Zircon U-Pb dating of early Palaeozoic monzonitic intrusives from the Goonumbla area, New South Wales

International Nuclear Information System (INIS)

Butera, K.M.; Williams, I.S.; Blevin, P.L.; Simpson, C.J.

2001-01-01

Zircon U-Pb ages measured on four small intrusions into the succession of Ordovician volcanic rocks that hosts North Parkes Cu-Au mine northwest of Parkes. New South Wales. place limits on the age of the volcanic sequence. The basal Nelungaloo Volcanics are constrained by a cross-cutting monzodiorite to be ≥484.3 ± 2.9Ma (Early Ordovician). Similarly. the overlying basal Goonumbla Volcanics are constrained by another cross-cutting monzodiorite to be ≥450.8 ± 4.2Ma (Middle Ordovician). A later generation of monzonites intruded into the middle and upper Goonumbla Volcanics yield ages of 439.1 ± 4.5 and 438.9 ± 4.7 Ma (Siluro-Ordovician). These various ages are consistent with the ages of fossiliferous sediments within the volcanic sequence. and indicate that both the intrusive and volcanic rocks span an appreciable period of time-neither are the product of a single magmatic episode. Intrusion of the youngest monzonites and mineralisation was virtually contemporaneous. Copyright (2001) Geological Society of Australia

Petrology and geochemistry of Granitoids at Khanchay-Aliabad region, Tarom sub-zone, East of Zanjan

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Arefeh Saiedi

2018-03-01

Full Text Available Khanchay-Aliabad area as a part of Tarom magmatic belt contains some shallow depth intrusions which are intruded the Eocene volcanic- sedimentary rocks and have very close association with Cu mineralization. The Eocene volcanic- sedimentary rocks include alternation of basalt, basaltic andesite and andesite, various kinds of tuff, tuffaceous sandstone, sandstone, siltstone and occasionally shale. Petrographical studies demonstrate that intrusions are pyroxene quartz monzonite and olivine gabbro in composition. The Khanchay pyroxene quartz monzonite have porphyritic to porphyroidic, hetero-granular to sereitic, ophitic and sub- ophitic textures and composed of plagioclase, clinopyroxene, hornblende, quartz, K-feldspar and biotite. The Aliabad pyroxene quartz monzonite shows porphyritic to porphyroidic textures composing of plagioclase, clinopyroxene and hornblende in the quartz- feldspatic matrix. The Khanchay olivine gabbro is characterized by the presence of coarse grained granular, ophitic and sub- ophitic textures as well as the occurrence of plagioclase, clinopyroxene and olivine. Geochemical studies indicate that the Khanchay- Aliabad pyroxene quartz monzonitic intrusions have SiO2 content varying from 59.58 to 61.34 %. These intrusions have high- K calc- alkaline nature and are classified as I-type metaluminous granitoids. Their similar patterns on spider diagrams are indication of genetic relation of these intrusions. On these diagrams LILEs (Ba, K, Th and Pb enrichment along with negative anomalies of HFSEs (Nb and Ti are observed. Moreover, the Chondrite normalized REE patterns demonstrate LREE enrichment with high ratio of LREE/HREE and Lan/Ybn ratio ranging from 3.08 to 3.72. The overall  field investigation, petrological and geochemical studies as well as  tectonic setting discrimination diagrams confirm that the Khanchay- Aliabad high-K intrusions were formed from a subduction related metasomatized lithospheric mantle in a post

Plasma-assisted quartz-to-quartz direct bonding for the fabrication of a multilayered quartz template for nanoimprint lithography

International Nuclear Information System (INIS)

Lee, Jihye; Ali, Altun; Kim, Ki-don; Choi, Dae-guen; Choi, Jun-Hyuk; Jeong, Jun-ho; Kim, Jae-Hyun

2010-01-01

In this paper, a low-temperature plasma-assisted process is developed to realize a uniform, ultraviolet (UV) transparent and chemically inert quartz-to-quartz direct bonding. Two sets of pretests are performed in order to understand how the bond surface energy changes with the plasma exposure time and the wet etching of quartz, respectively. The developed technique is used to fabricate a multilayered quartz template for UV nanoimprint lithography (UV-NIL). The multilayered quartz template is fabricated by bonding a square piece of a standard quartz wafer, which is about 625 µm in thickness, to a wet-etched 6.35 mm thick quartz photomask plate. A fabricated multilayered template is loaded to the commercial UV-NIL tool Imprio(TM) 100, and NIL was performed successfully. The developed direct bonding technique makes it possible for standard quartz wafers, which are compatible with high-resolution semiconductor fabrication processes, to be utilized as the templates in commercial UV-NIL machines with enhanced mechanical stability.

The physical properties of coal

CSIR Research Space (South Africa)

Van Schoor, Abraham M

2015-01-01

Full Text Available FORMATION KIMBERLITE LAMPROPHYRE LAVA LIMESTONE LUTACEOUS ARENITE LUTITE MAGNETITE METAMORPHIC ROCKS MONZONITE NORITE OLIVINE GABBRO PLUTONIC ROCKS PYROCLASTIC BRECCIA PYROXENITE QUARTZ DIORITE RHYOLITE RUDITE SAND SEDIMENTARY SILCRETE SILICICLASTIC SEDIMENT...

Mineralization and geophysical exploration by IP/RS and ground magnetic survey in MA-I and surrounding area, Maherabad porphyry Cu-Au prospect area, east of Iran

OpenAIRE

Azadeh Malekzadeh Shafaroudi; Mohammad Reza Hidarian Shahri; Mohammad Hassan Karimpour

2009-01-01

Maherabad prospect area, which is studied in detail, is the first porphyry Cu-Au mineralization in the east of Iran. Based on relation of mineralization with subvolcanic intrusive bodies mostly monzonitic with porphyry texture, extent and types of alteration including potassic, sericitic- potassic, quartz- sericite- carbonate- pyrite, quartz- carbonate- pyrite, silicification- propylitic, propylitic, stockwork mineralization, assemblages hypogene mineralization including pyrite, chalcopyrite,...

Role of Substrate on Quartz Cementation in Quartz Aggregates

Science.gov (United States)

Farver, J. R.; Winslow, D.; Onasch, C.

2010-12-01

Quartz cementation in quartz aggregates has been experimentally investigated. The starting material was disaggregated detrital quartz grains from the well-sorted, mature St. Peter Sandstone. The ‘as-is’ grains have patches of iron oxide coatings and some have euhedral overgrowths that contain iron oxide dust rims. In addition a set of experiments was run using grains that were cleaned by soaking in sodium hydrosulfite and sodium bisulfate solutions to remove exposed iron oxide coatings. Experimental charges consisted of amorphous silica powder (≈30 mg) to provide a source of silica for the quartz cement, AlCl3 powder (≈3 mg) to provide a tracer for Cathodoluminescence (CL) identification of cement formed during the experiment, 25 wt% NaCl brine solution (≈25 mg) to increase the silica solubility and to better mimic oil field brines, and the natural quartz grains (100-130 mg). The charges were weld-sealed in Au capsules and run in cold-seal pressure vessels at 250°C to 450°C at 150 MPa confining pressure for up to 8 weeks. After the experiments, the samples were vacuum impregnated with a low viscosity epoxy containing a blue dye. After curing, the sample charge was sawn in half along its long axis and one half was polished (to 1 micron diamond paste) for analysis. The nature and amount of quartz cement in the samples were determined by a combination of CL, light microscopy, and scanning electron microscopy. Photomosaics of the samples were created and the amount of cement, porosity, and average grain sizes were determined by point-counting. The cement formed during the experiment was easily recognized from the quartz grains (and previous overgrowths) by the difference in luminescence. The results indicate the amorphous silica powder provides a ready source for silica for quartz cementation due to its greater solubility than the quartz. The cementation rates are rapid (>14% cement formed in 2 weeks at 450°C and >7% in 8 weeks at 250°C). Compared to

Geological characters and petrological characters of metamorphosed medium-acidic intrusive complexes in Ludong Orogenic Belt,China

Institute of Scientific and Technical Information of China (English)

凌贤长; 胡庆立; 王丽霞

2002-01-01

Ludong orogenic belt in China is an importantal continent collision orogenic belt in eastern Asia, between Sino-Korean landmass and Yangtze landmass. The host rock of the orogenic belt is metamorphosed medium-acidic intrusive complexes, which can be divided into four types, that's, quartz dioritz, granite dioritz, monzonitic granite and undertint monzonitic granite, principal minerals are plagioclases, potassium feldspars and quartzs, minor minerals are hornblendes, biotites, clinopyxenes and garnets, accessory mineral types and assemblages are very similar, specially, various rocks are mainly fine-grained textures. They have the history of regional amphibolite facies metamorphism and deep-middle-shallow structural layer deformation, and are changed into various gneiss and tectonic system. There are many xenolithes of middle Proterozoic eclogite-host rock extrahigh-high pressure metamorphic complexes, a small xenolithes of early Proterozoic layered metamorphite system and granulites, and ultrabasic-basic rocks of various epoches in the metamorphosed medium-acidic intrusive complexes.

The Shah-Ali-Beiglou Zn-Pb-Cu (-Ag Deposit, Iran: An Example of Intermediate Sulfidation Epithermal Type Mineralization

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Khadijeh Mikaeili

2018-04-01

Full Text Available The Shah-Ali-Beiglou epithermal base metal-silver deposit is located in the Tarom-Hashjin metallogenic province (THMP in northwestern Iran. This deposit is hosted by quartz monzonite dikes of Oligocene age and surrounded by andesite to trachyandesite volcanic and volcaniclastic rocks of Eocene age. The subvolcanic rocks in the study area vary in composition from quartz-monzonite to monzonite and have metaluminous, calc-alkaline to shoshonitic affinity. These rocks have I-type geochemical characteristic and are related to post-collisional tectonic setting. The mineralization occurs as NE-SW and E-W-trending brecciated veins controlled by strike-slip and normal faults, which are associated to the Late Oligocene compressional regime. The mineral paragenesis of the vein mineralization is subdivided into pre-ore stage, ore stage, post-ore stage, and supergene stage. Pre-ore stage is dominated by quartz, sericite, and subhedral to anhedral pyrite as disseminated form. Ore-stage is represented by quartz, sphalerite (from 0.1 mol % to 4 mol % FeS, galena, chalcopyrite, tetrahedrite-tennantite, minor seligmannite and enargite, as vein-veinlet, cement and clast breccias. Post-ore stage is defined by deposition of quartz and carbonate along with minor barite, and supergene stage is characterized by bornite, chalcocite, covellite, hematite, goethite, and jarosite. The ore mineralization is associated with the silicic alteration. The styles of alteration are silicic, carbonate, sericitic, chloritic, and propylitic. Fluid inclusions in sphalerite have a wide range of salinities between 0.35 wt % and 21.4 wt % NaCl equivalent and homogenization temperatures range from 123 to 320 °C. The isotopic values of sulfides vary from 2.8‰ to 6.7‰ suggesting a magmatic source for the sulfur. In the present study, based on geological setting, alteration style of the host and wall rocks, main textures, mineral assemblages, composition of ore minerals, and structural

Preliminary study of the uranium favorability of granitic and contact-metamorphic rocks of the Owens Valley area, Inyo and Mono Counties, California, and Esmeralda and Mineral Counties, Nevada

International Nuclear Information System (INIS)

Cupp, G.M.; Mitchell, T.P.

1978-01-01

Granitic and contact-metamorphic rocks of the Owens Valley area were sampled to determine their favorability for uranium. Uranium deposits associated with these rocks were examined to determine the mode of occurrence. Metamorphic rocks near contacts with intrusive rocks include skarns, schists, quartzites, metaconglomerates, hornfels, gneisses, and metavolcanics. The grade of contact metamorphism ranges from slight to intense, depending upon the distance from the intrusive contact. The average U 3 O 8 content of the metamorphic rock samples is 3 ppM. Metamorphic rock samples in a roof pendant at the Claw prospect contain as much as 3 percent U 3 O 8 . Skarn samples from the Birch Creek pluton contain as much as 114 ppM U 3 O 8 ; those from the Santa Rita Flat pluton contain as much as 23 ppM U 3 O 8 . Most of the intrusive rocks are granite, quartz monzonite, or monzonite. Granodiorite and diorite are less common, and gabbro is rare. The average U 3 O 8 content of the crystalline rock samples is 4 ppM. Samples from a quartz-monzonite pluton east of Lone Pine, California, and quartz monzonite in the Santa Rosa Hills had maximum contents of 28 and 13 ppM U 3 O 8 , respectively. Areas of contact metamorphism and metasomatism, such as those at the Claw prospect and Birch Creek pluton, are probably the most favorable sites for uranium deposits. There are many miles of granitic and contact-metamorphic zones in which undiscovered uranium deposits may exist. Although the overall uranium content of granitic rocks appears to be low, the pluton east of Lone Pine and the Hunter Mountain pluton in the area of the Santa Rosa Hills have sufficient uranium to have acted as uranium and detrital source rocks for uranium deposits that may now be buried in Tertiary sediments in the basins around the plutons. The Claw deposit is the only known uranium deposit of a size and grade to be of possible commercial interest

Geochemistry and zircon U-Pb geochronology of the Pulang complex, Yunnan province, China

International Nuclear Information System (INIS)

Pang, Zhenshan; Du, Yangsong; Cao, Yi; Gao, Fuping; Wang, Gongwen; Dong, Qian

2014-01-01

The Pulang complex is located tectonically at the southern margin of the Yidun-Zhongdian island arc belt in Yunnan province, China, and is closely related to formation of the Pulang copper deposit, which is the largest copper deposit in Asia. The Pulang complex can be divided into three intrusion stages based on contact relationships and petrological characteristics: (1) a first stage of quartz dioritic porphyry; (2) a second stage of quartz monzonitic porphyry; and (3) a third stage of granodioritic porphyry. The crystallization ages of these intrusion stages were determined by single-zircon U-Pb dating, yielding ages of 221.0 ± 1.0, 211.8 ± 0.5, and 206.3 ± 0.7 Ma for the first, second, and third stages, respectively. These dates, integrated with previous geochronological data and field investigations, indicate that the second-stage quartz monzonitic porphyry has a close spatial and temporal relationship with the large Pulang porphyry copper deposit. These age data, geochemical and Sr-Nd isotopic results suggest that the Pulang complex formed in the Indo-Chinese epoch (257∼ 205 Ma) by multiphase intrusion of a mixture of mantle- and crust-derived magmas. (author)

Journal of Earth System Science | Indian Academy of Sciences

Indian Academy of Sciences (India)

These dates, integrated with previous geochronological data and field investigations, indicate that the second-stage quartz monzonitic porphyry has a close spatial and temporal relationship with the large Pulang porphyry copper deposit. These age data, geochemical and Sr–Nd isotopic results suggest that the Pulang ...

Colorado quartz: occurrence and discovery

Science.gov (United States)

Kile, D.E.; Modreski, P.J.; Kile, D.L.

1991-01-01

The many varieties and associations of quartz found throughout the state rank it as one of the premier worldwide localities for that species. This paper briefly outlines the historical importance of the mineral, the mining history and the geological setting before discussing the varieties of quartz present, its crystallography and the geological enviroments in which it is found. The latter include volcanic rocks and near surface igneous rocks; pegmatites; metamorphic and plutonic rocks; hydrothermal veins; skarns and sedimentary deposits. Details of the localities and mode of occurrence of smoky quartz, amethyst, milky quartz, rock crystal, rose quartz, citrine, agate and jasper are then given. -S.J.Stone

Mineralogy of metasomatic rocks and geochronology of the Olhovka porphyry-copper deposit, Chukotka, Russia

Science.gov (United States)

Rogacheva, Lyuba; Baksheev, Ivan

2010-05-01

The Olkhovka porphyry-copper deposit located on the border of foreland of the Okhotsk-Chukotka volcanic belt (OCVB) and a ledge composed of the Late Jurassic-Early Cretaceous Uda-Murgal arc (J3-K1) rocks is hosted by monzonite stock attributed to the Upper Cretaceous Kavralyan complex - K2) We estimated age of the Olkhovka monzonite by Rb-Sr and U-Pb methods. Rb-Sr age was determine om the basis of isotopic analysis of 8 monomineralic samples (potassium feldspar, plagioclase, amphibole, and dark mica). Isochron constructed on the basis of Rb-Sr data corresponds to the age of 78 + 2.6 Ma (MSWD=0.23). The Rb-Sr age is supported by U-Pb data derived from zircon of the same rock. One hundred and three single crystals of zircon were analyzed. Uranium content ranges from 52.66 ppm to 579.64 ppm; U/Th isotopic ratio varies from 0.567 to 1.746; age is 78.02+0.65 Ma (MSWD = 2.8). Monzonite is propylitized in variable degree. Propylite is composed of actinolite, chlorite, albite, quartz, and calcite. Propylite are cut by quartz-tourmaline veins. In addition, quartz-tourmaline metasomatic rock was identified in rhyolite ignimbrite out of the stock. Microscopically, tourmaline crystals of both types are oscilatory zoned that is caused by variable Fe content. Tourmalines of both assemblages can be classified as intermediate member of the schorl ("oxy-schorl")-dravite ("oxy-dravite") series. The Fetot/ (Fetot+Mg) varies from 0.31 to 0.95 in propylitic tourmaline and from 0.11 to 0.49, in quartz-tourmaline altered rocks from ignimbrite. Despite similar composition of both tourmalines, the major isomorphic substitutions in them are different. In propylite tourmaline, it is Fe → Al, whereas in the second case, it is Fe → Mg with certain effect of the Fe → Al type. Fe → Al isomorphic substitution is typical of porphyry style deposits (Baksheev et al., 2009 [1]). Therefore, we can conclude that quartz-tourmaline alteration in ignimbrite does not related to the formation of

Hydrogen speciation in synthetic quartz

Science.gov (United States)

Aines, R.D.; Kirby, S.H.; Rossman, G.R.

1984-01-01

The dominant hydrogen impurity in synthetic quartz is molecular H2O. H-OH groups also occur, but there is no direct evidence for the hydrolysis of Si-O-Si bonds to yield Si-OH HO-Si groups. Molecular H2O concentrations in the synthetic quartz crystals studied range from less than 10 to 3,300 ppm (H/Si), and decrease smoothly by up to an order of magnitude with distance away from the seed. OH- concentrations range from 96 to 715 ppm, and rise smoothly with distance away from the seed by up to a factor of three. The observed OH- is probably all associated with cationic impurities, as in natural quartz. Molecular H2O is the dominant initial hydrogen impurity in weak quartz. The hydrolytic weakening of quartz may be caused by the transformation H2O + Si-O-Si ??? 2SiOH, but this may be a transitory change with the SiOH groups recombining to form H2O, and the average SiOH concentration remaining very low. Synthetic quartz is strengthened when the H2O is accumulated into fluid inclusions and cannot react with the quartz framework. ?? 1984 Springer-Verlag.

Quartz fiber calorimeter

International Nuclear Information System (INIS)

Akchurin, N.; Doulas, S.; Ganel, O.; Gershtein, Y.; Gavrilov, V.; Kolosov, V.; Kuleshov, S.; Litvinsev, D.; Merlo, J.-P.; Onel, Y.; Osborne, D.; Rosowsky, A.; Stolin, V.; Sulak, L.; Sullivan, J.; Ulyanov, A.; Wigmans, R.; Winn, D.

1996-01-01

A calorimeter with optical quartz fibers embedded into an absorber matrix was proposed for the small angle region of the CMS detector at LHC (CERN). This type of calorimeter is expected to be radiation hard and to produce extremely fast signal. Some results from beam tests of the quartz fiber calorimeter prototype are presented. (orig.)

Geochemical constraints on the link between volcanism and plutonism at the Yunshan caldera complex, SE China

Science.gov (United States)

Yan, Lili; He, Zhenyu; Beier, Christoph; Klemd, Reiner

2018-01-01

The Yunshan caldera complex is part of a larger scale, ca. 2000-km-long volcanic-plutonic complex belt in the coastal region of SE China. The volcanic rocks in the caldera complex are characterized by high-silica peraluminous and peralkaline rhyolites associated with an intracaldera porphyritic quartz monzonite pluton. In this study, we present zircon U-Pb, Hf and stable O isotopes along with geochemical data of both volcanic and plutonic rocks to evaluate the potential petrogenetic link between volcanism and plutonism in the Yunshan caldera complex. SHRIMP zircon U-Pb geochronology of both volcanic and plutonic rocks yields almost identical ages ranging from 95.6 to 93.1 Ma. The peraluminous and peralkaline rhyolites show negative anomalies of Sr, P, Ti and Ba and to a lesser extent negative Nb and Ta anomalies, along with positive Rb anomalies and `seagull-like' rare earth element (REE) patterns with negative Eu anomalies and low (La/Yb)N ratios. The intracaldera porphyritic quartz monzonite displays minor negative Rb, Nb, Ta, Sr, P and Ti anomalies and a positive Ba anomaly with REE patterns characterized by relatively high (La/Yb)N ratios and lack significant Eu anomalies. The peraluminous and peralkaline rhyolites and the porphyritic quartz monzonite exhibit consistent ɛ Nd( t) of - 3.7 to - 2.2 and display zircon ɛ Hf( t) values of - 2.1 to 3.7. They further have similar, mantle-like, zircon oxygen isotopic compositions (δ18OVSMOW mainly = 4.63 to 5.76‰). We interpret these observations to be in agreement with a crystal mush model in which the parental magma of the volcanic and plutonic rocks of the Yunshan caldera complex was likely produced by interaction of asthenosphere melts with subduction-influenced enriched mantle wedge. The peralkaline rhyolites are interpreted to represent the most differentiated magma that has subsequently experienced significant fluid-melt interactions, whereas the porphyritic quartz monzonite may be representative of the

The problem of dating quartz 2: Synchrotron generated X-ray excited optical luminescence (XEOL) from quartz

International Nuclear Information System (INIS)

King, G.E.; Finch, A.A.; Robinson, R.A.J.; Taylor, R.P.; Mosselmans, J.F.W.

2011-01-01

The luminescence emission of quartz is used in optically stimulated luminescence dating (OSL), however the precise origins of the emission are unclear. A suite of quartz samples were analysed using X-ray excited optical luminescence (XEOL). Radiation dose effects were observed whereby the UV emissions (3.8 and 3.4 eV) were depleted to the benefit of the red emission (1.9-2.0 eV). Samples were excited at ∼7 keV. Understanding why some quartz emit light more brightly than others will increase the efficiency and precision of OSL analyses. - Highlights: → The X-ray excited optical luminescence (XEOL) emission of quartz is explored. → The XEOL of quartz of different provenances varies. → Radiation dosing causes UV emissions to deplete to the benefit of red emissions. → The 3.8 and 3.4 eV emissions deplete at the same rate. → The quartz luminescence emission exhibits anisotropic effects.

Quartz analysis in gravimetric sampling

International Nuclear Information System (INIS)

Rex, D.A.

1990-01-01

An overview of the methods employed in the assessment of quartz exposure is provided. The principles and some of the problems associated with each method is discussed. The methods reviewed include wet chemical methods, X-ray diffraction and infrared absorption of which the latter two methods are deemed appropriate for analysing quartz on personal gravimetric collected samples. The implications of combining area samples collected over a six month period, and performing only a single quartz analysis rather than separate analyses, are considered. Finally, various options open to mines with regard to their involvement with quartz analysis are also briefly discussed. 35 refs., 6 figs., 1 tab

Radiation-Hard Quartz Cerenkov Calorimeters

International Nuclear Information System (INIS)

Akgun, U.; Onel, Y.

2006-01-01

New generation hadron colliders are going to reach unprecedented energies and radiation levels. Quartz has been identified as a radiation-hard material that can be used for Cerenkov calorimeters of the future experiments. We report from the radiation hardness tests performed on quartz fibers, as well as the characteristics of the quartz fiber and plate Cerenkov calorimeters that have been built, designed, and proposed for the CMS experiment

Zircon U-Pb dating of Maherabad porphyry copper-gold prospect area: evidence for a late Eocene porphyry-related metallogenic epoch in east of Iran

Directory of Open Access Journals (Sweden)

Azadeh Malekzadeh Shafaroudi

2011-04-01

Full Text Available Eastern Iran has great potential for porphyry copper deposits, as a result of its past subduction zone tectonic setting that lead to extensive alkaline to calc-alkaline magmatic activity in Tertiary time. Maherabad is the first porphyry Cu-Au prospecting area which is discovered in eastern Iran. This is related to a succession o f monzonitic to dioritic porphyries stocks that were emplaced within volcanic rocks. Monzonitic porphyries have basic role in mineralization. Hydrothermal alteration zones are well developed including potassic, sericitic-potassic, quartz-sericite-carbonate-pyrite, quartz-carbonate-pyrite, silicified-propylitic, propylitic, carbonate and silicified zones. Mineralization occurs as Disseminated, stockwork and hydrothermal breccia. Based on early stage of exploration, Cu is between 179- 6830 ppm (ave. 3200 ppm and Au is up to 1000 ppb (ave. 570 ppb. This prospect is gold- rich porphyry copper deposit. Laser-ablation U-Pb dating of two samples from ore-related intrusive rocks indicate that these two monzonitic porphyries crystallized at 39.0 ± 0.8 Ma to 38.2 ± 0.8 Ma, within a short time span of less than ca. 1 Ma during the middle Eocene. This provides the first precise ages for metallogenic episode of porphyry-type mineralization. Also, the initial 87Sr/86Sr and (143Nd/144Ndi was recalculated to an age of 39 Ma. Initial 87Sr/86Sr ratios for monzonitic rocks are 0.7047-0.7048. The (143Nd/144Ndi isotope composition are 0.512694-0.512713. Initial ε Nd isotope values 1.45-1.81. Based on isotopic data the magma had originated beyond the continental crust. The study will be used for tectonic-magmatic setting and evolution of eastern Iran. Keywords: Lut block, Middle Eocene, Zircon, Geochronology, Laser ablation ICP-MS,

Post-collisional magmatism and ore-forming systems in the Menderes massif: new constraints from the Miocene porphyry Mo-Cu Pınarbaşı system, Gediz-Kütahya, western Turkey

Science.gov (United States)

Delibaş, Okan; Moritz, Robert; Chiaradia, Massimo; Selby, David; Ulianov, Alexey; Revan, Mustafa Kemal

2017-12-01

The Pınarbaşı Mo-Cu prospect is hosted within the Pınarbaşı intrusion, which is exposed together with the NW-SE-trending Koyunoba, Eğrigöz, and Baklan plutons along the northeastern border of the Menderes massif. The Pınarbaşı intrusion predominantly comprises monzonite, porphyritic granite, and monzodiorite. All units of the Pınarbaşı intrusion have sharp intrusive contacts with each other. The principal mineralization style at the Pınarbaşı prospect is a porphyry-type Mo-Cu mineralization hosted predominantly by monzonite and porphyritic granite. The porphyry type Mo-Cu mineralization consists mostly of stockwork and NE- and EW-striking sub-vertical quartz veins. Stockwork-type quartz veins hosted by the upper parts of the porphyritic granite within the monzonite, are typically enriched in chalcopyrite, molybdenite, pyrite, and limonite. The late NE- and EW-striking normal faults cut the stockwork vein system and control the quartz-molybdenite-chalcopyrite-sphalerite-fahlore-galena veins, as well as molybdenite-hematite-bearing silicified zones. Lithogeochemical and whole-rock radiogenic isotope data (Sr, Nd and Pb) of the host rocks, together with Re-Os molybdenite ages (18.3 ± 0.1 Ma - 18.2 ± 0.1 Ma) reveal that the monzonitic and granitic rocks of the Pınarbaşı intrusion were derived from an enriched lithospheric mantle-lower crust during Oligo-Miocene post-collisional magmatism. The lithospheric mantle was metasomatised by fluids and subducted sediments, and the mantle-derived melts interacted with lower crust at 35-40 km depth. This mechanism explains the Mo and Cu enrichments of the Pınarbaşı intrusion during back-arc magmatism. We conclude that the melt of the Pınarbaşı intrusion could have rapidly ascended to mid-crustal levels, with only limited crustal assimilation along major trans-lithospheric faults as a result of thinning of the middle to upper crust during regional extension, and resulted in the development of porphyry

Quartz glass behavior at ultraviolet spectrum region

International Nuclear Information System (INIS)

Braga, A.F.B.; Barbosa, L.C.; Evora, C.A.P.D.

1990-01-01

Melted quartz ingots were produced from raw materials of different sources. Behavior studies of these three different quartz glass were made at the eletromagnetic spectrum ultraviolet region. The atomic absorption spectroscopy was used as an analysis technique of the alkaline, transition and aluminum metal traces. It was found that the alkaline, transition and aluminum metals impurities present a great influence on the melted quartz spectral behavior at the ultraviolet region. It was stated that measurments at this spectrum region constitute an important characterization technique to natural quartz as well as melted quartz. (author) [pt

Petrogenesis of the Pulang porphyry complex, southwestern China: Implications for porphyry copper metallogenesis and subduction of the Paleo-Tethys Oceanic lithosphere

Science.gov (United States)

Wang, Peng; Dong, Guo-Chen; Zhao, Guo-Chun; Han, Yi-Gui; Li, Yong-Ping

2018-04-01

The Pulang complex is located in the southern segment of the Yidun Arc in the Sanjiang Tethys belt, southwestern China. It is composed of quartz diorite, quartz monzonite and granodiorite porphyries, and hosts the super-large Pulang deposit. This study presents new U-Pb geochronological, major-trace elemental and Sr-Nd-Hf isotopic data to constrain the petrogenesis of the Pulang complex and to evaluate its significances for porphyric mineralization and tectonic evolution of the Paleo-Tethys Ocean. The zircon U-Pb dating yields ages ranging from 208 Ma to 214 Ma. Geochemically, the Pulang complex has high Sr and MgO contents, and high Sr/Y and La/Yb ratios, but low Yb and Y contents, displaying adakitic affinities. However, it has moderate Sr/Y and La/Yb ratios, and high Rb contents (32 to 202 ppm). The Pulang samples plot into the transitional field between adakites and normal arc rocks, differing from typical adakites. It is attributed to the assimilation of 10-15% crustal components. The zircon εHf(t) (-4.6 to -2.5), whole-rock (87Sr/86Sr)i (0.7052 to 0.7102), εNd(t) (-0.62 to 2.12) values and adakitic affinities suggest that the Pulang complex was derived from a basaltic slab-melt source and reacted with peridotite during ascending through an enriched asthenospheric mantle wedge. The basaltic slab-melts likely resulted from the westward subduction of the Ganzi-Litang oceanic plate (a branch of the Paleo-Tethys). As far as the metallogenesis concerned, three factors in mineralization are proposed in this paper. The country rock, quartz diorite porphyry, has higher Cu contents than the mantle (average 30 ppm), suggesting that ore-forming magma was derived from a Cu-enriched source, which is a crucial contribution to the late mineralization to form the super-large Pulang deposit. In addition, the barren quartz diorite, granodiorite, and ore-bearing quartz monzonite porphyries are all characterized by high oxygen fugacity, which is another important factor for the

Experimental diagenesis of quartz with petroleum; Diagenese experimentale du quartz en presence d'hydrocarbures

Energy Technology Data Exchange (ETDEWEB)

Teinturier, St.

2002-11-01

Quartz cementation has a great impact on petroleum reservoir quality by controlling the porosity and thus the gas or oil storage. However, the possible cementation of quartz during petroleum emplacement is still debated. In most cases, the reconstitution and the understanding of diagenetic processes is based on fluid inclusions studies. However, many questions concerning the representativeness and the reading of the fluid inclusions still remains misunderstood. The experiments were carried out in a silica{+-}water{+-}salts{+-}oil{+-}gas system with the objective to simulate the siliceous diagenesis of natural petroleum reservoirs and to better understand the mechanisms of fluid inclusions formation and quartz cementation in a water and/or petroleum system. Calibration curves have been established using Raman micro-spectroscopy and synthetic reference inclusions to calculate the methane content of aqueous inclusions in the H{sub 2}O-CH{sub 4}-NaCl system. A quantitative procedure for FT-IR micro-spectrometry has been developed to obtain, from individual petroleum fluid inclusions, mole % concentrations of methane, alkanes and carbon dioxide as constraints to thermodynamic modelling. Synthetic aqueous inclusions were created within quartz micro-fractures, with methane (from 150 deg C-200 bar), with petroleum (from 184 deg C-163 bar) and inside quartz overgrowth with the presence of hydrocarbons (from 277 deg C-300 bar). Synthetic petroleum inclusions were created with different water/oil ratios (W/O) within quartz micro-fractures (0quartz overgrowth (10

Study of seed for synthetical quartz

International Nuclear Information System (INIS)

Suzuki, C.K.; Torikai, D.

1988-01-01

Natural quartz blocks for seed (synthetic quartz technology) were studied by using various characterization techniques, such as X-ray topography, optical micrography, inspectoscopy, polariscopy and conoscopy, and etching. One of the most commonly found defect is the electrical or Dauphine twin. In The present research, we have developed a methodology to obtain a highly perfect seed for the synthetic quartz industries. (author) [pt

Quartz gauge response in ion radiation

International Nuclear Information System (INIS)

Taylor, P.E.; Gilbert, P.H.; Kernthaler, C.; Anderson, M.U.

1995-01-01

This paper describes recent work to make high quality quartz gauge (temporal and spatial) shock wave measurements in a pulsed ion beam environment. Intense ion beam radiation, nominally 1 MeV protons, was deposited into material samples instrumented with shunted quartz gauges adjacent to the ion deposition zone. Fluence levels were chosen to excite three fundamentally different material response modes (1) strong vapor, (2) combined vapor and melt phase and (3) thermoelastic material response. A unique quartz gauge design was utilized that employed printed circuit board (PCB) technology to facilitate electrical shielding, ruggedness, and fabrication at sign e meeting the essential one dimensional requirements of the characterized Sandia shunted quartz gauge. Shock loading and unloading experiments were conducted to evaluate the piezoelectric response of the coupled quartz gauge/PCB transducer. High fidelity shock wave profiles were recorded at the three ion fluence levels providing dynamic material response data for vapor, melt and solid material phases

Growth of plutons by incremental emplacement of sheets in crystal-rich host: Evidence from Miocene intrusions of the Colorado River region, Nevada, USA

Science.gov (United States)

Miller, C.F.; Furbish, D.J.; Walker, B.A.; Claiborne, L.L.; Koteas, G.C.; Bleick, H.A.; Miller, J.S.

2011-01-01

crystal-laden host is important in pluton construction. The dominant granite unit of the Spirit Mountain batholith displays only subtle internal contacts. However, ages and elemental zoning in zircons demonstrate a protracted history of almost 2 million years, major fluctuations in T and host melt chemistry, and mixing of strongly contrasting populations of magmatic zircon in single samples. We interpret this to reflect reactivation of rigid sponge and mush and entrainment of earlier-formed crystals, and we infer that this was in response to granitic replenishment. Much of the smaller Aztec Wash pluton comprises interlayered cumulate-textured quartz monzonite and mafic sheets. The latest phase of pluton emplacement is marked by numerous thick, fine-grained granite "sills" that intruded the subhorizontal quartz monzonite sheets. Contacts between granite and quartz monzonite are "soft," highly irregular on cm-dm scale with coarse xenocrysts from the quartz monzonite entrained in the fine-grained granite. We interpret the granite replenishments to have spread laterally within crystal-rich, melt-bearing quartz monzonite beneath rigid mafic sheets. In this case, clear evidence for the emplacement process is fortuitously preserved because the granite was emplaced in the waning stage of the thermal lifetime of the pluton, and because the mafic sheets enhance the strength contrast and make the geometry more visible. Similar "sills" of fine-grained granite were also preserved during the late stages of the history of the Spirit Mountain batholith. ?? 2009 Elsevier B.V.

A Silurian-early Devonian slab window in the southern Central Asian Orogenic Belt: Evidence from high-Mg diorites, adakites and granitoids in the western Central Beishan region, NW China

Science.gov (United States)

Zheng, Rongguo; Xiao, Wenjiao; Li, Jinyi; Wu, Tairan; Zhang, Wen

2018-03-01

The Beishan orogenic belt is a key region for deciphering the accretionary processes of the southern Central Asian Orogenic Belt. Here in this paper we present new zircon U-Pb ages, bulk-rock major and trace element, and zircon Hf isotopic data for the Baitoushan, and Bagelengtai plutons in the western Central Beishan region to address the accretionary processes. The Baitoushan pluton consists of quartz diorites, monzonites and K-feldspar granites, with zircon LA-ICP-MS U-Pb ages of 435 Ma, 421 Ma and 401 Ma, respectively. The Baitoushan quartz diorites and quartz monzonites exhibit relatively high MgO contents and Mg# values (63-72), display enrichments in LILEs and LREEs, and exhibit high Ba (585-1415 ppm), Sr (416-570 ppm) and compatible element (such as Cr and Ni) abundances, which make them akin to typical high-Mg andesites. The Baitoushan quartz diorites and quartz monzonites were probably generated by the interaction of subducted oceanic sediment-derived melts and mantle peridotites. The Baitoushan K-feldspar granites are ascribed to fractionated I-type granites with peraluminous and high-K calc-alkaline characteristics. They exhibit positive εHf(t) values (2.43-7.63) and Mesoproterozoic-Neoproterozoic zircon Hf model ages (0.92-1.60 Ga). Those early Devonian granites, including Baitoushan K-feldspar granite and Gongpoquan leucogranites (402 Ma), are derived from melting of the mafic lower crust and/or sediments by upwelling of hot asthenospheric mantle. The Bagelengtai granodiorites exhibit similar geochemical signatures with that of typical adakites, with a zircon SHRIMP U-Pb age of 435 Ma. They exhibit relatively high Sr (502-628 ppm) and Al2O3 (16.40-17.40 wt.%) contents, and low MgO (1.02-1.29 wt.%), Y (3.37-6.94 ppm) and HREEs contents, with relatively high Sr/Y and (La/Yb)N ratios. The Bagelengtai granodiorites were derived from partial melting of subducted young oceanic crust, with significant contributions of subducted sediments, subsequently

Positron states and nanoobjects in proton-irradiated quartz single crystals: Positronium atom in quartz

International Nuclear Information System (INIS)

Grafutin, V. I.; Zaluzhnyi, A. G.; Timoshenkov, S. P.; Britkov, O. M.; Ilyukhina, O. V.; Myasishcheva, G. G.; Prokop'ev, E. P.; Funtikov, Yu. V.

2008-01-01

The influence of proton bombardment and metal atom impurities on the structure of quartz single crystals has been studied. The related defects have been studied using positron annihilation spectroscopy (angular correlation of positron-annihilation photons), acoustic absorption, and optical absorption measurements. It is shown that the presence of a narrow component f in the angular distribution of annihilation photons (ADAP), which is related to the formation of parapositronium, determines a high sensitivity of this method with respect to features of the crystal structure of quartz. It is established that the defectness of the structure of irradiated quartz crystals can be characterized by the ratio f/f 0 of the relative intensities of narrow components in the ADAP curves measured before (f 0 ) and after (f) irradiation. Any process leading to a decrease in the probability of positronium formation (e.g., positron loss as a result of the trapping on defects and the interaction with impurity atoms and lattice distortions) decreases the intensity of the narrow component. Based on the ADAP data, estimates of the radii and concentrations of nanodefects in quartz have been obtained and their variation upon annealing at temperatures up to T = 873 K has been studied

Quartz crystal reinforced quartz glass by spark plasma sintering

International Nuclear Information System (INIS)

Torikai, D.; Barazani, B.; Ono, E.; Santos, M.F.M.; Suzuki, C.K.

2011-01-01

The Spark Plasma Sintering presents fast processing time when compared to conventional sintering techniques. This allows to control the grain growth during sintering as well as the diffusion rate of a multi-material compounds, and make possible obtainment of functionally graded materials and nanostructured compounds. Powders of high purity silica glass and crystalline silica were sintered in a SPS equipment at temperatures around 1350° C, i.e., above the softening temperature of silica glass and below the melting temperature of quartz crystal. As a result, glass ceramics with pure silica glass matrix reinforced with crystalline alpha-quartz grains were fabricated at almost any desired range of composition, as well as controlled size of the crystalline reinforcement. X-ray diffraction and density measurements showed the possibility to manufacture a well controlled density and crystallinity glass-ceramic materials. (author)

Additive manufacturing of transparent fused quartz

Science.gov (United States)

Luo, Junjie; Hostetler, John M.; Gilbert, Luke; Goldstein, Jonathan T.; Urbas, Augustine M.; Bristow, Douglas A.; Landers, Robert G.; Kinzel, Edward C.

2018-04-01

This paper investigates a filament-fed process for additive manufacturing (AM) of fused quartz. Glasses such as fused quartz have significant scientific and engineering applications, which include optics, communications, electronics, and hermetic seals. AM has several attractive benefits such as increased design freedom, faster prototyping, and lower processing costs for small production volumes. However, current research into glass AM has focused primarily on nonoptical applications. Fused quartz is studied here because of its desirability for use in high-quality optics due to its high transmissivity and thermal stability. Fused quartz filaments are fed into a CO2 laser-generated molten region, smoothly depositing material onto the workpiece. Spectroscopy and pyrometry are used to measure the thermal radiation incandescently emitted from the molten region. The effects of the laser power and scan speed are determined by measuring the morphology of single tracks. Thin walls are printed to study the effects of layer-to-layer height. This information is used to deposit solid pieces including a cylindrical-convex shape capable of focusing visible light. The transmittance and index homogeneity of the printed fused quartz are measured. These results show that the filament-fed process has the potential to print transmissive optics.

Quartz-Enhanced Photoacoustic Spectroscopy: A Review

Science.gov (United States)

Patimisco, Pietro; Scamarcio, Gaetano; Tittel, Frank K.; Spagnolo, Vincenzo

2014-01-01

A detailed review on the development of quartz-enhanced photoacoustic sensors (QEPAS) for the sensitive and selective quantification of molecular trace gas species with resolved spectroscopic features is reported. The basis of the QEPAS technique, the technology available to support this field in terms of key components, such as light sources and quartz-tuning forks and the recent developments in detection methods and performance limitations will be discussed. Furthermore, different experimental QEPAS methods such as: on-beam and off-beam QEPAS, quartz-enhanced evanescent wave photoacoustic detection, modulation-cancellation approach and mid-IR single mode fiber-coupled sensor systems will be reviewed and analysed. A QEPAS sensor operating in the THz range, employing a custom-made quartz-tuning fork and a THz quantum cascade laser will be also described. Finally, we evaluated data reported during the past decade and draw relevant and useful conclusions from this analysis. PMID:24686729

Quartz-Enhanced Photoacoustic Spectroscopy: A Review

Directory of Open Access Journals (Sweden)

Pietro Patimisco

2014-03-01

Full Text Available A detailed review on the development of quartz-enhanced photoacoustic sensors (QEPAS for the sensitive and selective quantification of molecular trace gas species with resolved spectroscopic features is reported. The basis of the QEPAS technique, the technology available to support this field in terms of key components, such as light sources and quartz-tuning forks and the recent developments in detection methods and performance limitations will be discussed. Furthermore, different experimental QEPAS methods such as: on-beam and off-beam QEPAS, quartz-enhanced evanescent wave photoacoustic detection, modulation-cancellation approach and mid-IR single mode fiber-coupled sensor systems will be reviewed and analysed. A QEPAS sensor operating in the THz range, employing a custom-made quartz-tuning fork and a THz quantum cascade laser will be also described. Finally, we evaluated data reported during the past decade and draw relevant and useful conclusions from this analysis.

Aberrant thermoluminescence dates obtained from primary volcanic quartz

International Nuclear Information System (INIS)

Guerin, Gilles; Samper, Agnes

2007-01-01

This study deals with the dating by thermoluminescence (TL) of quartz from six volcanic formations of the Saint Lucia Island (Lesser Antilles Arc). Quartz microcrystals up to one millimetre in size were extracted from dacites and pumice flows and prepared in a way similar to the well-known inclusion technique. The TL properties of these quartz were used to estimate apparent palaeodoses using the multi-aliquot protocol. The quartz TL was studied in three different spectral domains: red, green and ultraviolet/blue. The calculated annual dose-rates yielded a set of 18 age-estimates. For some samples complementary dates were obtained using high temperature TL (HTTL) of plagioclase feldspars. These latter dates combined with previously determined radiocarbon and unspiked K-Ar dates were used to explore the validity of ages computed from the TL of quartz. Individual values for quartz appear to be scattered and do not match ages deduced from 14 C, unspiked K-Ar or HTTL on plagioclase dates. These results indicate that when conventional TL methodologies derived from the inclusion method are applied to volcanic quartz major dating problems are to be expected

Aberrant thermoluminescence dates obtained from primary volcanic quartz

Energy Technology Data Exchange (ETDEWEB)

Guerin, Gilles [Laboratoire des Sciences du Climat et de l' Environnement, CEA-CNRS, avenue de la Terrasse, 91191 Gif-sur-Yvette (France)], E-mail: gilles.guerin@u-psud.fr; Samper, Agnes [Laboratoire de geochronologie multitechnique (UPS-IPGP), Universite de Paris-Sud Orsay, 91405 Orsay Cedex (France)

2007-10-15

This study deals with the dating by thermoluminescence (TL) of quartz from six volcanic formations of the Saint Lucia Island (Lesser Antilles Arc). Quartz microcrystals up to one millimetre in size were extracted from dacites and pumice flows and prepared in a way similar to the well-known inclusion technique. The TL properties of these quartz were used to estimate apparent palaeodoses using the multi-aliquot protocol. The quartz TL was studied in three different spectral domains: red, green and ultraviolet/blue. The calculated annual dose-rates yielded a set of 18 age-estimates. For some samples complementary dates were obtained using high temperature TL (HTTL) of plagioclase feldspars. These latter dates combined with previously determined radiocarbon and unspiked K-Ar dates were used to explore the validity of ages computed from the TL of quartz. Individual values for quartz appear to be scattered and do not match ages deduced from {sup 14}C, unspiked K-Ar or HTTL on plagioclase dates. These results indicate that when conventional TL methodologies derived from the inclusion method are applied to volcanic quartz major dating problems are to be expected.

Age and origin of anorthosites, charnockites, and granulites in the Central Virginia Blue Ridge: Nd and Sr isotopic evidence

Science.gov (United States)

Pettingill, H.S.; Sinha, A.K.; Tatsumoto, M.

1984-01-01

Rb-Sr isotopic data for anorthosites, charnockites, ferrodioritic to quartz monzonitic plutons, and high-grade gneisses of the Blue Ridge of central Virginia show evidence of post-emplacement metamorphism, but in some cases retain Grenville ages. The Pedlar River Charnockite Suite yields an isochron age of 1021 +/-36 Ma, (initial 87Sr/86Sr ratio of 0.7047 +/-6), which agrees with published U-Pb zircon ages. Five samples of that unit which contain Paleozoic mylonitic fabrics define a regression line of 683 Ma, interpreted as a mixing line with no age significance. Samples of the Roseland Anorthosite Complex show excessive scatter on a Rb-Sr evolution diagram probably due to Paleozoic (475 m.y.) metamorphism. Data from the ferrodioritic to quartz monzonitic plutons of the area yield an age of 1009 +/-26 Ma (inital ratio=0.7058 +/-4), which is in the range of the U-Pb zircon ages of 1000-1100 Ma. The Stage Road Layered Gneiss yields an age of 1147 +/-34 Ma (initial ratio of 0.7047 +/- 5). Sm-Nd data for the Pedlar River Charnockite Suite reflect a pre-Grenville age of 1489 +/-118 Ma (e{open}Nd=+6.7 +/-1.2). Data for the Roseland Anorthosite Complex and the ferrodioritic to quartz monzonitic plutons yield Grenville isochron ages of 1045 +/44 Ma (e{open}Nd=+1.0 +/-0.3) and 1027 +/-101 Ma (e{open}Nd=+1.4 +/-1.0), respectively. Two Roseland Anorthosite samples plot far above the isochron, demonstrating the effects of post-emplacement disturbance of Sm-Nd systematics, while mylonitized Pedlar River Charnockite Suite samples show no evidence of Sm-Nd redistribution. The disparity of the Sm-Nd age and other isotopic ages for the Pedlar River Charnockite Suite probably reflects a Sm-Nd "source" age, suggesting the presence of an older crust within this portion of the ca. 1 Ga old basement. ?? 1984 Springer-Verlag.

Production of quartz plates for CMS-CASTOR Experiment

CERN Document Server

Adiguzel, Aytul; Ayhan, Aydin; Bakirci, Mustafa Numan; Basegmez, Suzan; Beaumont, Willem; Borras, Kerstin; Campbell, Alan; De Paula Carvalho, W; Çerçi, Salim; De Jesus Damiao, Dilson; Dogangün, O; Dumanoglu, Isa; d'Enterria, David; Erchov, Y; Eskut, Eda; Figueiredo, D; Girgis, Semiray; Göttlicher, P; Gouskos, Loukas; Gurpinar, Emine; Hos, Ilknur; Katkov, Igor; Katsas, Panagiotis; Khein, Lev; Knutsson, Albert; Kuznetsov, Andrey; Lebeau, Michel; Van Mechelen, Pierre; Muhl, Carsten; Musienko, Yuri; Ochesanu, Silvia; Onengüt, G; Onengut, G Jr; Ozdemir, Kadri; Panagiotou, Apostolos; Polatoz, A; Ripert, Marion; Shileev, K; Sogut, Kenan; Tiflov, B TaliV; Kayis-Topaksu, A; Uzun, Dilber

2008-01-01

Light transmission rate performance of $102$ irradiated quartz samples was measured to select the best quartz plates for CMS-CASTOR calorimeter. All the produced quartz plates were originally used in a previous CERN experiment, DELPHI. Three different doses of $^{60}$Co source were used with the collaboration of PSI (Paul Scherrer Institute, Villigen PSI, Switzerland.) to study the transmission rate performance of the quartz samples after irradiation for different incident light, ranging from $250$ to $700$ nm in $5$ nm increasing steps. All samples show different decrease in the rate with wavelength for different doses. Three different steps were followed before irradiation to find out the best way of cleaning the original DELPHI Cu/Cr tracks on the samples. Results of these measurements presented here correspond to the quartz plates that will be used in one hadronic sector of CASTOR calorimeter until end of 2008. For the full calorimeter new quartz plates will be installed. We also present the light transmi...

Mechanical and optical nanodevices in single-crystal quartz

Science.gov (United States)

Sohn, Young-Ik; Miller, Rachel; Venkataraman, Vivek; Lončar, Marko

2017-12-01

Single-crystal α-quartz, one of the most widely used piezoelectric materials, has enabled a wide range of timing applications. Owing to the fact that an integrated thin-film based quartz platform is not available, most of these applications rely on macroscopic, bulk crystal-based devices. Here, we show that the Faraday cage angled-etching technique can be used to realize nanoscale electromechanical and photonic devices in quartz. Using this approach, we demonstrate quartz nanomechanical cantilevers and ring resonators featuring Qs of 4900 and 8900, respectively.

A High Sensitivity Preamplifier for Quartz Tuning Forks in QEPAS (Quartz Enhanced PhotoAcoustic Spectroscopy Applications

Directory of Open Access Journals (Sweden)

Tomasz Starecki

2017-11-01

Full Text Available All the preamplifiers dedicated for Quartz Enhanced PhotoAcoustic Spectroscopy (QEPAS applications that have so far been reported in the literature have been based on operational amplifiers working in transimpedance configurations. Taking into consideration that QEPAS sensors are based on quartz tuning forks, and that quartz has a relatively high voltage constant and relatively low charge constant, it seems that a transimpedance amplifier is not an optimal solution. This paper describes the design of a quartz QEPAS sensor preamplifier, implemented with voltage amplifier configuration. Discussion of an electrical model of the circuit and preliminary measurements are presented. Both theoretical analysis and experiments show that use of the voltage configuration allows for a substantial increase of the output signal in comparison to the transimpedance circuit with the same tuning fork working in identical conditions. Assuming that the sensitivity of the QEPAS technique depends directly on the properties of the preamplifier, use of the voltage amplifier configuration should result in an increase of QEPAS sensitivity by one to two orders of magnitude.

A High Sensitivity Preamplifier for Quartz Tuning Forks in QEPAS (Quartz Enhanced PhotoAcoustic Spectroscopy) Applications.

Science.gov (United States)

Starecki, Tomasz; Wieczorek, Piotr Z

2017-11-03

All the preamplifiers dedicated for Quartz Enhanced PhotoAcoustic Spectroscopy (QEPAS) applications that have so far been reported in the literature have been based on operational amplifiers working in transimpedance configurations. Taking into consideration that QEPAS sensors are based on quartz tuning forks, and that quartz has a relatively high voltage constant and relatively low charge constant, it seems that a transimpedance amplifier is not an optimal solution. This paper describes the design of a quartz QEPAS sensor preamplifier, implemented with voltage amplifier configuration. Discussion of an electrical model of the circuit and preliminary measurements are presented. Both theoretical analysis and experiments show that use of the voltage configuration allows for a substantial increase of the output signal in comparison to the transimpedance circuit with the same tuning fork working in identical conditions. Assuming that the sensitivity of the QEPAS technique depends directly on the properties of the preamplifier, use of the voltage amplifier configuration should result in an increase of QEPAS sensitivity by one to two orders of magnitude.

Quartz exposure and increased respiratory symptoms among coal ...

African Journals Online (AJOL)

Quartz has been an inevitable composition of different type of coal mined. The quartz exposures among coalmine workers has been attributed to activities such as cutting the adjacent rock, the roof, the floor and the intrusions. Objective: The aim of the study is to determine the associations between quartz exposures and ...

Microwave GaAs Integrated Circuits On Quartz Substrates

Science.gov (United States)

Siegel, Peter H.; Mehdi, Imran; Wilson, Barbara

1994-01-01

Integrated circuits for use in detecting electromagnetic radiation at millimeter and submillimeter wavelengths constructed by bonding GaAs-based integrated circuits onto quartz-substrate-based stripline circuits. Approach offers combined advantages of high-speed semiconductor active devices made only on epitaxially deposited GaAs substrates with low-dielectric-loss, mechanically rugged quartz substrates. Other potential applications include integration of antenna elements with active devices, using carrier substrates other than quartz to meet particular requirements using lifted-off GaAs layer in membrane configuration with quartz substrate supporting edges only, and using lift-off technique to fabricate ultrathin discrete devices diced separately and inserted into predefined larger circuits. In different device concept, quartz substrate utilized as transparent support for GaAs devices excited from back side by optical radiation.

Experimental study of quartz inclusions in garnet at pressures up to 3.0 GPa: evaluating validity of the quartz-in-garnet inclusion elastic thermobarometer

Science.gov (United States)

Thomas, Jay B.; Spear, Frank S.

2018-05-01

Garnet crystals with quartz inclusions were hydrothermally crystallized from oxide starting materials in piston-cylinder apparatuses at pressures from 0.5 to 3 GPa and temperatures ranging from 700 to 800 °C to study how entrapment conditions affect remnant pressures of quartz inclusions used for quartz-in-garnet (QuiG) elastic thermobarometry. Systematic changes of the 128, 206 and 464 cm-1 Raman band frequencies of quartz were used to determine pressures of quartz inclusions in garnet using Raman spectroscopy calibrations that describe the P-T dependencies of Raman band shifts for quartz under hydrostatic pressure. Within analytical uncertainties, inclusion pressures calculated for each of the three Raman band frequencies are equivalent, which suggests that non-hydrostatic stress effects caused by elastic anisotropy in quartz are smaller than measurement errors. The experimental quartz inclusions have pressures ranging from - 0.351 to 1.247 GPa that span the range of values observed for quartz inclusions in garnets from natural rocks. Quartz inclusion pressures were used to model P-T conditions at which the inclusions could have been trapped. The accuracy of QuiG thermobarometry was evaluated by considering the differences between pressures measured during experiments and pressures calculated using published equation of state parameters for quartz and garnet. Our experimental results demonstrate that Raman measurements performed at room temperature can be used without corrections to estimate garnet crystallization pressures. Calculated entrapment pressures for quartz inclusions in garnet are less than 10% different from pressures measured during the experiments. Because the method is simple to apply with reasonable accuracy, we expect widespread usage of QuiG thermobarometry to estimate crystallization conditions for garnet-bearing silicic rocks.

Characterization of color centers in quartz induced by gamma irradiation

International Nuclear Information System (INIS)

Guttler, Rainer A.S.

2009-01-01

The availability of gamma ray irradiators in Brazil increased the possibilities of treatments of gemstones for color enhancements. One of the minerals with a very high potential of these treatments is quartz, a very widespread mineral with much colored commercial varieties. Quartz occurs in Brazil mainly in two geological environments, called pegmatitic and hydrothermal. The detailed mechanism of color center formation of these two types of quartz will be investigated by spectroscopic and chemical analysis. Until yet, it can be shown that due to chemical differences of the nature of mineral forming fluids, the two types behave differently. All quartzes contain mainly traces of Iron, Aluminum, Lithium and some amounts of Water. The quartz of hydrothermal origin incorporated much structurally bound water, and despite some similarities with the chemical composition of pegmatitic quartz, this high water content is the reason for the formation of Silanol radicals, giving the green color to the quartz. The main difference in chemical composition of pegmatitic quartz is the presence of higher amounts of Al and Li , responsible for the brownish and yellowish colors formed by irradiation. Since each pegmatite is different, the quartz will behave differently. This explains the formation of the famous 'Green Gold' of quartz from Sao Jose da Safira , and the more yellowish, Citrine type, color of quartz from the Coluna deposit, near Itamarandiba, Minas Gerais. (author)

Characterization of color centers in quartz induced by gamma irradiation

Energy Technology Data Exchange (ETDEWEB)

Guttler, Rainer A.S., E-mail: rainersg@usp.b [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias; Enokihara, Cyro T.; Rela, Paulo R., E-mail: prela@ipen.b, E-mail: cteiti@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

2009-07-01

The availability of gamma ray irradiators in Brazil increased the possibilities of treatments of gemstones for color enhancements. One of the minerals with a very high potential of these treatments is quartz, a very widespread mineral with much colored commercial varieties. Quartz occurs in Brazil mainly in two geological environments, called pegmatitic and hydrothermal. The detailed mechanism of color center formation of these two types of quartz will be investigated by spectroscopic and chemical analysis. Until yet, it can be shown that due to chemical differences of the nature of mineral forming fluids, the two types behave differently. All quartzes contain mainly traces of Iron, Aluminum, Lithium and some amounts of Water. The quartz of hydrothermal origin incorporated much structurally bound water, and despite some similarities with the chemical composition of pegmatitic quartz, this high water content is the reason for the formation of Silanol radicals, giving the green color to the quartz. The main difference in chemical composition of pegmatitic quartz is the presence of higher amounts of Al and Li , responsible for the brownish and yellowish colors formed by irradiation. Since each pegmatite is different, the quartz will behave differently. This explains the formation of the famous 'Green Gold' of quartz from Sao Jose da Safira , and the more yellowish, Citrine type, color of quartz from the Coluna deposit, near Itamarandiba, Minas Gerais. (author)

Surface complexation modelling: Experiments on sorption of nickel on quartz, goethite and kaolinite and preliminary tests on sorption of thorium on quartz

Energy Technology Data Exchange (ETDEWEB)

Puukko, E.; Hakanen, M. [Univ. of Helsinki (Finland). Dept. of Chemistry. Lab. of Radiochemistry

1997-09-01

The aim of the work was to study the sorption behaviour of Ni on quartz, goethite and kaolinite at different pH levels and in different electrolyte solutions of different strength. In addition preliminary experiments were made to study the sorption of thorium on quartz. The MUS quartz and Nilsiae quartz were analysed for MnO{sub 2} by neutron activation analysis (NAA) and the experimental results were modelled with the HYDRAQL computer model. 9 refs.

Geology and geochemistry of giant quartz veins from the ...

Indian Academy of Sciences (India)

Numerous younger thin quartz veins with somewhat similar orientation cut across the giant quartz .... Angular fragments of quartz are set in ... places along grain boundaries. ... Oxide values are in wt%, and trace element concentrations are.

Identifying well-bleached quartz using the different bleaching rates of quartz and feldspar luminescence signals

DEFF Research Database (Denmark)

Murray, A.S.; Thomsen, Kristina Jørkov; Masuda, N.

2012-01-01

When dating older sedimentary deposits using quartz, there are no unambiguous methods for identifying the presence of incomplete bleaching. Current statistical analysis of dose distributions depends entirely on the assumption that incomplete bleaching and mixing are the main causes of any excess...... dispersion in the distribution; the only existing way to test this assumption is using independent age control. Here we suggest a new approach to this question, based on the differential bleaching rates of quartz and feldspar luminescence signals. We first present data that confirm the differences...... in relative bleaching rates of quartz optically stimulated luminescence (OSL) and feldspar luminescence stimulated at 50 °C by infrared light (IR50) and feldspar luminescence stimulated at 290 °C by infrared light after a stimulation at 50 °C (pIRIR290), and use recently deposited samples to determine...

Live Site Demonstration Munitions Response Program Site UXO 01 at Marine Corps Air Ground Combat Center (MCAGCC) Twentynine Palms, California

Science.gov (United States)

2015-11-01

unconsolidated deposits of eolian sand, alluvial sands and gravels, and lacustrine silts, clays, and evaporates in playa lakes. The near-surface...adjacent lacustrine soils 27 of the playa lake (i.e., Mesquite Lake) and the outcropping quartz monzonite bedrock of the Bullion Mountains. The Bullion...the geophysical travelled between investigation grids. One target (320) was a no contact, meaning the dig team couldn’t find the particular item

Red and blue colouration of thermoluminescence from natural quartz sands

Energy Technology Data Exchange (ETDEWEB)

Hashimoto, T; Hayashi, Y; Koyanagi, A; Yokosaka, K; Kimura, K

1986-01-01

Quartz extracts, from a pegmatite rock, volcanic ashes and beach sands, were exposed to X-rays or gamma-rays upto 8.8kGy. The irradiated sands were observed through a thermoluminescence colour image technique (abbreviated to TLCI by the authors) using highly sensitive colour photographic system. The quartz sands from volcanic ash layers, containing ..beta..-quartz (mineralized at high temperature), always indicate a red TLCI, whereas the quartz rocks from pegmatite origin and granite strata, containing ..cap alpha..-quartz (mineralized at low temperature), gave a typical blue TLCI, being consistent with the well known quartz TL colour. Quartz fractions from the beach sands showed a mixture of both red and blue TLCI, probably reflecting the respective mixtures of ..beta..-(in their origin) and ..cap alpha..-quartz fractions along the riverside area. The search using X-ray diffractometry and instrumental neutron activation analysis proved that the cause of distinctly different colourations was attributable to the impurity atoms: light rare earth elements (Eu and/or Sm) bringing on red TLCI, while structural defects yielding the blue TLCI).

Gamma irradiation of quartz from Pannier basin, South America

Energy Technology Data Exchange (ETDEWEB)

Enokihara, Cyro T.; Rela, Paulo R. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)], E-mail: cteiti@ipen.br, E-mail: prela@ipen.br; Guttler, Rainer A.S. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias

2007-07-01

The use of gamma radiation to induce or enhance color centers in gemstones is a widespread technique and applied worldwide on a industrial scale since at least 1970. The presence of defects and defect structures in quartz from a border region of southern Brazil and Uruguay are the reason for the creation of a new color variety of quartz called 'Prasiolite' in the gem trade. This quartz has a pleasant green color produced by gamma irradiation. The procedures of irradiation at IPEN show that the activation of these color producing defects can be monitored by detailed chemical and spectroscopic analysis. For the first time UV-VIS-NIR spectra of this new color variety of quartz are shown. They revealed special features of these quartz crystals coming from basaltic terranes of the Parana Basin. Contrary to most specimen of quartz from other parts of Brazil, they have such a high water and OH content that they resemble more chalcedony or opal, but not highly crystalline quartz specimens. The cause of the color are broken bonds of Si-OH defining the so-called dangling bonds. (author)

TL response to quartz and aluminum oxide grain for α-irradiation

International Nuclear Information System (INIS)

Pan Baolin; Wei Mingjian; Li Dongxu; Liu Zhaowen; Liu Chao; Zhao Shiyuan

2009-01-01

Thermoluminescence (TL) response for an α-ray irradiation system ( 241 Am) was examined with quartz grains of 11-40 μm. Quartz grains of different sizes, i.e. 137 Cs), before they were irradiated to different doses by the α-ray irradiation system. TL response to the quartz grain samples was measured. TL response of the quartz grains smaller than 4 μm and 11-40 μm to α-ray irradiation is the best, as the α-rays cannot penetrate quartz larger than 40 μm. The TL response characteristic is related with quartz grain surface area. TL responses to α-irradiation of 11-40 μm quartz and aluminum oxide grains were compared. The α-irradiation TL response of aluminum oxide (330 degree C) is better than the quartz (375 degree C). (authors)

Radiation resistivity of quartz core fiber, 3

International Nuclear Information System (INIS)

Gozen, Toshikazu; Suzuki, Toshiya; Hayashi, Tokuji; Tanaka, Hiroyuki; Okamoto, Shinichi.

1985-01-01

Radiation resistance characteristics were evaluated for a multi-mode quartz core fiber in low temperature region together with photobleaching effect depending on the incident light power and dependency on the wavelength of measuring rays. This report describes the results of the abovementioned items and the next step study of trial manufacturing of a pure-quartz single-mode fiber for the employment of longer wavelength rays and greater capacity in light transmission communication system. Quartz core fiber specimens were irradiated by 60 Co γ-ray source at -55 deg C to 80 deg C in a constant temperature bath and light transmission loss was determined under irradiation conditions. Low temperature characteristics were superior in an MRT (modified rod-in tube) pure quartz fiber prepared by the plasma method as compared to VAD quartz and Ge-GI fibers. The MRT fiber showed better quality than the Ge-GI fiber also in the photobleaching effect examination. As for the wavelength dependency, light transmission loss of the MRT fiber was less than that of the Ge-GI fiber. The MRT fiber also showed a superior quality in the wide range of irradiation temperatures. Based on the above-mentioned understandings, a pure-quartz single-mode fiber of both BF 3 -doped and F-doped cladding types were developed for longer wavelengths uses. The fibers could attain low light transmission loss of less than 1.0 dB/km at 1.30 μm of wavelength. At the standpoint of radiation resistivity, the BF 3 -doped fiber was found superior. (Takagi, S.)

Kr-Ar and Rb-Sr dating and the genesis of tungsten at the Clea tungsten skarn property, Selwyn Mountains, Yukon Territory

International Nuclear Information System (INIS)

Godwin, C.I.; Armstrong, R.L.; Tompson, K.M.

1980-01-01

Tungsten skarn deposits on the Clea property in the Selwyn Mountains, Y.T., are related genetically to a quartz monzonite stock, about 500 metres in diameter at the surface. Lower Paleozoic sedimentary rocks are metamorphosed for a distance of 3 km from the stock. Tugnsten-bearing skarn mineralization within the altered sedimentary rocks is of two types: sulphide-rich pods and calc-silicate beds. The most significant sheelite concentration is in calc-silicate beds near or adjacent to the quartz monzonite stock. Discordant K-Ar and Rb-Sr isotopic dates indicate that the stock is probably of early Late Cretaceous age, 94 Ma or slightly older, and that it cooled slowly. High initial 87 Sr/ 86 Sr ratios and disequilibrium relationships between K-feldspar phenocrysts and groundmass minerals in the porphyritic phase of the granite rock, and between different granite rock specimens, indicate contamination of crystallizing magma by old sialic continental crust which extends westward under the Selwyn Basin. This study is significant to regional tungsten exploration. Granite rocks associated with tungsten deposits, in this part of the Canadian Cordillera at least, appear to have specific isotope characteristics that indicate they were generated at a specific time and in a particular way. (auth)

Fabrication of a novel quartz micromachined gyroscope

Science.gov (United States)

Xie, Liqiang; Xing, Jianchun; Wang, Haoxu; Wu, Xuezhong

2015-04-01

A novel quartz micromachined gyroscope is proposed in this paper. The novel gyroscope is realized by quartz anisotropic wet etching and 3-dimensional electrodes deposition. In the quartz wet etching process, the quality of Cr/Au mask films affecting the process are studied by experiment. An excellent mask film with 100 Å Cr and 2000 Å Au is achieved by optimization of experimental parameters. Crystal facets after etching seriously affect the following sidewall electrodes deposition process and the structure's mechanical behaviours. Removal of crystal facets is successfully implemented by increasing etching time based on etching rate ratios between facets and crystal planes. In the electrodes deposition process, an aperture mask evaporation method is employed to prepare electrodes on 3-dimensional surfaces of the gyroscope structure. The alignments among the aperture masks are realized by the ABM™ Mask Aligner System. Based on the processes described above, a z-axis quartz gyroscope is fabricated successfully.

Asymmetric adsorption of alanine by quartz powder from ethanol solution

Energy Technology Data Exchange (ETDEWEB)

Furuyama, Shozo; Sawada, Michio; Hachiya, Kinji; Morimoto, Tetsuo (Okayama Univ. (Japan). Faculty of Science)

1982-11-01

The asymmetric adsorption of the racemic alanine by the optically active quartz from ethanol solution at 8/sup 0/C was studied by the /sup 14/C-tracer method and the newly developed /sup 14/C-tracer ninhydrin-colorimetry combination method. The preferential adsorption of L-alanine by levorotatory quartz (l-quartz) and D-alanine by dextrorotatory quartz (d-quartz) was confirmed. The asymmetric adsorptivity (Asub(s)) falls in the range of 1.1 - 1.3, which is comparable with the value determined at - 80/sup 0/C in the previous paper. The effects of water content in the ethanol solution and of the adsorption temperature upon the adsorption affinity of alanine to quartz were also measured. The cause for the asymmetric adsorption is discussed from the crystallographic point of view.

Drilling-induced borehole-wall damage at spent fuel test-climax

International Nuclear Information System (INIS)

Weed, H.C.; Durham, W.B.

1982-12-01

Microcracks in a sample of quartz monzonite from the Spent Fuel Test-Climax were measured by means of a scanning electron microscope in order to estimate the background level of damage near the borehole-wall. It appears that the hammer-drilling operation used to create the borehole has caused some microfracturing in a region 10 to 30 mm wide around the borehole. Beyond 30 mm, the level of microfracturing cannot be distinguished from background

Fluid Evolution of the Magmatic Hydrothermal Porphyry Copper Deposit Based on Fluid Inclusion and Stable Isotope Studies at Darrehzar, Iran

OpenAIRE

Alizadeh Sevari, B.; Hezarkhani, A.

2014-01-01

The Darrehzar porphyry Cu-Mo deposit is located in southwestern Iran (~70 km southwest of Kerman City). The porphyries occur as Tertiary quartz-monzonite stocks and dikes, ranging in composition from microdiorite to diorite and granodiorite. Hydrothermal alteration and mineralization at Darrehzar are centered on the stock and were broadly synchronous with its emplacement. Early hydrothermal alteration was dominantly potassic and propylitic and was followed by later phyllic and argillic altera...

Luminescence sensitivity changes in quartz

CERN Document Server

Wintle, A G

1999-01-01

In the luminescence dating of sedimentary or heated quartz, some heat treatment is usually applied to the sample immediately prior to the measurement of the optically stimulated luminescence. In this paper we report experiments on a 30,000-year-old sedimentary quartz, in which we use the luminescence response to a test dose to monitor the changes in sensitivity that are caused by holding the quartz at temperatures from 160 to 280 deg. C for times from 10 s to 22 h. For an optically bleached sample, the monitoring is by both optically stimulated luminescence and the 110 deg. C TL peak; both luminescence signals are shown to have the same sensitisation (i.e. activation energy) characteristics. For natural or laboratory irradiated samples only the 110 deg. C TL peak can be used; sensitivity increases of up to a factor of 1.3 and 3 are observed for the natural and laboratory irradiated aliquots, respectively. Up to four exponential components are used to deconvolve the sensitivity change data; the dominant compon...

Geologic and geochemical insights into the formation of the Taiyangshan porphyry copper–molybdenum deposit, Western Qinling Orogenic Belt, China

Science.gov (United States)

Kun-Feng Qiu,; Taylor, Ryan D.; Yao-Hui Song,; Hao-Cheng Yu,; Kai-Rui Song,; Nan Li,

2016-01-01

Taiyangshan is a poorly studied copper–molybdenum deposit located in the Triassic Western Qinling collisional belt of northwest China. The intrusions exposed in the vicinity of the Taiyangshan deposit record episodic magmatism over 20–30 million years. Pre-mineralization quartz diorite porphyries, which host some of the deposit, were emplaced at 226.6 ± 6.2 Ma. Syn-collisional monzonite and quartz monzonite porphyries, which also host mineralization, were emplaced at 218.0 ± 6.1 Ma and 215.0 ± 5.8 Ma, respectively. Mineralization occurred during the transition from a syn-collisional to a post-collisional setting at ca. 208 Ma. A barren post-mineralization granite porphyry marked the end of post-collisional magmatism at 200.7 ± 5.1 Ma. The ore-bearing monzonite and quartz monzonite porphyries have a εHf(t) range from − 2.0 to + 12.5, which is much more variable than that of the slightly older quartz diorite porphyries, with TDM2 of 1.15–1.23 Ga corresponding to the positive εHf(t) values and TDM1 of 0.62–0.90 Ga corresponding to the negative εHf(t) values. Molybdenite in the Taiyangshan deposit with 27.70 to 38.43 ppm Re suggests metal sourced from a mantle–crust mixture or from mafic and ultramafic rocks in the lower crust. The δ34S values obtained for pyrite, chalcopyrite, and molybdenite from the deposit range from + 1.3‰ to + 4.0‰, + 0.2‰ to + 1.1‰, and + 5.3‰ to + 5.9‰, respectively, suggesting a magmatic source for the sulfur. Calculated δ18Ofluid values for magmatic K-feldspar from porphyries (+ 13.3‰), hydrothermal K-feldspar from stockwork veins related to potassic alteration (+ 11.6‰), and hydrothermal sericite from quartz–pyrite veins (+ 8.6 to + 10.6‰) indicate the Taiyangshan deposit formed dominantly from magmatic water. Hydrogen isotope values for hydrothermal sericite ranging from − 85 to − 50‰ may indicate that magma degassing progressively depleted residual liquid in

Microbially induced separation of quartz from hematite using sulfate reducing bacteria.

Science.gov (United States)

Prakasan, M R Sabari; Natarajan, K A

2010-07-01

Cells and metabolic products of Desulfovibrio desulfuricans were successfully used to separate quartz from hematite through environmentally benign microbially induced flotation. Bacterial metabolic products such as extracellular proteins and polysaccharides were isolated from both unadapted and mineral-adapted bacterial metabolite and their basic characteristics were studied in order to get insight into the changes brought about on bioreagents during adaptation. Interaction between bacterial cells and metabolites with minerals like hematite and quartz brought about significant surface-chemical changes on both the minerals. Quartz was rendered more hydrophobic, while hematite became more hydrophilic after biotreatment. The predominance of bacterial polysaccharides on interacted hematite and of proteins on quartz was responsible for the above surface-chemical changes, as attested through adsorption studies. Surface-chemical changes were also observed on bacterial cells after adaptation to the above minerals. Selective separation of quartz from hematite was achieved through interaction with quartz-adapted bacterial cells and metabolite. Mineral-specific proteins secreted by quartz-adapted cells were responsible for conferment of hydrophobicity on quartz resulting in enhanced separation from hematite through flotation. 2010 Elsevier B.V. All rights reserved.

Thermal quenching of thermoluminescence in quartz samples of various origin

International Nuclear Information System (INIS)

Subedi, B.; Oniya, E.; Polymeris, G.S.; Afouxenidis, D.; Tsirliganis, N.C.; Kitis, G.

2011-01-01

The effect of thermal quenching stands among the most important properties in the thermoluminescence (TL) of quartz on which many applications of TL are based. Since the quartz samples used in various applications are all of different origin it is useful to investigate whether the values of the thermal quenching parameters, i.e. the activation energy for thermal quenching W and a parameter C which describes the ratio of non-radiative to radiative luminescence transitions, evaluated mainly in specific quartz samples can be extrapolated to quartz samples of unknown origin as well as to quartz samples which are annealed at high temperatures. In the present work the TL glow curve of a series of un-annealed and annealed natural and synthetic quartz samples were studied as a function of the heating rate between 0.25 K/s and 16 K/s. Using an indirect fitting method it was found that the thermal quenching parameters W and C in most of the quartz samples are very similar to the values accepted in the literature. Furthermore, in some cases the thermal quenching parameters W and C are not the same for all TL glow-peaks in the same glow-curve. Finally, the strong external treatment of annealing the quartz samples at very high temperature can also influence at least one of the thermal quenching parameters.

Quartz exsolution topotaxy in clinopyroxene from the UHP eclogite of Weihai, China

Science.gov (United States)

Xu, Haijun; Zhang, Junfeng; Zong, Keqing; Liu, Liang

2015-06-01

Abundant oriented silica precipitates of α-quartz (4.0 ± 1.0 vol.%), in part coexisting with calcic amphiboles (topotactic relationships with their host clinopyroxenes. Three types of crystallographic topotactic relationship have been identified between quartz and host clinopyroxene: (1) 52% quartz precipitates share the same orientation for the c-axes with [0001]qz//[001]cpx; (2) 34% quartz precipitates share the same orientation for the a-axes with [11 2 bar0]qz//[001]cpx; and (3) 11% quartz precipitates share the same orientation for the s-planes with (11 2 bar1)qz//(100)cpx. Other quartz axes and planes disperse in large or small girdles around the shared axes or planes. Many quartz rods/needles are elongated parallel to the [001]cpx with the long axes of quartz being either [0001]qz or [11 2 bar0]qz. Amphibole precipitates have also a strong crystallographic relationship with host clinopyroxene, i.e., (100)amp//(100)cpx, [010]amp//[010]cpx, and [001]amp//[001]cpx. These results provide quantitative microstructural evidence supporting an exsolution origin for oriented quartz needles/rods in clinopyroxene and demonstrate that the exsolution of quartz from clinopyroxene occurred within the stability field of α-quartz rather than coesite. The oriented precipitates of α-quartz, in part coexisting with calcic amphiboles, in host clinopyroxene are probably promoted by supercritical fluid or partial melting during the early exhumation of eclogites. Our results suggest that oriented quartz precipitates in clinopyroxene cannot be used as an indisputable UHP-indicator.

Dating quartz: Ar/Ar analyses of coexisting muscovite and fluid inclusion - rich quartz from paleocene amorphic aureole

International Nuclear Information System (INIS)

Matthews, S.J.; Perez de Arce, C.; Cornejo, P.; Cuitino, L; Klein, J

2001-01-01

We present Ar/Ar total fusion and step-heating data for coexisting muscovite and white quartz from the metamorphic aureole of the Lower Paleocene La Copiapina Pluton, 6 km south of Inca de Oro, III Region, Chile. The pluton intrudes the upper clastic sedimentary member of the Punta del Cobre Group (Upper Jurassic - Lower Cretaceous) and the calcareous sedimentary rocks of the Chanarcillo Group (Neocomian), and comprises fine to coarse grained pyroxene-hornblende-biotite quartz diorites and monzodiorites. Its emplacement was controlled on its north-western side by a subvertical NE-trending fault, along which were developed vertically banded skarns (skarn mylonite), suggesting syntectonic intrusion. Biotite K-Ar ages for the pluton fall in the range 61-63 Ma, relating it to a latest Cretaceous to Lowest Paleocene syn-compressional intrusive belt which is present in the area (Matthews and Cornejo, 2000). A metamorphic / metasomatic aureole is developed within the sandstones of the Punta del Cobre Group, on the extreme northern limit of the pluton. In this area, the sedimentary rocks have been replaced by quartz-sericite and quartz-muscovite assemblages, with minor hematite and tourmaline, and late supergene kaolinite and pyrophyllite. A coarse muscovite-quartz-tourmaline-hematite assemblage is developed in and around older (early Upper Cretaceous) andesitic dykes, in the form of replacement / fracture fill veins and replacement zones. Further from the contact with the pluton, fine-grained quartz-sericite rock with coarser muscovite-rich replacement veins represents the dominant lithology. Quartz in the coarse replacement rock is very rich in fluid inclusions. Primary inclusions are mainly of two coexisting types; bi-phase (liquid and gas bubble) and tri-phase (liquid, gas bubble and halite crystal), indicating that the quartz formed in the presence of a boiling fluid. Some inclusions also contain sylvite and occasional hematite daughter crystals. Secondary inclusions

Passivation of quartz for halogen-containing light sources

Science.gov (United States)

Falkenstein, Zoran

1999-01-01

Lifetime of halogen containing VUV, UV, visible or IR light sources can be extended by passivating the quartz or glass gas containers with halogens prior to filling the quartz with the halogen and rare gas mixtures used to produce the light.

Quartz-molybdenite veins in the Priestly Lake granodiorite, north-central Maine

Science.gov (United States)

Ayuso, Robert A.; Shank, Stephen G.

1983-01-01

Quartz-molybdenite veins up to 15 cm in width occur in fine to medium-grained porphyritic biotite-hornblende granodiorite at Priestly Lake north-central Maine. An area of about 150 m x 150 m contains quartz-molybdenite veins; a larger area is characterized by barren quartz veins. Quartz-molybdenite veins are concentrated within the most felsic variants of the intrusion as suggested by lower mafic mineral contents. The pluton has a narrow range in SiO2 (67-70 wt.%), major oxides, and in trace-element compositions. Molybdenite occurs as coarse grained clusters in pockets within the quartz veins, and fills fractures in the quartz veins and host rocks. Disseminated molybdenite in the granodiorite is relatively rare and occurs only in the area characterized by a high density of quartz veins (up to 50 veins per square meter). Alteration envelopes along the quartz veins are very thin or absent, although in some areas the granodiorite appears to be selectively and pervasively altered. Sericite, chlorite, epidote, calcite, pyrite, and quartz are concentrated near the quartz-molybdenite veins. Many of the field and geochemical characteristics of the Priestly Lake pluton are unlike those of major molybdenum-producing areas (Climax, Henderson, Urad). For example, the area of alteration seems to be of limited extent, the host rock is not intensely altered hydrothermally at the surface, the density of fractures is rather low in the mineralized area, and the amount of disseminated molybdenite appears to be small. However, the Priestly Lake pluton may be a small fraction of a concealed batholith as suggested by geophysical data. It is conceivable that the type of mineralization at the surface might be the expression of more extensive molybdenite mineralization at depth. The quartz-molybdenite veins in the Priestly Lake pluton are significant because they indicate that potential molybdenum sources for producing mineralized granites were available at depth. Future studies should be

Geology of the Cupsuptic quadrangle, Maine

Science.gov (United States)

Harwood, David S.

1966-01-01

The Cupsuptic quadrangle, in west-central Maine, lies in a relatively narrow belt of pre-Silurian rocks extending from the Connecticut River valley across northern New Hampshire to north-central Maine. The Albee Formation, composed of green, purple, and black phyllite with interbedded-quartzite, is exposed in the core of a regional anticlinorium overlain to the southeast by greenstone of the Oquossoc Formation which in turn is overlain by black slate of the Kamankeag Formation. In the northern part of the quadrangle the Albee Formation is overlain by black slate, feldspathic graywacke, and minor greenstone of the Dixville Formation. The Kamankeag Formation is dated as 1-ate Middle Ordovician by graptolites (zone 12) found near the base of the unit. The Dixville Formation is correlated with the Kamankeag Formation and Oquossoc Formation and is considered to be Middle Ordovician. The Albee Formation is considered to be Middle to Lower Ordovician from correlations with similar rocks in northeastern and southwestern Vermont. The Oquossoc and Kamankeag Formations are correlated with the Amonoosuc and Partridge Formations of northern New Hampshire. The pre-Silurian rocks are unconformably overlain by unnamed rocks of Silurian age in the southeast, west-central, and northwest ninths of the quadrangle. The basal Silurian units are boulder to cobble polymict conglomerate and quartz-pebble conglomerate of late Lower Silurian (Upper Llandovery) age. The overlying rocks are either well-bedded slate and quartzite, silty limestone, or arenaceous limestone. Thearenaceous limestone contains Upper Silurian (Lower Ludlow) brachiopods. The stratified rocks have been intruded by three stocks of biotite-muscovite quartz monzonite, a large body of metadiorite and associated serpentinite, smaller bodies of gabbro, granodiorite, and intrusive felsite, as well as numerous diabase and quartz monzonite dikes. The metadiorite and serpentinite, and possibly the gabbro and granodiorite are Late

Quartz enhanced photoacoustic spectroscopy based trace gas sensors using different quartz tuning forks.

Science.gov (United States)

Ma, Yufei; Yu, Guang; Zhang, Jingbo; Yu, Xin; Sun, Rui; Tittel, Frank K

2015-03-27

A sensitive trace gas sensor platform based on quartz-enhanced photoacoustic spectroscopy (QEPAS) is reported. A 1.395 μm continuous wave (CW), distributed feedback pigtailed diode laser was used as the excitation source and H2O was selected as the target analyte. Two kinds of quartz tuning forks (QTFs) with a resonant frequency (f0) of 30.72 kHz and 38 kHz were employed for the first time as an acoustic wave transducer, respectively for QEPAS instead of a standard QTF with a f0 of 32.768 kHz. The QEPAS sensor performance using the three different QTFs was experimentally investigated and theoretically analyzed. A minimum detection limit of 5.9 ppmv and 4.3 ppmv was achieved for f0 of 32.768 kHz and 30.72 kHz, respectively.

Quartz Enhanced Photoacoustic Spectroscopy Based Trace Gas Sensors Using Different Quartz Tuning Forks

Directory of Open Access Journals (Sweden)

Yufei Ma

2015-03-01

Full Text Available A sensitive trace gas sensor platform based on quartz-enhanced photoacoustic spectroscopy (QEPAS is reported. A 1.395 μm continuous wave (CW, distributed feedback pigtailed diode laser was used as the excitation source and H2O was selected as the target analyte. Two kinds of quartz tuning forks (QTFs with a resonant frequency (f0 of 30.72 kHz and 38 kHz were employed for the first time as an acoustic wave transducer, respectively for QEPAS instead of a standard QTF with a f0 of 32.768 kHz. The QEPAS sensor performance using the three different QTFs was experimentally investigated and theoretically analyzed. A minimum detection limit of 5.9 ppmv and 4.3 ppmv was achieved for f0 of 32.768 kHz and 30.72 kHz, respectively.

Estimating Quartz Reserves Using Compositional Kriging

Directory of Open Access Journals (Sweden)

J. Taboada

2013-01-01

Full Text Available The aim of this study was to determine spatial distribution and volume of four commercial quartz grades, namely, silicon metal, ferrosilicon, aggregate, and kaolin (depending on content in impurities in a quartz seam. The chemical and mineralogical composition of the reserves in the seam were determined from samples collected from outcrops, blasting operations, and exploratory drilling, and compositional kriging was used to calculate the volume and distribution of the reserves. A more accurate knowledge of the deposit ensures better mine planning, leading to higher profitability and an improved relationship with the environment.

Refractometry characteristics of α-quartz after neutron irradiation

International Nuclear Information System (INIS)

Abdkadyrova, I.Kh.

1997-01-01

Lattice structure distortions in irradiated crystalline quartz were studied by refractometry methods. The refractometry constants of α-quartz for the flux of fast neutrons 10 18 - 10 21 neutron/cm 2 were calculated. The critical kinetics of this constants at the phase transformation is observed.(author). 5 refs., 1 fig

Dependence of red thermoluminescence on Eu-anomaly in natural quartzes

Energy Technology Data Exchange (ETDEWEB)

Hashimoto, T; Yokosaka, K; Notoya, S; Ojima, T; Sakaue, S [Niigata Univ. (Japan). Faculty of Science

1993-04-01

The causes of red colour thermoluminescence (RTL) from natural quartz have been sought in the presence of impurity elements. Some impurities in 31 varieties of natural quartz extracts, determined by a neutron activation analysis, have been examined with respect to a meaningful correlation of the RTL to the total detectable TL strength. Generally, the higher impurity contents were found in quartz of volcanic origin, which always emits purely RTL colour, whereas the lower impurities were usually detected in hydrothermal quartz, which emits purely blue TL (BTL) in all absorbed doses. Among the impurities, the middle REE (rare earth elements), involving Eu and Sm, particularly offered considerable correlation with RTL emission with the exception of pegmatite quartz. It was found from the chondrite-normalized REE patterns that a positive Eu anomaly or flattened Eu distribution gave rise to relatively high RTL proportions, while a negative Eu anomaly always showed extremely weak RTL intensity. Thus, it was concluded that the Eu[sup 3+], formed from the oxidizable surrounding or high oxygen fugacity relative to a Cl chondrite formation, is strongly related to the RTL intensity in natural quartz. (author).

Formation of cogenetic quartz and nepheline syenites

Science.gov (United States)

Foland, K. A.; Landoll, J. D.; Henderson, C. M. B.; Chen, Jiangfeng

1993-02-01

Understanding the processes involved in the formation of cogenetic silica-undersaturated and silica-saturated felsic rocks in alkaline igneous complexes has been a long-standing enigma because of constraints imposed by phase equilibria relationships. This problem is discussed in general drawing upon relationships at two magmatic centers: Marangudzi in Zimbabwe and Mt. Brome in Quebec, Canada. At each locality, cogenetic quartz and nepheline syenites appear to be derived from common critically undersaturated magmas. Strontium and neodymium isotope results indicate that quartz syenites bear the signatures of substantial amounts of crustal assimilation whereas nepheline syenites lack or display lesser effects. In the model outlined, quartz syenite melts develop from felsic silica undersaturated magmas by assimilation of granitic crust coupled with fractional crystallization whereas nepheline syenites form without large amounts of contamination. This model is compatible with the constraints imposed by phase equilibria.

Identification of color development potential of quartz by Raman spectroscopy

International Nuclear Information System (INIS)

Alkmim, Danielle G.; Lameiras, Fernando S.; Almeida, Frederico O.T.

2013-01-01

Colorless quartz is usually exposed to ionizing radiation (gamma rays or high energy electron beams) to acquire different colors for jewelry. Color development is due to the presence of traces of some elements such as aluminum, iron, hydrogen, lithium, or sodium. Most quartz crystals are extracted colorless from nature and it is necessary to separate those that can develop colors from those that cannot. Irradiation tests can be used to accomplish this separation, but they take a long time. Infrared signature of colorless quartz can also be used. However, infrared spectroscopy is quite expensive, especially when using portable devices. Raman spectroscopy is now available as an inexpensive and portable technique that could provide identification of the samples of colorless quartz still in the field, facilitating the prediction for their economic exploitation. In addition, Raman spectroscopy usually requires a minimum or no sample preparation. This paper presents an investigation of the feasibility of using Raman spectroscopy as a substitute for infrared spectroscopy to predict the potential for color development of quartz. A band at 3595 cm -1 in the Raman shift spectrum was observed only along the c axis of a prasiolite excited by a high power 514 nm laser. This band was not observed in quartz samples that do not develop color after irradiation. Further studies are required to identify the potential for color development by Raman spectroscopy of other types of colorless quartz. (author)

Radioluminescence of synthetic quartz related to alkali ions

Energy Technology Data Exchange (ETDEWEB)

Martini, M., E-mail: m.martini@unimib.it [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); INFN-Sezione di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Fasoli, M. [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Galli, A. [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Istituto di Fotonica e Nanostrutture, IFN-CNR (Italy); Villa, I. [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Guibert, P. [IRAMAT-CRP2A (Institut de recherche sur les Archeomateriaux), UMR no. 5060, CNRS-Universite Bordeaux III, F-33607 Pessac (France)

2012-04-15

The radioluminescence (RL) of synthetic quartzes (GEMMA Quartz and Crystal Company) has been measured at room temperature. Some samples were treated by electrodiffusion ('sweeping') in order to change the concentrations of alkali ions, mainly Li{sup +} and Na{sup +}, which in quartz are known to be linked to Al ions, substitutional for Si ions. The RL emission spectra show evidence of a role of alkali ions in affecting some specific emissions. All the spectra could be analysed as composed of four bands in the blue and UV region. Specifically, the well known blue emission at around 470 nm was seen to be composed by two bands at 430 nm (2.86 eV) and at 485 nm (2.53 eV). Effects of irradiation, during the RL measurements, were clearly seen only in the 'Li swept in' sample, namely an increase in the 485 nm band intensity and a decrease in the 430 nm band one. The previously reported UV emission was detected at 355 nm (3.44 eV) in all the samples, being the most intense band in the 'swept out' sample. A further UV emission was detected at 315 nm (3.94 eV), more intense in untreated samples. Possible assignments of the detected emission bands are discussed in relation to the defects of quartz, specifically focusing on the Al centres that are most affected by sweeping procedures. - Highlights: Black-Right-Pointing-Pointer Contribution to the understanding of relationships between defects in quartz and luminescence emissions. Black-Right-Pointing-Pointer Role of charge compensators at substitutional Al sites in the optical properties of quartz. Black-Right-Pointing-Pointer Evidence of the double nature of the 'blue emission' (around 470 nm).

Food irradiation dosimetry using thermoluminescence of quartz sand

International Nuclear Information System (INIS)

Khan, H.M.; Ehlermann, D.A.E.

1993-01-01

Thermoluminescence of quartz sand, which is inert and concomitant to several food materials, has been investigated for applications in food irradiation dosimetry and detection of irradiated foods. The glow curves consist of at least three overlapping peaks from 100 to 420 C. The peak at lower temperature is not stable and decays quickly at room temperature. However, the peaks at higher temperature are stable and more useful for dosimetry work. The intensity of the peak at 360 C, measured using different optical filters, shows a linear response in the range of 0.05 to 23 kGy. Stability of these signals at different annealing temperatures has been investigated. Thermoluminescence from adhering minerals and contaminating dust in different food materials has been found useful for the detection of irradiation treatment. Since quartz is frequently one of these minerals, further computerized deconvolution of individual glow peaks from the complex glow curves of quartz sand was carried out which improves the dosimetric results. Possible applications of thermoluminescence of quartz sand in food irradiation dosimetry and detection of irradiated foods have been discussed. (orig.)

Alpha efficiency determination for OSL of quartz extracted from Chinese loess

International Nuclear Information System (INIS)

Lai Zhongping; Zoeller, Ludwig; Fuchs, Markus; Brueckner, Helmut

2008-01-01

We report here the estimates of alpha efficiency for fine grain quartz extracted from Chinese loess using the SAR protocol. For the seven samples, the α-values range from 0.028 to 0.038 with an average of 0.035±0.001. The annealed quartz (450 deg. C, 45 min) has an α-value of 0.030±0.001 which is similar to the α-value of 0.029±0.001 for the non-annealed quartz extracts, suggesting that the α-value is independent of the quartz's thermal history for this sample. We suggest that an α-value of 0.035±0.003 can be adopted for quartz extracted from Chinese loess when calculating the environmental dose rate

Activation analysis of high pure quartz used as packing materials

International Nuclear Information System (INIS)

Luknitskij, V.A.; Morozov, B.A.

1979-01-01

A γ-spectrometric technique of neutron activation determination of microelements in quartz tubes used as a packing material for irradiation in reactors is reported. The analysis of 29 micro-admixtures in quartz tubes of USSR brands ''spectrtosil'' and ''KV'' was carried out. The γ-spectra of ''KV'' quartz irradiated by thermal and epithermal neutrons are presented. The activation by epithermal neutrons provides an activity gain for the nuclei whose resonance integral is high enough as compared to the activation cross-section with regard to thermal neutrons. The activation by epithermal neutrons permits additional determination of W, Cd, V, Th, Mn and Ni and provides for a substantial decrease in the activity of 24 Na, 42 K, 140 La, 46 Sc, 141 Ce, 51 Cr, and 59 Fe, which hinder the determination of the above-mentioned elements. The microelement composition of Soviet-made quartz varieties is compared to that of foreign-made quartz brands

Hydrothermal alteration at Roosevelt Hot Springs KGRA - DDH 1976-1

Energy Technology Data Exchange (ETDEWEB)

Bryant, N.L.; Parry, W.T.

1977-09-01

Hot waters of the Roosevelt Thermal Area, Utah, have altered granitic rocks and detritus of the Mineral Range pluton, Utah. Petrographic, x-ray, and chemical methods were used to characterize systematic changes in chemistry and mineralogy. Major alteration zones include: 1) an advanced argillic zone in the upper 30 feet of altered detritus containing alunite, opal, vermiculite, and relic quartz; 2) an argillic zone from 30 feet to 105 feet containing kaolinite, muscovite, and minor alunite; and 3) a propylitic zone from 105 to 200 feet containing muscovite, pyrite, marcasite, montmorillonite, and chlorite in weakly altered quartz monzonite. Comparison of the alternation mineral assemblages with known water chemistry and equilibrium activity diagrams suggests that a simple solution equilibrium model cannot account for the alteration. A model is proposed in which upward moving thermal water supersaturated with respect to quartz and a downward moving cool water undersaturated with respect to quartz produces the observed alteration. An estimate of the heat flow contributions from hydrothermal alteration was made by calculating reaction enthalpies for alteration reactions at each depth.

Construction of simple quartz crystal microbalance

Energy Technology Data Exchange (ETDEWEB)

Ristov, Milcho [Center of Energy, Informatics and Materials of the Macedonian Academy fo Science and Arts, Skopje (Macedonia, The Former Yugoslav Republic of); Mitrevski, Mitre [Institute of Physics, Faculty of natural Science and Mathematics, Ss Cyril and Methodius University, Skopje (Macedonia, The Former Yugoslav Republic of)

2003-07-01

A very simple Quartz Crystal Microbalance (QCM) was constructed for the measurement of thickness of chemically deposited thin films. QCM consisted of two active elements: one dual-gate MOSFET and one bipolar transistor, and as usually two AT-cut quartz crystal. The beat frequency oscillation generated as a result of loading of the sensor crystal by the deposited thin film, was measured by HP-multimeter, set as a low frequency meter. The sensitivity was found to be high and satisfactory for the study of growth rate of thin films, mainly deposited by methods of chemical deposition.

Construction of simple quartz crystal microbalance

International Nuclear Information System (INIS)

Ristov, Milcho; Mitrevski, Mitre

2002-01-01

A very simple Quartz Crystal Microbalance (QCM) was constructed for the measurement of thickness of chemically deposited thin films. QCM consisted of two active elements: one dual-gate MOSFET and one bipolar transistor, and as usually two AT-cut quartz crystal. The beat frequency oscillation generated as a result of loading of the sensor crystal by the deposited thin film, was measured by HP-multimeter, set as a low frequency meter. The sensitivity was found to be high and satisfactory for the study of growth rate of thin films, mainly deposited by methods of chemical deposition.

EPR investigation into the structure of boron-containing quartz glasses

International Nuclear Information System (INIS)

Amosov, A.V.; Bushmarin, D.B.; Prokhorova, T.I.; Yudin, D.M.

1975-01-01

Certain properties of boron-containing quartz glasses and the nature of occurrence of boron in the glass lattice are studied as functions of the method of alloying. The formation of three types of borate structural nodes (BO 4 , BO 3 and BO 4 -BO 3 ) in the lattice of quartz glasses is established. Alloying by boron oxide up to 3% (weight) increases the crystallization stability of quartz glasses, lowers down tsub(g) from 1220 to 950 deg C and does not affect the coefficient of thermal expansion. Low symmetry of borate structural nodes, following from the analysis of EPR spectra, confirms the literature data concerning the low symmetry of glass-forming polyhedrons in a quartz glass

Soil chemistry in lithologically diverse datasets: the quartz dilution effect

Science.gov (United States)

Bern, Carleton R.

2009-01-01

National- and continental-scale soil geochemical datasets are likely to move our understanding of broad soil geochemistry patterns forward significantly. Patterns of chemistry and mineralogy delineated from these datasets are strongly influenced by the composition of the soil parent material, which itself is largely a function of lithology and particle size sorting. Such controls present a challenge by obscuring subtler patterns arising from subsequent pedogenic processes. Here the effect of quartz concentration is examined in moist-climate soils from a pilot dataset of the North American Soil Geochemical Landscapes Project. Due to variable and high quartz contents (6.2–81.7 wt.%), and its residual and inert nature in soil, quartz is demonstrated to influence broad patterns in soil chemistry. A dilution effect is observed whereby concentrations of various elements are significantly and strongly negatively correlated with quartz. Quartz content drives artificial positive correlations between concentrations of some elements and obscures negative correlations between others. Unadjusted soil data show the highly mobile base cations Ca, Mg, and Na to be often strongly positively correlated with intermediately mobile Al or Fe, and generally uncorrelated with the relatively immobile high-field-strength elements (HFS) Ti and Nb. Both patterns are contrary to broad expectations for soils being weathered and leached. After transforming bulk soil chemistry to a quartz-free basis, the base cations are generally uncorrelated with Al and Fe, and negative correlations generally emerge with the HFS elements. Quartz-free element data may be a useful tool for elucidating patterns of weathering or parent-material chemistry in large soil datasets.

Importance of surface characteristics of QUARTZ DQ 12 for acute inflammation

Energy Technology Data Exchange (ETDEWEB)

Albrecht, C.; Becher, A.; Scins, R.P.F.; Hoehr, D.; Unfried, K.; Knaapen, A.M.; Borm, P.J.A. [Institut fuer medizinische Forschung (IUF), Duesseldorf (Germany)

2004-07-01

Although quartz is known to induce inflammation in rat lungs, mechanisms are not yet fully understood. The importance of particle surface characteristics was investigated in vivo after intratracheal instillation of different preparations of quartz in rat lungs. Three days after instillation of 2 mg DQ12 quartz, or DQ12 coated with polyvinylpyridine-N-oxide (PVNO) or Aluminium lactate (AL), lungs of female Wistar rats were lavaged in situ to determine markers of inflammation. Control rats received saline or the coating substances alone. DQ12 induced a marked inflammatory response, as indicated by a significant increase in the number of neutrophils and macrophages, as well as in the levels of b-glucuronidase and myeloperoxidase. None of these inflammatory markers was increased for both coated quartz preparations, with the exception of neutrophil influx which was also increased after treatment with AL quartz. Our results indicate that surface characteristics are important in the onset of quartz-induced lung inflammation which could imply a different development of persistent inflammation. This will be investigated in later follow-up time points of the same animal study. (orig.)

Quartz-Enhanced Photoacoustic Spectroscopy Sensor with a Small-Gap Quartz Tuning Fork

Directory of Open Access Journals (Sweden)

Yu-Fei Ma

2018-06-01

Full Text Available A highly sensitive quartz-enhanced photoacoustic spectroscopy (QEPAS sensor based on a custom quartz tuning fork (QTF with a small-gap of 200 μm was demonstrated. With the help of the finite element modeling (FEM simulation software COMSOL, the change tendency of the QEPAS signal under the influence of the laser beam vertical position and the length of the micro-resonator (mR were calculated theoretically. Water vapor (H2O was selected as the target analyte. The experimental results agreed well with those of the simulation, which verified the correctness of the theoretical model. An 11-fold signal enhancement was achieved with the addition of an mR with an optimal length of 5 mm in comparison to the bare QTF. Finally, the H2O-QEPAS sensor, which was based on a small-gap QTF, achieved a minimum detection limit (MDL of 1.3 ppm, indicating an improvement of the sensor performance when compared to the standard QTF that has a gap of 300 μm.

Properties and behavior of quartz for the silicon process

Energy Technology Data Exchange (ETDEWEB)

Aasly, Kurt

2008-07-01

This PhD-thesis is a result of the study on important properties of quartz as a raw material for the metallurgical production of ferrosilicon and silicon metal. This includes defining mechanical properties important for the size reduction experienced during transport and storage and thermo-mechanical properties of quartz that is important for how the quartz reacts to the high temperatures experienced as it is charged on the furnace. Additionally, softening properties of quartz have been briefly discussed in some of the papers. Another important goal has been to test analytical and experimental methods for investigating the various properties. The investigations of important factors for the mechanical properties of ores and industrial minerals have been carried out as a literature study. The mining operation and transport from mine to smelter has been discussed and several factors that are significant for achieving best possible mechanical properties of the quartz have been identified. The most important factors are related to production in the mine and processing plant, which should be carefully planned to minimize the amount of blast-induced damage in the rock and thus achieve the best possible mechanical strength of the raw material. The amount of fines can be minimized by controlling the handling of the raw materials during the transport and storage. It is especially important to avoid high drops, both high single drops and accumulated height of all the drops in total. Investigations of the thermo-mechanical properties of quartz have been carried out by using different experimental and characterization methods. The petrographic investigations of the raw materials by polarized light microscopy have been important. Thermo-mechanical investigations have been high-temperature microthermometry and shock heating of quartz samples in an induction furnace with subsequent investigations of the heated material. The subsequent investigation included polarized- and

Structure optimization and simulation analysis of the quartz micromachined gyroscope

Directory of Open Access Journals (Sweden)

Xuezhong Wu

2014-02-01

Full Text Available Structure optimization and simulation analysis of the quartz micromachined gyroscope are reported in this paper. The relationships between the structure parameters and the frequencies of work mode were analysed by finite element analysis. The structure parameters of the quartz micromachined gyroscope were optimized to reduce the difference between the frequencies of the drive mode and the sense mode. The simulation results were proved by testing the prototype gyroscope, which was fabricated by micro-electromechanical systems (MEMS technology. Therefore, the frequencies of the drive mode and the sense mode can match each other by the structure optimization and simulation analysis of the quartz micromachined gyroscope, which is helpful in the design of the high sensitivity quartz micromachined gyroscope.

Toroidal helical quartz forming machine

International Nuclear Information System (INIS)

Hanks, K.W.; Cole, T.R.

1977-01-01

The Scyllac fusion experimental machine used 10 cm diameter smooth bore discharge tubes formed into a simple toroidal shape prior to 1974. At about that time, it was discovered that a discharge tube was required to follow the convoluted shape of the load coil. A machine was designed and built to form a fused quartz tube with a toroidal shape. The machine will accommodate quartz tubes from 5 cm to 20 cm diameter forming it into a 4 m toroidal radius with a 1 to 5 cm helical displacement. The machine will also generate a helical shape on a linear tube. Two sets of tubes with different helical radii and wavelengths have been successfully fabricated. The problems encountered with the design and fabrication of this machine are discussed

A new equation of state for α-quartz

Science.gov (United States)

Magyar, Rudolph; Carpenter, John

2015-06-01

Quartz (SiO2) is often used as an optically transparent window for visar signals in shock experiments and is itself an active component of the experiments. Therefore, the shock response of quartz is an important input that must be known to high fidelity for precise measurement of other materials. We describe on-going work to develop a wide-range equation of state table that includes multiple phases and incorporates the latest high quality experimental and density functional theory (DFT) calculations. The emphasis in this work is the proper description of α-quartz along its principal Hugoniot through Stishovite and liquid phases. While molecular dissociation occurs at high pressures and temperatures, we find that an additional dissociation model is unnecessary. Although SiO2 possesses a number of solid phases, we restrict our focus to α-quartz and Stishovite as these two provide the density change along the Hugoniot path. We compare the model to recently measured data on Sandia's Z-machine. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE.

Application of hydrometallurgy techniques in quartz processing and purification: a review

Science.gov (United States)

Lin, Min; Lei, Shaomin; Pei, Zhenyu; Liu, Yuanyuan; Xia, Zhangjie; Xie, Feixiang

2018-04-01

Although there have been numerous studies on separation and purification of metallic minerals by hydrometallurgy techniques, applications of the chemical techniques in separation and purification of non-metallic minerals are rarely reported. This paper reviews disparate areas of study into processing and purification of quartz (typical non-metallic ore) in an attempt to summarize current work, as well as to suggest potential for future consolidation in the field. The review encompasses chemical techniques of the quartz processing including situations, progresses, leaching mechanism, scopes of application, advantages and drawbacks of micro-bioleaching, high temperature leaching, high temperature pressure leaching and catalyzed high temperature pressure leaching. Traditional leaching techniques including micro-bioleaching and high temperature leaching are unequal to demand of modern glass industry for quality of quartz concentrate because the quartz products has to be further processed. High temperature pressure leaching and catalyzed high temperature pressure leaching provide new ways to produce high-grade quartz sand with only one process and lower acid consumption. Furthermore, the catalyzed high temperature pressure leaching realizes effective purification of quartz with extremely low acid consumption (no using HF or any fluoride). It is proposed that, by integrating the different chemical processes of quartz processing and expounding leaching mechanisms and scopes of application, the research field as a monopolized industry would benefit.

Identification of Color Development Potential of Quartz by Raman Spectroscopy

International Nuclear Information System (INIS)

Gomides Alkmim, D.; Soares Lameiras, F.

2013-01-01

Colorless quartz is usually exposed to ionizing radiation (gamma rays or high energy electron beams) in order to acquire different colors for jewelry. This is due to the presence of traces of some elements such as aluminum, iron, hydrogen, lithium, or sodium, which are responsible for the extrinsic colors developed after irradiation. Most quartz crystals are extracted colorless from nature and it is necessary to separate those that can develop colors from those that cannot. This can be done through irradiation tests, which take a long time. Other option is to collect the infrared signature of colorless quartz. However, infrared spectroscopic analysis is quite expensive, especially when using portable devices. Raman spectroscopy is now available as an inexpensive and portable technique that could provide identification of the samples of colorless quartz still in the field, facilitating the prediction for their economic exploitation. In addition, Raman spectroscopy usually requires a minimum or no sample preparation. This paper presents an investigation of the feasibility of using Raman spectroscopy as a substitute for infrared spectroscopy to predict the potential for color development of quartz. A band at 3595 cm -1 was observed, only along the c axis of a prasiolite excited by a high power 514 nm laser. This band was nor observed in quartz samples that do not develop color after irradiation, hence requiring further studies. (Author)

The Suitability Of Local Quartz Sand In The Production Of Bath Crucibles.

Directory of Open Access Journals (Sweden)

C. O. Okpanachi

2017-03-01

Full Text Available The suitability of local quartz sand in the production of bath crucibles is a study that was carried out in order to impart overall strength on bath crucibles hence reduce breakages during fettling. Therefore this research constitutes a study to enhance the efficiency of production of bath crucibles by addition of quartz sand in slip preparation. The steps taken in the beneficiation of quartz sand for the production of bath crucibles are comminution which entails crushing and milling classification washing liquid dispersion sizing and reduction of iron content by magnetic separation. The slip contains materials like plastic clay feldspar kaolin talc sodium silicate water quartz sand etc. These were all milled in the ball mill for slip production casting and fettling glazing and sintering to get final bath crucibles as the end products. Quartz sand is used in a variety of products essentially as raw material for the foundry casting and glass industries and also in chemicals water filtration and ceramics the heat resistance nature of quartz sand makes it an excellent refractory substance for these industrial processes. Slip can be prepared for production of bath crucibles without the inclusion of quartz sand however the addition of quartz sand is needed to improve the mechanical performance of the slip in the production of bath crucibles.

Use of digital Munsell color space to assist interretation of imaging spectrometer data: Geologic examples from the northern Grapevine Mountains, California and Nevada

Science.gov (United States)

Kruse, F. A.; Knepper, D. H., Jr.; Clark, R. N.

1986-01-01

Techniques using Munsell color transformations were developed for reducing 128 channels (or less) of Airborne Imaging Spectrometer (AIS) data to a single color-composite-image suitable for both visual interpretation and digital analysis. Using AIS data acquired in 1984 and 1985, limestone and dolomite roof pendants and sericite-illite and other clay minerals related to alteration were mapped in a quartz monzonite stock in the northern Grapevine Mountains of California and Nevada. Field studies and laboratory spectral measurements verify the mineralogical distributions mapped from the AIS data.

Pulsed ESR measurements of oxygen deficient type centers in various quartz

International Nuclear Information System (INIS)

Yamanaka, C.; Kohno, H.; Ikeya, M.

1996-01-01

Phase-memory times T M for E'-centers in various quartz samples were measured by pulse-ESR. Manually ground quartz followed by γ-irradiation, α-irradiated quartz and that from a natural uranium deposit showed T M M of 15-18μs. Natural SiO 2 with dense spins, (∼ 3.96 Ga) and sandstone from an impact crater were also examined. (author)

Luminescence sensitivity changes in quartz as a result of annealing

DEFF Research Database (Denmark)

Bøtter-Jensen, L.; Agersnap Larsen, N.; Mejdahl, V.

1995-01-01

archaeological samples show very different OSL sensitivities. In this paper we report on studies of the effect of high temperature annealing on the OSL and phototransferred TL (PTTL) signals from sedimentary and synthetic quartz. A dramatic enhancement of both OSL and PTTL sensitivity was found especially...... in the temperature range 500-800 degrees C. Computer simulations of the possible effects are shown to produce data that agree in all essential details with the experimental observations. It is further demonstrated that the enhanced OSL sensitivity as a function of annealing temperature is not a pre-dose effect....... of magnitude less per unit radiation than that for heated material. The reason these temperature-induced sensitivity changes occur in quartz is presently not well understood. This phenomenon is also seen in the related area of luminescence dating in which sedimentary quartz and quartz from heated...

Fracture flow due to hydrothermally induced quartz growth

Science.gov (United States)

Kling, Tobias; Schwarz, Jens-Oliver; Wendler, Frank; Enzmann, Frieder; Blum, Philipp

2017-09-01

Mineral precipitations are a common feature and limitation of initially open, permeable rock fractures by forming sealing structures or secondary roughness in open voids. Hence, the objective of this numerical study is the evaluation of hydraulic properties of fractures sealed by hydrothermally induced needle and compact quartz growth. Phase-field models of progressive syntaxial and idiomorphic quartz growth are implemented into a fluid flow simulation solving the Navier-Stokes equation. Flow simulations for both quartz types indicate an obvious correlation between changes in permeability, fracture properties (e.g. aperture, relative roughness and porosity) and crystal growth behavior, which also forms distinct flow paths. Thus, at lower sealing stages initial fracture permeability significantly drops down for the 'needle fracture' forming highly tortuous flow paths, while the 'compact fracture' records a considerably smaller loss. Fluid flow in both sealing fractures most widely is governed by a ;parallel plate;-like cubic law behavior. However, the 'needle fracture' also reveals flow characteristics of a porous media. A semi-theoretical equation is introduced that links geometrical (am) with hydraulically effective apertures (ah) and the relative fracture roughness. For this purpose, a geometry factor α is introduced being α = 2.5 for needle quartz and α = 1.0 for compact quartz growth. In contrast to most common ah-am-relationships this novel formulation not only reveals more precise predictions for the needle (RMSE = 1.5) and the compact fractures (RMSE = 3.2), but also exhibit a larger range of validity concerning the roughness of the 'needle' (σ/am = 0-2.4) and the 'compact fractures' (σ/am = 0-1.8).

Quartz dissolution and silica deposition in hot-dry-rock geothermal systems

Energy Technology Data Exchange (ETDEWEB)

Robinson, B.A.

1982-07-01

The kinetics of quartz dissolution control the produced fluid dissolved silica concentration in geothermal systems in which the downhole residence time is finite. The produced fluid of the Phase I, Run Segment 5 experimental Hot Dry Rock (HDR) geothermal system at Fenton Hill, NM, was undersaturated with respect to quartz in one pass through the reservoir, suggesting that the rate of granite dissolution governed the outlet dissolved silica concentration in this system. The literature data for the rate of quartz dissolution in water from 65 to 625/sup 0/C is correlated using an empirical rate law which is first order in quartz surface area and degree of undersaturation of the fluid. The Arrhenius plot (ln k vs T/sup -1/) is linear over eight orders of magnitude of the rate constant, verifying the validity of the proposed rate expression. Carefully performed quartz dissolution experiments in the present study duplicated the literature data and completed the data base in the temperature range from 150 to 250/sup 0/C. Identical experiments using crushed granite indicate that the rate of quartz dissolution in the presence of granite could be as much as 1 to 2 orders of magnitude faster than the rates observed in the pure quartz experiments. A temperature dependent HDR reservoir model incorporates the quartz dissolution rate law to simulate the dissolved silica behavior during the Fenton Hill Run Segment 5 experiment. For this low-permeability, fracture-dominated reservoir, the assumptions of one-dimensional plug flow through a vertically-inclined rectangular fracture and one-dimensional rock heat conduction perpendicular to the direction of flow are employed. These simplifications lead to an analytical solution for the temperature field in the reservoir.

Ionic diffusion in quartz studied by transport measurements, SIMS and atomistic simulations

International Nuclear Information System (INIS)

Sartbaeva, Asel; Wells, Stephen A; Redfern, Simon A T; Hinton, Richard W; Reed, Stephen J B

2005-01-01

Ionic diffusion in the quartz-β-eucryptite system is studied by DC transport measurements, SIMS and atomistic simulations. Transport data show a large transient increase in ionic current at the α-β phase transition of quartz (the Hedvall effect). The SIMS data indicate two diffusion processes, one involving rapid Li + motion and the other involving penetration of Al and Li atoms into quartz at the phase transition. Atomistic simulations explain why the fine microstructure of twin domain walls in quartz near the transition does not hinder Li + diffusion

Mineralogy, morphology, and textural relationships in coatings on quartz grains in sediments in a quartz-sand aquifer

Science.gov (United States)

Zhang, Shouliang; Kent, Douglas B.; Elbert, David C.; Shi, Zhi; Davis, James A.; Veblen, David R.

2011-01-01

Mineralogical studies of coatings on quartz grains and bulk sediments from an aquifer on Western Cape Cod, Massachusetts, USA were carried out using a variety of transmission electron microscopy (TEM) techniques. Previous studies demonstrated that coatings on quartz grains control the adsorption properties of these sediments. Samples for TEM characterization were made by a gentle mechanical grinding method and focused ion beam (FIB) milling. The former method can make abundant electron-transparent coating assemblages for comprehensive and quantitative X-ray analysis and the latter technique protects the coating texture from being destroyed. Characterization of the samples from both a pristine area and an area heavily impacted by wastewater discharge shows similar coating textures and chemical compositions. Major constituents of the coating include Al-substituted goethite and illite/chlorite clays. Goethite is aggregated into well-crystallized domains through oriented attachment resulting in increased porosity. Illite/chlorite clays with various chemical compositions were observed to be mixed with goethite aggregates and aligned sub-parallel to the associated quartz surface. The uniform spatial distribution of wastewater-derived phosphorus throughout the coating from the wastewater-contaminated site suggests that all of the coating constituents, including those adjacent to the quartz surface, are accessible to groundwater solutes. Both TEM characterization and chemical extraction results indicate there is a significantly greater amount of amorphous iron oxide in samples from wastewater discharge area compared to those from the pristine region, which might reflect the impact of redox cycling of iron under the wastewater-discharge area. Coating compositions are consistent with the moderate metal and oxy-metalloid adsorption capacities, low but significant cation exchange capacities, and control of iron(III) solubility by goethite observed in reactive transport

Three-dimensional thermoluminescence spectra of different origin quartz from Altay Orogenic belt, Xinjiang, China

International Nuclear Information System (INIS)

Tan Kaixuan; Liu Zehua; Zeng Sheng; Liu Yan; Xie Yanshi; Rieser, Uwe

2009-01-01

Three-dimensional thermoluminescence spectra are measured for different types of geological origin quartz from the Altay orogenic belt, northern Xinjiang, China. The results show striking differences which appear to be characteristic of their geological origin. Granitic quartz is dominated by emission bands at 420-430 nm, 550-560 nm, at a temperature of 170 deg. C. Pegmatite quartz is characterized by an intense 480 nm emission band at 170 deg. C. Volcanic quartz has exclusive UV (340-360 nm) and violet (410-430 nm) emission bands. Hydrothermal quartz exhibits very different TL spectral characteristics because of different hydrothermal activity and mineralization. Only one TL peaks at 485 nm/170 deg. C was observed in sedimentary quartz. An intense 730 nm emission band observed at 170 deg. C considered generally to be characteristics of feldspar was observed in quartz from granite and hydrothermal Au-bearing quartz. This TL peak is probably related to the centre of [FeO 4 ] 0 on an Si site. All samples show an intense 990-1000 nm emission band at 330 deg. C. Identical types of quartz formed in different regions or different geological and tectonic settings can also exhibit striking differences in TL spectra.

Highly differentiated magmas linked with polymetallic mineralization: A case study from the Cuihongshan granitic intrusions, Lesser Xing'an Range, NE China

Science.gov (United States)

Fei, Xianghui; Zhang, Zhaochong; Cheng, Zhiguo; Santosh, M.; Jin, Ziliang; Wen, Bingbing; Li, Zixi; Xu, Lijuan

2018-03-01

The genetic link between granitoids and polymetallic skarn mineralization has remained equivocal. The Cuihongshan skarn-porphyry W-Mo-Pb-Zn-(Fe-Cu) deposit in the eastern part of the Central Asian Orogenic Belt provides a unique example to address this issue. The major rock types in the mine area are Early Paleozoic intrusions composed of biotite syenogranite and biotite porphyritic granite and Early Mesozoic intrusions represented by porphyritic quartz monzonite, biotite monzogranite, and porphyritic granite. The diagnostic mineralogical and geochemical features indicate that the rocks belong to A2-type granites. The Early Paleozoic suite shows zircon U-Pb ages of 501 Ma, and εHf(t) values of - 4.4 to + 2.7 and + 2.4 to + 7.6, respectively. In combination with their coherent geochemical trends, these rocks are inferred to be products of in-situ differentiation. Although the Mesozoic suite shows crystallization ages of 194-196 Ma, εHf(t) values are in the range of - 2.5 to + 7.5 for the porphyritic quartz monzonite, the - 1.8 to + 4.5 values for the monzogranite and the + 2.3 to + 8.0 range for the porphyritic granite. The porphyritic quartz monzonite displays distinct mineral assemblage and shows significant compositional gap with the other two lithofacies. In contrast, the monzogranite and porphyritic granite have similar geochemical features, and are thus inferred to be co-magmatic. Considering the high SiO2 contents, variable εHf(t) (- 4.4 to + 8.0) and εNd(t) values (- 8.4 to + 0.28) for the two suites, we infer that both episodes of granitoid magmatism resulted from partial melting of crustal materials with a mixed source containing varying proportions of juvenile and Precambrian crustal components. The Early Mesozoic porphyritic granite shows a highly evolved F-rich geochemical affinity, and experienced magma-fluid interaction. Cassiterite from the calcic skarn and the magnesian skarn that coexists with magnetite orebodies shows a mean U-Pb age of 195

Content of some microelements in Bulgarian quartz

International Nuclear Information System (INIS)

Kostadinov, K.; Kuleff, I.; Djingova, R.; Todorovski, D.

1982-01-01

Data on the content of As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Eu, Fe, Hf, Hg, Ir, K, La, Lu, Mn, Nd, Na, Rb, Sb, Sm, Ta, Tb, Sc, Th, U, W, Yb, Zn obtained by instrumental neutron activation analysis are reported. The method is published elsewhere (Kuleff, I. et J. Radional. Chem. 62 (1981) 187). The results of other authors for the amount of Al, Li, Ti, obtained by atomic absorption spectrometry and Cu, P measured by destructive neutron activation analysis are also reported for 3 batches of electrothermal quartz glass, manufactured by ''Svetlina'' plant in Sliven, Bulgaria. The results for Bulgarian quartz glass are compared with literature and authors' data for similar quality glasses produced in England, France, FRG, GDR, USA and USSR. The results show that the amount of As, Au, Cd, Ce, Co, Cs, Eu, Hg, La, Ta, Yb in Bulgarian made quartz glass is lower than in a number of other similar glasses and the amount of the other impurities is close to the mean values. (authors)

Development of quartz particulate reinforced AA6063 aluminum matrix composites via friction stir processing

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S. Joyson Abraham

2016-12-01

Full Text Available Friction stir processing (FSP has been accepted as a potential method to produce aluminum matrix composites (AMCs without the drawbacks of liquid metallurgy methods. The present work focuses on the development of AMCs reinforced with quartz (SiO2 particles using FSP. Grooves with various dimensions were machined on AA6063 plates and compacted with quartz particles. A single pass FSP was carried out using a combination of optimized process parameters. The volume fraction of quartz particles in the AMCs was varied from 0 to 18 vol.% in steps of 6 vol.%. The developed AA6063/Quartz AMCs were characterized using optical, scanning and transmission electron microscopy. The quartz particles were distributed uniformly in the aluminum matrix irrespective of the location within the stir zone. The grains of the AA6063 were extensively refined by the combination of thermomechanical effect of FSP and the pinning effect of quartz particles. The dispersion of the quartz particles improved the microhardness and wear resistance of the AMCs. The role of quartz particles on the worn surface and wear debris is reported.

Historical review of quartz crystal growth

Science.gov (United States)

Iwasaki, Fumiko; Iwasaki, Hideo

2002-04-01

The history of quartz crystal growth is reviewed from the origin to the industrialization. The developing process of growth techniques is divided into the following three stages: (1) The fundamental work based on the mineralogical genetic view point, which was performed in Italy during the end of the 19th to the beginning of the 20th centuries. (2) The works to attempt the industrial application made in Germany and in England during World War II. (3) The industrialization of quartz growth after World War II. These were initiated in England, in USA and independently in Russia. The highest mass production process was developed in Japan. The historical flow is traced by the interview of several persons based on the original references.

Surface coatings on quartz grains in bentonites and their relevance to human health

International Nuclear Information System (INIS)

Wendlandt, Richard F.; Harrison, Wendy J.; Vaughan, David J.

2007-01-01

The cytotoxicity of quartz in the human lung is recognized to be dependent on both the inherent properties of the silica dust and external factors related to the history of the dust and including the presence of surface contamination. In this study, the physical and chemical surface properties of quartz grains in commercial bentonite deposits from the western (South Dakota) and southern (Alabama) USA were investigated. Measured quartz contents of bentonites range from 1.9 to 8.5 wt% with the <10 μm size fraction comprising 6-45% of this total. Trace element contents (Fe-Ti-Al) of quartz grains from any given bentonite are similar, indicating a single origin for the quartz with little if any contamination from other sources. Surface coatings are pervasive on all quartz grains and resist removal by repeated vigorous washings and reaction with HCl. Textural attributes and XPS and EDS analyses of these coatings are consistent with most being montmorillonite and, less frequently, mixtures of montmorillonite and opaline silica. Opaline silica (opal-A and opal-CT) occurs in two texturally distinct generations: an early massive grain-coating event and as later lepispheres. Montmorillonite coating thicknesses range from <1 μm to more than 10 μm thick. Surfaces of plagioclase, K-feldspar, and biotite grains are conspicuously devoid of montmorillonite coatings, but may show sparse distributions of opal-CT lepispheres. HRTEM has not confirmed a topotactic relationship or atomic structural concordance between montmorillonite coatings and underlying quartz grains. Alternatively, a precursor volcanic glass phase that coats the quartz surfaces during volcanic eruption and/or preferential early precipitation of opaline silica on quartz may provide substrates for development of montmorillonite coatings. Estimations of montmorillonite biodurability under pulmonary pH conditions suggest possible prolonged sequestration of respired bentonite quartz grains from contact with lung

Evaluation of trapping parameters of annealed natural quartz

International Nuclear Information System (INIS)

Zhou, Rui; Wei, Ming-Jian; Song, Bo; Zhang, Yan; Zhao, Qiu-Yue; Pan, Bao-Lin; Li, Teng-Fei

2016-01-01

The thermoluminescence (TL) trapping parameters of annealed quartz have been investigated. The apparent TL peaks observed at temperatures of 133 °C, 211 °C, 266 °C and 405 °C, respectively, were named Peak I, Peak II, Peak III and Peak IV. The T_m − T_s_t_o_p method is applied to investigate the number of peaks and their positions, and to obtain the trap distributions in the quartz. Peak shape (PS), Hoogenstraaten method (Various Heating Rates Method, VHR), and Computerized Glow Curve Deconvolution (CGCD) are used to evaluate the trapping parameters of the annealed quartz. The glow curve can be considered as a superposition of at least nine overlapping peaks. These peaks show up at 133 °C, 211 °C, 266 °C, 308 °C, 333 °C, 384 °C, 441 °C, 466 °C and 484 °C. The PS method can be only used in evaluating the parameters for Peaks I. The VHR method can be used in evaluating the trapping parameters for the first three peaks. CGCD method is complementary to obtaining parameters for the sub-peaks, and the thermal quenching correction with the Urbach’s method is necessary. The Urbach’s coefficient for the quartz is 30.03 kT_m.

Evaluation of trapping parameters of annealed natural quartz

Energy Technology Data Exchange (ETDEWEB)

Zhou, Rui [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); Shisanling Seismic Station, Institute of Earthquake Science, CEA, 102200 Beijing (China); Wei, Ming-Jian, E-mail: weimj@cnu.edu.cn [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); Song, Bo [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); Beijing Jing Yuan School, 100040 Beijing (China); Zhang, Yan [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); School of TaiPingqiao, Nan Lu of West Railway Station, 100073 Beijing (China); Zhao, Qiu-Yue [Key Laboratory of Tourism and Resources Environment in Universities of Shandong, Taishan University, 271000 Tai’an (China); Pan, Bao-Lin; Li, Teng-Fei [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China)

2016-05-15

The thermoluminescence (TL) trapping parameters of annealed quartz have been investigated. The apparent TL peaks observed at temperatures of 133 °C, 211 °C, 266 °C and 405 °C, respectively, were named Peak I, Peak II, Peak III and Peak IV. The T{sub m} − T{sub stop} method is applied to investigate the number of peaks and their positions, and to obtain the trap distributions in the quartz. Peak shape (PS), Hoogenstraaten method (Various Heating Rates Method, VHR), and Computerized Glow Curve Deconvolution (CGCD) are used to evaluate the trapping parameters of the annealed quartz. The glow curve can be considered as a superposition of at least nine overlapping peaks. These peaks show up at 133 °C, 211 °C, 266 °C, 308 °C, 333 °C, 384 °C, 441 °C, 466 °C and 484 °C. The PS method can be only used in evaluating the parameters for Peaks I. The VHR method can be used in evaluating the trapping parameters for the first three peaks. CGCD method is complementary to obtaining parameters for the sub-peaks, and the thermal quenching correction with the Urbach’s method is necessary. The Urbach’s coefficient for the quartz is 30.03 kT{sub m}.

75 FR 30282 - Airworthiness Directives; Quartz Mountain Aerospace, Inc. Model 11E Airplanes

Science.gov (United States)

2010-06-01

... Airworthiness Directives; Quartz Mountain Aerospace, Inc. Model 11E Airplanes AGENCY: Federal Aviation... airworthiness directive (AD) for all Quartz Mountain Aerospace, Inc. Model 11E airplanes. This AD requires you... reference of certain publications listed in this AD. ADDRESSES: Quartz Mountain Aerospace, Inc. is in...

Geology, geochemistry and fluid inclusion of Qarachilar Cu-Mo-Au quartz veins, northeast of Kharvana, East Azerbaijan

Directory of Open Access Journals (Sweden)

Fariba Asiay Soufiani

2018-04-01

ICP-MS for trace elements and REE at the Zarazma Co., Tehran, Iran. Microthermometric data were performed on primary fluid inclusions using the Linkam THMS600 heating–freezing stage at the Iranian Mineral Processing Research Center (IMPRC, Tehran, Iran. Results The rock units exposed in the Qarachilar area are different sets of magmatic phases of QDB including granodiorite-quartz monzodiorite, porphyritic granite, quartz monzonite and acidic-intermediate dikes. Granodiorite-quartz monzodiorite is the dominant phase which hosts the Qarachilar quartz-sulfide veins. Mineralization at Qarachilar occurs as three quartz-sulfide veins. The veins reach up to 700-m in length and average 1-m in width, reaching a maximum of 2-m. They are generally steeply-dipping to the NE at 80°. The reported grades of Mo, Cu and Au range from 20 ppm to 3.6 wt%, 0.7 wt% to 5 wt%, and 0.23 to 37.2 g/t, respectively. Four stages of mineralization can be distinguished at Qarachilar. Stage-1 is represented by quartz veins (ranging from centimeters up to ≤1-m width that contain variable amounts of chalcopyrite and pyrite. Stage-2 is marked by Tm-h and type-2 (Tm-h>Th inclusions are homogenized in the range of 197-530°C and 203-375°C, respectively. They have a calculated bulk salinity of 29.5 to 55.1 and 32.4 to 45.6 wt% NaCl equiv., respectively. The variations in salinity and Th could be explained by a combination of mixing and boiling hydrothermal fluids. These processes led to the deposition of Cu, Mo and Au in the veins. Geology, ore mineralogy, textures, geochemistry and microthermometric data of Qarachilar occurrence are comparable with vein-type Cu-Mo-Au mineralization related to Cu-Mo porphyry and intrusion related gold deposits. References Jamali, H., Dilek, Y., Daliran, F., Yaghubpour, A.M. and Mehrabi, B., 2010. Metallogeny and tectonic evolution of the Cenozoic Ahar-Arasbaran volcanic belt, northern Iran. International Geology Review, 52(4–6: 608–630. Jamali, H. and Mehrabi, B

Dose response on the 110 °C thermoluminescence peak of un-heated, synthetic Merck quartz

Energy Technology Data Exchange (ETDEWEB)

Kaya Keleş, Şule, E-mail: sule.kaya@ankara.edu.tr; Meriç, Niyazi; Polymeris, George S.

2016-07-15

Studies on 110 °C TL peak have been carried out using natural quartz from different origins and synthetic quartz produced by different suppliers. The interest in quartz is due to its usage in dating and retrospective dosimetry as a main material; both synthetic and natural types of quartz yield the 110 °C TL peak in their glow curve. In most studies to understand the physical mechanism behind the TL system, synthetic quartz samples are used and there are many investigations about dose response, in both low and high radiation dose region. In these studies generally synthetic quartz samples produced by Sawyer Research Products are used and the studies showed that both heated and un-heated synthetic quartz samples have intense supra-linear responses. Supra-linearity was enhanced by applying a pre-irradiation while several models have been developed towards an explanation to these supra-linearity effects. In this study commercially available synthetic Merck quartz was used. Different combinations of optical filters were used to obtain dose response curves upto 266 Gy and the effect of pre-dose to these dose response curves was studied. Un-pre-dosed Merck quartz samples dose supra-linearity index is below 1 independently on the optical filters; so Merck quartz showed linear or sub-linear dose response.

The Effect of Quartz on the Flotation of Fine Wolframite with Octyl Hydroxamic Acid

Directory of Open Access Journals (Sweden)

Qingyou Meng

2017-09-01

Full Text Available The influence of quartz on the flotation of fine wolframite using octyl hydroxamic acid (OHA as the collector was investigated by micro-flotation tests, inductively coupled plasma (ICP measurements, adsorption experiments, zeta potential, and Fourier transform infrared spectroscopy (FT-IR analysis. Micro-flotation tests showed that a large difference in floatability existed between fine wolframite and quartz in the pH range of 7.0 to 10.0. However, in a synthetic mixture, the flotation separation of fine wolframite from quartz became more difficult as the particle size of the latter decreased. When a dissolved solution of wolframite was used as the flotation medium, quartz floatability improved significantly. Zeta potentials of quartz particles shifted positively in the dissolved solution of wolframite compared to distilled water, especially at a pH level of 7.0–10.0, which was attributed to the metal ions dissolved from the wolframite being adsorbed onto the quartz surface. The surface activation of quartz led to an increase in the OHA adsorption and made the surface hydrophobic. FT-IR analysis further demonstrated that OHA could adsorb onto the activated quartz surface through a dominantly chemical process.

Apatite-brannerite-pitchblende association in hydrothermal quartz veins

International Nuclear Information System (INIS)

Brodin, B.V.; Mel'nikova, A.M.; Osipov, B.S.; Pavlov, E.G.

1976-01-01

A study into the vein quartz mineralization confined to the tectonic zones of crush and silicification in sedimentary-igneous rocks of the lower Paleozoic has been made. The physicochemical characteristics of minerals were studied by way of optical and electron microscopy, chemical, laser-microspectral and X-ray structural analyses, microprobing and alpha-microradiography. 3 mineral associations have been discriminated, representative of the sequence of hydrothermal mineralization. An unusual parogenesis of pitchblende and brannerite with apatite, xenotime and more recent goethite has been revealed. The results are indicative of a medium-low-temperature hydrothermal process occurring at the final stages of formation of uraniferrous quartz veins. By composition and mineralization sequence, the latters are close to low- and medium-temperature uranium-quartz-chlorite-hydromica formations with apatite, coffinite, brannerite and pitchblende. The weak initial metamictization of goethite in veins 80 to 100 million years old is due to the radioactive effect of the submicroscopic radioactive mineral impurity on the crystalline lattice

Oxygen isotopic ratios in quartz as an indicator of provenance of dust

International Nuclear Information System (INIS)

Jackson, M.L.

1977-01-01

Quartz was isolated in the long range aerosol size range (fine silt, 1-10 μm in diameter) from atmospheric aerosols, wind-erosive soils, soil silts, shales, and Pacific pelagic sediments of the Northern and Southern Hemispheres, to trace their provenance or origin, as part of a study of dust mineral sequestering of 137 Cs and other products of nuclear fission. The oxygen isotopic ratio ( 18 O/ 16 O) was determined by mass spectrometry. The provenance has been established for this fine silt fraction which reflects the relative proportion of two classes of quartz source: (a) weathering of igneous and metamorphic rocks (high temperature origin and low 18 O/ 16 O ratio) and (b) of quartz crystallized in cherts and overgrowths (low temperature origin and high 18 O/ 16 O ratio). This quartz mixing ratio is a basic model or paradigm. Analyses of present day atmospheric aerosols and eolian-derived soils, Pacific pelagic sediments, and now-raised Phanerozoic marine sediments show that the Northern and Southern Hemispheres have separate large-scale reservoirs of the fine grain sizes that contribute to aerosol dusts. These can be identified by distinctive values of 18 O/ 16 O ratios of the quartz therein. The difference in quartz delta 18 O value in parts per thousand per ml ( 0 / 00 of about 12 +- 2 0 / 00 in Southern Hemisphere mixed detrital sediments and about 19 +- 2 0 / 00 in those of the Northern Hemisphere (for constant size, the 1-10 μm size fraction) results from the presence of a considerably larger proportion of quartz having low-temperature origin and higher delta 18 O values (chert, silica overgrowths, etc.) in the Northern Hemisphere reservoirs. The early paleoclimatic and paleogeochemical differences remain the control of the North-South Hemisphere difference in delta 18 O values in long-range aerosol sized quartz

OSL and IRSL characteristics of quartz and feldspar from southern California, USA

International Nuclear Information System (INIS)

Lawson, Michael J.; Roder, Belinda J.; Stang, Dallon M.; Rhodes, Edward J.

2012-01-01

Southern California comprises of a wide range of diverse landscapes and environments, from high mountains with glacial and periglacial sediments to deserts with large sand dunes, extensive alluvial fans and ephemeral playas. Highly active tectonic processes has exposed ancient (c. 2 Ga) plutonic and metamorphic basement from deep within the crust, while similar Palaeozoic, Mesozoic and Cenozoic rocks are also common. A rich array of volcanic lithologies extending into the late Quaternary complement many thick sedimentary sequences that formed in equally diverse ancient environments typical of an accreting active continental margin. In some locations, notably in the Coachella Valley close to Palm Springs and the Salton Sea, low OSL sensitivity and poor characteristics restrict the application of the quartz SAR protocol to date late Pleistocene and Holocene fluvial sediments. In other locations such as the Malibu coastline, high sensitivity of the quartz OSL signal is observed, despite local source rocks being dominated by volcanic lithologies. Problems of poor quartz characteristics, along with uncertainty in predicting quartz OSL behavior for future dating campaigns poses a significant problem for projects, in particular for neotectonic contexts. While K-feldspar has been used extensively to date eolian and fluvial sediments in southern California, little information regarding signal stability is available. We explore the characteristics of both quartz and feldspar sub-samples from eolian, fluvial, lacustrine environments, in order to help develop mineral selection criteria for optical dating applications and clarify these issues. The importance of radiation quenching in quartz grains recently eroded from bedrock and the role of fires in enhancing OSL sensitivity are considered. The relative bleachability of quartz and feldspar fractions, along with thermal stability considerations is discussed. A simple test for quartz OSL signal contamination based on thermal

Microscopy and Cathodoluminescence Spectroscopy Characterization of Quartz Exhibiting Different Alkali-Silica Reaction Potential.

Science.gov (United States)

Kuchařová, Aneta; Götze, Jens; Šachlová, Šárka; Pertold, Zdeněk; Přikryl, Richard

2016-02-01

Different quartz types from several localities in the Czech Republic and Sweden were examined by polarizing microscopy combined with cathodoluminescence (CL) microscopy, spectroscopy, and petrographic image analysis, and tested by use of an accelerated mortar bar test (following ASTM C1260). The highest alkali-silica reaction potential was indicated by very fine-grained chert, containing significant amounts of fine-grained to cryptocrystalline matrix. The chert exhibited a dark red CL emission band at ~640 nm with a low intensity. Fine-grained orthoquartzites, as well as fine-grained metamorphic vein quartz, separated from phyllite exhibited medium expansion values. The orthoquartzites showed various CL of quartz grains, from blue through violet, red, and brown. Two CL spectral bands at ~450 and ~630 nm, with various intensities, were detected. The quartz from phyllite displayed an inhomogeneous dark red CL with two CL spectral bands of low intensities at ~460 and ~640 nm. The massive coarse-grained pegmatite quartz from pegmatite was assessed to be nonreactive and displayed a typical short-lived blue CL (~480 nm). The higher reactivity of the fine-grained hydrothermal quartz may be connected with high concentrations of defect centers, and probably with amorphized micro-regions in the quartz, respectively; indicated by a yellow CL emission (~570 nm).

Absorption and luminescence of crystalline quartz under electron nanosecond irradiation

Energy Technology Data Exchange (ETDEWEB)

Gritsenko, B P; Lisitsyn, V M; Stepanchuk, V N [Tomskij Politekhnicheskij Inst. (USSR)

1981-02-01

The purpose of the study is continuation of investigations of principal regularities of production and destruction of short-lived defects in quartz and accompanying luminescence under electron pulse irradiation. For investigation purposes samples of crystalline synthetic quartz have been used. The irradiation has been performed at 80-400 K temperatures by means of an electron pulse accelerator with parameters: electron flow pulse duration 10 ns, pulse current density up to 1000 A/cm/sup 2/, electron mean energy 200 keV. Temperature-time characteristics of absorption and luminescence spectrum are studied. It has been found that quartz irradiation by electron pulses of nanosecond duration leads to appearance of short-lived bands of optical absorption at 4.1 and 5.15 eV to which by kinetic parameters correspond luminescence bands at 2.6 and 3.1 eV, respectively. The enumerated absorption bands are induced by quartz irradiation independently of the prehistory and phase state of the sample and are caused obviously by intrinsic radiation defects. Possible models of such defects are suggested.

Study of green quartz of hydrothermal origin treated by gamma radiation

International Nuclear Information System (INIS)

Enokihara, Cyro Teiti

2013-01-01

A specific variety of quartz showing a green color in nature or induced artificially by radiation is quite rare. This can be explained by the fact that the mechanism of formation of this color is very different from the ones widely discussed in the literature and responsible for the formation of the fumee, citrine and amethyst types of quartz, including the prasiolite (leak green quartz) formed by heating amethyst from Montezuma, Brazil. Only two occurrences are known today, where this type of quartz can be found: Canada, at the Thunder Bay Amethyst Mine, Ontario, a small district, and Brazil, at widely scattered geode occurrences along a 600 km stretch from Quarai at Brazils southernmost tip to Uberlandia in Minas Gerais. These two occurrences have been formed by strong hydrothermal activities, at Thunder Bay due to tectonics and in Brazil by meteoric and hydrothermal waters of the Guarani aquifer. That way much quartz crystals showed a very fast growth history facilitating the formation of growth defects (twinning, small angle tilting, mosaic growth, striations) and the uptake of water in form of micro inclusions, molecular water, silanol (Si-OH) and OH. This type of quartz can be considered 'wet quartz', similar to synthetic quartz. The water content with up to 3200 ppm by weight exceeds the amount of charge balancing cations (Fe, Al, Li). There is no correlation between water content and cations as in other color varieties. Instead, silanol complexes are formed, which by radiation due to gamma rays form the color center NBOHC (non-bonding oxygen hole defect), showing absorption between 590 to 620 nm and leaving a transmission window at about 550nm, responsible for the green color. To characterize samples which will be colored green by gamma rays analyses by ICP, NAA, Electron microscopy, water loss techniques and UV-VIS and NIR-FTIR spectroscopic have been made. The spectroscopic water determination showed less water (up to 2300 ppm by weight) compared with

Correct interpretation of diffraction properties of quartz crystals for X-ray optics applications

Energy Technology Data Exchange (ETDEWEB)

Huang, Xian-Rong; Gog, Thomas; Kim, Jungho; Kasman, Elina; Said, Ayman H.; Casa, Diego M.; Wieczorek, Michael; Hönnicke, Marcelo G.; Assoufid, Lahsen

2018-02-01

Quartz has hundreds of strong Bragg reflections that may offer a great number of choices for making fixed-angle X-ray analyzers and polarizers at virtually any hard X-ray energies with selectable resolution. However, quartz crystals, unlike silicon and germanium, are chiral and may thus appear in two different forms of handedness that are mirror images. Furthermore, because of the threefold rotational symmetry along thecaxis, the {h₁h₂h₃L} and {h₂h₁h₃L} Bragg reflections may have quite different Darwin bandwidth, reflectivity and angular acceptance, although they have the same Bragg angle. The design of X-ray optics from quartz crystals therefore requires unambiguous determination of the orientation, handedness and polarity of the crystals. The Laue method and single-axis diffraction technique can provide such information, but the variety of conventions used in the literature to describe quartz structures has caused widespread confusion. The current studies give detailed guidelines for design and fabrication of quartz X-ray optics, with special emphasis on the correct interpretation of Laue patterns in terms of the crystallography and diffraction properties of quartz. Meanwhile, the quartz crystals examined were confirmed by X-ray topography to have acceptably low densities of dislocations and other defects, which is the foundation for developing high-resolution quartz-based X-ray optics.

Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: I. Iron-copper-zinc-lead sulfide solubility relations

Science.gov (United States)

Hemley, J.J.; Cygan, G.L.; Fein, J.B.; Robinson, G.R.; d'Angelo, W. M.

1992-01-01

Experimental studies, using cold-seal and extraction vessel techniques, were conducted on Fe, Pb, Zn, and Cu sulfide solubilities in chloride soultions at temperatures from 300?? to 700??C and pressures from 0.5 to 2 kbars. The solutions were buffered in pH by quartz monzonite and the pure potassium feldspar-muscovite-quartz assemblage and in fS2-fO2 largely by the assemblage pyrite-pyrrhotite-magnetite. Solubilities increase with increasing temperature and total chloride, and decrease with increasing pressure. The effect of increasing chloride concentration on solubility reflects primarily a shift to lower pH via the silicate buffer reactions. Similarity in behaviour with respect to the temperature and pressure of Fe, Zn, and Pb sulfide solubilities points to similarity in chloride speciation, and the neutral species appear to be dominant in the high-temperature region. -from Authors

Geospatializing The Klang Gate Quartz Ridge in Malaysia: A Technological Perspective

Science.gov (United States)

Azahari Razak, Khamarrul; Mohamad, Zakaria; Zaki Ibrahim, Mohd; Azad Rosle, Qalam; Hattanajmie Abd Wahab, Mohd; Abu Bakar, Rabieahtul; Mohd Akib, Wan Abdul Aziz Wan

2015-04-01

Establishment of inventories on geological heritage, or geoheritage resources is a step forward for a comprehensive geoheritage management leading to a better conservation at national and global levels. Compiling and updating inventory of geoheritage is a tedious process and even so in a tropical environment. Malaysia has a tremendous list of geodiversity and generating its national database is a multi-institutional effort and worthwhile investment. However, producing accurate and reliable characteristics of such landform and spectacular geological features remained elusive. The advanced and modern mapping techniques have revolutionized the mapping, monitoring and modelling of the earth surface processes and landforms. Yet the methods for quantification of geodiversity physical features are not fully utilized in Malaysia for a better understanding its processes and activity. This study provides a better insight into the use of advanced active remote sensing technology for characterizing the forested Quartz Ridge in Malaysia. We have developed the novel method and tested in the Klang Gates Quartz Ridge, Selangor. The granitic country rock made up by quartz mineral is known as the longest quartz ridge in Malaysia and characterized by rugged topography, steep slopes, densely vegetated terrain and also rich-biodiversity area. This study presents an integrated field methodological framework and processing scheme by taking into account the climatic, topographic, geologic, and anthropogenic challenges in an equatorial region. Advanced terrestrial laser scanning system was used to accurately capture, map and model the ridge carried out within a relatively stringent time period. The high frequency Global Navigation Satellite System and modern Total Station coupled with the optical satellite and radar imageries and also advanced spatial analysis were fully utilized in the field campaign and data assessment performed during the recent monsoon season. As a result, the mapping

Complex impedance spectroscopy of alkali impurities in as-grown, irradiated and annealed quartz

International Nuclear Information System (INIS)

Devautour-Vinot, S.; Cambon, O.; Prud'homme, N.; Giuntini, J. C.; Boy, J.-J.; Cibiel, G.

2007-01-01

This work compares the dielectric relaxation properties of different crystalline quartz materials, according to their source (natural or synthetics). It is shown that these relaxation properties are due to a hopping process of alkaline (Li + , Na + , and K + ) impurities located near [Al-O 4 ] 5- tetrahedra. A detailed analysis, in terms of the distribution function of the dielectric loss peak, allowed us to perfectly distinguish the different types of as-grown quartz. We show that (i) the natural quartz has less stable M + charge carriers than the synthetic materials and that (ii) the homogeneity of the M + trapping sites, created by the [Al-O 4 ] 5- tetrahedra, strongly depends on the crystal growth conditions. These features were then studied using quartz samples with different treatment conditions: as-grown, irradiated, or annealed at high temperature. We propose that the irradiation greatly facilitates the M + relaxation, by creating additional low energy M + hosting sites, whose number depends on the source of the quartz crystals. We also show that for 100 krad irradiation, the saturation state of the defects is already reached for all the materials under consideration. Finally, we propose that the irradiation followed by annealing at 450 deg. C improves the M + stability and homogeneity in quartz materials, compared with the as-grown materials, this trend being much more relevant for the natural than for the synthetic quartz

Stable isotope compositions of quartz pebbles and their fluid inclusions as tracers of sediment provenance: Implications for gold- and uranium-bearing quartz pebble conglomerates

Energy Technology Data Exchange (ETDEWEB)

Vennemann, T.W.; Kesler, S.E.; O' Neil, J.R. (Univ. of Michigan, Ann Arbor (United States))

1992-09-01

Oxygen isotope compositions of pebbles from late Archean to paleo-Proterozoic gold- and/or uranium-bearing oligomictic quartz pebble conglomerates of the Witwatersrand district, South Africa, and Huronian Supergroup, Canada, were determined in an attempt to define the nature of the source terrain. The [delta][sup 18]O values of quartz pebbles within any one sample typically vary by [approximately] 4[per thousand] or more, but occasionally by as much as 8[per thousand], even for adjacent pebbles within the same hand specimen. In addition, adjacent quartz pebbles of widely contrasting [delta][sup 18]O values also preserve distinct isotopic signatures of their fluid inclusions. This overall heterogeneity suggests that the pebbles did not undergo significant oxygen isotope exchange after incorporation in the conglomerates. Therefore, oxygen isotope analyses of such quartz pebbles, in combination with a detailed investigation of their mineral and fluid inclusions, can provide a useful method for characterizing pebble populations and hence dominant sediment source modes. Comparison of values found in this study with [delta][sup 18]O values of quartz from Archean granites, pegmatites, and mesothermal greenstone gold veins, i.e., [delta][sup 18]O values of sources commonly proposed for the conglomerate ores, suggests that uranium is derived from a granitic source, whereas gold has a mesothermal greenstone gold source. Low [delta][sup 18]O values of chert pebbles (9[per thousand] to 11.5[per thousand]) relative to those expected for Archean and Proterozoic marine cherts (commonly [ge] 17[per thousand]) effectively exclude marine cherts, and therefore, auriferous iron formations and exhalatives, as likely sources of gold.

Stable isotope compositions of quartz pebbles and their fluid inclusions as tracers of sediment provenance: Implications for gold- and uranium-bearing quartz pebble conglomerates

International Nuclear Information System (INIS)

Vennemann, T.W.; Kesler, S.E.; O'Neil, J.R.

1992-01-01

Oxygen isotope compositions of pebbles from late Archean to paleo-Proterozoic gold- and/or uranium-bearing oligomictic quartz pebble conglomerates of the Witwatersrand district, South Africa, and Huronian Supergroup, Canada, were determined in an attempt to define the nature of the source terrain. The δ 18 O values of quartz pebbles within any one sample typically vary by ∼ 4 per-thousand or more, but occasionally by as much as 8 per-thousand, even for adjacent pebbles within the same hand specimen. In addition, adjacent quartz pebbles of widely contrasting δ 18 O values also preserve distinct isotopic signatures of their fluid inclusions. This overall heterogeneity suggests that the pebbles did not undergo significant oxygen isotope exchange after incorporation in the conglomerates. Therefore, oxygen isotope analyses of such quartz pebbles, in combination with a detailed investigation of their mineral and fluid inclusions, can provide a useful method for characterizing pebble populations and hence dominant sediment source modes. Comparison of values found in this study with δ 18 O values of quartz from Archean granites, pegmatites, and mesothermal greenstone gold veins, i.e., δ 18 O values of sources commonly proposed for the conglomerate ores, suggests that uranium is derived from a granitic source, whereas gold has a mesothermal greenstone gold source. Low δ 18 O values of chert pebbles (9 per-thousand to 11.5 per-thousand) relative to those expected for Archean and Proterozoic marine cherts (commonly ≥ 17 per-thousand) effectively exclude marine cherts, and therefore, auriferous iron formations and exhalatives, as likely sources of gold

Dew point fast measurement in organic vapor mixtures using quartz resonant sensor

Science.gov (United States)

Nie, Jing; Liu, Jia; Meng, Xiaofeng

2017-01-01

A fast dew point sensor has been developed for organic vapor mixtures by using the quartz crystal with sensitive circuits. The sensor consists of the quartz crystal and a cooler device. Proactive approach is taken to produce condensation on the surface of the quartz crystal, and it will lead to a change in electrical features of the quartz crystal. The cessation of oscillation was measured because this phenomenon is caused by dew condensation. Such a phenomenon can be used to detect the dew point. This method exploits the high sensitivity of the quartz crystal but without frequency measurement and also retains the stability of the resonant circuit. It is strongly anti-interfered. Its performance was evaluated with acetone-methanol mixtures under different pressures. The results were compared with the dew points predicted from the universal quasi-chemical equation to evaluate the performance of the proposed sensor. Though the maximum deviations of the sensor are less than 1.1 °C, it still has a fast response time with a recovery time of less than 10 s, providing an excellent dehumidifying performance.

Influence of hydrogen on optical destruction of the irradiated quartz glass

International Nuclear Information System (INIS)

Bedilov, M.R.; Beysembayeva, Kh.B.; Sabitov, M.S.

2002-01-01

The influence of concentration impurity of hydrogen on optical destruction of a quartz glass was investigated. As objects of researches the fragments of capsules of industrial lamps OQG, intended for job in low and hard load operation, modes i.e. lamp IFF-500 and IFF-8000 respectively were taken. The results of the elemental analysis of capsules lamps IFF-500 and IFF-8000 showed their complete identity. The exception was made only for an impurity of H, contents of which in a material of an environment of a lamp capsule IFF-500 was almost of the order higher than in quartz glass of lamp capsule IFF-8000 (10 -2 %). Absence in structure of investigated by us of Cl ions, as well as the available concentration of H, allowed to make the conclusion, that the quartz glasses used for manufacturing of environments of lamps capsules, investigated by us, are the full pump lamps and represent glasses of gas melt up; and the quartz glass of a lamp IFF-500 was melt- up or is processed in hydrogen. As of spectra of absorption results of research showed, quartz glass of an of a lamp capsule IFF-500, containing highest quantity impurity of hydrogen, at flux, not exceeding 10 18 neutron/cm 2 , is less painted in comparison with an capsule IFF-8000. Smaller density of coloring of capsules containing higher concentration H, is connected to the hydrogen, existing in glass, blocks the potential centers of capture holes as defective aluminum oxygen tetrahedron of non-bridge of oxygen. The authors found out, that at high γ-radiation and influence flux of neutrons leads to degradation of regular ≡Si-O-Si≡ connections in quartz glasses producing defects as non-bridge oxygen and three-coordinate of silicon, and also production of vacancies of oxygen. By results of the researches, carried out by us, at increase of concentration of hydrogen ions in quartz glass process of structural defective formation intensifies. Research of beam durability of quartz glasses of environments of not

BENTONITE-QUARTZ SAND AS THE BACKFILL MATERIALS ON THE RADIOACTIVE WASTE REPOSITORY

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Raharjo Raharjo

2010-06-01

Full Text Available An investigation of the contribution of quartz sand in the bentonite mixture as the backfill materials on the shallow land burial of radioactive waste has been done. The experiment objective is to determine the effect of quartz sand in a bentonite mixture with bentonite particle sizes of -20+40, -40+60, and -60+80 mesh on the retardation factor and the uranium dispersion in the simulation of uranium migration in the backfill materials. The experiment was carried out by the fixed bed method in the column filled by the bentonite mixture with a bentonite-to-quartz sand weight percent ratio of 0/100, 25/75, 50/50, 75/25, and 100/0 on the water saturated condition flown by uranyl nitrate solution at concentration (Co of 500 ppm. The concentration of uranium in the effluents in interval 15 minutes represented as Ct was analyzed by spectrophotometer, then using Co and Ct, retardation factor (R and dispersivity ( were determined. The experiment data showed that the bentonite of -60+80 mesh and the quartz sand of -20+40 mesh on bentonite-to-quartz sand with weight percent ratio of 50/50 gave the highest retardation factor and dispersivity of 18.37 and 0.0363 cm, respectively.   Keywords: bentonite, quartz sand, backfill materials, radioactive waste

The uranium deposits of Ontario

International Nuclear Information System (INIS)

Robertson, J.A.

1981-01-01

The principal types of uranium deposits in Ontario are carbonatites and fenites, alkalic volcanic rocks, pegiatites, calc-silicate rocks, pyritic quartz-pebble conglomerates, polymictic conglomerates and some pelitic rocks, and various 'pitchblende' deposits including late Precambrian unconformities, possibly late Precambrian diabase dikes, and other unconformities: carbonates, sandstones, lignites, and semi-pelitic rocks of middle and upper Precambrian age. Only red unzoned pegmatite and the pyritic quartz-pebble conglomerate have supported production. Ontario reasonably assured and estimated resources in the economic and subeconomic categories in 1977 amounted to 553 000 tonnes U, and 1977 production was 4000 tonnes U. Measured, indicated, and inferred resources in the Elliot Lake - Agnew Lake area are at least 400 000 tonnes U. The latter deposits are also a significant thorium resource. Geological features reflecting major changes in physics and chemistry are prime controls on distribution of uranium deposits. Geological province and subprovince boundaries, major faults, higher metamorphic grades, domain boundaries related to quartz monzonite batholiths, alkalic complexes, and the distribution of carbonate rocks are examples of such geological features

Recent progress in the performances of ultrastable quartz resonators and oscillators

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Salzenstein Patrice

2016-01-01

Full Text Available Stressed compensated (SC cut led recently to the best frequency stability ever obtained with a quartz oscillator, 2.5 × 10−14 for the flicker frequency modulation (FFM floor. This result is confirmed in this paper with a 3.2 × 10−14 ± 1.1 × 10−14. The quartz resonator is integrated in a 5 MHz enhanced aging box double oven controlled oscillator. After reminding a bit of history, this paper describes how the first significant development in terms of ultra-stable quartz state-of-the-art oscillators was performed in the last 20 years, how the resonators were chosen, and main information about the development of adequate electronics and how to mechanically and thermally stabilized such an ultra-stable oscillator. We also present how to characterize the expected performances, and hot topics in quartz based oscillators.

Development of a red TL detection system for a single grain of quartz

International Nuclear Information System (INIS)

Yawata, T.; Hashimoto, T.

2007-01-01

Red thermoluminescence (RTL) of natural quartz grains offers many desirable properties for quaternary chronology and archaeological dating, although RTL measurements suffer from high thermal background due to black-body radiation on heating. To reduce the thermal background to as low a level as possible, a silver sample disc covered with a biotite plate with a sample hole was used in combination with a light guide, cluster heater, optical filters, and photomultiplier tube cooling to -20 deg. C in the present system. As a result, the thermal background decreased from 2x10 4 to 1000 cps in the temperature range 350-380 deg. C, resulting in a detection limit of approximately 100 cps, corresponding to the RTL signal from a single quartz grain (250-500μm) irradiated with 4.0 Gy. In addition, application of lower heating rates retarded the thermal quenching effect, resulting in high RTL signals, which are preferable for young or insensitive quartz samples. Using RTL measurements with the single quartz grain method under optimal RTL conditions, comparison of equivalent doses from artificially irradiated single quartz grains to the known dose was within the 20% measurement error. Based on equivalent dose determinations for single quartz grains, large irregularities on non-etched quartz surfaces might be very detrimental to the TL detection process. This result confirms that surface etching treatment is required to achieve reliable dating with high counting efficiency

The Role of Source Material in Basin Sedimentation, as Illustrated within Eureka Valley, Death Valley National Park, CA.

Science.gov (United States)

Lawson, M. J.; Yin, A.; Rhodes, E. J.

2015-12-01

Steep landscapes are known to provide sediment to sink regions, but often petrological factors can dominate basin sedimentation. Within Eureka Valley, in northwestern Death Valley National Park, normal faulting has exposed a steep cliff face on the western margin of the Last Chance range with four kilometers of vertical relief from the valley floor and an angle of repose of nearly 38 degrees. The cliff face is composed of Cambrian limestone and dolomite, including the Bonanza King, Carrara and Wood Canyon formations. Interacting with local normal faulting, these units preferentially break off the cliff face in coherent blocks, which result in landslide deposits rather than as finer grained material found within the basin. The valley is well known for a large sand dune, which derives its sediment from distal sources to the north, instead of from the adjacent Last Chance Range cliff face. During the Holocene, sediment is sourced primary from the northerly Willow Wash and Cucomungo canyon, a relatively small drainage (less than 80 km2) within the Sylvan Mountains. Within this drainage, the Jurassic quartz monzonite of Beer Creek is heavily fractured due to motion of the Fish Valley Lake - Death Valley fault zone. Thus, the quartz monzonite is more easily eroded than the well-consolidated limestone and dolomite that forms the Last Change Range cliff face. As well, the resultant eroded material is smaller grained, and thus more easily transported than the limestone. Consequently, this work highlights an excellent example of the strong influence that source material can have on basin sedimentation.

Petrology, Magnetic susceptibility, Tectonic setting and mineralization associated with Plutonic and Volcanic Rocks, Eastern Bajestan and Taherabad, Iran

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Malihe Ghoorchi

2009-09-01

Full Text Available Study area is located in district of Bajestan and Ferdows cities, NE of Iran. Structurally, this area is part of Lut block. The oldest exposed rocks, to the north of intrusive rocks and in Eastern Bajestan, are meta-chert, slate, quartzite, thin-bedded crystalline limestone and meta-argillite. The sedimentary units are: Sardar Formation (Carboniferous, Jamal Formation (Permian, Sorkh Shale and Shotori Formations (Triassic, carbonateous rocks (Cretaceous and lithostratigraphically equivalent to Kerman conglomerate (Cretaceous-Paleocene are exposed in this area. Based on relative age, magmatism in eastern Bajestan and Taherabad started after Late Cretaceous and it has been active and repeated during Tertiary time. At least, three episodes of volcanic activities are recognized in this area. The first stage was mainly volcanic flow with mafic composition and minor intermediate. The second episode was mainly intermediate in composition. The third stage was changed to acid-intermediate in composition. Since the plutonic rocks intruded the volcanic rocks, therefore they may be Oligo-Miocene age. Bajestan intrusive rocks are granite-granodiorite-quartz monzonite. Taherabad intrusive rocks are diorite-quartz diorite- monzonite-latite. Bajestan intrusive rocks are reduced type (ilmenite series and Taherabad intrusive rocks are oxidized type (magnetite series.Based on geochemical analysis including trace elements, REE and isotopic data, Bajestan intrusive rocks formed in continental collision zone and the magma has crustal origin. Taherabad intrusive rocks were formed in subduction zone and magma originated from oceanic crust. Taherabad intrusive rock has exploration potential for Cu-Au and pb.

Radiation-Induced Changes in Quartz, A Mineral Analog of Nuclear Power Plant Concrete Aggregates.

Science.gov (United States)

Silva, Chinthaka M; Rosseel, Thomas M; Kirkegaard, Marie C

2018-03-19

Quartz single-crystal samples consisting of α-quartz crystal structure were neutron irradiated to fluences of 5 × 10 18 , 4 × 10 19 , and 2 × 10 20 n/cm 2 (E > 0.1 MeV) at two temperatures (52 and 95 °C). The changes in the α-quartz phase as a function of these two conditions (temperature and fluence) were studied using X-ray powder diffraction (XRD), Raman spectroscopy, and transmission electron microscopy (TEM), and the results acquired using these complementary techniques are presented in a single place for the first time. XRD studies showed that the lattice parameters of α-quartz increased with increasing neutron flux. The lattice growth was larger for the samples that were neutron irradiated at 52 °C than at 95 °C. Moreover, an amorphous content was determined in the quartz samples neutron irradiated at 4 × 10 19 n/cm 2 , with the greater amount being in the 52 °C irradiated sample. Complete amorphization of quartz was observed at a fluence of 2 × 10 20 n/cm 2 (E > 0.1 MeV) using XRD and confirmed by TEM characterization and Raman spectroscopic studies. The cause for α-quartz lattice expansion and sample amorphization was also explored using XRD and Raman spectroscopic studies.

Genomic instability in quartz dust exposed rat lungs: Is inflammation responsible?

Energy Technology Data Exchange (ETDEWEB)

Albrecht, C; Schins, R P F [Institut fuer Umweltmedizinische Forschung (IUF) at the Heinrich Heine University Duesseldorf (Germany); Demircigil, G Cakmak; Coskun, Erdem [Gazi University, Faculty of Pharmacy, Department of Toxicology, Ankara (Turkey); Schooten, F J van [Nutrition and Toxicology Research Institute Maastricht (NUTRIM), Department of Health Risk Analysis and Toxicology, University of Maastricht (Netherlands); Borm, P J A [Centre of Expertise in Life Sciences (Cel), Hogeschool Zuyd, Heerlen (Netherlands); Knaapen, A M, E-mail: catrin.albrecht@uni-duesseldorf.d

2009-02-01

Exposure to quartz dusts has been associated with lung cancer and fibrosis. Although the responsible mechanisms are not completely understood, progressive inflammation with associated induction of persistent oxidative stress has been discussed as a key event for these diseases. Previously we have evaluated the kinetics of pulmonary inflammation in the rat model following a single intratracheal instillation of 2mg DQ12 quartz, either in its native form or upon its surface modification with polyvinylpyridine-N-oxide or aluminium lactate. This model has been applied now to evaluate the role of inflammation in the kinetics of induction of DNA damage and response at 3, 7, 28, and 90 days after treatment. Bronchoalveolar lavage (BAL) cell counts and differentials as well as BAL fluid myeloperoxidase activity were used as markers of inflammation. Whole lung homogenate was investigated to determine the induction of the oxidative and pre-mutagenic DNA lesion 8-hydroxy-2-deoxy-guanosine (8-OHdG) by HPLC/ECD, while mRNA and protein expression of oxidative stress and DNA damage response genes including hemeoxygenase-1 (HO-1) and apurinic/apyrimidinic endonuclease (APE/Ref-1) were evaluated using Western blotting and real time PCR. Isolated lung epithelial cells from the treated rats were used for DNA strand breakage analysis using the alkaline comet assay as well as for micronucleus scoring in May-Gruenwald-Giemsa stained cytospin preparations. In the rats that were treated with quartz, no increased 8-OHdG levels were observed, despite the presence of a marked and persistent inflammation. However, DNA strand breakage in the lung epithelial cells of the quartz treated rats was significantly enhanced at 3 days, but not at 28 days. Moreover, significantly enhanced micronucleus frequencies were observed for all four time points investigated. In the animals that were treated with the PVNO modified quartz, micronuclei scores did not differ from controls, while in those treated with

OSL, TL and IRSL emission spectra of sedimentary quartz and feldspar samples

International Nuclear Information System (INIS)

Lomax, Johanna; Mittelstraß, Dirk; Kreutzer, Sebastian; Fuchs, Markus

2015-01-01

This contribution presents a variety of different luminescence emission spectra from sedimentary feldspar and quartz samples under various stimulation modes. These are green stimulated quartz (OSL-) spectra, quartz TL spectra, feldspar IRSL and post-IR IRSL spectra. A focus was set at recording OSL and IRSL spectra at elevated stimulation temperatures such as routinely applied in luminescence dating. This was to test whether optical stimulation at elevated temperatures results in a shift of emission peaks. For OSL emissions of quartz, this has so far not been tested. In case of feldspar emissions, post-IR IRSL conditions, hence IRSL emissions at a low temperature, directly followed by high temperature post-IRSL emissions, are explicitly investigated. All spectra were recorded using a new system incorporated into a Lexsyg luminescence reader. Thus, this study, besides presenting new spectral data, also serves as a feasibility study for this new device. It is shown that (a) the new device is capable of automatically measuring different sorts of spectra, also at elevated temperatures, (b) known thermally and optically stimulated peak emissions of quartz and feldspar are confirmed, (c) obtained IRSL and OSL spectra indicate that there is no significant relation between peak emission and stimulation temperature. - Highlights: • We have measured OSL, IRSL and TL emission spectra of sedimentary quartz and feldspar samples. • Spectral analyses were performed at elevated stimulation temperatures. • Emission spectra show very little variation with stimulation temperatures.

Optically stimulated luminescence characteristics of natural and doped quartz and alkali feldspars

Energy Technology Data Exchange (ETDEWEB)

Huett, G.; Jaek, I.; Brodski, L. [Institute of Geology at Tallinn Technical University, Tallinn (Estonia); Vasilchenko, V. [Institute of Experimental Physics and Technology of Tartu University, Tartu (Estonia)

1999-05-01

Natural alkali feldspars and quartz were doped by Tl and Cu by thermodiffusion and electrodiffusion technology. As a result of doping, intensive UV emission bands were created. The OSL stimulation spectra of irradiated natural and doped quartz and alkali feldspars were measured in the span of 400-1300 nm using UV emission of Tl at 280 nm and of Cu at 380 nm. One-trap centre conception was confirmed for high-temperature palaeodosimetrical TL peaks and OSL stimulation spectrum bands: for alkali feldspars at 880 and 420 nm and visible region of the spectrum for quartz. A thermooptical mechanism of the optical depopulation of the corresponding trap is confirmed in alkali feldspars, but there is no evidence for processes of this kind in quartz. An analogy between the physical background of OSL properties of both minerals is discussed.

Optically stimulated luminescence characteristics of natural and doped quartz and alkali feldspars

International Nuclear Information System (INIS)

Huett, G.; Jaek, I.; Brodski, L.; Vasilchenko, V.

1999-01-01

Natural alkali feldspars and quartz were doped by Tl and Cu by thermodiffusion and electrodiffusion technology. As a result of doping, intensive UV emission bands were created. The OSL stimulation spectra of irradiated natural and doped quartz and alkali feldspars were measured in the span of 400-1300 nm using UV emission of Tl at 280 nm and of Cu at 380 nm. One-trap centre conception was confirmed for high-temperature palaeodosimetrical TL peaks and OSL stimulation spectrum bands: for alkali feldspars at 880 and 420 nm and visible region of the spectrum for quartz. A thermooptical mechanism of the optical depopulation of the corresponding trap is confirmed in alkali feldspars, but there is no evidence for processes of this kind in quartz. An analogy between the physical background of OSL properties of both minerals is discussed

Thermal activation of OSL as a geothermometer for quartz grain heating during fault movements

CERN Document Server

Rink, W J; Rees-Jones, J; Schwarcz, H P

1999-01-01

In discussions of ESR dating of fault movements, there has been much debate whether zeroing of ESR signals is a mechanical shearing effect or caused by frictional heating. The OSL (optically stimulated luminescence) sensitivity of quartz is known to increase after heating. This thermal activation of dose response of the OSL in quartz should be useful as a geothermometer to test whether quartz particles in fault gouge had been heated. We tested the OSL sensitivities of quartz from fault gouge, and from a control (quartz grains from sandstone) and were able to show heat-induced enhancement of OSL sensitivity to a test dose. We observed that relative enhancement of OSL dose response (ratio of heated to unheated single aliquots) is significantly less for the finest grains (45-75 and 100-150 mu m) compared with coarser grains (150-250 mu m). These data are consistent with a model of zeroing of the quartz grains during faulting, by frictional heating localized to the grain boundaries, which would be expected to aff...

The response of quartz crystals coated with thin fatty acid film to organic gases

CERN Document Server

Jin, C N; Kim, K H; Kwon, Y S

1999-01-01

We tried to apply a quartz crystal as a sensor by using the resonant frequency and the resistance properties of quartz crystals. Four kinds of fatty acids that have the same head groups were coated on the surfaces of the quartz crystals, and the shift of the resonant frequency and the resistance were observed based on the lengths of the tail groups. Myristic acid (C sub 1 sub 4), palmitic acid (C sub 1 sub 6), stearic acid (C sub 1 sub 8), and arachidic acid (C sub 2 sub 0) were deposited on the surfaces of quartz crystals by using the Langmuir-Blodgett (LB) method. As a result, the resonant frequency change was more sensitive to high molecular-weight fatty acids than to low molecular-weight ones. We also observed the effect of temperature on stearic acid LB films, and the response properties of quartz crystals coated with stearic-acid LB films to organic gases were investigated. As a result, the sensitivity of quartz crystals to organic gases was higher for higher molecular-weight gas, and we found that quar...

Investigations on low temperature thermoluminescence centres in quartz

International Nuclear Information System (INIS)

Bernhardt, H.

1984-01-01

The present paper will help to understand the often investigated process of thermoluminescence of quartz which is of high complexity. A lot of traps exist in quartz crystals which compete with each other with respect to the trapping of charge carriers during the X-ray treatment. That is why a variety of processes takes place after X-irradiation at liquid nitrogen temperature (LNT) of quartz which complicate the phenomenology of low temperature thermoluminescence. This competition in the trapping process leads to the so-called 'sensibilization' or 'desensibilization' effects of thermoluminescence, respectively, which are described in this paper for the first time. This effect means the dependence of the LNT thermoluminescence intensity on a pre-irradiation dose applied at room temperature (RT). The influence of this pre-irradiation is understood assuming the saturation of competitive traps. This favours an enhanced trapping of charge carriers at LNT-(shallow) traps instead of the preferential trapping on the deep traps in the case of X-ray treatment of the as-grown crystal at LNT. To get the afore mentioned model we take into account not only thermoluminescence but also coloration, ir- and vuv-absorption measurements. (author)

Reconstruction of thermally quenched glow curves in quartz

International Nuclear Information System (INIS)

Subedi, Bhagawan; Polymeris, George S.; Tsirliganis, Nestor C.; Pagonis, Vasilis; Kitis, George

2012-01-01

The experimentally measured thermoluminescence (TL) glow curves of quartz samples are influenced by the presence of the thermal quenching effect, which involves a variation of the luminescence efficiency as a function of temperature. The real shape of the thermally unquenched TL glow curves is completely unknown. In the present work an attempt is made to reconstruct these unquenched glow curves from the quenched experimental data, and for two different types of quartz samples. The reconstruction is based on the values of the thermal quenching parameter W (activation energy) and C (a dimensionless constant), which are known from recent experimental work on these two samples. A computerized glow-curve deconvolution (CGCD) analysis was performed twice for both the reconstructed and the experimental TL glow curves. Special attention was paid to check for consistency between the results of these two independent CGCD analyses. The investigation showed that the reconstruction attempt was successful, and it is concluded that the analysis of reconstructed TL glow curves can provide improved values of the kinetic parameters E, s for the glow peaks of quartz. This also leads to a better evaluation of the half-lives of electron trapping levels used for dosimetry and luminescence dating.

Oxygen isotope exchange with quartz during pyrolysis of silver sulfate and silver nitrate.

Science.gov (United States)

Schauer, Andrew J; Kunasek, Shelley A; Sofen, Eric D; Erbland, Joseph; Savarino, Joel; Johnson, Ben W; Amos, Helen M; Shaheen, Robina; Abaunza, Mariana; Jackson, Terri L; Thiemens, Mark H; Alexander, Becky

2012-09-30

Triple oxygen isotopes of sulfate and nitrate are useful metrics for the chemistry of their formation. Existing measurement methods, however, do not account for oxygen atom exchange with quartz during the thermal decomposition of sulfate. We present evidence for oxygen atom exchange, a simple modification to prevent exchange, and a correction for previous measurements. Silver sulfates and silver nitrates with excess (17)O were thermally decomposed in quartz and gold (for sulfate) and quartz and silver (for nitrate) sample containers to O(2) and byproducts in a modified Temperature Conversion/Elemental Analyzer (TC/EA). Helium carries O(2) through purification for isotope-ratio analysis of the three isotopes of oxygen in a Finnigan MAT253 isotope ratio mass spectrometer. The Δ(17)O results show clear oxygen atom exchange from non-zero (17)O-excess reference materials to zero (17)O-excess quartz cup sample containers. Quartz sample containers lower the Δ(17)O values of designer sulfate reference materials and USGS35 nitrate by 15% relative to gold or silver sample containers for quantities of 2-10 µmol O(2). Previous Δ(17)O measurements of sulfate that rely on pyrolysis in a quartz cup have been affected by oxygen exchange. These previous results can be corrected using a simple linear equation (Δ(17)O(gold) = Δ(17)O(quartz) * 1.14 + 0.06). Future pyrolysis of silver sulfate should be conducted in gold capsules or corrected to data obtained from gold capsules to avoid obtaining oxygen isotope exchange-affected data. Copyright © 2012 John Wiley & Sons, Ltd.

Cathodoluminescence (CL Characteristics of Quartz from Different Metamorphic Rocks within the Kaoko Belt (Namibia

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Jonathan Sittner

2018-05-01

Full Text Available Quartz of metamorphic rocks from the Kaoko belt (Namibia representing metamorphic zones from greenshist to granulite facies were investigated by cathodoluminescence (CL microscopy and spectroscopy to characterize their CL properties. The samples cover P-T conditions from the garnet zone (500 ± 30 °C, 9 ± 1 kbar up to the garnet-cordierite-sillimanite-K-feldspar zone (750 ± 30 °C, 4.0–5.5 kbar. Quartz from 10 different localities and metamorphic environments exclusively exhibits blue CL. The observed CL colors and spectra seem to be more or less independent of the metamorphic grade of the host rocks, but are determined by the regional geological conditions. Quartz from different localities of the garnet-cordierite-sillimanite-K-feldspar zone shows a dominant 450 nm emission band similar to quartz from igneous rocks, which might be related to recrystallization processes. In contrast, quartz from different metamorphic zones in the western part of the central Kaoko zone (garnet, staurolite, kyanite, and kyanite-sillimanite-muscovite zone is characterized by a heterogeneous blue-green CL and a dominant 500 nm emission band that strongly decreases in intensity under electron irradiation. Such CL characteristics are typical for quartz of pegmatitic and/or hydrothermal origin and indicate the participation of fluids during neoformation of quartz during metamorphism.

Establishment of gold-quartz standard GQS-1

Science.gov (United States)

Millard, Hugh T.; Marinenko, John; McLane, John E.

1969-01-01

A homogeneous gold-quartz standard, GQS-1, was prepared from a heterogeneous gold-bearing quartz by chemical treatment. The concentration of gold in GQS-1 was determined by both instrumental neutron activation analysis and radioisotope dilution analysis to be 2.61?0.10 parts per million. Analysis of 10 samples of the standard by both instrumental neutron activation analysis and radioisotope dilution analysis failed to reveal heterogeneity within the standard. The precision of the analytical methods, expressed as standard error, was approximately 0.1 part per million. The analytical data were also used to estimate the average size of gold particles. The chemical treatment apparently reduced the average diameter of the gold particles by at least an order of magnitude and increased the concentration of gold grains by a factor of at least 4,000.

The interpretation of quartz optically stimulated luminescence equivalent dose versus time plots

International Nuclear Information System (INIS)

Bailey, R.M.

2000-01-01

Numerical modelling has shown that the form of the quartz OSL shine plateau (hereafter 'D e (t)-plot') is influenced by the effects of phototransferred TL in the ∼110 deg. C region. It is suggested also that the presence of multiple OSL components (as described by Partial bleaching and the decay form characteristics of quartz OSL. Radiat. Meas., 27, 123-136. The form of the optically stimulated luminescence signal of quartz: implications of dating. Unpublished PhD thesis, University of London) affects the form of the D e (t)-plot. Laboratory measurements of a fully reset and artificially dosed sample yielded non-flat D e (t)-plots, the deviation being greater for the larger of the two simulated palaeodoses, in accordance with theoretical predictions. It is suggested that the so-called 'shine plateau' test is of limited use in assessing the bleaching history of quartz sediments

Carbothermal Reduction of Quartz and Carbon Pellets at Elevated Temperatures

Science.gov (United States)

Li, Fei; Tangstad, Merete; Ringdalen, Eli

2018-02-01

In this study, the carbothermal reduction of pellets composed of quartz and carbon at temperatures between 1898 K and 1948 K (1625 °C and 1675 °C) are investigated. The main product from this reaction is silicon carbide (SiC). The reduction of quartz with carbon black, charcoal, coke, coal, and pre-heated coal in the pellet were compared to investigate the different carbon resources used in silicon production. Charcoal and coke have high SiO reactivity, while carbon black and coal (pre-heated coal) have low SiO reactivity. Charcoal and carbon black show better matching between quartz/carbon reactivity and SiO reactivity, and will lose less SiO gas than coke and pre-heated coal. Coal has a high volatile content and is thus not recommended as a raw material for the pellets.

Carbothermal Reduction of Quartz and Carbon Pellets at Elevated Temperatures

Science.gov (United States)

Li, Fei; Tangstad, Merete; Ringdalen, Eli

2018-06-01

In this study, the carbothermal reduction of pellets composed of quartz and carbon at temperatures between 1898 K and 1948 K (1625 °C and 1675 °C) are investigated. The main product from this reaction is silicon carbide (SiC). The reduction of quartz with carbon black, charcoal, coke, coal, and pre-heated coal in the pellet were compared to investigate the different carbon resources used in silicon production. Charcoal and coke have high SiO reactivity, while carbon black and coal (pre-heated coal) have low SiO reactivity. Charcoal and carbon black show better matching between quartz/carbon reactivity and SiO reactivity, and will lose less SiO gas than coke and pre-heated coal. Coal has a high volatile content and is thus not recommended as a raw material for the pellets.

Natural alpha recoil particle radiation and ionizing radiation sensitivities in quartz detected with EPR: implications for geochronometry

International Nuclear Information System (INIS)

Rink, W.J.; Odom, A.L.

1991-01-01

The electron paramagnetic resonance EPR signals in granitic quartz samples of known age are studied. Time-integrated alpha recoil activity and EPR signal intensity are more significantly correlated than sample age and EPR signal intensity. Neutron activation analysis for internal uranium and thorium in quartz are reported. Natural germanium EPR signals are observed in pegmatitic quartz samples and one granitic quartz. Pegmatitic quartz exhibits germanium EPR center growth competing strongly with E' center growth, apparently leading to depleted natural concentrations of E' centers. Calculations of lattice vacancy accumulation associated with alpha recoil damage are presented and compared with concentrations of paramagnetic oxygen vacancies in the quartz. Based on the results reported, the potential and problems associated with dating quartz are discussed, relating both to accumulated lattice damage and the additive dose methods. (author)

Emission properties of thermoluminescence from natural quartz - blue and red TL response to absorbed dose

International Nuclear Information System (INIS)

Hashimoto, T.; Yokosaka, K.; Habuki, H.

1987-01-01

The TL spectrometry of natural quartz exposed to a gamma radiation dose of 8.8 kGy proved that the red TL, mainly from volcanically originated quartz, has a broad emission band with a peak around 620 nm, while the blue TL from plutonically originated quartz also has a broad emission band giving a peak around 470 nm. These typical red or blue intrinsic colours were also confirmed on the thermoluminescence colour images (TLCI). Exceptionally, a pegmatite quartz changed its TLCI colour from red to blue when the absorbed dose was increased. By using colour filter assemblies, all these quartz samples were shown to emit mainly blue and red TLs, which have distinctly different TL responses to the absorbed dose; the blue invariably showed a supralinearity relation between 1 and 10 kGy dose. For the purpose of dating, the use of red TL, is preferable. The red TL component is related to the impurity Eu content in quartz minerals. (author)

Changes in the artificial thermoluminescence glow curves of quartz associated with uranium deposits

Energy Technology Data Exchange (ETDEWEB)

Hochman, M.B.M.; Ypma, P.J.M.

1988-01-01

Previous laboratory-based studies have shown that quartz thermoluminescence (TL) glow curves change in intensity and shape in response to large radiation doses. Initially, low temperature peaks are sensitized though at gamma doses of greater than 10/sup 5/ - 10/sup 6/ kGy desensitization occurs. This study has examined the change in artificial TL in quartz at various distances from a uranium deposit. Such quartz has been subjected to varying palaeoradiation doses in a natural uranium rich environment. Quartz from an uranium rich environment shows that the 130/sup 0/C glow peak is the dominant glow peak in background radiation environments, though this peak decreases with increasing palaeoradiation dose. At doses greater than 10/sup 5/-10/sup 6/ kGy the 350/sup 0/C glow peak is the dominant glow peak in these quartz samples. An increase in E'/sub 1/ centre concentration also occurs from the least radiation affected sample to the most radiation affected sample. These results suggest that artificial TL is useful in uranium exploration.

Thermal activation of OSL as a geothermometer for quartz grain heating during fault movements

International Nuclear Information System (INIS)

Rink, W.J.; Toyoda, S.; Rees-Jones, J.; Schwarcz, H.P.

1999-01-01

In discussions of ESR dating of fault movements, there has been much debate whether zeroing of ESR signals is a mechanical shearing effect or caused by frictional heating. The OSL (optically stimulated luminescence) sensitivity of quartz is known to increase after heating. This thermal activation of dose response of the OSL in quartz should be useful as a geothermometer to test whether quartz particles in fault gouge had been heated. We tested the OSL sensitivities of quartz from fault gouge, and from a control (quartz grains from sandstone) and were able to show heat-induced enhancement of OSL sensitivity to a test dose. We observed that relative enhancement of OSL dose response (ratio of heated to unheated single aliquots) is significantly less for the finest grains (45-75 and 100-150 μm) compared with coarser grains (150-250 μm). These data are consistent with a model of zeroing of the quartz grains during faulting, by frictional heating localized to the grain boundaries, which would be expected to affect smaller grains more than large ones. This argues against a zeroing model in which the entire fault gouge is heated by friction. Higher laboratory preheating of sandstone quartz reduces between-aliquot variability of OSL dose response in the unheated grains to nearly zero. Unheated coarsest fault gouge grains displayed virtually no among-aliquot variability, whereas fine grains showed much larger between-aliquot variability; as with the quartz sand, variability dropped to near zero after laboratory heating, suggesting that fine grains in fault gouge have experienced a wide range of natural thermal histories during faulting. This may present a problem for ESR dating of fault gouge using the plateau method

Creep of quartz by dislocation and grain boundary processes

Science.gov (United States)

Fukuda, J. I.; Holyoke, C. W., III; Kronenberg, A. K.

2015-12-01

Wet polycrystalline quartz aggregates deformed at temperatures T of 600°-900°C and strain rates of 10-4-10-6 s-1 at a confining pressure Pc of 1.5 GPa exhibit plasticity at low T, governed by dislocation glide and limited recovery, and grain size-sensitive creep at high T, governed by diffusion and sliding at grain boundaries. Quartz aggregates were HIP-synthesized, subjecting natural milky quartz powder to T=900°C and Pc=1.5 GPa, and grain sizes (2 to 25 mm) were varied by annealing at these conditions for up to 10 days. Infrared absorption spectra exhibit a broad OH band at 3400 cm-1 due to molecular water inclusions with a calculated OH content (~4000 ppm, H/106Si) that is unchanged by deformation. Rate-stepping experiments reveal different stress-strain rate functions at different temperatures and grain sizes, which correspond to differing stress-temperature sensitivities. At 600-700°C and grain sizes of 5-10 mm, flow law parameters compare favorably with those for basal plasticity and dislocation creep of wet quartzites (effective stress exponents n of 3 to 6 and activation enthalpy H* ~150 kJ/mol). Deformed samples show undulatory extinction, limited recrystallization, and c-axis maxima parallel to the shortening direction. Similarly fine-grained samples deformed at 800°-900°C exhibit flow parameters n=1.3-2.0 and H*=135-200 kJ/mol corresponding to grain size-sensitive Newtonian creep. Deformed samples show some undulatory extinction and grain sizes change by recrystallization; however, grain boundary deformation processes are indicated by the low value of n. Our experimental results for grain size-sensitive creep can be compared with models of grain boundary diffusion and grain boundary sliding using measured rates of silicon grain boundary diffusion. While many quartz mylonites show microstructural and textural evidence for dislocation creep, results for grain size-sensitive creep may apply to very fine-grained (<10 mm) quartz mylonites.

Studies of the spectral and spatial characteristics of shock-induced luminescence from x-cut quartz

International Nuclear Information System (INIS)

Brannon, P.J.; Konrad, C.; Morris, R.W.; Jones, E.D.; Asay, J.R.

1983-01-01

Spatial and spectral studies of shock-induced luminescence from x-cut crystalline quartz as a function of stress level revealed the following information: Crystalline x-cut quartz has a threshold for emission near the dynamic yield point (about 6 GPa); the spatial distribution of the luminescence from x-cut quartz changes from an intersecting linear emission pattern to a uniform emission pattern as the stress level increases from 6 to 8 GPa; spectra from x-cut quartz are band-like rather than blackbody; crystalline x-cut quartz has emission peaks near 400 and 600 nm; a change in the 400-nm emission with time can be correlated to wave interaction times. A discussion of the luminous emission in terms of yielding and other physical mechanisms is given

Measurement of the dose in quartz in the presence of feldspar contamination

DEFF Research Database (Denmark)

Wallinga, J.; Murray, A.S.; Bøtter-Jensen, L.

2002-01-01

To allow the determination of the dose in quartz in the presence of feldspar contamination. the quartz-to-feldspar optically stimulated luminescence (OSL) ratio needs to be maximised. Experiments were carried Out to find the optimum procedure to bleach the feldspar by exposure to infrared light...

Study of the α and β phases of quartz by neutron multiple diffraction

International Nuclear Information System (INIS)

Mazzocchi, V.L.

1984-01-01

Crystal structures of α and β phases of quartz are studied, employing neutron multiple diffraction as a method of analysis. Theoretical multiple diffraction patterns in a many-beam case were determined by a computer program which calculates intensities of beams as sums of Taylor's series expansions, retaining terms up to a order n. Experimental 'umweg' and transmitted beam patterns were obtained for the 00.1 primary reflection of α and β phases of quartz. To calculate α - quartz multiple diffraction intensities it was necessary to determine the Dauphine twinning fraction for the crystal after having passed by the β-phase. For the two models of β-quartz a better agreement between experimental and calculated integrated intensities was found for the disordered structure model based on split-half-oxigen positions. (Author) [pt

Imperfections study of the smoky quartz from Bahia by X-ray diffraction

International Nuclear Information System (INIS)

D'Aguiar Neto, M.M.F.

1974-01-01

X-ray diffraction techniques were used to study the type of point defects in Smoky quartz from Itambe and Vitoria da Conquista in Bahia. The power method, using the Seemann Bohlin camara (back refletion), was utilized in the analysis of the policrystals, while the monocrystals were studied by means of the precession camara. The positions occupied by the defects in the crystal net were calculated. The results show that while the defects of substitutional impurities predominate in the quartz from Itambe, in the quartz from Vitoria da Conquista the substitutional defects exist in comparable proportions that the interstital ones. Isochronous annealing curves, for both type of smoky quartz indicate an increase in the net parameter to temperature values above the annealing temperatures. Was formulated the hypothesis that providing a thermal energy greater than that of annealing is used, new interstitial defects would be created as a result of a thermic diffusion mechanism. (C.D.G.) [pt

Experiment study of a quartz tube falling particle receiver

Institute of Scientific and Technical Information of China (English)

Tianjian WANG; Fengwu BAI; Shunzhou CHU; Xiliang ZHANG; Zhifeng WANG

2017-01-01

This paper presents an experimental evaluation of a specially designed falling particle receiver.A quartz tube was used in the design,with which the particles would not be blown away by wind.Concentrated solar radiation was absorbed and converted into thermal energy by the solid particles flowed inside the quartz tube.Several experiments were conducted to test the dynamic thermal performance of the receiver on solar furnace system.During the experiments,the maximum particle temperature rise is 212℃,with an efficiency of 61.2％,which shows a good thermal performance with a falling distance of 0.2 m in a small scale particle receiver.The average outlet particle temperature is affected by direct normal irradiance (DNI) and other factors such as wind speed.The solid particles obtain a larger viscosity with a higher temperature while smaller solid particles are easier to get stuck in the helix quartz tube.The heat capacity of the silicon carbide gets larger with the rise of particle temperature,because as the temperature of solid particles increases,the temperature rise of the silicon carbide decreases.

Petrogenesis of low-δ18O quartz porphyry dykes, Koegel Fontein complex, South Africa

Science.gov (United States)

Harris, Chris; Mulder, Kwenidyn; Sarkar, Saheli; Whitehead, Benjamin; Roopnarain, Sherissa

2018-04-01

This paper investigates the origin of low-δ18O quartz porphyry dykes associated with the 144-133 Ma Koegel Fontein Igneous Complex, which was intruded during the initial phase of breakup of Africa and South America. The 25-km diameter Rietpoort Granite is the largest and youngest phase of activity, and is roofed by a 10-km diameter pendant of gneiss. Quartz porphyry (QP) dykes, up to 15 m in width, strike NW-SE across the complex. The QP dykes that intruded outside the granite have similar quartz phenocryst δ18O values (average 8.0‰, ± 0.7, n = 33) to the granite (average 8.3 ± 1.0, n = 7). The QP dykes that intruded the roof pendant have quartz phenocrysts with more variable δ18O values (average 1.6‰, ± 2.1, n = 55). In some cases quartz phenocrysts have δ18O values as low as - 2.5‰. The variation in δ18O value within the quartz crystal population of individual dykes is small relative to the overall range, and core and rim material from individual quartz phenocrysts in three samples are identical within error. There is no evidence that quartz phenocryst δ18O values have been affected by fluid-rock interaction. Based on a Δquartz-magma value of 0.6‰, magma δ18O values must have been as low as - 3.1‰. Samples collected along the length of the two main QP dykes that traverse the roof pendant have quartz phenocryst δ18O values that range from + 1.1 to + 4.6‰, and - 2.3 to + 5.6‰, respectively. These δ18O values correlate negatively ( r = - 0.96) with initial 87Sr/86Sr, which can be explained by the event that lowered δ18O values of the source being older than the dykes. We suggest that the QP dykes were fed by magma produced by partial melting of gneiss, which had been variably altered at high temperature by 18O-depleted meteoric water during global glaciation at 550 Ma. The early melts had variable δ18O value but as melt pockets interconnected during melting, the δ18O values approached that of average gneiss. Variable quartz phenocryst �

Thermal annealing studies in muscovite and in quartz

International Nuclear Information System (INIS)

Roberts, J.H.; Gold, R.; Ruddy, F.H.

1979-06-01

In order to use Solid State Track Recorders (SSTR) in environments at elevated temperatures, it is necessary to know the thermal annealing characteristics of various types of SSTR. For applications in the nuclear energy program, the principal interest is focused upon the annealing of fission tracks in muscovite mica and in quartz. Data showing correlations between changes in track diameters and track densities as a function of annealing time and temperature will be presented for Amersil quartz glass. Similar data showing changes in track lengths and in track densities will be presented for mica. Time-temperature regions will be defined where muscovite mica can be accurately applied with negligible correction for thermal annealing

The effects of pre-dose and annealing temperature on some dosimetric properties of thermoluminescence of quartz

International Nuclear Information System (INIS)

Lin Zhikai

1996-02-01

The following aspects of dosimetric properties of quartz sample were studied. (1) The changes in dosimetric sensitivity of quartz with different pre-doses under different annealing temperature; (2) the option of optimal annealing temperature which can make the dosimetric sensitivity of quartz to restore its original level; (3) The changes in dosimetric sensitivity of quartz with different annealing time at 500 degree C for 8 h; (4) Repeated experiments were carried out in order to prove whether the sensitivity of quartz can restore its original level at annealing temperature 700 degree C for 3 h. It has been found that at 700 degree C for 3 h gave the least sensitivity change and the sensitivity of quartz almost restored its original level. Repeated experiments with four kinds of quartz sample confirmed this conclusion. The dramatic change of TL glow curve occurred only at the condition of annealing temperature 900 degree C for 1 h. This result was different from that obtained by D. J. Huntley et al. (1988). (3 refs., 4 figs., 1 tab.)

Microbially induced separation of quartz from calcite using Saccharomyces cerevisiae.

Science.gov (United States)

Padukone, S Usha; Natarajan, K A

2011-11-01

Cells of Saccharomyces cerevisiae and their metabolites were successfully utilized to achieve selective separation of quartz and calcite through microbially induced flotation and flocculation. S. cerevisiae was adapted to calcite and quartz minerals. Adsorption studies and electrokinetic investigations were carried out to understand the changes in the surface chemistry of yeast cells and the minerals after mutual interaction. Possible mechanisms in microbially induced flotation and flocculation are outlined. Copyright © 2011 Elsevier B.V. All rights reserved.

Emission polarization study on quartz and calcite.

Science.gov (United States)

Vincent, R. K.

1972-01-01

Calculation of the spectral emission polarization of quartz and calcite polished plates for observation angles of 20 and 70 deg by the substitution of complex index of refraction values for each mineral into Fresnel's equations. The emission polarization is shown to be quite wavelength-dependent, demonstrating that selected narrow or medium-width spectral bands exhibit a significantly higher percentage of polarization than a broad spectral band for these two minerals. Field measurements with a broadband infrared radiometer yield polarizations on the order of 2% for a coarse-grained granite rock and beach sand (both quartz-rich). This implies that a more sensitive detector with a selected medium-width filter may be capable of measuring emission polarization accurately enough to make this parameter useful as a remote sensing tool for discrimination among rocks on the basis of texture.

The red thermoluminescence of quartz: 3-D spectral measurements

International Nuclear Information System (INIS)

Scholefield, R.B.; Prescott, J.R.

1999-01-01

As part of a general study of the thermoluminescence (TL) of quartz, we have examined the 3-D spectra of samples of quartz extracted from a variety of sediments. Blue emission at about 2.6 eV/475 nm, which is the photon energy region commonly used in luminescence dating, seems ubiquitous. Significant emission in the red, ∼1.9 eV/650 nm, has been found at most glow temperatures in all of our samples of Australian quartz sediments, and it is to this that particular attention is paid in the present work. A limited selection of samples from other countries has also been included. The ratio of the intensities of the red and blue emissions varies widely among samples. We have not found any evidence of a correlation between this ratio, nor the intensity of the red emission, with trace element concentration, including that of Al for which a correlation has been previously observed. In the context of luminescence dating, all samples have been examined to see whether they have a rapidly bleaching red component in a similar sense to the well-known 305 deg. C/2.95 eV/420 nm peak in quartz: some samples have such a component--some do not. A suggestive parallelism is found between the blue and red spectra, in that there are 'slowly bleaching' and 'rapidly bleaching' components at similar temperatures in the both red and the blue. However, there is no red component associated with the 110 deg. C peak used in pre-dose dating

Assessing rare earth elements in quartz rich geological samples

International Nuclear Information System (INIS)

Santoro, A.; Thoss, V.; Ribeiro Guevara, S.; Urgast, D.; Raab, A.; Mastrolitti, S.; Feldmann, J.

2016-01-01

Sodium peroxide (Na_2O_2) fusion coupled to Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS) measurements was used to rapidly screen quartz-rich geological samples for rare earth element (REE) content. The method accuracy was checked with a geological reference material and Instrumental Neutron Activation Analysis (INAA) measurements. The used mass-mode combinations presented accurate results (only exception being "1"5"7Gd in He gas mode) with recovery of the geological reference material QLO-1 between 80% and 98% (lower values for Lu, Nd and Sm) and in general comparable to INAA measurements. Low limits of detection for all elements were achieved, generally below 10 pg g"−"1, as well as measurement repeatability below 15%. Overall, the Na_2O_2/ICP-MS/MS method proved to be a suitable lab-based method to quickly and accurately screen rock samples originating from quartz-rich geological areas for rare earth element content; particularly useful if checking commercial viability. - Highlights: • Na_2O_2 fusion coupled to ICP-MS/MS was used to determine REE in quartz-rich samples. • The method accuracy was checked with a geological reference material and INAA. • Results were within 80–98% recovery of QLO-1 reference material, comparable to INAA. • Detection limits were generally below 10 pg g"−"1, and repeatability was below 15%. • Na_2O_2/ICP-MS/MS proved to be a suitable method for REE in quartz-rich samples.

Effect of pre-dose irradiation in the quartz and its use for archaelogical dating

International Nuclear Information System (INIS)

Yukimitu, K.

1985-01-01

The technique of pre-dose for dating ceramics, using the thermoluminescent properties of quartz is presented. The behavior of thermoluminescent (TL) sensitivity of the 110 0 C peak of Brazilian quartz, in its geologic state, submitted to thermal treatments from 600 to 900 0 C, is studied. The samples were tritured for separating the quartz crystals from clay. The quartz grains were submitted to leaching with chloric acid solution followed by leaching with running water. The samples were irradiated in laboratory, with gamma radiation using Co-60 and Cs-137 sources, for calibration. A sensitivity enhancement rate of 2% per rad was observed for samples annealed at 900 0 C, was observed. (M.C.K.) [pt

Data Acquisition System for Quartz Crystal Microbalances

Directory of Open Access Journals (Sweden)

Kleber Romero Felizardo

2006-02-01

Full Text Available This work presents a data acquisition system used in a mass sensor: quartz crystal microbalance. This system reads the frequency of this sensor along the time and sends the collected data to the computer through a serial interface.

Slaw extracted proton beam formation and monitoring for the ''QUARTZ'' setup

International Nuclear Information System (INIS)

Bushnin, Yu.B.; Gres', V.N.; Davydenko, Yu.P.

1982-01-01

The version of optical mode of the beam channel providing with simultaneous operating the experimental setups FODS and ''QUARTZ'' at consecutive usage of the slow extracted proton beam is reported. The ''QUARTZ'' setup beam diagnostics system comprises two subsystems: for measuring beam profile beam timing structure and beam intensity and operates in the beam extraction duration from 20 ns to few seconds at beam intensity from 10 10 to 5x10 12 protons/pulse. The ''QUARTZ'' setup represents a focusing crystal-diffraction spectrometer with 5-meter focal distance and Ge(Li) special construction detector. High efficiency target is applied in the setup. The ''QUARTZ'' setup is designed for studying exotic atoms produced by negative charged heavy particles (π, K, μ, P tilde) and atomic nuclei. Precise energy measurement of X ray transitions in such atoms is performed. For measuring beam geometric parameters 32-channel secondary emission chambers are used. As detector of beam intensity and timing structure of slow extracted beam the secondary emission chamber is employed. The principle circuit of current integrator is given. As data transmission line a 50-pair telephone cable is used. Information conversion into digital form and its subsequent processing is performed in the CAMAC system and the SM-3 computer. The proton beam full intensity measuring system provides with accuracy not worse than +-4.5% in the 10 10 -10 12 proton/sec range. The implemented optical mode of the beam channel and proton beam monitoring system permitted to begin fulfillment of the experimental program on the ''QUARTZ'' setup

Mineralogy of Copper-Gold Deposit, Masjid Daghi Area, Jolfa, IRAN

Science.gov (United States)

Zenoozi, Roya

2010-05-01

The Copper-Gold deposit of Masjid Daghi area is located in the Jolfa quadrangle (scale 1:100,000), East Azerbaijan Province, north-west Iran. The deposit, hosting by sub-volcanic bodies comprise of quartz monzonite composition whose intruded the Tertiary volcanic and volcanic-sedimentary rocks and turbidities. The Tertiary volcanic rocks consist of andesite, trachy andesite and quartz andesite. These mineral-bearing bodies related to Late Eocene sub-volcanic activities which intrudded the Eocene volcanic rocks. Mineralography, XRD and SEM studies showed that the variations in mineralization of the area. The main agent of mineralization is the intrusion of Late Eocene sub volcanic bodies inside the Tertiary volcanic units. The mineralography studies revealed two main groups of mineralization as oxides and sulfides. The sulfide minerals formed as veins, vein lets and stock work.The economic minerals comprise of native gold, copper sulfides. The native gold occurring in siliceous veins and almost as inclusions inside the sulfides minerals such as chalcopyrite. The copper sulfides, contain pyrite, chalcopyrite and chalco-pyrrhoyite. Pyrite is main sulfide in the area and formed as disseminations, cavity filling and colloform. The amount of pyrite, chalcopyrite and chalco-pyrrhoyite increases with depth. Supergene alteration produced digenite, covellite, bornite, and malachite. The alteration occurred as potassic, phyllic, argillic and propylitic minerals. Furthermore, selective sercitic, sericitic-chloritic and alunitic alterations are seen around the mineralized veins. The mineralography studies indicate that pyrite is main mineral phase and native gold occurred in silicious vein almost as inclusions inside the sulfide mineral. Most of economic mineral formed as veins, vein lets, disseminated, cavity filling and colloform which related to intrusions of Late Eocene quartz monzonite bodies into the Eocene volcanic rocks and turbiditse. Some types of alterations such as

Ferrobielastic twinning in irradiated quartz

International Nuclear Information System (INIS)

Shiau, S.M.

1986-01-01

Cultured quartz is usually free from electrical twinning; however, it may occur if the seed crystal is twinned or if undue applied forces are exerted on the crystal. Ferrobielastic twinning was studied optically (photoelastic effect) and electrically (piezoelectric effect). At room temperature, twins were perceptible at stresses of about 2.l5 x 10 8 N/m 2 , and crystals switched from their original states to the alternative twin states at stresses about 5.0 x 10 8 N/m 2 (called coercive stress). The decrease in coercive stress with increasing temperature was observed, and these coercive stresses become very low as temperatures reach to 300 0 C. The effects of irradiation on the twinning in quartz were also studied. The presence of defects produced by irradiation was utilized to pin the domain wall motion. Both neutrons and gamma rays were employed. The stress required to nucleate an appreciable volume of twins is about twice as high for irradiated crystals than for those unirradiated. This result demonstrated that the irradiated crystals can tolerate higher stresses. However, the coercive stress for complete switch-over was not much different for irradiated and unirradiated crystals. It appears that the defects caused by irradiation eliminate the initial twinning events but do not affect switch-over

Significance of Dauphiné twins in crystallographic fabrics of quartz tectonites

Science.gov (United States)

Eske Sørensen, Bjørn

2014-05-01

Dauphine twins are commonly found in quartz tectonites, however their role in deformation processes are not completely understood. This study represents a new attempt to understand the interaction between slip systems and Dauphine twins in deforming quartz-rich rocks at different temperatures. There is no doubt that Dauphine twins are mobilized under stress as this has been shown by experiments for single crystals and in polycrystalline aggregates where distinct crystallographic fabrics develop in previously randomly oriented aggregates related to minimization of elastic energy (Tullis 1972). However in quartz tectonites the Dauphine twin process is a part of interplay between plastic deformation and recovery processes which depends on PT, strain-rate and fluid composition and availability. In quartz tectonites with Y-girdle C-axis (GBM-regime) fabrics Dauphiné twins are abundant, relating different parts of r- and z rhomb "comet" distributions. This is interpreted as completion between prism slip and Dauphiné twinning. Slip rotates grains such that CRSS is low on the prism planes, but then Dauphiné twin boundaries sweeps through the grain back to the orientation giving lower stored elastic energy. The faster recovery at higher temperatures gives subgrain walls slowing down twin movement across the mm-sized grain of the GBM regime. At lower temperatures in the SGR-regime grain-size is reduced and different rotations of the grains are happening due to the domination of rhomb and basal slip. Because recrystallization is effective relative to grain-size the grains are commonly free of internal strain and subgrain walls, allowing the favorably oriented Dauphiné twin member to sweep across the whole grain overwhelming the unfavorably oriented Dauphiné twin member. As a consequence high strain reduces the number of Dauphiné twins and quartz rhomb fabrics appear trigonal, missing the "comet" shape of the GBM regime rhomb fabrics. Since Dauphiné twinning is also

Mathematical modeling of quartz particle melting process in plasma-chemical reactor

Energy Technology Data Exchange (ETDEWEB)

Volokitin, Oleg, E-mail: volokitin-oleg@mail.ru; Volokitin, Gennady, E-mail: vgg-tomsk@mail.ru; Skripnikova, Nelli, E-mail: nks2003@mai.ru; Shekhovtsov, Valentin, E-mail: shehovcov2010@yandex.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Vlasov, Viktor, E-mail: rector@tsuab.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); National Research Tomsk Polytechnic University, 30, Lenin Ave., 634050, Tomsk (Russian Federation)

2016-01-15

Among silica-based materials vitreous silica has a special place. The paper presents the melting process of a quartz particle under conditions of low-temperature plasma. A mathematical model is designed for stages of melting in the experimental plasma-chemical reactor. As calculation data show, quartz particles having the radius of 0.21≤ r{sub p} ≤0.64 mm completely melt at W = 0.65 l/s particle feed rate depending on the Nusselt number, while 0.14≤ r{sub p} ≤0.44 mm particles melt at W = 1.4 l/s. Calculation data showed that 2 mm and 0.4 mm quartz particles completely melted during and 0.1 s respectively. Thus, phase transformations occurred in silicon dioxide play the important part in its heating up to the melting temperature.

Measurements of the Shock Release Of Quartz and Paralyene-N

Science.gov (United States)

Hawreliak, James; Karasik, Max; Oh, Jaechul; Aglitskiy, Yefim

2017-06-01

The shock and release properties of Quartz and hydrocarbons are important to high energy density (HED) research and inertial confinement fusion (ICF) science. The bulk of HED material research studies single shock or multiple shock conditions. The challenge with measuring release properties is unlike shocks which have a single interface from which to measure the properties, the release establishes gradients in the sample. The streaked x-ray imaging capability of the NIKE laser allow the interface between quartz and CH to be measured during the release, giving measurements of the interface velocity and CH density. Here, we present experimental results from the NIKE laser where quartz and parylene-N are shock compressed to high pressure and temperature and the release state is measured through x-ray imaging. The shock state is characterized by shock front velocity measurements using VISAR and the release state is characterized by using side-on streaked x-ray radiography Work supported by DOE/NNSA.

Usability of VTL from natural quartz grains for retrospective dosimetry

International Nuclear Information System (INIS)

Fujita, H.; Hashimoto, T.

2007-01-01

To develop retrospective dosimetry of unexpected radiation accident, basic studies on violet thermoluminescence (VTL) phenomena were conducted using natural quartz grains. All VTL glow curves of as-received samples did not exhibit peaks <250 deg. C, although for artificially irradiated quartz samples there were VTL peaks in the temperature region <250 deg. C. Therefore, accident doses could be estimated without the interference of naturally accumulated doses by VTL measurements from natural quartz. The mean lives of VTL were evaluated by the various heating rates method and the range of values was found to be between some days and ten thousands of years depending on each peak. Especially, the mean life of VTL peak at 200 deg. C was years order. Furthermore, the lower detection limit was calculated to be tens of mGy from the response curve. This value was lower than that of other methods such as ESR dosimetry. From these results, we conclude that VTL dosimetry can be preferred for accidental evaluation. (authors)

Luminescence quartz dating of lime mortars. A first research approach

International Nuclear Information System (INIS)

Zacharias, N.; Mauz, B.; Michael, C.T.

2002-01-01

Lime mortars mixed with sand are well suited for connecting structural materials, like stones and bricks, due to the mechanical properties this material exhibits. Their extensive use in architectural and decorative works during the last 4000 years motivated the introduction of the 'Luminescence clock' for age determination of mortars. The same principles as for quartz optically stimulated luminescence (OSL) dating of sediments were applied for age estimation of a mortar fragment removed from a Byzantine church monument dated by archaeological means to 1050-1100 years ago (the first half of the 10th century). The OSL from the quartz was monitored under blue light stimulation and UV detection, using a single-aliquot-regenerative-dose protocol. The quartz-OSL dating of the mortar resulted in 870±230 a. TL polymineral fine grain dating was also performed on a brick fragment which was connected to the mortar, resulting in a TL age of 1095±190 a. (author)

Experimental and modelling study of pulsed optically stimulated luminescence in quartz, marble and beta irradiated salt

International Nuclear Information System (INIS)

Pagonis, V; Mian, S M; Barnold, C; Chithambo, M L; Christensen, E

2009-01-01

Optical stimulation luminescence (OSL) signals can be obtained using continuous-wave optical stimulation (CW-OSL), the linear modulation optical stimulation method (LM-OSL) and the time-resolved optical stimulation (TR-OSL) method. During TR-OSL measurements, the stimulation and emission of luminescence are experimentally separated in time by using short light pulses. This paper presents new TR-OSL data for annealed high purity synthetic quartz, for marble and for commercially available iodized salt. A new type of behaviour for TR-OSL signals for quartz and iodized salt is presented, in which the OSL signal exhibits a nonmonotonic behaviour during optical stimulation; this type of behaviour has not been reported previously in the literature for quartz. Furthermore, a luminescence component with very long luminescence lifetime is reported for some quartz aliquots, which may be due to the presence of a delayed-OSL (DOSL) mechanism in quartz. A new kinetic model for TR-OSL in quartz is presented, which is based on a main electron trap and on several luminescence centres. The model is used to quantitatively fit several sets of experimental data of pulsed optically stimulated luminescence from quartz.

Spectrographic analysis of metallic silicium and natural quartz

International Nuclear Information System (INIS)

Grigoletto, T.; Lordello, A.R.

1985-01-01

A method has been developed for the spectrographic determination of B, Mg, Al, Ca, Ti, Mn, Fe, Ni, Cu and Ag in silicon metal and other for Al, Ca, Mg, Ti, Cr, Mn, and Fe in natural quartz. A mixture of the matrix with a proper buffer is excited directly in a dc-arc. High-current (25A) and argon atmosphere are used for both the methods. Silicon metal is blended with 8% NaF and after 1:1 (w/w) with graphite. For natural quartz 20% NaF and 30% graphite by weight is the buffer mixture employed. The lower values in the determinations varies from 0.5 to 40 μg/g and the precision of the analysis from 7% to 45%. (Author) [pt

Quartz luminescence response to a mixed alpha-beta field: Investigations on Romanian loess

International Nuclear Information System (INIS)

Constantin, Daniela; Jain, Mayank; Murray, Andrew S.; Buylaert, Jan-Pieter; Timar-Gabor, Alida

2015-01-01

Previous SAR-OSL dating studies using quartz extracted from Romanian and Serbian loess samples report SAR-OSL dose–response curves on fine grained (4–11 μm) quartz that grow to much higher doses compared to those of coarse-grained (63–90, 90–125, 125–180 μm) quartz. Furthermore, quartz SAR-OSL laboratory dose response curves do not reflect the growth of the OSL signal in nature. A main difference in coarse- and fine-grained quartz dating lies in the alpha irradiation history, but the effect of mixed alpha-beta fields has so far received little attention. In the present study we investigate whether the alpha dose experienced by fine grains over geological cycles of irradiation and bleaching may have an effect on the saturation characteristics of the laboratory dose response. By applying time resolved optically stimulated luminescence we confirm that the OSL signals induced in quartz by alpha and beta radiation follow the same recombination path. We also show that a mixed alpha-beta dose response reproduces the beta dose response only up to about 800 Gy. Assuming an a-value of 0.04 we have shown that laboratory alpha and beta dose response curves overlap up to effective alpha doses of ∼50 Gy. Based on these results, we conclude that exposure of fine grains to alpha radiation during burial and transport cycles prior to deposition, as well exposure to the mixed radiation field experienced during burial are not responsible for the age discrepancies previously reported on fine and coarse grained quartz extracted from Romanian and Serbian loess. - Highlights: • Prior alpha irradiation history does not influence the laboratory beta growth curves. • Alpha and beta induced photon emissions in quartz follow the same recombination path. • Laboratory alpha and beta growth curves overlap up to total alpha doses of ∼1250 Gy. • Mixed alpha-beta growth curves reproduce the beta dose response curves up to ∼800 Gy. • Mixed radiation field is not

Radiation-induced frequency transients in AT, BT, and SC cut quartz resonators

International Nuclear Information System (INIS)

Koehler, D.R.

1979-01-01

Earlier studies of transient frequency changes in high-purity swept AT quartz resonators led to the conclusion that impurity-induced effects were small, while the observed changes were qualitatively and quantitatively well characterized in terms of the time changing temperature of the vibrating quartz and its effect on frequency. 5 MHz, AT cut fifth overtone, and BT and SC cut third overtone resonators were prepared from a single stone of Sawyer swept Premium-Q quartz. The resonators were operated in precision ovenized oscillators at or near their turnover temperatures. Pulsed irradiation, at dose levels of the order of 10 4 rads (Si) per pulse, was accomplished at Sandia. The experimental data display negative frequency transients for the AT cut resonators, positive frequency transients for the BT cut resonators, and very small transient effects for the SC cut resonators. From these experimental results, it is concluded that no measurable impurity-induced frequency changes are observed in this high-purity swept-quartz and that the frequency transients are accurately modelled in terms of transient temperature effects stemming from the thermal characteristics of the resonator structure

A study of positron properties in quartz crystals and synthetic silica glass

International Nuclear Information System (INIS)

Anwand, W.; Brauer, G.; Hesegawa, M.; Dersch, O.; Rauch, F.

2001-01-01

The monoenergetic positron beamline 'SPONSOR' at Rossendorf has been used to investigate the positron behaviour in a naturally grown Brasilian quartz, two synthetic quartz crystals of different origin, and synthetic silica glass. The measurements allow us to obtain the positron diffusion length of free positrons and Bloch para-positronium, if formed, in these materials. In addition, hydrothermal treatment of a synthetic quartz has been used to introduce hydrogen into the crystal up to a certain depth. The presence of hydrogen is found to influence the formation of para-positronium. The depth distribution of hydrogen has been measured independently by the nuclear reaction analysis, and will be discussed in comparison with the results deduced from the positron studies. (author)

Constraints on Alpine Fault (New Zealand) Mylonitization Temperatures and Geothermal Gradient from Ti-in-quartz Thermobarometry

OpenAIRE

Kidder, Steven; Toy, Virginia; Prior, Dave; Little, Tim; MacRae, Colin

2018-01-01

We constrain the thermal state of the central Alpine Fault using approximately 750 Ti-in-quartz SIMS analyses from a suite of variably deformed mylonites. Ti-in-quartz concentrations span more than an order of magnitude from 0.24 to ~5 ppm, suggesting recrystallization of quartz over a 300° range in temperature. Most Ti-in-quartz concentrations in mylonites, protomylonites, and the Alpine Schist protolith are between 2 and 4 ppm and do not vary as a function of grain size or bul...

Adhesion of Escherichia coli onto quartz, hematite and corundum: extended DLVO theory and flotation behavior.

Science.gov (United States)

Farahat, Mohsen; Hirajima, Tsuyoshi; Sasaki, Keiko; Doi, Katsumi

2009-11-01

The adhesion of Escherichia coli onto quartz, hematite and corundum was experimentally investigated. A strain of E. coli was used that had the genes for expressing protein for silica precipitation. The maximum cell adhesion was observed at pH mineral adhesion was assessed by the extended DLVO theory approach. The essential parameters for calculation of microbe-mineral interaction energy (Hamaker constants and acid-base components) were experimentally determined. The extended DLVO approach could be used to explain the results of the adhesion experiments. The effect of E. coli on the floatability of three oxide minerals was determined and the results showed that E. coli can act as a selective collector for quartz at acidic pH values, with 90% of the quartz floated at 1.5 x 10(9)cells/ml. However, only 9% hematite and 30% corundum could be floated under similar conditions. By using E. coli and no reagents, it was possible to separate quartz from a hematite-quartz mixture with Newton's efficiency of 0.70. Removal of quartz from the corundum mixture was achieved by E. coli with Newton's efficiency of 0.62.

Acoustic loss and frequency stability studies of gamma- and proton-irradiated alpha-quartz crystal resonators

International Nuclear Information System (INIS)

Suter, J.J.

1988-01-01

This work examines the radiation-induced effects in alpha-quartz crystal resonators and distinguishes the various acoustic losses responsible for the frequency susceptibility over these dose ranges. Simulation of low-earth-orbit proton radiation was accomplished with protons from the Harvard University Cyclotron using a novel proton-beam modulator, which was designed to emulate a 10-120 MeV proton spectrum for the radiation susceptibility and acoustic-loss studies on AT quartz resonators. Quartz resonators having aluminum defect center concentrations between 0.01 and 19 ppm experienced proton-induced frequency shifts not correlated to their aluminum impurity content. It was also found that AT quartz resonators of the electrode-less BVA design experienced the smallest frequency shifts. Experiments conducted with 1.25-MeV gamma rays from a cobalt 60 source demonstrated identical frequency shifts in quartz, indicating that the energy losses of gamma rays and protons in quartz over the examined dose and energy ranges were similar. Acoustic-loss measurements conducted over the 0.3-70 K range revealed that the phonon-phonon and two-level energy excitation peaks near 20 and 5 K, respectively, were not affected by proton or cobalt 60 radiation

Post mortem analysis of a JET quartz microbalance system

Energy Technology Data Exchange (ETDEWEB)

Esser, H.G. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany)]. E-mail: h.g.esser@fz-juelich.de; Philipps, V. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany); Wienhold, P. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany); Sugiyama, K. [Department of Nuclear Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Kreter, A. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany); Coad, J.P. [UKAEA/EURATOM Fusion Association, Culham Science Centre, Abingdon (United Kingdom); Tanabe, T. [Department of Nuclear Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

2007-06-15

In the year 2001, a quartz microbalance system (QMB) was installed in the remote area of the inner JET divertor to investigate in situ material erosion and redeposition processes. When removed in 2004, the system was found to be coated all over with carbon deposits. The deposit on the quartz oscillator and the outer and inner housing was analysed by various methods, as SIMS (secondary ion mass spectroscopy), stylus depth profilometry, EPMA (electron probe microanalysis), TIPT (Tritium imaging plate technique) and colorimetry and compared to the frequency change of the quartz. The layer thickness was determined to 1.85 {+-} 0.1 {mu}m in average on an area of 0.95 cm{sup 2} which has to be related to the equivalent of 1.77 x 10{sup -4} g measured from the frequency change of 23 640 Hz. This corresponds to a carbon areal density of 9.3 x 10{sup 18} C atoms/cm{sup 2}. Significant deposition was found also on the surfaces inside the QMB housing which can only be understood if reflection and low sticking is assumed for a high fraction of particles.

Relationship of Technological Properties with Dynamic Recrystallization of Quartz on the Example of Objects of the Karelian-Kola Region

Science.gov (United States)

Skamnitskaya, Lubov; Rakov, Leonid; Bubnova, Tatyana; Shchiptsov, Vladimir

2017-12-01

Despite the significant reserves of quartz raw materials, there is a deficit of high purity quartz. It is due to the strict technical requirements imposed by standards for this type of raw materials and technological properties of quartz, which are determined by the features of the crystal structure. The crystalline structure is of particular importance for the technological properties of quartz, since such important characteristics as the limit of raw material enrichment, dissolution rate in acid, melting point of quartz, etc., are determined. The formation of the crystal structure of quartz under natural conditions is associated with the successive dynamic recrystallization of the mineral. The degree of dynamic recrystallization of quartz reflects the distribution of dispersed impurities. If it is weakly manifested, the dispersed impurities are not displaced from one zone to another, and all quartz microblocks contain approximately the same concentration. In this case, more or less uniform dissolution of various regions of quartz is observed, and the pattern of distribution of submicroscopic inhomogeneities is monotonic. If intensive dynamic recrystallization of quartz takes place, then it causes a significant redistribution of the scattered impurities. Then the treatment in HF leads to the appearance of a contrast pattern of the distribution of submicroscopic inhomogeneities. The details of the crystal structure of quartz in this work were investigated by the electron paramagnetic resonance (EPR) method using the ER-420 “Bruker” spectrometer. In the selected samples of quartz, the concentrations of isomorphic impurities Al and Ti were measured, and the degree of crystallinity D of the mineral was estimated from the EPR spectra of each of them. Thus, the technological properties of quartz are determined by various geological processes. The results of the studies show that when evaluating the prospects of quartz raw materials, it is necessary to take into

Magma reservoir dynamics at Toba caldera, Indonesia, recorded by oxygen isotope zoning in quartz.

Science.gov (United States)

Budd, David A; Troll, Valentin R; Deegan, Frances M; Jolis, Ester M; Smith, Victoria C; Whitehouse, Martin J; Harris, Chris; Freda, Carmela; Hilton, David R; Halldórsson, Sæmundur A; Bindeman, Ilya N

2017-01-25

Quartz is a common phase in high-silica igneous rocks and is resistant to post-eruptive alteration, thus offering a reliable record of magmatic processes in silicic magma systems. Here we employ the 75 ka Toba super-eruption as a case study to show that quartz can resolve late-stage temporal changes in magmatic δ 18 O values. Overall, Toba quartz crystals exhibit comparatively high δ 18 O values, up to 10.2‰, due to magma residence within, and assimilation of, local granite basement. However, some 40% of the analysed quartz crystals display a decrease in δ 18 O values in outermost growth zones compared to their cores, with values as low as 6.7‰ (maximum ∆ core-rim  = 1.8‰). These lower values are consistent with the limited zircon record available for Toba, and the crystallisation history of Toba quartz traces an influx of a low-δ 18 O component into the magma reservoir just prior to eruption. Here we argue that this late-stage low-δ 18 O component is derived from hydrothermally-altered roof material. Our study demonstrates that quartz isotope stratigraphy can resolve magmatic events that may remain undetected by whole-rock or zircon isotope studies, and that assimilation of altered roof material may represent a viable eruption trigger in large Toba-style magmatic systems.

75 FR 12468 - Airworthiness Directives; Quartz Mountain Aerospace, Inc. Model 11E Airplanes

Science.gov (United States)

2010-03-16

... Aerospace, Inc. Model 11E Airplanes AGENCY: Federal Aviation Administration (FAA), Department of... airworthiness directive (AD) for all Quartz Mountain Aerospace, Inc. Model 11E airplanes. This proposed AD would... 5 p.m., Monday through Friday, except Federal holidays. Quartz Mountain Aerospace, Inc. is in...

Nitrate-cancrinite precipitation on quartz sand in simulated Hanford tank solutions.

Science.gov (United States)

Bickmore, B R; Nagy, K L; Young, J S; Drexler, J W

2001-11-15

Caustic NaNO3 solutions containing dissolved Al were reacted with quartz sand at 89 degrees C to simulate possible reactions between leaked nuclear waste and primary subsurface minerals at the U.S. Department of Energy's Hanford site in Washington. Nitrate-cancrinite began to precipitate onto the quartz after 2-10 days, cementing the grains together. Estimates of the equilibrium constant for the precipitation reaction differ for solutions with 0.1 or 1.0 m OH- (log Keq = 30.4 +/- 0.8 and 36.2 +/- 0.6, respectively). The difference in solubility may be attributable to more perfect crystallinity (i.e., fewer stacking faults) in the higher-pH cancrinite structure. This is supported by electron micrographs of crystal morphology and measured rates of Na volatilization under an electron beam. Precipitate crystallinity may affect radionuclide mobility, because stacking faults in the cancrinite structure can diminish its zeolitic cation exchange properties. The precipitation rate near the onset of nucleation depends on the total Al and Si concentrations in solution. The evolution of experimental Si concentrations was modeled by considering the dependence of quartz dissolution rate on AI(OH)4- activity, cancrinite precipitation, and the reduction of reactive surface area of quartz due to coverage by cancrinite.

Gas loading of graphene-quartz surface acoustic wave devices

Science.gov (United States)

Whitehead, E. F.; Chick, E. M.; Bandhu, L.; Lawton, L. M.; Nash, G. R.

2013-08-01

Graphene was transferred to the propagation path of quartz surface acoustic wave devices and the attenuation due to gas loading of air and argon measured at 70 MHz and 210 MHz and compared to devices with no graphene. Under argon loading, there was no significant difference between the graphene and non-graphene device and the values of measured attenuation agree well with those calculated theoretically. Under air loading, at 210 MHz, there was a significant difference between the non-graphene and graphene devices, with the average value of attenuation obtained with the graphene devices being approximately twice that obtained from the bare quartz devices.

Quartz microbalance device for transfer into ultrahigh vacuum systems

International Nuclear Information System (INIS)

Stavale, F.; Achete, C. A.; Niehus, H.

2008-01-01

An uncomplicated quartz microbalance device has been developed which is transferable into ultrahigh vacuum (UHV) systems. The device is extremely useful for flux calibration of different kinds of material evaporators. Mounted on a commercial specimen holder, the device allows fast quartz microbalance transfer into the UHV and subsequent positioning exactly to the sample location where subsequent thin film deposition experiments shall be carried out. After backtransfer into an UHV sample stage, the manipulator may be loaded in situ with the specimen suited for the experiment. The microbalance device capability is demonstrated for monolayer and submonolayer vanadium depositions with an achieved calibration sensitivity of less the 0.001 ML coverage.

Characterization of silica quartz as raw material in photovoltaic applications

Energy Technology Data Exchange (ETDEWEB)

Boussaa, S. Anas, E-mail: sabiha.anas@gmail.com; Kheloufi, A.; Kefaifi, A.; Kerkar, F. [Division croissance cristalline et procédés métallurgiques CCPM Centre de recherche en technologie des semi-conducteurs pour l’énergétique (C.R.T.S.E) 02 Bd Frantz Fanon BP. 140 Alger 7 merveilles, Alger 16200 (Algeria); Zaourar, N. Boutarek [Laboratoire des technologies des matériaux, USTHB, B.P. 32 El Alia, Bab Ezzouar, Alger, Algérie 16111 (Algeria)

2016-07-25

Raw materials are essential for the functioning of modern societies, and access to these raw materials is vital to the world economy. Sustainable development, both globally level, raises important new challenges associated with access and efficient use of raw materials. High purity quartz, is consider as a critical raw material and it is a rare commodity that only forms under geological conditions where a narrow set of chemical and physical parameters is fulfilled. When identified and following special beneficiation techniques, high purity quartz obtains very attractive prices and is applied in high technology sectors that currently are under rapid expansion such as photovoltaic solar cells, silicon metal - oxide wafers in the semiconductor industry and long distance optical fibers that are used in communication networks. Crystalline silicon remains the principal material for photovoltaic technology. Metallurgical silicon is produced industrially by the reduction of silica with carbon in an electric arc furnace at temperatures higher than 2000 °C in the hottest parts, by a reaction that can be written ideally as: SiO{sub 2} + 2C = Si + 2CO. The aim of this study has been to test experimental methods for investigating the various physical and chemical proprieties of Hoggar quartz with different techniques: X Ray Fluorescence, infra-red spectroscopy, Scanning Electron Microscopy, Optic Microscopy, Carbon Analyzer and Vickers Hardness. The results show finally that the quartz has got good result in purity but need enrichment for the photovoltaic application.

Theoretical modelling of experimental diagnostic procedures employed during pre-dose dosimetry of quartz

International Nuclear Information System (INIS)

Pagonis, V.; Chen, R.; Kitis, G.

2006-01-01

The pre-dose technique in thermoluminescence (TL) is used for dating archaeological ceramics and for accident dosimetry. During routine applications of this technique, the sensitisation of the quartz samples is measured as a function of the annealing temperature, yielding the so-called thermal activation characteristic (TAC). The measurement of multiple TACs and the study of the effect of UV-radiation on the TL sensitivity of quartz are important analytical and diagnostic tools. In this paper, it is shown that a modified Zimmerman model for quartz can successfully model the experimental steps undertaken during a measurement of multiple TACs. (authors)

Luminescence lifetimes in quartz: dependence on annealing temperature prior to beta irradiation

International Nuclear Information System (INIS)

Galloway, R.B.

2002-01-01

It is well known that the thermal history of a quartz sample influences the optically stimulated luminescence sensitivity of the quartz. It is found that the optically stimulated luminescence lifetime, determined from time resolved spectra obtained with pulsed stimulation, also depends on past thermal treatment. For samples at 20 deg. C during stimulation, the lifetime depends on beta dose and on duration of preheating at 220 deg. C prior to stimulation for quartz annealed at 600 deg. C and above, but is independent of these factors for quartz annealed at 500 deg. C and below. For stimulation at higher temperatures, the lifetime becomes shorter if the sample is held at temperatures above 125 deg. C during stimulation, in a manner consistent with thermal quenching. A single exponential decay is all that is required to fit the time resolved spectra for un-annealed quartz regardless of the temperature during stimulation (20-175 deg. C), or to fit the time resolved spectra from all samples held at 20 deg. C during stimulation, regardless of annealing temperature (20-1000 deg. C). An additional shorter lifetime is found for some combinations of annealing temperature and temperature during stimulation. The results are discussed in terms of a model previously used to explain thermal sensitisation. The luminescence lifetime data are best explained by the presence of two principal luminescence centres, their relative importance depending on the annealing temperature, with a third centre involved for limited combinations of annealing temperature and temperature during stimulation

High-Precision Hysteresis Sensing of the Quartz Crystal Inductance-to-Frequency Converter.

Science.gov (United States)

Matko, Vojko; Milanović, Miro

2016-06-28

A new method for the automated measurement of the hysteresis of the temperature-compensated inductance-to-frequency converter with a single quartz crystal is proposed. The new idea behind this method is a converter with two programmable analog switches enabling the automated measurement of the converter hysteresis, as well as the temperature compensation of the quartz crystal and any other circuit element. Also used is the programmable timing control device that allows the selection of different oscillating frequencies. In the proposed programmable method two different inductances connected in series to the quartz crystal are switched in a short time sequence, compensating the crystal's natural temperature characteristics (in the temperature range between 0 and 50 °C). The procedure allows for the measurement of the converter hysteresis at various values of capacitance connected in parallel with the quartz crystal for the converter sensitivity setting at selected inductance. It, furthermore, enables the measurement of hysteresis at various values of inductance at selected parallel capacitance (sensitivity) connected to the quartz crystal. The article shows that the proposed hysteresis measurement of the converter, which converts the inductance in the range between 95 and 100 μH to a frequency in the range between 1 and 200 kHz, has only 7 × 10(-13) frequency instability (during the temperature change between 0 and 50 °C) with a maximum 1 × 10(-11) hysteresis frequency difference.

High-Precision Hysteresis Sensing of the Quartz Crystal Inductance-to-Frequency Converter

Directory of Open Access Journals (Sweden)

Vojko Matko

2016-06-01

Full Text Available A new method for the automated measurement of the hysteresis of the temperature-compensated inductance-to-frequency converter with a single quartz crystal is proposed. The new idea behind this method is a converter with two programmable analog switches enabling the automated measurement of the converter hysteresis, as well as the temperature compensation of the quartz crystal and any other circuit element. Also used is the programmable timing control device that allows the selection of different oscillating frequencies. In the proposed programmable method two different inductances connected in series to the quartz crystal are switched in a short time sequence, compensating the crystal’s natural temperature characteristics (in the temperature range between 0 and 50 °C. The procedure allows for the measurement of the converter hysteresis at various values of capacitance connected in parallel with the quartz crystal for the converter sensitivity setting at selected inductance. It, furthermore, enables the measurement of hysteresis at various values of inductance at selected parallel capacitance (sensitivity connected to the quartz crystal. The article shows that the proposed hysteresis measurement of the converter, which converts the inductance in the range between 95 and 100 μH to a frequency in the range between 1 and 200 kHz, has only 7 × 10−13 frequency instability (during the temperature change between 0 and 50 °C with a maximum 1 × 10−11 hysteresis frequency difference.

Diagenèse expérimentale du quartz en présence d'hydrocarbures

OpenAIRE

Teinturier , Stéphane

2002-01-01

Quartz cementation has a great impact on petroleum reservoir quality by controlling the porosity and thus the gas or oil storage. Experiments were carried out in a silica+-water+-salts+-oil+-gas system with the objective to simulate the siliceous diagenesis of natural petroleum reservoirs and to better understand the mechanisms of fluid inclusions formation and quartz cementation in a water and/or petroleum system.; La cimentation du quartz est un processus diagénétique important puisqu'elle ...

Experimental deformation in sandstone, carbonates and quartz aggregate

Energy Technology Data Exchange (ETDEWEB)

Cheung, Cecilia See Nga [Stony Brook Univ., NY (United States)

2015-05-01

The first part of my thesis is mainly focused on the effect of grain size distribution on compaction localization in porous sandstone. To identify the microstructural parameters that influence compaction band formation, I conducted a systematic study of mechanical deformation, failure mode and microstructural evolution in Bleurswiller and Boise sandstones, of similar porosity (~25%) and mineralogy but different sorting. Discrete compaction bands were observed to develop over a wide range of pressure in the Bleurswiller sandstone that has a relatively uniform grain size distribution. In contrast, compaction localization was not observed in the poorly sorted Boise sandstone. My results demonstrate that grain size distribution exerts important influence on compaction band development, in agreement with recently published data from Valley of Fire and Buckskin Gulch, as well as numerical studies. The second part aimed to improve current knowledge on inelastic behavior, failure mode and brittle-ductile transition in another sedimentary rock, porous carbonates. A micritic Tavel (porosity of ~13%) and an allochemical Indiana (~18%) limestones were deformed under compaction in wet and dry conditions. At lower confining pressures, shear localization occurred in brittle faulting regime. Through transitional regime, the deformation switched to cataclastic flow regime at higher confining pressure. Specifically in the cataclastic regime, the (dry and wet) Tavel and dry Indiana failed by distributed cataclastic flow, while in contrast, wet Indiana failed as compaction localization. My results demonstrate that different failure modes and mechanical behaviors under different deformation regimes and water saturation are fundamental prior to any geophysical application in porous carbonates. The third part aimed to focus on investigating compaction on quartz aggregate starting at low (MPa) using X-ray diffraction. We report the diffraction peak evolution of quartz with increasing

Thermal dependence of luminescence lifetimes and radioluminescence in quartz

Energy Technology Data Exchange (ETDEWEB)

Pagonis, V., E-mail: vpagonis@mcdaniel.edu [McDaniel College, Physics Department, Westminster, MD 21157 (United States); Chithambo, M.L. [Department of Physics and Electronics, Rhodes University, PO BOX 94, Grahamstown 6140 (South Africa); Chen, R. [Raymond and Beverly Sackler School of Physics and Astronomy, Tel-Aviv University, Tel-Aviv 69978 (Israel); Chruścińska, A. [Institute of Physics, Nicholas Copernicus University, 87-100 Toruń (Poland); Fasoli, M. [Department of Materials Science, University of Milano-Bicocca, Via Cozzi 53, 20125 Milano (Italy); Li, S.H. [Department of Earth Sciences, The University of Hong Kong (Hong Kong); Martini, M. [Department of Materials Science, University of Milano-Bicocca, Via Cozzi 53, 20125 Milano (Italy); Ramseyer, K. [Institut für Geologie, Baltzerstrasse 1-3, 3012 Bern (Switzerland)

2014-01-15

During time-resolved optical stimulation experiments (TR-OSL), one uses short light pulses to separate the stimulation and emission of luminescence in time. Experimental TR-OSL results show that the luminescence lifetime in quartz of sedimentary origin is independent of annealing temperature below 500 °C, but decreases monotonically thereafter. These results have been interpreted previously empirically on the basis of the existence of two separate luminescence centers L{sub H} and L{sub L} in quartz, each with its own distinct luminescence lifetime. Additional experimental evidence also supports the presence of a non-luminescent hole reservoir R, which plays a critical role in the predose effect in this material. This paper extends a recently published analytical model for thermal quenching in quartz, to include the two luminescence centers L{sub H} and L{sub L}, as well as the hole reservoir R. The new extended model involves localized electronic transitions between energy states within the two luminescence centers, and is described by a system of differential equations based on the Mott–Seitz mechanism of thermal quenching. It is shown that by using simplifying physical assumptions, one can obtain analytical solutions for the intensity of the light during a TR-OSL experiment carried out with previously annealed samples. These analytical expressions are found to be in good agreement with the numerical solutions of the equations. The results from the model are shown to be in quantitative agreement with published experimental data for commercially available quartz samples. Specifically the model describes the variation of the luminescence lifetimes with (a) annealing temperatures between room temperature and 900 °C, and (b) with stimulation temperatures between 20 and 200 °C. This paper also reports new radioluminescence (RL) measurements carried out using the same commercially available quartz samples. Gaussian deconvolution of the RL emission spectra was

Hydrogen sensing method with a quartz sensor

International Nuclear Information System (INIS)

Suzuki, A.; Kurokawa, A.; Nonaka, H.

2006-01-01

The stability for hydrogen leakage detection was improved by impedance measurement with a quartz sensor (Q-sensor) instead of pressure measurement with a quartz friction pressure gauge (Q-gauge) previously used. Degree of the experimental fluctuation of the impedance from the Q-sensor and of the pressure from the Q-gauge was 0.06 and 0.2 % of each output, thus showing that the Q-sensor measurement was more stable than that by the Q-gauge. Estimated minimum detection limit for hydrogen by the Q-sensor impedance measurement is also improved compared to the Q-gauge pressure measurement. Low hydrogen concentration experiment presented that the Q-sensor impedance measurement detects the 0.05 vol.% hydrogen in air at atmospheric pressure more sensitively than the Q-gauge pressure measurement. It was proved that the Q-sensor impedance measurement was more sensitive and stable as a hydrogen leakage detection method than the Q-gauge pressure measurement. (authors)

Aspects of pre-dose and other luminescence phenomena in quartz absorbed dose estimation

International Nuclear Information System (INIS)

Adamiec, G.

2000-01-01

The understanding of all luminescence processes occurring in quartz is of paramount importance in the further development of robust absorbed dose estimation techniques (for the purpose of dating and retrospective dosimetry). The findings presented in this thesis, aid future improvements of absorbed dose estimation techniques using quartz by presenting investigations in the following areas: 1) interpretation of measurement results, 2) numerical modelling of luminescence in quartz, 3) phenomena needing inclusion in future physical models of luminescence. In the first part, the variability of properties of single quartz grains is examined. Through empirical and theoretical considerations, investigations are made of various problems of measurements of luminescence using multi-grain aliquots, and specifically areas where the heterogeneity of the sample at the inter-grain level may be misinterpreted at the multi-grain-aliquot level. The results obtained suggest that the heterogeneity of samples is often overlooked, and that such differences can have a profound influence on the interpretation of measurement results. Discussed are the shape of TL glow curves, OSL decay curves, dose response curves (including consequences for using certain signals as proxies for others), normalisation procedures and D E estimation techniques. Further, a numerical model of luminescence is proposed, which includes multiple R-centres and is used to describe the pre-dose sensitisation in quartz. The numerical model exhibits a broad-scale behaviour observed experimentally in a sample of annealed quartz. The shapes of TAC for lower (20 Gy) and higher doses (1 kGy) and the evolution with temperature of the isothermal sensitisation curves are qualitatively matched for the empirical and numerical systems. In the third area, a preliminary investigation of the properties of the '110 deg. C peak' in the 550 nm emission band, in annealed quartz is presented. These properties are in sharp contrast with

Petrography, geochemistry and tectonic setting of Rigi granitoid body (east of Lut Block, Central Iran)

International Nuclear Information System (INIS)

Ghonjalipour, R.; Biabangard, H.; Ahmadi, A.

2016-01-01

The Rigi Granitoid Mountain is located in 5 Km West of Dehsalm and 85 Km West of Nehbandan city, southeast of Birjand province and east of Lut Block. This granitoid with Eocene-Oligocene age was penetrated into sedimentary rocks (shale, limestone and sandstone) and changes theses rocks to skarn, hornfels and calcsilicate rocks. This granitoid consist of granodiorite, quartz monzonite and syenogranite with plagioclase, orthose, biotite, hornblende and quartz minerals. Sericite, chlorite, and Magnetite are secondary mineral in these rocks. Geochemical properties this pluton showes that it subalkaline and has metaluminous. Geochemical diagrams and presence of hornblende mineral in this pluton shows that belong to I-type granite. The rocks in granitoid pluton are enrichment LREE compare to HREE, high contents of LILE relative to HFSE and negative anomalies of Nb, Ti and P show it granitoid related to subduction zone. Also, tectonomagmatic diagrams improve that this pluton has belong to active continental margin.

Design and fabrication of an AT-cut quartz phononic Lamb wave resonator

International Nuclear Information System (INIS)

Hung, Chia-Hao; Liu, Ting-Wei; Wu, Tsung-Tsong; Wang, Wei-Shan; Esashi, Masayoshi; Lin, Yu-Ching; Sun, Jia-Hong; Chen, Yung-Yu

2013-01-01

This paper presents results on the design and fabrication of an AT-cut quartz Lamb wave resonator with phononic crystal (PC) reflective gratings. The deep reactive ion etching process with a laboratory-made etcher was utilized to fabricate PC structures of the AT-cut quartz Lamb wave resonator. The finite element method was adopted to calculate the PC band structure, effective reflective distance from the PC boundary and further the resonant modes and admittance of the phononic Lamb wave resonant cavity. Through the comparison studies between the experimental and simulated results, a design process for the AT-cut quartz phononic Lamb wave resonator was proposed. It is noted that by using the phononic reflectors, the size of the Lamb wave resonator can be reduced significantly. (paper)

Quantitative Classification of Quartz by Laser Induced Breakdown Spectroscopy in Conjunction with Discriminant Function Analysis

Directory of Open Access Journals (Sweden)

A. Ali

2016-01-01

Full Text Available A responsive laser induced breakdown spectroscopic system was developed and improved for utilizing it as a sensor for the classification of quartz samples on the basis of trace elements present in the acquired samples. Laser induced breakdown spectroscopy (LIBS in conjunction with discriminant function analysis (DFA was applied for the classification of five different types of quartz samples. The quartz plasmas were produced at ambient pressure using Nd:YAG laser at fundamental harmonic mode (1064 nm. We optimized the detection system by finding the suitable delay time of the laser excitation. This is the first study, where the developed technique (LIBS+DFA was successfully employed to probe and confirm the elemental composition of quartz samples.

Quartz substrate infrared photonic crystal

Science.gov (United States)

Ghadiri, Khosrow; Rejeb, Jalel; Vitchev, Vladimir N.

2003-01-01

This paper presents the fabrication of a planar photonic crystal (p2c) made of a square array of dielectric rods embedded in air, operating in the infrared spectrum. A quartz substrate is employed instead of the commonly used silicon or column III-V substrate. Our square structure has a normalized cylinder radius-to-pitch ratio of r/a = 0.248 and dielectric material contrast ɛr of 4.5. We choose a Z-cut synthetic quartz for its cut (geometry), and etching properties. Then a particular Z-axis etching process is employed in order to ensure the sharp-edged verticality of the rods and fast etching speed. We also present the computer simulations that allowed the establishment of the photonic band gaps (PBG) of our photonic crystal, as well as the actual measurements. An experimental measurement have been carried out and compared with different simulations. It was found that experimental results are in good agreement with different simulation results. Finally, a frequency selective device for optical communication based on the introduction of impurity sites in the photonic crystal is presented. With our proposed structure Optical System on a Chip (OsoC) with micro-cavity based active devices such as lasers, diodes, modulators, couplers, frequency selective emitters, add-drop filters, detectors, mux/demuxes and polarizers connected by passive waveguide links can be realized.

SORPTION AND DISPERSION OF STRONTIUM RADIONUCLIDE IN THE BENTONITE-QUARTZ-CLAY AS BACKFILL MATERIAL CANDIDATE ON RADIOACTIVE WASTE REPOSITORY

Directory of Open Access Journals (Sweden)

Herry Poernomo

2010-12-01

Full Text Available The experiment of sorption and dispersion characteristics of strontium in the mixture of bentonite-quartz, clay-quartz, bentonite-clay-quartz as candidate of raw material for backfill material in the radioactive waste repository has been performed. The objective of this research is to know the grain size effect of bentonite, clay, and quartz on the weight percent ratio of bentonite to quartz, clay to quartz, bentonite to clay to-quartz can be gives physical characteristics of best such as bulk density (rb, effective porosity (e, permeability (K, best sorption characteristic such as distribution coefficient (Kd, and best dispersion characteristics such as dispersivity (a and effective dispersion coefficient (De of strontium in the backfill material candidate. The experiment was carried out in the column filled by the mixture of bentonite-quartz, clay-quartz, bentonite-clay-quartz with the weight percent ratio of bentonite to quartz, clay to quartz, bentonite to clay to quartz of 100/0, 80/20, 60/40, 40/60, 20/80, 0/100 respectively at saturated condition of water, then flowed 0.1 N Sr(NO32 as buffer solution with tracer of 0.05 Ci/cm3 90Sr as strontium radionuclide simulation was leached from immobilized radioactive waste in the radioactive waste repository. The concentration of 90Sr in the effluents represented as Ct were analyzed by Ortec b counter every 30 min, then by using profile concentration of Co and Ct, values of Kd, a and De of 90Sr in the backfill material was determined. The experiment data showed that the best results were -80+120 mesh grain size of bentonite, clay, quartz respectively on the weight percent ratio of bentonite to clay to quartz of 70/10/20 with physical characteristics of rb = 0.658 g/cm3, e = 0.666 cm3/cm3, and K = 1.680x10-2 cm/sec, sorption characteristic of Kd = 46.108 cm3/g, dispersion characteristics of a = 5.443 cm, and De = 1.808x10-03 cm2/sec can be proposed as candidate of raw material of backfill material

Variation of airborne quartz in air of Beijing during the Asia-Pacific Economic Cooperation Economic Leaders' Meeting.

Science.gov (United States)

Li, Gang; Li, Yingming; Zhang, Hongxing; Li, Honghua; Gao, Guanjun; Zhou, Qian; Gao, Yuan; Li, Wenjuan; Sun, Huizhong; Wang, Xiaoke; Zhang, Qinghua

2016-01-01

Quartz particles are a toxic component of airborne particulate matter (PM). Quartz concentrations were analyzed by X-ray diffraction in eighty-seven airborne PM samples collected from three locations in Beijing before, during, and after the Asia-Pacific Economic Cooperation (APEC) Leaders' Meeting in 2014. The results showed that the mean concentrations of quartz in PM samples from the two urban sites were considerably higher than those from the rural site. The quartz concentrations in samples collected after the APEC meeting, when the pollution restriction lever was lifted, were higher than those in the samples collected before or during the APEC meeting. The quartz concentrations ranged from 0.97 to 13.2 μg/m(3), which were among the highest values amid those reported from other countries. The highest quartz concentration exceeded the Californian Office of Environmental Health Hazard Assessment reference exposure level and was close to the occupational threshold limit values for occupational settings. Moreover, a correlation analysis showed that quartz concentrations were positively correlated with concentrations of pollution parameters PM10, PM2.5, SO2 and NOx, but were negatively correlated with O3 concentration. The results suggest that the airborne quartz particles may potentially pose health risks to the general population of Beijing. Copyright © 2015. Published by Elsevier B.V.

Natural quartz TL property and similarity in Piper nigrum L

International Nuclear Information System (INIS)

Guzman A, S.; Cruz Z, E.; Furetta, C.; Brown, F.; Barboza F, M.

2009-10-01

Quartz is a mineral abundant in nature and can provide information thermoluminescent (TL), and also is located in the mineral fraction of some herbs and spices consumed. It is present the analysis of the TL properties of a sample of natural quartz rock and compared with those obtained from the fraction of Piper nigrum L. poly mineral when they were exposed to 60 Co gamma radiation. The poly minerals of Piper nigrum L. were analyzed by X-ray diffraction, where the quartz was found as a major component. They separated in different particle sizes (10, 53, 74 and 149 μm). The samples were irradiated at relatively low doses (1-500 Gy) and high (0.1-40 kGy) in order to determine the linearity of the TL emission as a function of the dose and the analysis of glow curves. Also there was the fading of the TL signal, the effect of ultra violet light. The reproducibility of the TL signal in the samples indicates that a smaller particle size gives better TL signal. (author)

Analysis of optical bleaching of OSL signal in sediment quartz

International Nuclear Information System (INIS)

Przegiętka, K.R.; Chruścińska, A.

2013-01-01

The aim of this work was to study the effect of the quality of optical bleaching on the results of OSL (Optically Stimulated Luminescence) dating method. The large aliquots of coarse quartz grains extracted from fluvial deposit were used in the study. The poor, medium and good bleaching were simulated in laboratory with help of Blue LED light source in series of experiments. Then the samples were irradiated with a common laboratory dose. The equivalent doses (DE) were measured by the help of standard Single Aliquot Regeneration (SAR) technique, but obtained DE distributions are analyzed in a new way. The method for recognizing and compensating for partial bleaching is proposed. The conclusions for dating sediment quartz samples are presented and discussed. -- Highlights: ► Bleaching experiments on sediment quartz are performed. ► Blue LED light source incorporated in luminescence reader is used. ► New analysis of data measured by standard SAR OSL technique is proposed. ► The results are promising for recognizing and compensating for partial bleaching

Understanding optically stimulated charge movement in quartz and feldspar using time-resolved measurements

International Nuclear Information System (INIS)

Ankjaergaard, C.

2010-02-01

Thermoluminescence (TL) and optically stimulated luminescence (OSL) from quartz and feldspar are widely used in accident dosimetry and luminescence dating. In order to improve already existing methods or to develop new methods towards extending the current limits of the technique, it is important to understand the charge movement within these materials. Earlier studies have primarily focussed on examination of the trap behaviour; however, this only tells half of the story as OSL is a combination of charge stimulation and recombination. By using time-resolved OSL (TR-OSL), one can directly examine the recombination route(s), and thus obtain insight into the other half of the process involved in luminescence emission. This thesis studies the TR-OSL and optically stimulated phosphorescence signals from quartz and feldspars spanning several orders of magnitude in time (few ns to the seconds time scale) in order to identify various charge transport mechanisms in the different time regimes. The techniques employed are time-resolved OSL, continuous-wave OSL, TL, optically stimulated exo-electron (OSE) emission and time-resolved OSE. These different techniques are used in combination with variable thermal or optical stimulation energy. The thesis first delves into three main methodological developments, namely (i) research and development of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration for the best separation of quartz OSL from a mixed quarts-feldspar sample. It then proceeds to study the different charge transport mechanisms subsequent to an optical stimulation pulse in quartz and feldspars. The results obtained for quartz conclude that the main lifetime component in quartz represents an excited state lifetime of the recombination centre, and the more slowly decaying components on the millisecond to seconds time scale arise from charge recycling

Understanding optically stimulated charge movement in quartz and feldspar using time-resolved measurements

Energy Technology Data Exchange (ETDEWEB)

Ankjaergaard, C.

2010-02-15

Thermoluminescence (TL) and optically stimulated luminescence (OSL) from quartz and feldspar are widely used in accident dosimetry and luminescence dating. In order to improve already existing methods or to develop new methods towards extending the current limits of the technique, it is important to understand the charge movement within these materials. Earlier studies have primarily focussed on examination of the trap behaviour; however, this only tells half of the story as OSL is a combination of charge stimulation and recombination. By using time-resolved OSL (TR-OSL), one can directly examine the recombination route(s), and thus obtain insight into the other half of the process involved in luminescence emission. This thesis studies the TR-OSL and optically stimulated phosphorescence signals from quartz and feldspars spanning several orders of magnitude in time (few ns to the seconds time scale) in order to identify various charge transport mechanisms in the different time regimes. The techniques employed are time-resolved OSL, continuous-wave OSL, TL, optically stimulated exo-electron (OSE) emission and time-resolved OSE. These different techniques are used in combination with variable thermal or optical stimulation energy. The thesis first delves into three main methodological developments, namely (i) research and development of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration for the best separation of quartz OSL from a mixed quarts-feldspar sample. It then proceeds to study the different charge transport mechanisms subsequent to an optical stimulation pulse in quartz and feldspars. The results obtained for quartz conclude that the main lifetime component in quartz represents an excited state lifetime of the recombination centre, and the more slowly decaying components on the millisecond to seconds time scale arise from charge recycling

On luminescence lifetimes in quartz

International Nuclear Information System (INIS)

Chithambo, M.L.; Galloway, R.B.

2000-01-01

In this paper we present results of investigations concerning the time dependence of luminescence emission relative to the time of stimulation in quartz. Measurements of time-resolved spectra were performed on a new versatile pulsed light emitting diode system using 525 nm stimulation, an 11 μs duration pulse, a repetition rate of 11 kHz and a 64 μs dynamic range. Effects on luminescence lifetime resulting from sample treatments such as optical stimulation, irradiation, and preheating, are reported

Mineralization and geophysical exploration by IP/RS and ground magnetic survey in MA-I and surrounding area, Maherabad porphyry Cu-Au prospect area, east of Iran

Directory of Open Access Journals (Sweden)

Azadeh Malekzadeh Shafaroudi

2009-10-01

Full Text Available Maherabad prospect area, which is studied in detail, is the first porphyry Cu-Au mineralization in the east of Iran. Based on relation of mineralization with subvolcanic intrusive bodies mostly monzonitic with porphyry texture, extent and types of alteration including potassic, sericitic- potassic, quartz- sericite- carbonate- pyrite, quartz- carbonate- pyrite, silicification- propylitic, propylitic, stockwork mineralization, assemblages hypogene mineralization including pyrite, chalcopyrite, bornite and magnetite and high anomalies of Cu and Au, Mineralization is porphyry Cu-Au-type. MA-I area, which is covered by regolith from its surrounding is the most important section of mineralization in the region because of intensive of quartz-sericite-carbonate-pyrite alteration and very high dense quartz-sulfide veinlets. IP/RS and ground magnetic surveys were conducted in the MA-I prospect area and its surrounding plain. Drilling on the IP suede section anomaly resulted to the recognition of sulfide mineralization in on extensive area under the regolith. Surface and underground detailed studies of geology, alteration, mineralization and geochemistry confirm the extension of covered mineralization to the south and west of the area. Based on the ground magnetic anomaly, the center of mineralization system, potassic zone, to the southwest of the area was recognized. Quartz0sericite-carbonate-pyrite alteration zone, which is located around the potassic zone, has very low magnetic response. IP/RS and ground magnetic surveys in a broader area than before are strongly recommended.

Measurement of fast risetime megampere currents by quartz gauge

International Nuclear Information System (INIS)

Williams, R.R.; McDaniel, D.H.; Stinnett, R.W.

1980-01-01

Quartz gauges have been used on the Sandia National Laboratories Proto II accelerator to measure current in the magnetically insulated transmission line at the 11 TW power level. The accelerator delivers 3.5 MA at 2 x 10 14 A/s in a 40 ns pulse to a 0.0127 m diameter aluminum liner to produce a high density plasma. At this radius and dI/dt levels, the B-dot monitors no longer function for the measurement of load current because the monitor suffers electrical breakdown. Quartz pressure gauges mounted at a radius of 0.0086 m have successfully measured the magnetic pressure due to the load current with nanosecond temporal resolution

Natural sunlight bleaching of the aluminum center in quartz

International Nuclear Information System (INIS)

Lin Min; Yin Gongming; Han Kongyan; Bao Jifei; Liu Jingwei; Jia Li

2007-01-01

The effect of sunlight bleaching on ESR signals from the aluminum center in quartz is reported for two samples of sand-sized quartz, one from a granite and one from a beach sand. The grains were exposed to direct sunlight for periods of time up to 500 h, with bleaching carried out in four different cities in China that are from 50 to 3600 m above sea level. Each sample bleached to the same residual level, ∼55% for the granite and 80% for the beach sand of the initial value after a 200 Gy dose had been given. After 200 h, the bleaching level reached was independent of the height above sea level

Timescales of quartz crystallization and the longevity of the Bishop giant magma body.

Science.gov (United States)

Gualda, Guilherme A R; Pamukcu, Ayla S; Ghiorso, Mark S; Anderson, Alfred T; Sutton, Stephen R; Rivers, Mark L

2012-01-01

Supereruptions violently transfer huge amounts (100 s-1000 s km(3)) of magma to the surface in a matter of days and testify to the existence of giant pools of magma at depth. The longevity of these giant magma bodies is of significant scientific and societal interest. Radiometric data on whole rocks, glasses, feldspar and zircon crystals have been used to suggest that the Bishop Tuff giant magma body, which erupted ~760,000 years ago and created the Long Valley caldera (California), was long-lived (>100,000 years) and evolved rather slowly. In this work, we present four lines of evidence to constrain the timescales of crystallization of the Bishop magma body: (1) quartz residence times based on diffusional relaxation of Ti profiles, (2) quartz residence times based on the kinetics of faceting of melt inclusions, (3) quartz and feldspar crystallization times derived using quartz+feldspar crystal size distributions, and (4) timescales of cooling and crystallization based on thermodynamic and heat flow modeling. All of our estimates suggest quartz crystallization on timescales of magma bodies are ephemeral features that, once established, evolve on millennial timescales. We also suggest that zircon crystals, rather than recording the timescales of crystallization of a large pool of crystal-poor magma, record the extended periods of time necessary for maturation of the crust and establishment of these giant magma bodies.

Radiation-induced conductivity and high-temperature Q changes in quartz resonators

International Nuclear Information System (INIS)

Koehler, D.R.

1981-01-01

While high temperature electrolysis has proven beneficial as a technique to remove interstitial impurities from quartz, reliable indices to measure the efficacy of such a processing step are still under development. The present work is directed toward providing such an index. Two techniques have been investigated - one involves measurement of the radiation induced conductivity in quartz along the optic axis, and the second involves measurement of high temperature Q changes. Both effects originate when impurity charge compensators are released from their traps, in the first case resulting in ionic conduction and in the second case resulting in increased acoustic losses. Radiation induced conductivity measurements have been carried out with a 200 kV, 14 mA x-ray machine producing 5 rads/s. With electric fields of the order of 10 4 V/cm, the noise level in the current measuring system is equivalent to an ionic current generated by quartz impurities in the 1 ppB range. The accuracy of the high temperature ( 300 to 800 0 K) Q -1 measurement technique will be determined. A number of resonators constructed of quartz material of different impurity contents have been tested and both the radiation induced conductivity and the high temperature Q -1 results compared with earlier radiation induced frequency and resonator resistance changes. 10 figures

Defect studies in quartz: Composite nature of the blue and UV emissions

Energy Technology Data Exchange (ETDEWEB)

Martini, Marco, E-mail: m.martini@unimib.it [Dipartimento di Scienza dei Materiali, Università degli Studi di Milano Bicocca, via R. Cozzi 55, I-20125 Milano (Italy); INFN, Sezione di Milano Bicocca, Piazza della Scienza 1, I-20126 Milano (Italy); Fasoli, Mauro; Villa, Irene [Dipartimento di Scienza dei Materiali, Università degli Studi di Milano Bicocca, via R. Cozzi 55, I-20125 Milano (Italy)

2014-05-01

Quartz is an extremely diffused natural luminescence dosimeter. Thanks to the presence of traps and luminescence centres, its TSL and OSL (Thermally and Optically Stimulated Luminescence) properties have been extensively exploited. Quartz is then used for archaeological and geological dating and is one of the most useful materials for accident dosimetry. Many luminescence emissions are known to be present in the OSL and TSL of quartz. Three main emission bands are always reported, as the red, blue and UV bands, centred at around 650, 470, and 360–380 nm, respectively. Although the assignment of the luminescence emissions to specific defect centres in quartz is still undefined, a thorough analysis of the radioluminescence emissions and their response to irradiation and thermal treatments turned out to be very useful in understanding many features. Specifically, the presence of the same emission bands in natural and synthetic quartz and their dependence on the presence of extrinsic impurities is a common characteristic. The main impurities involve Al ions substituting Si ones and charge compensated by nearby either alkali ions, H{sup +}, or a hole. The emission spectra dynamics evidenced in our experiment confirm the role of Al-related centres in the luminescence properties of quartz. From the measurements presented in this paper the composite nature of the “blue” emission is confirmed. Two bands labelled as A at 2.5 eV and B at 2.8 eV contribute to the emission in this region, their behaviour being different as a function of irradiation. More complex is the picture in the UV region, where, besides the already detected C and D bands at 3.4 eV and 3.9 eV, respectively, two further emissions have been detected at 3.1 eV and 3.7 eV. Despite both the 3.4 eV and the 3.7 eV bands are shown to be affected by thermal treatments, the annealing temperature dependence of their intensity is markedly different. In fact, whereas the C band intensity, at 3.4 eV, increases

Defect studies in quartz: Composite nature of the blue and UV emissions

International Nuclear Information System (INIS)

Martini, Marco; Fasoli, Mauro; Villa, Irene

2014-01-01

Quartz is an extremely diffused natural luminescence dosimeter. Thanks to the presence of traps and luminescence centres, its TSL and OSL (Thermally and Optically Stimulated Luminescence) properties have been extensively exploited. Quartz is then used for archaeological and geological dating and is one of the most useful materials for accident dosimetry. Many luminescence emissions are known to be present in the OSL and TSL of quartz. Three main emission bands are always reported, as the red, blue and UV bands, centred at around 650, 470, and 360–380 nm, respectively. Although the assignment of the luminescence emissions to specific defect centres in quartz is still undefined, a thorough analysis of the radioluminescence emissions and their response to irradiation and thermal treatments turned out to be very useful in understanding many features. Specifically, the presence of the same emission bands in natural and synthetic quartz and their dependence on the presence of extrinsic impurities is a common characteristic. The main impurities involve Al ions substituting Si ones and charge compensated by nearby either alkali ions, H + , or a hole. The emission spectra dynamics evidenced in our experiment confirm the role of Al-related centres in the luminescence properties of quartz. From the measurements presented in this paper the composite nature of the “blue” emission is confirmed. Two bands labelled as A at 2.5 eV and B at 2.8 eV contribute to the emission in this region, their behaviour being different as a function of irradiation. More complex is the picture in the UV region, where, besides the already detected C and D bands at 3.4 eV and 3.9 eV, respectively, two further emissions have been detected at 3.1 eV and 3.7 eV. Despite both the 3.4 eV and the 3.7 eV bands are shown to be affected by thermal treatments, the annealing temperature dependence of their intensity is markedly different. In fact, whereas the C band intensity, at 3.4 eV, increases after

Optically stimulated exoelectron emission processes in quartz: comparison of experiment and theory

DEFF Research Database (Denmark)

Pagonis, V.; Ankjærgaard, Christina; Murray, A.S.

2009-01-01

Recent experiments have demonstrated that it is possible to measure optically stimulated exoelectron emission (OSE) signals simultaneously with optically stimulated luminescence (OSL) from quartz samples. These experiments provide valuable information on the charge movement in quartz grains. Two...... data yield a value of χ1.2 eV for the work function of quartz. The experimental temperature dependence of the OSE signals is interpreted on the basis of a photo-thermostimulated (PTSEE) process involving the main OSL trap at 320 °C; this process takes place with a thermal assistance energy estimated...... at W(0.29±0.02) eV. Good quantitative agreement is obtained between theory and experiment by assuming a thermal broadening of the thermal depletion factor for the OSL traps, described by a Gaussian distribution of energies....

Trace element characterisation and purification of quartz powder of Indian origin

International Nuclear Information System (INIS)

Dash, K.; Thangavel, S.; Dhavile, S.M.; Sahayam, A.C.; Chaurasia, S.C.

2002-11-01

Analytical methodologies for the trace element characterisation and purification of quartz powder of Indian origin have been described. Metallic impurities (11 elements) in ∼700 quartz samples have been analysed using different instrumental techniques. The values are cross-validated by American and British analytical laboratories. A special multi channel vapour phase digestion (MCVPD) chamber has been designed to reduce the process blank levels for the determination of ultra trace impurities in high purity silicon matrix. In this vessel 21 samples can be digested at a time in a period of 8 hrs. at normal pressure and low temperature (∼ 80 degC). Analytical methodologies for the determination of non-metals (phosphorus, boron and chloride) at very low levels <1 ppm) have also been described. A highly cost effective, single step, room temperature purification procedure is developed based on chemical leaching. Around 300 raw quartz powders (3-4N) from various mines have been purified to 5N pure ( optical grade ). (author)

Recommendations concerning an interim annual individual exposure limit for respirable quartz

International Nuclear Information System (INIS)

Stocker, H.; Horvath, F.J.; Napier, W.

1983-07-01

This paper presents AECB staff recommendations on the desirability of an annual individual occupational exposure limit for respirable quartz and on the magnitude of this limit, for uranium miners. Justifications are presented for the magnitude of this suggested limit for respirable quartz, drawing on experience gained in Ontario uranium and non-uranium mines and on that in other countries. The suggestion is made that an exposure limit be set for an interim period in order that additional information on the adequacy of the magnitude of the limit may be acquired. To complement the suggested exposure limit, it is proposed that a co-existing control program of action levels, to be triggered at various respirable quartz concentrations, be set up. It is the contention of this paper that the degree of protection afforded to individuals by the suggested exposure limit would be equivalent to the time-weighted average threshold limit value derived from recommendations, based on group average exposures, of the American Conference of Governmental Industrial Hygienists

Difference in luminescence sensitivity of coarse-grained quartz from deserts of northern China

International Nuclear Information System (INIS)

Zheng, C.X.; Zhou, L.P.; Qin, J.T.

2009-01-01

The luminescence sensitivity of coarse quartz extracted from desert sands in northern China was investigated. In general, the western deserts' samples are shown to be less sensitive than samples from the eastern deserts with respect to both OSL and the 110 deg. C TL peak. However, internal scatter among different aliquots of the same sample is observed for these two signals, which have already been normalized by weight. Laboratory dosing/bleach experiments indicate that earth surface processes, such as repeated burial and transportation can cause the sensitivity change and suggest that they may be responsible for the internal scatter. An intrinsic property of quartz was explored via the luminescence response to thermal activation to a maximum temperature of 700 deg. C. The thermal activation curves obtained with quartz from western and central deserts are similar, except one sample from Gurbantungut, which follows the pattern of eastern samples. The differences in quartz luminescence sensitivity exhibited by OSL/110 deg. C TL sensitivity and response to thermal activation are in accordance with the published results of geochemical studies.

Quartz: structural and thermodynamic analyses across the α ↔ β transition with origin of negative thermal expansion (NTE) in β quartz and calcite

Energy Technology Data Exchange (ETDEWEB)

Antao, Sytle M.

2016-04-01

The temperature variation,T, of the crystal structure of quartz, SiO₂, from 298 to 1235 K was obtained with synchrotron powder X-ray diffraction data and Rietveld structure refinements. The polymorphic transformation fromP3₂21 (low-T, α quartz) toP6₂22 (high-T, β quartz) occurs at a transition temperature,T_tr= 847 K. TheTvariations of spontaneous strains and several structural parameters are fitted to an order parameter,Q, using Landau theory. The change in Si atom coordinate, Si_x, givesT_tr-T_c= 0.49 K, which indicates an α ↔ β transition that is weakly first order and nearly tricritical in character (Q⁴∝T). Strains give higherT_tr-T_cvalues (≃ 7 K). Other fitted parameters are the oxygen O_zcoordinate, Si—Si distance, Si—O—Si and φ angles, and intensity of the (111) reflection,I₁₁₁. In α quartz, the Si—Si distance increases withTbecause of cation repulsion, so the Si—O—Si angle increases (and φ decreases) and causes the thermal expansion of the framework structure that consists of corner-sharing distorted rigid SiO₄tetrahedra. The Si—Si distances contract withTand cause negative thermal expansion (NTE) in β quartz because of increasing thermal librations of the O atom in the Si—O—Si linkage that occur nearly perpendicular to the Si—Si contraction. In calcite, CaCO₃, the short Ca—Ca distance expands withT, but the next-nearest Ca—Ca distance, which is of equal length to theaaxis, contracts withTand causes NTE along

Direct Growth of III-Nitride Nanowire-Based Yellow Light-Emitting Diode on Amorphous Quartz Using Thin Ti Interlayer

KAUST Repository

Prabaswara, Aditya; Min, Jung-Wook; Zhao, Chao; Janjua, Bilal; Zhang, Daliang; Albadri, Abdulrahman M.; Alyamani, Ahmed Y.; Ng, Tien Khee; Ooi, Boon S.

2018-01-01

.6 V, on an amorphous quartz substrate. We achieved ~ 40% transparency across the visible wavelength while maintaining electrical conductivity by employing a TiN/Ti interlayer on quartz as a translucent conducting layer. The nanowire-on-quartz LED emits

Kinetics of the coesite to quartz transformation

Science.gov (United States)

Mosenfelder, J.L.; Bohlen, S.R.

1997-01-01

The survival of coesite in ultrahigh-pressure (UHP) rocks has important implications for the exhumation of subducted crustal rocks. We have conducted experiments to study the mechanism and rate of the coesite ??? quartz transformation using polycrystalline coesite aggregates, fabricated by devitrifying silica glass cylinders containing 2850H/106 Si at 1000??C and 3.6 GPa for 24h. Conditions were adjusted following synthesis to transform the samples at 700-1000??C at pressures 190-410 MPa below the quartz-coesite equilibrium boundary. Reaction proceeds via grain-boundary nucleation and interface-controlled growth, with characteristic reaction textures remarkably similar to those seen in natural UHP rocks. We infer that the experimental reaction mechanism is identical to that in nature, a prerequisite for reliable extrapolation of the rate data. Growth rates obtained by direct measurement differ by up to two orders of magnitude from those estimated by fitting a rate equation to the transformation-time data. Fitting the rates to Turnbull's equation for growth therefore yields two distinct sets of parameters with similar activation energies (242 or 269 kJ/mol) but significantly different pre-exponential constants. Extrapolation based on either set of growth rates suggests that coesite should not be preserved on geologic time scales if it reaches the quartz stability field at temperatures above 375-400??C. The survival of coesite has previously been linked to its inclusion in strong phases, such as garnet, that can sustain a high internal pressure during decompression. Other factors that may play a crucial role in preservation are low fluid availability - possibly even less than that of our nominally "dry" experiments - and the development of transformation stress, which inhibits nucleation and growth. These issues are discussed in the context of our experiments as well as recent observations from natural rocks. ?? 1997 Elsevier Science B.V.

Analytical results for 544 water samples collected in the Attean Quartz Monzonite in the vicinity of Jackman, Maine

Science.gov (United States)

Ficklin, W.H.; Nowlan, G.A.; Preston, D.J.

1983-01-01

Water samples were collected in the vicinity of Jackman, Maine as a part of the study of the relationship of dissolved constituents in water to the sediments subjacent to the water. Each sample was analyzed for specific conductance, alkalinity, acidity, pH, fluoride, chloride, sulfate, phosphate, nitrate, sodium, potassium, calcium, magnesium, and silica. Trace elements determined were copper, zinc, molybdenum, lead, iron, manganese, arsenic, cobalt, nickel, and strontium. The longitude and latitude of each sample location and a sample site map are included in the report as well as a table of the analytical results.

A parametric comparative study of electrocoagulation and coagulation using ultrafine quartz suspensions.

Science.gov (United States)

Kiliç, Mehtap Gülsün; Hoşten, Cetin; Demirci, Sahinde

2009-11-15

This paper attempts to compare electrocoagulation using aluminum anodes and stainless steel cathodes with conventional coagulation by aluminum sulfate dosing on aqueous suspensions of ultrafine quartz. Several key parameters affecting the efficiency of electrocoagulation and coagulation were investigated with laboratory scale experiments in search of optimal parameter values. Optimal values of the parameters were determined on the basis of the efficiency of turbidity removal from ultrafine quartz suspensions. The parameters investigated in the study were suspension pH, electrical potential, current density, electrocoagulation time, and aluminum dosage. A comparison between electrocoagulation and coagulation was made on the basis of total dissolved aluminum, revealing that electrocoagulation and coagulation were equally effective at the same aluminum dosage for the removal of quartz particles from suspensions. Coagulation, however, was more effective in a wider pH range (pH 6-9) than electrocoagulation which yielded optimum effectiveness in a relatively narrower pH range around 9, where, in both methods, these pH values corresponded to near-zero zeta potentials of quartz particles. Furthermore, experimental results confirmed that electrocoagulation could display some pH buffering capacity. The kinetics of electrocoagulation was very fast (<10 min) in approaching a residual turbidity, which could be modeled with a second-order rate equation.

Timescales of Quartz Crystallization and the Longevity of the Bishop Giant Magma Body

Energy Technology Data Exchange (ETDEWEB)

Gualda, Guilherme A.R.; Pamukcu, Ayla S.; Ghiorso, Mark S.; Anderson, Jr. , Alfred T.; Sutton, Stephen R.; Rivers, Mark L. (OFM Res.); (Vanderbilt); (UC)

2013-04-08

Supereruptions violently transfer huge amounts (100 s-1000 s km{sup 3}) of magma to the surface in a matter of days and testify to the existence of giant pools of magma at depth. The longevity of these giant magma bodies is of significant scientific and societal interest. Radiometric data on whole rocks, glasses, feldspar and zircon crystals have been used to suggest that the Bishop Tuff giant magma body, which erupted {approx}760,000 years ago and created the Long Valley caldera (California), was long-lived (>100,000 years) and evolved rather slowly. In this work, we present four lines of evidence to constrain the timescales of crystallization of the Bishop magma body: (1) quartz residence times based on diffusional relaxation of Ti profiles, (2) quartz residence times based on the kinetics of faceting of melt inclusions, (3) quartz and feldspar crystallization times derived using quartz+feldspar crystal size distributions, and (4) timescales of cooling and crystallization based on thermodynamic and heat flow modeling. All of our estimates suggest quartz crystallization on timescales of <10,000 years, more typically within 500-3,000 years before eruption. We conclude that large-volume, crystal-poor magma bodies are ephemeral features that, once established, evolve on millennial timescales. We also suggest that zircon crystals, rather than recording the timescales of crystallization of a large pool of crystal-poor magma, record the extended periods of time necessary for maturation of the crust and establishment of these giant magma bodies.

Effect of Water Glass Modification on Its Viscosity and Wettability of Quartz Grains

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A. Kmita

2012-09-01

Full Text Available The aim of the present study was to develop a modifier for water glass. The method of thermal generation of metal oxide nanoparticleswas adapted and used in the research. Nanoparticles of ZnO from the thermal decomposition of basic zinc carbonate were used. A methodfor the modifier introduction was developed, and the effect of modifier content and organic solvent type on the physico-chemicalproperties of binder (viscosity and quartz wettability was determined. Binder viscosity was examined from the flow curves plotted with the help of a RHEOTEST 2 rotational rheometer equipped with proper software. Quartz wettability was determined examining timerelated changes in the value of the contact angle in a quartz-binder system, until full stabilisation of the angle value has been achieved.Binder modification was carried out on sodium water glass designated as R"145". The water glass modifiers were suspensions of ZnOnanoparticles in propanol and methanol at a fixed concentration of c = 0.3 M and with the size of nanoparticles comprised in a range of. Water glass modification with the suspensions of ZnO nanoparticles in methanol and propanol showed the effect ofmodifier on the water glass viscosity and quartz wettability. This effect depends on the type of alcohol used. The ZnO suspension inpropanol (alcohol with a longer hydrocarbon chain affects more strongly the viscosity of binder and quartz wettability than the methanol suspension.

Effect of Water Glass Modification on Its Viscosity and Wettability of Quartz Grains

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Kmita A.

2012-09-01

Full Text Available The aim of the present study was to develop a modifier for water glass. The method of thermal generation of metal oxide nanoparticles was adapted and used in the research. Nanoparticles of ZnO from the thermal decomposition of basic zinc carbonate were used. A method for the modifier introduction was developed, and the effect of modifier content and organic solvent type on the physico-chemical properties of binder (viscosity and quartz wettability was determined. Binder viscosity was examined from the flow curves plotted with the help of a RHEOTEST 2 rotational rheometer equipped with proper software. Quartz wettability was determined examining timerelated changes in the value of the contact angle in a quartz-binder system, until full stabilisation of the angle value has been achieved. Binder modification was carried out on sodium water glass designated as R"145". The water glass modifiers were suspensions of ZnO nanoparticles in propanol and methanol at a fixed concentration of c = 0.3 M and with the size of nanoparticles comprised in a range of . Water glass modification with the suspensions of ZnO nanoparticles in methanol and propanol showed the effect of modifier on the water glass viscosity and quartz wettability. This effect depends on the type of alcohol used. The ZnO suspension in propanol (alcohol with a longer hydrocarbon chain affects more strongly the viscosity of binder and quartz wettability than the methanol suspension

Amplifier Module for 260-GHz Band Using Quartz Waveguide Transitions

Science.gov (United States)

Padmanabhan, Sharmila; Fung, King Man; Kangaslahti, Pekka P.; Peralta, Alejandro; Soria, Mary M.; Pukala, David M.; Sin, Seth; Samoska, Lorene A.; Sarkozy, Stephen; Lai, Richard

2012-01-01

Packaging of MMIC LNA (monolithic microwave integrated circuit low-noise amplifier) chips at frequencies over 200 GHz has always been problematic due to the high loss in the transition between the MMIC chip and the waveguide medium in which the chip will typically be used. In addition, above 200 GHz, wire-bond inductance between the LNA and the waveguide can severely limit the RF matching and bandwidth of the final waveguide amplifier module. This work resulted in the development of a low-loss quartz waveguide transition that includes a capacitive transmission line between the MMIC and the waveguide probe element. This capacitive transmission line tunes out the wirebond inductance (where the wire-bond is required to bond between the MMIC and the probe element). This inductance can severely limit the RF matching and bandwidth of the final waveguide amplifier module. The amplifier module consists of a quartz E-plane waveguide probe transition, a short capacitive tuning element, a short wire-bond to the MMIC, and the MMIC LNA. The output structure is similar, with a short wire-bond at the output of the MMIC, a quartz E-plane waveguide probe transition, and the output waveguide. The quartz probe element is made of 3-mil quartz, which is the thinnest commercially available material. The waveguide band used is WR4, from 170 to 260 GHz. This new transition and block design is an improvement over prior art because it provides for better RF matching, and will likely yield lower loss and better noise figure. The development of high-performance, low-noise amplifiers in the 180-to- 700-GHz range has applications for future earth science and planetary instruments with low power and volume, and astrophysics array instruments for molecular spectroscopy. This frequency band, while suitable for homeland security and commercial applications (such as millimeter-wave imaging, hidden weapons detection, crowd scanning, airport security, and communications), also has applications to

FTIR measurements of OH in deformed quartz and feldspars of the South Tibetan Detachment, Greater Himalaya

Science.gov (United States)

Jezek, L.; Law, R. D.; Jessup, M. J.; Searle, M. P.; Kronenberg, A. K.

2017-12-01

OH absorption bands due to water in deformed quartz and feldspar grains of mylonites from the low-angle Lhotse Detachment (of the South Tibetan Detachment System, Rongbuk Valley north of Mount Everest) have been measured by Fourier Transform Infrared (FTIR) Spectroscopy. Previous microstructural studies have shown that these rocks deformed by dislocation creep at high temperature conditions in the middle crust (lower - middle amphibolite facies), and oxygen isotope studies suggest significant influx of meteoric water. OH absorption bands at 3400 cm-1 of quartz mylonites from the footwall of the Lhotse Detachment Fault are large, with the character of the molecular water band due to fluid inclusions in milky quartz. Mean water contents depend on structural position relative to the core of the Lhotse Detachment, from 1000 ppm (OH/106 Si) at 420 m below the fault to 11,350 (+/-1095) ppm near its center. The gradient in OH content shown by quartz grains implies influx of meteoric water along the Lhotse Detachment from the Tibetan Plateau ground surface to middle crustal depths, and significant fluid penetration into the extruding Himalayan slab by intergranular, permeable fluid flow processes. Feldspars of individual samples have comparable water contents to those of quartz and some are wetter. Large water contents of quartz and feldspar may have contributed to continued deformation and strain localization on the South Tibetan Detachment System. Dislocation creep in quartz is facilitated by water in laboratory experiments, and the water contents of the Lhotse fault rocks are similar to (and even larger than) water contents of quartz experimentally deformed during water weakening. Water contents of feldspars are comparable to those of plagioclase aggregates deformed experimentally by dislocation and diffusion creep under wet conditions.

A STUDY OF THE PRESSURE SOLUTION AND DEFORMATION OF QUARTZ CRYSTALS AT HIGH pH AND UNDER HIGH STRESS

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JUNG-HAE CHOI

2013-02-01

Full Text Available Bentonite is generally used as a buffer material in high-level radioactive waste disposal facilities and consists of 50% quartz by weight. Quartz strongly affects the behavior of bentonite over very long periods. For this reason, quartz dissolution experiment was performed under high-pressure and high-alkalinity conditions based on the conditions found in a high-level radioactive waste disposal facility located deep underground. In this study, two quartz dissolution experiments were conducted on 1 quartz beads under low-pressure and high-alkalinity conditions and 2 a single quartz crystal under high-pressure and high-alkalinity conditions. Following the experiments, a confocal laser scanning microscope (CLSM was used to observe the surfaces of experimental samples. Numerical analyses using the finite element method (FEM were also performed to quantify the deformation of contact area. Quartz dissolution was observed in both experiments. This deformation was due to a concentrated compressive stress field, as indicated by the quartz deformation of the contact area through the FEM analysis. According to the numerical results, a high compressive stress field acted upon the neighboring contact area, which showed a rapid dissolution rate compared to other areas of the sample.

Nature sunlight bleaching of Ti center ESR signal in quartz

International Nuclear Information System (INIS)

Yin Gongming; Liu Chunru; Li Jianping; Fang Jiahu; Gao Lu; Lin Min

2009-01-01

Quartz grains were extracted from granite. Bleaching was carried out in four different area chosen for their different altitudes (Beijing, Yinchuan, Germu, Lhasa), in order to observe their behavior under different intensities of the UV (Ultra violet) component of sunlight. The result of our experiments indicate that the Ti center signal is totally bleachable by the natural sunlight and show that the Ti center signal was reduced to zero after about 128 h in Beijing and after 56 h for Lhasa. We can speculate that different intensity of the UV component of sunlight lead to different minimal time necessary to obtain the total bleaching of the quartz sample. (authors)

Uraniferous quartz-pebble conglomerates in South Africa

International Nuclear Information System (INIS)

von Backstroem, J.W.

1981-01-01

The purpose of this paper is to give a short background statement summarizing data on the Dominion Reef Group, the Witwatersrand Supergroup, and the Ventersdorp Contact Reef, with particular reference to the close relationship of gold and uranium with sedimentary features as well as the mineralization, conditions of deposition, and the nature of the quartz-pebble conglomerates

The quartz crystal microbalance in soft matter research fundamentals and modeling

CERN Document Server

Johannsmann, Diethelm

2014-01-01

This book describes the physics of the second-generation quartz crystal microbalance (QCM), a fundamental method of analysis for soft matter at interfaces.From a device for measuring film thickness in vacuum, the quartz crystal microbalance (QCM) has in the past two decades evolved into a versatile instrument for analyzing soft matter at solid/liquid and solid/gas interfaces that found applications in diverse fields including the life sciences, material science, polymer research and electrochemistry. As a consequence of this success, the QCM is now being used by scientists with a wide variety

The Cherenkov correlated timing detector: beam test results from quartz and acrylic bars

International Nuclear Information System (INIS)

Kichimi, H.; Sugaya, Y.; Yamaguchi, H.; Yoshimura, Y.; Kanda, S.; Olsen, S.; Ueno, K.; Varner, G.; Bergfeld, T.; Bialek, J.; Lorenc, J.; Palmer, M.; Rudnick, G.; Selen, M.; Auran, T.; Boyer, V.; Honscheid, K.; Tamura, N.; Yoshimura, K.; Lu, C.; Marlow, D.; Mindas, C.; Prebys, E.; Asai, M.; Kimura, A.; Hayashi, S.

1996-01-01

Several prototypes of a Cherenkov correlated timing (CCT) detector have been tested at the KEK-PS test beam line. We describe the results for Cherenkov light yields and timing characteristics from quartz and acrylic bar prototypes. A Cherenkov angle resolution is found to be 15 mrad at a propagation distance of 100 cm with a 2 cm thick quartz bar prototype. (orig.)

Pressure solution of minerals in quartz-type buffer materials

International Nuclear Information System (INIS)

Erlstroem, M.

1986-12-01

Two samples, pure quartz sand and a sand-bentonite (10%) mixture, were tested under conditions of high pressure (200 bar) and temperature (115 0 C). The experiment was carried out over a period of 70 days. A series of thin slides were prepared on a resin embedded sample at the end of the test period. A microscopical study was performed as to obtain data concerning the effects of pressure and temperature. It showed that no pressure solution had taken place in the pure quartz sand. However, the individual grains had been severely fractured, thus causing significant internal sedimentation. The mixed sample showed that the clay component coated the quartz grains and significantly decreased the effect of stress in the grains by having a cushioning effect. Relative grain movement was facilitated by the clay, by which the grains rotated and slipped into stable positions with large contact areas and low contact stresses. This probably minimized pressure solution. However, a few contact regions indicated the presence of precipitated silica. The investigation shows no definite evidence of pressure solution after an experiment duration of 70 days. Since the effect of solution may be time dependent at the applied temperature, it is recommended that further experiments be conducted at higher effective and porewater pressures but still at 115 0 C. (orig.)

Analytical expressions for time-resolved optically stimulated luminescence experiments in quartz

International Nuclear Information System (INIS)

Pagonis, V.; Lawless, J.; Chen, R.; Chithambo, M.L.

2011-01-01

Optically stimulated luminescence (OSL) signals can be obtained using a time-resolved optical stimulation (TR-OSL) method, also known as pulsed OSL. During TR-OSL measurements, the stimulation and emission of luminescence are experimentally separated in time using short light pulses. This paper presents analytical expressions for the TR-OSL intensity observed during and after such a pulse in quartz experiments. The analytical expressions are derived using a recently published kinetic model which describes thermal quenching phenomena in quartz samples. In addition, analytical expressions are derived for the concentration of electrons in the conduction band during and after the TR-OSL pulse, and for the maximum signals attained during optical stimulation of the samples. The relevance of the model for dosimetric applications is examined, by studying the dependence of the maximum TR-OSL signals on the degree of initial trap filling, and also on the probability of electron retrapping into the dosimetric trap. Analytical expressions are derived for two characteristic times of the TR-OSL mechanism; these times are the relaxation time for electrons in the conduction band, and the corresponding relaxation time for the radiative transition within the luminescence center. The former relaxation time is found to depend on several experimental parameters, while the latter relaxation time depends only on internal parameters characteristic of the recombination center. These differences between the two relaxation times can be explained by the presence of localized and delocalized transitions in the quartz sample. The analytical expressions in this paper are shown to be equivalent to previous analytical expressions derived using a different mathematical approach. A description of thermal quenching processes in quartz based on AlO 4 - /AlO 4 defects is presented, which illustrates the connection between the different descriptions of the luminescence process found in the literature

Analytical investigations of thermoluminescence glow curve on quartz for luminescence dating

International Nuclear Information System (INIS)

Kim, K.B.; Hong, D.G.

2015-01-01

Investigations of bleaching and thermoluminescence (TL) response to radiation dose of quartz are importance in luminescence dating. Although such research has been extensively carried out for various types of quartz, most work was performed on the basis of TL intensity integrated for a particular temperature range on the glow curve, without any peak separation. In this study we investigated bleaching by a blue light stimulation and radiation dose behaviour for separated TL glow peaks of quartz, which are thermally stable, by using the computerized glow curve deconvolution (CGCD) method combined with the T_m–T_s_t_o_p method. The T_m–T_s_t_o_p method indicates that the glow curve of quartz is the superposition of at least seven components (P1–P7) in the temperature range between room temperature and 450 °C. A bleaching experiment for four thermally stable glow peaks (P4–P7) using a blue light stimulation revealed that the bleaching rate of peak P4 exhibits three different exponential decays, whereas the peaks P5, P6 and P7 are bleached with two different exponential decays. After bleaching of 12 h, the TL intensity of peaks P4, P5, P6 and P7 were reduced to approximately 6%, 16%, 26% and 68% of the initial value, respectively. Additionally, in a study of the radiation dose response of the four thermally stable glow peaks, all peaks have a similar pattern, which are well fitted by a single saturating exponential function. - Highlights: • We studied the physical characteristics of the separated TL glow peaks on quartz. • The kinetic parameters of each separated glow peak are evaluated by a CGCD method. • The separated peaks were bleached with two or three exponential decays. • The dose responses for the separated peaks showed a similar growth curve.

Retrospective dosimetry: dose evaluation using unheated and heated quartz from a radioactive waste storage building

International Nuclear Information System (INIS)

Jain, M.; Boetter-Jensen, L.; Murray, A.S.; Jungner, H.

2002-01-01

In the assessment of dose received from a nuclear accident, considerable attention has been paid to retrospective dosimetry using heated materials such as household ceramics and bricks. However, unheated materials such as mortar and concrete are more commonly found in industrial sites and particularly in nuclear installations. These materials contain natural dosemeters such as quartz, which usually is less sensitive than its heated counterpart. The potential of quartz extracted from mortar is a wall of a low-level radioactive-waste storage facility containing distributed sources of 60 Co and 13C s has been investigated. Dose-depth profiles based on small aliquots and single grains from the quartz extracted from the mortar samples are reported here. These are compared with results from heated quartz and polymineral fine grains extracted from an adjacent brick, and the integrated dose recorded by environmental TLDs. (author)

Retrospective dosimetry: Dose evaluation using unheated and heated quartz from a radioactive waste storage building

DEFF Research Database (Denmark)

Jain, M.; Bøtter-Jensen, L.; Murray, A.S.

2002-01-01

In the assessment of dose received from a nuclear accident, considerable attention has been paid to retrospective dosimetry using heated materials such as household ceramics and bricks. However, unheated materials such as mortar and concrete are more commonly found in industrial sites......-137 has been investigated. Dose-depth profiles based on small aliquots and single grains from the quartz extracted from the mortar samples are reported here. These are compared with results from heated quartz and polymineral fine grains extracted from an adjacent brick, and the integrated dose...... and particularly in nuclear installations. These materials contain natural dosemeters Such as quartz. which usually is less sensitive than its heated counterpart. The potential of quartz extracted from mortar in a wall of a low-level radioactive-waste storage facility containing distributed sources of Co-60 and Cs...

Characterisation of blue-light stimulated luminescence components in different quartz samples: Implications for dose measurement

DEFF Research Database (Denmark)

Jain, M.; Murray, A.S.; Bøtter-Jensen, L.

2003-01-01

-aliquot dose-evaluation protocols seem to be relatively free of complications when applied to quartz dominated by the fast OSL component coming from 325degreesC TL region, but this may not be true for quartz in which other components are more significant. An adequate understanding of how different OSL...... results from measurement of (a) sensitisation, (b) thermal stability, (c) recuperation, and (d) infrared response as a function of stimulation temperature from 3 different samples of sedimentary quartz selected on the basis of relative OSL contribution from different blue light stimulated linearly...

Developing Effective Separation of Feldspar and Quartz While Recycling Tailwater by HF Pretreatment

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Weiqing Wang

2018-04-01

Full Text Available The effect of hydrofluoric acid (HF pretreatment on flotation of feldspar and quartz using dodecylamine (DDA as collector was investigated by micro-flotation, zeta potential, pyrene fluorescence spectroscopy, attenuated total reflection flourier transformed infrared spectroscopy (ATR-FTIR, scanning electron microscope (SEM, X-ray photoelectron spectroscopy (XPS and bench scale flotation. The micro-flotation tests revealed that there was little difference in the flotation of feldspar and quartz at pH 2, using H2SO4 as pH regulator. After HF pretreatment, the floatability of feldspar significantly increased while the floatability of quartz showed no change. HF pretreatment resulted in leaching of SiO2 and enrichment of Na, K and Al on the feldspar surface. Consequently, the negative surface charge of feldspar increased at pH 2, which allowed for the flotation separation of the feasible minerals. This took place via an increased electrostatic adsorption between DDA and Na, K, Al on the feldspar surface, which effectively increased its hydrophobicity and as a result, improved the floatability of feldspar. An alternative process which exhibited effective separation of quartz and feldspar while recycling the tailwater from the flotation was proposed.

Optically continuous silcrete quartz cements of the St. Peter Sandstone: High precision oxygen isotope analysis by ion microprobe

Science.gov (United States)

Kelly, Jacque L.; Fu, Bin; Kita, Noriko T.; Valley, John W.

2007-08-01

A detailed oxygen isotope study of detrital quartz and authigenic quartz overgrowths from shallowly buried (ratio by laser fluorination, resulting in an average δ 18O of 10.0 ± 0.2‰ (1SD, n = 109). Twelve thin sections were analyzed by CAMECA-1280 ion microprobe (6-10 μm spot size, analytical precision better than ±0.2‰, 1SD). Detrital quartz grains have an average δ 18O of 10.0 ± 1.4‰ (1SD, n = 91) identical to the data obtained by laser fluorination. The ion microprobe data reveal true variability that is otherwise lost by homogenization of powdered samples necessary for laser fluorination. Laser fluorination uses samples that are one million times larger than the ion microprobe. Whole rock (WR) samples from the 53 rocks were analyzed by laser fluorination, giving δ 18O between 9.8‰ and 16.7‰ ( n = 110). Quartz overgrowths in thin sections from 10 rocks were analyzed by ion microprobe and average δ 18O = 29.3 ± 1.0‰ (1SD, n = 161). Given the similarity, on average, of δ 18O for all detrital quartz grains and for all quartz overgrowths, samples with higher δ 18O(WR) values can be shown to have more cement. The quartz cement in the 53 rocks, calculated by mass balance, varies from outlier at 33 vol.% cement. Eolian samples have an average of 11% cement compared to marine samples, which average 4% cement. Two models for quartz cementation have been investigated: high temperature (50-110 °C) formation from ore-forming brines related to Mississippi Valley Type (MVT) mineralization and formation as silcretes at low temperature (10-30 °C). The homogeneity of δ 18O for quartz overgrowths determined by ion microprobe rules out a systematic regional variation of temperature as predicted for MVT brines and there are no other known heating events in these sediments that were never buried to depths >1 km. The data in this study suggest that quartz overgrowths formed as silcretes in the St. Peter Sandstone from meteoric water with δ 18O values of -10

Guiding effect of bent macroscopic quartz tube for high current electron beam

International Nuclear Information System (INIS)

Zhang Mingwu; Chen Jing; Wu Yehong; Yang Bian; Wang Wei; Xue Yingli; Yu Deyang; Cai Xiaohong

2012-01-01

By using an incident electron beam with the high current and high energy, the guiding effect of the bent macroscopic quartz tube for the electron beam has been investigated. The angular distributions of outgoing electrons depending on the current and energy of incident electrons were measured. The dependences of electron transmitted fraction on energy and current of incident electrons are also shown. As the incident electron energy increasing, the electron transmitted fraction increases, but it decreases while the incident electron current increasing. The results have been compared with the present data. This work presents, the process of guiding electrons is essentially different from that of guiding highly charged ions, the guiding electron beam was caused by both elastic and inelastic collisions between electrons and inner walls of quartz tube, rather than self-organized charging effect on the surface of inner wall of quartz tube. (authors)

DISPERSION AND SORPTION CHARACTERISTICS OF URANIUM IN THE ZEOLITE-QUARTZ MIXTURE AS BACKFILL MATERIAL IN THE RADIOACTIVE WASTE REPOSITORY

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Herry Poernomo

2010-06-01

Full Text Available The experiment of sorption and dispersion characteristics of uranium in the zeolite-quartz mixture as candidate of raw material of backfill material in the radioactive waste repository has been performed. The objective is to know the effect of zeolite and quartz grain size on the zeolite-to-quartz weight ratio that gives porosity (ε, permeability (K, and dispersivity (α of uranium in the zeolite-quartz mixture as backfill material. The experiment was carried out by fixed bed method in the column filled by the zeolite-quartz mixture with zeolite-to-quartz weight percent ratio of 100/0, 80/20, 60/40, 40/60, 20/80, 0/100 wt. % in the water saturated condition flowed by uranyl nitrate solution of 500 ppm concentration (Co as uranium simulation which was leached from immobilized radioactive waste in the repository. The concentration of uranium in the effluents represented as Ct were analyzed by spectrophotometer Corning Colorimeter 253 every 15 minutes, then using Co and Ct uranium dispersivity (α in the backfill material was determined. The experiment data shown that 0.196 mm particle size of zeolite and 0.116 mm particle size of quartz on the zeolite-to-quartz weight ratio of 60/40 wt. % with ε = 0.678, K = 3.345x10-4 cm/second, and α = 0.759 cm can be proposed as candidate of raw material of backfill material in the radioactive waste repository.   Keywords: backfill material, quartz, radioactive waste, zeolite

Luminescence lifetimes in natural quartz annealed beyond its second phase inversion temperature

International Nuclear Information System (INIS)

Chithambo, M.L.

2015-01-01

The influence of annealing, irradiation dose, preheating and measurement temperature on luminescence lifetimes has been studied in quartz annealed at 1000 °C. The measurements were supplemented by studies on quartz annealed at 900 and 800 °C. Lifetimes increase with dose as well as with temperature and duration of annealing between 800 and 1000 °C. Preheating produces the same effect. The changes are accounted for in terms of hole-transfer from the non-radiative luminescence centre to and between radiative centres. The influence of measurement temperature on lifetimes depends on whether the stimulation is carried out from ambient to 200 °C or otherwise. This result is unlike that in quartz annealed at or below 500 °C where lifetimes are independent of the direction of heating. In particular, lifetimes decrease monotonically when measurements are made from 20 to 200 °C but not when recorded from 200 to 20 °C. The latter produces a pattern resembling that in quartz annealed up to 500 °C. The results are concluded as evidence of thermal effects on separate luminescence centres. In support of this, different values of the activation energy for thermal quenching were found for each supposed luminescence centre. The change of the corresponding luminescence intensity with temperature is also qualitatively consistent with this notion. - Highlights: • Luminescence lifetimes in natural quartz annealed beyond its second phase inversion temperature is reported. • Lifetimes increase with dose, annealing between 800 and 1000 °C, and preheating. • Lifetimes under stimulation temperature are affected by direction of heating. • Changes are accounted for in terms of hole-transfer luminescence centres.

U-Th-Mo mineralisation in quartz syenite from Maturigiri-Dhurakantagiri, West Garo Hills District, Meghalaya, India

International Nuclear Information System (INIS)

Basu, A.N.; Sharma, G.S.; Varma, H.M.; Dhana Raju, R.; Dougall, N.K.; Raju, B.N.V.

1987-01-01

At Maturigiri and Dhurkantagiri, mineralised coarse-grained quartz syenite bodies (up to 10x2m) occur as intrusives along the NNW-SSE trending joints in the gneissic country rock. Mineralogically, the quartz syenite is characterised by over 50 per cent K-feldspar, lesser plagioclase, quartz, mica, garnet and chlorite, together with accessory uraninite, monazite, molybdenite and pyrite. Uraninite occurs as euhedral to subhedral inclusions and mineralisation is syngenetic. Two types of monazite, Th-poor and Th-rich, are present. Molybdenite occurs as veins along fractures and appears to be of late hydrothermal origin. The mineralogical and textural features suggest that quartz syenite was formed from a residual melt of granitic magma of crustal origin. (author). 7 refs., 9 figs

OH-point defects in quartz in B- and Li-bearing systems and their application to pegmatites

Science.gov (United States)

Baron, M. A.; Stalder, R.; Konzett, J.; Hauzenberger, C. A.

2015-01-01

OH incorporation in quartz in Al-, B- and Li-bearing systems (granitic systems containing tourmaline or spodumene) was studied experimentally in order to investigate the effect of pressure, temperature and chemical impurities on the generation of OH-defects. High-pressure experiments were carried out at pressures between 5 and 25 kbar and temperatures between 800 and 900 °C, and OH-contents in quartz were calculated from IR absorption spectra measured on oriented quartz crystals. IR absorption features were assigned to impurity substitutions, such as AlOH (3,420, 3,379 and 3,315 cm-1) and BOH (3,595 cm-1), LiOH (3,483 cm-1), and hydrogarnet substitution (4H)Si defects (3,583 cm-1). Results indicate a negative correlation of incorporated Al-specific OH-defect content versus pressure (630 ± 130 wt ppm H2O at 5 kbar to 102 ± 6 wt ppm H2O at 25 kbar), but no clear correlation of B-specific OH-defects with pressure. In runs initially containing spodumene, virtually OH-free quartzes were observed at pressures ≥10 kbar, where impurity cations compensate each other forming an anhydrous eucryptite-defect component. In contrast, at 5 kbar, both Li- ad Al-specific OH-defects are observed (corresponding to 470 ± 75 wt ppm H2O). Results from this study may therefore be used to monitor formation conditions of quartz in terms of pressure and trace metal saturation of the crystallizing petrological system. IR spectra obtained from natural quartz grains from a tourmaline-bearing pegmatite exhibit B- and Al-related OH-bands. The B-related OH-band is also exhibited in quartz from a tourmaline + spodumene-bearing pegmatite. Li- and Al-related OH-bands, however, are subordinate or not observed at all in the spodumene-bearing system, which suggests that OH-vibrations do not reflect absolute Li-contents in quartz due to efficient coupled substitution involving Al. Data from experimental runs and natural specimens indicate that the B-related OH-band can be used as a rough proxy for

Manufacturing polycrystalline pellets of natural quartz for applications in thermoluminescence dosimetry

Energy Technology Data Exchange (ETDEWEB)

Carvalho Junior, Alvaro Barbosa de; Khoury, Helen Jamil [Federal University of Pernambuco (UFPE), Recife, PE (Brazil). Department of Nuclear Energy; Barros, Thiago Fernandes; Guzzo, Pedro Luiz [Federal University of Pernambuco (UFPE), Recife, PE (Brazil). Department of Mining Engineering

2012-07-15

This paper describes the manufacturing process of quartz-pellets and shows their potential use as thermoluminescence dosimeters (TLD) for those applications where low-levels of ionising radiation are present. Two batches of cold-pressed pellets were produced and their resistance were evaluated by vibration tests and weight-loss measurements. The batch manufactured with 75 Multiplication-Sign 150 Micro-Sign m particles showed enough resistance to be employed as TLD. The dosimetric properties of the 310 Degree-Sign C peak appearing in the glow curves of these pellets were characterized together with commercial TLD-100 units using {gamma}- and X-ray beams with different energies. The uncertainties related to reproducibility and stability of the TL signal were better than 10%. The sensitivity and the linearity of the TL response of quartz-pellets were better than that measured for TLD-100 for doses ranging from 0.5 to 200mGy. The energy dependence of the quartz-pellets was higher than that of TLD-100 but it cannot be considered a restriction to their use in clinical procedures and industrial applications. (author)

Saturation spectroscopy of calcium atomic vapor in hot quartz cells with cold windows

Science.gov (United States)

Vilshanskaya, E. V.; Saakyan, S. A.; Sautenkov, V. A.; Murashkin, D. A.; Zelener, B. B.; Zelener, B. V.

2018-01-01

Saturation spectroscopy of calcium atomic vapor was performed in hot quartz cells with cold windows. The Doppler-free absorption resonances with spectral width near 50 MHz were observed. For these experiments and future applications long-lived quartz cells with buffer gas were designed and made. A cooling laser for calcium magneto-optical trap will be frequency locked to the saturation resonances in the long-lived cells.

Petrology, geochemistry and LA-ICP-MS U-Pb geochronology of Paleoproterozoic basement rocks in Bangladesh: An evaluation of calc-alkaline magmatism and implication for Columbia supercontinent amalgamation

Science.gov (United States)

Hossain, Ismail; Tsunogae, Toshiaki; Tsutsumi, Yukiyasu; Takahashi, Kazuki

2018-05-01

The Paleoproterozoic (1.7 Ga) basement rocks from Maddhapara, Bangladesh show a large range of chemical variations (e.g. SiO2 = 50.7-74.7%) and include diorite, quartz diorite, monzodiorite, quartz monzonite and granite. The pluton overall displays metaluminous, calc-alkaline orogenic suite; mostly I-type suites formed within subduction-related magmatism. The observed major elements show general trends for fractional crystallization. Trace element contents also indicate the possibility of a fractionation or assimilation; explain the entire variation from diorite to monzonite, even granite. The pluton may have evolved the unique chemical features by a process that included partial melting of calc-alkaline lithologies and mixing of mantle-derived magmas, followed by fractional crystallization, and by assimilation of country rocks. The pluton shows evidence of crystal fractionation involving largely plagioclase, amphibole and possibly biotite. Some of the fractionated magmas may have mixed with more potassic melts from distinct parts of the continental lithosphere to produce granites and/or pegmatites. New geochronological results of granitic pegmatite (1722 ± 10 Ma) are indisputably consistent with diorite and tonalite and those data showing credible geochronological sequence (i.e., diorite - tonalite - granitic pegmatite). Identical Paleoproterozoic age (1.7 Ga) with distinctive magmatism of the Maddhapara basement rocks have agreeable relationship with the CITZ, India. The consistent magmatism is also common in the Transamazonian of South America, Trans-Hudson orogeny in North America, Bohemian Massif and the Svecofennian, Poland, have identified the sequential growth of the continent through the amalgamation of juvenile terrains, succeeded by a major collisional orogeny. Such Paleoproterozoic subduction-related orogens in Australia have similar counterparts in Antarctica and other part of the world. These types of Paleoproterozoic magmatism dominantly contributed

Testing the application of quartz and feldspar luminescence dating to MIS 5 Japanese marine deposits

DEFF Research Database (Denmark)

Thiel, Christine; Tsukamoto, Sumiko; Tokuyasu, Kayoko

2015-01-01

The applicability of both quartz and feldspar luminescence dating was tested on twenty-five samples from a marine succession now forming a coastal cliff at Oga Peninsula, Honshu Island, Japan. The quartz optically stimulated luminescence (OSL) signal shows thermal instability and linear modulated...

Uranium, thorium and trace elements in geologic occurrences as analogues of nuclear waste repository conditions

International Nuclear Information System (INIS)

Wollenberg, H.A.; Brookins, D.G.; Cohen, L.H.; Flexser, S.; Abashian, M.; Murphy, M.; Williams, A.E.

1984-01-01

Contact zones between intrusive rocks and tuff, basalt, salt and granitic rock were investigated as possible analogues of nuclear waste repository conditions. Results of detailed studies of contacts between quartz monzonite of Laramide age, intrusive into Precambrian gneiss, and a Tertiary monzonite-tuff contact zone indicate that uranium, thorium and other trace elements have not migrated significantly from the more radioactive instrusives into the country rock. Similar observations resulted from preliminary investigations of a rhyodacite dike cutting basalt of the Columbia River plateau and a kimberlitic dike cutting bedded salt of the Salina basin. This lack of radionuclide migration occurred in hydrologic and thermal conditions comparable to, or more severe than those expected in nuclear waste repository environments and over time periods of the order of concern for waste repositories. Attention is now directed to investigation of active hydrothermal systems in candidate repository rock types, and in this regard a preliminary set of samples has been obtained from a core hole intersecting basalt underlying the Newberry caldera, Oregon, where temperatures presently range from 100 to 265 0 C. Results of mineralogical and geochemical investigations of this core should indicate the alteration mineralogy and behavior of radioelements in conditions analogous to those in the near field of a repository in basalt

A quartz crystal microbalance dew point sensor without frequency measurement

Science.gov (United States)

Wang, Guohua; Zhang, Weishuo; Wang, Shuo; Sun, Jinglin

2014-11-01

This work deals with the design of a dew point sensor based on Quartz Crystal Microbalance (QCM) without measuring the frequency. This idea is inspired by the fact that the Colpitts oscillation circuit will stop oscillating when the QCM works in the liquid media. The quartz crystal and the electrode are designed through the finite element simulation and the stop oscillating experiment is conducted to verify the sensibility. Moreover, the measurement result is calibrated to approach the true value. At last a series of dew points at the same temperature is measured with the designed sensor. Results show that the designed dew point sensor is able to detect the dew point with the proper accuracy.

Fission track dating of authigenic quartz in red weathering crusts of carbonate rocks in Guizhou province

International Nuclear Information System (INIS)

Liu Xiuming; Wang Shijie; Zhang Feng

2004-01-01

The Cenozoic evolution history of Guizhou Province, which is located on the southeastern flank of the Qinghai-Tibet Plateau, is unclear because of the lack of sedimentation records. The red weathering crusts widespread on the Yunnan-Guizhou Plateau may bear critical information about their evolution history. This work firstly determined the ages of four red weathering crusts in eastern, central and northern Guizhou. The material used in fission track dating is well-crystallized quartz occurring in many in-situ weathering crusts of carbonate rocks. The results showed that the fission track ages of quartz vary over a wide range from 1 Ma to 25 Ma in the four profiles, significantly younger than the ages of Triassic and Cambrian parent rocks. In combination with the regionally geological evolution history during the period from 25 Ma to 1 Ma, the ages of quartz can exclude the possibility that the origin of quartz has nothing to do with primary clastic minerals in parent rocks, authigenesis during diagenesis and hydrothermal precipitation or replacement by volcanic activities. It is deduced that the well-crystallized quartz was precipitated from Si-rich weathering fluids during weathering processes of carbonate rocks. The recorded ages of quartz from the four profiles are consistent with the episodes of planation surfaces on the Qinghai-Tibet Plateau, the stages of red soil in the tropics of South China, the tectonically stable periods in Guizhou, and the ages of weathering in other parts of the world during the Cenozoic era. That is to say, the ages of authigenic quartz dated by the fission track method are well feasible and credible. (authors)

INFLUENCE OF QUARTZ CERAMICS SINGLE-STAGE PROCESSING BY GEL-FORMING WATER SOLUTIONS ON ITS STRENGTH

Directory of Open Access Journals (Sweden)

S. K. Evstropiev

2014-09-01

Full Text Available The main research results of the influence of quartz ceramics processing by silicon- and aluminum-containing gel- forming water solutions on its durability and porosity are given. Aqueous-alcoholic solutions based on tetraethoxysilane (TEOS, Si(C2H5O4 with additives of aluminum nitrate are proposed for impregnation of porous quartz ceramics samples. Ceramic samples are being impregnated with solutions at the room temperature for 12 minutes. After impregnation they are being exposed to drying at the room temperature for 24 hours and heat treatment in the electric muffle furnace. The made experiments show that impregnation of quartz ceramics porous samples by gel-forming solutions leads to durability growth of not burned samples by 6-7 times even without additional heat treatment. High-temperature heat treatment of previously impregnated ceramic samples leads to decomposition of aluminum nitrate and removal of fossils, and also to hardening of the formed additional bonds between material particles. It considerably improves strength characteristics of quartz ceramics as well. Thus, the possibility of considerable hardening of porous quartz ceramics and stability growth of its strength properties by preliminary impregnation of silicon- and aluminum-bearing gel-forming solutions even without additional heat treatment is experimentally shown. It is revealed that impregnation of porous quartz ceramic samples by these solutions leads only to insignificant reduction of porosity of samples. Subsequent heat treatment of the impregnated porous ceramic samples at the temperatures, equal to 900-1200oC, results in additional significant increase in their mechanical durability.

Neutron peak velocity measurements at the National Ignition Facility (NIF) using novel quartz detectors

Science.gov (United States)

Grim, Gary; Eckart, Mark; Hartouni, Edward; Hatarik, Robert; Moore, Alastair; Root, Jaben; Sayre, Daniel; Schlossberg, David; Waltz, Cory

2017-10-01

In mid-2017 the NIF implemented quartz based neutron time-of-flight (nToF) detectors which have a faster and narrower impulse response function (IRF) relative to traditional scintillator detectors. In this presentation we report on comparisons between fusion neutron first moments as measured by quartz and scintillator based detectors using DT layered implosions at the NIF. We report on the change in precision presaged by the quartz converter and quantify the change in both in shot, line-of-site velocity variability. as well as, shot-to-shot variation. Work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344. LLNL-ABS-734511-DRAFT.

Cathodoluminescence investigations on quartz cement in the sandstones of Khabour Formation from Iraqi Kurdistan Region, Northern Iraq

Science.gov (United States)

Omer, Muhamed F.; Friis, Henrik

2014-03-01

The Ordovician deltaic to shallow marine Khabour Formation in Northern Iraq consists mainly of sandstone with minor siltstone and interbedded shale. The sandstones are pervasively cemented by quartz that resulted in very little preserved primary porosity. Cathodoluminescence and petrographic studies showed that the silica cementation occurred in five successive phases which can be distinguished by their luminescence pattern. The precipitations of two phases have predated the major compaction process while the other phases are younger. The successive phases represent a sequence of changes in silica supply which were classified as very early and early, derived from dissolved biogenic silica that precipitated as opal/microquartz, possibly pre-compactional and of non-luminescent quartz overgrowth type. This was followed by phases whose silica supply derived from pressure solution of quartz, dissolution of feldspar, and hydrothermal fluids related to major thrust fault event. These successive quartz cement phases showed an increase in luminescence and the development of complicated zonation pattern in late-stage quartz cementation.

R and D on Radiation Hard Active Media Based on Quartz Plates

CERN Document Server

Onel, Yasar

2014-01-01

The need for radiation-hard active media in particle detectors is prominently dictated by the future colliders and the future operations of the Large Hadron Collider. The areas of implementation range from calorimetry to beamline instrumentation to specialized forward detectors e.g. luminosity monitors. In this context, we developed the idea of utilizing quartz plates with various surface coating properties as the active medium for such detectors. Plain quartz is a pure Cerenkov radiator which has quite limited photostatistics. In order to improve the efficiency of the photodetection, various methods were investigated including radiation hard wavelength shifters, p-terphenyl or 4pct gallium doped zinc oxide. The readout options include direct coupling of the photodetector to the quartz plate, or fibers. We have studied various geometries and readout options and constructed calorimeter prototypes. Here we report on the results of the previous tests, and the recent developments, which enable several factors of ...

Characterization of hydrothermal green quartz produced by gamma radiation

Energy Technology Data Exchange (ETDEWEB)

Enokihara, Cyro T.; Rela, Paulo R., E-mail: cteiti@ipen.br, E-mail: prela06@yahoo.com.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Schultz-Güttler, Rainer A., E-mail: rainersgut@gmail.com [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto de Geociencias

2015-07-01

A specific variety of quartz showing a green color in nature or induced artificially by radiation gamma ({sup 60}Co) is quite rare. Only two occurrences are known today, where this type of quartz can be found: Canada, at the Thunder Bay Amethyst Mine, Ontario and Brazil, at widely scattered geode occurrences along a 600 km stretch from Quarai at Brazils southern most tip to Uberlandia in Minas Gerais. These two occurrences have been formed by strong hydrothermal activities.That way much quartz crystals showed a very fast growth history facilitating the formation of growth defects (twinning, small angle tilting, mosaic growth, striations) and the uptake of water in form of micro inclusions, molecular water, silanol (Si-OH) and OH. In the present work the material analyzed is from hydrothermal regimes found in intrusions of basaltic rocks located in the Rio Grande do Sul state. To characterize these materials, colored green by gamma rays, analyses by ICP, electron microscopy, water loss techniques and UV-VIS or NIR-FTIR spectroscopic measurements have been made. Silanol complexes are formed, which by radiation due to gamma rays form the color center NBOHC (Non-bonding Oxygen Hole Center), showing absorption between 590 to 620 nm, responsible for the green color. The water content with up to 3200 ppm by weight exceeds the amount of charge balancing cations (Fe, Al, Li). There is no correlation between water content and cations as in other color varieties. (author)

Quartz exposure, retention, and early silicosis in sheep.

Science.gov (United States)

Bégin, R; Dufresne, A; Cantin, A; Possmayer, F; Sébastien, P; Fabi, D; Bilodeau, G; Martel, M; Bisson, D; Pietrowski, B

1989-05-01

The purposes of this study were (1) to investigate the chronology of events in cellular and biochemical changes thought to be important in the development of silicosis, (2) to relate these to changes in lung function and radiograph, and (3) to evaluate the relation of quartz exposure and retention to individual response leading to early silicosis. Thirty-six sheep were exposed by repeated intratracheal infusion at 10-day intervals to 100 mg Minusil-5 in 100 ml saline (Si group), and 10 sheep were exposed at the same intervals to 100 ml saline (control). All sheep were investigated at 3-month intervals by chest radiograph, lung function, and lung lavage. At month 9, chest radiograph score of parenchymal opacities was significantly increased at 2.8 +/- 0.6 versus 0.4 +/- 0.4 in the Si group (p less than .05), establishing early radiologic silicosis. Lung function was significantly altered with reduction in lung compliance, vital capacity, and diffusion capacity (p less than .05). Lung lavage cellularity revealed significant increase in total cells (X 2.5), macrophages (X3), and neutrophils (X3). Albumin in BAL remained at the control level. Fibronectin production was significantly increased, as was the fibroblast growth activity, without significant change in procollagen 3 at this early stage of disease. Total phospholipids were significantly elevated in the Si-exposed sheep, and the profile demonstrated an increase in all the phospholipid components. Spontaneous release of hydrogen peroxide by alveolar cells was not increased, but in the presence of phorbol myristate acetate (PMA) higher levels of peroxide were found in the quartz-exposed sheep (p less than .05). The cellular and biochemical alterations of lung lavage preceded other changes. At month 12, there were good correlations (r greater than .49, p less than .001) between parameters evaluating related phenomena but poor correlations between measurements evaluating different aspects of the disorder. To

Study of radiation-induced paramagnetic centers in quartz and its possible use in radiation dosimetry

International Nuclear Information System (INIS)

Mansour, A.M.E.

2008-01-01

A new EPR dosimetry system has been developed based on the radiation-formed stable paramagnetic centers in quartz. The first part of the thesis includes the preparation of quartz rods (diameter = 3 mm, length = 10 mm) where quartz powder was mixed with molten mixture of paraffin wax and ethylene vinyl acetate copolymer (EVA). The binding-mixture EVA / paraffin do not present interference or noise in the EPR signal before or after irradiation to high doses. The quartz rods were prepared by different concentrations (5, 10, 20, 30 and 50 %). The rods (30 %) show good mechanical properties for safe and multi-use handling. The second part is concerned with studying the dosimetric characteristics of gamma irradiation sensitive rods where the radiation-formed stable free radicals (E-center, peroxy radical and non-bridging oxygen hole center) which analyzed by using electron paramagnetic resonance (EPR) spectrometer. Unirradiated rods have no EPR signals. The useful dose range of these rods was found to range from 0.1 to 80 kGy depending on concentration of quartz powder, indicating their suitability for low and high dose gamma radiation applications. Also it was found that quartz rod exhibits a linear dose response in the dose regions 0.1-2.34 and 2.34-26 kGy at optimum EPR parameters. The dosimeter response was assessed using the peak-to-peak amplitude of the first-derivatives EPR spectrum. Its EPR signal was found unchanged in shape with different doses and different concentrations. A signal line spectrum attributed to the E-center was observed after irradiation, and this radical is insensitive to temperature, light independence as well as it have a very low decay (4.768 % per year). The overall uncertainty for quartz rod dosimeters at 2σ (σ is standard deviation) was found to be 3.8436 %. The dosimetric parameters, e. g. dose response, effect of temperature during irradiation on response as well as pre- and post-irradiation stability at different storage conditions

Understanding optically stimulated charge movement in quartz and feldspar using time-resolved measurements

DEFF Research Database (Denmark)

Ankjærgaard, Christina

. Although, results are only presented for some quartz and feldspar samples, they were found to be very similar within the each group during the course of this work.Thermoluminescence (TL) and optically stimulated luminescence (OSL) from quartz and feldspar are widely used in accident dosimetry...... stimulation energy. The thesis first delves into three main methodological developments, namely (i) research and development of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration...... of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration for the best separation of quartz OSL from a mixed quarts-feldspar sample. It then proceeds to study the different charge transport...

Hydrothermal alteration at Roosevelt Hot Springs KGRA: DDH 1976-1

Energy Technology Data Exchange (ETDEWEB)

Bryant, N.L.; Parry, W.T.

1977-09-01

Hot waters of the Roosevelt Thermal Area, Utah, have altered granitic rocks and detritus of the Mineral Range pluton, Utah. Alteration and mineral deposition recognized in a 200' drill core from DDH 1-76 is most intense in the upper 100 feet which consists of altered alluvium and opal deposits; the lower 100 feet is weakly altered quartz monzonite. Petrographic, x-ray, and chemical methods were used to characterize systematic changes in chemistry and mineralogy. Comparison of the alteration mineral assemblages with known water chemistry and equilibrium activity diagrams suggests that a simple solution equilibrium model cannot account for the alteration. A model is proposed in which upward moving thermal water supersaturated with respect to quartz and a downward moving cool water undersaturated with respect to quartz produces the observed alteration. An estimate of the heat flow contributions from hydrothermal alteration was made by calculating reaction enthalpies for alteration reactions at each depth. The estimated heat flow varied from .02 HFU (for 200' depth, 400,000 yr duration, and no sulfur oxidation) to 67 HFU (for 5,000' depth, 1,000 yr duration, and all sulfur oxidized from sulfide). Heat flow contributions from hydrothermal alteration are comparable with those from a cooling granitic magma.

Adsorption of bis(2-hydroxy-3-chloropropyl) dodecylamine on quartz surface and its implication on flotation

Science.gov (United States)

Liu, Wengang; Liu, Wenbao; Dai, Shujuan; Wang, Benying

2018-06-01

In order to clarify the effect of polar group modification on flotation performance of amine collector, flotation properties of quartz and hematite using bis(2-hydroxy-3-chloropropyl) dodecylamine (N23) as a collector were investigated. And the adsorption mechanism of N23 on quartz surface was established by zeta potential measurements, SEM/EDS measurements, and molecular structure analysis. Single mineral flotation results indicated that N23 showed stronger collecting ability on quartz and hematite than DDA-CH3COOH. However, starch could depress the flotation of hematite. Flotation recovery of 98.10% for quartz could be achieved, when N23 concentration was 43.33 mg/L and starch concentration was 16.67 mg/L at natural slurry pH. Separation of artificially mixed minerals of hematite and quartz was achieved effectively using N23 as the collector. The optimized separation result with 66.29% iron grade and 90.06% iron recovery in concentrate was obtained when slurry pH was 7.34 with 43.33 mg/L N23 and 23.33 mg/L starch. The interaction energies of N23 with mineral surface also showed well consistency with flotation results. SEM/EDS analyses and zeta potential measurements revealed that N23 could absorb on quartz surface in the forms of strong electrostatic and hydrogen bonding interaction. Compared with DDA, N23 had a higher HLB value and better water-solubility, which resulted in better dispersion in water and stronger adsorption on mineral surface.

ESR signals in quartz for the studies of earth surface processes

Science.gov (United States)

Toyoda, S.; Shimada, A., , Dr; Takada, M.

2017-12-01

Various ESR (electron spin resonance) signals are observed in quartz. As they are formed by natural radiation, the signals are useful in dating of geological events, such as volcanic eruption, faulting and sedimentation. It was also found that those paramagnetic defects can be fingerprints of sediments, to be used for studies in sediment provenance. The signal of the E1' center, unpaired electron at an oxygen vacancy, was first used for such studies. A method was proposed to estimate the number of the precursors (oxygen vacancies) from the E1' center intensity. The number of oxygen vacancies in quartz was found to have positive correlation with the crystallization age. Using this feature, studies were quite successful in aeolian dust. It was shown that the sources of aeolian dust deposited in northern part of Japanese Islands were different between in MIS1 and MIS 2. In combination with crystallinity index, the contributions of the dust components from three origins were quantitatively obtained. After these, the provenance studies on river sediments have started where the impurity centers in quartz were employed, which are the Al center, the Ti centers, and the Ge centers. Sediments of Kizu River, Mie to Nara prefectures in Central Japan are most extensively studied. Firstly, it was shown that each of possible sources of granitic quartz around the reaches has respective characteristics in the number of oxygen vacancies and the signal intensities of impurity centers. Secondary, by the artificial mixing experiments, the impurity signal intensities have the values consistent with the mixing ratio of the two samples of quartz with different intensities. At river junctions, the mixing ratios were calculated from the ESR signals. At some locations, the mixing ratio values obtained from one signal were consistent with the ones from another signal while at some locations they were not. The latter inconsistent results would indicate that the river sediments are

Optically stimulated luminescence from quartz measured using the linear modulation technique

International Nuclear Information System (INIS)

Bulur, E.; Boetter-Jensen, L.; Murray, A.S.

2000-01-01

The optically stimulated luminescence (OSL) from heated natural quartz has been investigated using the linear modulation technique (LMT), in which the excitation light intensity is increased linearly during stimulation. In contrast to conventional stimulation, which usually produces a monotonically decreasing signal, linearly increasing the stimulation power gives peaks in the signal as a function of time. In cases where the OSL signal contains more than one component, the linear increase in power of the stimulation light may result in a curve containing overlapping peaks, where the most easily stimulated component occurs at a shorter time. This allows the separation of the overlapping OSL components, which are assumed to originate from different traps. The LM-OSL curve from quartz shows an initial peak followed by a broad one. Deconvolution using curve fitting has shown that the composite OSL curve from quartz can be approximated well by using a linear combination of first-order peaks. In addition to the three known components, i.e. fast, medium and slow components from continuous-wave-OSL studies, an additional slow component is also identified for the first time. The dose responses and thermal stabilities of the various components are also studied

Surface complexation modelling: Experiments on the sorption of nickel on quartz

International Nuclear Information System (INIS)

Puukko, E.; Hakanen, M.

1995-10-01

Assessing the safety of a final repository for nuclear wastes requires knowledge concerning the way in which the radionuclides released are retarded in the geosphere. The aim of the work is to aquire knowledge of empirical methods repeating the experiments on the sorption of nickel on quartz described in the reports published by the British Geological Survey (BGS). The experimental results were modelled with computer models at the Technical Research Centre of Finland (VTT Chemical Technology). The results showed that the experimental knowledge of the sorption of Ni on quartz have been acheved by repeating the experiments of BGS. Experiments made with the two quartz types, Min-U-Sil 5 (MUS) and Nilsiae, showed the difference in sorption of Ni in the low ionic strength solution (0.001 M NaNO 3 ). The sorption of Ni on MUS was higher than predicted by the Surface Complexation Model (SCM). The phenomenon was also observed by the BGS, and may be due to the different amounts of inpurities in the MUS and in the NLS. In other respects, the results of the sorption experiments fitted quite well with those predicted by the SCM model. (8 refs., 8 figs., 11 tabs.)

Surface Textural Analysis of Quartz Grains from Modern Point Bar Deposits in Lower Reaches of the Yellow River

Science.gov (United States)

Cheng, Yong; Liu, Cong; Lu, Ping; Zhang, Yu; Nie, Qi; Wen, Yiming

2018-01-01

The surfaces of quartz grains contain characteristic textures formed during the process of transport, due to their stable physical and chemical properties. The surface textures include the information about source area, transporting force, sedimentary environment and evolution history of sediment. Surface textures of quartz grains from modern point bar deposits in the lower reaches of the Yellow River are observed and studied by scanning electron microscopy (SEM). Results indicate that there are 22 kinds of surface textures. The overall surface morphology of quartz grains shows short transporting time and distance and weak abrasive action of the river water. The combined surface textures caused by mechanical action indicate that quartz grains are transporting in a high-energy hydrodynamic condition and suffer a strong mechanical impact and abrasion. The common solution pits prove that the chemical property of transportation medium is very active and quartz grains receive an obvious chemical action. The combination of these surface textures can be an identification mark of fluvial environment, and that is: quartz grains are main subangular outline, whose roundness is higher with the farther motion distance; Surface fluctuation degree of quartz grains is relatively high, and gives priority to high and medium relief; V-shaped percussion marks are very abundant caused by mechanical action; The conchoidal of different sizes and steps are common-developed with paragenesis relationship; Solution pits are common-developed as well. The study makes up for the blank of surface textures analysis of quartz grains from modern fluvial deposits in China. It provides new ideas and evidence for studies of the sedimentary process and environmental significance, although the deep meanings of these micro textures remain to be further researched.

Detection of Molecular Oxygen at Low Concentrations Using Quartz Enhanced Photoacoustic Spectroscopy

Directory of Open Access Journals (Sweden)

Andreas Pohlkötter

2010-09-01

Full Text Available Molecular oxygen is detected at low concentrations using photoacoustic spectroscopy despite its unfavorable photoacoustic properties. The system consists of a seed laser diode, a tapered amplifier and a quartz tuning fork based spectrophone, thus employing quartz enhanced photoacoustic spectroscopy (QEPAS. With this system a detection limit of 13 ppm is reached with a compact and long term stable setup. Further improvement of the detection limit is possible by adding suitable gases to the sample gas that promote the radiationless de-excitation of the oxygen molecules.

Molecular dynamics simulation of siderite-hematite-quartz flotation with sodium oleate

Science.gov (United States)

Li, Lixia; Hao, Haiqing; Yuan, Zhitao; Liu, Jiongtian

2017-10-01

Models of sodium oleate adsorption on siderite, hematite and quartz were investigated by molecular dynamic simulation, respectively. Surface energy was calculated to confirm the cleavage plan of hematite and quartz. Both natural cleavage plane of siderite and calculated plane were used to investigate the flotation of the three minerals. Based on the molecular simulation in solution with water as medium, adsorption quantity and interaction capability of oleate ions on the three minerals indicated that siderite could be collected efficiently by sodium oleate at neutral pH. Results of flotation experiments were further demonstrated by analysis of relative concentration of carbon atoms and oxygen atoms.

Electron spin resonance of Fe4+ in amethyst quartz

International Nuclear Information System (INIS)

Cox, R.T.

1975-01-01

The ESR spectrum of Fe 4+ was looked for in amethyst quartz. Besides saturated Fe 3+ lines, ESR lines of a new paramagnetic center whose spin-lattice relaxation time is relatively short were observed. They could be attributed to Fe 4+ [fr

Devonian alkaline magmatic belt along the northern margin of the North China Block: Petrogenesis and tectonic implications

Science.gov (United States)

Zhang, Qi-Qi; Zhang, Shuan-Hong; Zhao, Yue; Liu, Jian-Min

2018-03-01

Some Devonian magmatic rocks have been identified from the northern margin of the North China Block (NCB) in recent years. However, their petrogenesis and tectonic setting are still highly controversial. Here we present new geochronological, Sr-Nd-Hf isotopic and whole-rock chemical data on several newly identified and previously reported Devonian alkaline complexes, including mafic-ultramafic rocks (pyroxenites and gabbros), alkaline rocks (syenites, monzonites) and alkaline granites in the northern NCB. We firstly identified some mafic-ultramafic rocks coeval with monzonite and quartz monzonite in the Sandaogou and Wulanhada alkaline intrusions. New zircon U-Pb dating of 16 samples from the Baicaigou, Gaojiacun, Sandaogou, Wulanhada and Chifeng alkaline intrusions combined with previous geochronological results indicate that the Devonian alkaline rocks emplaced during the early-middle Devonian at around 400-380 Ma and constitute an E-W-trending alkaline magmatic belt that extend ca. 900 km long along the northern margin of the NCB. Whole-rock geochemical and Sr-Nd-Hf isotopic data reveal that the Devonian alkaline rocks were mainly originated from partial melting of a variably enriched lithospheric mantle with different involvement of ancient lower crustal component and fractional crystallization. The Devonian alkaline magmatic belt rocks in the northern NCB are characterized by very weak or no deformations and were most likely related to post-collision extension after arc-continent collision between the Bainaimiao island arc and the northern margin of North China Craton during the latest Silurian. Partial melting of subcontinental lithospheric mantle to produce the Devonian alkaline magmatic rocks suggests that the northern North China Craton has an inhomogeneous, variably enriched subcontinental lithospheric mantle and was characterized by significant vertical crustal growth during the Devonian period.

Shock pressure estimation in basement rocks of the Chicxulub impact crater using cathodoluminescence spectroscopy of quartz

Science.gov (United States)

Tomioka, N.; Tani, R.; Kayama, M.; Chang, Y.; Nishido, H.; Kaushik, D.; Rae, A.; Ferrière, L.; Gulick, S. P. S.; Morgan, J. V.

2017-12-01

The Chicxulub impact structure, located in the northern Yucatan Peninsula, Mexico, was drilled by the joint IODP-ICDP Expedition 364 in April-May 2016. This expedition is the first attempt to obtain materials from the topographic peak ring within the crater previously identified by seismic imaging. A continuous core was successfully recovered from the peak ring at depths between 505.7 and 1334.7 mbsf. Uplifted, fractured, and shocked granitic basement rocks forming the peak ring were found below, in the impact breccia and impact melt rock unit (747.0-1334.7 mbsf; Morgan et al. 2016). In order to constrain impact crater formation, we investigated shock pressure distribution in the peak-ring basement rocks. Thin sections of the granitic rocks were prepared at intervals of 60 m. All the samples contains shocked minerals, with quartz grains frequently showing planar deformation features (PDFs). We determined shock pressures based on the cathodoluminescence (CL) spectroscopy of quartz. The strong advantage of the CL method is its applicability to shock pressure estimation for individual grains for both quartz and diaplectic SiO2 glass with high-spatial resolution ( 1 μm) (Chang et al. 2016). CL spectra of quartz shows a blue emission band caused by shock-induced defect centers, where its intensity increases with shock pressure. A total of 108 quartz grains in ten thin sections were analyzed using a scanning electron microscope with a CL spectrometer attached (an acceleration voltage of 15 kV and a beam current of 2 nA were used). Natural quartz single crystals, which were experimentally shocked at 0-30 GPa, were used for pressure calibration. CL spectra of all the quartz grains in the basement rocks showed broad blue emission band at the wavelength range of 300-500 nm and estimated shock pressures were in the range of 15-20 GPa. The result is consistent with values obtained from PDFs analysis in quartz using the universal stage (Ferrière et al. 2017; Rae et al. 2017

Distillation of shale and the like. [quartz catalyst

Energy Technology Data Exchange (ETDEWEB)

Copp, E R

1937-03-25

To recover vapourizable contents from materials by low temperature distillation, the material is passed slowly through an externally heated retort containing natural quartz as a catalyzing agent and gas preheated to its critical temperature is supplied into the retort, the evolved vapours being educted and condensed. A longitudinal retort enlarging upwardly from its inlet to its outlet and containing natural quartz on supporting shelves suspended at requisite heights by means of hangers, has a furnace mounted on girders within a tank which forms a liquid seal for the retort chamber. A heating space is supplied with heating gas through pipes to externally heat the retort chamber which is heated internally by means of preheated gas admitted through branch pipes. Material is fed by screw conveyor through passage and spreader plate on to endless conveyor moving slowly along the retort floor, and is discharged through a chamber and conveyor. The vapours evolved in the retort chamber, after passing in contact with a catalyst are educted through an exit port to a condenser.

Refractometry characteristics of {alpha}-quartz after neutron irradiation; Refraktometrichaskie kharakteristiki {alpha}-kvartsa posle oblucheniya nejtronami

Energy Technology Data Exchange (ETDEWEB)

Abdkadyrova, I Kh [AN RU, Tashkent (Uzbekistan). Inst. Yadernoj Fiziki

1997-02-01

Lattice structure distortions in irradiated crystalline quartz were studied by refractometry methods. The refractometry constants of {alpha}-quartz for the flux of fast neutrons 10{sup 18} - 10{sup 21} neutron/cm{sup 2} were calculated. The critical kinetics of this constants at the phase transformation is observed.(author). 5 refs., 1 fig.

Application of pulsed OSL to the separation of the luminescence components from a mixed quartz/feldspar sample

International Nuclear Information System (INIS)

Denby, P.M.; Botter-Jensen, L.; Murray, A.S.; Thomsen, K.J.; Moska, P.

2006-01-01

It is known that the pulsed optically stimulated luminescence (OSL) characteristics of quartz and feldspars are very different. These differences can be used to preferentially discriminate against the feldspar signal in mixed quartz-bar feldspar mineral assemblages, or in separated quartz contaminated with a feldspar signal. We have developed instrumentation for the study of high-speed pulse stimulated OSL. Our system uses the standard blue/IR LED stimulation unit of a Riso reader (allowing stimulation pulses down to 1-2μs duration) and can thus be applied to the routine analysis of samples. Using this stimulation source, and high-speed photon timing, the OSL yield can be monitored throughout the pulsing cycle and subsequent OSL decay. It is found that the total photon yield per unit stimulation power in pulsed mode is, for quartz, twice and, for feldspar, nearly four times, that in continuous wave mode. Observation of this OSL signal, between stimulation pulses, is seen to be characteristic of the mineral being examined, and has been used to preferentially discriminate against feldspar contamination in a mixed quartz/feldspar sample. Simple implementation of this technique by gating the counting period, so that counts are only accumulated during a windowed period, reduces the feldspar signal to 1.6% of its original value relative to that of the quartz

Quartz-Containing Ceramic Dusts: In vitro screening of the cytotoxic, genotoxic and pro-inflammatory potential of 5 factory samples

Energy Technology Data Exchange (ETDEWEB)

Ziemann, C; Creutzenberg, O [Fraunhofer Institute of Toxicology and Experimental Medicine, Hannover (Germany); Jackson, P [CERAM Research Ltd., Stoke-on-Trent (United Kingdom); Brown, R [TOXSERVICES, Stretton (United Kingdom); Attik, G; Rihn, B H, E-mail: christina.ziemann@item.fraunhofer.d [Nancy-University, Faculte de Pharmacie, Nancy (France)

2009-02-01

Inhalation of some respirable crystalline silica (MMAD < approx. 4 mum) leads to inflammatory and malignant diseases. Comprehensive physicochemical/biological data and suitable in vitro/in vivo methods may distinguish between more or less harmful quartz-varieties. Within the European Collective Research Project SILICERAM an in vitro screening battery was established to evaluate cytotoxicity (LDH-release, MTT-assay), genotoxicity (Comet-assay) and pro-inflammatory potential (PGE{sub 2}-liberation, TNF-a mRNA expression) of 5 respirable quartz-containing dusts from ceramic plants: brickwork (BR: 7.8% quartz), tableware granulate/cast (TG/TC: 5.8%/3.1%), tiles (TI: 8.1%), refractory (RF: 3.7%). DQ12 (87% a-quartz) and Al{sub 2}O{sub 3} were used as particulate positive and negative controls, respectively. Primary rat alveolar macrophages and the macrophage cell line NR8383 served as model systems. Aluminium lactate was used as inhibitor of biologically active silica, enabling differentiation of silica- and non-specific toxicity. At 200mug/cm{sup 2} (2h) the dusts did not alter significantly LDH-release (except TC), whereas the MTT-assay demonstrated the mainly quartz-independent rank order: DQ12>RF>TG>Ti>BR>TC>Al{sub 2}O{sub 3}. DNA-damage was maximal for BR and TI followed by DQ12>TG>TC>RF>Al{sub 2}O{sub 3}. All dusts induced PGE{sub 2}-liberation (DQ12>BR>TC>TG>Ti>RF>Al{sub 2}O{sub 3}) at 50mug/cm{sup 2} (4h), but TNF-a mRNA (10mug/cm{sup 2}, 24h) was only increased by DQ12, TG (quartz-dependently), and TC. In conclusion, these in vitro tests were an adequate approach to screen the toxic potential of quartz-containing ceramic dusts, but the quartz-content was too low to differentiate the various quartz-varieties.

Optimising the separation of quartz and feldspar optically stimulated luminescence using pulsed excitation

International Nuclear Information System (INIS)

Ankjaergaard, C.; Jain, M.; Thomsen, K.J.; Murray, A.S.

2010-01-01

In luminescence dating, the two most commonly used natural minerals, quartz and feldspar, are exposed to different dose rates in the natural environment, and so record different doses. The luminescence signals also have different stabilities. For accurate dosimetry, the signals from these two minerals must be separated, either by physical separation of the mineral grains, or by instrumental separation of the luminescence signals. The luminescence signals from quartz and feldspar have different luminescence lifetimes under pulsed optical stimulation. This difference in lifetime can be used to discriminate between the two signals from a mixed quartz-feldspar sample. The purpose of this study is to identify optimum measurement conditions for the best separation of quartz OSL from that of feldspar in a mixed sample using pulsed stimulation and time-resolved OSL. We integrate the signal from 5 μs after the LEDs are switched off until just before the LEDs are switched on again, with the pulse on-time equal to the pulse off-time of 50 μs. By using only the initial interval of the pulsed OSL decay curve (equivalent to 0.2 s of CW-OSL using blue light at 50 mW cm -2 ) we find that the quartz to feldspar pulsed OSL intensity ratio is at a maximum. By using these parameters with an additional infrared (IR) stimulation at 175 o C before measurement (to further reduce the feldspar signal intensity), we obtain a factor of 25 enhancement in signal separation compared to that from a conventional prior-IR CW measurement. This ratio can be further improved if the counting window in the pulse off-time is restricted to detect between 20 and 50 μs instead of the entire off-period.

Quartz Crystal Microbalance Coated with Sol-gel-derived Thin Films as Gas Sensor for NO Detection

Directory of Open Access Journals (Sweden)

S. J. O’Shea

2003-10-01

Full Text Available This paper presents the possibilities and properties of Indium tin oxide (ITO-covered quartz crystal as a NOx toxic gas-sensor. The starting sol-gel solution was prepared by mixing indium chloride dissolved in acetylacetone and tin chloride dissolved in ethanol (0-20% by weight. The ITO thin films were deposited on the gold electrodes of quartz crystal by spin-coating technique and subsequently followed a standard photolithography to pattern the derived films to ensure all sensors with the same sensing areas. All heat treatment processes were controlled below 500°C in order to avoid the piezoelectric characteristics degradation of quartz crystal (Quartz will lose its piezoelectricity at ~573°C due to the phase change from α to β. The electrical and structural properties of ITO thin films were characterized with Hall analysis system, TG/DTA, XRD, XPS, SEM and etc. The gas sensor had featured with ITO thin films of ~100nm as the receptor to sense the toxic gas NO and quartz crystal with frequency of 10MHz as the transducer to transfer the surface reactions (mass loading, etc into the frequency shift. A homemade setup had been employed to measure the sensor response under the static mode. The experimental results had indicated that the ITO-coated QCM had a good sensitivity for NO gas, ~12Hz/100ppm within 5mins. These results prove that the ITO-covered quartz crystals are usable as a gas sensor and as an analytical device.

Influence of cementation on the deformation properties of bentonite/quartz buffer substance

International Nuclear Information System (INIS)

Pusch, R.

1977-06-01

Cementation, e.g.precipitation of crystalline or solid amorphous inorganic substance between individual grains, greatly affects the mechanical properties of fine-grained soils. As concerns the buffer mass with the composition suggested (10 weight percent bentonite and 90% quartz particles) the intergranular contact pressure between the quartz particles will not be able to cause 'pressure solution'. Also, the other possible cementation effects will be negligible with the exception of the process which leads to precipitation of SiO 2 dissolved from quartz particles and enriched in the interstitial pore space. This process and its consequences will be treated in this report. The nature of silica solution and precipitation is not known in detail. The chemical environment, temperature, pH and ion strength are known to be controlling factors which combine to make possible alternating solution and precipitation of silica. However, as shown by the case survey and the presented theoretical treatment the amount of precipitated SiO 2 will not be able to produce a brittle behaviour of the buffer mass even after thousands of years

Triplet states at an O vacancy in alpha-quartz

DEFF Research Database (Denmark)

Lægsgaard, Jesper

2002-01-01

The energy landscape of an alpha-quartz O vacancy in the lowest triplet state is investigated. Four local minima are identified and geometries, total energies, and electron paramagnetic resonance (EPR) parameters are obtained. On the basis of calculated values for the magnetic dipole interaction...

Respirable dust and quartz exposure from three South African farms with sandy, sandy loam, and clay soils.

Science.gov (United States)

Swanepoel, Andrew J; Kromhout, Hans; Jinnah, Zubair A; Portengen, Lützen; Renton, Kevin; Gardiner, Kerry; Rees, David

2011-07-01

To quantify personal time-weighted average respirable dust and quartz exposure on a sandy, a sandy loam, and a clay soil farm in the Free State and North West provinces of South Africa and to ascertain whether soil type is a determinant of exposure to respirable quartz. Three farms, located in the Free State and North West provinces of South Africa, had their soil type confirmed as sandy, sandy loam, and clay; and, from these, a total of 298 respirable dust and respirable quartz measurements were collected between July 2006-November 2009 during periods of major farming operations. Values below the limit of detection (LOD) (22 μg · m(-3)) were estimated using multiple 'imputation'. Non-parametric tests were used to compare quartz exposure from the three different soil types. Exposure to respirable quartz occurred on all three farms with the highest individual concentration measured on the sandy soil farm (626 μg · m(-3)). Fifty-seven, 59, and 81% of the measurements on the sandy soil, sandy loam soil, and clay soil farm, respectively, exceeded the American Conference of Governmental Industrial Hygienists (ACGIH) threshold limit value (TLV) of 25 μg · m(-3). Twelve and 13% of respirable quartz concentrations exceeded 100 μg · m(-3) on the sandy soil and sandy loam soil farms, respectively, but none exceeded this level on the clay soil farm. The proportions of measurements >100 μg · m(-3) were not significantly different between the sandy and sandy loam soil farms ('prop.test'; P = 0.65), but both were significantly larger than for the clay soil farm ('prop.test'; P = 0.0001). The percentage of quartz in respirable dust was determined for all three farms using measurements > the limit of detection. Percentages ranged from 0.5 to 94.4% with no significant difference in the median quartz percentages across the three farms (Kruskal-Wallis test; P = 0.91). This study demonstrates that there is significant potential for over-exposure to respirable quartz in

Luminescence characteristics of quartz from Hsuehshan Range (Central Taiwan) and implications for thermochronometry

International Nuclear Information System (INIS)

Wu, Tzu-Shuan; Jain, Mayank; Guralnik, Benny; Murray, Andrew S.; Chen, Yue-Gau

2015-01-01

The mountain building processes in Taiwan are currently among the most rapid in the world. However, the spatial and temporal dynamics of this orogen are still poorly resolved within the <0.5 Ma timescale, reflecting methodological gaps in addressing young and rapid bedrock cooling by erosion. Optically Stimulated Luminescence (OSL) from quartz is an emerging thermochronometer that could potentially provide valuable low-temperature markers on a ∼0.1 Ma timescale. Here we study four meta-sandstone samples from the Hsuehshan Range in central Taiwan. We characterize the OSL from these samples in terms of feldspar contamination, saturation dose, signal components, and thermal stability. We conclude that the OSL is dominated by the fast component, and is therefore amenable to dose measurement using the SAR protocol. Based on the luminescence characteristics and ambient dose rate, we suggest that these samples may be valuable for evaluating recent cooling rates exceeding 360 ± 100 °C/Ma, in places where the alternative thermal scenarios (instantaneous cooling or prolonged isothermal storage) may be ruled out by external geological constraints. - Highlights: • Bedrock quartz with well-behaved luminescence characteristics are found in Taiwan. • Kinetic parameters for samples in this study are confirmed as typical quartz. • Quartz OSL-thermochronometer may work for cooling rate exceeding 360 ± 100 °C/Ma.

Isotopes and ages in the northern Peninsular Ranges batholith, southern California

Science.gov (United States)

Kistler, Ronald W.; Wooden, Joseph L.; Morton, Douglas M.

2003-01-01

Strontium, oxygen and lead isotopic and rubidium-strontium geochronologic studies have been completed on Cretaceous and Jurassic (?) granitic rock samples from the northern Peninsular Ranges batholith in southern California. Many of these samples were collected systematically and studied chemically by A. K. Baird and colleagues (Baird and others, 1979). The distribution of these granitic rocks is shown in the Santa Ana, Perris, and San Jacinto Blocks, bounded by the Malibu Coast-Cucamonga, Banning, and San Andreas fault zones, and the Pacific Ocean on the map of the Peninsular Ranges batholith and surrounding area, southern California. The granitic rock names are by Baird and Miesch (1984) who used a modal mineral classification that Bateman and others (1963) used for granitic rocks in the Sierra Nevada batholith. In this classification, granitic rocks have at least 10% quartz. Boundaries between rock types are in terms of the ratio of alkali-feldspar to total feldspar: quartz diorite, 0-10%; granodiorite, 10-35%; quartz monzonite 35-65%; granite >65%. Gabbros have 0-10% quartz. Data for samples investigated are giv in three tables: samples, longitude, latitude, specific gravity and rock type (Table 1); rubidium and strontium data for granitic rocks of the northern Peninsular Ranges batholith, southern California (Table 2); U, Th, Pb concentrations, Pb and Sr initial isotopic compositions, and δ18O permil values for granitic rocks of the northern Peninsular Ranges batholith (table 3).

Yttria coating on quartz mould inner surface for fabrication of metal fuel slug using injection casting process

International Nuclear Information System (INIS)

Vinod, A.V.; Hemanth Kumar, S.; Manivannan, A.; Muralidaran, P.; Anthonysamy, S.; Sudha, R.

2016-01-01

Quartz moulds are used for casting metal alloy of U-Zr slugs by injection casting process. Ceramic (Y_2O_3) coating on inner surface of the quartz mould is provided to avoid silica contamination in the fuel slugs during casting. Experiments were carried out to standardise the coating process and optimising various parameters such as particle size of Y_2O_3, choice of suitable binder, method for application of coating, drying and sintering at high temperature to ensure uniformity and strength of coating. Required Coating thickness of ∼40 μm was achieved on a quartz mould of inner diameter of 4.98±0.01mm. Experimental procedure for coating on inner surface of the quartz tubes using yttrium oxide is described in this work. (author)

Cathodoluminescence investigations on quartz cement in sandstones of Khabour Formation from Iraqi Kurdistan region, northern Iraq

DEFF Research Database (Denmark)

Omer, Muhamed Fakhri; Friis, Henrik

in silica supply which were classified as very early and early, derived from dissolved biogenic silica that precipitated as opal/microquartz, possibly pre-compactional and of non-luminescent quartz overgrowth type. This was followed by phases whose silica supply derived from pressure solution of quartz...

Trace Element Compositions and Defect Structures of High-Purity Quartz from the Southern Ural Region, Russia

Directory of Open Access Journals (Sweden)

Jens Götze

2017-10-01

Full Text Available Quartz samples of different origin from 10 localities in the Southern Ural region, Russia have been investigated to characterize their trace element compositions and defect structures. The analytical combination of cathodoluminescence (CL microscopy and spectroscopy, electron paramagnetic resonance (EPR spectroscopy, and trace-element analysis by inductively coupled plasma mass spectrometry (ICP-MS revealed that almost all investigated quartz samples showed very low concentrations of trace elements (cumulative concentrations of <50 ppm with <30 ppm Al and <10 ppm Ti and low abundances of paramagnetic defects, defining them economically as “high-purity” quartz (HPQ suitable for high-tech applications. EPR and CL data confirmed the low abundances of substitutional Ti and Fe, and showed Al to be the only significant trace element structurally bound in the investigated quartz samples. CL microscopy revealed a heterogeneous distribution of luminescence centres (i.e., luminescence active trace elements such as Al as well as features of deformation and recrystallization. It is suggested that healing of defects due to deformation-related recrystallization and reorganization processes of the quartz lattice during retrograde metamorphism resulted in low concentrations of CL activator and other trace elements or vacancies, and thus are the main driving processes for the formation of HPQ deposits in the investigated area.

Effect of coal mine dust and clay extracts on the biological activity of the quartz surface

Energy Technology Data Exchange (ETDEWEB)

Stone, V.; Jones, R.; Rollo, K.; Duffin, R.; Donaldson, K.; Brown, D.M. [Napier University, Edinburgh (United Kingdom). School of Life Science

2004-04-01

Modification of the quartz surface by aluminum salts and metallic iron have been shown to reduce the biological activity of quartz. This study aimed to investigate the ability of water soluble extracts of coal mine dust (CMD), low aluminum clays (hectorite and montmorillonite) and high aluminum clays (attapulgite and kaolin) to inhibit the reactivity of the quartz surface. DQ12 induced significant haemolysis of sheep erythrocytes in vitro and inflammation in vivo as indicated by increases in the total cell numbers, neutrophil cell numbers, MIP-2 protein and albumin content of bronchoalveolar lavage (BAL) fluid. Treatment of DQ12 with CMD extract prevented both haemolysis and inflammation. Extracts of the high aluminum clays (kaolin and attapulgite) prevented inhibition of DQ12 induced haemolysis, and the kaolin extract inhibited quartz driven inflammation. DQ12 induced haemolysis by coal mine dust and kaolin extract could be prevented by pre-treatment of the extracts with a cation chellator. Extracts of the low aluminum clays (montmorillonite and hectorite) did not prevent DQ12 induced haemolysis, although the hectorite extract did prevent inflammation. These results suggest that CMD, and clays both low and rich in aluminum, all contain soluble components (possibly cations) capable of masking the reactivity of the quartz surface.

Orientation of quartz nanocrystallites in the silicon lattice

International Nuclear Information System (INIS)

Kalanov, M.U.; Ibragimova, E.M.; Khamraeva, R.N.; Rustamova, V.M.; Ummatov, Kh.D.

2006-01-01

Full text: Basing on the study of medium angle diffuse X-ray scattering from silicon single crystals, it was supposed to be due to rod like oxygen precipitates. It was shown by us later, that depending on the growth conditions, as-grown silicon single crystals contain quartz crystal inclusions at an amount of 0.3 / 0.5 wt. % . Since it has not been done before, the aim of this work was to study the shape and orientation of quartz inclusions relative to a chosen axis of the silicon crystal lattice. We studied p-Si single crystals of one crucible origin with the specific resistance ρ 0 ≅ 1/10 Ohm· cm with different cut surfaces parallel to the crystal planes (100), (110) and (111). All the samples were cut and polished in the bar form with the sizes of 20x12x1.5 mm 3 . The dislocation density was N D ≅ 10 1 /10 3 cm -2 , the concentrations of oxygen and boron were N O ≅ 2/ 4 x10 17 cm -3 and N B ≅ 3· 10 1 5 c m -3 . Structure was analyzed at the set-up DRON-3M ( λ Cu K∝ = 0.1542 nm) at the room temperature in the angle range of angles 2Θ = 10/70 deg. The diffraction spectrum of the sample cut in (111) includes 5 selective reflections and the only diffuse one at 2Θ≅ 20 deg (d/n≅ 0.3136 nm), having a large width 0.1032 rad, which is due to presence of amorphous SiO x precipitate in the surface layer of silicon single crystal. The dominative selective line with d/n≅ 0.3136 nm at 2Θ≅ 28.5 deg belongs to reflection from (111) planes of the silicon lattice and the second less intensive one comes from the same planes with Cu K β radiation. Another selective reflection of a medium intensity at 2Θ≅ 59 deg with d/n≅ 0.1568 nm is its second order (222) and forbidden by the weakening laws. The rest narrow but weak lines with d/n≅ 0.3345 nm at 2Θ≅ 26.6 deg and 0.2468 nm at≅36.6 deg correspond to the diffraction reflections (101) and (110) from the crystal quartz lattice SiO 2 . It means that they are caused by optimally oriented quartz

Temperature dependence of ion-beam induced amorphization in α-quartz

International Nuclear Information System (INIS)

Dhar, Sankar; Bolse, Wolfgang; Lieb, Klaus-Peter

1999-01-01

The temperature dependence of the amorphization in α-quartz by Ne-ion bombardment has been investigated using Rutherford Backscattering Spectrometry in channeling geometry (RBS-C). The experimental results show that the critical temperature T c for inhibiting amorphization in quartz is around 940 K. The damage depth profile χ(z,phi) is independent of the temperature and fluence and can be simulated with a power-law function [χ(z,phi)∝(phiF D (z)) 3 ] of the damage energy distribution F D (z). At low irradiation temperature, the critical dose phi c for amorphization is independent of the temperature but it strongly increases at higher temperatures with an activation energy of 0.28 eV and has been explained by out-diffusion model of Morehead and Crowder

Time-resolved luminescence from quartz: An overview of contemporary developments and applications

Energy Technology Data Exchange (ETDEWEB)

Chithambo, M.L., E-mail: m.chithambo@ru.ac.za [Department of Physics and Electronics, Rhodes University, PO BOX 94, Grahamstown 6140 (South Africa); Ankjærgaard, C. [Soil Geography and Landscape Group, Wageningen University Netherlands Centre for Luminescence Dating, Droevendaalsesteeg 3, 6708 PB Wageningen, The Netherlands (Netherlands); Pagonis, V. [McDaniel College, Physics Department, Westminster, MD 21157 (United States)

2016-01-15

Time-resolved optical stimulation of luminescence has become established as a key method for measurement of optically stimulated luminescence from quartz, feldspar and α-Al{sub 2}O{sub 3}:C, all materials of interest in dosimetry. The aim of time-resolved optical stimulation is to separate in time the stimulation and emission of luminescence. The luminescence is stimulated from a sample using a brief light pulse and the emission monitored during stimulation in the presence of scattered stimulating light or after pulsing, over photomultiplier noise only. Although the use of the method in retrospective dosimetry has been somewhat limited, the technique has been successfully applied to study mechanisms in the processes leading up to luminescence emission. The main means for this has been the temperature dependence of the luminescence intensity as well as the luminescence lifetimes determined from time-resolved luminescence spectra. In this paper we review some key developments in theory and applications to quartz including methods of evaluating lifetimes, techniques of evaluating kinetic parameters using both the dependence of luminescence intensity and lifetime on measurement temperature, and of lifetimes on annealing temperature. We then provide an overview of some notable applications such as separation of quartz signals from a quartz–feldspar admixture and the utility of the dynamic throughput, a measure of luminescence measured as a function of the pulse width. The paper concludes with some suggestions of areas where further exploration would advance understanding of dynamics of luminescence in quartz and help address some outstanding problems in its application.

Density Variations in Quartz As a Key for Deciphering Impact-Related Ultrasonic Sounding (Rajlich's Hypothesis)?

Science.gov (United States)

Mestan, J.; Alvarez Polanco, E. I.

2014-12-01

Ultrasound is a form of mechanical energy with a frequency greater than ≈ 20 kHz (upper human hearing limit). It is used in many scientific as well as industrial fields. Most modern applications of ultrasound utilize sources which are either piezoelectric or magnetostrictive (Benwell et Bly 1987). A meteorite impact has been considered to be an ultrasound source during last years (Rajlich 2011). Rajlich (2014) is coming with a hypothesis that white planes made of microcavities in Bohemian quartz have their origin in an impact-related ultrasonic sounding. The Bohemian Massif has been considered to be one of the largest impact craters in whole of the world (Papagiannis et El-Baz 1988, Papagiannis 1989, Rajlich 2014). Rajlich's hypothesis implies a liquid behavior of quartz during the impact event. We state that then there have to exist planes of slightly higher density than their surroundings together with planes of microcavities. They should intersect each other without mutual influencing (as in a case of planes made of microcavities). Because physics of ultrasound during an impact event is a brand new and unknown field, we try to choose a simple way of its cognition. It is possible to take the sine wave and set 3 requirements. (1) There exist some surroundings of points of peak amplitudes. (2) These surroundings are of higher density (compression) or lower density (rarefaction) than the mean density of quartz. (3) The difference between the higher/lower and surrounding density is measurable. There was done an experimental study of Bohemian quartz using QCT bone densitometry at the Radiology Munich. Quartz with a size of ≈ 5 x 8 cm absorbed too much RTG radiation (kV 140, mAs 330), which made a picture of internal structure impossible. We propose another techniques and appeal to other scientists to face this challenge. If Bohemian quartz has a harmonically distributed density, we consider it to be a support for Rajlich's hypothesis. AcknowledgementsWe would like

Application of acoustic micro-resonators in quartz-enhanced photoacoustic spectroscopy for trace gas analysis

Science.gov (United States)

Zheng, Huadan; Dong, Lei; Wu, Hongpeng; Yin, Xukun; Xiao, Liantuan; Jia, Suotang; Curl, Robert F.; Tittel, Frank K.

2018-01-01

During the past 15 years since the first report of quartz enhanced photoacoustic spectroscopy (QEPAS), QEPAS has become one of the leading optical techniques for trace chemical gas sensing. This paper is a review of the current state-of-the art of QEPAS. QEPAS based spectrophones with different acoustic micro-resonators (AmR) configurations employing both standard quartz tuning forks (QTFs) and custom-made QTFs are summarized and discussed in detail.

Formation of quartz veins by local dissolution and transport of silica

Energy Technology Data Exchange (ETDEWEB)

Wangen, Magnus; Munz, Ingrid Anne

2004-08-01

A simple model is proposed for the (often) thick quartz veins observed in the Modum Complex in Southern Norway. The formation of these veins cannot easily be explained by silica imported by hot ascending fluids. The proposed model has dissolution in the host rock adjacent to the veins as the source for silica. The suggested process for vein formation is represented by a reaction-diffusion equation, and the process is studied in terms of a Damkoehler number. Estimates for the growth rate of quartz cement are derived. The estimates for the growth rate can be used to constrain poorly known parameters of the vein formation process, like for instance, the degree of supersaturation in the host rock. (Author)

Petrology, composition, and age of intrusive rocks associated with the Quartz Hill molybdenite deposit, southeastern Alaska.

Science.gov (United States)

Hudson, T.; Smith, James G.; Elliott, R.L.

1979-01-01

A large porphyry molybdenum deposit (Quartz Hill deposit) was recently discovered in the heart of the Coast Range batholithic complex about 70 km E of Ketchikan, SE Alaska. Intrusive rocks associated with the mineral deposit form two composite epizonal to hypabyssal stocks and many dikes in country rocks. All observed metallization and alteration is within the Quartz Hill stock. Molybdenite forms fracture coatings and occurs in veins with quartz. Alteration is widespread and includes development of secondary quartz, pyrite, K-feldspar, biotite, white mica, chlorite, and zeolite. Field relations indicate that the stocks were emplaced after regional uplift and erosion of the Coast Range batholithic complex, and K-Ar data show that intrusion and alteration took place in late Oligocene time, about 27 to 30 Ma ago. Data from the Ketchikan quadrangle indicate that porphyry molybdenum metallization in the Coast Range batholithic complex is associated with regionally extensive but spotty, middle Tertiary or younger, felsic magmatism. -from Authors

Towards dating Quaternary sediments using the quartz Violet Stimulated Luminescence (VSL) signal

DEFF Research Database (Denmark)

Ankjærgaard, C.; Jain, Mayank; Wallinga, J.

2013-01-01

Quaternary sediments using the violet (402 nm) stimulated luminescence (VSL) signal of quartz.We develop and test a new post-blue VSL single aliquot regenerative dose dating protocol, and demonstrate that the VSL signal originates from a deep trap at about 1.9 eV with a thermal lifetime of 1011 years at 10......Quartz optically stimulated luminescence (OSL) dating is widely used to determine the time of deposition and burial of Late Quaternary sediments. Application of the method is usually limited to the past 150,000 years due to early saturation of the OSL signal. Here we explore the potential to date...

Assessing rare earth elements in quartz rich geological samples.

Science.gov (United States)

Santoro, A; Thoss, V; Ribeiro Guevara, S; Urgast, D; Raab, A; Mastrolitti, S; Feldmann, J

2016-01-01

Sodium peroxide (Na2O2) fusion coupled to Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS) measurements was used to rapidly screen quartz-rich geological samples for rare earth element (REE) content. The method accuracy was checked with a geological reference material and Instrumental Neutron Activation Analysis (INAA) measurements. The used mass-mode combinations presented accurate results (only exception being (157)Gd in He gas mode) with recovery of the geological reference material QLO-1 between 80% and 98% (lower values for Lu, Nd and Sm) and in general comparable to INAA measurements. Low limits of detection for all elements were achieved, generally below 10 pg g(-1), as well as measurement repeatability below 15%. Overall, the Na2O2/ICP-MS/MS method proved to be a suitable lab-based method to quickly and accurately screen rock samples originating from quartz-rich geological areas for rare earth element content; particularly useful if checking commercial viability. Copyright © 2015 Elsevier Ltd. All rights reserved.

Direct electro-optic effect in langasites and α-quartz

Science.gov (United States)

Ivanov, Vadim

2018-05-01

Strain-constant (clamped) electro-optic coefficients r11S of langasite La3Ga5SiO14 (LGS), langatate La3Ga5.5Ta0.5O14 (LGT), catangasite Ca3TaGa3Si2O14 (CTGS) and α-quartz are measured at 1540 nm in the frequency range of 3-25 MHz. Experimental ratio of clamped and unclamped electro-optic coefficients r11S/r11T is 0.97 for LGS, 0.91 for LGT, 0.31 for CTGS, and 0.49 for quartz. Most of direct electro-optic effect in LGS and LGT is associated with lanthanum ions: clamped electro-optic coefficient r11S in lanthanum-free CTGS is 14 times less than in LGS. Low piezoelectric contribution to unclamped electro-optic coefficient r11T makes LGS and LGT promising materials for electro-optic devices, whose performance can be deteriorated by piezoelectric effect, especially, for high-voltage optical voltage sensors.

Modification of kaolinite surfaces through mechanochemical activation with quartz: A diffuse reflectance infrared fourier transform and chemometrics study.

Science.gov (United States)

Carmody, Onuma; Frost, Ray L; Kristóf, János; Kokot, Serge; Kloprogge, J Theo; Makó, Eva

2006-12-01

Studies of kaolinite surfaces are of industrial importance. One useful method for studying the changes in kaolinite surface properties is to apply chemometric analyses to the kaolinite surface infrared spectra. A comparison is made between the mechanochemical activation of Kiralyhegy kaolinites with significant amounts of natural quartz and the mechanochemical activation of Zettlitz kaolinite with added quartz. Diffuse reflectance infrared Fourier transform (DRIFT) spectra were analyzed using principal component analysis (PCA) and multi-criteria decision making (MCDM) methods, the preference ranking organization method for enrichment evaluations (PROMETHEE) and geometrical analysis for interactive assistance (GAIA). The clear discrimination of the Kiralyhegy spectral objects on the two PC scores plots (400-800 and 800-2030 cm(-1)) indicated the dominance of quartz. Importantly, no ordering of any spectral objects appeared to be related to grinding time in the PC plots of these spectral regions. Thus, neither the kaolinite nor the quartz are systematically responsive to grinding time according to the spectral criteria investigated. The third spectral region (2600-3800 cm(-1), OH vibrations), showed apparent systematic ordering of the Kiralyhegy and, to a lesser extent, Zettlitz spectral objects with grinding time. This was attributed to the effect of the natural quartz on the delamination of kaolinite and the accompanying phenomena (i.e., formation of kaolinite spheres and water). The mechanochemical activation of kaolinite and quartz, through dry grinding, results in changes to the surface structure. Different grinding times were adopted to study the rate of destruction of the kaolinite and quartz structures. This relationship (i.e., grinding time) was classified using PROMETHEE and GAIA methodology.

Blue and red thermoluminescence of natural quartz in the temperature region from -196 to 400deg. C

International Nuclear Information System (INIS)

Hashimoto, Tetsuo; Yanagawa, Yuji; Yawata, Takashi

2007-01-01

Quartz samples of three different origins were γ-irradiated with 20kGy at room temperature or at the temperature of liquid nitrogen (-196 deg. C), and analyzed by on-line TL-emission spectrometry over two temperature ranges: above 200deg. C (high-temperature region) and -196 to 200deg. C (low-temperature region). The emission spectra in the high-temperature region could be separated into intense blue TL (BTL) or red TL (RTL) properties. All quartz samples displayed more or less both properties of BTL and RTL in the low temperature region, shifting the BTL-emission spectra towards violet. Particularly, volcanically originated quartz (RTL, Medeshima) showed highly complex BTL and RTL peaks in the low-temperature region, and a stronger simple RTL peak in the high temperature. These complex glow-curve peaks are considered to reflect the presence of many crystal defects and much content of impurities in the volcanically formed quartz. In the glow-curve measurements, Brazilian quartz (quartz-vein origin) gave weak RTL and intense BTL in the low-temperature range, followed by faint emission of BTL in the high-temperature side. On the other hand, the radiation-induced colored (CC) part of a Madagascan crystal rock slice (hydrothermal origin) showed intense BTL together with slight RTL in the low temperatures, followed by strong BTL and appreciable strength of RTL in the high temperatures. The BTL-emission pattern (TL-color image) of a Madagascan slice showed a complementary relationship between irradiations at liquid-nitrogen temperature and at room temperature. To explain these radiation-induced phenomena from quartz, hydrogen radicals and Li + ions, derived from radiolysis products of OH-related impurities, could operate to eliminate the BTL centers by recombination below the room temperature

INTERFACE LAYER TO IMPROVE POLYSTYRENE ATTACHMENT ON A QUARTZ CRYSTAL RESONATOR

Directory of Open Access Journals (Sweden)

Doris Susana Llanes

Full Text Available Technologies for thin film deposition have been used to improve the functionalization of quartz crystal resonators (QCR; such technologies, for example, are spin coating and Langmuir-Blodgett (LB film preparation. These experiments are required because the film uniformity and homogeneity over the quartz crystal resonator are fundamental for its applications as chemical and biological sensors. Film deposition of polystyrene (PS particles, as well as polyvinyl chloride (PVC, was performed in solvents such as cyclohexanone, tetrahydrofuran (THF, dimethylformamide and chloroform at different concentrations using the spin coating procedure on wafer targets. The film quality was determined by optical microscopy, ellipsometry, and profilometry. Additionally, films on wafers or QCR with gold surface have been prepared by spreading the mentioned substances on an aqueous subphase and transferring it by dipping from the subphase surface onto the target. For LB film preparation arachidic acid and PS particles have been used. Prepared mono- or multilayered films of these substances on wafer or gold quartzes have been controlled additionally by IR-spectrometry. The resonant behavior of QCR before and after surface coating has been measured with a network analyzer. In combination with a graphical user interface the data could be easily recorded and visualized.

Interfacial fracture of dentin adhesively bonded to quartz-fiber reinforced composite

International Nuclear Information System (INIS)

Melo, Renata M.; Rahbar, Nima; Soboyejo, Wole

2011-01-01

The paper presents the results of an experimental study of interfacial failure in a multilayered structure consisting of a dentin/resin cement/quartz-fiber reinforced composite (FRC). Slices of dentin close to the pulp chamber were sandwiched by two half-circle discs made of a quartz-fiber reinforced composite, bonded with bonding agent (All-bond 2, BISCO, Schaumburg) and resin cement (Duo-link, BISCO, Schaumburg) to make Brazil-nut sandwich specimens for interfacial toughness testing. Interfacial fracture toughness (strain energy release rate, G) was measured as a function of mode mixity by changing loading angles from 0 deg. to 15 deg. The interfacial fracture surfaces were then examined using Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDX) to determine the failure modes when loading angles changed. A computational model was also developed to calculate the driving forces, stress intensity factors and mode mixities. Interfacial toughness increased from ∼ 1.5 to 3.2 J/m 2 when the loading angle increases from ∼ 0 to 15 deg. The hybridized dentin/cement interface appeared to be tougher than the resin cement/quartz-fiber reinforced epoxy. The Brazil-nut sandwich specimen was a suitable method to investigate the mechanical integrity of dentin/cement/FRC interfaces.

Efficacy of Argentum-Quartz Solution in the Treatment of Perianal Fistulas: A Preliminary Study

Directory of Open Access Journals (Sweden)

Tomasello Giovanni

2015-12-01

Full Text Available Abstract Background: Nowadays, an optimal and effective medical surgery remains the gold standard for perianal fistulas. Hereby we reported preliminary results in favor of using Argentum-quartz solution for both primary and recurrent perianal fistulas. Methods: Three patients with intersphincteric and extrasphincteric fistulas were enrolled. Argentum-quartz solution was administrated twice a week for a period of 4 weeks, followed by a pause of 8 days and then another 4 weeks of treatment, totally 16 administrations. After treatment, all patients were monitored for a 4-month follow-up. Results: Complete closures of 2 extrasphincteric fistulas and a partial closure with absence of inflammation and superative phenomena in the intrasphincteric fistula were both manifested. Conclusion: Selective treatment of perianal fistulas with an argentum-quartz solution is safe and effective, and may represent a reliable alternative.

Neptunium(V) sorption on quartz and albite in aqueous suspension

International Nuclear Information System (INIS)

Kohler, M.; Leckie, J.O.

1991-10-01

The behavior of neptunium in the subsurface environment is of interest since neptunium isotopes are included in nuclear waste. Previous work investigated the sorption behavior of Np onto α-Fe 2 O 3 (hematite), an accessory mineral of the Yucca Mountain repository. The work reported herein involves the much more abundant silicate minerals quartz and albite, and is a logical continuation of the ongoing task. In previous work increased sorption was observed in systems containing hematite and EDTA, a ligand which acts as a surrogate for organic complexing agents. In addition, increased partial pressures of CO 2 are common in many ground waters and the effects of carbonate on sorption of radionuclides have to be studied as well. At concentration levels of 10 -7 M, Np(V) does not adsorb strongly on quartz and albite up to pH values of approximately 9 at solid/solution ratios of 30 to 40 g/l. Significant adsorption (> 20%) occurs on both minerals only at pH > 9. Pretreatment of albite affects the sorption behavior of this mineral at pH > 9, possibly due to the formation of secondary mineral phases at the albite surface. EDTA does not adsorb on quartz at concentrations of 10 -6 M. In the presence of 50 μM EDTA, Np(V) sorption seems to be restricted. EDTA at the 10 -6 M level adsorbs onto albite to an appreciable degree at pH values 3 - is the predominant solution species

Surface chemistry and reactivity of SiO{sub 2} polymorphs: A comparative study on α-quartz and α-cristobalite

Energy Technology Data Exchange (ETDEWEB)

Tang, Cuihua [CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 511 Kehua Street, Guangzhou 510640 (China); Guangdong Provincial Key Laboratory of Mineral Physics and Materials, 511 Kehua Street, Guangzhou 510640 (China); University of Chinese Academy of Sciences, 19 Yuquan Road, Beijing 100049 (China); Zhu, Jianxi, E-mail: zhujx@gig.ac.cn [CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 511 Kehua Street, Guangzhou 510640 (China); Guangdong Provincial Key Laboratory of Mineral Physics and Materials, 511 Kehua Street, Guangzhou 510640 (China); Li, Zhaohui [Geosciences Department, University of Wisconsin – Parkside, Kenosha, WI 53141 (United States); Zhu, Runliang [CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 511 Kehua Street, Guangzhou 510640 (China); Guangdong Provincial Key Laboratory of Mineral Physics and Materials, 511 Kehua Street, Guangzhou 510640 (China); Zhou, Qing [CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 511 Kehua Street, Guangzhou 510640 (China); Guangdong Provincial Key Laboratory of Mineral Physics and Materials, 511 Kehua Street, Guangzhou 510640 (China); University of Chinese Academy of Sciences, 19 Yuquan Road, Beijing 100049 (China); Wei, Jingming; He, Hongping; Tao, Qi [CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 511 Kehua Street, Guangzhou 510640 (China); Guangdong Provincial Key Laboratory of Mineral Physics and Materials, 511 Kehua Street, Guangzhou 510640 (China)

2015-11-15

Highlights: • The surface site density of α-quartz was higher than that of α-cristobalite. • The capacity of proton-donating by α-quartz was stronger than that by α-cristobalite. • The surface heterogeneity of α-quartz and α-cristobalite resulted in their different responses to solution pH. • Adsorption of methylene blue (MB) was spontaneous and endothermic. • The higher ΔH for α-quartz accounted for a larger tilt angle of MB on its surface. - Abstract: Silica minerals are widely used in environmental remediation for their prevalence in soil and sediment. Two common SiO{sub 2} polymorphs, α-quartz and α-cristobalite, were investigated for the removal of a typical cationic dye, methylene blue (MB), from aqueous solutions. Their adsorption behaviors were studied in batch experiments as a function of specific surface area (SSA), pH, and temperature. The surface site density of α-quartz (10.6 sites/nm{sup 2}) was higher than that of α-cristobalite (6.2 sites/nm{sup 2}) with the Gran plot method, and the adsorption maxima of MB on the two were 0.84 mg/m{sup 2} and 0.49 mg/m{sup 2}, respectively, at 303 K and pH 8. The potentiometric titration showed the capacity of proton-donating by α-quartz was stronger than that by α-cristobalite. A drastic increase of adsorption amount on α-quartz at pH < 3 was caused by its greater quantity of isolated silanols. The negative ΔG and positive ΔH values suggested adsorption of MB on both minerals was spontaneous and endothermic. At three different temperatures (288 K, 298 K, and 303 K), the adsorption capacities of two polymorphs increased with increasing temperature. The surface heterogeneity of α-quartz and α-cristobalite corresponds to their different adsorption behavior, and our work also provides some referential significance in evaluating the overall quality of soils and sediments.

Characteristics of the Late Devonian Tsagaan Suvarga Cu-Mo deposit, Southern Mongolia

Science.gov (United States)

Tungalag, Naidansuren; Jargalan, Sereenen; Khashgerel, Bat-Erdene; Mijiddorj, Chuluunbaatar; Kavalieris, Imants

2018-05-01

The Late Devonian Tsagaan Suvarga deposit (255 Mt at 0.55% Cu, 0.02% Mo) is located on the NW margin of the Tsagaan Suvarga Complex (TSC), which extends ENE over 15 × 10 km and comprises mainly medium-grained equigranular hornblende-biotite quartz monzonite and monzodiorite. Distinct mineralized intrusions are inferred from distribution of Cu-Mo mineralization but are not clearly discernible. The Tsagaan Suvarga Complex is a window within Carboniferous volcanic and sedimentary rocks, and wall rocks to the TSC are not known or exposed in the nearby district. Whole-rock analyses and Sr-Nd isotopes, 87Sr/86Sr0 = 0.7027 to 0.7038 (n = 12) and ɛNd0 = + 4.26 to + 2.77 (n = 12), show that the granitoids are subduction-related I-type, high K-calc-alkaline to shoshonitic series and derived from a mantle source. They exhibit fractionated light rare earth elements, without depleted Eu and depleted middle heavy rare earth elements and Y, typical of oxidized, fertile porphyry magmatic suites. Early porphyry-style quartz veins include A- and B-type. Molybdenite occurs in monomineralic veins (1-5 mm) or A veins. Copper mineralization occurs mainly as chalcopyrite and subordinate bornite, disseminated and associated with quartz-muscovite veins. Pyrite (vol%) content is less than chalcopyrite and bornite combined. Deep oxidation to about 50 m depth has formed zones of malachite and covellite in late fractures. The most important alteration is actinolite-biotite-chlorite-magnetite replacing hornblende and primary biotite. Quartz-K-feldspar alteration is minor. Late albite replaces primary K-feldspar and enhances sodic rims on plagioclase crystals. Quartz-muscovite (or sericitic alteration) overprints actinolite-biotite and porphyry-type quartz veins. Field observations and petrographic studies suggest that the bulk of the chalcopyrite-bornite mineralization at the Tsagaan Suvarga formed together with coarse muscovite alteration.

Melting and Pressure-Induced Amorphization of Quartz

OpenAIRE

Badro, James; Gillet, Philippe; Barrat, Jean-Louis

1997-01-01

It has recently been shown that amorphization and melting of ice were intimately linked. In this letter, we infer from molecular dynamics simulations on the SiO2 system that the extension of the quartz melting line in the metastable pressure-temperature domain is the pressure-induced amorphization line. It seems therefore likely that melting is the physical phenomenon responsible for pressure induced amorphization. Moreover, we show that the structure of a "pressure glass" is similar to that ...

Gamma radiation of quartz from Entre Rios (SC) and QuaraÍ (RS)

International Nuclear Information System (INIS)

Enokihara, Cyro T.; Rela, Paulo R.; Schultz-Güttler, Rainer A.

2017-01-01

The availability of gamma ray irradiators in Brazil increased the possibilities of treatments of gemstones for color enhancements. One of the minerals with a very high potential of these treatments is quartz, a very widespread mineral with many colored commercial varieties. A specific variety of quartz showing a green color in nature or induced artificially by radiation gamma ( 60 Co) is quite rare. In Brazil the widely scattered geode occurrences along a 600 km stretch from Quaraí at Brazil southernmost tip to Uberlandia in Minas Gerais is one of these. Quartz from these occurrences have been formed by strong hydrothermal activities. That way much quartz crystals showed a very fast growth history facilitating the formation of growth defects and the uptake of water in form of micro inclusions, molecular water, silanol (Si-OH) and OH. In the present work the material analyzed is from hydrothermal regimes located near the towns Entre Rios (SC) and Quaraí (RS). To characterize these materials analyses have been made by ICP, NAA, electron microscopy, water loss techniques and UV-VIS and NIR-FTIR spectroscopic measurements. Silanol complexes are found, which by radiation due to gamma rays form the color center NBOHC (Non-Bonding Oxygen Hole Center), showing absorption between 590 to 620 nm and leaving a transmission window at about 550nm, responsible for the green color. The spectroscopic water determination showed less molecular water (up to 2300 ppm by weight), probably due to remaining silanol complexes.The water content with up to 3200 ppm by weight exceeds the amount of charge balancing cations (Fe, Al, Li). (author)

Gamma radiation of quartz from Entre Rios (SC) and QuaraÍ (RS)

Energy Technology Data Exchange (ETDEWEB)

Enokihara, Cyro T.; Rela, Paulo R., E-mail: cteiti@ipen.br, E-mail: prela06@yahoo.com.br [Instituto de Pesquisas Energéticas e Nucleares (IPEN/CNEN-SP), São Paulo, SP (Brazil); Schultz-Güttler, Rainer A., E-mail: rainersgut@gmail.com [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto de Geociências

2017-07-01

The availability of gamma ray irradiators in Brazil increased the possibilities of treatments of gemstones for color enhancements. One of the minerals with a very high potential of these treatments is quartz, a very widespread mineral with many colored commercial varieties. A specific variety of quartz showing a green color in nature or induced artificially by radiation gamma ({sup 60}Co) is quite rare. In Brazil the widely scattered geode occurrences along a 600 km stretch from Quaraí at Brazil southernmost tip to Uberlandia in Minas Gerais is one of these. Quartz from these occurrences have been formed by strong hydrothermal activities. That way much quartz crystals showed a very fast growth history facilitating the formation of growth defects and the uptake of water in form of micro inclusions, molecular water, silanol (Si-OH) and OH. In the present work the material analyzed is from hydrothermal regimes located near the towns Entre Rios (SC) and Quaraí (RS). To characterize these materials analyses have been made by ICP, NAA, electron microscopy, water loss techniques and UV-VIS and NIR-FTIR spectroscopic measurements. Silanol complexes are found, which by radiation due to gamma rays form the color center NBOHC (Non-Bonding Oxygen Hole Center), showing absorption between 590 to 620 nm and leaving a transmission window at about 550nm, responsible for the green color. The spectroscopic water determination showed less molecular water (up to 2300 ppm by weight), probably due to remaining silanol complexes.The water content with up to 3200 ppm by weight exceeds the amount of charge balancing cations (Fe, Al, Li). (author)

Impurity-related point defects and gamma-radiation response of massive quartz from the Borborema pegmatite province, in Brazil

International Nuclear Information System (INIS)

Miranda, Milena Ribas de; Gonzaga, Raysa Sthefany Gomes; Guzzo, Pedro Luiz; Barreto, Sandra de Brito; Melgarejo, Joan Carles

2012-01-01

This work has investigated the changes induced by γ-radiation on impurity-related point defects in massive rose quartz from one deposit located at The Borborema Pegmatite Province (Northeast Region, in Brazil). Samples extracted from rose and colorless (milky) quartz blocks were irradiated with doses of 60 Co, from 0.5 to 96 kGy. Point defects related to Al, Ge, Li and OH were measured by optical, infrared, and electron paramagnetic resonance spectroscopy, prior and after irradiation. The contents of Al, Li, Ge, Fe, Ti and other impurities were measured by inductively-coupled plasma mass spectrometry in quartz fragments exhibiting rose, pale-rose, and milky colorations. It was found that [AlO 4 ] 0 , [AlO 4 /H] 0 and [GeO 4 /Li] 0 were generated by the dissociation of [AlO 4 /Li] 0 and [Li-OH] centers with doses as lower as 0.5 kGy. Above 8 kGy, the electron paramagnetic resonance signal related to [GeO 4 /Li] 0 decreases due to the intense mobility of Li species throughout the quartz lattice, giving rise to E' 1 centers perturbed by Ge. The increase in [AlO 4 ] 0 content with γ doses and the consequent rise in the intensity of smoky color were similar for both rose and colorless quartz. Scanning electron microscopy carried out in insoluble residues obtained after chemical dissolution of each type of quartz revealed the presence of nanometric fibers only in rose specimens. These results suggested that the cause of rose color in massive quartz from Borborema Pegmatite Province is probably related to the presence of dumortierite inclusions. (author)

Preparation of triangular and hexagonal silver nanoplates on the surface of quartz substrate

International Nuclear Information System (INIS)

Jia Huiying; Zeng Jianbo; An Jing; Song Wei; Xu Weiqing; Zhao Bing

2008-01-01

In this paper, triangular and hexagonal silver nanoplates were prepared on the surface of quartz substrate using photoreduction of silver ions in the presence of silver seeds. The obtained silver nanoplates were characterized by atomic force microscopy and UV-vis spectroscopy. It was found that the silver seeds played an important role in the formation of triangular and hexagonal silver nanoplates. By varying the irradiation time, nanoplates with different sizes and shapes could be obtained. The growth mechanism for triangular and hexagonal nanoplates prepared on quartz substrate was discussed

Occupational exposure to crystalline silica (quartz) and and prevalence of lung diseases in Dhand Killi, Mohmand Agency, northern Pakistan

International Nuclear Information System (INIS)

Jehan, N.

2005-01-01

Occupational exposure to respirable crystalline silica (quartz) has long been known to produce fatal lung diseases specifically silicosis and pulmonary tuberculosis. This issue a cohort analysis of occupational exposure, relation to crystalline silica (quartz), the mortality and morbidity rate of various lung diseases were carried out among silica miners and millers in Dhand Killi Mohamand Agency, northern Pakistan. The exposure level of respirable silica (quartz) in the indoor environment counts from 1-14 mg/m sup 3/ per 1 hour, which is thousand fold higher as compared to internationally recommended exposure limits (0.05 mg/m/sup 3) over time-weighted average of 8 hours. The mortality and morbidity rate of silica related lung diseases were found potentially high among the silica (quartz) miners and millers during the follow up period (1996 to 2004) in the target area. The overall analytical data illustrates that the cohort cases of occupational exposure to respirable silica (quartz) and silica related fatal diseases is remarkably high. (author)

Metalliferous deposits of the greater Helena mining region, Montana

Science.gov (United States)

Pardee, Joseph Thomas; Schrader, F.C.

1933-01-01

The ore deposits described in this bulletin are distributed through a region of about 3,000 square miles surrounding the city of Helena, Mont. In general the surface of this region is mountainous, but it includes several large intermontane valleys. Large areas in the northern and eastern parts of the region sire underlain by sedimentary rocks of the Algonkian Belt series, and on the northeast and southwest the Belt rocks are overlain without any noticeable angular unconformity by Paleozoic and Mesozoic beds. Oligocene, Miocene, and possibly Pliocene sediments, composed chiefly of volcanic ash and land waste of local origin, occupy large areas in the intermontane valleys and lie unconformably upon Cretaceous and older rocks. A thin veneer of Pleistocene and Recent alluvium generally overspreads the Tertiary. In the extreme northern part of the region are large deposits of glacial drift that represent two stages of the Pleistocene. The principal igneous body of the region is the northern part of the early Tertiary or late Cretaceous Boulder batholitb of quartz monzonite. The main exposure of this body occupies an area of nearly 1,200 square miles and extends southward beyond the limits of the particular region considered. Smaller areas of similar rocks are clustered around this exposure. Most of the exposures probably represent bodies that are connected in depth to form a single mass. The late Cretaceous and older sedimentary rocks are involved in a series of northwestward-trending folds. Along the east side of the region overthrust faults related to the great Lewis overthrust of Glacier National Park cause Belt rocks to overlie rocks of Paleozoic and Mesozoic ages. Large normal faults occur near Marysville and faults of moderate displacement near Helena. The Tertiary beds are slightly deformed by folds and faults that are unrelated to the structure of the older rock. The geologic history of the region includes two contrasting periods, the earlier of which was

Propagation of photons induced by a proton beam in a quartz bar

International Nuclear Information System (INIS)

Plaszczynski, S.; Torassa, E.; Wormser, G.; Aleksan, R.; Amadon, A.; Besson, P.; Bourgeois, P.; Monchenault, G.H.; Jarry, P.; Lemaire, M.C.; Lemeur, J.; London, G.; Robert, J.P.

1996-01-01

For the BABAR experiment, an amplitude and timing analysis of photons produced by a proton beam in a quartz bar has been performed. The photoelectron yield is obtained for different angles and positions. It is found that the linear speed of propagation of the Cherenkov photons through the bar is well described y internal reflections. The timing analysis reveals also the existence of an unexpected parasite light component, not described by the simulation. However, all the results can be reproduced by adding an isotropic scintillation of about 4 photons/cm in the quartz bar on the trajectory of the primary proton, in 50 % of the cases. (author)

Fabrication of quartz microcylinders by laser interference lithography for angular optical tweezers

Science.gov (United States)

Santybayeva, Zhanna; Meghit, Afaf; Desgarceaux, Rudy; Teissier, Roland; Pichot, Frederic; de Marin, Charles; Charlot, Benoit; Pedaci, Francesco

2016-07-01

The use of optical tweezers (OTs) and spin angular momentum transfer to birefringent particles allows new mechanical measurements in systems where torque and rotation are relevant parameters at the single-molecule level. There is a growing interest in developing simple, fast, and inexpensive protocols to produce a large number of submicron scale cylinders of quartz, a positive uniaxial birefringent crystal, to be employed for such angular measurements in OTs. Here, we show that laser interference lithography, a method well known for its simplicity, fulfills these requirements and produces quartz cylindrical particles that we successfully use to apply and measure optical torque in the piconewton nm range in an optical torque wrench.

Propagation of photons induced by a proton beam in a quartz bar

International Nuclear Information System (INIS)

Plaszczynski, S.; Torassa, E.; Wormser, G.; Aleksan, R.; Amadon, A.; Besson, P.; Bourgeois, P.; Monchenault, G.H.

1995-01-01

For the BABAR experiment, an amplitude and timing analysis produced by a proton beam in a quartz bar has been performed. The photoelectron yield is obtained for different angles and positions. It is found that the linear speed of propagation of the Cherenkov photons through the bar is well described by internal reflections. The timing analysis reveals also the existence of an unexpected parasite light component, not described by the simulation. However, all the results can be reproduced by adding an isotopic scintillation of about 4 photons/cm in the quartz bar on the trajectory of the primary proton, in 50 % of the cases. (authors)

Determination of the hexagonal network parameters of the quartz β using neutron multiple diffraction

International Nuclear Information System (INIS)

Campos, L.C.; Parente, C.B.R.; Mazzocchi, V.L.; Helene, O.

2000-01-01

In this work, neutron multiple diffraction is employed for the determination of the parameters a and c of the β-quartz hexagonal cell. This crystalline phase of silica (SiO 2 ) occurs in temperatures between ca. 846 and 1143 K. A β-quartz neutron multiple diffraction pattern has been used in the determinations. This pattern was obtained with a natural quartz single crystal heated to 1003 K. During the indexing of the pattern it was verified that most of the pairs of secondary reflections, which are responsible for the formation of peaks, could be classified as 'good for the determination of a' or 'good for the determination of c'. With this classification, it became possible to employ an iterative method for the determination of both parameters. After 8 cycles of iteration the values found for the parameters were a = 4.9964 +- 0.0018 and c = 5.46268 +- 0.00052 A. (author)

Quartz Crystal Temperature Sensor for MAS NMR

Science.gov (United States)

Simon, Gerald

1997-10-01

Quartz crystal temperature sensors (QCTS) were tested for the first time as wireless thermometers in NMR MAS rotors utilizing the NMR RF technique itself for exiting and receiving electro-mechanical quartz resonances. This new tool in MAS NMR has a high sensitivity, linearity, and precision. When compared to the frequently used calibration of the variable temperature in the NMR system by a solid state NMR chemical shift thermometer (CST), such as lead nitrate, QCTS shows a number of advantages. It is an inert thermometer in close contact with solid samples operating parallel to the NMR experiment. QCTS can be manufactured for any frequency to be near a NMR frequency of interest (typically 1 to 2 MHz below or above). Due to the strong response of the crystal, signal detection is possible without changing the tuning of the MAS probe. The NMR signal is not influenced due to the relative sharp crystal resonance, restricted excitation by finite pulses, high probeQvalues, and commonly used audio filters. The quadratic dependence of the temperature increase on spinning speed is the same for the QCTS and for the CST lead nitrate and is discussed in terms of frictional heat in accordance with the literature about lead nitrate and with the results of a simple rotor speed jump experiment with differently radial located lead nitrate in the rotor.

Recent Advances in Quartz Crystal Microbalance-Based Sensors

Directory of Open Access Journals (Sweden)

Sandeep Kumar Vashist

2011-01-01

Full Text Available Quartz crystal microbalance (QCM has gained exceptional importance in the fields of (biosensors, material science, environmental monitoring, and electrochemistry based on the phenomenal development in QCM-based sensing during the last two decades. This review provides an overview of recent advances made in QCM-based sensors, which have been widely employed in a plethora of applications for the detection of chemicals, biomolecules and microorganisms.

Cathodoluminescence investigations on quartz cement in the sandstones of Khabour Formation from Iraqi Kurdistan Region, Northern Iraq

DEFF Research Database (Denmark)

Omer, Muhamed Fakhri; Friis, Henrik

2014-01-01

in silica supply which were classified as very early and early, derived from dissolved biogenic silica that precipitated as opal/microquartz, possibly pre-compactional and of non-luminescent quartz overgrowth type. This was followed by phases whose silica supply derived from pressure solution of quartz...

Mineralogic and petrologic investigation of pre-test core samples from the spent fuel test-climax

International Nuclear Information System (INIS)

Ryerson, F.J.; Qualheim, B.J.

1983-12-01

Pre-test samples obtained from just inside the perimeter of the canister emplacement holes of the Spent Fuel Test-Climax have been characterized by petrographic and microanalytical techniques. The primary quartz monzonite has undergone various degrees of hydrothermal alteration as a result of natural processes. Alteration is most apparent on primary plagioclase and biotite. The most common secondary phases on plagioclase are muscovite and calcite, while the most common secondary phases on biotite are epidote and chlorite. The major alteration zones encountered are localized along filled fractures, i.e. veins. The thickness and mineralogy of the alteration zones can be correlated with the vein mineralogy, becoming wider and more complex mineralogically when the veins contain calcite. 7 references, 10 figures, 4 tables

Using quartz sand to enhance the removal efficiency of M. aeruginosa by inorganic coagulant and achieve satisfactory settling efficiency.

Science.gov (United States)

Pei, Haiyan; Jin, Yan; Xu, Hangzhou; Ma, Chunxia; Sun, Jiongming; Li, Hongmin

2017-10-19

In this study, low-cost and non-polluting quartz sand was respectively mixed with AlCl 3 , FeCl 3 and PAFC to synergistically remove Microcystis aeruginosa. Results showed that quartz sand could markedly increase the algae removal efficiency and decrease the coagulant doses. The increase of removal efficiency with AlCl 3 and FeCl 3 was only due to the enhancement of floc density by the quartz sand. However, the removal efficiency with PAFC was increased not only by the enhanced floc density, but also by the enlarged floc size. Flocs from 50 mg/L sand addition were larger than that with other sand doses, which was on account of the appropriate enhancement of collision efficiency at this dose. After coagulation, the extracellular organic matter (EOM) and microcystins (MCs) in system with quartz sand was remarkably reduced. That's because quartz sand can enhance the coagulation so as to improve capping the EOM and MCs in flocs during coagulation process. Owing to 200 mg/L quartz sand could damage the cell's membrane during coagulation proces, algal cells in the system lysed two days earlier than with 50 mg/L sand during flocs storage. In addition, cells with PAFC incurred relatively moderate cellular oxidative damage and could remain intact for longer time.

Fluid Inclusion Study of Quartz Xenocrysts in Mafic Dykes from Kawant Area, Chhota Udaipur District, Gujarat, India

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Randive Kirtikumar

2015-09-01

Full Text Available Unusual mafic dykes occur in the proximity of the Ambadongar Carbonatite Complex, Lower Narmada Valley, Gujarat, India. The dykes contain dense population of quartz xenocrysts within the basaltic matrix metasomatised by carbonate-rich fluids. Plagioclase feldspars, relict pyroxenes, chlorite, barite, rutile, magnetite, Fe-Ti oxides and glass were identified in the basaltic matrix. Quartz xenocrysts occur in various shapes and sizes and form an intricate growth pattern with carbonates. The xenocrysts are fractured and contain several types of primary and secondary, single phase and two-phase fluid inclusions. The two-phase inclusions are dominated by aqueous liquid, whereas the monophase inclusions are composed of carbonic gas and the aqueous inclusions homogenize to liquid between 226°C and 361°C. Majority of the inclusions are secondary in origin and are therefore unrelated to the crystallization of quartz. Moreover, the inclusions have mixed carbonic-aqueous compositions that inhibit their direct correlation with the crustal or mantle fluids. The composition of dilute CO2-rich fluids observed in the quartz xenocrysts appear similar to those exsolved during the final stages of evolution of the Amba Dongar carbonatites. However, the carbonates are devoid of fluid inclusions and therefore their genetic relation with the quartz xenocrysts cannot be established.

Luminescence property of volcanic quartz and the use of red isothermal TL for dating tephras

International Nuclear Information System (INIS)

Tsukamoto, S.; Murray, A.S.; Huot, S.; Watanuki, T.; Denby, P.M.; Botter-Jensen, L.

2007-01-01

An optically stimulated luminescence (OSL) age obtained from a Japanese tephra using quartz phenocrysts severely underestimated the known age. The characteristics of the OSL signals were investigated in order to understand the cause of the underestimation; the main OSL component of volcanic quartz has a thermodynamic lifetime of about 1700 years at room temperature, and it also seems to fade anomalously (i.e. athermally). Measurement of conventional red thermoluminescence (RTL) using a Ga-As photomultiplier tube was difficult due to the presence of a strong thermal background, although RTL gave an age consistent with the independent age. Furthermore, red isothermal TL (RITL) at 380 deg. C allowed the RTL signal to be separated from to the thermal background, and RITL ages of three volcanic quartz samples show good agreement with independent ages

Production of mineral aggregates in quartz tumbling experiments

Science.gov (United States)

Nørnberg, Per; Finster, Kai; Pall Gunnlaugsson, Haraldur; Knak Jensen, Svend; Merrison, Jonathan Peter

2013-04-01

Introduction Tumbling experiments with quartz sand with the purpose of tracing the effect of broken bonds in mineral surfaces resulted in an unexpected production of aggregates. These aggregates are a few microns in diameter, spherical and resembling tiny white "snowballs." Particle comminution by aeolian and other natural weathering processes are known in soil science and is often seen as an increase of fine particles towards the top of soil profiles (Nørnberg, P. 1987, 1988, 2002, J.S. Wright 2007). When mineral grains collide in aeolian processes they break up along weakness zones in the crystal lattice. This mechanism causes broken bonds between atoms in the crystal lattice and results in reactive groups in the mineral surface. This mechanism provides the background for experiments to investigate the oxidation processes of magnetite on the planet Mars. The primary magnetic iron oxide phase on Mars is to day known to be magnetite and the colour of the dust on Mars is most likely due to hematite. To investigate if the oxidation process could take place without going over dissolution and precipitation in water, experiments with tumbling of quartz grains in sealed glass containers along with magnetite were started. The idea was that activated bonds at the surface of quartz could oxidize magnetite and convert it to hematite over time. This proved to be the case (Merrison, J.P. et al. 2010). However, in these experiments we observed the formation of the white aggregates which has been the subject of the study that we present here. Results of tumbling experiments Commercially available quarts (Merck) was sieved to obtain the fraction between 125 and 1000 µm. This fraction was tumbled in glass containers for months and resulted in production of a significant amount of fine grained material (Merrison, J.P et al. 2010). A part of this fine fraction consists of the "snowball"-like aggregates which is a fragile element with relatively high specific surface. The physical

Photochemical Synthesis and Properties of Colloidal Copper, Silver and Gold Adsorbed on Quartz

International Nuclear Information System (INIS)

Loginov, Anatoliy V.; Gorbunova, Valentina V.; Boitsova, Tatiana B.

2002-01-01

Original methods for the photochemical production of stable copper, silver and gold colloids in the form of films on quartz, and dispersion in liquids were devised. It is shown that photochemical synthesis of colloidal metals is a difficult multiphase process, and includes the formation of low-valence forms of Cu(I), Au(I) and nonmetal clusters, colloidal particles and their agglomerates. Cluster stabilization and further growth to colloidal particles are achieved by adsorption onto the solid surface (quartz) or by increasing the viscosity of photolyte. In the absence of these methods of stabilization, the processes of intermediate reoxidation to Cu(II) and Au(III) and agglomeration of Ag and Au colloids proceed in a photolyte. Adsorption and the rate of cluster growth on a quartz surface are speeded up by the action of monochromatic UV light. Experimental models of the mechanism of colloidal formation are suggested. The dependence of the growth rate and the properties of the colloids on conditions of the photochemical procedure (energy and light intensity, concentration of initial complex) has been established

Geology of the central Mineral Mountains, Beaver County, Utah

Energy Technology Data Exchange (ETDEWEB)

Sibbett, B.S.; Nielson, D.L.

1980-03-01

The Mineral Mountains are located in Beaver and Millard Counties, southwestern Utah. The range is a horst located in the transition zone between the Basin and Range and Colorado Plateau geologic provinces. A multiple-phase Tertiary pluton forms most of the range, with Paleozoic rocks exposed on the north and south and Precambrian metamorphic rocks on the west in the Roosevelt Hot Springs KGRA (Known Geothermal Resource Area). Precambrian banded gneiss and Cambrian carbonate rocks have been intruded by foliated granodioritic to monzonitic rocks of uncertain age. The Tertiary pluton consists of six major phases of quartz monzonitic to leucocratic granitic rocks, two diorite stocks, and several more mafic units that form dikes. During uplift of the mountain block, overlying rocks and the upper part of the pluton were partially removed by denudation faulting to the west. The interplay of these low-angle faults and younger northerly trending Basin and Range faults is responsible for the structural control of the Roosevelt Hot Springs geothermal system. The structural complexity of the Roosevelt Hot Springs KGRA is unique within the range, although the same tectonic style continues throughout the range. During the Quaternary, rhyolite volcanism was active in the central part of the range and basaltic volcanism occurred in the northern portion of the map area. The heat source for the geothermal system is probably related to the Quaternary rhyolite volcanic activity.

Accurate dew-point measurement over a wide temperature range using a quartz crystal microbalance dew-point sensor

Science.gov (United States)

Kwon, Su-Yong; Kim, Jong-Chul; Choi, Buyng-Il

2008-11-01

Quartz crystal microbalance (QCM) dew-point sensors are based on frequency measurement, and so have fast response time, high sensitivity and high accuracy. Recently, we have reported that they have the very convenient attribute of being able to distinguish between supercooled dew and frost from a single scan through the resonant frequency of the quartz resonator as a function of the temperature. In addition to these advantages, by using three different types of heat sinks, we have developed a QCM dew/frost-point sensor with a very wide working temperature range (-90 °C to 15 °C). The temperature of the quartz surface can be obtained effectively by measuring the temperature of the quartz crystal holder and using temperature compensation curves (which showed a high level of repeatability and reproducibility). The measured dew/frost points showed very good agreement with reference values and were within ±0.1 °C over the whole temperature range.

Accurate dew-point measurement over a wide temperature range using a quartz crystal microbalance dew-point sensor

International Nuclear Information System (INIS)

Kwon, Su-Yong; Kim, Jong-Chul; Choi, Buyng-Il

2008-01-01

Quartz crystal microbalance (QCM) dew-point sensors are based on frequency measurement, and so have fast response time, high sensitivity and high accuracy. Recently, we have reported that they have the very convenient attribute of being able to distinguish between supercooled dew and frost from a single scan through the resonant frequency of the quartz resonator as a function of the temperature. In addition to these advantages, by using three different types of heat sinks, we have developed a QCM dew/frost-point sensor with a very wide working temperature range (−90 °C to 15 °C). The temperature of the quartz surface can be obtained effectively by measuring the temperature of the quartz crystal holder and using temperature compensation curves (which showed a high level of repeatability and reproducibility). The measured dew/frost points showed very good agreement with reference values and were within ±0.1 °C over the whole temperature range

Oxygen isotopic ratios of quartz from wind-erosive soils of southwestern United States in relation to aerosol dust

Energy Technology Data Exchange (ETDEWEB)

Sridhar, K.; Jackson, M.L.; Clayton, R.N.; Gillette, D.A.; Hawley, J.W.

1978-01-01

The oxygen isotopic ratios (expressed as parts per thousand relative to mean ocean water, SMOW, delta/sup 18/O) of the quartz from 13 soils undergoing much wind erosion during the study period of 1972-1975 in four southwestern states and from comparison areas were determined. The delta/sup 18/O for quartz from eight Texas (TX) and Arizona (AZ) soils range from 13.0 to 15.9 /sup 0///sub 00/. The quartz of the sands and silts coarser than 20 ..mu..m from three of the soils had delta/sup 18/O values ranging from 13.1 to 15.1 /sup 0///sub 00/, characteristic of an ultimate igneous-metamorphic origin. The delta/sup 18/O values increase greatly with decreasing particle size of quartz from three soils ranging from loamy fine sand to loam to clay in texture. The delta/sup 18/O of the 1-10 ..mu..m quartz fraction (aerosol size) ranged from 19.2 to 20.2 /sup 0///sub 00/ (19.55 +- 0.28 /sup 0///sub 00/; +- sigma) for the thirteen soils most affected by dust storms. The oxygen isotopic ratios of 1-10 ..mu..m quartz from three Hawaiian soils and two sediments from Lake Waiau occurring at 3,970 m altitude on the Mauna Kea summit on the Island of Hawaii give a delta/sup 18/O mean of 18.3 +- 0.2 /sup 0///sub 00/.

A quartz Cherenkov detector for polarimetry at the ILC

International Nuclear Information System (INIS)

Vauth, Annika

2014-09-01

At the proposed International Linear Collider (ILC), the use of polarised electron and positron beams is a key ingredient of the physics program. A measurement of the polarisation with a yet unprecedented precision of δP / P =0.25% is required. To achieve this, Compton polarimeter measurements in front of and behind the collision point are foreseen. In this thesis, a novel concept for a detector for ILC polarimetry is introduced to eliminate one of the dominating systematics limiting the previous best measurement of beam polarisation: a detector using quartz as Cherenkov medium could increase the tolerance against non-linear photodetector responses. The high refractive index of quartz results in a higher Cherenkov light yield compared to conventional Cherenkov gases. This could allow single-peak resolution in the Cherenkov photon spectra produced by the Compton electrons at the polarimeters. The detailed simulation studies presented in this work imply that such single-peak resolution is possible. Considerations for the choice of a suitable detector geometry are discussed. A four-channel prototype has been constructed and successfully operated in a first testbeam campaign at the DESY testbeam, confirming simulation predictions. Although further studies have to be considered to quantify all aspects of the detector response, the findings of the analysis of the data from the first testbeam are promising with regards to reaching the desired light yield. In the final part of this thesis, the application of a detector concept allowing single-peak resolution to the polarisation measurement at the ILC is examined. Two of the main sources of systematic uncertainties on the polarimeter measurements are detector non-linearities and misalignments. The performance of the suggested quartz detector concept in Monte Carlo studies promises a control of these systematics which meets the precision requirements for ILC polarimetry.

A study of Love wave devices in ZnO/Quartz and ZnO/LiTaO3 structures

International Nuclear Information System (INIS)

Chang, R.-C.; Chu, S.-Y.; Hong, C.-S.; Chuang, Y.-T.

2006-01-01

Love wave devices are very promising for sensing applications because of high sensitivity. In this paper, ZnO thin films doped with lithium (Li) and magnesium (Mg) were deposited on the 42 o 45' ST-cut quartz and 36 o YX-LiTaO 3 substrates by RF magnetron sputtering technique. XRD, SEM, and AFM measurements investigated characteristics of the films. Under different conditions such as doping content, layer thickness, and substrate temperature, the phase velocity, temperature coefficient of frequency, electromechanical coupling coefficient and sensitivity of Love wave devices in ZnO/Quartz and ZnO/LiTaO 3 structures are presented. The maximum sensitivities of ZnO/Quartz and ZnO/LiTaO 3 are much higher than the SiO 2 /Quartz and SiO 2 /LiTaO 3 structures reported

Blue light emitting diodes for optical stimulation of quartz in retrospective dosimetry and dating

DEFF Research Database (Denmark)

Bøtter-Jensen, L.; Duller, G.A.T.; Murray, A.S.

1999-01-01

Recently developed blue light emitting diodes (LEDs) for the optical stimulation of quartz for use in routine optically stimulated luminescence (OSL) dating and retrospective dosimetry have been tested. For similar power densities, it was found that the higher energy light provided by the blue LE......, preliminary results from ramping the blue light power output with time are demonstrated. It is shown that this technique enables the separation of OSL components with differing stimulation rates.......Recently developed blue light emitting diodes (LEDs) for the optical stimulation of quartz for use in routine optically stimulated luminescence (OSL) dating and retrospective dosimetry have been tested. For similar power densities, it was found that the higher energy light provided by the blue LEDs...... (470 nm) gives order of magnitude greater rate of stimulation in quartz than that from conventional blue-green light filtered from a halogen lamp. A practical blue LED OSL configuration is described. From comparisons of OSL decay curves produced by green and blue light sources, and by examination...

Absorbed dose evaluations in retrospective dosimetry: Methodological developments using quartz

DEFF Research Database (Denmark)

Bailiff, I.K.; Bøtter-Jensen, L.; Correcher, V.

2000-01-01

Dose evaluation procedures based on luminescence techniques were applied to 50 quartz samples extracted from bricks that had been obtained from populated or partly populated settlements in Russia and Ukraine downwind of the Chernobyl NPP. Determinations of accrued dose in the range similar to 30...

Allan Deviation Plot as a Tool for Quartz-Enhanced Photoacoustic Sensors Noise Analysis.

Science.gov (United States)

Giglio, Marilena; Patimisco, Pietro; Sampaolo, Angelo; Scamarcio, Gaetano; Tittel, Frank K; Spagnolo, Vincenzo

2016-04-01

We report here on the use of the Allan deviation plot to analyze the long-term stability of a quartz-enhanced photoacoustic (QEPAS) gas sensor. The Allan plot provides information about the optimum averaging time for the QEPAS signal and allows the prediction of its ultimate detection limit. The Allan deviation can also be used to determine the main sources of noise coming from the individual components of the sensor. Quartz tuning fork thermal noise dominates for integration times up to 275 s, whereas at longer averaging times, the main contribution to the sensor noise originates from laser power instabilities.

Quartz luminescence response to a mixed alpha-beta field: Investigations on Romanian loess

DEFF Research Database (Denmark)

Constantin, Daniela; Jain, Mayank; Murray, Andrew S.

2015-01-01

-OSL laboratory dose response curves do not reflect the growth of the OSL signal in nature. A main difference in coarse- and fine-grained quartz dating lies in the alpha irradiation history, but the effect of mixed alpha-beta fields has so far received little attention. In the present study we investigate whether...... the alpha dose experienced by fine grains over geological cycles of irradiation and bleaching may have an effect on the saturation characteristics of the laboratory dose response. By applying time resolved optically stimulated luminescence we confirm that the OSL signals induced in quartz by alpha and beta...

Kinetic model for quartz and spinel dissolution during melting of high-level-waste glass batch

International Nuclear Information System (INIS)

Pokorny, Richard; Rice, Jarrett A.; Crum, Jarrod V.; Schweiger, Michael J.; Hrma, Pavel

2013-01-01

The dissolution of quartz particles and the growth and dissolution of crystalline phases during the conversion of batch to glass potentially affects both the glass melting process and product quality. Crystals of spinel exiting the cold cap to molten glass below can be troublesome during the vitrification of iron-containing high-level wastes. To estimate the distribution of quartz and spinel fractions within the cold cap, we used kinetic models that relate fractions of these phases to temperature and heating rate. Fitting the model equations to data showed that the heating rate, apart from affecting quartz and spinel behavior directly, also affects them indirectly via concurrent processes, such as the formation and motion of bubbles. Because of these indirect effects, it was necessary to allow one kinetic parameter (the pre-exponential factor) to vary with the heating rate. The resulting kinetic equations are sufficiently simple for the detailed modeling of batch-to-glass conversion as it occurs in glass melters. The estimated fractions and sizes of quartz and spinel particles as they leave the cold cap, determined in this study, will provide the source terms needed for modeling the behavior of these solid particles within the flow of molten glass in the melter

Effects of quartz on crystallization behavior of mold fluxes and microstructural characteristics of flux film.

Science.gov (United States)

Lei, Liu; Xiuli, Han; Mingduo, Li; Di, Zhang

2018-01-01

Mold fluxes are mainly prepared using cement clinker, quartz, wollastonite, borax, fluorite, soda ash and other mineral materials. Quartz, as one of the most common and essential materials, was chosen for this study to analyze itseffects on crystallization temperature, critical cooling rate, crystal incubation time, crystallization ratio and phases of flux film. We used the research methods of process mineralogy with the application of the single hot thermocouple technique, heat flux simulator, polarizing microscope, X-ray diffraction, etc. Results: By increasing the quartz content from 16 mass% to 24 mass%, the crystallization temperature, critical cooling rate and crystallization ratio of flux film decreased, and the crystal incubation time was extended. Meanwhile, the mineralogical structure of the flux film changed, with a large amount of wollastonite precipitation and a significant decrease in the cuspidine content until it reached zero. This showed a steady decline in the heat transfer control capacity of the flux film. The reason for the results above is that, by increasing the quartz content, the silicon-oxygen tetrahedron network structure promoted a rise in viscosity and restrained ion migration, inhibiting crystal nucleation and growth, leading to the weakening of the crystallization and a decline in the crystallization ratio.

Extending the dose range: Probing deep traps in quartz with 3.06 eV photons

DEFF Research Database (Denmark)

Jain, Mayank

2009-01-01

stimulation. Although, the fast OSL component is measured with similar efficiency by blue and violet lights, the slower OSL components (especially S3) are measured relatively more efficiently with the latter. New insight into the origins of quartz luminescence is presented through a comparison of violet......This article demonstrates that violet (405 nm) stimulated luminescence (VSL) signal from quartz contains contribution from deep traps that are otherwise not accessible with blue light (470 nm). Additionally, it also contains the typical fast and slow components observed with the blue light...... and blue lights stimulation, and thermal stimulations. Finally, it is shown that the deep traps probed through violet light stimulation have potential for increasing the dose measurement/dating range using quartz. The post-blue VSL signal allows easy, precise measurement of dose up to at least 1 kGy in our...

A Transimpedance Amplifier for Remotely Located Quartz Tuning Forks

OpenAIRE

Kleinbaum, Ethan; Csathy, Gabor

2012-01-01

The cable capacitance in cryogenic and high vacuum applications of quartz tuning forks imposes severe constraints on the bandwidth and noise performance of the measurement. We present a single stage low noise transimpedance amplifier with a bandwidth exceeding 1 MHz and provide an in-depth analysis of the dependence of the amplifier parameters on the cable capacitance.

QUARTZ: a numerical simulation of an asymmetric electrostatic accelerator

International Nuclear Information System (INIS)

Wooten, J.W.; Drooks, L.J.; McCollough, D.H.; McGaffey, R.W.; Whealton, J.H.

1979-01-01

The physics and numerical aspects of the development of the computer code QUARTZ are given. This code includes the (1) use of a finite element code to obtain solutions of Poisson's equation in an asymmetric, three-dimensional volume; (2) inclusion of space charge neutralization by electrons; and (3) inclusion of ion space charge through an iterative procedure

Investigations of alteration zones based on fluid inclusion microthermometry at Sungun porphyry copper deposit, Iran

Directory of Open Access Journals (Sweden)

Omid ASGHARI

2010-06-01

Full Text Available The Sungun porphyry copper deposit is located in East Azerbaijan, NW of Iran. The porphyries occur as stocks and dikes ranging in composition from quartz monzodiorite to quartz monzonite. Four types of hypogene alteration are developed; potassic, phyllic, propylitic and argillic. Three types of fluid inclusions are typically observed at Sungun; (1 vapor-rich, (2 liquid-rich and (3 multi-phase. Halite is the principal solid phase in the latter. The primary multiphase inclusions within the quartz crystals were chosen for micro-thermometric analyses and considered to calculate the geological pressure and hydrothermal fluid density. In potassic zone, the average of homogenization temperature is 413.6 °C while in phyllic alteration, 375.9 °C. As expected in potassic alteration, the temperature of hydrothermal solutions is higher than that in the phyllic zone. The salinity of the hydrothermal fluids has a high coherency with homogenization temperature, so the average of salinity in potassic samples is 46.3 (wt% NaCl which is higher than phyllic samples. Based on the location of potassic alteration, as expected, the lithostatic pressure is much more than the phyllic one. Finally, the average density of hydrothermal fluids in the potassically altered samples is 1.124 (gr/cm3 which is higher than the ones in phyllic zone (1.083 gr/cm3 .

Lighting equipment with the DRSh-1000 and PRK-7 mercury-quartz lamps for radiation chemistry

International Nuclear Information System (INIS)

Maslov, B.V.; Gol'din, V.A.; Tapil'skij, E.L.

1976-01-01

Operation of lighting units with mercury-quartz lamps under the conditions of intensive γ irradiation is described. A condenser liquid lens has been designed and tested. The lens makes it possible to use quartz glass with a low radiation-optical resistance in the optical systems of the units. It is shown that in an ultra-violet range of spectrum z = 300 - 400 nm reduction of luminous flux resulting from 150 Mrad irradiation approximates 5%

Study of the relation of the band at 3595 CM-1 in FTIR spectrum of natural quartz with color development by gamma irradiation

International Nuclear Information System (INIS)

Silva, Helena Cristina M.; Lameiras, Fernando S.

2015-01-01

Brazil is a major producer of gemological quartz as smoky quartz, morion, citrine, amethyst, and prasiolite. Due to its abundance, hardness, and color varieties, quartz is used in jewelry industry. However, very often quartz is found in nature colorless or with faint colors, which requires exposure to ionizing radiation for color enhancement or development. Not all quartz can develop color. Chromophore chemical elements must be present in suitable proportions for color development after irradiation and heating. Infrared spectrometry is used to separate the quartz that can develop colors from the ones that cannot. Bands in infrared spectrum can indicate the presence and relative contents of chromophore chemical elements, such as aluminum, iron, lithium, sodium, and hydrogen. Some samples of colorless quartz show a band at 3595 cm -1 whose origin is yet not assigned. Samples of quartz with a prominent band at 3595 cm -1 were exposed to gamma rays and heating to observe its behavior. From the statistical point of view, no modification was observed on the position and amplitude of this band after irradiation up 75 kGy and heating to 300-330 deg C. This study should be completed with samples of different origins and higher doses, as well as chemical analyses of trace chemical elements in the samples. (author)

Quartz-enhanced photo-acoustic spectroscopy for breath analyses

Science.gov (United States)

Petersen, Jan C.; Lamard, Laurent; Feng, Yuyang; Focant, Jeff-F.; Peremans, Andre; Lassen, Mikael

2017-03-01

An innovative and novel quartz-enhanced photoacoustic spectroscopy (QEPAS) sensor for highly sensitive and selective breath gas analysis is introduced. The QEPAS sensor consists of two acoustically coupled micro- resonators (mR) with an off-axis 20 kHz quartz tuning fork (QTF). The complete acoustically coupled mR system is optimized based on finite element simulations and experimentally verified. Due to the very low fabrication costs the QEPAS sensor presents a clear breakthrough in the field of photoacoustic spectroscopy by introducing novel disposable gas chambers in order to avoid cleaning after each test. The QEPAS sensor is pumped resonantly by a nanosecond pulsed single-mode mid-infrared optical parametric oscillator (MIR OPO). Spectroscopic measurements of methane and methanol in the 3.1 μm to 3.7 μm wavelength region is conducted. Demonstrating a resolution bandwidth of 1 cm-1. An Allan deviation analysis shows that the detection limit at optimum integration time for the QEPAS sensor is 32 ppbv@190s for methane and that the background noise is solely due to the thermal noise of the QTF. Spectra of both individual molecules as well as mixtures of molecules were measured and analyzed. The molecules are representative of exhaled breath gasses that are bio-markers for medical diagnostics.

Transitional grain-size-sensitive flow of milky quartz aggregates

Science.gov (United States)

Fukuda, J. I.; Holyoke, C. W., III; Kronenberg, A. K.

2014-12-01

Fine-grained (~15 μm) milky quartz aggregates exhibit reversible flow strengths in triaxial compression experiments conducted at T = 800-900oC, Pc = 1.5 GPa when strain rates are sequentially decreased (typically from 10-3.5 to 10-4.5 and 10-5.5 s-1), and then returned to the original rate (10-3.5 s-1), while samples that experience grain growth at 1000oC (to 35 μm) over the same sequence of strain rates exhibit an irreversible increase in strength. Polycrystalline quartz aggregates have been synthesized from natural milky quartz powders (ground to 5 μm) by HIP methods at T = 1000oC, Pc = 1.5 GPa and t = 24 hours, resulting in dense, fine-grained aggregates of uniform water content of ~4000 ppm (H/106Si), as indicated by a broad OH absorption band at 3400 cm-1. In experiments performed at 800o and 900oC, grain sizes of the samples are essentially constant over the duration of each experiment, though grain shapes change significantly, and undulatory extinction and deformation lamellae indicate that much of the sample shortening (to 50%) is accomplished, over the four strain-rate steps, by dislocation creep. Differential stresses measured at T = 800oC decrease from 160 to 30 MPa as strain rate is reduced from 10-4.6 to 10-5.5 s-1, and a stress of 140 MPa is measured when strain rate is returned to 10-4.5 s-1. Samples deformed at 1000o and 1100oC experience normal grain growth, with grain boundary energy-driven grain-coarsening textures superposed by undulatory extinction and deformation lamellae. Differential stresses measured at 1000oC and strain rates of 10-3.6, 10-4.6, and 10-5.5 s-1 are 185, 80, and 80 MPa, respectively, while an increased flow stress of 260 MPa is measured (following ~28 hours of prior high temperature deformation and grain growth) when strain rate is returned to 10-3.6 s-1. While all samples exhibit lattice preferred orientations, the stress exponent n inferred for the fine-grained 800oC sample is 1.5 and the stress exponent of the coarse

Optimizing detection filters for single-grain optical dating of quartz

International Nuclear Information System (INIS)

Ballarini, M.; Wallinga, J.; Duller, G.A.T.; Brouwer, J.C.; Bos, A.J.J.; Van Eijk, C.W.E.

2005-01-01

We investigate the use of different optical detection filters for single-grain optically stimulated luminescence (OSL) measurements of quartz samples with a Riso TL/OSL single-grain reader. We selected three filter combinations that considerably improve the light detection efficiency when compared with the 7.5 mm U340 filters that are routinely used. These are the UG1+BG4 filter combination, the 2 mm UG1 and the 2.5 mm U340 filters, which allow a greater transmission in the quartz emission band. This leads to two benefits: (1) more grains can be accepted for equivalent dose analysis, and (2) OSL responses on individual grains are determined with a greater precision. While these three alternative filter combinations perform equally well if compared to each other, we suggest the 2.5 mm thick Hoya U340 to be the filter of choice as it allows the use of blue-diode and IR-diode stimulation sources for bleaching purposes and feldspar detection

The correlation of fast OSL component with the TL peak at 3250C in quartz of various origins

International Nuclear Information System (INIS)

Kitis, G.; Kiyak, N.; Polymeris, G.S.; Tsirliganis, N.C.

2010-01-01

The fast component of the optically stimulated luminescence (OSL) signal in quartz is the basic tool for the optical dating. Its relation with the thermoluminescence (TL) glow-peak at about 325 deg. C is well established for naturally irradiated quartz. This relationship is also an important part of a general model for quartz on which many theoretical simulations of various OSL experimental results have been based. In the present work this relationship is systematically investigated in nine quartz samples of different origin. The linearly modulated OSL (LM-OSL) curves of all quartz samples for stimulation time less than 50 s consists of two components discriminated easily by a computerized curve deconvolution (CCD) analysis. By comparing the un-bleached to the respective bleached TL glow-curve, it is found that the system of these two fast OSL components is directly related with only a small portion of the electron traps responsible for the TL glow-peaks in the temperature region 200-400 0 C. By increasing the stimulation times, besides the two fast components, the medium and the slow components are also obtained. The medium and slow components are clearly related with the main body of the electron traps responsible for TL glow-peaks in the same temperature region 200-400 0 C. Despite their different origin all quartz samples show an appreciable homogeneity concerning the number and time position of the individual components, whereas, the relative TL/OSL intensities vary strongly from sample to sample with the integrated TL intensity being generally much less than the integrated OSL intensity.

Relieved Working study: systematic development and design of an intervention to decrease occupational quartz exposure at construction worksites

NARCIS (Netherlands)

Oude Hengel, K.M.; Deurssen, E. van; Meijster, T.; Tielemans, E.; Heederik, D.; Pronk, A.

2014-01-01

Background: Occupational quartz exposure continues to be a serious hazard in the construction industry. Until now, evidence-based interventions aimed at reducing quartz exposure are scarce. The aim of this study was to systematically develop an intervention and to describe the study to evaluate its

Study of Pellets and Lumps as Raw Materials in Silicon Production from Quartz and Silicon Carbide

Science.gov (United States)

Dal Martello, E.; Tranell, G.; Gaal, S.; Raaness, O. S.; Tang, K.; Arnberg, L.

2011-10-01

The use of high-purity carbon and quartz raw materials reduces the need for comprehensive refining steps after the silicon has been produced carbothermically in the electric reduction furnace. The current work aims at comparing the reaction mechanisms and kinetics occurring in the inner part of the reduction furnace when pellets or lumpy charge is used, as well as the effect of the raw material mix. Laboratory-scale carbothermic reduction experiments have been carried out in an induction furnace. High-purity silicon carbide and two different high-purity hydrothermal quartzes were charged as raw materials at different molar ratios. The charge was in the form of lumps (size, 2-5 mm) or as powder (size, 10-20 μm), mixed and agglomerated as pellets (size, 1-3 mm) and reacted at 2273 K (2000 °C). The thermal properties of the quartzes were measured also by heating a small piece of quartz in CO atmosphere. The investigated quartzes have different reactivity in reducing atmosphere. The carbothermal reduction experiments show differences in the reacted charge between pellets and lumps as charge material. Solid-gas reactions take place from the inside of the pellets porosity, whereas reactions in lumps occur topochemically. Silicon in pellets is produced mainly in the rim zone. Larger volumes of silicon have been found when using lumpy charge. More SiO is produced when using pellets than for lumpy SiO2 for the same molar ratio and heating conditions. The two SiC polytypes used in the carbothermal reduction experiments as carbon reductants presented different reactivity.

Developing a SAR TT-OSL protocol for volcanically-heated aeolian quartz from Datong (China)

DEFF Research Database (Denmark)

Liu, Jinfeng; Murray, Andrew S.; Jain, Mayank

2012-01-01

The thermally-transferred optically stimulated luminescence (TT-OSL) responses of chemically-purified fine-grained quartz from a lava-baked aeolian sediment from Datong (China) are presented. Our main focus is to examine the suitability of the test dose TT-OSL and OSL response to monitor sensitiv......The thermally-transferred optically stimulated luminescence (TT-OSL) responses of chemically-purified fine-grained quartz from a lava-baked aeolian sediment from Datong (China) are presented. Our main focus is to examine the suitability of the test dose TT-OSL and OSL response to monitor...

Miniature quartz crystal-resonator-based thermogravimetric detector.

Science.gov (United States)

Sai, N; Tagawa, Y; Sohgawa, M; Abe, T

2014-09-01

In this work, a new design for a microheater combined with a quartz crystal microbalance (QCM) array for thermogravimetric analysis is presented. Each QCM consists of two electrodes to excite thickness-shear-mode vibrations and one microheater to increase the temperature on the crystal backside. In addition, all the electrode pads are patterned on the crystal backside, making the design of the QCM compact and user-friendly. Finally, the proposed QCM array was employed to separate ethanol from methanol. This was successfully achieved via thermal desorption spectra calculated by differentiating the frequency changes.

Anisotropic viscoelastic properties of quartz and quartzite in the vicinity of the α- β phase transition

Science.gov (United States)

Klumbach, Steffen; Schilling, Frank R.

2017-10-01

In this study we performed high-temperature, dynamic (i.e. sinusoidal), three-point bending experiments of quartz single crystals and quartzite samples within the frequency range of seismic surveys (i.e. 0.1-20 Hz). At constant temperature close to the α- β phase transition we observed a unique complex elastic behaviour of both quartz and quartzite. We find a frequency dependence of the complex Young's modulus of α-quartz, including a dissipation maximum at ≈1 Hz supposedly related to the formation and variation of Dauphiné twin domains. Based on our experimental results for different crystallographic directions and additional modelling, we are able to describe the complex Young's modulus of quartz at its α- β phase transition in a 3D diagram. We derive a frequency-dependent elasticity tensor, using a three-element equivalent circuit, composed of two springs E 1 and E 2 as well as a dashpot η. E 1 and η are connected parallel to each other, E 2 is added in series. Compliance coefficients yield ( S 11) E 1 = 572 GPa, E 2 = 70.0 GPa, η = 64.6 GPa·s, ( S 33) E 1 = 127 GPa, E 2 = 52.1 GPa, η = 22.9 GPa·s, ( S 44) E 1 = 204 GPa, E 2 = 37.5 GPa, η = 26.4 GPa·s, ( S 12) E 1 = 612 GPa, E 2 = 106.7 GPa, η = 78.5 GPa·s, ( S 13) E 1 = 1546 GPa, E 2 = 284 GPa, η = 200 GPa·s; S 14 ≈-0.0024 GPa-1. We use the derived direction-dependent coefficients to predict the frequency-dependent complex elastic properties of isotropic polycrystalline quartz. These predictions agree well with the experimental results of the investigated quartzite. Finally, we explore the potential of using the anomalous frequency-dependent complex elastic properties of quartz at the α- β phase transition that we observed as an in situ temperature probe for seismic studies of the Earth's continental crust.

OSL dating of fine-grained quartz from Holocene Yangtze delta sediments

DEFF Research Database (Denmark)

Sugisaki, Saiko; Buylaert, Jan-Pieter; Murray, Andrew

2015-01-01

Holocene flood events in the Yangtze River are associated with variations in East Asian Summer Monsoon (EASM) precipitation, and so Yangtze delta sediments may preserve information about the frequency and magnitude of EASM precipitation. These flood/drought cycles of the EASM directly affect...... the living standards of East Asian population. However, despite its importance, little chronological control is available for the Yangtze Delta sediments; because biogenic carbonate only occurs sporadically, it has proved the difficulty to discuss sedimentation mechanisms and rates in any detail. In 2013 two...... sediment cores (YD13-G3 and H1) were taken from the Yangtze subaqueous delta to investigate precipitation history. In this study, we investigate the potential of quartz OSL dating of the fine silt fraction (fine-grained quartz; 4-11 μm) from these cores to estimate the depositional age of the sediments. We...

Optically stimulated luminescence from quartz measured using the linear modulation technique

DEFF Research Database (Denmark)

Bulur, E.; Bøtter-Jensen, L.; Murray, A.S.

2000-01-01

The optically stimulated luminescence (OSL) from heated natural quartz has been investigated using the linear modulation technique (LMT), in which the excitation light intensity is increased linearly during stimulation. In contrast to conventional stimulation, which usually produces a monotonical...

Three sets of crystallographic sub-planar structures in quartz formed by tectonic deformation

Science.gov (United States)

Derez, Tine; Pennock, Gill; Drury, Martyn; Sintubin, Manuel

2016-05-01

In quartz, multiple sets of fine planar deformation microstructures that have specific crystallographic orientations parallel to planes with low Miller-Bravais indices are commonly considered as shock-induced planar deformation features (PDFs) diagnostic of shock metamorphism. Using polarized light microscopy, we demonstrate that up to three sets of tectonically induced sub-planar fine extinction bands (FEBs), sub-parallel to the basal, γ, ω, and π crystallographic planes, are common in vein quartz in low-grade tectonometamorphic settings. We conclude that the observation of multiple (2-3) sets of fine scale, closely spaced, crystallographically controlled, sub-planar microstructures is not sufficient to unambiguously distinguish PDFs from tectonic FEBs.

Origin of ore-forming fluids of the Haigou gold deposit in the eastern Central Asian Orogenic belt, NE China: Constraints from H-O-He-Ar isotopes

Science.gov (United States)

Zeng, Qingdong; He, Huaiyu; Zhu, Rixiang; Zhang, Song; Wang, Yongbin; Su, Fei

2017-08-01

The Haigou lode deposit contains 40 t of gold at an average grade of 3.5 g/t, and is one of the largest deposits in the Jiapigou gold belt located along the eastern segment of the northern margin of the North China Craton. The deposit comprises 15 gold-bearing quartz veins hosted in a Carboniferous monzonite-monzogranite stock. Cretaceous dikes consisting of diorite, diabase, and granodiorite porphyries are well developed in the deposit. The diorite porphyry dikes (130.4 ± 6.3 Ma) occur together with gold-bearing quartz veins in NNE- and NE-striking faults. Gold-bearing quartz veins crosscut the diorite porphyry dikes, and the veins are in turn crosscut by E-W-striking 124.6 ± 2.2 Ma granodiorite porphyry dikes. The mineralization mainly occurs as auriferous quartz veins with minor amounts of sulfide minerals, including pyrite, galena, chalcopyrite, and molybdenite. Gold occurs as either native gold or calaverite. Common gangue minerals in the deposit include quartz, sericite, and calcite. The deposit is characterized by various types of hydrothermal alteration, including silicification, sericitization, chloritization, potassic alteration, and carbonatization. Three stages of hydrothermal activity have been recognized in the deposit: (1) a barren quartz stage; (2) a polymetallic sulfide (gold) stage; (3) a calcite stage. Fluid inclusions in hydrothermal pyrites have 3He/4He ratios of 0.3 to 3.3 Ra and 40Ar/36Ar ratios of 351 to 1353, indicating mixing of fluids of mantle and crustal origin. Hydrothermal quartz yielded δ18O values of -1.3‰ to +7.2‰ and δD values of fluid inclusions in the quartz vary between -80‰ and -104‰. These stable isotope data also suggest mixing of magmatic and meteoric fluids. Noble gas and stable isotopic data suggest that the ore fluids have a predominant mantle source with a significant crustal component. Based on the spatial association of gold-bearing quartz veins with early Cretaceous intrusions, and the H-O-He-Ar isotopic

Quartz crystal microbalance gas sensor with nanocrystalline diamond sensitive layer

Czech Academy of Sciences Publication Activity Database

Varga, Marián; Laposa, A.; Kulha, Pavel; Kroutil, J.; Husák, M.; Kromka, Alexander

2015-01-01

Roč. 252, č. 11 (2015), s. 2591-2597 ISSN 0370-1972 R&D Projects: GA ČR(CZ) GBP108/12/G108 Institutional support: RVO:68378271 Keywords : gas sensor * nanocrystalline diamond * quartz resonator * thickness shear mode Subject RIV: JB - Sensor s, Measurment, Regulation Impact factor: 1.522, year: 2015

SPHERICAL MICROPARTICLES FROM GOLD–BEARING QUARTZ VEINS OF THE IROKINDA DEPOSIT, WESTERN TRANSBAIKALIA

Directory of Open Access Journals (Sweden)

A. V. Tatarinov

2016-01-01

Full Text Available We have studied the material composition of ore microparticles extracted from gold concentrates of operating quartz vein No. 30 located in the Irokinda deposit, Western Transbaikalia. We consider the origin of such microparticles in connection with our observation data and the previously published structural and geological features revealed in formation of the ore field, as well as tectonophysical conditions of formation of many gold-bearing quartz veins, including vein No. 30.Gold-quartz veins, located in the allochthonous plate thrusted onto the Kelyano-Irokinda belt (Fig. 1, infill the NE-striking fault zones. E.A. Namolov conducted the tectonophysical analysis of the “elementary fracture – ore-bearing suture/joint” system, which provided a genetic explanation of the morphology of ore quartz veins (including vein No. 30 and conditions for formation of their host fault zones. Ore-bearing fractures are combinations of shear and cleavage cracks that occur in case of certain positions of the strain ellipsoid in conditions of horizontal compression. Due to repeated intra-mineralization displacements, the texture of the ores is strappy, and the quartz matrix of the veins contains numerous inclusions of host rocks.The spherical particles have zonal structures and consist of metal nodes and external continuous or discontinuous shells, which thickness ranges from 10 to 400 microns (Fig. 2, Fig. 3. The nodes are composed mainly of native Fe with admixtures of Fe, Mn, Al (Table, the contents of which are typically less than 1.0–1.5 wt %.Characteristic features of the mineral composition of shells of the spheroidal microparticles:– The widespread graphite matrix consisting of minerals of different classes, except for native;– Pyrite in the group of ore oxides of Fe, Mn, Cr, Ti;– A large group of carbonate minerals;– Feldspars and natrosilite among silicates;– The mineral with CaBr2 composition;– Mono-mineral quartz rims

Mechanisms of fine extinction band development in vein quartz: new insights from correlative light and electron microscopy

Science.gov (United States)

Derez, Tine; Van Der Donck, Tom; Plümper, Oliver; Muchez, Philippe; Pennock, Gill; Drury, Martyn R.; Sintubin, Manuel

2017-07-01

Fine extinction bands (FEBs) (also known as deformation lamellae) visible with polarized light microscopy in quartz consist of a range of nanostructures, inferring different formation processes. Previous transmission electron microscopy studies have shown that most FEB nanostructures in naturally deformed quartz are elongated subgrains formed by recovery of dislocation slip bands. Here we show that three types of FEB nanostructure occur in naturally deformed vein quartz from the low-grade metamorphic High-Ardenne slate belt (Belgium). Prismatic oriented FEBs are defined by bands of dislocation walls. Dauphiné twin boundaries present along the FEB boundaries probably formed after FEB formation. In an example of two sub-rhombohedral oriented FEBs, developed as two sets in one grain, the finer FEB set consists of elongated subgrains, similar to FEBs described in previous transmission electron microscopy studies. The second wider FEB set consists of bands with different dislocation density and fluid-inclusion content. The wider FEB set is interpreted as bands with different plastic strain associated with the primary growth banding of the vein quartz grain. The nanometre-scale fluid inclusions are interpreted to have formed from structurally bounded hydroxyl groups that moreover facilitated formation of the elongate subgrains. Larger fluid inclusions aligned along FEBs are explained by fluid-inclusion redistribution along dislocation cores. The prismatic FEB nanostructure and the relation between FEBs and growth bands have not been recognized before, although related structures have been reported in experimentally deformed quartz.

Lack of inhibiting effect of oil emplacement on quartz cementation: Evidence from Cambrian reservoir sandstones, Paleozoic Baltic Basin

DEFF Research Database (Denmark)

Molenaar, Nicolaas; Cyziene, Jolanta; Sliaupa, Saulius

2008-01-01

Currently, the question of whether or not the presence of oil in sandstone inhibits quartz cementation and preserves porosity is still debated. Data from a number of Cambrian sandstone oil fields and dry fields have been studied to determine the effects of oil emplacement on quartz cementation. T...

Quartz microstructures in the Younger Dryas boundary layer ~12.9 ka.

Science.gov (United States)

van Hoesel, A.; Hoek, W. Z.; Pennock, G. M.; Drury, M. R.

2012-04-01

In 2007, Firestone et al. proposed that an extraterrestrial impact occurred at the end of the Allerød interstadial, destabilizing the North American ice sheet and initiating the colder Younger Dryas (YD) stadial. Up to now, the evidence for this proposed impact has been heavily debated (Pinter et al., 2011) and no one has been able to provide convincing evidence in favour of the hypothesis. Two years later, Mahaney et al. (2009) claimed that they had frequently found planar deformation features (PDFs) in quartz from a possible YD boundary layer in Venezuela. However, the data presented consisted of an SEM image of the surface of a quartz grain only, and in following work Mahaney et al. (2010) stated that they had found no irrefutable evidence of PDFs. Instead, they showed grains with oriented cracks along their edges, which they claimed to be related to the 'mass impact and extreme heat' from incoming ejecta material. However, oriented cracks are not accepted evidence for an impact (French, Koeberl, 2010). We investigate the quartz fraction of samples from the European Usselo horizon, an Allerød-YD age soil, as well as one sample from the North American Black Mat, which marks the onset of the YD. Possible shocked quartz grains were isolated using density separation, mounted in epoxy and polished. No evidence for oriented cracks along grain edges, like those reported by Mahaney et al. (2010), has been found so far. Transmitted light microscopy showed that a number of grains contained tectonic deformation lamellae. One grain from the Usselo horizon contains at least two sets of closely spaced, straight, and narrow lamellae, similar to PDFs. In SEM-CL imaging however, only some of these lamellae showed up as non-luminescent, while most had the same intensity as the host grain. This is not typical for PDFs (Hamers, Drury 2011). It is possible that these lamellae represent planar fractures, which also form by low pressure shock processes. It must be noted that even if

Mass production of CNTs using CVD multi-quartz tubes

Energy Technology Data Exchange (ETDEWEB)

Yousef, Samy; Mohamed, Alaa [Dept. of Production Engineering and Printing Technology, Akhbar Elyom Academy, Giza (Egypt)

2016-11-15

Carbon nanotubes (CNTs) have become the backbone of modern industries, including lightweight and heavy-duty industrial applications. Chemical vapor deposition (CVD) is considered as the most common method used to synthesize high yield CNTs. This work aims to develop the traditional CVD for the mass production of more economical CNTs, meeting the growing CNT demands among consumers by increasing the number of three particular reactors. All reactors housing is connected by small channels to provide the heat exchange possibility between the chambers, thereby decreasing synthesis time and reducing heat losses inside the ceramic body of the furnace. The novel design is simple and cheap with a lower reacting time and heat loss compared with the traditional CVD design. Methane, hydrogen, argon, and catalyzed iron nanoparticles were used as a carbon source and catalyst during the synthesis process. In addition, CNTs were produced using only a single quartz tube for comparison. The produced samples were examined using XRD, TEM, SEM, FTIR, and TGA. The results showed that the yield of CNTs increases by 287 % compared with those synthesized with a single quartz tube. Moreover, the total synthesis time of CNTs decreases by 37 % because of decreased heat leakage.

Study of the relation of the band at 3595 CM{sup -1} in FTIR spectrum of natural quartz with color development by gamma irradiation

Energy Technology Data Exchange (ETDEWEB)

Silva, Helena Cristina M.; Lameiras, Fernando S., E-mail: helenacrisms@gmail.com, E-mail: fsl@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

2015-07-01

Brazil is a major producer of gemological quartz as smoky quartz, morion, citrine, amethyst, and prasiolite. Due to its abundance, hardness, and color varieties, quartz is used in jewelry industry. However, very often quartz is found in nature colorless or with faint colors, which requires exposure to ionizing radiation for color enhancement or development. Not all quartz can develop color. Chromophore chemical elements must be present in suitable proportions for color development after irradiation and heating. Infrared spectrometry is used to separate the quartz that can develop colors from the ones that cannot. Bands in infrared spectrum can indicate the presence and relative contents of chromophore chemical elements, such as aluminum, iron, lithium, sodium, and hydrogen. Some samples of colorless quartz show a band at 3595 cm{sup -1} whose origin is yet not assigned. Samples of quartz with a prominent band at 3595 cm{sup -1} were exposed to gamma rays and heating to observe its behavior. From the statistical point of view, no modification was observed on the position and amplitude of this band after irradiation up 75 kGy and heating to 300-330 deg C. This study should be completed with samples of different origins and higher doses, as well as chemical analyses of trace chemical elements in the samples. (author)

Control of Precambrian basement deformation zones on emplacement of the Laramide Boulder batholith and Butte mining district, Montana, United States

Science.gov (United States)

Berger, Byron R.; Hildenbrand, Thomas G.; O'Neill, J. Michael

2011-01-01

What are the roles of deep Precambrian basement deformation zones in the localization of subsequent shallow-crustal deformation zones and magmas? The Paleoproterozoic Great Falls tectonic zone and its included Boulder batholith (Montana, United States) provide an opportunity to examine the importance of inherited deformation fabrics in batholith emplacement and the localization of magmatic-hydrothermal mineral deposits. Northeast-trending deformation fabrics predominate in the Great Falls tectonic zone, which formed during the suturing of Paleoproterozoic and Archean cratonic masses approximately 1,800 mega-annum (Ma). Subsequent Mesoproterozoic to Neoproterozoic deformation fabrics trend northwest. Following Paleozoic through Early Cretaceous sedimentation, a Late Cretaceous fold-and-thrust belt with associated strike-slip faulting developed across the region, wherein some Proterozoic faults localized thrust faulting, while others were reactivated as strike-slip faults. The 81- to 76-Ma Boulder batholith was emplaced along the reactivated central Paleoproterozoic suture in the Great Falls tectonic zone. Early-stage Boulder batholith plutons were emplaced concurrent with east-directed thrust faulting and localized primarily by northwest-trending strike-slip and related faults. The late-stage Butte Quartz Monzonite pluton was localized in a northeast-trending pull-apart structure that formed behind the active thrust front and is axially symmetric across the underlying northeast-striking Paleoproterozoic fault zone, interpreted as a crustal suture. The modeling of potential-field geophysical data indicates that pull-apart?stage magmas fed into the structure through two funnel-shaped zones beneath the batholith. Renewed magmatic activity in the southern feeder from 66 to 64 Ma led to the formation of two small porphyry-style copper-molybdenum deposits and ensuing world-class polymetallic copper- and silver-bearing veins in the Butte mining district. Vein orientations

Formation of Intermediate Plutonic Rocks by Magma Mixing: the Shoshonite Suite of Timna, Southern Israel.

Science.gov (United States)

Fox, S.; Katzir, Y.

2017-12-01

In magmatic series considered to form by crystal fractionation intermediate rocks are usually much less abundant than expected. Yet, intermediate plutonic rocks, predominantly monzodiorites, are very abundant in the Neoproterozoic Timna igneous complex, S. Israel. A previously unnoticed plutonic shoshonitic suite was recently defined and mapped in Timna (Litvinovsky et al., 2015). It mostly comprises intermediate rocks in a seemingly 'continuous' trend from monzodiorite through monzonite to quartz syenite. Macroscale textures including gradational boundaries of mafic and felsic rocks and MME suggest that magma mixing is central in forming intermediate rocks in Timna. Our petrographic, microtextural and mineral chemistry study delineates the mode of incipient mixing, ultimate mingling and crystal equilibration in hybrid melts. An EMP study of plagioclase from rocks across the suite provides a quantitative evaluation of textures indicative of magma mixing/mingling, including recurrent/patchy zoning, Ca spike, boxy/sponge cellular texture and anti-Rapakivi texture. Each texture has an affinity to a particular mixing region. A modal count of these textures leads to a kinetic mixing model involving multi temporal and spatial scales necessary to form the hybrid intermediate rocks. A `shell'-like model for varying degrees of mixing is developed with the more intensive mixing at the core and more abundant felsic and mafic end-members towards the outer layer. REE patterns in zircon shows that it originated from both mafic and felsic parent melts. Whole rock Fe vs Sr plot suggests a two-stage mixing between the monzogabbro and quartz-syenite producing first mesocratic syenite, and subsequent mixing with a fractionating monzogabbro resulting in monzonitic compositions. A fractionating monzogabbro intruded into a syenitic melt sequentially. While slowly cooling, the monzogabbro heated the immediate syenitic melt, lowering the viscosity and rheological obstruction to overturn

Effects of Metal Ions on the Flotation of Apatite, Dolomite and Quartz

Directory of Open Access Journals (Sweden)

Yaoyang Ruan

2018-04-01

Full Text Available The effects of Ca2+, Mg2+, Al3+, and Fe3+ on the flotation behaviors of apatite, dolomite and quartz were investigated through a micro-flotation test, and the influence of calcium ions on the flotation of these minerals was further elucidated by solution chemistry study, zeta potential measurement, and X-ray photoelectron spectroscopy (XPS analyses. The results indicate that an appropriate amount of Ca2+ and Mg2+ can improve the floatability of apatite but had a negligible effect on the flotation performance of dolomite, whereas Al3+, Fe3+, and excessive amounts of Ca2+ decreased the recovery of apatite and dolomite. The studied metal cations can activate quartz at a particular pH. It can be inferred from solution chemistry and zeta potential measurement that the influence of metal ions on the flotation of different minerals should be attributed to the adsorption of various hydrolysis species on the mineral surfaces. XPS analyses reveal that calcium ions can enhance the adsorption of anionic collector on apatite and quartz surfaces, and there are no apparent changes to be observed on the surface of dolomite in the absence and presence of calcium ions at a concentration of 2.5 × 10−3 M, which was in good agreement with the micro-flotation results.

Theoretical model and optimization of a novel temperature sensor based on quartz tuning fork resonators

International Nuclear Information System (INIS)

Xu Jun; You Bo; Li Xin; Cui Juan

2007-01-01

To accurately measure temperatures, a novel temperature sensor based on a quartz tuning fork resonator has been designed. The principle of the quartz tuning fork temperature sensor is that the resonant frequency of the quartz resonator changes with the variation in temperature. This type of tuning fork resonator has been designed with a new doubly rotated cut work at flexural vibration mode as temperature sensor. The characteristics of the temperature sensor were evaluated and the results sufficiently met the target of development for temperature sensor. The theoretical model for temperature sensing has been developed and built. The sensor structure was analysed by finite element method (FEM) and optimized, including tuning fork geometry, tine electrode pattern and the sensor's elements size. The performance curve of output versus measured temperature is given. The results from theoretical analysis and experiments indicate that the sensor's sensitivity can reach 60 ppm 0 C -1 with the measured temperature range varying from 0 to 100 0 C

Comparative study of the thermoluminescence properties of natural metamorphic quartz belonging to Turkey and Spain

International Nuclear Information System (INIS)

Topaksu, M.; Dogan, T.; Yüksel, M.; Kurt, K.; Topak, Y.; Yegingil, Z.

2014-01-01

The aim of this study is to investigate the sensitization of the thermoluminescence (TL) peak of metamorphic quartzes from Adiyaman in Turkey (TMQ) and from Madrid in Spain (SMQ). Quartz samples of two different origins were β-irradiated between ∼6.689 Gy and 4816 Gy at room temperature. X-ray diffraction analysis has indicated that both TMQ and SMQ have the same crystal structure. Chemical analyses of both TMQ and SMQ were performed using the XRF technique. The preheat processes were carried out at 125 °C for 10 s in the TL measurement. TMQ and SMQ samples have different TL properties in two ways. First TMQ has four first order TL glow peaks while SMQ has five first order TL peaks and secondly, the observed dose sensitivity of TMQ samples is higher than the SMQ samples. - Highlights: • The thermoluminescence (TL) peak of metamorphic quartzes was investigated. • Comparable differences were seen between low and high dose levels. • AD and CGCD methods were used

Shocked quartz in the SEM: Distinction between amorphous and healed PDFs

NARCIS (Netherlands)

Hamers, M.F.; Pennock, G.M.; Drury, M.R.

2012-01-01

Combined SEM techniques show that different CL signatures of PDFs are related to fresh and healed microstructures of PDFs and host quartz. This is confirmed by TEM results. A combination of SEM techniques can give the same type of information as TEM

Timescale of Petrogenetic Processes Recorded in the Mount Perkins Magma System, Northern Colorado River Extension Corridor, Arizona

Science.gov (United States)

Danielson, Lisa R.; Metcalf, Rodney V.; Miller, Calvin F.; Rhodes Gregory T.; Wooden, J. L.

2013-01-01

The Miocene Mt. Perkins Pluton is a small composite intrusive body emplaced in the shallow crust as four separate phases during the earliest stages of crustal extension. Phase 1 (oldest) consists of isotropic hornblende gabbro and a layered cumulate sequence. Phase 2 consists of quartz monzonite to quartz monzodiorite hosting mafic microgranitoid enclaves. Phase 3 is composed of quartz monzonite and is subdivided into mafic enclave-rich zones and enclave-free zones. Phase 4 consists of aphanitic dikes of mafic, intermediate and felsic compositions hosting mafic enclaves. Phases 2-4 enclaves record significant isotopic disequilibrium with surrounding granitoid host rocks, but collectively enclaves and host rocks form a cogenetic suite exhibiting systematic variations in Nd-Sr-Pb isotopes that correlate with major and trace elements. Phases 2-4 record multiple episodes of magma mingling among cogenetic hybrid magmas that formed via magma mixing and fractional crystallization at a deeper crustal. The mafic end-member was alkali basalt similar to nearby 6-4 Ma basalt with enriched OIB-like trace elements and Nd-Sr-Pb isotopes. The felsic end-member was a subalkaline crustal-derived magma. Phase 1 isotropic gabbro exhibits elemental and isotopic compositional variations at relatively constant SiO2, suggesting generation of isotropic gabbro by an open-system process involving two mafic end-members. One end-member is similar in composition to the OIB-like mafic end-member for phases 2-4; the second is similar to nearby 11-8 Ma tholeiite basalt exhibiting low epsilon (sub Nd), and depleted incompatible trace elements. Phase 1 cumulates record in situ fractional crystallization of an OIB-like mafic magma with isotopic evidence of crustal contamination by partial melts generated in adjacent Proterozoic gneiss. The Mt Perkins pluton records a complex history in a lithospheric scale magma system involving two distinct mantle-derived mafic magmas and felsic magma sourced in the

Interaction of radium with fresh water sediments and their mineral components Pt. 1. Ferris hydroxide and quartz

Energy Technology Data Exchange (ETDEWEB)

Benes, P; Strejc, P; Lukavec, Z [Ceske Vysoke Uceni Technicke, Prague (Czechoslovakia). Katedra Jaderne Chemie

1984-05-01

The radiotracer method has been used for investigation of the adsorption and desorption of radium traces on ferric hydroxide and quartz under conditions similar to those prevailing in waste and surface waters. The effects of pH, liquid to solid ratio, ionic strength and presence of Ca/sup 2 +/ or SO/sub 4//sup 2 -/ ions have been studied. It is concluded that at pH less than 7 and at concentration of suspended sediments of common composition less than 100 mg.1/sup -1/, ferric hydroxide and quartz have negligible effect on the state and migration of radium in surface waters. Radium adsorbed on quartz can be easily desorbed with dilute solutions of hydrochloric acid or sodium chloride. 14 refs.

The E{sub 1}'-centre and its role in TL sensitization in quartz

Energy Technology Data Exchange (ETDEWEB)

Benny, P.G. E-mail: sunsab@magnum.barc.ernet.in; Gundu Rao, T.K.; Bhatt, B.C

2002-08-01

The effect of UV (253.7 nm) bleaching and subsequent thermal annealing treatment in the range 400-500 deg. C, were studied in order to investigate the role of E{sub 1}'-centre on sensitization of 110 deg. C and 220 deg. C peaks in quartz. The decay of E{sub 1}'-centre in thermal annealed samples and observation of E{sub 1}'-centres after UV bleach, accompanied by desensitization of TL in the quartz sample, appears to lend support to the role of competing traps and E{sub 1}'-centres in the sensitization process.

Effect of foamability index of short chain alkyl amines on flotation of quartz

Directory of Open Access Journals (Sweden)

Szczerkowska Sabina

2016-01-01

Full Text Available Amines can be used for flotation of various minerals, especially quartz. The flotation efficiency of quartz depends on the amine type and dose. It was proved that the shorter alkyl amine, higher amine concentration has to be used to recover quartz at the same level. In flotation amines play a role of both collectors and frothers. The ability of a amine to collect particles can be expressed in the form of contact angle, while the foaming properties by different parameters including dynamic foamability index (DFI and critical coalescence concentration (CCC. Determination of DFI and CCC requires advanced techniques and methods. Therefore, in this paper a rapid and facile method for determination of foaming properties of amines and also other surfactants was used. It was based on measuring the initial foam and froth heights in a conventional flotation machine at different concentrations of surfactants. The foam height-concentration curve was described by utilizing an empirical equation which was based on one-adjustable parameter called the foamability index (FI. In this work the foamability index was determined for butylamine (ButNH2, hexylamine (HexNH2 and octylamine (OctNH2 as examples of short chain alkyl amines. The determined foamability indices were 92, 12 and 4 mg/dm3 for ButNH2, HexNH2 and OctNH2, respectively. It was shown that when the flotation results of quartz were presented in the form of recovery versus normalized amine concentration in relation to the foamability index (c/FI, all the experimental data points converged to one curve. It indicates that amines act similarly but at different concentrations expressed as FI. The foamability index seems to be a useful parameter for characterizing any flotation frother.

Luminescence of quartz and feldspar fingerprints provenance and correlates with the source area denudation in the Amazon River basin

Science.gov (United States)

Sawakuchi, A. O.; Jain, M.; Mineli, T. D.; Nogueira, L.; Bertassoli, D. J.; Häggi, C.; Sawakuchi, H. O.; Pupim, F. N.; Grohmann, C. H.; Chiessi, C. M.; Zabel, M.; Mulitza, S.; Mazoca, C. E. M.; Cunha, D. F.

2018-06-01

The Amazon region hosts the world's largest watershed spanning from high elevation Andean terrains to lowland cratonic shield areas in tropical South America. This study explores variations in optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL) signals in suspended silt and riverbed sands retrieved from major Amazon rivers. These rivers drain Pre-Cambrian to Cenozoic source rocks in areas with contrasting denudation rates. In contrast to the previous studies, we do not observe an increase in the OSL sensitivity of quartz with transport distance; for example, Tapajós and Xingu Rivers show more sensitive quartz than Solimões and Madeira Rivers, even though the latter have a significantly larger catchment area and longer sediment transport distance. Interestingly, high sensitivity quartz is observed in rivers draining relatively stable Central Brazil and Guiana shield areas (denudation rate ξ = 0.04 mmyr-1), while low sensitivity quartz occurs in less stable Andean terrains (ξ = 0.24 mmyr-1). An apparent linear correlation between quartz OSL sensitivity and denudation rate suggests that OSL sensitivity may be used as a proxy for erosion rates in the Amazon basin. Furthermore, luminescence sensitivity measured in sand or silt arises from the same mineral components (quartz and feldspar) and clearly discriminates between Andean and shield sediments, avoiding the grain size bias in provenance analysis. These results have implications for using luminescence sensitivity as a proxy for Andean and shield contributions in the stratigraphic record, providing a new tool to reconstruct past drainage configurations within the Amazon basin.

Quartz fast component opticallystimulated luminescence: Towards routine extraction for dating applications

International Nuclear Information System (INIS)

Shen, Zhixiong; Lang, Andreas

2016-01-01

Using an uncontaminated fast component is a key for improving the reliability of quartz OSL dating for many deposits. So far no approach to extract the fast component of quartz OSL has routinely been adopted for dating practice. Key challenges for extracting fast components are (1) the difficulty of finding a unique solution in curve-fitting deconvolution of OSL decay curves and (2) the relatively poor dating precision when using experimental fast component extraction. Here, a simple mathematic solution for fast component extraction is presented that is not relying on curve-fitting deconvolution and can easily be adopted into routine dating practices. By using specifically selected data points from smoothed OSL decay curves, the precision of equivalent doses calculated using the extracted fast component can be improved over equivalent doses calculated using bulk OSL. The fast component extraction is tested on a group of age-constrained samples containing both insufficiently bleached and sufficiently bleached deposits. Fast component OSL ages are as accurate as bulk OSL ages for the sufficiently bleached deposits, but more accurate for samples where bulk OSL is affected by insufficient bleaching. We also demonstrate how using a curve smoothing procedure can improve dating precision in case of both sufficiently and insufficiently bleached deposits. - Highlights: • A simple mathematical method to extract quartz OSL fast component is presented. • The method can be adopted in D_e calculation programs for routine extraction. • The method leads to an increase in accuracy and precision of D_e. • The method works for relatively dim samples with low signal-to-noise ratios.

Characterization and Gravimetric Analysis of the Dissolved Quartz in the Conversion of Coal Fly Ash to Sodalite

International Nuclear Information System (INIS)

Mohd Hilmi Mohamed; Zainab Ramli

2012-01-01

Coal fly ash (CFA) is a waste product produced from the electrical power plant and hazardous towards the environment. However, the high composition of silica and alumina in the CFA makes it useful as raw materials in the zeolite synthesis. However, the presence of silica in the form of quartz in the CFA does not facilitate the transformation of CFA to zeolite at 100 degree Celsius and autogeneous pressure. In this study, CFA was converted to zeolites in various NaOH concentrations by microwave heating at various heating time. All synthesized product were characterized by X-ray diffraction (XRD), and gravimetric analysis. XRD has shown that quite pure sodalite in nano size has been formed as early as 15 minutes and increase with time. Prolong heating up to 45 minutes has reduced the content of quartz to ca 20 %. Gravimetric analysis performed on the liquor of the reaction showed that the dissolved silica decrease with increase of heating time indicating that most of the dissolved quartz is used up to form sodalite framework. Hence, quartz of CFA did help in enhancing the crystallinity of the formed sodalite after prolong heating. (author)

Interlaboratory beta source calibration using TL and OSL on natural quartz

DEFF Research Database (Denmark)

Goksu. H.Y.; Bailiff, I.K.; Bøtter-Jensen, L.

1995-01-01

Laboratory at GSF using a Go-60 source as well as the in situ measurements with an ionization chamber, calibrated to the primary standards of PTB Braunschweig. Irradiated and unirradiated quartz was distributed to the five laboratories and although different procedures were used for thermoluminescence...

Thickness shear mode quartz crystal resonators with optimized elliptical electrodes

International Nuclear Information System (INIS)

Ma Ting-Feng; Feng Guan-Ping; Zhang Chao; Jiang Xiao-Ning

2011-01-01

Quartz crystal resonators (QCRs) with circular electrodes have been widely used for various liquid and gas sensing applications. In this work, quartz crystal resonators with elliptical electrodes were studied and tested for liquid property measurement. Mindlin's theory was used to optimize the dimension and geometry of the electrodes and a 5-MHz QCR with minimum series resistance and without any spurious modes was obtained. A series of AT-cut QCRs with elliptical electrodes of different sizes were fabricated and their sensing performances were compared to devices with circular electrodes. The experimental result shows that the device with elliptical electrodes can obtain lower resonance impedance and a higher Q factor, which results in a better loading capability. Even though the sensitivities of devices with elliptical and circular electrodes are found to be similar, the sensor with elliptical electrodes has much higher resolution due to a better frequency stability. The study indicates that the performance of QCRs with elliptical electrodes is superior to that of traditional QCRs with circular electrodes. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

The composite nature of the thermoluminescence UV emission of quartz

Energy Technology Data Exchange (ETDEWEB)

Fasoli, Mauro, E-mail: mauro.fasoli@mater.unimib.it [Dipartimento di Scienza dei Materiali, Università degli Studi di Milano Bicocca, via R. Cozzi 55, I-20125 Milano (Italy); INFN, Sezione di Milano Bicocca, Piazza della Scienza 1, I-20126 Milano (Italy); Martini, Marco [Dipartimento di Scienza dei Materiali, Università degli Studi di Milano Bicocca, via R. Cozzi 55, I-20125 Milano (Italy); INFN, Sezione di Milano Bicocca, Piazza della Scienza 1, I-20126 Milano (Italy)

2016-05-15

The radioluminescence (RL) spectra of three types of quartz have been compared to those obtained from wavelength resolved thermally stimulated luminescence (TSL) measurements. A detailed numerical deconvolution into Gaussian components allowed to identify which of the bands are involved in either types of luminescence processes. The blue “A band” at 2.51 eV was confirmed to dominate both RL and TSL spectra in samples exposed to prolonged irradiation. The UV emission of the 110 °C TSL peak was found to be composite. Analogously to what previously reported for RL spectra, an annealing at 500 °C for 10 min induced a strong enhancement of the “C band” at 3.42 eV. This effect was particularly evident in natural and pre-irradiated quartz. A second intense UV component, the “M band” at 3.7 eV, was found to contribute to both TSL and RL spectra of samples annealed at 1000 °C for 10 min. A further broad UV emission seems to be involved only in RL emission but not in the TSL one.

Resetting of Quartz OSL (optically stimulated luminescence) Signals by Frictional Heating in Experimentally Sheared Gouges at Seismic Slip Rates.

Science.gov (United States)

Kim, J. H.; Choi, J. H.; Chauhan, N.; Lee, S.; Hirose, T.; Ree, J. H.

2014-12-01

Recent studies on natural and experimental seismic faults have revealed that frictional heating plays an important role in earthquake dynamics as well as in producing mineralogical and microstructural signatures of seismic faulting. Here, we report changes in OSL signals in quartz by frictional heating in experimental fault gouges. The gouges (80% of quartz and 20% of bentonite by weight) with a thickness of 1 mm were sheared between sandstone cylinders (diameter: 25 mm) at a normal stress of 1 MPa and slip rate of 1.31 m/s. The quartz grains from a sand dune on the western coast of South Korea were sieved to select size fractions between 90 and 250 μm. The equivalent dose (De) of the undeformed quartz grains was 8.0 ± 0.3 Gy. Upon displacement, the friction abruptly increases to the 1st peak (with friction coefficient μ ≈ 0.75) followed by slip weakening. Then the fault zones show two more peak frictions (μ ≈ 0.53~0.75) and finally reach a steady-state friction (μ ≈ 0.2~0.35). The fault can be divided into three zones based grain size (thus slip rate); slip localization (SLZ), intermediate slip-rate (ISZ) and low slip-rate (LSZ) zones. SLZ develops adjacent to the moving side of the sandstone cylinder with P-foliation and shear band. The size of quartz (Dq) in ISZ and LSZ is 5-30 μm and 50-250 μm, respectively. SEM and TEM analyses indicate that the fault gouge of SLZ consists of subangular quartz clasts (Dq ≈ 3 μm) and matrix of nano-scale quartz, unidentified silicate minerals and amorphous material. The fault zones were sectioned into six layers (~160 µm thick for each layer) parallel to the fault zone boundary for OSL analyses. Quartz grains from all the layers except the one immediately adjacent to the stationary side of the sandstone cylinder show De of 'effectively' 0 Gy indicating a full resetting of OSL signals. The partial resetting of OSL signal in the layer adjacent to the stationary side of the cylinder indicates the temperature (T

Origin of dioritic magma and its contribution to porphyry Cu-Au mineralization at Pulang in the Yidun arc, eastern Tibet

Science.gov (United States)

Cao, Kang; Yang, Zhi-Ming; Xu, Ji-Feng; Fu, Bin; Li, Wei-Kai; Sun, Mao-Yu

2018-04-01

The giant Pulang porphyry Cu-Au deposit in the Yidun arc, eastern Tibet, formed due to westward subduction of the Garze-Litang oceanic plate in the Late Triassic. The deposit is hosted in an intrusive complex comprising primarily coarse-grained quartz diorite and cored quartz monzonite. Here, we investigate a suite of simultaneous (216.6 ± 1.9 Ma) diorite porphyries within the complex. The diorite porphyries are geochemically similar to mafic magmatic enclaves (MME) hosted in coarse-grained quartz diorite, and both are characterized by low SiO2 (59.4-63.0 wt%) and high total alkali (Na2O + K2O = 7.0-9.2 wt%), K2O (3.5-6.4 wt%), MgO (3.2-5.5 wt%), and compatible trace element (e.g., Cr = 72-149 ppm) concentrations. They are enriched in large-ion lithophile and light rare earth elements (LILE and LREE, respectively), but depleted in high field-strength and heavy rare earth elements (HFSE and HREE, respectively), and yield variably high (La/Yb)N ratios (17-126, average 65) with weak to negligible Eu anomalies. Furthermore, they yield low (87Sr/86Sr)i ratios (0.7054-0.7067), weakly negative εNd(t) (-2.8 to -0.8) values, and variable zircon εHf(t) (-5.4 to +0.8) and δ18O (6.0‰-6.7‰) values. These geochemical features indicate that the diorite porphyry and MME formed through crustal assimilation of a magma produced during low-degree partial melting of metasomatized phlogopite-rich subcontinental lithospheric mantle. In contrast, the coarse-grained quartz diorite and quartz monzonite have relatively high concentrations of SiO2 (61.1-65.3 wt%), K2O (4.1-5.4 wt%), and total alkali (Na2O + K2O = 7.1-8.1 wt%), and low concentrations of MgO (generally Y ratios (50-63) that indicate an adakitic affinity, and are enriched in LILE, depleted in HFSE, and yield lower (La/Yb)N values (13-20, average 17) than the diorite porphyry and MME. They yield low (87Sr/86Sr)i ratios (0.7046-0.7066), negative εNd(t) (-3.3 to -1.7) values, and zircon εHf(t) and δ18O values of -2.9 to

Pressure-induced drastic collapse of a high oxygen coordination shell in quartz-like α-GeO2

International Nuclear Information System (INIS)

Dong, Juncai; Zhang, Xiaoli; Wu, Ziyu; Chen, Dongliang; Zhang, Qian; Wu, Ye; Wu, Xiang

2014-01-01

With the combination of a single crystal diamond anvil cell and a polycapillary half-lens, the local structural evolution around germanium in tetrahedrally networked quartz-like α-GeO 2 has been investigated using extended x-ray absorption fine structure spectroscopy of up to 14 GPa by multiple-scattering analysis method. While the first shell Ge–O bond distances show a slight contraction with increasing pressure, the third shell Ge–O bond distances are found to decrease dramatically. The sluggish lengthening of the first shell Ge–O bond distances, initiated by coordination increase from fourfold to sixfold, occurs in the 7–14 GPa range just when the third shell Ge–O bond distances fall in the region of the second shell Ge–Ge bond distances. Moreover, these features are accompanied by the closing of intertetrahedral Ge–O–Ge angles and the opening of two intratetrahedral O–Ge–O angles, whose topological configuration surprisingly exhibits a helical chirality along the c axis that is opposite to the double helices of the corner-linked GeO 4 tetrahedra. These results suggest that the high-pressure phase transitions in quartz and quartz-like materials could be associated with a structural instability that is driven by the drastic collapse of the next-nearest-neighbour anion shell, which is consistent with the emergence of high-symmetry anion sublattice. Our findings provide crucial insights into the densification mechanisms of quartz-like oxides, which would have broad implications for our understanding of the metastability of various post-quartz crystalline phases and pressure-induced amorphization. (paper)

Installation and evaluation of weigh-in-motion utilizing quartz-piezo sensor technology.

Science.gov (United States)

2016-06-28

The objective of the research study was: to install a quartz-piezo based WIM system, and to : determine sensor survivability, accuracy and reliability under actual traffic conditions in : Connecticuts environment. If the systems prove dependable a...

Note: a transimpedance amplifier for remotely located quartz tuning forks.

Science.gov (United States)

Kleinbaum, Ethan; Csáthy, Gábor A

2012-12-01

The cable capacitance in cryogenic and high vacuum applications of quartz tuning forks imposes severe constraints on the bandwidth and noise performance of the measurement. We present a single stage low noise transimpedance amplifier with a bandwidth exceeding 1 MHz and provide an in-depth analysis of the dependence of the amplifier parameters on the cable capacitance.

Retrospective dosimetry using Japanese brick quartz: A way forward despite an unstable fast decaying OSL signal

DEFF Research Database (Denmark)

Fujita, Hiroki; Jain, Mayank; Murray, A.S.

2011-01-01

signals has been carried out towards identification of common source traps. It is observed that OSL from Japanese brick quartz shows unusual luminescence characteristics; in particular, the initial fast decaying OSL signal contains a dominant (>90%) thermally unstable component related to the 85 °C TL...... peak, which necessitates a prior heat treatment. A single-aliquot regenerative-dose (SAR) protocol is developed and tested using thermal treatments intended to isolate a stable dosimetric signal. A minimum detection limit of 65 mGy is then estimated using this protocol. Following irradiation using 60Co...... of Japanese brick quartz examined here can be used to derive precise estimates of accident dose, and, possibly to distinguish between sources of gamma radiation in a nuclear accident. To our knowledge, this is the first report on the existence of an unstable fast decaying OSL signal in quartz derived from...

The Efficiency of Quartz Particles Evaporation in the Argon Plasma Flow of the RF Inductively Coupled Plasma Torch

Directory of Open Access Journals (Sweden)

Yu. M. Grishin

2017-01-01

Full Text Available Owing to high-power density and high-purity plasma, a RF inductively coupled plasma torch (ICPT is widely used both in research laboratory and in industry. The potential RF ICPT application areas are powders spheroidisation, waste treatment, thermal spraying, etc.In the last decade the investigation was focused on the treatment processes of quartz into polycrystalline silicon. An analysis of these results has shown that the increasing productivity and producing high-purity silicon can be achieved only when using the electrodeless radio-frequency induction plasma torches and in case the optimum conditions for evaporation of SiO2solid particles are realized.Optimization of the RF ICPT design and power parameters calls for a wide range of computational studies. In spite of the fact that to date a large number of efforts to calculate the evaporation efficiency of powder materials have been made, a number of issues, as applied to the problem of obtaining silicon, require further research.In this paper, we present the results of a two-dimensional numerical simulation of the heating and evaporation of quartz particles in the RF ICPT channel with axial flow of gases. The main aim is to determine how the axial position of the central tube (through which the particles are injected into the discharge zone, the dispersion of the quartz powder, the amplitude of the discharge current (and, respectively, flow regimes impact on the evaporation efficiency of quartz particles.The paper presented the numerical modeling results of heating and evaporation processes of quartz particles supplied by transporting gas to the RF ICPT channel with axial gas flow (argon. Defined the impact of the axial position of the central tube, the plasma flow regime, the discharge current, the flow rate of transporting gas, and other parameters on the evaporation efficiency of quartz particles.It is shown that the evaporation efficiency of particles reaches its maximum when their

Titanium zoning and diffusion chronometry reveal dynamic and late-stage quartz growth in the Youngest Toba Tuff, Indonesia

Science.gov (United States)

Tierney, C. R.; Reid, M. R.; Burns, D. H.; Costa Rodriguez, F.; Chesner, C. A.

2017-12-01

The enormous 74 ka Youngest Toba Tuff (YTT) ejected 2800 km3 of compositionally zoned (68-77 wt.% SiO2) ignimbrite and co-ignimbrite ash. Titanium zoning within YTT quartz records a dynamic growth history, and sometimes concludes with a final growth stage under different conditions. We investigated the timescales of quartz growth using diffusion chronometry, and determined whether the last stage of crystallization was the result of a discrete and chamber-wide magmatic event. This work offers insight into the dynamics and timescales of storage and remobilization of voluminous silicic magmas - an important consideration for hazards assessment. High-resolution (1 µm steps) hyperspectral CL was mapped from 5-20 quartz crystals from each of five pumices spanning the YTT compositional spectrum. CL intensity was calibrated to Ti concentration via EPMA, and numerically modeled time-dependent diffusional relaxation curves where fit to concentration profiles across zone boundaries. CL-bright/high-Ti rims are found in quartz from all samples, but become less common and have lower Ti concentrations with increasing host pumice silica content (e.g., 70 ppm vs 50 ppm). Some large crystals contain distinct CL-bright interior zones with similar Ti concentration to the rims. Onset of growth of CL-bright rims commenced between 15 and 100 years before eruption, and interior bands between 30 and 1500 years. Neither rim nor interior ages correlate significantly with host pumice silica. Rim growth on quartz evidently occurred closer to eruption than a previous estimate of several decades to centuries for quartz from a single YTT pumice (Matthews et al., 2012). The similar timing for the onset of high-Ti quartz rim growth across all samples suggests a marked and temporally discrete magmatic event in the years to decades prior to eruption and may be recording the chamber-wide influence of magmatic recharge or remobilization. High-Ti interior zones likely record older recharge events that

Cathodoluminescence, fluid inclusions and trace element data for the syntaxial quartz cementation in the sandstones of Ora Formation, northern Iraq

DEFF Research Database (Denmark)

Omer, Muhamed Fakhri; Friis, Henrik

2018-01-01

Quartz cements of the quartz arenitic sandstones from the Chalky Nasara and Ora section of the (Devonian-Carboniferous) Ora Formation in northern Iraq have been studied. A combination of Hot-Cathodoluminescence (CL), LA-ICP-MS and fluid inclusions microthermometry revealed three syntaxial quartz......-bedded sandstones than in the6 thickly-bedded sandstones filling most of remaining pore space during mesogenesis. The Q3 was formed during early telogenesis stage fully cementing the sandstones and the fractures were filled by hydrothermal chlorite and sulfides. Significant amount of trace elements Al, Li, Ge...

Modelling the thermal quenching mechanism in quartz based on time-resolved optically stimulated luminescence

International Nuclear Information System (INIS)

Pagonis, V.; Ankjaergaard, C.; Murray, A.S.; Jain, M.; Chen, R.; Lawless, J.; Greilich, S.

2010-01-01

This paper presents a new numerical model for thermal quenching in quartz, based on the previously suggested Mott-Seitz mechanism. In the model electrons from a dosimetric trap are raised by optical or thermal stimulation into the conduction band, followed by an electronic transition from the conduction band into an excited state of the recombination center. Subsequently electrons in this excited state undergo either a direct radiative transition into a recombination center, or a competing thermally assisted non-radiative process into the ground state of the recombination center. As the temperature of the sample is increased, more electrons are removed from the excited state via the non-radiative pathway. This reduction in the number of available electrons leads to both a decrease of the intensity of the luminescence signal and to a simultaneous decrease of the luminescence lifetime. Several simulations are carried out of time-resolved optically stimulated luminescence (TR-OSL) experiments, in which the temperature dependence of luminescence lifetimes in quartz is studied as a function of the stimulation temperature. Good quantitative agreement is found between the simulation results and new experimental data obtained using a single-aliquot procedure on a sedimentary quartz sample.

Investigation on nonlinear optical properties of MoS2 nanoflake, grown on silicon and quartz substrates

Science.gov (United States)

Bayesteh, S.; Mortazavi, S. Z.; Reyhani, A.

2018-03-01

In this study, MoS2 was directly synthesized by one-step thermal chemical vapour deposition (TCVD), on different substrates including Si/SiO2 and quartz, using MoO3 and sulfide powders as precursor. The XRD patterns demonstrate the high crystallinity of MoS2 on Si/SiO2 and quartz substrates. SEM confirmed the formation of MoS2 grown on both substrates. According to line width and frequency difference between the E1 2g and A1g in Raman spectroscopy, it is inferred that the MoS2 grown on Si/SiO2 substrate is monolayer and the MoS2 grown on quartz substrate is multilayer. Moreover, by assessment of MoS2 nanoflake band gap via UV-visible analysis, it verified the formation of few layer structures. In addition, the open-aperture and close-aperture Z-scan techniques were employed to study the nonlinear optical properties including nonlinear absorption and nonlinear refraction of the synthesized MoS2. All experiments were performed using a diode laser with a wavelength of 532 nm as light source. The monolayer MoS2 synthesized on Si/SiO2, display considerable two-photon absorption. However, the multilayer MoS2 synthesized on quartz displayed saturable absorption (SA). It is noticeable that both samples demonstrate obvious self-defocusing behaviour.

Measurement of temperature fields in specimens of quartz ceramic during surface ablation

Science.gov (United States)

Frolov, G. A.; Pasichnyi, V. V.; Suzdal'Tsev, E. I.; Tsyganenko, V. S.

1989-08-01

The authors propose a method of mounting thermocouples and have obtained temperature fields within specimens of pure and doped quartz ceramic. The linearity of the dependenceΔ * = fleft( {sqrt tau } right) for deep isotherms has been proved experimentally.

A comprehensive comparative study of the pre-dose effect for three quartz crystals of different origin

International Nuclear Information System (INIS)

Kitis, G.; Pagonis, V.; Chen, R.; Polymeris, G.

2006-01-01

The study of the thermoluminescence (TL) sensitivity of quartz due to heat and irradiation treatments is of importance in dating and retrospective dosimetry. A comprehensive comparative study of the pre-dose effect was carried out for three types of quartz of different origin. Complete TL vs. dose and sensitivity S vs. pre-dose curves were obtained for the dose range of 0.1 < D < 400 Gy. Additional complete sensitivity vs. pre-dose curves were obtained for samples which underwent a combined pre-dose irradiation and a subsequent heat treatment to 500 deg. C. Although the TL vs. dose curves showed very different behaviours, the sensitivity vs. pre-dose curves showed several common characteristics. The sensitivity vs. pre-dose curves showed abrupt changes ∼10 Gy. The sensitivity after a combined pre-dose irradiation and heat treatment to 500 deg. C showed a very gradual change in the whole dose range studied. These results are explained qualitatively by using the modified Zimmerman model for quartz. (authors)

Quartz-coesite-stishovite relations in shocked metaquartzites from the Vredefort impact structure, South Africa

Science.gov (United States)

Spray, John G.; Boonsue, Suporn

2018-01-01

Coesite and stishovite are developed in shock veins within metaquartzites beyond a radius of 30 km from the center of the 2.02 Ga Vredefort impact structure. This work focuses on deploying analytical field emission scanning electron microscopy, electron backscattered diffraction, and Raman spectrometry to better understand the temporal and spatial relations of these silica polymorphs. α-Quartz in the host metaquartzites, away from shock veins, exhibits planar features, Brazil twins, and decorated planar deformation features, indicating a primary (bulk) shock loading of >5 < 35 GPa. Within the shock veins, coesite forms anhedral grains, ranging in size from 0.5 to 4 μm, with an average of 1.25 μm. It occurs in clasts, where it displays a distinct jigsaw texture, indicative of partial reversion to a less dense SiO2 phase, now represented by microcrystalline quartz. It is also developed in the matrix of the shock veins, where it is typically of smaller size (<1 μm). Stishovite occurs as euhedral acicular crystals, typically <0.5 μm wide and up to 15 μm in length, associated with clast-matrix or shock vein margin-matrix interfaces. In this context, the needles occur as radiating or subparallel clusters, which grow into/over both coesite and what is now microcrystalline quartz. Stishovite also occurs as more blebby, subhedral to anhedral grains in the vein matrix (typically <1 μm). We propose a model for the evolution of the veins (1) precursory frictional melting in a microfault ( 1 mm wide) generates a molten matrix containing quartz clasts. This is followed by (2) arrival of the main shock front, which shocks to 35 GPa. This generates coesite in the clasts and in the matrix. (3) On initial shock release, the coesite partly reverts to a less dense SiO2 phase, which is now represented by microcrystalline quartz. (4) With continued release, stishovite forms euhedral needle clusters at solid-liquid interfaces and as anhedral crystals in the matrix. (5) With

Improvement of the thickness distribution of a quartz crystal wafer by numerically controlled plasma chemical vaporization machining

International Nuclear Information System (INIS)

Shibahara, Masafumi; Yamamura, Kazuya; Sano, Yasuhisa; Sugiyama, Tsuyoshi; Endo, Katsuyoshi; Mori, Yuzo

2005-01-01

To improve the thickness uniformity of thin quartz crystal wafer, a new machining process that utilizes an atmospheric pressure plasma was developed. In an atmospheric pressure plasma process, since the kinetic energy of ions that impinge to the wafer surface is small and the density of the reactive species is large, high-efficiency machining without damage is realized, and the thickness distribution is corrected by numerically controlled scanning of the quartz wafer to the localized high-density plasma. By using our developed machining process, the thickness distribution of an AT cut wafer was improved from 174 nm [peak to valley (p-v)] to 67 nm (p-v) within 94 s. Since there are no unwanted spurious modes in the machined quartz wafer, it was proved that the developed machining method has a high machining efficiency without any damage

Spatial variation in deposition rate coefficients of an adhesion-deficient bacterial strain in quartz sand.

Science.gov (United States)

Tong, Meiping; Camesano, Terri A; Johnson, William P

2005-05-15

The transport of bacterial strain DA001 was examined in packed quartz sand under a variety of environmentally relevant ionic strength and flow conditions. Under all conditions, the retained bacterial concentrations decreased with distance from the column inlet at a rate that was faster than loglinear, indicating that the deposition rate coefficient decreased with increasing transport distance. The hyperexponential retained profile contrasted againstthe nonmonotonic retained profiles that had been previously observed for this same bacterial strain in glass bead porous media, demonstrating that the form of deviation from log-linear behavior is highly sensitive to system conditions. The deposition rate constants in quartz sand were orders of magnitude below those expected from filtration theory, even in the absence of electrostatic energy barriers. The degree of hyperexponential deviation of the retained profiles from loglinear behavior did not decrease with increasing ionic strength in quartz sand. These observations demonstrate thatthe observed low adhesion and deviation from log-linear behavior was not driven by electrostatic repulsion. Measurements of the interaction forces between DA001 cells and the silicon nitride tip of an atomic force microscope (AFM) showed that the bacterium possesses surface polymers with an average equilibrium length of 59.8 nm. AFM adhesion force measurements revealed low adhesion affinities between silicon nitride and DA001 polymers with approximately 95% of adhesion forces having magnitudes responsible for the low adhesion to silicon nitride, indicating that steric interactions from extracellular polymers controlled DA001 adhesion deficiency and deviation from log-linear behavior on quartz sand.

Sensitivity of Clay Suspension Rheological Properties to pH, Temperature, Salinity, and Smectite-Quartz Ratio

Science.gov (United States)

Kameda, Jun; Morisaki, Tomonori

2017-10-01

Understanding the rheological properties of clay suspensions is critical to assessing the behavior of sediment gravity flows such as debris flow or turbidity current. We conducted rheological measurements of composite smectite-quartz suspensions at a temperature of 7°C and a salt concentration of 0.6 M. This is representative of smectite-bearing sediments under conditions on the seafloor. The flow curves obtained were fitted by the Bingham fluid model, from which we determined the Bingham yield stress and dynamic viscosity of each suspension. At a constant smectite-quartz mixing ratio, the yield stress and the dynamic viscosity tend to increase as the solid/water ratio of the suspension is increased. In the case of a constant solid/water ratio, these values increase with increasing smectite content in the smectite-quartz mixture. Additional experiments exploring differing physicochemical conditions (pH 1.0-9.0; temperature 2-30°C; and electrolyte (NaCl) concentration 0.2-0.6 M) revealed that the influence of temperature is negligible, while pH moderately affects the rheology of the suspension. More significantly, the electrolyte concentration greatly affects the flow behavior. These variations can be explained by direct and/or indirect (double-layer) interactions between smectite-smectite particles as well as between smectite-quartz particles in the suspension. Although smectite is known as a frictionally weak material, our experimental results suggest that its occurrence can reduce the likelihood that slope failure initiates. Furthermore, smectite can effectively suppress the spreading distance once the slope has failed.

Association of antibiotic resistance in agricultural Escherichia coli isolates with attachment to quartz.

Science.gov (United States)

Liu, Ping; Soupir, Michelle L; Zwonitzer, Martha; Huss, Bridgette; Jarboe, Laura R

2011-10-01

Surface water can be contaminated by bacteria from various sources, including manure from agricultural facilities. Attachment of these bacteria to soil and organic particles contributes to their transport through the environment, though the mechanism of attachment is unknown. As bacterial attachment to human tissues is known to be correlated with antibiotic resistance, we have investigated here the relationship between bacterial attachment to environmental particles and antibiotic resistance in agricultural isolates. We evaluated 203 Escherichia coli isolates collected from swine facilities for attachment to quartz, resistance to 13 antibiotics, and the presence of genes encoding 13 attachment factors. The genes encoding type I, EcpA, P pili, and Ag43 were detected, though none was significantly related to attachment. Quartz attachment was positively and significantly (P amoxicillin/streptomycin/tetracycline/sulfamethazine/tylosin/chlortetracycline and negatively and significantly (P < 0.0038) related to combined resistance to nalidixic acid/kanamycin/neomycin. These results provide clear evidence for a link between antibiotic resistance and attachment to quartz in agricultural isolates. We propose that this may be due to encoding by the responsible genes on a mobile genetic element. Further exploration of the relationship between antibiotic resistance and attachment to environmental particles will improve the understanding and modeling of environmental transport processes, with the goal of preventing human exposure to antibiotic-resistant or virulent microorganisms.

Extremely high Q-factor mechanical modes in quartz bulk acoustic wave resonators at millikelvin temperature

Energy Technology Data Exchange (ETDEWEB)

Goryachev, M.; Creedon, D. L.; Ivanov, E. N.; Tobar, M. E. [ARC Centre of Excellence for Engineered Quantum Systems, University of Western Australia, 35 Stirling Highway, Crawley WA 6009 (Australia); Galliou, S.; Bourquin, R. [Department of Time and Frequency, FEMTO-ST Institute, ENSMM, 26 Chemin de l' Épitaphe, 25000, Besançon (France)

2014-12-04

We demonstrate that Bulk Acoustic Wave (BAW) quartz resonator cooled down to millikelvin temperatures are excellent building blocks for hybrid quantum systems with extremely long coherence times. Two overtones of the longitudinal mode at frequencies of 15.6 and 65.4 MHz demonstrate a maximum f.Q product of 7.8×10{sup 16} Hz. With this result, the Q-factor in such devices near the quantum ground state can be four orders of magnitude better than previously attained in other mechanical systems. Tested quartz resonators possess the ultra low acoustic losses crucial for electromagnetic cooling to the phonon ground state.

Density-viscosity product of small-volume ionic liquid samples using quartz crystal impedance analysis.

Science.gov (United States)

McHale, Glen; Hardacre, Chris; Ge, Rile; Doy, Nicola; Allen, Ray W K; MacInnes, Jordan M; Bown, Mark R; Newton, Michael I

2008-08-01

Quartz crystal impedance analysis has been developed as a technique to assess whether room-temperature ionic liquids are Newtonian fluids and as a small-volume method for determining the values of their viscosity-density product, rho eta. Changes in the impedance spectrum of a 5-MHz fundamental frequency quartz crystal induced by a water-miscible room-temperature ionic liquid, 1-butyl-3-methylimiclazolium trifluoromethylsulfonate ([C4mim][OTf]), were measured. From coupled frequency shift and bandwidth changes as the concentration was varied from 0 to 100% ionic liquid, it was determined that this liquid provided a Newtonian response. A second water-immiscible ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide [C4mim][NTf2], with concentration varied using methanol, was tested and also found to provide a Newtonian response. In both cases, the values of the square root of the viscosity-density product deduced from the small-volume quartz crystal technique were consistent with those measured using a viscometer and density meter. The third harmonic of the crystal was found to provide the closest agreement between the two measurement methods; the pure ionic liquids had the largest difference of approximately 10%. In addition, 18 pure ionic liquids were tested, and for 11 of these, good-quality frequency shift and bandwidth data were obtained; these 12 all had a Newtonian response. The frequency shift of the third harmonic was found to vary linearly with square root of viscosity-density product of the pure ionic liquids up to a value of square root(rho eta) approximately 18 kg m(-2) s(-1/2), but with a slope 10% smaller than that predicted by the Kanazawa and Gordon equation. It is envisaged that the quartz crystal technique could be used in a high-throughput microfluidic system for characterizing ionic liquids.

Sources of variability in OSL dose measurements using single grains of quartz

DEFF Research Database (Denmark)

Thomsen, Kristina Jørkov; Murray, A.S.; Bøtter-Jensen, L.

2005-01-01

spread. In this preliminary study, dose distributions have been studied using single grains of heated and laboratory irradiated quartz. By heating the sample, the contribution from incomplete zeroing was excluded and at the same time the sample was sensitised. The laboratory gamma irradiation...

Designing a compensating quartz fiber calorimeter for low angle calorimetry at LHC

International Nuclear Information System (INIS)

Ferrando, A.; Fouz, M.C.; Josa, M.I.; Khan, A.; Rosowsky, A.; Salicio, J.M.

1996-01-01

We present a design of a compensating quartz fiber calorimeter, made of a unique active section, and ment for the specific physics requirements of the low angle calorimetry in LHC experiments. The purposed calorimeter is exemplified for the case of the CMS experiment

Peculiar Feldspar And Quartz Inclusions Within Zircons From Anorthosites, North Eastern Desert, Egypt

Science.gov (United States)

Eliwa, H. A.; Dawoud, M. I.; Khalaf, I. M.; Negendank, J. F.; Itaya, T.

2004-12-01

Zircons from three anorthosite outcrops along Wadi Dib area, north Eastern Desert of Egypt contain abundant and conspicuous inclusions of quartz, feldspar, amphibole and apatite. These anorthosites, as (50-100m thick) layers, represent the top of mafic-ultramafic intrusions exhibiting rhythmic layering visible by reputation of melanocratic and leucocratic layers. Field and microscopic studies exhibit that these anorthosites were affected by the action of residual magmatic solutions associated with the late stage crystallization of the younger granites, which modified their mineralogical composition. They are composed totally of plagioclase with subordinate amount of clinoenstatite, augite, amphibole, biotite, K-feldspar, and quartz. Accessories are magnetite, ilmenite, apatite and zircon. The abundance and the mode of occurrence of K-feldspar, quartz, and biotite with apatite and zircon among the megacrysts suggest their formation is ascribed to the interaction with the residual solutions. The microprobe data exhibit difference between feldspar and amphiboles contained herein zircons and those as anorthosite mineral constituents. The genetic relationship between zircons and their inclusions suggests later growth of zircons than inclusions and most probably at the final stage of rock modification. Zircons are magmatic and found in the interstitial feldspar and quartz among plagioclase megacrysts in aggregates or as individual grains. The microscopic and SEM images investigation exhibit that most zircons are subhedral to euhedral equant and prismatic crystals. Most zircons have same range of crystal morphologies and internal growth structures with predominance of prism /{100/} and pyramid /{101/} and occasionally prism /{110/} and pyramid /{111/}. No evidences for poly-faceted grains, inherited cores or later overgrowths were detected. CL images distinguished zircons with visible core-rim structures and others with regular and continuous growth zones contained herein

Development of Quartz Fiber Calorimetry

CERN Multimedia

2002-01-01

% RD40 \\\\ \\\\ Very Forward Calorimeters (VFCs) in LHC detectors should cover the pseudorapidity range from $\\eta$~=~2.5 to at least $\\eta$~=~5 in order to compute missing transverse energy and for jet tagging. Operation at such high rapidity requires the use of a calorimetry technique that is very radiation resistant, fast and insensitive to radioactivity (especially to neutrons). This can be accomplished through the Quartz-Calorimeter~(Q-Cal) concept of embedding silica core fibers, that resist to the Gigarad radiation level, into an absorber. In this calorimeter the shower particles produce light through the Cherenkov effect generating a signal less than 10~ns in duration. Unique to this new technology the visible energy of hadronic showers has a transverse dimension nearly an order of magnitude smaller than that in conventional calorimeters, enabling precise spatial resolution, sharper isolation cuts and better jet recognition against the minimum bias events background. Last but not least, most radioactive ...

A quartz Cherenkov detector for Compton-polarimetry at future e+e- colliders

International Nuclear Information System (INIS)

List, Jenny; Vauth, Annika; Vormwald, Benedikt; Hamburg Univ.

2015-02-01

Precision polarimetry is essential for future e + e - colliders and requires Compton polarimeters designed for negligible statistical uncertainties. In this paper, we discuss the design and construction of a quartz Cherenkov detector for such Compton polarimeters. The detector concept has been developed with regard to the main systematic uncertainties of the polarisation measurements, namely the linearity of the detector response and detector alignment. Simulation studies presented here imply that the light yield reachable by using quartz as Cherenkov medium allows to resolve in the Cherenkov photon spectra individual peaks corresponding to different numbers of Compton electrons. The benefits of the application of a detector with such single-peak resolution to the polarisation measurement are shown for the example of the upstream polarimeters foreseen at the International Linear Collider. Results of a first testbeam campaign with a four-channel prototype confirming simulation predictions for single electrons are presented.

Optically stimulated luminescence techniques in retrospective dosimetry using single grains of quartz extracted from unheated materials

DEFF Research Database (Denmark)

Thomsen, Kristina Jørkov

dosimetry). Special attention has been paid to quartz extracted from unheated building materials such as concrete and mortar. The single-aliquot regeneration-dose (SAR) protocol has been used to determine absorbeddoses in small aliquots as well as single grains of quartz. It is shown that OSL measurements...... that the observed variability in the data is consistent with the sum (in quadrature) of a component,which depends on the number of photons detected from each grain, and a fixed component independent of light level. Dose depth profiles through laboratory irradiated concrete bricks have successfully been measured...

The origin of the medium OSL component in West Australian quartz

International Nuclear Information System (INIS)

Wang, X.L.; Du, J.H.; Adamiec, G.; Wintle, A.G.

2015-01-01

Optically stimulated luminescence (OSL) of a coarse-grained sedimentary quartz from West Australia was investigated. Observations of OSL and TL (thermoluminescence) were made following a series of experiments using different heating and optical bleaching conditions, and with optical stimulation at several different temperatures. Analysis of the fast and medium OSL components suggests that the medium OSL component observed after heating at 260 °C is a by-product of the production of the fast component, and both of them have as their original source the 325 °C TL trap. During fast OSL production following irradiation and preheating, some of the electrons evicted into the conduction band are re-trapped in an intermediate trap corresponding to the 170 °C TL peak; from here they are instantaneously stimulated to give rise to the medium OSL signal when the blue light stimulation is switched on, and subsequently result in the residual recuperated TL after the blue light is switched off. The kinetic properties of the medium OSL component are determined by the properties of both the 170 °C and 325 °C TL traps in contrast to the conventional interpretation of the medium component being derived from an independent source trap. Therefore, the 170 °C TL trap also plays unexpected roles in quartz OSL production with elevated stimulation temperatures (e.g. 125 °C or 130 °C, currently used for OSL dating), while the 110 °C TL trap and its influences are being avoided. - Highlights: • Quartz medium OSL component is a by-product of fast OSL component production. • Medium component is mediated by the 170 C TL peak. • Phototransfer is responsible for the medium OSL

Replacement of quartz in cementitious composites using PET particles:A statistical analysis of the physical and mechanical properties

OpenAIRE

Detomi, Anine Cristina; Filho, Sergio Luiz Moni Ribeiro; Panzera, Túlio H C; Schiavon, Marco Antonio; Silva, Vania R V; Scarpa, Fabrizio

2016-01-01

This work investigates the mechanical behavior of cementitious composites (mortar) when quartz inclusions are totally or partially replaced with polyethylene terephthalate (PET) particles. A full factorial design is performed to identify the effect of the water/cement ratio and the range of quartz particles size used in the replacement on the different mechanical and physical parameters (bulk density, apparent porosity, water absorption, oxygen permeability, compressive strength, and modulus ...

Electrochemical and surface characterisation of carbon-film-coated piezoelectric quartz crystals

International Nuclear Information System (INIS)

Pinto, Edilson M.; Gouveia-Caridade, Carla; Soares, David M.; Brett, Christopher M.A.

2009-01-01

The electrochemical properties of carbon films, of thickness between 200 and 500 nm, sputter-coated on gold- and platinum-coated 6 MHz piezoelectric quartz crystal oscillators, as new electrode materials have been investigated. Comparative studies under the same experimental conditions were performed on bulk electrodes. Cyclic voltammetry was carried out in 0.1 M KCl electrolyte solution, and kinetic parameters of the model redox systems Fe(CN) 6 3-/4- and [Ru(NH 3 ) 6 ] 3+/2+ as well as the electroactive area of the electrodes were obtained. Atomic force microscopy was used in order to examine the surface morphology of the films, and the properties of the carbon films and the electrode-solution interface were studied by electrochemical impedance spectroscopy. The results obtained demonstrate the feasibility of the preparation and development of nanometer thick carbon film modified quartz crystals. Such modified crystals should open up new opportunities for the investigation of electrode processes at carbon electrodes and for the application of electrochemical sensing associated with the EQCM.

Uranium deposits in Proterozoic quartz-pebble conglomerates

International Nuclear Information System (INIS)

1987-09-01

This report is the result of an effort to gather together the most important information on uranium deposits in Proterozoic quartz-pebble conglomerates in the United States of America, Canada, Finland, Ghana, South Africa and Australia. The paper discusses the uranium potential (and in some cases also the gold potential in South Africa, Western Australia and Ghana) in terms of ores, sedimentation, mineralization, metamorphism, placers, geologic formations, stratigraphy, petrology, exploration, tectonics and distribution. Geologic history and application of geologic models are also discussed. Glacial outwash and water influx is also mentioned. The uranium deposits in a number of States in the USA are covered. The Witwatersrand placers are discussed in several papers. Refs, figs, tabs

Crystallinity study of a faceted Brazilian quartz by X-rays topography

International Nuclear Information System (INIS)

Suzuki, C.K.; Farias, C.R.L.

1986-01-01

A characterization study of crystalline perfection along the Z-direction (from the base to the top) of a single crystal of natural quartz was conducted. A gradual and very significanty change of crystalline perfection with the transparency was revealed by X-ray topography and goniometric observation in samples cut along perpendicular to the Z-direction. (L.J.) [pt

Direct Growth of III-Nitride Nanowire-Based Yellow Light-Emitting Diode on Amorphous Quartz Using Thin Ti Interlayer

KAUST Repository

Prabaswara, Aditya

2018-02-06

Consumer electronics have increasingly relied on ultra-thin glass screen due to its transparency, scalability, and cost. In particular, display technology relies on integrating light-emitting diodes with display panel as a source for backlighting. In this study, we undertook the challenge of integrating light emitters onto amorphous quartz by demonstrating the direct growth and fabrication of a III-nitride nanowire-based light-emitting diode. The proof-of-concept device exhibits a low turn-on voltage of 2.6 V, on an amorphous quartz substrate. We achieved ~ 40% transparency across the visible wavelength while maintaining electrical conductivity by employing a TiN/Ti interlayer on quartz as a translucent conducting layer. The nanowire-on-quartz LED emits a broad linewidth spectrum of light centered at true yellow color (~ 590 nm), an important wavelength bridging the green-gap in solid-state lighting technology, with significantly less strain and dislocations compared to conventional planar quantum well nitride structures. Our endeavor highlighted the feasibility of fabricating III-nitride optoelectronic device on a scalable amorphous substrate through facile growth and fabrication steps. For practical demonstration, we demonstrated tunable correlated color temperature white light, leveraging on the broadly tunable nanowire spectral characteristics across red-amber-yellow color regime.

Reactive magnetron sputtering of N-doped carbon thin films on quartz glass for transmission photocathode applications

Science.gov (United States)

Balalykin, N. I.; Huran, J.; Nozdrin, M. A.; Feshchenko, A. A.; Kobzev, A. P.; Sasinková, V.; Boháček, P.; Arbet, J.

2018-03-01

N-doped carbon thin films were deposited on a silicon substrate and quartz glass by RF reactive magnetron sputtering using a carbon target and an Ar+N2 gas mixture. During the magnetron sputtering, the substrate holder temperatures was kept at 800 °C. The carbon film thickness on the silicon substrate was about 70 nm, while on the quartz glass it was in the range 15 nm – 60 nm. The elemental concentration in the films was determined by RBS and ERD. Raman spectroscopy was used to evaluate the intensity ratios I D/I G of the D and G peaks of the carbon films. The transmission photocathodes prepared were placed in the hollow-cathode assembly of a Pierce-structure DC gun to produce photoelectrons. The quantum efficiency (QE) was calculated from the laser energy and cathode charge measured. The properties of the transmission photocathodes based on semitransparent N-doped carbon thin films on quartz glass and their potential for application in DC gun technology are discussed.

Receding and advancing (CO_2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity

International Nuclear Information System (INIS)

Al-Yaseri, Ahmed Z.; Lebedev, Maxim; Barifcani, Ahmed; Iglauer, Stefan

2016-01-01

Highlights: • (Water + CO_2) contact angle on quartz increases substantially with pressure and salinity. • (Water + CO_2) contact angle on quartz increases slightly with temperature. • Surface roughness has only a minor influence on (water + CO_2 + quartz) contact angles. - Abstract: The wetting characteristics of CO_2 in rock are of vital importance in carbon geo-storage as they determine fluid dynamics and storage capacities. However, the current literature data has a high uncertainty, which translates into uncertain predictions in terms of containment security and economic project feasibility. We thus measured contact angles for the CO_2/water/quartz system at relevant reservoir conditions, and analysed the effects of pressure (0.1 to 20) MPa, temperature (296 to 343) K, surface roughness (56 to 1300) nm, salt type (NaCl, CaCl_2, and MgCl_2) and brine salinities (0 to 35) wt%. Water contact angles decreased with surface roughness, but increased with pressure, temperature, and brine salinity. Overall the contact angles were significantly increased at storage conditions (∼50°) when compared to ambient conditions (always 0°). Consequently quartz is weakly water-wet (not completely water-wet) at storage conditions, and structural and residual trapping capacities are reduced accordingly.

Thermal conductivity measurements in porous mixtures of methane hydrate and quartz sand

Science.gov (United States)

Waite, W.F.; deMartin, B.J.; Kirby, S.H.; Pinkston, J.; Ruppel, C.D.

2002-01-01

Using von Herzen and Maxwell's needle probe method, we measured thermal conductivity in four porous mixtures of quartz sand and methane gas hydrate, with hydrate composing 0, 33, 67 and 100% of the solid volume. Thermal conductivities were measured at a constant methane pore pressure of 24.8 MPa between -20 and +15??C, and at a constant temperature of -10??C between 3.5 and 27.6 MPa methane pore pressure. Thermal conductivity decreased with increasing temperature and increased with increasing methane pore pressure. Both dependencies weakened with increasing hydrate content. Despite the high thermal conductivity of quartz relative to methane hydrate, the largest thermal conductivity was measured in the mixture containing 33% hydrate rather than in hydrate-free sand. This suggests gas hydrate enhanced grain-to-grain heat transfer, perhaps due to intergranular contact growth during hydrate synthesis. These results for gas-filled porous mixtures can help constrain thermal conductivity estimates in porous, gas hydrate-bearing systems.

Kinetic Modeling of the Reaction Rate for Quartz and Carbon Black Pellet

Science.gov (United States)

Li, Fei; Tangstad, Merete

2018-06-01

The kinetic modeling for the carbothermal reduction reaction rate in quartz and carbon black pellets is studied at different temperatures, under varying CO partial pressures in ambient atmosphere, varying carbon contents, different quartz particle sizes, and different crucible opening areas. Carbon black is produced by the cracking of natural gas. The activation energy of the SiC-producing step was determined to be 594 kJ/mol. The averaged pre-exponential factor A obtained from 1898 K, 1923 K, and 1948 K (1625 °C, 1650 °C, and 1675 °C) is 2.62E+16 min-1. The reaction rate of the gas-solid interface factor, fix-C content ( X fix-C), temperature ( T), and CO partial pressure ( X CO) can be expressed as follows: {{d/pct}}{{{d}t}} = (1 - 0.40 × X_{{{fix} - C}}^{ - 0.86} × {pct}) × 2.62 × 10^{16} × \\exp ( { - 594000/RT} ) × (2.6 - 0.015 × X_{co} ).

Geochemical evidence for subduction in the early Archaean from quartz-carbonate-fuchsite mineralization, Isua Supracrustal Belt, West Greenland

DEFF Research Database (Denmark)

Pope, Emily Catherine; Rosing, Minik Thorleif; Bird, Dennis K.

Quartz, carbonate and fuchsite (chromian muscovite) is a common metasomatic assemblage observed in orogenic gold systems, both in Phanerozoic convergent margin settings, and within supracrustal and greenstone belts of Precambrian rocks. Geologic and geochemical observations in younger orogenic...... systems suggest that ore-forming metasomatic fluids are derived from subduction-related devolitilization reactions, implying that orogenic Au-deposits in Archaean and Proterozoic supracrustal rock suites are related to subduction-style plate tectonics beginning early in Earth history. Justification...... with Phanerozoic orogenic deposits and that this type of metasomatism is a unique result of subduction-related processes. Fuchsite from the ISB has a δ18O and δD of 7.7 to 17.9‰ and -115 to -61‰, respectively. δ18O of quartz from the same rocks is between 10.3 and 18.6‰. Muscovite-quartz oxygen isotope thermometry...

Hydraulic and mechanical properties of natural fractures in low-permeability rock

International Nuclear Information System (INIS)

Pyrack-Nolte, L.J.; Myer, L.R.; Cook, N.G.W.; Witherspoon, P.A.

1987-01-01

The results of a comprehensive laboratory study of the mechanical displacement, permeability, and void geometry of single rock fractures in a quartz monzonite are summarized and analyzed. A metal-injection technique was developed that provided quantitative data on the precise geometry of the void spaces between the fracture surfaces and the areas of contact at different stresses. At effective stresses of less than 20 MPa fluid flow was proportional to the mean fracture aperture raised to a power greater than 3. As stress was increased, contact area was increased and void spaces become interconnected by small tortuous channels that constitute the principal impediment to fluid flow. At effective stresses higher than 20 MPa, the mean fracture aperture continued to diminish with increasing stress, but this had little effect on flow because the small tortuous flow channels deformed little with increasing stress

Physical and chemical changes to rock near electrically heated boreholes at Spent Fuel Test-Climax

International Nuclear Information System (INIS)

Beiriger, J.M.; Durham, W.B.; Ryerson, F.J.

1985-01-01

Sections of Climax Stock quartz monzonite taken from the vicinity of two electrically heated boreholes at Spent Fuel Test-Climax (SFT-C) have been studied by scanning electron microscopy and optical microscopy for signs of changes in crack structure and in mineralogy resulting from operations at SFT-C. The crack structure, as measured by density of cracks and average crack lengths was found not to have changed as a result of heating, regardless of distance from the heater hole. However, rock near the heater borehole sampled in the north heater drift was found to be more cracked than rock near the borehole sampled in the south heater drift. Mineralogically, the post-test samples are identical to the pre-test samples. No new phases have been formed as a result of the test. 10 refs., 6 figs., 8 tabs

Comparative study on the effect of annealing treatments on RTL mechanism in natural quartz from different origins

International Nuclear Information System (INIS)

Mebhah, D.; Imatoukene, D.; Lounis-Mokrani, Z.; Kechouane, M.

2009-01-01

The behaviour of trap centres and luminescence centres has been investigated for fired and unfired natural quartz from bricks and sediments irradiated at 100 Gy and annealed at different temperatures in the range 350-700 deg. C. The annealing treatment affects thermoluminescence (TL) glow curve as various changes were observed. The higher sensitization occurred for an annealing in the region 550-600 deg. C. At this annealing temperature, it has been observed the emergence of two peaks arising at 96 and 180 deg. C. At lower annealing temperatures, these peaks are overlapped by the peaks localized at 90 and 195 deg. C, respectively. Concerning the fired quartz, the higher sensitization occurred for an annealing in the region 500-550 deg. C for peak temperature around 200 deg. C and an unusual desensitization for the peak temperature around 100 deg. C. The behaviour of the two types of quartz is analyzed regarding to their kinetic parameters and luminescence emission and compared to literature data.

Comparative study on the effect of annealing treatments on RTL mechanism in natural quartz from different origins

Energy Technology Data Exchange (ETDEWEB)

Mebhah, D., E-mail: mebhahd@yahoo.f [Centre de Recherche Nucleaire d' Alger, 2 Bd, Frantz Fanon, BP 399 (Algeria); Imatoukene, D.; Lounis-Mokrani, Z. [Centre de Recherche Nucleaire d' Alger, 2 Bd, Frantz Fanon, BP 399 (Algeria); Kechouane, M. [Faculte de Physique, USTHB, BP 32 El Alia (Algeria)

2009-12-15

The behaviour of trap centres and luminescence centres has been investigated for fired and unfired natural quartz from bricks and sediments irradiated at 100 Gy and annealed at different temperatures in the range 350-700 deg. C. The annealing treatment affects thermoluminescence (TL) glow curve as various changes were observed. The higher sensitization occurred for an annealing in the region 550-600 deg. C. At this annealing temperature, it has been observed the emergence of two peaks arising at 96 and 180 deg. C. At lower annealing temperatures, these peaks are overlapped by the peaks localized at 90 and 195 deg. C, respectively. Concerning the fired quartz, the higher sensitization occurred for an annealing in the region 500-550 deg. C for peak temperature around 200 deg. C and an unusual desensitization for the peak temperature around 100 deg. C. The behaviour of the two types of quartz is analyzed regarding to their kinetic parameters and luminescence emission and compared to literature data.

Equivalent thermal history (H{sub E}) of ferruginous sandstones based on the thermal activation characteristics of quartz

Energy Technology Data Exchange (ETDEWEB)

Lahaye, Christelle [Centre de Recherche en Physique Appliquee a l' Archeologie (CRPAA), IRAMAT Institut de Recherche sur les Archeomateriaux, UMR 5060 CNRS - Universite de Bordeaux 3, Maison de l' Archeologie, 33607 Pessac Cedex (France) and Laboratorio di Datazione tramite Luminescenza e di Metodologie Fisiche per i Beni Culturali, Dipartimento di Fisica ed Astronomia dell' Universita di Catania, Via Santa Sofia, 645123 Catania (Italy)]. E-mail: christelle.lahaye@ct.infn.it; Godfrey-Smith, Dorothy I. [Department of Earth Sciences, Dalhousie University, Halifax, NS, B3H 4J1 (Canada); Radiological Analysis and Defence, Defence Research and Development Canada, 3701 Carling Ave., Ottawa, ON, K1A 0Z4 (Canada); Guibert, Pierre [Centre de Recherche en Physique Appliquee a l' Archeologie (CRPAA), IRAMAT Institut de Recherche sur les Archeomateriaux, UMR 5060 CNRS - Universite de Bordeaux 3, Maison de l' Archeologie, 33607 Pessac Cedex (France); Bechtel, Francoise [Centre de Recherche en Physique Appliquee a l' Archeologie (CRPAA), IRAMAT Institut de Recherche sur les Archeomateriaux, UMR 5060 CNRS - Universite de Bordeaux 3, Maison de l' Archeologie, 33607 Pessac Cedex (France)

2006-08-15

The thermal history of four quartz-rich ochre samples from an Upper Palaeolithic site was studied. This work is based on the changes in thermal activation characteristics (TAC) of the 110 deg. C TL peak of the quartz inclusions. An isothermal study of a previously unheated sample has highlighted the importance of the duration of annealing on the sensitization of quartz. In fact, the sensitivity change as a function of the duration of annealing is not monotonic. For that reason it seems necessary to consider the 'equivalent thermal history' H{sub E} rather than an 'equivalent temperature'. Isochronal annealing experiments demonstrate that the initial rise of sensitization overestimates the true H{sub E} by about 100 deg. C. Using a geological sample we have thus developed an empirical approach which allows the true H{sub E} of artifacts to be determined. Reheating of ochre originally heated in antiquity results in desensitization of the TAC.

Study of quartz lascas properties for technological applications

International Nuclear Information System (INIS)

Hummel, D.C.A.; Shinohara, A.H.; Torikai, D.; Suzuki, C.K.

1988-01-01

This paper describes a fundamental properties of Brasilian quartz lascas characterized by x-ray diffraction topography and goniometry, density and ultrasonic attenuation measurements, optical inspectoscopy, optical microscopy and impurity analysis by ASS (Al,Fe,Na,K,Li,Ca,Mn,Mg,Cr and Cu). The results were discussed with the correlation with nominal lascas graded as ''Ist'', ''mix'',''2nd'',''3rd'' and ''4th'' made by visual observation taking in consideration the transparency. The samples were collected from the proper mines deposited lascas. The main brazilian producted states are Minas Gerais, Bahia and Goias. (author) [pt

A vibrating quartz fork - a tool for cryogenic helium research

Czech Academy of Sciences Publication Activity Database

Blažková, Michaela; Člověčko, M.; Eltsov, V. B.; Gažo, E.; de Graaf, R.; Hosio, J.J.; Krusius, M.; Schmoranzer, D.; Schoepe, W.; Skrbek, Ladislav; Skyba, P.; Solntsev, R.E.; Vinen, W. F.

2008-01-01

Roč. 150, - (2008), s. 525-535 ISSN 0022-2291 R&D Projects: GA ČR GA202/05/0218 Grant - others:GAUK(CZ) 7953/2007; Transnational Access Programme(XE) RITA -CT-2003-505313 Institutional research plan: CEZ:AV0Z10100520 Keywords : normal 3He * superfluid 3He * superfluid 4He * turbulence, * cavitation * quartz tuning fork Subject RIV: BK - Fluid Dynamics Impact factor: 1.034, year: 2008

Curcumin protects against cytotoxic and inflammatory effects of quartz particles but causes oxidative DNA damage in a rat lung epithelial cell line

International Nuclear Information System (INIS)

Li Hui; Berlo, Damien van; Shi Tingming; Speit, Guenter; Knaapen, Ad M.; Borm, Paul J.A.; Albrecht, Catrin; Schins, Roel P.F.

2008-01-01

Chronic inhalation of high concentrations of respirable quartz particles has been implicated in various lung diseases including lung fibrosis and cancer. Generation of reactive oxygen species (ROS) and oxidative stress is considered a major mechanism of quartz toxicity. Curcumin, a yellow pigment from Curcuma longa, has been considered as nutraceutical because of its strong anti-inflammatory, antitumour and antioxidant properties. The aim of our present study was to investigate whether curcumin can protect lung epithelial cells from the cytotoxic, genotoxic and inflammatory effects associated with quartz (DQ12) exposure. Electron paramagnetic resonance (EPR) measurements using the spin-trap DMPO demonstrated that curcumin reduces hydrogen peroxide-dependent hydroxyl-radical formation by quartz. Curcumin was also found to reduce quartz-induced cytotoxicity and cyclooxygenase 2 (COX-2) mRNA expression in RLE-6TN rat lung epithelial cells (RLE). Curcumin also inhibited the release of macrophage inflammatory protein-2 (MIP-2) from RLE cells as observed upon treatment with interleukin-1 beta (IL-1β) and tumour necrosis factor-alpha (TNFα). However, curcumin failed to protect the RLE cells from oxidative DNA damage induced by quartz, as shown by formamidopyrimidine glycosylase (FPG)-modified comet assay and by immunocytochemistry for 8-hydroxydeoxyguanosine. In contrast, curcumin was found to be a strong inducer of oxidative DNA damage itself at non-cytotoxic and anti-inflammatory concentrations. In line with this, curcumin also enhanced the mRNA expression of the oxidative stress response gene heme oxygenase-1 (ho-1). Curcumin also caused oxidative DNA damage in NR8383 rat alveolar macrophages and A549 human lung epithelial cells. Taken together, these observations indicate that one should be cautious in considering the potential use of curcumin in the prevention or treatment of lung diseases associated with quartz exposure

In-homogeneity in the pre-dose sensitization of the 110 °C TL peak in various quartz samples: The influence of annealing

International Nuclear Information System (INIS)

Polymeris, George S.; Oniya, Ebenezer O.; Jibiri, Nnamdi N.; Tsirliganis, Nestor C.; Kitis, George

2012-01-01

The pre-dose sensitization effect of the 110 °C TL glow-peak of quartz is a basic tool in thermoluminescence and optically stimulated luminescence dating and retrospective dosimetry. In the present work, a homogeneity study was performed on pre-dose sensitization in grains obtained from large quartz crystals samples collected from 10 different origins. The aliquot – to – aliquot scatter of the pre-dose sensitization of the 110 °C TL peak within each quartz crystal was monitored. The influence of the annealing on this scattering was also studied. Therefore, the investigation was applied to the un-fired “as is” samples as well as to samples annealed at 900 °C for 1 h following cooling to room temperature in air. The results showed that in the case of “as is” quartz the sensitization effect vary strongly within each aliquot of the same quartz sample. This strong variation is removed by both the high temperature annealing as well as heating up to 500 °C, involved in the TL measurements. These results are generally discussed in the framework of existing models and applications of the effect.

Mechanical Mounting and Adhesive Junction for Large Quartz Optics Operatng at Cryogenic Temperature

Science.gov (United States)

Pellizzari, M.; Mosciarello, P.

2012-07-01

Gaia is a global space astrometry mission, with the goal to make the largest, most precise three-dimensional map of our Galaxy. Gaia contains two optical telescopes: in front of their Focal Plane Assembly -FPA- two narrow quartz prisms are mounted for spectrophotometer science: the Blue and Red Photometer Prisms -BPP and RPP-. They are framed in a SiC structure by means of brackets and adhesive junctions between metal parts and quartz optical elements. SELEX GALILEO developed this project as subcontractor of Astrium France. The assembly has to withstand thermoelastic loads due to CTE mismatch at an operative temperature of 120 K. The mechanical mountings design to reduce the stresses due to thermal loads on the adhesive joint is described and the results of the bonding qualification process as well as the flight hardware bonding results are reported.

Use of quartz crystal nanobalance to study the binding and stabilization of albumin and doxycycline on a thin layer of hydroxyapatite

Science.gov (United States)

Victor, Sunita Prem; Sharma, Chandra P.; Sreenivasan, K.

2011-12-01

This study reports the use of quartz crystal nanobalance (QCN) to study the adsorption of two model molecules namely albumin and doxycycline by hydroxyapatite (HA). The work focuses on the deposition of a stable coating of HA on the quartz crystal, modification of the coating using doxycycline and its subsequent effects on albumin adsorption. The uniformity and thickness of the HA coating has been studied using atomic force microscopy (AFM). The functional groups to ascertain the presence of the selected moieties have been characterized by Raman spectroscopy. The results indicate that the mass of albumin deposited on the surface of the HA coated quartz crystal functionalized with doxycycline shows a substantial increase when compared to the standard HA coated quartz crystal. The adsorbed albumin has also been found to be retained for an enhanced period of time. This surface immobilization of doxycycline and subsequent albumin adsorption seem to be a promising approach to confer biomaterials with antithrombogenic and antibacterial surfaces.

Use of quartz crystal nanobalance to study the binding and stabilization of albumin and doxycycline on a thin layer of hydroxyapatite

Energy Technology Data Exchange (ETDEWEB)

Victor, Sunita Prem [Biosurface Technology Division, Biomedical Technology Wing, Sree Chitra Tirunal Institute for Medical Sciences and Technology, Trivandrum 695012, Kerala (India); Sharma, Chandra P., E-mail: sharmacp@sctmist.ac.in [Biosurface Technology Division, Biomedical Technology Wing, Sree Chitra Tirunal Institute for Medical Sciences and Technology, Trivandrum 695012, Kerala (India); Sreenivasan, K. [Biosurface Technology Division, Biomedical Technology Wing, Sree Chitra Tirunal Institute for Medical Sciences and Technology, Trivandrum 695012, Kerala (India); Laboratory for Polymer Analysis, Biomedical Technology Wing, Sree Chitra Tirunal Institute for Medical Sciences and Technology, Trivandrum 695012, Kerala (India)

2011-12-15

This study reports the use of quartz crystal nanobalance (QCN) to study the adsorption of two model molecules namely albumin and doxycycline by hydroxyapatite (HA). The work focuses on the deposition of a stable coating of HA on the quartz crystal, modification of the coating using doxycycline and its subsequent effects on albumin adsorption. The uniformity and thickness of the HA coating has been studied using atomic force microscopy (AFM). The functional groups to ascertain the presence of the selected moieties have been characterized by Raman spectroscopy. The results indicate that the mass of albumin deposited on the surface of the HA coated quartz crystal functionalized with doxycycline shows a substantial increase when compared to the standard HA coated quartz crystal. The adsorbed albumin has also been found to be retained for an enhanced period of time. This surface immobilization of doxycycline and subsequent albumin adsorption seem to be a promising approach to confer biomaterials with antithrombogenic and antibacterial surfaces.

Use of quartz crystal nanobalance to study the binding and stabilization of albumin and doxycycline on a thin layer of hydroxyapatite

International Nuclear Information System (INIS)

Victor, Sunita Prem; Sharma, Chandra P.; Sreenivasan, K.

2011-01-01

This study reports the use of quartz crystal nanobalance (QCN) to study the adsorption of two model molecules namely albumin and doxycycline by hydroxyapatite (HA). The work focuses on the deposition of a stable coating of HA on the quartz crystal, modification of the coating using doxycycline and its subsequent effects on albumin adsorption. The uniformity and thickness of the HA coating has been studied using atomic force microscopy (AFM). The functional groups to ascertain the presence of the selected moieties have been characterized by Raman spectroscopy. The results indicate that the mass of albumin deposited on the surface of the HA coated quartz crystal functionalized with doxycycline shows a substantial increase when compared to the standard HA coated quartz crystal. The adsorbed albumin has also been found to be retained for an enhanced period of time. This surface immobilization of doxycycline and subsequent albumin adsorption seem to be a promising approach to confer biomaterials with antithrombogenic and antibacterial surfaces.

Fluid inclusion study of the uranium mineralised granite cataclasite/mylonite and quartz reef in the Mulapalle area, Cuddapah district, Andhra Pradesh

International Nuclear Information System (INIS)

Thirupathi, P.V.; Tripathi, B.K.; Umamaheswar, K.; Dhana Raju, R.

2004-01-01

Granite cataclasite and mylonite in the basement fracture zones around Mulapalle in the southwestern environs of the Cuddapah basin are uraniferous with the presence of brannerite, U-Ti complex and uraninite. The ENE-WSW trending fracture zone is cut by NW-SE trending quartz reef. Fluid inclusion study carried out on quartz from the mineralized cataclasite and as well as from the quartz reef shows the presence of both primary [8-20 microns] and abundant secondary up to [6 microns] inclusions. Most of the inclusions are bi-phase (L+V) liquid rich having a degree of fill around 0.90 with constant liquid to vapour ratio. Few inclusions are liquid monophase and multiphase [S+L+V]. They behave as H 2 O-NaCl system and homogenize into liquid phase at low temperature range [125 to 200 degC] except some bi-phase inclusions in the barren quartz reef, which are found to behave as an impure H 2 O-NaCl system admixed with other salts. Wide variation of salinity in the range of 3-25 wt%e NaCl is recorded by the inclusions in both the mineralized cataclasite and the barren quartz reef. The trapping pressure [P T ] of the inclusions of barren quartz reef spreads between 200 to 600 bars while those of mineralized cataclasite restricts to upper end of that range. Some inclusions in mineralized cataclasite that homogenize at high temperatures [200 to 250 degC] show P T between 800 to 1000 bars. The presence of more than one population without any change in fluid composition indicate their origin at different stages of deformation modifying the primary inclusions of the granite and from fluids migrated through fractures at later stages. In the barren quartz reef, the distribution of inclusions of contrasting salinity implies the environment of mixing of connectively driven hydrothermal fluid of metamorphic origin and meteoric water. (author)

Scratching experiments on quartz crystals: Orientation effects in chipping

Science.gov (United States)

Tellier, C. R.; Benmessaouda, D.

1994-06-01

The deformation and microfracture properties of quartz crystals were studied by scratching experiments. The critical load at which microfractures are initiated was found to be orientation dependent, whereas the average width of ductile grooves and chips remained relatively insensitive to crystal orientation. In contrast, a marked anisotropy in the shape of chips was observed. This anisotropy has been interpreted in terms of microfractures propagating preferentially along slip planes. Simple geometrical conditions for the SEM (scanning electron microscopy) observation of active slip planes are proposed.

Error variation in OSL palaeodose estimates from single aliquots of quartz: a factorial experiment

International Nuclear Information System (INIS)

Galbraith, R.F.; Roberts, R.G.; Yoshida, H.

2005-01-01

We use a factorial experiment to study systematic and random differences between measured OSL palaeodoses for a variety of quartz samples. These include samples that have absorbed either a large or small natural or laboratory-induced radiation dose, either with or without prior heating or bleaching. The systematic factors studied are the size of the test dose, the preheat temperature and the number of quartz grains in each multi-grain aliquot. Palaeodoses were estimated using a single-aliquot regenerative-dose protocol. The main parameter of interest is the amount of random variation, over and above that due to photon counting statistics, to be expected between estimates from aliquots that have received the same radiation dose. This over-dispersion is generally larger for natural samples than for artificially bleached ones, and it varies from about 1% in the most favourable cases to about 18% for small aliquots of a sample that had received a natural dose of about 46 Gy. The latter is comparable to the over-dispersion reported for single grains of natural quartz that are thought to have been well-bleached at the time of deposition. The factorial experiment also revealed a number of systematic effects. In particular, measured palaeodoses using a preheat temperature of 260 deg. C were systematically lower than those using 180 deg. C, by up to about 5% in some cases

Association behaviour of 241Am(III) on SiO2(amorphous) and SiO2(quartz) colloids

International Nuclear Information System (INIS)

Degueldre, C.; Wernli, B.

1993-01-01

SiO 2 colloids have been identified as a potential vector for enhancing radionuclide transport in granitic groundwater and in concrete pore water. The sorption behaviour of 241 Am(III) on SiO 2 colloids was studied as a function of americium concentration pH (5-12), colloid concentration, ionic strength, temperature and SiO 2 allotropic species. The Am(III) sorption mechanism on amorphous silica is different from that on quartz. For SiO 2(amorphous) solution, the variation of log K p (ml g -1 ) with pH is linear (pH=5-9) with a slope of +1 indicating a one proton exchange mechanism. The colloid concentration (ppm) affects the sorption and log K p 3.7-0.67 log [SiO 2 ] (pH = 6). K p increases insignificantly when the ionic strength decreases. It shows no significant variation, however, with the Am concentration. On amorphous silica, the Am(III) sorption is driven by proton exchange from the silanol groups. For SiO 2 (quartz), log K p is constant over a large range of quartz concentration in suspension and the variation of log K p with pH is about linear (pH = 5-12), with a slope of 0.28, indicating a more complex exchange mechanism. Reactions taking into account the interaction of positive Am(OH) w (3-w)+ species on to the negatively charged quartz surface are suggested. (author)

Estimating average shock pressures recorded by impactite samples based on universal stage investigations of planar deformation features in quartz - Sources of error and recommendations

Science.gov (United States)

Holm-Alwmark, S.; Ferrière, L.; Alwmark, C.; Poelchau, M. H.

2018-01-01

Planar deformation features (PDFs) in quartz are the most widely used indicator of shock metamorphism in terrestrial rocks. They can also be used for estimating average shock pressures that quartz-bearing rocks have been subjected to. Here we report on a number of observations and problems that we have encountered when performing universal stage measurements and crystallographically indexing of PDF orientations in quartz. These include a comparison between manual and automated methods of indexing PDFs, an evaluation of the new stereographic projection template, and observations regarding the PDF statistics related to the c-axis position and rhombohedral plane symmetry. We further discuss the implications that our findings have for shock barometry studies. Our study shows that the currently used stereographic projection template for indexing PDFs in quartz might induce an overestimation of rhombohedral planes with low Miller-Bravais indices. We suggest, based on a comparison of different shock barometry methods, that a unified method of assigning shock pressures to samples based on PDFs in quartz is necessary to allow comparison of data sets. This method needs to take into account not only the average number of PDF sets/grain but also the number of high Miller-Bravais index planes, both of which are important factors according to our study. Finally, we present a suggestion for such a method (which is valid for nonporous quartz-bearing rock types), which consists of assigning quartz grains into types (A-E) based on the PDF orientation pattern, and then calculation of a mean shock pressure for each sample.

Adaptability of some legume trees on quartz tailings of a former tin mining area in Bangka Island, Indonesia

Directory of Open Access Journals (Sweden)

B H Narendra

2016-10-01

Full Text Available Tin mining activities in Bangka Island, besides their important role in contributing to state revenues, also caused damage to the environment, among others in the form of quartz tailings overlay. To rehabilitate this land, in addition to the necessary efforts to improve soil conditions, success is also determined by the selection of appropriate plant species. This study was aimed to determine the adaptability of some legume trees grown on the quartz tailings in land rehabilitation trials in the post tin mining areas of Bangka Island. The legume trees tested were Calliandra calothyrsus Meisn., Caesalpinia sappan L., Enterolobium cyclocarpum (Jacq. Griseb., Gliricidia sepium (Jacq. Walp., Delonix regia ( Hook. Raf., and Cassia siamea Lamk. Treatments of growing media applied  in  the field were medium I (a mixture of 20% organic material, 20% top soil, 1% NPK fertilizer, 5% calcium, and 54% quartz tailings, media II (a mixture of 25%organic material, 25%top soil, 2% NPK fertilizer, 6% calcium, 42% quartz tailings, and media III (a mixture of 30% organic material, 30% top soil, 3% NPK fertilizer, 7% calcium, and 30% quartz tailings. The observation was done by measuring the height and diameter of the stem of the plants, as well as the viability of one year after planting. Analysis of the results of measurements of stem height and diameter showed their diversity. Enterolobium cyclocarpum had the largest dimensions, while the lowest was Caesalpinia sappan. At the age of one year in the field, Gliricida sepium and Enterolobium cyclocarpum showed the average ability of the high life of up to 100%, whereas Calliandra calothyrsus was totally death. In general, the types of legumes selected in this trial showed good adaptability, except for of Calliandra calothyrsus

Complexometric determination of rare earth elements in quartz glasses with indicator xylenol orange-cetylpyridinium chloride

International Nuclear Information System (INIS)

Svistunova, G.P.; Amelin, V.G.

1988-01-01

A study was made on possibility of using the system xylenol orange (XO)-cetypyridinium determination of REE. XO forms with REE in the presence of CP intensively coloured complexes with absorbtion maximums at 610-615 nm. Colour transformation from blue to yellow is observed during complexometric titration in CP presence in the final point of titration by EDTA solution. The method was applied for Eu and Ce determination in alloyed quartz glasses. Titanium doesn't prevent REE determination at its content in titrated solution up to 1 mg. Other elements affect slightly the results. The method is recommended to use for 0.1-0.7% REE determination in quartz glasses of 0.5-1.5 g samples

Complexometric determination of rare earth elements in quartz glasses with indicator xylenol orange-cetylpyridinium chloride

Energy Technology Data Exchange (ETDEWEB)

Svistunova, G P; Amelin, V G

1988-11-01

A study was made on possibility of using the system xylenol orange (XO)-cetypyridinium determination of REE. XO forms with REE in the presence of CP intensively coloured complexes with absorbtion maximums at 610-615 nm. Colour transformation from blue to yellow is observed during complexometric titration in CP presence in the final point of titration by EDTA solution. The method was applied for Eu and Ce determination in alloyed quartz glasses. Titanium doesn't prevent REE determination at its content in titrated solution up to 1 mg. Other elements affect slightly the results. The method is recommended to use for 0.1-0.7% REE determination in quartz glasses of 0.5-1.5 g samples.

Influence of pre-measurement thermal treatment on OSL of synthetic quartz measured at room temperature

International Nuclear Information System (INIS)

Kale, Y.D.; Gandhi, Y.H.

2008-01-01

Much effort has been made to study the influence of pre-measurement thermal treatment and ionizing radiation on quartz specimens owing to its use in a large number of applications. Optically stimulated luminescence (OSL) being a structured and sensitive phenomenon promises to correlate the responsible color center and luminescence emission. OSL studies on quartz with such conditions can reveal many significant results. The aim of the present investigation is to understand the effect of annealing temperature on OSL characteristics of synthetic quartz recorded at room temperature. At identical annealing duration and β-dose, the shape of OSL decay curve remains non-exponential; when specimens annealed at lower temperature (∼400 deg. C). The shape of decay curve changes to exponential in nature along with rise in OSL intensity when the specimen was given higher temperature of annealing (>400 deg. C). The effects of such protocol on pattern of OSL sensitivity as well as area under the OSL decay curve are also presented here. The presence of shallow traps, when OSL decay curve was recorded at room temperature seems to be responsible for the changes in OSL pattern. The influence of shallow traps is attributed to non-exponential decay of OSL recorded at room temperature

Carbon dioxide/brine wettability of porous sandstone versus solid quartz: An experimental and theoretical investigation.

Science.gov (United States)

Alnili, Firas; Al-Yaseri, Ahmed; Roshan, Hamid; Rahman, Taufiq; Verall, Michael; Lebedev, Maxim; Sarmadivaleh, Mohammad; Iglauer, Stefan; Barifcani, Ahmed

2018-08-15

Wettability plays an important role in underground geological storage of carbon dioxide because the fluid flow and distribution mechanism within porous media is controlled by this phenomenon. CO 2 pressure, temperature, brine composition, and mineral type have significant effects on wettability. Despite past research on this subject, the factors that control the wettability variation for CO 2 /water/minerals, particularly the effects of pores in the porous substrate on the contact angle at different pressures, temperatures, and salinities, as well as the physical processes involved are not fully understood. We measured the contact angle of deionised water and brine/CO 2 /porous sandstone samples at different pressures, temperatures, and salinities. Then, we compared the results with those of pure quartz. Finally, we developed a physical model to explain the observed phenomena. The measured contact angle of sandstone was systematically greater than that of pure quartz because of the pores present in sandstone. Moreover, the effect of pressure and temperature on the contact angle of sandstone was similar to that of pure quartz. The results showed that the contact angle increases with increase in temperature and pressure and decreases with increase in salinity. Copyright © 2018 Elsevier Inc. All rights reserved.

Analysis of adsorption behavior of cations onto quartz surface by electrical double-layer model

International Nuclear Information System (INIS)

Kitamura, Akira; Yamamoto, Tadashi; Fujiwara, Kenso; Nishikawa, Sataro; Moriyama, Hirotake

1999-01-01

In a study of the adsorption behavior of cations onto quartz, the distribution coefficient of a variety of cations was determined using the batch method, and using the titration method, the surface charge densities of quartz in a number of electrolyte solutions. The two values thus determined were analyzed applying the electrical double-layer model, from which optimum parameter values were derived for double-layer electrostatics and intrinsic adsorption equilibrium constants. Based on these parameter values, the mechanism of cation adsorption is discussed: A key factor governing this mechanism proved to be the hydration behavior of cations. Consideration of the Coulomb interaction between the adsorbate ions and adsorbent surface led to the finding of a simple rule governing in common the adsorption equilibrium constants of different metal ions. (author)

Fluid Inclusion Analysis of other Host Minerals besides Quartz: Application to Granite-Related Quartz-Topaz Veins and Garnet Skarns in Porphyry Copper-Gold Ore Systems

OpenAIRE

Schlöglova, Katerina

2018-01-01

Fluid inclusions are the only available samples of paleo-fluids responsible for crystallization of hydrothermal minerals including ore phases. Analysis of fluid inclusions implicitly assumes that the inclusions have preserved their chemical composition since the time of their entrapment. There is, however, an increasing evidence from experimental work and analytical studies of natural samples showing that inclusions hosted in quartz – a ubiquitous host in many ore-forming systems – can experi...

Late Cretaceous porphyry copper mineralization in Sonora, Mexico: Implications for the evolution of the Southwest North America porphyry copper province

Science.gov (United States)

Barra, Fernando; Valencia, Victor A.

2014-10-01

Two porphyry Cu-Mo prospects in northern Sonora, Mexico (Fortuna del Cobre and Los Humos) located within the southwestern North American porphyry province have been dated in order to constrain the timing of crystallization and mineralization of these ore deposits. In Fortuna del Cobre, the pre-mineralization granodiorite porphyry yielded an U-Pb zircon age of 76.5 ± 2.3 Ma, whereas two samples from the ore-bearing quartz feldespathic porphyry were dated at 74.6 ± 1.3 and 75.0 ± 1.4 Ma. Four molybdenite samples from Los Humos porphyry Cu prospect yielded a weighted average Re-Os age of 73.5 ± 0.2 Ma, whereas two samples from the ore-bearing quartz monzonite porphyry gave U-Pb zircon ages of 74.4 ± 1.1 and 74.5 ± 1.3 Ma, showing a Late Cretaceous age for the emplacement of this ore deposit. The results indicate that Laramide porphyry Cu mineralization of Late Cretaceous age is not restricted to northern Arizona as previously thought and provide evidence for the definition of NS trending metallogenic belts that are parallel to the paleo-trench. Porphyry copper mineralization follows the inland migration trend of the magmatic arc as a result of the Farallon slab flattening during the Laramide orogeny.

Activation energies from blue- and red-thermoluminescence (TL) of quartz grains and mean lives of trapped electrons related to natural red-TL

International Nuclear Information System (INIS)

Hashimoto, T.; Kojima, M.; Shirai, N.; Ichino, M.

1993-01-01

A three-dimensional representation of thermoluminescence (TL) spectra has been established by employing an image intensifier unit combined with a simple spectrophotometer and a microcomputer. By means of this TL spectrometric system, natural quartz grains could be distinguished as either blue-and/or red-TL ones. In these blue- and red-TL wavelength regions, activation energies from artificially irradiated quartz grains are evaluated using a repeated initial rise method. An apparent difference of activation energies in the two colorations was observed for dune sands presumably originating from different quartz sources. On the other hand, quartz grains extracted from a volcanic ash sediment showed completely similar activation energies in both TL color regions over all temperatures. Subsequently, the kinetic parameters were derived for the naturally occurring red-TL, possessing an apparent single peak around 340 o C, from volcanically originating quartz grains by fitting a theoretical equation to the glow curves, after evaluating activation energies. On the basis of the empirical kinetic parameters, the mean life of trapped electrons relating to a main 340 o C peak has been proved to be 1 million years, and a secondary weak peak around 280 o C in the natural red-TL glow curve has been confirmed. (author)

Geology, mineralization, Rb-Sr & Sm-Nd geochemistry, and U–Pb zircon geochronology of Kalateh Ahani Cretaceous intrusive rocks, southeast Gonabad

Directory of Open Access Journals (Sweden)

Mohammad Hassan Karimpour

2013-10-01

Full Text Available Kalateh Ahani is located 27 km southeast of Gonabad within the Khorasan Razavi province. The area is part of Lut Block. Sub-volcanic monzonitic rocks intruded regional metamorphosed Shemshak Formation (Jurassic age. Magnetic susceptibility of less altered monzonitic rocks is 0.6%., As, Pb and Zn > 1%, Au up to 150 ppb and Sn = 133 ppm. The Sn content of vein in the northern part of Kalateh Ahani (Rud Gaz is > 1%. Based on mineralization, alteration and geochemistry, it seems that Sn mineralization is associated with the Cretaceous monzonitic rocks. Zircon U–Pb dating indicates that the age of the monzonitic rocks associated with mineralization is 109 Ma (Lower Cretaceous. Based on (87Sr/86Sri = 0.71089-0.710647 and (143Nd/144Ndi = 0.512113-0.51227 of the monzonitic rocks, the magma for these rocks were originated from the continental crust. This research has opened new window with respect to Sn-Cu mineralization and exploration within the Lut Block which is associated with Cretaceous granitoid rocks (reduced type, ilmenite series originated from the continental crust.

The role of the incommensurate phase in the opalescence of quartz

Science.gov (United States)

Dolino, G.; Bastie, P.

2001-12-01

Forty five years ago, an intense light scattering was observed at the α-β transition of quartz but the origin of this opalescence has remained mysterious for a long time. Recently Saint-Grégoire et al and Aslanyan et al have explained the origin of the opalescence by introducing new incommensurate (`inc') phases with ferroelastic properties in the transition region. In this paper we recall the main features of the α-β transition, of the inc phase and of the opalescence of quartz, which presents different properties in two regions of the α-inc phase boundary. We also describe the three typical structures observed in the phase boundary regions by electron microscopy. We present briefly the two previous ferroelastic models and we propose our own explanation for the origin of the opalescence. We discuss the relations of these three models with experimental results concerning thermal behaviour, microscopic structures and the origin of the refractive index variations. Most experimental results are in agreement, at least qualitatively, with our model where the two opalescence regions correspond respectively to the presence of inc rotation patches and of irregular Dauphiné microtwins, both in a non-equilibrium state.

The role of the incommensurate phase in the opalescence of quartz

Energy Technology Data Exchange (ETDEWEB)

Dolino, G.; Bastie, P. [Laboratoire de Spectrometrie Physique, Universite J. Fourier (Grenoble I), CNRS UMR 5588, BP 87, Saint Martin d' Heres Cedex (France)]. E-mail: Dolino@spectro.ujf-grenoble.fr

2001-12-17

Forty five years ago, an intense light scattering was observed at the {alpha}-{beta} transition of quartz but the origin of this opalescence has remained mysterious for a long time. Recently Saint-Gregoire et al and Aslanyan et al have explained the origin of the opalescence by introducing new incommensurate ('inc') phases with ferroelastic properties in the transition region. In this paper we recall the main features of the {alpha}- {beta} transition, of the inc phase and of the opalescence of quartz, which presents different properties in two regions of the -inc phase boundary. We also describe the three typical structures observed in the phase boundary regions by electron microscopy. We present briefly the two previous ferroelastic models and we propose our own explanation for the origin of the opalescence. We discuss the relations of these three models with experimental results concerning thermal behaviour, microscopic structures and the origin of the refractive index variations. Most experimental results are in agreement, at least qualitatively, with our model where the two opalescence regions correspond respectively to the presence of inc rotation patches and of irregular Dauphine microtwins, both in a non-equilibrium state. (author)

Optically stimulated luminescence techniques in retrospective dosimetry using single grains of quartz extracted from unheated materials

Energy Technology Data Exchange (ETDEWEB)

Joerkov Thomsen, Kristina

2004-02-01

This work investigates the possibility of applying optically stimulated luminescence (OSL) in retrospective dose determinations using unheated materials. It focuses on identifying materials suitable for use in assessment of doses absorbed as a consequence of radiation accidents (i.e. accident dosimetry). Special attention has been paid to quartz extracted from unheated building materials such as concrete and mortar. The single-aliquot regeneration-dose (SAR) protocol has been used to determine absorbed doses in small aliquots as well as single grains of quartz. It is shown that OSL measurements of single grains of quartz extracted from poorly-bleached building materials can provide useful information on radiation accident doses, even when the luminescence sensitivity is low. Sources of variance in well-bleached single grain dose distributions have been investigated in detail and it is concluded that the observed variability in the data is consistent with the sum (in quadrature) of a component, which depends on the number of photons detected from each grain, and a fixed component independent of light level. Dose depth profiles through laboratory irradiated concrete bricks have successfully been measured and minimum detection limits of less than 100 mGy are derived. Measurements of thermal transfer in single grains of poorly-bleached quartz show that thermal transfer is variable on a grain-to-grain basis and that it can be a source of variance in single-grain dose distributions. Furthermore, the potential of using common household and workplace chemicals, such as table salt, washing powder and water softener, in retrospective dosimetry has been investigated. It is concluded that such materials should be considered as retrospective dosimeters in the event of a radiation accident. (au)

In-homogeneity in the pre-dose sensitization of the 110 Degree-Sign C TL peak in various quartz samples: The influence of annealing

Energy Technology Data Exchange (ETDEWEB)

Polymeris, George S., E-mail: polymers@auth.gr [Laboratory of Radiation Applications and Archaeological Dating, Department of Archaeometry and Physicochemical Measurements, Cultural and Educational Technology Institute, Athena, Research and Innovation Center in Information, Communication and Knowledge Technologies, Tsimiski 58, GR-67100 Xanthi (Greece); ISIK University, Faculty of Science and Arts, Physics Department, Sile 34980, Istanbul (Turkey); Oniya, Ebenezer O. [Laboratory of Radiation Applications and Archaeological Dating, Department of Archaeometry and Physicochemical Measurements, Cultural and Educational Technology Institute, Athena, Research and Innovation Center in Information, Communication and Knowledge Technologies, Tsimiski 58, GR-67100 Xanthi (Greece); Physics and Electronics Department, Adekunle Ajasin University, PMB 01 Akungba Akoko (Nigeria); Jibiri, Nnamdi N. [Department of Physics, University of Ibadan, Ibadan (Nigeria); Tsirliganis, Nestor C. [Laboratory of Radiation Applications and Archaeological Dating, Department of Archaeometry and Physicochemical Measurements, Cultural and Educational Technology Institute, Athena, Research and Innovation Center in Information, Communication and Knowledge Technologies, Tsimiski 58, GR-67100 Xanthi (Greece); Kitis, George [Aristotle University of Thessaloniki, Nuclear Physics Laboratory, 54124 Thessaloniki (Greece)

2012-03-01

The pre-dose sensitization effect of the 110 Degree-Sign C TL glow-peak of quartz is a basic tool in thermoluminescence and optically stimulated luminescence dating and retrospective dosimetry. In the present work, a homogeneity study was performed on pre-dose sensitization in grains obtained from large quartz crystals samples collected from 10 different origins. The aliquot - to - aliquot scatter of the pre-dose sensitization of the 110 Degree-Sign C TL peak within each quartz crystal was monitored. The influence of the annealing on this scattering was also studied. Therefore, the investigation was applied to the un-fired 'as is' samples as well as to samples annealed at 900 Degree-Sign C for 1 h following cooling to room temperature in air. The results showed that in the case of 'as is' quartz the sensitization effect vary strongly within each aliquot of the same quartz sample. This strong variation is removed by both the high temperature annealing as well as heating up to 500 Degree-Sign C, involved in the TL measurements. These results are generally discussed in the framework of existing models and applications of the effect.

Determination of antimony by using a quartz atom trap and electrochemical hydride generation atomic absorption spectrometry

Energy Technology Data Exchange (ETDEWEB)

Menemenlioglu, Ipek; Korkmaz, Deniz [Department of Chemistry, Middle East Technical University, 06531 Ankara (Turkey); Ataman, O. Yavuz [Department of Chemistry, Middle East Technical University, 06531 Ankara (Turkey)], E-mail: ataman@metu.edu.tr

2007-01-15

The analytical performance of a miniature quartz trap coupled with electrochemical hydride generator for antimony determination is described. A portion of the inlet arm of the conventional quartz tube atomizer was used as an integrated trap medium for on-line preconcentration of electrochemically generated hydrides. This configuration minimizes transfer lines and connections. A thin-layer of electrochemical flow through cell was constructed. Lead and platinum foils were employed as cathode and anode materials, respectively. Experimental operation conditions for hydride generation as well as the collection and revolatilization conditions for the generated hydrides in the inlet arm of the quartz tube atomizer were optimized. Interferences of copper, nickel, iron, cobalt, arsenic, selenium, lead and tin were examined both with and without the trap. 3{sigma} limit of detection was estimated as 0.053 {mu}g l{sup -1} for a sample size of 6.0 ml collected in 120 s. The trap has provided 18 fold sensitivity improvement as compared to electrochemical hydride generation alone. The accuracy of the proposed technique was evaluated with two standard reference materials; Trace Metals in Drinking Water, Cat CRM-TMDW and Metals on Soil/Sediment 4, IRM-008.

Luminescence of quartz and feldspar fingerprints provenance and correlates with the source area denudation in the Amazon River basin

DEFF Research Database (Denmark)

Sawakuchi, A.O.; Jain, M.; Mineli, T.D.

2018-01-01

The Amazon region hosts the world's largest watershed spanning from high elevation Andean terrains to lowland cratonic shield areas in tropical South America. This study explores variations in optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL) signals in suspended...... silt and riverbed sands retrieved from major Amazon rivers. These rivers drain Pre-Cambrian to Cenozoic source rocks in areas with contrasting denudation rates. In contrast to the previous studies, we do not observe an increase in the OSL sensitivity of quartz with transport distance; for example...... shield areas (denudation rate ξ=0.04 mmyr−1), while low sensitivity quartz occurs in less stable Andean terrains (ξ=0.24 mmyr−1). An apparent linear correlation between quartz OSL sensitivity and denudation rate suggests that OSL sensitivity may be used as a proxy for erosion rates in the Amazon basin...

Influence of Mould Pressure and Substitution of Quartz by Palm Oil ...

African Journals Online (AJOL)

This paper presents use of treated palm oil fuel ash (POFA) as a substitute material for quartz in fabricating an improved porcelain tile. Untreated POFA was dried in an oven at 100ºC for 24 h. The untreated POFA was then grounded in a ball mill to reduce the particle size to improve reactivity. It was then sieved using a set of ...

Application of surface complexation modelling: Nickel sorption on quartz, manganese oxide, kaolinite and goethite, and thorium on silica

International Nuclear Information System (INIS)

Olin, M.; Lehikoinen, J.

1997-12-01

The study is a follow-up to a previous modelling task on mechanistic sorption. The experimental work has been carried out at the Laboratory of Radiochemistry, University of Helsinki (HYRL), and the sorption modelling was performed using the HYDRAQL code. Parameters taken from the open literature were employed in the modelling phase. The thermodynamic data for aqueous solutions were extracted from the EQ3/6 database and subsequently modified for HYDRAQL where necessary. The experimental data were obtained from five different experiments, four of which concerned the adsorption of nickel. The first experimental system was a mixture of Nilsiae quartz and manganese dioxide. In the second experiment, quartz was equilibrated with a fresh and saline groundwater simulant instead of an electrolyte solution. The third and fourth experiments dealt with nickel adsorption from an electrolyte solution onto goethite and kaolinite surfaces respectively. In the fifth experiment, adsorption of thorium onto a quartz surface was investigated

Zircon U-Pb and molybdenite Re-Os geochronology and Sr-Nd-Pb-Hf isotopic constraints on the genesis of the Xuejiping porphyry copper deposit in Zhongdian, Northwest Yunnan, China

Science.gov (United States)

Leng, Cheng-Biao; Zhang, Xing-Chun; Hu, Rui-Zhong; Wang, Shou-Xu; Zhong, Hong; Wang, Wai-Quan; Bi, Xian-Wu

2012-10-01

The Xuejiping porphyry copper deposit is located in northwestern Yunnan Province, China. Tectonically, it lies in the southern part of the Triassic Yidun island arc. The copper mineralization is mainly hosted in quartz-dioritic and quartz-monzonitic porphyries which intruded into clastic-volcanic rocks of the Late Triassic Tumugou Formation. There are several alteration zones including potassic, strong silicific and phyllic, argillic, and propylitic alteration zones from inner to outer of the mineralized porphyry bodies. The ages of ore-bearing quartz-monzonitic porphyry and its host andesite are obtained by using the zircon SIMS U-Pb dating method, with results of 218.3 ± 1.6 Ma (MSWD = 0.31, N = 15) and 218.5 ± 1.6 Ma (MSWD = 0.91, N = 16), respectively. Meanwhile, the molybdenite Re-Os dating yields a Re-Os isochronal age of 221.4 ± 2.3 Ma (MSWD = 0.54, N = 5) and a weighted mean age of 219.9 ± 0.7 Ma (MSWD = 0.88). They are quite in accordance with the zircon U-Pb ages within errors. Furthermore, all of them are contemporary with the timing of the Garzê-Litang oceanic crust subduction in the Yidun arc. Therefore, the Xuejiping deposit could be formed in a continental margin setting. There are negative ɛNd(t) values ranging from -3.8 to -2.1 and relatively high initial 87Sr/86Sr ratios from 0.7051 to 0.7059 for the Xuejiping porphyries and host andesites. The (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t values of the Xuejiping porphyries and host andesites vary from 17.899 to 18.654, from 15.529 to 15.626, and from 37.864 to 38.52, respectively, indicative of high radiogenic Pb isotopic features. In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS exhibit that there are quite uniform and slightly positive ɛHf(t) values ranging from -0.2 to +3.2 (mostly between 0 and +2), corresponding to relatively young single-stage Hf model ages from 735 Ma to 871 Ma. These isotopic features suggest that the primary magmas of the Xuejiping porphyries and

Radiation dose response correlation between thermoluminescence and optically stimulated luminescence in quartz

International Nuclear Information System (INIS)

Oniya, E.O.; Polymeris, G.S.; Tsirliganis, N.C.; Kitis, G.

2012-01-01

The fast, linearly modulated optically stimulated luminescence (LM-OSL) component in quartz is the main dosimetric signal used for the dating applications of this material. Since the blue light stimulation (470 nm, 40 mW cm −2 ) time needed to obtain the fast LM-OSL component is less than 50 s the electron trapping levels responsible for it are still highly populated. In this way an active radiation history is created which could play an important role in the dosimetric characteristics of the fast OSL signal. In the present work the dose response behavior of the fast OSL signal is investigated in quartz samples with an annealed radiation history and quartz samples possessing an artificial radiation history. A computerized curve de-convolution analysis of the LM-OSL curves for 50 s stimulation time showed that it consists of three individual OSL components. The faster component C 1 with peak maximum time around 5 s has a linear dose response in virgin samples, which turns to a slight superlinearity as a function of the artificial radiation history. On the other hand the component C 2 with peak maximum time at 12 s is slightly superlinear which turns into strong superlinearity as a function of artificial radiation history. Finally, component C 3 with peak maximum time at about 45 s is strongly superlinear for both virgin samples and as a function of artificial radiation history. The implications to practical application are discussed. - Highlights: ► The fast OSL component consists of three components. ► The linearity of first fast component does not depend on radiation history. ► The linearity of second and third components depend on radiation history. ► The TL between 180 and 300 °C is the major source of OSL.

Influence of preliminary reactor irradiation on defect formation in quartz fibers under γ- ray activity

International Nuclear Information System (INIS)

Ashurov, M.Kh.; Baydjanov, M.I.; Ibragimov, J.D.; Rustamov, I.R.; Islamov, A.Kh.; Nuritdinov, I.; Gasanov, E.M.; Yuldashev, B.S.

2006-01-01

Full text: For study of influence of preliminary structure defects and type of cladding material on additional defects accumulation kinetics we investigated the absorption spectra of optical fibers (OF) marked FVP-400 (quartz core and quartz clad) and FSHA-800 (quartz core and polymeric clad) preliminary irradiated by fast neutrons fluencies 10 12 , 10 13 , 10 14 , 10 15 cm -2 before and after additional irradiation by γ-rays of 60 Co source. Preliminary irradiation of samples was conducted in cadmium-plated channel of the reactor. Dose rate of accompanying γ-radiation is determined as 1250 R/s using KI quartz glass based dosimeter. The spectra of the induced absorption (losses) were calculated by an expression A(λ)=(10/L)x lg[T(λ)/T 0 (λ)], where T 0 (λ) and (λ) are transmissions of samples before and after irradiation, L-sample length [m], A(λ)- optical losses [dB/m]. It's established that the transformation processes of previously existing structure damages arising during fiber drawing into other ones and creations of additional defects under influence of neutrons depends on hydroxyl content and type of fibers cladding material. It's shown that under influence of γ-rays at doses 10 5 , 5·10 5 , 10 6 , 5.10 6 , 10 7 , 5·10 7 and 10 8 R the two-stage accumulation of non-bridging oxygen hole centers (NBOHC) is observed in preliminary neutron-irradiated OF. The first stage is caused by appearance of potential NBOHC arising during fiber drawing and irradiation of OF by neutrons. The dose value of γ-rays at the beginning of the second stage that is connected to creation of additional NBOHC under γ-rays action decreases with growth of preliminary irradiation fluence. We suppose that under neutron irradiation of OF along with transformation of previously existing damages and creation of additional point defects there is formation of areas with the higher density than in quartz glass which concentration increases with growth of irradiation fluence. Hence

Study of green quartz of hydrothermal origin treated by gamma radiation; Estudo do quartzo verde de origem hidrotermal tratado com radiacao gama

Energy Technology Data Exchange (ETDEWEB)

Enokihara, Cyro Teiti

2013-07-01

A specific variety of quartz showing a green color in nature or induced artificially by radiation is quite rare. This can be explained by the fact that the mechanism of formation of this color is very different from the ones widely discussed in the literature and responsible for the formation of the fumee, citrine and amethyst types of quartz, including the prasiolite (leak green quartz) formed by heating amethyst from Montezuma, Brazil. Only two occurrences are known today, where this type of quartz can be found: Canada, at the Thunder Bay Amethyst Mine, Ontario, a small district, and Brazil, at widely scattered geode occurrences along a 600 km stretch from Quarai at Brazils southernmost tip to Uberlandia in Minas Gerais. These two occurrences have been formed by strong hydrothermal activities, at Thunder Bay due to tectonics and in Brazil by meteoric and hydrothermal waters of the Guarani aquifer. That way much quartz crystals showed a very fast growth history facilitating the formation of growth defects (twinning, small angle tilting, mosaic growth, striations) and the uptake of water in form of micro inclusions, molecular water, silanol (Si-OH) and OH. This type of quartz can be considered 'wet quartz', similar to synthetic quartz. The water content with up to 3200 ppm by weight exceeds the amount of charge balancing cations (Fe, Al, Li). There is no correlation between water content and cations as in other color varieties. Instead, silanol complexes are formed, which by radiation due to gamma rays form the color center NBOHC (non-bonding oxygen hole defect), showing absorption between 590 to 620 nm and leaving a transmission window at about 550nm, responsible for the green color. To characterize samples which will be colored green by gamma rays analyses by ICP, NAA, Electron microscopy, water loss techniques and UV-VIS and NIR-FTIR spectroscopic have been made. The spectroscopic water determination showed less water (up to 2300 ppm by weight

Lectin typing of Campylobacter jejuni using a novel quartz crystal microbalance technique

Energy Technology Data Exchange (ETDEWEB)

Yakovleva, Maria E., E-mail: maria.yakovleva@gmail.com [Department of Infectious Diseases and Medical Microbiology, Lund University, 223 62 Lund (Sweden); Moran, Anthony P. [Department of Microbiology, School of Natural Sciences, National University of Ireland, Galway (Ireland); Safina, Gulnara R. [Department of Analytical and Marine Chemistry, University of Gothenburg, 412 96 Gothenburg (Sweden); Wadstroem, Torkel [Department of Infectious Diseases and Medical Microbiology, Lund University, 223 62 Lund (Sweden); Danielsson, Bengt [Acromed Invest AB, Magistratsvaegen 10, 226 43 Lund (Sweden)

2011-05-23

Seven Campylobacter jejuni strains were characterised by a lectin typing assay. The typing system was based on a quartz crystal microbalance technique (QCM) with four commercially available lectins (wheat germ agglutinin, Maackia amurensis lectin, Lens culinaris agglutinin, and Concanavalin A), which were chosen for their differing carbohydrate specificities. Initially, the gold surfaces of the quartz crystals were modified with 11-mercaptoundecanoic acid followed by lectin immobilisation using a conventional amine-coupling technique. Bacterial cells were applied for lectin typing without preliminary treatment, and resonant frequency and dissipation responses were recorded. The adhesion of microorganisms on lectin surfaces was confirmed by atomic force microscopy. Scanning was performed in the tapping mode and the presence of bacteria on lectin-coated surfaces was successfully demonstrated. A significant difference in the dissipation response was observed for different C. jejuni strains which made it possible to use this parameter for discriminating between bacterial strains. In summary, the QCM technique proved a powerful tool for the recognition and discrimination of C. jejuni strains. The approach may also prove applicable to strain discrimination of other bacterial species, particularly pathogens.

A quartz-based micro catalytic methane sensor by high resolution screen printing

Science.gov (United States)

Lu, Wenshuai; Jing, Gaoshan; Bian, Xiaomeng; Yu, Hongyan; Cui, Tianhong

2016-02-01

A micro catalytic methane sensor was proposed and fabricated on a bulk fused quartz substrate using a high resolution screen printing technique for the first time, with reduced power consumption and optimized sensitivity. The sensor was designed by the finite element method and quartz was chosen as the substrate material and alumina support with optimized dimensions. Fabrication of the sensor consisted of two MEMS processes, lift-off and high resolution screen printing, with the advantages of high yield and uniformity. When the sensor’s regional working temperature changes from 250 °C to 470 °C, its sensitivity increases, as well as the power consumption. The highest sensitivity can reach 1.52 mV/% CH4. A temperature of 300 °C was chosen as the optimized working temperature, and the sensor’s sensitivity, power consumption, nonlinearity and response time are 0.77 mV/% CH4, 415 mW, 2.6%, and 35 s, respectively. This simple, but highly uniform fabrication process and the reliable performance of this sensor may lead to wide applications for methane detection.

A quartz-based micro catalytic methane sensor by high resolution screen printing

International Nuclear Information System (INIS)

Lu, Wenshuai; Jing, Gaoshan; Bian, Xiaomeng; Yu, Hongyan; Cui, Tianhong

2016-01-01

A micro catalytic methane sensor was proposed and fabricated on a bulk fused quartz substrate using a high resolution screen printing technique for the first time, with reduced power consumption and optimized sensitivity. The sensor was designed by the finite element method and quartz was chosen as the substrate material and alumina support with optimized dimensions. Fabrication of the sensor consisted of two MEMS processes, lift-off and high resolution screen printing, with the advantages of high yield and uniformity. When the sensor’s regional working temperature changes from 250 °C to 470 °C, its sensitivity increases, as well as the power consumption. The highest sensitivity can reach 1.52 mV/% CH 4 . A temperature of 300 °C was chosen as the optimized working temperature, and the sensor’s sensitivity, power consumption, nonlinearity and response time are 0.77 mV/% CH 4 , 415 mW, 2.6%, and 35 s, respectively. This simple, but highly uniform fabrication process and the reliable performance of this sensor may lead to wide applications for methane detection. (paper)

Salinity of the Archaean oceans from analysis of fluid inclusions in quartz

Science.gov (United States)

Marty, Bernard; Avice, Guillaume; Bekaert, David V.; Broadley, Michael W.

2018-05-01

Fluids trapped in inclusions in well-characterized Archaean hydrothermal quartz crystals were analyzed by the extended argon-argon method, which permits the simultaneous measurement of chlorine and potassium concentrations. Argon and nitrogen isotopic compositions of the trapped fluids were also determined by static mass spectrometry. Fluids were extracted by stepwise crushing of quartz samples from North Pole (NW Australia) and Barberton (South Africa) 3.5-3.0-Ga-old greenstone belts. The data indicate that fluids are a mixture of a low salinity end-member, regarded as the Archaean oceanic water, and several hydrothermal end-members rich in Cl, K, N, and radiogenic parentless 40Ar. The low Cl-K end-member suggests that the salinity of the Archaean oceans was comparable to the modern one, and that the potassium content of the Archaean oceans was lower than at present by about 40%. A constant salinity of the oceans through time has important implications for the stabilization of the continental crust and for the habitability of the ancient Earth.

Lectin typing of Campylobacter jejuni using a novel quartz crystal microbalance technique

International Nuclear Information System (INIS)

Yakovleva, Maria E.; Moran, Anthony P.; Safina, Gulnara R.; Wadstroem, Torkel; Danielsson, Bengt

2011-01-01

Seven Campylobacter jejuni strains were characterised by a lectin typing assay. The typing system was based on a quartz crystal microbalance technique (QCM) with four commercially available lectins (wheat germ agglutinin, Maackia amurensis lectin, Lens culinaris agglutinin, and Concanavalin A), which were chosen for their differing carbohydrate specificities. Initially, the gold surfaces of the quartz crystals were modified with 11-mercaptoundecanoic acid followed by lectin immobilisation using a conventional amine-coupling technique. Bacterial cells were applied for lectin typing without preliminary treatment, and resonant frequency and dissipation responses were recorded. The adhesion of microorganisms on lectin surfaces was confirmed by atomic force microscopy. Scanning was performed in the tapping mode and the presence of bacteria on lectin-coated surfaces was successfully demonstrated. A significant difference in the dissipation response was observed for different C. jejuni strains which made it possible to use this parameter for discriminating between bacterial strains. In summary, the QCM technique proved a powerful tool for the recognition and discrimination of C. jejuni strains. The approach may also prove applicable to strain discrimination of other bacterial species, particularly pathogens.

Maurim intrusive suite: a calc-alkacic batholite zoned of catarinense shield

International Nuclear Information System (INIS)

Wildner, W.; Ramgrab, G.E.; Zanini, L.F.P.; Branco, P.M.; Camozzato, E.

1990-01-01

The geological survey of the Florianopolis Sheet (SG.22-Z-D-V) identified and characterized a calc-alkacic multi-intrusive and polydiapiric suite that occurs as a granitic batholite roughly concentric in texture and composition. This co-magmatic plutonic sequence is intrusive in the granite-gneissic basement of amphibolite facies, with which it was formerly confounded. The initial magmatic terms, put-in-place at the marginal portions of the batholite, are represented by quartz-diorites and tonalites (Forquilha Tonalites), followed by granodiorites (alto da Varginha Granodiorite), granodiorites to monzonites (Rio das Antas Granite) and completed by an inner portions of porphyritic monzonites (Sao Pedro de Alcantara Granite). The identifications of the compositional zoning that results from the development of the magmatic chamber is based on the examination of 74 rock samples that were analysed for major and minor oxides and trace elements (Ba, F, Li, Mo, Sn, W, Y, Rb, Nb, Zr and Sr). The treatment of these data shows the portions where mantle fractions predominate as well as the others where crustal meltings dominate, what demonstrates an origin by in situ differentiation processes, fractioning and different degrees of magmatic mixing. Geochronologic dating by Rb/Sr, K/Ar and U/Pb methods show isochronic and conventional ages of 600 to 700 m.y. that roughly are in accord with the temporal progress towards the younger felsic phases, putting this suite in the Upper Proterozoic age. The initial Sr sup(87) / Sr sup(86) ratios, around 0.710, point to a crustal origin with variable mantle contribution to these rocks. (author)

Structural match of heterogeneously nucleated Mn(OH)_2(s) nanoparticles on quartz under various pH conditions

International Nuclear Information System (INIS)

Jung, Haesung; Lee, Byeongdu; Jun, Young-Shin

2016-01-01

The early nucleation stage of Mn (hydr)oxide on mineral surfaces is crucial to understand its occurrence and the cycling of nutrients in environmental systems. However, there are only limited studies on the heterogeneous nucleation of Mn(OH)_2(s) as the initial stage of Mn (hydr)oxide precipitation. Here, we investigated the effect of pH on the initial nucleation of Mn(OH)_2(s) on quartz. Under various pH conditions of 9.8, 9.9, and 10.1, we analyzed the structural matches between quartz and heterogeneously nucleated Mn(OH)_2(s). The structural matches were calculated by measuring lateral and vertical dimensions using grazing incidence small angle X-ray scattering (GISAXS) and atomic force microscopy (AFM), respectively. We found that a poorer structural match occurred at a higher pH than at a lower pH. The faster nucleation at a higher pH condition accounted for the observed poorer structural match. By fitting the structural match using classical nucleation theory, we also calculated the interfacial energy between Mn(OH)_2(s) and water (γ_n_f = 71 ± 7 mJ/m"2). The calculated m values and γ_n_f provided the variance of interfacial energy between quartz and Mn(OH)_2(s): γ_s_n = 262–272 mJ/m"2. As a result, this study provides new qualitative and quantitative information about heterogeneous nucleation on environmentally an abundant mineral surface, quartz, and it offers important underpinnings for understanding the fate and transport of trace ions in environmental systems.

Quartz reserves in Brazil: planning and photovoltaic industry; Reservas de quartzo no Brasil: planejamento e Industria fotovoltaica

Energy Technology Data Exchange (ETDEWEB)

Marczewski, Breitner; Gonzalez, Mariana Pedrosa; Oliveira, Sergio H.F. [Universidade Federal do ABC (UFABC), Santo Andre, SP (Brazil). Dept. de Energia], emails: mariana.gonzalez@ufabc.edu.br, sergio.oliveira@ufabc.edu.br

2010-07-01

The goal of this research was examine the availability of part of Brazilian quartz resource for the construction of a photovoltaic industry in the country and the possibility to expand your contribution for others markets. The use of renewable alternative sources of energy has been wining more space in the last years, mainly for the photovoltaic technology. The exponential growth of this technology in the world at an average rate of 20% per year allows understand the importance and contribution for the spheres economic, social and environmental. The solar energy it's renewable and doesn't emit greenhouse gases during the generation of electric energy. Favor this background, research and academic development have been investing to make this technology more efficiency and cheap. In this context, Brazil is in a position unique for several aspects, for example, the incidence of high levels of solar radiation during the year, the amount of reserve of quartz, and now, the knowledge to produce this technology in laboratory scale. So, to achieve an hypothetical scenario for the construction of an national industry, to supply this technology not just for the country, as well to Latin America, help the planning and gives credibility for possible actions to be taken. Through the proposal scenario, the result gained was that is at least part of the reserve of quartz, in this case crystal of quartz enough to attend the insertion of 50 MW/year in the country and the possibility to supply international demand without compromise your on future electronic or photovoltaic industry. (author)

Application of titanium-in-quartz thermobarometry to greenschist facies veins and recrystallized quartzites in the Hsüehshan range, Taiwan

Directory of Open Access Journals (Sweden)

S. Kidder

2013-01-01

Full Text Available The accuracy, reliability and best practises of Ti-in-quartz thermobarometry (TitaniQ in greenschist facies rocks have not been established. To address these issues, we measured Ti concentrations in rutile-bearing samples of moderately deformed, partially recrystallized quartzite and vein quartz from the Hsüehshan range, Taiwan. The spread of Ti concentrations of recrystallized grains in quartzite correlates with recrystallized grain size. Recrystallized quartz (grain size ~100–200 μm that formed during early deformation within the biotite stability field shows a marked increase in intermediate Ti-concentration grains (~1–10 ppm relative to detrital porphyroclasts (Ti ~0.1–200 ppm. Fine recrystallized quartz (~5% of the samples by area, grain size ~10–20 μm has a further restricted Ti concentration peaking at 0.8–2 ppm. This trend suggests equilibration of Ti in recrystallized quartz with a matrix phase during deformation and cooling. Unlike previously documented examples, Ti concentration in the quartzite is inversely correlated with blue cathodoluminescence. Deformation was associated with a minimum grain boundary diffusivity of Ti on the order of 10−22m2 s−1. Vein emplacement and quartzite recrystallization are independently shown to have occurred at 250–350 °C and 300–410 °C, respectively, with lithostatic pressure of 3–4 kbar (assuming a geothermal gradient of 25° km−1, and with hydrostatic fluid pressure. Estimates of the accuracy of TitaniQ at these conditions depend on whether lithostatic or fluid pressure is used in the TitaniQ calibration. Using lithostatic pressure and these temperatures, the Thomas et al. (2010 calibration yields Ti concentrations within error of concentrations measured by SIMS. If fluid pressure is instead used, predicted temperatures are ~30–40 °C too low. TitaniQ has potential to yield accurate PT information for vein emplacement and dynamic recrystallization of quartz at

Effect of substitution of sand stone dust for quartz and clay in triaxial ...

Indian Academy of Sciences (India)

Few quartz grains (20–40μm) are associated with circumferential cracks around them. Keywords. Environmental pollutant; sand stone dust; ceramic tiles; pavement block; vitrification; ... increased risk of tuberculosis. Moreover, exposure ..... Health. 14 94. Hamano K, Nakagawa Z and Hasegawa M 1992 J. Ceram. Soc. Jap.

Ultimate waveform reproducibility of extreme-ultraviolet pulses by high-harmonic generation in quartz

Science.gov (United States)

Garg, M.; Kim, H. Y.; Goulielmakis, E.

2018-05-01

Optical waveforms of light reproducible with subcycle precision underlie applications of lasers in ultrafast spectroscopies, quantum control of matter and light-based signal processing. Nonlinear upconversion of optical pulses via high-harmonic generation in gas media extends these capabilities to the extreme ultraviolet (EUV). However, the waveform reproducibility of the generated EUV pulses in gases is inherently sensitive to intensity and phase fluctuations of the driving field. We used photoelectron interferometry to study the effects of intensity and carrier-envelope phase of an intense single-cycle optical pulse on the field waveform of EUV pulses generated in quartz nanofilms, and contrasted the results with those obtained in gas argon. The EUV waveforms generated in quartz were found to be virtually immune to the intensity and phase of the driving field, implying a non-recollisional character of the underlying emission mechanism. Waveform-sensitive photonic applications and precision measurements of fundamental processes in optics will benefit from these findings.