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Sample records for pyrolytic oils

  1. Fuel properties of bituminous coal and pyrolytic oil mixture

    Science.gov (United States)

    Hamdan, Hazlin; Sharuddin, Munawar Zaman; Daud, Ahmad Rafizan Mohamad; Syed-Hassan, Syed Shatir A.

    2014-10-01

    Investigation on the thermal decomposition kinetics of coal-biooil slurry (CBS) fuel prepared at different ratios (100:0,70:30,60:40,0:100) was conducted using a Thermogravimetric Analyzer (TGA). The materials consisted of Clermont bituminous coal (Australia) and bio-oil (also known as pyrolytic oil) from the source of Empty Fruit Bunch (EFB) that was thermally converted by means of pyrolysis. Thermal decomposition of CBS fuel was performed in an inert atmosphere (50mL/min nitrogen) under non-isothermal conditions from room temperature to 1000°C at heating rate of 10°C/min. The apparent activation energy (Ea.) and pre-exponential factor (A) were calculated from the experimental results by using an Arrhenius-type kinetic model which first-order decomposition reaction was assumed. All kinetic parameters were tabulated based on the TG data obtained from the experiment. It was found that, the CBS fuel has higher reactivity than Clermont coal fuel during pyrolysis process, as the addition of pyrolytic oil will reduce the Ea values of the fuel. The thermal profiles of the mixtures showed potential trends that followed the characteristics of an ideal slurry fuel where high degradation rate is desirable. Among the mixture, the optimum fuel was found at the ratio of 60:40 of pyrolytic oil/coal mixtures with highest degradation rate. These findings may contribute to the development of a slurry fuel to be used in the vast existing conventional power plants.

  2. Pyrolysis of de-oiled seed cake of Jatropha Curcas and catalytic steam reforming of pyrolytic bio-oil to hydrogen.

    Science.gov (United States)

    Renny, Andrew; Santhosh, Viswanathan; Somkuwar, Nitin; Gokak, D T; Sharma, Pankaj; Bhargava, Sanjay

    2016-11-01

    The aim of this work was to study the pyrolysis of de-oiled seed cake of Jatropha Curcas and catalytic steam reforming of pyrolytic bio-oil to hydrogen. As per literature, presence of heavy nitrogenous and oxygenated compounds leads to catalyst deactivation. Here, an attempt has been made to tune pyrolytic reactions to optimize the N and O content of the pyrolytic bio-oil. Bio-oil conversion and hydrogen yield decreased as reaction progressed, which attributes to temporary loss of catalytic activity by blockage of catalyst pores by carbon deposition. Further, retention of steam reforming activity after repetitive steam activation suggests long-term catalyst usage.

  3. Pyrolytic Waste Plastic Oil and Its Diesel Blend: Fuel Characterization

    Science.gov (United States)

    Sultana, M.; Al-Mamun, M. R.; Hasan, M. R.

    2016-01-01

    The authors introduced waste plastic pyrolysis oil (WPPO) as an alternative fuel characterized in detail and compared with conventional diesel. High density polyethylene, HDPE, was pyrolyzed in a self-designed stainless steel laboratory reactor to produce useful fuel products. HDPE waste was completely pyrolyzed at 330–490°C for 2-3 hours to obtain solid residue, liquid fuel oil, and flammable gaseous hydrocarbon products. Comparison of the fuel properties to the petrodiesel fuel standards ASTM D 975 and EN 590 revealed that the synthetic product was within all specifications. Notably, the fuel properties included a kinematic viscosity (40°C) of 1.98 cSt, density of 0.75 gm/cc, sulphur content of 0.25 (wt%), and carbon residue of 0.5 (wt%), and high calorific value represented significant enhancements over those of conventional petroleum diesel fuel. PMID:27433168

  4. Pyrolytic Waste Plastic Oil and Its Diesel Blend: Fuel Characterization

    Directory of Open Access Journals (Sweden)

    M. Z. H. Khan

    2016-01-01

    Full Text Available The authors introduced waste plastic pyrolysis oil (WPPO as an alternative fuel characterized in detail and compared with conventional diesel. High density polyethylene, HDPE, was pyrolyzed in a self-designed stainless steel laboratory reactor to produce useful fuel products. HDPE waste was completely pyrolyzed at 330–490°C for 2-3 hours to obtain solid residue, liquid fuel oil, and flammable gaseous hydrocarbon products. Comparison of the fuel properties to the petrodiesel fuel standards ASTM D 975 and EN 590 revealed that the synthetic product was within all specifications. Notably, the fuel properties included a kinematic viscosity (40°C of 1.98 cSt, density of 0.75 gm/cc, sulphur content of 0.25 (wt%, and carbon residue of 0.5 (wt%, and high calorific value represented significant enhancements over those of conventional petroleum diesel fuel.

  5. The batch pyrolysis of tyre waste - fuel properties of the derived pyrolytic oil and overall plant economics

    Energy Technology Data Exchange (ETDEWEB)

    Williams, P.T.; Besler, S.; Taylor, D.T. (Leeds Univ. (United Kingdom). Dept. of Fuel and Energy)

    1993-01-01

    Pyrolysis of scrap tyres is currently receiving renewed attention, since the derived oils may be used directly as fuels or added to petroleum refinery feedstocks; they may also be an important source of refined chemicals. The derived gases are also useful as fuel and the solid char has the potential to be used either as smokeless fuel, carbon black or activated carbon. In this paper, halved and whole scrap tyres were pyrolysed in a commercial two tonne per day batch pyrolysis unit at furnace temperatures from 700 to 950[sup o]C. The proportion of derived products was dependent on pyrolysis conditions, with a maximum yield of 30 per cent oil. The fuel properties of the derived oils, including calorific value, flash point, carbon residue, viscosity, sulphur content, etc., were analysed and compared to refined petroleum products. In addition, the benzene, xylene, toluene, limonene and styrene concentration of the oils was determined to assess the potential of the oils as a source of chemical feedstocks. The oils were also analysed in terms of their chemical composition via liquid chromatography and Fourier transform infra-red spectroscopy and molecular mass range. The pyrolytic oils derived from tyres showed properties that were dependent on pyrolytic conditions and showed fuel properties comparable to those of petroleum products. (Author)

  6. Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic mechanical properties of natural rubber (NR/styrene-butadiene rubber (SBR blends

    Directory of Open Access Journals (Sweden)

    F. Karabork

    2016-01-01

    Full Text Available Pyrolytic carbon black (CBp and pyrolytic oil (Op made from used tires were used in natural rubber (NR/styrene-butadiene rubber (SBR blends. The effects of CBp and Op on the processing properties, the mechanical properties and the dynamic mechanical properties of the NR/SBR blends were investigated and compared with a control sample that was prepared with N550 and commercial process oil. It was found that the effect of CBp on the processing properties of the NR/SBR blends was similar to that of N550. With the increase of the CBp content, the curing properties of the NR/SBR blends changed little. The reinforcing effect of CBp was inferior to that of N550. With the increase of the CBp content, the tensile strength, tear strength and modulus at 100% elongation of the NR/SBR vulcanizates decreased significantly. Dynamic mechanical properties of the NR/SBR blends were also affected and all samples comprising CBp have a higher tan δ than control sample. It is suggested that the low surface area and high ash content of CBp strongly effects all of these property changes of the NR/SBR blends. The morphology and distribution of the carbon black particles are studied using a scanning electron microscope. It was also found that with the increase of the Op content, the properties of the NR/SBR blends were strongly affected due to the high sulfur content of Op, which produced a high crosslinking density.

  7. Characteristics of Waste Plastics Pyrolytic Oil and Its Applications as Alternative Fuel on Four Cylinder Diesel Engines

    Directory of Open Access Journals (Sweden)

    Nosal Nugroho Pratama

    2014-02-01

    Full Text Available Waste plastics recycling using pyrolysis method is not only able to decrease a number of environment pollutant but also able to produce economical and high quality hydrocarbon products. Two experiments were conducted to completely study Waste Plastic Pyrolytic Oil (WPPO characteristics and its applications.  First experiment investigated oil characteristics derived from pyrolysis process in two stages batch reactors: pyrolysis and catalytic reforming reactor, at maximum temperature 500oC and 450oC respectively. Waste Polyethylene (PE, Polypropylene (PP, Polystyrene (PS, Polyethylene Terepthalate (PET and others were used as raw material. Nitrogen flow rate at 0.8 l/minutes was used to increase oil weight percentage. Indonesian natural zeolite was used as catalyst. Then, second experiment was carried out on Diesel Engine Test Bed (DETB used blending of WPPO and Biodiesel fuel with a volume ratio of 1:9. This experiment was specifically conducted to study how much potency of blending of WPPO and biodiesel in diesel engine. The result of first experiment showed that the highest weight percentage of WPPO derived from mixture of PE waste (50%wt, PP waste (40%wt and PS waste (10%wt is 45.13%wt. The more weight percentage of PE in feedstock effected on the less weight percentage of WPPO, the more percentage of C12-C20 content in WPPO and the higher calorific value of WPPO. Characteristics of WPPO such as, Specific Gravity, Flash point, Pour Point, Kinematic Viscosity, Calorific value and percentage of C12-C20 showed interesting result that WPPO could be developed as alternative fuel on diesel fuel blending due to the proximity of their characteristics. Performance of diesel engine using blending of WPPO and biodiesel on second experiment gave good result so the WPPO will have great potency to be valuable alternative liquid fuel in future, especially on stationary diesel engine and transportation engine application.

  8. Comparison of the constituents of two jet engine lubricating oils and their volatile pyrolytic degradation products.

    Science.gov (United States)

    van Netten, C; Leung, V

    2000-03-01

    Leaking oil seals in jet engines, at locations prior to the compressor stage, can be a cause of smoke in the cabins of BAe-146 aircraft. Compressed combustion air is bled off to pressurize the cabin and to provide a source of fresh air. Bleed air is diverted from a location just prior to the combustion chamber at a temperature around 500 degrees C. To prevent oil breakdown products from entering the cabin air, catalytic converters have been used to clean the air. During an oil seal failure this device becomes overloaded and smoke is observed in the cabin. Some aircraft companies have removed the catalytic converters and claim an improvement in air quality. During an oil seal failure, however, the flight crew is potentially exposed to the thermal breakdown products of the engine oils. Because very little is known regarding the thermal breakdown products of jet engine lubrication oils, two commercially available oils were investigated under laboratory conditions at 525 degrees C to measure the release of CO, CO2,NO2, and HCN as well as volatiles which were analyzed using GC-Mass spectrometry in an attempt to see if the neurotoxic agents tricresyl phosphates (TCPs) and trimethyl propane phosphate (TMPP) would be present or formed. TMPP was not found in these experiments. Some CO2 was generated along with CO which reached levels in excess of 100 ppm. HCN and NO2 were not detected. GC compositions of the two bulk oils and their breakdown products were almost identical. The presence of TCPs was confirmed in the bulk oils and in the volatiles. Localized condensation in the ventilation ducts and filters in the air conditioning packs are likely the reason why the presence of TCPs has not been demonstrated in cabin air. It was recommended that this needed to be verified in aircraft.

  9. Pyrolytic oil of banana (Musa spp.) pseudo-stem via fast process

    Energy Technology Data Exchange (ETDEWEB)

    Abdullah, Nurhayati; Sulaiman, Fauziah; Taib, Rahmad Mohd [School of Physics, Universiti Sains Malaysia, 11800 USM Pulau Pinang (Malaysia); Miskam, Muhamad Azman [Science and Engineering Research Centre, Universiti Sains Malaysia, 14300 Nibong Tebal, Pulau Pinang (Malaysia)

    2015-04-24

    This study was an attempt to produce bio-oil from banana pseudo-stem, a waste of banana cultivation, using fast pyrolysis technology. The compositions were determined and the thermal degradation behaviour of the raw material was analyzed using Perkin-Elmer Simultaneous Thermal Analyzer (STA) 6000. A 300 g/h fluidized bed bench scale fast pyrolysis unit, assembled with double screw feeders and cyclones, operating at atmospheric pressure, was used to obtain the pyrolysis liquid. The study involves the impact of the following key variables; the reactor temperature in the range of 450–650 °C, and the residence time in the range of 1.00–3.00 s. The particle size was set at 224-400 µm. The properties of the liquid product were analyzed for calorific heating value, pH value, conductivity, water and char content. The basic functional groups of the compositions were also determined using FTIR. The properties of the liquid product were compared with other wood derived bio-oil. The pyrolysis liquids derived from banana pseudo-stem were found to be in an aqueous phase.

  10. Pyrolytic oil of banana (Musa spp.) pseudo-stem via fast process

    Science.gov (United States)

    Abdullah, Nurhayati; Sulaiman, Fauziah; Taib, Rahmad Mohd; Miskam, Muhamad Azman

    2015-04-01

    This study was an attempt to produce bio-oil from banana pseudo-stem, a waste of banana cultivation, using fast pyrolysis technology. The compositions were determined and the thermal degradation behaviour of the raw material was analyzed using Perkin-Elmer Simultaneous Thermal Analyzer.(STA) 6000. A 300 g/h fluidized bed bench scale fast pyrolysis unit, assembled with double screw feeders and cyclones, operating at atmospheric pressure, was used to obtain the pyrolysis liquid. The study involves the impact of the following key variables; the reactor temperature in the range of 450-650°C, and the residence time in the range of 1.00-3.00s. The particle size was set at 224-400µm. The properties of the liquid product were analyzed for calorific heating value, pH value, conductivity, water and char content. The basic functional groups of the compositions were also determined using FTIR. The properties of the liquid product were compared with other wood derived bio-oil. The pyrolysis liquids derived from banana pseudo-stem were found to be in an aqueous phase.

  11. Biochar potential evaluation of palm oil wastes through slow pyrolysis: Thermochemical characterization and pyrolytic kinetic studies.

    Science.gov (United States)

    Lee, Xin Jiat; Lee, Lai Yee; Gan, Suyin; Thangalazhy-Gopakumar, Suchithra; Ng, Hoon Kiat

    2017-03-22

    This research investigated the potential of palm kernel shell (PKS), empty fruit bunch (EFB) and palm oil sludge (POS), abundantly available agricultural wastes, as feedstock for biochar production by slow pyrolysis (50mLmin(-1) N2 at 500°C). Various characterization tests were performed to establish the thermochemical properties of the feedstocks and obtained biochars. PKS and EFB had higher lignin, volatiles, carbon and HHV, and lower ash than POS. The thermochemical conversion had enhanced the biofuel quality of PKS-char and EFB-char exhibiting increased HHV (26.18-27.50MJkg(-1)) and fixed carbon (53.78-59.92%), and decreased moisture (1.03-2.26%). The kinetics of pyrolysis were evaluated by thermogravimetry at different heating rates (10-40°C). The activation energies determined by Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa models were similar, and comparable with literature data. The findings implied that PKS and EFB are very promising sources for biochars synthesis, and the obtained chars possessed significant biofuel potential.

  12. PYROLYTIC CARBIDE DEVELOPMENT PROGRAM

    Science.gov (United States)

    and injector design changes were made to improve the quality of the carbide produced. Niobium carbide and tantalum carbide coated nozzles are described...Additional data for pyrolytic niobium carbide and hafnium carbide is also presented. (Author)

  13. 微波裂解制生物油技术研究进展%Production of Pyrolytic Oils Using Microwave

    Institute of Scientific and Technical Information of China (English)

    吴爽; 王鑫

    2012-01-01

    The production of pyrolytic oils using microwave,including the mechanism,the influence of parameters,analysis of product distribution and pyrolysis reactors are reviewed. Their application and developing trend were pointed out. The researches in recent literatures are mainly concerned with the combination of the microwave and catalytic cracking processing. Some continuous microwave reactors,such as vacuum piston flow reactor and rotative microwave reactor,was developed and used instead of the bench microwave reactor. The overall understanding of the technologies using microwave in biomass pyrolysis reaction would provide a further industrial development in the field of biomass to liquid fuel.%综述了微波热解作用机制、影响因素、产物分布分析、微波热解反应器以及生物质微波裂解制油技术研究现状和发展趋势.相比于传统热解,微波裂解生物油含有较少的杂质.生物质微波裂解最新发展多采用微波热解和催化裂解相结合的技术路线,热解装置以真空平推流和旋转锥等快速连续微波反应器代替间歇式微波炉.通过对生物质微波裂解技术的充分了解,有助于推动生物质制油产业化发展.

  14. Utilization of acetic acid-rich pyrolytic bio-oil by microalga Chlamydomonas reinhardtii: reducing bio-oil toxicity and enhancing algal toxicity tolerance.

    Science.gov (United States)

    Liang, Yi; Zhao, Xuefei; Chi, Zhanyou; Rover, Marjorie; Johnston, Patrick; Brown, Robert; Jarboe, Laura; Wen, Zhiyou

    2013-04-01

    This work was to utilize acetic acid contained in bio-oil for growth and lipid production of the microalga Chlamydomonas reinhardtii. The acetic acid-rich bio-oil fraction derived from fast pyrolysis of softwood contained 26% (w/w) acetic acid, formic acid, methanol, furfural, acetol, and phenolics as identified compounds, and 13% (w/w) unidentified compounds. Among those identified compounds, phenolics were most inhibitory to algal growth, followed by furfural and acetol. To enhance the fermentability of the bio-oil fraction, activated carbon was used to reduce the toxicity of the bio-oil, while metabolic evolution was used to enhance the toxicity tolerance of the microalgae. Combining activated carbon treatment and using evolved algal strain resulted in significant algal growth improvement. The results collectively showed that fast pyrolysis-fermentation process was a viable approach for converting biomass into fuels and chemicals. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Thermal Pyrolytic Graphite Enhanced Components

    Science.gov (United States)

    Hardesty, Robert E. (Inventor)

    2015-01-01

    A thermally conductive composite material, a thermal transfer device made of the material, and a method for making the material are disclosed. Apertures or depressions are formed in aluminum or aluminum alloy. Plugs are formed of thermal pyrolytic graphite. An amount of silicon sufficient for liquid interface diffusion bonding is applied, for example by vapor deposition or use of aluminum silicon alloy foil. The plugs are inserted in the apertures or depressions. Bonding energy is applied, for example by applying pressure and heat using a hot isostatic press. The thermal pyrolytic graphite, aluminum or aluminum alloy and silicon form a eutectic alloy. As a result, the plugs are bonded into the apertures or depressions. The composite material can be machined to produce finished devices such as the thermal transfer device. Thermally conductive planes of the thermal pyrolytic graphite plugs may be aligned in parallel to present a thermal conduction path.

  16. Using pyrolytic acid leaching as a pretreatment step in a biomass fast pyrolysis plant: process design and economic evaluation

    NARCIS (Netherlands)

    Oudenhoven, S.R.G; Ham, van der A.G.J.; Berg, van den H.; Westerhof, R.J.M.; Kersten, S.R.A.

    2016-01-01

    Removing alkali and alkaline earth metals (AAEMs) from biomass, with pyrolytic acids, before pyrolysis leads to increased organic oil and sugar yields. These pyrolytic acids are produced and concentrated within the pyrolysis process itself. The purpose of this paper was to evaluate under which condi

  17. Pyrolytic sugars from cellulosic biomass

    Science.gov (United States)

    Kuzhiyil, Najeeb

    phosphoric acids) and organic acids (formic and acetic acids) followed by analytical pyrolysis on a micropyrolyzer/GC/MS/FID system. It was found that sulfuric and phosphoric acids are very effective in passivating the AAEM thereby increasing the yield of anhydrosugars. An excellent correlation was discovered between the amount of acid required to obtain the maximum yield of anhydrosugars and the amount of AAEM contained in the biomass feedstock. In the micro-scale studies, up to 56% of the cellulose contained in the biomass was converted into anhydrosugars which is close to the 57% conversion obtained from pure cellulose pyrolysis. It is known that LG polymerization and subsequent charring occur at temperatures above 275°C depending on the vapor pressure of LG in the gas stream. A study of pyrolysis of acid-infused biomass feedstocks at various temperatures revealed that LG recovery is best at lower temperatures than the conventional pyrolysis temperature range of 450-500°C. Pyrolysis of acid-infused biomass failed in a continuous fluidized bed reactor due to clogging of the bed. The feedstock formed vitreous material along with the fluidizing sand that was formed from poor pyrolysis of lignin. However, more investigation of this phenomenon is a subject for future work. Pyrolysis experiments on an auger type reactor were successful in producing bio-oils with unprecedented amounts of sugars. Though there was increase in charring when compared to the control feedstock, pyrolysis of red oak infused with 0.4 wt% of sulfuric acid produced bio-oil with 18wt% of sugars. One of the four fractions of bio-oil collected contained most of the sugars, which shows significant potential for separating the sugars from bio-oil using simple means. This work points towards a new pathway for making advanced biofuels viz. upgrading pyrolytic sugars from biomass that could compete with enzymatic sugars from biomass.

  18. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    Energy Technology Data Exchange (ETDEWEB)

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

  19. Pyrolytic 3D Carbon Microelectrodes for Electrochemistry

    DEFF Research Database (Denmark)

    Hemanth, Suhith; Caviglia, Claudia; Amato, Letizia

    2016-01-01

    This work presents the fabrication and characterization of suspended three-dimensional (3D) pyrolytic carbon microelectrodes for electrochemical applications. For this purpose, an optimized process with multiple steps of UV photolithography with the negative tone photoresist SU-8 followed by pyro...

  20. Production of clean pyrolytic sugars for fermentation.

    Science.gov (United States)

    Rover, Marjorie R; Johnston, Patrick A; Jin, Tao; Smith, Ryan G; Brown, Robert C; Jarboe, Laura

    2014-06-01

    This study explores the separate recovery of sugars and phenolic oligomers produced during fast pyrolysis with the effective removal of contaminants from the separated pyrolytic sugars to produce a substrate suitable for fermentation without hydrolysis. The first two stages from a unique recovery system capture "heavy ends", mostly water-soluble sugars and water-insoluble phenolic oligomers. The differences in water solubility can be exploited to recover a sugar-rich aqueous phase and a phenolic-rich raffinate. Over 93 wt % of the sugars is removed in two water washes. These sugars contain contaminants such as low-molecular-weight acids, furans, and phenols that could inhibit successful fermentation. Detoxification methods were used to remove these contaminants from pyrolytic sugars. The optimal candidate is NaOH overliming, which results in maximum growth measurements with the use of ethanol-producing Escherichia coli.

  1. Suspended 3D pyrolytic carbon microelectrodes for electrochemistry

    DEFF Research Database (Denmark)

    Hemanth, Suhith; Caviglia, Claudia; Keller, Stephan Sylvest

    2017-01-01

    Carbon microelectrodes have a wide range of applications because of their unique material properties and biocompatibility. This work presents the fabrication and characterization of suspended pyrolytic carbon microstructures serving as three-dimensional (3D) carbon microelectrodes for electrochem...

  2. Characterization of the pyrolytic solid derived from used disposable diapers.

    Science.gov (United States)

    Oh, Taek-Keun; Shinogi, Yoshiyuki

    2013-01-01

    This paper confirms through physical and chemical analyses the possibility to reuse the solid pyrolytic residue derived from used disposable diapers (UDD), heated at different temperatures ranging from 500, 700 and 900 degrees C as a soil amendment. With an increasing pyrolytic temperature, the pH, electrical conductivity, available P2O5, exchangeable K+ and cation exchange capacity tended to increase; however, total-N and exchangeable Ca2+ and Mg2+ decreased. The pyrolytic diaper solid produced at 500 degrees C had a high volatile matter (60.22%) and low ash content (19.10%), which can negatively affect crop growth and productivity when added to soil. Heavy metal concentrations were less than the maximum allowable limits according to Japan standards. The surface of the pyrolytic diaper solid was coarse, porous and heterogeneous with higher temperatures. Hydrogen-containing functional groups, such as OH, C-H, N-H and CH2, decreased with increasing pyrolytic temperature. Based on these results, we concluded that the pyrolytic product derived from UDD at higher temperatures offers a potentially effective soil amendment option.

  3. Edge plane pyrolytic graphite electrodes in electroanalysis: an overview.

    Science.gov (United States)

    Banks, Craig E; Compton, Richard G

    2005-11-01

    The recent development, behavior and scope of edge plane pyrolytic graphite electrodes in electroanalysis are overviewed. Similarities to, and advantages, over multi-walled CNT modified electrodes are noted and the wide scope of applications, ranging through gas sensing, stripping voltammetry and biosensing, illustrated.

  4. Flame Retardant and Pyrolytic Behaviors of Polyamide 6/Montmorillonite Nanocomposite

    Institute of Scientific and Technical Information of China (English)

    LIU Zhi-guo; OU Yu-xiang; WU Jun-hao

    2005-01-01

    Na+-montmorillonite(Na+-MMT) was converted to organic montmorillonite(OMMT) using modifier which was synthesized at authors' laboratory. PA6/OMMT nanocomposite was prepared via in situ intercalative polymerization. The limiting oxygen index (LOI), UL 94V flame retardancy and thermal stability of PA6/OMMT using thermal gravity analysis (TGA) were measured. The Fourier transform infrared (FTIR) technique was used to analyze the pyrolytic residuum and the cone calorimeter (CONE) was applied to determine a number of combustion parameters which were closely related to fire safety, including heat release rate, mass loss rate, effective combustion heat, total heat release, specific extinction area and the time of ignition. In addition, the elemental composition of the surface pyrolytic residuum and the corresponding X-ray photoelectron spectroscopy (XPS) data were obtained, and the morphology of the residuum from CONE measurement was examined by scanning electron microscope (SEM).

  5. Friction and wear of metals in contact with pyrolytic graphite

    Science.gov (United States)

    Buckley, D. H.; Brainard, W. A.

    1975-01-01

    Sliding friction experiments were conducted with gold, iron, and tantalum single crystals sliding on prismatic and basal orientations of pyrolytic graphite in various environments, including vacuum, oxygen, water vapor, nitrogen, and hydrogen bromide. Surfaces were examined in the clean state and with various adsorbates present on the graphite surfaces. Auger and LEED spectroscopy, SEM, and EDXA were used to characterize the graphite surfaces. Results indicate that the prismatic and basal orientations do not contain nor do they chemisorb oxygen, water vapor, acetylene, or hydrogen bromide. All three metals exhibited higher friction on the prismatic than on the basal orientation and these metals transferred to the atomically clean prismatic orientation of pyrolytic graphite. No metal transfer to the graphite was observed in the presence of adsorbates at 760 torr. Ion bombardment of the graphite surface with nitrogen ions resulted in the adherence of nitrogen to the surface.

  6. Optical Properties of Pyrolytic Carbon Films Versus Graphite and Graphene.

    Science.gov (United States)

    Dovbeshko, Galyna I; Romanyuk, Volodymyr R; Pidgirnyi, Denys V; Cherepanov, Vsevolod V; Andreev, Eugene O; Levin, Vadim M; Kuzhir, Polina P; Kaplas, Tommi; Svirko, Yuri P

    2015-12-01

    We report a comparative study of optical properties of 5-20 nm thick pyrolytic carbon (PyC) films, graphite, and graphene. The complex dielectric permittivity of PyC is obtained by measuring polarization-sensitive reflectance and transmittance spectra of the PyC films deposited on silica substrate. The Lorentz-Drude model describes well the general features of the optical properties of PyC from 360 to 1100 nm. By comparing the obtained results with literature data for graphene and highly ordered pyrolytic graphite, we found that in the visible spectral range, the effective dielectric permittivity of the ultrathin PyC films are comparable with those of graphite and graphene.

  7. Thermal Performance of an Annealed Pyrolytic Graphite Solar Collector

    Science.gov (United States)

    Jaworske, Donald A.; Hornacek, Jennifer

    2002-01-01

    A solar collector having the combined properties of high solar absorptance, low infrared emittance, and high thermal conductivity is needed for applications where solar energy is to be absorbed and transported for use in minisatellites. Such a solar collector may be used with a low temperature differential heat engine to provide power or with a thermal bus for thermal switching applications. One concept being considered for the solar collector is an Al2O3 cermet coating applied to a thermal conductivity enhanced polished aluminum substrate. The cermet coating provides high solar absorptance and the polished aluminum provides low infrared emittance. Annealed pyrolytic graphite embedded in the aluminum substrate provides enhanced thermal conductivity. The as-measured thermal performance of an annealed pyrolytic graphite thermal conductivity enhanced polished aluminum solar collector, coated with a cermet coating, will be presented.

  8. A comparative study of bio-oils from pyrolysis of microalgae and oil seed waste in a fluidized bed.

    Science.gov (United States)

    Kim, Sung Won; Koo, Bon Seok; Lee, Dong Hyun

    2014-06-01

    The pyrolysis of Scenedesmus sp. and Jatropha seedshell cake (JSC) was investigated under similar operating condition in a fluidized bed reactor for comparison of pyrolytic behaviors from different species of lipids-containing biomass. Microalgae showed a narrower main peak in differential thermogravimetric curve compared to JSC due to different constituents. Pyrolysis liquid yields were similar; liquid's oil proportion of microalgae is higher than JSC. Microalgae bio-oil was characterized by similar carbon and hydrogen contents and higher H/C and O/C molar ratios compared to JSC due to compositional difference. The pyrolytic oils from microalgae and JSC contained more oxygen and nitrogen and less sulfur than petroleum and palm oils. The pyrolytic oils showed high yields of fatty oxygenates and nitrogenous compounds. The microalgae bio-oil features in high concentrations of aliphatic compounds, fatty acid alkyl ester, alcohols and nitriles. Microalgae showed potentials for alternative feedstock for green diesel, and commodity and valuable chemicals.

  9. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    Science.gov (United States)

    Sharp, D.J.; Armstrong, P.S.; Panitz, J.K.G.

    1998-03-17

    A solid electrolytic capacitor is described having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects. 2 figs.

  10. Aromatics extraction from pyrolytic sugars using ionic liquid to enhance sugar fermentability

    NARCIS (Netherlands)

    Li, X.; Luque-Moreno, L.C.; Oudenhoven, S.R.G; Rehmann, L.; Kersten, S.R.A.; Schuur, B.

    2016-01-01

    Fermentative bioethanol production from pyrolytic sugars was improved via aromatics removal by liquid–liquid extraction. As solvents, the ionic liquid (IL) trihexyltetradecylphosphonium dicyanamide (P666,14[N(CN)2]) and ethyl acetate (EA) were compared. Two pyrolytic sugar solutions were created fro

  11. Friction and transfer behavior of pyrolytic boron nitride in contact with various metals

    Science.gov (United States)

    Buckley, D. H.

    1976-01-01

    Sliding friction experiments were conducted with pyrolytic boron nitride in sliding contact with itself and various metals. Auger emission spectroscopy was used to monitor transfer of pyrolytic boron nitride to metals and metals to pyrolytic boron nitride. Results indicate that the friction coefficient for pyrolytic boron nitride in contact with metals can be related to the chemical activity of the metals and more particularly to the d valence bond character of the metal. Transfer was found to occur to all metals except silver and gold and the amount of transfer was less in the presence than in the absence of metal oxide. Friction was less for pyrolytic boron nitride in contact with a metal in air than in vacuum.

  12. Pyrolytic Treatment and Fertility Enhancement of Soils Contaminated with Heavy Hydrocarbons.

    Science.gov (United States)

    Vidonish, Julia E; Zygourakis, Kyriacos; Masiello, Caroline A; Gao, Xiaodong; Mathieu, Jacques; Alvarez, Pedro J J

    2016-03-01

    Pyrolysis of contaminated soils at 420 °C converted recalcitrant heavy hydrocarbons into "char" (a carbonaceous material similar to petroleum coke) and enhanced soil fertility. Pyrolytic treatment reduced total petroleum hydrocarbons (TPH) to below regulatory standards (typically hydrocarbons (PAHs) was not observed, with post-pyrolysis levels well below applicable standards. Plant growth studies showed a higher biomass production of Arabidopsis thaliana and Lactuca sativa (Simpson black-seeded lettuce) (80-900% heavier) in pyrolyzed soils than in contaminated or incinerated soils. Elemental analysis showed that pyrolyzed soils contained more carbon than incinerated soils (1.4-3.2% versus 0.3-0.4%). The stark color differences between pyrolyzed and incinerated soils suggest that the carbonaceous material produced via pyrolysis was dispersed in the form of a layer coating the soil particles. Overall, these results suggest that soil pyrolysis could be a viable thermal treatment to quickly remediate soils impacted by weathered oil while improving soil fertility, potentially enhancing revegetation.

  13. Pyrolytic carbon film deposit as an electrochemical interface.

    Directory of Open Access Journals (Sweden)

    M. Hadi

    2009-02-01

    Full Text Available A pyrolytic carbon (PC film was grown on planar substrate (graphite rods by chemical vapor deposition from gaseous feed of methane using a vertical hot-wall deposition reactor. Scanning electron microscopy was used to study the surface structure. The PC film was also characterized by cyclic voltammetry technique to evaluate the background current, stability and the electrochemical response using ascorbic acid, Co(phen32+/3+ and Fe(CN6 3-/4- redox couplesand compared to glassy carbon (GC electrode. High degree of electrochemical activity and the enhanced signal to background (S/B ratio demonstrated that the PC film might be an attractive electrode material for electroanalytical measurements.

  14. Low temperature transport properties of pyrolytic graphite sheet

    Science.gov (United States)

    Nakamura, Sachiko; Miyafuji, Daisuke; Fujii, Takenori; Matsui, Tomohiro; Fukuyama, Hiroshi

    2017-09-01

    We have made thermal and electrical transport measurements of uncompressed pyrolytic graphite sheet (uPGS), a mass-produced thin graphite sheet with various thicknesses between 10 and 100 μ m, at temperatures between 2 and 300 K. Compared to exfoliated graphite sheets like Grafoil, uPGS has much higher conductivities by an order of magnitude because of its high crystallinity confirmed by X-ray diffraction and Raman spectroscopy. This material is advantageous as a thermal link of light weight in a wide temperature range particularly above 60 K where the thermal conductivity is much higher than common thermal conductors such as copper and aluminum alloys. We also found a general relationship between thermal and electrical conductivities in graphite-based materials which have highly anisotropic conductivities. This would be useful to estimate thermal conductance of a cryogenic part made of these materials from its electrical conductance more easily measurable at low temperature.

  15. Xanthine Biosensor Based on Didodecyldimethylammonium Bromide Modified Pyrolytic Graphite Electrode

    Institute of Scientific and Technical Information of China (English)

    TANG,Ji-Lin(唐纪琳); HAN,Xiao-Jun(韩晓军); HUANG,Wei-Min(黄卫民); WANG,Er-Kang(汪尔康)

    2002-01-01

    The vesicle of didodecyldimethylammonium bromide (DDAB)which contained tetrathiafulvalene (TTF) was mixed with xanthine oxidase, and the mixture was cast on the pyrolytic graphite electrode. The lipid films were used to supply a biological environment resembling biomembrane on the surface of the electrode. TTF was used as a mediator because of its high electron-transfer efficiency. A novel xanthine biosensor based on cast DDAB film was developed. The effects of pH and operating potential were explored for optimum analytical performance by using the amperometric method. The response time of the biosensor was less than 10 s. The detection limit of the biosensor was 3.2 × 10-7 mol/L and the liner range was from 4 × 10-7 mol/L to 2.4 × 10-6 mol/L.

  16. Pyrolytic characteristics of burning residue of fire-retardant wood

    Institute of Scientific and Technical Information of China (English)

    ZHAO Guangjie; LUO Wensheng; Furuno T; REN Qiang; MA Erni

    2007-01-01

    In order to investigate the pyrolytic characteristics of the burning residue of fire-retardant wood,a multifunctional fire-resistance test oven aimed at simulating the course of a fire was used to burn fire-retardant wood and untreated wood.Samples at different distances from the combustion surface were obtained and a thennogravimetric analysis (TG) was applied to test the pyrolytic process of the burning residue in an atmosphere of nitrogen.The results showed that:1) there was little difference between fireretardant wood and its residue in the initial temperature of thermal degradation.The initial temperature of thermal degradation of the combustion layer in untreated wood was higher than that in the no burning wood sample;2) the temperature of the flame retardant in fire-retardant wood was 200℃ in the differential thermogravimetry (DTG).The peak belonging to the flame retardant tended to dissipate during the time of burning;3) for the burning residue of fire-retardant wood,the peak belonging to hemicellulose near 230℃ in the DTG disappeared and there was a gentle shoulder from 210 to 240℃;4) the temperature of the main peaks of the fireretardant wood and its burning residue in DTG was 100℃ lower than that of the untreated wood and its burning residue.The rate of weight loss also decreased sharply;5) the residual weight of fire-retardant wood at 600~C clearly increased compared with that of untreated wood.Residual weight of the burning residue increased markedly as the heating temperature increased when burning;6) there was a considerable difference with respect to the thermal degradation temperature of the no burning sample and the burning residue between fire-retardant wood and untreated wood.

  17. Pyrolytic transformation from polydihydrosilane to hydrogenated amorphous silicon film

    Energy Technology Data Exchange (ETDEWEB)

    Masuda, Takashi, E-mail: mtakashi@jaist.ac.jp [Japan Science and Technology Agency, ERATO, Shimoda Nano-Liquid Process Project, 2-13 Asahidai, Nomi, Ishikawa, 923-1211 (Japan); Matsuki, Yasuo [Japan Science and Technology Agency, ERATO, Shimoda Nano-Liquid Process Project, 2-13 Asahidai, Nomi, Ishikawa, 923-1211 (Japan); Yokkaichi Research Center, JSR Corporation, 100 Kawajiri-cho, Yokkaichi, Mie, 510-8552 (Japan); Shimoda, Tatsuya [Japan Science and Technology Agency, ERATO, Shimoda Nano-Liquid Process Project, 2-13 Asahidai, Nomi, Ishikawa, 923-1211 (Japan); School of Materials Science, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Nomi, Ishikawa, 923-1292 (Japan)

    2012-08-31

    The fabrication of thin film silicon devices based on solution processes rather than on conventional vacuum processes is of substantial interest since cost reductions may result. Using a solution process, we coated substrates with polydihydrosilane solution and studied the pyrolytic transformation of the material into hydrogenated amorphous silicon (a-Si:H). From thermal gravimetry and differential thermal analysis data a significant reduction in weight of the material and a construction of Si-Si bonds are concluded for the pyrolysis temperature T{sub p} = 270 to 360 Degree-Sign C. The appearance of amorphous silicon phonon bands in Raman spectra for films prepared at T{sub p} {>=} 330 Degree-Sign C suggests the construction of a three-dimensional amorphous silicon network. Films prepared at T{sub p} {>=} 360 Degree-Sign C exhibit a hydrogen content near 10 at.% and an optical gap near 1.6 eV similar to device-grade vacuum processed a-Si:H. However, the infrared microstructure factor, the spin density, and the photosensitivity require significant improvements. - Highlights: Black-Right-Pointing-Pointer We fabricate hydrogenated amorphous silicon (a-Si:H) films by a solution process. Black-Right-Pointing-Pointer The a-Si:H films are prepared by pyrolytic transformation in polysilane solution. Black-Right-Pointing-Pointer We investigate basic properties in relation to the pyrolysis temperature. Black-Right-Pointing-Pointer Raman spectra, hydrogen content, and optical gap are similar to device-grade a-Si:H. Black-Right-Pointing-Pointer Microstructure factor, spin density, and photoconductivity show poor quality.

  18. Oxidative desulfurization of tire pyrolysis oil

    OpenAIRE

    Ahmad Shahzad; Ahmad Muhammad Imran; Naeem Khawar; Humayun Muhammad; Sebt-E-Zaeem; Faheem Farrukh

    2016-01-01

    This paper presents a low cost method for the purification of oils obtained from the pyrolysis of used tires. Oxidative desulfurization is a promising route for purification of tire pyrolysis oils as hydro-desulfurization may not be affordable for small scale industries. Different additives and acids have been employed for the enhancement of properties of pyrolytic oils. The experimental conditions were kept identical throughout, i.e. atmospheric pressure a...

  19. Performance evaluation of household pyrolytic stove: Effect of outer air holes condition

    Science.gov (United States)

    Pradana, Yano Surya; Prasetya, Agus

    2017-03-01

    Renewable energy is the future energy for the substitution of the depleting fossil fuels. In Indonesia, biomass is one of promising renewable energy due to its abundant availability. Biomass can be converted into energy by thermochemical process, such as pyrolysis. In the implementation, pyrolysis can be applied in household cookstove, called pyrolytic stove. Pyrolytic stove will be proposed for people still cooking over an open biomass fire. This paper studied the pyrolysis of Indonesian teak using household pyrolytic stove. The effect of outer air holes on the performance of household pyrolytic stove was investigated. The increasing of cross section area of outer air holes effected on the higher of biomass combustion releasing energy for pyrolysis and cooking. Furthermore, the optimum outer air holes condition in the stove was fully open with the minimum of char product and the maximum of energy recovered for cooking.

  20. Determination of Micro U, Np, Pu by Highly Oriented Pyrolytic Graphite Pre-diffraction EDXRF

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Based on the prototype of Highly Oriented Pyrolytic Graphite Pre-Diffraction EDXRF, a new device was constructed after optimizing of hardware including high voltage supplier, detector, sample bracket, and software of data processing.

  1. The effect of heat treatment on the microstructure and diffusion of silver in pyrolytic carbon coatings

    OpenAIRE

    CANCINO TREJOA F.; SÁENZ PADILLA M.; LOPEZ HONORATO Eddie; CARVAJAL NUNEZ URSULA; BOSHOVEN Jacobus; Somers, Joseph

    2016-01-01

    It is well accepted that TRISO (tristructural isotropic) coated nuclear fuel particles are capable of retaining fission products up to 1600 ºC, however above this temperature fission products can diffuse through the pyrolytic carbon and silicon carbide coatings that act as the containment barriers in this fuel. Despite decades of research and development, little is known on the origin of this fuel temperature limit. Since pyrolytic carbon (PyC) coatings are an integral part of the safety of ...

  2. Chemical and Pyrolytic Thermogravimetric Characterization of Nigerian Bituminous Coals

    Directory of Open Access Journals (Sweden)

    Nyakuma Bemgba Bevan

    2016-12-01

    Full Text Available The discovery of new coal deposits in Nigeria presents solutions for nation’s energy crises and prospects for socioeconomic growth and sustainable development. Furthermore, the quest for sustainable energy to limit global warming, climate change, and environmental degradation has necessitated the exploration of alternatives using cleaner technologies such as coal pyrolysis. However, a lack of comprehensive data on physico-chemical and thermal properties of Nigerian coals has greatly limited their utilization. Therefore, the physico-chemical properties, rank (classification, and thermal decomposition profiles of two Nigerian bituminous coals – Afuze (AFZ and Shankodi-Jangwa (SKJ – were examined in this study. The results indicate that the coals contain high proportions of C, H, N, S, O and a sufficiently high heating value (HHV for energy conversion. The coal classification revealed that the Afuze (AFZ coal possesses a higher rank, maturity, and coal properties compared to the Shankodi-Jangwa (SKJ coal. A thermal analysis demonstrated that coal pyrolysis in both cases occurred in three stages; drying (30-200 °C, devolatilization (200-600 °C, and char decomposition (600-1000 °C. The results also indicated that pyrolysis at 1000 °C is not sufficient for complete pyrolysis. In general, the thermochemical and pyrolytic fuel properties indicate that the coal from both places can potentially be utilized for future clean energy applications.

  3. X-ray diffraction properties of highly oriented pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Freund, A.K.; Munkholm, A.; Brennan, S. [Stanford Synchrotron Radiation Lab., CA (United States)

    1996-12-31

    The x-ray diffraction properties of highly oriented pyrolytic graphite (HOPG) were studied for x-ray energies ranging from 4 to 60 keV. In particular, the secondary extinction thickness was determined by recording the peak and integrated reflectivity as a function of depth below the surface. The results showed that for the high quality material investigated a thickness of 200 to 300 {micro}m was sufficient to get 80% of the maximum reflectivity that is obtained for a very thick plate. Primary extinction was important for low energy and still persisted at higher energies. Inhomogeneities of the mosaic structure were observed, too, that make this material not a truly ideal mosaic monochromator crystal. However, quite high peak reflectivities between 35% and 58% were measured at FWHM of 0.25 to 0.45 degrees. A 200 {micro}m thick plate was then prepared and glued on a bending device to manufacture a monochromator or analyzer with variable curvature that works from flat down to a minimum bending radius of 10 cm. The successful tests of this device confirmed that HOPG plates much thinner than those commonly used as x-ray monochromators and analyzers still have high efficiency and can be curved to achieve dynamical focusing.

  4. Neutron transmission measurements of poly and pyrolytic graphite crystals

    Science.gov (United States)

    Adib, M.; Abbas, Y.; Abdel-Kawy, A.; Ashry, A.; Kilany, M.; Kenawy, M. A.

    The total neutron cross-section measurements of polycrystalline graphite have been carried out in a neutron wavelength from 0.04 to 0.78 nm. This work also presents the neutron transmission measurements of pyrolytic graphite (PG) crystal in a neutron wavelength band from 0.03 to 0.50 nm, at different orientations of the PG crystal with regard to the beam direction. The measurements were performed using three time-of-flight (TOF) spectrometers installed in front of three of the ET-RR-1 reactor horizontal channels. The average value of the coherent scattering amplitude for polycrystalline graphite was calculated and found to be bcoh = (6.61 ± 0.07) fm. The behaviour of neutron transmission through the PG crystal, while oriented at different angles with regard to the beam direction, shows dips at neutron wavelengths corresponding to the reflections from (hkl) planes of hexagonal graphite structure. The positions of the observed dips are found to be in good agreement with the calculated ones. It was also found that a 40 mm thick PG crystal is quite enough to reduce the second-order contamination of the neutron beam from 2.81 to 0.04, assuming that the incident neutrons have a Maxwell distribution with neutron gas temperature 330 K.

  5. Laser sputtering of highly oriented pyrolytic graphite at 248 nm

    Science.gov (United States)

    Krajnovich, Douglas J.

    1995-01-01

    The interaction of excimer laser pulses with a highly oriented pyrolytic graphite (HOPG) target has been studied. HOPG, a close approximation to single crystal graphite, was irradiated along a freshly cleaved basal plane in vacuum by pulses from a KrF excimer laser. The energy fluence was varied between 300-700 mJ/cm2, resulting in material removal rates of plasma effects are minimized. Time-of-flight distributions of the neutral carbon atoms and small carbon clusters were measured and inverted to obtain translational energy flux distributions and relative sputtering yields as a function of fluence. The translational energy distributions are remarkably close to Maxwell-Boltzmann distributions over most of the fluence range studied. However, the mean translational energies are far too high to reconcile with a simple thermal vaporization model. For example, the mean translational energy of C3, the most abundant species, increases from 1.1 eV at 305 mJ/cm2 to 31.7 eV at 715 mJ/cm2. Explanations are considered for this curious mix of thermal and non-thermal behavior. At the high end of our fluence range, the mean translational energies of C1, C2, C3 converge to a 1:2:3 ratio, indicating that the velocity distributions are almost identical. This particular result can be interpreted as a gas dynamic effect. Prolonged sputtering of the same target spot results in a falloff in the sputtering yield and the mean translational energies, but little change in the cluster size distribution. These effects are related to impurity induced topography formation on the target surface.

  6. A study on biocompatibility and bactericidal properties of pyrolytic carbon by silver ion implantation

    Energy Technology Data Exchange (ETDEWEB)

    Tang, H.Q. [College of Physics and Electronic Information Science, Tianjin Normal University, Tianjin 300074 (China); Liu, T. [College of Physics and Electronic Information Science, Tianjin Normal University, Tianjin 300074 (China); Liu, X. [Tianjin Urinary Surgery Institute, Tianjin 300211 (China); Gu, H.Q. [Tianjin Urinary Surgery Institute, Tianjin 300211 (China); Zhao, J. [College of Physics and Electronic Information Science, Tianjin Normal University, Tianjin 300074 (China)]. E-mail: jiezhao1943@126.com

    2007-02-15

    The biocompatibility and bactericidal properties of Ag{sup +}-implanted pyrolytic carbon were investigated by means of Staphylococcus aureus and Escherichia coli bacteria and some biocompatible experiments. The pyrolytic carbon samples were implanted by silver ions with the dose ranging from 5 x 10{sup 14} to 5 x 10{sup 18} ions/cm{sup 2} at an energy of 70 keV. The silver distribution in pyrolytic carbon was characterized by Rutherford Backscattering Spectrometry (RBS). The results show that the bactericidal rate for both S. aureus and E. coli increase with the ion dose when the silver ion dose is under the saturated dose of 5 x 10{sup 17} ions/cm{sup 2}. The bactericidal rate is over 97% when the ion dose exceeds that value. In comparison with the reference sample, Ag{sup +}-implanted pyrolytic carbon shows a good biocompatibility and without biotoxication by means of cytotoxicity, hemolysis and platelet tests. RBS analyses show that silver atoms penetrate into the sample surface and form a silver-rich surface region which plays an important role in killing bacteria. When the ion dose is not exceed 1 x 10{sup 16} ions/cm{sup 2}, the structure of Ag{sup +}-implanted pyrolytic carbon is kept unchanged maintaining the original biocompatibility.

  7. GROWTH CHARACTERS AND MODEL OF PYROLYTIC CARBON IN CHEMICAL VAPOR INFILTRATION PROCESS

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Chemical Vapor Infiltration (CVI) processes are the essential techniques for fabrication of high performance carbon-carbon composites. Based on the polarized light and scanning electron analysis, the authors study the micro-morphology and texture characteristics of pyrolytic carbon deposited in CVI process, as well as the growth behavior of pyrolytic carbon. The research shows that Rough Laminar (RL) texture has the hierarchical and self-similar structural features, which reflects the stage-growth and self-similar behavior during the growth course of pyrolytic carbon. According to the two growth features, a laminated growth model of pyrolytic carbon is proposed with the concept of Cone-Growth Units (CGU). The laminated growth model can provide a fine description for the growth course of RL pyrolytic carbon. The model indicates that formation, developing and combination of local high-order structures (such as CGU structures) are the essential factors for the growth of RL texture. Smooth Laminar (SL) texture and ISO carbon come into being with long-range orderliness and isotropy structure respectively, which no local high-orderliness intermediate involves in.

  8. Spray pyrolytic deposition of ZnO thin layers composed of low dimensional nanostructures

    Science.gov (United States)

    Junaid Bushiri, M.; Agouram, S.; Reig, C.; Martínez-Tomás, M. C.; Jimenez, J.; Hortelano, V.; Muñoz-Sanjosé, V.

    ZnO nanolayers composed of fine nanostructures have been successively grown by spray pyrolytic deposition at 300 ∘C over amorphous glass substrates. As deposited samples were analysed by scanning electron microscopy (SEM), showing a granular morphology with grain size in the limit of the microscope resolution. CL measurement shows a broad near band edge (3.4 eV) emission of ZnO in the UV region and the defect level emissions in the green region of the spectrum. The use of intermittent spray pyrolytic deposition is shown as an alternative to increase the homogeneity of the samples when temperatures near to the precursor pyrolytic decomposition is selected, long depositions times are involved, and low thermal conductive substrates are used. We have focused on one of these low thermal conductive substrates, glass, on which spheroid shaped microstructures and inhomogeneities appear.

  9. Microstructure of carbon fiber preform and distribution of pyrolytic carbon by chemical vapor infiltration

    Institute of Scientific and Technical Information of China (English)

    陈建勋; 黄伯云

    2004-01-01

    The carbon/carbon composites were made by chemical vapor infiltration(CVI) with needled felt preform. The distribution of the pyrolytic carbon in the carbon fiber preform was studied by polarized light microscope(PLM) and scanning electronic microscope(SEM). The experimental results indicate that the amount of pyrolytic carbon deposited on the surface of chopped carbon fiber is more than that on the surface of long carbon fiber. The reason is the different porosity between the layer of chopped carbon fiber and long carbon fiber. The carbon precursor gas which passes through the part of chopped carbon fibers decomposes and deposits on the surface of chopped carbon fiber. The pyrolytic carbon on the surface of long carbon fibers is produced by the carbon precursor gas diffusing from the chopped fiber and the Z-d fiber. Uniform pore distribution and porosity in preform are necessary for producing C/C composites with high properties.

  10. Adsorption of Pb(II by Activated Pyrolytic Char from Used Tire

    Directory of Open Access Journals (Sweden)

    Lu Ping

    2016-01-01

    Full Text Available As a renewable resource, the pyrolytic char derived from used tire has promising adsorption capacities owing to its similar structure and properties with active carbon. The purification and activation of the pyrolytic char from used tire, as well as the application of this material in the adsorption of Pb(II in water is conducted. The influences on the adsorption capacity by temperature and pH value are investigated and discussed; the adsorption thermodynamics and kinetics are also studied. The results show that the pyrolytic char from used tire has remarkable adsorption capacity for Pb(II, and the adsorption is an endothermic process complying with the Langmuir isotherm. The adsorption kinetics is a pseudo second-order reaction.

  11. Polymerization and cracking during the hydrotreatment of bio-oil and heavy fractions obtained by fractional condensation using Ru/C and NiMo/Al2O3 catalyst

    NARCIS (Netherlands)

    Kadarwati, S.; Oudenhoven, S.R.G; Schagen, M.; Hu, X.; Garcia-Perez, M.; Kersten, S.R.A.; Li, C.Z.; Westerhof, R.J.M.

    2016-01-01

    Two-step hydrotreatment experiments were performed using three completely different bio-oil fractions namely: whole bio-oil, heavy bio-oil obtained after fractional condensation of pyrolysis vapours and pyrolytic lignin obtained by cold water precipitation of the bio-oil. The aim is to study the de-

  12. Pyrolytic Behavior of Citric Acid%柠檬酸的热解特性

    Institute of Scientific and Technical Information of China (English)

    周顺; 徐迎波; 王程辉; 田振峰

    2011-01-01

    The pyrolytic behavior of citric acid was investigated by thermogravimetric system coupled to Fourier transform infrared spectrometer ( TG-FTIR). The TG curves, DTG curves, and relative contents of pyrolytic gas phase products of citric acid in oxygen of different concentrations were determined and compared. The formation rules of gas phase products and pyrolytic mechanism of citric acid were explored. The results showed that: 1) The main pyrolytic gas phase products of citric acid included C02, H20, CO, anhydride and ketone compounds, in which CO2 was the major, while CO was the minor, H20 emerged first, while anhydride the last. 2) There might exist two pyrolytic pathways, in one of the pathways citric acid was dehydrated and then decarbonated to form anhydride, and in the other to form ketones mainly by decarbonation. At the initial pyrolytic stage, both pathways coexisted, increasing oxygen concentration would benefit the formation of ketones. While at higher temperature, anhydride formation dominated.%使用热失重/傅里叶变换红外联用( TG-FTIR)技术研究了柠檬酸的热裂解特性,测定并比较了不同氧气浓度下柠檬酸的热重(TG)和微商热重(DTG)曲线,以及柠檬酸热解气相产物相对含量和生成规律,探讨了柠檬酸可能的热解机制.结果表明:①柠檬酸的热解气相产物主要有CO2,CO,H2O,酸酐和酮类物质.CO2是气相产物中相对含量最高的物质,CO最低;水最早出现在气相产物中,酸酐是最后存在于气相产物中的物质;②柠檬酸可能有2种主要热解途径:先脱水后脱CO2的酸酐生成模式和主要脱CO2的酮生成模式.在热解初期,2种模式同时发生,氧气浓度的增加有利于酮的生成.在较高温度下,主要以酸酐生成模式为主.

  13. Glass-like carbon, pyrolytic graphite or nanostructured carbon for electrochemical sensing of bismuth ion?

    Directory of Open Access Journals (Sweden)

    Jadranka Milikić

    2016-06-01

    Full Text Available Different carbon electrodes were explored for application in electroanalysis, namely for sensing of bismuth ion as model analyte. Carbon materials tested included glassy carbon, basal and edge plane pyrolytic graphite, as well as nanostructured carbonized polyaniline prepared in the presence of 3,5-dinitrosalicylic acid. Bismuth ion was chosen as model analyte as protocol for its detection and quantifications is still to be determined. Herein, anodic stripping voltammetry was used with study of effect of several parameters such as scan rate and deposition time. Electrode based on carbonized polyaniline showed the highest activity for bismuth ion sensing in terms of the highest current densities recorded both in a laboratory and in real sample, while basal plane pyrolytic graphite electrode gave the lowest limit of detection.

  14. Structural and Compositional Characterization of Fungus-Derived Pyrolytic Carbon Architectures

    Directory of Open Access Journals (Sweden)

    Brennan Campbell

    2016-01-01

    Full Text Available Three distinctive pyrolytic carbon structures, derived from three specific tissues of Agaricus bisporus mushroom, were studied and characterized. The three structures discovered within the stalk, cap, and cap skin tissues were found to contain unique microarchitectures, which were preserved upon anoxic carbonization. Experiments also revealed the formation of salt pockets and deposits within each microarchitecture, leading to a potential natural hard-template method for porous carbon structures.

  15. Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera

    Institute of Scientific and Technical Information of China (English)

    ZHAO Hui; YAN Huaxiao; LIU Ming; ZHANG Congwang; QIN Song

    2011-01-01

    The marine macroalgae Enteromorpha prolifera was one of the main algal genera that occurred in the widespread green tides in Qingdao,China,during the summers of 2007,2008 and 2010.It is thus a plentiful source of biomass and could be used as a biofuel.In this study,the pyrolytic characteristics and kinetics of E.prolifera were investigated using thermogravimetric analysis (TGA)method.Cornstalk and sawdust were used as comparisons.Pyrolytic characteristics were studied using TG-DTG (thermogravimetry-derivative thermogravimetry) curves.Three stages in the pyrolytic process were determined:dehydration,dramatic weight loss and slow weight loss.E.prolifera was pyrolyzed at a lower initial temperature than the two terrestrial biomass forms.The apparent activation energy values for the three types of biomass were calculated and the mechanism functions were determined using 16 different mechanism functions,frequently used in thermal kinetics analysis.Activation energy values varied with mechanism function and the range of activation energy values for E.prolifera,cornstalk,and sawdust were 25-50 kJ/mol,60-90 kJ/mol and 120-155 kJ/mol,respectively.This indicates that E.prolifera has low thermal stability for pyrolysis and good combustion chaxacteristics.

  16. Nanomechanical Pyrolytic Carbon Resonators: Novel Fabrication Method and Characterization of Mechanical Properties

    Science.gov (United States)

    Kurek, Maksymilian; Larsen, Frederik K.; Larsen, Peter E.; Schmid, Silvan; Boisen, Anja; Keller, Stephan S.

    2016-01-01

    Micro- and nanomechanical string resonators, which essentially are highly stressed bridges, are of particular interest for micro- and nanomechanical sensing because they exhibit resonant behavior with exceptionally high quality factors. Here, we fabricated and characterized nanomechanical pyrolytic carbon resonators (strings and cantilevers) obtained through pyrolysis of photoresist precursors. The developed fabrication process consists of only three processing steps: photolithography, dry etching and pyrolysis. Two different fabrication strategies with two different photoresists, namely SU-8 2005 (negative) and AZ 5214e (positive), were compared. The resonant behavior of the pyrolytic resonators was characterized at room temperature and in high vacuum using a laser Doppler vibrometer. The experimental data was used to estimate the Young’s modulus of pyrolytic carbon and the tensile stress in the string resonators. The Young’s moduli were calculated to be 74 ± 8 GPa with SU-8 and 115 ± 8 GPa with AZ 5214e as the precursor. The tensile stress in the string resonators was 33 ± 7 MPa with AZ 5214e as the precursor. The string resonators displayed maximal quality factor values of up to 3000 for 525-µm-long structures. PMID:27428980

  17. Pyrolytic-carbon coating in carbon nanotube foams for better performance in supercapacitors

    Science.gov (United States)

    He, Nanfei; Yildiz, Ozkan; Pan, Qin; Zhu, Jiadeng; Zhang, Xiangwu; Bradford, Philip D.; Gao, Wei

    2017-03-01

    Nowadays, the wide-spread adoption of supercapacitors has been hindered by their inferior energy density to that of batteries. Here we report the use of our pyrolytic-carbon-coated carbon nanotube foams as lightweight, compressible, porous, and highly conductive current collectors in supercapacitors, which are infiltrated with chemically-reduced graphene oxide and later compressed via mechanical and capillary forces to generate the active electrodes. The pyrolytic carbon coatings, introduced by chemical vapor infiltration, wrap around the CNT junctions and increase the surface roughness. When active materials are infiltrated, the pyrolytic-carbon coatings help prevent the π-stacking, enlarge the accessible surface area, and increase the electrical conductivity of the scaffold. Our best-performing device offers 48% and 57% higher gravimetric energy and power density, 14% and 23% higher volumetric energy and power density, respectively, and two times higher knee frequency, than the device with commercial current collectors, while the "true-performance metrics" are strictly followed in our measurements. We have further clarified the solution resistance, charge transfer resistance/capacitance, double-layer capacitance, and Warburg resistance in our system via comprehensive impedance analysis, which will shed light on the design and optimization of similar systems.

  18. The Pyrolytic Profile of Lyophilized and Deep-Frozen Compact Part of the Human Bone

    Directory of Open Access Journals (Sweden)

    Jolanta Lodowska

    2012-01-01

    Full Text Available Background. Bone grafts are used in the treatment of nonunion of fractures, bone tumors and in arthroplasty. Tissues preserved by lyophilization or deep freezing are used as implants nowadays. Lyophilized grafts are utilized in the therapy of birth defects and bone benign tumors, while deep-frozen ones are applied in orthopedics. The aim of the study was to compare the pyrolytic pattern, as an indirect means of the analysis of organic composition of deep-frozen and lyophilized compact part of the human bone. Methods. Samples of preserved bone tissue were subjected to thermolysis and tetrahydroammonium-hydroxide- (TMAH- associated thermochemolysis coupled with gas chromatography and mass spectrometry (Py-GC/MS. Results. Derivatives of benzene, pyridine, pyrrole, phenol, sulfur compounds, nitriles, saturated and unsaturated aliphatic hydrocarbons, and fatty acids (C12–C20 were identified in the pyrolytic pattern. The pyrolyzates were the most abundant in derivatives of pyrrole and nitriles originated from proteins. The predominant product in pyrolytic pattern of the investigated bone was pyrrolo[1,2-α]piperazine-3,6-dione derived from collagen. The content of this compound significantly differentiated the lyophilized graft from the deep-frozen one. Oleic and palmitic acid were predominant among fatty acids of the investigated samples. The deep-frozen implants were characterized by higher percentage of long-chain fatty acids than lyophilized grafts.

  19. Nanomechanical Pyrolytic Carbon Resonators: Novel Fabrication Method and Characterization of Mechanical Properties

    Directory of Open Access Journals (Sweden)

    Maksymilian Kurek

    2016-07-01

    Full Text Available Micro- and nanomechanical string resonators, which essentially are highly stressed bridges, are of particular interest for micro- and nanomechanical sensing because they exhibit resonant behavior with exceptionally high quality factors. Here, we fabricated and characterized nanomechanical pyrolytic carbon resonators (strings and cantilevers obtained through pyrolysis of photoresist precursors. The developed fabrication process consists of only three processing steps: photolithography, dry etching and pyrolysis. Two different fabrication strategies with two different photoresists, namely SU-8 2005 (negative and AZ 5214e (positive, were compared. The resonant behavior of the pyrolytic resonators was characterized at room temperature and in high vacuum using a laser Doppler vibrometer. The experimental data was used to estimate the Young’s modulus of pyrolytic carbon and the tensile stress in the string resonators. The Young’s moduli were calculated to be 74 ± 8 GPa with SU-8 and 115 ± 8 GPa with AZ 5214e as the precursor. The tensile stress in the string resonators was 33 ± 7 MPa with AZ 5214e as the precursor. The string resonators displayed maximal quality factor values of up to 3000 for 525-µm-long structures.

  20. Aromatics extraction from pyrolytic sugars using ionic liquid to enhance sugar fermentability.

    Science.gov (United States)

    Li, Xiaohua; Luque-Moreno, Luis C; Oudenhoven, Stijn R G; Rehmann, Lars; Kersten, Sascha R A; Schuur, Boelo

    2016-09-01

    Fermentative bioethanol production from pyrolytic sugars was improved via aromatics removal by liquid-liquid extraction. As solvents, the ionic liquid (IL) trihexyltetradecylphosphonium dicyanamide (P666,14[N(CN)2]) and ethyl acetate (EA) were compared. Two pyrolytic sugar solutions were created from acid-leached and untreated pinewood, with levoglucosan contents (most abundant sugar) of 29.0% and 8.3% (w/w), respectively. In a single stage extraction, 70% of the aromatics were effectively removed by P666,14[N(CN)2] and 50% by EA, while no levoglucosan was extracted. The IL was regenerated by vacuum evaporation (100mbar) at 220°C, followed by extraction of aromatics from fresh pyrolytic sugar solutions. Regenerated IL extracted aromatics with similar extraction efficiency as the fresh IL, and the purified sugar fraction from pretreated pinewood was hydrolyzed to glucose and fermented to ethanol, yielding 0.46g ethanol/(g glucose), close to the theoretical maximum yield.

  1. Recycling of waste engine oil for diesel production.

    Science.gov (United States)

    Maceiras, R; Alfonsín, V; Morales, F J

    2017-02-01

    The aim of this work was to recycle waste engine oil until converting it into reusable product, diesel fuel. The waste oil was treated using pyrolytic distillation. The effect of two additives (sodium hydroxide and sodium carbonate) in the purification of the obtained fuel was also studied. Moreover, the influence of the number of distillations were analysed. Some thermal and physicochemical properties (density, viscosity, colour, turbidity, acidity value, distillation curves, cetane number, corrosiveness to Cu, water content, flash point and hydrocarbons) were determined to analyse the quality of the obtained fuel. The best results were obtained with 2% of sodium carbonate and two successive distillations. The obtained results showed that pyrolytic distillation of waste engine oil is an excellent way to produce diesel fuel to be used in engines.

  2. Effect of acoustic, deformation on radiation-induced luminescence of pyrolytic boron nitride

    CERN Document Server

    Kardashev, B K; Plaksin, O A; Stepanov, V A; Stepanov, P A; Chernov, V M

    2001-01-01

    The effect of the ultrasound oscillations with the frequency of approximately 100 kHz on the radiation-induced luminescence on the pyrolytic boron nitride, originating by the protons irradiation (the energy of 8 MeV, the flux of 1.6 x 10 sup 1 sup 2 p/cm s), is studied. The impact of the ultrasound oscillations manifests itself by high deformation amplitudes (approximately 10 sup - sup 4), when the nonlinear, amplitude-dependent ultrasound absorption is observed. The obtained data are explained by the change in the kinetics of recrystallization, induced by irradiation, whereby the disappearance (radiation annealing) of the small angle boundaries occurs

  3. Mass spectrometric characterization of a pyrolytic radical source using femtosecond ionization

    Energy Technology Data Exchange (ETDEWEB)

    Frey, H.M.; Beaud, P.; Mischler, B.; Radi, P.P.; Tzannis, A.P.; Gerber, T. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Radicals play, as reactive species, an important role in the chemistry of combustion. In contrast to atmospheric flames where spectra are congested due to high vibrational and rotational excitation, experiments in the cold environment of a molecular beam (MB) yield clean spectra that can be easily attributed to one species by Resonantly Enhanced Multi Photon Ionization (REMP). A pyrolytic radical source has been set up. To characterize the efficiency of the source `soft` ionization with femto second pulses is applied which results in less fragmentation, simplifying the interpretation of the mass spectrum. (author) figs., tabs., refs.

  4. Specific heat of pristine and brominated graphite fibers, composites and HOPG. [Highly Oriented Pyrolytic Graphite

    Science.gov (United States)

    Hung, Ching-Chen; Maciag, Carolyn

    1987-01-01

    Differential scanning calorimetry was used to obtain specific heat values of pristine and brominated P-100 graphite fibers and brominated P-100/epoxy composite as well as pristine and brominated highly oriented pyrolytic graphite (HOPG) for comparison. Based on the experimental results obtained, specific heat values are calculated for several different temperatures, with a standard deviation estimated at 1.4 percent of the average values. The data presented here are useful in designing heat transfer devices (such as airplane de-icing heaters) from bromine fibers.

  5. Thermal conductivity mapping of pyrolytic carbon and silicon carbide coatings on simulated fuel particles by time-domain thermoreflectance

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Honorato, E. [Materials Science Centre, School of Materials, University of Manchester, Grosvenor Street, Manchester M1 7HS (United Kingdom); Chiritescu, C. [Department of Materials Science and Engineering, Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, IL 61801 (United States); Xiao, P. [Materials Science Centre, School of Materials, University of Manchester, Grosvenor Street, Manchester M1 7HS (United Kingdom)], E-mail: Ping.xiao@manchester.ac.uk; Cahill, David G. [Department of Materials Science and Engineering, Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, IL 61801 (United States); Marsh, G.; Abram, T.J. [Nexia Solutions Ltd., Springfields PR4 0XJ (United Kingdom)

    2008-08-15

    Thermal conductivity of pyrolytic carbon and silicon carbide coatings on spherical particles has been mapped using time-domain thermoreflectance. The thermal conductivities measured for pyrolytic carbon ranged between 3.4 and 13.5 W/m K. The effect of porosity, pore-size distribution, anisotropy, in-plane disorder and domain sizes is discussed. A thermal conductivity of 168 W/m K was obtained for SiC. Mapping of the thermal conductivity of coated fuel particles provides useful data for modeling fuel performance during the operation of nuclear reactors.

  6. Decomposition mechanism of melamine borate in pyrolytic and thermo-oxidative conditions

    Energy Technology Data Exchange (ETDEWEB)

    Hoffendahl, Carmen; Duquesne, Sophie; Fontaine, Gaëlle; Bourbigot, Serge, E-mail: serge.bourbigot@ensc-lille.fr

    2014-08-20

    Highlights: • Decomposition of melamine borate in pyrolytic and thermo-oxidative conditions was investigated. • With increasing temperature, orthoboric acid forms boron oxide releasing water. • Melamine decomposes evolving melamine, ammonia and other fragments. • Boron oxide is transformed into boron nitride and boron nitride-oxide structures through presence of ammonia. - Abstract: Decomposition mechanism of melamine borate (MB) in pyrolytic and thermo-oxidative conditions is investigated in the condensed and gas phases using solid state NMR ({sup 13}C and {sup 11}B), X-ray photoelectron spectroscopy (XPS), pyrolysis-gas chromatography–mass spectrometry (py-GCMS) and thermogravimetric analysis coupled with a Fourier transform infrared spectrometer (TGA–FTIR). It is evidenced that orthoboric acid dehydrates to metaboric and then to boron oxide. The melamine is partially sublimated. At the same time, melamine condensates, i.e., melem and melon are formed. Melon is only formed in thermo-oxidative conditions. At higher temperature, melem and melon decompose releasing ammonia which reacts with the boron oxide to form boron nitride (BN) and BNO structures.

  7. DETERMINATION OF WATER CONTENT IN PYROLYTIC TARS USING COULOMETRIC KARL-FISHER TITRATION

    Directory of Open Access Journals (Sweden)

    Lenka Jílková

    2017-02-01

    Full Text Available The liquid organic fraction of pyrolytic tar has a high energy value which makes possible its utilization as an energy source. However, before utilization, it is crucial to remove water from the liquid fraction. The presence of water reduces the energy value of pyrolytic tars. Water separation from the organic tar fraction is a complex process, since an emulsion can be readily formed. Therefore, after phase separation, it is important to know the residual water content in the organic phase and whether it is necessary to further dry it. The results presented in this manuscript focus on a water determination in liquid products from coal and biomass pyrolysis by a coulometric Karl‑Fischer titration. The Coulometric Karl‑Fischer titration is often used for a water content determination in gaseous, liquid and solid samples. However, to date, this titration method has not been used for a water determination in tars. A new water determination method, which has been tested on different types of tar, has been developed. The Coulometric Karl‑Fischer titration is suitable for tar samples with a water content not greater than 5 wt. %. The obtained experimental results indicate that the new introduced method can be used with a very good repeatability for a water content determination in tars.

  8. Absence of field anisotropy in the intrinsic ferromagnetic signals of highly oriented pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Ballestar, A. [Laboratorio de Fisica y Sistemas Pequenos y Nanotecnologia, CSIC, Serano 144, E-28006 Madrid (Spain); Division of Superconductivity and Magnetism, Linnestrasse 5, Universitaet Leipzig, D-04103 Leipzig (Germany); Setzer, A. [Division of Superconductivity and Magnetism, Linnestrasse 5, Universitaet Leipzig, D-04103 Leipzig (Germany); Esquinazi, P., E-mail: esquin@physik.uni-leipzig.d [Division of Superconductivity and Magnetism, Linnestrasse 5, Universitaet Leipzig, D-04103 Leipzig (Germany); Garcia, N. [Laboratorio de Fisica y Sistemas Pequenos y Nanotecnologia, CSIC, Serano 144, E-28006 Madrid (Spain)

    2011-03-15

    We have measured the magnetization of bulk samples of highly oriented pyrolytic graphite (HOPG) at magnetic fields applied parallel and perpendicular to the graphene layers. Within experimental error the intrinsic ferromagnetic signals of the samples show similar magnetic moments at saturation for the two magnetic field directions, in contrast to recently published data (J. Cervenka et al., Nat. Phys. 5 (2009) 840). To check that the SQUID device provides correctly the small ferromagnetic signals obtained after subtracting the 100 times larger diamagnetic background, we have prepared a sample with a superconducting Pb-film deposited on one of the HOPG surfaces. We show that the field dependence of the measured magnetic moment and after the background subtraction is highly reliable even in the sub-{mu} emu range providing the real magnetic properties of the embedded small ferromagnetic and superconducting signals. - Research highlights: > We have measured the magnetization of bulk samples of highly oriented pyrolytic graphite (HOPG) at magnetic fields applied parallel and perpendicular to the graphene layers. > Within experimental error the intrinsic ferromagnetic signals of the samples show similar magnetic moments at saturation for the two magnetic field directions. > The absence of magnetic anisotropy of the intrinsic ferromagnetic order found in HOPG samples contrasts recently published data by Cervenka et al., Nat Phys 5, 840 (2009).

  9. Structure and mechanical properties of pyrolytic carbon produced by fluidized bed chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Honorato, E.; Meadows, P.J. [Manchester Materials Science Centre, School of Materials, University of Manchester, Grosvenor Street, Manchester M1 7HS (United Kingdom); Xiao, P. [Manchester Materials Science Centre, School of Materials, University of Manchester, Grosvenor Street, Manchester M1 7HS (United Kingdom)], E-mail: Ping.Xiao@manchester.ac.uk; Marsh, G.; Abram, T.J. [Nexia Solutions Ltd., Springfields PR4 0XJ (United Kingdom)

    2008-11-15

    Pyrolytic carbon was deposited on spherical particles using a multi-spout fluidized bed chemical vapor deposition reactor to fabricate TRISO fuel for the High Temperature Reactor (HTR). Modern techniques such as Raman spectroscopy and nanoindentation supported by porosimetry, scanning electron microscopy and transmission electron microscopy were employed to analyze the particle coatings directly. Raman spectroscopy and nanoindentation were given special attention due to their capacity to provide information on the internal structure of pyrolytic carbon and its mechanical properties without the necessity of complex sample preparation. The results obtained were used to study the relationship deposition conditions-microstructure-mechanical properties in more detail. Increasing the deposition temperature reduced the density and Young's modulus as porosity and in-plane disorder of carbon domains increased. There was also a change from a laminar microstructure of PyC to that containing more spherical particles. It appeared that anisotropy, domain size and level of graphitization (examined by Raman and TEM) had a strong influence on the mechanical properties. Clear differences were observed between acetylene and the acetylene/propylene mixture as precursor gases.

  10. Structure-property relations for silicon nitride matrix composites reinforced with pyrolytic carbon pre-coated Hi-Nicalon fibers

    NARCIS (Netherlands)

    Kooi, B.J.; Hosson, J.Th.M. De; Olivier, C.; Veyret, J.B.

    1999-01-01

    Si3N4 matrix composites reinforced with pyrolytic carbon pre-coated Hi-Nicalon (SiC) fibers, were studied using tensile testing and transmission electron microscopy. Three types of samples were evaluated all with a nominal coating thickness of 200 nm. The composites were densified by hot pressing at

  11. Structure-property relations for silicon nitride matrix composites reinforced with pyrolytic carbon pre-coated Hi-Nicalon fibers

    NARCIS (Netherlands)

    Kooi, B.J.; Hosson, J.Th.M. De; Olivier, C.; Veyret, J.B.

    1999-01-01

    Si3N4 matrix composites reinforced with pyrolytic carbon pre-coated Hi-Nicalon (SiC) fibers, were studied using tensile testing and transmission electron microscopy. Three types of samples were evaluated all with a nominal coating thickness of 200 nm. The composites were densified by hot pressing at

  12. Electron spectra line shape analysis of highly oriented pyrolytic graphite and nanocrystalline diamond.

    Science.gov (United States)

    Lesiak, Beata; Zemek, Josef; Houdkova, Jana; Kromka, Alexander; Józwik, Adam

    2010-01-01

    The X-ray excited Auger electron spectroscopy (XAES), X-ray photoelectron spectroscopy (XPS) and elastic peak electron spectroscopy (EPES) methods were applied in investigating samples of nanocrystalline diamond and highly oriented pyrolytic graphite of various C sp(2)/sp(3) ratios, crystallinity conditions and grain sizes. The composition at the surface was estimated from the XPS. The C sp(2)/sp(3) ratio was evaluated from the width of the XAES first derivative C KLL spectra and from fitting of XPS C 1s spectra into components. The pattern recognition (PR) method applied for analyzing the spectra line shapes exhibited high accuracy in distinguishing different carbon materials. The PR method was found to be a potentially useful approach for identification, especially important for technological applications in fields of materials engineering and for controlling the chemical reaction products during synthesis.

  13. One_dimensional chains of gold clusters on the surface of highly oriented pyrolytic graphite

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    We have investigated the growth of gold nanoclusters on thesurface of highly oriented pyrolytic graphite in ultrahigh vacuum. Studies of ultrahigh vacuum scanning tunneling microscopy revealed that the size distribution of gold clusters was very narrow and quasi-one-dimensional chains of gold nanoclusters of approximately 2 nm diameter were produced after being annealed at 74℃. Unlike the results obtained by previous workers, these chains of gold clusters were not formed along steps on the substrate surface, and some of them could even go across monoatomic steps. The orientation of chains of gold clusters was also dependent on the size of gold nanoclusters. These results suggest the viability of a new route to the creation of ordered nanoscale structures.

  14. Atomic force microscopy study of anion intercalation into highly oriented pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Alliata, D.; Haering, P.; Haas, O.; Koetz, R. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Siegenthaler, H. [University of Berne (Switzerland)

    1999-08-01

    In the context of ion transfer batteries, we studied highly oriented pyrolytic graphite (HOPG) in perchloric acid, as a model to elucidate the mechanism of electrochemical intercalation in graphite. Aim of the work is the local and time dependent investigation of dimensional changes of the host material during electrochemical intercalation processes on the nanometer scale. We used atomic force microscopy (AFM), combined with cyclic voltammetry, as in-situ tool of analysis during intercalation and expulsion of perchloric anions into the HOPG electrodes. According to the AFM measurements, the HOPG interlayer spacing increases by 32% when perchloric anions intercalate, in agreement with the formation of stage IV of graphite intercalation compounds. (author) 3 figs., 3 refs.

  15. Pyrolytic characteristics of biodiesel prepared from lipids accumulated in diatom cells with growth regulation.

    Science.gov (United States)

    Cheng, Jun; Feng, Jia; Ge, Tingting; Yang, Weijuan; Zhou, Junhu; Cen, Kefa

    2015-08-01

    Dynamic compositions of lipids accumulated in two diatoms Chaetoceros gracilis and Nitzschia closterium cultured with nitrogen and silicon deprivation were studied. It was found that short-chain fatty acids (C14-C16) content was much higher than long-chain fatty acids (C18-C20) content in lipids of two diatoms. The pyrolytic characteristics of biodiesel made from two diatoms and two plant seeds were compared by thermogravimetric analysis. The highest activation energy of 46.68 kJ mol(-1) and the minimum solid residue of 25.18% were obtained in the pyrolysis of biodiesel made from C. gracilis cells, which were cultured with 0.5 mmol L(-1) of nitrogen (no silicon) and accumulated the minimum polyunsaturated fatty acid (C20:5). The pyrolysis residue percentage of C. gracilis biodiesel was lower than that of N. closterium biodiesel and higher than those of plant (Cormus wilsoniana and Pistacia chinensis) biodiesels.

  16. Scanning electrochemical microscopy of a fuel-cell electrocatalyst deposited onto highly oriented pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Kucernak, A.R.; Chowdhury, P.B.; Wilde, C.P. [Imperial College, London (United Kingdom). Department of Chemistry; Kelsall, G.H. [Imperial College, London (United Kingdom). Huxley School; Zhu, Y.Y.; Williams, D.E. [University College London, (United Kingdom). Department of Chemistry

    2000-07-01

    The hydrogen evolution reaction (HER) has been examined on a platinum electrocatalysts (Johnson Matthey HSA platinum black) dispersed onto a flat highly oriented pyrolytic graphite (HOPG) electrode using an atomic force microscope (AFM) modified to perform scanning tunneling microscopy (STM) and scanning electrochemical microscopy (SECM). For both STM and SECM experiments the same Pt/Ir tips produced by electrochemical etching of Pt/Ir wire followed by coating with varnish have been used. The coating process leaves only the very end of the tip exposed. Positioning the SECM tip 42 nm from one of the particles allows monitoring of hydrogen evolution from that particle as a function of substrate potential. In a separate experiment the substrate has been polarized at a potential at which hydrogen evolution occurs and the SECM tip rastered over the surface to obtain images of the local concentration of hydrogen. This map indicates the activity of hydrogen production as a function of position. (author)

  17. Mass spectroscopic analysis of a plume induced by laser ablation of pyrolytic boron nitride

    CERN Document Server

    Chae, H B; Lee, I H; Park, S M

    1998-01-01

    The laser ablation of a pyrolytic boron nitride (pBN) target was investigated by time-of- flight quadrupole mass spectroscopy. According to the laser-correlated ion mass spectra, B sup + and B sub 2 sup + ions were produced, but neither N sup + , N sub 2 sup + , or BN sup + ions were observed at laser fluences below 1 J/cm sup 2. Instead, neutral N sub 2 molecules were found to be formed. The mean velocities and kinetic energies of the B sup + ions were obtained by time-of-flight analysis. Also, reactive laser ablation under a N sub 2 atmosphere was attempted by using a pulsed valve synchronized with the laser pulse.

  18. Standard specification for pyrolytic and vacuum deposition coatings on flat glass

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 This specification covers the optical and aesthetic quality requirements for coatings applied to glass for use in building glazing. 1.2 The coatings covered are applied to the glass using either pyrolytic or vacuum (sputtering) deposition methods and are typically applied to control solar heat gain, energy performance, comfort level, and condensation and enhance the aesthetic of the building. 1.3 This specification addresses blemishes related to the coating only. It does not address glass blemishes, applied ceramic frits, and organic films. 1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.

  19. Electrocrystallization of Monodisperse Nanocrystal Copper on Highly Oriented Pyrolytic Graphite Electrode

    Institute of Scientific and Technical Information of China (English)

    黄令; LEE,Eun-Sung; KIM,Kwang-Bum

    2005-01-01

    Mechanism of copper electrocrystallization on highly oriented pyrolytic graphite electrode from a solution of 1 mmol/L CuSO4 and 1.0 mol/L H2SO4 has been studied using cyclic voltammogram and chronoamperometry. The results show that in copper electrodeposition the charge-transfer step is fast and the rate of growth is controlled by the rate of mass transfer of copper ions to the growing centers. Reduction of Cu(Ⅱ) ions did not undergo underpotential deposition. The initial deposition kinetics of Cu electrocrystallization corresponds to a model including progressive nucleation and diffusion controlled growth. Copper nanocrystals with size of 75.6 nm and relative standard deviation of 9% can be obtained by modulation potential electrodeposition.

  20. Atomic-Resolution Kinked Structure of an Alkylporphyrin on Highly Ordered Pyrolytic Graphite.

    Science.gov (United States)

    Chin, Yiing; Panduwinata, Dwi; Sintic, Maxine; Sum, Tze Jing; Hush, Noel S; Crossley, Maxwell J; Reimers, Jeffrey R

    2011-01-20

    The atomic structure of the chains of an alkyl porphyrin (5,10,15,20-tetranonadecylporphyrin) self-assembled monolayer (SAM) at the solid/liquid interface of highly ordered pyrolytic graphite (HOPG) and 1-phenyloctane is resolved using calibrated scanning tunneling microscopy (STM), density functional theory (DFT) image simulations, and ONIOM-based geometry optimizations. While atomic structures are often readily determined for porphyrin SAMs, the determination of the structure of alkyl-chain connections has not previously been possible. A graphical calibration procedure is introduced, allowing accurate observation of SAM lattice parameters, and, of the many possible atomic structures modeled, only the lowest-energy structure obtained was found to predict the observed lattice parameters and image topography. Hydrogen atoms are shown to provide the conduit for the tunneling current through the alkyl chains.

  1. STM observation of a box-shaped graphene nanostructure appeared after mechanical cleavage of pyrolytic graphite

    CERN Document Server

    Lapshin, Rostislav V

    2016-01-01

    A description is given of a three-dimensional box-shaped graphene (BSG) nanostructure formed/uncovered by mechanical cleavage of highly oriented pyrolytic graphite (HOPG). The discovered nanostructure is a multilayer system of parallel hollow channels located along the surface and having quadrangular cross-section. The thickness of the channel walls/facets is approximately equal to 1 nm. The typical width of channel facets makes about 25 nm, the channel length is 390 nm and more. The investigation of the found nanostructure by means of a scanning tunneling microscope (STM) allows us to draw a conclusion that it is possible to make spatial constructions of graphene similar to the discovered one by mechanical compression, bending, splitting, and shifting graphite surface layers. The distinctive features of such constructions are the following: simplicity of the preparation method, small contact area between graphene planes and a substrate, large surface area, nanometer cross-sectional sizes of the channels, lar...

  2. Characterization of a polychromatic neutron beam diffracted by pyrolytic graphite crystals

    CERN Document Server

    Byun, S H; Choi, H D

    2002-01-01

    The beam spectrum for polychromatic neutrons diffracted by pyrolytic graphite crystals was characterized. The theoretical beam spectrum was obtained using the diffraction model for a mosaic crystal. The lattice vibration effects were included in the calculation using the reported vibration amplitude of the crystal and the measured time-of-flight spectra in the thermal region. The calculated beam spectrum was compared with the results obtained in the absence of thermal motion. The lattice vibration effects became more important for the higher diffraction orders and a large decrease in the neutron flux induced by the vibrations was identified in the epithermal region. The validity of the beam spectrum was estimated by comparing with the effective quantities determined from prompt gamma-ray measurements and Cd-ratios measured both for 1/nu and non-1/nu nuclides.

  3. Modification of highly oriented pyrolytic graphite (HOPG) surfaces with highly charged ion (HCI) irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Koguchi, Y. E-mail: ykoguchi@postman.riken.go.jp; Meguro, T.; Hida, A.; Takai, H.; Maeda, K.; Yamamoto, Y.; Aoyagi, Y

    2003-05-01

    Slow Ar{sup 8+} irradiation and the following electron injection creates a non-conductive area to a depth of a few nanometers on a highly oriented pyrolytic graphite surface (HOPG). The annealing of the sample in a hydrogen atmosphere stabilizes the Ar{sup 8+} impact area, which results in the field emission from the impact region. The property of the field emission is similar to that of diamond-like carbon (DLC), suggesting the possibility that sp{sup 3} hybridization occurs at the Ar{sup 8+} impact region. The work function estimated from the Fowler-Nordheim plot is much lower than non-treated HOPG and similar to a hydrogen-terminated DLC film.

  4. Effect of the heating rate on the morphology of the pyrolytic char from hazelnut shell

    Energy Technology Data Exchange (ETDEWEB)

    Hanzade, H.A.; Serdar, Y. [Istanbul Technical Univ., Istanbul (Turkey). Faculty of Chemical and Metallurgical Engineering

    2008-07-01

    Although biomass chars have a high potential for use in various applications, their performance is directly related to the chemical and the physical properties of the chars. The surface area, porosity, pore size distribution, and density are the physical properties that determine the suitability of the chars to be used. Hazelnut shells are touted as being an extremely appropriate feedstock for high quality pyrolytic char, but the working conditions under which char is obtained have significant influence on the char structure and its properties, such as the thermal reactivity. Therefore, effects of the various parameters on the char structure must be considered. In this context, the present study focused on the physical changes that occur in char as a result of different heating rates during the pyrolysis of hazelnut shells. The effects of the heating rate on the structure of the pyrolytic char obtained from ground hazelnut shells under six different heating rate conditions were investigated. The hazelnut shell was burned in a thermogravimetric analyzer (TGA) under nitrogen flow. Non-isothermal heating was performed from ambient to 900 degrees C and held at this temperature until no further mass loss occurred. The changes in char morphology were studied with respect to the heating rate during charring. Scanning electron microscopy (SEM) was used with each char sample to determine the effect of heating rate. The dominant inorganic phases found in hazelnut shells were found to survive in the char. It was concluded that the high lignin content found in the char played a critical role in the decomposition mechanism. 3 refs., 2 tabs., 2 figs.

  5. Fixed-bed adsorption study of methylene blue onto pyrolytic tire char

    Science.gov (United States)

    Makrigianni, Vassiliki; Giannakas, Aris; Papadaki, Maria; Albanis, Triantafyllos; Konstantinou, Ioannis

    2016-04-01

    In this work, the adsorption efficiency of acid treated pyrolytic tire char to cationic methylene blue (MB) dye adsorption from aqueous solutions was investigated by fixed-bed adsorption column experiments. The effects of the initial dye concentration (10 - 40 mg L-1) and feed flow rate (50 - 150 mL min -1) with a fixed bed height (15 cm) were studied in order to determine the breakthrough characteristics of the adsorption system. The Adams-Bohart, Yoon-Nelson and Thomas model were applied to the adsorption of MB onto char at different operational conditions to predict the breakthrough curves and to determine the characteristic parameters of the column. The results showed that the maximum adsorbed quantities decreased with increasing flow rate and increased with increasing initial MB concentration. Breakthrough time and exhaustion time increased with decreasing inlet dye concentration and flow rate. In contrast with Adams-Bohart model, Yoon-Nelson model followed by Thomas model were found more suitable to describe the fixed-bed adsorption of methylene blue by char. The correlation coefficient values R2 for both models at different operating conditions are higher than 0.9 and the low average relative error values provided very good fittings of experimental data at different operating conditions. Higher adsorption capacity of 3.85 mg g -1 was obtained at 15 cm of adsorbent bed height, flow rate of 100 mL min -1and initial MB concentration of 40 mg L-1. Although that activated carbons exhibited higher adsorption capacities in the literature, acid-treated pyrolytic tire char was found to be considerably efficient adsorbent for the removal of MB dye column taking into account the advantages of the simpler production process compared to activated carbons, as well as, the availability of waste tire feedstock and concurrent waste tire management.

  6. Investigations into the pyrolytic behaviour of coal/biomass blends using thermogravimetric analysis

    Energy Technology Data Exchange (ETDEWEB)

    Vuthaluru, H.B. [Curtin Univ. of Technology, Dept. of Chemical Engineering, Perth, WA (Australia)

    2004-04-01

    Investigations into the pyrolytic behaviour during co-pyrolysis of coal, biomass materials and coal/biomass blends prepared at different ratios (10:90, 20:80, 30:70 and 50:50) have been conducted using a thermogravimetric analysis (TGA) apparatus. The coal sample selected was Collie sub-bituminous coal from Western Australia, while wood waste (WW) and wheat straw (WS) were used as biomass samples. Three thermal events were identified during the pyrolysis. The first two were dominated by the biomass pyrolysis, while the third was linked to the coal pyrolysis, which occurred at much higher temperatures. No interactions were seen between the coal and biomass during co-pyrolysis. The pyrolytic characteristics of the blends followed those of the parent fuels in an additive manner. Among the tested blends, 20:80 blends showed the lowest activation energies of 90.9 and 78.7 kJ mol{sup -1} for coal/WW and coal/WS blends respectively. The optimum blend ratio for pyrolysis of coal/WS was 50:50 with a high degradation rate in all the thermal events and a higher mass loss over the course of the co-pyrolysis compared to coal/WW blends examined. The reaction orders in these experiments were in the range of 0.21-1.60, thus having a significant effect on the overall reaction rate. Besides the pyrolysis of coal alone, the 50:50 coal/biomass blends had the highest reaction rate, ranging 1x10{sup 9}-2x10{sup 9} min{sup -1}. The experimental results may provide useful data for power generation industries for the development of co-firing options with biomass. (Author)

  7. Analysis of the anisotropy, stoichiometry and polytypes in pyrolytic carbon and silicon carbide coatings

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Honorato, E., E-mail: eddie.lopez@cinvestav.edu.mx [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany); Zhang, H.; Shatwell, R.A. [Materials Science Centre, School of Materials, University of Manchester, Grosvenor St., Manchester M1 7HS (United Kingdom); Guillermier, P. [AREVA Lyon, Rue Juliette Recamier, 69006 Lyon (France); Manara, D. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany); Xiao, P. [Materials Science Centre, School of Materials, University of Manchester, Grosvenor St., Manchester M1 7HS (United Kingdom); Somers, J. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer We have compared the values of anisotropy of pyrolytic carbon measured by Raman spectroscopy and 2MGEM. Black-Right-Pointing-Pointer The values of anisotropy depend on the sampling area. Black-Right-Pointing-Pointer The values of diattenuation for SiC measured by 2MGEM were affected by the content of stacking faults. Black-Right-Pointing-Pointer Raman spectroscopy can be used as a semi-quantitative tool for the characterisation of excess carbon and silicon in SiC. - Abstract: Silicon carbide (SiC) and pyrolytic carbon (PyC) coatings in tristructural isotropic (TRISO) coated fuel particles were characterised by a combination of 2-modulator generalised ellipsometry microscopy (2-MGEM), Raman spectroscopy and transmission electron microscopy. We compared the values of anisotropy obtained from 2-MGEM and Raman spectroscopy to investigate the effect of sampling area and microstructure. No linear correlation in anisotropy was found between these two techniques despite both sampling areas of 2-5 {mu}m. The largest deviations were observed for highly anisotropic samples with optical anisotropy factors (OPTAFs) above 1.1. For medium and low anisotropy samples (OPTAF < 1.1) the relationship is close to linear. The limited use of only the average value of diattenuation does not give an accurate representation of the characteristics of the coatings as significant areas can exist with considerably higher diattenuations that could increase the probability of failure under neutron irradiation. We also observe a change in the diattenuation of SiC due to the presence of stacking faults as confirmed by Raman spectroscopy. Raman spectroscopy was also used to perform semiquantitative analysis of the Si and carbon excess in SiC in four TRISO particles.

  8. Development of an efficient catalyst for the pyrolytic conversion of biomass into transport fuel

    NARCIS (Netherlands)

    Nguyen, T.S.

    2014-01-01

    Fast pyrolysis is a promising technique to convert biomass into a liquid fuel/fuel precursor, known as bio-oil. However, compared to conventional crude oil, bio-oil has much higher oxygen content which results in various detrimental properties and limits its application. Thus the first part of this

  9. Characterization of cadmium removal from aqueous solution by biochar produced from a giant Miscanthus at different pyrolytic temperatures.

    Science.gov (United States)

    Kim, Woong-Ki; Shim, Taeyong; Kim, Yong-Seong; Hyun, Seunghun; Ryu, Changkook; Park, Young-Kwon; Jung, Jinho

    2013-06-01

    The objective of this study was to investigate the feasibility of biochar for removing Cd from aqueous solution. Biochars were produced from a Miscanthus sacchariflorus via slow pyrolysis at 300, 400, 500 and 600°C. Higher pyrolytic temperature resulted in biochar with a higher aromatic structure and fewer polar functional groups. In particular, pH and surface area of biochar increased greatly at pyrolytic temperatures ≥ 500°C, which increased Cd sorption capacity up to 13.24 mgg(-1). The diffuse-controlled Cd removal was likely due to a surface sorption or a precipitation reaction depending on pH. A simulation with the visual MINTEQ program indicated that the precipitate was Cd(OH)2. In addition, biochar treatment significantly removed the acute toxicity of Cd toward Daphnia magna, resulting in increase of EC50 (50% effective concentration) value from 0.16 to 0.76 mgL(-1).

  10. Direct Electrochemistry of Hemoglobin in Layer-by-layer {PDDA/Hb}n Films Assembled on Pyrolytic Graphite Electrodes

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Layer-by-layer {PDDA/Hb}n films were assembled by means of alternate adsorption of positively charged poly(diallyldimethyl ammonium) (PDDA) and negatively charged hemoglobin (Hb) at pH 9.2 from their aqueous solutions on pyrolytic graphite (PG) electrodes. Film growth during adsorption cycles was demonstrated by cyclic voltammetry and UV-Vis spectroscopy.Direct electrochemistry of Hb in {PDDA/Hb} n films on PG was studied.

  11. The pyrolytic-plasma method and the device for the utilization of hazardous waste containing organic compounds

    OpenAIRE

    Opalińska, Teresa; Wnęk, Bartłomiej; Witowski, Artur; Juszczuk, Rafał; Majdak, Małgorzata; Bartusek, Stanislav

    2016-01-01

    This paper is focused on the new method of waste processing. The waste, including hazardous waste, contain organic compounds. The method consists in two main processes: the pyrolysis of waste and the oxidation of the pyrolytic gas with a use of non-equilibrium plasma. The practical implementation of the method requires the design, construction and testing of the new device in large laboratory scale. The experiments were carried out for the two kinds of waste: polyethylene as a model waste and...

  12. Molecular characterization of fossil organic matter in Glyptostrobus europaeus remains from the Orawa basin (Poland). Comparison of pyrolytic techniques

    Energy Technology Data Exchange (ETDEWEB)

    Almendros, G.; Dorado, J.; Gonzalez-Vila, F.J.; Martin, F.; Sanz, J.; Alvarez-Ramis, C.; Stuchlik, L. [CSIC, Madrid (Spain). Centro de Ciencias Medioambientales

    1999-05-01

    Pyrolytic methods (standard Curie-point pyrolysis and pyrolysis in the presence of tetramethylammonium hydroxide (TMAH), followed by gas chromatography-mass spectrometry), were used to analyze the organic composition of Glyptostrobus (Taxodiaceae) remains from the Miocene deposits of Lipnica Mala (Poland), consisting of branches with their leaves. The pyrolytic analysis revealed a series of aromatic compounds with a large proportion of guaiacyl-type lignin markers (including intact C{sub 3}-methoxyphenols), and small quantities of polycyclic aromatic hydrocarbons. The alkyl compounds included fatty acid series where the C{sub 14}-C{sub 18} homologues dominated as well as additional amounts of alkanes and alkenes (maximum ca. C{sub 21}). The results suggest that lignin as well as protective epicuticular lipid polymers (including cutin and other long chain-based polyalkyl structures) selectively show the greatest degree of molecular preservation in the Glyptostrobus remains. The comparison between pyrolytic methods shows that the lignin-derived aromatic assemblages predominate in the chromatograms after conventional pyrolysis whereas thermochemolysis with TMAH leads to an `aliphatic enhancement`. This latter technique was found to be the best for analysis of the lipid signature in fossil samples with condensed polymethylene networks. 44 refs., 3 figs., 2 tabs.

  13. Cf/C composites: correlation between CVI process parameters and Pyrolytic Carbon microstructure

    Directory of Open Access Journals (Sweden)

    F. Burgio

    2014-10-01

    Full Text Available Chemical Vapour Infiltration (CVI technique has been long used to produce carbon/carbon composites. The Pyrolytic Carbon (Py-C matrix infiltrated by CVI could have different microstructures, i.e. Rough Laminar (RL, Smooth Laminar (SL or Isotropic (ISO. These matrix microstructures, characterized by different properties, influence the mechanical behaviour of the obtained composites. Tailoring the process parameters, it is possible to direct the infiltration towards a specific Py-C type. However, the factors, influencing the production of a specific matrix microstructure, are numerous and interconnected, e.g. temperature, pressure, flow rates etc. Due to the complexity of the physical and chemical phenomena involved in CVI process, up to now it has not been possible to obtain a general correlation between CVI process parameters and Py–C microstructure. This study is aimed at investigating the relationship between infiltration temperature and the microstructure of obtained Py-C, for a pilot - sized CVI/CVD reactor. Fixing the other process parameters and varying only the temperature, from 1100°C to 1300°C, the Py-C infiltration was performed on fibrous preforms. Polarized light microscopy, with quantitative measurements of average extinction angle (Ae, and Raman spectroscopy were used to characterize the obtained Py-C microstructures

  14. Cf/C composites: correlation between CVI process parameters and Pyrolytic Carbon microstructure

    Directory of Open Access Journals (Sweden)

    F. Burgio

    2014-10-01

    Full Text Available Chemical Vapour Infiltration (CVI technique has been long used to produce carbon/carbon composites. The Pyrolytic Carbon (Py-C matrix infiltrated by CVI could have different microstructures, i.e. Rough Laminar (RL, Smooth Laminar (SL or Isotropic (ISO. These matrix microstructures, characterized by different properties, influence the mechanical behaviour of the obtained composites. Tailoring the process parameters, it is possible to direct the infiltration towards a specific Py-C type. However, the factors, influencing the production of a specific matrix microstructure, are numerous and interconnected, e.g. temperature, pressure, flow rates etc. Due to the complexity of the physical and chemical phenomena involved in CVI process, up to now it has not been possible to obtain a general correlation between CVI process parameters and Py–C microstructure. This study is aimed at investigating the relationship between infiltration temperature and the microstructure of obtained Py-C, for a pilot - sized CVI/CVD reactor. Fixing the other process parameters and varying only the temperature, from 1100°C to 1300°C, the Py-C infiltration was performed on fibrous preforms. Polarized light microscopy, with quantitative measurements of average extinction angle (Ae, and Raman spectroscopy were used to characterize the obtained Py-C microstructures.

  15. Material Based Structure Design: Numerical Analysis Thermodynamic Response of Thermal Pyrolytic Graphite /Al Sandwich Composites

    Science.gov (United States)

    Wang, Junxia; Yan, Shilin; Yu, Dingshan

    2016-06-01

    Amine-grafted multiwalled carbon nanotubes (MWCNTs) based thermally conductive adhesive (TCA) was studied in the previous paper and applied here in thermal pyrolytic graphite (TPG)/Al radiator due to its high thermal conductivity, toughness and cohesiveness. In this paper, in an attempt to confirm the application of TCA to TPG/Al sandwich radiator, the thermodynamic response in TPG/Al sandwich composites associated with key material properties and structural design was investigated using finite element simulation with commercial available ANSYS software. The induced thermal stress in TCA layer is substantial due to the thermal expansion mismatch between Al plate and TPG. The maximum thermal stress is located near the edge of TCA layer with the von Mises stress value of 4.02 MPa and the shear stress value of 1.66 MPa. The reasonable adjustment of physical-mechanical properties including thermal conductivity, thermal expansion, Young,s modulus and the thickness of TCA layer, Al plate and TPG are beneficial for reducing the temperature of the top surface of the upper skin and their effects on the reduction of thermal structural response in some ways. These findings will highlight the structural optimization of TPG/Al radiator for future application.

  16. Nucleation and growth in electrodeposition of thin copper films on pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Kinaci, F.S.; Muller, R.H.

    1992-05-01

    Electrodeposition of Cu on graphite electrodes was studied, with emphasis on nucleation. Various ex-situ and in-situ methods were investigated for determining the number density of nuclei. Two direct methods were studied (scanning electron microscopy and scanning tunneling microscopy); indirect determinations included Raman spectroscopy and analysis of potentiostatic current transients. Though some of the techniques correctly predicted the nucleation densities under special conditions, SEM was the most reliable tool. The large scatter in the data necessitated steps to minimize this effect. To electrodeposit Cu on graphite, a nucleation overpotential of 250 mV was measured with cyclic voltammetry; such a large overpotential does not occur on a Pt or on a Cu-covered graphite electrode. The deposition potential is the dominant parameter governing nucleation density. There is a sharp increase in the nucleation density with applied potential. Cu can be deposited on highly oriented pyrolytic graphite only between the nucleation overpotential and the hydrogen evolution potential. To increase the Cu nucleation density, while avoiding excessive H evolution, a double pulse potential technique was used; nucleation densities on the order of 10{sup 10} nuclei/cm{sup 2} were achieved. The use of inhibitors (PVA, benzotriazole) was also investigated. Deposition on conducting polymer electrodes was also studied; initial results with polyaniline show promise. 57 figs, 6 tabs, refs. (DLC)

  17. Formation of Nanocones on Highly Oriented Pyrolytic Graphite by Oxygen Plasma

    Directory of Open Access Journals (Sweden)

    Alenka Vesel

    2014-03-01

    Full Text Available Improvement in hemocompatibility of highly oriented pyrolytic graphite (HOPG by formation of nanostructured surface by oxygen plasma treatment is reported. We have showed that by appropriate fine tuning of plasma and discharge parameters we are able to create nanostructured surface which is densely covered with nanocones. The size of the nanocones strongly depended on treatment time. The optimal results in terms of material hemocompatibility were obtained after treatment with oxygen plasma for 15 s, when both the nanotopography and wettability were the most favorable, since marked reduction in adhesion and activation of platelets was observed on this surface. At prolonged treatment times, the rich surface topography was lost and thus also its antithrombogenic properties. Chemical composition of the surface was always more or less the same, regardless of its morphology and height of the nanocones. Namely, on all plasma treated samples, only a few atomic percent of oxygen was found, meaning that plasma caused mostly etching, leading to changes in the surface morphology. This indicates that the main preventing mechanism against platelets adhesion was the right surface morphology.

  18. Material Based Structure Design: Numerical Analysis Thermodynamic Response of Thermal Pyrolytic Graphite /Al Sandwich Composites

    Science.gov (United States)

    Wang, Junxia; Yan, Shilin; Yu, Dingshan

    2016-12-01

    Amine-grafted multiwalled carbon nanotubes (MWCNTs) based thermally conductive adhesive (TCA) was studied in the previous paper and applied here in thermal pyrolytic graphite (TPG)/Al radiator due to its high thermal conductivity, toughness and cohesiveness. In this paper, in an attempt to confirm the application of TCA to TPG/Al sandwich radiator, the thermodynamic response in TPG/Al sandwich composites associated with key material properties and structural design was investigated using finite element simulation with commercial available ANSYS software. The induced thermal stress in TCA layer is substantial due to the thermal expansion mismatch between Al plate and TPG. The maximum thermal stress is located near the edge of TCA layer with the von Mises stress value of 4.02 MPa and the shear stress value of 1.66 MPa. The reasonable adjustment of physical-mechanical properties including thermal conductivity, thermal expansion, Young,s modulus and the thickness of TCA layer, Al plate and TPG are beneficial for reducing the temperature of the top surface of the upper skin and their effects on the reduction of thermal structural response in some ways. These findings will highlight the structural optimization of TPG/Al radiator for future application.

  19. Self-assembly of thiophene derivatives on highly oriented pyrolytic graphite: hydrogen bond effect.

    Science.gov (United States)

    Xu, Li-Ping; Liu, Yibiao; Zhao, Jing; Wang, Shuqi; Lin, Chen-Sheng; Zhang, Rui-Qin; Wen, Yongqiang; Du, Hongwu; Zhang, Xueji

    2013-02-01

    In this paper, to elucidate the hydrogen bond effect on the assembly behavior, we studied the assembly structures of two carboxylic substituted thiophene derivatives on highly oriented pyrolytic graphite (HOPG) by scanning tunneling microscopy. Here thiophene-2-carboxylic acid (TCA) and thiophene-2,5-dicarboxylic acid (TDA) were employed. TDA molecules spontaneously adsorb on the HOPG surface and self-organize into a two-dimensional (2D) assembly with well-defined structure. Two types of domain could be observed. Each TDA molecule appears as a round circle with two small faint dots and forms hydrogen bonds with neighbours. Besides monolayer structure, a bilayer structure of TDA adlayer on HOPG was also observed in this research. Remnant TDA molecules adsorb on the monolayer of TDA and bilayer structure is formed. In contrast to TDA, no ordered structure of TCA on HOPG can be observed. TCA molecules have high propensity to form dimers through H-bond between carboxylic groups. But TCA dimer is not stable enough for either adsorption or imaging. Our result provides a new example for understanding hydrogen effect on stabilizing and controlling two-dimensional assembly structure and is helpful for surface nanofabrication and development of electric nanodevices.

  20. Electrocatalytic Nitrate Reduction by a Cobalt Protoporphyrin Immobilized on a Pyrolytic Graphite Electrode.

    Science.gov (United States)

    Shen, Jing; Birdja, Yuvraj Y; Koper, Marc T M

    2015-08-04

    A series of simple molecular catalysts, i.e., Co(III), Fe(II), Ni(II), Cu(II), and Rh(II) protoporphyrins (metal-PP), directly adsorbed on pyrolytic graphite have been utilized for catalyzing the electrochemical reduction of nitrate. These catalysts are studied by combining cyclic voltammetry with online electrochemical mass spectrometry (OLEMS) to monitor volatile products and online ion chromatography (IC) to detect ionic products in the aqueous electrolyte solution. Among all investigated porphyrins, the Co-based protoporphyrin shows the highest selectivity toward hydroxylamine (NH2OH), which made it the catalyst of primary interest in the article. The reactivity and selectivity of the immobilized Co-protoporphyrin depend significantly on pH, with more acidic conditions leading to higher reactivity and higher selectivity toward hydroxylamine over ammonia. Potential controlled electrolysis results show that the potential also greatly influences the selectivity: at pH 1, hydroxylamine is the main product around -0.5 V with approximately 100% selectivity, while hydroxylamine and ammonia are both formed at a more negative potential, -0.75 V. The mechanism of the reaction is discussed, invoking of the possibility of two pathways for hydroxylamine/ammonia formation: a sequential pathway in which hydroxylamine is produced as an intermediate, with ammonia subsequently formed through the reduction of NH2OH/NH3OH(+), and a parallel pathway in which the formation of hydroxylamine and ammonia is derived from a common intermediate.

  1. Comparative studies of the pyrolytic and kinetic characteristics of maize straw and the seaweed Ulva pertusa.

    Directory of Open Access Journals (Sweden)

    Naihao Ye

    Full Text Available Seaweed has attracted considerable attention as a potential biofuel feedstock. The pyrolytic and kinetic characteristics of maize straw and the seaweed Ulva pertusa were studied and compared using heating rates of 10, 30 and 50°C min(-1 under an inert atmosphere. The activation energy, and pre-exponential factors were calculated by the Flynn-Wall-Ozawa (FWO, Kissinger-Akahira-Sunose (KAS and Popescu methods. The kinetic mechanism was deduced by the Popescu method. The results indicate that there are three stages to the pyrolysis; dehydration, primary devolatilization and residual decomposition. There were significant differences in average activation energy, thermal stability, final residuals and reaction rates between the two materials. The primary devolatilization stage of U. pertusa can be described by the Avramic-Erofeev equation (n=3, whereas that of maize straw can be described by the Mampel Power Law (n=2. The average activation energy of maize straw and U. pertusa were 153.0 and 148.7 KJ mol(-1, respectively. The pyrolysis process of U.pertusa would be easier than maize straw. And co-firing of the two biomass may be require less external heat input and improve process stability. There were minor kinetic compensation effects between the pre-exponential factors and the activation energy.

  2. Kinetic analyses and pyrolytic behavior of Para grass (Urochloa mutica) for its bioenergy potential.

    Science.gov (United States)

    Ahmad, Muhammad Sajjad; Mehmood, Muhammad Aamer; Al Ayed, Omar S; Ye, Guangbin; Luo, Huibo; Ibrahim, Muhammad; Rashid, Umer; Arbi Nehdi, Imededdine; Qadir, Ghulam

    2017-01-01

    The biomass of Urochloa mutica was subjected to thermal degradation analyses to understand its pyrolytic behavior for bioenergy production. Thermal degradation experiments were performed at three different heating rates, 10, 30 and 50°Cmin(-1) using simultaneous thermogravimetric-differential scanning calorimetric analyzer, under an inert environment. The kinetic analyses were performed using isoconversional models of Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO). The high heating value was calculated as 15.04MJmol(-1). The activation energy (E) values were shown to be ranging from 103 through 233 kJmol(-1). Pre-exponential factors (A) indicated the reaction to follow first order kinetics. Gibbs free energy (ΔG) was measured to be ranging from 169 to 173kJmol(-1) and 168 to 172kJmol(-1), calculated by KAS and FWO methods, respectively. We have shown that Para grass biomass has considerable bioenergy potential comparable to established bioenergy crops such as switchgrass and miscanthus. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Production of pyrolytic liquids from industrial sewage sludges in an induction-heating reactor.

    Science.gov (United States)

    Tsai, Wen-Tien; Chang, Jeng-Hung; Hsien, Kuo-Jung; Chang, Yuan-Ming

    2009-01-01

    With the application of induction-heating, the pyrolytic experiments have been carried out for three sewage sludges from the food processing factories in an externally heated fixed-bed reactor. The thermochemical characteristics of sludge samples were first analyzed. The results indicated that the calorific value had about 15 MJ/kg on an average, suggesting that it had a potential for biomass energy source. However, its nitrogen concentration was relatively high. From the thermogravimetric analysis (TGA) curves, it showed that the pyrolysis reaction can be almost finished in the temperature range of 450-750 degrees C. The yields of resulting liquid and char products from the pyrolysis of sewage sludge were discussed for examining the effects of pyrolysis temperature (500-800 degrees C), heating rate (200-500 degrees C/min), and holding time (1-8 min). Overall, the variation of yield was not so significant in the experimental conditions for three sewage sludges. All results of the resulting liquid products analyzed by elemental analyzer, pH meter, Karl-Fischer moisture titrator and bomb calorimeter were in consistence with those analyses by FTIR spectroscopy. Furthermore, the pyrolysis liquid products contained large amounts of water (>73% by weight) mostly derived from the bound water in the biosludge feedstocks and the condensation reactions during the pyrolysis reaction, and fewer contents of oxygenated hydrocarbons composing of carbonyl and nitrogen-containing groups, resulting in low pH and low calorific values.

  4. Determination of methacrylic acid in food simulants by pyrolytic butylation-gas chromatography.

    Science.gov (United States)

    Huang, Zhongping; Qiu, Ruofeng; Liu, Tingfei; Huang, Yilei; Zhu, Zuoyi; Wang, Lili

    2016-07-08

    An on-line pyrolytic butylation approach was proposed to determine methacrylic acid (MA) in food simulants by gas chromatography (GC) without an expensive pyrolyzer. MA in food simulants was converted into butyl methacrylate in the presence of tetrabutylammonium hydroxide (TBAH) without any pretreatment at 330°C in the injection-port, contributing to high GC signal response. The derivatizing conditions for the proposed method were optimized, namely the injection-port temperature, type and amount of the organic alkaline used for derivatization. A series of standard solutions of MA in the range of 1.0-50mg/kg were analyzed with correlation coefficient r≥0.9975. The limits of detection (LODs) were less than 0.15mg/kg for MA in four matrix simulants (distilled water, 3%w/v acetic acid, 10%v/v ethanol, and isooctane). Relative standard deviations (RSDs) for retention time, peak height and peak area were all less than 3.88%. The technique was successfully applied to the analysis of MA migrating from plastic cup samples, with recoveries of added MA in the range of 96.5-123.0%. Direct injection of the simulants into the GC system after migration tests, without any pretreatment step, makes the developed method of great value for rapid screening analysis of samples in bulks.

  5. Electroanalytical and spectroscopic characterization of poly(o-phenylenediamine) grown on highly oriented pyrolytic graphite.

    Science.gov (United States)

    De Giglio, Elvira; Losito, Ilario; Torsi, Luisa; Sabbatini, Luigia; Zambonin, Pier Giorgio

    2003-03-01

    The polymerization of ortho-phenylenediamine (o-PD) on Highly Oriented Pyrolytic Graphite (HOPG) at different pH (1,3,5,7) was investigated by electroanalytical and spectroscopic methods. Cyclic voltammetry was used both to polymerize o-PD and to study the electroactivity of the resulting poly(ortho-phenylenediamine) (PPD) film. A redox couple associated to the PPD electroactivity, deeply influenced by the pH adopted during polymerization, was recorded. A correlation between this feature and the electrochemistry shown by the oligomers of o-PD, generated in solution during the polymer synthesis, was also found. A comparison between the absorption spectra, in the visible region, of the soluble oligomers and of the PPD films was also performed, suggesting that changes in both the polymer and the oligomer structure occur and are highly related to the polymerization pH. In particular, a higher degree of conjugation is exhibited by the PPD films electrosynthesised at lower pH and this likely explains the higher conductivity as well as the higher electroactivity shown by the material obtained in these conditions.

  6. Evaluating the Surface Topography of Pyrolytic Carbon Finger Prostheses through Measurement of Various Roughness Parameters

    Directory of Open Access Journals (Sweden)

    Andrew Naylor

    2016-04-01

    Full Text Available The articulating surfaces of four different sizes of unused pyrolytic carbon proximal interphalangeal prostheses (PIP were evaluated though measuring several topographical parameters using a white light interferometer: average roughness (Sa; root mean-square roughness (Sq; skewness (Ssk; and kurtosis (Sku. The radii of the articulating surfaces were measured using a coordinate measuring machine, and were found to be: 2.5, 3.3, 4.2 and 4.7 mm for proximal, and 4.0, 5.1, 5.6 and 6.3 mm for medial components. ANOVA was used to assess the relationship between the component radii and each roughness parameter. Sa, Sq and Ssk correlated negatively with radius (p = 0.001, 0.001, 0.023, whilst Sku correlated positively with radius (p = 0.03. Ergo, the surfaces with the largest radii possessed the better topographical characteristics: low roughness, negative skewness, high kurtosis. Conversely, the surfaces with the smallest radii had poorer topographical characteristics.

  7. Evaluating the Surface Topography of Pyrolytic Carbon Finger Prostheses through Measurement of Various Roughness Parameters.

    Science.gov (United States)

    Naylor, Andrew; Talwalkar, Sumedh C; Trail, Ian A; Joyce, Thomas J

    2016-01-01

    The articulating surfaces of four different sizes of unused pyrolytic carbon proximal interphalangeal prostheses (PIP) were evaluated though measuring several topographical parameters using a white light interferometer: average roughness (Sa); root mean-square roughness (Sq); skewness (Ssk); and kurtosis (Sku). The radii of the articulating surfaces were measured using a coordinate measuring machine, and were found to be: 2.5, 3.3, 4.2 and 4.7 mm for proximal, and 4.0, 5.1, 5.6 and 6.3 mm for medial components. ANOVA was used to assess the relationship between the component radii and each roughness parameter. Sa, Sq and Ssk correlated negatively with radius (p = 0.001, 0.001, 0.023), whilst Sku correlated positively with radius (p = 0.03). Ergo, the surfaces with the largest radii possessed the better topographical characteristics: low roughness, negative skewness, high kurtosis. Conversely, the surfaces with the smallest radii had poorer topographical characteristics.

  8. Laser induced periodic surface structures on pyrolytic carbon prosthetic heart valve

    Science.gov (United States)

    Stepak, Bogusz D.; Łecka, Katarzyna M.; Płonek, Tomasz; Antończak, Arkadiusz J.

    2016-12-01

    Laser-induced periodic surface structures (LIPSS) can appear in different forms such as ripples, grooves or cones. Those highly periodic wavy surface features which are frequently smaller than incident light wavelength bring possibility of nanostructuring of many different materials. Furthermore, by changing laser parameters one can obtain wide spectrum of periodicities and geometries. The aim of this research was to determine possibility of nanostructuring pyrolytic carbon (PyC) heart valve leaflets using different irradiation conditions. The study was performed using two laser sources with different pulse duration (15 ps, 450 fs) as well as different wavelengths (1064, 532, 355 nm). Both low and high spatial frequency LIPSS were observed for each set of irradiation parameters. In case femtosecond laser pulses we obtained deep subwavelength ripple period which was even ten times smaller than applied wavelength. Obtained ripple period was ranging from 90 up to 860 nm. Raman spectra revealed the increase of disorder after laser irradiation which was comparable for both pico- and femtosecond laser.

  9. Exploring site-specific chemical interactions at surfaces: a case study on highly ordered pyrolytic graphite

    Science.gov (United States)

    Dagdeviren, Omur E.; Götzen, Jan; Altman, Eric I.; Schwarz, Udo D.

    2016-12-01

    A material’s ability to interact with approaching matter is governed by the structural and chemical nature of its surfaces. Tailoring surfaces to meet specific needs requires developing an understanding of the underlying fundamental principles that determine a surface’s reactivity. A particularly insightful case occurs when the surface site exhibiting the strongest attraction changes with distance. To study this issue, combined noncontact atomic force microscopy and scanning tunneling microscopy experiments have been carried out, where the evolution of the local chemical interaction with distance leads to a contrast reversal in the force channel. Using highly ordered pyrolytic graphite surfaces and metallic probe tips as a model system, we find that at larger tip-sample distances, carbon atoms exhibit stronger attractions than hollow sites while upon further approach, hollow sites become energetically more favorable. For the tunneling current that is recorded at large tip-sample separations during acquisition of a constant-force image, the contrast is dominated by the changes in tip-sample distance required to hold the force constant (‘cross-talk’) at smaller separations the contrast turns into a convolution of this cross-talk and the local density of states. Analysis shows that the basic factors influencing the force channel contrast reversal are locally varying decay lengths and an onset of repulsive forces that occurs for distinct surface sites at different tip-sample distances. These findings highlight the importance of tip-sample distance when comparing the relative strength of site-specific chemical interactions.

  10. Pyrolytic carbon-coated stainless steel felt as a high-performance anode for bioelectrochemical systems.

    Science.gov (United States)

    Guo, Kun; Hidalgo, Diana; Tommasi, Tonia; Rabaey, Korneel

    2016-07-01

    Scale up of bioelectrochemical systems (BESs) requires highly conductive, biocompatible and stable electrodes. Here we present pyrolytic carbon-coated stainless steel felt (C-SS felt) as a high-performance and scalable anode. The electrode is created by generating a carbon layer on stainless steel felt (SS felt) via a multi-step deposition process involving α-d-glucose impregnation, caramelization, and pyrolysis. Physicochemical characterizations of the surface elucidate that a thin (20±5μm) and homogenous layer of polycrystalline graphitic carbon was obtained on SS felt surface after modification. The carbon coating significantly increases the biocompatibility, enabling robust electroactive biofilm formation. The C-SS felt electrodes reach current densities (jmax) of 3.65±0.14mA/cm(2) within 7days of operation, which is 11 times higher than plain SS felt electrodes (0.30±0.04mA/cm(2)). The excellent biocompatibility, high specific surface area, high conductivity, good mechanical strength, and low cost make C-SS felt a promising electrode for BESs.

  11. Pyrolytic synthesis and characterization of N-doped carbon nanoflakes for electrochemical applications

    Energy Technology Data Exchange (ETDEWEB)

    Savilov, S.V., E-mail: savilov@chem.msu.ru [M.V. Lomonosov Moscow State University, Department of Chemistry, Leninskie gory, 1-3, Moscow 119991 (Russian Federation); N.S. Kurnakov Institute of General and Inorganic Chemistry Of Russian Academy of Sciences, Leninsky avenue, 31, Moscow 119991 (Russian Federation); Arkhipova, E.A. [M.V. Lomonosov Moscow State University, Department of Chemistry, Leninskie gory, 1-3, Moscow 119991 (Russian Federation); N.S. Kurnakov Institute of General and Inorganic Chemistry Of Russian Academy of Sciences, Leninsky avenue, 31, Moscow 119991 (Russian Federation); Ivanov, A.S.; Maslakov, K.I [M.V. Lomonosov Moscow State University, Department of Chemistry, Leninskie gory, 1-3, Moscow 119991 (Russian Federation); Shen, Z. [Nanyang Technological University, Centre for Disruptive Photonic Technologies, 637371 Singapore (Singapore); Aldoshin, S.M.; Lunin, V.V. [M.V. Lomonosov Moscow State University, Department of Chemistry, Leninskie gory, 1-3, Moscow 119991 (Russian Federation)

    2015-09-15

    Highlights: • Carbon nanoflakes doped with nitrogen were produced by a pyrolytic technique. • Quarternary, pyrrolic and pyridinic types of nitrogen are confirmed by XPS. • Nitrogen content depends on precursor used and temperature processed. • Specific surface area values decrease with increasing of synthesis duration. • N-doped carbon nanoflakes may be suitable for electrochemical applications. - Abstract: Nitrogen doped carbon nanoflakes, which are very important for many electrochemical applications, were synthesized by pyrolysis of nitrogen containing organic compounds over metal oxide template. Acetonitrile, pyridine and butylamine, which are of different volatility were tested as N-containing precursors. Morphology, structure and chemical composition of the as-synthesized materials were investigated by scanning electron microscopy (SEM), high resolution transmission electron microscopy (TEM), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). It was found that materials are highly defective and consist of a few malformed graphene layers. X-ray photoelectron spectra reflect the dominant graphitic and pyridinic N-bonding configuration. It was also noted that specific surface area depends on the duration and temperature of the reaction. Increase in duration and temperature led to decrease of the specific surface area from 1000 to 160 m{sup 2}/g, 1170 to 210 m{sup 2}/g and 1180 to 480 m{sup 2}/g for acetonitrile, butylamine and pyridine precursors, respectively.

  12. Gas-oil fluids in the formation of travertines in the Baikal rift zone

    Science.gov (United States)

    Tatarinov, A. A.; Yalovik, L. I.; Shumilova, T. G.; Kanakin, S. V.

    2016-07-01

    Active participation of gas-oil fluids in the processes of mineral formation and petrogenesis in travertines of the Arshan and Garga hot springs is substantiated. The parageneses of the products of pyrolytic decomposition and oxidation of the gas-oil components of hydrothermal fluids (amorphous bitumen, graphite-like CM, and graphite) with different genetic groups of minerals crystallized in a wide range of P-T conditions were established. Travertines of the Baikal rift zone were formed from multicomponent hydrous-gas-oil fluids by the following basic mechanisms of mineral formation: chemogenic, biogenic, cavitation, fluid pyrometamorphism, and pyrolysis.

  13. Pyrolytic acrylamide formation from purified wheat gluten and gluten-supplemented wheat bread rolls.

    Science.gov (United States)

    Claus, Achim; Weisz, Georg M; Schieber, Andreas; Carle, Reinhold

    2006-01-01

    Recent studies have revealed different acrylamide formation mechanisms, e. g. from carnosine (N-beta-alanyl-L-histidine) and aminopropionamide as additional precursors. The occurrence of acrylamide in food matrices devoid of common precursors such as meat supports an additional formation pathway. Gluten was recovered from wheat flour by water extraction. Starch, reducing sugars and amino acids were removed using alpha-amylase and NaCl solution and were completely absent in the purified gluten fraction. The gluten was dry heated at temperatures ranging from 160 to 240 degrees C for 8 to 12 min and analyzed for acrylamide and cinnamic amide using liquid chromatography-tandem mass spectrometry. Acrylamide could be detected up to 3997 microg/kg gluten dry weight. Cinnamic amide was detected and unambiguously identified in the gluten samples, thus confirming the proposed formation of acrylamide from proteins. After gluten addition to bread roll dough, protein pyrolysis to form acrylamide in the complex food matrix was assessed. Contents of asparagine and reducing sugars were diminished due to the addition of the gluten. In contrast to the expectation with respect to the well-established common formation mechanism of acrylamide, it increased from 53.4 to 63.9 microg/kg (+20%), which was in good correlation with the higher proportion of gluten. As demonstrated by the t-test, the increase in acrylamide was significant when comparing 0 and 15% gluten addition. Additionally, cinnamic amide could be found in crusts of bread rolls. Thus, evidence for pyrolytic formation of acrylamide from wheat gluten was provided.

  14. STM observation of a box-shaped graphene nanostructure appeared after mechanical cleavage of pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Lapshin, Rostislav V., E-mail: rlapshin@gmail.com [Solid Nanotechnology Laboratory, Institute of Physical Problems, Zelenograd, Moscow 124460 (Russian Federation); Department of Photosensitive Nano and Microsystems, Moscow Institute of Electronic Technology, Zelenograd, Moscow 124498 (Russian Federation)

    2016-01-01

    Graphical abstract: - Highlights: • A previously unknown 3D box-shaped graphene (BSG) nanostructure has been detected. • The nanostructure is a multilayer system of parallel nanochannels having quadrangular cross-section. • Typical width of a nanochannel facet makes 25 nm, typical wall/facet thickness is 1 nm. • A mechanism qualitatively explaining the nanostructure formation has been proposed. • Possible applications of the BSG nanostructure are briefly discussed. - Abstract: A description is given of a three-dimensional box-shaped graphene (BSG) nanostructure formed/uncovered by mechanical cleavage of highly oriented pyrolytic graphite (HOPG). The discovered nanostructure is a multilayer system of parallel hollow channels located along the surface and having quadrangular cross-section. The thickness of the channel walls/facets is approximately equal to 1 nm. The typical width of channel facets makes about 25 nm, the channel length is 390 nm and more. The investigation of the found nanostructure by means of a scanning tunneling microscope (STM) allows us to draw a conclusion that it is possible to make spatial constructions of graphene similar to the discovered one by mechanical compression, bending, splitting, and shifting graphite surface layers. The distinctive features of such constructions are the following: simplicity of the preparation method, small contact area between graphene planes and a substrate, large surface area, nanometer cross-sectional sizes of the channels, large aspect ratio. Potential fields of application include: ultra-sensitive detectors, high-performance catalytic cells, nanochannels for DNA manipulation, nanomechanical resonators, electron multiplication channels, high-capacity sorbents for hydrogen storage.

  15. Adsorption of anionic, cationic and disperse dyes with activated pyrolytic tire char

    Directory of Open Access Journals (Sweden)

    Duangkamol Danwanichakul

    2015-12-01

    Full Text Available Activated pyrolytic tire char was applied as adsorbents to remove dyes from contaminated water. The method of surface treatment with ethanol solution, HCl solution and then activation with NaOH solution was proposed. After activation at 750oC, the specific surface area (SSA of activated char (AC increased from 154.7 m2 /g to 228.9 m2 /g. The pore size increased slightly from 323.4 oA to 349.3 oA and iodine number increased from 95 mg/g to 137 mg/g. AC was then utilized in the adsorption of three dyes which were acid dye (AR131, basic dye (BR18 and disperse dye (DR167 in a shaker with a speed of 75 rpm at 26oC. The initial concentration was varied to be 10 – 50 mg/L. The kinetic results were more consistent with pseudo-second-order model. Considering the adsorption rate constant, k2, it was found that kinetics for acid dye (AR131 was slower than basic dye (BR18 while kinetics for disperse dye (DR167 did not follow specific pattern since it cannot be dispersed well in water without any dispersing agent. Regarding adsorption equilibrium when the initial concentration was between 10-50 mg/L, the adsorption percentages for acid dye (AR131, basic dye (BR18 and disperse dye (DR167 were 88.2 - 100%, 100%, and 26.9 – 50.7%, respectively. In addition, the adsorption isotherms for acid dye (AR131 and basic dye (BR18 followed the Langmuir equation, whereas, that for disperse dye (DR167 was better fit with the Freundlich equation.

  16. Characteristics of Pyrolytic Topping in Fluidized Bed for Different Volatile Coals

    Science.gov (United States)

    Xiong, R.; Dong, L.; Xu, G. W.

    Coal is generally combusted or gasified directly to destroy completely the chemical structures, such as aromatic rings containing in volatile coals including bituminite and lignite. Coal topping refers to a process that extracts chemicals with aromatic rings from such volatile coals in advance of combustion or gasification and thereby takes advantage of the value of coal as a kind of chemical structure resource. CFB boiler is the coal utilization facility that can be easily retrofitted to implement coal topping. A critical issue for performing coal topping is the choice of the pyrolytic reactor that can be different types. The present study concerns fluidized bed reactor that has rarely been tested for use in coal topping. Two different types of coals, one being Xiaolongtan (XLT) lignite and the other Shanxi (SX) bituminous, were tested to clarify the yield and composition of pyrolysis liquid and gas under conditions simulating actual operations. The results showed that XLT lignite coals had the maximum tar yield in 823-873K and SX bituminite realized its highest tar yield in 873-923K. Overall, lignite produced lower tar yield than bituminous coal. The pyrolysis gas from lignite coals contained more CO and CO2 and less CH4, H2 and C2+C3 (C2H4, C2H6, C3H6, C3H8) components comparing to that from bituminous coal. TG-FTIR analysis of tars demonstrated that for different coals there are different amounts of typical chemical species. Using coal ash of CFB boiler, instead of quartz sand, as the fluidized particles decreased the yields of both tar and gas for all the tested coals. Besides, pyrolysis in a reaction atmosphere simulating the pyrolysis gas (instead of N2) resulted also in higher production of pyrolysis liquid.

  17. Large scale computational chemistry modeling of the oxidation of highly oriented pyrolytic graphite.

    Science.gov (United States)

    Poovathingal, Savio; Schwartzentruber, Thomas E; Srinivasan, Sriram Goverapet; van Duin, Adri C T

    2013-04-04

    Large scale molecular dynamics (MD) simulations are performed to study the oxidation of highly oriented pyrolytic graphite (HOPG) by hyperthermal atomic oxygen beam (5 eV). Simulations are performed using the ReaxFF classical reactive force field. We present here additional evidence that this method accurately reproduces ab initio derived energies relevant to HOPG oxidation. HOPG is modeled as multilayer graphene and etch-pit formation and evolution is directly simulated through a large number of sequential atomic oxygen collisions. The simulations predict that an oxygen coverage is first established that acts as a precursor to carbon-removal reactions, which ultimately etch wide but shallow pits, as observed in experiments. In quantitative agreement with experiment, the simulations predict the most abundant product species to be O2 (via recombination reactions), followed by CO2, with CO as the least abundant product species. Although recombination occurs all over the graphene sheet, the carbon-removal reactions occur only about the edges of the etch pit. Through isolated defect analysis on small graphene models as well as trajectory analysis performed directly on the predicted etch pit, the activation energies for the dominant reaction mechanisms leading to O2, CO2, and CO product species are determined to be 0.3, 0.52, and 0.67 eV, respectively. Overall, the qualitative and quantitative agreement between MD simulation and experiment is very promising. Thus, the MD simulation approach and C/H/O ReaxFF parametrization may be useful for simulating high-temperature gas interactions with graphitic materials where the microstructure is more complex than HOPG.

  18. Intensification of adsorption process by using the pyrolytic char from waste tires to remove chromium(Ⅵ) from wastewater

    Institute of Scientific and Technical Information of China (English)

    ZHOU Jie; YANG Yong-rong

    2004-01-01

    Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C-OH, C=O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) has been identified as pseudo-second- order kinetics. The rate constants of adsorption have been evaluated.

  19. Intensification of adsorption process by using the pyrolytic char from waste tires to remove chromium (VI) from wastewater.

    Science.gov (United States)

    Zhou, Jie; Yang, Yong-Rong

    2004-01-01

    Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char (PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(VI) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution/concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon (CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C-OH, C=O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(VI) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(VI) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(VI) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(VI) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(VI) removal. The adsorption of Cr(VI) was identified as pseudo-second-order kinetics. The rate constants of adsorption were evaluated.

  20. Electrochemical Determination of Epinephrine with a Pyrolytic Graphite Electrode in the Presence of Ascorbic Acid and Dopamine

    Institute of Scientific and Technical Information of China (English)

    Xiu Hui LIU; Yan ZHANG; Guo Fang ZUO; Xiao Quan LU

    2006-01-01

    A method for determination of epinephrine(EP) in the presence of ascorbic acid (AA)and dopamine (DA) with bare pyrolytic graphite electrodes has been described for the first time.In pH 7.0 phosphate buffer solution, the linear relationship was observed between the reduction peak current of EP and its concentration over the range from 1×10-4 to 5×10-7 mol/L, the related coefficient is 0.9992 (N=8).

  1. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2006-02-14

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  2. High temperature stability of onion-like carbon vs highly oriented pyrolytic graphite.

    Directory of Open Access Journals (Sweden)

    Alessandro Latini

    Full Text Available The thermodynamic stability of onion-like carbon (OLC nanostructures with respect to highly oriented pyrolytic graphite (HOPG was determined in the interval 765-1030 K by the electromotive force (emf measurements of solid electrolyte galvanic cell: (Low Pt|Cr3C2,CrF2,OLC|CaF2s.c.|Cr3C2,CrF2,HOPG|Pt (High. The free energy change of transformation HOPG = OLC was found positive below 920.6 K crossing the zero value at this temperature. Its trend with temperature was well described by a 3rd degree polynomial. The unexpected too high values of [Formula: see text] jointly to the HR-TEM, STEM and EELS evidences that showed OLC completely embedded in rigid cages made of a Cr3C2/CrF2 matrix, suggested that carbon in the electrodes experienced different internal pressures. This was confirmed by the evaluation under constant volume of [dP/dT by the α/κ ratio for OLC (0.5 MPa K(-1 and HOPG (8 Pa K(-1 where α and κ are the isobaric thermal expansion and isothermal compressibility coefficients, respectively. The temperature dependency of the pressure was derived and utilized to calculate the enthalpy and entropy changes as function of temperature and pressure. The highest value of the internal pressure experienced by OLC was calculated to be about 7 GPa at the highest temperature. At 920.6 K, ΔrH and ΔrS values are 95.8 kJ mol(-1 and 104.1 JK(-1 mol(-1, respectively. The surface contributions to the energetic of the system were evaluated and they were found negligible compared with the bulk terms. As a consequence of the high internal pressure, the values of the enthalpy and entropy changes were mainly attributed to the formation of carbon defects in OLC considered as multishell fullerenes. The change of the carbon defect fraction is reported as a function of temperature.

  3. High temperature stability of onion-like carbon vs highly oriented pyrolytic graphite.

    Science.gov (United States)

    Latini, Alessandro; Tomellini, Massimo; Lazzarini, Laura; Bertoni, Giovanni; Gazzoli, Delia; Bossa, Luigi; Gozzi, Daniele

    2014-01-01

    The thermodynamic stability of onion-like carbon (OLC) nanostructures with respect to highly oriented pyrolytic graphite (HOPG) was determined in the interval 765-1030 K by the electromotive force (emf) measurements of solid electrolyte galvanic cell: (Low) Pt|Cr3C2,CrF2,OLC|CaF2s.c.|Cr3C2,CrF2,HOPG|Pt (High). The free energy change of transformation HOPG = OLC was found positive below 920.6 K crossing the zero value at this temperature. Its trend with temperature was well described by a 3rd degree polynomial. The unexpected too high values of [Formula: see text] jointly to the HR-TEM, STEM and EELS evidences that showed OLC completely embedded in rigid cages made of a Cr3C2/CrF2 matrix, suggested that carbon in the electrodes experienced different internal pressures. This was confirmed by the evaluation under constant volume of [dP/dT by the α/κ ratio for OLC (0.5 MPa K(-1)) and HOPG (8 Pa K(-1)) where α and κ are the isobaric thermal expansion and isothermal compressibility coefficients, respectively. The temperature dependency of the pressure was derived and utilized to calculate the enthalpy and entropy changes as function of temperature and pressure. The highest value of the internal pressure experienced by OLC was calculated to be about 7 GPa at the highest temperature. At 920.6 K, ΔrH and ΔrS values are 95.8 kJ mol(-1) and 104.1 JK(-1) mol(-1), respectively. The surface contributions to the energetic of the system were evaluated and they were found negligible compared with the bulk terms. As a consequence of the high internal pressure, the values of the enthalpy and entropy changes were mainly attributed to the formation of carbon defects in OLC considered as multishell fullerenes. The change of the carbon defect fraction is reported as a function of temperature.

  4. Bisolute sorption and thermodynamic behavior of organic pollutants to biomass-derived biochars at two pyrolytic temperatures.

    Science.gov (United States)

    Chen, Zaiming; Chen, Baoliang; Zhou, Dandan; Chen, Wenyuan

    2012-11-20

    The bisolute sorption and thermodynamic behavior of organic pollutants on low temperature biochars (LTB) at 300 °C and high temperature biochars (HTB) at 700 °C were determined to elucidate sorptive properties of biochar changed with pyrolytic temperatures. The structural characteristics and isotherms shape of the biochar were more dependent on the pyrolytic temperature than on the biomass feedstocks, which included orange peel, pine needle, and sugar cane bagasse. For LTB, the thermally altered organic matter colocalized with the carbonized matter, and the visible fine pores of the fixed carbons were plugged by the remaining volatile carbon. For HTB, most of the volatile matter was gone and the fixed matter was composed of fully carbonized adsorptive sites. Monolayer adsorption of 1-naphthol to HTB was dominant but was suppressed by phenol. In comparison, LTB displayed exceptional sorption behavior where partition and adsorption were concurrently promoted by a cosolute and elevated temperature. In addition to monolayer surface coverage, pore-filling mechanisms may contribute to the increase of adsorption fraction. Moreover, the entropy gain was a dominant force driving the partition and adsorption processes in LTB. Thus, the colocalizing partition phase and adsorptive sites in LTB are proposed to be in interencased states rather than in physical separation.

  5. Study of nanometric thin pyrolytic carbon films for explosive electron emission cathode in high-voltage planar diode

    Energy Technology Data Exchange (ETDEWEB)

    Baryshevsky, Vladimir; Belous, Nikolai; Gurinovich, Alexandra; Gurnevich, Evgeny [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); Kuzhir, Polina, E-mail: polina.kuzhir@gmail.com [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); National Research Tomsk State University, 36 Lenin Prospekt, Tomsk 634050 (Russian Federation); Maksimenko, Sergey [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); National Research Tomsk State University, 36 Lenin Prospekt, Tomsk 634050 (Russian Federation); Molchanov, Pavel; Shuba, Mikhail [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); Roddatis, Vladimir [CIC energiGUNE, Albert Einstein 48, 01510 Minano, Alava (Spain); Institut für Materialphysik of Universität Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Kaplas, Tommi; Svirko, Yuri [Institute of Photonics, University of Eastern Finland, P.O. Box 111, Joensuu FI-80101 (Finland)

    2015-04-30

    We report on an experimental study of explosive electron emission properties of cathode made by nanometric thin pyrolytic carbon (PyC) films (2–150 nm) deposited on Cu substrate via methane-based chemical vapor deposition. High current density at level of 300 A/cm{sup 2} in 5 · 10{sup −5} Pa vacuum has been observed together with very stable explosive emission from the planar cathode. The Raman spectroscopy investigation proves that the PyC films remain the same after seven shots. According to the optical image analysis of the cathode before and after one and seven shots, we conclude that the most unusual and interesting feature of using the PyC films/Cu cathode for explosive emission is that the PyC layer on the top of the copper target prevents its evaporation and oxidation, which leads to higher emission stability compared to conventional graphitic/Cu cathodes, and therefore results in longer working life. - Highlights: • Explosive electron emission from pyrolytic carbon (PyC) cathode is reported. • We observe high current density, 300 A/cm{sup 2}, and stable emission parameters. • PyC integrity ensures a high application potential for high current electronics.

  6. Feasibility study: Application of the geopressured-geothermal resource to pyrolytic conversion or decomposition/detoxification processes

    Energy Technology Data Exchange (ETDEWEB)

    Propp, W.A.; Grey, A.E.; Negus-de Wys, J.; Plum, M.M.; Haefner, D.R.

    1991-09-01

    This study presents a preliminary evaluation of the technical and economic feasibility of selected conceptual processes for pyrolytic conversion of organic feedstocks or the decomposition/detoxification of hazardous wastes by coupling the process to the geopressured-geothermal resource. The report presents a detailed discussion of the resource and of each process selected for evaluation including the technical evaluation of each. A separate section presents the economic methodology used and the evaluation of the technically viable process. A final section presents conclusions and recommendations. Three separate processes were selected for evaluation. These are pyrolytic conversion of biomass to petroleum like fluids, wet air oxidation (WAO) at subcritical conditions for destruction of hazardous waste, and supercritical water oxidation (SCWO) also for the destruction of hazardous waste. The scientific feasibility of all three processes has been previously established by various bench-scale and pilot-scale studies. For a variety of reasons detailed in the report the SCWO process is the only one deemed to be technically feasible, although the effects of the high solids content of the geothermal brine need further study. This technology shows tremendous promise for contributing to solving the nation's energy and hazardous waste problems. However, the current economic analysis suggests that it is uneconomical at this time. 50 refs., 5 figs., 7 tabs.

  7. Co-pyrolsis of polyethylene waste with the Campos basin heavy oil; Co-pirolise de residuos de polietileno com gasoleo pesado da Bacia de Campos

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro, Debora da S.; Marques, Monica R. da C. [Laboratorio de Tecnologia Ambiental, UERJ, Rio de Janeiro, RJ (Brazil)], e-mail: monica@pesquisador.cnpq.br

    2011-07-01

    In this study, four mixtures of LDPE post consumer with heavy gas from the Campos Basin, in different proportions, were subjected to pyrolysis in an inert atmosphere at 550 deg C. The pyrolytic liquids were characterized by gas chromatography coupled to mass spectrometry (GC/MS). Pyrolysis of pure diesel supplied large amounts of waste oil and only 4% in the range of diesel. On the other hand, the pyrolysis of LDPE mixture of diesel (at the ratio 1/0,5 m/m) provided 20% of light hydrocarbons with high production of pyrolytic oil (96%). The formation of high levels of paraffins and olefins in the range of diesel oil during the co-pyrolysis suggests a promising technology for recycling of plastic waste. (author)

  8. The effect of torrefaction on the chemistry of fast-pyrolysis bio-oil.

    Science.gov (United States)

    Meng, Jiajia; Park, Junyeong; Tilotta, David; Park, Sunkyu

    2012-05-01

    Fast pyrolysis was performed on torrefied loblolly pine and the collected bio-oils were analyzed to compare the effect of the torrefaction treatment on their quality. The results of the analyses show that bio-oils produced from torrefied wood have improved oxygen-to-carbon ratios compared to those from the original wood with the penalty of a decrease in bio-oil yield. The extent of this improvement depends on the torrefaction severity. Based on the GC/MS analysis of the pyrolysis bio-oils, bio-oils produced from torrefied biomass show different compositions compared to that from the original wood. Specifically, the former becomes more concentrated in pyrolytic lignin with less water content than the latter. It was considered that torrefaction could be a potential upgrading method to improve the quality of bio-oil, which might be a useful feedstock for phenolic-based chemicals.

  9. Fungicidal values of bio-oils and their lignin-rich fractions obtained from wood/bark fast pyrolysis.

    Science.gov (United States)

    Mohan, Dinesh; Shi, Jenny; Nicholas, Darrel D; Pittman, Charles U; Steele, Philip H; Cooper, Jerome E

    2008-03-01

    Pine wood, pine bark, oak wood and oak bark were pyrolyzed in an auger reactor. A total of 16 bio-oils or pyrolytic oils were generated at different temperatures and residence times. Two additional pine bio-oils were produced at the National Renewable Energy Laboratory in a fluidized-bed reactor at different temperatures. All these bio-oils were fractionated to obtain lignin-rich fractions which consist mainly of phenols and neutrals. The pyrolytic lignin-rich fractions were obtained by liquid-liquid extraction. Whole bio-oils and their lignin-rich fractions were studied as potential environmentally benign wood preservatives to replace metal-based CCA and copper systems that have raised environmental concerns. Each bio-oil and several lignin-rich fractions were tested for antifungal properties. Soil block tests were conducted using one brown-rot fungus (Gloeophyllum trabeum) and one white-rot fungus (Trametes versicolor). The lignin-rich fractions showed greater fungal inhibition than whole bio-oils for a impregnation solution 10% concentration level. Water repellence tests were also performed to study wood wafer swelling behavior before and after bio-oil and lignin-rich fraction treatments. In this case, bio-oil fractions did not exhibit higher water repellency than whole bio-oils. Comparison of raw bio-oils in soil block tests, with unleached wafers, at 10% and 25% bio-oil impregnation solution concentration levels showed excellent wood preservation properties at the 25% level. The good performance of raw bio-oils at higher loading levels suggests that fractionation to generate lignin-rich fractions is unnecessary. At this more effective 25% loading level in general, the raw bio-oils performed similarly. Prevention of leaching is critically important for both raw bio-oils and their fractions to provide decay resistance. Initial tests of a polymerization chemical to prevent leaching showed some success.

  10. Fabrication and Electromagnetic Wave-Absorbing Property of Si3N4 Ceramics with Gradient Pyrolytic Carbon Distribution

    Science.gov (United States)

    Li, Xiangming; Gao, Mingjun

    2016-07-01

    A Si3N4 ceramic with gradient distribution of pyrolytic carbon (Gradient-PyC-Si3N4) was fabricated by a combined technique of precursor infiltration pyrolysis and directional oxidation. An electromagnetic wave could enter Gradient-PyC-Si3N4 with little reflection because of a weak impedance mismatch at its surface, and the electromagnetic wave entering Gradient-PyC-Si3N4 could propagate forward along the PyC changing belt and simultaneously be absorbed by PyC with little reflection. The electromagnetic reflectivity of the Gradient-PyC-Si3N4 with an absence of PyC could reach a low level of -12.1 dB, which means that about 94% of the incident energy is absorbed and so makes the Gradient-PyC-Si3N4 a promising electromagnetic absorbing material for covert action.

  11. Covalent Modification of Highly Ordered Pyrolytic Graphite with a Stable Organic Free Radical by Using Diazonium Chemistry.

    Science.gov (United States)

    Seber, Gonca; Rudnev, Alexander V; Droghetti, Andrea; Rungger, Ivan; Veciana, Jaume; Mas-Torrent, Marta; Rovira, Concepció; Crivillers, Núria

    2017-01-26

    A novel, persistent, electrochemically active perchlorinated triphenylmethyl (PTM) radical with a diazonium functionality has been covalently attached to highly ordered pyrolytic graphite (HOPG) by electrografting in a single-step process. Electrochemical scanning tunneling microscopy (EC-STM) and Raman spectroscopy measurements revealed that PTM molecules had a higher tendency to covalently react at the HOPG step edges. The cross-section profiles from EC-STM images showed that there was current enhancement at the functionalized areas, which could be explained by redox-mediated electron tunneling through surface-confined redox-active molecules. Cyclic voltammetry clearly demonstrated that the intrinsic properties of the organic radical were preserved upon grafting and DFT calculations also revealed that the magnetic character of the PTM radical was preserved. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Optimisation and fabrication of a composite pyrolytic graphite monochromator for the Pelican instrument at the ANSTO OPAL reactor

    Science.gov (United States)

    Freund, A. K.; Yu, D. H.

    2011-04-01

    The triple monochromator for the TOF neutron spectrometer Pelican at ANSTO has been fully optimised in terms of overall performance, including the determination of the thickness of the pyrolytic graphite crystals. A total of 24 composite crystals were designed and fabricated. The calculated optimum thickness of 1.3 mm and the length of 15 cm of the monochromator crystals, that are not available commercially, were obtained by cleaving and soldering with indium. An extensive characterisation of the crystals using X-ray and neutron diffraction was conducted before and after the cleaving and bonding processes. The results proved that no damage was introduced during fabrication and showed that the design goals were fully met. The measured peak reflectivity and rocking curve widths were indeed in an excellent agreement with theory. In addition to the superior efficiency of the triple monochromator achieved by this novel approach, the amount of the crystal material required could be reduced by 1/3.

  13. PYROLYTIC PRODUCTS FROM RICE STRAW AND ENZYMATIC/MILD ACIDOLYSIS LIGNIN (EMAL

    Directory of Open Access Journals (Sweden)

    Rui Lou

    2010-08-01

    Full Text Available A pyrolysis tube furnace system was designed to assess the impact of different components on pyrolysis characteristics under nitrogen atmosphere, and pyrolysis temperature (400 to 900oC as important factors acting on the samples during pyrolysis. The obtained pyrolysate was classified into three groups, i.e. the condensed liquid product (bio-oil, solid product (bio-char, and light gas. Gas chromatography (GC was used to analyze ingredients of the light gas released during pyrolysis, and a gas chromatography/mass spectrometer (GC/MS was used to analyze bio-oil. The results revealed that the volatiles from rice straw pyrolysis exceeded that from lignin at temperatures below 700oC as a result of the higher char generation from lignin pyrolysis. With an increase of pyrolysis temperature, the yield of char decreased and light gas persistently increased, and the yield of bio-tar was maximized at 500oC. In the gas product, H2, CO, CO2 and some light hydrocarbons (CH4, C2H4 and C2H6 could be found, and H2 and CO were abundant. Compounds of bio-oil derived from lignin were simple and consisted of aromatic hydrocarbons, chain hydrocarbon, monoaromatics, and a minor amount of ketones. Phenolic compounds, which comprised 50 to 60%, can be converted easily to obtain high-value chemicals and high quality biofuels.

  14. X-ray photoelectron spectroscopy study of pyrolytically coated graphite platforms submitted to simulated electrothermal atomic absorption spectrometry conditions

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz, Frine [Laboratorio de Quimica Analitica, Centro de Quimica, Instituto Venezolano de Investigaciones Cientificas, IVIC, Apartado Postal 21827, Caracas 1020-A (Venezuela); Benzo, Zully [Laboratorio de Quimica Analitica, Centro de Quimica, Instituto Venezolano de Investigaciones Cientificas, IVIC, Apartado Postal 21827, Caracas 1020-A (Venezuela); Quintal, Manuelita [Laboratorio de Quimica Analitica, Centro de Quimica, Instituto Venezolano de Investigaciones Cientificas, IVIC, Apartado Postal 21827, Caracas 1020-A (Venezuela); Garaboto, Angel [Laboratorio de Quimica Analitica, Centro de Quimica, Instituto Venezolano de Investigaciones Cientificas, IVIC, Apartado Postal 21827, Caracas 1020-A (Venezuela); Albornoz, Alberto [Laboratorio de Fisicoquimica de Superficies, Centro de Quimica, Instituto Venezolano de Investigaciones Cientificas, IVIC, Apartado Postal 21827, Caracas 1020-A (Venezuela); Brito, Joaquin L. [Laboratorio de Fisicoquimica de Superficies, Centro de Quimica, Instituto Venezolano de Investigaciones Cientificas, IVIC, Apartado Postal 21827, Caracas 1020-A (Venezuela)]. E-mail: joabrito@ivic.ve

    2006-10-15

    The present work is part of an ongoing project aiming to a better understanding of the mechanisms of atomization on graphite furnace platforms used for electrothermal atomic absorption spectrometry (ETAAS). It reports the study of unused pyrolytic graphite coated platforms of commercial origin, as well as platforms thermally or thermo-chemically treated under simulated ETAAS analysis conditions. X-ray photoelectron spectroscopy (XPS) was employed to study the elements present at the surfaces of the platforms. New, unused platforms showed the presence of molybdenum, of unknown origin, in concentrations up to 1 at.%. Species in two different oxidations states (Mo{sup 6+} and Mo{sup 2+}) were detected by analyzing the Mo 3d spectral region with high resolution XPS. The analysis of the C 1s region demonstrated the presence of several signals, one of these at 283.3 eV related to the presence of Mo carbide. The O 1s region showed also various peaks, including a signal that can be attributed to the presence of MoO{sub 3}. Some carbon and oxygen signals were consistent with the presence of C=O and C-O- (probably C-OH) groups on the platforms surfaces. Upon thermal treatment up to 2900 deg. C, the intensity of the Mo signal decreased, but peaks due to Mo oxides (Mo{sup 6+} and Mo{sup 5+}) and carbide (Mo{sup 2+}) were still apparent. Thermo-chemical treatment with 3 vol.% HCl solutions and heating up to 2900 deg. C resulted in further diminution of the Mo signal, with complete disappearance of Mo carbide species. Depth profiling of unused platforms by Ar{sup +} ion etching at increasing time periods demonstrated that, upon removal of several layers of carbonaceous material, the Mo signal disappears suggesting that this contamination is present only at the surface of the pyrolytic graphite platform.

  15. Aluminum doped nickel oxide thin film with improved electrochromic performance from layered double hydroxides precursor in situ pyrolytic route

    Science.gov (United States)

    Shi, Jingjing; Lai, Lincong; Zhang, Ping; Li, Hailong; Qin, Yumei; Gao, Yuanchunxue; Luo, Lei; Lu, Jun

    2016-09-01

    Electrochromic materials with unique performance arouse great interest on account of potential application values in smart window, low-power display, automobile anti-glare rearview mirror, and e-papers. In this paper, high-performing Al-doped NiO porous electrochromic film grown on ITO substrate has been prepared via a layered double hydroxides(LDHs) precursor in situ pyrolytic route. The Al3+ ions distributed homogenously within the NiO matrix can significantly influence the crystallinity of Ni-Al LDH and NiO:Al3+ films. The electrochromic performance of the films were evaluated by means of UV-vis absorption spectroscopy, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry(CA) measurements. In addition, the ratio of Ni3+/Ni2+ also varies with Al content which can lead to different electrochemical performances. Among the as-prepared films, NiO film prepared from Ni-Al (19:1) LDH show the best electrochromic performance with a high transparency of 96%, large optical modulation range (58.4%), fast switching speed (bleaching/coloration times are 1.8/4.2 s, respectively) and excellent durability (30% decrease after 2000 cycles). The improved performance was owed to the synergy of large NiO film specific surface area and porous morphology, as well as Al doping stifled the formation of Ni3+ making bleached state more pure. This LDHs precursor pyrolytic method is simple, low-cost and environmental benign and is feasible for the preparation of NiO:Al and other Al-doped oxide thin film.

  16. Transformation, morphology, and dissolution of silicon and carbon in rice straw-derived biochars under different pyrolytic temperatures.

    Science.gov (United States)

    Xiao, Xin; Chen, Baoliang; Zhu, Lizhong

    2014-03-18

    Biochars are increasingly recognized as environmentally friendly and cheap remediation agents for soil pollution. The roles of silicon in biochars and interactions between silicon and carbon have been neglected in the literature to date, while the transformation, morphology, and dissolution of silicon in Si-rich biochars remain largely unaddressed. In this study, Si-rich biochars derived from rice straw were prepared under 150-700 °C (named RS150-RS700). The transformation and morphology of carbon and silicon in biochar particles were monitored by FTIR, XRD, and SEM-EDX. With increasing pyrolytic temperature, silicon accumulated, and its speciation changed from amorphous to crystalline matter, while the organic matter evolved from aliphatic to aromatic. For rice straw biomass containing amorphous carbon and amorphous silicon, dehydration (silicon. At medium pyrolysis temperatures (250-350 °C), an intense cracking of carbon components occurred, and, thus, the silicon located in the inside tissue was exposed. At high pyrolysis temperatures (500-700 °C), the biochar became condensed due to the aromatization of carbon and crystallization of silicon. Correspondingly, the carbon release in water significantly decreased, while the silicon release somewhat decreased and then sharply increased with pyrolytic temperature. Along with SEM-EDX images of biochars before and after water washing, we proposed a structural relationship between carbon and silicon in biochars to explain the mutual protection between carbon and silicon under different pyrolysis temperatures, which contribute to the broader understanding of biochar chemistry and structure. The silicon dissolution kinetics suggests that high Si biochars could serve as a novel slow release source of biologically available Si in low Si agricultural soils.

  17. Oxidative desulfurization of tire pyrolysis oil

    Directory of Open Access Journals (Sweden)

    Ahmad Shahzad

    2016-01-01

    Full Text Available This paper presents a low cost method for the purification of oils obtained from the pyrolysis of used tires. Oxidative desulfurization is a promising route for purification of tire pyrolysis oils as hydro-desulfurization may not be affordable for small scale industries. Different additives and acids have been employed for the enhancement of properties of pyrolytic oils. The experimental conditions were kept identical throughout, i.e. atmospheric pressure and 50°C temperature for comparison of performance of various additives. The use of hydrogen peroxide-acetic acid mixture (10 wt.% was found more economical and effective in desulfurization and improvement of fuel properties of sample oils. The contribution of sulfuric acid in desulfurization and decreasing viscosity was also satisfactory but due to high price of concentrated sulfuric acid its use may not be economical. Calcium oxide and Fuller’s earth was not found to be effective in desulfurization. Results indicate that oxidative desulfurization could render tire pyrolysis oils suitable for blending as heating fuel.

  18. Palm Oil

    Science.gov (United States)

    Palm oil is obtained from the fruit of the oil palm tree. Palm oil is used for preventing vitamin A deficiency, cancer, ... blood pressure, high cholesterol, and cyanide poisoning. Palm oil is used for weight loss and increasing the ...

  19. Diesel oil

    Science.gov (United States)

    Oil ... Diesel oil ... Diesel oil poisoning can cause symptoms in many parts of the body. EYES, EARS, NOSE, AND THROAT Loss of ... most dangerous effects of hydrocarbon (such as diesel oil) poisoning are due to inhaling the fumes. NERVOUS ...

  20. Biological and functional evaluation of a novel pyrolytic carbon implant for the treatment of focal osteochondral defects in the medial femoral condyle: assessment in a canine model.

    Science.gov (United States)

    Salkeld, Samantha L; Patron, Laura P; Lien, Joan C; Cook, Stephen D; Jones, Deryk G

    2016-12-01

    Osteochondral defects continue to be a clinical treatment challenge, and when left untreated, may cause pain and functional impairment. Pyrolytic carbon is a unique isotropic biomaterial used in heart valve and small joint replacements due to its excellent wear properties and biocompatibility with bone and articular cartilage. Therefore, a proposed solution is to utilize a focal pyrolytic carbon hemiarthroplasty implant as an alternative resurfacing treatment strategy for isolated cartilage lesions. A canine model (n = 9) was used to evaluate the in vivo histologic response and function of a pyrolytic carbon implant replacing a full-thickness osteochondral defect in the medial femoral condyle (MFC) of the knee. The gross appearance and histologic results were compared to an identical cobalt-chromium (Co-Cr) alloy implant placed in a defect in the contralateral MFC and evaluated up to 52 weeks. Extensive bone incorporation to the stem portion was observed for both implant types. The total mean histologic score for the cartilage of the MFC surrounding the pyrolytic carbon implants was significantly improved compared to that of the Co-Cr alloy implants at all evaluation periods (p implants were similar to those of Co-Cr alloy implants at 24 weeks. At 24 weeks, the mean total histologic score for Co-Cr alloy implants was 11.6 ± 0.7 (0-16 range point; 16 = normal appearance), while at 52 weeks, the mean total score for the pyrolytic carbon implants was 11.7 ± 1.3. Mean total histologic score of opposing medial tibia cartilage for the pyrolytic carbon implants was superior to that of the Co-Cr alloy group at all evaluation periods and significantly improved over the Co-Cr alloy implant group at 24 weeks (p = 0.001) and 52 weeks (p implant for reconstruction of a focal cartilage defect demonstrated effective implant fixation and superior in vivo response compared to an identical Co-Cr alloy implant.

  1. Characterization and Catalytic Upgrading of Crude Bio-oil Produced by Hydrothermal Liquefaction of Swine Manure and Pyrolysis of Biomass

    Science.gov (United States)

    Cheng, Dan

    ethanol to acetic acid ratio of 3. Crude pyrolytic oil obtained from the RTI International had distillation temperatures from 164.8°C to 365.5°C and 50% volumetric fraction of the crude bio-oil was distillable. Esterified pyrolytic bio-oil had an increased distillability up to 55% volumetric fraction. The esterified pyrolytic bio-oil had an increased pH of 6.12. Diesel range pyrolytic bio-oil distilled from esterified pyrolytic bio-oil had quite comparable properties with commercial diesel, with an energy content of 41.41 MJ/kg, water content of 0.58 wt%, and viscosity of 7.45 cP.

  2. Pyrolytic conversion of lipid feeds for bio-chemical and bio-fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Maher, K.D.; Kirkwood, K.M.; Bressler, D.C. [Alberta Univ., Edmonton, AB (Canada). Dept. of Agricultural, Food and Nutritional Sciences

    2009-07-01

    The production of renewable fuels and chemicals through pyrolysis of lipid feedstock was investigated with particular focus on the effect of unsaturation on thermal cracking behaviour and product distribution. The feasibility of producing deoxygenated liquid hydrocarbons for renewable fuel and chemical applications was studied using oleic acid and linoleic acid as unsaturated model free fatty acids. These were pyrolyzed in 15 mL batch micro-reactors under a nitrogen atmosphere. The analyzed products were compared to previous work investigating pyrolysis of a fully saturated free fatty acid, stearic acids, as well as fatty acids hydrolyzed from animal fats and vegetable oils. The primary reaction in oleic acid pyrolysis was decarboxylation to heptadecene and carbon dioxide, which is consistent with stearic acid pyrolysis. Some hydrogen addition was indicated by the presence of n-heptacecane. Cracking at the double bond was found to be a dominant reaction because only the C9 and lower alkane/alkenes were present in notable concentrations. In addition, the C10-C20 alkanes/alkenes were not easily distinguishable from other compounds that were found to be alkane isomers. The product mixture was highly influenced by reaction temperatures (350-500 degrees C) and time (0.5-8 hours). Lower temperatures and shorter reaction times resulted in low acid conversion. Although higher temperatures and longer reaction times increased conversion, they eventually caused degeneration into aromatic compounds. Pyrolysis of fatty acids from hydrolyzed beef tallow, poultry tallow and canola oil yielded a similar series of alkanes and alkenes where the product distribution was consistent with an additive effect of the constituent saturated and unsaturated fatty acids.

  3. Aluminum doped nickel oxide thin film with improved electrochromic performance from layered double hydroxides precursor in situ pyrolytic route

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Jingjing; Lai, Lincong; Zhang, Ping; Li, Hailong; Qin, Yumei; Gao, Yuanchunxue; Luo, Lei; Lu, Jun, E-mail: lujun@mail.buct.edu.cn

    2016-09-15

    Electrochromic materials with unique performance arouse great interest on account of potential application values in smart window, low-power display, automobile anti-glare rearview mirror, and e-papers. In this paper, high-performing Al-doped NiO porous electrochromic film grown on ITO substrate has been prepared via a layered double hydroxides(LDHs) precursor in situ pyrolytic route. The Al{sup 3+} ions distributed homogenously within the NiO matrix can significantly influence the crystallinity of Ni-Al LDH and NiO:Al{sup 3+} films. The electrochromic performance of the films were evaluated by means of UV–vis absorption spectroscopy, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry(CA) measurements. In addition, the ratio of Ni{sup 3+}/Ni{sup 2+} also varies with Al content which can lead to different electrochemical performances. Among the as-prepared films, NiO film prepared from Ni-Al (19:1) LDH show the best electrochromic performance with a high transparency of 96%, large optical modulation range (58.4%), fast switching speed (bleaching/coloration times are 1.8/4.2 s, respectively) and excellent durability (30% decrease after 2000 cycles). The improved performance was owed to the synergy of large NiO film specific surface area and porous morphology, as well as Al doping stifled the formation of Ni{sup 3+} making bleached state more pure. This LDHs precursor pyrolytic method is simple, low-cost and environmental benign and is feasible for the preparation of NiO:Al and other Al-doped oxide thin film. - Graphical abstract: The ratio of Ni{sup 3+}/Ni{sup 2+} varies with Al content which can lead to different electrochemical performances. Among the as-prepared films, NiO film prepared from Ni-Al (19:1) LDH show the best electrochromic performance with a high transparency of 96%, large optical modulation range, fast switching speed and excellent durability. Display Omitted.

  4. 生物质快速热裂解炭的分析及活化研究%Characterization and Activation of Pyrolytic Char from Fast Pyrolysis

    Institute of Scientific and Technical Information of China (English)

    尹倩倩; 王树荣

    2013-01-01

    采用化学(KOH)方法对两种具有代表性的生物质原料(花梨木和稻壳)的快速热裂解固体产物-热解炭进行了活化,并采用氮吸附、X射线衍射(XRD)、傅里叶红外光谱分析(FTIR)和扫描电镜(SEM)技术测试了热解炭的结构特性、表面特性以及物理化学性质.结果表明,这两种热解炭经过活化后可以获得许多优良的性质,固定碳含量增加,灰分含量减少.同时,活化后BET比表面积迅速增大,超过1100m2/g,而且热解炭的石墨化程度都有所加深.热解炭通过活化过程可以实现其高品质利用,有利于生物质热裂解技术的工业化发展.%The pyrolytic chars from fast pyrolysis of rosewood and rice husk have been activated with KOH solvent. The texture and structure, surface properties and physico-chemical properties of the pyrolytic chars have been characterized by N2 physisorption, X-ray diffraction (XRD), Fourier transform infrared spectroscopy ( FTIR) and Scanning electron microscope ( SEM). Compared with the original pyrolytic chars, the activated chars had higher fixed carbon content and lower ash content. The BET surface area increased beyond 1100m /g after activation. Moreover,the activated chars had higher graphitization degree. Through this activation process, high grade utilization of pyrolytic char will be achieved, as will benefit the industrialization of biomass fast pyrolysis technology.

  5. Significance of the carbonization of volatile pyrolytic products on the properties of activated carbons from phosphoric acid activation of lignocellulosic material

    Energy Technology Data Exchange (ETDEWEB)

    Zuo, Songlin; Yang, Jianxiao; Cai, Xuan [Faculty of Chemical Engineering, Nanjing Forestry University, Nanjing 210037 (China); Liu, Junli [Institute of Chemical Industry of Forest Products, CAF, Nanjing 210042 (China)

    2009-07-15

    Two series of activated carbons derived from China fir (Cunninghamia lanceolata) wood impregnated with phosphoric acid were prepared in a cylindrical container that was kept in a closed state covered with a lid (the covered case) or in an open state. The effects of the carbonization of volatile pyrolytic products of starting materials on the properties of activated carbon were investigated in the process of phosphoric acid activation. Elemental analysis and SEM observation showed that both activating in the covered case and increasing the mass of starting material used favored the carbonization of volatile pyrolytic products. An investigation of N{sub 2} adsorption isotherms revealed that the carbonization of volatile pyrolytic products significantly enhanced mesopore development in the final carbons, especially pores with a size range from 2.5 to 30 nm, with little influence on micropores, and therefore produced a large increase in the adsorption capacity to Vitamin B12 (with a molecular size of 2.09 nm). Activated carbons with highly developed mesopores could be obtained in the covered case. The carbonization mechanism of volatiles was discussed and two different carbonization pathways (in solid and gas phases) were proposed during phosphoric acid activation. (author)

  6. Thermal Behavior and Kinetics of Raw/Pyrolytic Wood and Coal Blends during Co-combustion Process

    Institute of Scientific and Technical Information of China (English)

    Jian DING; Qing-cai LIU; Li-jun JIANG; Guo-qing LIU; Shan REN; Jian YANG; Lu YAO; Fei MENG

    2016-01-01

    The thermal properties of raw wood (RW)biomass,corresponding pyrolytic wood (PW)biomass,and their blends with anthracite coal (AC)were evaluated under combustion conditions with a thermogravimetric analysis (TGA)method.The blending ratios of the biomass with AC ranging from 0 to 100 mass% were taken into consider-ation to investigate the thermal behavior and kinetics of these blends during their co-combustion.For blends with dif-ferent ratios of the RW to AC and 100% AC (100 AC),two distinct mass loss peaks related to the release or com-bustion process of the volatiles and the combustion of the char were noted.The addition of a higher ratio of RW or PW into AC can improve the combustion process of the blends.The thermal behavior of the RW/AC or PW/AC blends could not be characterized by a simple linear correlation of their pure material thermal behavior.With the RW/PW addition ratios varying from 25 mass% to 80 mass%,the apparent activation energy of the blends gradually decreased from 48.46 to 34.93 kJ/mol and from 82.74 to 37.81 kJ/mol for the RW/AC and PW/AC blends,re-spectively,with high correlation coefficient (R2 )values ranging from 0.995 6 to 0.998 4.

  7. Performance of a proton exchange membrane fuel cell stack with thermally conductive pyrolytic graphite sheets for thermal management

    Energy Technology Data Exchange (ETDEWEB)

    Wen, Chih-Yung; Lin, Yu-Sheng; Lu, Chien-Heng [Department of Aeronautics and Astronautics, National Cheng-Kung University, Tainan 70101 (China)

    2009-04-15

    This work experimentally investigates the effects of the pyrolytic graphite sheets (PGS) on the performance and thermal management of a proton exchange membrane fuel cell (PEMFC) stack. These PGS with the features of light weight and high thermal conductivity serve as heat spreaders in the fuel cell stack for the first time to reduce the volume and weight of cooling systems, and homogenizes the temperature in the reaction areas. A PEMFC stack with an active area of 100 cm{sup 2} and 10 cells in series is constructed and used in this research. Five PGS of thickness 0.1 mm are cut into the shape of flow channels and bound to the central five cathode gas channel plates. Four thermocouples are embedded on the cathode gas channel plates to estimate the temperature variation in the stack. It is shown that the maximum power of the stack increase more than 15% with PGS attached. PGS improve the stack performance and alleviate the flooding problem at low cathode flow rates significantly. Results of this study demonstrate the feasibility of application of PGS to the thermal management of a small-to-medium-sized fuel cell stack. (author)

  8. Axial Ligand Effects on the Structures of Self-Assembled Gallium-Porphyrin Monolayers on Highly Oriented Pyrolytic Graphite.

    Science.gov (United States)

    Kamm, Judith M; Iverson, Cameron P; Lau, Wing-Yeung; Hopkins, Michael D

    2016-01-19

    Monolayers of five-coordinate gallium octaethylporphyrin complexes (Ga(OEP)X; X = Cl, Br, I, O3SCF3, CCPh) on highly oriented pyrolytic graphite were studied at the solid-liquid (1-phenyloctane) interface using scanning tunneling microscopy (STM) to probe the dependence of their properties on the nature of the axial X ligand. Density functional theory calculations of the gas-phase structures of the free molecules reveal that the gallium atom is positioned above the plane of the porphyrin macrocycle, with this pyramidal distortion increasing in magnitude according to X = O3SCF3 (displacement = 0.35 Å) monolayers are sensitive to the nature of the axial ligand: the monolayers of Ga(OEP)(O3SCF3) and Ga(OEP)(CCPh) exhibit damage during the STM experiment upon repeated scanning and upon toggling the sign of the bias potential, but monolayers of Ga(OEP)Cl, Ga(OEP)Br, and Ga(OEP)I do not. A second important ligand-influenced property is that Ga(OEP)I forms bilayer structures, whereas the other Ga(OEP)X compounds form monolayers exclusively under identical conditions. The top layer of the Ga(OEP)I bilayer is oriented with the iodo ligand directed away from the surface, like the bottom layer, but the molecules pack in a square, lower-density geometry. The comparatively large polarizability of the iodo ligand is suggested to be important in stabilizing the bilayer structure.

  9. Electrochemical modification of a pyrolytic graphite sheet for improved negative electrode performance in the vanadium redox flow battery

    Science.gov (United States)

    Kabir, Humayun; Gyan, Isaiah O.; Francis Cheng, I.

    2017-02-01

    The vanadium redox flow battery is a promising technology for buffering renewable energies. It is recognized that negative electrode is the limitation in this device where there are problems of slow heterogeneous electron transfer (HET) of V3+/2+ and parasitic H2 evolution. Any methods aimed at addressing one of these barriers must assess the effects on the other. We examine electrochemical enhancement of a common commercially available material. Treatment of Panasonic pyrolytic graphite sheets is through oxidation at 2.1 V vs. Ag/AgCl for 1 min in 1 M H2SO4. This increases the standard HET rate for V3+/2+ from 3.2 × 10-7 to 1 × 10-3 cm/s, one of the highest in literature and shifts voltammetric reductive peak potential from -1.0 V to -0.65 V in 50 mM V3+ in 1 M H2SO4. Infrared analysis of the surfaces indicates formation of Csbnd OH, Cdbnd O, and Csbnd O functionalities. These groups catalyze HET with V3+/2+ as hypothesized by Skyllas-Kasacos. Also of significance is that electrode modification decreases the fraction of the current directed towards H2 evolution. This proportion decreases by two orders of a magnitude from 12% to 0.1% as measured at the respective voltammetric peak potentials of -1.0 V (pristine) and -0.65 V (modified).

  10. Influence of ZSM-5 zeolite on the pyrolytic intermediates from the co-pyrolysis of pubescens and LDPE

    Energy Technology Data Exchange (ETDEWEB)

    Liu Wenwu [Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064 (China); Hu Changwei, E-mail: gchem@scu.edu.c [Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064 (China); Yang Yu; Tong Dongmei; Li Guiying; Zhu Liangfang [Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064 (China)

    2010-05-15

    The catalytic reforming of the pyrolytic intermediates from the co-pyrolysis of pubescens and LDPE over the parent and desilicated zeolite ZSM-5 (DeZSM-5) was investigated. The results showed that the parent HZSM-5 exhibited high aromatization activity in the co-pyrolysis, whereas DeZSM-5 exhibited high alkanisation activity. On the other hand, the total relative content of phenolic compounds in aqua obtained by co-pyrolysis catalyzed by both parent HZSM-5 and DeZSM-5 was rather high (60-65%) compared to the thermal co-pyrolysis (26.94%). From the analysis of NH{sub 3}-TPD for ZSM-5, it might be proposed that the aromatization was favored mainly by strong acid sites and the alkanisation was favored chiefly by weak acid sites in catalyst ZSM-5. In addition, the formation of phenolic compounds was mainly related to the interactions between the intermediates from the co-pyrolysis over ZSM-5.

  11. The pyrolytic-plasma method and the device for the utilization of hazardous waste containing organic compounds.

    Science.gov (United States)

    Opalińska, Teresa; Wnęk, Bartłomiej; Witowski, Artur; Juszczuk, Rafał; Majdak, Małgorzata; Bartusek, Stanilav

    2016-11-15

    This paper is focused on the new method of waste processing. The waste, including hazardous waste, contain organic compounds. The method consists in two main processes: the pyrolysis of waste and the oxidation of the pyrolytic gas with a use of non-equilibrium plasma. The practical implementation of the method requires the design, construction and testing of the new device in large laboratory scale. The experiments were carried out for the two kinds of waste: polyethylene as a model waste and the electronic waste as a real waste. The process of polyethylene decomposition showed that the operation of the device is correct because 99.74% of carbon moles contained in the PE samples was detected in the gas after the process. Thus, the PE samples practically were pyrolyzed completely to hydrocarbons, which were completely oxidized in the plasma reactor. It turned out that the device is useful for decomposition of the electronic waste. The conditions in the plasma reactor during the oxidation process of the pyrolysis products did not promote the formation of PCDD/Fs despite the presence of the oxidizing conditions. An important parameter determining the efficiency of the oxidation of the pyrolysis products is gas temperature in the plasma reactor.

  12. Insight into STM image contrast of n-tetradecane and n-hexadecane molecules on highly oriented pyrolytic graphite

    Science.gov (United States)

    Zhao, Miao; Jiang, Peng; Deng, Ke; Yu, Ai-Fang; Hao, Yan-Zhong; Xie, Si-Shen; Sun, Jie-Lin

    2011-02-01

    Two-dimensional ordered patterns of n-tetradecane (n-C14H30) and n-hexadecane (n-C16H34) molecules at liquid/graphite interface have been directly imaged using scanning tunneling microscope (STM) under ambient conditions. STM images reveal that the two different kinds of molecules self-organize into ordered lamellar structures in which alkane chains of the molecules extend along one of three equivalent lattice axes of highly oriented pyrolytic graphite (HOPG) basal plane. For n-C14H30 molecules, the molecular axes are observed to tilt by 60° with respect to inter-lamellar trough lines and the carbon backbones of the alkane chains are perpendicular to the HOPG basal plane in an all-trans conformation. However, for n-C16H34 molecules, the molecular axes are perpendicular to lamellar borders (90°) and the planes of the all-trans carbon skeletons are parallel to the graphite basal plane. The results clearly indicate that outmost hydrogen atoms of the alkane chains dominate atom-scaled features of the STM images. That is, in the case of long-chain alkane molecules, topographic effects dominantly determine STM image contrast of the methylene regions of the alkane chains that are adsorbed on HOPG.

  13. Tritium permeation behavior through pyrolytic carbon in tritium production using high-temperature gas-cooled reactor for fusion reactors

    Directory of Open Access Journals (Sweden)

    H. Ushida

    2016-12-01

    Full Text Available Under tritium production method using a high-temperature gas-cooled reactor loaded Li compound, Li compound has to be coated by ceramic materials in order to suppress the spreading of tritium to the whole reactor. Pyrolytic carbon (PyC is a candidate of the coating material because of its high resistance for gas permeation. In this study, hydrogen permeation experiments using a PyC-coated isotropic graphite tube were conducted and hydrogen diffusivity, solubility and permeability were evaluated. Tritium permeation behavior through PyC-coated Li compound particles was simulated by using obtained data. Hydrogen permeation flux through PyC in a steady state is proportional to the hydrogen pressure and is larger than that through Al2O3 which is also candidate coating material. However, total tritium leak within the supposed reactor operation period through the PyC-coated Li compound particles is lower than that through the Al2O3-coated ones because the hydrogen absorption capacity in PyC is considerably larger than that in Al2O3.

  14. Peanut Oil

    Science.gov (United States)

    ... and baby care products. Sometimes the less expensive soya oil is added to peanut oil. ... are pregnant or breast-feeding. Allergy to peanuts, soybeans, and related plants: Peanut oil can cause serious ...

  15. Oil Spills

    Science.gov (United States)

    Oil spills often happen because of accidents, when people make mistakes or equipment breaks down. Other causes include natural disasters or deliberate acts. Oil spills have major environmental and economic effects. Oil ...

  16. The effect of pyrolytic carbon black prepared from junked tires on the properties of ethylene-propylene-diene copolymers (EPDM

    Directory of Open Access Journals (Sweden)

    2009-05-01

    Full Text Available Pyrolytic carbon black (PCB made from used tires was used in ethylene-propylene-diene copolymers (EPDM. The microstructure of PCB was characterized by scanning electron microscopy (SEM. PCB was compounded with EPDM to prepare EPDM vulcanizates. The effects of PCB on the processing properties of EPDM compounds and the mechanical properties of vulcanizates were investigated and compared with other traditional fillers such as semi-reinforcing furnace black (N774, light calcium carbonate (CaCO3 and thermal black (N990. At the same time, the rheological behavior of EPDM compounds filled with different fillers was characterized by capillary rheometrics. The SEM photos showed that the particle shape was quiet different from that of CaCO3 and N990, it was similar to that of N774. The primary particle size was smaller than that of N774, but the aggregate size of PCB was larger than that of N774. The effect of PCB on the processing properties of EPDM compounds was similar to that of other fillers. Among the four fillers, PCB imparted EPDM compounds with higher Mooney viscosity. With the increase of filler content, the scorch time and optimum curing time of EPDM compounds changed little. The reinforcing effect of PCB was similar to that of N990, but inferior to that of N774. With the increase of PCB content, tensile strength, tear strength, and modulus at 100% elongation of EPDM vulcanizates increased significantly. When EPDM was filled with 50 phr PCB, the tear strength of EPDM vulcanizates increased by 3 times, compared with that of EPDM gum vulcanizates. The appearance of EPDM extrudate filled with PCB was coarser than that of other fillers.

  17. Comparative effects of pyrolytic products of fiber reinforced plastic and wood shavings on the respiratory variables in mice.

    Science.gov (United States)

    Kumar, Pravin; Deb, Utsab; Gautam, Anshoo; Vijayaraghavan, R; Ratna, Debdatta; Chakraborty, B C

    2010-08-01

    Comparative inhalation toxicity studies of pyrolytic products (smoke) from synthetic polymer, fiberglass reinforced plastic (FRP) and teak wood shavings were carried out in male Swiss albino mice. The breathing pattern and the respiratory variables were monitored using a computer program that recognizes the modifications of the respiratory pattern. Exposure to the smoke from both the polymers caused a concentration dependent decrease in normal breathing and an increase in sensory irritation measure. The acute lethal concentration 50 values for a 15 min static inhalation exposure to the smoke from FRP and teak wood shavings were found to be > 200.00 and 62.99 g/m(3), respectively. Hence the inhalation toxicity of smoke from FRP sample on a mass basis is approximately one-third that of the smoke from teak wood. The concentration of smoke causing 50% respiratory depression of the exposed animals were found to be 6.877 and 0.106 g/m(3) for FRP and teak wood samples, respectively. Thus the sensory irritancy of the smoke from FRP sample is approximately 65 times lesser than the smoke from teak wood. The higher sensory irritancy potential of wood smoke as compared to FRP smoke may be caused by a greater number of submicron particles (size range of 2 micron and less) and greater percentage of gases present in wood smoke as compared to FRP smoke. Thus in case of accidental fires, synthetic polymers like FRP may be a safer choice for structural parts and interiors than the natural wood.

  18. Spectroscopic investigation of the wettability of multilayer graphene using highly ordered pyrolytic graphite as a model material.

    Science.gov (United States)

    Ashraf, Ali; Wu, Yanbin; Wang, Michael C; Aluru, Narayana R; Dastgheib, Seyed A; Nam, SungWoo

    2014-11-04

    We report the intrinsic water contact angle (WCA) of multilayer graphene, explore different methods of cleaning multilayer graphene, and evaluate the efficiency of those methods on the basis of spectroscopic analysis. Highly ordered pyrolytic graphite (HOPG) was used as a model material system to study the wettability of the multilayer graphene surface by WCA measurements. A WCA value of 45° ± 3° was measured for a clean HOPG surface, which can serve as the intrinsic WCA for multilayer graphene. A 1 min plasma treatment (100 W) decreased the WCA to 6°, owing to the creation of surface defects and functionalization by oxygen-containing groups. Molecular dynamics simulations of water droplets on the HOPG surface with or without the oxygen-containing defect sites confirmed the experimental results. Heat treatment at near atmospheric pressure and wet chemical cleaning methods using hydrofluoric acid and chloroform did not change the WCA significantly. Low-pressure, high-temperature annealing under argon and hydrogen reduced the WCA to 54°, close to the intrinsic WCA of HOPG. Raman spectroscopy and atomic force microscopy did not show any significant change for the HOPG surface after this treatment, confirming low-pressure, high-temperature annealing as an effective technique to clean multilayer graphene without damaging the surface. Time-of-flight secondary ion mass spectrometry indicated the existence of hydrocarbon species on the surface of the HOPG sample that was exposed to air for surfaces after the different cleaning techniques were performed to correlate the WCA to the surface chemistry. X-ray photoelectron spectroscopy results revealed that the WCA value changed drastically, depending on the amounts of oxygen-containing and hydrocarbon-containing groups on the surface.

  19. Nano-level monitoring of Mn(2+) ion by fabrication of coated pyrolytic graphite electrode based on isonicotinohydrazide derivatives.

    Science.gov (United States)

    Sahani, Manoj Kumar; Singh, A K; Jain, A K

    2015-05-01

    The two ionophores N'(N',N‴E,N',N‴E)-N',N‴-((((oxybis(ethane-2,1-diyl))bis(oxy)) bis(2,1-phenylene))bis(methanylylidene))di(isonicotinohydrazide) (I1) and (N',N‴E,N',N‴E)-N',N‴-(((propane-1,3-diylbis(oxy))bis(2,1-phenylene))bis(methanylylidene))di(isonicotinohydrazide) (I2) were synthesised and investigated as neutral carrier in the fabrication of Mn(2+) ion selective sensor. Several membranes were prepared by incorporating different plasticizers and anionic excluders and their effect on potentiometric response was studied. The best analytical performance was obtained with the electrode having a membrane of composition of I2: PVC: o-NPOE: NaTPB in the ratio of 6:34:58:2 (w/w, mg). Comparative studies of coated graphite electrode (CGE) and coated pyrolytic graphite electrode (CPGE) based on I2 reveal the superiority of CPGE. The CPGE exhibits wide working concentration range of 1.23×10(-8)-1.0×10(-1) mol L(-1) and a detection limit down to 4.78×10(-9) mol L(-1) with a Nernstian slope of 29.5±0.4 mV decade(-1) of activity. The sensor performs satisfactorily over a wide pH range (3.5-9.0) and exhibited a quick response time (9s). The sensor can work satisfactorily in water-acetonitrile and water-methanol mixtures. It can tolerate 30% acetonitrile and 20% methanol content in the mixtures. The sensor could be used for a period of four months without any significant divergence in performance. The sensor reflects its utility in the quantification of Mn(2+) ion in real samples and has been successfully employed as an indicator electrode in the potentiometric titration of Mn(2+) ion with ethylenediaminetetraacetic acid (EDTA).

  20. Oil risk in oil stocks

    NARCIS (Netherlands)

    Scholtens, Bert; Wang, L

    2008-01-01

    We assess the oil price sensitivities and oil risk premiums of NYSE listed oil & gas firms' returns by using a two-step regression analysis under two different arbitrage pricing models. Thus, we apply the Fama and French (1992) factor returns in a study of oil stocks. In all, we find that the return

  1. Oil risk in oil stocks

    NARCIS (Netherlands)

    Scholtens, Bert; Wang, L

    2008-01-01

    We assess the oil price sensitivities and oil risk premiums of NYSE listed oil & gas firms' returns by using a two-step regression analysis under two different arbitrage pricing models. Thus, we apply the Fama and French (1992) factor returns in a study of oil stocks. In all, we find that the return

  2. Results of the International Energy Agency Round Robin on Fast Pyrolysis Bio-oil Production

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Meier, Dietrich; Oasmaa, Anja; van de Beld, Bert; Bridgwater, Anthony V.; Marklund, Magnus

    2017-04-06

    An international round robin study of the production of fast pyrolysis bio-oil was undertaken. Fifteen institutions in six countries contributed. Three biomass samples were distributed to the laboratories for processing in fast pyrolysis reactors. Samples of the bio-oil produced were transported to a central analytical laboratory for analysis. The round robin was focused on validating the pyrolysis community understanding of production of fast pyrolysis bio-oil by providing a common feedstock for bio-oil preparation. The round robin included: •distribution of 3 feedstock samples from a common source to each participating laboratory; •preparation of fast pyrolysis bio-oil in each laboratory with the 3 feedstocks provided; •return of the 3 bio-oil products (minimum 500 ml) with operational description to a central analytical laboratory for bio-oil property determination. The analyses of interest were: density, viscosity, dissolved water, filterable solids, CHN, S, trace element analysis, ash, total acid number, pyrolytic lignin, and accelerated aging of bio-oil. In addition, an effort was made to compare the bio-oil components to the products of analytical pyrolysis through GC/MS analysis. The results showed that clear differences can occur in fast pyrolysis bio-oil properties by applying different reactor technologies or configurations. The comparison to analytical pyrolysis method suggested that Py-GC/MS could serve as a rapid screening method for bio-oil composition when produced in fluid-bed reactors. Furthermore, hot vapor filtration generally resulted in the most favorable bio-oil product, with respect to water, solids, viscosity, and total acid number. These results can be helpful in understanding the variation in bio-oil production methods and their effects on bio-oil product composition.

  3. Photodeposition of Gold, Platinum, or Silver onto Titanium Dioxide Nanoparticles at Steps of Highly Oriented Pyrolytic Graphite

    Science.gov (United States)

    Taing, James

    The photodeposition of gold, platinum, or silver nanoparticles selectively onto isolated titanium dioxide (TiO2) nanoparticles created metal/TiO2 photocatalysts and heterogeneous catalysts, and validated the photocatalytic property of the semiconductor. The isolated and ordered TiO2 nanoparticles permitted clear observations of the stability, and changes in morphology, of the particles in various experimental conditions. The fabrication of TiO2 nanoparticles at the steps of highly oriented pyrolytic graphite (HOPG), utilizing physical vapor deposition, required heating the graphite substrate to a minimum of 800 °C. The production of a photocurrent, and plating of gold nanoparticles, confirmed the photocatalytic property of the TiO2 nanoparticles on HOPG when utilized as a photoelectrode in a two half-cell setup. Employing sodium chloride (1.0 M) as an electrolyte resulted in an increase/decrease of the photocurrent with the addition of gold cations to the half-cell without/with the TiO2 nanoparticles. A poor distribution of gold nanoparticles, roughly 40-45 nm wide, deposited around few of the TiO2 nanoparticles. A lower concentration of sodium chloride (0.1 M) resulted in a coalescence of Au nanoparticles, roughly 10 nm, around many TiO2 nanoparticles. Using sodium nitrate as an electrolyte resulted in a rapid decay in the photocurrent and a growth of an unidentified material on the TiO2 nanoparticles. The unidentified material hindered the reduction of gold cations introduced midway through the experiment. With gold cations present at the onset of the experiment, disperse gold nanoparticles (˜5-10 nm) deposited around the TiO2 nanoparticles. In the absence of additional electrolyte, many disperse gold nanoparticles less than 5 nm deposited onto the TiO2 nanoparticles. More platinum than gold selectively deposited onto the TiO2 nanoparticles. On the contrary, less silver selectively deposited onto the TiO2 nanoparticles. Scanning electron microscopy and atomic

  4. Prospective framework for collection and exploitation of waste cooking oil as feedstock for energy conversion

    Energy Technology Data Exchange (ETDEWEB)

    Singhabhandhu, Ampaitepin; Tezuka, Tetsuo [Energy Economics Laboratory, Department of Socio-Environmental Energy Science, Graduate School of Energy Science, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501 (Japan)

    2010-04-15

    From the viewpoint of waste-to-energy, waste cooking oil is one of the attractive and available recycled feedstocks, apart from agricultural residues. The generation of energy from waste cooking oil is considered as an effective technique for waste management, as well as a beneficial form of energy recovery. Two alternative systems and a conventional system of waste cooking oil collection and conversion are evaluated by the cost benefit analysis in order to find a suitable method for waste-to-energy conversion. The results show that the collection of waste cooking oil with waste lubricating oil (System II) a useful alternative to the management of waste cooking oil (B/C > 1). The total heat produced by the combustion of pyrolytic oil at maximum and minimum conversion rates is also determined. The separate collection of waste cooking oil, subjected to chemical pre-treatment prior to introduction in a pyrolysis reactor (System III), is considered an undesirable option (B/C < 1) due to the cost of the chemicals involved. Although the exclusion of chemical pre-treatment makes System III a desirable option, the total amount of heat of combustion generated is less. The increased electricity cost required for the process has no effect on the benefit-cost ratio of System II. However, System III, excluding chemical pre-treatment, becomes an unprofitable alternative when the electricity cost reaches 100% of the fixed capital cost at the minimum conversion rate. (author)

  5. Theoretical Study on Gas—phase Pyrolytic Reactions of N—Ethyl,Isopropyl and N—t—Butyl Substituted 2—Aminopyrazine

    Institute of Scientific and Technical Information of China (English)

    洪三国; 陈丽萍

    2003-01-01

    Density functional theory(DFT)and ab initio methods were used to study gas-phase pyrolytic reaction mechanisms of N-ethyl,N-isopropyl and N-t-butyl substituted 2-aminopyrazine at B3LYP/6-31G* and MP2/6-31G*,respectively,Single-point energies of all optimized molecular geometries were calculated at B3LYP/6-311 G(2d,p)level.Results show that the pyrolytic reactions which were caused by the migration of atom H(17) via a six-member ring transiton state.The activation energies which were verified by vibrational analysis and correlated with zero-point energies along the reaction channel atB3LYP/6-3110 G(2d,p)level were 252.02kJ·mol-1(N-ethyl substituted),235.92kJ·mol-1(N-isopropyl substituted)and 234.27kJ·mol-1(N-t-butyl substituted),respectively.The results were in good agreement with available experimental data.

  6. Electrocatalytic activity of 2,3,5,6-tetrachloro-1,4-benzoquinone/multi-walled carbon nanotubes immobilized on edge plane pyrolytic graphite electrode for NADH oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Cassia Silva Luz, Rita de [Institute of Chemistry, UNICAMP, P.O. Box 6154, 13084-971, Campinas, SP (Brazil)], E-mail: rcsluz@iqm.unicamp.br; Damos, Flavio Santos [Institute of Chemistry, UNICAMP, P.O. Box 6154, 13084-971, Campinas, SP (Brazil); Tanaka, Auro Atsushi [Center of Science and Technology, UFMA, Avenida dos Portugueses s/n, 65085-040, Sao Luis, MA (Brazil); Kubota, Lauro Tatsuo; Gushikem, Yoshitaka [Institute of Chemistry, UNICAMP, P.O. Box 6154, 13084-971, Campinas, SP (Brazil)

    2008-05-30

    This work reports the electrocatalytic activity of 2,3,5,6-tetrachloro-1,4-benzoquinone (TCBQ)/multi-walled carbon nanotubes (MWCNT) immobilized on an edge plane pyrolytic graphite electrode for nicotinamide adenine dinucleotide (NADH) oxidation. Scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS) were used to confirms the presence of chloro after the nanotube modification with 2,3,5,6-tetrachloro-1,4-benzoquinone. The surface charge transfer constant, k{sub s}, and the charge transfer coefficient for the modified electrode, {alpha}, were estimated as 98.5 ({+-}0.6) s{sup -1} and 0.5, respectively. With this modified electrode the oxidation potential of the NADH was shifted about 300 mV toward a less positive value, presenting a peak current much higher than those measured on an unmodified edge plane pyrolytic graphite electrode (EPPG). Cyclic voltammetry and rotating disk electrode (RDE) experiments indicated that the NADH oxidation reaction involves 2 electrons and a heterogenous rate constant (k{sub obs}) of 3.1 x 10{sup 5} mol{sup -1} l s{sup -1}. The detection limit, repeatability, long-term stability, time of response and linear response range were also investigated.

  7. Petroleum Oils

    Science.gov (United States)

    Different types of crude oil and refined product, of all different chemical compositions, have distinct physical properties. These properties affect the way oil spreads and breaks down, its hazard to marine and human life, and the likelihood of threat.

  8. Oil spills

    National Research Council Canada - National Science Library

    Moghissi, A.A

    1980-01-01

    Contents: Oil spills on land as potential sources of groundwater contamination / J.J. Duffy, E. Peake and M.F. Mohtadi -- Ecological effects of experimental oil spills in eastern coastal plain estuaries...

  9. Oil Shale

    Science.gov (United States)

    Birdwell, Justin E.

    2017-01-01

    Oil shales are fine-grained sedimentary rocks formed in many different depositional environments (terrestrial, lacustrine, marine) containing large quantities of thermally immature organic matter in the forms of kerogen and bitumen. If defined from an economic standpoint, a rock containing a sufficient concentration of oil-prone kerogen to generate economic quantities of synthetic crude oil upon heating to high temperatures (350–600 °C) in the absence of oxygen (pyrolysis) can be considered an oil shale.

  10. Mineral oils

    Science.gov (United States)

    Furby, N. W.

    1973-01-01

    The characteristics of lubricants made from mineral oils are discussed. Types and compositions of base stocks are reviewed and the product demands and compositions of typical products are outlined. Processes for commercial production of mineral oils are examined. Tables of data are included to show examples of product types and requirements. A chemical analysis of three types of mineral oils is reported.

  11. Oil biodegradation

    NARCIS (Netherlands)

    Rahsepar, Shokouhalsadat; Langenhoff, Alette A.M.; Smit, Martijn P.J.; Eenennaam, van Justine S.; Murk, Tinka; Rijnaarts, Huub H.M.

    2017-01-01

    During the Deepwater Horizon (DwH) oil spill, interactions between oil, clay particles and marine snow lead to the formation of aggregates. Interactions between these components play an important, but yet not well understood, role in biodegradation of oil in the ocean water. The aim of this study

  12. Enhanced diesel fuel fraction from waste high-density polyethylene and heavy gas oil pyrolysis using factorial design methodology.

    Science.gov (United States)

    Joppert, Ney; da Silva, Alexsandro Araujo; da Costa Marques, Mônica Regina

    2015-02-01

    Factorial Design Methodology (FDM) was developed to enhance diesel fuel fraction (C9-C23) from waste high-density polyethylene (HDPE) and Heavy Gas Oil (HGO) through co-pyrolysis. FDM was used for optimization of the following reaction parameters: temperature, catalyst and HDPE amounts. The HGO amount was constant (2.00 g) in all experiments. The model optimum conditions were determined to be temperature of 550 °C, HDPE = 0.20 g and no FCC catalyst. Under such conditions, 94% of pyrolytic oil was recovered, of which diesel fuel fraction was 93% (87% diesel fuel fraction yield), no residue was produced and 6% of noncondensable gaseous/volatile fraction was obtained. Seeking to reduce the cost due to high process temperatures, the impact of using higher catalyst content (25%) with a lower temperature (500 °C) was investigated. Under these conditions, 88% of pyrolytic oil was recovered (diesel fuel fraction yield was also 87%) as well as 12% of the noncondensable gaseous/volatile fraction. No waste was produced in these conditions, being an environmentally friendly approach for recycling the waste plastic. This paper demonstrated the usefulness of using FDM to predict and to optimize diesel fuel fraction yield with a great reduction in the number of experiments.

  13. Impact of biochar produced from post-harvest residue on the adsorption behavior of diesel oil on loess soil.

    Science.gov (United States)

    Jiang, Yu Feng; Sun, Hang; Yves, Uwamungu J; Li, Hong; Hu, Xue Fei

    2016-02-01

    The primary objective of this study was to investigate the effect of biochar, produced from wheat residue at different temperatures, on the adsorption of diesel oil by loess soil. Kinetic and equilibrium data were processed to understand the adsorption mechanism of diesel by biochar-affected loess soil; dynamic and thermodynamic adsorption experiments were conducted to characterize this adsorption. The surface features and chemical structure of biochar, modified at varying pyrolytic temperatures, were investigated using surface scanning electron microscopy and Fourier transform infrared analysis. The kinetic data showed that the adsorption of diesel oil onto loess soil could be described by a pseudo-second-order kinetic model, with the rate-controlling step being intraparticle diffusion. However, in the presence of biochar, boundary layer control and intraparticle diffusion were both involved in the adsorption. Besides, the adsorption equilibrium data were well described by the Freundlich isothermal model. The saturated adsorption capacity weakened as temperature increased, suggesting a spontaneous exothermic process. Thermodynamic parameter analysis showed that adsorption was mainly a physical process and was enhanced by chemical adsorption. The adsorption capacity of loess soil for diesel oil was weakened with increasing pH. The biochar produced by pyrolytic wheat residue increased the adsorption behavior of petroleum pollutants in loess soil.

  14. Molecular orientation of copper phthalocyanine thin films on different monolayers of fullerene on SiO{sub 2} or highly oriented pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Chenggong; Wang, Congcong [Department of Physics and Astronomy, University of Rochester, Rochester, New York 14627 (United States); Liu, Xiaoliang [Institute for Super-microstructure and Ultrafast Process in Advanced Materials (ISUPAM), Central South University, Changsha, Hunan 410083 (China); Xu, Xumei; Li, Youzhen [School of Physics and Electronics, Central South University, Changsha, Hunan 410083 (China); Xie, Fangyan [Instrumental Analysis Center, Sun Yat-Sen University, Guangzhou 510275 (China); Gao, Yongli [Department of Physics and Astronomy, University of Rochester, Rochester, New York 14627 (United States); Institute for Super-microstructure and Ultrafast Process in Advanced Materials (ISUPAM), Central South University, Changsha, Hunan 410083 (China)

    2015-03-23

    The interface electronic structures of copper phthalocyanine (CuPc) have been studied using ultraviolet photoemission spectroscopy as different monolayers of C{sub 60} were inserted between CuPc and a SiO{sub 2} or highly ordered pyrolytic graphite (HOPG) substrate. The results show that CuPc has standing up configuration with one monolayer of C{sub 60} insertion on SiO{sub 2} while lying down on HOPG, indicating that the insertion layer propagates the CuPc-substrate interaction. Meanwhile, CuPc on more than one monolayers of C{sub 60} on different substrates show that the substrate orientation effect quickly vanished. Our study elucidates intriguing molecular interactions that manipulate molecular orientation and donor-acceptor energy level alignment.

  15. FAST PYROLYSIS – EFFECT OF WOOD DRYING ON THE YIELD AND PROPERTIES OF BIO-OIL

    Directory of Open Access Journals (Sweden)

    Eriks Samulis

    2007-11-01

    Full Text Available The composition and properties of the products of fast pyrolysis of hardwood, obtained in a two-chamber (drying and pyrolytic ablation type reactor in the temperature range 450-600ºС, were investigated. It has been found that, upon the additional drying of wood at 200ºС and subsequent pyrolysis, the quality of bio-oil is improved owing to the decrease in the amount of water and acids. It has been shown that the increase of the drying temperature to 240ºС decreases the yield of the main product. Optimum parameters of the drying conditions and the temperature of the pyrolysis of wood, at which the bio-oil yield exceeds 60% and its calorific value makes up 17-20 МJ/kg, have been determined.

  16. Antidiabetic oils.

    Science.gov (United States)

    Berraaouan, Ali; Abid, Sanae; Bnouham, Mohamed

    2013-11-01

    Many studies have demonstrated evidence of the health benefits of natural products. Plant extracts have been tested on a variety of physiological disorders, including diabetes mellitus. Studies have tested aqueous extracts, plant fractions extracts, families of active of compounds, and specific active compounds. In this review, we describe the antidiabetic effects of vegetable oils. Information was collected from ScienceDirect and PubMed databases using the following key words: Diabetes mellitus, Oils, Vegetable oils, Type 1 diabetes, type 2 diabetes, antidiabetic effect, antihyperglycemic, antidiabetic oil. We have compiled approximately ten vegetable oils with including experimental studies that have demonstrated benefits on diabetes mellitus. There are soybean, argan, olive, palm, walnut, black cumin, safflower, Colocynth, Black seed, Rice bran, Cinnamom, and Rocket oils. For each vegetable oil, we investigated on the plant's traditional uses, their pharmacological activities and their antidiabetic effects. It seems that many vegetable oils are really interesting and can be used in the improvement of human health, particularly, to prevent or to treat diabetes mellitus complications.

  17. Coconut Oil

    Science.gov (United States)

    ... immune system. Despite coconut oil's high calorie and saturated fat content, some people use it by mouth to ... Coconut oil is high in a saturated fat called medium chain triglycerides. These fats work differently than other types of saturated fat in the body. However, research on the effects ...

  18. Experimental Study of the Quick Pyrolysis of Enteromorpha Clathrata to Prepare Bio-oil Under Various Conditions%不同工况下条浒苔的快速热裂解制取生物油试验研究

    Institute of Scientific and Technical Information of China (English)

    王爽; 姜秀民; 王谦; 吉恒松

    2013-01-01

    Studied was the quick pyrolytic process of the seaweed substance and its kind ( Enteromorpha clathrata) and analyzed was the law governing the influence of various conditions on the pyrolytic characteristics. The pyrolytic reaction temperature has certain influence on the Enteromorpha clathrata bio-oil productivity. To heighten the reaction temperature can be favorable to the formation of pyrolytic gases but unfavorable to the formation of carbon. At around 500 ℃,there exists a maximum oil productivity. The residence time (carrier gas flow rate) has little influence on the seaweed bio-oil productivity. To reduce the residence time can slightly increase the bio-oil productivity. To heighten the pyrolytic reaction temperature can lower the proportion of the volatile in the carbon produced in the py-tolytic process but the proportion of the fixed carbon will increase, indicating that at a relatively high temperature, there will be more volatile substances to be precipitated. The testing results show that compared with common bio-mass on land, the seaweed bio-oil has a relatively high hydrocarbon content and a relatively low oxygen content.%分析了不同工况下海藻类生物质(条浒苔)的快速热裂解过程,研究了其热裂解特性的规律.热解反应温度对条浒苔生物油的产率有一定影响,在500℃左右存在最大产油率.停留时间(载气流量)对海藻生物油产率影响不大.停留时间减少,生物油产率略有提高.热解反应温度升高,热解生成炭中挥发分的比例下降,而固定碳的比例则增加,这说明在较高温度时有更多的挥发分析出.检测结果表明,海藻类生物油相比陆上一般生物质油具有较高的碳氢含量,较低的含氧量的优点.

  19. The waste-to-energy framework for integrated multi-waste utilization: Waste cooking oil, waste lubricating oil, and waste plastics

    Energy Technology Data Exchange (ETDEWEB)

    Singhabhandhu, Ampaitepin; Tezuka, Tetsuo [Energy Economics Laboratory, Department of Socio-Environmental Energy Science, Graduate School of Energy Science, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501 (Japan)

    2010-06-15

    Energy generation by wastes is considered one method of waste management that has the benefit of energy recovery. From the waste-to-energy point of view, waste cooking oil, waste lubricating oil, and waste plastics have been considered good candidates for feedstocks for energy conversion due to their high heating values. Compared to the independent management of these three wastes, the idea of co-processing them in integration is expected to gain more benefit. The economies of scale and the synergy of co-processing these wastes results in higher quality and higher yield of the end products. In this study, we use cost-benefit analysis to evaluate the integrated management scenario of collecting the three wastes and converting them to energy. We report the total heat of combustion of pyrolytic oil at the maximum and minimum conversion rates, and conduct a sensitivity analysis in which the parameters of an increase of the electricity cost for operating the process and increase of the feedstock transportation cost are tested. We evaluate the effects of economy of scale in the case of integrated waste management. We compare four cases of waste-to-energy conversion with the business as usual (BAU) scenario, and our results show that the integrated co-processing of waste cooking oil, waste lubricating oil, and waste plastics is the most profitable from the viewpoints of energy yield and economics. (author)

  20. Upgraded bio-oil production via catalytic fast co-pyrolysis of waste cooking oil and tea residual.

    Science.gov (United States)

    Wang, Jia; Zhong, Zhaoping; Zhang, Bo; Ding, Kuan; Xue, Zeyu; Deng, Aidong; Ruan, Roger

    2017-02-01

    Catalytic fast co-pyrolysis (co-CFP) offers a concise and effective process to achieve an upgraded bio-oil production. In this paper, co-CFP experiments of waste cooking oil (WCO) and tea residual (TR) with HZSM-5 zeolites were carried out. The influences of pyrolysis reaction temperature and H/C ratio on pyrolytic products distribution and selectivities of aromatics were performed. Furthermore, the prevailing synergetic effect of target products during co-CFP process was investigated. Experimental results indicated that H/C ratio played a pivotal role in carbon yields of aromatics and olefins, and with H/C ratio increasing, the synergetic coefficient tended to increase, thus led to a dramatic growth of aromatics and olefins yields. Besides, the pyrolysis temperature made a significant contribution to carbon yields, and the yields of aromatics and olefins increased at first and then decreased at the researched temperature region. Note that 600°C was an optimum temperature as the maximum yields of aromatics and olefins could be achieved. Concerning the transportation fuel dependence and security on fossil fuels, co-CFP of WCO and TR provides a novel way to improve the quality and quantity of pyrolysis bio-oil, and thus contributes bioenergy accepted as a cost-competitive and promising alternative energy. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. 废轮胎热解炭黑的表面修饰及其在平版印刷油墨中的应用%Surface Modification of Pyrolytic Carbon Black from Waste Tires and Its Use as Pigment for Offset Printing Ink

    Institute of Scientific and Technical Information of China (English)

    周洁; 王靖岱; 任晓红; 阳永荣; 蒋斌波

    2006-01-01

    Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) is one of the most important products resulting from the pyrolysis of used tires. One of the most significant applications of modified pyrolytic carbon black is its use as pigment for offset printing ink to obtain high added values.Inverse gas chromatography (IGC) results show that a large quantity of inorganic matters and carbonaceous deposit are removed by treating the pyrolytic carbon black with nitric acid solution. Plenty of active sites originally occupied by inorganic ash and coke are recovered. The surface energy of pyrolytic carbon black (TWPC) modified by titanate-coupling agent-especially the specific interaction γsPs determined by the specific probe molecule, toluene-shows the strong interaction between the TWPC and the synthetic resins. The offset printing ink performance confirms the IGC prediction. And TWPC has the great potential of applications in printing ink industry as pigment.

  2. Analysis of pyrolysis products of Trollius chinensis Bunge essential oil and its application in cigarette flavoring%金莲花挥发油的热裂解产物分析及卷烟加香应用研究

    Institute of Scientific and Technical Information of China (English)

    魏跃伟; 王建玲; 姬小明; 李冰洁; 于建军; 赵铭钦; 刘国顺

    2011-01-01

    The essential oil of Trollius chinensis Bunge was extracted with steam distillation extraction. The pyrolysis of the essential oil at 300, 600, 900 ℃ and the application of the oil in cigarette flavoring were studied respectively. The results showed that 17, 22 and 31 constituents were identified in the pyrolytic products at 300, 600, 900℃ , respectively; Consituents and their concetrations in pyrolytic products changed with pyrolytic temperatures. Styrene, p-ionone, and so on were detected at those three temperatures, ( ± ) -linalool was detected at 300 and 600℃ , and α-cedarene was only detected in the pyrolysis products of 900℃. Furthermore, with temperature increasing, pyrolysis products became more complex. The smoking quality of cigarette was improved by the oil, the irritation obviously reduced, and the smoke smoothed.%采用水蒸气蒸馏法提取金莲花挥发油,对其300,600,900℃的热裂解产物进行了GC - MS分析,并对其挥发油进行了卷烟加香试验.结果表明,300,600和900℃的热解产物中分别鉴定出17,22和31种成分;热解温度不同,其产物成分的种类和含量亦不同;苯乙烯、β-紫罗兰酮等在3个温度下都可检索到,芳樟醇在300,600℃可检测到,而α-雪松烯只出现在900℃的裂解产物中;随着温度的升高,裂解产物逐渐复杂.金莲花挥发油具有改善和修饰卷烟香气,减轻刺激性的作用.

  3. Microbial conversion of pyrolytic products to biofuels: a novel and sustainable approach toward second-generation biofuels.

    Science.gov (United States)

    Islam, Zia Ul; Zhisheng, Yu; Hassan, El Barbary; Dongdong, Chang; Hongxun, Zhang

    2015-12-01

    This review highlights the potential of the pyrolysis-based biofuels production, bio-ethanol in particular, and lipid in general as an alternative and sustainable solution for the rising environmental concerns and rapidly depleting natural fuel resources. Levoglucosan (1,6-anhydrous-β-D-glucopyranose) is the major anhydrosugar compound resulting from the degradation of cellulose during the fast pyrolysis process of biomass and thus the most attractive fermentation substrate in the bio-oil. The challenges for pyrolysis-based biorefineries are the inefficient detoxification strategies, and the lack of naturally available efficient and suitable fermentation organisms that could ferment the levoglucosan directly into bio-ethanol. In case of indirect fermentation, acid hydrolysis is used to convert levoglucosan into glucose and subsequently to ethanol and lipids via fermentation biocatalysts, however the presence of fermentation inhibitors poses a big hurdle to successful fermentation relative to pure glucose. Among the detoxification strategies studied so far, over-liming, extraction with solvents like (n-butanol, ethyl acetate), and activated carbon seem very promising, but still further research is required for the optimization of existing detoxification strategies as well as developing new ones. In order to make the pyrolysis-based biofuel production a more efficient as well as cost-effective process, direct fermentation of pyrolysis oil-associated fermentable sugars, especially levoglucosan is highlly desirable. This can be achieved either by expanding the search to identify naturally available direct levoglusoan utilizers or modify the existing fermentation biocatalysts (yeasts and bacteria) with direct levoglucosan pathway coupled with tolerance engineering could significantly improve the overall performance of these microorganisms.

  4. Torrefaction and HZSM-5 catalyst combination improving pyrolytic products of cedarwood%烘焙与HZSM-5催化剂联用改善柏木热解产物品质

    Institute of Scientific and Technical Information of China (English)

    张杨; 梅艳阳; 杨晴; 杨海平; 刘捷; 陈汉平

    2015-01-01

    of torrefaction and catalytic pyrolysis on characteristics of pyrolytic products of cedarwood have been investigated. Pretreament of cedarwood via torrefaction was performed in a tube furnace at varying reaction temperature(200, 230, 260, 290℃) with a residence time of 30min. The torrefied cedarwood were characterized by elemental analysis and proximate analysis. The results showed that increasing torrefaction temperature caused the increase of carbon content from 48.16% to 54.3%, the oxygen content decreased from 44.33%to 35.65%. And the torrefied cedarwood product has a brown/black color, reduced volatile content and increased energy density:21.25 MJ/kg (after 30 min reaction time at 290℃) versus 18.13MJ/kg for untreated cedarwood. Then the torrefied cedarwood were subsequently catalytically fast pyrolyzed over HZSM-5 in a vertical tubular reactor at 550℃ with a residence time of 30 min. The gas products of pyrolysis were analyzed by chromatograph(GC), and liquid products were analyzed by gas chromatography mass spectrometry (GC-MS). Torrefaction caused deacetylation and decomposition of hemicellulose, cleavage of ester linkages and demethoxylation of lignin. And the experimental results show that after coupled torrefaction and catalytic pyrolysis, increasing the torrefaction temperature caused the coke yield decreased; the content of CO in gas product decreased from 53.69% to 40.84%, the content of H2 and CO2 increased by 43.1%and 35.04%respectively, and the content of CH4 had no obvious change. As for liquid products, with the increasing of torrefaction temperature, the content of acid significantly deceased, aromatic yield increased , and enrichment of phenols. The result indicated that the couple effects between torrefaction and catalytic pyrolysis are very important for upgrading of bio-oil. However, severe torrefaction can lead the coke yield increased and aromatic yield reduced. So the optimal torrefaction condition of cedarwood is 230-260℃.

  5. Oil Spills

    Science.gov (United States)

    ... Deepwater Horizon well blowout in the Gulf of Mexico. See a map showing the largest oil spills ... Hurricane Season Meet the New CAMEO Chemicals Mobile App Revised: Sep 25, 2017 10:35pm | Site Map | ...

  6. Co-pyrolysis behaviour and kinetic of two typical solid wastes in China and characterisation of activated carbon prepared from pyrolytic char.

    Science.gov (United States)

    Ma, Yuhui; Niu, Ruxuan; Wang, Xiaona; Wang, Qunhui; Wang, Xiaoqiang; Sun, Xiaohong

    2014-11-01

    This is the first study on the co-pyrolysis of spent substrate of Pleurotus ostreatus and coal tar pitch, and the activated carbon prepared from the pyrolytic char. Thermogravimetry (TG) analysis was carried out taking spent substrate, coal tar pitch and spent substrate-coal tar pitch mixture. The activation energies of pyrolysis reactions were obtained via the Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose methods. The kinetic models were determined by the master-plots method. The activated carbons were characterised by N2-adsorption, Fourier transform infrared spectroscopy and X-ray diffraction. Experimental results demonstrated a synergistic effect happened during co-pyrolysis, which was characterised by a decreased maximum decomposition rate and an enhanced char yield. The average activation energies of the pyrolysis reactions of spent substrate, coal tar pitch and the mixture were 115.94, 72.92 and 94.38 kJ mol(-1) for the Flynn-Wall-Ozawa method, and 112.17, 65.62 and 89.91 kJ mol(-1) for the Kissinger-Akahira-Sunose method. The reaction model functions were f(α) = (1-α)(3.42), (1-α)(1.72) and (1-α)(3.07) for spent substrate, coal tar pitch and the mixture, respectively. The mixture char-derived activated carbon had a Brunauer-Emmett-Teller surface area up to 1337 m(2) g(-1) and a total pore volume of 0.680 cm(3) g(-1). Mixing spent substrate with coal tar pitch led to the creation of more micropores and a higher surface area compared with the single spent substrate and coal tar pitch char. Also, the mixture char-derived activated carbon had a higher proportion of aromatic stacking. This study provides a reference for the utilisation of spent substrate and coal tar pitch via co-pyrolysis, and their pyrolytic char as a promising precursor of activated carbon.

  7. Single-Walled-Carbon-Nanotube-Modified Pyrolytic Graphite Electrode Used as a Simple Sensor for the Determination of Salbutamol in Urine

    Directory of Open Access Journals (Sweden)

    Rajendra N. Goyal

    2011-01-01

    Full Text Available A fast and sensitive voltammetric method has been proposed for the determination of salbutamol at single-walled-carbon-nanotube-modified edge-plane pyrolytic graphite electrode (SWNT/EPPGE in human urine. The electrochemical response of salbutamol was determined by square wave voltammetry (SWV in phosphate buffer solution (PBS at physiological pH 7.2. The modified electrode showed improved voltammetric response towards the oxidation of salbutamol, and a well-defined anodic peak was observed at ~600 mV with enhanced peak current in comparison to the bare electrode. Linear calibration plot using SWNT/EPPGE was obtained in the concentration range of 50 to 2500 ngml-1 with sensitivity and detection limit of 2.15 nA/ngml-1 and 4.31 ngml-1, respectively. The developed method has been successfully applied for the determination of salbutamol in commercial preparations and human body fluids. Fast analysis of salbutamol in human urine makes the proposed method of great interest for doping control purposes at the site of competitive games.

  8. Electronic and geometric properties of Au nanoparticles on Highly Ordered Pyrolytic Graphite (HOPG) studied using X-ray Photoelectron Spectroscopy (XPS) and Scanning Tunneling Microscopy (STM).

    Science.gov (United States)

    Lopez-Salido, Ignacio; Lim, Dong Chan; Dietsche, Rainer; Bertram, Nils; Kim, Young Dok

    2006-01-26

    Au nanoparticles grown on mildly sputtered Highly Ordered Pyrolytic Graphite (HOPG) surfaces were studied using Scanning Tunneling Microscopy (STM) and X-ray Photoelectron Spectroscopy (XPS). The results were compared with those of Ag nanoparticles on the same substrate. By varying the defect densities of HOPG and the Au coverages, one can create Au nanoparticles in various sizes. At high Au coverages, the structures of the Au films significantly deviate from the ideal truncated octahedral form: the existence of many steps between different Au atomic layers can be observed, most likely due to a high activation barrier of the diffusion of Au atoms across the step edges. This implies that the particle growth at room temperature is strongly limited by kinetic factors. Hexagonal shapes of Au structures could be identified, indicating preferential growth of Au nanostructures along the (111) direction normal to the surface. In the case of Au, XPS studies reveal a weaker core level shift with decreasing particle size compared to the 3d level in similarly sized Ag particles. Also taking into account the Auger analysis of the Ag particles, the core level shifts of the metal nanoparticles on HOPG can be understood in terms of the metal/substrate charge transfer. Ag is (partially) positively charged, whereas Au negatively charged on HOPG. It is demonstrated that XPS can be a useful tool to study metal-support interactions, which plays an important role for heterogeneous catalysis, for example.

  9. The theory of cyclic voltammetry of electrochemically heterogeneous surfaces: comparison of different models for surface geometry and applications to highly ordered pyrolytic graphite.

    Science.gov (United States)

    Ward, Kristopher R; Lawrence, Nathan S; Hartshorne, R Seth; Compton, Richard G

    2012-05-28

    The cyclic voltammetry at electrodes composed of multiple electroactive materials, where zones of one highly active material are distributed over a substrate of a second, less active material, is investigated by simulation. The two materials are assumed to differ in terms of their electrochemical rate constants towards any given redox couple. For a one-electron oxidation or reduction, the effect on voltammetry of the size and relative surface coverages of the zones as well as the rate constant of the slower zone are considered for systems where it is much slower than the rate constant of the faster zones. The occurrence of split peak cyclic voltammetry where two peaks are observed in the forward sweep, is studied in terms of the diffusional effects present in the system. A number of surface geometries are compared: specifically the more active zones are modelled as long, thin bands, as steps in the surface, as discs, and as rings (similar to a partially blocked electrode). Similar voltammetry for the band, step and ring models is seen but the disc geometry shows significant differences. Finally, the simulation technique is applied to the modelling of highly-ordered pyrolytic graphite (HOPG) surface and experimental conditions under which it may be possible to observe split peak voltammetry are predicted.

  10. Myristica oil poisoning

    Science.gov (United States)

    Nutmeg oil; Myristicin ... Myristica oil ( Myristica fragrans ) can be harmful. It comes from the seed of a nutmeg. ... Myristica oil is found in: Aromatherapy products Mace Nutmeg Other products may also contain myristica oil.

  11. All About Oils

    Science.gov (United States)

    ... in monounsaturated or polyunsaturated fats, and low in saturated fats. Oils from plant sources (vegetable and nut oils) ... oil, and palm kernel oil, are high in saturated fats and for nutritional purposes should be considered to ...

  12. Quantitative investigation of free radicals in bio-oil and their potential role in condensed-phase polymerization.

    Science.gov (United States)

    Kim, Kwang Ho; Bai, Xianglan; Cady, Sarah; Gable, Preston; Brown, Robert C

    2015-03-01

    We report on the quantitative analysis of free radicals in bio-oils produced from pyrolysis of cellulose, organosolv lignin, and corn stover by EPR spectroscopy. Also, we investigated their potential role in condensed-phase polymerization. Bio-oils produced from lignin and cellulose show clear evidence of homolytic cleavage reactions during pyrolysis that produce free radicals. The concentration of free radicals in lignin bio-oil was 7.5×10(20)  spin g(-1), which was 375 and 138 times higher than free-radical concentrations in bio-oil from cellulose and corn stover. Pyrolytic lignin had the highest concentration in free radicals, which could be a combination of carbon-centered (benzyl radicals) and oxygen-centered (phenoxy radicals) organic species because they are delocalized in a π system. Free-radical concentrations did not change during accelerated aging tests despite increases in molecular weight of bio-oils, suggesting that free radicals in condensed bio-oils are stable.

  13. seed oils

    African Journals Online (AJOL)

    Timothy Ademakinwa

    processes, production of biodiesel, as lubricant and in deep-frying purposes. They could also be ..... during the domestic deep-frying and pan- frying of potatoes. Int J Food Sci Nutr. 53, ... commercial edible vegetable oils. JAOCS. 84, 31-36.

  14. Upgrading of Bio-Oil into High-Value Hydrocarbons via Hydrodeoxygenation

    Directory of Open Access Journals (Sweden)

    Murni M. Ahmad

    2010-01-01

    Full Text Available Problem statement: World energy consumption is forecasted to grow significantly for the foreseeable future with fossil fuel remains the governing energy source. The demand in the need to explore alternative fuel source was further triggered by the overwhelmingly inconsistent cost of gasoline. Bio-oil is an alternative energy source produced from pyrolysis of biomass. However it is undesirable as a ready alternative transportation fuel due to its unfavorable nature i.e., highly oxygenated and low octane number. To overcome these physicochemical issues, hydrodeoxygenation reaction is a possible upgrading method i.e., by partial or total elimination of oxygen and hydrogenation of chemical structures. Hence, this study aimed to investigate feasible routes and to develop the process route to upgrade the pyrolytic bio-oil from biomass into value-added chemicals for the production of transportation fuel, i.e., benzene and cyclohexane, via hydrodeoxygenation process via simulation in PETRONAS iCON software. Approach: In this study, hydrodeoxygenation of phenols and substituted phenols was used to represent the hydrodeoxygenation of the major oxygen compound in bio-oil due to their low reactivity in HDO. Results: By assuming the feedstock used was 1% of the total palm shell available in Malaysia, i.e., 2,587 kg h-1 bio-oil, the simulation predicted the production of 226 kg h-1 benzene, 236 kg h-1 cyclohexane and 7 kg h-1 cyclohexene, with the yield of 34, 81 and 3% respectively. The preliminary economic potential was calculated to be positive. It was also observed that hydrogen was the limiting reactant in the hydrogenation reaction. Conclusion/Recommendations: The simulation study indicated positive technical and economic feasibility of hydrodeoxygenation of pyrolytic bio-oil from biomass into benzene and cyclohexane for the transportation fuel industry. This potential can be explored in more details and further findings can promote the prospect of co

  15. Femtosecond laser ablation of highly oriented pyrolytic graphite: a green route for large-scale production of porous graphene and graphene quantum dots.

    Science.gov (United States)

    Russo, Paola; Hu, Anming; Compagnini, Giuseppe; Duley, Walter W; Zhou, Norman Y

    2014-02-21

    Porous graphene (PG) and graphene quantum dots (GQDs) are attracting attention due to their potential applications in photovoltaics, catalysis, and bio-related fields. We present a novel way for mass production of these promising materials. The femtosecond laser ablation of highly oriented pyrolytic graphite (HOPG) is employed for their synthesis. Porous graphene (PG) layers were found to float at the water-air interface, while graphene quantum dots (GQDs) were dispersed in the solution. The sheets consist of one to six stacked layers of spongy graphene, which form an irregular 3D porous structure that displays pores with an average size of 15-20 nm. Several characterization techniques have confirmed the porous nature of the collected layers. The analyses of the aqueous solution confirmed the presence of GQDs with dimensions of about 2-5 nm. It is found that the formation of both PG and GQDs depends on the fs-laser ablation energy. At laser fluences less than 12 J cm(-2), no evidence of either PG or GQDs is detected. However, polyynes with six and eight carbon atoms per chain are found in the solution. For laser energies in the 20-30 J cm(-2) range, these polyynes disappeared, while PG and GQDs were found at the water-air interface and in the solution, respectively. The origin of these materials can be explained based on the mechanisms for water breakdown and coal gasification. The absence of PG and GQDs, after the laser ablation of HOPG in liquid nitrogen, confirms the proposed mechanisms.

  16. An Experimental Study on Catalytic Cracking of Polyethylene and Engine Oils

    Directory of Open Access Journals (Sweden)

    S.K. Kimutai

    2014-02-01

    Full Text Available The utility of plastics and engine oils is very important due to their wide application in the packaging and automotive industries respectively and as such their continued use has led to an in increase in plastics and oil waste. However, the huge amount of plastic and engine oil waste produced may be treated with thermal catalytic methods to produce fossil fuel substitutes. In this research, the co-processing of polyethylene resin with petrol engine oil into high value hydrocarbons using thermal catalytic cracking (consisting of initial pyrolytic stage followed by a catalytic reforming stage was investigated. Plastic resins and petrol engine oil were loaded in the thermal reactor and HZSM-5 zeolite catalyst placed in the catalytic chamber. The system was purged with nitrogen at temperatures between 400 and 520oC. The resulting products were compared with those obtained in the absence of a catalyst. At temperatures greater than 460oC the conversion into liquid and gas fuels is above 70% wt. At similar temperatures and in the absence of catalyst, thermal cracking of low density polyethylene generated majorly liquid products with a low calorific value. The use of HZSM-5 as a catalyst caused a significant increase in the proportion of gaseous hydrocarbons that consisted mainly of light fraction olefins and liquid oil with calorific value of 43.9 MJ/kg and also comparable to regular petrol fuel. This study focuses on developing a method of conversion that can be adopted by industries as a means of converting waste plastics and waste oils into resources rather than waste.

  17. Finite Element Analysis of Fracture Toughness of Pyrolytic Carbon in Prosthetic Heart Valve%人工心瓣热解炭断裂韧性有限元分析

    Institute of Scientific and Technical Information of China (English)

    张建辉; 邢兴

    2012-01-01

    This article used ANSYS to conduct simulation analysis of compact tension and 3 points bending test for the isotropic pyrolytic carbon and pyrolytic carbon-coated graphite composite material used in heart valve prosthesis, calculated the plane strain fracture toughness KIC and compared the calculated results with the results of related experiments, then analyzed the effectiveness of the method that used ANSYS to calculate KIC as well as the influence of the thickness ratio of the coating and substrate and crack tip radius for the KIC of pyrolytic carbon-coated graphite composite material. Results showed that the KIC of the pure pyrolytic carbon and graphite material were respectively 1. 176 MPa √m and 1. 415 MPa √m, which were close to the results of related experiments, verifying the accuracy of using ANSYS to calculate KIC ; the KIC of composite material of pyrolytic carbon-coated graphite reduced with the increase of thickness ratio for the coating and substrate. The fracture toughness of composite material was better than that of pure pyrolytic carbon or graphite composite material when the thickness ratio of coating and substrate was on the low side; pyrolitic carbon-coated graphite had a limit notch root radius p0, which was about 5 μm, when the notch root radius p >p0, the measured value of KIC was proportional to p1/2 , and when p < po, the measured value of KIC was in line with the value of samples with sharp crack.%利用有限元分析软件ANSYS,对人工心瓣各向同性热解炭和热解炭包覆石墨复合材料进行紧凑拉伸以及三点弯曲实验仿真分析,计算材料的平面应变断裂韧性KIC,并将计算结果与相关实验结果进行对比,分析利用ANSYS计算KIC方法的有效性,以及涂层与基体厚度比、裂纹尖端半径对热解炭包覆石墨复合材料KIC值的影响.结果表明,纯热解炭和石墨材料的ANSYS计算KIC值分别为1.176 MPa√m以及1.415 MPa√m,与相关实验结果接近,验证

  18. Turbine oil

    Energy Technology Data Exchange (ETDEWEB)

    Eminov, E.A.; Bogdanov, Sh.K.; Dovgopolyi, E.E.; Gryaznov, B.V.; Ivanov, V.S.; Ivanova, Z.M.; Kozlova, E.K.; Nikolaeva, N.M.; Rozhdestvenskaya, A.A.

    1981-03-10

    In the known turbine oil (TO), for the purpose of improving the anticorrosion and demulsifying properties, a polyoxypropylene glycol ether, ethylenediamine or propylene glycol or an alkylphenol are additionally introduced, where the C/sub 8/-C/sub 12/ alkyl has a molecular weight of 2000-10,000. The proportions of the components are: 2, 6-di-tert-butyl-4-methylphenol 0.2-1.0%, quinizarin 0.01-0.05%, an acid ester of an alkenylsuccinic acid 0.02-0.1%, a polyoxypropylene glycol ether 0.02-0.2%, polymethylsiloxane 0.003-0.005%, and petroleum oil the remainder. The TO is prepared by mixing the petroleum oil with the additives in any sequence at a temperature of 60-80/sup 0/ by mechanical stirring. On the five TO samples the antioxidative, demulsifying, and anticorrosion properties by comparison with the prototype were investigated. It was shown that the obtained TO possesses improved anticorrosion properties (time until the appearance of Kr (staining.), up to 60 h as against 35 on the prototype) and demulsifying properties (quantity of water separating on breaking the emulsion 10 mg/L as against 65 mg/L on the prototype) for an antioxidative stability equal to that of the analog. The TO is designated for use in various turbo-units, in the first place in marine steam turbine units, where there is the probability of contact of the TO with seawater. Use of the TO makes it possible to increase the service life of the mechanisms, to reduce the amount of oil mixable in the form of an emulsion (by a factor of 1.5 to 2), and to lower the operating expenses.

  19. Flash co-pyrolysis of biomass with polylactic acid. Part 1: Influence on bio-oil yield and heating value

    Energy Technology Data Exchange (ETDEWEB)

    T. Cornelissen; J. Yperman; G. Reggers; S. Schreurs; R. Carleer [Hasselt University, Diepenbeek (Belgium). Laboratory of Applied Chemistry

    2008-06-15

    High amounts of water present in bio-oil are one of the major drawbacks for its utilisation as a fuel. One technology that shows the potential to satisfy the demand for bio-oil with a reduced water content is the flash co-pyrolysis of biomass with polylactic acid, PLA. The influence of PLA on the pyrolysis of willow is investigated with a semi-continuous home-built pyrolysis reactor. Flash co-pyrolysis of willow/PLA blends (10:1, 3:1, 1:1 and 1:2) show synergetic interaction. A higher bio-oil yield and a lower water content as a function of the willow/PLA ratios are obtained. Among the tested blends, the 1:2 willow/PLA blend shows the most pronounced synergy: a reduction in the production of pyrolytic water of almost 28%, accompanied by an increase of more than 37% in the production of water-free bio-oil. Additionally, PLA shows to have a positive influence on the energetic value of the bio-oil produced and on the resulting energy recuperation. 23 refs., 7 figs., 4 tabs.

  20. Fractional pyrolysis of Cyanobacteria from water blooms over HZSM-5 for high quality bio-oil production

    Institute of Scientific and Technical Information of China (English)

    Huijuan Li; Linling Li; Rui Zhang; Dongmei Tong∗; Changwei Hu∗

    2014-01-01

    Fractional pyrolysis and one-step pyrolysis of natural algae Cyanobacteria from Taihu Lake were comparatively studied from 200 to 500◦C. One-step pyrolysis produced bio-oil with complex composition and low high heating value (HHV630.9 MJ/kg). Fractional pyrolysis separated the degradation of different components in Cyanobacteria and improved the selectivity to products in bio-oil. That is, acids at 200◦C, amides and acids at 300◦C, phenols and nitriles at 400◦C, and phenols at 500◦C, were got as main products, respectively. HZSM-5 could promote the dehydration, cracking and aromatization of pyrolytic intermediates in fractional pyrolysis. At optimal HZSM-5 catalyst dosage of 1.0 g, the selectivity to products and the quality of bio-oil were improved obviously. The main products in bio-oil changed to nitriles (47.2%) at 300◦C, indoles (51.3%) and phenols (36.3%) at 400◦C. The oxygen content was reduced to 7.2 wt%and 9.4 wt%, and the HHV was raised to 38.1 and 37.3 MJ/kg at 300 and 400◦C, respectively. Fractional catalytic pyrolysis was proposed to be an efficient method not only to provide a potential solution for alleviating environmental pressure from water blooms, but also to improve the selectivity to products and obtain high quality bio-oil.

  1. Chemistry of oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Iida, T.

    1974-01-01

    A review with several references covers the formation, distribution, and mining of oil shales of Fu-Shun colliery; retorting furnaces for oil shale; refining of crude shale oils; and components of oil from Fu-Shun oil shales including pyrolle, matrine, fatty acid anilides, 2,4,5-trimethylpyrrole, and middle-layer bases.

  2. 2D self-assembly of phenylene-vinylene tectons at the liquid-highly oriented pyrolytic graphite interface: from chain length effects to anisotropic guest-host dynamics

    Science.gov (United States)

    Six, A.; Bocheux, A.; Charra, F.; Mathevet, F.; Kreher, D.; Attias, A.-J.

    2017-01-01

    Here we report the synthesis and characterization of a series of new phenylene-vinylene tectons. The study by scanning tunneling microscopy of their supramolecular self-assembly at the interface between a phenyloctane solution and highly oriented pyrolytic graphite demonstrates that variation of concentration and length of alkyl chains led to the formation of different networks, a compact one and a nanoporous one, with a fine control of the lattice parameters. The study of guest-host properties of the nanoporous network revealed a selectivity toward guest compounds according to their shape and size. Moreover, the statistical analysis of pore-to-pore guest dynamics evidences an anisotropic diffusion process.

  3. Self-assembly of 50 bp poly(dA)·poly(dT) DNA on highly oriented pyrolytic graphite via atomic force microscopy observation and molecular dynamics simulation.

    Science.gov (United States)

    Doi, Kentaro; Takeuchi, Hiroshi; Nii, Ryosuke; Akamatsu, Shingo; Kakizaki, Toshiya; Kawano, Satoyuki

    2013-08-28

    This study has investigated the formation patterns resulting from the self-assembly of deoxyribonucleic acid (DNA) on highly oriented pyrolytic graphite (HOPG), using both experimental and molecular dynamics approaches. Under optimized conditions based on pretreatment of HOPG surface and specific solution concentrations, DNA is found to self-assemble to form various patterned networks. The associated self-assembly mechanism is elucidated using coarse-grained molecular dynamics simulations and fractal dimension analysis. The results of this work demonstrate an effective technique allowing the formation of arrays of negatively charged biomacromolecules on negatively charged HOPG surfaces.

  4. 高温熔融钢渣热闷热平衡分析及余热回收利用%Analysis of heat balance and waste heat recovery and utilization for the high temperature molten slag by pyrolytic

    Institute of Scientific and Technical Information of China (English)

    张宇; 陈媛; 张天有; 张健; 韩自博; 刘银梅

    2014-01-01

    对钢渣热闷过程中的热量平衡进行了分析和计算,提出了余热回收方案,并对经济效益进行了分析,为钢渣余热回收的进一步研究和实践打下了基础。%The heat balance during the steel slag self -slaking process by pyrolytic was analyzed and calculated.Put forward the waste heat recovery scheme and analyzed the economic benefits .It lays a solid basis for the further research and practice of steel slag waste heat recovery .

  5. Exploring Oil Pollution

    Science.gov (United States)

    Rillo, Thomas J.

    1974-01-01

    Discusses damages of oil tanker spillage to the marine organisms and scientists' research in oil pollution removal techniques. Included is a list of learning activities concerning the causes and effects of oil pollution and methods of solving the problem. (CC)

  6. Rheology of Structured Oils

    Science.gov (United States)

    Kelbaliev, G. I.; Rasulov, S. R.; Rzaev, A. G.; Mustafaeva, G. R.

    2017-07-01

    Rheological models of structured oils are proposed and compared with available experimental data on oils from different deposits. It is shown that structured oils can possess properties of Bingham and power-law non-Newtonian fluids.

  7. Cedar leaf oil poisoning

    Science.gov (United States)

    Cedar leaf oil is made from some types of cedar trees. Cedar leaf oil poisoning occurs when someone swallows this substance. ... The substance in cedar leaf oil that can be harmful is thujone (a hydrocarbon).

  8. Altering bio-oil composition by catalytic treatment of pinewood pyrolysis vapors over zeolites using an auger - packed bed integrated reactor system

    Directory of Open Access Journals (Sweden)

    Vamshi Krishna Guda

    2016-09-01

    Full Text Available Pine wood pyrolysis vapors were catalytically treated using Zeolite catalysts. An auger fed reactor was used for the pinewood pyrolysis while a packed bed reactor mounted on the top of the auger reactor housed the catalyst for the treatment of pinewood pyrolytic vapors. The pyrolytic vapors produced at 450 oC were passed through zeolite catalysts maintained at 425 oC at a weight hourly space velocity (WHSV of 12 h-1. Five zeolites, including ZSM-5, mordenite, ferrierite, Zeolite-Y, and Zeolite-beta (all in H form, were used to study the effect of catalyst properties such as acidity, pore size, and pore structure on catalytic cracking of pinewood pyrolysis vapors. Product bio-oils were analyzed for their chemical composition using GC-MS, water content, density, viscosity, acid value, pH, and elemental compositions. Thermogravimetric analysis (TGA was performed to analyze the extent of coking on zeolite catalysts. Application of catalysis to biomass pyrolysis increased gas product yields at the expense of bio-oil yields. While all the zeolites deoxygenated the pyrolysis vapors, ZSM-5 was found to be most effective. The ZSM-5 catalyzed bio-oil, rich in phenolics and aromatic hydrocarbons, was less viscous, had relatively lower acid number and high pH, and possessed oxygen content nearly half that of un-catalyzed bio-oil. Brønsted acidity, pore size, and shape-selective catalysis of ZSM-5 catalyst proved to be the determining factors for its activity. TGA results implied that the pore size of catalysts highly influenced coking reactions. Regeneration of the used catalysts was successfully completed at 700 oC.

  9. 热解型绝热材料烧蚀过程数值仿真%Research on Numerical Simulation for Ablation of Pyrolytic Insulator

    Institute of Scientific and Technical Information of China (English)

    周源; 黄志勇; 王斌

    2015-01-01

    绝热层的热防护性能直接影响了固体火箭发动机工作的安全性和可靠性。热解型绝热材料在传热烧蚀过程中形成了碳化层—热解面—基体层的物理结构。通过建立热化学烧蚀计算模型和绝热层传热计算模型对传热烧蚀过程进行了计算分析。考虑到烧蚀过程中绝热层边界的移动,根据预测—校正格式对模型进行离散,对绝热层的烧蚀过程及传热过程进行了耦合计算。计算结果表明,绝热层的热解速率比烧蚀速率大很多,绝热材料的热解潜热对绝热层的热防护能力具有很大影响。%The thermal protection ability of insulator has great influence on the safety and reliability of SRM. During the progress of heat-transfer and ablation,the pyrolytic insulator changes into the physical structure with carbonization-layer,pyrolysis-side and insulator-layer. The thermal behavior and ablation of insulator were calculated and analyzed by the thermo-chemistry ablation model and heat-transfer calculation model. In consideration of the fact that the boundary of insulator is moving during the ablation,the models were discredited with predicted-correction method. Insulator ablation and temperature field were coupling calculated. The results show that the rate of pyrolysis is higher than the rate of ablation and the latent heat of pyrolysis has great influence on thermal protection ability of insulator.

  10. Particles at Oil-Air Surfaces: Powdered Oil, Liquid Oil Marbles, and Oil Foam.

    Science.gov (United States)

    Binks, Bernard P; Johnston, Shaun K; Sekine, Tomoko; Tyowua, Andrew T

    2015-07-08

    The type of material stabilized by four kinds of fluorinated particles (sericite and bentonite platelet clays and spherical zinc oxide) in air-oil mixtures has been investigated. It depends on the particle wettability and the degree of shear. Upon vigorous agitation, oil dispersions are formed in all the oils containing relatively large bentonite particles and in oils of relatively low surface tension (γla cyclomethicone containing the other fluorinated particles. Particle-stabilized oil foams were obtained in oils having γla > 26 mN m(-1) where the advancing air-oil-solid contact angle θ lies between ca. 90° and 120°. Gentle shaking, however, gives oil-in-air liquid marbles with all the oil-particle systems except for cases where θ is 24 mN m(-1) with omniphobic zinc oxide and sericite particles for which advancing θ ≥ 90°, dry oil powders consisting of oil drops in air which do not leak oil could be made upon gentle agitation up to a critical oil:particle ratio (COPR). Above the COPR, catastrophic phase inversion of the dry oil powders to air-in-oil foams was observed. When sheared on a substrate, the dry oil powders containing at least 60 wt % of oil release the encapsulated oil, making these materials attractive formulations in the cosmetic and food industries.

  11. Pressurized pyrolysis of rice husk in an inert gas sweeping fixed-bed reactor with a focus on bio-oil deoxygenation.

    Science.gov (United States)

    Qian, Yangyang; Zhang, Jie; Wang, Jie

    2014-12-01

    The pyrolysis of rice husk was conducted in a fixed-bed reactor with a sweeping nitrogen gas to investigate the effects of pressure on the pyrolytic behaviors. The release rates of main gases during the pyrolysis, the distributions of four products (char, bio-oil, water and gas), the elemental compositions of char, bio-oil and gas, and the typical compounds in bio-oil were determined. It was found that the elevation of pressure from 0.1MPa to 5.0MPa facilitated the dehydration and decarboxylation of bio-oil, and the bio-oils obtained under the elevated pressures had significantly less oxygen and higher calorific value than those obtained under atmospheric pressure. The former bio-oils embraced more acetic acid, phenols and guaiacols. The elevation of pressure increased the formation of CH4 partially via the gas-phase reactions. An attempt is made in this study to clarify "the pure pressure effect" and "the combined effect with residence time".

  12. [MICROBIAL DESTRUCTION MINERAL (OIL) MOTOR OIL].

    Science.gov (United States)

    Homenko, L A; Nogina, T M

    2015-01-01

    In a review information is presented about composition of mineral motor oils and their negative impact on the environment and the ability of microorganisms, in particular actinobacteria, to assimilate hydrocarbon oil components. The role of bacteria is described in the process of cleaning up polluted environments motor oils and the prospect of their use in biotechnology, environmental clean-up of these pollutants.

  13. Non-Petroleum Oils

    Science.gov (United States)

    These include synthetics such as silicone fluids and tung oils, wood-derivative oils such as resin/rosin, animal fats/oil, and seed oils. Many have similar physical properties to petroleum-based, such as water insolubility and formation of slicks.

  14. Contact Angle Hysteresis on Graphene Surfaces and Hysteresis-free Behavior on Oil-infused Graphite Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Cyuan-Jhang; Li, Yueh-Feng [Department of Chemical and Materials Engineering, National Central University, Jhongli 320, Taiwan (China); Woon, Wei-Yen [Department of Physics, National Central University, Jhongli 320, Taiwan (China); Sheng, Yu-Jane, E-mail: yjsheng@ntu.edu.tw [Department of Chemical Engineering, National Taiwan University, Taipei 106, Taiwan (China); Tsao, Heng-Kwong, E-mail: hktsao@cc.ncu.edu.tw [Department of Chemical and Materials Engineering, National Central University, Jhongli 320, Taiwan (China); Department of Physics, National Central University, Jhongli 320, Taiwan (China)

    2016-11-01

    Highlights: • Contact angle hysteresis(CAH) on four graphitic surfacesisinvestigated. • The hysteresis loopof water drops on the polished graphite sheetshowsparticularly small receding contact angle. • The significant CAH observed on CVD graphene and highly oriented pyrolytic graphite is attributed mainly to adhesion hysteresis. • An oil-infused surface of a graphite sheet is produced by imbibition of hexadecane into its porous structure. • The hysteresis-free property for water drops on such a surface is examined and quantitatively explained. - Abstract: Contact angle hysteresis (CAH) on graphitic surfaces, including chemical vapor deposition (CVD) graphene, reduced electrophoretic deposition (EPD) graphene, highly oriented pyrolytic graphite (HOPG), and polished graphite sheet, has been investigated. The hysteresis loops of water drops on the first three samples are similar but the receding contact angle is particularly small for the polished graphite sheet.The significant CAH observed on CVD graphene and HOPG associated with atom-scale roughness has to be attributed mainly to adhesion hysteresis (surface relaxation), instead of roughness or defects.The difference of the wetting behavior among those four graphitic samples has been further demonstrated by hexadecane drops. On the surface of HOPG or CVD graphene,the contact line expands continuously with time, indicating total wetting for which the contact angle does not exist and contact line pinning disappears. In contrast, on the surface of reduced EPD graphene, spontaneous spreading is halted by spikes on it and partial wetting with small contact angle (θ≈4°) is obtained. On the surface of polished graphite sheet, the superlipophilicity and porous structure are demonstrated by imbibition and capillary rise of hexadecane. Consequently, an oil-infused graphite surface can be fabricated and the ultralow CAH of water (∆θ≈2°) is achieved.

  15. Oil Reserve Center Established

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Like other countries,China has started to grow its strategic oil reserve in case oil supplies are cut On December 18,2007,the National Development and Reform Commission(NDRC),China’s top economic planner,announced that the national oil reserve center has been officially launched.The supervisory system over the oil reserves has three levels: the energy department of the NDRC,the oil reserve center,and the reserve bases.

  16. Oil spill contingency planning

    Energy Technology Data Exchange (ETDEWEB)

    Kip, S.H. (Sarawak Shell Bhd/Saban Shell Petroleum Co. Ltd. (MY))

    1988-01-01

    Oil spill contingency planning is an essential feature required in present day activities involving oil and gas exploration, production and transportation. A well through out continency plan will not only eliminate or minimize the sense of panic, normally associated with oil spill emergency, but also can minimize damage and cost involved. Oil spill contingency planning is a process of predetermining a response to an oil spill emergency. The process of preparing a contingency plan is discussed in this paper.

  17. Developments in Oil Shale

    Science.gov (United States)

    2008-11-17

    demonstration (RD&D). The ongoing program will confirm whether an economically significant shale oil volume can be extracted under current operating...Petroleum Trade, [http://www.eia.doe.gov/emeu/mer/pdf/pages/sec1_15.pdf]. 2 Oil sands yield a bitumen substantially heavier most crude oils and shale oil. 3...hydrocarbon products that can be extracted from the shale. The most promising oil shales occur in the Green River formation that underlies 16,000 square

  18. Mexican oil industry: Shifting to difficult oil

    Energy Technology Data Exchange (ETDEWEB)

    Bazan G., Gerardo; Gonzalez, Cristobal J.

    2010-09-15

    Mexico has stepped into an important transition of declining oil fields and new challenging oil projects. The aim of this paper is to show a new perspective of the oil resources that have been exploited throughout the Mexican territory, as well as the remaining resources yet to be exploited. We have developed a resources/production-costs chart that illustrates the historical and future development of the Mexican oil industry, showing the shift that the industry will face in the coming years; this chart was taken from a model already in use by the most prestige energy agencies in the world.

  19. SUITABILITY OF SOYBEAN SEED OIL AS TRANSFORMER OIL

    OpenAIRE

    Egbuna, S.O.*, Ude, O.C., Ude, C.N.

    2016-01-01

    In search of solution to the harmful ecological problems due to toxicity and non-biodegradability posed by conventional transformer insulation oil (mineral oil), the production of transformer oil from soybean seed oil (vegetable oil) was carried out. The oil was extracted using n-hexane and was refined. The transformer oil was produced by transesterification and was characterized using American Society for Testing Material (ASTM) standard test. The solvent employed gave good yield of oil from...

  20. Nanoindentation experiment and finite element simulation for isotropic pyrolytic graphite%各向同性热解石墨的纳米压痕试验与有限元仿真研究

    Institute of Scientific and Technical Information of China (English)

    王明海; 王虎军; 孙磊; 刘中海

    2011-01-01

    The load-displacement curves of isotropic pyrolytic graphite were obtained through nanoin-dentation experimentAccording to the theory of olive and pharr the hardness and the young modulus were calculated to obtain performance of main materials.Then a numerical model for the nanoindentation experiment was set up by finite element method.Through comparing the load-displacement curve fitted by finite element with the actual curve obtained from nanoindentation experiment,relative correlation was achievedFinally plastic property of isotropic pyrolytic graphite was got,which prove the feasibility of finite element simulation at the same time.%通过对各向同性热解石墨进行了纳米压痕试验,得到了其材料的载荷-位移曲线.并根据Olive和Pharr理论算出了其硬度与弹性模量值,得到了主要的材料性能.在纳米压痕试验的基础上,通过有限元单元法建立了纳米压痕试验的数值模型,通过比较有限元所拟合的载荷一位移曲线和实际纳米压痕试验所得到的曲线,进行相应的修正,最后得到了该材料的塑性性能,也证明了有限元仿真的可行性.

  1. Determination of Pyrolytic Products of Extract of Raisin by Py-GC-MS%热裂解气相色谱-质谱法测定葡萄干提取物的热裂解产物

    Institute of Scientific and Technical Information of China (English)

    赵国玲

    2012-01-01

    50g葡萄干用70%乙醇溶液300mL在80℃回流提取3h,提取两次,过滤提取物.滤液减压浓缩至干。残渣用5200裂解仪在400℃,50℃.600℃,800℃下处理,在各裂解温度下得到的裂解产物导入仪器进行气相色谱质谱分析。结果表明:主要裂解产物是糠醛、呋喃甲醇、5-甲基糠醛、5-羟甲基-2呋喃甲醛、2,3-二氢-3,5二羟基6-甲基-4H-吡喃酮,这些裂解产物是赋予卷烟具有独特香味和较好口感的重要物质。%50 g of raisin were exlracted twice by refluxing with 300 mI. of 70% ethanol at 80℃ for 3 h. The extracts wgre filtered and the filtrate was evaporated to dryness under reduced pressure. The residue was lrealed whh Pyroprohc 5200 at 400 C, 500℃, 600℃ and 800℃, the pyrolytic products obtained al eaeh of lhe pyrolylie tempuratures were introduced into the instrument and analyzed by (GC-MS. It was shown that the main pyrolytic products obtained were furfural, 2-furanmethanol, 5 mcthyl 2-furancarboxaldehyde, 5 hydroxymethyl 2 furancarboxaldehyde, and 2, 3-dihydro-3, 5 dihydroxy6methyl.-4H-pyran-4one. These pyrolysates are the important substances to make cigarettes to have distinctive fragrance and better taste.

  2. 烟草中一种糖苷的分离鉴定及其热解产物%Isolation and Identification of a New Glycoside in Tobacco and Analysis of its Pyrolytic Products

    Institute of Scientific and Technical Information of China (English)

    周容; 冯广林; 李东亮; 李国友; 戴亚; 袁月

    2013-01-01

    通过95%乙醇提取,常压和高压制备色谱分离,从红花大金元烟叶中提取分离得到化合物Ⅰ,利用质谱和核磁共振技术鉴定了化合物Ⅰ的结构,并在氦气中进行了热裂解-GC/MS分析.结果表明:①化合物Ⅰ为(E)-N-[(4-羟基-3-甲氧基)苯乙基]-3-[(3-甲氧基-4-β-D-吡喃葡萄糖)苯基]丙烯酰胺;②化合物Ⅰ的热解产物主要是4-乙烯基愈创木酚、愈创木酚、香兰素、对甲基苯酚、2,3-二氢苯并呋喃、4-烯丙基苯酚和3-乙基苯酚.%A new glycoside,(E)-N-[(4-hydroxy-3-methoxy)-phenethyl]-3-[(3-methoxy-4-O-β-D-glucopyranosyloxy)phenyl]acrylamide (Ⅰ),was isolated from leaves of flue-cured tobacco cv."Hongda" through extraction with 95% ethanol,preparation at normal and high pressure and separation with chromatography.The molecular structure of compound (Ⅰ) was identified with HRESI-MS and NMR.Compound (Ⅰ) was pyrolyzed in He atmosphere and its pyrolytic products were analyzed by GC/MS.The results showed that the separated product was compound (Ⅰ),and its major pyrolytic products were 4-vinylguaiacol,guaiacol,vanillin,p-cresol,2,3-dihydrobenzofuran,4-allylphenol,and m-ethylphenol.

  3. HEAVY OIL DEVELOPMENT KEY TO CHINA'S OIL PRODUCTION GROWTH

    Institute of Scientific and Technical Information of China (English)

    Ma Chunpeng

    2006-01-01

    @@ How to raise the heavy oil production rate has long been a difficult research project focused by international oil giants while the super-heavy oil development is particularly a world-class bottleneck for many oil producers. However, China's main oil companies will give priority to heavy oil exploration and production in the next decade to meet China's increasing energy needs.

  4. efficacy of olive oil, groundnut oil, soybean oil and palm kernel oil in ...

    African Journals Online (AJOL)

    AGROSEARCH UIL

    Although food grains are commonly protected by insecticidal application and fumigation, ... (1978) reported that groundnut oil applied to cowpeas has no effect on mortality or .... Effectiveness of vegetable oil fractions in controlling the Mexican.

  5. Compositional insights and valorization pathways for carbonaceous material deposited during bio-oil thermal treatment.

    Science.gov (United States)

    Ochoa, Aitor; Aramburu, Borja; Ibáñez, María; Valle, Beatriz; Bilbao, Javier; Gayubo, Ana G; Castaño, Pedro

    2014-09-01

    This work analyses the composition, morphology, and thermal behavior of the carbonaceous materials deposited during the thermal treatment of bio-oil (thermal pyrolytic lignin-TPL). The bio-oil was obtained by flash pyrolysis of lignocellulosic biomass (pine sawdust), and the TPLs were obtained in the 400-700 °C range. The TPLs were characterized by performing elemental analysis; (13)C NMR, Raman, FTIR, and X-ray photoelectron spectroscopy; SEM; and temperature-programmed oxidation analyzed by differential thermogravimetry and differential scanning calorimetry. The results are compared to a commercial lignin (CL). The TPLs have lower oxygen and hydrogen contents and a greater aromaticity and structural order than the CL material. Based on these features, different valorization routes are proposed: the TPL obtained at 500 °C is suitable for use as a fuel, and the TPL obtained at 700 °C has a suitable morphology and composition for use as an adsorbent or catalyst support.

  6. China Aviation Oil Acquires Overseas Oil Company

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ China Aviation Oil (Singapore) announced an acquisition of a 20.6 percent stake in Singapore Petroleum Company (SPC) from Satya Capital Inc Ltd, the largest investment the company has ever made in its history. China Aviation Oil (Singapore),which is the largest Chinese enterprise Singapore,will become the second largest shareholder of SPC after the acquisition.

  7. Oil Module Working Paper

    Science.gov (United States)

    1973-12-01

    in any a^regate sense, or (b) to be "valid" for crude oil production in all countries. Neither, however, is it to provide detailed point... oil production by the oil companies through their regular channels. Such oil is said to be "sold back" by the countries to the coirpanies...a royalty to the producing country government. revenue received by the producing country government as a result of sales of its share of crude

  8. Indonesia's palm oil subsector

    OpenAIRE

    Larson, Donald F.

    1996-01-01

    Debate on Indonesia's palm oil policy was stimulated by a sharp increase in cooking oil prices in 1994-95 and a resulting increase in the export tax rate on crude palm oil. Palm oil has been one of the fastest growing subsectors in Indonesia. Using a quantitative model, the author analyzes the effect of government policies, including the export tax, buffer stock operations by the BULOG (the national logistics agency), and directed sales from public estates. The author acknowledges the export ...

  9. Soluble oil cutting fluid

    Energy Technology Data Exchange (ETDEWEB)

    Rawlinson, A.P.; White, J.

    1987-06-23

    A soluble oil, suitable when diluted with water, for use as a cutting fluid comprises an alkali or alkaline-earth metal alkyl benzene sulphonate, a fatty acid diethanolamide, a mixed alkanolamine borate, a polyisobutenesuccinimide and a major proportion of mineral oil. The soluble oil is relatively stable without the need for a conventional coupling agent and some soluble oil emulsions are bio-static even though conventional biocides are not included.

  10. The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene

    Energy Technology Data Exchange (ETDEWEB)

    Solak, Agnieszka; Rutkowski, Piotr, E-mail: piotr.rutkowski@pwr.wroc.pl

    2014-02-15

    Highlights: • Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. • Optimization of process temperature was done. • Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. • The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 – montmorillonite K10, KSF – montmorillonite KSF, B – Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 °C with heating rate of 100 °C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.3–79.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 °C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

  11. Oil Spill Cleanup

    Science.gov (United States)

    Kauble, Christena Ann

    2011-01-01

    Several classroom activities using a model of a seashore and an oil spill demonstrate the basic properties of oil spills in oceans. Students brainstorm about how to best clean up the mess. They work in teams, and after agreeing on how they will proceed, their method is tested by measuring the amount of oil removed and by rating the cleanliness of…

  12. Natural oils as lubricants

    Science.gov (United States)

    There is currently an availability of vegetable oil lubricants, with the exception of engine oils. Vegetable oils are environmentally friendly, renewable, contribute to the reduction of our dependence on imported petroleum, and add value to the farmer. However, there are inherent weaknesses in veg...

  13. Oil Spill Response Manual

    NARCIS (Netherlands)

    Marieke Zeinstra; Sandra Heins; Wierd Koops

    2014-01-01

    A two year programme has been carried out by the NHL University of Applied Sciences together with private companies in the field of oil and chemical spill response to finalize these manuals on oil and chemical spill response. These manuals give a good overview of all aspects of oil and chemical

  14. OIL AS POLITICAL WEAPON

    Directory of Open Access Journals (Sweden)

    Mariana, BUICAN

    2013-12-01

    Full Text Available Oil (called by some black gold has not always been as coveted and used, but only in the last hundred years has established itself as a highly sought after as an indispensable proper functioning of modern economic activity that an important factor in international politics. International oil regime has changed in the last decades. In 1960, oil regime was a private oligopol which had links with governments main consuming countries. By then the price of a barrel of oil was two U.S. dollars and seven major transnational oil companies decided the amount of oil that will be produced. Meanwhile the world region with the largest oil exports were more strongly expressed nationalism and decolonization. Result, it was so in the late 60s in the region occur independent states. They have created an organization aim of this resource to their advantage - OPEC (Organization of Petroleum Exporting Countries. Thus since 1973 there have been changes in the international regime governing oil field, namely producing countries were fixed production rate and price. After this time the oil weapon has become increasingly important in the management of international relations. Oil influenced the great powers to Middle East conflicts that occurred in the last century, but their attitude about the emergence of new sources of oil outside OPEC. In the late 90's, Russia has become a major supplier of oil to the West.

  15. Oil Spill Cleanup

    Science.gov (United States)

    Kauble, Christena Ann

    2011-01-01

    Several classroom activities using a model of a seashore and an oil spill demonstrate the basic properties of oil spills in oceans. Students brainstorm about how to best clean up the mess. They work in teams, and after agreeing on how they will proceed, their method is tested by measuring the amount of oil removed and by rating the cleanliness of…

  16. Lubricating oil; Junkatsuyu

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, H.

    1999-07-20

    As a reflection of business recession, sales amount of lubricating oils in 1998 in Japan was 2.334 million kl that is 96.1% of that in the previous year. In addition, export amount was 394 thousand kl that also decreased sharply to 81.9% of that in the previous year. In this situation, researches and developments of environment-adaptable lubricating oils such as fuel consumption-saving engine oils, new mechanism-corresponding drive system oils (AFT, CVT), refrigerating machine oils for substitute coolants, biodegradable oils and greases, environment corresponding processing oils (non-chlorine type cutting oils), and so on have been executed actively. In respect to lubricating oils for vehicles, numerous researches and developments of engine oils are executed while putting stress on the improvement of fuel consumption saving for reducing CO{sub 2} exhaust; improvement of adaptability to exhaust treating apparatus for purging harmful components from exhaust gas; and environmental corresponding of long drain for reducing waste oils. In respect to lubricating oils for industry, basic characteristics and utility characteristics of fire-resistant working fluids and biodegradable working fluids; and utility characteristics of new functional fluids and electric viscous fluids are reported in view of their relationship with environmental protection. (NEDO)

  17. Utah Heavy Oil Program

    Energy Technology Data Exchange (ETDEWEB)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  18. Oil shale commercialization study

    Energy Technology Data Exchange (ETDEWEB)

    Warner, M.M.

    1981-09-01

    Ninety four possible oil shale sections in southern Idaho were located and chemically analyzed. Sixty-two of these shales show good promise of possible oil and probable gas potential. Sixty of the potential oil and gas shales represent the Succor Creek Formation of Miocene age in southwestern Idaho. Two of the shales represent Cretaceous formations in eastern Idaho, which should be further investigated to determine their realistic value and areal extent. Samples of the older Mesozonic and paleozoic sections show promise but have not been chemically analyzed and will need greater attention to determine their potential. Geothermal resources are of high potential in Idaho and are important to oil shale prospects. Geothermal conditions raise the geothermal gradient and act as maturing agents to oil shale. They also might be used in the retorting and refining processes. Oil shales at the surface, which appear to have good oil or gas potential should have much higher potential at depth where the geothermal gradient is high. Samples from deep petroleum exploration wells indicate that the succor Creek shales have undergone considerable maturation with depth of burial and should produce gas and possibly oil. Most of Idaho's shales that have been analyzed have a greater potential for gas than for oil but some oil potential is indicated. The Miocene shales of the Succor Creek Formation should be considered as gas and possibly oil source material for the future when technology has been perfectes. 11 refs.

  19. Nutritional properties of poppyseed oil relative to some other oils.

    Science.gov (United States)

    Beare-Rogers, J L; Gray, L; Nera, E A; Levin, O L

    1979-01-01

    Male Wistar rats were fed a purified basal diet with 20% lard and corn oil (3:1), sunflower oil, poppyseed oil, low-erucic rapeseed oil from Brassica napus, cultivar Tower, or mixtures of these oils, for 1 or 26 weeks. None of the hearts exhibited lipidosis at 1 week. At 26 weeks, the level of serum triglycerides was higher in rats fed the mixture of lard and corn oil than in those fed only vegetable oil, and the incidence of cardiac necrosis and fibrosis was higher in rats fed the rapeseed oil than in the other animals. Cardiac phospholipids in rats fed the rapeseed oil contained an elevated level of omega 3 docosahexaenoic acid, particularly in phosphatidylethanolamine. Poppyseed oil exhibited properties similar to those of sunflower oil, was absorbed as well as olive oil, and appeared to be a promising oil for human consumption.

  20. Tarim Oil Field Company Oil Output Exceeds 5 Million Tons

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    PetroChina Tarim Oil Field Company (Tarim Oil Field), located in the hinterland of Takelamagan Desert in Northwest Xinjiang Autonomous Region,produced 5.006 million tons of crude oil in 2002,ranking it as the sixth largest onshore oil field in China. This is the first time Tarim Oil Field has topped 5 million tons for its crude production.

  1. Oil: Economics and politics

    Energy Technology Data Exchange (ETDEWEB)

    Ayoub, A. (Laval Univ., PQ (Canada))

    1994-01-01

    A review is presented of the evolution of the international petroleum sector since 1973 with a special emphasis on the interdependence between the economic and political factors that influence it. Two issues are focused on: the effects of the nationalization of oil companies on the sharing of oil rents and on changes in the structure of the oil market; and the determination of oil prices. Definitions are presented of oil rents, and the reasons for OPEC nationalization of oil companies are explored. The effects of nationalization on market structures, expansion of free markets, and vertical integration are discussed. The existence of an oil price floor and the reasons for such a floor are examined. It is shown that nationalization induced an internalization of rents by the producing countries, leading to the emergence of a differential rent supported by the politics of the industrialized countries. Nationalization led to the breakup of systems of vertical and horizontal integration, with replacement by a new dual structure with OPEC controlling the upstream activities of the oil sector and oil companies controlling the downstream ones. Prices move between a floor price set by the costs of substitute deposits in the U.S., while the determination of ceiling levels by OPEC rests on successive fragile compromises. Overall oil is still a strategic product, despite the existence of spot markets, forward trading options, etc. 29 refs.

  2. 烘焙对生物质热解产物特性的影响%Effect of torrefaction on characteristics of pyrolytic products of biomass

    Institute of Scientific and Technical Information of China (English)

    杨晴; 梅艳阳; 郝宏蒙; 杨海平; 王贤华; 陈汉平

    2013-01-01

    烘焙可有效地降低生物质中的水分和氧,对其热解过程有显著的影响。该文主要研究了烘焙温度(200,230,260,290℃)对生物质热解过程及产物特性的影响行为及影响机制;研究发现烘焙能改善热解产物的品质,随着烘焙温度的升高,热解合成气中CO含量由48%逐渐减少到34%,CH4和H2增加,其中H2含量最大增加了77.4%,而液体产物中,乙酸和水分含量逐渐减小,水分含量最大减少了42.8%,而酚类产物的含量明显增加,有利于生物油品质的提高。该研究为烘焙技术的发展和生物质高效热化学转化提供科学参考。%The pyrolysis of biomass is one of the promising methods for obtaining bio-energy, and is discussed widely. Bio-oil obtained from pyrolysis is easy to store and transport, and can be used directly and indirectly as a fuel. However, bio-oils have high acid content, high water content, and low heating value. These drawbacks have limited the broad application of bio-oils. Torrefaction is a low temperature pyrolysis process carried out at temperatures ranging from 200 to 300℃ for liberating water and releasing volatile organic compounds, which may affect the subsequent pyrolysis process and related products. In this sense, there has been significant increase of interest in biomass torrefaction techniques. In this work, torrefaction of cotton stalk was conducted on a tube furnace at 200, 230, 260, 290℃ with a residence time of 30 min. Pyrolysis of torrefied cotton stalk was also performed on a tube furnace reactor at 550℃with a residence time of 30 min. The effect of torrefaction temperature on the yield, products composition, and physical properties of bio-oil were studied. In addition, the product distribution of torrefied cotton stalk pyrolysis was also investigated. Torrefied cotton stalk was chosen as the benchmark when calculate the yield .The gas products of pyrolysis were analyzed by chromatograph

  3. Contamination by PAHs, PCBs, PCPs and heavy metals in the Mecoacan lake Estuarine water and sediments after oil spilling

    Energy Technology Data Exchange (ETDEWEB)

    Armenta-Arteaga, G. [Univ. Juarez Autonoma de Tabasco, D.A., Ciencias Biologicas, Villahermosa, Tabasco (Mexico); Elizalde-Gonzalez, M.P. [Centro de Quimica, Univ. Autonoma de Puebla, Puebla, Pue (Mexico)

    2003-07-01

    Intention, Goal, Scope, Background. Environmental pollution caused by oil spills is a major ecological problem. Oil contamination in the environment is primarily evaluated by measuring the chemical concentrations of hydrocarbons. The results of chemical analyses are important for estimating water and sediment quality in the risk assessment to the flora and fauna of oil-contaminated sites. In the world there are lake ecosystems under permanent chemical stress due to urbanization and the oil industry. Studies, however, have been generally limited to petroleum compounds and have not considered other pollutants of the site like PCBs, polychlorinated pesticides and heavy metals. Objective. Water and sediment from stations in the Mecoacan Lake in the Mexican State of Tabasco were analyzed for polycyclic aromatic compounds (PAHs), aliphatic hydrocarbons (AHs), polychlorinated biphenyls (PCBs), polychlorinated pesticides (PCPs) and heavy metals. The objective of this study was to examine the contaminant levels of the samples collected in February 1993 and 1996 after oil spills at the Mecoacan petroleum region. The goals of this study were to reveal the effect of the spills on the distribution of the hydrocarbons and assess the toxicological significance of the levels found. In addition, our aim was to examine the distribution of the PAHs in sediments from Mecoacan originated from both pyrolytic and petrogenic sources. Methods. Samples were collected from 19 stations and prepared according to the CARIPOL (Caribbean Pollution) methodology of the United Nations Environmental Programme (1992) of the Great Caribbean Region for hydrocarbons in marine and coastal water, and sediments. The gas-chromatographic and atomic absorption analysis of the samples was performed after sampling. (orig.)

  4. Increasing oil recovery from heavy oil waterfloods

    Energy Technology Data Exchange (ETDEWEB)

    Brice, B.W. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[BP Exploration, Calgary, AB (Canada)

    2008-10-15

    In an effort to optimize waterflood strategies in Alaska, the authors examined the results of up to 50 years of waterflooding on 166 western Canadian waterfloods recovering oil of less than 30 degrees API. The study determined the best operating practices for heavy oil waterflooding by investigating the difference between waterflooding of heavy oil and lighter oil counterparts. Operators of light oil waterflooding are advised to begin waterflooding early and maintain the voidage replacement ratio (VRR) at 1. However, this study showed that it is beneficial to delay the start of waterflooding until a certain fraction of the original oil in place was recovered. Varying the VRR was also shown to correlate with increased ultimate recovery. This statistical study of 166 western Canadian waterfloods also examined the effect of injection strategy and the effect of primary production before waterflooding. Some pre-waterflood production and under injection time is advantageous for ultimate recovery by waterfloods. Specific recommendations were presented for waterfloods in reservoirs with both high and low API gravity ranges. Each range showed a narrow sweet spot window where improved recovery occurred. 27 refs., 13 figs.

  5. Spectroscopic study of Mentha oils

    Science.gov (United States)

    Rai, A. K.; Singh, A. K.

    The visible fluorescence and excitation spectra of Mentha oils (Japanese mint oil, peppermint oil and spearmint oil) have been recorded. Different physical constants which are characteristic of the fluorescent molecules have been calculated for all three oils. Results reveal that the same group of organic compounds dominate in the oils of peppermint and spearmint, whereas some different compound is present in Japanese mint oil. It is also found that the fluorescence intensity of these oils is comparable to that of Rhodamine 6G dye in methanol solution. Our studies suggest that Mentha oils may be a useful lasing material in the 450-600 nm wavelength range.

  6. Adsorption Characteristics of Activated Carbon Derived from Pyrolytic Tire Char for Malachite Green%废轮胎活性炭对孔雀石绿的吸附性能研究

    Institute of Scientific and Technical Information of China (English)

    李丽; 张强年; 刘双喜; 朱坦

    2012-01-01

    Activated carbon produced from pyrolytic tire char in an industrial scale was investigated its potential ability to adsorb Malachite Green (MG) by a batch method.The effect of operation parameters,such as contact time,pH,adsorbent dosage,initial concentration,temperature,ionic strength and metal ion on the adsorption were investigated to provide more information about the adsorption characteristics of the activated pyrolytic tire char (APTC).It has shown that APTC is a potential adsorbent for MG removal.The results show that higher initial MG solution,higher initial solution pH (pH>7.0) and higher temperature are fit for the adsorption,while higher ionic strength and the presence of metal ions are unfavorable for the adsorption process.%以工业规模的废轮胎热解炭黑为原料,经过水蒸汽活化制备废轮胎活性炭,采用间歇实验法考察了废轮胎活性炭对三苯甲烷类染料孔雀石绿的吸附性能.系统考察了操作因素如接触时间、溶液pH、吸附剂用量、孔雀石绿初始浓度、离子强度、重金属离子以及温度等对吸附过程以及吸附性能的影响.结果表明,废轮胎活性炭是孔雀石绿的有效吸附剂,其吸附容量高于文献报道的相关吸附剂.吸附过程在240 min内达到平衡,与相关吸附剂的平衡时间一致;孔雀石绿初始浓度高、较高的初始溶液pH值以及升高吸附温度有利于废轮胎活性炭对孔雀石绿的吸附;而较高的溶液离子强度以及重金属离子的存在不利于孔雀石绿的吸附.

  7. Chemometric techniques in oil classification from oil spill fingerprinting.

    Science.gov (United States)

    Ismail, Azimah; Toriman, Mohd Ekhwan; Juahir, Hafizan; Kassim, Azlina Md; Zain, Sharifuddin Md; Ahmad, Wan Kamaruzaman Wan; Wong, Kok Fah; Retnam, Ananthy; Zali, Munirah Abdul; Mokhtar, Mazlin; Yusri, Mohd Ayub

    2016-10-15

    Extended use of GC-FID and GC-MS in oil spill fingerprinting and matching is significantly important for oil classification from the oil spill sources collected from various areas of Peninsular Malaysia and Sabah (East Malaysia). Oil spill fingerprinting from GC-FID and GC-MS coupled with chemometric techniques (discriminant analysis and principal component analysis) is used as a diagnostic tool to classify the types of oil polluting the water. Clustering and discrimination of oil spill compounds in the water from the actual site of oil spill events are divided into four groups viz. diesel, Heavy Fuel Oil (HFO), Mixture Oil containing Light Fuel Oil (MOLFO) and Waste Oil (WO) according to the similarity of their intrinsic chemical properties. Principal component analysis (PCA) demonstrates that diesel, HFO, MOLFO and WO are types of oil or oil products from complex oil mixtures with a total variance of 85.34% and are identified with various anthropogenic activities related to either intentional releasing of oil or accidental discharge of oil into the environment. Our results show that the use of chemometric techniques is significant in providing independent validation for classifying the types of spilled oil in the investigation of oil spill pollution in Malaysia. This, in consequence would result in cost and time saving in identification of the oil spill sources.

  8. Tea tree oil.

    Science.gov (United States)

    Larson, David; Jacob, Sharon E

    2012-01-01

    Tea tree oil is an increasingly popular ingredient in a variety of household and cosmetic products, including shampoos, massage oils, skin and nail creams, and laundry detergents. Known for its potential antiseptic properties, it has been shown to be active against a variety of bacteria, fungi, viruses, and mites. The oil is extracted from the leaves of the tea tree via steam distillation. This essential oil possesses a sharp camphoraceous odor followed by a menthol-like cooling sensation. Most commonly an ingredient in topical products, it is used at a concentration of 5% to 10%. Even at this concentration, it has been reported to induce contact sensitization and allergic contact dermatitis reactions. In 1999, tea tree oil was added to the North American Contact Dermatitis Group screening panel. The latest prevalence rates suggest that 1.4% of patients referred for patch testing had a positive reaction to tea tree oil.

  9. Essentials of essential oils.

    Science.gov (United States)

    Manion, Chelsea R; Widder, Rebecca M

    2017-05-01

    Information to guide clinicians in educating and advising patients using or intending to use essential oils for self-administered aromatherapy or other medicinal purposes is presented. The term essential oils refers to highly concentrated, aromatic oils extracted from plants by steam distillation, hydrodiffusion, or pressure. Market reports indicate strong growth in the use of essential oils in the United States in recent decades. Therapeutic claims made in the marketing of essential oils have led the Food and Drug Administration to caution a number of suppliers. Along with rapid growth in sales of essential oils to consumers there has been an increase in the amount of published evidence regarding aromatherapy and essential oils; the annual number of relevant articles indexed using Medical Subject Headings terminology has doubled since 2004. In order to help ensure proper application and safe use of essential oils as a self-care modality, healthcare professionals can benefit from a general knowledge of the terminology and foundational concepts of medicinal use of essential oils, as well as resources to facilitate evaluations of appropriateness of use. Because of the increasing popularity of essential oils and the prevalence of essential oil-based self-care practices targeting a wide variety of ailments in the United States, healthcare professionals must be prepared to address concerns about the agents' safety and efficacy. Proper literature evaluation requires the ability to discern the quality of an oil, the safety of administration, and the validity of its use. Copyright © 2017 by the American Society of Health-System Pharmacists, Inc. All rights reserved.

  10. Treatment of vegetable oils

    Energy Technology Data Exchange (ETDEWEB)

    Bessler, T.R.

    1986-05-13

    A process is described for preparing an injectable vegetable oil selected from the group consisting of soybean oil and sunflower oil and mixtures thereof which comprise: (a) first treating the vegetable oil at a temperature of 80/sup 0/C to about 130/sup 0/C with an acid clay; (b) deodorizing the vegetable oil with steam at a temperature of 220/sup 0/C to about 280/sup 0/C and applying a vacuum to remove volatilized components; (c) treating the deodorized vegetable oil, at a temperature of from about 10/sup 0/C to about 60/sup 0/C, with an acid clay to reduce the content of a member selected from the group consisting of diglycerides, tocopherol components, and trilinolenin and mixtures thereof, wherein the acid clay is added in a weight ratio to the deoderized vegetable oil of from about 1:99 to about 1:1; and (d) thereafter conducting a particulate filtration to remove a substantial portion of the acid clay from the vegetable oil, wherein the filtration is accomplished with filters having a pore size of from about 0.1 to 0.45 microns, thereby obtaining the injectable oil.

  11. Oil:SOS

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Chinese economy will be hit hard if the recent oil shortage is not eased quickly This year’s oil shortage was reminis- cent of the previous one in 2005. Cargo drivers drove gingerly with half-full tanks,diesel generators sat silently waiting for oil that wasn’t there,and many taxis even stopped running because of the shortage. This time the oil shortage,which first started in southern cities like Guangzhou and Shenzhen in August,spread to northern cities like Zhengzhou and Taiyuan in November.

  12. Oil-based paint poisoning

    Science.gov (United States)

    Paint - oil based - poisoning ... Hydrocarbons are the primary poisonous ingredient in oil paints. Some oil paints have heavy metals such as lead, mercury, cobalt, and barium added as pigment. These heavy metals can cause additional ...

  13. Crude Oil Spills and Health

    Science.gov (United States)

    ... Environmental Enforcement, U.S. Department of the Interior Emergency Management: Oil Spills U.S. Environmental Protection Agency Oil Spill Preparation and Response U.S. Fish and Wildlife Service Return to top Oil Spills and Wildlife ...

  14. Characterization of bio-oil from induction-heating pyrolysis of food-processing sewage sludges using chromatographic analysis.

    Science.gov (United States)

    Tsai, Wen-Tien; Lee, Mei-Kuei; Chang, Jeng-Hung; Su, Ting-Yi; Chang, Yuan-Ming

    2009-05-01

    In this study, gas chromatography-mass spectrometry (GC-MS) was used to analyze the pyrolytic bio-oils and gas fractions derived from the pyrolysis of industrial sewage sludges using induction-heating technique. The liquid products were obtained from the cryogenic condensation of the devolatilization fraction in a nitrogen atmosphere using a heating rate of 300 degrees C/min ranging from 25 to 500 degrees C. The analytical results showed that the pyrolysis bio-oils were very complex mixtures of organic compounds and contained a lot of nitrogenated and/or oxygenated compounds such as aliphatic hydrocarbons, phenols, pyridines, pyrroles, amines, ketones, and so on. These organic hydrocarbons containing nitrogen and/or oxygen should originate from the protein and nucleic acid textures of the microbial organisms present in the sewage sludge. The non-condensable devolatilization fractions were also composed of nitrogenated and oxygenated compounds, but contained small fractions of phenols, 1H-indoles, and fatty carboxylic acids. On the other hand, the compositions in the non-condensable gas products were principally carbon dioxide, carbon monoxide and methane analyzed by gas chromatography-thermal conductivity detector (GC-TCD).

  15. Oil spill statistics and oil spill monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Viebahn, C. von [Greifswald Univ. (Germany). Dept. of Geography

    2001-09-01

    The main parts of the report describe the analysis and it's results of German and international oil spill data (North Sea and Baltic Sea). In order to improve the current oil spill monitoring of the Baltic Sea regarding oil spill data, the report proposes the establishment of a combined monitoring system; its suitability is shown on selected examples. This contains today's pollution control aircraft plus in-service aircraft and satellites. (orig.) [German] Der Schwerpunkt der Arbeit liegt in der Analyse von Daten ueber marine Oelschadensfaelle in deutschen und internationalen Gewaessern (Nord- und Ostsee). Um die heutige Ueberwachung der Ostsee im Hinblick auf Oelschadensfaelle zu verbessern, wird die Einrichtung eines kombinierten Ueberwachungssystems vorgeschlagen und dessen Eignung an ausgewaehlten Beispielen dargestellt. Dieses umfasst sowohl die heute eingesetzten Ueberwachungsflugzeuge sowie zusaetzlich Linienflugzeuge und Satelliten. (orig.)

  16. Oil supply and demand

    Energy Technology Data Exchange (ETDEWEB)

    Rech, O

    2004-07-01

    World oil demand, driven by economic development in China, posted the highest growth rate in 20 years. In a context of geopolitical uncertainty, prices are soaring, encouraged by low inventory and the low availability of residual production capacity. Will 2004 bring a change in the oil market paradigm? (author)

  17. Another Oil Disaster

    Institute of Scientific and Technical Information of China (English)

    YIN PUMIN

    2010-01-01

    @@ More than 800 fishing boats in Dalian,a coastal city in northeast China's Liaoning Province,joined the effort on July 20 to clean up crude oil that gushed into the sea after two oil pipelines exploded at Dalian Xingang Harbor four days earlier.

  18. Krill oil: new nutraceuticals

    Directory of Open Access Journals (Sweden)

    Beuy Joob

    2015-08-01

    Full Text Available Krill oil is a new available health product which is produced from deep marine species. Its property is to promote good health. The good lipid composition and antioxidant enrichment make krill oil a new nutraceutical for reducing health problems.

  19. Tree nut oils

    Science.gov (United States)

    The major tree nuts include almonds, Brazil nuts, cashew nuts, hazelnuts, macadamia nuts, pecans, pine nuts, pistachio nuts, and walnuts. Tree nut oils are appreciated in food applications because of their flavors and are generally more expensive than other gourmet oils. Research during the last de...

  20. Cooking with Healthier Fats and Oils

    Science.gov (United States)

    ... use fats and oils, choose those with less saturated fat, trans fat, and cholesterol. Choose Less Often Choose More Often Percent of Saturated Fat Canola Oil Safflower Oil Sesame Oil Sunflower Oil ...

  1. Rheology of waxy oils

    Energy Technology Data Exchange (ETDEWEB)

    Alicke, Alexandra A.; Marchesini, Flavio H.; Mendes, Paulo R. de Souza [Pontificia Universidade Catolica do Rio de Janeiro (PUC-Rio), RJ (Brazil)], e-mails: fhmo@puc-rio.br, pmendes@puc-rio.br; Ziglio, Claudio [Petrobras Research Center, Rio de Janeiro, RJ (Brazil)], e-mail: ziglio@petrobras.com.br

    2010-07-01

    It is well known that below the crystallization temperature the rheology of waxy oils changes from Newtonian to an extremely complex non-Newtonian behavior, which is shear-rate and temperature-history dependent. Along the last decades a lot of effort has been put into obtaining reliable rheological measurements from different oils so as to understand the yielding of waxy oils as well as the effects of shear and temperature histories on rheological properties, such as viscosity, yield stress, storage and loss moduli. In this paper we examine in detail the related literature, discussing the main reasons for some disagreements concerning the history effects on the flow properties of waxy oils. In addition, we performed temperature ramps and stress-amplitude-sweep tests and compared the results obtained with the main trends observed, highlighting the effects of cooling and shear on the microstructure and consequently on the rheological properties of these oils. (author)

  2. Chinese Oil Giants Eye Canadian Oil Fields

    Institute of Scientific and Technical Information of China (English)

    Miao Bin

    2005-01-01

    @@ SinoCanada, a subsidiary of Sinopec International Petroleum Exploration and Development Corporation, and Canada-based Synenco Energy Inc announced on May 31 that they have inked a series of agreements to launch a joint venture for common development of the oil sand project located in Athabasca region of Northeast Canada's Alberta Province. Based on the agreements, Sinopec will pay 105 million Canadian dollars (US$84 million) for a stake in Canada's Northern Lights oil sands project while Synenco owns the remaining 60 percent share,and will operate the project as the managing partner.

  3. Experimental Researches on Milled Wood Lignin Pyrolysis Based on Analysis of Bio-oil

    Institute of Scientific and Technical Information of China (English)

    GUO Xiu-juan; WANG Shu-rong; WANG Kai-ge; LUO Zhong-yang

    2011-01-01

    The structure of milled wood lignin(MWL), isolated via the Bj(6)rkman procedure, was studied by means of 1H NMR spectroscopy and Fourier transform infrared spectroscopy, and then its pyrolytic product distribution was investigated on a pyrolysis device. MWL obtained from Manchurian Ash(MA) contained more methoxyl and free phenolic hydroxyl groups per C9 unit than MWL from Mongolian Pine(MP) due to the existence of both guaiacyl and syringyl units, which have a major influence on the pyrolysis behavior of lignin. The results of pyrolysis show that MWL from MA generated a higher yield of bio-oil, mainly composed of phenols, guaiacols, syringols and catechols,and a less yield of char, in addition to the gaseous products CO, CO2, methane and methanol, compared with MWL from MP. Guaiacol and syringol were the typical products from G-lignin and S-lignin, probably attributed to the easier cleavage of the aryl-alkyl linkage in the side chain compared with the C-OCH3 bond in the benzene ring. The degradation of MWL from MP was dominated by the demethylation reaction and the cleavage of aliphatic -CH2OH at the γ-position, followed by the cracking of the Cα-Cβ and C4-Cα bonds.

  4. Thermal treatment of Lloydminster heavy oil: yield and product separation by adsorption chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Tiwari, P.K.; Sastre, H.; Chornet, E.; Kotlyar, L.S.; Ripmeester, J.A.; Overend, R.P. (University of Sherbrooke, Quebec (Canada). Dept. of Chemical Engineering)

    1989-09-01

    The effect of thermal treatment on Lloydminster heavy oil has been studied under pyrolytic, catalytic and non-catalytic hydropyrolysis and hydrogen donor solvent (tetralin) regimes using a batch autoclave. Product yields are reported for each type of reaction regime in terms of gases, maltenes, asphaltenes and toluene insoluble organic matter (coke). The maltene fraction was further separated by column chromatography into four chemical compound types namely: saturates, mono- and di-aromatics, polyaromatics and polars. The asphaltene fraction was also separated in four fractions by column chromatography by elution with solvents of increasing polarity. These fractions were characterized by FTIR and {sup 1}{sup 3}C NMR. The evolution of these fractions was studied as a function of the treatment. Tetralin was found to be effective in eliminating coke and increasing the maltene content relative to other treatments. It has been observed that the decrease of polyaromatic and polar species in the maltenes results in a corresponding increase of saturates. The asphaltene yield also decreases with thermal treatment. In all treatments the asphaltene fractions rich in polar and highly functional groups decrease drastically. 34 refs., 7 figs., 2 tabs.

  5. Detection of argan oil adulterated with vegetable oils: New markers

    Energy Technology Data Exchange (ETDEWEB)

    Ourrach, I.; Rada, M.; Perez-Camino, M. C.; Benaissa, M.; Guinda, A

    2012-07-01

    This work aims to contribute to controlling the authenticity of pure argan oil, a valuable Moroccan product. Fatty acids, hydrocarbon fraction, 3,5-stigmastadiene, the alkyl esters of fatty acids, chlorophyllic pigments and physical properties such as viscosity, density and refractive index were studied in order to detect the adulteration of argan oil with edible vegetable oils. The results found in this study show that 3,5-stigmastadiene, kaurene and pheophytin-a can be used as possible new markers for argan oil blends of up to 5% with refined, sunflower and virgin olive oils. Due to the similarity of the fatty acid compositions of the edible oils studied and argan oil, fatty acids can be employed as markers for the detection of argan oil adulteration at levels higher than 10%. Among the physical properties studied, the refractive index shows significant differences for sunflower oil and its blend at 10% with argan oil. (Author) 35 refs.

  6. GOOD OLD OIL

    Directory of Open Access Journals (Sweden)

    Akula Annapurna

    2013-10-01

    Full Text Available Nowadays everybody is getting puzzled and confused about choosing right oil for daily use. Most of the ads in the market revolving around sunflower oil only with different brand names claiming it is heart friendly. In recent years, younger generation may not be familiar much with our age old traditional oils like sesame oil. Sesame oil is also called as gingelly oil or til oil is rich in vitamin E and B. It is a good source of minerals like calcium, manganese and phosphorous and promotes healing. It contains high amounts of polyunsaturated fatty acids and decreases high blood pressure. Because of its antioxidant property, it decreases cholesterol and good for heart. It acts like a sedative, relieves mental fatigue and promotes sleep when it is used for head massage. It is having laxative nature, relieving constipation. When applied topically on to the skin it is acting as an excellent moisturizer and an emollient. Because of its natural antibacterial, antiviral and anti-inflammatory properties it keeps away the skin and tooth infections. Hence, it can be used by one and all without any hesitation for regular cooking. However, it is not preferred for deep frying. Let us once again say OLD IS GOLD

  7. Jojoba oil and derivates

    Energy Technology Data Exchange (ETDEWEB)

    Wisniak, T.

    1977-01-01

    Jojoba oil differs from all known seed oils by its almost complete absence of glycerides, making it more a liquid wax than a fat. It has become important as a possible substitute for sperm-whale oil to produce lubricants, lubricant additives and other products. The plant occurs naturally in southern Arizona and N.W. Mexico and its oil has long been used by Indians for medicinal, culinary, ritual and other purposes. It tolerates extreme daily fluctuations of temperature and grows well under the difficult soil and moisture conditions of the region. In the first part of this review the plant and its uses are described, including its floral, fruit and seed anatomy and the use of liquid wax during germination. Stored coryledon wax is used up by the embryo as a linear function of time during the first 30 days of germination and growth. Before germination, seeds weight about 0.59 mg and contain about 54% wax. The second and greater part of the review deals with jojoba oil (its extraction, properties, molecular description, toxicity and composition), jojoba meal, which remains after the oil has been extracted, and the chemical modification of the oil.

  8. Co-pyrolysis of waste propylene and gas oil from Campos Basin: a case study; Tecnologia de co-pirolise de polipropileno pos-consumo com gasoleo da Bacia de Campos: um estudo de caso

    Energy Technology Data Exchange (ETDEWEB)

    Assumpcao, Luiz Carlos F.N. de; Aguiar, Monica Regina M.P. de [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil); Carbonell, Montserrat Motas [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    In this study the process of co-pyrolysis of plastic polypropylene residues with gas-oil was evaluated, varying the temperature and the amount of polypropylene. The co-pyrolysis is a promising route to minimize the environmental impact caused by the inadequate plastic disposal, preventing its accumulation and giving a better use of the not renewable raw material (oil). The polypropylene samples and gas-oil were submitted to the thermal co-pyrolysis in inert atmosphere, varying the temperature from 400 deg C to 500 deg C and the amount of PP from 0,1 to 1,0 g. The influence of gas-oil was evaluated carrying the co-pyrolysis in the absence of PP. The pyrolyzed liquids produced by this thermal treatment had been characterized by modified gaseous chromatography objectifying the evaluation of the diesel fractions generation. As a result, the increase of PP amount lead to a reduction in the income of the pyrolytic liquid and to increase of the amount of solid generated. The effect of the increase of temperature showed an inverse result. The addition of PP in the reactor showed little interference in diesel range of distillation in the co-pyrolysis. On the other hand, an increase in temperature favors the increase of products in this range of distillation. The results show that plastic residue co-pyrolysis is a potential method of chemical recycling. (author)

  9. China Offshore Oil Logging Technology

    Institute of Scientific and Technical Information of China (English)

    Duan Kang

    1996-01-01

    @@ China offshore oil logging business entered a faster developing stage sin-ce 1982 with the beginning of international cooperation in its offshore oil exploration. Nearly 90% of the logging expertises of China National Offshore Oil Corporation (CNOOC)are in China Offshore Oil Logging Company (COOLC), headquartered in Yanjiao, Hebei Province.

  10. Yield gaps in oil palm

    NARCIS (Netherlands)

    Woittiez, Lotte S.; Wijk, van Mark T.; Slingerland, Maja; Noordwijk, van Meine; Giller, Ken E.

    2017-01-01

    Oil palm, currently the world's main vegetable oil crop, is characterised by a large productivity and a long life span (≥25 years). Peak oil yields of 12 t ha−1 yr−1 have been achieved in small plantations, and maximum theoretical yields as calculated with simulation models are 18.5 t oil ha−1 yr−1,

  11. 21 CFR 172.861 - Cocoa butter substitute from coconut oil, palm kernel oil, or both oils.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Cocoa butter substitute from coconut oil, palm... substitute from coconut oil, palm kernel oil, or both oils. The food additive, cocoa butter substitute from coconut oil, palm kernel oil, or both oils, may be safely used in food in accordance with the...

  12. Precious Oil, New Equipment

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ The oil price is flying sky high, not only with respect to the purchase price, but also in oil futures and stock. On November 7, the International oil future price reached a new high of US$ 98.62 per barrel in New York.Just two days before the peak day, on November 5, the China National Petroleum Corporation (CNPC) was back in China's A-share market with a new offering. The opening quotation on the first day of this new issue reached RMB 48.60 yuan per share.

  13. OIL DISPLACEMENT IN MISCIBLE CONDITION

    Directory of Open Access Journals (Sweden)

    Ivanka Juttner

    1997-12-01

    Full Text Available After primary oil recovery in reservoirs remains about 70% of unexploited oil. To improve the recovery of the remaining reserves, injection of a fluid provide the extra energy in a mchunical form. Oil displacement can he achieved by gas injection of lean natural gas, mainly methane, carbon dioxide etc. Oil displacement can be in immiscible or miscible conditions. This paper deals with mechanism of miscible gas drive. On the basis of simulation of the oil displacement process by gas injection into oil field Žutica the character of process, i. c. a degree of miscibility or immiscibility between the injected fluid and reservoir oil was determined.

  14. MOC encourages private oil companies

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    The Ministry of Commerce issued a guideline in late June, encouraging private oil companies to take part in refined oil's processing, transportation and retail. The government will support competitive and large companies to integrate into asset-based oil groups and technology service-based oil companies, according to the guideline. Private business will be encouraged to obtain stable access to refined oil resources, technology and management service. China's refined oil market is largely controlled by three State-owned heavyweights: PetroChina, the largest oil producer in Asia; Sinopec,

  15. A comparison of the higher order harmonic components derived from large-amplitude Fourier transformed ac voltammetry of myoglobin and heme in DDAB films at a pyrolytic graphite electrode.

    Science.gov (United States)

    Lee, Chong-Yong; Bond, Alan M

    2010-04-06

    A debate as to whether heme remains bound or is released in myoglobin molecules incorporated into a didodecyldimethylammonium bromide (DDAB) film adhered to a pyrolytic graphite electrode has prompted a comparison of their electrochemistry by the highly sensitive large-amplitude Fourier transformed ac voltammetric method. The accessibility of third, fourth, and higher harmonic components that are devoid of background current and the enhanced resolution relative to that available in dc voltammetry have allowed a detailed comparison of the Fe(III)/Fe(II) and Fe(II)/Fe(I) redox processes of myoglobin and heme molecules to be undertaken as a function of buffer composition and pH and in the presence and absence of NaBr in the buffer and/or film. Under most conditions examined, only very subtle differences, in the Fe(III)/Fe(II) process were found, implying this process cannot be used to indicate the intactness or otherwise of myoglobin in myoglobin-DDAB films. In contrast, higher order ac harmonics obtained from myoglobin-DDAB and heme-DDAB films reveal pH dependent differences with respect to the Fe(II)/Fe(I) couple. Analysis of the ac harmonics, and with the hypothesis that the Fe(II)/Fe(I) process reflects the myoglobin state, suggests that the majority of the iron heme is released from myoglobin-DDAB (pH 5.0, no NaBr) films in contact with pH 5.0 (0.1 M sodium acetate) buffer solution devoid of or containing NaBr. However, myoglobin films prepared with pH 5.0 buffer containing NaBr shows significant difference in the higher harmonic shapes and midpoint potentials in the Fe(II)/Fe(I) process relative to the case when heme molecules are used, although as noted in other studies, a significant fraction of the Mb is rendered electroinactive in the presence of NaBr. The voltammetric responses of myoglobin and heme-DDAB (pH 5.0) films in contact with pH 7.0 (0.1 M) phosphate buffer solution also exhibit significant differences in the Fe(II)/Fe(I) redox couple in the higher

  16. 7 CFR 985.4 - Spearmint oil.

    Science.gov (United States)

    2010-01-01

    ... oil. Spearmint oil, hereinafter referred to as oil, means essential oil extracted by distillation from... the production area, that produce a spearmint flavored oil. Oil shall be segregated into the following... 7 Agriculture 8 2010-01-01 2010-01-01 false Spearmint oil. 985.4 Section 985.4...

  17. Oil Rig Weather Observations

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Weather observations taken at offshore platforms along the United States coastlines. The majority are located in oil-rich areas of the Gulf of Mexico, Gulf of...

  18. Enhanced oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Chakma, A.; Rafiq Islam, M.; Berruti, F.

    1991-01-01

    Some forty to sixty percent of the original oil in place typically remains trapped in the reservoir after primary and secondary recoveries. Enhanced oil recovery refers to the recovery of the residual oil by different techniques. Many of the existing and proposed enhanced oil recovery techniques require sound understanding of basic chemical engineering principles such as fluid flow, heat and mass transfer, interfacial phenomena etc. Chemical EOR techniques require a good understanding of interfacial phenomena, chemical reaction, multicomponent absorption. Understanding of the fundamentals of the various EOR processes is not adequate. EOR is increasingly attracting a growing number of chemical engineers and, as a result, some of the fundamental aspect of EOR are now being investigated. However, much more remains to be done and chemical engineers can play an important role in providing a better understanding of EOR fundamentals. This volume presents selected papers on EOR presented at AICHE meetings.

  19. Peak oil and gas

    Energy Technology Data Exchange (ETDEWEB)

    Ziegler, W. H. [W. H. Ziegler, Av. des Mousquines 40bis, Lausanne (Switzerland); Campbell, C. J. [Stabbal Hill, Ballydehob, County Cork (Ireland); Zagar, J.J. [Four Blues, Schull, County Cork (Ireland)

    2009-07-01

    Oil and gas were formed under exceptional conditions in the geological past, meaning that they are subject to natural depletion, such that the past growth in production must give way to decline. Although depletion is a simple concept to grasp, public data on the resource base are extremely unreliable due to ambiguous definitions and lax reporting. The oil industry is reluctant to admit to an onset of decline carrying obvious adverse financial consequences. There are several different categories of oil and gas, from tar sands to deep water fields, each with specific characteristics that need to be evaluated. It is important to build a global model on a country by country basis in order that anomalous statistics may be identified and evaluated. Such a study suggests that the world faces the onset of decline, with far-reaching consequences given the central role of oil-based energy. It is accordingly an important subject deserving detailed consideration by policy makers. (author)

  20. Oil Spills Research

    Science.gov (United States)

    EPA monitors impacts and mitigates the effects of spilled oil, which threatens public health and safety, contaminates drinking water, causes fire and explosion, diminishes air and water quality, harms ecosystems, and more.

  1. Extracting oil from coffee

    Directory of Open Access Journals (Sweden)

    Elkin Mauricio López Fontal

    2010-04-01

    Full Text Available The present work describes oil being extracted from toasted coffee by the extrusion method; two products are obtained from this process: coffee oil and pulp. Toasted coffee was used which has a high amount of sensorial compounds. It should be noted that a significant criterion in evaluating the quality of coffee lies in its aroma. When extracting oil from coffee, a significant part of toasted coffee’s aromatic content leaves with it, varying according to the extraction method. A fixed oil having a high volatile load is thus obtained, presenting favourable sensory characteristics. The pulp was physically and chemically analysed to show its benefit and particular properties and, according to the results so obtained, it is a product having potential usefulness.

  2. Crude oil burning mechanisms

    DEFF Research Database (Denmark)

    van Gelderen, Laurens; Malmquist, Linus Mattias Valdemar; Jomaas, Grunde

    2015-01-01

    In order to improve predictions for the burning efficiency and the residue composition of in-situ burning of crude oil, the burning mechanism of crude oil was studied in relation to the composition of its hydrocarbon mixture, before, during and after the burning. The surface temperature, flame...... height, mass loss rate and residues of three hydrocarbon liquids (n-octane, dodecane and hexadecane), two crude oils (DUC and REBCO) and one hydrocarbon liquid mixture of the aforementioned hydrocarbon liquids were studied using the Crude Oil Flammability Apparatus. The experimental results were compared...... to the predictions of four conceptual models that describe the burning mechanism of multicomponent fuels. Based on the comparisons, hydrocarbon liquids were found to be best described by the Equilibrium Flash Vaporization model, showing a constant gas composition and gasification rate. The multicomponent fuels...

  3. Economic Geology (Oil & Gas)

    Science.gov (United States)

    Geotimes, 1972

    1972-01-01

    Briefly reviews the worldwide developments in petroleum geology in 1971, including exploration, new fields, and oil production. This report is condensed from the October Bulletin of the American Association of Petroleum Geologists. (PR)

  4. Economic Geology (Oil & Gas)

    Science.gov (United States)

    Geotimes, 1972

    1972-01-01

    Briefly reviews the worldwide developments in petroleum geology in 1971, including exploration, new fields, and oil production. This report is condensed from the October Bulletin of the American Association of Petroleum Geologists. (PR)

  5. Evaluation of levels of defect sites present in highly ordered pyrolytic graphite electrodes using capacitive and faradaic current components derived simultaneously from large-amplitude Fourier transformed ac voltammetric experiments.

    Science.gov (United States)

    Lee, Chong-Yong; Bond, Alan M

    2009-01-15

    The level of edge plane defect sites present in highly ordered pyrolytic graphite (HOPG) electrodes has been evaluated via analysis of dc, ac fundamental, and higher-order ac harmonics available from a single large-amplitude Fourier transformed (FT) ac voltammetric experiment. Deliberate introduction of a low level of edge plane defect was achieved by polishing, with a higher level being introduced via electrochemical pretreatment. Kinetics regimes associated with fast electron transfer on the edge plane defect sites and slow electron transfer on the basal plane surface are resolved under ac conditions when using the surface-sensitive [Fe(CN)(6)](3-/4-) redox probe. However, because of their insensitivity to slow electron transfer, higher-order ac faradaic harmonics almost exclusively detect only the much faster processes that emanate from edge plane defect sites. Thus, detection of fourth- and higher-order ac Faradaic harmonic components that are devoid of background capacitive current is possible at freshly cleaved HOPG in the region near the reversible potential for the [Fe(CN)(6)](3-/4-) process. Under these circumstances, dc cyclic voltammograms exhibit only reduction and oxidation peaks separated by more than 1 V. The fundamental ac harmonic provides detailed information on the capacitive current, which increases with the level of edge plane defect sites. Apparent charge transfer rate constants also can be derived from peak-to-peak separations obtained from the dc aperiodic component. Estimates of the percentage of edge plane defect sites based on ac higher harmonics, capacitance, and dc aperiodic component that are available from a single experiment have been compared. The edge plane defect levels deduced from capacitance (fundamental harmonic ac component) and higher harmonic Faradaic currents are considered to be more reliable than estimations based on apparent rate constants derived from the dc aperiodic component or conventional dc cyclic voltammogram.

  6. Fabrication of novel coated pyrolytic graphite electrodes for the selective nano-level monitoring of Cd²⁺ ions in biological and environmental samples using polymeric membrane of newly synthesized macrocycle.

    Science.gov (United States)

    Sahani, Manoj Kumar; Singh, A K; Jain, A K; Upadhyay, Anjali; Kumar, Amit; Singh, Udai P; Narang, Shikha

    2015-02-20

    Novel 5-amino-1,3,4-thiadiazole-2-thiol unit based macrocyclic ionophore 5,11,17-trithia-1,3,7,9,13,15,19,20,21-nonaazatetracyclo[14.2.1.1(4,7).1(10,13)]henicosa-4(20),10(21),16(19)-triene-6,12,18-trithione (M1), was synthesized and characterized. Preliminary studies on M1 have showed that it has more the affinity toward Cd(2+) ion. Thus, the macrocyclic ionophore (M1) was used as electroactive material in the fabrication of PVC-membrane electrodes such as polymeric membrane electrode (PME), coated graphite electrode (CGE) and coated pyrolytic graphite electrode (CPGE) were prepared and its performance characteristic were compared with. The electroanalytical studies performed on PME, CGE and CPGE revealed that CPGE having membrane composition M1:PVC:1-CN:NaTPB in the ratio of 7:37:54:2 exhibits the best potentiometric characteristics in terms of detection limit of 7.58×10(-9) mol L(-1), Nernstian slope of 29.6 mV decade(-1) of activity. The sensor was found to be independent of pH in the range 2.5-8.5. The sensor showed a fast response time of 10s and could be used over a period of 4 months without any significant divergence in its potentiometric characteristics. The sensor has been employed for monitoring of the Cd(2+) ion in real samples and also used as an indicator electrode in the potentiometric titration of Cd(2+) ion with EDTA.

  7. Authentication of vegetable oils.

    OpenAIRE

    Cunha, S.C.; Amaral, J S; Oliveira, M.B.P.P.

    2011-01-01

    Authenticity of vegetable oils continues to be a challenge and the target of many studies. Consumers expectancy on healthier products that conform to the labelled information, and the vast amount of legislation a bout the correct characterisation and classification of vegetable oils have boosted a number of scientific works on this subject. Analytical t echniques to face this challenge are, at least, as manifold as ar e the ways of adulteration, ranging fro...

  8. Shoreline oiling from the Deepwater Horizon oil spill.

    Science.gov (United States)

    Nixon, Zachary; Zengel, Scott; Baker, Mary; Steinhoff, Marla; Fricano, Gail; Rouhani, Shahrokh; Michel, Jacqueline

    2016-06-15

    We build on previous work to construct a comprehensive database of shoreline oiling exposure from the Deepwater Horizon (DWH) spill by compiling field and remotely-sensed datasets to support oil exposure and injury quantification. We compiled a spatial database of shoreline segments with attributes summarizing habitat, oiling category and timeline. We present new simplified oil exposure classes for both beaches and coastal wetland habitats derived from this database integrating both intensity and persistence of oiling on the shoreline over time. We document oiling along 2113km out of 9545km of surveyed shoreline, an increase of 19% from previously published estimates and representing the largest marine oil spill in history by length of shoreline oiled. These data may be used to generate maps and calculate summary statistics to assist in quantifying and understanding the scope, extent, and spatial distribution of shoreline oil exposure as a result of the DWH incident.

  9. Quantification of rice bran oil in oil blends

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, R.; Sharma, H. K.; Sengar, G.

    2012-11-01

    Blends consisting of physically refined rice bran oil (PRBO): sunflower oil (SnF) and PRBO: safflower oil (SAF) in different proportions were analyzed for various physicochemical parameters. The quantification of pure rice bran oil in the blended oils was carried out using different methods including gas chromatographic, HPLC, ultrasonic velocity and methods based on physico-chemical parameters. The physicochemical parameters such as ultrasonic velocity, relative association and acoustic impedance at 2 MHz, iodine value, palmitic acid content and oryzanol content reflected significant changes with increased proportions of PRBO in the blended oils. These parameters were selected as dependent parameters and % PRBO proportion was selected as independent parameters. The study revealed that regression equations based on the oryzanol content, palmitic acid composition, ultrasonic velocity, relative association, acoustic impedance, and iodine value can be used for the quantification of rice bran oil in blended oils. The rice bran oil can easily be quantified in the blended oils based on the oryzanol content by HPLC even at a 1% level. The palmitic acid content in blended oils can also be used as an indicator to quantify rice bran oil at or above the 20% level in blended oils whereas the method based on ultrasonic velocity, acoustic impedance and relative association showed initial promise in the quantification of rice bran oil. (Author) 23 refs.

  10. Moringa Seed Oils

    Directory of Open Access Journals (Sweden)

    Joana O. Ilesanmi

    2010-01-01

    Full Text Available This study was conducted to determine the effects of neem (Azadirachta indica A. Juss and moringa (Moringa oleifera seed oils on the storability of cowpea grain. Cowpea samples were treated with various concentrations (0.5, 1.0, and 1.5 mL/200 g cowpea of pure neem and moringa oils and their mixtures in ratios of 1:1, 1:2, and 1:3. The treated cowpea samples were stored for 180 days. Data were collected every 30 days on number of eggs laid, total weevil population, and percentage of uninfested grains and analysed statistically. Significantly different means were compared using LSD at <.05. Increasing oil concentration resulted in better cowpea protection, for example, in oviposition where the control had 6513 eggs, only 8 eggs were recorded in pure neem oil-treated sample at 0.5 mL/200 g. Generally, better results were obtained with higher oil concentrations either in their pure forms or mixtures. The control had a total weevil population of 4988, while most treated samples had none. The control samples had 0% uninfested grains, while 73–94% of uninfested grains were observed in treated samples after 6 months of storage. Therefore, mixture of the oils at 1.5 mL/200 g can be effectively used to store cowpea.

  11. Heavy fuel oil pyrolysis and combustion: kinetics and evolved gases investigated by TGA-FTIR

    KAUST Repository

    Abdul Jameel, Abdul Gani

    2017-08-24

    Heavy fuel oil (HFO) obtained from crude oil distillation is a widely used fuel in marine engines and power generation technologies. In the present study, the pyrolysis and combustion of a Saudi Arabian HFO in nitrogen and in air, respectively, were investigated using non-isothermal thermo-gravimetric analysis (TGA) coupled with a Fourier-transform infrared (FTIR) spectrometer. TG and DTG (differential thermo-gravimetry) were used for the kinetic analysis and to study the mass loss characteristics due to the thermal degradation of HFO at temperatures up to 1000°C and at various heating rates of 5, 10 and 20°C/min, in air and N2 atmospheres. FTIR analysis was then performed to study the composition of the evolved gases. The TG/DTG curves during HFO combustion show the presence of three distinct stages: the low temperature oxidation (LTO); fuel decomposition (FD); and high temperature oxidation (HTO) stages. The TG/DTG curves obtained during HFO pyrolysis show the presence of two devolatilization stages similar to that seen in the LTO stage of HFO combustion. Apart from this, the TG/DTG curves obtained during HFO combustion and pyrolysis differ significantly. Kinetic analysis was also performed using the distributed activation energy model, and the kinetic parameter (E) was determined for the different stages of HFO combustion and pyrolysis processes, yielding a good agreement with the measured TG profiles. FTIR analysis showed the signal of CO2 as approximately 50 times more compared to the other pollutant gases under combustion conditions. Under pyrolytic conditions, the signal intensity of alkane functional groups was the highest followed by alkenes. The TGA-FTIR results provide new insights into the overall HFO combustion processes, which can be used to improve combustor designs and control emissions.

  12. Spreading of oil and the concept of average oil thickness

    Energy Technology Data Exchange (ETDEWEB)

    Goodman, R. [Innovative Ventures Ltd., Cochrane, AB (Canada); Quintero-Marmol, A.M. [Pemex E and P, Campeche (Mexico); Bannerman, K. [Radarsat International, Vancouver, BC (Canada); Stevenson, G. [Calgary Univ., AB (Canada)

    2004-07-01

    The area of on oil slick on water can be readily measured using simple techniques ranging from visual observations to satellite-based radar systems. However, it is necessary to know the volume of spilled oil in order to determine the environmental impacts and best response strategy. The volume of oil must be known to determine spill quantity, response effectiveness and weathering rates. The relationship between volume and area is the average thickness of the oil over the spill area. This paper presents the results of several experiments conducted in the Gulf of Mexico that determined if average thickness of the oil is a characteristic of a specific crude oil, independent of spill size. In order to calculate the amount of oil on water from the area of slick requires information on the oil thickness, the inhomogeneity of the oil thickness and the oil-to-water ratio in the slick if it is emulsified. Experimental data revealed that an oil slick stops spreading very quickly after the application of oil. After the equilibrium thickness has been established, the slick is very sensitive to disturbances on the water surface, such as wave action, which causes the oil circle to dissipate into several small irregular shapes. It was noted that the spill source and oceanographic conditions are both critical to the final shape of the spill. 31 refs., 2 tabs., 8 figs.

  13. Phenolation of vegetable oils

    Directory of Open Access Journals (Sweden)

    ZORAN S. PETROVIĆ

    2011-04-01

    Full Text Available Novel bio-based compounds containing phenols suitable for the syn­thesis of polyurethanes were prepared. The direct alkylation of phenols with different vegetable oils in the presence of superacids (HBF4, triflic acid as ca­talysts was studied. The reaction kinetics was followed by monitoring the de­crease of the double bond content (iodine value with time. In order to under­stand the mechanism of the reaction, phenol was alkylated with model com­pounds. The model compounds containing one internal double bond were 9-oc­tadecene and methyl oleate and those with three double bonds were triolein and high oleic safflower oil (82 % oleic acid. It was shown that the best structures for phenol alkylation are fatty acids with only one double bond (oleic acid. Fatty acids with two double bonds (linoleic acid and three double bonds (lino­lenic acid lead to polymerized oils by a Diels–Alder reaction, and to a lesser extent to phenol alkylated products. The reaction product of direct alkylation of phenol with vegetable oils is a complex mixture of phenol alkylated with poly­merized oil (30–60 %, phenyl esters formed by transesterification of phenol with triglyceride ester bonds (<10 % and unreacted oil (30 %. The phenolated vegetable oils are new aromatic–aliphatic bio-based raw materials suitable for the preparation of polyols (by propoxylation, ethoxylation, Mannich reactions for the preparation of polyurethanes, as intermediates for phenolic resins or as bio-based antioxidants.

  14. Compositional analysis of bio-oil from pyrolysis of algae%海藻热解生物油的成分分析

    Institute of Scientific and Technical Information of China (English)

    王爽; 王谦; 徐姗楠; 姜秀民; 吉恒松; 何志霞

    2013-01-01

    comparison between two bio-oils that Enteromorpha clathrata bio-oil had lots of hydrocarbons, carboxylic acids and their derivatives, while Sargassum natans bio-oil contained many alcohols compounds and steroids. In addition, in Sargassum natans bio-oil, palmitate, oleic acid, and peanut acid were also detected. Furthermore, the pyrolysis mechanism of seaweed biomass was studied preliminarily. The GC-MS method was also applied to analyze the collected oil pyrolyzed from pure protein. It was shown that nitrogen-containing compounds occupied 50%in the product, and phenols and aldehydes accounted for a part of oil, while alcohols, ketones and ethers were not found. The results also indicated that aromatic hydrocarbons did not exist in oil of protein. Most nitrogen-containing compounds in algae pyrolytic bio-oil were in accordance with the decomposition of protein. It was found in the result that the nitrogen content in bio-oil of Enteromorpha clathrata was apparently higher than that of Sargassum natans, which was closely due to their protein content. In this paper, the effects of temperature and carrier gas on the behavior of seaweed fast pyolysis were analyzed. The oil, gas and coke production rates were obtained, respectively. The bio-oils pyrolyzed under different work conditions were very similar in composition, but the relative contents of the components were different. Significant difference analysis was used to analyze the results. Pyrolysis temperature played an important role on the distribution of algal bio-oil composition, while the influence of the carrier gas flow rate was not obvious. The carrier gas only had the effect on the contents of C11∼C15, nitrogen-containing compounds, and carboxylic acids and derivatives. The optimum temperature for algal pyrolytic bio-oil was determined to be from 500 to 600℃. Comparing bio-oil pyrolyzed from seaweed with that from terrestrial lignocelluloses biomass, it was obvious to find that the content of hydrocarbons in

  15. Estudo voltamétrico do complexo de cobre(II com o ligante vermelho de alizarina S, adsorvido na superfície do eletrodo de grafite pirolítico Voltammetric study of complex of copper (II with alizarin red S ligand, absorbed on surface of pyrolytic graphite electrode

    Directory of Open Access Journals (Sweden)

    Victor E. Mouchrek Filho

    1999-06-01

    Full Text Available The alizarin red S (ARS has been used as a spectrophotometric reagent of several metals for a long time. Now this alizarin has been used as modifier agent of electrodes, for voltammetric analyses. In this work cyclic voltammetry experiments was accomplished on closed circuit, with the objective of studying the voltammetric behavior of alizarin red S adsorbed and of its copper complex, on the surface of the pyrolytic graphite electrode. These studies showed that ARS strongly adsorbs on the surface of this electrode. This adsorption was used to immobilize ions copper(II from the solution.

  16. Brine crude oil interactions at the oil-water interface

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    mechanisms. The ion specific interaction between fines and polar fractions of crude oil at the oil-water interface has been less explored. In this study the relative affinity between different ions and the oil surface was determined. The experiments prove the importance of Ca2+, SO42-, and HPO42- ions...... emulsion formation at 0.05 mol/1. The amount of emulsion formation showed significant dependency on the type of acid doped in oil. Experiments demonstrate that the brine solution can alter the micro forces at the oil-water interface, and this ion specific interaction leads to oil emulsion formation......The impact of brine salinity and its ionic composition on oil displacement efficiency has been investigated extensively in recent years due to the potential of enhanced oil recovery (EOR). Wettability alterations through relative interactions at the mineral surface have been the basis of proposed...

  17. Abandoned Texas oil fields

    Energy Technology Data Exchange (ETDEWEB)

    1980-12-01

    Data for Texas abandoned oil fields were primarily derived from two sources: (1) Texas Railroad Commission (TRRC), and (2) Dwight's ENERGYDATA. For purposes of this report, abandoned oil fields are defined as those fields that had no production during 1977. The TRRC OILMASTER computer tapes were used to identify these abandoned oil fields. The tapes also provided data on formation depth, gravity of oil production, location (both district and county), discovery date, and the cumulative production of the field since its discovery. In all, the computer tapes identified 9211 abandoned fields, most of which had less than 250,000 barrel cumulative production. This report focuses on the 676 abandoned onshore Texas oil fields that had cumulative production of over 250,000 barrels. The Dwight's ENERGYDATA computer tapes provided production histories for approximately two-thirds of the larger fields abandoned in 1966 and thereafter. Fields which ceased production prior to 1966 will show no production history nor abandonment date in this report. The Department of Energy hopes the general availability of these data will catalyze the private sector recovery of this unproduced resource.

  18. Pyrolysis Oil Biorefinery.

    Science.gov (United States)

    Meier, Dietrich

    2017-03-14

    In biorefineries several conversion processes for biomasses may be applied to obtain maximum value from the feed materials. One viable option is the liquefaction of lignocellulosic feedstocks or residues by fast pyrolysis. The conversion technology requires rapid heating of the biomass particles along with rapid cooling of the hot vapors and aerosols. The main product, bio-oil, is obtained in yields of up to 75 wt% on a dry feed basis, together with by-product char and gas which are used within the process to provide the process heat requirements; there are no waste streams other than flue gas and ash. Bio-oils from fast pyrolysis have a great potential to be used as renewable fuel and/or a source for chemical feedstocks. Existing technical reactor designs are presented together with actual examples. Bio-oil characterization and various options for bio-oil upgrading are discussed based on the potential end-use. Existing and potential utilization alternatives for bio-oils are presented with respect to their use for heat and power generation as well as chemical and material use.

  19. Anthelmintic Activity of Grapeseed Oil and Linseed Oil

    Directory of Open Access Journals (Sweden)

    Goswami J

    2013-05-01

    Full Text Available The aim of the present study was to investigate the anthelminthic activity of vegetable fixed oils,grapeseed and linseed oil using adult earthworm, Pheritima posthuma. The oils were tested at differentconcentrations for the determination of paralysis time and death time of the earthworms. Albendazole isused as standard and it was found that grapeseed and linseed oil showed a better anthelminthic activityin comparison with the standard.

  20. Olive oil and pomace olive oil processing

    Directory of Open Access Journals (Sweden)

    Siragakis, George

    2006-03-01

    Full Text Available Olive oil processing is introduced in food industry at the end of the nineteenth century and a lot of improvements have been initialized since. The steps for refining are, settling, neutralizing, bleaching and deodorizing. Monitoring of effective refining and the use of processes that remove less minor components of olive oil, like polyphenols and tocopherols are some issues for the process. The stringent environmental requirements and the target of industry for continuous improvements and cost savings, forcing equipment manufacturers to innovations and new products. The complete removal of polycyclic aromatic hydrocarbons during pomace oil process and the utilization of distillates are also important areas for research and development.El procesado del aceite de oliva se introdujo en la industria alimentaria a finales del siglo diecinueve y desde entonces se han realizado considerables mejoras. Los pasos de refinación son: decantado, neutralización, decoloración, y desodorización. La monitorización de una refinación efectiva así como el uso de procesos que eliminen una menor proporción de componentes menores del aceite de oliva, tales como polifenoles y tocoferoles, son algunos de los objetivos del proceso. La rigurosa normativa medioambiental y el interés de la industria por introducir mejoras y ahorro de costes han forzado a los fabricantes de equipos a innovar y desarrollar nuevos productos. La eliminación completa de los hidrocarburos aromáticos policíclicos durante el refinado del aceite de orujo y la utilización de los destilados son también áreas importantes de investigación y desarrollo.

  1. RECENT OIL PRICE DECLINE BENEFITS OIL GIANTS LIMITEDLY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ Sinopec, Asia's largest refiner, hasn't really benefited from recent declines in global crude oil prices, because its refining costs still far exceed domestic oil product prices. China caps refined oil product prices at relatively low levels by world standards.

  2. Oil scenarios; Escenarios petroleros

    Energy Technology Data Exchange (ETDEWEB)

    Quiros Corradi, Alberto [Oxford Energy Policy Club (United States)

    2003-04-15

    If there is a war in Middle East affecting the Saudi Arabian crude oil production, the crude oil prices will increase at unimaginable levels. This is due to both the current decrease of the production capacity of Venezuela and the Nigeria's political fragility. Therefore, despite the fact that the majority of the reasons why the United States invade Irak are unknown, it is clear that the crude oil is one of them and is playing a major role. [Spanish] Cualesquiera que sean las verdaderas razones de Estados Unidos para invadir Irak, esta claro que el petroleo tiene un papel muy importante. Una guerra en Medio Oriente que afectara la produccion petrolera de Arabia Saudita elevaria los precios del crudo a niveles nunca vistos, debido al actual descenso de la capacidad de produccion de Venezuela y a la fragilidad politica de Nigeria.

  3. Power from oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Yerushalmi, J.; Wohlfarth, A.; Schwartz, M.; Luria, S.

    1988-02-01

    The possibilities for burning oil shale directly to generate a substantial fraction of Israel's electric power are to be investigated by means of a demonstration plant. The plant incorporates a fluidized bed reactor in which combustion tests have shown Israeli oil-shale will burn with high carbon utilization and without the need for supplementary fuel. Sulphur dioxide emissions are nearly all absorbed by the limestone that makes up about 50% of the shale. The design is for co-generation, supplying low pressure process steam for a chemical plant and electricity to the grid. Economic evaluation suggests that oil shale power generation in Israel could in the future be at least competitive with coal and under some circumstances have a cost advantage.

  4. Wavelets in oil industry

    Science.gov (United States)

    Siddiqi, A. H.

    2012-07-01

    In this chapter, the role of wavelet methods applied to identification and characterization of oil reservoir is elaborated. The market rate of petroleum product is very much related to exploration, drilling and production cost. The main goal of researchers working in oil industry is to develop tools and techniques for minimizing cost of exploration and production. Efforts of researchers working in applications of wavelet methods in different parts of the world to achieve this goal is reviewed. Wavelet based solution of Buckley-Leverett equation modelling reservoir is discussed. Variants of Buckley-Leverett equations including its higher dimension versions are introduced. Wavelet methods for inverse problems associated with Buckley-Leverett equation, which are quite useful for oil recovery, are also explained in this chapter.

  5. Oil problems of Ecuador

    Energy Technology Data Exchange (ETDEWEB)

    Angelier, J.P.

    1982-11-01

    Ecuador used to be referred to as a typical ''banana republic'', but beginning in 1973, it became South America's second biggest oil exporter and during that same year it was admitted into the Organization of Petroleum Exporting Countries. Ecuador then established a nationalistic policy which succeeded in giving it a certain measure of control over its oil industry even if serious problems are still hindering the management of this industry. Today, Ecuador is facing an alternative: either it continues along the road it traced beginning in 1973, or else it takes a road which aims at relatively autonomous development of the national economy, or else it becomes a country which essentially lives from its oil revenues, produced and exploited by others.

  6. Seed storage oil mobilization.

    Science.gov (United States)

    Graham, Ian A

    2008-01-01

    Storage oil mobilization starts with the onset of seed germination. Oil bodies packed with triacylglycerol (TAG) exist in close proximity with glyoxysomes, the single membrane-bound organelles that house most of the biochemical machinery required to convert fatty acids derived from TAG to 4-carbon compounds. The 4-carbon compounds in turn are converted to soluble sugars that are used to fuel seedling growth. Biochemical analysis over the last 50 years has identified the main pathways involved in this process, including beta-oxidation, the glyoxylate cycle, and gluconeogenesis. In the last few years molecular genetic dissection of the overall process in the model oilseed species Arabidopsis has provided new insight into its complexity, particularly with respect to the specific role played by individual enzymatic steps and the subcellular compartmentalization of the glyoxylate cycle. Both abscisic acid (ABA) and sugars inhibit storage oil mobilization and a substantial degree of the control appears to operate at the transcriptional level.

  7. Olive oil for tuna canning

    National Research Council Canada - National Science Library

    Cucurachi, A

    1967-01-01

    The paper presents studies on the phenomenon of contamination of the preserving oil by contact with the tunnyfish, and attempts to discover a method for guaranteeing the genuineness of the olive oil...

  8. Business cycles in oil economies

    Energy Technology Data Exchange (ETDEWEB)

    Al-Mutairi, N.H.

    1991-01-01

    This study examines the impact of oil price shocks on output fluctuations of several oil-exporting economies. In most studies of business cycles, the role of oil price is ignored; the few studies that use oil price as one of the variables in the system focus on modeling oil-importing economies. The vector autoregression (VAR) technique is used to consider the cases of Norway, Nigeria, and Mexico. Both atheoretical and structural' VARs are estimated to determine the importance of oil price impulses on output variations. The study reports two types of results: variance decomposition and impulse response functions, with particular emphasis on the issues of stationarity and co-integration among the series. The empirical results suggest that shocks to oil price are important in explaining output variations. In most cases, shocks to oil price are shown to explain more than 20% of the forecast variance of output over a 40-quarter horizon.

  9. Study of initial stage in coal liquefaction. Increase in oil yield with suppression of retrogressive reaction during initial stage; Ekika hanno no shoki katei ni kansuru kenkyu. 1.

    Energy Technology Data Exchange (ETDEWEB)

    Uesugi, K.; Kanaji, M.; Kaneko, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan)

    1996-10-28

    For the coal liquefaction, improvement of liquefaction conditions and increase of liquefied oil yield are expected by suppressing the recombination through rapid stabilization of pyrolytic radicals which are formed at the initial stage of liquefaction. Two-stage liquefaction combining prethermal treatment and liquefaction was performed under various conditions, to investigate the effects of reaction conditions on the yields and properties of products as well as to increase liquefied oil yield. Consequently, it was found that the catalyst contributes greatly to the hydrogen transfer to coal at the prethermal treatment. High yield of n-hexane soluble fraction with products having low condensation degree could be obtained by combining the prethermal treatment in the presence of hydrogen and catalyst with the concentration of slurry after the treatment. This was considered to be caused by the synergetic effect between the improvement of liquefaction by suppressing polymerization/condensation at the initial stage of reaction through the prethermal treatment and the effective hydrogen transfer accompanied with the improvement of contact efficiency of coal/catalyst by the concentration of slurry at the stage of liquefaction. 4 refs., 8 figs.

  10. Oil Trading Centre to Reopen in Shanghai

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ Chinese oil companies will likely resume activities at the oil trading centre in Shanghai this year, a move to further liberalize the once tightly controlled oil market. The centre will trade forward contracts for refined oil products,including gasoline, diesel oil, kerosene and fuel oil, industrial sources said.

  11. Natural cold pressed oils as cosmetic products

    Directory of Open Access Journals (Sweden)

    Małgorzata Ligęza

    2016-12-01

    Full Text Available Background. It seems that patients may ask general practitioners about natural cosmetics applied on the skin regarding their safety and suitability. Objectives. The aim of the study was to analyze natural cold pressed oils as potential cosmetic products. Material and methods. Cold pressed oils obtained from selected seeds and fruit stones were analyzed, including: chokeberry seed oil, blackcurrant seed oil, elderberry seed oil, raspberry seed oil, apricot seed oil, tomato seed oil, strawberry seed oil, broccoli seed oil, Nigella sativa seed oil, hemp oil, safflower seed oil, Silybum marianum seed oil and coconut oil. 80 adult volunteers assessed the cosmetic properties of the analyzed oils. Each of the volunteers tested 2 to 4 different oils, by applying them on the skin. In addition, patch tests with all analyzed oils were performed on 23 individuals. Results. The majority of tested oils were positively evaluated by the participants: in the opinion of the participants, oil extracted from safflower had the best appearance (100% positive opinions, coconut oil had the best smell (70% positive opinions, while black currant seed oil showed the best absorbency (85% positive opinions. No irritation was observed within the analyzed product group, albeit one allergic reaction to apricot seed oil was observed with patch testing. Conclusions . Based on the achieved results, it could be suggested that natural cold pressed oils can be applied to the skin as cosmetics. Our observations may be helpful for general practitioners when choosing natural cosmetics.

  12. Refrigerating machine oil

    Energy Technology Data Exchange (ETDEWEB)

    Nozawa, K.

    1981-03-17

    Refrigerating machine oil to be filled in a sealed motorcompressor unit constituting a refrigerating cycle system including an electric refrigerator, an electric cold-storage box, a small-scaled electric refrigerating show-case, a small-scaled electric cold-storage show-case and the like, is arranged to have a specifically enhanced property, in which smaller initial driving power consumption of the sealed motor-compressor and easier supply of the predetermined amount of the refrigerating machine oil to the refrigerating system are both guaranteed even in a rather low environmental temperature condition.

  13. Aquathermolysis of heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Hyne, J.B.; Clark, P.D.; Clarke, R.A.; Koo, J.; Greidanus, J.W.

    1982-07-01

    The use of steam injection as a recovery method is based mainly on the physical effect of transferring the energy of the steam to enhance the flow properties of heavy oils. Other physical effects, such as emulsification, also may take place but little attention has been given to the possibility of a chemical reaction between the steam and some of the heavy oil components. This work addresses the question of such a chemical reaction to which the name, Aquathermolysis, has been given. The results of gas analyses to simulate field conditions of steam injection are presented. Two samples were used. Means to enhance the flow properties during the aquathermolysis process also were determined.

  14. Oil Spill Cleanup

    Science.gov (United States)

    1994-01-01

    Petroleum Remediation Product (PRP) is a new way of cleaning up oil spills. It consists of thousands of microcapsules, tiny balls of beeswax with hollow centers, containing live microorganisms and nutrients to sustain them. As oil flows through the microcapsule's shell, it is consumed and digested by the microorganisms. Pressure buildup causes the PRP to explode and the enzymes, carbon dioxide and water are released into the BioBoom used in conjunction with PRP, preventing contaminated water from spreading. The system incorporates technology originally developed at the Jet Propulsion Laboratory and Marshall Space Flight Center.

  15. Suspension of oil supply and import of oil from the overseas oil development program

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Hyung [Korea Energy Economics Institute, Euiwang (Korea)

    1999-03-01

    The import of oil from the overseas oil development is not only reducing the probability and the scale of supply suspension but also enhancing the competitive power of oil industry by securing crude oil stably and economically. Therefore, the import of oil from the overseas oil development is desperately required to meet the opening of domestic oil market. Since the overseas oil development program has started in 1981, the government subsidy from special energy accounting is $0.6 billion occupying 25% of total investment with $2.4 billion. In spite of such a government subsidy, the import amount of development in 1997 is 13.6 million barrel, which is only 1.6% of domestic crude oil consumption. With the goal of supplying 10% of domestically consumed crude oil with self-developed crude oil by 2010, the government is considering a support plan to secure oil for the energy security, because enterprises are lowering its priority of investment on the overseas oil development program as a result of IMF crisis and restructuring. This study estimates the amount of government subsidy through the positive analysis, by selecting an aftermath supporting program as an alternative. (author). 28 refs., 3 figs., 9 tabs.

  16. Global oil palm suitability assessment

    OpenAIRE

    Pirker, J.; Mosnier, A

    2015-01-01

    The palm oil boom of recent years has brought about both positive - economic development - and negative impacts - deforestation, habitat losses and increased GHG emissions - in the main producer countries in South-East Asia. As global demand for palm oil is still increasing, governments of developing and emerging countries increasingly promote oil palm cultivation as a major contributor to economic development, but there are concerns about the potential negative impacts of oil palm expansion ...

  17. Electric Cars and Oil Prices

    OpenAIRE

    Azar, Jose

    2009-01-01

    This paper studies the joint dynamics of oil prices and interest in electric cars, measured as the volume of Google searches for related phrases. Not surprisingly, I find that oil price shocks predict increases in Google searches for electric cars. Much more surprisingly, I also find that an increase in Google searches predicts declines in oil prices. The high level of public interest in electric cars between April and August of 2008 can explain approximately half of the decline in oil prices...

  18. [Antioxidant activity of flaxseed oil].

    Science.gov (United States)

    Prozorovskaia, N N; Rusina, I F; Lupinovich, V L; Beketova, N A; Sorokin, I V; Ipatova, O M; Levachev, M M

    2003-01-01

    Effective concentration of antioxidants and its reactivity toward peroxil radicals (constant k7) have been measured by the chemiluminescence technique for flaxseed oil. Effective concentration of antioxidants is shown to depend on the technology of producing flaxseed oil; period of seed storage before use; and storing duration of flaxseed oil also. Minor component content of flaxseed oil, which may be the members of antioxidant pool, has been quantitatively estimated.

  19. WEO-2006 Fact Sheet: Oil

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    We have revised upwards our assumptions for oil prices in this Outlook, reflecting current market conditions. Globally, fossil fuels will remain the dominant source of energy to 2030 in both scenarios. Rising oil and gas demand and imports, if unchecked, would accentuate the consuming countries' vulnerability to a severe supply disruption and resulting price shock. The growing insensitivity of oil demand to price accentuates the potential impact on international oil prices of such a disruption.

  20. Green bio-oil extraction for oil crops

    Science.gov (United States)

    Zainab, H.; Nurfatirah, N.; Norfaezah, A.; Othman, H.

    2016-06-01

    The move towards a green bio-oil extraction technique is highlighted in this paper. The commonly practised organic solvent oil extraction technique could be replaced with a modified microwave extraction. Jatropha seeds (Jatropha curcas) were used to extract bio-oil. Clean samples were heated in an oven at 110 ° C for 24 hours to remove moisture content and ground to obtain particle size smaller than 500μm. Extraction was carried out at different extraction times 15 min, 30 min, 45 min, 60 min and 120 min to determine oil yield. The biooil yield obtained from microwave assisted extraction system at 90 minutes was 36% while that from soxhlet extraction for 6 hours was 42%. Bio-oil extracted using the microwave assisted extraction (MAE) system could enhance yield of bio-oil compared to soxhlet extraction. The MAE extraction system is rapid using only water as solvent which is a nonhazardous, environment-friendly technique compared to soxhlet extraction (SE) method using hexane as solvent. Thus, this is a green technique of bio-oil extraction using only water as extractant. Bio-oil extraction from the pyrolysis of empty fruit bunch (EFB), a biomass waste from oil palm crop, was enhanced using a biocatalyst derived from seashell waste. Oil yield for non-catalytic extraction was 43.8% while addition of seashell based biocatalyst was 44.6%. Oil yield for non-catalytic extraction was 43.8% while with addition of seashell-based biocatalyst was 44.6%. The pH of bio-oil increased from 3.5 to 4.3. The viscosity of bio-oil obtained by catalytic means increased from 20.5 to 37.8 cP. A rapid and environment friendly extraction technique is preferable to enhance bio-oil yield. The microwave assisted approach is a green, rapid and environmental friendly extraction technique for the production of bio-oil bearing crops.

  1. Oil from algae; salvation from peak oil?

    Science.gov (United States)

    Rhodes, Christopher J

    2009-01-01

    A review is presented of the use of algae principally to produce biodiesel fuel, as a replacement for conventional fuel derived from petroleum. The imperative for such a strategy is that cheap supplies of crude oil will begin to wane within a decade and land-based crops cannot provide more than a small amount of the fuel the world currently uses, even if food production were allowed to be severely compromised. For comparison, if one tonne of biodiesel might be produced say, from rape-seed per hectare, that same area of land might ideally yield 100 tonnes of biodiesel grown from algae. Placed into perspective, the entire world annual petroleum demand which is now provided for by 31 billion barrels of crude oil might instead be met from algae grown on an area equivalent to 4% of that of the United States. As an additional benefit, in contrast to growing crops it is not necessary to use arable land, since pond-systems might be placed anywhere, even in deserts, and since algae grow well on saline water or wastewaters, no additional burden is imposed on freshwater-a significant advantage, as water shortages threaten. Algae offer the further promise that they might provide future food supplies, beyond what can be offered by land-based agriculture to a rising global population.

  2. Methods of analyzing crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Cooks, Robert Graham; Jjunju, Fred Paul Mark; Li, Anyin; Rogan, Iman S.

    2017-08-15

    The invention generally relates to methods of analyzing crude oil. In certain embodiments, methods of the invention involve obtaining a crude oil sample, and subjecting the crude oil sample to mass spectrometry analysis. In certain embodiments, the method is performed without any sample pre-purification steps.

  3. Culture systems: mineral oil overlay.

    Science.gov (United States)

    Morbeck, Dean E; Leonard, Phoebe H

    2012-01-01

    Mineral oil overlay microdrop is commonly used during in vitro fertilization (IVF) procedures. Though mineral oil appears homogeneous, it is an undefined product that can vary in quality. Here, we describe the history, chemistry, processing, and optimal use of mineral oil for IVF and embryo culture.

  4. Towards sustainable oil revenue management

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    Challenges to oil revenue management in existing and emerging African oil economies are examined, with a special emphasis on countries in UNDP's Central and Eastern Africa (CEA) Region. It is part of the first phase of UNDP/CEA's Oil Revenue Initiative (ml)

  5. Oil Futures off the Agenda

    Institute of Scientific and Technical Information of China (English)

    LiuShijun

    2003-01-01

    Speculation that the domestic oil futures exchange would reopen soon was premature, industry sources said. Beijing-based media indicated on March 4 that the resumption of oil futures was imminent, as part of the government's efforts to limit oil price fluctuations over fears of war with Iraq. The source

  6. Ozonated Olive Oils and Troubles

    Directory of Open Access Journals (Sweden)

    Bulent Uysal

    2014-04-01

    Full Text Available One of the commonly used methods for ozone therapy is ozonated oils. Most prominent type of used oils is extra virgin olive oil. But still, each type of unsaturated oils may be used for ozonation. There are a lot of wrong knowledge on the internet about ozonated oils and its use as well. Just like other ozone therapy studies, also the studies about ozone oils are inadequate to avoid incorrect knowledge. Current data about ozone oil and its benefits are produced by supplier who oversees financial interests and make misinformation. Despite the rapidly increasing ozone oil sales through the internet, its quality and efficacy is still controversial. Dozens of companies and web sites may be easily found to buy ozonated oil. But, very few of these products are reliable, and contain sufficiently ozonated oil. This article aimed to introduce the troubles about ozonated oils and so to inform ozonated oil users. [J Intercult Ethnopharmacol 2014; 3(2.000: 49-50

  7. Oil and fat absorbing polymers

    Science.gov (United States)

    Marsh, H. E., Jr. (Inventor)

    1977-01-01

    A method is described for forming a solid network polymer having a minimal amount of crosslinking for use in absorbing fats and oils. The polymer remains solid at a swelling ratio in oil or fat of at least ten and provides an oil absorption greater than 900 weight percent.

  8. The exploitation of volatile oil

    Institute of Scientific and Technical Information of China (English)

    MENG Teng; ZHANG Da; TENG Xiangjin; LINing; HAO Zaibin

    2007-01-01

    Rose is a kind of favorite ornamental plant. This article briefly introduced the cultivation and the use of rose around the world both in ancient time and nowadays. Today, volatile oil becomes the mainstream of the rose industry. People pay attention to the effect of volatile oil; meanwhile, they speed up their research on extracting volatile oil and the ingredients.

  9. OIL OUTLOOK:USGS Optimistic on World Oil Prospects.

    Science.gov (United States)

    Kerr, R A

    2000-07-14

    According to the latest estimates by the U.S. Geological Survey, the world has 20% more oil awaiting discovery in yet-to-be-found fields than the USGS estimated 6 years ago. And a newly analyzed category--oil lurking in and around known fields--offers almost as much additional oil as in those undiscovered reservoirs. But even if the additional oil is really there, pessimists argue that it pushes back the global production peak--and the end of the era of cheap oil--by years, not decades.

  10. HOW PROPERTIES OF EDIBLE OILS ARE IMPROVED BY ESSENTIAL OILS

    Directory of Open Access Journals (Sweden)

    SONIA AMARIEI

    2016-10-01

    Full Text Available The main aim of the present paper is to find out whether the addition of essential oils determines better oxidation stability and positive change of sensory and hedonic perception of edible oils. The oxidation stability of sunflower, corn and grape seed oils was analyzed in the presence of antioxidants in essential oils of rosemary (Rosmarinus officinalis, thyme (Thymus vulgaris and basil (Ocimum basilicum during storage, under conditions of accelerated oxidative processes (4 days, at 60 °C. The total phenolic compounds of these essential oils were determined by the Folin-Ciocalteu method. The DPPH method was used to evaluate the antioxidant capacity of basil, rosemary and thyme essential oils in comparison with known synthetic antioxidant L(+-ascorbic acid. The addition of essential oils to edible oils, the amounts proposed in analyses, determines a favorable influence on their oxidation stability as well as their taste. The influence of addition of essential oils on the taste of edible oils was studied in two products consumed mainly at breakfast, bread and spinach leaves. The results recommend the use of these plant extracts as additives in edible oils rather than synthetic antioxidants.

  11. A Comparative Study of Diesel Oil and Soybean Oil as Oil-Based Drilling Mud

    OpenAIRE

    Okorie E. Agwu; Okon, Anietie N.; Udoh, Francis D.

    2015-01-01

    Oil-based mud (OBM) was formulated with soybean oil extracted from soybean using the Soxhlet extraction method. The formulated soybean mud properties were compared with diesel oil mud properties. The compared properties were rheological properties, yield point and gel strength, and mud density and filtration loss properties, fluid loss and filter cake. The results obtained show that the soybean oil mud exhibited Bingham plastic rheological model with applicable (low) yield point and gel stren...

  12. Contact Angle Hysteresis on Graphene Surfaces and Hysteresis-free Behavior on Oil-infused Graphite Surfaces

    Science.gov (United States)

    Wu, Cyuan-Jhang; Li, Yueh-Feng; Woon, Wei-Yen; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2016-11-01

    Contact angle hysteresis (CAH) on graphitic surfaces, including chemical vapor deposition (CVD) graphene, reduced electrophoretic deposition (EPD) graphene, highly oriented pyrolytic graphite (HOPG), and polished graphite sheet, has been investigated. The hysteresis loops of water drops on the first three samples are similar but the receding contact angle is particularly small for the polished graphite sheet.The significant CAH observed on CVD graphene and HOPG associated with atom-scale roughness has to be attributed mainly to adhesion hysteresis (surface relaxation), instead of roughness or defects.The difference of the wetting behavior among those four graphitic samples has been further demonstrated by hexadecane drops. On the surface of HOPG or CVD graphene,the contact line expands continuously with time, indicating total wetting for which the contact angle does not exist and contact line pinning disappears. In contrast, on the surface of reduced EPD graphene, spontaneous spreading is halted by spikes on it and partial wetting with small contact angle (θ≈4°) is obtained. On the surface of polished graphite sheet, the superlipophilicity and porous structure are demonstrated by imbibition and capillary rise of hexadecane. Consequently, an oil-infused graphite surface can be fabricated and the ultralow CAH of water (∆θ≈2°) is achieved.

  13. Pyrogenic transformation of Nannochloropsis oceanica into fatty acid methyl esters without oil extraction for estimating total lipid content.

    Science.gov (United States)

    Kim, Jieun; Jung, Jong-Min; Lee, Jechan; Kim, Ki-Hyun; Choi, Tae O; Kim, Jae-Kon; Jeon, Young Jae; Kwon, Eilhann E

    2016-07-01

    This study fundamentally investigated the pseudo-catalytic transesterification of dried Nannochloropsis oceanica into fatty acid methyl esters (FAMEs) without oil extraction, which was achieved in less than 5min via a thermo-chemical pathway. This study presented that the pseudo-catalytic transesterification reaction was achieved in the presence of silica and that its main driving force was identified as temperature: pores in silica provided the numerous reaction space like a micro-reactor, where the heterogeneous reaction was developed. The introduced FAME derivatization showed an extraordinarily high tolerance of impurities (i.e., pyrolytic products and various extractives). This study also explored the thermal cracking of FAMEs derived from N. oceanica: the thermal cracking of saturated FAMEs was invulnerable at temperatures lower than 400°C. Lastly, this study reported that N. oceanica contained 14.4wt.% of dried N. oceanica and that the introduced methylation technique could be applicable to many research fields sharing the transesterification platform. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. 3-dimensional Oil Drift Simulations

    Science.gov (United States)

    Wettre, C.; Reistad, M.; Hjøllo, B.Å.

    Simulation of oil drift has been an ongoing activity at the Norwegian Meteorological Institute since the 1970's. The Marine Forecasting Centre provides a 24-hour service for the Norwegian Pollution Control Authority and the oil companies operating in the Norwegian sector. The response time is 30 minutes. From 2002 the service is extended to simulation of oil drift from oil spills in deep water, using the DeepBlow model developed by SINTEF Applied Chemistry. The oil drift model can be applied both for instantaneous and continuous releases. The changes in the mass of oil and emulsion as a result of evaporation and emulsion are computed. For oil spill at deep water, hydrate formation and gas dissolution are taken into account. The properties of the oil depend on the oil type, and in the present version 64 different types of oil can be simulated. For accurate oil drift simulations it is important to have the best possible data on the atmospheric and oceanic conditions. The oil drift simulations at the Norwegian Meteorological Institute are always based on the most updated data from numerical models of the atmosphere and the ocean. The drift of the surface oil is computed from the vectorial sum of the surface current from the ocean model and the wave induced Stokes drift computed from wave energy spectra from the wave prediction model. In the new model the current distribution with depth is taken into account when calculating the drift of the dispersed oil droplets. Salinity and temperature profiles from the ocean model are needed in the DeepBlow model. The result of the oil drift simulations can be plotted on sea charts used for navigation, either as trajectory plots or particle plots showing the situation at a given time. The results can also be sent as data files to be included in the user's own GIS system.

  15. Between Oil and Reindeer

    NARCIS (Netherlands)

    Tulaeva, S.; Tysyachnyouk, M.

    2017-01-01

    This research provides insight into various modes of benefit-sharing agreements between oil and gas companies and indigenous people in the Russian Arctic and Subarctic regions. We indicate three main modes of benefit sharing, as follows: (1) paternalism, (2) corporate social responsibility, and (3)

  16. Helicopter Transmission Oil Discolouration

    Science.gov (United States)

    2012-02-01

    passivator, some times also called a metal inhibitor or deactivator. Alloys that contain copper can catalyse reactions that can cause oxidative...If catalytically active metals, especially copper, are not ‘passivated’ they will catalyse oxidative degradation reactions in the oil thus

  17. Mineral oil; Mineraloel

    Energy Technology Data Exchange (ETDEWEB)

    Schult-Bornemann, Karl-Heinz [Magdeburg Univ. (Germany)

    2015-07-01

    The dominant theme in the world energy market was the fall in oil prices in 2014. From 115 US-$/bbl in June it dropped to below 50 US-$/bbl in January 2015. Thereby the shale oil revolution has had the strong impact on the global energy situation, to this point has been predicted for three years. Although no one could predict the exact height of the fall in oil prices, but with oil as a reserve currency for all other fuels, it has not only had an impact on the gas and coal prices, but other commodities, such as copper, have also yielded. About cause and effect, there is a lot of speculation - not all of which are supported by wisdom. [German] Das beherrschende Thema im Weltenergiemarkt war der Absturz des Rohoelpreises in 2014. Von 115 US-$/bbl im Juni sank er auf unter 50 US-$/bbl im Januar 2015. Damit hat die Schieferoelrevolution den kraeftigen Einfluss auf die Weltenergiesituation gehabt, der an dieser Stelle seit drei Jahren vorhergesagt wurde. Zwar konnte niemand die exakte Hoehe des Rueckgangs des Oelpreises prognostizieren, aber mit Oel als Leitwaehrung fuer alle anderen Energietraeger hat es nicht nur Einfluss auf den Gas- und Kohlepreis gehabt, sondern andere Rohstoffe, wie zum Beispiel Kupfer, haben ebenfalls nachgegeben. Ueber Ursache und Wirkung gibt es viele Spekulationen - nicht alle sind von Weisheit getragen.

  18. Windfall Tax on Oil

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    China has adopted a special income tax on oil companies, to restrict excessive monopoly profits and subsidize weak sectors O n April 4, the China Petroleum & Chemical Corp., known as Sinopec, together with its holding subsidiaries Sinopec Shengli Oilfield Daming Co. Ltd. and

  19. Kicking the oil addiction

    Science.gov (United States)

    Vilenchik, Yaakov; Peled, Emanuel; Andelman, David

    2010-01-01

    Few people were left unaffected by the soaring oil prices of summer 2008. Motorists were the hardest hit as the price at the pumps reached an all time high, but nobody could avoid paying more for their food as higher transport costs were passed on from the retailer to the consumer.

  20. Striking Oil: Another Puzzle

    NARCIS (Netherlands)

    G. Driesprong (Gerben); B. Jacobsen (Ben); B. Maat (Benjamin)

    2003-01-01

    textabstractWe find that changes in oil prices strongly predict future stock market returns in many countries in the world. In our thirty year sample of monthly data for developed stock markets, we find statistically significant predictability in 12 out of the 18 countries and in a world market inde

  1. Another Oil Disaster

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Cleanup work is underway after oil gushes into the seaoff Dalian’s coast in northeast China More than 800 fishing boats in Dalian,a coastal city in northeast China’s Liaoning Province,joined the effort on July 20 to clean up

  2. Oil shortage policy; Olieschaarstebeleid

    Energy Technology Data Exchange (ETDEWEB)

    Koppelaar, R.; Van Meerkerk, B.; Polder, P.; Van den Bulk, J.; Kamphorst, F.

    2008-10-15

    This policy proposal addresses the deployment of options for decreasing Dutch dependency on oil by means of firm government policy. [Dutch] Dit beleidsvoorstel richt zich op het benutten van de mogelijkheden voor Nederland om via een sterke overheidsaanpak de afhankelijkheid van olie te verminderen.

  3. Scramble for Oil Power

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Geopolitical as well as economic concerns underlie the worldwide rush to establish petroleum exchanges New oil exchange programs have recently been mushrooming around the world. The Shanghai Petroleum Exchange, which uses renminbi in its transactions, kicked off operations on August 18. In May, Iran

  4. Virgin coconut oil improves hepatic lipid metabolism in rats--compared with copra oil, olive oil and sunflower oil.

    Science.gov (United States)

    Arunima, S; Rajamohan, T

    2012-11-01

    Effect of virgin coconut oil (VCO) on lipid levels and regulation of lipid metabolism compared with copra oil (CO), olive oil (OO), and sunflower oil (SFO) has been reported. Male Sprague-Dawley rats were fed different oils at 8% level for 45 days along with synthetic diet. Results showed that VCO feeding significantly lowered (P VCO than other groups. Hepatic lipogenesis was also down regulated in VCO fed rats, which was evident from the decreased activities of enzymes viz., HMG CoA reductase, glucose-6-phosphate dehydrogenase, isocitrate dehydrogenase and malic enzyme. In addition, VCO significantly (P VCO by regulating the synthesis and degradation of lipids.

  5. Effect of mineral oil, sunflower oil, and coconut oil on prevention of hair damage.

    Science.gov (United States)

    Rele, Aarti S; Mohile, R B

    2003-01-01

    Previously published results showed that both in vitro and in vivo coconut oil (CNO) treatments prevented combing damage of various hair types. Using the same methodology, an attempt was made to study the properties of mineral oil and sunflower oil on hair. Mineral oil (MO) was selected because it is extensively used in hair oil formulations in India, because it is non-greasy in nature, and because it is cheaper than vegetable oils like coconut and sunflower oils. The study was extended to sunflower oil (SFO) because it is the second most utilized base oil in the hair oil industry on account of its non-freezing property and its odorlessness at ambient temperature. As the aim was to cover different treatments, and the effect of these treatments on various hair types using the above oils, the number of experiments to be conducted was a very high number and a technique termed as the Taguchi Design of Experimentation was used. The findings clearly indicate the strong impact that coconut oil application has to hair as compared to application of both sunflower and mineral oils. Among three oils, coconut oil was the only oil found to reduce the protein loss remarkably for both undamaged and damaged hair when used as a pre-wash and post-wash grooming product. Both sunflower and mineral oils do not help at all in reducing the protein loss from hair. This difference in results could arise from the composition of each of these oils. Coconut oil, being a triglyceride of lauric acid (principal fatty acid), has a high affinity for hair proteins and, because of its low molecular weight and straight linear chain, is able to penetrate inside the hair shaft. Mineral oil, being a hydrocarbon, has no affinity for proteins and therefore is not able to penetrate and yield better results. In the case of sunflower oil, although it is a triglyceride of linoleic acid, because of its bulky structure due to the presence of double bonds, it does not penetrate the fiber, consequently resulting

  6. Antigenotoxicity of Dietary Coconut Oil

    Directory of Open Access Journals (Sweden)

    Clara Lim-Sylianco

    1992-06-01

    Full Text Available Benzo(apyrene, dimethylnitrosamine, methylmethanesulfonate and tetracycline induced formation of micronucleated polychromatic erythrocytes indicating that these substances are genotoxic to bone marrow cells of the experimental mice.Genotoxicity of these substances to germ cells was also observed when low fertility index and high percentage dead implants were induced in experimental mice.When each genotoxin was administered to mice fed with diets containing 18 % coconut oil for 23 days, the formation of micronucleated polychromatic erythrocytes was greatly reduced. Antigenotoxic activity of dietary coconut oil was very much greater than dietary soybean oil.Germ cell genotoxicity of each genotoxin was also reduced when male mice fed the 18 % coconut oil diet were used. When male mice treated with the genotoxin was mated with virgin females, fertility index was increased in the group fed with coconut oil diet. Percentage dead implants was reduced. The antigenotoxic activity of dietary coconut oil on germ cells far exceeds that of dietary soybean oil.Dietary restriction of coconut oil diets enhanced the antigenotoxic activity of coconut oil in bone marrow cells and germs cells.Among the triacylglycerols of coconut oil, trilaurin gave the best antigenotoxic activity in bone marrow cells. Trilaurin is the major triacylglycerol in coconut oil.

  7. Thermal Pyrolytic Graphite Enhanced Components Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Peregrines innovation will reduce the required input power, increase a coolers systems margin for a giving cooling load and reduce vibration accordingly for...

  8. Pyrolytic 3D Carbon Microelectrodes for Electrochemistry

    DEFF Research Database (Denmark)

    Hemanth, Suhith; Caviglia, Claudia; Amato, Letizia

    2016-01-01

    electrochemical activity, chemical stability, and ease in surface functionalization [1]. The most common carbon microfabrication techniques (i.e. screen printing) produce two-dimensional (2D) electrodes, which limit the detection sensitivity. Hence several 3D microfabrication techniques have been explored......This work presents the fabrication and characterization of multi-layered three-dimensional (3D) pyrolysed carbon microelectrodes for electrochemical applications. For this purpose, an optimized UV photolithography and pyrolysis process with the negative tone photoresist SU-8 has been developed...... carbon [2]. This process enables fabrication of 2D and 3D electrodes with possibility for tailoring ad-hoc designs and unique sensitivities for specific applications. Due to this, pyrolysed carbon is becoming increasingly attractive for numerous applications, such as novel sensors and scaffolds for cell...

  9. Thermal Pyrolytic Graphite Enhanced Components Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Peregrine's innovation will reduce the required input power, increase a coolers systems margin for a giving cooling load and reduce vibration accordingly for...

  10. Pyrolytic 3D Carbon Microelectrodes for Electrochemistry

    DEFF Research Database (Denmark)

    Hemanth, Suhith; Caviglia, Claudia; Amato, Letizia

    2016-01-01

    ,” Chem. Rev., vol. 108, no. 7, pp. 2646–2687, 2008. [2] R. Martinez-Duarte, “SU-8 Photolithography as a Toolbox for Carbon MEMS,” Micromachines, vol. 5, no. 3, pp. 766–782, 2014. [3] L. Amato, A. Heiskanen, C. Caviglia, F. Shah, K. Zéór, M. Skolimowski, M. Madou, L. Gammelgaard, R. Hansen, E. G. Seiz...

  11. Are olive oil diets antithrombotic?

    DEFF Research Database (Denmark)

    Larsen, L.F.; Jespersen, J; Marckmann, P.

    1999-01-01

    BACKGROUND: The incidence of ischemic heart disease (IHD) in Crete was lower than expected on the basis of blood lipid concentrations of participants in the Seven Countries Study. A favorable effect of a high intake of olive oil on thrombogenesis may have contributed to this finding. OBJECTIVE: We...... compared the effects of virgin olive oil with those of rapeseed and sunflower oils on blood coagulation factor VII (FVII), a key factor in thrombogenesis. DESIGN: In a randomized and strictly controlled crossover study, 18 healthy young men consumed diets enriched with 5 g/MJ (19% of total energy) olive...... FVII (FVIIa) were 11.3 +/- 5.1 U/L lower after olive oil than after sunflower oil, an 18% reduction (P Olive oil also tended to cause lower FVIIa peak concentrations than did rapeseed oil (mean difference: 8.6 U/L, a 15% reduction; P = 0.09). There were no significant differences between diets...

  12. Aerobic microbial enhanced oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Torsvik, T. [Univ. of Bergen (Norway); Gilje, E.; Sunde, E.

    1995-12-31

    In aerobic MEOR, the ability of oil-degrading bacteria to mobilize oil is used to increase oil recovery. In this process, oxygen and mineral nutrients are injected into the oil reservoir in order to stimulate growth of aerobic oil-degrading bacteria in the reservoir. Experiments carried out in a model sandstone with stock tank oil and bacteria isolated from offshore wells showed that residual oil saturation was lowered from 27% to 3%. The process was time dependent, not pore volume dependent. During MEOR flooding, the relative permeability of water was lowered. Oxygen and active bacteria were needed for the process to take place. Maximum efficiency was reached at low oxygen concentrations, approximately 1 mg O{sub 2}/liter.

  13. Oil Prices Take a Hike

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The National Development and Reform Commission(NDRC),China’s top economic planner,announced at the end of October that the benchmark prices of gasoline,diesel oil and aviation kerosene would be raised by 500 yuan per ton. Recently,international oil prices have been rising continuously.Crude oil futures prices traded in New York surged to$93 per barrel on October 29. However,in China,oil prices are set by the government and not by the market. The recent hike on the price of oil in China is a measure implemented,to narrow the gap between soaring global crude oil prices and domestic fuel prices.NDRC officials answered questions posed by Xinhua News Agency about recent oil price hikes.The questions and answers follow:

  14. The Future of Oil Industry

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Oil and gas are the major energy resources all over the world but are not renewable. According to their present reserves, the resource volumes yet to be found and the large amount of non-conventional oil and gas resources, there is still great potential in oil and gas production. The proportion ofoil and gas in energy structure will be influenced by four major factors: 1) Potential of the world oil and gas resources; 2) Technological progress of oil and gas exploration and development; 3) Speed of the development of substitute energy resources; and 4) Variation of oil price. It is estimated that, oil and gas will still retain an important proportion in energy structure by the first half of the 21st century.

  15. Heavy oil markets and investments

    Energy Technology Data Exchange (ETDEWEB)

    Forrest, Jackie [CERA North America (United States)

    2011-07-01

    With the depletion of traditional energy resources and the rising demand for energy, the exploitation of heavy oil resources is increasing. The aim of this paper is to present the heavy oil sector and to show which are the factors influencing heavy oil growth and production. A large part of heavy oil reserves lies in the Americas, with about 45% of the world's reserves in Latin America and over 35% in North America. The development of the heavy oil sector is dependent on economic, technological and environmental factors; greenhouse gas policies have important impacts on the development of the heavy oil industry as well as downstream market access. This presentation highlighted the great potential that North and South America have in terms of heavy oil but that the development of this sector will depend on several factors.

  16. China's Oil Imports and Exports in 2009

    Institute of Scientific and Technical Information of China (English)

    Tian Chunrong

    2010-01-01

    @@ The so-called imported oil dependence degree commonly refers to the proportion of oil imported to China's oil consumption,which hit 56% in 2009 and has exceeded 50% in 2007.In the past two years,the net imports of oil,including crude oil,refined oil,LPG and other oil products,increased by 8.8% and rose to218.38 million tons.

  17. Preparation of Renewable Fuel from Saponificated China Tallow Oil by Fast Pyrolysis Reaction Assisted with Microwave%乌桕油皂微波催化快速裂解制备可再生燃油研究

    Institute of Scientific and Technical Information of China (English)

    王允圃; 程方园; 刘玉环; 阮榕生; 刘英语; 马雯; 杨倩; 黄伊宁

    2015-01-01

    Preparation of renewable fuel was studied with saponificated China tallow seed oil and stillingia oil as raw materials using microwave pyrolysis. The effects of reaction power and temperature on the yield of pyrolysis products were investigated. The optimum conditions were obtained as pyrolysis power 700 W, pyrolysis temperature 450 ℃. The corresponding liquid yields were 75. 26% and 77. 01% for microwave pyrolysis oil from saponificated China tallow seed oil and stillingia oil, respectively. The GC-MS analysis indicated that the main components of the product were C8-C18 alkanes, alkenes, ring-containing alkanes and aromatic hydrocarbon. Pyrolysis oil properties were also determined. The results indicated that the pyrolysis oil from saponificated China tallow seed oil had higher heat value, lower density and viscosity with the comparation of pyrolysis oil from saponificated China tallow stillingia oil, which was similar to 0# diesel. Freezing point and cold filter plugging point of the pyrolytic products have good low temperature fluidity, which are better than those of the biodiesel.%采用微波催化快速裂解技术,以乌桕木油皂和乌桕梓油皂为原料,利用其强极性羧基端吸收微波迅速的特点,研究了其制备可再生燃油的技术。考察了裂解功率、裂解温度对裂解产物得率的影响。结果表明:裂解功率700 W,裂解温度450℃,乌桕木油皂和乌桕梓油皂微波裂解液体燃料的得率分别为75.26%和77.01%, GC-MS分析表明,产物的主要成分为C8~C18的正构烷烃、烯烃、环烷烃以及芳香烃等烃类化合物。产物的部分燃料油性能测定结果表明,乌桕木油皂裂解燃油比乌桕梓油皂裂解燃油热值略高,密度和运动黏度略低,基本符合0#柴油的标准,冷凝点和冷滤点均优于生物柴油,低温流动性好。

  18. Effects of oil and oil burn residues on seabird feathers

    DEFF Research Database (Denmark)

    Fritt-Rasmussen, Janne; Linnebjerg, Jannie Fries; Sørensen, Martin X.

    2016-01-01

    It is well known, that in case of oil spill, seabirds are among the groups of animals most vulnerable. Even small amounts of oil can have lethal effects by destroying the waterproofing of their plumage, leading to loss of insulation and buoyancy. In the Arctic these impacts are intensified....... To protect seabirds, a rapid removal of oil is crucial and in situ burning could be an efficient method. In the present work exposure effects of oil and burn residue in different doses was studied on seabird feathers from legally hunted Common eider (Somateria mollissima) by examining changes in total weight...... of the feather and damages on the microstructure (Amalgamation Index) of the feathers before and after exposure. The results of the experiments indicate that burn residues from in situ burning of an oil spill have similar or larger fouling and damaging effects on seabird feathers, as compared to fresh oil....

  19. Effects of oil and oil burn residues on seabird feathers.

    Science.gov (United States)

    Fritt-Rasmussen, Janne; Linnebjerg, Jannie Fries; Sørensen, Martin X; Brogaard, Nicholas L; Rigét, Frank F; Kristensen, Paneeraq; Jomaas, Grunde; Boertmann, David M; Wegeberg, Susse; Gustavson, Kim

    2016-08-15

    It is well known, that in case of oil spill, seabirds are among the groups of animals most vulnerable. Even small amounts of oil can have lethal effects by destroying the waterproofing of their plumage, leading to loss of insulation and buoyancy. In the Arctic these impacts are intensified. To protect seabirds, a rapid removal of oil is crucial and in situ burning could be an efficient method. In the present work exposure effects of oil and burn residue in different doses was studied on seabird feathers from legally hunted Common eider (Somateria mollissima) by examining changes in total weight of the feather and damages on the microstructure (Amalgamation Index) of the feathers before and after exposure. The results of the experiments indicate that burn residues from in situ burning of an oil spill have similar or larger fouling and damaging effects on seabird feathers, as compared to fresh oil.

  20. Crude oil burning mechanisms

    DEFF Research Database (Denmark)

    van Gelderen, Laurens; Malmquist, L.M.V.; Jomaas, Grunde

    2015-01-01

    In order to improve predictions for the burning efficiency and the residue composition of in-situ burning of crude oil, the burning mechanism of crude oil was studied in relation to the composition of its hydrocarbon mixture, before, during and after the burning. The surface temperature, flame...... to the predictions of four conceptual models that describe the burning mechanism of multicomponent fuels. Based on the comparisons, hydrocarbon liquids were found to be best described by the Equilibrium Flash Vaporization model, showing a constant gas composition and gasification rate. The multicomponent fuels...... followed the diffusion-limited gasification model, showing a change in the hydrocarbon composition of the fuel and its evaporating gases, as well as a decreasing gasification rate, as the burning progressed. This burning mechanism implies that the residue composition and burning efficiency mainly depend...

  1. Emulsified industrial oils recycling

    Energy Technology Data Exchange (ETDEWEB)

    Gabris, T.

    1982-04-01

    The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

  2. Is it all oil?

    OpenAIRE

    2005-01-01

    After opening up of the Interconnector, the liberalized UK natural gas market and the regulated Continental gas markets became physically integrated. The oil-linked Continental gas price became dominant, due to both the large volume of the Continental market and to the fact that the significant call options embedded in the complex take-or-pay contracts make these contracts the marginal source of supply. However, in an interim period – after deregulation of the UK gas market (1995) and the ope...

  3. Is It All Oil?

    OpenAIRE

    2005-01-01

    After opening up of the Interconnector, the liberalized UK natural gas market and the regulated Continental gas markets became physically integrated. The oil-linked Continental gas price became dominant, due to both the large volume of the Continental market and to the fact that the significant call options embedded in the complex take-or-pay contracts make these contracts the marginal source of supply. However, in an interim period – after deregulation of the UK gas market (1995) and the ope...

  4. Physicochemical methods for enhancing oil recovery from oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Altunina, L K; Kuvshinov, V A [Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences, Tomsk (Russian Federation)

    2007-10-31

    Physicochemical methods for enhancing oil recovery from oil fields that are developed using water flooding and thermal steam treatment are considered. The results of pilot testing of processes based on these methods carried out at West Siberian and Chinese oil fields are analysed. The attention is focused on the processes that make use of surfactant blends and alkaline buffer solutions and thermotropic gel-forming systems.

  5. Physicochemical methods for enhancing oil recovery from oil fields

    Science.gov (United States)

    Altunina, L. K.; Kuvshinov, V. A.

    2007-10-01

    Physicochemical methods for enhancing oil recovery from oil fields that are developed using water flooding and thermal steam treatment are considered. The results of pilot testing of processes based on these methods carried out at West Siberian and Chinese oil fields are analysed. The attention is focused on the processes that make use of surfactant blends and alkaline buffer solutions and thermotropic gel-forming systems.

  6. Enzymatic Aqueous Extraction of Soybean Oil

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The procedure of enzymatic aqueous extraction of soybean oil was assessed when two-step controlled enzymatic hydrolysis was applied. With aqueous extraction of soybean oil-containing protein, the highest yield of oil was 96.1% at the optimized conditions studied. Soybean oil-containing protein was hydrolyzed and resulted in releasing part of oil. The separated protein that contained 40% oil was enriched due to its adsorption capacity of released oil, the average oil extraction yeild reached 93.5%. Then the high oil content protein was hydrolyzed again to release oil by enzyme, the oil extraction yeild was 80.4%. As a result, high quality of soybean oil was obtained and the content of total oil yield was 74.4%.

  7. Detection of Chemlali extra-virgin olive oil adulteration mixed with soybean oil, corn oil, and sunflower oil by using GC and HPLC.

    Science.gov (United States)

    Jabeur, Hazem; Zribi, Akram; Makni, Jamel; Rebai, Ahmed; Abdelhedi, Ridha; Bouaziz, Mohamed

    2014-05-28

    Fatty acid composition as an indicator of purity suggests that linolenic acid content could be used as a parameter for the detection of extra/virgin olive oil fraud with 5% of soybean oil. The adulteration could also be detected by the increase of the trans-fatty acid contents with 3% of soybean oil, 2% of corn oil, and 4% of sunflower oil. The use of the ΔECN42 proved to be effective in Chemlali extra-virgin olive oil adulteration even at low levels: 1% of sunflower oil, 3% of soybean oil, and 3% of corn oil. The sterol profile is almost decisive in clarifying the adulteration of olive oils with other cheaper ones: 1% of sunflower oil could be detected by the increase of Δ7-stigmastenol and 4% of corn oil by the increase of campesterol. Linear discriminant analysis could represent a powerful tool for faster and cheaper evaluation of extra-virgin olive oil adulteration.

  8. Colombian fusel oil

    Directory of Open Access Journals (Sweden)

    Natalia Montoya

    2016-08-01

    Full Text Available By-products valorization in bio-fuels industry is an important issue for making the global process more efficient, more profitable and closer to the concept of biorefinery. Fusel oil is a by-product of bioethanol production that can be considered as an inexpensive and renewable raw material for manufacturing value-added products. In this work, results in terms of composition and physicochemical properties of six samples of fusel oil from industrial alcohol facilities are presented. Composition of the main components was established by gas chromatography. Complementary techniques, such as headspace solid-phase microextraction and gas chromatography–mass spectrometry (GC-MS, were used for detection of minor components. Fifty-five compounds were identified. Physicochemical properties such as density, acid value, moisture content and true boiling point curves were determined. Results are useful in the conceptual design of separation strategies for recovering higher alcohols, as well as to consider new options of valorization alternatives for fusel oil.

  9. China's Two Oil Giants Halt Oil Products Exports

    Institute of Scientific and Technical Information of China (English)

    Yin Xian

    2008-01-01

    @@ CNPC, China's largest oil producer, and Sinopec, the nation's largest refiner expressed they would increase their oil processing and halt oil products exports in the third quarter to ensure domestic supply. Vice president of CNPC Wang Yilin said on June 2 that CNPC would stop oil products export and increase the imports to secure the domestic market supplies. Meanwhile, Sinopec President Wang Tianpu also said that Sinopec would raise production, halt exports and adjust product structure to ensure domestic supply, especially for the reconstruction after the earthquake, the summer harvest and the Olympic Games.

  10. RHEOLOGICAL PROPERTIES OF RAPESEED OIL AND HYDRAULIC OIL

    Directory of Open Access Journals (Sweden)

    IOANA STANCIU

    2012-06-01

    Full Text Available This article presents the rheological behavior of refined rapeseed oil and hydraulic oil. Apparent viscosity of both oils was determined at temperatures between 40 and 90°C and shear rates ranging from 3.3 to 120 s-1. The aim of the study was to find a polynomial dependence of oil viscosity on temperature and shear rate. The modified Andrade equation was used. Constants A, B, C and correlation coefficient were determined by correlating a characteristic polynomial equation of each curve.

  11. Direct Electron Transfer of Catalase at a Pyrolytic Graphite Electrode Modified with DNA%过氧化氢酶在DNA修饰的热解石墨电极上的直接电子转移

    Institute of Scientific and Technical Information of China (English)

    荣志江; 田燕妮

    2005-01-01

    The direct voltammetry and electrocatalytic properties of catalase (Cat) in single-stranded or doublestranded (ss-or ds-) calf thymus DNA films cast on pyrolytic graphite (PG) electrodes were investigated. CatDNA film electrodes showed a pair of well-defined and nearly reversible cyclic voltammetry peaks. The formal -0. 209 V with dsDNA and -0. 223 V with ssDNA, respectively. The electron transfer between catalase and PG electrodes was greatly facilitated in the DNA films. At a dsDNA/PG electrode,reduction and oxidation electrontransfer rate constant values of ks, red= 13.5 s-1 and ks ,ox= 13.3 s-1 were obtained. At the ssDNA/PG electrode,the values were ks, red = 21. 0 s-1 and ks, ox = 33. 0 s 1, respectively. UV-Vis absorption spectroscopy demonstrated that catalase retained a near native conformation in DNA films at medium pH. We further investigated the responding with pH,Scanrate and H2O2. Obtaining a series valued information.%通过将单、双螺旋的小牛胸腺DNA膜修饰在热解石墨电极上,研究了过氧化氢酶的直接伏安和电催化性质.结果表明过氧化氢酶(Cat)-DNA膜上显示出一对很好的几乎可逆的循环伏安峰,在50 mmol·L,pH为7.0磷酸缓冲溶液中,扫描速度为0.1 V·s-1情况下,单、双螺旋DNA膜上,其式电位分别为-0.223 V和-0.209V,其还原和氧化电子传递速率常数值分别为ks,red=21.0 s-1;ks,ox=33.0 s-1和ks,Red=13.5 s-1;ks,ox=13.3 s-1.在pH为3.81~7.72的范围内,Fe(Ⅲ)/Fe(Ⅱ)电对的还原电位随pH呈线性变化,表明一电子的转移伴有一质子的耦合.另外从紫外可见吸收光谱可见,在中性pH条件下,过氧化氢酶在DNA膜中保持了原有的结构不变.此外,我们还研究得到在DNA膜中过氧化氢酶保持了对过氧化氢的催化活性,并提出了可能的催化机制.

  12. Microstructure of a pyrolytic carbon coating on a nuclear graphite substrate IG-110%沉积在核石墨IG-110基体上的热解炭涂层微观结构

    Institute of Scientific and Technical Information of China (English)

    冯尚蕾; 杨迎国; 白朔; 许力; 杨新梅; 夏汇浩; 周兴泰

    2015-01-01

    采用化学气相沉积技术,以甲烷作为碳源,在核石墨IG-110基体上制备层状热解炭涂层。利用偏光显微镜、扫描电子显微镜( SEM)、透射电子显微镜( TEM)以及同步辐射掠入射X 射线衍射( GI-XRD)研究热解炭涂层的微观结构和生长特性。结果表明,热解炭涂层具有大锥体、小锥体和再生锥体三种生长锥微观结构,热解炭片层间结合紧密,生长锥间结合密实。热解炭涂层存在光滑层和再生层两种织构,每种织构都含有两种晶面间距不同的相结构,平滑层主要含有低石墨化度相,而再生层主要含有高石墨化度相。热解炭涂层致密的微观结构和仅存在的纳米级别的微孔使其可以作为气体阻隔涂层。%The molten salt reactor ( MSR) is one of the six Generation IV reactors that is being reexamined today, owing to its unique fuel cycle capabilities and safety characteristics. IG-110 nuclear graphite a candidate material for constructing a MSR. However, the existence of large pores at its surface is a big problem due to the impregnation of molten salts and the diffusion of fission product gases into the graphite through the pores. A pyrolytic carbon ( PyC) coating can act as a barrier coating on the nuclear graphite. Investigation of the microstructure and growth characteristics of PyC is very important for an understanding of the relationship between microstructure and performance. In this study, polarized light microscopy, scanning electron microscopy, transmission electron microscopy and synchrotron based grazing incidence X-ray diffraction were used to study the microstructure and growth characteristics of the PyC coating. Results show that the PyC coating shows three growth cones ( a large cone, a smaller one and a regenerative cone) and exhibits a wave-like layered structure. The resulting structure is fairly dense. There are two kinds of textures in the PyC coating:smooth laminar and regenerative

  13. Research on Pyrolytic Decomposition and Pattern Evolution of the Pyrolysate of Ammoniam Paramolybdate%仲钼酸铵热分解过程及其形貌演变的研究

    Institute of Scientific and Technical Information of China (English)

    傅小明; 刘照文

    2011-01-01

    通过TG-DSC和SEM对仲钼酸铵在空气中热分解过程进行分析,结果表明:仲钼酸铵在空气中的热分解过程经历了3个阶段:室温至222.6℃之间仲钼酸铵失去结晶水;从222.6~240.7℃之间仲钼酸铵热分解了部分氨根离子;从240.7~248.7℃之间氨根离子完全分解,同时有亚稳态的氧化钼生成.从248.7~322.5℃之间亚稳态的氧化钼发生相变生成了稳态的三氧化钼.与此同时,仲钼酸铵在热分解温度300℃以下时,其热分解产物的形貌几乎没有太大的变化;在300℃以上时,其热分解产物的形貌由原来不规则的块体向不规则的片状转变,最后转变为了较规则的片状三氧化钼.这主要是由于随着热分解温度的进一步升高,热分解产物之间的相互作用、迁移和重组加剧,以及在高温下三氧化钼的挥发与沉积所致.%The pyrolysates of ammonium paramolybdate were investigated by TG-DSC and SEM. The results showed that there were three stages in the process of the pyrolytic decomposition of ammonium paramolybdate in the air. Firstly, crystal water in ammonium paramolybdate was lost from room temperature to 222. 6℃. Secondly, partial ammonia ion in ammonium paramolybdate was decomposed from 222. 6 to 240. 7 ℃. Thirdly, the residual ammonia ion was decomposed entirely and metastable molybdenum oxide was formed from 240.7 to 248.7 ℃., and metastable molybdenum oxide was turned into molybdic oxide from 248. 7 to 322. 5 ℃. At the same time, the pattern of pyrolysates of ammonium paramolybdate was changed hardly below 300 ℃. But, its pattern was changed into irregular flake above 300 ℃ , and relatively regular flake MoO3 was obtained at last. The main reason was that the pyrolysates of ammonium paramolybdate were interacted, migrated and recombined with the increase of temperature, and MoO3 was volatilized and deposited under high temperature.

  14. CASTOR SEED BIO -TRANSFORMER OIL AS AN ALTERNATIVE TO CONVENTIONAL TRANSFORMER OIL

    OpenAIRE

    Egbuna, S.O.*, Ude, O.C., Ude, C.N.

    2016-01-01

    In search of solution to the harmful ecological problems due to toxicity and non-biodegradability posed by conventional transformer insulation oil (mineral oil), the production of transformer oil from castor seed oil (vegetable oil) was carried out. The oil was extracted using N-hexane and was refined. The transformer oil was produced by trans-esterification and was characterized using American Society for Testing Material (ASTM) standard test. The solvent employed gave good yield of oil from...

  15. 14 CFR 25.1013 - Oil tanks.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil tanks. 25.1013 Section 25.1013... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Oil System § 25.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 25.967. (b) Expansion space. Oil tank...

  16. 14 CFR 29.1013 - Oil tanks.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil tanks. 29.1013 Section 29.1013... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Oil System § 29.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 29.967. (b) Expansion space. Oil tank...

  17. 14 CFR 29.1025 - Oil valves.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil valves. 29.1025 Section 29.1025... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Oil System § 29.1025 Oil valves. (a) Each oil shutoff.... (c) Each oil valve must have positive stops or suitable index provisions in the “on” and...

  18. 14 CFR 25.1025 - Oil valves.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil valves. 25.1025 Section 25.1025... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Oil System § 25.1025 Oil valves. (a) Each oil shutoff... feathering. (c) Each oil valve must have positive stops or suitable index provisions in the “on” and...

  19. 7 CFR 985.11 - Salable oil.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Salable oil. 985.11 Section 985.11 Agriculture... HANDLING OF SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Definitions § 985.11 Salable oil. Salable oil means that oil which is free to be handled....

  20. China's Oil Imports and Exports in 2007

    Institute of Scientific and Technical Information of China (English)

    Tian Chunrong

    2008-01-01

    @@ The net imports of oil increased by 8.4% in China in 2007, hitting the record of 183.48 million tons (Fig.l).The net imports of crude oil and other oil products including paraffin wax, oil coke, and asphalt increased and balanced out the decrease of the net imports of product oil and liquefied petroleum gas (LPG).

  1. Oil patch pariah

    Energy Technology Data Exchange (ETDEWEB)

    Nikiforuk, A.

    1999-12-10

    Problems that can arise when Western oil companies invest in developing countries suffering under political instability are described using Calgary-based Talisman Energy Inc.'s recent experiences in the Sudan as example. In 1998 Talisman acquired a 25 per cent interest in an oil project by cash-poor Arakis Energy Corporation, thus acquiring a foothold in the Middle East , and more importantly, access to one of the world's largest oil reserves at a bargain-basement price. A UN report accusing the Sudanese government of gross human rights violations , the chagrin expressed by the US Secretary of State that a Canadian company would do business with a country that the US officially regards as 'a state sponsor of terrorism', a warning by the Canadian Minister of Foreign Affairs of economic sanctions unless Talisman demonstrates active promotion of human rights in the Sudan, led the Ontario Teachers Federation to threaten to withdraw its $ 184-million stake in Talisman if reports of human rights abuses in the country can be corroborated. A fact finding mission has been dispatched by the Minister of Foreign Affairs to establish by next month who is killing whom in the Sudan and whether oil revenue from Talisman is being used to fund a campaign of terror and killing that have claimed the lives of some two million Sudanese citizens in the past 16 years. As a result of the turmoil caused by these actions Talisman lost nearly $ 700 million in value in the last week of October, and several institutional investors are actively considering selling their shares in Talisman. The company has hired a top public relations firm to defend itself against the 'coordinated attack' by human rights groups, Sudanese refugees, and Christian fundamentalists whose aim is said to be to shut down oil production in the Sudan. Talisman management is confident that given the company's reputation and its large asset base, it can weather the storm that its Sudanese

  2. Sulfonation of phenols extracted from the pyrolysis oil of oil palm shells for enhanced oil recovery.

    Science.gov (United States)

    Awang, Mariyamni; Seng, Goh Meng

    2008-01-01

    The cost of chemicals prohibits many technically feasible enhanced oil recovery methods to be applied in oil fields. It is shown that by-products from oil palm processing can be a source of valuable chemicals. Analysis of the pyrolysis oil from oil palm shells, a by-product of the palm oil industry, reveals a complex mixture of mainly phenolic compounds, carboxylic acids, and aldehydes. The phenolic compounds were extracted from the pyrolysis oil by liquid-liquid extraction using alkali and an organic solvent and analyzed, indicating the presence of over 93% phenols and phenolic compounds. Simultaneous sulfonation and alkylation of the pyrolysis oil was carried out to produce surfactants for application in oil fields. The lowest measured surface tension and critical micelle concentration was 30.2 mNm(-1) and 0.22 wt%, respectively. Displacement tests showed that 7-14% of the original oil in place was recovered by using a combination of surfactants and xanthan (polymer) as additives.

  3. International Oil Supplies and Demands

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--90 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  4. International Oil Supplies and Demands

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-01

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--1990 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  5. Are olive oil diets antithrombotic?

    DEFF Research Database (Denmark)

    Larsen, L.F.; Jespersen, J; Marckmann, P.

    1999-01-01

    BACKGROUND: The incidence of ischemic heart disease (IHD) in Crete was lower than expected on the basis of blood lipid concentrations of participants in the Seven Countries Study. A favorable effect of a high intake of olive oil on thrombogenesis may have contributed to this finding. OBJECTIVE: We...... compared the effects of virgin olive oil with those of rapeseed and sunflower oils on blood coagulation factor VII (FVII), a key factor in thrombogenesis. DESIGN: In a randomized and strictly controlled crossover study, 18 healthy young men consumed diets enriched with 5 g/MJ (19% of total energy) olive...... oil, sunflower oil, or rapeseed oil for periods of 3 wk. On the final day of each period, participants consumed standardized high-fat meals (42% of energy as fat). Fasting and nonfasting blood samples were collected after each period. RESULTS: Mean (+/-SEM) nonfasting peak concentrations of activated...

  6. Liquid oil and residual characteristics of printed circuit board recycle by pyrolysis.

    Science.gov (United States)

    Lin, Kuo-Hsiung; Chiang, Hung-Lung

    2014-04-30

    Non-metal fractions of waste printed circuit boards (PCBs) were thermally treated (200-500°C) under nitrogen atmosphere. Carbon, hydrogen, and nitrogen were determined by elemental analyzer, bromine by instrumental neutron activation analysis (INAA), phosphorus by energy dispersive X-ray spectrometer (EDX), and 29 trace elements by inductively coupled plasma atomic emission spectrometer (ICP-AES) and mass spectrometry (ICP-MS) for raw material and pyrolysis residues. Organic compositions of liquid oil were identified by GC (gas chromatography)-MS, trace element composition by ICP system, and 12 water-soluble ions by IC (ionic chromatography). Elemental content of carbon was >450 mg/g, oxygen 300 mg/g, bromine and hydrogen 60 mg/g, nitrogen 30 mg/g, and phosphorus 28 mg/g. Sulfur was trace in PCBs. Copper content was 25-28 mg/g, iron 1.3-1.7 mg/g, tin 0.8-1.0mg/g and magnesium 0.4-1.0mg/g; those were the main metals in the raw materials and pyrolytic residues. In the liquid products, carbon content was 68-73%, hydrogen was 10-14%, nitrogen was 4-5%, and sulfur was less than 0.05% at pyrolysis temperatures from 300 to 500°C. Phenol, 3-bromophenol, 2-methylphenol and 4-propan-2-ylphenol were major species in liquid products, accounting for >50% of analyzed organic species. Bromides, ammonium and phosphate were the main species in water sorption samples for PCB pyrolysis exhaust. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. CSR Important to Oil Companies

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    @@ Corporations are human endeavors, and all human endeavors should benefit our society and reflect our morals. They should provide more than just investor return. The nature of oil industry demands that oil companies be socially responsible in addition to operating in an ethical and environmentally friendly manner. At a time of rising energy prices and global concern over our energy future, however, oil companies should give even greater emphasis to this part of their approach to corporate social responsibility(CSR).

  8. Regeneration of used lubricating oils

    Energy Technology Data Exchange (ETDEWEB)

    Adler, N.; Adler, E.; Cismic, V.; Prohaska, B.; Yabar-Mejia, B.

    1981-01-01

    In Yugoslavia in 1985, it is planned that 150,000 tons/year will be recycled, at a consumption of 317,000 tons/year of lubricating oils. The technology is described for recycling waste oil by the traditional method of sulfuric acid cleaning with precleaning by bleaching clay and modern waste oil recycling processes, based on using selective solvents and hydraulic cleaning. The technological features are examined of performing individual recycling stages; dehydration, purification by sulfuric acid, propane, and a mixture of propanol-2, methyl ethyl ketone and butanol-1, propanol-2 and butanol-1, hydraulic cleaning, rectification, precleaning by bleaching clay, and addition of additives. It is noted that the unit capacity of old waste oil recycling plants using sulfuric acid and bleaching clay, built in Zaqreb, Modrits and Maribor, does not exceed 10,000 tons/year, while the new plant for deasphalting by propane and hydraulic cleaning built in Belgrad is rated to recycle 25,000 tons/year of oil (the total capacity of the oil recycling plants has reached 55,000 tons/year). A comparison is made of the economic indices of operation of the old and new waste oil recycling plants. Initial data, the technique and results of economic calculations are given. It is established that modern waste oil recycling plants are more profitable than antiquated ones with a low unit capacity. The profitability of the plants will grow with an increase in the capacity and in oil prices.

  9. Oil tankers: some basic economics

    Energy Technology Data Exchange (ETDEWEB)

    Banks, F.E.

    1987-06-01

    A non-technical introduction to the economics of transporting crude oil by sea notes the large number of brokers and frequent changes in freight rates make it a risky enterprise. Most of the crude oil that enters into international trade is carried in ships owned by oil companies, although some oil-producing countries want to build their own fleets. Basic freight rates for selected voyages are available from the monthly published Average Freight Rate Assessment, which shows rates as a percentage of the Worldscale Index. The author explains how tanker size, speed, availability, and other factors influence the economics of the tanker industry. 7 references, 2 tables.

  10. Co-pirólise de resíduos de polietileno com gasóleo pesado da Bacia de Campos Co-pirolysis of Polyethylene Waste with the Campos Bacia Heavy Oil

    Directory of Open Access Journals (Sweden)

    Débora da S. Carneiro

    2011-01-01

    Full Text Available Neste estudo, quatro misturas de PEBD pós-consumo com gasóleo pesado da Bacia de Campos, em diferentes proporções, foram submetidas à pirólise em atmosfera inerte a 550 °C. Os líquidos pirolíticos foram caracterizados por cromatografia em fase gasosa acoplada à espectrometria de massas (CG/EM. A pirólise do gasóleo puro forneceu elevado teor de resíduo e apenas 4% hidrocarbonetos na faixa do óleo diesel. Por outro lado, a pirólise da mistura de gasóleo com PEBD (na proporção 1/0,5 em m/m forneceu 20% de hidrocarbonetos leves com elevada produção de óleo pirolítico (96%. Desta forma, pode-se concluir que a pirólise de resíduos plásticos com gasóleo pesado pode ser uma tecnologia promissora não apenas para aumentar a formação de hidrocarbonetos leves derivados de gasóleo pesado como também para o reaproveitamento de resíduos plásticos.In this study, four mixtures of LDPE post consumer with heavy gas from the Campos Basin, in different proportions, were subjected to pyrolysis in an inert atmosphere at 550 °C. The pyrolytic liquids were characterized by gas chromatography coupled to mass spectrometry (GC/MS. Pyrolysis of pure diesel supplied large amounts of waste oil and only 4% in the range of diesel. On the other hand, the pyrolysis of LDPE mixture of diesel (at the ratio 1/0,5 m/m provided 20% of light hydrocarbons with high production of pyrolytic oil (96%. The formation of high levels of paraffins and olefins in the range of diesel oil during the co-pyrolysis suggests a promising technology for recycling of plastic waste.

  11. Structures, Mixed Types - Oil & Gas Locations

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — An Oil and Gas Location is a DEP primary facility type related to the Oil & Gas Program. The sub-facility types related to Oil and Gas that are included in this...

  12. Review and Outlook of China's Oil Market

    Institute of Scientific and Technical Information of China (English)

    Gong Jinshuang

    2006-01-01

    @@ Major features of China's oil market in 2005 China's oil market is changing under the influence of domestic economy and the international oil market, witnessing different characteristics from time to time.

  13. China's Oil Industry Seeking Overseas Cooperation

    Institute of Scientific and Technical Information of China (English)

    CD News

    1996-01-01

    @@ China is actively exploring international oil markets,while making the efforts to tap huge oil and gas resources domestically, with the participation of foreign firms,according to a senior Chinese oil official.

  14. Environmental emergency in the oil production and oil products transport

    Directory of Open Access Journals (Sweden)

    Jozef Čopan

    2006-10-01

    Full Text Available The paper refers to the experience of the environmental emergency response in the case of accidental leakages of oil or oil products into the environment. The gained experience is demonstrated on four different sites where the remediation of contaminated soil / groundwater and emergency response were carried out by the Czech environmental company DEKONTA a.s.

  15. Do oil dispersants make spilled oil more toxic to fish?

    Energy Technology Data Exchange (ETDEWEB)

    Hodson, P. [Queen' s Univ., Kingston, ON (Canada)

    2010-07-01

    The Deepwater Horizon blowout in the Gulf of Mexico was the world's largest oil spill in terms of duration and volume spilled. Clean-up operations, which involved the continuous and wide-spread use of oil dispersant at the surface and at the seabed discharge point at 1500 metres depth, gave rise to public concern about dispersant toxicity. Reports from the United States Environmental Protection Agency (EPA) claimed little difference in acute toxicity to marine fish and invertebrate species among commonly available dispersants and between dispersed and non-dispersed Louisiana Sweet Crude. Technically, the toxicity of waterborne hydrocarbons does not vary with chemical dispersion. However, the EPA omitted any consideration of loading, and misled the public about the risks of dispersant use in oil clean-up. This study examined the chronic toxicity of dispersed oil to fish embryos. The study revealed that toxicity expressed as oil loading increases by a factor of 10 to 1000 times with dispersion, largely because 10 to 1000 times more oil enters the water column. Since the action of dispersant is on the exposure component of the risk equation, not on the potency of the toxic components of oil, then the risk of oil toxicity to fish increases an equivalent amount.

  16. Life cycle of transformer oil

    Directory of Open Access Journals (Sweden)

    Đurđević Ksenija R.

    2008-01-01

    Full Text Available The consumption of electric power is constantly increasing due to industrialization and population growth. This results in much more severe operating conditions of transformers, the most important electrical devices that make integral parts of power transmission and distribution systems. The designed operating life of the majority of worldwide transformers has already expired, which puts the increase of transformer reliability and operating life extension in the spotlight. Transformer oil plays a very important role in transformer operation, since it provides insulation and cooling, helps extinguishing sparks and dissolves gases formed during oil degradation. In addition to this, it also dissolves moisture and gases from cellulose insulation and atmosphere it is exposed to. Further and by no means less important functions of transformer are of diagnostic purpose. It has been determined that examination and inspection of insulation oil provide 70% of information on transformer condition, which can be divided in three main groups: dielectric condition, aged transformer condition and oil degradation condition. By inspecting and examining the application oil it is possible to determine the condition of insulation, oil and solid insulation (paper, as well as irregularities in transformer operation. All of the above-mentioned reasons and facts create ground for the subject of this research covering two stages of transformer oil life cycle: (1 proactive maintenance and monitoring of transformer oils in the course of utilization with reference to influence of transformer oil condition on paper insulation condition, as well as the condition of the transformer itself; (2 regeneration of transformer oils for the purpose of extension of utilization period and paper insulation revitalization potential by means of oil purification. The study highlights advantages of oil-paper insulation revitalization over oil replacement. Besides economic, there are

  17. Degumming of soybean oil

    Directory of Open Access Journals (Sweden)

    Aly, Saadia M.

    1992-10-01

    Full Text Available Degumming process was carried out on Factory grade crude soybean oil in fats and oils Department. Thirty two samples were treated with different concentrations of phosphoric acid and / or water at different temperatures and with different time of stirring. It was found that degumming 100 gm of oil with 3,5% water only and with 0,34 gm phosphoric acid in 5,8% water, at 75°C with stirring time of 30 minutes gave better results compared with other conditions. The analysis of variance of factorial experiments for illustrating the different effect and interaction between time of stirring and temperature during degumming process was recorded.

    El proceso de desgomado fue llevado a cabo en una fábrica de aceite crudo de soja en el departamento de aceites y grasas. Treinta y dos muestras fueron tratadas con concentraciones diferentes de ácido fosfórico y/o agua a temperaturas diferentes y con tiempo diferente de agitación. Se encontró que el desgomado de 100 g de aceite con solo 3,5% de agua y con 0,34 g de ácido fosfórico en 5,8% de agua a 75°C, con tiempo de agitación de 30 minutos, dio mejores resultados comparado con otras condiciones. Se realizó el análisis de varianza de experiencias factoriales para ilustrar el diferente efecto y la interacción entre el tiempo de agitación y la temperatura, durante el proceso de desgomado.

  18. Oil palm seed distribution

    Directory of Open Access Journals (Sweden)

    Durand-Gasselin Tristan

    2005-03-01

    Full Text Available For a tropical plant, the oil palm commodity chain has the peculiarity of possessing a major seed production sector for reasons that are primarily genetic. This seed sector has numerous original aspects. Breeders are also propagators and usually also distribute their seeds. Oil palm seeds are semi-recalcitrant: they display pseudo-dormancy. Achieving seed germination is difficult and requires lengthy treatments and special installations. This restriction greatly influences seed distribution and the role of the different stakeholders in the commodity chain. It was only once it had been discovered how the “sh” gene functioned, which controls shell thickness, and when it became necessary to produce “tenera” seeds derived from exclusively “dura x pisifera” crosses, that a true seed market developed. In addition it is difficult to organize seed distribution to smallholders. This is partly due to difficulties that the profession, or a State-run organization, has in controlling middlemen networks, and partly to the absence of any protective systems (UPOV, plant breeder certificate, etc. that generally oblige breeders to preserve and propagate parents in their own installations. In fact there are major inequalities in the access to seeds between agroindustry and smallholders. Another peculiarity of the oil palm seed market is the virtually total absence of guarantees for buyers: the quality of the research conducted by breeders, the seed production strategies necessary for transferring genetic progress, and the technical quality of production. The only guarantee today comes from the relations of confidence established year after year between breeders/distributors and growers. In this fields, research can lead to some proposals: molecular biology offers some interesting prospects for certifying seed quality and social science develop effective communication methods.

  19. Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Gui, M.M.; Lee, K.T.; Bhatia, S. [School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang (Malaysia)

    2008-11-15

    Biodiesel has high potential as a new and renewable energy source in the future, as a substitution fuel for petroleum-derived diesel and can be used in existing diesel engine without modification. Currently, more than 95% of the world biodiesel is produced from edible oil which is easily available on large scale from the agricultural industry. However, continuous and large-scale production of biodiesel from edible oil without proper planning may cause negative impact to the world, such as depletion of food supply leading to economic imbalance. A possible solution to overcome this problem is to use non-edible oil or waste edible oil (WEO). In this context, the next question that comes in mind would be if the use of non-edible oil overcomes the short-comings of using edible oil. Apart from that, if WEO were to be used, is it sufficient to meet the demand of biodiesel. All these issues will be addressed in this paper by discussing the advantages and disadvantages of using edible oil vs. non-edible vs. WEO as feedstock for biodiesel production. The discussion will cover various aspects ranging from oil composition, oil yield, economics, cultivation requirements, land availability and also the resources availability. Finally, a proposed solution will be presented. (author)

  20. 21 CFR 184.1472 - Menhaden oil.

    Science.gov (United States)

    2010-04-01

    ... hydrogenated menhaden oils are used as edible fats or oils, as defined in § 170.3(n)(12) of this chapter, in... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Menhaden oil. 184.1472 Section 184.1472 Food and... Substances Affirmed as GRAS § 184.1472 Menhaden oil. (a) Menhaden oil. (1) Menhaden oil is prepared from...

  1. Olive oil and haemostasis

    Directory of Open Access Journals (Sweden)

    Williams, Christine M.

    2004-03-01

    Full Text Available Olive oil is a key component of the traditional Mediterranean diet; a diet that may explain the low rate of cardiovascular disease (CVD in Southern European. (Extra virgin Olive oil is a good source of monounsaturated fatty acids (MUFA and phenolic compounds, both of which have been investigated for their effects on plasma lipids and lipoproteins, measures of oxidation and factors related to thrombosis. This issue aims to summarise the current understanding of the effects of such dietary components on the haemostatic system and subsequent risk of CVD. To date, evidence suggests that diets rich in MUFA and thus in olive oil attenuate the thrombotic response via a reduction in platelet aggregation and in postprandial FVII levels. Thrombosis is a key event in causing heart attacks and strokes, which if modulated by diet could pose a cost-effective way of reducing CVD incidence in populations that adhere to MUFA/olive oil-rich diets long-term.El aceite de oliva es un componente esencial de la dieta Mediterránea que puede explicar el bajo índice de enfermedad cardiovascular (CVD en los países del sur de Europa. El aceite de oliva (extra virgen es una fuente de ácidos grasos monoinsaturados (MUFA y de compuestos fenólicos, de gran interés por sus efectos, entre otros, sobre las lipoproteínas y los lípidos plasmáticos, su capacidad antioxidante y su papel en la expresión de factores relacionados con la trombosis. En este capítulo se presenta un resumen del conocimiento actual sobre la influencia derivada del consumo de aceite de oliva (extra virgen en el sistema hemostático y el riesgo de CVD. Por ahora se sabe que dietas ricas en MUFA (aceite de oliva pueden atenuar la respuesta trombótica mediante la reducción de la agregación plaquetaria y de las concentraciones postprandiales del factor VII de coagulación (FVII. La trombosis es un evento relevante en los ataques al corazón y el ictus, de manera que su modulación con la dieta puede

  2. Oil from plants

    Science.gov (United States)

    Calvin, M.

    1983-01-01

    As a result of the exhaustion of our supplies of ancient photosynthesis (oil and gas) it is necessary to develop renewable fuels for the future. The most immediate source of renewable fuel is, of course, the annually growing green plants, some of which produce hydrocarbon(s) directly. New plant sources can be selected for this purpose, plants which have high potential for production of chemicals and liquid fuels. Suggestions are made for modification of both the product character and the productivity of the plants. Ultimately, a totally synthetic device will be developed for the conversion of solar quanta into useful chemical form completely independent of the need for arable land.

  3. 预制体结构和热解碳组织对二维碳/碳复合材料热物理性能影响%Effects of Preform and Pyrolytic Carbon Structure on Thermophysical Properties of 2D Carbon/Carbon Composites

    Institute of Scientific and Technical Information of China (English)

    罗瑞盈; 程永宏

    2004-01-01

    Four kinds of carbon/carbon (C/C) composites, including the needled carbon fiber felt/the pyrolytic carbon (two different pyrolytic carbon microstructures), the chopped carbon fiber/the resin + pyrolytic carbon (PyrC), and the carbon cloth/PyrC, named as the composites 1#, 4#, 2#, and 3#, are prepared respectively. Effects of the preform and pyrolytic carbon structure on the thermophysical properties of 2D C/C composites are studied. The C/C composites possess low coefficient of thermal expansion (CTE). In a range of some temperatures, the negative expansion emerges in x-y direction for four C/C composites. From 0 to 900℃, the CTE is small and almost linear with the temperatures. The C/C composites have high thermal conductivities (TCs). As a function of temperature, TCs of the C/C composites are varied with the structures of preform and pyrc as well as the direction of heat transfer. In x-y and z direction, TCs differ greatly and that in x-y direction (25.6-174 W/m·K) is several times larger than that in z direction(3.5-50 W/m·K).%制备了针刺毡、短纤维树脂模压、碳布叠层3种预制体,其碳纤维体积含量均为40%.采用化学气相沉积工艺制备了4种C/C复合材料: 针刺毡+粗糙体热解碳(具有两种定向热解碳组织)、短纤维+树脂和热解碳、碳布+光滑体热解碳复合材料,对其进行2500℃保温2h的高温热处理.在0~900℃,研究了预制体结构和热解碳组织对二维C/C复合材料的热膨胀系数、比热容、热扩散率、导热系数等热物理性能影响.研究发现:预制体和热解碳结构对C/C复合材料热物理性能有强烈影响.0~900℃,4种材料的热膨胀系数都非常小,与温度近似的成线性关系,且几乎具有相同的斜率,在一定条件下,其值呈现负热膨胀性质;0~900℃,4种材料都有高的导热系数,但作为温度的函数,其值随预制体结构、热解碳组织和传热方向而变化, x-y向的导热系数(25.6~174W

  4. Oil-in-oil emulsions stabilised solely by solid particles.

    Science.gov (United States)

    Binks, Bernard P; Tyowua, Andrew T

    2016-01-21

    A brief review of the stabilisation of emulsions of two immiscible oils is given. We then describe the use of fumed silica particles coated with either hydrocarbon or fluorocarbon groups in acting as sole stabilisers of emulsions of various vegetable oils with linear silicone oils (PDMS) of different viscosity. Transitional phase inversion of emulsions, containing equal volumes of the two oils, from silicone-in-vegetable (S/V) to vegetable-in-silicone (V/S) occurs upon increasing the hydrophobicity of the particles. Close to inversion, emulsions are stable to coalescence and gravity-induced separation for at least one year. Increasing the viscosity of the silicone oil enables stable S/V emulsions to be prepared even with relatively hydrophilic particles. Predictions of emulsion type from calculated contact angles of a silica particle at the oil-oil interface are in agreement with experiment provided a small polar contribution to the surface energy of the oils is included. We also show that stable multiple emulsions of V/S/V can be prepared in a two-step procedure using two particle types of different hydrophobicity. At fixed particle concentration, catastrophic phase inversion of emulsions from V/S to S/V can be effected by increasing the volume fraction of vegetable oil. Finally, in the case of sunflower oil + 20 cS PDMS, the study is extended to particles other than silica which differ in chemical type, particle size and particle shape. Consistent with the above findings, we find that only sufficiently hydrophobic particles (clay, zinc oxide, silicone, calcium carbonate) can act as efficient V/S emulsion stabilisers.

  5. Oil spill cleanup method and apparatus

    Energy Technology Data Exchange (ETDEWEB)

    Mayes, F.M.

    1980-06-24

    A method for removing oil from the surface of water where an oil spill has occurred, particularly in obstructed or shallow areas, which comprises partially surrounding a hovercraft with a floating oil-collecting barrier, there being no barrier at the front of the hovercraft, moving the oil-barrier-surrounded-hovercraft into oil contaminated water, and collecting oil gathered within the barrier behind the hovercraft through a suction line which carries the oil to a storage tank aboard the hovercraft. The invention also embodies the hovercraft adapted to effect an oil spill cleanup.

  6. Bergen conference on oil and economics

    Energy Technology Data Exchange (ETDEWEB)

    1988-01-01

    The conference proceedings contain 7 papers. The topics covered are: Possible oil supply distribution and IEA's contingency plan; The oil market and economic progress in third world countries; The impact of oil on the foreign policies of the superpowers and its ramifications on the oil market; The role of the international oil market in Soviet oil policies; International trade -Status and possible developments. Do oil producers hold any particular responsibility; Economic and political issues in the Middle East oil exporting countries; Coping with political risks - business strategies in the case of Mobil. Separate abstract was prepared for one of the papers.

  7. Research on the Pipeline Technology of Heavy Crude Oil%稠油管道输送技术研究

    Institute of Scientific and Technical Information of China (English)

    邹帅; 吴明; 刘佳春

    2014-01-01

    高粘的稠油使得输送成为管道从业者的一个难题,尤其是发生凝管事故后的再启动问题。对稠油高粘的实质迚行研究发现,决定稠油粘度的实质为原油体系中沥青质分子和非沥青质分子相互作用所形成的大分子胶束聚集体所致。国内外稠油输送方法有加热法、裂解降粘法、掺稀输送法、添加改性剂法、低粘液环输送法、微生物法、超声波法和超临界CO2输送法。各方法各具优缺点,没有一种方法适用于所有稠油,另外还需要考虑经济性问题。目前国内最常用的输送方法为加热法和掺稀法。在实际中,针对不同稠油要迚行一定的技术分析和研究才能决定选择何种输送技术。%The pipeline transportation of heavy crude oil with high viscosity has become a difficult problem to operators of pipelines, especially restarting of the pipeline transportation after the pipeline congelation accident. Through research on properties of heavy crude, it’s concluded that the high viscosity of heavy crude depends on macromolecule micelles aggregates formed by interaction between asphaltene molecules and non-asphaltene molecules in the system of crude oil. There are some pipeline processes at home and abroad, such as heating, pyrolytic decomposition, blending method, adding modifiers, ultrasonic method, microbiological process and supercritical CO2 transport method. Every method has its advantages and disadvantages, and none can fit all kinds of heavy crude oil. At present, heating and blending methods are the most common at home and abroad. In the practical condition, the most suitable process should be chosen based on analysis and research on the heavy crude oil.

  8. A biological oil adsorption filter

    Energy Technology Data Exchange (ETDEWEB)

    Pasila, A. [University of Helsinki (Finland). Dept. of Agricultural Engineering and Household Technology

    2005-12-01

    A new oil adsorption method called adsorption filtration (AF) has been developed. It is a technology where by oil residues can be cleaned from water by running it through a simple filter made from freeze treated, dried, milled and then fragmented plant material. By choosing suitable plants and fragmentation sizes it is possible to produce filters, which pass water but adsorb oil. The aim of this study was to investigate the possibilities of manufacturing oil adsorbing filter materials from reed canary grass (Phalaris arundinacea), flax (Linum usitatissimum L.) or hemp fibre (Cannabis sativa L.). The oil (80 ml) was mixed with de-ionised water (200 ml) and this mixture was filtered through 10 or 20 g adsorption filters. Fine spring harvested hemp fibre (diameter less than 1 mm) and reed canary grass fragments adsorb 2-4 g of oil per gram of adsorption material compared to 1-3 g of water. Adsorption filtration is thus a novel way of gathering spilled oil in shallow coastal waters before the oil reaches the shore. (author)

  9. Detergent Additive for Lubricating Oils,

    Science.gov (United States)

    The Russian patent pertains to a method of producing additives for lubricating oils . A method is known for producing an antiwear additive for... lubricating oils by processing phenols with phosphorus oxychloride, phosphoric acid esters are obtained. In order to give the additive detergent properties

  10. Pyrolysis oil as diesel fuel

    Energy Technology Data Exchange (ETDEWEB)

    Gros, S. [Wartsila Diesel International Ltd., Vaasa (Finland). Diesel Technology

    1996-12-31

    Wood waste pyrolysis oil is an attractive fuel alternative for diesel engine operation. The main benefit is the sustainability of the fuel. No fossil reserves are consumed. The fact that wood waste pyrolysis oil does not contribute to CO{sub 2} emissions is of utmost importance. This means that power plants utilising pyrolysis oil do not cause additional global warming. Equally important is the reduced sulphur emissions that this fuel alternative implies. The sulphur content of pyrolysis oil is extremely low. The high water content and low heating value are also expected to result in very low NO{sub x} emissions. Utilisation of wood waste pyrolysis oil in diesel engines, however, involves a lot of challenges and problems to be solved. The low heating value requires a new injection system with high capacity. The corrosive characteristics of the fluid also underline the need for new injection equipment materials. Wood waste pyrolysis oil contains solid particles which can clog filters and cause abrasive wear. Wood waste pyrolysis oil has proven to have extremely bad ignition properties. The development of a reliable injection system which is able to cope with such a fuel involves a lot of optimisation tests, redesign and innovative solutions. Successful single-cylinder tests have already been performed and they have verified that diesel operation on wood pyrolysis oil is technically possible. (orig.)

  11. Basil (Ocimum basilicum L.) oils

    Science.gov (United States)

    Basil (Ocimum basilicum) is one of the most popular and healthy culinary herbs in the world. Essential oil derived from basil (basil oil) through steam distillation has traditionally been used for a wide range of applications such as cooking spices, aromatherapy, perfumery, medicinal treatments, pes...

  12. A biological oil adsorption filter.

    Science.gov (United States)

    Pasila, Antti

    2004-12-01

    A new oil adsorption method called adsorption filtration (AF) has been developed. It is a technology where by oil residues can be cleaned from water by running it through a simple filter made from freeze treated, dried, milled and then fragmented plant material. By choosing suitable plants and fragmentation sizes it is possible to produce filters, which pass water but adsorb oil. The aim of this study was to investigate the possibilities of manufacturing oil adsorbing filter materials from reed canary grass (Phalaris arundinacea), flax (Linum usitatissimum L.) or hemp fibre (Cannabis sativa L.). The oil (80 ml) was mixed with de-ionised water (200 ml) and this mixture was filtered through 10 or 20 g adsorption filters. Fine spring harvested hemp fibre (diameter less than 1 mm) and reed canary grass fragments adsorb 2-4 g of oil per gram of adsorption material compared to 1-3 g of water. Adsorption filtration is thus a novel way of gathering spilled oil in shallow coastal waters before the oil reaches the shore.

  13. Characterization of amaranth seed oils

    NARCIS (Netherlands)

    Gamel, T.H.; Mesallam, A.S.; Damir, A.A.; Shekib, L.A.; Linssen, J.P.H.

    2007-01-01

    The oil fractions of Amaranthus caudatus L. and Amaranthus cruentus L. seeds were studied after different treatments of the seeds. The oil contents were 7.1 and 8.5% for raw A. caudatus L. and A. cruentus L. seeds, and consisted of 80.3¿82.3% of triacylglycerols (TAGs). Phospholipids represented 9.1

  14. Tariffs Formation on oil transportation

    Science.gov (United States)

    Glyzina, T. S.; Kolbysheva, Yu. V.; Grivtsova, I. S.; Dmitrieva, N. V.

    2016-09-01

    Oil transportation via trunk pipelines is an important part of the oil industry's activity. The main instrument of tariff regulation is the method of tariffs formation. Three methods of tariffs formation such as the method of economically justified costs (the Cost plus method), the method of economically justified return on investment capital (the RAB method), and the method of tariffs indexation were considered.

  15. Press Oil Final Release Survey

    Energy Technology Data Exchange (ETDEWEB)

    Whicker, Jeffrey Jay [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ruedig, Elizabeth [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-05-11

    There are forty-eight 55 gallon barrels filled with hydraulic oil that are candidates for release and recycle. This oil needs to be characterized prior to release. Principles of sampling as provided in MARSAME/MARSSIM approaches were used as guidance for sampling.

  16. Oil sorption by lignocellulosic fibers

    Science.gov (United States)

    Beom-Goo. Lee; James S. Han; Roger M. Rowell

    1999-01-01

    The oil sorption capacities of cotton fiber, kenaf bast fiber, kenaf core fiber, and moss fiber were compared after refining, extraction, and reduction in particle sizes. The tests were conducted on diesel oil in a pure form. Cotton fiber showed the highest capacity, followed by kenaf core and bast fibers. Wetting, extraction, and reduction in particle size all...

  17. Oil Analysis by Fast DSC

    NARCIS (Netherlands)

    Wetten, I.A.; Herwaarden, A.W.; Splinter, R.; Ruth, van S.M.

    2014-01-01

    Thermal analysis of Olive and Sunflower Oil is done by Fast DSC to evaluate its potential to replace DSC for adulteration detection. DSC measurements take hours, Fast DSC minutes. Peak temperatures of the crystallisation peak in cooling for different Olive and Sunflower Oils are both comparable to D

  18. Consequences of oil film degradation

    DEFF Research Database (Denmark)

    Ravendran, Rathesan

    2017-01-01

    In a review of recent studies into two-stroke lubrication, Rathesan Ravendran and Peter Jensen of Hans Jensen Lubricators highlight the importance of cylinder oil distribution.......In a review of recent studies into two-stroke lubrication, Rathesan Ravendran and Peter Jensen of Hans Jensen Lubricators highlight the importance of cylinder oil distribution....

  19. Oil Analysis by Fast DSC

    NARCIS (Netherlands)

    Wetten, I.A.; Herwaarden, A.W.; Splinter, R.; Ruth, van S.M.

    2014-01-01

    Thermal analysis of Olive and Sunflower Oil is done by Fast DSC to evaluate its potential to replace DSC for adulteration detection. DSC measurements take hours, Fast DSC minutes. Peak temperatures of the crystallisation peak in cooling for different Olive and Sunflower Oils are both comparable to

  20. Castor oil: Biosynthesis and Uses

    Science.gov (United States)

    Castor oil is unique among commodity oils in its fatty acid composition, which consists of 90% ricinoleate, (12-hydroxy-octadec-cis 9-enoate). The mid-chain hydroxyl group imparts physical and chemical properties that make it useful in many industrial applications. Among its uses are lithium grease,...

  1. Characterization of amaranth seed oils

    NARCIS (Netherlands)

    Gamel, T.H.; Mesallam, A.S.; Damir, A.A.; Shekib, L.A.; Linssen, J.P.H.

    2007-01-01

    The oil fractions of Amaranthus caudatus L. and Amaranthus cruentus L. seeds were studied after different treatments of the seeds. The oil contents were 7.1 and 8.5% for raw A. caudatus L. and A. cruentus L. seeds, and consisted of 80.3¿82.3% of triacylglycerols (TAGs). Phospholipids represented

  2. About Oil, Cars and Comrades

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The last century was the century of oil, cars and electricity. Crude oil was probably the critical raw material for the industrial development of the United States, England, Germany and the like from the late 19th century to the beginning of the 21 st. Amazing amounts of riches were made. Those who called

  3. Vegetable oil spills on salt marsh sediments; comparison between sunflower and linseed oils.

    Science.gov (United States)

    Pereira, M Glória; Mudge, Stephen M; Latchford, John

    2003-09-01

    The effects of a simulated spill of sunflower oil in salt marsh sediments were compared with an experiment with linseed oil. Sunflower and linseed oil penetrated the sediments at the same rates but different adsorption of the oils onto sediment particles resulted in the establishment of anaerobic conditions at shallower depths in sediments contaminated with linseed oil than with sunflower oil. The total lipid content of sunflower oil contaminated sediments remained almost stable for 6 months, whilst only 40% of linseed oil remained in the sediment after 2 months. Numbers of culturable heterotrophic bacteria and aerobic oil degrading bacteria in muddy sediment increased rapidly in response to the presence of the oils but bacterial numbers in sandy sediments increased more slowly for sunflower oil. Changes in fatty acid composition indicate similar degradation pathways for both oils but sunflower oil degraded more slowly than linseed oil and thus has the potential for longer lasting effects in marine environments.

  4. Engine oil wear resistance

    Directory of Open Access Journals (Sweden)

    A.N. Farhanah

    2015-03-01

    Full Text Available Lubricants play a vital role in an internal combustion engine to lubricate parts and help to protect and prolong the engine life. Lubricant also will help to reduce wear by creating lubricating film between the moving parts hence reduce metal-to-metal contacts. Engine oil from three different manufacturers with the same SAE viscosity grade available in market does not mean it will have the same lubricity for an engine. In this study, commercial mineral lubrication oil (SAE 10W-30 from three manufacturers was investigated to compare the lubrication performance at three different temperatures (40˚C, 70˚C and 100˚C in 60 minutes time duration by using four ball wear tester. The speed will be varied from 1000 rpm to 2500 rpm. Results show that all three lubricants have different lubricity performance; the smaller the wear scar, the better the lubricant since the lubricant can protect the moving surfaces from direct metal-to-metal contact occur.

  5. China to Bolster Oil Stockpiles

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    @@ China is accelerating the build-up of its oil reserves to avoid the economic dislocations the country suffered in 2008 from fluctuations in the world oil price.China will,in addition to the current four strategic petroleum reserve bases,build eight new ones by 2011.The program will increase China's strategic crude reserve capacity to 44.6 million cubic meters,or 281 million barrels.The country will also increase its oil products reserve to 10 million tons by 2011."China's attentiveness to its oil reserve capacity has grown in tandem with its rising dependence on imported oil," said Pan Jiahua,an expert with the Chinese petroleum society.

  6. CYLINDER AND SYSTEM LUBRICATING OILS

    Directory of Open Access Journals (Sweden)

    ION ADRIAN GIRBA

    2016-06-01

    Full Text Available Increased thermal efficiency, savings in the fuel consumption and the possibility to burn low quality fuels conducted to an intense development of marine engines in past 20 years, this progress being emphasized by the increased combustion pressures and better combustion properties. These improvements represent a continuous challenge for lubricating oil manufacturers: the rise in combustion temperatures and pressures is making difficult to preserve the oil film in critical areas and the longer strokes of the piston leads to issues of spreading the oil. Adding here the new type of engines using gas or biofuel which requires different types of lubricating oils. Therefore, the success of new generation of engines will depend on lubricating oils quality. :

  7. Enzymatic transesterification of Jatropha oil

    Directory of Open Access Journals (Sweden)

    Garlapati Vijay

    2009-01-01

    Full Text Available Abstract Background Transesterification of Jatropha oil was carried out in t-butanol solvent using immobilized lipase from Enterobacter aerogenes. The presence of t-butanol significantly reduced the negative effects caused by both methanol and glycerol. The effects of various reaction parameters on transesterification of Jatropha oil were studied. Results The maximum yield of biodiesel was 94% (of which 68% conversion was achieved with respect to methyl oleate with an oil:methanol molar ratio of 1:4, 50 U of immobilized lipase/g of oil, and a t-butanol:oil volume ratio of 0.8:1 at 55°C after 48 h of reaction time. There was negligible loss in lipase activity even after repeated use for seven cycles. Conclusion To the best of our knowledge this is the first report on biodiesel synthesis using immobilized E. aerogenes lipase.

  8. Microbial enhanced oil recovery (MEOR).

    Science.gov (United States)

    Brown, Lewis R

    2010-06-01

    Two-thirds of the oil ever found is still in the ground even after primary and secondary production. Microbial enhanced oil recovery (MEOR) is one of the tertiary methods purported to increase oil recovery. Since 1946 more than 400 patents on MEOR have been issued, but none has gained acceptance by the oil industry. Most of the literature on MEOR is from laboratory experiments or from field trials of insufficient duration or that lack convincing proof of the process. Several authors have made recommendations required to establish MEOR as a viable method to enhance oil recovery, and until these tests are performed, MEOR will remain an unproven concept rather than a highly desirable reality. Copyright 2010 Elsevier Ltd. All rights reserved.

  9. Oil for development 2009

    Energy Technology Data Exchange (ETDEWEB)

    2010-09-15

    In this report present key achievements for each of the various cooperation countries. Oil for Development (OfD) assistance has been important for the ability of a country like Ghana to improve petroleum resource management on its most important oil and gas field, and to better safeguard that the petroleum activities are conducted in an environmentally sustainable way. Competence building on Increased Oil Recovery (IOR), and negotiation training have helped to increase both the resource extraction potential and the revenue generation potential of a more mature oil producing country like Iraq. Furthermore, OfD has contributed to improving the legislative frameworks in several of our cooperating countries, including Afghanistan, Cambodia and Madagascar, although it will take time before we can assess to what extent the laws have been implemented. OfD's strong focus on providing legal assistance reflects our belief that clear divisions of roles and firm legal mandates are prerequisites for good governance of the petroleum sector and for attracting serious investors. A lot of our capacity building took place through seminars and more tailored workshops with a national or regional scope. We believe that some of these events have significantly increased awareness as well as the level of debate among government institutions and civil society. The oil production accounting workshop in Nigeria and the NOC workshop in Timor-Leste are particularly valid examples. Timor-Leste also addressed other petroleum sector governance issues with a focus on including civil society and by the end of 2009 had nearly fulfilled all criteria for becoming Extractive Industries Transparency Initiative (EITI) compliant. It should be noted that OfD assistance only made a relatively small contribution to this process, which was very much nationally driven. Petroleum related environmental issues were addressed at different levels and from different angles. A thorough environmental needs

  10. Fuel oil quality task force

    Energy Technology Data Exchange (ETDEWEB)

    Laisy, J.; Turk, V. [R.W. Beckett Corp., Elyria, OH (United States)

    1997-09-01

    In April, 1996, the R.W. Beckett Corporation became aware of a series of apparently unrelated symptoms that made the leadership of the company concerned that there could be a fuel oil quality problem. A task force of company employees and industry consultants was convened to address the topic of current No. 2 heating oil quality and its effect on burner performance. The task force studied changes in fuel oil specifications and trends in properties that have occurred over the past few years. Experiments were performed at Beckett and Brookhaven National Laboratory to understand the effect of changes in some fuel oil properties. Studies by other groups were reviewed, and field installations were inspected to gain information about the performance of fuel oil that is currently being used in the U.S. and Canada. There was a special concern about the use of red dye in heating oils and the impact of sulfur levels due to the October, 1993 requirement of low sulfur (<0.05%) for on-highway diesel fuel. The results of the task force`s efforts were published in July, 1996. The primary conclusion of the task force was that there is not a crisis or widespread general problem with fuel oil quality. Localized problems that were seen may have been related to refinery practices and/or non-traditional fuel sources. System cleanliness is very important and the cause of many oil burner system problems. Finally, heating oil quality should get ongoing careful attention by Beckett engineering personnel and heating oil industry groups.

  11. Nanoporous polystyrene fibers for oil spill cleanup.

    Science.gov (United States)

    Lin, Jinyou; Shang, Yanwei; Ding, Bin; Yang, Jianmao; Yu, Jianyong; Al-Deyab, Salem S

    2012-02-01

    The development of oil sorbents with high sorption capacity, low cost, scalable fabrication, and high selectivity is of great significance for water environmental protection, especially for oil spillage on seawater. In this work, we report nanoporous polystyrene (PS) fibers prepared via a one-step electrospinning process used as oil sorbents for oil spill cleanup. The oleophilic-hydrophobic PS oil sorbent with highly porous structures shows a motor oil sorption capacity of 113.87 g/g, approximately 3-4 times that of natural sorbents and nonwoven polypropylene fibrous mats. Additionally, the sorbents also exhibit a relatively high sorption capacity for edible oils, such as bean oil (111.80 g/g) and sunflower seed oil (96.89 g/g). The oil sorption mechanism of the PS sorbent and the sorption kinetics were investigated. Our nanoporous material has great potential for use in wastewater treatment, oil accident remediation and environmental protection.

  12. Oil exploitation and the environmental Kuznets curve

    Energy Technology Data Exchange (ETDEWEB)

    Esmaeili, Abdoulkarim; Abdollahzadeh, Negar [Department of Agricultural Economics, College of Agriculture, Shiraz University, Shiraz, Fars (Iran)

    2009-01-15

    This study refers to a panel estimation of an environmental Kuznets curve (EKC) for oil to determine the factors most affecting oil exploitation in 38 oil-producing countries during 1990-2000. Control variables such as oil reserves, oil price, population, political rights, and the Gini index were used to determine its contribution to the main EKC model. The empirical results fully support the existence of an EKC for oil exploitation. Furthermore, the result indicates that the proved oil reserves has a significant and positive role in oil production, but oil price and population do not significantly affect crude oil production. Also, increased freedoms and a better income distribution will reduce the rate of oil exploitation. Thus, policies aiming at enhancing democratic society and better income distribution would be more compatible with sustainability. (author)

  13. RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek; William E. Brigham

    1999-06-01

    The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

  14. Calendula oil processing : seed classification, oil extraction, refining process development and oil quality aspects

    NARCIS (Netherlands)

    Janssens, R.J.J.

    2000-01-01

    The difference in Calendula oil quality from fractions obtained after seed classification is enormous. The oil quality varies from excellent to very poor, according to important aspects such as in the hulls and dust fraction, high free fatty acid values (13% vs. 0.6%) are found. This can be

  15. Calendula oil processing : seed classification, oil extraction, refining process development and oil quality aspects

    NARCIS (Netherlands)

    Janssens, R.J.J.

    2000-01-01

    The difference in Calendula oil quality from fractions obtained after seed classification is enormous. The oil quality varies from excellent to very poor, according to important aspects such as in the hulls and dust fraction, high free fatty acid values (13% vs. 0.6%) are found. This can be explaine

  16. Calendula oil processing : seed classification, oil extraction, refining process development and oil quality aspects

    NARCIS (Netherlands)

    Janssens, R.J.J.

    2000-01-01

    The difference in Calendula oil quality from fractions obtained after seed classification is enormous. The oil quality varies from excellent to very poor, according to important aspects such as in the hulls and dust fraction, high free fatty acid values (13% vs. 0.6%) are found. This can be explaine

  17. Water issues associated with heavy oil production.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  18. Absorbing materials of thin film for photovoltaic structures prepared by the process of pyrolytic spraying; Materiales absorbedores en pelicula delgada para estructuras fotovoltaicas preparados por el proceso de rocio pirolitico

    Energy Technology Data Exchange (ETDEWEB)

    Calixto Rodriguez, Manuela

    2006-11-15

    In this thesis work thin semiconducting films were grown with the following compounds: In{sub 2}S{sub 3}, Ag{sub 2}S, AgInS{sub 2}, SnS{sub 2} and SnS with the pyrolytic spray technique. The structural, optical and electrical proposals of these films were analyzed to determine the set of deposit parameters in which are obtained the physical properties for the applications of the same in photovoltaic structures. It was found that the molar relation in solution of the departing compounds and the deposit temperature are the same dominant parameters in the process of growing the films. For the deposit of thin films of Indio acetate were used and N, N-dimetil tiourea as precursory compounds of In and S, respectively. Polycrystalline films were obtained from the compound In{sub 2}S{sub 3} using underlying temperatures, Ts, between 400 and 450 degrees Celsius, and Indio acetate solutions and N, N-dimetil tiourea with molar relations (In:S) of 1:8 and 1:1. The energy breach, Eg, of these films varies from 2.04 to 2.67 eV, and the value of the conductivity in the darkness, D varies from 10-7 to 1(cm)-1 in function of the molar relation in solution. It was found that the deposited films using a molar relation of In:S=1:8 are of intrinsic nature independently of Ts, while the ones deposited using a molar relations of In:S=1:1 and Ts 400 degrees Celsius posses type-n conductivity. Using the molar relation of I:S=1:1 and Ts=500 degrees Celsius the compound polycrystalline of In{sub 2}O{sub 3} is obtained whose optical and electrical properties are Eg {approx} 3 eV and D=11 (cm)-1, with electrical conductivity type-n. The deposited films using a molar relation of In:S=1:1 and Ts=450 degrees Celsius are the ones that keep the appropriate characteristics for their use as type-n material in photovoltaic structures (Eg=2eV and D=1?-1 com-1). [Spanish] En este trabajo de tesis se crecieron peliculas delgadas semiconductoras de los compuestos: In{sub 2}S{sub 3}, Ag{sub 2}S, Ag

  19. Preparation of the alkaline lignin pyrolytic based carbon quantum dots/TiO 2 composite photocatalyst%碱木质素基碳量子点/TiO2复合光催化剂的制备

    Institute of Scientific and Technical Information of China (English)

    李伟; 佟国宾; 王梦茹; 田甜; 曾阳; 王思纯

    2016-01-01

    In this paper, we introduced the method of preparing carbon quantum dots ( CQDs) by alkaline lignin pyrolyt⁃ic carbon. The carbon quantum dots were prepared by acid reflux method. Carbon quantum dots/TiO2 composite photo⁃catalyst were prepared by using blending method which combined carbon quantum dots and TiO2 together. Phenol was used as pollutant model for the visible light catalytic activity. Hydrosoluble carbon quantum dots were prepared by using acid reflux method from lignin pyrolytic carbon. SEM, TEM, FT-IR and fluorescence spectrophotometer were used to characterize the particle size distribution, structure and fluorescence properties. The results showed that the carbon quan⁃tum dots were uniform spheres in size with a diameter of 1�5-2�5 nm. FT-IR analysis showed that the surface of carbon quantum dots contained—OH functional groups. Emission spectra around 400-600 nm with a peak at 442 nm were ob⁃served upon excitation at 355 nm. A peak centered at 355 nm in the excitation spectrum was present with an emission wavelength of 442 nm. Photoluminescence spectra also showed that the maximum emission and intensity had a direct re⁃lationship with the excitation wavelength. The fluorescence spectrum analysis showed that when the excitation wavelength was changed, the emission wavelength was red⁃shifted, and the product had a good response in the visible region. With the increase of pH at specific excitation wavelength, the peak of the carbon quantum dots showed a decreasing trend. When pH>7, the spectrum of the spectrum was blue⁃shifted. The CQDs/TiO2 system was found to be an effective photo⁃catalyst, and the CQDs on the surface of TiO2 acted as a photosensitizer. They had the wide spectral response range of TiO2 in the UV region, in addition to spectral response in the visible⁃light region. CQDs/TiO2 composite photocatalyst showed excellent catalytic activity with the phenol degradation percentage of 91%.%以碱木质素热解炭为

  20. Study on Pyrolyzing Castor Oil Catalytically in Preparing Undecenoic Acid%蓖麻油催化裂解-制十一烯酸研究

    Institute of Scientific and Technical Information of China (English)

    靳福泉

    2001-01-01

    采用减压催化的方式,对蓖麻油直接裂解制备十一烯酸的方法进行了研究。结果表明:使用N型催化剂,在温度400℃,压力23.3 kPa,物料流量700g/h的条件下,十一烯酸收率达24.6%,庚醛18.3%。该法降低了解裂温度,简化了工艺,节省了原料,且催化剂可反复再生使用。%Castor oil was catalytically pyrolyzed for preparing undecenoic acid under reduced pressure. Results showed that the yield of undecenoic acid was up to 24. 6% and that of heptaldehyde to 18.3% in pres ence of N catalyst and at 400℃ and 23.3 kPa pressure, 700 g/h flow rate. In the process, pyrolytic temperature was reduced, the process simplified and the material economized. Moreover, the catalyst can be regenerated.

  1. Oil Giants Play Vital Role in China's Strategic Oil Reserves

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ China plans to start building of its strategic reserve in August this year in the attempts to meet the emergency case and moderate the oil prices, according to a senior official at Sinopec, one of China's three oil giants."This will definitely be used as a mechanism to manage prices," he added. The government planned to allow State-owned companies to draw on the oil reserve when prices breached a yet-to-be-determined ceiling, and this was strongly supported by the refiners, the Petroleum Intelligence Weekly recently reported.

  2. Efek Olive Oil dan Virgin Coconut Oil terhadap Striae Gravidarum

    OpenAIRE

    2014-01-01

    The prevalence of striae gravidarum (SG) in pregnant women ranges from 50% to 90%. Effects of SG include itchy and hot feeling as well as dry skin. This situation also causes emotional disturbances that poses a cosmetic problem for most pregnant women. Nowadays, many pregnant women use olive oil to prevent SG, but it is relatively difficult to find and costly. In Indonesia, a similar oil, virgin coconut oil (VCO), has been used by many pregnant women for the same reason. The aim of this study...

  3. Research on oil recovery mechanisms in heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, Anthony R.; Brigham, William E., Castanier, Louis M.

    2000-03-16

    The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties, (2) in-situ combustion, (3) additives to improve mobility control, (4) reservoir definition, and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx.

  4. Olive oil and cancer

    Directory of Open Access Journals (Sweden)

    Muriana, Francisco J.G.

    2004-03-01

    Full Text Available In the last years, numerous studies have examined the association of dietary fat and cancer. Polyunsaturated fatty acids (PUFA from n -6 family display a strong promoting effect, this may be partially due to the especially prone to lipid peroxidation of PUFA that leads to formation of aldehydes, which react with DNA bases, forming genotoxic exocyclic etheno(epsilon-adducts. On the contrary, there are growing evidences that monounsaturated oils, like olive oil, may be associated with a decreased risk of some cancers. However, the epidemiological data do not fully agree with the experimental ones previously published. Minor compounds from (extra virgin olive oil, mainly phenolics like hydroxytyrosol and tocopherol, are antioxidants and radical scavenging. They can minimize the amount of reactive oxygen species (ROS generated by fatty acid peroxidation and in the case of monounsaturated fatty acids (MUFA the DNA damage can be reduced by a lower lipid peroxidation.Numerosos estudios en los últimos años han determinado la existencia de una asociación entre las grasas procedentes de la dieta y el cáncer. Los ácidos grasos poliinsaturados (PUFA de la familia n -6 pueden tener efectos proliferativos y angiogénicos, lo cual se debe en parte a que son especialmente sensibles a la peroxidación lipídica, formándose aldehídos que reaccionan con las bases del ADN y por lo tanto aductos exocíclicos con propiedades genotóxicas. Por el contrario, el consumo de dietas ricas en ácidos grasos monoinsaturados (MUFA está relacionado con un menor riesgo de distintos tipos de cáncer. Si bien, los datos epidemiológicos no siempre concuerdan con los datos experimentales. Los componentes menores del aceite de oliva (extra virgen, fundamentalmente el hidroxitirosol y tocoferol, son antioxidantes y secuestradores de radicales libres. Pueden minimizar la cantidad de especies reactivas de oxígeno que se generan por la peroxidación lipídica y además los

  5. Biodiesel production from palm oil

    Directory of Open Access Journals (Sweden)

    Kiatsimkul, P.

    2001-11-01

    Full Text Available Methyl ester was produced from many sources of oil palm products, namely used frying oil, RBD palm oil, degummed and deacidified palm oil, palm stearin and superhard palm stearin. Production process was a conventional transesterification batch process using methanol as reactant and sodium hydroxide as catalyst. Production procedure consisted of oil preparation, solvent preparation, reaction step, glycerol separation, washing step and finishing step. Thin layer chromatograph was used to determine the composition of product and nearly 100% methyl ester was obtained at a suitable condition. Molar ratio of oil: methanol was about 1:6, which equal to 20% by weight of methanol. Sodium hydroxide was 0.5-1 %wt. of oil. The production temperature was 60-80ºC, mixing time was only 15-30 minutes and reaction time was 3-4 hours. Many fuel properties of methyl ester were very close to high-speed diesel such as viscosity, density, heating value and boiling point range. Pour point of methyl ester was higher than diesel owing to the high composition of saturated methyl ester that has a high melting point.

  6. Agricultural waste derived fuel from oil meal and waste cooking oil.

    Science.gov (United States)

    Chang, Fang-Chih; Tsai, Ming-Jer; Ko, Chun-Han

    2017-05-27

    Oil meal is a by-product of the oil industry (peanut meal, sesame meal, and camellia meal). Oil is extracted from seeds, and the leftover meal is then pelletized, and this process generates a large amount of waste oil meal in Taiwan. In this study, peanut meal, sesame meal, and camellia meal derived fuels were prepared from the waste oil meal with waste cooking oil. The combustion behaviors of the oil meal derived fuels were also investigated. The characteristics of the derived fuel made from oil meal with waste cooking oil showed that the ash content is less than 10% and its calorific value reached 5000 kcal/kg. Additionally, the activation energy of the oil meal and waste cooking oil was analyzed by the Kissinger method. The results show that the fuel prepared in this work from the oil meal mixed with waste cooking oil is suitable for use as an alternative fuel and also avoids food safety issues.

  7. Global Trends and Development Prospects for Oil and the Oil Products Market

    Directory of Open Access Journals (Sweden)

    Maria Dorozhkina

    2006-03-01

    Full Text Available This article discusses the important issue of the development of the global market of oil and oil products. It offers an overview of how this market was formed and its current status, classification, location and potential of countries in the oil and oil processing business. It analyzes the Ukrainian oil products market. The article discusses the shortcomings and strategic areas for the development of Ukraine’s oil transport system. It presents an optimum method for creating integration groups in order to develop the oil processing business in Ukraine for the future. The article considers the main trends and outlines development prospects for the global oil and oil products market.

  8. The economics of oil definitions: the case of Canada's oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, D.B. [University of Alaska Fairbanks (United States). School of Management, Department of Economics

    2005-03-01

    Canada has chosen to define its 174 billion barrels of oil sand bitumen reserves as crude oil deposits, putting the country on a par with Saudi Arabia in potential oil production. However, the physical and economic definition of calling oil sand bitumen crude oil needs to be questioned. On the face of it, these definitions make Canada look as powerful as OPEC's leading producer, or Russia, on the world oil market. However, a fuller analysis shows that Canadian oil sand is quite different from crude oil and that Canada will have little if any effect on the global oil market, or on OPEC. (author)

  9. Oil-free transportation

    Science.gov (United States)

    Lovins, Amory B.

    2015-03-01

    Automotive efficiency can be cost-effectively improved ˜2-3× by integrated reductions in mass, drag, and rolling resistance. (Mass is the key because it causes two-thirds of tractive load.) These improvements make affordable a variety of electrified advanced powertrain options that can raise efficiency by a further ˜2×, achieving ˜1-2 L-gasoline-equivalent per 100 km. These innovations are starting to enter the market. They could spread more by competition than by regulation. So will 3× gains in truck and 3-6× gains in airplane efficiency. Such superefficient vehicles can profitably eliminate oil use and decouple mobility from climate change and pollution.

  10. Maglev crude oil pipeline

    Science.gov (United States)

    Knolle, Ernst G.

    1994-05-01

    This maglev crude oil pipeline consists of two conduits guiding an endless stream of long containers. One conduit carries loaded containers and the other empty returns. The containers are levitated by permanent magnets in repulsion and propelled by stationary linear induction motors. The containers are linked to each other in a manner that allows them, while in continuous motion, to be folded into side by side position at loading and unloading points. This folding causes a speed reduction in proportion to the ratio of container diameter to container length. While in side by side position, containers are opened at their ends to be filled or emptied. Container size and speed are elected to produce a desired carrying capacity.

  11. Manitoba 2004 oil activity review

    Energy Technology Data Exchange (ETDEWEB)

    Fox, J.N. [Manitoba Industry, Economic Development and Mines, Winnipeg, MB (Canada)

    2005-07-01

    This paper presented data on oil and gas activities in Manitoba during 2004, the busiest year in Manitoba's oil patch since the mid 1980s. Increases in the leasing of Crown and freehold acreage were also noted, with accompanying increases in drilling activity for the latter part of 2004. Details of Crown land sales were presented, with a total of 43,725 hectares of crown oil and gas rights under lease. During 2004, over 15,000 hectares of Crown oil and gas leases were sold, the highest figures since 1997. More wells were licensed and drilled in 2004 than in any year since 1986. Overall drilling success rate was 96.7 per cent. Details of top drillers in Manitoba were presented, with drilling activity focused in Waskada and Daly fields and the Sinclair area. Oil production increased by 0.7 per cent, with 1474 wells in production. Daily oil production statistics were presented, with the total value of Manitoba's oil production being $196 million. Details of the top 5 producers were provided, in addition to details of horizontal well production. Recent developments in Sinclair Field, Pierson L. Amaranth MC 3b A Pool, Waskada L. Amaranth I Pool and Virden Lodgepole D Pool were reviewed. The Manitoba Drilling Incentive Program was discussed with reference to the following enhancements: new well incentives, horizontal well incentives; holiday oil volume accounts; and marginal well major workover programs. Various Oil and Gas Act amendments were reviewed. In addition, the Williston Basin Architecture and Hydrocarbon Potential Project was discussed. 3 figs.

  12. Cheap oil. Good news - for most

    NARCIS (Netherlands)

    Lorié, J.

    2014-01-01

    - The oil price has fallen by 40% in recent months, as a result of increasing oil supply, and is expected to be in the range of USD 70 - 80 per barrel in 2015. - The global economy is set to benefit, as are oil importing regions such as Europe and Asia. - Oil exporting countries like Brazil, Russia

  13. 14 CFR 27.1013 - Oil tanks.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil tanks. 27.1013 Section 27.1013... STANDARDS: NORMAL CATEGORY ROTORCRAFT Powerplant Oil System § 27.1013 Oil tanks. Each oil tank must be... space of not less than the greater of 10 percent of the tank capacity or 0.5 gallon, and where used...

  14. 49 CFR 230.116 - Oil tanks.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Oil tanks. 230.116 Section 230.116 Transportation... Locomotive Tanks § 230.116 Oil tanks. The oil tanks on oil burning steam locomotives shall be maintained free... adjacent to the fuel supply tank or in another safe location; (b) Closes automatically when tripped...

  15. 14 CFR 23.1013 - Oil tanks.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil tanks. 23.1013 Section 23.1013... tanks. (a) Installation. Each oil tank must be installed to— (1) Meet the requirements of § 23.967 (a...) Expansion space. Oil tank expansion space must be provided so that— (1) Each oil tank used with...

  16. 21 CFR 573.680 - Mineral oil.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Mineral oil. 573.680 Section 573.680 Food and... Listing § 573.680 Mineral oil. Mineral oil may be safely used in animal feed, subject to the provisions of this section. (a) Mineral oil, for the purpose of this section, is that complying with the...

  17. Crude Oil Stockpiling Needed in China

    Institute of Scientific and Technical Information of China (English)

    Fu Bin

    1997-01-01

    @@ The two oil crises in the 1970's had badly disturbed the economy and the way of life of those oil importing countries, which began to realize the importance of oil stockpiling. With the rapid development of economy, China could no longer satisfy itself soly with the domesticallyproduced oil.

  18. Fire and explosion hazards of oil shale

    Energy Technology Data Exchange (ETDEWEB)

    1989-01-01

    The US Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles. 10 refs., 54 figs., 29 tabs.

  19. Immiscible foam for enhancing oil recovery

    NARCIS (Netherlands)

    Simjoo, M.

    2012-01-01

    Growing worldwide oil demand increased the need of new and efficient oil recovery methods. Gas injection in oil reservoirs is deemed one of the most widely used methods to increase oil recovery. However, the full potential of gas injection is often not realized due to poor vertical and areal sweep e

  20. 14 CFR 125.137 - Oil valves.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Oil valves. 125.137 Section 125.137....137 Oil valves. (a) Each oil valve must— (1) Comply with § 125.155; (2) Have positive stops or... the valve. (b) The closing of an oil shutoff means must not prevent feathering the propeller,...

  1. 7 CFR 985.58 - Exempt oil.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Exempt oil. 985.58 Section 985.58 Agriculture... HANDLING OF SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Volume Limitations § 985.58 Exempt oil. Oil held by a producer or handler on the effective date of this subpart shall not...

  2. 7 CFR 985.56 - Excess oil.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Excess oil. 985.56 Section 985.56 Agriculture... HANDLING OF SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Volume Limitations § 985.56 Excess oil. Oil of any class in excess of a producer's applicable annual allotment shall be identified...

  3. Fire and explosion hazards of oil shale

    Energy Technology Data Exchange (ETDEWEB)

    1989-01-01

    The US Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles. 10 refs., 54 figs., 29 tabs.

  4. Immiscible foam for enhancing oil recovery

    NARCIS (Netherlands)

    Simjoo, M.

    2012-01-01

    Growing worldwide oil demand increased the need of new and efficient oil recovery methods. Gas injection in oil reservoirs is deemed one of the most widely used methods to increase oil recovery. However, the full potential of gas injection is often not realized due to poor vertical and areal sweep e

  5. 21 CFR 102.37 - Mixtures of edible fat or oil and olive oil.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Mixtures of edible fat or oil and olive oil. 102... for Specific Nonstandardized Foods § 102.37 Mixtures of edible fat or oil and olive oil. The common or... olive oil shall be as follows: (a) A descriptive name for the product meeting the requirements of § 102...

  6. 75 FR 22363 - United States Standards for Grades of Olive Oil and Olive-Pomace Oil

    Science.gov (United States)

    2010-04-28

    ... Agricultural Marketing Service United States Standards for Grades of Olive Oil and Olive-Pomace Oil AGENCY... Department of Agriculture (USDA) is revising the United States Standards for Grades of Olive Oil. This... the grades of olive oil and olive-pomace oil commonly accepted in the United States and abroad....

  7. Running Out Of and Into Oil. Analyzing Global Oil Depletion and Transition Through 2050

    Energy Technology Data Exchange (ETDEWEB)

    Greene, David L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hopson, Janet L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Li, Jia [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2003-10-01

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value.

  8. Effect Supermint oil (Peppermint oil on children's pain during Colonoscopy

    Directory of Open Access Journals (Sweden)

    M Najafi

    2014-04-01

    Full Text Available Introduction: Pain during colonoscopy, especially in children, including the challenges faced by the medical team. The aim of study was investigation the analgesic effect Supermint oil (peppermint oil on pain in children during colonoscopy. Methods and Materials: In this clinical trial study, 101 children (7-14 years old candidate colonoscopy were randomly divided into two groups, respectively. About half an hour before the colonoscopy case group (n=51 was administrated oral drops Supermint oil (peppermint oil. Patients were filled a pediatric pain questionnaire. In control group (n=50 filled a questionnaire without any administration. Data were analyzed using SPSS version 11.5 and (T-test and Paired sample t-test, Corraletion,Man withney. Results: Mean value of pain, duration of colonoscopy in control group was 5/60+1/85 and in case group was 4/20+1/70 and this diference was significant (P

  9. Deepwater Horizon MC252 - Oil Spill: Oil Trajectories Maps

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Trajectory maps are produced using GNOME (General NOAA Operational Modeling Environment), which is an oil spill trajectory model developed by OR and academic...

  10. Physicochemical Evaluation of Seeds and Oil of Nontraditional Oil Seeds

    Directory of Open Access Journals (Sweden)

    Adam Ismail Ahmed

    2015-08-01

    Full Text Available The present work was conducted in the Laboratory of Biochemistry and Food science department, Faculty of Natural Resources and Environmental Studies, University of Kordofan, in order to evaluate some nontraditional oil seeds these are i.e. Marula (Sclerocarya birrea, Roselle (Hibiscus sabdariffa L. seeds and Christ’s thorn (Zizyphus spina-christi seeds. The seeds of the roselle and Christ’s thorn fruits were procured from Elobeid local market, North Kordofan State, while marula fruits were obtained from Elnuhod, West Kordofan State. The proximate composition of the seeds, cake and christ’s thorn pulp was done. Some chemical and physical properties were performed for the extracted oil. The results revealed that proximate composition of the seeds and cake differ statistically among the studied materials. Significant differences were observed among the oil extracted from these species; moreover, these oils differ significantly in color and viscosity only.

  11. Aerogel Microparticles from Oil-in-Oil Emulsion Systems.

    Science.gov (United States)

    Gu, Senlong; Zhai, Chunhao; Jana, Sadhan C

    2016-06-01

    This paper reports preparation of polymer aerogel microparticles via sol-gel reactions inside micrometer size droplets created in an oil-in-oil emulsion system. The oil-in-oil emulsion system is obtained by dispersing in cyclohexane the droplets of the sols of polybenzoxazine (PBZ) or polyimide (PI) prepared in dimethylformamide. The sol droplets transform into harder gel microparticles due to sol-gel reactions. Finally, the aerogel microparticles are recovered using supercritical drying of the gel microparticles. The PBZ and PI aerogel microparticles prepared in this manner show mean diameter 32.7 and 40.0 μm, respectively, mesoporous internal structures, and surface area 55.4 and 512.0 m(2)/g, respectively. Carbonization of PBZ aerogel microparticles maintains the mesoporous internal structures but yields narrower pore size distribution.

  12. 27 CFR 21.98 - Bone oil (Dipple's oil).

    Science.gov (United States)

    2010-04-01

    ... hydrochloric acid, into 10 ml of the 0.025 percent bone oil solution. After a few minutes the splinter should..., DEPARTMENT OF THE TREASURY LIQUORS FORMULAS FOR DENATURED ALCOHOL AND RUM Specifications for Denaturants § 21...

  13. North American oil demand outlook

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, M.B. [National Economic Research Associates, White Plains, NY (United States)

    1995-11-01

    An understanding of the relationship of economic growth and potential petroleum product demand is needed to forecast the potential for North American oil demand growth as well as knowledge of world supply and price. The bullish expectations for economic growth in the US and Canada auger well for North American refiners and marketeers. The growth in world economic output forecast, however, means a larger oil demand and an increase in OPEC`s pricing power. Such price increases could depress North American oil demand growth. (author)

  14. A new paradigm for oil?

    Energy Technology Data Exchange (ETDEWEB)

    Noel, P

    2004-09-15

    The author takes stock on the dynamic of the oil system. He shows how the economic laws can be applied to the petroleum market and analyzes the effects of the prices evolution. The creeping oil shock of 2003-2004 has proven less disruptive than one may have anticipated. Commodity cycles on the one hand the shaky management of marginal supply by OPEC on the other hand, are very likely to create ample prices swings with little relations, if any, to the actual scarcity-or lack thereof-of oil resources. (A.L.B.)

  15. Methanogenic Oil Degradation in the Dagang Oil Field

    Science.gov (United States)

    Jiménez, Núria; Cai, Minmin; Straaten, Nontje; Yao, Jun; Richnow, Hans Hermann; Krüger, Martin

    2014-05-01

    Anaerobic biodegradation is one of the main in situ oil transformation processes in subsurface oil reservoirs. Recent studies have provided evidence of biodegradation of residual oil constituents under methanogenic conditions. Methane, like other biogenic gases, may contribute to reduce the viscosity of oil and enhance its flow characteristics (making it more available) but it can also be used as a energy source. So the aim of the present study was to provide reliable information on in situ biotransformation of oil under methanogenic conditions, and to assess the feasibility of implementing a MEOR strategy at this site. For this reason, chemical and isotopic analyses of injection and production fluids of the Dagang oil field (Hebei province, China) were performed. Microbial abundances were assessed by qPCR, and clone libraries were performed to study the diversity. In addition, microcosms with either oil or 13C-labelled hydrocarbons were inoculated with injection or production waters to characterize microbial processes in vitro. Geochemical and isotopic data were consistent with in situ biogenic methane production linked to aliphatic and aromatic hydrocarbon degradation: GC-MS profiles of petroleum samples were nearly devoid of n-alkanes, linear alkylbenzenes, and alkyltoluenes, and light PAH, confirming that Dagang oil is mostly highly weathered. In addition, carbon and hydrogen isotopic signatures of methane (δ13CCH4 and δDCH4, respectively), and the bulk isotopic discrimination (Δδ13C) between methane and CO2 (between 32 and 65 ) were in accordance with previously reported values for methane formation during hydrocarbon degradation. Furthermore, methane-producing Archaea and hydrocarbon-degrading Bacteria were abundant in produced oil-water samples. On the other hand, our laboratory degradation experiments revealed that autochthonous microbiota are capable of significantly degrade oil within several months, with biodegradation patterns resembling those

  16. Sustainability in the Malaysian palm oil industry

    OpenAIRE

    Choong, CG; McKay, A

    2014-01-01

    With a rapidly growing world population, the demand for palm oil is increasing. In 2010, palm oil accounted for 36.5% of the world's vegetable oil production and it is projected to be the leading vegetable oil in the world by 2016. As the Malaysian palm oil industry is committed to delivering sustainable palm oil products to meet customer demand, this research was to enable identification and prioritisation of areas for improvement. As an example, the Roadmap of Malaysian Palm Oil Industry 20...

  17. China's Oil Imports and Exports in 2008

    Institute of Scientific and Technical Information of China (English)

    Tian Chunrong

    2009-01-01

    @@ The net imports of oil,including crude oil,refined oil,LPG and other oil products,increased by 9.5% in 2008 and rose to 200.67 million tons from 183.28 million tons in 2007 (Fig.1,Fig.2).The net imports of crude oil reached 175.16 million tons,up by 9.9%.According to the statistics of State Customs Administration,the net imports of oil products,including gasoline,kerosene,diesel and fuel oil increased by 19.4% and rose to 21.84 million tons.

  18. China's quest for oil security: oil (wars) in the pipeline?

    OpenAIRE

    Lee, Pak K.

    2005-01-01

    China's rapidly expanding demand for crude oil in the 1990s has brought about debates about the potential impact of the energy challenges facing China. Within the country, energy as a security issue has seized the attention of its leaders. Outside China, international strategic thinkers have been arguing among themselves over how China's thirst for oil would impact on regional peace and stability.\\ud \\ud This paper sets out to examine the following questions: How and why has the basic need fo...

  19. China's Oil Giants Benefited from High Oil Price

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ High crude prices and strong local demand boosted the profits of China's oil sector in the year's first half, but government-capped petrol prices, cooling economic growth and rising costs threaten future earnings. State-owned big-three oil companies - PetroChina, Sinopec Corp and CNOOC Ltd - posted net profit increases ranging from 11 percent to 48 percent for the first six months of this year.

  20. National Oil Companies and the Future of the Oil Industry

    OpenAIRE

    Victor, David G.

    2013-01-01

    Ever since the 1970s, a small number of national oil companies (NOCs) have dominated the world supply of oil and other hydrocarbons. Despite the huge influence that NOCs have on political economy, systematic scholarship remains surprisingly thin. I examine the factors that explain the wide variation in the strategy and performance of NOCs and survey the literature that has suggested the many ways in which NOCs play pivotal political and economic roles in resource-rich countries. As we look to...

  1. Calorimetry for Fast Authentication of Edible Oils

    Science.gov (United States)

    Angiuli, Marco; Bussolino, Gian Carlo; Ferrari, Carlo; Matteoli, Enrico; Righetti, Maria Cristina; Salvetti, Giuseppe; Tombari, Elpidio

    2009-06-01

    There are little data in the literature on how to authenticate edible oils through calorimetry techniques. However, oil melting curves can be used to represent correlations between calorimetric results and oil quality. A calorimetric method has been developed for studying the solid-liquid phase transitions of olive oil and seed oils, in which melting peak behavior is correlated to the type, quality, and composition of the oil. Good reproducible thermograms were obtained by defining precise protocols for use in testing, which take into account the specific characteristics of a particular oil. This approach does not replace classical analytical methods; nevertheless, it is believed that calorimetric tests could be a useful preliminary stage for quality testing. The calorimetric technique allows the detection of the adulterant (seed oils or refined olive oil), oil origin, and possible photo-oxidation degradation processes, before more complex and expensive procedures and analyses are applied.

  2. Efek Olive Oil dan Virgin Coconut Oil terhadap Striae Gravidarum

    Directory of Open Access Journals (Sweden)

    Evi Pratami

    2014-03-01

    Full Text Available The prevalence of striae gravidarum (SG in pregnant women ranges from 50% to 90%. Effects of SG include itchy and hot feeling as well as dry skin. This situation also causes emotional disturbances that poses a cosmetic problem for most pregnant women. Nowadays, many pregnant women use olive oil to prevent SG, but it is relatively difficult to find and costly. In Indonesia, a similar oil, virgin coconut oil (VCO, has been used by many pregnant women for the same reason. The aim of this study was to analyze the differences and correlation between effects of olive oil and VCO against SG. The study was conducted in March−July 2012. An experimental study was performed on 80 pregnant women in Surabaya Municipality and they were divided into 2 groups using random permuted blocks. The results of this study showed that there was no difference in SG appearance based on the number of lines and levels of erythema between groups (p=0.156 and 1.00. Furthermore, there was a strong negative correlation between the effect of olive oil or VCO on the number of lines (r=-0.576 and -0.560 and the level of erythema (r=-0.699 and -0.586. In conclusion, there is no difference in the effect of olive oil and VCO against SG.

  3. Oil flow in deep waters: comparative study between light oils and heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Andreolli, Ivanilto [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2009-12-19

    Ultra deeper waters fields are being exploited due to technological development. Under this scenario, the flow design is accomplished through pipelines subjected to low temperature and high pressure. Moreover, these flow lines are usually long causing a fast fluid cooling, which may affect flow assurance in some cases. Problems during topsides production plant's restart might occur if the oil is viscous and even in steady state a significant different behavior can be noticed, if compared to a less viscous oil. A comparison between light and heavy oil through a case study with the objective to show some heavy oil flow particularities is the purpose of this paper. Permanent and transient analyses for a specific geometry are presented. The results showed that thermal and proper viscosity modeling are required for heavy oil flow, differently from that of light oil flow, due to the exponential viscosity dependence to temperature and because the predominant laminar regime. In addition, on heavier and heavier oil flow systems, it is essential to consider exportation system's restart. (author)

  4. Huge Oil Spill off North China Coast

    Institute of Scientific and Technical Information of China (English)

    Yu Xiaojie

    2011-01-01

    ConocoPhillips China, a subsidiary of the US oil giant, operates an oilfield in Bohai Bay in partnership with Chinese offshore oil producer China National Offshore Oil Company (CNOOC), where a massive oil slick was detected on June 4 this year. The spill from the oilfield, which the United States' ConocoPhillips operates with China's state-run oil giant CNOOC, has polluted a total area of almost 4,250 square kilometers. The figures,

  5. Oil price shocks and stock market activity

    Energy Technology Data Exchange (ETDEWEB)

    Sadorsky, P. [Schulich School of Business, York University, Toronto, ON (Canada)

    1999-10-01

    Results from a vector autoregression show that oil prices and oil price volatility both play important roles in affecting real stock returns. There is evidence that oil price dynamics have changed. After 1986, oil price movements explain a larger fraction of the forecast error variance in real stock returns than do interest rates. There is also evidence that oil price volatility shocks have asymmetric effects on the economy. 29 refs.

  6. Preparation of function-enhanced vegetable oils

    OpenAIRE

    Hiroshi Maeda; Takao Satoh; Waliul Islam

    2016-01-01

    Background: Previously, we (HM) found that most commercially available edible oils, which were processed by hexane extraction followed by a number of purification steps, were extremely low in anti-peroxy radical (ROO.), or radical scavenging activity. This is a great contrast to the respective virgin oils as exemplified by extra-virgin olive oil or crude rape seed oil [1-4] (Figure 1). Therefore, such highly purified oils will became prooxidant and less desirable food components in terms of...

  7. West African Oil: Will It Make a Difference?

    Science.gov (United States)

    1982-12-01

    Crude Oil Production --------------------- 21 2. Cameroon’s Oil Production ------------------------ 30 3. Congolese Crude Oil Production ------------------- 39...4. Gabon: Crude Oil Production , 1980 and 1981 ------ 47 5. Nigerian Crude Oil Production -------------------- 67 6. Nigeria’s 1981 Crude ... Oil Production -------------- 69 7. Zairian Crude Oil Production

  8. Oil for development 2009

    Energy Technology Data Exchange (ETDEWEB)

    2010-09-15

    In this report present key achievements for each of the various cooperation countries. Oil for Development (OfD) assistance has been important for the ability of a country like Ghana to improve petroleum resource management on its most important oil and gas field, and to better safeguard that the petroleum activities are conducted in an environmentally sustainable way. Competence building on Increased Oil Recovery (IOR), and negotiation training have helped to increase both the resource extraction potential and the revenue generation potential of a more mature oil producing country like Iraq. Furthermore, OfD has contributed to improving the legislative frameworks in several of our cooperating countries, including Afghanistan, Cambodia and Madagascar, although it will take time before we can assess to what extent the laws have been implemented. OfD's strong focus on providing legal assistance reflects our belief that clear divisions of roles and firm legal mandates are prerequisites for good governance of the petroleum sector and for attracting serious investors. A lot of our capacity building took place through seminars and more tailored workshops with a national or regional scope. We believe that some of these events have significantly increased awareness as well as the level of debate among government institutions and civil society. The oil production accounting workshop in Nigeria and the NOC workshop in Timor-Leste are particularly valid examples. Timor-Leste also addressed other petroleum sector governance issues with a focus on including civil society and by the end of 2009 had nearly fulfilled all criteria for becoming Extractive Industries Transparency Initiative (EITI) compliant. It should be noted that OfD assistance only made a relatively small contribution to this process, which was very much nationally driven. Petroleum related environmental issues were addressed at different levels and from different angles. A thorough environmental needs

  9. Oil additive and its effect

    Directory of Open Access Journals (Sweden)

    Vojtěch Kumbár

    2013-01-01

    Full Text Available The aim of this paper are experimental approaches, selected for analysis of the engine oils and described above, are surely sufficient for the needs of presented research. The spectrometry was used for determination of presence of selected chemical elements and especially metals in oil. Particles monitoring was employed in order to describe the amount, type, and size of friction particles. The temperature dependence of dynamic viscosity was evaluated by use of rotary viscometer. In case of all three approaches it is advantageous to compare the measured values with the results received for unused engine oil of the same marking and viscosity index. If the degradation of oil is classified as low or medium, it is possible to increase its service life for several thousands of kilometers. Mathematical model (polynomial 6th degree it was used for fitting experimental values.

  10. Recycling used automotive oil filters

    Science.gov (United States)

    Peaslee, Kent D.

    1994-02-01

    Over 400 million used automotive oil filters are discarded in the United States each year, most of which are disposed of in landfills wasting valuable resources and risking contamination of ground- and surface-water supplies. This article summarizes U.S. bureau of Mines research evaluating scrap prepared from used automotive oil filters. Experimental results show that crushed and drained oil filters have a bulk density that is higher than many typical scrap grades, a chemical analysis low in residual elements (except tin due to use of tin plate in filters), and an overall yield, oil-filter scrap to cast steel, of 76% to 85%, depending on the method used to prepare the scrap.

  11. Viscoelastic properties of heavy oils

    Science.gov (United States)

    Rojas Luces, Maria Alejandra

    Rheological low frequency measurements were carried out to analyze the viscoelastic properties of four heavy oil samples. At room conditions, the heavy oil samples exhibit non-Newtonian or viscoelastic behavior since they have a viscous component and an elastic component. The latter becomes very important for temperatures below 30°C, and for seismic to ultrasonic frequencies. Above this temperature, the viscous component increases significantly in comparison to the elastic component, and for seismic frequencies heavy oils can be considered as Newtonian fluids. A new viscosity model based on the concept of activation energy was derived to predict viscosity in terms of frequency and temperature for temperatures below 60°C. A new frequency-temperature dispersion model was derived to address the variation of the complex shear modulus (G*) with frequency and temperature for the heavy oil samples. This model fits the data well for seismic and sonic frequencies but it overpredicts G* at ultrasonic frequencies.

  12. Oil Paintings by Ou Yang

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Ou Yang, professor of the Oil Painting Department of Guangdong Art College, has been pursuing perfection in the field of art for many years. With their rich emotional color, paintings by her do not simply

  13. Extracting oil using carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Torok, J.

    1984-01-01

    Special literature is the basis for a brief characterization of a method for extracting oil using CO2 and for generalizing the basic results of physical and chemical experiments, as well as displacement experiments conducted in laboratory conditions.

  14. Preventing Rancidity in sunflower Oil

    African Journals Online (AJOL)

    used in turn to extract the polar flavonoids, while chilled acetone and petroleum ether ... sunflower oil was measured using changes in peroxide values and the UV absorbances (Conjugated diene) .... metal ions and metalloprotein catalysts.

  15. Remote sensing of oil slicks

    Digital Repository Service at National Institute of Oceanography (India)

    Fondekar, S.P.; Rao, L.V.G.

    the drawback of expensive conventional surveying methods. An airborne remote sensing system used for monitoring and surveillance of oil comprises different sensors such as side-looking airborne radar, synthetic aperture radar, infrared/ultraviolet line scanner...

  16. 2010 oil sands performance report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    With the depletion of traditional energy resources and the rising demand for energy, oil sands have become an important energy resource for meeting energy needs. Oil sands are a mixture of water, sand, clay and bitumen which is recovered either through open pit mining or in situ drilling techniques. The bitumen is then converted into syncrude or sold to refineries for the production of gasoline, diesel or other products. Shell has oil sands operations in Alberta and the aim of this report is to present its 2010 performance in terms of CO2, water, tailings, land, and reclamation and engagement. This document covers several of Shell's operations in the Muskeg River and Jackpine mines, Scotford upgrader, Peace River, Orion, Seal, Cliffdale and Chipmunk. It provides useful information on Shell's oil sands performance to governments, environmental groups, First Nations, local communities and the public.

  17. Oil prices and long-run risk

    Science.gov (United States)

    Ready, Robert Clayton

    I show that relative levels of aggregate consumption and personal oil consumption provide an excellent proxy for oil prices, and that high oil prices predict low future aggregate consumption growth. Motivated by these facts, I add an oil consumption good to the long-run risk model of Bansal and Yaron [2004] to study the asset pricing implications of observed changes in the dynamic interaction of consumption and oil prices. Empirically I observe that, compared to the first half of my 1987--2010 sample, oil consumption growth in the last 10 years is unresponsive to levels of oil prices, creating an decrease in the mean-reversion of oil prices, and an increase in the persistence of oil price shocks. The model implies that the change in the dynamics of oil consumption generates increased systematic risk from oil price shocks due to their increased persistence. However, persistent oil prices also act as a counterweight for shocks to expected consumption growth, with high expected growth creating high expectations of future oil prices which in turn slow down growth. The combined effect is to reduce overall consumption risk and lower the equity premium. The model also predicts that these changes affect the riskiness of of oil futures contracts, and combine to create a hump shaped term structure of oil futures, consistent with recent data.

  18. Exposure Standard for Fog Oil

    Science.gov (United States)

    1990-11-15

    18 frmmation, dermatitis, folliculitis, acne, eczema and contact sensitivity. ,’• (The term ’conventionally-refined’ is used here to describe...comparable to "new" fog oil. Of the species tested (rat, rabbit, dog , hamster and mouse), rats and dog & were most affected by the mineral oil mists (Table 3...Exposures to 100 mg/mr for one year caused pulmonary lipoid granulomas in the dog and pneumonitis in the rat. Findings of "a few fibrotic strands

  19. CYLINDER AND SYSTEM LUBRICATING OILS

    OpenAIRE

    ION ADRIAN GIRBA

    2016-01-01

    Increased thermal efficiency, savings in the fuel consumption and the possibility to burn low quality fuels conducted to an intense development of marine engines in past 20 years, this progress being emphasized by the increased combustion pressures and better combustion properties. These improvements represent a continuous challenge for lubricating oil manufacturers: the rise in combustion temperatures and pressures is making difficult to preserve the oil film in critical area...

  20. ECOLOGY AFFECTED IN OIL EXPLOITATION

    Institute of Scientific and Technical Information of China (English)

    Wang Mingren; Zeng Dezhang; Zhang Shiquan; Shi Lifeng

    1997-01-01

    @@ Introduction During the Eighth Five-Year Plan period(1991-1995), a study about crude impacts on ecology in oil exploitation was conducted in seven representative onshore oil fields of China. The study discusses crude pollutant's impacts on ecology in terms of its production,movement, transformation and concentration in the ecological system,as well as its toxicity and damage degree on living things , by means of investigation on the spot, test analysis and analogue test.