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Sample records for quartz isothermal tl

  1. Luminescence property of volcanic quartz and the use of red isothermal TL for dating tephras

    International Nuclear Information System (INIS)

    Tsukamoto, S.; Murray, A.S.; Huot, S.; Watanuki, T.; Denby, P.M.; Botter-Jensen, L.

    2007-01-01

    An optically stimulated luminescence (OSL) age obtained from a Japanese tephra using quartz phenocrysts severely underestimated the known age. The characteristics of the OSL signals were investigated in order to understand the cause of the underestimation; the main OSL component of volcanic quartz has a thermodynamic lifetime of about 1700 years at room temperature, and it also seems to fade anomalously (i.e. athermally). Measurement of conventional red thermoluminescence (RTL) using a Ga-As photomultiplier tube was difficult due to the presence of a strong thermal background, although RTL gave an age consistent with the independent age. Furthermore, red isothermal TL (RITL) at 380 deg. C allowed the RTL signal to be separated from to the thermal background, and RITL ages of three volcanic quartz samples show good agreement with independent ages

  2. Dose response, thermal stability and optical bleaching of the 310 degrees C isothermal TL signal in quartz

    DEFF Research Database (Denmark)

    Jain, Mayank; Duller, G.A.T.; Wintle, A.G.

    2007-01-01

    , thermal stability and the effects of optical bleaching. The (0-5s) signal shows all order of magnitude higher for saturation level with laboratory dose than the optically stimulated luminescence (OSL) signal, and has a thermal stability that is very sintilar to published values for the OSL or the 325...... degrees C TL peak. Bleaching with a solar simulator reduces both parts of the ITL signal to a low, but non-zero level in a few thousand seconds. This result is supported by an equivalent dose estimate oil a modern river sample from Zambia of 11 +/- 2 Gy. This combination of low residual dose and high...

  3. Natural quartz TL property and similarity in Piper nigrum L

    International Nuclear Information System (INIS)

    Guzman A, S.; Cruz Z, E.; Furetta, C.; Brown, F.; Barboza F, M.

    2009-10-01

    Quartz is a mineral abundant in nature and can provide information thermoluminescent (TL), and also is located in the mineral fraction of some herbs and spices consumed. It is present the analysis of the TL properties of a sample of natural quartz rock and compared with those obtained from the fraction of Piper nigrum L. poly mineral when they were exposed to 60 Co gamma radiation. The poly minerals of Piper nigrum L. were analyzed by X-ray diffraction, where the quartz was found as a major component. They separated in different particle sizes (10, 53, 74 and 149 μm). The samples were irradiated at relatively low doses (1-500 Gy) and high (0.1-40 kGy) in order to determine the linearity of the TL emission as a function of the dose and the analysis of glow curves. Also there was the fading of the TL signal, the effect of ultra violet light. The reproducibility of the TL signal in the samples indicates that a smaller particle size gives better TL signal. (author)

  4. TL response to quartz and aluminum oxide grain for α-irradiation

    International Nuclear Information System (INIS)

    Pan Baolin; Wei Mingjian; Li Dongxu; Liu Zhaowen; Liu Chao; Zhao Shiyuan

    2009-01-01

    Thermoluminescence (TL) response for an α-ray irradiation system ( 241 Am) was examined with quartz grains of 11-40 μm. Quartz grains of different sizes, i.e. 137 Cs), before they were irradiated to different doses by the α-ray irradiation system. TL response to the quartz grain samples was measured. TL response of the quartz grains smaller than 4 μm and 11-40 μm to α-ray irradiation is the best, as the α-rays cannot penetrate quartz larger than 40 μm. The TL response characteristic is related with quartz grain surface area. TL responses to α-irradiation of 11-40 μm quartz and aluminum oxide grains were compared. The α-irradiation TL response of aluminum oxide (330 degree C) is better than the quartz (375 degree C). (authors)

  5. Emission properties of thermoluminescence from natural quartz - blue and red TL response to absorbed dose

    International Nuclear Information System (INIS)

    Hashimoto, T.; Yokosaka, K.; Habuki, H.

    1987-01-01

    The TL spectrometry of natural quartz exposed to a gamma radiation dose of 8.8 kGy proved that the red TL, mainly from volcanically originated quartz, has a broad emission band with a peak around 620 nm, while the blue TL from plutonically originated quartz also has a broad emission band giving a peak around 470 nm. These typical red or blue intrinsic colours were also confirmed on the thermoluminescence colour images (TLCI). Exceptionally, a pegmatite quartz changed its TLCI colour from red to blue when the absorbed dose was increased. By using colour filter assemblies, all these quartz samples were shown to emit mainly blue and red TLs, which have distinctly different TL responses to the absorbed dose; the blue invariably showed a supralinearity relation between 1 and 10 kGy dose. For the purpose of dating, the use of red TL, is preferable. The red TL component is related to the impurity Eu content in quartz minerals. (author)

  6. TL Dating Technique Based on a Trap Model and its Application as a Geochronometer for Granitic Quartz

    International Nuclear Information System (INIS)

    Han, Y.; Li, H.; Tso, Y.W.

    1999-01-01

    A trap model is introduced to describe the behaviours of both thermally sensitive and radiation sensitive TL traps. The former are relatively shallow traps. The latter are deep traps, in which population increases with exposure to alpha dose. Thermal decay of both types of traps at ambient temperature is dependent on the trap lifetimes. A trap's population can be measured as TL sensitivity to a laboratory test dose. The trap model has been supported by observations of age dependent TL signals from granitic quartz samples with different crystallisation ages. The trap lifetimes are from 1.98 x 10 9 to 5.36 x 10 15 years estimated using the isothermal decay experiment with the assumption of first order kinetics. Dating techniques are proposed based on the trap model. For old granites (>400 Ma), ages can be obtained by measuring the total exposed alpha dose using the additive alpha dose method, whereas for young granites (<400 Ma), ages can also be obtained by interpolating the TL sensitivity to a curve of TL sensitivities for known ages. (author)

  7. Trace element geochemistry and thermoluminescence (TL) of quartz ...

    African Journals Online (AJOL)

    *

    3Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China. ... exposure in the recent twenty years, the TL characteristics of the fish otolith have not yet been ..... New discoveries in the study of carp otoliths.

  8. OSL, TL and IRSL emission spectra of sedimentary quartz and feldspar samples

    International Nuclear Information System (INIS)

    Lomax, Johanna; Mittelstraß, Dirk; Kreutzer, Sebastian; Fuchs, Markus

    2015-01-01

    This contribution presents a variety of different luminescence emission spectra from sedimentary feldspar and quartz samples under various stimulation modes. These are green stimulated quartz (OSL-) spectra, quartz TL spectra, feldspar IRSL and post-IR IRSL spectra. A focus was set at recording OSL and IRSL spectra at elevated stimulation temperatures such as routinely applied in luminescence dating. This was to test whether optical stimulation at elevated temperatures results in a shift of emission peaks. For OSL emissions of quartz, this has so far not been tested. In case of feldspar emissions, post-IR IRSL conditions, hence IRSL emissions at a low temperature, directly followed by high temperature post-IRSL emissions, are explicitly investigated. All spectra were recorded using a new system incorporated into a Lexsyg luminescence reader. Thus, this study, besides presenting new spectral data, also serves as a feasibility study for this new device. It is shown that (a) the new device is capable of automatically measuring different sorts of spectra, also at elevated temperatures, (b) known thermally and optically stimulated peak emissions of quartz and feldspar are confirmed, (c) obtained IRSL and OSL spectra indicate that there is no significant relation between peak emission and stimulation temperature. - Highlights: • We have measured OSL, IRSL and TL emission spectra of sedimentary quartz and feldspar samples. • Spectral analyses were performed at elevated stimulation temperatures. • Emission spectra show very little variation with stimulation temperatures.

  9. Activation energies from blue- and red-thermoluminescence (TL) of quartz grains and mean lives of trapped electrons related to natural red-TL

    International Nuclear Information System (INIS)

    Hashimoto, T.; Kojima, M.; Shirai, N.; Ichino, M.

    1993-01-01

    A three-dimensional representation of thermoluminescence (TL) spectra has been established by employing an image intensifier unit combined with a simple spectrophotometer and a microcomputer. By means of this TL spectrometric system, natural quartz grains could be distinguished as either blue-and/or red-TL ones. In these blue- and red-TL wavelength regions, activation energies from artificially irradiated quartz grains are evaluated using a repeated initial rise method. An apparent difference of activation energies in the two colorations was observed for dune sands presumably originating from different quartz sources. On the other hand, quartz grains extracted from a volcanic ash sediment showed completely similar activation energies in both TL color regions over all temperatures. Subsequently, the kinetic parameters were derived for the naturally occurring red-TL, possessing an apparent single peak around 340 o C, from volcanically originating quartz grains by fitting a theoretical equation to the glow curves, after evaluating activation energies. On the basis of the empirical kinetic parameters, the mean life of trapped electrons relating to a main 340 o C peak has been proved to be 1 million years, and a secondary weak peak around 280 o C in the natural red-TL glow curve has been confirmed. (author)

  10. The E{sub 1}'-centre and its role in TL sensitization in quartz

    Energy Technology Data Exchange (ETDEWEB)

    Benny, P.G. E-mail: sunsab@magnum.barc.ernet.in; Gundu Rao, T.K.; Bhatt, B.C

    2002-08-01

    The effect of UV (253.7 nm) bleaching and subsequent thermal annealing treatment in the range 400-500 deg. C, were studied in order to investigate the role of E{sub 1}'-centre on sensitization of 110 deg. C and 220 deg. C peaks in quartz. The decay of E{sub 1}'-centre in thermal annealed samples and observation of E{sub 1}'-centres after UV bleach, accompanied by desensitization of TL in the quartz sample, appears to lend support to the role of competing traps and E{sub 1}'-centres in the sensitization process.

  11. Development of a red TL detection system for a single grain of quartz

    International Nuclear Information System (INIS)

    Yawata, T.; Hashimoto, T.

    2007-01-01

    Red thermoluminescence (RTL) of natural quartz grains offers many desirable properties for quaternary chronology and archaeological dating, although RTL measurements suffer from high thermal background due to black-body radiation on heating. To reduce the thermal background to as low a level as possible, a silver sample disc covered with a biotite plate with a sample hole was used in combination with a light guide, cluster heater, optical filters, and photomultiplier tube cooling to -20 deg. C in the present system. As a result, the thermal background decreased from 2x10 4 to 1000 cps in the temperature range 350-380 deg. C, resulting in a detection limit of approximately 100 cps, corresponding to the RTL signal from a single quartz grain (250-500μm) irradiated with 4.0 Gy. In addition, application of lower heating rates retarded the thermal quenching effect, resulting in high RTL signals, which are preferable for young or insensitive quartz samples. Using RTL measurements with the single quartz grain method under optimal RTL conditions, comparison of equivalent doses from artificially irradiated single quartz grains to the known dose was within the 20% measurement error. Based on equivalent dose determinations for single quartz grains, large irregularities on non-etched quartz surfaces might be very detrimental to the TL detection process. This result confirms that surface etching treatment is required to achieve reliable dating with high counting efficiency

  12. The correlation of fast OSL component with the TL peak at 3250C in quartz of various origins

    International Nuclear Information System (INIS)

    Kitis, G.; Kiyak, N.; Polymeris, G.S.; Tsirliganis, N.C.

    2010-01-01

    The fast component of the optically stimulated luminescence (OSL) signal in quartz is the basic tool for the optical dating. Its relation with the thermoluminescence (TL) glow-peak at about 325 deg. C is well established for naturally irradiated quartz. This relationship is also an important part of a general model for quartz on which many theoretical simulations of various OSL experimental results have been based. In the present work this relationship is systematically investigated in nine quartz samples of different origin. The linearly modulated OSL (LM-OSL) curves of all quartz samples for stimulation time less than 50 s consists of two components discriminated easily by a computerized curve deconvolution (CCD) analysis. By comparing the un-bleached to the respective bleached TL glow-curve, it is found that the system of these two fast OSL components is directly related with only a small portion of the electron traps responsible for the TL glow-peaks in the temperature region 200-400 0 C. By increasing the stimulation times, besides the two fast components, the medium and the slow components are also obtained. The medium and slow components are clearly related with the main body of the electron traps responsible for TL glow-peaks in the same temperature region 200-400 0 C. Despite their different origin all quartz samples show an appreciable homogeneity concerning the number and time position of the individual components, whereas, the relative TL/OSL intensities vary strongly from sample to sample with the integrated TL intensity being generally much less than the integrated OSL intensity.

  13. TL sensitivity constancy of quartz upon UV+(β,γ) irradiation cycle: An improvement on dating methodology

    International Nuclear Information System (INIS)

    Souza, J.H.

    1985-01-01

    Thermoluminescence (TL) sensivitivy of natural quartz (beaches, paleobeaches and fixed dunes) to Beta and Gamma rays has been studied in a temperature range between 250-400 0 C, before and after bleaching by solar irradiation. A first TL glow growth curve was obtained through Beta irradiation of 'as found' samples and a second glow growth curve was obtained by bleaching through solar irradiation the TL acquired either through an excitation Gamma dose or through environmental radiation to finally re-irradiate the samples under Beta rays. Experimental results showing the constancy of sensitivity, for doses of until about 10K rads, are the basis for a proposal to improve TL dating methodology expanding its present limits. (Author) [pt

  14. Relative response of TL and component-resolved OSL to alpha and beta radiations in annealed sedimentary quartz

    International Nuclear Information System (INIS)

    Polymeris, George S.; Afouxenidis, Dimitrios; Raptis, Spyridoula; Liritzis, Ioannis; Tsirliganis, Nestor C.; Kitis, George

    2011-01-01

    Knowledge of the relative luminescence response to alpha and beta radiation is very important in TL and OSL dating. In the present study the relative alpha to beta response is studied in a sedimentary quartz sample, previously fired at 900 deg. C for 1 h, in the dose region between 1 and 128 Gy, for both thermoluminescence (TL) and linearly modulated optically stimulated luminescence (LM - OSL). The LM - OSL measurements were performed at room temperature and at 125 deg. C. All OSL signals were deconvolved into their individual components. Comparison of OSL curves after alpha and beta irradiation strongly supports that quartz OSL components follow first order kinetics in both cases. In the case of TL, the relative alpha to beta response is found to be very different for each TL glow-peak, but it does not depend strongly on irradiation dose. In the case of LM - OSL measurements, it is found that the relative behaviour of the alpha to beta response is different for three distinct regions, namely the fast OSL component, the region of medium OSL component originating from the TL glow-peak at 110 deg. C when stimulation takes place at room temperature and finally the region of slow OSL component. Following stimulation at ambient temperature, the relative alpha to beta response of all components was not observed to depend significantly on dose, with the value of ratio being 0.03 and a tendency to decrease with increasing dose. However, in the case of measurements performed at 125 deg. C, the relative response of the fast components is much enhanced, and for the remaining components it increases with increasing dose. Special care must be taken to examine the relative alpha to beta response of the fast component at 125 deg. C which contrasts the relative response of the TL peak at ca. 325 deg. C. The implications for the dating of annealed quartz are also briefly discussed. - Highlights: → Relative alpha to beta response for TL and LM-OSL is studied in annealed

  15. Dependence of TL-property changes of natural quartzes on aluminium contents accompanied by thermal annealing treatment

    International Nuclear Information System (INIS)

    Hashimoto, T.; Sakaue, S.; Aoki, H.; Ichino, M.

    1994-01-01

    The TL properties were investigated using both an IPDA (Intensified Photo-Diode Array) spectrometric system and a TLCI (Thermoluminescence Colour Image) method after thermal annealing treatment at several temperatures. An apparent colour change from original blue- (BTL) to red-TL(RTL) has unexpectedly occurred in a Z-cut slice of Madagascar quartz, after an annealing treatment around 1000 o C. From the TL-colour change studies of the Z-cut slice, it was confirmed that original BTL intensities are inversely proportional to the Al contents; the TLCI-patterns of the original or annealed Z-cut slice gave stripe patterns corresponding to Al impurity contents along the crystal growth direction particularly yielding an intense appearance of RTL on higher Al contents after the annealing treatment. This changeability of TL-colour towards RTL after thermal annealing treatment was found to be intimately correlated with the square of Al concentrations, although BTL clearly changed as linearly proportional to Al impurity contents. Finally, the cleavage of Al-O-Al bonds or some sites in the vicinity of Al-O-Al bonds were plausibly considered to play an important role for the formation of RTL colour centres in natural quartzes as a result of the operation of high temperature effects. (Author)

  16. Investigation of the thermal stability of 210 deg. C TL peak of quartz and dating the components of terrazzo from the monastery church of Tegernsee

    International Nuclear Information System (INIS)

    Goeksu, H.Y.; Schwenk, P.; Semiochkina, N.

    2001-01-01

    The lifetime of the thermoluminescence (TL) peak of quartz observed at 210 deg. C using 5 deg. C/s heating rate is assessed using well-dated thermally isolated bricks from a monastery and exposed bricks from warmer climatic zones by comparing the absorbed dose obtained using the 210 deg. C TL peak with those obtained from 310 deg. C TL peak. The lifetimes of the 210 deg. C TL peak calculated for samples collected from thermally isolated excavations and exposed buildings are found to be clustered around 8000-10000 and 600-800 years, respectively. The results proved that 210 deg. C TL peak could be used for dating of samples younger than 1000 years without thermal correction if the samples are thermally isolated from their environment. TL ages are obtained using quartz, polyminerals from brick pieces as well as flint splinters, and other quartz inclusions extracted from the mortar of the terrazzo floor of the monastery church. The measured TL ages and the consistency of the results are discussed. The fine grains in the mortar, which contained calcite/aragonite, could not be dated using thermoluminescence due to presence of a very strong non-radiation induced TL glow

  17. Humidity scanning quartz crystal microbalance with dissipation monitoring setup for determination of sorption-desorption isotherms and rheological changes

    Energy Technology Data Exchange (ETDEWEB)

    Björklund, Sebastian, E-mail: sebastianbjorklund@gmail.com; Kocherbitov, Vitaly [Department of Biomedical Science, Faculty of Health and Society, Malmö University, Malmö (Sweden); Biofilms—Research Center for Biointerfaces, Malmö University, Malmö (Sweden)

    2015-05-15

    A new method to determine water sorption-desorption isotherms with high resolution in the complete range of water activities (relative humidities) is presented. The method is based on quartz crystal microbalance with dissipation monitoring (QCM-D). The QCM-D is equipped with a humidity module in which the sample film is kept in air with controlled humidity. The experimental setup allows for continuous scanning of the relative humidity from either dry to humid conditions or vice versa. The amount of water sorbed or desorbed from the sample is determined from the resonance frequencies of the coated quartz sensor, via analysis of the overtone dependence. In addition, the method allows for characterization of hydration induced changes of the rheological properties from the dissipation data, which is closely connected to the viscoelasticity of the film. The accuracy of the humidity scanning setup is confirmed in control experiments. Sorption-desorption isotherms of pig gastric mucin and lysozyme, obtained by the new method, show good agreement with previous results. Finally, we show that the deposition technique used to coat the quartz sensor influences the QCM-D data and how this issue can be used to obtain further information on the effect of hydration. In particular, we demonstrate that spin-coating represents an attractive alternative to obtain sorption-desorption isotherms, while drop-coating provides additional information on changes of the rheological properties during hydration.

  18. Interlaboratory beta source calibration using TL and OSL on natural quartz

    DEFF Research Database (Denmark)

    Goksu. H.Y.; Bailiff, I.K.; Bøtter-Jensen, L.

    1995-01-01

    Laboratory at GSF using a Go-60 source as well as the in situ measurements with an ionization chamber, calibrated to the primary standards of PTB Braunschweig. Irradiated and unirradiated quartz was distributed to the five laboratories and although different procedures were used for thermoluminescence...

  19. An investigation of coseismic OSL / TL time zeroing of quartz gouge based on low- to high-velocity friction experiments

    Science.gov (United States)

    Akasegawa, K.; Oohashi, K.; Hasebe, N.; Miura, K.

    2016-12-01

    To determine an age of coseismic event of an active fault, we generally examine crosscutting relationship between faults and overlying strata by trenching. However, we could not apply this method in case there are no overlying young strata in the vicinity of the fault zones. The alternative is a dating of fault zone materials whose age experienced resetting with seismic fault slip (for example, the ESR method;. Ikeya et al,1982; the OSL and TL methods). The idea behinds to the OSL (optically stimulated luminescence) and TL (thermoluminescence) dating methods for a determination of paleo-earthquake event is the accumulated natural radiation damage becomes to zero (time zeroing) by the frictional heating and grinding. However, physical and geological conditions required to induce time zeroing is not well understood because there is only few experimental investigations under the limited conditions (Hiraga et al,2004;. Kim et al, 2014) . In this study, we conduct low- to high-velocity friction experiments using quartz gouge under various experimental conditions (e.g., normal stress, displacement, moisture content) to establish an empirical relationship and physical and geological conditions of coseismic OSL time zeroing. In this experiment, we carry out the friction experiments using quartz in Tsushigawa granite taken from the east wall of the Nojima fault Ogura trench site, which was excavated in 2015. Samples were taken from the most distant position from the fault in the trench site. The samples were clashed using a mortar and sieved to a grain size of treatment. The residual is user for the friction experiments after having known radiation dose using an artificial gamma-ray source. In this presentation, we show results of the friction experiments and dating of the quartz gouge and discuss physical and geological conditions of OSL time zeroing. References Okumura, T., and Shitaoka, Y., 2011. Engineering Geology of Japan, No. 1, 5-17. Hiraga, S., Yoshimoto, A., and

  20. In-homogeneity in the pre-dose sensitization of the 110 °C TL peak in various quartz samples: The influence of annealing

    International Nuclear Information System (INIS)

    Polymeris, George S.; Oniya, Ebenezer O.; Jibiri, Nnamdi N.; Tsirliganis, Nestor C.; Kitis, George

    2012-01-01

    The pre-dose sensitization effect of the 110 °C TL glow-peak of quartz is a basic tool in thermoluminescence and optically stimulated luminescence dating and retrospective dosimetry. In the present work, a homogeneity study was performed on pre-dose sensitization in grains obtained from large quartz crystals samples collected from 10 different origins. The aliquot – to – aliquot scatter of the pre-dose sensitization of the 110 °C TL peak within each quartz crystal was monitored. The influence of the annealing on this scattering was also studied. Therefore, the investigation was applied to the un-fired “as is” samples as well as to samples annealed at 900 °C for 1 h following cooling to room temperature in air. The results showed that in the case of “as is” quartz the sensitization effect vary strongly within each aliquot of the same quartz sample. This strong variation is removed by both the high temperature annealing as well as heating up to 500 °C, involved in the TL measurements. These results are generally discussed in the framework of existing models and applications of the effect.

  1. In-homogeneity in the pre-dose sensitization of the 110 Degree-Sign C TL peak in various quartz samples: The influence of annealing

    Energy Technology Data Exchange (ETDEWEB)

    Polymeris, George S., E-mail: polymers@auth.gr [Laboratory of Radiation Applications and Archaeological Dating, Department of Archaeometry and Physicochemical Measurements, Cultural and Educational Technology Institute, Athena, Research and Innovation Center in Information, Communication and Knowledge Technologies, Tsimiski 58, GR-67100 Xanthi (Greece); ISIK University, Faculty of Science and Arts, Physics Department, Sile 34980, Istanbul (Turkey); Oniya, Ebenezer O. [Laboratory of Radiation Applications and Archaeological Dating, Department of Archaeometry and Physicochemical Measurements, Cultural and Educational Technology Institute, Athena, Research and Innovation Center in Information, Communication and Knowledge Technologies, Tsimiski 58, GR-67100 Xanthi (Greece); Physics and Electronics Department, Adekunle Ajasin University, PMB 01 Akungba Akoko (Nigeria); Jibiri, Nnamdi N. [Department of Physics, University of Ibadan, Ibadan (Nigeria); Tsirliganis, Nestor C. [Laboratory of Radiation Applications and Archaeological Dating, Department of Archaeometry and Physicochemical Measurements, Cultural and Educational Technology Institute, Athena, Research and Innovation Center in Information, Communication and Knowledge Technologies, Tsimiski 58, GR-67100 Xanthi (Greece); Kitis, George [Aristotle University of Thessaloniki, Nuclear Physics Laboratory, 54124 Thessaloniki (Greece)

    2012-03-01

    The pre-dose sensitization effect of the 110 Degree-Sign C TL glow-peak of quartz is a basic tool in thermoluminescence and optically stimulated luminescence dating and retrospective dosimetry. In the present work, a homogeneity study was performed on pre-dose sensitization in grains obtained from large quartz crystals samples collected from 10 different origins. The aliquot - to - aliquot scatter of the pre-dose sensitization of the 110 Degree-Sign C TL peak within each quartz crystal was monitored. The influence of the annealing on this scattering was also studied. Therefore, the investigation was applied to the un-fired 'as is' samples as well as to samples annealed at 900 Degree-Sign C for 1 h following cooling to room temperature in air. The results showed that in the case of 'as is' quartz the sensitization effect vary strongly within each aliquot of the same quartz sample. This strong variation is removed by both the high temperature annealing as well as heating up to 500 Degree-Sign C, involved in the TL measurements. These results are generally discussed in the framework of existing models and applications of the effect.

  2. Effect of particle size in the TL response of natural quartz sensitized by high dose of gamma radiation and heat-treatments

    Directory of Open Access Journals (Sweden)

    Álvaro Barbosa de Carvalho Jr

    2010-06-01

    Full Text Available This work investigates the effect of particle size in the thermoluminescence (TL response of a quartz crystal that was initially crushed and classified into ten size fractions between 38 μm and 5 mm. Aliquots of each size fraction were sensitized with a dose of 25 kGy of γ rays and heat-treatments at 400 °C. TL glow curves of sensitized and non-sensitized samples were recorded as a function of different test-doses of γ rays. For the non-sensitized samples, the TL peak near 325 °C increases with the decrease in particle size. In the case of sensitized samples, a strong TL peak near 300 °C increases with the increase in particle size up to mean grain size equal to 304 μm. Above 304 μm, an abrupt reduction in the TL intensity is noticed for the sensitized peak. These effects are discussed in relation to the specific surface area of quartz particles and the intensity of the electron paramagnetic resonance signal of the E'1 center induced by the sensitization process.

  3. The TL and room temperature OSL properties of the glow peak at 110 deg. C in natural milky quartz: A case study

    International Nuclear Information System (INIS)

    Polymeris, George S.; Afouxenidis, Dimitrios; Tsirliganis, Nestor C.; Kitis, George

    2009-01-01

    The LM-OSL signal of quartz, while measured at room temperature, is dominated by an intermediate, broad and intense OSL component, so that its contribution and general characteristics are derived very accurately. Through a series of dose-response, bleaching and thermal decay at room temperature experiments, in conjunction with curve fitting studies, a component resolved analysis is carried out studying the correlation between this specific component, termed as LM-OSL component C 2 and the 110 deg. C TL glow peak in quartz. The dose-response of these two luminescence components behaves exactly similar being linear at low doses and saturating at almost 100 Gy. Both signals decay exponentially under illumination, providing identical optical detrapping cross-section values. Residual of both luminescence signals after thermal decay at room temperature follows an exponential law, yielding similar mean half-lives. All previous luminescence features provide strong evidence for the electron trap being the same for both the 110 deg. C TL trap and the LM-OSL component C 2 . The results of the present work are very promising and clearly support the possibility of extrapolating the TL pre-dose methodology to the OSL pre-dose effect using only the LM-OSL component C 2

  4. Progress and problems with automated TL dating

    International Nuclear Information System (INIS)

    McKerrell, H.; Mejdahl, V.

    1981-01-01

    A number of basic problems connected with the measurement of beta and gamma dose-rates are discussed, and the possibility of using low-temperature peaks in quartz and feldspar for dose-rate measurements is examined. Preliminary results of TL measurements on individual grains of quartz and feldspar are presented. A TL dating method based on the difference in the archaeological dose received by potassium feldspar and quartz grains is proposed. (author)

  5. Study of the lifetime of the TL peaks of quartz: comparison of the deconvolution using the first order kinetic with the initial rise method

    International Nuclear Information System (INIS)

    RATOVONJANAHARY, A.J.F.

    2005-01-01

    Quartz is a thermoluminescent material which can be used for dating and/or for dosimetry. This material has been used since 60s for dating samples like pottery, flint, etc., but the method is still subject to some improvement. One of the problem of thermoluminescence dating is the estimation of the lifetime of the ''used peak'' . The application of the glow-curve deconvolution (GCD) technique for the analysis of a composite thermoluminescence glow curve into its individual glow peaks has been applied widely since the 80s. Many functions describing a single glow peak have been proposed. For analysing quartz behaviour, thermoluminescence glow-curve deconvolution (GCD) functions are compared for first order of kinetic. The free parameters of the GCD functions are the maximum peak intensity (I m ) and the maximum peak temperature (T m ), which can be obtained experimentally. The activation energy (E) is the additional free parameter. The lifetime (τ) of each glow peak, which is an important factor for dating, is calculated from these three parameters. For ''used'' ''peak'' lifetime analysis, GCD results are compared to those from initial rise method (IRM). Results vary fairly from method to method. [fr

  6. Interaction of Soybean 7S Globulin Peptide with Cell Membrane Model via Isothermal Titration Calorimetry, Quartz Crystal Microbalance with Dissipation, and Langmuir Monolayer Study.

    Science.gov (United States)

    Zou, Yuan; Pan, Runting; Ruan, Qijun; Wan, Zhili; Guo, Jian; Yang, Xiaoquan

    2018-05-16

    To understand the underlying molecular mechanism of the cholesterol-lowering effect of soybean 7S globulins, the interactions of their pepsin-released peptides (7S-peptides) with cell membrane models consisting of dipalmitoylphosphatidylcholine (DPPC), dioleoylphosphatidylcholine (DOPC), and cholesterol (CHOL) were systematically studied. The results showed that 7S-peptides were bound to DPPC/DOPC/CHOL liposomes mainly through van der Waals forces and hydrogen bonds, and the presence of higher CHOL concentrations enhanced the binding affinity (e.g., DPPC/DOPC/CHOL = 1:1:0, binding ratio = 0.114; DPPC/DOPC/CHOL = 1:1:1, binding ratio = 2.02). Compression isotherms indicated that the incorporation of 7S-peptides increased the DPPC/DOPC/CHOL monolayer fluidity and the lipid raft size. The presence of CHOL accelerated the 7S-peptide accumulation on lipid rafts, which could serve as platforms for peptides to develop into β-sheet rich structures. These results allow us to hypothesize that 7S-peptides may indirectly influence membrane protein functions via altering the membrane organization in the enterocytes.

  7. Aberrant thermoluminescence dates obtained from primary volcanic quartz

    International Nuclear Information System (INIS)

    Guerin, Gilles; Samper, Agnes

    2007-01-01

    This study deals with the dating by thermoluminescence (TL) of quartz from six volcanic formations of the Saint Lucia Island (Lesser Antilles Arc). Quartz microcrystals up to one millimetre in size were extracted from dacites and pumice flows and prepared in a way similar to the well-known inclusion technique. The TL properties of these quartz were used to estimate apparent palaeodoses using the multi-aliquot protocol. The quartz TL was studied in three different spectral domains: red, green and ultraviolet/blue. The calculated annual dose-rates yielded a set of 18 age-estimates. For some samples complementary dates were obtained using high temperature TL (HTTL) of plagioclase feldspars. These latter dates combined with previously determined radiocarbon and unspiked K-Ar dates were used to explore the validity of ages computed from the TL of quartz. Individual values for quartz appear to be scattered and do not match ages deduced from 14 C, unspiked K-Ar or HTTL on plagioclase dates. These results indicate that when conventional TL methodologies derived from the inclusion method are applied to volcanic quartz major dating problems are to be expected

  8. Aberrant thermoluminescence dates obtained from primary volcanic quartz

    Energy Technology Data Exchange (ETDEWEB)

    Guerin, Gilles [Laboratoire des Sciences du Climat et de l' Environnement, CEA-CNRS, avenue de la Terrasse, 91191 Gif-sur-Yvette (France)], E-mail: gilles.guerin@u-psud.fr; Samper, Agnes [Laboratoire de geochronologie multitechnique (UPS-IPGP), Universite de Paris-Sud Orsay, 91405 Orsay Cedex (France)

    2007-10-15

    This study deals with the dating by thermoluminescence (TL) of quartz from six volcanic formations of the Saint Lucia Island (Lesser Antilles Arc). Quartz microcrystals up to one millimetre in size were extracted from dacites and pumice flows and prepared in a way similar to the well-known inclusion technique. The TL properties of these quartz were used to estimate apparent palaeodoses using the multi-aliquot protocol. The quartz TL was studied in three different spectral domains: red, green and ultraviolet/blue. The calculated annual dose-rates yielded a set of 18 age-estimates. For some samples complementary dates were obtained using high temperature TL (HTTL) of plagioclase feldspars. These latter dates combined with previously determined radiocarbon and unspiked K-Ar dates were used to explore the validity of ages computed from the TL of quartz. Individual values for quartz appear to be scattered and do not match ages deduced from {sup 14}C, unspiked K-Ar or HTTL on plagioclase dates. These results indicate that when conventional TL methodologies derived from the inclusion method are applied to volcanic quartz major dating problems are to be expected.

  9. Multi-method (TL and OSL), multi-material (quartz and flint) dating of the Mousterian site of Roc de Marsal (Dordogne, France): correlating Neanderthal occupations with the climatic variability of MIS 5–3

    DEFF Research Database (Denmark)

    Guerin, Guillaume; Discamps, Emmanuel; Lahaye, Christelle

    2012-01-01

    on unheated quartz. Chronological results combined with palaeoenvironmental data – faunal remains and micromorphological features in the sediments from the cave, pollen proxies and faunal remains from the region – allowed us to place climate variations in southwest France on a numerical time scale...

  10. Thermal quenching of thermoluminescence in quartz samples of various origin

    International Nuclear Information System (INIS)

    Subedi, B.; Oniya, E.; Polymeris, G.S.; Afouxenidis, D.; Tsirliganis, N.C.; Kitis, G.

    2011-01-01

    The effect of thermal quenching stands among the most important properties in the thermoluminescence (TL) of quartz on which many applications of TL are based. Since the quartz samples used in various applications are all of different origin it is useful to investigate whether the values of the thermal quenching parameters, i.e. the activation energy for thermal quenching W and a parameter C which describes the ratio of non-radiative to radiative luminescence transitions, evaluated mainly in specific quartz samples can be extrapolated to quartz samples of unknown origin as well as to quartz samples which are annealed at high temperatures. In the present work the TL glow curve of a series of un-annealed and annealed natural and synthetic quartz samples were studied as a function of the heating rate between 0.25 K/s and 16 K/s. Using an indirect fitting method it was found that the thermal quenching parameters W and C in most of the quartz samples are very similar to the values accepted in the literature. Furthermore, in some cases the thermal quenching parameters W and C are not the same for all TL glow-peaks in the same glow-curve. Finally, the strong external treatment of annealing the quartz samples at very high temperature can also influence at least one of the thermal quenching parameters.

  11. Luminescence sensitivity changes in quartz

    CERN Document Server

    Wintle, A G

    1999-01-01

    In the luminescence dating of sedimentary or heated quartz, some heat treatment is usually applied to the sample immediately prior to the measurement of the optically stimulated luminescence. In this paper we report experiments on a 30,000-year-old sedimentary quartz, in which we use the luminescence response to a test dose to monitor the changes in sensitivity that are caused by holding the quartz at temperatures from 160 to 280 deg. C for times from 10 s to 22 h. For an optically bleached sample, the monitoring is by both optically stimulated luminescence and the 110 deg. C TL peak; both luminescence signals are shown to have the same sensitisation (i.e. activation energy) characteristics. For natural or laboratory irradiated samples only the 110 deg. C TL peak can be used; sensitivity increases of up to a factor of 1.3 and 3 are observed for the natural and laboratory irradiated aliquots, respectively. Up to four exponential components are used to deconvolve the sensitivity change data; the dominant compon...

  12. Study of thermoluminescence response of purple to violet amethyst quartz from Balikesir, Turkey

    International Nuclear Information System (INIS)

    Nur, N.; Yeğingil, Z.; Topaksu, M.; Kurt, K.; Doğan, T.; Sarıgül, N.; Yüksel, M.; Altunal, V.; Özdemir, A.; Güçkan, V.; Günay, I.

    2015-01-01

    Highlights: • We reported on dosimetric characterisation of natural amethyst quartz specimens from Turkey, using TL technique. • The thermoluminescence characterisation tests were performed under the beta radiation exposure. • The IT peaks ∼230 °C show superlinear dose response behavior (g(D) > 1) between 1 Gy and 5 kGy. The HT peaks ∼300 °C show linear behavior (g(D) = 1) at low dose levels (1 < D < 20 Gy) and superlinearity (g(D) > 1) between 20 Gy < D < 2 kGy. • Deviations were determined for recycling measurements for various dose values of 0.1, 0.5, 0.8 and 1 kGy. • Amethyst quartz has great potential to be investigated for dosimetry purpose. - Abstract: In thermoluminescence (TL) dosimetry, the phosphor amethyst quartz as a thermoluminescent, appears to be one of the materials arousing the highest interest. In this study the dosimetric characteristics of natural amethyst quartz crystals collected from Balikesir–Dursunbey (Turkey) were investigated for the purpose of determination of the general properties that phosphors should have in order to be useful for thermoluminescence dosimetry. The natural thermoluminescence was drained by annealing the powder samples at 450 °C for 1.5 h. The effects of high temperature annealing, dose response curves, glow curves after a postirradiation annealing, reusability of the samples and storage of trapped electrons in dark at room temperature were clarified through irradiating the samples with the desired exposures by 90 Sr/ 90 Y beta particles. Isothermal annealing before and after irradiation was found to have a definite effect upon the TL glow curve of amethyst crystal powder. The same sample varied in sensitivity depending upon its previous thermal and radiation history. The peak heights of the glow peaks were examined with respect to dose response at dose levels between 1 Gy and 5 kGy. The intermediate temperature (IT) and high temperature (HT) peaks of 230 °C and 300 °C, respectively, exhibit dose

  13. Study of thermoluminescence response of purple to violet amethyst quartz from Balikesir, Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Nur, N., E-mail: nnur@adiyaman.edu.tr [Adiyaman University, Engineering Faculty, Department of Electrical and Electronic Engineering, 02040 Adiyaman (Turkey); Yeğingil, Z.; Topaksu, M. [Cukurova University, Art and Sciences Faculty, Physics Department, 01330 Adana (Turkey); Kurt, K. [University of Mersin, Science and Art Faculty, Physics Department, 33343 Mersin (Turkey); Doğan, T. [Cukurova University, Vocational School of Imamoglu, Department of Technical Programs, 01700 Adana (Turkey); Sarıgül, N. [Institute of Nuclear Science, Hacettepe University, 06532 Ankara (Turkey); Yüksel, M.; Altunal, V.; Özdemir, A.; Güçkan, V. [Cukurova University, Art and Sciences Faculty, Physics Department, 01330 Adana (Turkey); Günay, I. [Cukurova University, Medicine Faculty, Biophysics Department, Adana (Turkey)

    2015-09-01

    Highlights: • We reported on dosimetric characterisation of natural amethyst quartz specimens from Turkey, using TL technique. • The thermoluminescence characterisation tests were performed under the beta radiation exposure. • The IT peaks ∼230 °C show superlinear dose response behavior (g(D) > 1) between 1 Gy and 5 kGy. The HT peaks ∼300 °C show linear behavior (g(D) = 1) at low dose levels (1 < D < 20 Gy) and superlinearity (g(D) > 1) between 20 Gy < D < 2 kGy. • Deviations were determined for recycling measurements for various dose values of 0.1, 0.5, 0.8 and 1 kGy. • Amethyst quartz has great potential to be investigated for dosimetry purpose. - Abstract: In thermoluminescence (TL) dosimetry, the phosphor amethyst quartz as a thermoluminescent, appears to be one of the materials arousing the highest interest. In this study the dosimetric characteristics of natural amethyst quartz crystals collected from Balikesir–Dursunbey (Turkey) were investigated for the purpose of determination of the general properties that phosphors should have in order to be useful for thermoluminescence dosimetry. The natural thermoluminescence was drained by annealing the powder samples at 450 °C for 1.5 h. The effects of high temperature annealing, dose response curves, glow curves after a postirradiation annealing, reusability of the samples and storage of trapped electrons in dark at room temperature were clarified through irradiating the samples with the desired exposures by {sup 90}Sr/{sup 90}Y beta particles. Isothermal annealing before and after irradiation was found to have a definite effect upon the TL glow curve of amethyst crystal powder. The same sample varied in sensitivity depending upon its previous thermal and radiation history. The peak heights of the glow peaks were examined with respect to dose response at dose levels between 1 Gy and 5 kGy. The intermediate temperature (IT) and high temperature (HT) peaks of 230 °C and 300 °C, respectively

  14. Effective removal of trace thallium from surface water by nanosized manganese dioxide enhanced quartz sand filtration.

    Science.gov (United States)

    Huangfu, Xiaoliu; Ma, Chengxue; Ma, Jun; He, Qiang; Yang, Chun; Zhou, Jian; Jiang, Jin; Wang, Yaan

    2017-12-01

    Thallium (Tl) has drawn wide concern due to its high toxicity even at extremely low concentrations, as well as its tendency for significant accumulation in the human body and other organisms. The need to develop effective strategies for trace Tl removal from drinking water is urgent. In this study, the removal of trace Tl (0.5 μg L -1 ) by conventional quartz sand filtration enhanced by nanosized manganese dioxide (nMnO 2 ) has been investigated using typical surface water obtained from northeast China. The results indicate that nMnO 2 enhanced quartz sand filtration could remove trace Tl(I) and Tl(III) efficiently through the adsorption of Tl onto nMnO 2 added to a water matrix and onto nMnO 2 attached on quartz sand surfaces. Tl(III)-HA complexes might be responsible for higher residual Tl(III) in the effluent compared to residual Tl(I). Competitive Ca 2+ cations inhibit Tl removal to a certain extent because the Ca 2+ ions will occupy the Tl adsorption site on nMnO 2 . Moreover, high concentrations of HA (10 mgTOC L -1 ), which notably complexes with and dissolves nMnO 2 (more than 78%), resulted in higher residual Tl(I) and Tl(III). Tl(III)-HA complexes might also enhance Tl(III) penetration to a certain extent. Additionally, a higher pH level could enhance the removal of trace Tl from surface water. Finally, a slight increase of residual Tl was observed after backwash, followed by the reduction of the Tl concentration in the effluent to a "steady" state again. The knowledge obtained here may provide a potential strategy for drinking water treatment plants threatened by trace Tl. Copyright © 2017. Published by Elsevier Ltd.

  15. Doped Tl-1212 and Tl-1223 superconductors

    International Nuclear Information System (INIS)

    Eder, M.H.

    2001-09-01

    This work describes the preparation and characterization of thallium-lead-strontium-barium-calcium-(uranium)-copperoxide (Tl-1212, Tl-1223) high-temperature superconductors. The precursors were prepared via nitrate method. After calcination the oxidic powders were mixed with stoichiometric amounts of an Tl 2 O 3 , PbO, Er 2 O 3 and Gd 2 O 3 by milling and afterwards uniaxial compressed. Sintering was carried out in silver foils. X-ray diffractometry and high-resolution microscopy in combination with scanning electron microscopy (including EDAX) were used to study the influence of varying thallium/lead-, strontium/barium-, calcium/rare earth element ratios and the effect of uranium on the phase composition and microstructure of bulk superconductors. Furthermore the influence of the composition on the electrical and magnetical properties was studied. On phase pure Tl-1212 and Tl-1223 superconductors NMR-measurements were done. Small amounts of gadolinium and erbium instead of calcium and excess-uranium have a positive impact on the electrical and magnetical properties of the Tl-1223 superconductors. Higher amounts of these doping elements favor the Tl-1212 phase. Tl-1212 superconductors with varying thallium/lead- strontium/barium- and calcium/gadolinium ratios were prepared phasepure in wide range of doping. Transition temperatures up to 96 K were achieved. It was shown that lead has an oxidation number of +4 and thallium of +3. (author)

  16. Aspects of pre-dose and other luminescence phenomena in quartz absorbed dose estimation

    International Nuclear Information System (INIS)

    Adamiec, G.

    2000-01-01

    The understanding of all luminescence processes occurring in quartz is of paramount importance in the further development of robust absorbed dose estimation techniques (for the purpose of dating and retrospective dosimetry). The findings presented in this thesis, aid future improvements of absorbed dose estimation techniques using quartz by presenting investigations in the following areas: 1) interpretation of measurement results, 2) numerical modelling of luminescence in quartz, 3) phenomena needing inclusion in future physical models of luminescence. In the first part, the variability of properties of single quartz grains is examined. Through empirical and theoretical considerations, investigations are made of various problems of measurements of luminescence using multi-grain aliquots, and specifically areas where the heterogeneity of the sample at the inter-grain level may be misinterpreted at the multi-grain-aliquot level. The results obtained suggest that the heterogeneity of samples is often overlooked, and that such differences can have a profound influence on the interpretation of measurement results. Discussed are the shape of TL glow curves, OSL decay curves, dose response curves (including consequences for using certain signals as proxies for others), normalisation procedures and D E estimation techniques. Further, a numerical model of luminescence is proposed, which includes multiple R-centres and is used to describe the pre-dose sensitisation in quartz. The numerical model exhibits a broad-scale behaviour observed experimentally in a sample of annealed quartz. The shapes of TAC for lower (20 Gy) and higher doses (1 kGy) and the evolution with temperature of the isothermal sensitisation curves are qualitatively matched for the empirical and numerical systems. In the third area, a preliminary investigation of the properties of the '110 deg. C peak' in the 550 nm emission band, in annealed quartz is presented. These properties are in sharp contrast with

  17. Three-dimensional thermoluminescence spectra of different origin quartz from Altay Orogenic belt, Xinjiang, China

    International Nuclear Information System (INIS)

    Tan Kaixuan; Liu Zehua; Zeng Sheng; Liu Yan; Xie Yanshi; Rieser, Uwe

    2009-01-01

    Three-dimensional thermoluminescence spectra are measured for different types of geological origin quartz from the Altay orogenic belt, northern Xinjiang, China. The results show striking differences which appear to be characteristic of their geological origin. Granitic quartz is dominated by emission bands at 420-430 nm, 550-560 nm, at a temperature of 170 deg. C. Pegmatite quartz is characterized by an intense 480 nm emission band at 170 deg. C. Volcanic quartz has exclusive UV (340-360 nm) and violet (410-430 nm) emission bands. Hydrothermal quartz exhibits very different TL spectral characteristics because of different hydrothermal activity and mineralization. Only one TL peaks at 485 nm/170 deg. C was observed in sedimentary quartz. An intense 730 nm emission band observed at 170 deg. C considered generally to be characteristics of feldspar was observed in quartz from granite and hydrothermal Au-bearing quartz. This TL peak is probably related to the centre of [FeO 4 ] 0 on an Si site. All samples show an intense 990-1000 nm emission band at 330 deg. C. Identical types of quartz formed in different regions or different geological and tectonic settings can also exhibit striking differences in TL spectra.

  18. Equivalent thermal history (H{sub E}) of ferruginous sandstones based on the thermal activation characteristics of quartz

    Energy Technology Data Exchange (ETDEWEB)

    Lahaye, Christelle [Centre de Recherche en Physique Appliquee a l' Archeologie (CRPAA), IRAMAT Institut de Recherche sur les Archeomateriaux, UMR 5060 CNRS - Universite de Bordeaux 3, Maison de l' Archeologie, 33607 Pessac Cedex (France) and Laboratorio di Datazione tramite Luminescenza e di Metodologie Fisiche per i Beni Culturali, Dipartimento di Fisica ed Astronomia dell' Universita di Catania, Via Santa Sofia, 645123 Catania (Italy)]. E-mail: christelle.lahaye@ct.infn.it; Godfrey-Smith, Dorothy I. [Department of Earth Sciences, Dalhousie University, Halifax, NS, B3H 4J1 (Canada); Radiological Analysis and Defence, Defence Research and Development Canada, 3701 Carling Ave., Ottawa, ON, K1A 0Z4 (Canada); Guibert, Pierre [Centre de Recherche en Physique Appliquee a l' Archeologie (CRPAA), IRAMAT Institut de Recherche sur les Archeomateriaux, UMR 5060 CNRS - Universite de Bordeaux 3, Maison de l' Archeologie, 33607 Pessac Cedex (France); Bechtel, Francoise [Centre de Recherche en Physique Appliquee a l' Archeologie (CRPAA), IRAMAT Institut de Recherche sur les Archeomateriaux, UMR 5060 CNRS - Universite de Bordeaux 3, Maison de l' Archeologie, 33607 Pessac Cedex (France)

    2006-08-15

    The thermal history of four quartz-rich ochre samples from an Upper Palaeolithic site was studied. This work is based on the changes in thermal activation characteristics (TAC) of the 110 deg. C TL peak of the quartz inclusions. An isothermal study of a previously unheated sample has highlighted the importance of the duration of annealing on the sensitization of quartz. In fact, the sensitivity change as a function of the duration of annealing is not monotonic. For that reason it seems necessary to consider the 'equivalent thermal history' H{sub E} rather than an 'equivalent temperature'. Isochronal annealing experiments demonstrate that the initial rise of sensitization overestimates the true H{sub E} by about 100 deg. C. Using a geological sample we have thus developed an empirical approach which allows the true H{sub E} of artifacts to be determined. Reheating of ochre originally heated in antiquity results in desensitization of the TAC.

  19. TL response of citrine samples for high-dose dosimetry

    International Nuclear Information System (INIS)

    Teixeira, Maria Ines; Caldas, Linda V.E.

    2011-01-01

    The possibility of using samples of Brazilian stones as quartz, amethyst, topaz, etc. for high-dose dosimetry has been studied in recent years at IPEN, using the thermoluminescence technique (TL). In this work, the TL properties of citrine samples were studied. They were exposed to different doses of gamma radiation ( 60 Co). The natural citrine stone was extracted from a mine in Minas Gerais state, Brazil; it is a tectosilicate ranked as one of three-dimensional structure, showing clear yellow to golden brown color. The natural citrine stone is classified as quartz (SiO 2 ), and it has a lower symmetry and more compact reticulum. The citrine stone samples were powdered, and the selected grains were mixed with Teflon in the proportion 2 (Teflon):1 (Citrine). The mixture was pressed and sintered for production of Citrine -Teflon pellets of 50 mg. The TL emission curve showed two peaks at 160 deg C and 220 deg C. To remove the TL peak (160 deg C) of the sintered citrine pellet glow curves, different thermal treatments were tested during several time intervals. The TL dose-response curve between 50 Gy and 100 kGy, the reproducibility of TL response and the lower detection dose were obtained. The preliminary results show that citrine may be useful for high-dose dosimetry. (author)

  20. Kinetic parameters and TL mechanism in cadmium tetra borate phosphor

    International Nuclear Information System (INIS)

    Annalakshmi, O.; Jose, M.T.; Sridevi, J.; Venkatraman, B.; Amarendra, G.; Mandal, A.B.

    2014-01-01

    Polycrystalline powder samples of cadmium tetra borate were synthesized by a simple solid state sintering technique and gamma irradiated sample showed a simple Thermoluminescence (TL) glow peak around 460 K. The TL kinetic parameters of gamma irradiated phosphor were determined by initial rise (IR), isothermal decay (ID), peak shape (PS), variable heating rate (VHR) and glow curve de-convolution method. The kinetic parameters such as activation energy (E), frequency factor (s) and order of kinetics (b) were calculated by IR, ID, PS and VHR methods are in the order of ∼1.05 eV, 10 9 –10 12 s −1 and 1.58, respectively. From the results of TL and PL emission studies carried out on the phosphor revealed that the defect centers related to TL is different from that for PL. EPR measurements were carried out to identify the defect centers formed in cadmium tetra borate phosphor on gamma irradiation. Based on EPR studies the mechanism for TL process in cadmium tetra borate is proposed in this paper -- Highlights: • Polycrystalline powder samples of undoped cadmium tetra borate synthesized. • Cadmium tetra borate phosphor exhibits a dosimetric peak at 458 K. • Kinetic parameters of the trap responsible for TL evaluated. • TL mechanism is proposed from TL to EPR correlation studies

  1. Kinetic parameters and TL mechanism in cadmium tetra borate phosphor

    Energy Technology Data Exchange (ETDEWEB)

    Annalakshmi, O. [Radiological Safety Division, Materials Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam-603102 (India); Jose, M.T., E-mail: mtj@igcar.gov.in [Radiological Safety Division, Materials Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam-603102 (India); Sridevi, J. [Central Leather Research Institute, Council of Scientific and Industrial Research, Chennai 600 020, Tamilnadhu (India); Venkatraman, B. [Radiological Safety Division, Materials Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam-603102 (India); Amarendra, G. [Materials Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam-603102 (India); Mandal, A.B. [Central Leather Research Institute, Council of Scientific and Industrial Research, Chennai 600 020, Tamilnadhu (India)

    2014-03-15

    Polycrystalline powder samples of cadmium tetra borate were synthesized by a simple solid state sintering technique and gamma irradiated sample showed a simple Thermoluminescence (TL) glow peak around 460 K. The TL kinetic parameters of gamma irradiated phosphor were determined by initial rise (IR), isothermal decay (ID), peak shape (PS), variable heating rate (VHR) and glow curve de-convolution method. The kinetic parameters such as activation energy (E), frequency factor (s) and order of kinetics (b) were calculated by IR, ID, PS and VHR methods are in the order of ∼1.05 eV, 10{sup 9}–10{sup 12} s{sup −1} and 1.58, respectively. From the results of TL and PL emission studies carried out on the phosphor revealed that the defect centers related to TL is different from that for PL. EPR measurements were carried out to identify the defect centers formed in cadmium tetra borate phosphor on gamma irradiation. Based on EPR studies the mechanism for TL process in cadmium tetra borate is proposed in this paper -- Highlights: • Polycrystalline powder samples of undoped cadmium tetra borate synthesized. • Cadmium tetra borate phosphor exhibits a dosimetric peak at 458 K. • Kinetic parameters of the trap responsible for TL evaluated. • TL mechanism is proposed from TL to EPR correlation studies.

  2. TL transgenic mouse strains

    International Nuclear Information System (INIS)

    Obata, Y.; Matsudaira, Y.; Hasegawa, H.; Tamaki, H.; Takahashi, T.; Morita, A.; Kasai, K.

    1993-01-01

    As a result of abnormal development of the thymus of these mice, TCR αβ lineage of the T cell differentiation is disturbed and cells belonging to the TCR γδ CD4 - CD8 - double negative (DN) lineage become preponderant. The γδ DN cells migrate into peripheral lymphoid organs and constitute nearly 50% of peripheral T cells. Immune function of the transgenic mice is severely impaired, indicating that the γδ cells are incapable of participating in these reactions. Molecular and serological analyses of T-cell lymphomas reveal that they belong to the γδ lineage. Tg.Tla a -3-1 mice should be useful in defining the role of TL in normal and abnormal T cell differentiation as well as in the development of T-cell lymphomas, and further they should facilitate studies on the differentiation and function of γδ T cells. We isolated T3 b -TL gene from B6 mice and constructed a chimeric gene in which T3 b -TL is driven by the promoter of H-2K b . With the chimeric gene, two transgenic mouse strains, Tg. Con.3-1 and -2 have been derived in C3H background. Both strains express TL antigen in various tissues including skin. The skin graft of transgenic mice on C3H and (B6 X C3H)F 1 mice were rejected. In the mice which rejected the grafts, CD8 + TCRαβ cytotoxic T cells (CTL) against TL antigens were recognized. The recognition of TL by CTL did not require the antigen presentation by H-2 molecules. The results indicated that TL antigen in the skin becomes a transplantation antigen and behaves like a typical allogeneic MHC class I antigen. The facts that (B6 X C3H)F 1 mice rejected the skin expressing T3 b -TL antigen and induced CTL that killed TL + lymphomas of B6 origin revealed that TL antigen encoded by T3 b -TL is recognized as non-self in B6 mice. Experiments are now extended to analyze immune responses to TL antigen expressed on autochthonous T cell lymphomas. (J.P.N.)

  3. Luminescence quartz dating of lime mortars. A first research approach

    International Nuclear Information System (INIS)

    Zacharias, N.; Mauz, B.; Michael, C.T.

    2002-01-01

    Lime mortars mixed with sand are well suited for connecting structural materials, like stones and bricks, due to the mechanical properties this material exhibits. Their extensive use in architectural and decorative works during the last 4000 years motivated the introduction of the 'Luminescence clock' for age determination of mortars. The same principles as for quartz optically stimulated luminescence (OSL) dating of sediments were applied for age estimation of a mortar fragment removed from a Byzantine church monument dated by archaeological means to 1050-1100 years ago (the first half of the 10th century). The OSL from the quartz was monitored under blue light stimulation and UV detection, using a single-aliquot-regenerative-dose protocol. The quartz-OSL dating of the mortar resulted in 870±230 a. TL polymineral fine grain dating was also performed on a brick fragment which was connected to the mortar, resulting in a TL age of 1095±190 a. (author)

  4. Theoretical modelling of experimental diagnostic procedures employed during pre-dose dosimetry of quartz

    International Nuclear Information System (INIS)

    Pagonis, V.; Chen, R.; Kitis, G.

    2006-01-01

    The pre-dose technique in thermoluminescence (TL) is used for dating archaeological ceramics and for accident dosimetry. During routine applications of this technique, the sensitisation of the quartz samples is measured as a function of the annealing temperature, yielding the so-called thermal activation characteristic (TAC). The measurement of multiple TACs and the study of the effect of UV-radiation on the TL sensitivity of quartz are important analytical and diagnostic tools. In this paper, it is shown that a modified Zimmerman model for quartz can successfully model the experimental steps undertaken during a measurement of multiple TACs. (authors)

  5. Optically stimulated luminescence characteristics of natural and doped quartz and alkali feldspars

    Energy Technology Data Exchange (ETDEWEB)

    Huett, G.; Jaek, I.; Brodski, L. [Institute of Geology at Tallinn Technical University, Tallinn (Estonia); Vasilchenko, V. [Institute of Experimental Physics and Technology of Tartu University, Tartu (Estonia)

    1999-05-01

    Natural alkali feldspars and quartz were doped by Tl and Cu by thermodiffusion and electrodiffusion technology. As a result of doping, intensive UV emission bands were created. The OSL stimulation spectra of irradiated natural and doped quartz and alkali feldspars were measured in the span of 400-1300 nm using UV emission of Tl at 280 nm and of Cu at 380 nm. One-trap centre conception was confirmed for high-temperature palaeodosimetrical TL peaks and OSL stimulation spectrum bands: for alkali feldspars at 880 and 420 nm and visible region of the spectrum for quartz. A thermooptical mechanism of the optical depopulation of the corresponding trap is confirmed in alkali feldspars, but there is no evidence for processes of this kind in quartz. An analogy between the physical background of OSL properties of both minerals is discussed.

  6. Optically stimulated luminescence characteristics of natural and doped quartz and alkali feldspars

    International Nuclear Information System (INIS)

    Huett, G.; Jaek, I.; Brodski, L.; Vasilchenko, V.

    1999-01-01

    Natural alkali feldspars and quartz were doped by Tl and Cu by thermodiffusion and electrodiffusion technology. As a result of doping, intensive UV emission bands were created. The OSL stimulation spectra of irradiated natural and doped quartz and alkali feldspars were measured in the span of 400-1300 nm using UV emission of Tl at 280 nm and of Cu at 380 nm. One-trap centre conception was confirmed for high-temperature palaeodosimetrical TL peaks and OSL stimulation spectrum bands: for alkali feldspars at 880 and 420 nm and visible region of the spectrum for quartz. A thermooptical mechanism of the optical depopulation of the corresponding trap is confirmed in alkali feldspars, but there is no evidence for processes of this kind in quartz. An analogy between the physical background of OSL properties of both minerals is discussed

  7. Thermal and x-ray studies on Tl2U(MoO4)3 and Tl4U(MoO4)4

    International Nuclear Information System (INIS)

    Dahale, N.D.; Keskar, Meera; Kulkarni, N.K.; Singh Mudher, K.D.

    2006-01-01

    In the quaternary Tl-U(IV)-Mo-O system, two new compounds namely Tl 2 U(MoO 4 ) 3 and Tl 4 U(MoO 4 ) 4 were prepared and characterized by powder X-ray diffraction and thermal methods. These compounds were prepared by solid state reactions of Tl 2 MoO 4 , UMoO 5 and MoO 3 in the required stoichiometric ratio at 500 deg C in evacuated sealed quartz ampoule. The XRD data of Tl 2 U(MoO 4 ) 3 and Tl 4 U(MoO 4 ) 4 were indexed on orthorhombic cell. TG curves of Tl 2 U(MoO 4 ) 3 and Tl 4 U(MoO 4 ) 4 did not show any weight change up to 700 deg C in an inert atmosphere. During heating in an inert atmosphere, Tl 2 U(MoO 4 ) 3 and Tl 4 U(MoO 4 ) 4 showed endothermic Dta peaks due to melting of the compounds at 519 and 565 deg C, respectively. (author)

  8. Reconstruction of thermally quenched glow curves in quartz

    International Nuclear Information System (INIS)

    Subedi, Bhagawan; Polymeris, George S.; Tsirliganis, Nestor C.; Pagonis, Vasilis; Kitis, George

    2012-01-01

    The experimentally measured thermoluminescence (TL) glow curves of quartz samples are influenced by the presence of the thermal quenching effect, which involves a variation of the luminescence efficiency as a function of temperature. The real shape of the thermally unquenched TL glow curves is completely unknown. In the present work an attempt is made to reconstruct these unquenched glow curves from the quenched experimental data, and for two different types of quartz samples. The reconstruction is based on the values of the thermal quenching parameter W (activation energy) and C (a dimensionless constant), which are known from recent experimental work on these two samples. A computerized glow-curve deconvolution (CGCD) analysis was performed twice for both the reconstructed and the experimental TL glow curves. Special attention was paid to check for consistency between the results of these two independent CGCD analyses. The investigation showed that the reconstruction attempt was successful, and it is concluded that the analysis of reconstructed TL glow curves can provide improved values of the kinetic parameters E, s for the glow peaks of quartz. This also leads to a better evaluation of the half-lives of electron trapping levels used for dosimetry and luminescence dating.

  9. Measurement of temperature fields in specimens of quartz ceramic during surface ablation

    Science.gov (United States)

    Frolov, G. A.; Pasichnyi, V. V.; Suzdal'Tsev, E. I.; Tsyganenko, V. S.

    1989-08-01

    The authors propose a method of mounting thermocouples and have obtained temperature fields within specimens of pure and doped quartz ceramic. The linearity of the dependenceΔ * = fleft( {sqrt tau } right) for deep isotherms has been proved experimentally.

  10. Red and blue colouration of thermoluminescence from natural quartz sands

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T; Hayashi, Y; Koyanagi, A; Yokosaka, K; Kimura, K

    1986-01-01

    Quartz extracts, from a pegmatite rock, volcanic ashes and beach sands, were exposed to X-rays or gamma-rays upto 8.8kGy. The irradiated sands were observed through a thermoluminescence colour image technique (abbreviated to TLCI by the authors) using highly sensitive colour photographic system. The quartz sands from volcanic ash layers, containing ..beta..-quartz (mineralized at high temperature), always indicate a red TLCI, whereas the quartz rocks from pegmatite origin and granite strata, containing ..cap alpha..-quartz (mineralized at low temperature), gave a typical blue TLCI, being consistent with the well known quartz TL colour. Quartz fractions from the beach sands showed a mixture of both red and blue TLCI, probably reflecting the respective mixtures of ..beta..-(in their origin) and ..cap alpha..-quartz fractions along the riverside area. The search using X-ray diffractometry and instrumental neutron activation analysis proved that the cause of distinctly different colourations was attributable to the impurity atoms: light rare earth elements (Eu and/or Sm) bringing on red TLCI, while structural defects yielding the blue TLCI).

  11. Quartz fiber calorimeter

    International Nuclear Information System (INIS)

    Akchurin, N.; Doulas, S.; Ganel, O.; Gershtein, Y.; Gavrilov, V.; Kolosov, V.; Kuleshov, S.; Litvinsev, D.; Merlo, J.-P.; Onel, Y.; Osborne, D.; Rosowsky, A.; Stolin, V.; Sulak, L.; Sullivan, J.; Ulyanov, A.; Wigmans, R.; Winn, D.

    1996-01-01

    A calorimeter with optical quartz fibers embedded into an absorber matrix was proposed for the small angle region of the CMS detector at LHC (CERN). This type of calorimeter is expected to be radiation hard and to produce extremely fast signal. Some results from beam tests of the quartz fiber calorimeter prototype are presented. (orig.)

  12. Phase diagrams of novel Tl{sub 4}SnSe{sub 4}–TlSbSe{sub 2}–Tl{sub 2}SnSe{sub 3} quasi-ternary system following DTA and X-ray diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Barchiy, I.E.; Tatzkar, A.R. [Department of Chemistry, Uzhgorod National University, Pidgirna St., 46, Uzhgorod 88000 (Ukraine); Fedorchuk, A.O. [Department of Inorganic and Organic Chemistry, Lviv National University of Veterinary Medicine and Biotechnologies, Pekarska St., 50, Lviv 79010 (Ukraine); Plucinski, K., E-mail: kpluc2006@wp.pl [Electronics Department, Military University Technology, Warsaw, Kaliskiego 2, Warsaw 00-908 (Poland)

    2016-06-25

    Phase relation in the Tl{sub 4}SnSe{sub 4}–TlSbSe{sub 2}–Tl{sub 2}SnSe{sub 3} quasiternary system were studied by the DTA and X-ray diffraction in combination with mathematical modeling. The phase diagrams of the Tl{sub 4}SnSe{sub 4}–TlSbSe{sub 2} and Tl{sub 2}SnSe{sub 3}–TlSbSe{sub 2} systems, the perspective views of the phase interaction in the ternary system, the liquidus surface projection, the isothermal section at 423 K were built for the first time. The Tl{sub 4}SnSe{sub 4}–TlSbSe{sub 2}–Tl{sub 2}SnSe{sub 3} system is of the invariant eutectic type and is characterized by the formation of limited solid solutions following initial ternary compounds. New complex compounds are not formed. - Highlights: • Two Tl{sub 4}SnSe{sub 4}–TlSbSe{sub 2},Tl{sub 2}SnSe{sub 3}–TlSbSe{sub 2} systems were explored. • Invariant processes in the ternary system were determined. • New complex compounds were not observed in ternary system.

  13. Luminescence sensitivity changes in quartz as a result of annealing

    DEFF Research Database (Denmark)

    Bøtter-Jensen, L.; Agersnap Larsen, N.; Mejdahl, V.

    1995-01-01

    archaeological samples show very different OSL sensitivities. In this paper we report on studies of the effect of high temperature annealing on the OSL and phototransferred TL (PTTL) signals from sedimentary and synthetic quartz. A dramatic enhancement of both OSL and PTTL sensitivity was found especially...... in the temperature range 500-800 degrees C. Computer simulations of the possible effects are shown to produce data that agree in all essential details with the experimental observations. It is further demonstrated that the enhanced OSL sensitivity as a function of annealing temperature is not a pre-dose effect....... of magnitude less per unit radiation than that for heated material. The reason these temperature-induced sensitivity changes occur in quartz is presently not well understood. This phenomenon is also seen in the related area of luminescence dating in which sedimentary quartz and quartz from heated...

  14. Dose response on the 110 °C thermoluminescence peak of un-heated, synthetic Merck quartz

    Energy Technology Data Exchange (ETDEWEB)

    Kaya Keleş, Şule, E-mail: sule.kaya@ankara.edu.tr; Meriç, Niyazi; Polymeris, George S.

    2016-07-15

    Studies on 110 °C TL peak have been carried out using natural quartz from different origins and synthetic quartz produced by different suppliers. The interest in quartz is due to its usage in dating and retrospective dosimetry as a main material; both synthetic and natural types of quartz yield the 110 °C TL peak in their glow curve. In most studies to understand the physical mechanism behind the TL system, synthetic quartz samples are used and there are many investigations about dose response, in both low and high radiation dose region. In these studies generally synthetic quartz samples produced by Sawyer Research Products are used and the studies showed that both heated and un-heated synthetic quartz samples have intense supra-linear responses. Supra-linearity was enhanced by applying a pre-irradiation while several models have been developed towards an explanation to these supra-linearity effects. In this study commercially available synthetic Merck quartz was used. Different combinations of optical filters were used to obtain dose response curves upto 266 Gy and the effect of pre-dose to these dose response curves was studied. Un-pre-dosed Merck quartz samples dose supra-linearity index is below 1 independently on the optical filters; so Merck quartz showed linear or sub-linear dose response.

  15. The neutron diffraction of molten TlCl, TlBr, and TlI

    International Nuclear Information System (INIS)

    Satow, T.; Uemura, O.; Hoshino, K.; Watanabe, T.

    1984-01-01

    Structure factors S(K) for liquid TlCl, TlBr, and TlI are determined by neutron diffraction measurements. Atomic radial distribution functions (RDF) derived from S(K) are presented. All RDF values are slightly smaller than those of their solid state counter parts. Results show that TlX has a tendency not to retain cesium-chloride type local order, but to take sodium-chloride type order when melting

  16. 205Tl experiment

    International Nuclear Information System (INIS)

    Henning, W.; Kutschera, W.; Ernst, H.

    1984-01-01

    205 Tl has been previously proposed as a geological detector for solar neutrinos, making use of the reaction 205 Tl(nu, e - ) 205 Pb with a neutrino threshold of only approx. = 43 keV. We report on an experiment performed to study the feasibility of detecting radioactive 205 Pb nuclei (T/sub 1/2/ = 15 million years) at very low concentrations using the recently developed technique of accelerator mass spectrometry. Employing the high-energy ion beams of good quality from the UNILAC heavy-ion accelerator at the GSI Darmstadt, we are able to demonstrate a suppression of neighbouring isotopes to better than 1 in 10 16 and of neighbouring elements to about 1 in 10 3 . While these results are very encouraging, the minimum number of atoms detectable is still severely limited by the efficiency of producing multiply-charged ions from present ion sources. Future improvements in ion-source performance are briefly discussed

  17. Comparative study of the thermoluminescence properties of natural metamorphic quartz belonging to Turkey and Spain

    International Nuclear Information System (INIS)

    Topaksu, M.; Dogan, T.; Yüksel, M.; Kurt, K.; Topak, Y.; Yegingil, Z.

    2014-01-01

    The aim of this study is to investigate the sensitization of the thermoluminescence (TL) peak of metamorphic quartzes from Adiyaman in Turkey (TMQ) and from Madrid in Spain (SMQ). Quartz samples of two different origins were β-irradiated between ∼6.689 Gy and 4816 Gy at room temperature. X-ray diffraction analysis has indicated that both TMQ and SMQ have the same crystal structure. Chemical analyses of both TMQ and SMQ were performed using the XRF technique. The preheat processes were carried out at 125 °C for 10 s in the TL measurement. TMQ and SMQ samples have different TL properties in two ways. First TMQ has four first order TL glow peaks while SMQ has five first order TL peaks and secondly, the observed dose sensitivity of TMQ samples is higher than the SMQ samples. - Highlights: • The thermoluminescence (TL) peak of metamorphic quartzes was investigated. • Comparable differences were seen between low and high dose levels. • AD and CGCD methods were used

  18. Evaluation of trapping parameters of annealed natural quartz

    International Nuclear Information System (INIS)

    Zhou, Rui; Wei, Ming-Jian; Song, Bo; Zhang, Yan; Zhao, Qiu-Yue; Pan, Bao-Lin; Li, Teng-Fei

    2016-01-01

    The thermoluminescence (TL) trapping parameters of annealed quartz have been investigated. The apparent TL peaks observed at temperatures of 133 °C, 211 °C, 266 °C and 405 °C, respectively, were named Peak I, Peak II, Peak III and Peak IV. The T_m − T_s_t_o_p method is applied to investigate the number of peaks and their positions, and to obtain the trap distributions in the quartz. Peak shape (PS), Hoogenstraaten method (Various Heating Rates Method, VHR), and Computerized Glow Curve Deconvolution (CGCD) are used to evaluate the trapping parameters of the annealed quartz. The glow curve can be considered as a superposition of at least nine overlapping peaks. These peaks show up at 133 °C, 211 °C, 266 °C, 308 °C, 333 °C, 384 °C, 441 °C, 466 °C and 484 °C. The PS method can be only used in evaluating the parameters for Peaks I. The VHR method can be used in evaluating the trapping parameters for the first three peaks. CGCD method is complementary to obtaining parameters for the sub-peaks, and the thermal quenching correction with the Urbach’s method is necessary. The Urbach’s coefficient for the quartz is 30.03 kT_m.

  19. Evaluation of trapping parameters of annealed natural quartz

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Rui [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); Shisanling Seismic Station, Institute of Earthquake Science, CEA, 102200 Beijing (China); Wei, Ming-Jian, E-mail: weimj@cnu.edu.cn [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); Song, Bo [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); Beijing Jing Yuan School, 100040 Beijing (China); Zhang, Yan [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China); School of TaiPingqiao, Nan Lu of West Railway Station, 100073 Beijing (China); Zhao, Qiu-Yue [Key Laboratory of Tourism and Resources Environment in Universities of Shandong, Taishan University, 271000 Tai’an (China); Pan, Bao-Lin; Li, Teng-Fei [College of Resources, Environment & Tourism, Capital Normal University, 100048 Beijing (China)

    2016-05-15

    The thermoluminescence (TL) trapping parameters of annealed quartz have been investigated. The apparent TL peaks observed at temperatures of 133 °C, 211 °C, 266 °C and 405 °C, respectively, were named Peak I, Peak II, Peak III and Peak IV. The T{sub m} − T{sub stop} method is applied to investigate the number of peaks and their positions, and to obtain the trap distributions in the quartz. Peak shape (PS), Hoogenstraaten method (Various Heating Rates Method, VHR), and Computerized Glow Curve Deconvolution (CGCD) are used to evaluate the trapping parameters of the annealed quartz. The glow curve can be considered as a superposition of at least nine overlapping peaks. These peaks show up at 133 °C, 211 °C, 266 °C, 308 °C, 333 °C, 384 °C, 441 °C, 466 °C and 484 °C. The PS method can be only used in evaluating the parameters for Peaks I. The VHR method can be used in evaluating the trapping parameters for the first three peaks. CGCD method is complementary to obtaining parameters for the sub-peaks, and the thermal quenching correction with the Urbach’s method is necessary. The Urbach’s coefficient for the quartz is 30.03 kT{sub m}.

  20. Firing temperature of pottery using TL and OSL techniques

    International Nuclear Information System (INIS)

    Polymeris, G.S.; Sakalis, A.; Papadopoulou, D.; Dallas, G.; Kitis, G.; Tsirliganis, N.C.

    2007-01-01

    Several methods of thermal analysis are used to determine in the laboratory the firing temperature of ancient ceramic sherds. These methods are based primarily on changes of physical characteristics occurring when clay minerals are heated. The luminescence properties of quartz grains in a ceramic matrix also undergo certain changes during firing. The possibility of measuring the sensitivity change (sensitization) of quartz in order to determine the firing temperature of archeological ceramic artifacts was investigated. The sensitivity change was studied for both the thermoluminescence (TL) and the optically stimulated luminescence (OSL) signal for a ceramic sample of known firing temperature. Various segments of the sample were annealed to a different temperature. Subsequently, the initial sensitivity, as well as the thermal and the pre-dose sensitization were measured for both TL and OSL at room temperature as a function of the annealing temperature. The obtained TL glow curves showed different shapes for annealing temperatures above the firing temperature. Thermal and pre-dose sensitizations also exhibited a similar, although less prominent, rise. The OSL signal was analyzed by integrating the raw signal over the initial second of stimulation. The initial sensitivity showed an abrupt change for annealing temperatures around the firing temperature. An alternative approach used for the analysis of the OSL signal involved a full-component resolved sensitization study. The same abrupt change for the initial sensitivity of both the first and second components was observed, as well as, a clear but not very prominent thermal sensitization trend for annealing temperatures above the firing temperature

  1. The origin of the medium OSL component in West Australian quartz

    International Nuclear Information System (INIS)

    Wang, X.L.; Du, J.H.; Adamiec, G.; Wintle, A.G.

    2015-01-01

    Optically stimulated luminescence (OSL) of a coarse-grained sedimentary quartz from West Australia was investigated. Observations of OSL and TL (thermoluminescence) were made following a series of experiments using different heating and optical bleaching conditions, and with optical stimulation at several different temperatures. Analysis of the fast and medium OSL components suggests that the medium OSL component observed after heating at 260 °C is a by-product of the production of the fast component, and both of them have as their original source the 325 °C TL trap. During fast OSL production following irradiation and preheating, some of the electrons evicted into the conduction band are re-trapped in an intermediate trap corresponding to the 170 °C TL peak; from here they are instantaneously stimulated to give rise to the medium OSL signal when the blue light stimulation is switched on, and subsequently result in the residual recuperated TL after the blue light is switched off. The kinetic properties of the medium OSL component are determined by the properties of both the 170 °C and 325 °C TL traps in contrast to the conventional interpretation of the medium component being derived from an independent source trap. Therefore, the 170 °C TL trap also plays unexpected roles in quartz OSL production with elevated stimulation temperatures (e.g. 125 °C or 130 °C, currently used for OSL dating), while the 110 °C TL trap and its influences are being avoided. - Highlights: • Quartz medium OSL component is a by-product of fast OSL component production. • Medium component is mediated by the 170 C TL peak. • Phototransfer is responsible for the medium OSL

  2. Characterisation of blue-light stimulated luminescence components in different quartz samples: Implications for dose measurement

    DEFF Research Database (Denmark)

    Jain, M.; Murray, A.S.; Bøtter-Jensen, L.

    2003-01-01

    -aliquot dose-evaluation protocols seem to be relatively free of complications when applied to quartz dominated by the fast OSL component coming from 325degreesC TL region, but this may not be true for quartz in which other components are more significant. An adequate understanding of how different OSL...... results from measurement of (a) sensitisation, (b) thermal stability, (c) recuperation, and (d) infrared response as a function of stimulation temperature from 3 different samples of sedimentary quartz selected on the basis of relative OSL contribution from different blue light stimulated linearly...

  3. Spectral measurements of loess TL

    International Nuclear Information System (INIS)

    Rendell, H.M.; Mann, S.J.; Townsend, P.D.

    1988-01-01

    Variations in thermoluminescence (TL) glow curves are reported for two loess samples when examined with broad band filters in the range 275-650 nm. Samples show striking differences in bleaching behaviour, when their TL emissions are observed in the u.v., blue, green and yellow spectral regions. The age estimates, given by the equivalent dose (ED) values, differ by up to a factor of two for analyses using the green and u.v. TL signals. These ED values also vary with prolonged room temperature storage between the bleaching and irradiation steps. The anomalies in the bleaching behaviour are interpreted in terms of changes in TL efficiency. The results have major implications for the regeneration method of TL dating for these fine-grained sediments and suggest that reliable dates obtained by it may be fortuitous. (author)

  4. 201Tl heart studies

    International Nuclear Information System (INIS)

    Bell, R.L.

    1976-01-01

    At the annual meeting of the Society of Nuclear Medicine there was a preponderance of papers dealing with the heart. The most impressive papers detailed the use of monovalent cation 201 Tl in the evaluation of coronary artery disease. Thallium-201 behaves like potassium in that it enters heart muscle quickly and persists in that organ for several hours. It is unlike most radioactive potassium analogues used for heart studies in that: (1) its gamma energy peaks (69 keV and 80 keV) are more easily collimated with resultant image improvement, (2) its physical half life of 72 hours is sufficiently short to attain high counting rates without too much radiation and is sufficiently long so that storage is not prohibitive, (3) its short half life and lack of Beta radiation results in lower radiation to the patient, and (4) its uptake in heart is greater and uptake in liver and stomach less than other potassium analogues

  5. Colorado quartz: occurrence and discovery

    Science.gov (United States)

    Kile, D.E.; Modreski, P.J.; Kile, D.L.

    1991-01-01

    The many varieties and associations of quartz found throughout the state rank it as one of the premier worldwide localities for that species. This paper briefly outlines the historical importance of the mineral, the mining history and the geological setting before discussing the varieties of quartz present, its crystallography and the geological enviroments in which it is found. The latter include volcanic rocks and near surface igneous rocks; pegmatites; metamorphic and plutonic rocks; hydrothermal veins; skarns and sedimentary deposits. Details of the localities and mode of occurrence of smoky quartz, amethyst, milky quartz, rock crystal, rose quartz, citrine, agate and jasper are then given. -S.J.Stone

  6. Changes in the artificial thermoluminescence glow curves of quartz associated with uranium deposits

    Energy Technology Data Exchange (ETDEWEB)

    Hochman, M.B.M.; Ypma, P.J.M.

    1988-01-01

    Previous laboratory-based studies have shown that quartz thermoluminescence (TL) glow curves change in intensity and shape in response to large radiation doses. Initially, low temperature peaks are sensitized though at gamma doses of greater than 10/sup 5/ - 10/sup 6/ kGy desensitization occurs. This study has examined the change in artificial TL in quartz at various distances from a uranium deposit. Such quartz has been subjected to varying palaeoradiation doses in a natural uranium rich environment. Quartz from an uranium rich environment shows that the 130/sup 0/C glow peak is the dominant glow peak in background radiation environments, though this peak decreases with increasing palaeoradiation dose. At doses greater than 10/sup 5/-10/sup 6/ kGy the 350/sup 0/C glow peak is the dominant glow peak in these quartz samples. An increase in E'/sub 1/ centre concentration also occurs from the least radiation affected sample to the most radiation affected sample. These results suggest that artificial TL is useful in uranium exploration.

  7. Annual dose measurements and TL-dating of ancient Egyptian pottery

    Energy Technology Data Exchange (ETDEWEB)

    Abdel-Wahab, M S; El-Fiki, S A; Abdel-Kariem, S; El-Faramawy, N [Ain Shams University, Cairo (Egypt). Faculty of Science; EL-Fiki, M A [National Institute of Standards, Cairo (Egypt); Gomaa, M [Atomic Energy Establishment, Cairo (Egypt). Nuclear Research Center

    1996-05-01

    In the course of the dating of ancient Egyptian pottery, pottery sherds were collected from three archaeological tombs in Nazlet El Samman region, Giza zone (Egypt). The annual dose from natural background was measured by gamma spectrosocopic technique as well as thermoluminescence (TL) measurements. The results of both methods are in good agreement with a consistency of 99.69%. The extracted quartz exhibited TL dating peaks at about (305 {+-} 5){sup o}C. The TL dating shows an age of 4301 {+-} 100 years for the examined pottery which belongs to the ``Fourth Dynasty`` in the ``OlKingdom`` . The uncertainties in TL dating using the additive method are much lower than that of archaeologists. (author).

  8. Annual dose measurements and TL-dating of ancient Egyptian pottery

    Science.gov (United States)

    Abdel-Wahab, M. S.; El-Fiki, S. A.; El-Fiki, M. A.; Gomaa, M.; Abdel-Kariem, S.; El-Faramawy, N.

    1996-05-01

    In the course of the dating of ancient Egyptian pottery, pottery sherds were collected from three archaeological tombs in Nazlet El Samman region, Giza zone (Egypt). The annual dose from natural background was measured by gamma spectroscopic technique as well as thermoluminescence (TL) measurements. The results of both methods are in good agreement with a consistency of 99.69%. The extracted quartz exhibited TL dating peaks at about(305 ± 5|4)°C. The TL dating shows an age of 4301 ± 100 years for the examined pottery which belongs to the "Fourth Dynasty" in the "Old Kingdom". The uncertainties in TL dating using the additive method are much lower than that of archeologists.

  9. Annual dose measurements and TL-dating of ancient Egyptian pottery

    International Nuclear Information System (INIS)

    Abdel-Wahab, M.S.; El-Fiki, S.A.; Abdel-Kariem, S.; El-Faramawy, N.; Gomaa, M.

    1996-01-01

    In the course of the dating of ancient Egyptian pottery, pottery sherds were collected from three archaeological tombs in Nazlet El Samman region, Giza zone (Egypt). The annual dose from natural background was measured by gamma spectrosocopic technique as well as thermoluminescence (TL) measurements. The results of both methods are in good agreement with a consistency of 99.69%. The extracted quartz exhibited TL dating peaks at about (305 ± 5) o C. The TL dating shows an age of 4301 ± 100 years for the examined pottery which belongs to the ''Fourth Dynasty'' in the ''OlKingdom'' . The uncertainties in TL dating using the additive method are much lower than that of archaeologists. (author)

  10. Investigation of the characteristics of thermoluminescence glow curves of natural hydrothermal quartz from Hakkari area in Turkey

    International Nuclear Information System (INIS)

    Topaksu, M.; Yüksel, M.; Dogan, T.; Nur, N.; Akkaya, R.; Yegingil, Z.; Topak, Y.

    2013-01-01

    In this study the dosimetric characteristics of some natural hydrothermal quartz (NHQ) samples collected from Hakkari were investigated by using the thermoluminescence (TL) technique for the purpose of determining whether they are suitable as dosimetric materials or not and calculating the kinetic parameters. The experiments carried out can be outlined as: analyzing TL glow curves of NHQ; determining the annealing conditions; the effects of pre-irradiation annealing procedures on TL sensitivity; the investigation of the characteristics of TL glow curves obtained after annealing the samples; determination of the trap parameters with the computerized glow curve deconvolution (CGCD) method and the peak shape (PS) method. The obtained results showed that the trap depths and the frequency factor values are consistent with the literature. The studied samples have linear dose responses for the absorbed doses ranging between ∼6.689 Gy and ∼301 Gy. In conclusion, the examined quartz samples can be used as dosimetric materials in high dose applications

  11. Analytical investigations of thermoluminescence glow curve on quartz for luminescence dating

    International Nuclear Information System (INIS)

    Kim, K.B.; Hong, D.G.

    2015-01-01

    Investigations of bleaching and thermoluminescence (TL) response to radiation dose of quartz are importance in luminescence dating. Although such research has been extensively carried out for various types of quartz, most work was performed on the basis of TL intensity integrated for a particular temperature range on the glow curve, without any peak separation. In this study we investigated bleaching by a blue light stimulation and radiation dose behaviour for separated TL glow peaks of quartz, which are thermally stable, by using the computerized glow curve deconvolution (CGCD) method combined with the T_m–T_s_t_o_p method. The T_m–T_s_t_o_p method indicates that the glow curve of quartz is the superposition of at least seven components (P1–P7) in the temperature range between room temperature and 450 °C. A bleaching experiment for four thermally stable glow peaks (P4–P7) using a blue light stimulation revealed that the bleaching rate of peak P4 exhibits three different exponential decays, whereas the peaks P5, P6 and P7 are bleached with two different exponential decays. After bleaching of 12 h, the TL intensity of peaks P4, P5, P6 and P7 were reduced to approximately 6%, 16%, 26% and 68% of the initial value, respectively. Additionally, in a study of the radiation dose response of the four thermally stable glow peaks, all peaks have a similar pattern, which are well fitted by a single saturating exponential function. - Highlights: • We studied the physical characteristics of the separated TL glow peaks on quartz. • The kinetic parameters of each separated glow peak are evaluated by a CGCD method. • The separated peaks were bleached with two or three exponential decays. • The dose responses for the separated peaks showed a similar growth curve.

  12. Progress in TL Dating at Risø

    DEFF Research Database (Denmark)

    Mejdahl, V.

    1972-01-01

    This article outlines the thermoluminescent dating technique employed at Risö. The intensity of beta and gamma radiation is determined by means of the TL phosphors CaSO4:Mn and CaSO4:Dy, and the determination of accumulated exposure is based on quartz and feldspar inclusions with a size of 0.......3–0.5 mm. Results are presented of a dating programme comprising sherds, bricks, burned stones and burned clay (from kilns) from seventeen excavation sites. The age of the sites ranged from a.d. 1600 to 4000 b.c....

  13. Study on fine quartz pre-dose techniques

    International Nuclear Information System (INIS)

    Leung, P.L.; Stokes, M.J.; Wang Weida; Xia Junding

    1996-01-01

    When using the pre-dose technique in ceramic dating, it is essential to add a calibration dose and to eliminate the background dose. For doing this measurement the sample requires multiple activation following multiple administration of a test dose to induce simulated 'ancient' thermoluminescence (TL). However, the procedures introduce many factors that are difficultly corrected. The authors compare existing two kinds of measurement procedures and proposes a new procedure involving single activation following a single test dose administration. An experiment using the single activation procedure is carried out with natural fine quartz where the results obtained exhibit only 0.07 relative error. It appears that this new procedure increases the precision of the ancient TL measurement by about 0.04 and 0.11 over those of existing two kinds of procedures. In addition this method can give realistic values in TL dating for relatively 'young' samples aged tens to hundreds of years where the standard high temperature TL method is relatively insensitive

  14. Dependence of red thermoluminescence on Eu-anomaly in natural quartzes

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T; Yokosaka, K; Notoya, S; Ojima, T; Sakaue, S [Niigata Univ. (Japan). Faculty of Science

    1993-04-01

    The causes of red colour thermoluminescence (RTL) from natural quartz have been sought in the presence of impurity elements. Some impurities in 31 varieties of natural quartz extracts, determined by a neutron activation analysis, have been examined with respect to a meaningful correlation of the RTL to the total detectable TL strength. Generally, the higher impurity contents were found in quartz of volcanic origin, which always emits purely RTL colour, whereas the lower impurities were usually detected in hydrothermal quartz, which emits purely blue TL (BTL) in all absorbed doses. Among the impurities, the middle REE (rare earth elements), involving Eu and Sm, particularly offered considerable correlation with RTL emission with the exception of pegmatite quartz. It was found from the chondrite-normalized REE patterns that a positive Eu anomaly or flattened Eu distribution gave rise to relatively high RTL proportions, while a negative Eu anomaly always showed extremely weak RTL intensity. Thus, it was concluded that the Eu[sup 3+], formed from the oxidizable surrounding or high oxygen fugacity relative to a Cl chondrite formation, is strongly related to the RTL intensity in natural quartz. (author).

  15. Spectrophotometric determination of Tl carrier in 201Tl-TlCl injection

    International Nuclear Information System (INIS)

    Gong Quansheng; Jing Lie

    1997-01-01

    A simple and sensitive method for the spectrophotometric determination of carrier content (Thallium) in 201 Tl-TlCl injection is described. Thallium (I) is oxidised to Thallium (III) by aqueous bromine, then excess bromine is removed by adding sulfosalicylic acid. In buffer solution (NH 4 Cl-NH 4 OH) at pH 11.7 with the presence of emulsifier OP, thallium (III) and cadion form a complex having an absorption maximum at 469 nm with a molar absorptivity of 1.37 x 10 4 m 2 /mol. Beer's law is obeyed in the concentration range of 0-7 μg/5 mL. The effect of impurity elements in 201 Tl-TlCl injection is examined. It is an ideal method for the analysis of radioactive solution

  16. Quartz analysis in gravimetric sampling

    International Nuclear Information System (INIS)

    Rex, D.A.

    1990-01-01

    An overview of the methods employed in the assessment of quartz exposure is provided. The principles and some of the problems associated with each method is discussed. The methods reviewed include wet chemical methods, X-ray diffraction and infrared absorption of which the latter two methods are deemed appropriate for analysing quartz on personal gravimetric collected samples. The implications of combining area samples collected over a six month period, and performing only a single quartz analysis rather than separate analyses, are considered. Finally, various options open to mines with regard to their involvement with quartz analysis are also briefly discussed. 35 refs., 6 figs., 1 tab

  17. Generalized isothermic lattices

    International Nuclear Information System (INIS)

    Doliwa, Adam

    2007-01-01

    We study multi-dimensional quadrilateral lattices satisfying simultaneously two integrable constraints: a quadratic constraint and the projective Moutard constraint. When the lattice is two dimensional and the quadric under consideration is the Moebius sphere one obtains, after the stereographic projection, the discrete isothermic surfaces defined by Bobenko and Pinkall by an algebraic constraint imposed on the (complex) cross-ratio of the circular lattice. We derive the analogous condition for our generalized isothermic lattices using Steiner's projective structure of conics, and we present basic geometric constructions which encode integrability of the lattice. In particular, we introduce the Darboux transformation of the generalized isothermic lattice and we derive the corresponding Bianchi permutability principle. Finally, we study two-dimensional generalized isothermic lattices, in particular geometry of their initial boundary value problem

  18. Effect of pre-dose irradiation in the quartz and its use for archaelogical dating

    International Nuclear Information System (INIS)

    Yukimitu, K.

    1985-01-01

    The technique of pre-dose for dating ceramics, using the thermoluminescent properties of quartz is presented. The behavior of thermoluminescent (TL) sensitivity of the 110 0 C peak of Brazilian quartz, in its geologic state, submitted to thermal treatments from 600 to 900 0 C, is studied. The samples were tritured for separating the quartz crystals from clay. The quartz grains were submitted to leaching with chloric acid solution followed by leaching with running water. The samples were irradiated in laboratory, with gamma radiation using Co-60 and Cs-137 sources, for calibration. A sensitivity enhancement rate of 2% per rad was observed for samples annealed at 900 0 C, was observed. (M.C.K.) [pt

  19. The interpretation of quartz optically stimulated luminescence equivalent dose versus time plots

    International Nuclear Information System (INIS)

    Bailey, R.M.

    2000-01-01

    Numerical modelling has shown that the form of the quartz OSL shine plateau (hereafter 'D e (t)-plot') is influenced by the effects of phototransferred TL in the ∼110 deg. C region. It is suggested also that the presence of multiple OSL components (as described by Partial bleaching and the decay form characteristics of quartz OSL. Radiat. Meas., 27, 123-136. The form of the optically stimulated luminescence signal of quartz: implications of dating. Unpublished PhD thesis, University of London) affects the form of the D e (t)-plot. Laboratory measurements of a fully reset and artificially dosed sample yielded non-flat D e (t)-plots, the deviation being greater for the larger of the two simulated palaeodoses, in accordance with theoretical predictions. It is suggested that the so-called 'shine plateau' test is of limited use in assessing the bleaching history of quartz sediments

  20. Influence of thermoluminescence trapping parameter from abundant quartz powder on equivalent dose

    International Nuclear Information System (INIS)

    Zhao Qiuyue; Wei Mingjian; Song Bo; Pan Baolin; Zhou Rui

    2014-01-01

    Glow curves of abundant quartz powder were obtained with the RGD-3B thermoluminescence (TL) reader. TL peaks with 448, 551, 654, 756 K were identified at the heating rate of 5 K/s. The activation energy, frequency factor and lifetime of trapped charge were evaluated at ambient temperature for four peaks by the method of various heating rates. Within a certain range of activation energy, the equivalent dose increases exponentially with the activation energy. The equivalent dose increases from 54 Gy to 485 Gy with the temperature from 548 K to 608 K, and it fluctuates around 531 Gy with the temperature from 608 K to 748 K. (authors)

  1. Blue and red thermoluminescence of natural quartz in the temperature region from -196 to 400deg. C

    International Nuclear Information System (INIS)

    Hashimoto, Tetsuo; Yanagawa, Yuji; Yawata, Takashi

    2007-01-01

    Quartz samples of three different origins were γ-irradiated with 20kGy at room temperature or at the temperature of liquid nitrogen (-196 deg. C), and analyzed by on-line TL-emission spectrometry over two temperature ranges: above 200deg. C (high-temperature region) and -196 to 200deg. C (low-temperature region). The emission spectra in the high-temperature region could be separated into intense blue TL (BTL) or red TL (RTL) properties. All quartz samples displayed more or less both properties of BTL and RTL in the low temperature region, shifting the BTL-emission spectra towards violet. Particularly, volcanically originated quartz (RTL, Medeshima) showed highly complex BTL and RTL peaks in the low-temperature region, and a stronger simple RTL peak in the high temperature. These complex glow-curve peaks are considered to reflect the presence of many crystal defects and much content of impurities in the volcanically formed quartz. In the glow-curve measurements, Brazilian quartz (quartz-vein origin) gave weak RTL and intense BTL in the low-temperature range, followed by faint emission of BTL in the high-temperature side. On the other hand, the radiation-induced colored (CC) part of a Madagascan crystal rock slice (hydrothermal origin) showed intense BTL together with slight RTL in the low temperatures, followed by strong BTL and appreciable strength of RTL in the high temperatures. The BTL-emission pattern (TL-color image) of a Madagascan slice showed a complementary relationship between irradiations at liquid-nitrogen temperature and at room temperature. To explain these radiation-induced phenomena from quartz, hydrogen radicals and Li + ions, derived from radiolysis products of OH-related impurities, could operate to eliminate the BTL centers by recombination below the room temperature

  2. Isothermal Martensite Formation

    DEFF Research Database (Denmark)

    Villa, Matteo

    Isothermal (i.e. time dependent) martensite formation in steel was first observed in the 40ies of the XXth century and is still treated as an anomaly in the description of martensite formation which is considered as a-thermal (i.e. independent of time). Recently, the clarification of the mechanism...... of lattice strains provided fundamental information on the state of stress in the material and clarified the role of the strain energy on martensite formation. Electron backscatter diffraction revealed that the microstructure of the material and the morphology of martensite were independent on the cooling...... leading to isothermal kinetics acquired new practical relevance because of the identification of isothermal martensite formation as the most likely process responsible for enhanced performances of sub-zero Celsius treated high carbon steel products. In the present work, different iron based alloys...

  3. Adiabatic and isothermal resistivities

    International Nuclear Information System (INIS)

    Fishman, R.S.

    1989-01-01

    The force-balance method is used to calculate the isothermal resistivity to first order in the electric field. To lowest order in the impurity potential, the isothermal resistivity disagrees with the adiabatic results of the Kubo formula and the Boltzmann equation. However, an expansion of the isothermal resistivity in powers of the impurity potential is divergent, with two sets of divergent terms. The first set arises from the density matrix of the relative electron-phonon system. The second set arises from the explicit dependence of the density matrix on the electric field, which was ignored by force-balance calculations. These divergent contributions are calculated inductively, by applying a recursion relation for the Green's functions. Using the λ 2 t→∞ limit of van Hove, I show that the resummation of these divergent terms yields the same result for the resistivity as the adiabatic calculations, in direct analogy with the work of Argyres and Sigel, and Huberman and Chester

  4. Quartz crystal fabrication facility

    Science.gov (United States)

    Ney, R. J.

    1980-05-01

    The report describes the design and operation of a five chamber, interconnected vacuum system, which is capable of cleaning, plating, and sealing precision quartz crystal units in ceramic flatpack enclosures continuously in a high vacuum environment. The production rate design goal was 200 units per eight hour day. A unique nozzle beam gold deposition source was developed to operate for extended periods of time without reloading. The source puts out a narrow beam of gold typically in the order of 2 1/2 deg included cone angle. Maximum deposition rates are in the order of 400 a/min at 5.5 in. 'throw' distance used. Entrance and exit air lock chambers expedite the material throughput, so that the processing chambers are at high vacuum for extended periods of time. A stainless steel conveyor belt, in conjunction with three vacuum manipulators, transport the resonator components to the various work stations. Individual chambers are normally separated from each other by gate valves. The crystal resonators, mounted in flatpack frames but unplated, are loaded into transport trays in a lid-frame-lid sequency for insertion into the system and exit as completed crystal units. The system utilizes molybdenum coated ball bearings at essentially all friction surfaces. The gold sources and plating mask heads are equipped with elevators and gate valves, so that they can be removed from the system for maintenance without exposing the chambers to atmosphere.

  5. Hydrogen speciation in synthetic quartz

    Science.gov (United States)

    Aines, R.D.; Kirby, S.H.; Rossman, G.R.

    1984-01-01

    The dominant hydrogen impurity in synthetic quartz is molecular H2O. H-OH groups also occur, but there is no direct evidence for the hydrolysis of Si-O-Si bonds to yield Si-OH HO-Si groups. Molecular H2O concentrations in the synthetic quartz crystals studied range from less than 10 to 3,300 ppm (H/Si), and decrease smoothly by up to an order of magnitude with distance away from the seed. OH- concentrations range from 96 to 715 ppm, and rise smoothly with distance away from the seed by up to a factor of three. The observed OH- is probably all associated with cationic impurities, as in natural quartz. Molecular H2O is the dominant initial hydrogen impurity in weak quartz. The hydrolytic weakening of quartz may be caused by the transformation H2O + Si-O-Si ??? 2SiOH, but this may be a transitory change with the SiOH groups recombining to form H2O, and the average SiOH concentration remaining very low. Synthetic quartz is strengthened when the H2O is accumulated into fluid inclusions and cannot react with the quartz framework. ?? 1984 Springer-Verlag.

  6. Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements

    Directory of Open Access Journals (Sweden)

    Gierlotka W.

    2002-01-01

    Full Text Available The partial vapour pressure of mercury over liquid Hg-Tl liquid solutions were determined in the temperature range from 450 to 700 K by direct vapour pressure measurements carried out with the quartz gauge. From the measured ln pHg vs. T relationships activities of mercury were determined. Using Redlich-Kister formulas logarithms of the activity coefficients were described with the following equations: From which all thermodynamic functions in the solutions can be derived.

  7. Tl Cuprate Superconductors Studied by XPS

    Energy Technology Data Exchange (ETDEWEB)

    Vasquez, R. P. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109-8099 (United States); Siegal, M. P. [Sandia National Laboratories, Albuquerque, NM 87185-1421 (United States); Overmyer, D. L. [Sandia National Laboratories, Albuquerque, NM 87185-1421 (United States); Ren, Z. F. [Department of Chemistry, State University of New York, Buffalo, NY 14260-3000 (United States); Lao, J. Y. [Department of Chemistry, State University of New York, Buffalo, NY 14260-3000 (United States); Wang, J. H. [Department of Chemistry, State University of New York, Buffalo, NY 14260-3000 (United States)

    1999-07-01

    XPS measurements on epitaxial thin films of the Tl cuprate superconductors Tl2Ba2CaCu2O8, Tl2Ba2Ca2Cu3O10, and Tl0.78Bi0.22Ba0.4Sr1.6Ca2Cu3O9-{delta} are presented. These data, together with previous measurements in this lab on Tl2Ba2CuO6-{delta} and TlBa2CaCu2O7-{delta}, comprise a comprehensive data set for comparison of Tl cuprates in which the number of Tl-O and Cu-O layers, and hence the chemical and electronic properties, vary. (c) 2000 American Vacuum Society.

  8. Tl Cuprate Superconductors Studied by XPS

    International Nuclear Information System (INIS)

    Vasquez, R. P.; Siegal, M. P.; Overmyer, D. L.; Ren, Z. F.; Lao, J. Y.; Wang, J. H.

    1999-01-01

    XPS measurements on epitaxial thin films of the Tl cuprate superconductors Tl2Ba2CaCu2O8, Tl2Ba2Ca2Cu3O10, and Tl0.78Bi0.22Ba0.4Sr1.6Ca2Cu3O9-δ are presented. These data, together with previous measurements in this lab on Tl2Ba2CuO6-δ and TlBa2CaCu2O7-δ, comprise a comprehensive data set for comparison of Tl cuprates in which the number of Tl-O and Cu-O layers, and hence the chemical and electronic properties, vary. (c) 2000 American Vacuum Society

  9. Role of Substrate on Quartz Cementation in Quartz Aggregates

    Science.gov (United States)

    Farver, J. R.; Winslow, D.; Onasch, C.

    2010-12-01

    Quartz cementation in quartz aggregates has been experimentally investigated. The starting material was disaggregated detrital quartz grains from the well-sorted, mature St. Peter Sandstone. The ‘as-is’ grains have patches of iron oxide coatings and some have euhedral overgrowths that contain iron oxide dust rims. In addition a set of experiments was run using grains that were cleaned by soaking in sodium hydrosulfite and sodium bisulfate solutions to remove exposed iron oxide coatings. Experimental charges consisted of amorphous silica powder (≈30 mg) to provide a source of silica for the quartz cement, AlCl3 powder (≈3 mg) to provide a tracer for Cathodoluminescence (CL) identification of cement formed during the experiment, 25 wt% NaCl brine solution (≈25 mg) to increase the silica solubility and to better mimic oil field brines, and the natural quartz grains (100-130 mg). The charges were weld-sealed in Au capsules and run in cold-seal pressure vessels at 250°C to 450°C at 150 MPa confining pressure for up to 8 weeks. After the experiments, the samples were vacuum impregnated with a low viscosity epoxy containing a blue dye. After curing, the sample charge was sawn in half along its long axis and one half was polished (to 1 micron diamond paste) for analysis. The nature and amount of quartz cement in the samples were determined by a combination of CL, light microscopy, and scanning electron microscopy. Photomosaics of the samples were created and the amount of cement, porosity, and average grain sizes were determined by point-counting. The cement formed during the experiment was easily recognized from the quartz grains (and previous overgrowths) by the difference in luminescence. The results indicate the amorphous silica powder provides a ready source for silica for quartz cementation due to its greater solubility than the quartz. The cementation rates are rapid (>14% cement formed in 2 weeks at 450°C and >7% in 8 weeks at 250°C). Compared to

  10. Dosimetric characterization and identification of TL defect centres in sand for its application in sludge irradiators as an in situ dosimeter

    International Nuclear Information System (INIS)

    Benny, P.G.; Shah, M.R.; Sabharwal, S.; Bhatt, B.C.; Gundu Rao, T.K.

    2003-08-01

    The report presents investigations that have been carried out to establish a method for the routine/ periodic dosimetry for Sludge Hygienisation Research Irradiator (SHRI) facility set up at Baroda (India) for disinfection of liquid sewage sludge in bulk quantity. For this purpose, the possibility of using the sand, one of the components of inorganic matter found in sewage sludge, directly as a TL dosimeter has been explored. The report is presented in two parts. Part 1 presents dosimetric characterization of sand for its application as an in situ dosimeter. A review on various sewage sludge irradiators operating in the world and the different dosimetric techniques used for these facilities are briefly described. In the present studies, in order to investigate the thermoluminescence properties of sand, it was separated from the sewage sludge by an extensive cleaning procedure. Part 1 also describes the procedure for separation of sand from sewage sludge, study on its TL properties, dosimetric characterization of sand and application of cleaned sand collected at the outlet of the SHRI facility for estimating radiation absorbed dose imparted to the sludge during its disinfection as well as for determining distribution of dose for an irradiated sludge batch. A new method by using phototransferred thermoluminescence (PTTL) in quartz separated from sand has been explored for high-level gamma dosimetry. Part 2 of the report presents sensitization properties of TL peaks and study of TL defect centres in quartz. It describes the results on pre-dose sensitization of 220 degC and 110 degC TL peaks in the quartz samples separated from sand. From the TL and ESR studies, a mechanism for TL sensitization has been suggested, which involves the role of competing traps and E I - centres in the sensitization process. The paramagnetic radicals formed in quartz samples after gamma irradiation by using ESR technique have been briefly described. (author)

  11. Difference in luminescence sensitivity of coarse-grained quartz from deserts of northern China

    International Nuclear Information System (INIS)

    Zheng, C.X.; Zhou, L.P.; Qin, J.T.

    2009-01-01

    The luminescence sensitivity of coarse quartz extracted from desert sands in northern China was investigated. In general, the western deserts' samples are shown to be less sensitive than samples from the eastern deserts with respect to both OSL and the 110 deg. C TL peak. However, internal scatter among different aliquots of the same sample is observed for these two signals, which have already been normalized by weight. Laboratory dosing/bleach experiments indicate that earth surface processes, such as repeated burial and transportation can cause the sensitivity change and suggest that they may be responsible for the internal scatter. An intrinsic property of quartz was explored via the luminescence response to thermal activation to a maximum temperature of 700 deg. C. The thermal activation curves obtained with quartz from western and central deserts are similar, except one sample from Gurbantungut, which follows the pattern of eastern samples. The differences in quartz luminescence sensitivity exhibited by OSL/110 deg. C TL sensitivity and response to thermal activation are in accordance with the published results of geochemical studies.

  12. Development of NaI(Tl) scintillating films for imaging soft x-rays

    International Nuclear Information System (INIS)

    Shepherd, J.A.

    1993-01-01

    Thin film NaI(Tl) scintillators, of areas of up to 130 cm 2 , have been fabricated and characterized for use on soft x-ray imaging photomultiplier tubes. Relevant parameters of photon-counting imaging detectors are defined and used to predict the performance of several materials, including CsI(Na), CsI(Tl), CaF 2 (Eu), Lu 2 (SiO 4 )O:Ce, and NaI(Tl), as thin film scintillators on fiber optic substrates. Also, x-ray imaging methodologies are compared. The NaI(Tl) films were vapor-deposited onto quartz and fiber optic substrates using a powder flash deposition technique. When compared to single crystal NaI(Tl), the films were found to have equally high light yield but lower energy resolution. Light yield optimization was studied in detail including the effects of substrate temperature, activator concentration in the evaporant, and boat temperature. Spatial resolution as well as parallax errors are discussed and measured for film thicknesses up to 61 μm. A technique is described that can substantially increase the light collection of high index films on fiber optic disks. The light collection was improved by 20% by coating the disk with potassium silicate before the NaI(Tl) deposition. Large area films, up to 130 cm 2 , had a spatial uniformity of response within ±1.5% for count rate and ±3.5% for light yield, and their spatial resolution exceeded 16.6 lp mm -1 when deposited onto fiber optic substrates. The 8-keV x-ray detection efficiency of the microchannel plate imaging photomultiplier tube coupled to a NaI(Tl) film scintillator is predicted to be 88%. Other uses for the films are also described

  13. Understanding optically stimulated charge movement in quartz and feldspar using time-resolved measurements

    DEFF Research Database (Denmark)

    Ankjærgaard, Christina

    . Although, results are only presented for some quartz and feldspar samples, they were found to be very similar within the each group during the course of this work.Thermoluminescence (TL) and optically stimulated luminescence (OSL) from quartz and feldspar are widely used in accident dosimetry...... stimulation energy. The thesis first delves into three main methodological developments, namely (i) research and development of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration...... of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration for the best separation of quartz OSL from a mixed quarts-feldspar sample. It then proceeds to study the different charge transport...

  14. Retrospective dosimetry using Japanese brick quartz: A way forward despite an unstable fast decaying OSL signal

    DEFF Research Database (Denmark)

    Fujita, Hiroki; Jain, Mayank; Murray, A.S.

    2011-01-01

    signals has been carried out towards identification of common source traps. It is observed that OSL from Japanese brick quartz shows unusual luminescence characteristics; in particular, the initial fast decaying OSL signal contains a dominant (>90%) thermally unstable component related to the 85 °C TL...... peak, which necessitates a prior heat treatment. A single-aliquot regenerative-dose (SAR) protocol is developed and tested using thermal treatments intended to isolate a stable dosimetric signal. A minimum detection limit of 65 mGy is then estimated using this protocol. Following irradiation using 60Co...... of Japanese brick quartz examined here can be used to derive precise estimates of accident dose, and, possibly to distinguish between sources of gamma radiation in a nuclear accident. To our knowledge, this is the first report on the existence of an unstable fast decaying OSL signal in quartz derived from...

  15. The red thermoluminescence of quartz: 3-D spectral measurements

    International Nuclear Information System (INIS)

    Scholefield, R.B.; Prescott, J.R.

    1999-01-01

    As part of a general study of the thermoluminescence (TL) of quartz, we have examined the 3-D spectra of samples of quartz extracted from a variety of sediments. Blue emission at about 2.6 eV/475 nm, which is the photon energy region commonly used in luminescence dating, seems ubiquitous. Significant emission in the red, ∼1.9 eV/650 nm, has been found at most glow temperatures in all of our samples of Australian quartz sediments, and it is to this that particular attention is paid in the present work. A limited selection of samples from other countries has also been included. The ratio of the intensities of the red and blue emissions varies widely among samples. We have not found any evidence of a correlation between this ratio, nor the intensity of the red emission, with trace element concentration, including that of Al for which a correlation has been previously observed. In the context of luminescence dating, all samples have been examined to see whether they have a rapidly bleaching red component in a similar sense to the well-known 305 deg. C/2.95 eV/420 nm peak in quartz: some samples have such a component--some do not. A suggestive parallelism is found between the blue and red spectra, in that there are 'slowly bleaching' and 'rapidly bleaching' components at similar temperatures in the both red and the blue. However, there is no red component associated with the 110 deg. C peak used in pre-dose dating

  16. Converting Hg-1212 to Tl-2212 via Tl-Hg cation exchange in combination with Tl cation intercalation

    International Nuclear Information System (INIS)

    Zhao Hua; Wu, Judy Z

    2007-01-01

    In a cation exchange process developed recently for epitaxy of HgBa 2 CaCu 2 O 6 (Hg-1212) thin films, TlBa 2 CaCu 2 O 7 (Tl-1212) or Tl 2 Ba 2 CaCu 2 O 9 (Tl-2212) precursor films were employed as the precursor matrices and Hg-1212 was obtained by replacing Tl cations on the precursor lattice with Hg cations. The reversibility of the cation exchange dictates directly the underlying mechanism. Following our recent success in demonstrating a complete reversibility within '1212' structure, we show the conversion from Hg-1212 to Tl-2212 can be achieved via two steps: conversion from Hg-1212 to Tl-1212 followed by Tl intercalation to form double Tl-O plans in each unit cell. The demonstrated reversibility of the cation exchange process has confirmed the process is a thermal perturbation of weakly bonded cations on the lattice and the direction of the process is determined by the population ratio between the replacing cations and that to be replaced

  17. Superconducting transition in TlBiTe/sub 2/ and TlTe compounds

    Energy Technology Data Exchange (ETDEWEB)

    Kantser, V G; Popovich, N S; Sidorenko, A S

    1985-10-01

    On the basis of zone structure calculation for TlBiTe/sub 2/ and TlTe it is found that TlBiTe/sub 2/ is a narrow-gap semiconductor and TlTe is a p-metal. At Tsub(c)=0.19 K TlTe is found to experience the superconducting transition. In TlBiTe/sub 2/ superconductivity is not observed to occur up to 0.05 K, since there is a possibility of occupying the high density of states zones because they are remote from actual ones. The earlier discovered superconducting transition in TlBiTe/sub 2/ is inherent in the alien phase of TlTe.

  18. Pure thermal sensitisation and pre-dose effect of OSL in both unfired and annealed quartz samples

    Energy Technology Data Exchange (ETDEWEB)

    Oniya, Ebenezer O., E-mail: ebenezer.oniya@aaua.edu.ng [Physics and Electronics Department, Adekunle Ajasin University, 342111 Akungba Akoko (Nigeria); Polymeris, George S. [Institute of Nuclear Sciences, Ankara University, Beşevler 06100, Ankara (Turkey); Jibiri, Nnamdi N. [Department of Physics, University of Ibadan, Ibadan (Nigeria); Tsirliganis, Nestor C. [Department of Archaeometry and Physicochemical Measurements, R.C. ‘Athena’, P.O. Box 159, Kimmeria University Campus, 67100 Xanthi (Greece); Babalola, Israel A. [Department of Physics, University of Ibadan, Ibadan (Nigeria); Kitis, George [Nuclear Physics Laboratory, Department of Physics, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)

    2017-06-01

    The sensitisation of quartz has attracted much attention since its thorough understanding is important in luminescence studies and dating applications. The present investigation examines the influence of pure thermal activation and predose treatments on the sensitisation of different components of linearly modulated optically stimulated luminescence (LM-OSL) measured at room temperature (RT) thereby eliminating undesired thermal quenching effects. Annealed and unfired quartz samples from Nigeria were used. The OSL measurements were carried out using an automated RISØTL/OSL reader (model-TL/OSL–DA–15). A new approach was adopted to match each of the resolved components of the RT-LM-OSL to respective thermoluminescence (TL) peaks that share the same electron trap and recombination centers. Pure thermal activation and pre-dose treatments respectively affect the sensitisation of all the components of the RT-LM-OSL in a similar manner as the one reported for the 110 °C TL peak but without thermal quenching contributions. Component C4 in annealed samples that was identified to share the same electron trap and recombination centers with the 110 °C TL peak was also proved appropriate for RT-LM-OSL, instead of the initial part of the continuous wave (CW) OSL signal, thus the methods can serve as complementary dating methods.

  19. Pure thermal sensitisation and pre-dose effect of OSL in both unfired and annealed quartz samples

    International Nuclear Information System (INIS)

    Oniya, Ebenezer O.; Polymeris, George S.; Jibiri, Nnamdi N.; Tsirliganis, Nestor C.; Babalola, Israel A.; Kitis, George

    2017-01-01

    The sensitisation of quartz has attracted much attention since its thorough understanding is important in luminescence studies and dating applications. The present investigation examines the influence of pure thermal activation and predose treatments on the sensitisation of different components of linearly modulated optically stimulated luminescence (LM-OSL) measured at room temperature (RT) thereby eliminating undesired thermal quenching effects. Annealed and unfired quartz samples from Nigeria were used. The OSL measurements were carried out using an automated RISØTL/OSL reader (model-TL/OSL–DA–15). A new approach was adopted to match each of the resolved components of the RT-LM-OSL to respective thermoluminescence (TL) peaks that share the same electron trap and recombination centers. Pure thermal activation and pre-dose treatments respectively affect the sensitisation of all the components of the RT-LM-OSL in a similar manner as the one reported for the 110 °C TL peak but without thermal quenching contributions. Component C4 in annealed samples that was identified to share the same electron trap and recombination centers with the 110 °C TL peak was also proved appropriate for RT-LM-OSL, instead of the initial part of the continuous wave (CW) OSL signal, thus the methods can serve as complementary dating methods.

  20. Quartz crystal reinforced quartz glass by spark plasma sintering

    International Nuclear Information System (INIS)

    Torikai, D.; Barazani, B.; Ono, E.; Santos, M.F.M.; Suzuki, C.K.

    2011-01-01

    The Spark Plasma Sintering presents fast processing time when compared to conventional sintering techniques. This allows to control the grain growth during sintering as well as the diffusion rate of a multi-material compounds, and make possible obtainment of functionally graded materials and nanostructured compounds. Powders of high purity silica glass and crystalline silica were sintered in a SPS equipment at temperatures around 1350° C, i.e., above the softening temperature of silica glass and below the melting temperature of quartz crystal. As a result, glass ceramics with pure silica glass matrix reinforced with crystalline alpha-quartz grains were fabricated at almost any desired range of composition, as well as controlled size of the crystalline reinforcement. X-ray diffraction and density measurements showed the possibility to manufacture a well controlled density and crystallinity glass-ceramic materials. (author)

  1. Study of seed for synthetical quartz

    International Nuclear Information System (INIS)

    Suzuki, C.K.; Torikai, D.

    1988-01-01

    Natural quartz blocks for seed (synthetic quartz technology) were studied by using various characterization techniques, such as X-ray topography, optical micrography, inspectoscopy, polariscopy and conoscopy, and etching. One of the most commonly found defect is the electrical or Dauphine twin. In The present research, we have developed a methodology to obtain a highly perfect seed for the synthetic quartz industries. (author) [pt

  2. Toroidal helical quartz forming machine

    International Nuclear Information System (INIS)

    Hanks, K.W.; Cole, T.R.

    1977-01-01

    The Scyllac fusion experimental machine used 10 cm diameter smooth bore discharge tubes formed into a simple toroidal shape prior to 1974. At about that time, it was discovered that a discharge tube was required to follow the convoluted shape of the load coil. A machine was designed and built to form a fused quartz tube with a toroidal shape. The machine will accommodate quartz tubes from 5 cm to 20 cm diameter forming it into a 4 m toroidal radius with a 1 to 5 cm helical displacement. The machine will also generate a helical shape on a linear tube. Two sets of tubes with different helical radii and wavelengths have been successfully fabricated. The problems encountered with the design and fabrication of this machine are discussed

  3. Prolate yrast cascade in 183Tl

    International Nuclear Information System (INIS)

    Reviol, W.; Carpenter, M. P.; Janssens, R. V. F.; Jenkins, D.; Toth, K. S.; Bingham, C. R.; Riedinger, L. L.; Weintraub, W.; Cizewski, J. A.; Lauritsen, T.

    2000-01-01

    The yrast sequence in 183 Tl has been studied for the first time in recoil-mass selected γ-ray spectroscopic measurements. A rotational-like cascade of seven transitions is established down to the band head with probable spin and parity (13/2 + ). Unlike in the adjacent odd-mass Tl nuclei, prompt γ decay from the yrast band to a lower lying weakly deformed (oblate) structure is not observed. These features are consistent with the predicted drop of the prolate band head in 183 Tl compared to 185 Tl. The implications for the prolate energy minimum in odd-mass Tl nuclei at the neutron i 13/2 midshell (N=103) are discussed. (c) 2000 The American Physical Society

  4. The effects of pre-dose and annealing temperature on some dosimetric properties of thermoluminescence of quartz

    International Nuclear Information System (INIS)

    Lin Zhikai

    1996-02-01

    The following aspects of dosimetric properties of quartz sample were studied. (1) The changes in dosimetric sensitivity of quartz with different pre-doses under different annealing temperature; (2) the option of optimal annealing temperature which can make the dosimetric sensitivity of quartz to restore its original level; (3) The changes in dosimetric sensitivity of quartz with different annealing time at 500 degree C for 8 h; (4) Repeated experiments were carried out in order to prove whether the sensitivity of quartz can restore its original level at annealing temperature 700 degree C for 3 h. It has been found that at 700 degree C for 3 h gave the least sensitivity change and the sensitivity of quartz almost restored its original level. Repeated experiments with four kinds of quartz sample confirmed this conclusion. The dramatic change of TL glow curve occurred only at the condition of annealing temperature 900 degree C for 1 h. This result was different from that obtained by D. J. Huntley et al. (1988). (3 refs., 4 figs., 1 tab.)

  5. Quartz glass behavior at ultraviolet spectrum region

    International Nuclear Information System (INIS)

    Braga, A.F.B.; Barbosa, L.C.; Evora, C.A.P.D.

    1990-01-01

    Melted quartz ingots were produced from raw materials of different sources. Behavior studies of these three different quartz glass were made at the eletromagnetic spectrum ultraviolet region. The atomic absorption spectroscopy was used as an analysis technique of the alkaline, transition and aluminum metal traces. It was found that the alkaline, transition and aluminum metals impurities present a great influence on the melted quartz spectral behavior at the ultraviolet region. It was stated that measurments at this spectrum region constitute an important characterization technique to natural quartz as well as melted quartz. (author) [pt

  6. TL/OSL properties of natural schist for archaeological dating and retrospective dosimetry

    International Nuclear Information System (INIS)

    Afouxenidis, D.; Stefanaki, E.C.; Polymeris, G.S.; Sakalis, A.; Tsirliganis, N.C.; Kitis, G.

    2007-01-01

    Schist, a metamorphic rock composed largely of quartz and muscovite, has been used as a building stone through the centuries in many parts of the world. In ancient Greece, it was used in buildings and monuments (Knossos, Karthaia, etc). Basic TL and OSL properties of schist are studied in the present work to evaluate its potential use in archaeological dating and retrospective dosimetry. In particular, the optical stability, as well as the linearity of the TL and OSL signal were investigated for samples of natural schist obtained from a roofing slate. The results indicate that both signals are rapidly bleached when the sample is exposed to sunlight. An exposure of 1 min reduces the TL signal by 93%, the IRSL signal by 99% and the post-IR BSL signal by 90%. The dose response was found to be linear for a radiation dose at least up to 75 Gy for the TL and the IR OSL signal and at least up to 25 Gy for the post-IR BSL signal

  7. Diagnostic and corrective procedures for TL analysis using the pre-dose technique

    International Nuclear Information System (INIS)

    Haskell, E.H.

    1985-01-01

    The high sensitivity of the pre-dose TL technique using fired quartz grains with relatively low doses makes it the only TL technique that is generally suitable for retrospective environmental dosimetry. The use of this technique for dose measurements of less than 0.2 Gy has been the focus of research at the Utah laboratory, while the extension of the useful range of the pre-dose technique to doses in excess of 5 Gy has been the aim of the Durham laboratory. Certain characteristics of the pre-dose phenomenon, if not properly diagnosed, can lead to erroneous dose estimates at both extremes. This paper describes the procedures used at both laboratories to diagnose such problems and recently developed methods for their circumvention. (author)

  8. Manufacturing polycrystalline pellets of natural quartz for applications in thermoluminescence dosimetry

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho Junior, Alvaro Barbosa de; Khoury, Helen Jamil [Federal University of Pernambuco (UFPE), Recife, PE (Brazil). Department of Nuclear Energy; Barros, Thiago Fernandes; Guzzo, Pedro Luiz [Federal University of Pernambuco (UFPE), Recife, PE (Brazil). Department of Mining Engineering

    2012-07-15

    This paper describes the manufacturing process of quartz-pellets and shows their potential use as thermoluminescence dosimeters (TLD) for those applications where low-levels of ionising radiation are present. Two batches of cold-pressed pellets were produced and their resistance were evaluated by vibration tests and weight-loss measurements. The batch manufactured with 75 Multiplication-Sign 150 Micro-Sign m particles showed enough resistance to be employed as TLD. The dosimetric properties of the 310 Degree-Sign C peak appearing in the glow curves of these pellets were characterized together with commercial TLD-100 units using {gamma}- and X-ray beams with different energies. The uncertainties related to reproducibility and stability of the TL signal were better than 10%. The sensitivity and the linearity of the TL response of quartz-pellets were better than that measured for TLD-100 for doses ranging from 0.5 to 200mGy. The energy dependence of the quartz-pellets was higher than that of TLD-100 but it cannot be considered a restriction to their use in clinical procedures and industrial applications. (author)

  9. Understanding optically stimulated charge movement in quartz and feldspar using time-resolved measurements

    International Nuclear Information System (INIS)

    Ankjaergaard, C.

    2010-02-01

    Thermoluminescence (TL) and optically stimulated luminescence (OSL) from quartz and feldspar are widely used in accident dosimetry and luminescence dating. In order to improve already existing methods or to develop new methods towards extending the current limits of the technique, it is important to understand the charge movement within these materials. Earlier studies have primarily focussed on examination of the trap behaviour; however, this only tells half of the story as OSL is a combination of charge stimulation and recombination. By using time-resolved OSL (TR-OSL), one can directly examine the recombination route(s), and thus obtain insight into the other half of the process involved in luminescence emission. This thesis studies the TR-OSL and optically stimulated phosphorescence signals from quartz and feldspars spanning several orders of magnitude in time (few ns to the seconds time scale) in order to identify various charge transport mechanisms in the different time regimes. The techniques employed are time-resolved OSL, continuous-wave OSL, TL, optically stimulated exo-electron (OSE) emission and time-resolved OSE. These different techniques are used in combination with variable thermal or optical stimulation energy. The thesis first delves into three main methodological developments, namely (i) research and development of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration for the best separation of quartz OSL from a mixed quarts-feldspar sample. It then proceeds to study the different charge transport mechanisms subsequent to an optical stimulation pulse in quartz and feldspars. The results obtained for quartz conclude that the main lifetime component in quartz represents an excited state lifetime of the recombination centre, and the more slowly decaying components on the millisecond to seconds time scale arise from charge recycling

  10. Understanding optically stimulated charge movement in quartz and feldspar using time-resolved measurements

    Energy Technology Data Exchange (ETDEWEB)

    Ankjaergaard, C.

    2010-02-15

    Thermoluminescence (TL) and optically stimulated luminescence (OSL) from quartz and feldspar are widely used in accident dosimetry and luminescence dating. In order to improve already existing methods or to develop new methods towards extending the current limits of the technique, it is important to understand the charge movement within these materials. Earlier studies have primarily focussed on examination of the trap behaviour; however, this only tells half of the story as OSL is a combination of charge stimulation and recombination. By using time-resolved OSL (TR-OSL), one can directly examine the recombination route(s), and thus obtain insight into the other half of the process involved in luminescence emission. This thesis studies the TR-OSL and optically stimulated phosphorescence signals from quartz and feldspars spanning several orders of magnitude in time (few ns to the seconds time scale) in order to identify various charge transport mechanisms in the different time regimes. The techniques employed are time-resolved OSL, continuous-wave OSL, TL, optically stimulated exo-electron (OSE) emission and time-resolved OSE. These different techniques are used in combination with variable thermal or optical stimulation energy. The thesis first delves into three main methodological developments, namely (i) research and development of the equipment for TR-OSL measurements, (ii) finding the best method for multiple-exponential analysis of a TR-OSL curve, and (iii) optimisation of the pulsing configuration for the best separation of quartz OSL from a mixed quarts-feldspar sample. It then proceeds to study the different charge transport mechanisms subsequent to an optical stimulation pulse in quartz and feldspars. The results obtained for quartz conclude that the main lifetime component in quartz represents an excited state lifetime of the recombination centre, and the more slowly decaying components on the millisecond to seconds time scale arise from charge recycling

  11. A comprehensive comparative study of the pre-dose effect for three quartz crystals of different origin

    International Nuclear Information System (INIS)

    Kitis, G.; Pagonis, V.; Chen, R.; Polymeris, G.

    2006-01-01

    The study of the thermoluminescence (TL) sensitivity of quartz due to heat and irradiation treatments is of importance in dating and retrospective dosimetry. A comprehensive comparative study of the pre-dose effect was carried out for three types of quartz of different origin. Complete TL vs. dose and sensitivity S vs. pre-dose curves were obtained for the dose range of 0.1 < D < 400 Gy. Additional complete sensitivity vs. pre-dose curves were obtained for samples which underwent a combined pre-dose irradiation and a subsequent heat treatment to 500 deg. C. Although the TL vs. dose curves showed very different behaviours, the sensitivity vs. pre-dose curves showed several common characteristics. The sensitivity vs. pre-dose curves showed abrupt changes ∼10 Gy. The sensitivity after a combined pre-dose irradiation and heat treatment to 500 deg. C showed a very gradual change in the whole dose range studied. These results are explained qualitatively by using the modified Zimmerman model for quartz. (authors)

  12. On luminescence lifetimes in quartz

    International Nuclear Information System (INIS)

    Chithambo, M.L.; Galloway, R.B.

    2000-01-01

    In this paper we present results of investigations concerning the time dependence of luminescence emission relative to the time of stimulation in quartz. Measurements of time-resolved spectra were performed on a new versatile pulsed light emitting diode system using 525 nm stimulation, an 11 μs duration pulse, a repetition rate of 11 kHz and a 64 μs dynamic range. Effects on luminescence lifetime resulting from sample treatments such as optical stimulation, irradiation, and preheating, are reported

  13. RDM lifetime measurements in 187Tl

    International Nuclear Information System (INIS)

    Chamoli, S.K.; Joshi, P.; Kumar, A.; Govil, I.M.; Mukherjee, G.; Singh, R.P.; Muralithar, S.; Bhowmik, R.K.

    2003-01-01

    The present work is an attempt to study the shape changes in 187 Tl through a measurement of electromagnetic transition probabilities of the high spin states. The Doppler shifted recoil distance technique was used to measure the lifetimes

  14. Disquisition and technical alteration about TL apparatus

    International Nuclear Information System (INIS)

    Wang Guangxiang; Li Mingliang

    2002-01-01

    The author simply introduces the disadvantage of TL apparatus controlled by single chip. The project uses the PC computer to replace single chip control. So it must be changed the interface and made up a software with Chinese

  15. TL dosimetric properties BAM:EU

    International Nuclear Information System (INIS)

    Rao, Bellam N.; Murthy, K.V.R.; Subba Rao, B.; Saiprasad, A.S.

    2011-01-01

    In phosphor area today top priority is the replacement of the high performance but very expensive rare earth activated phosphors with cheaper materials. This essentially means replacing the rare earth ions with transition metal ions or post transition ions. Now a day's phosphors are used in various fields. After World War II, the advances in the optical spectroscopy of solids, especially those of transition metals ions help to evolve research on phosphor and solid state luminescence. In 1960 efficient rare earth activated phosphors were developed for use in color TV (Tb 3+ green, Eu 3+ red, and Dy 3+ yellow). In 1970 tricolor lamp was introduced blue emission from Ce 3+ + Tb 3+ pair was used in tricolor lamps. At present combination of halo phosphor and tri-band phosphor blend is used in many lamp as a compromise between performance, phosphor cost and the lamp making Cost. Thermo luminescence of 0.5 Gy X-ray irradiated BAM.Eu has been studied. The irradiated phosphor has been studied for its TL dosimetric properties one week after irradiation and after 100 weeks of storage. Interesting TL results are reported in the present paper. Heating rate used in the present experiment is 6.6 deg C/Sec. The following two figures are on TL recorded 100 weeks after irradiation and TL recorded after 235 weeks of storage. Before storage for 100 weeks the TL glow curve with a hump around 180 deg C followed by a peak at 273 deg C. After storage for 100 weeks the TL pattern changes entirely. i.e. the composite TL peak structure emerged as two well resolved peaks and with slightly higher TL peak temperatures at 215 deg C and 300 deg C. Normally after storage for 100 weeks the peak at 190 deg C reduces in its intensity or disappears in some cases, instead of that the peak appears at 215 deg C as well resolved peak and its intensity is almost comparable to that of 300 deg C peak. Since the TL phenomenon observed is interesting the two well resolved, isolated, high intensity peaks

  16. Ferrobielastic twinning in irradiated quartz

    International Nuclear Information System (INIS)

    Shiau, S.M.

    1986-01-01

    Cultured quartz is usually free from electrical twinning; however, it may occur if the seed crystal is twinned or if undue applied forces are exerted on the crystal. Ferrobielastic twinning was studied optically (photoelastic effect) and electrically (piezoelectric effect). At room temperature, twins were perceptible at stresses of about 2.l5 x 10 8 N/m 2 , and crystals switched from their original states to the alternative twin states at stresses about 5.0 x 10 8 N/m 2 (called coercive stress). The decrease in coercive stress with increasing temperature was observed, and these coercive stresses become very low as temperatures reach to 300 0 C. The effects of irradiation on the twinning in quartz were also studied. The presence of defects produced by irradiation was utilized to pin the domain wall motion. Both neutrons and gamma rays were employed. The stress required to nucleate an appreciable volume of twins is about twice as high for irradiated crystals than for those unirradiated. This result demonstrated that the irradiated crystals can tolerate higher stresses. However, the coercive stress for complete switch-over was not much different for irradiated and unirradiated crystals. It appears that the defects caused by irradiation eliminate the initial twinning events but do not affect switch-over

  17. Quartz substrate infrared photonic crystal

    Science.gov (United States)

    Ghadiri, Khosrow; Rejeb, Jalel; Vitchev, Vladimir N.

    2003-01-01

    This paper presents the fabrication of a planar photonic crystal (p2c) made of a square array of dielectric rods embedded in air, operating in the infrared spectrum. A quartz substrate is employed instead of the commonly used silicon or column III-V substrate. Our square structure has a normalized cylinder radius-to-pitch ratio of r/a = 0.248 and dielectric material contrast ɛr of 4.5. We choose a Z-cut synthetic quartz for its cut (geometry), and etching properties. Then a particular Z-axis etching process is employed in order to ensure the sharp-edged verticality of the rods and fast etching speed. We also present the computer simulations that allowed the establishment of the photonic band gaps (PBG) of our photonic crystal, as well as the actual measurements. An experimental measurement have been carried out and compared with different simulations. It was found that experimental results are in good agreement with different simulation results. Finally, a frequency selective device for optical communication based on the introduction of impurity sites in the photonic crystal is presented. With our proposed structure Optical System on a Chip (OsoC) with micro-cavity based active devices such as lasers, diodes, modulators, couplers, frequency selective emitters, add-drop filters, detectors, mux/demuxes and polarizers connected by passive waveguide links can be realized.

  18. Measurement of the equivalent dose in quartz using a regenerative-dose single-aliquot protocol

    International Nuclear Information System (INIS)

    Murray, A.S.; Roberts, R.G.

    1998-01-01

    The principles behind a regenerative-dose single-aliquot protocol are outlined. It is shown for three laboratory-bleached Australian sedimentary quartz samples that the relative change in sensitivity of the optically stimulated luminescence (OSL) during a repeated measurement cycle (consisting of a dose followed by a 10 s preheat at a given temperature and then a 100 s exposure to blue/green light at 125 deg. C) is very similar to that of the 110 deg. C thermoluminescence (TL) peak measured during the preheat cycle. The absolute change in the TL sensitivity with preheat temperature is different for samples containing a natural or a regenerative dose. Furthermore, the absolute change in sensitivity in both the OSL and TL signals is non-linear with regeneration cycle, but the relative change in the OSL signal compared to the following 110 deg. C TL measurement is well approximated by a straight line. Both signals are thought to use the same luminescence centres, and so some common behaviour is not unexpected. A new regenerative-dose protocol is presented which makes use of this linear relationship to correct for sensitivity changes with regeneration cycle, and requires only one aliquot for the estimation of the equivalent dose (D e ). The protocol has been applied to quartz from nine Australian sites. To illustrate the value of the regenerative-dose single-aliquot approach, the apparent values of D e for 13 samples, containing doses of between 0.01 and 100 Gy, have been measured at various preheat temperatures of between 160 and 300 deg. C, using a single aliquot for each D e measurement. Excellent agreement is found between these single-aliquot estimates of D e and those obtained from additive-dose multiple-aliquot and single-aliquot protocols, over the entire dose range

  19. Radiation-Hard Quartz Cerenkov Calorimeters

    International Nuclear Information System (INIS)

    Akgun, U.; Onel, Y.

    2006-01-01

    New generation hadron colliders are going to reach unprecedented energies and radiation levels. Quartz has been identified as a radiation-hard material that can be used for Cerenkov calorimeters of the future experiments. We report from the radiation hardness tests performed on quartz fibers, as well as the characteristics of the quartz fiber and plate Cerenkov calorimeters that have been built, designed, and proposed for the CMS experiment

  20. Estimation of the total absorbed dose by quartz in retrospective conditions

    International Nuclear Information System (INIS)

    Correcher, V.; Delgado, A.

    2003-01-01

    The estimation of the total absorbed dose is of great interest in areas affected by a radiological accident when no conventional dosimetric systems are available. This paper reports about the usual methodology employed in dose reconstruction from the thermoluminescence (TL) properties of natural quartz, extracted from selected ceramic materials (12 bricks) picked up in the Chernobyl area. It has been possible to evaluate doses under 50mGy after more than 11 years later since the radiological accident happened. The main advance of this fact is the reduction of the commonly accepted limit dose estimation more than 20 times employing luminescence methods. (Author) 11 refs

  1. Using soils for accident dosimetry: a preliminary study using optically stimulated luminescence from quartz

    DEFF Research Database (Denmark)

    Fujita, Hiroki; Jain, Mayank; Murray, Andrew S.

    2011-01-01

    . The objective was to assess the potential of SAROSL dosimetry using soils for retrospective assessment of a radiation accident. Variation in dose with depth was also measured. The SAR data showed good reproducibility and dose recovery, and there was no evidence of fading of the quartz signal based on “delayed......” dose recovery experiments. The minimum detection limit (MDL) dose was about 0.1Gy. The dose dependence was measured using both the above SAR OSL protocol as well as a SAR thermoluminescence (TL, violet emission) protocol. The background doses were generally in the range of the MDL to several Gy......, and no clear trend in dose depth profile was observed. From these results, we conclude that SAR OSL dosimetry using natural quartz extracted from soil could be used to evaluate the dose of an accident....

  2. The Tl{sub 2}S–PbS–SiS{sub 2} system and the crystal and electronic structure of quaternary chalcogenide Tl{sub 2}PbSiS{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Mozolyuk, M.Y.; Piskach, L.V. [Department of Inorganic and Physical Chemistry, Lesya Ukrainka Eastern European National University, 13 Voli Avenue, 43025, Lutsk (Ukraine); Fedorchuk, A.O. [Department of Inorganic and Organic Chemistry, Lviv National University of Veterinary Medicine and Biotechnologies, 50 Pekarska Street, 79010, Lviv (Ukraine); Olekseyuk, I.D.; Parasyuk, O.V. [Department of Inorganic and Physical Chemistry, Lesya Ukrainka Eastern European National University, 13 Voli Avenue, 43025, Lutsk (Ukraine); Khyzhun, O.Y., E-mail: khyzhun@ipms.kiev.ua [Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, 3 Krzhyzhanivsky Street, 03142, Kyiv (Ukraine)

    2017-07-01

    Chalcogenides of the quasi-ternary system Tl{sub 2}S–PbS–SiS{sub 2} were synthesized in the evacuated silica ampoules by the melting and annealing technique. Phase equilibria in the system was investigated by XRD method. Isothermal section of the system was studied, and two intermediate quaternary phases were discovered to exist (Tl{sub 2}PbSiS{sub 4}, ∼Tl{sub 2}PbSi{sub 3}S{sub 8}). The quasi-binary section Tl{sub 2}SiS{sub 3}–PbS was investigated by DTA. Its phase diagram was constructed, and it was established that the equimolar compound melts incongruently at 818 K. The crystal structure of the quaternary compound Tl{sub 2}PbSiS{sub 4} was determined by X-ray powder diffraction. It crystallizes in the monoclinic space group P2{sub 1}/a with the unit-cell parameters a = 8.8141(4), b = 9.0150(5), c = 10.4383(5) Å, and β = 94.490(4)° (Tl{sub 2}PbGeS{sub 4} structure type). Reliability factors calculated in the isotropic approximation were found to be R{sub I} = 0.0564 and R{sub P} = 0.1070. The Tl{sub 2}PbSiS{sub 4} single crystal was tested with X-ray photoelectron spectroscopy. In particular, the XPS core-level and valence-band spectra were recorded for pristine and Ar{sup +}-ion bombarded surfaces of Tl{sub 2}PbSiS{sub 4}. The Tl{sub 2}PbSiS{sub 4} single crystal was found to be rather stable with respect to Ar{sup +}-ion irradiation. We have also measured the X-ray emission band depicting the energy distribution of mainly the S 3p states and compared it on a common energy scale with the XPS valence-band spectrum of the Tl{sub 2}PbSiS{sub 4} crystal. The above comparison indicates that the S 3p states contribute substantively in the upper portion of the valence band of Tl{sub 2}PbSiS{sub 4}, with their significant contributions in other portions of the valence-band region. - Highlights: • Chalcogenides of the quasi-ternary system Tl{sub 2}S–PbS–SiS{sub 2} were synthesized. • Two intermediate quaternary phases were discovered to exist (Tl

  3. The use of thallium diethyldithiocarbamate for mapping CNS potassium metabolism and neuronal activity: Tl+ -redistribution, Tl+ -kinetics and Tl+ -equilibrium distribution.

    Science.gov (United States)

    Wanger, Tim; Scheich, Henning; Ohl, Frank W; Goldschmidt, Jürgen

    2012-07-01

    The potassium (K(+)) analogue thallium (Tl(+)) can be used as a tracer for mapping neuronal activity. However, because of the poor blood-brain barrier (BBB) K(+) -permeability, only minute amounts of Tl(+) enter the brain after systemic injection of Tl(+) -salts like thallium acetate (TlAc). We have recently shown that it is possible to overcome this limitation by injecting animals with the lipophilic chelate complex thallium diethyldithiocarbamate (TlDDC), that crosses the BBB and releases Tl(+) prior to neuronal or glial uptake. TlDDC can thus be used for mapping CNS K(+) metabolism and neuronal activity. Here, we analyze Tl(+) -kinetics in the rodent brain both experimentally and using simple mathematical models. We systemically injected animals either with TlAc or with TlDDC. Using an autometallographic method we mapped the brain Tl(+) -distribution at various time points after injection. We show that the patterns and kinetics of Tl(+) -redistribution in the brain are essentially the same irrespective of whether animals have been injected with TlAc or TlDDC. Data from modeling and experiments indicate that transmembrane Tl(+) -fluxes in cells within the CNS in vivo equilibrate at similar rates as K(+) -fluxes in vitro. This equilibration is much faster than and largely independent of the equilibration of Tl(+) -fluxes across the BBB. The study provides further proof-of-concept for the use of TlDDC for mapping neuronal activity and CNS K(+) -metabolism. A theoretical guideline is given for the use of K(+) -analogues for imaging neuronal activity with general implications for the use of metal ions in neuroimaging. © 2012 The Authors. Journal of Neurochemistry © 2012 International Society for Neurochemistry.

  4. Plasma-assisted quartz-to-quartz direct bonding for the fabrication of a multilayered quartz template for nanoimprint lithography

    International Nuclear Information System (INIS)

    Lee, Jihye; Ali, Altun; Kim, Ki-don; Choi, Dae-guen; Choi, Jun-Hyuk; Jeong, Jun-ho; Kim, Jae-Hyun

    2010-01-01

    In this paper, a low-temperature plasma-assisted process is developed to realize a uniform, ultraviolet (UV) transparent and chemically inert quartz-to-quartz direct bonding. Two sets of pretests are performed in order to understand how the bond surface energy changes with the plasma exposure time and the wet etching of quartz, respectively. The developed technique is used to fabricate a multilayered quartz template for UV nanoimprint lithography (UV-NIL). The multilayered quartz template is fabricated by bonding a square piece of a standard quartz wafer, which is about 625 µm in thickness, to a wet-etched 6.35 mm thick quartz photomask plate. A fabricated multilayered template is loaded to the commercial UV-NIL tool Imprio(TM) 100, and NIL was performed successfully. The developed direct bonding technique makes it possible for standard quartz wafers, which are compatible with high-resolution semiconductor fabrication processes, to be utilized as the templates in commercial UV-NIL machines with enhanced mechanical stability.

  5. Development of Quartz Fiber Calorimetry

    CERN Multimedia

    2002-01-01

    % RD40 \\\\ \\\\ Very Forward Calorimeters (VFCs) in LHC detectors should cover the pseudorapidity range from $\\eta$~=~2.5 to at least $\\eta$~=~5 in order to compute missing transverse energy and for jet tagging. Operation at such high rapidity requires the use of a calorimetry technique that is very radiation resistant, fast and insensitive to radioactivity (especially to neutrons). This can be accomplished through the Quartz-Calorimeter~(Q-Cal) concept of embedding silica core fibers, that resist to the Gigarad radiation level, into an absorber. In this calorimeter the shower particles produce light through the Cherenkov effect generating a signal less than 10~ns in duration. Unique to this new technology the visible energy of hadronic showers has a transverse dimension nearly an order of magnitude smaller than that in conventional calorimeters, enabling precise spatial resolution, sharper isolation cuts and better jet recognition against the minimum bias events background. Last but not least, most radioactive ...

  6. TL studies of calcareous rocks of Danta area, North Gujarat

    International Nuclear Information System (INIS)

    Limaye, M.A.; Desai, S.J.; Murthy, K.V.R.; Joshi, T.R.

    1992-01-01

    The lithounits exposed around Danta in Banaskantha district of North Gujarat belong to Ajabgarh Group, the upper division of the Delhi super group. These rocks are intruded by syn to late kinematic basic rocks and by Erinpura granites of post Delhi age. The Ajabgarh group consists of pelitic and calcareous components. Mineralogically the pelitic rocks comprise cordierite, almandine garnet, k-feldspar, sillimanite, quartz and mica in variable proportions. The calcareous rocks are seen to contain dominantly calcite, scapolite, forsterite, sphene, k-feldspar. These mineral assemblages correspond to upper Amphibolite to lower Granulite facies of regional metamorphism. The chemistry of the calcareous rocks show predominance of CaO over MgO. The glow curves obtained from virgin samples (NTL) as well as artificial beta irradiated indicate glow peaks at 140 o C, 290 o C, 310 o C and 390 o C. The TL glow peak temperatures are in general agreement with those reported by Borsi and Rinaldi and Medlin. The pronounced peak at 390 o C and 290 o C are suggestive of their high irradiation sensitivity and also probably reflect variation in the Mn content of the rocks. (author). 9 refs., 16 tabs., 2 figs

  7. NaI(Tl) electron energy resolution

    CERN Document Server

    Mengesha, W

    2002-01-01

    NaI(Tl) electron energy resolution eta sub e was measured using the Modified Compton Coincidence Technique (MCCT). The MCCT allowed detection of nearly monoenergetic internal electrons resulting from the scattering of incident 662 keV gamma rays within a primary NaI(Tl) detector. Scattered gamma rays were detected using a secondary HPGe detector in a coincidence mode. Measurements were carried out for electron energies ranging from 16 to 438 keV, by varying the scattering angle. Measured HPGe coincidence spectra were deconvolved to determine the scattered energy spectra from the NaI(Tl) detector. Subsequently, the NaI(Tl) electron energy spectra were determined by subtracting the energy of scattered spectra from the incident source energy (662 keV). Using chi-squared minimization, iterative deconvolution of the internal electron energy spectra from the measured NaI(Tl) spectra was then used to determine eta sub e at the electron energy of interest. eta sub e values determined using this technique represent va...

  8. Quartz gauge response in ion radiation

    International Nuclear Information System (INIS)

    Taylor, P.E.; Gilbert, P.H.; Kernthaler, C.; Anderson, M.U.

    1995-01-01

    This paper describes recent work to make high quality quartz gauge (temporal and spatial) shock wave measurements in a pulsed ion beam environment. Intense ion beam radiation, nominally 1 MeV protons, was deposited into material samples instrumented with shunted quartz gauges adjacent to the ion deposition zone. Fluence levels were chosen to excite three fundamentally different material response modes (1) strong vapor, (2) combined vapor and melt phase and (3) thermoelastic material response. A unique quartz gauge design was utilized that employed printed circuit board (PCB) technology to facilitate electrical shielding, ruggedness, and fabrication at sign e meeting the essential one dimensional requirements of the characterized Sandia shunted quartz gauge. Shock loading and unloading experiments were conducted to evaluate the piezoelectric response of the coupled quartz gauge/PCB transducer. High fidelity shock wave profiles were recorded at the three ion fluence levels providing dynamic material response data for vapor, melt and solid material phases

  9. Determination of activation energies of K2YF5: Tb by the isothermal decay method

    International Nuclear Information System (INIS)

    Gallegos, A.A.; Azorin, J.; Khaidukov, M.

    2007-01-01

    the samples K 2 YF 5 : Tb 0.8% and K 2 YF 5 : Tb 0.99% which were subjected to isothermic decay treatment to temperatures of 373.15 K, 398.15 K and 423.15 K, making registration of the TL glow curve at different times of decay, the curves were studied by the 'phosphorescent' decay method. In this last dosimetric characterization was observed in the TL glow curves a marked one 'competition' among the visible traps, during the heating stage to two different heating ramps (10 C/s), for what became necessary to characterize by another dosimetric test suggested by the McKeever pattern and collaborators: Response to the dose. Of the competition among traps during heating stage Chen and collaborators predict that the response sample to the dose will not be lineal to 'big' absorbed doses (ITL α D 2 ). This charge transfer among traps stimulated during the heating stage can associate to an apparent thermal-transfer among trapper states. (Author)

  10. Electrochemically produced alumina as TL detector

    International Nuclear Information System (INIS)

    Osvay, M.

    1996-01-01

    The goal of this work was to compare the TL properties of various electrochemically produced alumina layers (E-AIO) in order to investigate the effect of the electrolyte and the Mg content on the alloys. It has been found that the TL sensitivity of oxidised layers is more influenced by the type of electrolyte, than by the composition of alloy. Hard oxide layer evolved in reduction electrolyte has rather different character compared to other alumina production investigated. The effect of reducing media seems to be very important during preparation of alumina layer. One of the advantages properties of E-AIO is, that it serve a promising method to increase the measuring range of TL method above 10 kGy as well. (author)

  11. Accidental and retrospective dosimetry using TL method

    International Nuclear Information System (INIS)

    Mesterházy, D.; Osvay, M.; Kovács, A.; Kelemen, A.

    2012-01-01

    Retrospective dosimetry is one of the most important tools of accidental dosimetry for dose estimation when dose measurement was not planned. In the affected area many objects can be applied as natural dosimeters. The paper discusses our recent investigations on various electronic components and common salt (NaCl) having useful thermoluminescence (TL) properties. Among materials investigated the electronic components of cell phones seem promising for retrospective dosimetry purposes, having high TL responses, proper glow curve peaks and the intensity of TL peaks vs. gamma dose received provided nearly linear response in the dose range of 10 mGy–1.5 Gy. - Highlights: ► Electronic components and common salt were investigated for accidental and retrospective dosimetry. ► SMD resistors seem promising for retrospective dosimetry purposes. ► Table salt can be used effectively for accidental dosimetry purposes, as well.

  12. Detailed α -decay study of 180Tl

    Science.gov (United States)

    Andel, B.; Andreyev, A. N.; Antalic, S.; Barzakh, A.; Bree, N.; Cocolios, T. E.; Comas, V. F.; Diriken, J.; Elseviers, J.; Fedorov, D. V.; Fedosseev, V. N.; Franchoo, S.; Ghys, L.; Heredia, J. A.; Huyse, M.; Ivanov, O.; Köster, U.; Liberati, V.; Marsh, B. A.; Nishio, K.; Page, R. D.; Patronis, N.; Seliverstov, M. D.; Tsekhanovich, I.; Van den Bergh, P.; Van De Walle, J.; Van Duppen, P.; Venhart, M.; Vermote, S.; Veselský, M.; Wagemans, C.

    2017-11-01

    A detailed α -decay spectroscopy study of 180Tl has been performed at ISOLDE (CERN). Z -selective ionization by the Resonance Ionization Laser Ion Source (RILIS) coupled to mass separation provided a high-purity beam of 180Tl. Fine-structure α decays to excited levels in the daughter 176Au were identified and an α -decay scheme of 180Tl was constructed based on an analysis of α -γ and α -γ -γ coincidences. Multipolarities of several γ -ray transitions deexciting levels in 176Au were determined. Based on the analysis of reduced α -decay widths, it was found that all α decays are hindered, which signifies a change of configuration between the parent and all daughter states.

  13. Geology and geochemistry of giant quartz veins from the ...

    Indian Academy of Sciences (India)

    Numerous younger thin quartz veins with somewhat similar orientation cut across the giant quartz .... Angular fragments of quartz are set in ... places along grain boundaries. ... Oxide values are in wt%, and trace element concentrations are.

  14. Non-monotonic dose dependence of the Ge- and Ti-centres in quartz

    International Nuclear Information System (INIS)

    Woda, C.; Wagner, G.A.

    2007-01-01

    The dose response of the Ge- and Ti-centres in quartz is studied over a large dose range. After an initial signal increase in the low dose range, both defects show a pronounced decrease in signal intensities for high doses. The model by Euler and Kahan [1987. Radiation effects and anelastic loss in germanium-doped quartz. Phys. Rev. B 35 (9), 4351-4359], in which the signal drop is explained by an enhanced trapping of holes at the electron trapping site, is critically discussed. A generalization of the model is then developed, following similar considerations by Lawless et al. [2005. A model for non-monotonic dose dependence of thermoluminescence (TL). J. Phys. Condens. Matter 17, 737-753], who explained a signal drop in TL by an enhanced recombination rate with electrons at the recombination centre. Finally, an alternative model for the signal decay is given, based on the competition between single and double electron capture at the electron trapping site. From the critical discussion of the different models it is concluded that the double electron capture mechanism is the most probable effect for the dose response

  15. Isotopic exchange in a neutron-irradiated mixed-valence compound: Tl3(I) Tl(III)Cl6

    International Nuclear Information System (INIS)

    Fernandez Valverde, S.; Duplatre, G.

    1977-01-01

    The initial distribution of Tl(I) and Tl(III) species, and its change on heating, have been investigated in solid thermal neutron-irradiated Th 4 Cl 6 . An initial ratio of 5/1 for 204 Tl(I)/ 204 Tl(III) is found and this remains constant for integral gamma-doses of 3 to 12 MRad. The variation of the 204 Tl(III) fraction with temperature is found identical to that observed in labelled Tl 4 Cl 6 for which a genuine isotopic exchange has previously been described. It is concluded that the recoil species are rapidly converted, after the recoil processes, into stable ions

  16. Brain SPECT with Tl-201 DDC

    International Nuclear Information System (INIS)

    Bruine, J.F. de.

    1988-01-01

    The development, animal and human experiments and the first clinical results of a new blood flow tracer thallium-201 diethyldithiocarbamate (Tl-201 DDC) are discussed for functional brain imaging with single-photon emission computed tomography (SPECT). 325 refs.; 43 figs.; 22 tabs

  17. (Tl, Sb) and (Tl, Bi) binary surface reconstructions on Ge(111) substrate

    Science.gov (United States)

    Gruznev, D. V.; Bondarenko, L. V.; Tupchaya, A. Y.; Yakovlev, A. A.; Mihalyuk, A. N.; Zotov, A. V.; Saranin, A. A.

    2018-03-01

    2D compounds made of Group-III and Group-V elements on the surface of silicon and germanium attract considerable attention due to prospects of creating III-V binary monolayers, which are predicted to hold advanced physical properties. In the present work, we have investigated two such systems, (Tl, Sb)/Ge(111) and (Tl, Bi)/Ge(111) using scanning tunneling microscopy, low energy electron diffraction observations and density-functional-theory calculations. In addition to the previously reported surface structures of 2D (Tl, Sb) and (Tl, Bi) compounds on Si(111), we found new ones, namely, √{ 7} × √{ 7} and 3 × 3. Formation processes and plausible models of their atomic arrangements are discussed.

  18. Quartz-Enhanced Photoacoustic Spectroscopy: A Review

    Science.gov (United States)

    Patimisco, Pietro; Scamarcio, Gaetano; Tittel, Frank K.; Spagnolo, Vincenzo

    2014-01-01

    A detailed review on the development of quartz-enhanced photoacoustic sensors (QEPAS) for the sensitive and selective quantification of molecular trace gas species with resolved spectroscopic features is reported. The basis of the QEPAS technique, the technology available to support this field in terms of key components, such as light sources and quartz-tuning forks and the recent developments in detection methods and performance limitations will be discussed. Furthermore, different experimental QEPAS methods such as: on-beam and off-beam QEPAS, quartz-enhanced evanescent wave photoacoustic detection, modulation-cancellation approach and mid-IR single mode fiber-coupled sensor systems will be reviewed and analysed. A QEPAS sensor operating in the THz range, employing a custom-made quartz-tuning fork and a THz quantum cascade laser will be also described. Finally, we evaluated data reported during the past decade and draw relevant and useful conclusions from this analysis. PMID:24686729

  19. Quartz-Enhanced Photoacoustic Spectroscopy: A Review

    Directory of Open Access Journals (Sweden)

    Pietro Patimisco

    2014-03-01

    Full Text Available A detailed review on the development of quartz-enhanced photoacoustic sensors (QEPAS for the sensitive and selective quantification of molecular trace gas species with resolved spectroscopic features is reported. The basis of the QEPAS technique, the technology available to support this field in terms of key components, such as light sources and quartz-tuning forks and the recent developments in detection methods and performance limitations will be discussed. Furthermore, different experimental QEPAS methods such as: on-beam and off-beam QEPAS, quartz-enhanced evanescent wave photoacoustic detection, modulation-cancellation approach and mid-IR single mode fiber-coupled sensor systems will be reviewed and analysed. A QEPAS sensor operating in the THz range, employing a custom-made quartz-tuning fork and a THz quantum cascade laser will be also described. Finally, we evaluated data reported during the past decade and draw relevant and useful conclusions from this analysis.

  20. Fabrication of a novel quartz micromachined gyroscope

    Science.gov (United States)

    Xie, Liqiang; Xing, Jianchun; Wang, Haoxu; Wu, Xuezhong

    2015-04-01

    A novel quartz micromachined gyroscope is proposed in this paper. The novel gyroscope is realized by quartz anisotropic wet etching and 3-dimensional electrodes deposition. In the quartz wet etching process, the quality of Cr/Au mask films affecting the process are studied by experiment. An excellent mask film with 100 Å Cr and 2000 Å Au is achieved by optimization of experimental parameters. Crystal facets after etching seriously affect the following sidewall electrodes deposition process and the structure's mechanical behaviours. Removal of crystal facets is successfully implemented by increasing etching time based on etching rate ratios between facets and crystal planes. In the electrodes deposition process, an aperture mask evaporation method is employed to prepare electrodes on 3-dimensional surfaces of the gyroscope structure. The alignments among the aperture masks are realized by the ABM™ Mask Aligner System. Based on the processes described above, a z-axis quartz gyroscope is fabricated successfully.

  1. Luminescence characteristics of quartz from Hsuehshan Range (Central Taiwan) and implications for thermochronometry

    International Nuclear Information System (INIS)

    Wu, Tzu-Shuan; Jain, Mayank; Guralnik, Benny; Murray, Andrew S.; Chen, Yue-Gau

    2015-01-01

    The mountain building processes in Taiwan are currently among the most rapid in the world. However, the spatial and temporal dynamics of this orogen are still poorly resolved within the <0.5 Ma timescale, reflecting methodological gaps in addressing young and rapid bedrock cooling by erosion. Optically Stimulated Luminescence (OSL) from quartz is an emerging thermochronometer that could potentially provide valuable low-temperature markers on a ∼0.1 Ma timescale. Here we study four meta-sandstone samples from the Hsuehshan Range in central Taiwan. We characterize the OSL from these samples in terms of feldspar contamination, saturation dose, signal components, and thermal stability. We conclude that the OSL is dominated by the fast component, and is therefore amenable to dose measurement using the SAR protocol. Based on the luminescence characteristics and ambient dose rate, we suggest that these samples may be valuable for evaluating recent cooling rates exceeding 360 ± 100 °C/Ma, in places where the alternative thermal scenarios (instantaneous cooling or prolonged isothermal storage) may be ruled out by external geological constraints. - Highlights: • Bedrock quartz with well-behaved luminescence characteristics are found in Taiwan. • Kinetic parameters for samples in this study are confirmed as typical quartz. • Quartz OSL-thermochronometer may work for cooling rate exceeding 360 ± 100 °C/Ma.

  2. Principles of Good Practice in SoTL

    Science.gov (United States)

    Felten, Peter

    2013-01-01

    For the Scholarship of Teaching and Learning (SoTL) to be understood as significant intellectual work in the academy, SoTL practitioners need to identify shared principles of good practice. While honoring the diversity of SoTL in its many forms across the globe, such principles can serve as a heuristic for assessing work in our field. These…

  3. Understand rotating isothermal collapses yet

    International Nuclear Information System (INIS)

    Tohline, J.E.

    1985-01-01

    A scalar virial equation is used to describe the dynamic properties of equilibrium gas clouds, taking into account the relative effects of surface pressure, rotation, self gravity and internal isothermal pressure. Details concerning the internal structure of the clouds are ignored in order to obtain a globalized analytical expression. The obtained solution to the equation is found to agree with the surface-pressure-dominated model of Stahler (1983), and the rotation-dominated model of Hayashi, Narita, and Miyama (1982). On the basis of the analytical expression of virial equilibrium in the clouds, some of the limiting properties of isothermal clouds are described, and a realistic starting model for cloud collapse is proposed. 18 references

  4. Activation analysis of thallium in urine using the 203Tl(n,2n) 202Tl reaction

    International Nuclear Information System (INIS)

    Korob, R.O.; Cohen, I.M.; Lage, M.; Baro, G.B.

    1976-04-01

    The method developed by the authors of thallium determination in human urine, based on the 203 Tl(n,2n) 202 Tl reaction followed by chemical separation and measurement of the produced 202 Tl by gamma spectrometry, is described. Its application in some cases of intoxication by thallium is reported. The advantages and limitations of the described technique are discussed. (author) [es

  5. Electron spin resonance and thermoluminescence in powder form of clear fused quartz: effects of grinding

    International Nuclear Information System (INIS)

    Ranjbar, A.H.; Durrani, S.A.; Randle, K.

    1999-01-01

    Clear fused quartz (CFQ) tubes were powdered either manually by using a mortar and pestle (for coarse production) or mechanically, using a micronising mill (for fine production). A high and multisignal electron spin resonance (ESR) background was found in the fine powder even after annealing it at 900 deg. C for 20 min. In the case of the coarse powder, the signal (ESR background) varied inversely with particle size and was quite high for particle sizes lower than 38 μm. In a subsidiary experiment, using fine SiO 2 powder (99.8% pure, with the particle size of ∼0.007 μm), manufactured by using flame hydrolysis, only a weak background signal was found. The 60 Co gamma-ray irradiated powders (∼22 Gy) were subjected to ESR analysis or thermoluminescence (TL) readout. The ESR intensity of the coarse powder varied directly with particle size. Thus, the intensity for a particle size of 20-38 μm was very low and almost the same as the unirradiated intensity. In TL readout the results were the opposite: the TL intensity of the coarse powder varied inversely with the particle size down to 38 μm, after which it decreased with decreasing particle size of the material. The fine powder, produced by grinding the CFQ tubes, was insensitive to gamma-rays (at least at doses of up to 50 Gy); but for the flame hydrolysis SiO 2 the situation was the opposite. The minimum detectable dose (MDD) for the CFQ in powder form using ESR was ∼2 Gy, which is ∼2 times higher than that for the bulk form, while the MDD for the powder using TL was ∼20 μGy, which is ∼2 times lower than that for the bulk form of the material

  6. Electron spin resonance and thermoluminescence in powder form of clear fused quartz: effects of grinding

    Energy Technology Data Exchange (ETDEWEB)

    Ranjbar, A.H. [Physics Department, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of); Durrani, S.A. [School of Physics and Space Research, University of Birmingham, Birmingham (United Kingdom); Randle, K. [School of Chemistry, University of Birmingham, Birmingham (United Kingdom)

    1999-02-01

    Clear fused quartz (CFQ) tubes were powdered either manually by using a mortar and pestle (for coarse production) or mechanically, using a micronising mill (for fine production). A high and multisignal electron spin resonance (ESR) background was found in the fine powder even after annealing it at 900 deg. C for 20 min. In the case of the coarse powder, the signal (ESR background) varied inversely with particle size and was quite high for particle sizes lower than 38 {mu}m. In a subsidiary experiment, using fine SiO{sub 2} powder (99.8% pure, with the particle size of {approx}0.007 {mu}m), manufactured by using flame hydrolysis, only a weak background signal was found. The {sup 60}Co gamma-ray irradiated powders ({approx}22 Gy) were subjected to ESR analysis or thermoluminescence (TL) readout. The ESR intensity of the coarse powder varied directly with particle size. Thus, the intensity for a particle size of 20-38 {mu}m was very low and almost the same as the unirradiated intensity. In TL readout the results were the opposite: the TL intensity of the coarse powder varied inversely with the particle size down to 38 {mu}m, after which it decreased with decreasing particle size of the material. The fine powder, produced by grinding the CFQ tubes, was insensitive to gamma-rays (at least at doses of up to 50 Gy); but for the flame hydrolysis SiO{sub 2} the situation was the opposite. The minimum detectable dose (MDD) for the CFQ in powder form using ESR was {approx}2 Gy, which is {approx}2 times higher than that for the bulk form, while the MDD for the powder using TL was {approx}20 {mu}Gy, which is {approx}2 times lower than that for the bulk form of the material.

  7. Microcomputer control of automated TL reader

    International Nuclear Information System (INIS)

    Bjarland, B.

    1980-01-01

    An automatic TL reader has been developed for use within a TLD based personal monitoring service. A 6800 based microcomputer is used for system control, operator communication, calibration and checking of reader operation, and for output of data. The dosimeter identity code is printed in human readable characters on the dosimeter card, and is read by using an optical character recognition unit. The code may include individual sensitivity correction coefficients for the TL chips on the card. The chips are heated with hot nitrogen gas and the thermoluminescence is recorded by a photomultiplier tube circuit, the gain and offset of which are continuously monitored and, when necessary, adjusted, to maintain calibration. The reader may operate in any of seven modes, i.e. reading modes for three types of dosimeters, semiautomatic modes for production of the three types of dosimeters, and a monitor mode. (Auth.)

  8. Tl and OSL on diopside crystal

    International Nuclear Information System (INIS)

    Cano, N.F.; Watanabe, S.; Mittani, J.C.R.; Yukihara, E.G.

    2006-01-01

    The diopside with chemical composition CaMgSi 2 O 6 is part of an important solid solution series of the pyroxene group. The mineral is commonly found in meteorites and it is an important rock forming mineral of medium and high grade metamorphic rocks which are rich in calcium. In the bibliography it is possible to found several studies on electron spin resonance (ESR), reflectance, etc. but not on thermoluminescence (TL) or optically stimulated luminescence (OSL). In the present work we studied diopside TL and OSL behaviour on natural and natural irradiated samples. The sample used in our study is a white coloured diopside provided by Mineracao Sao Judas located in Sao Paulo, Brazil. The X-Ray Fluorescence technique has shown high concentrations of SiO 2 (55.81 % mol), CaO (23.47 % mol), MgO (18.03 % mol), Al 2 O 3 (1.56 % mol), Fe 2 O 3 (0.53 % mol), K 2 O (0.44 % mol), TiO 2 (0.065 % mol), P 2 O 5 (0.026 % mol), and MnO (0.013 % mol). TL measurements on natural samples show four TL peaks at 160, 260, 360, and 450 C. After beta-irradiation an increment mainly in the low temperature peaks is observed. As for OSL measurements, low OSL signal was observed on natural samples using blue light stimulation and UV detection. The intensity of the signal was observed to increase with the irradiation dose. (Author)

  9. Measurement of conversion coefficients in 208Tl

    International Nuclear Information System (INIS)

    Wendling, F.

    1976-06-01

    A electron spectrometer composed by a Li drifted Si detector and a uniform magnetic field was constructed. The magnetic field is used to focus the electrons on the detector and to filter the other radiations. After the construction the instrument was calibrated in absolute eficience and was used together with a Ge(Li) spectrometer also calibrated, in the measurement of internal conversion coeficients of the 433 and 453 keV transitions in 208 Tl [pt

  10. Improving TL dosimetry for external radiotherapy

    International Nuclear Information System (INIS)

    Bustos, S.R.; Velez, G.; Rubio, M.

    1998-01-01

    Full text: In vivo thermoluminescence dosimetry (TLD) has always been one of the most accurate dosimetry method for external radiotherapy control, but the delay in the response is a well know drawback when it is applied. In this work we show some improvements and demonstrate that keeping the precision and accuracy of this technique, it is possible to obtain a response in few hours. Harshaw 4000 TL reader and LiF TLD-100 dosimeters, chips (3,1 x 3,1 x 0,9 mm 3 ) and rods (1 x 1 x 6 mm 3 ) have been used. The thermal treatment necessary to reuse the TLD is only 1h at 400 degree C, by using a glow curve analyser developed at the Ciemat (Spain), that allows a complete, prompt and precise identification of the individuals peaks. The dosimeters are periodically and individually calibrated. We also have study the factors contributing to the relation TL-dose like linearity, energy correction, directional response and fading. All those results are included into an Excel worksheet which automatically give us the dose resulting from the TL reading (peaks areas 4 and 5). The obtained uncertainty is better than 5%. The TLD already irradiated in radiotherapy institutions distant 30-40 Km from our centre can be read and analysed in about 3-4 hours. These facts render our methods rapid and allow a better control of radiotherapy treatment even if it is bi-fractionated. (author) [es

  11. Additive manufacturing of transparent fused quartz

    Science.gov (United States)

    Luo, Junjie; Hostetler, John M.; Gilbert, Luke; Goldstein, Jonathan T.; Urbas, Augustine M.; Bristow, Douglas A.; Landers, Robert G.; Kinzel, Edward C.

    2018-04-01

    This paper investigates a filament-fed process for additive manufacturing (AM) of fused quartz. Glasses such as fused quartz have significant scientific and engineering applications, which include optics, communications, electronics, and hermetic seals. AM has several attractive benefits such as increased design freedom, faster prototyping, and lower processing costs for small production volumes. However, current research into glass AM has focused primarily on nonoptical applications. Fused quartz is studied here because of its desirability for use in high-quality optics due to its high transmissivity and thermal stability. Fused quartz filaments are fed into a CO2 laser-generated molten region, smoothly depositing material onto the workpiece. Spectroscopy and pyrometry are used to measure the thermal radiation incandescently emitted from the molten region. The effects of the laser power and scan speed are determined by measuring the morphology of single tracks. Thin walls are printed to study the effects of layer-to-layer height. This information is used to deposit solid pieces including a cylindrical-convex shape capable of focusing visible light. The transmittance and index homogeneity of the printed fused quartz are measured. These results show that the filament-fed process has the potential to print transmissive optics.

  12. Thallium (Tl) sorption onto illite and smectite: Implications for Tl mobility in the environment

    Science.gov (United States)

    Martin, Loïc A.; Wissocq, Aubéry; Benedetti, M. F.; Latrille, Christelle

    2018-06-01

    Clay minerals play a relevant role in the transport and fate of trace elements in the environment. Though illite has been referred as an important Thallium (Tl) bearing phase in soils, mechanisms and affinity of thallium for clay minerals remain poorly known. This study investigated the sorption behavior of thallium as Tl(I) onto illite and smectite, two clay minerals occurring mainly in soils and sediments. Different sorption experiments were carried out under various pH conditions and Tl concentrations, in competition with sodium and calcium at a constant ionic strength of 0.01 mol L-1. Our results showed that illite displayed more affinity than smectite for thallium. With illite, the distribution coefficients (Kd in L kg-1) varied between 102.75 ± 0.17 and 104.0 ± 0.17 in Na solutions versus between 102.25 ± 0.17 and 103.0 ± 0.17 in Ca solutions, depending on pH. With smectite, Kd (in L kg-1) ranged between 102.50 ± 0.16 and 103.20 ± 0.16 and between 101.25 ± 0.16 and 101.95 ± 0.16 in Na and Ca solutions, respectively. Sorption behavior was described with the Multi-Site Ion Exchanger model and selectivity coefficients with respect to protons were calculated for the first time. In all cases, independently of clay mineral and background electrolyte, low capacity but highly reactive sites were dominant in thallium uptake, highlighting Tl affinity for those sites. Moreover, the exchangeable and reversible interactions between Tl+ and clays reactive sites suggested that in changing conditions, thallium could be released in solution. The role of clay minerals in thallium environmental cycle is evident and confirmed illite to be a dominant Tl bearing phase, in some environment competing with manganese oxides. Compared to others Tl bearing mineral phases, clays are ranked as follows: MnO2 > illite > smectite ∼ ferrihydrite ≥ Al2O3 ∼ goethite > SiO2. Finally, over the three monovalent cations (Tl, Rb, Cs) Tl is the one less sorbed on illite independently of

  13. Using the OSL single-aliquot regenerative-dose protocol with quartz extracted from building materials in retrospective dosimetry

    DEFF Research Database (Denmark)

    Bøtter-Jensen, L.; Solongo, S.; Murray, A.S.

    2000-01-01

    We report on the application of the single-aliquot regenerative-dose (SAR) protocol to the optically stimulated luminescence signal from quartz extracted from fired bricks acid unfired mortar in retrospective dosimetry. The samples came from a radioactive materials storage facility, with ambient...... dose rates of about 0.1 mGy/h. A detailed dose-depth profile was analysed from one brick, and compared with dose records from area TL dosemeters. Small-aliquot dose-distributions were analysed from the mortar samples; one associated with the exposed brick, and one from a remote site exposed only...

  14. Ceramics baking temperature influence on the dosimetric parameters essential in TL dating

    International Nuclear Information System (INIS)

    Krumpschmid, K.R.

    1986-11-01

    Thermoluminescence in quartz is used for dating of ceramics. The main problem is the 'intercept', i.e. the deviation from linearity in the relationship thermoluminescence versus absorbed dose of natural radiation. This deviation is most probably dependent on the fabrication method of the ceramics. In the present work the hypothesis is tested that the most important parameter, in this respect, is the baking temperature. Four types of ceramic bricks were fabricated, with four burning cycles of end temperatures of 550 0 C, 650 0 C, 900 0 C and 1200 0 C respectively, then irradiated and finally underwent the TL-procedure. The results are discussed with regard of the maximum of glow curve, intensity, fading, sensitivity to beta radiation and to additional alpha radiation and the intercept. (qui)

  15. Formation of cogenetic quartz and nepheline syenites

    Science.gov (United States)

    Foland, K. A.; Landoll, J. D.; Henderson, C. M. B.; Chen, Jiangfeng

    1993-02-01

    Understanding the processes involved in the formation of cogenetic silica-undersaturated and silica-saturated felsic rocks in alkaline igneous complexes has been a long-standing enigma because of constraints imposed by phase equilibria relationships. This problem is discussed in general drawing upon relationships at two magmatic centers: Marangudzi in Zimbabwe and Mt. Brome in Quebec, Canada. At each locality, cogenetic quartz and nepheline syenites appear to be derived from common critically undersaturated magmas. Strontium and neodymium isotope results indicate that quartz syenites bear the signatures of substantial amounts of crustal assimilation whereas nepheline syenites lack or display lesser effects. In the model outlined, quartz syenite melts develop from felsic silica undersaturated magmas by assimilation of granitic crust coupled with fractional crystallization whereas nepheline syenites form without large amounts of contamination. This model is compatible with the constraints imposed by phase equilibria.

  16. Radiation resistivity of quartz core fiber, 3

    International Nuclear Information System (INIS)

    Gozen, Toshikazu; Suzuki, Toshiya; Hayashi, Tokuji; Tanaka, Hiroyuki; Okamoto, Shinichi.

    1985-01-01

    Radiation resistance characteristics were evaluated for a multi-mode quartz core fiber in low temperature region together with photobleaching effect depending on the incident light power and dependency on the wavelength of measuring rays. This report describes the results of the abovementioned items and the next step study of trial manufacturing of a pure-quartz single-mode fiber for the employment of longer wavelength rays and greater capacity in light transmission communication system. Quartz core fiber specimens were irradiated by 60 Co γ-ray source at -55 deg C to 80 deg C in a constant temperature bath and light transmission loss was determined under irradiation conditions. Low temperature characteristics were superior in an MRT (modified rod-in tube) pure quartz fiber prepared by the plasma method as compared to VAD quartz and Ge-GI fibers. The MRT fiber showed better quality than the Ge-GI fiber also in the photobleaching effect examination. As for the wavelength dependency, light transmission loss of the MRT fiber was less than that of the Ge-GI fiber. The MRT fiber also showed a superior quality in the wide range of irradiation temperatures. Based on the above-mentioned understandings, a pure-quartz single-mode fiber of both BF 3 -doped and F-doped cladding types were developed for longer wavelengths uses. The fibers could attain low light transmission loss of less than 1.0 dB/km at 1.30 μm of wavelength. At the standpoint of radiation resistivity, the BF 3 -doped fiber was found superior. (Takagi, S.)

  17. New colour centres in KCl:(Tl+ + Ca2+) and KCl:(Tl+ + Sr2+) crystals

    International Nuclear Information System (INIS)

    Ioan, A.; Topa, V.; Giurgea, M.

    1978-01-01

    Electrolytic colouring under unusual conditions (low temperature and high voltage) gives rise to the appearance of three new absorption bands peaking at 3.2, 2.5, and 1.7 eV and at 2.8, 2.1, and 1.5 eV in KCl:(Tl + + Ca 2+ ) and in KCl:(Tl + + Sr 2+ ) single crystals, respectively. The modifications of the absorption spectra of the coloured crystals induced by the application of a reversed electric field at the colouring temperature or by heat treatment are investigated. It is likely that the colour centre responsible for the new absorption bands is an aggregate centre which, besides an Tl - -complex, contains also at least an Ca(Sr) ion, a trapped electron, and an anionic vacancy. (author)

  18. Construction of simple quartz crystal microbalance

    Energy Technology Data Exchange (ETDEWEB)

    Ristov, Milcho [Center of Energy, Informatics and Materials of the Macedonian Academy fo Science and Arts, Skopje (Macedonia, The Former Yugoslav Republic of); Mitrevski, Mitre [Institute of Physics, Faculty of natural Science and Mathematics, Ss Cyril and Methodius University, Skopje (Macedonia, The Former Yugoslav Republic of)

    2003-07-01

    A very simple Quartz Crystal Microbalance (QCM) was constructed for the measurement of thickness of chemically deposited thin films. QCM consisted of two active elements: one dual-gate MOSFET and one bipolar transistor, and as usually two AT-cut quartz crystal. The beat frequency oscillation generated as a result of loading of the sensor crystal by the deposited thin film, was measured by HP-multimeter, set as a low frequency meter. The sensitivity was found to be high and satisfactory for the study of growth rate of thin films, mainly deposited by methods of chemical deposition.

  19. Construction of simple quartz crystal microbalance

    International Nuclear Information System (INIS)

    Ristov, Milcho; Mitrevski, Mitre

    2002-01-01

    A very simple Quartz Crystal Microbalance (QCM) was constructed for the measurement of thickness of chemically deposited thin films. QCM consisted of two active elements: one dual-gate MOSFET and one bipolar transistor, and as usually two AT-cut quartz crystal. The beat frequency oscillation generated as a result of loading of the sensor crystal by the deposited thin film, was measured by HP-multimeter, set as a low frequency meter. The sensitivity was found to be high and satisfactory for the study of growth rate of thin films, mainly deposited by methods of chemical deposition.

  20. Estimating Quartz Reserves Using Compositional Kriging

    Directory of Open Access Journals (Sweden)

    J. Taboada

    2013-01-01

    Full Text Available The aim of this study was to determine spatial distribution and volume of four commercial quartz grades, namely, silicon metal, ferrosilicon, aggregate, and kaolin (depending on content in impurities in a quartz seam. The chemical and mineralogical composition of the reserves in the seam were determined from samples collected from outcrops, blasting operations, and exploratory drilling, and compositional kriging was used to calculate the volume and distribution of the reserves. A more accurate knowledge of the deposit ensures better mine planning, leading to higher profitability and an improved relationship with the environment.

  1. Copper interactions in TlCu7S4 and TlCu7Se4

    International Nuclear Information System (INIS)

    Noren, L.; Delaplane, R.G.; Berger, R.

    1999-01-01

    Complete text of publication follows. The copper chalcogenides ACu 7 S 4 (A=NH 4 + , Tl + , Rb + ) are quasi-one-dimensional metals at ambient and higher temperatures which is due to the high mobility of copper in these structures. TlCu 7 S 4 and TlCu 7 Se 4 are isostructural compounds, space group I4/m, which can be described on the basis of a TlX 8 cube with two different Cu sites, Cu(1) and Cu(2). Cu(2)-Cu(2) zigzag chains run along the c axis with only 3/4 occupation of the Cu(2) sites. However, these two compounds differ in behaviour on cooling. The sulphide shows a polymorphic first-order transition to the CsAg 7 S 4 type (P4/n) owing to ordering of the vacancies in the Cu(2)-Cu(2) chains. In order to study the nature of the Cu(2) order/disorder in the two title compounds, a series of neutron diffraction measurements (both Bragg and diffuse scattering) were made at several temperatures from 40 to 713 K on the instrument SLAD at Studsvik. The structure at each temperature was modelled using RMC techniques. The resulting configuration show that as the temperature increases, there is a marked increase in the mobility of the Cu atoms in the Cu(2)-Cu(2) chains for TlCu 7 S 4 but not for TlCu 7 Se 4 . This is due to the initial difference in the Cu(2)-Cu(2) distances, only 2.2A for the thiocuprate, but 2.7A in the selenocuprate which explains the relative ease for Cu(2) ordering in the latter case. (author)

  2. Insight on a novel layered semiconductors: CuTlS and CuTlSe

    Energy Technology Data Exchange (ETDEWEB)

    Aliev, Ziya S., E-mail: ziyasaliev@gmail.com [Institute of Catalysis and Inorganic Chemistry, ANAS, H.Javid ave. 113, AZ1143 Baku (Azerbaijan); Institute of Physics, ANAS, H.Javid ave. 131, AZ1143 Baku (Azerbaijan); Donostia International Physics Center (DIPC), 20080 San Sebastian (Spain); Zúñiga, Fco. Javier [Departamento de Física de la Materia Condensada, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao (Spain); Koroteev, Yury M. [Institute of Strength Physics and Materials Science, Russian Academy of Sciences, Siberian Branch, 634055 Tomsk (Russian Federation); Tomsk State University, Tomsk, 634050 (Russian Federation); Breczewski, Tomasz [Departamento de Física de la Materia Condensada, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao (Spain); Babanly, Nizamaddin B. [Institute of Catalysis and Inorganic Chemistry, ANAS, H.Javid ave. 113, AZ1143 Baku (Azerbaijan); Amiraslanov, Imamaddin R. [Institute of Physics, ANAS, H.Javid ave. 131, AZ1143 Baku (Azerbaijan); Politano, Antonio [Department of Physics, University of Calabria, 87036 Rende (CS) (Italy); Madariaga, Gotzon [Departamento de Física de la Materia Condensada, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao (Spain); Babanly, Mahammad B. [Institute of Catalysis and Inorganic Chemistry, ANAS, H.Javid ave. 113, AZ1143 Baku (Azerbaijan); and others

    2016-10-15

    Single crystals of the ternary copper compounds CuTlS and CuTlSe have been successfully grown from stoichiometric melt by using vertical Bridgman-Stockbarger method. The crystal structure of the both compounds has been determined by powder and single crystal X-Ray diffraction. They crystallize in the PbFCl structure type with two formula units in the tetragonal system, space group P4/nmm, a=3.922(2); c=8.123(6); Z=2 and a=4.087(6); c=8.195(19) Å; Z=2, respectively. The band structure of the reported compounds has been analyzed by means of full-potential linearized augmented plane-wave (FLAPW) method based on the density functional theory (DFT). Both compounds have similar band structures and are narrow-gap semiconductors with indirect band gap. The resistivity measurements agree with a semiconductor behavior although anomalies are observed at low temperature. - Graphical abstract: The crystal structures of CuTl and CuTlSe are isostructural with the PbFCl-type and the superconductor LiFeAs-type tetragonal structure. The band structure calculations confirmed that they are narrow-gap semiconductors with indirect band gaps of 0.326 and 0.083 eV. The resistivity measurements, although confirming the semiconducting behavior of both compounds exhibit unusual anomalies at low temperatures. - Highlights: • Single crystals of CuTlS and CuTlSe have been successfully grown by Bridgman-Stockbarger method. • The crystal structure of the both compounds has been determined by single crystal XRD. • The band structure of the both compounds has been analyzed based on the density functional theory (DFT). • The resistivity measurements have been carried out from room temperature down to 10 K.

  3. Adsorption of tetrabutylammonium cations on negatively charged surfaces of the Hg, Ga, In-Ga, Tl-Ga electrodes

    International Nuclear Information System (INIS)

    Damaskin, B.B.; Baturina, O.A.; Vykhodtseva, L.N.; Emets, V.V.; Kazarinov, V.E.

    1999-01-01

    The differential capacitance curves in the 0.05M Na 2 SO 4 + [(C 4 H 9 ) 4 N]BF 4 aqueous solutions on the electrodes of mercury gallium and also of the In-Ga and Tl-Ga alloys are obtained. The adsorption parameters of the tetrabutylammonium cations on each of the electrodes within the frames of two parallel condensers model, supplemented by the Frumkin isotherm are calculated. The conclusion is made that different adsorption behaviour of the (C 4 H 9 ) 4 N + cations on the gallium subgroup metals by the electrodes high negative charges is related to nonuniform electrochemical work of the output electrons [ru

  4. Tl-201 per rectum scintigraphy in chronic liver disease: assessment of Tl-201 uptake indices

    International Nuclear Information System (INIS)

    Moon, Won Jin; Choi, Yun Young; Cho, Suk Shin; Lee, Min Ho

    1999-01-01

    Heart to liver ratio on Tl-201 per rectal scintigraphy (shunt index) is known to be useful in the assessment of portal systemic shunt. We assessed Tl-201 uptake pattern and early liver/heart uptake rate of Tl-201 and correlated with shunt index in patients with chronic active hepatitis (CAH) and liver cirrhosis (LC). Fifty eight patients with biopsy-proven chronic liver disease (35 with CAH, 23 with LC) underwent Tl-201 per rectum scintigraphy after instillation of 18.5 MBq of Tl-201 into the upper rectum. We evaluated hepatic uptake (type 1: homogeneous, 2: inhomogeneous segmental, 3: inhomogeneous nonsegmental) and extrahepatic uptake of spleen, heart and kidney (grade 0: no uptake, 1: less than liver, 2: equal to liver, 3: greater than liver). We measured the early liver/heart uptake rate (the slope of the liver to heart uptake ratio for 10 mim) and shunt index (heart to liver uptake ratio). Tl-201 uptake pattern and early liver/heart uptake rate of Tl-201 was correlated with the pathologic diagnosis and shunt index. Hepatic uptake patterns of type 1 and 2 were dominant in CAH (CAH: 27/35, LC: 8/23), and type 3 in LC (CAH: 8/35, LC: 15/23)(p<0.005). The grades of extrahepatic uptake were higher in LC than in CAH (spleen: p<0.001, other soft tissue: p<0.005). The early liver/heart uptake rate of CAH (0.110±0.111) was significantly higher than that of LC (0.014±0.090)(p<0.001). The sensitivity and specificity of the early liver/heart uptake rate were 77.7% and 67.7% in differentiating LC from CAH. There was negative correlation between early liver/heart uptake rate and shunt index (r=-0.3347, p<0.01). Hepatic and extrahepatic uptake pattern and early liver/heart uptake rate on Tl-201 per rectum scintigraphy are useful in the assessment of portal systemic shunt in patients with chronic liver disease

  5. Room temperature isotherms for Mo and Ni

    International Nuclear Information System (INIS)

    Masse, J.L.

    1986-11-01

    Isotherms at room temperature for Mo and Ni are proposed. They are of three types: BIRCH, KEANE and BORN-MIE. The adjustable constants appearing in these isotherms have been determined from experimental quantities at zero pressure. An evaluation of the limit of (δB T /δP) T as P #-> # ∞, where B T is the isothermal bulk modulus, has been also used. These three isotherms obtained for Mo and Ni are compared with isotherms derived from shock-wave data according to the PRIETO's model. There is a good agreement between these and these derived from shock-wave data. The three isotherms proposed for Mo and Ni can be considered as valid until pressures of several B To , where B To is the bulk modulus B T at P = o [fr

  6. TL and radiocarbon dating of neolithic sepultures from Sudan: intercomparison of results

    International Nuclear Information System (INIS)

    Guibert, P.; Ney, C.; Bechtel, F.; Schvoerer, M.; Geus, F.

    1994-01-01

    Thermoluminescence dating of a set of 29 pottery sherds excavated at the neolithic sites of El Kadada and El Ghaba (near Shendi, Central Sudan) was carried out at Bordeaux University. The archaeological dose was measured using the fine grain technique. The annual dose was determined by analytical techniques (neutron activation analysis, ICP spectrometry, XRF, low background gamma spectrometry) and by ''on-site'' measurements of the environmental radioactivity (gammametry). The crystalline inclusions of the samples were characterized by optical microscopy and cathodoluminescence: the TL minerals mainly consist of quartz and K-feldspar crystals. In some cases, radioactive inclusions of zircons and monazites are observed. The TL and the radiocarbon dates show a good agreement, verifying the validity of the radiocarbon ages which were suspected to be too old because of the nature of the dated material (shells). Taking into account all the chronological data, it is shown that El Ghaba and El Ghaba necropolis were used respectively within the 4800-3300 B.C. and 4200-3000 B.C. date-ranges for neolithic cultures, the occupation of El Kadada starting five or six centuries later than El Ghaba. (Author)

  7. 207Pb and 205Tl NMR on Perovskite Type Crystals APbX3 (A = Cs, Tl, X = Br, I)

    Science.gov (United States)

    Sharma, Surendra; Weiden, Norbert; Weiss, Alarich

    1987-11-01

    By 205Tl and 207Pb NM R the chemical shift in polycrystalline samples of binary halides AX, BX2 and ternary halides ABX3 (A = Cs, Tl; B = Pb; X = Br, I) was studied at room temperature. The chemical shift tensors δ ( 205Tl) and δ (207Pb) were determined in magnitude and orientation on single crystals of the orthorhombic TlPbI3. The components of the δ(205Tl) tensor are δx (205Tl) || a = 611ppm; δy (205Tl) || b = 680 ppm; δZ(205Tl) || c = 1329 ppm; δiso(205Tl) = 873.3 ppm (with respect to 3.4 molar aqueous solution of TlOOCCH3). The chemical shift tensor of 207Pb in TlPbI3 shows two orientations. One of them is: δx (207Pb) = 3760 ppm, inclined 30° from b towards c, δy(207Pb) || a = 3485 ppm, δz(207Pb) = 2639 ppm inclined 120° from b towards c. δiso(207Pb) = 3295 ppm (with respect to saturated aqueous solution of Pb(NO3)2). The results are discussed with respect to the crystal structure and a model to explain orientation and anisotropy of the tensors δ(205Tl) and δ(207Pb) in TlPbI3 is proposed. In the system CsPbBr3-x Ix δ(207Pb) was studied on polycrystalline samples. The chemical shift increases with increasing x and negative excess shift is observed.

  8. Resetting of Quartz OSL (optically stimulated luminescence) Signals by Frictional Heating in Experimentally Sheared Gouges at Seismic Slip Rates.

    Science.gov (United States)

    Kim, J. H.; Choi, J. H.; Chauhan, N.; Lee, S.; Hirose, T.; Ree, J. H.

    2014-12-01

    ) there was not enough to empty the main OSL traps (i.e. 325 °C TL traps), which is supported by T (~250 °C) measured at the stationary side with thermocouples. Our results suggest that frictional heat during seismic events reset 'geologic clocks' of fault rocks and OSL signals in quartz from gouges in natural fault zones can be used to constrain the age of seismic events.

  9. Intrinsic thermoluminescence of NaCl:Tl in UV dosimetry

    International Nuclear Information System (INIS)

    Barghare, S.P.; Joshi, R.V.; Joshi, T.R.; Kathuria, S.P.

    1982-01-01

    NaCl:Tl(T) phosphor is found to have high intrinsic thermoluminescence (TL) sensitivity to 253.7 nm UV-radiation. The dosimetric glow peak II grows sublinearly with increase in UV dose in the range 10 3 to 10 6 JM -2 . The other requirements of an efficient dosimeter material such as high storage stability, matching of the spectral response of detector tube and TL-emission from phosphor, reproducibility, desirable size and shape, easy availability in powder, pellet and crystal forms at cheaper rates, and repeated re-usability of the same phosphor without much difficulty, etc., are additional factors which strengthen the claim of NaCl:Tl(T) phosphor as UV dosimetric material. It is proposed that present NaCl:Tl(T) material is suitable TL-phosphor for UV dosimetry in the range 10 3 to 10 6 JM -2 . (author)

  10. Improvements in the Tl dosimetry for Radiotherapy

    International Nuclear Information System (INIS)

    Bustos, S.; Velez, G.; Rubio, M.

    1998-01-01

    The thermoluminescent dosimetry (TLD) in vivo has been demonstrated to be one of the most reliable for the control of radiotherapeutic treatments, but the delay in the response is the main disadvantage in its applicability. In this work are presented important improvements and it is demonstrated that maintaining the accuracy and reliability of the technique, it is possible to accelerate the response times at a few hours. To realize this work is utilized a lecturer Harshaw 4000, dosemeters LiF-TLD-100 chips (3.1 x 3.1 x 0.89 mm 3 ) and rods (1 x 1 x 6 mm 3 ). With the implementation of a glow curve analysis program developed in CIEMAT, its obtained a Tl peaks separation in such manner rapid and accurate, by that the thermal treatment of dosemeters may be reduced at one unique annealing pre-irradiation for 1 hr at 400 Centigrade. It is realized a periodical and individual calibration of the TLD and a study of the factors which influencing the ratio Tl signal-dose as linearity, correction by energy, directional response and pride of Tl signal. the results of this study are introducing in a calculation list specially designed and which allows to obtain absorbed dose by TLD starting of the dates (dosimetric peaks area) which appear of the glow curves analysis. The dose is obtained with an accuracy less than 5 %. The dosemeters already irradiated (in vivo) are analysed and informed in only four hours, allowing a greater control of the treatment and a correction of the possible errors for the next session, still in bi fractional treatments. The method implemented results thus accurate, rapid and reliable. (Author)

  11. Data Acquisition System for Quartz Crystal Microbalances

    Directory of Open Access Journals (Sweden)

    Kleber Romero Felizardo

    2006-02-01

    Full Text Available This work presents a data acquisition system used in a mass sensor: quartz crystal microbalance. This system reads the frequency of this sensor along the time and sends the collected data to the computer through a serial interface.

  12. The TL dating of ancient porcelain

    International Nuclear Information System (INIS)

    Leung, P.L.; Stokes, M.J.; Wang Weida; Xia Junding; Zhou Zhixin

    1997-01-01

    The age determination of ancient porcelain using the pre-dose technique in TL dating was reported. The variation of beta dose with depth below the surface of the porcelain slice, the thermal activation characteristic (TAC) for 110 degree C peak, the measurement of paleodose and the estimation of annual dose were studied. The results show that this technique is suitable for authenticity testing of ancient porcelain, but both accuracy and precision for porcelain dating are worse than those for pottery, because porcelain differs from pottery on composition, structure and firing temperature. Besides, some complicated factors in the pre-dose technique would be the possible cause of the greater errors

  13. Prediction of Phase Separation of Immiscible Ga-Tl Alloys

    Science.gov (United States)

    Kim, Yunkyum; Kim, Han Gyeol; Kang, Youn-Bae; Kaptay, George; Lee, Joonho

    2017-06-01

    Phase separation temperature of Ga-Tl liquid alloys was investigated using the constrained drop method. With this method, density and surface tension were investigated together. Despite strong repulsive interactions, molar volume showed ideal mixing behavior, whereas surface tension of the alloy was close to that of pure Tl due to preferential adsorption of Tl. Phase separation temperatures and surface tension values obtained with this method were close to the theoretically calculated values using three different thermodynamic models.

  14. Lunar ash flows - Isothermal approximation.

    Science.gov (United States)

    Pai, S. I.; Hsieh, T.; O'Keefe, J. A.

    1972-01-01

    Suggestion of the ash flow mechanism as one of the major processes required to account for some features of lunar soil. First the observational background and the gardening hypothesis are reviewed, and the shortcomings of the gardening hypothesis are shown. Then a general description of the lunar ash flow is given, and a simple mathematical model of the isothermal lunar ash flow is worked out with numerical examples to show the differences between the lunar and the terrestrial ash flow. The important parameters of the ash flow process are isolated and analyzed. It appears that the lunar surface layer in the maria is not a residual mantle rock (regolith) but a series of ash flows due, at least in part, to great meteorite impacts. The possibility of a volcanic contribution is not excluded. Some further analytic research on lunar ash flows is recommended.

  15. Instabilities of isothermal liquid films

    International Nuclear Information System (INIS)

    Solesio, J.N.

    1977-04-01

    The integral forms of the mass and linear momentum balances are given for a two-phase flow system with surface tension and without material surface properties. The instantaneous local laws for each phase and the jump conditions for the interface are derived from these balance laws. Then, these laws are systematically simplified by means of dimensional analysis for an isothermal liquid film flowing down a plane. The stability studies of films are critically reviewed. The different methods are divided into two groups: the first one deals with the global approach, the second one with the perturbation theory. This group includes a new technique based upon the method of quadrature by differentiation. Finally, the different methods are compared [fr

  16. Using optically stimulated electrons from quartz for the estimation of natural doses

    DEFF Research Database (Denmark)

    Ankjærgaard, Christina; Murray, A.S.; Denby, Phil M.

    2009-01-01

    A flow-through Geiger-Müller pancake electron detector attachment has been fitted to a standard Risø TL/OSL reader enabling optically stimulated electrons (OSE) to be measured simultaneously with optically stimulated luminescence (OSL). Using this detector, OSE and OSL measurements from natural......, a dose recovery test shows that OSE can successfully recover a laboratory dose of 300 Gy given before any laboratory thermal treatment, for preheating temperatures between 160 and 260 °C. Furthermore, for the first time natural OSE decay curves are detected and these signals are used to estimate a burial...... dose using the single-aliquot regenerative-dose (SAR) procedure. Finally, a comparative study of the equivalent doses estimated using both OSE and OSL from 10 quartz samples are presented, and it is shown that OSE has a significant potential in retrospective dosimetry....

  17. Characterization of cartilaginous tumors with 201Tl scintigraphy

    International Nuclear Information System (INIS)

    Higuchi, Takahiro; Taki, Junichi; Sumiya, Hisashi; Kinuya, Seigo; Nakajima, Kenichi; Tonami, Norihisa

    2005-01-01

    Histological diagnosis and grading of cartilaginous tumors are closely correlated with patient prognosis; consequently, they are essential elements. We attempted to clarify the characteristics of 201 Tl uptake in various histological types of cartilaginous tumors and to assess its clinical value. Twenty-two cases with histologically proven cartilaginous tumors (3 enchondromas, 15 conventional chondrosarcomas (grade I=9, II=5, III=1), 3 mesenchymal chondrosarcomas, and 1 de-differentiated chondrosarcoma) were examined retrospectively. Planar 201 Tl images were recorded 15 mm following intravenous injection of 201 Tl (111 MBq). 201 Tl uptake in the tumor was evaluated visually employing a five-grade scoring system: 0=no appreciable uptake, 1=faint uptake above the background level, 2=moderate uptake, 3=intense uptake but lower than heart uptake and 4=uptake higher than heart uptake. 201 Tl uptake scores were 0 in 3 of 3 enchondromas, 9 of 9 grade I, and 4 of 5 grade II conventional chondrosarcomas. 201 Tl uptake scores were 1 among 1 of 5 grades II and a grade III conventional chondrosarcoma. Mesenchymal chondrosarcoma and de-differentiated chondrosarcoma displayed 201 Tl uptake scores of 2 or 3. Absence of elevated 201 Tl uptake in cartilaginous tumors was indicative of enchondroma or low-grade conventional chondrosarcoma. However, in instances in which 201 Tl uptake is obvious, high-grade chondrosarcoma or variant types should be considered. (author)

  18. Methods, qualitative and quantitative evaluations of 201Tl myocardial scintiscans

    International Nuclear Information System (INIS)

    Buell, U.; Kleinhans, E.; Klepzig, M.; Seiderer, M.; Strauer, B.E.

    1981-01-01

    Exercise 201 Tl myocardial scintiscanning is a technique used to supplement exercise electrocardiography. The procedure employed should be identical to the standard procedure of electrocardiography. If the coronary disease has already been established by coronary angiography and kineventriculography, 201 Tl examinations should be carried out before surgery in order to determine the ''regional functional reserve''. Visual evaluations of the 201 Tl scintiscans should be supplemented by quantification methods. Quantification is also required between 201 Tl examination and surgery and to assure constant diagnostic accuracy in case of examination by different examiners. (orig./MG) [de

  19. NaI(Tl) response functions

    International Nuclear Information System (INIS)

    Vega C, H. R.; Ortiz R, J. M.; Benites R, J. L.; De Leon M, H. A.

    2015-09-01

    The response functions of a NaI(Tl) detector have been estimated using Monte Carlo methods. Response functions were calculated for monoenergetic photon sources (0.05 to 3 MeV). Responses were calculated for point-like sources and for sources distributed in Portland cement cylinders. The responses were used to calculate the efficiency functions in term of photon energy. Commonly, sources used for calibration are point-like, and eventually sources to be measured have different features. In order to use the calibrated sources corrections due to solid angle, self-absorption and scattering, must be carried out. However, some of these corrections are not easy to perform. In this work, the calculated responses were used to estimate the detector efficiency of point-like sources, and sources distributed in Portland type cement. Samples of Portland paste were prepared and were exposed to photoneutrons produced by a 15 MV linac. Some of the elements in the cement were activated producing γ-emitting radionuclides that were measured with a NaI(Tl) gamma-ray spectrometer, that was calibrated with point-like sources. In order to determine the specific activity in the induced radioisotopes calculated efficiencies were used to make corrections due to the differences between the solid angle, photon absorption and photon scattering in the point-like calibration sources and the sources distributed in cement. During the interaction between photoneutrons and the cement samples three radioisotopes were induced: 56 Mn, 24 Na, and 28 Al. (Author)

  20. THERMODYNAMICS AND ADSORPTION ISOTHERMS FOR THE ...

    African Journals Online (AJOL)

    BAFFA

    data were tested using Freundlich and Langmuir adsorption isotherms. The values of the numeric constants ... Keywords: Adsorbate, Adsorbent, Adsorption isotherms, Maize cob, Thermodynamics. INTRODUCTION. Maize (Zea mays) ... several times with water, air – dried and ground to. 850μm particle size and finally kept ...

  1. [Tl(III)(dota)](-): An Extraordinarily Robust Macrocyclic Complex.

    Science.gov (United States)

    Fodor, Tamás; Bányai, István; Bényei, Attila; Platas-Iglesias, Carlos; Purgel, Mihály; Horváth, Gábor L; Zékány, László; Tircsó, Gyula; Tóth, Imre

    2015-06-01

    The X-ray structure of {C(NH2)3}[Tl(dota)]·H2O shows that the Tl(3+) ion is deeply buried in the macrocyclic cavity of the dota(4-) ligand (1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetate) with average Tl-N and Tl-O distances of 2.464 and 2.365 Å, respectively. The metal ion is directly coordinated to the eight donor atoms of the ligand, which results in a twisted square antiprismatic (TSAP') coordination around Tl(3+). A multinuclear (1)H, (13)C, and (205)Tl NMR study combined with DFT calculations confirmed the TSAP' structure of the complex in aqueous solution, which exists as the Λ(λλλλ)/Δ(δδδδ) enantiomeric pair. (205)Tl NMR spectroscopy allowed the protonation constant associated with the protonation of the complex according to [Tl(dota)](-) + H(+) ⇆ [Tl(Hdota)] to be determined, which turned out to be pK(H)Tl(dota) = 1.4 ± 0.1. [Tl(dota)](-) does not react with Br(-), even when using an excess of the anion, but it forms a weak mixed complex with cyanide, [Tl(dota)](-) + CN(-) ⇆ [Tl(dota)(CN)](2-), with an equilibrium constant of Kmix = 6.0 ± 0.8. The dissociation of the [Tl(dota)](-) complex was determined by UV-vis spectrophotometry under acidic conditions using a large excess of Br(-), and it was found to follow proton-assisted kinetics and to take place very slowly (∼10 days), even in 1 M HClO4, with the estimated half-life of the process being in the 10(9) h range at neutral pH. The solution dynamics of [Tl(dota)](-) were investigated using (13)C NMR spectroscopy and DFT calculations. The (13)C NMR spectra recorded at low temperature (272 K) point to C4 symmetry of the complex in solution, which averages to C4v as the temperature increases. This dynamic behavior was attributed to the Λ(λλλλ) ↔ Δ(δδδδ) enantiomerization process, which involves both the inversion of the macrocyclic unit and the rotation of the pendant arms. According to our calculations, the arm-rotation process limits the Λ(λλλλ) ↔

  2. Isothermal transitions of a thermosetting system

    Science.gov (United States)

    Gillham, J. K.; Benci, J. A.; Noshay, A.

    1974-01-01

    A study of the curing reactions of a cycloaliphatic epoxy resin/anhydride system by torsional braid analysis showed the existence of two critical isothermal temperatures - namely, the maximum glass transition temperature of the thermoset system and the glass transition temperature of the material at its gel point. Two rheologically active kinetic transitions occur during isothermal cure which correspond to gelation and vitrification. Three types of isothermal behavior occur. Methods for determining the time to gel and the time to vitrify, and also the two above-mentioned critical isothermal temperatures, have been developed. The time to gel obeyed the Arrhenius relationship, whereas the time to vitrify passed through a minimum. Application of these results to thermosetting systems in general is discussed in terms of the influence of molecular structure on the values of the critical isothermal temperatures.

  3. Thermoluminescence dose response of quartz as a function of irradiation temperature

    International Nuclear Information System (INIS)

    Kitis, G.; Kaldoudi, E.; Charalambous, S.

    1990-01-01

    The thermoluminescence (TL) response of pure Norwegian quartz as a function of irradiation temperature (T irr ) and dose has been investigated. The TL response of the (150-230 o C) and (230-350 o C) glow curve intervals shows a strong dependence on T irr between 77 and 373 K in the dose range from 54 to 8.4 x 10 4 Gy. Both glow curve intervals also show temperature dependent dose response properties. The 150-230 o C interval is supralinear from the lowest dose (54 Gy). Its maximum supralinearity factor appears at T irr = 293 K. The 230-350 o C interval shows sublinear behaviour below T irr = + 193 K, while at T irr ≥ 273 K it shows the well known dose response curves. Its maximum supralinearity factor appears at T irr = 323 K. The linear response is extended up to 460 Gy at T irr = 273 K and falls to 80 Gy at T irr = 373 K. (author)

  4. Electron spin resonance and thermoluminescence in powder form of clear fused quartz: effects of grinding

    CERN Document Server

    Ranjbar, A H; Randle, K

    1999-01-01

    Clear fused quartz (CFQ) tubes were powdered either manually by using a mortar and pestle (for coarse production) or mechanically, using a micronising mill (for fine production). A high and multisignal electron spin resonance (ESR) background was found in the fine powder even after annealing it at 900 deg. C for 20 min. In the case of the coarse powder, the signal (ESR background) varied inversely with particle size and was quite high for particle sizes lower than 38 mu m. In a subsidiary experiment, using fine SiO sub 2 powder (99.8% pure, with the particle size of approx 0.007 mu m), manufactured by using flame hydrolysis, only a weak background signal was found. The sup 6 sup 0 Co gamma-ray irradiated powders (approx 22 Gy) were subjected to ESR analysis or thermoluminescence (TL) readout. The ESR intensity of the coarse powder varied directly with particle size. Thus, the intensity for a particle size of 20-38 mu m was very low and almost the same as the unirradiated intensity. In TL readout the results w...

  5. TL and EPR dating: some applications

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, S. [Institute of Physics, University of Sao Paulo, Sao Paulo (Brazil)

    2006-07-01

    The intensity of thermoluminescence light emitted by a crystal is a function of radiation dose. The number of defects or of radicals in a crystal or organic substances is also a function of radiation dose. Since such defects or radicals present EPR signals, the EPR intensity is also a function of radiation dose. These facts are basis for radiation dosimetry and can be applied in dating of archaeological potteries or other materials, as well as in dating geological substances such as sediments, caves speleothemes, animal teeth and bones. Recent investigation on sensitized quartz based dosimeters and dating calcite covering ancient wall painting to find early settlers in Brazil will be presented. (Author)

  6. Quartz exposure and increased respiratory symptoms among coal ...

    African Journals Online (AJOL)

    Quartz has been an inevitable composition of different type of coal mined. The quartz exposures among coalmine workers has been attributed to activities such as cutting the adjacent rock, the roof, the floor and the intrusions. Objective: The aim of the study is to determine the associations between quartz exposures and ...

  7. Phytotoxicity of thallium (Tl) in culture solution. Pt. 1. Effects of Tl(I) on the growth and heavy metal contents of pea and field bean plants

    Energy Technology Data Exchange (ETDEWEB)

    Poetsch, U; Austenfeld, F A

    1985-01-01

    The effects of TlNO/sub 3/ and Tl(I)EDTA on growth and heavy metal contents of pea plants and field bean plants were compared in hydroponic culture experiments. In the presence of TlNO/sub 3/, the essential heavy metals were available to the plants in their ionic forms. When Tl(I)EDTA was present the essential heavy metals were available as chelated complexes. With increasing concentration of TlNO/sub 3/ dry matter production of pea plants was lowered and the Tl content of each organ was increased. The highest Tl content was found within the stems. The increased Tl contents were accompanied by depressed Mn, Zn, and Cu contents of the roots and depressed Mn contents of the stems, but increased Fe contents of the stems. Substitution of TlNO/sub 3/ by Tl(I)EDTA resulted in a stronger growth inhibition of the pea plants, and higher Tl contents of each organ. The highest Tl content was found within the stems. Tl(I)EDTA depressed Mn in the roots, but increased Fe and Mn in the stems, and Fe, Zn and Cu in the leaves. The increases may due to concentration by growth inhibition. The growth of the field bean was not effected by TlNO/sub 3/ nor by Tl(I)EDTA. The field bean contained most of the Tl within the roots and translocated only relatively small amounts to the shoots. This pattern was independent of the Tl compound. Increasing concentrations of TlNO/sub 3/ resulted in depressed Mn and Zn contents of the roots, and Mn contents of the stems. Chelation of Tl(I) resulted in a decrease of the Tl content of each organ. Tl(I)EDTA depressed only the Mn content of the roots.

  8. Historical review of quartz crystal growth

    Science.gov (United States)

    Iwasaki, Fumiko; Iwasaki, Hideo

    2002-04-01

    The history of quartz crystal growth is reviewed from the origin to the industrialization. The developing process of growth techniques is divided into the following three stages: (1) The fundamental work based on the mineralogical genetic view point, which was performed in Italy during the end of the 19th to the beginning of the 20th centuries. (2) The works to attempt the industrial application made in Germany and in England during World War II. (3) The industrialization of quartz growth after World War II. These were initiated in England, in USA and independently in Russia. The highest mass production process was developed in Japan. The historical flow is traced by the interview of several persons based on the original references.

  9. Emission polarization study on quartz and calcite.

    Science.gov (United States)

    Vincent, R. K.

    1972-01-01

    Calculation of the spectral emission polarization of quartz and calcite polished plates for observation angles of 20 and 70 deg by the substitution of complex index of refraction values for each mineral into Fresnel's equations. The emission polarization is shown to be quite wavelength-dependent, demonstrating that selected narrow or medium-width spectral bands exhibit a significantly higher percentage of polarization than a broad spectral band for these two minerals. Field measurements with a broadband infrared radiometer yield polarizations on the order of 2% for a coarse-grained granite rock and beach sand (both quartz-rich). This implies that a more sensitive detector with a selected medium-width filter may be capable of measuring emission polarization accurately enough to make this parameter useful as a remote sensing tool for discrimination among rocks on the basis of texture.

  10. The TL and OSL study of hydroxyapatites for dosimetric applications

    International Nuclear Information System (INIS)

    Alencar, Marcus A. Vallim de

    2009-01-01

    The hydroxyapatite, the principal mineral component of the bone and tooth enamel, is one of the dosimetric materials that has distinguished itself in the high dose and accidents dosimetry, as well as in the dating, for the Electron Paramagnetic Resonance (EPR) technique. For this reason, the hydroxyapatite could also be used as Thermoluminescence (TL) and Optically Stimulated Luminescence (OSL) dosimeter in the dosimetry of high doses and accidents, and also in the archaeological and geological dating. This work presents a brief study of the TL and OSL behaviour of the B type synthetic carbonated hydroxyapatite, observing the possibility to use this material in TL and OSL dosimetry. The samples were irradiated to a dose of 100 Gy and 1000 Gy, and the TL and OSL measurements were obtained by the RISOE TL/OSL reader, model TL/OSL-DA-15B. The first results demonstrate the presence of three peaks in the TL glow curve in the temperatures of 100 deg C, 150 deg C and 280 deg C. The synthetic carbonated hydroxyapatite also presents an OSL signal when the sample is stimulated with blue light and a small OSL signal for stimulation with infrared light (IR). These results indicate the possibility of this synthetic carbonated hydroxyapatite to be used as dose indicator material using the TL and OSL techniques. (author)

  11. Leading the Charge for SoTL--Embracing Collaboration

    Science.gov (United States)

    Cassard, Anita; Sloboda, Brian

    2014-01-01

    The scholarship of teaching and learning (SoTL) enables colleges and universities to assess student learning and measure the outcomes by engaging in meaningful research, and to disseminate this research. The objective of this paper is to give a snapshot of and assess the current thinking behind this scholarship by presenting examples of SoTL, and…

  12. Abnormal 201Tl limb scan due to unilateral tremor

    International Nuclear Information System (INIS)

    Simons, M.; Schelstraete, K.; Bratzlavsky, M.

    1982-01-01

    A abnormal intra- and interextremity distribution pattern on 201 Tl was observed on the limb scan of a patient with a unilateral tremor. This is ascribed to the increased blood flow in the muscles responsible for the tremor. The suggestion is made that the existence of tremor should be considered as a possible explanation for unexpected abnormalities on 201 Tl limb scintigrams

  13. Water Adsorption Isotherms on Fly Ash from Several Sources.

    Science.gov (United States)

    Navea, Juan G; Richmond, Emily; Stortini, Talia; Greenspan, Jillian

    2017-10-03

    In this study, horizontal attenuated total reflection (HATR) Fourier-transform infrared (FT-IR) spectroscopy was combined with quartz crystal microbalance (QCM) gravimetry to investigate the adsorption isotherms of water on fly ash, a byproduct of coal combustion in power plants. Because of composition variability with the source region, water uptake was studied at room temperature as a function of relative humidity (RH) on fly ash from several regions: United States, India, The Netherlands, and Germany. The FT-IR spectra show water features growth as a function of RH, with water absorbing on the particle surface in both an ordered (ice-like) and a disordered (liquid-like) structure. The QCM data was modeled using the Brunauer, Emmett, and Teller (BET) adsorption isotherm model. The BET model was found to describe the data well over the entire range of RH, showing that water uptake on fly ash takes place mostly on the surface of the particle, even for poorly combusted samples. In addition, the source region and power-plant efficiency play important roles in the water uptake and ice nucleation (IN) ability of fly ash. The difference in the observed water uptake and IN behavior between the four samples and mullite (3Al 2 O 3 ·2SiO 2 ), the aluminosilicate main component of fly ash, is attributed to differences in composition and the density of OH binding sites on the surface of each sample. A discussion is presented on the RH required to reach monolayer coverage on each sample as well as a comparison between surface sites of fly ash samples and enthalpies of adsorption of water between the samples and mullite.

  14. ISOTHERMAL AIR INGRESS VALIDATION EXPERIMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Chang H Oh; Eung S Kim

    2011-09-01

    Idaho National Laboratory carried out air ingress experiments as part of validating computational fluid dynamics (CFD) calculations. An isothermal test loop was designed and set to understand the stratified-flow phenomenon, which is important as the initial air flow into the lower plenum of the very high temperature gas cooled reactor (VHTR) when a large break loss-of-coolant accident occurs. The unique flow characteristics were focused on the VHTR air-ingress accident, in particular, the flow visualization of the stratified flow in the inlet pipe to the vessel lower plenum of the General Atomic’s Gas Turbine-Modular Helium Reactor (GT-MHR). Brine and sucrose were used as heavy fluids, and water was used to represent a light fluid, which mimics a counter current flow due to the density difference between the stimulant fluids. The density ratios were changed between 0.87 and 0.98. This experiment clearly showed that a stratified flow between simulant fluids was established even for very small density differences. The CFD calculations were compared with experimental data. A grid sensitivity study on CFD models was also performed using the Richardson extrapolation and the grid convergence index method for the numerical accuracy of CFD calculations . As a result, the calculated current speed showed very good agreement with the experimental data, indicating that the current CFD methods are suitable for predicting density gradient stratified flow phenomena in the air-ingress accident.

  15. Content of some microelements in Bulgarian quartz

    International Nuclear Information System (INIS)

    Kostadinov, K.; Kuleff, I.; Djingova, R.; Todorovski, D.

    1982-01-01

    Data on the content of As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Eu, Fe, Hf, Hg, Ir, K, La, Lu, Mn, Nd, Na, Rb, Sb, Sm, Ta, Tb, Sc, Th, U, W, Yb, Zn obtained by instrumental neutron activation analysis are reported. The method is published elsewhere (Kuleff, I. et J. Radional. Chem. 62 (1981) 187). The results of other authors for the amount of Al, Li, Ti, obtained by atomic absorption spectrometry and Cu, P measured by destructive neutron activation analysis are also reported for 3 batches of electrothermal quartz glass, manufactured by ''Svetlina'' plant in Sliven, Bulgaria. The results for Bulgarian quartz glass are compared with literature and authors' data for similar quality glasses produced in England, France, FRG, GDR, USA and USSR. The results show that the amount of As, Au, Cd, Ce, Co, Cs, Eu, Hg, La, Ta, Yb in Bulgarian made quartz glass is lower than in a number of other similar glasses and the amount of the other impurities is close to the mean values. (authors)

  16. Optimizing detection filters for single-grain optical dating of quartz

    International Nuclear Information System (INIS)

    Ballarini, M.; Wallinga, J.; Duller, G.A.T.; Brouwer, J.C.; Bos, A.J.J.; Van Eijk, C.W.E.

    2005-01-01

    We investigate the use of different optical detection filters for single-grain optically stimulated luminescence (OSL) measurements of quartz samples with a Riso TL/OSL single-grain reader. We selected three filter combinations that considerably improve the light detection efficiency when compared with the 7.5 mm U340 filters that are routinely used. These are the UG1+BG4 filter combination, the 2 mm UG1 and the 2.5 mm U340 filters, which allow a greater transmission in the quartz emission band. This leads to two benefits: (1) more grains can be accepted for equivalent dose analysis, and (2) OSL responses on individual grains are determined with a greater precision. While these three alternative filter combinations perform equally well if compared to each other, we suggest the 2.5 mm thick Hoya U340 to be the filter of choice as it allows the use of blue-diode and IR-diode stimulation sources for bleaching purposes and feldspar detection

  17. Some advances in the instrumental retrospective dosimetry techniques with tooth enamel and quartz

    International Nuclear Information System (INIS)

    Sholom, S.V.; Chumak, V.V.; Pasalskaja, L.F.; Pavlenko, J.V.

    1996-01-01

    Some aspects of retrospective dosimetry with tooth enamel and quartz have been considered. Firstly, the experimental and theoretical investigation had been carried out concerning influence of secondary electron equilibrium on the absorbed dose in enamel under the laboratory irradiation. The irradiation had been made with photons of energy 1,25 MeV, 662 and 100 keV. It is demonstrated that the influence of secondary electron equilibrium on the absorbed dose in enamel does not exceed few percent. Secondly, some of paramagnetic centers of enamel different from CO 2 - ones have been researched by using of the thermo activation technique. The enamel for this experiment had been carefully purified from organic components and then irradiated following annealed to consecutively increasing temperature. It was established that at least four of EPR centers of enamel possess radiation sensitivity and could be used for dosimetry purposes. Thirsty, it was performed a thorough investigation of the influence of different stages in quartz separation and purification with respect to obtaining of samples for TL-dosimetry. The optimal procedure has been developed

  18. ESR and TL age determination of caliche nodules

    Energy Technology Data Exchange (ETDEWEB)

    Oezer, A.M. (Middle East Technical Univ., Ankara (Turkey)); Wieser, A.; Goeksu, H.Y.; Mueller, P.; Regulla, D.F. (Gesellschaft fuer Strahlen- und Umweltforschung mbH Muenchen, Neuherberg (Germany, F.R.). Inst. fuer Strahlenschutz); Erol, O. (Istanbul Univ. (Turkey). School of Geography and Marine Sciences)

    1989-01-01

    Feasibility of dating caliche nodules by ESR and TL is investigated. For both methods the properties of the dating signal are described. Chemical composition as well as TL glow curves of caliches originating from different localities exhibit some differences. Due to the complexity of the TL glow curves, some samples required a special post-annealing procedure in order to resolve the main TL peak for age determination. Typical ESR calcite signals do not exist in caliche, therefore usefulness of the g=2.0040 ESR signal is studied. The results of TL and ESR ages are found to be compatible except for two samples. Possible causes of the discrepancy in these samples are discussed. It is shown that, with proper treatment of the radiation-induced signals, it was possible to date caliche formations older than 350 ka, which is not achievable with other methods like uranium series disequilibrium and/or radiocarbon dating. (author).

  19. ESR and TL age determination of caliche nodules

    International Nuclear Information System (INIS)

    Oezer, A.M.; Wieser, A.; Goeksu, H.Y.; Mueller, P.; Regulla, D.F.; Erol, O.

    1989-01-01

    Feasibility of dating caliche nodules by ESR and TL is investigated. For both methods the properties of the dating signal are described. Chemical composition as well as TL glow curves of caliches originating from different localities exhibit some differences. Due to the complexity of the TL glow curves, some samples required a special post-annealing procedure in order to resolve the main TL peak for age determination. Typical ESR calcite signals do not exist in caliche, therefore usefulness of the g=2.0040 ESR signal is studied. The results of TL and ESR ages are found to be compatible except for two samples. Possible causes of the discrepancy in these samples are discussed. It is shown that, with proper treatment of the radiation-induced signals, it was possible to date caliche formations older than 350 ka, which is not achievable with other methods like uranium series disequilibrium and/or radiocarbon dating. (author)

  20. The automated Risoe TL dating reader system

    International Nuclear Information System (INIS)

    Boetter-Jensen, L.

    1988-01-01

    The features of the new modified Riso TL dating reader system are described. A vacuum chamber that accommodates the entire 24-position sample changer unit has been designed. The vacuum and N 2 -gas functions are software-controlled. A newly designed heater system is capable of repeated heating cycles to 700 0 C. The sample changer system accommodates fine-grain discs as well as planchettes for coarse grains. Two software-controlled beta irradiators can be attached to the reader, e.g. for predose measurement. The software allows a user without programming expertise to create any desired measuring sequence, and to store and recall data and glow curves for making analyses. (author)

  1. Evaluasi Pengendalian Sistem Informasi Pengiriman pada TL

    Directory of Open Access Journals (Sweden)

    Nelly Nelly

    2011-06-01

    Full Text Available The purpose of this study is to evaluate the control systems on the TL shipping information, in order to discern weaknesses or problems in delivery of enterprise information systems control using CobIT approach. The research method used is the data collecting by observation, checklists, interviews, and literature study. The results achieved are findings and issue recommendations that provide an illustration about a control of the running information delivery systems. From the illustration it is known that on the company’s control of information delivery system, there are still many things that have not been up to standard. The conclusion obtained is that the control of information delivery systems that have been implemented meets only partially the standards set small, so it still needs much improvement. 

  2. Quality control 201TlCl solution obtained at IPEN-CNEN/SP through the direct method of 201Tl preparation

    International Nuclear Information System (INIS)

    Fernandes, L.; Silva, C.P.G. da.

    1991-09-01

    The radiopharmaceutical 201 TlCl is used in Nuclear medicine for myocardial visualization. The solution of 201 TlCl was prepared using 201 Tl obtained by irradiating a natural mercury target with protons. This radionuclide was subjected to different quality control processes to verify the purity required for its use in Medicine. Some of these controls concerned the determination of 200 Tl, 201 Tl and 202 Tl; the chemical identification of 201 Tl +1 ; the hydrazine concentration, mercury contamination and the presence of phosphate. Furthermore, the biologic distribution in Wistar rats and tests for sterility, pyrogens and for toxicity were carried out. It was verified that the solution obtained was in the form of thallous chloride. This radiopharmaceutical can give a good heart image in animals but due to the contamination of 201 Tl with 200 Tl and 202 Tl its use in human beings is not possible unless enriched 202 Hg is used as target of irradiation. (author)

  3. Clinical use of 201Tl myocardial scintigraphy

    International Nuclear Information System (INIS)

    Senda, Kohei; Imaeda, Takeyoshi; Kato, Toshimitsu; Asada, Shuichi; Doi, Hidetaka

    1977-01-01

    Myocardial imaging with 201 Tl and scinticamera was studied experimentally using specially designed phantoms and clinically in 23 patients with myocardial infarction or other heart disease. In the phantom experiment, quality of image, accumulative count rate, and detectability of the defect were compared to obtain the best technique for their detection, using four different collimators, i.e., converging, pin-hole, 4000-hole, and 140 keV high-resolution, at two photopeak levels of 201 Tl of 75 and 167 keV, and combining a radiation absorber. In patient examination, myocardial images taken at different periods after injection, different detecting conditions of the scinticamera, and various detecting projections were compared. Images of the converging collimator at the 75 keV photopeak revealed considerably higher accumulative counts and relatively higher quality than those of other detecting conditions. It was necessary to take as many images as possible in various projections, in order to detect the location and size of the myocardial ischemic lesion because the lesion was demonstrated as a clear defect only in profile. It became evident that images taken between about 25 and 90 min delineated the myocardium more clearly than those taken in other periods. Normal images taken in 8 patients without ischemic heart disease appeared in the shape of a doughnut of horseshoe, demonstrating mainly the left venticular myocardium. The image was faint in the region of the aortic or mitral valve and thin in the region of the apical wall. A faint image of the right ventricular myocardium was sometimes seen. In 3 patients with valvular heart disease, findings suggested changes in the thickness of myocardium and the distribution of coronary blood flow. In 11 of 12 patients with old myocardial infarction, the location and size of the lesion was detected. (Evans, J.)

  4. NaI(Tl) response functions

    Energy Technology Data Exchange (ETDEWEB)

    Vega C, H. R.; Ortiz R, J. M. [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas, Zac. (Mexico); Benites R, J. L. [Centro Estatal de Cancerologia de Nayarit, Calz. de la Cruz 118 Sur, Tepic, Nayarit (Mexico); De Leon M, H. A., E-mail: fermineutron@yahoo.com.mx [Instituto Tecnologico de Aguascalientes, Av. Adolfo Lopez Mateos 1801 Ote., 20155 Aguascalientes, Ags. (Mexico)

    2015-09-15

    The response functions of a NaI(Tl) detector have been estimated using Monte Carlo methods. Response functions were calculated for monoenergetic photon sources (0.05 to 3 MeV). Responses were calculated for point-like sources and for sources distributed in Portland cement cylinders. The responses were used to calculate the efficiency functions in term of photon energy. Commonly, sources used for calibration are point-like, and eventually sources to be measured have different features. In order to use the calibrated sources corrections due to solid angle, self-absorption and scattering, must be carried out. However, some of these corrections are not easy to perform. In this work, the calculated responses were used to estimate the detector efficiency of point-like sources, and sources distributed in Portland type cement. Samples of Portland paste were prepared and were exposed to photoneutrons produced by a 15 MV linac. Some of the elements in the cement were activated producing γ-emitting radionuclides that were measured with a NaI(Tl) gamma-ray spectrometer, that was calibrated with point-like sources. In order to determine the specific activity in the induced radioisotopes calculated efficiencies were used to make corrections due to the differences between the solid angle, photon absorption and photon scattering in the point-like calibration sources and the sources distributed in cement. During the interaction between photoneutrons and the cement samples three radioisotopes were induced: {sup 56}Mn, {sup 24}Na, and {sup 28}Al. (Author)

  5. Photoluminescence and absorption spectra of various common TL phosphors - interpretation of TL mechanisms

    International Nuclear Information System (INIS)

    Nagpal, J.S.

    1980-01-01

    Photoluminescence and absorption spectra of TL phosphors TLD-100, CaF 2 :Dy, CaSO 4 :Dy(0.05%wt), CaSO 4 :Tm(0.05%wt) and Mg 2 SiO 4 :Tb have been measured. The absorption spectra are typical of RE 2+ in rare earth doped irradiated phosphors. On heating RE 2+ yields RE 3+ and emission from the excited states of RE 3+ is observed. (author)

  6. Pulse shaper for scintillation detectors with NaI(Tl) or CsI(Tl) crystals

    International Nuclear Information System (INIS)

    Novisov, B.S.; Maksimenko, A.S.; Baryshev, A.V.; Zhukov, A.V.

    1978-01-01

    The basic circuit of a signal shaper for scintillation detectors with NaI(Tl) and CsI(Tl) crystals is described. To increase amplitude resolution, it is suggested to integrate not the whole charge at the photomultiplier output, but a part of the charge during the initial 100 ns of the current pulse; the remaining part of the current signal is compensated directly at the photomultiplier anode by means of an electric circuit. The principal elements of the spectrometric signal shaper include an input transistor amplifier, a compensation circuit, a key element, a shaper amplifier of time pulses, a shaper of signal duration for controlling the key element, and an output spectrometric amplifier. This device, being used, one can shape pulses at durations of 100 ns and more. The shaper restoration time does not exceed 50 ns. When the shaper operates with NaI(Tl) crystals and at counting rate of 10 6 pulse/s, the amplitude resolution with and without the compensation circuit is 17% and 21% respectively

  7. Radiation dose response correlation between thermoluminescence and optically stimulated luminescence in quartz

    International Nuclear Information System (INIS)

    Oniya, E.O.; Polymeris, G.S.; Tsirliganis, N.C.; Kitis, G.

    2012-01-01

    The fast, linearly modulated optically stimulated luminescence (LM-OSL) component in quartz is the main dosimetric signal used for the dating applications of this material. Since the blue light stimulation (470 nm, 40 mW cm −2 ) time needed to obtain the fast LM-OSL component is less than 50 s the electron trapping levels responsible for it are still highly populated. In this way an active radiation history is created which could play an important role in the dosimetric characteristics of the fast OSL signal. In the present work the dose response behavior of the fast OSL signal is investigated in quartz samples with an annealed radiation history and quartz samples possessing an artificial radiation history. A computerized curve de-convolution analysis of the LM-OSL curves for 50 s stimulation time showed that it consists of three individual OSL components. The faster component C 1 with peak maximum time around 5 s has a linear dose response in virgin samples, which turns to a slight superlinearity as a function of the artificial radiation history. On the other hand the component C 2 with peak maximum time at 12 s is slightly superlinear which turns into strong superlinearity as a function of artificial radiation history. Finally, component C 3 with peak maximum time at about 45 s is strongly superlinear for both virgin samples and as a function of artificial radiation history. The implications to practical application are discussed. - Highlights: ► The fast OSL component consists of three components. ► The linearity of first fast component does not depend on radiation history. ► The linearity of second and third components depend on radiation history. ► The TL between 180 and 300 °C is the major source of OSL.

  8. Characterization of color centers in quartz induced by gamma irradiation

    International Nuclear Information System (INIS)

    Guttler, Rainer A.S.

    2009-01-01

    The availability of gamma ray irradiators in Brazil increased the possibilities of treatments of gemstones for color enhancements. One of the minerals with a very high potential of these treatments is quartz, a very widespread mineral with much colored commercial varieties. Quartz occurs in Brazil mainly in two geological environments, called pegmatitic and hydrothermal. The detailed mechanism of color center formation of these two types of quartz will be investigated by spectroscopic and chemical analysis. Until yet, it can be shown that due to chemical differences of the nature of mineral forming fluids, the two types behave differently. All quartzes contain mainly traces of Iron, Aluminum, Lithium and some amounts of Water. The quartz of hydrothermal origin incorporated much structurally bound water, and despite some similarities with the chemical composition of pegmatitic quartz, this high water content is the reason for the formation of Silanol radicals, giving the green color to the quartz. The main difference in chemical composition of pegmatitic quartz is the presence of higher amounts of Al and Li , responsible for the brownish and yellowish colors formed by irradiation. Since each pegmatite is different, the quartz will behave differently. This explains the formation of the famous 'Green Gold' of quartz from Sao Jose da Safira , and the more yellowish, Citrine type, color of quartz from the Coluna deposit, near Itamarandiba, Minas Gerais. (author)

  9. Characterization of color centers in quartz induced by gamma irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Guttler, Rainer A.S., E-mail: rainersg@usp.b [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias; Enokihara, Cyro T.; Rela, Paulo R., E-mail: prela@ipen.b, E-mail: cteiti@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    The availability of gamma ray irradiators in Brazil increased the possibilities of treatments of gemstones for color enhancements. One of the minerals with a very high potential of these treatments is quartz, a very widespread mineral with much colored commercial varieties. Quartz occurs in Brazil mainly in two geological environments, called pegmatitic and hydrothermal. The detailed mechanism of color center formation of these two types of quartz will be investigated by spectroscopic and chemical analysis. Until yet, it can be shown that due to chemical differences of the nature of mineral forming fluids, the two types behave differently. All quartzes contain mainly traces of Iron, Aluminum, Lithium and some amounts of Water. The quartz of hydrothermal origin incorporated much structurally bound water, and despite some similarities with the chemical composition of pegmatitic quartz, this high water content is the reason for the formation of Silanol radicals, giving the green color to the quartz. The main difference in chemical composition of pegmatitic quartz is the presence of higher amounts of Al and Li , responsible for the brownish and yellowish colors formed by irradiation. Since each pegmatite is different, the quartz will behave differently. This explains the formation of the famous 'Green Gold' of quartz from Sao Jose da Safira , and the more yellowish, Citrine type, color of quartz from the Coluna deposit, near Itamarandiba, Minas Gerais. (author)

  10. Diagnostic Devices for Isothermal Nucleic Acid Amplification

    Directory of Open Access Journals (Sweden)

    Chia-Chen Chang

    2012-06-01

    Full Text Available Since the development of the polymerase chain reaction (PCR technique, genomic information has been retrievable from lesser amounts of DNA than previously possible. PCR-based amplifications require high-precision instruments to perform temperature cycling reactions; further, they are cumbersome for routine clinical use. However, the use of isothermal approaches can eliminate many complications associated with thermocycling. The application of diagnostic devices for isothermal DNA amplification has recently been studied extensively. In this paper, we describe the basic concepts of several isothermal amplification approaches and review recent progress in diagnostic device development.

  11. Diagnostic devices for isothermal nucleic acid amplification.

    Science.gov (United States)

    Chang, Chia-Chen; Chen, Chien-Cheng; Wei, Shih-Chung; Lu, Hui-Hsin; Liang, Yang-Hung; Lin, Chii-Wann

    2012-01-01

    Since the development of the polymerase chain reaction (PCR) technique, genomic information has been retrievable from lesser amounts of DNA than previously possible. PCR-based amplifications require high-precision instruments to perform temperature cycling reactions; further, they are cumbersome for routine clinical use. However, the use of isothermal approaches can eliminate many complications associated with thermocycling. The application of diagnostic devices for isothermal DNA amplification has recently been studied extensively. In this paper, we describe the basic concepts of several isothermal amplification approaches and review recent progress in diagnostic device development.

  12. Emergence of topological and topological crystalline phases in TlBiS2 and TlSbS2

    KAUST Repository

    Zhang, Qingyun; Cheng, Yingchun; Schwingenschlö gl, Udo

    2015-01-01

    Using first-principles calculations, we investigate the band structure evolution and topological phase transitions in TlBiS2 and TlSbS2 under hydrostatic pressure as well as uniaxial and biaxial strain. The phase transitions are identified by parity analysis and by calculating the surface states. Zero, one, and four Dirac cones are found for the (111) surfaces of both TlBiS2 and TlSbS2 when the pressure grows, which confirms trivial-nontrivial-trivial phase transitions. The Dirac cones at the (M) over bar points are anisotropic with large out-of-plane component. TlBiS2 shows normal, topological, and topological crystalline insulator phases under hydrostatic pressure, thus being the first compound to exhibit a phase transition from a topological to a topological crystalline insulator.

  13. Emergence of topological and topological crystalline phases in TlBiS2 and TlSbS2

    KAUST Repository

    Zhang, Qingyun

    2015-02-11

    Using first-principles calculations, we investigate the band structure evolution and topological phase transitions in TlBiS2 and TlSbS2 under hydrostatic pressure as well as uniaxial and biaxial strain. The phase transitions are identified by parity analysis and by calculating the surface states. Zero, one, and four Dirac cones are found for the (111) surfaces of both TlBiS2 and TlSbS2 when the pressure grows, which confirms trivial-nontrivial-trivial phase transitions. The Dirac cones at the (M) over bar points are anisotropic with large out-of-plane component. TlBiS2 shows normal, topological, and topological crystalline insulator phases under hydrostatic pressure, thus being the first compound to exhibit a phase transition from a topological to a topological crystalline insulator.

  14. Development of low background CsI(Tl) and NaI(Tl) crystals for WIMP search

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Hyun Su [Department of Physics, Ewha Womans University, Seoul 120-750 (Korea, Republic of)

    2015-08-17

    We have developed low background CsI(Tl) and NaI(Tl) crystals to search for weakly interacting massive particles as well as to verify the origin of the annual modulation signal observed by the DAMA/LIBRA experiment. Extensive studies about the contamination mechanisim of {sup 137}Cs in CsI powder lead to the growth of ultra-low-background CsI(Tl) crystals. Similar approaches for NaI(Tl) crystals have been applied to reduce internal backgrounds to less than 0.5 counts/kg/day/keV. Status and understanding of backgrounds and background reduction in NaI(Tl) crystals will be discussed.

  15. Identifying well-bleached quartz using the different bleaching rates of quartz and feldspar luminescence signals

    DEFF Research Database (Denmark)

    Murray, A.S.; Thomsen, Kristina Jørkov; Masuda, N.

    2012-01-01

    When dating older sedimentary deposits using quartz, there are no unambiguous methods for identifying the presence of incomplete bleaching. Current statistical analysis of dose distributions depends entirely on the assumption that incomplete bleaching and mixing are the main causes of any excess...... dispersion in the distribution; the only existing way to test this assumption is using independent age control. Here we suggest a new approach to this question, based on the differential bleaching rates of quartz and feldspar luminescence signals. We first present data that confirm the differences...... in relative bleaching rates of quartz optically stimulated luminescence (OSL) and feldspar luminescence stimulated at 50 °C by infrared light (IR50) and feldspar luminescence stimulated at 290 °C by infrared light after a stimulation at 50 °C (pIRIR290), and use recently deposited samples to determine...

  16. Experimental diagenesis of quartz with petroleum; Diagenese experimentale du quartz en presence d'hydrocarbures

    Energy Technology Data Exchange (ETDEWEB)

    Teinturier, St.

    2002-11-01

    Quartz cementation has a great impact on petroleum reservoir quality by controlling the porosity and thus the gas or oil storage. However, the possible cementation of quartz during petroleum emplacement is still debated. In most cases, the reconstitution and the understanding of diagenetic processes is based on fluid inclusions studies. However, many questions concerning the representativeness and the reading of the fluid inclusions still remains misunderstood. The experiments were carried out in a silica{+-}water{+-}salts{+-}oil{+-}gas system with the objective to simulate the siliceous diagenesis of natural petroleum reservoirs and to better understand the mechanisms of fluid inclusions formation and quartz cementation in a water and/or petroleum system. Calibration curves have been established using Raman micro-spectroscopy and synthetic reference inclusions to calculate the methane content of aqueous inclusions in the H{sub 2}O-CH{sub 4}-NaCl system. A quantitative procedure for FT-IR micro-spectrometry has been developed to obtain, from individual petroleum fluid inclusions, mole % concentrations of methane, alkanes and carbon dioxide as constraints to thermodynamic modelling. Synthetic aqueous inclusions were created within quartz micro-fractures, with methane (from 150 deg C-200 bar), with petroleum (from 184 deg C-163 bar) and inside quartz overgrowth with the presence of hydrocarbons (from 277 deg C-300 bar). Synthetic petroleum inclusions were created with different water/oil ratios (W/O) within quartz micro-fractures (0quartz overgrowth (10

  17. Color centers in heavily irradiated CsI(Tl) crystals

    International Nuclear Information System (INIS)

    Yakovlev, V.; Meleshko, A.; Trefilova, L.

    2008-01-01

    The absorption and luminescence properties of CsI(Tl) crystals colored by irradiation are studied by the method of the time-resolved spectroscopy. The scheme of the electron transitions in CsI(Tl) crystal is suggested to explain the appearance of the color centers under exposure to the near-UV light. It is established that either of the two types activator color centers holds the charge carrier with opposite sign. The model of the hole Tl 2+ v c - activator color center is suggested. According to the model the positive charge of Tl 2+ ion is compensated by the negative charge of a close cation vacancy v c - . The color center emission reveals in the cathode-luminescence spectrum of the colored CsI(Tl) crystal. The high-dose irradiation of CsI(Tl) crystal results in the reduction of the decay time of the near-thallium self-trapped excitons (STE) emission. The decay kinetics of Tl 2+ v c - emission contains the time components typical for the decay kinetics of near-thallium STE emission. The reason of the observed effects is the energy transfer from the near-thallium STE excitons to the color centers via the inductive-resonant mechanism

  18. Model-free method for isothermal and non-isothermal decomposition kinetics analysis of PET sample

    International Nuclear Information System (INIS)

    Saha, B.; Maiti, A.K.; Ghoshal, A.K.

    2006-01-01

    Pyrolysis, one possible alternative to recover valuable products from waste plastics, has recently been the subject of renewed interest. In the present study, the isoconversion methods, i.e., Vyazovkin model-free approach is applied to study non-isothermal decomposition kinetics of waste PET samples using various temperature integral approximations such as Coats and Redfern, Gorbachev, and Agrawal and Sivasubramanian approximation and direct integration (recursive adaptive Simpson quadrature scheme) to analyze the decomposition kinetics. The results show that activation energy (E α ) is a weak but increasing function of conversion (α) in case of non-isothermal decomposition and strong and decreasing function of conversion in case of isothermal decomposition. This indicates possible existence of nucleation, nuclei growth and gas diffusion mechanism during non-isothermal pyrolysis and nucleation and gas diffusion mechanism during isothermal pyrolysis. Optimum E α dependencies on α obtained for non-isothermal data showed similar nature for all the types of temperature integral approximations

  19. Isothermal calorimeter for reactor radiation dosimetry

    Energy Technology Data Exchange (ETDEWEB)

    Radak, B; Markovic, V [Institute of Nuclear Sciences Boris Kidric, Odeljenje za radijacionu hemiju, Vinca, Beograd (Serbia and Montenegro)

    1961-12-15

    An isothermal calorimeter with thermistors for measuring absorbed dose rates from 10{sup 4}-5-6.10{sup 5} rad/h in reactor experimental holes has been designed. A kinetics method for determining the equilibrium temperature difference has been developed, and its application in isothermal calorimetry proved. The expected accuracy in measurements within {+-} 2-5% has been proved by measurements carried out in the reactor. Some data obtained by measurements in the reactor RA are presented (author)

  20. Isotherms clustering in cosmic microwave background

    International Nuclear Information System (INIS)

    Bershadskii, A.

    2006-01-01

    Isotherms clustering in cosmic microwave background (CMB) has been studied using the 3-year WMAP data on cosmic microwave background radiation. It is shown that the isotherms clustering could be produced by the baryon-photon fluid turbulence in the last scattering surface. The Taylor-microscale Reynolds number of the turbulence is estimated directly from the CMB data as Re λ ∼10 2

  1. Comparative study on the effect of annealing treatments on RTL mechanism in natural quartz from different origins

    International Nuclear Information System (INIS)

    Mebhah, D.; Imatoukene, D.; Lounis-Mokrani, Z.; Kechouane, M.

    2009-01-01

    The behaviour of trap centres and luminescence centres has been investigated for fired and unfired natural quartz from bricks and sediments irradiated at 100 Gy and annealed at different temperatures in the range 350-700 deg. C. The annealing treatment affects thermoluminescence (TL) glow curve as various changes were observed. The higher sensitization occurred for an annealing in the region 550-600 deg. C. At this annealing temperature, it has been observed the emergence of two peaks arising at 96 and 180 deg. C. At lower annealing temperatures, these peaks are overlapped by the peaks localized at 90 and 195 deg. C, respectively. Concerning the fired quartz, the higher sensitization occurred for an annealing in the region 500-550 deg. C for peak temperature around 200 deg. C and an unusual desensitization for the peak temperature around 100 deg. C. The behaviour of the two types of quartz is analyzed regarding to their kinetic parameters and luminescence emission and compared to literature data.

  2. Comparative study on the effect of annealing treatments on RTL mechanism in natural quartz from different origins

    Energy Technology Data Exchange (ETDEWEB)

    Mebhah, D., E-mail: mebhahd@yahoo.f [Centre de Recherche Nucleaire d' Alger, 2 Bd, Frantz Fanon, BP 399 (Algeria); Imatoukene, D.; Lounis-Mokrani, Z. [Centre de Recherche Nucleaire d' Alger, 2 Bd, Frantz Fanon, BP 399 (Algeria); Kechouane, M. [Faculte de Physique, USTHB, BP 32 El Alia (Algeria)

    2009-12-15

    The behaviour of trap centres and luminescence centres has been investigated for fired and unfired natural quartz from bricks and sediments irradiated at 100 Gy and annealed at different temperatures in the range 350-700 deg. C. The annealing treatment affects thermoluminescence (TL) glow curve as various changes were observed. The higher sensitization occurred for an annealing in the region 550-600 deg. C. At this annealing temperature, it has been observed the emergence of two peaks arising at 96 and 180 deg. C. At lower annealing temperatures, these peaks are overlapped by the peaks localized at 90 and 195 deg. C, respectively. Concerning the fired quartz, the higher sensitization occurred for an annealing in the region 500-550 deg. C for peak temperature around 200 deg. C and an unusual desensitization for the peak temperature around 100 deg. C. The behaviour of the two types of quartz is analyzed regarding to their kinetic parameters and luminescence emission and compared to literature data.

  3. Preparation of 199Tl and its labelled compound

    International Nuclear Information System (INIS)

    Zhou Dehai; Guan Changtian; Kuang Anren

    1991-10-01

    Usually, 199 Ti is obtained by the nuclear reaction of 197 Au(α, 2n) 199 Tl. A gold target with 50±0.1 mm in diameter, 0.8 mm in thickness and 99.99% in purity was mounted in a cyclotron beam line. The target was bombarded by α particles with the energy of 25∼27 MeV and the beam current of 15∼20μA. The irradiated gold target was dissolved by aqua regia. Then the saturated aqueous solution of SO 2 was added. The 199 Tl(III)reduced to 199 Tl(I). The deposit of gold was removed. For separation of 199 Tl)I), about 5 mL of raw material solution obtained was transferred to 201 x 8 type anion exchange resin column which had been equilibrated with 4 mol/L HCl. The 199 Tl(I) and Au(III) were desorbed separately with the eluants (90% of aqueous diamide solution,, and 2 mol/L HCL∼5% thiourea) at the flow rate of 0.25 mL/min. After separation, the 10 mL concentrated nitric acid was added to the 199 Tl collected solution to destroy and remove the aqueous diamide solution, then 4 mol/L HCl was added and heated up to remove NO 3 - . The TlCl injection with pH = 5 was made up by using physiological saline. After filtering the 199 TlCl injection was sterilized at 137.3 kPa, 120 deg C about 30 min in an autoclave. The 199 TlCl injection was used in the animal pyrogen, a bacterial, safety, dispensation and myocardial imaging experiments. The good results have been obtained. Now it has undergone clinical experiments

  4. Miniaturized isothermal nucleic acid amplification, a review.

    Science.gov (United States)

    Asiello, Peter J; Baeumner, Antje J

    2011-04-21

    Micro-Total Analysis Systems (µTAS) for use in on-site rapid detection of DNA or RNA are increasingly being developed. Here, amplification of the target sequence is key to increasing sensitivity, enabling single-cell and few-copy nucleic acid detection. The several advantages to miniaturizing amplification reactions and coupling them with sample preparation and detection on the same chip are well known and include fewer manual steps, preventing contamination, and significantly reducing the volume of expensive reagents. To-date, the majority of miniaturized systems for nucleic acid analysis have used the polymerase chain reaction (PCR) for amplification and those systems are covered in previous reviews. This review provides a thorough overview of miniaturized analysis systems using alternatives to PCR, specifically isothermal amplification reactions. With no need for thermal cycling, isothermal microsystems can be designed to be simple and low-energy consuming and therefore may outperform PCR in portable, battery-operated detection systems in the future. The main isothermal methods as miniaturized systems reviewed here include nucleic acid sequence-based amplification (NASBA), loop-mediated isothermal amplification (LAMP), helicase-dependent amplification (HDA), rolling circle amplification (RCA), and strand displacement amplification (SDA). Also, important design criteria for the miniaturized devices are discussed. Finally, the potential of miniaturization of some new isothermal methods such as the exponential amplification reaction (EXPAR), isothermal and chimeric primer-initiated amplification of nucleic acids (ICANs), signal-mediated amplification of RNA technology (SMART) and others is presented.

  5. Kinetics of the coesite to quartz transformation

    Science.gov (United States)

    Mosenfelder, J.L.; Bohlen, S.R.

    1997-01-01

    The survival of coesite in ultrahigh-pressure (UHP) rocks has important implications for the exhumation of subducted crustal rocks. We have conducted experiments to study the mechanism and rate of the coesite ??? quartz transformation using polycrystalline coesite aggregates, fabricated by devitrifying silica glass cylinders containing 2850H/106 Si at 1000??C and 3.6 GPa for 24h. Conditions were adjusted following synthesis to transform the samples at 700-1000??C at pressures 190-410 MPa below the quartz-coesite equilibrium boundary. Reaction proceeds via grain-boundary nucleation and interface-controlled growth, with characteristic reaction textures remarkably similar to those seen in natural UHP rocks. We infer that the experimental reaction mechanism is identical to that in nature, a prerequisite for reliable extrapolation of the rate data. Growth rates obtained by direct measurement differ by up to two orders of magnitude from those estimated by fitting a rate equation to the transformation-time data. Fitting the rates to Turnbull's equation for growth therefore yields two distinct sets of parameters with similar activation energies (242 or 269 kJ/mol) but significantly different pre-exponential constants. Extrapolation based on either set of growth rates suggests that coesite should not be preserved on geologic time scales if it reaches the quartz stability field at temperatures above 375-400??C. The survival of coesite has previously been linked to its inclusion in strong phases, such as garnet, that can sustain a high internal pressure during decompression. Other factors that may play a crucial role in preservation are low fluid availability - possibly even less than that of our nominally "dry" experiments - and the development of transformation stress, which inhibits nucleation and growth. These issues are discussed in the context of our experiments as well as recent observations from natural rocks. ?? 1997 Elsevier Science B.V.

  6. Comparison of TL profiles in recent sea cores

    Energy Technology Data Exchange (ETDEWEB)

    Castagnoli, G C; Bonino, G

    1985-01-01

    The thermoluminescence (TL) profile of different recent Tyrrhenian sea cores sampled at various intervals during the last centuries have been compared in order to check the reproducibility of the profiles and investigate the possibility of using the results for monitoring solar-terrestrial relations in the past. The satisfactory results obtained by comparison of two different cores in the time interval 1755-1969 A.D. has demonstrated: (a) the two TL profiles are correlated; (b) the 11 yr cycle corresponding to the main solar cycle is evident in both TL profiles.

  7. Dielectric and baric characteristics of TlS single crystal

    Energy Technology Data Exchange (ETDEWEB)

    Mustafaeva, S.N., E-mail: solmust@gmail.com [Institute of Physics, ANAS, G. Javid prosp. 33, Az 1143 Baku (Azerbaijan); Asadov, M.M. [Institute of Chemical Problems, ANAS, G. Javid prosp. 29, Az 1143 Baku (Azerbaijan); Ismailov, A.A. [Institute of Physics, ANAS, G. Javid prosp. 33, Az 1143 Baku (Azerbaijan)

    2014-11-15

    The investigation of the frequency dependences of the dielectric coefficients and ac-conductivity of the TlS single crystals made it possible to elucidate the nature of dielectric loss and the charge transfer mechanism. Moreover, we evaluated the density and energy spread of localized states near the Fermi level, the average hopping time and the average hopping length. It was shown that the dc-conductivity of the TlS single crystals can be controlled by varying the hydrostatic pressure. This has opened up possibilities for using TlS single crystals as active elements of pressure detectors.

  8. Photon and neutron energy response of Thermoluminescent (TL) dosimeters

    International Nuclear Information System (INIS)

    Thilagam, L.; Priya, M.R.; Mohapatra, D.K.

    2018-01-01

    Theoretical Monte Carlo (MC) simulations are carried out to investigate the relative thermoluminesence (TL) response of the most commonly used TLD materials to a wide range of photon energy. The effect of polytetrafluoroethylene (PTFE) on TL response of CaSO 4 :Dy is also studied. Additionally, the neutron response of LiF:Mg,Ti TL materials with different concentrations of 6 Li is estimated in terms of the number of 6 Li(n, t) 4 He capture reactions for a wider neutron energy

  9. Positron states and nanoobjects in proton-irradiated quartz single crystals: Positronium atom in quartz

    International Nuclear Information System (INIS)

    Grafutin, V. I.; Zaluzhnyi, A. G.; Timoshenkov, S. P.; Britkov, O. M.; Ilyukhina, O. V.; Myasishcheva, G. G.; Prokop'ev, E. P.; Funtikov, Yu. V.

    2008-01-01

    The influence of proton bombardment and metal atom impurities on the structure of quartz single crystals has been studied. The related defects have been studied using positron annihilation spectroscopy (angular correlation of positron-annihilation photons), acoustic absorption, and optical absorption measurements. It is shown that the presence of a narrow component f in the angular distribution of annihilation photons (ADAP), which is related to the formation of parapositronium, determines a high sensitivity of this method with respect to features of the crystal structure of quartz. It is established that the defectness of the structure of irradiated quartz crystals can be characterized by the ratio f/f 0 of the relative intensities of narrow components in the ADAP curves measured before (f 0 ) and after (f) irradiation. Any process leading to a decrease in the probability of positronium formation (e.g., positron loss as a result of the trapping on defects and the interaction with impurity atoms and lattice distortions) decreases the intensity of the narrow component. Based on the ADAP data, estimates of the radii and concentrations of nanodefects in quartz have been obtained and their variation upon annealing at temperatures up to T = 873 K has been studied

  10. Solid solutions of thallium in TlGaSe2, TlGaS2, and TlInS2

    International Nuclear Information System (INIS)

    Voroshilov, Yu. V.; Potorii, M.V.; Shevchenko, S.V.

    1986-01-01

    The authors study the nature of the dissolution of thallium in ternary phases. They have synthesized alloys of the stoichiometric compositions TlGaS 2 , TlGaSe 2 , and T1InS 2 , and their solid solutions, maximally enriched in thallium, the compositions of which were Tl /SUB 1.34/ GA /SUB 0.89/ S 2 , Tl /SUB 1.31/ Ga /SUB 0.90/ Se 2 , and Tl /SUB 1.15/ In /SUB 0.95/ S /SUB 2./ . Samples were synthesized from the elemental components of the following purities: gallium of V4 grade; indium of V4 grade; thallium of T1000 grade; selenium of special purity 22-4 grade, and sulfur of special purity garde. The compositions were checked by x-ray-phase-(DRON-0.5) and microstructural-analyses with simultaneous determination of the density and microhardness of the samples. It is found that the lattic parameter increases and the increase in the density and microhardness points to strengthening of the structure during the formation of the solid solutions

  11. Improvements in the Tl dosimetry for Radiotherapy; Mejoras en la dosimetria Tl para Radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Bustos, S.; Velez, G.; Rubio, M. [CEPROCOR. Arenales 230 Juniors Cordoba 5000 (Argentina)

    1998-12-31

    The thermoluminescent dosimetry (TLD) in vivo has been demonstrated to be one of the most reliable for the control of radiotherapeutic treatments, but the delay in the response is the main disadvantage in its applicability. In this work are presented important improvements and it is demonstrated that maintaining the accuracy and reliability of the technique, it is possible to accelerate the response times at a few hours. To realize this work is utilized a lecturer Harshaw 4000, dosemeters LiF-TLD-100 chips (3.1 x 3.1 x 0.89 mm{sup 3}) and rods (1 x 1 x 6 mm{sup 3}). With the implementation of a glow curve analysis program developed in CIEMAT, its obtained a Tl peaks separation in such manner rapid and accurate, by that the thermal treatment of dosemeters may be reduced at one unique annealing pre-irradiation for 1 hr at 400 Centigrade. It is realized a periodical and individual calibration of the TLD and a study of the factors which influencing the ratio Tl signal-dose as linearity, correction by energy, directional response and pride of Tl signal. the results of this study are introducing in a calculation list specially designed and which allows to obtain absorbed dose by TLD starting of the dates (dosimetric peaks area) which appear of the glow curves analysis. The dose is obtained with an accuracy less than 5 %. The dosemeters already irradiated (in vivo) are analysed and informed in only four hours, allowing a greater control of the treatment and a correction of the possible errors for the next session, still in bi fractional treatments. The method implemented results thus accurate, rapid and reliable. (Author)

  12. Hydrogen sensing method with a quartz sensor

    International Nuclear Information System (INIS)

    Suzuki, A.; Kurokawa, A.; Nonaka, H.

    2006-01-01

    The stability for hydrogen leakage detection was improved by impedance measurement with a quartz sensor (Q-sensor) instead of pressure measurement with a quartz friction pressure gauge (Q-gauge) previously used. Degree of the experimental fluctuation of the impedance from the Q-sensor and of the pressure from the Q-gauge was 0.06 and 0.2 % of each output, thus showing that the Q-sensor measurement was more stable than that by the Q-gauge. Estimated minimum detection limit for hydrogen by the Q-sensor impedance measurement is also improved compared to the Q-gauge pressure measurement. Low hydrogen concentration experiment presented that the Q-sensor impedance measurement detects the 0.05 vol.% hydrogen in air at atmospheric pressure more sensitively than the Q-gauge pressure measurement. It was proved that the Q-sensor impedance measurement was more sensitive and stable as a hydrogen leakage detection method than the Q-gauge pressure measurement. (authors)

  13. Quartz Crystal Temperature Sensor for MAS NMR

    Science.gov (United States)

    Simon, Gerald

    1997-10-01

    Quartz crystal temperature sensors (QCTS) were tested for the first time as wireless thermometers in NMR MAS rotors utilizing the NMR RF technique itself for exiting and receiving electro-mechanical quartz resonances. This new tool in MAS NMR has a high sensitivity, linearity, and precision. When compared to the frequently used calibration of the variable temperature in the NMR system by a solid state NMR chemical shift thermometer (CST), such as lead nitrate, QCTS shows a number of advantages. It is an inert thermometer in close contact with solid samples operating parallel to the NMR experiment. QCTS can be manufactured for any frequency to be near a NMR frequency of interest (typically 1 to 2 MHz below or above). Due to the strong response of the crystal, signal detection is possible without changing the tuning of the MAS probe. The NMR signal is not influenced due to the relative sharp crystal resonance, restricted excitation by finite pulses, high probeQvalues, and commonly used audio filters. The quadratic dependence of the temperature increase on spinning speed is the same for the QCTS and for the CST lead nitrate and is discussed in terms of frictional heat in accordance with the literature about lead nitrate and with the results of a simple rotor speed jump experiment with differently radial located lead nitrate in the rotor.

  14. Ultrashort-period lateral composition modulation in TlInGaAsN/TlInP structures

    International Nuclear Information System (INIS)

    Ishimaru, Manabu; Tanaka, Yuusuke; Hasegawa, Shigehiko; Asahi, Hajime; Sato, Kazuhisa; Konno, Toyohiko J.

    2009-01-01

    We prepared TlInGaAsN/TlInP quantum well structures using gas source molecular-beam epitaxy and characterized them by means of transmission electron microscopy and scanning transmission electron microscopy. It was found that naturally formed vertical quantum wells, so-called lateral composition modulation (LCM), with a periodicity of ∼1 nm are formed in TlInGaAsN layers. We discuss their formation process using a simple kinetic Ising model for layer-by-layer growth, and point out that the formation of ultrashort-period LCM is a universal phenomenon in most of epitaxially grown III-V semiconductor alloys.

  15. Production of quartz plates for CMS-CASTOR Experiment

    CERN Document Server

    Adiguzel, Aytul; Ayhan, Aydin; Bakirci, Mustafa Numan; Basegmez, Suzan; Beaumont, Willem; Borras, Kerstin; Campbell, Alan; De Paula Carvalho, W; Çerçi, Salim; De Jesus Damiao, Dilson; Dogangün, O; Dumanoglu, Isa; d'Enterria, David; Erchov, Y; Eskut, Eda; Figueiredo, D; Girgis, Semiray; Göttlicher, P; Gouskos, Loukas; Gurpinar, Emine; Hos, Ilknur; Katkov, Igor; Katsas, Panagiotis; Khein, Lev; Knutsson, Albert; Kuznetsov, Andrey; Lebeau, Michel; Van Mechelen, Pierre; Muhl, Carsten; Musienko, Yuri; Ochesanu, Silvia; Onengüt, G; Onengut, G Jr; Ozdemir, Kadri; Panagiotou, Apostolos; Polatoz, A; Ripert, Marion; Shileev, K; Sogut, Kenan; Tiflov, B TaliV; Kayis-Topaksu, A; Uzun, Dilber

    2008-01-01

    Light transmission rate performance of $102$ irradiated quartz samples was measured to select the best quartz plates for CMS-CASTOR calorimeter. All the produced quartz plates were originally used in a previous CERN experiment, DELPHI. Three different doses of $^{60}$Co source were used with the collaboration of PSI (Paul Scherrer Institute, Villigen PSI, Switzerland.) to study the transmission rate performance of the quartz samples after irradiation for different incident light, ranging from $250$ to $700$ nm in $5$ nm increasing steps. All samples show different decrease in the rate with wavelength for different doses. Three different steps were followed before irradiation to find out the best way of cleaning the original DELPHI Cu/Cr tracks on the samples. Results of these measurements presented here correspond to the quartz plates that will be used in one hadronic sector of CASTOR calorimeter until end of 2008. For the full calorimeter new quartz plates will be installed. We also present the light transmi...

  16. Asymmetric adsorption of alanine by quartz powder from ethanol solution

    Energy Technology Data Exchange (ETDEWEB)

    Furuyama, Shozo; Sawada, Michio; Hachiya, Kinji; Morimoto, Tetsuo (Okayama Univ. (Japan). Faculty of Science)

    1982-11-01

    The asymmetric adsorption of the racemic alanine by the optically active quartz from ethanol solution at 8/sup 0/C was studied by the /sup 14/C-tracer method and the newly developed /sup 14/C-tracer ninhydrin-colorimetry combination method. The preferential adsorption of L-alanine by levorotatory quartz (l-quartz) and D-alanine by dextrorotatory quartz (d-quartz) was confirmed. The asymmetric adsorptivity (Asub(s)) falls in the range of 1.1 - 1.3, which is comparable with the value determined at - 80/sup 0/C in the previous paper. The effects of water content in the ethanol solution and of the adsorption temperature upon the adsorption affinity of alanine to quartz were also measured. The cause for the asymmetric adsorption is discussed from the crystallographic point of view.

  17. Superdeformation in the Hg-Tl-Pb region

    International Nuclear Information System (INIS)

    Henry, E.A.; Becker, J.A.; Yates, S.W.; Wang, T.F.; Kuhnert, A.; Brinkman, M.J.; Cizewski, J.A.; Deleplanque, M.A.; Diamond, R.M.; Stephens, F.S.; Azaiez, F.; Korten, W.; Draper, J.E.

    1990-10-01

    Superdeformation in the Hg-Tl-Pb region is discussed, with concentration on the experimental results. At least twenty-five superdeformed bands are known in this region, providing much new data to test theoretical calculations. 22 refs., 5 figs

  18. Use of universal functional optimisation for TL glow curve analysis

    International Nuclear Information System (INIS)

    Pernicka, F.; Linh, H.Q.

    1996-01-01

    The effective use of any TL instrument requires an efficient software package to be able to fulfil different tasks required by research and practical applications. One of the standard features of the package used at the NPI Prague is the application of the interactive modular system Universal Functional Optimisation (UFO) for glow curve deconvolution. The whole system has been tested on standard glow curves using different models of the TL process (a single peak described by the Podgorsak approximation, first order kinetics and/or general order kinetics). Calculated values of basic TL parameters (E and s) show a good agreement with the results obtained by other authors. The main advantage of the system is in its modularity that enables flexible changes in the TL model and mathematical procedures of the glow curve analysis. (author)

  19. A preliminary study of landslide gouge dating by TL technique

    Energy Technology Data Exchange (ETDEWEB)

    Fengju, Ji; Jianping, Li [Inst. of Geology, National Seismological Bereau, Beijing (China); Mingda, Liu [Inst. of Crustal Dynamics, SSB, Beijing (China)

    1993-04-01

    The key to date slipping of landslide by TL method is whether the temperature and pressure caused by slipping can lead the original TL to 'zero'for some minerals within the slipping band. For this purpose, the simulated experiments under different temperature-pressure were made and the TL annealing effect of landslide gouge was studied. The results show that the frictional heating caused during slipping is a main factor leading the mineral's TL to decrease on the slip plane and that increment of temperature is in close relation with strength of shear stress, thickness of landslide gouge and amount of displacement. As an example, the slipping age of a paleo-landslide at Huangtupo, Hubei Province, has been dated to be about 140 ka.

  20. TL dating of vases with elephant ears in Yuan Dynasty

    International Nuclear Information System (INIS)

    Xia Junding; Wang Weida; Leung, P.L.

    2005-01-01

    Thermoluminescence (TL) dating using an activation method in pre-dose technique was described. Three vases in underglaze blue with elephant ears and one vase in underglaze red with elephant ears in Yuan Dynasty were dated by this method. The results show that the TL ages are all less than 100 a B.P., and in which sbc 648 and sbc 649 were imitated in recent years. This method is quick, convenient and reliable for porcelain dating with the age of less than 1000 a B.P.. As a comparison, a porcelain sample with underglaze blue in Yuan Dynasty was dated too, and its TL age is 620 ± 140 B.P.. In addition, some complex factors associated with dating have been discussed and a resolution has been raised, which will help improve the accuracy of TL dating. (authors)

  1. Examination of TL and optical absorption in calcite's mineral

    International Nuclear Information System (INIS)

    Sabikoglu, I.; Can, N.

    2009-01-01

    Calcite which is a form of crystalline of the calcium carbonate composes parent material of chalk stone (limestone) and marble. Calcite which presents in various colors also in our country consists of yellow, blue, transparent and green colors. In this study, green calcite mineral which is taken from the region of Ayvalik, was examined of its thermoluminescence (TL) and optical absorption features in different doses. It has been obtained a large TL peak in 179 degree C and absorption peak in 550 mm.

  2. Deformation effects in electronic spectra of the layered semiconductors TlGaS sub 2 , TlGaSe sub 2 and TlInS sub 2

    CERN Document Server

    Allakhverdiev, K R; Suleymanov, R A; Gasanov, N Z

    2003-01-01

    The deformation effects in electronic spectra of the ternary layered semiconductors TlGaS sub 2 , TlGaSe sub 2 and TlInS sub 2 are considered. It is shown that the influence of hydrostatic pressure, thermal expansion and variation of composition in solid solutions on the band gap of the crystals investigated can be described in the framework of one common model of deformation potentials. This model appears to be close to that of layered semiconductors of the A sub 3 B sub 6 group, attesting to the fact that the main principles of formation of band structure in these two groups of layered crystals are the same.

  3. TL1A regulates TCRγδ+ intraepithelial lymphocytes and gut microbial composition

    DEFF Research Database (Denmark)

    Tougaard, Peter; Skov, S.; Pedersen, A. E.

    2015-01-01

    TL1A is a proinflammatory cytokine, which is prevalent in the gut. High TL1A concentrations are present in patients with inflammatory bowel disease (IBD) and in IBD mouse models. However, the role of TL1A during steady‐state conditions is relatively unknown. Here, we used TL1A knockout (KO) mice ...

  4. Mechanical and optical nanodevices in single-crystal quartz

    Science.gov (United States)

    Sohn, Young-Ik; Miller, Rachel; Venkataraman, Vivek; Lončar, Marko

    2017-12-01

    Single-crystal α-quartz, one of the most widely used piezoelectric materials, has enabled a wide range of timing applications. Owing to the fact that an integrated thin-film based quartz platform is not available, most of these applications rely on macroscopic, bulk crystal-based devices. Here, we show that the Faraday cage angled-etching technique can be used to realize nanoscale electromechanical and photonic devices in quartz. Using this approach, we demonstrate quartz nanomechanical cantilevers and ring resonators featuring Qs of 4900 and 8900, respectively.

  5. Remote TL and OSL for asteroid and meteorite study

    International Nuclear Information System (INIS)

    Takaki, Shunji; Ikeya, Motoji; Yamanaka, Chihiro

    1997-01-01

    Thermoluminescence (TL) and optically stimulated luminescence (OSL) of the Allende meteorite have been studied using infrared CO 2 laser light as a heat source and He-Ne laser light to excite the material, respectively from a long distance. New techniques of remote TL (R-TL) and remote OSL (R-OSL) have been developed for future remote dating from a long distance in a planetary survey. The upper limits of the distance for R-TL and R-OSL were estimated using the laboratory TL signal of the meteorite peaking at 320 o C: about 400 photons s -1 for the R-TL and 60 photons s -1 for R-OSL at a distance of 1 km using a laser beam with the divergence of 0.1 mrad at powers of 100 and 1 W, respectively. An age limit of 10 5 or 10 6 years due to the signal saturation and the objects heterogeneity, as expected from previous studies, may make the asteroid survey difficult but would still help to investigate the surface activities of icy planets and satellites in outer planet worlds. (author)

  6. Leg 201Tl-SPECT in chronic exertional compartment syndrome

    International Nuclear Information System (INIS)

    Elkadri, N.; Slim, I.; Blondet, C.; Choquet, Ph.; Constantinesco, A.; Lecocq, J.

    2004-01-01

    Leg 201 Tl-SPECT in chronic exertional compartment syndrome Background: The chronic exertional compartment syndrome is one of the most frequent origins regarding leg pain due to sport training. The diagnosis can be established by invasive compartment pressure measurement. The aim of this study is to evaluate the role that could have 201 Tl-SPECT for patients with suspicion of compartment syndrome. Patients and methods: 51 leg 201 Tl-SPECT exams were performed (exercise - and rest without reinjection) in 49 patients; 28 had compartment syndrome confirmed by pressure measurement. About 100 MBq of 201 Tl were injected during exercise, when pain appeared or at least after 25 minutes exercise. We studied mean percentages of level uptake for each compartment, referred to the maximal uptake of both legs. Results: 47 compartments were concerned by compartment syndrome and 361 compartments were not. Scintigraphic patterns in compartments are reversible ischaemia (45%), uptake stability (36%) or reverse redistribution (19%); these patterns are not linked to compartment syndrome. However, there is a significant difference of rest 201 Tl level uptake between compartments with and without compartment syndrome and a significant correlation between muscular pressure measurement and rest level uptake. Conclusion: 201 Tl-SPECT shows that only ischaemia does not explain compartment syndrome. Moreover, it allows to predict pressure variation during exercise but it does not offer any interest in order to select patients for muscular invasive pressure measurement. (author)

  7. $\\alpha$-decay study of $^{182,184}$Tl

    CERN Document Server

    Van Beveren, C; Barzakh, A E; Cocolios, T E; de Groote, R P; Fedorov, D; Fedosseev, V N; Ferrer, R; Ghys, L; Huyse, M; Köster, U; Lane, J; Liberati, V; Lynch, K M; Marsh, B A; Molkanov, P L; Procter, T J; Rapisarda, E; Sandhu, K; Seliverstov, M D; Van Duppen, P; Venhart, M; Veselský, M

    2016-01-01

    α -decay spectroscopy of 182,184 Tl has been performed at the CERN isotope separator on-line ( ISOLDE ) facility. New fi ne-structure α decays have been observed for both isotopes. α -decay branching ratios of 0.089 ( 19 ) %, 0.047 ( 6 ) % and 1.22 ( 30 ) % have been deduced for the ( 10 − ) , ( 7 + ) and ( 2 − ) states respectively in 184 Tl and a lower limit of 0.49% for the α -decay branching ratio of 182 Tl. A new half-life of 9.5 ( 2 ) s for the ( 2 − ) state in 184 Tl and 1.9 ( 1 ) s for the low-spin state in 182 Tl has been deduced. Using α – γ coincidence analysis, multiple γ rays were observed de-exciting levels in 178,18 0 Au fed by 182,184 Tl α decays. The γ transitions connecting these low-lying states in 178,18 0 Au are essential to sort the data and possibly identify bands from in- beam studies in these isotopes. Owing to the complex fi ne-structure α decays and limited knowledge about the structure of the daughter nuclei, only partial level schemes could be constructed for bot...

  8. Kinetics of the stress induced phase transition in quartz by real-time neutron scattering

    International Nuclear Information System (INIS)

    Gibhardt, H.; Eckold, G.; Guethoff, F.

    1999-01-01

    Complete text of publication follows. The stability regime of the incommensurate phase of quartz is influenced by uniaxial stress. Hence, the phase transition can be induced under isothermal conditions by the application of external mechanical forces. Using real-time neutron scattering the time evolution of structural changes is investigated id detail during stress variations. The time dependent behaviour of the satellite reflection is compared with that one of the fundamental Bragg reflection which - via primary extinction - gives information about the perfection of the crystal. On increasing stress the perfection of the lattice is destroyed immediately while the modulated structure is built up with a delay of about 1 s. Decreasing the stress leads to a reverse behaviour. Moreover, there is evidence that under periodical load residual non-relaxed strain fields survive leading to a different temperature dependence as compared to static conditions. This finding is compatible with pronounced hysteresis effects observed under cycling stress. It is argued that these residual strains are associated with non-relaxed topological 4-line defects, that drive the structural changes in quartz (1). (author)

  9. Transport and retention of strontium in surface-modified quartz sand with different wettability

    International Nuclear Information System (INIS)

    Yifei Li; Shuaihui Tian; Tianwei Qian

    2011-01-01

    Instead of radioactive 90 Sr, common strontium chloride was used to simulate the migration of radioactive strontium chloride in surface hydroxylated, silanized, and common quartz sand. The sorption and retardation characteristics of strontium (Sr 2+ ) in these surface modified quartz sands were studied by batch tests and column experiments. The equilibrium sorption data for Sr 2+ on different wettability sands were described by the Langmuir and Freundlich isotherm models, and the Langmuir model has been found to provide better correlation for hydrophilic sand. The breakthrough curves (BTCs) of Sr 2+ in these media were analyzed with the equilibrium convection-dispersion equation (CDE) and a non-equilibrium two-region mobile-immobile model (TRM) using a nonlinear least square curve-fitting program CXTFIT. The TRM model showed better fit to the measured BTCs of Sr 2+ , and the parameters of the fraction of mobile water indicated that significant preferential flow effected the non-equilibrium transport of Sr 2+ . Although TRM model could not fit the Sr 2+ BTCs very well, the parameter estimated by TRM model may be more reliable than those obtained from batch experiments because the transport of Sr 2+ in these kind of sand is non-equilibrium processes. (author)

  10. Modeling of Experimental Adsorption Isotherm Data

    Directory of Open Access Journals (Sweden)

    Xunjun Chen

    2015-01-01

    Full Text Available Adsorption is considered to be one of the most effective technologies widely used in global environmental protection areas. Modeling of experimental adsorption isotherm data is an essential way for predicting the mechanisms of adsorption, which will lead to an improvement in the area of adsorption science. In this paper, we employed three isotherm models, namely: Langmuir, Freundlich, and Dubinin-Radushkevich to correlate four sets of experimental adsorption isotherm data, which were obtained by batch tests in lab. The linearized and non-linearized isotherm models were compared and discussed. In order to determine the best fit isotherm model, the correlation coefficient (r2 and standard errors (S.E. for each parameter were used to evaluate the data. The modeling results showed that non-linear Langmuir model could fit the data better than others, with relatively higher r2 values and smaller S.E. The linear Langmuir model had the highest value of r2, however, the maximum adsorption capacities estimated from linear Langmuir model were deviated from the experimental data.

  11. Tl, Bi, and Pb doping in Ba4BiPb2TlO12-δ

    International Nuclear Information System (INIS)

    Sutto, T.E.; Averill, B.A.

    1992-01-01

    To determine the effects of different 6s metal concentrations on the superconducting nature of Ba 4 BiPb 2 TlO 12-δ , materials produced via four doping schemes were examined: Ba 4 Bi(Pb, Tl) 3 O 12-δ , Ba 4 -(BiPb) 3 TlO 12-δ , Ba 4 (Bi,Tl) 2 Pb 2 O 12-δ , and Ba 4 Bi x Pb 4-2x Tl x O 12-δ . For the parent compound a value of δ = 0.91 was observed, indicating that approximately 1/4 oxygen atom was missing per cubic subsection of the unit cell. For all samples, the symmetry of the parent compound changed from orthorhombic to tetragonal as the system moved away from the ideal composition. This was usually accompanied by the loss of superconductivity, which exhibited a maximum T c of 10.5 K for the parent compound Ba 4 BiPb 2 TlO 12-δ . Also reported are high-temperature magnetic susceptibility results, which are used to determine the effect of metal substitution on the density of states at the Fermi level. For each set of variants on the parent composition, the onset of superconductivity was accompanied by a significant decrease in the size of the Pauli paramagnetic signal. 16 refs., 6 figs

  12. Adsorption isotherms of pear at several temperatures

    OpenAIRE

    Mitrevski Vangelče; Lutovska Monika; Mijakovski Vladimir; Pavkov Ivan S.; Babić Mirko M.; Radojčin Milivoje T.

    2015-01-01

    The moisture adsorption isotherms of pear were determined at 15ºC, 30ºC and 45ºC using the standard static gravimetric method over a range of water activity from 0.112 to 0.920. The experimental data were fitted with isotherm equations recommended in ASAE Standard D245.5. In order to find which equation gives the best results, large number of numerical experiments were performed. After that, several statistical criteria proposed in scientific literature for...

  13. Quartz enhanced photoacoustic spectroscopy based trace gas sensors using different quartz tuning forks.

    Science.gov (United States)

    Ma, Yufei; Yu, Guang; Zhang, Jingbo; Yu, Xin; Sun, Rui; Tittel, Frank K

    2015-03-27

    A sensitive trace gas sensor platform based on quartz-enhanced photoacoustic spectroscopy (QEPAS) is reported. A 1.395 μm continuous wave (CW), distributed feedback pigtailed diode laser was used as the excitation source and H2O was selected as the target analyte. Two kinds of quartz tuning forks (QTFs) with a resonant frequency (f0) of 30.72 kHz and 38 kHz were employed for the first time as an acoustic wave transducer, respectively for QEPAS instead of a standard QTF with a f0 of 32.768 kHz. The QEPAS sensor performance using the three different QTFs was experimentally investigated and theoretically analyzed. A minimum detection limit of 5.9 ppmv and 4.3 ppmv was achieved for f0 of 32.768 kHz and 30.72 kHz, respectively.

  14. Quartz Enhanced Photoacoustic Spectroscopy Based Trace Gas Sensors Using Different Quartz Tuning Forks

    Directory of Open Access Journals (Sweden)

    Yufei Ma

    2015-03-01

    Full Text Available A sensitive trace gas sensor platform based on quartz-enhanced photoacoustic spectroscopy (QEPAS is reported. A 1.395 μm continuous wave (CW, distributed feedback pigtailed diode laser was used as the excitation source and H2O was selected as the target analyte. Two kinds of quartz tuning forks (QTFs with a resonant frequency (f0 of 30.72 kHz and 38 kHz were employed for the first time as an acoustic wave transducer, respectively for QEPAS instead of a standard QTF with a f0 of 32.768 kHz. The QEPAS sensor performance using the three different QTFs was experimentally investigated and theoretically analyzed. A minimum detection limit of 5.9 ppmv and 4.3 ppmv was achieved for f0 of 32.768 kHz and 30.72 kHz, respectively.

  15. Myocardial viability assessed by Tl-201 SPECT. Redistribution versus reinjection

    International Nuclear Information System (INIS)

    Chalela, William Azem; Pimentel, Flavio Ferrarini de Oliveira; Uchida, Augusto Hiroshi; Bottega, Augusto; Ramires, Jose Antonio Franchine; Izaki, Marisa; Moraes, Aguinaldo Pereira; Soares Junior, Jose; Giorgi, Maria C. Pinto; Moffa, Paulo Jorge; Bellotti, Giovanni; Giovanni Guido Cerri; Meneghetti, Jose Claudio

    1994-01-01

    The purpose of this study was to verify if a third series of images acquired by reinjection thallium-201, 24 h after conventional myocardial perfusion with the radioisotope, improves the identification of myocardial viability segments. The methods: we studied 30 patients, mean age 57.7 ±9.4 years, with old myocardial infarction using thallium (Tl)-201 SPECT, and we obtained three series of images (stress, redistribution after 4 h and reinjection after 24 h. Cardiac images were divided in 5 segments (apical, lateral, anterior, septal and inferior) and each one received a value by a score system according to the Tl-201 myocardial uptake (0=normal uptake; 1=mild hypoperfusion; 2=moderate hypoperfusion; 3=severe hypoperfusion or no myocardial uptake). We considered viable myocardium when the uptake of Tl-201 in the segment related to te myocardial infarction increases at least 1 point in two different axis of Tl-201 SPECT. The results: seven (23,3%) patients demonstrated increase of Tl-201 uptake only at reinjection images, showing a high efficacy of the method. Nine (30%) patients showed persistent hypoperfusion at all series of images suggesting only fibrosis in the are related to the infarction. Fourteen (46,7%) patients showed increase of Tl-201 concentration at redistribution images; among these patients, six showed improvement of myocardial uptake at reinjection. This condition was interpreted as regional chronic ischemic process: hibernating myocardium. The conclusion was that Tl-201 hypoperfusion at redistribution images without significant changes in relation to the stress images do not represent fibrosis at all. The reinjection technic was better than conventional redistribution in the detection of viable myocardium. This data allows a better therapeutic orientation. (author)

  16. Development of tailor-made silica fibres for TL dosimetry

    International Nuclear Information System (INIS)

    Bradley, D.A.; Abdul Sani, Siti F.; Alalawi, Amani I.; Jafari, S.M.; Noor, Noramaliza M.; Hairul Azhar, A.R.; Mahdiraji, Ghafour Amouzad; Tamchek, Nizam; Ghosh, S.; Paul, M.C.; Alzimami, Khalid S.; Nisbet, A.; Maah, M.J.

    2014-01-01

    The Ge dopant in commercially available silica optical fibres gives rise to appreciable thermoluminscence (TL), weight-for-weight offering sensitivity to MV X-rays several times that of the LiF dosimeter TLD100. The response of these fibres to UV radiation, X-rays, electrons, protons, neutrons and alpha particles, with doses from a fraction of 1 Gy up to 10 kGy, have stimulated further investigation of the magnitude of the TL signal for intrinsic and doped SiO 2 fibres. We represent a consortium effort between Malaysian partners and the University of Surrey, aimed at production of silica fibres with specific TL dosimetry applications, utilizing modified chemical vapour deposition (MCVD) doped silica–glass production and fibre-pulling facilities. The work is informed by defect and dopant concentration and various production dependences including pulling parameters such as temperature, speed and tension; the fibres also provide for spatial resolutions down to <10 µm, confronting many limitations faced in use of conventional (TL) dosimetry. Early results are shown for high spatial resolution (∼0.1 mm) single-core Ge-doped TL sensors, suited to radiotherapy applications. Preliminary results are also shown for undoped flat optical fibres of mm dimensions and Ge-B doped flat optical fibres of sub-mm dimensions, with potential for measurement of doses in medical diagnostic applications. - Highlights: • Optical fibres tailor-made for TL dosimetry. • Sensitive to diagnostic as well as therapy doses in medicine. • Preform and fibre pulling facilities. • Relative TL and EPR measurements

  17. Multiple stable isotope fronts during non-isothermal fluid flow

    Science.gov (United States)

    Fekete, Szandra; Weis, Philipp; Scott, Samuel; Driesner, Thomas

    2018-02-01

    Stable isotope signatures of oxygen, hydrogen and other elements in minerals from hydrothermal veins and metasomatized host rocks are widely used to investigate fluid sources and paths. Previous theoretical studies mostly focused on analyzing stable isotope fronts developing during single-phase, isothermal fluid flow. In this study, numerical simulations were performed to assess how temperature changes, transport phenomena, kinetic vs. equilibrium isotope exchange, and isotopic source signals determine mineral oxygen isotopic compositions during fluid-rock interaction. The simulations focus on one-dimensional scenarios, with non-isothermal single- and two-phase fluid flow, and include the effects of quartz precipitation and dissolution. If isotope exchange between fluid and mineral is fast, a previously unrecognized, significant enrichment in heavy oxygen isotopes of fluids and minerals occurs at the thermal front. The maximum enrichment depends on the initial isotopic composition of fluid and mineral, the fluid-rock ratio and the maximum change in temperature, but is independent of the isotopic composition of the incoming fluid. This thermally induced isotope front propagates faster than the signal related to the initial isotopic composition of the incoming fluid, which forms a trailing front behind the zone of transient heavy oxygen isotope enrichment. Temperature-dependent kinetic rates of isotope exchange between fluid and rock strongly influence the degree of enrichment at the thermal front. In systems where initial isotope values of fluids and rocks are far from equilibrium and isotope fractionation is controlled by kinetics, the temperature increase accelerates the approach of the fluid to equilibrium conditions with the host rock. Consequently, the increase at the thermal front can be less dominant and can even generate fluid values below the initial isotopic composition of the input fluid. As kinetics limit the degree of isotope exchange, a third front may

  18. Passivation of quartz for halogen-containing light sources

    Science.gov (United States)

    Falkenstein, Zoran

    1999-01-01

    Lifetime of halogen containing VUV, UV, visible or IR light sources can be extended by passivating the quartz or glass gas containers with halogens prior to filling the quartz with the halogen and rare gas mixtures used to produce the light.

  19. Refractometry characteristics of α-quartz after neutron irradiation

    International Nuclear Information System (INIS)

    Abdkadyrova, I.Kh.

    1997-01-01

    Lattice structure distortions in irradiated crystalline quartz were studied by refractometry methods. The refractometry constants of α-quartz for the flux of fast neutrons 10 18 - 10 21 neutron/cm 2 were calculated. The critical kinetics of this constants at the phase transformation is observed.(author). 5 refs., 1 fig

  20. Activation analysis of high pure quartz used as packing materials

    International Nuclear Information System (INIS)

    Luknitskij, V.A.; Morozov, B.A.

    1979-01-01

    A γ-spectrometric technique of neutron activation determination of microelements in quartz tubes used as a packing material for irradiation in reactors is reported. The analysis of 29 micro-admixtures in quartz tubes of USSR brands ''spectrtosil'' and ''KV'' was carried out. The γ-spectra of ''KV'' quartz irradiated by thermal and epithermal neutrons are presented. The activation by epithermal neutrons provides an activity gain for the nuclei whose resonance integral is high enough as compared to the activation cross-section with regard to thermal neutrons. The activation by epithermal neutrons permits additional determination of W, Cd, V, Th, Mn and Ni and provides for a substantial decrease in the activity of 24 Na, 42 K, 140 La, 46 Sc, 141 Ce, 51 Cr, and 59 Fe, which hinder the determination of the above-mentioned elements. The microelement composition of Soviet-made quartz varieties is compared to that of foreign-made quartz brands

  1. Microwave GaAs Integrated Circuits On Quartz Substrates

    Science.gov (United States)

    Siegel, Peter H.; Mehdi, Imran; Wilson, Barbara

    1994-01-01

    Integrated circuits for use in detecting electromagnetic radiation at millimeter and submillimeter wavelengths constructed by bonding GaAs-based integrated circuits onto quartz-substrate-based stripline circuits. Approach offers combined advantages of high-speed semiconductor active devices made only on epitaxially deposited GaAs substrates with low-dielectric-loss, mechanically rugged quartz substrates. Other potential applications include integration of antenna elements with active devices, using carrier substrates other than quartz to meet particular requirements using lifted-off GaAs layer in membrane configuration with quartz substrate supporting edges only, and using lift-off technique to fabricate ultrathin discrete devices diced separately and inserted into predefined larger circuits. In different device concept, quartz substrate utilized as transparent support for GaAs devices excited from back side by optical radiation.

  2. Using the OSL single-aliquot regenerative-dose protocol with quartz extracted from building materials in retrospective dosimetry

    International Nuclear Information System (INIS)

    Boetter-Jensen, L.; Solongo, S.; Murray, A.S.; Banerjee, D.; Jungner, H.

    2000-01-01

    We report on the application of the single-aliquot regenerative-dose (SAR) protocol to the optically stimulated luminescence signal from quartz extracted from fired bricks and unfired mortar in retrospective dosimetry. The samples came from a radioactive materials storage facility, with ambient dose rates of about 0.1 mGy/h. A detailed dose-depth profile was analysed from one brick, and compared with dose records from area TL dosemeters. Small-aliquot dose-distributions were analysed from the mortar samples; one associated with the exposed brick, and one from a remote site exposed only to background radiation. We conclude that unfired materials have considerable potential in retrospective dosimetry

  3. Point defects and the blue emission in fired quartz at high doses: a comparative luminescence and EPR study

    International Nuclear Information System (INIS)

    Woda, C.; Schilles, T.; Riser, U.; Mangini, A.; Wagner, G.A.

    2002-01-01

    The dose response of the 375 deg/ C, 470 nm TL peak in fired quartz is studied by using thermoluminescence emission spectra and monochromatic glow curves. The blue emission displays a significant sensitivity increase for doses in excess of 1000 Gy, subsequent saturation at 16 kGy and a pre-dose effect over the entire dose range. Comparison with the growth of the known electron paramagnetic resonance centres and radioluminescence emission spectra indicates that the [AlO 4 ] centre is the recombination site for the blue emission, whereas the electron trap remains unknown. The sensitivity change seems to be linked to the dose-induced reduction of the [GeO 4 /Li] centre. Possible mechanisms for the observed dose response are discussed. (author)

  4. TL studies of quaternary biogenic carbonate deposits of Saurashtra, Western India

    International Nuclear Information System (INIS)

    Patel, M.P.; Bhatt, Nilesh; Murthy, K.V.R.

    1992-01-01

    The quaternary biogenic carbonate deposits of Saurashtra, coastal as well as inland, comprise the beach rocks, miliolites and the stabilised sand dunes. The beach rocks contain the varieties of megafossils and broken shell fragments while the miliolites are granular made up of medium to fine grained, well sorted, abraded to finely abraded and even pelletised microfossils and shell fragments. The various constituents of the beach rocks and miliolites are cemented together by a fine calcite cement. The carbonate sand dunes contain relatively less amount of biogenic material and are rich in quartz. Age wise, the well consolidated beach rocks and miliolites are older (middle to later upper pleistocene) as compared to poorly consolidated coastal stabilised younger sand dunes (holocene). Chemically the former are rich in CaCO 3 while the latter are rich in SiO 2 . TL studies of the representative samples of beach rocks, miliolites and sand dunes clearly suggest that the glow curves of beach rocks and miliolites differ from that of sand dunes. Again, the existence of close similarity between the ATL/NTL curves for beach rocks and miliolites substantiate their close affinity in the field. (author). 14 refs., 2 tabs., 2 figs

  5. Sequence crystallization during isotherm evaporation of southern ...

    African Journals Online (AJOL)

    Southern Algerian's natural brine sampled from chott Baghdad may be a source of mineral salts with a high economic value. These salts are recoverable by simple solar evaporation. Indeed, during isothermal solar evaporation, it is possible to recover mineral salts and to determine the precipitation sequences of different ...

  6. THERMODYNAMICS AND ADSORPTION ISOTHERMS FOR THE ...

    African Journals Online (AJOL)

    BAFFA

    The use of maize (Zea mays) cob for the biosorption of Cr(VI), Ni(II) and Cd(II) is ... Variations in the concentration of the different adsorbates during the adsorption process .... Langmuir isotherm is the dimensionless separation .... The use of Sago waste for the sorption of lead and copper. Water S. Afr., 24 (3), p251-256.

  7. Isothermal Titration Calorimetry in the Student Laboratory

    Science.gov (United States)

    Wadso, Lars; Li, Yujing; Li, Xi

    2011-01-01

    Isothermal titration calorimetry (ITC) is the measurement of the heat produced by the stepwise addition of one substance to another. It is a common experimental technique, for example, in pharmaceutical science, to measure equilibrium constants and reaction enthalpies. We describe a stirring device and an injection pump that can be used with a…

  8. Isothermal Gravitational Segregation: Algorithms and Specifications

    DEFF Research Database (Denmark)

    Halldórsson, Snorri; Stenby, Erling Halfdan

    2000-01-01

    New algorithms for calculating the isothermal equilibrium state of reservoir fluids under the influence of gravity are presented. Two types of specifications are considered: the specification of pressure and composition at a reference depth; and the specification of the total overall content of t...

  9. Benchmarking NaI(Tl) Electron Energy Resolution Measurements

    International Nuclear Information System (INIS)

    Mengesha, Wondwosen; Valentine, J D.

    2002-01-01

    A technique for validating electron energy resolution results measured using the modified Compton coincidence technique (MCCT) has been developed. This technique relies on comparing measured gamma-ray energy resolution with calculated values that were determined using the measured electron energy resolution results. These gamma-ray energy resolution calculations were based on Monte Carlo photon transport simulations, the measured NaI(Tl) electron response, a simplified cascade sequence, and the measured electron energy resolution results. To demonstrate this technique, MCCT-measured NaI(Tl) electron energy resolution results were used along with measured gamma-ray energy resolution results from the same NaI(Tl) crystal. Agreement to within 5% was observed for all energies considered between the calculated and measured gamma-ray energy resolution results for the NaI(Tl) crystal characterized. The calculated gamma-ray energy resolution results were also compared with previously published gamma-ray energy resolution measurements with good agreement (<10%). In addition to describing the validation technique that was developed in this study and the results, a brief review of the electron energy resolution measurements made using the MCCT is provided. Based on the results of this study, it is believed that the MCCT-measured electron energy resolution results are reliable. Thus, the MCCT and this validation technique can be used in the future to characterize the electron energy resolution of other scintillators and to determine NaI(Tl) intrinsic energy resolution

  10. Coronal Loops: Evolving Beyond the Isothermal Approximation

    Science.gov (United States)

    Schmelz, J. T.; Cirtain, J. W.; Allen, J. D.

    2002-05-01

    Are coronal loops isothermal? A controversy over this question has arisen recently because different investigators using different techniques have obtained very different answers. Analysis of SOHO-EIT and TRACE data using narrowband filter ratios to obtain temperature maps has produced several key publications that suggest that coronal loops may be isothermal. We have constructed a multi-thermal distribution for several pixels along a relatively isolated coronal loop on the southwest limb of the solar disk using spectral line data from SOHO-CDS taken on 1998 Apr 20. These distributions are clearly inconsistent with isothermal plasma along either the line of sight or the length of the loop, and suggested rather that the temperature increases from the footpoints to the loop top. We speculated originally that these differences could be attributed to pixel size -- CDS pixels are larger, and more `contaminating' material would be expected along the line of sight. To test this idea, we used CDS iron line ratios from our data set to mimic the isothermal results from the narrowband filter instruments. These ratios indicated that the temperature gradient along the loop was flat, despite the fact that a more complete analysis of the same data showed this result to be false! The CDS pixel size was not the cause of the discrepancy; rather, the problem lies with the isothermal approximation used in EIT and TRACE analysis. These results should serve as a strong warning to anyone using this simplistic method to obtain temperature. This warning is echoed on the EIT web page: ``Danger! Enter at your own risk!'' In other words, values for temperature may be found, but they may have nothing to do with physical reality. Solar physics research at the University of Memphis is supported by NASA grant NAG5-9783. This research was funded in part by the NASA/TRACE MODA grant for Montana State University.

  11. Phytotoxicity of thallium (Tl) in culture solution. Pt. 2. Effects of Tl(III) on the growth and heavy metal contents of pea and field bean plants

    Energy Technology Data Exchange (ETDEWEB)

    Pieper, B; Austenfeld, F A

    1985-01-01

    The effects of Tl(NO/sub 3/)/sub 3/ and Tl(III)EDTA on growth and heavy metal contents of pea plants and field bean plants were compared in hydroponic culture experiments. In the presence of Tl(NO/sub 3/)/sub 3/, the essential heavy metals were available to the plants in their ionic forms. When Tl(III)EDTA was present the essential heavy metals were available as chelated complexes. Dry matter production of the pea plants was inhibited to a greater extent by Tl(III)EDTA than by Tl(NO/sub 3/)/sub 3/. The distribution of Tl within the plant was unaffected by the accompanying anion, however an increase of the Tl content of the stems and the leaves was observed in the presence of Tl(III)EDTA. The micronutrients exhibited different interactions with Tl(III). In the presence of increasing concentrations of Tl(NO/sub 3/)/sub 3/ the Mn content of each organ and the Zn content of the roots were lowered, but the Zn content of the stems was increased. Increasing concentrations of Tl(III)EDTA resulted only in a decrease of the Mn content of the roots, but in an increase of the contents of Fe and Mn within the stems, and Fe, Mn, Zn, and Cu within the leaves. The increases may be due to concentration by growth inhibition. In contrast to pea plants, growth of field bean plants was inhibited only by Tl(NO/sub 3/)/sub 3/. The field bean plants retained most of the Tl within the roots independent of the Tl compound in the solution. Chelation of Tl(III) resulted in higher Tl contents of both the roots and the stems, but equal or reduced Tl contents of the leaves. Whereas increasing concentrations of Tl(NO/sub 3/)/sub 3/ reduced the Mn content of each organ as well as the Zn content of the roots and the leaves, Tl(III)EDTA only reduced the Mn content of the roots.

  12. Ab initio calculations of the electron spectrum and density of states of TlFeS{sub 2} and TlFeSe{sub 2} crystals

    Energy Technology Data Exchange (ETDEWEB)

    Ismayilova, N. A., E-mail: ismayilova-narmin-84@mail.ru; Orudjev, H. S.; Jabarov, S. H. [Azerbaijan National Academy of Sciences, Institute of Physics (Azerbaijan)

    2017-04-15

    The results of ab initio calculations of the electron spectrum of TlFeS{sub 2} and TlFeSe{sub 2} crystals in the antiferromagnetic phase are reported. Calculations are carried out in the context of the density functional theory. The origin of the bands of s, p, and d electron states of Tl, Fe, S, and Se atoms is studied. It is established that, in the antiferromagnetic phase, the crystals possess semiconductor properties. The band gaps are found to be 0.05 and 0.34 eV for TlFeS{sub 2} and TlFeSe{sub 2} crystals, respectively.

  13. Stability of Tl-Ba-Ca-Cu-O Superconducting Thin Films

    Energy Technology Data Exchange (ETDEWEB)

    Siegal, M.P.; Overmyer, D.L.; Venturini, E.L.; Padilla, R.R.; Provencio, P.N.

    1999-08-23

    We report the stability of TlBa{sub 2}CaCu{sub 2}O{sub 7} (Tl-1212) and Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8} (T1-2212) thin films and by inference, the stability of TlBa{sub 2}Ca{sub 2}Cu{sub 3}O{sub 9} (Tl-1223) and Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} (Tl-2223) thin films, under a variety of conditions. In general, we observe that the stability behavior of the single Tl-O layer materials (Tl-1212 and Tl-1223)are similar and the double Tl-O layer materials (Tl-2212 and Tl-2223) are similar. All films are stable with repeated thermal cycling to cryogenic temperatures. Films are also stable in acetone and methanol. Moisture degrades film quality rapidly, especially in the form of vapor. Tl-1212 is more sensitive to vapor than Tl-2212. These materials are stable to high temperatures in either N{sub 2}, similar to vacuum for the cuprates, and O{sub 2} ambients. While total degradation of properties (superconducting and structural) occur at the same temperatures for all phases, 600 C in N{sub 2} and 700 C in O{sub 2}, the onset of degradation occurs at somewhat lower temperatures for Tl-1212 than for Tl-2212 films. In all cases, sample degradation is associated with Tl depletion from the films.

  14. EPR and TL correlation in some powdered Greek white marbles

    International Nuclear Information System (INIS)

    Baieetto, Vanessa; Villeneuve, Gerard; Guibert, Pierre; Schvoerer, Max

    2000-01-01

    Thermoluminescence of white powdered marble samples, chosen to display different EPR spectra, were studied. Two peaks at 280 deg. C and 360 deg. C can be observed among the TL glow curves while the EPR spectra exhibit two signals: the A signal with g perp =2.0038 and g par =2.0024 due to the SO - 3 centre and the B one with g 1 =2.0005; g 2 =2.0001; g 3 =1.9998 due to mechanical powder reduction (drilling). Owing to heating and simultaneous experiments, a correlation have been established: the 280 deg. C TL peak is associated to the A signal and thus to the SO - 3 centre and the 360 deg. C TL peak is caused by mechanical treatment corresponding to the B EPR signal

  15. EPR and TL correlation in some powdered Greek white marbles

    Energy Technology Data Exchange (ETDEWEB)

    Baieetto, Vanessa E-mail: crpaa@montaigne.u-bordeaux.fr; Villeneuve, Gerard; Guibert, Pierre; Schvoerer, Max

    2000-02-01

    Thermoluminescence of white powdered marble samples, chosen to display different EPR spectra, were studied. Two peaks at 280 deg. C and 360 deg. C can be observed among the TL glow curves while the EPR spectra exhibit two signals: the A signal with g{sub perp}=2.0038 and g{sub par} =2.0024 due to the SO{sup -}{sub 3} centre and the B one with g{sub 1}=2.0005; g{sub 2}=2.0001; g{sub 3}=1.9998 due to mechanical powder reduction (drilling). Owing to heating and simultaneous experiments, a correlation have been established: the 280 deg. C TL peak is associated to the A signal and thus to the SO{sup -}{sub 3} centre and the 360 deg. C TL peak is caused by mechanical treatment corresponding to the B EPR signal.

  16. EPR and TL correlation in some powdered Greek white marbles.

    Science.gov (United States)

    Baïetto, V; Villeneuve, G; Guibert, P; Schvoerer, M

    2000-02-01

    Thermoluminescence of white powdered marble samples, chosen to display different EPR spectra, were studied. Two peaks at 280 degrees C and 360 degrees C can be observed among the TL glow curves while the EPR spectra exhibit two signals: the A signal with g perpendicular = 2.0038 and g parallel = 2.0024 due to the SO3- centre and the B one with g1 = 2.0005; g2 = 2.0001; g3 = 1.9998 due to mechanical powder reduction (drilling). Owing to heating and simultaneous experiments, a correlation have been established: the 280 degrees C TL peak is associated to the A signal and thus to the SO3- centre and the 360 degrees C TL peak is caused by mechanical treatment corresponding to the B EPR signal.

  17. Stability of detecting system using NaI(Tl)

    International Nuclear Information System (INIS)

    Zhuo Yunshang; Lei Zhangyun; Zen Yu; Gong Hua

    1996-01-01

    A detecting system using NaI(Tl) is widely used in research and industry of nuclear science and other fields. For providing the high accuracy and working well under inclement environment, the stability of detecting system using NaI(Tl) is very important. The variation of environment temperature, the change of counting rate and long time continuous working of detector will cause un-negligible effect on the measurement. Three approaches were used. They are: 1) temperature control (It makes the effect of the variation of environment temperature on the measurement negligible.); 2) spectrum stabilizing (It adjust the peak position of the spectrum when the counting rate changes.); and 3) auto-checking and adjusting (It adjusts the drift of the NaI(Tl) detecting system when it works continuously)

  18. Standardization of 201Tl and 55Fe radionuclides in a 4 (PC)-NaI(Tl) coincidence system

    International Nuclear Information System (INIS)

    Pires, Carlos Augusto

    2008-01-01

    In the present work the procedure for the standardization of radionuclides using the 4π(PC)-NaI(Tl) coincidence system was developed. The radionuclides selected were 201 Tl, used in nuclear medicine, and 55 Fe primary standard source, used for x-ray spectrometers calibration. The 4π(PC)-NaI(Tl) is composed of a 4 proportional counter operated at 0.1MPa coupled to two NaI(Tl) crystals. The 201 Tl decays by electron capture process followed by a prompt gamma-ray. The disintegration rate was determined by extrapolation technique using two methods: electronic discrimination and external absorbers. The radioactive sources were prepared in a 20 μg cm -2 thick Collodion film. The conventional electronic system was used. The observed events were registered by the TAC method. The 55 Fe decays by electron capture process to the ground state of 55 Mn, emitting x rays with around 6 keV. The standardization was obtained by the tracing method. This technique was applied using two radionuclides, which decay by electron capture process followed by a prompt gamma-ray, namely 51 Cr and 54 Mn, as tracers. Measurements with 1 and 2 aluminum foils, each 150 g cm-2 thick were carried out. The activity was obtained by extrapolation for zero thickness Al foil. The uncertainties were treated by means of matrix covariance methodology and takes into account all correlations involved. (author)

  19. Radiation resisting features of pure quartz fiber

    International Nuclear Information System (INIS)

    Fujii, Takashi; Nagasawa, Yoshiya; Hoshi, Hiroshi; Tomon, Ryoichi; Ooki, Yoshimichi; Yahagi, Kichinosuke

    1985-01-01

    The control of the generation of color centers is essential for optical fibers used in radiation environment. Even pure quartz which is the best radiation resisting material is not exceptional also elucidarion of the mechanism of the generation of color center is necessary for the development of optical fiber with higher radiation resisting feature. Previously, it was assumed that color centers are distributed uniformly throughout cores. Determination of the distribution of color centers was attempted. Cores were etched with HF after γ-ray irradiation, and the changes of intensity of ESR signals of NBOHC and E'-center were determined. NBOHC were not found in circumferential part, and concentrated in the central part. In other words the tendency of distribution is diametral. Thus, the distribution of precursor is supposed to be affected by certain external cause and the generation of NBOHC was depressed in circumferential area. The distribution of E'-center of high OH sample showed similar tendency and high in the center. Where as the distribution in low OH sample was uniform. The external cause is supposed to be hydrogen derived from silicone clad and silicone buffer. Two kind of precursor is suspected for the explanation of the difference of the E'-center in high OH sample and low OH sample. (Ishimitsu, A.)

  20. Comparison of radiation-induced colouration images, thermoluminescence, and after-glow colour images with aluminium impurity distribution in Japanese twin quartzes

    International Nuclear Information System (INIS)

    Hashimoto, Tetsuo; Ojima, Tetsu; Takahashi, Eishi; Konishi, Masayoshi; Kanemaki, Motoko.

    1995-01-01

    After-glow colour images (AGCI) and thermoluminescence (TL) from Japanese twin quartz slices have been successfully photographed by means of a commercially available negative colour film after the irradiation of X-rays. After-glow colour images (AGCI) offered very interesting distinction of colour images; the core part showed the colour changed from sky blue with zonal orange to blue with increasing absorbed doses, whereas the outer parts maintained orange AG colour giving clear boundary. On the other hand, the radiation-induced colour (blackish or brownish) center image (CCI) appeared at the core portion, while thermoluminescence colour images (TLCI) also consisted of two portions distinguishable into stripe and zonal bluish core and faint TL emission part in outer ones. These luminescence colour images, probably reflecting the formation mechanism of Japanese twin quartzes, are evidently correlated with the concentration patterns of aluminium impurity obtained by an EPMA (electron probe microanalyzer) method. From these radiation-induced images, it was assumed that the conditions of crystal formation should be greatly different between the core and the outer parts; the outer parts were secondarily started to grow from hydrothermal solution with higher Al-concentration after the initial formation of single core. (author)

  1. Magnetism and superconductivity of some Tl-Cu oxides

    Science.gov (United States)

    Datta, Timir

    1991-01-01

    Many copper oxide based Thallium compounds are now known. In comparison to the Bi-compounds, the Tl-system shows a richer diversity; i.e., High Temperature Superconductors (HTSC) can be obtained with either one or two Tl-0 layers (m = 1,2); also, the triple-digit phases are easier to synthesize. The value of d, oxygen stoichiometry, is critical to achieving superconductivity. The Tl system is robust to oxygen loss; Tl may be lost or incorporated by diffusion. A diffusion coefficient equal to 10 ms at 900 C was determined. Both ortho-rhombic and tetragonal structures are found, but HTSC behavior is indifferent to the crystal symmetry. This system has the highest T(sub c) confirmed. T(sub c) generally increases with p, the number of CuO layers, but tends to saturate at p = 3. Zero resistance was observed at temperatures as great as 125 K. Most of these HTSC's are hole type, but the Ce-doped specimens may be electronic. The magnetic aspects were studied; because in addition to defining the perfectly diamagnetic ground state as in conventional superconductors, magnetism of the copper oxides show a surprising variety. This is true of both the normal and the superconducting states. Also, due to the large phonon contribution to the specific heat at the high T(sub c) jump, electronic density of states, D(Ef), and coherence length are uncertain, and thus, are estimated from the magnetic results. Results from the Tl-system CuO, LaBaCuO,120 and the Bi-CuO compounds are discussed. The emphasis is on the role of magnetism in the Tl-CuO HTSC, but technological aspects are also pointed out.

  2. Gamma irradiation of quartz from Pannier basin, South America

    Energy Technology Data Exchange (ETDEWEB)

    Enokihara, Cyro T.; Rela, Paulo R. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)], E-mail: cteiti@ipen.br, E-mail: prela@ipen.br; Guttler, Rainer A.S. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias

    2007-07-01

    The use of gamma radiation to induce or enhance color centers in gemstones is a widespread technique and applied worldwide on a industrial scale since at least 1970. The presence of defects and defect structures in quartz from a border region of southern Brazil and Uruguay are the reason for the creation of a new color variety of quartz called 'Prasiolite' in the gem trade. This quartz has a pleasant green color produced by gamma irradiation. The procedures of irradiation at IPEN show that the activation of these color producing defects can be monitored by detailed chemical and spectroscopic analysis. For the first time UV-VIS-NIR spectra of this new color variety of quartz are shown. They revealed special features of these quartz crystals coming from basaltic terranes of the Parana Basin. Contrary to most specimen of quartz from other parts of Brazil, they have such a high water and OH content that they resemble more chalcedony or opal, but not highly crystalline quartz specimens. The cause of the color are broken bonds of Si-OH defining the so-called dangling bonds. (author)

  3. Identification of color development potential of quartz by Raman spectroscopy

    International Nuclear Information System (INIS)

    Alkmim, Danielle G.; Lameiras, Fernando S.; Almeida, Frederico O.T.

    2013-01-01

    Colorless quartz is usually exposed to ionizing radiation (gamma rays or high energy electron beams) to acquire different colors for jewelry. Color development is due to the presence of traces of some elements such as aluminum, iron, hydrogen, lithium, or sodium. Most quartz crystals are extracted colorless from nature and it is necessary to separate those that can develop colors from those that cannot. Irradiation tests can be used to accomplish this separation, but they take a long time. Infrared signature of colorless quartz can also be used. However, infrared spectroscopy is quite expensive, especially when using portable devices. Raman spectroscopy is now available as an inexpensive and portable technique that could provide identification of the samples of colorless quartz still in the field, facilitating the prediction for their economic exploitation. In addition, Raman spectroscopy usually requires a minimum or no sample preparation. This paper presents an investigation of the feasibility of using Raman spectroscopy as a substitute for infrared spectroscopy to predict the potential for color development of quartz. A band at 3595 cm -1 in the Raman shift spectrum was observed only along the c axis of a prasiolite excited by a high power 514 nm laser. This band was not observed in quartz samples that do not develop color after irradiation. Further studies are required to identify the potential for color development by Raman spectroscopy of other types of colorless quartz. (author)

  4. Expanding the Teaching Commons: Making the Case for a New Perspective on SoTL

    Directory of Open Access Journals (Sweden)

    Kim A. Case, PhD

    2013-08-01

    Full Text Available As a reflection on O’Meara, Terosky, and Neumann’s (2011 work on scholarship of teaching and learning (SoTL faculty development, this essay describes the benefits of SoTL to individual faculty and university goals. In support and expansion of arguments advanced by O’Meara et al., this work calls for the use of SoTL faculty development to promote the shared teaching commons, active recruitment of new SoTL scholars, institutionalization of SoTL values, and integration of SoTL initiatives in both teaching centers and research-focused development offices.

  5. Isotopically exchangeable phosphorus as a correction value to adsorption isotherms

    International Nuclear Information System (INIS)

    Lopez, S.C.; Barbaro, N.O.; Rojas de Tramontini, S.L.; Martini, O.

    1984-01-01

    Adsorption isotherms in evaluation and characterization of soils are studied. The quantity of phosphorus present at first in soil, evaluated by radioisotopic techniques and used in correction of Langmuir and Freundlich isotherms, is discussed. (M.A.C.) [pt

  6. M1 transitions between superdeformed states in 195Tl

    International Nuclear Information System (INIS)

    Zheng Xing; Xingqu Chen; Xiaochun Wang

    1996-01-01

    Using a triaxial-particle-rotor model, the quadrupole and dipole transition energies, kinematic and dynamic moments of inertia, electromagnetic transition probabilities and the relative intensity of the E2 γ-transitions are calculated for superdeformed bands in 195 Tl. A strong perturbation effect of rotation on transition energies and M1 and E2 transitions of superdeformed states is investigated. The total M1 transitions, enhanced by internal conversion, are expected to compete strongly with the E2 γ-ray at low spins in the superdeformed 195 Tl nucleus. (author)

  7. The model of recombination process in TlBr

    International Nuclear Information System (INIS)

    Grigorjeva, L.; Millers, D.

    2002-01-01

    The time-resolved luminescence was used as a tool in the study of recombination process in several undoped TlBr crystals. The spectra and decay kinetics observed under electron beam excitation were investigated. Observation of several luminescence bands with different decay rates shows that more than one recombination center is involved and the recombination process is quite complicated. The band at ∼2.5 eV is dominant under 10 ns excitation pulse (electron beam or nitrogen laser pulses). The results of short-lived absorption and luminescence are used for analysis of possible mechanisms of recombination processes in TlBr

  8. Portable in situ NaI(Tl) γ spectroscopy system

    International Nuclear Information System (INIS)

    Wang Bairong; Dong Binjiang; Zeng Liping; Shen Tingyun

    2000-01-01

    The author describes a portable in situ NaI(Tl) γ spectroscopy system, which consists of a NaI (Tl) scintillation detector, an integrative spectroscopy card, a notebook computer and spectroscopy software. The spectrometer addresses applications in environmental or nuclear accident in situ γ spectroscopy measurements, and gives valid quantitative results of radionuclide concentrations per unit volume (Bq/kg) or unit area (Bq/cm 2 ) in the soil and absorbed dose rate in air at 1 m above ground (Gy/h)

  9. Anisotropic superconducting state parameters of Tl-2212 superconductors

    International Nuclear Information System (INIS)

    Khaskalam, Amit K.; Singh, R.K.; Varshney, Dinesh

    2001-01-01

    We have estimated the superconducting state parameters and their anisotropy in thallium based superconductors (Tl-2212), in the frame work of Fermi liquid approach. Determination of the effective mass of the charge carriers from the Fermi velocity and estimated anisotropic superconducting state parameters, particularly, the magnetic penetration depth along and perpendicular to the conducting plane. The coherence length along and perpendicular to the ab plane is evaluated and appears to be higher. The temperature dependence of penetration depth, their anisotropy and Ginsburg Landau parameter for optimised doped Tl based cuprates shows the power law. The technique permits a consistency with the reported data. (author)

  10. Coronary spasm: 201Tl scintiscanning following pharmacological provocation

    International Nuclear Information System (INIS)

    Montz, R.; Mathey, D.; Bleifeld, W.; Hamburg Univ.

    1981-01-01

    According to the authors' experience so far, 201 Tl myocardial scintiscanning is a sufficiently sensitive non-invasive method for detection of coronary vasospasm provoked by ergotamine administration. Mild incomplete and asymptotic forms of coronary vasospasm were detected by scintiscanning. Indications for myocardial scintiscanning of ergotamine-provoked vasospasm are: Cases of angina pectoris at rest in which electrocardiograms during spasm are not available; elleviated symptoms after nitroglycerine administration; exercise electrocardiograms without any sign of ischaemia; negative results of exercise 201 Tl myocardial scintiscanning. (orig.) [de

  11. Thermoluminescence (TL) in the identification of irradiated food

    International Nuclear Information System (INIS)

    Luthra, J.M.

    1992-01-01

    Due to progressive expansion of commercial food irradiation in recent years, the interest in detecting whether a food has been irradiated or not is growing fast and research in several methods for identification of various irradiated food stuffs is the order of the day. TL has emerged as one of the most promising tool for distinguishing between irradiated and unirradiated food. Advantages of TL method over other physical methods, its application to various foods, limitation and present state of art are discussed.(author). 9 refs., 3 tabs

  12. Automation of TL brick dating by ADAM-1

    International Nuclear Information System (INIS)

    Cechak, T.; Gerndt, J.; Hirsl, P.; Jirousek, P.; Kubelik, M.; Musilek, L.; Kanaval, J.

    2000-01-01

    Thermoluminescence has become an established dating method for ceramics and more recently for bricks. Based on the experiences of the work carried out since the late 1970's at the Rathgen-Forschungslabor in Berlin on the dating of bricks from historic architecture, and after evaluating all commercially available and some individually built automated and semi-automated TL-readers, a specially adapted machine for the fine grain dating of bricks was constructed in an interdisciplinary research project, undertaken by a team recruited from three faculties of the Czech Technical University in Prague. The result is the automated TL-reader ADAM-1 (Automated Dating Apparatus for Monuments) for the dating of historic architecture. Both the specific adaptation of the technique and the necessary optimal automation have influenced the design of this TL-reader. The principle advantage of brick as opposed to ceramic TL-dating emerges from the possibility of being able to obtain both a large number of samples and an above average quantity of datable material from each sample. This, together with the specific physical and chemical conditions in a brick wall, allowed a rethinking of the traditional error calculation and thus lower error margins as those obtained when dating ceramic shards. The TL-reader must therefore be able to measure and evaluate automatically numerous samples. The annular sample holder of ADAM-1 has 60 sample positions, which allow the irradiation and evaluation of samples taken from two locations. The thirty samples from one sampling point are divided into subgroups, which are processed in various ways. Three samples serve for a rough estimate of the TL sensitivity of the brick material. Nine samples are used for the measurement of 'natural TL' of the material. A further nine samples are used for testing the sensitivity of the material to beta radiation. The last nine samples serve for the testing of the sensitivity to alpha radiation. To determine the

  13. Linear expansion, specific heat and thermodynamic properties of the CdTl2Te4 compound

    International Nuclear Information System (INIS)

    Karimov, S.K.

    1979-01-01

    Presented are the results of studying temperature dependence of the thermal expansion coefficient for poly- and monocrystalline samples of CdTl 2 Te 4 . The coefficient of linear expansion in a perpendicular direction to the axis of growth (0010) is shown to be larger than the coefficient of linear expansion along the axis. Temperature dependence of thermal capacity (Csub(p)(T)) has been obtained, which is used to plot tables of adjusted values of Csub(p)(T); the values of entropy and enthalpy are calculated. Standard values of these parameters are as follows: Csub(p)=42.90 cal/molxgrad; Ssub(298.15K)sup(.)=78.95+-0.32 cal/mol, and Δsub(298.15K)sup(.)=10629+-31 cal/mol. Lattice contribution and thermal expansion contribution into thermal capacity are calculated. Determined are Debye characteristic temperature, isothermal coefficient of compressibility, and Grueneisen constant. The calculations testify to the prevalence of the repulsive force along the axis (0010) over the attractive force

  14. Alpha efficiency under TL and OSL - A subtraction technique using OSL and TL to detect artificial irradiation

    International Nuclear Information System (INIS)

    Zink, A.J.C.; Dabis, S.; Porto, E.; Castaing, J.

    2010-01-01

    With the development of thermoluminescence (TL) and optically stimulated luminescence (OSL) to determine the authenticity of old ceramics, forgers use artificial irradiation by gamma ray to age modern productions. Besides fraudulent action, objects can be exposed to various sources of X-rays (e.g. radiography, security control at airports). For all these reasons, the determination of artificial irradiation is an important topic for dating art objects. The main technique to identify artificial irradiations is the subtraction technique. It is based on the fact that alpha efficiency varies according to the luminescence technique (fine grain, coarse grains, predose, OSL). Having observed a rather significant difference of alpha efficiency for TL and OSL, we propose a new subtraction technique using OSL and TL of fine grains.

  15. Kinetics of first order phase transformation in metals and alloys. Isothermal evolution in martensite transformation

    International Nuclear Information System (INIS)

    Iwasaki, Hiroshi; Ohshima, Ken-ichi

    2011-01-01

    The 11th lecture about microstructures and fluctuation in solids reports on the martensitic phase transformation of alkali metals and alloys. The martensitic transformation is a diffusionless first order phase transformation. Martensitic transformations are classified into two with respect to kinetics, one is isothermal transformation and the other is athermal transformation. The former transformation depends upon both temperature and time, but the latter solely depends on temperature. The former does not have a definite transformation start temperature but occurs after some finite incubation time during isothermal holding. The isothermal martensitic transformation is changed to the athermal one under high magnetic field, and also the reverse transformation occurs under the application of hydrostatic pressure. The former phenomena were observed in Fe-Ni-Mn alloys, Fe-Ni-Cr alloys and also the reverse transformation in Fe-3.1at%Ni-0.5at%Mn alloys. The athermal transformation was observed in Li and Na metals at 73 and 36 K, respectively. A neutron diffraction study has been performed on single crystals of metallic Na. On cooling the virgin sample, the incubation time to transform from the bcc structure to the low-temperature structure (9R structure) is formed to be more than 2h at 38 K, 2 K higher than the transformation temperature of 36 K. The full width of half maximum of the Bragg reflection suddenly increased, due to some deformation introduced by the nucleation of the low-temperature structure. In relation to the deformation, strong extra-diffuse scattering (Huang scattering) was observed around the Bragg reflection in addition to thermal diffuse scattering. The kinetics of the martensitic transformation in In-Tl alloys has been studied by x-ray and neutron diffraction methods. A characteristic incubation time appeared at fixed temperature above Ms, the normal martensitic transformation start temperature. (author)

  16. Isothermal calorimetry on enzymatic biodiesel production

    DEFF Research Database (Denmark)

    Fjerbæk, Lene

    2008-01-01

    information about effects taking place when using lipases immobilized on an inert carrier for transesterification of a triglyceride and an alcohol as for biodiesel production. The biodiesel is produced by rapeseed oil and methanol as well as ethanol and a commercial biocatalyst Novozym 435 from Novozymes...... containing a Candida Antarctica B lipase immobilized on an acrylic resin. The reaction investigated is characterized by immiscible liquids (oil, methanol, glycerol and biodiesel) and enzymes imm. on an inert carrier during reaction, which allows several effects to take place that during normal reaction...... conditions can not be elucidated. These effects have been observed with isothermal calorimetry bringing forth new information about the reaction of enzymes catalyzing transesterification. Enzymatic biodiesel production has until now not been investigated with isothermal microcalorimetry, but the results...

  17. Vortex states of Tl2Ba2CuO6+δ studied via 205Tl NMR at 2 tesla

    International Nuclear Information System (INIS)

    Itoh, Yutaka; Michioka, Chishiro; Yoshimura, Kazuyoshi; Hayashi, Akihiko; Ueda, Yutaka

    2005-01-01

    We report a 205 Tl NMR study of vortex states in an aligned polycrystalline sample of an overdoped high-T c superconductor, Tl 2 Ba 2 CuO 6+δ (Tc - 85 K), at a magnetic field of 2 T along the c axis. We observed an imperfect vortex lattice, so-called Bragg glass, at T=5 K, the coexistence of vortex solid and vortex liquid between 10 and 60 K, and vortex melting between 65 and 85 K. No evidence for local antiferromagnetic ordering at vortex cores was found for our sample. (author)

  18. Moisture sorption isotherms of dehydrated whey proteins

    OpenAIRE

    Suzana Rimac Brnčić; Vesna Lelas; Zoran Herceg; Marija Badanjak

    2010-01-01

    Moisture sorption isotherms describe the relation between the moisture content of the dry material (food) and relative humidity of the surrounding environment. The data obtained are important in modelling of drying process conditions, packaging and shelf-life stability of food that will provide maximum retaining of aroma, colour and texture as well as nutritive and biological value. The objective of this research was to establish the equilibrium moisture content and water activity, as well as...

  19. Fragmentation in rotating isothermal protostellar clouds

    International Nuclear Information System (INIS)

    Bodenheimer, P.; Black, D.C.

    1980-01-01

    In this paper we report briefly the results of an extensive set of 3-D hydrodynamic calculations that have been performed during the past two and one-half years to investigate the susceptibility of rotating clouds to gravitational fragmentation. Because of the immensity of parameter space and the expense of computations, we have chosen to restrict this investigation to strictly isothermal collapse sequences. (orig./WL)

  20. Local galactic kinematics: an isothermal model

    International Nuclear Information System (INIS)

    Nunez, J.

    1983-01-01

    The kinematical parameters of galactic rotation in the solar neighborhood and the corrections to the precession have been calculated. For this purpose, an isothermal model for the solar neighborhood has been used together with the high order momenta of the local stellar velocity distribution and the Ogorodnikov-Milne model. Both have been calculated using some samples of the ''512 Distant FK4/FK4 Sup. Stars'' of Fricke (1977) and of Gliese's Gatalogue. (author)

  1. The Stellar IMF from Isothermal MHD Turbulence

    Science.gov (United States)

    Haugbølle, Troels; Padoan, Paolo; Nordlund, Åke

    2018-02-01

    We address the turbulent fragmentation scenario for the origin of the stellar initial mass function (IMF), using a large set of numerical simulations of randomly driven supersonic MHD turbulence. The turbulent fragmentation model successfully predicts the main features of the observed stellar IMF assuming an isothermal equation of state without any stellar feedback. As a test of the model, we focus on the case of a magnetized isothermal gas, neglecting stellar feedback, while pursuing a large dynamic range in both space and timescales covering the full spectrum of stellar masses from brown dwarfs to massive stars. Our simulations represent a generic 4 pc region within a typical Galactic molecular cloud, with a mass of 3000 M ⊙ and an rms velocity 10 times the isothermal sound speed and 5 times the average Alfvén velocity, in agreement with observations. We achieve a maximum resolution of 50 au and a maximum duration of star formation of 4.0 Myr, forming up to a thousand sink particles whose mass distribution closely matches the observed stellar IMF. A large set of medium-size simulations is used to test the sink particle algorithm, while larger simulations are used to test the numerical convergence of the IMF and the dependence of the IMF turnover on physical parameters predicted by the turbulent fragmentation model. We find a clear trend toward numerical convergence and strong support for the model predictions, including the initial time evolution of the IMF. We conclude that the physics of isothermal MHD turbulence is sufficient to explain the origin of the IMF.

  2. Performance of novel materials for radiation detection: Tl3AsSe3, TlGaSe2, and Tl4HgI6

    International Nuclear Information System (INIS)

    Kahler, D.; Singh, N.B.; Knuteson, D.J.; Wagner, B.; Berghmans, A.; McLaughlin, S.; King, M.; Schwartz, K.; Suhre, D.; Gotlieb, M.

    2011-01-01

    In this paper we report on the electrical characteristics of three novel ternary compounds, Tl 3 AsSe 3 (TAS), TlGaSe 2 (TGS), and Tl 4 HgI 6 (THI), pertaining to their use as radiation detectors. The details for growth and material characterization are not presented. A semiconductor based gamma ray detector requires a material with high Z, high density, high resistivity, appropriate bandgap (1.5-2 eV), low energy/electron-hole pair, and a high μτ product. CZT is currently the best semiconductor material for room temperature gamma ray spectroscopy; however, it is extremely difficult to produce large volumes of detector grade material, making it expensive and in limited supply. DNDO/DHS began searching for other materials that might perform as well as CZT but be easier to grow and in the end lower the cost. For this purpose, we investigated the above three materials as possible replacements for CZT as gamma ray detectors. The bulk resistivity, I-V curves, X-ray response, and gamma ray response measurements for doped and undoped crystals are presented and discussed. TAS shows good X-ray and gamma ray response, but has poor resistivity, which results in large dark current and poor spectral response. TGS has good resistivity, but shows poor X-ray and gamma ray response. THI has excellent resistivity, shows some X-ray and gamma ray response, and has great potential as a gamma ray detector.

  3. Adsorption isotherms of pear at several temperatures

    Directory of Open Access Journals (Sweden)

    Mitrevski Vangelče

    2015-01-01

    Full Text Available The moisture adsorption isotherms of pear were determined at 15ºC, 30ºC and 45ºC using the standard static gravimetric method over a range of water activity from 0.112 to 0.920. The experimental data were fitted with isotherm equations recommended in ASAE Standard D245.5. In order to find which equation gives the best results, large number of numerical experiments were performed. After that, several statistical criteria proposed in scientific literature for estimation and selection of the best sorption isotherm equations were used. For each equation and experimental data set, the average performance index was calculated and models were ranked afterwards. After that, some statistical rejection criteria were checked (D’Agostino-Pearson test of normality, single-sample run test and significance and precision of the model parameters. The performed statistical analysis shows that the Guggenheim-Anderson-de Boer (GAB equation has the highest value of average performance index, but higher correlation between pair of parameters leads to lower precision of estimated parameters.[Projekat Ministarstva nauke Republike Srbije, br. TR 31058

  4. Effects of industrial by-product amendments on As, Cd and Tl retention/release in an element-spiked acidic soil

    International Nuclear Information System (INIS)

    Aguilar-Carrillo, Javier; Barrios, Laura; Garrido, Fernando; Garcia-Gonzalez, Maria Teresa

    2007-01-01

    To asses the efficiency of two by-products (phosphogypsum (PG) and sugar foam (SF), rich in gypsum and calcium carbonate, respectively) in the immobilization of three toxic elements (As, Cd and Tl) in an acidic soil, batch-scale sorption and desorption experiments were conducted after 18 months of in situ amendment application. The Langmuir isotherms applied for sorption studies showed that the estimated maximum sorption capacity of the elements was highest in the SF-treated samples. The amount of element retained and the percentage of extraction after TCLP tests indicated that those samples amended with sugar foam (SF and PG + SF) had the potential to immobilize As, Cd and Tl in an acidic soil with low sorptive capacity. In addition to sorption and desorption experiments, scanning electron microscopy in back-scattered electron mode (SEM-BSE) showed the formation of Al-hydroxy polymers which provides the soil with additional sorption capacity. The three target elements were associated with the Al-hydroxy polymers, probably through direct coordination or the formation of ternary complexes. By means of statistical analysis it has been found that sorption processes of As, Cd and Tl in this soil mainly depend on the treatment, whereas desorption is an element-dependent process

  5. Quartz-Enhanced Photoacoustic Spectroscopy Sensor with a Small-Gap Quartz Tuning Fork

    Directory of Open Access Journals (Sweden)

    Yu-Fei Ma

    2018-06-01

    Full Text Available A highly sensitive quartz-enhanced photoacoustic spectroscopy (QEPAS sensor based on a custom quartz tuning fork (QTF with a small-gap of 200 μm was demonstrated. With the help of the finite element modeling (FEM simulation software COMSOL, the change tendency of the QEPAS signal under the influence of the laser beam vertical position and the length of the micro-resonator (mR were calculated theoretically. Water vapor (H2O was selected as the target analyte. The experimental results agreed well with those of the simulation, which verified the correctness of the theoretical model. An 11-fold signal enhancement was achieved with the addition of an mR with an optimal length of 5 mm in comparison to the bare QTF. Finally, the H2O-QEPAS sensor, which was based on a small-gap QTF, achieved a minimum detection limit (MDL of 1.3 ppm, indicating an improvement of the sensor performance when compared to the standard QTF that has a gap of 300 μm.

  6. Development of a TL personal dosimeter identifiable PA exposure, and comparison with commercial TL dosimeters

    International Nuclear Information System (INIS)

    Kwon, J.W.; Kim, H.K.; Lee, J.K.; Kim, J.L.

    2004-01-01

    A single-dosimeter worn on the anterior surface of the body of a worker was found to significantly underestimate the effective dose to the worker when the radiation comes from the back. Several researchers suggested that this sort of underestimation can be corrected to a certain extent by using an extra dosimeter on the back. However, use of multiple dosimeters also has disadvantages such as complication in control or incurrence of extra cost. Instead of the common multi-dosimeter approach, in this study, a single dosimeter introducing asymmetric filters which enabled to identify PA exposure was designed, and its dose evaluation algorithm for AP-PA mixed radiation fields was established. A prototype TL personal dosimeter was designed and constructed. The Monte Carlo simulations were utilized in the design process and verified by experiments. The dosimeter and algorithm were applicable to photon radiation having an effective energy beyond 100 keV in AP-PA mixed radiation fields. A simplified performance test based on ANSI N13.11 showed satisfactory results. Considering that the requirements of the International Electrotechnical Commission (IEC) and the American National Standards Institute (ANSI) with regard to the dosimeter on angular dependency is reinforced, the dosimeter and the dose evaluation algorithm developed in this study provides a useful approach in practical personal dosimetry against inhomogeneous high energy radiation fields. (author)

  7. Structure optimization and simulation analysis of the quartz micromachined gyroscope

    Directory of Open Access Journals (Sweden)

    Xuezhong Wu

    2014-02-01

    Full Text Available Structure optimization and simulation analysis of the quartz micromachined gyroscope are reported in this paper. The relationships between the structure parameters and the frequencies of work mode were analysed by finite element analysis. The structure parameters of the quartz micromachined gyroscope were optimized to reduce the difference between the frequencies of the drive mode and the sense mode. The simulation results were proved by testing the prototype gyroscope, which was fabricated by micro-electromechanical systems (MEMS technology. Therefore, the frequencies of the drive mode and the sense mode can match each other by the structure optimization and simulation analysis of the quartz micromachined gyroscope, which is helpful in the design of the high sensitivity quartz micromachined gyroscope.

  8. Giant Rashba spin splitting in Bi2Se3: Tl

    KAUST Repository

    Singh, Nirpendra; Saeed, Yasir; Schwingenschlö gl, Udo

    2014-01-01

    First-principles calculations are employed to demonstrate a giant Rashba spin splitting in Bi2Se3:Tl. Biaxial tensile and compressive strain is used to tune the splitting by modifying the potential gradient. The band gap is found to increase under

  9. Preparation of biaxially oriented TlCu-1234 thin films

    CERN Document Server

    Khan, N A; Tateai, F; Kojima, T; Ishida, K; Terada, N; Ihara, H

    1999-01-01

    The single phase of TlCu-1234 superconductor thin films is prepared for the first time by the amorphous phase epitaxy (APE) method, which is thallium treatment of sputtered amorphous phase at 900 degrees C for 1 h. The amorphous $9 phase is prepared by sputtering from the stoichiometric target composition CuBa/sub 2/Ca/sub 3/Cu/sub 4/O/sub 12-y/. The films on the SrTiO/sub 3/ substrate are aligned biaxially after the thallium treatment. Highly reproducible $9 TlCu-1234 films are prepared by this method. The XRD reflected a predominant single phase with the c-axis lattice constant of 18.74 AA. This lattice constant value is in between that of Cu-1234 (17.99 AA) and Tl-1234 (19.11 AA) . The $9 pole figure measurements of (103) reflection of the films showed a-axis-oriented crystals with Delta phi =0.8 degrees . The composition of the films after energy dispersive X-ray (EDX) measurements is Tl/sub 0.8/Cu/sub 0.2/Ba/sub $9 2/Ca/sub 3/Cu/sub 4/O /sub 12-y/. From the resistivity measurements, the T/sub c/ is 113 K...

  10. Reader's Response: What Is a SoTL?

    Science.gov (United States)

    Griebenow, Kai

    2010-01-01

    In this response to, "SoTL Commons Conference: A Spirit of Inquiry" (Margaret Davis, Kera Watkins, and Deborah Allen, "International Journal for the Scholarship of Teaching and Learning,"v3 n2 Jul 2009), Griebenow adds his personal impressions as an "SOTL newbie." He states that many scientists have an idea of…

  11. TL, EPR and optical absorption in natural grossular crystal

    Energy Technology Data Exchange (ETDEWEB)

    Yauri, J.M. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo (Brazil); Department of Physics, University of San Agustin, Av. Independencia S/N, Arequipa (Peru); Cano, N.F. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo (Brazil)], E-mail: nilocano@dfn.if.usp.br; Watanabe, S. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo (Brazil)

    2008-10-15

    Grossular is one of six members of silicate Garnet group. Two samples GI and GII have been investigated concerning their luminescence thermally stimulated (TL). EPR and optical absorption and the measurements were carried out to find out whether or not same point defects are responsible for all three properties. Although X-rays diffraction analysis has shown that both GI and GII have practically the same crystal structure of a standard grossular crystal, they presented different behavior in many aspects. The TL glow curve shape, TL response to radiation dose, the effect of annealing at high temperatures before irradiation, the dependence of UV bleaching parameters on peak temperature, all of them differ going from GI to GII. The EPR signals around g=2.0 as well as at g=4.3 and 6.0 have much larger intensity in GI than in GII. Very high temperature (>800 deg. C) annealing causes large increase in the bulk background absorption in GI, however, only very little in GII. In the cases of EPR and optical absorption, the difference in their behavior can be attributed to Fe{sup 3+} ions; however, in the TL case one cannot and the cause was not found as yet.

  12. Neutron Scattering from fcc Pr and Pr3Tl

    DEFF Research Database (Denmark)

    Birgeneau, R. J.; Als-Nielsen, Jens Aage; Bucher, E.

    1972-01-01

    Elastic-neutron-scattering measurements on the singlet-ground-state ferromagnets fcc Pr and Pr3 Tl are reported. Both exhibit magnetic phase transitions, possibly to a simple ferromagnetic state at 20 and 11.6 °K, respectively. The transitions appear to be of second order although that in fcc Pr...

  13. TL, EPR and optical absorption in natural grossular crystal

    International Nuclear Information System (INIS)

    Yauri, J.M.; Cano, N.F.; Watanabe, S.

    2008-01-01

    Grossular is one of six members of silicate Garnet group. Two samples GI and GII have been investigated concerning their luminescence thermally stimulated (TL). EPR and optical absorption and the measurements were carried out to find out whether or not same point defects are responsible for all three properties. Although X-rays diffraction analysis has shown that both GI and GII have practically the same crystal structure of a standard grossular crystal, they presented different behavior in many aspects. The TL glow curve shape, TL response to radiation dose, the effect of annealing at high temperatures before irradiation, the dependence of UV bleaching parameters on peak temperature, all of them differ going from GI to GII. The EPR signals around g=2.0 as well as at g=4.3 and 6.0 have much larger intensity in GI than in GII. Very high temperature (>800 deg. C) annealing causes large increase in the bulk background absorption in GI, however, only very little in GII. In the cases of EPR and optical absorption, the difference in their behavior can be attributed to Fe 3+ ions; however, in the TL case one cannot and the cause was not found as yet

  14. Spinel + quartz-bearing ultrahigh-temperature granulites from Xumayao, Inner Mongolia Suture Zone, North China Craton: Petrology, phase equilibria and counterclockwise p-T path

    Directory of Open Access Journals (Sweden)

    Huatian Zhang

    2012-09-01

    Our phase equilibria modeling indicates two main stages during the metamorphic evolution of these rocks: 1 near-isobaric cooling from 975 °C to 875 °C around 8 kbar, represented by the formation of garnet porphyroblasts from spinel and quartz; and 2 cooling and decompression from 850 °C, 8 kbar to below 750 °C, 6.5 kbar, represented by the break-down of garnet. The spinel + quartz assemblage is considered to have been stable at peak metamorphism, formed through the break-down of cordierite, indicating a near isothermal compression process. Our study confirms the regional extent of UHT metamorphism within the IMSZ associated with the Paleoproterozoic subduction-collision process.

  15. Quality control of the solution sup(201)TlCl obtained at IPEN-CNEN/SP by sup(201)Tl direct preparation

    International Nuclear Information System (INIS)

    Fernandes, L.; Silva, C.P.G. da

    1991-01-01

    The radiopharmaceutical sup(201) TlCl is used in Nuclear Medicine for myocardial visualization. The solution of sup(201)TlCl was prepared using sup(201)Tl obtained by irradiating a natural mercury target with protons. This radionuclide was subjected to different quality control processes to verify the purity required for its use in Medicine. Some of these controls concerned the determination of sup(200)Tl, sup(201)Tl and sup(202)Tl; the chemical identification of sup(201)Tl sup(+1); the hydrazine concentration, mercury contamination and the presence of phosphate. Furthermore, the biologic distribution in Wistar rats and tests for sterility pyrogens and for toxicity were carried out. It was verified that the solution obtained was in the form of tallous chloride. This radiopharmaceutical can give a good heart image in animals but due to the contamination of sup(201)Tl with sup(200)Tl and sup(202)Tl its use in human beings is not possible unless enriched sup(202)Hg is used as target of irradiation. (author)

  16. Investigating the origins of double photopeaks in CsI:Tl samples through activator mapping

    Science.gov (United States)

    Onken, Drew R.; Gridin, Sergii; Williams, Richard T.; Williams, Charles B.; Donati, George L.; Gayshan, Vadim; Vasyukov, Sergey; Gektin, Alex

    2018-06-01

    Careful examination of the origins of double photopeaks in CsI:Tl provides a foundation for exploring the relationship between activator homogeneity and photopeak resolution in scintillators. In rare cases, certain CsI:Tl crystals exhibit a second photopeak in the pulse-height spectrum. A combination of optical mapping and ICP-MS measurements reveals the presence of two distinct regions with differing Tl concentrations in these crystals. The oscillator strength of the 299 nm absorption A-band of Tl in CsI was measured to be 0.0526 ± 0.0008; this parameter can be used to quantify activator concentration from the optical absorption. Using published measurements of luminescence intensity versus Tl concentration, the distributions of Tl measured from optical absorption maps of the samples were reconstructed into photopeaks in good agreement with experiment. The distribution of Tl concentrations in these particular crystals allowed examining luminescence pulse shape as a function of Tl concentration.

  17. Microbially induced separation of quartz from calcite using Saccharomyces cerevisiae.

    Science.gov (United States)

    Padukone, S Usha; Natarajan, K A

    2011-11-01

    Cells of Saccharomyces cerevisiae and their metabolites were successfully utilized to achieve selective separation of quartz and calcite through microbially induced flotation and flocculation. S. cerevisiae was adapted to calcite and quartz minerals. Adsorption studies and electrokinetic investigations were carried out to understand the changes in the surface chemistry of yeast cells and the minerals after mutual interaction. Possible mechanisms in microbially induced flotation and flocculation are outlined. Copyright © 2011 Elsevier B.V. All rights reserved.

  18. Identification of Color Development Potential of Quartz by Raman Spectroscopy

    International Nuclear Information System (INIS)

    Gomides Alkmim, D.; Soares Lameiras, F.

    2013-01-01

    Colorless quartz is usually exposed to ionizing radiation (gamma rays or high energy electron beams) in order to acquire different colors for jewelry. This is due to the presence of traces of some elements such as aluminum, iron, hydrogen, lithium, or sodium, which are responsible for the extrinsic colors developed after irradiation. Most quartz crystals are extracted colorless from nature and it is necessary to separate those that can develop colors from those that cannot. This can be done through irradiation tests, which take a long time. Other option is to collect the infrared signature of colorless quartz. However, infrared spectroscopic analysis is quite expensive, especially when using portable devices. Raman spectroscopy is now available as an inexpensive and portable technique that could provide identification of the samples of colorless quartz still in the field, facilitating the prediction for their economic exploitation. In addition, Raman spectroscopy usually requires a minimum or no sample preparation. This paper presents an investigation of the feasibility of using Raman spectroscopy as a substitute for infrared spectroscopy to predict the potential for color development of quartz. A band at 3595 cm -1 was observed, only along the c axis of a prasiolite excited by a high power 514 nm laser. This band was nor observed in quartz samples that do not develop color after irradiation, hence requiring further studies. (Author)

  19. Thermoluminescent dependence with the particle size of polyminerals in food irradiated of Mexican spices; Dependencia Tl con el tamano de particula de poliminerales en alimentos irradiados de especias Mexicanas

    Energy Technology Data Exchange (ETDEWEB)

    Teuffer Z, C. [FQ-UNAM, 04510 Mexico D.F. (Mexico); Cruz Z, E. [ICN-UNAM, A.P. 70-543, 04510 Mexico D.F. (Mexico); Calderon, T. [Depto. de Quimica Agricola-Geologia- Geoquimica, Universidad Autonoma de Madrid, 28049 (Spain); Chernov, V.; Barboza F, M. [CIF, UNISON, A.P. 5-88, Hermosillo, Sonora (Mexico)

    2004-07-01

    The influence of grain size on Tl was analysed in poly minerals extracted from Mexican spices as Origanum vulgare L. (oregano) y Capsicum annun (chile guajillo). The poly minerals size were selected by Zimmerman method up to 10 {mu}m and exposed to 0.5-10 kGy range from {sup 60}Co. The glow curves were centered at 166 C for Capsicum annun and at 126 C for Origanum vulgare l. In both cases was observed at 5 kGy a weak saturation for Tl response. This behaviour is attributed to feldspar and quartz are present in the samples and this results is in agreement with other european spices obtained. For >10 {mu}m particle size the Tl response increased respect to the doses, and it is possible that increase the organic impurities quantities are present in the samples and contributed to the Tl when the samples were thermally excited. The aim of this work is provide more ideas with regard to the behaviour of luminescence emission as dependent of the size particle in the irradiated spices. The methodology might useful for quality control also in radiation processing. (Author)

  20. Prediction of half-metallic properties in TlCrS{sub 2} and TlCrSe{sub 2} based on density functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Hashimzade, F.M.; Huseinova, D.A. [Institute of Physics, National Academy of Sciences of Azerbaijan, AZ 1143 Baku (Azerbaijan); Jahangirli, Z.A. [Institute of Physics, National Academy of Sciences of Azerbaijan, AZ 1143 Baku (Azerbaijan); Institute of Radiation Problems, National Academy of Sciences of Azerbaijan, AZ 1143 Baku (Azerbaijan); Mehdiyev, B.H., E-mail: bachschi@yahoo.de [Institute of Physics, National Academy of Sciences of Azerbaijan, AZ 1143 Baku (Azerbaijan)

    2017-08-01

    Highlights: • Half-metallic properties of TlCrS2, TlCrSe2 and hypothetical TlCrSSe have been investigated by first-principles all-electron full-potential linearized augmented plane wave plus local orbital (FP-LAPW+lo) method based on density functional theory (DFT). • Total magnetic moment keeps its integer value on a relatively wide range of changes in volume (−10% ÷ 10%) for TlCrS2 and TlCrSSe, while total magnetic moment TlCrSe2 decreases with increasing volume, approaching to integer value 3 μB. • The states at the Fermi level in the case of spin-up channel consist of a hybridization of p-states of the atom S(Se) with d-states of Cr. - Abstract: Half-metallic properties of TlCrS{sub 2}, TlCrSe{sub 2} and hypothetical TlCrSSe have been investigated by first-principles all-electron full-potential linearized augmented plane wave plus local orbital (FP-LAPW+lo) method based on density functional theory (DFT). The results of calculations show that TlCrS{sub 2} and TlCrSSe are half-metals with energy gap (E{sub g}) ∼0.12 eV for spin-down channel. Strong hybridization of p-state of chalchogen and d-state of Cr leads to bonding and antibonding states and subsequently to the appearance of a gap in spin-down channel of TlCrS{sub 2} and TlCrSSe. In the case of TlCrSe{sub 2}, there is a partial hybridization and p-state is partially present in the DOS at Fermi level making this compound nearly half-metallic. The present calculations revealed that total magnetic moment keeps its integer value on a relatively wide range of changes in volume (−10% ÷ 10%) for TlCrS{sub 2} and TlCrSSe, while total magnetic moment of TlCrSe{sub 2} decreases with increasing volume approaching to integer value 3 μB.

  1. Experimental studies on radiation damages of CsI(Tl) crystals

    International Nuclear Information System (INIS)

    He Jingtang; Mao Yufang; Dong Xiaoli; Chen Duanbao; Li Zuhao

    1997-01-01

    The results of experimental studies on radiation damage of CsI(Tl) crystal were reported. There are radiation damage effects on CsI(Tl) crystal. Experimental studies on recovery of damaged CsI(Tl) crystals were made. It seems that after heating at 200 degree C for 4 hours, the damaged crystals could be recovered completely

  2. Left ventricular ejection fraction determined by gated Tl-201 perfusion SPECT and quantitative software

    International Nuclear Information System (INIS)

    Hyun, In Young; Kim, Sung Eun; Seo, Jeong Kee; Hong, Eui Soo; Kwan, Jun; Park, Keum Soo; Lee, Woo Hyung

    2000-01-01

    We compared estimates of ejection fraction (EF) determined by gated Tl-201 perfusion SPECT (g-Tl-SPECT) with those by gated blood pool (GBP) scan. Eighteen subjects underwent g-Tl-SPECT and GBP scan. After reconstruction of g-Tl-SPECT, we measured EF with Cedars software. The comparison of the EF with g-Tl-SPECT and GBP scan was assessed by correlation analysis and Bland Altman plot. The estimates of EF were significantly different (p<0.05) with g-Tl-SPECT (40%±14%) and GBP scan (43%±14%). There was an excellent correlation of EF between g-Tl-SPECT and GBP scan (r=3D0.94, p<0.001). The mean difference of EF between GBP scan and g-Tl-SPECT was +3.2%. Ninety-five percent limits of agreement were ±9.8%. EF between g-Tl-SPECT and GBP scan were in poor agreement. The estimates of EF by g-Tl-SPECT was well correlated with those by GBP scan. However, EF of g-Tl-SPECT doesn't agree with EF of GBP scan. EF of g-Tl-SPECT can't be used interchangeably with EF of GBP scan.=20

  3. Challenges to Disciplinary Knowing and Identity: Experiences of Scholars in a SoTL Development Program

    Science.gov (United States)

    Miller-Young, Janice E.; Yeo, Michelle; Manarin, Karen

    2018-01-01

    Faculty members from five years of an annual Scholarship of Teaching and Learning (SoTL) development program were invited to participate in a study about the impact of SoTL on their teaching, scholarship, and career trajectory. During semi-structured interviews, many expressed feeling discomfort during their journey into SoTL. A qualitative…

  4. High current Tl-203, Rh-103 targets preparation for cyclotron production of Tl-201 and Pd-103 radionuclides

    International Nuclear Information System (INIS)

    Arzumanov, A.; Berger, V.; Borissenko, A.; Gorodisskaya, N.; Ilmatov, I.; Knyazev, A.; Koptev, V.; Lyssukhin, S.; Platov, A.; Sychikov, G.; Zheltov, D.

    2004-01-01

    The objectives of the present work are to increase thermal stability of cyclotron targets for production of Tl-201 isotope, increase Tl-203 regeneration rate at radiochemical reprocessing of the targets and develop production technology for radiochemical sources based on Rd-103 isotope. Electrochemical coating of copper substrate with Tl increased the beam current at target irradiation from 100 μA to 125 μA. Further increase of the beam current results in sharp decrease of target stability time at irradiation to 15 min at beam current 150 μA. Thermal calculations and tests at the electron-beam stand predict satisfactory stability at such currents. The discrepancy with the irradiation results has not been explained. More accurate specification of regimes for Tl-203 electrochemical recovery from irradiated targets and better matching of the electrolyte composition made it possible to increase the recovery rate up to 99.5%. Before the present Project, the INP had no experience in production of radioactive sources based on Pd-103. Thermo-diffusion extraction of Pd-103 from irradiated rhodium foil has been chosen as a technology-defining method. The process assures good extraction rate and high purity of extracted isotope. Production of Pd-103 sources based on this technology is much simpler compared to the same based on electrochemical processes. (author)

  5. Importance of controlling the Tl-oxide partial pressure throughout the processing of TlBa2CaCu2O7 thin films

    International Nuclear Information System (INIS)

    Siegal, M.P.; Venturini, E.L.; Newcomer, P.P.; Overmyer, D.L.; Dominguez, F.; Dunn, R.

    1995-01-01

    TlBa 2 CaCu 2 O 7 (Tl-1212) superconducting films 5000--6000 A thick have been grown on LaAlO 3 (100) substrates using oxide precursors in a closed two-zone thallination furnace. Tl-1212 films can be grown with transition temperatures ∼100 K, and critical current densities measured by magnetization of J cm (5 K)>10 7 A/cm 2 and J cm (77 K)>10 5 A/cm 2 . Processing conditions, substrate temperatures and Tl-oxide source temperatures are found which result in smooth, nearly phase-pure Tl-1212 films. Variations in the respective temperature ramps of the Tl-oxide zone and the substrate zone can greatly influence resulting film properties such as microstructure, morphology, superconducting transition temperature, and critical current density. copyright 1995 American Institute of Physics

  6. The problem of dating quartz 2: Synchrotron generated X-ray excited optical luminescence (XEOL) from quartz

    International Nuclear Information System (INIS)

    King, G.E.; Finch, A.A.; Robinson, R.A.J.; Taylor, R.P.; Mosselmans, J.F.W.

    2011-01-01

    The luminescence emission of quartz is used in optically stimulated luminescence dating (OSL), however the precise origins of the emission are unclear. A suite of quartz samples were analysed using X-ray excited optical luminescence (XEOL). Radiation dose effects were observed whereby the UV emissions (3.8 and 3.4 eV) were depleted to the benefit of the red emission (1.9-2.0 eV). Samples were excited at ∼7 keV. Understanding why some quartz emit light more brightly than others will increase the efficiency and precision of OSL analyses. - Highlights: → The X-ray excited optical luminescence (XEOL) emission of quartz is explored. → The XEOL of quartz of different provenances varies. → Radiation dosing causes UV emissions to deplete to the benefit of red emissions. → The 3.8 and 3.4 eV emissions deplete at the same rate. → The quartz luminescence emission exhibits anisotropic effects.

  7. Soil chemistry in lithologically diverse datasets: the quartz dilution effect

    Science.gov (United States)

    Bern, Carleton R.

    2009-01-01

    National- and continental-scale soil geochemical datasets are likely to move our understanding of broad soil geochemistry patterns forward significantly. Patterns of chemistry and mineralogy delineated from these datasets are strongly influenced by the composition of the soil parent material, which itself is largely a function of lithology and particle size sorting. Such controls present a challenge by obscuring subtler patterns arising from subsequent pedogenic processes. Here the effect of quartz concentration is examined in moist-climate soils from a pilot dataset of the North American Soil Geochemical Landscapes Project. Due to variable and high quartz contents (6.2–81.7 wt.%), and its residual and inert nature in soil, quartz is demonstrated to influence broad patterns in soil chemistry. A dilution effect is observed whereby concentrations of various elements are significantly and strongly negatively correlated with quartz. Quartz content drives artificial positive correlations between concentrations of some elements and obscures negative correlations between others. Unadjusted soil data show the highly mobile base cations Ca, Mg, and Na to be often strongly positively correlated with intermediately mobile Al or Fe, and generally uncorrelated with the relatively immobile high-field-strength elements (HFS) Ti and Nb. Both patterns are contrary to broad expectations for soils being weathered and leached. After transforming bulk soil chemistry to a quartz-free basis, the base cations are generally uncorrelated with Al and Fe, and negative correlations generally emerge with the HFS elements. Quartz-free element data may be a useful tool for elucidating patterns of weathering or parent-material chemistry in large soil datasets.

  8. Isothermal deformation of gamma titanium aluminide

    International Nuclear Information System (INIS)

    Srinivasan, R.; Singh, J.P.; Tuval, E.; Weiss, I.

    1996-01-01

    Gamma titanium aluminide has received considerable attention in recent years from the automotive industry as a potential material for making rotating and reciprocating components to produce a quieter and more efficient engine. The objectives of this study were to identify processing routes for the manufacture of automobile valves from gamma titanium aluminide. The issues considered were microstructure and composition of the material, and processing parameters such as deformation rates, temperatures, and total deformation. This paper examines isothermal deformation of gamma titanium aluminide in order to develop a processing window for this type of material

  9. Isothermal calorimetry of enzymatic biodiesel reaction

    DEFF Research Database (Denmark)

    Fjerbæk Søtoft, Lene; Westh, Peter; Christensen, Knud Villy

    2010-01-01

      Isothermal calorimetry ITC has been used to investigate enzymatic biodiesel production. The transesterification of rapeseed oil with methanol and ethanol was catalyzed by the immobilized lipase Novozym 435 at 40°C. The ITC-experiments clearly demonstrate the possibilities of investigating complex...... and composition change in the system, the heat of reaction at 40°C for the two systems has been determined to -9.8 ± 0.9 kJ/mole biodiesel formed from rapeseed oil and methanol, and - 9.3 ± 0.7 kJ/mole when rapeseed oil and ethanol is used....

  10. Mechanisms of TL for production of the 230 {sup o}C peak in natural sodalite

    Energy Technology Data Exchange (ETDEWEB)

    Cano, Nilo F., E-mail: nilocano@dfn.if.usp.b [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-090, Sao Paulo (Brazil); Professional School of Physics, University of San Agustin of Arequipa, Av. Independencia S/N, Arequipa (Peru); Blak, Ana R. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-090, Sao Paulo (Brazil); Ayala-Arenas, Jorge S. [Professional School of Physics, University of San Agustin of Arequipa, Av. Independencia S/N, Arequipa (Peru); Watanabe, Shigueo [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-090, Sao Paulo (Brazil)

    2011-02-15

    The thermoluminescence (TL) peak in natural sodalite near 230 {sup o}C, which appears only after submitted to thermal treatments and to gamma irradiation, has been studied in parallel with electron paramagnetic resonance (EPR) spectrum appearing under the same procedure. This study revealed a full correlation between the 230 {sup o}C TL peak and the eleven hyperfine lines from EPR spectrum. In both case, the centers disappear at the same temperature and are restored after gamma irradiation. A complete model for the 230 {sup o}C TL peak is presented and discussed. In addition to the correlation and TL model, specific characteristics of the TL peaks are described.

  11. Electronic band structure study of colossal magnetoresistance in Tl 2Mn 2O 7

    Science.gov (United States)

    Seo, D.-K.; Whangbo, M.-H.; Subramanian, M. A.

    1997-02-01

    The electronic structure of Tl 2Mn 2O 7 was examined by performing tight binding band calculations. The overlap between the Mn t 2g- and Tl 6 s-block bands results in a partial filling of the Tl 6 s-block bands. The associated Fermi surface consists of 12 cigar-shape electron pockets with each electron pocket about {1}/{1000} of the first Brillouin zone in size. The Tl 6 s-block bands have orbital contributions from the Mn atoms, and the carrier density is very low. These are important for the occurrence of a colossal magnetoresistance in Tl 2Mn 2O 7.

  12. Two crystal structures of Ag sup + -and Tl sup + -exchanged zeolite X, Ag sub 2 sub 7 Tl sub 6 sub 5 -X and Ag sub 2 sub 3 Tl sub 6 sub 9 -X

    CERN Document Server

    Kim, S Y; Kim, Y

    2002-01-01

    Two crystal structures of dehydrated Ag sup + -and Tl sup + -exchanged zeolite X (Ag sub 2 sub 7 Tl sub 6 sub 5 -X and Ag sub 2 sub 3 Tl sub 6 sub 9 -X) have been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at 21(1) .deg. C (a = 24.758(4) A, a = 24.947(4) A, respectively). Their structures were refined to the final error indices R sub 1 = 0.055 and wR sub 2 = 0.057 with 375 reflections, and R sub 1 = 0.058 and wR sub 2 = 0.057 with 235 reflections, respectively, for which I> 3 sigma(I). In the structure of Ag sub 2 sub 7 Tl sub 6 sub 5 -X, 27 Ag sup + ions were found at two crystallographic sites: 15 Ag sup + ions at site I at the center of the hexagonal prism and the remaining 12 Ag sup + ions at site II' in the sodalite cavity. Sixty-five Tl sup + ions were located at three crystallographic sites: 20 Tl sup + ions at site II opposite single six-rings in the supercage, 18 Tl sup + ions at site I' in the sodalite cavity opposite the D6Rs, and the remaining 27 Tl sup ...

  13. Surface complexation modelling: Experiments on sorption of nickel on quartz, goethite and kaolinite and preliminary tests on sorption of thorium on quartz

    Energy Technology Data Exchange (ETDEWEB)

    Puukko, E.; Hakanen, M. [Univ. of Helsinki (Finland). Dept. of Chemistry. Lab. of Radiochemistry

    1997-09-01

    The aim of the work was to study the sorption behaviour of Ni on quartz, goethite and kaolinite at different pH levels and in different electrolyte solutions of different strength. In addition preliminary experiments were made to study the sorption of thorium on quartz. The MUS quartz and Nilsiae quartz were analysed for MnO{sub 2} by neutron activation analysis (NAA) and the experimental results were modelled with the HYDRAQL computer model. 9 refs.

  14. Isothermal and non-isothermal conditions of isotope separation by chemical exchange method

    International Nuclear Information System (INIS)

    Khoroshilov, A.V.; Andreev, B.M.; Katalnikov, S.G.

    1992-01-01

    The published data about the effect of temperature on thermodynamic and mass transfer parameters of isotope separation by the chemical exchange method were used to examine the influence of iso- and non-isothermal conditions on the effectiveness of the separation process. It has been shown that simultaneous fulfillment of several optimization criteria is impossible in optimization of the isothermal process. If the limitation that temperature must be constant in the whole range of concentrational changes for an isolated isotope is removed, then it is possible to solve the problem of optimization with simultaneous fulfillment of several optimization criteria. When the separation process is carried out with non-isothermal conditions, that is, in temperature cascade, then the maximum concentration change takes place at every theoretical separation plate, and whole cascade is characterised by maximum throughput, minimum height and volume, and minimum cost for the stream reflux. From the results of our study, it was concluded that in the optimum temperature cascade, the cost of production of unity quantity of isotope can be decreased at least by a factor of two as compared with the optimal isothermal version of the separation process. (author)

  15. Pulse shape analysis using CsI(Tl) Crystals

    International Nuclear Information System (INIS)

    Silva, J.; Fiori, E.; Loher, B.; Savran, D.; Wirth, R.; Vencelj, M.

    2013-06-01

    The decay time of CsI(Tl) scintillating material consists of more than a single exponential component. The ratio between the intensity of these components varies as a function of the ionizing power of the absorbed particles, such as γ -rays or protons, and the temperature. This property can therefore be used for particle discrimination and for temperature monitoring, using pulse shape analysis. An unsupervised method that uses fuzzy clustering algorithms for particle identification based on pulse shape analysis is presented. The method is applied to discriminate between photon and proton-induced signals in CsI(Tl) scintillator detectors. The first results of a method that uses pulse shape analysis for correcting the temperature-dependent gain effect of the detector are also presented. The method aims at conserving a good energy resolution in a temperature varying environment without the need to measure the temperature of the detector externally (authors)

  16. Statistics and the additive dose method in TL dating

    International Nuclear Information System (INIS)

    Scott, E.M.

    1988-01-01

    Estimation of the palaeo-dose and its associated error in thermoluminescence (TL) dating requires assumptions to be made concerning the error structures of both the TL signal and dose. In this paper, we consider the sensitivity of palaeo-dose estimation to different error structures and describe techniques for estimation of the resultant palaeo-dose errors. We also indicate how the validity of the assumptions may be verified. We have taken the approach that procedures for the analysis of a glow curve at a single temperature must first be proved prior to their inclusion in a full analysis of the glow curves over a series of temperatures. Thus, the paper deals mainly with the analysis of the univariate structure of glow curves, i.e. estimation of the palaeo-dose and error at each temperature, but in the final section of the paper, we discuss briefly the multivariate structure of the results including automatic detection of plateau regions. (author)

  17. Computerized study with 201Tl of the gold thyroid node

    International Nuclear Information System (INIS)

    Palermo, F.; Saitta, B.; Coghetto, F.; Tiberio, M.; Caldato, L.

    1982-01-01

    Because of its physical and potassium-metabolic characteristics 201 Tl is more suitable than 131 Cs for radioisotopic studies of the cold thyroid nodule, with the further diagnostic possibility of quantitatively assessing intranodular behaviour for a specific differentiation among different kinds of neoformations. Using a gamma-camera on line with a computer data processing device, sequential scintiscans were recorded for the first 20-30 min after i.v. administration of 15-20 μCi/kg of radiothallium; delayed sequences were taken at 40-60 min if intranodular uptake appeared. A quantitative appraisal was made of the differential 201 Tl uptake-ratio between nodule and healthy thyroid tissue (density-index) and the multiparameter analysis of thyroid time/activity curves generated on the relative regions of interest (ROIs). This computerized study, in 120 out of 293 patients submitted to this radiothallium test, has shown a) diagnostic agreement between clinical-histological and radioisotopic findings in 76 out of 79 colloid-cystic or degenerative neoformations, in all 16 malignant and in 23 out of 25 hyperplastic benign nodules; b) significant statistical difference of the density-index in solid versus cystic but not between benign and malignant nodules; c) different 201 Tl kinetics behaviour in different kinds of solid thyroid lesions with a satisfactory statistical difference of the radiothallium nodular dissappearance-index. (orig.) [de

  18. Comparison of 201Tl solution sources in UK hospitals, 2001

    International Nuclear Information System (INIS)

    Baker, M.; Woods, M.

    2001-01-01

    During recent years, concerns have been raised within the nuclear medicine field about the accuracy of activity measurements for 201 Tl. And indeed, NPL calibrations repeatedly indicated that the level of impurities present in such samples and the significant amount of activity adsorbed onto the glass wall of the container could produce erroneous results. In addition, the standard P6 vials, in which 201 Tl solution had been previously supplied, were recently replaced with the new ''10R Type 1 plus'' Schott vials. To assess the magnitude of these effects on the accuracy of clinical measurements of the activity of 201 Tl, an intercomparison exercise was conducted between the National Physical Laboratory (NPL), Nycomed-Amersham (NA) and the UK hospital physics community. The majority of the 273 reported results were within the ± 10 % limit of accuracy that hospitals aim to achieve for diagnosis, biased high. The tendency to overestimate the activity was more evident for syringe measurements. The exercise also revealed that the adsorption losses experienced with P6 vials had been solved by the introduction of the 10R vials, but individual calibrators need to be recalibrated for this new container. (author)

  19. Nuclear resonance fluorescence of {sup 203,205}Tl

    Energy Technology Data Exchange (ETDEWEB)

    Pfeifer, Fabian; Fritzsche, Matthias; Pietralla, Norbert; Savran, Deniz; Weller, Henry; Zweidinger, Markus [Institut fuer Kernphysik, Technische Universitaet, Darmstadt (Germany); Rusev, Gencho; Tonchev, Anton P.; Tornow, Werner [Triangle Universities Nuclear Laboratory, Duke University, Durham (United States); Zilges, Andreas [Institut fuer Kernphysik, Universitaet Koeln (Germany)

    2009-07-01

    In order to investigate the dipole strength distribution in Thalium isotopes we have studied Nuclear Resonance Fluorescence of a sample composed of natural Thallium (consisting of 30% {sup 203}Tl and 70% {sup 205}Tl). Unpolarized bremsstrahlung with photo energies up to 7.5 MeV was used at the High Intensity Photon Setup (HIPS) at S-DALINAC at the IKP Darmstadt. 24 fluorescent {gamma}-ray transitions were observed, 19 of them for the first time. For the assignment of the polarity of two prominent {gamma}-ray transitions, one at 4.7 MeV and one at 4.9 MeV, the polarized photon beam of the High Intensity {gamma}-ray Source (HI{gamma}S) at Duke University was used. The experiment at HI{gamma}S revealed the existence of a photo-excited state of {sup 205}Tl at an excitation energy of 4.971 MeV that exhibits a transition to the first excited state at 203 keV.

  20. Isothermal martensite formation at sub-zero temperatures

    DEFF Research Database (Denmark)

    Stojko, Allan; Hansen, Mikkel Fougt; Slycke, Jan

    2010-01-01

    austenitized and quenched in oil and thereafter investigated with vibrating sample agnetometry, which allows a quantitative assessment of the fraction of retained austenite as a function of the subzero temperature and time. Isothermal martensite formation was observed on interrupting the continuous cooling (5...... with a continuation of the martensitic transformation. On prolonged isothermal holding a volume reduction was observed for AISI 52100, but not for AISI 1070. A mechanism is proposed that explains the occurrence of isothermal martensite formation....

  1. Carbothermal Reduction of Quartz and Carbon Pellets at Elevated Temperatures

    Science.gov (United States)

    Li, Fei; Tangstad, Merete; Ringdalen, Eli

    2018-02-01

    In this study, the carbothermal reduction of pellets composed of quartz and carbon at temperatures between 1898 K and 1948 K (1625 °C and 1675 °C) are investigated. The main product from this reaction is silicon carbide (SiC). The reduction of quartz with carbon black, charcoal, coke, coal, and pre-heated coal in the pellet were compared to investigate the different carbon resources used in silicon production. Charcoal and coke have high SiO reactivity, while carbon black and coal (pre-heated coal) have low SiO reactivity. Charcoal and carbon black show better matching between quartz/carbon reactivity and SiO reactivity, and will lose less SiO gas than coke and pre-heated coal. Coal has a high volatile content and is thus not recommended as a raw material for the pellets.

  2. Carbothermal Reduction of Quartz and Carbon Pellets at Elevated Temperatures

    Science.gov (United States)

    Li, Fei; Tangstad, Merete; Ringdalen, Eli

    2018-06-01

    In this study, the carbothermal reduction of pellets composed of quartz and carbon at temperatures between 1898 K and 1948 K (1625 °C and 1675 °C) are investigated. The main product from this reaction is silicon carbide (SiC). The reduction of quartz with carbon black, charcoal, coke, coal, and pre-heated coal in the pellet were compared to investigate the different carbon resources used in silicon production. Charcoal and coke have high SiO reactivity, while carbon black and coal (pre-heated coal) have low SiO reactivity. Charcoal and carbon black show better matching between quartz/carbon reactivity and SiO reactivity, and will lose less SiO gas than coke and pre-heated coal. Coal has a high volatile content and is thus not recommended as a raw material for the pellets.

  3. Sorption of lambda-cyhalothrin, cypermethrin, deltamethrin and fenvalerate to quartz, corundum, kaolinite and montmorillonite.

    Science.gov (United States)

    Oudou, H Chaaieri; Hansen, H C Bruun

    2002-12-01

    Sorption to mineral surfaces may be important for retention and degradation of hydrophobic pesticides in subsoils and aquifers poor in organic matter. In this work the title pyrethroids have been used to investigate selective interactions with the surfaces of four minerals. Sorption of the four pyrethroids was quantified in batch experiments with initial pyrethroid concentrations of 1-100 microg/l. Sorption to centrifuge tubes used in the batch experiments accounted for 25-60% of total sorption. Net sorption was obtained from total sorption after subtracting the amounts of pyrethroids sorbed to centrifuge tubes used. All isotherms could be fitted by the Freundlich equation with n ranging between 0.9 and 1.1. Bonding affinities per unit surface area decreased in the order: corundum > quartz > montmorillonite approximately equal kaolinite. A similar sequence as found for the total surface tension of the minerals. All minerals showed the same selectivity order with respect to sorption affinity of the four pyrethroids: lambda-cyhalothrin > deltamethrin > cypermethrin > fenvalerate, which shows that the most hydrophobic compound is sorbed most strongly. Stereochemical properties of the four pyrethroid formulations may also contribute to the selectivity pattern.

  4. Activation analysis of thallium by /sup 203/Tl(n,2n)/sup 202/Tl reaction in nuclear reactors

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, I M; Resnizky, S M; Baro, G B [Comision Nacional de Energia Atomica, Buenos Aires (Argentina). Gerencia de Radioisotopos y Radiaciones

    1982-01-01

    Two techniques are described for neutron activation analysis of thallium in biological and geological materials, based on /sup 203/Tl(n,2n)/sup 202/Tl reaction in nuclear reactors. Co-precipitation with bismuth sulphide is used as a pre-concentration method of thallium in urine samples, and post-irradiation chemical separation is also performed. The detection limit is 0.5 ..mu..g/l, for 100 ml urine samples. For thallium determination in blendes a radiochemical separation is carried out after the irradiation. An extension of this technique is presented for glass and silicate rocks. Results for seven blende samples from different places of Argentina are shown. Analysis of two reference materials, the 614 glass from the National Bureau of Standards and the granodiorite GSP-1 from the U.S. Geological Survey were also performed. The results are in very good agreement with the certified or estimated values.

  5. Radioluminescence of synthetic quartz related to alkali ions

    Energy Technology Data Exchange (ETDEWEB)

    Martini, M., E-mail: m.martini@unimib.it [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); INFN-Sezione di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Fasoli, M. [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Galli, A. [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Istituto di Fotonica e Nanostrutture, IFN-CNR (Italy); Villa, I. [Dipartimento di Scienza dei Materiali, Universita degli Studi di Milano Bicocca, Via Cozzi 53, I-20125 Milano (Italy); Guibert, P. [IRAMAT-CRP2A (Institut de recherche sur les Archeomateriaux), UMR no. 5060, CNRS-Universite Bordeaux III, F-33607 Pessac (France)

    2012-04-15

    The radioluminescence (RL) of synthetic quartzes (GEMMA Quartz and Crystal Company) has been measured at room temperature. Some samples were treated by electrodiffusion ('sweeping') in order to change the concentrations of alkali ions, mainly Li{sup +} and Na{sup +}, which in quartz are known to be linked to Al ions, substitutional for Si ions. The RL emission spectra show evidence of a role of alkali ions in affecting some specific emissions. All the spectra could be analysed as composed of four bands in the blue and UV region. Specifically, the well known blue emission at around 470 nm was seen to be composed by two bands at 430 nm (2.86 eV) and at 485 nm (2.53 eV). Effects of irradiation, during the RL measurements, were clearly seen only in the 'Li swept in' sample, namely an increase in the 485 nm band intensity and a decrease in the 430 nm band one. The previously reported UV emission was detected at 355 nm (3.44 eV) in all the samples, being the most intense band in the 'swept out' sample. A further UV emission was detected at 315 nm (3.94 eV), more intense in untreated samples. Possible assignments of the detected emission bands are discussed in relation to the defects of quartz, specifically focusing on the Al centres that are most affected by sweeping procedures. - Highlights: Black-Right-Pointing-Pointer Contribution to the understanding of relationships between defects in quartz and luminescence emissions. Black-Right-Pointing-Pointer Role of charge compensators at substitutional Al sites in the optical properties of quartz. Black-Right-Pointing-Pointer Evidence of the double nature of the 'blue emission' (around 470 nm).

  6. Modeling and Prediction of Soil Water Vapor Sorption Isotherms

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Moldrup, Per

    2015-01-01

    Soil water vapor sorption isotherms describe the relationship between water activity (aw) and moisture content along adsorption and desorption paths. The isotherms are important for modeling numerous soil processes and are also used to estimate several soil (specific surface area, clay content.......93) for a wide range of soils; and (ii) develop and test regression models for estimating the isotherms from clay content. Preliminary results show reasonable fits of the majority of the investigated empirical and theoretical models to the measured data although some models were not capable to fit both sorption...... directions accurately. Evaluation of the developed prediction equations showed good estimation of the sorption/desorption isotherms for tested soils....

  7. Exploration of GaInTlP and related Tl-containing III-V alloys for photovoltaics

    International Nuclear Information System (INIS)

    Friedman, D. J.; Kurtz, Sarah R.; Kibbler, A. E.

    1999-01-01

    This paper discusses the results of an attempt to grow GaInTlP for application as a 1-eV material for the third junction of a GaInP/GaAs/3rd-junction high-efficiency solar cell. Although early indications from the literature were promising, we are unable to produce crystalline homogeneous material, and so we conclude that this material is not a promising candidate for such applications as photovoltaics

  8. Development of surgical gamma probes with TlBr semiconductors and CsI(Tl) scintillators crystals

    International Nuclear Information System (INIS)

    Costa, Fabio Eduardo da

    2006-01-01

    Radio guided surgery, using probes with radiation detectors, has been prominence in the medical area in the last decade. This technique consists in injecting a radioactive substance to concentrate in tumour and assist the localization during the surgical procedure. The radio guided surgeries allowing the identification of lymph node has revolutioned the behavior of tumour in initial stadium when are being spread by lymphatic way. The conditions imposed to the surgery due the proximity between some lymph nodes, demands of the probes, a small diameters and capacity of individual identification of these lymph nodes radiolabelled by a specific tracer. The international market supplies these probes with CdTe semiconductors and scintillators, but there is some time lack a promptly technical assistance in the Brazilian market. This work developed probes with national technology, using CsI(Tl) scintillators crystals and, in substitution to CdTe crystals semiconductors, the TlBr crystal, that is a new semiconductor detector in a world-wide development, with advantages in relation to the CdTe. Both crystals have been grown in IPEN. All the necessary electronics, specially, the preamplifier, that was also a restrictive factor for development of these types of probe in the country, have been developed with components found in the national market. Systematic measures of spatial resolution, spatial selectivity, maximum sensitivity and quality of the shielding have been carried the probes development. The results have shown that the probes, one with the CsI(Tl) crystal and another with TlBr semiconductor presented the requested performance in the international literature for radio guided probes. (author)

  9. Quartz microbalance device for transfer into ultrahigh vacuum systems

    International Nuclear Information System (INIS)

    Stavale, F.; Achete, C. A.; Niehus, H.

    2008-01-01

    An uncomplicated quartz microbalance device has been developed which is transferable into ultrahigh vacuum (UHV) systems. The device is extremely useful for flux calibration of different kinds of material evaporators. Mounted on a commercial specimen holder, the device allows fast quartz microbalance transfer into the UHV and subsequent positioning exactly to the sample location where subsequent thin film deposition experiments shall be carried out. After backtransfer into an UHV sample stage, the manipulator may be loaded in situ with the specimen suited for the experiment. The microbalance device capability is demonstrated for monolayer and submonolayer vanadium depositions with an achieved calibration sensitivity of less the 0.001 ML coverage.

  10. Nature sunlight bleaching of Ti center ESR signal in quartz

    International Nuclear Information System (INIS)

    Yin Gongming; Liu Chunru; Li Jianping; Fang Jiahu; Gao Lu; Lin Min

    2009-01-01

    Quartz grains were extracted from granite. Bleaching was carried out in four different area chosen for their different altitudes (Beijing, Yinchuan, Germu, Lhasa), in order to observe their behavior under different intensities of the UV (Ultra violet) component of sunlight. The result of our experiments indicate that the Ti center signal is totally bleachable by the natural sunlight and show that the Ti center signal was reduced to zero after about 128 h in Beijing and after 56 h for Lhasa. We can speculate that different intensity of the UV component of sunlight lead to different minimal time necessary to obtain the total bleaching of the quartz sample. (authors)

  11. Gas loading of graphene-quartz surface acoustic wave devices

    Science.gov (United States)

    Whitehead, E. F.; Chick, E. M.; Bandhu, L.; Lawton, L. M.; Nash, G. R.

    2013-08-01

    Graphene was transferred to the propagation path of quartz surface acoustic wave devices and the attenuation due to gas loading of air and argon measured at 70 MHz and 210 MHz and compared to devices with no graphene. Under argon loading, there was no significant difference between the graphene and non-graphene device and the values of measured attenuation agree well with those calculated theoretically. Under air loading, at 210 MHz, there was a significant difference between the non-graphene and graphene devices, with the average value of attenuation obtained with the graphene devices being approximately twice that obtained from the bare quartz devices.

  12. Exploring the thermoelectric and magnetic properties of uranium selenides: Tl2Ag2USe4 and Tl3Cu4USe6

    International Nuclear Information System (INIS)

    Azam, Sikander; Khan, Saleem Ayaz; Din, Haleem Ud; Khenata, Rabah; Goumri-Said, Souraya

    2016-01-01

    The electronic, magnetic and thermoelectric properties of Tl 2 Ag 2 USe 4 and Tl 3 Cu 4 USe 6 compounds were investigated using the full potential linear augmented plane wave (FP-LAPW) method based on the density functional theory (DFT). The exchange correlation was treated with the generalized gradient approximation plus optimized effective Hubbard parameter and spin–orbit coupling (GGA+U+SOC). The present uranium selenides show narrow direct energy band gap values of 0.7 and 0.875 eV for Tl 2 Ag 2 USe 4 and Tl 3 Cu 4 USe 6 respectively. For both selenides U-d/f states are responsible for electrical transport properties. Uranium atoms were the most contributors in the magnetic moment compared to other atoms and show ferromagnetic nature. The spin density isosurfaces show the polarization of neighboring atoms of Uranium, such as silver/copper and selenium. Thermoelectric calculations reveal that Tl 3 Cu 4 USe 6 is more suitable for thermoelectric device applications than Tl 2 Ag 2 USe 4 . - Highlights: • Electronic, magnetic and thermoelectric properties of uranium selenides are investigated with DFT. • They show a narrow direct energy band gap of 0.7 and 0.875 eV. • U-d/f states are responsible for electrical transport properties. • Tl 3 Cu 4 USe 6 is more suitable for thermoelectric device applications than Tl 2 Ag 2 USe 4 .

  13. Gamma-radiation-induced change in the activation energy of TL traps in LiRbSO[sub 4]:Tl

    Energy Technology Data Exchange (ETDEWEB)

    Kassem, M.E.; El-Kolaly, M.A.; Al-Houty, L.I. (Qatar Univ., Doha (Qatar). Dept. of Physics)

    1994-06-01

    Thermoluminescence (TL) measurements were carried out for pure and doped LiRbSO[sub 4], with different concentrations of thallium (Tl). The glow-curve range of measurement is between room temperature up to 300[sup o]C. The radiation absorbed dose is in the range 56-3.2 x 10[sup 5] Gy. The results show that both pure and doped samples have glow peak temperatures that are dose dependent, and vary between 70-80[sup o]C and 140-170[sup o]C for pure and doped samples respectively. Doped samples display double peaks that increase with dopant concentration up to about 0.7% wt. The second peak which occurs at high temperature increases linearly with dose up to 4500 Gy. From the results it is proposed that LiRbSO[sub 4] doped with 0.7% Tl can be used for dosimetric purposes in this range. The activation energies of structural transitions are estimated and the results are discussed on the basis of radiation-induced stable dipoles in the random field system. (Author).

  14. Isothermal and non-isothermal cure of a tri-functional epoxy resin (TGAP): a stochastic TMDSC study

    OpenAIRE

    Hutchinson, John M.; Shiravand, Fatemeh; Calventus Solé, Yolanda; Fraga Rivas, Iria

    2012-01-01

    The isothermal cure of a highly reactive tri-functional epoxy resin, tri-glycidyl para-amino phenol (TGAP), with diamino diphenyl sulphone (DDS), at two different cure temperatures Tc has been studied by both conventional differential scanning calorimetry (DSC) and by a stochastic temperature modulated DSC technique, TOPEM. From a series of isothermal cure experiments for increasing cure times, the glass transition temperature Tg as a function of isothermal cure time is determined by co...

  15. Removal of ammonium and heavy metals by cost-effective zeolite synthesized from waste quartz sand and calcium fluoride sludge.

    Science.gov (United States)

    Zhang, Qian; Lin, Bing; Hong, Junming; Chang, Chang-Tang

    2017-02-01

    This study focuses on the effectiveness of zeolite (10% CF-Z [0.5]) hydrothermally synthesized from waste quartz sand and calcium fluoride (CF) for ammonium ion and heavy metal removal. Zeolite was characterized through powder X-ray diffraction, Fourier-transform infrared spectroscopy, micromeritics N 2 adsorption/desorption analysis, and field emission scanning electron microscopy. The effects of CF addition, Si/Al ratio, initial ammonium concentration, solution pH, and temperature on the adsorption of ammonium on 10% CF-Z (0.5) were further examined. Results showed that 10% CF-Z (0.5) was a single-phase zeolite A with cubic-shaped crystals and 10% CF-Z (0.5) efficiently adsorbs ammonium and heavy metals. For instance, 91% ammonium (10 mg L -1 ) and 93% lead (10 mg L -1 ) are removed. The adsorption isotherm, kinetics, and thermodynamics of ammonium adsorption on 10% CF-Z (0.5) were also theoretically analyzed. The adsorption isotherm of ammonium and lead on 10% CF-Z (0.5) in single systems indicated that Freundlich model provides the best fit for the equilibrium data, whereas pseudo-second-order model best describes the adsorption kinetics. The adsorption degree of ions on 10% CF-Z (0.5) in mixed systems exhibits the following pattern: lead > ammonium > cadmium > chromium.

  16. Tunneling in cosmology and isothermal inflation

    International Nuclear Information System (INIS)

    Brout, R.; Spindel, P.

    1991-01-01

    The wave function for the universe, as proposed by Hartle and Hawking, experiences tunneling for small values of the radius of the universe. This induces thermal effects and so a hot big bang. We first give a detailed analysis of the observer accelerating in Minkowski space in terms of the tunneling of his wave function beyond his turning point. Applied to cosmology one finds a temperature at the big bang equal to the Gibbons-Hawking value. The residual thermal effects which result in an isothermal inflationary expansion give rise to a renormalized self-consistently determined Hubble constant (and hence Gibbons-Hawking temperature) through the trace anomaly. A thermodynamic interpretation is given. These results militate against phase transitions as a motor for inflation. (orig.)

  17. Moisture sorption isotherms of dehydrated whey proteins

    Directory of Open Access Journals (Sweden)

    Suzana Rimac Brnčić

    2010-03-01

    Full Text Available Moisture sorption isotherms describe the relation between the moisture content of the dry material (food and relative humidity of the surrounding environment. The data obtained are important in modelling of drying process conditions, packaging and shelf-life stability of food that will provide maximum retaining of aroma, colour and texture as well as nutritive and biological value. The objective of this research was to establish the equilibrium moisture content and water activity, as well as monolayer value of two commercial powdered whey protein isolates before and after tribomechanical micronisation and enzymatic hydrolysis, respectively. At the same time it was necessary to evaluate the best moisture sorption isotherm equation to fit the experimental data. The equilibrium moisture contents in investigated samples were determined using standard gravimetric method at 20 °C. The range of water activities was 0.11 to 0.75. The monolayer moisture content was estimated from sorption data using Brunauer-Emmett-Teller (BET and Guggenheim-Anderson-de Boer (GAB models. The results have shown that tribomechanically treated whey protein isolates as well as protein hydrolizates had lower monolayer moisture content values as well as higher corresponding water activity. Therefore, in spite of the fact that they have lower moisture content, they can be storage at higher relative humidity compared to untreated samples. BET model gave better fit to experimental sorption data for a water activity range from 0.11-0.54, while GAB model gave the closest fit for a water activity to 0.75.

  18. ANALYTICAL SOLUTIONS OF SINGULAR ISOTHERMAL QUADRUPOLE LENS

    International Nuclear Information System (INIS)

    Chu Zhe; Lin, W. P.; Yang Xiaofeng

    2013-01-01

    Using an analytical method, we study the singular isothermal quadrupole (SIQ) lens system, which is the simplest lens model that can produce four images. In this case, the radial mass distribution is in accord with the profile of the singular isothermal sphere lens, and the tangential distribution is given by adding a quadrupole on the monopole component. The basic properties of the SIQ lens have been studied in this Letter, including the deflection potential, deflection angle, magnification, critical curve, caustic, pseudo-caustic, and transition locus. Analytical solutions of the image positions and magnifications for the source on axes are derived. We find that naked cusps will appear when the relative intensity k of quadrupole to monopole is larger than 0.6. According to the magnification invariant theory of the SIQ lens, the sum of the signed magnifications of the four images should be equal to unity, as found by Dalal. However, if a source lies in the naked cusp, the summed magnification of the left three images is smaller than the invariant 1. With this simple lens system, we study the situations where a point source infinitely approaches a cusp or a fold. The sum of the magnifications of the cusp image triplet is usually not equal to 0, and it is usually positive for major cusps while negative for minor cusps. Similarly, the sum of magnifications of the fold image pair is usually not equal to 0 either. Nevertheless, the cusp and fold relations are still equal to 0 in that the sum values are divided by infinite absolute magnifications by definition.

  19. Tl-201 and Tc-99m-DTPA neuro-SPECT in cerebral radiation necrosis

    International Nuclear Information System (INIS)

    Cleto, E.M. Jr.; Holmes, R.A.; Gumerlock, M.K.; Cabeen, M.; Logan, K.W.; Hoffman, T.J.

    1992-01-01

    The results in 3 cases of radiation necrosis demonstrate that by using both radionuclides Tl-201 and Tc-99m-DTPA, one can provide a semi-quantitative method to differentiate recurrent tumor from radiation necrosis. Focally increased cerebral Tl-201 activity in irradiated brain tumor patients is not specific for tumor recurrence, but when used in combination with DTPA, one is able to estimate the amount of Tl-201 activity resulting from increased blood-brain barrier permeability. If the average Tl-201 index is less than the average Tc-99m-DTPA index it suggests that the increased Tl-201 activity results primarily from blood-brain barrier breakdown. Tc-99m-DTPA SPECT, in addition to Tl-201 SPECT, or serial Tl-201 SPECT imaging may increase the accuracy of brain scintigraphy in differentiating radiation necrosis from tumor recurrence. To verify these preliminary findings, we are in the process of analyzing additional SPECT data on 9 more patients with malignant brain tumors. Using a slightly different method of quantifying Tl- 201/Tc-99m-DTPA ratios (computing the ratio of intralesional Tl-201 or Tc-99m-DTPA activity compared to adjacent scalp activity), patients with tumor recurrence have higher Tl-201/Tc-99m-DTPA ratios compared to those with radiation necrosis (verbal communication with Dr. Mary K. Gumerlock). (orig.) [de

  20. Electronic structure of TlBa2CaCu2O7-δ

    Science.gov (United States)

    Vasquez, R. P.; Novikov, D. L.; Freeman, A. J.; Siegal, M. P.

    1997-06-01

    The core levels of TlBa2CaCu2O7-δ (Tl-1212) epitaxial films have been measured with x-ray photoelectron spectroscopy (XPS). The valence electronic structure has been determined using the full-potential linear muffin-tin-orbital band-structure method and measured with XPS. The calculations show that a van Hove singularity (VHS) lies above the Fermi level (EF) for the stoichiometric compound (δ=0), while for 50% oxygen vacancies in the Tl-O layer (δ=0.5) EF is in close proximity to the VHS. Samples annealed in nitrogen (to reduce the hole overdoping by the removal of oxygen) exhibit higher core-level binding energies and a higher Tc, consistent with a shift of EF closer to the VHS. Comparisons are made to the core levels and valence bands of Tl2Ba2CaCu2O8+δ (Tl-2212) and HgBa2CaCu2O6+δ (Hg-1212). The similarity of the Cu 2p3/2 spectra for Tl-1212 and Tl-2212 indicates that the number of Tl-O layers has little effect on the Cu-O bonding. However, the Tl-1212 and Hg-1212 Cu 2p3/2 signals exhibit differences which suggest that the replacement of Tl3+ with Hg2+ results in a decrease in the O 2p-->Cu 3d charge-transfer energy and differences in the probabilities of planar vs apical oxygen charge transfer and/or Zhang-Rice singlet-state formation. Differences between the Tl-1212 and the Tl-2212 and Hg-1212 measured valence bands are consistent with the calculated Cu 3d and (Tl,Hg) 6s/5d partial densities of states.

  1. Electronic structure of TlBa2CaCu2O7-δ

    International Nuclear Information System (INIS)

    Vasquez, R.P.; Novikov, D.L.; Freeman, A.J.; Siegal, M.P.

    1997-01-01

    The core levels of TlBa 2 CaCu 2 O 7-δ (Tl-1212) epitaxial films have been measured with x-ray photoelectron spectroscopy (XPS). The valence electronic structure has been determined using the full-potential linear muffin-tin-orbital band-structure method and measured with XPS. The calculations show that a van Hove singularity (VHS) lies above the Fermi level (E F ) for the stoichiometric compound (δ=0), while for 50% oxygen vacancies in the Tl-O layer (δ=0.5) E F is in close proximity to the VHS. Samples annealed in nitrogen (to reduce the hole overdoping by the removal of oxygen) exhibit higher core-level binding energies and a higher T c , consistent with a shift of E F closer to the VHS. Comparisons are made to the core levels and valence bands of Tl 2 Ba 2 CaCu 2 O 8+δ (Tl-2212) and HgBa 2 CaCu 2 O 6+δ (Hg-1212). The similarity of the Cu 2p 3/2 spectra for Tl-1212 and Tl-2212 indicates that the number of Tl-O layers has little effect on the Cu-O bonding. However, the Tl-1212 and Hg-1212 Cu 2p 3/2 signals exhibit differences which suggest that the replacement of Tl 3+ with Hg 2+ results in a decrease in the O 2p→Cu 3d charge-transfer energy and differences in the probabilities of planar vs apical oxygen charge transfer and/or Zhang-Rice singlet-state formation. Differences between the Tl-1212 and the Tl-2212 and Hg-1212 measured valence bands are consistent with the calculated Cu 3d and (Tl,Hg) 6s/5d partial densities of states. copyright 1997 The American Physical Society

  2. Chemical bonding in Tl cuprates studied by x-ray photoemission

    International Nuclear Information System (INIS)

    Vasquez, R.P.; Siegal, M.P.; Overmyer, D.L.; Ren, Z.F.; Lao, J.Y.; Wang, J.H.

    1999-01-01

    Epitaxial thin films of the Tl cuprate superconductors Tl 2 Ba 2 CaCu 2 O 8 , Tl 2 Ba 2 Ca 2 Cu 3 O 10 , and Tl 0.78 Bi 0.22 Ba 0.4 Sr 1.6 Ca 2 Cu 3 O 9-δ are studied with x-ray photoemission spectroscopy. These data, together with previous measurements in this lab of Tl 2 Ba 2 CuO 6+δ and TlBa 2 CaCu 2 O 7-δ , comprise a comprehensive data set for a comparative study of Tl cuprates with a range of chemical and electronic properties. In the Cu 2p spectra, a larger energy separation between the satellite and main peaks (E s -E m ) and a lower intensity ratio (I s /I m ) are found to correlate with higher values of T c . Analysis of these spectra within a simple configuration interaction model suggests that higher values of T c are related to low values of the O 2p→Cu 3d charge transfer energy. In the O 1s region, a smaller bond length between Ba and Cu-O planar oxygen is found to correlate with a lower binding energy for the signal associated with Cu-O bonding, most likely resulting from the increased polarization screening by Ba 2+ ions. For samples near optimum doping, maximum T c is observed to occur when the Tl 4f 7/2 binding energy is near 117.9 eV, which is near the middle of the range of values observed for Tl cuprates. Higher Tl 4f 7/2 binding energies, corresponding to formal oxidation states nearer Tl 1+ , are also found to correlate with longer bond lengths between Ba and Tl-O planar oxygen, and with higher binding energies of the O 1s signal associated with Tl-O bonding. copyright 1999 The American Physical Society

  3. A new equation of state for α-quartz

    Science.gov (United States)

    Magyar, Rudolph; Carpenter, John

    2015-06-01

    Quartz (SiO2) is often used as an optically transparent window for visar signals in shock experiments and is itself an active component of the experiments. Therefore, the shock response of quartz is an important input that must be known to high fidelity for precise measurement of other materials. We describe on-going work to develop a wide-range equation of state table that includes multiple phases and incorporates the latest high quality experimental and density functional theory (DFT) calculations. The emphasis in this work is the proper description of α-quartz along its principal Hugoniot through Stishovite and liquid phases. While molecular dissociation occurs at high pressures and temperatures, we find that an additional dissociation model is unnecessary. Although SiO2 possesses a number of solid phases, we restrict our focus to α-quartz and Stishovite as these two provide the density change along the Hugoniot path. We compare the model to recently measured data on Sandia's Z-machine. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE.

  4. Food irradiation dosimetry using thermoluminescence of quartz sand

    International Nuclear Information System (INIS)

    Khan, H.M.; Ehlermann, D.A.E.

    1993-01-01

    Thermoluminescence of quartz sand, which is inert and concomitant to several food materials, has been investigated for applications in food irradiation dosimetry and detection of irradiated foods. The glow curves consist of at least three overlapping peaks from 100 to 420 C. The peak at lower temperature is not stable and decays quickly at room temperature. However, the peaks at higher temperature are stable and more useful for dosimetry work. The intensity of the peak at 360 C, measured using different optical filters, shows a linear response in the range of 0.05 to 23 kGy. Stability of these signals at different annealing temperatures has been investigated. Thermoluminescence from adhering minerals and contaminating dust in different food materials has been found useful for the detection of irradiation treatment. Since quartz is frequently one of these minerals, further computerized deconvolution of individual glow peaks from the complex glow curves of quartz sand was carried out which improves the dosimetric results. Possible applications of thermoluminescence of quartz sand in food irradiation dosimetry and detection of irradiated foods have been discussed. (orig.)

  5. Characterization of silica quartz as raw material in photovoltaic applications

    Energy Technology Data Exchange (ETDEWEB)

    Boussaa, S. Anas, E-mail: sabiha.anas@gmail.com; Kheloufi, A.; Kefaifi, A.; Kerkar, F. [Division croissance cristalline et procédés métallurgiques CCPM Centre de recherche en technologie des semi-conducteurs pour l’énergétique (C.R.T.S.E) 02 Bd Frantz Fanon BP. 140 Alger 7 merveilles, Alger 16200 (Algeria); Zaourar, N. Boutarek [Laboratoire des technologies des matériaux, USTHB, B.P. 32 El Alia, Bab Ezzouar, Alger, Algérie 16111 (Algeria)

    2016-07-25

    Raw materials are essential for the functioning of modern societies, and access to these raw materials is vital to the world economy. Sustainable development, both globally level, raises important new challenges associated with access and efficient use of raw materials. High purity quartz, is consider as a critical raw material and it is a rare commodity that only forms under geological conditions where a narrow set of chemical and physical parameters is fulfilled. When identified and following special beneficiation techniques, high purity quartz obtains very attractive prices and is applied in high technology sectors that currently are under rapid expansion such as photovoltaic solar cells, silicon metal - oxide wafers in the semiconductor industry and long distance optical fibers that are used in communication networks. Crystalline silicon remains the principal material for photovoltaic technology. Metallurgical silicon is produced industrially by the reduction of silica with carbon in an electric arc furnace at temperatures higher than 2000 °C in the hottest parts, by a reaction that can be written ideally as: SiO{sub 2} + 2C = Si + 2CO. The aim of this study has been to test experimental methods for investigating the various physical and chemical proprieties of Hoggar quartz with different techniques: X Ray Fluorescence, infra-red spectroscopy, Scanning Electron Microscopy, Optic Microscopy, Carbon Analyzer and Vickers Hardness. The results show finally that the quartz has got good result in purity but need enrichment for the photovoltaic application.

  6. Quartz crystal microbalance gas sensor with nanocrystalline diamond sensitive layer

    Czech Academy of Sciences Publication Activity Database

    Varga, Marián; Laposa, A.; Kulha, Pavel; Kroutil, J.; Husák, M.; Kromka, Alexander

    2015-01-01

    Roč. 252, č. 11 (2015), s. 2591-2597 ISSN 0370-1972 R&D Projects: GA ČR(CZ) GBP108/12/G108 Institutional support: RVO:68378271 Keywords : gas sensor * nanocrystalline diamond * quartz resonator * thickness shear mode Subject RIV: JB - Sensor s, Measurment, Regulation Impact factor: 1.522, year: 2015

  7. Uraniferous quartz-pebble conglomerates in South Africa

    International Nuclear Information System (INIS)

    von Backstroem, J.W.

    1981-01-01

    The purpose of this paper is to give a short background statement summarizing data on the Dominion Reef Group, the Witwatersrand Supergroup, and the Ventersdorp Contact Reef, with particular reference to the close relationship of gold and uranium with sedimentary features as well as the mineralization, conditions of deposition, and the nature of the quartz-pebble conglomerates

  8. Absorbed dose evaluations in retrospective dosimetry: Methodological developments using quartz

    DEFF Research Database (Denmark)

    Bailiff, I.K.; Bøtter-Jensen, L.; Correcher, V.

    2000-01-01

    Dose evaluation procedures based on luminescence techniques were applied to 50 quartz samples extracted from bricks that had been obtained from populated or partly populated settlements in Russia and Ukraine downwind of the Chernobyl NPP. Determinations of accrued dose in the range similar to 30...

  9. A Transimpedance Amplifier for Remotely Located Quartz Tuning Forks

    OpenAIRE

    Kleinbaum, Ethan; Csathy, Gabor

    2012-01-01

    The cable capacitance in cryogenic and high vacuum applications of quartz tuning forks imposes severe constraints on the bandwidth and noise performance of the measurement. We present a single stage low noise transimpedance amplifier with a bandwidth exceeding 1 MHz and provide an in-depth analysis of the dependence of the amplifier parameters on the cable capacitance.

  10. Note: a transimpedance amplifier for remotely located quartz tuning forks.

    Science.gov (United States)

    Kleinbaum, Ethan; Csáthy, Gábor A

    2012-12-01

    The cable capacitance in cryogenic and high vacuum applications of quartz tuning forks imposes severe constraints on the bandwidth and noise performance of the measurement. We present a single stage low noise transimpedance amplifier with a bandwidth exceeding 1 MHz and provide an in-depth analysis of the dependence of the amplifier parameters on the cable capacitance.

  11. Triplet states at an O vacancy in alpha-quartz

    DEFF Research Database (Denmark)

    Lægsgaard, Jesper

    2002-01-01

    The energy landscape of an alpha-quartz O vacancy in the lowest triplet state is investigated. Four local minima are identified and geometries, total energies, and electron paramagnetic resonance (EPR) parameters are obtained. On the basis of calculated values for the magnetic dipole interaction...

  12. Electron spin resonance of Fe4+ in amethyst quartz

    International Nuclear Information System (INIS)

    Cox, R.T.

    1975-01-01

    The ESR spectrum of Fe 4+ was looked for in amethyst quartz. Besides saturated Fe 3+ lines, ESR lines of a new paramagnetic center whose spin-lattice relaxation time is relatively short were observed. They could be attributed to Fe 4+ [fr

  13. Absorption and luminescence of crystalline quartz under electron nanosecond irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Gritsenko, B P; Lisitsyn, V M; Stepanchuk, V N [Tomskij Politekhnicheskij Inst. (USSR)

    1981-02-01

    The purpose of the study is continuation of investigations of principal regularities of production and destruction of short-lived defects in quartz and accompanying luminescence under electron pulse irradiation. For investigation purposes samples of crystalline synthetic quartz have been used. The irradiation has been performed at 80-400 K temperatures by means of an electron pulse accelerator with parameters: electron flow pulse duration 10 ns, pulse current density up to 1000 A/cm/sup 2/, electron mean energy 200 keV. Temperature-time characteristics of absorption and luminescence spectrum are studied. It has been found that quartz irradiation by electron pulses of nanosecond duration leads to appearance of short-lived bands of optical absorption at 4.1 and 5.15 eV to which by kinetic parameters correspond luminescence bands at 2.6 and 3.1 eV, respectively. The enumerated absorption bands are induced by quartz irradiation independently of the prehistory and phase state of the sample and are caused obviously by intrinsic radiation defects. Possible models of such defects are suggested.

  14. QUARTZ: a numerical simulation of an asymmetric electrostatic accelerator

    International Nuclear Information System (INIS)

    Wooten, J.W.; Drooks, L.J.; McCollough, D.H.; McGaffey, R.W.; Whealton, J.H.

    1979-01-01

    The physics and numerical aspects of the development of the computer code QUARTZ are given. This code includes the (1) use of a finite element code to obtain solutions of Poisson's equation in an asymmetric, three-dimensional volume; (2) inclusion of space charge neutralization by electrons; and (3) inclusion of ion space charge through an iterative procedure

  15. Financial Statement Audit Report of Isothermal Community College.

    Science.gov (United States)

    Campbell, Ralph

    This report presents the results of the Isothermal Community College financial statement audit for the fiscal year ending on June 30, 1998. Isothermal Community College is a component of the State of North Carolina, thus the authority to audit is granted by Article 5A of G.S. 147. The accounts and operations of the institution were subject to…

  16. Adsorption isotherms and kinetics for dibenzothiophene on activated

    Indian Academy of Sciences (India)

    Adsorption isotherms were obtained and desulphurization kinetics were carried out on solutions of dibenzothiophene (DBT) and thiophene in a model fuel. The efficiencies of DBT and thiophene removal were reported. The adsorption isotherms fitted the Langmuir and Freundlich models. The highest adsorption capacity for ...

  17. Interpretation of Quasi-Isothermal Thermogravimetric Weight Curves

    DEFF Research Database (Denmark)

    Sørensen, Ole Toft

    1979-01-01

    Quasi-isothermal analysis (QIA) is a very useful technique. Compared to conventional non-isothermal thermogravimetry, close-lying reactions can easily be separated by use of this method and kinetic data can be obtained for each intermediate reaction in a single run. This paper discusses the shape...

  18. New Theoretical Expressions for the Five Adsorption Type Isotherms ...

    African Journals Online (AJOL)

    New Theoretical Expressions for the Five Adsorption Type Isotherms Classified by Bet Basing on Statistical Physics Treatment. ... that we have proposed, basing on statistical physics treatment, are rather powerful to better understand and interpret the various five physical adsorption Type isotherms at a microscopic level.

  19. Phase equilibria in TlX-Cd(Zn)X (X-S, Se, Te) systems

    International Nuclear Information System (INIS)

    Gusejnov, F.Kh.; Babanly, M.B.; Kuliev, A.A.

    1982-01-01

    The methods of DTA, RPA and measurement of the alloys microhardness have been used to investigate the phase equilibria in the TlX-Zn(Cd)X systems. It is established that the TlZn(Cd)X 2 compounds, the presence of which is mentioned in the literature earlier, do not form in these systems. The TlSe-Zn(Cd)Se systems apply to the simple eutectic type and characterized by digenerated eutectic near the TlSe. Thermodynamical analysis of the liquidus of the TlSe-CdSe and TlTe-Zn(Cd)Te systems in approximation of the regular solutions, taking into account the dissociation of tallium chalcogenides in liquid phase, is made

  20. TL and ESR based identification of gamma-irradiated frozen fish using different hydrolysis techniques

    Science.gov (United States)

    Ahn, Jae-Jun; Akram, Kashif; Shahbaz, Hafiz Muhammad; Kwon, Joong-Ho

    2014-12-01

    Frozen fish fillets (walleye Pollack and Japanese Spanish mackerel) were selected as samples for irradiation (0-10 kGy) detection trials using different hydrolysis methods. Photostimulated luminescence (PSL)-based screening analysis for gamma-irradiated frozen fillets showed low sensitivity due to limited silicate mineral contents on the samples. Same limitations were found in the thermoluminescence (TL) analysis on mineral samples isolated by density separation method. However, acid (HCl) and alkali (KOH) hydrolysis methods were effective in getting enough minerals to carry out TL analysis, which was reconfirmed through the normalization step by calculating the TL ratios (TL1/TL2). For improved electron spin resonance (ESR) analysis, alkali and enzyme (alcalase) hydrolysis methods were compared in separating minute-bone fractions. The enzymatic method provided more clear radiation-specific hydroxyapatite radicals than that of the alkaline method. Different hydrolysis methods could extend the application of TL and ESR techniques in identifying the irradiation history of frozen fish fillets.

  1. Differential diagnosis of thyroid diseases with 131I and 201TlCl scintigraphy

    International Nuclear Information System (INIS)

    Kumano, Machiko; Ishida, Osamu

    1979-01-01

    Scintigraphic study with 131 I and 201 TlCl was performed on the differential diagnosis of various kinds of thyroid disease. When thyroid nodules are cold by scintigraphy with 131 I and hot with 201 TlCl, the lesions were proved to be solid tumor, that is, mostly follicular adenoma and carcinoma, and also most probably chronic thyroiditis. Accumulation of 201 TlCl, however, is not observed in cystic lesions, and is very high with high frequency in metastatic lesion of the lymph nodes as well as the thyroid cancer, especially in well differentiated follicular carcinoma. Therefore 201 TlCl was very useful to confirm the metastatic tumors from the thyroid cancer. These features in accumulation of 131 I and 201 TlCl in thyroid disease suggest the imaging technique with 201 TlCl combined with 131 I seem to provide more pathological information on the thyroid and metastatic lesions. (author)

  2. Fracture flow due to hydrothermally induced quartz growth

    Science.gov (United States)

    Kling, Tobias; Schwarz, Jens-Oliver; Wendler, Frank; Enzmann, Frieder; Blum, Philipp

    2017-09-01

    Mineral precipitations are a common feature and limitation of initially open, permeable rock fractures by forming sealing structures or secondary roughness in open voids. Hence, the objective of this numerical study is the evaluation of hydraulic properties of fractures sealed by hydrothermally induced needle and compact quartz growth. Phase-field models of progressive syntaxial and idiomorphic quartz growth are implemented into a fluid flow simulation solving the Navier-Stokes equation. Flow simulations for both quartz types indicate an obvious correlation between changes in permeability, fracture properties (e.g. aperture, relative roughness and porosity) and crystal growth behavior, which also forms distinct flow paths. Thus, at lower sealing stages initial fracture permeability significantly drops down for the 'needle fracture' forming highly tortuous flow paths, while the 'compact fracture' records a considerably smaller loss. Fluid flow in both sealing fractures most widely is governed by a ;parallel plate;-like cubic law behavior. However, the 'needle fracture' also reveals flow characteristics of a porous media. A semi-theoretical equation is introduced that links geometrical (am) with hydraulically effective apertures (ah) and the relative fracture roughness. For this purpose, a geometry factor α is introduced being α = 2.5 for needle quartz and α = 1.0 for compact quartz growth. In contrast to most common ah-am-relationships this novel formulation not only reveals more precise predictions for the needle (RMSE = 1.5) and the compact fractures (RMSE = 3.2), but also exhibit a larger range of validity concerning the roughness of the 'needle' (σ/am = 0-2.4) and the 'compact fractures' (σ/am = 0-1.8).

  3. Radiation exposure around patients after 201Tl-myocardial scintigraphy

    International Nuclear Information System (INIS)

    Kurtaran, A.; Preitfellner, J.; Kohoutek, D.; Tousek, A.; Virgolini, I.; Havlik, E.

    1997-01-01

    Aim: It was the aim of the study to assess the additional radiation exposure to patients, attendents and nurses by patients who are undergoing nuclear medicine investigations (myocardial scintigraphy) with 201 Tl-chloride ( 201 Tl-Cl). Methode: In 16 cases the dose rates at 0.5, 1 and 2 m distance from patients were measured at 0.5, 1.5, 3-4 and 24, in some cases until 370 h after administration of 100±10 MBq 201 Tl-Cl. From the time courses of the dose rates around the patients the possible radiation exposure of other persons were estimated. Results: The initial values of the dose rate were 3.82 μSv/h at 0.5 m, 1.18 μSv/h at 1 m and 0.30 μSv/h at 2 m distance from the patients respectively. The dose rates were decreasing following a monoexponential course with an effective half-life of 60 h. The maximum doses to other persons at 1 m distance from the patients were determined by considering three scenarios. The values were 13 μSv in the waiting room, 26 μSv for nurses working in the ward and 105 μSv for persons living in the same household. Conclusion: Even at very restrictive assumptions the doses were far below the maximum permissible dose to non-radiation workers set by radiation protection regulations (1.5 mSv per year). (orig.) [de

  4. Dosimetric characteristics of LKB:Cu,P solid TL detector

    International Nuclear Information System (INIS)

    Hashim, S.; Alajerami, Y.S.M.; Ghoshal, S.K.; Saleh, M.A.; Saripan, M.I.; Kadir, A.B.A.; Bradley, D.A.; Alzimami, K.

    2014-01-01

    The dosimetric characteristics of newly developed borate glass dosimeter modified with lithium and potassium carbonate (LKB) and co-doped with CuO and NH 4 H 2 PO 4 are reported. Broad peaks in the absence of any sharp peak confirms the amorphous nature of the prepared glass. A simple glow curve of Cu doped sample is observed with a single prominent peak (T m ) at 220 °C. The TL intensity response shows an enhancement of ∼100 times due to the addition of CuO (0.1 mol%) to LKB compound. A further enhancement of the intensity by a factor of 3 from the addition of 0.25 mol% NH 4 H 2 PO 4 as a co-dopant impurity is attributed to the creation of extra electron traps with consequent increase in energy transfer of radiation recombination centers. The TL yield performance of LKB:Cu,P with Z eff ≈8.92 is approximately seventeen times less sensitive compared to LiF:Mg,Ti (TLD-100). The proposed dosimeter shows good linearity up to 10 3 Gy, minimal fading and photon energy independence. These attractive features offered by our dosimeter is expected to pave the way towards dosimetric applications. - Highlights: • The NH 4 H 2 PO 4 impurities are cross linked with the CuO defect. • The addition of NH 4 H 2 PO 4 as a co-dopant improved the TL intensity by a factor of 3. • The proposed dosimeter shows good linearity up to 10 3 Gy. • Minimal fading and photon energy independence were observed

  5. Model-based visual tracking the OpenTL framework

    CERN Document Server

    Panin, Giorgio

    2011-01-01

    This book has two main goals: to provide a unifed and structured overview of this growing field, as well as to propose a corresponding software framework, the OpenTL library, developed by the author and his working group at TUM-Informatik. The main objective of this work is to show, how most real-world application scenarios can be naturally cast into a common description vocabulary, and therefore implemented and tested in a fully modular and scalable way, through the defnition of a layered, object-oriented software architecture.The resulting architecture covers in a seamless way all processin

  6. Design and manufacture of TL analyser by using the microcomputer

    International Nuclear Information System (INIS)

    Doh, Sih Hong; Woo, Chong Ho

    1986-01-01

    This paper describes the design of the thermoluminescence analyser using microcomputer. TL analyser is designed to perform the three step heat treatment, such as pre-read heating, readout procedure and post-heating (or pre-irradiation ) anneal. We used a 12-bit A/D converter to get the precise measurement and the phase control method to control the heating temperature. Since the used Apple II microcomputer is cheap and popular, it is possible to design the economical system. Experimental results showed the successful operation with flexibility. The error of temperature control was less than ± 0.2% of the expected value. (Author)

  7. Environmental monitoring by CaSO4:Dy TL dosimeters

    International Nuclear Information System (INIS)

    Deme, S.; Szabo, P.P.

    1975-12-01

    The thermoluminescent dosimeters of high sensitivity are useful for monitoring the area near nuclear installations. CaSO 4 :Dy TL dosimeters have high sensitivity and low fading so that by means of them the dose from the background can be measured with an accuracy of 10-20%. An increase of 2 mR in the background can be observed and doses as high as 1000R can be registered with an accuracy of 5%. The measuring method and results are reported here. For two years these CaSO 4 :Dy dosimeters have been successfully used at the site of the Central Research Institute for Physics. (K.A.)

  8. MF-plan till företaget Design TL

    OpenAIRE

    Virtanen, Aino

    2015-01-01

    Examensarbetet gjordes för företaget Design TL med uppgiften att göra en mark-nadsföringsplan för företaget som skall starta verksamheten 2016. Detta examensar-bete har utförts genom litteraturstudie och information av uppdragsgivaren. Upp-dragsgivaren var Tarja Lamberg. Företaget sysslar med konst, konsthantverks plane-ring och design, tillverkning och försäljning. Uppdragsgivaren gav mig fria händer med planet, det enda som skulle tas i beakta var den begränsade budgeten. Teoride-len satte...

  9. Spins of superdeformed rotational bands in Tl isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Dadwal, Anshul; Mittal, H.M. [Dr. B.R. Ambedkar National Institute of Technology, Jalandhar (India)

    2017-01-15

    The two-parameter model defined for even-even nuclei viz. soft-rotor formula is used to assign the band-head spin of the 17 rotational bands in Tl isotopes. The least-squares fitting method is employed to obtain the spins of these bands in the A ∝ 190 mass region. The calculated transition energies are found to depend sensitively on the proposed spin. Whenever a correct spin assignment is made, the calculated and experimental transition energies coincide very well. The dynamic moment of inertia is also calculated and its variation with rotational frequency is explored. (orig.)

  10. Double blocking in the superdeformed {sup 192}Tl nucleus

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Y; Carpenter, M P; Janssens, R V.F.; Ahmad, I; Henry, R; Khoo, T L; Lauritsen, T [Argonne National Lab., IL (United States); Soramel, F [Padova University, Padova (Italy); Pilotte, S [Ottawa Univ., ON (Canada); Lewis, J M; Riedinger, L L; Yu, C H [Tennessee Univ., Knoxville, TN (United States); Garg, U; Reviol, W [Notre Dame Univ., IN (United States); Bearden, I G [Purdue Univ., Lafayette, IN (United States)

    1992-08-01

    Six superdeformed bands have been found in the nucleus {sup 192}Tl. For two of the bands, the dynamic moment of inertia J{sup (2)} is found to be constant with the rotational frequency {Dirac_h}{omega}. This result can be understood in terms of Pauli blocking of quasiparticle alignments in intruder orbitals, and represents the first experimental evidence that the alignment of these intruders is responsible for the smooth rise in J{sup (2)} seen in other superdeformed nuclei of this mass region. (author). 18 refs., 2 figs.

  11. Scintigraphic detection of ischemic and other myocardial lesions using 201Tl

    International Nuclear Information System (INIS)

    Duska, F.; Novak, J.; Vizda, J.; Kubicek, J.; Kafka, P.

    1981-01-01

    Current knowledge of the myocardium scintiscanning using 201 Tl is briefly outlined. The principle is shown of 201 Tl cumulation in a healthy myocardium and the use of the radionuclide is justified. Heart scintiscanning after exercise or after administration of drugs increasing the blood flow through the coronaries allows detecting latent ischaemic heart disease. 201 Tl scintigraphy can also be used for diagnosing the myocardial infarction, angina pectoris and other heart diseases. (J.P.)

  12. Electronic Structure of TlBa2CaCu2O(7-Delta)

    Science.gov (United States)

    Vasquez, R. P.; Novikov, D. L.; Freeman, A. J.; Siegal, M. P.

    1997-01-01

    The core levels of TlBa2CaCu2O(7-delta) (Tl-1212) epitaxial films have been measured with X-ray photoelectron spectroscopy (XPS). The valence electronic structure has been determined using the full-potential linear muffin-tin-orbital band-structure method and measured with XPS. The calculations show that a van Hove singularity (VHS) lies above the Fermi level (E(sub F)) for the stoichiometric compound (delta = 0.5), while for 50% oxygen vacancies in the Tl-O layer (delta = 0.5) E(sub F) is in close proximity to the VHS. Samples annealed in nitrogen (to reduce the hole overdoping by the removal of oxygen) exhibit higher core-level binding energies and a higher T(sub c), consistent with a shift of E(sub F) closer to the VHS. Comparisons are made to the core levels and valence bands of Tl2Ba2CaCu2O(8 + delta)(Tl-2212) and HgBa2CaCu2O)6 + delta) (Hg- 1212). The similarity of the Cu 2p(sub 3/2) spectra for Tl-1212 and Tl-2212 indicates that the number of Tl-O layers has little effect on the Cu-O bonding. However, the Tl-1212 and Hg-1212 Cu 2p(sub 3/2) signals exhibit differences which suggest that the replacement of T(sup 3+) with Hg(sup 2+) results in a decrease in the O 2p right arrow Cu 3d charge-transfer energy and differences in the probabilities of planar vs apical oxygen charge transfer and/or Zhang-Rice singlet-state formation. Differences between the Tl-1212 and the Tl-2212 and Hg-1212 measured valence bands are consistent with the calculated Cu 3d and (Tl,Hg) 6s/5d partial densities of states.

  13. Photo-TL in CaSO4:Dy: high exposure dosimetry

    International Nuclear Information System (INIS)

    Caldas, L.V.E.; Mayhugh, M.R.

    1974-01-01

    CaSO 4 :Dy exposed to 10 3 to 10 8 R then annealed in the range 280 to 400 0 C displays little TL in the major dosimetry peak near 200 0 C. Subsequent illumination with 250 nm light reinduces the 200 0 C TL. This radiation-enabled photo-TL is roughly proportional to the square root of the enabling exposure at least to 10 8 R. (auth)

  14. Microcomputer-Controlled Reader Systems for Archaeological and Geological TL Dating

    DEFF Research Database (Denmark)

    Bøtter-Jensen, Lars; Mejdahl, V.

    1984-01-01

    Two fully automated TL reader systems for TL dating and a manually operated reader for research purpose were put into operation during 1982-3. All systems are controlled by HP-85 or HP-86 microcomputers; thus flexibility in selection of measurement parameters, calculation of TL signals and displa...... the archaeological and geological ages. The principle of the measurement procedures are described, and dating results are presented to illustrate the performance of the systems...

  15. A High Sensitivity Preamplifier for Quartz Tuning Forks in QEPAS (Quartz Enhanced PhotoAcoustic Spectroscopy Applications

    Directory of Open Access Journals (Sweden)

    Tomasz Starecki

    2017-11-01

    Full Text Available All the preamplifiers dedicated for Quartz Enhanced PhotoAcoustic Spectroscopy (QEPAS applications that have so far been reported in the literature have been based on operational amplifiers working in transimpedance configurations. Taking into consideration that QEPAS sensors are based on quartz tuning forks, and that quartz has a relatively high voltage constant and relatively low charge constant, it seems that a transimpedance amplifier is not an optimal solution. This paper describes the design of a quartz QEPAS sensor preamplifier, implemented with voltage amplifier configuration. Discussion of an electrical model of the circuit and preliminary measurements are presented. Both theoretical analysis and experiments show that use of the voltage configuration allows for a substantial increase of the output signal in comparison to the transimpedance circuit with the same tuning fork working in identical conditions. Assuming that the sensitivity of the QEPAS technique depends directly on the properties of the preamplifier, use of the voltage amplifier configuration should result in an increase of QEPAS sensitivity by one to two orders of magnitude.

  16. A High Sensitivity Preamplifier for Quartz Tuning Forks in QEPAS (Quartz Enhanced PhotoAcoustic Spectroscopy) Applications.

    Science.gov (United States)

    Starecki, Tomasz; Wieczorek, Piotr Z

    2017-11-03

    All the preamplifiers dedicated for Quartz Enhanced PhotoAcoustic Spectroscopy (QEPAS) applications that have so far been reported in the literature have been based on operational amplifiers working in transimpedance configurations. Taking into consideration that QEPAS sensors are based on quartz tuning forks, and that quartz has a relatively high voltage constant and relatively low charge constant, it seems that a transimpedance amplifier is not an optimal solution. This paper describes the design of a quartz QEPAS sensor preamplifier, implemented with voltage amplifier configuration. Discussion of an electrical model of the circuit and preliminary measurements are presented. Both theoretical analysis and experiments show that use of the voltage configuration allows for a substantial increase of the output signal in comparison to the transimpedance circuit with the same tuning fork working in identical conditions. Assuming that the sensitivity of the QEPAS technique depends directly on the properties of the preamplifier, use of the voltage amplifier configuration should result in an increase of QEPAS sensitivity by one to two orders of magnitude.

  17. Recovery of 201Tl by ion exchange chromatography from proton bombarded thallium cyclotron targets

    International Nuclear Information System (INIS)

    Walt, T.N. van der; Naidoo, C.

    2000-01-01

    A method based on ion exchange chromatography is presented for the recovery of 201 Tl and its precursor 201 Pb from proton bombarded natural thallium cyclotron targets. After bombardment the target is dissolved in diluted nitric acid. Water, hydrazine and ammonium acetate are added to the solution and the lead radioisotopes separated from the thallium by cation exchange chromatography on a Bio-Rex 70 column. The sorbed lead radioisotopes are eluted with dilute nitric acid and the separation repeated on a second Bio-Rex 70 column. After elution of the remaining thallium the column is left for 32 hours and the 201 Tl formed by decay of 201 Pb is eluted with an ammonium acetate solution. The 201 Tl eluate is acidified with a HNO 3 -HBr-Br 2 mixture and the resulting solution is passed through an AG MP-1 anion exchanger column to remove any remaining lead isotopes. The 201 Tl is eluted with a hydrazine solution, the eluate evaporated to dryness and the 201 Tl finally dissolved in an appropriate solution to produce a 201 TlCl solution suitable for medical use. A high quality 201 Tl product is obtained containing ≤ 0.1 μg of Tl/mCi (37 MBq) 201 Tl. The radionuclidic impurities are less than the maximum values specified by the US Pharmacopoeia and the British Pharmacopoeia. (orig.)

  18. Measurements of environmental gamma-ray spectra using a multi-element TL dosemeter

    International Nuclear Information System (INIS)

    Furuta, Sadaaki; Boetter-Jensen, L.; Nielsen, S.P.

    1986-12-01

    A method to estimate the energy distribution and dose of environmental gamma radiation was developed using a multielement TL dosemeter. Experimentally obtained energy responses from a multi-element TL dosemeter with different kinds of filters were used to calculate the energy distribution and related dose by the SAND-II computer code. The code was originally developed to estimate the neutron flux using a multiple foil activation method. Measurements were made at several locations with the multi-element TL dosemeter and comparisons were made with results from a NaI(Tl) scintillation detector and a high-pressure ionization chamber. (author)

  19. How Experienced SoTL Researchers Develop the Credibility of Their Work

    Directory of Open Access Journals (Sweden)

    Jennie Billot

    2017-03-01

    Full Text Available Teaching and learning research in higher education, often referred to as the Scholarship of Teaching and Learning (SoTL, is still relatively novel in many academic contexts compared to the mainstay of disciplinary research. One indication of this is the challenges those who engage in SoTL report in terms of how this work is valued or considered credible amongst disciplinary colleagues and in the face of institutional policies and practices. This paper moves beyond the literature that describes these specific challenges to investigate how 23 experienced SoTL researchers from five different countries understood the notion of credibility in relationship to their SoTL research and how they went about developing credibility for their work. Semi-structured interviews were facilitated and analyzed using inductive analysis. Findings indicate that notions of credibility encompassed putting SoTL research into action and building capacity and community around research findings, as well as gaining external validation through traditional indicators such as publishing. SoTL researchers reported a variety of strategies and approaches they were using, both formal and informal, to develop credibility for their work. The direct focus of this paper on credibility of SoTL work as perceived by experienced SoTL researchers, and how they go about developing credibility, is a distinct contribution to the discussions about the valuing of SoTL work.

  20. Self-trapping nature of Tl nanoclusters on the Si(111)-7x7 surface

    International Nuclear Information System (INIS)

    Hwang, C G; Kim, N D; Lee, G; Shin, S Y; Kim, J S; Chung, J W

    2008-01-01

    We have studied properties of thallium (Tl) nanoclusters formed on the Si(111)-7x7 surface at room temperature (RT) by utilizing photoemission spectroscopy (PES) and high-resolution electron-energy-loss spectroscopy (HREELS) combined with first principles calculations. Our PES data reveal that the surface states stemming from the Si substrate remain quite inert with Tl adsorption producing no Tl-induced state until saturation at Tl coverage θ=0.21 monolayers. Such a behavior, in sharp contrast with the extremely reactive surface states upon the formation of Na or Li nanoclusters, together with the presence of a unique Tl-induced loss peak in HREELS spectra suggests no strong Si-Tl bonding, and is well understood in terms of gradual filling of Si dangling bonds with increasing θ. Our calculation further indicates the presence of several metastable atomic structures of Tl nanoclusters at RT rapidly transforming from one to another faster than 10 10 flippings per second. We thus conclude that the highly mobile Tl atoms form self-trapped nanoclusters within the attractive basins of the Si substrate at RT with several metastable phases. The mobile and multi-phased nature of Tl nanoclusters not only accounts for all the existing experimental observations available at present, but also provides an example of self-trapping of atoms in a nanometre-scale region

  1. Auto-regenerative TL dating with zircon inclusions from fired materials

    International Nuclear Information System (INIS)

    Templer, R.H.; Smith, B.W.

    1988-01-01

    In this paper it is shown that it is possible to date fired material using zircon inclusions. The effects of zoning and anomalous fading are overcome using an auto-regenerative dating procedure. The high radioactivity of the grains gives a measurable self-induced TL (thermoluminescence) signal within a few months. Comparison of this ''auto-regenerated'' TL with the natural TL (which has accumulated since the firing) yields the age of the material. A sensitive TL reader capable of recording the auto-regenerated signal after 6 months is also described, and the results of age determinations on a number of known age samples are presented. (author)

  2. Two cases of hyperparathyroidism revealed by /sup 201/Tl-chloride

    Energy Technology Data Exchange (ETDEWEB)

    Otsuka, Kokichi; Asano, Haruko; Moriyama, Shigeharu (Okayama Red Cross Hospital (Japan))

    1983-08-01

    /sup 201/Tl scintigraphy at 15 min and 120 min after intravenous injection of /sup 201/TlCl revealed a parathyroidal adenoma (1.7g) in a 49-year-old female patient with hyperthyroidism complicated by renal calculi and that (1.8g) in a 58-year-old female patient without symptoms. /sup 75/Se could be substituted by /sup 201/Tl which was useful for localizing parathyroidal adenoma in hyperparathyroidism. /sup 201/Tl scintigraphy revealed the adenoma which was not palpable. The smallest adenoma detected by it was 0.9g.

  3. Properties and behavior of quartz for the silicon process

    Energy Technology Data Exchange (ETDEWEB)

    Aasly, Kurt

    2008-07-01

    This PhD-thesis is a result of the study on important properties of quartz as a raw material for the metallurgical production of ferrosilicon and silicon metal. This includes defining mechanical properties important for the size reduction experienced during transport and storage and thermo-mechanical properties of quartz that is important for how the quartz reacts to the high temperatures experienced as it is charged on the furnace. Additionally, softening properties of quartz have been briefly discussed in some of the papers. Another important goal has been to test analytical and experimental methods for investigating the various properties. The investigations of important factors for the mechanical properties of ores and industrial minerals have been carried out as a literature study. The mining operation and transport from mine to smelter has been discussed and several factors that are significant for achieving best possible mechanical properties of the quartz have been identified. The most important factors are related to production in the mine and processing plant, which should be carefully planned to minimize the amount of blast-induced damage in the rock and thus achieve the best possible mechanical strength of the raw material. The amount of fines can be minimized by controlling the handling of the raw materials during the transport and storage. It is especially important to avoid high drops, both high single drops and accumulated height of all the drops in total. Investigations of the thermo-mechanical properties of quartz have been carried out by using different experimental and characterization methods. The petrographic investigations of the raw materials by polarized light microscopy have been important. Thermo-mechanical investigations have been high-temperature microthermometry and shock heating of quartz samples in an induction furnace with subsequent investigations of the heated material. The subsequent investigation included polarized- and

  4. Adsorption isotherm special study. Final report

    International Nuclear Information System (INIS)

    1993-05-01

    The study was designed to identify methods to determine adsorption applicable to Uranium Mill Tailings Remedial Action (UMTRA) Project sites, and to determine how changes in aquifer conditions affect metal adsorption, resulting retardation factors, and estimated contaminant migration rates. EPA and ASTM procedures were used to estimate sediment sorption of U, As, and Mo under varying groundwater geochemical conditions. Aquifer matrix materials from three distinct locations at the DOE UMTRA Project site in Rifle, CO, were used as the adsorbents under different pH conditions; these conditions stimulated geochemical environments under the tailings, near the tailings, and downgradient from the tailings. Grain size, total surface area, bulk and clay mineralogy, and petrography of the sediments were characterized. U and Mo yielded linear isotherms, while As had nonlinear ones. U and Mo were adsorbed strongly on sediments acidified to levels similar to tailings leachate. Changes in pH had much less effect on As adsorption. Mo was adsorbed very little at pH 7-7.3, U was weakly sorbed, and As was moderately sorbed. Velocities were estimated for metal transport at different pHs. Results show that the aquifer materials must be characterized to estimate metal transport velocities in aquifers and to develop groundwater restoration strategies for the UMTRA project

  5. Isothermal thermogravimetric data acquisition analysis system

    Science.gov (United States)

    Cooper, Kenneth, Jr.

    1991-01-01

    The description of an Isothermal Thermogravimetric Analysis (TGA) Data Acquisition System is presented. The system consists of software and hardware to perform a wide variety of TGA experiments. The software is written in ANSI C using Borland's Turbo C++. The hardware consists of a 486/25 MHz machine with a Capital Equipment Corp. IEEE488 interface card. The interface is to a Hewlett Packard 3497A data acquisition system using two analog input cards and a digital actuator card. The system provides for 16 TGA rigs with weight and temperature measurements from each rig. Data collection is conducted in three phases. Acquisition is done at a rapid rate during initial startup, at a slower rate during extended data collection periods, and finally at a fast rate during shutdown. Parameters controlling the rate and duration of each phase are user programmable. Furnace control (raising and lowering) is also programmable. Provision is made for automatic restart in the event of power failure or other abnormal terminations. Initial trial runs were conducted to show system stability.

  6. Isothermal recovery rates in shape memory polyurethanes

    International Nuclear Information System (INIS)

    Azra, Charly; Plummer, Christopher J G; Månson, Jan-Anders E

    2011-01-01

    This work compares the time dependence of isothermal shape recovery in thermoset and thermoplastic shape memory polyurethanes (SMPUs) with comparable glass transition temperatures. In each case, tensile tests have been used to quantify the influence of various thermo-mechanical programming parameters (deformation temperature, recovery temperature, and stress and storage times following the deformation step) on strain recovery under zero load (free recovery) and stress recovery under fixed strain (constrained recovery). It is shown that the duration of the recovery event may be tuned over several decades of time with an appropriate choice of programming parameters, but that there is a trade-off between the rate of shape recovery and the recoverable stress level. The results are discussed in terms of the thermal characteristics of the SMPUs in the corresponding temperature range as characterized by modulated differential scanning calorimetry and dynamic mechanical analysis, with the emphasis on the role of the effective width of the glass transition temperature and the stability of the network that gives rise to the shape memory effect. (fast track communication)

  7. Reverse 201Tl myocardial redistribution induced by coronary artery spasm

    International Nuclear Information System (INIS)

    Xiang Dingcheng; Yin Jilin; Gong Zhihua; Xie Zhenhong; Zhang Jinhe; Wen Yanfei; Yi Shaodong

    2010-01-01

    Objective: To investigate the mechanism of reverse redistribution (RR) on dipyridamole 201 Tl myocardial perfusion studies in the patients with coronary artery spasm. Methods: Twenty-six patients with coronary artery spasm and presented as RR on dipyridamole 201 Tl myocardial perfusion studies were enlisted as RR group, while other 16 patients with no coronary artery stenosis nor RR were enlisted as control group. Dipyridamole test was repeated during coronary angiography. Corrected thrombolysis in myocardial infarction (TIMI) frame count (CTFC) and TIMI myocardial perfusion grade (TMPG) were measured at RR related and non-RR related coronary arteries before and after dipyridamole infusion respectively. All of the data were analyzed by Student's t-test or χ 2 -test and correlation analysis. Results: Coronary artery angiography showed slower blood flow and lower myocardial perfusion in RR related vessels when compared with non-RR related vessels in RR group, but there was no significant difference among the main coronary arteries in control group. The perfusion defects of RR area at rest were positively related to slower blood velocity at corresponding coronary arteries (r = 0.79, t =10.18, P 0.05). Conclusion: RR is related to the decreased blood flow and myocardial perfusion induced by coronary artery spasm at rest, which may be improved by stress test such as intravenous dipyridamole infusion. (authors)

  8. Radiation accident dosimetry: TL properties of mobile phone screen glass

    International Nuclear Information System (INIS)

    Bassinet, C.; Pirault, N.; Baumann, M.; Clairand, I.

    2014-01-01

    Mobile phones are carried by a large part of the population and previous studies have shown that they may be able to function as individual fortuitous dosimeters in case of radiological accident. This study deals with thermoluminescence (TL) properties of mobile phone screen glass. The presence of a significant background signal which partially overlaps with the radiation-induced signal is a serious issue for dose reconstruction. A mechanical method to reduce this signal using a diamond grinding bit is presented. An over-response at low energy (∼50 keV) is observed for two investigated glasses. The results of a dose recovery test using a single-aliquot regenerative-dose (SAR) procedure are discussed. - Highlights: • Mobile phone screen glass is a promising material for retrospective dosimetry. • The TL non-radiation induced background signal can be significantly reduced by a mechanical method. • A dose recovery test using an SAR procedure was successfully carried out for the investigated glass

  9. Developing SoTL through Organized Scholarship Institutes

    Directory of Open Access Journals (Sweden)

    Elizabeth Marquis

    2015-12-01

    Full Text Available The need to further integrate SoTL into college and university cultures has been discussed relatively frequently in recent teaching and learning literature. While a number of useful strategies to assist in this task have been advanced, one especially promising suggestion is the development of organized, institutionally-recognized scholarship institutes. Centres or units of this sort have been created at higher education institutions in a number of countries, but little published information currently exists about the design of these institutes or the experiences of individuals affiliated with them. To that end, the present study sought to examine the perceived benefits, challenges and design features of teaching and learning scholarship institutes at research-intensive universities worldwide. A website scan and a survey of individuals affiliated with these units were used to collect qualitative and quantitative data of relevance to the research questions. Based on the findings, and on ideas from the existing research institute and scholarship of teaching and learning literatures, a series of recommendations for individuals and campuses interested in developing effective SoTL institutes are provided.

  10. Evaluation of Tl-201 SPECT imaging findings in prostate cancer

    Directory of Open Access Journals (Sweden)

    Sinem Ozyurt

    2015-07-01

    Full Text Available Objectives: To compare with histopathological findings the findings of prostate cancer imaging by SPECT method using Tl-201 as a tumor seeking agent. Methods: The study comprised 59 patients (age range 51-79 years, mean age 65.3 ± 6.8 years who were planned to have transrectal ultrasonography (TRUS-guided biopsies due to suspicion of prostate cancer between April 2011 and September 2011. Early planar, late planar and SPECT images were obtained for all patients. Scintigraphic evaluation was made in relation to uptake presence and patterns in the visual assessment and to Tumor/Background (T/Bg ratios for both planar and SPECT images in the quantitative assessment. Histopathological findings were compatible with benign etiology in 36 (61% patients and malign etiology in 23 (39% patients. Additionally, comparisons were made to evaluate the relationships between uptake patterns,total PSA values and Gleason scores. Results: A statistically significant difference was found between the benign and malignant groups in terms of uptake in planar and SPECT images and T/Bg ratios and PSA values. No statistically significant difference was found between uptake patterns of planar and SPECT images and Gleason scores in the malignant group. Conclusions: SPECT images were superior to planar images in the comparative assessment. Tl-201 SPECT imaging can provide an additional contribution to clinical practice in the diagnosis of prostate cancer and it can be used in selected patients.

  11. 75 FR 30282 - Airworthiness Directives; Quartz Mountain Aerospace, Inc. Model 11E Airplanes

    Science.gov (United States)

    2010-06-01

    ... Airworthiness Directives; Quartz Mountain Aerospace, Inc. Model 11E Airplanes AGENCY: Federal Aviation... airworthiness directive (AD) for all Quartz Mountain Aerospace, Inc. Model 11E airplanes. This AD requires you... reference of certain publications listed in this AD. ADDRESSES: Quartz Mountain Aerospace, Inc. is in...

  12. Phase field modeling of dendritic coarsening during isothermal

    Directory of Open Access Journals (Sweden)

    Zhang Yutuo

    2011-08-01

    Full Text Available Dendritic coarsening in Al-2mol%Si alloy during isothermal solidification at 880K was investigated by phase field modeling. Three coarsening mechanisms operate in the alloy: (a melting of small dendrite arms; (b coalescence of dendrites near the tips leading to the entrapment of liquid droplets; (c smoothing of dendrites. Dendrite melting is found to be dominant in the stage of dendritic growth, whereas coalescence of dendrites and smoothing of dendrites are dominant during isothermal holding. The simulated results provide a better understanding of dendrite coarsening during isothermal solidification.

  13. Total Correlation Function Integrals and Isothermal Compressibilities from Molecular Simulations

    DEFF Research Database (Denmark)

    Wedberg, Rasmus; Peters, Günther H.j.; Abildskov, Jens

    2008-01-01

    Generation of thermodynamic data, here compressed liquid density and isothermal compressibility data, using molecular dynamics simulations is investigated. Five normal alkane systems are simulated at three different state points. We compare two main approaches to isothermal compressibilities: (1...... in approximately the same amount of time. This suggests that computation of total correlation function integrals is a route to isothermal compressibility, as accurate and fast as well-established benchmark techniques. A crucial step is the integration of the radial distribution function. To obtain sensible results...

  14. Experimental study of quartz inclusions in garnet at pressures up to 3.0 GPa: evaluating validity of the quartz-in-garnet inclusion elastic thermobarometer

    Science.gov (United States)

    Thomas, Jay B.; Spear, Frank S.

    2018-05-01

    Garnet crystals with quartz inclusions were hydrothermally crystallized from oxide starting materials in piston-cylinder apparatuses at pressures from 0.5 to 3 GPa and temperatures ranging from 700 to 800 °C to study how entrapment conditions affect remnant pressures of quartz inclusions used for quartz-in-garnet (QuiG) elastic thermobarometry. Systematic changes of the 128, 206 and 464 cm-1 Raman band frequencies of quartz were used to determine pressures of quartz inclusions in garnet using Raman spectroscopy calibrations that describe the P-T dependencies of Raman band shifts for quartz under hydrostatic pressure. Within analytical uncertainties, inclusion pressures calculated for each of the three Raman band frequencies are equivalent, which suggests that non-hydrostatic stress effects caused by elastic anisotropy in quartz are smaller than measurement errors. The experimental quartz inclusions have pressures ranging from - 0.351 to 1.247 GPa that span the range of values observed for quartz inclusions in garnets from natural rocks. Quartz inclusion pressures were used to model P-T conditions at which the inclusions could have been trapped. The accuracy of QuiG thermobarometry was evaluated by considering the differences between pressures measured during experiments and pressures calculated using published equation of state parameters for quartz and garnet. Our experimental results demonstrate that Raman measurements performed at room temperature can be used without corrections to estimate garnet crystallization pressures. Calculated entrapment pressures for quartz inclusions in garnet are less than 10% different from pressures measured during the experiments. Because the method is simple to apply with reasonable accuracy, we expect widespread usage of QuiG thermobarometry to estimate crystallization conditions for garnet-bearing silicic rocks.

  15. Spectrographic analysis of metallic silicium and natural quartz

    International Nuclear Information System (INIS)

    Grigoletto, T.; Lordello, A.R.

    1985-01-01

    A method has been developed for the spectrographic determination of B, Mg, Al, Ca, Ti, Mn, Fe, Ni, Cu and Ag in silicon metal and other for Al, Ca, Mg, Ti, Cr, Mn, and Fe in natural quartz. A mixture of the matrix with a proper buffer is excited directly in a dc-arc. High-current (25A) and argon atmosphere are used for both the methods. Silicon metal is blended with 8% NaF and after 1:1 (w/w) with graphite. For natural quartz 20% NaF and 30% graphite by weight is the buffer mixture employed. The lower values in the determinations varies from 0.5 to 40 μg/g and the precision of the analysis from 7% to 45%. (Author) [pt

  16. Measurement of fast risetime megampere currents by quartz gauge

    International Nuclear Information System (INIS)

    Williams, R.R.; McDaniel, D.H.; Stinnett, R.W.

    1980-01-01

    Quartz gauges have been used on the Sandia National Laboratories Proto II accelerator to measure current in the magnetically insulated transmission line at the 11 TW power level. The accelerator delivers 3.5 MA at 2 x 10 14 A/s in a 40 ns pulse to a 0.0127 m diameter aluminum liner to produce a high density plasma. At this radius and dI/dt levels, the B-dot monitors no longer function for the measurement of load current because the monitor suffers electrical breakdown. Quartz pressure gauges mounted at a radius of 0.0086 m have successfully measured the magnetic pressure due to the load current with nanosecond temporal resolution

  17. A quartz crystal microbalance dew point sensor without frequency measurement

    Science.gov (United States)

    Wang, Guohua; Zhang, Weishuo; Wang, Shuo; Sun, Jinglin

    2014-11-01

    This work deals with the design of a dew point sensor based on Quartz Crystal Microbalance (QCM) without measuring the frequency. This idea is inspired by the fact that the Colpitts oscillation circuit will stop oscillating when the QCM works in the liquid media. The quartz crystal and the electrode are designed through the finite element simulation and the stop oscillating experiment is conducted to verify the sensibility. Moreover, the measurement result is calibrated to approach the true value. At last a series of dew points at the same temperature is measured with the designed sensor. Results show that the designed dew point sensor is able to detect the dew point with the proper accuracy.

  18. Natural sunlight bleaching of the aluminum center in quartz

    International Nuclear Information System (INIS)

    Lin Min; Yin Gongming; Han Kongyan; Bao Jifei; Liu Jingwei; Jia Li

    2007-01-01

    The effect of sunlight bleaching on ESR signals from the aluminum center in quartz is reported for two samples of sand-sized quartz, one from a granite and one from a beach sand. The grains were exposed to direct sunlight for periods of time up to 500 h, with bleaching carried out in four different cities in China that are from 50 to 3600 m above sea level. Each sample bleached to the same residual level, ∼55% for the granite and 80% for the beach sand of the initial value after a 200 Gy dose had been given. After 200 h, the bleaching level reached was independent of the height above sea level

  19. Establishment of gold-quartz standard GQS-1

    Science.gov (United States)

    Millard, Hugh T.; Marinenko, John; McLane, John E.

    1969-01-01

    A homogeneous gold-quartz standard, GQS-1, was prepared from a heterogeneous gold-bearing quartz by chemical treatment. The concentration of gold in GQS-1 was determined by both instrumental neutron activation analysis and radioisotope dilution analysis to be 2.61?0.10 parts per million. Analysis of 10 samples of the standard by both instrumental neutron activation analysis and radioisotope dilution analysis failed to reveal heterogeneity within the standard. The precision of the analytical methods, expressed as standard error, was approximately 0.1 part per million. The analytical data were also used to estimate the average size of gold particles. The chemical treatment apparently reduced the average diameter of the gold particles by at least an order of magnitude and increased the concentration of gold grains by a factor of at least 4,000.

  20. Thermal annealing studies in muscovite and in quartz

    International Nuclear Information System (INIS)

    Roberts, J.H.; Gold, R.; Ruddy, F.H.

    1979-06-01

    In order to use Solid State Track Recorders (SSTR) in environments at elevated temperatures, it is necessary to know the thermal annealing characteristics of various types of SSTR. For applications in the nuclear energy program, the principal interest is focused upon the annealing of fission tracks in muscovite mica and in quartz. Data showing correlations between changes in track diameters and track densities as a function of annealing time and temperature will be presented for Amersil quartz glass. Similar data showing changes in track lengths and in track densities will be presented for mica. Time-temperature regions will be defined where muscovite mica can be accurately applied with negligible correction for thermal annealing

  1. Assessing rare earth elements in quartz rich geological samples

    International Nuclear Information System (INIS)

    Santoro, A.; Thoss, V.; Ribeiro Guevara, S.; Urgast, D.; Raab, A.; Mastrolitti, S.; Feldmann, J.

    2016-01-01

    Sodium peroxide (Na_2O_2) fusion coupled to Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS) measurements was used to rapidly screen quartz-rich geological samples for rare earth element (REE) content. The method accuracy was checked with a geological reference material and Instrumental Neutron Activation Analysis (INAA) measurements. The used mass-mode combinations presented accurate results (only exception being "1"5"7Gd in He gas mode) with recovery of the geological reference material QLO-1 between 80% and 98% (lower values for Lu, Nd and Sm) and in general comparable to INAA measurements. Low limits of detection for all elements were achieved, generally below 10 pg g"−"1, as well as measurement repeatability below 15%. Overall, the Na_2O_2/ICP-MS/MS method proved to be a suitable lab-based method to quickly and accurately screen rock samples originating from quartz-rich geological areas for rare earth element content; particularly useful if checking commercial viability. - Highlights: • Na_2O_2 fusion coupled to ICP-MS/MS was used to determine REE in quartz-rich samples. • The method accuracy was checked with a geological reference material and INAA. • Results were within 80–98% recovery of QLO-1 reference material, comparable to INAA. • Detection limits were generally below 10 pg g"−"1, and repeatability was below 15%. • Na_2O_2/ICP-MS/MS proved to be a suitable method for REE in quartz-rich samples.

  2. Recent Advances in Quartz Crystal Microbalance-Based Sensors

    Directory of Open Access Journals (Sweden)

    Sandeep Kumar Vashist

    2011-01-01

    Full Text Available Quartz crystal microbalance (QCM has gained exceptional importance in the fields of (biosensors, material science, environmental monitoring, and electrochemistry based on the phenomenal development in QCM-based sensing during the last two decades. This review provides an overview of recent advances made in QCM-based sensors, which have been widely employed in a plethora of applications for the detection of chemicals, biomolecules and microorganisms.

  3. A vibrating quartz fork - a tool for cryogenic helium research

    Czech Academy of Sciences Publication Activity Database

    Blažková, Michaela; Člověčko, M.; Eltsov, V. B.; Gažo, E.; de Graaf, R.; Hosio, J.J.; Krusius, M.; Schmoranzer, D.; Schoepe, W.; Skrbek, Ladislav; Skyba, P.; Solntsev, R.E.; Vinen, W. F.

    2008-01-01

    Roč. 150, - (2008), s. 525-535 ISSN 0022-2291 R&D Projects: GA ČR GA202/05/0218 Grant - others:GAUK(CZ) 7953/2007; Transnational Access Programme(XE) RITA -CT-2003-505313 Institutional research plan: CEZ:AV0Z10100520 Keywords : normal 3He * superfluid 3He * superfluid 4He * turbulence, * cavitation * quartz tuning fork Subject RIV: BK - Fluid Dynamics Impact factor: 1.034, year: 2008

  4. Melting and Pressure-Induced Amorphization of Quartz

    OpenAIRE

    Badro, James; Gillet, Philippe; Barrat, Jean-Louis

    1997-01-01

    It has recently been shown that amorphization and melting of ice were intimately linked. In this letter, we infer from molecular dynamics simulations on the SiO2 system that the extension of the quartz melting line in the metastable pressure-temperature domain is the pressure-induced amorphization line. It seems therefore likely that melting is the physical phenomenon responsible for pressure induced amorphization. Moreover, we show that the structure of a "pressure glass" is similar to that ...

  5. Tl response of KMgF{sub 3}: Lu + PTFE at ultraviolet radiation; Respuesta Tl de KMgF{sub 3}: Lu + PTFE a radiacion ultravioleta

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, P R [Instituto Nacional de Investigaciones Nucleares, A.P. 18 -1027, 11801 Mexico D.F. (Mexico); Alarcon, N G [Facultad de Quimica, Universidad Autonoma del Estado de Mexico. Paseo Tollocan, Esq. con Jesus Carranza, 50180 Toluca, Estado de Mexico (Mexico); Furetta, C; Azorin, J [Universidad Autonoma Metropolitana- Iztapalapa, San Rafael Atlixco 186, 09340 Mexico. D.F. (Mexico)

    2003-07-01

    Ionizing radiation has different types of interaction with a crystalline solid. However, only few effects are interesting to optimize some thermoluminescent (Tl) properties of certain Tl materials. This paper presents results obtained by irradiating KMgF{sub 3}: Lu + Ptfe Tl dosimeters with ultraviolet (UV) radiation previously exposed to gamma radiation. These results showed that those dosimeters not exposed previously to gamma radiation did not presented any Tl signal. Meanwhile, those previously submitted to gamma irradiation showed that their sensitivity was increased as the gamma dose increased. The glow curve of sensitized KMgF{sub 3}: Lu + Ptfe exposed to UV radiation, presented the dosimetric pea at 212 C. This makes this material to be promissory for measuring UV radiation. (Author)

  6. Study of /sup 201/Tl uptake by bone and bone marrow on /sup 201/Tl scintigraphy. With special reference to bone marrow abnormalities

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, Tadashige; Tanaka, Masao; Hirose, Yoshiki; Hirayama, Jiro; Handa, Kenjiro; Nakanishi, Fumiko; Yano, Kesato; Ueda, Hitoshi

    1989-04-01

    Thallium-201 (Tl-201) uptake in the bone and bone marrow was examined in a total of 93 patients with various diseases. Sternal uptake of Tl-201 was observed when patients had bone marrow abnormality especially associated with hematopoietic disease. It was associated with proliferation of immature cells and of various types of bone marrow cells, especially erythroblastic and plasma cells. Whole-body Tl-201 scanning showed a high uptake (82%) in the sternum, chest, lumbar vertebrae, and pelvis. Thallium-201 was definitively taken up by the sternum in polycythemia (5/41), hemolytic anemia (2/2), iron deficiency anemia (2/2), and multiple myeloma (2/5). For leukemia, Tl-201 uptake was slight or negative. Thallium-201 scanning proved useful in visualizing bone marrow abnormality, although careful interpretation of bone and bone marrow uptake is required. (Namekawa, K).

  7. Characterization of hydrothermal green quartz produced by gamma radiation

    Energy Technology Data Exchange (ETDEWEB)

    Enokihara, Cyro T.; Rela, Paulo R., E-mail: cteiti@ipen.br, E-mail: prela06@yahoo.com.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Schultz-Güttler, Rainer A., E-mail: rainersgut@gmail.com [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto de Geociencias

    2015-07-01

    A specific variety of quartz showing a green color in nature or induced artificially by radiation gamma ({sup 60}Co) is quite rare. Only two occurrences are known today, where this type of quartz can be found: Canada, at the Thunder Bay Amethyst Mine, Ontario and Brazil, at widely scattered geode occurrences along a 600 km stretch from Quarai at Brazils southern most tip to Uberlandia in Minas Gerais. These two occurrences have been formed by strong hydrothermal activities.That way much quartz crystals showed a very fast growth history facilitating the formation of growth defects (twinning, small angle tilting, mosaic growth, striations) and the uptake of water in form of micro inclusions, molecular water, silanol (Si-OH) and OH. In the present work the material analyzed is from hydrothermal regimes found in intrusions of basaltic rocks located in the Rio Grande do Sul state. To characterize these materials, colored green by gamma rays, analyses by ICP, electron microscopy, water loss techniques and UV-VIS or NIR-FTIR spectroscopic measurements have been made. Silanol complexes are formed, which by radiation due to gamma rays form the color center NBOHC (Non-bonding Oxygen Hole Center), showing absorption between 590 to 620 nm, responsible for the green color. The water content with up to 3200 ppm by weight exceeds the amount of charge balancing cations (Fe, Al, Li). There is no correlation between water content and cations as in other color varieties. (author)

  8. Post mortem analysis of a JET quartz microbalance system

    Energy Technology Data Exchange (ETDEWEB)

    Esser, H.G. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany)]. E-mail: h.g.esser@fz-juelich.de; Philipps, V. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany); Wienhold, P. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany); Sugiyama, K. [Department of Nuclear Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Kreter, A. [Association EURATOM-Forschungszentrum Juelich, IPP, D-52425, Juelich (Germany); Coad, J.P. [UKAEA/EURATOM Fusion Association, Culham Science Centre, Abingdon (United Kingdom); Tanabe, T. [Department of Nuclear Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

    2007-06-15

    In the year 2001, a quartz microbalance system (QMB) was installed in the remote area of the inner JET divertor to investigate in situ material erosion and redeposition processes. When removed in 2004, the system was found to be coated all over with carbon deposits. The deposit on the quartz oscillator and the outer and inner housing was analysed by various methods, as SIMS (secondary ion mass spectroscopy), stylus depth profilometry, EPMA (electron probe microanalysis), TIPT (Tritium imaging plate technique) and colorimetry and compared to the frequency change of the quartz. The layer thickness was determined to 1.85 {+-} 0.1 {mu}m in average on an area of 0.95 cm{sup 2} which has to be related to the equivalent of 1.77 x 10{sup -4} g measured from the frequency change of 23 640 Hz. This corresponds to a carbon areal density of 9.3 x 10{sup 18} C atoms/cm{sup 2}. Significant deposition was found also on the surfaces inside the QMB housing which can only be understood if reflection and low sticking is assumed for a high fraction of particles.

  9. Pressure solution of minerals in quartz-type buffer materials

    International Nuclear Information System (INIS)

    Erlstroem, M.

    1986-12-01

    Two samples, pure quartz sand and a sand-bentonite (10%) mixture, were tested under conditions of high pressure (200 bar) and temperature (115 0 C). The experiment was carried out over a period of 70 days. A series of thin slides were prepared on a resin embedded sample at the end of the test period. A microscopical study was performed as to obtain data concerning the effects of pressure and temperature. It showed that no pressure solution had taken place in the pure quartz sand. However, the individual grains had been severely fractured, thus causing significant internal sedimentation. The mixed sample showed that the clay component coated the quartz grains and significantly decreased the effect of stress in the grains by having a cushioning effect. Relative grain movement was facilitated by the clay, by which the grains rotated and slipped into stable positions with large contact areas and low contact stresses. This probably minimized pressure solution. However, a few contact regions indicated the presence of precipitated silica. The investigation shows no definite evidence of pressure solution after an experiment duration of 70 days. Since the effect of solution may be time dependent at the applied temperature, it is recommended that further experiments be conducted at higher effective and porewater pressures but still at 115 0 C. (orig.)

  10. Experiment study of a quartz tube falling particle receiver

    Institute of Scientific and Technical Information of China (English)

    Tianjian WANG; Fengwu BAI; Shunzhou CHU; Xiliang ZHANG; Zhifeng WANG

    2017-01-01

    This paper presents an experimental evaluation of a specially designed falling particle receiver.A quartz tube was used in the design,with which the particles would not be blown away by wind.Concentrated solar radiation was absorbed and converted into thermal energy by the solid particles flowed inside the quartz tube.Several experiments were conducted to test the dynamic thermal performance of the receiver on solar furnace system.During the experiments,the maximum particle temperature rise is 212℃,with an efficiency of 61.2%,which shows a good thermal performance with a falling distance of 0.2 m in a small scale particle receiver.The average outlet particle temperature is affected by direct normal irradiance (DNI) and other factors such as wind speed.The solid particles obtain a larger viscosity with a higher temperature while smaller solid particles are easier to get stuck in the helix quartz tube.The heat capacity of the silicon carbide gets larger with the rise of particle temperature,because as the temperature of solid particles increases,the temperature rise of the silicon carbide decreases.

  11. Investigations on low temperature thermoluminescence centres in quartz

    International Nuclear Information System (INIS)

    Bernhardt, H.

    1984-01-01

    The present paper will help to understand the often investigated process of thermoluminescence of quartz which is of high complexity. A lot of traps exist in quartz crystals which compete with each other with respect to the trapping of charge carriers during the X-ray treatment. That is why a variety of processes takes place after X-irradiation at liquid nitrogen temperature (LNT) of quartz which complicate the phenomenology of low temperature thermoluminescence. This competition in the trapping process leads to the so-called 'sensibilization' or 'desensibilization' effects of thermoluminescence, respectively, which are described in this paper for the first time. This effect means the dependence of the LNT thermoluminescence intensity on a pre-irradiation dose applied at room temperature (RT). The influence of this pre-irradiation is understood assuming the saturation of competitive traps. This favours an enhanced trapping of charge carriers at LNT-(shallow) traps instead of the preferential trapping on the deep traps in the case of X-ray treatment of the as-grown crystal at LNT. To get the afore mentioned model we take into account not only thermoluminescence but also coloration, ir- and vuv-absorption measurements. (author)

  12. Usability of VTL from natural quartz grains for retrospective dosimetry

    International Nuclear Information System (INIS)

    Fujita, H.; Hashimoto, T.

    2007-01-01

    To develop retrospective dosimetry of unexpected radiation accident, basic studies on violet thermoluminescence (VTL) phenomena were conducted using natural quartz grains. All VTL glow curves of as-received samples did not exhibit peaks <250 deg. C, although for artificially irradiated quartz samples there were VTL peaks in the temperature region <250 deg. C. Therefore, accident doses could be estimated without the interference of naturally accumulated doses by VTL measurements from natural quartz. The mean lives of VTL were evaluated by the various heating rates method and the range of values was found to be between some days and ten thousands of years depending on each peak. Especially, the mean life of VTL peak at 200 deg. C was years order. Furthermore, the lower detection limit was calculated to be tens of mGy from the response curve. This value was lower than that of other methods such as ESR dosimetry. From these results, we conclude that VTL dosimetry can be preferred for accidental evaluation. (authors)

  13. Analysis of optical bleaching of OSL signal in sediment quartz

    International Nuclear Information System (INIS)

    Przegiętka, K.R.; Chruścińska, A.

    2013-01-01

    The aim of this work was to study the effect of the quality of optical bleaching on the results of OSL (Optically Stimulated Luminescence) dating method. The large aliquots of coarse quartz grains extracted from fluvial deposit were used in the study. The poor, medium and good bleaching were simulated in laboratory with help of Blue LED light source in series of experiments. Then the samples were irradiated with a common laboratory dose. The equivalent doses (DE) were measured by the help of standard Single Aliquot Regeneration (SAR) technique, but obtained DE distributions are analyzed in a new way. The method for recognizing and compensating for partial bleaching is proposed. The conclusions for dating sediment quartz samples are presented and discussed. -- Highlights: ► Bleaching experiments on sediment quartz are performed. ► Blue LED light source incorporated in luminescence reader is used. ► New analysis of data measured by standard SAR OSL technique is proposed. ► The results are promising for recognizing and compensating for partial bleaching

  14. Apatite-brannerite-pitchblende association in hydrothermal quartz veins

    International Nuclear Information System (INIS)

    Brodin, B.V.; Mel'nikova, A.M.; Osipov, B.S.; Pavlov, E.G.

    1976-01-01

    A study into the vein quartz mineralization confined to the tectonic zones of crush and silicification in sedimentary-igneous rocks of the lower Paleozoic has been made. The physicochemical characteristics of minerals were studied by way of optical and electron microscopy, chemical, laser-microspectral and X-ray structural analyses, microprobing and alpha-microradiography. 3 mineral associations have been discriminated, representative of the sequence of hydrothermal mineralization. An unusual parogenesis of pitchblende and brannerite with apatite, xenotime and more recent goethite has been revealed. The results are indicative of a medium-low-temperature hydrothermal process occurring at the final stages of formation of uraniferrous quartz veins. By composition and mineralization sequence, the latters are close to low- and medium-temperature uranium-quartz-chlorite-hydromica formations with apatite, coffinite, brannerite and pitchblende. The weak initial metamictization of goethite in veins 80 to 100 million years old is due to the radioactive effect of the submicroscopic radioactive mineral impurity on the crystalline lattice

  15. Investigation of the gamma radiation from the inelastic scattering of 2.75 MeV on 203Tl and 205Tl

    International Nuclear Information System (INIS)

    Hegewisch, S.

    1976-01-01

    The experimental presupositions for the measurements of (n,n'γ) reactions with time of flight discrimination have been established. By an investigation of the isotopes 203 Tl and 205 Tl with this method 120 gamma-transitions could be determined. The exact evaluation of their energies and intensities led to a completion of the level diagrams. The enrgies could be determined with a precision nearly one order of magnitude higher than the values existing hither to. (orig./WL) [de

  16. The superconductor (Tl,Hg,Ca)2(Ba,Sr)2(Ca,Sr,Tl)Cu2O7.6

    International Nuclear Information System (INIS)

    Valldor, M.; Bryntse, I.; Morawski, A.

    2002-01-01

    In the title 2212-type superconductor (thallium mercury calcium barium strontium copper oxide), which contains both Tl and Hg in the charge reservoir (CR), Sr is located at both alkali-earth (AE) metal sites. Ca enters the CR at the same time as Tl shares the smaller AE site, which increases the apical Cu-Cu distance significantly. The structure causes the superconducting Cu-O layers to become significantly puckered. (orig.)

  17. Antiferromagnetism Induced in the Vortex Core of Tl2Ba2CuO6++δ Probed by Spatially-Resolved 205Tl-NMR

    International Nuclear Information System (INIS)

    Kumagai, K.; Kakuyanagi, K.; Matsuda, Y.; Hasegawa, T.

    2003-01-01

    Magnetism in the vortex core state has been studied by spatially-resolved NMR. The nuclear spin lattice relaxation rate T 1 -1 of 205 Tl in nearly optimal-doped Tl 2 Ba 2 CuO 6+ δ (T c =85 K) is significantly enhanced in the vortex core region. The NMR results suggest that the suppression of the d-wave superconducting order parameter in the vortex core leads to the nucleation of islands with local antiferromagnetic (AF) order. (author)

  18. 201Tl in myocardial diagnosis: studies on the influence of dipyridamole, dobutamine ergometer exercise and background subtraction on the 201Tl myocadial scintiscam

    International Nuclear Information System (INIS)

    Seiderer, M.

    1979-01-01

    Changes in 201 Tl myocardial scintiscans upon administration of dipyridamole or dobutamine and upon ergometer exercise relative to scintiscans at rest were investigated as well as the influence of myocardial background subtraction on scintiscan quality and information. A total of 90 201 Tl examinations were carried out in 59 patients. 18 patients had no myocardial disease, 30 patients had a coronary disease, 5 patients suffered from cardiomyopathy and 6 from left ventricular hypertrophy. The findings are discussed in detail. (orig.) [de

  19. Study of multi-quasiparticle band structures in 197Tl using α beam

    International Nuclear Information System (INIS)

    Mukherjee, G.; Nandi, S.; Pai, H.

    2016-01-01

    Study of the multi-quasiparticle (qp) states and the band structures built on them in the neutron deficient Tl nuclei in A ∼ 190 mass region provides useful information on particle-hole interaction in the heavy nuclei. In order to investigate the multi-qp band structures we have studied the excited states in 197 Tl by gamma ray spectroscopy

  20. On the Constitution of SoTL: Its Domains and Contexts

    Science.gov (United States)

    Booth, S.; Woollacott, L. C.

    2018-01-01

    In this paper, we present an analysis of the Scholarship of Teaching and Learning in Higher Education (SoTL) which contributes to SoTL both as a field of research practice and as a background to professional development in higher education. We analyse and describe the constitution of the field, and in so doing address its nature in the face of the…

  1. Enhanced thermoelectric figure of merit in strained Tl-doped Bi2Se3

    KAUST Repository

    Saeed, Y.; Singh, Nirpendra; Schwingenschlö gl, Udo

    2014-01-01

    We explain recent experimental findings on Tl-doped Bi2Se3 by determining the electronic and transport properties by first-principles calculations and semi-classical Boltzmann theory. Though Tl-doping introduces a momentum-dependent spin

  2. Preparation of 199Tl using the electroplating gold targets on the internal target installation of cyclotron

    International Nuclear Information System (INIS)

    Zhou Dehai; Xie Degao; Chao Yangshu; Liao Fuquan; Zhang Youfa; Wang Zefu

    1992-01-01

    The separative conditions of 199 Tl from Cu, Au and Ga by reaction 197 Au(α, 2n) 199 Tl on the internal target installation of cyclotron is studied. The α-particle energy is selected in the range of 24-15 MeV. The cumulative current intensities of such α-particle beams bombarding the gold target at 150-200 μA are 1200 μA · h and 1500 μA · h respectively. The radiochemical separation of 199 Tl is carried out with isopropyl ether extraction and anions exchange from the irradiated gold targets. The radioactivities of 199 Tl and 200 Tl are 2.3 x 10 5 Bq and 7.1 x 10 2 Bq, and 200 Tl makes up 0.29% of the total radioactivity. The impurity elements contained 1 ml of 199 TlCl injection solution are Au 199 TlCl has been used in clinical experiments in vivo and relatively good results have been obtained

  3. Identification of food preserved by ionizing radiation; Preliminary tests in strawberries using thermoluminescent (TL)

    International Nuclear Information System (INIS)

    Rubio, T.; Sillano, O.; Espinoza, J.; Roman, A.; Deza, A.

    1992-01-01

    TL measurements, of irradiated and unirradiated strawberries were carried out, using peel, seeds (achenes), leaves and sediment. The four types of samples presented a different thermoluminescence response. The best results were obtained with sediment removed from the soil of the fruit surface. It is concluded that TL is a promising technique for detecting irradiated strawberries using sediment samples. (author)

  4. Value of dipyridamole stress 201Tl myocardial SPECT in detecting dysfunction of coronary microcirculation

    International Nuclear Information System (INIS)

    Lou Ying; Jiang Jinqi; Xie Wenhui; Yuan Fang; Wang Tong; Yang Yiqing

    2012-01-01

    Objective: To evaluate the value of dipyridamole stress 201 Tl myocardial SPECT in detecting dysfunction of coronary microcirculation. Methods: Forty-eight patients diagnosed with cardiac syndrome X underwent dipyridamole stress 201 Tl myocardial SPECT. Dipyridamole (0.56 mg/kg) was intravenously injected over 4 min followed by 201 Tl (111 MBq) injection at 2 min after dipyridamole administration. Image was acquired at 10 min and 240 min post-injection and co-analyzed by over two experienced doctors in nuclear medicine after three-dimensional reconstruction. The patients with 'reverse redistribution' underwent repeated dipyridamole stress 201 Tl SPECT after medical therapy for 2 weeks. The clinical symptoms and results of the treadmill exercise test pre-and post-therapy were compared. Results: Forty two patients (42/48, 87.50%) showed segmental defects: 'reverse redistribution' on delayed (240 min) 201 Tl images. After medical treatment, 36 cases of the 42 'reverse redistribution' patients had improvement in both clinical symptoms and treadmill exercise test. Post-treatment 201 Tl imaging showed improvement in 45/49 (91.84%) defect segments. Six of the 42 patients had no improvement in clinical symptoms and/or treadmill exercise test. Post-treatment 201 Tl imaging showed no improvement in all the 7 defect segments on the first scan. Conclusion: Dipyridamole stress 201 Tl myocardial SPECT may be valuable in evaluation of impaired coronary microcirculation associated with cardiac syndrome X. (authors)

  5. Observation of curious spiral growth features in Tl doped Hg bearing ...

    Indian Academy of Sciences (India)

    Synthesis of H(Tl)Ba2Ca2Cu3O8+ superconducting tapes have been accomplished by annealing the precursor tape, Ba2Ca2Cu3O (fabricated by doctor blade tape casting technique) in an environment of H(Tl) vapour. Characterization of superconducting HTSC tape sample was carried out through XRD, TEM, SEM ...

  6. Pulse shaping for fast coincidence with NaI(Tl) detectors

    International Nuclear Information System (INIS)

    Bose, S.; Sinha, B.K.; Bhattacharya, R.

    1983-01-01

    The effect of multiple limiting of the anode pulses of the photomultiplier tubes on the resolving time of an NaI(Tl)-NaI(Tl) fast coincidence set up is investigated with the help of a simple transistored limiter circuit. The performance of the set up for different energy ranges selected in the side channels is also investigated. (orig.)

  7. TL and ESR based identification of gamma-irradiated frozen fish using different hydrolysis techniques

    International Nuclear Information System (INIS)

    Ahn, Jae-Jun; Akram, Kashif; Shahbaz, Hafiz Muhammad; Kwon, Joong-Ho

    2014-01-01

    Frozen fish fillets (walleye Pollack and Japanese Spanish mackerel) were selected as samples for irradiation (0–10 kGy) detection trials using different hydrolysis methods. Photostimulated luminescence (PSL)-based screening analysis for gamma-irradiated frozen fillets showed low sensitivity due to limited silicate mineral contents on the samples. Same limitations were found in the thermoluminescence (TL) analysis on mineral samples isolated by density separation method. However, acid (HCl) and alkali (KOH) hydrolysis methods were effective in getting enough minerals to carry out TL analysis, which was reconfirmed through the normalization step by calculating the TL ratios (TL 1 /TL 2 ). For improved electron spin resonance (ESR) analysis, alkali and enzyme (alcalase) hydrolysis methods were compared in separating minute-bone fractions. The enzymatic method provided more clear radiation-specific hydroxyapatite radicals than that of the alkaline method. Different hydrolysis methods could extend the application of TL and ESR techniques in identifying the irradiation history of frozen fish fillets. - Highlights: • Irradiation has potential to improve hygienic quality of raw and processed seafood. • Detection of irradiated food is important to enforce the applied regulations. • Different techniques were compared to separate silicate minerals from frozen fish. • Limitations were observed in TL analysis on minerals isolated by density separation. • Hydrolysis methods provided more clear identification using TL and ESR techniques

  8. Hexamethyldisiloxane thin films as sensitive coating for quartz crystal microbalance based volatile organic compounds sensors

    International Nuclear Information System (INIS)

    Boutamine, M.; Bellel, A.; Sahli, S.; Segui, Y.; Raynaud, P.

    2014-01-01

    Hexamethyldisiloxane (HMDSO) thin films coated quartz crystal microbalance (QCM) electrodes have been characterized for the detection of volatile organic compounds (VOCs). The sensitive coatings were plasma polymerized in pure vapor of HMDSO and HMDSO/O 2 mixture. The sensor sensitivity was evaluated by monitoring the frequency shift (∆f) of the coated QCM electrode exposed to different concentrations of VOC vapors, such as ethanol, methanol, benzene and chloroform. The isotherm response characteristics showed good reproducibility and reversibility. For all types of analyte, ∆f were found to be linearly correlated with the concentration of VOC vapor. It was shown that it is possible to tune the chemical affinity of the sensor by changing the oxygen ratio in the deposition gas mixture. Contact angle measurements (CA), attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, atomic force microscopy (AFM) and scanning electron microscopy (SEM) were used to study surface wettability, chemical composition and surface morphology of the coated QCM electrodes. ATR-FTIR analysis showed the presence of methyl groups around 840 cm −1 due to Si-(CH 3 ) 3 rocking vibration making the elaborated sensor surface hydrophobic. When the coating is performed in HMDSO/O 2 mixture, AFM and SEM images showed an increase in the effective specific surface area of the sensor due to the increase in surface roughness. Surface morphology combined with chemical composition significantly affects the sensitivity of the QCM-based sensor. - Highlights: • Hexamethyldisiloxane layers were evaluated for volatile organic compounds detection. • The kinetic response of the sensor showed good reproducibility and reversibility. • Hydrophobic coating and high specific surface area increase the sensor sensitivity. • Sensor affinity can be controlled by controlling oxygen proportion in the mixture

  9. Dating quartz: Ar/Ar analyses of coexisting muscovite and fluid inclusion - rich quartz from paleocene amorphic aureole

    International Nuclear Information System (INIS)

    Matthews, S.J.; Perez de Arce, C.; Cornejo, P.; Cuitino, L; Klein, J

    2001-01-01

    We present Ar/Ar total fusion and step-heating data for coexisting muscovite and white quartz from the metamorphic aureole of the Lower Paleocene La Copiapina Pluton, 6 km south of Inca de Oro, III Region, Chile. The pluton intrudes the upper clastic sedimentary member of the Punta del Cobre Group (Upper Jurassic - Lower Cretaceous) and the calcareous sedimentary rocks of the Chanarcillo Group (Neocomian), and comprises fine to coarse grained pyroxene-hornblende-biotite quartz diorites and monzodiorites. Its emplacement was controlled on its north-western side by a subvertical NE-trending fault, along which were developed vertically banded skarns (skarn mylonite), suggesting syntectonic intrusion. Biotite K-Ar ages for the pluton fall in the range 61-63 Ma, relating it to a latest Cretaceous to Lowest Paleocene syn-compressional intrusive belt which is present in the area (Matthews and Cornejo, 2000). A metamorphic / metasomatic aureole is developed within the sandstones of the Punta del Cobre Group, on the extreme northern limit of the pluton. In this area, the sedimentary rocks have been replaced by quartz-sericite and quartz-muscovite assemblages, with minor hematite and tourmaline, and late supergene kaolinite and pyrophyllite. A coarse muscovite-quartz-tourmaline-hematite assemblage is developed in and around older (early Upper Cretaceous) andesitic dykes, in the form of replacement / fracture fill veins and replacement zones. Further from the contact with the pluton, fine-grained quartz-sericite rock with coarser muscovite-rich replacement veins represents the dominant lithology. Quartz in the coarse replacement rock is very rich in fluid inclusions. Primary inclusions are mainly of two coexisting types; bi-phase (liquid and gas bubble) and tri-phase (liquid, gas bubble and halite crystal), indicating that the quartz formed in the presence of a boiling fluid. Some inclusions also contain sylvite and occasional hematite daughter crystals. Secondary inclusions

  10. Isothermal, kinetic and thermodynamic studies on basic dye sorption ...

    African Journals Online (AJOL)

    Isothermal, kinetic and thermodynamic studies on basic dye sorption onto tartaric acid esterified wheat straw. ... African Journal of Biotechnology ... esterified wheat straw (EWS), was originally prepared by solid phase thermochemistry method.

  11. Isothermal, kinetic and thermodynamic studies on basic dye sorption ...

    African Journals Online (AJOL)

    PRECIOUS

    2009-12-15

    Dec 15, 2009 ... The isothermal data correlated with the Langmuir model better than the. Freundlich model. ... there were two intra-particle diffusion steps in the dye sorption processes. .... rated monolayer of sorbate molecule on the sorbent.

  12. Improved Isotherm Data for Adsorption of Methane on Activated Carbons

    KAUST Repository

    Loh, Wai Soong

    2010-08-12

    This article presents the adsorption isotherms of methane onto two different types of activated carbons, namely, Maxsorb III and ACF (A-20) at temperatures from (5 to 75) °C and pressures up to 2.5 MPa. The volumetric technique has been employed to measure the adsorption isotherms. The experimental results presented herein demonstrate the improved accuracy of the uptake values compared with previous measurement techniques for similar adsorbate-adsorbent combinations. The results are analyzed with various adsorption isotherm models. The heat of adsorption, which is concentration and temperature dependent, has been calculated from the measured isotherm data. Henry\\'s law coefficients for these adsorbent-methane pairs are also evaluated at various temperatures. © 2010 American Chemical Society.

  13. Universality of isothermal fluid spheres in Lovelock gravity

    Science.gov (United States)

    Dadhich, Naresh; Hansraj, Sudan; Maharaj, Sunil D.

    2016-02-01

    We show universality of isothermal fluid spheres in pure Lovelock gravity where the equation of motion has only one N th order term coming from the corresponding Lovelock polynomial action of degree N . Isothermality is characterized by the equation of state, p =α ρ and the property, ρ ˜1 /r2 N . Then the solution describing isothermal spheres, which exist only for the pure Lovelock equation, is of the same form for the general Lovelock degree N in all dimensions d ≥2 N +2 . We further prove that the necessary and sufficient condition for the isothermal sphere is that its metric is conformal to the massless global monopole or the solid angle deficit metric, and this feature is also universal.

  14. Creep of quartz by dislocation and grain boundary processes

    Science.gov (United States)

    Fukuda, J. I.; Holyoke, C. W., III; Kronenberg, A. K.

    2015-12-01

    Wet polycrystalline quartz aggregates deformed at temperatures T of 600°-900°C and strain rates of 10-4-10-6 s-1 at a confining pressure Pc of 1.5 GPa exhibit plasticity at low T, governed by dislocation glide and limited recovery, and grain size-sensitive creep at high T, governed by diffusion and sliding at grain boundaries. Quartz aggregates were HIP-synthesized, subjecting natural milky quartz powder to T=900°C and Pc=1.5 GPa, and grain sizes (2 to 25 mm) were varied by annealing at these conditions for up to 10 days. Infrared absorption spectra exhibit a broad OH band at 3400 cm-1 due to molecular water inclusions with a calculated OH content (~4000 ppm, H/106Si) that is unchanged by deformation. Rate-stepping experiments reveal different stress-strain rate functions at different temperatures and grain sizes, which correspond to differing stress-temperature sensitivities. At 600-700°C and grain sizes of 5-10 mm, flow law parameters compare favorably with those for basal plasticity and dislocation creep of wet quartzites (effective stress exponents n of 3 to 6 and activation enthalpy H* ~150 kJ/mol). Deformed samples show undulatory extinction, limited recrystallization, and c-axis maxima parallel to the shortening direction. Similarly fine-grained samples deformed at 800°-900°C exhibit flow parameters n=1.3-2.0 and H*=135-200 kJ/mol corresponding to grain size-sensitive Newtonian creep. Deformed samples show some undulatory extinction and grain sizes change by recrystallization; however, grain boundary deformation processes are indicated by the low value of n. Our experimental results for grain size-sensitive creep can be compared with models of grain boundary diffusion and grain boundary sliding using measured rates of silicon grain boundary diffusion. While many quartz mylonites show microstructural and textural evidence for dislocation creep, results for grain size-sensitive creep may apply to very fine-grained (<10 mm) quartz mylonites.

  15. Amplifier Module for 260-GHz Band Using Quartz Waveguide Transitions

    Science.gov (United States)

    Padmanabhan, Sharmila; Fung, King Man; Kangaslahti, Pekka P.; Peralta, Alejandro; Soria, Mary M.; Pukala, David M.; Sin, Seth; Samoska, Lorene A.; Sarkozy, Stephen; Lai, Richard

    2012-01-01

    Packaging of MMIC LNA (monolithic microwave integrated circuit low-noise amplifier) chips at frequencies over 200 GHz has always been problematic due to the high loss in the transition between the MMIC chip and the waveguide medium in which the chip will typically be used. In addition, above 200 GHz, wire-bond inductance between the LNA and the waveguide can severely limit the RF matching and bandwidth of the final waveguide amplifier module. This work resulted in the development of a low-loss quartz waveguide transition that includes a capacitive transmission line between the MMIC and the waveguide probe element. This capacitive transmission line tunes out the wirebond inductance (where the wire-bond is required to bond between the MMIC and the probe element). This inductance can severely limit the RF matching and bandwidth of the final waveguide amplifier module. The amplifier module consists of a quartz E-plane waveguide probe transition, a short capacitive tuning element, a short wire-bond to the MMIC, and the MMIC LNA. The output structure is similar, with a short wire-bond at the output of the MMIC, a quartz E-plane waveguide probe transition, and the output waveguide. The quartz probe element is made of 3-mil quartz, which is the thinnest commercially available material. The waveguide band used is WR4, from 170 to 260 GHz. This new transition and block design is an improvement over prior art because it provides for better RF matching, and will likely yield lower loss and better noise figure. The development of high-performance, low-noise amplifiers in the 180-to- 700-GHz range has applications for future earth science and planetary instruments with low power and volume, and astrophysics array instruments for molecular spectroscopy. This frequency band, while suitable for homeland security and commercial applications (such as millimeter-wave imaging, hidden weapons detection, crowd scanning, airport security, and communications), also has applications to

  16. Experimental deformation in sandstone, carbonates and quartz aggregate

    Energy Technology Data Exchange (ETDEWEB)

    Cheung, Cecilia See Nga [Stony Brook Univ., NY (United States)

    2015-05-01

    The first part of my thesis is mainly focused on the effect of grain size distribution on compaction localization in porous sandstone. To identify the microstructural parameters that influence compaction band formation, I conducted a systematic study of mechanical deformation, failure mode and microstructural evolution in Bleurswiller and Boise sandstones, of similar porosity (~25%) and mineralogy but different sorting. Discrete compaction bands were observed to develop over a wide range of pressure in the Bleurswiller sandstone that has a relatively uniform grain size distribution. In contrast, compaction localization was not observed in the poorly sorted Boise sandstone. My results demonstrate that grain size distribution exerts important influence on compaction band development, in agreement with recently published data from Valley of Fire and Buckskin Gulch, as well as numerical studies. The second part aimed to improve current knowledge on inelastic behavior, failure mode and brittle-ductile transition in another sedimentary rock, porous carbonates. A micritic Tavel (porosity of ~13%) and an allochemical Indiana (~18%) limestones were deformed under compaction in wet and dry conditions. At lower confining pressures, shear localization occurred in brittle faulting regime. Through transitional regime, the deformation switched to cataclastic flow regime at higher confining pressure. Specifically in the cataclastic regime, the (dry and wet) Tavel and dry Indiana failed by distributed cataclastic flow, while in contrast, wet Indiana failed as compaction localization. My results demonstrate that different failure modes and mechanical behaviors under different deformation regimes and water saturation are fundamental prior to any geophysical application in porous carbonates. The third part aimed to focus on investigating compaction on quartz aggregate starting at low (MPa) using X-ray diffraction. We report the diffraction peak evolution of quartz with increasing

  17. Studies on the tumor and organ affinity of /sup 201/Tl

    Energy Technology Data Exchange (ETDEWEB)

    Mori, H; Ando, I; Takeuchi, T [Kanazawa Univ. (Japan). School of Medicine; Ando, A; Hiraki, T

    1980-01-01

    In order to evaluate the tumor and organ affinity of /sup 201/Tl, using the Yoshida sarcoma bearing rats, the distribution of /sup 201/Tl/sup +/ in tissues and tumor was examined and compared to /sup 22/Na/sup +/, /sup 42/K/sup +/, /sup 86/Rb/sup +/, /sup 134/Cs/sup +/, and /sup 67/Ga-citrate. /sup 201/Tl/sup +/ showed almost same organ accumulation and kinetics as /sup 42/K/sup +/, /sup 86/Rb/sup +/, /sup 134/Cs, whereas /sup 201/Tl/sup +/ and /sup 22/Na/sup +/ had completely different organ distribution. These results suggest that organ affinity of /sup 201/Tl/sup +/ might be related to active transport, namely Na/sup +/-K/sup +/-ATPase pump mechanism as well as blood flow. However, it appeared to be taken into account the other factors such as different accumulation and clearance rate due to different substrates of organs. Kidney accumulation rate of /sup 201/Tl/sup +/ was much higher than /sup 42/K/sup +/, /sup 86/Rb/sup +/, /sup 134/Cs/sup +/ and about 10 times as /sup 42/K/sup +/. Macroautoradiograms of rat kidneys showed that /sup 201/Tl/sup +/ exhibited an initial high accumulation in the cortex and appeared in the outer cortex, as the cortex cleared of radioactivity. /sup 201/Tl might be interchangeable with K/sup +/ in the tubular system, reabsorbed with more affinity and cleared more slowly than K/sup +/. The tumor accumulation /sup 201/Tl/sup +/ might be related to Na/sup +/-K/sup +/-ATPase pump mechanism as well as other organs. However, in terms of tumor accumulation and concentration ratio to other organs, /sup 201/Tl/sup +/ was inferior to /sup 67/Ga-citrate, although the tumor to blood ratio was identical to that of /sup 67/Ga-citrate. Since /sup 201/Tl/sup + + +/ showed almost same distribution as /sup 201/Tl/sup +/, /sup 201/Tl/sup + + +/ might change into /sup 201/Tl/sup +/ in vivo.

  18. Mineralogy, morphology, and textural relationships in coatings on quartz grains in sediments in a quartz-sand aquifer

    Science.gov (United States)

    Zhang, Shouliang; Kent, Douglas B.; Elbert, David C.; Shi, Zhi; Davis, James A.; Veblen, David R.

    2011-01-01

    Mineralogical studies of coatings on quartz grains and bulk sediments from an aquifer on Western Cape Cod, Massachusetts, USA were carried out using a variety of transmission electron microscopy (TEM) techniques. Previous studies demonstrated that coatings on quartz grains control the adsorption properties of these sediments. Samples for TEM characterization were made by a gentle mechanical grinding method and focused ion beam (FIB) milling. The former method can make abundant electron-transparent coating assemblages for comprehensive and quantitative X-ray analysis and the latter technique protects the coating texture from being destroyed. Characterization of the samples from both a pristine area and an area heavily impacted by wastewater discharge shows similar coating textures and chemical compositions. Major constituents of the coating include Al-substituted goethite and illite/chlorite clays. Goethite is aggregated into well-crystallized domains through oriented attachment resulting in increased porosity. Illite/chlorite clays with various chemical compositions were observed to be mixed with goethite aggregates and aligned sub-parallel to the associated quartz surface. The uniform spatial distribution of wastewater-derived phosphorus throughout the coating from the wastewater-contaminated site suggests that all of the coating constituents, including those adjacent to the quartz surface, are accessible to groundwater solutes. Both TEM characterization and chemical extraction results indicate there is a significantly greater amount of amorphous iron oxide in samples from wastewater discharge area compared to those from the pristine region, which might reflect the impact of redox cycling of iron under the wastewater-discharge area. Coating compositions are consistent with the moderate metal and oxy-metalloid adsorption capacities, low but significant cation exchange capacities, and control of iron(III) solubility by goethite observed in reactive transport

  19. Stability of Tl-Ba-Ca-Cu-O superconducting thin films

    International Nuclear Information System (INIS)

    Siegal, M. P.; Overmyer, D. L.; Venturini, E. L.; Padilla, R. R.; Provencio, P. N.

    1999-01-01

    We report the stability of TlBa 2 CaCu 2 O 7 and Tl 2 Ba 2 CaCu 2 O 8 on LaAlO 3 (100) epitaxial thin films, under a variety of conditions. All films are stable in acetone and methanol and with repeated thermal cycling to cryogenic temperatures. Moisture, especially vapor, degrades film quality rapidly. These materials are stable to high temperatures in either N 2 or O 2 ambients. While total degradation, resulting from Tl depletion, occurs at the same temperatures for both phases, 600 degree sign C in N 2 and 700 degree sign C in O 2 , the onset of degradation occurs at somewhat lower temperatures for TlBa 2 CaCu 2 O 7 than for Tl 2 Ba 2 CaCu 2 O 8 . (c) 1999 Materials Research Society

  20. Synthesis and properties of Tl endash Ba endash Ca endash Cu endash O superconductors

    International Nuclear Information System (INIS)

    Siegal, M.P.; Venturini, E.L.; Morosin, B.; Aselage, T.L.

    1997-01-01

    We review the synthesis methods and properties of single crystal, powder and thin film TlBaCaCuO high-temperature superconducting (Tl-HTS) materials. With transition temperatures ≥100K for several compounds, Tl-HTS materials present real opportunities for applications above 77 K. Experiments using (1) single crystals: determined precise structural parameters and identified the complex Tl 1+ -Tl 3+ equilibrium model; (2) powders: studied the complex thermodynamic phase diagram; and (3) epitaxial films: have studied fundamental properties such as electron pair symmetry and the effect of controlled extrinsic defects on flux pinning strength, as well as providing the large-area surfaces required for device applications. copyright 1997 Materials Research Society

  1. Effects of smoking on lung uptake of 201Tl during exercise myocardial perfusion imaging

    International Nuclear Information System (INIS)

    Ouyang Wei; He Guorong; Liu Jinhua

    2004-01-01

    Objective: To investigate the influence of smoking on lung uptake of 201 Tl during myocardial perfusion imaging. Methods: Ninety-two healthy subjects, with normal 201 Tl myocardial perfusion imaging findings but no evidence of left ventricular hypertrophy and pulmonary disease, were divided into three groups, smoker, nonsmoker and quitted smoker groups. Exercise/delay 201 Tl myocardial perfusion imaging was performed on all subjects included. Lung/heart ratio was defined on the anterior planar image obtained during exercise tomography. Results: Both the lung/heart ratios during exercise in smoker (0.40 ± 0.07, F=10.635, P 201 Tl lung/heart ratios in smokers are higher than in nonsmokers and this must be kept in mind when 201 Tl lung/heart ratios are used clinically, even in quitted smokers

  2. A Call for Expanding Inclusive Student Engagement in SoTL

    Directory of Open Access Journals (Sweden)

    Peter Felten

    2013-09-01

    of student-faculty partnerships focused on inquiry into teaching and learning. However, some students tend to be privileged in SoTL initiatives while others are discouraged, implicitly or explicitly, from engaging in this work. In this paper, we consider why certain students tend to be excluded from SoTL, summarize the possible developmental gains made by students and faculty when diverse student voices are included, and highlight strategies for generating a more inclusive SoTL. We call for expanding student engagement in SoTL by encouraging a diversity of student voices to engage in co-inquiry with faculty. Inclusive engagement has tremendous potential to enhance student and faculty learning, to deepen SoTL initiatives, and to help redress the exclusionary practices that too often occur in higher education.

  3. Sample dependent correlation between TL and LM-OSL in Al2O3:C

    International Nuclear Information System (INIS)

    Dallas, G.I.; Polymeris, G.S.; Stefanaki, E.C.; Afouxenidis, D.; Tsirliganis, N.C.; Kitis, G.

    2008-01-01

    Al 2 O 3 :C single crystals are known to exhibit different, sample dependent, glow-curve shapes. The relation between the Thermoluminescence (TL) traps and the linear modulated optically stimulation luminescence (LM-OSL) traps is of high importance. In the present work a correlation study is attempted using 23 single crystals with dimensions between 400 and 500μm. The correlation study involved two steps. In the first step, both TL glow curves and LM-OSL decay curves are deconvoluted and a one-to-one correlation between TL peaks and LM-OSL components is attempted. In the second step the TL glow-curves are corrected for thermal quenching, the corrected curves are deconvoluted and a new correlation between TL and LM-OSL individual components is performed

  4. Clinical application of 201Tl scintigraphy in patients with cold thyroid nodules

    International Nuclear Information System (INIS)

    Tonami, N.; Bunko, H.; Michigishi, T.; Kuwajima, A.; Hisada, K.

    1978-01-01

    201 Tl-chloride scintigraphy was performed in 45 patients with cold thyroid nodules. The 201 Tl scintigram was positive in 17 of 18 thyroid patients with cancer (94.4%), 8 of 20 patients with an adenoma (40.0%), 1 of 2 adenomatous goiter patients (50.5%), and all of 5 cases of chronic thyroiditis (100.0%). When the cold nodule was demonstrated to be positive with 201 Tl, the statistical chance of the lesion being a cellular one was 100.0% and a risk of its malignancy was 54.8%. On the other hand, the nodule with negative 201 Tl concentration had a 14.3% chance of cellularity and a 7.1% risk of malignancy. Thus, 201 Tl scintigraphy is of use in the differential diagnosis of the cold thyroid nodule

  5. Comparison of functional parameters of CsI:Tl crystals and thick films

    International Nuclear Information System (INIS)

    Fedorov, A.; Gektin, A.; Lebedynskiy, A.; Mateychenko, P.; Shkoropatenko, A.

    2013-01-01

    500 mkm thick CsI:Tl columnar films can be produced using thermal evaporation in vacuum by sublimation of the same bulk crystal. Comparison of afterglow and radiation stability of deposited CsI:Tl films with source crystal was the aim of current work. It is shown that the afterglow in the films is always below its level in initial single crystal. It was ascertained that the annealing atmospheres influence the processes leading to the activator depletion of the films during the thermal processing. -- Highlights: ► Thick CsI:Tl columnar films were obtained by thermal evaporation in vacuum. ► Radiation stability of such CsI:Tl films appears to be better than that of crystal. ► CsI:Tl film parameters can be modified by annealing in different atmospheres

  6. Isothermal martensite formation at sub-zero temperatures

    DEFF Research Database (Denmark)

    Stojko, Allan; Hansen, Mikkel Fougt; Slycke, Jan

    2012-01-01

    , quenched in oil, and thereafter investigated with vibrating sample magnetometry, which allows a quantitative assessment of the fraction of retained austenite as a function of the sub-zero temperature and time. Isothermal martensite formation was observed on interrupting the continuous cooling (5 K...... with a continuation of the martensitic transformation. On prolonged isothermal holding, a volume reduction was observed for AISI 52100, but not for AISI 1070. Copyright © 2011 by ASTM International....

  7. Multi-band Monopole Antennas Loaded with Metamaterial TL

    Science.gov (United States)

    Song, Zhi-jie; Liang, Jian-gang

    2015-05-01

    A novel metamaterial transmission line (TL) by loading complementary single Archimedean spiral resonator pair (CSASRP) is investigated and used to design a set of multi-frequency monopole antennas. The particularity is that the CSASRP which features dual-shunt branches in the equivalent circuit model is directly etched in the signal strip. By smartly controlling the element parameters, three antennas are designed and one of them covering UMTS and Bluetooth bands is fabricated and measured. The antenna exhibits impedance matching better than -10 dB and normal monopolar radiation patterns at working bands of 1.9-2.22 and 2.38-2.5 GHz. Moreover, the loaded element also contributes to the radiation, which is the major advantage of this prescription over previous lumped-element loadings. The proposed antenna is also more compact over previous designs.

  8. Superdeformed bands in Hg and Tl nuclei for N≤112

    International Nuclear Information System (INIS)

    Carpenter, M.P.; Jannsens, R.V.F.; Liang, Y.; Ahmad, I.; Henry, R.; Khoo, T.L.; Lauritsen, T.; Soramel, F.; Lewis, J.M.; Riedinger, L.L.; Yu, C.H.; Garg, U.; Reviol, W.; Pilotte, S.; Bearden, I.G.; Daly, P.J.

    1992-01-01

    The study of superdeformed (SD) nuclei in the A ∼ 190 region has provided a wealth of new information on SD states at moderate to high spins (I ∼ 10 to 50 h). The dynamical moment of inertia for almost all of the SD bands reported on to date in this mass region display a similar behavior, i.e. a smooth increase with increasing rotational frequency. This increase has been attributed to both quasiparticle alignments and a decrease in pairing with increasing rotational frequency. However, standard mean-field calculations have problems reproducing the magnitude and extent of the rise. The authors' recent results on SD states in the Hg-Tl nuclei at and below the N = 112 SD-gap add support to this interpretation of the rise in the dynamical moment of inertia while at the same time showing more clearly the inadequacies of the previous theoretical calculations

  9. Retrospective dosimetry using EPR and TL techniques: a status report

    International Nuclear Information System (INIS)

    Haskell, E.H.

    1996-01-01

    Methods of retrospective dosimetry, including luminescence and electron paramagnetic resonance spectroscopy (EPR), rely on measurement of accident dose absorbed by naturally occurring materials - ceramics in the case of both thermoluminescence (TL) and optically stimulated luminescence (OSL) and organic materials and bio- minerals in the case of EPR. Each of these methods relies on measurement of radiation defects resulting from accidental exposure. Since defects also result from natural sources of radiation over the lifetime of a sample, analysis is usually restricted to materials for which the natural dose may be determined and subtracted from the measured cumulative dose. Luminescence dating techniques rely heavily on an accurate assessment of cumulative dose from natural radiation sources, and dating research has provided us with the bulk of our knowledge in this area. Virtually all of the work on natural dose determination can be directly applied to retrospective techniques. With EPR techniques the cumulative dose from diagnostic x- rays is also of importance

  10. A new type of spurious reading in TL personnel monitoring

    International Nuclear Information System (INIS)

    Duftschmid, K.E.; Stadtmann, H.; Strachotinsky, Ch.; Winker, N.

    1996-01-01

    A particularly serious type of spurious reading in automated TL personnel monitoring has been observed. These readings simulate dose values up to several mSv and can only be detected by glow curve analysis. Characteristics for these events are high artifical dose values and irregular glow curves of a particular shape. Extensive investigations to reproduce this effect purposely failed to produce any results. It can be assumed, however, that it must be some chemical surface contamination, which penetrates the sealed dosemeter bag or which is transferred from the bag to the detector. The effect can be eliminated by manual cleaning of the dosemeter cards. The importance of this observation lies in the fact that only proper glow curve evaluation can prevent the monitoring service from reporting artificial high dose readings creating lots of serious problems. The paper shows how this problem can be avoided for this kind of spurious effect, if glow curves are available and stored for every dosemeter readout. (author)

  11. Giant Rashba spin splitting in Bi2Se3: Tl

    KAUST Repository

    Singh, Nirpendra

    2014-07-25

    First-principles calculations are employed to demonstrate a giant Rashba spin splitting in Bi2Se3:Tl. Biaxial tensile and compressive strain is used to tune the splitting by modifying the potential gradient. The band gap is found to increase under compression and decreases under tension, whereas the dependence of the Rashba spin splitting on the strain is the opposite. Large values of αR = 1.57 eV Å at the bottom of the conduction band (electrons) and αR = 3.34 eV Å at the top of the valence band (holes) are obtained without strain. These values can be further enhanced to αR = 1.83 eV Å and αR = 3.64 eV Å, respectively, by 2% tensile strain. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Core excitations across the neutron shell gap in 207Tl

    Directory of Open Access Journals (Sweden)

    E. Wilson

    2015-07-01

    Full Text Available The single closed-neutron-shell, one proton–hole nucleus 207Tl was populated in deep-inelastic collisions of a 208Pb beam with a 208Pb target. The yrast and near-yrast level scheme has been established up to high excitation energy, comprising an octupole phonon state and a large number of core excited states. Based on shell-model calculations, all observed single core excitations were established to arise from the breaking of the N=126 neutron core. While the shell-model calculations correctly predict the ordering of these states, their energies are compressed at high spins. It is concluded that this compression is an intrinsic feature of shell-model calculations using two-body matrix elements developed for the description of two-body states, and that multiple core excitations need to be considered in order to accurately calculate the energy spacings of the predominantly three-quasiparticle states.

  13. Retrospective dosimetry using EPR and TL techniques: a status report

    Energy Technology Data Exchange (ETDEWEB)

    Haskell, E.H.

    1996-12-31

    Methods of retrospective dosimetry, including luminescence and electron paramagnetic resonance spectroscopy (EPR), rely on measurement of accident dose absorbed by naturally occurring materials - ceramics in the case of both thermoluminescence (TL) and optically stimulated luminescence (OSL) and organic materials and bio- minerals in the case of EPR. Each of these methods relies on measurement of radiation defects resulting from accidental exposure. Since defects also result from natural sources of radiation over the lifetime of a sample, analysis is usually restricted to materials for which the natural dose may be determined and subtracted from the measured cumulative dose. Luminescence dating techniques rely heavily on an accurate assessment of cumulative dose from natural radiation sources, and dating research has provided us with the bulk of our knowledge in this area. Virtually all of the work on natural dose determination can be directly applied to retrospective techniques. With EPR techniques the cumulative dose from diagnostic x- rays is also of importance.

  14. Non-radiation induced signals in TL dosimetry

    International Nuclear Information System (INIS)

    German, U.; Weinstein, M.

    2002-01-01

    One source of background signals, which are non-radiation related, is the reader system and it includes dark current, external contaminants and electronic spikes. These factors can induce signals equivalent to several hundredths of mSv. Mostly, the effects are minimised by proper design of the TLD reader, but some effects are dependent on proper operation of the system. The other main group of background signals originate in the TL crystal and is due to tribothermoluminescence, dirt, chemical reactions and stimulation by visible or UV light. These factors can have a significant contribution, equivalent to over several mSv, depending on whether the crystal is bare or protected by PTFE. Working in clean environments, monitoring continuously the glow curve and performing glow curve deconvolution are suggested to minimise non-radiation induced spurious signals. (author)

  15. Clinical use of /sup 201/Tl myocardial scintigraphy

    Energy Technology Data Exchange (ETDEWEB)

    Senda, K; Imaeda, T; Kato, T; Asada, S; Doi, H

    1977-04-01

    Myocardial imaging with /sup 201/Tl and scinticamera was studied experimentally using specially designed phantoms and clinically in 23 patients with myocardial infarction or other heart disease. In the phantom experiment, quality of image, accumulative count rate, and detectability of the defect were compared to obtain the best technique for their detection, using four different collimators, i.e., converging, pin-hole, 4000-hole, and 140 keV high-resolution, at two photopeak levels of /sup 201/Tl of 75 and 167 keV, and combining a radiation absorber. In patient examination, myocardial images taken at different periods after injection, different detecting conditions of the scinticamera, and various detecting projections were compared. Images of the converging collimator at the 75 keV photopeak revealed considerably higher accumulative counts and relatively higher quality than those of other detecting conditions. It was necessary to take as many images as possible in various projections, in order to detect the location and size of the myocardial ischemic lesion because the lesion was demonstrated as a clear defect only in profile. It became evident that images taken between about 25 and 90 min delineated the myocardium more clearly than those taken in other periods. Normal images taken in 8 patients without ischemic heart disease appeared in the shape of a doughnut of horseshoe, demonstrating mainly the left venticular myocardium. The image was faint in the region of the aortic or mitral valve and thin in the region of the apical wall. A faint image of the right ventricular myocardium was sometimes seen. In 3 patients with valvular heart disease, findings suggested changes in the thickness of myocardium and the distribution of coronary blood flow. In 11 of 12 patients with old myocardial infarction, the location and size of the lesion was detected.

  16. Column Chromatography To Obtain Organic Cation Sorption Isotherms.

    Science.gov (United States)

    Jolin, William C; Sullivan, James; Vasudevan, Dharni; MacKay, Allison A

    2016-08-02

    Column chromatography was evaluated as a method to obtain organic cation sorption isotherms for environmental solids while using the peak skewness to identify the linear range of the sorption isotherm. Custom packed HPLC columns and standard batch sorption techniques were used to intercompare sorption isotherms and solid-water sorption coefficients (Kd) for four organic cations (benzylamine, 2,4-dichlorobenzylamine, phenyltrimethylammonium, oxytetracycline) with two aluminosilicate clay minerals and one soil. A comparison of Freundlich isotherm parameters revealed isotherm linearity or nonlinearity was not significantly different between column chromatography and traditional batch experiments. Importantly, skewness (a metric of eluting peak symmetry) analysis of eluting peaks can establish isotherm linearity, thereby enabling a less labor intensive means to generate the extensive data sets of linear Kd values required for the development of predictive sorption models. Our findings clearly show that column chromatography can reproduce sorption measures from conventional batch experiments with the benefit of lower labor-intensity, faster analysis times, and allow for consistent sorption measures across laboratories with distinct chromatography instrumentation.

  17. An Isothermal Steam Expander for an Industrial Steam Supplying System

    Directory of Open Access Journals (Sweden)

    Chen-Kuang Lin

    2015-01-01

    Full Text Available Steam is an essential medium used in the industrial process. To ensure steam quality, small and middle scale boilers are often adopted. However, because a higher steam pressure (compared to the necessary steam pressure is generated, the boiler’s steam pressure will be reduced via a pressure regulator before the steam is directed through the process. Unfortunately, pressure is somewhat wasted during the reducing process. Therefore, in order to promote energy efficiency, a pressure regulator is replaced by a steam expander. With this steam expander, the pressure will be transformed into mechanical energy and extracted during the expansion process. A new type of isothermal steam expander for an industrial steam supplying system will be presented in the paper. The isothermal steam expander will improve the energy efficiency of a traditional steam expander by replacing the isentropic process with an isothermal expansion process. With this, steam condensation will decrease, energy will increase, and steam quality will be improved. Moreover, the mathematical model of the isothermal steam expander will be established by using the Schmidt theory, the same principle used to analyze Stirling engines. Consequently, by verifying the correctness of the theoretical model for the isothermal steam expander using experimental data, a prototype of 100 c.c. isothermal steam expander is constructed.

  18. Numerical studies of pulsating buoyant plume in isothermal and non isothermal situations

    International Nuclear Information System (INIS)

    Sharma, Pavan K.; Singh, R.K.; Mohanty, Ananya; Das, D.

    2014-01-01

    A computational study has been carried out for predicting the behaviour of buoyant plume in isothermal and non isothermal configuration. General simulation objectives of any buoyant flow simulation are macroscopic in nature and deals with the grass data in respect of buoyancy induced scalar transport. However, the accuracy of predicting such macroscopic parameters is a strong function of several other microscopic parameters which govern the overall macroscopic behaviour. Some of the microscopic parameters for analysis could be buoyancy induced stable/unstable flows, relative plume behaviour, baroclinic velocity distribution etc. Only the CFD based flow modelling approach is capable of calculating several of these aspects. LES based modelling scores over the conventional RANS based computational modelling. The primary objective of the present study was to model buoyant plume simulation of different types in order to explore the details regarding plume and flow structure, instabilities and puffing behaviour. One of the influencing parameters on the overall plume behaviour is the buoyancy resolution index i.e. fineness of chosen grid in relation to the buoyancy intensity and other hydrodynamic parameters. The grid sensitivity studies have been carried out to find out the optimum value grid size by way of buoyant pool fire simulations. Comparative simulation has also been made for a square and round pool fire and it was found that for engineering simulations equivalent area square pool modeling is sufficient. Using the optimum value of grid size and square pool shape simulations have been carried out for different value of fire intensity. The flame puffing frequency as calculated by the reported correlation was compared against the computationally observed puffing frequency and the agreement was generally found to be excellent. Besides these results the comparisons of predicted peak flames temperatures data for various case studies with the available experimental data

  19. Isothermal and non-isothermal infiltration and deuterium transport: a case study in a soil column from a headwater catchment

    Czech Academy of Sciences Publication Activity Database

    Sobotková, M.; Sněhota, M.; Budínová, E.; Tesař, Miroslav

    2017-01-01

    Roč. 65, č. 3 (2017), s. 234-243 ISSN 0042-790X Grant - others:GA ČR(CZ) GA14-03691S Institutional support: RVO:67985874 Keywords : isothermal infiltration * non-isothermal infiltration * column leaching * breakthrough curve * deuterium * viscosity * capillary trapping * entrapped air * permeability Subject RIV: DA - Hydrology ; Limnology OBOR OECD: Environmental sciences (social aspects to be 5.7) Impact factor: 1.654, year: 2016

  20. Isothermal and non-isothermal cure of a tri-functional epoxy resin (TGAP): A stochastic TMDSC study

    International Nuclear Information System (INIS)

    Hutchinson, John M.; Shiravand, Fatemeh; Calventus, Yolanda; Fraga, Iria

    2012-01-01

    Highlights: ► First evaluation of T g of tri-functional epoxy resin TGAP by DSC. ► Clearly shows advantages of TOPEM for isothermal and non-isothermal cure analysis. ► Evidence of highly non-linear enthalpy relaxation in partially cured TGAP system. - Abstract: The isothermal cure of a highly reactive tri-functional epoxy resin, tri-glycidyl para-amino phenol (TGAP), with diamino diphenyl sulphone (DDS), at two different cure temperatures T c has been studied by both conventional differential scanning calorimetry (DSC) and by a stochastic temperature modulated DSC technique, TOPEM. From a series of isothermal cure experiments for increasing cure times, the glass transition temperature T g as a function of isothermal cure time is determined by conventional DSC from a second (non-isothermal) scan, and the vitrification time t v is obtained as the time at which T g = T c . In parallel, TOPEM experiments at the same T c lead directly to the determination of t v from the sigmoidal change in the quasi-static heat capacity. It is not possible to identify the glass transition temperature of the fully cured system, T g∞ , in a third scan by conventional DSC. In contrast, with TOPEM a second (non-isothermal) scan at 2 K/min after the isothermal cure gives rise to three separate transitions: devitrification of the partially cured and vitrified material; almost immediate vitrification as the T g of the system again rises; finally another devitrification, at a temperature approximating closely to T g∞ . Thus with TOPEM it is possible to obtain a calorimetric measure of the glass transition temperature of this fully cured system.

  1. Chemical Bonding in Tl Cuprates Studied by X-Ray Photoemission

    Energy Technology Data Exchange (ETDEWEB)

    Lao, J.Y.; Overmyer, D.L.; Ren, Z.F.; Siegal, M.P.; Vasquez, R.P.; Wang, J.H.

    1999-04-05

    Epitaxial thin films of the Tl cuprate superconductors Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8}, Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10}, and TL{sub 0.78}Bi{sub 0.22}Ba{sub 0.4}Sr{sub 1.6}Ca{sub 2}Cu{sub 3}O{sub 9{minus}{delta}} are studied with x-ray photoemission spectroscopy. These data, together with previous measurements in this lab of Tl{sub 2}Ba{sub 2}CuO{sub 6+{delta}} and TlBa{sub 2}CaCu{sub 2}O{sub 7{minus}{delta}}, comprise a comprehensive data set for a comparative study of Tl cuprates with a range of chemical and electronic properties. In the Cu 2p spectra, a larger energy separation between the satellite and main peaks (E{sub s}-E{sub m}) and a lower intensity ratio (I{sub s}/I{sub m}) are found to correlate with higher values of T{sub c}. Analysis of these spectra within a simple configuration interaction model suggests that higher values of T{sub c} are related to low values of the O 2p {r_arrow} Cu 3d charge transfer energy. In the O 1s region, a smaller bond length between Ba and Cu-O planar oxygen is found to correlate with a lower binding energy for the signal associated with Cu-O bonding, most likely resulting from the increased polarization screening by Ba{sup 2+} ions. For samples near optimum doping, maximum T{sub c} is observed to occur when the Tl 4f{sub 7/2} binding energy is near 117.9 eV, which is near the middle of the range of values observed for Tl cuprates. Higher Tl 4f{sub 7/2} binding energies, corresponding to formal oxidation states nearer Tl{sup 1+}, are also found to correlate with longer bond lengths between Ba and Tl-O planar oxygen, and with higher binding energies of the O 1s signal associated with Tl-O bonding.

  2. Chemical bonding in Tl cuprates studied by x-ray photoemission

    Energy Technology Data Exchange (ETDEWEB)

    Vasquez, R.P. [Center for Space Microelectronics Technology, Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109-8099 (United States); Siegal, M.P.; Overmyer, D.L. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Ren, Z.F.; Lao, J.Y.; Wang, J.H. [Materials Synthesis Laboratory, Department of Chemistry, State University of New York, Buffalo, New York 14260-3000 (United States)

    1999-08-01

    Epitaxial thin films of the Tl cuprate superconductors Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8}, Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10}, and Tl{sub 0.78}Bi{sub 0.22}Ba{sub 0.4}Sr{sub 1.6}Ca{sub 2}Cu{sub 3}O{sub 9{minus}{delta}} are studied with x-ray photoemission spectroscopy. These data, together with previous measurements in this lab of Tl{sub 2}Ba{sub 2}CuO{sub 6+{delta}} and TlBa{sub 2}CaCu{sub 2}O{sub 7{minus}{delta}}, comprise a comprehensive data set for a comparative study of Tl cuprates with a range of chemical and electronic properties. In the Cu 2p spectra, a larger energy separation between the satellite and main peaks (E{sub s}{minus}E{sub m}) and a lower intensity ratio (I{sub s}/I{sub m}) are found to correlate with higher values of T{sub c}. Analysis of these spectra within a simple configuration interaction model suggests that higher values of T{sub c} are related to low values of the O&hthinsp;2p{r_arrow}Cu&hthinsp;3d charge transfer energy. In the O&hthinsp;1s region, a smaller bond length between Ba and Cu-O planar oxygen is found to correlate with a lower binding energy for the signal associated with Cu-O bonding, most likely resulting from the increased polarization screening by Ba{sup 2+} ions. For samples near optimum doping, maximum T{sub c} is observed to occur when the Tl 4f{sub 7/2} binding energy is near 117.9 eV, which is near the middle of the range of values observed for Tl cuprates. Higher Tl&hthinsp;4f{sub 7/2} binding energies, corresponding to formal oxidation states nearer Tl{sup 1+}, are also found to correlate with longer bond lengths between Ba and Tl-O planar oxygen, and with higher binding energies of the O&hthinsp;1s signal associated with Tl-O bonding. {copyright} {ital 1999} {ital The American Physical Society}

  3. Production of valuable pyrolytic oils from mixed Municipal Solid Waste (MSW in Indonesia using non-isothermal and isothermal experimental

    Directory of Open Access Journals (Sweden)

    Indra Mamad Gandidi

    2017-09-01

    Full Text Available Municipal solid waste (MSW, disposed of at open dumping sites, poses health risks, contaminates surface water, and releases greenhouse gasses such as methane. However, pyrolysis offers the opportunity to convert MSW into Bio-Oil (BO for clean energy resource. In this paper, an MSW sample consisting of plastic, paper and cardboard, rubber and textiles, and vegetable waste is pyrolysed on a laboratory scale in a fixed-bed vacuum reactor. In the non-isothermal process, the sample was fed into the reactor and then heated. In the isothermal process, the reactor is first heated and then the sample is added. The non-isothermal process created greater BO in both quality and quantity. The BO had a larger amount of gasoline species than diesel-48 fuel, with at 33.44%the BO produced by isothermal pyrolysis and 36.42% in non-isothermal pyrolysis. However the product of isothermal pyrolysis had a higher acid content that reduced its heating value.

  4. Trithallium tetraselenophosphate Tl3PSe4, and trithallium tetrathioarsenate, Tl3AsS4, by neutron time-of-flight diffraction

    International Nuclear Information System (INIS)

    Alkire, R.W.; Vergamini, P.J.; Larson, A.C.; Morosin, B.

    1984-01-01

    Room-temperature (293 K) single-crystal structure determinations of the isostructural materials Tl 3 PSe 4 and Tl 3 AsS 4 were performed at the Los Alamos National Laboratory Pulsed Neutron Facility. For Tl 3 PSe 4 : Msub(r) = 959.92, Pcmn, a = 9.276 (1), b = 11.036 (2), c = 9.058 (1) A, V = 927.27 A 3 , Z = 4, Dsub(m) = 6.87 (2), Dsub(x) = 6.876 Mg m -3 , lambdasub(neutron) = 0.5 → 5.2 A, F(000) = 252.5 fm. For Tl 3 AsS 4 : Msub(r) = 816.29, Pcmn, a = 9.084 (3), b = 10.877 (3), c = 8.877 (3) A, V = 877.11 A 3 , Z = 4, Dsub(m) = 6.18 (2), Dsub(x) = 6.181 Mg m -3 , lambdasub(neutron) = 0.5 → 5.2 A, F(000) = 177.2 fm. For Tl 3 PSe 4 (Tl 3 AsS 4 ), 1929 (1013) reflections were measured with I > 3sigma(I) and refined by full-matrix least squares to R(F) = 0.061 (0.063). Results on atomic refinement from this study represent an order of magnitude increase in precision over previous single-crystal X-ray structural work using Mo Kα radiation. The PSe 4 3- (AsS 4 3- ) groups have essentially tetrahedral configurations and one Tl + ion shows large anisotropic thermal motion which is structure related. (Auth.)

  5. Thermal dependence of luminescence lifetimes and radioluminescence in quartz

    Energy Technology Data Exchange (ETDEWEB)

    Pagonis, V., E-mail: vpagonis@mcdaniel.edu [McDaniel College, Physics Department, Westminster, MD 21157 (United States); Chithambo, M.L. [Department of Physics and Electronics, Rhodes University, PO BOX 94, Grahamstown 6140 (South Africa); Chen, R. [Raymond and Beverly Sackler School of Physics and Astronomy, Tel-Aviv University, Tel-Aviv 69978 (Israel); Chruścińska, A. [Institute of Physics, Nicholas Copernicus University, 87-100 Toruń (Poland); Fasoli, M. [Department of Materials Science, University of Milano-Bicocca, Via Cozzi 53, 20125 Milano (Italy); Li, S.H. [Department of Earth Sciences, The University of Hong Kong (Hong Kong); Martini, M. [Department of Materials Science, University of Milano-Bicocca, Via Cozzi 53, 20125 Milano (Italy); Ramseyer, K. [Institut für Geologie, Baltzerstrasse 1-3, 3012 Bern (Switzerland)

    2014-01-15

    During time-resolved optical stimulation experiments (TR-OSL), one uses short light pulses to separate the stimulation and emission of luminescence in time. Experimental TR-OSL results show that the luminescence lifetime in quartz of sedimentary origin is independent of annealing temperature below 500 °C, but decreases monotonically thereafter. These results have been interpreted previously empirically on the basis of the existence of two separate luminescence centers L{sub H} and L{sub L} in quartz, each with its own distinct luminescence lifetime. Additional experimental evidence also supports the presence of a non-luminescent hole reservoir R, which plays a critical role in the predose effect in this material. This paper extends a recently published analytical model for thermal quenching in quartz, to include the two luminescence centers L{sub H} and L{sub L}, as well as the hole reservoir R. The new extended model involves localized electronic transitions between energy states within the two luminescence centers, and is described by a system of differential equations based on the Mott–Seitz mechanism of thermal quenching. It is shown that by using simplifying physical assumptions, one can obtain analytical solutions for the intensity of the light during a TR-OSL experiment carried out with previously annealed samples. These analytical expressions are found to be in good agreement with the numerical solutions of the equations. The results from the model are shown to be in quantitative agreement with published experimental data for commercially available quartz samples. Specifically the model describes the variation of the luminescence lifetimes with (a) annealing temperatures between room temperature and 900 °C, and (b) with stimulation temperatures between 20 and 200 °C. This paper also reports new radioluminescence (RL) measurements carried out using the same commercially available quartz samples. Gaussian deconvolution of the RL emission spectra was

  6. A quartz Cherenkov detector for polarimetry at the ILC

    International Nuclear Information System (INIS)

    Vauth, Annika

    2014-09-01

    At the proposed International Linear Collider (ILC), the use of polarised electron and positron beams is a key ingredient of the physics program. A measurement of the polarisation with a yet unprecedented precision of δP / P =0.25% is required. To achieve this, Compton polarimeter measurements in front of and behind the collision point are foreseen. In this thesis, a novel concept for a detector for ILC polarimetry is introduced to eliminate one of the dominating systematics limiting the previous best measurement of beam polarisation: a detector using quartz as Cherenkov medium could increase the tolerance against non-linear photodetector responses. The high refractive index of quartz results in a higher Cherenkov light yield compared to conventional Cherenkov gases. This could allow single-peak resolution in the Cherenkov photon spectra produced by the Compton electrons at the polarimeters. The detailed simulation studies presented in this work imply that such single-peak resolution is possible. Considerations for the choice of a suitable detector geometry are discussed. A four-channel prototype has been constructed and successfully operated in a first testbeam campaign at the DESY testbeam, confirming simulation predictions. Although further studies have to be considered to quantify all aspects of the detector response, the findings of the analysis of the data from the first testbeam are promising with regards to reaching the desired light yield. In the final part of this thesis, the application of a detector concept allowing single-peak resolution to the polarisation measurement at the ILC is examined. Two of the main sources of systematic uncertainties on the polarimeter measurements are detector non-linearities and misalignments. The performance of the suggested quartz detector concept in Monte Carlo studies promises a control of these systematics which meets the precision requirements for ILC polarimetry.

  7. Study of quartz lascas properties for technological applications

    International Nuclear Information System (INIS)

    Hummel, D.C.A.; Shinohara, A.H.; Torikai, D.; Suzuki, C.K.

    1988-01-01

    This paper describes a fundamental properties of Brasilian quartz lascas characterized by x-ray diffraction topography and goniometry, density and ultrasonic attenuation measurements, optical inspectoscopy, optical microscopy and impurity analysis by ASS (Al,Fe,Na,K,Li,Ca,Mn,Mg,Cr and Cu). The results were discussed with the correlation with nominal lascas graded as ''Ist'', ''mix'',''2nd'',''3rd'' and ''4th'' made by visual observation taking in consideration the transparency. The samples were collected from the proper mines deposited lascas. The main brazilian producted states are Minas Gerais, Bahia and Goias. (author) [pt

  8. Transitional grain-size-sensitive flow of milky quartz aggregates

    Science.gov (United States)

    Fukuda, J. I.; Holyoke, C. W., III; Kronenberg, A. K.

    2014-12-01

    Fine-grained (~15 μm) milky quartz aggregates exhibit reversible flow strengths in triaxial compression experiments conducted at T = 800-900oC, Pc = 1.5 GPa when strain rates are sequentially decreased (typically from 10-3.5 to 10-4.5 and 10-5.5 s-1), and then returned to the original rate (10-3.5 s-1), while samples that experience grain growth at 1000oC (to 35 μm) over the same sequence of strain rates exhibit an irreversible increase in strength. Polycrystalline quartz aggregates have been synthesized from natural milky quartz powders (ground to 5 μm) by HIP methods at T = 1000oC, Pc = 1.5 GPa and t = 24 hours, resulting in dense, fine-grained aggregates of uniform water content of ~4000 ppm (H/106Si), as indicated by a broad OH absorption band at 3400 cm-1. In experiments performed at 800o and 900oC, grain sizes of the samples are essentially constant over the duration of each experiment, though grain shapes change significantly, and undulatory extinction and deformation lamellae indicate that much of the sample shortening (to 50%) is accomplished, over the four strain-rate steps, by dislocation creep. Differential stresses measured at T = 800oC decrease from 160 to 30 MPa as strain rate is reduced from 10-4.6 to 10-5.5 s-1, and a stress of 140 MPa is measured when strain rate is returned to 10-4.5 s-1. Samples deformed at 1000o and 1100oC experience normal grain growth, with grain boundary energy-driven grain-coarsening textures superposed by undulatory extinction and deformation lamellae. Differential stresses measured at 1000oC and strain rates of 10-3.6, 10-4.6, and 10-5.5 s-1 are 185, 80, and 80 MPa, respectively, while an increased flow stress of 260 MPa is measured (following ~28 hours of prior high temperature deformation and grain growth) when strain rate is returned to 10-3.6 s-1. While all samples exhibit lattice preferred orientations, the stress exponent n inferred for the fine-grained 800oC sample is 1.5 and the stress exponent of the coarse

  9. Ultrasonic attenuation measurements and 'glassy' behaviour of neutron irradiated quartz

    International Nuclear Information System (INIS)

    Laermans, C.; Esteves, V.; Vanelstraete, A.

    1986-01-01

    The ultrasonic attenuation of longitudinal acoustic waves in slightly disordered crystalline quartz has been measured over a temperature range from 1.3 to 300 K, using the pulse-echo technique. Neutron irradiation is demonstrated to increase the ultrasonic attenuation at low temperatures indicating the presence of two-level tunneling systems similar to those of glasses. The present low-temperature acoustic results agree with a frequency independence and a T 3 behaviour for the relaxation process predicted by the two-level tunneling TLS-model where the regime ωT 1 >> 1 holds. (author)

  10. Power dependence on the rotational strength in a quartz crystal

    International Nuclear Information System (INIS)

    Joshi, N.V.; Salcedo, D.; Gil, H.

    2007-01-01

    The rotational strength of optical activity has been examined as a function of power of the incident radiation in a quartz crystal for the first time. It has been observed that the angle of rotation is proportional to the square root of the intensity of the radiation. The present experimental data directly support the recently proposed model which takes into account the electronic polarizability rather than the atomic polarizability. This model explicitly explains the role of the incident power in estimating the angle of rotation

  11. Quartz exposure, retention, and early silicosis in sheep.

    Science.gov (United States)

    Bégin, R; Dufresne, A; Cantin, A; Possmayer, F; Sébastien, P; Fabi, D; Bilodeau, G; Martel, M; Bisson, D; Pietrowski, B

    1989-05-01

    The purposes of this study were (1) to investigate the chronology of events in cellular and biochemical changes thought to be important in the development of silicosis, (2) to relate these to changes in lung function and radiograph, and (3) to evaluate the relation of quartz exposure and retention to individual response leading to early silicosis. Thirty-six sheep were exposed by repeated intratracheal infusion at 10-day intervals to 100 mg Minusil-5 in 100 ml saline (Si group), and 10 sheep were exposed at the same intervals to 100 ml saline (control). All sheep were investigated at 3-month intervals by chest radiograph, lung function, and lung lavage. At month 9, chest radiograph score of parenchymal opacities was significantly increased at 2.8 +/- 0.6 versus 0.4 +/- 0.4 in the Si group (p less than .05), establishing early radiologic silicosis. Lung function was significantly altered with reduction in lung compliance, vital capacity, and diffusion capacity (p less than .05). Lung lavage cellularity revealed significant increase in total cells (X 2.5), macrophages (X3), and neutrophils (X3). Albumin in BAL remained at the control level. Fibronectin production was significantly increased, as was the fibroblast growth activity, without significant change in procollagen 3 at this early stage of disease. Total phospholipids were significantly elevated in the Si-exposed sheep, and the profile demonstrated an increase in all the phospholipid components. Spontaneous release of hydrogen peroxide by alveolar cells was not increased, but in the presence of phorbol myristate acetate (PMA) higher levels of peroxide were found in the quartz-exposed sheep (p less than .05). The cellular and biochemical alterations of lung lavage preceded other changes. At month 12, there were good correlations (r greater than .49, p less than .001) between parameters evaluating related phenomena but poor correlations between measurements evaluating different aspects of the disorder. To

  12. Scratching experiments on quartz crystals: Orientation effects in chipping

    Science.gov (United States)

    Tellier, C. R.; Benmessaouda, D.

    1994-06-01

    The deformation and microfracture properties of quartz crystals were studied by scratching experiments. The critical load at which microfractures are initiated was found to be orientation dependent, whereas the average width of ductile grooves and chips remained relatively insensitive to crystal orientation. In contrast, a marked anisotropy in the shape of chips was observed. This anisotropy has been interpreted in terms of microfractures propagating preferentially along slip planes. Simple geometrical conditions for the SEM (scanning electron microscopy) observation of active slip planes are proposed.

  13. Miniature quartz crystal-resonator-based thermogravimetric detector.

    Science.gov (United States)

    Sai, N; Tagawa, Y; Sohgawa, M; Abe, T

    2014-09-01

    In this work, a new design for a microheater combined with a quartz crystal microbalance (QCM) array for thermogravimetric analysis is presented. Each QCM consists of two electrodes to excite thickness-shear-mode vibrations and one microheater to increase the temperature on the crystal backside. In addition, all the electrode pads are patterned on the crystal backside, making the design of the QCM compact and user-friendly. Finally, the proposed QCM array was employed to separate ethanol from methanol. This was successfully achieved via thermal desorption spectra calculated by differentiating the frequency changes.

  14. Preliminary results on TL and OSL aluminium oxide dosimeters developed at IPEN

    Energy Technology Data Exchange (ETDEWEB)

    Fukumori, David T.; Yoshito, Walter K.; Ussui, Valter; Lazar, Dolores R.R.; Campos, Leticia L., E-mail: fukumori@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-07-01

    The aluminum oxide composes the modern TL and OSL radiation dosimeters. TL and OSL phenomena are related to chemical elements in the crystalline structure of {alpha}-Al{sub 2}O{sub 3}. The aim of this work was to develop materials based on aluminum oxide for use in TL and OSL dosimetry. The studies included the dosimetric properties of alumina samples obtained by electro fusion, adsorption and coprecipitation. Electro fused alumina commercially available as abrasive particles was used to produce the pellets by glass sintering. Adsorption and coprecipitation were the methods used to insert metal ions to alumina. The best results were achieved with electro fused alumina and Tm{sup 3+} doped Al{sub 2}O{sub 3} pellets. The electro fused alumina-glass pellets show TL and OSL signals and the TL curve has two peaks. Its minimum detectable radiation dose is 7.2 mGy and the linearity of TL response as function of dose is up to about 800 mGy. The {alpha}-Al{sub 2}O{sub 3}:Tm pellets produced by sintering at 1550 deg C presented a meaningful TL glow curve so that it is worth studying their properties and viability of use in dosimetry. (author)

  15. The usefulness of [sup 201]TlCl scintigraphy for the diagnosis of breast tumor

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, Tamami; Moriya, Etsuo; Miyamoto, Yukio; Kawakami, Kenji; Kubo, Hirotaka; Uchida, Takeshi [Jikei Univ., Tokyo (Japan). School of Medicine

    1994-06-01

    The usefulness of [sup 201]TlCl SPECT (Tl SPECT) for the diagnosis of breast cancer was evaluated in 14 patients with various breast tumors (9 with invasive ductal carcinoma, 2 with fibroadenoma and 3 with benign process). These tumors ranged in size from 1.5 cm x 1.5 cm to 15.0 cm x 14.0 cm. Tl SPECT was carried out 2 hours after the intravenous injection of [sup 201]TlCl (185 MBq). For quantitative study, ROIs were set in the tumor (T), normal tissue of the opposite breast (B) and myocardium (M). Count ratios of T/B and T/M were calculated. Eight patients with breast cancer and a case of fibroadenoma showed intense accumulation of [sup 201]TlCl in the tumors. The T/B ratio was 1.20[+-]0.68 and the T/M ratio was 0.68[+-]0.31 in the 9 cases. Lymph node metastasis was detected in 2 of 6 cases that were confirmed at operation. No remarkable accumulation of [sup 201]TlCl was seen in 4 patients with benign process. One patient with benign tumor showed a false positive result. The rates of accuracy of mammography and ultrasonography for the same subjects were 82% and 84%, respectively. The results suggest that [sup 201]TlCl SPECT might be useful to assess breast cancer in cases in which the findings of other modalities are equivocal. (author).

  16. Myocardial 201Tl washout after combined dipyridamole submaximal exercise stress: Reference values from different patient groups

    International Nuclear Information System (INIS)

    Fridrich, L.

    1989-01-01

    Dipyridamole stress is favorable in patients unable to exercise maximally for 201 Tl myocardial scintigraphy. Aside from an analysis of uptake defects, proper washout analysis can be limited by heart rate variations when isolated dipyridamole stress is used. Heart rate standardized 201 Tl washout kinetics after a combined dipyridamole and submaximal exercise stress protocol (CDSE), feasible in elderly patients as well as in patients with peripheral artery disease, were therefore studied to investigate the 201 Tl washout after CDSE in differently defined patient groups: Group I comprised 19 patients with documented heart disease and angiographically excluded coronary artery disease (CAD); group II contained 17 patients with a very low likelihood of CAD determined by both normal exercise radionuclide ventriculography and normal 201 Tl uptake. Group III comprised 56 patients with a 50% pretest likelihood of CAD but normal 201 Tl uptake. Mean washout values were nearly identical in all groups. Despite similar uptake patterns, however, washout standardized by CDSE was significantly lower than the normal washout values after maximal treadmill exercise. Thus an obviously lower 201 Tl washout after CDSE than after maximal treadmill exercise must be considered if washout analysis criteria after dipyridamole are applied to evaluate ischemic heart disease. Nevertheless, heart rate elevation achieved by additional submaximal exercise stress seems necessary, adequate and clinically safe for standardisation of washout analysis in dipyridamole 201 Tl scintigraphy. (orig.)

  17. Dipyridamole 201Tl scintigraphy in the evaluation of prognosis after myocardial infarction

    International Nuclear Information System (INIS)

    Okada, R.D.; Glover, D.K.; Leppo, J.A.

    1991-01-01

    Dipyridamole 201Tl imaging has been proposed as an alternative to exercise ECG testing for the prehospital discharge evaluation of patients recovering from myocardial infarction. The rationale is that many postinfarction patients with exercise-induced ischemia experience later cardiac events, and the sensitivity of predischarge exercise ECG testing in patients with multivessel disease ranges from only 45% to 62%. In addition, several groups of investigators have shown the sensitivity of submaximum exercise 201Tl imaging to be less than ideal. This report summarizes the current status of dipyridamole 201Tl imaging in the period of 1-13 days after myocardial infarction. Although the number of studies performed to date is limited, the following conclusions can be drawn: dipyridamole 201Tl imaging after myocardial infarction was associated with no serious side effects, and those present could be quickly reversed with aminophylline; redistribution with dipyridamole 201Tl images definitely correlates with prognosis after uncomplicated myocardial infarction; dipyridamole 201Tl imaging is definitely useful in patients unable to exercise for a variety of reasons; and future studies are definitely indicated to further define the role of dipyridamole 201Tl imaging for assessing prognosis, especially in those patients undergoing interventional therapy after acute myocardial infarction

  18. Usefulness of 201Tl myocardial scintigraphy after dipyridamole infusion in patients with atherosclerotic vascular disease

    International Nuclear Information System (INIS)

    Toyama, Takuji; Nishimura, Tsunehiko; Uehara, Toshiisa

    1992-01-01

    To determine the utility for detecting ischemic heart disease (IHD), dipyridamole thallium myocardial images (DIP-Tl) have been performed in 103 patients with atherosclerotic vascular disease who can't exercise fully. Of the 103 patients, there were 36 patients with arteriosclerosis obliterans (ASO), 31 patients with aneurysm of the abdominal aorta (AAA), 24 patients with aneurysm of the thoracic aorta (TAA) and 12 patients with dissecting aortic aneurysm (DAA). Clinical evidence of IHD was found in 20 patients with ASO, 10 with AAA, 7 with TAA and 4 with DAA. Positive evidence of DIP-Tl was identified in 66% of 41 patients who had clinical evidence of IHD, and particularly in the patients with AAA (80%) and ASO (65%). On the other hand, in the patients without clinical evidence of IHD, positive evidence of DIP-Tl was identified in 19% of 62 patients and particularly in the patients with AAA (39%). In all patients, the percentage of the positive DIP-Tl ratio was 38%. And, when the 38% patients of the positive DIP-Tl were added to the patients of the negative DIP-Tl who had clinical evidence of IHD, almost half patients (51%) were considered to be complicated with IHD. This study suggests that the atherosclerotic vascular disease is highly complicated with IHD and DIP-Tl is useful to detect IHD. (author)

  19. Significance of Tl-201 redistribution on infarcted region assessed by coronary sinus flow and lactate metabolism

    International Nuclear Information System (INIS)

    Mori, Takao; Yamabe, Hiroshi; Suda, Kenichirou; Ohnishi, Masataka; Shiotani, Hideyuki; Kurimoto, Yasuyuki; Kobayashi, Katsuya; Maeda, Kazumi; Fukuzaki, Hisashi

    1987-01-01

    To clarify the significance of Tl-201 redistribution on infarcted regions, coronary sinus and great cardiac vein flow response and lactate metabolism assessed by Webster catheter on 14 infarcted regions after dipyridamole administration were compared with Tl-201 redistribution phenomenon. The regional coronary flow response and lactate extraction ratio in 11 regions with Tl-201 redistribution were lower than those in 3 regions without Tl-201 redistribution. Only 5 regions in 11 with Tl-201 redistribution showed lactate production. The coronary flow response in 5 regions with lactate production was not different from those in 6 without lactate production (1.16 ± 0.89 vs. 1.47 ± 0.67; n.s.). The degree of Tl-201 redistribution assessed by relative activity was not different between regions with and without lactate production. The left ventricular end-diastolic pressure elevated in 5 regions with lactate production (17.8 ± 5.4 mmHg to 29.6 ± 4.9 mmHg; p < 0.05), but didn't in 6 regions without lactate production. Five regions with lactate production contained 4 hypokinetic regions, on the other hand 6 regions without lactate production contained only 3 hypokinetic regions. In conclusion, Tl-201 redistribution on infarcted region revealed not only ischemia but also decreased coronary flow response without lactate production and/or left ventricular dysfunction. (author)

  20. Estimating distribution parameters of annual maximum streamflows in Johor, Malaysia using TL-moments approach

    Science.gov (United States)

    Mat Jan, Nur Amalina; Shabri, Ani

    2017-01-01

    TL-moments approach has been used in an analysis to identify the best-fitting distributions to represent the annual series of maximum streamflow data over seven stations in Johor, Malaysia. The TL-moments with different trimming values are used to estimate the parameter of the selected distributions namely: Three-parameter lognormal (LN3) and Pearson Type III (P3) distribution. The main objective of this study is to derive the TL-moments ( t 1,0), t 1 = 1,2,3,4 methods for LN3 and P3 distributions. The performance of TL-moments ( t 1,0), t 1 = 1,2,3,4 was compared with L-moments through Monte Carlo simulation and streamflow data over a station in Johor, Malaysia. The absolute error is used to test the influence of TL-moments methods on estimated probability distribution functions. From the cases in this study, the results show that TL-moments with four trimmed smallest values from the conceptual sample (TL-moments [4, 0]) of LN3 distribution was the most appropriate in most of the stations of the annual maximum streamflow series in Johor, Malaysia.