability of modern fragmented plant populations. The demographic histories of tree taxa obtained by combined palaeobotanical and genetic studies is a most challenging field of research needed not only to assess species/population differentiation, but also to reach a better understanding of extinction processes, an essential task in the current global change scenario.

  7. Quaternary geologic map of the White Lake 4° x 6° quadrangle, United States

    Science.gov (United States)

    State compilations by Pope, David E.; Gilliland, William A.; Wermund, E.G.; edited and integrated by Richmond, Gerald Martin; Weide, David L.; Moore, David W.; Digital edition by Bush, Charles A.

    1990-01-01

    This map is part of the Quaternary Geologic Atlas of the United States (I-1420). It was first published as a printed edition in 1990. The geologic data have now been captured digitally and are presented here along with images of the printed map sheet and component parts as PDF files. The Quaternary Geologic Map of the White Lake 4° x 6° Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the Earth. They make up the ground on which we walk, the dirt in which we dig foundations, and the soil in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale. In recent years, surficial deposits and materials have become the focus of much interest by scientists, environmentalists, governmental agencies, and the general public. They are the foundations of ecosystems, the materials that support plant growth and animal habitat, and the materials through which travels much of the water required for our agriculture, our industry, and our general well being. They also are materials that easily can become contaminated by pesticides, fertilizers, and toxic wastes. In this context, the value of the surficial geologic map is evident.

  8. Apparent late Quaternary fault slip rate increase in the southwestern Lower Rhine Graben, central Europe

    Science.gov (United States)

    Gold, Ryan D.; Friedrich, Anke M.; Kubler, Simon; Salamon, Martin

    2017-01-01

    In regions of low strain, long earthquake recurrence intervals (104–106  yrs) and erosive processes limit preservation of Quaternary markers suitable for distinguishing whether faults slip at uniform or secularly varying rates. The Lower Rhine graben in the border region of Germany, The Netherlands, and Belgium provides a unique opportunity to explore Quaternary slip‐rate variations in a region of low strain using the basal (2.29±0.29  Ma) and surface (700±80  ka) contacts of the regionally extensive main terrace (“Hauptterrasse”), deposited by the Rhine and Maas Rivers. These surfaces are vertically offset 3–140 m and 0–68 m, respectively, across individual fault strands within a distributed network of northwest‐trending, slow‐slipping (earth digital terrain models, which we synthesize with existing constraints on the offset basal contact of this fluvial deposit (n=91 collocated sites with displacement constraints). We find that >80% of the sites record an apparent increase in slip rate for the more recent interval from 700 ka to present, which corresponds to a period of increased uplift of the nearby Rhenish Massif and regional volcanism. However, the apparent increase in slip rate could result, in part, from erosion of the footwall surface below the main terrace, leading to an apparent displacement that is smaller than the total vertical offset since the start of the Quaternary. Prior work focused on characterization of these faults as seismic sources in the Lower Rhine graben has preferentially relied on the average fault‐slip rate constrained using the base of the main terrace. We suggest that average fault‐slip rates calculated using the ∼700  ka main terrace surface are subjected to fewer uncertainties and sample a time interval that is more relevant for seismic‐hazard analysis.

  9. 根据日本中部琵琶湖深井孢粉资料重建第四纪古植被和古气候及全球古气候对比%PALAEOVEGETATION AND PALAEOCLIMATE DURING THE QUATERNARY PERIOD BASED ON THE LONG CORES FROM LAKE BIWA, CENTRAL JAPAN, AND GLOBAL CORRELATION OF THE PALAEOCLIMATE RECORDS

    Institute of Scientific and Technical Information of China (English)

    藤则雄

    2003-01-01

    根据日本中部琵琶湖深井钻探资料研究了过去3Ma的古植被、地层及古气候.由湖底取得的200m和1 400m样品的孢粉组合可分别划分出19个和37个带,反映了湖区及其周围自晚上新世以来的古植被和古气候演变史.在冰期阶时琵琶湖附近山区的典型植被为亚北极带,低地为冷温带.而在间冰期阶里山区一般为温带或冷温带植被,低地则主要由落叶和常绿树组成的温带和暖温带的植被.在进行过去3Ma古植被、古气候演变对比中,当地古气候史和以下资料显示出明显的一致,例如加勒比海、西太平洋及赤道海洋的氧同位素资料,地中海西部(Mallorca)的沉积旋回,欧洲中部的风成沉积序列,日本关东和新几内亚的海平面变化记录,以及在南美波哥大高地和以色列死海裂谷根据孢粉得出的古气候变化记录.%Investigation was carried out on the palaeovegetation, stratigraphy and palaeoclimate in the last 3 Ma based onthe long cores from the Lake Biwa, Central Japan. Samples of 200-meter and 1400-meter cores obtained from the bottom of thelake yield nineteen and thirty-seven pollen zones respectively showing the palaeovegetational and palaeoclimatic changes inand around the lake since the late Pliocene period. During the glacial stages or stadials, typical vegetation of the subpolar zoneoccurred in the mountainous area around Lake Biwa. While in the lowland area in and around the lake, characteristic plants ofthe Cool Temperate zone occurred. During the interglacial stages or interstadials the vegetation of the mountainous area wasgenerally characterized by plants of the Temperate zone and/or Cool Temperate zone, while in the lowland area the vegetationwas composed mainly of deciduous and evergreen broad-leaved trees of the Temperate and Warm Temperate zones. In theglobal correlation from the viewpoints of palaeovegetation and palaeoclimate changes during the last 3 Ma since the late

  10. Late Quaternary Faulting along the San Juan de los Planes Fault Zone, Baja California Sur, Mexico

    Science.gov (United States)

    Busch, M. M.; Coyan, J. A.; Arrowsmith, J.; Maloney, S. J.; Gutierrez, G.; Umhoefer, P. J.

    2007-12-01

    Los Planes highway, the fault steps to the right 2km with no overlap. The fault is inactive until ~3km south of the Los Planes highway where scarp heights in the Quaternary sediments rise to ~3-11m for ~11km with an average trend of 160°, implying increasing slip rate. The fault then steps left 2km with no overlap, trending 145°. Scarp heights range from 3-6m in the step. The southernmost 9km of the fault zone, trending 200°, is marked by discontinuous scarps and embayed bedrock, reflecting diminished fault activity. The footwall landscape in this area is characterized by a broad, gently-sloping, low-relief pediment surface with thin Quaternary cover, disrupted by inselberg-like hills. The young scarp-forming fault appears to have reactivated older faults to rupture this pediment, reflecting the episodic nature of slip along this fault zone. Preliminary OSL ages of the youngest faulted deposit imply a Late Pleistocene-Holocene slip rate of 0.1-1mm/yr. The SJPFZ is thus characterized by reactivation of pre-existing faults to rupture a pre-existing low relief erosional landscape. Whereas the entire region might have experienced the quiescent period that allowed for development of the low- relief, stable surface along the SJPFZ, we speculate that while the SJPFZ was dormant, other faults within the gulf-margin system were actively accommodating strain.

  11. Session Introduction: Global correlation on late Quaternary paleovalley systems

    NARCIS (Netherlands)

    Cohen, K.M.; Amorosi, A.; Busschers, F.S.; Hori, K.; Tanabe, S.

    2015-01-01

    All around the world, paleovalley systems have trapped great amounts of deposits and hold a quite complete Late Quaternary record. Uniquely, these records directly interlink the shelf marine with the hinterland fluvial realms. In the vicinity of ice sheets, in similar ways, paleovalleys interlink th

  12. Application of Analytic Geometry to Ternary and Quaternary Diagrams.

    Science.gov (United States)

    MacCarthy, Patrick

    1986-01-01

    Advantages of representing ternary and quaternary composition diagrams by means of rectangular coordinates were pointed out in a previous paper (EJ 288 693). A further advantage of that approach is that analytic geometry, based on rectangular coordinates, is directly applicable as demonstrated by the examples presented. (JN)

  13. A revision of the Pliocene and Quaternary Lutrinae from Europe

    NARCIS (Netherlands)

    Willemsen, G.F.

    1992-01-01

    In this paper, a revision of the Pliocene and Quaternary Lutrinae from Europe is presented. Such a revision, including fossil material, has not been published since the work of Pohle (1919). Three tribes within the Lutrinae are recognized: the Lutrini, the Aonyxini and the Enhydrini. The latter comp

  14. Significant differences in late Quaternary bedrock erosion and transport

    DEFF Research Database (Denmark)

    Andrews, John; Bjørk, Anders Anker; Eberl, Dennis;

    2015-01-01

    We use quantitative X-ray diffraction to determine the mineralogy of late Quaternary marine sediments from the West and East Greenland shelves offshore from early Tertiary basalt outcrops. Despite the similar basalt outcrop area (60 000–70 000 km2), there are significant differences between East ...

  15. Quaternary biogenic opal records in the South China Sea: Linkages to East Asian monsoon, global ice volume and orbital forcing

    Institute of Scientific and Technical Information of China (English)

    WANG RuJian; JIAN ZhiMin; XIAO WenShen; TIAN Jun; LI JianRu; CHEN RongHua; ZHENG YuLong; CHEN JianFang

    2007-01-01

    Particulate fluxes investigated in the central South China Sea (SCS) during 1993-1996 indicate that opal flux can be used to show primary productivity change, which provides a foundation for tracing the evolutionary relationship between the surface productivity and East Asian monsoon in the SCS during the late Quaternary glacial and interglacial periods. Based on the studies of opal % and their mass accumulation rates (MAR) at the six sites recovered from the SCS during the "Resolution" ODP Leg 184 and "Sonne" 95 cruise of the Sino-Germany cooperation, opal % and their MARs increased evidently in the northern sites since 470-900 ka, and they enhanced and reduced, respectively, during the glacial and interglacial periods. Whereas they increased obviously in the southern sites since 420-450 ka,and they augmented and declined, respectively, during the interglacial and glacial periods. The variability in opal % and their MARs in the late Quaternary glacial cyclicity indicate the "seesaw" pattern of surface productivity in the SCS. The winter monsoon intensified during the glacial periods, surface productivity increased and decreased, respectively, in the northern and southern SCS. The summer monsoon strengthened during the interglacial periods, surface productivity increased and decreased,respectively, in the southern and northern SCS. The cross spectral analyses between the opal % in the northern and southern SCS during the Quaternary and global ice volume (δ18O) and orbital forcing (ETP) indicate that the East Asian winter and summer monsoons could be ascribed to the different drive mechanisms. On the orbital time scale, the global ice volume change could be a dominant factor for the winter monsoon intension and temporal variations. As compared with the winter monsoon, the correlative summer solar radiation with the obliquity and precession in the Northern Hemisphere could be a mostly controlling factor for the summer monsoon intension and temporal variations.

  16. Quaternary biogenic opal records in the South China Sea: Linkages to East Asian monsoon, global ice volume and orbital forcing

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Particulate fluxes investigated in the central South China Sea (SCS) during 1993―1996 indicate that opal flux can be used to show primary productivity change, which provides a foundation for tracing the evolutionary relationship between the surface productivity and East Asian monsoon in the SCS during the late Quaternary glacial and interglacial periods. Based on the studies of opal % and their mass accumulation rates (MAR) at the six sites recovered from the SCS during the “Resolution” ODP Leg 184 and “Sonne” 95 cruise of the Sino-Germany cooperation, opal % and their MARs increased evidently in the northern sites since 470―900 ka, and they enhanced and reduced, respectively, during the glacial and interglacial periods. Whereas they increased obviously in the southern sites since 420―450 ka, and they augmented and declined, respectively, during the interglacial and glacial periods. The vari- ability in opal % and their MARs in the late Quaternary glacial cyclicity indicate the “seesaw” pattern of surface productivity in the SCS. The winter monsoon intensified during the glacial periods, surface productivity increased and decreased, respectively, in the northern and southern SCS. The summer monsoon strengthened during the interglacial periods, surface productivity increased and decreased, respectively, in the southern and northern SCS. The cross spectral analyses between the opal % in the northern and southern SCS during the Quaternary and global ice volume (δ 18O) and orbital forcing (ETP) indicate that the East Asian winter and summer monsoons could be ascribed to the different drive mechanisms. On the orbital time scale, the global ice volume change could be a dominant factor for the winter monsoon intension and temporal variations. As compared with the winter monsoon, the correlative summer solar radiation with the obliquity and precession in the Northern Hemisphere could be a mostly controlling factor for the summer monsoon intension and

  17. River terraces and alluvial fans: The case for an integrated Quaternary fluvial archive

    Science.gov (United States)

    Mather, A. E.; Stokes, M.; Whitfield, E.

    2017-06-01

    The fluvial archive literature is dominated by research on river terraces with appropriate mention of adjacent environments such as lakes. Despite modern sedimentary basins comprising a significant (>88%) volume of distributive fluvial systems, of which alluvial fans (>1 km, archive community. Published literature is used to examine both thematic and geographical based benefits of alluvial fan research that can assist understanding of Quaternary fluvial archives. 3 regional case studies are presented that illustrate the interaction between alluvial fan and river terrace archives at Quaternary time-scales at 3 different stages of landscape evolution. These are i) continuous mountain front alluvial fans interacting with a non incising but laterally eroding axial fluvial system; ii) alluvial fans which transition into fluvial terraces as sedimentary basins shift from net aggradation to net incision and iii) tributary-junction alluvial fans that develop predominantly within incising river valley systems. A simple conceptual model is proposed to summarise the dynamic role of alluvial fans within this landscape context. The alluvial fans act as potential 'buffers' between hillslopes and river terrace records under 'top down' climate-driven high sediment supply and alluvial fan aggradation, and 'couplers' during periods of less sediment (in relation to water) discharge and alluvial fan incision. These dynamics will change with the addition of 'bottom up' controls such as main river incision, which will typically enhance the coupling effect of both systems.

  18. Albedo changes, Milankovitch forcing, and late quaternary climate changes in the central Andes

    Energy Technology Data Exchange (ETDEWEB)

    Kull, C.; Grosjean, M. [Swiss Federal Inst. of Tech., Zurich (Switzerland). Dept. of Geography

    1998-11-01

    Late quaternary humidity changes resulted in substantial modifications of the land surface characteristics in the Altiplano of the Atacama desert, central Andes. Reconstructions of surface albedo, top-of-atmosphere (TOA) albedo, and shortwave net radiation in the Andes of northern Chile for 20,14,10,7 and 0 ka suggest that surface and TOA albedo increased substantially during periods of relatively humid environmental conditions (i.e., with large palaeolakes, glaciers and dense vegetation). The decrease of summer shortwave net radiation and seasonality during the late-glacial/early Holocene humid phase (14 to 10 ka) due to Earth`s surface and atmospheric characteristics added to the effect of orbitally driven negative deviations of southern Hemisphere austral summer insolation and minimum seasonality at 20 S. Therefore, in situ radiative forcing is, in contrast to the Northern Hemisphere tropics, not a suitable explanation for enhanced convective precipitation and, ultimately, humid climatic conditions. Our results suggest that late Quaternary humidity changes on the Altiplano reflect a collective response to (1) environmental changes in the source area of the moisture (e.g., reexpansion of the rain forest and increased release of latent heat over Amazonia and the Chaco, warm sea surface temperatures in the E Pacific) and, (2) large-scale circulation patterns and wave structures in the upper troposphere (strength and position of the Bolivian high, divergent flow stimulating convection over the Altiplano), or that they even reflect a response to (3) interhemispherical teleconnections. (orig.) With 5 figs., 2 tabs., 45 refs.

  19. Periodic paralysis.

    Science.gov (United States)

    Fontaine, Bertrand

    2008-01-01

    Periodic paralyses are rare diseases characterized by severe episodes of muscle weakness concomitant to variations in blood potassium levels. It is thus usual to differentiate hypokalemic, normokalemic, and hyperkalemic periodic paralysis. Except for thyrotoxic hypokalemic periodic paralysis and periodic paralyses secondary to permanent changes of blood potassium levels, all of these diseases are of genetic origin, transmitted with an autosomal-dominant mode of inheritance. Periodic paralyses are channelopathies, that is, diseases caused by mutations in genes encoding ion channels. The culprit genes encode for potassium, calcium, and sodium channels. Mutations of the potassium and calcium channel genes cause periodic paralysis of the same type (Andersen-Tawil syndrome or hypokalemic periodic paralysis). In contrast, distinct mutations in the muscle sodium channel gene are responsible for all different types of periodic paralyses (hyper-, normo-, and hypokalemic). The physiological consequences of the mutations have been studied by patch-clamp techniques and electromyography (EMG). Globally speaking, ion channel mutations modify the cycle of muscle membrane excitability which results in a loss of function (paralysis). Clinical physiological studies using EMG have shown a good correlation between symptoms and EMG parameters, enabling the description of patterns that greatly enhance molecular diagnosis accuracy. The understanding of the genetics and pathophysiology of periodic paralysis has contributed to refine and rationalize therapeutic intervention and will be without doubts the basis of further advances.

  20. Quaternary Evolution of North Core Sound Sound, North Carolina

    Science.gov (United States)

    Dietsche, Andrew

    Northern Core Sound is a shallow lagoonal estuary located behind the Outer Banks barrier islands of eastern North Carolina. Thirty-two vibracores and 155 km of chirp and boomer seismic data have been used to define the geologic framework and establish the Holocene evolution of this back-barrier lagoon. Vibracores have been logged for lithology, and sampled to establish the distribution and abundance of foraminifera. The lithostratigraphy and biofacies could not be directly correlated but when related to the seismic data, apparent patterns could be recognized. The Quaternary stratigraphic framework of North Core Sound consists of five depositional sequences, comprising transgressive, highstand, and falling stage systems tracts. Seismic reflections are prominent and are correlated to the sequence stratigraphic surfaces within Pamlico Sound defined by Mallinson et al. (2010). The late Pleistocene paleotopographic surface dips slightly seaward and is characterized by two or three fluvial channels correlating to modern embayments. These channels are separated by a paleotopographic high that extends from Cedar Island seaward. The channels run northeast in the north and southwest in the south creating two different paleo-environments. The paleotopographic high may have contributed to differing foraminiferal assemblages found within Holocene unit. The Holocene unit is characterized by high salinity estuarine deposits dominated by the foraminifera Elphidium excavatum and Ammonia parkinsoniana. Three very similar biofacies were defined with more abundant Ammonia parkinsoniana where salinities may have been slightly lower. Only a salt marsh facies was significantly different. The biofacies may also represent the two paleo-environments illustrated in the seismic data as one is mainly found to the north of the paleotopographic high and the other to the south. Two seismic reflections, H30 and H60, are interpreted as tidal ravinement surfaces and divide the Holocene into three

  1. Environmental Magnetic Signature Of Late Quaternary Climate and Paleoceanography in the Bering Sea

    Science.gov (United States)

    Platzman, E. S.; Lund, S.; Kirby, M. E.

    2014-12-01

    High latitude drilling during IODP expedition 323 in the Bering Sea provides a unique opportunity to study in detail the evolution of Quaternary paleoceanography, climate and glacial history of the Bering Sea gateway to the Arctic Ocean. Our study focuses on a 400 ky interval of Quaternary marine sediments cored along the Bering Slope. Samples for magnetic analysis were obtained from sites U1339, U1343, U1344, U1345, at depths of 1008-3484 m. Sediments in these cores are a mixture of siliclastic material, derived primarily from terrigeneous sources, and biogenic material. Detailed measurements of the variation in bulk magnetic properties including natural remanent magnetization (NRM), susceptibility, ARM, and IRM, have been used to monitor changes in concentration, composition and grainsize of the magnetic components. In addition, sediment grain size analysis was preformed on biogenic free aliquots at selected intervals. Our results indicate that the dramatic bimodal magnetic intensity signal that alternates between a strong and weak NRM and magnetic susceptibility is associated with relatively course and fine grain sizes repectively. This is the opposite to the pattern estimated by our initial IODP Ex. 323 reports. Current models propose that, as has been observed in the North Atlantic, high intensities are likely to be related to high contributions of terrigenous and glaciomarine sediments deposited during glacial periods and low intensities are likely to occur during interglacials when continental sediments become trapped on the on the shelf. Contrary to this hypothesis, however, we find compelling evidence for a substantial increase in terrigenous input during the interglacial periods and what appears to be a predominantly pelagic signal during the glacial periods. Comparison of our data with other proxy data including oxygen isotopes, NGR, GRA allows us to investigate the possible causal links between these changes and the environmental history of the North

  2. Irregular Periods

    Science.gov (United States)

    ... blood become too low or too high. Some women have irregular periods because their bodies produce too much androgen, which is a hormone that causes increased muscle mass, facial hair, and deepening of the voice in males and ...

  3. Period Pain

    Science.gov (United States)

    ... You may also have other symptoms, such as lower back pain, nausea, diarrhea, and headaches. Period pain is not ... Taking a hot bath Doing relaxation techniques, including yoga and meditation You might also try taking over- ...

  4. Agulhas leakage as a key process in the modes of Quaternary climate changes.

    Science.gov (United States)

    Caley, Thibaut; Giraudeau, Jacques; Malaizé, Bruno; Rossignol, Linda; Pierre, Catherine

    2012-05-01

    Heat and salt transfer from the Indian Ocean to the Atlantic Ocean (Agulhas leakage) has an important effect on the global thermohaline circulation and climate. The lack of long transfer record prevents elucidation of its role on climate changes throughout the Quaternary. Here, we present a 1,350-ka accumulation rate record of the planktic foraminiferal species Globorotalia menardii. We demonstrate that, according to previous assumptions, the presence and reseeding of this fauna in the subtropical southeast Atlantic was driven by interocean exchange south of Africa. The Agulhas transfer strengthened at glacial ice-volume maxima for every glacial-interglacial transition, with maximum reinforcements organized according to a 400-ka periodicity. The long-term dynamics of Agulhas leakage may have played a crucial role in regulating meridional overturning circulation and global climate changes during the Mid-Brunhes event and the Mid-Pleistocene transition, and could also play an important role in the near future.

  5. Climate change not to blame for late Quaternary megafauna extinctions in Australia.

    Science.gov (United States)

    Saltré, Frédérik; Rodríguez-Rey, Marta; Brook, Barry W; Johnson, Christopher N; Turney, Chris S M; Alroy, John; Cooper, Alan; Beeton, Nicholas; Bird, Michael I; Fordham, Damien A; Gillespie, Richard; Herrando-Pérez, Salvador; Jacobs, Zenobia; Miller, Gifford H; Nogués-Bravo, David; Prideaux, Gavin J; Roberts, Richard G; Bradshaw, Corey J A

    2016-01-29

    Late Quaternary megafauna extinctions impoverished mammalian diversity worldwide. The causes of these extinctions in Australia are most controversial but essential to resolve, because this continent-wide event presaged similar losses that occurred thousands of years later on other continents. Here we apply a rigorous metadata analysis and new ensemble-hindcasting approach to 659 Australian megafauna fossil ages. When coupled with analysis of several high-resolution climate records, we show that megafaunal extinctions were broadly synchronous among genera and independent of climate aridity and variability in Australia over the last 120,000 years. Our results reject climate change as the primary driver of megafauna extinctions in the world's most controversial context, and instead estimate that the megafauna disappeared Australia-wide ∼13,500 years after human arrival, with shorter periods of coexistence in some regions. This is the first comprehensive approach to incorporate uncertainty in fossil ages, extinction timing and climatology, to quantify mechanisms of prehistorical extinctions.

  6. Late Quaternary fine silt deposits of Jammu, NW Himalaya: Genesis and climatic significance

    Indian Academy of Sciences (India)

    Rajinder K Ganjoo; Vinod Kumar

    2012-02-01

    The fine silt deposits of Jammu (J & K State, India) stretch all along the Siwalik foothills from Jammu to the Potwar Plateau in Pakistan. The post-Siwalik deposits, first discussed by de Terra and Paterson (1939), are attributed to wind action. The deposits termed as ‘Potwar loessic silt’ comprising sandy silt are essentially of late Quaternary age (75–18 ka) and are re-looked herein from the point of view of genesis and climatic significance. The sorting, skewness and kurtosis parameters of fine silts of Jammu suggest fluvial environment of the deposits wherein the water budget fluctuated. The weak pedogenesis of fine silts at certain intervals corroborate to periods of less or no sedimentation. The bivariant plot studies further suggest fluvial environment of deposition for the fine silt at Jammu, with regular fluctuations in the budget of river water that was perhaps in consonance with oscillations in the climate of the region.

  7. Active tectonics of the Oran (Algeria) Quaternary plain

    Science.gov (United States)

    youcef, Bouhadad; rabah, Bensalem; e-hadi, oubaiche

    2016-04-01

    The Oran region, in north-western Algeria, has been hit several times in the past by destructive moderate-sized and strong earthquakes. The Oran October 9th , 1790 (I0= X) was among the strongest seismic events in the western Mediterranean area comparable, if we consider the described effects, to the El- Asnam (1980, Ms=7.3) and Zemmouri (2003, Mw=6.8) earthquakes. Such strong seismic events requires the presence of major active geological structures that are re-activated several times in the past. In this work we present results of a multi- disciplinary study combining geomorphic analysis, field earthquake geological investigations and geophysical methods, undertaken to study the southern border of the Oran Quaternary plain. A 50 km long, SW-dipping and NE-SW trending active fault has been identified that showing clear quaternary deformation. Keywords: earthquake geology, active fault, geomorphic, geophysics, Algeria.

  8. Synthesis and Antibacterial Activity of Novel Quaternary Ammonium Pyridoxine Derivatives.

    Science.gov (United States)

    Shtyrlin, Nikita V; Sapozhnikov, Sergey V; Koshkin, Sergey A; Iksanova, Alfiya G; Sabirov, Arthur H; Kayumov, Airat R; Nureeva, Aliya A; Zeldi, Marina I; Shtyrlin, Yurii G

    2015-01-01

    A series of 26 quaternary ammonium pyridoxine derivatives were synthesized and their cytotoxicity and antibacterial activities against clinically relevant bacterial strains were tested in vitro. The antibacterial activity of mono-ammonium salts increased with the rise of the lipophilicity and compound 3,3,5-trimethyl-8,8-dioctyl-1,7,8,9-tetrahydro-[1,3]dioxino[5,4-d]pyrrolo[3,4-b]pyridin-8-ium chloride (2d) reaches a maximum among them. Bis-ammonium salt of pyridoxine 4 with two dimethyloctylamine groups also demonstrated high antibacterial activity despite lower lipophilicity. The results of MTT assay indicated that HEK 293 cells were more sensitive than HSF to quaternary ammonium pyridoxine derivatives. Compounds 2d and 4 did not induce the damage of the DNA and might be of interest in the development of new antimicrobials.

  9. New quantum codes constructed from quaternary BCH codes

    Science.gov (United States)

    Xu, Gen; Li, Ruihu; Guo, Luobin; Ma, Yuena

    2016-10-01

    In this paper, we firstly study construction of new quantum error-correcting codes (QECCs) from three classes of quaternary imprimitive BCH codes. As a result, the improved maximal designed distance of these narrow-sense imprimitive Hermitian dual-containing quaternary BCH codes are determined to be much larger than the result given according to Aly et al. (IEEE Trans Inf Theory 53:1183-1188, 2007) for each different code length. Thus, families of new QECCs are newly obtained, and the constructed QECCs have larger distance than those in the previous literature. Secondly, we apply a combinatorial construction to the imprimitive BCH codes with their corresponding primitive counterpart and construct many new linear quantum codes with good parameters, some of which have parameters exceeding the finite Gilbert-Varshamov bound for linear quantum codes.

  10. Alpha-Crystallin: The Quest For A Homogeneous Quaternary Structure

    Science.gov (United States)

    Horwitz, Joseph

    2009-01-01

    Alpha A and alpha B crystallins are key members of the small heat-shock protein family. In addition to being a major structural protein of the lens, they are constitutively found in many other cells, where their function to is not completely understood. Alpha B crystallin is also known to be over-expressed in many neurological diseases. To date, all efforts to crystallize alpha A or alpha B have failed. Thus, high-resolution data on the tertiary and quaternary structure of alpha crystallin is not available. The main reason for this failure seems to be the polydisperse nature of alpha crystallin. This review deals mainly with the polydisperse properties of alpha crystallin and the influence of post-translational modification, chemical modifications, truncations and mutation on its quaternary structure. PMID:18703051

  11. Distribution of acidic groundwater around quaternary volcanoes in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Asamori, Koichi; Ishimaru, Tsuneari; Iwatsuki, Teruki [Japan Nuclear Cycle Development Inst., Toki, Gifu (Japan). Tono Geoscience Center

    2002-06-01

    One important key issue in the understanding of the long-term stability of the geological environment is the influence of magmatism. In this study, we examined the general spatial distribution of acidic groundwater around Quaternary volcanoes in Japan using a database of groundwater geochemistry. The results may be summarized as follows: Acidic groundwater with pH < 4.8 mainly occur in present volcanic regions and are distributed from several kilometers to about 20 km from Quaternary volcanoes. The pH value of groundwater tends to decrease with increasing distance from a volcano. However, these results may be affected by inhomogeneity of groundwater data distribution and the characteristic activity of each volcano. In order to assess a specific volcanic region, a detailed analysis that considers volcanic activity, using a data set with high spatial density is necessary. (author)

  12. Studies on a Cationically Modified Quaternary Ammonium Salt of Lignin

    Institute of Scientific and Technical Information of China (English)

    YANG Ai-li; JIANG Wen-ju

    2007-01-01

    A new quaternary ammonium salt monomer was synthesized and a quaternary amination of lignin( noted as QL),with the monomer was carried out by grafting copolymerization. The products were characterized by Fourier Transform Infrared spectroscopy(FTIR). The experimental results indicate that the yield of the monomer was 99.06%, and the conversion of the monomer and the grafting yield of QL were 93.69% and 185.78%, respectively. The feasibility of QL as the fiocculant to be applied in color removal of five artificial dyes, eriochrome black T( dye A), gongo red( dye B), direct fast black G (dye C), cuprofix blue green B (dye D), and acid black ATT (dye E) was examined.Results show that QL exhibits the favorable flocculation performance and high stability.

  13. A Synthetic Route to Quaternary Pyridinium Salt-Functionalized Silsesquioxanes

    Directory of Open Access Journals (Sweden)

    Nataliya Kostenko

    2012-01-01

    Full Text Available A synthetic route to potentially biocidal silsesquioxanes functionalized by quaternary pyridinium functionalities has been developed. N-Alkylation reactions of the precursor compounds 4-(2-(trimethoxysilylethyl-pyridine (5 and 4-(2-trichloro-silylethylpyridine (6 with iodomethane, n-hexylbromide, and n-hexadecylbromide cleanly afforded the corresponding N-alkylpyridinium salts (7–10. The synthesis of a 4-(2-ethylpyridine POSS derivative (2 was achieved by capping of the silsesquioxane trisilanol Cy7Si7O9(OH3 (1 via two different preparative routes. Attempts to use compound 2 as precursor for quaternary pyridinium salt-functionalized POSS derivatives were met with only partial success. Only the reaction with iodomethane cleanly afforded the new N-methylpyridinium salt 12 in high yield, whereas n-hexylbromide and n-hexadecylbromide failed to react with 2 even under forcing conditions.

  14. Geological provenance of Quaternary deposits from the southeastern Brazilian coast

    Energy Technology Data Exchange (ETDEWEB)

    Anjos, R.M. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil)]. E-mail: meigikos@if.uff.br; Veiga, R. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil); Carvalho, C. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil); Macario, K.D. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil); Gomes, P.R.S. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil)

    2007-05-01

    Natural gamma radiation measurements of beach sand deposits were performed with the aim of understanding the provenance and transport processes of sediments along the coastal zone of three Brazilian States. The method employs thorium, uranium and potassium as tracers of the mineralogical properties of beach sand minerals, which reflect the geological history of transport and sorting processes. A considerable positive correlation with the geological evolution of these Quaternary coastal deposits was observed.

  15. The impact of Quaternary Ice Ages on mammalian evolution.

    Science.gov (United States)

    Lister, Adrian M

    2004-02-29

    The Quaternary was a time of extensive evolution among mammals. Most living species arose at this time, and many of them show adaptations to peculiarly Quaternary environments. The latter include continental northern steppe and tundra, and the formation of lakes and offshore islands. Although some species evolved fixed adaptations to specialist habitats, others developed flexible adaptations enabling them to inhabit broad niches and to survive major environmental changes. Adaptation to short-term (migratory and seasonal) habitat change probably played a part in pre-adapting mammal species to the longer-term cyclical changes of the Quaternary. Fossil evidence indicates that environmental changes of the order of thousands of years have been sufficient to produce subspeciation, but speciation has typically required one hundred thousand to a few hundred thousand years, although there are both shorter and longer exceptions. The persistence of taxa in environments imposing strong selective regimes may have been important in forcing major adaptive change. Individual Milankovitch cycles are not necessarily implicated in this process, but nor did they generally inhibit evolutionary change among mammals: many evolutionary divergences built over multiple climatic cycles. Deduction of speciation timing requires input from fossils and modern phenotypic and breeding data, to complement and constrain mitochondrial DNA coalescence dates which appear commonly to overestimate taxic divergence dates and durations of speciation. Migrational and evolutionary responses to climate change are not mutually exclusive but, on the contrary, may be synergistic. Finally, preliminary analysis suggests that faunal turnover, including an important element of speciation, was elevated in the Quaternary compared with the Neogene, at least in some biomes. Macroevolutionary species selection or sorting has apparently resulted in a modern mammalian fauna enriched with fast-reproducing and/or adaptively

  16. Quaternary fossil fauna from the Luangwa Valley, Zambia.

    OpenAIRE

    Bishop, LC; Barham, LS; Ditchfield, P.; Elton, S; Harcourt-Smith, WH; Dawkins, P

    2016-01-01

    This paper describes a large collection of Quaternary fossil fauna from the Luangwa rift valley, Zambia. Stone Age artefacts have been recovered from stratified fluvial contexts, but no in situ fossil fauna have yet been recovered. We report on 500 fossil specimens collected from the surface of point bars exposed seasonally along the banks of the main Luangwa river channel. We used non-destructive x-ray fluorescence analysis of the fossils' chemical signatures to determine whether they derive...

  17. Micromorphological investigations of the Late Quaternary loess-paleosol sequences of the Kashmir Valley, India

    Science.gov (United States)

    Dar, Reyaz Ahmad; Chandra, Rakesh; Romshoo, Shakil Ahmad; Kowser, Nazia

    2015-11-01

    The loess-paleosol sequences of the Karewa Group preserve a valuable repository of the Late Quaternary climatic changes and the landscape evolution history of the Karewa Basin of Kashmir Valley in their lithological and pedogenic records. Three representative loess-paleosol sections at Shankerpora (SP), Khan Sahib (KS) and Pattan (PT) localities were chosen for detailed lithostratigraphic fieldwork and micromorphological observations of thin sections. Lithostratigraphic analysis revealed lateral and vertical variation in thickness and number of paleosol profiles from south-west to north-west of the Karewa Basin suggesting the availability of land-surface for periodic loess deposition. The SP section is marked by 6 (SP-S6, S7, S8, S9, S10, S12), KS section by 3 (KS-S2, S4, S5) and PT section by 2 (PT-S1, S3) thick mature paleosol profiles. Theses paleosols have well developed 'Ah' and 'Btk' horizons representing prolonged land-surface stability when pedogenic processes outpace loess deposition. On the other hand comparatively thin to thick paleosol profiles represent weak to moderate pedogenic maturity indicating short stratigraphic breaks with rapid loess deposition. Micromorphological observations of thin sections suggested that clay illuviation and CaCO3 accumulation have operated within the paleosol profiles. CaCO3 features are often associated with clay coatings suggesting decalcification of carbonates followed by clay illuviation. Pedogenic CaCO3 probably resulted from the precipitation of the soil solution near the average depth of wetting front. The pedogenic CaCO3, illuvial clay, mottles, iron manganese features, pedal microstructure and blocky aggregates reveal variation in the pedogenic maturity among and within the loess-paleosol sections. The morphological (both micro- and macro-morphological) attributes of loess-paleosols suggest variation of climatic conditions during the Late Quaternary period in the Karewa Basin of Kashmir Valley, India.

  18. Microstructure development in Al-Cu-Ag-Mg quaternary alloy

    Science.gov (United States)

    Zhou, Bin; Froyen, L.

    2012-01-01

    The solidification behaviour of multi-component and multi-phase systems has been largely investigated in binary and ternary alloys. In the present study, a quaternary model system is proposed based on the well known Al-Cu-Ag and Al-Cu-Mg ternary eutectic alloys. The quaternary eutectic composition and temperature were determined by EDS (Energy Dispersive Spectrometry) and DSC (Differential Scanning Calorimetry) analysis, respectively. The microstructure was then characterised by SEM (Scanning Electron Microscope). In the DSC experiments, two types of quaternary eutectics were determined according to their phase composition. For each type of eutectic, various microstructures were observed, which result in different eutectic compositions. Only one of the determined eutectic compositions was further studied by the controlled growth technique in a vertical Bridgeman type furnace. In the initial part of the directionally solidified sample, competing growth between two-phase dendrites and three-phase eutectics was obtained, which was later transformed to competing growth between three-phase and four-phase eutectics. Moreover, silver enrichment was measured at the solidification front, which is possibly caused by Ag sedimentation due to gravity and Ag rejection from dendritic and three-phase eutectic growth, and its accumulation at the solidification front.

  19. Periodic behaviors

    CERN Document Server

    Napp, Diego; Shankar, Shiva

    2010-01-01

    This paper studies behaviors that are defined on a torus, or equivalently, behaviors defined in spaces of periodic functions, and establishes their basic properties analogous to classical results of Malgrange, Palamodov, Oberst et al. for behaviors on R^n. These properties - in particular the Nullstellensatz describing the Willems closure - are closely related to integral and rational points on affine algebraic varieties.

  20. PERIODIC BEHAVIORS

    NARCIS (Netherlands)

    Napp, Diego; Put, Marius van der; Shankar, Shiva

    2010-01-01

    This paper studies behaviors that are defined on a torus, or equivalently, behaviors defined in spaces of periodic functions, and establishes their basic properties analogous to classical results of Malgrange, Palamodov, Oberst et al. for behaviors on R(n). These properties-in particular the Nullste

  1. Quaternary tectonic faulting in the Eastern United States

    Science.gov (United States)

    Wheeler, R.L.

    2006-01-01

    Paleoseismological study of geologic features thought to result from Quaternary tectonic faulting can characterize the frequencies and sizes of large prehistoric and historical earthquakes, thereby improving the accuracy and precision of seismic-hazard assessments. Greater accuracy and precision can reduce the likelihood of both underprotection and unnecessary design and construction costs. Published studies proposed Quaternary tectonic faulting at 31 faults, folds, seismic zones, and fields of earthquake-induced liquefaction phenomena in the Appalachian Mountains and Coastal Plain. Of the 31 features, seven are of known origin. Four of the seven have nontectonic origins and the other three features are liquefaction fields caused by moderate to large historical and Holocene earthquakes in coastal South Carolina, including Charleston; the Central Virginia Seismic Zone; and the Newbury, Massachusetts, area. However, the causal faults of the three liquefaction fields remain unclear. Charleston has the highest hazard because of large Holocene earthquakes in that area, but the hazard is highly uncertain because the earthquakes are uncertainly located. Of the 31 features, the remaining 24 are of uncertain origin. They require additional work before they can be clearly attributed either to Quaternary tectonic faulting or to nontectonic causes. Of these 24, 14 features, most of them faults, have little or no published geologic evidence of Quaternary tectonic faulting that could indicate the likely occurrence of earthquakes larger than those observed historically. Three more features of the 24 were suggested to have had Quaternary tectonic faulting, but paleoseismological and other studies of them found no evidence of large prehistoric earthquakes. The final seven features of uncertain origin require further examination because all seven are in or near urban areas. They are the Moodus Seismic Zone (Hartford, Connecticut), Dobbs Ferry fault zone and Mosholu fault (New York

  2. Lithostratigraphic development and neotectonic significance of the Quaternary sediments along the Kachchh Mainland Fault (KMF) zone, western India

    Indian Academy of Sciences (India)

    V Chowksey; D M Maurya; Parul Joshi; N Khonde; Archana Das; L S Chamyal

    2011-12-01

    tectonically controlled incision and dissection of the Quaternary deposits is the result of neotectonic activity that continues at present day. The overall nature, sedimentary characteristics and geomorphic setting of the sediments suggest that the KMF remained neotectonically active throughout the Quaternary period.

  3. Virucidal activity of a quaternary ammonium compound disinfectant against feline calicivirus: a surrogate for norovirus.

    Science.gov (United States)

    Jimenez, Luis; Chiang, Michael

    2006-06-01

    Norovirus, formerly known as Norwalk virus, is an important cause of gastroenteritis outbreaks in hospitals, food services, schools, and cruise ships. Infection control practices by using disinfectants to eliminate noroviruses from surfaces and environmental samples reduce the morbidity and spread of virus outbreaks. There are not many commercial disinfectants effective against norovirus. Noroviruses cannot be cultivated in vitro. However, feline calicivirus can be used as a surrogate to determine disinfectant efficacy against noroviruses. Feline calicivirus was used in a virucidal effectiveness test protocol as a surrogate for norovirus to determine the virucidal efficacy of R-82, a quaternary ammonium compound disinfectant cleaner. Feline calicivirus suspensions containing at least 5% fetal bovine serum were dried on carriers and treated with 1:256 dilutions of R-82 disinfectant in water, with a hardness of 400 ppm as calcium carbonate, for 10 minutes. Hypochlorite concentrations of 100 +/- 10 and 1,000 +/- 10 ppm, respectively, were also analyzed as internal control standards. After contact period, the test agents were neutralized with 2 mL of appropriate neutralizer, and mixtures were scraped from carrier surfaces with a cell scraper. Selected dilutions of the neutralized inoculum/test agent mixtures were added to cultured cell monolayers of appropriate host cells. Postincubation, the infectious feline calicivirus was scored microscopically by observing virus-specific cytopathic effects produced by replicating infectious virus. The performance criterion was a minimum of 4-log(10) reduction in cytopathic effects of feline calicivirus. After a 10-minute contact time, formulation R-82 diluted 1:256 showed a 6.6- and 6.4-log(10) reductions in cytopathic effects of feline calicivirus during initial and confirmatory testing, respectively, demonstrating complete inactivation of the virus. A hypochlorite solution of 1,000 ppm exhibited similar log(10) reductions to the

  4. Genetic and morphological consequences of Quaternary glaciations: A relic barbel lineage (Luciobarbus pallaryi, Cyprinidae) of Guir Basin (Algeria).

    Science.gov (United States)

    Brahimi, Amina; Tarai, Nacer; Benhassane, Abdelkrim; Henrard, Arnaud; Libois, Roland

    2016-02-01

    Climatic variations during the Quaternary period had a considerable impact on landscapes and habitat fragmentation (rivers) in North Africa. These historical events can have significant consequences on the genetic structure of the populations. Indeed, geographically separated and genetically isolated populations tend to differentiate themselves through time, eventually becoming distinct lineages, allowing new species to emerge in later generations. The aim of the present study is to use genetic and morphological techniques to evaluate the major role of the Saalian glaciation (Middle Quaternary) in the establishment of the geographic space and in the evolution of the intraspecific genetic diversity, by tracing the demographic history of barbels belonging to the Luciobarbus pallaryi (Cyprinidae) species in the Guir Basin (Algeria). In this context, two populations, from two distinct and isolated sites, were studied. Analysis of the cytochrome b (cyt b) mitochondrial markers and of the "D-loop" control region has shown that the "upstream" and "downstream" Guir populations are genetically differentiated. The molecular analyses suggest that the upstream population was disconnected from this hydrographic system during the Saalian glaciation period of the Quaternary. Subsequently, it was isolated in the foggaras underground waters in the Great Western Erg, at approximately 320 000 years BP, creating, through a bottleneck effect, a new allopatric lineage referred to as "Adrar". Conversely, the high genetic diversity in the upstream Guir (Bechar) population suggests that the stock is globally in expansion. These barbels (n=52) were also examined with meristic, morphometric, osteological, and biological features. These data also reveal a complete discrimination between the two populations, with a remarkable and distinctive behavioural adaptation for the Adrar specimens: neoteny.

  5. Use-dependent block of cardiac sodium channels by quaternary derivatives of lidocaine.

    Science.gov (United States)

    Gintant, G A; Hoffman, B F

    1984-02-01

    Modulation of the reduction of fast inward sodium current by local anesthetics due to changes in electrical activity has been termed use-dependent block ( Courtney 1975). To determine the mechanisms responsible for use-dependent block of cardiac sodium channels and to compare use-dependent block in cardiac and nerve preparations, we investigated use-dependent block of cardiac sodium channels by the quaternary lidocaine analogues QX -314 and QX -222 (two agents previously studied in nerve). We used canine cardiac Purkinje fibers, and assessed changes in the fast inward sodium current using changes in the maximum rate of rise of the action potential upstroke (Vmax). Two microelectrode voltage clamp and current clamp techniques were used to control membrane potential prior to stimulated upstrokes . Use-dependent block was not affected by shortening the action potential duration during rapid stimulation. Partial recovery from use-dependent block was observed during rapid stimulation with brief depolarizing prepulses terminating immediately prior to the upstroke. Similar prepulses also prevented the development of use-dependent block following an abrupt increase in the stimulation rate. Hyperpolarizing prepulses during rapid stimulation caused recovery from use-dependent block; recovery was greater and more rapid with increasingly negative prepulses . Hyperpolarization during periods of electrical quiescence also caused greater recovery. These results, interpreted using the modulated receptor hypothesis ( Hille 1977; Hondeghem and Katzung 1977), suggest that use-dependent block of cardiac sodium channels by quaternary local anesthetics is due to drug association with the inactivated sodium channel receptor which occurs only after these drugs gain access to the receptor site through open sodium channels.

  6. Quaternary paleoceanographic reconstruction of Eastern Equatorial Pacific:planktic foraminiferal evidence

    Science.gov (United States)

    Mallick, Kirtiranjan; Sinha, Devesh K.; Singh, Ashutosh K.

    2016-04-01

    The Eastern Equatorial Pacific (EEP) is quite unique in its oceanographic set up and exhibits considerable variations on shorter to longer time scales. The region encounters intense upwelling caused by the Peru Current. The EEP show a strong ocean-atmosphere coupling, which is manifested in form of events like (El Nino Southern Oscillations (ENSO) that affects the global climate. The present work is based on planktic foraminiferal census data from the ODP Hole 846B, situated at 3°S latitude near the Galapagos spreading centre in the EEP, for paleoceanographic reconstructions for the Quaternary Period. Four species which show significant fluctuations in the relative abundance are Globigerinoides ruber (mixed layer and oligotrophic species), Neogloboquadrina dutertrei (fertility indicator and thermocline dweller),Globigerina bulloides (upwelling indicator) and Globorotalia inflata (temperate species). Results of the analyses of the census count of the planktic foraminifera indicate the overall dominance of the shallow water thermocline species N. dutertrei, suggesting the prevalence of the robust EEP Cold tongue during the Quaternary. The increase in the relative abundance of Gs.ruber marks seven planktic foraminiferal events (2.52Ma to 0.5Ma) of reduced strength of the cold tongue along the EEP. These intervals are concomitant with spreading and encroachment of warm water from the Western Pacific suggesting El Nino like conditions due to reduced strength of trade winds. Seven planktic foraminiferal events (2.42Ma to 0.20Ma) show prominent increase in the relative abundance of Gg.bulloides indicating advection of nutrient rich waters due to enhanced coastal upwelling. Invasion of the temperate species Globorotalia inflata is indicated by its abundance reaching up to 20 percent of the total assemblage at 3°S occur during ~ 2.07 Ma, 1.32 Ma and 1.05 Ma. The unusual occurrence of the cold water temperate species indicates the expansion of southern polar front which

  7. Paleontology to policy: the Quaternary history of Southeast Asian tapirs (Tapiridae) in relation to large mammal species turnover, with a proposal for conservation of Malayan tapir by reintroduction to Borneo.

    Science.gov (United States)

    of Cranbrook, Earl; Piper, Philip J

    2013-03-01

    The Southeast Asian zoogeographical region is divided into Indochinese, Sundaic and Philippine subregions. Two clades of tapirs, Tapirus spp., have been recognized in Quaternary Southeast Asia. A review of sites at which they occurred shows that representatives of both clades, one of which was the ancestral Malayan tapir Tapirus indicus, co-existed with a diversity of other Pleistocene mammal megafauna. The process of replacement of archaic large mammals was progressive and prolonged through the Quaternary. Zooarcheological investigation has extended knowledge of the former occurrence and distribution of tapirs and other large mammals of the region, with discoveries beyond the outer limits of their previously known ranges. These large mammals were subjected to paleoenvironmental changes as a consequence of the Quaternary cycles of glacial and interglacial periods. Archeological evidence suggests that hunting pressure has intensified the effects of altered environments, leading ultimately to the local disappearance of the Malayan tapir in most of Southeast Asia, including Borneo. The survival of the Malayan tapir through the Quaternary until the present shows that the species is both resilient to environmental change and flexible in its ecological re'uirements and, given proper protection, could continue to inhabit tropical Southeast Asia. To assist the species conservation, reintroduction is proposed from the remaining range of Malayan tapir in the wild, to suitable sites of past occurrence in Borneo, where these ancient survivors of the Quaternary megafauna can be accommodated and safeguarded alongside other forms of land usage.

  8. The Quaternary evolutionary history, potential distribution dynamics, and conservation implications for a Qinghai-Tibet Plateau endemic herbaceous perennial, Anisodus tanguticus (Solanaceae).

    Science.gov (United States)

    Wan, Dong-Shi; Feng, Jian-Ju; Jiang, De-Chun; Mao, Kang-Shan; Duan, Yuan-Wen; Miehe, Georg; Opgenoorth, Lars

    2016-04-01

    Various hypotheses have been proposed about the Quaternary evolutionary history of plant species on the Qinghai-Tibet Plateau (QTP), yet only a handful of studies have considered both population genetics and ecological niche context. In this study, we proposed and compared climate refugia hypotheses based on the phylogeographic pattern of Anisodus tanguticus (three plastid DNA fragments and nuclear internal transcribed spacer regions from 32 populations) and present and past species distribution models (SDMs). We detected six plastid haplotypes in two well-differentiated lineages. Although all haplotypes could be found in its western (sampling) area, only haplotypes from one lineage occurred in its eastern area. Meanwhile, most genetic variations existed between populations (F ST = 0.822). The SDMs during the last glacial maximum and last interglacial periods showed range fragmentation in the western area and significant range contraction in the eastern area, respectively, in comparison with current potential distribution. This species may have undergone intraspecific divergence during the early Quaternary, which may have been caused by survival in different refugia during the earliest known glacial in the QTP, rather than geological isolation due to orogenesis events. Subsequently, climate oscillations during the Quaternary resulted in a dynamic distribution range for this species as well as the distribution pattern of its plastid haplotypes and nuclear genotypes. The interglacial periods may have had a greater effect on A. tanguticus than the glacial periods. Most importantly, neither genetic data nor SDM alone can fully reveal the climate refugia history of this species. We also discuss the conservation implications for this important Tibetan folk medicine plant in light of these findings and SDMs under future climate models. Together, our results underline the necessity to combine phylogeographic and SDM approaches in future investigations of the Quaternary

  9. Quaternary chronostratigraphy and stable isotope paleoecology of Big Bone Lick, Kentucky, USA

    Science.gov (United States)

    Tankersley, Kenneth Barnett; Murari, Madhav Krishna; Crowley, Brooke E.; Owen, Lewis A.; Storrs, Glenn W.; Mortensen, Litsa

    2015-05-01

    Big Bone Lick (BBL) in northern Kentucky, USA has been a critical geologic site in the historical development of North American Quaternary vertebrate paleontology since the 1700s. Sedimentology, geoarcheology, paleontology, accelerator mass spectrometry radiocarbon and optically stimulated luminescence dating, and stable carbon and nitrogen isotope analyses were undertaken to develop a chronostratigraphy and history of erosion and deposition for the site to provide a foundation for understanding taphonomy, and species extinction and adaptation to periods of climatic and environmental change. Three geomorphic surfaces are recognized at BBL representing significant periods of floodplain aggradation since the last glacial maximum (26.5-19 ka) dating to the Oldest Dryas (Tazewell, 25-19 ka), the Older Dryas (Cary, 14-12 ka), and late Holocene (5 ka to the present). Unconformities suggest significant periods of degradation during the transitions from cold and dry to warm and moist climates from the Oldest Dryas (Tazewell) to Bølling Oscillation, from the Older Dryas (Cary) to the Allerød, and from the Younger Dryas (Valders) to the Holocene Climatic Optimum. Increased anthropogenic activities since 5 ka may have increased soil upland erosion and floodplain aggradation. Stable isotopes demonstrate that the landscape has been dominated by C3 vegetation since the last glacial maximum.

  10. Episodic Late Quaternary slopewash deposition as recorded in colluvial aprons, Southeastern Wyoming

    Science.gov (United States)

    Hanson, Paul R.; Mason, Joseph A.; Goble, Ronald J.

    2004-09-01

    Colluvial aprons found along fluvial terraces of the Laramie River and Sybille Creek in southeastern Wyoming are interpreted as late Quaternary slopewash deposits. Each apron studied contained multiple buried soils, interpreted to indicate that slopewash activity was episodic and short-lived, and was followed by relatively long periods of landscape stability and soil development. Apron deposits were described and subsequently correlated based on their internal stratigraphy and their relative degree of soil development. Optical dating was used to chronologically constrain periods of slopewash deposition, and based on 17 optical ages taken from five aprons, aggradation occurred at ˜65-56, 16.0, 12.9, 11.8, 8.1, 7.3, 5.0, and 1.7 ka. Several of these events correspond with climatic transitions such as the termination of Heinrich Event 1, the onset and termination of the Younger Dryas, and the 8.2 ka event, suggesting that apron aggradation was driven by changes in climatic regime. Although either increased aridity or a change in precipitation regime could result in increased erosion of terrace scarps, apron aggradation events do not correlate with regional records of aridity. Instead, periods of increased precipitation intensity and/or frequency that occur during climatic transitions most likely drive apron aggradation events.

  11. Modern and late Quaternary clay mineral distribution in the area of the SE Mediterranean Sea

    Science.gov (United States)

    Hamann, Yvonne; Ehrmann, Werner; Schmiedl, Gerhard; Kuhnt, Tanja

    2009-05-01

    The present-day clay mineral distribution in the southeastern Levantine Sea and its borderlands reveals a complex pattern of different sources and distribution paths. Smectite dominates the suspended load of the Nile River and of rivers in the Near East. Illite sources are dust-bearing winds from the Sahara and southwestern Europe. Kaolinite is prevalent in rivers of the Sinai, in Egyptian wadis, and in Saharan dust. A high-resolution sediment core from the southeastern Levantine Sea spanning the last 27 ka shows that all these sources contributed during the late Quaternary and that the Nile River played a very important role in the supply of clay. Nile influence was reduced during the glacial period but was higher during the African Humid Period. In contrast to the sharp beginning and end of the African Humid Period recorded in West African records (15 and 5.5 ka), our data show a more transitional pattern and slightly lower Nile River discharge rates not starting until 4 ka. The similarity of the smectite concentrations with fluctuations in sea-surface temperatures of the tropical western Indian Ocean indicates a close relationship between the Indian Ocean climate system and the discharge of the Nile River.

  12. Buried Quaternary Valleys In NW Europe - Aquifers and Drilling Hazards

    Science.gov (United States)

    Huuse, M.; Lykke-Andersen, H.; Piotrowski, J.

    Buried Quaternary valleys are extremely widespread in the formerly glaciated, low- land areas of NW Europe (Huuse &Lykke-Andersen 2000, Fig. 4). The valleys may be several hundred metres deep, some kilometres across and few to several tens of kilometres long. Most of the deep valleys have irregular length profiles with sills and basins, unlike standard subaerial river systems. We interpret these as overdeepened valleys, formed mainly by subglacial meltwater erosion. Buried valleys located on- shore often provide sheltered reservoirs of clean groundwater, and much attention is presently focused on locating onshore valleys and quantifying their potential as groundwater aquifers. In nearshore areas, buried valleys may be a risk factor by pro- viding pathways of salt-water intrusion of onshore groundwater aquifers. Far offshore, buried valleys are located in the shallow subsurface above the prolific oil and gas fields of the central North Sea. Here, the valleys pose a risk for drilling operations by hosting shallow gas and potentially unstable sediments. The central North Sea is now largely covered by 3D seismic data, which often image the buried valleys in a level of de- tail much greater than that available onshore. Hence offshore valleys imaged by 3D seismic data may be used as analogues for groundwater reservoirs onshore NW Eu- rope. Here, we present examples of buried valleys from onshore, nearshore and far offshore locations, to illustrate how genetically and morphologically identical valleys may benefit or hamper the exploitation of subsurface accummulations of groundwater and hydrocarbons. Huuse, M. &Lykke-Andersen, H. 2000. Buried Quaternary valleys in the eastern Dan- ish North Sea: morphology and origin. Quaternary Science Reviews 19, 1233-1253.

  13. The Quaternary thrust system of the northern Alaska Range

    Science.gov (United States)

    Bemis, Sean P.; Carver, Gary A.; Koehler, Richard D.

    2012-01-01

    The framework of Quaternary faults in Alaska remains poorly constrained. Recent studies in the Alaska Range north of the Denali fault add significantly to the recognition of Quaternary deformation in this active orogen. Faults and folds active during the Quaternary occur over a length of ∼500 km along the northern flank of the Alaska Range, extending from Mount McKinley (Denali) eastward to the Tok River valley. These faults exist as a continuous system of active structures, but we divide the system into four regions based on east-west changes in structural style. At the western end, the Kantishna Hills have only two known faults but the highest rate of shallow crustal seismicity. The western northern foothills fold-thrust belt consists of a 50-km-wide zone of subparallel thrust and reverse faults. This broad zone of deformation narrows to the east in a transition zone where the range-bounding fault of the western northern foothills fold-thrust belt terminates and displacement occurs on thrust and/or reverse faults closer to the Denali fault. The eastern northern foothills fold-thrust belt is characterized by ∼40-km-long thrust fault segments separated across left-steps by NNE-trending left-lateral faults. Altogether, these faults accommodate much of the topographic growth of the northern flank of the Alaska Range.Recognition of this thrust fault system represents a significant concern in addition to the Denali fault for infrastructure adjacent to and transecting the Alaska Range. Although additional work is required to characterize these faults sufficiently for seismic hazard analysis, the regional extent and structural character should require the consideration of the northern Alaska Range thrust system in regional tectonic models.

  14. Mutagenic activity of quaternary ammonium salt derivatives of carbohydrates

    Science.gov (United States)

    Sikora, Karol; Woziwodzka, Anna; Piosik, Jacek; Podgórska, Beata

    2016-01-01

    Summary This paper presents a study on a series of quaternary ammonium salt (QAS) derivatives of glucopyranosides with an elongated hydrophobic hydrocarbon chain. The new N-[6-(β-D-glucopyranosyloxy)hexyl]ammonium bromides and their O-acetyl derivatives were analyzed via 1H and 13C NMR spectroscopy. The mutagenic activity of the newly synthesized QAS was investigated using two different techniques: The Vibrio harveyi luminescence assay and the Ames test. The obtained results support previous findings contesting QAS safety and indicate that QAS, specifically pyridinium derivatives, might be mutagenic. PMID:27559394

  15. Mutagenic activity of quaternary ammonium salt derivatives of carbohydrates

    Directory of Open Access Journals (Sweden)

    Barbara Dmochowska

    2016-07-01

    Full Text Available This paper presents a study on a series of quaternary ammonium salt (QAS derivatives of glucopyranosides with an elongated hydrophobic hydrocarbon chain. The new N-[6-(β-D-glucopyranosyloxyhexyl]ammonium bromides and their O-acetyl derivatives were analyzed via 1H and 13C NMR spectroscopy. The mutagenic activity of the newly synthesized QAS was investigated using two different techniques: The Vibrio harveyi luminescence assay and the Ames test. The obtained results support previous findings contesting QAS safety and indicate that QAS, specifically pyridinium derivatives, might be mutagenic.

  16. Quaternary basaltic volcanism in the Payenia volcanic province, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina

    The extensive Quaternary volcanism in the Payenia volcanic province, Mendoza, Argentina, is investigated in this study by major and trace element analyses, Sr, Nd, Hf and Pb-isotopic analyses and Zr-Hf isotope dilution data on samples from almost the entire province. The samples are mainly...... in basalts from all the studied volcanic fields in Payenia is signs of lower crustal contamination indicating assimilation of, in some cases, large amounts of trace element depleted, mafic, plagioclase-bearing rocks. The northern Payenia is dominated by backarc basalts erupted between late Pliocene to late...

  17. Efficient formation of benzylic quaternary centers via palladium catalysis.

    Science.gov (United States)

    Gottumukkala, Aditya L; Suljagic, Jasmin; Matcha, Kiran; de Vries, Johannes G; Minnaard, Adriaan J

    2013-09-01

    Four's a crowd: An efficient protocol for the formation of benzylic quaternary centers via arylation of enones using a catalyst made from Pd(O2 CCF3 )2 and 2,2'-bipyridine is developed. For cyclic substrates, catalyst loadings as low as 1 mol % Pd are enough to afford excellent yields (>90%) using a variety of arylboronic acids. In case of acyclic substrates, the addition of KSbF6 was found to improve conversions and yields. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. A Quaternary Decision Diagram Machine: Optimization of Its Code

    Science.gov (United States)

    2010-08-01

    2026 IEICE TRANS. INF. & SYST., VOL.E93–D, NO.8 AUGUST 2010 INVITED PAPER Special Section on Multiple-Valued Logic and VLSI Computing A Quaternary...sequentially. A straightforward method to increase the speed is to increase the clock frequency. However, this is 2028 IEICE TRANS. INF. & SYST...reduce the 2030 IEICE TRANS. INF. & SYST., VOL.E93–D, NO.8 AUGUST 2010 Fig. 9 4-address QDD machine. Fig. 10 Branch instruction for 4-address QDD

  19. Cycling of phosphorus and manganese in the Arabian Sea during the Late Quaternary

    NARCIS (Netherlands)

    Scheanu, S.J.

    1999-01-01

    This thesis investigates phosphorus and manganese cycling in the Arabian Sea during the Late Quaternary, using sediment records recovered during the Netherlands Indian Ocean Programme (NIOP) in 1992. The first part is concerned with the reconstruction of Late Quaternary variability in

  20. Cycling of phosphorus and Manganese in the Arabian Sea during the Late Quaternary

    NARCIS (Netherlands)

    Schenau, S.J.

    1999-01-01

    This thesis investigates phosphorus and manganese cycling in the Arabian Sea during the Late Quaternary, using sediment records recovered during the Netherlands Indian Ocean Programme (NIOP) in 1992. The first part is concerned with the reconstruction of Late Quaternary variability in

  1. 40 CFR 721.10154 - Quaternary ammonium compounds, dicoco alkyldimethyl, chlorides, reaction products with silica.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Quaternary ammonium compounds, dicoco alkyldimethyl, chlorides, reaction products with silica. 721.10154 Section 721.10154 Protection of Environment... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10154 Quaternary ammonium...

  2. Paleoenvironmental Reconstruction of Late Quaternary Insect Fossils, Halashazi Site, Altai Region, China.

    Science.gov (United States)

    Zhang, Tianshu; Elias, Scott; Angus, Robert

    2017-04-01

    The Altai region northwest China, is located in the middle of arid central Asia and is therefore sensitive to climate change. However, there is a debate on the heat-moisture pattern (warm-dry pattern or cold-dry pattern) during the early Holocene in the Altai region, and a debate on the dominant atmospheric circulation (westerlies or monsoon) control for central Asian climate changes during the Holocene, and the mechanisms that cause the arid early Holocene in central Asia. Thus, the principal aim of the project is use the MCR method to produce quantified temperature and precipitation estimates, and a high-precision palaeoclimatic record for the Altai region, based on fossil beetle assemblages, to reveal the heat-moisture pattern and its mechanisms. This project will begin to fill in the blank of Quaternary beetle research in China. Using Quaternary beetles to reconstruct palaeoenvironments is a new research method for this region, and has never before been done in China, which will provide new evidence for the palaeoenvironmental study in this area. Furthermore, this project will contribute to the beetle faunal research in Eurasia. The sample site for this project - Halashazi Wetland (048°06'54"N, 088°21'48"E), is located at the crossroad of the Altai Mountains and the Dzungarian Basin, where two ecosystems meet. Thus the fossil beetle assemblages should show dramatic change in response to changes of climate. The sampled deposits are made up entirely of sedge peat. Two different profiles were sampled, with depths of 160 cm and 200 cm, respectively. Both profiles were sampled at 5 cm intervals, with approximately 2 kg of material in each unit. The results of the radiocarbon dating will be available in December 2016. Based on other previous studies, the bottom of the peat sediment is 11,500 cal yr BP, so project focuses on the Holocene period approximately from 10,000 cal yr BP. More than 80 species of Coleoptera from 55 genera, 22 families have been recognised so

  3. Quaternary IPM (integrated pest management)--concept for the control of powdery mildew in sugar beets.

    Science.gov (United States)

    Wolf, P F J; Verreet, A

    2008-01-01

    Powdery mildew, caused by Erysiphe betae (Vanha) Weltzien, may be assumed as an important leaf disease in sugar beet growing areas of central Europe. Although the causal agent is mainly adapted to arid climatic zones, the disease is appearing every year, where the extent of infection is mainly dependent on weather conditions and susceptibility of cultivar. The losses caused by powdery mildew seldom exceed 10% of sugar yield; moreover, losses are likely only under the condition that the epidemic onset occurs before end-August. Nevertheless, the epidemic onset varies in a wide range, as there are years with high incidence followed by growing periods without severe infection. Therefore, in order to have a flexible control of the disease, where the use of fungicides could be minimised to an essential amount, a quaternary IPM (Integrated Pest Management) -concept was developed. The development is based on epidemiological field studies (Germany, 1993-2004, n = 76) of sugar beet leaf diseases under variation of year, site and cultivar. Efficacy of fungicide treatment timing was assessed in relation to the epidemic development. Comparison of treatments comprised fungicide sprays carried out from disease initiation till later stages of the epidemic. Additionally, the assessments were performed in relation to an untreated and a healthy control--the latter was three times treated according to a treatment regime with three to four week intervals. The effect of different application timings was measured by the potential of disease and yield loss control. The quaternary concept combines the advantages of four elements in order to compensate the constraints of the single tools: The period without disease risk is determined by a so-called negative-prognosis (i). First symptoms appear in the period from mid-July till the beginning of September. If disease initiation cannot be excluded, field observations by a sample of 100 leaves are advised. The disease scores enable the appliance

  4. Quaternary climate - Terrestrial Biosphere Interaction: amplifying or stabilizing?

    Science.gov (United States)

    Claussen, Martin

    2016-04-01

    According to the Gaia hypothesis, interaction between climate and biological processes tend to homeostatically maintain, on a global scale, conditions favourable for life. Does the idea of homeostatic interaction between terrestrial biosphere and climate hold for the Quaternary glacial - interglacial changes? Interpretation of palaeoclimate and palaeobotanic evidence by using climate and Earth system models yields an interesting picture. The synergy between the sea-ice albedo - climate feedback and the taiga-tundra - climate feedback is suggested to amplify the orbitally forced climatic precession. This effect seems to be strong at regional scale, but small at global scale. Various simulations indicate that biogeophysical processes amplify the difference of some 4 to 6 K in global mean temperature between glacial and interglacial climate by some 10 percent. The combined effect of biogeophysical and biogeochemical processes, i.e. processes with involve carbon stored in biomass and soil, is less clear. Theoretical studies suggest that in pre-industrial, interglacial climate, a reduction in boreal and extratropical forests tend to cool the climate and a reduction in tropical forest, to warm the climate. Recent estimates in changes in organic carbon stored under ice sheets and in permafrost point at the possibility that the sum of all terrestrial biogeochemical processes might almost "carbon neutral" to the climate system. If corroborated, this observation would favour the assumption of a dominance of biogeophysical processes amplifying orbitally forced Quaternary climate variations.

  5. Mineralogical and geological study of quaternary deposits and weathering profiles

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Gi Young; Lee, Bong Ho [Andong National Univ., Andong (Korea, Republic of)

    2004-01-15

    Movement history of a quaternary reverse fault cutting marine terrace deposit and tertiary bentonite in the Yangnammyon, Gyoungju city was studied by the mineralogical and microtextural analysis of the fault clays and weathered terrace deposits. Two types of fault clays were identified as greenish gray before the deposition of the marine terrace deposits and reddish brown after deposition. Greenish gray fault clay is composed mostly of smectite probably powdered from bentonite showing at least two events of movement from microtextures. After the bentonite was covered by quaternary marine gravel deposits, the reverse fault was reactivated cutting marine gravel deposits to form open spaces along the fault plane which allowed the hydrological infiltration of soil particles and deposition of clays in deep subsurface. The reddish brown 'fault' clays enclosed the fragments of dark brown ultrafine varved clay, proving two events of faulting, and slicken sides bisecting reddish brown clays suggest another faulting event in the final stage. Mineralogical and microtextural analysis of the fault clay show total five events of faulting, which had not been recognized even by thorough conventional paleoseismological investigation using trench, highlighting the importance of microtextural and mineralogical analysis in paleoseismology.

  6. Quaternary evolution of the Southern Apennines coastal plains: a review

    Science.gov (United States)

    Santangelo, Nicoletta; Romano, Paola; Ascione, Alessandra; Russo Ermolli, Elda

    2017-02-01

    The Quaternary evolution of the main coastal basins located along the southwestern margin of the Southern Apennines has been reconstructed by integrating the huge amount of existing stratigraphical and geomorphological data. The information produced in the last twenty years has shed new light on the recent (late Middle Pleistocene to Present) history of the Campanian and Sele plains or basins. During the early Quaternary, the analysed coastal basins originated as half-grabens in response to opening processes active since the late Tortonian in the southern Tyrrhenian back-arc basin. In some of these basins (e.g. the Campanian Plain), volcanism has also played an important role. In the inner sectors of the coastal basins, the complex interplay between block faulting, sedimentary inputs and glacioeustatic fluctuations gave rise to relative sea-level change and related coastline migrations, leading to the formation of the present-day coastal plains. In the Sele Plain basin, the construction of the present-day landscape mainly resulted from the substantial ceasing of subsidence in the final part of the Middle Pleistocene. Conversely, a strong contribution to the recent evolution of the Campanian Plain has been provided by abundant volcaniclastic aggradation, able to hinder the effect of the vertical motions that occurred in the last 100 ka.

  7. Quaternary evolution of the Southern Apennines coastal plains: a review

    Directory of Open Access Journals (Sweden)

    Santangelo Nicoletta

    2017-02-01

    Full Text Available The Quaternary evolution of the main coastal basins located along the southwestern margin of the Southern Apennines has been reconstructed by integrating the huge amount of existing stratigraphical and geomorphological data. The information produced in the last twenty years has shed new light on the recent (late Middle Pleistocene to Present history of the Campanian and Sele plains or basins. During the early Quaternary, the analysed coastal basins originated as half-grabens in response to opening processes active since the late Tortonian in the southern Tyrrhenian back-arc basin. In some of these basins (e.g. the Campanian Plain, volcanism has also played an important role. In the inner sectors of the coastal basins, the complex interplay between block faulting, sedimentary inputs and glacioeustatic fluctuations gave rise to relative sea-level change and related coastline migrations, leading to the formation of the present-day coastal plains. In the Sele Plain basin, the construction of the present-day landscape mainly resulted from the substantial ceasing of subsidence in the final part of the Middle Pleistocene. Conversely, a strong contribution to the recent evolution of the Campanian Plain has been provided by abundant volcaniclastic aggradation, able to hinder the effect of the vertical motions that occurred in the last 100 ka.

  8. Estuarine fluvial floodplain formation in the Holocene Lower Tagus valley (Central Portugal) and implications for Quaternary fluvial system evolution

    Science.gov (United States)

    van der Schriek, Tim; Passmore, David G.; Rolão, Jose; Stevenson, Anthony C.

    2007-11-01

    We present a brief synthesis of the Quaternary fluvial record in the Lower Tagus Basin (central Portugal), concentrating on factors controlling infill and incision. The Holocene part of the record forms the focus of this paper and guides the questioning of the basic assumptions of the established Quaternary fluvial evolution model, in particular the link between sea-level change and fluvial incision-deposition. We suggest that several incision-aggradation phases may have occurred during glacial periods. Major aggradation events may overlap with cold episodes, while incision appears to concentrate on the warming limb of climate transitions. The complex stratigraphy of the Quaternary record in the Lower Tagus valley is influenced by repeated base-level and climate changes. This paper submits the first chronostratigraphic framework for valley fill deposits in the Lower Tagus area. Sea-level rise forced aggradation and controlled deposition of the fine-grained sedimentary wedge underlying the low-gradient Lower Tagus floodplain. Investigations have focused on the lower Muge tributary, where rapidly aggrading estuarine and fluvial environments were abruptly established (∼8150 cal BP) as sea level rose. Base level at the valley mouth controlled the upstream extent of the fine-grained backfill. Tidal environments disappeared abruptly (∼5800 cal BP) when the open estuary at the Muge confluence was infilled by the Tagus River. The decrease and final still stand of sea-level rise led to floodplain stabilisation with peat (∼6400-5200 cal BP) and soil formation (∼5200-2200 cal BP). Localised renewed sedimentation (∼2200-200 cal BP) is linked to human activity.

  9. Late Quaternary eolian and alluvial response to paleoclimate, Canyonlands, southeastern Utah

    Science.gov (United States)

    Reheis, M.C.; Reynolds, R.L.; Goldstein, H.; Roberts, H.M.; Yount, J.C.; Axford, Y.; Cummings, L.S.; Shearin, N.

    2005-01-01

    In upland areas of Canyonlands National Park, Utah, thin deposits and paleosols show late Quaternary episodes of eolian sedimentation, pedogenesis, and climate change. Interpretation of the stratigraphy and optically stimulated luminescence ages of eolian and nearby alluvial deposits, their pollen, and intercalated paleosols yields the following history: (1) Eolian deposition at ca. 46 ka, followed by several episodes of alluviation from some time before ca. 40 ka until after 16 ka (calibrated). (2) Eolian deposition from ca. 17 ka to 12 ka, interrupted by periods of pedogenesis, coinciding with late Pleistocene alluviation as local climate became warmer and wetter. (3) A wetter period from 12 to 8.5 ka corresponding to the peak of summer monsoon influence, during which soils formed relatively quickly by infiltration of eolian silt and clay, and trees and grasses were more abundant. (4) A drier period between ca. 8.5 and 6 ka during which sheetwash deposits accumulated and more desertlike vegetation was dominant; some dunes were reactivated at ca. 8 ka. (5) Episodic eolian and fluvial deposition during a wetter, cooler period that began at ca. 6 ka and ended by ca. 3-2 ka, followed by a shift to drier modern conditions; localized mobilization of dune sand has persisted to the present. These interpretations are similar to those of studies at the Chaco dune field, New Mexico, and the Tusayan dune field, Arizona, and are consistent with paleoclimate interpretations of pollen and packrat middens in the region. A period of rapid deposition and infiltration of eolian dust derived from distant igneous source terranes occurred between ca. 12 and 8 ka. Before ca. 17 ka, and apparently back to at least 45 ka, paleosols contain little or no such infiltrated dust. After ca. 8 ka, either the supply of dust was reduced or the more arid climate inhibited translocation of dust into the soils. ?? 2005 Geological Society of America.

  10. Shift in detrital sedimentation in the eastern Bay of Bengal during the late Quaternary

    Indian Academy of Sciences (India)

    C Prakash Babu; J N Pattan; K Dutta; N Basavaiah; G V Ravi Prasad; D K Ray; P Govil

    2010-06-01

    Down-core variations of granulometric, geochemical and mineral magnetism of a 70-cm long sediment core retrieved from the eastern Bay of Bengal abyssal region were studied to understand sedimentation pattern and sediment provenance during the last ∼12 kyr BP. Based on down-core physical and elemental variations, three units were identified: unit 3 (70–43 cm) is a ∼30 cm thick clayey silt organic carbon-rich (0.5–0.92%) turbidite probably delivered by the Brahmaputra River during the late Quaternary period. Units 2 (43–24 cm) and 1 (24–0 cm) represent enhanced and reduced supply of coarse-grained detrital sediments from the Ganges River during early and late Holocene period, respectively. Increased terrigenous supply dilutes calcium carbonate (CaCO3) and biogenic elements (P, Ba and Cu) in units 3 and 2. On the contrary, a reduction in detrital input enhances CaCO3 and biogenic elements in unit 1. Lithogenic elements (Ti, Al, K and Rb) and shale-normalized REE patterns in all three units suggest terrigenous source. The shift in provenance from the Brahmaputra to the Ganges derived sediments is evident by a sharp increase in sediment grain size, increased concentration and grain size assemblages of magnetic minerals, lithogenic elements concentration and Lan/Ybn ratio. This study highlights terrigenous dilution on biogenic sedimentation in the eastern Bay of Bengal sediments.

  11. Quaternary Reorganization of North American Mid-continent Drainage Systems

    Science.gov (United States)

    Carson, E. C.; Rawling, J. E., III; Attig, J. W.; Bates, B. R.

    2013-12-01

    Identification of ancestral drainage systems in the North American mid-continent has been a topic of research and debate among geologists since the middle of the 19th Century. Over time our understanding of the significance of Quaternary glaciations in reshaping drainage patterns has grown. The ancestral Teays River, which drained large areas of the central Appalachians and flowed westward across Indiana and western Illinois, was dammed multiple times by Quaternary glaciers before finally being rerouted to the course of the modern central Ohio River. Similarly, the northward-flowing ancestral Pittsburgh River was dammed by pre-Illinoian glaciers; subsequent stream piracy converted this river system into the modern Allegheny, Monongahela and uppermost Ohio Rivers. Deposits and geomorphic features along the westward-flowing lower Wisconsin River indicate that the modern upper Mississippi River and Wisconsin River may have experienced a similar history of ice blockage, stream piracy, and radical rerouting. Coring into the Bridgeport strath terrace along the lower Wisconsin River reveals that the bedrock surface dips to the east, indicating the valley was cut by an eastward-flowing river. We believe the most likely scenario following this interpretation is that an ancestral river flowing along the modern upper Mississippi River valley made a sharp bend at Prairie du Chien, WI, and flowed eastward along the valley occupied by the modern lower Wisconsin River. This river, referred to here as the Wyalusing River, likely flowed northeastward into the Great Lakes (St. Lawrence) drainage until that path was blocked by ice advancing from the northwest. Subsequent stream piracy immediately south of the modern confluence of the Mississippi and Wisconsin Rivers rerouted these streams, converting them to the headwaters of the greater Mississippi drainage. The combined rerouting of these river systems into entirely different drainage basins necessitates significant fundamental

  12. Understanding the major transitions in Quaternary climate dynamics

    Science.gov (United States)

    Willeit, Matteo; Ganopolski, Andrey

    2017-04-01

    Climate dynamics over the past 3 million years was characterized by strong variability associated with glacial cycles and several distinct regime changes. The Pliocene-Pleistocene Transition (PPT), which happened around 2.7 million years ago, was characterized by the appearance of the large continental ice sheets over Northern Eurasia and North America. For two million years after the PPT climate variability was dominated by relatively symmetric 40 kyr cycles. At around 1 million years ago the dominant mode of climate variability experienced a relatively rapid transition from 40 kyr to strongly asymmetric 100 kyr cycles of larger amplitude (Mid-Pleistocene Transition). Additionally, during the past 800 kyr there are clear differences between the earlier and the later glacial cycles with the last five cycles characterized by larger magnitude of variability (Mid-Brunhes Event). Here, we use the Earth system model of intermediate complexity CLIMBER-2 to explore possible mechanisms that could explain these regime shifts. CLIMBER-2 incorporates all major components of the Earth system - atmosphere, ocean, land surface, northern hemisphere ice sheets, terrestrial biota and soil carbon, marine biogeochemistry and aeolian dust. The model was optimally tuned to reproduce climate, ice volume and CO2 variability over the last 400,000 years. Using the same model version, we performed a large set of simulations covering the entire Quaternary (3 million years) starting from identical initial conditions and using a parallelization in time technique which consists of starting the model at different times (every 100,000 years) and running each simulation for 500,000 years. The Earth's orbital variations are the only prescribed radiative forcing. Several sets of the Northern Hemisphere orography and sediment thickness representing different stages of landscape evolution during the Quaternary are prescribed as boundary conditions for the ice sheet model and volcanic CO2 outgassing is

  13. Late Quaternary stratigraphy, sedimentology, and geochemistry of an underfilled lake basin in the Puna (north-west Argentina)

    Science.gov (United States)

    McGlue, Michael M.; Cohen, Andrew S.; Ellis, Geoffrey S.; Kowler, Andrew L.

    2013-01-01

    Depositional models of ancient lakes in thin-skinned retroarc foreland basins rarely benefit from appropriate Quaternary analogues. To address this, we present new stratigraphic, sedimentological and geochemical analyses of four radiocarbon-dated sediment cores from the Pozuelos Basin (PB; northwest Argentina) that capture the evolution of this low-accommodation Puna basin over the past ca. 43 cal kyr. Strata from the PB are interpreted as accumulations of a highly variable, underfilled lake system represented by lake-plain/littoral, profundal, palustrine, saline lake and playa facies associations. The vertical stacking of facies is asymmetric, with transgressive and thin organic-rich highstand deposits underlying thicker, organic-poor regressive deposits. The major controls on depositional architecture and basin palaeogeography are tectonics and climate. Accommodation space was derived from piggyback basin-forming flexural subsidence and Miocene-Quaternary normal faulting associated with incorporation of the basin into the Andean hinterland. Sediment and water supply was modulated by variability in the South American summer monsoon, and perennial lake deposits correlate in time with several well-known late Pleistocene wet periods on the Altiplano/Puna plateau. Our results shed new light on lake expansion–contraction dynamics in the PB in particular and provide a deeper understanding of Puna basin lakes in general.

  14. Coupling genetic and species distribution models to examine the response of the Hainan Partridge (Arborophila ardens to late quaternary climate.

    Directory of Open Access Journals (Sweden)

    Jiang Chang

    Full Text Available Understanding the historical dynamics of animal species is critical for accurate prediction of their response to climate changes. During the late Quaternary period, Southeast Asia had a larger land area than today due to lower sea levels, and its terrestrial landscape was covered by extensive forests and savanna. To date, however, the distribution fluctuation of vegetation and its impacts on genetic structure and demographic history of local animals during the Last Glacial Maximum (LGM are still disputed. In addition, the responses of animal species on Hainan Island, located in northern Southeast Asia, to climate changes during the LGM are poorly understood. Here, we combined phylogeographic analysis, paleoclimatic evidence, and species distribution models to examine the response of the flightless Hainan Partridge (Arborophila ardens to climate change. We concluded that A. ardens survived through LGM climate changes, and its current distribution on Hainan Island was its in situ refuge. Range model results indicated that A. ardens once covered a much larger area than its current distribution. Demographic history described a relatively stable pattern during and following the LGM. In addition, weak population genetic structure suggests a role in promoting gene flow between populations with climate-induced elevation shifts. Human activities must be considered in conservation planning due to their impact on fragmented habitats. These first combined data for Hainan Partridge demonstrate the value of paired genetic and SDMs study. More related works that might deepen our understanding of the responses of the species in Southeast Asia to late Quaternary Climate are needed.

  15. Ice-sheet dynamics through the Quaternary on the mid-Norwegian continental margin inferred from 3D seismic data.

    Science.gov (United States)

    Montelli, A; Dowdeswell, J A; Ottesen, D; Johansen, S E

    2017-02-01

    Reconstructing the evolution of ice sheets is critical to our understanding of the global environmental system, but most detailed palaeo-glaciological reconstructions have hitherto focused on the very recent history of ice sheets. Here, we present a three-dimensional (3D) reconstruction of the changing nature of ice-sheet derived sedimentary architecture through the Quaternary Ice Age of almost 3 Ma. An extensive geophysical record documents a marine-terminating, calving Fennoscandian Ice Sheet (FIS) margin present periodically on the mid-Norwegian shelf since the beginning of the Quaternary. Spatial and temporal variability of the FIS is illustrated by the gradual development of fast-flowing ice streams and associated intensification of focused glacial erosion and sedimentation since that time. Buried subglacial landforms reveal a complex and dynamic ice sheet, with converging palaeo-ice streams and several flow-switching events that may reflect major changes in topography and basal thermal regime. Lack of major subglacial meltwater channels suggests a largely distributed drainage system beneath the marine-terminating part of the FIS. This palaeo-environmental examination of the FIS provides a useful framework for ice-sheet modelling and shows that fragmentary preservation of buried surfaces and variability of ice-sheet dynamics should be taken into account when reconstructing glacial history from spatially limited datasets.

  16. A Quaternary ZnCdSeTe Nanotip Photodetector

    Directory of Open Access Journals (Sweden)

    Cheng YC

    2009-01-01

    Full Text Available Abstract The authors report the growth of needle-like high density quaternary Zn0.87Cd0.13Se0.98Te0.02nanotips on oxidized Si(100 substrate. It was found that average length and average diameter of the nanotips were 1.3 μm and 91 nm, respectively. It was also found that the as-grown ZnCdSeTe nanotips exhibit mixture of cubic zinc-blende and hexagonal wurtzite structures. Furthermore, it was found that the operation speeds of the fabricated ZnCdSeTe nanotip photodetector were fast with turn-on and turn-off time constants both less than 2 s.

  17. Control of Quaternary sea-level changes on gas seeps

    Science.gov (United States)

    Riboulot, Vincent; Thomas, Yannick; Berné, Serge; Jouet, Gwénaël.; Cattaneo, Antonio

    2014-07-01

    Gas seeping to the seafloor through structures such as pockmarks may contribute significantly to the enrichment of atmospheric greenhouse gases and global warming. Gas seeps in the Gulf of Lions, Western Mediterranean, are cyclical, and pockmark "life" is governed both by sediment accumulation on the continental margin and Quaternary climate changes. Three-dimensional seismic data, correlated to multi-proxy analysis of a deep borehole, have shown that these pockmarks are associated with oblique chimneys. The prograding chimney geometry demonstrates the syn-sedimentary and long-lasting functioning of the gas seeps. Gas chimneys have reworked chronologically constrained stratigraphic units and have functioned episodically, with maximum activity around sea level lowstands. Therefore, we argue that one of the main driving mechanisms responsible for their formation is the variation in hydrostatic pressure driven by relative sea level changes.

  18. Quaternary Prevention, an Answer of Family Doctors to Overmedicalization

    Directory of Open Access Journals (Sweden)

    Marc Jamoulle

    2015-02-01

    Full Text Available In response to the questioning of Health Policy and Management (HPAM by colleagues on the role of rank and file family physicians in the same journal, the author, a family physician in Belgium, is trying to highlight the complexity and depth of the work of his colleagues and their contribution to the understanding of the organization and economy of healthcare. It addresses, in particular, the management of health elements throughout the ongoing relationship of the family doctor with his/her patients. It shows how the three dimensions of prevention, clearly included in the daily work, are complemented with the fourth dimension, quaternary prevention or prevention of medicine itself, whose understanding could help to control the economic and human costs of healthcare.

  19. Antibacterial effect of composite resins containing quaternary ammonium polyethyleneimine nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Yudovin-Farber, Ira [Hebrew University of Jerusalem, Department of Medicinal Chemistry and Natural Products, School of Pharmacy, Faculty of Medicine (Israel); Beyth, Nurit; Weiss, Ervin I. [Hebrew University of Jerusalem, Department of Prosthodontics, Faculty of Dentistry (Israel); Domb, Abraham J., E-mail: avid@ekmd.huji.ac.i [Hebrew University of Jerusalem, Department of Medicinal Chemistry and Natural Products, School of Pharmacy, Faculty of Medicine (Israel)

    2010-02-15

    Quaternary ammonium polyethyleneimine (QA-PEI)-based nanoparticles were synthesized by crosslinking with dibromopentane followed by N-alkylation with various alkyl halides and further N-methylation with methyl iodide. Insoluble pyridinium-type particles were prepared by suspension polymerization of 4-vinyl pyridine followed by N-alkylation with alkyl halides. Polyamine-based nanoparticles embedded in restorative composite resin at 1% w/w were tested for antibacterial activity against Streptococcus mutans using direct contact test. Activity analysis revealed that the alkyl chain length of the QA-PEI nanoparticles plays a significant role in antibacterial activity of the reagent. The most potent compound was octyl-alkylated QA-PEI embedded in restorative composite resin at 1% w/w that totally inhibited S. mutans growth in 3-month-aged samples. This data indicates that restorative composite resin with antibacterial properties can be produced by the incorporation of QA-PEI nanoparticles.

  20. Expansion and contraction of Chinese deserts during the Quaternary

    Institute of Scientific and Technical Information of China (English)

    刘东生; 孙继敏

    2002-01-01

    Episodic dune formations during the Quaternary are found in many deserts of China.The causes of desert expansions on different time scales are not the same. Desert extension atabout 1.1 and 0.9 Ma ago were the response to the active tectonic movements, whereas the de-sert evolutions on the ten-thousand years time scale were the response to the orbital scale climaticchanges. Spatial scale studies on desert evolution indicate that desert margins shifted greatly dur-ing the last glacial maximum (LGM) and the Holocene optimum, its changing from 125°E of theLGM to 105°E of the climatic optimum. Historical desertification in the semiarid China is not a re-sponse to climate drought but largely associated with the human impacts (mainly over-cultivation)since about 2300 years ago, which leads to the reworking of the underlying LGM sands.

  1. Evolution of Quaternary groundwater system in North China Plain

    Institute of Scientific and Technical Information of China (English)

    张宗祜; 施德鸿; 任福弘; 殷正宙; 孙继朝; 张翠云

    1997-01-01

    The Quaternary groundwater system in the North China Plain is formed mainly through the terrestrial water flow action on the united geological and tectonic backgrounds. The analysis of groundwater dynamic field, simulation of groundwater geochemistry, and the 14C dating and extraction of isotope information have provided more evidence for recognizing and assessing the evolution of groundwater circulation system and studying the past global changes. The exploitation and utilization of groundwater on a large scale and overexploitation have given rise to the decline of regional groundwater level, change of flow field, decrease of water resources and downward movement of saline water body. The water environment has entered a new evolution stage in which it is intensely disturbed by the mankind’s activities.

  2. QUATERNARY DELSARTE-GOETHALS AND GOETHALS-DELSARTE CODES

    Institute of Scientific and Technical Information of China (English)

    CUI Jie; WAN Zhexian

    2002-01-01

    In this paper, the quaternary Delsarte-Goethals code DG(m,δ) and its dual code GD(m, δ) are discussed. The type and the trace representation are given for DG(m, δ),while the type and the minimum Lee weight are determined for GD(m, δ). The shortened codes of DG(m, δ) and GD(m, δ) are proved to be Z4-cyclic. The binary image of DG(m, δ)is proved to be the binary Delsarte-Goethals code DG(m+1, δ), and the essential difference between the binary image of GD(m, δ) and the binary Goethals-Delsarte code GD(m +1, δ)is exhibited. Finally, the decoding algorithms of DG(m, δ) and GD(m, δ) are discussed.

  3. QUATERNARY DELSARTE—GOETHALS AND GOETHALS—DELSARTE CODES

    Institute of Scientific and Technical Information of China (English)

    CUIJie; WANZhexian

    2002-01-01

    In this paper,the quaternary Delsarte-Goethals code DG(m,δ)and its dual code GD(m,δ)are discussed.The type and the trace representation are given for DG\\(m,δ),while the type and the minimum Lee weight are determined for GD(m,δ),The shortened codes of DG(m,δ)and GD(m,δ),are proved to be ZZ4-cyclic.The binary image of DG(m,δ) is proved to be the binary Delsarte-Goethals code DG((m+1,δ),and the essential difference between the binary image of GD(m,δ)and the binary Goethals-Delsarte code GD((m+1,δ)is exhibited.Finally,the decoding algorithms of DG(m,δ)and GD(m,δ)are discussed.

  4. Rapid dendrite growth in quaternary Ni-based alloys

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The high undercooling and rapid solidification of Ni-10%Cu-10%Fe-10%Co quaternary alloy were achieved by electromagnetic levitation and glass fluxing techniques. The maximum undercooling of 276 K (0.16TL) was obtained in the experiments. All the solidified samples are determined to be α-Ni single-phase solid solutions by DSC thermal analysis and X-ray diffraction analysis. The microstructure of the α-Ni solid solution phase transfers from dendrite to equiaxed grain with an increase in undercooling, accompanied by the grain refinement effect. When the undercooling is very large, the solute trapping effect becomes quite significant and the microsegregation is suppressed. The experimental measurement of α-Ni dendrite growth velocity indicates that it increases with undercooling according to the relation, V=8×10-2×△T1.2.

  5. Asynchronous extinction of late Quaternary sloths on continents and islands

    Science.gov (United States)

    Steadman, David W.; Martin, Paul S.; MacPhee, Ross D. E.; Jull, A. J. T.; McDonald, H. Gregory; Woods, Charles A.; Iturralde-Vinent, Manuel; Hodgins, Gregory W. L.

    2005-01-01

    Whatever the cause, it is extraordinary that dozens of genera of large mammals became extinct during the late Quaternary throughout the Western Hemisphere, including 90% of the genera of the xenarthran suborder Phyllophaga (sloths). Radiocarbon dates directly on dung, bones, or other tissue of extinct sloths place their “last appearance” datum at ≈11,000 radiocarbon years before present (yr BP) or slightly less in North America, ≈10,500 yr BP in South America, and ≈4,400 yr BP on West Indian islands. This asynchronous situation is not compatible with glacial–interglacial climate change forcing these extinctions, especially given the great elevational, latitudinal, and longitudinal variation of the sloth-bearing continental sites. Instead, the chronology of last appearance of extinct sloths, whether on continents or islands, more closely tracks the first arrival of people. PMID:16085711

  6. Antibacterial effect of composite resins containing quaternary ammonium polyethyleneimine nanoparticles

    Science.gov (United States)

    Yudovin-Farber, Ira; Beyth, Nurit; Weiss, Ervin I.; Domb, Abraham J.

    2010-02-01

    Quaternary ammonium polyethyleneimine (QA-PEI)-based nanoparticles were synthesized by crosslinking with dibromopentane followed by N-alkylation with various alkyl halides and further N-methylation with methyl iodide. Insoluble pyridinium-type particles were prepared by suspension polymerization of 4-vinyl pyridine followed by N-alkylation with alkyl halides. Polyamine-based nanoparticles embedded in restorative composite resin at 1% w/w were tested for antibacterial activity against Streptococcus mutans using direct contact test. Activity analysis revealed that the alkyl chain length of the QA-PEI nanoparticles plays a significant role in antibacterial activity of the reagent. The most potent compound was octyl-alkylated QA-PEI embedded in restorative composite resin at 1% w/w that totally inhibited S. mutans growth in 3-month-aged samples. This data indicates that restorative composite resin with antibacterial properties can be produced by the incorporation of QA-PEI nanoparticles.

  7. Book Review: The history of the Quaternary Research Association

    Science.gov (United States)

    Bowen, D. Q.

    2016-06-01

    This is a book that should be in the library of every member of the QRA as well as their institutions. This volume is a celebration of 50 years of the Quaternary Studies Field Group (1964), which was renamed the Quaternary Research Association (QRA) in 1969. What follows is a combination of a review with some further information based on the recollection of someone who was there. In examining the origins of the QSFG due credit is paid to Richard Hey and Richard West, but an inexplicable omission is the earlier discussion between Hey, Allan Straw and others during the field meeting of the Yorkshire Geological Society in September 1962 (Worsley, 2014). It is said that history is always written by the victors, or in modern parlance by those who write the minutes! But, in the writing of history there are only degrees of unsuccess. In Chapter 2 John Catt comments on the less than perfect early archival records of the QRA. So it is to his credit that 50 years of archival material has been diligently sifted and edited. In this he was assisted by memories of some named QRA members who are thanked. Wider consultation may have filled some of the gaps. At earlier meetings it was always a pleasure to greet long retired colleagues, such as Archie Lamont at the Carlops glacial drainage system when being demonstrated by Brian Sissons in 1966, or Tony Farringdon at Ballycotton Bay in 1968, or Hallam Movius in 1971 at a London discussion meeting. Similarly, who can forget the field meeting at Canterbury in 1967 when Alec Skempton demonstrated the Sevenoaks by-pass late-glacial slope failures, and John Hutchinson's use of Pomatias elegans for dating the Folkestone Warren landslips? Jan Mangerud's first QRA meeting on the Isle of Man (1971) was notable for his prescient recognition of glaciomarine deposits.

  8. Relaxed random walk model coupled with ecological niche modeling unravel the dispersal dynamics of a Neotropical savanna tree species in the deeper Quaternary.

    Science.gov (United States)

    Collevatti, Rosane G; Terribile, Levi C; Rabelo, Suelen G; Lima-Ribeiro, Matheus S

    2015-01-01

    Understanding the dispersal routes of Neotropical savanna tree species is an essential step to unravel the effects of past climate change on genetic patterns, species distribution and population demography. Here we reconstruct the demographic history and dispersal dynamics of the Neotropical savanna tree species Tabebuia aurea to understand the effects of Quaternary climate change on its current spatial patterns of genetic diversity. We sampled 285 individuals from 21 populations throughout Brazilian savannas and sequenced all individuals for three chloroplast intergenic spacers and ITS nrDNA. We analyzed data using a multi-model inference framework by coupling the relaxed random walk model (RRW), ecological niche modeling (ENM) and statistical phylogeography. The most recent common ancestor of T. aurea lineages dated from ~4.0 ± 2.5 Ma. T. aurea lineages cyclically dispersed from the West toward the Central-West Brazil, and from the Southeast toward the East and Northeast Brazil, following the paleodistribution dynamics shown by the ENMs through the last glacial cycle. A historical refugium through time may have allowed dispersal of lineages among populations of Central Brazil, overlapping with population expansion during interglacial periods and the diversification of new lineages. Range and population expansion through the Quaternary were, respectively, the most frequent prediction from ENMs and the most likely demographic scenario from coalescent simulations. Consistent phylogeographic patterns among multiple modeling inferences indicate a promising approach, allowing us to understand how cyclical climate changes through the Quaternary drove complex population dynamics and the current patterns of species distribution and genetic diversity.

  9. Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms.

    Science.gov (United States)

    Büschleb, Martin; Dorich, Stéphane; Hanessian, Stephen; Tao, Daniel; Schenthal, Kyle B; Overman, Larry E

    2016-03-18

    Strategies for the total synthesis of complex natural products that contain two or more contiguous stereogenic quaternary carbon atoms in their intricate structures are reviewed with 12 representative examples. Emphasis has been put on methods to create quaternary carbon stereocenters, including syntheses of the same natural product by different groups, thereby showcasing the diversity of thought and individual creativity. A compendium of selected natural products containing two or more contiguous stereogenic quaternary carbon atoms and key reactions in their total or partial syntheses is provided in the Supporting Information.

  10. Occurrence of volcanic ash in the Quaternary alluvial deposits, lower Narmada basin, western India

    Indian Academy of Sciences (India)

    Rachna Raj

    2008-02-01

    This communication reports the occurrence of an ash layer intercalated within the late Quaternary alluvial succession of the Madhumati River, a tributary of the lower Narmada River. Petrographic, morphological and chemical details of glass shards and pumice fragments have formed the basis of this study. The ash has been correlated with the Youngest Toba Tuff. The finding of ash layer interbedded in Quaternary alluvial sequences of western Indian continental margin is significant, as ash being datable material, a near precise time-controlled stratigraphy can be interpreted for the Quaternary sediments of western India. The distant volcanic source of this ash requires a fresh re-assessment of ash volume and palaeoclimatic interpretations.

  11. Deep-sea ostracode species diversity: Response to late Quaternary climate change

    Science.gov (United States)

    Cronin, T. M.; DeMartino, D.M.; Dwyer, Gary S.; Rodriguez-Lazaro, J.

    1999-01-01

    Late Quaternary ostracode assemblages from the North Atlantic Ocean were studied to establish the effect of climatic changes of the past 210,000 yr (marine oxygen isotope stages 7–1) on deep-sea benthic biodiversity and faunal composition. Two-hundred and twenty five samples from the Chain 82-24 Core 4PC (41°43′N, 32°51′W, 3427 m water depth) on the western Mid-Atlantic Ridge revealed high amplitude fluctuations in ostracode abundance and diversity coincident with orbital and suborbital scale climate oscillations measured by several paleoceanographic proxy records. During the past 210,000 yr, ostracode biodiversity as measured by species number (S) and the Shannon–Weaver index, H(S), oscillated from H(S)=0.4 during glacial periods (marine isotope stages 6, 5d, 5b, 4, and 2) to H(S)=1.1 during interglacial and interstadial periods (stages 7, 5e, 5c, 5a, 3 and 1). A total of 23 diversity peaks could be recognized. Eleven of these signify major periods of high diversity [H(S)>0.8, S = 10–21] occurring every 15–20 ka. Twelve were minor peaks which may represent millennial-scale diversity oscillations. The composition of ostracode assemblages varies with Krithe-dominated assemblages characterizing glacial intervals, and Argilloecia–Cytheropteron characterizing deglacials, and trachyleberid genera (Poseidonamicus, Echinocythereis, Henryhowella, Oxycythereis) abundant during interglacials. Diversity and faunal composition changes can be matched to independent deep-sea paleoceanographic tracers such as benthic foraminiferal carbon isotopes, Krithe trace elements (Mg/Ca ratios), and to North Atlantic region climate records such as Greenland ice cores. When interpreted in light of ostracode species' ecology, these faunal and diversity patterns provide evidence that deep-sea benthic ecosystems experience significant reorganization in response to climate changes over orbital to millennial timescales.

  12. Stratigraphical and palynological appraisal of the Late Quaternary mangrove deposits of the west coast of India

    Science.gov (United States)

    Kumaran, K. P. N.; Nair, K. M.; Shindikar, Mahesh; Limaye, Ruta B.; Padmalal, D.

    2005-11-01

    The organic deposits derived from the mangrove swamps form reliable stratigraphic markers within the Late Quaternary sequence of Kerala-Konkan Basin. Three generations of such deposits have been identified. The older one is dated to around 43,000-40,000 14C yr B.P., with a few dates beyond the range of radiocarbon. The younger ones date from the Middle Holocene to latest Pleistocene (10,760-4540 14C yr B.P.) and the Late Holocene (mangrove vegetation. Peat accumulation during the period 40,000-28,000 14C yr B.P. can be correlated with the excess rainfall, 40-100% greater than modern values, of the Asian summer monsoon. The low occurrence of mangrove between 22,000 and 18,000 14C yr B.P. can be attributed to the prevailing aridity and/or reduced precipitation associated worldwide with Last Glacial Maximum, because exposure surfaces and ferruginous layers are commonly found in intervals representing this period. The high rainfall of 11,000-4000 14C yr B.P. is found to be the most significant as the mangrove reached an optimum growth around 11,000 14C yr B.P. but with periods of punctuated weaker monsoons. From the present and previous studies, it has been observed that after about 5000 or 4000 14C yr B.P., the monsoons became gradually reduced leading to drying up of many of the marginal marine mangrove ecosystems. A case study of Hadi profile provided an insight to the relevance of magnetic susceptibility (χ) to record the ecological shift in Late Holocene.

  13. Chemical, biochemical, and microbiological aspects of chitosan quaternary salt as active coating on sliced apples

    Directory of Open Access Journals (Sweden)

    Douglas de Britto

    2012-09-01

    Full Text Available The biocompatibility of chitosan and chitosan quaternary salt coatings was evaluated for use as edible coatings for sliced apple. Measurement of water loss, color change, and fungal growth appearance were monitored as a function of time. A significant brownish effect was observed on chitosan coated slices, varying greatly from L* = 76.5 and Hue angle = 95.9° (t = 0 to L* = 45.3 and Hue angle = 69.8° (t = 3 days, whilst for TMC coated samples the variation was considerable lower (L* = 74.1; Hue angle = 95.0° to (L* = 67.0; Hue angle = 83.8° within the same period. The hydrosoluble derivative N,N,N-trimethylchitosan demonstrated good antifungal activity against P. expansum although highly dependent on the polymer properties such as degree of quaternization. The most efficient formulation was that prepared from derivative having a degree of quaternization of 45%, high solubility, and high viscosity. This formulation restrained fungus spreading up to 30%, while for the control it reached almost 80% of the total assessed surfaces during 7 days of storage.

  14. Quaternary dating by electron spin resonance (ESR applied to human tooth enamel

    Directory of Open Access Journals (Sweden)

    Carvajal Eduar

    2011-12-01

    Full Text Available This paper presents the results obtained from using electron paramagnetic resonance (EPR to analyse tooth enamel found at the Aguazuque archaeological site (Cundinamarca, Colombia, located on the savannah near Bogota at 4° 37' North and 74°17' West. It was presumed that the tooth enamel came from a collective burial consisting of 23 people, involving men, women and children. The tooth enamel was irradiated with gamma rays and the resulting free radicals were measured using an electron spin resonance (ESR X-band spectrometer to obtain a signal intensity compared to absorbed doses curve. Fitting this curve allowed the mean archaeological dose accumulated in the enamel during the period that it was buried to be estimated, giving a 2.10 ± 0.14 Gyvalue. ROSY software was used for estimating age, giving a mean 3,256 ± 190y before present (BP age. These results highlight EPR's potential when using the quaternary ancient ruins dating technique in Colombia and its use with other kinds of samples like stalagmites, calcite, mollusc shells and reefs.

  15. Vegetation and aquatic communities responses to late Quaternary climate change in central Mexico

    Science.gov (United States)

    Lozano-Garcia, S.; Caballero, M.; Correa-Metrio, A.

    2013-05-01

    A significant amount of information regarding the glacial history of volcanoes, vegetation history and lakes evolution of the Trans Mexican Volcanic Belt (TMVB) is available. The TMVB is a volcanically active highland area, and during its geological history numerous lakes basins have been formed. Climate change has been a significant factor in promoting transformations of the landscape and changes in the vegetation and lake levels during the Quaternary. Paleoclimatic studies carried out in central Mexico have documented variations in temperature and humidity during the late Pleistocene. In order to explore the response of vegetation to late glacial climatic and geological change, multyproxy records of lacustrine sequences from a series of lakes in the western and central sections of the TMVB have been under analysis. Calculated ecological change and its associated rates (RoCs) for six sites that follow an altitudinal and longitudinal gradient of central Mexico offer information on vegetation and dynamics of the lakes in the area. Most of these records show high variability. Dry periods in Lakes Cuitzeo and Zacapu (the most western and lower locations) show high RoC and seem to coincide with Heinrich events (H4 and H5). Contrastingly, RoC in Chalco and Texcoco records (the eastern and higher locations) seem more variable. The observed patterns are most likely the result of the confluence of climate, geologic events, and human occupation, all of them interacting at different time scales and posing difficulties when interpreting fossil sequences from the area.

  16. Geomorphologic evolution and environmental changes in the Shaluli Mountain region during the Quaternary

    Institute of Scientific and Technical Information of China (English)

    ZHOU Shangzhe; XU Liubing; CUI Jianxin; ZHANG Xiaowei; ZHAO Jingdong

    2005-01-01

    Geologic and geomorphologic evidence from the Shaluli Mountain indicates that the planation surface that formed in the Late Tertiary disintegrated during the Late Pliocene-Early Quaternary. At the same time, rift basins appeared on some parts of the planation surface, and began to accumulate fluvial-lacustrine sediment. These are interpreted as being the response of this region to Phase-A of the Qingzang Tectonic Movement. After this, the Shaluli Mountain continued to rise in several pulses. Faulting and incision by some large tributaries of the Jinsha and Yalong Rivers resulted in several rift river valleys and the earliest terraces. Generally, the planation surface in this region had been uplifted to about 3500-3700 m a.s.l. no later than 550-600 ka BP, after the Kunlun-Huanghe Tectonic Movement, and coupled with global glacial climate, and resulted in the earliest glaciation recognized so far in the Hengduan Mountains. At the same time, loess was deposited in the Ganzi area of the northern Shaluli Mountain. During the last glacial period, the Shaluli Mountain approached its present altitude and developed several large ice caps, such as the Daocheng Ice Cap and Xinlong Ice Cap, as well as several huge valley glaciers. These paleoglaciers produced some of the most spectacular glacial topography on the Tibetan Plateau.

  17. Tropical Rain Forest and Climate Dynamics of the Atlantic Lowland, Southern Brazil, during the Late Quaternary

    Science.gov (United States)

    Behling, Hermann; Negrelle, Raquel R. B.

    2001-11-01

    Palynological analysis of a core from the Atlantic rain forest region in Brazil provides unprecedented insight into late Quaternary vegetational and climate dynamics within this southern tropical lowland. The 576-cm-long sediment core is from a former beach-ridge "valley," located 3 km inland from the Atlantic Ocean. Radio-carbon dates suggest that sediment deposition began prior to 35,000 14C yr B.P. Between ca. 37,500 and ca. 27,500 14C yr B.P. and during the last glacial maximum (LGM; ca. 27,500 to ca. 14,500 14C yr B.P.), the coastal rain forest was replaced by grassland and patches of cold-adapted forest. Tropical trees, such as Alchornea, Moraceae/Urticaceae, and Arecaceae, were almost completely absent during the LGM. Furthermore, their distributions were shifted at least 750 km further north, suggesting a cooling between 3°C and 7°C and a strengthening of Antarctic cold fronts during full-glacial times. A depauperate tropical rain forest developed as part of a successional sequence after ca. 12,300 14C yr B.P. There is no evidence that Araucaria trees occurred in the Atlantic lowland during glacial times. The rain forest was disturbed by marine incursions during the early Holocene period until ca. 6100 14C yr B.P., as indicated by the presence of microforaminifera. A closed Atlantic rain forest then developed at the study site.

  18. Lithostratigraphy, volcanism, paleomagnetism and palynology of Quaternary lacustrine deposits from Barombi Mbo (West Cameroon): Preliminary results

    Science.gov (United States)

    Maley, J.; Livingstone, D. A.; Giresse, P.; Thouveny, N.; Brenac, P.; Kelts, K.; Kling, G.; Stager, C.; Haag, M.; Fournier, M.; Bandet, Y.; Williamson, D.; Zogning, A.

    1990-08-01

    We present preliminary results from the study of 23.50-m core from Lake Barombi Mbo, representing the last 25,000 years. The lake is in an explosion crater formed during Quaternary time. The very laminated sediment is composed mostly of clay containing 5-10% organic carbon. Each couplet is commonly composed of a basal lamina rich in quartz, plant debris, muscovite and sponge spicules, and of a more clayey upper lamina often with siderite. A perturbed section near the base of the core, before ca. 21,000 yr B.P., could be the result of a violent release of gas, such CO 2, comparable to the recent Nyos gas eruption. The paleomagnetic studies exhibit high-frequency oscillations interpreted as paleosecular variations of the local geomagnetic field. This first record obtained on the African continent can be closely compared to the type record obtained in Western Europe. The pollen results demonstrate the presence of a forest refuge in West Cameroon during the last great arid period, ca. 18,000 yr B.P. When equatorial forest was broken up, elements of montane vegetation spread to the lowlands. These phenomena resulted from a drying and cooling climate.

  19. Late Quaternary river channel migrations of the Kura River in Transcaucasia - tectonic versus climatic causes

    Science.gov (United States)

    von Suchodoletz, Hans; Gärtner, Andreas; Hoth, Silvan; Umlauft, Josefine; Godoladze, Tea; Faust, Dominik

    2015-04-01

    Large-scale river channel migrations either in the form of avulsions or combing, i.e. progressive lateral migrations, are global phenomena during the Late Quaternary. Such channel migrations were triggered by tectonics, climate change, human activity or a combination of those factors. River channel migrations have the potential to cause significant human and economic losses. Thus, a more thorough knowledge about underlying causes and process rates is essential. Furthermore, such studies will elucidate the sensitivity or robustness of rivers to different external and internal forcing-agents, i.e. they help to identify the dominant drivers of regional landscape evolution. The Caucasus region is part of the active collision zone between the Africa-Arabian and the Eurasian plates, and is characterized by high current tectonic activity. Furthermore, significant environmental changes took place during the Late Quaternary, i.e. the shrinking or even disappearance of glaciers in the Greater and Lesser Caucasus or fundamental changes of the vegetation cover varying between woodland and grassland-dominated vegetation. The Kura River is the main gaining stream of the Transcaucasian Depression located between the Greater Caucasus Mountains in the north and the Lesser Caucasus Mountains in the south, and receives several tributaries from both mountain ranges. This study focusses on the middle course of the Kura River in eastern Georgia, SE of the city of Tbilisi. Integration of fluvial geomorphology, geochronology, heavy mineral analyses and seismo-tectonic analyses demonstrates that this part of the Kura River underwent large-scale channel migrations up to >10 km during Late Pleistocene and Holocene. It is interpreted that these movements followed both tectonic and climatic triggers: Whereas SW-ward migrations were caused by tectonic uplift in and SW-directed advance of the Kura fold and thrust belt as part of the Greater Caucasus, NE-ward migrations occurred during cold

  20. Influence of fluvial processes on the quaternary geologic framework of the continental shelf, North Carolina, USA

    Science.gov (United States)

    Boss, S.K.; Hoffman, C.W.; Cooper, B.

    2002-01-01

    Digital, single-channel, high-resolution seismic reflection profiles were acquired from the insular continental shelf of North Carolina, USA along a data grid extending from Oregon Inlet northward 48 km to Duck, North Carolina and from the nearshore zone seaward approximately 28 km (total surveyed area= 1334 km2). These data were processed and interpreted to delineate principal reflecting horizons and develop a three-dimensional seismic stratigraphic framework for the continental shelf that was compared to stratigraphic data from the shoreward back-barrier (estuarine) and barrier island system. Six principal reflecting horizons (designated R0 through R5) were present within the upper 60 m of the shelf stratigraphic succession. Three-dimensional mapping of reflector R1 demonstrated its origin from fluvial incision of the continental shelf during an episode (or episodes) of lowered sea-level. Fluvial processes during development of reflector R1 were responsible for extensive reworking and re-deposition of sediment throughout most of the northern half of the study area. Five seismic stratigraphic units (designated S1 through S5) were tentatively correlated with depositional sequences previously identified from the North Carolina back-barrier (estuarine) and barrier island system. These five stratigraphic units span the Quaternary Period (S1 = early Holocene; S2 = 51-78 ka; S3 = 330-530 ka; S4 = 1.1-1.8 Ma; S5 = earliest Pleistocene). Unit S1 is composed of fine-grained fluvial/estuarine sediment that back-filled incised streams during early Holocene sea-level rise. The four other stratigraphic units (S2-S5) display tabular depositional geometries, low total relief, and thicken toward the east-southeast as their basal reflectors dip gently between 0.41 m km-1 (0.02??) and 0.54 m km-1 (0.03??). Knowledge of the three-dimensional subsurface stratigraphic architecture of the continental shelf enhances understanding of the development of shelf depositional successions and

  1. Quaternary vegetation and climate changes on Banks Peninsula, South Island, New Zealand

    Science.gov (United States)

    Soons, J. M.; Moar, N. T.; Shulmeister, J.; Wilson, H. D.; Carter, J. A.

    2002-07-01

    Late Quaternary terrestrial and marine pollen records from the Canterbury Plains and Banks Peninsula suggest that climates during the peak of Marine Isotope Stage 7 (MIS 7) were similar to those prevailing during stage 5e and the Holocene. Podocarp forest (notably Prumnopitys taxifolia—matai) characterises each interglaciation. In contrast, marine records from DSDP 594 cores, off the east coast of Canterbury, indicate that stage 7 was dominated by montane forest ( Libocedrus sp. and Phyllocladus). This suggests temperatures as much as 3 °C colder than indicated by the Banks Peninsula assemblage. Age control from both sites appears to be robust. Some of the differences may be related to the taphonomy of the pollen at both sites. DSDP 594 may reflect a more southerly catchment of fluvially and aeolian-derived pollen than does the Banks Peninsula site. Banks Peninsula was alternately separated from, and joined to, the mainland as Quaternary sea levels fell and rose. Assuming modern ocean current patterns, during interglacials the south-north Southland Current would have swept through the seaway separating the island from the mainland, diverting the flow of rivers embouching on the Canterbury coast, and moving sediments and fluvially transported pollen northwards. Little of this material would have reached DSDP 594, nor, if wind patterns were similar to those of today, would wind-borne pollen from Banks Peninsula have reached the site. It is probable that vegetation on the Peninsula was consistently distinct from that recorded at DSDP 594, which has a more southerly derivation. In contrast to the high mountain areas of the South Island, the low levels of grass pollen in the available record suggest that the Peninsula retained a woody vegetation over much of its area during glacial periods. This was favoured by the physiography of the area, with a variety of micro-climates, and by the extensive areas available for colonisation at times of low sea level. The podocarp

  2. Late Quaternary landscape evolution in the Great Karoo, South Africa: Processes and drivers.

    Science.gov (United States)

    Oldknow, Chris; Hooke, Janet; Lang, Andreas

    2016-04-01

    The Great Karoo spans the north-central part of South Africa at a major climatic boundary. The characteristics, sequences, spatial patterns and drivers of river response to Late Quaternary climate changes in this region remain unclear due to the fragmentary alluvial/colluvial stratigraphic record and the lack of dated palaeoclimatic archives. Dendritic gully networks incised into deep deposits (up to 6 m) of colluvium and alluvium in the upper Sundays River catchment expose a legacy of "cut and fill" features. In 1st order tributaries, these are predominantly discontinuous palaeochannels and flood-outs with localised palaeosols, whereas in 2nd & 3rd order tributaries there are: 1) incised palaeo-geomorphic surfaces, 2) semi-continuous inset terrace sequences, 3) buried palaeo-gully topography. Using a combination of field mapping, logging of sediment outcrops, soil micromorphological and grain size analysis, mineral magnetic measurements and radiometric dating (OSL & 14C), we derive a stratigraphic evolution model which demonstrates a) the number of phases of incision, aggradation and pedogenesis, b) the spatial and temporal extent of each phase and c) the drivers of alluviation and associated feedbacks. Our reconstruction of regional valley alluviation indicates four distinct terrace units of contrasting depositional age. The base of the succession reflects slow aggradation under periglacial conditions associated with the Last Glacial Maximum. Subsequent channel entrenchment, causing terrace abandonment (T1) occurred in the deglacial period when vegetation and rainfall were in anti-phase. Re-instatement of connectivity with deep upland colluvial stores resulted in the injection of a pulse of sediment to valley floors, triggering compartmentalised backfilling (aggradation of T2) which propagated upstream as far as the second order drainage lines. This backfilling restructured the local hydrology, which, in concert with enhanced summer-rainfall, contributed to a

  3. Novel approach for prediction of ultrasonic velocity in quaternary liquid mixtures

    Indian Academy of Sciences (India)

    J D Pandey; A K Singh; Ranjan Dey

    2005-01-01

    A modified Flory theory along with the Auerbach and Altenberg relations has been employed for the computation of ultrasonic velocity of three quaternary liquid mixtures and a comparative study of all the three relations has then been carried out.

  4. Effects of quaternary ammonium silane coatings on mixed fungal and bacterial biofilms on tracheoesophageal shunt prostheses

    NARCIS (Netherlands)

    Oosterhof, JJH; Buijssen, KJDA; Busscher, HJ; van der Laan, BFAM; van der Mei, HC

    2006-01-01

    Two quaternary ammonium silanes (QAS) were used to coat silicone rubber tracheoesophageal shunt prostheses, yielding a positively charged surface. One QAS coating [(trimethoxysilyl)-propyidimethylocta-decylammonium chloride] was applied through chemical bonding, while the other coating, Biocidal ZF,

  5. HETEROGENEOUS RECEPTOR-BINDING OF CLASSICAL QUATERNARY MUSCARINIC ANTAGONISTS .1. BOVINE TISSUE DISTRIBUTION

    NARCIS (Netherlands)

    ROFFEL, AF; ENSING, K; INTHOUT, WG; DEZEEUW, RA; ZAAGSMA, J

    1991-01-01

    In competition experiments with the teritiary radioligand [H-3]dexetimide, classical quaternary muscarinic antagonists like ipratropium bromide and N-methylscopolamine bromide distinguished two muscarinic binding sites in bovine brain (total brain minus cerebellum) membranes, in contrast to their

  6. Planktonic foraminifera from a quaternary deep sea core from the southern Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Naidu, P.D.; Rao, P.S.; Pattan, J.N.

    An investigation on planktonic foraminifera and calcium carbonate content of a box core collected at a depth of 2556 m from the southern part of the Arabian sea indicates faunal changes depicting Quaternary climatic fluctuations. Based on the study...

  7. Estimated Thickness of Quaternary Sediment in the Wood River Valley aquifer system, South-Central Idaho

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset is the estimated thickness of Quaternary sediment of the Wood River Valley aquifer system. This isopach map was constructed by subtracting the estimated...

  8. Global late Quaternary megafauna extinctions linked to humans, not climate change

    National Research Council Canada - National Science Library

    Sandom, Christopher; Faurby, Søren; Sandel, Brody; Svenning, Jens-Christian

    2014-01-01

    The late Quaternary megafauna extinction was a severe global-scale event. Two factors, climate change and modern humans, have received broad support as the primary drivers, but their absolute and relative importance remains controversial...

  9. Evaluation of chitosan quaternary ammonium salt-modified resin denture base material.

    Science.gov (United States)

    Song, Rong; Zhong, Zhaohua; Lin, Lexun

    2016-04-01

    Chitosan quaternary ammonium salt displays good antioxidant and antibacterial characteristics and it shows appreciable solubility in water. When added to the traditional denture material to form a resin base, it could promote good oral health by improving the oral environment. In this study, chitosan quaternary ammonium salt was added to the denture material following two different methods. After three months of immersion in artificial saliva, the specimens were tested for tensile strength and were scanned by electron microscope. The murine fibroblast cytotoxicity and antibacterial properties were also tested. The result showed no significant differences in the tensile strength and in the proliferation of murine L929 fibroblast cells. The two structures of chitosan quaternary ammonium salt-modified denture material had different degrees of corrosion resistance and antimicrobial properties. These results indicate that chitosan quaternary ammonium salt-modified resin denture base material has the potential to become a new generation oral denture composite material.

  10. Metalorganic Vapor-Phase Epitaxial Growth and Characterization of Quaternary AlGaInN

    Energy Technology Data Exchange (ETDEWEB)

    BANAS, MICHAEL ANTHONY; CRAWFORD, MARY H.; FIGIEL, JEFFREY J.; HAN, JUNG; LEE, STEPHEN R.; MYERS JR., SAMUEL M.; PETERSON, GARY D.

    1999-09-27

    In this letter we report the growth (by MOVPE) and characterization of quaternary AlGaInN. A combination of PL, high-resolution XRD, and RBS characterizations enables us to explore and delineate the contours of equil-emission energy and lattice parameters as functions of the quaternary compositions. The observation of room temperature PL emission as short as 351nm (with 20% Al and 5% In) renders initial evidence that the quaternary could be used to provide confinement for GaInN (and possibly GaN). AlGaInN/GdnN MQW heterostructures have also been grown; both x-ray diffraction and PL measurement suggest the possibility of incorporating this quaternary into optoelectronic devices.

  11. Quaternary epitopes of α345(IV) collagen initiate Alport post-transplant anti-GBM nephritis

    DEFF Research Database (Denmark)

    Olaru, Florina; Luo, Wentian; Wang, Xu-Ping

    2013-01-01

    Alport post-transplant nephritis (APTN) is an aggressive form of anti-glomerular basement membrane disease that targets the allograft in transplanted patients with X-linked Alport syndrome. Alloantibodies develop against the NC1 domain of α5(IV) collagen, which occurs in normal kidneys, including...... of alloantibodies against allogeneic collagen IV. Some alloantibodies targeted alloepitopes within α5NC1 monomers, shared by α345NC1 and α1256NC1 hexamers. Other alloantibodies specifically targeted alloepitopes that depended on the quaternary structure of α345NC1 hexamers. In Col4a5-null mice, immunization...... with native forms of allogeneic collagen IV exclusively elicited antibodies to quaternary α345NC1 alloepitopes, whereas alloimmunogens lacking native quaternary structure elicited antibodies to shared α5NC1 alloepitopes. These results imply that quaternary epitopes within α345NC1 hexamers may initiate...

  12. Quaternary shorelines of the broader area of Cape Maleas - Neapolis - Elafonissos Isl. (SE Peloponnese)

    Science.gov (United States)

    Karymbalis, Efthimios; Gaki-Papanastassiou, Kalliopi; Papanastassiou, Dimitris; Tsodoulos, Ioannis; Tsivgoulis, Nikolaos; Tsanakas, Konstantinos; Valkanou, Kanella

    2015-04-01

    marine notches. Remnants of Quaternary marine terraces have also been identified at several locations on the Elafonissos Isl. The marine terraces are imprinted into pre-existing Pleistocene marine - lacustrine formations and only a few of them have a thin sandstone caprock. The uplifted Quaternary marine terraces are excellent morphological markers and have been used worldwide to recognize past sea-level changes. Their correlation with the main interglacial high-stands can be done only in areas where a continuous uplift at a regional scale exists combined by dating their exposure. Selected samples were collected for OSL dating in order to correlate the terraces in space and time. The detailed field geomorphological mapping of the study area revealed a sequence of seven to eight marine terraces, according their location, ranging in elevations from 2 to 180m. Based on the raised coastal features of the study area it becomes evident that the prevailing tectonic movement is positive (emergence) during the Pleistocene and Holocene periods. The occurrence of the terraces at different elevations supports the suggestion that the study area is composed by different tectonic blocks moving disparately.

  13. Combining the least cost path method with population genetic data and species distribution models to identify landscape connectivity during the late Quaternary in Himalayan hemlock.

    Science.gov (United States)

    Yu, Haibin; Zhang, Yili; Liu, Linshan; Qi, Wei; Li, Shicheng; Hu, Zhongjun

    2015-12-01

    Himalayan hemlock (Tsuga dumosa) experienced a recolonization event during the Quaternary period; however, the specific dispersal routes are remain unknown. Recently, the least cost path (LCP) calculation coupled with population genetic data and species distribution models has been applied to reveal the landscape connectivity. In this study, we utilized the categorical LCP method, combining species distribution of three periods (the last interglacial, the last glacial maximum, and the current period) and locality with shared chloroplast, mitochondrial, and nuclear haplotypes, to identify the possible dispersal routes of T. dumosa in the late Quaternary. Then, both a coalescent estimate of migration rates among regional groups and establishment of genetic divergence pattern were conducted. After those analyses, we found that the species generally migrated along the southern slope of Himalaya across time periods and genomic makers, and higher degree of dispersal was in the present and mtDNA haplotype. Furthermore, the direction of range shifts and strong level of gene flow also imply the existence of Himalayan dispersal path, and low area of genetic divergence pattern suggests that there are not any obvious barriers against the dispersal pathway. Above all, we inferred that a dispersal route along the Himalaya Mountains could exist, which is an important supplement for the evolutionary history of T. dumosa. Finally, we believed that this integrative genetic and geospatial method would bring new implications for the evolutionary process and conservation priority of species in the Tibetan Plateau.

  14. Quaternary Alkylammonium Conjugates of Steroids: Synthesis, Molecular Structure, and Biological Studies

    Directory of Open Access Journals (Sweden)

    Bogumił Brycki

    2015-11-01

    Full Text Available The methods of synthesis as well as physical, spectroscopic (1H-NMR, 13C-NMR, and FT-IR, ESI-MS, and biological properties of quaternary and dimeric quaternary alkylammonium conjugates of steroids are presented. The results were contrasted with theoretical calculations (PM5 methods and potential pharmacological properties (PASS. Alkylammonium sterols exhibit a broad spectrum of antimicrobial activity comparable to squalamine.

  15. Progress report. Task 1 - quaternary tectonics, 1 October 1991--30 September 1992

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-09-30

    Progress is reported on a study concerned with the quaternary tectonics of Yucca Mountain, the proposed site for an underground disposal facility for high-level radioactive wastes. Refinement and revision of crater Flat Quaternary stratigraphy continued and consisted of several activities: revision of rock varnish cation leaching curve; sample comparison of RV manganese;,iron microlaminations;and correlation of Crater Flat allostratigraphic units with regional chronologies.

  16. From Morphostratigraphy to Chronostratigraphy – Modern Quaternary Geomorphology as a Basic for Climatic Research

    OpenAIRE

    Böse, Margot

    2015-01-01

    In preparation for the Congress of the International Association of Geomorphologists (IAG) in Paris 2013, our French colleagues discussed session proposals with their colleagues from other countries. Hanna Bremer, the internationally renowned geomorphologist from Germany, was informally involved in the discussion – and she proposed a session with Quaternary aspects; I got involved as geomorphologist and president of the German Quaternary Association (DEUQUA) at that time. We were still develo...

  17. Sustainable groundwater development and management in the Quaternary Hang-Jia-Hu Plain, China

    Institute of Scientific and Technical Information of China (English)

    朱琰

    2002-01-01

    Based on the results of study on regional water supply system, water quality assessments, Quaternary aquifers investigation, and correlation analysis of groundwater depression resulting from land subsidence in the Hang-Jia-Hu Quaternary Plain, this paper presents the groundwater resources policy and sustainable management methods suitable for this area. Suggestions for controlling land subsidence by implementation of wise groundwater policy and management measures are also given.

  18. Quaternary Alkylammonium Conjugates of Steroids: Synthesis, Molecular Structure, and Biological Studies.

    Science.gov (United States)

    Brycki, Bogumił; Koenig, Hanna; Pospieszny, Tomasz

    2015-11-23

    The methods of synthesis as well as physical, spectroscopic (¹H-NMR, 13C-NMR, and FT-IR, ESI-MS), and biological properties of quaternary and dimeric quaternary alkylammonium conjugates of steroids are presented. The results were contrasted with theoretical calculations (PM5 methods) and potential pharmacological properties (PASS). Alkylammonium sterols exhibit a broad spectrum of antimicrobial activity comparable to squalamine.

  19. Synthesis of Main-Chain Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Using Quaternization Polymerization

    Directory of Open Access Journals (Sweden)

    Md. Masud Parvez

    2012-06-01

    Full Text Available Main-chain chiral quaternary ammonium polymers were successfully synthesized by the quaternization polymerization of cinchonidine dimer with dihalides. The polymerization occurred smoothly under optimized conditions to give novel type of main-chain chiral quaternary ammonium polymers. The catalytic activity of the polymeric chiral organocatalysts was investigated on the asymmetric benzylation of N-(diphenylmethylideneglycine tert-butyl ester.

  20. Quaternary Organic Amines Inhibit Na,K Pump Current in a Voltage-dependent Manner

    OpenAIRE

    2004-01-01

    The effects of organic quaternary amines, tetraethylammonium (TEA) chloride and benzyltriethylammonium (BTEA) chloride, on Na,K pump current were examined in rat cardiac myocytes superfused in extracellular Na+-free solutions and whole-cell voltage-clamped with patch electrodes containing a high Na+-salt solution. Extracellular application of these quaternary amines competitively inhibited extracellular K+ (K+ o) activation of Na,K pump current; however, the concentration for half maximal inh...

  1. The pragmatic roots of American Quaternary geology and geomorphology

    Science.gov (United States)

    Baker, Victor R.

    1996-07-01

    H.L. Fairchild's words from the 1904 Geological Society of America Bulletin remain appropriate today: "Geologists have been too generous in allowing other people to make their philosophy for them". Geologists have quietly followed a methodological trinity involving (1) inspiration by analogy, (2) impartial and critical assessment of hypotheses, and (3) skepticism of authority (prevailing theoretical constraints or paradigms). These methods are described in classical papers by Quaternary geologists and geomorphologists, mostly written a century ago. In recent years these papers have all been criticized in modern philosophical terms with little appreciation for the late 19th century American philosophical tradition from which they arose. Recent scholarly research, however, has revealed some important aspects of that tradition, giving it a coherence that has largely been underappreciated as 20th century philosophy of science pursued its successive fads of logical positivism, critical rationalism, relativism, and deconstructivism — for all of which "science" is synonymous with "physics". Nearly all this ideology is geologically irrelevant. As philosophy of science in the late 20th century has come to be identical with philosophy of analytical physics, focused on explanations via ideal truths, much of geology has remained true to its classical doctrines of commonsensism, fallibilism, and realism. In contrast to the conceptualism and the reductionism of the analytical sciences, geology has emphasized synthetic thinking: the continuous activity of comparing, connecting, and putting together thoughts and perceptions. The classical methodological studies of geological reasoning all concern the formulation and testing of hypotheses. Analysis does not serve to provide the ultimate answers for intellectual puzzles predefined by limiting assumptions imposed on the real world. Rather, analysis in geology allows the investigator to consider the consequential effects of

  2. Time-Domain Quaternary-Weighted Pulse Width Modulation Driving Method for Active Matrix Organic Light-Emitting Diode Displays

    Science.gov (United States)

    Park, Hyun-Sang; Kuk, Seung-Hee; Han, Min-Koo

    2008-03-01

    We proposed a new digital driving method and its pixel structure for active matrix organic light-emitting diode (AMOLED) displays employing time-domain quaternary-weighted pulse width modulation. In the new digital driving method, the luminance of AMOLED displays is accurately determined by averaging photon flux to the desired level over a frame period. The proposed pixel was verified by spice simulation and the output linearity between the grayscale and the OLED current was successfully achieved. In the proposed digital driving pixel, the timing margin was increased and the effect on luminance of AMOLED displays by the troublesome variation of the thin-film transistors (TFTs) was suppressed without additional compensation schemes.

  3. Quaternary continetal back-arc evolution from southern Mendoza, Argentina

    Science.gov (United States)

    Espanon, Venera; Chivas, Allan; Dosseto, Anthony; Honda, Masahiko; Phillips, David; Matchan, Erin; Price, David

    2016-04-01

    The Quaternary evolution of the Payenia Basaltic Province (PBP) in southern Mendoza, Argentina has been investigated using a multi-dating approach in combination with pre-exiting geochemical data. This basaltic province covers an area of approximately 40000 km2 and is mainly characterised by backarc volcanism. In the current investigation nine new radiometric ages obtained using surface exposure, 40Ar/39Ar and thermoluminescence dating are presented. Six ages correspond to the late Pleistocene and three to the Holocene. The surface exposure ages obtained using cosmogenic 3He and 21Ne are in good agreement with previous publications and confidently suggest that part of this basaltic province was active at least 4000 years ago (taking a conservative approach). In addition, we combined the available geochronological and geochemical data to reconstruct the Quaternary evolution of this basaltic province. This approach was used to create maps of geospatial distribution of trace-element ratios to determine geochemical changes during the Pleistocene. Employing this method it is evident that two geochemical distinct types of magma were erupting at the same time interval within the PBP. In the north eastern part (Nevado volcanic field) of the PBP an arc-like signature is evident, while in the southern part (Río Colorado volcanic field) of the same basaltic province an Ocean Island Basalt (OIB) signature is evident. The arc-like signature in the north eastern part of the PBP, decreased during the Pleistocene in a north-west direction indicated by a reduction in Ba/La and La/Ta in the Nevado and Llancanelo volcanic field. The Holocene volcanism is restricted to the western side of the Payún Matrú volcanic field and is dominated by OIB-like signatures such as high Ta/Hf and low Ba/La and La/Ta. This contribution presents new geochronology for the PBP and confirms that two different types of volcanism occurred simultaneously during the Pleistocene, while the Holocene

  4. A model of the Quaternary geological deposits of Bucharest City

    Science.gov (United States)

    Serpescu, Irina; Radu, Emil; Radu Gogu, Constantin; Amine Boukhemacha, Mohamed; Gaitanaru, Dragos; Bica, Ioan

    2013-04-01

    Bucharest city is located in the central part of the Moesic Platform, in the Romanian Plain with micro-relief resulting from erosion and sedimentary processes which extended along the valleys of the Dambovita River to the south and the Colentina River to the north. The city is located in the axial area of a syncline where the thickness of the sedimentary deposits is up to 1000 m. The area lies on a rigid base is made of metamorphites, and various igneous intrusions (granodiorite, granite). The sedimentary deposits covering this rigid base are made by different phases of erosion and sedimentary processes of marine, lacustrian or continental sediments ending with Quaternary sediments. As a result, different alluvial deposits (such as piedmont, deltaic, alluvial cones, terrace, waterside and lacustrine deposits) can be met. Furthermore one also can find loess deposits which in turn cover totally the older deposits where rivers dug the present relief. To highlight the spatial extent of these geological structures, a geological model of Bucharest city is developed. A set of information coming from different sources as geological and geotechnical boreholes showing a detailed geological and lithological description, geological and topographical maps, geological and hydrogeological reports have been used to develop the 3D geological model of this region. 33 geological cross sections were defined and interpreted by using lithological and sedimentological criteria. Using these geological cross sections and prior geological knowledge, the Quaternary deposits have been described and classified into 6 structural units given from top to down as follows: (1) Superficial deposits represented by loess and anthropogenic materials. The geological model indicates that these deposits show a sporadic development becoming more concentrated in the central west part of the city. (2) Colentina Formations composed by of poorly sorted, cross-stratified sand and gravel with clayey lens

  5. Quaternary ammonium derivatives as spasmolytics for irritable bowel syndrome.

    Science.gov (United States)

    Evangelista, S

    2004-01-01

    Quaternary ammonium derivatives such as cimetropium, n-butyl scopolammonium, otilonium and pinaverium bromide have been discovered and developed as potent spasmolytics of the gastrointestinal tract. Their pharmacological activity has been proven in both "in vivo" and "in vitro" studies of hypermotility. "In vitro" experiments showed that they possess antimuscarinic activity at nM level but only pinaverium and otilonium are endowed with calcium channel blocker properties. These latter compounds relaxed the gastrointestinal smooth muscle mainly through a specific inhibition of calcium ion influx through L-type voltage operated calcium channels. Molecular pharmacology trials have indicated that pinaverium and otilonium can bind specific subunits of the calcium channel in the external surface of the plasma membrane and in this way they block the machinery of the contraction. Recent evidence showed that otilonium is able to bind tachykinin NK(2) receptors and not only inhibits one of the major contractile agents but can reduce the activation of afferent nerves devoted to the passage of sensory signals from the periphery to the central nervous system. Thanks to their typical physico-chemical characteristics, they are poorly absorbed by the systemic circulation and generally remain in the gastrointestinal tract where they exert the muscle relaxant activity by a local activity. Some differences exists in the absorption among these compounds: both n-butyl scopolammonium and cimetropium are partially taken up in the bloodstream, pinaverium has a low absorption (8-10 %) but is endowed with an excellent hepato-biliary excretion and otilonium, which has the lowest absorption (3 %), is almost totally excreted by faeces. Quaternary ammonium derivatives are widely used for the treatment of irritable bowel syndrome and recent meta-analyses have supported their efficacy in this disease. Due to its therapeutic index, the use of n-butyl scopolammonium is more indicated to treat acute

  6. Quaternary Deformation of Sumba, Indonesia: Evidence from Carbonate Terraces

    Science.gov (United States)

    Dahlquist, M. P.; West, A. J.; Dolan, J. F.

    2014-12-01

    The Banda Arc of Indonesia remains one of the least understood tectonic domains on the modern Earth. The island of Sumba, located approximately 50 km south of Flores and 120 km north of the Java Trench, northwest of where it transitions into the Timor Trough, lies in a region of tectonic transition and potentially offers insights into regional dynamics. The Banda Arc is volcanically active, but Sumba itself is not volcanic. The northern coast of Sumba is covered in Quaternary coral terraces, with the rest of the island's surface geology composed of Mio-pliocene carbonates and uplifted Late Cretaceous-Oligocene forearc basin and volcanic rocks. The purpose of this study is to remotely map the topographic expression of the coral terraces and use the information gained to better understand deformation on Sumba since their deposition. The ages of the coral terraces, of which many platforms are exposed over significant areas of the island, have been constrained at Cape Luandi in north central Sumba, but uplift rates calculated from those ages may not be representative of the island as a whole. The lateral continuity of these dated terraces can help constrain the extent to which uplift of Sumba is spatially variable. Analysis of the terraces using SRTM digital elevation data with ArcGIS software makes it possible to trace the same terrace platforms over large distances, and shows that the north central part of the island has experienced the most uplift since the deposition of the terraces, forming an anticline with the east limb dipping more steeply than the west. The terraces are not well preserved on the southern half of the island. Exposure of older rocks and lack of terrace preservation, as well as a south-skewed drainage divide suggests the southern half of the island experiences greater exhumation, but this could be driven by climate or other factors and does not necessarily indicate more rapid uplift. Study of Quaternary deformation of Sumba can offer greater

  7. Expanding extension, subsidence and lateral segmentation within the Santorini - Amorgos basins (central - south Aegean Sea, Greece) during Quaternary.

    Science.gov (United States)

    Nomikou, Paraskevi; Hübscher, Christian; Papanikolaou, Dimitris; Farangitakis, Georgios-Pavlos; Ruhnau, Marcel; Lampridou, Danai

    2017-04-01

    New bathymetric and seismic reflection data from the Santorini-Amorgos Tectonic Zone in the southern Cyclades have been analysed and a description of the morphology and tectonic structure of the area has been presented. The basins of Anhydros, Amorgos and Santorini-Anafi have been distinguished together with the intermediate Anhydros Horst within the NE-SW oriented Santorini-Amorgos Tectonic Zone which has a length of 60-70km and a width of 20-25km. The basins represent tectonic grabens or semigrabens bordered by the active marginal normal faults of Santorini-Anafi, Amorgos, Ios, Anhydros and Astypalaea. The Santorini-Anafi, Amorgos and Ios marginal faults have their footwall towards the NW where Alpine basement occurs in the submarine scarps and their hangingwall towards the southeast, where the Quaternary sediments have been deposited with maximum thickness of 700m. Six sedimentary units 1-6 have been distinguished in the stratigraphic successions of the Santorini-Anafi and the westerrn Anhydros Basin whereas in the rest area only the upper four units 3-6 have been deposited. This shows the expansion of the basin with subsidence during the Quaternary due to ongoing extension in a northwest-southeast direction. Growth structures are characterised by different periods of maximum deformation as this is indicated by the different sedimentary units with maximum thickness next to each fault. Transverse structures of northwest-southeast direction have been identified along the Santorini-Amorgos Tectonic Zone with distinction of the blocks/segments of Santorini, Anhydros/Kolumbo, Anhydros islet and Amorgos. Our study shows that the active geodynamic regime is an ongoing process evolved during the last 2-3myears with well-defined periods of expanding, extension and subsidence of a rift zone which however has been segmented by transverse structures separating different geodynamic processes of faulting, tilting, volcanism and morphogenesis.

  8. Quaternary Geologic Map of the Lake Nipigon 4 Degrees x 6 Degrees Quadrangle, United States and Canada

    Science.gov (United States)

    Sado, Edward V.; Fullerton, David S.; Farrand, William R.; Edited and Integrated by Fullerton, David S.

    1994-01-01

    The Quaternary Geologic Map of the Lake Nipigon 4 degree x 6 degree Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale. This map is a product of collaboration of the Ontario Geological Survey, the University of Michigan, and the U.S. Geological Survey, and is designed for both scientific and practical purposes. It was prepared in two stages. First, separate maps and map explanations were prepared by the compilers. Second, the maps were combined, integrated, and supplemented by the editor. Map unit symbols were revised to a uniform system of classification and the map unit descriptions were prepared by the editor from information received from the compilers and from additional sources listed under Sources of Information. Diagrams accompanying the map were prepared by the editor. For scientific purposes, the map differentiates Quaternary surficial deposits on the basis of lithology or composition, texture or particle size, structure, genesis, stratigraphic relationships, engineering geologic properties, and relative age, as shown on the correlation diagram and indicated in the map unit descriptions. Deposits of some constructional landforms, such as kame moraine deposits, are distinguished as map units. Deposits of

  9. Quaternary Geologic Map of the Lake of the Woods 4 Degrees x 6 Degrees Quadrangle, United States and Canada

    Science.gov (United States)

    Sado, Edward V.; Fullerton, David S.; Goebel, Joseph E.; Ringrose, Susan M.; Edited and Integrated by Fullerton, David S.

    1995-01-01

    The Quaternary Geologic Map of the Lake of the Woods 4 deg x 6 deg Quadrangle, United States and Canada, was mapped as part of the U.S. Geological Survey Quaternary Geologic Atlas of the United States map series (Miscellaneous Investigations Series I-1420, NM-15). The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale. This map is a product of collaboration of the Ontario Geological Survey, the Minnesota Geological Survey, the Manitoba Department of Energy and Mines, and the U.S. Geological Survey, and is designed for both scientific and practical purposes. It was prepared in two stages. First, separate maps and map explanations were prepared by the compilers. Second, the maps were combined, integrated, and supplemented by the editor. Map unit symbols were revised to a uniform system of classification and the map unit descriptions were prepared by the editor from information received from the compilers and from additional sources listed under Sources of Information. Diagrams accompanying the map were prepared by the editor. For scientific purposes, the map differentiates Quaternary surficial deposits on the basis of lithology or composition, texture or particle size, structure, genesis, stratigraphic relationships, engineering geologic properties, and relative age, as shown on the correlation diagram and

  10. New morphostratigraphic and chronological constraints for the Quaternary paleosurfaces of the Molise Apennine (southern Italy)

    Science.gov (United States)

    Aucelli, Pietro P. C.; Amato, Vincenzo; Cesarano, Massimo; Pappone, Gerardo; Rosskopf, Carmen M.; Ermolli, Elda Russo; Scarciglia, Fabio

    2011-02-01

    The Molise Apennines feature numerous relicts of paleosurfaces, mostly of erosional origin, which represent the remnants of gently-rolling ancient landscapes now hanging at different altitudes above the local base-levels of erosion. Their genesis can be related to prolonged periods of relative tectonic stability alternating with periods of uplift, or to the interplay between steady tectonic uplift and climatic fluctuations. Four orders of paleosurfaces were recognized: I (> 1,100 m a.s.l.), II (900-1,000 m a.s.l.), III (750-850 m a.s.l.), IV (600-720 m a.s.l.). The most ancient orders (I and II) are cut into the bedrock and are located at the top of the Matese and Montagnola di Frosolone massifs. The youngest paleosurfaces (III—IV), partially cut into Quaternary deposits, are found along the valley flanks of the main river systems and within the Boiano, Carpino, Isernia and Sessano intramontane basins. The present study deals with the dating of the Sessano Basin Paleosurface (SBP) which is related to the IV order and is cut into the basin infill. The 40Ar/39Ar age of a tephra layer (437 ± 1.9 ka), intercalated at the top of the succession, supported by archaeo-stratigraphic, palynological and paleopedological data, allowed the SBP surface to be constrained to 350-300 ka. The SBP chronological position represents an important morphostratigraphic marker: it is the first ante quem and post quem date that allows the chronological position of the other orders of paleosurfaces to be better constrained.

  11. Human impact on late Quaternary landscapes in the Central Spanish Pyrenees

    Science.gov (United States)

    Hirsch, F.; Raab, T. A.

    2011-12-01

    Like the Alps in Central Europe the Pyrenees in Southeast Europe are well known for their glacial history. Within the scope of the ongoing research project Post-LGM pedogenesis and geomorphodynamics in the Aragonese Pyrenees, Spain, funded by the Deutsche Forschungsgemeinschaft (DFG), we are studying the landscapes in the Gallego valley and the Aragon valley formed during the late Quaternary period. The aim of this research is to describe and characterize the soil development since the retreat of the valley glaciers from the LGM-moraines which are supposed to have an age of up to 60 ka yrs. To these purposes soil profiles are excavated in sediments and landforms of different ages (LGM to Holocene) and different genesis (glacigenic, glacifluvial, fluvial, gravitational). The soil profiles are arranged as catenas and provide insight into the pedo-stratigraphy of moraines, fluvial terraces, glacis and alluvial fans. Our preliminary results show that besides geogenic process past human land use must be considered as a main trigger of landscape development during the late Holocene. Truncated soil profiles in the backslopes and the correlate sediments of soil erosion burying soil horizons in the footslopes clearly indicate one or even more periods of re-shaping the landforms after deglaciation. Considerable amounts of small charcoal and tile fragments in the translocated sediments hint to an anthropogenic agent. The disturbance in the soil profiles and sediments is visible in the field and by micromorphology. Although 14C and OSL datings on the base of the correlate sediments of soil erosion indicate at least one phase of erosion and redeposition at the end of the 17th century, the onset of afresh pedogenic processes in the correlate sediments of soil erosion indicate young soil formation.

  12. Possible Late Quaternary faulting in the Benton Hills, southeastern Missouri

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, J.R.; Hoffman, D. (Missouri Geological Survey Program, Rolla, MO (United States). Dept. of Natural Resources)

    1993-03-01

    Geologic mapping in the 1930's by Dan Stewart and Lyle McManamy identified numerous faults in the Thebes Gap area of the Benton Hills, including two post-late Quaternary faults (max. of 10 m displacement) along the southeastern escarpment. Recent geologic mapping (Richard Harrison, pers. comm.) suggests dextral strike-slip displacement on most of these faults; some deformation post-dates the Pliocene-Pleistocene Mounds gravel. Small historical earthquake epicenters have been recorded in the Benton Hills area. Review of these data and analysis of the geologic and structural relationships to small- and large-scale drainage and alluvial features suggest tectonic control of the southeastern escarpment of the Benton Hills. The authors propose the coincidence of geologic structures and landforms resembles tectonically active alluvial basin margins, with the Benton Hills southeastern margin representing a fault block uplift escarpment. Future seismic reflection, drilling and trenching studies are planned to determine if the escarpment is fault controlled and of recent origin.

  13. Enhanced adsorption of quaternary amine using modified activated carbon.

    Science.gov (United States)

    Prahas, Devarly; Wang, M J; Ismadji, Suryadi; Liu, J C

    2014-01-01

    This study examined different methodologies to modify activated carbon (AC) for the removal of quaternary amine, tetramethylammonium hydroxide (TMAH), from water. Commercial carbon (WAC) was treated by nitric acid oxidation (NA-WAC), silica impregnation (SM-WAC0.5), and oxygen plasma (P10-WAC), and their characteristics and adsorption capacity were compared. The Langmuir model fitted the equilibrium adsorption data well under different pH. The maximum adsorption capacity of WAC was 27.77 mg/g, while those of NA-WAC, SM-WAC 0.5, and P10-WAC were 37.46, 32.83 and 29.03 mg/g, respectively. Nitric acid oxidation was the most effective method for enhancing the adsorption capacity of TMAH. Higher pH was favorable for TMAH adsorption. Desorption study revealed that NA-WAC had no considerable reduction in performance even after five cycles of regeneration by 0.1 N hydrochloric acid. It was proposed that electrostatic interaction was the main mechanism of TMAH adsorption on activated carbon.

  14. Antibacterial Activity of Dental Cements Containing Quaternary Ammonium Polyethylenimine Nanoparticles

    Directory of Open Access Journals (Sweden)

    Nurit Beyth

    2012-01-01

    Full Text Available Glass ionomer cements (GICs are commonly used for cementing full cast crown restorations. Regrettably, although the dental cements fill the gap between the tooth and the crown, bacterial microleakage may occur, resulting in secondary caries. As microleakage cannot be completely prevented, GICs possessing antibacterial properties are in demand. In the present study the antibacterial activity of insoluble, cross-linked quaternary ammonium polyethylenimine (QPEI nanoparticles incorporated at 1% w/w in two clinically available GICs were studied. The antibacterial activity was tested against Streptococcus mutans and Lactobacillus casei using the direct contact test (DCT and the agar diffusion test (ADT. Using the direct contact test, antibacterial activity (<0.05 was found in both tested GICs with incorporated QPEI nanoparticles, the effect lasting for at least one month. However, the ADT showed no inhibition halo in the test bacteria, indicating that the antimicrobial nanoparticles do not diffuse into the agar. The results show that the incorporation of QPEI nanoparticles in glass ionomer cements has a long-lasting antibacterial effect against Streptococcus mutans and Lactobacillus casei. Changing the antibacterial properties of glass ionomer cements by incorporating QPEI antibacterial nanoparticles may prolong the clinical performance of dental crowns.

  15. Late Quaternary deformation, Saddle Mountains anticline, south-central Washington

    Science.gov (United States)

    West, M. W.; Ashland, F. X.; Busacca, A. J.; Berger, G. W.; Shaffer, M. E.

    1996-12-01

    Grabens and beheaded streams above a subjacent thrust fault illuminate late Quaternary deformation on the north limb of the Saddle Mountains anticline, Yakima fold belt, Washington. Geologic mapping and trenches excavated across a scarp on the north flank of a 13-km-long graben and a ± 5-m-high scarp north of the graben, confirm that deformation is related to coseismic slip on the underlying Saddle Mountains fault. Graben development began ca. 100 ka and continued into the Holocene. At least 6.5 m of vertical displacement in a ca. 20 40 ka paleosol yields minimum normal fault slip rates of 0.16 0.33 mm/yr. Assuming that normal slip in the hanging wall above the daylighting fault tip is related to primary reverse slip on the fault, resolution of throw on the 30°-dipping Saddle Mountains fault yields minimum slip of 13 m and minimum slip rates of 0.33 0.65 mm/yr, 2.3 9.4 times greater than slip rates used in a recent seismic hazard analysis for the Hanford Reservation.

  16. Late Quaternary carbonate accumulation along eastern South Atlantic Ocean

    Science.gov (United States)

    Crabill, K.; Slowey, N. C.; Foreman, A. D.; Charles, C. D.

    2015-12-01

    Water masses originating from both the North Atlantic Ocean and the Southern Ocean intersect the Walvis Ridge and Namibian margin of southwest Africa. Changes in the distribution and properties of these water masses through time are reflected by variations in the nature of the sediments accumulating along this margin. As part of our ongoing studies, we are investigating the interrelationships between oceanographic/climatic change and the accumulation of carbonate minerals during the late Quaternary. A suite of cores that possess sediment records corresponding to the most recent glacial-interglacial cycles was collected from the water depth range of 500 to 3000 meters. Cores that preserve records of key water masses were selected for detailed analyses. Sediment bulk density, the concentration of calcium carbonate, and the relative proportions of carbonate minerals were precisely determined at regular depth intervals in these cores. Foraminiferal d18O and C-14 dates provide chronologic control. Results will be used to calculate how the accumulation rates of carbonate minerals on the seafloor vary through time, and the correspondence of such variation to changes in ocean circulation and climate will be assessed.

  17. Ligand exchange in quaternary alloyed nanocrystals--a spectroscopic study.

    Science.gov (United States)

    Gabka, Grzegorz; Bujak, Piotr; Giedyk, Kamila; Kotwica, Kamil; Ostrowski, Andrzej; Malinowska, Karolina; Lisowski, Wojciech; Sobczak, Janusz W; Pron, Adam

    2014-11-14

    Exchange of initial, predominantly stearate ligands for pyridine in the first step and butylamine (BA) or 11-mercaptoundecanoic acid (MUA) in the second one was studied for alloyed quaternary Cu-In-Zn-S nanocrystals. The NMR results enabled us to demonstrate, for the first time, direct binding of the pyridine labile ligand to the nanocrystal surface as evidenced by paramagnetic shifts of the three signals attributed to its protons to 7.58, 7.95 and 8.75 ppm. XPS investigations indicated, in turn, a significant change in the composition of the nanocrystal surface upon the exchange of initial ligands for pyridine, which being enriched in indium in the 'as prepared' form became enriched in zinc after pyridine binding. This finding indicated that the first step of ligand exchange had to involve the removal of the surface layer enriched in indium with simultaneous exposure of a new, zinc-enriched layer. In the second ligand exchange step (replacement of pyridine with BA or MUA) the changes in the nanocrystal surface compositions were much less significant. The presence of zinc in the nanocrystal surface layer turned out necessary for effective binding of pyridine as shown by a comparative study of ligand exchange in Cu-In-Zn-S, Ag-In-Zn-S and CuInS2, carried out by complementary XPS and NMR investigations.

  18. Late Quaternary environments, vegetation and agriculture in northern New Zealand

    Science.gov (United States)

    Horrocks, M.; Nichol, S. L.; Augustinus, P. C.; Barber, I. G.

    2007-03-01

    A sedimentological and plant microfossil history of the Late Quaternary is preserved in two sediment cores from early Polynesian ditch systems on southern Aupouri Peninsula. The study places human activities into a geomorphological and ecological context and allows comparison of natural and anthropogenic effects on two different geological settings: a floodplain and a relatively closed peat swamp. The data fill part of the current gap in the environmental record from northern New Zealand, namely MIS 3 (57k-26k yr BP). There is evidence for an increase in fire frequency in the region after 40k 14C yr BP, suggesting a shift to drier (and cooler) conditions. Pollen records show that conifer-hardwood forest dominated by podocarps (especially Dacrydium) prevailed prior to Polynesian arrival and deforestation within the last millennium, with Fuscopsora insignificant throughout. Both cores show sections with gaps in deposition or preservation, possible flood-stripping of peat during the pre-Holocene and mechanical disturbance by early Polynesians. The identification of prehistoric starch grains and other microremains of introduced Colocasia esculenta (taro) in both cores supports indirect evidence that the ditch systems of far northern New Zealand were used for the extensive cultivation of this crop. Copyright

  19. Interaction of ochratoxin A with quaternary ammonium beta-cyclodextrin.

    Science.gov (United States)

    Poór, Miklós; Kunsági-Máté, Sándor; Szente, Lajos; Matisz, Gergely; Secenji, Györgyi; Czibulya, Zsuzsanna; Kőszegi, Tamás

    2015-04-01

    Ochratoxin A (OTA) is a widely spread nephrotoxic food contaminant mycotoxin. Unfortunately, attenuation or prevention of the toxic effects of OTA is still an unresolved problem. Molecular inclusion of OTA by cyclodextrins (CDs) results in complexes with low stability. In the human organism, OTA exists mostly in the dianionic state (OTA(2-)). Therefore, our major goal was to develop a chemically modified cyclodextrin which gives a more stable complex with OTA than the previously published derivatives and which shows stronger preference towards OTA(2-). In our fluorescence spectroscopic study we demonstrate that quaternary ammonium beta-cyclodextrin (QABCD) fulfils both of these requirements. The calculated stability constant of the QABCD-OTA(2-) complex was 28,840 M(-1) (about 200-fold higher than that of the β-CD-OTA(2-) complex). We hypothesize, that QABCD may be a suitable tool for the decontamination of different OTA-contaminated drinks; furthermore, for alleviation of the toxic effects of OTA, such complex formation may reduce its absorption from the intestine.

  20. Summary of Quaternary geology of the Municipality of Anchorage, Alaska

    Science.gov (United States)

    Schmoll, H.R.; Yehle, L.A.; Updike, R.G.

    1999-01-01

    Quaternary geology of the Upper Cook Inlet region is dominated by deposits of glacier retreats that followed repeated advances from both adjacent and more distant mountains. At several levels high on the mountains, there are remnant glacial deposits and other features of middle or older Pleistocene age. Late Pleistocene lateral moraines along the Chugach Mountain front represent successively younger positions of ice retreat from the last glacial maximum. As the trunk glacier retreated northeastward up the Anchorage lowland, Cook Inlet transgressed the area, depositing the Bootlegger Cove Formation and Tudor Road deposits. The glacier then readvanced to form the latest Pleistocene Elmendorf Moraine, a prominent feature that trends across the Anchorage lowland. Extensive alluvium was deposited both concurrently and somewhat later as Cook Inlet regressed. Mountain valleys contain (1) locally preserved moraines possibly of early Holocene age; (2) poorly preserved moraine remnants of older late Holocene age; and (3) well-preserved moraines formed mainly during the Little Ice Age. Glaciers still occupy large parts of the mountains, the upper ends of some mountain valleys, and small cirques. Holocene landslide deposits, including those formed during the great Alaska earthquake of 1964, occur throughout the area, especially along bluffs containing the Bootlegger Cove Formation.

  1. Late Quaternary Alluvial Fans of Southern Baja California, Mexico: Relation to Eastern Pacific Tropical Cyclones

    Science.gov (United States)

    Antinao, J.; McDonald, E.

    2009-12-01

    In the arid, non-glaciated regions of the Southwestern USA and Northwestern Mexico, aggradation in alluvial fan systems has been traditionally linked to cold and humid periods (e.g., Last Glacial Maximum) or to the transition to warm periods (e.g., the Pleistocene-Holocene transition, PHT). However, major intervals of sediment transport and aggradation have also occurred during climatically warm periods in these regions. These periods have also been identified as portraying enhanced humidity or “monsoonal’ conditions. Investigations on the weather systems able to perform geomorphic work during predominantly warm periods, i.e. the North American Monsoon (NAM) and Eastern Pacific (EP) Tropical Cyclones (TCs), have concentrated mainly in the USA. To understand the relative contribution of these systems to sediment transport over millennial timescales, we have mapped and characterized preliminarily the alluvial fans in four different areas of the Southern Baja California peninsula, Mexico. This region is dominated by EPTC precipitation, which in turn is driving the sediment transport along alluvial channels. Detailed geomorphologic mapping shows that a distinct Late Quaternary chronostratigraphy of alluvial fan units can be developed using geochronological and pedological tools. Specifically, a soil chronosequence can be compared to sequences in the SW USA, allowing a correlation to Late Pleistocene - Holocene events in the region. At least five alluvial units can be identified. Older units have well defined gravel pediments, Av and B horizons and pervasive pedogenic carbonate morphology, with alluvial terraces that rise tens of meters above the present channel. Intermediate age units have developed B horizons and carbonate morphology at different stages. The younger units have thin soil horizons, no carbonate morphology in the soil profile, and some of them are subject to episodic flooding during TC activity. The chronosequence developed is the first step towards

  2. Modeling global vegetation in the late Quaternary: What progress have we made and what are the priorities for the future?

    Science.gov (United States)

    Kaplan, Jed

    2017-04-01

    More than two decades ago, the development of the first global biogeography models led to an interest in simulating global land cover in the past. These models promised the possibility of creating a coherent picture of the Earth's vegetation that went beyond qualitative extrapolation of site-based observations, e.g., from paleoecological archives, and was not limited to areas with a high density of sites. Then as now, the goal of much work simulating past vegetation was to explore and understand the role of biogeophysical and biogeochemical feedbacks between the Earth's land surface and the climate system. Paleovegetation modeling for the late Quaternary has also influenced debates on the character of natural vegetation, conservation and ecological restoration goals, and the co-evolution of humans, civilizations, and the landscapes in which they live. The first simulations of global land cover in the past used equilibrium vegetation models, e.g., BIOME1, BIOME3, and BIOME4, and focused on well-known timeslices of interest in paleoclimate research, including the Last Glacial Maximum (21,000 BP) and the mid-Holocene (6,000 BP). Questions addressed included: quantification of the importance of terrestrial vegetation in the glacial carbon cycle, the role of changing vegetation cover on glacial inception, and the influence of biogeophysical feedbacks on the amplitude and spatial pattern of the mid-Holocene African Monsoon. In the intervening years, as both vegetation and climate models evolved and improved, the spatial resolution, number of periods studied, and the type of research questions addressed expanded greatly. Studies covered the dynamics of Arctic vegetation, wetland area, wetland methane emissions, and paleo-atmospheric chemistry, dust emissions and effects on paleoclimate, among others. A major recent advance in paleovegetation modeling for the late Quaternary has come with the development of Dynamic Global Vegetation Models (DGVMs) that are capable of

  3. The age measures and its layer sequence tratigraphy of Late Quaternary sediment in Lushan Dajiaochang of China

    Institute of Scientific and Technical Information of China (English)

    Hu Dongsheng; Hu Rong; Li Xiaoyu; Hu Wenxuan; Wang Xulong; Tian Xingong; Liu Weiguo; Zhang Guowei

    2013-01-01

    Through the scientific investigation on Lushan for a long time,detailed studies have been carried out on the geologic stratum section of Late Quaternary in Dajiaochang. The series age data of complete stratigraphic section and full time formation since 400 kaBP were based on the results of the analyses using the dating methods with various instruments such as the ancient geomagnetism,electronics spin resonance (ESR),36Cl and lumines-cence dating,etc. Corresponding to these data,it identified the paleomagnetic polarity events including Biwa-Ⅲevent (320 kaBP),Biwa-Ⅱevent (260 kaBP),Biwa-Ⅰevent (180 kaBP,scarcity due to the disturbance of the iron dish),Blake event (100 kaBP) and Laschamp event (20 kaBP,didn’t grow due to the activities of the surface), etc. Combined with the sequence stratigraphy,layer type characteristics and its sediment environment,the strati-graphic can be divided into 4 stages of development respectively:StageⅠis the climate period of glacial epoch (200~400 kaBP);stageⅡis the climate period of interglacial epoch (100~200 kaBP);stageⅢis the climate peri-od of periglacial epoch (10~100 kaBP);stageⅣis the climate period of postglacial epoch (0~10 kaBP).

  4. Vegetation evolution on the central Chinese Loess Plateau since late Quaternary evidenced by elemental carbon isotopic composition

    Institute of Scientific and Technical Information of China (English)

    ZHOU Bin; SHEN ChengDe; ZHENG HongBo; ZHAO MeiXun; SUN YanMin

    2009-01-01

    There are many controversial issues in loess studies such as natural vegetation types on the Chinese Loess Plateau during the historical periods and the spatial and temporal evolution of C3/C4 plants.Elemental carbon isotopic composition (δ13Cec) in the loess section may offer new evidence for these problems. Elemental carbon (EC) is produced by incomplete combustion of vegetation, and its carbon isotopic composition has a very small difference from that of the formal vegetation, then δ13Cec can be used as a record to recover the changes of vegetation. Elemental carbon was extracted by applying the oxidation method from the loess-paleosol sequence in the central Chinese Loess Plateau, and its carbon isotope composition was analyzed by the isotope mass spectrometer. The results showed that the vegetation in this region was a mixed type of C3 and C4 plants, dominated with C3 plants in most of the time. Since late Quaternary, C3/C4 plants may not follow a simple glacial-interglacial cycle mode on the Chinese Loess Plateau, but showing fluctuations. C3 plants increased gradually in L4 period, and more C3 plants occurred during S3 period, and C4 plants increased again during L3-L2 periods, after that, C3plants dominated again during S1-S0 periods. During periods of paleosol development, C3 plants were abundant in S3 and S1, and there were more C4 plants in S2 and S0. During periods of loess sedimentation, there were more C3 plants in L4 and L1, and there were more C4 plants in L3 and L2. On the orbital timescale, the vegetation variations revealed by δ13Cec record are consistent with the results of pollen data and also similar to the results obtained by organic carbon isotopic composition since the last glacial period.

  5. The Quaternary climate records of coral reef in the tropical zone of China%中国热带珊瑚礁的第四纪气候记录

    Institute of Scientific and Technical Information of China (English)

    黄镇国; 张伟强

    2006-01-01

    The analysis results of oxygen isotopes, carbon isotopes, geochemistry and the growth belt of reef coral etc. for some profiles of coral reef show that the basic pattern of climatic fluctuation during the Quaternary period can be reflected by coral reef. The trend of climate change was from cooling to warming during the Early Pleistocene with at least four cycles, and from warming to cooling with at least seven cycles during the Middle Pleistocene. The late Pleistocene is a period of the Quaternary which shows the most frequent variation of climate but generally two main cycles of warming-cooling can be seen. During the Holocene the climate went through a process of warming-rise in temperature-drop in temperature. During the historical period there were four cycles of cooling-warming at 1700 a BP. During the last 200 years climate change is characterized by two stages; a positive deviation in the former 100years, and a negative deviation in the latter 100 years with general warming trend.

  6. Plio-Quaternary sedimentation in the Mozambique Channel and in the Zambezi Fan

    Science.gov (United States)

    Fierens, Ruth; Droz, Laurence; Toucanne, Samuel; Jorry, Stephan; Raisson, François

    2017-04-01

    The classical stratigraphic framework stating minimum land-to-sea transfers during periods of high relative sea-level is challenged by marine sedimentary systems in regions where climate (low latitude, monsoon-type) is dominated by the 23-ky cyclicity. Known turbidite systems at the lowest latitudes, like the Nile and Bengal systems (Ducassou et al., 2009; Weber et al., 1997) show that the supply of sediments to the deep oceanic domain could persist during relative high sea-level periods. But turbidite systems at low-latitudes still remain poorly understood. In this work, we use the Zambezi turbidite system as a case study to develop our understanding of the reactivity of deep marine sedimentary systems and land-sea transfers to low-latitude climate variability. The Zambezi Plio-Quaternary turbidite system ( 2000 km long x 500 km wide) is located within the Mozambique Channel (Indian Ocean; 11°-30°S), separating Madagascar from the African continent, in a context of high hydronamic conditions. An extensive dataset acquired strategically along the turbidite system was obtained within the scope of the PAMELA project (scientific project leaded by Ifremer and TOTAL in collaboration with Université de Bretagne Occidentale, Université Rennes 1, Université Pierre and Marie Curie, CNRS et IFPEN) and includes multibeam bathymetry, seismic reflection data and sediment cores. Preliminary results of morphological, seismic and sedimentological study suggest that this turbidite system in the Mozambique Channel is particular: i) The Zambezi Valley currently appears to be dominated by erosional or vacuity process over its entire length, which is observed within the valley as well as on the flanks; ii) Only two restricted zones of tubiditic deposition are identified; iii) The sedimentary record of the last 375 ky shows few turbidites that occurs both during glacial and interglacial periods, with a rate of recurrence of several tens of thousands of years. Additional

  7. Scientists Identify New Quaternary Materials for Solar Cell Absorbers (Fact Sheet), NREL Highlights, Science

    Energy Technology Data Exchange (ETDEWEB)

    2011-10-01

    Research provides insight for exploring use of earth-abundant quaternary semiconductors for large-scale solar cell applications. For large-scale solar electricity generation, it is critical to find new material that is Earth abundant and easily manufactured. Previous experimental studies suggest that Cu{sub 2}ZnSnS{sub 4} could be a strong candidate absorber materials for large-scale thin-film solar cells due to its optimal bandgap, high adsorption coefficient, and ease of synthesis. However, due to the complicated nature of the quaternary compound, it is unclear whether other quaternary compounds have physical properties suitable for solar cell application. Researchers at the National Renewable Energy Laboratory (NREL), Fudan University, and University College London have performed systematic searches of quaternary semiconductors using a sequential cation mutation method in which the material properties of the quaternary compounds can be derived and understood through the evolution from the binary, to ternary, and to quaternary compounds. The searches revealed that in addition to Cu{sub 2}ZnSnS{sub 4}, Cu{sub 2}ZnGeSe{sub 4} and Cu{sub 2}ZnSnSe{sub 4} are also suitable quaternary materials for solar cell absorbers. Through the extensive study of defect and alloy properties of these materials, the researchers propose that to maximize solar cell performance, growth of Cu{sub 2}ZnSnS{sub 4} under Cu-poor/Zn-rich conditions will be optimal and the formation of Cu{sub 2}ZnSn(S,Se){sub 4} alloy will be beneficial in improving solar cell performance.

  8. Mapping the late Quaternary evolution of the lower Mississippi Valley

    Science.gov (United States)

    Haugerud, R. A.; Simon, K. M.; James, T. S.

    2013-12-01

    The lower Mississippi Valley (LMV) extends from Cape Girardeau to Natchez and from Little Rock to Memphis. Extensive Quaternary terraces within the LMV have been considered to reflect downstream changes in base level (global sea level) and (or) upstream changes in water and sediment input because of glaciation. We suggest that the first-order control on terrace development was glacial-isostatic adjustment (GIA). Observed variation in heights of Quaternary alluvial surfaces at Memphis is 50 m (Rittenour et al., 2007). GIA modeling by Clark et al. (1994) predicted vertical displacement of as much as 130 m at Memphis over the last 18,000 years. ICE-5G models predict smaller displacement and reinforce the viability of GIA as the primary cause of LMV aggradation and incision. Existing analyses of LMV terraces are built on geomorphic maps by Saucier and colleagues (1974, 1994; Autin et al., 1991) that were interpreted from aerial photographs and inch-to-the-mile contour maps. Geomorphic mapping from high-resolution DEMs is more accurate, more rapid, and more reproducible than mapping from aerial photography and intermediate-resolution contours. Working from lidar DEMs (1-5 m XY resolution) and the 10 m National Elevation Dataset (NED) DEM largely derived from 1:24,000 scale contours, Haugerud is mapping the geomorphology of the LMV at ~1:500,000 scale. Goals are to explore the GIA-terrace hypothesis and improve the geomorphic and stratigraphic context for studies of New Madrid seismicity. Mapping leads to several observations: 1. The Holocene floodplain of the Mississippi River onlaps older surfaces. The river appears to be filling a hole created by collapse of the Laurentide forebulge. Continued filling of this accommodation space will, barring human intervention, enable the river to abandon its course through Thebes Gap in favor of a lower-elevation route through Oran Gap. 2. Within Holocene meander belts, younger levee crests are higher than older levee crests. The

  9. Quaternary tectonic setting of South-Central coastal California

    Science.gov (United States)

    Lettis, William R.; Hanson, Kathryn L.; Unruh, Jeffrey R.; McLaren, Marcia; Savage, William U.; Keller, Margaret A.

    2004-01-01

    Recent geodetic, geologic, and seismologic studies show that the south-central coast of California is a region of active Quaternary deformation. Northeast-directed crustal shortening is occurring in a triangular-shaped region between the Hosgri-San Simeon fault system on the west, the Southern Coast Ranges on the northeast, and the western Transverse Ranges on the south. We informally call this region the Los Osos domain. In this study, we conducted detailed geological, seismological, and geophysical investigations to characterize the nature and rates of deformation in the domain. Locations of active and potentially active faults and folds are compiled at a scale of 1:250,000 for the entire domain based primarily on onshore geologic data and offshore geophysical data. Crustal shortening in the domain is accommodated by a series of prominent northwest-trending reverse faults and localized folding. The reverse faults separate distinct structural blocks that have little or no internal deformation. Hangingwall blocks are being uplifted at rates of up to 0.2 mm/yr. Footwall blocks are either static or slowly subsiding at rates of 0.1 mm/yr or less, except for localized areas of concentrated subsidence directly adjacent to some faults. The cumulative rate of crustal shortening is about 1 to 2 mm/yr across the northern part of the domain based on observed geologic deformation. Cumulative shortening across the central and southern parts of the domain is poorly constrained by geologic data and may approach 2 to 3 mm/yr. Historical and instrumental seismicity generally are spatially associated with the uplifted blocks and bordering reverse faults to depths of about 10 km. Together with near-surface geological data and deeper crustal geophysical imaging that show high-angle faulting, the seismicity data indicate that the reverse faults probably extend to the base of the seismogenic crust. The base of the seismogenic crust may correspond with a mid-crustal detachment or

  10. Europe's Neogene and Quaternary lake gastropod diversity - a statistical approach

    Science.gov (United States)

    Neubauer, Thomas A.; Georgopoulou, Elisavet; Harzhauser, Mathias; Mandic, Oleg; Kroh, Andreas

    2014-05-01

    During the Neogene Europe's geodynamic history gave rise to several long-lived lakes with conspicuous endemic radiations. However, such lacustrine systems are rare today as well as in the past compared to the enormous numbers of "normal" lakes. Most extant European lakes are mainly results of the Ice Ages and are due to their (geologically) temporary nature largely confined to the Pleistocene-Holocene. As glacial lakes are also geographically restricted to glacial regions (and their catchment areas) their preservation potential is fairly low. Also deposits of streams, springs, and groundwater, which today are inhabited by species-rich gastropod assemblages, are rarely preserved. Thus, the pre-Quaternary lacustrine record is biased towards long-lived systems, such as the Late Miocene Lake Pannon, the Early to Middle Miocene Dinaride Lake System, the Middle Miocene Lake Steinheim and several others. All these systems have been studied for more than 150 years concerning their mollusk inventories and the taxonomic literature is formidable. However, apart from few general overviews precise studies on the γ-diversities of the post-Oligocene European lake systems and the shifting biodiversity in European freshwater systems through space and time are entirely missing. Even for the modern faunas, literature on large-scale freshwater gastropod diversity in extant lakes is scarce and lacks a statistical approach. Our preliminary data suggest fundamental differences between modern and pre-Pleistocene freshwater biogeography in central Europe. A rather homogenous central European Pleistocene and Holocene lake fauna is contrasted by considerable provincialism during the early Middle Miocene. Aside from the ancient Dessaretes lakes of the Balkan Peninsula, Holocene lake faunas are dominated by planorbids and lymnaeids in species numbers. This composition differs considerably from many Miocene and Pliocene lake faunas, which comprise pyrgulid-, hydrobiid-, viviparid-, melanopsid

  11. Equiatomic quaternary Heusler alloys: A material perspective for spintronic applications

    Science.gov (United States)

    Bainsla, Lakhan; Suresh, K. G.

    2016-09-01

    Half-metallic ferromagnetic (HMF) materials show high spin polarization and are therefore interesting to researchers due to their possible applications in spintronic devices. In these materials, while one spin sub band has a finite density of states at the Fermi level, the other sub band has a gap. Because of their high Curie temperature (TC) and tunable electronic structure, HMF Heusler alloys have a special importance among the HMF materials. Full Heusler alloys with the stoichiometric composition X2YZ (where X and Y are the transition metals and Z is a sp element) have the cubic L21 structure with four interpenetrating fcc sublattices. When each of these four fcc sublattices is occupied by different atoms (XX'YZ), a quaternary Heusler structure with different structural symmetries (space group F-43m, #216) is obtained. Recently, these equiatomic quaternary Heusler alloys (EQHAs) with 1:1:1:1 stoichiometry have attracted a lot of attention due to their superior magnetic and transport properties. A special class of HMF materials identified recently is known as spin gapless semiconductors (SGS). The difference in this case, compared with HMFs, is that the density of states for one spin band is just zero at the Fermi level, while the other has a gap as in the case of HMFs. Some of the reported SGS materials belong to EQHAs family. This review is dedicated to almost all reported materials belonging to EQHAs family. The electronic structure and hence the physical properties of Heusler alloys strongly depend on the degree of structural order and distribution of the atoms in the crystal lattice. A variety of experimental techniques has been used to probe the structural parameters and degree of order in these alloys. Their magnetic properties have been investigated using the conventional methods, while the spin polarization has been probed by point contact Andreev reflection technique. The experimentally obtained values of saturation magnetization are found to be in

  12. An Atlas of Submarine Glacial Landforms: Modern, Quaternary and Ancient

    Science.gov (United States)

    Jakobsson, M.; Dowdeswell, J. A.; Canals, M.; Todd, B. J.; Dowdeswell, E. K.; Hogan, K. A.

    2014-12-01

    In the past two decades there have been several advances that make the production of an atlas of submarine glacial landforms timely. First is the development of high-resolution imaging technologies; multi-beam echo-sounding or swath bathymetry that allows the detailed mapping of the sea floor at water depths of tens to thousands of metres across continental margins, and 3-D seismic methods that enable the visualisation of palaeo-continental shelves in Quaternary sediments and ancient palaeo-glacial rocks (e.g. Late Ordovician of Northern Africa). A second technological development is that of ice-breaking or ice-strengthened ships that can penetrate deep into the ice-infested waters of the Arctic and Antarctic, to deploy the multibeam systems. A third component is that of relevance - through both the recognition that the polar regions, and especially the Arctic, are particularly sensitive parts of the global environmental system and that these high-latitude margins (both modern and ancient) are likely to contain significant hydrocarbon resources. An enhanced understanding of the sediments and landforms of these fjord-shelf-slope systems is, therefore, of increasing importance to both academics and industry. We are editing an Atlas of Submarine Glacial Landforms that presents a series of individual contributions that describe, discuss and illustrate features on the high-latitude, glacier-influenced sea floor. Contributions are organised in two ways: first, by position on a continental margin - from fjords, through continental shelves to the continental slope and rise; secondly, by scale - as individual landforms and assemblages of landforms. A final section provides discussion of integrated fjord-shelf-slope systems. Over 100 contributions by scientists from many countries contain descriptions and interpretation of swath-bathymetric data from both Arctic and Antarctic margins and use 3D seismic data to investigate ancient glacial landforms. The Atlas will be

  13. Quaternary fossil fish from the Kibish Formation, Omo Valley, Ethiopia.

    Science.gov (United States)

    Trapani, Josh

    2008-09-01

    The late Quaternary Kibish Formation of the Omo Valley, southwestern Ethiopia, preserves environments reflecting a history of fluctuations in the level of nearby Lake Turkana over the past 200,000 years. The Kibish Formation has yielded a diverse mammalian fauna (as well as birds and crocodiles), stone tools, and the oldest anatomically modern Homo sapiens. Fish, the most common vertebrate fossils in this unit, are reported in this study. Catfish (especially clariids and Synodontis) and Nile perch (Lates niloticus) predominate, but the gymnarchid Gymnarchus, a cyprinid (Barbus), tigerfish (Hydrocynus), pufferfish (Tetraodon), and other catfish are also present. In total, nine teleost genera are found in the Kibish Formation, representing a subset of the 37 genera that constitute the modern Omo-Turkana ichthyofauna. Several taxa present in the modern fauna, including Polypterus and members of the family Cichlidae, are not found in the Kibish deposits. Most specimens are preserved as disarticulated or broken skeletal elements, but some preservation of articulated elements (e.g., sets of vertebrae, crania with lower jaws or cleithra) also occurs. Many of the catfish and Nile perch specimens are larger than the largest reported from the modern river or lake. Faunas of Kibish Members I and III closely resemble one another; the fauna from Member IV contains only the three most common taxa (Clarias, Synodontis, Lates), though this may result from insufficient sampling. Barbed bone points have been collected from the upper part of the formation, indicating a long association between the human inhabitants and the fish fauna of the Omo Valley.

  14. Quaternary Tectonism in a Collision Zone, Northwest Washington

    Science.gov (United States)

    McCrory, P. A.; Wolf, S. C.; Intelmann, S. S.; Danforth, W. W.; Weldon, R. J.; Blair, J. L.

    2004-12-01

    Kinematic, geodetic, and geologic observations define a region with 6-8 mm/y of north-south contraction between the Columbia River and Vancouver Island. We attribute this contraction to differential forearc-block motion within the Cascadia subduction system where the Oregon Coast Range block is moving northward relative to Vancouver Island. The contraction is accommodated by a combination of distributed uplift in the Olympic Mountains, and faulting along the margins of the Coast Range and Vancouver Island blocks. The tide gauge at Neah Bay, which records one of the highest rates of uplift anywhere along the Cascadia subduction margin, suggests that a significant portion of this north-south contraction occurs between the northern Olympic Peninsula and Vancouver Island. The northwest-trending Calawah fault, extending from Makah Bay eastward to near Lake Crescent, appears to mark the modern boundary between the Olympic Mountains block and the Vancouver Island block in northwestern Washington. Onshore, the 80+ km-long Calawah fault displaces late Quaternary glacial sediments and geodetic uplift rates increase abruptly across the fault zone. Offshore in Makah Bay, new multibeam, sidescan-sonar, and high-resolution seismic reflection data image a complex, multi-strand fault zone that offsets the seafloor and moves Cape Flattery rocks seaward. Two parallel, northwest-trending fault strands bound a down-dropped block that in turn terminates along a northward-trending anticlinal fold and thrust fault. These data suggest that the Calawah fault zone currently accommodates contraction both by uplift and by seaward translation of rocks north of the forearc-block boundary. Our geologic mapping in the Cape Flattery area indicates that differential block motion is accommodated by a combination of crustal uplift, folding, and left-lateral, strike-slip faulting.

  15. Quaternary deformation around the Palo Negro area, Pampa Norte, Argentina

    Science.gov (United States)

    Brunetto, E.; Iriondo, M.; Zamboni, L.; Gottardi, G.

    2010-04-01

    The Pampa Norte region is a great plain characterized by low slopes and accumulation of hundreds of meters of thick loose sediments. A high morphostructure denominated San Guillermo block stands out in the central plain, the Tostado-Selva scarp forming its western boundary. It is located in an intraplate setting characterized by low tectonic activity. However recent uplift can be inferred by means of terrain analysis and the sedimentology of the Palo Negro Fm. Pond deposits (Palo Negro Fm.) observed in the scarp suggest topographic inversion during the Late Quaternary in the Palo Negro area. The morphology indicates that the deformation was widely distributed, forming a gentle (ca. 5 m amplitude and 13 km wavelength) asymmetric fold. Low sinuosity lineaments located in the base of the scarp, coincident with knick points in the topographic profile, can be interpreted as the projection of tip-lines by high-angle fault-propagation. This geometry is compatible with reverse kinematics on blind faults. A deformation style with reactivation of pre-existing faults is consistent with structural observations. Seismic reflectors suggest the presence of Cretaceous high-angle normal faults, and the orientation of lineaments is similar to the orientation of the graben systems and transverse accommodation zones originated during the opening of the South Atlantic Ocean. One OSL dating of 67.4 ± 5.1 kyr B.P (from Palo Negro Fm. supposed as deposited on a flat plain floor) and a height difference of 9.5 m measured in the Tostado-Selva scarp account for an averaged uplift rate of 0.14 mm/year.

  16. Plio-Quaternary history of the Turkish coastal zone of the Enez-Evros Delta: NE Aegean Sea

    Directory of Open Access Journals (Sweden)

    B. ALPAR

    2001-12-01

    Full Text Available The Enez-Evros Delta, NE Aegean Sea, is located in one the most important wetlands in the world with its sandy offshore islands, abandoned channel mouths, sand-dunes, shoals, marshlands, saline lagoons and saltpans. It comprises very well developed sedimentary units and a prodelta lying on an older submarine delta. The present day elevations of the middle-late Pleistocene marine terraces indicate a regional tectonic uplift in the area. Due to lack of geophysical and bore hole data and partly due to its strategic position, the structural and stratigraphic features of the submarine extension of the delta are not known in detail. In this paper, Plio-Quaternary history of this delta and its submarine part on the Turkish shelf was explored by using high-resolution shallow reflection seismic profiles. The delta is formed by the alluvial deposits of the Enez-Evros River and shaped by their interaction with the sea. It takes place in front of a large and protected ancient bay which was filled rapidly over millennia. The sediments in the plateau off the river are principally pro-deltaic with muddy areas near the river mouths changing to muddy sand further out. The sea-level changes in Plio-Quaternary were characterised by three different seismic stratigraphic units on the folded Miocene limestone basement. In the late Pleistocene, the shelf area over an Upper Miocene basement was flooded during the Riss-Würm interglacial period, exposed in the Würm glacial stage, and flooded once again during the Holocene transgression.

  17. The ichthyofauna of limnic systems in Quaternary deposits of extreme southern Brazil

    Directory of Open Access Journals (Sweden)

    Cindy Marques

    2016-12-01

    Full Text Available The Quaternary in the state of Rio Grande do Sul (RS, southern Brazil, is geologically represented by the coastal plain and was originated by successive events of Pleistocene-Holocene marine transgressions and the occurrence of alluvial deposits. This paper aimed to characterize the fish assemblage occurring in a swampy Quaternary area adjacent to Lagoa Pequena, a lacustrine system connected to the west margin of the Laguna dos Patos estuary. A checklist is also provided of the ichthyofauna so far recorded in limnic systems of Quaternary deposits in the state of Rio Grande do Sul. A total of 42 species was recorded, distributed in nine orders, 18 families and 31 genera. Characidae and Cichlidae were the most representative families, comprising 15 and 4 species respectively. A bibliographic revision associated to our sample data revealed the occurrence of 156 species in limnic systems inserted in RS Quaternary deposits (114 limnic, 15 marine/estuarine/limnic, ten marine/estuarine, nine estuarine/limnic and eight marine. Characiformes and Siluriformes are the most diverse orders, corroborating the Neotropical pattern. Seven species can be considered endemic to RS Quaternary deposits.

  18. The ichthyofauna of limnic systems in Quaternary deposits of extreme southern Brazil

    Science.gov (United States)

    Assumpção, Cindy M.; Quintela, Fernando M.; Corrêa, Fabiano; Loebmann, Daniel

    2016-01-01

    Abstract The Quaternary in the state of Rio Grande do Sul (RS), southern Brazil, is geologically represented by the coastal plain and was originated by successive events of Pleistocene-Holocene marine transgressions and the occurrence of alluvial deposits. This paper aimed to characterize the fish assemblage occurring in a swampy Quaternary area adjacent to Lagoa Pequena, a lacustrine system connected to the west margin of the Laguna dos Patos estuary. A checklist is also provided of the ichthyofauna so far recorded in limnic systems of Quaternary deposits in the state of Rio Grande do Sul. A total of 42 species was recorded, distributed in nine orders, 18 families and 31 genera. Characidae and Cichlidae were the most representative families, comprising 15 and 4 species respectively. A bibliographic revision associated to our sample data revealed the occurrence of 156 species in limnic systems inserted in RS Quaternary deposits (114 limnic, 15 marine/estuarine/limnic, ten marine/estuarine, nine estuarine/limnic and eight marine). Characiformes and Siluriformes are the most diverse orders, corroborating the Neotropical pattern. Seven species can be considered endemic to RS Quaternary deposits. PMID:28174498

  19. Ultra-low-power carbon nanotube FET-based quaternary logic gates

    Science.gov (United States)

    Sharifi, Fazel; Moaiyeri, Mohammad Hossein; Navi, Keivan; Bagherzadeh, Nader

    2016-09-01

    This paper presents low-power carbon nanotube field-effect transistor (CNTFET)-based quaternary logic circuits. The proposed quaternary circuits are designed based on the CNTFET unique properties, such as the same carrier mobility for N- and P-type devices and also providing desirable threshold voltages by adopting proper diameters for the nanotubes. In addition, no paths exist between supply and ground rails in the steady states of the proposed designs, which eliminates the ON state static current and also the stacking technique is utilised in order to significantly reduce the leakage currents. The results of the simulations, conducted using Synopsys HSPICE with the standard 32 nm CNTFET technology, confirm the significantly lower power consumption, higher energy efficiency and lower sensitivity to process variation of the proposed designs compared to the state-of-the-art quaternary logic circuits. The proposed quaternary logic circuits have on average 92, 99 and 91% less total power, static power and PDP, respectively, compared with the most low-power and energy-efficient CNTFET-based quaternary logic circuits, recently presented in the literature.

  20. Effect of quaternary ammonium salts on flotation behavior of aluminosilicate minerals

    Institute of Scientific and Technical Information of China (English)

    ZHAO Sheng-gui; ZHONG Hong; LIU Guang-yi

    2007-01-01

    The electrokinetic properties and flotation of diaspore, kaolinite, pyrophyllite and illite with quaternary ammonium salts collectors were studied. The results of flotation tests show that the collecting ability of quaternary ammonium salts for the four minerals is in the order(from strong to weak) of octadecyl dimethyl benzyl ammonium chloride(ODBA), cetyl trimethyl ammonium bromide(CTAB), dodecyl trimethyl ammonium chloride(DTAC). Under the condition of alkalescence, it is possible to separate the diaspore from the silicate minerals such as kaolinite, illite and pyrophyllite using quaternary ammonium salts as collector. Isoelectric points (IEP) of diaspore, kaolinite, pyrophyllite and illite are pH=6.0, 3.4, 2.3 and 3.2, respectively. Quaternary ammonium salts can change ζ-potential of the aluminosilicate minerals obviously. The flotation mechanisms were explained by ζ-potential and Fourier transform infrared spectrum (FT-IR) measurements. The results demonstrate that only electrostatic interaction takes place between aluminosilicate minerals (diaspore, kaolinite, pyrophyllite and illite) and quaternary ammonium salts.

  1. Quaternary ostracodes and molluscs from the Rukwa Basin (Tanzania) and their evolutionary and paleobiogeographic implications

    Science.gov (United States)

    Cohen, Andrew S.; Van Bocxlaer, Bert; Todd, Jonathan A.; McGlue, Michael; Michel, Ellinor; Nkotagu, Hudson H.; Grove, A.T.; Delvaux, Damien

    2013-01-01

    Much of the spectacular biodiversity of the African Great Lakes is endemic to single lake basins so that the margins of these basins or their lakes coincide with biogeographic boundaries. Longstanding debate surrounds the evolution of these endemic species, the stability of bioprovinces, and the exchange of faunas between them over geologic time as the rift developed. Because these debates are currently unsettled, we are uncertain of how much existing distribution patterns are determined by modern hydrological barriers versus reflecting past history. This study reports on late Quaternary fossils from the Rukwa Basin and integrates geological and paleoecological data to explore faunal exchange between freshwater bioprovinces, in particular with Lake Tanganyika. Lake Rukwa's water level showed large fluctuations over the last 25 ky, and for most of this period the lake contained large habitat diversity, with different species assemblages and taphonomic controls along its northern and southern shores. Comparison of fossil and modern invertebrate assemblages suggests faunal persistence through the Last Glacial Maximum, but with an extirpation event that occurred in the last 5 ky. Some of the molluscs and ostracodes studied here are closely related to taxa (or part of clades) that are currently endemic to Lake Tanganyika, but others testify to wider and perhaps older faunal exchanges between the Rukwa bioprovince and those of Lake Malawi and the Upper Congo (in particular Lake Mweru). The Rukwa Basin has a long history of rifting and lacustrine conditions and, at least temporarily, its ecosystems appear to have functioned as satellites to Lake Tanganyika in which intralacustrine speciation occurred. Paleontological studies of the Rukwa faunas are particularly relevant because of the basin's important role in the late Cenozoic biogeography of tropical Africa, and because many of the molecular traces potentially revealing this history would have been erased in the late

  2. Numerical modelling of chloride propagation in the quaternary aquifer of the southern Upper Rhine Graben

    Science.gov (United States)

    Lang, U.; Gudera, T.; Elsass, P.; Wirsing, G.

    2005-09-01

    The deep groundwater in the quaternary gravel sequence of the southern Upper Rhine Graben locally contains high chloride concentrations near the river Rhine between Fessenheim (France) in the South and Breisach (Germany) in the North. This historical pollution is mainly due to past infiltration from the former brine storage basins of the French potash mines on the “Fessenheim Island” and—to a lesser extent—from the leaching of the salt dumps of the German potash mines in Buggingen and Heitersheim. The spreading of the salt plume was investigated by means of a groundwater model. The aim of the model was to understand the brine movement, the present distribution of chloride as defined by recent hydrochemical investigations, and to select locations for new reconnaissance boreholes. The geological structure was reproduced by a three layer model, which was calibrated for steady state flow conditions. The hydraulic conductivity of the first layer was determined by comparing measured and calculated heads in the model area. The vertical resolution was refined to simulate the density-dependent salt transport processes. The transport of the salt plumes was simulated over a 40-year period, starting at the beginning of brine storage in the 1950s. The relevant transport parameters have been estimated in a sensitivity analysis, where the simulated breakthrough curves of chloride concentration have been compared with the measured data. The results of the groundwater model indicate that brines containing approximately 1 million tons of chloride are still present at the bottom of the aquifer. These highly concentrated salt brines mix with fresh water from the upper part of the aquifer. This dispersive process leads to the formation of a plume of chloride-rich water extending downstream, where pumping wells for several local water supplies are located.

  3. Late Quaternary stratigraphy and sedimentation patterns in the western Arctic Ocean

    Science.gov (United States)

    Polyak, L.; Bischof, J.; Ortiz, J.D.; Darby, D.A.; Channell, J.E.T.; Xuan, C.; Kaufman, D.S.; Lovlie, R.; Schneider, D.A.; Eberl, D.D.; Adler, R.E.; Council, E.A.

    2009-01-01

    Sediment cores from the western Arctic Ocean obtained on the 2005 HOTRAX and some earlier expeditions have been analyzed to develop a stratigraphic correlation from the Alaskan Chukchi margin to the Northwind and Mendeleev-Alpha ridges. The correlation was primarily based on terrigenous sediment composition that is not affected by diagenetic processes as strongly as the biogenic component, and paleomagnetic inclination records. Chronostratigraphic control was provided by 14C dating and amino-acid racemization ages, as well as correlation to earlier established Arctic Ocean stratigraphies. Distribution of sedimentary units across the western Arctic indicates that sedimentation rates decrease from tens of centimeters per kyr on the Alaskan margin to a few centimeters on the southern ends of Northwind and Mendeleev ridges and just a few millimeters on the ridges in the interior of the Amerasia basin. This sedimentation pattern suggests that Late Quaternary sediment transport and deposition, except for turbidites at the basin bottom, were generally controlled by ice concentration (and thus melt-out rate) and transportation distance from sources, with local variances related to subsurface currents. In the long term, most sediment was probably delivered to the core sites by icebergs during glacial periods, with a significant contribution from sea ice. During glacial maxima very fine-grained sediment was deposited with sedimentation rates greatly reduced away from the margins to a hiatus of several kyr duration as shown for the Last Glacial Maximum. This sedimentary environment was possibly related to a very solid ice cover and reduced melt-out over a large part of the western Arctic Ocean.

  4. Quaternary ostracode and foraminiferal biostratigraphy and paleoceanography in the western Arctic Ocean

    Science.gov (United States)

    Cronin, Thomas M.; DeNinno, Lauren H.; Polyak, L.V.; Caverly, Emma K.; Poore, Richard; Brenner, Alec R.; Rodriguez-Lazaro, J.; Marzen, R.E.

    2014-01-01

    The stratigraphic distributions of ostracodes and selected calcareous benthic and planktic foraminiferal species were studied in sediment cores from ~ 700 to 2700 m water depth on the Northwind, Mendeleev, and Lomonosov Ridges in the western Arctic Ocean. Microfaunal records in most cores cover mid- to late Quaternary sediments deposited in the last ~ 600 ka, with one record covering the last ~ 1.5 Ma. Results show a progressive faunal turnover during the mid-Pleistocene transition (MPT, ~ 1.2 to 0.7 Ma) and around the mid-Brunhes event (MBE, ~ 0.4 Ma) reflecting major changes in Arctic Ocean temperature, circulation and sea-ice cover. The observed MPT shift is characterized by the extinction of species that today inhabit the sea-ice free subpolar North Atlantic and/or seasonally sea-ice free Nordic Seas (Echinocythereis sp., Rockalliacf. enigmatica, Krithe cf. aquilonia, Pterygocythereis vannieuwenhuisei). After a very warm interglacial during marine isotope stage (MIS) 11 dominated by the temperate planktic foraminifer Turborotalita egelida, the MBE experienced a shift to polar assemblages characteristic of predominantly perennial Arctic sea-ice cover during the interglacial and interstadial periods of the last 300 ka. These include the planktic foraminifera Neogloboquadrina pachyderma, the sea-ice dwelling ostracodeAcetabulastoma arcticum and associated benthic taxa Pseudocythere caudata,Pedicythere neofluitans, and Polycope spp. Several species can be used as biostratigraphic markers of specific intervals such as ostracodes Rabilimis mirabilis — MIS 5 and P. vannieuwenhuisei extinction after MIS 11, and foraminiferal abundance zones Bulimina aculeata — late MIS 5 and Bolivina arctica — MIS 5-11.

  5. Quaternary evolution and ice sheet history of contrasting landscapes in Uummannaq and Sukkertoppen, western Greenland

    Science.gov (United States)

    Beel, C. R.; Lifton, N. A.; Briner, J. P.; Goehring, B. M.

    2016-10-01

    Constraining the history of the Greenland Ice Sheet (GIS) is important for improving our understanding of ice sheet dynamics and landscape evolution processes. We analyzed in situ cosmogenic 10Be and 26Al in 26 rock samples from two high-elevation landscapes adjacent to the GIS, minimally eroded by past glaciations and of differing character in Uummannaq (n = 16) and Sukkertoppen (n = 10), western Greenland. The Uummannaq region is characterized by a marine embayment with islands and peninsulas, where the margin of the GIS is marine-based, whereas the Sukkertoppen landscape resides within the wide terrestrial fringe outboard of the land-terminating portion of the southwestern GIS margin. We targeted landscapes for sampling with highly weathered surfaces adjacent to cold-based portions of extant ice caps (indicated by preservation of fragile, dead vegetation emerging from beneath retreating ice margins). Paired isotope results require differing surface histories between the two areas. Many surfaces in the Uummannaq region have minimum exposure durations up to ca. 300 kyr, but with no significant burial. Most surfaces in the Sukkertoppen region, however, yield complex exposure histories with minimum cumulative exposure durations up to ca. 100 kyr and minimum cumulative burial durations up to ca. 400 kyr, yielding minimum total surface histories of up to 500 ka. These findings suggest that parts of the Uummannaq landscape may have been continuously exposed throughout much of the middle and late Quaternary. On the other hand, the high-altitude surfaces in the Sukkertoppen region were largely preserved beneath minimally-erosive, cold-based ice during the same period. Data from the Uummannaq region thus stand in contrast not only to the Sukkertoppen region, but also to other sites surrounding Baffin Bay reported in previous studies. We hypothesize that surfaces in the Uummannaq region may have remained as nunataks above the Last Glacial Maximum (LGM) ice sheet surface

  6. Leaching of Nutrient Elements in a Red Soil Derived from Quaternary Red Clay

    Institute of Scientific and Technical Information of China (English)

    SHENRENFANG; ZHAOQIGUO

    1998-01-01

    A red soil derived from Quaternary red clay was employed to study nutrient leaching with woil columns repacked in laboratory,The objective was to identify the effects of fertilization practices on leaching patterns and magnitudes of Ca2+,Mg2+,K+,NH4+,and NO3-,The treatments were CK (as a control),CaCO3, CaSO4,MgCO3,Ca(H2PO4)2,urea,KCl,and multiple (a mixture of the above-mentioned fertilizers),The fertilizers were added to the bare surface of the soil columns,and then the columns were leached with 120 mL deionized water daily through peristaltic pumps over a period of 92 days.Leaching processes of NH4+,and NO3- wer e only measured in CK,ured,and multiple treatments which were directly related to N leaching, Results showed that sole application of CaSO4,and Ca(H2PO4)2 scarcely hd any effect on the leching losses of Ca2+,Mg2+,and K+; the application of MgCO3 sthimulated the leaching of Mg2+;the application of CaCO3 promoted the leaching of Ca2+,Mg2+ and K+; urea treatment also promoted the leaching of K+ and NH4+,and NO3- leaching mainly occurred at late stage of leaching process in particular;under KCl treatment,leaching of Ca2+,Mg2+,and K+ was promoted to a large extent;under multiple treatment, leaching of Ca2+,Mg2+,K+,NH4+,and NO3- was all increased and NO3- was mainly leached at the end of leaching process and still had a trend of increase.

  7. Relative roles of Neogene vicariance and Quaternary climate change on the historical diversification of bunchgrass lizards (Sceloporus scalaris group) in Mexico.

    Science.gov (United States)

    Bryson, Robert W; García-Vázquez, Uri Omar; Riddle, Brett R

    2012-01-01

    Neogene vicariance during the Miocene and Pliocene and Quaternary climate change have synergistically driven diversification in Mexican highland taxa. We investigated the impacts of these processes on genetic diversification in the widely distributed bunchgrass lizards in the Sceloporus scalaris group. We searched for correlations between timing in diversification and timing of (1) a period of marked volcanism across the Trans-Mexican Volcanic Belt in central Mexico 3-7.5million years ago (Ma) and (2) a transition to larger glacial-interglacial cycles during the mid-Pleistocene. From our phylogenetic analyses of mitochondrial DNA we identified two major clades that contained 13 strongly supported lineages. One clade contained lineages from the two northern sierras of Mexico, and the other clade included lineages associated with the Trans-Mexican Volcanic Belt and Central Mexican Plateau. Results provided support for Neogene divergences within the S. scalaris group in response to uplift of the Trans-Mexican Volcanic Belt, a pattern observed in several co-distributed taxa, and suggested that Quaternary climate change likely had little effect on diversification between lineages. Uplift of the Trans-Mexican Volcanic Belt during specific time periods appears to have strongly impacted diversification in Mexican highland taxa.

  8. Iranian speleothems: Investigating Quaternary climate variability in semi-arid Western Asia

    Science.gov (United States)

    Carolin, Stacy; Morgan, Jacob; Peckover, Emily; Walker, Richard; Henderson, Gideon; Rowe, Peter; Andrews, Julian; Ersek, Vasile; Sloan, Alastair; Talebian, Morteza; Fattahi, Morteza; Nezamdoust, Javad

    2016-04-01

    Rapid population growth and limited water supply has highlighted the need for vigorous water resource management practices in the semi-arid regions of Western Asia. One significant unknown in this discussion is the future change in rainfall amount due to the consequential effects of today's greenhouse gas forcing on the regional climate system. Currently, there is little paleoclimate proxy data in Western Asia to extend climate records beyond the limits of the instrumental period, leaving scant evidence to investigate the system's response to various climate forcings on different timescales. Here we present a synthesis of speleothem climate records across northern Iran, from the wetter climate of the Alborz and Zagros mountain ranges to the dry northeast, in order to investigate the magnitude of past climate variability and the forcings responsible. The stalagmites collected from the west and north-central mountain ranges, areas with ~200-400mm mean annual precipitation mostly falling within the fall-winter-spring months, all demonstrate growth limited to the interglacial periods of the Quaternary. We present overlapping Holocene stable isotope records with a complementary trace element record to assist in interpreting the isotopic variability. One of the records is sampled at <4yr resolution and spans 3.7-5.3 kyBP, a contested period of catastrophic droughts that allegedly eradicated civilizations in areas of the near East. Imposed upon decadal-scale variability, the record reveals a 1,000-yr gradual trend toward enriched stable oxygen isotope values, interpreted as a trend toward drier conditions, which ends with an abrupt 300-yr cessation in growth beginning at 4.3 kyBP, coincident with the so-called 4.2 kyBP drought event. From the northeast Iranian plateau, we present a new stalagmite record that spans the penultimate deglaciation and Stages 5e-5a. This region presently receives limited rain annually (~100-300mm/yr, regularly falling between November and May

  9. Atmospheric effects on Quaternary polarization encoding for free space communication, laboratory simulation

    CERN Document Server

    Soorat, Ram

    2015-01-01

    We have simulated atmospheric effects such as fog and smoke in laboratory environment to simulate depolarisation due to atmospheric effects during a free space optical communi- cation. This has been used to study noise in two components of quaternary encoding for polarization shift keying. Individual components of a Quaternary encoding, such as vertical and horizontal as well as 45$^\\circ$ and 135$^\\circ$ , are tested separately and indicates that the depo- larization effects are different for these two situation. However, due to a differential method used to extract information bits, the protocol shows extremely low bit error rates. The information obtained is useful during deployment of a fully functional Quaternary encoded PolSK scheme in free space.

  10. Evidence of seismites in coastal Quaternary deposits of western Oranie (northwestern Algeria)

    Science.gov (United States)

    Boukhedimi, Mohamed Amine; Louni-Hacini, Amina; Bouhadad, Youcef; Ritz, Jean-François; Machane, Djamel; Benhamouche, Azzeddine; Bourenane, Hamid

    2016-10-01

    Coastal Quaternary deposits of western Oranie show typical soft-sediment deformations including sedimentary dykes, sand volcanoes, sismoslumps, thixotropic bowls, thixotropic wedges, diapir-like structures, and faults grading. Field observations indicate that these deformations exist at several levels of the studied deposits along the west Oranian coast. This study demonstrated that these structures are earthquakes-related, by analysis of potential trigger sources. Several arguments demonstrate the seismic origin: the depositional environment rich in water that located in an active tectonic region, the thixotropic nature of deformations and their large vertical and horizontal diffusion in the Quaternary series consistent with a seismic recurrence. This allows characterizing these Quaternary soft-sediment deformations as seismites that were triggered by earthquakes.

  11. Synthesis and characterization of chitosan based dye containing quaternary ammonium group.

    Science.gov (United States)

    Tang, Ruilin; Zhang, Ying; Zhang, Yang; Yu, Zhiming

    2016-03-30

    A new antimicrobial biopolymer dye was synthesized by reaction of quaternary ammonium salt of chitosan and reactive red x-3b. And quaternary ammonium salt of chitosan was produced by grafting glycidyltrimethylammonium chloride on chitosan. The synthesized materials were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), solubility test and antimicrobial test. Results show that the antimicrobial biopolymer dye was combined by N(+)(CH3)3 of quaternary ammonium salt of chitosan and sulfonic group of reactive red x-3b. Water solubility of chitosan biopolymer dye was increased as well as pH value. In addition, antibacterial property of new synthesized dye was excellent, whose antibacterial rates of Staphylococcus and Escherichia coli were both bigger than 99%. These results may provide new perspectives on improving the decorative properties and antimicrobial properties in wood industry.

  12. The nonmarine environment of Quaternary foraminifers in Yanshuzhuang, China: Evidence from boron and strontium isotopes

    Institute of Scientific and Technical Information of China (English)

    XIAO YingKai; XIAO Jun; ZHAO ZhiQi; HE MaoYong; LI ShiZhen

    2008-01-01

    The concentrations and isotopic compositions of boron and strontium of Quaternary foraminifers and bivalve fossils collected in the Yanghuzhuang section of Yanqing, Beijing and of modern gastropods living in the Guishui River and of river water were measured. The concentrations and isotopic compo-sitions of Quaternary foraminifers and bivalve fossils differed from those of modern marine fo-raminifers and were similar to those of modern terrestrial gastropods from the Guishui River. These results indicate that early Quaternary foraminifers in the Yanghuzhuang section inhabited a nonmarine environment and that these foraminifers were not the result of a transgression or sea flooding. The foraminifers were not special halobios and can survive in the terrestrial condition that resembled those of the ocean.

  13. NUCHLEOPHILIC SUBSTITUTION REACTION OF CYANIDE AND METHOXYDE IONS TO QUATERNARY MANNICH BASE FROM VANILLIN

    Directory of Open Access Journals (Sweden)

    Bambang Purwono

    2010-06-01

    Full Text Available The nucleophilic substitution reaction to quaternary Mannich base from vanillin has been investigated. Mannich reaction to vanillin was carried out by refluxing mixture of vanillin, formaldehyde and dimethyl amine. Quaternary ammonium halide salt was obtained from reaction of Mannich vanillin base with methyl iodide in THF solvents and yielded  93.28%. Nucleophilic substituion to the halide salts with cyanide nucleophile produced 4-hidroxy-3-methoxy-5-(cyanomethylbenzaldehyde in 54.39% yield, with methoxyde ion obtained  4-hidroxy- 3-methoxy-5-(methoxy-methyl-benzaldehide in 67.80% yield. The nucleophilic substitution reaction showed that substituen of trimethylamino quaternary Mannich base can act as a good leaving on nucleophilic reaction substitutions.   Keywords: Mannich Reaction, Vanillin, nucleophilic substitution.

  14. NUCLEOPHILIC SUBSTITUTION REACTION OF CYANIDE AND METHOXYDE IONS TO QUATERNARY MANNICH BASE FROM VANILLIN

    Directory of Open Access Journals (Sweden)

    Bambang Purwono

    2010-06-01

    Full Text Available The nucleophilic substitution reaction to quaternary Mannich base from vanillin has been investigated. Mannich reaction to vanillin was carried out by refluxing mixture of vanillin, formaldehyde and dimethyl amine. Quaternary ammonium halide salt was obtained from reaction of Mannich vanillin base with methyl iodide in THF solvents and yielded 93.28 %. Nucleophilic substituion to the halide salts with cyanide nucleophile produced 4-hidroxy-3-methoxy-5-(cyanomethylbenzaldehyde in 54.39% yield. Reaction with methoxyde ion yielded 4-hydroxy- 3-methoxy-5-(methoxy -methylbenzaldehyde in 67.80% yield. The nucleophilic substitution reaction showed that trimethylamino substituent of quaternary Mannich base can act as a good leaving group on nucleophilic substitution reactions. Keywords: Mannich reaction, vanillin, nucleophilic substitution

  15. Book Review: Quaternary Environmental Change in Southern Africa: Physical and Human Dimensions

    Science.gov (United States)

    Murray-Wallace, Colin V.

    2017-02-01

    This attractively presented book examines the legacy of a diverse range of Quaternary environmental processes in the fashioning of Southern African landscapes and their ultimate interconnection with human evolution, technological developments and subsistence in dynamically changing environments. In its 25 chapters the book reviews different elements of Southern African landscapes and emphasizes their diversity, from classical desert dune environments to glacial, periglacial, fluvial, karst, wetlands, estuaries and sandy coastal landscapes. In addition, the soils and duricrusts that are so distinctive to these landscapes (Runge) and colluvial deposits and slope instability (Botha et al.) are also reviewed. Evidence for Quaternary environmental change is also examined in terms of pollen, charcoal and plant macrofossil records (Bamford et al.), minerogenic microfossil records (Fitchett et al.) and terrestrial ecosystem changes in the late Quaternary (Meadows and Quick). The archaeological records of the Earlier Stone Age (Kuman), Middle Stone Age, and Later Stone Age (Mitchell) are also comprehensively reviewed.

  16. Late Quaternary rates of stream incision in Northeast Peloponnese, Greece

    Science.gov (United States)

    Karymbalis, Efthimios; Papanastassiou, Dimitrios; Gaki-Papanastassiou, Kalliopi; Ferentinou, Maria; Chalkias, Christos

    2016-09-01

    This study focuses on defining rates of fluvial incision for the last 580±5 kyr along valley systems of eight streams that drain the eastern part of the northern Peloponnese. The streams are developed on the uplifted block of the offshore-running Xylokastro normal fault, one of the main faults bounding the southern edge of the Gulf of Corinth half-graben, and have incised a set of ten uplifted marine terraces having an amphitheatric shape. These terraces range in age from 60±5 kyr to 580±5 kyr and have been mapped in detail and correlated with late Pleistocene oxygen-isotope stages of high sea-level stands by previous studies. The terraces were used in this paper as reference surfaces in order to define fluvial incision rates at the lower reaches of the studied streams. To evaluate incision rates, thirty-three topographic valley cross-sections were drawn using fieldwork measurements as well as using a highly accurate (2×2 cell size) Digital Elevation Model (DEM) at specific locations where streams cut down the inner edges of the marine terraces. For each cross-section the ratio of valley floor width to valley height (Vf) and long-term mean stream incision rates were estimated for the last 580±5 kyr, while rock uplift rates were estimated for the last 330±5 kyr. The geomorphic evolution of the valleys on the uplifted block of the Xylokastro fault has been mainly driven by the lithology of the bedrock, sea level fluctuations during the late Quaternary, and incision of the channels due to the tectonic uplift. Stream incision rates range from 0.10±0.1 mm/yr for the last 123±7 kyr to 1.14±0.1 mm/yr for the last 310±5 kyr and are gradually greater from east to west depending on the distance from the trace of the fault. Downcutting rates are comparable with the rock uplift rates, which range from 0.4±0.02 mm/yr to 1.49±0.12 mm/yr, over the last 330±5 kyr.

  17. A New Quaternary Strand of the Karakoram Fault System, Ladakh Himalayas

    Science.gov (United States)

    Bohon, W.; Hodges, K.; Arrowsmith, R.; Tripathy, A.

    2009-12-01

    The NW-SE striking, dextral Karakoram fault system stretches for more than 1200 km from the Pamirs of Central Asia at least as far southeast as the Kailas area of Tibet. Estimates for the total lateral displacement along the fault system range from 150-1000 km, and estimated Quaternary rates of slip range from 1 to 30 mm/yr. In the Ladakh region of NW India (~ 33°28’N, 78°45’E), the fault system expresses as northern and southern strands bounding the Pangong Range. Studies of ductile deformation fabrics along these strands suggest that slip began in the Miocene, and Brown et al. (2002) documented Quaternary right-lateral slip along the northern strand at ~4 mm/yr on the basis of offset geomorphic features. The lack of documented Quaternary offset along the southern strand has led most researchers to assume that Quaternary slip on the Karakoram fault system in this region was partitioned exclusively to the northern strand. Our summer 2009 field work in the Pangong Range and adjacent Nubra Valley provides the first documentation of significant Quaternary activity along the southern strand. In the valley between the villages of Tangste (34°01’ N, 78°10’ E) and Durbuk (34°06’ N, 78°07’), the fault is visible high on the northeastern mountain side as a break in slope with offset Quaternary paleosurfaces and beheaded and offset stream channels, the largest of which have been displaced by as much as 250 m. Field mapping north of Durbuk, near the town of Tangyar (34°15’N, 77°52’E), shows that the southern strand continues northwest and cuts across the landscape as a sinuous, continuous trace with shutter ridges, offset alluvial fan surfaces, and sag ponds developed along its length. In this region, the northern and southern strands are linked by a Quaternary, E-directed thrust fault that places high-grade metamorphic rocks over poorly consolidated Quaternary alluvium. The partitioning of dextral slip between two strands of the Karakoram system

  18. A study of 36Cl age in Quaternary groundwater of Hebei plain, China

    Institute of Scientific and Technical Information of China (English)

    周炼; 刘存富; 姜山; 高山

    2001-01-01

    Chlorine-36 has various advantages as a dating tool for old groundwater. In this paper, 36CI of Quaternary groundwater in the Hebei plain of North China has been measured using accelerator mass spectrometry (AMS). Ages calculated from the 36CI/CI ratio show that ion filtration, which is responsible for the CI- concentration increasing with depth and along flow paths in Hebei plain groundwater. It is concluded that 36CI age of the groundwater in the 3rd Group of the Quaternary (Q2) in the Cangzhou area is 250ka, and that of the 4th Group(Q1) is 300ka.

  19. Towards dating Quaternary sediments using the quartz Violet Stimulated Luminescence (VSL) signal

    DEFF Research Database (Denmark)

    Ankjærgaard, C.; Jain, Mayank; Wallinga, J.

    2013-01-01

    Quartz optically stimulated luminescence (OSL) dating is widely used to determine the time of deposition and burial of Late Quaternary sediments. Application of the method is usually limited to the past 150,000 years due to early saturation of the OSL signal. Here we explore the potential to date...... Quaternary sediments using the violet (402 nm) stimulated luminescence (VSL) signal of quartz.We develop and test a new post-blue VSL single aliquot regenerative dose dating protocol, and demonstrate that the VSL signal originates from a deep trap at about 1.9 eV with a thermal lifetime of 1011 years at 10...

  20. Quaternary cocrystals: combinatorial synthetic strategies based on long-range synthon Aufbau modules (LSAM

    Directory of Open Access Journals (Sweden)

    Ritesh Dubey

    2016-03-01

    Full Text Available A synthetic strategy is outlined whereby a binary cocrystal may be developed in turn into a ternary and finally into a quaternary cocrystal. The strategy hinges on the concept of the long-range synthon Aufbau module (LSAM which is a large supramolecular synthon containing more than one type of intermolecular interaction. Modulation of these interactions may be possible with the use of additional molecular components so that higher level cocrystals are produced. We report six quaternary cocrystals here. All are obtained as nearly exclusive crystallization products when four appropriate solid compounds are taken together in solution for crystallization.

  1. Thermodynamic Description of the Quaternary Ag-Bi-Cu-Sn System

    Science.gov (United States)

    Gierlotka, Wojciech

    2017-09-01

    Lead-free soldering is an important part of electronic devices production. New lead-free solders that replace classical Sn-37Pb solder are still under development. Thermodynamic modeling makes the development process faster, cheaper and more environmentally friendly due to predictions of phases stabilities and phases transformations. In this work, the thermodynamic description of quaternary Ag-Bi-Cu-Sn system is presented. The thermodynamic assessment of promising lead-free quaternary solder was prepared using the Calphad approach. A good agreement between available experimental data and calculation was found.

  2. Geomorphological effects of plate movemen during Quaternary in China's tropics

    Institute of Scientific and Technical Information of China (English)

    ZHANGWeiqiang; HUANGZhenguo

    2004-01-01

    The eastern and western fronts of plate movement in Taiwan Island and Tibetan Plateau respectively are the two major sources of tectonic force for the morphogensis during Quaternary in China's tropics. Seven examples of geomorphological effects of plate movement are enumerated to discuss the differentiation of tectonic landforms in space and time during Quaternary. The tectonic movement tends to be more active since middle Pleistocene. Some phenomena such as the arc-shape mountain systems, volcanism and crustal deformation imply that the juncture zone of eastern and western tectonic forces is located at about 110°E.

  3. Synthesis and antibacterial activity screening of quaternary ammonium derivatives of triazolyl pyranochromenones

    Indian Academy of Sciences (India)

    PREETI YADAV; BIPUL KUMAR; HEMANT K GAUTAM; SUNIL K SHARMA

    2017-02-01

    A series of quaternary ammonium derivatives of triazolyl pyranochromen-2-ones have been synthesized and characterized; their antibacterial potential were investigated against two gram negative (Pseudomonas aeruginosa and Escherichia coli) and two gram positive bacterial strains (Bacillus cereus and Staphylococcus aureus). In order to develop structure-activity relationship (SAR), the effect of varying the substituent (R) at the C-10 position of pyranochromen-2-one as well as the length of the spacer (n) between the triazolyl pyranochromen-2-ones and quaternary ammonium group, on the antibacterial activity of compoundshas been evaluated. Some of the screened compounds exhibited antibacterial potential against the studied strains in the microgram range.

  4. Relaxed random walk model coupled with ecological niche modeling unravel the dispersal dynamics of a Neotropical savanna tree species in the deeper Quaternary

    Directory of Open Access Journals (Sweden)

    Rosane Garcia Collevatti

    2015-08-01

    Full Text Available Understanding the dispersal routes of Neotropical savanna tree species is an essential step to unravel the effects of past climate change on genetic patterns, species distribution and population demography. Here we reconstruct the demographic history and dispersal dynamics of the Neotropical savanna tree species Tabebuia aurea to understand the effects of Quaternary climate change on its current spatial patterns of genetic diversity. We sampled 285 individuals from 21 populations throughout Brazilian savannas and sequenced all individuals for three chloroplast intergenic spacers and ITS nrDNA. We analyzed data using a multi-model inference framework by coupling the relaxed random walk model, ecological niche modeling (ENM and statistical phylogeography. The most recent common ancestor of T. aurea lineages dated from ~4.0 ± 2.5 Ma. Tabebuia aurea lineages cyclically dispersed from the West towards the Central-West Brazil, and from the Southeast towards the East and Northeast Brazil, following the paleodistribution dynamics shown by the ENMs through the last glacial cycle. A historical refugium through time may have allowed dispersal of lineages among populations of Central Brazil, overlapping with population expansion during interglacial periods and the diversification of new lineages. Range and population expansion through the Quaternary were, respectively, the most frequent prediction from ENMs and the most likely demographic scenario from coalescent simulations. Consistent phylogeographic patterns among multiple modeling inferences indicate a promising approach, allowing us to understand how cyclical climate changes through the Quaternary drove complex population dynamics and the current patterns of species distribution and genetic diversity.

  5. Critical access hospital ED to quaternary medical center: successful implementation of an integrated Picture Archiving and Communications System for patient transfers by air and sea.

    Science.gov (United States)

    Prabhakar, Anand M; Harvey, H Benjamin; Brinegar, Katelyn N; Raja, Ali S; Kelly, James R; Brink, James A; Saini, Sanjay; Oklu, Rahmi

    2016-08-01

    The purpose of this study was to investigate the role of imaging in transfers between an island Critical Access Hospital (CAH) emergency department (ED) and a quaternary care hospital. Electronic medical records were reviewed to identify all patients who were transferred from an island CAH to our quaternary care hospital in 2012 and 2013. Medical history, transfer diagnosis, and the type of imaging performed at the CAH prior to transfer were reviewed. During the study period, a total of 22075 ED visits were made to the CAH and 696 (3.2%) of these patients were transferred for higher level of care, with 424 (60.9%) of the patients transferred to our quaternary care hospital. The most common reasons for transfer were cardiac (121; 28.5%), trauma (82; 19.3%), gastrointestinal (63; 14.9%), and neurologic conditions (54; 12.7%). 349 patients (82.3%) had imaging prior to transfer (56.4% radiograph, 33.5% computed tomography, 4.7% magnetic resonance imaging, 8.0% ultrasound). Of patients that had imaging, 53.6% had positive imaging findings related to the transfer diagnosis, and patients transferred for noncardiac etiologies were significantly more likely to have imaging findings related to their transfer diagnosis compared with patients transferred for cardiac etiologies (72.9% vs 6.9%, respectively; Ptransfer for higher level of care, with nearly three-quarters of noncardiac transferred patients having a positive imaging finding related to the reason for transfer. Copyright © 2016 Elsevier Inc. All rights reserved.

  6. Neogene and Quaternary history of vegetation, climate, and plant diversity in Amazonia

    Science.gov (United States)

    van der Hammen, Thomas; Hooghiemstra, Henry

    2000-04-01

    The neotropical Amazonian and Andean plant diversity developed mainly during the Tertiary. In Amazonia, Miocene floral diversity seems considerably higher than today. During the Neogene, tropical taxa entered newly created montane area, and montane taxa entered the tropical lowlands. The general decrease of temperature during the upper Neogene and especially during the Quaternary glacial periods may have caused considerable extinctions in the lowlands. Representation of pollen of apparently principally montane taxa ( Podocarpus, Hedyosmum) in Miocene, Pliocene, and Quaternary sediments of Amazonia and surroundings, is still difficult to interpret in terms of temperature decrease at low elevation. Changes in precipitation may have profound impact on the composition of vegetation communities; Ilex and Melastomataceae increase significantly in many glacial pollen records. Increase of Weinmannia in Amazonian pollen records seems the best indicator of downward migration of montane vegetation belts. A temperature lowering at sea-level of 4.5 ±1°C during the Last Glacial Maximum (LGM) seems reasonable; it may have caused a downslope migration of some 700 m of the lower montane vegetation belt; lower montane arboreal species may have been able to grow in higher elevation areas (>500 m) of Amazonia, increasing background pollen values of montane taxa in the area. Difference between a cool and wet Middle Pleniglacial (60-28 ka BP), and a cold and dry Upper Pleniglacial (28-14 ka BP; thus including the LGM) is evident in Andean and Amazonian records; statements about environmental conditions of the ice-age Amazon should be specified chronologically. The Middle Pleniglacial is a time of accumulation of fluvial sediments. The Upper Pleniglacial is a time of incision of the rivers in their sediments; sedimentation started again in the Lateglacial (since ca. 13 ka BP) and the Holocene, when lake levels rose again. Based on simplified considerations of precipitation changes and

  7. Late Quaternary paleoenvironmental records from the Chatanika River valley near Fairbanks (Alaska)

    Science.gov (United States)

    Schirrmeister, Lutz; Meyer, Hanno; Andreev, Andrei; Wetterich, Sebastian; Kienast, Frank; Bobrov, Anatoly; Fuchs, Margret; Sierralta, Melanie; Herzschuh, Ulrike

    2016-09-01

    Perennially-frozen deposits are considered as excellent paleoenvironmental archives similar to lacustrine, deep marine, and glacier records because of the long-term and good preservation of fossil records under stable permafrost conditions. A permafrost tunnel in the Vault Creek Valley (Chatanika River Valley, near Fairbanks) exposes a sequence of frozen deposits and ground ice that provides a comprehensive set of proxies to reconstruct the late Quaternary environmental history of Interior Alaska. The multi-proxy approach includes different dating techniques (radiocarbon-accelerator mass spectrometry [AMS 14C], optically stimulated luminescence [OSL], thorium/uranium radioisotope disequilibria [230Th/U]), as well as methods of sedimentology, paleoecology, hydrochemistry, and stable isotope geochemistry of ground ice. The studied sequence consists of 36-m-thick late Quaternary deposits above schistose bedrock. Main portions of the sequence accumulated during the early and middle Wisconsin periods. The lowermost unit A consists of about 9-m-thick ice-bonded fluvial gravels with sand and peat lenses. A late Sangamon (MIS 5a) age of unit A is assumed. Spruce forest with birch, larch, and some shrubby alder dominated the vegetation. High presence of Sphagnum spores and Cyperaceae pollen points to mires in the Vault Creek Valley. The overlying unit B consists of 10-m-thick alternating fluvial gravels, loess-like silt, and sand layers, penetrated by small ice wedges. OSL dates support a stadial early Wisconsin (MIS 4) age of unit B. Pollen and plant macrofossil data point to spruce forests with some birch interspersed with wetlands around the site. The following unit C is composed of 15-m-thick ice-rich loess-like and organic-rich silt with fossil bones and large ice wedges. Unit C formed during the interstadial mid-Wisconsin (MIS 3) and stadial late Wisconsin (MIS 2) as indicated by radiocarbon ages. Post-depositional slope processes significantly deformed both, ground

  8. A Shape-Adaptive, Antibacterial-Coating of Immobilized Quaternary-Ammonium-Compounds Tethered on Hyperbranched Polyurea and its Mechanism of Action

    NARCIS (Netherlands)

    Asri, Lia; Crismaru, Mihaela; Roest, Steven; Chen, Yun; Ivashenko, Oleksii; Rudolf, Petra; Tiller, Joerg C.; van der Mei, Henny C.; Loontjens, Ton J.A.; Busscher, Henk J. Busscher

    2014-01-01

    Quaternary-ammonium-compounds are potent cationic antimicrobials used in everyday consumer products. Surface-immobilized, quaternary-ammonium-compounds create an antimicrobial contact-killing coating. We describe the preparation of a shape-adaptive, contact-killing coating by tethering quaternary-am

  9. Late Quaternary Glacial Chronology in the Cordillera de Talamanca, Costa Rica, Investigated Using Cosmogenic Cl-36 Surface Exposure Dating

    Science.gov (United States)

    Li, Y.; Potter, R.; Horn, S.; Orvis, K. H.

    2015-12-01

    The role of the tropics in past and future climate change has garnered significant attention in recent decades, but debate still exists over climate linkages between the tropics and the middle and high latitudes. Glaciers in tropical mountains are highly sensitive indicators of climate, and glacial landforms left behind by past glacier fluctuations provide key evidence of paleoclimate trends and their forcing mechanisms. We investigated late Quaternary glacial chronology from two glaciated valleys on the Chirripó massif in the Cordillera de Talamanca, Costa Rica. Previous studies in this highland have constrained the most recent deglaciation to 12.4-9.7 ka cal BP based on radiocarbon dates on basal sediments of glacial lakes within the cirque at the head of the Morrenas Valley. However, no studies have been conducted to constrain the ages of the moraines located down valley. We dated the formation ages of these moraines in the Morrenas and Talari valleys using cosmogenic Cl-36 surface exposure dating. Our results indicate a major glacial event ~21-18 ka, broadly synchronous with the global Last Glacial Maximum (LGM). Glaciers during this period advanced 3.2-3.4 km down valley on both sides of the Chirripó massif. Our ages also suggest periods of glacial retreat or standstills ~18-10 ka before complete deglaciation of this highland ~10 ka. These results provide insight into the timing and extent of glacial events in this tropical highland that is of critical importance for reconstructing regional and global climate patterns.

  10. Evolution characteristics of Quaternary tectonic stress field in the north and east margin of Qinghai-Xizang plateau

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    By inversion of fault slip data for Quaternary tectonic stress field and the analysis of crustal deformation after late Teriary, we explained the evolution of crustal dynamic about the north and east margin of Qinghai-Xizang (Tibet) plateau since Miocene. From middle or late Miocene to early Pleistocene, the tectonic stress field was featured by a maximum principal compression which was coming from the collision of India Plate perpendicular to the boundary of the plateau, and was basically of reverse faulting type. Since the late period of early Pleistocene, India Plate continued to push northward and the compressional deformation of the plateau interior increased continuously, meanwhile, NW-SE extension appeared on the east side of the plateau. This formed a favorable condition for the interior block of the plateau to slide towards east and southeast, causing the faults surrounding the plateau to change from thrust to strike-slip. The contemporary tectonic stress field was formed from the late period of early Pleistocene and continued to present. The direction of maximum principal compressional stress rotated clockwise with respect to the previous tectonic stress field, the stress field was mainly of strike-slip type.

  11. Hydrogeological characterization of the Nador Plio-Quaternary aquifer, Tipaza (Algeria); Caracterizacion hidrogeologica del acuifero pliocuaternario de Nador, Tipaza (Argelia)

    Energy Technology Data Exchange (ETDEWEB)

    Bouderbala, A.; Remini, B.; Pulido-Bosch, A.

    2014-06-01

    This paper focuses on the hydrogeological and hydrochemical knowledge of the Nador Plio-Quaternary aquifer in Tipaza, situated along the Algerian coastline. It includes the identification of the hydrodynamic aquifer, hydrogeological and piezometric characteristics and, finally, an overview of the hydro-geochemistry of the area. We carried out this study between 2008 and 2013, with piezometric and hydrochemical monitoring of 24 wells in the study area. The physicochemical analysis of water shows that 25 % of the wells in the coastal zone have values of electrical conductivity greater than 3000 μS/cm The Mg{sup 2}+/Ca{sup 2}+ ratio is also higher than one and there are sodium chloride facies due to the mix of freshwater with seawater exceeding 10 % in some places. However, the comparison of the salinity of the groundwater during the period 2008-2013 with 1988-2004 indicates that there is a low dilution due to the reduction of pumping in the aquifer after the construction of the Boukourdane dam. There has also been a more rainy period and a possible return flow from irrigation in the area. (Author)

  12. Late Quaternary Megafaunal Extinctions in Northern Eurasia: Latest Results

    Science.gov (United States)

    Stuart, Anthony

    2010-05-01

    Anthony J. Stuart1 & Adrian M. Lister2 1 Biological and Biomedical Sciences, Durham University, South Road, Durham DH1 3LE, UK. Email: tony.s@megafauna.org.uk 2 Department of Palaeontology, The Natural History Museum, Cromwell Road, London SW7 5BD, UK. Email: a.lister@nhm.ac.uk. The global extinction of many spectacular species of megafauna (large terrestrial mammals, together with a few large reptiles and birds) within the last c. 50,000 years (Late Quaternary) has been attributed on the one hand to ‘overkill' by human hunters and on the other to environmental change. However, in spite of more than half a century of active interest and research the issue remains unresolved, largely because there are insufficient dated records of megafaunal species for most parts of the world. Northern Eurasia is an especially fruitful region in which to research megafaunal extinctions as it has a wealth of megafaunal material and crucially most extinctions occurred well within the range of radiocarbon dating. Our approach, in a series of projects over the last decade funded by the UK Natural Environment Research Council (NERC), involves amassing radiocarbon dates made directly on megafaunal material from across the entire region: a) by submitting a substantial number of samples (so far c. 500 dates) for AMS dating at Oxford (ORAU); b) obtaining AMS dates from colleagues working on aDNA projects; and c) carefully screening (‘auditing') dates from the literature. The dates (calibrated using OxCal) are plotted as time-sliced maps and as chronological/geographical charts. In our previous work we targeted a range of extinct species from Northern Eurasia: woolly mammoth, woolly rhinoceros, giant deer, cave bear (in collaboration with Martina Pacher), cave lion, and spotted hyaena (which survives today only in Sub-Saharan Africa). By this means we have established a reliable chronology for these extinctions which we are able to compare with the climatic, vegetational and

  13. Late Quaternary clay minerals off Middle Vietnam in the western South China Sea: Implications for source analysis and East Asian monsoon evolution

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 450 ka during late Quaternary from Core MD05-2901 off Middle Vietnam in the western South China Sea are reported to reconstruct a history of East Asian monsoon evolution.Variations in Illite,chlorite,and kaolinite contents indicate a strong glacial-interglacial cyclicity,while changes in smectite content present a higher frequency cyclicity.The provenance analysis indicates a mixture of individual clay minerals from various sources surrounding the South China Sea.Smectite derived mainly from the Sunda shelf and its major source area of the Indonesian islands.Illite and chlorite originated mainly from the Mekong and Red rivers.Kaolinite was provided mainly by the Pearl River.Spectral analysis of the kaolinite/(illite+chlorite) ratio displays a strong eccentricity period of 100 ka,implying the ice sheet-forced winter monsoon evolution; whereas higher frequency changes in the smectite content show an ice sheet-forced obliquity period of 41 ka,and precession periods of 23 and 19 ka and a semi-precession period of 13 ka as well,implying the tropical-forced summer monsoon evolution.The winter monsoon evolution is generally in coherence with the glacial-interglacial cyclicity,with intensified winter monsoon winds during glacials and weakened winter monsoon winds during interglacials; whereas the summer monsoon evolution provides an almost linear response to the summer insolation of low latitude in the Northern Hemisphere,with strengthened summer monsoon during higher insolation and weakened summer monsoon during lower insolation.The result suggests that the high-latitude ice sheet and low-latitude tropical factor could drive the late Quaternary evolution of East Asian winter and summer monsoons,respectively,implying their diplex and self-contained forcing mechanism.

  14. Superoxide Anion Radical Scavenging Ability of Quaternary Ammonium Salt of Chitosan

    Institute of Scientific and Technical Information of China (English)

    Xiao Yan ZHU; Jian Min WU; Zhi Shen JIA

    2004-01-01

    A series of N-alkyl or N-aryl chitosan quaternary ammonium salt were prepared using 96% deacetylated chitosan. Their scavenging activities against superoxide anion radical were investigated by chemiluminescence. The IC50 values of these compounds range from 280 to 880 μg/mL, which should be attributed to their different substitutes.

  15. Characteristics of Quaternary deposits near Songjianghe Town on west slope of Changbai Mountain

    Institute of Scientific and Technical Information of China (English)

    WANG Xi-kui; LI Jun-min; ZHANG Hong-yan

    2004-01-01

    On the basis of field survey, microscope sighting, TL dating and scanning electron microscope analysis, the characteristics of Quaternary deposits near Songjianghe Town on the west slope of Changbai Mountain are analyzed and described. There were two phases of volcanism during Mid-Late Quaternary. One occurred before 15.22 × 104 aB.P. and the other happened between 14.27 × 104 aB.P. and 1.41 × 104 aB.P. Volcanism is a landform-making process which makes the rough relief in the studied area become higher and higher. Flow water is a main erosion agency and it cuts into the basalts making river valleys. The Quaternary fluvial deposits distributed on terraces first come from the weathered debris of basement rocks, then they are transported and deposited by flow water. After 1.41 × 104 aB.P, the river water quickly cuts into the newly formed basalts making a deep valley. Volcanism in the studied area is a main landform-making event in Mid-Late Quaternary.

  16. 40 CFR 721.9075 - Quaternary ammonium salt of fluorinated alkylaryl amide.

    Science.gov (United States)

    2010-07-01

    ... fluorinated alkylaryl amide. 721.9075 Section 721.9075 Protection of Environment ENVIRONMENTAL PROTECTION... amide. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as quaternary ammonium salt of fluorinated alkylaryl amide (PMN No. P-92-688)...

  17. Kinetics of Hydrolysis of Cationic Reactive Disperse Dyes Containing Quaternary Group

    Institute of Scientific and Technical Information of China (English)

    XIE Kong-liang; HOU Ai-qin

    2006-01-01

    The kinetics of hydrolysis of cationic reactive disperse dyes containing quaternary group and chemical shift(13CNMR) of the adjacent carbon atoms with pyridine-acetylamino were discussed. The results show pyridine-acetylamino reactive group had higher reactivity than chloroacetylamino and chemical shift(13CNMR) of the adjacent carbon atoms with pyridine-acetylamino moved 18.77 ppm.

  18. Gravity field separation and mapping of buried quaternary valleys in Lolland, Denmark using old geophysical data

    DEFF Research Database (Denmark)

    Møller, M.J.; Olsen, Henrik; Ploug, C.;

    2007-01-01

    In this paper we utilise the old industrial data for planning new surveys. The overall purpose is a detailed mapping of possible aquifers for the island of Lolland, Denmark. This is done through detection and modelling of the buried quaternary valleys, which either can serve as potential aquifers...

  19. Quaternary Volcanic Activities in Shandong Peninsula and Northern Parts of Jiangsu and Anhui Provinces

    Institute of Scientific and Technical Information of China (English)

    郑洪汉; 高维明; 等

    1990-01-01

    Quaternary volcanic rocks often coexist with loess,as observed in the same geologic sections in the Shandong Peninsula and northern parts of Jiangsu and Anhui provinces.The development age of Shandong loess in close to that in the middle reaches of the Yellow River.Loess strata are of synchronous implication in the loess belt of North China.So the ages of volcanic activities can be es-timated approximately from the stratigraphic relations between loess layers and volcanic rocks.The re-sults of dating of the Quaternary volcanic rocks,baked layers and the TL dates of loess samples sug-gest that the Quaternary volcanic activity can be divided into 4 stages in the region studied,with the ages being 1.15-1.03,0.86-0.72,0.55-0.33 and 0.02 Ma B.P.respectively .The occurrence of tephra in the Shandong loess sections is possible due to multiple episodes of volcanism during the Quaternary time.

  20. Epoxidation of Alkenes with Aqueous Hydrogen Peroxide and Quaternary Ammonium Bicarbonate Catalysts

    DEFF Research Database (Denmark)

    Mielby, Jerrik Jørgen; Kegnæs, Søren

    2013-01-01

    A range of solid and liquid catalysts containing bicarbonate anions were synthesised and tested for the epoxidation of alkenes with aqueous hydrogen peroxide. The combination of bicarbonate anions and quaternary ammonium cations opens up for new catalytic systems that can help to overcome...

  1. Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions.

    Science.gov (United States)

    Potter, Bowman; Edelstein, Emma K; Morken, James P

    2016-07-01

    The catalytic Suzuki-Miyaura cross-coupling with chiral γ,γ-disubstituted allylboronates in the presence of RuPhos ligand occurs with high regioselectivity and enantiospecificity, furnishing nonracemic compounds with quaternary centers. Mechanistic experiments suggest that the reaction occurs by transmetalation with allyl migration, followed by rapid reductive elimination.

  2. Systematic paleontology of Quaternary ostracode assemblages from the Gulf of Alaska; Part 3, Family Cytheruridae

    Science.gov (United States)

    Brouwers, E.M.

    1994-01-01

    Forty-six species of podocopid ostracodes, most belonging to the Family Cytheruridae, are reported from Quaternary continental-shelf sediments of the Gulf of Alaska. Descriptions and illustrations are provided for 27 new species, 11 previously described species, and 8 species retained in open nomenclature. This report is based on 198 bottom grab samples collected during 1975, 1979, and 1980.

  3. Synthesis of hierarchical zeolites using an inexpensive mono-quaternary ammonium surfactant as mesoporogen.

    Science.gov (United States)

    Zhu, Xiaochun; Rohling, Roderigh; Filonenko, Georgy; Mezari, Brahim; Hofmann, Jan P; Asahina, Shunsuke; Hensen, Emiel J M

    2014-12-04

    A simple amphiphilic surfactant containing a mono-quaternary ammonium head group (N-methylpiperidine) is effective in imparting substantial mesoporosity during synthesis of SSZ-13 and ZSM-5 zeolites. Highly mesoporous SSZ-13 prepared in this manner shows greatly improved catalytic performance in the methanol-to-olefins reaction compared to bulk SSZ-13.

  4. Quaternary Structure and Functional Unit of Energy Coupling Factor (ECF)-type Transporters

    NARCIS (Netherlands)

    Beek, Josy ter; Duurkens, Ria H.; Erkens, Guus B.; Slotboom, Dirk Jan

    2011-01-01

    ATP-binding cassette (ABC) transporters mediate transport of diverse substrates across membranes. We have determined the quaternary structure and functional unit of the recently discovered ECF-type (energy coupling factor) of ABC transporters, which is widespread among prokaryotes. ECF transporters

  5. Complete genome sequence of Campylobacter jejuni RM1246-ERRC that exhibits resistance to Quaternary Ammonium Compounds

    Science.gov (United States)

    Campylobacter jejuni strain RM1246-ERRC is a clinical isolate. In laboratory experiments RM1246-ERRC exhibited resistance to the antimicrobial effects of quaternary ammonium compounds (QACs) when compared to other C. jejuni strains. The chromosome of RM1246-ERRC was determined to be 1,659,694 bp w...

  6. A New Method to Identify Quaternary Moraine:Acoustic Emission Stress Measurement

    Institute of Scientific and Technical Information of China (English)

    ZHAO Zhizhong; QIAO Yansong; TIAN Jiaorong; WANG Min; LI Mingze; HE Peiyuan; QIAN Fang

    2006-01-01

    How to effectively identify glacial sediments, especially Quaternary moraine, has been in dispute for decades. The traditional methods, e.g., sedimentary and geomorphologic ones, are facing challenge in eastern China where controversial moraine deposits are dominatingly distributed. Here,for the first time, we introduce the acoustic emission (AE) stress measurement, a kind of historical stress measurement, to identify Quaternary moraine. The results demonstrate that it can be employed to reconstruct stress information of glaciation remaining in gravels, and may shed light on the identification of Quaternary moraine in eastern China. First, we measured the AE stress of gravels of glacial origin that are underlying the Xidatan Glacier, eastern Kunlun Mountains in western China.Second, we calculated the stress according to the actual thickness of the glacier. The almost identical stress values suggest that the glacial gravels can memorize and preserve the overlying glacier-derived aplomb stress. And then we introduce this new approach to the controversial moraine in Mount Lushan, eastern China. The results indicate that the stress is attributed to the Quaternary glacier, and the muddy gravels in the controversial moraine in Mount Lushan are moraine deposits but not others.

  7. QuaBingo: A Prediction System for Protein Quaternary Structure Attributes Using Block Composition

    Directory of Open Access Journals (Sweden)

    Chi-Hua Tung

    2016-01-01

    Full Text Available Background. Quaternary structures of proteins are closely relevant to gene regulation, signal transduction, and many other biological functions of proteins. In the current study, a new method based on protein-conserved motif composition in block format for feature extraction is proposed, which is termed block composition. Results. The protein quaternary assembly states prediction system which combines blocks with functional domain composition, called QuaBingo, is constructed by three layers of classifiers that can categorize quaternary structural attributes of monomer, homooligomer, and heterooligomer. The building of the first layer classifier uses support vector machines (SVM based on blocks and functional domains of proteins, and the second layer SVM was utilized to process the outputs of the first layer. Finally, the result is determined by the Random Forest of the third layer. We compared the effectiveness of the combination of block composition, functional domain composition, and pseudoamino acid composition of the model. In the 11 kinds of functional protein families, QuaBingo is 23% of Matthews Correlation Coefficient (MCC higher than the existing prediction system. The results also revealed the biological characterization of the top five block compositions. Conclusions. QuaBingo provides better predictive ability for predicting the quaternary structural attributes of proteins.

  8. Mechanism of Osmotic Activation of the Quaternary Ammonium Compound Transporter (QacT) of Lactobacillus plantarum

    NARCIS (Netherlands)

    Glaasker, Erwin; Heuberger, Esther H.M.L.; Konings, Wil N.; Poolman, Bert

    1998-01-01

    The accumulation of quaternary ammonium compounds in Lactobacillus plantarum is mediated via a single transport system with a high affinity for glycine betaine (apparent Km of 18 μM) and carnitine and a low affinity for proline (apparent Km of 950 μM) and other analogues. Mutants defective in the

  9. Synthesis and Spectroscopic Characterisation of N-Alkyl Quaternary Ammonium Salts Typical Precursors of Cyanines

    OpenAIRE

    Almeida, P; Reis, L. V.; SANTOS, P.F.; Ramos, S. S.; Pardal, A. C.

    2002-01-01

    The synthesis and spectroscopic characterisation of some representative N-alkylsubstituted quaternary ammonium salts derived from benzothiazole, benzoxazole, benzoselenazole, indole and quinoline are described. These heterocyclic salts, bearing an activated methyl group in the 2-position in relation to the nitrogen atom and N-methyl, -pentyl, -hexyl and -decyl chains, are typical precursors of cyanine dyes.

  10. Synthesis and Spectroscopic Characterisation of N-Alkyl Quaternary Ammonium Salts Typical Precursors of Cyanines

    Directory of Open Access Journals (Sweden)

    P. Almeida

    2002-03-01

    Full Text Available The synthesis and spectroscopic characterisation of some representative N-alkylsubstituted quaternary ammonium salts derived from benzothiazole, benzoxazole, benzoselenazole, indole and quinoline are described. These heterocyclic salts, bearing an activated methyl group in the 2-position in relation to the nitrogen atom and N-methyl, -pentyl, -hexyl and -decyl chains, are typical precursors of cyanine dyes.

  11. Long alkyl chain bis-quaternary ammonium-based ionic liquids as biologically active xanthene dyes

    Energy Technology Data Exchange (ETDEWEB)

    Pernak, Juliusz; Swierczynska, Anna; Walkiewicz, Filip [Poznan Univ. of Technology, Poznan (Poland). Faculty of Chemical Technology; Krystkowiak, Ewa [A. Mickiewicz University, Poznan, (Poland). Faculty of Chemistry; Maciejewski, Andrzej [A. Mickiewicz University, Poznan (Poland). Centre of Ultrafast Laser Spectroscopy

    2009-07-01

    New examples of air- and moisture-stable, hydrophobic and hydrophilic bis-quaternary ammonium derived ionic liquids have been prepared. These ionic liquids have been proposed to act as biological active dyes with characteristic unique physicochemical properties, providing alternatives to some conventional anionic xanthene dyes such as eosine Y, fluorescein and erythrosine. (author)

  12. Blockfields in Reinheimen Nationalpark, Norway – Neogene weathering remnants or Quaternary periglacial origin?

    DEFF Research Database (Denmark)

    Andersen, Jane Lund; Egholm, David Lundbek; Knudsen, Mads Faurschou;

    rates of landscape evolution of the mountain summit. References Goodfellow B W, 2012. A granulometry and secondary mineral fingerprint of chemical weathering in periglacial landscapes and its application to blockfield origins. Quaternary Science Reviews, 57, 121- 135. Strømsøe J R, Paasche Ø, 2011....... Weathering patterns in high-latitude regolith. Journal of Geophysical Research: Earth Surface, 116 (F3)...

  13. Kinetic resolution of alkyne-substituted quaternary oxindoles via copper catalysed azide-alkyne cycloadditions.

    Science.gov (United States)

    Brittain, William D G; Buckley, Benjamin R; Fossey, John S

    2015-12-18

    The synthesis and kinetic resolution of quaternary oxindoles through copper catalysed azide-alkyne cycloadditions is presented. Selectivity factors (s) up to 22.1 ± 0.5 are reported. Enantioenriched alkynes and triazoles were obtained in ≥80% enantiomeric excess (e.e.).

  14. Quaternary rhyolite from the Mineral Mountains, Utah, USA. Final report, Volume 77-10

    Energy Technology Data Exchange (ETDEWEB)

    Evans, S.H. Jr.; Nash, W.P.

    1978-03-01

    A suite of silicic volcanic rocks is associated with the Roosevelt Hot Springs geothermal area in southwestern Utah. The volcanic sequence includes Tertiary rhyolite 8 My old and obsidian, ash and rhyolite of Quaternary age. The Quaternary lavas are characterized by high silica content (76.5% Si0/sub 2/) and total alkalies in excess of 9 percent. Obsidians commonly contain greater amounts of fluorine than water. Two older flows (0.8 My) can be distinguished from younger dome and pyroclastic material (approximately 0.5 My) by subtle differences in their chemistry. The mineralogy of the rhyolites consists of alkali feldspar, plagioclase, and small amounts of Fe-Ti oxides, biotite, hornblende and rare allanite. Fe-Ti oxide temperatures are 740 to 785/sup 0/C for the flows and 635 to 665/sup 0/C for the domes; two feldspar temperatures give similar results. The phase relationships of bulk rock, glass and feldspar compositions demonstrate that the younger Quaternary rhyolites could have been derived from the earlier magma type, represented by the obsidian flows, by a process of crystal fractionation. The major phases which must fractionate are alkali feldspar, plagioclase and quartz with minor amounts of biotite, magnetite and ilmenite participating also. Trace element patterns support this scheme as well. The Tertiary lavas cannot be related to the Quaternary rhyolites and are thought to represent a separate event.

  15. A chronology of alluvial fan response to Late Quaternary sea level and climate change, Crete

    Science.gov (United States)

    Pope, Richard J. J.; Candy, Ian; Skourtsos, Emmanuel

    2016-09-01

    To better understand how fluvial systems respond to late Quaternary climatic forcing OSL and U-series dating was applied to stratigraphically significant sedimentary units within a small (aggradation to occur except during major climatic driven transitions i.e. major sea level fall and postglacial vegetation development.

  16. Synthesis, EPR and Fluorescence Properties of Quaternary Lanthanide Complexes with Chloroacetate and Phenanthroline Ligands

    Institute of Scientific and Technical Information of China (English)

    朱龙观; 肖洪平

    2002-01-01

    A series of novel quaternary mixed anion complexes of lanthanide containing 1,10-phenanthroline (phen) and chloroacetate ligands were synthesized from the water/ethanol solution with slightly acidic solution and characterized by elemental analysis, IR, UV and thermal analysis. The EPR and fluorescence properties also were studied.

  17. High order quaternary arrangement confers increased structural stability to Brucella Spp. lumazine synthase

    Energy Technology Data Exchange (ETDEWEB)

    Zylberman, V.; Craig, P.O.; Klinke, S.; Cauerhff, A.; Goldbaum, F.A. [Instituto Leloir, Buenos Aires (Argentina); Braden, B.C. [Bowie State Univ., Maryland (United States)

    2004-07-01

    The penultimate step in the pathway of riboflavin biosynthesis is catalyzed by the enzyme lumazine synthase (LS). One of the most distinctive characteristics of this enzyme is the structural quaternary divergence found in different species. The protein exists as pentameric and icosahedral forms, built from practically the same structural monomeric unit. The pentameric structure is formed by five 18 kDa monomers, each extensively contacting neighboring monomers. The icosahedral structure consists of 60 LS monomers arranged as twelve pentamers giving rise to a capsid exhibiting icosahedral 532 symmetry. In all lumazine synthases studied, the topologically equivalent active sites are located at the interfaces between adjacent subunits in the pentameric modules. The Brucella spp. lumazine synthase (BLS) sequence clearly diverges from pentameric and icosahedral enzymes. This unusual divergence prompted to further investigate on its quaternary arrangement. In the present work, we demonstrate by means of solution Light Scattering and X-ray structural analyses that BLS assembles as a very stable dimer of pentamers representing a third category of quaternary assembly for lumazine synthases. We also describe by spectroscopic studies the thermodynamic stability of this oligomeric protein, and postulate a mechanism for dissociation/unfolding of this macromolecular assembly. The higher molecular order of BLS increases its stability 20 deg C compared to pentameric lumazine synthases. The decameric arrangement described in this work highlights the importance of quaternary interactions in the stabilization of proteins. (author)

  18. Different virucidal activities of hyperbranched quaternary ammonium coatings on poliovirus and influenza virus

    NARCIS (Netherlands)

    Tuladhar, E.; Koning, M.C. de; Fundeanu, I.; Beumer, R.; Duizer, E.

    2012-01-01

    Virucidal activity of immobilized quaternary ammonium compounds (IQACs) coated onto glass and plastic surfaces was tested against nveloped influenza A (H1N1) virus and nonenveloped poliovirus Sabin1. The IQACs tested were virucidal against the influenza virus within 2 min, but no virucidal effect ag

  19. Tertiary and Quaternary sedimentation in a part of the Duero Basin Palencia, (Spain)

    NARCIS (Netherlands)

    Mabesoone, J.M.

    1959-01-01

    Sediments in the foreland of a mountain chain are sometimes suited to reconstitute the conditions in these mountains at the time of deposition of the sediments. The present study gives the results of a sedimentological investigation of the Tertiary and Quaternary deposits in a part of the Duero basi

  20. Quaternary tectonic movements in the Argentine Puna, 24/sup 0/ to 27/sup 0/ s latitude

    Energy Technology Data Exchange (ETDEWEB)

    Strecker, M.R.; Alonso, R.; Rivelli, F.; Mon, R.

    1985-01-01

    The Puna of NW Argentina, one of the highest plateaus in the world, is the southern continuation of the Andean Altiplano geomorphic province of Peru and Bolivia. The region is not seismically active and reports of neotectonic movements are scarce. However, the areas of Salar de los Pastos Grandes, Salar del Hombre Muerto and Sierra Calalaste clearly have experienced Quaternary tectonic movements. At Salar de los Pastos Grandes, early Pleistocene lake sediments are offset by reverse faulting. At Salar del Hombre Muerto, Quaternary pyroclastic and debris-flow deposits are unconformable over sediments 5.86 m.y. old that were folded during the Pliocene-Pleistocene Diaguita deformation. Within the Quaternary sediments two separate deformational phases with reverse faulting and shallow thrusting are recognized. The timing of movement is well defined since the deformed strata are covered by a basalt flow 0.75 m.y. old. The flow in turn is affected by normal faulting. Similar normal faults associated with basalt flows were found at Sierra Calalaste. These observations are in accord with pronounced extensional movements and basaltic volcanism at the Calama-Olacapato-Toro Lineament (0.2 m.y. old flows) and might document the Quaternary transition from a compressive to an extensional tectonic regime in the southern Puna.

  1. Synthesis and biological activity of quaternary ammonium salt-type agents containing cholesterol and terpenes.

    Science.gov (United States)

    Novotná, Eva; Waisser, Karel; Kuneš, Jiří; Palát, Karel; Buchta, Vladimír; Stolaříková, Jiřina; Beckert, Rainer; Wsól, Vladimír

    2014-06-01

    New quaternary ammonium salt-type compounds with lipophilic cholesterol and terpene moieties were synthesized. The compounds showed promising antibacterial and antimycobacterial activities. Those compounds containing the cholesterol moiety showed significant activity against Staphylococcus aureus, Staphylococcus epidermidis, and Enterococcus faecium. On the contrary, the antimycobacterial activity increased with the presence of the terpene unit in the molecule.

  2. Different virucidal activities of hyperbranched quaternary ammonium coatings on poliovirus and influenza virus

    NARCIS (Netherlands)

    Tuladhar, E.; Koning, de M.C.; Fundeanu, I.; Beumer, R.R.; Duizer, E.

    2012-01-01

    Virucidal activity of immobilized quaternary ammonium compounds (IQACs) coated onto glass and plastic surfaces was tested against enveloped influenza A (H1N1) virus and nonenveloped poliovirus Sabin1. The IQACs tested were virucidal against the influenza virus within 2 min, but no virucidal effect

  3. Late Quaternary vegetation and glacial history in the St. Lawrence Lowlands, Canada

    NARCIS (Netherlands)

    Lasalle, Pierre

    1966-01-01

    This paper presents data of various kinds concerning the Quaternary geology of the St. Lawrence Lowlands: pollen diagrams, C14 dates, and diatom floras. These data show that the highest parts of the St. Lawrence Lowlands were already deglaciated more than 12,000 years ago, as appears from the existe

  4. Late Quaternary vegetational and climate dynamics in northeastern Brazil, inferences from marine core GeoB 3104-1

    Science.gov (United States)

    Behling, Hermann; W. Arz, Helge; Pätzold, Jürgen; Wefer, Gerold

    2000-06-01

    Late Quaternary paleoenvironments from northeastern (NE) Brazil have been studied by pollen analysis of marine sediment. The studied core GeoB 3104-1 (3°40' S, 37°43' W, 767 m b.s.l.) from the upper continental slope off NE Brazil is 517 cm long and >42,000 14C yr BP old. Chronological control was obtained by 12 radiocarbon (AMS) dates from individuals of the foraminiferal species Globigerinoides sacculifer. Modern pollen analogs were received from 15 river, lake and forest soil surface samples from NE Brazil. Marine pollen dates indicate the predominance of semi-arid caatinga vegetation in NE Brazil during the recorded period between >42,000 and 8500 14C yr BP. The increased fluvial input of terrigenous material, with high concentrations of pollen and specially fern spores, into the marine deposits, about 40,000, 33,000 and 24,000 14C yr BP and between 15,500 and 11,800 14C yr BP, indicate short-term periods of strong rainfall on the NE Brazilian continent. The expansion of mountain, floodplain and gallery forests characterize the interval between 15,500 and 11,800 14C yr BP as the wettest recorded period in NE Brazil, which allowed floristic exchanges between Atlantic rain forest and Amazonian rain forest, and vice versa. The paleodata from core GeoB 3104-1 confirm the, in general, dry pre-Last Glacial Maximum (LGM) and LGM conditions and the change to wet Lateglacial environments in tropical South America. The annual movement of the intertropical convergence zone over NE Brazil, the strong influence of the Antarctic cold fronts and changes of the high-pressure cell over the southern Atlantic, may explain the very wet Lateglacial period in NE Brazil. The documented NE Brazilian short-term signals correlate with the documented Dansgaard-Oeschger cycles and Heinrich events from the northern Hemisphere and suggest strong teleconnections.

  5. Autecological traits determined two evolutionary strategies in Mediterranean plants during the Quaternary: low differentiation and range expansion versus geographical speciation in Linaria.

    Science.gov (United States)

    Blanco-Pastor, J L; Vargas, P

    2013-11-01

    The evolutionary patterns of the Mediterranean flora during the Quaternary have been relatively well documented based on phylogenetic and biogeographic analyses, but few studies have addressed the evolutionary traits that determined diversification and range expansion success during this period. We analysed previously published and newly generated sequences of three plastid noncoding regions (rpl32-trnL(UAG) , trnS-trnG and trnL-trnF), the nuclear ribosomal internal transcribed spacer (ITS) and a low-copy nuclear gene intron (AGT1) of Linaria sect. Supinae, a group of angiosperms that diversified in the Quaternary. The origin and recent colonization dynamics of closely related lineages were inferred by biogeographic reconstruction and phylogeographic analyses, while breeding system experiments coupled with ecological and morphological data were used to test association with range expansion and diversification. A combination of traits, including selfing, short lifespan and the ability to tolerate a wide variety of substrates, were key factors underlying range expansion after long-distance dispersal throughout the Mediterranean basin. By contrast, self-incompatibility may have promoted higher diversification rates in narrow ranges of the Iberian Peninsula. We argue that a few traits contributed to the adoption of two contrasting strategies that may have been predominant in the evolution of Mediterranean angiosperms. © 2013 John Wiley & Sons Ltd.

  6. Electrophysiological effects of bepridil and its quaternary derivative CERM 11888 in closed chest anaesthetized dogs: a comparison with verapamil and diltiazem.

    Science.gov (United States)

    Leboeuf, J; Lamar, J C; Massingham, R; Ponsonnaille, J

    1989-12-01

    1. The electrophysiological effects of bepridil, its quaternary derivative, CERM 11888 (methylpyrrolidinium bromide) (both 2.5 mg kg-1 i.v.) and those of verapamil and diltiazem (0.2 mg kg-1 i.v.) were studied in closed chest anaesthetized dogs at doses used in clinical studies. 2. The four drugs caused a bradycardia with the following order of potency: bepridil greater than CERM 11888 greater than diltiazem greater than verapamil. 3. All the compounds slowed conduction in the AV node, increased the refractory period (RP) and decreased Wenckebach rates with the following order: verapamil much greater than diltiazem greater than bepridil greater than CERM 11888. 4. Verapamil and diltiazem did not affect conduction or the RP in atria while bepridil weakly slowed the former and markedly increased the latter. CERM 11888 caused a lengthening of RP but this was a delayed effect. 5. In the ventricle, bepridil and CERM 11888 caused a small increase in the QRS and a more pronounced increase in the RP. Both compounds increased QTc but did not modify HV. Verapamil and diltiazem had no significant effects at the ventricular level. 6. Our results confirm that the main sites of action of calcium antagonists are the SA and AV nodes. Bepridil has a broader spectrum of activity and also acts at the atrial and ventricular levels. A comparison of the effects of bepridil with those of its quaternary derivative suggests the involvement of an intracellular action in the electrophysiological effects of bepridil.

  7. Late Quaternary faulting and historic seismicity in the western Lake Mead area, Nevada, Arizona and California

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, L.W.; O' Connel, D.R. (Bureau of Reclamation, Denver, CO (United States))

    1993-04-01

    As part of a regional seismic hazard study for Reclamation dams on the northern lower Colorado River, the age and distribution of known and suspected late Quaternary faults were investigated and historic seismicity was analyzed for the western Lake Mead area. Late Quaternary faults in the area consist of the Mead Slope, Black Hills, Frenchman Mountain, and California Wash faults. Geologic mapping and scarp profiles indicate that of these late Quaternary faults, the Black Hills fault displays evidence for the youngest (probably mid-Holocene) surface faulting. No information about the ages of older events was obtained for any of the faults; however, the ages of the most recent surface-rupturing events for individual faults suggest recurrence intervals of tens of thousands of years for specific faults and regional recurrence rates of several thousand years for M[sub 3] [>=] 6 1/2 events. Since 1936 when Hoover Dam was completed and the initial filling of Lake Mead began, the Boulder Basin area, the largest and deepest part of Lake Mead, has experienced abundant seismic activity that includes some of the largest historic earthquakes in southern Nevada (at least 21 M 4 events and one M 5). Based on earthquake locations from early networks (1937--1950) and those from temporary networks operating in 1975--1976 and 1988, earthquakes are clearly associated with the northeast-striking Mead Slope and Black Hills faults; one of the few associations of seismicity with late Quaternary faults in the Basin and Range. However, earthquakes also appear to be associated with the Fortification fault, a north-striking fault with no evidence of Quaternary surface faulting. Focal mechanisms for some of the 1975--1976 and 1988 events (all events M [<=] 3) suggest active strike-slip/oblique-slip motion on north-striking faults and normal/oblique-slip motion on northeast-striking structures.

  8. Luminescence dating of Late Quaternary sediments from East Greenland

    DEFF Research Database (Denmark)

    Mejdahl, V.; Funder, Svend Visby

    1994-01-01

    Luminescence dating based on K-feldspars and using both TL and OSL methods have been performed on 94 sediment samples from East Greenland. The ages go back more than 380 ka, but are mainly from the last interglaciation and the subsequent period and include both shallow-marine/coastal-fluvial and ......Luminescence dating based on K-feldspars and using both TL and OSL methods have been performed on 94 sediment samples from East Greenland. The ages go back more than 380 ka, but are mainly from the last interglaciation and the subsequent period and include both shallow...

  9. Luminescence dating of Late Quaternary sediments from East Greenland

    DEFF Research Database (Denmark)

    Mejdahl, V.; Funder, Svend Visby

    1994-01-01

    Luminescence dating based on K-feldspars and using both TL and OSL methods have been performed on 94 sediment samples from East Greenland. The ages go back more than 380 ka, but are mainly from the last interglaciation and the subsequent period and include both shallow-marine/coastal-fluvial and ......Luminescence dating based on K-feldspars and using both TL and OSL methods have been performed on 94 sediment samples from East Greenland. The ages go back more than 380 ka, but are mainly from the last interglaciation and the subsequent period and include both shallow...

  10. Wrench tectonics control on Neogene-Quaternary sedimentation along the Mid-Hungarian Mobile Belt

    Science.gov (United States)

    Pogacsas, Gyorgy; Juhász, Györgyi; Mádl-Szőnyi, Judit; Simon, Szilvia; Lukács, Szilveszter; Csizmeg, János

    2010-05-01

    The Neogene Pannonian basin is underlain by a large orogenic collage which is built up by several tectonostratigraphic terrains. The basement of the Pannonian Basin became imbricate nappes during the Cretaceous Alpine collision. Nappes of Late Cretaceous in age have been proven below the Great Hungarian Plain (Grow et al 1994). The boundary of the two main terrains, the northwestern ALCAPA (Alpine-Carpathian-Pannonian) and the southeastern TISZA, is the Mid-Hungarian Mobile Belt. It is the most significant neotectonic zone of the Pannonian Basin. The structural analysis of the middle section of the Mid-Hungarian Mobile Belt was carried out on a 120km x 50km area, between the Danube and the Tisza river, on the basis of interpretation of seismic data. The structural analysis of the Neogene-Quaternary sediments was supported by sequence stratigraphic interpretation of seismic, well log and core-sample data. Regional seismic profiles were both oriented in the dip direction, which highlights sediment supply routes into the basin, and strike-oriented. The studied segment of the Mid-Hungarian Mobile Belt consists of several long (some ten kilometres long) strike slip fault zones. The offset lengths of the individual strike slipe faults varies between a few and a dozens of kilometres. Activity along the Mid-Hungarian Mobile Belt can be characterised by four periods, the size and shape of facies zones of each development period were controlled by tectonics: 1. During the early Miocene, the ALPACA moved eastward, bounded by sinistral strike-slipe system along its northern side and dextral strike-slipe fault system along its contact with the Southern Alps and the TISZA terrain. The largest movement took part during the Ottnangian-Karpatian (19-16.5 Ma). The TISZA unit moved northeastward over the remnant Carpathian Flysch Basin (Nemcok et al 2006). These terrains movements resulted in right lateral, convergent wide wrench along the Mid-Hungarian Mobile Belt. The ALPACA

  11. The geologic records of dust in the Quaternary

    Science.gov (United States)

    Muhs, Daniel R.

    2013-06-01

    Study of geologic records of dust composition, sources and deposition rates is important for understanding the role of dust in the overall planetary radiation balance, fertilization of organisms in the world's oceans, nutrient additions to the terrestrial biosphere and soils, and for paleoclimatic reconstructions. Both glacial and non-glacial processes produce fine-grained particles that can be transported by the wind. Geologic records of dust flux occur in a number of depositional archives for sediments: (1) loess deposits; (2) lake sediments; (3) soils; (4) deep-ocean basins; and (5) ice sheets and smaller glaciers. These archives have several characteristics that make them highly suitable for understanding the dynamics of dust entrainment, transport, and deposition. First, they are often distributed over wide geographic areas, which permits reconstruction of spatial variation of dust flux. Second, a number of dating methods can be applied to sediment archives, which allows identification of specific periods of greater or lesser dust flux. Third, aeolian sediment particle size and composition can be determined so that dust source areas can be ascertained and dust transport pathways can be reconstructed. Over much of the Earth's surface, dust deposition rates were greater during the last glacial period than during the present interglacial period. A dustier Earth during glacial periods is likely due to increased source areas, greater aridity, less vegetation, lower soil moisture, possibly stronger winds, a decreased intensity of the hydrologic cycle, and greater production of dust-sized particles from expanded ice sheets and glaciers.

  12. Inverse periodic shadowing properties

    CERN Document Server

    Osipov, Alexey V

    2011-01-01

    We consider inverse periodic shadowing properties of discrete dynamical systems generated by diffeomorphisms of closed smooth manifolds. We show that the $C^1$-interior of the set of all diffeomorphisms having so-called inverse periodic shadowing property coincides with the set of $\\Omega$-stable diffeomorphisms. The equivalence of Lipschitz inverse periodic shadowing property and hyperbolicity of the closure of all periodic points is proved. Besides, we prove that the set of all diffeomorphisms that have Lipschitz inverse periodic shadowing property and whose periodic points are dense in the nonwandering set coincides with the set of Axiom A diffeomorphisms.

  13. Late Quaternary vegetation history of Rough Canyon, south-central New Mexico, USA

    Science.gov (United States)

    Betancourt, J.L.; Rylander, Kate Aasen; Penalba, C.; McVickar, J.L.

    2001-01-01

    South-central New Mexico, USA, at the junction of the Rocky Mountains, High Plains and Chihuahuan Desert, is one of the better known regions in the late Quaternary of North America. Plant macrofossils and pollen from a packrat midden series in Rough Canyon, New Mexico allows refinement of plant distributions and paleoclimates in this transitional area since full glacial times. From 17 000 to 12 000 14C yr BP, Pinus edulis–Juniperus scopulorum woodlands dominated limestone substrates between 1800 and 1490 m, with Pseudotsugamenziesii and other mixed-conifer species restricted to shady, north-facing slopes. Juniperus deppeana, the dominant juniper today above 2000 m in southern New Mexico, is conspicuously absent from glacial middens and must have been displaced south of the US–Mexico border. The minimum climatic conditions for P. edulis–J. scopulorum woodlands are ca 20% wetter and 3.5–5°C cooler (July mean maximum temperatures) than the modern climate at Rough Canyon. Holocene warming/drying may have started as early as 12 000 14C yr BP with the extirpation of J. scopulorum from Rough Canyon, and was completed by at least 10 54014C yr BP. The record for arrivals of some desert species is confounded by traces of pollen and macrofossils in some of the glacial middens, which could signify either earliest occurrence or temporal mixing (contamination) of assemblages. AMS 14C dating can discriminate between early arrival and contamination in midden macrofossils but not in pollen. AMS dates show that Choisya dumosa, presently near its northern (cold) limits at Rough Canyon, endured late glacial winters, possibly as clonal populations. Some Larrea tridentata leaves and pollen occur in middens dominated by conifers and oaks no longer at the site; an AMS date of 3205 14C yr BP on Larrea leaves from one midden indicates contamination. Evidence for some macrofossil contamination, however, does not rule out the possibility that pollen of desert

  14. Provenance of the Quaternary Southern Kalahari sediments: A wetland that became dry

    Science.gov (United States)

    Vainer, Shlomy; Erel, Yigal; Matmon, Ari

    2017-04-01

    The ca. 140 Ma vast Kalahari basin is characterized by uplifted margins, terrestrial sedimentation within semi endorheic sub-basins, subdued morphology and tectonic quiescence. This intracratonic basin has been subjected to a prolonged period of subsidence affecting its sedimentary fill by changing plate motion and climatic cycles. Provenance studies of Kalahari Group sediments mainly focused on the easily accessible uppermost part that represents only the last phase of sedimentation, leaving unresolved questions for the rest of the strata. The Southern Kalahari Group succession exposed along the walls of the Mamatwan Mine, Northern Cape, South Africa, reveals three main depositional environments; a bottom pluvial, low-energy water body, a middle fluvial, high-energy environment and an upper aeolian sandy unit. The entire section, which was deposited within the Quaternary, records significant environmental and depositional changes suggesting a highly dynamic landscape. The fully exposed section (55 m) of the Kalahari Group at Mamatwan Mine was analysed for its mineralogy, elemental composition, Sr, Nd and Pb isotopic ratios and iron species. Mineralogical assemblage imply that a saline and alkaline shallow water-body existed during the early-middle Pleistocene contemporaneous with relative dense hominine occupation of the area. Isotopic ratios were used to determine the source of the sediments, which was found to be mainly of mafic rocks located to the north-east of Mamatwan. Weathering sensitive indices of both elemental ratios and iron phases show that sediments carried to the basin underwent considerable weathering indicative to a greater availability of surface water than the present. The lacustrine environment was rapidly filled with clasts that were derived mainly from the surrounding hills and experienced limited degree of chemical weathering during transport, but underwent subsequent groundwater alteration by iron-rich solution and precipitation of celcrete

  15. Siliceous microfossils as late Quaternary paleo-environmental indicators at Braamhoek wetland, South Africa

    Science.gov (United States)

    Finné, M.; Norström, E.; Risberg, J.; Scott, L.

    2009-04-01

    phytolith indices (Iph and Ic) interpreted as indicators of climatic change, show periods of increased wetness and possibly minor temperature fluctuations during the late Quaternary. The fossil diatom record infer changes in past moisture conditions. Unlike the modern wetland, which is dominated by benthic and aerophilic diatoms, the late Pleistocene-early Holocene wetland favoured growth of planktonic species requiring deeper water. Abundance of planktonic diatoms suggests three main phases of greater water depth than today at c.13.6 ka, 11.3 ka and 10.4-10.0 ka. As part of a multi-proxy comparison, siliceous microfossil indications of past fluctuations in humidity in the Braamhoek wetland generally accord with the results from previous studies of pollen, charcoal fragments and stable isotopes in the same core.

  16. GC estimation of organic hydrocarbons that threaten shallow Quaternary sandy aquifer Northwestern Gulf of Suez, Egypt.

    Science.gov (United States)

    Zawrah, M F; Ebiad, M A; Rashad, A M; El-Sayed, E; Snousy, Moustafa Gamal; Tantawy, M A

    2014-11-01

    Soil and groundwater contamination is one of the important environmental problems at petroleum-related sites, which causes critical environmental and health defects. Severe petroleum hydrocarbon contamination from coastal refinery plant was detected in a shallow Quaternary sandy aquifer is bordered by Gulf in the Northwestern Gulf of Suez, Egypt. The overall objective of this investigation is to estimate the organic hydrocarbons in shallow sandy aquifers, released from continuous major point-source of pollution over a long period of time (91 years ago). This oil refinery contamination resulted mainly in the improper disposal of hydrocarbons and produced water releases caused by equipment failures, vandalism, and accidents that caused direct groundwater pollution or discharge into the gulf. In order to determine the fate of hydrocarbons, detailed field investigations were made to provide intensive deep profile information. Eight composite randomly sediment samples from a test plot were selected for demonstration. The tested plot was 50 m long × 50 m wide × 70 cm deep. Sediment samples were collected using an American auger around the point 29° 57' 33″ N and 32° 30' 40″ E in 2012 and covered an area of 2,500 m(2) which represents nearly 1/15 of total plant area (the total area of the plant is approximately 3.250 km(2)). The detected total petroleum hydrocarbons (TPHs) were 2.44, 2.62, 4.54, 4.78, 2.83, 3.22, 2.56, and 3.13 wt%, respectively. TPH was calculated by differences in weight and subjected to gas chromatography (GC). Hydrocarbons were analyzed on Hewlett-Packard (HP-7890 plus) gas chromatograph equipped with a flame ionization detector (FID). The percentage of paraffine of the investigated TPH samples was 7.33, 7.24, 7.58, 8.25, 10.25, 9.89, 14.77, and 17.53 wt%, respectively.

  17. Detrital cave sediments record Late Quaternary hydrologic and climatic variability in northwestern Florida, USA

    Science.gov (United States)

    Winkler, Tyler S.; van Hengstum, Peter J.; Horgan, Meghan C.; Donnelly, Jeffrey P.; Reibenspies, Joseph H.

    2016-04-01

    Detrital sediment in Florida's (USA) submerged cave systems may preserve records of regional climate and hydrologic variability. However, the basic sedimentology, mineralogy, stratigraphic variability, and emplacement history of the successions in Florida's submerged caves remains poorly understood. Here we present stratigraphic, mineralogical, and elemental data on sediment cores from two phreatic cave systems in northwestern Florida (USA), on the Dougherty Karst Plain: Hole in the Wall Cave (HITW) and Twin Cave. Water flowing through these caves is subsurface flow in the Apalachicola River drainage basin, and the caves are located just downstream from Jackson Blue (1st magnitude spring, > 2.8 m3 s- 1 discharge). Sedimentation in these caves is dominated by three primary sedimentary styles: (i) ferromanganese deposits dominate the basal recovered stratigraphy, which pass upsection into (ii) poorly sorted carbonate sediment, and finally into (iii) fine-grained organic matter (gyttja) deposits. Resolving the emplacement history of the lower stratigraphic units was hampered by a lack of suitable material for radiocarbon dating, but the upper organic-rich deposits have a punctuated depositional history beginning in the earliest Holocene. For example, gyttja primarily accumulated in HITW and Twin Caves from ~ 5500 to 3500 cal yr. BP, which coincides with regional evidence for water-table rise of the Upper Floridian Aquifer associated with relative sea-level rise in the Gulf of Mexico, and evidence for invigorated drainage through the Apalachicola River drainage basin. Gyttja sediments were also deposited in one of the caves during the Bølling/Allerød climate oscillation. Biologically, these results indicate that some Floridian aquatic cave (stygobitic) ecosystems presently receive minimal organic matter supply in comparison to prehistoric intervals. The pre-Holocene poorly sorted carbonate sediment contains abundant invertebrate fossils, and likely documents a period

  18. Your First Period

    Science.gov (United States)

    ... Events Advocacy For Patients About ACOG Your First Period (Especially for Teens) Home For Patients Search FAQs ... Teens) FAQ049, May 2015 PDF Format Your First Period (Especially for Teens) Especially For Teens What is ...

  19. Middle Helladic Period

    DEFF Research Database (Denmark)

    Sarri, Kalliopi

    1999-01-01

    The Middle Bronze Age on Mainland Greece is also known as the Middle Helladic period. The chronological framework of this period extends from the beginnings of the second millenium - roughly 1900 - until 1550 BC, that is until the beginnings of the Mycenaean period. The Middle Helladic period...... is considered as the dark period of the cultural decline. The remains of the material culture reveal a clear retrogression while the information available on the social stratification and economy are so few and problematic in interpretation that this period is considered as the "Middle Age of Greek Prehistory......". About 1900 BC, the period during which the first palaces of Crete were being built, Mainland Greece was entering a long period of decline during which economic features changed radically. A large number of metals and imported products became particularly rare while composite forms of economic...

  20. ON PERIODIC DYNAMICAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    LU WENLIAN; CHEN TIANPING

    2004-01-01

    The authors investigate the existence and the global stability of periodic solution for dynamical systems with periodic interconnections, inputs and self-inhibitions. The model is very general, the conditions are quite weak and the results obtained are universal.

  1. Community College Periodicals.

    Science.gov (United States)

    Pederson, Eldor O.

    Drawing from an examination of community college periodicals, their availability and characteristics, the academic affiliations of contributing authors, and the topics of their articles, this paper discusses the minor role which community college periodicals appear to play. A list of 35 periodicals dealing primary with community college education…

  2. Few period quasisymmetric stellarators

    Energy Technology Data Exchange (ETDEWEB)

    Isaev, M.Y.; Mikhailov, M.I.; Shafranov, V.D.; Subbotin, A.A. [Russian Research Centre `Kurchatov Institute`, Moscow (Russian Federation); Cooper, W.A. [Ecole Polytechnique Federale, Lausanne (Switzerland). Centre de Recherche en Physique des Plasma (CRPP); Medvedev, S.Y. [Keldysh Inst. of Applied Mathematics, Russian Academy of Sciences, Moscow (Russian Federation)

    1997-06-01

    The results of plasma equilibrium and local stability investigations in two and four-period quasisymmetric stellarators are presented. A near-axis approximation is used for 2-period systems and the 3D codes VMEC and TERPSICHORE are used for four-periods devices to optimise the configurations. (author) 4 figs., 8 refs.

  3. The Periodic Pyramid

    Science.gov (United States)

    Hennigan, Jennifer N.; Grubbs, W. Tandy

    2013-01-01

    The chemical elements present in the modern periodic table are arranged in terms of atomic numbers and chemical periodicity. Periodicity arises from quantum mechanical limitations on how many electrons can occupy various shells and subshells of an atom. The shell model of the atom predicts that a maximum of 2, 8, 18, and 32 electrons can occupy…

  4. The contributions of Donald Lee Johnson to understanding the Quaternary geologic and biogeographic history of the California Channel Islands

    Science.gov (United States)

    Muhs, Daniel R.

    2013-01-01

    Over a span of 50 years, native Californian Donald Lee Johnson made a number of memorable contributions to our understanding of the California Channel Islands. Among these are (1) recognizing that carbonate dunes, often cemented into eolianite and derived from offshore shelf sediments during lowered sea level, are markers of glacial periods on the Channel Islands; (2) identifying beach rock on the Channel Islands as the northernmost occurrence of this feature on the Pacific Coast of North America; (3) recognizing of the role of human activities in historic landscape modification; (4) identifying both the biogenic and pedogenic origins of caliche “ghost forests” and laminar calcrete forms on the Channel Islands; (5) providing the first soil maps of several of the islands, showing diverse pathways of pedogenesis; (6) pointing out the importance of fire in Quaternary landscape history on the Channel Islands, based on detailed stratigraphic studies; and (7), perhaps his greatest contribution, clarifying the origin of Pleistocene pygmy mammoths on the Channel Islands, due not to imagined ancient land bridges, but rather the superb swimming abilities of proboscideans combined with lowered sea level, favorable paleowinds, and an attractive paleovegetation on the Channel Islands. Don was a classic natural historian in the great tradition of Charles Darwin and George Gaylord Simpson, his role models. Don’s work will remain important and useful for many years and is an inspiration to those researching the California Channel Islands today.

  5. Climate warming and humans played different roles in triggering Late Quaternary extinctions in east and west Eurasia.

    Science.gov (United States)

    Wan, Xinru; Zhang, Zhibin

    2017-03-29

    Climate change and humans are proposed as the two key drivers of total extinction of many large mammals in the Late Pleistocene and Early Holocene, but disentangling their relative roles remains challenging owing to a lack of quantitative evaluation of human impact and climate-driven distribution changes on the extinctions of these large mammals in a continuous temporal-spatial dimension. Here, our analyses showed that temperature change had significant effects on mammoth (genus Mammuthus), rhinoceros (Rhinocerotidae), horse (Equidae) and deer (Cervidae). Rapid global warming was the predominant factor driving the total extinction of mammoths and rhinos in frigid zones from the Late Pleistocene and Early Holocene. Humans showed significant, negative effects on extirpations of the four mammalian taxa, and were the predominant factor causing the extinction or major extirpations of rhinos and horses. Deer survived both rapid climate warming and extensive human impacts. Our study indicates that both the current rates of warming and range shifts of species are much faster than those from the Late Pleistocene to Holocene. Our results provide new insight into the extinction of Late Quaternary megafauna by demonstrating taxon-, period- and region-specific differences in extinction drivers of climate change and human disturbances, and some implications about the extinction risk of animals by recent and ongoing climate warming.

  6. Quaternary sea level high-stand deposits of the southeast U.S. Atlantic Coastal Plain: Age, distribution, and implications.

    Science.gov (United States)

    Poirier, R. K.; Cronin, T. M.; Ghaleb, B.; Portell, R.; Hillaire-Marcel, C.; Wehmiller, J. F.; Thompson, W. G.; Oches, E. A.; Willard, D. A.; Katz, M. E.

    2015-12-01

    Emerged Quaternary paleo-shorelines and marine deposits provide a more direct way to reconstruct and analyze sea-level variability than methods using oxygen isotope analyses of deep ocean benthic foraminifera. New Uranium-series dates on fossil corals (primarily Astrangia spp. and Septastrea spp.) combined with previously published dates have allowed us to constrain the age, elevation, and geographical distribution of marine sediments deposited in the United States Atlantic Coastal Plain (ACP) from Virginia to Florida during periods of past high relative sea level (SL). We present new dates from deposits (VA/NC: Tabb/Norfolk, Nassawadox, & Omar Formations; SC: Wando, Socastee, & Canepatch Formations; FL: Anastasia, Ft. Thompson, & Bermont Formations) representing interglacial high-stands during Marine Isotope Stages (MIS) 5, 7, 9, and 11. In addition, we incorporate stratigraphic, marine micropaleontologic, and palynologic records with our SL chronology to reconstruct a more complete history of middle-to-late Pleistocene interglacial climates of the ACP. Ultimately, these results will test modeled sea-level fingerprint studies based on various melting scenarios of the Greenland and/or Antarctic ice sheets.

  7. Differences in Late Quaternary primary productivity between the western tropical Pacific and the South China Sea: Evidence from coccoliths

    Science.gov (United States)

    Su, Xiang; Liu, Chuanlian; Beaufort, Luc; Barbarin, Nicolas; Jian, Zhimin

    2015-12-01

    Changes in Late Quaternary oceanic primary productivity in the western tropical Pacific were reconstructed using coccolith counts from the improved SYRACO system in piston core MD01-2386 retrieved from the Halmahera Sea near northwest New Guinea. The calculated primary productivity exhibits cycles on obliquity and precession timescales over the last 192 ka. There are marked differences between primary productivity records from the western tropical Pacific and the South China Sea (SCS), with the former being dominated by precession, and the latter showing all three Milankovitch cycles (eccentricity, obliquity and precession). Empirical Orthogonal Function (EOF) analyses reveal two significant EOF modes in the western tropical Pacific and SCS records. EOF-1 accounts for 38% of the total variance and exhibits obvious precessional cycles corresponding to Northern Hemisphere summer insolation, while EOF-2 accounts for 22% of the total variance and exhibits strong 41-kyr periodicity, suggesting different biological responses to hydroclimate changes in the two regions. A more complex hydroclimate regime influenced by the East Asian monsoon and the large contrast in regional topography and circulation during glacial cycles are considered to be the primary drivers of the stronger temporal variability in productivity in the SCS compared to the relatively stable western tropical Pacific.

  8. Munroa argentina, a Grass of the South American Transition Zone, Survived the Andean Uplift, Aridification and Glaciations of the Quaternary

    Science.gov (United States)

    Amarilla, Leonardo D.; Anton, Ana M.; Chiapella, Jorge O.; Manifesto, María M.; Angulo, Diego F.; Sosa, Victoria

    2015-01-01

    The South American Transition Zone (SATZ) is a biogeographic area in which not only orogeny (Andes uplift) and climate events (aridification) since the mid-Miocene, but also Quaternary glaciation cycles had an important impact on the evolutionary history of the local flora. To study this effect, we selected Munroa argentina, an annual grass distributed in the biogeographic provinces of Puna, Prepuna and Monte. We collected 152 individuals from 20 localities throughout the species’ range, ran genetic and demographic analyses, and applied ecological niche modeling. Phylogenetic and population genetic analyses based on cpDNA and AFLP data identified three phylogroups that correspond to the previously identified subregions within the SATZ. Molecular dating suggests that M. argentina has inhabited the SATZ since approximately 3.4 (4.2–1.2) Ma and paleomodels predict suitable climate in these areas during the Interglacial period and the Last Glacial Maximum. We conclude that the current distribution of M. argentina resulted from the fragmentation of its once continuous range and that climate oscillations promoted ecological differences that favored isolation by creating habitat discontinuity. PMID:26110533

  9. Geological Age of Quaternary Series in Lianjiang Plain%练江平原第四系的时代

    Institute of Scientific and Technical Information of China (English)

    宋毅盛; 陈文彬; 潘华; 张志中; 何振勤; 程小久; 曾强; 佘奕平; 张俊杰

    2012-01-01

    基于钻孔柱状图将练江平原区第四系划分为9个基本层,通过对WYZK-06孔岩心的系统测年,标定了第四系的年代.第四系底部地层时代为中更新世,厚度约40m,为陆相沉积.中更新统底部地质年龄为(325±32) ka,属中更新世中晚期;顶部为一套厚达1o cm左右的稳定花斑黏土层.上覆地层为上更新统,反映中更新世与晚更新世之间有较长时间的沉积间断.中更新统分布局限于普宁一两英之间,上更新统和全新统占据平原的大部分地区,表明练江平原是在中更新世发生局部断陷,在晚更新世以来开始接受大面积沉积.%Nine basic layers was divided based on the drill histogram, and the period of Quaternary was calibrated by the rock core of WYZK-06 drill. The age of bottom of the Quaternary was middle Pleistocene, with the thickness of about 40 m of continental sedimentary. The geological age of the under part of the basin is (325 ±32) ka B. P. , belonging to Medio-Pleistocene. The top part of Medio-Pleistocene series is 10 em's stable mottle clay, which reflects there was a long sedimentary interruption between Medio-Pleistocene and Epipleistocene. Medio-Pleistocene series only distributes along Puning - Laangying and larger part of the basin is occupied by Epipleistocene series and Holocene series, which shows that partly fault-depression starts in Medio-Pleistocene and sediments develop in large scale since Epipleistocene.

  10. Reflection seismic investigations of the Beaufort Sea margin, Arctic Ocean: Variable history of Quaternary ice-sheet advance

    Science.gov (United States)

    Batchelor, Christine; Dowdeswell, Julian; Pietras, Jeffrey

    2013-04-01

    The seismic stratigraphy and sedimentary architecture of the formerly-glaciated Beaufort Sea shelf and adjacent slope are investigated using a comprehensive grid of high-resolution 2-D seismic reflection data collected by ION Geophysical Corporation as part of the BeaufortSPAN East survey. Three cross-shelf troughs, representing locations of former ice streams draining a 1000 km-long section of the Laurentide Ice Sheet are examined; the Mackenzie, Amundsen Gulf and M'Clure Strait systems. These palaeo-ice streams operated during the last, Late Wisconsinan, glacial maximum and a hitherto unknown number of earlier glacial periods. Their dynamics influenced past ice-sheet configuration and may have forced abrupt climate change through transport of ice and freshwater to the Arctic Ocean. The objectives of this work are to constrain the number of ice advances through each trough, to discuss the possible timing of these events, and to examine the impact of Quaternary glaciation on the continental shelf and adjacent slope. The number of cycles of ice-sheet growth and decay varies markedly between the Mackenzie Trough on the western Beaufort Sea margin, with only two recorded events, and the Amundsen Gulf Trough to the east, with at least nine. The Mackenzie Trough was probably occupied by an ice stream during the Late Wisconsinan and either the Illinoian or Early Wisconsinan glaciation. The Amundsen Gulf ice stream was initiated earlier in the Quaternary, suggesting that the onset of cross-shelf glaciation on the eastern Beaufort Sea margin occurred significantly prior to initial glaciation of Mackenzie Trough to the west. Whereas the continental slope beyond the Mackenzie Trough lacks a significant glacial-sedimentary depocentre, major trough-mouth fans (of volumes ~10,000 km³ and ~60,000 km³) are present beyond the Amundsen Gulf and M'Clure Strait, respectively. A number of buried glacigenic landforms, including grounding-zone wedges and lateral moraines, are

  11. Along-strike Deformation in Quaternary Valleys of Tropical NW Borneo: Implications for Active Tectonics, Seismicity and Geomorphology

    Science.gov (United States)

    Sautter, B.; Mathew, M. J.; Menier, D.; Pubellier, M. F.; Sapin, F.; Siddiqui, N.

    2015-12-01

    In the wee hours of 5th June, 2015, NW Borneo was jolted by a 6.0 magnitude earthquake, caused by fault movement at a shallow depth of 10 km. The quake that originated from near the foot of the picturesque Mount Kinabalu, Sabah, was felt as far as 350 km away from the epicentre and has produced more than 90 aftershocks to date; ranging in magnitudes from 1.6 to 5.2. Although the geologically complex NW Borneo has experienced more than 60 mainshocks and numerous aftershocks since 1970 to present; research pertaining to active tectonics, morphotectonics analysis and subsequent geomorphic response to resulting transient dynamic topography remains inadequate.Here, we show evidences of active tectonics in tropical Sabah, NW Borneo, using morphometric indices, geomorphic indicators and report our results of morphotectonic analysis and consequent feedback of landscape and topography. Results from stream length gradient index, normalized channel steepness index and spatial distribution of hypsometric integral showed evidences of fault rejuvenation during Quaternary and recent periods. River longitudinal profiles showed the presence of several knickpoints indicating fault reactivations as the study area lacks lithological contrasts and similar climatic conditions along the channel reach. Field survey revealed the presence of highly elevated Quaternary fluvial terraces illustrating recent and important tectonic uplift rates in the trend of the exhumation rates calculated on Mt. Kinabalu by means of thermochronology. The uplifted terraces show a positive correlation with geomorphic analysis along the main valleys and other areas of active tectonics. Our analysis show the competition between important uplifts related to the dynamics of the NW Borneo Wedge and active normal faulting. These faults are in trend to the major earthquakes that occurred recently in this area, which have a normal faulting mechanism. The cause of the mechanism for recent tectonism and/or decoupling

  12. Climatically controlled increase in Quaternary erosion rates: An exploration of real and perceived biases from thermochronology data

    Science.gov (United States)

    van der Beek, Peter; Schildgen, Taylor

    2017-04-01

    The potential increase of erosion rates over the last few million years in response to climate change and Quaternary glaciations remains controversial. Such an increase was initially inferred from the sedimentary record, but several authors have argued that this record is biased due to unresolved erosional hiatuses, and therefore the inferred increase in sedimentation rates is an artefact. More recently, the discussion has focused on erosional records from the source areas themselves; in particular records extracted from low-temperature thermochronology data. A global compilation of such data appears to show increasing erosion rates toward the present, but it has been argued that this increase may also be an artefact, for similar reasons that affect the sedimentary record. Here we assess real and perceived biases in the thermochronological record that might affect the inference of temporal variations in erosion rates from such data. We argue that it is unlikely that erosional hiatuses affect thermochronology data because the temporal and spatial scales at which such hiatuses might occur are significantly smaller than those that are resolved by the data. Instead, we explore the potential bias introduced by the erosional response time of thermochronological systems (defined as the time required to exhume rocks that are fully reset for the thermochronological system considered, i.e. to attain exhumational steady state). These response times are typically longer than the timescale of Quaternary glacial-interglacial cycles, implying that thermochronological systems are insensitive to such variations. For thermochronological data to record an overall increase in erosion rates, the increase must occur over longer time periods, independent of superimposed shorter-term variations. However, because the erosional response times depend strongly on the final exhumation rate, it is much easier to detect increases in erosion rates with thermochronological data than to detect

  13. Quaternary colluvial episodes (Upper Paraná River Hydrographic Basin, Brazil

    Directory of Open Access Journals (Sweden)

    Alethea E.M. Sallun

    2010-09-01

    Full Text Available Colluvial deposits occur extensively in the Upper Paraná River Hydrographic Basin (UPRHB in Southeastern,Southern, and Western central Brazil. These deposits were recognized as an allostratigraphic unit and related to creeping during the Quaternary. Every studied colluvial profile is homogeneous, which indicates relatively long periods of landscape stability that is sufficient for the development of a thick soil cover. The deposits were dated by luminescence and indicate periods of more intense colluvial deposition between 6 and 220 ky B.P. These events correspond approximately to the transitions between the oxygen isotope stages 2-3-4 and 5-6, suggesting that this aggradation was influenced by climatic changes. However, the most important alluviation episode was tentatively correlated with the Middle to Upper Pleniglacial of the Wisconsin glaciation. The most intensive and frequent periods of precipitation that occurred during climate transitions are probably correlated with aggradation events. The regularity of the colluvial deposits suggests continuous uplift accompanied by sediment deposition throughout the UPRHB due to neotectonic activity during the last million years.Depósitos coluviais ocorrem extensivamente na Bacia Hidrográfica do Alto Rio Paraná, no sudeste, sul e centro-oeste do Brasil. Esses depósitos foram reconhecidos como uma unidade aloestratigráfica, e são interpretados como depósitos formados por processos de rastejo durante o Quaternário. Cada perfil coluvial estudado é muito homogêneo, e indica relativamente períodos longos de estabilidade da paisagem, suficiente para desenvolvimento de espessa cobertura. Estes depósitos foram datados por luminescência para estabelecer cronologicamente períodos de deposição coluvial mais intensa entre 6 e 220 ky B.P. Estes eventos correspondem aproximadamente às transições entre os estágios de isótopos do oxigênio 2-3-4 e 5-6, sugerindo que essa agradação esteve

  14. Clay minerals as palaeomonsoon proxies: Evaluation and relevance to the late Quaternary records from SE Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Thamban, M.; Rao, V.P.

    as palaeoclimatic proxies are evaluated and discussed. Systematic investigations using several sediment cores from the SE Arabian Sea reveal that despite the influence of several complicating factors, variations in clay mineral composition during the late Quaternary...

  15. The quaternary lidocaine derivative, QX-314, exerts biphasic effects on transient receptor potential vanilloid subtype 1 channels in vitro

    DEFF Research Database (Denmark)

    Rivera-Acevedo, Ricardo E; Pless, Stephan Alexander; Ahern, Christopher A;

    2011-01-01

    BACKGROUND: Transient receptor potential vanilloid subfamily member 1 (TRPV1) channels are important integrators of noxious stimuli with pronounced expression in nociceptive neurons. The experimental local anesthetic, QX-314, a quaternary (i.e., permanently charged) lidocaine derivative, recently...

  16. Radiocarbon chronologies and extinction dynamics of the Late Quaternary mammalian megafauna of the Taimyr Peninsula, Russian Federation

    NARCIS (Netherlands)

    MacPhee, RDE; Tikhonov, AN; Mol, D; Maliave, CD; Van der Plicht, H; Greenwood, AD; Flemming, C; Agenbroad, L; MacPhee, Ross D.E.; Tikhonov, Alexei N.; Marliave, Christian de; Greenwood, Alex D.

    2002-01-01

    This paper presents 75 new radiocarbon dates based on late Quaternary mammal remains recovered from eastern Taimyr Peninsula and adjacent parts of the northern Siberian lowlands, Russian Federation, including specimens of woolly mammoth (Mammuthus primigenius), steppe bison (Bison priscus), muskox (

  17. Cretaceous to Quaternary Siliciclastic Sediments of the Tarfaya Basin, Marginal Atlantic, SW Morocco Petrography, Geochemistry, Provenance, Climate and Weathering

    OpenAIRE

    Ali, Sajid

    2012-01-01

    This dissertation is prepared to attain the doctorate under the title "Cretaceous to Quaternary Siliciclastic Sediments of the Tarfaya Basin, Marginal Atlantic, SW Morocco Petrography, Geochemistry, Provenance, Climate and Weathering".

  18. Ground-water quality in quaternary deposits of the central high plains aquifer, south-central Kansas, 1999

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Water samples from 20 randomly selected domestic water-supply wells completed in the Quaternary deposits of south-central Kansas were collected as part of the High...

  19. Microstructure and mechanical properties of Al3Ti-based alloys in Al-Ti-Mo-X quaternary systems

    Institute of Scientific and Technical Information of China (English)

    Seiji Miura; Tetsuo Mohri

    2003-01-01

    A part of Al -Ti-Mo-Cr quaternary phase diagram is constructed for the microstructure control of D022-Al3Ti or its derivative, LI2-(Al,Cr)3Ti, -based alloys. It was found that quaternary bce phase equilibrates with either DO222-A13Ti or L12-(Al,Cr)3Ti, orboth, exist in large compositional areas. The mechanical properties is strongly affected by precipitates appearing, and presumablyalloy microstructures.

  20. SN2-type ring opening of substituted--tosylaziridines with zinc (II) halides: Control of racemization by quaternary ammonium salt

    Indian Academy of Sciences (India)

    Manas K Ghorai; Deo Prakash Tiwari; Amit Kumar; Kalpataru Das

    2011-11-01

    Quaternary ammonium salt mediated highly regioselective ring opening of aziridines with zinc(II) halides to racemic and non-racemic -halo amines in excellent yield and selectivity is described. The reaction proceeds via an SN2-type pathway and the partial racemization of the starting substrate and the product was effectively controlled by using quaternary ammonium salts to afford the enantioenriched products (er up to 95:5).

  1. The Establishment of Quaternary Stratum Comprehensive Profiles in Shenzhen Region%深圳市第四纪地层综合剖面的建立

    Institute of Scientific and Technical Information of China (English)

    徐俊; 肖兵; 余成华; 张桂香; 蒋鹏; 邓文龙; 陈庞龙

    2011-01-01

    通过沿深圳主干断裂分布的4个控制性钻孔探测,结合大量资料的综合研究,从岩石地层、生物地层、气候地层、年代地层等方面,详细剖析深圳地区的地层特征,建立了深圳市第四纪地层综合剖面。%Based on the four controlled boreholes located on main faults of Shenzhen region,combined with the research on large amounts of data,the stratum characteristics of Shenzhen region,such as rock stratum、organism stratum、climate stratum、period stratum,are analyzed in detail,The quaternary stratum comprehensive profiles are established in this paper.

  2. Dating of the late Quaternary volcanic events using Uranium-series technique on travertine deposit: A case study in Ihlara, Central Anatolia Volcanic Province

    Science.gov (United States)

    Karabacak, Volkan; Tonguç Uysal, İ.; Ünal-İmer, Ezgi

    2016-04-01

    Dating of late Quaternary volcanism is crucial to understanding of the recent mechanism of crustal deformation and future volcanic explosivity risk of the region. However, radiometric dating of volcanic products has been a major challenge because of high methodological error rate. In most cases, there are difficulties on discrimination of the volcanic lava flow relations in the field. Furthermore, there would be unrecorded and unpreserved volcanoclastic layers by depositional and erosional processes. We present a new method that allows precise dating of late Quaternary volcanic events (in the time range of 0-500,000 years before present) using the Uranium-series technique on travertine mass, which is thought to be controlled by the young volcanism. Since the high pressure CO2 in the spring waters are mobilized during crustal strain cycles and the carbonates are precipitated in the fissures act as conduit for hot springs, thus, travertine deposits provide important information about crustal deformation. In this study we studied Ihlara fissure ridge travertines in the Central Anatolia Volcanic Province. This region is surrounded by many eruption centers (i.e. Hasandaǧı, Acıgöl and Göllüdaǧı) known as the late Quaternary and their widespread volcanoclastic products. Recent studies have suggested at least 11 events at around Acıgöl Caldera for the last 180 ka and 2 events at Hasandaǧı Stratovolcano for the last 30 ka. Active travertine masses around Ihlara deposited from hotwaters, which rise up through deep-penetrated fissures in volcanoclastic products of surrounding volcanoes. Analyses of the joint systems indicate that these vein structures are controlled by the crustal deformation due to young volcanism in the vicinity. Thus, the geological history of Ihlara travertine mass is regarded as a record of surrounding young volcanism. We dated 9 samples from 5 ridge-type travertine masses around Ihlara region. The age distribution indicates that the crustal

  3. New insights into the earliest Quaternary environments in the Central North Sea from 3D seismic

    Science.gov (United States)

    Lamb, Rachel; Huuse, Mads; Stewart, Margaret; Brocklehurst, Simon H.

    2014-05-01

    In the past the transition between an unconformable surface in the south to a conformable horizon towards the north has made identification and mapping the base-Quaternary in the central North Sea difficult (Sejrup et al 1991; Gatliff et al 1994). However recent integration of biostratigraphy, pollen analysis, paleomagnetism and amino acid analysis in the Dutch and Danish sectors (Rasmussen et al 2005; Kuhlmann et al 2006) has allowed greater confidence in the correlation to the region 3D seismic datasets and thus has allowed the base-Quaternary to be mapped across the entire basin. The base-Quaternary has been mapped using the PGS MegaSurvey dataset from wells in the Danish Sector along the initially unconformable horizon and down the delta front into the more conformable basin giving a high degree of confidence in the horizon pick. The revised base-Quaternary surface reaches a depth of 1248 ms TWT with an elongate basin shape which is significantly deeper than the traditionally mapped surface. Using RMS amplitudes and other seismic attributes the revised base-Quaternary has been investigated along the horizon and in time slice to interpret the environments of the earliest Quaternary prior to the onset of glaciation. Combined with analysis of aligned elongate furrows over 10 km long, 100 m wide and 100 m deep suggest a deep marine environment in an almost enclosed basin with persistent strong NW-SE bottom currents in the deepest parts. Pockmarks were formed by the escape of shallow gas on the sides of a small delta in the eastern part of the basin. The progradation of large deltas from both the north and south into the basin make up the majority of the deposition of sediment into the basin. Key Words: base-Quaternary; seismic interpretation; paleoenvironments References: Gatliff, R.W, Richards, P.C, Smith, K, Graham, C.C, McCormac, M, Smith, N.J.P, Long, D, Cameron, T.D.J, Evans, D, Stevenson, A.G, Bulat, J, Ritchie, J.D, (1994) 'United Kingdom offshore regional

  4. PREPARATION AND PHOTOSENSITIVITY OF WATER SOLUBLE PHENOLIC RESINS CONTAINING ACRYLOYL AND QUATERNARY AMMONIUM CHLORIDE GROUPS

    Institute of Scientific and Technical Information of China (English)

    Xiao-ming Tan; Hong-quan Xie; Nai-yu Huang

    2002-01-01

    New water soluble and photocrosslinkable prepolymers containing acrylate and quaternary ammonium salt groups were synthesized from epoxy phenolic resin via ring-opening reaction with acrylic acid and with aqueous solution of triethylamine hydrochloride successively. The second reaction needs no phase transfer catalyst to accelerate, since the product formed can act as a phase transfer catalyst. The prepolymer obtained contains both photocrosslinkable acrylate groups and hydrophilic quaternary ammonium salt groups. Optimum conditions for these reactions were studied. The photosensitivity of the prepolymer was also investigated. The effects of different photoinitiators, different crosslinkable diluent monomers and amine accelerator on the photosensitivity of the prepolymer were compared. The photoinitiator of hydrogen abstraction type is still effective without using amine or alcohol as accelerator, because the prepolymer contains α H beside the OH groups formed in the ring-opening reactions.

  5. Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

    KAUST Repository

    Behenna, Douglas C.

    2011-12-18

    The enantioselective synthesis of nitrogen-containing heterocycles (N-heterocycles) represents a substantial chemical research effort and resonates across numerous disciplines, including the total synthesis of natural products and medicinal chemistry. In this Article, we describe the highly enantioselective palladium-catalysed decarboxylative allylic alkylation of readily available lactams to form 3,3-disubstituted pyrrolidinones, piperidinones, caprolactams and structurally related lactams. Given the prevalence of quaternary N-heterocycles in biologically active alkaloids and pharmaceutical agents, we envisage that our method will provide a synthetic entry into the de novo asymmetric synthesis of such structures. As an entry for these investigations we demonstrate how the described catalysis affords enantiopure quaternary lactams that intercept synthetic intermediates previously used in the synthesis of the Aspidosperma alkaloids quebrachamine and rhazinilam, but that were previously only available by chiral auxiliary approaches or as racemic mixtures. © 2012 Macmillan Publishers Limited. All rights reserved.

  6. β-CD assisted dissolution of quaternary ammonium permanganates in aqueous medium.

    Science.gov (United States)

    Bank, Suraj Prakash; Guru, Partha Sarathi; Dash, Sukalyan

    2014-10-13

    The non-polar internal cavity of β-cyclodextrin (β-CD) has been exploited for the entrapment of the hydrophobic tails of two water insoluble quaternary ammonium permanganates (QAPs): cetyltrimethylammonium permanganate (CTAP) and tetrabutylammonium permanganate (TBAP), for solubilization in aqueous medium. The solubilization and organizational behavior of the QAPs in aqueous β-CD solution have been determined from the comparison of their rates of self-oxidation in presence and in absence of β-CD. Effect of QAP concentration on their observed rate constants (k(obs)) at a fixed β-CD concentration, phase solubility analysis in varying β-CD concentration, impact of quaternary ammonium bromides (QABs) on the kobs values of CTAP and TBAP at fixed QAP and β-CD concentrations, and the temperature effect have been reported. A scheme to explain the solvation of QAPs in aqueous β-CD has been proposed based on dynamic light scattering (DLS) analysis of the samples.

  7. Synthesis and surface-active property of bis-quaternary ammonium-sodium sulfate Gemini surfactant

    Institute of Scientific and Technical Information of China (English)

    Zhao Qiuling; Gao Zhinong

    2006-01-01

    N,N-dimethyldodecylamine,hydrochloride and epichlorohydrin (molar ration is 2:1:1) were used to synthesize bis-quaternary ammonium Gemini surfactant with a hydroxyl in its spacer group by the one-pot method.This hydroxyl was sulfonated by chlorosulfonic acid and then neutralized to bis-quaternary ammonium-sodium sulfate zwitterionic Gemini surfactant.The yield of the final product was 78%,and the melting point was 231-233℃.Its structure was characterized by IR,1H-NMR,MS,and elemental analyses.The critical micelle concentration (cmc)and surface tension of the novel zwitterionic Gemini surfactant in aqueous solution at 15℃ are 7.2×10-5 mol/L and 34.5 mN/m,respectively.

  8. Ion Mobility-Mass Spectrometry Differentiates Protein Quaternary Structures Formed in Solution and in Electrospray Droplets.

    Science.gov (United States)

    Han, Linjie; Ruotolo, Brandon T

    2015-07-01

    Electrospray ionization coupled to mass spectrometry is a key technology for determining the stoichiometries of multiprotein complexes. Despite highly accurate results for many assemblies, challenging samples can generate signals for artifact protein-protein binding born of the crowding forces present within drying electrospray droplets. Here, for the first time, we study the formation of preferred protein quaternary structures within such rapidly evaporating nanodroplets. We use ion mobility and tandem mass spectrometry to investigate glutamate dehydrogenase dodecamers and serum amyloid P decamers as a function of protein concentration, along with control experiments using carefully chosen protein analogues, to both establish the formation of operative mechanisms and assign the bimodal conformer populations observed. Further, we identify an unprecedented symmetric collision-induced dissociation pathway that we link directly to the quaternary structures of the precursor ions selected.

  9. Quaternary Galois field adder based all-optical multivalued logic circuits.

    Science.gov (United States)

    Chattopadhyay, Tanay; Taraphdar, Chinmoy; Roy, Jitendra Nath

    2009-08-01

    Galois field (GF) algebraic expressions have been found to be promising choices for reversible and quantum implementation of multivalued logic. For the first time to our knowledge, we developed GF(4) adder multivalued (four valued) logic circuits in an all-optical domain. The principle and possibilities of an all-optical GF(4) adder circuit are described. The theoretical model is presented and verified through numerical simulation. The quaternary inverter, successor, clockwise cycle, and counterclockwise cycle gates are proposed with the help of the all-optical GF(4) adder circuit. In this scheme different quaternary logical states are represented by different polarized light. A terahertz optical asymmetric demultiplexer interferometric switch plays an important role in this scheme.

  10. Paleomagnetic dating of tectonically influenced Plio-Quaternary fan-system deposits from the Apennines (Italy

    Directory of Open Access Journals (Sweden)

    Michele Saroli

    2015-03-01

    Full Text Available The Roveto Valley is a narrow, elongated, NW-trending depression filled with continental Plio-Quaternary deposits that outcrop at different topographic elevations. A morpho-lithostratigraphic succession of the continental deposits has been defined in order to reconstruct the geological Quaternary evolution of the area. These deposits do not contain materials suitable for biostratigraphic dating; therefore, in order to determine their chronology, three different units were sampled for magnetostratigraphic investigations. Paleomagnetic results demonstrated that standard demagnetization techniques are effective in removing secondary remanence components and in isolating the characteristic remanent magnetization, allowing us to determine, for each cycle, whether it was deposited before or after the Brunhes-Matuyama geomagnetic reversal at 781 ka. Preliminary rock magnetic analyses indicated that magnetite is the main magnetic carrier and that hematite, which gives the pink colour to the matrix, is in the superparamagnetic grain-size range and thus does not retain any paleomagnetic remanence.

  11. Two Classes of Bacterial IMPDHs according to Their Quaternary Structures and Catalytic Properties

    Science.gov (United States)

    Alexandre, Thomas; Rayna, Bertrand; Munier-Lehmann, Hélène

    2015-01-01

    Inosine-5′-monophosphate dehydrogenase (IMPDH) occupies a key position in purine nucleotide metabolism. In this study, we have performed the biochemical and physico-chemical characterization of eight bacterial IMPDHs, among which six were totally unexplored. This study led to a classification of bacterial IMPDHs according to the regulation of their catalytic properties and their quaternary structures. Class I IMPDHs are cooperative enzymes for IMP, which are activated by MgATP and are octameric in all tested conditions. On the other hand, class II IMPDHs behave as Michaelis-Menten enzymes for both substrates and are tetramers in their apo state or in the presence of IMP, which are shifted to octamers in the presence of NAD or MgATP. Our work provides new insights into the IMPDH functional regulation and a model for the quaternary structure modulation is proposed. PMID:25706619

  12. Loess in China: A Good Archive of Climatic and Environmental Changes during the Quaternary

    Institute of Scientific and Technical Information of China (English)

    Wang Limeng; Lu Huayu

    2005-01-01

    @@ Quaternary scientists in China have significantly improved our knowledge of loess deposition as well as our understanding of paleoclimatic and paleoenvironmental changes over the past 2.5 million years. It is recognized that loess is of aeolian origin with loess forming dust continuously deposited. It is also believed that grain-size, magnetic susceptibility, carbon isotopes and fossil assemblages in loess deposits are good proxy indicators of paleomonsoon climate and paleovegetation changes over the past 2.5 million years. Chinese loess is regarded as one of the best terrestrial archives of climatic and environmental changes during the Quaternary.Further investigation of loess deposits and their records of climatic and environmental change aids understanding of climate change and gives scientific backing for the project of ecological and environmental restoration in northwest China.

  13. Hydrolysed ginseng-saponin quaternary: a novel conditioning agent for hair care products.

    Science.gov (United States)

    Young-Dae, K; Chang-Kew, K; Chung-Nam, L; Byung-Jo, H

    1989-10-01

    Synopsis A new quaternary ammonium compound, hydrolysed ginseng-saponin quaternary (HGSQ), from Korean ginseng saponin and 2,3-epoxypropyltrimethyl ammonium chloride, has been developed as a conditioning agent for hair care products. This structure has a hydrophobic group from the aglycone of ginseng saponin which is biologically active and considered as the most important component of Korean ginseng. Its properties of surface tension, conductivity, critical micelle concentration (CMC), eye irritation, sorption onto hair, tensile strength for 20% extension and moisture retention effect were studied. Its cationic character allows the molecule to be more substantive than ginseng saponin. HGSQ had good physical properties and was safe enough as a cosmetic raw material. Also half-head tests of HGSQ-containing shampoo were carried out to evaluate the conditioning effects in shampoos. HGSQ showed good conditioning properties in a shampoo.

  14. Design and analysis of carbon nanotube FET based quaternary full adders

    Institute of Scientific and Technical Information of China (English)

    Mohammad Hossein MOAIYERI; Shima SEDIGHIANI; Fazel SHARIFI; Keivan NAVI

    2016-01-01

    CMOS binary logic is limited by short channel effects, power density, and interconnection restrictions. The effective solution is non-silicon multiple-valued logic (MVL) computing. This study presents two high-performance quaternary full adder cells based on carbon nanotube field effect transistors (CNTFETs). The proposed designs use the unique properties of CNTFETs such as achieving a desired threshold voltage by adjusting the carbon nanotube diameters and having the same mobility as p-type and n-type devices. The proposed circuits were simulated under various test conditions using the Synopsys HSPICE simulator with the 32 nm Stanford comprehensive CNTFET model. The proposed designs have on average 32% lower delay, 68% average power, 83% energy consumption, and 77% static power compared to current state-of-the-art quaternary full adders. Simulation results indicated that the proposed designs are robust against process, voltage, and temperature variations, and are noise tolerant.

  15. A Quaternary-Stage User Interest Model Based on User Browsing Behavior and Web Page Classification

    Institute of Scientific and Technical Information of China (English)

    Zongli Jiang; Hang Su

    2012-01-01

    The key to personalized search engine lies in user model. Traditional personalized model results in that the search results of secondary search are partial to the long-term interests, besides, forgetting to the long-term interests disenables effective recollection of user interests. This paper presents a quaternary-stage user interest model based on user browsing behavior and web page classification, which consults the principles of cache and recycle bin in operating system, by setting up an illuminating text-stage and a recycle bin interest-stage in front and rear of the traditional interest model respectively to constitute the quaternary-stage user interest model. The model can better reflect the user interests, by using an adaptive natural weight and its calculation method, and by efficiently integrating user browsing behavior and web document content.

  16. EVALUATION OF THE ANTIMICROBIAL EFFECTS OF NEW HETEROCYCLIC BIS-QUATERNARY AMMONIUM COMPOUNDS ON BIOFILMS

    Directory of Open Access Journals (Sweden)

    OANA E. CONSTANTIN

    2016-07-01

    Full Text Available Considering the well-known mechanism of adaptable resistance of microorganisms to chemical compounds through biofilms formation and the widespread use of N-heterocyclic quaternary ammonium salts (QAC as disinfectants, in this study we have evaluate the effect of 8 newly synthesized symmetrical and unsymmetrical diquaternary ammonium salts of 1,2-bis-(4-pyridil-ethane on bacterial biofilms produced by three different bacterial strains. The effect of the exposure to quaternary ammonium salts on biofilm communities was investigated within biofilms obtained in a conventional testing system, on stainless steel and glass surfaces. Differential plate counts were used to characterize the developed communities and the effects of QAC exposure and the results were correlated with epifluorescence microphotographs. The data obtained revealed a significant reduction of bacterial cells in the biofilms tested with 4-7 log CFU for all the QAC.

  17. Growth of ternary and quaternary cubic III-nitrides on 3C-SiC substrates

    Science.gov (United States)

    Schörmann, J.; Potthast, S.; Schnietz, M.; Li, S. F.; As, D. J.; Lischka, K.

    2006-06-01

    Cubic GaN, AlxGa1-xN/GaN multiple quantum wells and quaternary AlxGayIn1-x-yN layers were grown by plasma assisted molecular beam epitaxy on 3C-SiC substrates. Using the intensity of a reflected high energy electron beam as a probe optimum growth conditions of c-III nitrides were found, when a 1 monolayer Ga coverage is formed at the growing surface. Clear RHEED oscillations during the initial growth of AlxGa1-xN/GaN quantum wells were observed. X-ray diffraction measurements of these quantum well structures show clear satellite peaks indicating smooth interfaces. Growth of quaternary AlxGayIn1-x-yN lattice matched to GaN were demonstrated.

  18. Effective electron mass in quantum wires of III-V, ternary and quaternary materials.

    Science.gov (United States)

    Paitya, N; Ghatak, K P

    2012-12-01

    In this paper, an attempt is made to study the effective electron mass (EEM) in Quantum wires (QWs) of III-V, ternary and quaternary materials on the basis of three and two band models of Kane within the framework of k x p formalism. It has been found, taking QWs of InAs, InSb, GaAs, Hg(1-x)Cd(x)Te and In(1-x)Ga(x)As(1-y)P(t) that the 1D EEM increases with electron concentration per unit length and decreases with increasing film thickness respectively. For ternary and quaternary materials the EEM increases with increase in alloy composition. Under certain special conditions all the results for all the 1-D materials get simplified into the well known parabolic energy bands and thus confirming the compatibility test. The results of this paper find two applications in the fields of nanoscience and technology.

  19. Simultaneous adsorption/desorption of quaternary ammonium herbicides by acid vineyard soils

    Science.gov (United States)

    Conde Cid, Manuel; Paradelo Núñez, Remigio; Fernández Calviño, David; Nóvoa Muñoz, Juan Carlos; Arias Estévez, Manuel

    2017-04-01

    Competitive adsorption and desorption of three quaternary ammonium herbicides (paraquat, diquat, and difenzoquat) have been studied in four sandy-loam acid vineyard soils from NW Spain and Portugal. The soils present organic matter contents between 3 and 48 g kg-1 and copper contents ranging from 25 to 107 mg kg-1. Adsorption has been studied under equilibrium conditions in batch experiments, and kinetics were studied in a stirred-flow chamber. Adsorption and desorption followed a Freundlich model and kinetics were well described by the pseudo-first-order model. The retention capacity for the pesticides by the four soils followed the sequence: paraquat > diquat > difenzoquat. The different adsorption capacities of each soil were not related to pH, clay or organic matter contents, as could be expected, but rather to soil copper content. The results show that competition with copper for adsorption sites is an important factor in quaternary ammonium herbicides retention in soils with these characteristics.

  20. Mechanisms of flotation separation of diaspore and kaolinite by quaternary ammonium salt DTAL

    Institute of Scientific and Technical Information of China (English)

    陈湘清; 胡岳华; 王毓华

    2004-01-01

    The FTIR spectroscopy indicates that the adsorption of quaternary ammonium salt DTAL on the diaspore and kaolinite is physical adsorption. The adsorption of cationic surfactants measured by two-phase titration shows that the adsorption on the kaolinite is notably more than that on diaspore. The adsorption isotherm on kaolinte is linear while that of DTAL on diaspore is two-step flat form. The analysis on the cationic ions of kaolinite supernatants shows that kaolinite releases plenty of crystalloid structure ions which countervail the crystalloid charge because of the adsorption of the cationic surfactant. The mechanisms of the quaternary ammonium salt DTAL on flotation separation of diaspore and kaolinite include ion exchange interaction as well as electrostatic force.

  1. Thermoelectric properties of quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compound

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Pengfei, E-mail: photon.bupt@gmail.com [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Li, Yiluan; Wu, Chengjie; Yu, Zhongyuan; Cao, Huawei; Zhang, Xianlong; Cai, Ningning; Zhong, Xuxia [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Wang, Shumin [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Photonics Laboratory, Department of Microtechnology and Nanoscience, Chalmers University of Technology, 41296 Gothenburg (Sweden)

    2014-01-25

    Highlights: • Sb and Se spin–orbit coupling play a key role in the band structure. • Substituted Bi/Sb and Te/Se have a limited impact on the transport coefficients. • n-Type doping will be preferred for quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compound. -- Abstract: The quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compounds are investigated using first-principles study and Boltzmann transport theory. The energy band structure and density of states are studied in detail. The electronic transport coefficients are then calculated as a function of chemical potential. The figure of merit ZT is obtained assuming a constant relaxation time and an averaged thermal conductivity. Our theoretical result agrees well with previous experimental data.

  2. Quaternary grabens in southernmost Illinois: Deformation near an active intraplate seismic zone

    Science.gov (United States)

    Nelson, W.J.; Denny, F.B.; Follmer, L.R.; Masters, J.M.

    1999-01-01

    Narrow grabens displace Quaternary sediments near the northern edge of the Mississippi Embayment in extreme southern Illinois, east-central United States. Grabens are part of the Fluorspar Area Fault Complex (FAFC), which has been recurrently active throughout Phanerozoic time. The FAFC strikes directly toward the New Madrid Seismic Zone (NMSZ), scene of some of the largest intra-plate earthquakes in history. The NMSZ and FAFC share origin in a failed Cambrian rift (Reelfoot Rift). Every major fault zone of the FAFC in Illinois exhibits Quaternary displacement. The structures appear to be strike-slip pull-apart grabens, but the magnitude and direction of horizontal slip and their relationship to the current stress field are unknown. Upper Tertiary strata are vertically displaced more than 100 m, Illinoian and older Pleistocene strata 10 to 30 m, and Wisconsinan deposits 1 m or less. No Holocene deformation has been observed. Average vertical slip rates are estimated at 0.01 to 0.03 mm/year, and recurrence intervals for earthquakes of magnitude 6 to 7 are on the order of 10,000s of years for any given fault. Previous authors remarked that the small amount of surface deformation in the New Madrid area implies that the NMSZ is a young feature. Our findings show that tectonic activity has shifted around throughout the Quaternary in the central Mississippi Valley. In addition to the NMSZ and southern Illinois, the Wabash Valley (Illinois-Indiana), Benton Hills (Missouri), Crowley's Ridge (Arkansas-Missouri), and possibly other sites have experienced Quaternary tectonism. The NMSZ may be only the latest manifestation of seismicity in an intensely fractured intra-plate region.

  3. Geological and geomorphological evolution of a sedimentary periglacial landscape in Northeast Siberia during the Late Quaternary

    OpenAIRE

    2007-01-01

    A wide variety of environmental records is necessary for analysing and understanding the complex Late Quaternary dynamics of permafrost-dominated Arctic landscapes. A NE Siberian periglacial key region was studied in detail using sediment records, remote sensing data, and terrain modelling, all incorporated in a geographical information system (GIS). The study area consists of the Bykovsky Peninsula and the adjacent Khorogor Valley in the Kharaulakh Ridge situated a few kilometres southeast o...

  4. Fluctuations in productivity and denitrification in the southeastern Arabian Sea during the Late Quaternary

    Digital Repository Service at National Institute of Oceanography (India)

    Kessarkar, P.M.; Rao, V.P.; Naqvi, S.W.A.; Chivas, A.R.; Saino, T.

    , D. W., The effect of millennial-scale changes in Arabian Sea denitrification on atmos- pheric CO 2 . Nature, 2002, 415, 159–162. 8. Reichart, G. J., Lourens, L. J. and Zachariasse, W. J., Temporal variability in the northern Arabian Sea Oxygen.... Suthhof, A., Ittekkot, V. and Gaye-Haake, B., Millennial-scale oscillations of denitrification intensity in the Arabian Sea during the late Quaternary and its potential influence on atmospheric N 2 O and global climate. Glob. Biogeochem. Cycles, 2001...

  5. Quantitative analysis of deuterium using the isotopic effect on quaternary {sup 13}C NMR chemical shifts

    Energy Technology Data Exchange (ETDEWEB)

    Darwish, Tamim A., E-mail: tamim.darwish@ansto.gov.au [National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Locked Bag 21, Kirrawee DC, NSW 2232 (Australia); Yepuri, Nageshwar Rao; Holden, Peter J. [National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Locked Bag 21, Kirrawee DC, NSW 2232 (Australia); James, Michael [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2016-07-13

    Quantitative analysis of specifically deuterated compounds can be achieved by a number of conventional methods, such as mass spectroscopy, or by quantifying the residual {sup 1}H NMR signals compared to signals from internal standards. However, site specific quantification using these methods becomes challenging when dealing with non-specifically or randomly deuterated compounds that are produced by metal catalyzed hydrothermal reactions in D{sub 2}O, one of the most convenient deuteration methods. In this study, deuterium-induced NMR isotope shifts of quaternary {sup 13}C resonances neighboring deuterated sites have been utilized to quantify the degree of isotope labeling of molecular sites in non-specifically deuterated molecules. By probing {sup 13}C NMR signals while decoupling both proton and deuterium nuclei, it is possible to resolve {sup 13}C resonances of the different isotopologues based on the isotopic shifts and the degree of deuteration of the carbon atoms. We demonstrate that in different isotopologues, the same quaternary carbon, neighboring partially deuterated carbon atoms, are affected to an equal extent by relaxation. Decoupling both nuclei ({sup 1}H, {sup 2}H) resolves closely separated quaternary {sup 13}C signals of the different isotopologues, and allows their accurate integration and quantification under short relaxation delays (D1 = 1 s) and hence fast accumulative spectral acquisition. We have performed a number of approaches to quantify the deuterium content at different specific sites to demonstrate a convenient and generic analysis method for use in randomly deuterated molecules, or in cases of specifically deuterated molecules where back-exchange processes may take place during work up. - Graphical abstract: The relative intensities of quaternary {sup 13}C {"1H,"2H} resonances are equal despite the different relaxation delays, allowing the relative abundance of the different deuterated isotopologues to be calculated using NMR fast

  6. Polyamide 6 Nanocomposites with Inorganic Particles Modified with Three Quaternary Ammonium Salts

    Directory of Open Access Journals (Sweden)

    Hélio de Lucena Lira

    2011-11-01

    Full Text Available The purpose of this study was to obtain polyamide 6 nanocomposites with national organically modified clay with three quaternary ammonium salts. The obtained results confirm the intercalation of molecules of salt in the clay layers, and a good interaction with the polymer, showing the formation of intercalated and/or partially exfoliated structures. The nanocomposites showed similar thermal stability compared to pure polymer, and the mechanical properties presented interesting and promising results.

  7. Intercalating quaternary nicotinamide-based poly(amido amine)s for gene delivery.

    Science.gov (United States)

    van der Aa, L J; Vader, P; Storm, G; Schiffelers, R M; Engbersen, J F J

    2014-12-10

    In the development of potent polymeric gene carriers for gene therapy, a good interaction between the polymer and the nucleotide is indispensable to form small and stable polyplexes. Polymers with relatively high cationic charge density are frequently used to provide these interactions, but high cationic charge is usually associated with severe cytotoxicity. In this study an alternative, nucleotide specific binding interaction based on intercalation was investigated to improve polymer/pDNA complex formation. For this purpose bioreducible poly(amido amine) copolymers (p(CBA-ABOL/Nic)) were synthesized with different degrees of intercalating quaternary nicotinamide (Nic) groups and amide-substituted derivatives in their side chains. The quaternary nicotinamide group was chosen as intercalating moiety because this group is part of the naturally occurring NAD+ coenzyme and is therefore expected to be non-toxic and non-carcinogenic. The presence of the quaternary nicotinamide moieties in the poly(amido amine) copolymers showed to effectively promote self-assembled polyplex formation already at low polymer/DNA ratios and results in decreased polyplex size and increased stability of the polyplexes. Furthermore, in contrast to the primary amine functionalized analogs the quaternary nicotinamide polymers showed to be non-hemolytic, indicating their compatibility with cell membranes. Polymers with 25% of Nic in the side chains induced GFP expressions of about 4-5 times that of linear PEI, which is comparable with p(CBA-ABOL), the parent PAA without Nic, but at a two- to fourfold lower required polymer dose. N-phenylation of the nicotinamide functionality even further reduces the required polymer dose to form stable polyplexes, which is a major improvement for these kinds of cationic polymers. Copyright © 2014 Elsevier B.V. All rights reserved.

  8. Synthesis and Characterization of Novel Ternary and Quaternary Alkali Metal Thiophosphates

    KAUST Repository

    Alahmary, Fatimah S.

    2014-05-01

    The ongoing development of nonlinear optical (NLO) crystals such as coherent mid-IR sources focuses on various classes of materials such as ternary and quaternary metal chalcophosphates. In case of thiophosphates, the connection between PS4-tetrahedral building blocks and metals gives rise to a broad structural variety where approximately one third of all known ternary (A/P/S) and quaternary (A/M/P/S) (A = alkali metal, M = metal) structures are acentric and potential nonlinear optical materials. The molten alkali metal polychalcophosphate fluxes are a well-established method for the synthesis of new ternary and quaternary thiophosphate and selenophosphate compounds. It has been a wide field of study and investigation through the last two decades. Here, the flux method is used for the synthesis of new quaternary phases containing Rb, Ag, P and S. Four new alkali metal thiophosphates, Rb4P2S10, RbAg5(PS4), Rb2AgPS4 and Rb3Ag9(PS4)4, have been synthesized successfully from high purity elements and binary starting materials. The new compounds were characterized by single crystal and powder X-ray diffraction, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), ultraviolet-visible (UV-VIS), Raman spectroscopy, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). These compounds show interesting structural variety and physical properties. The crystal structures feature 3D anionic framework built up of PS4 tetrahedral units and charge balanced by Ag and alkali metal cations. All prepared compounds are semiconductors with band gap between 2.3 eV to 2.6 eV and most of them are thermally stable up to 600ºC.

  9. Late Quaternary glaciation of the Upper Soca River Region (Southern Julian Alps, NW Slovenia)

    Science.gov (United States)

    Bavec, Milos; Tulaczyk, Slawek M.; Mahan, Shannon; Stock, Gregory M.

    2004-01-01

    Extent of Late Quaternary glaciers in the Upper Soc??a River Region (Southern Julian Alps, SE Europe) has been analyzed using a combination of geological mapping, glaciological modeling, and sediment dating (radiocarbon, U/Th series and Infrared Stimulated Luminescence-IRSL). Field investigations focused mainly on relatively well preserved Quaternary sequences in the Bovec Basin, an intramontane basin located SW of the Mediterranean/Black Sea divide and surrounded by mountain peaks reaching from approximately 2100 up to 2587 m a.s.l. Within the Basin we recognized two Late Quaternary sedimentary assemblages, which consist of the same facies association of diamictons, laminated lacustrine deposits and sorted fluvial sediments. Radiocarbon dating of the upper part of the lake sediments sequence (between 12790??85 and 5885??60 14C years b.p.) indicates that the younger sedimentary assemblage was deposited during the last glacial maximum and through early Holocene (Marine Isotope Stage 21, MIS 2-1). Sediment ages obtained for the older assemblage with U/Th and IRSL techniques (between 154.74??22.88 and 129.93??7.90 ka b.p. for selected samples) have large errors but both methods yield results consistent with deposition during the penultimate glacial-interglacial transition (MIS 6-5). Based on analyses of field data combined with glaciological modeling, we argue that both sediment complexes formed due to high sediment productivity spurred by paraglacial conditions with glaciers present in the uplands around the Bovec Basin but not extending down to the basin floor. Our study shows that the extent and intensity of direct glacial sedimentation by Late Quaternary glaciers in the region was previously significantly overestimated. ?? 2004 Elsevier B.V. All rights reserved.

  10. Effect of quaternary ammonium salts in the process of extracting oil filled rubber from latex

    Directory of Open Access Journals (Sweden)

    N. S. Nikulina

    2016-01-01

    Full Text Available Currently, much attention is paid to the improvement of production technology of synthetic rubber. Much attention is given to rubber is produced by emulsion polymerization. This is due to the fact that rubbers produced by emulsion polymerization have a number of positive characteristics, and are widely used in the tire and rubber industry, in composite formulations for various purposes. In recent years, the technology of production of synthetic rubbers are widely used quaternary ammonium salts which are produced on an industrial scale. Application low and high molecular weight quaternary ammonium salts to reduce pollution of environ-mental protection, exclude the use of mineral salts without significant changes in the process flowsheet. It is found that quaternary ammonium salts react with the components of the emulsion system to form insoluble complexes, which are captured produced rubber crumb. However, Applications, quaternary salts in the manufacture of oil-filled rubber in the literature sources have not been given due attention. The study presents the results of research on the effect of the concentration of a coagulating agent, tempera tours and concentration of the dispersed phase in the process of coagulation of latex in the preparation of oil-filled rubber stamps SCS-30 ARKM-15. The concentration of the coagulating agent does not significantly affect the process of separation of the rubber from the latex. The process of isolation rubber latex is advantageously carried out at a reduced temperature. The concentration of the dispersed phase also provides material effect on the coagulation process. The lead researches mouthestablished that produced rubber, rubber compounds and vulcanizates based on these indicators correspond to their requirements.

  11. Late Quaternary transgressive large dunes on the sediment-starved Adriatic shelf

    Science.gov (United States)

    Correggiari, A.; Field, M.E.; Trincardi, F.

    1996-01-01

    The Adriatic epicontinental basin is a low-gradient shelf where the late-Quaternary transgressive systems tract (TST) is composed of thin parasequences of backbarrier, shoreface and offshore deposits. The facies and internal architecture of the late-Quaternary TST in the Adriatic epicontinental basin changed consistently from early transgression to late transgression reflecting: (1) fluctuations in the balance between sediment supply and accommodation increase, and (2) a progressive intensification of the oceanographic regime, driven by the transgressive widening of the basin to as much as seven times its lowstand extent. One of the consequences of this trend is that high-energy marine bedforms such as sand ridges and sand waves characterize only areas that were flooded close to the end of the late-Quaternary sea-level rise, when the wind fetch was maximum and bigger waves and stronger storm currents could form. We studied the morphology, sediment composition and sequence-stratigraphical setting of a field of asymmetric bedforms (typically 3 m high and 600 m in wavelength) in 20-24 m water depth offshore the Venice Lagoon in the sediment-starved North Adriatic shelf. The sand that forms these large dunes derived from a drowned transgressive coastal deposit reworked by marine processes. Early cementation took place over most of the dune crests limiting their activity and preventing their destruction. Both the formation and deactivation of this field of sand dunes occurred over a short time interval close to the turn-around point that separates the late-Quaternary sea-level rise and the following highstand and reflect rapid changes in the oceanographic regime of the basin.

  12. InGaAsP Quaternary Materials for Near Infrared Detector and Laser Applications

    Science.gov (United States)

    1980-06-01

    Japanese Journal of Applied Physics , vol. 19, pp. L17-L20, January 1980. 52. H. Kaube, Y. Yamaucbi and N. Susa...Sugiyama, H. Kojima, H. Enda, and M. Shibata, "Vapor Phase Epitaxial Growth and Characterization of Gal-ylnyAsl-xPx Quaternary Alloys," Japanese Journal of Applied Physics , vol...34 Japanese Journal of Applied Physics , vol. 18, pp. 2167-2168, 1979. 59. G. H. Olsen and T. J. Zamerowski, *Crystal Growth

  13. Anti-Caries Effects of Dental Adhesives Containing Quaternary Ammonium Methacrylates with Different Chain Lengths

    OpenAIRE

    Qi Han; Bolei Li; Xuedong Zhou; Yang Ge; Suping Wang; Mingyun Li; Biao Ren; Haohao Wang; Keke Zhang; Hockin H. K. Xu; Xian Peng; Mingye Feng; Michael D. Weir; Yu Chen; Lei Cheng

    2017-01-01

    The objectives of this study were to investigate the effects of dental adhesives containing quaternary ammonium methacrylates (QAMs) with different alkyl chain lengths (CL) on ecological caries prevention in vitro. Five QAMs were synthesized with a CL = 3, 6, 9, 12, and 16 and incorporated into adhesives. Micro-tensile bond strength and surface charge density were used to measure the physical properties of the adhesives. The proportion change in three-species biofilms consisting of Streptococ...

  14. Extraction of metals from metal ion-catechol-quaternary base systems.

    Science.gov (United States)

    Vrchlabský, M; Sommer, L

    1968-09-01

    Methods are given for the extraction of iron(III), molybdenum(VI), titanium(IV), niobium(V), vanadium(IV), uranium(VI) and tungsten(VI) as ternary complexes with catechol and a quaternary cation such as n-butyltriphenylphosphonium, n-propyltriphenylphosphonium, tetraphenylarsonium, cetylpyridinium, cetyltrimethylammonium and 2,3,5-triphenyltetrazolium, the solvent being chloroform. By use of masking agents and pH control, some of these elements can be separated from each other by this means.

  15. Electric field dynamics in nitride structures containing quaternary alloy (Al, In, Ga)N

    Energy Technology Data Exchange (ETDEWEB)

    Borysiuk, J., E-mail: jolanta.borysiuk@ifpan.edu.pl [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Faculty of Physics, University of Warsaw, Pasteura 5, 02-093 Warsaw (Poland); Sakowski, K.; Muziol, G.; Krukowski, S. [Institute of High Pressure Physics, Polish Academy of Sciences, Sokolowska 29/37, 01-142 Warsaw (Poland); Dróżdż, P. [Faculty of Physics, University of Warsaw, Pasteura 5, 02-093 Warsaw (Poland); Institute of High Pressure Physics, Polish Academy of Sciences, Sokolowska 29/37, 01-142 Warsaw (Poland); Korona, K. P. [Faculty of Physics, University of Warsaw, Pasteura 5, 02-093 Warsaw (Poland); Sobczak, K. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Skierbiszewski, C. [Institute of High Pressure Physics, Polish Academy of Sciences, Sokolowska 29/37, 01-142 Warsaw (Poland); TopGaN Ltd., Sokolowska 29/37, 01-142 Warsaw (Poland); Kaminska, A. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Department of Mathematics and Natural Sciences, College of Science, Cardinal Stefan Wyszynski University, Dewajtis 5, 01-815 Warsaw (Poland)

    2016-07-07

    Molecular beam epitaxy growth and basic physical properties of quaternary AlInGaN layers, sufficiently thick for construction of electron blocking layers (EBL), embedded in ternary InGaN layers are presented. Transmission electron microscopy (TEM) measurement revealed good crystallographic structure and compositional uniformity of the quaternary layers contained in other nitride layers, which are typical for construction of nitride based devices. The AlInGaN layer was epitaxially compatible to InGaN matrix, strained, and no strain related dislocation creation was observed. The strain penetrated for limited depth, below 3 nm, even for relatively high content of indium (7%). For lower indium content (0.6%), the strain was below the detection limit by TEM strain analysis. The structures containing quaternary AlInGaN layers were studied by time dependent photoluminescence (PL) at different temperatures and excitation powers. It was shown that PL spectra contain three peaks: high energy donor bound exciton peak from the bulk GaN (DX GaN) and the two peaks (A and B) from InGaN layers. No emission from quaternary AlInGaN layers was observed. An accumulation of electrons on the EBL interface in high-In sample and formation of 2D electron gas (2DEG) was detected. The dynamics of 2DEG was studied by time resolved luminescence revealing strong dependence of emission energy on the 2DEG concentration. Theoretical calculations as well as power-dependence and temperature-dependence analysis showed the importance of electric field inside the structure. At the interface, the field was screened by carriers and could be changed by illumination. From these measurements, the dynamics of electric field was described as the discharge of carriers accumulated on the EBL.

  16. Periodicity of chaotic solutions

    CERN Document Server

    Berezowski, Marek

    2016-01-01

    The scope of the paper is the analysis of the impact of flow reversal on the dynamics of cascades of reactors. Periodic and chaotic oscillations occur in the analyzed system. There is a dependence between the oscillation period of the state variable of the system without flow reversal and the recurrence period of windows of chaos in the steady-state diagram of the system with flow reversal.

  17. Bott periodicity of inclusions

    CERN Document Server

    Mare, Augustin-Liviu

    2011-01-01

    When looking at Bott's original proof of his periodicity theorem for the stable homotopy groups of the orthogonal and unitary groups, one sees in the background a differential geometric periodicity phenomenon. We show that this geometric phenomenon extends to the standard inclusion of the orthogonal group into the unitary group. This explains the periodicity of the group homomorphisms between stable homotopy groups which are induced by the inclusion map. Standard inclusions between other classical Riemannian symmetric spaces are also discussed.

  18. Characterisation of quaternary polymethacrylate films containing tartaric acid, metoprolol free base or metoprolol tartrate.

    Science.gov (United States)

    Glaessl, B; Siepmann, F; Tucker, I; Siepmann, J; Rades, T

    2009-11-01

    The aim of this study was to better understand the interactions between metoprolol tartrate and quaternary polymethacrylate (Eudragit RL and Eudragit RS) films. For reasons of comparison, polymeric films containing the free base metoprolol or free tartaric acid were also prepared. Systems containing various amounts of the free base, free acid and the salt were characterised using polarising light microscopy, X-ray powder diffraction, differential scanning calorimetry and mechanical analysis (puncture test). The free base is the most efficient plasticiser of the three species for Eudragit RL and Eudragit RS, but with limited solubility in the polymers. Due to its hydrophobicity, it can interact with the hydrophobic polymer backbones. In contrast, in salt containing films, ionic interactions between the positively charged quaternary ammonium groups and the negatively charged tartrate anions apparently occur, this being suggested by the different effects on Eudragit RL versus RS, which have different contents of quaternary ammonium groups. Importantly, the combination of acid and base as a salt avoids drug precipitation at higher metoprolol contents. The obtained new insight into the occurring drug-polymer interactions can help to facilitate the development/optimisation of this type of dosage forms.

  19. Spontaneous quaternary and tertiary T-R transitions of human hemoglobin in molecular dynamics simulation.

    Directory of Open Access Journals (Sweden)

    Jochen S Hub

    2010-05-01

    Full Text Available We present molecular dynamics simulations of unliganded human hemoglobin (Hb A under physiological conditions, starting from the R, R2, and T state. The simulations were carried out with protonated and deprotonated HC3 histidines His(beta146, and they sum up to a total length of 5.6 micros. We observe spontaneous and reproducible T-->R quaternary transitions of the Hb tetramer and tertiary transitions of the alpha and beta subunits, as detected from principal component projections, from an RMSD measure, and from rigid body rotation analysis. The simulations reveal a marked asymmetry between the alpha and beta subunits. Using the mutual information as correlation measure, we find that the beta subunits are substantially more strongly linked to the quaternary transition than the alpha subunits. In addition, the tertiary populations of the alpha and beta subunits differ substantially, with the beta subunits showing a tendency towards R, and the alpha subunits showing a tendency towards T. Based on the simulation results, we present a transition pathway for coupled quaternary and tertiary transitions between the R and T conformations of Hb.

  20. Quaternary transgressive and regressive depositional sequences in the East China Sea

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Based on the interpretation more than 4000 km sparker single channel seismic profiles and the comparison with Borehole DZQ4 on the outer shelf of the East China Sea (ECS), the seismic sequences, sedimentary facies and paleo-sedimentary environment are studied to establish the chronology framework and discuss the Quaternary transgressive and regressive sequences of the ECS shelf as well as their response to glacio-eustatic sea-level changes. The sea level of the ECS fluctuated with global climate changes in the Quaternary. During the sea level rise, the Pacific tidal wave impacted actively on the ECS continental shelf and the reciprocating tidal currents in NW-SE direction formed tidal sand ridges, which represent large transgressive deposits visible on the seismic profiles. In response to sea level fall, the Yangtze River deltas prograded seaward and built massive subaqueous deltas to form regressive sequences on the seismic profiles. Alternative transgression and regression sequences were vertically distributed on the ECS shelf with the frequent eustacy in the Quaternary. The gentle slope of the ECS shelf makes it possible for the coastline to migrate hundreds of kilometers forth and back on the shelf because of tens of meters sea level changes, in the meanwhile, the Yangtze River discharged large amounts of sediments into the ECS resulting in large-scale subaqueous deltas and tidal sand ridges. There have developed 3 stages of tidal sand ridges and 4 stages of deltas on the ECS shelf since oxygen isotope stage 8.

  1. A study of the formation constants of ternary and quaternary complexes of some bivalent transition metals

    Directory of Open Access Journals (Sweden)

    MADHURJYA NEOG

    2010-01-01

    Full Text Available The formation of hetero-ligand 1:1:1, M(II-Opda-Sal/Gly ternary and 1:1:1:1, M(II-Opda-Sal-Gly quaternary complexes, where M(II = Ni, Cu, Zn and Cd; Opda = o‑phenylenediamine, Sal = salicylic acid, Gly = glycine, was studied pH-metrically in aqueous medium. The formation constants for the resulting ternary and quaternary complexes were evaluated at a constant ionic strength, μ = 0.20 mol dm-3 and temperature, 30±0.1 °C. The order of the formation constants in terms of the metal ion for both type of complexes was found to be Cu(II > Ni(II > Zn(II > Cd(II. This order was explained based on the increasing number of fused rings, the coordination number of the metal ions, the Irving – William order and the stability of various species. The expected species formed in solution were pruned with the Fortran IV program SPEPLOT and the stability of the ternary and quaternary complexes is explained.

  2. Hydrolysis of cellulose catalyzed by quaternary ammonium perrhenates in 1-allyl-3-methylimidazolium chloride.

    Science.gov (United States)

    Wang, Jingyun; Zhou, Mingdong; Yuan, Yuguo; Zhang, Quan; Fang, Xiangchen; Zang, Shuliang

    2015-12-01

    Quaternary ammonium perrhenates were applied as catalyst to promote the hydrolysis of cellulose in 1-allyl-3-methylimidazolium chloride ([Amim]Cl). The quaternary ammonium perrhenates displayed good catalytic performance for cellulose hydrolysis. Water was also proven to be effective to promote cellulose hydrolysis. Accordingly, 97% of total reduced sugar (TRS) and 42% of glucose yields could be obtained under the condition of using 5mol% of tetramethyl ammonium perrhenate as catalyst, 70μL of water, ca. 0.6mmol of microcrystalline cellulose (MCC) and 2.0g of [Amim]Cl as solvent under microwave irradiation for 30min at 150°C (optimal conditions). The influence of quaternary ammonium cation on the efficiency of cellulose hydrolysis was examined based on different cation structures of perrhenates. The mechanism on perrhenate catalyzed cellulose hydrolysis is also discussed, whereas hydrogen bonding between ReO4 anion and hydroxyl groups of cellulose is assumed to be the key step for depolymerization of cellulose. Copyright © 2015. Published by Elsevier Ltd.

  3. Quaternary polymethacrylate-magnesium aluminum silicate films: molecular interactions, mechanical properties and tackiness.

    Science.gov (United States)

    Rongthong, Thitiphorn; Sungthongjeen, Srisagul; Siepmann, Juergen; Pongjanyakul, Thaned

    2013-12-15

    The aim of this study was to investigate the impact of the addition of magnesium aluminum silicate (MAS), a natural clay, on the properties of polymeric films based on quaternary polymethacrylates (QPMs). Two commercially available aqueous QPM dispersions were studied: Eudragit(®) RS 30D and Eudragit(®) RL 30D (the dry copolymers containing 5 and 10% quaternary ammonium groups, respectively). The composite QPM-MAS films were prepared by casting. Importantly, QPM interacted with MAS and formed small flocculates prior to film formation. Continuous films were obtained up to MAS contents of 19% (referred to the QPM dry mass). ATR-FTIR and PXRD revealed that the positively charged quaternary ammonium groups of QPM interacted with negatively charged SiO(-) groups of MAS, creating nanocomposite materials. This interaction led to improved thermal stability of the composite films. The puncture strength and elongation at break of dry systems decreased with increasing MAS content. In contrast, the puncture strength of the wet QPM-MAS films (upon exposure to acidic or neutral media) increased with increasing MAS content. Furthermore, incorporation of MAS into QPM films significantly decreased the latter's tackiness in the dry and wet state. These findings suggest that nanocomposite formation between QPM and MAS in the systems can enhance the strength of wet films and decrease their tackiness. Thus, MAS offers an interesting potential as novel anti-tacking agent for QPM coatings.

  4. Synthesis and application of a quaternary phosphonium polymer coagulant to avoid N-nitrosamine formation.

    Science.gov (United States)

    Zeng, Teng; Pignatello, Joseph J; Li, Russell Jingxian; Mitch, William A

    2014-11-18

    Quaternary ammonium cationic polymers, such as poly(diallyldimethylammonium chloride) (polyDADMAC) are widely used for coagulating and removing negatively charged particles and dissolved organic matter (DOM) from drinking water. Their use, however, has been linked to the formation of carcinogenic N-nitrosamines as byproducts during chloramine-based drinking water disinfection. In this study, a novel quaternary phosphonium cationic polymer, poly(diallyldiethylphosphonium chloride) (polyDADEPC), was synthesized such that the quaternary nitrogen atom of polyDADMAC was substituted with a phosphorus atom. Formation potential tests revealed that even under strong nitrosation conditions, polyDADEPC and related lower-order P-based compounds formed oxygenated and not nitrosated products. Bench-scale jar tests using three different source waters further demonstrated that polyDADEPC achieved coagulation performance comparable to commercial polyDADMACs for particle and DOM removals within the typical dose range used for drinking water treatment. This work highlights the potential use of a phosphonium coagulant polymer, polyDADEPC, as a viable alternative to polyDADMAC to avoid nitrosated byproduct formation during chloramination.

  5. Primary solidification phases of the Sn-rich Sn-Ag-Cu-Ni quaternary system

    Science.gov (United States)

    Chang, Cheng-An; Chen, Sinn-Wen; Chiu, Chen-Nan; Huang, Yu-Chih

    2005-08-01

    The eutectic and near-eutectic Sn-Ag-Cu solders are the most promising lead-free solders, and nickel is frequently used as the barrier layer material. Nickel dissolves into the molten Sn-Ag-Ni alloy during the soldering process, and the ternary solder becomes a Sn-Ag-Cu-Ni quaternary melt near the nickel substrate. Liquidus projection is the projection of the liquidus trough and it delineates the boundaries of various primary solidification phases. Information of liquidus projection is helpful for understanding the alloys’ solidification behavior. This study prepared the Sn-Ag-Cu-Ni alloys of various compositions at the Sn-rich corner. The alloys were melted at higher temperatures and solidified in air. The solidified alloys were metallographically examined to determine the phases formed, especially the primary solidification phases. No ternary or quaternary compounds were found. The knowledge of the primary solidification phases, phase formation sequences, and reaction temperatures determined in this study were put together with all of the available liquidus projections of the constituent ternary systems to determine the primary solidification phases of the quaternary Sn-Ag-Cu-Ni system at the Sn-rich corner.

  6. Quaternary fluvial response to climate change in glacially influenced river systems

    Science.gov (United States)

    Cordier, Stéphane; Adamson, Kathryn; Delmas, Magali; Calvet, Marc; Harmand, Dominique

    2016-04-01

    Over the last few decades, many studies in Europe and other continents have focused on the fluvial response to climate forcing in unglaciated basins. However, glacial activity may have a profound impact on the behaviour of the fluvial systems located downstream. In comparison to ice-free basins, these systems are characterised by distinctive hydrological and sediment supply regimes. Over Quaternary timescales, the fluvial records are influenced by periglacial (in non-glaciated areas), proglacial, and paraglacial processes. Understanding the impacts of these processes on the formation and preservation of the Quaternary geomorphological and sedimentary archives is key for our understanding of glacial-fluvial interactions. We investigate the impact of Quaternary glacial activity on fluvial sediment transfer, deposition, and preservation. Using existing studies from across Europe, we create a database of glaciofluvial geomorphology, sedimentology, and geochronology. This is used to examine how glacial forcing of fluvial systems varies spatially in different basin settings, and temporally over successive Milankovitch cycles. In particular, we focus on the ways in which the primary glacial-fluvial depositional signal could be distinguished from periglacial and paraglacial reworking and redeposition.

  7. Flotation and adsorption of quaternary ammonium salts collectors on kaolinite of different particle size

    Institute of Scientific and Technical Information of China (English)

    Jiang Hao; Liu Guorong; Hu Yuehua; Xu Longhua; Yu Yawen; Xie Zhen; Chen Haochuan

    2013-01-01

    The flotation behaviors of decyltrimethylammonium (103C),dodecyltrimethylammonium chloride (DTAC),tetradecyltrimethylammonium chloride (TTAC) and cetyltrimethylammonium chloride (CTAC) on kaolinite of different particle size fraction were studied.The adsorbed amount and adsorption isotherms of collectors on kaolinite were determined for painstaking investigation into the adsorption of quaternary amines at kaolinite-water interface by ultraviolet spectrophotometer methods.The flotation results show that the flotation recovery of kaolinite of different particle fraction increases with an increase in pH when 103C,DTAC,TrAC and CTAC are used as collectors.As the concentration of collectors increases,the flotation recovery increases.Particle size of kaolinite has a strong effect on flotation.The flotation recovery of fine kaolinite decreases with the carbon chain of quaternary ammonium salts collectors increasing,while coarse kaolinite is on the contrary.The adsorbed amount tests and adsorption isotherms show that adsorbed amount increases when the particle size of kaolinite increases or when the carbon chain length of quaternary ammonium salts increases.Within the range of flotation collector concentration,the longer the hydrocarbon chain,the more probable to be absolutely adsorbed by fine kaolinite particles and then the lower the collector concentration in the bulk,which leds to lower flotation recovery.

  8. Quaternary Geology and Geomorphology of Terna River Basin in West Central India

    Directory of Open Access Journals (Sweden)

    Mohammad Babar

    2012-12-01

    Full Text Available This paper presents the morphostratigraphy, lithostratigraphy and sedimentary structures of Terna River basin in the Deccan Basaltic Province (DBP of West Central India. These Quaternary deposits have been divided into three informal formations (i dark grey silt formation – Late Holocene, (ii Light grey silt formations – Early Holocene, (iii Dark grayish brown silt formation – Late Pleistocene with the older Quaternary Alluvial deposits of Upper Pleistocene age. The fine clay and silt formations in the lower reaches reflect that the streams are of low gradient and more sinuous. The river shows evidences of channel movement by avulsion, largely controlled by lineaments. Palaeo-levees, in the form 4–5 m high ridges exist along the Terna River floodplain, specifically in the Ter, Killari, Sastur, Dhuta and Makni villages. Several lineaments occur along NE-SW, NW-SE, E-W and WNW-ESE directions, which control the basement structure in the study area. The values of the Topographic Sinuosity Index (TSI indicate rejuvenation of the area leading to the dominance of topography on the sinuosity of the river channels. The break in slope in the long profile is also indication of the Quaternary tectonic uplift of the area. Radiocarbon dating of some charcoal fragments collected from folded beddings indicates that paleoseismic activity might have taken place along the basin between AD 120 and AD 1671.

  9. Partial phase diagram of Pd-Ag-Ru-Gd quaternary system

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    On the basis of the Ag-Pd-Gd, Ag-Ru-Gd and Pd-Ru-Gd ternary systems, the partial phase diagram of Pd-Ag-Ru-Gd(Gd<25% atom fraction) quaternary system has been studied by means of X-ray diffraction analysis, differential thermal analysis, electron probe microanalysis and optical microscopy.The 700℃ isothermal sections of the Ag-Pd-5Ru-Gd, Ag-Pd-20Ru-Gd and Ag-Pd-50Ru-Gd (Gd≤25%atom fraction) phase diagrams were determined respectively. And the 700℃ isothermal section of the PdAg-Ru-Gd (Gd≤25% atom fraction) quaternary system phase diagram was finally irferred. The section consists of four single-phase regions: solid solution Pd(Ag), (Ru), Pd3Gd and Ag51 Gd14; five two-phase regions: Pd(Ag) + (Ru), Pd(Ag) + Ag51 Gd14 , (Ru) + Ag51 Gd14 , Pd(Ag) + Pd3Gd and (Ru) +Pd3Gd; three three-phase regions: Pd(Ag) + Pd3Gd+ (Ru), Pd(Ag) + Ag51Gd14 + (Ru) and (Ru) +Ag51Gd14 + Pd3Gd; one four-phase region Pd(Ag) + (Ru) + Ag51Gd14 + Pd3Gd. No new quaternary intermetallic phase is found.

  10. Painful menstrual periods

    Science.gov (United States)

    Menstruation - painful; Dysmenorrhea; Periods - painful; Cramps - menstrual; Menstrual cramps ... related activities for a few days during each menstrual cycle. Painful menstruation is the leading cause of ...

  11. Hypokalemic periodic paralysis

    National Research Council Canada - National Science Library

    Abbas, Haider; Kothari, Nikhil; Bogra, Jaishri

    2012-01-01

    Hypokalemic periodic paralysis is a rare genetic disorder characterized by recurrent attacks of skeletal muscle weakness with associated hypokalemia which is precipitated by stress, cold, carbohydrate...

  12. Quaternary basaltic volcanism in the Payenia volcanic province, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina

    primitive basalts and trachybasalts but also more evolved samples from the retroarc region and the larger volcanoes Payún Matrú and Payún Liso are presented. The samples cover a broad range of compositions from intraplate lavas similar to ocean island basalts to arc andesites. A common feature found...... Pleistocene times. These basalts mark the end of a period of shallow subduction of the Nazca slab beneath the Payenia province and volcanism in the Nevado volcanic field apparently followed the downwarping slab in a north-northwest direction ending in the Northern Segment. The northern Payenia basalts...... the literature. The Nevado basalts have been modelled by 4-10 % melting of a primitive mantle added 1-5 % upper continental crust. In the southern Payenia province, intraplate basalts dominate. The samples from the Payún Matrú and Río Colorado volcanic fields are apparently unaffected by the subducting slab...

  13. One-year water-ageing of calcium phosphate composite containing nano-silver and quaternary ammonium to inhibit biofilms

    Institute of Scientific and Technical Information of China (English)

    Lei Cheng; Ke Zhang; Chen-Chen Zhou; Michael D Weir; Xue-Dong Zhou; Hockin HK Xu

    2016-01-01

    Dental composites are commonly used restorative materials; however, secondary caries due to biofilm acids remains a major problem. The objectives of this study were (1) to develop a composite containing quaternary ammonium dimethacrylate (QADM), nanoparticles of silver (NAg), and nanoparticles of amorphous calcium phosphate (NACP), and (2) to conduct the first investigation of the mechanical properties, biofilm response and acid production vs water-ageing time from 1 day to 12 months. A 4 × 5 design was utilized, with four composites (NACP-QADM composite, NACP-NAg composite, NACP-QADM-NAg composite, and a commercial control composite), and five water-ageing time periods (1 day, and 3, 6, 9, and 12 months). After each water-ageing period, the mechanical properties of the resins were measured in a three-point flexure, and antibacterial properties were tested via a dental plaque biofilm model using human saliva as an inoculum. After 12 months of water-ageing, NACP-QADM-NAg had a flexural strength and elastic modulus matching those of the commercial control (P40.1). Incorporation of QADM or NAg into the NACP composite greatly reduced biofilm viability, metabolic activity and acid production. A composite containing both QADM and NAg possessed a stronger antibacterial capability than one with QADM or NAg alone (Po0.05). The anti-biofilm activity was maintained after 12 months of water-ageing and showed no significant decrease with increasing time (P40.1). In conclusion, the NACP-QADM-NAg composite decreased biofilm viability and lactic acid production, while matching the load-bearing capability of a commercial composite. There was no decrease in its antibacterial properties after 1 year of water-ageing. The durable antibacterial and mechanical properties indicate that NACP-QADM-NAg composites may be useful in dental restorations to combat caries.

  14. One-year water-ageing of calcium phosphate composite containing nano-silver and quaternary ammonium to inhibit biofilms.

    Science.gov (United States)

    Cheng, Lei; Zhang, Ke; Zhou, Chen-Chen; Weir, Michael D; Zhou, Xue-Dong; Xu, Hockin H K

    2016-09-29

    Dental composites are commonly used restorative materials; however, secondary caries due to biofilm acids remains a major problem. The objectives of this study were (1) to develop a composite containing quaternary ammonium dimethacrylate (QADM), nanoparticles of silver (NAg), and nanoparticles of amorphous calcium phosphate (NACP), and (2) to conduct the first investigation of the mechanical properties, biofilm response and acid production vs water-ageing time from 1 day to 12 months. A 4 × 5 design was utilized, with four composites (NACP-QADM composite, NACP-NAg composite, NACP-QADM-NAg composite, and a commercial control composite), and five water-ageing time periods (1 day, and 3, 6, 9, and 12 months). After each water-ageing period, the mechanical properties of the resins were measured in a three-point flexure, and antibacterial properties were tested via a dental plaque biofilm model using human saliva as an inoculum. After 12 months of water-ageing, NACP-QADM-NAg had a flexural strength and elastic modulus matching those of the commercial control (P>0.1). Incorporation of QADM or NAg into the NACP composite greatly reduced biofilm viability, metabolic activity and acid production. A composite containing both QADM and NAg possessed a stronger antibacterial capability than one with QADM or NAg alone (P0.1). In conclusion, the NACP-QADM-NAg composite decreased biofilm viability and lactic acid production, while matching the load-bearing capability of a commercial composite. There was no decrease in its antibacterial properties after 1 year of water-ageing. The durable antibacterial and mechanical properties indicate that NACP-QADM-NAg composites may be useful in dental restorations to combat caries.

  15. Statistical analyses of soil properties on a quaternary terrace sequence in the upper sava river valley, Slovenia, Yugoslavia

    Science.gov (United States)

    Vidic, N.; Pavich, M.; Lobnik, F.

    1991-01-01

    Alpine glaciations, climatic changes and tectonic movements have created a Quaternary sequence of gravely carbonate sediments in the upper Sava River Valley, Slovenia, Yugoslavia. The names for terraces, assigned in this model, Gu??nz, Mindel, Riss and Wu??rm in order of decreasing age, are used as morphostratigraphic terms. Soil chronosequence on the terraces was examined to evaluate which soil properties are time dependent and can be used to help constrain the ages of glaciofluvial sedimentation. Soil thickness, thickness of Bt horizons, amount and continuity of clay coatings and amount of Fe and Me concretions increase with soil age. The main source of variability consists of solutions of carbonate, leaching of basic cations and acidification of soils, which are time dependent and increase with the age of soils. The second source of variability is the content of organic matter, which is less time dependent, but varies more within soil profiles. Textural changes are significant, presented by solution of carbonate pebbles and sand, and formation is silt loam matrix, which with age becomes finer, with clay loam or clayey texture. The oldest, Gu??nz, terrace shows slight deviation from general progressive trends of changes of soil properties with time. The hypothesis of single versus multiple depositional periods of deposition was tested with one-way analysis of variance (ANOVA) on a staggered, nested hierarchical sampling design on a terrace of largest extent and greatest gravel volume, the Wu??rm terrace. The variability of soil properties is generally higher within subareas than between areas of the terrace, except for the soil thickness. Observed differences in soil thickness between the areas of the terrace could be due to multiple periods of gravel deposition, or to the initial differences of texture of the deposits. ?? 1991.

  16. Second Period Access Report

    DEFF Research Database (Denmark)

    Maisondieu, Christophe; Giebhardt, Jochen; Tetu, Amelie

    The work described in this publication has received support from the European Community - Research Infrastructure Action under the FP7 “Capacities” Specific Programme through grant agreement number 262552, MaRINET. Project Periodic Report. 2nd Period: October 2012 – March 2014 inclusive....

  17. The Living Periodic Table

    Science.gov (United States)

    Nahlik, Mary Schrodt

    2005-01-01

    To help make the abstract world of chemistry more concrete eighth-grade students, the author has them create a living periodic table that can be displayed in the classroom or hallway. This display includes information about the elements arranged in the traditional periodic table format, but also includes visual real-world representations of the…

  18. Latent Period of Relaxation.

    Science.gov (United States)

    Kobayashi, M; Irisawa, H

    1961-10-27

    The latent period of relaxation of molluscan myocardium due to anodal current is much longer than that of contraction. Although the rate and the grade of relaxation are intimately related to both the stimulus condition and the muscle tension, the latent period of relaxation remains constant, except when the temperature of the bathing fluid is changed.

  19. On some periodicity effects

    DEFF Research Database (Denmark)

    Sorokin, Sergey V.

    2015-01-01

    The talk is concerned with the modelling of wave propagation in and vibration of periodic elastic structures. Although analysis of wave-guide properties of infinite periodic structures is a well establish research subject, some issues have not yet been fully addressed in the literature. The aim o...

  20. The Living Periodic Table

    Science.gov (United States)

    Nahlik, Mary Schrodt

    2005-01-01

    To help make the abstract world of chemistry more concrete eighth-grade students, the author has them create a living periodic table that can be displayed in the classroom or hallway. This display includes information about the elements arranged in the traditional periodic table format, but also includes visual real-world representations of the…

  1. Periodic Time Series Models

    NARCIS (Netherlands)

    Ph.H.B.F. Franses (Philip Hans); R. Paap (Richard)

    2004-01-01

    textabstractThis book considers periodic time series models for seasonal data, characterized by parameters that differ across the seasons, and focuses on their usefulness for out-of-sample forecasting. Providing an up-to-date survey of the recent developments in periodic time series, the book

  2. Quaternary nanofossils on the Brazilian continental shelf; Nanofosseis calcarios do quaternario da margem continental brasileira

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, Rogerio Loureiro [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES). Gerencia de Bioestratigrafia e Paleoecologia], E-mail: rlantunes@petrobras.com.br

    2007-07-01

    The study of calcareous nanofossils occurring in the deposits on the Brazilian continental margin began in the late 1960s, undertaken solely by PETROBRAS. Instead of presenting an academic outlook, the purpose of these investigations is first to formulate a biostratigraphic framework to apply to oil well samples. The initial result was the first zoning for the Brazilian continental margin, which considered the deposits formed between the Aptian and Miocene series. Since the 1960s to date, many papers have been written either with details of that original zoning or applying nanofossil biostratigraphy to solve stratigraphic problems. Regardless of all the papers and studies undertaken, little attention has been paid to the Quaternary, since these deposits are normally of no interest to petroleum geology stricto sensu, especially in a large part of the Brazilian margin. On the other hand, there are a few articles and some Master's dissertations and PhD theses that were written and/or are in progress in Brazilian universities. On the other hand, elsewhere in the world, Quaternary nanofossils have been thoroughly investigated in terms of biostratigraphy and paleoceanography. It is, therefore, very clear that there is a gap between what is being done elsewhere in the world and what has been done in Brazil. In fact, this gap is not larger simply because of a few researchers in Brazilian universities who are studying this topic. The intention of this paper is to contribute toward a richer study of Quaternary nanofossils. It, therefore, contains illustrations and taxonomic descriptions of many species observed in the younger strata of the Brazilian margin basins. This article not only aspires to portray and disseminate the potential of nanofossils for the marine Quaternary study but is also an invitation to students (under and post-graduates) and university researchers - an invitation to learn a little more about the subject and spend some time studying these real gems

  3. The New ILP Database of Quaternary Faults and Folds in South America

    Science.gov (United States)

    Costa, C. H.; Cisneros, H. A.; Machette, M. N.; Dart, R. L.

    2003-12-01

    As part of the International Lithosphere Program's Task Group II-2, we have completed the compilation of Quaternary faults and folds in South America and have established an Internet website for this data. The underpinning maps and reports have been released as electronic U.S. Geological Survey Open-File Reports (pdfs, see poster). The maps show the location, time, sense of slip, and activity rate of major earthquake-related features such as faults and fault-related folds. The maps are accompanied by descriptions of their Quaternary activity. The primary elements of the 10-year project are supervision and interpretation of geologic/tectonic information (Costa and Machette), data compilation (project participants), database design and management (Cisneros), and GIS input and management (Dart). A dozen experts in Quaternary faulting, neotectonics, paleoseismology, and seismology compiled the data: questions about individual faults or additions to the database should be directed to them. Prior to this project, digital maps of Quaternary faults did not exist for any of the South America countries, even though understanding the extent and character of active and older Quaternary faults are critical elements of seismic-hazards analysis. These new data will help extend the relatively short record of instrumental and felt seismicity that is the primary parameter for current seismic-hazard assessments in South American countries. Although some fault data were available for most of the countries (i.e., Venezuela), the degree of completeness varies as a function of the remoteness and vegetation cover (i.e., Brazil). A few faults such as the Bocono have had detailed investigations involving modern paleoseismic techniques. Other faults have been studied in some detail, usually in association with concerns about hazards to urban areas or the safety of critical facilities such as mining operations, oil-and-gas pipelines, or power-generating facilities. However, the general state

  4. Map and Data for Quaternary Faults and Fault Systems on the Island of Hawai`i

    Science.gov (United States)

    Cannon, Eric C.; Burgmann, Roland; Crone, Anthony J.; Machette, Michael N.; Dart, Richard L.

    2007-01-01

    Introduction This report and digitally prepared, GIS-based map is one of a series of similar products covering individual states or regions of United States that show the locations, ages, and activity rates of major earthquake-related features such as faults and fault-related folds. It is part of a continuing the effort to compile a comprehensive Quaternary fault and fold map and database for the United States, which is supported by the U.S. Geological Survey's (USGS) Earthquake Hazards Program. Guidelines for the compilation of the Quaternary fault and fold maps for the United States were published by Haller and others (1993) at the onset of this project. This compilation of Quaternary surface faulting and folding in Hawai`i is one of several similar state and regional compilations that were planned for the United States. Reports published to date include West Texas (Collins and others, 1996), New Mexico (Machette and others, 1998), Arizona (Pearthree, 1998), Colorado (Widmann and others, 1998), Montana (Stickney and others, 2000), Idaho (Haller and others, 2005), and Washington (Lidke and others, 2003). Reports for other states such as California and Alaska are still in preparation. The primary intention of this compilation is to aid in seismic-hazard evaluations. The report contains detailed information on the location and style of faulting, the time of most recent movement, and assigns each feature to a slip-rate category (as a proxy for fault activity). It also contains the name and affiliation of the compiler, date of compilation, geographic and other paleoseismologic parameters, as well as an extensive set of references for each feature. The map (plate 1) shows faults, volcanic rift zones, and lineaments that show evidence of Quaternary surface movement related to faulting, including data on the time of most recent movement, sense of movement, slip rate, and continuity of surface expression. This compilation is presented as a digitally prepared map product

  5. Quaternary geologic map of the Winnipeg 4 degrees x 6 degrees quadrangle, United States and Canada

    Science.gov (United States)

    Fullerton, D. S.; Ringrose, S.M.; Clayton, Lee; Schreiner, B.T.; Goebel, J.E.

    2000-01-01

    The Quaternary Geologic Map of the Winnipeg 4? ? 6? Quadrangle, United States and Canada, is a component of the U.S. Geological Survey Quaternary Geologic Atlas of the United States map series (Miscellaneous Investigations Series I-1420), an effort to produce 4? ? 6? Quaternary geologic maps, at 1:1 million scale, of the entire conterminous United States and adjacent Canada. The map and the accompanying text and supplemental illustrations provide a regional overview of the areal distributions and characteristics of surficial deposits and materials of Quaternary age (~1.8 Ma to present) in parts of North Dakota, Minnesota, Manitoba, and Saskatchewan. The map is not a map of soils as soils are recognized in agriculture. Rather, it is a map of soils as recognized in engineering geology, or of substrata or parent materials in which agricultural soils are formed. The map units are distinguished chiefly on the basis of (1)genesis (processes of origin) or environments of deposition: for example, sediments deposited primarily by glacial ice (glacial deposits or till), sediments deposited in lakes (lacustrine deposits), or sediments deposited by wind (eolian deposits); (2) age: for example, how long ago the deposits accumulated; (3) texture (grain size)of the deposits or materials; (4) composition (particle lithology) of the deposits or materials; (5) thickness; and (6) other physical, chemical, and engineering properties. Supplemental illustrations show (1) temporal correlation of the map units, (2) the areal relationships of late Wisconsin glacial ice lobes and sublobes, (3) temporal and spatial correlation of late Wisconsin glacial phases, readvance limits, and ice margin stillstands, (4) temporal and stratigraphic correlation of surface and subsurface glacial deposits in the Winnipeg quadrangle and in adjacent 4? ? 6? quadrangles, and (5) responsibility for state and province compilations. The database provides information related to geologic hazards (for example

  6. Periods and Nori motives

    CERN Document Server

    Huber, Annette

    2017-01-01

    This book casts the theory of periods of algebraic varieties in the natural setting of Madhav Nori’s abelian category of mixed motives. It develops Nori’s approach to mixed motives from scratch, thereby filling an important gap in the literature, and then explains the connection of mixed motives to periods, including a detailed account of the theory of period numbers in the sense of Kontsevich-Zagier and their structural properties. Period numbers are central to number theory and algebraic geometry, and also play an important role in other fields such as mathematical physics. There are long-standing conjectures about their transcendence properties, best understood in the language of cohomology of algebraic varieties or, more generally, motives. Readers of this book will discover that Nori’s unconditional construction of an abelian category of motives (over fields embeddable into the complex numbers) is particularly well suited for this purpose. Notably, Kontsevich's formal period algebra represents a to...

  7. Origin, Extent, and Thickness of Quaternary Geologic Units in the Willamette Valley, Oregon

    Science.gov (United States)

    O'Connor, Jim E.; Sarna-Wojcicki, Andrei M.; Wozniak, Karl C.; Polette, Danial J.; Fleck, Robert J.

    2001-01-01

    Stratigraphic and chronologic information collected for Quaternary deposits in the Willamette Valley, Oregon, provides a revised stratigraphic framework that serves as a basis for a 1:250,000-scale map, as well as for thickness estimates of widespread Quaternary geologic units. We have mapped 11 separate Quaternary units that are differentiated on the basis of stratigraphic, topographic, pedogenic, and hydrogeologic properties. In summation, these units reflect four distinct episodes in the Quaternary geologic development of the Willamette Valley: 1) Fluvial sands and gravels that underlie terraces flanking lowland margins and tributary valleys were probably deposited between 2.5 and 0.5 million years ago. They are the oldest widespread surficial Quaternary deposits in the valley. Their present positions and preservation are undoubtedly due to postdepositional tectonic deformation - either by direct tectonic uplift of valley margins, or by regional tectonic controls on local base level. 2) Tertiary and Quaternary excavation or tectonic lowering of the Willamette Valley accommodated as much as 500 m (meters) of lacustrine and fluvial fill. Beneath the lowland floor, much of the upper 10 to 50 m of fill is Quaternary sand and gravel deposited by braided channel systems in subhorizontal sheets 2 to 10 m thick. These deposits grade to gravel fans 40 to 100 m thick where major Cascade Range rivers enter the valley and are traced farther upstream as much thinner valley trains of coarse gravel. The sand and gravel deposits have ages that range from greater than 420,000 to about 12,000 years old. A widely distributed layer of sand and gravel deposited at about 12 ka (kiloannum, thousands of years before the present) is looser and probably more permeable than older sand and gravel. Stratigraphic exposures and drillers' logs indicate that this late Pleistocene unit is mostly between 5 and 20 m thick where it has not been subsequently eroded by the Willamette River and its

  8. The Quaternary Silver Creek Fault Beneath the Santa Clara Valley, California

    Science.gov (United States)

    Wentworth, Carl M.; Williams, Robert A.; Jachens, Robert C.; Graymer, Russell W.; Stephenson, William J.

    2010-01-01

    The northwest-trending Silver Creek Fault is a 40-km-long strike-slip fault in the eastern Santa Clara Valley, California, that has exhibited different behaviors within a changing San Andreas Fault system over the past 10-15 Ma. Quaternary alluvium several hundred meters thick that buries the northern half of the Silver Creek Fault, and that has been sampled by drilling and imaged in a detailed seismic reflection profile, provides a record of the Quaternary history of the fault. We assemble evidence from areal geology, stratigraphy, paleomagnetics, ground-water hydrology, potential-field geophysics, and reflection and earthquake seismology to determine the long history of the fault in order to evaluate its current behavior. The fault formed in the Miocene more than 100 km to the southeast, as the southwestern fault in a 5-km-wide right step to the Hayward Fault, within which the 40-km-long Evergreen pull-apart basin formed. Later, this basin was obliquely cut by the newly recognized Mt. Misery Fault to form a more direct connection to the Hayward Fault, although continued growth of the basin was sufficient to accommodate at least some late Pliocene alluvium. Large offset along the San Andreas-Calaveras-Mt Misery-Hayward Faults carried the basin northwestward almost to its present position when, about 2 Ma, the fault system was reorganized. This led to near abandonment of the faults bounding the pull-apart basin in favor of right slip extending the Calaveras Fault farther north before stepping west to the Hayward Fault, as it does today. Despite these changes, the Silver Creek Fault experienced a further 200 m of dip slip in the early Quaternary, from which we infer an associated 1.6 km or so of right slip, based on the ratio of the 40-km length of the strike-slip fault to a 5-km depth of the Evergreen Basin. This dip slip ends at a mid-Quaternary unconformity, above which the upper 300 m of alluvial cover exhibits a structural sag at the fault that we interpret as

  9. Significance of Quaternary and Experimental Fluvial Systems to Interpretation of the Stratigraphic Record

    Science.gov (United States)

    Blum, M. D.; Martin, J. M.

    2012-12-01

    Studies of Quaternary and experimental fluvial systems provide significant insight for interpretation of fluvial deposits in the stratigraphic record, ranging from measurement of processes and relevant scales of key architectural elements, to process-based understanding of fluvial systems in sequence stratigraphic models. One key advantage for Quaternary and experimental systems is they commonly provide the ability to test, in a classical verification or falsification sense, interpretations, models and their alternatives that were developed from the stratigraphic record alone. First, scaling relationships developed from Quaternary fluvial deposits can be utilized to constrain interpretations of ancient strata, as well as predict the scale of channel fills, channel-belt sand bodies, and incised valleys. Scaling relationships are defined by power laws, with absolute dimensions that scale to drainage area, water flux, and sediment flux. Width-to-thickness ratios for channel fills range from 10-20:1, whereas channel-belt sand bodies upstream from backwater effects commonly range from 70-300:1, and 20-40:1within the backwater zone, where channel migration is limited. Quaternary incised valleys range from 25-150 m in thickness, and ~5-100 km in width, with width-to-thickness ratios of ~500-800. Scales of Quaternary channel fills and channel-belt sand bodies overlap are consistent with compilations from the ancient record. However, even the smallest Quaternary incised valleys reside in the uppermost part of the domain of published ancient valleys, with ancient examples overlapping significantly with modern channel fills and channel belts. We suggest that many ancient examples have been overinterpreted because of a lack of objective criteria for differentiating channel fills, channel belts, and incised valleys. Second, incised valleys have long played a key role in sequence-stratigraphic interpretations. For incised valleys in the stratigraphic record, either in outcrop or

  10. The Late Quaternary Oxygen Isotope Composition of Lake Michigan

    Science.gov (United States)

    MacDonald, R. A.; Longstaffe, F. J.; Crowe, A. S.

    2007-12-01

    We present stable isotope records for porewater (oxygen, hydrogen) and biogenic carbonates (oxygen, carbon; ostracode and clam shells) in sediment cores from the Chippewa, Milwaukee and South Chippewa Basins of Lake Michigan. The oxygen and hydrogen isotope compositions of porewater from the South Chippewa Basin core showed very little variation with depth. At the maximum depth of 16.6m, δ18O values were within 2‰ and δD values were within 12‰ of modern Lake Michigan water (average δ18O = -5.9‰; average δD = -45‰); original porewater compositions have not been preserved. The oxygen isotope results for the biogenic carbonates, by comparison, provide a record of the isotopic composition of Lake Michigan over the last ~11,000 years, including significant incursions of very low-18O water, as first reported by Colman et al. (1990) and Forester et al. (1994). The low-18O waters originated from the retreating Laurentide ice sheet and may have been routed through Lakes Agassiz and Superior and discharged as large volumes over very short intervals of time. Periods characterized by much higher oxygen isotope compositions likely record the isotopic composition of regional precipitation over the catchment area. In summary, the large variations in the oxygen isotope composition of early Lake Michigan water arose from regional climate change and changing water sources during the times of ice-sheet retreat.

  11. Quaternary Geological Phenomena in Labuhan Area, Pandeglang Regency, Banten Province

    Directory of Open Access Journals (Sweden)

    U. Lumban Batu

    2014-07-01

    Full Text Available DOI: 10.17014/ijog.v7i4.148Geological features in Labuhan area were studied from the middle of October to the middle of November 2011 covering seventy days. Surface and subsurface data were obtained from interpretation of landsat images and shallow hand-auger boreholes. The geological features are distinctly associated with active tectonics. The stratigraphy clearly indicates at least three phases of tectonic activities since the Late Miocene until Holocene. Tectonics of phase one occurred in the Late Miocene; phase two took place in the period from Pliocene to Late Pleistocene, while tectonics phase three is ongoing in the Holocene. Volcanic activity has intensified since the Early Pleistocene. The landsat images show an irregular outline of the northern coast line. This penomenon is interpreted to be the result of tectonic uplift. On the other hand, the southern coast is linear in plan which is interpreted to correlate with tectonic subsidence. Furthermore, stratigraphic correlation shows that depositional environment changed vertically due to a local subsidence. The northern researched area is occupied by Pleistocene volcanic eruption centres, whilst the younger ones tend to shift southward. This fact tends to indicate that the subduction zone moved southward slowly.

  12. Quaternary Geological Phenomena in Labuhan Area, Pandeglang Regency, Banten Province

    Directory of Open Access Journals (Sweden)

    U. Lumban Batu

    2014-07-01

    Full Text Available DOI: 10.17014/ijog.v7i4.148Geological features in Labuhan area were studied from the middle of October to the middle of November 2011 covering seventy days. Surface and subsurface data were obtained from interpretation of landsat images and shallow hand-auger boreholes. The geological features are distinctly associated with active tectonics. The stratigraphy clearly indicates at least three phases of tectonic activities since the Late Miocene until Holocene. Tectonics of phase one occurred in the Late Miocene; phase two took place in the period from Pliocene to Late Pleistocene, while tectonics phase three is ongoing in the Holocene. Volcanic activity has intensified since the Early Pleistocene. The landsat images show an irregular outline of the northern coast line. This penomenon is interpreted to be the result of tectonic uplift. On the other hand, the southern coast is linear in plan which is interpreted to correlate with tectonic subsidence. Furthermore, stratigraphic correlation shows that depositional environment changed vertically due to a local subsidence. The northern researched area is occupied by Pleistocene volcanic eruption centres, whilst the younger ones tend to shift southward. This fact tends to indicate that the subduction zone moved southward slowly.

  13. Spotted hyena and steppe lion predation behaviours on cave bears of Europe - ?Late Quaternary cave bear extinction as result of predator stress

    Science.gov (United States)

    Diedrich, Cajus G.

    2010-05-01

    high alpine regions the leopard Panthera pardus seem to have used the ecological niche of the absent hyenas (Diedrich 2009d, in review a). At open air sites cave bear scavenging by the largest Late Quaternary predators were proven, too (Diedrich 2006, 2009e). The predation stress caused by the three main and largest Late Quaternary predators seem to have provided cave bears to hibernate often deeply in many European caves, and here especially in larger and longer cave systems (e.g. Diedrich et al 2009, in review, Diedrich and Moldovan 2010) to protect themselves against the largest Quaternary predators. In conflicts with those large felids must have been killed by adult cave bears, which explains why those predator carcasses remained as complete skeletons or as partly disarticulated ones even deep in caves all over Europe which were finally not scavenged by the herbivorous cave bears (Diedrich in review). In such cave bear den caves the amount of lion bones generally take only 1-3% of the total bone amount being highly dominated by cave bear bones (Diedrich 2009c, in review). Lions and hyenas seem to have focussed onto the hunt of cave bears all over Europe, especially with the reduction of the biomass in the open environments at the maximum cold period during around 26.000-24.000 BP (Solutrean). The slow extinction of their largest prey was an important motor of the predation pressure onto cave bears. This might be one reason for the cave bear extinction in the final Late Quaternary (early Late Weichselian, maximum cold period) at least in northern Europe, but it seem to have happened in a combination of climatic change, and also human impact (cf. Diedrich, this volume). References Diedrich, C., 2005. Cracking and nibbling marks as indicators for the Upper Pleistocene spotted hyena as a scavenger of cave bear (Ursus spelaeus Rosenmüller, 1794) carcasses in the Perick Caves den of Northwest Germany. Abhandlungen der Naturhistorischen Gesellschaft Nürnberg, 45, 73

  14. Mean-periodic functions

    Directory of Open Access Journals (Sweden)

    Carlos A. Berenstein

    1980-01-01

    Full Text Available We show that any mean-periodic function f can be represented in terms of exponential-polynomial solutions of the same convolution equation f satisfies, i.e., u∗f=0(μ∈E′(ℝn. This extends to n-variables the work of L. Schwartz on mean-periodicity and also extends L. Ehrenpreis' work on partial differential equations with constant coefficients to arbitrary convolutors. We also answer a number of open questions about mean-periodic functions of one variable. The basic ingredient is our work on interpolation by entire functions in one and several complex variables.

  15. Late Quaternary sedimentary features of Bear Lake, Utah and Idaho

    Science.gov (United States)

    Smoot, J.P.

    2009-01-01

    Bear Lake sediments were predominantly aragonite for most of the Holocene, reflecting a hydrologically closed lake fed by groundwater and small streams. During the late Pleistocene, the Bear River flowed into Bear Lake and the lake waters spilled back into the Bear River drainage. At that time, sediment deposition was dominated by siliciclastic sediment and calcite. Lake-level fluctuation during the Holocene and late Pleistocene produced three types of aragonite deposits in the central lake area that are differentiated primarily by grain size, sorting, and diatom assemblage. Lake-margin deposits during this period consisted of sandy deposits including well-developed shoreface deposits on margins adjacent to relatively steep gradient lake floors and thin, graded shell gravel on margins adjacent to very low gradient lake-floor areas. Throughout the period of aragonite deposition, episodic drops in lake level resulted in erosion of shallow-water deposits, which were redeposited into the deeper lake. These sediment-focusing episodes are recognized by mixing of different mineralogies and crystal habits and mixing of a range of diatom fauna into poorly sorted mud layers. Lake-level drops are also indicated by erosional gaps in the shallow-water records and the occurrence of shoreline deposits in areas now covered by as much as 30 m of water. Calcite precipitation occurred for a short interval of time during the Holocene in response to an influx of Bear River water ca. 8 ka. The Pleistocene sedimentary record of Bear Lake until ca. 18 ka is dominated by siliciclastic glacial fl our derived from glaciers in the Uinta Mountains. The Bear Lake deep-water siliciclastic deposits are thoroughly bioturbated, whereas shallow-water deposits transitional to deltas in the northern part of the basin are upward-coarsening sequences of laminated mud, silt, and sand. A major drop in lake level occurred ca. 18 ka, resulting in subaerial exposure of the lake floor in areas now covered by

  16. Biogenicity of an Early Quaternary iron formation, Milos Island, Greece.

    Science.gov (United States)

    Chi Fru, E; Ivarsson, M; Kilias, S P; Frings, P J; Hemmingsson, C; Broman, C; Bengtson, S; Chatzitheodoridis, E

    2015-05-01

    A ~2.0-million-year-old shallow-submarine sedimentary deposit on Milos Island, Greece, harbours an unmetamorphosed fossiliferous iron formation (IF) comparable to Precambrian banded iron formations (BIFs). This Milos IF holds the potential to provide clues to the origin of Precambrian BIFs, relative to biotic and abiotic processes. Here, we combine field stratigraphic observations, stable isotopes of C, S and Si, rock petrography and microfossil evidence from a ~5-m-thick outcrop to track potential biogeochemical processes that may have contributed to the formation of the BIF-type rocks and the abrupt transition to an overlying conglomerate-hosted IF (CIF). Bulk δ(13) C isotopic compositions lower than -25‰ provide evidence for biological contribution by the Calvin and reductive acetyl-CoA carbon fixation cycles to the origin of both the BIF-type and CIF strata. Low S levels of ~0.04 wt.% combined with δ(34) S estimates of up to ~18‰ point to a non-sulphidic depository. Positive δ(30) Si records of up to +0.53‰ in the finely laminated BIF-type rocks indicate chemical deposition on the seafloor during weak periods of arc magmatism. Negative δ(30) Si data are consistent with geological observations suggesting a sudden change to intense arc volcanism potentially terminated the deposition of the BIF-type layer. The typical Precambrian rhythmic rocks of alternating Fe- and Si-rich bands are associated with abundant and spatially distinct microbial fossil assemblages. Together with previously proposed anoxygenic photoferrotrophic iron cycling and low sedimentary N and C potentially connected to diagenetic denitrification, the Milos IF is a biogenic submarine volcano-sedimentary IF showing depositional conditions analogous to Archaean Algoma-type BIFs.

  17. The new basic theory on Quaternary environmental research

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    On the basis of extensive survey to the Quatemary paleosols, soils and weathering layers in the vast northern China and the Loess Plateau, we found some unusually special phenomena of chemical components such as unsuccessive illuvium, twin illuviums, unusually thick illuvium and multi-illuviums etc. According to the analysis on the content of CaCO3 and the data of penetrating experiment, a new theory of illuvial depth or removal depth of CaCO3 in weathering and leaching belt was constructed, which indicates that the time of CaCO3 removing to the illuvial depth is very short,and the effect of time factor on illuvial depth can be ignored. The theory can be taken as a credible foundation for studying many geological and geographical problems in weathering and leaching belt.When the illuvial depth of CaCO3 iS bigger than the thickness of developing belt of soil or paleosol, it can be determined that the paleosol has turned into weathering crust. When the illuvial depth of CaCO3 is bigger than the thickness of paleosol, paleosol is leaching moderately acid soil. When two, three layers or unusually thick CaCO3 illuviums exist in the same weathering section or at the bottom of the same paleosol, there were two or more periods forming paleosol and corresponding climatic stages at that time. On the basis of the equation of relationship between mean annual rainfall (y) and illuvial depth of CaCO3 (x) (y = 305.5x + 168.5) determined in the paper, mean annual precipitation during the development of paleosol can be calculated.

  18. The large terrestrial carnivore guild in Quaternary Southeast Asia

    Science.gov (United States)

    Louys, Julien

    2014-07-01

    Much of Southeast Asia's large terrestrial carnivores appeared, evolved and disappeared from the region for reasons that remain poorly understood. Two of the most significant extinctions are represented by the charismatic Pleistocene megacarnivores Pachycrocuta and Pliocrocuta. Southeast Asia hosts the last populations of these species globally. Their persistence in southern China until the late Pleistocene suggests their extinction was not tied to that of the machairodont cats, which like the rest of the world became extinct sometime in the early Pleistocene in this region. Instead the disappearance of the hyenids is probably related to climate change and deteriorating environmental conditions. There is some evidence that the wolf and domesticated dog first appeared in Southeast Asia, although confirmation of this awaits more detailed fossil records. There does not appear to be a large carnivore guild turnover of the same scale or time as recorded in Europe and Africa, although an extinction event in the late Pleistocene is provisionally recorded. Environmental changes and fluctuating sea levels have had a unique impact on the region's large carnivore guild. Several large carnivores from Java show unique genetic and morphological variations, and this could potentially be related to the connection between Java and the Indochinese mainland sometime during the middle Pleistocene. The effects of islands on the large carnivores are complicated and at times contradictory. Nevertheless, periods of isolation of large carnivores on Java, Sumatra and Borneo from the continent had impacts on both extinctions and speciations, with at least one well documented endemic large carnivore evolving in Sundaland (Sunda clouded leopard). Hunting and deforestation ongoing since the mid- to late Holocene means that many extant members of the large carnivore guild are at high risk of extinction.

  19. Setting the Periodic Table.

    Science.gov (United States)

    Saturnelli, Annette

    1985-01-01

    Examines problems resulting from different forms of the periodic table, indicating that New York State schools use a form reflecting the International Union of Pure and Applied Chemistry's 1984 recommendations. Other formats used and reasons for standardization are discussed. (DH)

  20. The Periodic Table CD.

    Science.gov (United States)

    Banks, Alton J.; Holmes, Jon L.

    1995-01-01

    Describes the characteristics of the digitized version of The Periodic Table Videodisc. Provides details about the organization of information and access to the data via Macintosh and Windows computers. (DDR)

  1. Familial Periodic Paralyses

    Science.gov (United States)

    ... and less severe than the hypokalemic form. Muscle spasms are common. × Definition Familial periodic paralyses are a ... and less severe than the hypokalemic form. Muscle spasms are common. View Full Definition Treatment Treatment of ...

  2. Extremal periodic wave profiles

    Directory of Open Access Journals (Sweden)

    E. van Groesen

    2007-01-01

    Full Text Available As a contribution to deterministic investigations into extreme fluid surface waves, in this paper wave profiles of prescribed period that have maximal crest height will be investigated. As constraints the values of the momentum and energy integrals are used in a simplified description with the KdV model. The result is that at the boundary of the feasible region in the momentum-energy plane, the only possible profiles are the well known cnoidal wave profiles. Inside the feasible region the extremal profiles of maximal crest height are "cornered" cnoidal profiles: cnoidal profiles of larger period, cut-off and periodically continued with the prescribed period so that at the maximal crest height a corner results.

  3. On semi-periods

    CERN Document Server

    Avram, A C; Jancic, D; Uni, H; Uni, Humboldt

    1995-01-01

    The periods of the three-form on a Calabi-Yau manifold are found as solutions of the Picard-Fuchs equations; however, the toric varietal method leads to a generalized hypergeometric system of equations which has more solutions than just the periods. This same extended set of equations can be derived from symmetry considerations. Semi-periods are solutions of this extended system. They are obtained by integration of the three-form over chains; these chains can be used to construct cycles which, when integrated over, give periods. In simple examples we are able to obtain the complete set of solutions for the extended system. We also conjecture that a certain modification of the method will generate the full space of solutions in general.

  4. Setting the Periodic Table.

    Science.gov (United States)

    Saturnelli, Annette

    1985-01-01

    Examines problems resulting from different forms of the periodic table, indicating that New York State schools use a form reflecting the International Union of Pure and Applied Chemistry's 1984 recommendations. Other formats used and reasons for standardization are discussed. (DH)

  5. The Periodic Table CD.

    Science.gov (United States)

    Banks, Alton J.; Holmes, Jon L.

    1995-01-01

    Describes the characteristics of the digitized version of The Periodic Table Videodisc. Provides details about the organization of information and access to the data via Macintosh and Windows computers. (DDR)

  6. Optimal periodic control

    CERN Document Server

    Colonius, Fritz

    1988-01-01

    This research monograph deals with optimal periodic control problems for systems governed by ordinary and functional differential equations of retarded type. Particular attention is given to the problem of local properness, i.e. whether system performance can be improved by introducing periodic motions. Using either Ekeland's Variational Principle or optimization theory in Banach spaces, necessary optimality conditions are proved. In particular, complete proofs of second-order conditions are included and the result is used for various versions of the optimal periodic control problem. Furthermore a scenario for local properness (related to Hopf bifurcation) is drawn up, giving hints as to where to look for optimal periodic solutions. The book provides mathematically rigorous proofs for results which are potentially of importance in chemical engineering and aerospace engineering.

  7. Hyperkalemic periodic paralysis

    Science.gov (United States)

    ... Rott K, Rudel R, Lehmann-Horn F. Muscle channelopathies: myotonias and periodic paralyses. In: Darras BT, Jones ... Elsevier; 2015:chap 38. Kerchner GA, Ptacek LJ. Channelopathies: episodic and electrical disorders of nervous system. In: ...

  8. Hypokalemic periodic paralysis

    Science.gov (United States)

    ... Rott K, Rudel R, Lehmann-Horn F. Muscle channelopathies: myotor and periodic paralyses. In: Darras BT, Jones ... Elsevier; 2015:chap 38. Kerchner GA, Ptacek LJ. Channelopathies. In: Daroff RB, Jankovic J, Mazziotta JC, Pomeroy ...

  9. Historically defined autobiographical periods

    DEFF Research Database (Denmark)

    Brown, Norman R.; Hansen, Tia G. B.; Lee, Peter J.;

    2012-01-01

    The chapter reviews a research programme that has demonstrated the existence of historically defined autobiographical periods and identified the conditions that bring them about. Data from four samples of World War II-generation adults show that historically defined autobiographical periods endure...... over time and theoretical implications are discussed, notably by introducing a new approach to autobiographical memory, Transition Theory, which assumes that autobiographical memory is organized by transitional events that can be selfinitiated or externally imposed - historically defined...

  10. Fracture calcites at Olkiluoto. Evidence from quaternary infills for palaeohydrogeology

    Energy Technology Data Exchange (ETDEWEB)

    Gehoer, S.; Kaerki, A.; Taikina-aho, O. [Kivitieto Oy (Finland); Karhu, J. [Helsinki Univ. (Finland); Loefman, J. [VTT Processes, Espoo (Finland); Pitkaenen, P. [VTT Building and Transport, Espoo (Finland); Ruotsalainen, P. [TUKES, Helsinki (Finland)

    2002-02-01

    Recently formed secondary minerals, predominantly calcite, occur in varying amounts as fracture infills, and the calcite types, their chemical compositions and isotope ratios reflect the compositions and physicochemical factors of the groundwater system in which they were formed. Fluid inclusions trapped in calcites give direct evidence of trapping temperatures and past salinities and of the chemical compositions of the palaeo fluids. A wide range of mineralogical and geochemical examinations were carried out within the EQUIP project to examine features of this kind. The fracture calcites at the Olkiluoto site are of various origins and represent several textural types. The exact number of calcite-producing events is unknown, but the duration of the period that was appropriate for the precipitation of low temperature calcite is estimated to have exceeded 1000 Ma. Thus the number of genetically related calcite units is assumed to be considerable. This study was focused on the petrogenesis of calcites crystallized in fractures of high water conductivity during the latest stages of geological evolution. The majority of these late stage calcites form physically homogeneous, scaly layers, and in a few cases thin layers composed of idiomorphic crystals. Chemically these are almost stoichiometric calcites (CaCO{sub 3}). The MnO content may exceed 1%, while the amounts of other elements present are minor, although the trace element concentrations, particularly those of large ionic trace elements, can be used as distinguishing features for the recognition of individual precipitates representing different calcite generations. Evidence from fluid inclusions, or more correctly from the absence of these in the late stage calcites, can be interpreted as an indication of slow rates of crystallization under cool conditions. Many chemical variables, e.g. oxygen isotope ratios, demonstrate an equilibrium between the latest calcites and water similar to the present groundwater. Older

  11. Mapping the North Sea base-Quaternary: using 3D seismic to fill a gap in the geological record

    Science.gov (United States)

    Lamb, Rachel; Huuse, Mads; Stewart, Margaret; Brocklehurst, Simon H.

    2014-05-01

    The identification and mapping of the base-Quaternary boundary in the central parts of the North Sea is problematic due to the change from an unconformable transition between Pliocene and Pleistocene deltaic deposits in the southern North Sea to a conformable one further north (Sejrup et al 1991; Gatliff et al 1994). The best estimates of the transition use seismic reflection data to identify a 'crenulated reflector' (Buckley 2012), or rely on correlating sparse biostratigraphy (Cameron et al 1987). Recent integration of biostratigraphy, pollen analysis, paleomagnetism and amino acid analysis in the Dutch and Danish sectors (Rasmussen et al 2005; Kuhlmann et al 2006) allows greater confidence in the correlation to a regional 3D seismic dataset and show that the base-Quaternary can be mapped across the entire basin. The base-Quaternary has been mapped using the PGS MegaSurvey dataset from wells in the Danish Sector along the initially unconformable horizon and down the delta front into the more conformable basin giving a high degree of confidence in the horizon pick. The mapped horizon is presented here alongside the difference between this new interpretation and the previously interpreted base-Quaternary (Buckley 2012). The revised base-Quaternary surface reaches a depth of 1248 ms TWT or approximately 1120 m (assuming average velocity of 1800 m/s) showing an elongate basin shape that follows the underlying structure of the Central Graben. The difference between the revised base-Quaternary and the traditional base-Quaternary reaches a maximum of over 600 ms TWT or approximately 540 m in the south-west with over 300 ms TWT or approximately 270 m at the Josephine well (56° 36.11'N, 2° 27.09'E) in the centre of the basin. Mapping this new base-Quaternary allows for the interpretation of the paleo-envionrment during the earliest Quaternary. Seismic attribute analysis indicates a deep water basin with sediment deposition from multiple deltas and redistribution by deep

  12. Versatile methods for synthesizing organic acid salts of quaternary berberine-type alkaloids as anti-ulcerative colitis agents.

    Science.gov (United States)

    Zhang, Zhi-Hui; Li, Jing; Zhang, Hai-Jing; Deng, An-Jun; Wu, Lian-Qiu; Li, Zhi-Hong; Song, Hong-Rui; Wang, Wen-Jie; Qin, Hai-Lin

    2016-06-01

    Two versatile methods to synthesize kinds of organic acid salts of quaternary berberine-type alkaloids were investigated in order to determine which is more efficient to improve the liposolubility of the target compounds and to explore the efficacy of the target compounds as anti-ulcerative colitis (UC) agents. Overall evaluation according to the reaction results and yields of the final products indicated that the synthetic method using tertiary (±)-8-acylmethyldihydroberberine-type alkaloids as key intermediates is superior to that of using tertiary dihydroberberine-type alkaloids as intermediates. Ten target compounds were synthesized using quaternary berberine chloride and quaternary coptisine chloride as starting materials, respectively, and the anti-UC activity of some target compounds was evaluated in an in vitro x-box-binding protein 1 (XBP1) transcriptional activity assay using dual luciferase reporter detection. At 10 μM, the tested compounds were found to activate the transcription of XBP1 target at almost the same level as that of quaternary coptisine chloride. The synthesized target compounds were also found to share higher liposolubility than the inorganic acid salts of quaternary berberine-type alkaloid.

  13. The offshore Yangsan fault activity in the Quaternary, SE Korea: Analysis of high-resolution seismic profiles

    Science.gov (United States)

    Kim, Han-Joon; Moon, Seonghoon; Jou, Hyeong-Tae; Lee, Gwang Hoon; Yoo, Dong Geun; Lee, Sang Hoon; Kim, Kwang Hee

    2016-12-01

    The NNE-trending dextral Yangsan fault is a > 190-km-long structure in the Korean Peninsula traced to the southeastern coast. The scarcity of Quaternary deposits onland precludes any detailed investigation of the Quaternary activity and structure of the Yangsan fault using seismic reflection profiling. We acquired offshore high-resolution seismic profiles to investigate the extension of the Yangsan fault and constrain its Quaternary activity using stratigraphic markers. The seismic profiles reveal a NNE-trending fault system consisting of a main fault and an array of subsidiary faults that displaced Quaternary sequences. Stratigraphic analysis of seismic profiles indicates that the offshore faults were activated repeatedly in the Quaternary. The up-to-the-east sense of throw on the main fault and plan-view pattern of the fault system are explained by dextral strike-slip faulting. The main fault, when projected toward the Korean Peninsula along its strike, aligns well with the Yangsan fault. We suggest that the offshore fault system is a continuation of the Yangsan fault and has spatial correlation with weak but ongoing seismicity.

  14. Sex allocation and functional bias of quaternary and quinary flowers on same inflorescence in the hermaphrodite Ruta graveolens

    Science.gov (United States)

    Tang, Jing-Yu; Ren, Ming-Xun

    2011-09-01

    Intra-inflorescence variation in floral traits is important to understand the pollination function of an inflorescence and the real reproductive outputs of a plant. Ruta graveolens (Rutaceae) produce both quaternary (four petals and eight stamens) and quinary (five petals and ten stamens) flowers on the same cymes, while their pollination roles and the effects on the reproductive success remained unexplored. We experimentally examined the biomass of female versus male organs and pollen viability and stigma receptivity to explore the sex allocation patterns between the flowers. The breeding systems and reproductive outputs through either female function (seed set) or male function (pollen dispersal) were also studied for quinary and quaternary flowers to determine whether there was functional bias. The results showed that R. graveolens was protandrous, with a mixed mating system. Its stamens could slowly move one by one and only dehisce when positioning at the flower center, which could greatly enhance pollen dispersal. The first-opened quinary flower allocated significantly higher resources (dry biomass) in female organs while quaternary flowers allocated more resource in male organs. The quaternary flowers experienced higher pollen limitation in seed production but were more successful in pollen dispersal and the quinary flowers reproduced both through female and male functions. Our data suggested that quinary and quaternary flower on same inflorescence in R. graveolens functioned mainly as the sex role that most resources were allocated, which probably reflect an adaptation for floral phenology and pollination process in this plant.

  15. Treatment for periodic paralysis.

    Science.gov (United States)

    Sansone, V; Meola, G; Links, T P; Panzeri, M; Rose, M R

    2008-01-23

    Primary periodic paralyses are rare inherited muscle diseases characterised by episodes of flaccid weakness affecting one or more limbs, lasting several hours to several days, caused by mutations in skeletal muscle channel genes. The objective of this review was to systematically review treatment of periodic paralyses. We searched the Cochrane Neuromuscular Disease Group Trials Register, MEDLINE (from January 1966 to July 2007), and EMBASE (from January 1980 to July 2007) and any other available international medical library sources from the University of Milan for randomised trials. We included randomised (including cross-over studies) and quasi-randomised trials in participants with primary periodic paralyses, in which any form of treatment, including physical therapy and alternative therapies, was compared to placebo or another treatment. Our primary outcome measure was the change in attack severity or frequency by eight weeks from the start of treatment. Our secondary outcome measures were: change in muscle strength and mass; change in Quality of Life, using Short Form 36 (SF36) or similar; preference of treatment strategy; adverse effects at eight weeks. Three studies met our inclusion criteria. In one study dichlorphenamide (DCP) vs placebo was tested in two groups of participants: 42 with hypokalemic periodic paralysis (HypoPP) and 31 with hyperkalemic periodic paralysis (HyperPP), based on clinical criteria. Thirty-four of 42 participants with hypokalemic periodic paralysis completed both treatment phases. For the 34 participants having attack rate data for both treatment phases, the mean improvement in attack rate (P = 0.02) and severity-weighted attack rate (P = 0.01) on DCP relative to placebo were statistically significant. Fifteen preferred DCP, three placebo and six their baseline medication. Twenty-four of 31 participants with hyperkalemic periodic paralysis completed both treatment phases: for the 16 participants who had attack rate data for both

  16. Magnetostratigraphic age and monsoonal evolution recorded by the thickest Quaternary loess deposit of the Lanzhou region, western Chinese Loess Plateau

    Science.gov (United States)

    Zhang, Jun; Li, Jijun; Guo, Benhong; Ma, Zhenhua; Li, Xiaomiao; Ye, Xiyan; Yu, Hao; Liu, Jia; Yang, Cheng; Zhang, Shengda; Song, Chunhui; Hui, Zhengchuang; Peng, Tingjiang

    2016-05-01

    The loess-paleosol sequences of the Chinese Loess Plateau (CLP) are major paleoclimatic archives which document the evolution of the East Asian Monsoon (EAM) and changes in the Northern Hemisphere ice sheets during the Quaternary glacial-interglacial cycles. However, the mechanisms regulating the trend of EAM variations on a tectonic scale are unclear. The loess deposits of the western CLP, which have a close relationship with tectonics and climate, are much better-suited to exploring these mechanisms than those of the central CLP. However, studies of long-term EAM evolution from the western CLP have been hindered by the lack of long, accurately-dated sequences with high sediment accumulation rates. Here, we address this problem via high resolution magnetostratigraphic, magnetic susceptibility and grain-size analyses of a 416.2 m-long drill core located at Xijin Village, near Lanzhou. Paleomagnetic dating indicates that the basal age of the Xijin loess is ∼2.2 Ma. The χ and grain-size records reveal that the East Asian Summer Monsoon (EASM) and East Asian Winter Monsoon (EAWM) strengthened synchronously at ∼1.24 Ma. Subsequently, during interglacial periods, the EASM began to penetrate, and then dominate, in the Lanzhou region. This was followed by two stepwise uptrends, commencing at ∼0.87 and ∼0.62 Ma, which resulted in an increasingly moist interglacial climate in the region. We suggest that the uplift of the Tibetan Plateau was largely responsible for these three stepwise enhancements of the EASM. Overall, however, the long-term trend of strengthening in EAWM in the area may have been primarily caused by long-term global cooling from the Late Pliocene onwards.

  17. Quaternary fans and terraces in the Khumbu Himal south of Mount Everest: their characteristics, age and formation

    Science.gov (United States)

    Barnard, P.L.; Owen, L.A.; Finkel, R.C.

    2006-01-01

    Large fans and terraces are frequent in the Khumbu Himal within the high Himalayan valleys south of Mt. Everest. These features are composed of massive matrix- and clast-supported diamicts that were formed from both hyperconcentrated flows and coarse-grained debris flows. Cosmogenic radionuclide (CRN) exposure ages for boulders on fans and terraces indicate that periods of fan and terrace formation occurred at c. 16, c. 12, c. 8, c. 4 and c. 1.5 ka, and are broadly coincident with the timing of glaciation in the region. The dating precision is insufficient to resolve whether the surfaces formed before, during or after the correlated glacial advance. However, the sedimentology, and morphostratigraphic and geomorphological relationships suggest that fan and terrace sedimentation in this part of the Himalaya primarily occurs during glacier retreat and is thus paraglacial in origin. Furthermore, modern glacial-lake outburst floods and their associated deposits are common in the Khumbu Himal as the result of glacial retreat during historical times. We therefore suggest that Late Quaternary and Holocene fan and terrace formation and sediment transfer are probably linked to temporal changes in discharge and sediment load caused by glacier oscillations responding to climate change. The timing of major sedimentation events in this region can be correlated with fans and terraces in other parts of the Himalaya, suggesting that major sedimentation throughout the Himalaya is synchronous and tied to regional climatic oscillations. Bedrock incision rates calculated from strath terrace ages average c. 3.9 mm a−1, suggesting that the overall rate of incision is set by regional uplift.

  18. Significance of pre-Quaternary climate change for montane species diversity: insights from Asian salamanders (Salamandridae: Pachytriton).

    Science.gov (United States)

    Wu, Yunke; Wang, Yuezhao; Jiang, Ke; Hanken, James

    2013-01-01

    Despite extensive focus on the genetic legacy of Pleistocene glaciation, impacts of earlier climatic change on biodiversity are poorly understood. Because amphibians are highly sensitive to variations in precipitation and temperature, we use a genus of Chinese montane salamanders (Salamandridae: Pachytriton) to study paleoclimatic change in East Asia, which experienced intensification of its monsoon circulation in the late Miocene associated with subsequent Pliocene warming. Using both nuclear and mitochondrial DNA sequences, we reconstruct the species tree under a coalescent model and demonstrate that all major lineages originated before the Quaternary. Initial speciation within the genus occurred after the summer monsoon entered a stage of substantial intensification. Heavy summer precipitation established temporary water connectivity through overflows between adjacent stream systems, which may facilitate geographic range expansion by aquatic species such as Pachytriton. Species were formed in allopatry likely through vicariant isolation during or after range expansion. To evaluate the influence of Pliocene warming on these cold-adapted salamanders, we construct a novel temperature buffer-zone model, which suggests widespread physiological stress or even extinction during the warming period. A significant deceleration of species accumulation rate is consistent with Pliocene range contraction, which affected P. granulosus and P. archospotus the most because they lack large temperature buffer zones. In contrast, demographic growth occurred in species for which refugia persist. The buffer-zone model reveals the Huangshan Mountain as a potential climatic refugium, which is similar to that found for other East Asian organisms. Our approach can incorporate future climatic data to evaluate the potential impact of ongoing global warming on montane species (particularly amphibians) and to predict possible population declines.

  19. The new basic theory on Quaternary environmental research%第四纪环境研究新理论

    Institute of Scientific and Technical Information of China (English)

    赵景波

    2004-01-01

    On the basis of extensive survey to the Quaternary paleosols, soils and weathering layers in the vast northern China and the Loess Plateau, we found some unusually special phenomena of chemical components such as unsuccessive illuvium, twin illuviums, unusually thick illuvium and multi-illuviums etc. According to the analysis on the content of CaCO3 and the data of penetrating experiment, a new theory of illuvial depth or removal depth of CaCO3 in weathering and leaching belt was constructed, which indicates that the time of CaCO3 removing to the illuvial depth is very short,and the effect of time factor on illuvial depth can be ignored. The theory can be taken as a credible foundation for studying many geological and geographical problems in weathering and leaching belt.When the illuvial depth of CaCO3 is bigger than the thickness of developing belt of soil or paleosol, it can be determined that the paleosol has turned into weathering crust. When the illuvial depth of CaCO3is bigger than the thickness of paleosol, paleosol is leaching moderately acid soil. When two, three layers or unusually thick CaCO3 illuviums exist in the same weathering section or at the bottom of the same paleosol, there were two or more periods forming paleosol and corresponding climatic stages at that time. On the basis of the equation of relationship between mean annual rainfall (y) and illuvial depth of CaCO3 (x) (y = 305.5x + 168.5) determined in the paper, mean annual precipitation during the development of paleosol can be calculated.

  20. Influence of light waves on the thermoelectric power under large magnetic field in III-V, ternary and quaternary materials

    Energy Technology Data Exchange (ETDEWEB)

    Ghatak, K.P. [Department of Electronic Science, The University of Calcutta, 92, Acharya Prafulla Chandra Road, Kolkata 700 009 (India); Bhattacharya, S. [Post Graduate Department of Computer Science, St. Xavier' s College, 30 Park Street, Kolkata 700 016 (India); Pahari, S. [Department of Administration, Jadavpur University, Kolkata 700 032 (India); De, D. [Department of Computer Science and Engineering, West Bengal University of Technology, B. F. 142, Sector I, Salt Lake, Kolkata 700 064 (India); Ghosh, S.; Mitra, M. [Department of Electronics and Telecommunication Engineering, Bengal Engineering and Science University, Howrah 711 103 (India)

    2008-04-15

    We study theoretically the influence of light waves on the thermoelectric power under large magnetic field (TPM) for III-V, ternary and quaternary materials, whose unperturbed energy-band structures, are defined by the three-band model of Kane. The solution of the Boltzmann transport equation on the basis of this newly formulated electron dispersion law will introduce new physical ideas and experimental findings in the presence of external photoexcitation. It has been found by taking n-InAs, n-InSb, n-Hg{sub 1-x}Cd{sub x}Te and n-In{sub 1-x}Ga{sub x}As{sub y}P{sub 1-y} lattice matched to InP as examples that the TPM decreases with increase in electron concentration, and increases with increase in intensity and wavelength, respectively in various manners. The strong dependence of the TPM on both light intensity and wavelength reflects the direct signature of light waves that is in direct contrast as compared with the corresponding bulk specimens of the said materials in the absence of external photoexcitation. The rate of change is totally band-structure dependent and is significantly influenced by the presence of the different energy-band constants. The well-known result for the TPM for nondegenerate wide-gap materials in the absence of light waves has been obtained as a special case of the present analysis under certain limiting conditions and this compatibility is the indirect test of our generalized formalism. Besides, we have also suggested the experimental methods of determining the Einstein relation for the diffusivity:mobility ratio, the Debye screening length and the electronic contribution to the elastic constants for materials having arbitrary dispersion laws. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

  1. Evolution and variation of the Tsushima warm current during the late Quaternary: Evidence from planktonic foraminifera, oxygen and carbon isotopes

    Institute of Scientific and Technical Information of China (English)

    LI TieGang; SUN RongTao; ZHANG DeYu; LIU ZhenXia; LI Qing; JIANG Bo

    2007-01-01

    The evolution and variation history of the Tsushima warm current during the late Quaternary was reconstructed based on the quantitative census data of planktonic foraminiferal fauna, together with oxygen and carbon isotope records of mixed layer dweller G ruber and thermocline dweller N. dutertrei in piston core CSH1 and core DGKS9603 collected separately from the Tsushima warm current and the Kuroshio dominated area. The result showed that the Tsushima warm current vanished in the Iowstand period during 40-24 cai ka BP, while the Kuroshio still flowed across the Okinawa Trough, arousing strong upwelling in the northern Trough. Meanwhile, the influence of freshwater greatly increased in the northern Okinawa Trough, as the broad East China Sea continental shelf emerged. The freshwater reached its maximum during the last glacial maximum (LGM), when the upwelling obviously weakened for the lowest sea-level and the depression of the Kuroshio. The modern Tsushima warm current began its development since 16 cai ka BP, and the impact of the Kuroshio increased in the middle and northern Okinawa Trough synchronously during the deglaciation and gradually evolved as the main water source of the Tsushima current. The modern Tsushima current finally formed at about 8.5 cai ka BP,since then the circulation structure has been relatively stable. The water of the modern Tsushima current primarily came from the Kuroshio axis. A short-term wiggle of the current occurred at about 3 cai ka BP, probably for the influences from the enhancement of the winter monsoon and the depression of the Kuroshio. The cold water masses greatly strengthened during the wiggle.

  2. Evolution and variation of the Tsushima warm current during the late Quaternary: Evidence from planktonic foraminifera, oxygen and carbon isotopes

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The evolution and variation history of the Tsushima warm current during the late Quaternary was reconstructed based on the quantitative census data of planktonic foraminiferal fauna, together with oxygen and carbon isotope records of mixed layer dweller G. ruber and thermocline dweller N. dutertrei in piston core CSH1 and core DGKS9603 collected separately from the Tsushima warm current and the Kuroshio dominated area. The result showed that the Tsushima warm current vanished in the lowstand period during 40―24 cal ka BP, while the Kuroshio still flowed across the Okinawa Trough, arousing strong upwelling in the northern Trough. Meanwhile, the influence of freshwater greatly increased in the northern Okinawa Trough, as the broad East China Sea continental shelf emerged. The freshwater reached its maximum during the last glacial maximum (LGM), when the upwelling obviously weakened for the lowest sea-level and the depression of the Kuroshio. The modern Tsushima warm current began its development since 16 cal ka BP, and the impact of the Kuroshio increased in the middle and north- ern Okinawa Trough synchronously during the deglaciation and gradually evolved as the main water source of the Tsushima current. The modern Tsushima current finally formed at about 8.5 cal ka BP, since then the circulation structure has been relatively stable. The water of the modern Tsushima cur- rent primarily came from the Kuroshio axis. A short-term wiggle of the current occurred at about 3 cal ka BP, probably for the influences from the enhancement of the winter monsoon and the depression of the Kuroshio. The cold water masses greatly strengthened during the wiggle.

  3. A“Yellow Cap” on Quaternary Red Clay in Jiujiang,Jiangxi Province

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    A thin layer of yellow-brown-colored earth was generally found on Quaternary red clay in Jiujing,Jiangxi Province,A typical profile was established.Both particle size distribution and REE(rare earth elements)characteristics of the yellow-brown-colored earth of the profile fully suggested its aeolian origin and close similarity of Nanjing Xiashu Loess.The study also implied aeolian origin of the underlying Quaternary red clay,Compared with the red clay,the yellow-brown-colored earth was less weathered because of its lower content of free iron and higher mole ratios of SiO2/Al2O3 and SiO2(Fe2O3+Al2O3) as well as its less developed chemical microtextures of quartz grains.In order to study the ages of the two deposits comparatively,the thermoluminescent dating method was used.As a result,the bottom of the yellow-brown-colored earth was dated to 60±5 ka B.P.and the upper part of the red clay 388±54 ka B.P.It was suggested that the yellow-brown-colored earth earth was formed in the Late Pleistocene and was probably the aeolian deposit of the Last Glacial,which corresponded with the Malan Loess in the Loess Plateau of the northwestern part of China,while the underlying red clay was formed in the Middle Pleistocene.A“yellow cap” on Quaternary red clay in Jiujiang implied a great climatic and environmental variation in the beginning of the Late Pleistocene in the southern part of China,especially in the middle and lower reaches of the Yangtze River,The event not only halted the rubification,once dominating the region but also produced a widespread covering of aeolian deposit,as only occurred in the cold and dry environment.

  4. Quaternary transgressive and regressive depositional sequences in the East China Sea

    Institute of Scientific and Technical Information of China (English)

    LIUZhenxia; YINPing; XIONGYingqian; S.Beme; A.Trentesaux; LIChaoxin

    2003-01-01

    Based on the interpretation more than 4000 km sparker single channel seismic profiles and the comparison with Borehole DZQ4 on the outer shelf of the East China Sea (ECS),the seismic sequences,sedimentary facies and paleo-sedimentary environment are studied to establish the chronology framework and discuss the Quaternary transgressive and regressive sequences of the ECS shelf as well as their response to glacio-eustatic sea-level changes.The sea level of the ECS fluctuated with global climate changes in the Quaternary.During the sea level rise,the pacific tidal wave impacted actively on the ECS continental shelf and the reciprocating tidal currents in NW-SE direction formed tidal sand ridges,which represent large transgressive deposits visible on the seismic profiles.In response to sea level fall,the Yangtze River deltas prograded seaward and built massive subaqueous deltas to form regressive sequences on the seismic profiles.Alternative transgression and regression sequences were vertically distributed on the ECS shelf with the frequent eustacy in the Quaternary.The gentle slope of the ECS shelf makes it possible for the coastline to migrate hundreds of kilometers forth and back on the shelf because of tens of meters sea level changes,in the meanwhile,the Yangtze River discharged large amounts of sediments into the ECS resulting in large-scale subaqueous deltas and tidal sand ridges.There have developed 3 stages of tidal sand ridges and 4 stages of deltas on the ECS shelf since oxygen isotope stage 8.

  5. Mapping process and age of Quaternary deposits on Santa Rosa Island, Channel Islands National Park, California

    Science.gov (United States)

    Schmidt, K. M.; Minor, S. A.; Bedford, D.

    2016-12-01

    Employing a geomorphic process-age classification scheme, we mapped the Quaternary surficial geology of Santa Rosa (SRI) within the Channel Islands National Park. This detailed (1:12,000 scale) map represents upland erosional transport processes and alluvial, fluvial, eolian, beach, marine terrace, mass wasting, and mixed depositional processes. Mapping was motivated through an agreement with the National Park Service and is intended to aid natural resource assessments, including post-grazing disturbance recovery and identification of mass wasting and tectonic hazards. We obtained numerous detailed geologic field observations, fossils for faunal identification as age control, and materials for numeric dating. This GPS-located field information provides ground truth for delineating map units and faults using GIS-based datasets- high-resolution (sub-meter) aerial imagery, LiDAR-based DEMs and derivative raster products. Mapped geologic units denote surface processes and Quaternary faults constrain deformation kinematics and rates, which inform models of landscape change. Significant findings include: 1) Flights of older Pleistocene (>120 ka) and possibly Pliocene marine terraces were identified beneath younger alluvial and eolian deposits at elevations as much as 275 m above modern sea level. Such elevated terraces suggest that SRI was a smaller, more submerged island in the late Neogene and (or) early Pleistocene prior to tectonic uplift. 2) Structural and geomorphic observations made along the potentially seismogenic SRI fault indicate a protracted slip history during the late Neogene and Quaternary involving early normal slip, later strike slip, and recent reverse slip. These changes in slip mode explain a marked contrast in island physiography across the fault. 3) Many of the steeper slopes are dramatically stripped of regolith, with exposed bedrock and deeply incised gullies, presumably due effects related to past grazing practices. 4) Surface water presence is

  6. Enhanced water-solubility, antibacterial activity and biocompatibility upon introducing sulfobetaine and quaternary ammonium to chitosan.

    Science.gov (United States)

    Chen, Yuxiang; Li, Jianna; Li, Qingqing; Shen, Yuanyuan; Ge, Zaochuan; Zhang, Wenwen; Chen, Shiguo

    2016-06-05

    Chitosan (CS) has attracted much attention due to its good antibacterial activity and biocompatibility. However, CS is insoluble in neutral and alkaline aqueous solution, limiting its biomedical application to some extent. To circumvent this drawback, we have synthesized a novel N-quaternary ammonium-O-sulfobetaine-chitosan (Q3BCS) by introducing quaternary ammonium compound (QAC) and sulfobetaine, and its water-solubility, antibacterial activity and biocompatibility were evaluated compare to N-quaternary ammonium chitosan and native CS. The results showed that by introducing QAC, antibacterial activities and water-solubilities increase with degrees of substitution. The largest diameter zone of inhibition (DIZ) was improved from 0 (CS) to 15mm (N-Q3CS). And the water solution became completely transparent from pH 6.5 to pH 11; the maximal waters-solubility was improved from almost 0% (CS) to 113% at pH 7 (N-Q3CS). More importantly, by further introducing sulfobetaine, cell survival rate of Q3BCS increased from 30% (N-Q3CS) to 85% at 2000μg/ml, which is even greater than that of native CS. Furthermore, hemolysis of Q3BCS was dropped sharply from 4.07% (N-Q3CS) to 0.06%, while the water-solution and antibacterial activity were further improved significantly. This work proposes an efficient strategy to prepare CS derivatives with enhanced antibacterial activity, biocompatibility and water-solubility. Additionally, these properties can be finely tailored by changing the feed ratio of CS, glycidyl trimethylammonium chloride and NCO-sulfobetaine.

  7. Geothermal prospecting by geochemical methods in the Quaternary volcanic province of Dhamar (central Yemen)

    Science.gov (United States)

    Minissale, Angelo; Vaselli, Orlando; Mattash, Mohamed; Montegrossi, Giordano; Tassi, Franco; Ad-Dukhain, Abdulsalam; Kalberkamp, Ulrich; Al-Sabri, Ali; Al-Kohlani, Taha

    2013-01-01

    This paper deals with geothermal prospecting carried out in the Quaternary volcanic field of Dhamar, which is located almost in the centre of the main Oligo-Miocene basaltic trap plateau of Yemen. By applying geochemical and thermometric techniques in domestic wells producing water from the shallow unconfined aquifer in the area, which is prevalently hosted inside the Quaternary volcano-clastic material, a closed thermal anomaly associated with the Quaternary volcanic activity was well delineated. Although the aquifer(s) has a Ca-Na-HCO3 composition, that is typical of shallow groundwater, there are several chemical anomalies in the hotter central area compared to typical aquifers: i) the pH is lower and, consequently, the calculated partial pressure of CO2 in solution is higher, ii) the electrical conductivity is higher, iii) the total salinity is higher and iv) the fluoride ion concentration is higher. Such chemical anomalies in the hotter part of the aquifer do not seem to be generated by the rising and/or mixing of deep hydrothermal components rising into the shallow aquifer, but rather produced by enhanced water-rock interaction processes resulting from the higher temperature of the aquifer and its greater acidity. By applying some speculative calculations, based on the likely temperature of rainfall in the area and the depth and temperature of individual wells, the local thermal gradients in the area have been calculated. The thermal gradient varies from less than the average Earth gradient at the periphery of the delimitated thermal anomaly, to more than 250 °C/km, within an extensive area (exceeding 200 km2) where the gradient is greater than 100/120 °C/km.

  8. Tectonic control on the Late Quaternary hydrography of the Upper Tiber Basin (Northern Apennines, Italy)

    Science.gov (United States)

    Benvenuti, Marco; Bonini, Marco; Moroni, Adriana

    2016-09-01

    We examine the intramontane Upper Tiber Basin in the Northern Apennines (central Italy), where sub-orthogonal fault systems forced river deviation and the abandonment of alluvial fans since the late Middle Pleistocene. Archaeological material, spanning the Middle Palaeolithic-Iron Age, was collected mostly from the surface of the Late Quaternary alluvial landforms and related deposits (MUP and HOL units). This information contributed to the partial dating of seven major stages of drainage development. Normal faults parallel and transverse to the basin trend were active at different times and conditioned the valley pattern of the Middle (MUP1-2)-Late (MUP3) Pleistocene Tiber, Singerna, Sovara and Tignana rivers, which still flow today into the basin. The MUP1 and the MUP3 fans were beheaded by the displacement of their feeder valleys along the basin-transverse Carmine and Montedoglio faults. In some cases, the former feeder rivers underwent stream piracy but their courses mostly deviated in response of the topographic gradient created by faulting, as well as through the incision of new valleys that exploited the lithological contrast along the fault lines. The MUP3 Tignana fan was abandoned mostly due to the activity of the basin-parallel, dip-slip Sansepolcro fault. Subsidence driven by the basin-parallel Anghiari and Sansepolcro fault systems also provided the accommodation space for the MUP3 and HOl1-2 Afra fans between Late Pleistocene and early-mid Holocene. This study exemplifies the interplay between longitudinal and transverse fault systems, and the Late Quaternary hydrographic evolution of an extensional basin settled in the axial zone of an active fold-and-thrust belt. Although the faulting has interacted with the forcing exerted by the Late Quaternary climate fluctuations on the basin drainage systems, the tectonic rates are sufficiently high to represent the prime controller on base-level change and drainage routing patterns.

  9. Transient Quaternary erosion and tectonic inversion of the Northern Range, Trinidad

    Science.gov (United States)

    Arkle, Jeanette C.; Owen, Lewis A.; Weber, John; Caffee, Marc W.; Hammer, Sarah

    2017-10-01

    Cosmogenic 10Be measured in sediments from Northern Range catchments on the island of Trinidad reveals low millennial-scale rates of erosion (average 40 mm/ka) that increase roughly eightfold, from 11 to 92 mm/ka, eastward across the mountain range. These results, in conjunction with an analysis of mountain morphometrics, are consistent with Quaternary east-side-up tilting of the Northern Range, which has occurred recently ( 100 ka). The highest millennial-scale erosion rates coincide spatially with Quaternary east-side surface uplift (albeit not in magnitude), high modern rainfall rates, low topographic relief, and convex longitudinal stream profiles, indicating transient Quaternary erosion. We interpret that hillslope adjustment and erosion of the Northern Range is buffered from climatic and tectonic forcings by dense tropical vegetation cover, thick saprolite, and porous regolith. Compared with longer-term, thermochronology exhumation rates, we document that an order of magnitude deceleration of and reversal in the locus of erosion and exhumation has occurred during the Pliocene to the Holocene. We suggest that these combined data sets highlight distinct syn- and post-collisional phases of Northern Range development that are related to a major change in relative Caribbean-South American plate motion from oblique convergence to transform motion. Oblique collision during the mid-Miocene likely caused relatively higher rates of and asymmetric exhumation of the Northern Range. Post-collisional mountain-scale tilting is likely caused by a combination of crustal extension in the Gulf of Paria and by deep subsurface lithospheric detachment processes that drives dynamic topography.

  10. Fluvial responses to late Quaternary climate change in the Shiyang River drainage system, western China

    Science.gov (United States)

    Gao, Hongshan; Li, Zongmeng; Pan, Baotian; Liu, Fenliang; Liu, Xiaopeng

    2016-04-01

    As a drainage system located in arid western China, the Shiyang River, combined with considerable fluvial strata and landform information, provides an environmental context within which to investigate fluvial responses to late Quaternary climate change. Sedimentological analysis and optically stimulated luminescence (OSL) dating enabled us to reconstruct the processes and fluvial styles of three sedimentary sequences of the Shagou and Hongshui rivers in the Shiyang drainage system. Our results present a variety of river behaviors during the late Quaternary in these areas. In the upstream Shiyang River, Zhangjiadazhuang (ZJDZ) profile of the Shagou was dominated by aggradation and a meandering channel pattern at 10.6-4.2 ka, while a noticeable channel incision occurred at ~ 4.2 ka followed by lateral channel migration. In the downstream Shiyang River, Datugou (DTG) profile of the Hongshui was an aggrading meandering river from 39.7 to 7.2 ka while channel incision occurred at 7.2 ka. Another downstream profile, Wudunwan (WDW) of the Hongshui was also characterized by aggradation from 22.4 to 4.8 ka; however, its channel pattern shifted from braided to meandering at ~ 13 ka. A discernable downcutting event occurred at ~ 4.8 ka, followed by three channel aggradation and incision episodes prior to 1.8 ka. The last 1.8 ka has been characterized by modern channel and floodplain development. The fluvial processes and styles investigated have a close correlation with late Quaternary climate change in the Shiyang River drainage. During cold phases, the WDW reach was dominated by aggradation with a braided channel pattern. During warm phases, the rivers that we investigated were also characterized by aggradation but with meandering channel patterns. Channel incision events and changes of fluvial style occurred mainly during climate transitions.

  11. Beyond BLASTing: tertiary and quaternary structure analysis helps identify major vault proteins.

    Science.gov (United States)

    Daly, Toni K; Sutherland-Smith, Andrew J; Penny, David

    2013-01-01

    We examine the advantages of going beyond sequence similarity and use both protein three-dimensional (3D) structure prediction and then quaternary structure (docking) of inferred 3D structures to help evaluate whether comparable sequences can fold into homologous structures with sufficient lateral associations for quaternary structure formation. Our test case is the major vault protein (MVP) that oligomerizes in multiple copies to form barrel-like vault particles and is relatively widespread among eukaryotes. We used the iterative threading assembly refinement server (I-TASSER) to predict whether putative MVP sequences identified by BLASTp and PSI Basic Local Alignment Search Tool are structurally similar to the experimentally determined rodent MVP tertiary structures. Then two identical predicted quaternary structures from I-TASSER are analyzed by RosettaDock to test whether a pair-wise association occurs, and hence whether the oligomeric vault complex is likely to form for a given MVP sequence. Positive controls for the method are the experimentally determined rat (Rattus norvegicus) vault X-ray crystal structure and the purple sea urchin (Strongylocentrotus purpuratus) MVP sequence that forms experimentally observed vaults. These and two kinetoplast MVP structural homologs were predicted with high confidence value, and RosettaDock predicted that these MVP sequences would dock laterally and therefore could form oligomeric vaults. As the negative control, I-TASSER did not predict an MVP-like structure from a randomized rat MVP sequence, even when constrained to the rat MVP crystal structure (PDB:2ZUO), thus further validating the method. The protocol identified six putative homologous MVP sequences in the heterobolosean Naegleria gruberi within the excavate kingdom. Two of these sequences are predicted to be structurally similar to rat MVP, despite being in excess of 300 residues shorter. The method can be used generally to help test predictions of homology via

  12. Periodic Ising Correlations

    CERN Document Server

    Hystad, Grethe

    2010-01-01

    In this paper, we first rework B. Kaufman's 1949 paper, "Crystal Statistics. II. Partition Function Evaluated by Spinor Analysis", by using representation theory. Our approach leads to a simpler and more direct way of deriving the spectrum of the transfer matrix for the finite periodic Ising model. We then determine formulas for the spin correlation functions that depend on the matrix elements of the induced rotation associated with the spin operator in a basis of eigenvectors for the transfer matrix. The representation of the spin matrix elements is obtained by considering the spin operator as an intertwining map. We exhibit the "new" elements V+ and V- in the Bugrij-Lisovyy formula as part of a holomorphic factorization of the periodic and anti-periodic summability kernels on the spectral curve associated with the induced rotation for the transfer matrix.

  13. Thyrotoxic periodic paralysis

    Directory of Open Access Journals (Sweden)

    Rojith Karandode Balakrishnan

    2011-01-01

    Full Text Available This article aims at highlighting the importance of suspecting thyrotoxicosis in cases of recurrent periodic flaccid paralysis; especially in Asian men to facilitate early diagnosis of the former condition. A case report of a 28 year old male patient with recurrent periodic flaccid paralysis has been presented. Hypokalemia secondary to thyrotoxicosis was diagnosed as the cause of the paralysis. The patient was given oral potassium intervention over 24 hours. The patient showed complete recovery after the medical intervention and was discharged after 24 hours with no residual paralysis. Thyrotoxic periodic paralysis (TPP is a complication of thyrotoxicosis, more common amongst males in Asia. It presents as acute flaccid paralysis in a case of hyperthyroidism with associated hypokalemia. The features of thyrotoxicosis may be subtle or absent. Thus, in cases of recurrent or acute flaccid muscle paralysis, it is important to consider thyrotoxicosis as one of the possible causes, and take measures accordingly.

  14. Hyperthyroid hypokalemic periodic paralysis.

    Science.gov (United States)

    Neki, N S

    2016-01-01

    Hyperthyroid periodic paralysis (HPP) is a rare life threatening complication of hyperthyroidism commonly occurring in young Asian males but sporadically found in other races. It is characterised by hypokalemia and acute onset paraparesis with prevalence of one in one hundred thousand (1 in 100000). The symptoms resolve promptly with potassium supplementation. Nonselective beta blockers like propranol can also be used to ameliorate and prevent subsequent paralytic attack. We report a case of 22 year old male presenting with hyperthyroid periodic paralysis (HPP) having very low serum potassium level.

  15. PALEOSEISMICITY OF QUATERNARY FAULTS NEAR ALBUQUERQUE, NEW MEXICO: The Zia Fault

    OpenAIRE

    McCalpin, James P.

    2001-01-01

    This study continues USGS-funded efforts to assess the activity and earthquake hazard potential of Quaternary faults in the Albuquerque metropolitan region. Our target in 2000 was the Zia fault, a 37 km-long normal fault that trends N-S in northern Llano de Albuquerque (LdA). The Zia fault is one of three major east-dipping normal faults that define the western margin of the Rio Grande rift in the northern Albuquerque basin, the other faults being the Calabacillas fault (to the west of the Zi...

  16. Quaternary volcanism, tectonics, and sedimentation in the Idaho National Engineering Laboratory area

    Energy Technology Data Exchange (ETDEWEB)

    Hackett, W.R.; Smith, R.P.

    1992-09-01

    In this article, we discuss the regional context and describe localities for a two-day field excursion in the vicinity of the Idaho National Engineering Laboratory (INEL). We address several geologic themes: (1) Late Cenozoic, bimodal volcanism of the Eastern Snake River Plain (ESRP), (2) the regional tectonics and structural geology of the Basin and Range province to the northwest of the ESRP, (3) fluvial, lacustrine, and aeolian sedimentation in the INEL area, and (4) the influence of Quaternary volcanism and tectonics on sedimentation near the INEL.

  17. Quaternary volcanism, tectonics, and sedimentation in the Idaho National Engineering Laboratory area

    Energy Technology Data Exchange (ETDEWEB)

    Hackett, W.R.; Smith, R.P.

    1992-01-01

    In this article, we discuss the regional context and describe localities for a two-day field excursion in the vicinity of the Idaho National Engineering Laboratory (INEL). We address several geologic themes: (1) Late Cenozoic, bimodal volcanism of the Eastern Snake River Plain (ESRP), (2) the regional tectonics and structural geology of the Basin and Range province to the northwest of the ESRP, (3) fluvial, lacustrine, and aeolian sedimentation in the INEL area, and (4) the influence of Quaternary volcanism and tectonics on sedimentation near the INEL.

  18. Micropaleontologic record of Quaternary paleoenvironments in the Central Albemarle Embayment, North Carolina, U.S.A.

    Science.gov (United States)

    Culver, Stephen J.; Farrell, Kathleen M.; Mallinson, David J.; Willard, Debra A.; Horton, Benjamin P.; Riggs, Stanley R.; Thieler, E. Robert; Wehmiller, John F.; Parham, Peter; Snyder, Scott W.; Hillier, Caroline

    2011-01-01

    To understand the temporal and spatial variation of eustatic sea-level fluctuations, glacio-hydro-isostacy, tectonics, subsidence, geologic environments and sedimentation patterns for the Quaternary of a passive continental margin, a nearly complete stratigraphic record that is fully integrated with a three dimensional chronostratigraphic framework, and paleoenvironmental information are necessary. The Albemarle Embayment, a Cenozoic regional depositional basin in eastern North Carolina located on the southeast Atlantic coast of the USA, is an ideal setting to unravel these dynamic, interrelated processes.Micropaleontological data, coupled with sedimentologic, chronostratigraphic and seismic data provide the bases for detailed interpretations of paleoenvironmental evolution and paleoclimates in the 90. m thick Quaternary record of the Albemarle Embayment. The data presented here come from a transect of cores drilled through a barrier island complex in the central Albemarle Embayment. This area sits in a ramp-like setting between late Pleistocene incised valleys.The data document the episodic infilling of the Albemarle Embayment throughout the Quaternary as a series of transgressive-regressive (T-R) cycles, characterized by inner shelf, midshelf, and shoreface assemblages, that overlie remnants of fluvial to estuarine valley-fill. Barrier island and marginal marine deposits have a low preservation potential. Inner to mid-shelf deposits of the early Pleistocene are overlain by similar middle Pleistocene shelf sediments in the south of the study area but entirely by inner shelf deposits in the north. Late Pleistocene marine sediments are of inner shelf origin and Holocene deposits are marginal marine in nature. Pleistocene marine sediments are incised, particularly in the northern half of the embayment by lowstand paleovalleys, partly filled by fluvial/floodplain deposits and in some cases, overlain by remnants of transgressive estuarine sediments. The shallowing

  19. Fabrication and properties of HDPE/CF/CaCO3/PE-g-MAH quaternary composites

    Science.gov (United States)

    Wang, X.-L.; Ming, H.; Yin, H.

    2015-07-01

    In this research, carbon fiber (CF) was taken as reinforcing filler, nano calcium carbonate (CaCO3) was taken as toughener, maleic anhydride grafted polyethylene (PE-g-MAH) was taken as compatibilizer for high density polyethylene (HDPE) modification. Through orthogonal test, the influence of different amount of ingredient CF, CaCO3 and PE-g-MAH on the mechanical properties of the HDPE composites was researched. The optimal composition of the quaternary composites with the good toughness and high strength was obtained.

  20. Bio-based ionic liquid crystalline quaternary ammonium salts: properties and applications.

    Science.gov (United States)

    Sasi, Renjith; Rao, Talasila P; Devaki, Sudha J

    2014-03-26

    In the present work, we describe the preparation, properties, and applications of novel ionic liquid crystalline quaternary ammonium salts (QSs) of 3-pentadecylphenol, a bio-based low-cost material derived from cashew nut shell liquid. Amphotropic liquid crystalline phase formation in QSs was characterized using a combination of techniques, such as DSC, PLM, XRD, SEM, and rheology, which revealed the formation of one, two, and three dimensionally ordered mesophases in different length scales. On the basis of these results, a plausible mechanism for the formation of specific modes of packing in various mesophases was proposed. Observation of anisotropic ionic conductivity and electrochemical stability suggests their application as a solid electrolyte.

  1. Geomorphic evidence for enhanced Pliocene-Quaternary faulting in the northwestern Basin and Range

    Science.gov (United States)

    Ellis, Magdalena A; Barnes Jason B,; Colgan, Joseph P.

    2014-01-01

    Mountains in the U.S. Basin and Range Province are similar in form, yet they have different histories of deformation and uplift. Unfortunately, chronicling fault slip with techniques like thermochronology and geodetics can still leave sizable, yet potentially important gaps at Pliocene–Quaternary (∼105–106 yr) time scales. Here, we combine existing geochronology with new geomorphic observations and approaches to investigate the Miocene to Quaternary slip history of active normal faults that are exhuming three footwall ranges in northwestern Nevada: the Pine Forest Range, the Jackson Mountains, and the Santa Rosa Range. We use the National Elevation Dataset (10 m) digital elevation model (DEM) to measure bedrock river profiles and hillslope gradients from these ranges. We observe a prominent suite of channel convexities (knickpoints) that segment the channels into upper reaches with low steepness (mean ksn = ∼182; θref = 0.51) and lower, fault-proximal reaches with high steepness (mean ksn = ∼361), with a concomitant increase in hillslope angles of ∼6°–9°. Geologic maps and field-based proxies for rock strength allow us to rule out static causes for the knickpoints and interpret them as transient features triggered by a drop in base level that created ∼20% of the existing relief (∼220 m of ∼1050 m total). We then constrain the timing of base-level change using paleochannel profile reconstructions, catchment-scale volumetric erosion fluxes, and a stream-power–based knickpoint celerity (migration) model. Low-temperature thermochronology data show that faulting began at ca. 11–12 Ma, yet our results estimate knickpoint initiation began in the last 5 Ma and possibly as recently as 0.1 Ma with reasonable migration rates of 0.5–2 mm/yr. We interpret the collective results to be evidence for enhanced Pliocene–Quaternary fault slip that may be related to tectonic reorganization in the American West, although we cannot rule out climate as a

  2. Dimethyl carbonate synthesis via transesterification catalyzed by quaternary ammonium salt functionalized chitosan

    Institute of Scientific and Technical Information of China (English)

    Yuan Zhao; Liang Nian He; Yuan Yi Zhuang; Jin Quan Wang

    2008-01-01

    A quaternary ammonium salt covalently linked to chitosan was first used as a catalyst for dimethyl carbonate (DMC) synthesis by the transesterification of propylene carbonate (PC) with methanol. The effects of various reaction variables like reaction time, temperature and pressure on the catalytic performance were also investigated. 54% DMC yield and 71% PC conversion were obtained under the optimal reaction conditions. Notably, the catalyst was able to be reused with retention of high catalytic activity and selectivity. Consequently, the process presented here has great potential for industrial application due to its advantages such as stability, easy preparation from renewable biopolymer, and simple separation from products.

  3. Quaternary alloy semiconductor nanobelts with bandgap spanning the entire visible spectrum.

    Science.gov (United States)

    Pan, Anlian; Liu, Ruibin; Sun, Minghua; Ning, Cun-Zheng

    2009-07-15

    We used an improved cothermal evaporation route for the first time to achieve quaternary semiconductor nanostructured alloys, using an example of Zn(x)Cd(1-x)S(y)Se(1-y) nanobelts. The PL (bandgap) of these as-grown nanostructured alloys can be continuously tunable across the entire visible spectrum through experimentally controlling their compositions. Such widely controlled alloy nanostructures via composition/light emission provide a new material platform for applications in wavelength-tunable lasers, multicolor detectors, full-spectrum solar cells, LEDs, and color displays.

  4. A Quaternary Polybenzimidazole Membrane for Intermediate Temperature Polymer Electrolyte Membrane Fuel Cells

    DEFF Research Database (Denmark)

    Xu, C.; Scott, K.; Li, Qingfeng

    2013-01-01

    A quaternary ammonium polybenzimidazole (QPBI) membrane was synthesized for applications in intermediate temperature (100–200 °C) hydrogen fuel cells. The QPBI membrane was imbibed with phosphoric acid to provide suitable proton conductivity. The proton conductivity of the membrane was 0.051 S cm–1...... at 150 °C with the PA acid loading level of 3.5 PRU (amount of H3PO4 per repeat unit of polymer QPBI). The QPBI membrane was characterized in terms of composition, structure and morphology by NMR, FTIR, SEM, and EDX. The fuel cell performance with the membrane gave peak power densities of 440 and 240 m...

  5. Asymmetric synthesis of quaternary aryl amino acid derivatives via a three-component aryne coupling reaction

    Directory of Open Access Journals (Sweden)

    Elizabeth P. Jones

    2011-11-01

    Full Text Available A method was developed for the synthesis of α-alkyl, α-aryl-bislactim ethers in good to excellent yields and high diastereoselectivities, consisting of a facile one-pot procedure in which the aryl group is introduced by means of a nucleophilic addition to benzyne and the alkyl group by alkylation of a resultant benzylic anion. Hydrolysis of the sterically less hindered adducts gave the corresponding quaternary amino acids with no racemization, whereas hydrolytic ring opening gave the corresponding valine dipeptides from bulkier bislactims.

  6. On the Design and Analysis of Quaternary Serial and Parallel Adders

    CERN Document Server

    Das, Anindya; Hasan, Masud

    2010-01-01

    Optimization techniques for decreasing the time and area of adder circuits have been extensively studied for years mostly in binary logic system. In this paper, we provide the necessary equations required to design a full adder in quaternary logic system. We develop the equations for single-stage parallel adder which works as a carry look-ahead adder. We also provide the design of a logarithmic stage parallel adder which can compute the carries within log2(n) time delay for n qudits. At last, we compare the designs and finally propose a hybrid adder which combines the advantages of serial and parallel adder.

  7. The electronic and magnetic properties of quaternary Heusler alloy CoFeMnGe

    Science.gov (United States)

    Seema, K.

    2016-05-01

    We present study of quaternary Heusler alloy CoFeMnGe using density functional theory. The compound is half-metallic with half-metallic gap of 0.13 eV. The total magnetic moment of this compound is 3.96 μB which is in close agreement with Slater-Pauling rule. The effect of lattice compression and expansion shows the robustness of half-metallicity. A large value of half-metallic gap and 100% spin-polarization makes this material interesting for spin dependent applications.

  8. Critical Coalescence Concetration (CCC as a parameter for evaluation of selected quaternary ammonium compounds

    Directory of Open Access Journals (Sweden)

    Danuta Szyszka

    2013-10-01

    Full Text Available The objective of this paper was to determine the Critical Coalescence Concentration (CCC of surfactants such as N(dodecyloxycarboxymethyl N,N,N-(trimethylammonium bromide (DMGM- 12, N-[2-(dodecyoxycarboxyethyl] N,N,N-(trimethylammonium bromide (DMALM-12 and N-[3- (dodecanoyloxycarboxyprophyl] N,N,N-(trimethylammonium bromide (DMPM-11. The surfactants used represent quaternary ammonium compounds containing a hydrophobic moiety with an ester group (commonly known as “esterquats”. The CCC value was determined by analysis of the relationship between concentration of surfactant and average air bubble diameter. The values of the critical coalescence concentration (CCC were estimated using a graphical method.

  9. Bio- and aminostratigraphy of some Quaternary marine deposits in West Greenland

    DEFF Research Database (Denmark)

    Funder, Svend Visby; Simonarson, Leifur A.

    1984-01-01

    age. The mollusc faunas at the sites are distinctly different, although all reflect influx of some subarctic water into Baffin Bay. The fauna from Patorffk is the most diverse subfossil Quaternary fauna known from Baffin Bay. Such species as Panopea Ilorvegica and Balanus hameri indicate conditions...... warmer than the present, although no identical faunal assemblages are known. The fauna at Laksebugt is similar to modem faunas, but the dominating Portlandia arctica and Macoma moesta indicate a climate somewhat colder than the present, and Mytilus edulis suggests the presence of subarctic water...

  10. Ecosystem resilience to abrupt late Quaternary change in continental southern Siberia

    Science.gov (United States)

    Harding, Poppy; Mackay, Anson; Bezrukova, Elena; Shchetnikov, Alexander

    2017-04-01

    Quaternary climate variability is dominated by long term orbital forcing along with abrupt sub-Milankovitch events on the scales of millennia to centuries, driven by internal feedback mechanisms, volcanic forcing and fluctuating solar activity. Although these are well documented in the North Atlantic region, their expression is poorly understood in Siberia, particularly in relation to abrupt climatic events. Siberia has the world's highest level of continentality offering an opportunity to study changes remote from oceanic influences and improving understanding of interactions between the Siberian High and other atmospheric systems including the Aleutian Low, Arctic oscillation and Icelandic Low1 and ENSO2. Understanding of palaeoenvironmental change in Siberia is essential due to the region's high sensitivity to climatic change, with warming rates considerably higher than the global average over the past 50 years3, triggering significant environmental changes, including permafrost degradation, shifts in the forest-steppe biome, increases in forest fires and warming of seasonally ice-covered lakes. Additionally, the region provides essential palaeoenvironmental context for early hominins, for example at globally important sites such as Denisova cave4, and megafauna extinctions5. This presentation outlines ongoing work at Lake Baunt, SE Siberia including: key quaternary climate forcings, the site and its regional context, the key methods and preliminary results. These include a dated record back to ˜30ka BP (based on multiple 14C dates and Bayesian age modelling), multiproxy indicators of palaeoproductivity (e.g. biogenic silica and diatom analyses) and lake mixing regimes (inferred from diatom analyses). Together these highlight several key Quaternary fluctuations potentially correlated to events recorded in Greenland Ice Cores (GS2, GS2.1, GI1, GS1), and these are considered against key Quaternary records including those from nearby Lake Baikal and Hulu Cave in

  11. The Gediz River fluvial archive: A benchmark for Quaternary research in Western Anatolia

    Science.gov (United States)

    Maddy, D.; Veldkamp, A.; Demir, T.; van Gorp, W.; Wijbrans, J. R.; van Hinsbergen, D. J. J.; Dekkers, M. J.; Schreve, D.; Schoorl, J. M.; Scaife, R.; Stemerdink, C.; van der Schriek, T.; Bridgland, D. R.; Aytaç, A. S.

    2017-06-01

    The Gediz River, one of the principal rivers of Western Anatolia, has an extensive Pleistocene fluvial archive that potentially offers a unique window into fluvial system behaviour on the western margins of Asia during the Quaternary. In this paper we review our work on the Quaternary Gediz River Project (2001-2010) and present new data which leads to a revised stratigraphical model for the Early Pleistocene development of this fluvial system. In previous work we confirmed the preservation of eleven buried Early Pleistocene fluvial terraces of the Gediz River (designated GT11, the oldest and highest, to GT1, the youngest and lowest) which lie beneath the basalt-covered plateaux of the Kula Volcanic Province. Deciphering the information locked in this fluvial archive requires the construction of a robust geochronology. Fortunately, the Gediz archive provides ample opportunity for age-constraint based upon age estimates derived from basaltic lava flows that repeatedly entered the palaeo-Gediz valley floors. In this paper we present, for the first time, our complete dataset of 40Ar/39Ar age estimates and associated palaeomagnetic measurements. These data, which can be directly related to the underlying fluvial deposits, provide age constraints critical to our understanding of this sequence. The new chronology establishes the onset of Quaternary volcanism at ∼1320ka (MIS42). This volcanism, which is associated with GT6, confirms a pre-MIS42 age for terraces GT11-GT7. Evidence from the colluvial sequences directly overlying these early terraces suggests that they formed in response to hydrological and sediment budget changes forced by climate-driven vegetation change. The cyclic formation of terraces and their timing suggests they represent the obliquity-driven climate changes of the Early Pleistocene. By way of contrast the GT5-GT1 terrace sequence, constrained by a lava flow with an age estimate of ∼1247ka, span the time-interval MIS42 - MIS38 and therefore do not

  12. Quaternary Oxide of Cerium, Terbium, Praseodymium and Zirconium for Three-Way Catalysts

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Oxygen storagecapacity (OSC), oxygen buffer capacity (OBC), X-ray diffraction and electron diffraction pattern, high resolution electron microscopy were used to study the quaternary oxides, i.e., of Ce, Tb, Pr and Zr. (Ce0.6Tb0.2Zr0.2O2-δ and Ce0.6Pr0.2Zr0.2O2-δ). OSC and OBC data indicate that these oxides have very good oxygen transfer capacity (OTC) and their pseudo-solid solutions exhibit fluorite-type structure. These oxides may act as a good candidate for three-way catalysts (TWC).

  13. Phase Equilibria of Ternary and Quaternary Systems Containing Diethyl Carbonate with Water

    OpenAIRE

    Chen, Yao; Wen, Caiyu; Zhou, Xiaoming; Zeng, Jun

    2014-01-01

    In this study liquid phase equilibrium compositions were measured at 298.15 K under atmospheric pressure for (water + propan-1-ol + diethyl carbonate (DEC) + benzene or cyclohexane or heptane) quaternary systems and (water + DEC + propan-1-ol or benzene or cyclohexane) ternary systems. Good correlation of the experimental LLE data was seen for the measured systems by both modified and extended UNIQUAC models. The solubility of DEC in aqueous and organic phases is shown by equilibrium distribu...

  14. Phase Equilibria of Ternary and Quaternary Systems Containing Diethyl Carbonate with Water.

    Science.gov (United States)

    Chen, Yao; Wen, Caiyu; Zhou, Xiaoming; Zeng, Jun

    2014-01-01

    In this study liquid phase equilibrium compositions were measured at 298.15 K under atmospheric pressure for (water + propan-1-ol + diethyl carbonate (DEC) + benzene or cyclohexane or heptane) quaternary systems and (water + DEC + propan-1-ol or benzene or cyclohexane) ternary systems. Good correlation of the experimental LLE data was seen for the measured systems by both modified and extended UNIQUAC models. The solubility of DEC in aqueous and organic phases is shown by equilibrium distribution coefficients calculated from the LLE data.

  15. Intensity of African Humid Periods Estimated from Saharan Dust Fluxes

    Science.gov (United States)

    Ehrmann, Werner; Schmiedl, Gerhard; Beuscher, Sarah; Krüger, Stefan

    2017-01-01

    North Africa experienced dramatic changes in hydrology and vegetation during the late Quaternary driven by insolation-induced shifts of the tropical rain belt and further modulated by millennial-scale droughts and vegetation-climate feedbacks. While most past proxy and modelling studies concentrated on the temporal and spatial dynamics of the last African humid period, little is known about the intensities and characteristics of pre-Holocene humid periods. Here we present a high-resolution record of fine-grained eastern Saharan dust from the Eastern Mediterranean Sea spanning the last 180 kyr, which is based on the clay mineral composition of the marine sediments, especially the kaolinite/chlorite ratio. Minimum aeolian kaolinite transport occurred during the African Humid Periods because kaolinite deflation was hampered by increased humidity and vegetation cover. Instead, kaolinite weathering from kaolinite-bearing Cenozoic rocks was stored in lake basins, river beds and soils during these periods. During the subsequent dry phases, fine-grained dust was mobilised from the desiccated lakes, rivers and soils resulting in maximum aeolian uptake and transport of kaolinite. The kaolinite transport decreased again when these sediment sources exhausted. We conclude that the amount of clay-sized dust blown out of the Sahara into the Eastern Mediterranean Sea is proportional to the intensity of the kaolinite weathering and accumulation in soils and lake sediments, and thus to the strength of the preceding humid period. These humid periods provided the windows for the migration of modern humans out of Africa, as postulated previously. The strongest humid period occurred during the Eemian and was followed by two weaker phases centred at ca. 100 ka and ca. 80 ka. PMID:28129378

  16. Catalytic enantioselective construction of quaternary stereocenters: assembly of key building blocks for the synthesis of biologically active molecules.

    Science.gov (United States)

    Liu, Yiyang; Han, Seo-Jung; Liu, Wen-Bo; Stoltz, Brian M

    2015-03-17

    The ever-present demand for drugs with better efficacy and fewer side effects continually motivates scientists to explore the vast chemical space. Traditionally, medicinal chemists have focused much attention on achiral or so-called "flat" molecules. More recently, attention has shifted toward molecules with stereogenic centers since their three-dimensional structures represent a much larger fraction of the chemical space and have a number of superior properties compared with flat aromatic compounds. Quaternary stereocenters, in particular, add greatly to the three-dimensionality and novelty of the molecule. Nevertheless, synthetic challenges in building quaternary stereocenters have largely prevented their implementation in drug discovery. The lack of effective and broadly general methods for enantioselective formation of quaternary stereocenters in simple molecular scaffolds has prompted us to investigate new chemistry and develop innovative tools and solutions. In this Account, we describe three approaches to constructing quaternary stereocenters: nucleophilic substitution of 3-halooxindoles, conjugate addition of boronic acids to cyclic enones, and allylic alkylation of enolates. In the first approach, malonic ester nucleophiles attack electrophilic 3-halooxindoles, mediated by a copper(II)-bisoxazoline catalyst. A variety of oxindoles containing a benzylic quaternary stereocenter can be accessed through this method. However, it is only applicable to the specialized 3,3-disubstituted oxindole system. To access benzylic quaternary stereocenters in a more general context, we turned our attention to the enantioselective conjugate addition of carbon nucleophiles to α,β-unsaturated carbonyl acceptors. We discovered that in the presence of catalytic palladium-pyridinooxazoline complex, arylboronic acids add smoothly to β-substituted cyclic enones to furnish ketones with a β-benzylic quaternary stereocenter in high yields and enantioselectivities. The reaction is

  17. Role of quaternary additions on dislocated martensite, retain austenite and mechanical properties of Fe/Cr/C structural steels

    Energy Technology Data Exchange (ETDEWEB)

    Rao, B.V.N.

    1978-02-01

    The influence of quaternary alloy additions of Mn and Ni to Fe/Cr/C steels which have been designed to provide superior mechanical properties has been investigated. Transmission electron microscopy and x-ray analysis revealed increasing amounts of retained austenite with Mn up to 2 w/o and with 5 w/o Ni additions after quenching from 1100/sup 0/C. This is accompanied by a corresponding improvement in toughness properties of the quaternary alloys. In addition, the generally attractive combinations of strength and toughness in these quaternary alloys is attributed to the production of dislocated lath martensite from a homogeneous austenite phase free from undissolved alloy carbides. Grain-refining resulted in a further increase in the amount of retained austenite.

  18. Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters

    KAUST Repository

    Hong, Allen Y.

    2011-12-01

    General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedded in numerous natural products have been developed. The central stereoselective transformation in our divergent strategies is the enantioselective decarboxylative alkylation of seven-membered β-ketoesters to form α-quaternary vinylogous esters. Recognition of the unusual reactivity of β-hydroxyketones resulting from the addition of hydride or organometallic reagents enabled divergent access to γ-quaternary acylcyclopentenes through a ring contraction pathway or γ-quaternary cycloheptenones through a carbonyl transposition pathway. Synthetic applications of these compounds were explored through the preparation of mono-, bi-, and tricyclic derivatives that can serve as valuable intermediates for the total synthesis of complex natural products. This work complements our previous work with cyclohexanoid systems.

  19. Interionic pair potentials and partial structure factors of compound-forming quaternary NaSn liquid alloy: First principle approach

    Indian Academy of Sciences (India)

    Anil Thakur; P K Ahluwalia

    2007-10-01

    In this paper formulae for partial structure factors have been used to study partial structure factors of compound-forming quaternary liquid alloys by considering Hoshino's m-component hard-sphere mixture, which is based on Percus-Yevic equation of Hiroike. Formulae are applied to NaSn (Na, Sn, NaSn, Na3Sn) which is considered as a quaternary liquid mixture with the formation of two compounds simultaneously. We have compared the total structure factors for ternary and quaternary alloys with experimental total structure factors which are found to be in good agreement. This suggests that, for suitable stoichiometric composition, two compounds are formed simultaneously. The hard-sphere diameters needed have been calculated using Troullier and Martins ab-initio pseudopotentials.

  20. Specialization in Plant-Hummingbird Networks Is Associated with Species Richness, Contemporary Precipitation and Quaternary Climate-Change Velocity

    DEFF Research Database (Denmark)

    Dalsgaard, Bo; Magård, Else; Fjeldså, Jon

    2011-01-01

    hypothesis is that contemporary biotic specialization is determined by the degree of past climatic instability, primarily Quaternary climate-change velocity. Other prominent hypotheses predict that either contemporary climate or species richness affect biotic specialization. To gain insight into geographical...... latitudes, with latitude explaining 20-22% of the spatial variation in plant-hummingbird specialization. Potential drivers of specialization--contemporary climate, Quaternary climate-change velocity, and species richness--had superior explanatory power, together explaining 53-64% of the variation...... in specialization. Notably, our data provides empirical evidence for the hypothesized roles of species richness, contemporary precipitation and Quaternary climate-change velocity as key predictors of biotic specialization, whereas contemporary temperature and seasonality seem unimportant in determining...