WorldWideScience

Sample records for quantum efficiency

  1. Sorting quantum systems efficiently

    Science.gov (United States)

    Ionicioiu, Radu

    2016-05-01

    Measuring the state of a quantum system is a fundamental process in quantum mechanics and plays an essential role in quantum information and quantum technologies. One method to measure a quantum observable is to sort the system in different spatial modes according to the measured value, followed by single-particle detectors on each mode. Examples of quantum sorters are polarizing beam-splitters (PBS) – which direct photons according to their polarization – and Stern-Gerlach devices. Here we propose a general scheme to sort a quantum system according to the value of any d-dimensional degree of freedom, such as spin, orbital angular momentum (OAM), wavelength etc. Our scheme is universal, works at the single-particle level and has a theoretical efficiency of 100%. As an application we design an efficient OAM sorter consisting of a single multi-path interferometer which is suitable for a photonic chip implementation.

  2. Efficient quantum walk on a quantum processor

    Science.gov (United States)

    Qiang, Xiaogang; Loke, Thomas; Montanaro, Ashley; Aungskunsiri, Kanin; Zhou, Xiaoqi; O'Brien, Jeremy L.; Wang, Jingbo B.; Matthews, Jonathan C. F.

    2016-05-01

    The random walk formalism is used across a wide range of applications, from modelling share prices to predicting population genetics. Likewise, quantum walks have shown much potential as a framework for developing new quantum algorithms. Here we present explicit efficient quantum circuits for implementing continuous-time quantum walks on the circulant class of graphs. These circuits allow us to sample from the output probability distributions of quantum walks on circulant graphs efficiently. We also show that solving the same sampling problem for arbitrary circulant quantum circuits is intractable for a classical computer, assuming conjectures from computational complexity theory. This is a new link between continuous-time quantum walks and computational complexity theory and it indicates a family of tasks that could ultimately demonstrate quantum supremacy over classical computers. As a proof of principle, we experimentally implement the proposed quantum circuit on an example circulant graph using a two-qubit photonics quantum processor.

  3. Efficient quantum walk on a quantum processor.

    Science.gov (United States)

    Qiang, Xiaogang; Loke, Thomas; Montanaro, Ashley; Aungskunsiri, Kanin; Zhou, Xiaoqi; O'Brien, Jeremy L; Wang, Jingbo B; Matthews, Jonathan C F

    2016-05-05

    The random walk formalism is used across a wide range of applications, from modelling share prices to predicting population genetics. Likewise, quantum walks have shown much potential as a framework for developing new quantum algorithms. Here we present explicit efficient quantum circuits for implementing continuous-time quantum walks on the circulant class of graphs. These circuits allow us to sample from the output probability distributions of quantum walks on circulant graphs efficiently. We also show that solving the same sampling problem for arbitrary circulant quantum circuits is intractable for a classical computer, assuming conjectures from computational complexity theory. This is a new link between continuous-time quantum walks and computational complexity theory and it indicates a family of tasks that could ultimately demonstrate quantum supremacy over classical computers. As a proof of principle, we experimentally implement the proposed quantum circuit on an example circulant graph using a two-qubit photonics quantum processor.

  4. Efficient quantum walk on a quantum processor

    OpenAIRE

    Qiang, Xiaogang; Loke, Thomas; Montanaro, Ashley; Aungskunsiri, Kanin; Zhou, Xiao-Qi; O'Brien, Jeremy; Wang, Jingbo; Matthews, Jonathan

    2016-01-01

    The random walk formalism is used across a wide range of applications, from modelling share prices to predicting population genetics. Likewise quantum walks have shown much potential as a frame- work for developing new quantum algorithms. In this paper, we present explicit efficient quantum circuits for implementing continuous-time quantum walks on the circulant class of graphs. These circuits allow us to sample from the output probability distributions of quantum walks on circulant graphs ef...

  5. Efficient Quantum Key Distribution

    CERN Document Server

    Ardehali, M; Chau, H F; Lo, H K

    1998-01-01

    We devise a simple modification that essentially doubles the efficiency of a well-known quantum key distribution scheme proposed by Bennett and Brassard (BB84). Our scheme assigns significantly different probabilities for the different polarization bases during both transmission and reception to reduce the fraction of discarded data. The actual probabilities used in the scheme are announced in public. As the number of transmitted signals increases, the efficiency of our scheme can be made to approach 100%. The security of our scheme (against single-photon eavesdropping strategies) is guaranteed by a refined analysis of accepted data which is employed to detect eavesdropping: Instead of lumping all the accepted data together to estimate a single error rate, we separate the accepted data into various subsets according to the basis employed and estimate an error rate for each subset individually. Our scheme is the first quantum key distribution with an efficiency greater than 50%. We remark that our idea is rath...

  6. Efficient Quantum Pseudorandomness

    Science.gov (United States)

    Brandão, Fernando G. S. L.; Harrow, Aram W.; Horodecki, Michał

    2016-04-01

    Randomness is both a useful way to model natural systems and a useful tool for engineered systems, e.g., in computation, communication, and control. Fully random transformations require exponential time for either classical or quantum systems, but in many cases pseudorandom operations can emulate certain properties of truly random ones. Indeed, in the classical realm there is by now a well-developed theory regarding such pseudorandom operations. However, the construction of such objects turns out to be much harder in the quantum case. Here, we show that random quantum unitary time evolutions ("circuits") are a powerful source of quantum pseudorandomness. This gives for the first time a polynomial-time construction of quantum unitary designs, which can replace fully random operations in most applications, and shows that generic quantum dynamics cannot be distinguished from truly random processes. We discuss applications of our result to quantum information science, cryptography, and understanding the self-equilibration of closed quantum dynamics.

  7. Efficient Quantum Pseudorandomness.

    Science.gov (United States)

    Brandão, Fernando G S L; Harrow, Aram W; Horodecki, Michał

    2016-04-29

    Randomness is both a useful way to model natural systems and a useful tool for engineered systems, e.g., in computation, communication, and control. Fully random transformations require exponential time for either classical or quantum systems, but in many cases pseudorandom operations can emulate certain properties of truly random ones. Indeed, in the classical realm there is by now a well-developed theory regarding such pseudorandom operations. However, the construction of such objects turns out to be much harder in the quantum case. Here, we show that random quantum unitary time evolutions ("circuits") are a powerful source of quantum pseudorandomness. This gives for the first time a polynomial-time construction of quantum unitary designs, which can replace fully random operations in most applications, and shows that generic quantum dynamics cannot be distinguished from truly random processes. We discuss applications of our result to quantum information science, cryptography, and understanding the self-equilibration of closed quantum dynamics.

  8. Reconstructing quantum states efficiently

    OpenAIRE

    Cramer, M; Plenio, M. B.

    2010-01-01

    Quantum state tomography, the ability to deduce the density matrix of a quantum system from measured data, is of fundamental importance for the verification of present and future quantum devices. It has been realized in systems with few components but for larger systems it becomes rapidly infeasible because the number of quantum measurements and computational resources required to process them grow exponentially in the system size. Here we show that we can gain an exponential advantage over d...

  9. Quantum-enhanced Sensing and Efficient Quantum Computation

    Science.gov (United States)

    2015-07-27

    Quantum -enhanced sensing and efficient quantum computation Ian Walmsley THE UNIVERSITY OF...COVERED (From - To) 1 February 2013 - 31 January 2015 4. TITLE AND SUBTITLE Quantum -enhanced sensing and efficient quantum computation 5a. CONTRACT...1895616013 Standard Form 298 (Rev. 8/98) Prescribed by ANSI Std. Z39.18 Final report for “ Quantum ‐Enhanced Sensing and Efficient  Quantum   Computation

  10. Quantum computing: Efficient fault tolerance

    Science.gov (United States)

    Gottesman, Daniel

    2016-12-01

    Dealing with errors in a quantum computer typically requires complex programming and many additional quantum bits. A technique for controlling errors has been proposed that alleviates both of these problems.

  11. Efficient entanglement distillation without quantum memory

    Science.gov (United States)

    Abdelkhalek, Daniela; Syllwasschy, Mareike; Cerf, Nicolas J.; Fiurášek, Jaromír; Schnabel, Roman

    2016-01-01

    Entanglement distribution between distant parties is an essential component to most quantum communication protocols. Unfortunately, decoherence effects such as phase noise in optical fibres are known to demolish entanglement. Iterative (multistep) entanglement distillation protocols have long been proposed to overcome decoherence, but their probabilistic nature makes them inefficient since the success probability decays exponentially with the number of steps. Quantum memories have been contemplated to make entanglement distillation practical, but suitable quantum memories are not realised to date. Here, we present the theory for an efficient iterative entanglement distillation protocol without quantum memories and provide a proof-of-principle experimental demonstration. The scheme is applied to phase-diffused two-mode-squeezed states and proven to distil entanglement for up to three iteration steps. The data are indistinguishable from those that an efficient scheme using quantum memories would produce. Since our protocol includes the final measurement it is particularly promising for enhancing continuous-variable quantum key distribution. PMID:27241946

  12. Efficient entanglement distillation without quantum memory

    Science.gov (United States)

    Abdelkhalek, Daniela; Syllwasschy, Mareike; Cerf, Nicolas J.; Fiurášek, Jaromír; Schnabel, Roman

    2016-05-01

    Entanglement distribution between distant parties is an essential component to most quantum communication protocols. Unfortunately, decoherence effects such as phase noise in optical fibres are known to demolish entanglement. Iterative (multistep) entanglement distillation protocols have long been proposed to overcome decoherence, but their probabilistic nature makes them inefficient since the success probability decays exponentially with the number of steps. Quantum memories have been contemplated to make entanglement distillation practical, but suitable quantum memories are not realised to date. Here, we present the theory for an efficient iterative entanglement distillation protocol without quantum memories and provide a proof-of-principle experimental demonstration. The scheme is applied to phase-diffused two-mode-squeezed states and proven to distil entanglement for up to three iteration steps. The data are indistinguishable from those that an efficient scheme using quantum memories would produce. Since our protocol includes the final measurement it is particularly promising for enhancing continuous-variable quantum key distribution.

  13. Efficient entanglement distillation without quantum memory.

    Science.gov (United States)

    Abdelkhalek, Daniela; Syllwasschy, Mareike; Cerf, Nicolas J; Fiurášek, Jaromír; Schnabel, Roman

    2016-05-31

    Entanglement distribution between distant parties is an essential component to most quantum communication protocols. Unfortunately, decoherence effects such as phase noise in optical fibres are known to demolish entanglement. Iterative (multistep) entanglement distillation protocols have long been proposed to overcome decoherence, but their probabilistic nature makes them inefficient since the success probability decays exponentially with the number of steps. Quantum memories have been contemplated to make entanglement distillation practical, but suitable quantum memories are not realised to date. Here, we present the theory for an efficient iterative entanglement distillation protocol without quantum memories and provide a proof-of-principle experimental demonstration. The scheme is applied to phase-diffused two-mode-squeezed states and proven to distil entanglement for up to three iteration steps. The data are indistinguishable from those that an efficient scheme using quantum memories would produce. Since our protocol includes the final measurement it is particularly promising for enhancing continuous-variable quantum key distribution.

  14. Efficient Quantum Secure Direct Communication with Authentication

    Institute of Scientific and Technical Information of China (English)

    LIU Wen-Jie; CHEN Han-Wu; LI Zhi-Qiang; LIU Zhi-Hao

    2008-01-01

    Two protocols of quantum direct communication with authentication [Phys. Rev. A 73 (2006) 042305] were recently indicated to be insecure against the authenticator Trent attacks [Phys. Rev. A 75 (2007) 026301]. We present two efficient protocols by using four Pauli operations, which are secure against inner Trent attacks as well as outer Eve attacks. Finally, we generalize them to multiparty quantum direction communication.

  15. Energy-efficient quantum computing

    Science.gov (United States)

    Ikonen, Joni; Salmilehto, Juha; Möttönen, Mikko

    2017-04-01

    In the near future, one of the major challenges in the realization of large-scale quantum computers operating at low temperatures is the management of harmful heat loads owing to thermal conduction of cabling and dissipation at cryogenic components. This naturally raises the question that what are the fundamental limitations of energy consumption in scalable quantum computing. In this work, we derive the greatest lower bound for the gate error induced by a single application of a bosonic drive mode of given energy. Previously, such an error type has been considered to be inversely proportional to the total driving power, but we show that this limitation can be circumvented by introducing a qubit driving scheme which reuses and corrects drive pulses. Specifically, our method serves to reduce the average energy consumption per gate operation without increasing the average gate error. Thus our work shows that precise, scalable control of quantum systems can, in principle, be implemented without the introduction of excessive heat or decoherence.

  16. Resource-efficient linear optical quantum computation.

    Science.gov (United States)

    Browne, Daniel E; Rudolph, Terry

    2005-07-01

    We introduce a scheme for linear optics quantum computation, that makes no use of teleported gates, and requires stable interferometry over only the coherence length of the photons. We achieve a much greater degree of efficiency and a simpler implementation than previous proposals. We follow the "cluster state" measurement based quantum computational approach, and show how cluster states may be efficiently generated from pairs of maximally polarization entangled photons using linear optical elements. We demonstrate the universality and usefulness of generic parity measurements, as well as introducing the use of redundant encoding of qubits to enable utilization of destructive measurements--both features of use in a more general context.

  17. Quantum Dot Spectrum Converters for Enhanced High Efficiency Photovoltaics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This research proposes to enhance solar cell efficiency, radiation resistance and affordability. The Quantum Dot Spectrum Converter (QDSC) disperses quantum dots...

  18. Delocalized Quantum States Enhance Photocell Efficiency

    CERN Document Server

    Zhang, Yiteng; Alharbi, Fahhad H; Engel, Greg; Kais, Sabre

    2014-01-01

    The high quantum efficiency of photosynthetic complexes has inspired researchers to explore new routes to utilize this process for photovoltaic devices. Quantum coherence has been demonstrated to play a crucial role within this process. Herein, we propose a three-dipole system as a model of a new photocell type which exploits the coherence among its three dipoles. We have proved that the efficiency of such a photocell is greatly enhanced by quantum coherence. We have also predicted that the photocurrents can be enhanced by about 49.5 % in such a coherent coupled dipole system compared with the uncoupled dipoles. These results suggest a promising novel design aspect of photosynthesis-mimicking photovoltaic devices.

  19. Efficient quantum circuits for one-way quantum computing.

    Science.gov (United States)

    Tanamoto, Tetsufumi; Liu, Yu-Xi; Hu, Xuedong; Nori, Franco

    2009-03-13

    While Ising-type interactions are ideal for implementing controlled phase flip gates in one-way quantum computing, natural interactions between solid-state qubits are most often described by either the XY or the Heisenberg models. We show an efficient way of generating cluster states directly using either the imaginary SWAP (iSWAP) gate for the XY model, or the sqrt[SWAP] gate for the Heisenberg model. Our approach thus makes one-way quantum computing more feasible for solid-state devices.

  20. Improving quantum sensing efficiency with virtual modes

    Science.gov (United States)

    Lanzagorta, Marco; Uhlmann, Jeffrey; Le, Truc; Jitrik, Oliverio; Venegas-Andraca, Salvador E.

    2016-05-01

    Recent research suggests that quantum radar offers several potential advantages over classical sensing technologies. At present, the primary practical challenge is the fast and efficient generation of entangled microwave photons. To mitigate this limitation we propose and briefly examine a distributed architecture to synthetically increase the number of effectively-distinguishable modes.

  1. High efficiency quantum cascade laser frequency comb

    Science.gov (United States)

    Lu, Quanyong; Wu, Donghai; Slivken, Steven; Razeghi, Manijeh

    2017-03-01

    An efficient mid-infrared frequency comb source is of great interest to high speed, high resolution spectroscopy and metrology. Here we demonstrate a mid-IR quantum cascade laser frequency comb with a high power output and narrow beatnote linewidth at room temperature. The active region was designed with a strong-coupling between the injector and the upper lasing level for high internal quantum efficiency and a broadband gain. The group velocity dispersion was engineered for efficient, broadband mode-locking via four wave mixing. The comb device exhibits a narrow intermode beatnote linewidth of 50.5 Hz and a maximum wall-plug efficiency of 6.5% covering a spectral coverage of 110 cm‑1 at λ ~ 8 μm. The efficiency is improved by a factor of 6 compared with previous demonstrations. The high power efficiency and narrow beatnote linewidth will greatly expand the applications of quantum cascade laser frequency combs including high-precision remote sensing and spectroscopy.

  2. High efficiency quantum cascade laser frequency comb

    Science.gov (United States)

    Lu, Quanyong; Wu, Donghai; Slivken, Steven; Razeghi, Manijeh

    2017-01-01

    An efficient mid-infrared frequency comb source is of great interest to high speed, high resolution spectroscopy and metrology. Here we demonstrate a mid-IR quantum cascade laser frequency comb with a high power output and narrow beatnote linewidth at room temperature. The active region was designed with a strong-coupling between the injector and the upper lasing level for high internal quantum efficiency and a broadband gain. The group velocity dispersion was engineered for efficient, broadband mode-locking via four wave mixing. The comb device exhibits a narrow intermode beatnote linewidth of 50.5 Hz and a maximum wall-plug efficiency of 6.5% covering a spectral coverage of 110 cm−1 at λ ~ 8 μm. The efficiency is improved by a factor of 6 compared with previous demonstrations. The high power efficiency and narrow beatnote linewidth will greatly expand the applications of quantum cascade laser frequency combs including high-precision remote sensing and spectroscopy. PMID:28262834

  3. Efficient quantum computing using coherent photon conversion.

    Science.gov (United States)

    Langford, N K; Ramelow, S; Prevedel, R; Munro, W J; Milburn, G J; Zeilinger, A

    2011-10-12

    Single photons are excellent quantum information carriers: they were used in the earliest demonstrations of entanglement and in the production of the highest-quality entanglement reported so far. However, current schemes for preparing, processing and measuring them are inefficient. For example, down-conversion provides heralded, but randomly timed, single photons, and linear optics gates are inherently probabilistic. Here we introduce a deterministic process--coherent photon conversion (CPC)--that provides a new way to generate and process complex, multiquanta states for photonic quantum information applications. The technique uses classically pumped nonlinearities to induce coherent oscillations between orthogonal states of multiple quantum excitations. One example of CPC, based on a pumped four-wave-mixing interaction, is shown to yield a single, versatile process that provides a full set of photonic quantum processing tools. This set satisfies the DiVincenzo criteria for a scalable quantum computing architecture, including deterministic multiqubit entanglement gates (based on a novel form of photon-photon interaction), high-quality heralded single- and multiphoton states free from higher-order imperfections, and robust, high-efficiency detection. It can also be used to produce heralded multiphoton entanglement, create optically switchable quantum circuits and implement an improved form of down-conversion with reduced higher-order effects. Such tools are valuable building blocks for many quantum-enabled technologies. Finally, using photonic crystal fibres we experimentally demonstrate quantum correlations arising from a four-colour nonlinear process suitable for CPC and use these measurements to study the feasibility of reaching the deterministic regime with current technology. Our scheme, which is based on interacting bosonic fields, is not restricted to optical systems but could also be implemented in optomechanical, electromechanical and superconducting

  4. Quantum Otto cycle efficiency on coupled qudits

    Science.gov (United States)

    Ivanchenko, E. A.

    2015-09-01

    Properties of the coupled particles with spin 3/2 (quartits) in a constant magnetic field, as a working substance in the quantum Otto cycle of the heat engine, are considered. It is shown that this system as a converter of heat energy in work (i) shows the efficiency 1 at the negative absolute temperatures of heat baths, (ii) at the temperatures of the opposite sign the efficiency approaches 1, (iii) at the positive temperatures of heat baths antiferromagnetic interaction raises efficiency threefold in comparison with uncoupled particles.

  5. Internal quantum efficiency modeling of silicon photodiodes.

    Science.gov (United States)

    Gentile, T R; Brown, S W; Lykke, K R; Shaw, P S; Woodward, J T

    2010-04-01

    Results are presented for modeling of the shape of the internal quantum efficiency (IQE) versus wavelength for silicon photodiodes in the 400 nm to 900 nm wavelength range. The IQE data are based on measurements of the external quantum efficiencies of three transmission optical trap detectors using an extensive set of laser wavelengths, along with the transmittance of the traps. We find that a simplified version of a previously reported IQE model fits the data with an accuracy of better than 0.01%. These results provide an important validation of the National Institute of Standards and Technology (NIST) spectral radiant power responsivity scale disseminated through the NIST Spectral Comparator Facility, as well as those scales disseminated by other National Metrology Institutes who have employed the same model.

  6. Quantum Confined Semiconductors for High Efficiency Photovoltaics

    Science.gov (United States)

    Beard, Matthew

    2014-03-01

    Semiconductor nanostructures, where at least one dimension is small enough to produce quantum confinement effects, provide new pathways for controlling energy flow and therefore have the potential to increase the efficiency of the primary photon-to-free energy conversion step. In this discussion, I will present the current status of research efforts towards utilizing the unique properties of colloidal quantum dots (NCs confined in three dimensions) in prototype solar cells and demonstrate that these unique systems have the potential to bypass the Shockley-Queisser single-junction limit for solar photon conversion. The solar cells are constructed using a low temperature solution based deposition of PbS or PbSe QDs as the absorber layer. Different chemical treatments of the QD layer are employed in order to obtain good electrical communication while maintaining the quantum-confined properties of the QDs. We have characterized the transport and carrier dynamics using a transient absorption, time-resolved THz, and temperature-dependent photoluminescence. I will discuss the interplay between carrier generation, recombination, and mobility within the QD layers. A unique aspect of our devices is that the QDs exhibit multiple exciton generation with an efficiency that is ~ 2 to 3 times greater than the parental bulk semiconductor.

  7. Quantum wells for high-efficiency photovoltaics

    Science.gov (United States)

    Alonso-Álvarez, Diego; Ekins-Daukes, Nicholas

    2016-03-01

    Over the last couple of decades, there has been an intense research on strain balanced semiconductor quantum wells (QW) to increase the efficiency of multi-junction solar (MJ) solar cells grown monolithically on germanium. So far, the most successful application of QWs have required just to tailor a few tens of nanometers the absorption edge of a given subcell in order to reach the optimum spectral position. However, the demand for higher efficiency devices requiring 3, 4 or more junctions, represents a major difference in the challenges QWs must face: tailoring the absorption edge of a host material is not enough, but a complete new device, absorbing light in a different spectral region, must be designed. Among the most important issues to solve is the need for an optically thick structure to absorb enough light while keeping excellent carrier extraction using highly strained materials. Improvement of the growth techniques, smarter device designs - involving superlattices and shifted QWs, for example - or the use of quantum wires rather than QWs, have proven to be very effective steps towards high efficient MJ solar cells based on nanostructures in the last couple of years. But more is to be done to reach the target performances. This work discusses all these challenges, the limitations they represent and the different approaches that are being used to overcome them.

  8. Duality quantum algorithm efficiently simulates open quantum systems

    OpenAIRE

    Shi-Jie Wei; Dong Ruan; Gui-Lu Long

    2016-01-01

    Because of inevitable coupling with the environment, nearly all practical quantum systems are open system, where the evolution is not necessarily unitary. In this paper, we propose a duality quantum algorithm for simulating Hamiltonian evolution of an open quantum system. In contrast to unitary evolution in a usual quantum computer, the evolution operator in a duality quantum computer is a linear combination of unitary operators. In this duality quantum algorithm, the time evolution of the op...

  9. Efficient entanglement purification in quantum repeaters

    Institute of Scientific and Technical Information of China (English)

    Sheng Yu-Bo; Zhou Lan; Cheng Wei-Wen; Gong Long-Yan; Zhao Sheng-Mei; Zheng Bao-Yu

    2012-01-01

    We present an efficient entanglement purification protocol (EPP) with controlled-not (CNOT) gates and linear optics.With the CNOT gates,our EPP can reach a higher fidelity than the conventional one.Moreover,it does not require the fidelity of the initial mixed state to satisfy · · 1· 2.If the initial state is not entangled,it still can be purified.With the linear optics,this protocol can get pure maximally entangled pairs with some probabilities.Meanwhile,it can be used to purify the entanglement between the atomic ensembles in distant locations.This protocol may be useful in long-distance quantum communication.

  10. Efficient Controlled Quantum Secure Direct Communication Protocols

    OpenAIRE

    Patwardhan, Siddharth; Moulick, Subhayan Roy; Prasanta K. Panigrahi

    2015-01-01

    We study controlled quantum secure direct communication (CQSDC), a cryptographic scheme where a sender can send a secret bit-string to an intended recipient, without any secure classical channel, who can obtain the complete bit-string only with the permission of a controller. We report an efficient protocol to realize CQSDC using Cluster state and then go on to construct a (2-3)-CQSDC using Brown state, where a coalition of any two of the three controllers is required to retrieve the complete...

  11. Efficient Controlled Quantum Secure Direct Communication Protocols

    Science.gov (United States)

    Patwardhan, Siddharth; Moulick, Subhayan Roy; Panigrahi, Prasanta K.

    2016-07-01

    We study controlled quantum secure direct communication (CQSDC), a cryptographic scheme where a sender can send a secret bit-string to an intended recipient, without any secure classical channel, who can obtain the complete bit-string only with the permission of a controller. We report an efficient protocol to realize CQSDC using Cluster state and then go on to construct a (2-3)-CQSDC using Brown state, where a coalition of any two of the three controllers is required to retrieve the complete message. We argue both protocols to be unconditionally secure and analyze the efficiency of the protocols to show it to outperform the existing schemes while maintaining the same security specifications.

  12. Duality quantum algorithm efficiently simulates open quantum systems.

    Science.gov (United States)

    Wei, Shi-Jie; Ruan, Dong; Long, Gui-Lu

    2016-07-28

    Because of inevitable coupling with the environment, nearly all practical quantum systems are open system, where the evolution is not necessarily unitary. In this paper, we propose a duality quantum algorithm for simulating Hamiltonian evolution of an open quantum system. In contrast to unitary evolution in a usual quantum computer, the evolution operator in a duality quantum computer is a linear combination of unitary operators. In this duality quantum algorithm, the time evolution of the open quantum system is realized by using Kraus operators which is naturally implemented in duality quantum computer. This duality quantum algorithm has two distinct advantages compared to existing quantum simulation algorithms with unitary evolution operations. Firstly, the query complexity of the algorithm is O(d(3)) in contrast to O(d(4)) in existing unitary simulation algorithm, where d is the dimension of the open quantum system. Secondly, By using a truncated Taylor series of the evolution operators, this duality quantum algorithm provides an exponential improvement in precision compared with previous unitary simulation algorithm.

  13. Duality quantum algorithm efficiently simulates open quantum systems

    Science.gov (United States)

    Wei, Shi-Jie; Ruan, Dong; Long, Gui-Lu

    2016-07-01

    Because of inevitable coupling with the environment, nearly all practical quantum systems are open system, where the evolution is not necessarily unitary. In this paper, we propose a duality quantum algorithm for simulating Hamiltonian evolution of an open quantum system. In contrast to unitary evolution in a usual quantum computer, the evolution operator in a duality quantum computer is a linear combination of unitary operators. In this duality quantum algorithm, the time evolution of the open quantum system is realized by using Kraus operators which is naturally implemented in duality quantum computer. This duality quantum algorithm has two distinct advantages compared to existing quantum simulation algorithms with unitary evolution operations. Firstly, the query complexity of the algorithm is O(d3) in contrast to O(d4) in existing unitary simulation algorithm, where d is the dimension of the open quantum system. Secondly, By using a truncated Taylor series of the evolution operators, this duality quantum algorithm provides an exponential improvement in precision compared with previous unitary simulation algorithm.

  14. An efficient quantum circuit analyser on qubits and qudits

    Science.gov (United States)

    Loke, T.; Wang, J. B.

    2011-10-01

    This paper presents a highly efficient decomposition scheme and its associated Mathematica notebook for the analysis of complicated quantum circuits comprised of single/multiple qubit and qudit quantum gates. In particular, this scheme reduces the evaluation of multiple unitary gate operations with many conditionals to just two matrix additions, regardless of the number of conditionals or gate dimensions. This improves significantly the capability of a quantum circuit analyser implemented in a classical computer. This is also the first efficient quantum circuit analyser to include qudit quantum logic gates.

  15. High Efficiency Colloidal Quantum Dot Phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Kahen, Keith

    2013-12-31

    The project showed that non-Cd containing, InP-based nanocrystals (semiconductor materials with dimensions of ~6 nm) have high potential for enabling next-generation, nanocrystal-based, on chip phosphors for solid state lighting. Typical nanocrystals fall short of the requirements for on chip phosphors due to their loss of quantum efficiency under the operating conditions of LEDs, such as, high temperature (up to 150 °C) and high optical flux (up to 200 W/cm2). The InP-based nanocrystals invented during this project maintain high quantum efficiency (>80%) in polymer-based films under these operating conditions for emission wavelengths ranging from ~530 to 620 nm. These nanocrystals also show other desirable attributes, such as, lack of blinking (a common problem with nanocrystals which limits their performance) and no increase in the emission spectral width from room to 150 °C (emitters with narrower spectral widths enable higher efficiency LEDs). Prior to these nanocrystals, no nanocrystal system (regardless of nanocrystal type) showed this collection of properties; in fact, other nanocrystal systems are typically limited to showing only one desirable trait (such as high temperature stability) but being deficient in other properties (such as high flux stability). The project showed that one can reproducibly obtain these properties by generating a novel compositional structure inside of the nanomaterials; in addition, the project formulated an initial theoretical framework linking the compositional structure to the list of high performance optical properties. Over the course of the project, the synthetic methodology for producing the novel composition was evolved to enable the synthesis of these nanomaterials at a cost approximately equal to that required for forming typical conventional nanocrystals. Given the above results, the last major remaining step prior to scale up of the nanomaterials is to limit the oxidation of these materials during the tens of

  16. Detective quantum efficiency of the LODOX system

    Science.gov (United States)

    de Villiers, Mattieu; de Jager, Gerhard

    2003-06-01

    The Detective Quantum Efficiency (DQE) of a digital x-ray imaging system describes how much of the signal to noise ratio of the incident radiation is sustained in the resultant digital image. This measure of dose efficiency is suitable for the comparison of detectors produced by different manufacturers. The International Electrotechnical Commission (IEC) stipulates standard methods and conditions for the measurement of the DQE for single exposure imaging systems such as flat panel detectors. This paper shows how the calculation is adapted for DQE measurements of scanning systems. In this paper it is described how to measure the presampled Modulation Transfer Function (MTF) using an edge test method and how to extract the horizontal and vertical components of the Noise Power Spectrum (NPS) in a way that is insensitive to structured noise patterns often found in scanned images. The calculation of the total number of incident photons from the radiation dose measurement is explained and results are provided for the Lodox low dose full body digital x-ray scanning system which is developed in South Africa.

  17. The detective quantum efficiency of an imaging detector

    Energy Technology Data Exchange (ETDEWEB)

    Zanella, G. [Padova Univ. (Italy). Dipartimento di Fisica and INFN; Zannoni, R. [Padova Univ. (Italy). Dipartimento di Fisica and INFN

    1995-05-15

    The efficiency of an imaging detector is a more extensive parameter than the quantum efficiency of a track detector or of a counter, as an image is created by the summation of many responses due to the single incoming quanta. This efficiency parameter is the so-called detective quantum efficiency (DQE). The paper illustrates the general meaning of DQE and the procedure to measure it. (orig.).

  18. Absolute measurement of detector quantum efficiency using parametric downconversion.

    Science.gov (United States)

    Rarity, J G; Ridley, K D; Tapster, P R

    1987-11-01

    We show that a parametric downconversion crystal emitting angle resolved coincident photon pairs can be used to measure the absolute quantum efficiency of a photon counting detection system. We have measured the quantum efficiency of a silicon avalanche photodiode, operated in Geiger mode, as a function of operating voltage and compare this to results obtained using a conventional method.

  19. Efficient Scheme for Optimizing Quantum Fourier Circuits

    Institute of Scientific and Technical Information of China (English)

    JIANG Min; ZHANG Zengke; Tzyh-Jong Tarn

    2008-01-01

    In quantum circuits, importing of additional qubits can reduce the operation time and prevent de-coherence induced by the environment. However, excessive qubits may make the quantum system vulner-able. This paper describes how to relax existing qubits without additional qubits to significantly reduce the operation time of the quantum Fourier circuit compared to a circuit without optimization. The results indicate that this scheme makes full use of the qubits relaxation. The concepts can be applied to improve similar quantum circuits and guide the physical implementations of quantum algorithms or devices.

  20. Efficient quantum transmission in multiple-source networks.

    Science.gov (United States)

    Luo, Ming-Xing; Xu, Gang; Chen, Xiu-Bo; Yang, Yi-Xian; Wang, Xiaojun

    2014-04-02

    A difficult problem in quantum network communications is how to efficiently transmit quantum information over large-scale networks with common channels. We propose a solution by developing a quantum encoding approach. Different quantum states are encoded into a coherent superposition state using quantum linear optics. The transmission congestion in the common channel may be avoided by transmitting the superposition state. For further decoding and continued transmission, special phase transformations are applied to incoming quantum states using phase shifters such that decoders can distinguish outgoing quantum states. These phase shifters may be precisely controlled using classical chaos synchronization via additional classical channels. Based on this design and the reduction of multiple-source network under the assumption of restricted maximum-flow, the optimal scheme is proposed for specially quantized multiple-source network. In comparison with previous schemes, our scheme can greatly increase the transmission efficiency.

  1. Quantum efficiency and oscillator strength of site-controlled InGaAs quantum dots

    DEFF Research Database (Denmark)

    Albert, F.; Schneider, C.; Stobbe, Søren

    2010-01-01

    We report on time-resolved photoluminescence spectroscopy to determine the oscillator strength (OS) and the quantum efficiency (QE) of site-controlled In(Ga)As quantum dots nucleating on patterned nanoholes. These two quantities are determined by measurements on site-controlled quantum dot (SCQD.......1±2.6 and an encouragingly high QE of (48±14)% for the SCQDs....

  2. Quantum efficiency and oscillator strength of site-controlled InGaAs quantum dots

    DEFF Research Database (Denmark)

    Albert, F.; Schneider, C.; Stobbe, Søren;

    2010-01-01

    We report on time-resolved photoluminescence spectroscopy to determine the oscillator strength (OS) and the quantum efficiency (QE) of site-controlled In(Ga)As quantum dots nucleating on patterned nanoholes. These two quantities are determined by measurements on site-controlled quantum dot (SCQD...

  3. Quantum enhanced estimation of optical detector efficiencies

    Directory of Open Access Journals (Sweden)

    Barbieri Marco

    2016-01-01

    Full Text Available Quantum mechanics establishes the ultimate limit to the scaling of the precision on any parameter, by identifying optimal probe states and measurements. While this paradigm is, at least in principle, adequate for the metrology of quantum channels involving the estimation of phase and loss parameters, we show that estimating the loss parameters associated with a quantum channel and a realistic quantum detector are fundamentally different. While Fock states are provably optimal for the former, we identify a crossover in the nature of the optimal probe state for estimating detector imperfections as a function of the loss parameter using Fisher information as a benchmark. We provide theoretical results for on-off and homodyne detectors, the most widely used detectors in quantum photonics technologies, when using Fock states and coherent states as probes.

  4. Efficient quantum secure communication with a publicly known key

    Institute of Scientific and Technical Information of China (English)

    Li Chun-Yan; Li Xi-Han; Deng Fu-Guo; Zhou Hong-Yu

    2008-01-01

    This paper presents a simple way for an eavesdropper to eavesdrop freely the secret message in the experimental realization of quantum communication protocol proposed by Beige et al (2002 Acta Phys. Pol. A 101 357). Moreover, it introduces an efficient quantum secure communication protocol based on a publicly known key with decoy photons and two biased bases by modifying the original protocol. The total efficiency of this new protocol is double that of the original one. With a low noise quantum channel, this protocol can be used for transmitting a secret message. At present, this protocol is good for generating a private key efficiently.

  5. Quantum Cost Efficient Reversible BCD Adder for Nanotechnology Based Systems

    CERN Document Server

    Islam, Md Saiful; Begum, Zerina

    2011-01-01

    Reversible logic allows low power dissipating circuit design and founds its application in cryptography, digital signal processing, quantum and optical information processing. This paper presents a novel quantum cost efficient reversible BCD adder for nanotechnology based systems using PFAG gate. It has been demonstrated that the proposed design offers less hardware complexity and requires minimum number of garbage outputs than the existing counterparts. The remarkable property of the proposed designs is that its quantum realization is given in NMR technology.

  6. Highly efficient frequency conversion with bandwidth compression of quantum light

    Science.gov (United States)

    Allgaier, Markus; Ansari, Vahid; Sansoni, Linda; Eigner, Christof; Quiring, Viktor; Ricken, Raimund; Harder, Georg; Brecht, Benjamin; Silberhorn, Christine

    2017-01-01

    Hybrid quantum networks rely on efficient interfacing of dissimilar quantum nodes, as elements based on parametric downconversion sources, quantum dots, colour centres or atoms are fundamentally different in their frequencies and bandwidths. Although pulse manipulation has been demonstrated in very different systems, to date no interface exists that provides both an efficient bandwidth compression and a substantial frequency translation at the same time. Here we demonstrate an engineered sum-frequency-conversion process in lithium niobate that achieves both goals. We convert pure photons at telecom wavelengths to the visible range while compressing the bandwidth by a factor of 7.47 under preservation of non-classical photon-number statistics. We achieve internal conversion efficiencies of 61.5%, significantly outperforming spectral filtering for bandwidth compression. Our system thus makes the connection between previously incompatible quantum systems as a step towards usable quantum networks. PMID:28134242

  7. Highly efficient frequency conversion with bandwidth compression of quantum light

    Science.gov (United States)

    Allgaier, Markus; Ansari, Vahid; Sansoni, Linda; Eigner, Christof; Quiring, Viktor; Ricken, Raimund; Harder, Georg; Brecht, Benjamin; Silberhorn, Christine

    2017-01-01

    Hybrid quantum networks rely on efficient interfacing of dissimilar quantum nodes, as elements based on parametric downconversion sources, quantum dots, colour centres or atoms are fundamentally different in their frequencies and bandwidths. Although pulse manipulation has been demonstrated in very different systems, to date no interface exists that provides both an efficient bandwidth compression and a substantial frequency translation at the same time. Here we demonstrate an engineered sum-frequency-conversion process in lithium niobate that achieves both goals. We convert pure photons at telecom wavelengths to the visible range while compressing the bandwidth by a factor of 7.47 under preservation of non-classical photon-number statistics. We achieve internal conversion efficiencies of 61.5%, significantly outperforming spectral filtering for bandwidth compression. Our system thus makes the connection between previously incompatible quantum systems as a step towards usable quantum networks.

  8. Highly efficient frequency conversion with bandwidth compression of quantum light

    CERN Document Server

    Allgaier, Markus; Sansoni, Linda; Quiring, Viktor; Ricken, Raimund; Harder, Georg; Brecht, Benjamin; Silberhorn, Christine

    2016-01-01

    Hybrid quantum networks rely on efficient interfacing of dissimilar quantum nodes, since elements based on parametric down-conversion sources, quantum dots, color centres or atoms are fundamentally different in their frequencies and bandwidths. While pulse manipulation has been demonstrated in very different systems, to date no interface exists that provides both an efficient bandwidth compression and a substantial frequency translation at the same time. Here, we demonstrate an engineered sum-frequency-conversion process in Lithium Niobate that achieves both goals. We convert pure photons at telecom wavelengths to the visible range while compressing the bandwidth by a factor of 7.47 under preservation of non-classical photon-number statistics. We achieve internal conversion efficiencies of 75.5%, significantly outperforming spectral filtering for bandwidth compression. Our system thus makes the connection between previously incompatible quantum systems as a step towards usable quantum networks.

  9. Efficient self-consistent quantum transport simulator for quantum devices

    Energy Technology Data Exchange (ETDEWEB)

    Gao, X., E-mail: xngao@sandia.gov; Mamaluy, D.; Nielsen, E.; Young, R. W.; Lilly, M. P.; Bishop, N. C.; Carroll, M. S.; Muller, R. P. [Sandia National Laboratories, 1515 Eubank SE, Albuquerque, New Mexico 87123 (United States); Shirkhorshidian, A. [Sandia National Laboratories, 1515 Eubank SE, Albuquerque, New Mexico 87123 (United States); University of New Mexico, Albuquerque, New Mexico 87131 (United States)

    2014-04-07

    We present a self-consistent one-dimensional (1D) quantum transport simulator based on the Contact Block Reduction (CBR) method, aiming for very fast and robust transport simulation of 1D quantum devices. Applying the general CBR approach to 1D open systems results in a set of very simple equations that are derived and given in detail for the first time. The charge self-consistency of the coupled CBR-Poisson equations is achieved by using the predictor-corrector iteration scheme with the optional Anderson acceleration. In addition, we introduce a new way to convert an equilibrium electrostatic barrier potential calculated from an external simulator to an effective doping profile, which is then used by the CBR-Poisson code for transport simulation of the barrier under non-zero biases. The code has been applied to simulate the quantum transport in a double barrier structure and across a tunnel barrier in a silicon double quantum dot. Extremely fast self-consistent 1D simulations of the differential conductance across a tunnel barrier in the quantum dot show better qualitative agreement with experiment than non-self-consistent simulations.

  10. Wide-Band, High-Quantum-Efficiency Photodetector

    Science.gov (United States)

    Jackson, Deborah; Wilson, Daniel; Stern, Jeffrey

    2007-01-01

    A design has been proposed for a photodetector that would exhibit a high quantum efficiency (as much as 90 percent) over a wide wavelength band, which would typically be centered at a wavelength of 1.55 m. This and similar photodetectors would afford a capability for detecting single photons - a capability that is needed for research in quantum optics as well as for the practical development of secure optical communication systems for distribution of quantum cryptographic keys. The proposed photodetector would be of the hot-electron, phonon-cooled, thin-film superconductor type. The superconducting film in this device would be a meandering strip of niobium nitride. In the proposed photodetector, the quantum efficiency would be increased through incorporation of optiA design has been proposed for a photodetector that would exhibit a high quantum efficiency (as much as 90 percent) over a wide wavelength band, which would typically be centered at a wavelength of 1.55 m. This and similar photodetectors would afford a capability for detecting single photons - a capability that is needed for research in quantum optics as well as for the practical development of secure optical communication systems for distribution of quantum cryptographic keys. The proposed photodetector would be of the hot-electron, phonon-cooled, thin-film superconductor type. The superconducting film in this device would be a meandering strip of niobium nitride. In the proposed photodetector, the quantum efficiency would be increased through incorporation of opti-

  11. Efficient Measurement of Multiparticle Entanglement with Embedding Quantum Simulator.

    Science.gov (United States)

    Chen, Ming-Cheng; Wu, Dian; Su, Zu-En; Cai, Xin-Dong; Wang, Xi-Lin; Yang, Tao; Li, Li; Liu, Nai-Le; Lu, Chao-Yang; Pan, Jian-Wei

    2016-02-19

    The quantum measurement of entanglement is a demanding task in the field of quantum information. Here, we report the direct and scalable measurement of multiparticle entanglement with embedding photonic quantum simulators. In this embedding framework [R. Di Candia et al. Phys. Rev. Lett. 111, 240502 (2013)], the N-qubit entanglement, which does not associate with a physical observable directly, can be efficiently measured with only two (for even N) and six (for odd N) local measurement settings. Our experiment uses multiphoton quantum simulators to mimic dynamical concurrence and three-tangle entangled systems and to track their entanglement evolutions.

  12. Efficient quantum circuits for dense circulant and circulant like operators

    Science.gov (United States)

    Zhou, S. S.; Wang, J. B.

    2017-05-01

    Circulant matrices are an important family of operators, which have a wide range of applications in science and engineering-related fields. They are, in general, non-sparse and non-unitary. In this paper, we present efficient quantum circuits to implement circulant operators using fewer resources and with lower complexity than existing methods. Moreover, our quantum circuits can be readily extended to the implementation of Toeplitz, Hankel and block circulant matrices. Efficient quantum algorithms to implement the inverses and products of circulant operators are also provided, and an example application in solving the equation of motion for cyclic systems is discussed.

  13. A fully efficient secure quantum cryptography protocol

    CERN Document Server

    Xiang Bin Wang

    2001-01-01

    Since Bennett and Brassard suggested their quantum key distribution protocol(BB84 protocol) in 1984, the subject has been extensively studied both theoretically and experimentally. The protocol allows two remote parties Alice and Bob to create and share a secret key using a quantum channel and public authenticated communications. The quantum key created in this way is in principle secure because eavesdroppers have no way to tap the quantum channel without disturb it. In the protocol, two level quantum bits are measured in two basis, $X$ and $Z$ randomly by Bob. So at least half of the measurement results will be discarded because Bob has a half probability taking the measurement in a wrong basis. On the other hand, the security is not the maximum in BB84 protocol. To increase the security, one may straightforwardly increase the number of basis used in the protocol. For example, six state protocol was proposed recently for two level system. However, in this way, it seems to be the case that the higher the secu...

  14. Efficient Luminescence from Perovskite Quantum Dot Solids

    KAUST Repository

    Kim, Younghoon

    2015-11-18

    © 2015 American Chemical Society. Nanocrystals of CsPbX3 perovskites are promising materials for light-emitting optoelectronics because of their colloidal stability, optically tunable bandgap, bright photoluminescence, and excellent photoluminescence quantum yield. Despite their promise, nanocrystal-only films of CsPbX3 perovskites have not yet been fabricated; instead, highly insulating polymers have been relied upon to compensate for nanocrystals\\' unstable surfaces. We develop solution chemistry that enables single-step casting of perovskite nanocrystal films and overcomes problems in both perovskite quantum dot purification and film fabrication. Centrifugally cast films retain bright photoluminescence and achieve dense and homogeneous morphologies. The new materials offer a platform for optoelectronic applications of perovskite quantum dot solids.

  15. Quantum transport efficiency and Fourier's law.

    Science.gov (United States)

    Manzano, Daniel; Tiersch, Markus; Asadian, Ali; Briegel, Hans J

    2012-12-01

    We analyze the steady-state energy transfer in a chain of coupled two-level systems connecting two thermal reservoirs. Through an analytic treatment we find that the energy current is independent of the system size, hence violating Fourier's law of heat conduction. The classical diffusive behavior in Fourier's law of heat conduction can be recovered by introducing decoherence to the quantum systems constituting the chain. We relate these results to recent discussions of energy transport in biological light-harvesting systems, and discuss the role of quantum coherence and entanglement.

  16. Quantum transport efficiency and Fourier's law

    CERN Document Server

    Manzano, Daniel; Asadian, Ali; Briegel, Hans J

    2011-01-01

    We analyze the steady-state energy transfer in a chain of coupled two-level systems connecting two thermal reservoirs. Through an analytic treatment we find that the energy current is independent of the system size, hence violating Fourier's law of heat conduction. The classical diffusive behavior in Fourier's law of heat conduction can be recovered by introducing decoherence to the quantum systems constituting the chain. Implications of these results on energy transfer in biological light harvesting systems, and the role of quantum coherences and entanglement are discussed.

  17. Commuting quantum circuits: efficient classical simulations versus hardness results

    CERN Document Server

    Ni, Xiaotong

    2012-01-01

    The study of quantum circuits composed of commuting gates is particularly useful to understand the delicate boundary between quantum and classical computation. Indeed, while being a restricted class, commuting circuits exhibit genuine quantum effects such as entanglement. In this paper we show that the computational power of commuting circuits exhibits a surprisingly rich structure. First we show that every 2-local commuting circuit acting on d-level systems and followed by single-qudit measurements can be efficiently simulated classically with high accuracy. In contrast, we prove that such strong simulations are hard for 3-local circuits. Using sampling methods we further show that all commuting circuits composed of exponentiated Pauli operators e^{i\\theta P} can be simulated efficiently classically when followed by single-qubit measurements. Finally, we show that commuting circuits can efficiently simulate certain non-commutative processes, related in particular to constant-depth quantum circuits. This give...

  18. An efficient quantum secure direct communication scheme with authentication

    Institute of Scientific and Technical Information of China (English)

    Yang Yu-Guang; Wen Qiao-Yan; Zhu Fu-Chen

    2007-01-01

    In this paper an efficient quantum secure direct communication (QSDC) scheme with authentication is presented,which is based on quantum entanglement and polarized single photons. The present protocol uses Einstein-PodolskyRosen (EPR) pairs and polarized single photons in batches. A particle of the EPR pairs is retained in the sender's QSDC protocol. According to the shared information beforehand, these two kinds of quantum states are mixed and then transmitted via a quantum channel. The EPR pairs are used to transmit secret messages and the polarized single photons used for authentication and eavesdropping check. Consequently, because of the dual contributions of the polarized single photons, no classical information is needed. The intrinsic efficiency and total efficiency are both 1 in this scheme as almost all of the instances are useful and each EPR pair can be used to carry two bits of information.

  19. Quantum efficiency of self-assembled quantum dots determined by a modified optical local density of states

    DEFF Research Database (Denmark)

    Johansen, Jeppe; Stobbe, Søren; Nikolaev, I.S.

    2007-01-01

    We have measured time-resolved spontaneous emission from quantum dots near a dielectric interface with known photonic local density of states. We thus experimentally determine the quantum efficiency and the dipole moment, important for quantum optics.......We have measured time-resolved spontaneous emission from quantum dots near a dielectric interface with known photonic local density of states. We thus experimentally determine the quantum efficiency and the dipole moment, important for quantum optics....

  20. Quantum interferences reconstruction with low homodyne detection efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Esposito, Martina; Randi, Francesco [Universita degli studi di Trieste, Dipartimento di Fisica, Trieste (Italy); Titimbo, Kelvin; Zimmermann, Klaus; Benatti, Fabio [Universita degli studi di Trieste, Dipartimento di Fisica, Trieste (Italy); Istituto Nazionale di Fisica Nucleare, Sezione di Trieste, Trieste (Italy); Kourousias, Georgios; Curri, Alessio [Sincrotrone Trieste S.C.p.A., Trieste (Italy); Floreanini, Roberto [Istituto Nazionale di Fisica Nucleare, Sezione di Trieste, Trieste (Italy); Parmigiani, Fulvio [Universita degli studi di Trieste, Dipartimento di Fisica, Trieste (Italy); Sincrotrone Trieste S.C.p.A., Trieste (Italy); University of Cologne, Institute of Physics II, Cologne (Germany); Fausti, Daniele [Universita degli studi di Trieste, Dipartimento di Fisica, Trieste (Italy); Sincrotrone Trieste S.C.p.A., Trieste (Italy)

    2016-12-15

    Optical homodyne tomography consists in reconstructing the quantum state of an optical field from repeated measurements of its amplitude at different field phases (homodyne data). The experimental noise, which unavoidably affects the homodyne data, leads to a detection efficiency η<1. The problem of reconstructing quantum states from noisy homodyne data sets prompted an intense scientific debate about the presence or absence of a lower homodyne efficiency bound (η>0.5) below which quantum features, like quantum interferences, cannot be retrieved. Here, by numerical experiments, we demonstrate that quantum interferences can be effectively reconstructed also for low homodyne detection efficiency. In particular, we address the challenging case of a Schroedinger cat state and test the minimax and adaptive Wigner function reconstruction technique by processing homodyne data distributed according to the chosen state but with an efficiency η>0.5. By numerically reproducing the Schroedinger's cat interference pattern, we give evidence that quantum state reconstruction is actually possible in these conditions, and provide a guideline for handling optical tomography based on homodyne data collected by low efficiency detectors. (orig.)

  1. Popescu-Rohrlich correlations imply efficient instantaneous nonlocal quantum computation

    Science.gov (United States)

    Broadbent, Anne

    2016-08-01

    In instantaneous nonlocal quantum computation, two parties cooperate in order to perform a quantum computation on their joint inputs, while being restricted to a single round of simultaneous communication. Previous results showed that instantaneous nonlocal quantum computation is possible, at the cost of an exponential amount of prior shared entanglement (in the size of the input). Here, we show that a linear amount of entanglement suffices, (in the size of the computation), as long as the parties share nonlocal correlations as given by the Popescu-Rohrlich box. This means that communication is not required for efficient instantaneous nonlocal quantum computation. Exploiting the well-known relation to position-based cryptography, our result also implies the impossibility of secure position-based cryptography against adversaries with nonsignaling correlations. Furthermore, our construction establishes a quantum analog of the classical communication complexity collapse under nonsignaling correlations.

  2. Efficient arbitrated quantum signature and its proof of security

    Science.gov (United States)

    Li, Qin; Li, Chengqing; Long, Dongyang; Chan, Wai Hong; Wang, Changji

    2013-07-01

    In this paper, an efficient arbitrated quantum signature scheme is proposed by combining quantum cryptographic techniques and some ideas in classical cryptography. In the presented scheme, the signatory and the receiver can share a long-term secret key with the arbitrator by utilizing the key together with a random number. While in previous quantum signature schemes, the key shared between the signatory and the arbitrator or between the receiver and the arbitrator could be used only once, and thus each time when a signatory needs to sign, the signatory and the receiver have to obtain a new key shared with the arbitrator through a quantum key distribution protocol. Detailed theoretical analysis shows that the proposed scheme is efficient and provably secure.

  3. Research on quantum efficiency of GaN wire photocathode

    Science.gov (United States)

    Xia, Sihao; Liu, Lei; Diao, Yu; Kong, Yike

    2017-02-01

    On the basis of three-dimensional continuity equation in semiconductors and finite difference method, the carrier concentration and the quantum efficiency of GaN wire photocathode as a function of incident photon energy are achieved. Results show that the quantum efficiency of the wire photocathode is largely enhanced compared with the conventional planar photocathode. The superiority of the wire photocathode is reflected in its structure with surrounding surfaces. The quantum efficiency of the wire photocathode largely depends on the wire width, surface reflectivity, surface escape probability and incident angle of light. The back interface recombination rate, however, has little influences on the quantum efficiency of the wire photocathode. The simulation results suggest that the optimal width for photoemission is 150-200 nm. Besides, the quantum efficiency increases and decreases linearly with increasing surface escape probability and surface reflectivity, respectively. With increasing ratio of wire spacing to wire height, the optimal incident angle of light is reduced. These simulations are expected to guide the preparation of a better performing GaN wire photocathode.

  4. Efficient Quantum Private Communication Based on Dynamic Control Code Sequence

    Science.gov (United States)

    Cao, Zheng-Wen; Feng, Xiao-Yi; Peng, Jin-Ye; Zeng, Gui-Hua; Qi, Jin

    2016-12-01

    Based on chaos and quantum properties, we propose a quantum private communication scheme with dynamic control code sequence. The initial sequence is obtained via chaotic systems, and the control code sequence is derived by grouping, XOR and extracting. A shift cycle algorithm is designed to enable the dynamic change of control code sequence. Analysis shows that transmission efficiency could reach 100 % with high dynamics and security.

  5. Statistical estimation of the efficiency of quantum state tomography protocols.

    Science.gov (United States)

    Bogdanov, Yu I; Brida, G; Genovese, M; Kulik, S P; Moreva, E V; Shurupov, A P

    2010-07-02

    A novel operational method for estimating the efficiency of quantum state tomography protocols is suggested. It is based on a priori estimation of the quality of an arbitrary protocol by means of universal asymptotic fidelity distribution and condition number, which takes minimal value for better protocol. We prove the adequacy of the method both with numerical modeling and through the experimental realization of several practically important protocols of quantum state tomography.

  6. Efficient method for transport simulations in quantum cascade lasers

    Directory of Open Access Journals (Sweden)

    Maczka Mariusz

    2017-01-01

    Full Text Available An efficient method for simulating quantum transport in quantum cascade lasers is presented. The calculations are performed within a simple approximation inspired by Büttiker probes and based on a finite model for semiconductor superlattices. The formalism of non-equilibrium Green’s functions is applied to determine the selected transport parameters in a typical structure of a terahertz laser. Results were compared with those obtained for a infinite model as well as other methods described in literature.

  7. Efficient method for transport simulations in quantum cascade lasers

    Science.gov (United States)

    Maczka, Mariusz; Pawlowski, Stanislaw

    2016-12-01

    An efficient method for simulating quantum transport in quantum cascade lasers is presented. The calculations are performed within a simple approximation inspired by Büttiker probes and based on a finite model for semiconductor superlattices. The formalism of non-equilibrium Green's functions is applied to determine the selected transport parameters in a typical structure of a terahertz laser. Results were compared with those obtained for a infinite model as well as other methods described in literature.

  8. Efficient Quantum Private Communication Based on Dynamic Control Code Sequence

    Science.gov (United States)

    Cao, Zheng-Wen; Feng, Xiao-Yi; Peng, Jin-Ye; Zeng, Gui-Hua; Qi, Jin

    2017-04-01

    Based on chaos and quantum properties, we propose a quantum private communication scheme with dynamic control code sequence. The initial sequence is obtained via chaotic systems, and the control code sequence is derived by grouping, XOR and extracting. A shift cycle algorithm is designed to enable the dynamic change of control code sequence. Analysis shows that transmission efficiency could reach 100 % with high dynamics and security.

  9. Mid-infrared interband cascade photodetectors with high quantum efficiency

    Science.gov (United States)

    Tian, Zhao-Bing; Singh, Anjali; Rigg, Kevin; Krishna, Sanjay

    2016-02-01

    Antimony-based Interband Cascade (IC) photodetectors are emerging as viable candidates for highperformance infrared applications, especially at high operating temperatures. In our previous IC detector designs using InAs/GaSb Type-II superlattices, the quantum efficiency was relatively low as the designs were optimized for high signal to noise ratio. Here we report our recent development of low-noise mid-IR IC photodetectors with high external quantum efficiency. By adopting IC detectors with thicker absorber designs, the quantum efficiency of these mid-IR IC detectors has been increased up to 35%. These IC devices continue to have low-dark current and high temperature operations. Some further analysis on the device characteristics is also presented.

  10. Nano-patterned superconducting surface for high quantum efficiency cathode

    Science.gov (United States)

    Hannon, Fay; Musumeci, Pietro

    2017-03-07

    A method for providing a superconducting surface on a laser-driven niobium cathode in order to increase the effective quantum efficiency. The enhanced surface increases the effective quantum efficiency by improving the laser absorption of the surface and enhancing the local electric field. The surface preparation method makes feasible the construction of superconducting radio frequency injectors with niobium as the photocathode. An array of nano-structures are provided on a flat surface of niobium. The nano-structures are dimensionally tailored to interact with a laser of specific wavelength to thereby increase the electron yield of the surface.

  11. Nano-patterned superconducting surface for high quantum efficiency cathode

    Energy Technology Data Exchange (ETDEWEB)

    Hannon, Fay; Musumeci, Pietro

    2017-03-07

    A method for providing a superconducting surface on a laser-driven niobium cathode in order to increase the effective quantum efficiency. The enhanced surface increases the effective quantum efficiency by improving the laser absorption of the surface and enhancing the local electric field. The surface preparation method makes feasible the construction of superconducting radio frequency injectors with niobium as the photocathode. An array of nano-structures are provided on a flat surface of niobium. The nano-structures are dimensionally tailored to interact with a laser of specific wavelength to thereby increase the electron yield of the surface.

  12. Pure sources and efficient detectors for optical quantum information processing

    Science.gov (United States)

    Zielnicki, Kevin

    Over the last sixty years, classical information theory has revolutionized the understanding of the nature of information, and how it can be quantified and manipulated. Quantum information processing extends these lessons to quantum systems, where the properties of intrinsic uncertainty and entanglement fundamentally defy classical explanation. This growing field has many potential applications, including computing, cryptography, communication, and metrology. As inherently mobile quantum particles, photons are likely to play an important role in any mature large-scale quantum information processing system. However, the available methods for producing and detecting complex multi-photon states place practical limits on the feasibility of sophisticated optical quantum information processing experiments. In a typical quantum information protocol, a source first produces an interesting or useful quantum state (or set of states), perhaps involving superposition or entanglement. Then, some manipulations are performed on this state, perhaps involving quantum logic gates which further manipulate or entangle the intial state. Finally, the state must be detected, obtaining some desired measurement result, e.g., for secure communication or computationally efficient factoring. The work presented here concerns the first and last stages of this process as they relate to photons: sources and detectors. Our work on sources is based on the need for optimized non-classical states of light delivered at high rates, particularly of single photons in a pure quantum state. We seek to better understand the properties of spontaneous parameteric downconversion (SPDC) sources of photon pairs, and in doing so, produce such an optimized source. We report an SPDC source which produces pure heralded single photons with little or no spectral filtering, allowing a significant rate enhancement. Our work on detectors is based on the need to reliably measure single-photon states. We have focused on

  13. Fidelity decay as an efficient indicator of quantum chaos.

    Science.gov (United States)

    Emerson, Joseph; Weinstein, Yaakov S; Lloyd, Seth; Cory, D G

    2002-12-31

    We demonstrate that a system's rate of fidelity decay under repeated perturbations may be measured efficiently on a quantum information processor, and analyze the conditions under which this indicator is a reliable probe of quantum chaos. The type and rate of the decay are not dependent on the eigenvalue statistics of the unperturbed system, but depend on the system's eigenvector statistics in the eigenbasis of the perturbation. For random eigenvector statistics, the decay is exponential with a rate fixed by the variance of the perturbation's energy spectrum. Hence, even classically regular models can exhibit an exponential fidelity decay under generic quantum perturbations. These results clarify which perturbations can distinguish classically regular and chaotic quantum systems.

  14. An efficient quantum search engine on unsorted database

    Science.gov (United States)

    Lu, Songfeng; Zhang, Yingyu; Liu, Fang

    2013-10-01

    We consider the problem of finding one or more desired items out of an unsorted database. Patel has shown that if the database permits quantum queries, then mere digitization is sufficient for efficient search for one desired item. The algorithm, called factorized quantum search algorithm, presented by him can locate the desired item in an unsorted database using O() queries to factorized oracles. But the algorithm requires that all the attribute values must be distinct from each other. In this paper, we discuss how to make a database satisfy the requirements, and present a quantum search engine based on the algorithm. Our goal is achieved by introducing auxiliary files for the attribute values that are not distinct, and converting every complex query request into a sequence of calls to factorized quantum search algorithm. The query complexity of our algorithm is O() for most cases.

  15. Efficient Quantum State Estimation with Over-complete Tomography

    OpenAIRE

    Zhang, Chi; Xiang, Guo-Yong; Zhang, Yong-Sheng; Li, Chuan-Feng; Guo, Guang-Can

    2011-01-01

    It is widely accepted that the selection of measurement bases can affect the efficiency of quantum state estimation methods, precision of estimating an unknown state can be improved significantly by simply introduce a set of symmetrical measurement bases. Here we compare the efficiencies of estimations with different numbers of measurement bases by numerical simulation and experiment in optical system. The advantages of using a complete set of symmetrical measurement bases are illustrated mor...

  16. Report of high quantum efficiency photocathode at Milano

    Energy Technology Data Exchange (ETDEWEB)

    Michelato, P. (INFN and University of Milano, Lab. LASA, Via F.lli Cervi 201, 2009, Segrate (Georgia))

    1992-07-01

    R D activity on high quantum efficiency alkali antimonide photocathode is in progress at Milano, in the context of the ARES program. Inside a preliminary preparation chamber, Cs[sub 3]Sb layers with qunatum efficiency up to 9% (at [lambda]=543.5 nm) and lifetime of some days has been recently produced on copper, stainless steel and niobium, using a reproducible deposition procedure adapted to the material of the different substrata.

  17. High quantum efficiency GaP avalanche photodiodes.

    Science.gov (United States)

    McIntosh, Dion; Zhou, Qiugui; Chen, Yaojia; Campbell, Joe C

    2011-09-26

    Gallium Phosphide (GaP) reach-through avalanche photodiodes (APDs) are reported. The APDs exhibited dark current less than a pico-ampere at unity gain. A quantum efficiency of 70% was achieved with a recessed window structure; this is almost two times higher than previous work. © 2011 Optical Society of America

  18. Efficient wave-function matching approach for quantum transport calculations

    DEFF Research Database (Denmark)

    Sørensen, Hans Henrik Brandenborg; Hansen, Per Christian; Petersen, Dan Erik;

    2009-01-01

    The wave-function matching (WFM) technique has recently been developed for the calculation of electronic transport in quantum two-probe systems. In terms of efficiency it is comparable to the widely used Green's function approach. The WFM formalism presented so far requires the evaluation of all ...

  19. Modeling the irradiance dependency of the quantum efficiency of potosynthesis

    NARCIS (Netherlands)

    Silsbe, G.M.; Kromkamp, J.C.

    2012-01-01

    Measures of the quantum efficiency of photosynthesis (phi(PSII)) across an irradiance (E) gradient are an increasingly common physiological assay and alternative to traditional photosynthetic-irradiance (PE) assays. Routinely, the analysis and interpretation of these data are analogous to PE measure

  20. Quantum efficiency and oscillator strength of site-controlled InAs quantum dots

    DEFF Research Database (Denmark)

    Albert, F.; Stobbe, Søren; Schneider, C.

    2010-01-01

    We report on time-resolved photoluminescence spectroscopy to determine the oscillator strength (OS) and the quantum efficiency (QE) of site-controlled InAs quantum dots nucleating on patterned nanoholes. These two quantities are determined by measurements on site-controlled quantum dot (SCQD......) samples with varying thickness of the capping layer. We determine radiative and nonradiative decay rates, from which we calculate an OS of 10.1+/-2.6 and an encouragingly high QE of (47+/-14)% for the SCQDs. The nonideal QE is attributed to nonradiative recombination at the etched nanohole interface...

  1. High Quantum Efficiency OLED Lighting Systems

    Energy Technology Data Exchange (ETDEWEB)

    Shiang, Joseph [General Electric (GE) Global Research, Fairfield, CT (United States)

    2011-09-30

    The overall goal of the program was to apply improvements in light outcoupling technology to a practical large area plastic luminaire, and thus enable the product vision of an extremely thin form factor high efficiency large area light source. The target substrate was plastic and the baseline device was operating at 35 LPW at the start of the program. The target LPW of the program was a >2x improvement in the LPW efficacy and the overall amount of light to be delivered was relatively high 900 lumens. Despite the extremely difficult challenges associated with scaling up a wet solution process on plastic substrates, the program was able to make substantial progress. A small molecule wet solution process was successfully implemented on plastic substrates with almost no loss in efficiency in transitioning from the laboratory scale glass to large area plastic substrates. By transitioning to a small molecule based process, the LPW entitlement increased from 35 LPW to 60 LPW. A further 10% improvement in outcoupling efficiency was demonstrated via the use of a highly reflecting cathode, which reduced absorptive loss in the OLED device. The calculated potential improvement in some cases is even larger, ~30%, and thus there is considerable room for optimism in improving the net light coupling efficacy, provided absorptive loss mechanisms are eliminated. Further improvements are possible if scattering schemes such as the silver nanowire based hard coat structure are fully developed. The wet coating processes were successfully scaled to large area plastic substrate and resulted in the construction of a 900 lumens luminaire device.

  2. An Efficient Quantum Somewhat Homomorphic Symmetric Searchable Encryption

    Science.gov (United States)

    Sun, Xiaoqiang; Wang, Ting; Sun, Zhiwei; Wang, Ping; Yu, Jianping; Xie, Weixin

    2017-01-01

    In 2009, Gentry first introduced an ideal lattices fully homomorphic encryption (FHE) scheme. Later, based on the approximate greatest common divisor problem, learning with errors problem or learning with errors over rings problem, FHE has developed rapidly, along with the low efficiency and computational security. Combined with quantum mechanics, Liang proposed a symmetric quantum somewhat homomorphic encryption (QSHE) scheme based on quantum one-time pad, which is unconditional security. And it was converted to a quantum fully homomorphic encryption scheme, whose evaluation algorithm is based on the secret key. Compared with Liang's QSHE scheme, we propose a more efficient QSHE scheme for classical input states with perfect security, which is used to encrypt the classical message, and the secret key is not required in the evaluation algorithm. Furthermore, an efficient symmetric searchable encryption (SSE) scheme is constructed based on our QSHE scheme. SSE is important in the cloud storage, which allows users to offload search queries to the untrusted cloud. Then the cloud is responsible for returning encrypted files that match search queries (also encrypted), which protects users' privacy.

  3. An Efficient Quantum Somewhat Homomorphic Symmetric Searchable Encryption

    Science.gov (United States)

    Sun, Xiaoqiang; Wang, Ting; Sun, Zhiwei; Wang, Ping; Yu, Jianping; Xie, Weixin

    2017-04-01

    In 2009, Gentry first introduced an ideal lattices fully homomorphic encryption (FHE) scheme. Later, based on the approximate greatest common divisor problem, learning with errors problem or learning with errors over rings problem, FHE has developed rapidly, along with the low efficiency and computational security. Combined with quantum mechanics, Liang proposed a symmetric quantum somewhat homomorphic encryption (QSHE) scheme based on quantum one-time pad, which is unconditional security. And it was converted to a quantum fully homomorphic encryption scheme, whose evaluation algorithm is based on the secret key. Compared with Liang's QSHE scheme, we propose a more efficient QSHE scheme for classical input states with perfect security, which is used to encrypt the classical message, and the secret key is not required in the evaluation algorithm. Furthermore, an efficient symmetric searchable encryption (SSE) scheme is constructed based on our QSHE scheme. SSE is important in the cloud storage, which allows users to offload search queries to the untrusted cloud. Then the cloud is responsible for returning encrypted files that match search queries (also encrypted), which protects users' privacy.

  4. Efficient quantum algorithm for computing n-time correlation functions.

    Science.gov (United States)

    Pedernales, J S; Di Candia, R; Egusquiza, I L; Casanova, J; Solano, E

    2014-07-11

    We propose a method for computing n-time correlation functions of arbitrary spinorial, fermionic, and bosonic operators, consisting of an efficient quantum algorithm that encodes these correlations in an initially added ancillary qubit for probe and control tasks. For spinorial and fermionic systems, the reconstruction of arbitrary n-time correlation functions requires the measurement of two ancilla observables, while for bosonic variables time derivatives of the same observables are needed. Finally, we provide examples applicable to different quantum platforms in the frame of the linear response theory.

  5. Efficient method for the calculation of dissipative quantum transport in quantum cascade lasers.

    Science.gov (United States)

    Greck, Peter; Birner, Stefan; Huber, Bernhard; Vogl, Peter

    2015-03-09

    We present a novel and very efficient method for calculating quantum transport in quantum cascade lasers (QCLs). It follows the nonequilibrium Green's function (NEGF) framework but sidesteps the calculation of lesser self-energies by replacing them by a quasi-equilibrium expression. This method generalizes the phenomenological Büttiker probe model by taking into account individual scattering mechanisms. It is orders of magnitude more efficient than a fully self-consistent NEGF calculation for realistic devices. We apply this method to a new THz QCL design which works up to 250 K - according to our calculations.

  6. An efficient biologically-inspired photocell enhanced by quantum coherence

    CERN Document Server

    Creatore, C; Emmott, S; Chin, A W

    2013-01-01

    Artificially reproducing the biological light reactions responsible for the remarkably efficient photon-to-charge conversion in photosynthetic complexes represents a new direction for the future development of photovoltaic devices. Here, we develop such a paradigm and present a model photocell based on the nanoscale architecture of photosynthetic reaction centres that explicitly harnesses the quantum mechanical effects recently discovered in photosynthetic complexes. Quantum interference of photon absorption/emission induced by the dipole-dipole interaction between molecular excited states guarantees an enhanced light-to-current conversion and power generation for a wide range of realistic parameters, opening a promising new route for designing artificial light-harvesting devices inspired by biological photosynthesis and quantum technologies.

  7. Photoconductive gain and quantum efficiency of remotely doped Ge/Si quantum dot photodetectors

    Science.gov (United States)

    Yakimov, A. I.; Kirienko, V. V.; Armbrister, V. A.; Bloshkin, A. A.; Dvurechenskii, A. V.; Shklyaev, A. A.

    2016-10-01

    We study the effect of quantum dot charging on the mid-infrared photocurrent, optical gain, hole capture probability, and absorption quantum efficiency in remotely delta-doped Ge/Si quantum dot photodetectors. The dot occupation with holes is controlled by varying dot and doping densities. From our investigations of samples doped to contain from about one to nine holes per dot we observe an over 10 times gain enhancement and similar suppression of the hole capture probability with increased carrier population. The data are explained by quenching the capture process and increasing the photoexcited hole lifetime due to formation of the repulsive Coulomb potential of the extra holes inside the quantum dots. The normal incidence quantum efficiency is found to be strongly asymmetric with respect to applied bias polarity. Based on the polarization-dependent absorption measurements it is concluded that, at a positive voltage, when holes move toward the nearest δ-doping plane, photocurrent is originated from the bound-to-continuum transitions of holes between the ground state confined in Ge dots and the extended states of the Si matrix. At a negative bias polarity, the photoresponse is caused by optical excitation to a quasibound state confined near the valence band edge with subsequent tunneling to the Si valence band. In a latter case, the possibility of hole transfer into continuum states arises from the electric field generated by charge distributed between quantum dots and delta-doping planes.

  8. Efficient quantum circuits for continuous-time quantum walks on composite graphs

    Science.gov (United States)

    Loke, T.; Wang, J. B.

    2017-02-01

    In this paper, we investigate the simulation of continuous-time quantum walks on specific classes of graphs, for which it is possible to fast-forward the time-evolution operator to achieve constant-time simulation complexity and to perform the simulation exactly, i.e. ε =0 , while maintaining \\text{poly}≤ft(\\text{log}(n)\\right) efficiency. In particular, we discuss two classes of composite graphs, commuting graphs and Cartesian product of graphs, that contain classes of graphs which can be simulated in this fashion. This allows us to identify new families of graphs that we can efficiently simulate in a quantum circuit framework, providing practical and explicit means to explore quantum-walk based algorithms in laboratories.

  9. High-efficiency "green" quantum dot solar cells.

    Science.gov (United States)

    Pan, Zhenxiao; Mora-Seró, Iván; Shen, Qing; Zhang, Hua; Li, Yan; Zhao, Ke; Wang, Jin; Zhong, Xinhua; Bisquert, Juan

    2014-06-25

    Semiconductor quantum dots (QDs) are extremely interesting materials for the development of photovoltaic devices, but currently the present the drawback is that the most efficient devices have been prepared with toxic heavy metals of Cd or Pb. Solar cells based on "green" QDs--totally free of Cd or Pb--present a modest efficiency of 2.52%. Herein we achieve effective surface passivation of the ternary CuInS2 (CIS) QDs that provides high photovoltaic quality core/shell CIS/ZnS (CIS-Z) QDs, leading to the development of high-efficiency green QD solar cells that surpass the performance of those based on the toxic cadmium and lead chalcogenides QDs. Using wide absorption range QDs, CIS-Z-based quantum dot sensitized solar cell (QDSC) configuration with high QD loading and with the benefit of the recombination reduction with type-I core/shell structure, we boost the power conversion efficiency of Cd- and Pb-free QDSC to a record of 7.04% (with certified efficiency of 6.66%) under AM 1.5G one sun irradiation. This efficiency is the best performance to date for QDSCs and also demonstrates that it is possible to obtain comparable or even better photovoltaic performance from green CIS QDs to the toxic cadmium and lead chalcogenides QDs.

  10. High-efficiency reconciliation for continuous variable quantum key distribution

    Science.gov (United States)

    Bai, Zengliang; Yang, Shenshen; Li, Yongmin

    2017-04-01

    Quantum key distribution (QKD) is the most mature application of quantum information technology. Information reconciliation is a crucial step in QKD and significantly affects the final secret key rates shared between two legitimate parties. We analyze and compare various construction methods of low-density parity-check (LDPC) codes and design high-performance irregular LDPC codes with a block length of 106. Starting from these good codes and exploiting the slice reconciliation technique based on multilevel coding and multistage decoding, we realize high-efficiency Gaussian key reconciliation with efficiency higher than 95% for signal-to-noise ratios above 1. Our demonstrated method can be readily applied in continuous variable QKD.

  11. Enhanced Quantum Efficiency From Hybrid Cesium Halide/Copper Photocathode

    Energy Technology Data Exchange (ETDEWEB)

    Kong, Lingmei; Joly, Alan G.; Droubay, Timothy C.; Gong, Yu; Hess, Wayne P.

    2014-04-28

    The quantum efficiency of Cu is found to increase dramatically when coated by a CsI film and then irradiated by a UV laser. Over three orders of magnitude quantum efficiency enhancement at 266 nm is observed in CsI/Cu(100), indicating potential application in future photocathode devices. Upon laser irradiation, a large work function reduction to a value less than 2 eV is also observed, significantly greater than for similarly treated CsBr/Cu(100). The initial QE enhancement, prior to laser irradiation, is attributed to interface interaction, surface cleanliness and the intrinsic properties of the Cs halide film. Further QE enhancement following activation is attributed to formation of inter-band states and Cs metal accumulation at the interface induced by laser irradiation.

  12. High quantum efficiency S-20 photocathodes for photon counting applications

    CERN Document Server

    Orlov, Dmitry A; Pinto, Serge Duarte; Glazenborg, Rene; Kernen, Emilie

    2016-01-01

    Based on conventional S-20 processes, a new series of high quantum efficiency (QE) photocathodes has been developed that can be specifically tuned for use in the ultraviolet, blue or green regions of the spectrum. The QE values exceed 30% at maximum response, and the dark count rate is found to be as low as 30 Hz/cm2 at room temperature. This combination of properties along with a fast temporal response makes these photocathodes ideal for application in photon counting detectors.

  13. An efficient quantum key distribution protocol with orthogonal product states

    Institute of Scientific and Technical Information of China (English)

    Yang Yu-Guang; Wen Qiao-Yan

    2007-01-01

    An efficient quantum key distribution (QKD) protocol with orthogonal product states in the 3(×)3 Hilbert space is presented. The sender, Alice, disorders the orthogonal product state sequence and sends it to Bob. After Alice has published the matching information of the particle sequence, Bob recovers the correct correspondences and makes an orthogonal measurement on the orthogonal product states to obtain the information sent by Alice. Finally, security analysis is also made.

  14. High Quantum Efficiency Phototubes for Atmospheric Fluorescence Telescopes

    CERN Document Server

    Kruppke-Hansen, Daniel

    2009-01-01

    The detection of atmospheric fluorescence light from extensive air showers has become a powerful tool for accurate measurements of the energy and mass of ultra-high energy cosmic ray particles. Employing large area imaging telescopes with mirror areas of 10m2 or more, showers out to distances of 30km and more can be observed. Matrices of low-noise photomultipliers are used to detect the faint light of the air showers against the ambient night-sky background noise. The signal-to-noise ratio of such a system is found to be proportional to the square root of the mirror area times the quantum efficiency of the phototube. Thus, higher quantum efficiencies could potentially improve the quality of the measurement and/or lead to the construction of more compact telescopes. In this paper, we shall discuss such improvements to be expected from high quantum efficiency phototubes that became available on the market only very recently. A series of simulations has been performed with data of different types of commercially...

  15. Internal quantum efficiency enhancement of GaInN/GaN quantum-well structures using Ag nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Iida, Daisuke [Department of Applied Physics, Tokyo University of Science, Katsushika, 125-8585 Tokyo (Japan); Department of Photonics Engineering, Technical University of Denmark, 2800 Lyngby (Denmark); Faculty of Science and Technology, Meijo University, 1-501 Shiogamaguchi Tempaku, 468-8502 Nagoya (Japan); Fadil, Ahmed, E-mail: afad@fotonik.dtu.dk; Ou, Yiyu; Kopylov, Oleksii; Ou, Haiyan [Department of Photonics Engineering, Technical University of Denmark, 2800 Lyngby (Denmark); Chen, Yuntian, E-mail: yuntian@hust.edu.cn [Department of Photonics Engineering, Technical University of Denmark, 2800 Lyngby (Denmark); School of Optical and Electronic Information, Huazhong University of Science and Technology, 430074 Wuhan (China); Iwaya, Motoaki; Takeuchi, Tetsuya; Kamiyama, Satoshi [Faculty of Science and Technology, Meijo University, 1-501 Shiogamaguchi Tempaku, 468-8502 Nagoya (Japan); Akasaki, Isamu [Faculty of Science and Technology, Meijo University, 1-501 Shiogamaguchi Tempaku, 468-8502 Nagoya (Japan); Akasaki Research Center, Nagoya University, Furo-cho Chikusa, 464-8603 Nagoya (Japan)

    2015-09-15

    We report internal quantum efficiency enhancement of thin p-GaN green quantum-well structure using self-assembled Ag nanoparticles. Temperature dependent photoluminescence measurements are conducted to determine the internal quantum efficiency. The impact of excitation power density on the enhancement factor is investigated. We obtain an internal quantum efficiency enhancement by a factor of 2.3 at 756 W/cm{sup 2}, and a factor of 8.1 at 1 W/cm{sup 2}. A Purcell enhancement up to a factor of 26 is estimated by fitting the experimental results to a theoretical model for the efficiency enhancement factor.

  16. Internal quantum efficiency enhancement of GaInN/GaN quantum-well structures using Ag nanoparticles

    Directory of Open Access Journals (Sweden)

    Daisuke Iida

    2015-09-01

    Full Text Available We report internal quantum efficiency enhancement of thin p-GaN green quantum-well structure using self-assembled Ag nanoparticles. Temperature dependent photoluminescence measurements are conducted to determine the internal quantum efficiency. The impact of excitation power density on the enhancement factor is investigated. We obtain an internal quantum efficiency enhancement by a factor of 2.3 at 756 W/cm2, and a factor of 8.1 at 1 W/cm2. A Purcell enhancement up to a factor of 26 is estimated by fitting the experimental results to a theoretical model for the efficiency enhancement factor.

  17. An efficient quantum secret sharing protocol with orthogonal product states

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    An efficient quantum secret sharing protocol with orthogonal product states in the 33 Hilbert space is presented. The particles in the orthogonal product states form two particle sequences. One sequence is sent to Bob and the other is sent to Charlie after rearranging the particle orders. With the help of Alice, Bob and Charlie make the corresponding local measurement to obtain the information of the or- thogonal product states prepared. This protocol has many distinct features such as great capacity and high efficiency.

  18. An efficient quantum secret sharing protocol with orthogonal product states

    Institute of Scientific and Technical Information of China (English)

    YANG YuGuang; WEN QiaoYan; ZHU FuChen

    2007-01-01

    An efficient quantum secret sharing protocol with orthogonal product states in the 3(×)3 Hilbert space is presented. The particles in the orthogonal product states form two particle sequences. One sequence is sent to Bob and the other is sent to Charlie after rearranging the particle orders. With the help of Alice, Bob and Charlie make the corresponding local measurement to obtain the information of the orthogonal product states prepared. This protocol has many distinct features such as great capacity and high efficiency.

  19. Efficient sharing of a continuous-variable quantum secret

    CERN Document Server

    Tyc, T; Sanders, B C; Tyc, Tomas; Rowe, David J.; Sanders, Barry C.

    2003-01-01

    We propose an efficient scheme for sharing a continuous variable quantum secret using passive optical interferometry and squeezers: this efficiency is achieved by showing that a maximum of two squeezers is required to replicate the secret state, and we obtain the cheapest configuration in terms of total squeezing cost. Squeezing is a cost for the dealer of the secret as well as for the receivers, and we quantify limitations to the fidelity of the replicated secret state in terms of the squeezing employed by the dealer.

  20. Efficient calculation of dissipative quantum transport properties in semiconductor nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Greck, Peter

    2012-11-26

    We present a novel quantum transport method that follows the non-equilibrium Green's function (NEGF) framework but side steps any self-consistent calculation of lesser self-energies by replacing them by a quasi-equilibrium expression. We termed this method the multi-scattering Buettiker-Probe (MSB) method. It generalizes the so-called Buettiker-Probe model but takes into account all relevant individual scattering mechanisms. It is orders of magnitude more efficient than a fully selfconsistent non-equilibrium Green's function calculation for realistic devices, yet accurately reproduces the results of the latter method as well as experimental data. This method is fairly easy to implement and opens the path towards realistic three-dimensional quantum transport calculations. In this work, we review the fundamentals of the non-equilibrium Green's function formalism for quantum transport calculations. Then, we introduce our novel MSB method after briefly reviewing the original Buettiker-Probe model. Finally, we compare the results of the MSB method to NEGF calculations as well as to experimental data. In particular, we calculate quantum transport properties of quantum cascade lasers in the terahertz (THz) and the mid-infrared (MIR) spectral domain. With a device optimization algorithm based upon the MSB method, we propose a novel THz quantum cascade laser design. It uses a two-well period with alternating barrier heights and complete carrier thermalization for the majority of the carriers within each period. We predict THz laser operation for temperatures up to 250 K implying a new temperature record.

  1. Measuring nonadiabaticity of molecular quantum dynamics with quantum fidelity and with its efficient semiclassical approximation

    CERN Document Server

    Zimmermann, Tomas

    2011-01-01

    We propose to measure nonadiabaticity of molecular quantum dynamics rigorously with the quantum fidelity between the Born-Oppenheimer and fully nonadiabatic dynamics. It is shown that this measure of nonadiabaticity applies in situations where other criteria, such as the energy gap criterion or the extent of population transfer, fail. We further propose to estimate this quantum fidelity efficiently with a generalization of the dephasing representation to multiple surfaces. Two variants of the multiple-surface dephasing representation (MSDR) are introduced, in which the nuclei are propagated either with the fewest-switches surface hopping (FSSH) or with the locally mean field dynamics (LMFD). The LMFD can be interpreted as the Ehrenfest dynamics of an ensemble of nuclear trajectories, and has been used previously in the nonadiabatic semiclassical initial value representation. In addition to propagating an ensemble of classical trajectories, the MSDR requires evaluating nonadiabatic couplings and solving the Sc...

  2. Quantum efficiency of a single microwave photon detector based on a semiconductor double quantum dot

    Science.gov (United States)

    Wong, Clement H.; Vavilov, Maxim G.

    2017-01-01

    Motivated by recent interest in implementing circuit quantum electrodynamics with semiconducting quantum dots, we consider a double quantum dot (DQD) capacitively coupled to a superconducting resonator that is driven by the microwave field of a superconducting transmission line. We analyze the DQD current response using input-output theory and show that the resonator-coupled DQD is a sensitive microwave single photon detector. Using currently available experimental parameters of DQD-resonator coupling and dissipation, including the effects of 1 /f charge noise and phonon noise, we determine the parameter regime for which incident photons are completely absorbed and near-unit ≳98 % efficiency can be achieved. We show that this regime can be reached by using very high quality resonators with quality factor Q ≃105 .

  3. Optimal power and efficiency of quantum Stirling heat engines

    Science.gov (United States)

    Yin, Yong; Chen, Lingen; Wu, Feng

    2017-01-01

    A quantum Stirling heat engine model is established in this paper in which imperfect regeneration and heat leakage are considered. A single particle which contained in a one-dimensional infinite potential well is studied, and the system consists of countless replicas. Each particle is confined in its own potential well, whose occupation probabilities can be expressed by the thermal equilibrium Gibbs distributions. Based on the Schrödinger equation, the expressions of power output and efficiency for the engine are obtained. Effects of imperfect regeneration and heat leakage on the optimal performance are discussed. The optimal performance region and the optimal values of important parameters of the engine cycle are obtained. The results obtained can provide some guidelines for the design of a quantum Stirling heat engine.

  4. Efficient estimation of resonant coupling between quantum systems.

    Science.gov (United States)

    Stenberg, Markku P V; Sanders, Yuval R; Wilhelm, Frank K

    2014-11-21

    We present an efficient method for the characterization of two coupled discrete quantum systems, one of which can be controlled and measured. For two systems with transition frequencies ωq, ωr, and coupling strength g we show how to obtain estimates of g and ωr whose error decreases exponentially in the number of measurement shots rather than as a power law expected in simple approaches. Our algorithm can thereby identify g and ωr simultaneously with high precision in a few hundred measurement shots. This is achieved by adapting measurement settings upon data as it is collected. We also introduce a method to eliminate erroneous estimates with small overhead. Our algorithm is robust against the presence of relaxation and typical noise. Our results are applicable to many candidate technologies for quantum computation, in particular, for the characterization of spurious two-level systems in superconducting qubits or stripline resonators.

  5. Efficient Biologically Inspired Photocell Enhanced by Delocalized Quantum States

    Science.gov (United States)

    Creatore, C.; Parker, M. A.; Emmott, S.; Chin, A. W.

    2013-12-01

    Artificially implementing the biological light reactions responsible for the remarkably efficient photon-to-charge conversion in photosynthetic complexes represents a new direction for the future development of photovoltaic devices. Here, we develop such a paradigm and present a model photocell based on the nanoscale architecture and molecular elements of photosynthetic reaction centers. Quantum interference of photon absorption and emission induced by the dipole-dipole interaction between molecular excited states guarantees an enhanced light-to-current conversion and power generation for a wide range of electronic, thermal, and optical parameters for optimized dipolar geometries. This result opens a promising new route for designing artificial light-harvesting devices inspired by biological photosynthesis and quantum technologies.

  6. Radix-independent, efficient arrays for multi-level n-qudit quantum and reversible computation

    Science.gov (United States)

    Mohammadi, Majid

    2015-08-01

    Multiple-valued quantum logic allows the designers to reduce the number of cells while obtaining more functionality in the quantum circuits. Large r-valued reversible or quantum gates ( r stands for radix and is more than 2) cannot be directly realized in the current quantum technology. Therefore, we are interested in designing the large reversible and quantum controlled gates using the arrays of one-quantum digit (qudit) or two-qudit gates. In our previous work, we proposed quantum arrays to implement the r-valued quantum circuits. In this paper, we propose novel efficient structures and arrays, for r-valued quantum logic gates. The quantum costs of the developed quantum arrays are independent of the radix of calculations in the quantum circuit.

  7. Highly efficient metallic optical incouplers for quantum well infrared photodetectors

    Science.gov (United States)

    Liu, Long; Chen, Yu; Huang, Zhong; Du, Wei; Zhan, Peng; Wang, Zhenlin

    2016-01-01

    Herein, we propose a highly efficient metallic optical incoupler for a quantum well infrared photodetector (QWIP) operating in the spectrum range of 14~16 μm, which consists of an array of metal micropatches and a periodically corrugated metallic back plate sandwiching a semiconductor active layer. By exploiting the excitations of microcavity modes and hybrid spoof surface plasmons (SSPs) modes, this optical incoupler can convert infrared radiation efficiently into the quantum wells (QWs) layer of semiconductor region with large electrical field component (Ez) normal to the plane of QWs. Our further numerical simulations for optimization indicate that by tuning microcavity mode to overlap with hybrid SSPs mode in spectrum, a coupled mode is formed, which leads to 33-fold enhanced light absorption for QWs centered at wavelength of 14.5 μm compared with isotropic absorption of QWs without any metallic microstructures, as well as a large value of coupling efficiency (η) of |Ez|2 ~ 6. This coupled mode shows a slight dispersion over ~40° and weak polarization dependence, which is quite beneficial to the high performance infrared photodetectors. PMID:27456691

  8. Highly efficient metallic optical incouplers for quantum well infrared photodetectors

    Science.gov (United States)

    Liu, Long; Chen, Yu; Huang, Zhong; Du, Wei; Zhan, Peng; Wang, Zhenlin

    2016-07-01

    Herein, we propose a highly efficient metallic optical incoupler for a quantum well infrared photodetector (QWIP) operating in the spectrum range of 14~16 μm, which consists of an array of metal micropatches and a periodically corrugated metallic back plate sandwiching a semiconductor active layer. By exploiting the excitations of microcavity modes and hybrid spoof surface plasmons (SSPs) modes, this optical incoupler can convert infrared radiation efficiently into the quantum wells (QWs) layer of semiconductor region with large electrical field component (Ez) normal to the plane of QWs. Our further numerical simulations for optimization indicate that by tuning microcavity mode to overlap with hybrid SSPs mode in spectrum, a coupled mode is formed, which leads to 33-fold enhanced light absorption for QWs centered at wavelength of 14.5 μm compared with isotropic absorption of QWs without any metallic microstructures, as well as a large value of coupling efficiency (η) of |Ez|2 ~ 6. This coupled mode shows a slight dispersion over ~40° and weak polarization dependence, which is quite beneficial to the high performance infrared photodetectors.

  9. High quantum efficiency S-20 photocathodes in photon counting detectors

    Science.gov (United States)

    Orlov, D. A.; DeFazio, J.; Duarte Pinto, S.; Glazenborg, R.; Kernen, E.

    2016-04-01

    Based on conventional S-20 processes, a new series of high quantum efficiency (QE) photocathodes has been developed that can be specifically tuned for use in the ultraviolet, blue or green regions of the spectrum. The QE values exceed 30% at maximum response, and the dark count rate is found to be as low as 30 Hz/cm2 at room temperature. This combination of properties along with a fast temporal response makes these photocathodes ideal for application in photon counting detectors, which is demonstrated with an MCP photomultiplier tube for single and multi-photoelectron detection.

  10. Photocurrent extraction efficiency in colloidal quantum dot photovoltaics

    KAUST Repository

    Kemp, K. W.

    2013-01-01

    The efficiency of photocurrent extraction was studied directly inside operating Colloidal Quantum Dot (CQD) photovoltaic devices. A model was derived from first principles for a thin film p-n junction with a linearly spatially dependent electric field. Using this model, we were able to clarify the origins of recent improvement in CQD solar cell performance. From current-voltage diode characteristics under 1 sun conditions, we extracted transport lengths ranging from 39 nm to 86 nm for these materials. Characterization of the intensity dependence of photocurrent extraction revealed that the dominant loss mechanism limiting the transport length is trap-mediated recombination. © 2013 AIP Publishing LLC.

  11. Internal quantum efficiency enhancement of GaInN/GaN quantum-well structures using Ag nanoparticles

    DEFF Research Database (Denmark)

    Iida, Daisuke; Fadil, Ahmed; Chen, Yuntian

    2015-01-01

    We report internal quantum efficiency enhancement of thin p-GaN green quantumwell structure using self-assembled Ag nanoparticles. Temperature dependent photoluminescence measurements are conducted to determine the internal quantum efficiency. The impact of excitation power density...... on the enhancement factor is investigated. We obtain an internal quantum efficiency enhancement by a factor of 2.3 at 756 W/cm2 , and a factor of 8.1 at 1 W/cm2 . A Purcell enhancement up to a factor of 26 is estimated by fitting the experimental results to a theoretical model for the efficiency enhancement factor....

  12. Simulating Hamiltonians in Quantum Networks Efficient Schemes and Complexity Bounds

    CERN Document Server

    Wocjan, P; Janzing, D; Beth, T; Wocjan, Pawel; Roetteler, Martin; Janzing, Dominik; Beth, Thomas

    2001-01-01

    We address the problem of simulating pair-interaction Hamiltonians in n node quantum networks where the subsystems have arbitrary, possibly different, dimensions. We show that any pair-interaction can be used to simulate any other by applying sequences of appropriate local control sequences. Efficient schemes for decoupling and time reversal can be constructed from orthogonal arrays. Conditions on time optimal simulation are formulated in terms of spectral majorization of matrices characterizing the coupling parameters. Moreover, we consider a specific system of n harmonic oscillators with bilinear interaction. In this case, decoupling can efficiently be achieved using the combinatorial concept of difference schemes. For this type of interactions we present optimal schemes for inversion.

  13. Quantum efficiency of colloidal suspensions containing quantum dot/silica hybrid particles

    Science.gov (United States)

    Jeon, Hyungjoon; Yoon, Cheolsang; Lee, Sooho; Lee, Doh C.; Shin, Kyusoon; Lee, Kangtaek

    2016-10-01

    We have investigated the fluorescence properties of colloidal suspensions conntaining quantum dot (QD)/silica hybrid particles. First, we synthesized QD/silica hybrid particles with silica-QD-silica (SQS) core-shell-shell geometry, and monitored the quantum efficiencies of their suspensions at various particle concentrations. We found that the quantum efficiency (QE) of SQS particles in deionized (DI) water was much lower than that of the QDs even at low particle concentration, mainly due to the light scattering of emitted photons at the silica/water interface, followed by reabsorption by QDs. As the concentration of SQS particles was increased, both light scattering and reabsorption by QDs became more important, which further reduced the QE. Refractive index-matched solvent, however, reduced light scattering, yielding greater QE than DI water. Next, we induced aggregation of SQS particles, and found that QE increased as particles aggregated in DI water because of reduced light scattering and reabsorption, whereas it remained almost constant in the refractive index-matched solvent. Finally, we studied aggregation of highly concentrated silica particle suspensions containing a low concentration of SQS particles, and found that QE increased with aggregation because light scattering and reabsorption were reduced.

  14. Calculation method of quantum efficiency to TiO2 nanocrystal photocatalysis reaction

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The quantum yield is an important factor to evaluate the efficiency of photoreactor. This article gives an overall calculation method of the quantum efficiency(ф) and the apparent quantum efficiency(ф2) to the TiO2/UV photocatalysis system. Furthermore, for the immobility system (IS), the formulation of the faction of light absorbed by the TiO2 thin film is proposed so as to calculate the quantum efficiency by using the measured value and theoretic calculated value of transmissivity (T). For the suspension system(SS), due to the difficulty to obtain the absorption coefficient (α) of TiO2 particulates, the quantum efficiency is calculated by means of the relative photonic efficiency (ξr) and the standard quantum yield (фstandard).

  15. Efficient generation of photonic entanglement and multiparty quantum communication

    Energy Technology Data Exchange (ETDEWEB)

    Trojek, Pavel

    2007-09-15

    This thesis deals largely with the problem of efficient generation of photonic entanglement with the principal aim of developing a bright source of polarization-entangled photon pairs, which meets the requirements for reliable and economic operation of quantum communication prototypes and demonstrators. Our approach uses a cor-related photon-pair emission in nonlinear process of spontaneous parametric downconversion pumped by light coming from a compact and cheap blue laser diode. Two alternative source configurations are examined within the thesis. The first makes use of a well established concept of degenerate non-collinear emission from a single type-II nonlinear crystal and the second relies on a novel method where the emissions from two adjacent type-I phase-matched nonlinear crystals operated in collinear non-degenerate regime are coherently overlapped. The latter approach showed to be more effective, yielding a total detected rate of almost 10{sup 6} pairs/s at >98% quantum interference visibility of polarization correlations. The second issue addressed within the thesis is the simplification and practical implementation of quantum-assisted solutions to multiparty communication tasks. We show that entanglement is not the only non-classical resource endowing the quantum multiparty information processing its power. Instead, only the sequential communication and transformation of a single qubit can be sufficient to accomplish certain tasks. This we prove for two distinct communication tasks, secret sharing and communication complexity. Whereas the goal of the first is to split a cryptographic key among several parties in a way that its reconstruction requires their collaboration, the latter aims at reducing the amount of communication during distributed computational tasks. Importantly, our qubitassisted solutions to the problems are feasible with state-of-the-art technology. This we clearly demonstrate in the laboratory implementation for 6 and 5 parties

  16. Coherent nanocavity structures for enhancement in internal quantum efficiency of III-nitride multiple quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Kim, T.; Liu, B.; Smith, R.; Athanasiou, M.; Gong, Y.; Wang, T., E-mail: t.wang@sheffield.ac.uk [Department of Electronic and Electrical Engineering, University of Sheffield, Mappin Street, Sheffield S1 3JD (United Kingdom)

    2014-04-21

    A “coherent” nanocavity structure has been designed on two-dimensional well-ordered InGaN/GaN nanodisk arrays with an emission wavelength in the green spectral region, leading to a massive enhancement in resonance mode in the green spectra region. By means of a cost-effective nanosphere lithography technique, we have fabricated such a structure on an InGaN/GaN multiple quantum well epiwafer and have observed the “coherent” nanocavity effect, which leads to an enhanced spontaneous emission (SE) rate. The enhanced SE rate has been confirmed by time resolved photoluminescence measurements. Due to the coherent nanocavity effect, we have achieved a massive improvement in internal quantum efficiency with a factor of 88, compared with the as-grown sample, which could be significant to bridge the “green gap” in solid-state lighting.

  17. Equivalent Method of Solving Quantum Efficiency of Reflection-Mode Exponential Doping GaAs Photocathode

    Institute of Scientific and Technical Information of China (English)

    NIU Jun; YANG Zhi; CHANG Ben-Kang

    2009-01-01

    The mathematical expression of the electron diffusion and drift length LDE of exponential doping photocathode is deduced. In the quantum efficiency equation of the reflection-mode uniform doping cathode, substituting L_(DE) for L_D, the equivalent quantum efficiency equation of the reflection-mode exponential doping cathode is obtained. By using the equivalent equation, theoretical simulation and experimental analysis shows that the equivalent index formula and formula-doped cathode quantum efficiency results in fine.The equivalent equation avoids complicated calculation, thereby simplifies the process of solving the quantum efficiency of exponential doping photocathode.

  18. Pseudospectral Gaussian quantum dynamics: Efficient sampling of potential energy surfaces

    Science.gov (United States)

    Heaps, Charles W.; Mazziotti, David A.

    2016-04-01

    Trajectory-based Gaussian basis sets have been tremendously successful in describing high-dimensional quantum molecular dynamics. In this paper, we introduce a pseudospectral Gaussian-based method that achieves accurate quantum dynamics using efficient, real-space sampling of the time-dependent basis set. As in other Gaussian basis methods, we begin with a basis set expansion using time-dependent Gaussian basis functions guided by classical mechanics. Unlike other Gaussian methods but characteristic of the pseudospectral and collocation methods, the basis set is tested with N Dirac delta functions, where N is the number of basis functions, rather than using the basis function as test functions. As a result, the integration for matrix elements is reduced to function evaluation. Pseudospectral Gaussian dynamics only requires O ( N ) potential energy calculations, in contrast to O ( N 2 ) evaluations in a variational calculation. The classical trajectories allow small basis sets to sample high-dimensional potentials. Applications are made to diatomic oscillations in a Morse potential and a generalized version of the Henon-Heiles potential in two, four, and six dimensions. Comparisons are drawn to full analytical evaluation of potential energy integrals (variational) and the bra-ket averaged Taylor (BAT) expansion, an O ( N ) approximation used in Gaussian-based dynamics. In all cases, the pseudospectral Gaussian method is competitive with full variational calculations that require a global, analytical, and integrable potential energy surface. Additionally, the BAT breaks down when quantum mechanical coherence is particularly strong (i.e., barrier reflection in the Morse oscillator). The ability to obtain variational accuracy using only the potential energy at discrete points makes the pseudospectral Gaussian method a promising avenue for on-the-fly dynamics, where electronic structure calculations become computationally significant.

  19. High Speed Travelling Wave Single-Photon Detectors With Near-Unity Quantum Efficiency

    CERN Document Server

    Pernice, W; Minaeva, O; Li, M; Goltsman, G N; Sergienko, A V; Tang, H X

    2011-01-01

    Ultrafast, high quantum efficiency single photon detectors are among the most sought-after elements in modern quantum optics and quantum communication. Close-to-unity photon detection efficiency is essential for scalable measurement-based quantum computation, quantum key distribution, and loophole-free Bell experiments. However, imperfect modal matching and finite photon absorption rates have usually limited the maximum attainable detection efficiency of single photon detectors. Here we demonstrate a superconducting nanowire detector atop nanophotonic waveguides and achieve single photon detection efficiency up to 94% at telecom wavelengths. Our detectors are fully embedded in a scalable, low loss silicon photonic circuit and provide ultrashort timing jitter of 18ps at multi-GHz detection rates. Exploiting this high temporal resolution we demonstrate ballistic photon transport in silicon ring resonators. The direct implementation of such a detector with high quantum efficiency, high detection speed and low ji...

  20. Quantum Efficiency Measurements of Femtosecond Vectorial Photoemission on Cu Photocathodes

    CERN Document Server

    Banfi, F; Galimberti, P G; Giannetti, C; Pagliara, S; Parmigiani, F; Pedersoli, E

    2005-01-01

    Quantum Efficiency (QE) measurements of single photon photoemission from a Cu(111) single crystal and a Cu polycrystal photocathodes, irradiated by 150~fs-6.28~eV laser pulses, are reported over a broad range of incidence angle in both s and p polarizations. The maximum value of QE for the Cu polycrystal sample is Y~4*10(-4), obtained with p polarization at an angle of incidence theta=65°. Our data confirm the vectorial photoemission model. Issues concerning surface roughness and symmetry considerations are addressed. An explanation in terms of non local conductivity tensor is proposed. Advantages of a 6.28~eV photon as compared to the standard 4.71~eV photon in use with Cu photocathodes are discussed.

  1. Calculation and Improvement on External Quantum Efficiency of OLEDs

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The calculation of the external quantum efficiency(ηext) of organic light-emitting devices(OLEDs) is presented theoretically. The basic idea is to obtain ηext by calculating the fraction of the generated light that can escape through the top surface and the average transmittance over the escape cone. During the calculation, the effects of the interference, absorption and multiple reflections are neglected. Then a result of a typical 8-tris-hydroxyquinoline aluminum(Alq3)-based OLEDs on a planar glass substrate is obtained. And a twice increase in ηext can be achieved by using a high-index-glass substrate with an antireflection coating(SiO2) on substrate surface.

  2. A concise quantum efficiency measurement system for gaseous photomultipliers

    Energy Technology Data Exchange (ETDEWEB)

    Moriya, Toru [Department of Physics, Yamagata University, Yamagata 990-8560 (Japan); Tokanai, Fuyuki, E-mail: tokanai@sci.kj.yamagata-u.ac.jp [Department of Physics, Yamagata University, Yamagata 990-8560 (Japan); Okazaki, Keisuke; Sakurai, Hirohisa; Gunji, Shuichi [Department of Physics, Yamagata University, Yamagata 990-8560 (Japan); Kawabata, Hironobu; Sohtome, Takayuki [BUNKOUKEIKI Co., Ltd., Hachioji, Tokyo 192-0033 (Japan); Sumiyoshi, Takayuki [Graduate School of the Faculty of Science and Engineering, Tokyo Metropolitan University, Tokyo 192-0397 (Japan); Sugiyama, Hirioyuki; Okada, Teruyuki; Ohishi, Noboru [Electron Tube Division, Hamamatsu Photonics K.K., Shizuoka 438-0193 (Japan); Kishimoto, Syunji [Institute of Material Structure Science, KEK, Tsukuba 305-0801 (Japan)

    2013-12-21

    We have been developing gaseous photomultiplier tubes (PMTs) with a bialkali photocathode combined with micropattern gas detectors (MPGDs). The sensitivity of a PMT is described in terms of its quantum efficiency (QE). The QE is very important in many experiments, particularly when dealing with low photon statistics. A concise QE measurement system has been developed to evaluate the characteristics of a sealed gaseous PMT with a bialkali photocathode. This QE measurement system consists of a Xe arc lamp source, reflective optics and filters, a monochromator, and a reference Si photodiode detector. Using the system, we evaluated the QE, gain, and long-term stability of the gaseous PMT. Here, we report the results of our evaluation.

  3. Efficient Design of Reversible Multiplexers with Low Quantum Cost

    Directory of Open Access Journals (Sweden)

    Ashima Malhotra

    2014-07-01

    Full Text Available Multiplexing is the generic term used to designate the operation of sending one or more analogue or digital signals over a common transmission line at dissimilar times or speeds and as such, the scheme we use to do just that is called a Multiplexer. In digital electronics, multiplexers are similarly known as data selectors as they can “select” each input line, are made from individual Analogue Switches encased in a single IC package as conflicting to the “mechanical” type selectors such as standard conservative switches and relays. In today era, reversibility has become essential part of digital world to make digital circuits more efficient. In this paper, we have proposed a new method to reduce quantum cost and power for various multiplexers. The results are simulated in Xilinx by using VHDL language.

  4. High-conjugation-efficiency aqueous CdSe quantum dots.

    Science.gov (United States)

    Au, Giang H T; Shih, Wan Y; Shih, Wei-Heng

    2013-11-12

    Quantum dots (QDs) are photoluminescent nanoparticles that can be directly or indirectly coupled with a receptor such as an antibody to specifically image a target biomolecule such as an antigen. Recent studies have shown that QDs can be directly made at room temperature and in an aqueous environment (AQDs) with 3-mercaptopropionic acid (MPA) as the capping ligand without solvent and ligand exchange typically required by QDs made by the organic solvent routes (OQDs). In this study, we have synthesized CdSe AQDs and compared their conjugation efficiency and imaging efficacy with commercial carboxylated OQDs in HT29 colon cancer cells using a primary antibody-biotinylated secondary antibody-streptavidin (SA) sandwich. We showed that the best imaging condition for AQDs occurred when one AQD was bound with 3 ± 0.3 SA with a nominal SA/AQD ratio of 4 corresponding to an SA conjugation efficiency of 75 ± 7.5%. In comparison, for commercial CdSe-ZnS OQDs to achieve 2.7 ± 0.4 bound SAs per OQD for comparable imaging efficacy a nominal SA/OQD ratio of 80 was needed corresponding to an SA conjugation efficiency of 3.4 ± 0.5% for CdSe-ZnS OQDs. The more than 10 times better SA conjugation efficiency of the CdSe AQDs as compared to that of the CdSe-ZnS OQDs was attributed to more capping molecules on the AQD surface as a result of the direct aqueous synthesis. More capping molecules on the AQD surface also allowed the SA-AQD conjugate to be stable in cell culture medium for more than three days without losing their staining capability in a flowing cell culture medium. In contrast, SA-OQD conjugates aggregated in cell culture medium and in phosphate buffer saline solution over time.

  5. Effect of finite phosphor thickness on detective quantum efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Nishikawa, R.M.; Yaffe, M.J.; Holmes, R.B. (Univ. of Toronto (Canada))

    1989-09-01

    In this paper we describe theoretically the relationship between the finite thickness of a phosphor screen and its spatial-frequency-dependent detective quantum efficiency DQE(f-). The finite thickness of the screen causes a variation in both the total number of light quanta emitted from the screen in a burst from a given x-ray interaction and in the spatial distribution of the quanta within the light burst (i.e., shape or point spread function (PSF) of the light burst). The variation in magnitude of the burst gives rise to a spatial-frequency-independent reduction in DQE, characterized by the scintillation efficiency As. The variation in PSF causes a roll off in DQE with increasing spatial frequency which we have characterized by the function Rc(f). Both As and Rc(f) can be determined from the moments of the distribution of the spatial Fourier spectrum of light bursts emitted from the phosphor and thus they are related: As is a scaling factor for Rc(f). Our theory predicts that it is necessary for all light bursts which appear at the output to have the same magnitude to maximize As and the same shape to maximize Rc(f). These requirements can lead to the result that the fluorescent screen with the highest modulation transfer function will not necessarily have the highest DQE(f) even at high spatial frequencies.

  6. Increasing the Efficiencies of Random-Choice-Based Quantum Communication Protocols with Delayed Measurement

    Institute of Scientific and Technical Information of China (English)

    DENG Fu-Guo; LONG Gui-Lu; WANG Yan; XIAO Li

    2004-01-01

    @@ The security of quantum communications lies in the capability of the legitimate parties to detect eavesdropping.Here we propose to use delayed measurement to increase the efficiency of protocols of quantum key distribution and quantum secret sharing that uses a random choice of measuring-basis. In addition to a higher efficiency,these measures also bring the benefit of much reduced amount of classical communications.

  7. An Efficient Deterministic Quantum Algorithm for the Integer Square-free Decomposition Problem

    OpenAIRE

    Li, Jun; Peng, Xinhua; Du, Jiangfeng; Suter, Dieter

    2011-01-01

    Quantum computers are known to be qualitatively more powerful than classical computers, but so far only a small number of different algorithms have been discovered that actually use this potential. It would therefore be highly desirable to develop other types of quantum algorithms that widen the range of possible applications. Here we propose an efficient and deterministic quantum algorithm for finding the square-free part of a large integer - a problem for which no efficient classical algori...

  8. An Efficient Exact Quantum Algorithm for the Integer Square-free Decomposition Problem

    OpenAIRE

    Jun Li; Xinhua Peng; Jiangfeng Du; Dieter Suter

    2012-01-01

    Quantum computers are known to be qualitatively more powerful than classical computers, but so far only a small number of different algorithms have been discovered that actually use this potential. It would therefore be highly desirable to develop other types of quantum algorithms that widen the range of possible applications. Here we propose an efficient and exact quantum algorithm for finding the square-free part of a large integer - a problem for which no efficient classical algorithm exis...

  9. Origin of low quantum efficiency of photoluminescence of InP/ZnS nanocrystals

    DEFF Research Database (Denmark)

    Shirazi, Roza; Kovacs, Andras; Corell, Dennis Dan

    2013-01-01

    In this paper, we study the origin of a strong wavelength dependence of the quantum efficiency of InP/ZnS nanocrystals. We find that while the average size of the nanocrystals increased by 50%, resulting in longer emission wavelength, the quantum efficiency drops more than one order of magnitude ...

  10. Ancilla-less selective and efficient quantum process tomography

    CERN Document Server

    Schmiegelow, Christian Tomás; Larotonda, Miguel Antonio; Paz, Juan Pablo

    2011-01-01

    Several methods, known as Quantum Process Tomography, are available to characterize the evolution of quantum systems, a task of crucial importance. However, their complexity dramatically increases with the size of the system. Here we present the theory describing a new type of method for quantum process tomography. We describe an algorithm that can be used to selectively estimate any parameter characterizing a quantum process. Unlike any of its predecessors this new quantum tomographer combines two main virtues: it requires investing a number of physical resources scaling polynomially with the number of qubits and at the same time it does not require any ancillary resources. We present the results of the first photonic implementation of this quantum device, characterizing quantum processes affecting two qubits encoded in heralded single photons. Even for this small system our method displays clear advantages over the other existing ones.

  11. Detective quantum efficiency (DQE) in PET scanners: A simulation study.

    Science.gov (United States)

    Karpetas, George E; Michail, Christos M; Fountos, George P; Kalyvas, Nektarios I; Valais, Ioannis G; Kandarakis, Ioannis S; Panayiotakis, George S

    2017-07-01

    The aim of the present study is to introduce the detective quantum efficiency (DQE) for the image quality assessment of positron emission tomography (PET) scanners. For this purpose, a thin layer chromatography (TLC) plane source was simulated using a previously validated, scanner and source geometry, Monte Carlo (MC) model. The model was developed with the Geant4 application for tomographic emission (GATE) MC package and reconstructed images obtained with the software for tomographic image reconstruction (STIR), with cluster computing. The GE Discovery ST PET scanner was simulated by using a previously validated code. A plane source consisting of a TLC plate, was simulated by a layer of silica gel on aluminum (Al) foil substrate, immersed in 18F-FDG bath solution (1MBq). Image quality was assessed in terms of the modulation transfer function (MTF) and the normalized noise power spectrum (NNPS) in order to obtain the detective quantum efficiency (DQE). MTF curves were estimated from transverse reconstructed images of the plane source, whereas the NNPS data were estimated from the corresponding coronal images. Images were reconstructed by the maximum likelihood estimation ordered subsets maximum a posteriori one step late (MLE)-OS-MAP-OSL algorithm, by using various subsets 1-21) and iterations 1-20). MTF values were found to increase up to the 12th iteration whereas remain almost constant thereafter. However, the range of the increase in the MTF is limited as the number of subsets increases. The noise levels were found to increase with the corresponding increase of both the number of iterations and subsets. The maximum NNPS value (0.517mm(2)) was observed for the 420 MLEM-equivalent iterations reconstructed image at 0cycles/mm. Finally DQE values were found to increase for spatial frequencies up to 0.038cycles/mm and to decrease thereafter with the corresponding increase in both number of iterations and subsets. The maximum DQE value (0.48 at 0.038cycles/mm) was

  12. Toward efficient fiber-based quantum interface (Conference Presentation)

    Science.gov (United States)

    Soshenko, Vladimir; Vorobyov, Vadim V.; Bolshedvorsky, Stepan; Lebedev, Nikolay; Akimov, Alexey V.; Sorokin, Vadim; Smolyaninov, Andrey

    2016-04-01

    NV center in diamond is attracting a lot of attention in quantum information processing community [1]. Been spin system in clean and well-controlled environment of diamond it shows outstanding performance as quantum memory even at room temperature, spin control with single shot optical readout and possibility to build up quantum registers even on single NV center. Moreover, NV centers could be used as high-resolution sensitive elements of detectors of magnetic or electric field, temperature, tension, force or rotation. For all of these applications collection of the light emitted by NV center is crucial point. There were number of approaches suggested to address this issue, proposing use of surface plasmoms [2], manufacturing structures in diamond [3] etc. One of the key feature of any practically important interface is compatibility with the fiber technology. Several groups attacking this problem using various approaches. One of them is placing of nanodiamonds in the holes of photonic crystal fiber [4], another is utilization of AFM to pick and place nanodiamond on the tapered fiber[5]. We have developed a novel technique of placing a nanodiamond with single NV center on the tapered fiber by controlled transfer of a nanodiamond from one "donor" tapered fiber to the "target" clean tapered fiber. We verify our ability to transfer only single color centers by means of measurement of second order correlation function. With this technique, we were able to double collection efficiency of confocal microscope. The majority of the factors limiting the collection of photons via optical fiber are technical and may be removed allowing order of magnitude improved in collection. We also discuss number of extensions of this technique to all fiber excitation and integration with nanostructures. References: [1] Marcus W. Doherty, Neil B. Manson, Paul Delaney, Fedor Jelezko, Jörg Wrachtrup, Lloyd C.L. Hollenberg , " The nitrogen-vacancy colour centre in diamond," Physics Reports

  13. Calibrating and Controlling the Quantum Efficiency Distribution of Inhomogeneously Broadened Quantum Rods Using a Mirror Ball

    CERN Document Server

    Lunnemann, Per; van Dijk-Moes, Relinde J A; Pietra, Francesca; Vanmaekelbergh, Daniël; Koenderink, A Femius

    2013-01-01

    We demonstrate that a simple silver coated ball lens can be used to accurately measure the entire distribution of radiative transition rates of quantum dot nanocrystals. This simple and cost-effective implementation of Drexhage's method that uses nanometer-controlled optical mode density variations near a mirror, not only allows to extract calibrated ensemble-averaged rates, but for the first time also to quantify the full inhomogeneous dispersion of radiative and non radiative decay rates across thousands of nanocrystals. We apply the technique to novel ultra-stable CdSe/CdS dot-in-rod emitters. The emitters are of large current interest due to their improved stability and reduced blinking. We retrieve a room-temperature ensemble average quantum efficiency of 0.87+-0.08 at a mean lifetime around 20 ns. We confirm a log-normal distribution of decay rates as often assumed in literature and we show that the rate distribution-width, that amounts to about 30% of the mean decay rate, is strongly dependent on the l...

  14. Efficient Simulation of Quantum States Based on Classical Fields Modulated with Pseudorandom Phase Sequences

    CERN Document Server

    Fu, Jian

    2010-01-01

    We demonstrate that a tensor product structure could be obtained by introducing pseudorandom phase sequences into classical fields with two orthogonal modes. Using classical fields modulated with pseudorandom phase sequences, we discuss efficient simulation of several typical quantum states, including product state, Bell states, GHZ state, and W state. By performing quadrature demodulation scheme, we could obtain the mode status matrix of the simulating classical fields, based on which we propose a sequence permutation mechanism to reconstruct the simulated quantum states. The research on classical simulation of quantum states is important, for it not only enables potential practical applications in quantum computation, but also provides useful insights into fundamental concepts of quantum mechanics.

  15. Measuring the absolute quantum efficiency of luminescent materials

    Energy Technology Data Exchange (ETDEWEB)

    Rohwer, Lauren Shea [Sandia National Laboratories, P.O. Box 5800, MS-0892, Albuquerque, NM 87185-0892 (United States)]. E-mail: leshea@sandia.gov; Martin, James E. [Sandia National Laboratories, P.O. Box 5800, MS-0892, Albuquerque, NM 87185-0892 (United States)

    2005-11-15

    A measurement system and mathematical procedure are developed for determining the absolute quantum efficiency (QE), of luminescent materials. This technique, based on absorption of diffuse light within an integrating sphere, is applied to fluorescent laser dyes and conventional phosphor powders. The system described is tested for excitation in the near-UV and blue regions, but can be applied to higher energy excitation (UV), as well as lower energy excitation in the visible to near-IR, with the appropriate photodetectors and optical filters. The system was tested on both liquid and solid samples such as Coumarin 500 (CM500) dye in methanol and ethyl acetate; Rhodamine 6G in ethanol; and a variety of powder phosphors. The QE of quinine sulfate dihydrate solution (5x10{sup -3} M in 0.1 N H{sub 2}SO{sub 4}), a NIST fluorescence standard, was found to be in good agreement with the NIST value under 390 nm excitation. The accuracy of this measurement technique is acceptable for samples with absorption cross sections greater than {approx}6 mm{sup 2}.

  16. Effects of image processing on the detective quantum efficiency

    Science.gov (United States)

    Park, Hye-Suk; Kim, Hee-Joung; Cho, Hyo-Min; Lee, Chang-Lae; Lee, Seung-Wan; Choi, Yu-Na

    2010-04-01

    Digital radiography has gained popularity in many areas of clinical practice. This transition brings interest in advancing the methodologies for image quality characterization. However, as the methodologies for such characterizations have not been standardized, the results of these studies cannot be directly compared. The primary objective of this study was to standardize methodologies for image quality characterization. The secondary objective was to evaluate affected factors to Modulation transfer function (MTF), noise power spectrum (NPS), and detective quantum efficiency (DQE) according to image processing algorithm. Image performance parameters such as MTF, NPS, and DQE were evaluated using the international electro-technical commission (IEC 62220-1)-defined RQA5 radiographic techniques. Computed radiography (CR) images of hand posterior-anterior (PA) for measuring signal to noise ratio (SNR), slit image for measuring MTF, white image for measuring NPS were obtained and various Multi-Scale Image Contrast Amplification (MUSICA) parameters were applied to each of acquired images. In results, all of modified images were considerably influence on evaluating SNR, MTF, NPS, and DQE. Modified images by the post-processing had higher DQE than the MUSICA=0 image. This suggests that MUSICA values, as a post-processing, have an affect on the image when it is evaluating for image quality. In conclusion, the control parameters of image processing could be accounted for evaluating characterization of image quality in same way. The results of this study could be guided as a baseline to evaluate imaging systems and their imaging characteristics by measuring MTF, NPS, and DQE.

  17. Effects of image processing on the detective quantum efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Park, Hye-Suk; Kim, Hee-Joung; Cho, Hyo-Min; Lee, Chang-Lae; Lee, Seung-Wan; Choi, Yu-Na [Yonsei University, Wonju (Korea, Republic of)

    2010-02-15

    The evaluation of image quality is an important part of digital radiography. The modulation transfer function (MTF), the noise power spectrum (NPS), and the detective quantum efficiency (DQE) are widely accepted measurements of the digital radiographic system performance. However, as the methodologies for such characterization have not been standardized, it is difficult to compare directly reported the MTF, NPS, and DQE results. In this study, we evaluated the effect of an image processing algorithm for estimating the MTF, NPS, and DQE. The image performance parameters were evaluated using the international electro-technical commission (IEC 62220-1)-defined RQA5 radiographic techniques. Computed radiography (CR) posterior-anterior (PA) images of a hand for measuring the signal to noise ratio (SNR), the slit images for measuring the MTF, and the white images for measuring the NPS were obtained, and various multi-Scale image contrast amplification (MUSICA) factors were applied to each of the acquired images. All of the modifications of the images obtained by using image processing had a considerable influence on the evaluated image quality. In conclusion, the control parameters of image processing can be accounted for evaluating characterization of image quality in same way. The results of this study should serve as a baseline for based on evaluating imaging systems and their imaging characteristics by MTF, NPS, and DQE measurements.

  18. Detective quantum efficiency of electron area detectors in electron microscopy

    Energy Technology Data Exchange (ETDEWEB)

    McMullan, G., E-mail: gm2@mrc-lmb.cam.ac.uk [MRC Laboratory of Molecular Biology, Hills Road, Cambridge CB2 0QH (United Kingdom); Chen, S.; Henderson, R.; Faruqi, A.R. [MRC Laboratory of Molecular Biology, Hills Road, Cambridge CB2 0QH (United Kingdom)

    2009-08-15

    Recent progress in detector design has created the need for a careful side-by-side comparison of the modulation transfer function (MTF) and resolution-dependent detective quantum efficiency (DQE) of existing electron detectors with those of detectors based on new technology. We present MTF and DQE measurements for four types of detector: Kodak SO-163 film, TVIPS 224 charge coupled device (CCD) detector, the Medipix2 hybrid pixel detector, and an experimental direct electron monolithic active pixel sensor (MAPS) detector. Film and CCD performance was measured at 120 and 300 keV, while results are presented for the Medipix2 at 120 keV and for the MAPS detector at 300 keV. In the case of film, the effects of electron backscattering from both the holder and the plastic support have been investigated. We also show that part of the response of the emulsion in film comes from light generated in the plastic support. Computer simulations of film and the MAPS detector have been carried out and show good agreement with experiment. The agreement enables us to conclude that the DQE of a backthinned direct electron MAPS detector is likely to be equal to, or better than, that of film at 300 keV.

  19. Detective quantum efficiency of electron area detectors in electron microscopy.

    Science.gov (United States)

    McMullan, G; Chen, S; Henderson, R; Faruqi, A R

    2009-08-01

    Recent progress in detector design has created the need for a careful side-by-side comparison of the modulation transfer function (MTF) and resolution-dependent detective quantum efficiency (DQE) of existing electron detectors with those of detectors based on new technology. We present MTF and DQE measurements for four types of detector: Kodak SO-163 film, TVIPS 224 charge coupled device (CCD) detector, the Medipix2 hybrid pixel detector, and an experimental direct electron monolithic active pixel sensor (MAPS) detector. Film and CCD performance was measured at 120 and 300 keV, while results are presented for the Medipix2 at 120 keV and for the MAPS detector at 300 keV. In the case of film, the effects of electron backscattering from both the holder and the plastic support have been investigated. We also show that part of the response of the emulsion in film comes from light generated in the plastic support. Computer simulations of film and the MAPS detector have been carried out and show good agreement with experiment. The agreement enables us to conclude that the DQE of a backthinned direct electron MAPS detector is likely to be equal to, or better than, that of film at 300 keV.

  20. The Next Generation Photoinjector (thermal Emittance, Quantum Efficiency)

    CERN Document Server

    Palmer, D T

    1998-01-01

    This dissertation will elucidate the design, construction, theory, and operation of the Next Generation Photoinjector (NGP). This photoinjector is comprised of the BNL/SLAC/UCLA 1.6 cell symmetrized S-band photocathode radio frequency (rf) electron gun and a single emittance-compensation solenoidal magnet. This photoinjector is a prototype for the Linear Coherent Light Source X-ray Free Electron Laser operating in the 1.5 A range. Simulations indicate that this photoinjector is capable of producing a 1 nC electron bunch with transverse normalized emittance less than 1 $\\pi$ mm-mrad were the cathode is illuminated with a 10 psec longitudinal flat top pulse. Using a Gaussian longitudinal laser profile with a full width half maximum (FWHM) of 10 psec, simulation indicates that the NGP is capable of producing a normalized rms emittance of 2.50 $\\pi$ mm-mrad at 1 nC. Using the removable cathode plate we have studied the quantum efficiency (QE) of both copper and magnesium photo-cathodes...

  1. An efficient quantum light-matter interface with sub-second lifetime

    CERN Document Server

    Yang, Sheng-Jun; Bao, Xiao-Hui; Pan, Jian-Wei

    2015-01-01

    Quantum repeater holds the promise for scalable long-distance quantum communication. Towards a first quantum repeater based on memory-photon entanglement, significant progresses have made in improving performances of the building blocks. Further development is hindered by the difficulty of integrating key capabilities such as long storage time and high memory efficiency into a single system. Here we report an efficient light-matter interface with sub-second lifetime by confining laser-cooled atoms with 3D optical lattice and enhancing the atom-photon coupling with a ring cavity. An initial retrieval efficiency of 76(5)% together with an 1/e lifetime of 0.22(1) s have been achieved simultaneously, which already support sub-Hz entanglement distribution up to 1000 km through quantum repeater. Together with an efficient telecom interface and moderate multiplexing, our result may enable a first quantum repeater system that beats direct transmission in the near future.

  2. Popescu-Rohrlich correlations imply efficient instantaneous nonlocal quantum computation

    OpenAIRE

    Broadbent, Anne

    2015-01-01

    In instantaneous nonlocal quantum computation, two parties cooperate in order to perform a quantum computation on their joint inputs, while being restricted to a single round of simultaneous communication. Previous results showed that instantaneous nonlocal quantum computation is possible, at the cost of an exponential amount of prior shared entanglement (in the size of the input). Here, we show that a linear amount of entanglement suffices, (in the size of the computation), as long as the pa...

  3. Efficient and robust generation of maximally entangled states of two atomic ensembles by adiabatic quantum feedback

    CERN Document Server

    Lisi, A D; Illuminati, F; Vitali, D; Lisi, Antonio Di; Siena, Silvio De; Illuminati, Fabrizio; Vitali, David

    2004-01-01

    We introduce an efficient and robust scheme to generate maximally entangled states of two atomic ensembles. The scheme is based on quantum non-demolition measurements of total atomic populations and on quantum feedback conditioned by the measurements outputs. The high efficiency of the scheme is tested and confirmed numerically for photo-detection with ideal efficiency as well as in the presence of losses.

  4. Efficient and long-lived quantum memory with cold atoms inside a ring cavity

    CERN Document Server

    Bao, Xiao-Hui; Dietrich, Peter; Rui, Jun; Dück, Alexander; Strassel, Thorsten; Li, Li; Liu, Nai-Le; Zhao, Bo; Pan, Jian-Wei; 10.1038/nphys2324

    2012-01-01

    Quantum memories are regarded as one of the fundamental building blocks of linear-optical quantum computation and long-distance quantum communication. A long standing goal to realize scalable quantum information processing is to build a long-lived and efficient quantum memory. There have been significant efforts distributed towards this goal. However, either efficient but short-lived or long-lived but inefficient quantum memories have been demonstrated so far. Here we report a high-performance quantum memory in which long lifetime and high retrieval efficiency meet for the first time. By placing a ring cavity around an atomic ensemble, employing a pair of clock states, creating a long-wavelength spin wave, and arranging the setup in the gravitational direction, we realize a quantum memory with an intrinsic spin wave to photon conversion efficiency of 73(2)% together with a storage lifetime of 3.2(1) ms. This realization provides an essential tool towards scalable linear-optical quantum information processing.

  5. Photo-acoustic spectroscopy and quantum efficiency of Yb{sup 3+} doped alumino silicate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Kuhn, Stefan, E-mail: stefan.kuhn84@googlemail.com; Tiegel, Mirko; Herrmann, Andreas; Rüssel, Christian [Otto-Schott-Institute of Materials Research, Jena University, Fraunhoferstr. 6, 07743 Jena (Germany); Engel, Sebastian; Wenisch, Christoph; Gräf, Stephan; Müller, Frank A. [Otto-Schott-Institute of Materials Research, Jena University, Löbdergraben 32, 07743 Jena (Germany); Körner, Jörg; Seifert, Reinhard; Yue, Fangxin; Klöpfel, Diethardt [Institute of Optics and Quantum Electronics, Jena University, Max-Wien-Platz 1, 07743 Jena (Germany); Hein, Joachim; Kaluza, Malte C. [Institute of Optics and Quantum Electronics, Jena University, Max-Wien-Platz 1, 07743 Jena (Germany); Helmholtz-Institute Jena, Fröbelstieg 3, 07743 Jena (Germany)

    2015-09-14

    In this contribution, we analyze the effect of several preparation methods of Yb{sup 3+} doped alumino silicate glasses on their quantum efficiency by using photo-acoustic measurements in comparison to standard measurement methods including the determination via the fluorescence lifetime and an integrating sphere setup. The preparation methods focused on decreasing the OH concentration by means of fluorine-substitution and/or applying dry melting atmospheres, which led to an increase in the measured fluorescence lifetime. However, it was found that the influence of these methods on radiative properties such as the measured fluorescence lifetime alone does not per se give exact information about the actual quantum efficiency of the sample. The determination of the quantum efficiency by means of fluorescence lifetime shows inaccuracies when refractive index changing elements such as fluorine are incorporated into the glass. Since fluorine not only eliminates OH from the glass but also increases the “intrinsic” radiative fluorescence lifetime, which is needed to calculate the quantum efficiency, it is difficult to separate lifetime quenching from purely radiative effects. The approach used in this contribution offers a possibility to disentangle radiative from non-radiative properties which is not possible by using fluorescence lifetime measurements alone and allows an accurate determination of the quantum efficiency of a given sample. The comparative determination by an integrating sphere setup leads to the well-known problem of reabsorption which embodies itself in the measurement of too low quantum efficiencies, especially for samples with small quantum efficiencies.

  6. An Efficient Exact Quantum Algorithm for the Integer Square-free Decomposition Problem.

    Science.gov (United States)

    Li, Jun; Peng, Xinhua; Du, Jiangfeng; Suter, Dieter

    2012-01-01

    Quantum computers are known to be qualitatively more powerful than classical computers, but so far only a small number of different algorithms have been discovered that actually use this potential. It would therefore be highly desirable to develop other types of quantum algorithms that widen the range of possible applications. Here we propose an efficient and exact quantum algorithm for finding the square-free part of a large integer - a problem for which no efficient classical algorithm exists. The algorithm relies on properties of Gauss sums and uses the quantum Fourier transform. We give an explicit quantum network for the algorithm. Our algorithm introduces new concepts and methods that have not been used in quantum information processing so far and may be applicable to a wider class of problems.

  7. An Efficient Deterministic Quantum Algorithm for the Integer Square-free Decomposition Problem

    CERN Document Server

    Li, Jun; Du, Jiangfeng; Suter, Dieter

    2011-01-01

    Quantum computers are known to be qualitatively more powerful than classical computers, but so far only a small number of different algorithms have been discovered that actually use this potential. It would therefore be highly desirable to develop other types of quantum algorithms that widen the range of possible applications. Here we propose an efficient and deterministic quantum algorithm for finding the square-free part of a large integer - a problem for which no efficient classical algorithm exists. The algorithm relies on properties of Gauss sums and uses the quantum Fourier transform. We give an explicit quantum network for the algorithm. Our algorithm introduces new concepts and methods that have not been used in quantum information processing so far and may be applicable to a wider class of problems.

  8. Apparent bandgap shift in the internal quantum efficiency for solar cells with back reflectors

    Science.gov (United States)

    Steiner, M. A.; Perl, E. E.; Geisz, J. F.; Friedman, D. J.; Jain, N.; Levi, D.; Horner, G.

    2017-04-01

    We demonstrate that in solar cells with highly reflective back mirrors, the measured internal quantum efficiency exhibits a shift in bandgap relative to the measured external quantum efficiency. The shift arises from the fact that the measured reflectance at the front surface includes a superposition of waves reflecting from the front and back surfaces. We quantify the magnitude of the apparent shift and discuss the errors that can result in determination of quantities such as the photocurrent. Because of this apparent shift, it is important the bandgap be determined from the external quantum efficiency.

  9. Quantum efficiency of InAs/InP nanowire heterostructures grown on silicon substrates

    Energy Technology Data Exchange (ETDEWEB)

    Anufriev, Roman; Chauvin, Nicolas; Bru-Chevallier, Catherine [Universite de Lyon, Institut des Nanotechnologies de Lyon (INL)-UMR5270-CNRS, INSA-Lyon, Villeurbanne (France); Khmissi, Hammadi [Universite de Monastir, Laboratoire de Micro-Optoelectronique et Nanostructures (LMON), Faculte des Sciences, Monastir (Tunisia); Naji, Khalid; Gendry, Michel [Universite de Lyon, Institut des Nanotechnologies de Lyon (INL)-UMR5270-CNRS, Ecole Centrale de Lyon, Ecully (France); Patriarche, Gilles [Laboratoire de Photonique et de Nanostructures (LPN), UPR20-CNRS, Marcoussis (France)

    2013-10-15

    Photoluminescence (PL) quantum efficiency (QE) is experimentally investigated, using an integrating sphere, as a function of excitation power on both InAs/InP quantum rod nanowires (QRod-NWs) and radial quantum well nanowires (QWell-NWs) grown on silicon substrates. The measured values of the QE are compared with those of the planar analogues such as quantum dash and quantum well samples, and found to be comparable for the quantum well structures at relatively low power density. Further studies reveal that the values of QE of the QRod-NWs and QWell-NWs are limited by the low quality of the InP NW structure and the quality of radial quantum well, respectively. (copyright 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  10. Highly Efficient Perovskite-Quantum-Dot Light-Emitting Diodes by Surface Engineering

    KAUST Repository

    Pan, Jun

    2016-08-16

    A two-step ligand-exchange strategy is developed, in which the long-carbon-chain ligands on all-inorganic perovskite (CsPbX3, X = Br, Cl) quantum dots (QDs) are replaced with halide-ion-pair ligands. Green and blue light-emitting diodes made from the halide-ion-paircapped quantum dots exhibit high external quantum efficiencies compared with the untreated QDs.

  11. A highly efficient single-photon source based on a quantum dot in a photonic nanowire

    DEFF Research Database (Denmark)

    Claudon, Julien; Bleuse, Joel; Malik, Nitin Singh

    2010-01-01

    The development of efficient solid-state sources of single photons is a major challenge in the context of quantum communication,optical quantum information processing and metrology1. Such a source must enable the implementation of a stable, single-photon emitter, like a colour centre in diamond2...... with carefully tailored ends13. Under optical pumping, we demonstrate a record source efficiency of 0.72, combined with pure single-photon emission. This non-resonant approach also provides broadband spontaneous emission control, thus offering appealing novel opportunities for the development of single-photon......–4 or a semiconductor quantum dot5–7. Achieving a high extraction efficiency has long been recognized as a major issue, and both classical solutions8 and cavity quantum electrodynamics effects have been applied1,9–12. We adopt a different approach, based on an InAs quantum dot embedded in a GaAs photonic nanowire...

  12. Optimal efficiency of quantum transport in a disordered trimer.

    Science.gov (United States)

    Giusteri, Giulio G; Celardo, G Luca; Borgonovi, Fausto

    2016-03-01

    Disordered quantum networks, such as those describing light-harvesting complexes, are often characterized by the presence of peripheral ringlike structures, where the excitation is initialized, and inner structures and reaction centers (RCs), where the excitation is trapped and transferred. The peripheral rings often display distinguished coherent features: Their eigenstates can be separated, with respect to the transfer of excitation, into two classes of superradiant and subradiant states. Both are important to optimize transfer efficiency. In the absence of disorder, superradiant states have an enhanced coupling strength to the RC, while the subradiant ones are basically decoupled from it. Static on-site disorder induces a coupling between subradiant and superradiant states, thus creating an indirect coupling to the RC. The problem of finding the optimal transfer conditions, as a function of both the RC energy and the disorder strength, is very complex even in the simplest network, namely, a three-level system. In this paper we analyze such trimeric structure, choosing as the initial condition an excitation on a subradiant state, rather than the more common choice of an excitation localized on a single site. We show that, while the optimal disorder is of the order of the superradiant coupling, the optimal detuning between the initial state and the RC energy strongly depends on system parameters: When the superradiant coupling is much larger than the energy gap between the superradiant and the subradiant levels, optimal transfer occurs if the RC energy is at resonance with the subradiant initial state, whereas we find an optimal RC energy at resonance with a virtual dressed state when the superradiant coupling is smaller than or comparable to the gap. The presence of dynamical noise, which induces dephasing and decoherence, affects the resonance structure of energy transfer producing an additional incoherent resonance peak, which corresponds to the RC energy being

  13. Modeling of detective quantum efficiency considering scatter-reduction devices

    Energy Technology Data Exchange (ETDEWEB)

    Park, Ji Woong; Kim, Dong Woon; Kim, Ho Kyung [Pusan National University, Busan (Korea, Republic of)

    2016-05-15

    The reduction of signal-to-noise ratio (SNR) cannot be restored and thus has become a severe issue in digital mammography.1 Therefore, antiscatter grids are typically used in mammography. Scatter-cleanup performance of various scatter-reduction devices, such as air gaps,2 linear (1D) or cellular (2D) grids,3, 4 and slot-scanning devices,5 has been extensively investigated by many research groups. In the present time, a digital mammography system with the slotscanning geometry is also commercially available.6 In this study, we theoretically investigate the effect of scattered photons on the detective quantum efficiency (DQE) performance of digital mammography detectors by using the cascaded-systems analysis (CSA) approach. We show a simple DQE formalism describing digital mammography detector systems equipped with scatter reduction devices by regarding the scattered photons as additive noise sources. The LFD increased with increasing PMMA thickness, and the amounts of LFD indicated the corresponding SF. The estimated SFs were 0.13, 0.21, and 0.29 for PMMA thicknesses of 10, 20, and 30 mm, respectively. While the solid line describing the measured MTF for PMMA with 0 mm was the result of least-squares of regression fit using Eq. (14), the other lines were simply resulted from the multiplication of the fit result (for PMMA with 0 mm) with the (1-SF) estimated from the LFDs in the measured MTFs. Spectral noise-power densities over the entire frequency range were not much changed with increasing scatter. On the other hand, the calculation results showed that the spectral noise-power densities increased with increasing scatter. This discrepancy may be explained by that the model developed in this study does not account for the changes in x-ray interaction parameters for varying spectral shapes due to beam hardening with increasing PMMA thicknesses.

  14. Efficient numerical solution of excitation number conserving quantum systems

    Science.gov (United States)

    Zhang, Zheyong; Ding, Jianping; Wang, Hui-Tian

    2017-08-01

    A system composed of a harmonic oscillator coupled to a two-level atom is one of the quantum systems, which can be completely solved. Although this system is simple, it is never a easy work for the quantum calculations, especially when the system consists of many such simple constituent parts. In this paper, we present a programming method, by which the calculation tasks for the matrix representation of the Hamiltonian of system can be automatically fulfilled. Coupled-cavity array systems are used to demonstrate our programming method. Some quantum properties of these systems are also discussed.

  15. Efficient Computation of Transition State Resonances and Reaction Rates from a Quantum Normal Form

    NARCIS (Netherlands)

    Schubert, Roman; Waalkens, Holger; Wiggins, Stephen

    2006-01-01

    A quantum version of a recent formulation of transition state theory in phase space is presented. The theory developed provides an algorithm to compute quantum reaction rates and the associated Gamov-Siegert resonances with very high accuracy. The algorithm is especially efficient for multi-degree-o

  16. High Efficiency Quantum Well Waveguide Solar Cells Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The long-term objective of this program is to develop flexible, lightweight, single-junction solar cells using quantum structured designs that can achieve ultra-high...

  17. High efficiency detection technology on quantum action using radiation excitation

    Energy Technology Data Exchange (ETDEWEB)

    Okubo, Masataka; Ukibe, Masahiro; Sakamoto, Isao; Hayashi, Nobuyuki; Shoji, Akira; Kobayashi, Naoto [Electrotechnical Lab., Tsukuba, Ibaraki (Japan)

    2000-02-01

    In 1998 fiscal year, as a local quasi particle loss process, it was elucidated that there was a quasi particle loss induced with magnetic flux quantum trapped by a detector on its cooling. Hitherto, it was reported that action of a tunnel junction detector was different by its magnetic history. That is, the detector had unstability such as variation of its action on its cooling. Therefore, the quasi particle loss induced by magnetic flux quantum forming cause of the unstability was quantitatively evaluated. As a result, it was elucidated that output of the detector was reduced half only by trapping the magnetic flux quantum with numbers corresponding to weak magnetic field like geomagnetism. And, this phenomenon was also described by using a model concept with quasi particle trapping due to the magnetic flux quantum. (G.K.)

  18. Efficient Quantum Information Transfer Through a Uniform Channel

    Directory of Open Access Journals (Sweden)

    Paola Verrucchi

    2011-06-01

    Full Text Available Effective quantum-state and entanglement transfer can be obtained by inducing a coherent dynamics in quantum wires with homogeneous intrawire interactions. This goal is accomplished by optimally tuning the coupling between the wire endpoints and the two qubits there attached. A general procedure to determine such value is devised, and scaling laws between the optimal coupling and the length of the wire are found. The procedure is implemented in the case of a wire consisting of a spin-1/2 XY chain: results for the time dependence of the quantities which characterize quantum-state and entanglement transfer are found of extremely good quality also for very long wires. The present approach does not require engineered intrawire interactions nor a specific initial pulse shaping, and can be applied to a vast class of quantum channels.

  19. Influence of Disassociation Probability on External Quantum Efficiency in Organic Electrophosphorescent Devices

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jian-hua; OU YANG Jun; LI Xue-yong; LI Hong-jian

    2007-01-01

    An analytical model is presented to calculate the disassociation probability and the external quantum efficiency at high field in doped organic electrophosphorescence(EPH) devices. The charge recombination process and the triplet(T)-triplet(T) annihilation processes are taken into account in this model. The influences of applied voltage and the thickness of the device on the disassociation probability, and of current density and the thickness of the device on the external quantum efficiency are studied thoroughly by including and ignoring the disassociation of excitons. It is found that the dissociation probability of excitons will come close to 1 at high electric field, and the external EPH quantum efficiency is almost the same at low electric field. There is a large discrepancy of the external EPH quantum efficiency at high electric field for including or ignoring the disassociation of excitons.

  20. High Quantum Efficiency Type II SLS FPAs for Space-Based Applications Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This Phase I SBIR proposes to develop high quantum efficiency (QE) and low dark current infrared epitaxy materials based on Type II Strained Layer Superlattice (SLS)...

  1. High Efficiency Quantum Dot III-V Multijunction Solar Cell for Space Power Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We are proposing to utilize quantum dots to develop a super high-efficiency multijunction III-V solar cell for space. In metamorphic triple junction space solar...

  2. High Quantum Efficiency 1024x1024 Longwave Infrared SLS FPA and Camera Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose a high quantum efficiency (QE) 1024x1024 longwave infrared focal plane array (LWIR FPA) and CAMERA with ~ 12 micron cutoff wavelength made from...

  3. High Quantum Efficiency Type II SLS FPAs for Space-Based Applications Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This Phase II SBIR proposes to develop high quantum efficiency (QE) and low dark current infrared epitaxy materials based on Type II Strained Layer Superlattice...

  4. Role of the superposition principle for enhancing the efficiency of the quantum-mechanical Carnot engine.

    Science.gov (United States)

    Abe, Sumiyoshi; Okuyama, Shinji

    2012-01-01

    The role of the superposition principle is discussed for the quantum-mechanical Carnot engine introduced by Bender, Brody, and Meister [J. Phys. A 33, 4427 (2000)]. It is shown that the efficiency of the engine can be enhanced by the superposition of quantum states. A finite-time process is also discussed and the condition of the maximum power output is presented. Interestingly, the efficiency at the maximum power is lower than that without superposition.

  5. Determining the internal quantum efficiency of shallow-implanted nitrogen-vacancy defects in bulk diamond

    DEFF Research Database (Denmark)

    Radko, Ilya; Boll, Mads; Israelsen, Niels Møller

    2016-01-01

    It is generally accepted that nitrogen-vacancy (NV) defects in bulk diamond are bright sources of luminescence. However, the exact value of their internal quantum efficiency (IQE) has not been measured so far. Here we use an implementation of Drexhage's scheme to quantify the IQE of shallow...... the quantum efficiency to be 0.70 ± 0.07 and 0.82 ± 0.08, respectively....

  6. Characterization of Si nanostructures using internal quantum efficiency measurements

    Energy Technology Data Exchange (ETDEWEB)

    ZAIDI,SALEEM H.

    2000-04-01

    Hemispherical reflectance and internal quantum efficiency measurements have been employed to evaluate the response of Si nanostructured surfaces formed by using random and periodic reactive ion etching techniques. Random RIE-textured surfaces have demonstrated solar weighted reflectance of {approx} 3% over 300--1,200-nm spectral range even without the benefit of anti-reflection films. Random RIE-texturing has been found to be applicable over large areas ({approximately} 180 cm{sup 2}) of both single and multicrystalline Si surfaces. Due to the surface contamination and plasma-induced damage, RIE-textured surfaces did not initially provide increased short circuit current as expected from the enhanced absorption. Improved processing combined with wet-chemical damage removal etches resulted in significant improvement in the short circuit current with IQEs comparable to the random, wet-chemically textured surfaces. An interesting feature of the RIE-textured surfaces was their superior performance in the near IR spectral range. The response of RIE-textured periodic surfaces can be broadly classified into three distinct regimes. One-dimensional grating structures with triangular profiles are characterized by exceptionally low, polarization-independent reflective behavior. The reflectance response of such surfaces is similar to a graded-index anti-reflection film. The IQE response from these surfaces is severely degraded in the UV-Visible spectral region due to plasma-induced surface damage. One-dimensional grating structures with rectangular profiles exhibit spectrally selective absorptive behavior with somewhat similar IQE response. The third type of grating structure combines broadband anti-reflection behavior with significant IQE enhancement in 800--1,200-nm spectral region. The hemispherical reflectance of these 2D grating structures is comparable to random RIE-textured surfaces. The IQE enhancement in the long wavelength spectral region can be attributed to

  7. Towards Realising Secure and Efficient Image and Video Processing Applications on Quantum Computers

    Directory of Open Access Journals (Sweden)

    Abdullah M. Iliyasu

    2013-07-01

    Full Text Available Exploiting the promise of security and efficiency that quantum computing offers, the basic foundations leading to commercial applications for quantum image processing are proposed. Two mathematical frameworks and algorithms to accomplish the watermarking of quantum images, authentication of ownership of already watermarked images and recovery of their unmarked versions on quantum computers are proposed. Encoding the images as 2n-sized normalised Flexible Representation of Quantum Images (FRQI states, with n-qubits and 1-qubit dedicated to capturing the respective information about the colour and position of every pixel in the image respectively, the proposed algorithms utilise the flexibility inherent to the FRQI representation, in order to confine the transformations on an image to any predetermined chromatic or spatial (or a combination of both content of the image as dictated by the watermark embedding, authentication or recovery circuits. Furthermore, by adopting an apt generalisation of the criteria required to realise physical quantum computing hardware, three standalone components that make up the framework to prepare, manipulate and recover the various contents required to represent and produce movies on quantum computers are also proposed. Each of the algorithms and the mathematical foundations for their execution were simulated using classical (i.e., conventional or non-quantum computing resources, and their results were analysed alongside other longstanding classical computing equivalents. The work presented here, combined together with the extensions suggested, provide the basic foundations towards effectuating secure and efficient classical-like image and video processing applications on the quantum-computing framework.

  8. Efficiency and Coherence of Quantum-Dot Single-Photon Sources

    DEFF Research Database (Denmark)

    Madsen, Marta Arcari

    The main goal of the project has been to realize an efficient source of coherent single photons by coupling a self-assembled quantum dot to a photonic crystal waveguide. Such a source would have a wide range of applications in the field of quantum information processing. By studying the coupling...... on this result, we improved the design of the photonic crystal waveguide, and we characterized in detail the efficiency of the device and the coherence of the emitted single photons. We investigate the decoherence mechanisms affecting the quantum dots by performing resonance fluorescence experiments on emitters...... of a single charge. A very high degree of coherence can be achieved by embedding quantum dots in electrically gated samples. We show that a single quantum dot behaves like a nearly-ideal two-level system in a sample with electrical gates, and single photons emitted up to 1 μs apart show indistinguishability...

  9. Efficient quantum computation in a network with probabilistic gates and logical encoding

    DEFF Research Database (Denmark)

    Borregaard, J.; Sørensen, A. S.; Cirac, J. I.

    2017-01-01

    An approach to efficient quantum computation with probabilistic gates is proposed and analyzed in both a local and nonlocal setting. It combines heralded gates previously studied for atom or atomlike qubits with logical encoding from linear optical quantum computation in order to perform high......-fidelity quantum gates across a quantum network. The error-detecting properties of the heralded operations ensure high fidelity while the encoding makes it possible to correct for failed attempts such that deterministic and high-quality gates can be achieved. Importantly, this is robust to photon loss, which...... is typically the main obstacle to photonic-based quantum information processing. Overall this approach opens a path toward quantum networks with atomic nodes and photonic links....

  10. Multipulse addressing of a Raman quantum memory: configurable beam splitting and efficient readout.

    Science.gov (United States)

    Reim, K F; Nunn, J; Jin, X-M; Michelberger, P S; Champion, T F M; England, D G; Lee, K C; Kolthammer, W S; Langford, N K; Walmsley, I A

    2012-06-29

    Quantum memories are vital to the scalability of photonic quantum information processing (PQIP), since the storage of photons enables repeat-until-success strategies. On the other hand, the key element of all PQIP architectures is the beam splitter, which allows us to coherently couple optical modes. Here, we show how to combine these crucial functionalities by addressing a Raman quantum memory with multiple control pulses. The result is a coherent optical storage device with an extremely large time bandwidth product, that functions as an array of dynamically configurable beam splitters, and that can be read out with arbitrarily high efficiency. Networks of such devices would allow fully scalable PQIP, with applications in quantum computation, long distance quantum communications and quantum metrology.

  11. Efficient Three-Party Quantum Dialogue Protocol Based on the Continuous Variable GHZ States

    Science.gov (United States)

    Yu, Zhen-Bo; Gong, Li-Hua; Zhu, Qi-Biao; Cheng, Shan; Zhou, Nan-Run

    2016-07-01

    Based on the continuous variable GHZ entangled states, an efficient three-party quantum dialogue protocol is devised, where each legitimate communication party could simultaneously deduce the secret information of the other two parties with perfect efficiency. The security is guaranteed by the correlation of the continuous variable GHZ entangled states and the randomly selected decoy states. Furthermore, the three-party quantum dialogue protocol is directly generalized to an N-party quantum dialogue protocol by using the n-tuple continuous variable GHZ entangled states.

  12. Terahertz Quantum Cascade Laser With Efficient Coupling and Beam Profile

    Science.gov (United States)

    Chattopadhyay, Goutam; Kawamura, Jonathan H.; Lin, Robert H.; Williams, Benjamin

    2012-01-01

    Quantum cascade lasers (QCLs) are unipolar semiconductor lasers, where the wavelength of emitted radiation is determined by the engineering of quantum states within the conduction band in coupled multiple-quantum-well heterostructures to have the desired energy separation. The recent development of terahertz QCLs has provided a new generation of solid-state sources for radiation in the terahertz frequency range. Terahertz QCLs have been demonstrated from 0.84 to 5.0 THz both in pulsed mode and continuous wave mode (CW mode). The approach employs a resonant-phonon depopulation concept. The metal-metal (MM) waveguide fabrication is performed using Cu-Cu thermo-compression bonding to bond the GaAs/AlGaAs epitaxial layer to a GaAs receptor wafer.

  13. Modeling of dilute nitride cascaded quantum well solar cells for high efficiency photovoltaics

    Science.gov (United States)

    Vijaya, G.; Alemu, A.; Freundlich, A.

    2013-03-01

    III-V Dilute Nitride multi-quantum well structures are currently promising candidates to achieve 1 sun efficiencies of cell in a 4 junction configuration could yield 1 sun efficiencies greater than 40%. However for a conventional deep well design the characteristic carrier escape times could exceed that of radiative recombination hence limiting the current output of the cell, as has been indicated by prior experiments. In order to increase the current extraction here we evaluate the performance of a cascaded quantum well design whereby a thermally assisted resonant tunneling process is used to accelerate the carrier escape process (efficiency. The quantum efficiency of a p-i-n subcell where a periodic sequence of quantum wells with well and barrier thicknesses adjusted for the sequential extraction operation is calculated using a 2D drift diffusion model and taking into account absorption properties of resulting MQWs. The calculation also accounts for the E-field induced modifications of absorption properties and quantization in quantum wells. The results are then accounted for to calculate efficiencies for the proposed 4 junction design, and indicate potential for reaching efficiencies in excess of this structure is above 42% (1 sun) and above 50% (500 sun) AM1.5.

  14. Origin of low quantum efficiency of photoluminescence of InP/ZnS nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Shirazi, Roza, E-mail: rozas@fotonik.dtu.dk [Department of Photonics Engineering, Technical University of Denmark, Oersted Plads 343, 2800 Kgs Lyngby (Denmark); Kovacs, Andras [Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons, Peter Grunberg Institute, Forschungszentrum Julich, 52425 Julich (Germany); Dan Corell, Dennis [Department of Photonics Engineering, Technical University of Denmark, Riso, Frederiksborgvej 399, 4000 Roskilde (Denmark); Gritti, Claudia [Department of Photonics Engineering, Technical University of Denmark, Oersted Plads 343, 2800 Kgs Lyngby (Denmark); Thorseth, Anders; Dam-Hansen, Carsten; Michael Petersen, Paul [Department of Photonics Engineering, Technical University of Denmark, Riso, Frederiksborgvej 399, 4000 Roskilde (Denmark); Kardynal, Beata [Department of Photonics Engineering, Technical University of Denmark, Oersted Plads 343, 2800 Kgs Lyngby (Denmark); PGI-9, Forschungszentrum Julich, JARA FIT, 52425 Julich (Germany)

    2014-01-15

    In this paper, we study the origin of a strong wavelength dependence of the quantum efficiency of InP/ZnS nanocrystals. We find that while the average size of the nanocrystals increased by 50%, resulting in longer emission wavelength, the quantum efficiency drops more than one order of magnitude compared to the quantum efficiency of the small nanocrystals. By correlating this result with the time-resolved photoluminescence we find that the reduced photoluminescence efficiency is caused by a fast growing fraction of non-emissive nanocrystals while the quality of the nanocrystals that emit light is similar for all samples. Transmission electron microscopy reveals the polycrystalline nature of many of the large nanocrystals, pointing to the grain boundaries as one possible site for the photoluminescence quenching defects. -- Highlights: • We investigate drop of quantum efficiency of InP/ZnS nanocrystals emitting at longer wavelengths. • We correlate quantum efficiency measurements with time-resolved carrier dynamics. • We find that only a small fraction of larger nanocrystals is optically active.

  15. Enhancing Otto-Mobile Efficiency via Addition of a Quantum Carnot Cycle

    Science.gov (United States)

    Opatrný, Tomáš; Scully, Marlan O.

    2003-09-01

    It was shown recently that one can improve the efficiency of the Otto cycle by taking advantage of the internal degrees of freedom of an ideal gas [M. O. Scully, “The Quantum Afterburner”, Phys. Rev. Lett., to be published]. Here we discuss the limiting improvement of the efficiency by considering reversible cycles with both internal and external degrees of freedom.

  16. Efficiency and Coherence of Quantum-Dot Single-Photon Sources

    DEFF Research Database (Denmark)

    Madsen, Marta Arcari

    of single quantum dots to the waveguide, we demonstrate that the emitters are coupled with near-unity efficiency to the waveguide mode. We measure a coupling efficiency (β-factor) as high as 98.4% close to the band-edge of the waveguide mode, and β-factors above 90% over a bandwidth of 20 nm. Based...

  17. Efficient mode conversion in an optical nanoantenna mediated by quantum emitters

    CERN Document Server

    Straubel, Jakob; Rockstuhl, Carsten; Slowik, Karolina

    2016-01-01

    Converting signals between different electromagnetic modes is an asset for future information technologies. In general, slightly asymmetric optical nanoantennas enable the coupling between bright and dark modes sustained by an optical nanoantenna. However, the conversion efficiency might be very low. Here, we show that the additional incorporation of a quantum emitter allows to tremendously enhance this efficiency. The enhanced local density of states cycles the quantum emitter between its upper and lower level at an extremely hight rate; hence converting the energy very efficient. The process is robust with respect to possible experimental tolerances and adds a new ingredient to be exploited while studying and applying coupling phenomena in optical nanosystems.

  18. High heralding-efficiency of near-IR fiber coupled photon pairs for quantum technologies

    Energy Technology Data Exchange (ETDEWEB)

    Dixon, P. Ben [Massachusetts Institute of Technology (MIT); Murphy, Ryan [Lincoln Laboratory, Massachusetts Institute of Technology (MIT); Rosenberg, Danna [Massachusetts Institute of Technology (MIT); Grein, Matthew E. [Massachusetts Institute of Technology (MIT); Stelmakh, Veronika [Massachusetts Institute of Technology (MIT); Bennink, Ryan S [ORNL; Wong, Franco N. C. [Massachusetts Institute of Technology (MIT)

    2015-01-01

    We report on the development and use of a high heralding-efficiency, single-mode-fiber coupled telecom-band source of entangled photons for quantum technology applications. The source development efforts consisted of theoretical and experimental efforts and we demonstrated a correlated-mode coupling efficiency of 97% 2%, the highest efficiency yet achieved for this type of system. We then incorporated these beneficial source development techniques in a Sagnac configured telecom-band entangled photon source that generates photon pairs entangled in both time/energy and polarization degrees of freedom. We made use of these highly desirable entangled states to investigate several promising quantum technologies.

  19. Multiple-exciton generation in lead selenide nanorod solar cells with external quantum efficiencies exceeding 120%

    Science.gov (United States)

    Davis, Nathaniel J. L. K.; Böhm, Marcus L.; Tabachnyk, Maxim; Wisnivesky-Rocca-Rivarola, Florencia; Jellicoe, Tom C.; Ducati, Caterina; Ehrler, Bruno; Greenham, Neil C.

    2015-01-01

    Multiple-exciton generation—a process in which multiple charge-carrier pairs are generated from a single optical excitation—is a promising way to improve the photocurrent in photovoltaic devices and offers the potential to break the Shockley–Queisser limit. One-dimensional nanostructures, for example nanorods, have been shown spectroscopically to display increased multiple exciton generation efficiencies compared with their zero-dimensional analogues. Here we present solar cells fabricated from PbSe nanorods of three different bandgaps. All three devices showed external quantum efficiencies exceeding 100% and we report a maximum external quantum efficiency of 122% for cells consisting of the smallest bandgap nanorods. We estimate internal quantum efficiencies to exceed 150% at relatively low energies compared with other multiple exciton generation systems, and this demonstrates the potential for substantial improvements in device performance due to multiple exciton generation. PMID:26411283

  20. Multiple-exciton generation in lead selenide nanorod solar cells with external quantum efficiencies exceeding 120.

    Science.gov (United States)

    Davis, Nathaniel J L K; Böhm, Marcus L; Tabachnyk, Maxim; Wisnivesky-Rocca-Rivarola, Florencia; Jellicoe, Tom C; Ducati, Caterina; Ehrler, Bruno; Greenham, Neil C

    2015-09-28

    Multiple-exciton generation-a process in which multiple charge-carrier pairs are generated from a single optical excitation-is a promising way to improve the photocurrent in photovoltaic devices and offers the potential to break the Shockley-Queisser limit. One-dimensional nanostructures, for example nanorods, have been shown spectroscopically to display increased multiple exciton generation efficiencies compared with their zero-dimensional analogues. Here we present solar cells fabricated from PbSe nanorods of three different bandgaps. All three devices showed external quantum efficiencies exceeding 100% and we report a maximum external quantum efficiency of 122% for cells consisting of the smallest bandgap nanorods. We estimate internal quantum efficiencies to exceed 150% at relatively low energies compared with other multiple exciton generation systems, and this demonstrates the potential for substantial improvements in device performance due to multiple exciton generation.

  1. Efficient measurement of quantum gate error by interleaved randomized benchmarking.

    Science.gov (United States)

    Magesan, Easwar; Gambetta, Jay M; Johnson, B R; Ryan, Colm A; Chow, Jerry M; Merkel, Seth T; da Silva, Marcus P; Keefe, George A; Rothwell, Mary B; Ohki, Thomas A; Ketchen, Mark B; Steffen, M

    2012-08-24

    We describe a scalable experimental protocol for estimating the average error of individual quantum computational gates. This protocol consists of interleaving random Clifford gates between the gate of interest and provides an estimate as well as theoretical bounds for the average error of the gate under test, so long as the average noise variation over all Clifford gates is small. This technique takes into account both state preparation and measurement errors and is scalable in the number of qubits. We apply this protocol to a superconducting qubit system and find a bounded average error of 0.003 [0,0.016] for the single-qubit gates X(π/2) and Y(π/2). These bounded values provide better estimates of the average error than those extracted via quantum process tomography.

  2. Efficient algorithms for the laboratory discovery of optimal quantum controls.

    Science.gov (United States)

    Turinici, Gabriel; Le Bris, Claude; Rabitz, Herschel

    2004-01-01

    The laboratory closed-loop optimal control of quantum phenomena, expressed as minimizing a suitable cost functional, is currently implemented through an optimization algorithm coupled to the experimental apparatus. In practice, the most commonly used search algorithms are variants of genetic algorithms. As an alternative choice, a direct search deterministic algorithm is proposed in this paper. For the simple simulations studied here, it outperforms the existing approaches. An additional algorithm is introduced in order to reveal some properties of the cost functional landscape.

  3. Efficient spray-coated colloidal quantum dot solar cells

    KAUST Repository

    Kramer, Illan J.

    2014-11-10

    (Figure Presented). A colloidal quantum dot solar cell is fabricated by spray-coating under ambient conditions. By developing a room-temperature spray-coating technique and implementing a fully automated process with near monolayer control - an approach termed as sprayLD - an electronic defect is eliminated resulting in solar cell performance and statistical distribution superior to prior batch-processed methods along with a hero performance of 8.1%.

  4. Nanopatterned Quantum Dot Lasers for High Speed, High Efficiency, Operation

    Science.gov (United States)

    2015-04-27

    SUBTITLE 13. SUPPLEMENTARY NOTES 12. DISTRIBUTION AVAILIBILITY STATEMENT 6. AUTHORS 7. PERFORMING ORGANIZATION NAMES AND ADDRESSES 15. SUBJECT TERMS ...growth using metalorganic chemical vapor deposition (MOCVD). These methods allowed us to realize quantum dot active regions in which the injected carriers...temperature sensitivity , commonly observed in self-assembled QD lasers2. An alternate approach to SK QD formation is the use of nanopatterning with

  5. Efficient optimal minimum error discrimination of symmetric quantum states

    Science.gov (United States)

    Assalini, Antonio; Cariolaro, Gianfranco; Pierobon, Gianfranco

    2010-01-01

    This article deals with the quantum optimal discrimination among mixed quantum states enjoying geometrical uniform symmetry with respect to a reference density operator ρ0. It is well known that the minimal error probability is given by the positive operator-valued measure obtained as a solution of a convex optimization problem, namely a set of operators satisfying geometrical symmetry, with respect to a reference operator Π0 and maximizing Tr(ρ0Π0). In this article, by resolving the dual problem, we show that the same result is obtained by minimizing the trace of a semidefinite positive operator X commuting with the symmetry operator and such that X⩾ρ0. The new formulation gives a deeper insight into the optimization problem and allows to obtain closed-form analytical solutions, as shown by a simple but not trivial explanatory example. In addition to the theoretical interest, the result leads to semidefinite programming solutions of reduced complexity, allowing to extend the numerical performance evaluation to quantum communication systems modeled in Hilbert spaces of large dimension.

  6. Core/shell quantum dot based luminescent solar concentrators with reduced reabsorption and enhanced efficiency.

    Science.gov (United States)

    Coropceanu, Igor; Bawendi, Moungi G

    2014-07-09

    CdSe/CdS core/shell quantum dots (QDs) have been optimized toward luminescent solar concentration (LSC) applications. Systematically increasing the shell thickness continuously reduced reabsorption up to a factor of 45 for the thickest QDs studied (with ca. 14 monolayers of CdS) compared to the initial CdSe cores. Moreover, an improved synthetic method was developed that retains a high-fluorescence quantum yield, even for particles with the thickest shell volume, for which a quantum yield of 86% was measured in solution. These high quantum yield thick shell quantum dots were embedded in a polymer matrix, yielding highly transparent composites to serve as prototype LSCs, which exhibited an optical efficiency as high as 48%. A Monte Carlo simulation was developed to model LSC performance and to identify the major loss channels for LSCs incorporating the materials developed. The results of the simulation are in excellent agreement with the experimental data.

  7. Quantum Dots Promise to Significantly Boost Solar Cell Efficiencies (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2013-08-01

    In the search for a third generation of solar-cell technologies, a leading candidate is the use of 'quantum dots' -- tiny spheres of semiconductor material measuring only about 2-10 billionths of a meter in diameter. Quantum dots have the potential to dramatically increase the efficiency of converting sunlight into energy -- perhaps even doubling it in some devices -- because of their ability to generate more than one bound electron-hole pair, or exciton, per incoming photon. NREL has produced quantum dots using colloidal suspensions; then, using molecular self-assembly, they have been fabricated into the first-ever quantum-dot solar cells. While these devices operate with only 4.4% efficiency, they demonstrate the capability for low-cost manufacturing.

  8. Conversion efficiency of an energy harvester based on resonant tunneling through quantum dots with heat leakage

    Science.gov (United States)

    Kano, Shinya; Fujii, Minoru

    2017-03-01

    We study the conversion efficiency of an energy harvester based on resonant tunneling through quantum dots with heat leakage. Heat leakage current from a hot electrode to a cold electrode is taken into account in the analysis of the harvester operation. Modeling of electrical output indicates that a maximum heat leakage current is not negligible because it is larger than that of the heat current harvested into electrical power. A reduction of heat leakage is required in this energy harvester in order to obtain efficient heat-to-electrical conversion. Multiple energy levels of a quantum dot can increase the output power of the harvester. Heavily doped colloidal semiconductor quantum dots are a possible candidate for a quantum-dot monolayer in the energy harvester to reduce heat leakage, scaling down device size, and increasing electrical output via multiple discrete energy levels.

  9. A Highly Efficient Hybrid GaAs Solar Cell Based on Colloidal-Quantum-Dot-Sensitization

    Science.gov (United States)

    Han, Hau-Vei; Lin, Chien-Chung; Tsai, Yu-Lin; Chen, Hsin-Chu; Chen, Kuo-Ju; Yeh, Yun-Ling; Lin, Wen-Yi; Kuo, Hao-Chung; Yu, Peichen

    2014-07-01

    This paper presents a hybrid design, featuring a traditional GaAs-based solar cell combined with various colloidal quantum dots. This hybrid design effectively boosts photon harvesting at long wavelengths while enhancing the collection of photogenerated carriers in the ultraviolet region. The merits of using highly efficient semiconductor solar cells and colloidal quantum dots were seamlessly combined to increase overall power conversion efficiency. Several photovoltaic parameters, including short-circuit current density, open circuit voltage, and external quantum efficiency, were measured and analyzed to investigate the performance of this hybrid device. Offering antireflective features at long wavelengths and luminescent downshifting for high-energy photons, the quantum dots effectively enhanced overall power conversion efficiency by as high as 24.65% compared with traditional GaAs-based devices. The evolution of weighted reflectance as a function of the dilution factor of QDs was investigated. Further analysis of the quantum efficiency response showed that the luminescent downshifting effect can be as much as 6.6% of the entire enhancement of photogenerated current.

  10. External Quantum Efficiency Improvement with Luminescent Downshifting Layers: Experimental and Modelling

    OpenAIRE

    Ahmed, H.; S. J. McCormack; Doran, J.

    2016-01-01

    Core-shell quantum dots CdSe/ZnS and lumogen yellow organic dye are characterized by their inclusion in luminescent downshifting (LDS) layers. Layers were deposited on top of crystalline silicon cell (c-Si), dye synthesized solar cell (DSSC), and cadmium telluride (CdTe) minimodules. External quantum efficiency measurements for the solar cell/LDS devices are discussed. Experimental results were compared with an optical model developed by Rothemund, 2014.

  11. External Quantum Efficiency Improvement with Luminescent Downshifting Layers: Experimental and Modelling

    Directory of Open Access Journals (Sweden)

    H. Ahmed

    2016-01-01

    Full Text Available Core-shell quantum dots CdSe/ZnS and lumogen yellow organic dye are characterized by their inclusion in luminescent downshifting (LDS layers. Layers were deposited on top of crystalline silicon cell (c-Si, dye synthesized solar cell (DSSC, and cadmium telluride (CdTe minimodules. External quantum efficiency measurements for the solar cell/LDS devices are discussed. Experimental results were compared with an optical model developed by Rothemund, 2014.

  12. Efficient quantum dialogue using entangled states and entanglement swapping without information leakage

    Science.gov (United States)

    Wang, He; Zhang, Yu Qing; Liu, Xue Feng; Hu, Yu Pu

    2016-06-01

    We propose a novel quantum dialogue protocol by using the generalized Bell states and entanglement swapping. In the protocol, a sequence of ordered two-qutrit entangled states acts as quantum information channel for exchanging secret messages directly and simultaneously. Besides, a secret key string is shared between the communicants to overcome information leakage. Different from those previous information leakage-resistant quantum dialogue protocols, the particles, composed of one of each pair of entangled states, are transmitted only one time in the proposed protocol. Security analysis shows that our protocol can overcome information leakage and resist several well-known attacks. Moreover, the efficiency of our scheme is acceptable.

  13. Efficient Modeling of Coulomb Interaction Effect on Exciton in Crystal-Phase Nanowire Quantum Dot

    DEFF Research Database (Denmark)

    Taherkhani, Masoomeh; Gregersen, Niels; Mørk, Jesper

    2016-01-01

    The binding energy and oscillation strength of the ground-state exciton in type-II quantum dot (QD) is calculated by using a post Hartree-Fock method known as the configuration interaction (CI) method which is significantly more efficient than conventional methods like ab initio method. We show t...... that the Coulomb interaction between electron and holes in these structures considerably affects the transition dipole moment which is the key parameter of optical quantum gating in STIRAP (stimulated Raman adiabatic passage) process for implementing quantum gates [1], [2]....

  14. Fluorescent porous silicon biological probes with high quantum efficiency and stability.

    Science.gov (United States)

    Tu, Chang-Ching; Chou, Ying-Nien; Hung, Hsiang-Chieh; Wu, Jingda; Jiang, Shaoyi; Lin, Lih Y

    2014-12-01

    We demonstrate porous silicon biological probes as a stable and non-toxic alternative to organic dyes or cadmium-containing quantum dots for imaging and sensing applications. The fluorescent silicon quantum dots which are embedded on the porous silicon surface are passivated with carboxyl-terminated ligands through stable Si-C covalent bonds. The porous silicon bio-probes have shown photoluminescence quantum yield around 50% under near-UV excitation, with high photochemical and thermal stability. The bio-probes can be efficiently conjugated with antibodies, which is confirmed by a standard enzyme-linked immunosorbent assay (ELISA) method.

  15. Efficient Raman generation in a waveguide: A route to ultrafast quantum random number generation

    Science.gov (United States)

    England, D. G.; Bustard, P. J.; Moffatt, D. J.; Nunn, J.; Lausten, R.; Sussman, B. J.

    2014-02-01

    The inherent uncertainty in quantum mechanics offers a source of true randomness which can be used to produce unbreakable cryptographic keys. We discuss the development of a high-speed random number generator based on the quantum phase fluctuations in spontaneously initiated stimulated Raman scattering (SISRS). We utilize the tight confinement and long interaction length available in a Potassium Titanyl Phosphate waveguide to generate highly efficient SISRS using nanojoule pulse energies, reducing the high pump power requirements of the previous approaches. We measure the random phase of the Stokes output using a simple interferometric setup to yield quantum random numbers at 145 Mbps.

  16. Efficiency dip observed with InGaN-based multiple quantum well solar cells

    KAUST Repository

    Lai, Kunyu

    2014-01-01

    The dip of external quantum efficiency (EQE) is observed on In0.15Ga0.85N/GaN multiple quantum well (MQW) solar cells upon the increase of incident optical power density. With indium composition increased to 25%, the EQE dip becomes much less noticeable. The composition dependence of EQE dip is ascribed to the competition between radiative recombination and photocurrent generation in the active region, which are dictated by quantum-confined Stark effect (QCSE) and composition fluctuation in the MQWs.

  17. An efficient quantum scheme for Private Set Intersection

    Science.gov (United States)

    Shi, Run-hua; Mu, Yi; Zhong, Hong; Cui, Jie; Zhang, Shun

    2016-01-01

    Private Set Intersection allows a client to privately compute set intersection with the collaboration of the server, which is one of the most fundamental and key problems within the multiparty collaborative computation of protecting the privacy of the parties. In this paper, we first present a cheat-sensitive quantum scheme for Private Set Intersection. Compared with classical schemes, our scheme has lower communication complexity, which is independent of the size of the server's set. Therefore, it is very suitable for big data services in Cloud or large-scale client-server networks.

  18. Photoluminescence efficiency in AlGaN quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Tamulaitis, G.; Mickevičius, J. [Institute of Applied Research and Semiconductor Physics Department, Vilnius University, Sauletekio av. 9-III, Vilnius LT-10222 (Lithuania); Jurkevičius, J., E-mail: jonas.jurkevicius@ff.vu.lt [Institute of Applied Research and Semiconductor Physics Department, Vilnius University, Sauletekio av. 9-III, Vilnius LT-10222 (Lithuania); Shur, M.S. [Department of ECE and CIE, Rensselaer Polytechnic Institute (United States); Shatalov, M.; Yang, J.; Gaska, R. [Sensor Electronic Technology, Inc. (United States)

    2014-11-15

    Photoluminescence spectroscopy of AlGaN/AlGaN multiple quantum wells under quasi-steady-state conditions in the temperature range from 8 to 300 K revealed a strong dependence of droop onset threshold on temperature that was explained by the influence of carrier delocalization. The delocalization at room temperature results predominantly in enhancement of bimolecular radiative recombination, while being favorable for enhancement of nonradiative recombination at low temperatures. Studies of stimulated emission confirmed the strong influence of carrier localization on droop.

  19. Temperature dependence of quantum efficiency of Schottky diodes based on 4H-SiC

    CERN Document Server

    Blank, T V; Kalinina, E V; Konstantinov, O V; Konstantinov, A O; Hallen, A

    2001-01-01

    The metal-semiconductor structures, which made it possible to create the photoreceivers of the Cr-4H-SiC ultraviolet radiation with the photosensitivity maximum by 4.9 eV and quantum efficiency up to 0.3 were manufactured on the basis of the n-4H-SiC pure epitaxial layer. The experimental study on the temperature dependence of the quantum efficiency of the photoelectric transformation showed, that by the photons energy of 3.4-4.7 eV and the temperatures above 300 K there takes place fast growth of the quantum efficiency with growth of temperatures, which is conditioned by participation of the phonons in the indirect interzonal transitions

  20. An efficient quantum mechanical method for radical pair recombination reactions

    Science.gov (United States)

    Lewis, Alan M.; Fay, Thomas P.; Manolopoulos, David E.

    2016-12-01

    The standard quantum mechanical expressions for the singlet and triplet survival probabilities and product yields of a radical pair recombination reaction involve a trace over the states in a combined electronic and nuclear spin Hilbert space. If this trace is evaluated deterministically, by performing a separate time-dependent wavepacket calculation for each initial state in the Hilbert space, the computational effort scales as O (Z2log ⁡Z ) , where Z is the total number of nuclear spin states. Here we show that the trace can also be evaluated stochastically, by exploiting the properties of spin coherent states. This results in a computational effort of O (M Z log ⁡Z ) , where M is the number of Monte Carlo samples needed for convergence. Example calculations on a strongly coupled radical pair with Z >106 show that the singlet yield can be converged to graphical accuracy using just M =200 samples, resulting in a speed up by a factor of >5000 over a standard deterministic calculation. We expect that this factor will greatly facilitate future quantum mechanical simulations of a wide variety of radical pairs of interest in chemistry and biology.

  1. Scales of Time Where the Quantum Discord Allows an Efficient Execution of the DQC1 Algorithm

    Directory of Open Access Journals (Sweden)

    M. Ávila

    2014-01-01

    Full Text Available The power of one qubit deterministic quantum processor (DQC1 (Knill and Laflamme (1998 generates a nonclassical correlation known as quantum discord. The DQC1 algorithm executes in an efficient way with a characteristic time given by τ=Tr[Un]/2n, where Un is an n qubit unitary gate. For pure states, quantum discord means entanglement while for mixed states such a quantity is more than entanglement. Quantum discord can be thought of as the mutual information between two systems. Within the quantum discord approach the role of time in an efficient evaluation of τ is discussed. It is found that the smaller the value of t/T is, where t is the time of execution of the DQC1 algorithm and T is the scale of time where the nonclassical correlations prevail, the more efficient the calculation of τ is. A Mösbauer nucleus might be a good processor of the DQC1 algorithm while a nuclear spin chain would not be efficient for the calculation of τ.

  2. The effects of different quantum feedback operator types on the parameter precision of detection efficiency in optimal quantum estimation

    Science.gov (United States)

    Ma, Shao-Qiang; Zhu, Han-Jie; Zhang, Guo-Feng

    2017-04-01

    The effects of different quantum feedback types on the estimation precision of the detection efficiency are studied. It is found that the precision can be more effective enhanced by a certain feedback type through comparing these feedbacks and the precision has a positive relation with detection efficiency for the optimal feedback when the system reach the state of dynamic balance. In addition, the bigger the proportion of |1> is the higher the precision is and we will not obtain any information about the parameter to be estimated if |0> is chosen as initial state for the feedback type λσz.

  3. A highly efficient single-photon source based on a quantum dot in a photonic nanowire

    DEFF Research Database (Denmark)

    Claudon, Julien; Bleuse, Joel; Malik, Nitin Singh

    2010-01-01

    The development of efficient solid-state sources of single photons is a major challenge in the context of quantum communication,optical quantum information processing and metrology1. Such a source must enable the implementation of a stable, single-photon emitter, like a colour centre in diamond2...... with carefully tailored ends13. Under optical pumping, we demonstrate a record source efficiency of 0.72, combined with pure single-photon emission. This non-resonant approach also provides broadband spontaneous emission control, thus offering appealing novel opportunities for the development of single...

  4. High Efficiency Hybrid Solar Cells Using Nanocrystalline Si Quantum Dots and Si Nanowires.

    Science.gov (United States)

    Dutta, Mrinal; Thirugnanam, Lavanya; Trinh, Pham Van; Fukata, Naoki

    2015-07-28

    We report on an efficient hybrid Si nanocrystal quantum dot modified radial p-n junction thinner Si solar cell that utilizes the advantages of effective exciton collection by energy transfer from nanocrystal-Si (nc-Si) quantum dots to underlying radial p-n junction Si nanowire arrays with excellent carrier separation and propagation via the built-in electric fields of radial p-n junctions. Minimization of recombination, optical, and spectrum losses in this hybrid structure led to a high cell efficiency of 12.9%.

  5. Very Efficient Single-Photon Sources Based on Quantum Dots in Photonic Wires

    DEFF Research Database (Denmark)

    Gerard, Jean-Michel; Claudon, Julien; Bleuse, Joel

    2014-01-01

    We review the recent development of high efficiency single photon sources based on a single quantum dot in a photonic wire. Unlike cavity-based devices, very pure single photon emission and efficiencies exceeding 0.7 photon per pulse are jointly demonstrated under non-resonant pumping conditions....... By placing a tip-shaped or trumpet-like tapering at the output end of the wire, a highly directional Gaussian far-field emission pattern is obtained. More generally, a photonic wire containing a quantum dot appears as an attractive template to explore and exploit in a solid-state system the unique optical...

  6. Efficient algorithms for large-scale quantum transport calculations

    Science.gov (United States)

    Brück, Sascha; Calderara, Mauro; Bani-Hashemian, Mohammad Hossein; VandeVondele, Joost; Luisier, Mathieu

    2017-08-01

    Massively parallel algorithms are presented in this paper to reduce the computational burden associated with quantum transport simulations from first-principles. The power of modern hybrid computer architectures is harvested in order to determine the open boundary conditions that connect the simulation domain with its environment and to solve the resulting Schrödinger equation. While the former operation takes the form of an eigenvalue problem that is solved by a contour integration technique on the available central processing units (CPUs), the latter can be cast into a linear system of equations that is simultaneously processed by SplitSolve, a two-step algorithm, on general-purpose graphics processing units (GPUs). A significant decrease of the computational time by up to two orders of magnitude is obtained as compared to standard solution methods.

  7. A Novel Implementation of Efficient Algorithms for Quantum Circuit Synthesis

    Science.gov (United States)

    Zeller, Luke

    In this project, we design and develop a computer program to effectively approximate arbitrary quantum gates using the discrete set of Clifford Gates together with the T gate (π/8 gate). Employing recent results from Mosca et. al. and Giles and Selinger, we implement a decomposition scheme that outputs a sequence of Clifford, T, and Tt gates that approximate the input to within a specified error range ɛ. Specifically, the given gate is first rounded to an element of Z[1/2, i] with a precision determined by ɛ, and then exact synthesis is employed to produce the resulting gate. It is known that this procedure is optimal in approximating an arbitrary single qubit gate. Our program, written in Matlab and Python, can complete both approximate and exact synthesis of qubits. It can be used to assist in the experimental implementation of an arbitrary fault-tolerant single qubit gate, for which direct implementation isn't feasible.

  8. Robust and Efficient Sifting-Less Quantum Key Distribution Protocols

    CERN Document Server

    Grosshans, Frédéric

    2009-01-01

    We show that replacing the usual sifting step of the standard quantum-key-distribution protocol BB84 by a one-way reverse reconciliation procedure increases its robustness against photon-number-splitting (PNS) attacks to the level of the SARG04 protocol while keeping the raw key-rate of BB84. This protocol, which uses the same state and detection than BB84, is the m=4 member of a protocol-family using m polarization states which we introduce here. We show that the robustness of these protocols against PNS attacks increases exponentially with m, and that the effective keyrate of optimized weak coherent pulses decreases with the transmission T like T^{1+1/(m-2)}.

  9. Scaling-up quantum heat engines efficiently via shortcuts to adiabaticity

    CERN Document Server

    Beau, M; del Campo, A

    2016-01-01

    The finite-time operation of a quantum heat engine that uses a single particle as a working medium generally increases the output power at the expense of inducing friction that lowers the cycle efficiency. We propose to scale up a quantum heat engine utilizing a many-particle working medium in combination with the use of shortcuts to adiabaticity to boost the nonadiabatic performance by eliminating quantum friction and reducing the cycle time. To this end, we first analyze the finite-time thermodynamics of a quantum Otto cycle implemented with a quantum fluid confined in a time-dependent harmonic trap. We show that nonadiabatic effects can be controlled and tailored to match the adiabatic performance using a variety of shortcuts to adiabaticity. As a result, the nonadiabatic dynamics of the scaled-up many-particle quantum heat engine exhibits no friction and the cycle can be run at maximum efficiency with a tunable output power. We demonstrate our results with a working medium consisting of particles with inv...

  10. Scaling-Up Quantum Heat Engines Efficiently via Shortcuts to Adiabaticity

    Directory of Open Access Journals (Sweden)

    Mathieu Beau

    2016-04-01

    Full Text Available The finite-time operation of a quantum heat engine that uses a single particle as a working medium generally increases the output power at the expense of inducing friction that lowers the cycle efficiency. We propose to scale up a quantum heat engine utilizing a many-particle working medium in combination with the use of shortcuts to adiabaticity to boost the nonadiabatic performance by eliminating quantum friction and reducing the cycle time. To this end, we first analyze the finite-time thermodynamics of a quantum Otto cycle implemented with a quantum fluid confined in a time-dependent harmonic trap. We show that nonadiabatic effects can be controlled and tailored to match the adiabatic performance using a variety of shortcuts to adiabaticity. As a result, the nonadiabatic dynamics of the scaled-up many-particle quantum heat engine exhibits no friction, and the cycle can be run at maximum efficiency with a tunable output power. We demonstrate our results with a working medium consisting of particles with inverse-square pairwise interactions that includes non-interacting and hard-core bosons as limiting cases.

  11. Heralded high-efficiency quantum repeater with atomic ensembles assisted by faithful single-photon transmission.

    Science.gov (United States)

    Li, Tao; Deng, Fu-Guo

    2015-10-27

    Quantum repeater is one of the important building blocks for long distance quantum communication network. The previous quantum repeaters based on atomic ensembles and linear optical elements can only be performed with a maximal success probability of 1/2 during the entanglement creation and entanglement swapping procedures. Meanwhile, the polarization noise during the entanglement distribution process is harmful to the entangled channel created. Here we introduce a general interface between a polarized photon and an atomic ensemble trapped in a single-sided optical cavity, and with which we propose a high-efficiency quantum repeater protocol in which the robust entanglement distribution is accomplished by the stable spatial-temporal entanglement and it can in principle create the deterministic entanglement between neighboring atomic ensembles in a heralded way as a result of cavity quantum electrodynamics. Meanwhile, the simplified parity-check gate makes the entanglement swapping be completed with unity efficiency, other than 1/2 with linear optics. We detail the performance of our protocol with current experimental parameters and show its robustness to the imperfections, i.e., detuning and coupling variation, involved in the reflection process. These good features make it a useful building block in long distance quantum communication.

  12. Size-dependent oscillator strength and quantum efficiency of CdSe quantum dots controlled via the local density of states

    DEFF Research Database (Denmark)

    Leistikow, M.D.; Johansen, Jeppe; Kettelarij, A.J.;

    2009-01-01

    , allowing us to determine the size-dependent quantum efficiency and oscillator strength. We find that the quantum efficiency decreases with increasing emission energy mostly due to an increase in nonradiative decay. We manage to obtain the oscillator strength of the important class of CdSe quantum dots....... The oscillator strength varies weakly with frequency in agreement with behavior of quantum dots in the strong confinement limit. Surprisingly, previously calculated tight-binding results differ by a factor of 5 with the measured absolute values. Results from pseudopotential calculations agree well...

  13. Step-by-step magic state encoding for efficient fault-tolerant quantum computation

    Science.gov (United States)

    Goto, Hayato

    2014-01-01

    Quantum error correction allows one to make quantum computers fault-tolerant against unavoidable errors due to decoherence and imperfect physical gate operations. However, the fault-tolerant quantum computation requires impractically large computational resources for useful applications. This is a current major obstacle to the realization of a quantum computer. In particular, magic state distillation, which is a standard approach to universality, consumes the most resources in fault-tolerant quantum computation. For the resource problem, here we propose step-by-step magic state encoding for concatenated quantum codes, where magic states are encoded step by step from the physical level to the logical one. To manage errors during the encoding, we carefully use error detection. Since the sizes of intermediate codes are small, it is expected that the resource overheads will become lower than previous approaches based on the distillation at the logical level. Our simulation results suggest that the resource requirements for a logical magic state will become comparable to those for a single logical controlled-NOT gate. Thus, the present method opens a new possibility for efficient fault-tolerant quantum computation. PMID:25511387

  14. Step-by-step magic state encoding for efficient fault-tolerant quantum computation.

    Science.gov (United States)

    Goto, Hayato

    2014-12-16

    Quantum error correction allows one to make quantum computers fault-tolerant against unavoidable errors due to decoherence and imperfect physical gate operations. However, the fault-tolerant quantum computation requires impractically large computational resources for useful applications. This is a current major obstacle to the realization of a quantum computer. In particular, magic state distillation, which is a standard approach to universality, consumes the most resources in fault-tolerant quantum computation. For the resource problem, here we propose step-by-step magic state encoding for concatenated quantum codes, where magic states are encoded step by step from the physical level to the logical one. To manage errors during the encoding, we carefully use error detection. Since the sizes of intermediate codes are small, it is expected that the resource overheads will become lower than previous approaches based on the distillation at the logical level. Our simulation results suggest that the resource requirements for a logical magic state will become comparable to those for a single logical controlled-NOT gate. Thus, the present method opens a new possibility for efficient fault-tolerant quantum computation.

  15. Efficient interfacing of light and surface plasmon polaritons for quantum optics applications

    DEFF Research Database (Denmark)

    Eran, Kot

    control of matter. These include applications such as efficient photon collection, single-photon switching and transistors, and long-range optical coupling of quantum bits for quantum communications. However, generating and controlling strong coherent interaction between otherwise very weakly interacting...... interaction are the window to the underlying quantum world. It is no surprise then that there has always been push to find more, and gain better control over systems in which this interaction can be studied. In the past two decades, this end was further motivated as applications were envisioned to coherent...... light and quantum emitters proves a difficult task. Current days solutions range from cavities, atomic ensembles, photonic band gaps structures, ion traps and optical latices are all being improved and studied but none has yet to emerge as superior. Recently, another proposal for such a strong coupling...

  16. Efficient spin filter using multi-terminal quantum dot with spin-orbit interaction

    Directory of Open Access Journals (Sweden)

    Yokoyama Tomohiro

    2011-01-01

    Full Text Available Abstract We propose a multi-terminal spin filter using a quantum dot with spin-orbit interaction. First, we formulate the spin Hall effect (SHE in a quantum dot connected to three leads. We show that the SHE is significantly enhanced by the resonant tunneling if the level spacing in the quantum dot is smaller than the level broadening. We stress that the SHE is tunable by changing the tunnel coupling to the third lead. Next, we perform a numerical simulation for a multi-terminal spin filter using a quantum dot fabricated on semiconductor heterostructures. The spin filter shows an efficiency of more than 50% when the conditions for the enhanced SHE are satisfied. PACS numbers: 72.25.Dc,71.70.Ej,73.63.Kv,85.75.-d

  17. Quantum dot sensitized solar cells with improved efficiency prepared using electrophoretic deposition.

    Science.gov (United States)

    Salant, Asaf; Shalom, Menny; Hod, Idan; Faust, Adam; Zaban, Arie; Banin, Uri

    2010-10-26

    Quantum dot sensitized solar cells (QDSSC) may benefit from the ability to tune the quantum dot optical properties and band gap through the manipulation of their size and composition. Moreover, the inorganic nanocrystals may provide increased stability compared to organic sensitizers. We report the facile fabrication of QDSSC by electrophoretic deposition of CdSe QDs onto conducting electrodes coated with mesoporous TiO(2). Unlike prior chemical linker-based methods, no pretreatment of the TiO(2) was needed, and deposition times as short as 2 h were sufficient for effective coating. Cross-sectional chemical analysis shows that the Cd content is nearly constant across the entire TiO(2) layer. The dependence of the deposition on size was studied and successfully applied to CdSe dots with diameters between 2.5 and 5.5 nm as well as larger CdSe quantum rods. The photovoltaic characteristics of the devices are greatly improved compared with those achieved for cells prepared with a linker approach, reaching efficiencies as high as 1.7%, under 1 sun illumination conditions, after treating the coated electrodes with ZnS. Notably, the absorbed photon to electron conversion efficiencies did not show a clear size-dependence indicating efficient electron injection even for the larger QD sizes. The electrophoretic deposition method can be easily expanded and applied for preparations of QDSSCs using diverse colloidal quantum dot and quantum rod materials for sensitization.

  18. Efficient, stable infrared photovoltaics based on solution-cast colloidal quantum dots.

    Science.gov (United States)

    Koleilat, Ghada I; Levina, Larissa; Shukla, Harnik; Myrskog, Stefan H; Hinds, Sean; Pattantyus-Abraham, Andras G; Sargent, Edward H

    2008-05-01

    Half of the sun's power lies in the infrared. As a result, the optimal bandgaps for solar cells in both the single-junction and even the tandem architectures lie beyond 850 nm. However, progress in low-cost, large-area, physically flexible solar cells has instead been made in organic and polymer materials possessing absorption onsets in the visible. Recent advances have been achieved in solution-cast infrared photovoltaics through the use of colloidal quantum dots. Here we report stable solution-processed photovoltaic devices having 3.6% power conversion efficiency in the infrared. The use of a strongly bound bidentate linker, benzenedithiol, ensures device stability over weeks. The devices reach external quantum efficiencies of 46% in the infrared and 70% across the visible. We investigate in detail the physical mechanisms underlying the operation of this class of device. In contrast with drift-dominated behavior in recent reports of PbS quantum dot photovoltaics, we find that diffusion of electrons and holes over hundreds of nanometers through our PbSe colloidal quantum dot solid is chiefly responsible for the high external quantum efficiencies obtained in this new class of devices.

  19. Computational Design of a Family of Light-Driven Rotary Molecular Motors with Improved Quantum Efficiency.

    Science.gov (United States)

    Nikiforov, Alexander; Gamez, Jose A; Thiel, Walter; Filatov, Michael

    2016-01-07

    Two new light-driven molecular rotary motors based on the N-alkylated indanylidene benzopyrrole frameworks are proposed and studied using quantum chemical calculations and nonadiabatic molecular dynamics simulations. These new motors perform pure axial rotation, and the photochemical steps of the rotary cycle are dominated by the fast bond-length-alternation motion that enables ultrafast access to the S1/S0 intersection. The new motors are predicted to display a quantum efficiency higher than that of the currently available synthetic all-hydrocarbon motors. Remarkably, the quantum efficiency is not governed by the topography (peaked versus sloped) of the minimum-energy conical intersection, whereas the S1 decay time depends on the topography as well as on the energy of the intersection relative to the S1 minimum. It is the axial chirality (helicity), rather than the point chirality, that controls the sense of rotation of the motor.

  20. Efficient Dielectric Metasurface Collimating Lenses for Mid-Infrared Quantum Cascade Lasers

    CERN Document Server

    Arbabi, Amir; Horie, Yu; Bagheri, Mahmood; Faraon, Andrei

    2015-01-01

    Light emitted from single-mode semiconductor lasers generally has large divergence angles, and high numerical aperture lenses are required for beam collimation. Visible and near infrared lasers are collimated using aspheric glass or plastic lenses, yet collimation of mid-infrared quantum cascade lasers typically requires more costly aspheric lenses made of germanium, chalcogenide compounds, or other infrared-transparent materials. Here we report mid-infrared dielectric metasurface flat lenses that efficiently collimate the output beam of single-mode quantum cascade lasers. The metasurface lenses are composed of amorphous silicon posts on a flat sapphire substrate and can be fabricated at low cost using a single step conventional UV binary lithography. Mid-infrared radiation from a 4.8 $\\mu$m distributed-feedback quantum cascade laser is collimated using a polarization insensitive metasurface lens with 0.86 numerical aperture and 79% transmission efficiency. The collimated beam has a half divergence angle of 0...

  1. Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction

    Science.gov (United States)

    Lei, Fengcai; Liu, Wei; Sun, Yongfu; Xu, Jiaqi; Liu, Katong; Liang, Liang; Yao, Tao; Pan, Bicai; Wei, Shiqiang; Xie, Yi

    2016-09-01

    Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin-tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis.

  2. Highly efficient multiple-layer CdS quantum dot sensitized III-V solar cells.

    Science.gov (United States)

    Lin, Chien-Chung; Han, Hau-Vei; Chen, Hsin-Chu; Chen, Kuo-Ju; Tsai, Yu-Lin; Lin, Wein-Yi; Kuo, Hao-Chung; Yu, Peichen

    2014-02-01

    In this review, the concept of utilization of solar spectrum in order to increase the solar cell efficiency is discussed. Among the three mechanisms, down-shifting effect is investigated in detail. Organic dye, rare-earth minerals and quantum dots are three most popular down-shift materials. While the enhancement of solar cell efficiency was not clearly observed in the past, the advances in quantum dot fabrication have brought strong response out of the hybrid platform of a quantum dot solar cell. A multiple layer structure, including PDMS as the isolation layer, is proposed and demonstrated. With the help of pulse spray system, precise control can be achieved and the optimized concentration can be found.

  3. Spectral difference Lanczos method for efficient time propagation in quantum control theory.

    Science.gov (United States)

    Farnum, John D; Mazziotti, David A

    2004-04-01

    Spectral difference methods represent the real-space Hamiltonian of a quantum system as a banded matrix which possesses the accuracy of the discrete variable representation (DVR) and the efficiency of finite differences. When applied to time-dependent quantum mechanics, spectral differences enhance the efficiency of propagation methods for evolving the Schrodinger equation. We develop a spectral difference Lanczos method which is computationally more economical than the sinc-DVR Lanczos method, the split-operator technique, and even the fast-Fourier-Transform Lanczos method. Application of fast propagation is made to quantum control theory where chirped laser pulses are designed to dissociate both diatomic and polyatomic molecules. The specificity of the chirped laser fields is also tested as a possible method for molecular identification and discrimination.

  4. Confidence and efficiency scaling in Variational Quantum Monte Carlo calculations

    CERN Document Server

    Delyon, François; Holzmann, Markus

    2016-01-01

    Based on the central limit theorem, we discuss the problem of evaluation of the statistical error of Monte Carlo calculations using a time discretized diffusion process. We present a robust and practical method to determine the effective variance of general observables and show how to verify the equilibrium hypothesis by the Kolmogorov-Smirnov test. We then derive scaling laws of the efficiency illustrated by Variational Monte Carlo calculations on the two dimensional electron gas.

  5. Confidence and efficiency scaling in variational quantum Monte Carlo calculations

    Science.gov (United States)

    Delyon, F.; Bernu, B.; Holzmann, Markus

    2017-02-01

    Based on the central limit theorem, we discuss the problem of evaluation of the statistical error of Monte Carlo calculations using a time-discretized diffusion process. We present a robust and practical method to determine the effective variance of general observables and show how to verify the equilibrium hypothesis by the Kolmogorov-Smirnov test. We then derive scaling laws of the efficiency illustrated by variational Monte Carlo calculations on the two-dimensional electron gas.

  6. Simple formalism for efficient derivatives and multi-determinant expansions in quantum Monte Carlo

    NARCIS (Netherlands)

    Filippi, C.; Assaraf, R.; Moroni, S.

    2016-01-01

    We present a simple and general formalism to compute efficiently the derivatives of a multi-determinant Jastrow-Slater wave function, the local energy, the interatomic forces, and similar quantities needed in quantum Monte Carlo. Through a straightforward manipulation of matrices evaluated on the oc

  7. The effect of nonadiabaticity on the efficiency of quantum memory based on an optical cavity

    Science.gov (United States)

    Veselkova, N. G.; Sokolov, I. V.

    2017-07-01

    Quantum efficiency is an important characteristic of quantum memory devices that are aimed at recording the quantum state of light signals and its storing and reading. In the case of memory based on an ensemble of cold atoms placed in an optical cavity, the efficiency is restricted, in particular, by relaxation processes in the system of active atomic levels. We show how the effect of the relaxation on the quantum efficiency can be determined in a regime of the memory usage in which the evolution of signals in time is not arbitrarily slow on the scale of the field lifetime in the cavity and when the frequently used approximation of the adiabatic elimination of the quantized cavity mode field cannot be applied. Taking into account the effect of the nonadiabaticity on the memory quality is of interest in view of the fact that, in order to increase the field-medium coupling parameter, a higher cavity quality factor is required, whereas storing and processing of sequences of many signals in the memory implies that their duration is reduced. We consider the applicability of the well-known efficiency estimates via the system cooperativity parameter and estimate a more general form. In connection with the theoretical description of the memory of the given type, we also discuss qualitative differences in the behavior of a random source introduced into the Heisenberg-Langevin equations for atomic variables in the cases of a large and a small number of atoms.

  8. Quantum efficiencies exceeding unity due to impact ionization in silicon solar cells

    Science.gov (United States)

    Kolodinski, Sabine; Werner, Jürgen H.; Wittchen, Thomas; Queisser, Hans J.

    1993-10-01

    Absolute measurements demonstrate internal quantum efficiencies in silicon solar cells to exceed unity for photon energies above the first direct band gap and to show distinct spectral features that correspond to specific points in the Brillouin zone. Ultraviolet radiation can generate hot carriers with sufficient energy to cause impact ionization which results in two electron hole pairs per incident photon.

  9. A novel high-efficiency single-mode quantum dot single photon source

    DEFF Research Database (Denmark)

    Gerard, J.M.; Gregersen, Niels; Nielsen, Torben Roland

    2008-01-01

    We present a novel single-mode single photon source exploiting the emission of a semiconductor quantum dot (QD) located inside a photonic wire. Besides an excellent coupling (>95%) of QD spontaneous emission to the fundamental guided mode [1], we show that a single photon collection efficiency...

  10. Design Rules for High-Efficiency Quantum-Dot-Sensitized Solar Cells: A Multilayer Approach.

    Science.gov (United States)

    Shalom, Menny; Buhbut, Sophia; Tirosh, Shay; Zaban, Arie

    2012-09-06

    The effect of multilayer sensitization in quantum-dot (QD)-sensitized solar cells is reported. A series of electrodes, consisting of multilayer CdSe QDs were assembled on a compact TiO2 layer. Photocurrent measurements along with internal quantum efficiency calculation reveal similar electron collection efficiency up to a 100 nm thickness of the QD layers. Moreover, the optical density and the internal quantum efficiency measurements reveal that the desired surface area of the TiO2 electrode should be increased only by a factor of 17 compared with a compact electrode. We show that the sensitization of low-surface-area TiO2 electrode with QD layers increases the performance of the solar cell, resulting in 3.86% efficiency. These results demonstrate a conceptual difference between the QD-sensitized solar cell and the dye-based system in which dye multilayer decreases the cell performance. The utilization of multilayer QDs opens new opportunities for a significant improvement of quantum-dot-sensitized solar cells via innovative cell design.

  11. LHCb: Quantum Efficiency of Hybrid Photon Detectors for the LHCb RICH

    CERN Multimedia

    Lambert, Robert W

    2007-01-01

    The production of 550 hybrid photon detectors to be used within the LHCb RICH detectors has recently finished. Photonis-DEP have succeeded in consistently improving the tube quantum efficiency, by a relative 27,% with respect to preseries and prototype tubes, when integrated over the energy spectrum.

  12. Efficient scheme for preparation of the multi-atom W state via cavity quantum electrodynamics

    Institute of Scientific and Technical Information of China (English)

    Zhang Jin; Ye Liu

    2004-01-01

    We present an efficient scheme for preparation of the multi-atom W state via cavity quantum electrodynamics.Involved in this scheme are n identical two-level atoms and a single-mode cavity field. Discussion indicates that this scheme can be realized easily by current technologies.

  13. Efficiency at maximum power of a quantum Otto cycle within finite-time or irreversible thermodynamics

    Science.gov (United States)

    Wu, Feilong; He, Jizhou; Ma, Yongli; Wang, Jianhui

    2014-12-01

    We consider the efficiency at maximum power of a quantum Otto engine, which uses a spin or a harmonic system as its working substance and works between two heat reservoirs at constant temperatures Th and Tc (Otto engine working in the linear-response regime.

  14. Area laws and efficient descriptions of quantum many-body states

    Science.gov (United States)

    Ge, Yimin; Eisert, Jens

    2016-08-01

    It is commonly believed that area laws for entanglement entropies imply that a quantum many-body state can be faithfully represented by efficient tensor network states—a conjecture frequently stated in the context of numerical simulations and analytical considerations. In this work, we show that this is in general not the case, except in one-dimension. We prove that the set of quantum many-body states that satisfy an area law for all Renyi entropies contains a subspace of exponential dimension. We then show that there are states satisfying area laws for all Renyi entropies but cannot be approximated by states with a classical description of small Kolmogorov complexity, including polynomial projected entangled pair states or states of multi-scale entanglement renormalisation. Not even a quantum computer with post-selection can efficiently prepare all quantum states fulfilling an area law, and we show that not all area law states can be eigenstates of local Hamiltonians. We also prove translationally and rotationally invariant instances of these results, and show a variation with decaying correlations using quantum error-correcting codes.

  15. Near-unity coupling efficiency of a quantum emitter to a photonic crystal waveguide.

    Science.gov (United States)

    Arcari, M; Söllner, I; Javadi, A; Lindskov Hansen, S; Mahmoodian, S; Liu, J; Thyrrestrup, H; Lee, E H; Song, J D; Stobbe, S; Lodahl, P

    2014-08-29

    A quantum emitter efficiently coupled to a nanophotonic waveguide constitutes a promising system for the realization of single-photon transistors, quantum-logic gates based on giant single-photon nonlinearities, and high bit-rate deterministic single-photon sources. The key figure of merit for such devices is the β factor, which is the probability for an emitted single photon to be channeled into a desired waveguide mode. We report on the experimental achievement of β=98.43%±0.04% for a quantum dot coupled to a photonic crystal waveguide, corresponding to a single-emitter cooperativity of η=62.7±1.5. This constitutes a nearly ideal photon-matter interface where the quantum dot acts effectively as a 1D "artificial" atom, since it interacts almost exclusively with just a single propagating optical mode. The β factor is found to be remarkably robust to variations in position and emission wavelength of the quantum dots. Our work demonstrates the extraordinary potential of photonic crystal waveguides for highly efficient single-photon generation and on-chip photon-photon interaction.

  16. Efficient method for calculating electronic bound states in arbitrary one-dimensional quantum wells

    Science.gov (United States)

    de Aquino, V. M.; Iwamoto, H.; Dias, I. F. L.; Laureto, E.; da Silva, M. A. T.; da Silva, E. C. F.; Quivy, A. A.

    2017-01-01

    In the present paper it is demonstrated that the bound electronic states of multiple quantum wells structures may be calculated very efficiently by expanding their eigenstates in terms of the eigenfunctions of a particle in a box. The bound states of single and multiple symmetric or nonsymmetric wells are calculated within the single-band effective mass approximation. A comparison is then made between the results obtained for simple cases with exact calculations. We also apply our approach to a GaAs/AlGaAs multiple quantum well structure composed of forty periods each one with seven quantum wells. The method may be very useful to design narrow band quantum cascade photodetectors to work without applied bias in a photovoltaic mode. With the presented method the effects of a electric field may also be easily included which is very important if one desires study quantum well structures for application to the development of quantum cascade lasers. The advantages of the method are also presented.

  17. Functional Basis for Efficient Physical Layer Classical Control in Quantum Processors

    Science.gov (United States)

    Ball, Harrison; Nguyen, Trung; Leong, Philip H. W.; Biercuk, Michael J.

    2016-12-01

    The rapid progress seen in the development of quantum-coherent devices for information processing has motivated serious consideration of quantum computer architecture and organization. One topic which remains open for investigation and optimization relates to the design of the classical-quantum interface, where control operations on individual qubits are applied according to higher-level algorithms; accommodating competing demands on performance and scalability remains a major outstanding challenge. In this work, we present a resource-efficient, scalable framework for the implementation of embedded physical layer classical controllers for quantum-information systems. Design drivers and key functionalities are introduced, leading to the selection of Walsh functions as an effective functional basis for both programing and controller hardware implementation. This approach leverages the simplicity of real-time Walsh-function generation in classical digital hardware, and the fact that a wide variety of physical layer controls, such as dynamic error suppression, are known to fall within the Walsh family. We experimentally implement a real-time field-programmable-gate-array-based Walsh controller producing Walsh timing signals and Walsh-synthesized analog waveforms appropriate for critical tasks in error-resistant quantum control and noise characterization. These demonstrations represent the first step towards a unified framework for the realization of physical layer controls compatible with large-scale quantum-information processing.

  18. Heterostructures for Increased Quantum Efficiency in Nitride LEDs

    Energy Technology Data Exchange (ETDEWEB)

    Davis, Robert F. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2010-09-30

    Task 1. Development of an advanced LED simulator useful for the design of efficient nitride-based devices. Simulator will contain graphical interface software that can be used to specify the device structure, the material parameters, the operating conditions and the desired output results. Task 2. Theoretical and experimental investigations regarding the influence on the microstructure, defect concentration, mechanical stress and strain and IQE of controlled changes in the chemistry and process route of deposition of the buffer layer underlying the active region of nitride-based blue- and greenemitting LEDs. Task 3. Theoretical and experimental investigations regarding the influence on the physical properties including polarization and IQE of controlled changes in the geometry, chemistry, defect density, and microstructure of components in the active region of nitride-based blue- and green-emitting LEDs. Task 4. Theoretical and experimental investigations regarding the influence on IQE of novel heterostructure designs to funnel carriers into the active region for enhanced recombination efficiency and elimination of diffusion beyond this region. Task 5. Theoretical and experimental investigations regarding the influence of enhanced p-type doping on the chemical, electrical, and microstructural characteristics of the acceptor-doped layers, the hole injection levels at Ohmic contacts, the specific contact resistivity and the IQE of nitride-based blue- and green-emitting LEDs. Development and optical and electrical characterization of reflective Ohmic contacts to n- and p-type GaN films.

  19. Optimal Power and Efficiency of Quantum Thermoacoustic Micro-cycle Working in 1D Harmonic Trap

    Science.gov (United States)

    E, Qing; Wu, Feng; Yin, Yong; Liu, XiaoWei

    2017-10-01

    Thermoacoustic engines (including heat engines and refrigerators) are energy conversion devices without moving part. They have great potential in aviation, new energy utilization, power technology, refrigerating and cryogenics. The thermoacoustic parcels, which compose the working fluid of a thermoacoustic engine, oscillate within the sound channel with a temperature gradient. The thermodynamic foundation of a thermoacoustic engine is the thermoacoustic micro-cycle (TAMC). In this paper, the theory of quantum mechanics is applied to the study of the actual thermoacoustic micro-cycle for the first time. A quantum mechanics model of the TAMC working in a 1D harmonic trap, which is named as a quantum thermoacoustic micro-cycle (QTAMC), is established. The QTAMC is composed of two constant force processes connected by two straight line processes. Analytic expressions of the power output and the efficiency for QTAMC have been derived. The effects of the trap width and the temperature amplitude on the power output and the thermal efficiency have been discussed. Some optimal characteristic curves of power output versus efficiency are plotted, and then the optimization region of QTAMC is given in this paper. The results obtained here not only enrich the thermoacoustic theory but also expand the application of quantum thermodynamics.

  20. Negentropy as a source of efficiency: a nonequilibrium quantum Otto cycle

    Science.gov (United States)

    Li, Hai; Zou, Jian; Yu, Wen-Li; Li, Lin; Xu, Bao-Ming; Shao, Bin

    2013-07-01

    We consider a single quantum mechanical particle confined to an one-dimensional (1D) infinite square well, and propose a nonequilibrium quantum Otto cycle (NQOC). Compared with the conventional quantum Otto engine (CQOE) investigated by [T.D. Kieu, Phys. Rev. Lett. 93, 140403 (2004); T.D. Kieu, Eur. Phys. J. D 39, 115 (2006)], due to the effects of negentropy produced in the NQOC, many interesting features appear: (1) in general, the NQOC is capable of extracting more work, so it is more efficient; (2) the NQOC can operate even when T 1 = T 2 or T 1 < T 2, where T 1 ( T 2) represents the temperature of hot (cold) bath; (3) in some cases, the NQOC can absorb heat from both baths and completely transforms them into work. These results demonstrate that the negentropy can be understood as an effective source of efficiency in quantum heat engines (QHEs) and meanwhile it is shown that the second law of thermodynamics is not violated. At last, we also show that the efficiency of NQOC reduces to that of classical Otto cycle in the classical limit.

  1. Efficient exciton funneling in cascaded PbS quantum dot superstructures.

    Science.gov (United States)

    Xu, Fan; Ma, Xin; Haughn, Chelsea R; Benavides, Jamie; Doty, Matthew F; Cloutier, Sylvain G

    2011-12-27

    Benzenedithiol (BDT) and ethanedithiol (EDT) ligand-exchange treatments can be used to cross-link colloidal PbS quantum dots into nanocrystalline film structures with distinct optoelectronic properties. Such structures can provide a unique platform to study the energy transfer between layers of quantum dots with different sizes. In this report, efficient exciton funneling and recycling of surface state-bound excitons is observed in cascaded PbS quantum dot-based multilayered superstructures, where the excitons transfer from the larger band gap or donor layers to the smallest band gap or acceptor layers. In this system, both the BDT- and EDT-treated cascaded structures exhibit dramatically enhanced photoluminescence from the acceptor layers. As we show, the energy transfer mechanisms involved and their efficiencies are significantly different depending on the ligand-exchange treatment. In the future, we believe these efficient exciton recycling and funneling mechanisms could be used to improve significantly the photocurrent, charge-transport, and conversion efficiencies in low-cost nanocrystalline and hybrid solar cells and the emission efficiencies in hybrid light-emitting devices.

  2. Highly efficient CdS-quantum-dot-sensitized GaAs solar cells.

    Science.gov (United States)

    Lin, Chien-Chung; Chen, Hsin-Chu; Tsai, Yu Lin; Han, Hau-Vei; Shih, Huai-Shiang; Chang, Yi-An; Kuo, Hao-Chung; Yu, Peichen

    2012-03-12

    We demonstrate a hybrid design of traditional GaAs-based solar cell combined with colloidal CdS quantum dots. With anti-reflective feature at long wavelength and down-conversion at UV regime, the CdS quantum dot effectively enhance the overall power conversion efficiency by as high as 18.9% compared to traditional GaAs-based device. A more detailed study showed an increase of surface photoconductivity due to UV presence, and the fill factor of the solar cell can be improved accordingly.

  3. Quantum efficiencies of the photo-Fenton degradation of atrazine in water.

    Science.gov (United States)

    Benzaquén, T B; Isla, M A; Alfano, O M

    2012-01-01

    An experimental work in a well-stirred batch recycling reactor for the photo-Fenton degradation of atrazine in water is presented. A study of the quantum efficiency is performed to assess the effectiveness of the photo-Fenton process on the atrazine degradation and total organic carbon (TOC) mineralization. Apparent and absolute quantum efficiencies of degradation and mineralization of an atrazine-based commercial herbicide are determined under different experimental conditions. Higher apparent efficiencies were found for both atrazine degradation and TOC mineralization when the ferric ion and hydrogen peroxide concentrations are increased. Because of the well known stability of the triazine ring, atrazine was not completely mineralized by the photo-Fenton process. However, a TOC reduction of 40% was achieved, being 62.5% of the maximum value that can be reached.

  4. Efficient Multiparty Quantum Secret Sharing with Greenberger-Horne-Zeilinger States

    Institute of Scientific and Technical Information of China (English)

    DENG Fu-Guo; ZHOU Ping; LI Xi-Han; LI Chun-Yan; ZHOU Hong-Yu

    2006-01-01

    @@ An efficient multiparty quantum secret sharing scheme is proposed with Greenberger-Horne-Zeilinger (GHZ)states following some ideas in quantum dense coding. The agents take the single-photon measurements on the photons received for eavesdropping check and exploit the four local unitary operations I, σz, σx and iσy tocode their message. This scheme has the advantage of high capacity as each GHZ state can carry two bits of information. The parties do not need to announce the measuring bases for almost all the photons, which will reduce the classical information exchanged largely. The intrinsic efficiency for qubits and the total efficiency both approach the maximal values.

  5. Triarylboron-Based Fluorescent Organic Light-Emitting Diodes with External Quantum Efficiencies Exceeding 20 .

    Science.gov (United States)

    Suzuki, Katsuaki; Kubo, Shosei; Shizu, Katsuyuki; Fukushima, Tatsuya; Wakamiya, Atsushi; Murata, Yasujiro; Adachi, Chihaya; Kaji, Hironori

    2015-12-01

    Triarylboron compounds have attracted much attention, and found wide use as functional materials because of their electron-accepting properties arising from the vacant p orbitals on the boron atoms. In this study, we design and synthesize new donor-acceptor triarylboron emitters that show thermally activated delayed fluorescence. These emitters display sky-blue to green emission and high photoluminescence quantum yields of 87-100 % in host matrices. Organic light-emitting diodes using these emitting molecules as dopants exhibit high external quantum efficiencies of 14.0-22.8 %, which originate from efficient up-conversion from triplet to singlet states and subsequent efficient radiative decay from singlet to ground states.

  6. Efficiency at maximum power of a quantum Otto cycle within finite-time or irreversible thermodynamics.

    Science.gov (United States)

    Wu, Feilong; He, Jizhou; Ma, Yongli; Wang, Jianhui

    2014-12-01

    We consider the efficiency at maximum power of a quantum Otto engine, which uses a spin or a harmonic system as its working substance and works between two heat reservoirs at constant temperatures T(h) and T(c) (power based on these two different kinds of quantum systems are bounded from the upper side by the same expression η(mp)≤η(+)≡η(C)(2)/[η(C)-(1-η(C))ln(1-η(C))] with η(C)=1-T(c)/T(h) as the Carnot efficiency. This expression η(mp) possesses the same universality of the CA efficiency η(CA)=1-√(1-η(C)) at small relative temperature difference. Within the context of irreversible thermodynamics, we calculate the Onsager coefficients and show that the value of η(CA) is indeed the upper bound of EMP for an Otto engine working in the linear-response regime.

  7. General Formula for the Efficiency of Quantum-Mechanical Analog of the Carnot Engine

    Directory of Open Access Journals (Sweden)

    Sumiyoshi Abe

    2013-04-01

    Full Text Available An analog of the Carnot engine reversibly operating within the framework of pure-state quantum mechanics is discussed. A general formula is derived for the efficiency of such an engine with an arbitrary confining potential. Its expression is given in terms of an energy spectrum and shows how the efficiency depends on a potential as the analog of a working material in thermodynamics, in general. This non-universal nature results from the fact that there exists no analog of the second law of thermodynamics in pure-state quantum mechanics where the von Neumann entropy identically vanishes. A special class of spectra, which leads to a common form of the efficiency, is identified.

  8. Efficient near-infrared quantum cutting in NaYF4: Ho3+, Yb3+ for solar photovoltaics.

    Science.gov (United States)

    Deng, Kaimo; Gong, Tao; Hu, Lingxun; Wei, Xiantao; Chen, Yonghu; Yin, Min

    2011-01-31

    Quantum cutting converting a ultraviolet photon into two near-infrared photons has been demonstrated by spectroscopic measurements in NaYF4:Ho3+,Yb3+ synthesized by hydrothermal method. Evidence is provided to confirm the occurrence of quantum cutting. Upon excitation of Ho3+ 5G4 level, near-infrared quantum cutting could occur through a two-step resonance energy transfer from Ho3+ to Yb3+ by cross relaxation, with a maximum quantum efficiency of 155.2%. This result reveals the possibility of violet to near-infrared quantum cutting with a quantum efficiency larger than 100% in Ho3+/Yb3+ codoped fluorides, suggesting the possible application in modifying the solar spectrum to enhance the efficiency of silicon solar cells.

  9. [Three photons quantum-cutting system on the rear surface of cells to improve the efficiencies of solar cells].

    Science.gov (United States)

    Yao, Wen-ting; Chen, Xiao-bo; Cheng, Huan-li; Zhou, Gu; Deng, Zhi-wei; Li, Yong-liang; Yan, Da-dong; Peng, Fang-lin

    2015-02-01

    The authors present a solar cell model with a three photons quantum-cutting system on the rear surface, then the method of calculation of limiting efficiencies was used to get the maximum efficiency 58.58% at the band gap Eg=0.9315 eV, and in contrast with two-photons quantum-cutting system, it is greatly improved. The result can prove that the three-photons quantum-cutting has a great sense to improve the efficiencies of solar cells. It is the exciting development for us to find out the useful luminescence materials to get the high efficiency.

  10. Highly efficient photonic nanowire single-photon sources for quantum information applications

    DEFF Research Database (Denmark)

    Gregersen, Niels; Claudon, J.; Munsch, M.

    2013-01-01

    must feature near-unity efficiency, where the efficiency is defined as the number of detected photons per trigger, the probability g(2)(τ=0) of multi-photon emission events should be 0 and the emitted photons are required to be indistinguishable. An optically or electrically triggered quantum light......  factor, meaning that efficient coupling from the QD to the guided mode is obtained over a broad spectral range of ~ 50-100 nm. [4] This means that spectral alignment between the emitter line and a narrow cavity line is not required, which represents a huge practical advantage in the fabrication...

  11. Efficient Approximation of the Dynamics of One-Dimensional Quantum Spin Systems

    Science.gov (United States)

    Osborne, Tobias J.

    2006-10-01

    In this Letter we show that an arbitrarily good approximation to the propagator eitH for a 1D lattice of n quantum spins with Hamiltonian H may be obtained with polynomial computational resources in n and the error γ and exponential resources in |t|. Our proof makes use of the finitely correlated state or matrix product state formalism exploited by numerical renormalization group algorithms like the density matrix renormalization group. There are two immediate consequences of this result. The first is that Vidal’s time-dependent density matrix renormalization group will require only polynomial resources to simulate 1D quantum spin systems for logarithmic |t|. The second consequence is that continuous-time 1D quantum circuits with logarithmic |t| can be simulated efficiently on a classical computer, despite the fact that, after discretization, such circuits are of polynomial depth.

  12. An efficient matrix product operator representation of the quantum chemical Hamiltonian

    Energy Technology Data Exchange (ETDEWEB)

    Keller, Sebastian, E-mail: sebastian.keller@phys.chem.ethz.ch; Reiher, Markus, E-mail: markus.reiher@phys.chem.ethz.ch [ETH Zürich, Laboratory of Physical Chemistry, Vladimir-Prelog-Weg 2, 8093 Zürich (Switzerland); Dolfi, Michele, E-mail: dolfim@phys.ethz.ch; Troyer, Matthias, E-mail: troyer@phys.ethz.ch [ETH Zürich, Institute of Theoretical Physics, Wolfgang-Pauli-Strasse 27, 8093 Zürich (Switzerland)

    2015-12-28

    We describe how to efficiently construct the quantum chemical Hamiltonian operator in matrix product form. We present its implementation as a density matrix renormalization group (DMRG) algorithm for quantum chemical applications. Existing implementations of DMRG for quantum chemistry are based on the traditional formulation of the method, which was developed from the point of view of Hilbert space decimation and attained higher performance compared to straightforward implementations of matrix product based DMRG. The latter variationally optimizes a class of ansatz states known as matrix product states, where operators are correspondingly represented as matrix product operators (MPOs). The MPO construction scheme presented here eliminates the previous performance disadvantages while retaining the additional flexibility provided by a matrix product approach, for example, the specification of expectation values becomes an input parameter. In this way, MPOs for different symmetries — abelian and non-abelian — and different relativistic and non-relativistic models may be solved by an otherwise unmodified program.

  13. High Efficient Quantum Key Distribution by Random Using Classified Signal Coherent States

    Institute of Scientific and Technical Information of China (English)

    XI Jing-Bo; FANG Xi-Ming

    2006-01-01

    The decoy-state method is a useful method in resisting the attacks on quantum key distribution. However, how to choose the intensities of decoy states and the ratio of the decoy states and the signal state is still an open question. We present a simple formula to analyse the problem. We also give a simple method to derive the bounds of the necessary counting rates and quantum bit error rates for BB84 and SARG04; the latter was previously proposed by Scarani et al. [Phys. Rev. Lett. 92 (2004) 057901] We then propose a multi-signal-state method which employs different coherent states either as the decoy state or as the signal state to carry out quantum key distribution. We find our protocol more efficient and feasible.

  14. Limits to solar power conversion efficiency with applications to quantum and thermal systems

    Science.gov (United States)

    Byvik, C. E.; Buoncristiani, A. M.; Smith, B. T.

    1983-01-01

    An analytical framework is presented that permits examination of the limit to the efficiency of various solar power conversion devices. Thermodynamic limits to solar power efficiency are determined for both quantum and thermal systems, and the results are applied to a variety of devices currently considered for use in space systems. The power conversion efficiency for single-threshold energy quantum systems receiving unconcentrated air mass zero solar radiation is limited to 31 percent. This limit applies to photovoltaic cells directly converting solar radiation, or indirectly, as in the case of a thermophotovoltaic system. Photoelectrochemical cells rely on an additional chemical reaction at the semiconductor-electrolyte interface, which introduces additional second-law demands and a reduction of the solar conversion efficiency. Photochemical systems exhibit even lower possible efficiencies because of their relatively narrow absorption bands. Solar-powered thermal engines in contact with an ambient reservoir at 300 K and operating at maximum power have a peak conversion efficiency of 64 percent, and this occurs for a thermal reservoir at a temperature of 2900 K. The power conversion efficiency of a solar-powered liquid metal magnetohydrodydnamic generator, a solar-powered steam turbine electric generator, and an alkali metal thermoelectric converter is discussed.

  15. Green synthesis of highly efficient CdSe quantum dots for quantum-dots-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Bing; Shen, Chao; Zhang, Mengya; Yuan, Shuanglong; Yang, Yunxia, E-mail: yangyunxia@ecust.edu.cn, E-mail: grchen@ecust.edu.cn; Chen, Guorong, E-mail: yangyunxia@ecust.edu.cn, E-mail: grchen@ecust.edu.cn [Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237 (China); Zhang, Bo [Department of Physics, East China University of Science and Technology, Shanghai 200237 (China)

    2014-05-21

    Green synthesis of CdSe quantum dots for application in the quantum-dots-sensitized solar cells (QDSCs) is investigated in this work. The CdSe QDs were prepared with glycerol as the solvent, with sharp emission peak, full width at half maximum around 30 nm, and absorption peak from 475 nm to 510 nm. The reaction is environmental friendly and energy saving. What's more, the green synthesized CdSe QDs are coherence to the maximum remittance region of the solar spectrum and suitable as sensitizers to assemble onto TiO{sub 2} electrodes for cell devices application. What's more, the dynamic procedure of the carriers' excitation, transportation, and recombination in the QDSCs are discussed. Because the recombination of the electrons from the conduction band of TiO{sub 2}'s to the electrolyte affects the efficiency of the solar cells greatly, 3-Mercaptopropionic acid capped water-dispersible QDs were used to cover the surface of TiO{sub 2}. The resulting green synthesized CdSe QDSCs with Cu{sub 2}S as the electrode show a photovoltaic performance with a conversion efficiency of 3.39%.

  16. Highly efficient visual detection of trace copper(II) and protein by the quantum photoelectric effect.

    Science.gov (United States)

    Wang, Peng; Lei, Jianping; Su, Mengqi; Liu, Yueting; Hao, Qing; Ju, Huangxian

    2013-09-17

    This work presented a photocurrent response mechanism of quantum dots (QDs) under illumination with the concept of a quantum photoelectric effect. Upon irradiation, the photoelectron could directly escape from QDs. By using nitro blue tetrazolium (NBT) to capture the photoelectron, a new visual system was proposed due to the formation of an insoluble reduction product, purple formazan, which could be used to visualize the quantum photoelectric effect. The interaction of copper(II) with QDs could form trapping sites to interfere with the quantum confinement and thus blocked the escape of photoelectron, leading to a "signal off" visual method for sensitive copper(II) detection. Meanwhile, by using QDs as a signal tag to label antibody, a "signal on" visual method was also proposed for immunoassay of corresponding protein. With meso-2,3-dimercaptosuccinic-capped CdTe QDs and carcino-embryonic antigen as models, the proposed visual detection methods showed high sensitivity, low detection limit, and wide detectable concentration ranges. The visualization of quantum photoelectric effect could be simply extended for the detection of other targets. This work opens a new visual detection way and provides a highly efficient tool for bioanalysis.

  17. Efficiency studies on semipolar GaInN-GaN quantum well structures

    Energy Technology Data Exchange (ETDEWEB)

    Scholz, Ferdinand; Meisch, Tobias; Elkhouly, Karim [Institute of Optoelectronics, Ulm University (Germany)

    2016-12-15

    In order to clarify the reasons for the fairly poor electroluminescence (EL) performance of semipolar LED structures grown on patterned sapphire wafers, we have analyzed both, pure photoluminescence (PL) test structures without doping only containing 5 GaInN quantum wells and full EL test structures, all emitting at a wavelength of about 510 nm. Evaluating the PL intensity over a wide range of temperatures and excitation powers, we conclude that such quantum wells possess a fairly large internal quantum efficiency of about 20%. However, on EL test structures containing nominally the same quantum wells, we obtained an optical output power of only about 150μW at an applied current of 20 mA. This may be due partly to some thermal destruction of the quantum wells by the overgrowth with p-GaN. Even more important seems to be the not yet finally optimized p-doping of these structures. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Structural Investigation of Cesium Lead Halide Perovskites for High-Efficiency Quantum Dot Light Emitting Diodes

    Energy Technology Data Exchange (ETDEWEB)

    Van Le, Quyet; Beom Kim, Jong; Kim, Soo Young; Lee, Byeongdu; Lee, Dong Ryeol

    2017-08-16

    We have investigated the effect of reaction temperature of hot-injection method on the structural properties of CsPbX3 (X: Br, I, Cl) perovskite nanocrystals (NCs) using the small- and wide-angle X-ray scattering. It is confirmed that the size of the NCs decreased as the reaction temperature decreased, resulting stronger quantum confinement. The cubic-phase perovskite NCs were formed despite the reaction temperatures increased from 140 to 180 °C. However, monodispersive NC cubes which are required for densely packing self-assembly film were only formed at lower temperatures. From the X-ray scattering measurements, the spin-coated film from more monodispersive perovskite nanocubes synthesized at lower temperatures resulted in more preferred orientation. This dense-packing perovskite film with preferred orientation yielded efficient light-emitting diode (LED) performance. Thus, the dense-packing structure of NC assemblies formed after spin-coating should be considered for high-efficient LEDs based on perovskite quantum dots in addition to quantum confinement effect of the quantum dots.

  19. An efficient two-step quantum key distribution protocol with orthogonal product states

    Institute of Scientific and Technical Information of China (English)

    Yang Yu-Guang; Wen Qiao-Yan; Zhu Fu-Chen

    2007-01-01

    An efficient two-step quantum key distribution (QKD) protocol with orthogonal product states in the n( )n(n ≥ 3) Hilbert space is presented. In this protocol, the particles in the orthogonal product states form two particle sequences.The sender, Alice, first sends one sequence to the receiver, Bob. After Bob receives the first particle sequence, Alice and Bob check eavesdropping by measuring a fraction of particles randomly chosen. After ensuring the security of the quantum channel, Alice sends the other particle sequence to Bob. By making an orthogonal measurement on the two particle sequences, Bob can obtain the information of the orthogonal product states sent by Alice. This protocol has many distinct features such as great capacity, high efficiency in that it uses all orthogonal product states in distributing the key except those chosen for checking eavesdroppers.

  20. A novel method to increase quantum efficiency of the monolithically integrated PIN/HBT-receiver

    Science.gov (United States)

    Cui, Hailin; Zhou, Shouli; Huang, Hui; Huang, Yongqing; Ren, Xiaomin

    2005-11-01

    Adding resonant cavity to increase quantum efficiency of the monolithically integrated PIN/HBT-Receiver is described. Between the InP buffer and device epitaxial structure, InP/InGaAsP quarter wavelength stack (QWS) are used to form DBR (Distributed Bragg Reflectors) mirror. The PIN-PD is integrated within a Fabry-Perot cavity and the incident light is reflected many times by the Fabry-Perot cavity and consequently absorbed many times by the absorption layer. Therefore, the quantum efficiency of this detector is enlarged, meanwhile other performances such as frequency response are not influenced. We discuss the method to fabricate the resonance cavity, make theory simulation, optimize design on it, and analyze the advantage of this device.

  1. General and Efficient C-C Bond Forming Photoredox Catalysis with Semiconductor Quantum Dots.

    Science.gov (United States)

    Caputo, Jill A; Frenette, Leah C; Zhao, Norman; Sowers, Kelly L; Krauss, Todd D; Weix, Daniel J

    2017-03-29

    Photoredox catalysis has become an essential tool in organic synthesis because it enables new routes to important molecules. However, the best available molecular catalysts suffer from high catalyst loadings and rely on precious metals. Here we show that colloidal nanocrystal quantum dots (QDs) can serve as efficient and robust, precious-metal free, photoassisted redox catalysts. A single-sized CdSe quantum dot (3.0 ± 0.2 nm) can replace several different dye catalysts needed for five different photoredox reactions (β-alkylation, β-aminoalkylation, dehalogenation, amine arylation, and decarboxylative radical formation). Even without optimization of the QDs or the reaction conditions, efficiencies rivaling those of the best available metal dyes were obtained.

  2. Quantum efficiency of the CCD camera (XIS) for the ASTRO-E mission

    CERN Document Server

    Katayama, H; Kohmura, T; Katayama, K; Yoshita, K; Tsunemi, H; Kitamoto, S; Hayashida, K; Miyata, E; Hashimotodani, K; Koyama, K; Ricker, G; Bautz, M W; Foster, R; Kissel, S

    1999-01-01

    We measured the optical and the X-ray transmission of the optical blocking filters for the X-ray Imaging Spectrometers (XISs) which are the X-ray CCD cameras of the ASTRO-E satellite. We conclude that the oxidation of the aluminum reduces the optical transmission down to approx 60-70% of the theoretical value of the aluminum. We achieved optical transmission below 5x10 sup - sup 5 in the range from 4000 to 9500 A by using aluminum thickness of 1200 A, while the theoretical calculation requires 800 A. The measurement of absolute quantum efficiency of XIS is also performed at several particular energies. We confirmed 20% quantum efficiency at 0.5 keV for the XIS engineering model (XIS EM).

  3. Simulation of the detective quantum efficiency for a hybrid pixel detector

    Energy Technology Data Exchange (ETDEWEB)

    Risco Norrlid, L. del [Department of Radiation Sciences, Uppsala University, Box 535, 751 21 Uppsala (Sweden)]. E-mail: lilian@tsl.uu.se; Edling, Fredrik [Department of Radiation Sciences, Uppsala University, Box 535, 751 21 Uppsala (Sweden); Fransson, K. [The Svedberg Laboratory, Uppsala University, Box 533, 751 21 Uppsala (Sweden); Brenner, R. [Department of Radiation Sciences, Uppsala University, Box 535, 751 21 Uppsala (Sweden); Bingefors, N. [Department of Radiation Sciences, Uppsala University, Box 535, 751 21 Uppsala (Sweden); Gustafsson, L. [Department of Radiation Sciences, Uppsala University, Box 535, 751 21 Uppsala (Sweden); Roennqvist, C. [Scanditronix Wellhoefer AB, Stalgatan 14, 754 50 Uppsala (Sweden)

    2005-05-11

    A simulation tool has been developed for the analysis of the performance of an X-ray imaging hybrid pixel detector. The photon transport and charge collection were simulated with the aid of the Monte Carlo based code GEANT and the readout signal processing was simulated in a program written in the LabView programming environment. Results of the spatial frequency-dependent detective quantum efficiency are presented and the influence of charge sharing, the threshold settings, level of exposure, the noise sources on the detector performance are studied. The detector was found to operate quantum limited down to an exposure of 0.08 {mu}Gy, below which it is limited by the readout noise. The threshold setting has a strong influence on both the efficiency and the spatial resolution due to charge sharing, and a compromise between the two is necessary. The optimized threshold value corresponds to half of the mean energy of the input spectrum.

  4. Enhanced quantum efficiency for CsI grown on a graphite-based substrate coating

    CERN Document Server

    Friese, J; Homolka, J; Kastenmüller, A; Maier-Komor, P; Peter, M; Zeitelhack, K; Kienle, P; Körner, H J

    1999-01-01

    Quantum efficiencies (QE) in the vacuum ultraviolet (VUV) wavelength region have been measured for solid CsI layers on various substrates. The CsI films were deposited applying electron beam evaporation. The QE measurements were performed utilizing synchrotron radiation as well as light from a deuterium lamp. A GaAsP diode with a sensitivity calibration traceable to a primary radiation standard was used for normalization. For CsI layers grown on resin-stabilized graphite films a significant enhancement of QE was observed. Substrates suitable for gas detector applications and aging properties were investigated. The procedures to prepare and reproduce high quantum efficient CsI layers are described.

  5. Investigating the temperature dependence of photomultiplier quantum efficiency when operating in the visible spectrum

    CERN Document Server

    Clawson, Savannah Ellen

    2017-01-01

    The quantum efficiency of a Burle 8850 photomultiplier tube with a potassium-caesium-antimony (bialkali) photocathode was determined by attenuating a 1 mW HeNe laser emitting at 633 nm and measuring the signal frequency when the laser was incident on the photomultiplier. A temperature range of 5 $^{\\circ}$C $-$ 20 $^{\\circ}$C was investigated and it was found that the quantum efficiency decreases with temperature, with the signal frequency decreasing at a faster rate than the dark current frequency. Therefore, it was concluded that it would not be beneficial to cool photomultiplier tubes operating in the visible spectrum for use in collinear laser spectroscopy due to a decreasing signal-to-noise ratio. The signal pulse height distribution was also analysed and found to be independent of temperature within the range investigated.

  6. Enhanced quantum efficiency of photoelectron emission, through surface textured metal electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, Anna; Bandaru, Prabhakar R., E-mail: pbandaru@ucsd.edu [Program in Materials Science, Department of Mechanical Engineering, University of California, San Diego, La Jolla, California, 92130 (United States); Moody, Nathan A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2016-03-15

    It is predicted that the quantum efficiency (QE) of photoelectron emission from metals may be enhanced, possibly by an order of magnitude, through optimized surface texture. Through extensive computational simulations, it is shown that the absorption enhancement in select surface groove geometries may be a dominant contributor to enhanced QE and corresponds to localized Fabry–Perot resonances. The inadequacy of extant analytical models in predicting the QE increase, and suggestions for further improvement, are discussed.

  7. Efficient parabolic evaluation of coupling terms in hybrid quantum/classical simulations

    Energy Technology Data Exchange (ETDEWEB)

    Bastida, Adolfo, E-mail: bastida@um.es [Departamento de Quimica Fisica, Facultad de Quimica, Universidad de Murcia, 30100 Murcia (Spain); Soler, Miguel Angel; Zuniga, Jose; Requena, Alberto [Departamento de Quimica Fisica, Facultad de Quimica, Universidad de Murcia, 30100 Murcia (Spain); Miguel, Beatriz [Departamento de Ingenieria Quimica y Ambiental, Universidad Politecnica de Cartagena, 30203 Cartagena (Spain)

    2009-03-30

    A parabolic interpolation function of time is proposed to evaluate the non-adiabatic coupling matrix elements and the adiabatic energies at intermediate times within the classical time integration interval in hybrid quantum/classical simulations. The accuracy and the computational efficiency of this parabolic approximation are illustrated by carrying out a numerical application to the well-studied vibrational relaxation of I{sub 2} in liquid xenon.

  8. Solution-processed ultrasensitive polymer photodetectors with high external quantum efficiency and detectivity.

    Science.gov (United States)

    Liu, Xilan; Wang, Hangxing; Yang, Tingbin; Zhang, Wei; Gong, Xiong

    2012-07-25

    Operating at room temperature, polymer photodetectors (PDs) with external quantum efficiency approximately 80%, detectivity over 10(13) Jones, linear dynamic range over 120 dB, and dark current a few decades of nA/cm(2) were demonstrated. All these performance parameters were achieved by combined treatment of active layer with solvent vapor annealing and of polymer PDs with postproduction thermal annealing. These high performance parameters demonstrated that polymer PDs is comparable to or better than inorganic counterparts.

  9. Highly Efficient Quantum Sieving in Porous Graphene-like Carbon Nitride for Light Isotopes Separation

    Science.gov (United States)

    Qu, Yuanyuan; Li, Feng; Zhou, Hongcai; Zhao, Mingwen

    2016-01-01

    Light isotopes separation, such as 3He/4He, H2/D2, H2/T2, etc., is crucial for various advanced technologies including isotope labeling, nuclear weapons, cryogenics and power generation. However, their nearly identical chemical properties made the separation challenging. The low productivity of the present isotopes separation approaches hinders the relevant applications. An efficient membrane with high performance for isotopes separation is quite appealing. Based on first-principles calculations, we theoretically demonstrated that highly efficient light isotopes separation, such as 3He/4He, can be reached in a porous graphene-like carbon nitride material via quantum sieving effect. Under moderate tensile strain, the quantum sieving of the carbon nitride membrane can be effectively tuned in a continuous way, leading to a temperature window with high 3He/4He selectivity and permeance acceptable for efficient isotopes harvest in industrial application. This mechanism also holds for separation of other light isotopes, such as H2/D2, H2/T2. Such tunable quantum sieving opens a promising avenue for light isotopes separation for industrial application. PMID:26813491

  10. Heterogeneous photocatalysis for air and water treatment: Fundamental needs for quantum efficiency enhancement

    Energy Technology Data Exchange (ETDEWEB)

    Ollis, D.F. [North Carolina State Univ., Raleigh, NC (United States)

    1996-09-01

    In the remediation industries, a useful treatment technology must be {open_quotes}general, robust, and cheap{close_quotes}. Among oxidation processes, heterogeneous photocatalysis is now broadly demonstrated to destroy common water and air contaminants. The potential process uses of highly stable titania, long lived lamps (one year), and room temperature operation, indicating a simple and robust process. We are left to address the third criterion: Can photocatalysis be {open_quotes}cheap{close_quotes}? In both liquid phase and gas phase treatment and purification by photocatalysis, it is established that the primary barrier to commercialization is often cost. Cost in return is dominated by the efficiency with which solar or lamp photons are harvested for productive light, and subsequent dark, reactions. This paper therefore defines fundamental needs in photocatalysis for pollution control in terms of activities which could lead to quantum efficiency enhancement. We first recall three related definitions. The quantum yield (QY) is the ratio of molecules of reactant converted per photon absorbed, a fundamental quantity. A less fundamental, but more easily measured variable is the quantum efficiency (QE), the ratio of molecules converted per photon entering the reactor. A third variable is the energy required per order of magnitude pollutant reduction, or EEO, a definition which provides for easy energy cost comparisons among different technologies. Each measure cited here reflects the photon, and thus the electrical, cost of this photochemistry.

  11. Efficient photon extraction from a quantum dot in a broad-band planar cavity antenna

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Yong, E-mail: y.ma@hw.ac.uk; Kremer, Peter E.; Gerardot, Brian D., E-mail: B.D.Gerardot@hw.ac.uk [Institute of Photonics and Quantum Sciences, SUPA, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom)

    2014-01-14

    We analyse the extraction of photons emitted from single InAs quantum dots embedded in planar microcavities. The structures are designed to achieve broad-band operation and high-collection efficiency from a device requiring straightforward fabrication, even with electrical contacts. The designs consist of a quantum dot in a GaAs membrane with asymmetric top and bottom mirrors and a top-side solid immersion lens (SIL). Four separate cases are considered in our design: a GaAs membrane only (case 1), GaAs membrane with a glass SIL on top (case 2), a GaAs membrane with a glass SIL on top and a back mirror consisting of Au (case 3), a GaAs membrane with a glass SIL on top of a distribute Bragg reflector mirror and Au back mirror (case 4). Both finite difference time domain and analytical simulations are used to calculate the electric field, power density, and far-field radiation pattern. For optimized structures (case 4), we obtain significant extraction efficiencies (>50%) with modest Purcell enhancements (∼20%) and a large spectral full-width-half-maximum (>100 nm). The high-extraction efficiency, broad-band operation, and facile fabrication make the proposed structures promising for realistic quantum dot devices.

  12. Efficient Blue Electroluminescence Using Quantum-Confined Two-Dimensional Perovskites.

    Science.gov (United States)

    Kumar, Sudhir; Jagielski, Jakub; Yakunin, Sergii; Rice, Peter; Chiu, Yu-Cheng; Wang, Mingchao; Nedelcu, Georgian; Kim, Yeongin; Lin, Shangchao; Santos, Elton J G; Kovalenko, Maksym V; Shih, Chih-Jen

    2016-10-03

    Solution-processed hybrid organic-inorganic lead halide perovskites are emerging as one of the most promising candidates for low-cost light-emitting diodes (LEDs). However, due to a small exciton binding energy, it is not yet possible to achieve an efficient electroluminescence within the blue wavelength region at room temperature, as is necessary for full-spectrum light sources. Here, we demonstrate efficient blue LEDs based on the colloidal, quantum-confined 2D perovskites, with precisely controlled stacking down to one-unit-cell thickness (n = 1). A variety of low-k organic host compounds are used to disperse the 2D perovskites, effectively creating a matrix of the dielectric quantum wells, which significantly boosts the exciton binding energy by the dielectric confinement effect. Through the Förster resonance energy transfer, the excitons down-convert and recombine radiatively in the 2D perovskites. We report room-temperature pure green (n = 7-10), sky blue (n = 5), pure blue (n = 3), and deep blue (n = 1) electroluminescence, with record-high external quantum efficiencies in the green-to-blue wavelength region.

  13. Quantum efficiency performances of the NIR European Large Format Array detectors tested at ESTEC

    Science.gov (United States)

    Crouzet, P.-E.; Duvet, L.; de Wit, F.; Beaufort, T.; Blommaert, S.; Butler, B.; Van Duinkerken, G.; ter Haar, J.; Heijnen, J.; van der Luijt, K.; Smit, H.

    2015-10-01

    Publisher's Note: This paper, originally published on 10/12/2015, was replaced with a corrected/revised version on 10/23/2015. If you downloaded the original PDF but are unable to access the revision, please contact SPIE Digital Library Customer Service for assistance. The Payload Technology Validation Section (SRE-FV) at ESTEC has the goal to validate new technology for future or on-going mission. In this framework, a test set up to characterize the quantum efficiency of near-infrared (NIR) detectors has been created. In the context of the NIR European Large Format Array ("LFA"), 3 deliverables detectors coming from SELEX-UK/ATC (UK) on one side, and CEA/LETI- CEA/IRFU-SOFRADIR (FR) on the other side were characterized. The quantum efficiency of an HAWAII-2RG detector from Teledyne was as well measured. The capability to compare on the same setup detectors from different manufacturers is a unique asset for the future mission preparation office. This publication will present the quantum efficiency results of a HAWAII-2RG detector from Teledyne with a 2.5um cut off compared to the LFA European detectors prototypes developed independently by SELEX-UK/ATC (UK) on one side, and CEA/LETI- CEA/IRFU-SOFRADIR (FR) on the other side.

  14. A novel high-efficiency single-mode quantum dot single photon source

    DEFF Research Database (Denmark)

    Gerard, J.M.; Gregersen, Niels; Nielsen, Torben Roland

    2008-01-01

    We present a novel single-mode single photon source exploiting the emission of a semiconductor quantum dot (QD) located inside a photonic wire. Besides an excellent coupling (>95%) of QD spontaneous emission to the fundamental guided mode [1], we show that a single photon collection efficiency...... above 80% within a 0.5 numerical aperture can be achieved using a bottom Bragg mirror and a tapering of the nanowire tip. Because this photon collection strategy does not exploit the Purcell effect, it could also be efficiently applied to broadband single photon emitters such as F-centers in diamond....

  15. Efficiency enhancement of solid-state PbS quantum dot-sensitized solar cells with Al2O3 barrier layer

    KAUST Repository

    Brennan, Thomas P.

    2013-01-01

    Atomic layer deposition (ALD) was used to grow both PbS quantum dots and Al2O3 barrier layers in a solid-state quantum dot-sensitized solar cell (QDSSC). Barrier layers grown prior to quantum dots resulted in a near-doubling of device efficiency (0.30% to 0.57%) whereas barrier layers grown after quantum dots did not improve efficiency, indicating the importance of quantum dots in recombination processes. © 2013 The Royal Society of Chemistry.

  16. Significant internal quantum efficiency enhancement of GaN/AlGaN multiple quantum wells emitting at ~350 nm via step quantum well structure design

    KAUST Repository

    Wu, Feng

    2017-05-03

    Significant internal quantum efficiency (IQE) enhancement of GaN/AlGaN multiple quantum wells (MQWs) emitting at similar to 350 nm was achieved via a step quantum well (QW) structure design. The MQW structures were grown on AlGaN/AlN/sapphire templates by metal-organic chemical vapor deposition (MOCVD). High resolution x-ray diffraction (HR-XRD) and scanning transmission electron microscopy (STEM) were performed, showing sharp interface of the MQWs. Weak beam dark field imaging was conducted, indicating a similar dislocation density of the investigated MQWs samples. The IQE of GaN/AlGaN MQWs was estimated by temperature dependent photoluminescence (TDPL). An IQE enhancement of about two times was observed for the GaN/AlGaN step QW structure, compared with conventional QW structure. Based on the theoretical calculation, this IQE enhancement was attributed to the suppressed polarization-induced field, and thus the improved electron-hole wave-function overlap in the step QW.

  17. Significant internal quantum efficiency enhancement of GaN/AlGaN multiple quantum wells emitting at ~350 nm via step quantum well structure design

    Science.gov (United States)

    Wu, Feng; Sun, Haiding; AJia, Idris A.; Roqan, Iman S.; Zhang, Daliang; Dai, Jiangnan; Chen, Changqing; Feng, Zhe Chuan; Li, Xiaohang

    2017-06-01

    Significant internal quantum efficiency (IQE) enhancement of GaN/AlGaN multiple quantum wells (MQWs) emitting at ~350 nm was achieved via a step quantum well (QW) structure design. The MQW structures were grown on AlGaN/AlN/sapphire templates by metal-organic chemical vapor deposition (MOCVD). High resolution x-ray diffraction (HR-XRD) and scanning transmission electron microscopy (STEM) were performed, showing sharp interface of the MQWs. Weak beam dark field imaging was conducted, indicating a similar dislocation density of the investigated MQWs samples. The IQE of GaN/AlGaN MQWs was estimated by temperature dependent photoluminescence (TDPL). An IQE enhancement of about two times was observed for the GaN/AlGaN step QW structure, compared with conventional QW structure. Based on the theoretical calculation, this IQE enhancement was attributed to the suppressed polarization-induced field, and thus the improved electron-hole wave-function overlap in the step QW.

  18. High Quantum Efficiency AlGaN/InGaN Photodetectors

    Energy Technology Data Exchange (ETDEWEB)

    Buckley, James H; Leopold, Daniel

    2009-11-24

    High efficiency photon counting detectors in use today for high energy particle detection applications have a significant spectral mismatch with typical sources and have a number of practical problems compared with conventional bialkali photomultiplier tubes. Numerous high energy physics experiments that employ scintillation light detectors or Cherenkov detectors would benefit greatly from photomultipliers with higher quantum efficiencies. The need for extending the sensitivity of photon detectors to the blue and UV wavebands comes from the fact that both Cherenkov light and some scintillators have an emission spectrum which is peaked at short wavelengths. This research involves the development of high quantum efficiency, high gain, UV/blue photon counting detectors based on AlGaN/InGaN photocathode heterostructures grown by molecular beam epitaxy (MBE). The work could eventually lead to nearly ideal light detectors with a number of distinct advantages over existing technologies for numerous applications in high-energy physics and particle astrophysics. Potential advantages include much lower noise detection, better stability and radiation resistance than other cathode structures, very low radioactive background levels for deep underground experiments and high detection efficiency of individual UV-visible photons. We are also working on the development of photocathodes with intrinsic gain, initially improving the detection efficiency of hybrid semiconductor-vacuum tube devices, and eventually leading to an all-solid-state photomultiplier device.

  19. Fluorescence quantum efficiency of CdSe/ZnS quantum dots functionalized with amine or carboxyl groups

    Energy Technology Data Exchange (ETDEWEB)

    Pilla, Viviane, E-mail: vivianepilla@infis.ufu.br [Universidade Federal de Uberlandia (UFU), Instituto de Fisica (Brazil); Munin, Egberto [Universidade Camilo Castelo Branco (UNICASTELO), Centro de Engenharia Biomedica (Brazil)

    2012-10-15

    The thermo-optical parameters of cadmium selenide/zinc sulfide (CdSe/ZnS) core-shell quantum dots (QDs) suspended in aqueous solutions were measured using a Thermal Lens (TL) technique. TL transient measurements were performed using the mode-mismatched dual-beam (excitation and probe) configuration. A He-Ne laser at {lambda}{sub p} = 632.8 nm was used as the probe beam, and an Ar{sup +} laser (at {lambda}{sub e} = 514.5 nm) was used as the excitation beam to study the effect of the core sizes (2-4 nm) of CdSe/ZnS nanocrystals functionalized with amine (R-NH{sub 2}) or carboxyl (R-COOH) groups. The average values of the thermal diffusivity D = (1.48 {+-} 0.06) Multiplication-Sign 10{sup -3} cm{sup 2}/s obtained for QDs samples are in good agreement with the pure water solvent result. The fraction thermal load ({phi}) and radiative quantum efficiencies ({eta}) of the functionalized CdSe/ZnS QDs were determined and compared with non-functionalized CdSe/ZnS QDs. The obtained {eta} values for non-functionalized CdSe/ZnS are slightly higher than those for the QDs functionalized with amine or carboxyl groups.

  20. Efficiency at maximum power output of quantum heat engines under finite-time operation

    Science.gov (United States)

    Wang, Jianhui; He, Jizhou; Wu, Zhaoqi

    2012-03-01

    We study the efficiency at maximum power, ηm, of irreversible quantum Carnot engines (QCEs) that perform finite-time cycles between a hot and a cold reservoir at temperatures Th and Tc, respectively. For QCEs in the reversible limit (long cycle period, zero dissipation), ηm becomes identical to the Carnot efficiency ηC=1-Tc/Th. For QCE cycles in which nonadiabatic dissipation and the time spent on two adiabats are included, the efficiency ηm at maximum power output is bounded from above by ηC/(2-ηC) and from below by ηC/2. In the case of symmetric dissipation, the Curzon-Ahlborn efficiency ηCA=1-Tc/Th is recovered under the condition that the time allocation between the adiabats and the contact time with the reservoir satisfy a certain relation.

  1. Clustered Geometries Exploiting Quantum Coherence Effects for Efficient Energy Transfer in Light Harvesting

    CERN Document Server

    Ai, Qing; Jin, Bih-Yaw; Cheng, Yuan-Chung

    2013-01-01

    Elucidating quantum coherence effects and geometrical factors for efficient energy transfer in photosynthesis has the potential to uncover non-classical design principles for advanced organic materials. We study energy transfer in a linear light-harvesting model to reveal that dimerized geometries with strong electronic coherences within donor and acceptor pairs exhibit significantly improved efficiency, which is in marked contrast to predictions of the classical F\\"orster theory. We reveal that energy tuning due to coherent delocalization of photoexcitations is mainly responsible for the efficiency optimization. This coherence-assisted energy-tuning mechanism also explains the energetics and chlorophyll arrangements in the widely-studied Fenna-Matthews-Olson complex. We argue that a clustered network with rapid energy relaxation among donors and resonant energy transfer from donor to acceptor states provides a basic formula for constructing efficient light-harvesting systems, and the general principles revea...

  2. Efficiency at maximum power output of quantum heat engines under finite-time operation.

    Science.gov (United States)

    Wang, Jianhui; He, Jizhou; Wu, Zhaoqi

    2012-03-01

    We study the efficiency at maximum power, η(m), of irreversible quantum Carnot engines (QCEs) that perform finite-time cycles between a hot and a cold reservoir at temperatures T(h) and T(c), respectively. For QCEs in the reversible limit (long cycle period, zero dissipation), η(m) becomes identical to the Carnot efficiency η(C)=1-T(c)/T(h). For QCE cycles in which nonadiabatic dissipation and the time spent on two adiabats are included, the efficiency η(m) at maximum power output is bounded from above by η(C)/(2-η(C)) and from below by η(C)/2. In the case of symmetric dissipation, the Curzon-Ahlborn efficiency η(CA)=1-√(T(c)/T(h)) is recovered under the condition that the time allocation between the adiabats and the contact time with the reservoir satisfy a certain relation.

  3. Efficiency, Power and Period of a model quantum heat engine working in a finite time

    Science.gov (United States)

    Bekele, Mulugeta; Dima, Tolasa A.; Alemye, Mekuannent; Chegeno, Warga

    We take a spin-half quantum particle undergoing Carnot type cyclic process in a finite time assisted by two heat reservoirs and an external magnetic field. We find that the power of the heat engine is maximum at a particular period of the cyclic process and efficiency at the maximum power is at least half of the Carnot efficiency. We further apply the Omega-criterion for a figure of merit representing a compromise between useful power and lost power determining the corresponding efficiency for the optimization criterion to be at least three fourth of the Carnot efficiency. The authers are thankful to the International Science programme, IPS, Uppsala, Sweden for their support to our research lab.

  4. Internal quantum efficiency and tunable colour temperature in monolithic white InGaN/GaN LED

    OpenAIRE

    Titkov, Ilya E.; Yadav, Amit; Zerova, Vera L.; Zulonas, Modestas; Tsatsulnikov, Andrey F.; Lundin, Wsevolod V.; Sakharov, Alexey V.; Rafailov, Edik U.

    2014-01-01

    Internal Quantum Efficiency (IQE) of two-colour monolithic white light emitting diode (LED) was measured by temperature dependant electro-luminescence (TDEL) and analysed with modified rate equation based on ABC model. External, internal and injection efficiencies of blue and green quantum wells were analysed separately. Monolithic white LED contained one green InGaN QW and two blue QWs being separated by GaN barrier. This paper reports also the tunable behaviour of correlated colour temperat...

  5. Thermodynamic limits to the efficiency of solar energy conversion by quantum devices

    Science.gov (United States)

    Buoncristiani, A. M.; Byvik, C. E.; Smith, B. T.

    1981-01-01

    The second law of thermodynamics imposes a strict limitation to the energy converted from direct solar radiation to useful work by a quantum device. This limitation requires that the amount of energy converted to useful work (energy in any form other than heat) can be no greater than the change in free energy of the radiation fields. Futhermore, in any real energy conversion device, not all of this available free energy in the radiation field can be converted to work because of basic limitations inherent in the device itself. A thermodynamic analysis of solar energy conversion by a completely general prototypical quantum device is presented. This device is completely described by two parameters, its operating temperature T sub R and the energy threshold of its absorption spectrum. An expression for the maximum thermodynamic efficiency of a quantum solar converter was derived in terms of these two parameters and the incident radiation spectrum. Efficiency curves for assumed solar spectral irradiance corresponding to air mass zero and air mass 1.5 are presented.

  6. High-efficiency atomic entanglement concentration for quantum communication network assisted by cavity QED

    Science.gov (United States)

    Wang, Guan-Yu; Li, Tao; Deng, Fu-Guo

    2015-04-01

    Quantum entanglement is the key resource in quantum information processing, especially in quantum communication network. However, affected by the environment noise, the maximally entangled states usually collapse into nonmaximally entangled ones or even mixed states. Here we present two high-efficiency schemes to complete the entanglement concentration of nonlocal two-atom systems. Our first scheme is used to concentrate the nonlocal atomic systems in the partially entangled states with known parameters, and it has the optimal success probability. The second scheme is used to concentrate the entanglement of the nonlocal two-atom systems in the partially entangled states with unknown parameters. Compared with the other schemes for the entanglement concentration of atomic systems, our two protocols are more efficient and practical. They require only an ancillary single photon to judge whether they succeed or not, and they work in a heralded way with detection inefficiency and absence of sophisticated single-photon detectors in practical applications. Moreover, they are insensitive to both the cavity decay and atomic spontaneous emission.

  7. Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction

    Science.gov (United States)

    Lei, Fengcai; Liu, Wei; Sun, Yongfu; Xu, Jiaqi; Liu, Katong; Liang, Liang; Yao, Tao; Pan, Bicai; Wei, Shiqiang; Xie, Yi

    2016-01-01

    Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin–tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis. PMID:27585984

  8. Image quality and detective quantum efficiency of new screens HG-M and XG-S

    Energy Technology Data Exchange (ETDEWEB)

    Sawada, Michito; Tsuge, Tatsuya; Oda, Koji; Kosuge, Keiko [Anjo Kosei Hospital, Aichi (Japan)

    1998-04-01

    Imaging characteristics of the new screens HG-M (AD system) and XG-S (EX system) were examined in terms of both image quality and x-ray utilization efficiency. For the evaluation of these screens, NEQ(u), which represents an overall evaluation of the imaging properties of the screen-film system, was measured to determine image quality, and DQE(u), which represents detective quantum efficiency, was measured to determine x-ray utilization efficiency. The conventional screen HR-8, which has similar sensitivity, was examined in the same way, and the results were compared with those of the new screens. The new screens were found to have inferior graininess but superior sharpness, NEQ(u), and DQE(u) in comparison with the HR-8 screen. These results indicate that the new screens improve both image quality and detective quantum efficiency. Therefore, the HG-M and XG-S screens, which include the new phosphor technology, can be considered new-generation screens with improved image quality performance for sensitivity. In use, these screens provided superior image quality to the conventional screen with identical exposure. (author)

  9. Quantum efficiency of silica-coated rare-earth doped yttrium silicate

    Energy Technology Data Exchange (ETDEWEB)

    Cervantes-Vásquez, D., E-mail: dcervant@cnyn.unam.mx [Centro de Investigación Científica y de Educación Superior de Ensenada, Carretera Ensenada-Tijuana No. 3918, Zona Playitas, C.P. 22860 Ensenada, B.C., México (Mexico); Contreras, O.E.; Hirata, G.A. [Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, Km. 107 Carretera Tijuana-Ensenada, C.P. 22800 Ensenada, B.C., México (Mexico)

    2013-11-15

    The photoluminescent properties of rare earth-activated white-emitting Y{sub 2}SiO{sub 5}:Ce,Tb nanocrystalline phosphor prepared by two different methods, pressure-assisted combustion synthesis and sol–gel, were studied. The synthesized phosphor samples were post-annealed at 1373 K and 1623 K in order to obtain the X1-Y{sub 2}SiO{sub 5} and X2-Y{sub 2}SiO{sub 5} phases, respectively, which were confirmed by X-ray diffraction measurements. Photoluminescence analysis showed the contribution of two blue-emission bands within the 380–450 nm region originating from 5d–4f transitions in Ce{sup 3+} ions and a well-defined green emission of Tb{sup 3+} ions located at 545 nm corresponding to {sup 5}D{sub 4}→{sup 7}F{sub 5} electronic transitions. Thereafter, Y{sub 2}SiO{sub 5}:Ce,Tb powders were coated with colloidal silica in order to investigate the effect of silica coatings on their luminescent properties. Absolute fluorescence quantum efficiency measurements were carefully performed, which revealed an increase of 12% of efficiency in coated compared with bare-Y{sub 2}SiO{sub 5}:Ce,Tb phosphor. -- Highlights: • Y{sub 2}SiO{sub 5}:Ce,Tb phosphor powders were successfully coated with colloidal silica. • Post-annealing treatments improved the quantum efficiency of silica-coated Y{sub 2}SiO{sub 5}:Ce,Tb phosphors. • Absolute fluorescence quantum efficiency measurements showed an increase of 12%.

  10. Efficient method for computing the maximum-likelihood quantum state from measurements with additive Gaussian noise.

    Science.gov (United States)

    Smolin, John A; Gambetta, Jay M; Smith, Graeme

    2012-02-17

    We provide an efficient method for computing the maximum-likelihood mixed quantum state (with density matrix ρ) given a set of measurement outcomes in a complete orthonormal operator basis subject to Gaussian noise. Our method works by first changing basis yielding a candidate density matrix μ which may have nonphysical (negative) eigenvalues, and then finding the nearest physical state under the 2-norm. Our algorithm takes at worst O(d(4)) for the basis change plus O(d(3)) for finding ρ where d is the dimension of the quantum state. In the special case where the measurement basis is strings of Pauli operators, the basis change takes only O(d(3)) as well. The workhorse of the algorithm is a new linear-time method for finding the closest probability distribution (in Euclidean distance) to a set of real numbers summing to one.

  11. Quantum Coherent Three-Terminal Thermoelectrics: Maximum Efficiency at Given Power Output

    Directory of Open Access Journals (Sweden)

    Robert S. Whitney

    2016-05-01

    Full Text Available This work considers the nonlinear scattering theory for three-terminal thermoelectric devices used for power generation or refrigeration. Such systems are quantum phase-coherent versions of a thermocouple, and the theory applies to systems in which interactions can be treated at a mean-field level. It considers an arbitrary three-terminal system in any external magnetic field, including systems with broken time-reversal symmetry, such as chiral thermoelectrics, as well as systems in which the magnetic field plays no role. It is shown that the upper bound on efficiency at given power output is of quantum origin and is stricter than Carnot’s bound. The bound is exactly the same as previously found for two-terminal devices and can be achieved by three-terminal systems with or without broken time-reversal symmetry, i.e., chiral and non-chiral thermoelectrics.

  12. Spectral-gap analysis for efficient tunneling in quantum adiabatic optimization

    Science.gov (United States)

    Brady, Lucas T.; van Dam, Wim

    2016-09-01

    We investigate the efficiency of quantum adiabatic optimization when overcoming potential barriers to get from a local to a global minimum. Specifically we look at n qubit systems with symmetric cost functions f :{0,1 } n→R , where the ground state must tunnel through a potential barrier of width nα and height nβ. By the quantum adiabatic theorem the time delay sufficient to ensure tunneling grows quadratically with the inverse spectral gap during this tunneling process. We analyze barrier sizes with 1 /2 ≤α +β and α folklore result by Goldstone from 2002, which used large spin and instanton methods. Parts of our result also refine recent results by Kong and Crosson [arXiv:1511.06991] and Jiang et al. [arXiv:1603.01293] about the exponential gap scaling.

  13. Multidentate Polymer Coatings for Compact and Homogeneous Quantum Dots with Efficient Bioconjugation.

    Science.gov (United States)

    Ma, Liang; Tu, Chunlai; Le, Phuong; Chitoor, Shweta; Lim, Sung Jun; Zahid, Mohammad U; Teng, Kai Wen; Ge, Pinghua; Selvin, Paul R; Smith, Andrew M

    2016-03-16

    Quantum dots are fluorescent nanoparticles used to detect and image proteins and nucleic acids. Compared with organic dyes and fluorescent proteins, these nanocrystals have enhanced brightness, photostability, and wavelength tunability, but their larger size limits their use. Recently, multidentate polymer coatings have yielded stable quantum dots with small hydrodynamic dimensions (≤10 nm) due to high-affinity, compact wrapping around the nanocrystal. However, this coating technology has not been widely adopted because the resulting particles are frequently heterogeneous and clustered, and conjugation to biological molecules is difficult to control. In this article we develop new polymeric ligands and optimize coating and bioconjugation methodologies for core/shell CdSe/Cd(x)Zn(1-x)S quantum dots to generate homogeneous and compact products. We demonstrate that "ligand stripping" to rapidly displace nonpolar ligands with hydroxide ions allows homogeneous assembly with multidentate polymers at high temperature. The resulting aqueous nanocrystals are 7-12 nm in hydrodynamic diameter, have quantum yields similar to those in organic solvents, and strongly resist nonspecific interactions due to short oligoethylene glycol surfaces. Compared with a host of other methods, this technique is superior for eliminating small aggregates identified through chromatographic and single-molecule analysis. We also demonstrate high-efficiency bioconjugation through azide-alkyne click chemistry and self-assembly with hexa-histidine-tagged proteins that eliminate the need for product purification. The conjugates retain specificity of the attached biomolecules and are exceptional probes for immunofluorescence and single-molecule dynamic imaging. These results are expected to enable broad utilization of compact, biofunctional quantum dots for studying crowded macromolecular environments such as the neuronal synapse and cellular cytoplasm.

  14. A fast and efficient algorithm for Slater determinant updates in quantum Monte Carlo simulations.

    Science.gov (United States)

    Nukala, Phani K V V; Kent, P R C

    2009-05-28

    We present an efficient low-rank updating algorithm for updating the trial wave functions used in quantum Monte Carlo (QMC) simulations. The algorithm is based on low-rank updating of the Slater determinants. In particular, the computational complexity of the algorithm is O(kN) during the kth step compared to traditional algorithms that require O(N(2)) computations, where N is the system size. For single determinant trial wave functions the new algorithm is faster than the traditional O(N(2)) Sherman-Morrison algorithm for up to O(N) updates. For multideterminant configuration-interaction-type trial wave functions of M+1 determinants, the new algorithm is significantly more efficient, saving both O(MN(2)) work and O(MN(2)) storage. The algorithm enables more accurate and significantly more efficient QMC calculations using configuration-interaction-type wave functions.

  15. Efficiency Enhancement of Silicon Heterojunction Solar Cells via Photon Management Using Graphene Quantum Dot as Downconverters

    KAUST Repository

    Tsai, Meng-Lin

    2015-12-16

    By employing graphene quantum dots (GQDs), we have achieved a high efficiency of 16.55% in n-type Si heterojunction solar cells. The efficiency enhancement is based on the photon downconversion phenomenon of GQDs to make more photons absorbed in the depletion region for effective carrier separation, leading to the enhanced photovoltaic effect. The short circuit current and the fill factor are increased from 35.31 to 37.47 mA/cm2 and 70.29% to 72.51%, respectively. The work demonstrated here holds the promise for incorporating graphene-based materials in commercially available solar devices for developing ultra-high efficiency photovoltaic cells in the future.

  16. High quantum-efficiency photon-number-resolving detector for photonic on-chip information processing

    CERN Document Server

    Calkins, Brice; Lita, Adriana E; Metcalf, Benjamin J; Kolthammer, W Steven; Linares, Antia Lamas; Spring, Justin B; Humphreys, Peter C; Mirin, Richard P; Gates, James C; Smith, Peter G R; Walmsley, Ian A; Gerrits, Thomas; Nam, Sae Woo

    2013-01-01

    The integrated optical circuit is a promising architecture for the realization of complex quantum optical states and information networks. One element that is required for many of these applications is a high-efficiency photon detector capable of photon-number discrimination. We present an integrated photonic system in the telecom band at 1550 nm based on UV-written silica-on-silicon waveguides and modified transition-edge sensors capable of number resolution and over 40% efficiency. Exploiting the mode transmission failure of these devices, we multiplex three detectors in series to demonstrate a combined 79% +/- 2% detection efficiency with a single pass, and 88% +/- 3% at the operating wavelength of an on-chip terminal reflection grating. Furthermore, our optical measurements clearly demonstrate no significant unexplained loss in this system due to scattering or reflections. This waveguide and detector design therefore allows the placement of number-resolving single-photon detectors of predictable efficienc...

  17. Development of III-Sb Quantum Dot Systems for High Efficiency Intermediate Band Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Huffaker, Diana [Univ. of California, Los Angeles, CA (United States); Hubbard, Seth [Rochester Inst. of Technology, NY (United States); Norman, Andrew [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2015-07-31

    This project aimed to develop solar cells that can help reduce cost per watt. This work focused on developing solar cells that utilize quantum dot (QD) nanomaterials to provide multijunction solar cell efficiency at the cost of single junction solar cell. We focused on a novel concept known as intermediate band solar cells (IBSC) where an additional energy band is inserted in a single solar cell to accommodate sub-bandgap photons absorption which otherwise are lost through transmission. The additional energy band can be achieved by growing QDs within a solar cell p-n junction. Though numerous studies have been conducted to develop such QD systems, very small improvements in solar energy conversion efficiency have been reported. This is mainly due to non-optimal material parameters such as band gap, band offset etc. In this work, we identified and developed a novel QD material system that meets the requirements of IBSC more closely than the current state-of-the-art technology. To achieve these goals, we focused on three important areas of solar cell design: band structure calculations of new materials, efficient device design for high efficiency, and development of new semiconductor materials. In this project, we focused on III-Sb materials as they possess a wide range of energy bandgaps from 0.2 eV to 2eV. Despite the difficulty involved in realizing these materials, we were successfully developed these materials through a systematic approach. Materials studied in this work are AlAsSb (Aluminum Arsenide Antimonide), InAlAs (Indium Aluminum Arsenide) and InAs (Indium Arsenide). InAs was used to develop QD layers within AlAsSb and InAlAs p-n junctions. As the QDs have very small volume, up to 30 QD layers been inserted into the p-n junction to enhance light absorption. These QD multi-stack devices helped in understanding the challenges associated with the development of quantum dot solar cells. The results from this work show that the quantum dot solar cells indeed

  18. High-Efficiency Colloidal Quantum Dot Photovoltaics via Robust Self-Assembled Monolayers.

    Science.gov (United States)

    Kim, Gi-Hwan; García de Arquer, F Pelayo; Yoon, Yung Jin; Lan, Xinzheng; Liu, Mengxia; Voznyy, Oleksandr; Jagadamma, Lethy Krishnan; Abbas, Abdullah Saud; Yang, Zhenyu; Fan, Fengjia; Ip, Alexander H; Kanjanaboos, Pongsakorn; Hoogland, Sjoerd; Kim, Jin Young; Sargent, Edward H

    2015-11-11

    The optoelectronic tunability offered by colloidal quantum dots (CQDs) is attractive for photovoltaic applications but demands proper band alignment at electrodes for efficient charge extraction at minimal cost to voltage. With this goal in mind, self-assembled monolayers (SAMs) can be used to modify interface energy levels locally. However, to be effective SAMs must be made robust to treatment using the various solvents and ligands required for to fabricate high quality CQD solids. We report robust self-assembled monolayers (R-SAMs) that enable us to increase the efficiency of CQD photovoltaics. Only by developing a process for secure anchoring of aromatic SAMs, aided by deposition of the SAMs in a water-free deposition environment, were we able to provide an interface modification that was robust against the ensuing chemical treatments needed in the fabrication of CQD solids. The energy alignment at the rectifying interface was tailored by tuning the R-SAM for optimal alignment relative to the CQD quantum-confined electron energy levels. This resulted in a CQD PV record power conversion efficiency (PCE) of 10.7% with enhanced reproducibility relative to controls.

  19. A theoretical model for calculation of the detective quantum efficiency in granular scintillators

    Energy Technology Data Exchange (ETDEWEB)

    Cavouras, D. E-mail: cavouras@hol.gr; Kandarakis, I.; Tsoukos, S.; Kateris, A.; Nomicos, C.D.; Panayiotakis, G.S

    2001-11-01

    A theoretical model has been developed for calculating the detective quantum efficiency (DQE) of scintillators, by taking into account the internal structure of granular scintillators often used in medical imaging detectors. Scintillators were considered to consist of N elementary thin layers containing spherical scintillating grains of equal size. Grains were assumed to be regularly distributed within each thin layer, the thickness of the latter being equal to the grain diameter. Values of the X-ray absorption and X-ray attenuation coefficients, of the intrinsic X-ray to light conversion efficiency and of the optical scattering and absorption coefficients were used as input data to the model. Optical scattering and optical absorption coefficients were determined by fitting the model to experimental luminescence data. The model was employed to calculate the detective quantum efficiency of La{sub 2}O{sub 2}S:Tb, Y{sub 2}O{sub 2}S:Tb, Y{sub 2}O{sub 2}S:Eu, ZnSCdS:Ag, ZnSCdS:Au,Cu scintillators. Results of the calculations were found close to values published in previous studies.

  20. Necessary detection efficiencies for secure quantum key distribution and bound randomness

    Science.gov (United States)

    Acín, Antonio; Cavalcanti, Daniel; Passaro, Elsa; Pironio, Stefano; Skrzypczyk, Paul

    2016-01-01

    In recent years, several hacking attacks have broken the security of quantum cryptography implementations by exploiting the presence of losses and the ability of the eavesdropper to tune detection efficiencies. We present a simple attack of this form that applies to any protocol in which the key is constructed from the results of untrusted measurements performed on particles coming from an insecure source or channel. Because of its generality, the attack applies to a large class of protocols, from standard prepare-and-measure to device-independent schemes. Our attack gives bounds on the critical detection efficiencies necessary for secure quantum key distribution, which show that the implementation of most partly device-independent solutions is, from the point of view of detection efficiency, almost as demanding as fully device-independent ones. We also show how our attack implies the existence of a form of bound randomness, namely nonlocal correlations in which a nonsignalling eavesdropper can find out a posteriori the result of any implemented measurement.

  1. High-Efficiency Colloidal Quantum Dot Photovoltaics via Robust Self-Assembled Monolayers

    KAUST Repository

    Kim, Gi-Hwan

    2015-11-11

    © 2015 American Chemical Society. The optoelectronic tunability offered by colloidal quantum dots (CQDs) is attractive for photovoltaic applications but demands proper band alignment at electrodes for efficient charge extraction at minimal cost to voltage. With this goal in mind, self-assembled monolayers (SAMs) can be used to modify interface energy levels locally. However, to be effective SAMs must be made robust to treatment using the various solvents and ligands required for to fabricate high quality CQD solids. We report robust self-assembled monolayers (R-SAMs) that enable us to increase the efficiency of CQD photovoltaics. Only by developing a process for secure anchoring of aromatic SAMs, aided by deposition of the SAMs in a water-free deposition environment, were we able to provide an interface modification that was robust against the ensuing chemical treatments needed in the fabrication of CQD solids. The energy alignment at the rectifying interface was tailored by tuning the R-SAM for optimal alignment relative to the CQD quantum-confined electron energy levels. This resulted in a CQD PV record power conversion efficiency (PCE) of 10.7% with enhanced reproducibility relative to controls.

  2. Harmonic bath averaged Hamiltonian: an efficient tool to capture quantum effects of large systems.

    Science.gov (United States)

    Yang, Yonggang; Liu, Xiaomeng; Meuwly, Markus; Xiao, Liantuan; Jia, Suotang

    2012-11-26

    Starting from a reaction path Hamiltonian, a suitably reduced harmonic bath averaged Hamiltonian is derived by averaging over all the normal mode coordinates. Generalization of the harmonic bath averaged Hamiltonian to any dimensions are performed and the feasibility to use a linear reaction path/surface are investigated and discussed. By use of a harmonic bath averaged Hamiltonian, the tunneling splitting and proton transfer dynamics of malonaldehyde is briefly discussed and shows that the harmonic bath averaged Hamiltonian is an efficient tool to capture quantum effects in larger systems.

  3. A hybrid superconducting quantum dot acting as an efficient charge and spin Seebeck diode

    Science.gov (United States)

    Hwang, Sun-Yong; Sánchez, David; López, Rosa

    2016-09-01

    We propose a highly efficient thermoelectric diode device built from the coupling of a quantum dot with a normal or ferromagnetic electrode and a superconducting reservoir. The current shows a strongly nonlinear behavior in the forward direction (positive thermal gradients) while it almost vanishes in the backward direction (negative thermal gradients). Our discussion is supported by a gauge-invariant current-conserving transport theory accounting for electron-electron interactions inside the dot. We find that the diode behavior is greatly tuned with external gate potentials, Zeeman splittings or lead magnetizations. Our results are thus relevant for the search of novel thermoelectric devices with enhanced functionalities.

  4. Information detective quantum efficiency of X-ray film-intensifier foil systems

    Energy Technology Data Exchange (ETDEWEB)

    Hoeschen, D.; Stargardt, A.; Mirande, W.

    1988-04-01

    The capability of screen-film combinations of detection and representation of information is described by the detective quantum efficiency (DQE). The DQE may be calculated from the sensitivity, the gradient of the characteristic curve, the modulation transfer function and the Wiener spectrum. These parameters have been determined for fourteen screen-film combinations and the DQE's have been calculated. It is shown that the low frequency region the DQE does not depend on spatial frequency. This constant level of DQE is mostly dependent on the absorbance of the screens. Consequences from this fact, as well for the manufacturer as for the user of the screens, are discussed.

  5. A one-dimensional model for the quantum efficiency of front-surface-field solar cells

    Science.gov (United States)

    Yernaux, M. I.; Battochio, C.; Verlinden, P.; van de Wiele, F.

    1984-11-01

    A one-dimensional analytical model is proposed to calculate the photocurrent generated in interdigitated back contact solar cells with a high-low junction at the front illuminated surface. The high-low junction is simulated by constant doping levels, mobilities and lifetimes. A study of the quantum efficiency of front-surface-field (FSF) solar cells is made and the computer results are compared with experimental results. A method of determining the real and the effective surface recombination velocity of FSF solar cells is proposed.

  6. Efficient Energy Transfer in Light-Harvesting Systems, II: Quantum-Classical Comparison, Flux Network, and Robustness Analysis

    CERN Document Server

    Wu, Jianlan; Ma, Jian; Silbey, Robert J; Cao, Jianshu

    2011-01-01

    Following the calculation of optimal energy transfer in thermal environment in our first paper (New J. Phys. {\\bf 12}, 105012), full quantum dynamics and leading-order `classical' hopping kinetics are compared for the Fenna-Matthews-Olson (FMO) protein complex with the thermal bath described by classical white noise (the Haken-Strobl model) and by quantum Debye noise. Because the two-site quantum dynamics is fully captured by the hopping kinetics, the difference between the quantum dynamics and 'classical' kinetics is due to higher-order quantum corrections, which include non-local multi-site coherence, i.e. long-range coherence. We observe that higher-order quantum correction leads to small changes in the trapping time or in energy transfer efficiency. (1-2% in the Haken-Strobl model and $\\lessapprox 10%$ in the quantum Debye model), suggesting that quantum coherence does not extend beyond a pair of sites in FMO and the optimal efficiency in FMO can be explained by Forster rate theory. However, using the pop...

  7. Practical expressions describing detective quantum efficiency in flat-panel detectors

    Science.gov (United States)

    Kim, H. K.

    2011-11-01

    In radiology, image quality excellence is a balance between system performance and patient dose, hence x-ray systems must be designed to ensure the maximum image quality is obtained for the lowest consistent dose. The concept of detective quantum efficiency (DQE) is widely used to quantify, understand, measure, and predict the performance of x-ray detectors and imaging systems. Cascaded linear-systems theory can be used to estimate DQE based on the system design parameters and this theoretical DQE can be utilized for determining the impact of various physical processes, such as secondary quantum sinks, noise aliasing, reabsorption noise, and others. However, the prediction of DQE usually requires tremendous efforts to determine each parameter consisting of the cascaded linear-systems model. In this paper, practical DQE formalisms assessing both the photoconductor- and scintillator-based flat-panel detectors under quantum-noise-limited operation are described. The developed formalisms are experimentally validated and discussed for their limits. The formalisms described in this paper would be helpful for the rapid prediction of the DQE performances of developing systems as well as the optimal design of systems.

  8. Near-Unity Internal Quantum Efficiency of Luminescent Silicon Nanocrystals with Ligand Passivation.

    Science.gov (United States)

    Sangghaleh, Fatemeh; Sychugov, Ilya; Yang, Zhenyu; Veinot, Jonathan G C; Linnros, Jan

    2015-07-28

    Spectrally resolved photoluminescence (PL) decays were measured for samples of colloidal, ligand-passivated silicon nanocrystals. These samples have PL emission energies with peak positions in the range ∼1.4-1.8 eV and quantum yields of ∼30-70%. Their ensemble PL decays are characterized by a stretched-exponential decay with a dispersion factor of ∼0.8, which changes to an almost monoexponential character at fixed detection energies. The dispersion factors and decay rates for various detection energies were extracted from spectrally resolved curves using a mathematical approach that excluded the effect of homogeneous line width broadening. Since nonradiative recombination would introduce a random lifetime variation, leading to a stretched-exponential decay for an ensemble, we conclude that the observed monoexponential decay in size-selected ensembles signifies negligible nonradiative transitions of a similar strength to the radiative one. This conjecture is further supported as extracted decay rates agree with radiative rates reported in the literature, suggesting 100% internal quantum efficiency over a broad range of emission wavelengths. The apparent differences in the quantum yields can then be explained by a varying fraction of "dark" or blinking nanocrystals.

  9. Highly efficient luminescent solar concentrators based on earth-abundant indirect-bandgap silicon quantum dots

    Science.gov (United States)

    Meinardi, Francesco; Ehrenberg, Samantha; Dhamo, Lorena; Carulli, Francesco; Mauri, Michele; Bruni, Francesco; Simonutti, Roberto; Kortshagen, Uwe; Brovelli, Sergio

    2017-02-01

    Building-integrated photovoltaics is gaining consensus as a renewable energy technology for producing electricity at the point of use. Luminescent solar concentrators (LSCs) could extend architectural integration to the urban environment by realizing electrode-less photovoltaic windows. Crucial for large-area LSCs is the suppression of reabsorption losses, which requires emitters with negligible overlap between their absorption and emission spectra. Here, we demonstrate the use of indirect-bandgap semiconductor nanostructures such as highly emissive silicon quantum dots. Silicon is non-toxic, low-cost and ultra-earth-abundant, which avoids the limitations to the industrial scaling of quantum dots composed of low-abundance elements. Suppressed reabsorption and scattering losses lead to nearly ideal LSCs with an optical efficiency of η = 2.85%, matching state-of-the-art semi-transparent LSCs. Monte Carlo simulations indicate that optimized silicon quantum dot LSCs have a clear path to η > 5% for 1 m2 devices. We are finally able to realize flexible LSCs with performances comparable to those of flat concentrators, which opens the way to a new design freedom for building-integrated photovoltaics elements.

  10. Simple formalism for efficient derivatives and multi-determinant expansions in quantum Monte Carlo

    Science.gov (United States)

    Filippi, Claudia; Assaraf, Roland; Moroni, Saverio

    2016-05-01

    We present a simple and general formalism to compute efficiently the derivatives of a multi-determinant Jastrow-Slater wave function, the local energy, the interatomic forces, and similar quantities needed in quantum Monte Carlo. Through a straightforward manipulation of matrices evaluated on the occupied and virtual orbitals, we obtain an efficiency equivalent to algorithmic differentiation in the computation of the interatomic forces and the optimization of the orbital parameters. Furthermore, for a large multi-determinant expansion, the significant computational gain afforded by a recently introduced table method is here extended to the local value of any one-body operator and to its derivatives, in both all-electron and pseudopotential calculations.

  11. Efficient molecular quantum dynamics in coordinate and phase space using pruned bases

    CERN Document Server

    Larsson, Henrik R; Tannor, David J

    2016-01-01

    We present an efficient implementation of dynamically pruned quantum dynamics, both in coordinate space and in phase space. We combine the ideas behind the biorthogonal von Neumann basis (PvB) with the orthogonalized momentum-symmetrized Gaussians (Weylets) to create a new basis, projected Weylets, that takes the best from both methods. We benchmark pruned dynamics using phase-space-localized PvB, projected Weylets, and coordinate-space-localized DVR bases, with real-world examples in up to six dimensions. We show that coordinate-space localization is most important for efficient pruning and that pruned dynamics is much faster compared to unpruned, exact dynamics. Phase-space localization is useful for more demanding dynamics where many basis functions are required. There, projected Weylets offer a more compact representation than pruned DVR bases.

  12. Efficient molecular quantum dynamics in coordinate and phase space using pruned bases

    Science.gov (United States)

    Larsson, H. R.; Hartke, B.; Tannor, D. J.

    2016-11-01

    We present an efficient implementation of dynamically pruned quantum dynamics, both in coordinate space and in phase space. We combine the ideas behind the biorthogonal von Neumann basis (PvB) with the orthogonalized momentum-symmetrized Gaussians (Weylets) to create a new basis, projected Weylets, that takes the best from both methods. We benchmark pruned time-dependent dynamics using phase-space-localized PvB, projected Weylets, and coordinate-space-localized DVR bases, with real-world examples in up to six dimensions. For the examples studied, coordinate-space localization is the most important factor for efficient pruning and the pruned dynamics is much faster than the unpruned, exact dynamics. Phase-space localization is useful for more demanding dynamics where many basis functions are required. There, projected Weylets offer a more compact representation than pruned DVR bases.

  13. External quantum efficiency of p-i-n solar cells incorporating oligothiophene: Fullerene heterojunctions

    Energy Technology Data Exchange (ETDEWEB)

    Seifert, Holger; Schueppel, Rico; Riede, Moritz K.; Leo, Karl [Institut fuer Angewandte Photophysik, Technische Universitaet Dresden (Germany); Brier, Eduard; Reinold, Egon; Baeuerle, Peter [Institut fuer Organische Chemie II und Neue Materialien, Universitaet Ulm (Germany)

    2008-07-01

    We investigate organic p-i-n solar cells with an oligothiophene derivative as donor and Fullerene C{sub 60} as acceptor materials. This donor-acceptor heterojunction leads to solar cells with an open circuit voltage as high as 1.0 V and a reasonable power conversion efficiency of up to 3.4%. Measuring current-voltage characteristics under monochromatic illumination of low intensity (non-standard reporting conditions), we find a wavelength dependent fill factor of these photovoltaic devices. Furthermore, we determine the external quantum efficiency (EQE) from the photoresponse of these devices using a modulated monochromatic illumination on top of a white light bias as well as an external voltage bias. The EQE spectrum can be attributed to the spectrally different absorption of donor and acceptor. We discuss the dependence of the EQE spectrum from the applied external voltage with respect to the charge generation mechanism.

  14. Efficient dipolar double quantum filtering under magic angle spinning without a (1)H decoupling field.

    Science.gov (United States)

    Courtney, Joseph M; Rienstra, Chad M

    2016-08-01

    We present a systematic study of dipolar double quantum (DQ) filtering in (13)C-labeled organic solids over a range of magic-angle spinning rates, using the SPC-n recoupling sequence element with a range of n symmetry values from 3 to 11. We find that efficient recoupling can be achieved for values n⩾7, provided that the (13)C nutation frequency is on the order of 100kHz or greater. The decoupling-field dependence was investigated and explicit heteronuclear decoupling interference conditions identified. The major determinant of DQ filtering efficiency is the decoupling interference between (13)C and (1)H fields. For (13)C nutation frequencies greater than 75kHz, optimal performance is observed without an applied (1)H field. At spinning rates exceeding 20kHz, symmetry conditions as low as n=3 were found to perform adequately.

  15. Efficient quantum-classical method for computing thermal rate constant of recombination: application to ozone formation.

    Science.gov (United States)

    Ivanov, Mikhail V; Babikov, Dmitri

    2012-05-14

    Efficient method is proposed for computing thermal rate constant of recombination reaction that proceeds according to the energy transfer mechanism, when an energized molecule is formed from reactants first, and is stabilized later by collision with quencher. The mixed quantum-classical theory for the collisional energy transfer and the ro-vibrational energy flow [M. Ivanov and D. Babikov, J. Chem. Phys. 134, 144107 (2011)] is employed to treat the dynamics of molecule + quencher collision. Efficiency is achieved by sampling simultaneously (i) the thermal collision energy, (ii) the impact parameter, and (iii) the incident direction of quencher, as well as (iv) the rotational state of energized molecule. This approach is applied to calculate third-order rate constant of the recombination reaction that forms the (16)O(18)O(16)O isotopomer of ozone. Comparison of the predicted rate vs. experimental result is presented.

  16. Two-Step Efficient Deterministic Secure Quantum Communication Using Three-Qubit W State

    Institute of Scientific and Technical Information of China (English)

    YUAN Hao; ZHOU Jun; ZHANG Gang; WEI Xiang-Fei; LIU Xiang-Yuan

    2011-01-01

    A two-step deterministic secure quantum communication (DSQC) scheme using blocks of three-qubit W state is proposed. In this scheme, the secret messages can be encoded by employing four two-particle unitary operations and directly decoded by utilizing the corresponding measurements in Bell basis or single-particle basis. Comparing with most previous DSQC protocols, the present scheme has a high total efficiency, which comes up to 50%. Apart from this,it has still the advantages of high capacity as each W state can carry two bits of secret information, and high intrinsic efficiency because almost all the instances are useful. Furthermore, the security of this communication can be ensured by the decoy particle checking technique and the two-step transmitting idea.

  17. Rate equations model and optical external efficiency of optically pumped electrically driven terahertz quantum cascade lasers

    Science.gov (United States)

    Hamadou, A.; Thobel, J.-L.; Lamari, S.

    2016-10-01

    A four level rate equations model for a terahertz optically pumped electrically driven quantum cascade laser is here introduced and used to model the system both analytically and numerically. In the steady state, both in the presence and absence of the terahertz optical field, we solve the resulting nonlinear system of equations and obtain closed form expressions for the levels occupation, population inversion as well as the mid-infrared pump threshold intensity in terms of the device parameters. We also derive, for the first time for this system, an analytical formula for the optical external efficiency and analyze the simultaneous effects of the cavity length and pump intensity on it. At moderate to high pump intensities, we find that the optical external efficiency scales roughly as the reciprocal of the cavity length.

  18. Simple formalism for efficient derivatives and multi-determinant expansions in quantum Monte Carlo.

    Science.gov (United States)

    Filippi, Claudia; Assaraf, Roland; Moroni, Saverio

    2016-05-21

    We present a simple and general formalism to compute efficiently the derivatives of a multi-determinant Jastrow-Slater wave function, the local energy, the interatomic forces, and similar quantities needed in quantum Monte Carlo. Through a straightforward manipulation of matrices evaluated on the occupied and virtual orbitals, we obtain an efficiency equivalent to algorithmic differentiation in the computation of the interatomic forces and the optimization of the orbital parameters. Furthermore, for a large multi-determinant expansion, the significant computational gain afforded by a recently introduced table method is here extended to the local value of any one-body operator and to its derivatives, in both all-electron and pseudopotential calculations.

  19. Efficient and universal quantum key distribution based on chaos and middleware

    Science.gov (United States)

    Jiang, Dong; Chen, Yuanyuan; Gu, Xuemei; Xie, Ling; Chen, Lijun

    2017-01-01

    Quantum key distribution (QKD) promises unconditionally secure communications, however, the low bit rate of QKD cannot meet the requirements of high-speed applications. Despite the many solutions that have been proposed in recent years, they are neither efficient to generate the secret keys nor compatible with other QKD systems. This paper, based on chaotic cryptography and middleware technology, proposes an efficient and universal QKD protocol that can be directly deployed on top of any existing QKD system without modifying the underlying QKD protocol and optical platform. It initially takes the bit string generated by the QKD system as input, periodically updates the chaotic system, and efficiently outputs the bit sequences. Theoretical analysis and simulation results demonstrate that our protocol can efficiently increase the bit rate of the QKD system as well as securely generate bit sequences with perfect statistical properties. Compared with the existing methods, our protocol is more efficient and universal, it can be rapidly deployed on the QKD system to increase the bit rate when the QKD system becomes the bottleneck of its communication system.

  20. Efficient inorganic solid solar cells composed of perovskite and PbS quantum dots

    Science.gov (United States)

    Li, Yi; Zhu, Jun; Huang, Yang; Wei, Junfeng; Liu, Feng; Shao, Zhipeng; Hu, Linhua; Chen, Shuanghong; Yang, Shangfeng; Tang, Junwang; Yao, Jianxi; Dai, Songyuan

    2015-05-01

    Lead halide perovskite solar cells have attracted great interest due to their high efficiency and simple fabrication process. However, the high efficiency heavily relies on expensive organic hole-transporting materials (OHTMs) such as 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-MeOTAD), it is preferable to replace these expensive OHTMs by inorganic and low cost materials. Here, we report colloidal PbS quantum dots synthesized by a facile method and used as the inorganic hole-transporting material in a hybrid perovskite solar cell. By controlling the crystalline morphology of the perovskite capping layer, the recombination process is significantly retarded. Furthermore, a pure inorganic solar cell prepared by a two-step process demonstrated a nearly 8% power conversion efficiency due to efficient charge separation by a cascade of junctions and retarding charge recombination by a void-free capping layer. The stability of the inorganic solar cell was also tested with a little decay observed within ca. 100 h.Lead halide perovskite solar cells have attracted great interest due to their high efficiency and simple fabrication process. However, the high efficiency heavily relies on expensive organic hole-transporting materials (OHTMs) such as 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-MeOTAD), it is preferable to replace these expensive OHTMs by inorganic and low cost materials. Here, we report colloidal PbS quantum dots synthesized by a facile method and used as the inorganic hole-transporting material in a hybrid perovskite solar cell. By controlling the crystalline morphology of the perovskite capping layer, the recombination process is significantly retarded. Furthermore, a pure inorganic solar cell prepared by a two-step process demonstrated a nearly 8% power conversion efficiency due to efficient charge separation by a cascade of junctions and retarding charge recombination by a void-free capping layer

  1. Charging of quantum dots by sulfide redox electrolytes reduces electron injection efficiency in quantum dot sensitized solar cells.

    Science.gov (United States)

    Zhu, Haiming; Song, Nianhui; Lian, Tianquan

    2013-08-07

    In quantum dot (QD) sensitized solar cells (QDSSCs), redox electrolytes act as hole scavengers to regenerate the QD ground state from its oxidized form, thus enabling a continuous device operation. However, unlike molecular sensitizers, QDs also have redox-active trap states within the band gap, which can be charged in the presence of redox electrolyte. The effects of electrolyte induced charging of QDs on the performance of QDSSCs have not been reported. Here, using steady-state and time-resolved absorption and emission spectroscopy, we show that CdSe/CdS3MLZnCdS2MLZnS2ML core/multishell QDs are charged in the presence of sulfide electrolytes due to the reduction of surface states. As a result, exciton lifetimes in these QDs are shortened due to an Auger recombination process. Such charging induced fast Auger recombination can compete effectively with electron transfer from QDs to TiO2 and reduce the electron injection efficiency in QDSSCs. We believe that the reported charging effects are present for most colloidal nanocrystals in the presence of redox media and have important implications for designing QD-based photovoltaic and photocatalytic devices.

  2. Influence of dislocation density on internal quantum efficiency of GaN-based semiconductors

    Directory of Open Access Journals (Sweden)

    Jiadong Yu

    2017-03-01

    Full Text Available By considering the effects of stress fields coming from lattice distortion as well as charge fields coming from line charges at edge dislocation cores on radiative recombination of exciton, a model of carriers’ radiative and non-radiative recombination has been established in GaN-based semiconductors with certain dislocation density. Using vector average of the stress fields and the charge fields, the relationship between dislocation density and the internal quantum efficiency (IQE is deduced. Combined with related experimental results, this relationship is fitted well to the trend of IQEs of bulk GaN changing with screw and edge dislocation density, meanwhile its simplified form is fitted well to the IQEs of AlGaN multiple quantum well LEDs with varied threading dislocation densities but the same light emission wavelength. It is believed that this model, suitable for different epitaxy platforms such as MOCVD and MBE, can be used to predict to what extent the luminous efficiency of GaN-based semiconductors can still maintain when the dislocation density increases, so as to provide a reasonable rule of thumb for optimizing the epitaxial growth of GaN-based devices.

  3. Use of non evaporable getter pumps to ensure long term performances of high quantum efficiency photocathodes

    Energy Technology Data Exchange (ETDEWEB)

    Sertore, Daniele, E-mail: daniele.sertore@mi.infn.it; Michelato, Paolo; Monaco, Laura [Istituto Nazionale di Fisica Nucleare Sez. Milano – LASA, Via Fratelli Cervi 201, I-20090 Segrate (Italy); Manini, Paolo; Siviero, Fabrizio [SAES Getters S.p.A., Viale Italia 77, 20020 Lainate (Italy)

    2014-05-15

    High quantum efficiency photocathodes are routinely used as laser triggered emitters in the advanced high brightness electron sources based on radio frequency guns. The sensitivity of “semiconductor” type photocathodes to vacuum levels and gas composition requires special care during preparation and handling. This paper will discuss the results obtained using a novel pumping approach based on coupling a 20 l s{sup −1} sputter ion getter pump with a CapaciTorr® D100 non evaporable getter (NEG) pump. A pressure of 8⋅10{sup −8} Pa was achieved using only a sputter ion pump after a 6 day bake-out. With the addition of a NEG pump, a pressure of 2⋅10{sup −9} Pa was achieved after a 2 day bake-out. These pressure values were maintained without power due to the ability of the NEG to pump gases by chemical reaction. Long term monitoring of cathodes quantum efficiencies was also carried out at different photon wavelengths for more than two years, showing no degradation of the photoemissive film properties.

  4. Enhanced and tunable optical quantum efficiencies from plasmon bandwidth engineering in bimetallic CoAg nanoparticles

    Directory of Open Access Journals (Sweden)

    A. Malasi

    2016-10-01

    Full Text Available Plasmonic nanoparticles are amongst the most effective ways to resonantly couple optical energy into and out of nanometer sized volumes. However, controlling and/or tuning the transfer of this incident energy to the surrounding near and far field is one of the most interesting challenges in this area. Due to the dielectric properties of metallic silver (Ag, its nanoparticles have amongst the highest radiative quantum efficiencies (η, i.e., the ability to radiatively transfer the incident energy to the surrounding. Here we report the discovery that bimetallic nanoparticles of Ag made with immiscible and plasmonically weak Co metal can show comparable and/or even higher η values. The enhancement is a result of the narrowing of the plasmon bandwidth from these bimetal systems. The phenomenological explanation of this effect based on the dipolar approximation points to the reduction in radiative losses within the Ag nanoparticles when in contact with cobalt. This is also supported by a model of coupling between poor and good conductors based on the surface to volume ratio. This study presents a new type of bandwidth engineering, one based on using bimetal nanostructures, to tune and/or enhance the quality factor and quantum efficiency for near and far-field plasmonic applications.

  5. High Efficiency Quantum Well Waveguide Solar Cells and Methods for Constructing the Same

    Science.gov (United States)

    Welser, Roger E. (Inventor); Sood, Ashok K. (Inventor)

    2014-01-01

    Photon absorption, and thus current generation, is hindered in conventional thin-film solar cell designs, including quantum well structures, by the limited path length of incident light passing vertically through the device. Optical scattering into lateral waveguide structures provides a physical mechanism to increase photocurrent generation through in-plane light trapping. However, the insertion of wells of high refractive index material with lower energy gap into the device structure often results in lower voltage operation, and hence lower photovoltaic power conversion efficiency. The voltage output of an InGaAs quantum well waveguide photovoltaic device can be increased by employing a III-V material structure with an extended wide band gap emitter heterojunction. Analysis of the light IV characteristics reveals that non-radiative recombination components of the underlying dark diode current have been reduced, exposing the limiting radiative recombination component and providing a pathway for realizing solar-electric conversion efficiency of 30% or more in single junction cells.

  6. Quantum efficiency measurement of the Transiting Exoplanet Survey Satellite (TESS) CCD detectors

    Science.gov (United States)

    Krishnamurthy, A.; Villasenor, J.; Thayer, C.; Kissel, S.; Ricker, G.; Seager, S.; Lyle, R.; Deline, A.; Morgan, E.; Sauerwein, T.; Vanderspek, R.

    2016-07-01

    Very precise on-ground characterization and calibration of TESS CCD detectors will significantly assist in the analysis of the science data from the mission. An accurate optical test bench with very high photometric stability has been developed to perform precise measurements of the absolute quantum efficiency. The setup consists of a vacuum dewar with a single MIT Lincoln Lab CCID-80 device mounted on a cold plate with the calibrated reference photodiode mounted next to the CCD. A very stable laser-driven light source is integrated with a closed-loop intensity stabilization unit to control variations of the light source down to a few parts-per-million when averaged over 60 s. Light from the stabilization unit enters a 20 inch integrating sphere. The output light from the sphere produces near-uniform illumination on the cold CCD and on the calibrated reference photodiode inside the dewar. The ratio of the CCD and photodiode signals provides the absolute quantum efficiency measurement. The design, key features, error analysis, and results from the test campaign are presented.

  7. Enhanced and tunable optical quantum efficiencies from plasmon bandwidth engineering in bimetallic CoAg nanoparticles

    Science.gov (United States)

    Malasi, A.; Taz, H.; Ehrsam, M.; Goodwin, J.; Garcia, H.; Kalyanaraman, R.

    2016-10-01

    Plasmonic nanoparticles are amongst the most effective ways to resonantly couple optical energy into and out of nanometer sized volumes. However, controlling and/or tuning the transfer of this incident energy to the surrounding near and far field is one of the most interesting challenges in this area. Due to the dielectric properties of metallic silver (Ag), its nanoparticles have amongst the highest radiative quantum efficiencies (η), i.e., the ability to radiatively transfer the incident energy to the surrounding. Here we report the discovery that bimetallic nanoparticles of Ag made with immiscible and plasmonically weak Co metal can show comparable and/or even higher η values. The enhancement is a result of the narrowing of the plasmon bandwidth from these bimetal systems. The phenomenological explanation of this effect based on the dipolar approximation points to the reduction in radiative losses within the Ag nanoparticles when in contact with cobalt. This is also supported by a model of coupling between poor and good conductors based on the surface to volume ratio. This study presents a new type of bandwidth engineering, one based on using bimetal nanostructures, to tune and/or enhance the quality factor and quantum efficiency for near and far-field plasmonic applications.

  8. Degree of supersaturation: An effective tool to control the luminescence efficiency and size distribution in CdTe quantum dots

    Science.gov (United States)

    Kumar, Indrajit; Priyam, Amiya; Choubey, Ravi Kant

    2013-06-01

    Supersaturation controlled synthesis of thioglycollic acid (TGA) capped CdTe quantum dots in aqueous medium has been carried out. With a four-fold increase in the degree of supersaturation, the photoluminescence quantum efficiency of the nanoparticles was enhanced more than five times to a remarkably high value of 46%. This was accompanied by concomitant narrowing of the size distribution of the QDs. The simplified approach obviates the need for post-preparative treatments to improve the particle characteristics.

  9. Enhanced photoluminescence efficiency in AlGaN quantum wells with gradient-composition AlGaN barriers

    Science.gov (United States)

    Shevchenko, E. A.; Nechaev, D. V.; Jmerik, V. N.; Kaibyshev, V. Kh; Ivanov, S. V.; Toropov, A. A.

    2016-08-01

    We present photoluminescence studies of AIxGa1-xN/AlyGa1-yN (y = x+0.3) quantum well (QW) heterostructures with graded AI content in barrier layers, emitting in the range 285-315 nm. The best-established internal quantum efficiency of the QW emission is as high as 81% at 300 K, owing to enhanced activation energy of charge carriers and exciton binding energy in the QW heterostructure with optimized design.

  10. Sky-Blue Organic Light Emitting Diode with 37% External Quantum Efficiency Using Thermally Activated Delayed Fluorescence from Spiroacridine-Triazine Hybrid.

    Science.gov (United States)

    Lin, Ting-An; Chatterjee, Tanmay; Tsai, Wei-Lung; Lee, Wei-Kai; Wu, Meng-Jung; Jiao, Min; Pan, Kuan-Chung; Yi, Chih-Lung; Chung, Chin-Lung; Wong, Ken-Tsung; Wu, Chung-Chih

    2016-08-01

    Extremely efficient sky-blue organic electroluminescence with external quantum efficiency of ≈37% is achieved in a conventional planar device structure, using a highly efficient thermally activated delayed fluorescence emitter based on the spiroacridine-triazine hybrid and simultaneously possessing nearly unitary (100%) photoluminescence quantum yield, excellent thermal stability, and strongly horizontally oriented emitting dipoles (with a horizontal dipole ratio of 83%).

  11. Quantum Monte Carlo for large chemical systems: implementing efficient strategies for petascale platforms and beyond.

    Science.gov (United States)

    Scemama, Anthony; Caffarel, Michel; Oseret, Emmanuel; Jalby, William

    2013-04-30

    Various strategies to implement efficiently quantum Monte Carlo (QMC) simulations for large chemical systems are presented. These include: (i) the introduction of an efficient algorithm to calculate the computationally expensive Slater matrices. This novel scheme is based on the use of the highly localized character of atomic Gaussian basis functions (not the molecular orbitals as usually done), (ii) the possibility of keeping the memory footprint minimal, (iii) the important enhancement of single-core performance when efficient optimization tools are used, and (iv) the definition of a universal, dynamic, fault-tolerant, and load-balanced framework adapted to all kinds of computational platforms (massively parallel machines, clusters, or distributed grids). These strategies have been implemented in the QMC=Chem code developed at Toulouse and illustrated with numerical applications on small peptides of increasing sizes (158, 434, 1056, and 1731 electrons). Using 10-80 k computing cores of the Curie machine (GENCI-TGCC-CEA, France), QMC=Chem has been shown to be capable of running at the petascale level, thus demonstrating that for this machine a large part of the peak performance can be achieved. Implementation of large-scale QMC simulations for future exascale platforms with a comparable level of efficiency is expected to be feasible. Copyright © 2013 Wiley Periodicals, Inc.

  12. Utilizing fast multipole expansions for efficient and accurate quantum-classical molecular dynamics simulations

    Energy Technology Data Exchange (ETDEWEB)

    Schwörer, Magnus; Lorenzen, Konstantin; Mathias, Gerald; Tavan, Paul, E-mail: paul.tavan@physik.uni-muenchen.de [Lehrstuhl für BioMolekulare Optik, Ludwig–Maximilians Universität München, Oettingenstr. 67, 80538 München (Germany)

    2015-03-14

    Recently, a novel approach to hybrid quantum mechanics/molecular mechanics (QM/MM) molecular dynamics (MD) simulations has been suggested [Schwörer et al., J. Chem. Phys. 138, 244103 (2013)]. Here, the forces acting on the atoms are calculated by grid-based density functional theory (DFT) for a solute molecule and by a polarizable molecular mechanics (PMM) force field for a large solvent environment composed of several 10{sup 3}-10{sup 5} molecules as negative gradients of a DFT/PMM hybrid Hamiltonian. The electrostatic interactions are efficiently described by a hierarchical fast multipole method (FMM). Adopting recent progress of this FMM technique [Lorenzen et al., J. Chem. Theory Comput. 10, 3244 (2014)], which particularly entails a strictly linear scaling of the computational effort with the system size, and adapting this revised FMM approach to the computation of the interactions between the DFT and PMM fragments of a simulation system, here, we show how one can further enhance the efficiency and accuracy of such DFT/PMM-MD simulations. The resulting gain of total performance, as measured for alanine dipeptide (DFT) embedded in water (PMM) by the product of the gains in efficiency and accuracy, amounts to about one order of magnitude. We also demonstrate that the jointly parallelized implementation of the DFT and PMM-MD parts of the computation enables the efficient use of high-performance computing systems. The associated software is available online.

  13. Titanium oxide morphology controls charge collection efficiency in quantum dot solar cells.

    Science.gov (United States)

    Kolay, Ankita; Kumar, P Naresh; Kumar, Sarode Krishna; Deepa, Melepurath

    2017-02-08

    Charge transfer at the TiO2/quantum dots (QDs) interface, charge collection at the TiO2/QDs/current collector (FTO or SnO2:F) interface, and back electron transfer at the TiO2/QDs/S(2-) interface are processes controlled by the electron transport layer or TiO2. These key processes control the power conversion efficiencies (PCEs) of quantum dot solar cells (QDSCs). Here, four TiO2 morphologies, porous nanoparticles (PNPs), nanowires (NWs), nanosheets (NSHs) and nanoparticles (NPs), were sensitized with CdS and the photovoltaic performances were compared. The marked differences in the cell parameters on going from one morphology to the other have been explained by correlating the shape, structure and the above-described interfacial properties of a given TiO2 morphology to the said parameters. The average magnitudes of PCEs follow the order: NWs (5.96%) > NPs (4.95%) > PNPs (4.85%) > NSHs (2.5%), with the champion cell based on NWs exhibiting a PCE of 6.29%. For NWs, an optimal balance between the fast photo-excited electron injection to NWs at the NW/CdS interface, the high resistance offered at the TiO2 NW/CdS/S(2-) interfaces to electron recombination with the oxidized electrolyte or with the holes in CdS, the low electron transport resistance in NWs, and low dark currents, yields the highest efficiency due to directional unhindered transport of electrons afforded by the NWs. For NSHs, electron trapping in the two dimensional sheets, and a high electron recombination rate prevent the effective transfer of electrons to FTO, thus reducing short circuit current density significantly, resulting in a poor performance. This study provides a deep understanding of charge transfer, transport and collection processes necessary for the design of efficient QDSCs.

  14. Detective quantum efficiency of photon-counting x-ray detectors.

    Science.gov (United States)

    Tanguay, Jesse; Yun, Seungman; Kim, Ho Kyung; Cunningham, Ian A

    2015-01-01

    Single-photon-counting (SPC) x-ray imaging has the potential to improve image quality and enable novel energy-dependent imaging methods. Similar to conventional detectors, optimizing image SPC quality will require systems that produce the highest possible detective quantum efficiency (DQE). This paper builds on the cascaded-systems analysis (CSA) framework to develop a comprehensive description of the DQE of SPC detectors that implement adaptive binning. The DQE of SPC systems can be described using the CSA approach by propagating the probability density function (PDF) of the number of image-forming quanta through simple quantum processes. New relationships are developed to describe PDF transfer through serial and parallel cascades to accommodate scatter reabsorption. Results are applied to hypothetical silicon and selenium-based flat-panel SPC detectors including the effects of reabsorption of characteristic/scatter photons from photoelectric and Compton interactions, stochastic conversion of x-ray energy to secondary quanta, depth-dependent charge collection, and electronic noise. Results are compared with a Monte Carlo study. Depth-dependent collection efficiency can result in substantial broadening of photopeaks that in turn may result in reduced DQE at lower x-ray energies (20-45 keV). Double-counting interaction events caused by reabsorption of characteristic/scatter photons may result in falsely inflated image signal-to-noise ratio and potential overestimation of the DQE. The CSA approach is extended to describe signal and noise propagation through photoelectric and Compton interactions in SPC detectors, including the effects of escape and reabsorption of emission/scatter photons. High-performance SPC systems can be achieved but only for certain combinations of secondary conversion gain, depth-dependent collection efficiency, electronic noise, and reabsorption characteristics.

  15. Detective quantum efficiency of photon-counting x-ray detectors

    Energy Technology Data Exchange (ETDEWEB)

    Tanguay, Jesse, E-mail: jessetan@mail.ubc.ca [Robarts Research Institute, Western University, London, Ontario N6A 5C1, Canadaand Department of Medical Biophysics, Western University, London, Ontario, N6A 3K7 (Canada); Yun, Seungman [Biomedical Engineering Program, Western University, London, Ontario, N6A 3K7, Canadaand School of Mechanical Engineering, Pusan National University, Jangjeon-dong, Geumjeong-gu, Busan 609-73 (Korea, Republic of); Kim, Ho Kyung [School of Mechanical Engineering, Pusan National University, Jangjeon-dong, Geumjeong-gu, Busan 609-73 (Korea, Republic of); Cunningham, Ian A. [Robarts Research Institute, Western University, London, Ontario N6A 5C1 (Canada); Department of Medical Biophysics, Western University, London, Ontario, N6A 3K7 (Canada); Biomedical Engineering Program, Western University, London, Ontario, N6A 3K7 (Canada)

    2015-01-15

    Purpose: Single-photon-counting (SPC) x-ray imaging has the potential to improve image quality and enable novel energy-dependent imaging methods. Similar to conventional detectors, optimizing image SPC quality will require systems that produce the highest possible detective quantum efficiency (DQE). This paper builds on the cascaded-systems analysis (CSA) framework to develop a comprehensive description of the DQE of SPC detectors that implement adaptive binning. Methods: The DQE of SPC systems can be described using the CSA approach by propagating the probability density function (PDF) of the number of image-forming quanta through simple quantum processes. New relationships are developed to describe PDF transfer through serial and parallel cascades to accommodate scatter reabsorption. Results are applied to hypothetical silicon and selenium-based flat-panel SPC detectors including the effects of reabsorption of characteristic/scatter photons from photoelectric and Compton interactions, stochastic conversion of x-ray energy to secondary quanta, depth-dependent charge collection, and electronic noise. Results are compared with a Monte Carlo study. Results: Depth-dependent collection efficiency can result in substantial broadening of photopeaks that in turn may result in reduced DQE at lower x-ray energies (20–45 keV). Double-counting interaction events caused by reabsorption of characteristic/scatter photons may result in falsely inflated image signal-to-noise ratio and potential overestimation of the DQE. Conclusions: The CSA approach is extended to describe signal and noise propagation through photoelectric and Compton interactions in SPC detectors, including the effects of escape and reabsorption of emission/scatter photons. High-performance SPC systems can be achieved but only for certain combinations of secondary conversion gain, depth-dependent collection efficiency, electronic noise, and reabsorption characteristics.

  16. Internal quantum efficiency in yellow-amber light emitting AlGaN-InGaN-GaN heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Ngo, Thi Huong; Gil, Bernard; Valvin, Pierre [Laboratoire Charles Coulomb – UMR 5221, CNRS and University Montpellier, Case courier 074, 34095 Montpellier Cedex 5 (France); Damilano, Benjamin; Lekhal, Kaddour; De Mierry, Philippe [CRHEA-CNRS Centre de Recherche sur l' Hétéro-Epitaxie et ses Applications, Centre National de la Recherche Scientifique, rue Bernard Gregory, 06560 Valbonne (France)

    2015-09-21

    We determine the internal quantum efficiency of strain-balanced AlGaN-InGaN-GaN hetero-structures designed for yellow-amber light emission, by using a recent model based on the kinetics of the photoluminescence decay initiated by Iwata et al. [J. Appl. Phys. 117, 075701 (2015)]. Our results indicate that low temperature internal quantum efficiencies sit in the 50% range and we measure that adding an AlGaN layer increases the internal quantum efficiency from 50% up to 57% with respect to the GaN-InGaN case. More dramatic, it almost doubles from 2.5% up to 4.3% at room temperature.

  17. Efficient single-photon source based on a deterministically fabricated single quantum dot - microstructure with backside gold mirror

    Science.gov (United States)

    Fischbach, Sarah; Kaganskiy, Arsenty; Tauscher, Esra Burcu Yarar; Gericke, Fabian; Thoma, Alexander; Schmidt, Ronny; Strittmatter, André; Heindel, Tobias; Rodt, Sven; Reitzenstein, Stephan

    2017-07-01

    We present an efficient broadband single-photon source which is fabricated by a flip-chip gold-bonding technique and in-situ electron beam lithography. The device comprises a single InGaAs quantum dot that is centered at the bottom of a monolithic mesa structure and located above a gold mirror for enhanced photon-extraction efficiency. We show a photon-extraction efficiency of ηex t=(18 ±2 ) % into a numerical aperture of 0.4 and a high suppression of multi-photon events from this source with g(2 )(0 )=0.015 ±0.009 . Our deterministic device with a backside gold mirror can be combined with electrical contacts and piezo-tuning capabilities in future refinements, which represents an important step towards a spectrally tunable plug-and-play quantum-light source with broadband enhancement for photonic quantum networks.

  18. Carrier Localization Effects in InGaN/GaN Multiple-Quantum-Wells LED Nanowires: Luminescence Quantum Efficiency Improvement and “Negative” Thermal Activation Energy

    OpenAIRE

    Wei Bao; Zhicheng Su; Changcheng Zheng; Jiqiang Ning; Shijie Xu

    2016-01-01

    Two-dimensional InGaN/GaN multiple-quantum-wells (MQW) LED structure was nanotextured into quasi-one-dimensional nanowires (NWs) with different average diameters with a combination approach of Ni nanoislands as mask + dry etching. Such nanotexturing bring out several appealing effects including deeper localization of carriers and significant improvement in quantum efficiency (e.g., from 4.76% of the planar MQW structure to 12.5% of the 160 nm MQW NWs) of light emission in the whole interested...

  19. Highly Efficient Nondoped Organic Light Emitting Diodes Based on Thermally Activated Delayed Fluorescence Emitter with Quantum-Well Structure.

    Science.gov (United States)

    Meng, Lingqiang; Wang, Hui; Wei, Xiaofang; Liu, Jianjun; Chen, Yongzhen; Kong, Xiangbin; Lv, Xiaopeng; Wang, Pengfei; Wang, Ying

    2016-08-17

    Highly efficiency nondoped thermally activated delayed fluorescence (TADF) organic light emitting diodes (OLEDs) with multiquantum wells structure were demonstrated. By using an emitting layer with seven quantum wells, the nondoped TADF OLEDs exhibit high efficiency with EQE of 22.6%, a current efficiency of 69 cd/A, and a power efficiency of 50 lm/W, which are higher than those of the conventional doped OLED and among the best of the TADF OLEDs. The high performance of the devices can be ascribed to effective confinement of the charges and excitons in the emission layer by the quantum well structure. The emission layer with multiquantum well structure is demonstrated to be cost effective for highly efficient nondoped TADF OLEDs and holds great potential for organic electronics.

  20. Internal quantum efficiency and tunable colour temperature in monolithic white InGaN/GaN LED

    Science.gov (United States)

    Titkov, Ilya E.; Yadav, Amit; Zerova, Vera L.; Zulonas, Modestas; Tsatsulnikov, Andrey F.; Lundin, Wsevolod V.; Sakharov, Alexey V.; Rafailov, Edik U.

    2014-03-01

    Internal Quantum Efficiency (IQE) of two-colour monolithic white light emitting diode (LED) was measured by temperature dependant electro-luminescence (TDEL) and analysed with modified rate equation based on ABC model. External, internal and injection efficiencies of blue and green quantum wells were analysed separately. Monolithic white LED contained one green InGaN QW and two blue QWs being separated by GaN barrier. This paper reports also the tunable behaviour of correlated colour temperature (CCT) in pulsed operation mode and effect of self-heating on device performance.

  1. Effect of Particle Size and Capping on Photoluminescence Quantum Efficiency of 1,3,5-Triphenyl-2-pyrazoline Nanocrystals

    Institute of Scientific and Technical Information of China (English)

    XIAO,De-Bao; TIAN,Zhi-Yuan; XI,Lu; ZHAO,Li-Yun; YANG,Wen-Sheng; YAO,Jian-Nian

    2003-01-01

    Organic nanocrystals of 1,3,5-triphenyl-2-pyrazoline(TPP) with a series of sizes were synthesized by reprecipitation method. The luminescence quantum efficiency of TPP nanocrystals increases from 24.2% for the nanocrystals with an average size of 300 nm to 34.6% for those with an average size of 20 nm. Surface cappinb by polyvinyl pyrrolidone (PVP) will improve the quantum efficiency of TPP nanocrystals. The size-dependence and equilibrium between the TPP monomers and the aggregates in TPP nanocrystals.

  2. PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere.

    Science.gov (United States)

    Zhang, Jianbing; Gao, Jianbo; Church, Carena P; Miller, Elisa M; Luther, Joseph M; Klimov, Victor I; Beard, Matthew C

    2014-10-08

    Colloidal quantum dots (QDs) are promising candidates for the next generation of photovoltaic (PV) technologies. Much of the progress in QD PVs is based on using PbS QDs, partly because they are stable under ambient conditions. There is considerable interest in extending this work to PbSe QDs, which have shown an enhanced photocurrent due to multiple exciton generation (MEG). One problem complicating such device-based studies is a poor stability of PbSe QDs toward exposure to ambient air. Here we develop a direct cation exchange synthesis to produce PbSe QDs with a large range of sizes and with in situ chloride and cadmium passivation. The synthesized QDs have excellent air stability, maintaining their photoluminescence quantum yield under ambient conditions for more than 30 days. Using these QDs, we fabricate high-performance solar cells without any protection and demonstrate a power conversion efficiency exceeding 6%, which is a current record for PbSe QD solar cells.

  3. Detective quantum efficiency dependence on x-ray energy weighting in mammography

    Energy Technology Data Exchange (ETDEWEB)

    Cahn, R. N. [Lawrence Berkeley National Laboratory, Berkeley, California 94707 (United States); Cederstroem, B. [Royal Institute of Technology, Frescativaegen 24, 10405 Stockholm, (Sweden); Danielsson, M. [Royal Institute of Technology, Frescativaegen 24, 10405 Stockholm, (Sweden); Hall, A. [Royal Institute of Technology, Frescativaegen 24, 10405 Stockholm, (Sweden); Lundqvist, M. [Royal Institute of Technology, Frescativaegen 24, 10405 Stockholm, (Sweden); Nygren, D. [Lawrence Berkeley National Laboratory, Berkeley, California 94707 (United States)

    1999-12-01

    An evaluation of the dependence of detective quantum efficiency (DQE) on the incident energy spectrum has been made for mammography. The DQE dependence on the energy spectrum has been evaluated for energy-integrating detectors, photon-counting detectors, and detectors that measure the energy of each photon. To isolate the effect of the x-ray energy spectrum the detector has been assumed to be ideal, i.e., all noise sources are assumed to be zero except for quantum fluctuations. The result shows that the improvement in DQE, if the energy-integrating detector is compared to a single-photon counting detector, is of the order of 10%. Comparing the energy-integrating detector and the detector measuring the energy for each photon the improvement is around 30% using a molybdenum anode spectrum typical in mammography. It is shown that the optimal weight factors to combine the data in the case the energy is measured are very well approximated if the weight factors are proportional to E{sup -3}. Another conclusion is that in calculating the DQE, a detector should be compared to one that uses ideal energy weighting for each photon since this provides the best signal-to-noise ratio. This has generally been neglected in the literature. (c) 1999 American Association of Physicists in Medicine.

  4. Fair and Efficient Packet Scheduling Using Resilient Quantum Round-Robin

    Directory of Open Access Journals (Sweden)

    Guikai Liu

    2014-02-01

    Full Text Available Round-robin based packet scheduling algorithms are suitable for high-speed networks, but in a variable-length packet environment, this kind of scheduling algorithm need consider packet length to guarantee scheduling fairness. Previous schemes are not perfect for fairness and efficiency. This paper presents a new easily implementable scheduling discipline, called Resilient Quantum Round-Robin (RQRR, in which the quantum given to each of the flows in a round is not fixed and is calculated depending on the transmission situation of all the flows in the previous round. We prove that the implementation complexity of RQRR is O (1 with respect to the number of flows. We analytically prove the fairness properties of RQRR, and show that its relative fairness measure has an upper bound of 7Max-1, where Max is the size of the largest packets. Finally, we present simulation results comparing the fairness and performance characteristics of RQRR with deficit round-robin (DRR, which show that RQRR achieves better short time scale fairness and scheduling delay properties.

  5. Near-unity quantum efficiency of broadband black silicon photodiodes with an induced junction

    Science.gov (United States)

    Juntunen, Mikko A.; Heinonen, Juha; Vähänissi, Ville; Repo, Päivikki; Valluru, Dileep; Savin, Hele

    2016-12-01

    Ideal photodiodes can detect all incoming photons independently of the wavelength, angle or intensity of the incident light. Present-day photodiodes notably suffer from optical losses and generated charge carriers are often lost via recombination. Here, we demonstrate a device with an external quantum efficiency above 96% over the wavelength range 250-950 nm. Instead of a conventional p-n junction, we use negatively charged alumina to form an inversion layer that generates a collecting junction extending to a depth of 30 µm in n-type silicon with bulk resistivity larger than 10 kΩ cm. We enhance the collection efficiency further by nanostructuring the photodiode surface, which results in higher effective charge density and increased charge-carrier concentration in the inversion layer. Additionally, nanostructuring and efficient surface passivation allow for a reliable device response with incident angles up to 70°. We expect the considered device to improve data quality, reduce the area of photodiodes as well as decrease the cost per pixel.

  6. Go Pink! The Effect of Secondary Quanta on Detective Quantum Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Watson, Scott [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-09-05

    Photons are never directly observable. Consequently, we often use photoelectric detectors (eg CCDs) to record associated photoelectrons statistically. Nonetheless, it is an implicit goal of radiographic detector designers to achieve the maximum possible detector efficiency1. In part the desire for ever higher efficiency has been due to the fact that detectors are far less expensive than associated accelerator facilities (e.g. DARHT and PHERMEX2). In addition, higher efficiency detectors often have better spatial resolution. Consequently, the optimization of the detector, not the accelerator, is the system component with the highest leverage per dollar. In recent years, imaging scientists have adopted the so-called Detective Quantum Efficiency, or DQE as a summary measure of detector performance. Unfortunately, owing to the complex nature of the trade-space associated with detector components, and the natural desire for simplicity and low(er) cost, there has been a recent trend in Los Alamos to focus only on the zerofrequency efficiency, or DQE(0), when designing such systems. This narrow focus leads to system designs that neglect or even ignore the importance of high-spatial-frequency image components. In this paper we demonstrate the significant negative impact of these design choices on the Noise Power Spectrum1 (NPS) and recommend a more holistic approach to detector design. Here we present a statistical argument which indicates that a very large number (>20) of secondary quanta (typically visible light and/or recorded photo-electrons) are needed to take maximum advantage of the primary quanta (typically x-rays or protons) which are available to form an image. Since secondary particles come in bursts, they are not independent. In short, we want to maximize the pink nature of detector noise at DARHT.

  7. Efficient bit sifting scheme of post-processing in quantum key distribution

    Science.gov (United States)

    Li, Qiong; Le, Dan; Wu, Xianyan; Niu, Xiamu; Guo, Hong

    2015-10-01

    Bit sifting is an important step in the post-processing of quantum key distribution (QKD). Its function is to sift out the undetected original keys. The communication traffic of bit sifting has essential impact on the net secure key rate of a practical QKD system. In this paper, an efficient bit sifting scheme is presented, of which the core is a lossless source coding algorithm. Both theoretical analysis and experimental results demonstrate that the performance of the scheme is approaching the Shannon limit. The proposed scheme can greatly decrease the communication traffic of the post-processing of a QKD system, which means the proposed scheme can decrease the secure key consumption for classical channel authentication and increase the net secure key rate of the QKD system, as demonstrated by analyzing the improvement on the net secure key rate. Meanwhile, some recommendations on the application of the proposed scheme to some representative practical QKD systems are also provided.

  8. A Novel Quantum Cost Efficient Reversible Full Adder Gate in Nanotechnology

    CERN Document Server

    Islam, Md Saiful

    2010-01-01

    Reversible logic has become one of the promising research directions in low power dissipating circuit design in the past few years and has found its applications in low power CMOS design, cryptography, optical information processing and nanotechnology. This paper presents a novel and quantum cost efficient reversible full adder gate in nanotechnology. This gate can work singly as a reversible full adder unit and requires only one clock cycle. The proposed gate is a universal gate in the sense that it can be used to synthesize any arbitrary Boolean functions. It has been demonstrated that the hardware complexity offered by the proposed gate is less than the existing counterparts. The proposed reversible full adder gate also adheres to the theoretical minimum established by the researchers.

  9. Photoluminescence quantum efficiency of Er optical centers in GaN epilayers.

    Science.gov (United States)

    Ho, V X; Dao, T V; Jiang, H X; Lin, J Y; Zavada, J M; McGill, S A; Vinh, N Q

    2017-01-05

    We report the quantum efficiency of photoluminescence processes of Er optical centers as well as the thermal quenching mechanism in GaN epilayers prepared by metal-organic chemical vapor deposition. High resolution infrared spectroscopy and temperature dependence measurements of photoluminescence intensity from Er ions in GaN under resonant excitation excitations were performed. Data provide a picture of the thermal quenching processes and activation energy levels. By comparing the photoluminescence from Er ions in the epilayer with a reference sample of Er-doped SiO2, we find that the fraction of Er ions that emits photon at 1.54 μm upon a resonant optical excitation is approximately 68%. This result presents a significant step in the realization of GaN:Er epilayers as an optical gain medium at 1.54 μm.

  10. Design of efficient full adder in quantum-dot cellular automata.

    Science.gov (United States)

    Sen, Bibhash; Rajoria, Ayush; Sikdar, Biplab K

    2013-01-01

    Further downscaling of CMOS technology becomes challenging as it faces limitation of feature size reduction. Quantum-dot cellular automata (QCA), a potential alternative to CMOS, promises efficient digital design at nanoscale. Investigations on the reduction of QCA primitives (majority gates and inverters) for various adders are limited, and very few designs exist for reference. As a result, design of adders under QCA framework is gaining its importance in recent research. This work targets developing multi-layered full adder architecture in QCA framework based on five-input majority gate proposed here. A minimum clock zone (2 clock) with high compaction (0.01 μ m(2)) for a full adder around QCA is achieved. Further, the usefulness of such design is established with the synthesis of high-level logic. Experimental results illustrate the significant improvements in design level in terms of circuit area, cell count, and clock compared to that of conventional design approaches.

  11. Design of Efficient Full Adder in Quantum-Dot Cellular Automata

    Directory of Open Access Journals (Sweden)

    Bibhash Sen

    2013-01-01

    Full Text Available Further downscaling of CMOS technology becomes challenging as it faces limitation of feature size reduction. Quantum-dot cellular automata (QCA, a potential alternative to CMOS, promises efficient digital design at nanoscale. Investigations on the reduction of QCA primitives (majority gates and inverters for various adders are limited, and very few designs exist for reference. As a result, design of adders under QCA framework is gaining its importance in recent research. This work targets developing multi-layered full adder architecture in QCA framework based on five-input majority gate proposed here. A minimum clock zone (2 clock with high compaction (0.01 μm2 for a full adder around QCA is achieved. Further, the usefulness of such design is established with the synthesis of high-level logic. Experimental results illustrate the significant improvements in design level in terms of circuit area, cell count, and clock compared to that of conventional design approaches.

  12. Electrostatic Stabilized InP Colloidal Quantum Dots with High Photoluminescence Efficiency.

    Science.gov (United States)

    Mnoyan, Anush N; Kirakosyan, Artavazd Gh; Kim, Hyunki; Jang, Ho Seong; Jeon, Duk Young

    2015-06-30

    Electrostatically stabilized InP quantum dots (QDs) showing a high luminescence yield of 16% without any long alkyl chain coordinating ligands on their surface are demonstrated. This is achieved by UV-etching the QDs in the presence of fluoric and sulfuric acids. Fluoric acid plays a critical role in selectively etching nonradiative sites during the ligand-exchange process and in relieving the acidity of the solution to prevent destruction of the QDs. Given that the InP QDs show high luminescence without any electrical barriers, such as long alkyl ligands or inorganic shells, this method can be applied for QD treatment for application to highly efficient QD-based optoelectronic devices.

  13. High Quantum Efficiency and High Concentration Erbium-Doped Silica Glasses Fabricated by Sintering Nanoporous Glasses

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    A new method was used to prepare erbium-doped high silica (SiO2%>96%) glasses by sintering nanoporous glasses. The concentration of erbium ions in high silica glasses can be considerably more than that in silica glasses prepared by using conventional methods. The fluorescence of 1532 nm has an FWHM (Full Wave at Half Maximum) of 50 nm, wider than 35 nm of EDSFA (erbium-doped silica fiber amplifer), and hence the glass possesses potential application in broadband fiber amplifiers. The Judd-Ofelt theoretical analysis reflects that the quantum efficiency of this erbium-doped glass is about 0.78, although the erbium concentration in this glass (6×103) is about twenty times higher than that in silica glass. These excellent characteristics of Er-doped high silica glass will be conducive to its usage in optical amplifiers and microchip lasers.

  14. Efficient Implementation of Many-body Quantum Chemical Methods on the Intel Xeon Phi Coprocessor

    Energy Technology Data Exchange (ETDEWEB)

    Apra, Edoardo; Klemm, Michael; Kowalski, Karol

    2014-12-01

    This paper presents the implementation and performance of the highly accurate CCSD(T) quantum chemistry method on the Intel Xeon Phi coprocessor within the context of the NWChem computational chemistry package. The widespread use of highly correlated methods in electronic structure calculations is contingent upon the interplay between advances in theory and the possibility of utilizing the ever-growing computer power of emerging heterogeneous architectures. We discuss the design decisions of our implementation as well as the optimizations applied to the compute kernels and data transfers between host and coprocessor. We show the feasibility of adopting the Intel Many Integrated Core Architecture and the Intel Xeon Phi coprocessor for developing efficient computational chemistry modeling tools. Remarkable scalability is demonstrated by benchmarks. Our solution scales up to a total of 62560 cores with the concurrent utilization of Intel Xeon processors and Intel Xeon Phi coprocessors.

  15. Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots.

    Science.gov (United States)

    Meinardi, Francesco; McDaniel, Hunter; Carulli, Francesco; Colombo, Annalisa; Velizhanin, Kirill A; Makarov, Nikolay S; Simonutti, Roberto; Klimov, Victor I; Brovelli, Sergio

    2015-10-01

    Luminescent solar concentrators serving as semitransparent photovoltaic windows could become an important element in net zero energy consumption buildings of the future. Colloidal quantum dots are promising materials for luminescent solar concentrators as they can be engineered to provide the large Stokes shift necessary for suppressing reabsorption losses in large-area devices. Existing Stokes-shift-engineered quantum dots allow for only partial coverage of the solar spectrum, which limits their light-harvesting ability and leads to colouring of the luminescent solar concentrators, complicating their use in architecture. Here, we use quantum dots of ternary I-III-VI2 semiconductors to realize the first large-area quantum dot-luminescent solar concentrators free of toxic elements, with reduced reabsorption and extended coverage of the solar spectrum. By incorporating CuInSexS2-x quantum dots into photo-polymerized poly(lauryl methacrylate), we obtain freestanding, colourless slabs that introduce no distortion to perceived colours and are thus well suited for the realization of photovoltaic windows. Thanks to the suppressed reabsorption and high emission efficiencies of the quantum dots, we achieve an optical power efficiency of 3.2%. Ultrafast spectroscopy studies suggest that the Stokes-shifted emission involves a conduction-band electron and a hole residing in an intragap state associated with a native defect.

  16. Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Meinardi, Francesco; McDaniel, Hunter; Carulli, Francesco; Colombo, Annalisa; Velizhanin, Kirill A.; Makarov, Nikolay S.; Simonutti, Roberto; Klimov, Victor I.; Brovelli, Sergio

    2015-08-24

    Luminescent solar concentrators serving as semitransparent photovoltaic windows could become an important element in net zero energy consumption buildings of the future. Colloidal quantum dots are promising materials for luminescent solar concentrators as they can be engineered to provide the large Stokes shift necessary for suppressing reabsorption losses in large-area devices. Existing Stokes-shift-engineered quantum dots allow for only partial coverage of the solar spectrum, which limits their light-harvesting ability and leads to colouring of the luminescent solar concentrators, complicating their use in architecture. Here, we use quantum dots of ternary I–III–VI2 semiconductors to realize the first large-area quantum dot–luminescent solar concentrators free of toxic elements, with reduced reabsorption and extended coverage of the solar spectrum. By incorporating CuInSexS2–x quantum dots into photo-polymerized poly(lauryl methacrylate), we obtain freestanding, colourless slabs that introduce no distortion to perceived colours and are thus well suited for the realization of photovoltaic windows. Thanks to the suppressed reabsorption and high emission efficiencies of the quantum dots, we achieve an optical power efficiency of 3.2%. Ultrafast spectroscopy studies suggest that the Stokes-shifted emission involves a conduction-band electron and a hole residing in an intragap state associated with a native defect.

  17. Study of a prototype high quantum efficiency thick scintillation crystal video-electronic portal imaging device.

    Science.gov (United States)

    Samant, Sanjiv S; Gopal, Arun

    2006-08-01

    Image quality in portal imaging suffers significantly from the loss in contrast and spatial resolution that results from the excessive Compton scatter associated with megavoltage x rays. In addition, portal image quality is further reduced due to the poor quantum efficiency (QE) of current electronic portal imaging devices (EPIDs). Commercial video-camera-based EPIDs or VEPIDs that utilize a thin phosphor screen in conjunction with a metal buildup plate to convert the incident x rays to light suffer from reduced light production due to low QE (quantum efficiency (DQE). A theoretical expression of DQE(0) was developed to be used as a predictive model to propose improvements in the optics associated with the light detection. The prototype TSC provides DQE(0)=0.02 with its current imaging geometry, which is an order of magnitude greater than that for commercial VEPID systems and comparable to flat-panel imaging systems. Following optimization in the imaging geometry and the use of a high-end, cooled charge-coupled-device (CCD) camera system, the performance of the TSC is expected to improve even further. Based on our theoretical model, the expected DQE(0)=0.12 for the TSC system with the proposed improvements, which exceeds the performance of current flat-panel EPIDs. The prototype TSC provides high quality imaging even at subMU exposures (typical imaging dose is 0.2 MU per image), which offers the potential for daily patient localization imaging without increasing the weekly dose to the patient. Currently, the TSC is capable of limited frame-rate fluoroscopy for intratreatment visualization of patient motion at approximately 3 frames/second, since the achievable frame rate is significantly reduced by the limitations of the camera-control processor. With optimized processor control, the TSC is expected to be capable of intratreatment imaging exceeding 10 frames/second to monitor patient motion.

  18. Preparation optimization and spectral properties of BCNO phosphors with high quantum efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Chunrong; Zhang, Xinghua, E-mail: xinghua146@126.com; Zhou, Liyu; Lu, Zunming; Lin, Jing; Xu, Xuewen; Li, Lanlan; Zhang, Xiao; Xue, Yanming; Meng, Fanbin; Zhao, Jianling; Tang, Chengchun, E-mail: tangcc@hebut.edu.cn

    2014-09-15

    BCNO phosphors with high quantum efficiency (QE) were synthesized using trimethyl borate, melamine and urotropine as raw materials. The effects of urotropine, starting materials ratio, sintering time and temperature on luminescence properties were systematically investigated and the preparation conditions were optimized. The BCNO phosphor has turbostratic boron nitride structure and its size in the range of several millimeters. The emission peak position was not influenced by the content of urotropine. However, the emission peak blue can be tuned from 475 nm to 535 nm with increasing B/N source ratios (R{sub B/N}=2–6), while the QE decreased from 65.2% to 15.8%. The emission peaks of BCNO phosphor with R{sub B/N}=4 were in the range of green light (495–540 nm) with high QE (20.8–51.4%) as sintering time increased (4–20 h). In addition, the emission peaks of BCNO phosphor with R{sub B/N}=4 blue-shifted from 525 nm to 460 nm and increased QE (16.1–56.7%) with increasing sintering temperature (650–750 °C). The formation mechanism of BCNO phosphors was investigated by means of ultraviolet visible absorption spectra and infrared spectra. The tunable emission spectra and high QE corresponded to the chemical composition, carbon concentration and crystallinity of BCNO phosphors. - Highlights: • We prepared BCNO phosphors with high quantum efficiency (65.2%). • The effects of raw materials, sintering condition on spectral properties were investigated. • The formation and luminescence mechanism of BCNO phosphors were investigated.

  19. Efficient vacuum-free-processed quantum dot light-emitting diodes with printable liquid metal cathodes.

    Science.gov (United States)

    Peng, Huiren; Jiang, Yibin; Chen, Shuming

    2016-10-20

    Colloidal quantum dot light-emitting diodes (QLEDs) are recognized as promising candidates for next generation displays. QLEDs can be fabricated by low-cost solution processing except for the metal electrodes, which, in general, are deposited by costly vacuum evaporation. To be fully compatible with the low-cost solution process, we herein demonstrate vacuum-free and solvent-free fabrication of electrodes using a printable liquid metal. With eutectic gallium-indium (EGaIn) based liquid metal cathodes, vacuum-free-processed QLEDs are demonstrated with superior external quantum efficiencies of 11.51%, 12.85% and 5.03% for red, green and blue devices, respectively, which are about 2-, 1.5- and 1.1-fold higher than those of the devices with thermally evaporated Al cathodes. The improved performance is attributable to the reduction of electron injection by the native oxide of EGaIn, which serves as an electron-blocking layer for the devices and thus improves the balance of carrier injection. Also, the T50 half-lifetime of the vacuum-free-processed QLEDs is about 2-fold longer than that of the devices with Al cathodes. Our results demonstrate that EGaIn-based solvent-free liquid metals are promising printable electrodes for realizing efficient, low-cost and vacuum-free-processed QLEDs. The elimination of vacuum and high-temperature processes significantly reduces the production cost and paves the way for industrial roll-to-roll manufacturing of large area displays.

  20. High-Efficiency Cooper-Pair Splitter in Quantum Anomalous Hall Insulator Proximity-Coupled with Superconductor.

    Science.gov (United States)

    Zhang, Ying-Tao; Deng, Xinzhou; Sun, Qing-Feng; Qiao, Zhenhua

    2015-01-01

    The quantum entanglement between two qubits is crucial for applications in the quantum communication. After the entanglement of photons was experimentally realized, much effort has been taken to exploit the entangled electrons in solid-state systems. Here, we propose a Cooper-pair splitter, which can generate spatially-separated but entangled electrons, in a quantum anomalous Hall insulator proximity-coupled with a superconductor. After coupling with a superconductor, the chiral edge states of the quantum anomalous Hall insulator can still survive, making the backscattering impossible. Thus, the local Andreev reflection becomes vanishing, while the crossed Andreev reflection becomes dominant in the scattering process. This indicates that our device can serve as an extremely high-efficiency Cooper-pair splitter. Furthermore, because of the chiral characteristic, our Cooper-pair splitter is robust against disorders and can work in a wide range of system parameters. Particularly, it can still function even if the system length exceeds the superconducting coherence length.

  1. Efficient charge carrier injection into sub-250 nm AlGaN multiple quantum well light emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Mehnke, Frank, E-mail: mehnke@physik.tu-berlin.de; Kuhn, Christian; Guttmann, Martin; Reich, Christoph; Kolbe, Tim; Rass, Jens; Wernicke, Tim [Technische Universität Berlin, Institut für Festkörperphysik, Hardenbergstr. 36, EW 6-1, 10623 Berlin (Germany); Kueller, Viola; Knauer, Arne; Lapeyrade, Mickael; Einfeldt, Sven; Weyers, Markus [Ferdinand-Braun-Institut, Leibniz-Institut für Höchstfrequenztechnik, Gustav-Kirchhoff-Str. 4, 12489 Berlin (Germany); Kneissl, Michael [Technische Universität Berlin, Institut für Festkörperphysik, Hardenbergstr. 36, EW 6-1, 10623 Berlin (Germany); Ferdinand-Braun-Institut, Leibniz-Institut für Höchstfrequenztechnik, Gustav-Kirchhoff-Str. 4, 12489 Berlin (Germany)

    2014-08-04

    The design and Mg-doping profile of AlN/Al{sub 0.7}Ga{sub 0.3}N electron blocking heterostructures (EBH) for AlGaN multiple quantum well (MQW) light emitting diodes (LEDs) emitting below 250 nm was investigated. By inserting an AlN electron blocking layer (EBL) into the EBH, we were able to increase the quantum well emission power and significantly reduce long wavelength parasitic luminescence. Furthermore, electron leakage was suppressed by optimizing the thickness of the AlN EBL while still maintaining sufficient hole injection. Ultraviolet (UV)-C LEDs with very low parasitic luminescence (7% of total emission power) and external quantum efficiencies of 0.19% at 246 nm have been realized. This concept was applied to AlGaN MQW LEDs emitting between 235 nm and 263 nm with external quantum efficiencies ranging from 0.002% to 0.93%. After processing, we were able to demonstrate an UV-C LED emitting at 234 nm with 14.5 μW integrated optical output power and an external quantum efficiency of 0.012% at 18.2 A/cm{sup 2}.

  2. Quantum

    CERN Document Server

    Al-Khalili, Jim

    2003-01-01

    In this lively look at quantum science, a physicist takes you on an entertaining and enlightening journey through the basics of subatomic physics. Along the way, he examines the paradox of quantum mechanics--beautifully mathematical in theory but confoundingly unpredictable in the real world. Marvel at the Dual Slit experiment as a tiny atom passes through two separate openings at the same time. Ponder the peculiar communication of quantum particles, which can remain in touch no matter how far apart. Join the genius jewel thief as he carries out a quantum measurement on a diamond without ever touching the object in question. Baffle yourself with the bizzareness of quantum tunneling, the equivalent of traveling partway up a hill, only to disappear then reappear traveling down the opposite side. With its clean, colorful layout and conversational tone, this text will hook you into the conundrum that is quantum mechanics.

  3. Computational study of power conversion and luminous efficiency performance for semiconductor quantum dot nanophosphors on light-emitting diodes.

    Science.gov (United States)

    Erdem, Talha; Nizamoglu, Sedat; Demir, Hilmi Volkan

    2012-01-30

    We present power conversion efficiency (PCE) and luminous efficiency (LE) performance levels of high photometric quality white LEDs integrated with quantum dots (QDs) achieving an averaged color rendering index of ≥90 (with R9 at least 70), a luminous efficacy of optical radiation of ≥380 lm/W(opt) a correlated color temperature of ≤4000 K, and a chromaticity difference dC quantum efficiency of 43%, 61%, and 80% in film, respectively, using state-of-the-art blue LED chips (81.3% PCE). Furthermore, our computational analyses suggest that QD-LEDs can be both photometrically and electrically more efficient than phosphor based LEDs when state-of-the-art QDs are used.

  4. Spectrometric performances of high quantum efficiency multi and single anode PMTs coupled to LaBr3(Ce) crystal

    Science.gov (United States)

    Cinti, Maria Nerina; Pani, Roberto; Pellegrini, Rosanna; Bennati, Paolo; Orlandi, Chiara; Fabbri, Andrea; Ridolfi, Stefano; Scafè, Raffaele

    2013-10-01

    High quantum efficiency semiconductor photodetectors have recently drawn the attention of the scientific community for their potential in the realization of a new class of scintillation imagers with very high energy and spatial resolution performance. However, this goal does not seem within easy reach, due to various technological issues such as, for example, the difficulty to scale the characteristics of a single detector to an imager with suitable dimensions. Lately a definite technical improvement in increasing quantum efficiency up to 42% for position sensitive photomultipliers was achieved. The aim of this work is thus to test this new technological progress and to study the possible implications in imaging applications. Four Hamamatsu PMTs were tested: two multi anode photomultipliers, one with a bialkali (27% quantum efficiency) and the other one with a super-bialkali photocathode (38% quantum efficiency), and two 1×1 in. PMTs, both equipped with an ultra bialkali photocathode (42% quantum efficiency). In particular one of the ultra bialkali PMT has also an increased efficiency of first dynode charge collection. The results were compared with the ones obtained with a reference PMT (Hamamatsu R6231), mainly used in spectroscopy. The PMTs were coupled to LaBr3(Ce), NaI(Tl) and LSO(Ce) continuous scintillation crystals. The tests were done using two independent electronic chains: one dedicated for spectroscopic application and a second one, using a multi wire 64 channel readout, for imaging applications. The super-bialkali MA-PMTs have shown high energy resolution, both with spectroscopic and imaging setup, highlighting the appropriateness of these devices for the development of imaging devices with high spectroscopic performance.

  5. Extending quantum efficiency roll-over threshold with compositionally graded InGaN/GaN LED

    KAUST Repository

    Mishra, Pawan

    2014-12-01

    We report a significant improvement in the electrical characteristic of compositionally graded InGaN/GaN multiple-quantum-well (MQWs) micro-LED. The efficiency droop in this device occurred at ∼20 times higher injection levels (∼275 A/cm2) compared to a conventional step-MQWs microLED (∼14 A/cm2).

  6. Spectroscopic investigations of dark Si nanocrystals in SiO2 and their role in external quantum efficiency quenching"

    NARCIS (Netherlands)

    Limpens, R.; Gregorkiewicz, T.

    2013-01-01

    The percentage of dark silicon nanocrystals, i.e., the nanocrystals that are not able to radiatively recombine after absorption of a photon, is investigated by combining measurements of external and internal quantum efficiencies. The study is conducted on samples prepared by co-sputtering and subseq

  7. ZnSe Light Emitting Diode Quantum Efficiency and Emission Characterization

    Directory of Open Access Journals (Sweden)

    Sahbudin U.K.

    2016-01-01

    Full Text Available ZnSe has demonstrated as a potential candidate in realizing advance LED in some appications for current and future works that utilize a cheaper preparation technique. Blue and white LEDs have been shown to spread across compound semiconductors. This II-VI compound semiconductor with a direct and wide band gap is used in the study which focused on a preparation and its characterization. The device is developed using a circular chip of ZnSe but only part of the active region is designed to allow shorter computation time. Analyses of the proposed LED are performed in an environment that allows optical transition and nonradiative recombination mechanisms. Voltage variation from 0 V to 1.5 V is maintained throughout the observation. The curent-voltage plot shows the p-n junction or diode behavior with central emissive layer. The two dimensions surface emission rate obtained indicates that voltage increment causes the emission concentration to become higher near the central pcontact. The LED efficiency is assessed in terms of internal quantum efficiency and emitting rate.

  8. Enhance Efficiency of Solar Cell Using Luminescence PbS Quantum Dots Concentrators.

    Science.gov (United States)

    Reda, S M

    2015-05-01

    Thin film and sheet PbS quantum dots (QDs) concentrators were synthesized by sol-gel method using three different PbS concentrations (0.14, 0.2, and 0.4 mol%). The structure and morphology of the prepared PbS QDs were characterized by X-ray diffraction (XRD), Scan electron microscopy (SEM), and Transmission electron microscopy (TEM). The photostability of the PbS QDs concentrators under outdoor exposure to sunlight for 8 weeks was studied. The results showed that the PbS QDs sheet with PbS concentration (0.14 mol%) has the highest luminescence intensity. The sheet PbS QDs concentrator was used to couple with PV solar cell and the corresponding photoelectric conversion efficiency was measured under sun light illumination. I-V characteristics of the photovoltaic devices, both open circuit voltage and short circuit current were improved as compared to the device without collector. This indicates that the proposed technique is very useful for improving the efficiency of solar cell.

  9. Efficient and robust quantum random number generation by photon number detection

    Science.gov (United States)

    Applegate, M. J.; Thomas, O.; Dynes, J. F.; Yuan, Z. L.; Ritchie, D. A.; Shields, A. J.

    2015-08-01

    We present an efficient and robust quantum random number generator based upon high-rate room temperature photon number detection. We employ an electric field-modulated silicon avalanche photodiode, a type of device particularly suited to high-rate photon number detection with excellent photon number resolution to detect, without an applied dead-time, up to 4 photons from the optical pulses emitted by a laser. By both measuring and modeling the response of the detector to the incident photons, we are able to determine the illumination conditions that achieve an optimal bit rate that we show is robust against variation in the photon flux. We extract random bits from the detected photon numbers with an efficiency of 99% corresponding to 1.97 bits per detected photon number yielding a bit rate of 143 Mbit/s, and verify that the extracted bits pass stringent statistical tests for randomness. Our scheme is highly scalable and has the potential of multi-Gbit/s bit rates.

  10. High Efficiency, Low Power-Consumption DFB Quantum Cascade Lasers Without Lateral Regrowth.

    Science.gov (United States)

    Jia, Zhi-Wei; Wang, Li-Jun; Zhang, Jin-Chuan; Liu, Feng-Qi; Zhou, Yu-Hong; Wang, Dong-Bo; Jia, Xue-Feng; Zhuo, Ning; Liu, Jun-Qi; Zhai, Shen-Qiang; Wang, Zhan-Guo

    2017-12-01

    Very low power-consumption distributed feedback (DFB) quantum cascade lasers (QCLs) at the wavelength around 4.9 μm were fabricated by conventional process without lateral regrowth of InP:Fe or using sidewall grating. Benefitted from the optimized materials and low waveguide loss, very low threshold current density of 0.5 kA/cm(2) was obtained for a device with cavity length of 2 mm. Combined with the partial-high-reflection coating, the 1-mm-long DFB QCL achieved low power-consumption continuous wave (CW) operation up to 105 °C. The CW threshold power-consumptions were 0.72 and 0.78 W at 15 and 25 °C, respectively. The maximum CW output power was over 110 mW at 15 °C and still more than 35 mW at 105 °C. At 15 °C, wall-plug efficiency of 5.5% and slope efficiency of 1.8 W/A were deduced, which were very high for low power-consumption DFB QCLs.

  11. A spatio-temporal detective quantum efficiency and its application to fluoroscopic systems

    Energy Technology Data Exchange (ETDEWEB)

    Friedman, S. N.; Cunningham, I. A. [Sackler School of Medicine, Faculty of Medicine, Tel Aviv University, Ramat Aviv 69978 (Israel); Imaging Research Laboratories, Robarts Research Institute and Lawson Health Research Institute, 100 Perth Drive, London, Ontario N6A 5K8 (Canada) and Department of Medical Biophysics, University of Western Ontario, 1151 Richmond Street, London, Ontario N6A 5B8 (Canada)

    2010-11-15

    Purpose: Fluoroscopic x-ray imaging systems are used extensively in spatio-temporal detection tasks and require a spatio-temporal description of system performance. No accepted metric exists that describes spatio-temporal fluoroscopic performance. The detective quantum efficiency (DQE) is a metric widely used in radiography to quantify system performance and as a surrogate measure of patient ''dose efficiency.'' It has been applied previously to fluoroscopic systems with the introduction of a temporal correction factor. However, the use of a temporally-corrected DQE does not provide system temporal information and it is only valid under specific conditions, many of which are not likely to be satisfied by suboptimal systems. The authors propose a spatio-temporal DQE that describes performance in both space and time and is applicable to all spatio-temporal quantum-based imaging systems. Methods: The authors define a spatio-temporal DQE (two spatial-frequency axes and one temporal-frequency axis) in terms of a small-signal spatio-temporal modulation transfer function (MTF) and spatio-temporal noise power spectrum (NPS). Measurements were made on an x-ray image intensifier-based bench-top system using continuous fluoroscopy with an RQA-5 beam at 3.9 {mu}R/frame and hardened 50 kVp beam (0.8 mm Cu filtration added) at 1.9 {mu}R/frame. Results: A zero-frequency DQE value of 0.64 was measured under both conditions. Nonideal performance was noted at both larger spatial and temporal frequencies; DQE values decreased by {approx}50% at the cutoff temporal frequency of 15 Hz. Conclusions: The spatio-temporal DQE enables measurements of decreased temporal system performance at larger temporal frequencies analogous to previous measurements of decreased (spatial) performance. This marks the first time that system performance and dose efficiency in both space and time have been measured on a fluoroscopic system using DQE and is the first step toward the

  12. A spatio-temporal detective quantum efficiency and its application to fluoroscopic systems.

    Science.gov (United States)

    Friedman, S N; Cunningham, I A

    2010-11-01

    Fluoroscopic x-ray imaging systems are used extensively in spatio-temporal detection tasks and require a spatio-temporal description of system performance. No accepted metric exists that describes spatio-temporal fluoroscopic performance. The detective quantum efficiency (DQE) is a metric widely used in radiography to quantify system performance and as a surrogate measure of patient "dose efficiency". It has been applied previously to fluoroscopic systems with the introduction of a temporal correction factor. However, the use of a temporally-corrected DQE does not provide system temporal information and it is only valid under specific conditions, many of which are not likely to be satisfied by suboptimal systems. The authors propose a spatio-temporal DQE that describes performance in both space and time and is applicable to all spatio-temporal quantum-based imaging systems. The authors define a spatio-temporal DQE (two spatial-frequency axes and one temporal-frequency axis) in terms of a small-signal spatio-temporal modulation transfer function (MTF) and spatio-temporal noise power spectrum (NPS). Measurements were made on an x-ray image intensifier-based bench-top system using continuous fluoroscopy with an RQA-5 beam at 3.9 microR/frame and hardened 50 kVp beam (0.8 mm Cu filtration added) at 1.9 microR/frame. A zero-frequency DQE value of 0.64 was measured under both conditions. Nonideal performance was noted at both larger spatial and temporal frequencies; DQE values decreased by approximately 50% at the cutoff temporal frequency of 15 Hz. The spatio-temporal DQE enables measurements of decreased temporal system performance at larger temporal frequencies analogous to previous measurements of decreased (spatial) performance. This marks the first time that system performance and dose efficiency in both space and time have been measured on a fluoroscopic system using DQE and is the first step toward the generalized use of DQE on clinical fluoroscopic systems.

  13. Improving the Efficiency of an Ideal Heat Engine: The Quantum Afterburner

    OpenAIRE

    Scully, Marlan O.

    2001-01-01

    By using a laser and maser in tandem, it is possible to obtain laser action in the hot exhaust gases involved in heat engine operation. Such a "quantum afterburner" involves the internal quantum states of working gas atoms or molecules as well as the techniques of cavity quantum electrodynamics and is therefore in the domain of quantum thermodynamics. As an example, it is shown that Otto cycle engine performance can be improved beyond that of the "ideal" Otto heat engine.

  14. Experimental realization of highly efficient broadband coupling of single quantum dots to a photonic crystal waveguide

    DEFF Research Database (Denmark)

    Lund-Hansen, Toke; Stobbe, Søren; Julsgaard, Brian;

    2008-01-01

    We present time-resolved spontaneous emission measurements of single quantum dots embedded in photonic crystal waveguides. Quantum dots that couple to a photonic crystal waveguide are found to decay up to 27 times faster than uncoupled quantum dots. From these measurements -factors of up to 0.89 ...

  15. Efficient controlled-phase gate for single-spin qubits in quantum dots

    NARCIS (Netherlands)

    Meunier, T.; Calado, V.E.; Vandersypen, L.M.K.

    2011-01-01

    Two-qubit interactions are at the heart of quantum information processing. For single-spin qubits in semiconductor quantum dots, the exchange gate has always been considered the natural two-qubit gate. The recent integration of a magnetic field or g-factor gradients in coupled quantum dot systems

  16. Efficient implementation of the continuous-time hybridization expansion quantum impurity solver

    Science.gov (United States)

    Hafermann, Hartmut; Werner, Philipp; Gull, Emanuel

    2013-04-01

    Strongly correlated quantum impurity problems appear in a wide variety of contexts ranging from nanoscience and surface physics to material science and the theory of strongly correlated lattice models, where they appear as auxiliary systems within dynamical mean-field theory. Accurate and unbiased solutions must usually be obtained numerically, and continuous-time quantum Monte Carlo algorithms, a family of algorithms based on the stochastic sampling of partition function expansions, perform well for such systems. With the present paper we provide an efficient and generic implementation of the hybridization expansion quantum impurity solver, based on the segment representation. We provide a complete implementation featuring most of the recently developed extensions and optimizations. Our implementation allows one to treat retarded interactions and provides generalized measurement routines based on improved estimators for the self-energy and for vertex functions. The solver is embedded in the ALPS-DMFT application package. Catalogue identifier: AEOL_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEOL_v1_0.html Program obtainable from: CPC Program Library, Queen’s University, Belfast, N. Ireland Licensing provisions: Use of the hybridization expansion impurity solvers requires citation of this paper. Use of any ALPS program requires citation of the ALPS [1] paper. No. of lines in distributed program, including test data, etc.: 650044 No. of bytes in distributed program, including test data, etc.: 20553265 Distribution format: tar.gz Programming language: C++/Python. Computer: Desktop PC, high-performance computers. Operating system: Unix, Linux, OSX, Windows. Has the code been vectorized or parallelized?: Yes, MPI parallelized. RAM: 1 GB Classification: 7.3. External routines: ALPS [1, 2, 3], BLAS [4, 5], LAPACK [6], HDF5 [7] Nature of problem: Quantum impurity models were originally introduced to describe a magnetic transition metal ion in a non

  17. Efficient fiber-coupled single-photon sources based on quantum dots

    DEFF Research Database (Denmark)

    Daveau, Raphaël Sura

    refrigeration with coupled quantum wells. Many photonic quantum information processing applications would benet from a highbrightness, ber-coupled source of triggered single photons. This thesis presents a study of such sources based on quantum dots coupled to unidirectional photonic-crystal waveguide devices......This thesis presents the study of solid-state quantum emitters in two dierent forms. The rst part of the thesis deals with quantum dot based single-photon sources with an emphasis on ecient photon extraction into an optical ber. The second part of the thesis covers a theoretical study of optical...... the characterization of single quantum dots. The second method, evanescent coupling from a tapered waveguide to a microber, demonstrates a chip-to-ber coupling eciency exceeding 80 % in passive re- ection measurements. The characterization of quantum dots from this device establishes a ber-coupled source eciency of 15...

  18. OP09O-OP404-9 Wide Field Camera 3 CCD Quantum Efficiency Hysteresis

    Science.gov (United States)

    Collins, Nick

    2009-01-01

    The HST/Wide Field Camera (WFC) 3 UV/visible channel CCD detectors have exhibited an unanticipated quantum efficiency hysteresis (QEH) behavior. At the nominal operating temperature of -83C, the QEH feature contrast was typically 0.1-0.2% or less. The behavior was replicated using flight spare detectors. A visible light flat-field (540nm) with a several times full-well signal level can pin the detectors at both optical (600nm) and near-UV (230nm) wavelengths, suppressing the QEH behavior. We are characterizing the timescale for the detectors to become unpinned and developing a protocol for flashing the WFC3 CCDs with the instrument's internal calibration system in flight. The HST/Wide Field Camera 3 UV/visible channel CCD detectors have exhibited an unanticipated quantum efficiency hysteresis (QEH) behavior. The first observed manifestation of QEH was the presence in a small percentage of flat-field images of a bowtie-shaped contrast that spanned the width of each chip. At the nominal operating temperature of -83C, the contrast observed for this feature was typically 0.1-0.2% or less, though at warmer temperatures contrasts up to 5% (at -50C) have been observed. The bowtie morphology was replicated using flight spare detectors in tests at the GSFC Detector Characterization Laboratory by power cycling the detector while cold. Continued investigation revealed that a clearly-related global QE suppression at the approximately 5% level can be produced by cooling the detector in the dark; subsequent flat-field exposures at a constant illumination show asymptotically increasing response. This QE "pinning" can be achieved with a single high signal flat-field or a series of lower signal flats; a visible light (500-580nm) flat-field with a signal level of several hundred thousand electrons per pixel is sufficient for QE pinning at both optical (600nm) and near-UV (230nm) wavelengths. We are characterizing the timescale for the detectors to become unpinned and developing a

  19. A comparison of digital radiography systems in terms of effective detective quantum efficiency.

    Science.gov (United States)

    Bertolini, Marco; Nitrosi, Andrea; Rivetti, Stefano; Lanconelli, Nico; Pattacini, Pierpaolo; Ginocchi, Vladimiro; Iori, Mauro

    2012-05-01

    The purpose of this study is to compare digital radiography systems using the metric effective detective quantum efficiency (eDQE), which better reflects digital radiography imaging system performance under clinical operating conditions, in comparison with conventional metrics such as modulation transfer function (MTF), normalized noise power spectra (NNPS), and detective quantum efficiency (DQE). The eDQE was computed by the calculation of the MTF, the NNPS, the phantom attenuation and scatter, and estimation of x-ray flux. The physical characterization of the systems was obtained with the standard beam conditions RQA5 and RQA9, using the PA Chest phantom proposed by AAPM Report # 31 simulating the attenuation and scatter characteristics of the adult human thorax. The MTF (eMTF) was measured by using an edge test placed at the frontal surface of the phantom, the NNPS (eNNPS) was calculated from images of the phantom acquired at three different exposure levels covering the operating range of the system (E(0), which is the exposure at which a system is normally operated, 1/3 E(0), and 3 E0), and scatter measurements were assessed by using a beam-stop technique. The integral of DQE (IDQE) and eDQE (IeDQE) was calculated over the whole spatial frequency range. The eMTF results demonstrate degradation due to magnification and the presence of scattered radiation. The eNNPS was influenced by the grid presence, and in some systems, it contained structured noise. At typical clinical exposure levels, the magnitude of eDQE(0) with respect to DQE(0) at RQA9 beam conditions was 13%, 17%, 16%, 36%, and 24%, respectively, for Carestream DRX-1, Carestream DRX-1C, Carestream Direct View CR975, Philips Digital Diagnost VM, and GE Revolution XR/d. These results were confirmed by the ratio of IeDQE and IDQE in the same conditions. The authors confirm the robustness and reproducibility of the eDQE method. As expected, the DR systems performed better than the CR systems due to their

  20. A comparison of digital radiography systems in terms of effective detective quantum efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Bertolini, Marco; Nitrosi, Andrea; Rivetti, Stefano; Lanconelli, Nico; Pattacini, Pierpaolo; Ginocchi, Vladimiro; Iori, Mauro [Department of Advanced Technology, Medical Physics Unit, Azienda Ospedaliera ASMN, Istituto di Ricovero e Cura a Carattere Scientifico, Reggio Emilia 42123 (Italy); Fisica Medica, Ospedale di Sassuolo S.p.A., Modena 41049 (Italy); Alma Mater Studiorum, Physics Department, University of Bologna, Bologna 40127 (Italy); Department of Diagnostic Imaging, Radiology Unit, Azienda Ospedaliera ASMN, Istituto di Ricovero e Cura a Carattere Scientifico, Reggio Emilia 42123 (Italy); Department of Diagnostic Imaging, Radiology Unit, Azienda USL, Reggio Emilia 42122 (Italy); Department of Advanced Technology, Medical Physics Unit, Azienda Ospedaliera ASMN, Istituto di Ricovero e Cura a Carattere Scientifico, Reggio Emilia 42123 (Italy)

    2012-05-15

    Purpose: The purpose of this study is to compare digital radiography systems using the metric effective detective quantum efficiency (eDQE), which better reflects digital radiography imaging system performance under clinical operating conditions, in comparison with conventional metrics such as modulation transfer function (MTF), normalized noise power spectra (NNPS), and detective quantum efficiency (DQE). Methods: The eDQE was computed by the calculation of the MTF, the NNPS, the phantom attenuation and scatter, and estimation of x-ray flux. The physical characterization of the systems was obtained with the standard beam conditions RQA5 and RQA9, using the PA Chest phantom proposed by AAPM Report no. 31 simulating the attenuation and scatter characteristics of the adult human thorax. The MTF (eMTF) was measured by using an edge test placed at the frontal surface of the phantom, the NNPS (eNNPS) was calculated from images of the phantom acquired at three different exposure levels covering the operating range of the system (E{sub 0}, which is the exposure at which a system is normally operated, 1/3 E{sub 0}, and 3 E0), and scatter measurements were assessed by using a beam-stop technique. The integral of DQE (IDQE) and eDQE (IeDQE) was calculated over the whole spatial frequency range. Results: The eMTF results demonstrate degradation due to magnification and the presence of scattered radiation. The eNNPS was influenced by the grid presence, and in some systems, it contained structured noise. At typical clinical exposure levels, the magnitude of eDQE(0) with respect to DQE(0) at RQA9 beam conditions was 13%, 17%, 16%, 36%, and 24%, respectively, for Carestream DRX-1, Carestream DRX-1C, Carestream Direct View CR975, Philips Digital Diagnost VM, and GE Revolution XR/d. These results were confirmed by the ratio of IeDQE and IDQE in the same conditions. Conclusions: The authors confirm the robustness and reproducibility of the eDQE method. As expected, the DR systems

  1. The photonic nanowire: an emerging platform for highly efficient single-photon sources for quantum information applications

    DEFF Research Database (Denmark)

    Gregersen, Niels; Munsch, Mathieu; Malik, Nitin S.

    2013-01-01

    Efficient coupling between a localized quantum emitter and a well defined optical channel represents a powerful route to realize single-photon sources and spin-photon interfaces. The tailored fiber-like photonic nanowire embedding a single quantum dot has recently demonstrated an appealing potent....... A first implementation of this strategy has lead to an ultra-bright single-photon source with a first-lens external efficiency of 0.75 ± 0.1 and a predicted coupling to a Gaussian beam of 0.61 ± 0.08.......Efficient coupling between a localized quantum emitter and a well defined optical channel represents a powerful route to realize single-photon sources and spin-photon interfaces. The tailored fiber-like photonic nanowire embedding a single quantum dot has recently demonstrated an appealing...... potential. However, the device requires a delicate, sharp needle-like taper with performance sensitive to minute geometrical details. To overcome this limitation we demonstrate the photonic trumpet, exploiting an opposite tapering strategy. The trumpet features a strongly Gaussian far-field emission...

  2. NaLaF4:Pr3+,Yb3+, an efficient blue to near infra-red quantum cutter

    Directory of Open Access Journals (Sweden)

    A. Guille

    2013-12-01

    Full Text Available In order to reduce the thermalization losses in solar cells, down-conversion of blue photons into near infra-red photons is a promising solution. In the present paper, we analyse the energy transfer processes between Pr3+ and Yb3+ in NaLaF4 and we show that an efficient quantum-cutting process occurs. Nevertheless, we also show that a back transfer from Yb3+ toward the 1G4 level of Pr3+ ion leading to emission beyond 1 μm reduces the potentiality of this material as a quantum cutter for Si solar cells.

  3. Solid Confinement of Quantum Dots in ZIF-8 for Efficient and Stable Color-Conversion White LEDs.

    Science.gov (United States)

    Ying, Wen; Mao, Yiyin; Wang, Xiaobing; Guo, Yi; He, Haiping; Ye, Zhizhen; Lee, Shuit-Tong; Peng, Xinsheng

    2017-03-13

    The powder form and low photoluminescence quantum yield (PLQY) of fluorescent metal-organic frameworks (MOFs) present a serious obstacle to fabricating high-efficiency film-like lighting devices. Here, we present a facile way to produce thin films of CdSex S1-x /ZnS quantum dots (QDs)@ZIF-8 with high PLQY by encapsulating red, green, and blue CdSex S1-x /ZnS QDs in ZIF-8 through a one-pot solid-confinement conversion process. The QDs@ZIF-8 thin film emits warm white light with good color quality and presents good thermal stability and long-term durability.

  4. Study of efficiency droop and carrier localisation in an InGaN/GaN quantum well structure

    Energy Technology Data Exchange (ETDEWEB)

    Hammersley, S.; Badcock, T.J.; Watson-Parris, D.; Godfrey, M.J.; Dawson, P. [School of Physics and Astronomy, Photon Science Institute, Alan Turing Building, University of Manchester, M13 9PL (United Kingdom); Kappers, M.J.; Humphreys, C.J. [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB2 3QZ (United Kingdom)

    2011-07-15

    It is well known that the efficiency of InGaN LEDs reduces significantly at high injection currents. To date there have been several explanations for this phenomena, although no consensus has emerged as to the controlling mechanism(s). In this paper we report on the temperature dependence of the photoluminescence emission from an InGaN/GaN quantum well structure as a function of excitation level. We have observed a reduction in the S-shape temperature dependence of the peak of the emission spectrum at an excitation level that coincides with the onset of the efficiency droop. We suggest that both the efficiency droop and the reduction in the observed S-shape temperature dependence are caused by saturation of the available localised states within the quantum well. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  5. Nanowire-quantum-dot solar cells and the influence of nanowire length on the charge collection efficiency

    Science.gov (United States)

    Leschkies, Kurtis S.; Jacobs, Alan G.; Norris, David J.; Aydil, Eray S.

    2009-11-01

    External quantum efficiency in solar cells based on junctions between PbSe quantum dots (QDs) and thin ZnO films is increased by replacing the ZnO films with a vertically oriented array of single-crystalline ZnO nanowires, and infiltrating this array with colloidal QDs. When illuminated with 100 mW/cm2 of simulated solar light, QD-nanowire solar cells exhibited power conversion efficiencies approaching 2%, approximately three times higher than that achieved with thin-film ZnO devices constructed with the same amount of QDs. Significant photocurrent and power conversion improvement with increasing nanowire length is consistent with higher exciton and charge collection efficiencies.

  6. Estimation of the quantum efficiency of the photodissociation of HbO2 and HbCO

    Science.gov (United States)

    Gisbrecht, A. I.; Mamilov, S. A.; Esman, S. S.; Asimov, M. M.

    2016-01-01

    The paper presents our results on the study of the efficiency of inter-fractional changes in hemoglobin molecules depending on the laser radiation parameters. The evaluation of the quantum efficiency of light interaction in vivo with oxyhemoglobin (HbO2) and carboxyhemoglobin (HbCO) in the blood at wavelengths for 525 and 605 nm is presented. The photodissociation yield of 11% for HbO2 and 79% for HbCO are measured at the wavelength of 525 nm and 10 % for HbO2 and 76 % for HbCO at a wavelength of 605 nm. Thus, the quantum yield of photodissociation of the HbCO is considerably higher, which ensures high efficiency of photodecomposition of the HbCO in the blood. The obtained results can be used in the clinical phototherapy practice for effective treatment of CO poisoning.

  7. Quantum Networks for Generating Arbitrary Quantum States

    OpenAIRE

    Kaye, Phillip; Mosca, Michele

    2004-01-01

    Quantum protocols often require the generation of specific quantum states. We describe a quantum algorithm for generating any prescribed quantum state. For an important subclass of states, including pure symmetric states, this algorithm is efficient.

  8. Spectra and quantum efficiency of light-emitting diodes based on GaN heterostructures with quantum wells and their dependence on current and voltage

    CERN Document Server

    Kudryashov, V E; Turkin, A N; Yunovich, A E; Kovalev, A N; Manyakhin, F I

    2001-01-01

    Spectra and quantum efficiency of light-emitted diodes based on heterostructures InGaN/AlGaN/GaN with multiple quantum wells have been studied at currents J = 10 sup - sup 6 -10 sup - sup 1 A. Minor differences in quantum efficiency (of +- 10% at J approx = 10 mA) are caused by sufficiently different distribution of effective charges in the space charge region as well as by different role of the tunnel component of current at low voltages. The main peak in spectra near of 2.35-2.36 eV at small current (0.05-0.5 mA) does not depend on the voltage and is explained by radiative transitions in localized states. At J > 1 mA the spectral band 2.36-2.52 eV shifts with gamma current. The band form is described in the 4-parameter model of tail population of two-dimensional energy-level density

  9. High quantum efficiency mid-wavelength interband cascade infrared photodetectors with one and two stages

    Science.gov (United States)

    Zhou, Yi; Chen, Jianxin; Xu, Zhicheng; He, Li

    2016-08-01

    In this paper, we report on mid-wavelength infrared interband cascade photodetectors grown on InAs substrates. We studied the transport properties of the photon-generated carriers in the interband cascade structures by comparing two different detectors, a single stage detector and a two-stage cascade detector. The two-stage device showed quantum efficiency around 19.8% at room temperature, and clear optical response was measured even at a temperature of 323 K. The two detectors showed similar Johnson-noise limited detectivity. The peak detectivity of the one- and two-stage devices was measured to be 2.15 × 1014 cm·Hz1/02/W and 2.19 × 1014 cm·Hz1/02/W at 80 K, 1.21 × 109 cm·Hz1/02/W and 1.23 × 109 cm·Hz1/02/W at 300 K, respectively. The 300 K background limited infrared performance (BLIP) operation temperature is estimated to be over 140 K.

  10. High quantum efficiency Type-II superlattice N-structure photodetectors with thin intrinsic layers

    Science.gov (United States)

    Ergun, Yuksel; Hostut, Mustafa; Tansel, Tunay; Muti, Abdullah; Kilic, Abidin; Turan, Rasit; Aydinli, Atilla

    2013-06-01

    We report on the development of InAs/AlSb/GaSb based N-structure superlattice pin photodiode. In this new design, AlSb layer in between InAs and GaSb layers acts as an electron barrier that pushes electron and hole wave functions towards the GaSb/InAs interface to perform strong overlap under reverse bias. Experimental results show that, with only 20 periods of intrinsic layers, dark current density and dynamic resistance at -50 mV bias are measured as 6x10-3 A/cm2 and 148 Ωcm2 at 77K, respectively. Under zero bias, high spectral response of 1.2A/W is obtained at 5 μm with 50% cut-off wavelengths (λc) of 6 μm. With this new design, devices with only 146 nm thick i-regions exhibit a quantum efficiency of 42% at 3 μm with front-side illimunation and no anti-reflection coatings.

  11. Performance of SEM scintillation detector evaluated by modulation transfer function and detective quantum efficiency function.

    Science.gov (United States)

    Bok, Jan; Schauer, Petr

    2014-01-01

    In the paper, the SEM detector is evaluated by the modulation transfer function (MTF) which expresses the detector's influence on the SEM image contrast. This is a novel approach, since the MTF was used previously to describe only the area imaging detectors, or whole imaging systems. The measurement technique and calculation of the MTF for the SEM detector are presented. In addition, the measurement and calculation of the detective quantum efficiency (DQE) as a function of the spatial frequency for the SEM detector are described. In this technique, the time modulated e-beam is used in order to create well-defined input signal for the detector. The MTF and DQE measurements are demonstrated on the Everhart-Thornley scintillation detector. This detector was alternated using the YAG:Ce, YAP:Ce, and CRY18 single-crystal scintillators. The presented MTF and DQE characteristics show good imaging properties of the detectors with the YAP:Ce or CRY18 scintillator, especially for a specific type of the e-beam scan. The results demonstrate the great benefit of the description of SEM detectors using the MTF and DQE. In addition, point-by-point and continual-sweep e-beam scans in SEM were discussed and their influence on the image quality was revealed using the MTF.

  12. Sandwiched confinement of quantum dots in graphene matrix for efficient electron transfer and photocurrent production.

    Science.gov (United States)

    Zhu, Nan; Zheng, Kaibo; Karki, Khadga J; Abdellah, Mohamed; Zhu, Qiushi; Carlson, Stefan; Haase, Dörthe; Žídek, Karel; Ulstrup, Jens; Canton, Sophie E; Pullerits, Tõnu; Chi, Qijin

    2015-05-21

    Quantum dots (QDs) and graphene are both promising materials for the development of new-generation optoelectronic devices. Towards this end, synergic assembly of these two building blocks is a key step but remains a challenge. Here, we show a one-step strategy for organizing QDs in a graphene matrix via interfacial self-assembly, leading to the formation of sandwiched hybrid QD-graphene nanofilms. We have explored structural features, electron transfer kinetics and photocurrent generation capacity of such hybrid nanofilms using a wide variety of advanced techniques. Graphene nanosheets interlink QDs and significantly improve electronic coupling, resulting in fast electron transfer from photoexcited QDs to graphene with a rate constant of 1.3 × 10(9) s(-1). Efficient electron transfer dramatically enhances photocurrent generation in a liquid-junction QD-sensitized solar cell where the hybrid nanofilm acts as a photoanode. We thereby demonstrate a cost-effective method to construct large-area QD-graphene hybrid nanofilms with straightforward scale-up potential for optoelectronic applications.

  13. Observation of Significant Quantum Efficiency Enhancement from a Polarized Photocathode with Distributed Bragg Reflector

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Shukui [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Poelker, Matthew [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Stutzman, Marcy L. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Chen, Yiqiao [SVT Associates, Inc., Eden Prairie, MN (United States); Moy, Aaron [SVT Associates, Inc., Eden Prairie, MN (United States)

    2015-09-01

    Polarized photocathodes with higher Quantum efficiency (QE) would help to reduce the technological challenge associated with producing polarized beams at milliampere levels, because less laser light would be required, which simplifies photocathode cooling requirements. And for a given amount of available laser power, higher QE would extend the photogun operating lifetime. The distributed Bragg reflector (DBR) concept was proposed to enhance the QE of strained-superlattice photocathodes by increasing the absorption of the incident photons using a Fabry-Perot cavity formed between the front surface of the photocathode and the substrate that includes a DBR, without compromising electron polarization. Here we present recent results showing QE enhancement of a GaAs/GaAsP strained-superlattice photocathode made with a DBR structure. Typically, a GaAs/GaAsP strained-superlattice photocathode without DBR provides a QE of 1%, at a laser wavelength corresponding to peak polarization. In comparison, the GaAs/GaAsP strained-superlattice photocathodes with DBR exhibited an enhancement of over 2 when the incident laser wavelength was tuned to meet the resonant condition for the Fabry-Perot resonator.

  14. Effects of exciton localization on internal quantum efficiency of InGaN nanowires

    Science.gov (United States)

    Murotani, Hideaki; Yamada, Yoichi; Tabata, Takuya; Honda, Yoshio; Yamaguchi, Masahito; Amano, Hiroshi

    2013-10-01

    The optical properties of InGaN nanowires with different emission wavelengths of 485, 515, 555, and 580 nm have been studied by means of photoluminescence (PL) and time-resolved PL (TRPL) spectroscopy. The PL peak energy of the nanowires exhibited an anomalous shift to higher energy and then to lower energy with increasing temperature. Analysis of the temperature-dependent variations in the PL peak energy let us evaluate the localization energies of excitons, which increased with increasing indium composition. TRPL measurements also revealed that the PL decay time of the nanowires increased and then became constant with decreasing emission energy, which was typical of localized excitons and enabled us to evaluate the characteristic energies of localized states. The characteristic energy increased with increasing indium composition, indicating that the density of localized states broadened with increasing indium composition. In addition, a correlation was clearly observed between the internal quantum efficiency (IQE) and localization energy of the nanowire: the IQE increased with increasing localization energy. The increase in the IQE was attributed to the increase in the degree of exciton localization as the indium composition of the nanowire increased. Moreover, it was found that with increasing excitation power density, a reduction in the IQE occurred simultaneously with a PL blue shift. This indicated that the reduction in the IQE was associated with saturation of localized states.

  15. Methods for Efficiently and Accurately Computing Quantum Mechanical Free Energies for Enzyme Catalysis.

    Science.gov (United States)

    Kearns, F L; Hudson, P S; Boresch, S; Woodcock, H L

    2016-01-01

    Enzyme activity is inherently linked to free energies of transition states, ligand binding, protonation/deprotonation, etc.; these free energies, and thus enzyme function, can be affected by residue mutations, allosterically induced conformational changes, and much more. Therefore, being able to predict free energies associated with enzymatic processes is critical to understanding and predicting their function. Free energy simulation (FES) has historically been a computational challenge as it requires both the accurate description of inter- and intramolecular interactions and adequate sampling of all relevant conformational degrees of freedom. The hybrid quantum mechanical molecular mechanical (QM/MM) framework is the current tool of choice when accurate computations of macromolecular systems are essential. Unfortunately, robust and efficient approaches that employ the high levels of computational theory needed to accurately describe many reactive processes (ie, ab initio, DFT), while also including explicit solvation effects and accounting for extensive conformational sampling are essentially nonexistent. In this chapter, we will give a brief overview of two recently developed methods that mitigate several major challenges associated with QM/MM FES: the QM non-Boltzmann Bennett's acceptance ratio method and the QM nonequilibrium work method. We will also describe usage of these methods to calculate free energies associated with (1) relative properties and (2) along reaction paths, using simple test cases with relevance to enzymes examples. © 2016 Elsevier Inc. All rights reserved.

  16. CHARACTERISING THE EOS SLOT-SCANNING SYSTEM WITH THE EFFECTIVE DETECTIVE QUANTUM EFFICIENCY.

    Science.gov (United States)

    Clavel, A H; Monnin, P; Létang, J M; Verdun, F R; Darbon, A

    2016-06-01

    As opposed to the standard detective quantum efficiency (DQE), effective DQE (eDQE) is a figure of merit that allows comparing the performances of imaging systems in the presence of scatter rejection devices. The geometry of the EOS™ slot-scanning system is such that the detector is self-collimated and rejects scattered radiation. In this study, the EOS system was characterised using the eDQE in imaging conditions similar to those used in clinical practice: with phantoms of different widths placed in the X-ray beam, for various incident air kerma and tube voltages corresponding to the phantom thickness. Scatter fractions in EOS images were extremely low, around 2 % for all configurations. Maximum eDQE values spanned 9-14.8 % for a large range of air kerma at the detector plane from 0.01 to 1.34 µGy. These figures were obtained with non-optimised EOS setting but still over-performed most of the maximum eDQEs recently assessed for various computed radiology and digital radiology systems with antiscatter grids.

  17. Efficient Quantum Key Distribution Scheme And Proof of Its Unconditional Security

    CERN Document Server

    Lo, H K; Ardehali, M; Lo, Hoi-Kwong

    2000-01-01

    We devise a simple modification that essentially doubles the efficiency of the BB84 quantum key distribution scheme proposed by Bennett and Brassard. We also prove the security of our modified scheme against the most general eavesdropping attack that is allowed by the laws of physics. The first major ingredient of our scheme is the assignment of significantly different probabilities to the different polarization bases during both transmission and reception, thus reducing the fraction of discarded data. A second major ingredient of our scheme is a refined analysis of accepted data: We separate the accepted data into various subsets according to the basis employed and estimate an error rate for each subset {\\em separately}. We then show that such a refined data analysis guarantees the security of our scheme against the most general eavesdropping strategy, thus generalizing Shor and Preskill's proof of security of BB84 to our new scheme. Up till now, most proposed proofs of security of single-particle type quant...

  18. Quantum efficiency investigations of type-II InAs/GaSb midwave infrared superlattice photodetectors

    Energy Technology Data Exchange (ETDEWEB)

    Giard, E., E-mail: edouard.giard@onera.fr; Ribet-Mohamed, I.; Jaeck, J.; Viale, T.; Haïdar, R. [ONERA, DOTA, Chemin de la Hunière, 91761 Palaiseau Cedex (France); Taalat, R.; Delmas, M.; Rodriguez, J.-B.; Christol, P. [Institut d' Electronique du Sud, UMR-CNRS 5214, Université Montpellier 2, Place Eugène Bataillon, 34095 Montpellier Cedex 5 (France); Steveler, E.; Bardou, N. [Laboratoire de Photonique et de Nanostructures (LPN-CNRS), Route de Nozay, 91460 Marcoussis (France); Boulard, F. [CEA, LETI, MINATEC Campus, 17 Avenue des martyrs, 38054 Grenoble (France)

    2014-07-28

    We present in this paper a comparison between different type-II InAs/GaSb superlattice (T2SL) photodiodes and focal plane array (FPA) in the mid-wavelength infrared domain to understand which phenomenon drives the performances of the T2SL structure in terms of quantum efficiency (QE). Our measurements on test photodiodes suggest low minority carrier diffusion length in the “InAs-rich” design, which penalizes carriers' collection in this structure for low bias voltage and front side illumination. This analysis is completed by a comparison of the experimental data with a fully analytic model, which allows to infer a hole diffusion length shorter than 100 nm. In addition, measurements on a FPA with backside illumination are finally presented. Results show an average QE in the 3–4.7 μm window equal to 42% for U{sub bias} = −0.1 V, 77 K operating temperature and no anti-reflection coating. These measurements, completed by modulation transfer function and noise measurements, reveal that the InAs-rich design, despite a low hole diffusion length, is promising for high performance infrared imaging applications.

  19. Nitride based quantum well light-emitting devices having improved current injection efficiency

    Science.gov (United States)

    Tansu, Nelson; Zhao, Hongping; Liu, Guangyu; Arif, Ronald

    2014-12-09

    A III-nitride based device provides improved current injection efficiency by reducing thermionic carrier escape at high current density. The device includes a quantum well active layer and a pair of multi-layer barrier layers arranged symmetrically about the active layer. Each multi-layer barrier layer includes an inner layer abutting the active layer; and an outer layer abutting the inner layer. The inner barrier layer has a bandgap greater than that of the outer barrier layer. Both the inner and the outer barrier layer have bandgaps greater than that of the active layer. InGaN may be employed in the active layer, AlInN, AlInGaN or AlGaN may be employed in the inner barrier layer, and GaN may be employed in the outer barrier layer. Preferably, the inner layer is thin relative to the other layers. In one embodiment the inner barrier and active layers are 15 .ANG. and 24 .ANG. thick, respectively.

  20. Quantum propagation of electronic excitations in macromolecules: A computationally efficient multiscale approach

    Science.gov (United States)

    Schneider, E.; a Beccara, S.; Mascherpa, F.; Faccioli, P.

    2016-07-01

    We introduce a theoretical approach to study the quantum-dissipative dynamics of electronic excitations in macromolecules, which enables to perform calculations in large systems and cover long-time intervals. All the parameters of the underlying microscopic Hamiltonian are obtained from ab initio electronic structure calculations, ensuring chemical detail. In the short-time regime, the theory is solvable using a diagrammatic perturbation theory, enabling analytic insight. To compute the time evolution of the density matrix at intermediate times, typically ≲ps , we develop a Monte Carlo algorithm free from any sign or phase problem, hence computationally efficient. Finally, the dynamics in the long-time and large-distance limit can be studied combining the microscopic calculations with renormalization group techniques to define a rigorous low-resolution effective theory. We benchmark our Monte Carlo algorithm against the results obtained in perturbation theory and using a semiclassical nonperturbative scheme. Then, we apply it to compute the intrachain charge mobility in a realistic conjugated polymer.

  1. Sandwiched confinement of quantum dots in graphene matrix for efficient electron transfer and photocurrent production

    Science.gov (United States)

    Zhu, Nan; Zheng, Kaibo; Karki, Khadga J.; Abdellah, Mohamed; Zhu, Qiushi; Carlson, Stefan; Haase, Dörthe; Žídek, Karel; Ulstrup, Jens; Canton, Sophie E.; Pullerits, Tõnu; Chi, Qijin

    2015-05-01

    Quantum dots (QDs) and graphene are both promising materials for the development of new-generation optoelectronic devices. Towards this end, synergic assembly of these two building blocks is a key step but remains a challenge. Here, we show a one-step strategy for organizing QDs in a graphene matrix via interfacial self-assembly, leading to the formation of sandwiched hybrid QD-graphene nanofilms. We have explored structural features, electron transfer kinetics and photocurrent generation capacity of such hybrid nanofilms using a wide variety of advanced techniques. Graphene nanosheets interlink QDs and significantly improve electronic coupling, resulting in fast electron transfer from photoexcited QDs to graphene with a rate constant of 1.3 × 109 s-1. Efficient electron transfer dramatically enhances photocurrent generation in a liquid-junction QD-sensitized solar cell where the hybrid nanofilm acts as a photoanode. We thereby demonstrate a cost-effective method to construct large-area QD-graphene hybrid nanofilms with straightforward scale-up potential for optoelectronic applications.

  2. Highly efficient photocatalytic activity of CuO quantum dot decorated rGO nanocomposites

    Science.gov (United States)

    Dutta, Shibsankar; Das, Kajari; Chakrabarti, Kaushik; Jana, D.; De, S. K.; De, Sukanta

    2016-08-01

    CuO quantum dots (QD) of size 4.5 nm decorated on a rGO sheet to form nanocomposites with different weight percentages via a simple soft chemical route was reported here. Tuning of CuO QD absorption towards the visible region from the UV region in the presence of rGO was also observed. The luminescence of rGO was found to be quenched in rGO-CuO nanocomposites due to charge transfer from the lowest unoccupied molecular orbital of the rGO layer to the conduction band of CuO. Systematic and concise studies of photocatalytic performance towards degradation of methylene blue (MB) dye by CuO QD along with rGO-CuO nanocomposites were presented in this work. A nanocomposite with an equal weight percentage of rGO and CuO degrades almost 99% of MB under irradiation of visible light for 50 min, showing maximum degradation efficiency.

  3. The use of detective quantum efficiency (DQE) in evaluating the performance of gamma camera systems

    Energy Technology Data Exchange (ETDEWEB)

    Starck, Sven-Ake [Department of Hospital Physics, County Hospital Ryhov, Joenkoeping (Sweden); Department of Radiation Physics, Goeteborg University, Goeteborg (Sweden); Baath, Magnus [Department of Medical Physics and Biomedical Engineering, Sahlgrenska University Hospital, Goeteborg (Sweden); Department of Radiation Physics, Goeteborg University, Goeteborg (Sweden); Carlsson, Sten [Department of Radiology, Uddevalla Hospital, Uddevalla (Sweden); Department of Radiation Physics, Goeteborg University, Goeteborg (Sweden)

    2005-04-07

    The imaging properties of an imaging system can be described by its detective quantum efficiency (DQE). Using the modulation transfer function calculated from measured line spread functions and the normalized noise power spectrum calculated from uniformity images, DQE was calculated with the number of photons emitted from a plane source as a measure for the incoming SNR{sup 2}. Measurements were made with {sup 99m}Tc, using three different pulse height windows at 2 cm and 12 cm depths in water with high resolution and all purpose collimators and with two different crystal thicknesses. The results indicated that at greater depths a 15% window is the best choice. The choice of collimator depends on the details in the organ being investigated. There is a break point at 0.5 cycles cm{sup -1} and 1.2 cycles cm{sup -1} at 12 cm and 2 cm depths, respectively. A difference was found in DQE between the two crystal thicknesses, with a slightly better result for the thick crystal for measurements at 12 cm depth. At 2 cm depth, the thinner crystal was slightly better for frequencies over 0.5 cm{sup -1}. The determination of DQE could be a method to optimize the parameters for different nuclear medicine investigations. The DQE could also be used in comparing different gamma camera systems with different collimators to obtain a figure of merit.

  4. Comparison of gamma (Anger) camera systems in terms of detective quantum efficiency using Monte Carlo simulation.

    Science.gov (United States)

    Eriksson, Ida; Starck, Sven-Åke; Båth, Magnus

    2014-04-01

    The aim of the present study was to perform an extensive evaluation of available gamma camera systems in terms of their detective quantum efficiency (DQE) and determine their dependency on relevant parameters such as collimator type, imaging depth, and energy window using the Monte Carlo technique. The modulation transfer function was determined from a simulated (99m)Tc point source and was combined with the system sensitivity and photon yield to obtain the DQE of the system. The simulations were performed for different imaging depths in a water phantom for 13 gamma camera systems from four manufacturers. Except at very low spatial frequencies, the highest DQE values were found with a lower energy window threshold of around 130 keV for all systems. The height and shape of the DQE curves were affected by the collimator design and the intrinsic properties of the gamma camera systems. High-sensitivity collimators gave the highest DQE at low spatial frequencies, whereas the high-resolution and ultrahigh-resolution collimators showed higher DQE values at higher frequencies. The intrinsic resolution of the system mainly affected the DQE curve at superficial depths. The results indicate that the manufacturers have succeeded differently in their attempts to design a system constituting an optimal compromise between sensitivity and spatial resolution.

  5. Technical Note: Detective quantum efficiency simulation of a-Se imaging detectors using ARTEMIS.

    Science.gov (United States)

    Fang, Yuan; Ito, Takaaki; Nariyuki, Fumito; Kuwabara, Takao; Badano, Aldo; Karim, Karim S

    2017-08-01

    This work studies the detective quantum efficiency (DQE) of a-Se-based solid state x-ray detectors for medical imaging applications using ARTEMIS, a Monte Carlo simulation tool for modeling x-ray photon, electron and charged carrier transport in semiconductors with the presence of applied electric field. ARTEMIS is used to model the signal formation process in a-Se. The simulation model includes x-ray photon and high-energy electron interactions, and detailed electron-hole pair transport with applied detector bias taking into account drift, diffusion, Coulomb interactions, recombination and trapping. For experimental validation, the DQE performance of prototype a-Se detectors is measured following IEC Testing Standard 62220-1-3. Comparison of simulated and experimental DQE results show reasonable agreement for RQA beam qualities. Experimental validation demonstrated within 5% percentage difference between simulation and experimental DQE results for spatial frequency above 0.25 cycles/mm using uniform applied electric field for RQA beam qualities (RQA5, RQA7 and RQA9). Results include two different prototype detectors with thicknesses of 240 μm and 1 mm. ARTEMIS can be used to model the DQE of a-Se detectors as a function of x-ray energy, detector thickness, and spatial frequency. The ARTEMIS model can be used to improve understanding of the physics of x-ray interactions in a-Se and in optimization studies for the development of novel medical imaging applications. © 2017 American Association of Physicists in Medicine.

  6. The effects of x-ray beam hardening on detective quantum efficiency and radiation dose.

    Science.gov (United States)

    Wong, Molly Donovan; Wu, Xizeng; Liu, Hong

    2011-01-01

    The goal of this preliminary study was to investigate the effects of x-ray beam hardening on the detective quantum efficiency (DQE) and the radiation dose of an inline x-ray imaging system. The ability to decrease the risk of harmful radiation to the patient without compromising the detection capability would more effectively balance the tradeoff between image quality and radiation dose, and therefore benefit the fields of diagnostic x-ray imaging, especially mammography. The DQE and the average glandular dose were both calculated under the same experimental conditions for a range of beam hardening levels, corresponding to no added beam hardening and two thicknesses each of Rhodium (Rh) and Molybdenum (Mo) filters. The dose calculation results demonstrate a reduction of 15% to 24% for the range of beam hardening levels. The comparison of all quantities comprising the DQE exhibit very close correlation between the results obtained without added beam hardening to the results corresponding to the range of beam hardening levels. For the specific experimental conditions utilized in this preliminary study, the results are an indication that the use of beam hardening holds the potential to reduce the radiation dose without decreasing the performance of the system. Future studies will seek to apply this method in a clinical environment and perform a comprehensive image quality evaluation, in an effort to further evaluate the potential of beam hardening to balance the tradeoff between dose and image quality.

  7. Detective quantum efficiency of CT reconstruction: the detection of small objects

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, K.M.

    1979-01-01

    The loss of detection sensitivity incurred by any stage of image processing may normally be characterized by the frequency dependence of the detective quantum efficiency (DQE) of that stage of processing, provided the image is represented in continuous coordinates. However, limitations to the DQE concept arise when discretely sampled projection data are used to obtain discretely sampled computed tomographic (CT) reconstructions. The source of these limitations is the aliasing produced by the discrete sampling which mixes contributions from various frequencies. An associated problem is that the signal-to-noise ratio (SNR) for the detection of an object can depend upon the position of the object relative to the discrete reconstruction pixels. The effective SNR for discrete images must take into account this variation. While there may be no loss in the detection SNR for reconstructions in continuous coordinates (DQE = 100%), a reduction in the SNR will result from aliasing for discrete reconstructions. A simple one-dimensional model elucidates the characteristics of discrete CT reconstruction.

  8. Efficient Detection of 3 THz Radiation from Quantum Cascade Laser Using Silicon CMOS Detectors

    Science.gov (United States)

    Ikamas, Kęstutis; Lisauskas, Alvydas; Boppel, Sebastian; Hu, Qing; Roskos, Hartmut G.

    2017-10-01

    In this paper, we report on efficient detection of the radiation emitted by a THz quantum cascade laser (QCL) using an antenna-coupled field effect transistor (TeraFET). In the limiting case when all radiated power would be collected, the investigated TeraFET can show up to 230 V/W responsivity with the noise equivalent power being as low as 85 pW/√ { {Hz}} at 3.1 THz, which is several times lower than that of the typical Golay cell. A combination of the QCL and a set of off-axis parabolic mirrors with 3-inch and 2-inch focal lengths was used to measure the signal-to-noise ratio (SNR) of the TeraFET. The practically achieved SNR was five times lower than that of the Golay cell and two orders of magnitude lower than a bolometer's. However, TeraFETs are much faster and do not need a signal modulation, thus can be used both in a continuous mode for power monitoring or for investigation of transient processes on a sub-microsecond time scale.

  9. An efficient solver for large structured eigenvalue problems in relativistic quantum chemistry

    CERN Document Server

    Shiozaki, Toru

    2015-01-01

    We report an efficient program for computing the eigenvalues and symmetry-adapted eigenvectors of very large quaternionic (or Hermitian skew-Hamiltonian) matrices, using which structure-preserving diagonalization of matrices of dimension N > 10000 is now routine on a single computer node. Such matrices appear frequently in relativistic quantum chemistry owing to the time-reversal symmetry. The implementation is based on a blocked version of the Paige-Van Loan algorithm [D. Kressner, BIT 43, 775 (2003)], which allows us to use the Level 3 BLAS subroutines for most of the computations. Taking advantage of the symmetry, the program is faster by up to a factor of two than state-of-the-art implementations of complex Hermitian diagonalization; diagonalizing a 12800 x 12800 matrix took 42.8 (9.5) and 85.6 (12.6) minutes with 1 CPU core (16 CPU cores) using our symmetry-adapted solver and Intel MKL's ZHEEV that is not structure-preserving, respectively. The source code is publicly available under the FreeBSD license.

  10. Mitigating the Impact of Large Intrapixel Quantum Efficiency Variations on Precision Stellar Photometry and Astrometry

    Science.gov (United States)

    Mighell, K. J.

    2005-12-01

    Current infrared detector technology can produce imagers with non-uniform intrapixel response functions. This can cause significant stellar flux loss (depending on where a star is centered within the central pixel) which is an observational fact in some existing space-based astronomical cameras. Large intrapixel quantum efficiency (QE) variations can also cause the observed (apparent) positions of stars to be significantly corrupted. With such ugly detectors, the observed stellar brightnesses and positions are neither precise or accurate. Excellent stellar photometry and astrometry is, fortunately, still achievable even in the presence of large intrapixel QE variations --- as long as the image formation process inside the detector is accurately modeled within the photometric reduction code. Detailed analysis of simulated space-based stellar observations are presented which demonstrate how the impact of large intrapixel QE variations can be mitigated using the MATPHOT algorithm with accurate discrete Point Spread functions and accurate Detector Response Functions. Source code and documentation for MATPHOT and support software is freely available at the following web site: http://www.noao.edu/staff/mighell/matphot K.J.M was supported by a grant from the National Aeronautics and Space Administration (NASA), Interagency Order No. NNG05EB61I, which was awarded by the Applied Information Systems Research (AISR) Program of NASA's Science Mission Directorate.

  11. Effects of the molecular diffusion on the determination of the quantum efficiencies in heterogenous photocatalysis

    Energy Technology Data Exchange (ETDEWEB)

    Corboz, M.; Alxneit, I.; Tschudi, H.-R.

    2000-07-01

    A framework to determine the quantum efficiency greek eta {eta} of a photoreaction in a porous layer of photocatalyst is presented. The procedure relies on a model of the photoproduct diffusion in the porous structure of the photocatalyst. The model incorporates a position dependent source term mirroring the light intensity profile in the layer and an effective diffusion coefficient D{sub eff}. It allows for a simultaneous determination of h as well as D{sub eff}. The method is applied to the photosynthesis of CH{sub 4} from gaseous H{sub 2}O at the solid/gas interface of a porous layer of TiO{sub 2} (Degussa P25). A value of h = (8.79 {+-} 0.79) x 10{sup -4} is found for the formation of CH{sub 4} and an effective diffusion coefficient D{sub eff} = (5.64 {+-} 2.51) x 10{sup -10} cm{sup 2}s{sup -1} is obtained. (authors)

  12. Girdling effects on fruit set and quantum yield efficiency of PSII in two Citrus cultivars.

    Science.gov (United States)

    Rivas, F; Gravina, A; Agustí, M

    2007-04-01

    Girdling effects on fruitlet abscission, leaf chlorophyll, chlorophyll a fluorescence and carbohydrate concentration in various flowering and vegetative shoots were studied during natural fruit drop in two Citrus cultivars. Irrespective of shoot type, girdling delayed fruitlet abscission, but only fruitlets borne on leafy shoots had increased final fruit set. Chlorophyll a fluorescence analysis revealed differences in quantum yield efficiency of photosystem II of light adapted leaves (Phi(PSII)) among shoot types and in response to girdling. In young leaves of vegetative shoots, girdling decreased Phi(PSII), whereas Phi(PSII) increased from Day 30 after girdling in young leaves of leafy flowering shoots; however, Phi(PSII) did not change in mature leaves during fruit set in either control or girdled trees. Girdling altered leaf carbohydrate concentrations and the photosynthetic performance of the various shoot types. Our results indicate that, in Citrus, several carbohydrate-based regulatory mechanisms of photosynthesis coexist during carbohydrate accumulation brought about by girdling. It is concluded that the delay in fruitlet abscission and the increase in Phi(PSII )observed in girdled leafy flowering shoots are the mechanisms underlying the enhancement of fruit set after girdling.

  13. Intercomparison of a correlated-photon-based method to measure detector quantum efficiency.

    Science.gov (United States)

    Migdall, Alan; Castelletto, Stefania; Degiovanni, Ivo Pietro; Rastello, Maria Luisa

    2002-05-20

    We report on the absolute calibration of photodetector quantum efficiency by using correlated photon sources, performed independently at two laboratories, the National Institute of Standards and Technology and the Istituto Elettrotecnico Nazionale (IEN). The goal is to use an interlaboratory comparison to demonstrate the inherent absoluteness of the photon correlation technique by showing its independence from the particular experimental setup. We find that detector nonuniformity limited this comparison rather than uncertainty inherent in the method itself. The ultimate goal of these investigations is development of a robust measurement protocol that allows the uncertainties of individual measurements to be determined experimentally and verified operationally. Furthermore, to demonstrate the generality of the procedure, the IEN measurement setup was also used to calibrate a fiber-coupled avalanche photodiode module. Uncertainties are evaluated for the detector both with and without fiber coupling and differences are discussed. The current IEN setup using a thinner and higher transmittance nonlinear crystal for the generation of correlated photons shows a significant improvement in overall accuracy with respect to previously reported results from IEN [Metrologia 32, 501-503 (1996)].

  14. High quantum efficiency annular backside silicon photodiodes for reflectance pulse oximetry in wearable wireless body sensors

    Science.gov (United States)

    Duun, Sune; Haahr, Rasmus G.; Hansen, Ole; Birkelund, Karen; Thomsen, Erik V.

    2010-07-01

    The development of annular photodiodes for use in a reflectance pulse oximetry sensor is presented. Wearable and wireless body sensor systems for long-term monitoring require sensors that minimize power consumption. We have fabricated large area 2D ring-shaped silicon photodiodes optimized for minimizing the optical power needed in reflectance pulse oximetry. To simplify packaging, backside photodiodes are made which are compatible with assembly using surface mounting technology without pre-packaging. Quantum efficiencies up to 95% and area-specific noise equivalent powers down to 30 fW Hz-1/2 cm-1 are achieved. The photodiodes are incorporated into a wireless pulse oximetry sensor system embedded in an adhesive patch presented elsewhere as 'The Electronic Patch'. The annular photodiodes are fabricated using two masked diffusions of first boron and subsequently phosphor. The surface is passivated with a layer of silicon nitride also serving as an optical filter. As the final process, after metallization, a hole in the center of the photodiode is etched using deep reactive ion etch.

  15. Efficient Detection of 3 THz Radiation from Quantum Cascade Laser Using Silicon CMOS Detectors

    Science.gov (United States)

    Ikamas, Kęstutis; Lisauskas, Alvydas; Boppel, Sebastian; Hu, Qing; Roskos, Hartmut G.

    2017-06-01

    In this paper, we report on efficient detection of the radiation emitted by a THz quantum cascade laser (QCL) using an antenna-coupled field effect transistor (TeraFET). In the limiting case when all radiated power would be collected, the investigated TeraFET can show up to 230 V/W responsivity with the noise equivalent power being as low as 85 pW/ √ {Hz} at 3.1 THz, which is several times lower than that of the typical Golay cell. A combination of the QCL and a set of off-axis parabolic mirrors with 3-inch and 2-inch focal lengths was used to measure the signal-to-noise ratio (SNR) of the TeraFET. The practically achieved SNR was five times lower than that of the Golay cell and two orders of magnitude lower than a bolometer's. However, TeraFETs are much faster and do not need a signal modulation, thus can be used both in a continuous mode for power monitoring or for investigation of transient processes on a sub-microsecond time scale.

  16. Type II GaSb/GaAs quantum dot/ring stacks with extended photoresponse for efficient solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Carrington, Peter James, E-mail: p.carrington@lancaster.ac.uk [Physics Department, Lancaster University, Lancaster LA1 4YB (United Kingdom); Mahajumi, Abu Syed [Physics Department, Lancaster University, Lancaster LA1 4YB (United Kingdom); Wagener, Magnus C.; Botha, Johannes Reinhardt [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Zhuang Qian; Krier, Anthony [Physics Department, Lancaster University, Lancaster LA1 4YB (United Kingdom)

    2012-05-15

    We report on the fabrication of GaAs based p-i-n solar cells containing 5 and 10 layers of type II GaSb quantum rings grown by molecular beam epitaxy. Solar cells containing quantum rings show improved efficiency at longer wavelengths into the near-IR extending up to 1500 nm and show enhanced short-circuit current under 1 sun illumination compared to a GaAs control cell. A reduction in the open-circuit voltage is observed due to the build-up of internal strain. The MBE growth, formation and photoluminescence of single and stacked layers of GaSb/GaAs quantum rings are also presented.

  17. Sulfated Carbon Quantum Dots as Efficient Visible-Light Switchable Acid Catalysts for Room-Temperature Ring-Opening Reactions.

    Science.gov (United States)

    Li, Haitao; Sun, Chenghua; Ali, Muataz; Zhou, Fengling; Zhang, Xinyi; MacFarlane, Douglas R

    2015-07-13

    Acid catalytic processes play a classic and important role in modern organic synthesis. How well the acid can be controlled often plays the key role in the controllable synthesis of the products with high conversion yield and selectivity. The preparation of a novel, photo-switchable solid-acid catalyst based on carbon quantum dots is described. The carbon quantum dots are decorated with small amounts of hydrogensulfate groups and thus exhibit a photogenerated acidity that produces a highly efficient acid catalysis of the ring opening of epoxides with methanol and other primary alcohols. This reversible, light-switchable acidity is shown to be due to photoexcitation and charge separation in the carbon quantum dots, which create an electron withdrawing effect from the acidic groups. The catalyst is easily separated by filtration, and we demonstrate multiple cycles of its recovery and reuse.

  18. Highly indistinguishable on-demand resonance fluorescence photons from a deterministic quantum dot micropillar device with 74% extraction efficiency

    DEFF Research Database (Denmark)

    Gregersen, Niels

    2016-01-01

    The implementation and engineering of bright and coherent solid state quantum light sources is key for the realization of both on chip and remote quantum networks. Despite tremendous efforts for more than 15 years, the combination of these two key prerequisites in a single, potentially scalable...... device is a major challenge. Here, we report on the observation of bright single photon emission generated via pulsed, resonance fluorescence conditions from a single quantum dot (QD) deterministically centered in a micropillar cavity device via cryogenic optical lithography. The brightness of the QD...... fluorescence is greatly enhanced on resonance with the fundamental mode of the pillar, leading to an overall device efficiency of η = (74 ± 4) % for a single photon emission as pure as g (2) (0) = 0.0092 ± 0.0004. The combination of large Purcell enhancement and resonant pumping conditions allows us to observe...

  19. Diagnostics of the efficiency of surface plasmon-polariton excitation by quantum dots via polarization measurements of the output radiation

    Energy Technology Data Exchange (ETDEWEB)

    Kukushkin, V. A., E-mail: vakuk@appl.sci-nnov.ru [Russian Academy of Sciences, Institute of Applied Physics (Russian Federation); Baidus, N. V. [Lobachevsky State University of Nizhni Novgorod (Russian Federation); Zdoroveishchev, A. V. [Lobachevsky State University of Nizhni Novgorod, Physicotechnical Research Institute (Russian Federation)

    2015-06-15

    It is demonstrated that the efficiency of surface plasmon-polariton excitation at a metal-semiconductor interface by active quantum dots can be determined from measurements of the polarization characteristics of the output radiation. Experimentally, the proposed diagnostic method is based on finding the ratio of the intensities of the output radiation with polarizations orthogonal and parallel to the nanoheterostructure plane for two different distances between the quantum-dot layer and the metal-semiconductor interface. These data are then used to obtain the unknown parameters in the proposed mathematical model which makes it possible to calculate the rate of surface plasmon-polariton excitation by active quantum dots. As a result, this rate can be determined without complicated expensive equipment for fast time-resolved measurements.

  20. Enhanced life time and suppressed efficiency roll-off in phosphorescent organic light-emitting diodes with multiple quantum well structures

    Directory of Open Access Journals (Sweden)

    Ja-Ryong Koo

    2012-03-01

    Full Text Available We demonstrate red phosphorescent organic light-emitting diodes (OLEDs with multiple quantum well structures which confine triplet exciton inside an emitting layer (EML region. Five types of OLEDs, from a single to five quantum wells, are fabricated with charge control layers to produce high efficiencies, and the performance of the devices is investigated. The improved quantum efficiency and lifetime of the OLED with four quantum wells, and its suppressed quantum efficiency roll-off of 17.6%, can be described by the increased electron–hole charge balance owing to the bipolar property as well as the efficient triplet exciton confinement within each EML, and by prevention of serious triplet–triplet and/or triplet–polaron annihilation as well as the Förster self-quenching due to charge control layers.

  1. Efficiency enhancement of InGaN/GaN multiple quantum well solar cells using CdS quantum dots and distributed Bragg reflectors

    Science.gov (United States)

    Tsai, Yu-Lin; Lin, Chien-Chung; Han, Hau-Vei; Chen, Hsin-Chu; Chen, Kuo-Ju; Lai, Wei-Chi; Sheu, Jin-Kong; Lai, Fang-I.; Yu, Peichen; Kuo, Hao-Chung

    2013-03-01

    In recent year, InGaN-based alloy was also considered for photovoltaic devices owing to the distinctive material properties which are benefit photovoltaic performance. However, the Indium tin oxide (ITO) layer on top, which plays a role of transparent conductive oxide (TCO), can absorb UV photons without generating photocurrent. Also, the thin absorber layer in the device, which is consequent result after compromising with limited crystal quality, has caused insufficient light absorption. In this report, we propose an approach for solving these problems. A hybrid design of InGaN/GaN multiple quantum wells (MQWs) solar cells combined with colloidal CdS quantum dots (QDs) and back side distributed Bragg reflectors (DBRs) has been demonstrated. CdS QDs provide down-conversion effect at UV regime to avoid absorption of ITO. Moreover, CdS QDs also exhibit anti-reflective feature. DBRs at the back side have effectively reflected the light back into the absorber layer. CdS QDs enhance the external quantum efficiency (EQE) for light with wavelength shorter than 400 nm, while DBRs provide a broad band enhancement in EQE, especially within the region of 400 nm ~ 430 nm in wavelength. CdS QDs effectively achieved a power conversion efficiency enhancement as high as 7.2% compared to the device without assistance of CdS QDs. With the participation of DBRs, the power conversion efficiency enhancement has been further boosted to 14%. We believe that the hybrid design of InGaN/GaN MQWs solar cells with QDs and DBRs can be a method for high efficiency InGaN/GaN MQWs solar cells.

  2. Generating free charges by carrier multiplication in quantum dots for highly efficient photovoltaics.

    Science.gov (United States)

    Ten Cate, Sybren; Sandeep, C S Suchand; Liu, Yao; Law, Matt; Kinge, Sachin; Houtepen, Arjan J; Schins, Juleon M; Siebbeles, Laurens D A

    2015-02-17

    CONSPECTUS: In a conventional photovoltaic device (solar cell or photodiode) photons are absorbed in a bulk semiconductor layer, leading to excitation of an electron from a valence band to a conduction band. Directly after photoexcitation, the hole in the valence band and the electron in the conduction band have excess energy given by the difference between the photon energy and the semiconductor band gap. In a bulk semiconductor, the initially hot charges rapidly lose their excess energy as heat. This heat loss is the main reason that the theoretical efficiency of a conventional solar cell is limited to the Shockley-Queisser limit of ∼33%. The efficiency of a photovoltaic device can be increased if the excess energy is utilized to excite additional electrons across the band gap. A sufficiently hot charge can produce an electron-hole pair by Coulomb scattering on a valence electron. This process of carrier multiplication (CM) leads to formation of two or more electron-hole pairs for the absorption of one photon. In bulk semiconductors such as silicon, the energetic threshold for CM is too high to be of practical use. However, CM in nanometer sized semiconductor quantum dots (QDs) offers prospects for exploitation in photovoltaics. CM leads to formation of two or more electron-hole pairs that are initially in close proximity. For photovoltaic applications, these charges must escape from recombination. This Account outlines our recent progress in the generation of free mobile charges that result from CM in QDs. Studies of charge carrier photogeneration and mobility were carried out using (ultrafast) time-resolved laser techniques with optical or ac conductivity detection. We found that charges can be extracted from photoexcited PbS QDs by bringing them into contact with organic electron and hole accepting materials. However, charge localization on the QD produces a strong Coulomb attraction to its counter charge in the organic material. This limits the production

  3. Air-Stable and Efficient PbSe Quantum-Dot Solar Cells Based upon ZnSe to PbSe Cation-Exchanged Quantum Dots

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sungwoo; Marshall, Ashley R.; Kroupa, Daniel M.; Miller, Elisa M.; Luther, Joseph M.; Jeong, Sohee; Beard, Matthew C.

    2015-08-25

    We developed a single step, cation-exchange reaction that produces air-stable PbSe quantum dots (QDs) from ZnSe QDs and PbX2 (X = Cl, Br, or I) precursors. The resulting PbSe QDs are terminated with halide anions and contain residual Zn cations. We characterized the PbSe QDs using UV–vis–NIR absorption, photoluminescence quantum yield spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. Solar cells fabricated from these PbSe QDs obtained an overall best power conversion efficiency of 6.47% at one sun illumination. The solar cell performance without encapsulation remains unchanged for over 50 days in ambient conditions; and after 50 days, the National Renewable Energy Laboratory certification team certified the device at 5.9%.

  4. Quantum efficiency and temperature coefficients of GaInP/GaAs dual-junction solar cell

    Institute of Scientific and Technical Information of China (English)

    LIU Lei; CHEN NuoFu; BAI YiMing; CUI Ming; ZHANG Han; GAO FuBao; YIN ZhiGang; ZHANG XingWang

    2009-01-01

    GalnP/GaAs dual-junction solar cell with a conversion efficiency of 25.2% has been fabricated using metalorganic chemical vapor deposition (MOCVD) technique. Quantum efficiencies of the solar cell were measured within a temperature range from 25 to 160℃. The results indicate that the quantum ef-ficiencies of the subcells increase slightly with the increasing temperature. And red-shift phenomena of absorption limit for all subcells are observed by increasing the cell's work temperature, which are consistent with the viewpoint of energy gap narrowing effect. The short-circuit current density tem-perature coefficients dJoc/dT of GalnP subcell and GaAs subcell are determined to be 8.9 and 7.4 μA/cm2/℃ from the quantum efficiency data, respectively. And the open-circuit cell voltage temperature coefficients d Voc/d T calculated based on a theoretical equation are -2.4 mV/℃ and -2.1 mV/℃ for GalnP subcell and GaAs subcell.

  5. Effective detective quantum efficiency for two mammography systems: Measurement and comparison against established metrics

    Energy Technology Data Exchange (ETDEWEB)

    Salvagnini, Elena [UZ Gasthuisberg, Medical Imaging Research Center and Department of Radiology, Herestraat 49, B-3000 Leuven, Belgium and SCK-CEN, Boeretang 200, B-2400 Mol (Belgium); Bosmans, Hilde; Marshall, Nicholas W. [UZ Gasthuisberg, Medical Imaging Research Center and Department of Radiology, Herestraat 49, B-3000 Leuven (Belgium); Struelens, Lara [SCK-CEN, Boeretang 200, B-2400 Mol (Belgium)

    2013-10-15

    Purpose: The aim of this paper was to illustrate the value of the new metric effective detective quantum efficiency (eDQE) in relation to more established measures in the optimization process of two digital mammography systems. The following metrics were included for comparison against eDQE: detective quantum efficiency (DQE) of the detector, signal difference to noise ratio (SdNR), and detectability index (d′) calculated using a standard nonprewhitened observer with eye filter.Methods: The two systems investigated were the Siemens MAMMOMAT Inspiration and the Hologic Selenia Dimensions. The presampling modulation transfer function (MTF) required for the eDQE was measured using two geometries: a geometry containing scattered radiation and a low scatter geometry. The eDQE, SdNR, and d′ were measured for poly(methyl methacrylate) (PMMA) thicknesses of 20, 40, 60, and 70 mm, with and without the antiscatter grid and for a selection of clinically relevant target/filter (T/F) combinations. Figures of merit (FOMs) were then formed from SdNR and d′ using the mean glandular dose as the factor to express detriment. Detector DQE was measured at energies covering the range of typical clinically used spectra.Results: The MTF measured in the presence of scattered radiation showed a large drop at low spatial frequency compared to the low scatter method and led to a corresponding reduction in eDQE. The eDQE for the Siemens system at 1 mm{sup −1} ranged between 0.15 and 0.27, depending on T/F and grid setting. For the Hologic system, eDQE at 1 mm{sup −1} varied from 0.15 to 0.32, again depending on T/F and grid setting. The eDQE results for both systems showed that the grid increased the system efficiency for PMMA thicknesses of 40 mm and above but showed only small sensitivity to T/F setting. While results of the SdNR and d′ based FOMs confirmed the eDQE grid position results, they were also more specific in terms of T/F selection. For the Siemens system at 20 mm PMMA

  6. Effective detective quantum efficiency for two mammography systems: measurement and comparison against established metrics.

    Science.gov (United States)

    Salvagnini, Elena; Bosmans, Hilde; Struelens, Lara; Marshall, Nicholas W

    2013-10-01

    The aim of this paper was to illustrate the value of the new metric effective detective quantum efficiency (eDQE) in relation to more established measures in the optimization process of two digital mammography systems. The following metrics were included for comparison against eDQE: detective quantum efficiency (DQE) of the detector, signal difference to noise ratio (SdNR), and detectability index (d') calculated using a standard nonprewhitened observer with eye filter. The two systems investigated were the Siemens MAMMOMAT Inspiration and the Hologic Selenia Dimensions. The presampling modulation transfer function (MTF) required for the eDQE was measured using two geometries: a geometry containing scattered radiation and a low scatter geometry. The eDQE, SdNR, and d' were measured for poly(methyl methacrylate) (PMMA) thicknesses of 20, 40, 60, and 70 mm, with and without the antiscatter grid and for a selection of clinically relevant target/filter (T/F) combinations. Figures of merit (FOMs) were then formed from SdNR and d' using the mean glandular dose as the factor to express detriment. Detector DQE was measured at energies covering the range of typical clinically used spectra. The MTF measured in the presence of scattered radiation showed a large drop at low spatial frequency compared to the low scatter method and led to a corresponding reduction in eDQE. The eDQE for the Siemens system at 1 mm(-1) ranged between 0.15 and 0.27, depending on T/F and grid setting. For the Hologic system, eDQE at 1 mm(-1) varied from 0.15 to 0.32, again depending on T/F and grid setting. The eDQE results for both systems showed that the grid increased the system efficiency for PMMA thicknesses of 40 mm and above but showed only small sensitivity to T/F setting. While results of the SdNR and d' based FOMs confirmed the eDQE grid position results, they were also more specific in terms of T/F selection. For the Siemens system at 20 mm PMMA, the FOMs indicated Mo/Mo (grid out) as

  7. Efficient heralding of O-band passively spatial-multiplexed photons for noise-tolerant quantum key distribution.

    Science.gov (United States)

    Liu, Mao Tong; Lim, Han Chuen

    2014-09-22

    When implementing O-band quantum key distribution on optical fiber transmission lines carrying C-band data traffic, noise photons that arise from spontaneous Raman scattering or insufficient filtering of the classical data channels could cause the quantum bit-error rate to exceed the security threshold. In this case, a photon heralding scheme may be used to reject the uncorrelated noise photons in order to restore the quantum bit-error rate to a low level. However, the secure key rate would suffer unless one uses a heralded photon source with sufficiently high heralding rate and heralding efficiency. In this work we demonstrate a heralded photon source that has a heralding efficiency that is as high as 74.5%. One disadvantage of a typical heralded photon source is that the long deadtime of the heralding detector results in a significant drop in the heralding rate. To counter this problem, we propose a passively spatial-multiplexed configuration at the heralding arm. Using two heralding detectors in this configuration, we obtain an increase in the heralding rate by 37% and a corresponding increase in the heralded photon detection rate by 16%. We transmit the O-band photons over 10 km of noisy optical fiber to observe the relation between quantum bit-error rate and noise-degraded second-order correlation function of the transmitted photons. The effects of afterpulsing when we shorten the deadtime of the heralding detectors are also observed and discussed.

  8. A quantum-chemical perspective into low optical-gap polymers for highly-efficient organic solar cells

    KAUST Repository

    Risko, Chad

    2011-03-15

    The recent and rapid enhancement in power conversion efficiencies of organic-based, bulk heterojunction solar cells has been a consequence of both improved materials design and better understanding of the underlying physical processes involved in photocurrent generation. In this Perspective, we first present an overview of the application of quantum-chemical techniques to study the intrinsic material properties and molecular- and nano-scale processes involved in device operation. In the second part, these quantum-chemical tools are applied to an oligomer-based study on a collection of donor-acceptor copolymers that have been used in the highest-efficiency solar cell devices reported to date. The quantum-chemical results are found to be in good agreement with the empirical data related to the electronic and optical properties. In particular, they provide insight into the natures of the electronic excitations responsible for the near-infrared/visible absorption profiles, as well as into the energetics of the low-lying singlet and triplet states. These results lead to a better understanding of the inherent differences among the materials, and highlight the usefulness of quantum chemistry as an instrument for material design. Importantly, the results also point to the need to continue the development of integrated, multi scale modeling approaches to provide a thorough understanding of the materials properties. © The Royal Society of Chemistry 2011.

  9. The Colloidal Stabilization of Quantum Dots: Towards Manufacturable, Efficient Solution-Processed Solar Cells

    Science.gov (United States)

    Rollny, Lisa

    Understanding colloidal stabilization can influence the design of optoelectronic devices and enable improvements to their performance and stability. For photovoltaics, important characteristics of the active layer material are high conductivity along with a minimum of recombination centers. In order to capitalize on the benefits of solution-processed materials, it is important to minimize the number of processing steps: ideally, to achieve a low-cost solution, materials would be deposited using a single process step compatible with roll-to-roll manufacturing. Prior to this work, the highest-performing colloidal quantum dots (CQD) solar cells have relied on several deposition steps that are repeated in a layer-by-layer (LBL) fashion. The purpose of these process steps has been to remove the long insulating ligands used in synthesis and replace them with short ligands that allow electrical conduction. The large number of steps combined, typically implemented via spin coating, leads to inefficient materials utilization and fails to show a path to a manufacturable solution. In this work, the first CQD solar cells were designed, built, and characterized combining state-of-art performance with scalable manufacture. Firstly, I report the first automated CQD synthesis to result in CQDs that form high-performance CQD solar cells. I analyze the CQD synthesis and by separating it into two phases---nucleation and growth phase---my insights are used to create higher-quality CQDs exhibiting enhanced monodispersity. I then proceed to develop a CQD ink: a CQD solution ready for direct deposition to form a semiconducting film exhibiting low trap state density. In early trials the CQD ink showed only limited power conversion efficiencies of 2%. I designed a new ink strategy, which I term cleavable hemiketal ligands. This novel two-component ligand strategy enables the combination of colloidal stabilization (via this longer two-component ligand) and cleavability (enabling excellent

  10. High-efficiency WSi superconducting nanowire single-photon detectors for quantum state engineering in the near infrared

    CERN Document Server

    Jeannic, H Le; Cavaillès, A; Marsili, F; Shaw, M D; Huang, K; Morin, O; Nam, S W; Laurat, J

    2016-01-01

    We report on high-efficiency superconducting nanowire single-photon detectors based on amorphous WSi and optimized at 1064 nm. At an operating temperature of 1.8 K, we demonstrated a 93% system detection efficiency at this wavelength with a dark noise of a few counts per second. Combined with cavity-enhanced spontaneous parametric down-conversion, this fiber-coupled detector enabled us to generate narrowband single photons with a heralding efficiency greater than 90% and a high spectral brightness of $0.6\\times10^4$ photons/(s$\\cdot$mW$\\cdot$MHz). Beyond single-photon generation at large rate, such high-efficiency detectors open the path to efficient multiple-photon heralding and complex quantum state engineering.

  11. Efficient scheme for two-atom entanglement and quantum information processing in cavity QED

    Science.gov (United States)

    Zheng; Guo

    2000-09-11

    A scheme is proposed for the generation of two-atom maximally entangled states and realization of quantum logic gates and teleportation with cavity QED. The scheme does not require the transfer of quantum information between the atoms and cavity. In the scheme the cavity is only virtually excited and thus the requirement on the quality factor of the cavities is greatly loosened.

  12. An Experimental Study of the Quantum Efficiency and Topology of Copper Photocathode Due to Plasma Cleaning and Etching

    CERN Document Server

    Palmer, Denni T; Kirby, Robert

    2005-01-01

    We have developed an experimental research program to the study of the photoemission properties of copper photocathodes as a function of various plasma cleaning/etching parameters. The quantum efficiency, QE, and topology, Ra and Rpp, of Copper Photocathodes, , will be monitored while undergoing plasma cleaning/etching process. We will monitor the QE as a function of time for the various test coupons while we optimize the various plasma processing parameters. In addition, surface topology, will be studied to determine the suitability of the cleaning/etching process to produce an acceptable photoemitter. We propose to use two metrics in the evaluation of the plasma cleaning process as an acceptable cleaning method for metallic photocathodes, Quantum Efficiency versus Wavelength and Surface roughness: Ra and Rpp represent the Average Roughness and Peak to Peak Roughness parameters, respectively.

  13. Femtosecond laser direct writing of gratings and waveguides in high quantum efficiency erbium-doped Baccarat glass

    Energy Technology Data Exchange (ETDEWEB)

    Vishnubhatla, K C; Kumar, R Sai Santosh; Rao, D Narayana [School of Physics, University of Hyderabad, Hyderabad 500046 (India); Rao, S Venugopal [ACRHEM, University of Hyderabad, Hyderabad 500046 (India); Osellame, R; Ramponi, R [IFN - CNR and Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci, 32, 20133, Milano (Italy); Bhaktha, S N B; Mattarelli, M; Montagna, M [Dipartimento di Fisica, CSMFO Lab., Universita di Trento, 38050 Trento (Italy); Turrell, S [Universite des Sciences et Technologies de Lille, Laboratoire de Spectrochimie Infrarouge et Raman, Batiment C5 - UMR CNRS 8516, 59655 Villeneuve d' Ascq cedex (France); Chiappini, A; Chiasera, A; Ferrari, M [CNR-IFN, CSMFO Lab., Via alla Cascata 56/c, 38050 Povo-Trento (Italy); Righini, G C, E-mail: dnrsp@uohyd.ernet.i, E-mail: svrsp@uohyd.ernet.i, E-mail: krishna.vishunubhatla@polimi.i [CNR-IFAC, MDF Lab., Sesto Fiorentino (Firenze) (Italy)

    2009-10-21

    The femtosecond laser direct writing technique was employed to inscribe gratings and waveguides in high quantum efficiency erbium-doped Baccarat glass. Using the butt coupling technique, a systematic study of waveguide loss with respect to input pulse energy and writing speed was performed to achieve the best waveguide with low propagation loss (PL). By pumping at 980 nm, we observed signal enhancement in these active waveguides in the telecom spectral region. The refractive index change was smooth and we estimated it to be {approx}10{sup -3}. The high quantum efficiency ({approx}80%) and a best PL of {approx}0.9 dB cm{sup -1} combined with signal enhancement makes Baccarat glass a potential candidate for application in photonics.

  14. Calibrating and Controlling the Quantum Efficiency Distribution of Inhomogeneously Broadened Quantum Rods by Using a Mirror Ball

    DEFF Research Database (Denmark)

    Hansen, Per Lunnemann; Rabouw, Freddy T.; van Dijk-Moes, Relinde J. A.

    2013-01-01

    We demonstrate that a simple silver coated ball lens can be used to accurately measure the entire distribution of radiative transition rates of quantum dot nanocrystals. This simple and cost-effective implementation of Drexhage’s method that uses nanometer-controlled optical mode density variations...... near a mirror, not only allows an extraction of calibrated ensemble-averaged rates, but for the first time also to quantify the full inhomogeneous dispersion of radiative and non radiative decay rates across thousands of nanocrystals. We apply the technique to novel ultrastable CdSe/CdS dot-in-rod...

  15. Theoretical Insight into the Internal Quantum Efficiencies of Polymer/C$_{60}$ and Polymer/SWNT Photovoltaic Devices

    OpenAIRE

    Glanzmann, Livia Noëmi; Mowbray, Duncan John

    2016-01-01

    The internal quantum efficiency (IQE) of an organic photovoltaic device (OPV) is proportional to the number of free charge carriers generated and their conductivity, per absorbed photon. However, both the IQE and the quantities that determine it, for example, electron-hole binding, charge separation, electron-hole recombination, and conductivity, can only be inferred indirectly from experiments. Using density functional theory, we calculate the excited-state formation energy, charge transfer,...

  16. Efficiency of four-wave mixing in injection-locked InAs/GaAs quantum-dot lasers

    Directory of Open Access Journals (Sweden)

    H. Huang

    2016-12-01

    Full Text Available Frequency conversion using highly non-degenerate four-wave mixing is investigated in optically injection-locked InAs/GaAs quantum-dot Fabry-Perot lasers with different ridge waveguide dimensions. Conversion efficiencies up to -16 dB with a large optical signal-to-noise ratios of 36 dB are unveiled. The conversion bandwidth is extended to 4 THz with a quasi-symmetrical response between up- and down-converted signals.

  17. A study of the quantum efficiency of multichannel relaxation in LiNbO3:Yb, Er crystals

    Science.gov (United States)

    Stroganova, E. V.; Nalbantov, N. N.; Galutsky, V. V.; Yakovenko, N. A.

    2016-12-01

    Luminescence spectra of gradient-activated LiNbO3:Yb, Er crystals with predefined concentration profiles of the optical centers are studied in different spectral regions. The process of electronic excitation energy transfer in the Yb3+-Er3+ system inside the LiNbO3 matrix is calculated and dependences of the quantum efficiency of the up-conversion processes for the green and red luminescences of erbium ions on the time of excitation energy deactivation are obtained.

  18. High-Speed Widely-Tunable 90% Quantum-Efficiency Resonant Cavity Enhanced p-i-n Photodiodes

    Science.gov (United States)

    1998-12-01

    REPORT unclassified b . ABSTRACT unclassified c. THIS PAGE unclassified Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18 8:45am - 9...00am WB2 High-Speed Widely-Tunable >90% Quantum-Efficiency Resonant Cavity Enhanced p-i-n Photodiodes Necmi Biyiklia. Ibrahim Kimukinb. Orhan ...Bilkent, Ankara 06533, Turkey. b Department of Physics, Bilkent University, Bilkent, Ankara 06533, Turkey. c Department of Electrical and Computer

  19. Adaptation to high CO2 concentration in an optimal environment: radiation capture, canopy quantum yield and carbon use efficiency

    Science.gov (United States)

    Monje, O.; Bugbee, B.

    1998-01-01

    The effect of elevated [CO2] on wheat (Triticum aestivum L. Veery 10) productivity was examined by analysing radiation capture, canopy quantum yield, canopy carbon use efficiency, harvest index and daily C gain. Canopies were grown at either 330 or 1200 micromoles mol-1 [CO2] in controlled environments, where root and shoot C fluxes were monitored continuously from emergence to harvest. A rapidly circulating hydroponic solution supplied nutrients, water and root zone oxygen. At harvest, dry mass predicted from gas exchange data was 102.8 +/- 4.7% of the observed dry mass in six trials. Neither radiation capture efficiency nor carbon use efficiency were affected by elevated [CO2], but yield increased by 13% due to a sustained increase in canopy quantum yield. CO2 enrichment increased root mass, tiller number and seed mass. Harvest index and chlorophyll concentration were unchanged, but CO2 enrichment increased average life cycle net photosynthesis (13%, P < 0.05) and root respiration (24%, P < 0.05). These data indicate that plant communities adapt to CO2 enrichment through changes in C allocation. Elevated [CO2] increases sink strength in optimal environments, resulting in sustained increases in photosynthetic capacity, canopy quantum yield and daily C gain throughout the life cycle.

  20. Enhancing the quantum efficiency of InGaN yellow-green light-emitting diodes by growth interruption

    Energy Technology Data Exchange (ETDEWEB)

    Du, Chunhua; Ma, Ziguang; Zhou, Junming; Lu, Taiping; Jiang, Yang; Zuo, Peng; Jia, Haiqiang; Chen, Hong, E-mail: hchen@iphy.ac.cn [Key Laboratory for Renewable Energy, Chinese Academy of Sciences, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condense Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2014-08-18

    We studied the effect of multiple interruptions during the quantum well growth on emission-efficiency enhancement of InGaN-based yellow-green light emitting diodes on c-plane sapphire substrate. The output power and dominant wavelength at 20 mA are 0.24 mW and 556.3 nm. High resolution x-ray diffraction, photoluminescence, and electroluminescence measurements demonstrate that efficiency enhancement could be partially attributed to crystal quality improvement of the active region resulted from reduced In clusters and relevant defects on the surface of InGaN layer by introducing interruptions. The less tilted energy band in the quantum well is also caused by the decrease of In-content gradient along c-axis resulted from In segregation during the interruptions, which increases spatial overlap of electron-hole wavefunction and thus the internal quantum efficiency. The latter also leads to smaller blueshift of dominant wavelength with current increasing.

  1. Adaptation to high CO2 concentration in an optimal environment: radiation capture, canopy quantum yield and carbon use efficiency

    Science.gov (United States)

    Monje, O.; Bugbee, B.

    1998-01-01

    The effect of elevated [CO2] on wheat (Triticum aestivum L. Veery 10) productivity was examined by analysing radiation capture, canopy quantum yield, canopy carbon use efficiency, harvest index and daily C gain. Canopies were grown at either 330 or 1200 micromoles mol-1 [CO2] in controlled environments, where root and shoot C fluxes were monitored continuously from emergence to harvest. A rapidly circulating hydroponic solution supplied nutrients, water and root zone oxygen. At harvest, dry mass predicted from gas exchange data was 102.8 +/- 4.7% of the observed dry mass in six trials. Neither radiation capture efficiency nor carbon use efficiency were affected by elevated [CO2], but yield increased by 13% due to a sustained increase in canopy quantum yield. CO2 enrichment increased root mass, tiller number and seed mass. Harvest index and chlorophyll concentration were unchanged, but CO2 enrichment increased average life cycle net photosynthesis (13%, P CO2 enrichment through changes in C allocation. Elevated [CO2] increases sink strength in optimal environments, resulting in sustained increases in photosynthetic capacity, canopy quantum yield and daily C gain throughout the life cycle.

  2. Adaptation to high CO2 concentration in an optimal environment: radiation capture, canopy quantum yield and carbon use efficiency

    Science.gov (United States)

    Monje, O.; Bugbee, B.

    1998-01-01

    The effect of elevated [CO2] on wheat (Triticum aestivum L. Veery 10) productivity was examined by analysing radiation capture, canopy quantum yield, canopy carbon use efficiency, harvest index and daily C gain. Canopies were grown at either 330 or 1200 micromoles mol-1 [CO2] in controlled environments, where root and shoot C fluxes were monitored continuously from emergence to harvest. A rapidly circulating hydroponic solution supplied nutrients, water and root zone oxygen. At harvest, dry mass predicted from gas exchange data was 102.8 +/- 4.7% of the observed dry mass in six trials. Neither radiation capture efficiency nor carbon use efficiency were affected by elevated [CO2], but yield increased by 13% due to a sustained increase in canopy quantum yield. CO2 enrichment increased root mass, tiller number and seed mass. Harvest index and chlorophyll concentration were unchanged, but CO2 enrichment increased average life cycle net photosynthesis (13%, P CO2 enrichment through changes in C allocation. Elevated [CO2] increases sink strength in optimal environments, resulting in sustained increases in photosynthetic capacity, canopy quantum yield and daily C gain throughout the life cycle.

  3. A novel EPID design for enhanced contrast and detective quantum efficiency

    Science.gov (United States)

    Rottmann, Joerg; Morf, Daniel; Fueglistaller, Rony; Zentai, George; Star-Lack, Josh; Berbeco, Ross

    2016-09-01

    Beams-eye-view imaging applications such as real-time soft-tissue motion estimation are hindered by the inherently low image contrast of electronic portal imaging devices (EPID) currently available for clinical use. We introduce and characterize a novel EPID design that provides substantially increased detective quantum efficiency (DQE), contrast-to-noise ratio (CNR) and sensitivity without degradation in spatial resolution. The prototype design features a stack of four conventional EPID layers combined with low noise integrated readout electronics. Each layer consists of a copper plate, a scintillator (\\text{G}{{\\text{d}}2}{{\\text{O}}2}{{\\text{S}}{}}\\text{:Tb} ) and a photodiode/TFT-switch (aSi:H). We characterize the prototype’s signal response to a 6 MV photon beam in terms of modulation transfer function (MTF), DQE and CNR. The presampled MTF is estimated using a slanted slit technique, the DQE is calculated from measured normalized noise power spectra (nNPS) and the MTF and CNR is estimated using a Las Vegas contrast phantom. The prototype has been designed and built to be interchangeable with the current clinical EPID on the Varian TrueBeam platform (AS-1200) in terms of size and data output specifications. Performance evaluation is conducted in absolute values as well as in relative terms using the Varian AS-1200 EPID as a reference detector. A fivefold increase of DQE(0) to about 6.7% was observed by using the four-layered design versus the AS-1200 reference detector. No substantial differences are observed between each layer’s individual MTF and the one for all four layers operating combined indicating that defocusing due to beam divergence is negligible. Also, using four layers instead of one increases the signal to noise ratio by a factor of 1.7.

  4. Investigation of measurement accuracy of factors used for detective quantum efficiency measurement in digital radiography.

    Science.gov (United States)

    Kunitomo, Hiroshi; Koyama, Shuji; Higashide, Ryo; Ichikawa, Katsuhiro; Hattori, Masumi; Okada, Yoko; Hayashi, Norio; Sawada, Michito

    2014-07-01

    In the detective quantum efficiency (DQE) evaluation of detectors for digital radiography (DR) systems, physical image quality indices such as modulation transfer function (MTF) and normalized noise power spectrum (NNPS) need to be accurately measured to obtain highly accurate DQE evaluations. However, there is a risk of errors in these measurements. In this study, we focused on error factors that should be considered in measurements using clinical DR systems. We compared the incident photon numbers indicated in IEC 62220-1 with those estimated using a Monte Carlo simulation based on X-ray energy spectra measured employing four DR systems. For NNPS, influences of X-ray intensity non-uniformity, tube voltage and aluminum purity were investigated. The effects of geometric magnifications on MTF accuracy were also examined using a tungsten edge plate at distances of 50, 100 and 150 mm from the detector surface at a source-image receptor distance of 2000 mm. The photon numbers in IEC 62220-1 coincided with our estimates of values, with error rates below 2.5%. Tube voltage errors of approximately ±5 kV caused NNPS errors of within 1.0%. The X-ray intensity non-uniformity caused NNPS errors of up to 2.0% at the anode side. Aluminum purity did not affect the measurement accuracy. The maximum MTF reductions caused by geometric magnifications were 3.67% for 1.0-mm X-ray focus and 1.83% for 0.6-mm X-ray focus.

  5. Determination of the detective quantum efficiency of gamma camera systems: a Monte Carlo study.

    Science.gov (United States)

    Eriksson, Ida; Starck, Sven-Ake; Båth, Magnus

    2010-01-01

    The purpose of the present work was to investigate the validity of using the Monte Carlo technique for determining the detective quantum efficiency (DQE) of a gamma camera system and to use this technique in investigating the DQE behaviour of a gamma camera system and its dependency on a number of relevant parameters. The Monte Carlo-based software SIMIND, simulating a complete gamma camera system, was used in the present study. The modulation transfer function (MTF) of the system was determined from simulated images of a point source of (99m)Tc, positioned at different depths in a water phantom. Simulations were performed using different collimators and energy windows. The MTF of the system was combined with the photon yield and the sensitivity, obtained from the simulations, to form the frequency-dependent DQE of the system. As figure-of-merit (FOM), the integral of the 2D DQE was used. The simulated DQE curves agreed well with published data. As expected, there was a strong dependency of the shape and magnitude of the DQE curve on the collimator, energy window and imaging position. The highest FOM was obtained for a lower energy threshold of 127 keV for objects close to the detector and 131 keV for objects deeper in the phantom, supporting an asymmetric window setting to reduce scatter. The Monte Carlo software SIMIND can be used to determine the DQE of a gamma camera system from a simulated point source alone. The optimal DQE results in the present study were obtained for parameter settings close to the clinically used settings.

  6. Construction of 3-dimensional ZnO-nanoflower structures for high quantum and photocurrent efficiency in dye sensitized solar cell

    Energy Technology Data Exchange (ETDEWEB)

    Kilic, Bayram, E-mail: bkilic@yalova.edu.tr [Yalova University, Department of Energy Systems Engineering, Faculty of Engineering, 77100 Yalova (Turkey); Günes, Taylan; Besirli, Ilknur; Sezginer, Merve [Yalova University, Department of Energy Systems Engineering, Faculty of Engineering, 77100 Yalova (Turkey); Tuzemen, Sebahattin [Department of Physics, Faculty of Science, Atatürk University, Erzurum 25240 (Turkey)

    2014-11-01

    Graphical abstract: - Highlights: • The structural and optical characterizations of ZnO nanoflowers were carried out on ITO by hydrothermal method. • Dye sensitized solar cell based ZnO nanoflowers were constructed on substrate. • The surface morphology effect on quantum efficiency and solar conversion efficiency were investigated. - Abstract: 3-dimensional ZnO nanoflower were obtained on FTO (F:SnO{sub 2}) substrate by hydrothermal method in order to produce high efficiency dye sensitized solar cells (DSSCs). We showed that nanoflowers structures have nanoscale branches that stretch to fill gaps on the substrate and these branches of nano-leaves provide both a larger surface area and a direct pathway for electron transport along the channels. It was found that the solar conversion efficiency and quantum efficiency (QE) or incident photon to current conversion efficiencies (IPCE) is highly dependent on nanoflower surface due to high electron injection process. The highest solar conversion efficiency of 5.119 and QE of 60% was obtained using ZnO nanoflowers/N719 dye/I{sup −}/I{sup −}{sub 3} electrolyte. In this study, three dimensional (3D)-nanoflower and one dimensional (1D)-nanowires ZnO nanostructures were also compared against each other in respect to solar conversion efficiency and QE measurements. In the case of the 1D-ZnO nanowire conversion efficiency (η) of 2.222% and IPCE 47% were obtained under an illumination of 100 mW/cm{sup 2}. It was confirmed that the performance of the 3D-nanoflowers was better than about 50% that of the 1D-nanowire dye-sensitized solar cells.

  7. Photovoltaic efficiency of intermediate band solar cells based on CdTe/CdMnTe coupled quantum dots.

    Science.gov (United States)

    Prado, Silvio J; Marques, Gilmar Eugenio; Alcalde, Augusto

    2017-08-11

    In this work we show calculation of optimized efficiencies of intermediate band solar cells (IBSC) based on Mn-doped II-VI CdTe/CdMnTe coupled quantum dot (QD) structures. We focus our attention on the combined effects of geometrical and Mn-doping parameters on the optical properties and solar cell efficiency. In the framework of k . p theory, we accomplished detailed calculations of electronic structure, transition energies, optical selection rules and their corresponding intra- and interband oscillator strengths. With these results and by following the intermediate band model, we have developed a strategy which allows us to find optimal photovoltaic efficiency values. We also show that the effects of band admixture which can lead to degradation of optical transitions and reduction of efficiency, can be partly minimized by a careful selection of the structural parameters and Mn-concentration. Thus, the improvement of band engineering is mandatory for any practical implementation of QD systems as intermediate band solar cell hardware. Finally, our calculations show that it is possible to reach significant efficiency up to ~ 60% by selecting a restricted space of parameters such as quantum dot size and shape and Mn-concentration effects, to improve the modulation of the optical absorption in the structures. © 2017 IOP Publishing Ltd.

  8. Quantum efficiencies of imaging detectors with alkali halide photocathodes. I - Microchannel plates with separate and integral CsI photocathodes

    Science.gov (United States)

    Carruthers, George R.

    1987-01-01

    Measurements and comparisons have been made of the quantum efficiencies of microchannel plate (MCP) detectors in the far-UV (below 2000-A) wavelength range using CsI photocathodes (a) deposited on the front surfaces of microchannel plates and (b) deposited on solid substrates as opaque photocathodes with the resulting photoelectrons input to microchannel plates. The efficiences were measured in both pulse-counting and photodiode modes of operation. Typical efficiencies are about 15 percent at 1216 A for a CsI-coated MCP compared with 65 percent for an opaque CsI photocathode MCP detector. Special processing has yielded an efficiency as high as 20 percent for a CsI-coated MCP. This may possibly be further improved by optimization of the tilt angle of the MCP channels relative to the front face of the MCP and incident radiation. However, at present there still remains a factor of at least 3 quantum efficiency advantage in the separate opaque CsI photocathode configuration.

  9. Efficient scheme for entangled states and quantum information transfer with trapped atoms in a resonator

    Institute of Scientific and Technical Information of China (English)

    Li Peng-Bo; Li Fu-Li

    2011-01-01

    A protocol is proposed to generate atomic entangled states and implement quantum information transfer in a cavity quantum electrodynamics system. It utilizes Raman transitions or stimulated Raman adiabatic passages between two systems to entangle the ground states of two three-state A-type atoms trapped in a single mode cavity. It does not need the measurements on cavity field nor atomic detection and can be implemented in a deterministic fashion. Since the present protocol is insensitive to both cavity decay and atomic spontaneous emission,it may have some interesting applications in quantum information processing.

  10. Colored ultra-thin hybrid photovoltaics with high quantum efficiency for decorative PV applications (Presentation Recording)

    Science.gov (United States)

    Guo, L. Jay

    2015-10-01

    adopted by other material systems as well. Based on these understandings, we have also developed colored perovskite PV by integrating an optical cavity with the perovskite semiconductors [4]. The principle and experimental results will be presented. 1. J. Y. Lee, K. T. Lee, S.Y. Seo, L. J. Guo, "Decorative power generating panels creating angle insensitive transmissive colors," Sci. Rep. 4, 4192, 2014. 2. K. T. Lee, J.Y. Lee, S.-Y. Seo, and L. J. Guo, "Colored ultra-thin hybrid photovoltaics with high quantum efficiency," Light: Science and Applications, 3, e215, 2014. 3. K. T. Lee, S.-Y. Seo, J.Y. Lee, and L. J. Guo, "Ultrathin metal-semiconductor-metal resonator for angle invariant visible band transmission filters," Appl. Phys. Lett. 104, 231112, (2014); and "Strong resonance effect in a lossy medium-based optical cavity for angle robust spectrum filters," Adv. Mater, 26, 6324-6328, 2014. 4. K. T. Lee, M. Fukuda, L. J. Guo, "Colored, see-through perovskite solar cells employing an optical cavity," Submitted, 2015

  11. An Efficient Algorithm for Simulating the Real-Time Quantum Dynamics of a Single Spin-1/2 Coupled to Specific Spin-1/2 Baths

    NARCIS (Netherlands)

    Novotny, M.A.; Guerra, M.; Raedt, H. De; Michielsen, K.; Jin, F.

    2012-01-01

    An efficient algorithm for the computation of the real-time dependence of a single quantum spin-1/2 coupled to a specific set of quantum spin-1/2 baths is presented. The specific spin baths have couplings only with the spin operators Sx between bath spins and the central spin. We calculate spin expe

  12. Information Leakage Problem in Efficient Bidirectional Quantum Secure Direct Communication with Single Photons in Both Polarization and Spatial-Mode Degrees of Freedom

    Science.gov (United States)

    Liu, Zhi-Hao; Chen, Han-Wu; Liu, Wen-Jie

    2016-11-01

    The information leakage problem in the efficient bidirectional quantum secure direct communication protocol with single photons in both polarization and spatial-mode degrees of freedom is pointed out. Next, a way to revise this protocol to a truly secure one is given. We hope people pay more attention to the information leakage problem in order to design truly secure quantum communication protocols.

  13. Design for an efficient single photon source based on a single quantum dot embedded in a parabolic solid immersion lens.

    Science.gov (United States)

    Devaraj, Vasanthan; Baek, Jongseo; Jang, Yudong; Jeong, Hyuk; Lee, Donghan

    2016-04-18

    We have designed a single photon emitter based on a single quantum dot embedded within a single mode parabolic solid immersion lens (pSIL) and a capping low-index pSIL. Numerical simulations predicted that the emitter performance should exhibit a high photon collection efficiency with excellent far-field emission properties, broadband operation, and good tolerance in its geometric (spatial configuration) parameters. Good geometric tolerance in a single-mode pSIL without yielding significant losses in the photon collection efficiency is advantageous for device fabrication. The low-index top pSIL layer provided this structure with a high photon collection efficiency, even in the case of a small numerical aperture (NA). Photon collection efficiencies of 64% and 78% were expected for NA values of 0.41 and 0.5, respectively. In addition to the benefits listed above, our combined pSIL design provided excellent broadband performance in a 100 nm range.

  14. Broadband Epsilon-near-Zero Reflectors Enhance the Quantum Efficiency of Thin Solar Cells at Visible and Infrared Wavelengths

    KAUST Repository

    Labelle, A. J.

    2017-02-03

    The engineering of broadband absorbers to harvest white light in thin-film semiconductors is a major challenge in developing renewable materials for energy harvesting. Many solution-processed materials with high manufacturability and low cost, such as semiconductor quantum dots, require the use of film structures with thicknesses on the order of 1 μm to absorb incoming photons completely. The electron transport lengths in these media, however, are 1 order of magnitude smaller than this length, hampering further progress with this platform. Herein, we show that, by engineering suitably disordered nanoplasmonic structures, we have created a new class of dispersionless epsilon-near-zero composite materials that efficiently harness white light. Our nanostructures localize light in the dielectric region outside the epsilon-near-zero material with characteristic lengths of 10-100 nm, resulting in an efficient system for harvesting broadband light when a thin absorptive film is deposited on top of the structure. By using a combination of theory and experiments, we demonstrate that ultrathin layers down to 50 nm of colloidal quantum dots deposited atop the epsilon-near-zero material show an increase in broadband absorption ranging from 200% to 500% compared to a planar structure of the same colloidal quantum-dot-absorber average thickness. When the epsilon-near-zero nanostructures were used in an energy-harvesting module, we observed a spectrally averaged 170% broadband increase in the external quantum efficiency of the device, measured at wavelengths between 400 and 1200 nm. Atomic force microscopy and photoluminescence excitation measurements demonstrate that the properties of these epsilon-near-zero structures apply to general metals and could be used to enhance the near-field absorption of semiconductor structures more widely. We have developed an inexpensive electrochemical deposition process that enables scaled-up production of this nanomaterial for large

  15. High Efficiency Quantum Dot III-V Thermophotovoltaic Cell for Space Power Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Quantum dots are nanoscale materials that have already improved the performance of optical sensors, lasers, light emitting diodes and solar cells. The unique...

  16. High Efficiency Quantum Dot III-V Multijunction Solar Cell for Space Power Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Quantum dots are nanoscale materials that have already improved the performance of optical sensors, lasers, and light emitting diodes. The unique properties of these...

  17. Efficient transfer of an arbitrary qutrit state in circuit quantum electrodynamics.

    Science.gov (United States)

    Liu, Tong; Xiong, Shao-Jie; Cao, Xiao-Zhi; Su, Qi-Ping; Yang, Chui-Ping

    2015-12-01

    Compared with a qubit, a qutrit (i.e., three-level quantum system) has a larger Hilbert space and thus can be used to encode more information in quantum information processing and communication. Here, we propose a method to transfer an arbitrary quantum state between two flux qutrits coupled to two resonators. This scheme is simple because it only requires two basic operations. The state-transfer operation can be performed fast because only resonant interactions are used. Numerical simulations show that the high-fidelity transfer of quantum states between the two qutrits is feasible with current circuit-QED technology. This scheme is quite general and can be applied to accomplish the same task for other solid-state qutrits coupled to resonators.

  18. The photonic nanowire: An emerging platform for a highly efficient quantum light source

    DEFF Research Database (Denmark)

    Gregersen, Niels; Claudon, J.; Munsch, M.;

    The single-photon source capable of emitting single indistinguishable photons on demand represents a key component in quantum information applications. The photonic nanowire represents an attractive platform to construct a source with near-unity eciency......The single-photon source capable of emitting single indistinguishable photons on demand represents a key component in quantum information applications. The photonic nanowire represents an attractive platform to construct a source with near-unity eciency...

  19. Effect of well layer thickness on quantum and energy conversion efficiencies for InGaN/GaN multiple quantum well solar cells

    Science.gov (United States)

    Miyoshi, Makoto; Tsutsumi, Tatsuya; Kabata, Tomoki; Mori, Takuma; Egawa, Takashi

    2017-03-01

    We investigated the effect of well layer thicknesses on the external quantum efficiency (EQE) and energy conversion efficiency (ECE) for InGaN/GaN multiple quantum well (MQW) solar cells grown on sapphire substrates by metalorganic chemical vapor deposition. The results indicated that EQE and ECE have maximum values at a specific well thickness. When the well thickness is sufficiently thin, EQE and ECE increase with an increase in the well thickness owing to an increase in light absorption. Then, once the well thickness surpasses a critical thickness, EQE and ECE begin to decrease owing to the influence of nonradiative recombination processes, which was indicated by the static and dynamic photoluminescence analyses. The critical well thickness probably depends not only on the MQW design but also on growth conditions. Further, we confirmed that the increased total thickness of the stacked well layers leads to increased light absorption and thereby contributes to the improvement of solar cell performance. A high short circuit current density of 1.34 mA/cm2 and a high ECE of 1.31% were achieved for a InGaN/GaN MQW solar cell with a 3.2-nm-thick InGaN well with total well thickness of 115 nm.

  20. Regression relation for pure quantum states and its implications for efficient computing.

    Science.gov (United States)

    Elsayed, Tarek A; Fine, Boris V

    2013-02-15

    We obtain a modified version of the Onsager regression relation for the expectation values of quantum-mechanical operators in pure quantum states of isolated many-body quantum systems. We use the insights gained from this relation to show that high-temperature time correlation functions in many-body quantum systems can be controllably computed without complete diagonalization of the Hamiltonians, using instead the direct integration of the Schrödinger equation for randomly sampled pure states. This method is also applicable to quantum quenches and other situations describable by time-dependent many-body Hamiltonians. The method implies exponential reduction of the computer memory requirement in comparison with the complete diagonalization. We illustrate the method by numerically computing infinite-temperature correlation functions for translationally invariant Heisenberg chains of up to 29 spins 1/2. Thereby, we also test the spin diffusion hypothesis and find it in a satisfactory agreement with the numerical results. Both the derivation of the modified regression relation and the justification of the computational method are based on the notion of quantum typicality.

  1. Highly Enhanced Photoelectrochemical Water Oxidation Efficiency Based on Triadic Quantum Dot/Layered Double Hydroxide/BiVO4 Photoanodes.

    Science.gov (United States)

    Tang, Yanqun; Wang, Ruirui; Yang, Ye; Yan, Dongpeng; Xiang, Xu

    2016-08-03

    The water oxidation half-reaction is considered to be a bottleneck for achieving highly efficient solar-driven water splitting due to its multiproton-coupled four-electron process and sluggish kinetics. Herein, a triadic photoanode consisting of dual-sized CdTe quantum dots (QDs), Co-based layered double hydroxide (LDH) nanosheets, and BiVO4 particles, that is, QD@LDH@BiVO4, was designed. Two sets of consecutive Type-II band alignments were constructed to improve photogenerated electron-hole separation in the triadic structure. The efficient charge separation resulted in a 2-fold enhancement of the photocurrent of the QD@LDH@BiVO4 photoanode. A significantly enhanced oxidation efficiency reaching above 90% in the low bias region (i.e., E < 0.8 V vs RHE) could be critical in determining the overall performance of a complete photoelectrochemical cell. The faradaic efficiency for water oxidation was almost 90%. The conduction band energy of QDs is ∼1.0 V more negative than that of LDH, favorable for the electron injection to LDH and enabling a more efficient hole separation. The enhanced photon-to-current conversion efficiency and improved water oxidation efficiency of the triadic structure may result from the non-negligible contribution of hot electrons or holes generated in QDs. Such a band-matching and multidimensional triadic architecture could be a promising strategy for achieving high-efficiency photoanodes by sufficiently utilizing and maximizing the functionalities of QDs.

  2. Cobalt-doped cadmium sulfide nanoparticles as efficient strategy to enhance performance of quantum dot sensitized solar cells

    Science.gov (United States)

    Firoozi, Najmeh; Dehghani, Hossein; Afrooz, Malihe

    2015-03-01

    In this study, we investigate the effect of Co2+ ion incorporation into CdS layer on the photovoltaic performance of quantum dot sensitized solar cell (QDSSC). Quantum dots are deposited by the successive ionic layer adsorption and reaction (SILAR) method on the mesoporous TiO2 film. The doped system modifies the structure of photoanode that leads to an increase in short circuit current density (Jsc) from 13.16 mA cm-2 to 16.6 mA cm-2 in the un-doped system. Electrochemical impedance analysis (EIS) reveals a decrease in charge transfer resistance at the TiO2/QDs/electrolyte interface that arises from the presence of an internal recombination pathway. The highest energy conversion efficiency (η) of 3.16% is obtained under standard air mass 1.5 global (AM 1.5G) simulated sun light by doping the optimized amount of Co2+ ion in CdS nanoparticles, corresponding to efficiency increment (35%) compared to the un-doped system. The origin of the increase in the efficiency is attributed to the dominance of charge collection to recombination. To further investigation of the electron transport time in the photoanode, the intensity modulated photocurrent spectroscopy (IMPS) is performed under standard conditions. Our obtained results can help to develop a simple and effective method to enhance the efficiency in the QDSSCs.

  3. Very Bright and Efficient Microcavity Top-Emitting Quantum Dot Light-Emitting Diodes with Ag Electrodes.

    Science.gov (United States)

    Liu, Guohong; Zhou, Xiang; Chen, Shuming

    2016-07-01

    The microcavity effect in top-emitting quantum dot light-emitting diodes (TQLEDs) is theoretically and experimentally investigated. By carefully optimizing the cavity length, the thickness of the top Ag electrode and the thickness of the capping layer, very bright and efficient TQLEDs with external quantum efficiency (EQE) of 12.5% are demonstrated. Strong dependence of luminance and efficiency on cavity length is observed, in good agreement with theoretical calculation. By setting the normal-direction resonant wavelength around the peak wavelength of the intrinsic emission, highest luminance of 112 000 cd/m(2) (at a driving voltage of 7 V) and maximum current efficiency of 27.8 cd/A are achieved, representing a 12-fold and a 2.1-fold enhancement compared to 9000 cd/m(2) and 13.2 cd/A of the conventional bottom emitting devices, respectively, whereas the highest EQE of 12.5% is obtained by setting the resonant wavelength 30 nm longer than the peak wavelength of the intrinsic emission. Benefit from the very narrow spectrum of QDs and the low absorption of silver electrodes, the potential of microcavity effect can be fully exploited in TQLEDs.

  4. Pulsed voltage deposited lead selenide thin film as efficient counter electrode for quantum-dot-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Bin Bin [Key Laboratory of Macromolecular Science of Shaanxi Province & School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062 (China); Department of Chemical Engineering, Institute of Chemical Industry, Shaanxi Institute of Technology, Xi’an 710300 (China); Wang, Ye Feng [Key Laboratory of Macromolecular Science of Shaanxi Province & School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062 (China); Wang, Xue Qing [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China); Zeng, Jing Hui, E-mail: jhzeng@ustc.edu [Key Laboratory of Macromolecular Science of Shaanxi Province & School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062 (China)

    2016-04-30

    Highlights: • PbSe thin film is deposited on FTO glass by a pulse voltage electrodeposition method. • The thin film is used as counter electrode (CE) in quantum dot-sensitized solar cell. • Superior electrocatalytic activity and stability in the polysulfide electrolyte is received. • The narrow band gap characteristics and p-type conductivity enhances the cell efficiency. • An efficiency of 4.67% is received for the CdS/CdSe co-sensitized solar cells. - Abstract: Lead selenide (PbSe) thin films were deposited on fluorine doped tin oxide (FTO) glass by a facile one-step pulse voltage electrodeposition method, and used as counter electrode (CE) in CdS/CdSe quantum dot-sensitized solar cells (QDSSCs). A power conversion efficiency of 4.67% is received for the CdS/CdSe co-sensitized solar cells, which is much better than that of 2.39% received using Pt CEs. The enhanced performance is attributed to the extended absorption in the near infrared region, superior electrocatalytic activity and p-type conductivity with a reflection of the incident light at the back electrode in addition. The physical and chemical properties were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), reflectance spectra, electrochemical impedance spectroscopy (EIS) and Tafel polarization measurements. The present work provides a facile pathway to an efficient CE in the QDSSCs.

  5. One-Pot Large-Scale Synthesis of Carbon Quantum Dots: Efficient Cathode Interlayers for Polymer Solar Cells.

    Science.gov (United States)

    Yang, Yuzhao; Lin, Xiaofeng; Li, Wenlang; Ou, Jiemei; Yuan, Zhongke; Xie, Fangyan; Hong, Wei; Yu, Dingshan; Ma, Yuguang; Chi, Zhenguo; Chen, Xudong

    2017-05-03

    Cathode interlayers (CILs) with low-cost, low-toxicity, and excellent cathode modification ability are necessary for the large-scale industrialization of polymer solar cells (PSCs). In this contribution, we demonstrated one-pot synthesized carbon quantum dots (C-dots) with high production to serve as efficient CIL for inverted PSCs. The C-dots were synthesized by a facile, economical microwave pyrolysis in a household microwave oven within 7 min. Ultraviolet photoelectron spectroscopy (UPS) studies showed that the C-dots possessed the ability to form a dipole at the interface, resulting in the decrease of the work function (WF) of cathode. External quantum efficiency (EQE) measurements and 2D excitation-emission topographical maps revealed that the C-dots down-shifted the high energy near-ultraviolet light to low energy visible light to generate more photocurrent. Remarkably improvement of power conversion efficiency (PCE) was attained by incorporation of C-dots as CIL. The PCE was boosted up from 4.14% to 8.13% with C-dots as CIL, which is one of the best efficiency for i-PSCs used carbon based materials as interlayers. These results demonstrated that C-dots can be a potential candidate for future low cost and large area PSCs producing.

  6. Plate-specific gain map correction for the improvement of detective quantum efficiency in computed radiography

    Energy Technology Data Exchange (ETDEWEB)

    Schnell, Erich A.; Samei, Ehsan; Dobbins, James T. [Ravin Advanced Imaging Laboratories, Department of Radiology and Medical Physics Graduate Program, Duke University Medical Center, North Carolina 27705 (United States); Ravin Advanced Imaging Laboratories, Departments of Radiology, Biomedical Engineering, and Physics, and Medical Physics Graduate Program, Duke University Medical Center, North Carolina 27705 (United States)

    2012-03-15

    Purpose: The purpose of this work is to improve the noise power spectrum (NPS), and thus the detective quantum efficiency (DQE), of computed radiography (CR) images by correcting for spatial gain variations specific to individual imaging plates. CR devices have not traditionally employed gain-map corrections, unlike the case with flat-panel detectors, because of the multiplicity of plates used with each reader. The lack of gain-map correction has limited the DQE(f) at higher exposures with CR. This current work describes a feasible solution to generating plate-specific gain maps. Methods: Ten high-exposure open field images were taken with an RQA5 spectrum, using a sixth generation CR plate suspended in air without a cassette. Image values were converted to exposure, the plates registered using fiducial dots on the plate, the ten images averaged, and then high-pass filtered to remove low frequency contributions from field inhomogeneity. A gain-map was then produced by converting all pixel values in the average into fractions with mean of one. The resultant gain-map of the plate was used to normalize subsequent single images to correct for spatial gain fluctuation. To validate performance, the normalized NPS (NNPS) for all images was calculated both with and without the gain-map correction. Variations in the quality of correction due to exposure levels, beam voltage/spectrum, CR reader used, and registration were investigated. Results: The NNPS with plate-specific gain-map correction showed improvement over the noncorrected case over the range of frequencies from 0.15 to 2.5 mm{sup -1}. At high exposure (40 mR), NNPS was 50%-90% better with gain-map correction than without. A small further improvement in NNPS was seen from carefully registering the gain-map with subsequent images using small fiducial dots, because of slight misregistration during scanning. Further improvement was seen in the NNPS from scaling the gain map about the mean to account for different beam

  7. Plate-specific gain map correction for the improvement of detective quantum efficiency in computed radiography.

    Science.gov (United States)

    Schnell, Erich A; Samei, Ehsan; Dobbins, James T

    2012-03-01

    The purpose of this work is to improve the noise power spectrum (NPS), and thus the detective quantum efficiency (DQE), of computed radiography (CR) images by correcting for spatial gain variations specific to individual imaging plates. CR devices have not traditionally employed gain-map corrections, unlike the case with flat-panel detectors, because of the multiplicity of plates used with each reader. The lack of gain-map correction has limited the DQE(f) at higher exposures with CR. This current work describes a feasible solution to generating plate-specific gain maps. Ten high-exposure open field images were taken with an RQA5 spectrum, using a sixth generation CR plate suspended in air without a cassette. Image values were converted to exposure, the plates registered using fiducial dots on the plate, the ten images averaged, and then high-pass filtered to remove low frequency contributions from field inhomogeneity. A gain-map was then produced by converting all pixel values in the average into fractions with mean of one. The resultant gain-map of the plate was used to normalize subsequent single images to correct for spatial gain fluctuation. To validate performance, the normalized NPS (NNPS) for all images was calculated both with and without the gain-map correction. Variations in the quality of correction due to exposure levels, beam voltage/spectrum, CR reader used, and registration were investigated. The NNPS with plate-specific gain-map correction showed improvement over the noncorrected case over the range of frequencies from 0.15 to 2.5 mm(-1). At high exposure (40 mR), NNPS was 50%-90% better with gain-map correction than without. A small further improvement in NNPS was seen from carefully registering the gain-map with subsequent images using small fiducial dots, because of slight misregistration during scanning. Further improvement was seen in the NNPS from scaling the gain map about the mean to account for different beam spectra. This study

  8. Efficient estimators for quantum instanton evaluation of the kinetic isotope effects: application to the intramolecular hydrogen transfer in pentadiene.

    Science.gov (United States)

    Vanícek, Jirí; Miller, William H

    2007-09-21

    The quantum instanton approximation is used to compute kinetic isotope effects for intramolecular hydrogen transfer in cis-1,3-pentadiene. Due to the importance of skeleton motions, this system with 13 atoms is a simple prototype for hydrogen transfer in enzymatic reactions. The calculation is carried out using thermodynamic integration with respect to the mass of the isotopes and a path integral Monte Carlo evaluation of relevant thermodynamic quantities. Efficient "virial" estimators are derived for the logarithmic derivatives of the partition function and the delta-delta correlation functions. These estimators require significantly fewer Monte Carlo samples since their statistical error does not increase with the number of discrete time slices in the path integral. The calculation treats all 39 degrees of freedom quantum mechanically and uses an empirical valence bond potential based on a molecular mechanics force field.

  9. Efficiency droop alleviation in blue light emitting diodes using the InGaN/GaN triangular-shaped quantum well

    Institute of Scientific and Technical Information of China (English)

    Chen Zhao; Hu Chen Wei-Hua; Xiao-Dong; Yang Wei; Liu Lei; Wan Cheng-Hao; Li Lei; He Yong-Fa; Liu Ning-Yang; Wang Lei; Li Din

    2012-01-01

    The InGaN/GaN blue light emitting diode (LED) is numerically investigated using a triangular-shaped quantum well model,which involves analysis on its energy band,carrier concentration,overlap of electron and hole wave functions,radiative recombination rate,and internal quantum efficiency.The simulation results reveal that the InGaN/GaN blue light emitting diode with triangular quantum wells exhibits a higher radiative recombination rate than the conventional light emitting diode with rectangular quantum wells due to the enhanced overlap of electron and hole wave functions (above 90%) under the polarization field.Consequently,the efficiency droop is only 18% in the light emitting diode with triangular-shaped quantum wells,which is three times lower than that in a conventional LED.

  10. Hardware-Efficient and Fully Autonomous Quantum Error Correction in Superconducting Circuits

    Science.gov (United States)

    Kapit, Eliot

    2016-04-01

    Superconducting qubits are among the most promising platforms for building a quantum computer. However, individual qubit coherence times are not far past the scalability threshold for quantum error correction, meaning that millions of physical devices would be required to construct a useful quantum computer. Consequently, further increases in coherence time are very desirable. In this Letter, we blueprint a simple circuit consisting of two transmon qubits and two additional lossy qubits or resonators, which is passively protected against all single-qubit quantum error channels through a combination of continuous driving and engineered dissipation. Photon losses are rapidly corrected through two-photon drive fields implemented with driven superconducting quantum interference device couplings, and dephasing from random potential fluctuations is heavily suppressed by the drive fields used to implement the multiqubit Hamiltonian. Comparing our theoretical model to published noise estimates from recent experiments on flux and transmon qubits, we find that logical state coherence could be improved by a factor of 40 or more compared to the individual qubit T1 and T2 using this technique. We thus demonstrate that there is substantial headroom for improving the coherence of modern superconducting qubits with a fairly modest increase in device complexity.

  11. Quantum-dot based ultrafast photoconductive antennae for efficient THz radiation

    Science.gov (United States)

    Gorodetsky, Andrei; Bazieva, Natalia; Rafailov, Edik U.

    2016-03-01

    Here we overview our work on quantum dot based THz photoconductive antennae, capable of being pumped at very high optical intensities of higher than 1W optical mean power, i.e. about 50 times higher than the conventional LT-GaAs based antennae. Apart from high thermal tolerance, defect-free GaAs crystal layers in an InAs:GaAs quantum dot structure allow high carrier mobility and ultra-short photo carrier lifetimes simultaneously. Thus, they combine the advantages and lacking the disadvantages of GaAs and LT-GaAs, which are the most popular materials so far, and thus can be used for both CW and pulsed THz generation. By changing quantum dot size, composition, density of dots and number of quantum dot layers, the optoelectronic properties of the overall structure can be set over a reasonable range-compact semiconductor pump lasers that operate at wavelengths in the region of 1.0 μm to 1.3 μm can be used. InAs:GaAs quantum dot-based antennae samples show no saturation in pulsed THz generation for all average pump powers up to 1W focused into 30 μm spot. Generated THz power is super-linearly proportional to laser pump power. The generated THz spectrum depends on antenna design and can cover from 150 GHz up to 1.5 THz.

  12. Hardware-Efficient and Fully Autonomous Quantum Error Correction in Superconducting Circuits.

    Science.gov (United States)

    Kapit, Eliot

    2016-04-15

    Superconducting qubits are among the most promising platforms for building a quantum computer. However, individual qubit coherence times are not far past the scalability threshold for quantum error correction, meaning that millions of physical devices would be required to construct a useful quantum computer. Consequently, further increases in coherence time are very desirable. In this Letter, we blueprint a simple circuit consisting of two transmon qubits and two additional lossy qubits or resonators, which is passively protected against all single-qubit quantum error channels through a combination of continuous driving and engineered dissipation. Photon losses are rapidly corrected through two-photon drive fields implemented with driven superconducting quantum interference device couplings, and dephasing from random potential fluctuations is heavily suppressed by the drive fields used to implement the multiqubit Hamiltonian. Comparing our theoretical model to published noise estimates from recent experiments on flux and transmon qubits, we find that logical state coherence could be improved by a factor of 40 or more compared to the individual qubit T_{1} and T_{2} using this technique. We thus demonstrate that there is substantial headroom for improving the coherence of modern superconducting qubits with a fairly modest increase in device complexity.

  13. Nanometer-scale monitoring of quantum-confined Stark effect and emission efficiency droop in multiple GaN/AlN quantum disks in nanowires

    Science.gov (United States)

    Zagonel, L. F.; Tizei, L. H. G.; Vitiello, G. Z.; Jacopin, G.; Rigutti, L.; Tchernycheva, M.; Julien, F. H.; Songmuang, R.; Ostasevicius, T.; de la Peña, F.; Ducati, C.; Midgley, P. A.; Kociak, M.

    2016-05-01

    We report on a detailed study of the intensity dependent optical properties of individual GaN/AlN quantum disks (QDisks) embedded into GaN nanowires (NW). The structural and optical properties of the QDisks were probed by high spatial resolution cathodoluminescence (CL) in a scanning transmission electron microscope (STEM). By exciting the QDisks with a nanometric electron beam at currents spanning over three orders of magnitude, strong nonlinearities (energy shifts) in the light emission are observed. In particular, we find that the amount of energy shift depends on the emission rate and on the QDisk morphology (size, position along the NW and shell thickness). For thick QDisks (>4 nm), the QDisk emission energy is observed to blueshift with the increase of the emission intensity. This is interpreted as a consequence of the increase of carriers density excited by the incident electron beam inside the QDisks, which screens the internal electric field and thus reduces the quantum confined Stark effect (QCSE) present in these QDisks. For thinner QDisks (current threshold above which the energy shifts, marking the transition from unscreened to partially screened QCSE. From the threshold value we estimate the lifetime in the unscreened regime. These observations suggest that, counterintuitively, electrons of high energy can behave ultimately as single electron-hole pair generators. In addition, when we increase the current from 1 to 10 pA the light emission efficiency drops by more than one order of magnitude. This reduction of the emission efficiency is a manifestation of the "efficiency droop" as observed in nitride-based 2D light emitting diodes, a phenomenon tentatively attributed to the Auger effect.

  14. Emulsion Synthesis of Size-Tunable CH3NH3PbBr3 Quantum Dots: An Alternative Route toward Efficient Light-Emitting Diodes.

    Science.gov (United States)

    Huang, Hailong; Zhao, Fangchao; Liu, Lige; Zhang, Feng; Wu, Xian-gang; Shi, Lijie; Zou, Bingsuo; Pei, Qibing; Zhong, Haizheng

    2015-12-30

    We report a facile nonaqueous emulsion synthesis of colloidal halide perovskite quantum dots by controlled addition of a demulsifier into an emulsion of precursors. The size of resulting CH3NH3PbBr3 quantum dots can be tuned from 2 to 8 nm by varying the amount of demulsifier. Moreover, this emulsion synthesis also allows the purification of these quantum dots by precipitation from the colloidal solution and obtains solid-state powder which can be redissolved for thin film coating and device fabrication. The photoluminescence quantum yields of the quantum dots is generally in the range of 80-92%, and can be well-preserved after purification (∼80%). Green light-emitting diodes fabricated comprising a spin-cast layer of the colloidal CH3NH3PbBr3 quantum dots exhibited maximum current efficiency of 4.5 cd/A, power efficiency of 3.5 lm/W, and external quantum efficiency of 1.1%. This provides an alternative route toward high efficient solution-processed perovskite-based light-emitting diodes. In addition, the emulsion synthesis is versatile and can be extended for the fabrication of inorganic halide perovskite colloidal CsPbBr3 nanocrystals.

  15. The influence of sodium in Cu(In,Ga)Se{sub 2} solar cells investigated by quantum efficiency measurements

    Energy Technology Data Exchange (ETDEWEB)

    Puttnins, Stefan; Daume, Felix [Solarion AG, Ostende 5, 04288 Leipzig (Germany); Institut fuer Experimentelle Physik II, Universitaet Leipzig, Linnestr. 5, 04103 Leipzig (Germany); Zachmann, Hendrik; Rahm, Andreas [Solarion AG, Ostende 5, 04288 Leipzig (Germany); Grundmann, Marius [Institut fuer Experimentelle Physik II, Universitaet Leipzig, Linnestr. 5, 04103 Leipzig (Germany)

    2011-07-01

    Thin film solar cells based on Cu(In,Ga)Se{sub 2} (CIGSe) absorbers can be deposited on flexible plastic foils reaching efficiencies up to 17.6 %. The addition of sodium plays a key role for enhancing CIGSe solar cell perfomance. As polyimide is a sodium free substrate (in contrast to soda-lime glass) extrinsic incorporation of sodium is indispensable to achieve high efficiencies. The aim of this work is to analyze the influence of different sodium contents on photocurrent and defect characteristics by quantum efficiency (QE) measurements. We show that the sodium content influences the CIGSe bandgap, carrier collection in the long wavelength region of the QE spectra and the Urbach energy as a measure of structural disorder. Furthermore, we show how luminescence spectra can be calculated from QE data and how the sodium content affects peak intensities and energetic peak positions in those spectra.

  16. Si Hybrid Solar Cells with 13% Efficiency via Concurrent Improvement in Optical and Electrical Properties by Employing Graphene Quantum Dots

    KAUST Repository

    Tsai, Meng Lin

    2015-12-18

    By employing graphene quantum dots (GQDs) in PEDOT:PSS, we have achieved an efficiency of 13.22% in Si/PEDOT:PSS hybrid solar cells. The efficiency enhancement is based on concurrent improvement in optical and electrical properties by the photon downconversion process and the improved conductivity of PEDOT:PSS via appropriate incorporation of GQDs. After introducing GQDs into PEDOT:PSS, the short circuit current and the fill factor of rear-contact optimized hybrid cells are increased from 32.11 to 36.26 mA/cm and 62.85% to 63.87%, respectively. The organic-inorganic hybrid solar cell obtained herein holds the promise for developing photon-managing, low-cost, and highly efficient photovoltaic devices.

  17. Improved Time-Efficient Output-Sensitive Quantum Algorithms for Boolean Matrix Multiplication

    CERN Document Server

    Gall, François Le

    2012-01-01

    A quantum algorithm that computes the product of two n x n Boolean matrices using O(nL^{1/2}) queries, where L is the number of non-zero entries in the product, has recently been constructed by Jeffery, Kothari and Magniez (arXiv:1112.5855). In this paper we build on these ideas to show that there exists a quantum algorithm for the same problem with time complexity O(nL^{1/2} + Ln^{1/2}). This improves the previous output-sensitive quantum algorithms for Boolean matrix multiplication in the time complexity setting by Buhrman and Spalek (SODA'06) and Le Gall (SODA'12).

  18. Step-taper active-region quantum cascade lasers for carrier-leakage suppression and high internal differential efficiency

    Science.gov (United States)

    Kirch, J. D.; Chang, C.-C.; Boyle, C.; Mawst, L. J.; Lindberg, D.; Earles, T.; Botez, D.

    2016-03-01

    By stepwise tapering both the barrier heights and quantum-well depths in the active regions of 8.7 μm- and 8.4 μm-emitting quantum cascade lasers (QCLs) virtually complete carrier-leakage suppression is achieved, as evidenced by high values for both the threshold-current characteristic temperature coefficient T0 (283 K and 242 K) and the slope-efficiency characteristic temperature coefficient T1 (561 K and 279 K), over the 20-60 °C heatsink-temperature range, for low- and high-doped devices, respectively. Such high values are obtained while the threshold-current density is kept relatively low for 35-period, low- and high-doped devices: 1.58 kA/cm2 and 1.88 kA/cm2, respectively. In addition, due to resonant extraction from the lower laser level, high differential-transition-efficiency values (89-90%) are obtained. In turn, the slope-efficiency for 3 mm-long, 35-period high-reflectivity (HR)-coated devices are: 1.15-1.23 W/A; that is, 30- 40 % higher than for same-geometry and similar-doping conventional 8-9 μm-emitting QCLs. As a result of both efficient carrier-leakage suppression as well as fast and efficient carrier extraction, the values for the internal differential efficiency are found to be ≍ 86%, by comparison to typical values in the 58-67 % range for conventional QCLs emitting in the 7-11 μm wavelength range.

  19. Efficient, High-Speed, Monolithic Optoelectronic Circuits Using Quantum- Confined Structures

    Science.gov (United States)

    1991-07-25

    made to optimize the ridge-waveguide laser fabrication process by working on GaAs and In0.2Ga0.sAs single quantum- laser monitoring and polyimidc...with and without a SSL active layer. Because the SSL laser samples are precious, a special effort has been made to optimize the ridge-waveguide laser ... fabrication process by working on GaAs and Ino.2Ga0.sAs single quantum- 20 well SCH structures. It is found that the choice among SiQz, SixNy and

  20. Very high efficiency photovoltaic cells based on fully organic multiple quantum wells. Quarterly technical progress report, 15 February 1995--15 May 1995

    Energy Technology Data Exchange (ETDEWEB)

    Forrest, S R [Princeton Univ., NJ (United States)

    1997-03-01

    The principal project objective is to demonstrate relatively high solar conversion efficiency using extremely low-cost, thin-film technology based on crystalline organic multiple quantum well (MQW) photovoltaic cells. The authors base their work on recent observations both in the laboratory and elsewhere that have indicated the quantum efficiency of organic photoconductors based on vacuum-deposited thin films can be increased by at least two orders of magnitude (to at least 10%) if the organic films are grown in a highly ordered manner, and if organic multiple quantum wells are used in the absorption region. The authors are investigating the physical origin of this phenomenon, and they are growing thin-film MQW cells that demonstrate relatively high quantum efficiencies to determine the practicality of crystalline organic thin-film cells for solar power applications. The investigations are based on a unique, ultrahigh-vacuum organic molecular beam deposition system in the laboratory.

  1. Solvothermal synthesis of InP quantum dots and their enhanced luminescent efficiency by post-synthetic treatments.

    Science.gov (United States)

    Byun, Ho-June; Lee, Ju Chul; Yang, Heesun

    2011-03-01

    InP quantum dots (QDs) were solvothermally synthesized by using a greener phosphorus source of P(N(CH(3))(2))(3) instead of highly toxic P(TMS)(3) widely used, and subsequently subjected to a size-sorting processing. While as-grown QDs showed an undetectably low emission intensity, post-synthetic treatments such as photo-etching, photo-radiation, and photo-assisted ZnS shell coating gave rise to a substantial increase in emission efficiency due to the effective removal and passivation of surface states. The emission efficiency of the photo-etched QDs was further enhanced by a consecutive UV photo-radiation, attributable to the photo-oxidation at QD surface. Furthermore, a relatively thick ZnS shell on the surface of InP QDs that were surface-modified with hydrophilic ligands beforehand was photochemically generated in an aqueous solution at room temperature. The resulting InP/ZnS core/shell QDs, emitting from blue to red wavelengths, were more efficient than the above photo-treated InP QDs, and their luminescent properties (emission bandwidth and quantum yield) were comparable to those of InP QDs synthesized with P(TMS)(3). Structural, size, and compositional analyses on InP/ZnS QDs were also conducted to elucidate their core/shell structure.

  2. Efficient fiber-coupled single-photon source based on quantum dots in a photonic-crystal waveguide

    CERN Document Server

    Daveau, Raphaël S; Pregnolato, Tommaso; Liu, Jin; Lee, Eun H; Song, Jin D; Verma, Varun; Mirin, Richard; Nam, Sae Woo; Midolo, Leonardo; Stobbe, Søren; Srinivasan, Kartik; Lodahl, Peter

    2016-01-01

    Many photonic quantum information processing applications would benefit from a high brightness, fiber-coupled source of triggered single photons. Here, we present a fiber-coupled photonic-crystal waveguide single-photon source relying on evanescent coupling of the light field from a tapered out-coupler to an optical fiber. A two-step approach is taken where the performance of the tapered out-coupler is recorded first on an independent device containing an on-chip reflector. Reflection measurements establish that the chip-to-fiber coupling efficiency exceeds 80 %. The detailed characterization of a high-efficiency photonic-crystal waveguide extended with a tapered out-coupling section is then performed. The corresponding overall single-photon source efficiency is 10.9 % $\\pm$ 2.3 %, which quantifies the success probability to prepare an exciton in the quantum dot, couple it out as a photon in the waveguide, and subsequently transfer it to the fiber. The applied out-coupling method is robust, stable over time, ...

  3. Internal quantum efficiency mapping analysis for a >20%-efficiency n-type bifacial solar cell with front-side emitter formed by BBr3 thermal diffusion

    Science.gov (United States)

    Simayi, Shalamujiang; Mochizuki, Toshimitsu; Kida, Yasuhiro; Shirasawa, Katsuhiko; Takato, Hidetaka

    2017-10-01

    This paper presents a large-area (239-cm2) high-efficiency n-type bifacial solar cell that is processed using tube-furnace thermal diffusion employing liquid sources BBr3 for the front-side boron emitter and POCl3 for the rear-side phosphorus back surface field (BSF). The SiN x /Al2O3 stack was applied to the front-side boron emitter as a passivation layer. Both the front and rear-side electrodes are obtained using screen-printed contacts with H-patterns. The resulting highest-efficiency solar cell has front- and rear-side efficiencies of 20.3 and 18.7%, respectively, while the corresponding bifaciality is up to 92%. Finally, the passivation quality of the SiN x /Al2O3 stack on the front-side boron emitter and rear-side phosphorus BSF is investigated and visualized by measuring the internal quantum efficiency mapping of the bifacial solar cell.

  4. Nonpolar and semipolar InGaN/GaN multiple-quantum-well solar cells with improved carrier collection efficiency

    Science.gov (United States)

    Huang, Xuanqi; Fu, Houqiang; Chen, Hong; Zhang, Xiaodong; Lu, Zhijian; Montes, Jossue; Iza, Michael; DenBaars, Steven P.; Nakamura, Shuji; Zhao, Yuji

    2017-04-01

    We demonstrate the nonpolar and semipolar InGaN/GaN multiple-quantum-well (MQW) solar cells grown on the nonpolar m-plane and semipolar ( 20 2 ¯ 1 ) plane bulk GaN substrates. The optical properties and photovoltaic performance of the nonpolar and semipolar InGaN solar cells were systematically studied, and the results were compared to the conventional polar c-plane devices. The absorption spectra, current density-voltage (J-V) characteristics, external quantum efficiency (EQE), and internal quantum efficiency (IQE) were measured for nonpolar m-plane, semipolar ( 20 2 ¯ 1 ) plane, and polar c-plane InGaN/GaN MQW solar cells. Nonpolar m-plane InGaN/GaN MQW solar cells showed the best performance across all devices, with a high open-circuit voltage of 2.32 V, a low bandgap-voltage offset of 0.59 V, and the highest EQE and IQE. In contrast, the polar c-plane device showed the lowest EQE despite the highest absorption spectra. This huge difference is attributed to the better carrier transport and collection on nonpolar m-plane devices due to the reduced polarization effects, which were further confirmed by bias-dependent EQE measurements and energy band diagram simulations. This study demonstrates the high potential of nonpolar and semipolar InGaN solar cells and can serve as guidance for the future design and fabrication of high efficiency III-nitride solar cells.

  5. Strongly coupled CdS/graphene quantum dots nanohybrids for highly efficient photocatalytic hydrogen evolution: unraveling the essential roles of graphene quantum dots

    KAUST Repository

    Lei, Yonggang

    2017-05-23

    It have been recognized that the coupling of graphene quantum dots (GQDs) with semiconductor photocatalysts endow the resulting nanocomposites with enhanced photocatalytic performances, however, the essential roles of GQDs have not been clearly revealed yet. Herein, we report that a high efficiency of the photocatalytic H2 evolution was achieved using strongly coupled nanohybrids of CdS with GQDs (CdS/GQDs) as visible-light-driven photocatalysts. CdS/GQDs nanohybrids were synthesized by a facile hydrothermal method in which the crystallization of CdS precursor and coupling of GQDs could be accomplished in one-step. GQDs are firmly decorated on the surface of CdS nanoparticles, forming “dot-on-particle” heterodimer structures. GQDs have no significant influence on the crystallite structure of CdS but render the nanohybrids with strong light absorption at the wavelength beyond the band edge of CdS. Under visible light irradiation (≥420nm), CdS/GQDs nanohybrids reach the highest H2 production rate of 95.4μmol·h−1, about 2.7 times higher than that of pure CdS nanoparticles, at GQDs content of 1.0wt %, and the apparent quantum efficiency (AQE) was determined to be 4.2% at 420nm. Incident light-wavelength dependent experiments reveal that the light absorption of CdS dominated the performance of nanohybrids, and the excess light absorption coming from GQDs hardly contributes to the observed higher activity. Photocurrent response, steady-state and time-resolved PL, and EIS measurements suggest that the high activity of CdS/GQDs is attributed predominantly to the graphene-like nature of GQDs, which can act as an efficient electron acceptor to induce an efficient charge separation. This work clearly reveals that GQDs mainly played a role of electron acceptor instead of a photosensitizer in enhancing the photocatalytic H2 evolution performances of CdS/GQDs nanohybrids, which offers a new insight to understand the essential roles of GQDs in semiconductor

  6. Measurement of Quantum Yield, Quantum Requirement, and Energetic Efficiency of the O2-Evolving System of Photosynthesis by a Simple Dye Reaction

    Science.gov (United States)

    Ros Barcelò, A.; Zapata, J. M.

    1996-11-01

    Photosynthesis is the conversion of absorbed radiant energy from sunlight into various forms of chemical energy by the chloroplasts of higher green plants. The overall process of photosynthesis consists of the oxidation of water (with the release of O2 as a product) and the reduction of CO2 to form carbohydrates. In the test tube electrons produced by the photolytic cleavage of H2) may be deviated from their true acceptor by inserting a suitable dye in the electron chain; i.e.; 2,6-dichlorophenol indophenol (DCPIP) (E'o = + 0.217 V), which is blue in the oxidized quinone form and which becomes colorless when reduced to the phenolic form. This dye-electrom acceptor also has the advantage that it accepts electroms directly from the quinone (Qa) electron-acceptor of the photosystem IIsupplied) of the O2-evolving system of photosynthesis. Although values for the quantum yield, the quantum requirement and the energetic efficiency calculated in the classroom laboratory differ widely from those expected theoretically, these calculations are useful for illustrating the transformation of light energy into chemical energy by the chloroplasts of green plants.

  7. Carrier Localization Effects in InGaN/GaN Multiple-Quantum-Wells LED Nanowires: Luminescence Quantum Efficiency Improvement and "Negative" Thermal Activation Energy.

    Science.gov (United States)

    Bao, Wei; Su, Zhicheng; Zheng, Changcheng; Ning, Jiqiang; Xu, Shijie

    2016-09-30

    Two-dimensional InGaN/GaN multiple-quantum-wells (MQW) LED structure was nanotextured into quasi-one-dimensional nanowires (NWs) with different average diameters with a combination approach of Ni nanoislands as mask + dry etching. Such nanotexturing bring out several appealing effects including deeper localization of carriers and significant improvement in quantum efficiency (e.g., from 4.76% of the planar MQW structure to 12.5% of the 160 nm MQW NWs) of light emission in the whole interested temperature range from 4 K to 300 K. With the aid of localized-state ensemble (LSE) luminescence model, the photoluminescence spectra of the samples are quantitatively interpreted in the entire temperature range. In terms of distinctive temperature dependence of photoluminescence from these samples, a concept of "negative" thermal activation energy is tentatively proposed for the MQW NWs samples. These findings could lead to a deeper insight into the physical nature of localization and luminescence mechanism of excitons in InGaN/GaN nanowires.

  8. Carrier Localization Effects in InGaN/GaN Multiple-Quantum-Wells LED Nanowires: Luminescence Quantum Efficiency Improvement and “Negative” Thermal Activation Energy

    Science.gov (United States)

    Bao, Wei; Su, Zhicheng; Zheng, Changcheng; Ning, Jiqiang; Xu, Shijie

    2016-09-01

    Two-dimensional InGaN/GaN multiple-quantum-wells (MQW) LED structure was nanotextured into quasi-one-dimensional nanowires (NWs) with different average diameters with a combination approach of Ni nanoislands as mask + dry etching. Such nanotexturing bring out several appealing effects including deeper localization of carriers and significant improvement in quantum efficiency (e.g., from 4.76% of the planar MQW structure to 12.5% of the 160 nm MQW NWs) of light emission in the whole interested temperature range from 4 K to 300 K. With the aid of localized-state ensemble (LSE) luminescence model, the photoluminescence spectra of the samples are quantitatively interpreted in the entire temperature range. In terms of distinctive temperature dependence of photoluminescence from these samples, a concept of “negative” thermal activation energy is tentatively proposed for the MQW NWs samples. These findings could lead to a deeper insight into the physical nature of localization and luminescence mechanism of excitons in InGaN/GaN nanowires.

  9. Carrier Localization Effects in InGaN/GaN Multiple-Quantum-Wells LED Nanowires: Luminescence Quantum Efficiency Improvement and “Negative” Thermal Activation Energy

    Science.gov (United States)

    Bao, Wei; Su, Zhicheng; Zheng, Changcheng; Ning, Jiqiang; Xu, Shijie

    2016-01-01

    Two-dimensional InGaN/GaN multiple-quantum-wells (MQW) LED structure was nanotextured into quasi-one-dimensional nanowires (NWs) with different average diameters with a combination approach of Ni nanoislands as mask + dry etching. Such nanotexturing bring out several appealing effects including deeper localization of carriers and significant improvement in quantum efficiency (e.g., from 4.76% of the planar MQW structure to 12.5% of the 160 nm MQW NWs) of light emission in the whole interested temperature range from 4 K to 300 K. With the aid of localized-state ensemble (LSE) luminescence model, the photoluminescence spectra of the samples are quantitatively interpreted in the entire temperature range. In terms of distinctive temperature dependence of photoluminescence from these samples, a concept of “negative” thermal activation energy is tentatively proposed for the MQW NWs samples. These findings could lead to a deeper insight into the physical nature of localization and luminescence mechanism of excitons in InGaN/GaN nanowires. PMID:27686154

  10. Highly Efficient Flexible Quantum Dot Solar Cells with Improved Electron Extraction Using MgZnO Nanocrystals.

    Science.gov (United States)

    Zhang, Xiaoliang; Santra, Pralay Kanti; Tian, Lei; Johansson, Malin B; Rensmo, Håkan; Johansson, Erik M J

    2017-08-22

    Colloidal quantum dot (CQD) solar cells have high potential for realizing an efficient and lightweight energy supply for flexible or wearable electronic devices. To achieve highly efficient and flexible CQD solar cells, the electron transport layer (ETL), extracting electrons from the CQD solid layer, needs to be processed at a low-temperature and should also suppress interfacial recombination. Herein, a highly stable MgZnO nanocrystal (MZO-NC) layer is reported for efficient flexible PbS CQD solar cells. Solar cells fabricated with MZO-NC ETL give a high power conversion efficiency (PCE) of 10.4% and 9.4%, on glass and flexible plastic substrates, respectively. The reported flexible CQD solar cell has the record efficiency to date of flexible CQD solar cells. Detailed theoretical simulations and extensive characterizations reveal that the MZO-NCs significantly enhance charge extraction from CQD solids and diminish the charge accumulation at the ETL/CQD interface, suppressing charge interfacial recombination. These important results suggest that the low-temperature processed MZO-NCs are very promising for use in efficient flexible solar cells or other flexible optoelectronic devices.

  11. Why can’t I measure the external quantum efficiency of the Ge subcell of my multijunction solar cell?

    Energy Technology Data Exchange (ETDEWEB)

    Barrigón, Enrique, E-mail: enrique.barrigon@ies-def.upm.es; Espinet-González, Pilar; Contreras, Yedileth; Rey-Stolle, Ignacio [Instituto de Energía Solar, Universidad Politécnica de Madrid ETSI de Telecomunicación, Avd. Complutense 30, 28040 Madrid (Spain)

    2015-09-28

    The measurement of the external quantum efficiency (EQE) of low bandgap subcells in a multijunction solar cell can be sometimes problematic. In particular, this paper describes a set of cases where the EQE of a Ge subcell in a conventional GaInP/GaInAs/Ge triple-junction solar cell cannot be fully measured. We describe the way to identify each case by tracing the I-V curve under the same light-bias conditions applied for the EQE measurement, together with the strategies that could be implemented to attain the best possible measurement of the EQE of the Ge subcell.

  12. Efficient Multiple Exciton Generation Observed in Colloidal PbSe Quantum Dots with Temporally and Spectrally Resolved Intraband Excitation

    KAUST Repository

    Ji, Minbiao

    2009-03-11

    We have spectrally resolved the intraband transient absorption of photogenerated excitons to quantify the exciton population dynamics in colloidal PbSe quantum dots (QDs). These measurements demonstrate that the spectral distribution, as well as the amplitude, of the transient spectrum depends on the number of excitons excited in a QD. To accurately quantify the average number of excitons per QD, the transient spectrum must be spectrally integrated. With spectral integration, we observe efficient multiple exciton generation In colloidal PbSe QDs. © 2009 American Chemical Society.

  13. Silicon Detector Arrays with Absolute Quantum Efficiency over 50% in the Far Ultraviolet for Single Photon Counting Applications

    CERN Document Server

    Nikzad, Shouleh; Greer, Frank; Jones, Todd; Jacquot, Blake; Monacos, Steve; Blacksberg, J; Hamden, Erika; Schiminovich, David; Martin, Chris; Morrissey, Patrick

    2011-01-01

    We have used Molecular Beam Epitaxy (MBE)-based delta doping technology to demonstrate near 100% internal quantum efficiency (QE) on silicon electron-multiplied Charge Coupled Devices (EMCCDs) for single photon counting detection applications. Furthermore, we have used precision techniques for depositing antireflection (AR) coatings by employing Atomic Layer Deposition (ALD) and demonstrated over 50% external QE in the far and near-ultraviolet in megapixel arrays. We have demonstrated that other device parameters such as dark current are unchanged after these processes. In this paper, we report on these results and briefly discuss the techniques and processes employed.

  14. Efficient, air-stable colloidal quantum dot solar cells encapsulated using atomic layer deposition of a nanolaminate barrier

    KAUST Repository

    Ip, Alexander H.

    2013-12-23

    Atomic layer deposition was used to encapsulate colloidal quantum dot solar cells. A nanolaminate layer consisting of alternating alumina and zirconia films provided a robust gas permeation barrier which prevented device performance degradation over a period of multiple weeks. Unencapsulated cells stored in ambient and nitrogen environments demonstrated significant performance losses over the same period. The encapsulated cell also exhibited stable performance under constant simulated solar illumination without filtration of harsh ultraviolet photons. This monolithically integrated thin film encapsulation method is promising for roll-to-roll processed high efficiency nanocrystal solar cells. © 2013 AIP Publishing LLC.

  15. A highly efficient noble metal free photocatalytic hydrogen evolution system containing MoP and CdS quantum dots

    Science.gov (United States)

    Yin, Shengming; Han, Jianyu; Zou, Yinjun; Zhou, Tianhua; Xu, Rong

    2016-07-01

    We report the construction of a highly efficient noble metal free photocatalytic hydrogen (H2) evolution system using CdS quantum dots as the light absorber and metallic MoP as the cocatalyst. MoP can be prepared by a facile temperature programmed reduction method and small clusters of MoP nanoparticles sized 10-30 nm were obtained by probe ultrasonication. The effect of synthesis conditions on the electrocatalytic and photocatalytic H2 evolution activity of MoP was investigated. The highest H2 evolution rate of 1100 μmol h-1 can be achieved by the optimized system under visible light (λ >= 420 nm), which is comparable to that when Pt was used as the cocatalyst. A high quantum efficiency of 45% is obtained at 460 nm irradiation.We report the construction of a highly efficient noble metal free photocatalytic hydrogen (H2) evolution system using CdS quantum dots as the light absorber and metallic MoP as the cocatalyst. MoP can be prepared by a facile temperature programmed reduction method and small clusters of MoP nanoparticles sized 10-30 nm were obtained by probe ultrasonication. The effect of synthesis conditions on the electrocatalytic and photocatalytic H2 evolution activity of MoP was investigated. The highest H2 evolution rate of 1100 μmol h-1 can be achieved by the optimized system under visible light (λ >= 420 nm), which is comparable to that when Pt was used as the cocatalyst. A high quantum efficiency of 45% is obtained at 460 nm irradiation. Electronic supplementary information (ESI) available: SEM image with EDS, XPS survey spectrum, XRD and TEM images of MoP samples prepared under different conditions; XRD, TEM, UV-vis and photoluminescence spectra of CdS QDs; H2 evolution activity comparison for different MoP/CdS samples; the effect of pH value on H2 evolution activity of a MoP/CdS system; the XPS spectrum of MoP/CdS after photoreaction; table of literature studies on H2 evolution activity by different noble metal free photocatalytic systems

  16. High-Efficiency and Air-Stable Perovskite Quantum Dots Light-Emitting Diodes with an All-Inorganic Heterostructure.

    Science.gov (United States)

    Shi, Zhifeng; Li, Ying; Zhang, Yuantao; Chen, Yongsheng; Li, Xinjian; Wu, Di; Xu, Tingting; Shan, Chongxin; Du, Guotong

    2017-01-11

    Perovskite light-emitting diodes (PeLEDs), because of its fundamental scientific importance and practical applications in the fields of low-cost light source or display applications, have drawn worldwide attention in recent years. However, PeLEDs available today suffer from a compromise in their emission efficiency and operation stability. In this study, we designed and fabricated a stacking all-inorganic multilayer structure by using inorganic perovskite CsPbBr3 quantum dots (QDs) as the emissive layer and inorganic n-type MgZnO and p-type MgNiO as the carrier injectors, respectively. Through energy band engineering of carrier injectors by Mg incorporation and their thickness optimization, PeLEDs with maximum luminance of 3809 cd/m(2), luminous efficiency of 2.25 cd/A, and external quantum efficiency of 2.39% have been realized, which are much better than most PeLEDs from CH3NH3PbBr3 films, and comparable with the highest results reported on CsPbBr3 QDs LEDs. More importantly, the unencapsulated PeLEDs in a continuous current mode demonstrate a remarkable operation stability against water and oxygen degradation. After a continuous operation for 10 h under a dc bias (10.0 V), nearly 80% of the original efficiency of the PeLEDs has been retained, greatly superior to reference and other previously reported devices constructed with conventional organic carrier injectors. Our results obtained open possibilities for the design and development of high-efficiency and air-stable PeLEDs that are not dependent on expensive and less-stable organic carrier injectors.

  17. An Efficient Quantum Jump Method for Coherent Energy Transfer Dynamics in Photosynthetic Systems under the Influence of Laser Fields

    CERN Document Server

    Ai, Qing; Jin, Bih-Yaw; Cheng, Yuan-Chung

    2014-01-01

    We present a non-Markovian quantum jump approach for simulating coherent energy transfer dynamics in molecular systems in the presence of laser fields. By combining a coherent modified Redfield theory (CMRT) and a non-Markovian quantum jump (NMQJ) method, this new approach inherits the broad-range validity from the CMRT and highly efficient propagation from the NMQJ. To implement NMQJ propagation of CMRT, we show that the CMRT master equation can be casted into a generalized Lindblad form. Moreover, we extend the NMQJ approach to treat time-dependent Hamiltonian, enabling the description of excitonic systems under coherent laser fields. As a benchmark of the validity of this new method, we show that the CMRT-NMQJ method accurately describes the energy transfer dynamics in a prototypical photosynthetic complex. Finally, we apply this new approach to simulate the quantum dynamics of a dimer system coherently excited to coupled single-excitation states under the influence of laser fields, which allows us to inve...

  18. The detective quantum efficiency of photon-counting x-ray detectors using cascaded-systems analyses

    Energy Technology Data Exchange (ETDEWEB)

    Tanguay, Jesse [Robarts Research Institute and Department of Medical Biophysics, Western University, London, Ontario N6A 5C1 (Canada); Yun, Seungman [Biomedical Engineering Program, Western University, London, Ontario N6A 5C1 (Canada); School of Mechanical Engineering, Pusan National University, Jangjeon-dong, Geumjeong-gu, Busan 609-735 (Korea, Republic of); Kim, Ho Kyung [School of Mechanical Engineering, Pusan National University, Jangjeon-dong, Geumjeong-gu, Busan 609-735 (Korea, Republic of); Cunningham, Ian A. [Robarts Research Institute, Department of Medical Biophysics, and Biomedical Engineering Program, Western University, London, Ontario N6A 5C1 (Canada)

    2013-04-15

    Purpose: Single-photon counting (SPC) x-ray imaging has the potential to improve image quality and enable new advanced energy-dependent methods. The purpose of this study is to extend cascaded-systems analyses (CSA) to the description of image quality and the detective quantum efficiency (DQE) of SPC systems. Methods: Point-process theory is used to develop a method of propagating the mean signal and Wiener noise-power spectrum through a thresholding stage (required to identify x-ray interaction events). The new transfer relationships are used to describe the zero-frequency DQE of a hypothetical SPC detector including the effects of stochastic conversion of incident photons to secondary quanta, secondary quantum sinks, additive noise, and threshold level. Theoretical results are compared with Monte Carlo calculations assuming the same detector model. Results: Under certain conditions, the CSA approach can be applied to SPC systems with the additional requirement of propagating the probability density function describing the total number of image-forming quanta through each stage of a cascaded model. Theoretical results including DQE show excellent agreement with Monte Carlo calculations under all conditions considered. Conclusions: Application of the CSA method shows that false counts due to additive electronic noise results in both a nonlinear image signal and increased image noise. There is a window of allowable threshold values to achieve a high DQE that depends on conversion gain, secondary quantum sinks, and additive noise.

  19. The detective quantum efficiency of photon-counting x-ray detectors using cascaded-systems analyses.

    Science.gov (United States)

    Tanguay, Jesse; Yun, Seungman; Kim, Ho Kyung; Cunningham, Ian A

    2013-04-01

    Single-photon counting (SPC) x-ray imaging has the potential to improve image quality and enable new advanced energy-dependent methods. The purpose of this study is to extend cascaded-systems analyses (CSA) to the description of image quality and the detective quantum efficiency (DQE) of SPC systems. Point-process theory is used to develop a method of propagating the mean signal and Wiener noise-power spectrum through a thresholding stage (required to identify x-ray interaction events). The new transfer relationships are used to describe the zero-frequency DQE of a hypothetical SPC detector including the effects of stochastic conversion of incident photons to secondary quanta, secondary quantum sinks, additive noise, and threshold level. Theoretical results are compared with Monte Carlo calculations assuming the same detector model. Under certain conditions, the CSA approach can be applied to SPC systems with the additional requirement of propagating the probability density function describing the total number of image-forming quanta through each stage of a cascaded model. Theoretical results including DQE show excellent agreement with Monte Carlo calculations under all conditions considered. Application of the CSA method shows that false counts due to additive electronic noise results in both a nonlinear image signal and increased image noise. There is a window of allowable threshold values to achieve a high DQE that depends on conversion gain, secondary quantum sinks, and additive noise.

  20. Multiphosphine-Oxide Hosts for Ultralow-Voltage-Driven True-Blue Thermally Activated Delayed Fluorescence Diodes with External Quantum Efficiency beyond 20.

    Science.gov (United States)

    Zhang, Jing; Ding, Dongxue; Wei, Ying; Han, Fuquan; Xu, Hui; Huang, Wei

    2016-01-20

    Highly efficient low-voltage-driven -true-blue thermally activated -delayed fluorescence diodes are realized through employing a tri-phosphine oxide host (2,2',4-tris(di(phenyl) -phosphoryl)-diphenylether (DPETPO)) with a record external quantum efficiency of 23.0% and the lowest onset voltage of 2.8 V to date.