Nonlocal quasinormal modes for arbitrarily shaped three-dimensional plasmonic resonators
DEFF Research Database (Denmark)
Kamandar Dezfouli, Mohsen; Tserkezis, Christos; Mortensen, N. Asger
2017-01-01
Nonlocal effects have been shown to be responsible for a variety of non-trivial optical effects in small-size plasmonic nanoparticles, beyond classical electrodynamics. However, it is not clear whether optical mode descriptions can be applied to such extreme confinement regimes. Here, we present...... quasinormal modes, even at the single mode level. We exemplify the use of this theory by calculating the Purcell factors of single quantum emitters, the electron energy-loss spectroscopy spatial maps, as well as the Mollow triplet spectra of field-driven quantum dots with and without nonlocal effects...... for different size nanoresonators. Our nonlocal quasinormal mode theory offers a reliable and efficient technique to study both classical and quantum optical problems in nanoplasmonics....
Quasinormal modes in pure de Sitter spacetimes
International Nuclear Information System (INIS)
Du Daping; Wang Bin; Su Ruheng
2004-01-01
We have studied scalar perturbations as well as fermion perturbations in pure de Sitter spacetimes. For scalar perturbations we have shown that well-defined quasinormal modes in d-dimensions can exist provided that the mass of scalar field m>(d-1/2l). The quasinormal modes of fermion perturbations in three and four dimensional cases have also been investigated. We found that different from other dimensional cases, in the three dimensional pure de Sitter spacetime there is no quasinormal mode for the s-wave. This interesting difference caused by the spacial dimensions is true for both scalar and fermion perturbations
Quasinormal modes of Kerr-de Sitter black holes
International Nuclear Information System (INIS)
Yoshida, Shijun; Uchikata, Nami; Futamase, Toshifumi
2010-01-01
We calculate the fundamental quasinormal modes of the Kerr-de Sitter black hole for the first time. In order to calculate the quasinormal modes, we employ the master equations derived by Suzuki, Takasugi, and Umetsu, who transform the Teukolsky equations for the Kerr-de Sitter black hole into the standard form of the Heun's equation. The transformed functions are expanded around the outer horizon of the black hole or the symmetric axis in the Froebenius series whose coefficients satisfy a three-term recurrence relation. These three-term recurrence relations allow us to use Leaver's continued fraction method to calculate the angular separation constant and the quasinormal mode frequency. Any unstable fundamental quasinormal mode is not found in this paper. It is also observed that for some black holes characterized by a large mass parameter, some retrograde modes in the slow rotation limit become prograde as the black hole spin increases. This phenomenon does not occur for the fundamental modes of the Kerr black hole.
Quasinormal-Mode Expansion of the Scattering Matrix
Directory of Open Access Journals (Sweden)
Filippo Alpeggiani
2017-06-01
Full Text Available It is well known that the quasinormal modes (or resonant states of photonic structures can be associated with the poles of the scattering matrix of the system in the complex-frequency plane. In this work, the inverse problem, i.e., the reconstruction of the scattering matrix from the knowledge of the quasinormal modes, is addressed. We develop a general and scalable quasinormal-mode expansion of the scattering matrix, requiring only the complex eigenfrequencies and the far-field properties of the eigenmodes. The theory is validated by applying it to illustrative nanophotonic systems with multiple overlapping electromagnetic modes. The examples demonstrate that our theory provides an accurate first-principles prediction of the scattering properties, without the need for postulating ad hoc nonresonant channels.
Fermionic quasinormal modes for two-dimensional Horava-Lifshitz black holes
Energy Technology Data Exchange (ETDEWEB)
Stetsko, M.M. [Ivan Franko National University of Lviv, Department for Theoretical Physics, Lviv (Ukraine)
2017-06-15
To obtain fermionic quasinormal modes, the Dirac equation for two types of black holes is investigated. It is shown that two different geometries lead to distinctive types of quasinormal modes, while the boundary conditions imposed on the solutions in both cases are identical. For the first type of black hole, the quasinormal modes have continuous spectrum with negative imaginary part that provides the stability of perturbations. For the second type of the black hole, the quasinormal modes have a discrete spectrum and are completely imaginary. (orig.)
Quasi-Normal Modes of Stars and Black Holes
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Kokkotas Kostas
1999-01-01
Full Text Available Perturbations of stars and black holes have been one of the main topics of relativistic astrophysics for the last few decades. They are of particular importance today, because of their relevance to gravitational wave astronomy. In this review we present the theory of quasi-normal modes of compact objects from both the mathematical and astrophysical points of view. The discussion includes perturbations of black holes (Schwarzschild, Reissner-Nordström, Kerr and Kerr-Newman and relativistic stars (non-rotating and slowly-rotating. The properties of the various families of quasi-normal modes are described, and numerical techniques for calculating quasi-normal modes reviewed. The successes, as well as the limits, of perturbation theory are presented, and its role in the emerging era of numerical relativity and supercomputers is discussed.
Quasi-normal modes from non-commutative matrix dynamics
Aprile, Francesco; Sanfilippo, Francesco
2017-09-01
We explore similarities between the process of relaxation in the BMN matrix model and the physics of black holes in AdS/CFT. Focusing on Dyson-fluid solutions of the matrix model, we perform numerical simulations of the real time dynamics of the system. By quenching the equilibrium distribution we study quasi-normal oscillations of scalar single trace observables, we isolate the lowest quasi-normal mode, and we determine its frequencies as function of the energy. Considering the BMN matrix model as a truncation of N=4 SYM, we also compute the frequencies of the quasi-normal modes of the dual scalar fields in the AdS5-Schwarzschild background. We compare the results, and we finda surprising similarity.
A Bloch mode expansion approach for analyzing quasi-normal modes in open nanophotonic structures
DEFF Research Database (Denmark)
de Lasson, Jakob Rosenkrantz; Kristensen, Philip Trøst; Mørk, Jesper
2014-01-01
We present a new method for determining quasi-normal modes in open nanophotonic structures using a modal ex- pansion technique. The outgoing wave boundary condition of the quasi-normal modes is satisfied automatically without absorbing boundaries, representing a significant advantage compared...
Are eikonal quasinormal modes linked to the unstable circular null geodesics?
Directory of Open Access Journals (Sweden)
R.A. Konoplya
2017-08-01
Full Text Available In Cardoso et al. [6] it was claimed that quasinormal modes which any stationary, spherically symmetric and asymptotically flat black hole emits in the eikonal regime are determined by the parameters of the circular null geodesic: the real and imaginary parts of the quasinormal mode are multiples of the frequency and instability timescale of the circular null geodesics respectively. We shall consider asymptotically flat black hole in the Einstein–Lovelock theory, find analytical expressions for gravitational quasinormal modes in the eikonal regime and analyze the null geodesics. Comparison of the both phenomena shows that the expected link between the null geodesics and quasinormal modes is violated in the Einstein–Lovelock theory. Nevertheless, the correspondence exists for a number of other cases and here we formulate its actual limits.
Are eikonal quasinormal modes linked to the unstable circular null geodesics?
Konoplya, R. A.; Stuchlík, Z.
2017-08-01
In Cardoso et al. [6] it was claimed that quasinormal modes which any stationary, spherically symmetric and asymptotically flat black hole emits in the eikonal regime are determined by the parameters of the circular null geodesic: the real and imaginary parts of the quasinormal mode are multiples of the frequency and instability timescale of the circular null geodesics respectively. We shall consider asymptotically flat black hole in the Einstein-Lovelock theory, find analytical expressions for gravitational quasinormal modes in the eikonal regime and analyze the null geodesics. Comparison of the both phenomena shows that the expected link between the null geodesics and quasinormal modes is violated in the Einstein-Lovelock theory. Nevertheless, the correspondence exists for a number of other cases and here we formulate its actual limits.
Exact quasinormal modes for a special class of black holes
International Nuclear Information System (INIS)
Oliva, Julio; Troncoso, Ricardo
2010-01-01
Analytic exact expressions for the quasinormal modes of scalar and electromagnetic perturbations around a special class of black holes are found in d≥3 dimensions. It is shown that the size of the black hole provides a lower bound for the angular momentum of the perturbation. Quasinormal modes appear when this bound is fulfilled; otherwise the excitations become purely damped.
Numerical study of the quasinormal mode excitation of Kerr black holes
International Nuclear Information System (INIS)
Dorband, Ernst Nils; Diener, Peter; Tiglio, Manuel; Berti, Emanuele; Schnetter, Erik
2006-01-01
We present numerical results from three-dimensional evolutions of scalar perturbations of Kerr black holes. Our simulations make use of a high-order accurate multiblock code which naturally allows for adapted grids and smooth inner (excision) and outer boundaries. We focus on the quasinormal ringing phase, presenting a systematic method for extraction of the quasinormal mode frequencies and amplitudes and comparing our results against perturbation theory. The detection of a single mode in a ringdown waveform allows for a measurement of the mass and spin of a black hole; a multimode detection would allow a test of the Kerr nature of the source. Since the possibility of a multimode detection depends on the relative mode amplitude, we study this topic in some detail. The amplitude of each mode depends exponentially on the starting time of the quasinormal regime, which is not defined unambiguously. We show that this time-shift problem can be circumvented by looking at appropriately chosen relative mode amplitudes. From our simulations we extract the quasinormal frequencies and the relative and absolute amplitudes of corotating and counterrotating modes (including overtones in the corotating case). We study the dependence of these amplitudes on the shape of the initial perturbation, the angular dependence of the mode, and the black hole spin, comparing against results from perturbation theory in the so-called asymptotic approximation. We also compare the quasinormal frequencies from our numerical simulations with predictions from perturbation theory, finding excellent agreement. For rapidly rotating black holes (of spin j=0.98) we can extract the quasinormal frequencies of not only the fundamental mode, but also of the first two overtones. Finally we study under what conditions the relative amplitude between given pairs of modes gets maximally excited and present a quantitative analysis of rotational mode-mode coupling. The main conclusions and techniques of our
Quasinormal modes of semiclassical electrically charged black holes
Energy Technology Data Exchange (ETDEWEB)
Fernandez Piedra, Owen Pavel [Departamento de Fisica y Quimica, Facultad de Mecanica, Universidad de Cienfuegos, Carretera a Rodas, km 4, Cuatro Caminos, Cienfuegos (Cuba); De Oliveira, Jeferson, E-mail: opavel@ucf.edu.cu, E-mail: jeferson@fma.if.usp.br [Instituto de Fisica, Universidade de Sao Paulo, CP 66318, 05315-970, Sao Paulo (Brazil)
2011-04-21
We report the results concerning the influence of vacuum polarization due to quantum massive vector, scalar and spinor fields on the scalar sector of quasinormal modes in spherically symmetric charged black holes. The vacuum polarization from quantized fields produces a shift in the values of the quasinormal frequencies, and correspondingly the semiclassical system becomes a better oscillator with respect to the classical Reissner-Nordstroem black hole.
Quasinormal modes of a strongly coupled nonconformal plasma and approach to criticality
Betzios, Panagiotis; Gürsoy, Umut; Järvinen, Matti; Policastro, Giuseppe
2018-04-01
We study fluctuations around equilibrium in a class of strongly interacting nonconformal plasmas using holographic techniques. In particular, we calculate the quasinormal mode spectrum of black hole backgrounds that approach Chamblin-Reall plasmas in the IR. In a specific limit, related to the exact linear-dilaton background in string theory, we observe that the plasma approaches criticality and we obtain the quasinormal spectrum analytically. We regulate the critical limit by gluing the IR geometry that corresponds to the nonconformal plasma to a part of AdS space-time in the UV. Near criticality, the spectrum can still be computed analytically and we find two sets of quasinormal modes, related to the IR and UV parts of the geometry. In the critical limit, the quasinormal modes accumulate to form a branch cut in the correlators of the energy-momentum tensor on the real axis of the complex frequency plane.
Regularized quasinormal modes for plasmonic resonators and open cavities
Kamandar Dezfouli, Mohsen; Hughes, Stephen
2018-03-01
Optical mode theory and analysis of open cavities and plasmonic particles is an essential component of optical resonator physics, offering considerable insight and efficiency for connecting to classical and quantum optical properties such as the Purcell effect. However, obtaining the dissipative modes in normalized form for arbitrarily shaped open-cavity systems is notoriously difficult, often involving complex spatial integrations, even after performing the necessary full space solutions to Maxwell's equations. The formal solutions are termed quasinormal modes, which are known to diverge in space, and additional techniques are frequently required to obtain more accurate field representations in the far field. In this work, we introduce a finite-difference time-domain technique that can be used to obtain normalized quasinormal modes using a simple dipole-excitation source, and an inverse Green function technique, in real frequency space, without having to perform any spatial integrations. Moreover, we show how these modes are naturally regularized to ensure the correct field decay behavior in the far field, and thus can be used at any position within and outside the resonator. We term these modes "regularized quasinormal modes" and show the reliability and generality of the theory by studying the generalized Purcell factor of dipole emitters near metallic nanoresonators, hybrid devices with metal nanoparticles coupled to dielectric waveguides, as well as coupled cavity-waveguides in photonic crystals slabs. We also directly compare our results with full-dipole simulations of Maxwell's equations without any approximations, and show excellent agreement.
Quasinormal modes for massless topological black holes
International Nuclear Information System (INIS)
Aros, Rodrigo; Martinez, Cristian; Troncoso, Ricardo; Zanelli, Jorge
2003-01-01
An exact expression for the quasinormal modes of scalar perturbation on a massless topological black hole in four and higher dimensions is presented. The massive scalar field is nonminimally coupled to the curvature, and the horizon geometry is assumed to have a negative constant curvature
Quasinormal modes of the near extremal Schwarzschild-de Sitter black hole
International Nuclear Information System (INIS)
Cardoso, Vitor; Lemos, Jose P.S.
2003-01-01
We present an exact expression for the quasinormal modes of scalar, electromagnetic, and gravitational perturbations of a near extremal Schwarzschild-de Sitter black hole and we show that is why a previous approximation holds exactly in this near extremal regime. In particular, our results give the asymptotic behavior of the quasinormal frequencies for highly damped modes, which has recently attracted much attention due to the proposed identification of its real part with the Barbero-Immirzi parameter
Quasinormal modes of Schwarzschild black holes: Defined and calculated via Laplace transformation
International Nuclear Information System (INIS)
Nollert, H.; Schmidt, B.G.
1992-01-01
Quasinormal modes play a prominent role in the literature when dealing with the propagation of linearized perturbations of the Schwarzschild geometry. We show that space-time properties of the solutions of the perturbation equation imply the existence of a unique Green's function of the Laplace-transformed wave equation. This Green's function may be constructed from solutions of the homogeneous time-independent equation, which are uniquely characterized by the boundary conditions they satisfy. These boundary conditions are identified as the boundary conditions usually imposed for quasinormal-mode solutions. It turns out that solutions of the homogeneous equation exist which satisfy these boundary conditions at the horizon and at spatial infinity simultaneously, leading to poles of the Green's function. We therefore propose to define quasinormal-mode frequencies as the poles of the Green's function for the Laplace-transformed equation. On the basis of this definition a new technique for the numerical calculation of quasinormal frequencies is developed. The results agree with computations of Leaver, but not with more recent results obtained by Guinn, Will, Kojima, and Schutz
Mesonic quasinormal modes of the Sakai-Sugimoto model at high temperature
International Nuclear Information System (INIS)
Evans, Nick; Threlfall, Ed
2008-01-01
We examine the mesonic thermal spectrum of the Sakai-Sugimoto model of holographic QCD by finding the quasinormal frequencies of the supergravity dual. If flavor is added using D8-D8 branes there exist embeddings where the D-brane world volume contains a black hole. For these embeddings (the high-temperature phase of the Sakai-Sugimoto model) we determine the quasinormal spectra of scalar and vector mesons arising from the world volume Dirac-Born-Infeld (DBI) action of the D-brane. We stress the importance of a coordinate change that makes the infalling quasinormal modes regular at the horizon allowing a simple numerical shooting technique. Finally we examine the effect of finite spatial momentum on quasinormal spectra
Lifshitz quasinormal modes and relaxation from holography
Sybesma, Watse|info:eu-repo/dai/nl/369283074; Vandoren, Stefan|info:eu-repo/dai/nl/304830739
2015-01-01
We obtain relaxation times for field theories with Lifshitz scaling and with holographic duals Einstein-Maxwell-Dilaton gravity theories. This is done by computing quasinormal modes of a bulk scalar field in the presence of Lifshitz black branes. We determine the relation between relaxation time and
Quasinormal modes of asymptotically (A)dS black hole in Lovelock background
Abbasvandi, N.; Soleimani, M. J.; Abdullah, W. A. T. Wan; Radiman, Shahidan
2017-03-01
We study the quasinormal modes of the massless scalar field in asymptotically (A)dS black holes in Lovelock spacetime by using the sixth order of the WKB approximation. We consider the effects of the second and third order of Lovelock coupling constants on quasinormal frequencies spectrum as well as cosmological constant.
Quasinormal Modes of a Quantum-Corrected Schwarzschild Black ...
Indian Academy of Sciences (India)
Chunyan Wang
2017-11-27
Nov 27, 2017 ... Abstract. In this work, we investigate the electromagnetic perturbation around a quantum-corrected. Schwarzschild black hole. The complex frequencies of the quasinormal modes are evaluated by the third- order WKB approximation. The numerical results obtained showed that the complex frequencies ...
Perturbative calculation of quasinormal modes of AdS Schwarzschild black holes
International Nuclear Information System (INIS)
Musiri, Suphot; Ness, Scott; Siopsis, George
2006-01-01
We calculate analytically quasinormal modes of AdS Schwarzschild black holes including first-order corrections. We consider massive scalar, gravitational and electromagnetic perturbations. Our results are in good agreement with numerical calculations. In the case of electromagnetic perturbations, ours is the first calculation to provide an analytic expression for quasinormal frequencies, because the effective potential vanishes at zeroth order. We show that the first-order correction is logarithmic
Wormhole potentials and throats from quasi-normal modes
Völkel, Sebastian H.; Kokkotas, Kostas D.
2018-05-01
Exotic compact objects refer to a wide class of black hole alternatives or effective models to describe phenomenologically quantum gravitational effects on the horizon scale. In this work we show how the knowledge of the quasi-normal mode spectrum of non-rotating wormhole models can be used to reconstruct the effective potential that appears in perturbation equations. From this it is further possible to obtain the parameters that characterize the specific wormhole model, which in this paper was chosen to be the one by Damour and Solodukhin. We also address the question whether one can distinguish such type of wormholes from ultra compact stars, if only the quasi-normal mode spectrum is known. We have proven that this is not possible by using the trapped modes only, but requires additional information. The inverse method presented here is an extension of work that has previously been developed and applied to the oscillation spectra of ultra compact stars and gravastars. However, it is not limited to the study of exotic compact objects, but applicable to symmetric double barrier potentials that appear in one-dimensional wave equations. Therefore we think it can be of interest for other fields too.
International Nuclear Information System (INIS)
Daghigh, Ramin G; Green, Michael D
2009-01-01
We analyze analytically the asymptotic regions of the quasinormal mode frequency spectra with infinitely large overtone numbers for D-dimensional Schwarzschild black holes in anti de Sitter spacetimes. In this limit, we confirm the analytic results obtained previously in the literature using different methods. In addition, we show that in certain spacetime dimensions these techniques imply the existence of other regions of the asymptotic quasinormal mode frequency spectrum which have not previously appeared in the literature. For large black holes, some of these modes have a damping rate of 1.2T H , where T H is the Hawking temperature. This is less than the damping rate of the lowest overtone quasinormal mode calculated by other authors. It is not completely clear whether these modes actually exist or are an artifact of an unknown flaw in the analytic techniques being used. We discuss the possibility of the existence of these modes and explore some of the consequences. We also examine the possible connection between the asymptotic quasinormal modes of Schwarzschild-anti de Sitter black holes and the quantum level spacing of their horizon area spectrum.
Quasinormal modes and classical wave propagation in analogue black holes
International Nuclear Information System (INIS)
Berti, Emanuele; Cardoso, Vitor; Lemos, Jose P.S.
2004-01-01
Many properties of black holes can be studied using acoustic analogues in the laboratory through the propagation of sound waves. We investigate in detail sound wave propagation in a rotating acoustic (2+1)-dimensional black hole, which corresponds to the 'draining bathtub' fluid flow. We compute the quasinormal mode frequencies of this system and discuss late-time power-law tails. Because of the presence of an ergoregion, waves in a rotating acoustic black hole can be superradiantly amplified. We also compute superradiant reflection coefficients and instability time scales for the acoustic black hole bomb, the equivalent of the Press-Teukolsky black hole bomb. Finally we discuss quasinormal modes and late-time tails in a nonrotating canonical acoustic black hole, corresponding to an incompressible, spherically symmetric (3+1)-dimensional fluid flow
Quasi-normal frequencies: Semi-analytic results for highly damped modes
International Nuclear Information System (INIS)
Skakala, Jozef; Visser, Matt
2011-01-01
Black hole highly-damped quasi-normal frequencies (QNFs) are very often of the form ω n = (offset) + in (gap). We have investigated the genericity of this phenomenon for the Schwarzschild-deSitter (SdS) black hole by considering a model potential that is piecewise Eckart (piecewise Poschl-Teller), and developing an analytic 'quantization condition' for the highly-damped quasi-normal frequencies. We find that the ω n = (offset) + in (gap) behaviour is common but not universal, with the controlling feature being whether or not the ratio of the surface gravities is a rational number. We furthermore observed that the relation between rational ratios of surface gravities and periodicity of QNFs is very generic, and also occurs within different analytic approaches applied to various types of black hole spacetimes. These observations are of direct relevance to any physical situation where highly-damped quasi-normal modes are important.
Quasinormal modes of Gauss-Bonnet black holes at large D
Energy Technology Data Exchange (ETDEWEB)
Chen, Bin [Department of Physics and State Key Laboratory of Nuclear Physics and Technology,Peking University,No. 5 Yiheyuan Rd, Beijing 100871 (China); Collaborative Innovation Center of Quantum Matter,No. 5 Yiheyuan Rd, Beijing 100871 (China); Center for High Energy Physics, Peking University,No. 5 Yiheyuan Rd, Beijing 100871 (China); Fan, Zhong-Ying [Center for High Energy Physics, Peking University,No. 5 Yiheyuan Rd, Beijing 100871 (China); Li, Pengcheng; Ye, Weicheng [Department of Physics and State Key Laboratory of Nuclear Physics and Technology,Peking University,No. 5 Yiheyuan Rd, Beijing 100871 (China)
2016-01-15
Einstein’s General Relativity theory simplifies dramatically in the limit that the spacetime dimension D is very large. This could still be true in the gravity theory with higher derivative terms. In this paper, as the first step to study the gravity with a Gauss-Bonnet(GB) term, we compute the quasi-normal modes of the spherically symmetric GB black hole in the large D limit. When the GB parameter is small, we find that the non-decoupling modes are the same as the Schwarzschild case and the decoupled modes are slightly modified by the GB term. However, when the GB parameter is large, we find some novel features. We notice that there are another set of non-decoupling modes due to the appearance of a new plateau in the effective radial potential. Moreover, the effective radial potential for the decoupled vector-type and scalar-type modes becomes more complicated. Nevertheless we manage to compute the frequencies of the these decoupled modes analytically. When the GB parameter is neither very large nor very small, though analytic computation is not possible, the problem is much simplified in the large D expansion and could be numerically treated. We study numerically the vector-type quasinormal modes in this case.
Perturbations and quasi-normal modes of black holes in Einstein-Aether theory
International Nuclear Information System (INIS)
Konoplya, R.A.; Zhidenko, A.
2007-01-01
We develop a new method for calculation of quasi-normal modes of black holes, when the effective potential, which governs black hole perturbations, is known only numerically in some region near the black hole. This method can be applied to perturbations of a wide class of numerical black hole solutions. We apply it to the black holes in the Einstein-Aether theory, a theory where general relativity is coupled to a unit time-like vector field, in order to observe local Lorentz symmetry violation. We found that in the non-reduced Einstein-Aether theory, real oscillation frequency and damping rate of quasi-normal modes are larger than those of Schwarzschild black holes in the Einstein theory
Stretched horizons, quasiparticles, and quasinormal modes
International Nuclear Information System (INIS)
Iizuka, Norihiro; Kabat, Daniel; Lifschytz, Gilad; Lowe, David A.
2003-01-01
We propose that stretched horizons can be described in terms of a gas of noninteracting quasiparticles. The quasiparticles are unstable, with a lifetime set by the imaginary part of the lowest quasinormal mode frequency. If the horizon arises from an AdS-CFT style duality the quasiparticles are also the effective low-energy degrees of freedom of the finite-temperature CFT. We analyze a large class of models including Schwarzschild black holes, nonextremal Dp-branes, the rotating BTZ black hole and de Sitter space, and we comment on degenerate horizons. The quasiparticle description makes manifest the relationship between entropy and area
Wang, Mengjie; Herdeiro, Carlos; Jing, Jiliang
2017-11-01
We study Dirac quasinormal modes of Schwarzschild-anti-de Sitter (Schwarzschild-AdS) black holes, following the generic principle for allowed boundary conditions proposed in [M. Wang, C. Herdeiro, and M. O. P. Sampaio, Phys. Rev. D 92, 124006 (2015)., 10.1103/PhysRevD.92.124006]. After deriving the equations of motion for Dirac fields on the aforementioned background, we impose vanishing energy flux boundary conditions to solve these equations. We find a set of two Robin boundary conditions are allowed. These two boundary conditions are used to calculate Dirac normal modes on empty AdS and quasinormal modes on Schwarzschild-AdS black holes. In the former case, we recover the known normal modes of empty AdS; in the latter case, the two sets of Robin boundary conditions lead to two different branches of quasinormal modes. The impact on these modes of the black hole size, the angular momentum quantum number and the overtone number are discussed. Our results show that vanishing energy flux boundary conditions are a robust principle, applicable not only to bosonic fields but also to fermionic fields.
Stability analysis and quasinormal modes of Reissner–Nordstrøm ...
Indian Academy of Sciences (India)
2016-06-09
Jun 9, 2016 ... They also determine important features of the space-time and give important information on the background geometry. The Lyapunov exponent (λ) has been used to probe the instability of circular null geodesics and in terms of the quasinormal modes (QNMs) for spherically symmetric space-time of arbitrary ...
Quasi-normal modes of extremal BTZ black holes in TMG
Afshar, Hamid R.; Alishahiha, Mohsen; Mosaffa, Amir E.
2010-08-01
We study the spectrum of tensor perturbations on extremal BTZ black holes in topologically massive gravity for arbitrary values of the coefficient of the Chern-Simons term, μ. Imposing proper boundary conditions at the boundary of the space and at the horizon, we find that the spectrum contains quasi-normal modes.
Breit-Wigner resonances and the quasinormal modes of anti-de Sitter black holes
International Nuclear Information System (INIS)
Berti, Emanuele; Cardoso, Vitor; Pani, Paolo
2009-01-01
We show that the theory of Breit-Wigner resonances can be used as an efficient numerical tool to compute black hole quasinormal modes. For illustration, we focus on the Schwarzschild anti-de Sitter (SAdS) spacetime. The resonance method is better suited to small SAdS black holes than the traditional series expansion method, allowing us to confirm that the damping time scale of small SAdS black holes for scalar and gravitational fields is proportional to r + -2l-2 , where r + is the horizon radius. The proportionality coefficients are in good agreement with analytic calculations. We also examine the eikonal limit of SAdS quasinormal modes, confirming quantitatively Festuccia and Liu's [arXiv:0811.1033] prediction of the existence of very long-lived modes. Our results are particularly relevant for the AdS/CFT correspondence, since long-lived modes presumably dominate the decay time scale of the perturbations.
International Nuclear Information System (INIS)
Severini, S.; Settimi, A.; Sibilia, C.; Bertolotti, M.; Napoli, A.; Messina, A.
2004-01-01
An extension of the second quantization scheme based on the quasinormal-modes theory to one-dimensional photonic band gap (PBG) structures is discussed. Such structures, treated as double open optical cavities, are studied as part of a compound closed system including the electromagnetic radiative external bath. The electromagnetic field inside the photonic crystal is successfully represented by a new class of modes called quasinormal modes. Starting from this representation we introduce the Feynman's propagator to calculate the decay rate of a dipole inside a PBG structure, related to the density of modes, in the presence of the vacuum fluctuations outside the one-dimensional cavity
A comparative study of Dirac quasinormal modes of charged black holes in higher dimensions
International Nuclear Information System (INIS)
Chakrabarti, Sayan K.
2009-01-01
In this work we study the Dirac quasinormal modes of higher dimensional charged black holes. Higher dimensional Reissner-Nordstroem type black holes as well as charged black holes in Einstein-Gauss-Bonnet theories are studied for fermionic perturbations using WKB method. A comparative study of the quasinormal modes in the two different theories of gravity has been performed. The behavior of the frequencies with the variation of black hole parameters as well as with the variation of space-time dimensions is studied. We also study the large multipole number limit of the black hole potential in order to look for an analytic expression for the frequencies. (orig.)
Quasinormal Modes and Strong Cosmic Censorship
Cardoso, Vitor; Costa, João L.; Destounis, Kyriakos; Hintz, Peter; Jansen, Aron
2018-01-01
The fate of Cauchy horizons, such as those found inside charged black holes, is intrinsically connected to the decay of small perturbations exterior to the event horizon. As such, the validity of the strong cosmic censorship (SCC) conjecture is tied to how effectively the exterior damps fluctuations. Here, we study massless scalar fields in the exterior of Reissner-Nordström-de Sitter black holes. Their decay rates are governed by quasinormal modes of the black hole. We identify three families of modes in these spacetimes: one directly linked to the photon sphere, well described by standard WKB-type tools; another family whose existence and time scale is closely related to the de Sitter horizon; finally, a third family which dominates for near-extremally charged black holes and which is also present in asymptotically flat spacetimes. The last two families of modes seem to have gone unnoticed in the literature. We give a detailed description of linear scalar perturbations of such black holes, and conjecture that SCC is violated in the near extremal regime.
Hawking Radiation-Quasinormal Modes Correspondence for Large AdS Black Holes
Directory of Open Access Journals (Sweden)
Dao-Quan Sun
2017-01-01
Full Text Available It is well-known that the nonstrictly thermal character of the Hawking radiation spectrum generates a natural correspondence between Hawking radiation and black hole quasinormal modes. This main issue has been analyzed in the framework of Schwarzschild black holes, Kerr black holes, and nonextremal Reissner-Nordstrom black holes. In this paper, by introducing the effective temperature, we reanalyze the nonstrictly thermal character of large AdS black holes. The results show that the effective mass corresponding to the effective temperature is approximatively the average one in any dimension. And the other effective quantities can also be obtained. Based on the known forms of frequency in quasinormal modes, we reanalyze the asymptotic frequencies of the large AdS black hole in three and five dimensions. Then we get the formulas of the Bekenstein-Hawking entropy and the horizon’s area quantization with functions of the quantum “overtone” number n.
Accretion-induced quasinormal mode excitation of a Schwarzschild black hole
International Nuclear Information System (INIS)
Nagar, Alessandro; Zanotti, Olindo; Font, Jose A.; Rezzolla, Luciano
2007-01-01
By combining the numerical solution of the nonlinear hydrodynamics equations with the solution of the linear inhomogeneous Zerilli-Moncrief and Regge-Wheeler equations, we investigate the properties of the gravitational radiation emitted during the axisymmetric accretion of matter onto a Schwarzschild black hole. The matter models considered include quadrupolar dust shells and thick accretion disks, permitting us to simulate situations which may be encountered at the end stages of stellar gravitational collapse or binary neutron star merger. We focus on the interference pattern appearing in the energy spectra of the emitted gravitational waves and on the amount of excitation of the quasinormal modes of the accreting black hole. We show that, quite generically in the presence of accretion, the black-hole ringdown is not a simple superposition of quasinormal modes, although the fundamental mode is usually present and often dominates the gravitational-wave signal. We interpret this as due to backscattering of waves off the nonexponentially decaying part of the black-hole potential and to the finite spatial extension of the accreting matter. Our results suggest that the black-hole QNM contributions to the full gravitational-wave signal should be extremely small and possibly not detectable in generic astrophysical scenarios involving the accretion of extended distributions of matter
Area spectrum of extremal Reissner-Nordstroem black holes from quasinormal modes
International Nuclear Information System (INIS)
Setare, M.R.
2004-01-01
Using the quasinormal mode frequency of extremal Reissner-Nordstroem black holes, we obtain the area spectrum for these types of black holes. We show that the area and entropy black hole horizon are equally spaced. Our results for the spacing of the area spectrum differ from that for Schwarzschild black holes
Directory of Open Access Journals (Sweden)
Sergio C. Ulhoa
2017-01-01
Full Text Available In this paper we investigate scalar perturbations of black holes embedded in a five-dimensional bulk space. The quasinormal frequencies of such black holes are calculated using the third order of Wentzel, Kramers, and Brillouin (WKB approximation for scalar perturbations. The high overtones of quasinormal modes indicate a resonant-like set of black holes suggesting a serious constraint of embedding models in five dimensions.
Quasinormal modes of black holes in Lovelock gravity
Yoshida, Daiske; Soda, Jiro
2016-02-01
We study quasinormal modes of black holes in Lovelock gravity. We formulate the WKB method adapted to Lovelock gravity for the calculation of quasinormal frequencies (QNFs). As a demonstration, we calculate various QNFs of Lovelock black holes in seven and eight dimensions. We find that the QNFs show remarkable features depending on the coefficients of the Lovelock terms, the species of perturbations, and spacetime dimensions. In the case of the scalar field, when we increase the coefficient of the third order Lovelock term, the real part of QNFs increases, but the decay rate becomes small irrespective of the mass of the black hole. For small black holes, the decay rate ceases to depend on the Gauss-Bonnet term. In the case of tensor type perturbations of the metric field, the tendency of the real part of QNFs is opposite to that of the scalar field. The QNFs of vector type perturbations of the metric show no particular behavior. The behavior of QNFs of the scalar type perturbations of the metric field is similar to the vector type. However, available data are rather sparse, which indicates that the WKB method is not applicable to many models for this sector.
Quasinormal modes of four-dimensional topological nonlinear charged Lifshitz black holes
Energy Technology Data Exchange (ETDEWEB)
Becar, Ramon [Universidad Cato lica de Temuco, Departamento de Ciencias Matematicas y Fisicas, Temuco (Chile); Gonzalez, P.A. [Universidad Diego Portales, Facultad de Ingenieria, Santiago (Chile); Vasquez, Yerko [Universidad de La Serena, Departamento de Fisica, Facultad de Ciencias, La Serena (Chile)
2016-02-15
We study scalar perturbations of four- dimensional topological nonlinear charged Lifshitz black holes with spherical and plane transverse sections, and we find numerically the quasinormal modes for scalar fields. Then we study the stability of these black holes under massive and massless scalar field perturbations. We focus our study on the dependence of the dynamical exponent, the nonlinear exponent, the angular momentum, and the mass of the scalar field in the modes. It is found that the modes are overdamped, depending strongly on the dynamical exponent and the angular momentum of the scalar field for a spherical transverse section. In contrast, for plane transverse sections the modes are always overdamped. (orig.)
Geodesic stability, Lyapunov exponents, and quasinormal modes
International Nuclear Information System (INIS)
Cardoso, Vitor; Miranda, Alex S.; Berti, Emanuele; Witek, Helvi; Zanchin, Vilson T.
2009-01-01
Geodesic motion determines important features of spacetimes. Null unstable geodesics are closely related to the appearance of compact objects to external observers and have been associated with the characteristic modes of black holes. By computing the Lyapunov exponent, which is the inverse of the instability time scale associated with this geodesic motion, we show that, in the eikonal limit, quasinormal modes of black holes in any dimensions are determined by the parameters of the circular null geodesics. This result is independent of the field equations and only assumes a stationary, spherically symmetric and asymptotically flat line element, but it does not seem to be easily extendable to anti-de Sitter spacetimes. We further show that (i) in spacetime dimensions greater than four, equatorial circular timelike geodesics in a Myers-Perry black-hole background are unstable, and (ii) the instability time scale of equatorial null geodesics in Myers-Perry spacetimes has a local minimum for spacetimes of dimension d≥6.
Partition functions in even dimensional AdS via quasinormal mode methods
International Nuclear Information System (INIS)
Keeler, Cynthia; Ng, Gim Seng
2014-01-01
In this note, we calculate the one-loop determinant for a massive scalar (with conformal dimension Δ) in even-dimensional AdS d+1 space, using the quasinormal mode method developed in http://dx.doi.org/10.1088/0264-9381/27/12/125001 by Denef, Hartnoll, and Sachdev. Working first in two dimensions on the related Euclidean hyperbolic plane H 2 , we find a series of zero modes for negative real values of Δ whose presence indicates a series of poles in the one-loop partition function Z(Δ) in the Δ complex plane; these poles contribute temperature-independent terms to the thermal AdS partition function computed in http://dx.doi.org/10.1088/0264-9381/27/12/125001. Our results match those in a series of papers by Camporesi and Higuchi, as well as Gopakumar et al. http://dx.doi.org/10.1007/JHEP11(2011)010 and Banerjee et al. http://dx.doi.org/10.1007/JHEP03(2011)147. We additionally examine the meaning of these zero modes, finding that they Wick-rotate to quasinormal modes of the AdS 2 black hole. They are also interpretable as matrix elements of the discrete series representations of SO(2,1) in the space of smooth functions on S 1 . We generalize our results to general even dimensional AdS 2n , again finding a series of zero modes which are related to discrete series representations of SO(2n,1), the motion group of H 2n .
Quasinormal modes of BTZ black hole and Hawking-like radiation in graphene
Energy Technology Data Exchange (ETDEWEB)
Kandemir, B.S.; Ertem, Uemit [Department of Physics, Ankara University, Faculty of Sciences, 06100, Tandogan-Ankara (Turkey)
2017-04-15
The Banados-Teitelboim-Zanelli (BTZ) black hole model corresponds to a solution of (2+1)-dimensional Einstein gravity with negative cosmological constant, and by a conformal rescaling its metric can be mapped onto the hyperbolic pseudosphere surface (Beltrami trumpet) with negative curvature. Beltrami trumpet shaped graphene sheets have been predicted to emit Hawking radiation that is experimentally detectable by a scanning tunnelling microscope. Here, for the first time we present an analytical algorithm that allows variational solutions to the Dirac Hamiltonian of graphene pseudoparticles in BTZ black hole gravitational field by using an approach based on the formalism of pseudo-Hermitian Hamiltonians within a discrete-basis-set method. We show that our model not only reproduces the exact results for the real part of quasinormal mode frequencies of (2+1)-dimensional spinless BTZ black hole, but also provides analytical results for the real part of quasinormal modes of spinning BTZ black hole, and also offers some predictions for the observable effects with a view to gravity-like phenomena in a curved graphene sheet. (copyright 2017 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Quasinormal modes of modified gravity (MOG) black holes
Manfredi, Luciano; Mureika, Jonas; Moffat, John
2018-04-01
The Quasinormal modes (QNMs) for gravitational and electromagnetic perturbations are calculated in a Scalar-Tensor-Vector (Modified Gravity) spacetime, which was initially proposed to obtain correct dynamics of galaxies and galaxy clusters without the need for dark matter. It is found that for the increasing model parameter α, both the real and imaginary parts of the QNMs decrease compared to those for a standard Schwarzschild black hole. On the other hand, when taking into account the 1 / (1 + α) mass re-scaling factor present in MOG, Im (ω) matches almost identically that of GR, while Re (ω) is higher. These results can be identified in the ringdown phase of massive compact object mergers, and are thus timely in light of the recent gravitational wave detections by LIGO.
International Nuclear Information System (INIS)
Uchikata, Nami; Yoshida, Shijun
2011-01-01
We investigate quasinormal modes of a massless charged scalar field on a small Reissner-Nordstroem-anti-de Sitter (RN-AdS) black hole both with analytical and numerical approaches. In the analytical approach, by using the small black hole approximation (r + + /L→0, where r + and L stand for the black hole event horizon radius and the AdS scale, respectively. We then show that the small RN-AdS black hole is unstable if its quasinormal modes satisfy the superradiance condition and that the instability condition of the RN-AdS black hole in the limit of r + /L→0 is given by Q>(3/eL)Q c , where Q, Q c , and e are the charge of the black hole, the critical (maximum) charge of the black hole, and the charge of the scalar field, respectively. In the numerical approach, we calculate the quasinormal modes for the small RN-AdS black holes with r + + =0.2L, 0.1L, and 0.01L become unstable against scalar perturbations with eL=4 when the charge of the black hole satisfies Q > or approx. 0.8Q c , 0.78Q c , and 0.76Q c , respectively.
Self-force calculations with matched expansions and quasinormal mode sums
International Nuclear Information System (INIS)
Casals, Marc; Dolan, Sam; Ottewill, Adrian C.; Wardell, Barry
2009-01-01
Accurate modeling of gravitational wave emission by extreme-mass ratio inspirals is essential for their detection by the LISA mission. A leading perturbative approach involves the calculation of the self-force acting upon the smaller orbital body. In this work, we present the first application of the Poisson-Wiseman-Anderson method of 'matched expansions' to compute the self-force acting on a point particle moving in a curved spacetime. The method employs two expansions for the Green function, which are, respectively, valid in the 'quasilocal' and 'distant past' regimes, and which may be matched together within the normal neighborhood. We perform our calculation in a static region of the spherically symmetric Nariai spacetime (dS 2 xS 2 ), in which scalar-field perturbations are governed by a radial equation with a Poeschl-Teller potential (frequently used as an approximation to the Schwarzschild radial potential) whose solutions are known in closed form. The key new ingredients in our study are (i) very high order quasilocal expansions and (ii) expansion of the distant past Green function in quasinormal modes. In combination, these tools enable a detailed study of the properties of the scalar-field Green function. We demonstrate that the Green function is singular whenever x and x ' are connected by a null geodesic, and apply asymptotic methods to determine the structure of the Green function near the null wave front. We show that the singular part of the Green function undergoes a transition each time the null wave front passes through a caustic point, following a repeating fourfold sequence δ(σ), 1/πσ, -δ(σ), -1/πσ, etc., where σ is Synge's world function. The matched-expansion method provides insight into the nonlocal properties of the self-force. We show that the self-force generated by the segment of the worldline lying outside the normal neighborhood is not negligible. We apply the matched-expansion method to compute the scalar self-force acting on
Behavior of quasinormal modes and high dimension RN-AdS black hole phase transition
Energy Technology Data Exchange (ETDEWEB)
Chabab, M.; Iraoui, S.; Masmar, K. [Cadi Ayyad University, High Energy Physics and Astrophysics Laboratory, Faculty of Science Semlalia, Marrakesh (Morocco); El Moumni, H. [Cadi Ayyad University, High Energy Physics and Astrophysics Laboratory, Faculty of Science Semlalia, Marrakesh (Morocco); Ibn Zohr University, LMTI, Physics Department, Faculty of Sciences, Agadir (Morocco)
2016-12-15
In this work we use the quasinormal frequencies of a massless scalar perturbation to probe the phase transition of the high dimension charged AdS black hole. The signature of the critical behavior of this black hole solution is detected in the isobaric as well as in isothermal process. This paper is a natural generalization of Liu et al. (JHEP 1409:179, 2014) to higher dimensional spacetime. More precisely our study shows a clear signal for any dimension d in the isobaric process. As to the isothermal case, we find that this signature can be affected by other parameters like the pressure and the horizon radius. We conclude that the quasinormal modes can be an efficient tool to investigate the first-order phase transition, but fail to disclose the signature of the second-order phase transition. (orig.)
Highly damped quasinormal modes of generic single-horizon black holes
Energy Technology Data Exchange (ETDEWEB)
Daghigh, Ramin G [Physics Department, University of Winnipeg, Winnipeg, Manitoba R3B 2E9 (Canada); Kunstatter, Gabor [Winnipeg Institute for Theoretical Physics, Winnipeg, Manitoba (Canada)
2005-10-07
We calculate analytically the highly damped quasinormal mode spectra of generic single-horizon black holes using the rigorous WKB techniques of Andersson and Howls (2004 Class. Quantum Grav. 21 1623). We thereby provide a firm foundation for previous analysis, and point out some of their possible limitations. The numerical coefficient in the real part of the highly damped frequency is generically determined by the behaviour of coupling of the perturbation to the gravitational field near the origin, as expressed in tortoise coordinates. This fact makes it difficult to understand how the famous ln(3) could be related to the quantum gravitational microstates near the horizon.
Thermodynamics, phase transition and quasinormal modes with Weyl corrections
Energy Technology Data Exchange (ETDEWEB)
Mahapatra, Subhash [The Institute of Mathematical Sciences,Chennai 600113 (India)
2016-04-21
We study charged black holes in D dimensional AdS space, in the presence of four derivative Weyl correction. We obtain the black hole solution perturbatively up to first as well as second order in the Weyl coupling, and show that first law of black hole thermodynamics is satisfied in all dimensions. We study its thermodynamic phase transition and then calculate the quasinormal frequencies of the massless scalar field perturbation. We find that, here too, the quasinormal frequencies capture the essence of black hole phase transition. Few subtleties near the second order critical point are discussed.
International Nuclear Information System (INIS)
Gonzalez, P.A.; Moncada, Felipe; Vasquez, Yerko
2012-01-01
We study scalar perturbations in the background of a topological Lifshitz black hole in four dimensions. We compute analytically the quasinormal modes and from these modes we show that topological Lifshitz black hole is stable. On the other hand, we compute the reflection and transmission coefficients and the absorption cross section and we show that there is a range of modes with high angular momentum which contributes to the absorption cross section in the low frequency limit. Furthermore, in this limit, we show that the absorption cross section decreases if the scalar field mass increases, for a real scalar field mass. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Gonzalez, P.A. [Universidad Central de Chile, Escuela de Ingenieria Civil en Obras Civiles, Facultad de Ciencias Fisicas y Matematicas, Santiago (Chile); Universidad Diego Portales, Santiago (Chile); Moncada, Felipe; Vasquez, Yerko [Universidad de La Frontera, Departamento de Ciencias Fisicas, Facultad de Ingenieria, Ciencias y Administracion, Temuco (Chile)
2012-12-15
We study scalar perturbations in the background of a topological Lifshitz black hole in four dimensions. We compute analytically the quasinormal modes and from these modes we show that topological Lifshitz black hole is stable. On the other hand, we compute the reflection and transmission coefficients and the absorption cross section and we show that there is a range of modes with high angular momentum which contributes to the absorption cross section in the low frequency limit. Furthermore, in this limit, we show that the absorption cross section decreases if the scalar field mass increases, for a real scalar field mass. (orig.)
AdS/CFT correspondence, quasinormal modes, and thermal correlators in N=4 SYM
Nunez, Alvaro; Starinets, Andrei O.
2003-01-01
We use the Lorentzian AdS/CFT prescription to find the poles of the retarded thermal Green's functions of ${\\cal N=4}$ SU(N) SYM theory in the limit of large N and large 't Hooft coupling. In the process, we propose a natural definition for quasinormal modes in an asymptotically AdS spacetime, with boundary conditions dictated by the AdS/CFT correspondence. The corresponding frequencies determine the dispersion laws for the quasiparticle excitations in the dual finite-temperature gauge theory...
Konoplya, R. A.; Zhidenko, A.
2017-09-01
Here we shall show that there is no other instability for the Einstein-Gauss-Bonnet-anti-de Sitter (AdS) black holes, than the eikonal one and consider the features of the quasinormal spectrum in the stability sector in detail. The obtained quasinormal spectrum consists from the two essentially different types of modes: perturbative and non-perturbative in the Gauss-Bonnet coupling α. The sound and hydrodynamic modes of the perturbative branch can be expressed through their Schwazrschild-AdS limits by adding a linear in α correction to the damping rates: ω≈Re ω SAdS -Im ω SAdS(1- α·(( D+1)( D-4) /2 R 2)) i, where R is the AdS radius. The non-perturbative branch of modes consists of purely imaginary modes, whose damping rates unboundedly increase when α goes to zero. When the black hole radius is much larger than the anti-de Sitter radius R, the regime of the black hole with planar horizon (black brane) is reproduced. If the Gauss-Bonnet coupling α (or used in holography λGB) is not small enough, then the black holes and branes suffer from the instability, so that the holographic interpretation of perturbation of such black holes becomes questionable, as, for example, the claimed viscosity bound violation in the higher derivative gravity. For example, D = 5 black brane is unstable at |λGB| > 1 /8 and has anomalously large relaxation time when approaching the threshold of instability.
Gravitational quasinormal modes of static Einstein-Gauss-Bonnet anti-de Sitter black holes
Ma, Hong; Li, Jin
2018-04-01
In this paper, we describe quasinormal modes (QNMs) for gravitational perturbations of Einstein-Gauss-Bonnet black holes (BHs) in higher dimensional spacetimes, and derive the corresponding parameters of such black holes in three types of spacetime (flat, de Sitter (dS) and anti-de Sitter (AdS)). Our attention is concentrated on discussing the (in)stability of Einstein-Gauss-Bonnet AdS BHs through the temporal evolution of all types of gravitational perturbation fields (tensor, vector and scalar). It is concluded that the potential functions in vector and scalar gravitational perturbations have negative regions, which suppress quasinormal ringing. Furthermore, the influences of the Gauss-Bonnet coupling parameter α, the number of dimensions n and the angular momentum quantum number l on the Einstein-Gauss-Bonnet AdS BHs quasinormal spectrum are analyzed. The QNM frequencies have greater oscillation and lower damping rate with the growth of α. This indicates that QNM frequencies become increasingly unstable with large α. Meanwhile, the dynamic evolutions of the perturbation field are compliant with the results of computation from the Horowitz and Hubeny method. Because the number of extra dimensions is connected with the string scale, the relationship between α and properties of Einstein-Gauss-Bonnet AdS BHs might be beneficial for the exploitation of string theory and extra-dimensional brane worlds. Supported by FAPESP (2012/08934-0), National Natural Science Foundation of China (11205254, 11178018, 11375279, 11605015), the Natural Science Foundation Project of CQ CSTC (2011BB0052), and the Fundamental Research Funds for the Central Universities (106112016CDJXY300002, 106112017CDJXFLX0014, CDJRC10300003)
Post-Kerr black hole spectroscopy
Glampedakis, Kostas; Pappas, George; Silva, Hector O.; Berti, Emanuele
2017-09-01
One of the central goals of the newborn field of gravitational wave astronomy is to test gravity in the highly nonlinear, strong field regime characterizing the spacetime of black holes. In particular, "black hole spectroscopy" (the observation and identification of black hole quasinormal mode frequencies in the gravitational wave signal) is expected to become one of the main tools for probing the structure and dynamics of Kerr black holes. In this paper we take a significant step toward that goal by constructing a "post-Kerr" quasinormal mode formalism. The formalism incorporates a parametrized but general perturbative deviation from the Kerr metric and exploits the well-established connection between the properties of the spacetime's circular null geodesics and the fundamental quasinormal mode to provide approximate, eikonal limit formulas for the modes' complex frequencies. The resulting algebraic toolkit can be used in waveform templates for ringing black holes with the purpose of measuring deviations from the Kerr metric. As a first illustrative application of our framework, we consider the Johannsen-Psaltis deformed Kerr metric and compute the resulting deviation in the quasinormal mode frequency relative to the known Kerr result.
Massive Vector Fields in Rotating Black-Hole Spacetimes: Separability and Quasinormal Modes.
Frolov, Valeri P; Krtouš, Pavel; Kubizňák, David; Santos, Jorge E
2018-06-08
We demonstrate the separability of the massive vector (Proca) field equation in general Kerr-NUT-AdS black-hole spacetimes in any number of dimensions, filling a long-standing gap in the literature. The obtained separated equations are studied in more detail for the four-dimensional Kerr geometry and the corresponding quasinormal modes are calculated. Two of the three independent polarizations of the Proca field are shown to emerge from the separation ansatz and the results are found in an excellent agreement with those of the recent numerical study where the full coupled partial differential equations were tackled without using the separability property.
Exact gravitational quasinormal frequencies of topological black holes
International Nuclear Information System (INIS)
Birmingham, Danny; Mokhtari, Susan
2006-01-01
We compute the exact gravitational quasinormal frequencies for massless topological black holes in d-dimensional anti-de Sitter space. Using the gauge invariant formalism for gravitational perturbations derived by Kodama and Ishibashi, we show that in all cases the scalar, vector, and tensor modes can be reduced to a simple scalar field equation. This equation is exactly solvable in terms of hypergeometric functions, thus allowing an exact analytic determination of the gravitational quasinormal frequencies
Núñez, Alvaro; Starinets, Andrei O.
2003-06-01
We use the Lorentzian AdS/CFT prescription to find the poles of the retarded thermal Green’s functions of N=4 SU(N) supersymmetric Yang-Mills theory in the limit of large N and large ’t Hooft coupling. In the process, we propose a natural definition for quasinormal modes in an asymptotically AdS spacetime, with boundary conditions dictated by the AdS/CFT correspondence. The corresponding frequencies determine the dispersion laws for the quasiparticle excitations in the dual finite-temperature gauge theory. Correlation functions of operators dual to massive scalar, vector and gravitational perturbations in a five-dimensional AdS-Schwarzschild background are considered. We find asymptotic formulas for quasinormal frequencies in the massive scalar and tensor cases, and an exact expression for vector perturbations. In the long-distance, low-frequency limit we recover results of the hydrodynamic approximation to thermal Yang-Mills theory.
International Nuclear Information System (INIS)
Nunez, Alvaro; Starinets, Andrei O.
2003-01-01
We use the Lorentzian AdS/CFT prescription to find the poles of the retarded thermal Green's functions of N=4 SU(N) supersymmetric Yang-Mills theory in the limit of large N and large 't Hooft coupling. In the process, we propose a natural definition for quasinormal modes in an asymptotically AdS spacetime, with boundary conditions dictated by the AdS/CFT correspondence. The corresponding frequencies determine the dispersion laws for the quasiparticle excitations in the dual finite-temperature gauge theory. Correlation functions of operators dual to massive scalar, vector and gravitational perturbations in a five-dimensional AdS-Schwarzschild background are considered. We find asymptotic formulas for quasinormal frequencies in the massive scalar and tensor cases, and an exact expression for vector perturbations. In the long-distance, low-frequency limit we recover results of the hydrodynamic approximation to thermal Yang-Mills theory
New Class of Quasinormal Modes of Neutron Stars in Scalar-Tensor Gravity
Mendes, Raissa F. P.; Ortiz, Néstor
2018-05-01
Detection of the characteristic spectrum of pulsating neutron stars can be a powerful tool not only to probe the nuclear equation of state but also to test modifications to general relativity. However, the shift in the oscillation spectrum induced by modified theories of gravity is often small and degenerate with our ignorance of the equation of state. In this Letter, we show that the coupling to additional degrees of freedom present in modified theories of gravity can give rise to new families of modes, with no counterpart in general relativity, which could be sufficiently well resolved in frequency space to allow for clear detection. We present a realization of this idea by performing a thorough study of radial oscillations of neutron stars in massless scalar-tensor theories of gravity. We anticipate astrophysical scenarios where the presence of this class of quasinormal modes could be probed with electromagnetic and gravitational wave measurements.
Gravitational Quasinormal Modes of Regular Phantom Black Hole
Directory of Open Access Journals (Sweden)
Jin Li
2017-01-01
Full Text Available We investigate the gravitational quasinormal modes (QNMs for a type of regular black hole (BH known as phantom BH, which is a static self-gravitating solution of a minimally coupled phantom scalar field with a potential. The studies are carried out for three different spacetimes: asymptotically flat, de Sitter (dS, and anti-de Sitter (AdS. In order to consider the standard odd parity and even parity of gravitational perturbations, the corresponding master equations are derived. The QNMs are discussed by evaluating the temporal evolution of the perturbation field which, in turn, provides direct information on the stability of BH spacetime. It is found that in asymptotically flat, dS, and AdS spacetimes the gravitational perturbations have similar characteristics for both odd and even parities. The decay rate of perturbation is strongly dependent on the scale parameter b, which measures the coupling strength between phantom scalar field and the gravity. Furthermore, through the analysis of Hawking radiation, it is shown that the thermodynamics of such regular phantom BH is also influenced by b. The obtained results might shed some light on the quantum interpretation of QNM perturbation.
DEFF Research Database (Denmark)
de Lasson, Jakob Rosenkrantz; Kristensen, Philip Trøst; Mørk, Jesper
2015-01-01
We present and validate a semi-analytical quasi-normal mode (QNM) theory for the local density of states (LDOS) in coupled photonic crystal (PhC) cavity-waveguide structures. By means of an expansion of the Green's function on one or a few QNMs, a closed-form expression for the LDOS is obtained, ......-trivial spectrum with a peak and a dip is found, which is reproduced only when including both the two relevant QNMs in the theory. In both cases, we find relative errors below 1% in the bandwidth of interest.......We present and validate a semi-analytical quasi-normal mode (QNM) theory for the local density of states (LDOS) in coupled photonic crystal (PhC) cavity-waveguide structures. By means of an expansion of the Green's function on one or a few QNMs, a closed-form expression for the LDOS is obtained......, and for two types of two-dimensional PhCs, with one and two cavities side-coupled to an extended waveguide, the theory is validated against numerically exact computations. For the single cavity, a slightly asymmetric spectrum is found, which the QNM theory reproduces, and for two cavities a non...
Hod, Shahar
2018-05-01
The quasinormal resonant modes of massless neutral fields in near-extremal Kerr-Newman-de Sitter black-hole spacetimes are calculated in the eikonal regime. It is explicitly proved that, in the angular momentum regime a bar >√{1 - 2 Λ bar/4 + Λ bar / 3 }, the black-hole spacetimes are characterized by slowly decaying resonant modes which are described by the compact formula ℑ ω (n) =κ+ ṡ (n + 1/2 ) [here the physical parameters { a bar ,κ+ , Λ bar , n } are respectively the dimensionless angular momentum of the black hole, its characteristic surface gravity, the dimensionless cosmological constant of the spacetime, and the integer resonance parameter]. Our results support the validity of the Penrose strong cosmic censorship conjecture in these black-hole spacetimes.
Panotopoulos, Grigoris
2018-06-01
We perturb the non-rotating BTZ black hole with a non-minimally coupled massless scalar field, and we compute the quasinormal spectrum exactly. We solve the radial equation in terms of hypergeometric functions, and we obtain an analytical expression for the quasinormal frequencies. In addition, we compare our analytical results with the 6th order semi-analytical WKB method, and we find an excellent agreement. The impact of the nonminimal coupling as well as of the cosmological constant on the quasinormal spectrum is briefly discussed.
International Nuclear Information System (INIS)
Destounis, Kyriakos; Panotopoulos, Grigoris; Rincon, Angel
2018-01-01
We study the stability under scalar perturbations, and we compute the quasinormal modes of the Einstein-Born-Infeld dilaton spacetime in 1 + 3 dimensions. Solving the full radial equation in terms of hypergeometric functions, we provide an exact analytical expression for the spectrum. We find that the frequencies are purely imaginary, and we confirm our results by computing them numerically. Although the scalar field that perturbs the black hole is electrically neutral, an instability similar to that seen in charged scalar perturbations of the Reissner-Nordstroem black hole is observed. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Destounis, Kyriakos; Panotopoulos, Grigoris [Universidade de Lisboa, Centro Multidisciplinar de Astrofisica, Instituto Superior Tecnico, Lisbon (Portugal); Rincon, Angel [Pontificia Universidad Catolica de Chile, Instituto de Fisica, Santiago (Chile)
2018-02-15
We study the stability under scalar perturbations, and we compute the quasinormal modes of the Einstein-Born-Infeld dilaton spacetime in 1 + 3 dimensions. Solving the full radial equation in terms of hypergeometric functions, we provide an exact analytical expression for the spectrum. We find that the frequencies are purely imaginary, and we confirm our results by computing them numerically. Although the scalar field that perturbs the black hole is electrically neutral, an instability similar to that seen in charged scalar perturbations of the Reissner-Nordstroem black hole is observed. (orig.)
Partition functions with spin in AdS2 via quasinormal mode methods
International Nuclear Information System (INIS)
Keeler, Cynthia; Lisbão, Pedro; Ng, Gim Seng
2016-01-01
We extend the results of http://dx.doi.org/10.1007/JHEP06(2014)099, computing one loop partition functions for massive fields with spin half in AdS 2 using the quasinormal mode method proposed by Denef, Hartnoll, and Sachdev http://dx.doi.org/10.1088/0264-9381/27/12/125001. We find the finite representations of SO(2,1) for spin zero and spin half, consisting of a highest weight state |h〉 and descendants with non-unitary values of h. These finite representations capture the poles and zeroes of the one loop determinants. Together with the asymptotic behavior of the partition functions (which can be easily computed using a large mass heat kernel expansion), these are sufficient to determine the full answer for the one loop determinants. We also discuss extensions to higher dimensional AdS 2n and higher spins.
Quasinormal modes of brane-localized standard model fields. II. Kerr black holes
International Nuclear Information System (INIS)
Kanti, P.; Konoplya, R. A.; Zhidenko, A.
2006-01-01
This paper presents a comprehensive study of the fundamental quasinormal modes of all standard model fields propagating on a brane embedded in a higher-dimensional rotating black-hole spacetime. The equations of motion for fields with spin s=0, 1/2 and 1 propagating in the induced-on-the-brane background are solved numerically, and the dependence of their QN spectra on the black-hole angular momentum and dimensionality of spacetime is investigated. It is found that the brane-localized field perturbations are longer-lived when the higher-dimensional black hole rotates faster, while an increase in the number of transverse-to-the-brane dimensions reduces their lifetime. Finally, the quality factor Q, that determines the best oscillator among the different field perturbations, is investigated and found to depend on properties of both the particular field studied (spin, multipole numbers) and the gravitational background (dimensionality, black-hole angular momentum parameter)
Quantum tunneling and quasinormal modes in the spacetime of the Alcubierre warp drive
Jusufi, Kimet; Sakallı, İzzet; Övgün, Ali
2018-01-01
In a seminal paper, Alcubierre showed that Einstein's theory of general relativity appears to allow a super-luminal motion. In the present study, we use a recent eternal-warp-drive solution found by Alcubierre to study the effect of Hawking radiation upon an observer located within the warp drive in the framework of the quantum tunneling method. We find the same expression for the Hawking temperatures associated with the tunneling of both massive vector and scalar particles, and show this expression to be proportional to the velocity of the warp drive. On the other hand, since the discovery of gravitational waves, the quasinormal modes (QNMs) of black holes have also been extensively studied. With this purpose in mind, we perform a QNM analysis of massive scalar field perturbations in the background of the eternal-Alcubierre-warp-drive spacetime. Our analytical analysis shows that massive scalar perturbations lead to stable QNMs.
Partition functions with spin in AdS{sub 2} via quasinormal mode methods
Energy Technology Data Exchange (ETDEWEB)
Keeler, Cynthia [Niels Bohr International Academy, Niels Bohr Institute,University of Copenhagen, Blegdamsvej 17, DK 2100, Copenhagen (Denmark); Lisbão, Pedro [Department of Physics, University of Michigan,Ann Arbor, MI-48109 (United States); Ng, Gim Seng [Department of Physics, McGill University,Montréal, QC H3A 2T8 (Canada)
2016-10-12
We extend the results of http://dx.doi.org/10.1007/JHEP06(2014)099, computing one loop partition functions for massive fields with spin half in AdS{sub 2} using the quasinormal mode method proposed by Denef, Hartnoll, and Sachdev http://dx.doi.org/10.1088/0264-9381/27/12/125001. We find the finite representations of SO(2,1) for spin zero and spin half, consisting of a highest weight state |h〉 and descendants with non-unitary values of h. These finite representations capture the poles and zeroes of the one loop determinants. Together with the asymptotic behavior of the partition functions (which can be easily computed using a large mass heat kernel expansion), these are sufficient to determine the full answer for the one loop determinants. We also discuss extensions to higher dimensional AdS{sub 2n} and higher spins.
Black-hole quasinormal resonances: Wave analysis versus a geometric-optics approximation
International Nuclear Information System (INIS)
Hod, Shahar
2009-01-01
It has long been known that null unstable geodesics are related to the characteristic modes of black holes--the so-called quasinormal resonances. The basic idea is to interpret the free oscillations of a black hole in the eikonal limit in terms of null particles trapped at the unstable circular orbit and slowly leaking out. The real part of the complex quasinormal resonances is related to the angular velocity at the unstable null geodesic. The imaginary part of the resonances is related to the instability time scale (or the inverse Lyapunov exponent) of the orbit. While this geometric-optics description of the black-hole quasinormal resonances in terms of perturbed null rays is very appealing and intuitive, it is still highly important to verify the validity of this approach by directly analyzing the Teukolsky wave equation which governs the dynamics of perturbation waves in the black-hole spacetime. This is the main goal of the present paper. We first use the geometric-optics technique of perturbing a bundle of unstable null rays to calculate the resonances of near-extremal Kerr black holes in the eikonal approximation. We then directly solve the Teukolsky wave equation (supplemented by the appropriate physical boundary conditions) and show that the resultant quasinormal spectrum obtained directly from the wave analysis is in accord with the spectrum obtained from the geometric-optics approximation of perturbed null rays.
Energy Technology Data Exchange (ETDEWEB)
Zou, De-Cheng; Yue, Ruihong [Yangzhou University, Center for Gravitation and Cosmology, College of Physical Science and Technology, Yangzhou (China); Liu, Yunqi [Huazhong University of Science and Technology, School of Physics, Wuhan (China)
2017-06-15
In this work, we utilize the quasinormal modes (QNMs) of a massless scalar perturbation to probe the Van der Waals-like small and large black holes (SBH/LBH) phase transition of charged topological Anti-de Sitter (AdS) black holes in four-dimensional massive gravity. We find that the signature of this SBH/LBH phase transition is detected in the isobaric as well as in the isothermal process. This further supports the idea that the QNMs can be an efficient tool to investigate the thermodynamical phase transition. (orig.)
Directory of Open Access Journals (Sweden)
John Cossey
2015-03-01
Full Text Available Quasinormal subgroups have been studied for nearly 80 years. In finite groups, questions concerning them invariably reduce to p-groups, and here they have the added interest of being invariant under projectivities, unlike normal subgroups. However, it has been shown recently that certain groups, constructed by Berger and Gross in 1982, of an important universal nature with regard to the existence of core-free quasinormal subgroups gener- ally, have remarkably few such subgroups. Therefore in order to overcome this misfortune, a generalization of the concept of quasi- normality will be defined. It could be the beginning of a lengthy undertaking. But some of the initial findings are encouraging, in particular the fact that this larger class of subgroups also remains invariant under projectivities of finite p-groups, thus connecting group and subgroup lattice structures.
DEFF Research Database (Denmark)
de Lasson, Jakob Rosenkrantz; Kristensen, Philip Trøst; Mørk, Jesper
2014-01-01
uses no external excitation and determines the quasi-normal modes as unity eigenvalues of the cavity roundtrip matrix. We demonstrate the method and the quasi-normal modes for two types of two-dimensional photonic crystal structures, and discuss the quasi-normal mode eld distributions and Q-factors...
On the branching of the quasinormal resonances of near-extremal Kerr black holes
Energy Technology Data Exchange (ETDEWEB)
Hod, Shahar, E-mail: shaharhod@gmail.com [The Ruppin Academic Center, 40250, Emeq Hefer (Israel); The Hadassah Institute, 91010, Jerusalem (Israel)
2015-11-02
It has recently been shown by Yang et al. (Phys Rev D 87:041502(R), 2013a; Phys Rev D 88:044047, 2013b) that rotating Kerr black holes are characterized by two distinct sets of quasinormal resonances. These two families of quasinormal resonances display qualitatively different asymptotic behaviors in the extremal (a/M→1) black-hole limit: the zero-damping modes are characterized by relaxation times which tend to infinity in the extremal black-hole limit (Iω→0 as a/M→1), whereas the damped modes (DMs) are characterized by non-zero damping rates (Iω→ finite-values as a/M→1). In this paper we refute the claim made by Yang et al. that co-rotating DMs of near-extremal black holes are restricted to the limited range 0≤μ≲μ{sub c}≈0.74, where μ≡m/l is the dimensionless ratio between the azimuthal harmonic index m and the spheroidal harmonic index l of the perturbation mode. In particular, we use an analytical formula originally derived by Detweiler in order to prove the existence of DMs (damped quasinormal resonances which are characterized by finiteIω values in the a/M→1 limit) of near-extremal black holes in the μ>μ{sub c} regime, the regime which was claimed by Yang et al. not to contain DMs. We show that these co-rotating DMs (in the regime μ>μ{sub c}) are expected to characterize the resonance spectra of rapidly rotating (near-extremal) black holes with a/M≳1-10{sup -9}.
Chen, C.-H.; Cho, H. T.; Cornell, A. S.; Harmsen, G.; Ngcobo, X.
2018-01-01
In this paper we consider spin-3 /2 fields in a D -dimensional Reissner-Nordström black hole spacetime. As these spacetimes are not Ricci flat, it is necessary to modify the covariant derivative to the supercovariant derivative, by including terms related to the background electromagnetic fields, so as to maintain the gauge symmetry. Using this supercovariant derivative we arrive at the corresponding Rarita-Schwinger equation in a charged black hole background. As in our previous works, we exploit the spherical symmetry of the spacetime and use the eigenspinor vectors on an N sphere to derive the radial equations for both nontransverse-traceless (non-TT) modes and TT modes. We then determine the quasinormal mode and absorption probabilities of the associated gauge-invariant variables using the WKB approximation and the asymptotic iteration method. We then concentrate on how these quantities change with the charge of the black hole, especially when they reach the extremal limits.
Energy Technology Data Exchange (ETDEWEB)
Prasia, P.; Kuriakose, V.C. [Cochin University of Science and Technology, Department of Physics, Kochi (India)
2017-01-15
In this work we study the Quasi-Normal Modes (QNMs) under massless scalar perturbations and the thermodynamics of linearly charged BTZ black holes in massive gravity in the (Anti)de Sitter ((A)dS) space-time. It is found that the behavior of QNMs changes with the massive parameter of the graviton and also with the charge of the black hole. The thermodynamics of such black holes in the (A)dS space-time is also analyzed in detail. The behavior of specific heat with temperature for such black holes gives an indication of a phase transition that depends on the massive parameter of the graviton and also on the charge of the black hole. (orig.)
On the branching of the quasinormal resonances of near-extremal Kerr black holes
Energy Technology Data Exchange (ETDEWEB)
Hod, Shahar [The Ruppin Academic Center, Emeq Hefer (Israel); The Hadassah Institute, Jerusalem (Israel)
2015-11-15
It has recently been shown by Yang et al. (Phys Rev D 87:041502(R), 2013a; Phys Rev D 88:044047, 2013b) that rotating Kerr black holes are characterized by two distinct sets of quasinormal resonances. These two families of quasinormal resonances display qualitatively different asymptotic behaviors in the extremal (a/M → 1) black-hole limit: the zero-damping modes are characterized by relaxation times which tend to infinity in the extremal black-hole limit (Iω → 0 as a/M @→ 1), whereas the damped modes (DMs) are characterized by non-zero damping rates (Iω @→ finite-values as a/M @→ 1). In this paper we refute the claim made by Yang et al. that co-rotating DMs of near-extremal black holes are restricted to the limited range 0 ≤ μ
Energy Technology Data Exchange (ETDEWEB)
Grozdanov, Sašo [Instituut-Lorentz for Theoretical Physics, Leiden University, Niels Bohrweg 2, Leiden 2333 CA (Netherlands); Starinets, Andrei O. [Rudolf Peierls Centre for Theoretical Physics, University of Oxford, 1 Keble Road, Oxford OX1 3NP (United Kingdom)
2017-03-30
Gauss-Bonnet holographic fluid is a useful theoretical laboratory to study the effects of curvature-squared terms in the dual gravity action on transport coefficients, quasinormal spectra and the analytic structure of thermal correlators at strong coupling. To understand the behavior and possible pathologies of the Gauss-Bonnet fluid in 3+1 dimensions, we compute (analytically and non-perturbatively in the Gauss-Bonnet coupling) its second-order transport coefficients, the retarded two- and three-point correlation functions of the energy-momentum tensor in the hydrodynamic regime as well as the relevant quasinormal spectrum. The Haack-Yarom universal relation among the second-order transport coefficients is violated at second order in the Gauss-Bonnet coupling. In the zero-viscosity limit, the holographic fluid still produces entropy, while the momentum diffusion and the sound attenuation are suppressed at all orders in the hydrodynamic expansion. By adding higher-derivative electromagnetic field terms to the action, we also compute corrections to charge diffusion and identify the non-perturbative parameter regime in which the charge diffusion constant vanishes.
High overtones of Schwarzschild-de-Sitter quasinormal spectrum
International Nuclear Information System (INIS)
Konoplya, R.A.; Zhidenko, A.
2004-01-01
We find the high overtones of gravitational and electromagnetic quasinormal spectrum of the Schwarzschild-de Sitter black hole. The calculations show that the real parts of the electromagnetic modes asymptotically approach zero. The gravitational modes show more peculiar behavior at large n: the real part oscillates as a function of imaginary even for very high overtones and these oscillations settles to some 'profile' which just repeats itself with further increasing of the overtone number n. This lets us judge that Reω is not a constant as n →∞ but rather some oscillating function. The spacing for imaginary part Imω n+1 -Imω n for electromagnetic perturbations at high n slowly approach k e as n→∞, where k e is the surface gravity. In addition we find the lower QN modes for which the values obtained with numerical methods are in a very good agreement with those obtained through the 6th order WKB technique. (author)
Spectroscopy of the Schwarzschild black hole at arbitrary frequencies.
Casals, Marc; Ottewill, Adrian
2012-09-14
Linear field perturbations of a black hole are described by the Green function of the wave equation that they obey. After Fourier decomposing the Green function, its two natural contributions are given by poles (quasinormal modes) and a largely unexplored branch cut in the complex frequency plane. We present new analytic methods for calculating the branch cut on a Schwarzschild black hole for arbitrary values of the frequency. The branch cut yields a power-law tail decay for late times in the response of a black hole to an initial perturbation. We determine explicitly the first three orders in the power-law and show that the branch cut also yields a new logarithmic behavior T(-2ℓ-5)lnT for late times. Before the tail sets in, the quasinormal modes dominate the black hole response. For electromagnetic perturbations, the quasinormal mode frequencies approach the branch cut at large overtone index n. We determine these frequencies up to n(-5/2) and, formally, to arbitrary order. Highly damped quasinormal modes are of particular interest in that they have been linked to quantum properties of black holes.
Black hole spectroscopy: Systematic errors and ringdown energy estimates
Baibhav, Vishal; Berti, Emanuele; Cardoso, Vitor; Khanna, Gaurav
2018-02-01
The relaxation of a distorted black hole to its final state provides important tests of general relativity within the reach of current and upcoming gravitational wave facilities. In black hole perturbation theory, this phase consists of a simple linear superposition of exponentially damped sinusoids (the quasinormal modes) and of a power-law tail. How many quasinormal modes are necessary to describe waveforms with a prescribed precision? What error do we incur by only including quasinormal modes, and not tails? What other systematic effects are present in current state-of-the-art numerical waveforms? These issues, which are basic to testing fundamental physics with distorted black holes, have hardly been addressed in the literature. We use numerical relativity waveforms and accurate evolutions within black hole perturbation theory to provide some answers. We show that (i) a determination of the fundamental l =m =2 quasinormal frequencies and damping times to within 1% or better requires the inclusion of at least the first overtone, and preferably of the first two or three overtones; (ii) a determination of the black hole mass and spin with precision better than 1% requires the inclusion of at least two quasinormal modes for any given angular harmonic mode (ℓ , m ). We also improve on previous estimates and fits for the ringdown energy radiated in the various multipoles. These results are important to quantify theoretical (as opposed to instrumental) limits in parameter estimation accuracy and tests of general relativity allowed by ringdown measurements with high signal-to-noise ratio gravitational wave detectors.
Modes and Mode Volumes for Leaky Optical Cavities and Plasmonic Nanoresonators
DEFF Research Database (Denmark)
Hughes, Stephen; Kristensen, Philip Trøst
2013-01-01
Electromagnetic cavity modes in photonic and plasmonic resonators offer rich and attractive regimes for tailoring the properties of light–matter interactions, yet there is a disturbing lack of a precise definition for what constitutes a cavity mode, and as a result their mathematical properties r...... methods for quasinormal modes of both photonic and plasmonic resonators and the concept of a generalized effective mode volume, and we illustrate the theory with several representative cavity structures from the fields of photonic crystals and nanoplasmonics....
Decoding Mode-mixing in Black-hole Merger Ringdown
Kelly, Bernard J.; Baker, John G.
2013-01-01
Optimal extraction of information from gravitational-wave observations of binary black-hole coalescences requires detailed knowledge of the waveforms. Current approaches for representing waveform information are based on spin-weighted spherical harmonic decomposition. Higher-order harmonic modes carrying a few percent of the total power output near merger can supply information critical to determining intrinsic and extrinsic parameters of the binary. One obstacle to constructing a full multi-mode template of merger waveforms is the apparently complicated behavior of some of these modes; instead of settling down to a simple quasinormal frequency with decaying amplitude, some |m| = modes show periodic bumps characteristic of mode-mixing. We analyze the strongest of these modes the anomalous (3, 2) harmonic mode measured in a set of binary black-hole merger waveform simulations, and show that to leading order, they are due to a mismatch between the spherical harmonic basis used for extraction in 3D numerical relativity simulations, and the spheroidal harmonics adapted to the perturbation theory of Kerr black holes. Other causes of mode-mixing arising from gauge ambiguities and physical properties of the quasinormal ringdown modes are also considered and found to be small for the waveforms studied here.
Roundtrip matrix method for calculating the leaky resonant modes of open nanophotonic structures
DEFF Research Database (Denmark)
de Lasson, Jakob Rosenkrantz; Kristensen, Philip Trøst; Mørk, Jesper
2014-01-01
We present a numerical method for calculating quasi-normal modes of open nanophotonic structures. The method is based on scattering matrices and a unity eigenvalue of the roundtrip matrix of an internal cavity, and we develop it in detail with electromagnetic fields expanded on Bloch modes...
Spectrally interleaved, comb-mode-resolved spectroscopy using swept dual terahertz combs.
Hsieh, Yi-Da; Iyonaga, Yuki; Sakaguchi, Yoshiyuki; Yokoyama, Shuko; Inaba, Hajime; Minoshima, Kaoru; Hindle, Francis; Araki, Tsutomu; Yasui, Takeshi
2014-01-22
Optical frequency combs are innovative tools for broadband spectroscopy because a series of comb modes can serve as frequency markers that are traceable to a microwave frequency standard. However, a mode distribution that is too discrete limits the spectral sampling interval to the mode frequency spacing even though individual mode linewidth is sufficiently narrow. Here, using a combination of a spectral interleaving and dual-comb spectroscopy in the terahertz (THz) region, we achieved a spectral sampling interval equal to the mode linewidth rather than the mode spacing. The spectrally interleaved THz comb was realized by sweeping the laser repetition frequency and interleaving additional frequency marks. In low-pressure gas spectroscopy, we achieved an improved spectral sampling density of 2.5 MHz and enhanced spectral accuracy of 8.39 × 10(-7) in the THz region. The proposed method is a powerful tool for simultaneously achieving high resolution, high accuracy, and broad spectral coverage in THz spectroscopy.
Spectrally interleaved, comb-mode-resolved spectroscopy using swept dual terahertz combs
Hsieh, Yi-Da; Iyonaga, Yuki; Sakaguchi, Yoshiyuki; Yokoyama, Shuko; Inaba, Hajime; Minoshima, Kaoru; Hindle, Francis; Araki, Tsutomu; Yasui, Takeshi
2014-01-01
Optical frequency combs are innovative tools for broadband spectroscopy because a series of comb modes can serve as frequency markers that are traceable to a microwave frequency standard. However, a mode distribution that is too discrete limits the spectral sampling interval to the mode frequency spacing even though individual mode linewidth is sufficiently narrow. Here, using a combination of a spectral interleaving and dual-comb spectroscopy in the terahertz (THz) region, we achieved a spectral sampling interval equal to the mode linewidth rather than the mode spacing. The spectrally interleaved THz comb was realized by sweeping the laser repetition frequency and interleaving additional frequency marks. In low-pressure gas spectroscopy, we achieved an improved spectral sampling density of 2.5 MHz and enhanced spectral accuracy of 8.39 × 10-7 in the THz region. The proposed method is a powerful tool for simultaneously achieving high resolution, high accuracy, and broad spectral coverage in THz spectroscopy.
Spectroscopy of Kerr Black Holes with Earth- and Space-Based Interferometers.
Berti, Emanuele; Sesana, Alberto; Barausse, Enrico; Cardoso, Vitor; Belczynski, Krzysztof
2016-09-02
We estimate the potential of present and future interferometric gravitational-wave detectors to test the Kerr nature of black holes through "gravitational spectroscopy," i.e., the measurement of multiple quasinormal mode frequencies from the remnant of a black hole merger. Using population synthesis models of the formation and evolution of stellar-mass black hole binaries, we find that Voyager-class interferometers will be necessary to perform these tests. Gravitational spectroscopy in the local Universe may become routine with the Einstein Telescope, but a 40-km facility like Cosmic Explorer is necessary to go beyond z∼3. In contrast, detectors like eLISA (evolved Laser Interferometer Space Antenna) should carry out a few-or even hundreds-of these tests every year, depending on uncertainties in massive black hole formation models. Many space-based spectroscopical measurements will occur at high redshift, testing the strong gravity dynamics of Kerr black holes in domains where cosmological corrections to general relativity (if they occur in nature) must be significant.
Mode coupling of Schwarzschild perturbations: Ringdown frequencies
International Nuclear Information System (INIS)
Pazos, Enrique; Brizuela, David; Martin-Garcia, Jose M.; Tiglio, Manuel
2010-01-01
Within linearized perturbation theory, black holes decay to their final stationary state through the well-known spectrum of quasinormal modes. Here we numerically study whether nonlinearities change this picture. For that purpose we study the ringdown frequencies of gauge-invariant second-order gravitational perturbations induced by self-coupling of linearized perturbations of Schwarzschild black holes. We do so through high-accuracy simulations in the time domain of first and second-order Regge-Wheeler-Zerilli type equations, for a variety of initial data sets. We consider first-order even-parity (l=2, m=±2) perturbations and odd-parity (l=2, m=0) ones, and all the multipoles that they generate through self-coupling. For all of them and all the initial data sets considered we find that--in contrast to previous predictions in the literature--the numerical decay frequencies of second-order perturbations are the same ones of linearized theory, and we explain the observed behavior. This would indicate, in particular, that when modeling or searching for ringdown gravitational waves, appropriately including the standard quasinormal modes already takes into account nonlinear effects.
Universality of the quasinormal spectrum of near-extremal Kerr-Newman black holes
Energy Technology Data Exchange (ETDEWEB)
Hod, Shahar [The Ruppin Academic Center, Emeq Hefer (Israel); The Hadassah Institute, Jerusalem (Israel)
2015-06-15
Our current knowledge about the quasinormal resonance spectrum of charged and rotating Kerr-Newman black holes is quite poor. This unsatisfactory situation is a direct consequence of the fact that all attempts to decouple the gravitational and electromagnetic perturbations of generic Kerr-Newman black holes have failed thus far. Recently, Zilhao et al. (Phys Rev D 90:12, 124088, 2014. arXiv:1410.0694) have studied the nonlinear stability of Kerr-Newman black holes. We show here that their numerical results for the time evolutions of the spacetime deformations of near-extremal Kerr-Newman black holes are described extremely well by a simple and universal analytical formula for the quasinormal resonances of the black holes. This formula is expressed in terms of the black-hole physical parameters: the horizon angular velocity Ω{sub H} and the Bekenstein-Hawking temperature T{sub BH}. (orig.)
THz time domain spectroscopy of biomolecular conformational modes
International Nuclear Information System (INIS)
Markelz, Andrea; Whitmire, Scott; Hillebrecht, Jay; Birge, Robert
2002-01-01
We discuss the use of terahertz time domain spectroscopy for studies of conformational flexibility and conformational change in biomolecules. Protein structural dynamics are vital to biological function with protein flexibility affecting enzymatic reaction rates and sensory transduction cycling times. Conformational mode dynamics occur on the picosecond timescale and with the collective vibrational modes associated with these large scale structural motions in the 1-100 cm -1 range. We have performed THz time domain spectroscopy (TTDS) of several biomolecular systems to explore the sensitivity of TTDS to distinguish different molecular species, different mutations within a single species and different conformations of a given biomolecule. We compare the measured absorbances to normal mode calculations and find that the TTDS absorbance reflects the density of normal modes determined by molecular mechanics calculations, and is sensitive to both conformation and mutation. These early studies demonstrate some of the advantages and limitations of using TTDS for the study of biomolecules
Holography and thermalization in optical pump-probe spectroscopy
Bagrov, A.; Craps, B.; Galli, F.; Keränen, V.; Keski-Vakkuri, E.; Zaanen, J.
2018-04-01
Using holography, we model experiments in which a 2 +1 D strange metal is pumped by a laser pulse into a highly excited state, after which the time evolution of the optical conductivity is probed. We consider a finite-density state with mildly broken translation invariance and excite it by oscillating electric field pulses. At zero density, the optical conductivity would assume its thermalized value immediately after the pumping has ended. At finite density, pulses with significant dc components give rise to slow exponential relaxation, governed by a vector quasinormal mode. In contrast, for high-frequency pulses the amplitude of the quasinormal mode is strongly suppressed, so that the optical conductivity assumes its thermalized value effectively instantaneously. This surprising prediction may provide a stimulus for taking up the challenge to realize these experiments in the laboratory. Such experiments would test a crucial open question faced by applied holography: are its predictions artifacts of the large N limit or do they enjoy sufficient UV independence to hold at least qualitatively in real-world systems?
Normed Orlicz function spaces which can be quasi-renormed with easily calculable quasinorms
Czech Academy of Sciences Publication Activity Database
Foralewski, P.; Hudzik, H.; Kaczmarek, R.; Krbec, Miroslav
2017-01-01
Roč. 11, č. 3 (2017), s. 636-660 ISSN 1735-8787 Institutional support: RVO:67985840 Keywords : embeddings into Lebesgue and weighted Lebesgue spaces * Orlicz spaces * quasinorms Subject RIV: BA - General Mathematics OBOR OECD: Pure mathematics Impact factor: 0.833, year: 2016 http://projecteuclid.org/euclid.bjma/1496973700
Black-hole hair loss: Learning about binary progenitors from ringdown signals
Kamaretsos, Ioannis; Hannam, Mark; Husa, Sascha; Sathyaprakash, B. S.
2012-01-01
Perturbed Kerr black holes emit gravitational radiation, which (for the practical purposes of gravitational-wave astronomy) consists of a superposition of damped sinusoids termed quasinormal modes. The frequencies and time constants of the modes depend only on the mass and spin of the black hole—a consequence of the no-hair theorem. It has been proposed that a measurement of two or more quasinormal modes could be used to confirm that the source is a black hole and to test if general relativity continues to hold in ultrastrong gravitational fields. In this paper, we propose a practical approach to testing general relativity with quasinormal modes. We will also argue that the relative amplitudes of the various quasinormal modes encode important information about the origin of the perturbation that caused them. This helps in inferring the nature of the perturbation from an observation of the emitted quasinormal modes. In particular, we will show that the relative amplitudes of the different quasinormal modes emitted in the process of the merger of a pair of nonspinning black holes can be used to measure the component masses of the progenitor binary.
Far infrared and terahertz spectroscopy of ferroelectric soft modes in thin films: a review
Czech Academy of Sciences Publication Activity Database
Petzelt, Jan; Kamba, Stanislav
2016-01-01
Roč. 503, č. 1 (2016), s. 19-44 ISSN 0015-0193 R&D Projects: GA ČR GA15-08389S Institutional support: RVO:68378271 Keywords : soft mode * central mode * ferroelectric thin film * terahertz spectroscopy * far-infrared spectroscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.551, year: 2016
International Nuclear Information System (INIS)
Cardoso, Vitor; Konoplya, Roman; Lemos, Jose P. S.
2003-01-01
We present a thorough analysis of the quasinormal (QN) behavior associated with the decay of scalar, electromagnetic, and gravitational perturbations of Schwarzschild black holes in anti-de Sitter (AdS) spacetimes. As is known, the AdS QN spectrum crucially depends on the relative size of the black hole to the AdS radius. There are three different types of behavior depending on whether the black hole is large, intermediate, or small. The results of previous works, concerning lower overtones for large black holes, are completed here by obtaining higher overtones for all three black hole regimes. There are two major conclusions that one can draw from this work: First, asymptotically for high overtones, all the modes are evenly spaced, and this holds for all three types of regime, large, intermediate, and small black holes, independently of l, where l is the quantum number characterizing the angular distribution; second, the spacing between modes is apparently universal in that it does not depend on the field; i.e., scalar, electromagnetic, and gravitational QN modes all have the same spacing for high overtones. We are also able to prove why scalar and gravitational perturbations are isospectral, asymptotically for high overtones, by introducing appropriate superpartner potentials
Strongly localized modes in one-dimensional defect-free magnonic quasicrystals
International Nuclear Information System (INIS)
Chen, C. H.; Qiu, R. Z.; Chang, C. H.; Hsueh, W. J.
2014-01-01
Signal storage in magnonic quasicrystals using a slow spin-wave mode, rather than the quasinormal mode of traditional periodic magnonic crystals, is proposed, which is analogous to the slow light mode in the field of optics. Compared to traditional materials, richer and more wavelength-selective sharp resonances are achieved using the quasicrystals with a fewer number of layers, because of the peculiar fractal transmission spectra of quasicrystals. The number of sharp resonance and the quality factor for the sharp resonances in the transmission spectra also increases as the generation order of the magnonic quasicrystal increases. This generic nature allows the storage of signals using spin wave, for a wide range of quasiperiodic systems
DEFF Research Database (Denmark)
Jana, Bimal; Baker, Kristin Renee; Guardabassi, Luca
2017-01-01
the biosynthesis rate of macromolecules (e.g., DNA, RNA, protein, and cell wall) and the cytoplasmic membrane proton motive force (PMF) energy can help to unravel the diverse modes of action of AMPs. Here, we present an overview of macromolecule biosynthesis rate measurement and fluorescence spectroscopy methods...
Scalar perturbations of two-dimensional Horava-Lifshitz black holes
International Nuclear Information System (INIS)
Cruz, Miguel; Gonzalez-Espinoza, Manuel; Saavedra, Joel; Vargas-Arancibia, Diego
2016-01-01
In this article, we study the stability of black hole solutions found in the context of dilatonic Horava-Lifshitz gravity in 1 + 1 dimensions by means of the quasinormal modes approach. In order to find the corresponding quasinormal modes, we consider the perturbations of massive and massless scalar fields minimally coupled to gravity. In both cases, we found that the quasinormal modes have a discrete spectrum and are completely imaginary, which leads to damping modes. For a massive scalar field and a non-vanishing cosmological constant, our results suggest unstable behavior for large values of the scalar field mass. (orig.)
Far-infrared ferroelectric soft mode spectroscopy on thin films
Czech Academy of Sciences Publication Activity Database
Petzelt, Jan; Ostapchuk, Tetyana
2001-01-01
Roč. 249, 1-2 (2001), s. 81-88 ISSN 0015-0193 R&D Projects: GA ČR GA202/98/1282; GA AV ČR IAA1010918; GA MŠk OC 514.10 Institutional research plan: CEZ:AV0Z1010914 Keywords : far-infrared spectroscopy * soft mode * dielectric spectra * permitivity Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.471, year: 2001
Whispering Gallery Mode Spectroscopy as a Diagnostic for Dusty Plasmas
International Nuclear Information System (INIS)
Thieme, G.; Basner, R.; Ehlbeck, J.; Roepcke, J.; Maurer, H.; Kersten, H.; Davies, P. B.
2008-01-01
Whispering-gallery-mode spectroscopy is being assessed as a diagnostic method for the characterisation of size and chemical composition of spherical particles levitated in a plasma. With a pulsed laser whispering gallery modes (cavity resonances) are excited in individual microspheres leading to enhanced Raman scattering or fluorescence at characteristic wavelengths. This method can be used to gain specific information from the particle surface and is thus of great interest for the characterisation of layers deposited on microparticles, e.g. in molecular plasmas. We present investigations of different microparticles in air and results from fluorescent particles levitated in an Argon rf plasma.
Mapping bright and dark modes in gold nanoparticle chains using electron energy loss spectroscopy.
Barrow, Steven J; Rossouw, David; Funston, Alison M; Botton, Gianluigi A; Mulvaney, Paul
2014-07-09
We present a scanning transmission electron microscopy-electron energy loss spectroscopy (STEM-EELS) investigation of gold nanosphere chains with lengths varying from 1 to 5 particles. We show localized EELS signals from the chains and identify energy-loss peaks arising due to l = 1, 2, 3, 4, and 5 plasmon modes through the use of EELS mapping. We also show the evolution of the energy of these modes as the length of a given chain increases, and we find that a chain containing N particles can accommodate at least N experimentally observable modes, in addition to the transverse mode. As the chain length is increased by the addition of one more gold particle to the chain, the new N + 1 mode becomes the highest energy mode, while the existing modes lower their energy and eventually asymptote as they delocalize along the chain. We also show that modes become increasingly difficult to detect with the EELS technique as l approaches N. The data are compared to numerical simulations.
Fermionic field perturbations of a three-dimensional Lifshitz black hole in conformal gravity
Energy Technology Data Exchange (ETDEWEB)
Gonzalez, P.A. [Facultad de Ingenieria y Ciencias, Universidad Diego Portales, Santiago (Chile); Vasquez, Yerko; Villalobos, Ruth Noemi [Universidad de La Serena, Departamento de Fisica y Astronomia, Facultad de Ciencias, La Serena (Chile)
2017-09-15
We study the propagation of massless fermionic fields in the background of a three-dimensional Lifshitz black hole, which is a solution of conformal gravity. The black-hole solution is characterized by a vanishing dynamical exponent. Then we compute analytically the quasinormal modes, the area spectrum, and the absorption cross section for fermionic fields. The analysis of the quasinormal modes shows that the fermionic perturbations are stable in this background. The area and entropy spectrum are evenly spaced. In the low frequency limit, it is observed that there is a range of values of the angular momentum of the mode that contributes to the absorption cross section, whereas it vanishes in the high frequency limit. In addition, by a suitable change of variables a gravitational soliton can also be obtained and the stability of the quasinormal modes are studied and ensured. (orig.)
Monitoring of biofilm growth using ATR-leaky mode spectroscopy
International Nuclear Information System (INIS)
Leitz, M.; Franke, H.; Grattan, K.T.V.; Tamachkiarow, A.
2002-01-01
An approach to the in situ monitoring of biofilm formation using the technique of ATR-leaky mode spectroscopy is given as an example for the case of Cytophaga. The biofilm growth was studied on an aluminium layer and on a bilayer of the hydrogel agarose on aluminium. This metal was chosen because of its chemical stability in aqueous systems. The spectra obtained have been recorded using a flow cell to contain the suspension and nutrients over a period of several days. In the case considered using a prism surface coated with agarose, the experiments were performed by breeding in an incubator. (author)
Dynamical stability of the holographic system with two competing orders
Energy Technology Data Exchange (ETDEWEB)
Du, Yiqiang [School of Physics, University of Chinese Academy of Sciences,Beijing 100049 (China); Lan, Shan-Quan [Department of Physics, Beijing Normal University,Beijing 100875 (China); Tian, Yu [School of Physics, University of Chinese Academy of Sciences,Beijing 100049 (China); State Key Laboratory of Theoretical Physics,Institute of Theoretical Physics, Chinese Academy of Science,Beijing 100190 (China); Zhang, Hongbao [Department of Physics, Beijing Normal University,Beijing 100875 (China); Theoretische Natuurkunde, Vrije Universiteit Brussel and The International Solvay Institutes,Pleinlaan 2, B-1050 Brussels (Belgium)
2016-01-04
We investigate the dynamical stability of the holographic system with two order parameters, which exhibits competition and coexistence of condensations. In the linear regime, we have developed the gauge dependent formalism to calculate the quasi-normal modes by gauge fixing, which turns out be considerably convenient. Furthermore, by giving different Gaussian wave packets as perturbations at the initial time, we numerically evolve the full nonlinear system until it arrives at the final equilibrium state. Our results show that the dynamical stability is consistent with the thermodynamical stability. Interestingly, the dynamical evolution, as well as the quasi-normal modes, shows that the relaxation time of this model is generically much longer than the simplest holographic system. We also find that the late time behavior can be well captured by the lowest lying quasi-normal modes except for the non-vanishing order towards the single ordered phase. To our knowledge, this exception is the first counter example to the general belief that the late time behavior towards a final stable state can be captured by the lowest lying quasi-normal modes. In particular, a double relation is found for this exception in certain cases.
The imprint of the equation of state on the axial w-modes of oscillating neutron stars
International Nuclear Information System (INIS)
Benhar, O.; Berti, E.; Ferrari, V.
2001-01-01
We study the dependence of the pulsation frequencies of axial quasi-normal modes of a nonrotating neutron star upon the equation of state describing the star interior. The complex frequencies corresponding to a set of equations of state based on different physical assumptions have been computed. The numerical results, which appear to depend primarily on the stiffness of the equation of state, show that axial gravitational waves carry relevant information on both the structure of neutron star matter and the nature of the hadronic interactions. (author)
Nieuwjaer, N; Desfrançois, C; Lecomte, F; Manil, B; Soorkia, S; Broquier, M; Grégoire, G
2018-04-19
We report the UV and IR photofragmentation spectroscopies of protonated synephrine in a cryogenically cooled Paul trap. Single (UV or IR) and double (UV-UV and IR-UV) resonance spectroscopies have been performed and compared to quantum chemistry calculations, allowing the assignment of the lowest-energy conformer with two rotamers depending on the orientation of the phenol hydroxyl (OH) group. The IR-UV hole burning spectrum exhibits the four expected vibrational modes in the 3 μm region, i.e., the phenol OH, C β -OH, and two NH 2 + stretches. The striking difference is that, among these modes, only the free phenol OH mode is active through IRPD. The protonated amino group acts as a proton donor in the internal hydrogen bond and displays large frequency shifts upon isomerization expected during the multiphoton absorption process, leading to the so-called IRMPD transparency. More interestingly, while the C β -OH is a proton acceptor group with moderate frequency shift for the different conformations, this mode is still inactive through IRPD.
Mode-Locked Multichromatic X-Rays in a Seeded Free-Electron Laser for Single-Shot X-Ray Spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Xiang, Dao; Ding, Yuantao; Raubenheimer, Tor; Wu, Juhao; /SLAC
2012-05-10
We present the promise of generating gigawatt mode-locked multichromatic x rays in a seeded free-electron laser (FEL). We show that, by using a laser to imprint periodic modulation in electron beam phase space, a single-frequency coherent seed can be amplified and further translated to a mode-locked multichromatic output in an FEL. With this configuration the FEL output consists of a train of mode-locked ultrashort pulses which span a wide frequency gap with a series of equally spaced sharp lines. These gigawatt multichromatic x rays may potentially allow one to explore the structure and dynamics of a large number of atomic states simultaneously. The feasibility of generating mode-locked x rays ranging from carbon K edge ({approx}284 eV) to copper L{sub 3} edge ({approx}931 eV) is confirmed with numerical simulation using the realistic parameters of the linac coherent light source (LCLS) and LCLS-II. We anticipate that the mode-locked multichromatic x rays in FELs may open up new opportunities in x-ray spectroscopy (i.e. resonant inelastic x-ray scattering, time-resolved scattering and spectroscopy, etc.).
Entropy Spectrum of Black Holes of Heterotic String Theory via Adiabatic Invariance
Institute of Scientific and Technical Information of China (English)
Alexis Larra？ aga; Luis Cabarique; Manuel Londo？ o
2012-01-01
Using adiabatic invariance and the Bohr-Sommerfeld quantization rule we investigate the entropy spectroscopy of two black holes of heterotic string theory,the charged GMGHS and the rotating Sen solutions.It is shown that the entropy spectrum is equally spaced in both cases,identically to the spectrum obtained before for Schwarzschild,Reissner-Nordstr?m and Kerr black holes.Since the adiabatic invariance method does not use quasinormal mode analysis,there is no need to impose the small charge or small angular momentum limits and there is no confusion on whether the real part or the imaginary part of the modes is responsible for the entropy spectrum.
Features and stability analysis of non-Schwarzschild black hole in quadratic gravity
International Nuclear Information System (INIS)
Cai, Yi-Fu; Zhang, Hezi; Liu, Junyu; Cheng, Gong; Wang, Min
2016-01-01
Black holes are found to exist in gravitational theories with the presence of quadratic curvature terms and behave differently from the Schwarzschild solution. We present an exhaustive analysis for determining the quasinormal modes of a test scalar field propagating in a new class of black hole backgrounds in the case of pure Einstein-Weyl gravity. Our result shows that the field decay of quasinormal modes in such a non-Schwarzschild black hole behaves similarly to the Schwarzschild one, but the decay slope becomes much smoother due to the appearance of the Weyl tensor square in the background theory. We also analyze the frequencies of the quasinormal modes in order to characterize the properties of new back holes, and thus, if these modes can be the source of gravitational waves, the underlying theories may be testable in future gravitational wave experiments. We briefly comment on the issue of quantum (in)stability in this theory at linear order.
DEFF Research Database (Denmark)
Mackenzie, David M.A.; Whelan, Patrick Rebsdorf; Bøggild, Peter
2018-01-01
We present a comparative study of electrical measurements of graphene using terahertz time-domain spectroscopy in transmission and reflection mode, and compare the measured sheet conductivity values to electrical van der Pauw measurements made independently in three different laboratories. Overall......, while offering the additional advantages associated with contactless mapping, such as high throughput, no lithography requirement, and with the spatial mapping directly revealing the presence of any inhomogeneities or isolating defects. The confirmation of the accuracy of reflection-mode removes...
Real-time dual-comb spectroscopy with a free-running bidirectionally mode-locked fiber laser
Mehravar, S.; Norwood, R. A.; Peyghambarian, N.; Kieu, K.
2016-06-01
Dual-comb technique has enabled exciting applications in high resolution spectroscopy, precision distance measurements, and 3D imaging. Major advantages over traditional methods can be achieved with dual-comb technique. For example, dual-comb spectroscopy provides orders of magnitude improvement in acquisition speed over standard Fourier-transform spectroscopy while still preserving the high resolution capability. Wider adoption of the technique has, however, been hindered by the need for complex and expensive ultrafast laser systems. Here, we present a simple and robust dual-comb system that employs a free-running bidirectionally mode-locked fiber laser operating at telecommunication wavelength. Two femtosecond frequency combs (with a small difference in repetition rates) are generated from a single laser cavity to ensure mutual coherent properties and common noise cancellation. As the result, we have achieved real-time absorption spectroscopy measurements without the need for complex servo locking with accurate frequency referencing, and relatively high signal-to-noise ratio.
Effects of three-mode field interactions in laser instabilities and in beat-frequency spectroscopy
International Nuclear Information System (INIS)
Herdow, S.T.
1982-01-01
Population pulsations are fluctuations in the population difference (of a two level system) due to the presence of two or more coherent waves interfering in the medium. In this work, the author shows that population pulsations generated by three waves, a central wave and two mode-locked sidebands, are responsible for both the multiwavelength and the single-wavelength instabilities of single-mode lasers containing homgeneously-broadened media. The role of the population pulsations in establishing these instabilities, however, diminish as the central mode is detuned away from the atomic resonance frequency. For homogeneously-broadened lasers, the author finds two regions of single-wavelength instability. The first is at line center, for which population pulsations are solely responsible, and the second is off line center where the unsaturated medium provides the required gain and anomalous dispersion. For the case of inhomogeneously-broadened lasers, the author shows that population pulsations significantly increase the instability range over that predicted by Casperson for single-mode bad-cavity lasers. Both the unidirectional ring and the standing-wave cavities are treated. The Fourier expansion technique, used in this work, for treating three-frequency operation in saturation spectroscopy is shown to be equivalent (in appropriate limits) to the linear stability analysis in laser theory and optical bistability. The author also shows, in single-sideband saturation spectroscopy, that for long interaction lengths propagation effects can significantly influence the absorption and dispersion coefficients of the medium. Finally, the author shows that under certain conditions the pronounced splitting effects of the population pulsations develop into regions of intense absorption
Is the Gravitational-Wave Ringdown a Probe of the Event Horizon?
Cardoso, Vitor; Franzin, Edgardo; Pani, Paolo
2016-04-29
It is commonly believed that the ringdown signal from a binary coalescence provides a conclusive proof for the formation of an event horizon after the merger. This expectation is based on the assumption that the ringdown waveform at intermediate times is dominated by the quasinormal modes of the final object. We point out that this assumption should be taken with great care, and that very compact objects with a light ring will display a similar ringdown stage, even when their quasinormal-mode spectrum is completely different from that of a black hole. In other words, universal ringdown waveforms indicate the presence of light rings, rather than of horizons. Only precision observations of the late-time ringdown signal, where the differences in the quasinormal-mode spectrum eventually show up, can be used to rule out exotic alternatives to black holes and to test quantum effects at the horizon scale.
Directory of Open Access Journals (Sweden)
A. Card
2016-02-01
Full Text Available We show resolution of fine spectral features within several Raman active vibrational modes in potassium titanyl phosphate (KTP crystal. Measurements are performed using a femtosecond time-domain coherent anti-Stokes Raman scattering spectroscopy technique that is capable of delivering equivalent spectral resolution of 0.1 cm−1. The Raman spectra retrieved from our measurements show several spectral components corresponding to vibrations of different symmetry with distinctly different damping rates. In particular, linewidths for unassigned optical phonon mode triplet centered at around 820 cm−1 are found to be 7.5 ± 0.2 cm−1, 9.1 ± 0.3 cm−1, and 11.2 ± 0.3 cm−1. Results of our experiments will ultimately help to design an all-solid-state source for sub-optical-wavelength waveform generation that is based on stimulated Raman scattering.
Resonance Spectra of Caged Stringy Black Hole and Its Spectroscopy
Directory of Open Access Journals (Sweden)
I. Sakalli
2015-01-01
quasinormal mode (QNM frequencies, is used to investigate the entropy/area spectra of the Garfinkle–Horowitz–Strominger black hole (GHSBH. Instead of the ordinary QNMs, we compute the boxed QNMs (BQNMs that are the characteristic resonance spectra of the confined scalar fields in the GHSBH geometry. For this purpose, we assume that the GHSBH has a confining cavity (mirror placed in the vicinity of the event horizon. We then show how the complex resonant frequencies of the caged GHSBH are computed using the Bessel differential equation that arises when the scalar perturbations around the event horizon are considered. Although the entropy/area is characterized by the GHSBH parameters, their quantization is shown to be independent of those parameters. However, both spectra are equally spaced.
Hyperspectral tomography based on multi-mode absorption spectroscopy (MUMAS)
Dai, Jinghang; O'Hagan, Seamus; Liu, Hecong; Cai, Weiwei; Ewart, Paul
2017-10-01
This paper demonstrates a hyperspectral tomographic technique that can recover the temperature and concentration field of gas flows based on multi-mode absorption spectroscopy (MUMAS). This method relies on the recently proposed concept of nonlinear tomography, which can take full advantage of the nonlinear dependency of MUMAS signals on temperature and enables 2D spatial resolution of MUMAS which is naturally a line-of-sight technique. The principles of MUMAS and nonlinear tomography, as well as the mathematical formulation of the inversion problem, are introduced. Proof-of-concept numerical demonstrations are presented using representative flame phantoms and assuming typical laser parameters. The results show that faithful reconstruction of temperature distribution is achievable when a signal-to-noise ratio of 20 is assumed. This method can potentially be extended to simultaneously reconstructing distributions of temperature and the concentration of multiple flame species.
Sahay, Peeyush; Scherrer, Susan T.; Wang, Chuji
2012-09-01
A portable optical emission spectroscopy-cavity ringdown spectroscopy (OES-CRDS) dual-mode plasma spectrometer is described. A compact, low-power, atmospheric argon microwave plasma torch (MPT) is utilized as the emission source when the spectrometer is operating in the OES mode. The same MPT serves as the atomization source for ringdown measurements in the CRDS mode. Initial demonstration of the instrument is carried out by observing OES of multiple elements including mercury (Hg) in the OES mode and by measuring absolute concentrations of Hg in the metastable state 6s6p 3P0 in the CRDS mode, in which a palm-size diode laser operating at a single wavelength 405 nm is incorporated in the spectrometer as the light source. In the OES mode, the detection limit for Hg is determined to be 44 parts per 109 (ppb). A strong radiation trapping effect on emission measurements of Hg at 254 nm is observed when the Hg solution concentration is higher than 50 parts per 106 (ppm). The radiation trapping effect suggests that two different transition lines of Hg at 253.65 nm and 365.01 nm be selected for emission measurements in lower (50 ppm), respectively. In the CRDS mode, the detection limit of Hg in the metastable state 6s6p 3P0 is achieved to be 2.24 parts per 1012 (ppt) when the plasma is operating at 150 W with sample gas flow rate of 480 mL min-1; the detection limit corresponds to 50 ppm in Hg sample solution. Advantage of this novel spectrometer has two-fold, it has a large measurement dynamic range, from a few ppt to hundreds ppm and the CRDS mode can serve as calibration for the OES mode as well as high sensitivity measurements. Measurements of seven other elements, As, Cd, Mn, Ni, P, Pb, and Sr, using the OES mode are also carried out with detection limits of 1100, 33, 30, 144, 576, 94, and 2 ppb, respectively. Matrix effect in the presence of other elements on Hg measurements has been found to increase the detection limit to 131 ppb. These elements in lower
DEFF Research Database (Denmark)
Berg, Rolf W.
This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules.......This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules....
Yasui, Takeshi
2017-08-01
Optical frequency combs are innovative tools for broadband spectroscopy because a series of comb modes can serve as frequency markers that are traceable to a microwave frequency standard. However, a mode distribution that is too discrete limits the spectral sampling interval to the mode frequency spacing even though individual mode linewidth is sufficiently narrow. Here, using a combination of a spectral interleaving and dual-comb spectroscopy in the terahertz (THz) region, we achieved a spectral sampling interval equal to the mode linewidth rather than the mode spacing. The spectrally interleaved THz comb was realized by sweeping the laser repetition frequency and interleaving additional frequency marks. In low-pressure gas spectroscopy, we achieved an improved spectral sampling density of 2.5 MHz and enhanced spectral accuracy of 8.39 × 10-7 in the THz region. The proposed method is a powerful tool for simultaneously achieving high resolution, high accuracy, and broad spectral coverage in THz spectroscopy.
Extreme gravity tests with gravitational waves from compact binary coalescences: (II) ringdown
Berti, Emanuele; Yagi, Kent; Yang, Huan; Yunes, Nicolás
2018-05-01
The LIGO/Virgo detections of binary black hole mergers marked a watershed moment in astronomy, ushering in the era of precision tests of Kerr dynamics. We review theoretical and experimental challenges that must be overcome to carry out black hole spectroscopy with present and future gravitational wave detectors. Among other topics, we discuss quasinormal mode excitation in binary mergers, astrophysical event rates, tests of black hole dynamics in modified theories of gravity, parameterized "post-Kerr" ringdown tests, exotic compact objects, and proposed data analysis methods to improve spectroscopic tests of Kerr dynamics by stacking multiple events.
Energy Technology Data Exchange (ETDEWEB)
Sala, Matthieu; Egorova, Dassia
2016-12-20
The multi-dimensional electronic spectroscopy of ultrafast nuclear dynamics at conical intersections (CI) is an emerging field of investigation, which profits also from the recent extension of the techniques to the UV domain. We present a detailed computational study of oscillatory signatures in two-dimensional (2D) photon-echo spectroscopy (also known as 2D electronic spectroscopy, 2DES) for the two-mode pyrazine model with dissipation. Conventional 2D signals as well as the resulting beating maps are considered. Although of a reduced character, the model captures quite well all the main signatures of the excited-state dynamics of the molecule. Due to the ultrafast relaxation via the CI and no excited-state absorption from the low-lying dark state, the oscillatory components of the signal are found to be predominantly determined by the ground state bleach contribution. They reflect, therefore, the ground-state vibrational coherence induced in the Raman active mode. Beating maps provide a way to experimentally differentiate between ground state bleach and stimulated emission oscillatory components. The ultrafast decay of the latter constitutes a clear indirect signature of the CI. In the considered model, because of the sign properties of the involved transition dipole moments, the dominance of the ground-state coherence leads to anti-correlated oscillations of cross peaks located at symmetric positions with respect to the main diagonal.
Directory of Open Access Journals (Sweden)
R. da Rocha
2017-12-01
Full Text Available Sound waves on a fluid stream, in a de Laval nozzle, are shown to correspond to quasinormal modes emitted by black holes that are physical solutions in a quadratic curvature gravity with cosmological constant. Sound waves patterns in transsonic regimes at a laboratory are employed here to provide experimental data regarding generalized theories of gravity, comprised by the exact de Sitter-like solution and a perturbative solution around the Schwarzschildâde Sitter standard solution as well. Using the classical tests of General Relativity to bound free parameters in these solutions, acoustic perturbations on fluid flows in nozzles are then regarded, to study quasinormal modes of these black holes solutions, providing deviations of the de Laval nozzle cross-sectional area, when compared to the Schwarzschild solution. The fluid sonic point in the nozzle, for sound waves in the fluid, is shown to implement the acoustic event horizon corresponding to quasinormal modes. Keywords: Black holes, Fluid branes, Fluid dynamics, Quadratic curvature gravity, de Laval nozzle
Black Hole Spectroscopy with Coherent Mode Stacking.
Yang, Huan; Yagi, Kent; Blackman, Jonathan; Lehner, Luis; Paschalidis, Vasileios; Pretorius, Frans; Yunes, Nicolás
2017-04-21
The measurement of multiple ringdown modes in gravitational waves from binary black hole mergers will allow for testing the fundamental properties of black holes in general relativity and to constrain modified theories of gravity. To enhance the ability of Advanced LIGO/Virgo to perform such tasks, we propose a coherent mode stacking method to search for a chosen target mode within a collection of multiple merger events. We first rescale each signal so that the target mode in each of them has the same frequency and then sum the waveforms constructively. A crucial element to realize this coherent superposition is to make use of a priori information extracted from the inspiral-merger phase of each event. To illustrate the method, we perform a study with simulated events targeting the ℓ=m=3 ringdown mode of the remnant black holes. We show that this method can significantly boost the signal-to-noise ratio of the collective target mode compared to that of the single loudest event. Using current estimates of merger rates, we show that it is likely that advanced-era detectors can measure this collective ringdown mode with one year of coincident data gathered at design sensitivity.
Brintlinger, Todd; Herzing, Andrew A; Long, James P; Vurgaftman, Igor; Stroud, Rhonda; Simpkins, B S
2015-06-23
We have produced large numbers of hybrid metal-semiconductor nanogap antennas using a scalable electrochemical approach and systematically characterized the spectral and spatial character of their plasmonic modes with optical dark-field scattering, electron energy loss spectroscopy with principal component analysis, and full wave simulations. The coordination of these techniques reveal that these nanostructures support degenerate transverse modes which split due to substrate interactions, a longitudinal mode which scales with antenna length, and a symmetry-forbidden gap-localized transverse mode. This gap-localized transverse mode arises from mode splitting of transverse resonances supported on both antenna arms and is confined to the gap load enabling (i) delivery of substantial energy to the gap material and (ii) the possibility of tuning the antenna resonance via active modulation of the gap material's optical properties. The resonant position of this symmetry-forbidden mode is sensitive to gap size, dielectric strength of the gap material, and is highly suppressed in air-gapped structures which may explain its absence from the literature to date. Understanding the complex modal structure supported on hybrid nanosystems is necessary to enable the multifunctional components many seek.
Transverse Electromagnetic Mode Conversion for High-Harmonic Self-Probing Spectroscopy
Directory of Open Access Journals (Sweden)
Antoine Camper
2015-02-01
Full Text Available We report on high-order harmonic (HHG two-source interferometry (TSI in molecular gases. We used a 0-\\(\\pi\\ phase plate to create two bright spots at the focus of a lens by converting a Gaussian laser beam into a TEM please define \\(_{01}\\ Transverse Electromagnetic Mode. The two bright foci produce two synchronized HHG sources. One of them is used to probe on-going dynamics in the generating medium, while the other serves to heterodyne the signal. The interference of the emissions in the far–field gives access to the phase difference between the two sources. In self–probing HHG phase spectroscopy, one of the two sources is used as a reference while the other one probes some on goin dynamics in the generating medium. We first compute overlap integrals to investigate the mode conversion efficiency. We then establish a clear relation between the laser phase-front curvature and the far-field overlap of the two HHG beams. Both Fresnel diffraction calculations and an experimental lens position scan are used to reveal variations of the phase front inclination in each source. We show that this arrangement offers \\(\\frac{\\lambda_{XUV}}{100}\\ precision, enabling extremely sensitive phase measurements. Finally, we use this compact setup for TSI and measure phase variations across the molecular alignment revival of nitrogen and in vibrating sulfur hexafluoride. In both gases, the phase variations change sign around the ionization threshold of the investigated molecule.
Classical and quantum temperature fluctuations via holography
Energy Technology Data Exchange (ETDEWEB)
Balatsky, Alexander V. [KTH Royal Inst. of Technology, Stockholm (Sweden); Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Gudnason, Sven Bjarke [KTH Royal Inst. of Technology, Stockholm (Sweden); Thorlacius, Larus [KTH Royal Inst. of Technology, Stockholm (Sweden); University of Iceland, Reykjavik (Iceland); Zarembo, Konstantin [KTH Royal Inst. of Technology, Stockholm (Sweden); Inst. of Theoretical and Experimental Physics (ITEP), Moscow (Russian Federation); Uppsala Univ. (Sweden); Krikun, Alexander [KTH Royal Inst. of Technology, Stockholm (Sweden); Inst. of Theoretical and Experimental Physics (ITEP), Moscow (Russian Federation); Kedem, Yaron [KTH Royal Inst. of Technology, Stockholm (Sweden)
2014-05-27
We study local temperature fluctuations in a 2+1 dimensional CFT on the sphere, dual to a black hole in asymptotically AdS space-time. The fluctuation spectrum is governed by the lowest-lying hydrodynamic sound modes of the system whose frequency and damping rate determine whether temperature fluctuations are thermal or quantum. We calculate numerically the corresponding quasinormal frequencies and match the result with the hydrodynamics of the dual CFT at large temperature. As a by-product of our analysis we determine the appropriate boundary conditions for calculating low-lying quasinormal modes for a four-dimensional Reissner-Nordstrom black hole in global AdS.
He, Lian; Lin, Yu; Shang, Yu; Shelton, Brent J.; Yu, Guoqiang
2013-01-01
The dual-wavelength diffuse correlation spectroscopy (DCS) flow-oximeter is an emerging technique enabling simultaneous measurements of blood flow and blood oxygenation changes in deep tissues. High signal-to-noise ratio (SNR) is crucial when applying DCS technologies in the study of human tissues where the detected signals are usually very weak. In this study, single-mode, few-mode, and multimode fibers are compared to explore the possibility of improving the SNR of DCS flow-oximeter measure...
Modeling and simulations of light emission and propagation in open nanophotonic systems
DEFF Research Database (Denmark)
de Lasson, Jakob Rosenkrantz
computational uncertainty to be of larger magnitude than typical estimates found in literature. A photonic crystal waveguide with one or two side-coupled cavities is considered, and the local density of states is described using a semi-analytical quasi-normal mode theory. We propose original techniques...... for computing and normalizing quasi-normal modes in extended systems, and comparing to numerically exact calculations, the theory correctly predicts a slight asymmetry (one cavity) and a peak and a dip (two cavities) in the local density of states spectra. Next, the photonic crystal waveguide is interfaced....... In a disjoint chapter, we study the localized surface plasmon modes of plasmonic nanodimers, and both theoretically and experimentally, we find an almost-inverse scaling of the relative shift of the plasmon wavelength with particle distance in the sub-radius range....
Vogt, Dominik Walter; Leonhardt, Rainer
2017-07-10
We report on data processing for continuous wave (CW) terahertz (THz) spectroscopy measurements based on a Hilbert spectral analysis to achieve MHz resolution. As an example we investigate the spectral properties of a whispering gallery mode (WGM) THz bubble resonator at critical coupling. The experimental verification clearly demonstrates the significant advantages in relative frequency resolution and required acquisition time of the proposed method over the traditional data analysis. An effective frequency resolution, only limited by the precision and stability of the laser beat signal, can be achieved without complex extensions to a standard commercially available CW THz spectrometer.
Temperature-Corrected Oxygen Detection Based on Multi-Mode Diode Laser Correlation Spectroscopy
Directory of Open Access Journals (Sweden)
Xiutao Lou
2013-01-01
Full Text Available Temperature-corrected oxygen measurements were performed by using multi-mode diode laser correlation spectroscopy at temperatures ranging between 300 and 473 K. The experiments simulate in situ monitoring of oxygen in coal-combustion exhaust gases at the tail of the flue. A linear relationship with a correlation coefficient of −0.999 was found between the evaluated concentration and the gas temperature. Temperature effects were either auto-corrected by keeping the reference gas at the same conditions as the sample gas, or rectified by using a predetermined effective temperature-correction coefficient calibrated for a range of absorption wavelengths. Relative standard deviations of the temperature-corrected oxygen concentrations obtained by different schemes and at various temperatures were estimated, yielding a measurement precision of 0.6%.
He, Lian; Lin, Yu; Shang, Yu; Shelton, Brent J.; Yu, Guoqiang
2013-03-01
The dual-wavelength diffuse correlation spectroscopy (DCS) flow-oximeter is an emerging technique enabling simultaneous measurements of blood flow and blood oxygenation changes in deep tissues. High signal-to-noise ratio (SNR) is crucial when applying DCS technologies in the study of human tissues where the detected signals are usually very weak. In this study, single-mode, few-mode, and multimode fibers are compared to explore the possibility of improving the SNR of DCS flow-oximeter measurements. Experiments on liquid phantom solutions and in vivo muscle tissues show only slight improvements in flow measurements when using the few-mode fiber compared with using the single-mode fiber. However, light intensities detected by the few-mode and multimode fibers are increased, leading to significant SNR improvements in detections of phantom optical property and tissue blood oxygenation. The outcomes from this study provide useful guidance for the selection of optical fibers to improve DCS flow-oximeter measurements.
Verma, Ajay; Baishya, Bikash
2016-05-01
;Pure shift; NMR spectra display singlet peak per chemical site. Thus, high resolution is offered at the cost of valuable J-coupling information. In the present work, real-time BIRD (BIlinear Rotation Decoupling) is applied to the absorptive-mode 2D J-spectroscopy to provide pure shift spectrum in the direct dimension and J-coupling information in the indirect dimension. Quite often in metabolomics, proton NMR spectra from complex bio-fluids display tremendous signal overlap. Although conventional J-spectroscopy in principle overcomes this problem by separating the multiplet information from chemical shift information, however, only magnitude mode of the experiment is practical, sacrificing much of the potential high resolution that could be achieved. Few J-spectroscopy methods have been reported so far that produce high-resolution pure shift spectrum along with J-coupling information for crowded spectral regions. In the present work, high-quality J-resolved spectrum from important metabolomic mixture such as tissue extract from rat cortex is demonstrated. Many low-intensity metabolite peaks which are obscured by the broad dispersive tails from high-intensity metabolite peaks in regular magnitude mode J-spectrum can be clearly identified in real-time BIRD J-resolved spectrum. The general practice of removing such spectral overlap is tedious and time-consuming as it involves repeated sample preparation to change the pH of the tissue extract sample and subsequent spectra recording.
Gravitational waves from a spinning particle scattered by a relativistic star: Axial mode case
International Nuclear Information System (INIS)
Tominaga, Kazuhiro; Saijo, Motoyuki; Maeda, Kei-ichi
2001-01-01
We use a perturbation method to study gravitational waves from a spinning test particle scattered by a relativistic star. The present analysis is restricted to axial modes. By calculating the energy spectrum, the wave forms, and the total energy and angular momentum of gravitational waves, we analyze the dependence of the emitted gravitational waves on particle spin. For a normal neutron star, the energy spectrum has one broad peak whose characteristic frequency corresponds to the angular velocity at the turning point (a periastron). Since the turning point is determined by the orbital parameter, there exists a dependence of the gravitational wave on particle spin. We find that the total energy of l=2 gravitational waves gets larger as the spin increases in the antiparallel direction to the orbital angular momentum. For an ultracompact star, in addition to such an orbital contribution, we find the quasinormal modes excited by a scattered particle, whose excitation rate to gravitational waves depends on the particle spin. We also discuss the ratio of the total angular momentum to the total energy of gravitational waves and explain its spin dependence
Inter-comb synchronization by mode-to-mode locking
Chun, Byung Jae; Kim, Young-Jin; Kim, Seung-Woo
2016-08-01
Two combs of fiber femtosecond lasers are synchronized through the optical frequency reference created by injection-locking of a diode laser to a single comb mode. Maintaining a mHz-level narrow linewidth, the optical frequency reference permits two combs to be stabilized by mode-to-mode locking with a relative stability of 1.52 × 10-16 at 10 s with a frequency slip of 2.46 mHz. This inter-comb synchronization can be utilized for applications such as dual-comb spectroscopy or ultra-short pulse synthesis without extra narrow-linewidth lasers.
Maekawa, Hiroaki; Sul, Soohwan; Ge, Nien-Hui
2013-08-01
We have applied infrared three-pulse photon echo and single- and dual-frequency 2D IR spectroscopy to the ester Cdbnd O and diazo Ndbnd N stretching modes in ethyl diazoacetate (EDA), and investigated their vibrational frequency fluctuations and correlation. The two modes exhibit different vibrational dynamics and 2D lineshape, which are well simulated by frequency-frequency correlation functions (FFCFs) with two decaying components. Although the FT IR spectrum shows a single Cdbnd O band, absolute magnitude 2D IR nonrephasing spectrum displays spectral signatures supporting the presence of cis and trans conformations. The cross-peak inclined toward the anti-diagonal in the dual-frequency 2D IR spectrum, indicating that the frequency fluctuations of the two modes are anticorrelated. This behavior is attributed to anticorrelated change in the bond orders when solvent and structural fluctuations causes EDA to adopt a different mixture of the two dominant resonance structures. The effects of cross FFCF on the cross-peak line shape are discussed.
Energy Technology Data Exchange (ETDEWEB)
Kado, S. [High Temperature Plasma Center, University of Tokyo, Kashiwanoha, Kashiwa, Chiba 277-8568 (Japan)]. E-mail: kado@q.t.u-tokyo.ac.jp; Oishi, T. [School of Engineering, University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Yoshinuma, M. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Ida, K. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Takeuchi, M. [Department of Energy Engineering and Science, Nagoya University, Nagoya 464-8603 (Japan); Toi, K. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Akiyama, T. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Minami, T. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Nagaoka, K. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Shimizu, A. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Okamura, S. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Tanaka, S. [School of Engineering, University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan)
2007-06-15
Edge harmonic oscillations (EHO) offer the potential to relax the H-mode pedestal in a tokamak, thus avoiding edge localised modes (ELM). The mode structure of the EHO in CHS was investigated using a poloidal array of beam emission spectroscopy (BES) and a magnetic probe array. The EHO exhibited a peculiar characteristic in which the first, second and third harmonics show the same wavenumber, suggesting that the propagation velocities are different. Change in the phase of higher harmonics at the time when that of the first harmonic is zero can be described as a variation along the (m, n) = (-2, 1) mode structure, though the EHO lies on the {iota} = 1 surface. This behavior leads to an oscillation that exhibits periodic dependence of shape on spatial position.
Journal of Astrophysics and Astronomy | Indian Academy of Sciences
Indian Academy of Sciences (India)
corrected Schwarzschild black hole. The complex frequencies of the quasinormal modes are evaluated by the third-order WKB approximation. The numerical results obtained showed that the complex frequencies depend on the quantum ...
High resolution main-ion charge exchange spectroscopy in the DIII-D H-mode pedestal.
Grierson, B A; Burrell, K H; Chrystal, C; Groebner, R J; Haskey, S R; Kaplan, D H
2016-11-01
A new high spatial resolution main-ion (deuterium) charge-exchange spectroscopy system covering the tokamak boundary region has been installed on the DIII-D tokamak. Sixteen new edge main-ion charge-exchange recombination sightlines have been combined with nineteen impurity sightlines in a tangentially viewing geometry on the DIII-D midplane with an interleaving design that achieves 8 mm inter-channel radial resolution for detailed profiles of main-ion temperature, velocity, charge-exchange emission, and neutral beam emission. At the plasma boundary, we find a strong enhancement of the main-ion toroidal velocity that exceeds the impurity velocity by a factor of two. The unique combination of experimentally measured main-ion and impurity profiles provides a powerful quasi-neutrality constraint for reconstruction of tokamak H-mode pedestals.
Directory of Open Access Journals (Sweden)
Tsen Shaw-Wei D
2006-09-01
Full Text Available Abstract Background Recently, a technique which departs radically from conventional approaches has been proposed. This novel technique utilizes biological objects such as viruses as nano-templates for the fabrication of nanostructure elements. For example, rod-shaped viruses such as the M13 phage and tobacco mosaic virus have been successfully used as biological templates for the synthesis of semiconductor and metallic nanowires. Results and discussion Low wave number (≤ 20 cm-1 acoustic vibrations of the M13 phage have been studied using Raman spectroscopy. The experimental results are compared with theoretical calculations based on an elastic continuum model and appropriate Raman selection rules derived from a bond polarizability model. The observed Raman mode has been shown to belong to one of the Raman-active axial torsion modes of the M13 phage protein coat. Conclusion It is expected that the detection and characterization of this low frequency vibrational mode can be used for applications in nanotechnology such as for monitoring the process of virus functionalization and self-assembly. For example, the differences in Raman spectra can be used to monitor the coating of virus with some other materials and nano-assembly process, such as attaching a carbon nanotube or quantum dots.
Directory of Open Access Journals (Sweden)
Masaharu Kagawa
2014-05-01
Full Text Available The aim of the study was to examine differences in total body water (TBW measured using single-frequency (SF and multi-frequency (MF modes of bioelectrical impedance spectroscopy (BIS in children and adults measured in different postures using the deuterium (2H dilution technique as the reference. Twenty-three boys and 26 adult males underwent assessment of TBW using the dilution technique and BIS measured in supine and standing positions using two frequencies of the SF mode (50 kHz and 100 kHz and the MF mode. While TBW estimated from the MF mode was comparable, extra-cellular fluid (ECF and intra-cellular fluid (ICF values differed significantly (p < 0.01 between the different postures in both groups. In addition, while estimated TBW in adult males using the MF mode was significantly (p < 0.01 greater than the result from the dilution technique, TBW estimated using the SF mode and prediction equation was significantly (p < 0.01 lower in boys. Measurement posture may not affect estimation of TBW in boys and adult males, however, body fluid shifts may still occur. In addition, technical factors, including selection of prediction equation, may be important when TBW is estimated from measured impedance.
Mesons versus quasi-normal modes: undercooling and overheating
Paredes Galan, A.; Peeters, K.; Zamaklar, m.
2008-01-01
In holographic models of gauge theories with matter, there generically exists a first order phase transition in which mesons dissociate. We perform a careful analysis of the meson and quasi-particle spectra in the overheated resp. undercooled regimes close to the junction of the two phases. We show
Yao, Hiroshi; Shiratsu, Taisuke
2016-05-01
Large magneto-optical (MO) responses at the energy of localized surface plasmon resonance (LSPR), namely, surface magnetoplasmons, are demonstrated for the first time in thiolate-protected silver nanoparticles with magnetic circular dichroism (MCD) spectroscopy. The samples examined are decanethiol (DT)-, azobenzenethiol (ABT)-, and ABT/DT mixed-monolayer-protected Ag nanoparticles. ABT-protected Ag nanoparticles are somewhat aggregated and thus exhibit a broad, collective mode of plasmonic absorption, whereas other samples with highly-dispersed nanoparticles show an individual mode of LSPR absorption. In all Ag nanoparticles, a derivative-like MCD signal is observed under an applied magnetic field of 1.6 T, which can be explained in terms of two circular modes of magnetoplasmon caused by the increase (or decrease) in the Lorentz force imparted on the free electrons that oscillate in the left (or right) circular orbits in the nanosphere. For the Ag nanoparticles exhibiting an individual LSPR mode, in particular, simultaneous deconvolution analysis of UV-vis absorption and MCD spectra reveal that (i) the amplitude of the magnetoplasmonic component with lower frequency (ω-), resulting from the reduction in the confinement strength of collective electrons by the Lorentz force, is stronger than that with a higher frequency (ω+) (ii) the accurate shift or cyclotron frequency between two magnetoplasmonic modes (ωc = ω+ - ω-) is size-dependent, and presents a very large value with implications for the apparent enhancement of the local magnetic-field in the Ag nanoparticles. These results strongly suggest that the Ag-thiolate layer or Ag-S bonding on the nanoparticle surface plays a significant role in the MO enhancement.Large magneto-optical (MO) responses at the energy of localized surface plasmon resonance (LSPR), namely, surface magnetoplasmons, are demonstrated for the first time in thiolate-protected silver nanoparticles with magnetic circular dichroism (MCD
International Nuclear Information System (INIS)
Umapathy, S.; Mallick, B.; Lakshmanna, A.
2010-01-01
Ultrafast Raman loss spectroscopy (URLS) enables one to obtain the vibrational structural information of molecular systems including fluorescent materials. URLS, a nonlinear process analog to stimulated Raman gain, involves a narrow bandwidth picosecond Raman pump pulse and a femtosecond broadband white light continuum. Under nonresonant condition, the Raman response appears as a negative (loss) signal, whereas, on resonance with the electronic transition the line shape changes from a negative to a positive through a dispersive form. The intensities observed and thus, the Franck-Condon activity (coordinate dependent), are sensitive to the wavelength of the white light corresponding to a particular Raman frequency with respect to the Raman pump pulse wavelength, i.e., there is a mode-dependent response in URLS.
Black hole acoustics in the minimal geometric deformation of a de Laval nozzle
Energy Technology Data Exchange (ETDEWEB)
Rocha, Roldao da [Universidade Federal do ABC-UFABC, Centro de Matematica, Computacao e Cognicao, Santo Andre (Brazil)
2017-05-15
The correspondence between sound waves, in a de Laval propelling nozzle, and quasinormal modes emitted by brane-world black holes deformed by a 5D bulk Weyl fluid are here explored and scrutinized. The analysis of sound waves patterns in a de Laval nozzle in the laboratory, reciprocally, is here shown to provide relevant data about the 5D bulk Weyl fluid and its on-brane projection, comprised by the minimal geometrically deformed compact stellar distribution on the brane. Acoustic perturbations of the gas fluid flow in the de Laval nozzle are proved to coincide with the quasinormal modes of black holes solutions deformed by the 5D Weyl fluid, in the geometric deformation procedure. Hence, in a phenomenological Eoetvoes-Friedmann fluid brane-world model, the realistic shape of a de Laval nozzle is derived and its consequences studied. (orig.)
Gravitational radiation emitted when a mass falls onto a compact star.
Borelli, A.
1997-03-01
The authors study the energy spectrum related to the axial perturbations of a compact star when a particle falls spiralling onto it. They find that both slowly-damped quasi-normal modes and strongly damped w-modes are excited, and that a part of the energy in the process is associated to these w-modes. A substantial difference between the energy spectra of compact stars and black holes is shown.
Far-infrared vibrational modes of DNA components studied by terahertz time-domain spectroscopy
International Nuclear Information System (INIS)
Fischer, B M; Walther, M; Jepsen, P Uhd
2002-01-01
The far-infrared dielectric function of a wide range of organic molecules is dominated by vibrations involving a substantial fraction of the atoms forming the molecule and motion associated with intermolecular hydrogen bond vibrations. Due to their collective nature such modes are highly sensitive to the intra- and intermolecular structure and thus provide a unique fingerprint of the conformational state of the molecule and effects of its environment. We demonstrate the use of terahertz time-domain spectroscopy (THz-TDS) for recording the far-infrared (0.5-4.0 THz) dielectric function of the four nucleobases and corresponding nucleosides forming the building blocks of deoxyribose nucleic acid (DNA). We observe numerous distinct spectral features with large differences between the molecules in both frequency-dependent absorption coefficient and index of refraction. Assisted by results from density-functional calculations we interpret the origin of the observed resonances as vibrations of hydrogen bonds between the molecules
Quantum quenches in a holographic Kondo model
Erdmenger, Johanna; Flory, Mario; Newrzella, Max-Niklas; Strydom, Migael; Wu, Jackson M. S.
2017-04-01
We study non-equilibrium dynamics and quantum quenches in a recent gauge/gravity duality model for a strongly coupled system interacting with a magnetic impurity with SU( N ) spin. At large N , it is convenient to write the impurity spin as a bilinear in Abrikosov fermions. The model describes an RG flow triggered by the marginally relevant Kondo operator. There is a phase transition at a critical temperature, below which an operator condenses which involves both an electron and an Abrikosov fermion field. This corresponds to a holographic superconductor in AdS2 and models the impurity screening. We quench the Kondo coupling either by a Gaussian pulse or by a hyperbolic tangent, the latter taking the system from the condensed to the uncondensed phase or vice-versa. We study the time dependence of the condensate induced by this quench. The timescale for equilibration is generically given by the leading quasinormal mode of the dual gravity model. This mode also governs the formation of the screening cloud, which is obtained as the decrease of impurity degrees of freedom with time. In the condensed phase, the leading quasinormal mode is imaginary and the relaxation of the condensate is over-damped. For quenches whose final state is close to the critical point of the large N phase transition, we study the critical slowing down and obtain the combination of critical exponents zν = 1. When the final state is exactly at the phase transition, we find that the exponential ringing of the quasinormal modes is replaced by a power-law behaviour of the form ˜ t - a sin( b log t). This indicates the emergence of a discrete scale invariance.
International Nuclear Information System (INIS)
Maekawa, Hiroaki; Sul, Soohwan; Ge, Nien-Hui
2013-01-01
Highlights: ► Vibrational dynamics of conjugated C=O and N=N modes of ethyl diazoacetate was studied. ► Their frequency–frequency correlation functions are different. ► The dual-frequency 2D IR spectrum indicates anticorrelated frequency fluctuations. ► Correlation effects on dual-frequency 2D IR spectra are discussed. ► The existence of cis and trans conformers is revealed in 2D IR spectra. - Abstract: We have applied infrared three-pulse photon echo and single- and dual-frequency 2D IR spectroscopy to the ester C=O and diazo N=N stretching modes in ethyl diazoacetate (EDA), and investigated their vibrational frequency fluctuations and correlation. The two modes exhibit different vibrational dynamics and 2D lineshape, which are well simulated by frequency–frequency correlation functions (FFCFs) with two decaying components. Although the FT IR spectrum shows a single C=O band, absolute magnitude 2D IR nonrephasing spectrum displays spectral signatures supporting the presence of cis and trans conformations. The cross-peak inclined toward the anti-diagonal in the dual-frequency 2D IR spectrum, indicating that the frequency fluctuations of the two modes are anticorrelated. This behavior is attributed to anticorrelated change in the bond orders when solvent and structural fluctuations causes EDA to adopt a different mixture of the two dominant resonance structures. The effects of cross FFCF on the cross-peak line shape are discussed
Energy Technology Data Exchange (ETDEWEB)
Maekawa, Hiroaki; Sul, Soohwan [Department of Chemistry, University of California at Irvine, Irvine, CA 92697-2025 (United States); Ge, Nien-Hui, E-mail: nhge@uci.edu [Department of Chemistry, University of California at Irvine, Irvine, CA 92697-2025 (United States)
2013-08-30
Highlights: ► Vibrational dynamics of conjugated C=O and N=N modes of ethyl diazoacetate was studied. ► Their frequency–frequency correlation functions are different. ► The dual-frequency 2D IR spectrum indicates anticorrelated frequency fluctuations. ► Correlation effects on dual-frequency 2D IR spectra are discussed. ► The existence of cis and trans conformers is revealed in 2D IR spectra. - Abstract: We have applied infrared three-pulse photon echo and single- and dual-frequency 2D IR spectroscopy to the ester C=O and diazo N=N stretching modes in ethyl diazoacetate (EDA), and investigated their vibrational frequency fluctuations and correlation. The two modes exhibit different vibrational dynamics and 2D lineshape, which are well simulated by frequency–frequency correlation functions (FFCFs) with two decaying components. Although the FT IR spectrum shows a single C=O band, absolute magnitude 2D IR nonrephasing spectrum displays spectral signatures supporting the presence of cis and trans conformations. The cross-peak inclined toward the anti-diagonal in the dual-frequency 2D IR spectrum, indicating that the frequency fluctuations of the two modes are anticorrelated. This behavior is attributed to anticorrelated change in the bond orders when solvent and structural fluctuations causes EDA to adopt a different mixture of the two dominant resonance structures. The effects of cross FFCF on the cross-peak line shape are discussed.
Directory of Open Access Journals (Sweden)
V. S. Voropaev
2015-01-01
Full Text Available Many femtosecond engineering applications require for a stable generation of ultrashort pulses. Thus, in the terahertz pulsed spectroscopy a measurement error in the refractive index is strongly dependent on the pulse duration stability with allowable variation of few femtoseconds. The aim of this work is to study the ultrashort pulses (USP regimes stability in the all – fiber erbium doped ring laser with Kerr mode-locking. The study was conducted at several different values of the total resonator intra-cavity dispersion. Three laser schemes with the intra-cavity dispersion values from -1.232 ps2 to +0.008 ps2 have been studied. In the experiment there were two regimes of generation observed: the stretched pulse generation and ordinary soliton generation. Main attention is focused on the stability of regimes under study. The most stable regime was that of the stretched pulse generation with a spectrum form of sech2 , possible pulse duration of 490 fs at least, repetition rate of 2.9 MHz, and average output power of 17 mW. It is worth noting, that obtained regimes had characteristics suitable for the successful use in the terahertz pulsed spectroscopy. The results may be useful in the following areas of science and technology: a high-precision spectroscopy, optical frequency standards, super-continuum generation, and terahertz pulsed spectroscopy. The future system development is expected to stabilize duration and repetition rate of the obtained regime of ultra-short pulse generation.
Black-hole spectroscopy: testing general relativity through gravitational-wave observations
Energy Technology Data Exchange (ETDEWEB)
Dreyer, Olaf [Perimeter Institute of Theoretical Physics, 35 King Street North, Waterloo, Ontario, N2J 2G9 (Canada); Kelly, Bernard [Center for Gravitational Wave Physics, Center for Gravitational Physics and Geometry and Department of Physics, 104 Davey Laboratory, University Park, PA 16802 (United States); Krishnan, Badri [Max Planck Institut fuer Gravitationsphysik, Am Muehlenberg 1, D-14476 Golm (Germany); Finn, Lee Samuel [Center for Gravitational Wave Physics, Center for Gravitational Physics and Geometry, Department of Physics and Department of Astronomy and Astrophysics, 104 Davey Laboratory, University Park, PA 16802 (United States); Garrison, David [University of Houston, Clear Lake, 2700 Bay Area Bvd, Room 3531-2, Houston, TX 77058 (United States); Lopez-Aleman, Ramon [Physical Sciences Department, University of Puerto Rico, Rio Piedras Campus, Rio Piedras, Puerto Rico 00931 (Puerto Rico)
2004-02-21
Assuming that general relativity is the correct theory of gravity in the strong-field limit, can gravitational-wave observations distinguish between black holes and other compact object sources? Alternatively, can gravitational-wave observations provide a test of one of the fundamental predictions of general relativity: the no-hair theorem? Here we describe a definitive test of the hypothesis that observations of damped, sinusoidal gravitational waves originate from a black hole or, alternatively, that nature respects the general relativistic no-hair theorem. For astrophysical black holes, which have a negligible charge-to-mass ratio, the black-hole quasi-normal mode spectrum is characterized entirely by the black-hole mass and angular momentum and is unique to black holes. In a different theory of gravity, or if the observed radiation arises from a different source (e.g., a neutron star, strange matter or boson star), the spectrum will be inconsistent with that predicted for general relativistic black holes. We give a statistical characterization of the consistency between the noisy observation and the theoretical predictions of general relativity and a demonstration, through simulation, of the effectiveness of the test for strong sources.
Black-hole spectroscopy: testing general relativity through gravitational-wave observations
International Nuclear Information System (INIS)
Dreyer, Olaf; Kelly, Bernard; Krishnan, Badri; Finn, Lee Samuel; Garrison, David; Lopez-Aleman, Ramon
2004-01-01
Assuming that general relativity is the correct theory of gravity in the strong-field limit, can gravitational-wave observations distinguish between black holes and other compact object sources? Alternatively, can gravitational-wave observations provide a test of one of the fundamental predictions of general relativity: the no-hair theorem? Here we describe a definitive test of the hypothesis that observations of damped, sinusoidal gravitational waves originate from a black hole or, alternatively, that nature respects the general relativistic no-hair theorem. For astrophysical black holes, which have a negligible charge-to-mass ratio, the black-hole quasi-normal mode spectrum is characterized entirely by the black-hole mass and angular momentum and is unique to black holes. In a different theory of gravity, or if the observed radiation arises from a different source (e.g., a neutron star, strange matter or boson star), the spectrum will be inconsistent with that predicted for general relativistic black holes. We give a statistical characterization of the consistency between the noisy observation and the theoretical predictions of general relativity and a demonstration, through simulation, of the effectiveness of the test for strong sources
Craft, H. S.; Collazo, R.; Losego, M. D.; Mita, S.; Sitar, Z.; Maria, J.-P.
2007-10-01
MgO is a proposed dielectric for use as a tunneling barrier in devices integrating GaN and ferroelectric oxides. In this study, we present data regarding the growth mode and band offsets of MgO grown epitaxially on GaN (0002) surfaces using molecular beam epitaxy. Using in situ x-ray photoelectron spectroscopy (XPS) and molecular beam epitaxy, we determine, from sequential growth experiments, that the growth of MgO proceeds via the Volmer-Weber (three-dimensional) mode, and full coalescence of the film does not occur until approximately 12nm of MgO has been deposited. The observation of a three-dimensional growth mode is in agreement with previously published data. For the valence band offset, we find a value of 1.2±0.2eV, which corresponds to a 3.2eV conduction band offset. XPS measurements suggest a chemically abrupt interface and no effect on band lineup due to the slow coalescence behavior.
International Nuclear Information System (INIS)
Craft, H. S.; Collazo, R.; Losego, M. D.; Mita, S.; Sitar, Z.; Maria, J.-P.
2007-01-01
MgO is a proposed dielectric for use as a tunneling barrier in devices integrating GaN and ferroelectric oxides. In this study, we present data regarding the growth mode and band offsets of MgO grown epitaxially on GaN (0002) surfaces using molecular beam epitaxy. Using in situ x-ray photoelectron spectroscopy (XPS) and molecular beam epitaxy, we determine, from sequential growth experiments, that the growth of MgO proceeds via the Volmer-Weber (three-dimensional) mode, and full coalescence of the film does not occur until approximately 12 nm of MgO has been deposited. The observation of a three-dimensional growth mode is in agreement with previously published data. For the valence band offset, we find a value of 1.2±0.2 eV, which corresponds to a 3.2 eV conduction band offset. XPS measurements suggest a chemically abrupt interface and no effect on band lineup due to the slow coalescence behavior
Quantum quenches in a holographic Kondo model
Energy Technology Data Exchange (ETDEWEB)
Erdmenger, Johanna [Max-Planck-Institut für Physik (Werner-Heisenberg-Institut),Föhringer Ring 6, 80805, Munich (Germany); Institut für Theoretische Physik und Astrophysik, Julius-Maximilians-Universität Würzburg,Am Hubland, 97074 Würzburg (Germany); Flory, Mario [Max-Planck-Institut für Physik (Werner-Heisenberg-Institut),Föhringer Ring 6, 80805, Munich (Germany); Institute of Physics, Jagiellonian University,Łojasiewicza 11, 30-348 Kraków (Poland); Newrzella, Max-Niklas; Strydom, Migael [Max-Planck-Institut für Physik (Werner-Heisenberg-Institut),Föhringer Ring 6, 80805, Munich (Germany); Wu, Jackson M. S. [Department of Physics and Astronomy, University of Alabama,Tuscaloosa, AL 35487 (United States)
2017-04-10
We study non-equilibrium dynamics and quantum quenches in a recent gauge/ gravity duality model for a strongly coupled system interacting with a magnetic impurity with SU(N) spin. At large N, it is convenient to write the impurity spin as a bilinear in Abrikosov fermions. The model describes an RG flow triggered by the marginally relevant Kondo operator. There is a phase transition at a critical temperature, below which an operator condenses which involves both an electron and an Abrikosov fermion field. This corresponds to a holographic superconductor in AdS{sub 2} and models the impurity screening. We quench the Kondo coupling either by a Gaussian pulse or by a hyperbolic tangent, the latter taking the system from the condensed to the uncondensed phase or vice-versa. We study the time dependence of the condensate induced by this quench. The timescale for equilibration is generically given by the leading quasinormal mode of the dual gravity model. This mode also governs the formation of the screening cloud, which is obtained as the decrease of impurity degrees of freedom with time. In the condensed phase, the leading quasinormal mode is imaginary and the relaxation of the condensate is over-damped. For quenches whose final state is close to the critical point of the large N phase transition, we study the critical slowing down and obtain the combination of critical exponents zν=1. When the final state is exactly at the phase transition, we find that the exponential ringing of the quasinormal modes is replaced by a power-law behaviour of the form ∼t{sup −a}sin (blog t). This indicates the emergence of a discrete scale invariance.
Shan, Lei; Gong, Jing; Wang, Yong-Lei; Shen, Bing; Hou, Xingyuan; Ren, Cong; Li, Chunhong; Yang, Huan; Wen, Hai-Hu; Li, Shiliang; Dai, Pengcheng
2012-06-01
We used high-resolution scanning tunneling spectroscopy to study the hole-doped iron pnictide superconductor Ba(0.6)K(0.4)Fe(2)As(2) (T(c)=38 K). Features of a bosonic excitation (mode) are observed in the measured quasiparticle density of states. The bosonic features are intimately associated with the superconducting order parameter and have a mode energy of ~14 meV, similar to the spin resonance measured by inelastic neutron scattering. These results indicate a strong electron-spin excitation coupling in iron pnictide superconductors, similar to that in high-T(c) copper oxide superconductors.
Visualizing Infrared (IR) Spectroscopy with Computer Animation
Abrams, Charles B.; Fine, Leonard W.
1996-01-01
IR Tutor, an interactive, animated infrared (IR) spectroscopy tutorial has been developed for Macintosh and IBM-compatible computers. Using unique color animation, complicated vibrational modes can be introduced to beginning students. Rules governing the appearance of IR absorption bands become obvious because the vibrational modes can be visualized. Each peak in the IR spectrum is highlighted, and the animation of the corresponding normal mode can be shown. Students can study each spectrum stepwise, or click on any individual peak to see its assignment. Important regions of each spectrum can be expanded and spectra can be overlaid for comparison. An introduction to the theory of IR spectroscopy is included, making the program a complete instructional package. Our own success in using this software for teaching and research in both academic and industrial environments will be described. IR Tutor consists of three sections: (1) The 'Introduction' is a review of basic principles of spectroscopy. (2) 'Theory' begins with the classical model of a simple diatomic molecule and is expanded to include larger molecules by introducing normal modes and group frequencies. (3) 'Interpretation' is the heart of the tutorial. Thirteen IR spectra are analyzed in detail, covering the most important functional groups. This section features color animation of each normal mode, full interactivity, overlay of related spectra, and expansion of important regions. This section can also be used as a reference.
Black-hole ringdown search in TAMA300: matched filtering and event selections
International Nuclear Information System (INIS)
Tsunesada, Yoshiki; Kanda, Nobuyuki; Nakano, Hiroyuki; Tatsumi, Daisuke
2005-01-01
Detecting gravitational ringdown waves provides a probe for direct observation of astrophysical black holes. The masses and angular momenta of black holes can be determined from the waveforms by using the black-hole perturbation theory. In this paper we present data analysis methods to search for black-hole ringdowns of fundamental quasi-normal modes with interferometric gravitational wave detectors, and report an application to the TAMA300 data. Our method is based upon matched filtering by which we calculate cross-correlations between detector outputs and reference waveforms. In a search for gravitational signals, fake reductions and event identifications are of most importance. We developed two methods to reject spurious triggers in filter outputs in the time domain and examined their reduction powers. It is shown that by using the methods presented here the number of fake triggers can be reduced by an order with a false dismissal probability of 5%. We also discuss the possibility of using the higher order quasi-normal modes for event selection
Coherent cavity-enhanced dual-comb spectroscopy
Fleisher, Adam J.; Long, David A.; Reed, Zachary D.; Hodges, Joseph T.; Plusquellic, David F.
2016-01-01
Dual-comb spectroscopy allows for the rapid, multiplexed acquisition of high-resolution spectra without the need for moving parts or low-resolution dispersive optics. This method of broadband spectroscopy is most often accomplished via tight phase locking of two mode-locked lasers or via sophisticated signal processing algorithms, and therefore, long integration times of phase coherent signals are difficult to achieve. Here we demonstrate an alternative approach to dual-comb spectroscopy usin...
Detection of biologically active diterpenoic acids by Raman Spectroscopy
DEFF Research Database (Denmark)
Talian, Ivan; Orinak, Andrej; Efremov, Evtim V.
2010-01-01
Three poorly detectable, biologically active diterpenoic acids, kaurenoic, abietic, and gibberellic acid, were studied by using different modes of Raman spectroscopy. Because of their structural similarities, in the absence of strongly polarizable groups, conventional Raman spectroscopy is not su......Three poorly detectable, biologically active diterpenoic acids, kaurenoic, abietic, and gibberellic acid, were studied by using different modes of Raman spectroscopy. Because of their structural similarities, in the absence of strongly polarizable groups, conventional Raman spectroscopy...... few enhanced Raman lines. SERS spectra with 514-nm excitation with Ag colloids were also relatively weak. The best SERS spectrawere obtained with 785-nm excitation on a novel nanostructured substrate, 'black silicon' coated with a 400-nm gold layer. The spectra showed clear differences...
Haskey, S R; Grierson, B A; Burrell, K H; Chrystal, C; Groebner, R J; Kaplan, D H; Pablant, N A; Stagner, L
2016-11-01
Recent completion of a thirty two channel main-ion (deuterium) charge exchange recombination spectroscopy (CER) diagnostic on the DIII-D tokamak [J. L. Luxon, Nucl. Fusion 42, 614 (2002)] enables detailed comparisons between impurity and main-ion temperature, density, and toroidal rotation. In a H-mode DIII-D discharge, these new measurement capabilities are used to provide the deuterium density profile, demonstrate the importance of profile alignment between Thomson scattering and CER diagnostics, and aid in determining the electron temperature at the separatrix. Sixteen sightlines cover the core of the plasma and another sixteen are densely packed towards the plasma edge, providing high resolution measurements across the pedestal and steep gradient region in H-mode plasmas. Extracting useful physical quantities such as deuterium density is challenging due to multiple photoemission processes. These challenges are overcome using a detailed fitting model and by forward modeling the photoemission using the FIDASIM code, which implements a comprehensive collisional radiative model.
Two-dimensional vibrational-electronic spectroscopy
Courtney, Trevor L.; Fox, Zachary W.; Slenkamp, Karla M.; Khalil, Munira
2015-10-01
Two-dimensional vibrational-electronic (2D VE) spectroscopy is a femtosecond Fourier transform (FT) third-order nonlinear technique that creates a link between existing 2D FT spectroscopies in the vibrational and electronic regions of the spectrum. 2D VE spectroscopy enables a direct measurement of infrared (IR) and electronic dipole moment cross terms by utilizing mid-IR pump and optical probe fields that are resonant with vibrational and electronic transitions, respectively, in a sample of interest. We detail this newly developed 2D VE spectroscopy experiment and outline the information contained in a 2D VE spectrum. We then use this technique and its single-pump counterpart (1D VE) to probe the vibrational-electronic couplings between high frequency cyanide stretching vibrations (νCN) and either a ligand-to-metal charge transfer transition ([FeIII(CN)6]3- dissolved in formamide) or a metal-to-metal charge transfer (MMCT) transition ([(CN)5FeIICNRuIII(NH3)5]- dissolved in formamide). The 2D VE spectra of both molecules reveal peaks resulting from coupled high- and low-frequency vibrational modes to the charge transfer transition. The time-evolving amplitudes and positions of the peaks in the 2D VE spectra report on coherent and incoherent vibrational energy transfer dynamics among the coupled vibrational modes and the charge transfer transition. The selectivity of 2D VE spectroscopy to vibronic processes is evidenced from the selective coupling of specific νCN modes to the MMCT transition in the mixed valence complex. The lineshapes in 2D VE spectra report on the correlation of the frequency fluctuations between the coupled vibrational and electronic frequencies in the mixed valence complex which has a time scale of 1 ps. The details and results of this study confirm the versatility of 2D VE spectroscopy and its applicability to probe how vibrations modulate charge and energy transfer in a wide range of complex molecular, material, and biological systems.
Two-dimensional vibrational-electronic spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Courtney, Trevor L.; Fox, Zachary W.; Slenkamp, Karla M.; Khalil, Munira, E-mail: mkhalil@uw.edu [Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195 (United States)
2015-10-21
Two-dimensional vibrational-electronic (2D VE) spectroscopy is a femtosecond Fourier transform (FT) third-order nonlinear technique that creates a link between existing 2D FT spectroscopies in the vibrational and electronic regions of the spectrum. 2D VE spectroscopy enables a direct measurement of infrared (IR) and electronic dipole moment cross terms by utilizing mid-IR pump and optical probe fields that are resonant with vibrational and electronic transitions, respectively, in a sample of interest. We detail this newly developed 2D VE spectroscopy experiment and outline the information contained in a 2D VE spectrum. We then use this technique and its single-pump counterpart (1D VE) to probe the vibrational-electronic couplings between high frequency cyanide stretching vibrations (ν{sub CN}) and either a ligand-to-metal charge transfer transition ([Fe{sup III}(CN){sub 6}]{sup 3−} dissolved in formamide) or a metal-to-metal charge transfer (MMCT) transition ([(CN){sub 5}Fe{sup II}CNRu{sup III}(NH{sub 3}){sub 5}]{sup −} dissolved in formamide). The 2D VE spectra of both molecules reveal peaks resulting from coupled high- and low-frequency vibrational modes to the charge transfer transition. The time-evolving amplitudes and positions of the peaks in the 2D VE spectra report on coherent and incoherent vibrational energy transfer dynamics among the coupled vibrational modes and the charge transfer transition. The selectivity of 2D VE spectroscopy to vibronic processes is evidenced from the selective coupling of specific ν{sub CN} modes to the MMCT transition in the mixed valence complex. The lineshapes in 2D VE spectra report on the correlation of the frequency fluctuations between the coupled vibrational and electronic frequencies in the mixed valence complex which has a time scale of 1 ps. The details and results of this study confirm the versatility of 2D VE spectroscopy and its applicability to probe how vibrations modulate charge and energy transfer in a
Andrews, Mark P.; Kanigan, Tanya
2007-06-01
Orientation anisotropies in structural properties relevant to the use of cellulosic polymers as membranes for lab-on-chips were investigated for cellulose acetate (CA) and regenerated cellulose (RC) films deposited as slab waveguides. Anisotropy was probed with mode and polarization state selected guided wave Raman spectroscopy. CA exhibits partial chain orientation in the plane of the film, and this orientation is independent of sample substrate and film preparation conditions. RC films also show in-plane anisotropy, where the hexose sugar rings lie roughly in the plane of the film. Explanations are given of the role of artifacts in interpreting waveguide Raman spectra, including anomalous contributions to Raman spectra that arise from deviations from right angle scattering geometry, mode-dependent contributions to longitudinal electric field components and TETM mode conversion. We explore diffusion profiles of small molecules in cellulosic films by adaptations of an inverse-Wentzel-Kramers-Brillouin (iWKB) recursive, noninteger virtual mode index algorithm. Perturbations in the refractive index distribution, n(z), are recovered from the measured relative propagation constants, neffective,m, of the planar waveguide. The refractive index distribution then yields the diffusion profile.
Resonance spectrum of near-extremal Kerr black holes in the eikonal limit
International Nuclear Information System (INIS)
Hod, Shahar
2012-01-01
The fundamental resonances of rapidly rotating Kerr black holes in the eikonal limit are derived analytically. We show that there exists a critical value, μ c =√((15-√(193))/2 ), for the dimensionless ratio μ≡m/l between the azimuthal harmonic index m and the spheroidal harmonic index l of the perturbation mode, above which the perturbations become long lived. In particular, it is proved that above μ c the imaginary parts of the quasinormal frequencies scale like the black-hole temperature: ω I (n;μ>μ c )=2πT BH (n+1/2 ). This implies that for perturbations modes in the interval μ c I of the black hole becomes extremely long as the extremal limit T BH →0 is approached. A generalization of the results to the case of scalar quasinormal resonances of near-extremal Kerr-Newman black holes is also provided. In particular, we prove that only black holes that rotate fast enough (with MΩ≥2/5 , where M and Ω are the black-hole mass and angular velocity, respectively) possess this family of remarkably long-lived perturbation modes.
Scalar Hairy Black Holes in Four Dimensions are Unstable
Ganchev, Bogdan; Santos, Jorge E.
2018-04-01
We present a numerical analysis of the stability properties of the black holes with scalar hair constructed by Herdeiro and Radu. We prove the existence of a novel gauge where the scalar field perturbations decouple from the metric perturbations, and analyze the resulting quasinormal mode spectrum. We find unstable modes with characteristic growth rates which for uniformly small hair are almost identical to those of a massive scalar field on a fixed Kerr background.
Scalar Hairy Black Holes in Four Dimensions are Unstable.
Ganchev, Bogdan; Santos, Jorge E
2018-04-27
We present a numerical analysis of the stability properties of the black holes with scalar hair constructed by Herdeiro and Radu. We prove the existence of a novel gauge where the scalar field perturbations decouple from the metric perturbations, and analyze the resulting quasinormal mode spectrum. We find unstable modes with characteristic growth rates which for uniformly small hair are almost identical to those of a massive scalar field on a fixed Kerr background.
A versatile optical microscope for time-dependent single-molecule and single-particle spectroscopy
Li, Hao; Yang, Haw
2018-03-01
This work reports the design and implementation of a multi-function optical microscope for time-dependent spectroscopy on single molecules and single nanoparticles. It integrates the now-routine single-object measurements into one standalone platform so that no reconfiguration is needed when switching between different types of sample or spectroscopy modes. The illumination modes include evanescent field through total internal reflection, dark-field illumination, and epi-excitation onto a diffraction-limited spot suitable for confocal detection. The detection modes include spectrally resolved line imaging, wide-field imaging with dual-color capability, and two-color single-element photon-counting detection. The switch between different spectroscopy and data acquisition modes is fully automated and executed through computer programming. The capability of this microscope is demonstrated through selected proof-of-principle experiments.
A versatile optical microscope for time-dependent single-molecule and single-particle spectroscopy.
Li, Hao; Yang, Haw
2018-03-28
This work reports the design and implementation of a multi-function optical microscope for time-dependent spectroscopy on single molecules and single nanoparticles. It integrates the now-routine single-object measurements into one standalone platform so that no reconfiguration is needed when switching between different types of sample or spectroscopy modes. The illumination modes include evanescent field through total internal reflection, dark-field illumination, and epi-excitation onto a diffraction-limited spot suitable for confocal detection. The detection modes include spectrally resolved line imaging, wide-field imaging with dual-color capability, and two-color single-element photon-counting detection. The switch between different spectroscopy and data acquisition modes is fully automated and executed through computer programming. The capability of this microscope is demonstrated through selected proof-of-principle experiments.
Area spectra of near extremal black holes
International Nuclear Information System (INIS)
Chen, Deyou; Yang, Haitang; Zu, Xiaotao
2010-01-01
Motivated by Maggiore's new interpretation of quasinormal modes, we investigate area spectra of a near extremal Schwarzschild-de Sitter black hole and a higher-dimensional near extremal Reissner-Nordstrom-de Sitter black hole. The result shows that the area spectra are equally spaced and irrelevant to the parameters of the black holes. (orig.)
Ni, Li-Jun; Luan, Shao-Rong; Zhang, Li-Guo
2016-10-01
Because of the numerous varieties of herbal species and active ingredients in the traditional Chinese medicine(TCM),the traditional methods employed could hardly satisfy the current determination requirements of TCM.The present work proposed an idea to realize rapid determination of the quality of TCM based on near infrared(NIR)spectroscopy and internet sharing mode. Low cost and portable multi-source composite spectrometer was invented by our group for in-site fast measurement of spectra of TCM samples. The database could be set up by sharing spectra and quality detection data of TCM samples among TCM enterprises based on the internet platform.A novel method called as keeping same relationship between X and Y space based on K nearest neighbors(KNN-KSR for short)was applied to predict the contents of effective compounds of the samples. In addition,a comparative study between KNN-KSR and partial least squares(PLS)was conducted. Two datasets were applied to validate above idea:one was about 58 Ginkgo Folium samples samples measured with four near-infrared spectroscopy instruments and two multi-source composite spectrometers,another one was about 80 corn samples available online measured with three NIR instruments. The results show that the KNN-KSR method could obtain more reliable outcomes without correcting spectrum.However transforming the PLS models to other instruments could hardly acquire better predictive results until spectral calibration is performed. Meanwhile,the similar analysis results of total flavonoids and total lactones of Ginkgo Folium samples are achieved on the multi-source composite spectrometers and near-infrared spectroscopy instruments,and the prediction results of KNN-KSR are better than PLS. The idea proposed in present study is in urgent need of more samples spectra, and then to be verified by more case studies. Copyright© by the Chinese Pharmaceutical Association.
Evanescent spectroscopy - theory and experiment
Karabchevsky, Alina
2014-01-01
Outline1 Introduction2 Literature Overview3 Photonic-Plasmonic WaveguideStructureModellingTheory4 ResultsOptical TransmittanceLoss of Fundamental Mode in a Gold RegionOptical Surface Intensity5 NIR Spectroscopy - Experiment6 Conclusions7 Acknowledgements
Mork, Steven Wayne
High resolution infrared spectroscopy was used to examine intramolecular vibrational interactions in 2 -fluoroethanol (2FE) and 1,2-difluoroethane (DFE). A high resolution infrared spectrophotometer capable of better than 10 MHz spectral resolution was designed and constructed. The excitation source consists of three lasers: an argon-ion pumped dye laser which pumps a color -center laser. The infrared beam from the color-center laser is used to excite sample molecules which are rotationally and vibrationally cooled in a supersonic molecular beam. Rovibrational excitation of the sample molecules is detected by monitoring the kinetic energy of the molecular beam with a bolometer. The high resolution infrared spectrum of 2FE was collected and analyzed over the 2977-2990 cm^ {-1}^ectral region. This region contains the asymmetric CH stretch on the fluorinated carbon. The spectrum revealed extensive perturbations in the rotational fine structure. Analysis of these perturbations has provided a quantitative measure of selective vibrational mode coupling between the C-H stretch and its many neighboring dark vibrational modes. Interestingly, excitation of the C-H stretch is known to induce a photoisomerization reaction between 2FE's Gg^' and Tt conformers. Implications of the role of mode coupling in the reaction mechanism are also addressed. Similarly, the high resolution infrared spectrum of DFE was collected and analyzed over the 2978-2996 cm ^{-1}^ectral region. This region contains the symmetric combination of asymmetric C-H stretches in DFE. Perturbations in the rotational fine structure indicate vibrational mode coupling to a single dark vibrational state. The dark state is split by approximately 19 cm^{-1} due to tunneling between two identical gauche conformers. The coupling mechanism is largely anharmonic with a minor component of B/C-plane Coriolis coupling. Effects of centrifugal distortion along the molecular A-axis are also observed. The coupled vibrational
Stability analysis and quasinormal modes of Reissner–Nordstrøm ...
Indian Academy of Sciences (India)
Home; Journals; Pramana – Journal of Physics; Volume 87; Issue 1 .... Department of Physics, Vivekananda Satavarshiki Mahavidyalaya, Manikpara, Jhargram, West Midnapur 721 513, India ... Proceedings of the International Workshop/Conference on Computational Condensed Matter Physics and Materials Science
Quasinormal Modes of a Noncommutative-Geometry-Inspired Schwarzschild Black Hole
Liang, Jun
2018-01-01
Not Available Supported by the Natural Science Foundation of Education Department of Shannxi Province under Grant No 15JK1077, and the Doctorial Scientific Research Starting Fund of Shannxi University of Science and Technology under Grant No BJ12-02.
Laser Spectroscopy and Frequency Combs
International Nuclear Information System (INIS)
Hänsch, Theodor W; Picqué, Nathalie
2013-01-01
The spectrum of a frequency comb, commonly generated by a mode-locked femtosecond laser consists of several hundred thousand precisely evenly spaced spectral lines. Such laser frequency combs have revolutionized the art measuring the frequency of light, and they provide the long-missing clockwork for optical atomic clocks. The invention of the frequency comb technique has been motivated by precision laser spectroscopy of the simple hydrogen atom. The availability of commercial instruments is facilitating the evolution of new applications far beyond the original purpose. Laser combs are becoming powerful instruments for broadband molecular spectroscopy by dramatically improving the resolution and recording speed of Fourier spectrometers and by creating new opportunities for highly multiplexed nonlinear spectroscopy, such as two-photon spectroscopy or coherent Raman spectroscopy. Other emerging applications of frequency combs range from fundamental research in astronomy, chemistry, or attosecond science to telecommunications and satellite navigation
Comb-Resolved Dual-Comb Spectroscopy Stabilized by Free-Running Continuous-Wave Lasers
Kuse, Naoya; Ozawa, Akira; Kobayashi, Yohei
2012-11-01
We demonstrate dual-comb spectroscopy with relatively phase-locked two frequency combs, instead of frequency combs firmly fixed to the absolute frequency references. By stabilizing two beat frequencies between two mode-locked lasers at different wavelengths observed via free-running continuous-wave (CW) lasers, two combs are tightly phase locked to each other. The frequency noise of the CW lasers barely affects the performance of dual-comb spectroscopy because of the extremely fast common-mode noise rejection. Transform-limited comb-resolved dual-comb spectroscopy with a 6 Hz radio frequency linewidth is demonstrated by the use of Yb-fiber oscillators.
Optical phonon modes of wurtzite InP
Gadret, E. G.; de Lima, M. M.; Madureira, J. R.; Chiaramonte, T.; Cotta, M. A.; Iikawa, F.; Cantarero, A.
2013-03-01
Optical vibration modes of InP nanowires in the wurtzite phase were investigated by Raman scattering spectroscopy. The wires were grown along the [0001] axis by the vapor-liquid-solid method. The A1(TO), E2h, and E1(TO) phonon modes of the wurtzite symmetry were identified by using light linearly polarized along different directions in backscattering configuration. Additionally, forbidden longitudinal optical modes have also been observed. Furthermore, by applying an extended 11-parameter rigid-ion model, the complete dispersion relations of InP in the wurtzite phase have been calculated, showing a good agreement with the Raman experimental data.
Dielectric spectroscopy of the SmQ* phase
Perkowski, P.; Bubnov, A.; Piecek, W.; Ogrodnik, K.; Hamplová, V.; Kašpar, M.
2011-11-01
Liquid crystal possessing two biphenyl moieties in the molecular core and lateral chlorine substitution far from the chiral chain has been studied by dielectric spectroscopy. On cooling from the isotropic phase, the material possesses the frustrated smectic Q* (SmQ*) and SmCA* phases. It has been confirmed by dielectric spectroscopy that the SmQ* phase can be related to the SmCA* anti-ferroelectric phase. However, only one relaxation process has been observed in the SmQ* phase, while in the SmCA*, two relaxations are clearly detectable. It seems that the mode found in the SmQ* can be connected with high-frequency anti-phase mode observed in the SmCA* phase. Its relaxation frequency is similar to PH relaxation frequency, but is weaker. The same relaxation has been observed even a few degrees above the SmQ*-Iso phase transition. Another explanation for the mode detected in SmQ* and isotropic phases can be molecular motions around short molecular axis.
Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes
Directory of Open Access Journals (Sweden)
Hugo Lourenço-Martins
2017-12-01
Full Text Available Recently, two reports [Krivanek et al. Nature (London 514, 209 (2014NATUAS0028-083610.1038/nature13870, Lagos et al. Nature (London 543, 529 (2017NATUAS0028-083610.1038/nature21699] have demonstrated the amazing possibility to probe vibrational excitations from nanoparticles with a spatial resolution much smaller than the corresponding free-space phonon wavelength using electron-energy-loss spectroscopy (EELS. While Lagos et al. evidenced a strong spatial and spectral modulation of the EELS signal over a nanoparticle, Krivanek et al. did not. Here, we show that discrepancies among different EELS experiments as well as their relation to optical near- and far-field optical experiments [Dai et al. Science 343, 1125 (2014SCIEAS0036-807510.1126/science.1246833] can be understood by introducing the concept of confined bright and dark surface phonon modes, whose density of states is probed by EELS. Such a concise formalism is the vibrational counterpart of the broadly used formalism for localized surface plasmons [Ouyang and Isaacson Philos. Mag. B 60, 481 (1989PMABDJ1364-281210.1080/13642818908205921, García de Abajo and Aizpurua Phys. Rev. B 56, 15873 (1997PRBMDO0163-182910.1103/PhysRevB.56.15873, García de Abajo and Kociak Phys. Rev. Lett. 100, 106804 (2008PRLTAO0031-900710.1103/PhysRevLett.100.106804, Boudarham and Kociak Phys. Rev. B 85, 245447 (2012PRBMDO1098-012110.1103/PhysRevB.85.245447]; it makes it straightforward to predict or interpret phenomena already known for localized surface plasmons such as environment-related energy shifts or the possibility of 3D mapping of the related surface charge densities [Collins et al. ACS Photonics 2, 1628 (2015APCHD52330-402210.1021/acsphotonics.5b00421].
Picosecond spectroscopy: The first 20 years
International Nuclear Information System (INIS)
Rentzepis, P.M.
1987-01-01
Lasers were at first operating in the pulsed mode. That was the ruby, Cr/sup 3+/, emitting at 694.3 nm with a few kilowatts power, several microseconds time width, and a rather broad non-smooth-spiky-intensity profile. Even with such a primitive laser source, several noteworthy, novel experiments were performed such as two photon processes and second harmonic generation. The advent of Q-switch lasers by means of dyes, Kerr cells and electro-optic crystals introduced the era of high power lasers and laser spectroscopy. The high intensity and rather smooth intensity versus time profile pulses emitted by ruby and Nd/sup 3+//glass lasers provided excellent means for non-linear spectroscopy studies and nanosecond Raman spectroscopy, a field which flourished ten years later. In the mid-sixties, the He/Ne laser was mode locked, and shortly thereafter, the Nd/sup 3+//glass laser was also mode locked and shown to emit picosecond duration pulses. This paper presents what one observes on the screen of an oscilloscope once a laser is set up so as to generate picosecond pulses by use of either a saturable absorbing dye or solid state modulator. What is seen is, of course, a train of pulses. It is characteristic of these pulses that their intensity is extremely high, in the gigawatt region. In this particular case, the band width is approximately twenty to thirty wavenumbers. The method utilized to measure the picosecond pulses, initially, was the two photon method. This paper also gives a more graphic illustration how this technique operates. This same procedure provides an extremely simple technique which the author believes made possible the initial development of the picosecond spectroscopy field
Dual-comb spectroscopy of water vapor with a free-running semiconductor disk laser.
Link, S M; Maas, D J H C; Waldburger, D; Keller, U
2017-06-16
Dual-comb spectroscopy offers the potential for high accuracy combined with fast data acquisition. Applications are often limited, however, by the complexity of optical comb systems. Here we present dual-comb spectroscopy of water vapor using a substantially simplified single-laser system. Very good spectroscopy measurements with fast sampling rates are achieved with a free-running dual-comb mode-locked semiconductor disk laser. The absolute stability of the optical comb modes is characterized both for free-running operation and with simple microwave stabilization. This approach drastically reduces the complexity for dual-comb spectroscopy. Band-gap engineering to tune the center wavelength from the ultraviolet to the mid-infrared could optimize frequency combs for specific gas targets, further enabling dual-comb spectroscopy for a wider range of industrial applications. Copyright © 2017, American Association for the Advancement of Science.
Microresonator soliton dual-comb spectroscopy
Suh, Myoung-Gyun; Yang, Qi-Fan; Yang, Ki Youl; Yi, Xu; Vahala, Kerry J.
2016-11-01
Measurement of optical and vibrational spectra with high resolution provides a way to identify chemical species in cluttered environments and is of general importance in many fields. Dual-comb spectroscopy has emerged as a powerful approach for acquiring nearly instantaneous Raman and optical spectra with unprecedented resolution. Spectra are generated directly in the electrical domain, without the need for bulky mechanical spectrometers. We demonstrate a miniature soliton-based dual-comb system that can potentially transfer the approach to a chip platform. These devices achieve high-coherence pulsed mode locking. They also feature broad, reproducible spectral envelopes, an essential feature for dual-comb spectroscopy. Our work shows the potential for integrated spectroscopy with high signal-to-noise ratios and fast acquisition rates.
Gauge/gravity duality. A road towards reality
International Nuclear Information System (INIS)
Kerner, Patrick
2012-01-01
In this dissertation we use gauge/gravity duality to investigate various phenomena of strongly coupled systems. In particular, we consider applications of the duality to real-world systems such as condensed matter systems and the quark-gluon plasma created by heavy ion collisions at the Relativistic Heavy Ion Collider (RHIC) and the Large Hadron Collider (LHC). Gauge/gravity duality which originates from string theory relates strongly coupled gauge theories to weakly coupled gravity theories. This duality allows for computations of non-perturbative results on the field theory side by perturbative calculations on the gravity side. As we have learned in the recent years, the duality is especially suitable to describe hot and dense plasmas as well as real-time processes related to transport properties or spectral functions. Unfortunately, so far there is no dual gravity description modeling every aspect of a strongly coupled real-world system. However, there are many gravity duals which describe several phenomena. The general idea of this thesis is to study different gravity duals in order to develop a gravity description of hot and dense plasmas. In particular, we focus on physics in thermal equilibrium and close to equilibrium. Motivated by the experimentally observed mesonic resonances in the quark-gluon plasma, we first study quasinormal modes of a gravity dual which contains such resonances. The quasinormal modes on the gravity side are identified with the poles of the Green's function on the field theory side. By studying these quasinormal modes, we observe how quasiparticle resonances develop in a hot and dense plasma. We find interesting trajectories of quasinormal frequencies which may be found experimentally as the temperature and density is varied. In addition, we find an instability in the quasinormal mode spectrum at large chemical potential or magnetic field. At large chemical potential, this instability triggers the condensation of a field which breaks
Gauge/gravity duality. A road towards reality
Energy Technology Data Exchange (ETDEWEB)
Kerner, Patrick
2012-02-23
In this dissertation we use gauge/gravity duality to investigate various phenomena of strongly coupled systems. In particular, we consider applications of the duality to real-world systems such as condensed matter systems and the quark-gluon plasma created by heavy ion collisions at the Relativistic Heavy Ion Collider (RHIC) and the Large Hadron Collider (LHC). Gauge/gravity duality which originates from string theory relates strongly coupled gauge theories to weakly coupled gravity theories. This duality allows for computations of non-perturbative results on the field theory side by perturbative calculations on the gravity side. As we have learned in the recent years, the duality is especially suitable to describe hot and dense plasmas as well as real-time processes related to transport properties or spectral functions. Unfortunately, so far there is no dual gravity description modeling every aspect of a strongly coupled real-world system. However, there are many gravity duals which describe several phenomena. The general idea of this thesis is to study different gravity duals in order to develop a gravity description of hot and dense plasmas. In particular, we focus on physics in thermal equilibrium and close to equilibrium. Motivated by the experimentally observed mesonic resonances in the quark-gluon plasma, we first study quasinormal modes of a gravity dual which contains such resonances. The quasinormal modes on the gravity side are identified with the poles of the Green's function on the field theory side. By studying these quasinormal modes, we observe how quasiparticle resonances develop in a hot and dense plasma. We find interesting trajectories of quasinormal frequencies which may be found experimentally as the temperature and density is varied. In addition, we find an instability in the quasinormal mode spectrum at large chemical potential or magnetic field. At large chemical potential, this instability triggers the condensation of a field which
2014-06-11
Failloux, N., Bonnet, 1., Baron, M. H., & Perrier, E. (2003). Quantitative analysis of vitamin A degradation by raman spectroscopy. Applied Spectroscopy...analysis of the Raman-active modes of the anti-tumor agent 6- mercaptopurine . Journal of Raman Spectroscopy, 32(1), 1-8. doi: Doi 10.1002/1097- 4555
Clemente, Isabel; Aznar, Margarita; Salafranca, Jesús; Nerín, Cristina
2017-02-01
One critical challenge when developing a new antimicrobial packaging material is to demonstrate the mode of action of the antimicrobials incorporated into the packaging. For this task, several analytical techniques as well as microbiology are required. In this work, the antimicrobial properties of benzyl isothiocyanate, allyl isothiocyanate and essential oils of cinnamon and oregano against several moulds and bacteria have been evaluated. Benzyl isothiocyanate showed the highest antimicrobial activity and it was selected for developing the new active packaging material. Scanning electron microscopy and Raman spectroscopy were successfully used to demonstrate the mode of action of benzyl isothiocyanate on Escherichia coli. Bacteria exhibited external modifications such as oval shape and the presence of septum surface, but they did not show any disruption or membrane damage. To provide data on the in vitro action of benzyl isothiocyanate and the presence of inhibition halos, the transfer mechanism to the cells was assessed using solid-phase microextraction-gas chromatography-mass spectrometry. Based on the transfer system, action mechanism and its stronger antimicrobial activity, benzyl isothiocyanate was incorporated to two kinds of antimicrobial labels. The labels were stable and active for 140 days against two mould producers of ochratoxin A; Penicillium verrucosum is more sensitive than Aspergillus ochraceus. Details about the analytical techniques and the results obtained are shown and discussed. Graphical Abstract Antimicrobial evaluation of pure compounds, incorporation in the packaging and study for mode of action on S. coli by Raman, SEM and SPME-GC-MS.
AdS-like spectrum of the asymptotically Goedel space-times
International Nuclear Information System (INIS)
Konoplya, R. A.; Zhidenko, A.
2011-01-01
A black hole immersed in a rotating universe, described by the Gimon-Hashimoto solution, is tested on stability against scalar field perturbations. Unlike the previous studies on perturbations of this solution, which dealt only with the limit of slow universe rotation j, we managed to separate variables in the perturbation equation for the general case of arbitrary rotation. This leads to qualitatively different dynamics of perturbations, because the exact effective potential does not allow for Schwarzschild-like asymptotic of the wave function in the form of purely outgoing waves. The Dirichlet boundary conditions are allowed instead, which result in a totally different spectrum of asymptotically Goedel black holes: the spectrum of quasinormal frequencies is similar to the one of asymptotically anti-de Sitter black holes. At large and intermediate overtones N, the spectrum is equidistant in N. In the limit of small black holes, quasinormal modes (QNMs) approach the normal modes of the empty Goedel space-time. There is no evidence of instability in the found frequencies, which supports the idea that the existence of closed timelike curves (CTCs) and the onset of instability correlate (if at all) not in a straightforward way.
Linear and Nonlinear Molecular Spectroscopy with Laser Frequency Combs
Picque, Nathalie
2013-06-01
The regular pulse train of a mode-locked femtosecond laser can give rise to a comb spectrum of millions of laser modes with a spacing precisely equal to the pulse repetition frequency. Laser frequency combs were conceived a decade ago as tools for the precision spectroscopy of atomic hydrogen. They are now becoming enabling tools for an increasing number of applications, including molecular spectroscopy. Recent experiments of multi-heterodyne frequency comb Fourier transform spectroscopy (also called dual-comb spectroscopy) have demonstrated that the precisely spaced spectral lines of a laser frequency comb can be harnessed for new techniques of linear absorption spectroscopy. The first proof-of-principle experiments have demonstrated a very exciting potential of dual-comb spectroscopy without moving parts for ultra-rapid and ultra-sensitive recording of complex broad spectral bandwidth molecular spectra. Compared to conventional Michelson-based Fourier transform spectroscopy, recording times could be shortened from seconds to microseconds, with intriguing prospects for spectroscopy of short lived transient species. The resolution improves proportionally to the measurement time. Therefore longer recordings allow high resolution spectroscopy of molecules with extreme precision, since the absolute frequency of each laser comb line can be known with the accuracy of an atomic clock. Moreover, since laser frequency combs involve intense ultrashort laser pulses, nonlinear interactions can be harnessed. Broad spectral bandwidth ultra-rapid nonlinear molecular spectroscopy and imaging with two laser frequency combs is demonstrated with coherent Raman effects and two-photon excitation. Real-time multiplex accessing of hyperspectral images may dramatically expand the range of applications of nonlinear microscopy. B. Bernhardt et al., Nature Photonics 4, 55-57 (2010); A. Schliesser et al. Nature Photonics 6, 440-449 (2012); T. Ideguchi et al. arXiv:1201.4177 (2012) T
Vogt, Dominik Walter; Leonhardt, Rainer
2017-11-01
We report on Fano resonances in a high-quality (Q) whispering-gallery mode (WGM) spherical resonator coupled to a multi-mode waveguide in the terahertz (THz) frequency range. The asymmetric line shape and phase of the Fano resonances detected with coherent continuous-wave (CW) THz spectroscopy measurements are in excellent agreement with the analytical model. A very high Q factor of 1600, and a finesse of 22 at critical coupling is observed around 0.35 THz. To the best of our knowledge this is the highest Q factor ever reported for a THz WGM resonator.
International Nuclear Information System (INIS)
Yau, Waifan.
1988-04-01
Substitutional carbon on an arsenic lattice site is the shallowest and one of the most dominant acceptors in semi-insulating Liquid Encapsulated Czochralski (LEC) GaAs. However, the role of this acceptor in determining the well known ''W'' shape spatial variation of neutral EL2 concentration along the diameter of a LEC wafer is not known. In this thesis, we attempt to clarify the issue of the carbon acceptor's effect on this ''W'' shaped variation by measuring spatial profiles of this acceptor along the radius of three different as-grown LEC GaAs wafers. With localized vibrational mode absorption spectroscopy, we find that the profile of the carbon acceptor is relatively constant along the radius of each wafer. Average values of concentration are 8 x 10E15 cm -3 , 1.1 x 10E15 cm -3 , and 2.2 x 10E15 cm -3 , respectively. In addition, these carbon acceptor LVM measurements indicate that a residual donor with concentration comparable to carbon exists in these wafers and it is a good candidate for the observed neutral EL2 concentration variation. 22 refs., 39 figs
The digital holographic interferometry in resonant acoustic spectroscopy
International Nuclear Information System (INIS)
GAPONOV, V.E.; AZAMATOV, Z.T.; REDKORECHEV, V.I.; ISAEV, A.M.
2014-01-01
The opportunities of application of digital holographic interferometry method for studies of shapes of resonant modes in resonant acoustic spectroscopy are shown. The results of experimental measurements and analytical calculations are submitted. (authors)
Crystal structure, thermal behaviour, vibrational spectroscopy and ...
Indian Academy of Sciences (India)
2018-05-23
May 23, 2018 ... modes corresponding to the kröhnkite is identified by the IR and Raman spectroscopies in the frequency ranges ..... The two weak bands near 1227 and 1202 cm ... ciated with the hydroxyl groups are taken into consideration.
Analytic family of post-merger template waveforms
Del Pozzo, Walter; Nagar, Alessandro
2017-06-01
Building on the analytical description of the post-merger (ringdown) waveform of coalescing, nonprecessing, spinning binary black holes introduced by Damour and Nagar [Phys. Rev. D 90, 024054 (2014), 10.1103/PhysRevD.90.024054], we propose an analytic, closed form, time-domain, representation of the ℓ=m =2 gravitational radiation mode emitted after merger. This expression is given as a function of the component masses and dimensionless spins (m1 ,2,χ1 ,2) of the two inspiraling objects, as well as of the mass MBH and (complex) frequency σ1 of the fundamental quasinormal mode of the remnant black hole. Our proposed template is obtained by fitting the post-merger waveform part of several publicly available numerical relativity simulations from the Simulating eXtreme Spacetimes (SXS) catalog and then suitably interpolating over (symmetric) mass ratio and spins. We show that this analytic expression accurately reproduces (˜0.01 rad ) the phasing of the post-merger data of other data sets not used in its construction. This is notably the case of the spin-aligned run SXS:BBH:0305, whose intrinsic parameters are consistent with the 90% credible intervals reported in the parameter-estimation followup of GW150914 by B.P. Abbott et al. [Phys. Rev. Lett. 116, 241102 (2016), 10.1103/PhysRevLett.116.241102]. Using SXS waveforms as "experimental" data, we further show that our template could be used on the actual GW150914 data to perform a new measure of the complex frequency of the fundamental quasinormal mode so as to exploit the complete (high signal-to-noise-ratio) post-merger waveform. We assess the usefulness of our proposed template by analyzing, in a realistic setting, SXS full inspiral-merger-ringdown waveforms and constructing posterior probability distribution functions for the central frequency damping time of the first overtone of the fundamental quasinormal mode as well as for the physical parameters of the systems. We also briefly explore the possibility
Spatially resolved quantum plasmon modes in metallic nano-films from first-principles
DEFF Research Database (Denmark)
Andersen, Kirsten; Jacobsen, Karsten W.; Thygesen, Kristian S.
2012-01-01
Electron energy loss spectroscopy (EELS) can be used to probe plasmon excitations in nanostructured materials with atomic-scale spatial resolution. For structures smaller than a few nanometers, quantum effects are expected to be important, limiting the validity of widely used semiclassical response...... as (conventional) surface modes, subsurface modes, and a discrete set of bulk modes resembling standing waves across the film. We find clear effects of both quantum confinement and nonlocal response. The quantum plasmon modes provide an intuitive picture of collective excitations of confined electron systems...
Directory of Open Access Journals (Sweden)
Diethelm Johannsmann
2016-12-01
Full Text Available Colloidal spheres attached to a quartz crystal microbalance (QCM produce the so-called “coupled resonances”. They are resonators of their own, characterized by a particle resonance frequency, a resonance bandwidth, and a modal mass. When the frequency of the main resonator comes close to the frequency of the coupled resonance, the bandwidth goes through a maximum. A coupled resonance can be viewed as an absorption line in acoustic shear-wave spectroscopy. The known concepts from spectroscopy apply. This includes the mode assignment problem, selection rules, and the oscillator strength. In this work, the mode assignment problem was addressed with Finite Element calculations. These reveal that a rigid sphere in contact with a QCM displays two modes of vibration, termed “slipping” and “rocking”. In the slipping mode, the sphere rotates about its center; it exerts a tangential force onto the resonator surface at the point of contact. In the rocking mode, the sphere rotates about the point of contact; it exerts a torque onto the substrate. In liquids, both axes of rotation are slightly displaced from their ideal positions. Characteristic for spectroscopy, the two modes do not couple to the mechanical excitation equally well. The degree of coupling is quantified by an oscillator strength. Because the rocking mode mostly exerts a torque (rather than a tangential force, its coupling to the resonator's tangential motion is weak; the oscillator strength consequently is small. Recent experiments on surface-adsorbed colloidal spheres can be explained by the mode of vibration being of the rocking type. Keywords: Quartz crystal microbalance, Coupled resonance, Biocolloids, Adsorption
Limiter H-mode experiments on TFTR
Energy Technology Data Exchange (ETDEWEB)
Bush, C [Oak Ridge National Lab., TN (USA); Bretz, N L; Fredrickson, E D; McGuire, K M; Nazikian, R; Park, H K; Schivell, J; Taylor, G; Bitter, B; Budny, R; Cohen, S A; Kilpatrick, S J; LeBlanc, B; Manos, D M; Meade, D; Paul, S F; Scott, S D; Stratton, B C; Synakowski, E J; Towner, H H; Weiland, R M; Arunasalam, V; Bateman, G; Bell, M G; Bell, R; Boivin, R; Cavallo, A; Cheng, C Z; Chu, T K; Cowl,
1990-12-15
Limiter H-modes with centrally peaked density profiles have been obtained in TFTR using a highly conditioned graphite limiter. The transition to these centrally peaked H-modes takes place from the supershot to the H-mode rather than the usual L- to H-mode transition observed on other tokamaks. Bi-directional beam heating is required to induce the transition. Density peaking factors, n{sub e}(0)/{l angle}n{sub e}{r angle}, >2.3 are obtained and at the same time the H-mode characteristics are similar to those of limiter H-modes on other tokamaks and the global confinement, {tau}{sub E}, can be >2.5 times L-mode scaling. The TRANSP analysis shows that transport in these H-modes is similar to that of supershots within the inner 60 cm of the plasma, but the stored electron energy (calculated using measured values of T{sub e} and n{sub e}) is higher for the H-mode at the plasma edge. Microwave scattering near the edge shows broad spectra at k = 5.5 cm{sup {minus}1} which begin at the drop in D{sub {alpha}} radiation and are strongly shifted in the electron diamagnetic drift direction. At the same time beam emission spectroscopy shows a coherent mode near the boundary with m = 15--20 at 20--30 kHz which is propagating in the ion direction. During an ELM event these apparent rotations cease and Mirnov fluctuations in the 50--500 kHz increase in intensity.
Auger electron spectroscopy study on interaction between aluminum thin layers and uranium substrate
International Nuclear Information System (INIS)
Zhou Wei; Liu Kezhao; Yang Jiangrong; Xiao Hong; Jiang Chunli; Lu Lei
2005-01-01
Aluminum thin layers on uranium were prepared by sputter deposition at room temperature in ultra high vacuum analysis chamber. Interaction between U and Al, and growth mode were investigated by Auger electron spectroscopy (AES) and electron energy loss spectroscopy (EELS). It is shown that Al thin film growth follows the volmer-weber (VW) mode. At room temperature, Al and U interact with each other, resulting in interdiffusion action and formation of U-Al alloys at U/Al interface. Annealing promotes interaction and interdiffusion between U and Al, and UAl x maybe formed at interface. (authors)
Adaptive real-time dual-comb spectroscopy
Ideguchi, Takuro; Poisson, Antonin; Guelachvili, Guy; Picqué, Nathalie; Hänsch, Theodor W.
2014-01-01
The spectrum of a laser frequency comb consists of several hundred thousand equally spaced lines over a broad spectral bandwidth. Such frequency combs have revolutionized optical frequency metrology and they now hold much promise for significant advances in a growing number of applications including molecular spectroscopy. Despite an intriguing potential for the measurement of molecular spectra spanning tens of nanometres within tens of microseconds at Doppler-limited resolution, the development of dual-comb spectroscopy is hindered by the demanding stability requirements of the laser combs. Here we overcome this difficulty and experimentally demonstrate a concept of real-time dual-comb spectroscopy, which compensates for laser instabilities by electronic signal processing. It only uses free-running mode-locked lasers without any phase-lock electronics. We record spectra spanning the full bandwidth of near-infrared fibre lasers with Doppler-limited line profiles highly suitable for measurements of concentrations or line intensities. Our new technique of adaptive dual-comb spectroscopy offers a powerful transdisciplinary instrument for analytical sciences. PMID:24572636
Adaptive real-time dual-comb spectroscopy
Ideguchi, Takuro; Poisson, Antonin; Guelachvili, Guy; Picqué, Nathalie; Hänsch, Theodor W.
2014-02-01
The spectrum of a laser frequency comb consists of several hundred thousand equally spaced lines over a broad spectral bandwidth. Such frequency combs have revolutionized optical frequency metrology and they now hold much promise for significant advances in a growing number of applications including molecular spectroscopy. Despite an intriguing potential for the measurement of molecular spectra spanning tens of nanometres within tens of microseconds at Doppler-limited resolution, the development of dual-comb spectroscopy is hindered by the demanding stability requirements of the laser combs. Here we overcome this difficulty and experimentally demonstrate a concept of real-time dual-comb spectroscopy, which compensates for laser instabilities by electronic signal processing. It only uses free-running mode-locked lasers without any phase-lock electronics. We record spectra spanning the full bandwidth of near-infrared fibre lasers with Doppler-limited line profiles highly suitable for measurements of concentrations or line intensities. Our new technique of adaptive dual-comb spectroscopy offers a powerful transdisciplinary instrument for analytical sciences.
Directory of Open Access Journals (Sweden)
Květoslava Šustová
2006-01-01
Full Text Available Our work deals with a possibility of determination of basic composition (dry matter, fat, protein, casein, lactose and urea nitrogen of ewe’s milk and colostrum by FT NIR spectroscopy. Samples of milk were warmed to 40 °C, agitated, cooled to 20 °C, transferred into Petri dishes and analysed by reference methods and by FT NIR in reflectance mode. The measured area was spaced by a metallic mirror. Statistically significant differences between the reference values and the calculated values of NIR were not found (p=0.05. Results of calibration for ewe’s milk determined the highest correlation coefficients: dry matter 0.983, fat 0.989, true protein 0.997, casein 0.977, lactose 0.980 and urea nitrogen 0.973. The study showed that NIRS method, when samples of milk are measured on Petri dishes, is a useful technique for the prediction of dry matter, fat, protein and casein in ewe’s milk.
Loop quantum gravity and black hole entropy quantization
Institute of Scientific and Technical Information of China (English)
无
2009-01-01
Using the spin networks and the asymptotic quasinormal mode frequencies of black holes given by loop quantum gravity,the minimum horizon area gap is obtained.Then the quantum area spectrum of black holes is derived and the black hole entropy is a realized quantization.The results show that the black hole entropy given by loop quantum gravity is in full accord with the Bekenstein-Hawking entropy with a suitable Immirzi.
Vibrational spectroscopy of the borate mineral kotoite Mg₃(BO₃)₂.
Frost, Ray L; Xi, Yunfei
2013-02-15
Vibrational spectroscopy has been used to assess the structure of kotoite a borate mineral of magnesium which is isostructural with jimboite. The mineral is orthorhombic with point group: 2/m 2/m 2/m. The mineral has the potential as a new memory insulator material. The mineral has been characterised by a combination of Raman and infrared spectroscopy. The Raman spectrum is dominated by a very intense band at 835 cm(-1), assigned to the symmetric stretching mode of tetrahedral boron. Raman bands at 919, 985 and 1015 cm(-1) are attributed to the antisymmetric stretching modes of tetrahedral boron. Kotoite is strictly an hydrous borate mineral. An intense Raman band observed at 3559 cm(-1) is attributed to the stretching vibration of hydroxyl units, more likely to be associated with the borate mineral hydroxyborate. The lack of observation of water bending modes proves the absence of water in the kotoite structure. Copyright © 2012 Elsevier B.V. All rights reserved.
SELF-TRAPPING OF DISKOSEISMIC CORRUGATION MODES IN NEUTRON STAR SPACETIMES
Energy Technology Data Exchange (ETDEWEB)
Tsang, David [Center for Theory and Computation, Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Pappas, George [Department of Physics and Astronomy, The University of Mississippi, University, MS 38677 (United States)
2016-02-10
We examine the effects of higher-order multipole contributions of rotating neutron star (NS) spacetimes on the propagation of corrugation (c-)modes within a thin accretion disk. We find that the Lense–Thirring precession frequency, which determines the propagation region of the low-frequency fundamental corrugation modes, can experience a turnover allowing for c-modes to become self-trapped for sufficiently high dimensionless spin j and quadrupole rotational deformability α. If such self-trapping c-modes can be detected, e.g., through phase-resolved spectroscopy of the iron line for a high-spin low-mass accreting neutron star, this could potentially constrain the spin-induced NS quadrupole and the NS equation of state.
Self-Trapping of Diskoseismic Corrugation Modes in Neutron Star Spacetimes
Tsang, David; Pappas, George
2016-02-01
We examine the effects of higher-order multipole contributions of rotating neutron star (NS) spacetimes on the propagation of corrugation (c-)modes within a thin accretion disk. We find that the Lense-Thirring precession frequency, which determines the propagation region of the low-frequency fundamental corrugation modes, can experience a turnover allowing for c-modes to become self-trapped for sufficiently high dimensionless spin j and quadrupole rotational deformability α. If such self-trapping c-modes can be detected, e.g., through phase-resolved spectroscopy of the iron line for a high-spin low-mass accreting neutron star, this could potentially constrain the spin-induced NS quadrupole and the NS equation of state.
Tunneling spectroscopy in NbN based Josephson junctions
International Nuclear Information System (INIS)
Chicault, R.; Villegier, J.C.
1984-08-01
Tunneling spectroscopy in high quality NbN-oxide-Pb(In) diodes offers a direct observation of various NbN and Pb phonon frequences as other vibrating modes existing near the tunnel barrier. The large number of peaks attribuated to dips in the transverses and longitudinal acoustic branches of NbN dispersion curves are found to confirm the previous theory developing the contribution of these modes to the strong coupling and high Tc behavior of NbN
Energy Technology Data Exchange (ETDEWEB)
Chang, Chih-Hsuan; Nesbitt, David J. [JILA, National Institute of Standards and Technology, University of Colorado, Boulder, Colorado 80309, USA and Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309 (United States)
2016-07-28
A series of CH stretch modes in phenyl radical (C{sub 6}H{sub 5}) has been investigated via high resolution infrared spectroscopy at sub-Doppler resolution (∼60 MHz) in a supersonic discharge slit jet expansion. Two fundamental vibrations of a{sub 1} symmetry, ν{sub 1} and ν{sub 2}, are observed and rotationally analyzed for the first time, corresponding to in-phase and out-of-phase symmetric CH stretch excitation at the ortho/meta/para and ortho/para C atoms with respect to the radical center. The ν{sub 1} and ν{sub 2} band origins are determined to be 3073.968 50(8) cm{sup −1} and 3062.264 80(7) cm{sup −1}, respectively, which both agree within 5 cm{sup −1} with theoretical anharmonic scaling predictions based on density functional B3LYP/6-311g++(3df,3dp) calculations. Integrated band strengths for each of the CH stretch bands are analyzed, with the relative intensities agreeing remarkably well with theoretical predictions. Frequency comparison with previous low resolution Ar-matrix spectroscopy [A. V. Friderichsen et al., J. Am. Chem. Soc. 123, 1977 (2001)] reveals a nearly uniform Δν ≈ + 10-12 cm{sup −1} blue shift between gas phase and Ar matrix values for ν{sub 1} and ν{sub 2}. This differs substantially from the much smaller red shift (Δν ≈ − 1 cm{sup −1}) reported for the ν{sub 19} mode, and suggests a simple physical model in terms of vibrational mode symmetry and crowding due to the matrix environment. Finally, the infrared phenyl spectra are well described by a simple asymmetric rigid rotor Hamiltonian and show no evidence for spectral congestion due to intramolecular vibrational coupling, which bodes well for high resolution studies of other ring radicals and polycyclic aromatic hydrocarbons. In summary, the combination of slit jet discharge methods with high resolution infrared lasers enables spectroscopic investigation of even highly reactive combustion and interstellar radical intermediates under gas phase, jet
International Nuclear Information System (INIS)
Rebreyend, D.; Pignol, G.; Baeßler, S.; Nesvizhevsky, V. V.; Protasov, K.; Voronin, A.
2014-01-01
Gravitational resonance spectroscopy consists in measuring the energy spectrum of bouncing ultracold neutrons above a mirror by inducing resonant transitions between different discrete quantum levels. We discuss how to induce the resonances with a flow through arrangement in the GRANIT spectrometer, excited by an oscillating magnetic field gradient. The spectroscopy could be realized in two distinct modes (so called DC and AC) using the same device to produce the magnetic excitation. We present calculations demonstrating the feasibility of the newly proposed AC mode
Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus.
Ling, Xi; Liang, Liangbo; Huang, Shengxi; Puretzky, Alexander A; Geohegan, David B; Sumpter, Bobby G; Kong, Jing; Meunier, Vincent; Dresselhaus, Mildred S
2015-06-10
As a new two-dimensional layered material, black phosphorus (BP) is a very promising material for nanoelectronics and optoelectronics. We use Raman spectroscopy and first-principles theory to characterize and understand the low-frequency (LF) interlayer breathing modes (<100 cm(-1)) in few-layer BP for the first time. Using a laser polarization dependence study and group theory analysis, the breathing modes are assigned to Ag symmetry. Compared to the high-frequency (HF) Raman modes, the LF breathing modes are considerably more sensitive to interlayer coupling and, thus, their frequencies show a stronger dependence on the number of layers. Hence, they constitute an effective means to probe both the crystalline orientation and thickness of few-layer BP. Furthermore, the temperature dependence shows that in the temperature range -150 to 30 °C, the breathing modes have a weak anharmonic behavior, in contrast to the HF Raman modes that exhibit strong anharmonicity.
Raman Spectroscopy for Homeland Security Applications
Directory of Open Access Journals (Sweden)
Gregory Mogilevsky
2012-01-01
Full Text Available Raman spectroscopy is an analytical technique with vast applications in the homeland security and defense arenas. The Raman effect is defined by the inelastic interaction of the incident laser with the analyte molecule’s vibrational modes, which can be exploited to detect and identify chemicals in various environments and for the detection of hazards in the field, at checkpoints, or in a forensic laboratory with no contact with the substance. A major source of error that overwhelms the Raman signal is fluorescence caused by the background and the sample matrix. Novel methods are being developed to enhance the Raman signal’s sensitivity and to reduce the effects of fluorescence by altering how the hazard material interacts with its environment and the incident laser. Basic Raman techniques applicable to homeland security applications include conventional (off-resonance Raman spectroscopy, surface-enhanced Raman spectroscopy (SERS, resonance Raman spectroscopy, and spatially or temporally offset Raman spectroscopy (SORS and TORS. Additional emerging Raman techniques, including remote Raman detection, Raman imaging, and Heterodyne imaging, are being developed to further enhance the Raman signal, mitigate fluorescence effects, and monitor hazards at a distance for use in homeland security and defense applications.
International Nuclear Information System (INIS)
Feit, Z.; Kostyk, D.; Woods, R.J.; Mak, P.
1991-01-01
Buried-heterostructure tunable PbEuSeTe/PbTe lasers were fabricated using a two-stage molecular beam epitaxy growth procedure. Improvements in the processing technique yielded lasers that show performance characteristics significantly better than those reported previously. A continuous wave (cw) operating temperature of 203 K was realized, which is the highest cw operating temperature ever reported for lead-chalcogenides diode lasers. This laser exhibited exceptionally low-threshold currents of 1.4 mA at 90 K and 43 mA at 160 K with single-mode operation for injection currents up to 30I th and 0.18 mW power at 100 K. The usefulness of the laser, when operating cw at 200 K, was demonstrated by the ability to perform high-resolution spectroscopy of a low-pressure CO 2 gas sample
Extremely confined gap surface-plasmon modes excited by electrons
DEFF Research Database (Denmark)
Raza, Søren; Stenger, Nicolas; Pors, Anders Lambertus
2014-01-01
High-spatial and energy resolution electron energy-loss spectroscopy (EELS) can be used for detailed characterization of localized and propagating surface-plasmon excitations in metal nanostructures, giving insight into fundamental physical phenomena and various plasmonic effects. Here, applying...... EELS to ultra-sharp convex grooves in gold, we directly probe extremely confined gap surface-plasmon (GSP) modes excited by swift electrons in nanometre-wide gaps. We reveal the resonance behaviour associated with the excitation of the antisymmetric GSP mode for extremely small gap widths, down to ~5...... mode exploited in plasmonic waveguides with extreme light confinement is a very important factor that should be taken into account in the design of nanoplasmonic circuits and devices....
Electrochemical surface plasmon spectroscopy-Recent developments and applications
International Nuclear Information System (INIS)
Zhang, Nan; Schweiss, Ruediger; Zong, Yun; Knoll, Wolfgang
2007-01-01
A survey is given on recent developments and applications of electrochemical techniques combined with surface plasmon resonance (SPR) spectroscopy. Surface plasmon spectroscopy (SPS) and optical waveguide mode spectroscopy make use of evanescent waves on metal-dielectric interfaces and can be conveniently combined with electrochemical methods. Selected examples of applications of high-pressure surface electrochemical plasmon resonance spectroscopy to study supramolecular architectures such as layer-by-layer films of conducting polymers or thin composite films will be presented. Then a combination of SPS with the electrochemical quartz crystal microbalance (EQCM) will be introduced and illustrated with a study on doping/de-doping process of a conducting polymer. This combination allows for simultaneous electrochemical, optical and microgravimetric characterization of interfaces. Finally, new technical developments including integration of SPS into microfluidic devices using a grating coupler and surface plasmon enhanced diffraction will be discussed
Ringing in de Sitter spacetime
Directory of Open Access Journals (Sweden)
Alex Buchel
2018-03-01
Full Text Available Hydrodynamics is a universal effective theory describing relaxation of quantum field theories towards equilibrium. Massive QFTs in de Sitter spacetime are never at equilibrium. We use holographic gauge theory/gravity correspondence to describe relaxation of a QFT to its Bunch–Davies vacuum — an attractor of its late-time dynamics. Specifically, we compute the analogue of the quasinormal modes describing the relaxation of a holographic toy model QFT in de Sitter.
Self-Similar Nanocavity Design with Ultrasmall Mode Volume for Single-Photon Nonlinearities
DEFF Research Database (Denmark)
Choi, Hyeongrak; Heuck, Mikkel; Englund, Dirk R.
2017-01-01
We propose a photonic crystal nanocavity design with self-similar electromagnetic boundary conditions, achieving ultrasmall mode volume (V-eff). The electric energy density of a cavity mode can be maximized in the air or dielectric region, depending on the choice of boundary conditions. We illust...... at the single-photon level. These features open new directions in cavity quantum electrodynamics, spectroscopy, and quantum nonlinear optics....
Remote Spectroscopy in the Visible Using Fibers on the Optical Internet Network
Ribeiro, Rafael A. S.; de Oliveira, Anderson R.; Zilio, Sergio C.
2010-01-01
The work presented here demonstrates the feasibility of using the single-mode fibers of an optical Internet network to deliver visible light between separate laboratories as a way to perform remote spectroscopy in the visible for teaching purposes. The coupling of a broadband light source into the single-mode fiber (SMF) and the characterization…
CO{sub 2} INFRARED PHONON MODES IN INTERSTELLAR ICE MIXTURES
Energy Technology Data Exchange (ETDEWEB)
Cooke, Ilsa R. [Department of Chemistry, University of Virginia, McCormick Road, Charlottesville, VA 22904 (United States); Fayolle, Edith C.; Öberg, Karin I., E-mail: irc5zb@virginia.edu [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)
2016-11-20
CO{sub 2} ice is an important reservoir of carbon and oxygen in star- and planet-forming regions. Together with water and CO, CO{sub 2} sets the physical and chemical characteristics of interstellar icy grain mantles, including desorption and diffusion energies for other ice constituents. A detailed understanding of CO{sub 2} ice spectroscopy is a prerequisite to characterize CO{sub 2} interactions with other volatiles both in interstellar ices and in laboratory experiments of interstellar ice analogs. We report laboratory spectra of the CO{sub 2} longitudinal optical (LO) phonon mode in pure CO{sub 2} ice and in CO{sub 2} ice mixtures with H{sub 2}O, CO, and O{sub 2} components. We show that the LO phonon mode position is sensitive to the mixing ratio of various ice components of astronomical interest. In the era of the James Webb Space Telescope , this characteristic could be used to constrain interstellar ice compositions and morphologies. More immediately, LO phonon mode spectroscopy provides a sensitive probe of ice mixing in the laboratory and should thus enable diffusion measurements with higher precision than has been previously possible.
I20; the Versatile X-ray Absorption spectroscopy beamline at Diamond Light Source
International Nuclear Information System (INIS)
Diaz-Moreno, S; Hayama, S; Amboage, M; Freeman, A; Sutter, J; Duller, G
2009-01-01
The Versatile Spectroscopy beamline at Diamond Light Source, I20, is currently under construction and aims to begin operation in late 2009 and early 2010. The beamline aims to cover applications from physics, chemistry and biology through materials, environmental and geological science. Three very distinctive modes of operation will be offered at the beamline: scanning X-ray Absorption spectroscopy (XAS), XAS in dispersive mode, and X-ray emission spectroscopy (XES). To achieve this, the beamline has been designed around two independent experimental end-stations operating from a pair of canted wigglers located in a 5m diamond straight section. One branch of the beamline will deliver monochromatic x-ray radiation of high spectral purity to one of the experimental hutches, whilst the other branch will constitute an energy dispersive spectrometer. The novel design of the beamline allows both branches to operate simultaneously.
Frequency-agile dual-comb spectroscopy
Millot, Guy; Pitois, Stéphane; Yan, Ming; Hovannysyan, Tatevik; Bendahmane, Abdelkrim; Hänsch, Theodor W.; Picqué, Nathalie
2015-01-01
We propose a new approach to near-infrared molecular spectroscopy, harnessing advanced concepts of optical telecommunications and supercontinuum photonics. We generate, without mode-locked lasers, two frequency combs of slightly different repetition frequencies and moderate, but rapidly tunable, spectral span. The output of a frequency-agile continuous wave laser is split and sent into two electro-optic intensity modulators. Flat-top low-noise frequency combs are produced by wave-breaking in ...
Broadband high-resolution two-photon spectroscopy with laser frequency combs
Hipke, Arthur; Meek, Samuel A.; Ideguchi, Takuro; Hänsch, Theodor W.; Picqué, Nathalie
2013-01-01
Two-photon excitation spectroscopy with broad spectral span is demonstrated at Doppler-limited resolution. We describe first Fourier transform two-photon spectroscopy of an atomic sample with two mode-locked laser oscillators in a dual-comb technique. Each transition is uniquely identified by the modulation imparted by the interfering comb excitations. The temporal modulation of the spontaneous two-photon fluorescence is monitored with a single photodetector, and the spectrum is revealed by a...
Dual comb generation from a mode-locked fiber laser with orthogonally polarized interlaced pulses.
Akosman, Ahmet E; Sander, Michelle Y
2017-08-07
Ultra-high precision dual-comb spectroscopy traditionally requires two mode-locked, fully stabilized lasers with complex feedback electronics. We present a novel mode-locked operation regime in a thulium-holmium co-doped fiber laser, a frequency-halved state with orthogonally polarized interlaced pulses, for dual comb generation from a single source. In a linear fiber laser cavity, an ultrafast pulse train composed of co-generated, equal intensity and orthogonally polarized consecutive pulses at half of the fundamental repetition rate is demonstrated based on vector solitons. Upon optical interference of the orthogonally polarized pulse trains, two stable microwave RF beat combs are formed, effectively down-converting the optical properties into the microwave regime. These co-generated, dual polarization interlaced pulse trains, from one all-fiber laser configuration with common mode suppression, thus provide an attractive compact source for dual-comb spectroscopy, optical metrology and polarization entanglement measurements.
Calculation, normalization and perturbation of quasinormal modes in coupled cavity-waveguide systems
DEFF Research Database (Denmark)
Kristensen, Philip Trøst; de Lasson, Jakob Rosenkrantz; Gregersen, Niels
2014-01-01
of divergent series to provide a framework for modeling of optical phenomena in such coupled cavity-waveguide systems. As an example, we apply the framework to study perturbative changes in the resonance frequency and Q value of a photonic crystal cavity coupled to a defect waveguide....
Characterization of Crystal Chirality in Amino Acids Using Low-Frequency Raman Spectroscopy.
Aviv, Hagit; Nemtsov, Irena; Mastai, Yitzhak; Tischler, Yaakov R
2017-10-19
We present a new method for differentiating racemic crystals from enantiopure crystals. Recently, developments in optical filters have enabled the facile use of Raman spectroscopy to detect low-frequency vibrational (LFV) modes. Here, for the first time, we use Raman spectroscopy to characterize the LFV modes for crystalline organic materials composed of chiral molecules. The LF-Raman spectra of racemic and enantiopure crystals exhibit a significant variation, which we attribute to different hydrogen-bond networks in the chiral crystal structures. Across a representative set of amino acids, we observed that when comparing racemic versus enantiopure crystals, the available LFV modes and their relative scattering intensity are strong functions of side chain polarity. Thus, LF-Raman can be used as a method that is complementary to the currently used methods for characterizing crystal chirality due to simpler, faster, and more sensitive measurements, along with the small sample size required, which is limited by the laser-beam diameter in the focus.
Hadron spectroscopy with COMPASS - First results
Nerling, Frank
2010-01-01
The COMPASS experiment at CERN is dedicated to light hadron spectroscopy with emphasis on the detection of new states, in particular the search for spin exotic states and glueballs. After a short pilot run in 2004 (190 GeV/c $\\pi^{-}$ beam, Pb target) showing significant production strength of an exotic $J^{PC}=1^{-+}$ state at 1.66\\,GeV/${\\rm c^2}$, we have collected data with 190 GeV/c hadron beams on a liquid hydrogen target in 2008/09. The spectrometer features good coverage by calorimetry and our data provide excellent opportunity for simultaneous observation of new states in different decay modes. The diffractively produced $(3\\pi)^{-}$ system for example can be studied in both modes $\\pi^{-}p \\rightarrow \\pi^{-}\\pi^{+}\\pi^{-}p$ and $\\pi^{-}~p \\rightarrow \\pi^{-}\\pi^{0}\\pi^{0}~p$. Reconstruction of charged and neutral mode rely on completely different parts of the apparatus. Observation of new st ates in both modes provides important checks. The results on diffractive dissociation into 3$\\pi$ final stat...
Visualization of multipolar longitudinal and transversal surface plasmon modes in nanowire dimers.
Alber, Ina; Sigle, Wilfried; Müller, Sven; Neumann, Reinhard; Picht, Oliver; Rauber, Markus; van Aken, Peter A; Toimil-Molares, Maria Eugenia
2011-12-27
We study the transversal and longitudinal localized surface plasmon resonances in single nanowires and nanowire dimers excited by the fast traveling electron beam in a transmission electron microscope equipped with high-resolution electron energy-loss spectroscopy. Bright and dark longitudinal modes up to the fifth order are resolved on individual metallic nanowires. On nanowire dimers, mode splitting into bonding and antibonding is measured up to the third order for several dimers with various aspect ratio and controlled gap size. We observe that the electric field maxima of the bonding modes are shifted toward the gap, while the electric field maxima of the antibonding modes are shifted toward the dimer ends. Finally, we observe that the transversal mode is not detected in the region of the dimer gap and decays away from the rod more rapidly than the longitudinal modes.
Gaynor, James D.; Wetterer, Anna M.; Cochran, Rea M.; Valente, Edward J.; Mayer, Steven G.
2015-01-01
Raman spectroscopy is a powerful experimental technique, yet it is often missing from the undergraduate physical chemistry laboratory curriculum. Tetrachloromethane (CCl[subscript 4]) is the ideal molecule for an introductory vibrational spectroscopy experiment and the symmetric stretch vibration contains fine structure due to isotopic variations…
Spectroscopy of fractional Josephson vortex molecules
Energy Technology Data Exchange (ETDEWEB)
Goldobin, Edward; Gaber, Tobias; Buckenmaier, Kai; Kienzle, Uta; Sickinger, Hanna; Koelle, Dieter; Kleiner, Reinhold [Physikalisches Institut - Experimentalphysik II, Center for Collective Quantum Phenomena, Universitaet Tuebingen, Auf der Morgenstelle 14, D-72076 Tuebingen (Germany)
2010-07-01
Using tiny current injectors we create {kappa} discontinuities of the Josephson phase in a long Josephson junction. The junction reacts at the discontinuities by creating fractional Josephson vortices of size {lambda}{sub J} pinned at them. Such vortices carry the flux {phi}, which is a fraction of the magnetic flux quantum {phi}{sub 0}{approx}2.07 x 10{sup -15} Wb. Being pinned, a fractional vortex has an eigenfrequency (localized mode), which depends on {kappa} and applied bias current, and which lays within the plasma gap. If one considers a molecule consisting of several coupled fractional vortices, the eigenfrequency will split into several modes. We report on spectroscopy of a fractional vortex molecule performed in the thermal regime.
Infrared Spectroscopy of Noh Suspended in Solid Parahydrogen: Part Two
Balabanoff, Morgan E.; Mutunga, Fredrick M.; Anderson, David T.
2015-06-01
The only report in the literature on the infrared spectroscopy of the parent oxynitrene NOH was performed using Ar matrix isolation spectroscopy at 10 K. In this previous study, they performed detailed isotopic studies to make definitive vibrational assignments. NOH is predicted by high-level calculations to be in a triplet ground electronic state, but the Ar matrix isolation spectra cannot be used to verify this triplet assignment. In our 2013 preliminary report, we showed that 193 nm in situ photolysis of NO trapped in solid parahydrogen can also be used to prepare the NOH molecule. Over the ensuing two years we have been studying the infrared spectroscopy of this species in more detail. The spectra reveal that NOH can undergo hindered rotation in solid parahydrogen such that we can observe both a-type and b-type rovibrational transitions for the O-H stretch vibrational mode, but only a-type for the mode assigned to the bend. In addition, both observed a-type infrared absorption features (bend and OH stretch) display fine structure; an intense central peak with weaker peaks spaced symmetrically to both lower and higher wavenumbers. The spacing between the peaks is nearly identical for both vibrational modes. We now believe this fine structure is due to spin-rotation interactions and we will present a detailed analysis of this fine structure. Currently, we are performing additional experiments aimed at making 15NOH to test these preliminary assignments. The most recent data and up-to-date analysis will be presented in this talk. G. Maier, H. P. Reisenauer, M. De Marco, Angew. Chem. Int. Ed. 38, 108-110 (1999). U. Bozkaya, J. M. Turney, Y. Yamaguchi, and H. F. Schaefer III, J. Chem. Phys. 136, 164303 (2012). David T. Anderson and Mahmut Ruzi, 68th Ohio State University International Symposium on Molecular Spectroscopy, talk TE01 (2013).
Precise Ab-initio prediction of terahertz vibrational modes in crystalline systems
DEFF Research Database (Denmark)
Jepsen, Peter Uhd; Clark, Stewart J.
2007-01-01
We use a combination of experimental THz time-domain spectroscopy and ab-initio density functional perturbative theory to accurately predict the terahertz vibrational spectrum of molecules in the crystalline phase. Our calculations show that distinct vibrational modes found in solid-state materials...
Structural Analysis of Spiropyran Polimers using ATR Spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Delgado Macui, R; Rojas Lopez, M; Gayou, V L; Orduna Diaz, A [Centro de Investigacion en BiotecnologIa Aplicada del IPN, San Juan de los Molinos km. 1.5 Tepetitla de Lardizabal, A.P. 90700, Tlaxcala (Mexico)
2006-01-01
We have used infrared spectroscopy in attenuated total reflection (ATR) mode to analyze the interactions between the polymeric base and solvent with a photochromic material (spyropiran). We used cellulose acetate as polymeric base and the spyropiran; 1,3,3 trimethyl indoline-5-nitro benzopyrane. Thin films with different weight concentrations of SP were deposited in the polymeric base. The infrared spectra show bands whose frequencies are associated to several molecular bondings. It was observed a decreasing in intensity of absorbance for C = O stretching mode of the acetate group at 1720 cm{sup -1} and for C = C stretching mode for the main chain at 823 and 982 cm{sup -1} both associated to the presence of SP in polymeric films.
Scalar QNMs for higher dimensional black holes surrounded by quintessence in Rastall gravity
Energy Technology Data Exchange (ETDEWEB)
Graca, J.P.M.; Lobo, Iarley P. [Universidade Federal da Paraiba, Departamento de Fisica, Joao Pessoa, PB (Brazil)
2018-02-15
The spacetime solution for a black hole, surrounded by an exotic matter field, in Rastall gravity, is calculated in an arbitrary d-dimensional spacetime. After this, we calculate the scalar quasinormal modes of such solution, and study the shift on the modes caused by the modification of the theory of gravity, i.e., by the introduction of a new term due to Rastall. We conclude that the shift strongly depends on the kind of exotic field one is studying, but for a low density matter that supposedly pervades the universe, it is unlikely that Rastall gravity will cause an instability for the probe field. (orig.)
Fluctuations and instabilities of a holographic metal
Jokela, Niko; Järvinen, Matti; Lippert, Matthew
2013-02-01
We analyze the quasinormal modes of the D2-D8' model of 2+1-dimensional, strongly-coupled, charged fermions in a background magnetic field and at non-zero density. The model is known to include a quantum Hall phase with integer filling fraction. As expected, we find a hydrodynamical diffusion mode at small momentum and the nonzero-temperature holographic zero sound, which becomes massive above a critical magnetic field. We confirm the previously-known thermodynamic instability. In addition, we discover an instability at low temperature, large mass, and in a charge density and magnetic field range near the quantum Hall phase to an inhomogeneous striped phase.
Vibrational spectroscopy in the electron microscope.
Krivanek, Ondrej L; Lovejoy, Tracy C; Dellby, Niklas; Aoki, Toshihiro; Carpenter, R W; Rez, Peter; Soignard, Emmanuel; Zhu, Jiangtao; Batson, Philip E; Lagos, Maureen J; Egerton, Ray F; Crozier, Peter A
2014-10-09
Vibrational spectroscopies using infrared radiation, Raman scattering, neutrons, low-energy electrons and inelastic electron tunnelling are powerful techniques that can analyse bonding arrangements, identify chemical compounds and probe many other important properties of materials. The spatial resolution of these spectroscopies is typically one micrometre or more, although it can reach a few tens of nanometres or even a few ångströms when enhanced by the presence of a sharp metallic tip. If vibrational spectroscopy could be combined with the spatial resolution and flexibility of the transmission electron microscope, it would open up the study of vibrational modes in many different types of nanostructures. Unfortunately, the energy resolution of electron energy loss spectroscopy performed in the electron microscope has until now been too poor to allow such a combination. Recent developments that have improved the attainable energy resolution of electron energy loss spectroscopy in a scanning transmission electron microscope to around ten millielectronvolts now allow vibrational spectroscopy to be carried out in the electron microscope. Here we describe the innovations responsible for the progress, and present examples of applications in inorganic and organic materials, including the detection of hydrogen. We also demonstrate that the vibrational signal has both high- and low-spatial-resolution components, that the first component can be used to map vibrational features at nanometre-level resolution, and that the second component can be used for analysis carried out with the beam positioned just outside the sample--that is, for 'aloof' spectroscopy that largely avoids radiation damage.
Directory of Open Access Journals (Sweden)
Qixin He
2017-12-01
Full Text Available A Pound-Drever-Hall (PDH-based mode-locked cavity-enhanced sensor system was developed using a distributed feedback diode laser centered at 1.53 µm as the laser source. Laser temperature scanning, bias control of the piezoelectric ceramic transducer (PZT and proportional-integral-derivative (PID feedback control of diode laser current were used to repetitively lock the laser modes to the cavity modes. A gas absorption spectrum was obtained by using a series of absorption data from the discrete mode-locked points. The 15 cm-long Fabry-Perot cavity was sealed using an enclosure with an inlet and outlet for gas pumping and a PZT for cavity length tuning. The performance of the sensor system was evaluated by conducting water vapor measurements. A linear relationship was observed between the measured absorption signal amplitude and the H2O concentration. A minimum detectable absorption coefficient of 1.5 × 10–8 cm–1 was achieved with an averaging time of 700 s. This technique can also be used for the detection of other trace gas species by targeting the corresponding gas absorption line.
Microwave-plasma interactions studied via mode diagnostics in ALPHA
Energy Technology Data Exchange (ETDEWEB)
Friesen, T., E-mail: tim.friesen@cern.ch [University of Calgary, Department of Physics and Astronomy (Canada); Andresen, G. B. [Aarhus University, Department of Physics and Astronomy (Denmark); Ashkezari, M. D. [Simon Fraser University, Department of Physics (Canada); Baquero-Ruiz, M. [University of California, Department of Physics (United States); Bertsche, W. [Swansea University, Department of Physics (United Kingdom); Bowe, P. D. [Aarhus University, Department of Physics and Astronomy (Denmark); Butler, E. [CERN, Physics Department (Switzerland); Cesar, C. L. [Universidade Federal do Rio de Janeiro, Instituto de Fisica (Brazil); Chapman, S. [University of California, Department of Physics (United States); Charlton, M.; Eriksson, S. [Swansea University, Department of Physics (United Kingdom); Fajans, J. [University of California, Department of Physics (United States); Fujiwara, M. C. [University of Calgary, Department of Physics and Astronomy (Canada); Gill, D. R. [TRIUMF (Canada); Gutierrez, A. [University of British Columbia, Department of Physics and Astronomy (Canada); Hangst, J. S. [Aarhus University, Department of Physics and Astronomy (Denmark); Hardy, W. N. [University of British Columbia, Department of Physics and Astronomy (Canada); Hayano, R. S. [University of Tokyo, Department of Physics (Japan); Hayden, M. E. [Simon Fraser University, Department of Physics (Canada); Humphries, A. J. [Swansea University, Department of Physics (United Kingdom); Collaboration: ALPHA Collaboration; and others
2012-12-15
The goal of the ALPHA experiment is the production, trapping and spectroscopy of antihydrogen. A direct comparison of the ground state hyperfine spectra in hydrogen and antihydrogen has the potential to be a high-precision test of CPT symmetry. We present a novel method for measuring the strength of a microwave field for hyperfine spectroscopy in a Penning trap. This method incorporates a non-destructive plasma diagnostic system based on electrostatic modes within an electron plasma. We also show how this technique can be used to measure the cyclotron resonance of the electron plasma, which can potentially serve as a non-destructive measurement of plasma temperature.
Active mode locking of quantum cascade lasers in an external ring cavity.
Revin, D G; Hemingway, M; Wang, Y; Cockburn, J W; Belyanin, A
2016-05-05
Stable ultrashort light pulses and frequency combs generated by mode-locked lasers have many important applications including high-resolution spectroscopy, fast chemical detection and identification, studies of ultrafast processes, and laser metrology. While compact mode-locked lasers emitting in the visible and near infrared range have revolutionized photonic technologies, the systems operating in the mid-infrared range where most gases have their strong absorption lines, are bulky and expensive and rely on nonlinear frequency down-conversion. Quantum cascade lasers are the most powerful and versatile compact light sources in the mid-infrared range, yet achieving their mode-locked operation remains a challenge, despite dedicated effort. Here we report the demonstration of active mode locking of an external-cavity quantum cascade laser. The laser operates in the mode-locked regime at room temperature and over the full dynamic range of injection currents.
Ultrabroadband time-resolved THz spectroscopy of polymer-based solar cells
DEFF Research Database (Denmark)
Cooke, David G.; Krebs, Frederik C; Jepsen, Peter Uhd
2011-01-01
We have developed ultrabroadband THz spectroscopy in reflection mode for characterization of conductivity dynamics in conductive polymer samples used in organic solar cells. The spectrometer is designed to have a time resolution limited only by the duration of the optical pump pulse, thus enabling...
Low-Frequency Shear and Layer-Breathing Modes in Raman Scattering of Two-Dimensional Materials.
Liang, Liangbo; Zhang, Jun; Sumpter, Bobby G; Tan, Qing-Hai; Tan, Ping-Heng; Meunier, Vincent
2017-12-26
Ever since the isolation of single-layer graphene in 2004, two-dimensional layered structures have been among the most extensively studied classes of materials. To date, the pool of two-dimensional materials (2DMs) continues to grow at an accelerated pace and already covers an extensive range of fascinating and technologically relevant properties. An array of experimental techniques have been developed and used to characterize and understand these properties. In particular, Raman spectroscopy has proven to be a key experimental technique, thanks to its capability to identify minute structural and electronic effects in nondestructive measurements. While high-frequency (HF) intralayer Raman modes have been extensively employed for 2DMs, recent experimental and theoretical progress has demonstrated that low-frequency (LF) interlayer Raman modes are more effective at determining layer numbers and stacking configurations and provide a unique opportunity to study interlayer coupling. These advantages are due to 2DMs' unique interlayer vibration patterns where each layer behaves as an almost rigidly moving object with restoring forces corresponding to weak interlayer interactions. Compared to HF Raman modes, the relatively small attention originally devoted to LF Raman modes is largely due to their weaker signal and their proximity to the strong Rayleigh line background, which previously made their detection challenging. Recent progress in Raman spectroscopy with technical and hardware upgrades now makes it possible to probe LF modes with a standard single-stage Raman system and has proven crucial to characterize and understand properties of 2DMs. Here, we present a comprehensive and forward-looking review on the current status of exploiting LF Raman modes of 2DMs from both experimental and theoretical perspectives, revealing the fundamental physics and technological significance of LF Raman modes in advancing the field of 2DMs. We review a broad array of materials, with
Nanosecond fluorescence spectroscopy
International Nuclear Information System (INIS)
Leskovar, B.
1985-03-01
This article is a summary of a short course lecture given in conjunction with the 1984 Nuclear Science Symposium. Measuring systems for nanosecond fluorescence spectroscopy using single-photon counting techniques are presented. These involve systems based on relaxation-type spark gap light pulser and synchronously pumped mode-locked dye lasers. Furthermore, typical characteristics and optimization of operating conditions of the critical components responsible for the system time resolution are discussed. A short comparison of the most important deconvolution methods for numerical analysis of experimental data is given particularly with respect to the signal-to-noise ratio of the fluorescence signal. 22 refs., 8 figs
Hirschmann, Thomas Ch; Araujo, Paulo T; Muramatsu, Hiroyuki; Zhang, Xu; Nielsch, Kornelius; Kim, Yoong Ahm; Dresselhaus, Mildred S
2013-03-26
The optical characterization of bundled and individual triple-walled carbon nanotubes was studied for the first time in detail by using resonant Raman spectroscopy. In our approach, the outer tube of a triple-walled carbon nanotube system protects the two inner tubes (or equivalently the inner double-walled carbon nanotube) from external environment interactions making them a partially isolated system. Following the spectral changes and line-widths of the radial breathing modes and G-band by performing laser energy dependent Raman spectroscopy, it is possible to extract important information as regards to the electronic and vibrational properties, tube diameters, wall-to-wall distances, radial breathing mode, and G-band resonance evolutions as well as high-curvature intertube interactions in isolated double- and triple-walled carbon nanotube systems.
Transparency or spectral narrowing for two-mode squeezing and entanglement
International Nuclear Information System (INIS)
Hu Xiangming; Oh, C. H.
2011-01-01
We analyze the nonadiabatic effects on the propagation of a two-mode squeezed field inside a medium of three-level Λ atoms that display the dark resonance. We identify the different effects for the two-mode quantum properties: (i) unconditional transparency for the sum squeezing and (ii) induced transparency or spectral narrowing for the difference squeezing depending on the relative widths of the initial correlation spectrum to the transparency window. These effects combine to induce transparency or spectrum narrowing for the bipartite entanglement. The potential applications range from quantum information to laser spectroscopy and frequency standards.
Raman spectroscopy of optical properties in CdS thin films
Directory of Open Access Journals (Sweden)
Trajić J.
2015-01-01
Full Text Available Properties of CdS thin films were investigated applying atomic force microscopy (AFM and Raman spectroscopy. CdS thin films were prepared by using thermal evaporation technique under base pressure 2 x 10-5 torr. The quality of these films was investigated by AFM spectroscopy. We apply Raman scattering to investigate optical properties of CdS thin films, and reveal existence of surface optical phonon (SOP mode at 297 cm-1. Effective permittivity of mixture were modeled by Maxwell - Garnet approximation. [Projekat Ministarstva nauke Republike Srbije, br. 45003
Yang, Jun; Wang, Ze-Xin; Lu, Sheng; Lv, Wei-gang; Jiang, Xi-zhi; Sun, Lei
2017-03-01
The micro-arc oxidation process was conducted on ZK60 Mg alloy under two and three steps voltage-increasing modes by DC pulse electrical source. The effect of each mode on current-time responses during MAO process and the coating characteristic were analysed and discussed systematically. The microstructure, thickness and corrosion resistance of MAO coatings were evaluated by scanning electron microscopy (SEM), energy disperse spectroscopy (EDS), microscope with super-depth of field and electrochemical impedance spectroscopy (EIS). The results indicate that two and three steps voltage-increasing modes can improve weak spark discharges with insufficient breakdown strength in later period during the MAO process. Due to higher value of voltage and voltage increment, the coating with maximum thickness of about 20.20μm formed under two steps voltage-increasing mode shows the best corrosion resistance. In addition, the coating fabricated under three steps voltage-increasing mode shows a smoother coating with better corrosion resistance due to the lower amplitude of voltage-increasing.
Mode dynamics and confinement in the reversed field pinch
International Nuclear Information System (INIS)
Brunsell, P.R.; Bergsaker, H.; Brzozowski, J.H.; Cecconello, M.; Drake, J.R.; Malmberg, J.-A.; Scheffel, J.; Schnack, D.D.
2001-01-01
Tearing mode dynamics and toroidal plasma flow in the RFP has been experimentally studied in the Extrap T2 device. A toroidally localised, stationary magnetic field perturbation, the 'slinky mode' is formed in nearly all discharges. There is a tendency of increased phase alignment of different toroidal Fourier modes, resulting in higher localised mode amplitudes, with higher magnetic fluctuation level. The fluctuation level increases slightly with increasing plasma current and plasma density. The toroidal plasma flow velocity and the ion temperature has been measured with Doppler spectroscopy. Both the toroidal plasma velocity and the ion temperature clearly increase with I/N. Initial, preliminary experimental results obtained very recently after a complete change of the Extrap T2 front-end system (first wall, shell, TF coil), show that an operational window with mode rotation most likely exists in the rebuilt device, in contrast to the earlier case discussed above. A numerical code DEBSP has been developed to simulate the behaviour of RFP confinement in realistic geometry, including essential transport physics. Resulting scaling laws are presented and compared with results from Extrap T2 and other RFP experiments. (author)
Study of optical phonon modes of CdS nanoparticles using Raman
Indian Academy of Sciences (India)
In this paper we report the study of optical phonon modes of nanoparticles of CdS using Raman spectroscopy. Nanoparticle sample for the present study was synthesized through chemical precipitation technique. The CdS nanoparticles were then subjected to heat treatment at low temperature (150°C) for extended time ...
Nuzhnyy, D.; Petzelt, J.; Bovtun, V.; Kempa, M.; Kamba, S.; Hlinka, J.; Hehlen, B.
2017-11-01
From the new infrared (IR) reflectivity and time-domain terahertz spectra combined with available high-frequency dielectric data above the megahertz range in a broad temperature range of 10 to 900 K, a full picture of the soft- and central-mode behavior in the classical relaxor ferroelectric Pb (M g1 /3N b2 /3 ) O3 (PMN) is suggested. A detailed comparison is made with the recent hyper-Raman spectroscopy data [Hehlen et al., Phys. Rev. Lett. 117, 155501 (2016), 10.1103/PhysRevLett.117.155501] and also with other available experiments based on inelastic light and neutron scattering. It is revealed that each type of experiment provides slightly different data. The closest agreement is with the hyper-Raman data: both techniques yield the same number of soft-mode components and the same high-temperature softening towards the temperature T*≈400 K . In addition to evaluation of the IR-terahertz data using fitting with the standard factorized form of the dielectric function, we performed a successful fitting of the same data using the effective medium approach (EMA), originally based on the assumption that the mesoscopic structure of PMN consists of randomly oriented uniaxially anisotropic polar nanodomains (PNDs) with somewhat harder transverse optical polar modes in the direction along the local PND dipole [Hlinka et al., Phys. Rev. Lett. 96, 027601 (2006), 10.1103/PhysRevLett.96.027601]. Evaluation using Bruggeman EMA modeling has been successfully applied in the entire investigated temperature range. These results suggest that the response perpendicular to the local dipole moment, at high temperatures induced by random fields rather than PNDs, undergoes a classical softening from high temperatures with permittivity obeying the Curie-Weiss law, ɛ⊥=C /(T -TC) , where C =1.7 ×105K and TC=380 K , whereas the response parallel to it shows no softening. Below the Burns temperature, ˜620 K , a gigahertz relaxation ascribed to flipping of the PNDs emerges from the soft-mode
Toward practical terahertz time-domain spectroscopy
Brigada, David J.
Terahertz time-domain spectroscopy is a promising technology for the identification of explosive and pharmaceutical substances in adverse conditions. It interacts strongly with intermolecular vibrational and rotational modes. Terahertz also passes through many common dielectric covering materials, allowing for the identification of substances in envelopes, wrapped in opaque plastic, or otherwise hidden. However, there are several challenges preventing the adoption of terahertz spectroscopy outside the laboratory. This dissertation examines the problems preventing widespread adoption of terahertz technology and attempts to resolve them. In order to use terahertz spectroscopy to identify substances, a spectrum measured of the target sample must be compared to the spectra of various known standard samples. This dissertation examines various methods that can be employed throughout the entire process of acquiring and transforming terahertz waveforms to improve the accuracy of these comparisons. The concepts developed in this dissertation directly apply to terahertz spectroscopy, but also carry implications for other spectroscopy methods, from Raman to mass spectrometry. For example, these techniques could help to lower the rate of false positives at airport security checkpoints. This dissertation also examines the implementation of several of these methods as a way to realize a fully self-contained, handheld, battery-operated terahertz spectrometer. This device also employs techniques to allow minimally-trained operators use terahertz to detect different substances of interest. It functions as a proof-of-concept of the true benefits of the improvements that have been developed in this dissertation.
Fourier Transform Infrared Spectroscopy and Photoacoustic Spectroscopy for Saliva Analysis.
Mikkonen, Jopi J W; Raittila, Jussi; Rieppo, Lassi; Lappalainen, Reijo; Kullaa, Arja M; Myllymaa, Sami
2016-09-01
Saliva provides a valuable tool for assessing oral and systemic diseases, but concentrations of salivary components are very small, calling the need for precise analysis methods. In this work, Fourier transform infrared (FT-IR) spectroscopy using transmission and photoacoustic (PA) modes were compared for quantitative analysis of saliva. The performance of these techniques was compared with a calibration series. The linearity of spectrum output was verified by using albumin-thiocyanate (SCN(-)) solution at different SCN(-) concentrations. Saliva samples used as a comparison were obtained from healthy subjects. Saliva droplets of 15 µL were applied on the silicon sample substrate, 6 drops for each specimen, and dried at 37 ℃ overnight. The measurements were carried out using an FT-IR spectrometer in conjunction with an accessory unit for PA measurements. The findings with both transmission and PA modes mirror each other. The major bands presented were 1500-1750 cm(-1) for proteins and 1050-1200 cm(-1) for carbohydrates. In addition, the distinct spectral band at 2050 cm(-1) derives from SCN(-) anions, which is converted by salivary peroxidases to hypothiocyanate (OSCN(-)). The correlation between the spectroscopic data with SCN(-) concentration (r > 0.990 for transmission and r = 0.967 for PA mode) was found to be significant (P < 0.01), thus promising to be utilized in future applications. © The Author(s) 2016.
High-frequency coherent edge fluctuations in a high-pedestal-pressure quiescent H-mode plasma.
Yan, Z; McKee, G R; Groebner, R J; Snyder, P B; Osborne, T H; Burrell, K H
2011-07-29
A set of high frequency coherent (HFC) modes (f=80-250 kHz) is observed with beam emission spectroscopy measurements of density fluctuations in the pedestal of a strongly shaped quiescent H-mode plasma on DIII-D, with characteristics predicted for kinetic ballooning modes (KBM): propagation in the ion-diamagnetic drift direction; a frequency near 0.2-0.3 times the ion-diamagnetic frequency; inferred toroidal mode numbers of n∼10-25; poloidal wave numbers of k(θ)∼0.17-0.4 cm(-1); and high measured decorrelation rates (τ(c)(-1)∼ω(s)∼0.5×10(6) s(-1)). Their appearance correlates with saturation of the pedestal pressure. © 2011 American Physical Society
Singh, H.; Donetsky, D.; Liu, J.; Attenkofer, K.; Cheng, B.; Trelewicz, J. R.; Lubomirsky, I.; Stavitski, E.; Frenkel, A. I.
2018-04-01
We report the development, testing, and demonstration of a setup for modulation excitation spectroscopy experiments at the Inner Shell Spectroscopy beamline of National Synchrotron Light Source - II. A computer algorithm and dedicated software were developed for asynchronous data processing and analysis. We demonstrate the reconstruction of X-ray absorption spectra for different time points within the modulation pulse using a model system. This setup and the software are intended for a broad range of functional materials which exhibit structural and/or electronic responses to the external stimulation, such as catalysts, energy and battery materials, and electromechanical devices.
Picometer-resolution dual-comb spectroscopy with a free-running fiber laser.
Zhao, Xin; Hu, Guoqing; Zhao, Bofeng; Li, Cui; Pan, Yingling; Liu, Ya; Yasui, Takeshi; Zheng, Zheng
2016-09-19
Dual-comb spectroscopy holds the promise as real-time, high-resolution spectroscopy tools. However, in its conventional schemes, the stringent requirement on the coherence between two lasers requires sophisticated control systems. By replacing control electronics with an all-optical dual-comb lasing scheme, a simplified dual-comb spectroscopy scheme is demonstrated using one dual-wavelength, passively mode-locked fiber laser. Pulses with a intracavity-dispersion-determined repetition-frequency difference are shown to have good mutual coherence and stability. Capability to resolve the comb teeth and a picometer-wide optical spectral resolution are demonstrated using a simple data acquisition system. Energy-efficient, free-running fiber lasers with a small comb-tooth-spacing could enable low-cost dual-comb systems.
Coherent radio-frequency detection for narrowband direct comb spectroscopy.
Anstie, James D; Perrella, Christopher; Light, Philip S; Luiten, Andre N
2016-02-22
We demonstrate a scheme for coherent narrowband direct optical frequency comb spectroscopy. An extended cavity diode laser is injection locked to a single mode of an optical frequency comb, frequency shifted, and used as a local oscillator to optically down-mix the interrogating comb on a fast photodetector. The high spectral coherence of the injection lock generates a microwave frequency comb at the output of the photodiode with very narrow features, enabling spectral information to be further down-mixed to RF frequencies, allowing optical transmittance and phase to be obtained using electronics commonly found in the lab. We demonstrate two methods for achieving this step: a serial mode-by-mode approach and a parallel dual-comb approach, with the Cs D1 transition at 894 nm as a test case.
[Structure analysis of disease-related proteins using vibrational spectroscopy].
Hiramatsu, Hirotsugu
2014-01-01
Analyses of the structure and properties of identified pathogenic proteins are important for elucidating the molecular basis of diseases and in drug discovery research. Vibrational spectroscopy has advantages over other techniques in terms of sensitivity of detection of structural changes. Spectral analysis, however, is complicated because the spectrum involves a substantial amount of information. This article includes examples of structural analysis of disease-related proteins using vibrational spectroscopy in combination with additional techniques that facilitate data acquisition and analysis. Residue-specific conformation analysis of an amyloid fibril was conducted using IR absorption spectroscopy in combination with (13)C-isotope labeling, linear dichroism measurement, and analysis of amide I band features. We reveal a pH-dependent property of the interacting segment of an amyloidogenic protein, β2-microglobulin, which causes dialysis-related amyloidosis. We also reveal the molecular mechanisms underlying pH-dependent sugar-binding activity of human galectin-1, which is involved in cell adhesion, using spectroscopic techniques including UV resonance Raman spectroscopy. The decreased activity at acidic pH was attributed to a conformational change in the sugar-binding pocket caused by protonation of His52 (pKa 6.3) and the cation-π interaction between Trp68 and the protonated His44 (pKa 5.7). In addition, we show that the peak positions of the Raman bands of the C4=C5 stretching mode at approximately 1600 cm(-1) and the Nπ-C2-Nτ bending mode at approximately 1405 cm(-1) serve as markers of the His side-chain structure. The Raman signal was enhanced 12 fold using a vertical flow apparatus.
The hydrogen-bond network of water supports propagating optical phonon-like modes.
Elton, Daniel C; Fernández-Serra, Marivi
2016-01-04
The local structure of liquid water as a function of temperature is a source of intense research. This structure is intimately linked to the dynamics of water molecules, which can be measured using Raman and infrared spectroscopies. The assignment of spectral peaks depends on whether they are collective modes or single-molecule motions. Vibrational modes in liquids are usually considered to be associated to the motions of single molecules or small clusters. Using molecular dynamics simulations, here we find dispersive optical phonon-like modes in the librational and OH-stretching bands. We argue that on subpicosecond time scales these modes propagate through water's hydrogen-bond network over distances of up to 2 nm. In the long wavelength limit these optical modes exhibit longitudinal-transverse splitting, indicating the presence of coherent long-range dipole-dipole interactions, as in ice. Our results indicate the dynamics of liquid water have more similarities to ice than previously thought.
Lebedieva, Tetiana; Gubanov, Victor; Dovbeshko, Galyna; Pidhirnyi, Denys
2015-12-01
Different notations of graphene irreducible representations and optical modes could be found in the literature. The goals of this paper are to identify the correspondence between available notations, to calculate the optical modes of graphene in different points of the Brillouin zone, and to compare them with experimental data obtained by Raman and coherent anti-Stokes Raman scattering (CARS) spectroscopy. The mechanism of the resonance enhancement of vibration modes of the molecules adsorbed on graphene in CARS experiments is proposed. The possibility of appearance of the discrete breathing modes is discussed.
Sahay, Peeyush; Scherrer, Susan; Wang, Chuji
2012-10-01
Design and development of a plasma based optical emission spectroscopy-cavity ringdown spectroscopy (OES-CRDS) dual-mode portable spectrometer for in situ monitoring of trace elements is described. A microwave plasma torch (MPT) has been utilized, which serves both as an atomization and excitation source for the two modes, viz. OES and CRDS, of the spectrometer. Operation of both modes of the instrument is demonstrated with initial measurements of elemental mercury (Hg). A detection limit of 44 ng mL-1 for Hg at 253.65 nm was determined with the emission mode of the instrument. Severe radiation trapping of 253.65 nm line hampers the measurement of Hg in higher concentration region (> 50 μg ml-1). Therefore, a different wavelength, 365.01 nm, is suggested to measure Hg in that region. Ringdown measurements of the metastable 6s6p ^3P0 state of Hg in the plasma using a 404.65 nm palm size diode laser was conducted to demonstrate the CRDS mode of the instrument. Along with being portable, dual-mode, and self-calibrated, the instrument is capable of measuring a wide range of concentration ranging from sub ng mL-1 to several μg ml-1 for a number of elements.
Whispering gallery mode emission from a composite system of J-aggregates and photonic microcavity
Energy Technology Data Exchange (ETDEWEB)
Melnikau, Dzmitry; Savateeva, Diana [Centro de Física de Materiales (MPC, CSIC-UPV/EHU) and Donostia International Physics Center (DIPC), Po Manuel de Lardizabal 5, Donostia, San Sebastian 20018 (Spain); Rusakov, Konstantin I. [Department of Physics, Brest State Technical University, Brest 224017 (Belarus); Rakovich, Yury P., E-mail: Yury.Rakovich@ehu.es [Centro de Física de Materiales (MPC, CSIC-UPV/EHU) and Donostia International Physics Center (DIPC), Po Manuel de Lardizabal 5, Donostia, San Sebastian 20018 (Spain); IKERBASQUE, Basque Foundation for Science, Bilbao (Spain)
2014-01-15
We report on development and characterization of Whispering Gallery Modes spherical microcavities integrated with organic dye molecules in a J-aggregate state. The microcavities are studied using micro-photoluminescence spectroscopy, and fluorescence lifetime imaging confocal microscopy. Directional emission of light from the microcavity is also experimentally demonstrated and attributed to the photonic jets generated in the microsphere. -- Highlights: • Report on the development and characterization of hybrid system consisting of thin shell of J-aggregates and spherical Whispering Gallery Mode microcavity. • An investigation of spontaneous emission rate in the shell of J-aggregates integrated with a Whispering Gallery Mode cavity. • Demonstration of directional emission from Whispering Gallery Mode cavity with J-aggregates which is highly desirable functionality for both micro- and nano-scale cavities.
Broadband Doppler-limited two-photon and stepwise excitation spectroscopy with laser frequency combs
Hipke, Arthur; Meek, Samuel A.; Ideguchi, Takuro; Hänsch, Theodor W.; Picqué, Nathalie
2014-07-01
Multiplex two-photon excitation spectroscopy is demonstrated at Doppler-limited resolution. We describe first Fourier-transform two-photon spectroscopy of an atomic sample with two mode-locked laser oscillators in a dual-comb technique. Each transition is uniquely identified by the modulation imparted by the interfering comb excitations. The temporal modulation of the spontaneous two-photon fluorescence is monitored with a single photodetector, and the spectrum of all excited transitions is revealed by a Fourier transform.
Self-Similarity of Plasmon Edge Modes on Koch Fractal Antennas.
Bellido, Edson P; Bernasconi, Gabriel D; Rossouw, David; Butet, Jérémy; Martin, Olivier J F; Botton, Gianluigi A
2017-11-28
We investigate the plasmonic behavior of Koch snowflake fractal geometries and their possible application as broadband optical antennas. Lithographically defined planar silver Koch fractal antennas were fabricated and characterized with high spatial and spectral resolution using electron energy loss spectroscopy. The experimental data are supported by numerical calculations carried out with a surface integral equation method. Multiple surface plasmon edge modes supported by the fractal structures have been imaged and analyzed. Furthermore, by isolating and reproducing self-similar features in long silver strip antennas, the edge modes present in the Koch snowflake fractals are identified. We demonstrate that the fractal response can be obtained by the sum of basic self-similar segments called characteristic edge units. Interestingly, the plasmon edge modes follow a fractal-scaling rule that depends on these self-similar segments formed in the structure after a fractal iteration. As the size of a fractal structure is reduced, coupling of the modes in the characteristic edge units becomes relevant, and the symmetry of the fractal affects the formation of hybrid modes. This analysis can be utilized not only to understand the edge modes in other planar structures but also in the design and fabrication of fractal structures for nanophotonic applications.
Energy Technology Data Exchange (ETDEWEB)
Fujiwara, M.; Sugisaki, M. [CREST-JST and Department of Physics, Osaka City University, Osaka 558-8585 (Japan); Gall, A.; Robert, B. [CEA, Institut de Biologie et Technologies de Saclay, and CNRS, Gif-sur-Yvette F-91191 (France); Cogdell, R.J. [IBLS, Glasgow Biomedical Research Centre, University of Glasgow, Glasgow G12 8QQ, Scotland (United Kingdom); Hashimoto, H., E-mail: hassy@sci.osaka-cu.ac.j [CREST-JST and Department of Physics, Osaka City University, Osaka 558-8585 (Japan)
2009-12-15
We investigate how structural distortions in carotenoid cause decoherences of its high-frequency vibrational modes by applying the sub-20-fs time-resolved transient grating spectroscopy to {beta}-carotene and lycopene. The results indicate that the C=C central stretching mode shows significant loss of coherence under the effects of the steric hindrance between {beta}-ionone ring and polyene backbone, whereas the other high-frequency modes do not show such dependency on the structural distortions.
International Nuclear Information System (INIS)
Fujiwara, M.; Sugisaki, M.; Gall, A.; Robert, B.; Cogdell, R.J.; Hashimoto, H.
2009-01-01
We investigate how structural distortions in carotenoid cause decoherences of its high-frequency vibrational modes by applying the sub-20-fs time-resolved transient grating spectroscopy to β-carotene and lycopene. The results indicate that the C=C central stretching mode shows significant loss of coherence under the effects of the steric hindrance between β-ionone ring and polyene backbone, whereas the other high-frequency modes do not show such dependency on the structural distortions.
Electrically-pumped, broad-area, single-mode photonic crystal lasers.
Zhu, Lin; Chak, Philip; Poon, Joyce K S; DeRose, Guy A; Yariv, Amnon; Scherer, Axel
2007-05-14
Planar broad-area single-mode lasers, with modal widths of the order of tens of microns, are technologically important for high-power applications and improved coupling efficiency into optical fibers. They may also find new areas of applications in on-chip integration with devices that are of similar size scales, such as for spectroscopy in microfluidic chambers or optical signal processing with micro-electromechanical systems. An outstanding challenge is that broad-area lasers often require external means of control, such as injection-locking or a frequency/spatial filter to obtain single-mode operation. In this paper, we propose and demonstrate effective index-guided, large-area, edge-emitting photonic crystal lasers driven by pulsed electrical current injection at the optical telecommunication wavelength of 1550 nm. By suitable design of the photonic crystal lattice, our lasers operate in a single mode with a 1/e(2) modal width of 25 microm and a length of 600 microm.
[MR spectroscopy of amygdala: investigation of methodology].
Tang, Hehan; Yue, Qiang; Gong, Qiyong
2013-08-01
This study was aimed to optimize the methods of magnetic resonance spectroscopy (MRS) to improve its quality in amygdala. Forty-three volunteers were examined at right and left amygdala using stimulated-echo acquisition mode (STEAM), and point-resolved spectroscopy series (PRESS) with and without saturation bands. The Cr-SNR, water-suppression level, water full width at half maximum (FWHM) and RMS noise of three sequences were compared. The results showed that (1) the Cr-SNR and water-suppression lelvel of PRESS with saturation bands were better than that of PRESS without saturation bands and STEAM (P<0.001); (2) the left and right RMS noise was significantly different both using PRESS with saturation bands and using STEAM (P<0.05); (3) there was a positive, significant correlation between Cr-SNR and voxel size (P<0.05). Therefore, PRESS with saturation bands is better than PRESS without saturation bands or STEAM for the spectroscopy of amygdala. It is also useful to make the voxel as big as possible to improve the spectral quality.
Multispectral detection of cutaneous lesions using spectroscopy and microscopy approaches
Borisova, E.; Genova-Hristova, Ts.; Troyanova, P.; Pavlova, E.; Terziev, I.; Semyachkina-Glushkovskaya, O.; Lomova, M.; Genina, E.; Stanciu, G.; Tranca, D.; Avramov, L.
2018-02-01
Autofluorescence, diffuse-reflectance and transmission spectral, and microscopic measurements were made on different cutaneous neoplastic lesions, namely basal cell carcinoma, squamous cell carcinoma, malignant melanoma, and dysplastic and benign lesions related. Spectroscopic measurements were made on ex vivo tissue samples, and confocal microscopy investigations were made on thin tissue slices. Fluorescence spectra obtained reveal statistically significant differences between the different benign, dysplastic and malignant lesions by the level of emission intensity, as well by spectral shape, which are fingerprints applicable for differentiation algorithms. In reflectance mode the most significant differences are related to the influence of skin pigments - melanin and hemoglobin. Transmission spectroscopy mode gave complementary optical properties information about the tissue samples investigated to that one of reflectance and absorption spectroscopy. Using autofluorescence detection of skin lesions we obtain very good diagnostic performance for distinguishing of nonmelanoma lesions. Using diffuse reflectance and transmission spectroscopy we obtain significant tool for pigmented pathologies differentiation, but it is a tool with moderate sensitivity for non-melanoma lesions detection. One could rapidly increase the diagnostic accuracy of the received combined "optical biopsy" method when several spectral detection techniques are applied in common algorithm for lesions' differentiation. Specific spectral features observed in each type of lesion investigated on micro and macro level would be presented and discussed. Correlation between the spectral data received and the microscopic features observed would be discussed in the report.
Fourier transform infrared spectroscopy in physics laboratory courses
International Nuclear Information System (INIS)
Möllmann, K-P; Vollmer, M
2013-01-01
Infrared spectrometry is one of the most important tools in the field of spectroscopic analysis. This is due to the high information content of spectra in the so-called spectroscopic fingerprint region, which enables measurement not only of gases, but also of liquids and solids. Today, infrared spectroscopy is almost completely dominated by Fourier transform infrared (FTIR) spectroscopy. FTIR spectroscopy is able to detect minute quantities in the ppm and ppb ranges, and the respective analyses are now standard tools in science as well as industry. Therefore FTIR spectroscopy should be taught within the standard curriculum at university to physicists and engineers. Here we present respective undergraduate laboratory experiments designed for students at the end of their third year. Experiments deal first with understanding the spectrometer and second with recording and analysing spectra. On the one hand, transmission spectra of gases are treated which relate to environmental analytics (being probably the most prominent and well-known examples), and on the other hand, the focus is on the transmission and reflection spectra of solids. In particular, silicon wafers are studied—as is regularly done in the microelectronics industry—in order to characterize their thickness, oxygen content and phonon modes. (paper)
Wang, Q; Liu, X; Kibria, M G; Zhao, S; Nguyen, H P T; Li, K H; Mi, Z; Gonzalez, T; Andrews, M P
2014-09-07
Micro-Raman scattering and X-ray photoelectron spectroscopy were employed to investigate Mg-doped GaN nanowires. With the increase of Mg doping level, pronounced Mg-induced local vibrational modes were observed. The evolution of longitudinal optical phonon-plasmon coupled mode, together with detailed X-ray photoelectron spectroscopy studies, show that the near-surface region of nanowires can be transformed from weakly n-type to p-type with the increase of Mg doping.
ATR and transmission analysis of pigments by means of far infrared spectroscopy.
Kendix, Elsebeth L; Prati, Silvia; Joseph, Edith; Sciutto, Giorgia; Mazzeo, Rocco
2009-06-01
In the field of FTIR spectroscopy, the far infrared (FIR) spectral region has been so far less investigated than the mid-infrared (MIR), even though it presents great advantages in the characterization of those inorganic compounds, which are inactive in the MIR, such as some art pigments, corrosion products, etc. Furthermore, FIR spectroscopy is complementary to Raman spectroscopy if the fluorescence effects caused by the latter analytical technique are considered. In this paper, ATR in the FIR region is proposed as an alternative method to transmission for the analyses of pigments. This methodology was selected in order to reduce the sample amount needed for analysis, which is a must when examining cultural heritage materials. A selection of pigments have been analyzed in both ATR and transmission mode, and the resulting spectra were compared with each other. To better perform this comparison, an evaluation of the possible effect induced by the thermal treatment needed for the preparation of the polyethylene pellets on the transmission spectra of the samples has been carried out. Therefore, pigments have been analyzed in ATR mode before and after heating them at the same temperature employed for the polyethylene pellet preparation. The results showed that while the heating treatment causes only small changes in the intensity of some bands, the ATR spectra were characterized by differences in both intensity and band shifts towards lower frequencies if compared with those recorded in transmission mode. All pigments' transmission and ATR spectra are presented and discussed, and the ATR method was validated on a real case study.
Hart, James L; Lang, Andrew C; Leff, Asher C; Longo, Paolo; Trevor, Colin; Twesten, Ray D; Taheri, Mitra L
2017-08-15
In many cases, electron counting with direct detection sensors offers improved resolution, lower noise, and higher pixel density compared to conventional, indirect detection sensors for electron microscopy applications. Direct detection technology has previously been utilized, with great success, for imaging and diffraction, but potential advantages for spectroscopy remain unexplored. Here we compare the performance of a direct detection sensor operated in counting mode and an indirect detection sensor (scintillator/fiber-optic/CCD) for electron energy-loss spectroscopy. Clear improvements in measured detective quantum efficiency and combined energy resolution/energy field-of-view are offered by counting mode direct detection, showing promise for efficient spectrum imaging, low-dose mapping of beam-sensitive specimens, trace element analysis, and time-resolved spectroscopy. Despite the limited counting rate imposed by the readout electronics, we show that both core-loss and low-loss spectral acquisition are practical. These developments will benefit biologists, chemists, physicists, and materials scientists alike.
Time-resolved and doppler-reduced laser spectroscopy on atoms
International Nuclear Information System (INIS)
Bergstroem, H.
1991-10-01
Radiative lifetimes have been studied in neutral boron, carbon, silicon and strontium, in singly ionized gadolinium and tantalum and in molecular carbon monoxide and C 2 . The time-resolved techniques were based either on pulsed lasers or pulse-modulated CW lasers. Several techniques have been utilized for the production of free atoms and ions such as evaporation into an atomic beam, sputtering in hollow cathodes and laser-produced plasmas. Hyperfine interactions in boron, copper and strontium have been examined using quantum beat spectroscopy, saturation spectroscopy and collimated atomic beam spectroscopy. Measurement techniques based on effusive hollow cathodes as well as laser produced plasmas in atomic physics have been developed. Investigations on laser produced plasmas using two colour beam deflection tomography for determination of electron densities have been performed. Finally, new possibilities for view-time-expansion in light-in-flight holography using mode-locked CW lasers have been demonstrated. (au)
Burton, Dallas Jonathan
The field of laser-based diagnostics has been a topic of research in various fields, more specifically for applications in environmental studies, military defense technologies, and medicine, among many others. In this dissertation, a novel laser-based optical diagnostic method, differential laser-induced perturbation spectroscopy (DLIPS), has been implemented in a spectroscopy mode and expanded into an imaging mode in combination with fluorescence techniques. The DLIPS method takes advantage of deep ultraviolet (UV) laser perturbation at sub-ablative energy fluences to photochemically cleave bonds and alter fluorescence signal response before and after perturbation. The resulting difference spectrum or differential image adds more information about the target specimen, and can be used in combination with traditional fluorescence techniques for detection of certain materials, characterization of many materials and biological specimen, and diagnosis of various human skin conditions. The differential aspect allows for mitigation of patient or sample variation, and has the potential to develop into a powerful, noninvasive optical sensing tool. The studies in this dissertation encompass efforts to continue the fundamental research on DLIPS including expansion of the method to an imaging mode. Five primary studies have been carried out and presented. These include the use of DLIPS in a spectroscopy mode for analysis of nitrogen-based explosives on various substrates, classification of Caribbean fruit flies versus Caribbean fruit flies that have been irradiated with gamma rays, and diagnosis of human skin cancer lesions. The nitrogen-based explosives and Caribbean fruit flies have been analyzed with the DLIPS scheme using the imaging modality, providing complementary information to the spectroscopic scheme. In each study, a comparison between absolute fluorescence signals and DLIPS responses showed that DLIPS statistically outperformed traditional fluorescence techniques
Acoustic resonance spectroscopy (ARS): ARS300 operations manual, software version 2.01
Energy Technology Data Exchange (ETDEWEB)
NONE
1996-07-25
Acoustic Resonance Spectroscopy (ARS) is a nondestructive evaluation technology developed at the Los Alamos National Laboratory. The ARS technique is a fast, safe, and nonintrusive technique that is particularly useful when a large number of objects need to be tested. Any physical object, whether solid, hollow, or fluid filled, has many modes of vibration. These modes of vibration, commonly referred to as the natural resonant modes or resonant frequencies, are determined by the object`s shape, size, and physical properties, such as elastic moduli, speed of sound, and density. If the object is mechanically excited at frequencies corresponding to its characteristic natural vibrational modes, a resonance effect can be observed when small excitation energies produce large amplitude vibrations in the object. At other excitation frequencies, i.e., vibrational response of the object is minimal.
Photoluminescence and Raman spectroscopy of MBE-grown InN nanocolumns
International Nuclear Information System (INIS)
Segura-Ruiz, J.; Cantarero, A.; Garro, N.; Denker, C.; Werner, F.; Malindretos, J.; Rizzi, A.
2008-01-01
InN nanocolumns grown under different conditions by plasma-assisted molecular beam epitaxy on p-Si (111) substrates are studied by micro-Raman and photoluminescence (PL) spectroscopies. The nanocolumns are free of strain and have an improved crystal quality as shown by the frequency and linewidth of the nonpolar E 2 h mode. Uncoupled polar modes coexist with a couple LO phonon-plasmon mode and are sensitive to the nanocolumn morphology. Variations in the growth conditions also modify the PL spectra significantly. An increase in the PL energy also involves a reduction of the integrated intensity and an increase of the PL linewidth. This overall phenomenology highlights the role of the surface accumulation layer in these nanostructures. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Photoluminescence and Raman spectroscopy of MBE-grown InN nanocolumns
Energy Technology Data Exchange (ETDEWEB)
Segura-Ruiz, J.; Cantarero, A. [Materials Science Institute, University of Valencia, PO Box 22085, 46071 Valencia (Spain); Garro, N. [Materials Science Institute, University of Valencia, PO Box 22085, 46071 Valencia (Spain); Fundacio General de la Universitat de Valencia, University of Valencia, PO Box 22085, 46071 Valencia (Spain); Denker, C.; Werner, F.; Malindretos, J.; Rizzi, A. [IV. Physikalisches Institut, Georg-August Universitaet Goettingen (Germany)
2008-07-01
InN nanocolumns grown under different conditions by plasma-assisted molecular beam epitaxy on p-Si (111) substrates are studied by micro-Raman and photoluminescence (PL) spectroscopies. The nanocolumns are free of strain and have an improved crystal quality as shown by the frequency and linewidth of the nonpolar E{sub 2}{sup h} mode. Uncoupled polar modes coexist with a couple LO phonon-plasmon mode and are sensitive to the nanocolumn morphology. Variations in the growth conditions also modify the PL spectra significantly. An increase in the PL energy also involves a reduction of the integrated intensity and an increase of the PL linewidth. This overall phenomenology highlights the role of the surface accumulation layer in these nanostructures. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Strong overtones modes in inelastic electron tunneling spectroscopy with cross-conjugated molecules
DEFF Research Database (Denmark)
Jørgensen, Jacob Lykkebo; Gagliardi, Alessio; Pecchia, Alessandro
2013-01-01
. With this in mind, we investigate a spectroscopic method capable of providing insight into these junctions for cross-conjugated molecules: inelastic electron tunneling spectroscopy (IETS). IETS has the advantage that the molecule interface is probed directly by the tunneling current. Previously, it has been thought...... and leading to suppressed levels of elastic current. In most theoretical studies, only the elastic contributions to the current are taken into account. In this paper, we study the inelastic contributions to the current in cross-conjugated molecules and find that while the inelastic contribution to the current...
Gravitational waves from rotating proto-neutron stars
International Nuclear Information System (INIS)
Ferrari, V; Gualtieri, L; Pons, J A; Stavridis, A
2004-01-01
We study the effects of rotation on the quasi-normal modes (QNMs) of a newly born proto-neutron star (PNS) at different evolutionary stages, until it becomes a cold neutron star (NS). We use the Cowling approximation, neglecting spacetime perturbations, and consider different models of evolving PNS. The frequencies of the modes of a PNS are considerably lower than those of a cold NS, and are further lowered by rotation; consequently, if QNMs were excited in a sufficiently energetic process, they would radiate waves that could be more easily detectable by resonant-mass and interferometric detectors than those emitted by a cold NS. We find that for high rotation rates, some of the g-modes become unstable via the CFS instability; however, this instability is likely to be suppressed by competing mechanisms before emitting a significant amount of gravitational waves
Optical Splitters Based on Self-Imaging Effect in Multi-Mode Waveguide Made by Ion Exchange in Glass
Directory of Open Access Journals (Sweden)
O. Barkman
2013-04-01
Full Text Available Design and modeling of single mode optical multi-mode interference structures with graded refractive index is reported. Several samples of planar optical channel waveguides were obtained by Ag+, Na+ and K+, Na+ one step thermal ion exchange process in molten salt on GIL49 glass substrate and new special optical glass for ion exchange technology. Waveguide properties were measured by optical mode spectroscopy. Obtained data were used for further design and modeling of single mode channel waveguide and subsequently for the design of 1 to 3 multimode interference power splitter in order to improve simulation accuracy. Designs were developed by utilizing finite difference beam propagation method.
Quantum interference effects on the intensity of the G modes in double-walled carbon nanotubes
International Nuclear Information System (INIS)
Tran, Huy Nam; Blancon, Jean-Christophe Robert; Arenal, Raul
2017-01-01
The effects of quantum interferences on the excitation dependence of the intensity of G modes have been investigated on single-walled carbon nanotubes [Duque et al., Phys. Rev. Lett.108, 117404 (2012)]. In this work, by combining optical absorption spectroscopy and Raman scattering on individual index identified double-walled carbon nanotubes, we examine the experimental excitation dependence of the intensity of longitudinal optical and transverse optical G modes of the constituent inner and outer single-walled carbon nanotubes. The observed striking dependencies are understood in terms of quantum interference effects. Considering such effects, the excitation dependence of the different components of the G modes permit to unambiguously assign each of them as originating from the longitudinal or transverse G modes of inner and outer tubes.
Polarization plasma spectroscopy (PPS) viewed from plasma physics and fusion research
International Nuclear Information System (INIS)
Ida, Katsumi
1998-01-01
Recently the measurements of poloidal magnetic field become important in plasma physics and nuclear fusion research, since an improved confinement mode associating with a negative magnetic shear has been found. The polarization plasma spectroscopy is recognized to be a useful tool to measure poloidal magnetic field and pitch angle of magnetic field. (author)
A mystery of black-hole gravitational resonances
International Nuclear Information System (INIS)
Hod, Shahar
2016-01-01
More than three decades ago, Detweiler provided an analytical formula for the gravitational resonant frequencies of rapidly-rotating Kerr black holes. In the present work we shall discuss an important discrepancy between the famous analytical prediction of Detweiler and the recent numerical results of Zimmerman et al. In addition, we shall refute the claim that recently appeared in the physics literature that the Detweiler-Teukolsky-Press resonance equation for the characteristic gravitational eigenfrequencies of rapidly-rotating Kerr black holes is not valid in the regime of damped quasinormal resonances with ℑω/T_B_H≫1 (here ω and T_B_H are respectively the characteristic quasinormal resonant frequency of the Kerr black hole and its Bekenstein-Hawking temperature). The main goal of the present paper is to highlight and expose this important black-hole quasinormal mystery (that is, the intriguing discrepancy between the analytical and numerical results regarding the gravitational quasinormal resonance spectra of rapidly-rotating Kerr black holes).
A mystery of black-hole gravitational resonances
Energy Technology Data Exchange (ETDEWEB)
Hod, Shahar [The Ruppin Academic Center, Emeq Hefer 40250 (Israel); The Hadassah Academic College, Jerusalem 91010 (Israel)
2016-08-30
More than three decades ago, Detweiler provided an analytical formula for the gravitational resonant frequencies of rapidly-rotating Kerr black holes. In the present work we shall discuss an important discrepancy between the famous analytical prediction of Detweiler and the recent numerical results of Zimmerman et al. In addition, we shall refute the claim that recently appeared in the physics literature that the Detweiler-Teukolsky-Press resonance equation for the characteristic gravitational eigenfrequencies of rapidly-rotating Kerr black holes is not valid in the regime of damped quasinormal resonances with ℑω/T{sub BH}≫1 (here ω and T{sub BH} are respectively the characteristic quasinormal resonant frequency of the Kerr black hole and its Bekenstein-Hawking temperature). The main goal of the present paper is to highlight and expose this important black-hole quasinormal mystery (that is, the intriguing discrepancy between the analytical and numerical results regarding the gravitational quasinormal resonance spectra of rapidly-rotating Kerr black holes).
System upgradation for surface mode negative ion beam extraction experiments in ROBIN
International Nuclear Information System (INIS)
Pandya, Kaushal; Bansal, Gourab; Gahlaut, Agrajit; Soni, Jignesh; Yadav, Ratnakar K.; Mahesh, Vuppugalla; Tyagi, Himanshu; Parmar, KanuG.; Mistri, Hiren; Bhagora, Jighesh; Prajapati, Bhavesh; Patel, Kartik; Bhuyan, Manas; Gouswami, Mehul; Bandyopadhyay, Mainak; Chakraborty, Arun K.
2017-01-01
Operational commissioning of ROBIN forms an important milestone in the Indian programme on the R&D on negative ion beams. The commissioning activity has been effected in sequence, in synchronisation with the availability of High voltage Power Supply (HVPS) systems and routine operation has now been established in the cesiated, surface mode. Significant efforts have been placed in upgrading the system to initiate the surface mode operation. These include incorporation of a temperature controlled Cesium (Cs) delivery system, spectroscopic diagnostics for detection of Cs lines, installation of plasma grid heating and closed loop warm water circuit for source components heating and Doppler Shift Spectroscopy (DSS) system. The specific design and integration features for these upgrades are discussed and preliminary results obtained from the operation of ROBIN in the surface mode are presented.
System upgradation for surface mode negative ion beam extraction experiments in ROBIN
Energy Technology Data Exchange (ETDEWEB)
Pandya, Kaushal, E-mail: kpandya@ipr.res.in [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Bansal, Gourab; Gahlaut, Agrajit; Soni, Jignesh [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Yadav, Ratnakar K. [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Mahesh, Vuppugalla [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Tyagi, Himanshu [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Parmar, KanuG.; Mistri, Hiren [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Bhagora, Jighesh [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Prajapati, Bhavesh; Patel, Kartik [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Bhuyan, Manas [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Gouswami, Mehul [Bhakti Management Services, Gandhinagar, 382007, Gujarat (India); Bandyopadhyay, Mainak [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Chakraborty, Arun K. [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India)
2017-01-15
Operational commissioning of ROBIN forms an important milestone in the Indian programme on the R&D on negative ion beams. The commissioning activity has been effected in sequence, in synchronisation with the availability of High voltage Power Supply (HVPS) systems and routine operation has now been established in the cesiated, surface mode. Significant efforts have been placed in upgrading the system to initiate the surface mode operation. These include incorporation of a temperature controlled Cesium (Cs) delivery system, spectroscopic diagnostics for detection of Cs lines, installation of plasma grid heating and closed loop warm water circuit for source components heating and Doppler Shift Spectroscopy (DSS) system. The specific design and integration features for these upgrades are discussed and preliminary results obtained from the operation of ROBIN in the surface mode are presented.
Bifurcation to Enhanced Performance H-mode on NSTX
Battaglia, D. J.; Chang, C. S.; Gerhardt, S. P.; Kaye, S. M.; Maingi, R.; Smith, D. R.
2015-11-01
The bifurcation from H-mode (H98 Performance (EP)H-mode (H98 = 1.2 - 2.0) on NSTX is found to occur when the ion thermal (χi) and momentum transport become decoupled from particle transport, such that the ion temperature (Ti) and rotation pedestals increase independent of the density pedestal. The onset of the EPH-mode transition is found to correlate with decreased pedestal collisionality (ν*ped) and an increased broadening of the density fluctuation (dn/n) spectrum in the pedestal as measured with beam emission spectroscopy. The spectrum broadening at decreased ν*ped is consistent with GEM simulations that indicate the toroidal mode number of the most unstable instability increases as ν*ped decreases. The lowest ν*ped, and thus largest spectrum broadening, is achieved with low pedestal density via lithium wall conditioning and when Zeff in the pedestal is significantly reduced via large edge rotation shear from external 3D fields or a large ELM. Kinetic neoclassical transport calculations (XGC0) confirm that Zeff is reduced when edge rotation braking leads to a more negative Er that shifts the impurity density profiles inward relative to the main ion density. These calculations also describe the role kinetic neoclassical and anomalous transport effects play in the decoupling of energy, momentum and particle transport at the bifurcation to EPH-mode. This work was sponsored by the U.S. Department of Energy.
NMR spectroscopy using liquid crystal solvents
Emsley, JW
2013-01-01
NMR Spectroscopy using Liquid Crystal Solvents covers the importance of using a liquid crystal solvent in NMR to derive nuclear dipolar spin-spin coupling constants. This book is composed of ten chapters, and begins with a brief description of the features and benefits of liquid crystal in NMR spectroscopic analysis. The succeeding chapters deal with the mode of operation of nuclear spin Hamiltonian for partially oriented molecules and the analysis of NMR spectra of partially oriented molecules, as well as the determination of rigid molecule structure. These topics are followed by discussions
High-resolution flurescence spectroscopy in immunoanalysis
Energy Technology Data Exchange (ETDEWEB)
Grubor, Nenad M. [Iowa State Univ., Ames, IA (United States)
2005-01-01
The work presented in this dissertation combines highly sensitive and selective fluorescence line-narrowing spectroscopy (FLNS) detection with various modes of immunoanalytical techniques. It has been shown that FLNS is capable of directly probing molecules immunocomplexed with antibodies, eliminating analytical ambiguities that may arise from interferences that accompany traditional immunochemical techniques. Moreover, the utilization of highly cross-reactive antibodies for highly specific analyte determination has been demonstrated. Finally, they demonstrate the first example of the spectral resolution of diastereomeric analytes based on their interaction with a cross-reactive antibody.
Spectroscopy with trapped highly charged ions
International Nuclear Information System (INIS)
Beiersdorfer, Peter
2009-01-01
We give an overview of atomic spectroscopy performed on electron beam ion traps at various locations throughout the world. Spectroscopy at these facilities contributes to various areas of science and engineering, including but not limited to basic atomic physics, astrophysics, extreme ultraviolet lithography, and the development of density and temperature diagnostics of fusion plasmas. These contributions are accomplished by generating, for example, spectral surveys, making precise radiative lifetime measurements, accounting for radiative power emitted in a given wavelength band, illucidating isotopic effects, and testing collisional-radiative models. While spectroscopy with electron beam ion traps had originally focused on the x-ray emission from highly charged ions interacting with the electron beam, the operating modes of such devices have expanded to study radiation in almost all wavelength bands from the visible to the hard x-ray region; and at several facilities the ions can be studied even in the absence of an electron beam. Photon emission after charge exchange or laser excitation has been observed; and the work is no longer restricted to highly charged ions. Much of the experimental capabilities are unique to electron beam ion traps, and the work performed with these devices cannot be undertaken elsewhere. However, in other areas the work on electron beam ion traps rivals the spectroscopy performed with conventional ion traps or heavy-ion storage rings. The examples we present highlight many of the capabilities of the existing electron beam ion traps and their contributions to physics.
TSUDA, H; ARENDS, J
Single crystals of synthetic hydroxyapatite have been examined by orientational micro-Raman spectroscopy. The observed Raman bands include the PO43-/OH- internal and external. modes over the spectral range from 180 to 3600 cm(-1). The Raman-active symmetry tensors (A, E(1), and E(2)) of
Heavy atom vibrational modes and low-energy vibrational autodetachment in nitromethane anions
International Nuclear Information System (INIS)
Thompson, Michael C.; Weber, J. Mathias; Baraban, Joshua H.; Matthews, Devin A.; Stanton, John F.
2015-01-01
We report infrared spectra of nitromethane anion, CH 3 NO 2 − , in the region 700–2150 cm −1 , obtained by Ar predissociation spectroscopy and electron detachment spectroscopy. The data are interpreted in the framework of second-order vibrational perturbation theory based on coupled-cluster electronic structure calculations. The modes in the spectroscopic region studied here are mainly based on vibrations involving the heavier atoms; this work complements earlier studies on nitromethane anion that focused on the CH stretching region of the spectrum. Electron detachment begins at photon energies far below the adiabatic electron affinity due to thermal population of excited vibrational states
Photothermal spectroscopy of aerosols
International Nuclear Information System (INIS)
Campillo, A.J.; Lin, H.B.
1981-04-01
In situ aerosol absorption spectroscopy was performed using two novel photothermal detection schemes. The first, based on a photorefractive effect and coherent detection, called phase fluctuation optical heterodyne (PFLOH) spectroscopy, could, depending on the geometry employed, yield particle specific or particle and gas absorption data. Single particles of graphite as small as 1 μm were detected in the particle specific mode. In another geometrical configuration, the total absorption (both gas and particle) of submicron sized aerosols of ammonium sulfate particles in equilibrium with gaseous ammonia and water vapor were measured at varying CO 2 laser frequencies. The specific absorption coefficient for the sulfate ion was measured to be 0.5 m 2 /g at 1087 cm -1 . The absorption coefficient sensitivity of this scheme was less than or equal to 10 -8 cm -1 . The second scheme is a hybrid visible Mie scattering scheme incorporating photothermal modulation. Particle specific data on ammonium sulfate droplets were obtained. For chemically identical species, the relative absorption spectrum versus laser frequency can be obtained for polydisperse aerosol distributions directly from the data without the need for complex inverse scattering calculations
Carbon nanotubes doped with trivalent elements by using back - scattering Raman spectroscopy
Directory of Open Access Journals (Sweden)
S. A. Babanejad
2008-12-01
Full Text Available In this paper by using DC arc discharge method and acetylene gas, as the carbon source, and nitrogen, as the carrier gas, canrbon nanotubes, CNTs, doped with trivalent element boron, B, have been produced. The deposited CNTs on the cathod electrod, which have structural doped properties to boron element, have been collected and after purification have been investigated by back-scattering Raman spectroscopy. The results reveal that the high frequency G mode component in CNTs doped with electron acceptor element, B, shift to higher wavenumbers. The low frequency G mode component which can appear at approximately 1540–1570 cm-1 wavenumber region, called BWF mode, is a sign of metallic CNT. In the synthesized doped CNTs due to the presence of boron dopant, D mode has sharp peaks and has relatively high intensity in the Raman spectra .
A reaction cell for ambient pressure soft x-ray absorption spectroscopy
Castán-Guerrero, C.; Krizmancic, D.; Bonanni, V.; Edla, R.; Deluisa, A.; Salvador, F.; Rossi, G.; Panaccione, G.; Torelli, P.
2018-05-01
We present a new experimental setup for performing X-ray Absorption Spectroscopy (XAS) in the soft X-ray range at ambient pressure. The ambient pressure XAS setup is fully compatible with the ultra high vacuum environment of a synchrotron radiation spectroscopy beamline end station by means of ultrathin Si3N4 membranes acting as windows for the X-ray beam and seal of the atmospheric sample environment. The XAS detection is performed in total electron yield (TEY) mode by probing the drain current from the sample with a picoammeter. The high signal/noise ratio achievable in the TEY mode, combined with a continuous scanning of the X-ray energies, makes it possible recording XAS spectra in a few seconds. The first results show the performance of this setup to record fast XAS spectra from sample surfaces exposed at atmospheric pressure, even in the case of highly insulating samples. The use of a permanent magnet inside the reaction cell enables the measurement of X-ray magnetic circular dichroism at ambient pressure.
Coherent cavity-enhanced dual-comb spectroscopy.
Fleisher, Adam J; Long, David A; Reed, Zachary D; Hodges, Joseph T; Plusquellic, David F
2016-05-16
Dual-comb spectroscopy allows for the rapid, multiplexed acquisition of high-resolution spectra without the need for moving parts or low-resolution dispersive optics. This method of broadband spectroscopy is most often accomplished via tight phase locking of two mode-locked lasers or via sophisticated signal processing algorithms, and therefore, long integration times of phase coherent signals are difficult to achieve. Here we demonstrate an alternative approach to dual-comb spectroscopy using two phase modulator combs originating from a single continuous-wave laser capable of > 2 hours of coherent real-time averaging. The dual combs were generated by driving the phase modulators with step-recovery diodes where each comb consisted of > 250 teeth with 203 MHz spacing and spanned > 50 GHz region in the near-infrared. The step-recovery diodes are passive devices that provide low-phase-noise harmonics for efficient coupling into an enhancement cavity at picowatt optical powers. With this approach, we demonstrate the sensitivity to simultaneously monitor ambient levels of CO2, CO, HDO, and H2O in a single spectral region at a maximum acquisition rate of 150 kHz. Robust, compact, low-cost and widely tunable dual-comb systems could enable a network of distributed multiplexed optical sensors.
Mid-Infrared Frequency-Agile Dual-Comb Spectroscopy
Luo, Pei-Ling; Yan, Ming; Iwakuni, Kana; Millot, Guy; Hänsch, Theodor W.; Picqué, Nathalie
2016-06-01
We demonstrate a new approach to mid-infrared dual-comb spectroscopy. It opens up new opportunities for accurate real-time spectroscopic diagnostics and it significantly simplifies the technique of dual-comb spectroscopy. Two mid-infrared frequency combs of slightly different repetition frequencies and moderate, but rapidly tunable, spectral span are generated in the 2800-3200 cm-1 region. The generators rely on electro-optic modulators, nonlinear fibers for spectral broadening and difference frequency generation and do not involve mode-locked lasers. Flat-top frequency combs span up to 10 cm-1 with a comb line spacing of 100 MHz (3×10-3 cm-1). The performance of the spectrometer without any phase-lock electronics or correction scheme is illustrated with spectra showing resolved comb lines and Doppler-limited spectra of methane. High precision on the spectroscopic parameter (line positions and intensities) determination is demonstrated for spectra measured on a millisecond time scale and it is validated with comparison with literature data. G. Millot, S. Pitois, M. Yan, T. Hovannysyan, A. Bendahmane, T.W. Hänsch, N. Picqué, Frequency-agile dual-comb spectroscopy, Nature Photonics 10, 27-30 (2016).
Force spectroscopy of hepatocytic extracellular matrix components
Energy Technology Data Exchange (ETDEWEB)
Yongsunthon, R., E-mail: YongsuntR@Corning.com [Corning Incorporated, SP-FR-01, R1S32D, Corning, NY 14831 (United States); Baker, W.A.; Bryhan, M.D.; Baker, D.E.; Chang, T.; Petzold, O.N.; Walczak, W.J.; Liu, J.; Faris, R.A.; Senaratne, W.; Seeley, L.A.; Youngman, R.E. [Corning Incorporated, SP-FR-01, R1S32D, Corning, NY 14831 (United States)
2009-07-15
We present atomic force microscopy and force spectroscopy data of live hepatocytes (HEPG2/C3A liver cell line) grown in Eagle's Minimum Essential Medium, a complex solution of salts and amino acids commonly used for cell culture. Contact-mode imaging and force spectroscopy of this system allowed correlation of cell morphology and extracellular matrix (ECM) properties with substrate properties. Force spectroscopy analysis of cellular 'footprints' indicated that the cells secrete large polymers (e.g., 3.5 {mu}m contour length and estimated MW 1000 kDa) onto their substrate surface. Although definitive identification of the polymers has not yet been achieved, fluorescent-labeled antibody staining has specified the presence of ECM proteins such as collagen and laminin in the cellular footprints. The stretched polymers appear to be much larger than single molecules of known ECM components, such as collagen and heparan sulfate proteoglycan, thus suggesting that the cells create larger entangled, macromolecular structures from smaller components. There is strong evidence which suggests that the composition of the ECM is greatly influenced by the hydrophobicity of the substrate surface, with preferential production and/or adsorption of larger macromolecules on hydrophobic surfaces.
Electron attachment cross sections obtained from electron attachment spectroscopy
International Nuclear Information System (INIS)
Popp, P.; Baumbach, J.I.; Leonhardt, J.W.; Mothes, S.
1988-01-01
Electron capture detectors have a high sensitivity for substances with high thermal electron attachment cross sections. The electron attachment spectroscopy makes it possible to change the mean electron energy in such a way that the maximum for dissociative electron attachment is reached. Thus, best operation modes of the detection system as well as significant dependencies of electron attachment coefficients are available. Cross sections for electron attachment as a function of the electron energy are obtained with the knowledge of electron energy distribution functions from Boltzmann equation analysis by a special computer code. A disadvantage of this electron attachment spectroscopy is the superposition of space charge effects due to the decrease of the electron drift velocity with increasing mean electron energy. These influences are discussed. (author)
Cavity QED experiments with a whispering-gallery-mode bottle resonator
International Nuclear Information System (INIS)
O'Shea, D.
2013-01-01
The interaction of a two-level atom with a single mode of the quantized electromagnetic field constitutes one of the most fundamental systems investigated in quantum optics. We have pursued such an investigation where rubidium atoms are strongly coupled to the modes of a whispering-gallery-mode (WGM) resonator that is itself interfaced with an optical fiber. In order to facilitate studies of this atom-light interaction, an experimental apparatus was constructed around a novel type of WGM resonator developed in our group. The spectral and spatial mode structure of this resonator yield an intriguing atom-light response arising principally from the existence of two frequency-degenerate modes. This thesis reports on high resolution experiments studying the transmission and reflection spectra of modes with a high quality factor (Q=10 7 -10 8 ) in our WGM resonator. Light is coupled into and out of WGMs by frustrated total internal reflection using an optical nanofiber. The atom-light interaction is facilitated by an atomic fountain that delivers a cloud of atoms to the location of the resonator. At random moments, single-atoms are clearly observed transiting the evanescent field of the resonator modes with a transit time of a few microseconds. A high-speed experimental control system was developed to firstly detect the coupling of individual atoms to the resonator and secondly to perform time-resolved spectroscopy on the strongly coupled atom-resonator system. Spectral measurements clearly resolve an atom-induced change in the resonant transmission of the coupled system (65% absolute change) that is much larger than predicted in the standard Jaynes-Cummings model (25% absolute change) and that has thus far not been observed. To gain further insight, we experimentally explored the properties of the interaction and performed supporting simulations. Spectroscopy was performed on the atom-resonator system using two nanofibers to in- and out-couple light for probing
Optical fiber strain sensor using fiber resonator based on frequency comb Vernier spectroscopy
DEFF Research Database (Denmark)
Zhang, Liang; Lu, Ping; Chen, Li
2012-01-01
A novel (to our best knowledge) optical fiber strain sensor using a fiber ring resonator based on frequency comb Vernier spectroscopy is proposed and demonstrated. A passively mode-locked optical fiber laser is employed to generate a phased-locked frequency comb. Strain applied to the optical fib...
Application of FTIR spectroscopy for analysis of the quality of honey
Directory of Open Access Journals (Sweden)
Kędzierska-Matysek Monika
2018-01-01
Full Text Available Every kind of honey is a very precious natural product which is made by Mellifera bees species. The chemical composition of honey depends on its origin or mode of production. Honey consists essentially of different sugars, predominantly fructose and glucose. There are also non – sugar ingredients like proteins and amino acids, as well as some kind of enzymes, such as: invertase, amylase, glucose oxidase, catalase and phosphatase. The fact that honey is one of the oldest medicine known worldwide is remarkable. Scientists all over the world have been trying to improve analytical methods as well as to implement new ones in order to reaffirm the high quality of honey the benefits of which may be distracted or disturbed. There are many methods and popular analytical techniques, including as follows: mass spectroscopy and molecular spectroscopy (especially FTIR spectroscopy. The infrared spectroscopy technique is one of the most common analytical methods which are used to analyse honey nowadays. The main aim of the task was to use ATR-FTIR infrared spectroscopy to compare selected honey samples as well as typical sequences coming out from certain functional groups in the analysed samples.
Avoided crossing of rattler modes in thermoelectric materials
DEFF Research Database (Denmark)
Christensen, Mogens; Abrahamsen, Asger Bech; Christensen, Niels Bech
2008-01-01
thermoelectric materials, and the challenge is to limit the conduction of heat by phonons, without simultaneously reducing the charge transport. This is named the 'phonon glass-electron crystal' concept and may be realized in host-guest systems. The guest entities are believed to have independent oscillations......, so-called rattler modes, which scatter the acoustic phonons and reduce the thermal conductivity. We have investigated the phonon dispersion relation in the phonon glass-electron crystal material Ba8Ga16Ge30 using neutron triple-axis spectroscopy. The results disclose unambiguously the theoretically...
Anomalous compression behaviour in Nd2O3 studied by x-ray diffraction and Raman spectroscopy
Directory of Open Access Journals (Sweden)
Sheng Jiang
2018-02-01
Full Text Available The structural stability of hexagonal Nd2O3 under pressure has been investigated by in situ synchrotron angle dispersive x-ray diffraction and Raman spectroscopy up to 53.1 GPa and 37.0 GPa, respectively. Rietveld analysis of the x-ray diffraction data indicate that the hexagonal Nd2O3 undergoes an isostructural phase transition in the pressure range from 10.2 to 20.3 GPa, accompanied by anomalous lattice compressibility and pressure-volume curve. A third-order Birch-Murnaghan fit based on the observed Pressure-Volume data yields zero pressure bulk moduli (B0 of 142(4 and 183(6 GPa for the low and high pressure hexagonal phases, respectively. Raman spectroscopy confirms this isostructural transition, the pressure dependence of the Raman modes display noticeable breaks in the pressure range of 9.7-20.9 GPa, which is consistent with the change of Nd-O bond length. The pressure coefficients of Raman peaks and the mode Grüneisen parameters of different Raman modes were also determined.
Raman and IR-ATR spectroscopy studies of heteroepitaxial structures with a GaN:C top layer
Cerqueira, M. F.; Vieira, L. G.; Alves, A.; Correia, R.; Huber, M.; Andreev, A.; Bonanni, A.; Vasilevskiy, M. I.
2017-09-01
This work, motivated by the technologically important task of determination of carbon dopant location in the GaN crystal lattice, employed Raman spectroscopy, with both resonant and non-resonant excitation, and infrared (IR) spectroscopy, in the attenuated total reflection (ATR) configuration, to study lattice vibration modes in a set of carbon-doped GaN (GaN:C) epilayers grown by metalorganic vapour phase epitaxy. We analyse Raman and IR-ATR spectra from the point of view of possible effects of the carbon doping, namely: (i) local vibration mode of C atoms in the nitrogen sublattice (whose frequency we theoretically estimate as 768 cm-1 using an isotope defect model), and (ii) shift in the positions of longitudinal modes owing to the phonon-plasmon coupling. We find only indirect hints of the doping effect on the resonant Raman spectra. However, we show theoretically and confirm experimentally that the IR-ATR spectroscopy can be a much more sensitive tool for this purpose, at least for the considered structures. A weak perturbation of the dielectric function of GaN:C, caused by the substitutional carbon impurity, is shown to produce a measurable dip in the ATR reflectivity spectra at ≈770 cm-1 for both p- and s-polarizations. Moreover, it influences a specific (guided-wave type) mode observed at ≈737 cm-1, originating from the GaN layer, which appears in the narrow frequency window where the real parts of the two components of the dielectric tensor of the hexagonal crystal have opposite signs. This interpretation is supported by our modelling of the whole multilayer structure, using a transfer matrix formalism.
Energy Technology Data Exchange (ETDEWEB)
Slenkamp, Karla M.; Lynch, Michael S.; Van Kuiken, Benjamin E.; Brookes, Jennifer F.; Bannan, Caitlin C.; Daifuku, Stephanie L.; Khalil, Munira, E-mail: mkhalil@chem.washington.edu [Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195 (United States)
2014-02-28
Using polarization-selective two-dimensional infrared (2D IR) spectroscopy, we measure anharmonic couplings and angles between the transition dipole moments of the four cyanide stretching (ν{sub CN}) vibrations found in [(NH{sub 3}){sub 5}Ru{sup III}NCFe{sup II}(CN){sub 5}]{sup −} (FeRu) dissolved in D{sub 2}O and formamide and [(NC){sub 5}Fe{sup II}CNPt{sup IV}(NH{sub 3}){sub 4}NCFe{sup II}(CN){sub 5}]{sup 4−} (FePtFe) dissolved in D{sub 2}O. These cyanide-bridged transition metal complexes serve as model systems for studying the role of high frequency vibrational modes in ultrafast photoinduced charge transfer reactions. Here, we focus on the spectroscopy of the ν{sub CN} modes in the electronic ground state. The FTIR spectra of the ν{sub CN} modes of the bimetallic and trimetallic systems are strikingly different in terms of frequencies, amplitudes, and lineshapes. The experimental 2D IR spectra of FeRu and FePtFe and their fits reveal a set of weakly coupled anharmonic ν{sub CN} modes. The vibrational mode anharmonicities of the individual ν{sub CN} modes range from 14 to 28 cm{sup −1}. The mixed-mode anharmonicities range from 2 to 14 cm{sup −1}. In general, the bridging ν{sub CN} mode is most weakly coupled to the radial ν{sub CN} mode, which involves the terminal CN ligands. Measurement of the relative transition dipole moments of the four ν{sub CN} modes reveal that the FeRu molecule is almost linear in solution when dissolved in formamide, but it assumes a bent geometry when dissolved in D{sub 2}O. The ν{sub CN} modes are modelled as bilinearly coupled anharmonic oscillators with an average coupling constant of 6 cm{sup −1}. This study elucidates the role of the solvent in modulating the molecular geometry and the anharmonic vibrational couplings between the ν{sub CN} modes in cyanide-bridged transition metal mixed valence complexes.
International Nuclear Information System (INIS)
Yatom, Shurik; Selinsky, Rachel S.
2017-01-01
Arc discharge synthesis of single-walled carbon nanotubes (SWCNTs) remains largely uncontrollable, due to incomplete understanding of the synthetic process itself. Here, we show that synthesis of SWCNTs by a carbon arc may not constitute a single continuous process, but may instead consist of two distinct modes. One of these, a “synthesis-on” mode, produces the majority of the nanomaterials. During the synthesis-on mode, proportionally more carbon nanotubes are collected than in another mode, a “synthesis-off” mode. Both synthesis-on and synthesis-off modes for a typical arc configuration, employing a hollow anode filled with a mixture of powdered metal catalyst and graphite, were characterized by using in situ electrical, imaging, and spectroscopic diagnostics, along with ex situ imaging and spectroscopy. The synthesis-on mode duration is rare compared to the total arc run-time, helping to explain the poor selectivity found in the final collected products, a known inadequacy of arc synthesis. Finally, the rarity of the synthesis on mode occurence may be due to the synthesis off mode being more favorable energetically.
Kendix, Elsebeth Langholz
2009-01-01
FIR spectroscopy is an alternative way of collecting spectra of many inorganic pigments and corrosion products found on art objects, which is not normally observed in the MIR region. Most FIR spectra are traditionally collected in transmission mode but as a real novelty it is now also possible to record FIR spectra in ATR (Attenuated Total Reflectance) mode. In FIR transmission we employ polyethylene (PE) for preparation of pellets by embedding the sample in PE. Unfortunately, ...
Gravitational wave spectroscopy of binary neutron star merger remnants with mode stacking
Yang, Huan; Paschalidis, Vasileios; Yagi, Kent; Lehner, Luis; Pretorius, Frans; Yunes, Nicolás
2018-01-01
A binary neutron star coalescence event has recently been observed for the first time in gravitational waves, and many more detections are expected once current ground-based detectors begin operating at design sensitivity. As in the case of binary black holes, gravitational waves generated by binary neutron stars consist of inspiral, merger, and postmerger components. Detecting the latter is important because it encodes information about the nuclear equation of state in a regime that cannot be probed prior to merger. The postmerger signal, however, can only be expected to be measurable by current detectors for events closer than roughly ten megaparsecs, which given merger rate estimates implies a low probability of observation within the expected lifetime of these detectors. We carry out Monte Carlo simulations showing that the dominant postmerger signal (the ℓ=m =2 mode) from individual binary neutron star mergers may not have a good chance of observation even with the most sensitive future ground-based gravitational wave detectors proposed so far (the Einstein Telescope and Cosmic Explorer, for certain equations of state, assuming a full year of operation, the latest merger rates, and a detection threshold corresponding to a signal-to-noise ratio of 5). For this reason, we propose two methods that stack the postmerger signal from multiple binary neutron star observations to boost the postmerger detection probability. The first method follows a commonly used practice of multiplying the Bayes factors of individual events. The second method relies on an assumption that the mode phase can be determined from the inspiral waveform, so that coherent mode stacking of the data from different events becomes possible. We find that both methods significantly improve the chances of detecting the dominant postmerger signal, making a detection very likely after a year of observation with Cosmic Explorer for certain equations of state. We also show that in terms of detection
Raman spectroscopy of ZnMnO thin films grown by pulsed laser deposition
Orozco, S.; Riascos, H.; Duque, S.
2016-02-01
ZnMnO thin films were grown by Pulsed Laser Deposition (PLD) technique onto Silicon (100) substrates at different growth conditions. Thin films were deposited varying Mn concentration, substrate temperature and oxygen pressure. ZnMnO samples were analysed by using Raman Spectroscopy that shows a red shift for all vibration modes. Raman spectra revealed that nanostructure of thin films was the same of ZnO bulk, wurzite hexagonal structure. The structural disorder was manifested in the line width and shape variations of E2(high) and E2(low) modes located in 99 and 434cm-1 respectively, which may be due to the incorporation of Mn ions inside the ZnO crystal lattice. Around 570cm-1 was found a peak associated to E1(LO) vibration mode of ZnO. 272cm-1 suggest intrinsic host lattice defects. Additional mode centred at about 520cm-1 can be overlap of Si and Mn modes.
Identification of surface species by vibrational normal mode analysis. A DFT study
Zhao, Zhi-Jian; Genest, Alexander; Rösch, Notker
2017-10-01
Infrared spectroscopy is an important experimental tool for identifying molecular species adsorbed on a metal surface that can be used in situ. Often vibrational modes in such IR spectra of surface species are assigned and identified by comparison with vibrational spectra of related (molecular) compounds of known structure, e. g., an organometallic cluster analogue. To check the validity of this strategy, we carried out a computational study where we compared the normal modes of three C2Hx species (x = 3, 4) in two types of systems, as adsorbates on the Pt(111) surface and as ligands in an organometallic cluster compound. The results of our DFT calculations reproduce the experimental observed frequencies with deviations of at most 50 cm-1. However, the frequencies of the C2Hx species in both types of systems have to be interpreted with due caution if the coordination mode is unknown. The comparative identification strategy works satisfactorily when the coordination mode of the molecular species (ethylidyne) is similar on the surface and in the metal cluster. However, large shifts are encountered when the molecular species (vinyl) exhibits different coordination modes on both types of substrates.
Resonant Absorption in GaAs-Based Nanowires by Means of Photo-Acoustic Spectroscopy
Petronijevic, E.; Leahu, G.; Belardini, A.; Centini, M.; Li Voti, R.; Hakkarainen, T.; Koivusalo, E.; Guina, M.; Sibilia, C.
2018-03-01
Semiconductor nanowires made of high refractive index materials can couple the incoming light to specific waveguide modes that offer resonant absorption enhancement under the bandgap wavelength, essential for light harvesting, lasing and detection applications. Moreover, the non-trivial ellipticity of such modes can offer near field interactions with chiral molecules, governed by near chiral field. These modes are therefore very important to detect. Here, we present the photo-acoustic spectroscopy as a low-cost, reliable, sensitive and scattering-free tool to measure the spectral position and absorption efficiency of these modes. The investigated samples are hexagonal nanowires with GaAs core; the fabrication by means of lithography-free molecular beam epitaxy provides controllable and uniform dimensions that allow for the excitation of the fundamental resonant mode around 800 nm. We show that the modulation frequency increase leads to the discrimination of the resonant mode absorption from the overall absorption of the substrate. As the experimental data are in great agreement with numerical simulations, the design can be optimized and followed by photo-acoustic characterization for a specific application.
Directory of Open Access Journals (Sweden)
Osorio M.R. Zapatero
2013-04-01
Full Text Available Thanks to different ground-based surveys and space missions, nowadays we have a fairly large sample of discovered extra-solar planets to study and, without a doubt, this number will increase in the future. One of the most succesful techniques that allows us to prove the physical properties and atmospheric composition of these exoplanets is transmission spectroscopy. The level of precision that is require to measure these effects provides a technical challenge that is solved by using big telescopes and stable instruments to reach low noise levels. In this article, we will discuss the use of the 10m class telescope GTC to observed planetary transits in spectroscopic mode and some of the results that we are currently obtaining.
Adaptive sampling dual terahertz comb spectroscopy using dual free-running femtosecond lasers.
Yasui, Takeshi; Ichikawa, Ryuji; Hsieh, Yi-Da; Hayashi, Kenta; Cahyadi, Harsono; Hindle, Francis; Sakaguchi, Yoshiyuki; Iwata, Tetsuo; Mizutani, Yasuhiro; Yamamoto, Hirotsugu; Minoshima, Kaoru; Inaba, Hajime
2015-06-02
Terahertz (THz) dual comb spectroscopy (DCS) is a promising method for high-accuracy, high-resolution, broadband THz spectroscopy because the mode-resolved THz comb spectrum includes both broadband THz radiation and narrow-line CW-THz radiation characteristics. In addition, all frequency modes of a THz comb can be phase-locked to a microwave frequency standard, providing excellent traceability. However, the need for stabilization of dual femtosecond lasers has often hindered its wide use. To overcome this limitation, here we have demonstrated adaptive-sampling THz-DCS, allowing the use of free-running femtosecond lasers. To correct the fluctuation of the time and frequency scales caused by the laser timing jitter, an adaptive sampling clock is generated by dual THz-comb-referenced spectrum analysers and is used for a timing clock signal in a data acquisition board. The results not only indicated the successful implementation of THz-DCS with free-running lasers but also showed that this configuration outperforms standard THz-DCS with stabilized lasers due to the slight jitter remained in the stabilized lasers.
Controlling magnetic and electric dipole modes in hollow silicon nanocylinders.
van de Haar, Marie Anne; van de Groep, Jorik; Brenny, Benjamin J M; Polman, Albert
2016-02-08
We propose a dielectric nanoresonator geometry consisting of hollow dielectric nanocylinders which support geometrical resonances. We fabricate such hollow Si particles with an outer diameter of 108-251 nm on a Si substrate, and determine their resonant modes with cathodo-luminescence (CL) spectroscopy and optical dark-field (DF) scattering measurements. The scattering behavior is numerically investigated in a systematic fashion as a function of wavelength and particle geometry. We find that the additional design parameter as a result of the introduction of a center gap can be used to control the relative spectral spacing of the resonant modes, which will enable additional control over the angular radiation pattern of the scatterers. Furthermore, the gap offers direct access to the enhanced magnetic dipole modal field in the center of the particle.
Hanzawa, Nobutomo; Saitoh, Kuimasa; Sakamoto, Taiji; Matsui, Takashi; Tsujikawa, Kyozo; Koshiba, Masanori; Yamamoto, Fumihiko
2013-11-04
We proposed a PLC-based mode multi/demultiplexer (MUX/DEMUX) with an asymmetric parallel waveguide for mode division multiplexed (MDM) transmission. The mode MUX/DEMUX including a mode conversion function with an asymmetric parallel waveguide can be realized by matching the effective indices of the LP(01) and LP(11) modes of two waveguides. We report the design of a mode MUX/DEMUX that can support C-band WDM-MDM transmission. The fabricated mode MUX/DEMUX realized a low insertion loss of less than 1.3 dB and high a mode extinction ratio that exceeded 15 dB. We used the fabricated mode MUX/DEMUX to achieve a successful 2 mode x 4 wavelength x 10 Gbps transmission over a 9 km two-mode fiber with a penalty of less than 1 dB.
Sil, Souvik; Kanti Saha, Tushar; Kumar, Avinash; Bera, Sudipta K.; Banerjee, Ayan
2017-12-01
We develop an optical tweezers system using a single dual-mode optical fiber where mesoscopic absorbing particles can be trapped in three dimensions and manipulated employing photophoretic forces. We generate a superposition of fundamental and first order Hermite-Gaussian beam modes by the simple innovation of coupling a laser into a commercial optical fiber designed to be single mode for a wavelength higher than that of the laser. We achieve robust trapping of the absorbing particles for hours using both the pure fundamental and superposition mode beams and attain large manipulation velocities of ˜5 mm s-1 in the axial direction and ˜0.75 mm s-1 in the radial direction. We then demonstrate that the superposition mode is more effective in trapping and manipulation compared to the fundamental mode by around 80%, which may be increased several times by the use of a pure first order Hermite-Gaussian mode. The work has promising implications for trapping and spectroscopy of aerosols in air using simple optical fiber-based traps.
Small black holes in global AdS spacetime
Jokela, Niko; Pönni, Arttu; Vuorinen, Aleksi
2016-04-01
We study the properties of two-point functions and quasinormal modes in a strongly coupled field theory holographically dual to a small black hole in global anti-de Sitter spacetime. Our results are seen to smoothly interpolate between known limits corresponding to large black holes and thermal AdS space, demonstrating that the Son-Starinets prescription works even when there is no black hole in the spacetime. Omitting issues related to the internal space, the results can be given a field theory interpretation in terms of the microcanonical ensemble, which provides access to energy densities forbidden in the canonical description.
On-chip dual-comb source for spectroscopy.
Dutt, Avik; Joshi, Chaitanya; Ji, Xingchen; Cardenas, Jaime; Okawachi, Yoshitomo; Luke, Kevin; Gaeta, Alexander L; Lipson, Michal
2018-03-01
Dual-comb spectroscopy is a powerful technique for real-time, broadband optical sampling of molecular spectra, which requires no moving components. Recent developments with microresonator-based platforms have enabled frequency combs at the chip scale. However, the need to precisely match the resonance wavelengths of distinct high quality-factor microcavities has hindered the development of on-chip dual combs. We report the simultaneous generation of two microresonator combs on the same chip from a single laser, drastically reducing experimental complexity. We demonstrate broadband optical spectra spanning 51 THz and low-noise operation of both combs by deterministically tuning into soliton mode-locked states using integrated microheaters, resulting in narrow (lasers or microwave oscillators. We demonstrate high signal-to-noise ratio absorption spectroscopy spanning 170 nm using the dual-comb source over a 20-μs acquisition time. Our device paves the way for compact and robust spectrometers at nanosecond time scales enabled by large beat-note spacings (>1 GHz).
Three-dimensional Einstein-Klein-Gordon system in characteristic numerical relativity
International Nuclear Information System (INIS)
Barreto, W.; Silva, A. da; Lehner, L.; Gomez, R.; Rosales, L.; Winicour, J.
2005-01-01
We incorporate a massless scalar field into a three-dimensional code for the characteristic evolution of the gravitational field. The extended three-dimensional code for the Einstein-Klein-Gordon system is calibrated to be second-order convergent. It provides an accurate calculation of the gravitational and scalar radiation at infinity. As an application, we simulate the fully nonlinear evolution of an asymmetric scalar pulse of ingoing radiation propagating toward an interior Schwarzschild black hole and compute the backscattered scalar and gravitational outgoing radiation patterns. The amplitudes of the scalar and gravitational outgoing radiation modes exhibit the predicted power law scaling with respect to the amplitude of the initial data. For the scattering of an axisymmetric scalar field, the final ring down matches the complex frequency calculated perturbatively for the l=2 quasinormal mode
International Nuclear Information System (INIS)
Oldenburg, Amy L; Boppart, Stephen A
2010-01-01
We present a new method for performing dynamic elastography of soft tissue samples. By sensing nanoscale displacements with optical coherence tomography, a chirped, modulated force is applied to acquire the mechanical spectrum of a tissue sample within a few seconds. This modulated force is applied via magnetic nanoparticles, named 'nanotransducers', which are diffused into the tissue, and which contribute negligible inertia to the soft tissue mechanical system. Using this novel system, we observed that excised tissues exhibit mechanical resonance modes which are well described by a linear damped harmonic oscillator. Results are validated by using cylindrical tissue phantoms of agarose in which resonant frequencies (30-400 Hz) are consistent with longitudinal modes and the sample boundary conditions. We furthermore show that the Young's modulus can be computed from their measured resonance frequencies, analogous to resonant ultrasound spectroscopy for stiff material analysis. Using this new technique, named magnetomotive resonant acoustic spectroscopy (MRAS), we monitored the relative stiffening of an excised rat liver during a chemical fixation process.
AgI -Induced Switching of DNA Binding Modes via Formation of a Supramolecular Metallacycle.
Basak, Shibaji; Léon, J Christian; Ferranco, Annaleizle; Sharma, Renu; Hebenbrock, Marian; Lough, Alan; Müller, Jens; Kraatz, Heinz-Bernhard
2018-03-12
The histidine derivative L1 of the DNA intercalator naphthalenediimide (NDI) forms a triangular Ag I complex (C2). The interactions of L1 and of C2 with DNA were studied by circular dichroism (CD) and UV/Vis spectroscopy and by viscosity studies. Different binding modes were observed for L1 and for C2, as the Ag I complex C2 is too large in size to act as an intercalator. If Ag I is added to the NDI molecule that is already intercalated into a duplex, higher order complexes are formed within the DNA duplex and cause disruptions in the helical duplex structure, which leads to a significant decrease in the characteristic CD features of B-DNA. Thus, via addition of a metal we show how a classic and well-known organic intercalator unit can be turned into a partial metallo insertor. We also show how electrochemical impedance spectroscopy (EIS) can be used to probe DNA binding modes on DNA films that are immobilized on gold surfaces. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Waveguide resonance mode response of stacked structures of metallic sub-wavelength slit arrays
Tokuda, Yasunori; Takano, Keisuke; Sakaguchi, Koichiro; Kato, Kosaku; Nakajima, Makoto; Akiyama, Koichi
2018-05-01
Detailed measurements of the optical properties of two-tier systems composed of metallic plates perforated with periodic sub-wavelength slit patterns were carried out using terahertz time-domain spectroscopy. We demonstrate that the transmission properties observed experimentally for various configurations can be reproduced successfully by simulations based on the finite-differential time-domain method. Fabry-Perot-like waveguide resonance mode behaviors specific to this quasi-dielectric system were then investigated. For structures with no lateral displacement between the slit-array plates, mode disappearance phenomena, which are caused by destructive interference between the odd-order mode and the blue- or red-shifted even-order modes, were observed experimentally. The uncommon behavior of the even-order modes was examined precisely to explain the slit-width dependence. For structures with half-pitched displacement between the plates, extraordinarily strong transmission was observed experimentally, even when the optical paths were shut off. This result was interpreted in terms of the propagation of surface plasmon polaritons through very thin and labyrinthine spacings that inevitably exist between the metallic plates. Furthermore, the optical mode disappearance phenomena are revealed to be characterized by anticrossing of the two mixing modes formed by even- and odd-order modes. These experimental observations that are supported theoretically are indispensable to the practical use of this type of artificial dielectric and are expected to encourage interest in optical mode behaviors that are not typically observed in conventional dielectric systems.
Raman spectroscopy, ab-initio model calculations, and conformational, equilibria in ionic liquids
DEFF Research Database (Denmark)
Berg, Rolf W.
2009-01-01
spectroscopy and ab-initio molecular orbital calculations. A discussion is given, based mainly on some recent FT- Raman spectroscopic results on the model ionic liquid system of 1-butyl-3-methyl-imidazolium ([C4C1Im]+X-) salts. The rotational isomerism of the [C4C1Im]+ cation is described: the presence of anti.......3 Brief introduction to ab-initio model calculations .... 312 12.4 Case study on Raman spectroscopy and structure of imidazolium-based ionic liquids ..... 312 12.5 Raman spectra and structure of [C4C1Im]+ liquids ..... 315 12.6 Normal mode analysis and rotational isomerism of the [C4C1Im]+ cation...
Auger electron spectroscopy, ionization loss spectroscopy, appearance potential spectroscopy
International Nuclear Information System (INIS)
Riwan, R.
1973-01-01
The spectroscopy of surfaces using an incident electron beam is studied. The fundamental mechanisms are discussed together with the parameters involved in Auger emission: excitation of the atom, de-excitation by electron emission, and the migration of electrons towards the surface and their ejection. Some examples of applications are given (surface structures, metallurgy, chemical information). Two new techniques for analyzing surfaces are studied: ionization spectroscopy, and appearance potential spectroscopy [fr
Electron energy loss spectroscopy of gold nanoparticles on graphene
International Nuclear Information System (INIS)
DeJarnette, Drew; Roper, D. Keith
2014-01-01
Plasmon excitation decay by absorption, scattering, and hot electron transfer has been distinguished from effects induced by incident photons for gold nanoparticles on graphene monolayer using electron energy loss spectroscopy (EELS). Gold nano-ellipses were evaporated onto lithographed graphene, which was transferred onto a silicon nitride transmission electron microscopy grid. Plasmon decay from lithographed nanoparticles measured with EELS was compared in the absence and presence of the graphene monolayer. Measured decay values compared favorably with estimated radiative and non-radiative contributions to decay in the absence of graphene. Graphene significantly enhanced low-energy plasmon decay, increasing mode width 38%, but did not affect higher energy plasmon or dark mode decay. This decay beyond expected radiative and non-radiative mechanisms was attributed to hot electron transfer, and had quantum efficiency of 20%, consistent with previous reports
Spectroscopy of the earth's atmosphere and interstellar medium
Rao, KN
1992-01-01
Spectroscopy of the Earth's Atmosphere and Interstellar Medium focuses on the characteristics of the electromagnetic spectrum of the Earth's atmosphere in the far-infrared and microwave regions. It discusses the modes of observation in field measurements and reviews the two techniques used in the spectral region. Organized into six chapters, this volume begins with an overview of the effect of water-vapor absorption, followed by a discussion on the two frequently used method for deriving atmospheric parameters from high-resolution infrared atmospheric spectra, namely, the equivalent width
Nanoscale probing of bandgap states on oxide particles using electron energy-loss spectroscopy.
Liu, Qianlang; March, Katia; Crozier, Peter A
2017-07-01
Surface and near-surface electronic states were probed with nanometer spatial resolution in MgO and TiO 2 anatase nanoparticles using ultra-high energy resolution electron energy-loss spectroscopy (EELS) coupled to a scanning transmission electron microscope (STEM). This combination allows the surface electronic structure determined with spectroscopy to be correlated with nanoparticle size, morphology, facet etc. By acquiring the spectra in aloof beam mode, radiation damage to the surface can be significantly reduced while maintaining the nanometer spatial resolution. MgO and TiO 2 showed very different bandgap features associated with the surface/sub-surface layer of the nanoparticles. Spectral simulations based on dielectric theory and density of states models showed that a plateau feature found in the pre-bandgap region in the spectra from (100) surfaces of 60nm MgO nanocubes is consistent with a thin hydroxide surface layer. The spectroscopy shows that this hydroxide species gives rise to a broad filled surface state at 1.1eV above the MgO valence band. At the surfaces of TiO 2 nanoparticles, pronounced peaks were observed in the bandgap region, which could not be well fitted to defect states. In this case, the high refractive index and large particle size may make Cherenkov or guided light modes the likely causes of the peaks. Copyright © 2016 Elsevier B.V. All rights reserved.
PLC-based mode multi/demultiplexers for mode division multiplexing
Saitoh, Kunimasa; Hanzawa, Nobutomo; Sakamoto, Taiji; Fujisawa, Takeshi; Yamashita, Yoko; Matsui, Takashi; Tsujikawa, Kyozo; Nakajima, Kazuhide
2017-02-01
Recently developed PLC-based mode multi/demultiplexers (MUX/DEMUXs) for mode division multiplexing (MDM) transmission are reviewed. We firstly show the operation principle and basic characteristics of PLC-based MUX/DEMUXs with an asymmetric directional coupler (ADC). We then demonstrate the 3-mode (2LP-mode) multiplexing of the LP01, LP11a, and LP11b modes by using fabricated PLC-based mode MUX/DEMUX on one chip. In order to excite LP11b mode in the same plane, a PLC-based LP11 mode rotator is introduced. Finally, we show the PLC-based 6-mode (4LP-mode) MUX/DEMUX with a uniform height by using ADCs, LP11 mode rotators, and tapered waveguides. It is shown that the LP21a mode can be excited from the LP11b mode by using ADC, and the two nearly degenerated LP21b and LP02 modes can be (de)multiplexed separately by using tapered mode converter from E13 (E31) mode to LP21b (LP02) mode.
Intense Terahertz Sources for 2D Spectroscopy
DEFF Research Database (Denmark)
Pedersen, Pernille Klarskov
in a molecular dynamics (MD) simulation. With this THz induced nonlinear responses and mode couplings in CsI and sucrose are investigated for increasing field strengths, and it is found that these occur for sucrose when the field strength is in the MV/cm range. THz sources based on LiNbO3, DAST, DSTMS and 2...... observed having a Gaussian beam profile. In addition to the intense THz pulses focused in free-space in order to achieve the highest possible field strength, it is shown that resonant microslit arrays can be used to enhance the THz field, and with the possibility of mounting crystalline samples inside...... the metallic slits, this is proposed as a combined spectroscopy system for investigating high-field phenomena. With a carefully optimized design, the slit resonance can be coupled to the lattice modes of the array structure to achieve a field enhancement of more than 35 times, which is approximately 60 % more...
Raman spectroscopy of sputtered metal-graphene and metal-oxide-graphene interfaces
Chen, Ching-Tzu; Gajek, Marcin; Freitag, Marcus; Kuroda, Marcelo; Perebeinos, Vasili; Raoux, Simone
2012-02-01
In this talk, we report our recent development in sputtering deposition of magnetic and non-magnetic metal and metal-oxide thin films on graphene for applications in spintronics and nanoeleoctronics. TEM and SEM images demonstrate homogeneous coverage, uniform thickness, and good crystallinity of the sputtered films. Raman spectroscopy shows that the structure of the underlying graphene is well preserved, and the spectral weight of the defect D mode is comparable to that of the e-beam evaporated samples. Most significantly, we report the first observation of graphene-enhanced surface excitations of crystalline materials. Specifically, we discover two pronounced dispersive Raman modes at the interface of graphene and the nickel-oxide and cobalt-oxide films which we attribute to the strong light absorption and high-order resonant scattering process in the graphene layer. We will present the frequency-dependent, polarization-dependent Raman data of these two modes and discuss their microscopic origin.
Energy Technology Data Exchange (ETDEWEB)
Kaminski, K; Kaminska, E; Wlodarczyk, P; Adrjanowicz, K; Wojnarowska, Z; Grzybowska, K; Paluch, M [Institute of Physics, Silesian University, ulica Uniwersytecka 4, 40-007 Katowice (Poland)
2010-09-15
Broadband dielectric measurements performed on D-glucose, L-sorbose, D-fructose and D-galactose revealed that, except for the structural relaxation process, one can detect in the liquid phase of these carbohydrates a much slower relaxation mode. Recently we have demonstrated that in D-glucose this relaxation mode might be related to the long range correlation of density fluctuations (LRCDF), also called Fischer clusters (FC). Based on the dielectric data obtained for the four monosaccharides we were able to make a more general conclusion about the characteristic dielectric features of the slow mode in the whole family of carbohydrates. We found out that the timescale separation between structural and considered relaxation reaches up to six decades at the glass transition temperature and the dielectric strength decreases significantly with lowering temperature. Another very interesting feature of the slow process is that it can be described by an almost exponential response function. We have found out that the fragility of the slow process lies within the range m = 44-50. Finally, we have also shown that there is a close link between structural and slow relaxation.
Walker, S
1976-01-01
The three volumes of Spectroscopy constitute the one comprehensive text available on the principles, practice and applications of spectroscopy. By giving full accounts of those spectroscopic techniques only recently introduced into student courses - such as Mössbauer spectroscopy and photoelectron spectroscopy - in addition to those techniques long recognised as being essential in chemistry teaching - sucha as e.s.r. and infrared spectroscopy - the book caters for the complete requirements of undergraduate students and at the same time provides a sound introduction to special topics for graduate students.
Time-resolved single-shot terahertz time-domain spectroscopy for ultrafast irreversible processes
Zhai, Zhao-Hui; Zhong, Sen-Cheng; Li, Jun; Zhu, Li-Guo; Meng, Kun; Li, Jiang; Liu, Qiao; Peng, Qi-Xian; Li, Ze-Ren; Zhao, Jian-Heng
2016-09-01
Pulsed terahertz spectroscopy is suitable for spectroscopic diagnostics of ultrafast events. However, the study of irreversible or single shot ultrafast events requires ability to record transient properties at multiple time delays, i.e., time resolved at single shot level, which is not available currently. Here by angular multiplexing use of femtosecond laser pulses, we developed and demonstrated a time resolved, transient terahertz time domain spectroscopy technique, where burst mode THz pulses were generated and then detected in a single shot measurement manner. The burst mode THz pulses contain 2 sub-THz pulses, and the time gap between them is adjustable up to 1 ns with picosecond accuracy, thus it can be used to probe the single shot event at two different time delays. The system can detect the sub-THz pulses at 0.1 THz-2.5 THz range with signal to noise ratio (SNR) of ˜400 and spectrum resolution of 0.05 THz. System design was described here, and optimizations of single shot measurement of THz pulses were discussed in detail. Methods to improve SNR were also discussed in detail. A system application was demonstrated where pulsed THz signals at different time delays of the ultrafast process were successfully acquired within single shot measurement. This time resolved transient terahertz time domain spectroscopy technique provides a new diagnostic tool for irreversible or single shot ultrafast events where dynamic information can be extracted at terahertz range within one-shot experiment.
DEFF Research Database (Denmark)
Alstrøm, Tommy Sonne; Schmidt, Mikkel Nørgaard; Rindzevicius, Tomas
2017-01-01
Raman spectroscopy is a well-known analytical technique for identifying and analyzing chemical species. Since Raman scattering is a weak effect, surface-enhanced Raman spectroscopy (SERS) is often employed to amplify the signal. SERS signal surface mapping is a common method for detecting trace...... to directly and reliably identify the Raman modes, with overall performance similar to the state of the art non-negative matrix factorization approach. However, the model provides better interpretation and is a step towards enabling the use of SERS in detection of trace amounts of molecules in real-life...
International Nuclear Information System (INIS)
Hegde, M.S.
1979-01-01
An introduction to the various techniques in electron spectroscopy is presented. These techniques include: (1) UV Photoelectron spectroscopy, (2) X-ray Photoelectron spectroscopy, (3) Auger electron spectroscopy, (4) Electron energy loss spectroscopy, (5) Penning ionization spectroscopy and (6) Ion neutralization spectroscopy. The radiations used in each technique, the basis of the technique and the special information obtained in structure determination in atoms and molecules by each technique are summarised. (A.K.)
Flexible Microsphere-Embedded Film for Microsphere-Enhanced Raman Spectroscopy.
Xing, Cheng; Yan, Yinzhou; Feng, Chao; Xu, Jiayu; Dong, Peng; Guan, Wei; Zeng, Yong; Zhao, Yan; Jiang, Yijian
2017-09-27
Dielectric microspheres with extraordinary microscale optical properties, such as photonic nanojets, optical whispering-gallery modes (WGMs), and directional antennas, have drawn interest in many research fields. Microsphere-enhanced Raman spectroscopy (MERS) is an alternative approach for enhanced Raman detection by dielectric microstructures. Unfortunately, fabrication of microsphere monolayer arrays is the major challenge of MERS for practical applications on various specimen surfaces. Here we report a microsphere-embedded film (MF) by immersing a highly refractive microsphere monolayer array in the poly(dimethylsiloxane) (PDMS) film as a flexible MERS sensing platform for one- to three-dimensional (1D to 3D) specimen surfaces. The directional antennas and wave-guided whispering-gallery modes (WG-WGMs) contribute to the majority of Raman enhancement by the MFs. Moreover, the MF can be coupled with surface-enhanced Raman spectroscopy (SERS) to provide an extra >10-fold enhancement. The limit of detection is therefore improved for sensing of crystal violet (CV) and Sudan I molecules in aqueous solutions at concentrations down to 10 -7 M. A hybrid dual-layer microsphere enhancer, constructed by depositing a MF onto a microsphere monolayer array, is also demonstrated, wherein the WG-WGMs become dominant and boost the enhancement ratio >50-fold. The present work opens up new opportunities for design of cost-effective and flexible MERS sensing platforms as individual or associated techniques toward practical applications in ultrasensitive Raman detection.
Circular magnetoplasmonic modes in gold nanoparticles.
Pineider, Francesco; Campo, Giulio; Bonanni, Valentina; Fernández, César de Julián; Mattei, Giovanni; Caneschi, Andrea; Gatteschi, Dante; Sangregorio, Claudio
2013-10-09
The quest for efficient ways of modulating localized surface plasmon resonance is one of the frontiers in current research in plasmonics; the use of a magnetic field as a source of modulation is among the most promising candidates for active plasmonics. Here we report the observation of magnetoplasmonic modes on colloidal gold nanoparticles detected by means of magnetic circular dichroism (MCD) spectroscopy and provide a model that is able to rationalize and reproduce the experiment with unprecedented qualitative and quantitative accuracy. We believe that the steep slope observed at the plasmon resonance in the MCD spectrum can be very efficient in detecting changes in the refractive index of the surrounding medium, and we give a simple proof of principle of its possible implementation for magnetoplasmonic refractometric sensing.
International Nuclear Information System (INIS)
2011-01-01
Spectroscopy has played and is playing a very important role as it is one of the most efficient methods of molecular structure studies with the help of which direct information about the chemical compounds can be obtained. Spectroscopy has its contribution in a number of branches in areas such as medicine, industry, environment, agriculture, power, construction, forensic analysis (both criminal and civil cases), etc., where it has revolutionized the very face of these sectors. Vibrational spectroscopic (Infrared and Raman) techniques have demonstrated potential to provide non-destructive, rapid clinically relevant diagnostic information. Raman and infrared spectroscopy enable the biochemical signatures from biological tissues to be extracted and analyzed there by advancing the treatment of cancer. Advancement in instrumentation has allowed the development of numerous infrared and Raman spectroscopic methods. Infrared spectroscopy is tremendously used in the fields of pharmaceuticals. medical diagnostics food and agrochemical quality control, and combustion research. Raman spectroscopy is used in condensed matter physics, biomedicinal fields for tissue analysis and chemistry to study vibrational, rotational, and other low-frequency modes in a system. Keeping in mind the fast development: in the Spectroscopy, we have planned to organize a national level conference for 2 days on 'Exploring the Frontiers of Vibrational Spectroscopy' to bring out the tremendous potential of various Spectroscopic techniques available at the global level. Papers relevant to INIS are indexed separately
Is black-hole ringdown a memory of its progenitor?
Kamaretsos, Ioannis; Hannam, Mark; Sathyaprakash, B S
2012-10-05
We perform an extensive numerical study of coalescing black-hole binaries to understand the gravitational-wave spectrum of quasinormal modes excited in the merged black hole. Remarkably, we find that the masses and spins of the progenitor are clearly encoded in the mode spectrum of the ringdown signal. Some of the mode amplitudes carry the signature of the binary's mass ratio, while others depend critically on the spins. Simulations of precessing binaries suggest that our results carry over to generic systems. Using Bayesian inference, we demonstrate that it is possible to accurately measure the mass ratio and a proper combination of spins even when the binary is itself invisible to a detector. Using a mapping of the binary masses and spins to the final black-hole spin allows us to further extract the spin components of the progenitor. Our results could have tremendous implications for gravitational astronomy by facilitating novel tests of general relativity using merging black holes.
Spatial-mode switchable ring fiber laser based on low mode-crosstalk all-fiber mode MUX/DEMUX
Ren, Fang; Yu, Jinyi; Wang, Jianping
2018-05-01
We report an all-fiber ring laser that emits linearly polarized (LP) modes based on the intracavity all-fiber mode multiplexer/demultiplexer (MUX/DEMUX). Multiple LP modes in ring fiber laser are generated by taking advantage of mode MUX/DEMUX. The all-fiber mode MUX/DEMUX are composed of cascaded mode-selective couplers (MSCs). The output lasing mode of the ring fiber laser can be switched among the three lowest-order LP modes by employing combination of a mode MUX and a simple N × 1 optical switch. The slope efficiencies, optical spectra and mode profiles are measured.
System upgradation for surface mode negative ion beam extraction experiments in ROBIN
International Nuclear Information System (INIS)
Pandya, Kaushal; Bansal, Gourab; Soni, Jignesh
2015-01-01
ROBIN (Replica Of BATMAN source in India) is a replica of BATMAN source of IPP, Garching. Plasma production (inductively coupled, RF produced plasma), plasma diagnostic (langmuir probe, optical emission spectroscopy), negative ion beam extraction in volume mode with reduced extraction area of 2 cm 2 (4 apertures) using small bench top type power supply (10kV, 400mA), with increase extraction area of 73 cm 2 (146 apertures) and using actual power supplies (Extraction Power Supply System, EPSS (11kV, 35A), and Accelerator Power Supply System, APSS (35kV, 15A)) and beam diagnostic etc have been performed successfully in ROBIN. This paper will describe the details of the system upgradation for surface mode negative ion experiments and its performance in ROBIN
Fourier transform Raman spectroscopy of synthetic and biological calcium phosphates.
Sauer, G R; Zunic, W B; Durig, J R; Wuthier, R E
1994-05-01
Fourier-transform (FT) Raman spectroscopy was used to characterize the organic and mineral components of biological and synthetic calcium phosphate minerals. Raman spectroscopy provides information on biological minerals that is complimentary to more widely used infrared methodologies as some infrared-inactive vibrational modes are Raman-active. The application of FT-Raman technology has, for the first time, enabled the problems of high sample fluorescence and low signal-to-noise that are inherent in calcified tissues to be overcome. Raman spectra of calcium phosphates are dominated by a very strong band near 960 cm-1 that arises from the symmetric stretching mode (v1) of the phosphate group. Other Raman-active phosphate vibrational bands are seen at approximately 1075 (v3), 590 (v4), and 435 cm-1 (v2). Minerals containing acidic phosphate groups show additional vibrational modes. The different calcium phosphate mineral phases can be distinguished from one another by the relative positions and shapes of these bands in the Raman spectra. FT-Raman spectra of nascent, nonmineralized matrix vesicles (MV) show a distinct absence of the phosphate v1 band even though these structures are rich in calcium and phosphate. Similar results were seen with milk casein and synthetic Ca-phosphatidyl-serine-PO4 complexes. Hence, the phosphate and/or acidic phosphate ions in these noncrystalline biological calcium phosphates is in a molecular environment that differs from that in synthetic amorphous calcium phosphate. In MV, the first distinct mineral phase to form contained acidic phosphate bands similar to those seen in octacalcium phosphate. The mineral phase present in fully mineralized MV was much more apatitic, resembling that found in bones and teeth.(ABSTRACT TRUNCATED AT 250 WORDS)
Near-infrared-excited confocal Raman spectroscopy advances in vivo diagnosis of cervical precancer.
Duraipandian, Shiyamala; Zheng, Wei; Ng, Joseph; Low, Jeffrey J H; Ilancheran, Arunachalam; Huang, Zhiwei
2013-06-01
Raman spectroscopy is a unique optical technique that can probe the changes of vibrational modes of biomolecules associated with tissue premalignant transformation. This study evaluates the clinical utility of confocal Raman spectroscopy over near-infrared (NIR) autofluorescence (AF) spectroscopy and composite NIR AF/Raman spectroscopy for improving early diagnosis of cervical precancer in vivo at colposcopy. A rapid NIR Raman system coupled with a ball-lens fiber-optic confocal Raman probe was utilized for in vivo NIR AF/Raman spectral measurements of the cervix. A total of 1240 in vivo Raman spectra [normal (n=993), dysplasia (n=247)] were acquired from 84 cervical patients. Principal components analysis (PCA) and linear discriminant analysis (LDA) together with a leave-one-patient-out, cross-validation method were used to extract the diagnostic information associated with distinctive spectroscopic modalities. The diagnostic ability of confocal Raman spectroscopy was evaluated using the PCA-LDA model developed from the significant principal components (PCs) [i.e., PC4, 0.0023%; PC5, 0.00095%; PC8, 0.00022%, (p<0.05)], representing the primary tissue Raman features (e.g., 854, 937, 1095, 1253, 1311, 1445, and 1654 cm(-1)). Confocal Raman spectroscopy coupled with PCA-LDA modeling yielded the diagnostic accuracy of 84.1% (a sensitivity of 81.0% and a specificity of 87.1%) for in vivo discrimination of dysplastic cervix. The receiver operating characteristic curves further confirmed that the best classification was achieved using confocal Raman spectroscopy compared to the composite NIR AF/Raman spectroscopy or NIR AF spectroscopy alone. This study illustrates that confocal Raman spectroscopy has great potential to improve early diagnosis of cervical precancer in vivo during clinical colposcopy.
Hajiyev, Parviz; Cong, Chunxiao; Qiu, Caiyu; Yu, Ting
2013-01-01
In this article, we report the first successful preparation of single- and few-layers of tantalum diselenide (2H-TaSe2) by mechanical exfoliation technique. Number of layers is confirmed by white light contrast spectroscopy and atomic force microscopy (AFM). Vibrational properties of the atomically thin layers of 2H-TaSe2 are characterized by micro-Raman spectroscopy. Room temperature Raman measurements demonstrate MoS2-like spectral features, which are reliable for thickness determination. E1g mode, usually forbidden in backscattering Raman configuration is observed in the supported TaSe2 layers while disappears in the suspended layers, suggesting that this mode may be enabled because of the symmetry breaking induced by the interaction with the substrate. A systematic in-situ low temperature Raman study, for the first time, reveals the existence of incommensurate charge density wave phase transition in single and double-layered 2H-TaSe2 as reflected by a sudden softening of the second-order broad Raman mode resulted from the strong electron-phonon coupling (Kohn anomaly). PMID:24005335
Single-molecule electronics: Cooling individual vibrational modes by the tunneling current.
Lykkebo, Jacob; Romano, Giuseppe; Gagliardi, Alessio; Pecchia, Alessandro; Solomon, Gemma C
2016-03-21
Electronic devices composed of single molecules constitute the ultimate limit in the continued downscaling of electronic components. A key challenge for single-molecule electronics is to control the temperature of these junctions. Controlling heating and cooling effects in individual vibrational modes can, in principle, be utilized to increase stability of single-molecule junctions under bias, to pump energy into particular vibrational modes to perform current-induced reactions, or to increase the resolution in inelastic electron tunneling spectroscopy by controlling the life-times of phonons in a molecule by suppressing absorption and external dissipation processes. Under bias the current and the molecule exchange energy, which typically results in heating of the molecule. However, the opposite process is also possible, where energy is extracted from the molecule by the tunneling current. Designing a molecular "heat sink" where a particular vibrational mode funnels heat out of the molecule and into the leads would be very desirable. It is even possible to imagine how the vibrational energy of the other vibrational modes could be funneled into the "cooling mode," given the right molecular design. Previous efforts to understand heating and cooling mechanisms in single molecule junctions have primarily been concerned with small models, where it is unclear which molecular systems they correspond to. In this paper, our focus is on suppressing heating and obtaining current-induced cooling in certain vibrational modes. Strategies for cooling vibrational modes in single-molecule junctions are presented, together with atomistic calculations based on those strategies. Cooling and reduced heating are observed for two different cooling schemes in calculations of atomistic single-molecule junctions.
Energy loss, equilibration, and thermodynamics of a baryon rich strongly coupled quark-gluon plasma
Energy Technology Data Exchange (ETDEWEB)
Rougemont, Romulo [Instituto de Física, Universidade de São Paulo, Rua do Matão, 1371, Butantã, CEP 05508-090, São Paulo, SP (Brazil); Ficnar, Andrej [Rudolf Peierls Centre for Theoretical Physics, University of Oxford, 1 Keble Road, Oxford OX1 3NP (United Kingdom); Finazzo, Stefano I. [Instituto de Física, Universidade de São Paulo, Rua do Matão, 1371, Butantã, CEP 05508-090, São Paulo, SP (Brazil); Instituto de Física Teórica, Universidade do Estado de São Paulo, Rua Dr. Bento T. Ferraz, 271, CEP 01140-070, São Paulo, SP (Brazil); Noronha, Jorge [Instituto de Física, Universidade de São Paulo, Rua do Matão, 1371, Butantã, CEP 05508-090, São Paulo, SP (Brazil); Department of Physics, Columbia University, 538 West 120th Street, New York, NY 10027 (United States)
2016-04-15
Lattice data for the QCD equation of state and the baryon susceptibility near the crossover phase transition (at zero baryon density) are used to determine the input parameters of a 5-dimensional Einstein-Maxwell-Dilaton holographic model that provides a consistent holographic framework to study both equilibrium and out-of-equilibrium properties of a hot and baryon rich strongly coupled quark-gluon plasma (QGP). We compare our holographic equation of state computed at nonzero baryon chemical potential, μ{sub B}, with recent lattice calculations and find quantitative agreement for the pressure and the speed of sound for μ{sub B}≤400 MeV. This holographic model is used to obtain holographic predictions for the temperature and μ{sub B} dependence of the drag force and the Langevin diffusion coefficients associated with heavy quark jet propagation as well as the jet quenching parameter q̂ and the shooting string energy loss of light quarks in the baryon dense plasma. We find that the energy loss of heavy and light quarks generally displays a nontrivial, fast-varying behavior as a function of the temperature near the crossover. Moreover, energy loss is also found to generally increase due to nonzero baryon density effects even though this strongly coupled liquid cannot be described in terms of well defined quasiparticle excitations. Furthermore, to get a glimpse of how thermalization occurs in a hot and baryon dense QGP, we study how the lowest quasinormal mode of an external massless scalar disturbance in the bulk is affected by a nonzero baryon charge. We find that the equilibration time associated with the lowest quasinormal mode decreases in a dense medium.
Energy Technology Data Exchange (ETDEWEB)
Hellman, Hal
1968-01-01
This booklet discusses spectroscopy, the study of absorption of radiation by matter, including X-ray, gamma-ray, microwave, mass spectroscopy, as well as others. Spectroscopy has produced more fundamental information to the study of the detailed structure of matter than any other tools.
International Nuclear Information System (INIS)
1992-01-01
Our aim is to investigate, on the molecular level at a spatially resolved mode of operation, structure-activity relations of DNA and their sensitivity to ionizing radiation. This entails in-vitro (and later in-vivo) ultra-resolved microscopy, spectroscopy and chemical sensing, with non-destructive probing
Goldstone mode and pair-breaking excitations in atomic Fermi superfluids
Hoinka, Sascha; Dyke, Paul; Lingham, Marcus G.; Kinnunen, Jami J.; Bruun, Georg M.; Vale, Chris J.
2017-10-01
Spontaneous symmetry breaking is a central paradigm of elementary particle physics, magnetism, superfluidity and superconductivity. According to Goldstone's theorem, phase transitions that break continuous symmetries lead to the existence of gapless excitations in the long-wavelength limit. These Goldstone modes can become the dominant low-energy excitation, showing that symmetry breaking has a profound impact on the physical properties of matter. Here, we present a comprehensive study of the elementary excitations in a homogeneous strongly interacting Fermi gas through the crossover from a Bardeen-Cooper-Schrieffer (BCS) superfluid to a Bose-Einstein condensate (BEC) of molecules using two-photon Bragg spectroscopy. The spectra exhibit a discrete Goldstone mode, associated with the broken-symmetry superfluid phase, as well as pair-breaking single-particle excitations. Our techniques yield a direct determination of the superfluid pairing gap and speed of sound in close agreement with strong-coupling theories.
Charge transfer in carbon nanotube actuators investigated using in situ Raman spectroscopy
International Nuclear Information System (INIS)
Gupta, S.; Hughes, M.; Windle, A.H.; Robertson, J.
2004-01-01
Charge transfer dynamics on the surface of single-wall carbon nanotube sheets is investigated using in situ Raman spectroscopy in order to understand the actuation mechanism of an electrochemical actuator and to determine associated parameters. We built an actuator from single-wall carbon nanotube mat and studied its actuation in several alkali metal (Li, Na, and K) and alkaline earth (Ca) halide and sulfate solutions in order to clarify the role of counterion as mobile ions in the film. The variation of bonding with applied potential was monitored using in situ Raman spectroscopy. This is because Raman can detect changes in C-C bond length: the radial breathing mode at ∼190 cm-1 varies inversely with the nanotube diameter, and the G band at ∼1590 cm-1 varies with the axial bond length. In addition, the intensities of both the modes vary with the emptying/depleting or filling of the bonding and antibonding states due to electrochemical charge injection. We discussed the variation of peak height and wave numbers of these modes providing valuable information concerning electrochemical charge injection on the carbon nanotube mat surface. We found in-plane microscopic compressive strain (∼-0.25%) and the equivalent charge transfer per carbon atom (f c ∼-0.005) as an upper bound for the actuators studied hereby. It is demonstrated that though the present analysis does comply with the proposition for the actuation principle made earlier, the quantitative estimates are significantly lower if compared with those of reported values. Furthermore, the extent of variation, i.e., coupled electro-chemo-mechanical response of single-wall carbon nanotubes (SWNT) mat depended upon the type of counterion used (Group I versus Group II). The cyclic voltammetry and ac electrochemical impedance spectroscopy results were described briefly, which help to demonstrate well-developed capacitive behavior of SWNT mat and to estimate the specific capacitances as well. Summarizing, the
THz Time-Domain Spectroscopy of Interstellar Ice Analogs
Ioppolo, Sergio; McGuire, Brett A.; de Vries, Xander; Carroll, Brandon; Allodi, Marco; Blake, Geoffrey
2015-08-01
The unambiguous identification of nearly 200 molecular species in different astronomical environments proves that our cosmos is a ‘Molecular Universe’. The cumulative outcome of recent observations, laboratory studies, and astrochemical models indicates that there is a strong interplay between the gas and the solid phase throughout the process of forming molecules in space. Observations of interstellar ices are generally limited to lines-of-sight along which infrared absorption spectroscopy is possible. Therefore, the identification of more complex prebiotic molecules in the mid-IR is difficult because of their low expected interstellar abundances and the overlap of their absorption features with those from the more abundant species. In the THz region, telescopes can detect Interstellar ices in emission or absorption against dust continuum. Thus, THz searches do not require a background point source. Moreover, since THz spectra are the fingerprint of inter- and intramolecular forces, complex species can present unique modes that do not overlap with those from simpler, more abundant molecules. THz modes are also sensitive to temperature and phase changes in the ice. Therefore, spectroscopy at THz frequencies has the potential to better characterize the physics and chemistry of the ISM. Currently, the Herschel Space Telescope, SOFIA, and ALMA databases contain a vast amount of new THz spectral data that require THz laboratory spectra for interpretation. The latter, however, are largely lacking. We have recently constructed a new THz time-domain spectroscopy system operating in the range between 0.3 - 7.5 THz. This work focuses on the laboratory investigation of the composition and structure of the most abundant interstellar ice analogs compared to some more complex species. Different temperatures, mixing ratios, and matrix isolation experiments will be shown. The ultimate goal of this research is to provide the scientific community with an extensive THz ice
Miljanić, Snežana; Dijanošić, Adriana; Kalac, Matea; Radić Stojković, Marijana; Piantanida, Ivo; Pawlica, Dariusz; Eilmes, Julita
2012-01-01
Binding modes of a dibenzotetraaza14annulene (DBTAA) derivative with synthetic nucleic acids were studied using surface-enhanced Raman spectroscopy (SERS). Changes in SERS intensity and appearance of new bands in spectra were attributed to different complexes formed between the DBTAA molecules and DNA/RNA polynucleotides. A decrease in intensity pointed to intercalation as the dominant binding mode of the annulene derivative with poly dGdC-poly dGdC and poly rA-poly rU, whereas new bands in...
Late-time dynamics of rapidly rotating black holes
International Nuclear Information System (INIS)
Glampedakis, K.; Andersson, N.
2001-01-01
We study the late-time behaviour of a dynamically perturbed rapidly rotating black hole. Considering an extreme Kerr black hole, we show that the large number of virtually undamped quasinormal modes (that exist for nonzero values of the azimuthal eigenvalue m) combine in such a way that the field (as observed at infinity) oscillates with an amplitude that decays as 1/t at late times. For a near extreme black hole, these modes, collectively, give rise to an exponentially decaying field which, however, is considerably 'long-lived'. Our analytic results are verified using numerical time-evolutions of the Teukolsky equation. Moreover, we argue that the physical mechanism behind the observed behaviour is the presence of a 'superradiance resonance cavity' immediately outside the black hole. We present this new feature in detail, and discuss whether it may be relevant for astrophysical black holes. (author)
Li, Yingmin; Wang, Jiaxi; Clark, Melissa L.; Kubiak, Clifford P.; Xiong, Wei
2016-04-01
We report the first fourth-order 3D SFG spectroscopy of a monolayer of the catalyst Re(diCN-bpy)(CO)3Cl on a gold surface. Besides measuring the vibrational coherences of single vibrational modes, the fourth-order 3D SFG spectrum also measures the dynamics of interstate coherences and vibrational coherences states between two vibrational modes. By comparing the 3D SFG to the corresponding 2D and third-order 3D IR spectroscopy of the same molecules in solution, we found that the interstate coherences exist in both liquid and surface systems, suggesting that the interstate coherence is not disrupted by surface interactions. However, by analyzing the 3D spectral lineshape, we found that the interstate coherences also experience non-negligible homogenous dephasing dynamics that originate from surface interactions. This unique ability of determining interstate vibrational coherence dynamics of the molecular monolayer can help in understanding of how energy flows within surface catalysts and other molecular monolayers.
A spectroelectrochemical cell for ultrafast two-dimensional infrared spectroscopy
Energy Technology Data Exchange (ETDEWEB)
El Khoury, Youssef; Van Wilderen, Luuk J. G. W.; Vogt, Tim; Winter, Ernst; Bredenbeck, Jens, E-mail: bredenbeck@biophysik.uni-frankfurt.org, E-mail: bredenbeck@biophysik.uni-frankfurt.de [Institut für Biophysik, Johann Wolfgang Goethe-Universität, Max-von-Laue-Strasse 1, 60438 Frankfurt (Germany)
2015-08-15
A spectroelectrochemical cell has been designed to combine electrochemistry and ultrafast two-dimensional infrared (2D-IR) spectroscopy, which is a powerful tool to extract structure and dynamics information on the femtosecond to picosecond time scale. Our design is based on a gold mirror with the dual role of performing electrochemistry and reflecting IR light. To provide the high optical surface quality required for laser spectroscopy, the gold surface is made by electron beam evaporation on a glass substrate. Electrochemical cycling facilitates in situ collection of ultrafast dynamics of redox-active molecules by means of 2D-IR. The IR beams are operated in reflection mode so that they travel twice through the sample, i.e., the signal size is doubled. This methodology is optimal for small sample volumes and successfully tested with the ferricyanide/ferrocyanide redox system of which the corresponding electrochemically induced 2D-IR difference spectrum is reported.
Use of FT-NIR Spectroscopy for Bovine Colostrum Analysis
Directory of Open Access Journals (Sweden)
P. Navrátilová
2006-01-01
Full Text Available Fourier transformation near infrared spectroscopy (FT-NIR in combination with partial least squares (PLS method were used to determine the content of total solids, fat, non-fatty solids, lactose and proteins in bovine colostrum. Spectra of 90 samples were measured in the reflectance mode with a transflectance cuvette in the 10000-4000 cm-1 spectral ranges with 100 scans. Calibration was performed and statistical values of correlation coefficients (R and standard error of calibration values (SEC were computed for total solids (0.986 and 0.919, respectively, fat (0.997 and 0.285, respectively, non-fatty solids (0.995 and 0.451, respectively, lactose (0.934 and 0.285, respectively and protein (0.999 and 0.149, respectively. The calibration models developed were verified by cross validation. It follows from the study that FT-NIR spectroscopy can be used to determine the components of bovine colostrum.
A spectroelectrochemical cell for ultrafast two-dimensional infrared spectroscopy
International Nuclear Information System (INIS)
El Khoury, Youssef; Van Wilderen, Luuk J. G. W.; Vogt, Tim; Winter, Ernst; Bredenbeck, Jens
2015-01-01
A spectroelectrochemical cell has been designed to combine electrochemistry and ultrafast two-dimensional infrared (2D-IR) spectroscopy, which is a powerful tool to extract structure and dynamics information on the femtosecond to picosecond time scale. Our design is based on a gold mirror with the dual role of performing electrochemistry and reflecting IR light. To provide the high optical surface quality required for laser spectroscopy, the gold surface is made by electron beam evaporation on a glass substrate. Electrochemical cycling facilitates in situ collection of ultrafast dynamics of redox-active molecules by means of 2D-IR. The IR beams are operated in reflection mode so that they travel twice through the sample, i.e., the signal size is doubled. This methodology is optimal for small sample volumes and successfully tested with the ferricyanide/ferrocyanide redox system of which the corresponding electrochemically induced 2D-IR difference spectrum is reported
Czech Academy of Sciences Publication Activity Database
Kamba, Stanislav; Simon, Elizabeth; Skoromets, Volodymyr; Bovtun, Viktor; Kempa, Martin; Pokorný, Jan; Savinov, Maxim; Koruza, J.; Malič, B.
2016-01-01
Roč. 89, č. 7-8 (2016), s. 785-793 ISSN 0141-1594 R&D Projects: GA MŠk(CZ) LD15014 Institutional support: RVO:68378271 Keywords : Dielectric spectroscopy * lead- free piezoelectrics * soft mode * central mode * phonons * polar nanoregions * infrared * terahertz * Raman spectroscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.060, year: 2016
DEFF Research Database (Denmark)
Mah, Pei T.; Fraser, Sara J.; Reish, Matthew E.
2015-01-01
in stored amorphous samples earlier than the mid-frequency 785 nm Raman system. Overall, this study suggests that low-frequency Raman spectroscopy has at least equally good performance compared to mid-frequency Raman for quantitative analysis of crystallinity in the pharmaceutical setting. More generally......Low-frequency Raman spectroscopy, which directly probes phonon lattice modes of crystal structures, has much unexplored potential for sensitive qualitative and quantitative analysis of crystallinity in drugs and excipients. In this study, the level of crystallinity in tablets containing amorphous...
Collective modes in CuxTiSe2 measured with meV-resolution EELS
Rak, Melinda; Vig, Sean; Husain, Ali; Mitrano, Matteo; Rubeck, Samantha; Kogar, Anshul; Karapetrov, Goran; Morosan, Emilia; Abbamonte, Peter
The charge density wave (CDW) in 1 T-TiSe2 has been widely thought to be the result of an excitonic insulator transition. We recently observed a soft electronic mode in TiSe2 using a new, momentum-resolved electron energy loss spectroscopy (M-EELS) technique, demonstrating a condensation of electron-hole pairs in this material. As TiSe2 is doped with Cu to produce CuxTiSe2, a superconducting dome emerges above x ˜ 0.04. In this talk, I describe how the electronic collective mode evolves with Cu doping. We find that the temperature dependence of the electronic mode reverses as Cu is introduced and that the mode is much broader at low temperature as compared to the undoped material. Additionally, the electronic mode no longer has a positive dispersion at 300 K as described by the Lindhard function, but has a slightly negative dispersion for small momentum transfers. We will discuss the implications of these results for the excitonic insulator transition in TiSe2. This work was supported by the Gordon and Betty Moore Foundation's EPiQS Initiative through Grant GBMF4542. An early prototype of the M-EELS instrument was supported by the DOE Center for Emergent Superconductivity under Award No. DE-AC02-98CH10886.
Vibrational Spectroscopy of Intramolecular Hydrogen Bonds in the Infrared and Near-Infrared Regions
DEFF Research Database (Denmark)
Schrøder, Sidsel Dahl
and 1,4-diaminobutane). Experimentally, the hydrogen bonds have been studied with vibrational spectroscopy in the infrared and near-infrared regions. The focus is primarily on spectra recorded in the near-infrared regions, which in these studies are dominated by O-H and N-H stretching overtones....... Overtone spectra have been recorded with intracavity laser photoacoustic laser spectroscopy and conventional long path absorption spectroscopy. Theoretically, a combination of electronic structure calculations and local mode models have been employed to guide the assignment of bands in the vibrational......,4-diaminobutane, no sign of intramolecular N-H···N hydrogen bonds were identified in the overtone spectra. However, theoretical analyzes indicate that intramolecular N-H···N hydrogen bonds are present in all three diamines if two hydrogen atoms on one of the methylene groups are substituted with triuoromethyl...
Sidabras, Jason W; Varanasi, Shiv K; Mett, Richard R; Swarts, Steven G; Swartz, Harold M; Hyde, James S
2014-10-01
A microwave Surface Resonator Array (SRA) structure is described for use in Electron Paramagnetic Resonance (EPR) spectroscopy. The SRA has a series of anti-parallel transmission line modes that provides a region of sensitivity equal to the cross-sectional area times its depth sensitivity, which is approximately half the distance between the transmission line centers. It is shown that the quarter-wave twin-lead transmission line can be a useful element for design of microwave resonators at frequencies as high as 10 GHz. The SRA geometry is presented as a novel resonator for use in surface spectroscopy where the region of interest is either surrounded by lossy material, or the spectroscopist wishes to minimize signal from surrounding materials. One such application is in vivo spectroscopy of human finger-nails at X-band (9.5 GHz) to measure ionizing radiation dosages. In order to reduce losses associated with tissues beneath the nail that yield no EPR signal, the SRA structure is designed to limit depth sensitivity to the thickness of the fingernail. Another application, due to the resonator geometry and limited depth penetration, is surface spectroscopy in coating or material science. To test this application, a spectrum of 1.44 μM of Mg(2+) doped polystyrene 1.1 mm thick on an aluminum surface is obtained. Modeling, design, and simulations were performed using Wolfram Mathematica (Champaign, IL; v. 9.0) and Ansys High Frequency Structure Simulator (HFSS; Canonsburg, PA; v. 15.0). A micro-strip coupling circuit is designed to suppress unwanted modes and provide a balanced impedance transformation to a 50 Ω coaxial input. Agreement between simulated and experimental results is shown.
Energy Technology Data Exchange (ETDEWEB)
Sidabras, Jason W.; Varanasi, Shiv K.; Hyde, James S. [Department of Biophysics, Medical College of Wisconsin, Milwaukee, Wisconsin 53211 (United States); Mett, Richard R. [Department of Biophysics, Medical College of Wisconsin, Milwaukee, Wisconsin 53211 (United States); Department of Physics and Chemistry, Milwaukee School of Engineering, Milwaukee, Wisconsin 53202 (United States); Swarts, Steven G. [Department of Radiation Oncology, University of Florida, Gainesville, Florida, 32610 (United States); Swartz, Harold M. [Department of Radiology, Geisel Medical School at Dartmouth, Hanover, New Hampshire 03755 (United States)
2014-10-15
A microwave Surface Resonator Array (SRA) structure is described for use in Electron Paramagnetic Resonance (EPR) spectroscopy. The SRA has a series of anti-parallel transmission line modes that provides a region of sensitivity equal to the cross-sectional area times its depth sensitivity, which is approximately half the distance between the transmission line centers. It is shown that the quarter-wave twin-lead transmission line can be a useful element for design of microwave resonators at frequencies as high as 10 GHz. The SRA geometry is presented as a novel resonator for use in surface spectroscopy where the region of interest is either surrounded by lossy material, or the spectroscopist wishes to minimize signal from surrounding materials. One such application is in vivo spectroscopy of human finger-nails at X-band (9.5 GHz) to measure ionizing radiation dosages. In order to reduce losses associated with tissues beneath the nail that yield no EPR signal, the SRA structure is designed to limit depth sensitivity to the thickness of the fingernail. Another application, due to the resonator geometry and limited depth penetration, is surface spectroscopy in coating or material science. To test this application, a spectrum of 1.44 μM of Mg{sup 2+} doped polystyrene 1.1 mm thick on an aluminum surface is obtained. Modeling, design, and simulations were performed using Wolfram Mathematica (Champaign, IL; v. 9.0) and Ansys High Frequency Structure Simulator (HFSS; Canonsburg, PA; v. 15.0). A micro-strip coupling circuit is designed to suppress unwanted modes and provide a balanced impedance transformation to a 50 Ω coaxial input. Agreement between simulated and experimental results is shown.
Assessment of the amide-I local modes in gamma- and beta-turns of peptides.
Wang, Jianping
2009-07-14
The amide-I local modes, mainly the C[double bond, length as m-dash]O stretching vibrations, form the structural basis of femtosecond 2D IR spectroscopy in characterizing backbone structures and dynamics of peptides and proteins. In this work, a density functional theory (DFT) level of computational assessment of the amide-I local modes in oligomers mostly in the turn conformations was carried out. It is shown that local mode properties, including transition frequencies and transition dipole magnitudes and orientations, are slightly conformational dependent. However, the distributions of these properties in the peptide oligomers are narrow and have mean values almost identical to those from an isolated peptide monomer, justifying the prevalent use of a uniform local mode in modeling the 1D and 2D IR spectra. In addition, it is shown that the transition dipole magnitude and orientation of the peptide monomer predicted by the DFT calculations can be well approximated by electrostatic potential-based transition charge schemes, e.g. Merz-Singh-Kollman, CHELP, as well as CHELPG.
Chevalier, Paul; Piccardo, Marco; Anand, Sajant; Mejia, Enrique A.; Wang, Yongrui; Mansuripur, Tobias S.; Xie, Feng; Lascola, Kevin; Belyanin, Alexey; Capasso, Federico
2018-02-01
Free-running Fabry-Perot lasers normally operate in a single-mode regime until the pumping current is increased beyond the single-mode instability threshold, above which they evolve into a multimode state. As a result of this instability, the single-mode operation of these lasers is typically constrained to few percents of their output power range, this being an undesired limitation in spectroscopy applications. In order to expand the span of single-mode operation, we use an optical injection seed generated by an external-cavity single-mode laser source to force the Fabry-Perot quantum cascade laser into a single-mode state in the high current range, where it would otherwise operate in a multimode regime. Utilizing this approach, we achieve single-mode emission at room temperature with a tuning range of 36 cm-1 and stable continuous-wave output power exceeding 1 W at 4.5 μm. Far-field measurements show that a single transverse mode is emitted up to the highest optical power, indicating that the beam properties of the seeded Fabry-Perot laser remain unchanged as compared to free-running operation.
Hall, David S; Lockwood, David J; Poirier, Shawn; Bock, Christina; MacDougall, Barry R
2012-06-28
The present work utilizes Raman and infrared (IR) spectroscopy, supported by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) to re-examine the fine structural details of Ni(OH)(2), which is a key material in many energy-related applications. This work also unifies the large body of literature on the topic. Samples were prepared by the galvanostatic basification of nickel salts and by aging the deposits in hot KOH solutions. A simplified model is presented consisting of two fundamental phases (α and β) of Ni(OH)(2) and a range of possible structural disorder arising from factors such as impurities, hydration, and crystal defects. For the first time, all of the lattice modes of β-Ni(OH)(2) have been identified and assigned using factor group analysis. Ni(OH)(2) films can be rapidly identified in pure and mixed samples using Raman or IR spectroscopy by measuring their strong O-H stretching modes, which act as fingerprints. Thus, this work establishes methods to measure the phase, or phases, and disorder at a Ni(OH)(2) sample surface and to correlate desired chemical properties to their structural origins.
Scattering of particles by deformed non-rotating black holes
International Nuclear Information System (INIS)
Pei, Guancheng; Bambi, Cosimo
2015-01-01
We study the excitation of axial quasi-normal modes of deformed non-rotating black holes by test particles and we compare the associated gravitational wave signal with that expected in general relativity from a Schwarzschild black hole. Deviations from standard predictions are quantified by an effective deformation parameter, which takes into account deviations from both the Schwarzschild metric and the Einstein equations. We show that, at least in the case of non-rotating black holes, it is possible to test the metric around the compact object, in the sense that the measurement of the gravitational wave spectrum can constrain possible deviations from the Schwarzschild solution. (orig.)
Strong cosmic censorship in de Sitter space
Dias, Oscar J. C.; Eperon, Felicity C.; Reall, Harvey S.; Santos, Jorge E.
2018-05-01
Recent work indicates that the strong cosmic censorship hypothesis is violated by nearly extremal Reissner-Nordström-de Sitter black holes. It was argued that perturbations of such a black hole decay sufficiently rapidly that the perturbed spacetime can be extended across the Cauchy horizon as a weak solution of the equations of motion. In this paper we consider the case of Kerr-de Sitter black holes. We find that, for any nonextremal value of the black hole parameters, there are quasinormal modes which decay sufficiently slowly to ensure that strong cosmic censorship is respected. Our analysis covers both scalar field and linearized gravitational perturbations.
Frequency and mode identification of γ Doradus from photometric and spectroscopic observations*
Brunsden, E.; Pollard, K. R.; Wright, D. J.; De Cat, P.; Cottrell, P. L.
2018-04-01
The prototype star for the γ Doradus class of pulsating variables was studied employing photometric and spectroscopic observations to determine the frequencies and modes of pulsation. The four frequencies found are self-consistent between the observation types and almost identical to those found in previous studies (1.3641 d-1, 1.8783 d-1, 1.4742 d-1, and 1.3209 d-1). Three of the frequencies are classified as l, m = (1, 1) pulsations and the other is ambiguous between l, m = (2, 0) and (2, -2) modes. Two frequencies are shown to be stable over 20 yr since their first identification. The agreement in ground-based work makes this star an excellent calibrator between high-precision photometry and spectroscopy with the upcoming TESS observations and a potential standard for continued asteroseismic modelling.
Directory of Open Access Journals (Sweden)
Ran Li
2016-07-01
Full Text Available Reissner–Nordström Anti-de Sitter (RNAdS black holes are unstable against the charged scalar field perturbations due to the well-known superradiance phenomenon. We present the time domain analysis of charged scalar field perturbations in the RNAdS black hole background in general dimensions. We show that the instabilities of charged scalar field can be explicitly illustrated from the time profiles of evolving scalar field. By using the Prony method to fit the time evolution data, we confirm the mode that dominates the long time behavior of scalar field is in accordance with the quasinormal mode from the frequency domain analysis. The superradiance origin of the instability can also be demonstrated by comparing the real part of the dominant mode with the superradiant condition of charged scalar field. It is shown that all the unstable modes are superradiant, which is consistent with the analytical result in the frequency domain analysis. Furthermore, we also confirm there exists the rapid exponential growing modes in the RNAdS case, which makes the RNAdS black hole a good test ground to investigate the nonlinear evolution of superradiant instability.
Infrared-emission spectroscopy of CO on Ni
International Nuclear Information System (INIS)
Chiang, S.; Tobin, R.G.; Richards, P.L.
1982-09-01
We report the first observation of thermally emitted infrared radiation from vibrational modes of molecules adsorbed on clean, single-crystal metal surfaces. The observation of emission from CO adsorbed on Ni demonstrates the surface sensitivity of a novel apparatus for infrared vibrational spectroscopy, with a resolution of 1 to 15 cm -1 over the frequency range from 330 to 3000 cm -1 . A liquid-helium-cooled grating spectrometer measures the thermal radiation from a room-temperature, single-crystal sample, which is mounted in an ultrahigh-vacuum system. Measurements of frequencies and linewidths of CO on a single-crystal Ni sample, as a function of coverage, are discussed
New multicore low mode noise scrambling fiber for applications in high-resolution spectroscopy
Haynes, Dionne M.; Gris-Sanchez, Itandehui; Ehrlich, Katjana; Birks, Tim A.; Giannone, Domenico; Haynes, Roger
2014-07-01
We present a new type of multicore fiber (MCF) and photonic lantern that consists of 511 individual cores designed to operate over a broadband visible wavelength range (380-860nm). It combines the coupling efficiency of a multimode fiber with modal stability intrinsic to a single mode fibre. It is designed to provide phase and amplitude scrambling to achieve a stable near field and far field illumination pattern during input coupling variations; it also has low modal noise for increased photometric stability. Preliminary results are presented for the new MCF as well as current state of the art octagonal fiber for comparison.
Energy Technology Data Exchange (ETDEWEB)
Chase, Hilary M.; Chen, Shunli; Fu, Li; Upshur, Mary Alice; Rudshteyn, Benjamin; Thomson, Regan J.; Wang, Hong-Fei; Batista, Victor S.; Geiger, Franz M.
2017-09-01
Inferring molecular orientations from vibrational sum frequency generation (SFG) spectra is challenging in polarization combinations that result in low signal intensities, or when the local point group symmetry approximation fails. While combining experiments with density functional theory (DFT) could overcome this problem, the scope of the combined method has yet to be established. Here, we assess its feasibility of determining the distributions of molecular orientations for one monobasic ester, two epoxides and three alcohols at the vapor/fused silica interface. We find that molecular orientations of nonlocal vibrational modes cannot be determined using polarization-resolved SFG measurements alone.
Growth and Raman spectroscopy studies of gold-free catalyzed semiconductor nanowires
Energy Technology Data Exchange (ETDEWEB)
Zardo, Ilaria
2010-12-15
The present Ph.D. thesis proposes two aims: the search for catalysts alternative to gold for the growth of silicon nanowires and the investigation of the structural properties of the gold-free catalyzed Si, Ge, and GaAs nanowires. The successful growth of gold free catalyzed silicon nanowires was obtained using Ga and In as catalyst. Hydrogen plasma conditions were needed during the growth process. We proposed a growth mechanism where the role of the hydrogen plasma is taken into account. The influence of the growth conditions on nanowire growth morphology and structural properties was investigated in detail. The TEM studies showed the occurrence of different kind of twin defects depending on the nanowire growth direction. The intersection of twins in different spatial directions in <111>-oriented nanowires or the periodicity of highly dense twins in <112>-oriented nanowires leads to the formation of hexagonal domains embedded in the diamond silicon structure. A simple crystallographic model which illustrates the formation of the hexagonal phase was proposed. The presence of the hexagonal domains embedded in the diamond silicon structure was investigated also by means of Raman spectroscopy. The measured frequencies of the E2g and A1g modes were found to be in agreement with frequencies expected from phonon dispersion folding. An estimation of the percentage of hexagonal structure with respect to the cubic structure was given. The relative percentage of the two structures was found to change with growth temperature. Spatially resolved Raman scattering experiments were also realized on single Si nanowires. The lattice dynamics of gold-free catalyzed Ge and GaAs nanowires was studied by means of Raman spectroscopy. We performed spatially resolved Raman spectroscopy experiments on single crystalline- amorphous core-shell Ge nanowires. The correlation with TEM studies on nanowires grown under the same conditions and with AFM measurements realized of the same nanowires
Photodissociation spectroscopy of the Mg + -CO2 complex and its isotopic analogs
Yeh, C. S.; Willey, K. F.; Robbins, D. L.; Pilgrim, J. S.; Duncan, M. A.
1993-02-01
Mg+-CO2 ion-molecule cluster complexes are produced by laser vaporization in a pulsed nozzle cluster source. The vibronic spectroscopy in these complexes is studied with mass-selected photodissociation spectroscopy in a reflectron time-of-flight mass spectrometer. Two excited electronic states are observed (2) 2Σ+ and 2Π. The 2Π state has a vibrational progression in the metal-CO2 stretching mode (ωe'=381.8 cm-1). The complexes are linear (Mg+-OCO) and are bound by the charge-quadrupole interaction. The dissociation energy (D0`) is 14.7 kcal/mol. Corresponding spectra are measured for each of the 24, 25, and 26 isotopes of magnesium. These results are compared to theoretical predictions made by Bauschlicher and co-workers.
Energy Technology Data Exchange (ETDEWEB)
Li, Jiawei; Huang, Wenhua [Department of Electronic Engineering and Information Science, University of Science and Technology of China, Hefei 230027 (China); Science and Technology on High Power Microwave Laboratory, Northwest Institute of Nuclear Technology, Xi' an 710024 (China); Xiao, Renzhen; Bai, Xianchen; Zhang, Yuchuan; Zhang, Xiaowei; Shao, Hao; Chen, Changhua [Science and Technology on High Power Microwave Laboratory, Northwest Institute of Nuclear Technology, Xi' an 710024 (China); Zhu, Qi [Department of Electronic Engineering and Information Science, University of Science and Technology of China, Hefei 230027 (China)
2015-03-16
A dual-cavity TM{sub 02}–TM{sub 01} mode converter is designed for a dual-mode operation over-moded relativistic backward-wave oscillator. With the converter, the fundamental mode output is achieved. Particle-in-cell simulation shows that the efficiency of beam-wave conversion was over 46% and a pureTM{sub 01} mode output was obtained. Effects of end reflection provided by the mode converter were studied. Adequate TM{sub 01} mode feedback provided by the converter enhances conversion efficiency. The distance between the mode converter and extraction cavity critically affect the generation of microwaves depending on the reflection phase of TM{sub 01} mode feedback.
International Nuclear Information System (INIS)
Li, Jiawei; Huang, Wenhua; Xiao, Renzhen; Bai, Xianchen; Zhang, Yuchuan; Zhang, Xiaowei; Shao, Hao; Chen, Changhua; Zhu, Qi
2015-01-01
A dual-cavity TM 02 –TM 01 mode converter is designed for a dual-mode operation over-moded relativistic backward-wave oscillator. With the converter, the fundamental mode output is achieved. Particle-in-cell simulation shows that the efficiency of beam-wave conversion was over 46% and a pureTM 01 mode output was obtained. Effects of end reflection provided by the mode converter were studied. Adequate TM 01 mode feedback provided by the converter enhances conversion efficiency. The distance between the mode converter and extraction cavity critically affect the generation of microwaves depending on the reflection phase of TM 01 mode feedback
Ultra-high Q terahertz whispering-gallery modes in a silicon resonator
Vogt, Dominik Walter; Leonhardt, Rainer
2018-05-01
We report on the first experimental demonstration of terahertz (THz) whispering-gallery modes (WGMs) with an ultra-high quality factor of 1.5 × 104 at 0.62 THz. The WGMs are observed in a high resistivity float zone silicon spherical resonator coupled to a sub-wavelength silica waveguide. A detailed analysis of the coherent continuous wave THz spectroscopy measurements combined with a numerical model based on Mie-Debye-Aden-Kerker theory allows us to unambiguously identify the observed higher order radial THz WGMs.
Single-mode fiber laser based on core-cladding mode conversion.
Suzuki, Shigeru; Schülzgen, Axel; Peyghambarian, N
2008-02-15
A single-mode fiber laser based on an intracavity core-cladding mode conversion is demonstrated. The fiber laser consists of an Er-doped active fiber and two fiber Bragg gratings. One Bragg grating is a core-cladding mode converter, and the other Bragg grating is a narrowband high reflector that selects the lasing wavelength. Coupling a single core mode and a single cladding mode by the grating mode converter, the laser operates as a hybrid single-mode laser. This approach for designing a laser cavity provides a much larger mode area than conventional large-mode-area step-index fibers.
Effect of modes interaction on the resistive wall mode stability
International Nuclear Information System (INIS)
Chen Longxi; Wu Bin
2013-01-01
Effects of modes interaction on the resistive wall mode (RWM) stability are studied. When considering the modes interaction effects, the linear growth rate of the most unstable (3, 1) mode decreases. After linear evolution, the RWM saturates at the nonlinear phase. The saturation can be attributed to flux piling up on the resistive wall. When some modes exist, the (3, 1) mode saturates at lower level compared with single mode evolution. Meanwhile, the magnetic energy of the (5, 2) mode increases correspondingly, but the magnetic energy saturation level of the (2, 1) mode changes weakly. (authors)
Ding, Edwin; Lefrancois, Simon; Kutz, Jose Nathan; Wise, Frank W
2011-01-01
The mode-locking of dissipative soliton fiber lasers using large mode area fiber supporting multiple transverse modes is studied experimentally and theoretically. The averaged mode-locking dynamics in a multi-mode fiber are studied using a distributed model. The co-propagation of multiple transverse modes is governed by a system of coupled Ginzburg-Landau equations. Simulations show that stable and robust mode-locked pulses can be produced. However, the mode-locking can be destabilized by excessive higher-order mode content. Experiments using large core step-index fiber, photonic crystal fiber, and chirally-coupled core fiber show that mode-locking can be significantly disturbed in the presence of higher-order modes, resulting in lower maximum single-pulse energies. In practice, spatial mode content must be carefully controlled to achieve full pulse energy scaling. This paper demonstrates that mode-locking performance is very sensitive to the presence of multiple waveguide modes when compared to systems such as amplifiers and continuous-wave lasers.
Arslanov, D.D.; Spunei, M.; Ngai, A.K.Y.; Cristescu, S.M.; Lindsay, I.D.; Lindsay, I.D.; Boller, Klaus J.; Persijn, S.T.; Harren, F.J.M.
2011-01-01
A fiber-amplified Distributed Bragg Reflector diode laser is used to pump a continuous wave, singly resonant Optical Parametric Oscillator (OPO). The output radiation covers the 3–4 μm with ability of rapid (100 THz/s) and broad mode-hop-free tuning (5 cm−1). Wavelength Modulation Spectroscopy is
International Nuclear Information System (INIS)
Adrian, H.
1981-01-01
The influence of crystal defects on the phonon spectra was studied for fcc lead using superconducting tunneling spectroscopy. The theory predicts low frequency modes for the vibrational states of interstitials in (100) dumbbell configuration. Low temperature irradiation of superconducting point contacts with fast ions (point contact thickness small compared to the average ion range) showed radiation-induced structures in the low-energy part of the Eliashberg function for lead. These resonant modes are reduced by annealing at 18.5 K; they are attributed to small interstitial clusters. The radiation-induced structures are completely removed by room temperature annealing. (orig.)
International Nuclear Information System (INIS)
Burrell, K.H.; Gohil, P.; Groebner, R.J.; Kaplan, D.H.; Robinson, J.I.; Solomon, W.M.
2004-01-01
Charge exchange spectroscopy is one of the key ion diagnostics on the DIII-D tokamak. It allows determination of ion temperature, poloidal and toroidal velocity, impurity density, and radial electric field E r throughout the plasma. For the 2003 experimental campaign, we replaced the intensified photodiode array detectors on the central portion of the DIII-D charge exchange spectroscopy system with advanced charge-coupled device (CCD) detectors mounted on faster (f/4.7) Czerny-Turner spectrometers equipped with toroidal mirrors. The CCD detectors are improved versions of the ones installed on our edge system in 1999. The combination improved the photoelectron signal level by about a factor of 20 and the signal to noise by a factor of 2-8, depending on the absolute signal level. The new cameras also allow shorter minimum integration times while archiving to PC memory: 0.552 ms for the slower, lower-read noise (15 e) readout mode and 0.274 ms in the faster, higher-read noise (30 e) mode
High spatial and temporal resolution charge exchange recombination spectroscopy on the HL-2A tokamak
Energy Technology Data Exchange (ETDEWEB)
Wei, Y. L.; Yu, D. L., E-mail: yudl@swip.ac.cn; Liu, L.; Cao, J. Y.; Sun, A. P.; Ma, Q.; Chen, W. J.; Liu, Yi; Yan, L. W.; Yang, Q. W.; Duan, X. R.; Liu, Yong [Southwestern Institute of Physics, Chengdu 610041 (China); Ida, K. [National Institute for Fusion Science, Toki 509-5292 (Japan); Hellermann, M. von [ITER Diagnostic Team, IO, Route de Vinon sur Verdon, 13115 St Paul lez Durance (France); FOM-Institute for Plasma physics “Rijnhuizen,” Association EURATOM, Trilateral Euregio Cluster, 3430 BE Nieuwegein (Netherlands)
2014-10-01
A 32/64-channel charge exchange recombination spectroscopy (CXRS) diagnostic system is developed on the HL-2A tokamak (R = 1.65 m, a = 0.4 m), monitoring plasma ion temperature and toroidal rotation velocity simultaneously. A high throughput spectrometer (F/2.8) and a pitch-controlled fiber bundle enable the temporal resolution of the system up to 400 Hz. The observation geometry and an optimized optic system enable the highest radial resolution up to ~1 cm at the plasma edge. The CXRS system monitors the carbon line emission (C VI, n = 8–7, 529.06 nm) whose Doppler broadening and Doppler shift provide ion temperature and plasma rotation velocity during the neutral beam injection. The composite CX spectral data are analyzed by the atomic data and analysis structure charge exchange spectroscopy fitting (ADAS CXSFIT) code. First experimental results are shown for the case of HL-2A plasmas with sawtooth oscillations, electron cyclotron resonance heating, and edge transport barrier during the high-confinement mode (H-mode)
Raman analysis of phonon modes in a short period AlN/GaN superlattice
Sarkar, Ketaki; Datta, Debopam; Gosztola, David J.; Shi, Fengyuan; Nicholls, Alan; Stroscio, Michael A.; Dutta, Mitra
2018-03-01
AlN/GaN-based optoelectronic devices have been the subject of intense research underlying the commercialization of efficient devices. Areas of considerable interest are the study of their lattice dynamics, phonon transport, and electron-phonon interactions specific to the interface of these heterostructures which results in additional optical phonon modes known as interface phonon modes. In this study, the framework of the dielectric continuum model (DCM) has been used to compare and analyze the optical phonon modes obtained from experimental Raman scattering measurements on AlN/GaN short-period superlattices. We have observed the localized E2(high), A1(LO) and the E1(TO) modes in superlattice measurements at frequencies shifted from their bulk values. To the best of our knowledge, the nanostructures used in these studies are among the smallest yielding useful Raman signatures for the interface modes. In addition, we have also identified an additional spread of interface phonon modes in the TO range resulting from the superlattice periodicity. The Raman signature contribution from the underlying AlxGa1-xN ternary has also been observed and analyzed. A temperature calibration was done based on Stokes/anti-Stokes ratio of A1(LO) using Raman spectroscopy in a broad operating temperature range. Good agreement between the experimental results and theoretically calculated calibration plot predicted using Bose-Einstein statistics was obtained.
International Nuclear Information System (INIS)
Ooi, C. H. Raymond
2009-01-01
Nonlinear spectroscopy using coherent anti-Stokes Raman scattering and femtosecond laser pulses has been successfully developed as powerful tools for chemical analysis and biological imaging. Recent developments show promising possibilities of incorporating CARS into LIDAR system for remote detection of molecular species in airborne particles. The corresponding theory is being developed to describe nonlinear scattering of a mesoscopic particle composed of complex molecules by laser pulses with arbitrary shape and spectral content. Microscopic many-body transform theory is used to compute the third order susceptibility for CARS in molecules with known absorption spectrum and vibrational modes. The theory is combined with an integral scattering formula and Mie-Lorentz formulae, giving a rigorous formalism which provides powerful numerical experimentation of CARS spectra, particularly on the variations with the laser parameters and the direction of detection.
DEFF Research Database (Denmark)
Jepsen, Peter Uhd
2009-01-01
In this presentation I will review methods for spectroscopy in the THz range, with special emphasis on the practical implementation of the technique known ad THz time-domain spectroscopy (THz-TDS). THz-TDS has revived the old field of far-infrared spectroscopy, and enabled a wealth of new...... activities that promise commercial potential for spectroscopic applications in the THz range. This will be illustrated with examples of spectroscopy of liquids inside their bottles as well as sensitive, quantitative spectroscopy in waveguides....
Double pulse laser ablation and plasma: Laser induced breakdown spectroscopy signal enhancement
International Nuclear Information System (INIS)
Babushok, V.I.; DeLucia, F.C.; Gottfried, J.L.; Munson, C.A.; Miziolek, A.W.
2006-01-01
A review of recent results of the studies of double laser pulse plasma and ablation for laser induced breakdown spectroscopy applications is presented. The double pulse laser induced breakdown spectroscopy configuration was suggested with the aim of overcoming the sensitivity shortcomings of the conventional single pulse laser induced breakdown spectroscopy technique. Several configurations have been suggested for the realization of the double pulse laser induced breakdown spectroscopy technique: collinear, orthogonal pre-spark, orthogonal pre-heating and dual pulse crossed beam modes. In addition, combinations of laser pulses with different wavelengths, different energies and durations were studied, thus providing flexibility in the choice of wavelength, pulse width, energy and pulse sequence. The double pulse laser induced breakdown spectroscopy approach provides a significant enhancement in the intensity of laser induced breakdown spectroscopy emission lines up to two orders of magnitude greater than a conventional single pulse laser induced breakdown spectroscopy. The double pulse technique leads to a better coupling of the laser beam with the plasma plume and target material, thus providing a more temporally effective energy delivery to the plasma and target. The experimental results demonstrate that the maximum effect is obtained at some optimum separation delay time between pulses. The optimum value of the interpulse delay depends on several factors, such as the target material, the energy level of excited states responsible for the emission, and the type of enhancement process considered. Depending on the specified parameter, the enhancement effects were observed on different time scales ranging from the picosecond time level (e.g., ion yield, ablation mass) up to the hundred microsecond level (e.g., increased emission intensity for laser induced breakdown spectroscopy of submerged metal target in water). Several suggestions have been proposed to explain
Energy Technology Data Exchange (ETDEWEB)
Kharlamova, M.V.; Kramberger, C.; Mittelberger, A. [University of Vienna, Faculty of Physics, Vienna (Austria)
2017-04-15
In the present work, the doping effect of terbium chloride, terbium bromide, and terbium iodide on single-walled carbon nanotubes (SWCNTs) was compared by Raman spectroscopy. A precise investigation of the doping-induced alterations of the Raman modes of the filled SWCNTs was conducted. The shifts of the components of the Raman modes and modification of their profiles allowed concluding that the inserted terbium halogenides have acceptor doping effect on the SWCNTs, and the doping efficiency increases in the line with terbium iodide, terbium bromide, and terbium chloride. (orig.)
International Nuclear Information System (INIS)
Gonzalo, A B; Rosa, M I de la; Perez, C; Mar, S; Gruetzmacher, K
2004-01-01
We report on quantitative measurements of ground-state atomic hydrogen densities in a stationary plasma far off thermodynamic equilibrium, generated in a hollow cathode discharge, by two-photon polarization spectroscopy via the 1S-2S transition. Absolute densities are obtained using a well established calibration method based on the non-resonant two-photon polarization signal of xenon gas at room temperature, which serves as the reference at the wavelength of the hydrogen transition. This study is dedicated to demonstrating the capability of two-photon polarization spectroscopy close to the detection limit. Therefore, it requires single-longitudinal mode UV-laser radiation provided by an advanced UV-laser spectrometer
Electron spin resonance modes in a strong-leg ladder in the Tomonaga-Luttinger liquid phase
Ozerov, M.; Maksymenko, M.; Wosnitza, J.; Honecker, A.; Landee, C. P.; Turnbull, M. M.; Furuya, S. C.; Giamarchi, T.; Zvyagin, S. A.
2015-12-01
Magnetic excitations in the strong-leg quantum spin ladder compound (C7H10N) 2CuBr4 (known as DIMPY) in the field-induced Tomonaga-Luttinger spin-liquid phase are studied by means of high-field electron spin resonance (ESR) spectroscopy. The presence of a gapped ESR mode with unusual nonlinear frequency-field dependence is revealed experimentally. Using a combination of analytic and exact-diagonalization methods, we compute the dynamical structure factor and identify this mode with longitudinal excitations in the antisymmetric channel. We argue that these excitations constitute a fingerprint of the spin dynamics in a strong-leg spin-1/2 Heisenberg antiferromagnetic ladder and owe their ESR observability to the uniform Dzyaloshinskii-Moriya interaction.
Methane penetration in DIII-D ELMing H-mode plasmas
International Nuclear Information System (INIS)
West, W.P.; Lasnier, C.J.; Whyte, D.G.; Isler, R.C.; Evans, T.E.; Jackson, G.L.; Rudakov, D.; Wade, M.R.; Strachan, J.
2003-01-01
Carbon penetration into the core plasma during midplane and divertor methane puffing has been measured for DIII-D ELMing H-mode plasmas. The methane puffs are adjusted to a measurable signal, but global plasma parameters are only weakly affected (line average density, e > increases by E , drops by 6+ density profiles in the core measured as a function of time using charge exchange recombination spectroscopy. The methane penetration factor is defined as the difference in the core content with the puff on and puff off, divided by the carbon confinement time and the methane puffing rate. In ELMing H-mode discharges with ion ∇B drift direction into the X-point, increasing the line averaged density from 5 to 8x10 19 m -3 dropped the penetration factor from 6.6% to 4.6% for main chamber puffing. The penetration factor for divertor puffing was below the detection limit (<1%). Changing the ion ∇B drift to away from the X-point decreased the penetration factor by more than a factor of five for main chamber puffing
Raman spectroscopy of triolein under high pressures
Tefelski, D. B.; Jastrzębski, C.; Wierzbicki, M.; Siegoczyński, R. M.; Rostocki, A. J.; Wieja, K.; Kościesza, R.
2010-03-01
This article presents results of the high pressure Raman spectroscopy of triolein. Triolein, a triacylglyceride (TAG) of oleic acid, is an unsaturated fat, present in natural oils such as olive oil. As a basic food component and an energy storage molecule, it has considerable importance for food and fuel industries. To generate pressure in the experiment, we used a high-pressure cylindrical chamber with sapphire windows, presented in (R.M. Siegoczyński, R. Kościesza, D.B. Tefelski, and A. Kos, Molecular collapse - modification of the liquid structure induced by pressure in oleic acid, High Press. Res. 29 (2009), pp. 61-66). Pressure up to 750 MPa was applied. A Raman spectrometer in "macro"-configuration was employed. Raman spectroscopy provides information on changes of vibrational modes related to structural changes of triolein under pressure. Interesting changes in the triglyceride C‒H stretching region at 2650-3100 cm-1 were observed under high-pressures. Changes were also observed in the ester carbonyl (C˭ O) stretching region 1700-1780 cm-1 and the C‒C stretching region at 1050-1150 cm-1. The overall luminescence of the sample decreased under pressure, making it possible to set longer spectrum acquisition time and obtain more details of the spectrum. The registered changes suggest that the high-pressure solid phase of triolein is organized as β-polymorphic, as was reported in (C. Akita, T. Kawaguchi, and F. Kaneko, Structural study on polymorphism of cis-unsaturated triacylglycerol: Triolein, J. Phys. Chem. B 110 (2006), pp. 4346-4353; E. Da Silva and D. Rousseau, Molecular order and thermodynamics of the solid-liquid transition in triglycerides via Raman spectroscopy, Phys. Chem. Chem. Phys. 10 (2008), pp. 4606-4613) (with temperature-induced phase transitions). The research has shown that Raman spectroscopy in TAGs under pressure reveals useful information about its structural changes.
Jobst, Markus A; Milles, Lukas F; Schoeler, Constantin; Ott, Wolfgang; Fried, Daniel B; Bayer, Edward A; Gaub, Hermann E; Nash, Michael A
2015-10-31
Receptor-ligand pairs are ordinarily thought to interact through a lock and key mechanism, where a unique molecular conformation is formed upon binding. Contrary to this paradigm, cellulosomal cohesin-dockerin (Coh-Doc) pairs are believed to interact through redundant dual binding modes consisting of two distinct conformations. Here, we combined site-directed mutagenesis and single-molecule force spectroscopy (SMFS) to study the unbinding of Coh:Doc complexes under force. We designed Doc mutations to knock out each binding mode, and compared their single-molecule unfolding patterns as they were dissociated from Coh using an atomic force microscope (AFM) cantilever. Although average bulk measurements were unable to resolve the differences in Doc binding modes due to the similarity of the interactions, with a single-molecule method we were able to discriminate the two modes based on distinct differences in their mechanical properties. We conclude that under native conditions wild-type Doc from Clostridium thermocellum exocellulase Cel48S populates both binding modes with similar probabilities. Given the vast number of Doc domains with predicted dual binding modes across multiple bacterial species, our approach opens up new possibilities for understanding assembly and catalytic properties of a broad range of multi-enzyme complexes.
International Nuclear Information System (INIS)
Siciliani de Cumis, M; D’Amato, F; Viciani, S; Patrizi, B; Foggi, P; Galea, C L
2013-01-01
We demonstrate the possibility of a quantitative analysis of the concentration of several dioxins and furans, among the most toxic ones, by only using infrared absorption laser spectroscopy. Two broadly tunable quantum cascade lasers, emitting in the mid-infrared, have been used to measure the absorption spectra of dioxins and furans, dissolved in CCl 4 , in direct absorption mode. The minimum detectable concentrations are inferred by analyzing diluted samples. A comparison between this technique and standard Fourier transform spectroscopy has been carried out and an analysis of future perspectives is reported. (paper)
Mork, Steven W.; Miller, C. Cameron; Philips, Laura A.
1992-09-01
The high resolution infrared spectrum of 1,2-difluoroethane (DFE) in a molecular beam has been obtained over the 2978-2996 cm-1 spectral region. This region corresponds to the symmetric combination of asymmetric C-H stretches in DFE. Observed rotational fine structure indicates that this C-H stretch is undergoing vibrational mode coupling to a single dark mode. The dark mode is split by approximately 19 cm-1 due to tunneling between the two identical gauche conformers. The mechanism of the coupling is largely anharmonic with a minor component of B/C plane Coriolis coupling. Effects of centrifugal distortion along the molecular A-axis are also observed. Analysis of the fine structure identifies the dark state as being composed of C-C torsion, CCF bend, and CH2 rock. Coupling between the C-H stretches and the C-C torsion is of particular interest because DFE has been observed to undergo vibrationally induced isomerization from the gauche to trans conformer upon excitation of the C-H stretch.
PENENTUAN BAHAN KERING BUAH SAWO SECARA TIDAK MERUSAK MENGGUNAKAN NIR SPECTROSCOPY
Directory of Open Access Journals (Sweden)
Diding Suhandy
2012-12-01
Full Text Available This work was conducted to develop a new measuring system for nondestructive dry matter prediction in sawo fruit using short wavelength near infrared (SW-NIR spectroscopy. In this research, a number of 100 sawo fruits were used as samples. Spectra were acquired using a portable spectrometer (VIS-NIR USB4000, The Ocean Optics, USA with 100 ms integration time and 50 scans for number of scanning. Dry matter was measured using oven drying. The calibration and validation model was developed using the partial least squares (PLS regression method. The result showed that the best calibration model could be developed for original spectra in the wavelength range of 700-990 nm with F= 8, r = 0.92, SEC = 0.68 and SEP = 0.86. Keywords: Absorbance mode, dry matter, nondestructive method, sawo fruit, SW-NIR spectroscopy.
Numerical analysis of dynamic force spectroscopy using the torsional harmonic cantilever
International Nuclear Information System (INIS)
Solares, Santiago D; Hoelscher, Hendrik
2010-01-01
A spectral analysis method has been recently introduced by Stark et al (2002 Proc. Natl Acad. Sci. USA 99 8473-8) and implemented by Sahin et al (2007 Nat. Nanotechnol. 2 507-14) using a T-shaped cantilever design, the torsional harmonic cantilever (THC), which is capable of performing simultaneous tapping-mode atomic force microscopy imaging and force spectroscopy. Here we report on numerical simulations of the THC system using a simple dual-mass flexural-torsional model, which is applied in combination with Fourier data processing software to illustrate the spectroscopy process for quality factors corresponding to liquid, air and vacuum environments. We also illustrate the acquisition of enhanced topographical images and deformed surface contours under the application of uniform forces, and compare the results to those obtained with a previously reported linear dual-spring-mass model.
Vibrational Spectroscopy on Photoexcited Dye-Sensitized Films via Pump-Degenerate Four-Wave Mixing.
Abraham, Baxter; Fan, Hao; Galoppini, Elena; Gundlach, Lars
2018-03-01
Molecular sensitization of semiconductor films is an important technology for energy and environmental applications including solar energy conversion, photocatalytic hydrogen production, and water purification. Dye-sensitized films are also scientifically complex and interesting systems with a long history of research. In most applications, photoinduced heterogeneous electron transfer (HET) at the molecule/semiconductor interface is of critical importance, and while great progress has been made in understanding HET, many open questions remain. Of particular interest is the role of combined electronic and vibrational effects and coherence of the dye during HET. The ultrafast nature of the process, the rapid intramolecular vibrational energy redistribution, and vibrational cooling present complications in the study of vibronic coupling in HET. We present the application of a time domain vibrational spectroscopy-pump-degenerate four-wave mixing (pump-DFWM)-to dye-sensitized solid-state semiconductor films. Pump-DFWM can measure Raman-active vibrational modes that are triggered by excitation of the sample with an actinic pump pulse. Modifications to the instrument for solid-state samples and its application to an anatase TiO 2 film sensitized by a Zn-porphyrin dye are discussed. We show an effective combination of experimental techniques to overcome typical challenges in measuring solid-state samples with laser spectroscopy and observe molecular vibrations following HET in a picosecond time window. The cation spectrum of the dye shows modes that can be assigned to the linker group and a mode that is localized on the Zn-phorphyrin chromophore and that is connected to photoexcitation.
Ultra-broadband THz time-domain spectroscopy of common polymers using THz air photonics
DEFF Research Database (Denmark)
D’Angelo, Francesco; Mics, Zoltán; Bonn, Mischa
2014-01-01
-domain spectrometer employing air-photonics for the generation and detection of single-cycle sub-50 fs THz transients. The time domain measurements provide direct access to both the absorption and refractive index spectra. The polymers LDPE and TOPAS® demonstrate negligible absorption and spectrally-flat refractive...... index across the entire spectroscopy window, revealing the high potential of these polymers for applications in THz photonics such as ultra-broadband polymer-based dielectric mirrors, waveguides, and fibers. Resonant high-frequency polar vibrational modes are observed and assigned in polymers PA6...... and PTFE, and their dielectric functions in the complete frequency window 2-15 THz are theoretically reproduced. Our results demonstrate the potential of ultrabroadband air-photonics-based THz time domain spectroscopy as a valuable analytic tool for materials science....
International Nuclear Information System (INIS)
Vieira, M.M.F.
1985-01-01
Vibrational-rotational overtones absorption solid hydrogens (H 2 , D 2 , HD) is studied using pulsed laser piezoeletric transducer (PULPIT) optoacoustic spectroscopy is studied. A general downward shift in energy from isolated molecular energies is observed. Studying normal-hydrogen it was observed that the phonon excitations associated with double-molecular transitions are predominantly transverse-optical phonons, whereas the excitations associated with single-molecular transitions are predominantly longitudinal - optical phonons. Multiplet structures were observed for certain double transitions in parahydrogen and orthodeuterium. The HD spectrum, besides presenting the sharp zero-phonon lines and the associated phonon side bands, like H 2 and D 2 , showed also two different features. This observation was common to all the transitions involving pure rotational excitation in H 2 and D 2 , which showed broad linewidths. This, together with some other facts (fluorescence lifetime *approx*10 5 sec; weak internal vibration and lattice coupling), led to the proposition of a mechanism for the fast nonradiative relaxation in solid hydrogens, implied from some observed experimental evidences. This relaxation, due to strong coupling, would happen in two steps: the internal vibration modes would relax to the rotational modes of the molecules, and then this rotational modes would relax to the lattice vibration modes. (Author) [pt
Authentication Sensing System Using Resonance Evaluation Spectroscopy (ASSURES)
Trolinger, James D.; Dioumaev, Andrei K.; Lal, Amit K.; Dimas, Dave
2017-08-01
This paper describes an ongoing instrument development project to distinguish genuine manufactured components from counterfeit components; we call the instrument ASSURES (Authentication Sensing System Using Resonance Evaluation Spectroscopy). The system combines Laser Doppler Vibrometry with acoustical resonance spectroscopy, augmented with finite element analysis. Vibrational properties of components, such as resonant modes, damping, and spectral frequency response to various forcing functions depend strongly upon the mechanical properties of the material, including its size, shape, internal hardness, tensile strength, alloy/composite compositions, flaws, defects, and other internal material properties. Although acoustic resonant spectroscopy has seen limited application, the information rich signals in the vibrational spectra of objects provide a pathway to many new applications. Components with the same shape but made of different materials, different fatigue histories, damage, tampering, or heat treatment, will respond differently to high frequency stimulation. Laser Doppler Vibrometry offers high sensitivity and frequency bandwidth to measure the component's frequency spectrum, and overcomes many issues that limit conventional acoustical resonance spectroscopy, since the sensor laser beam can be aimed anywhere along the part as well as to multiple locations on a part in a non-contact way. ASSURES is especially promising for use in additive manufacturing technology by providing signatures as digital codes that are unique to specific objects and even to specific locations on objects. We believe that such signatures can be employed to address many important issues in the manufacturing industry. These include insuring the part meets the often very rigid specifications of the customer and being able to detect non-visible internal manufacturing defects or non-visible damage that has occurred after manufacturing.
Superradiance and black hole bomb in five-dimensional minimal ungauged supergravity
Energy Technology Data Exchange (ETDEWEB)
Aliev, Alikram N., E-mail: alikram.n.aliev@gmail.com [Faculty of Engineering and Architecture, Yeni Yüzyıl University, Cevizlibağ-Topkapı, Istanbul, 34010 Turkey (Turkey)
2014-11-01
We examine the black hole bomb model which consists of a rotating black hole of five-dimenensional minimal ungauged supergravity and a reflecting mirror around it. For low-frequency scalar perturbations, we find solutions to the Klein-Gordon equation in the near-horizon and far regions of the black hole spacetime. To avoid solutions with logarithmic terms, we assume that the orbital quantum number l takes on nearly, but not exactly, integer values and perform the matching of these solutions in an intermediate region. This allows us to calculate analytically the frequency spectrum of quasinormal modes, taking the limits as l approaches even or odd integers separately. We find that all l modes of scalar perturbations undergo negative damping in the regime of superradiance, resulting in exponential growth of their amplitudes. Thus, the model under consideration would exhibit the superradiant instability, eventually behaving as a black hole bomb in five dimensions.
On Born approximation in black hole scattering
Batic, D.; Kelkar, N. G.; Nowakowski, M.
2011-12-01
A massless field propagating on spherically symmetric black hole metrics such as the Schwarzschild, Reissner-Nordström and Reissner-Nordström-de Sitter backgrounds is considered. In particular, explicit formulae in terms of transcendental functions for the scattering of massless scalar particles off black holes are derived within a Born approximation. It is shown that the conditions on the existence of the Born integral forbid a straightforward extraction of the quasi normal modes using the Born approximation for the scattering amplitude. Such a method has been used in literature. We suggest a novel, well defined method, to extract the large imaginary part of quasinormal modes via the Coulomb-like phase shift. Furthermore, we compare the numerically evaluated exact scattering amplitude with the Born one to find that the approximation is not very useful for the scattering of massless scalar, electromagnetic as well as gravitational waves from black holes.
Evolution of perturbations of squashed Kaluza-Klein black holes: Escape from instability
International Nuclear Information System (INIS)
Ishihara, Hideki; Kimura, Masashi; Konoplya, Roman A.; Murata, Keiju; Soda, Jiro; Zhidenko, Alexander
2008-01-01
The squashed Kaluza-Klien (KK) black holes differ from the Schwarzschild black holes with asymptotic flatness or the black strings even at energies for which the KK modes are not excited yet, so that squashed KK black holes open a window in higher dimensions. Another important feature is that the squashed KK black holes are apparently stable and, thereby, let us avoid the Gregory-Laflamme instability. In the present paper, the evolution of scalar and gravitational perturbations in time and frequency domains is considered for these squashed KK black holes. The scalar field perturbations are analyzed for general rotating squashed KK black holes. Gravitational perturbations for the so-called zero mode are shown to be decayed for nonrotating black holes, in concordance with the stability of the squashed KK black holes. The correlation of quasinormal frequencies with the size of extra dimension is discussed.
Curvature perturbations from dimensional decoupling
Giovannini, Massimo
2005-01-01
The scalar modes of the geometry induced by dimensional decoupling are investigated. In the context of the low energy string effective action, solutions can be found where the spatial part of the background geometry is the direct product of two maximally symmetric Euclidean manifolds whose related scale factors evolve at a dual rate so that the expanding dimensions first accelerate and then decelerate while the internal dimensions always contract. After introducing the perturbative treatment of the inhomogeneities, a class of five-dimensional geometries is discussed in detail. Quasi-normal modes of the system are derived and the numerical solution for the evolution of the metric inhomogeneities shows that the fluctuations of the internal dimensions provide a term that can be interpreted, in analogy with the well-known four-dimensional situation, as a non-adiabatic pressure density variation. Implications of this result are discussed with particular attention to string cosmological scenarios.
Sub-terahertz resonance spectroscopy of biological macromolecules and cells
Globus, Tatiana; Moyer, Aaron; Gelmont, Boris; Khromova, Tatyana; Sizov, Igor; Ferrance, Jerome
2013-05-01
Recently we introduced a Sub-THz spectroscopic system for characterizing vibrational resonance features from biological materials. This new, continuous-wave, frequency-domain spectroscopic sensor operates at room temperature between 315 and 480 GHz with spectral resolution of at least 1 GHz and utilizes the source and detector components from Virginia Diode, Inc. In this work we present experimental results and interpretation of spectroscopic signatures from bacterial cells and their biological macromolecule structural components. Transmission and absorption spectra of the bacterial protein thioredoxin, DNA and lyophilized cells of Escherichia coli (E. coli), as well as spores of Bacillus subtillis and B. atrophaeus have been characterized. Experimental results for biomolecules are compared with absorption spectra calculated using molecular dynamics simulation, and confirm the underlying physics for resonance spectroscopy based on interactions between THz radiation and vibrational modes or groups of modes of atomic motions. Such interactions result in multiple intense and narrow specific resonances in transmission/absorption spectra from nano-gram samples with spectral line widths as small as 3 GHz. The results of this study indicate diverse relaxation dynamic mechanisms relevant to sub-THz vibrational spectroscopy, including long-lasting processes. We demonstrate that high sensitivity in resolved specific absorption fingerprints provides conditions for reliable detection, identification and discrimination capability, to the level of strains of the same bacteria, and for monitoring interactions between biomaterials and reagents in near real-time. Additionally, it creates the basis for the development of new types of advanced biological sensors through integrating the developed system with a microfluidic platform for biomaterial samples.
High-coherence mid-infrared dual-comb spectroscopy spanning 2.6 to 5.2 μm
Ycas, Gabriel; Giorgetta, Fabrizio R.; Baumann, Esther; Coddington, Ian; Herman, Daniel; Diddams, Scott A.; Newbury, Nathan R.
2018-04-01
Mid-infrared dual-comb spectroscopy has the potential to supplant conventional Fourier-transform spectroscopy in applications requiring high resolution, accuracy, signal-to-noise ratio and speed. Until now, mid-infrared dual-comb spectroscopy has been limited to narrow optical bandwidths or low signal-to-noise ratios. Using digital signal processing and broadband frequency conversion in waveguides, we demonstrate a mid-infrared dual-comb spectrometer covering 2.6 to 5.2 µm with comb-tooth resolution, sub-MHz frequency precision and accuracy, and a spectral signal-to-noise ratio as high as 6,500. As a demonstration, we measure the highly structured, broadband cross-section of propane from 2,840 to 3,040 cm-1, the complex phase/amplitude spectra of carbonyl sulfide from 2,000 to 2,100 cm-1, and of a methane, acetylene and ethane mixture from 2,860 to 3,400 cm-1. The combination of broad bandwidth, comb-mode resolution and high brightness will enable accurate mid-infrared spectroscopy in precision laboratory experiments and non-laboratory applications including open-path atmospheric gas sensing, process monitoring and combustion.
Niemantsverdriet, J.W.; Butz, Tilman; Ertl, G.; Knözinger, H.; Schüth, F.
2008-01-01
No abstract. The sections in this article are 1 Introduction 2 Mössbauer Spectroscopy 3 Time-Differential Perturbed Angular Correlations (TDPAC) 4 Conclusions and Outlook Keywords: Mössbauer spectroscopy; gamma spectroscopy; perturbed angular correlation; TDPAC
Laser spectroscopy on a ''shoestring''
International Nuclear Information System (INIS)
Camparo, J.C.; Klimcak, C.M.
1983-01-01
The advent of tunable lasers has had a profound influence on both experimental and theoretical physics. Unfortunately, since these laser systems are typically hazardous and expensive, the physics student at the undergraduate or first-year graduate level has no real familiarity with their application in modern physics; and thus cannot fully appreciate their significance. Tunable single mode laser diodes, however, may offer a remedy to this situation. To demonstrate their applicability, we have designed a relatively simple and inexpensive experiment of laser diode spectroscopy in an atomic beam which illustrates the effect of hyperfine structure and the isotope shift in the rubidium D 1 transition (5 2 S/sub 1/2/-5 2 P/sub 1/2/). Furthermore, this experiment demonstrates the possibility of investigating basic physics without major expenditures for laser systems and laboratory facilities
Investigation of optical pump on dielectric tunability in PZT/PT thin film by THz spectroscopy.
Ji, Jie; Luo, Chunya; Rao, Yunkun; Ling, Furi; Yao, Jianquan
2016-07-11
The dielectric spectra of single-layer PbTiO3 (PT), single-layer PbZrxTi1-xO3 (PZT) and multilayer PZT/PT thin films under an external optical field were investigated at room temperature by time-domain terahertz (THz) spectroscopy. Results showed that the real part of permittivity increased upon application of an external optical field, which could be interpreted as hardening of the soft mode and increasing of the damping coefficient and oscillator strength. Furthermore, the central mode was observed in the three films. Among the dielectric property of the three thin films studied, the tunability of the PZT/PT superlattice was the largest.
Coadsorption and reaction of H2 and CO on Raney nickel: Neutron vibrational spectroscopy
International Nuclear Information System (INIS)
Kelley, R.D.; Kernforschungsanlage Juelich G.m.b.H.
1983-01-01
Neutron vibration spectroscopy is used to study the adsorption and reaction of H 2 and Co on a catalytic nickel surface. The sample was first exposed to H 2 and than to CO. At low temperatures there is no change of vibrational modes of H in the three-fold site; at a higher temperature changes occur. Some conclusions are drawn on the reaction product. (G.Q.)
Transverse multibunch modes for non-rigid bunches, including mode coupling
Energy Technology Data Exchange (ETDEWEB)
Berg, J S; Ruth, R D [Stanford Linear Accelerator Center, Menlo Park, CA (United States)
1996-08-01
A method for computing transverse multibunch growth rates and frequency shifts in rings, which has been described previously, is applied to the PEP-II B factory. The method allows multibunch modes with different internal-bunch oscillation modes to couple to one another, similar to single-bunch mode coupling. Including coupling between the multibunch modes gives effects similar to those seen in single-bunch mode coupling. These effects occur at currents that are lower than the single-bunch mode coupling threshold. (author)
CSIR Research Space (South Africa)
Sawyer, BC
2012-05-01
Full Text Available -insensitive Doppler profile measurements [25], which give a minimum detectable temperature of �0:5 mK in 9Be?. Our tempera- ture measurement is mode specific and may be employed below the Doppler cooling limit, providing an alternative to Raman sideband....-D. Lin, L.-M. Duan, and C. Monroe, Nature (London) 465, 590 (2010). [13] R. Islam et al., Nature Commun. 2, 377 (2011). [14] J.W. Britton, B. C. Sawyer, A. C. Keith, C.-C. J. Wang, J. K. Freericks, H. Uys, M. J. Biercuk, and J. J. Bollinger, Nature...
International Nuclear Information System (INIS)
Itoh, Sanae.
1991-06-01
After the discovery of the H-mode in ASDEX ( a tokamak in Germany ) the transition between the L-mode ( Low confinement mode ) and H-mode ( High confinement mode ) has been observed in many tokamaks in the world. The H-mode has made a breakthrough in improving the plasma parameters and has been recognized to be a universal phenomena. Since its discovery, the extensive studies both in experiments and in theory have been made. The research on H-mode has been casting new problems of an anomalous transport across the magnetic surface. This series of lectures will provide a brief review of experiments for explaining H-mode and a model theory of H-mode transition based on the electric field bifurcation. If the time is available, a new theoretical model of the temporal evolution of the H-mode will be given. (author)
Characterization of a direct dc-excited discharge in water by optical emission spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Bruggeman, Peter; Leys, Christophe [Department of Applied Physics, Ghent University, Jozef Plateaustraat 22, B-9000 Ghent (Belgium); Schram, Daan [Department of Applied Physics, Technische Universiteit Eindhoven, PO Box 513, 5600 MB Eindhoven (Netherlands); Gonzalez, Manuel A [Departamento de Fisica Aplicada, Universidad de Valladolid, 47011 Valladolid (Spain); Rego, Robby [Flemish Institute of Technological Research, VITO Materials, Boeretang 200, B-2400 Mol (Belgium); Kong, Michael G [Department of Electronic and Electrical Engineering, Loughborough University, Loughborough, Leicestershire LE11 3TU (United Kingdom)], E-mail: peter.bruggeman@ugent.be
2009-05-01
Dc-excited discharges generated in water at the tip of a tungsten wire which is located at the orifice of a quartz capillary are investigated by time-averaged optical emission spectroscopy. Two distinctive discharge modes are observed. For small conductivities of the liquid the discharge is a streamer-like discharge in the liquid itself (liquid mode). For conductivities above typically 45 {mu}S cm{sup -1} a large vapour bubble is formed and a streamer discharge in this vapour bubble is observed (bubble mode). Plasma temperatures and electron densities are investigated for both modes. The gas temperature is estimated from the rotational temperature of N{sub 2}(C-B) and is 1600 {+-} 200 K for the bubble mode and 1900 {+-} 200 K for the liquid mode. The rotational temperature of OH(A-X) is up to 2 times larger and cannot be used as an estimate for the gas temperature. The rotational population distribution of OH(A), {nu} = 0 is also non-Boltzmann with a large overpopulation of high rotational states. This discrepancy in rotational temperatures is discussed in detail. Electron densities are obtained from the Stark broadening of the hydrogen Balmer beta line. The electron densities in the liquid mode are of the order of 10{sup 21} m{sup -3}. In the bubble mode electron densities are significantly smaller: (3-4) x 10{sup 20} m{sup -3}. These values are compared with the Stark broadening of the hydrogen alpha and gamma lines and with electron densities obtained from current density measurements. The chemical reactivities of the bubble and liquid modes are compared by means of the hydrogen peroxide production rate.
Characterization of a direct dc-excited discharge in water by optical emission spectroscopy
International Nuclear Information System (INIS)
Bruggeman, Peter; Leys, Christophe; Schram, Daan; Gonzalez, Manuel A; Rego, Robby; Kong, Michael G
2009-01-01
Dc-excited discharges generated in water at the tip of a tungsten wire which is located at the orifice of a quartz capillary are investigated by time-averaged optical emission spectroscopy. Two distinctive discharge modes are observed. For small conductivities of the liquid the discharge is a streamer-like discharge in the liquid itself (liquid mode). For conductivities above typically 45 μS cm -1 a large vapour bubble is formed and a streamer discharge in this vapour bubble is observed (bubble mode). Plasma temperatures and electron densities are investigated for both modes. The gas temperature is estimated from the rotational temperature of N 2 (C-B) and is 1600 ± 200 K for the bubble mode and 1900 ± 200 K for the liquid mode. The rotational temperature of OH(A-X) is up to 2 times larger and cannot be used as an estimate for the gas temperature. The rotational population distribution of OH(A), ν = 0 is also non-Boltzmann with a large overpopulation of high rotational states. This discrepancy in rotational temperatures is discussed in detail. Electron densities are obtained from the Stark broadening of the hydrogen Balmer beta line. The electron densities in the liquid mode are of the order of 10 21 m -3 . In the bubble mode electron densities are significantly smaller: (3-4) x 10 20 m -3 . These values are compared with the Stark broadening of the hydrogen alpha and gamma lines and with electron densities obtained from current density measurements. The chemical reactivities of the bubble and liquid modes are compared by means of the hydrogen peroxide production rate.
Yao, Jie; Li, Qian; Zhou, Bo; Wang, Dan; Wu, Rie
2018-04-01
Fourier-Transform Infrared micro-spectroscopy is an excellent method for biological analyses. In this paper, series metal coating films on ITO glass were prepared by the electrochemical method and the different thicknesses of paraffin embedding rat's brain tissue on the substrates were studied by IR micro-spetroscopy in attenuated total reflection (ATR) mode and transflection mode respectively. The Co-Ni-Cu alloy coating film with low cost is good reflection substrates for the IR analysis. The infrared microscopic transflection mode needs not to touch the sample at all and can get the IR spectra with higher signal to noise ratios. The Paraffin-embedding method allows tissues to be stored for a long time for re-analysis to ensure the traceability of the sample. Also it isolates the sample from the metal and avoids the interaction of biological tissue with the metals. The best thickness of the tissues is 4 μm.
Directory of Open Access Journals (Sweden)
Sylvain Christiaens
2014-07-01
Full Text Available Dialkyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylates have been prepared in a batch mode under conventional heating as well as under continuous flow conditions in the Miniflow 200SS, Sairem’s microwave-assisted batch and continuous flow equipment. Real-time monitoring of the reactions by Raman spectroscopy enabled to compare both heating modes and to determine (optimized reaction times.
Molecular dynamics simulation of nonlinear spectroscopies of intermolecular motions in liquid water.
Yagasaki, Takuma; Saito, Shinji
2009-09-15
Water is the most extensively studied of liquids because of both its ubiquity and its anomalous thermodynamic and dynamic properties. The properties of water are dominated by hydrogen bonds and hydrogen bond network rearrangements. Fundamental information on the dynamics of liquid water has been provided by linear infrared (IR), Raman, and neutron-scattering experiments; molecular dynamics simulations have also provided insights. Recently developed higher-order nonlinear spectroscopies open new windows into the study of the hydrogen bond dynamics of liquid water. For example, the vibrational lifetimes of stretches and a bend, intramolecular features of water dynamics, can be accurately measured and are found to be on the femtosecond time scale at room temperature. Higher-order nonlinear spectroscopy is expressed by a multitime correlation function, whereas traditional linear spectroscopy is given by a one-time correlation function. Thus, nonlinear spectroscopy yields more detailed information on the dynamics of condensed media than linear spectroscopy. In this Account, we describe the theoretical background and methods for calculating higher order nonlinear spectroscopy; equilibrium and nonequilibrium molecular dynamics simulations, and a combination of both, are used. We also present the intermolecular dynamics of liquid water revealed by fifth-order two-dimensional (2D) Raman spectroscopy and third-order IR spectroscopy. 2D Raman spectroscopy is sensitive to couplings between modes; the calculated 2D Raman signal of liquid water shows large anharmonicity in the translational motion and strong coupling between the translational and librational motions. Third-order IR spectroscopy makes it possible to examine the time-dependent couplings. The 2D IR spectra and three-pulse photon echo peak shift show the fast frequency modulation of the librational motion. A significant effect of the translational motion on the fast frequency modulation of the librational motion is
International Nuclear Information System (INIS)
Hansch, T.W.
1983-01-01
This chapter examines Doppler-free saturation spectroscopy, tunable cw sources, and Doppler-free two-photon spectroscopy. Discusses saturation spectroscopy; continuous wave saturation spectroscopy in the ultraviolet; and two-photon spectroscopy of atomic hydrogen 1S-2S. Focuses on Doppler-free laser spectroscopy of gaseous samples. Explains that in saturation spectroscopy, a monochromatic laser beam ''labels'' a group of atoms within a narrow range of axial velocities through excitation or optical pumping, and a Doppler-free spectrum of these selected atoms is observed with a second, counterpropagating beam. Notes that in two-photon spectroscopy it is possible to record Doppler-free spectra without any need for velocity selection by excitation with two counterpropagating laser beams whose first order Doppler shifts cancel
Collective vibrational spectra of α- and γ-glycine studied by terahertz and Raman spectroscopy
International Nuclear Information System (INIS)
Shi Yulei; Wang Li
2005-01-01
Terahertz time-domain spectroscopy is used to investigate the absorption and dispersion of polycrystalline α- and γ-glycine in the spectral region 0.5-3.0 THz. The spectra exhibit distinct features in these two crystalline phases. The observed far-infrared responses are attributed to intermolecular vibrational modes mediated by hydrogen bonds. We also measure the Raman spectra of the polycrystalline and dissolved glycine in the frequency range 28-3900 cm -1 . The results show that all the vibrational modes below 200 cm -1 are nonlocalized but are of a collective (phonon-like) nature. Furthermore, the temperature dependence of the Raman spectra of α-glycine agrees with the anharmonicity mechanism of the vibrational potentials
Energy Technology Data Exchange (ETDEWEB)
Diallo, A.; Kramer, G. J.; Bell, R. E.; Guttenfelder, W.; LeBlanc, B. P.; Podesta, M. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08540 (United States); Smith, D. R.; McKee, G. J. [Departments of Engineering Physics and Physics, University of Wisconsin, Madison, Wisconsin (United States); Maingi, R. [Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37831 (United States); Fonck, R. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08540 (United States); Departments of Engineering Physics and Physics, University of Wisconsin, Madison, Wisconsin (United States)
2013-01-15
Characterization of the spatial structure of turbulence fluctuations during the edge localized mode cycle in the pedestal region is reported. Using the beam emission spectroscopy and the correlation reflectometry systems, measurements show spatial structure-k{sub Up-Tack }{rho}{sub i}{sup ped}-ranging from 0.2 to 0.7 propagating in the ion diamagnetic drift direction at the pedestal top. These propagating spatial scales are found to be anisotropic and consistent with ion-scale microturbulence of the type ion temperature gradient and/or kinetic ballooning modes.
Mode-to-mode energy transfers in convective patterns
Indian Academy of Sciences (India)
Abstract. We investigate the energy transfer between various Fourier modes in a low- dimensional model for thermal convection. We have used the formalism of mode-to-mode energy transfer rate in our calculation. The evolution equations derived using this scheme is the same as those derived using the hydrodynamical ...
A prototype stationary Fourier transform spectrometer for near-infrared absorption spectroscopy.
Li, Jinyang; Lu, Dan-feng; Qi, Zhi-mei
2015-09-01
A prototype stationary Fourier transform spectrometer (FTS) was constructed with a fiber-coupled lithium niobate (LiNbO3) waveguide Mach-Zehnder interferometer (MZI) for the purpose of rapid on-site spectroscopy of biological and chemical measurands. The MZI contains push-pull electrodes for electro-optic modulation, and its interferogram as a plot of intensity against voltage was obtained by scanning the modulating voltage from -60 to +60 V in 50 ms. The power spectrum of input signal was retrieved by Fourier transform processing of the interferogram combined with the wavelength dispersion of half-wave voltage determined for the MZI used. The prototype FTS operates in the single-mode wavelength range from 1200 to 1700 nm and allows for reproducible spectroscopy. A linear concentration dependence of the absorbance at λmax = 1451 nm for water in ethanolic solution was obtained using the prototype FTS. The near-infrared spectroscopy of solid samples was also implemented, and the different spectra obtained with different materials evidenced the chemical recognition capability of the prototype FTS. To make this prototype FTS practically applicable, work on improving its spectral resolution by increasing the maximum optical path length difference is in progress.
Kong, Weibao; Wang, Yang; Yang, Hong; Xi, Yuqin; Han, Rui; Niu, Shiquan
2015-03-04
We studied the effects of trophic modes related to glucose and light (photoautotrophy, mixotrophy and heterotrophy) on growth, cellular components and carbon metabolic pathway of Chlorella vulgaris. The parameters about growth of algal cells were investigated by using spectroscopy and chromatography techniques. When trophic mode changed from photoautotrophy to mixotrophy and to heterotrophy successively, the concentrations of soluble sugar, lipid and saturated C16/C18 fatty acids in C. vulgaris increased, whereas the concentrations of unsaturated C16, C18 fatty acids, proteins, photosynthetic pigments and 18 relative amino acids decreased. Light and glucose affect the growth, metabolism and the biochemical components biosynthesis of C. vulgaris. Addition of glucose can promote algal biomass accumulation, stimulate the synthesis of carbonaceous components, but inhibit nitrogenous components. Under illumination cultivation, concentration and consumption level of glucose decided the main trophic modes of C. vulgaris. Mixotrophic and heterotrophic cultivation could promote the growth of algal cells.
Directory of Open Access Journals (Sweden)
Jianfa Gu
2017-01-01
Full Text Available The low-mode shell asymmetry and high-mode hot spot mixing appear to be the main reasons for the performance degradation of the National Ignition Facility (NIF implosion experiments. The effects of the mode coupling between low-mode P2 radiation flux asymmetry and intermediate-mode L = 24 capsule roughness on the implosion performance of ignition capsule are investigated by two-dimensional radiation hydrodynamic simulations. It is shown that the amplitudes of new modes generated by the mode coupling are in good agreement with the second-order mode coupling equation during the acceleration phase. The later flow field not only shows large areal density P2 asymmetry in the main fuel, but also generates large-amplitude spikes and bubbles. In the deceleration phase, the increasing mode coupling generates more new modes, and the perturbation spectrum on the hot spot boundary is mainly from the strong mode interactions rather than the initial perturbation conditions. The combination of the low-mode and high-mode perturbations breaks up the capsule shell, resulting in a significant reduction of the hot spot temperature and implosion performance.
Impact of gas pressure on fission chamber sensitivity in Campbelling mode
International Nuclear Information System (INIS)
Geslot, B.; Blaise, P.; Loiseau, P.; Filliatre, P.; Jammes, C.; Breaud, S.; Villard, J-F.; Blanc-de-Lanaute, N.
2013-06-01
The study presented in this paper is based on measurements conducted in the MINERVE zero power reactor operated at CEA Cadarache with a CEA-made U-235 miniature fission chamber (8 mm in diameter) and obtained in both pulse and Campbelling modes. Our objective was to investigate the impact of the filling gas mixture and pressure on each operating mode, using the capacity of the chamber to be refilled with gas. Three gas mixtures were tested (pure Ar, Ar+4%N 2 and Ar+10%CH 4 ) with pressure ranging from 1 to 9 bars. The Mean Fission Product Charge (MFPC), which is the mean charge deposited in the gas by fission products, was obtained from pulse mode signals for each detector setting. It is shown the MFPC is another key parameter to optimize the detector neutron sensitivity, after the fissile coating cross section. Campbelling mode signal was acquired with the Fast Neutron Detector System (FNDS) recently developed by CEA and SCK·CEN. Interesting results were obtained which improve our knowledge of the detector operation. Firstly, it was found that the measurements obtained in both modes are very consistent. The MFPC as a function of the gas pressure was found to be not monotonic. Instead, it features a maximum between 3 and 4 bars. This behavior is expected if the detector does not operate in saturation regime. Indeed, our standard voltage bias of 300 V appeared to be not high enough so that the saturation regime is established. Saturation curves measured in Campbelling mode were fitted using a detector modeling in order to extrapolate the saturation regime MFPC, which came to be independent from the gas. Secondly, obtained results show that the measuring range in Campbelling mode with this detector starts from fission rates as low as a few thousand counts per second. So the so called overlapping range, in which both pulse and Campbelling modes are usable, is about one decade with our spectroscopy modules and more than two decades with fast counting electronic
Verifying black hole orbits with gravitational spectroscopy
International Nuclear Information System (INIS)
Drasco, Steve
2009-01-01
Gravitational waves from test masses bound to geodesic orbits of rotating black holes are simulated, using Teukolsky's black hole perturbation formalism, for about ten thousand generic orbital configurations. Each binary radiates power exclusively in modes with frequencies that are integer-linear combinations of the orbit's three fundamental frequencies. General spectral properties are found with a survey of orbits about a black hole taken to be rotating at 80% of the maximal spin. The orbital eccentricity is varied from 0.1 to 0.9. Inclination ranges from 20 deg. to 160 deg. and comes to within 20 deg. of polar. Semilatus rectum is varied from 1.2 to 3 times the value at the innermost stable circular orbits. The following general spectral properties are found: (i) 99% of the radiated power is typically carried by a few hundred modes, and at most by about a thousand modes, (ii) the dominant frequencies can be grouped into a small number of families defined by fixing two of the three integer frequency multipliers, and (iii) the specifics of these trends can be qualitatively inferred from the geometry of the orbit under consideration. Detections using triperiodic analytic templates modeled on these general properties would constitute a verification of radiation from an adiabatic sequence of black hole orbits and would recover the evolution of the fundamental orbital frequencies. In an analogy with ordinary spectroscopy, this would compare to observing the Bohr model's atomic hydrogen spectrum without being able to rule out alternative atomic theories or nuclei. The suitability of such a detection technique is demonstrated using snapshots computed at 12-hour intervals throughout the last three years before merger of a kludged inspiral. The system chosen is typical of those thought to occur in galactic nuclei and to be observable with space-based gravitational wave detectors like LISA. Because of circularization, the number of excited modes decreases as the binary
Morrissey, Michael J.; Deasy, Kieran; Frawley, Mary; Kumar, Ravi; Prel, Eugen; Russell, Laura; Truong, Viet Giang; Chormaic, Síle Nic
2013-01-01
The use of tapered optical fibers, i.e., optical nanofibers, for spectroscopy and the detection of small numbers of particles, such as neutral atoms or molecules, has been gaining interest in recent years. In this review, we briefly introduce the optical nanofiber, its fabrication, and optical mode propagation within. We discuss recent progress on the integration of optical nanofibers into laser-cooled atom and vapor systems, paying particular attention to spectroscopy, cold atom cloud characterization, and optical trapping schemes. Next, a natural extension of this work to molecules is introduced. Finally, we consider several alternatives to optical nanofibers that display some advantages for specific applications. PMID:23945738
Search for gravitational waves associated with the August 2006 timing glitch of the Vela pulsar
International Nuclear Information System (INIS)
Abadie, J.; Abbott, B. P.; Abbott, R.; Adhikari, R.; Ajith, P.; Anderson, S. B.; Araya, M.; Aso, Y.; Ballmer, S.; Betzwieser, J.; Billingsley, G.; Black, E.; Blackburn, J. K.; Bork, R.; Brooks, A. F.; Cannon, K. C.; Cardenas, L.; Cepeda, C.; Chalermsongsak, T.; Chatterji, S.
2011-01-01
The physical mechanisms responsible for pulsar timing glitches are thought to excite quasinormal mode oscillations in their parent neutron star that couple to gravitational-wave emission. In August 2006, a timing glitch was observed in the radio emission of PSR B0833-45, the Vela pulsar. At the time of the glitch, the two colocated Hanford gravitational-wave detectors of the Laser Interferometer Gravitational-wave observatory (LIGO) were operational and taking data as part of the fifth LIGO science run (S5). We present the first direct search for the gravitational-wave emission associated with oscillations of the fundamental quadrupole mode excited by a pulsar timing glitch. No gravitational-wave detection candidate was found. We place Bayesian 90% confidence upper limits of 6.3x10 -21 to 1.4x10 -20 on the peak intrinsic strain amplitude of gravitational-wave ring-down signals, depending on which spherical harmonic mode is excited. The corresponding range of energy upper limits is 5.0x10 44 to 1.3x10 45 erg.
Directory of Open Access Journals (Sweden)
K. Rehan
2017-01-01
Full Text Available Laser-induced breakdown spectroscopy (LIBS was used for the quantitative analysis of elements present in textile dyes at ambient pressure via the fundamental mode (1064 nm of a Nd:YAG pulsed laser. Three samples were collected for this purpose. Spectra of textile dyes were acquired using an HR spectrometer (LIBS2000+, Ocean Optics, Inc. having an optical resolution of 0.06 nm in the spectral range of 200 to 720 nm. Toxic metals like Cr, Cu, Fe, Ni, and Zn along with other elements like Al, Mg, Ca, and Na were revealed to exist in the samples. The %-age concentrations of the detected elements were measured by means of standard calibration curve method, intensities of every emission from every species, and calibration-free (CF LIBS approach. Only Sample 3 was found to contain heavy metals like Cr, Cu, and Ni above the prescribed limit. The results using LIBS were found to be in good agreement when compared to outcomes of inductively coupled plasma/atomic emission spectroscopy (ICP/AES.
Observation of Ω mode electron heating in dusty argon radio frequency discharges
Energy Technology Data Exchange (ETDEWEB)
Killer, Carsten; Bandelow, Gunnar; Schneider, Ralf; Melzer, André [Institut für Physik, Ernst-Moritz-Arndt-Universität Greifswald, 17489 Greifswald (Germany); Matyash, Konstantin [Universitätsrechenzentrum, Ernst-Moritz-Arndt-Universität Greifswald, 17489 Greifswald (Germany)
2013-08-15
The time-resolved emission of argon atoms in a dusty plasma has been measured with phase-resolved optical emission spectroscopy using an intensified charge-coupled device camera. For that purpose, three-dimensional dust clouds have been confined in a capacitively coupled rf argon discharge with the help of thermophoretic levitation. While electrons are exclusively heated by the expanding sheath (α mode) in the dust-free case, electron heating takes place in the entire plasma bulk when the discharge volume is filled with dust particles. Such a behavior is known as Ω mode, first observed in electronegative plasmas. Furthermore, particle-in-cell simulations have been carried out, which reproduce the trends of the experimental findings. These simulations support previous numerical models showing that the enhanced atomic emission in the plasma can be attributed to a bulk electric field, which is mainly caused by the reduced electrical conductivity due to electron depletion.
International Nuclear Information System (INIS)
Chen Qiang; Ren Ji-Rong
2013-01-01
In this paper, we use the modified Hod's treatment and the Kunstatter's method to study the horizon area spectrum and entropy spectrum in Gauss—Bonnet de-Sitter space-time, which is regarded as the natural generalization of Einstein gravity by including higher derivative correction terms to the original Einstein—Hilbert action. The horizon areas have some properties that are very different from the vacuum solutions obtained from the frame of Einstein gravity. With the new physical interpretation of quasinormal modes, the area/entropy spectrum for the event horizon for near-extremal Gauss—Bonnet de Sitter black holes are obtained. Meanwhile, we also extend the discussion of area/entropy quantization to the non-extremal black holes solutions. (general)
International Nuclear Information System (INIS)
Turiaci, Gustavo J.; Verlinde, Herman
2016-01-01
We make three observations that help clarify the relation between CFT and quantum chaos. We show that any 1+1-D system in which conformal symmetry is non-linearly realized exhibits two main characteristics of chaos: maximal Lyapunov behavior and a spectrum of Ruelle resonances. We use this insight to identify a lattice model for quantum chaos, built from parafermionic spin variables with an equation of motion given by a Y-system. Finally we point to a relation between the spectrum of Ruelle resonances of a CFT and the analytic properties of OPE coefficients between light and heavy operators. In our model, this spectrum agrees with the quasi-normal modes of the BTZ black hole.
Logarithmic two-point correlation functions from a z=2 Lifshitz model
International Nuclear Information System (INIS)
Zingg, T.
2014-01-01
The Einstein-Proca action is known to have asymptotically locally Lifshitz spacetimes as classical solutions. For dynamical exponent z=2, two-point correlation functions for fluctuations around such a geometry are derived analytically. It is found that the retarded correlators are stable in the sense that all quasinormal modes are situated in the lower half-plane of complex frequencies. Correlators in the longitudinal channel exhibit features that are reminiscent of a structure usually obtained in field theories that are logarithmic, i.e. contain an indecomposable but non-diagonalizable highest weight representation. This provides further evidence for conjecturing the model at hand as a candidate for a gravity dual of a logarithmic field theory with anisotropic scaling symmetry
Energy Technology Data Exchange (ETDEWEB)
Turiaci, Gustavo J. [Physics Department, Princeton University,Princeton NJ 08544 (United States); Verlinde, Herman [Physics Department, Princeton University,Princeton NJ 08544 (United States); Princeton Center for Theoretical Science, Princeton University,Princeton NJ 08544 (United States)
2016-12-21
We make three observations that help clarify the relation between CFT and quantum chaos. We show that any 1+1-D system in which conformal symmetry is non-linearly realized exhibits two main characteristics of chaos: maximal Lyapunov behavior and a spectrum of Ruelle resonances. We use this insight to identify a lattice model for quantum chaos, built from parafermionic spin variables with an equation of motion given by a Y-system. Finally we point to a relation between the spectrum of Ruelle resonances of a CFT and the analytic properties of OPE coefficients between light and heavy operators. In our model, this spectrum agrees with the quasi-normal modes of the BTZ black hole.
Holographic thermalization in N = 4 super Yang-Mills theory at finite coupling
Energy Technology Data Exchange (ETDEWEB)
Stricker, Stefan A. [Technische Universitaet Wien, Institut fuer Theoretische Physik, Vienna (Austria)
2014-02-15
We investigate the behavior of energy-momentum tensor correlators in holographic N = 4 super Yang-Mills plasma, taking finite coupling corrections into account. In the thermal limit we determine the flow of quasinormal modes as a function of the 't Hooft coupling. Then we use a specific model of holographic thermalization to study the deviation of the spectral densities from their thermal limit in an out-of-equilibrium situation. The main focus lies on the thermalization pattern with which the plasma constituents approach their thermal distribution as the coupling constant decreases from the infinite coupling limit. All obtained results point towards the weakening of the usual top-down thermalization pattern. (orig.)
PLC-based LP₁₁ mode rotator for mode-division multiplexing transmission.
Saitoh, Kunimasa; Uematsu, Takui; Hanzawa, Nobutomo; Ishizaka, Yuhei; Masumoto, Kohei; Sakamoto, Taiji; Matsui, Takashi; Tsujikawa, Kyozo; Yamamoto, Fumihiko
2014-08-11
A PLC-based LP11 mode rotator is proposed. The proposed mode rotator is composed of a waveguide with a trench that provides asymmetry of the waveguide. Numerical simulations show that converting LP11a (LP11b) mode to LP11b (LP11a) mode can be achieved with high conversion efficiency (more than 90%) and little polarization dependence over a wide wavelength range from 1450 nm to 1650 nm. In addition, we fabricate the proposed LP11 mode rotator using silica-based PLC. It is confirmed that the fabricated mode rotator can convert LP11a mode to LP11b mode over a wide wavelength range.
A bidirectional dual-comb ring laser for simple and robust dual-comb spectroscopy
Ideguchi, Takuro; Nakamura, Tasuku; Kobayashi, Yohei; Goda, Keisuke
2015-01-01
Fourier-transform spectroscopy is an indispensable tool for analyzing chemical samples in scientific research as well as chemical and pharmaceutical industries. Recently, its measurement speed, sensitivity, and precision have been shown to be significantly enhanced by using dual frequency combs. However, wide acceptance of this technique is hindered by its requirement for two frequency combs and active stabilization of the combs. Here we overcome this predicament with a Kerr-lens mode-locked ...
Future facilities for light quark spectroscopy: A perspective based on the LASS experience
International Nuclear Information System (INIS)
Ratcliff, B.N.
1991-10-01
Some desirable design features of a future facility for the study of light meson spectroscopy in hadroproduction are described and compared with what has been achieved by the LASS spectrometer. A few aspects of next-generation experiments using such a facility are also discussed, including final state sample sizes and performance requirements. The need for complementary production modes and decay channels, and the importance of a broad programmatic approach to the physics are stressed
Orbital angular momentum modes by twisting of a hollow core antiresonant fiber
DEFF Research Database (Denmark)
Stefani, Alessio; Kuhlmey, Boris T.; Fleming, Simon
2017-01-01
Generation and use of orbital angular momentum (OAM) of light is finding more and more interest in a wide variety of fields of photonics: communications, optical trapping, quantum optics, and many more [1]. In the investigation of such behavior, twisting of photonic crystal fibers shows interesting......, allowing a simple and tunable way to generate OAM modes. We take advantage of THz time domain spectroscopy to obtain information on both intensity and field components, and to be able to investigate how they change both in time and with frequency....
Infrared spectroscopy of different phosphates structures.
Jastrzębski, W; Sitarz, M; Rokita, M; Bułat, K
2011-08-15
Infrared (IR) spectroscopic studies of mineral and synthetic phosphates have been presented. The interpretation of the spectra has been preceded by the isolated [PO(4)](3-) tetrahedron spectra analyse. The K(3)PO(4) saturated aqueous solution was measured in the special cell for liquids. The obtained IR results have been compared with the theoretical number of IR-active modes. The number and positions of the bands due to P-O vibrations have been established. The phase composition of the phosphates has been determined using XRD and IR spectroscopy methods. The influence of non-tetrahedral cations on the shape of the spectra and the positions of bands has been analysed and the crystalline field splitting effect has been discussed. Copyright © 2010 Elsevier B.V. All rights reserved.
International Nuclear Information System (INIS)
Woods, J.P.
1986-01-01
High-resolution (10-meV FWHM) low-energy (≤ 100eV) electrons are scattered from the tungsten (100) surface. Electron-energy-loss spectroscopy (EELS) selection rules are utilized to identify vibrational modes of the surface tungsten atoms. A 36-meV mode is measured on the c(2 X 2) thermally reconstructed surface and is modeled as an overtone of the 18-meV mode at M in the surface Brillouin zone. The superstructure of the reconstructed surface allows this mode to be observed in specular scattering. The surface tungsten atoms return to their bulk lateral positions with saturated hydrogen (β 1 phase) adsorption; and a 26-meV mode identified is due to the perpendicular vibration of the surface tungsten layers. The clean-room temperature surface does not display either low-energy vibrations and the surface is modeled as disordered. The three β 1 phase hydrogen vibrations are observed and a new vibration at 118 meV is identified. The 118-meV cross section displays characteristics of a parallel mode, but calculations show this assignment to be erroneous. There are two hydrogen atoms for each surface tungsten atom in the β 1 phase, and lattice-dynamical calculations show that the 118-meV mode is due to a hydrogen-zone edge vibration. The predicted breakdown of the parallel hydrogen vibration selection rule was not observed
Sub-THz spectroscopic characterization of vibrational modes in artificially designed DNA monocrystal
International Nuclear Information System (INIS)
Sizov, Igor; Rahman, Masudur; Gelmont, Boris; Norton, Michael L.; Globus, Tatiana
2013-01-01
Highlights: • Sub-THz spectroscopy is used to characterize artificially designed DNA monocrystal. • Results are obtained using a novel near field, RT, frequency domain spectrometer. • Narrow resonances of 0.1 cm −1 width in absorption spectra of crystal are observed. • Signature measured between 310 and 490 GHz is reproducible and well resolved. • Absorption pattern is explained in part by simulation results from dsDNA fragment. - Abstract: Sub-terahertz (sub-THz) vibrational spectroscopy is a new spectroscopic branch for characterizing biological macromolecules. In this work, highly resolved sub-THz resonance spectroscopy is used for characterizing engineered molecular structures, an artificially designed DNA monocrystal, built from a short DNA sequence. Using a recently developed frequency domain spectroscopic instrument operating at room temperature with high spectral and spatial resolution, we demonstrated very intense and specific spectral lines from a DNA crystal in general agreement with a computational molecular dynamics (MD) simulation of a short double stranded DNA fragment. The spectroscopic signature measured in the frequency range between 310 and 490 GHz is rich in well resolved and reproducible spectral features thus demonstrating the capability of THz resonance spectroscopy to be used for characterizing custom macromolecules and structures designed and implemented via nanotechnology for a wide variety of application domains. Analysis of MD simulation indicates that intense and narrow vibrational modes with atomic movements perpendicular (transverse) and parallel (longitudinal) to the long DNA axis coexist in dsDNA, with much higher contribution from longitudinal vibrations
Polarity control and growth mode of InN on yttria-stabilized zirconia (111) surfaces
International Nuclear Information System (INIS)
Kobayashi, Atsushi; Okubo, Kana; Ohta, Jitsuo; Oshima, Masaharu; Fujioka, Hiroshi
2012-01-01
We have found that polarity of epitaxial InN layers has been controlled by choice of a capping material during high-temperature annealing of yttria-stabilized zirconia (YSZ) (111) substrates in air. Angle-resolved X-ray photoelectron spectroscopy has revealed that the amount of segregation of Y atoms to the YSZ surface depended on the capping material of the substrates. In-polar and N-polar InN have been reproducibly grown on Y-segregated and Y-segregation-free YSZ surfaces, respectively. We have also found that the growth of the first monolayer (ML) of N-polar InN proceeds in a step-flow mode which then switches to layer-by-layer mode after the coverage by 1-ML-thick InN. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Effects of multiple modes interaction on the resistive wall mode instability
International Nuclear Information System (INIS)
Chen, Longxi; Lei, Wenqing; Ma, Zhiwei; Wu, Bin
2013-01-01
The effects of multiple modes interaction on the resistive wall mode (RWM) are studied in a slab geometry with and without plasma flow. The modes interaction can have a large effect on both the linear growth rate and the nonlinear saturation level of the RWM. We found that modes interaction can suppress the linear growth rate for the most unstable mode. The plasma flow can also help to control the growth of the RWM. The RWM can be stabilized completely by a plasma flow when considering the modes interaction. The effect of modes interaction on the RWM is stronger for the mode rational surface in the vacuum than that in the plasma. The modes interaction results in a substantially lowered saturation level for the most unstable RWM. (paper)
Ballooning modes or Fourier modes in a toroidal plasma?
International Nuclear Information System (INIS)
Connor, J.W.; Taylor, J.B.
1987-01-01
The relationship between two different descriptions of eigenmodes in a torus is investigated. In one the eigenmodes are similar to Fourier modes in a cylinder and are highly localized near a particular rational surface. In the other they are the so-called ballooning modes that extend over many rational surfaces. Using a model that represents both drift waves and resistive interchanges the transition from one of these structures to the other is investigated. In this simplified model the transition depends on a single parameter which embodies the competition between toroidal coupling of Fourier modes (which enhances ballooning) and variation in frequency of Fourier modes from one rational surface to another (which diminishes ballooning). As the coupling is increased each Fourier mode acquires a sideband on an adjacent rational surface and these sidebands then expand across the radius to form the extended mode described by the conventional ballooning mode approximation. This analysis shows that the ballooning approximation is appropriate for drift waves in a tokamak but not for resistive interchanges in a pinch. In the latter the conventional ballooning effect is negligible but they may nevertheless show a ballooning feature. This is localized near the same rational surface as the primary Fourier mode and so does not lead to a radially extended structure
Kalanoor, Basanth S; Ronen, Maria; Oren, Ziv; Gerber, Doron; Tischler, Yaakov R
2017-03-31
The low-frequency vibrational (LFV) modes of biomolecules reflect specific intramolecular and intermolecular thermally induced fluctuations that are driven by external perturbations, such as ligand binding, protein interaction, electron transfer, and enzymatic activity. Large efforts have been invested over the years to develop methods to access the LFV modes due to their importance in the studies of the mechanisms and biological functions of biomolecules. Here, we present a method to measure the LFV modes of biomolecules based on Raman spectroscopy that combines volume holographic filters with a single-stage spectrometer, to obtain high signal-to-noise-ratio spectra in short acquisition times. We show that this method enables LFV mode characterization of biomolecules even in a hydrated environment. The measured spectra exhibit distinct features originating from intra- and/or intermolecular collective motion and lattice modes. The observed modes are highly sensitive to the overall structure, size, long-range order, and configuration of the molecules, as well as to their environment. Thus, the LFV Raman spectrum acts as a fingerprint of the molecular structure and conformational state of a biomolecule. The comprehensive method we present here is widely applicable, thus enabling high-throughput study of LFV modes of biomolecules.
2013-01-01
Complexes obtained by the ligation of nitric oxide (NO) to metalloporphyrins represent important model systems with biological relevance. Herein we report a molecular-level investigation of surface-confined cobalt tetraphenyl porphyrin (Co-TPP) species and their interaction with NO under ultrahigh vacuum conditions. It is demonstrated that individual NO adducts can be desorbed using the atomically sharp tip of a scanning tunneling microscope, whereby a writing process is implemented for fully saturated regular metalloporphyrin arrays. The low-energy vibrational characteristics of individual Co-TPP-nitrosyl complexes probed by inelastic electron tunneling spectroscopy (IETS) reveal a prominent signature at an energy of ≃31 meV. Using density functional theory-based IETS simulations—the first to be performed on such an extensive interfacial nanosystem—we succeed to reproduce the low-frequency spectrum for the NO-ligated complex and explain the absence of IETS activity for bare Co-TPP. Moreover, we can conclusively assign the IETS peak of NO-Co-TPP to a unique vibration mode involving the NO complexation site, namely, the in-plane Co–N–O rocking mode. In addition, we verify that the propensity rules previously designed on small aromatic systems and molecular fragments hold true for a metal–organic entity. This work notably permits one to envisage IETS spectroscopy as a sensitive tool to chemically characterize hybrid interfaces formed by complex metal–organic units and gaseous adducts. PMID:23718257
Planning JWST NIRSpec MSA spectroscopy using NIRCam pre-images
Beck, Tracy L.; Ubeda, Leonardo; Kassin, Susan A.; Gilbert, Karoline; Karakla, Diane M.; Reid, I. N.; Blair, William P.; Keyes, Charles D.; Soderblom, D. R.; Peña-Guerrero, Maria A.
2016-07-01
The Near-Infrared Spectrograph (NIRSpec) is the work-horse spectrograph at 1-5microns for the James Webb Space Telescope (JWST). A showcase observing mode of NIRSpec is the multi-object spectroscopy with the Micro-Shutter Arrays (MSAs), which consist of a quarter million tiny configurable shutters that are 0. ''20×0. ''46 in size. The NIRSpec MSA shutters can be opened in adjacent rows to create flexible and positionable spectroscopy slits on prime science targets of interest. Because of the very small shutter width, the NIRSpec MSA spectral data quality will benefit significantly from accurate astrometric knowledge of the positions of planned science sources. Images acquired with the Hubble Space Telescope (HST) have the optimal relative astrometric accuracy for planning NIRSpec observations of 5-10 milli-arcseconds (mas). However, some science fields of interest might have no HST images, galactic fields can have moderate proper motions at the 5mas level or greater, and extragalactic images with HST may have inadequate source information at NIRSpec wavelengths beyond 2 microns. Thus, optimal NIRSpec spectroscopy planning may require pre-imaging observations with the Near-Infrared Camera (NIRCam) on JWST to accurately establish source positions for alignment with the NIRSpec MSAs. We describe operational philosophies and programmatic considerations for acquiring JWST NIRCam pre-image observations for NIRSpec MSA spectroscopic planning within the same JWST observing Cycle.
Larsson, Anders; Gustavsson, Johan S.
The only active transverse mode in a truly single-mode VCSEL is the fundamental mode with a near Gaussian field distribution. A single-mode VCSEL produces a light beam of higher spectral purity, higher degree of coherence and lower divergence than a multimode VCSEL and the beam can be more precisely shaped and focused to a smaller spot. Such beam properties are required in many applications. In this chapter, after discussing applications of single-mode VCSELs, we introduce the basics of fields and modes in VCSELs and review designs implemented for single-mode emission from VCSELs in different materials and at different wavelengths. This includes VCSELs that are inherently single-mode as well as inherently multimode VCSELs where higher-order modes are suppressed by mode selective gain or loss. In each case we present the current state-of-the-art and discuss pros and cons. At the end, a specific example with experimental results is provided and, as a summary, the most promising designs based on current technologies are identified.
International Nuclear Information System (INIS)
Kokh, Eh.; Zonntag, B.
1981-01-01
The latest investigation results on molecular spectroscopy with application of synchrotron radiation in the region of vacuum ultraviolet are generalized. Some results on investigation of excited, superexcited and ionized molecule states with the use of adsorption spectroscopy, photoelectron spectroscopy, by fluorescent and mass-spectrometric methods are considered [ru
Beall, Charlotte M.; Stokes, M. Dale; Hill, Thomas C.; DeMott, Paul J.; DeWald, Jesse T.; Prather, Kimberly A.
2017-07-01
Ice nucleating particles (INPs) influence cloud properties and can affect the overall precipitation efficiency. Developing a parameterization of INPs in global climate models has proven challenging. More INP measurements - including studies of their spatial distribution, sources and sinks, and fundamental freezing mechanisms - must be conducted in order to further improve INP parameterizations. In this paper, an immersion mode INP measurement technique is modified and automated using a software-controlled, real-time image stream designed to leverage optical changes of water droplets to detect freezing events. For the first time, heat transfer properties of the INP measurement technique are characterized using a finite-element-analysis-based heat transfer simulation to improve accuracy of INP freezing temperature measurement. The heat transfer simulation is proposed as a tool that could be used to explain the sources of bias in temperature measurements in INP measurement techniques and ultimately explain the observed discrepancies in measured INP freezing temperatures between different instruments. The simulation results show that a difference of +8.4 °C between the well base temperature and the headspace gas results in an up to 0.6 °C stratification of the aliquot, whereas a difference of +4.2 °C or less results in a thermally homogenous water volume within the error of the thermal probe, ±0.2 °C. The results also show that there is a strong temperature gradient in the immediate vicinity of the aliquot, such that without careful placement of temperature probes, or characterization of heat transfer properties of the water and cooling environment, INP measurements can be biased toward colder temperatures. Based on a modified immersion mode technique, the Automated Ice Spectrometer (AIS), measurements of the standard test dust illite NX are reported and compared against six other immersion mode droplet assay techniques featured in Hiranuma et al. (2015) that used
Development of nondestructive sorting method for brown bloody eggs using VIS/NIR spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Lee, Hong Seock; Kim, Dae Yong; Kandpal, Lalit Mohan; Lee, Sang Dae; Cho, Byoung Kwan [Dept. of Biosystems Machinery Engineering, College of Agriculture and Life Science, Chungnam National University, Daejeon (Korea, Republic of); Mo, Chang Yeun; Hong, Soon Jung [Rural Development Administration, Jeonju (Korea, Republic of)
2014-02-15
The aim of this study was the non-destructive evaluation of bloody eggs using VIS/NIR spectroscopy. The bloody egg samples used to develop the sorting mode were produced by injecting chicken blood into the edges of egg yolks. Blood amounts of 0.1, 0.7, 0.04, and 0.01 mL were used for the bloody egg samples. The wavelength range for the VIS/NIR spectroscopy was 471 to 1154 nm, and the spectral resolution was 1.5nm. For the measurement system, the position of the light source was set to, and the distance between the light source and samples was set to 100 mm. The minimum exposure time of the light source was set to 30 ms to ensure the fast sorting of bloody eggs and prevent heating damage of the egg samples. Partial least squares-discriminant analysis (PLS-DA) was used for the spectral data obtained from VIS/NIR spectroscopy. The classification accuracies of the sorting models developed with blood samples of 0.1, 0.07, 0.04, and 0.01 mL were 97.9%, 98.9%, 94.8%, and 86.45%, respectively. In this study, a novel nondestructive sorting technique was developed to detect bloody brown eggs using spectral data obtained from VIS/NIR spectroscopy.
Umesh P. Agarwal; Rajai Atalla
2010-01-01
Vibrational spectroscopy is an important tool in modern chemistry. In the past two decades, thanks to significant improvements in instrumentation and the development of new interpretive tools, it has become increasingly important for studies of lignin. This chapter presents the three important instrumental methods-Raman spectroscopy, infrared (IR) spectroscopy, and...
Energy Technology Data Exchange (ETDEWEB)
Sun, Yi-Yang; Zhang, Shengbai [Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)
2016-07-14
Bulk black phosphorus has two optical phonon modes labeled as A{sub g}{sup 2} and B{sub 2u}, respectively, that are nearly degenerate in frequency. However, density functional theory calculations using local or semi-local functionals cannot reproduce this degeneracy. Here, we propose a hybrid functional approach aided by van der Waals (vdW) force fields, which can accurately describe the lattice dynamic and electronic properties of both bulk and few-layer black phosphorus (phosphorene). Using this approach we show that in bilayer phosphorene, the two Raman modes derived from the B{sub 2u} and A{sub g}{sup 2} modes could exhibit strong resonance as a result of the accidental degeneracy so that both modes could be observed in Raman experiment. Without the mode degeneracy, however, the Raman intensity of the B{sub 2u}-derived mode would be too weak to be observed. We further show that the accidental degeneracy is correlated to the applied strain, which enables Raman spectroscopy to be a powerful tool for characterizing built-in strains in 2D materials, e.g., due to the interaction with substrates, which has emerged as an important issue in vdW epitaxy.
Hollas, J Michael
2013-01-01
The latest edition of this highly acclaimed title introduces the reader to a wide range of spectroscopies, and includes both the background theory and applications to structure determination and chemical analysis. It covers rotational, vibrational, electronic, photoelectron and Auger spectroscopy, as well as EXAFs and the theory of lasers and laser spectroscopy. A revised and updated edition of a successful, clearly written book Includes the latest developments in modern laser techniques, such as cavity ring-down spectroscopy and femtosecond lasers Provides numerous worked examples, calculations and questions at the end of chapters.
Wavelength and pulse duration tunable ultrafast fiber laser mode-locked with carbon nanotubes
Li, Diao; Jussila, Henri; Wang, Yadong; Hu, Guohua; Albrow-Owen, Tom; C. T. Howe, Richard; Ren, Zhaoyu; Bai, Jintao; Hasan, Tawfique; Sun, Zhipei
2018-01-01
Ultrafast lasers with tunable parameters in wavelength and time domains are the choice of light source for various applications such as spectroscopy and communication. Here, we report a wavelength and pulse-duration tunable mode-locked Erbium doped fiber laser with single wall carbon nanotube-based saturable absorber. An intra-cavity tunable filter is employed to continuously tune the output wavelength for 34 nm (from 1525 nm to 1559 nm) and pulse duration from 545 fs to 6.1 ps, respectively....
International Nuclear Information System (INIS)
Kodling, K.
1981-01-01
Experiments on atom photoabsorption spectroscopy using synchrotron radiation in the 10-1000 eV range are reviewed. Properties of the necessary synchrotron radiation and the experiment on absorption spectroscopy are briefly described. Comparison with other spectroscopy methods is conducted. Some data on measuring photoabsorption, photoelectron emission and atom mass spectra are presented [ru
Shigeta, M.; Sato, T.; Dasgupta, B.
1985-01-01
The magnetohydrodynamic stability of streaming tearing mode is investigated numerically. A bulk plasma flow parallel to the antiparallel magnetic field lines and localized in the neutral sheet excites a streaming tearing mode more strongly than the usual tearing mode, particularly for the wavelength of the order of the neutral sheet width (or smaller), which is stable for the usual tearing mode. Interestingly, examination of the eigenfunctions of the velocity perturbation and the magnetic field perturbation indicates that the streaming tearing mode carries more energy in terms of the kinetic energy rather than the magnetic energy. This suggests that the streaming tearing mode instability can be a more feasible mechanism of plasma acceleration than the usual tearing mode instability.
Zhao, Yonghong; Li, Zhi; Liu, Jianjun; Chen, Tao; Zhang, Huo; Qin, Binyi; Wu, Yifang
2018-03-01
The characteristic absorption spectra of two structural isomers of dimethylurea(DMU) in 0.6-1.8 THz region have been measured using terahertz time-domain spectroscopy (THZ-TDS) at room temperature. Significant differences have been found between their terahertz spectra and implied that the THZ-TDS is an effective means of identifying structural isomers. To simulate their spectra, calculations on single molecule and cluster of 1,1-DMU and 1,3-DMU were performed, and we found that the cluster calculations using DFT-D3 method are better to predict the experimental spectra. Using the normal mode as displacements in redundant internal coordinates and the GaussView program, most observed THz vibrational modes are assigned to bending and rocking modes related to the intermolecular hydrogen bonding interactions, and twisting mode of ethyl groups. The different spectral features of two isomers mainly arise from different intermolecular hydrogen bonds resulting from different atom arrangements in molecules and different molecule arrangements in crystals. Using the reduced-density-gradient (RDG) analysis, the positions and types of intermolecular hydrogen bonding interactions in 1,1-DMU and 1,3-DMU crystals are visualized. Therefore, we can confirm that THz-TDS can be used as an effective means for the recognition of structural isomers and detection of intermolecular hydrogen bonding interactions in these crystals.
Competition and evolution of dielectric waveguide mode and plasmonic waveguide mode
Yuan, Sheng-Nan; Fang, Yun-Tuan
2017-10-01
In order to study the coupling and evolution law of the waveguide mode and two plasmonic surface modes, we construct a line defect waveguide based on hexagonal honeycomb plasmonic photonic crystal. Through adjusting the radius of the edge dielectric rods, the competition and evolution behaviors occur between dielectric waveguide mode and plasmonic waveguide mode. There are three status: only plasmonic waveguide modes occur for rA 0.25a; two kinds of modes coexist for 0.09a advantages in achieving slow light.
E-H mode transition in low-pressure inductively coupled nitrogen-argon and oxygen-argon plasmas
International Nuclear Information System (INIS)
Lee, Young Wook; Lee, Hye Lan; Chung, T. H.
2011-01-01
This work investigates the characteristics of the E-H mode transition in low-pressure inductively coupled N 2 -Ar and O 2 -Ar discharges using rf-compensated Langmuir probe measurements and optical emission spectroscopy (OES). As the ICP power increases, the emission intensities from plasma species, the electron density, the electron temperature, and the plasma potential exhibit sudden changes. The Ar content in the gas mixture and total gas pressure have been varied in an attempt to fully characterize the plasma parameters. With these control parameters varying, the changes of the transition threshold power and the electron energy distribution function (EEDF) are explored. In N 2 -Ar and O 2 -Ar discharges at low-pressures of several millitorr, the transition thresholds are observed to decrease with Ar content and pressure. It is observed that in N 2 -Ar plasmas during the transition, the shape of the EEDF changes from an unusual distribution with a flat hole near the electron energy of 3 eV in the E mode to a Maxwellian distribution in the H mode. However, in O 2 -Ar plasmas, the EEDFs in the E mode at low Ar contents show roughly bi-Maxwellian distributions, while the EEDFs in the H mode are observed to be nearly Maxwellian. In the E and H modes of O 2 -Ar discharges, the dissociation fraction of O 2 molecules is estimated using optical emission actinometry. During the E-H mode transition, the dissociation fraction of molecules is also enhanced.
Zhang, Qiu-Ju; Liu, Bao-Sheng; Li, Gai-Xia; Han, Rong
2016-08-01
At different temperatures (298, 310 and 318 K), the interaction between gliclazide and bovine serum albumin (BSA) was investigated using fluorescence quenching spectroscopy, resonance light scattering spectroscopy and UV/vis absorption spectroscopy. The first method studied changes in the fluorescence of BSA on addition of gliclazide, and the latter two methods studied the spectral change in gliclazide while BSA was being added. The results indicated that the quenching mechanism between BSA and gliclazide was static. The binding constant (Ka ), number of binding sites (n), thermodynamic parameters, binding forces and Hill's coefficient were calculated at three temperatures. Values for the binding constant obtained using resonance light scattering and UV/vis absorption spectroscopy were much greater than those obtained from fluorescence quenching spectroscopy, indicating that methods monitoring gliclazide were more accurate and reasonable. In addition, the results suggest that other residues are involved in the reaction and the mode 'point to surface' existed in the interaction between BSA and gliclazide. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.
Zhao, Tian; Herbert, Patrick J; Zheng, Hongjun; Knappenberger, Kenneth L
2018-05-08
Electronic carrier dynamics play pivotal roles in the functional properties of nanomaterials. For colloidal metals, the mechanisms and influences of these dynamics are structure dependent. The coherent carrier dynamics of collective plasmon modes for nanoparticles (approximately 2 nm and larger) determine optical amplification factors that are important to applied spectroscopy techniques. In the nanocluster domain (sub-2 nm), carrier coupling to vibrational modes affects photoluminescence yields. The performance of photocatalytic materials featuring both nanoparticles and nanoclusters also depends on the relaxation dynamics of nonequilibrium charge carriers. The challenges for developing comprehensive descriptions of carrier dynamics spanning both domains are multifold. Plasmon coherences are short-lived, persisting for only tens of femtoseconds. Nanoclusters exhibit discrete carrier dynamics that can persist for microseconds in some cases. On this time scale, many state-dependent processes, including vibrational relaxation, charge transfer, and spin conversion, affect carrier dynamics in ways that are nonscalable but, rather, structure specific. Hence, state-resolved spectroscopy methods are needed for understanding carrier dynamics in the nanocluster domain. Based on these considerations, a detailed understanding of structure-dependent carrier dynamics across length scales requires an appropriate combination of spectroscopic methods. Plasmon mode-specific dynamics can be obtained through ultrafast correlated light and electron microscopy (UCLEM), which pairs interferometric nonlinear optical (INLO) with electron imaging methods. INLO yields nanostructure spectral resonance responses, which capture the system's homogeneous line width and coherence dynamics. State-resolved nanocluster dynamics can be obtained by pairing ultrafast with magnetic-optical spectroscopy methods. In particular, variable-temperature variable-field (VTVH) spectroscopies allow quantification
Time-resolved spectroscopy in synchrotron radiation
International Nuclear Information System (INIS)
Rehn, V.; Stanford Univ., CA
1980-01-01
Synchrotron radiation (SR) from large-diameter storage rings has intrinsic time structure which facilitates time-resolved measurements form milliseconds to picoseconds and possibly below. The scientific importance of time-resolved measurements is steadily increasing as more and better techniques are discovered and applied to a wider variety of scientific problems. This paper presents a discussion of the importance of various parameters of the SR facility in providing for time-resolved spectroscopy experiments, including the role of beam-line optical design parameters. Special emphasis is placed on the requirements of extremely fast time-resolved experiments with which the effects of atomic vibrational or relaxation motion may be studied. Before discussing the state-of-the-art timing experiments, we review several types of time-resolved measurements which have now become routine: nanosecond-range fluorescence decay times, time-resolved emission and excitation spectroscopies, and various time-of-flight applications. These techniques all depend on a short SR pulse length and a long interpulse period, such as is provided by a large-diameter ring operating in a single-bunch mode. In most cases, the pulse shape and even the stability of the pulse shape is relatively unimportant as long as the pulse length is smaller than the risetime of the detection apparatus, typically 1 to 2 ns. For time resolution smaller than 1 ns, the requirements on the pulse shape become more stringent. (orig./FKS)
Angle-resolved photoemission spectroscopy on iron-chalcogenide superconductors
Energy Technology Data Exchange (ETDEWEB)
Maletz, Janek; Zabolotnyy, Volodymyr; Evtushinsky, Daniil; Thirupathaiah, Setti; Wolter-Giraud, Anja; Harnagea, Luminita; Kordyuk, Alexander; Borisenko, Sergey [IFW Dresden (Germany); Yaresko, Alexander [MPI-FKF, Stuttgart (Germany); Vasiliev, Alexander [Moscow State University (Russian Federation); Chareev, Dimitri [RAS, Chernogolovka (Russian Federation); Rienks, Emile [Helmholtz-Zentrum Berlin (Germany); Buechner, Bernd [IFW Dresden (Germany); TU Dresden (Germany); Shermadini, Zurab; Luetkens, Hubertus; Sedlak, Kamil; Khasanov, Rustem; Amato, Alex; Krzton-Maziopa, Anna; Conder, Kazimierz; Pomjakushina, Ekaterina [Paul Scherrer Institute (Switzerland); Klauss, Hans-Henning [TU Dresden (Germany)
2014-07-01
The electronic structure of the iron chalcogenide superconductors FeSe{sub 1-x} and Rb{sub 0.77}Fe{sub 1.61}Se{sub 2} was investigated by high-resolution angle-resolved photoemission spectroscopy (ARPES). The results were compared to DFT calculations and μSR measurements. Both compounds share ''cigar-shaped'' Fermi surface sheets in their electronic structure, that can be found in almost all iron-pnictide superconductors. These features originate from a strong interplay of two hole- and electron-like bands in the Brillouin zone center, leading to a pronounced singularity in the density of states just below the Fermi level. This facilitates the coupling to a bosonic mode responsible for superconductivity.
COSMOS: Carnegie Observatories System for MultiObject Spectroscopy
Oemler, A.; Clardy, K.; Kelson, D.; Walth, G.; Villanueva, E.
2017-05-01
COSMOS (Carnegie Observatories System for MultiObject Spectroscopy) reduces multislit spectra obtained with the IMACS and LDSS3 spectrographs on the Magellan Telescopes. It can be used for the quick-look analysis of data at the telescope as well as for pipeline reduction of large data sets. COSMOS is based on a precise optical model of the spectrographs, which allows (after alignment and calibration) an accurate prediction of the location of spectra features. This eliminates the line search procedure which is fundamental to many spectral reduction programs, and allows a robust data pipeline to be run in an almost fully automatic mode, allowing large amounts of data to be reduced with minimal intervention.
Photoelectron spectroscopy and the dipole approximation
Energy Technology Data Exchange (ETDEWEB)
Hemmers, O.; Hansen, D.L.; Wang, H. [Univ. of Nevada, Las Vegas, NV (United States)] [and others
1997-04-01
Photoelectron spectroscopy is a powerful technique because it directly probes, via the measurement of photoelectron kinetic energies, orbital and band structure in valence and core levels in a wide variety of samples. The technique becomes even more powerful when it is performed in an angle-resolved mode, where photoelectrons are distinguished not only by their kinetic energy, but by their direction of emission as well. Determining the probability of electron ejection as a function of angle probes the different quantum-mechanical channels available to a photoemission process, because it is sensitive to phase differences among the channels. As a result, angle-resolved photoemission has been used successfully for many years to provide stringent tests of the understanding of basic physical processes underlying gas-phase and solid-state interactions with radiation. One mainstay in the application of angle-resolved photoelectron spectroscopy is the well-known electric-dipole approximation for photon interactions. In this simplification, all higher-order terms, such as those due to electric-quadrupole and magnetic-dipole interactions, are neglected. As the photon energy increases, however, effects beyond the dipole approximation become important. To best determine the range of validity of the dipole approximation, photoemission measurements on a simple atomic system, neon, where extra-atomic effects cannot play a role, were performed at BL 8.0. The measurements show that deviations from {open_quotes}dipole{close_quotes} expectations in angle-resolved valence photoemission are observable for photon energies down to at least 0.25 keV, and are quite significant at energies around 1 keV. From these results, it is clear that non-dipole angular-distribution effects may need to be considered in any application of angle-resolved photoelectron spectroscopy that uses x-ray photons of energies as low as a few hundred eV.
Microstructural Study of IF-WS2 Failure Modes
Directory of Open Access Journals (Sweden)
Jamie Cook
2014-07-01
Full Text Available This manuscript summarizes the failure mechanisms found in inorganic fullerene-type tungsten disulfide (IF-WS2 nanoparticles treated with diverse pressure loading methods. The approaches utilized to induce failure included: the use of an ultrasonic horn, the buildup of high pressures inside a shock tube which created a shock wave that propagated and impinged in the sample, and impact with military rounds. After treatment, samples were characterized using electron microscopy, powder X-ray diffraction, energy dispersive X-ray spectroscopy, and surface area analysis. The microstructural changes observed in the IF-WS2 particulates as a consequence of the treatments could be categorized in two distinct fracture modes. The most commonly observed was the formation of a crack at the particles surface followed by a phase transformation from the 3D cage-like structures into the 2D layered polymorphs, with subsequent agglomeration of the plate-like sheets to produce larger particle sizes. The secondary mechanism identified was the incipient delamination of IF-WS2. We encountered evidence that the IF-WS2 structure collapse initiated in all cases at the edges and vertices of the polyhedral particles, which acted as stress concentrators, independent of the load application mode or its duration.
Cyclotron operating mode determination based on intelligent methods
International Nuclear Information System (INIS)
Ouda, M.M.E.M.
2011-01-01
Particle accelerators are generators that produce beams of charged particles with energies depending on the accelerator type. The MGC-20 cyclotron is a cyclic particle accelerator used for accelerating protons, deuterons, alpha particles, and helium-3 to different energies. Main applications are isotopes production, nuclear reactions studies, and mass spectroscopy studies and other industrial applications. The cyclotron is a complicated machine depends on using a strong magnetic field and high frequency-high voltage electric field together to accelerate and bend charged particles inside the accelerating chamber. It consists of the following main parts, the radio frequency system, the main magnet with the auxiliary concentric and harmonic coils, the electrostatic deflector, and the ion source, the beam transport system, and high precision and high stability DC power supplies.To accelerate a particle to certain energy, one has to adjust the cyclotron operating parameters to be suitable to accelerate this particle to that energy. If the cyclotron operating parameters together are adjusted to accelerate a charged particle to certain energy, then these parameters together are named the operating mode to accelerate this particle to that energy. For example the operating mode to accelerate protons to 18 MeV is named the (18 MeV protons operating mode). The operating mode includes many parameters that must be adjusted together to be successful to accelerate, extract, focus, steer a particle from the ion source to the experiment. Due to the big number of parameters in the operating modes, 19 parameters have been selected in this thesis to be used in an intelligent system based on feed forward back propagation neural network to determine the parameters for new operating modes. The new intelligent system depends on the available information about the currently used operating modes.The classic way to determine a new operating mode was depending on trial and error method to
Mode coupling in hybrid square-rectangular lasers for single mode operation
Energy Technology Data Exchange (ETDEWEB)
Ma, Xiu-Wen; Huang, Yong-Zhen, E-mail: yzhuang@semi.ac.cn; Yang, Yue-De; Xiao, Jin-Long; Weng, Hai-Zhong; Xiao, Zhi-Xiong [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors and University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100083 (China)
2016-08-15
Mode coupling between a square microcavity and a Fabry-Pérot (FP) cavity is proposed and demonstrated for realizing single mode lasers. The modulations of the mode Q factor as simulation results are observed and single mode operation is obtained with a side mode suppression ratio of 46 dB and a single mode fiber coupling loss of 3.2 dB for an AlGaInAs/InP hybrid laser as a 300-μm-length and 1.5-μm-wide FP cavity connected to a vertex of a 10-μm-side square microcavity. Furthermore, tunable single mode operation is demonstrated with a continuous wavelength tuning range over 10 nm. The simple hybrid structure may shed light on practical applications of whispering-gallery mode microcavities in large-scale photonic integrated circuits and optical communication and interconnection.
Diode laser spectroscopy of oxygen electronic band at 760 nm
International Nuclear Information System (INIS)
Lucchesini, A.; De Rosa, M.; Gozzini, S.
1998-01-01
Collisional broadening and shift coefficients have been obtained by analyzing the line shapes of oxygen absorptions in the 760 nm electronic band. By using a diode laser spectrometer with commercially available etherostructure Al x Ga 1-x As diode lasers operating in 'free-running mode', line shape parameters have been collected at room temperature by varying the gas pressure. A systematic study has been carried on seven absorption lines by scanning the diode laser emission wavelength around the gas resonances. The weak absorption lines have been detected by using the wavelength modulation (WM) spectroscopy technique with second-harmonic detection
Detection of elemental mercury by multimode diode laser correlation spectroscopy.
Lou, Xiutao; Somesfalean, Gabriel; Svanberg, Sune; Zhang, Zhiguo; Wu, Shaohua
2012-02-27
We demonstrate a method for elemental mercury detection based on correlation spectroscopy employing UV laser radiation generated by sum-frequency mixing of two visible multimode diode lasers. Resonance matching of the multimode UV laser is achieved in a wide wavelength range and with good tolerance for various operating conditions. Large mode-hops provide an off-resonance baseline, eliminating interferences from other gas species with broadband absorption. A sensitivity of 1 μg/m3 is obtained for a 1-m path length and 30-s integration time. The performance of the system shows promise for mercury monitoring in industrial applications.
Multi-mode optical fibers for connecting space-based spectrometers
Roberts, W. T.; Lindenmisth, C. A.; Bender, S.; Miller, E. A.; Motts, E.; Ott, M.; LaRocca, F.; Thomes, J.
2017-11-01
significantly smaller, less massive and less robust. Large core multi-mode optical fibers are often used to accommodate the optical connection of the two separated portions of such instrumentation. In some cases, significant throughput efficiency improvement can be realized by judiciously orienting the strands of multi-fiber cable, close-bunching them to accommodate a tight focus of the optical system on the optical side of the connection, and splaying them out linearly along a spectrometer slit on the other end. For such instrumentation to work effectively in identifying elements and molecules, and especially to produce accurate quantitative results, the spectral throughput of the optical fiber connection must be consistent over varying temperatures, over the range of motion of the optical head (and it's implied optical cable stresses), and over angle-aperture invariant of the total system. While the first two of these conditions have been demonstrated[4], spectral observations of the latter present a cause for concern, and may have an impact on future design of fiber-connected LIBS and Raman spectroscopy instruments. In short, we have observed that the shape of the spectral efficiency curve of a large multi-mode core optical fiber changes as a function of input angle.
Delocalization of brane gravity by a bulk black hole
International Nuclear Information System (INIS)
Seahra, Sanjeev S; Clarkson, Chris; Maartens, Roy
2005-01-01
We investigate the analogue of the Randall-Sundrum braneworld in the case when the bulk contains a black hole. Instead of the static vacuum Minkowski brane of the RS model, we have an Einstein static vacuum brane. We find that the presence of the bulk black hole has a dramatic effect on the gravity that is felt by brane observers. In the RS model, the 5D graviton has a stable localized zero mode that reproduces 4D gravity on the brane at low energies. With a bulk black hole, there is no such solution-gravity is delocalized by the 5D horizon. However, the brane does support a discrete spectrum of metastable massive bound states, or quasinormal modes, as was recently shown to be the case in the RS scenario. These states should dominate the high frequency component of the bulk gravity wave spectrum on a cosmological brane. We expect our results to generalize to any bulk spacetime containing a Killing horizon. (letter to the editor)
Fluctuations of inflationary magnetogenesis
Giovannini, Massimo
2013-01-01
This analysis aims at exploring what can be said about the growth rate of magnetized inhomogeneities under two concurrent hypotheses: a phase of quasi-de Sitter dynamics driven by a single inflaton field and the simultaneous presence of a spectator field coupled to gravity and to the gauge sector. Instead of invoking ad hoc correlations between the various components, the system of scalar inhomogeneities is diagonalized in terms of two gauge-invariant quasi-normal modes whose weighted sum gives the curvature perturbations on comoving orthogonal hypersurfaces. The predominance of the conventional adiabatic scalar mode implies that the growth rate of magnetized inhomogeneities must not exceed 2.2 in Hubble units if the conventional inflationary phase is to last about 70 efolds and for a range of slow roll parameters between 0.1 and 0.001. Longer and shorter durations of the quasi-de Sitter stage lead, respectively, either to tighter or to looser bounds which are anyway more constraining than the standard backre...
Blázquez-Salcedo, Jose Luis
2016-01-01
Gravitational waves emitted by distorted black holes---such as those arising from the coalescence of two neutron stars or black holes---carry not only information about the corresponding spacetime but also about the underlying theory of gravity. Although general relativity remains the simplest, most elegant and viable theory of gravitation, there are generic and robust arguments indicating that it is not the ultimate description of the gravitational universe. Here we focus on a particularly appealing extension of general relativity, which corrects Einstein's theory through the addition of terms which are second order in curvature: the topological Gauss-Bonnet invariant coupled to a dilaton. We study gravitational-wave emission from black holes in this theory, and (i) find strong evidence that black holes are linearly (mode) stable against both axial and polar perturbations; (ii) discuss how the quasinormal modes of black holes can be excited during collisions involving black holes, and finally (iii) show that...
Czech Academy of Sciences Publication Activity Database
Ostapchuk, Tetyana; Petzelt, Jan; Kužel, Petr; Savinov, Maxim; Hlinka, Jiří; Tkach, A.; Vilarinho, P. M.; Lisenkov, S.; Ponomareva, I.; Bellaiche, L.
2010-01-01
Roč. 83, 10-11 (2010), s. 955-965 ISSN 0141-1594 R&D Projects: GA ČR GAP204/10/0616; GA MŠk ME08109 Institutional research plan: CEZ:AV0Z10100520 Keywords : soft mode * central mode * complex dielectric function * time-domain terahertz spectroscopy * infrared reflectivity Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.006, year: 2010
Fourier transform near-infrared spectroscopy application for sea salt quality evaluation.
Galvis-Sánchez, Andrea C; Lopes, João Almeida; Delgadillo, Ivonne; Rangel, António O S S
2011-10-26
Near-infrared (NIR) spectroscopy in diffuse reflectance mode was explored with the objective of discriminating sea salts according to their quality type (traditional salt vs "flower of salt") and geographical origin (Atlantic vs Mediterranean). Sea salts were also analyzed in terms of Ca(2+), Mg(2+), K(+), alkalinity, and sulfate concentrations to support spectroscopic results. High concentrations of Mg(2+) and K(+) characterized Atlantic samples, while a high Ca(2+) content was observed in traditional sea salts. A partial least-squares discriminant analysis model considering the 8500-7500 cm(-1) region permitted the discrimination of salts by quality types. The regions 4650-4350 and 5900-5500 cm(-1) allowed salts classification according to their geographical origin. It was possible to classify correctly 85.3 and 94.8% of the analyzed samples according to the salt type and to the geographical origin, respectively. These results demonstrated that NIR spectroscopy is a suitable and very efficient tool for sea salt quality evaluation.
Davis, Caitlin M; Reddish, Michael J; Dyer, R Brian
2017-05-05
Time-resolved temperature-jump (T-jump) coupled with fluorescence and infrared (IR) spectroscopy is a powerful technique for monitoring protein dynamics. Although IR spectroscopy of the polypeptide amide I mode is more technically challenging, it offers complementary information because it directly probes changes in the protein backbone, whereas, fluorescence spectroscopy is sensitive to the environment of specific side chains. With the advent of widely tunable quantum cascade lasers (QCL) it is possible to efficiently probe multiple IR frequencies with high sensitivity and reproducibility. Here we describe a dual time-resolved T-jump fluorescence and IR spectrometer and its application to study protein folding dynamics. A Q-switched Ho:YAG laser provides the T-jump source for both time-resolved IR and fluorescence spectroscopy, which are probed by a QCL and Ti:Sapphire laser, respectively. The Ho:YAG laser simultaneously pumps the time-resolved IR and fluorescence spectrometers. The instrument has high sensitivity, with an IR absorbance detection limit of jump induced difference spectrum from 50ns to 0.5ms. This study demonstrates the power of the dual time-resolved T-jump fluorescence and IR spectroscopy to resolve complex folding mechanisms by complementary IR absorbance and fluorescence measurements of protein dynamics. Copyright © 2017 Elsevier B.V. All rights reserved.
Red-excitation resonance Raman analysis of the nu(Fe=O) mode of ferryl-oxo hemoproteins.
Ikemura, Kenichiro; Mukai, Masahiro; Shimada, Hideo; Tsukihara, Tomitake; Yamaguchi, Satoru; Shinzawa-Itoh, Kyoko; Yoshikawa, Shinya; Ogura, Takashi
2008-11-05
The Raman excitation profile of the nuFe O mode of horseradish peroxidase compound II exhibits a maximum at 580 nm. This maximum is located within an absorption band with a shoulder assignable to an oxygen-to-iron charge transfer band on the longer wavelength side of the alpha-band. Resonance Raman bands of the nuFe O mode of various ferryl-oxo type hemoproteins measured at 590 nm excitation indicate that many hemoproteins in the ferryl-oxo state have an oxygen-to-iron charge transfer band in the visible region. Since this red-excited resonance Raman technique causes much less photochemical damage in the proteins relative to blue-excited resonance Raman spectroscopy, it produces a higher signal-to-noise ratio and thus represents a powerful tool for investigations of ferryl-oxo intermediates of hemoproteins.
Liang, >Jun
2018-05-01
Not Available Supported by the Natural Science Foundation of Education Department of Shannxi Province under Grant No 15JK1077, and the Doctorial Scientific Research Starting Fund of Shannxi University of Science and Technology under Grant No BJ12-02.
International Nuclear Information System (INIS)
Hu, T.A.; Chappell, E.L.; Sharpe, S.W.
1993-01-01
Rotationally resolved vibrational spectra consisting of a-type transitions have been observed for the low-frequency, intermolecular bending mode in combination with the highest frequency, intramolecular stretching mode of Ar--N 2 O. Analysis of the spectral data places the origin of the combination band at 2256.1 cm -1 while the origin of the intramolecular stretching fundamental is at 2223.9 cm -1 . The difference between these two origins is approximately 32.2 cm -1 and agrees well with our calculated frequency of 31.5 cm -1 for the intermolecular bending mode, which was obtained by analysis of the centrifugal distortion constants. In addition, argon--nitrous oxide exhibits an anomalously large inertial defect of 10.96 amu A 2 in the combination state. This indicates a breakdown in the assumption of separation between vibration and rotation. While much of the inertial defect in the ground state can be accounted for by including Coriolis interactions, that occurring in the combination state is only partially accounted for by a similar analysis. Small, but significant changes, are observed in both the radial and angular parameters for Ar--N 2 O when going from the ground to the combination state, indicating large amplitude motion. The combination band is approximately 200 times less intense than the high-frequency, stretching fundamental of Ar--N 2 O. In addition, over 400 new rovibrational transitions are assigned to the previously observed 1 0 1 intramolecular stretching fundamental of the complex, and the subsequent rotational analysis is found to be in close agreement with earlier studies. Data were taken on a newly built, rapid-scan, diode laser spectrometer that incorporates a 12 cmx200 μm pulsed slit-expansion nozzle
Energy Technology Data Exchange (ETDEWEB)
Liu, Xiumei; Jin, Zuanming; Lin, Xian; Ma, Guohong [Department of Physics, Shanghai University (China); Cheng, Zhenxiang [Institute for Superconducting and Electronic Materials, University of Wollongong, NSW (Australia); Balakrishnan, Geetha [Department of Physics, University of Warwick, Coventry (United Kingdom)
2017-09-15
A low-energy collective excitation mode in charge-ordered multiferroic LuFe{sub 2}O{sub 4} is reported via terahertz time-domain spectroscopy. Upon cooling from 300 to 40 K, the central resonance frequency showed a pronounced hardening from 0.85 to 1.15 THz. In analogy to the well-known low-energy optical properties of LuFe{sub 2}O{sub 4}, this emerging resonance was attributed to the charge-density-wave (CDW) collective excitations. By using the Drude-Lorentz model fitting, the CDW collective mode becomes increasingly damped with the increasing temperature. Furthermore, the kinks of the CDW collective mode at the magnetic transition temperature are analyzed, which indicate the coupling of spin order with electric polarization. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
International Nuclear Information System (INIS)
Vukolov, K.Yu.; Shvindt, N.N.
1992-01-01
Measurement cycle for determination of iron atom absolute concentrations was carried out in divertor and diaphragm modes of laser fluorescence spectroscopy. The conclusion is made on effective wall shielding by divertor layer as compared to material diaphragm. The basic result of the work consists in creating and testing on the tokamak TO-2 of multichannel diagnostic complex for remote measurement of atom (ion) absolute concentrations of metallic impurities in the near-wall plasma with high spatial and time resolution through laser fluorescence spectroscopy method intended for studies at the Tokamak-15 facility
High-temperature and high-pressure cubic zirconia anvil cell for Raman spectroscopy.
Chen, Jinyang; Zheng, Haifei; Xiao, Wansheng; Zeng, Yishan
2003-10-01
A simple and inexpensive cubic zirconia anvil cell has been developed for the performance of in situ Raman spectroscopy up to the conditions of 500 degrees C and 30 kbar pressure. The design and construction of this cell are fully described, as well as its applications for Raman spectroscopy. Molybdenum heater wires wrapped around ceramic tubes encircling two cubic zirconia anvils are used to heat samples, and the temperatures are measured and controlled by a Pt-PtRh thermocouple adhered near the sample chamber and an intelligent digital control apparatus. With this cell, Raman spectroscopic measurements have been satisfactorily performed on water at 6000 bar pressure to 455 degrees C and on ice of room temperature to 24 kbar, in which the determinations of pressures make use of changes of the A1 Raman modes of quartz and the shift of the sharpline (R-line) luminescence of ruby, respectively.
International Nuclear Information System (INIS)
Li, Zhi; Schlaf, Rudy; Sun, Siqi; Li, Xiao
2014-01-01
Inverse photoemission spectroscopy (IPES) enables the characterization of the density of states of unoccupied energy states above the Fermi level. However, due to the relatively high electron currents required to achieve useful signal to noise ratios, sample damage is a concern. Regioregular poly(3-hexylthiophene) (rr-P3HT) was used to systematically study the influence of electron radiation during IPES measurements on a prototypical conductive polymer. A series of IPES measurements exposing the samples to a range of electron fluxes was performed. An analysis of the electronic structure and the morphology showed that significant changes occurred in the investigated samples depending on the electron flux. X-ray diffraction results revealed that the root cause of the spectral changes is most likely related to crystallization of the film in an edge-on orientation. This was confirmed by Raman spectroscopy where both the C-C and C=C stretch modes shifted to lower frequencies after 5 IPES scans indicating a more ordered molecular structure. The observation of these stretch modes even after exposure to higher electron flux indicates that the main chemical structure of the P3HT molecules remains mostly intact during the IPES measurements. The absence of significant changes in C 1s and S 2p photoemission core level lines also confirmed this conclusion
Raman spectroscopy as an advanced structural nanoprobe for conjugated molecular semiconductors
International Nuclear Information System (INIS)
Wood, Sebastian; Hollis, Joseph Razzell; Kim, Ji-Seon
2017-01-01
Raman spectroscopy has emerged as a powerful and important characterisation tool for probing molecular semiconducting materials. The useful optoelectronic properties of these materials arise from the delocalised π -electron density in the conjugated core of the molecule, which also results in large Raman scattering cross-sections and a strong coupling between its electronic states and vibrational modes. For this reason, Raman spectroscopy offers a unique insight into the properties of molecular semiconductors, including: chemical structure, molecular conformation, molecular orientation, and fundamental photo- and electro-chemical processes—all of which are critically important to the performance of a wide range of optical and electronic organic semiconductor devices. Experimentally, Raman spectroscopy is non-intrusive, non-destructive, and requires no special sample preparation, and so is suitable for a wide range of in situ measurements, which are particularly relevant to issues of thermal and photochemical stability. Here we review the development of the family of Raman spectroscopic techniques, which have been applied to the study of conjugated molecular semiconductors. We consider the suitability of each technique for particular circumstances, and the unique insights it can offer, with a particular focus on the significance of these measurements for the continuing development of stable, high performance organic electronic devices. (topical review)
Analytical applications of spectroscopy
International Nuclear Information System (INIS)
Creaser, C.S.
1988-01-01
This book provides an up to date overview of recent developments in analytical spectroscopy, with a particular emphasis on the common themes of chromatography - spectroscopy combinations, Fourier transform methods, and data handling techniques, which have played an increasingly important part in the development of all spectroscopic techniques. The book contains papers originally presented at a conference entitled 'Spectroscopy Across The Spectrum' held jointly with the first 'International Near Infrared Spectroscopy Conference' at the University of East Anglia, Norwich, UK, in July 1987, which have been edited and rearranged with some additional material. Each section includes reviews of key areas of current research as well as short reports of new developments. The fields covered are: Near Infrared Spectroscopy; Infrared Spectroscopy; Mass Spectroscopy; NMR Spectroscopy; Atomic and UV/Visible Spectroscopy; Chemometrics and Data Analysis. (author)
E1 Gap of Wurtzite InAs Single Nanowires Measured by Means of Resonant Raman Spectroscopy
International Nuclear Information System (INIS)
Moeller, M.; Lima, M. M. Jr. de; Cantarero, A.; Dacal, L. C. O.; Iikawa, F.; Chiaramonte, T.; Cotta, M. A.
2011-01-01
Indium arsenide nanowires were synthesized with an intermixing of wurtzite and zincblende structure by chemical beam epitaxy with the vapor-liquid-solid mechanism. Resonant Raman spectroscopy of the transverse optical phonon mode at 215 cm -1 reveals an E 1 gap of 2.47 eV which is assigned to the electronic band gap at the A point in the indium arsenide wurtzite phase.
E1 Gap of Wurtzite InAs Single Nanowires Measured by Means of Resonant Raman Spectroscopy
Möller, M.; Dacal, L. C. O.; de Lima, M. M.; Iikawa, F.; Chiaramonte, T.; Cotta, M. A.; Cantarero, A.
2011-12-01
Indium arsenide nanowires were synthesized with an intermixing of wurtzite and zincblende structure by chemical beam epitaxy with the vapor-liquid-solid mechanism. Resonant Raman spectroscopy of the transverse optical phonon mode at 215 cm-1 reveals an E1 gap of 2.47 eV which is assigned to the electronic band gap at the A point in the indium arsenide wurtzite phase.
Nanoscale probing of bandgap states on oxide particles using electron energy-loss spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Liu, Qianlang [School for the Engineering of Matter, Transport and Energy, Arizona State University, 85287 AZ (United States); March, Katia [Laboratoire de Physique des Solides, Bâtiment 510, Université Paris-Sud, 91405 Orsay Cedex (France); Crozier, Peter A., E-mail: CROZIER@asu.edu [School for the Engineering of Matter, Transport and Energy, Arizona State University, 85287 AZ (United States)
2017-07-15
Surface and near-surface electronic states were probed with nanometer spatial resolution in MgO and TiO{sub 2} anatase nanoparticles using ultra-high energy resolution electron energy-loss spectroscopy (EELS) coupled to a scanning transmission electron microscope (STEM). This combination allows the surface electronic structure determined with spectroscopy to be correlated with nanoparticle size, morphology, facet etc. By acquiring the spectra in aloof beam mode, radiation damage to the surface can be significantly reduced while maintaining the nanometer spatial resolution. MgO and TiO{sub 2} showed very different bandgap features associated with the surface/sub-surface layer of the nanoparticles. Spectral simulations based on dielectric theory and density of states models showed that a plateau feature found in the pre-bandgap region in the spectra from (100) surfaces of 60 nm MgO nanocubes is consistent with a thin hydroxide surface layer. The spectroscopy shows that this hydroxide species gives rise to a broad filled surface state at 1.1 eV above the MgO valence band. At the surfaces of TiO{sub 2} nanoparticles, pronounced peaks were observed in the bandgap region, which could not be well fitted to defect states. In this case, the high refractive index and large particle size may make Cherenkov or guided light modes the likely causes of the peaks. - Highlights: • Bandgap states detected with aloof beam monochromated EELS on oxide nanoparticle surfaces. • Dielectric theory applied to simulate the spectra and interpret surface structure. • Density of states models also be employed to understand the surface electronic structure. • In MgO, one states associate with water species was found close to the valence band edge. • In anatase, two mid-gap states associated with point defects were found.
Adaptive variational mode decomposition method for signal processing based on mode characteristic
Lian, Jijian; Liu, Zhuo; Wang, Haijun; Dong, Xiaofeng
2018-07-01
Variational mode decomposition is a completely non-recursive decomposition model, where all the modes are extracted concurrently. However, the model requires a preset mode number, which limits the adaptability of the method since a large deviation in the number of mode set will cause the discard or mixing of the mode. Hence, a method called Adaptive Variational Mode Decomposition (AVMD) was proposed to automatically determine the mode number based on the characteristic of intrinsic mode function. The method was used to analyze the simulation signals and the measured signals in the hydropower plant. Comparisons have also been conducted to evaluate the performance by using VMD, EMD and EWT. It is indicated that the proposed method has strong adaptability and is robust to noise. It can determine the mode number appropriately without modulation even when the signal frequencies are relatively close.
Electromagnetic theories of surface-enhanced Raman spectroscopy.
Ding, Song-Yuan; You, En-Ming; Tian, Zhong-Qun; Moskovits, Martin
2017-07-07
Surface-enhanced Raman spectroscopy (SERS) and related spectroscopies are powered primarily by the concentration of the electromagnetic (EM) fields associated with light in or near appropriately nanostructured electrically-conducting materials, most prominently, but not exclusively high-conductivity metals such as silver and gold. This field concentration takes place on account of the excitation of surface-plasmon (SP) resonances in the nanostructured conductor. Optimizing nanostructures for SERS, therefore, implies optimizing the ability of plasmonic nanostructures to concentrate EM optical fields at locations where molecules of interest reside, and to enhance the radiation efficiency of the oscillating dipoles associated with these molecules and nanostructures. This review summarizes the development of theories over the past four decades pertinent to SERS, especially those contributing to our current understanding of SP-related SERS. Special emphasis is given to the salient strategies and theoretical approaches for optimizing nanostructures with hotspots as efficient EM near-field concentrating and far-field radiating substrates for SERS. A simple model is described in terms of which the upper limit of the SERS enhancement can be estimated. Several experimental strategies that may allow one to approach, or possibly exceed this limit, such as cascading the enhancement of the local and radiated EM field by the multiscale EM coupling of hierarchical structures, and generating hotspots by hybridizing an antenna mode with a plasmonic waveguide cavity mode, which would result in an increased local field enhancement, are discussed. Aiming to significantly broaden the application of SERS to other fields, and especially to material science, we consider hybrid structures of plasmonic nanostructures and other material phases and strategies for producing strong local EM fields at desired locations in such hybrid structures. In this vein, we consider some of the numerical
Raman Scattering and Surface Photovoltage Spectroscopy Studies of InGaAs/GaAs Radial Superlattices
Angelova, T.; Cros, A.; Ivanov, Ts.; Donchev, V.; Cantarero, A.; Shtinkov, N.; Deneke, Ch.; Schmidt, O. G.
2011-12-01
In this work we get insight into the multilayer structure of rolled-up microtube radial superlattices (RSLs) by the study of the optical and folded acoustic phonon modes of individual microtubes. Raman results show shifts of the InGaAs and GaAs related longitudinal optical modes that can be related to the strain state of the tubes. The folding of the acoustic modes has been related with the periodicity of the artificial superlattice formed by the multiple turns of the heterostructures. Information on the electronic structure and optical transitions of RSLs has been obtained by surface photovoltage spectroscopy. Room temperature spectra reveal several electronic transitions with energies below 1.3 eV. These transitions have been identified as originating from defect levels at the interfaces, as well as from the RSLs and the In0.215Ga0.785As/GaAs quantum well in the unfolded regions of the sample.
Walker, Greg; Römann, Philipp; Poller, Bettina; Löbmann, Korbinian; Grohganz, Holger; Rooney, Jeremy S; Huff, Gregory S; Smith, Geoffrey P S; Rades, Thomas; Gordon, Keith C; Strachan, Clare J; Fraser-Miller, Sara J
2017-12-04
This study uses a multimodal analytical approach to evaluate the rates of (co)amorphization of milled drug and excipient and the effectiveness of different analytical methods in detecting these changes. Indomethacin and tryptophan were the model substances, and the analytical methods included low-frequency Raman spectroscopy (785 nm excitation and capable of measuring both low- (10 to 250 cm -1 ) and midfrequency (450 to 1800 cm -1 ) regimes, and a 830 nm system (5 to 250 cm -1 )), conventional (200-3000 cm -1 ) Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray powder diffraction (XRPD). The kinetics of amorphization were found to be faster for the mixture, and indeed, for indomethacin, only partial amorphization occurred (after 360 min of milling). Each technique was capable of identifying the transformations, but some, such as low-frequency Raman spectroscopy and XRPD, provided less ambiguous signatures than the midvibrational frequency techniques (conventional Raman and FTIR). The low-frequency Raman spectra showed intense phonon mode bands for the crystalline and cocrystalline samples that could be used as a sensitive probe of order. Multivariate analysis has been used to further interpret the spectral changes. Overall, this study demonstrates the potential of low-frequency Raman spectroscopy, which has several practical advantages over XRPD, for probing (dis-)order during pharmaceutical processing, showcasing its potential for future development, and implementation as an in-line process monitoring method.