Sample records for pump wo mochiita

  1. Investigation on chemical heat pump using calcium-chloride; Enka calcium no suiwa dassui hanno wo mochiita solar chemical heat pump ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, I.; Arai, T.; Saito, Y. [Meiji University, Tokyo (Japan)


    With an objective of developing a room heating system utilizing a solar chemical heat pump, an experimental system was fabricated to evaluate its performance. Steam was employed as a working gas, and for a reaction material, calcium-chloride was used, which has a reaction temperature zone permitting safe use and fitting the purpose among other hydrate systems and has high standard enthalpy in hydration. Water was used as a solar heat transferring medium. The system operates under the following principle: a container I is filled with hydrated salt and a container II with water, the two containers being linked with a pipe interposed with a valve; heat is inputted and outputted by performing charging and discharging alternately; and the role of a heat pump is played by deriving from environment the heat of water evaporation in the container II during discharging. The COP must take into account the electric power consumption of the water circulation pump to transfer solar heat. A COP of 0.256 was derived as a result of the experiment. 3 refs., 5 figs.

  2. Forced-circulation solar water heater using a solar battery; Taiyo denchi wo mochiita kyosei junkahshiki taiyonetsu onsuiki

    Energy Technology Data Exchange (ETDEWEB)

    Asai, S.; Mizuno, T. [Yazaki Corp., Tokyo (Japan)


    Optimal operation control was discussed on a forced-circulation solar water heater using solar cells not only as the power supply of a heat collecting pump, but also for controlling operation of the heat collecting pump. With this system, when the amount of power generated by solar cells reaches a sufficient level for operating the heat collecting pump, the heat collecting pump starts operation, wherein the heat collecting medium circulates in the system. The discussion was given by using simulation based on experimental expressions such as the relation expression between insolation and heat collecting medium flow rate as derived from the result of the system`s heat collecting performance test. As a result, the following conclusions were obtained: optimal insolation for activating the discussed system is from 50 to 100 W/m {sup 2}, and the heat collected within this range is within -1.5% of the collected heat amount at an optimum value; optimal activating insolation for the case of 1000 to 2000 W/m {sup 2} with low daily cumulative insolation is from 0 to 50 W/m {sup 2}, whereas the optimal activating insolation amount increases as the daily cumulative insolation amount increases; and the optimal activating insolation amount increases as water to be supplied requires higher temperature. 1 ref., 17 figs., 2 tabs.

  3. Forced-circulation solar water heater using a solar battery; Taiyo denchi wo mochiita kyosei junkanshiki taiyonetsu onsuiki

    Energy Technology Data Exchange (ETDEWEB)

    Asai, S.; Mizuno, T. [Yazaki Resources Co. Ltd., Shizuoka (Japan)


    For the purpose of satisfying demands for qualitative improvement on tapwater temperature and pressure, an indirect-type solar water heater using solar cells, in which a closed type hot water storage tank connected directly to the water supply is integrated with a solar collector, was examined for its characteristics and performance. The heat collecting medium is a water solution of polypropylene glycol, which circulates through the solar collector pump, cistern, solar collector, and heat exchanger (hot water storage tank). The results of the test are summarized below. When comparison is made between the two solar collector pump control methods, the solar cells direct connection method and the differential thermo method utilizing temperature difference between the solar collector and the hot water storage tank, they are alike in collecting heat on clear days, but on cloudy days the latter collects 5% more than the former. In winter, when the heat exchanger heat transfer area is 0.4m{sup 2} large, a further increase in the area improves but a little the heat collecting efficiency. An increase in the medium flow rate and temperature, or in the Reynolds number, enhances the heat collecting efficiency. 13 figs., 6 tabs.

  4. End pumped yellow laser performance of Dy3+:ZnWO4 (United States)

    Xia, Zhongchao; Yang, Fugui; Qiao, Liang; Yan, Fengpo


    We report an end pumped single transverse-mode (TEM00) yellow laser based on Dy3+:ZnWO4 crystal. The pump light is InGaN blue laser diode at 450 nm with the maximum power of 1.5 W. A 3 cm length Dy3+:ZnWO4 crystal served as the gain medium. By way of the square filter, we discuss the TEM00 properties. In continuous-wave operation and single transverse-mode, a maximum output power of 0.110 W and a slope efficiency of 13.0% are achieved at an emission wavelength of 575 nm.

  5. Compact KGd(WO4)2 picosecond pulse-train synchronously pumped broadband Raman laser. (United States)

    Gao, Xiao Qiang; Long, Ming Liang; Meng, Chen


    We demonstrate an efficient approach to realizing an extra-cavity, synchronously pumped, stimulated Raman cascaded process under low repetition frequency (1 kHz) pump conditions. We also construct a compact KGd(WO4)2 (KGW) crystal picosecond Raman laser that has been configured as the developed method. A pulse-train green laser pumped the corresponding 70 mm long KGW crystal Raman cavity. The pulse train contains six pulses, about 800 ps separated, for every millisecond; thus, it can realize synchronous pumping between pump pulse and the pumped Raman cavity. The investigated system produced a collinear Raman laser output that includes six laser lines covering the 532 to 800 nm spectra. This is the first report on an all-solid-state, high-average-power picosecond collinear multi-wavelength (more than three laser components) laser to our knowledge. This method has never been reported on before in the synchronously pumped stimulated Raman scattering (SRS) realm.

  6. Indirect solar-pumped laser diode using a solar cell; Taiyo denchi wo mochiita taiyoko kansetsu reikigata handotai laser no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kanamori, Y.; Yugami, H.; Naito, H.; Arashi, H. [Tohoku University, Sendai (Japan). Faculty of Engineering


    This paper describes the operating characteristics of a stabilizing circuit using commercial electricity, those of a stabilizing circuit using solar cells, relation between the quantity of solar radiation and the maximum output of a semiconductor laser diode (LD), and simulation results of annual LD output in Sendai City. The stabilizing circuit for the solar-cell driven LD was structured such that the output of the solar cell panels was guided to a DC/DC converter, that the voltage was set at a prescribed value and that the current was stabilized with the use of power MOSFET. The solar cells used in the experiment were monocrystal silicone solar cells with the maximum output of 53W each. In the experiment, the LD was protected by stabilizing the current at a set value when an excess current was supplied to the stabilizing circuit. As a result of the simulation of the annual LD output from the meteorological data of Sendai City, it was predicted that a solar cell of approximately 1kW was able to provide an annual output of 102MJ and that the efficiency was highest with four sheets of the solar cell. Consequently, consistency proved to be essential between the LD and the solar cell output. 3 refs., 7 figs.

  7. Preparation of biodegradable microcapsules with (W/O/W) emulsion in solvent evaporation; (W/O/W) fukugo emulsion wo mochiita ekichu kansoho ni yoru seibunkaisei microcapsule no chosei

    Energy Technology Data Exchange (ETDEWEB)

    Kiyoyama, S.; Shiomori, K.; Baba, Y.; Kawano, Y. [Miyazaki University, Miyazaki (Japan). Faculty of Engineering; Yoshizawa, H.; Hatate, Y. [Kagoshima University, Kagoshima (Japan). Faculty of Engineering


    This paper describes the preparation of biodegradable microcapsules which can control the shape and size of capsules and also can control the discharge of contents. The biodegradable polymers are frequently used as medical materials, and have attracted attention as base materials for drug prescription. At first, (W/O) emulsion was prepared by dispersing an inner aqueous ascorbic acid Mg salt solution into the organic solution consisting of biodegradable poly(3HV-co-3HB) membrane material and 1,2-dichloroethane. Then, (W/O/W) emulsion was prepared by dispersing the (W/O) emulsion into the outer aqueous phase consisting of interfacial active agent and dispersion stabilizer. The biodegradable microcapsules were prepared by the solvent evaporation process including heating, evaporation of solvent by air blasting, and vacuum drying. The stability of solvent evaporation depended on the concentration of membrane material and solvent removal rate. The surface characteristics of microcapsules were not affected by the volume fraction of the inner aqueous phase during the primary emulsion, but by the solvent removal rate and dispersion stabilizer. The surface characteristics could be controlled by the solvent evaporation with considering these factors. 12 refs., 11 figs., 2 tabs.

  8. Continuous-wave Raman generation in a diode-pumped Nd3+:KGd(WO4)2 laser. (United States)

    Demidovich, A A; Grabtchikov, A S; Lisinetskii, V A; Burakevich, V N; Orlovich, V A; Kiefer, W


    Continuous-wave Raman generation in a compact solid-state laser system pumped by a multimode diode laser is demonstrated. The Stokes radiation of stimulated Raman scattering at 1.181 microm is generated as a result of self-frequency conversion of the 1.067 microm laser radiation in Nd3+:KGd(WO4)2 crystal placed in the cavity. The Raman threshold was measured at 1.15 W of laser diode power. The highest output power obtained at the Stokes wavelength was 54 mW. The anomalous delay of Raman generation relative to the start of laser generation (the oscillation buildup) due to slow accumulation of Stokes photons in the cavity at low Raman gain and Raman threshold dependence not only on the laser intensity but also on the time of laser action are observed.

  9. Preparation of spherical fine particulate pigments within water-in-oil emulsions and their properties. (II). ; Formation mechanism and characteristic of spherical fine particulate pigment of tartrazine. W/O emulsion wo mochiita kyujo biryushi ganryo no chosei to seishitsu(dai 2 ho). ; Kiiro 4 go kyujo biryushi ganryo no seisei kiko to tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Imai, T.; Iwano, K.; Hotta, H.; Takano, S.; Tsutsumi, H. (Kao Corporation, Tokyo (Japan))


    The previous report explained that an excellent spherical particulate pigment with a grain size of 0.5 mm or less can be obtained by preparing multinuclear aluminum lakes from acidic dyes and multinuclear aluminum salt using water droplets in a W/O emulsion as reaction fields. This paper describes preparing pigments varying the charging concentrations of the pigments in a W/O emulsion and the droplet particle size to discuss the mechanism of forming the pigments. As a result, it was found that the particle sizes in the produced pigments have a clear correlation with the charging concentrations of the pigments and the droplet particle sizes in the W/O emulsion. A pigment produced in the W/O emulsion forms only in its own droplets, and reflects its particle sizes. Films dispersed with pigments having different particle sizes were prepared to discuss their tinting abilities, whereas it was clarified that the smaller the particle size, the higher the tinting ability and the higher saturation in colored paint films. 6 refs., 9 figs., 3 tabs.

  10. Hybrid utilization of solar energy. Part 2. Performance analyses of heating system with air hybrid collector; Taiyo energy no hybrid riyo ni kansuru kenkyu. 2. Kuki shunetsu hybrid collector wo mochiita danbo system no seino hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Yoshinaga, M.; Okumiya, M. [Nagoya University, Nagoya (Japan)


    For the effective utilization of solar energy at houses, a heating system using an air hybrid collector (capable of simultaneously performing heat collection and photovoltaic power generation). As the specimen house, a wooden house of a total floor area of 120m{sup 2} was simulated. Collected air is fanned into a crushed stone heat accumulator (capable of storing one day`s collection) or into a living room. The output of solar cell arrays is put into a heat pump (capable of handling a maximum hourly load of 36,327kJ/h) via an inverter so as to drive the fan (corresponding to average insolation on the heat collecting plate of 10.7MJ/hm{sup 2} and heat collecting efficiency of 40%), and shortage in power if any is supplied from the system interconnection. A hybrid collector, as compared with the conventional air collector, is lower in thermal efficiency but the merit that it exhibits with respect to power generation is far greater than what is needed to counterbalance the demerit. When the hybrid system is in heating operation, there is an ideal heat cycle of collection, accumulation, and radiation when the load is light, but the balance between accumulation and radiation is disturbed when the load is heavy. 4 refs., 8 figs., 3 tabs.

  11. Injection and spray characteristics of a variable orifice nozzle applied the jerk type fuel injection pump for DI diesel engine; Jerk shiki nenryo funsha pump wo mochiita kahen funko nozzle no funsha funmu tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Hasegawa, T.; Matsui, K.; Iwasaki, T.; Kobayashi, T. [Zexel Corp., Tokyo (Japan); Matsumoto, Y. [The University of Tokyo, Tokyo (Japan)


    A Variable Orifice Nozzle (VON) by changing a cross-sectional area of the nozzle injection hole, for improving a rate of injection and injection duration, has been developed to study its injection and spray characteristics. The nozzle geometry was optimized to analyze a nozzle internal flow by computational method. Results show that, injection and spray pattern responded to the nozzle orifice cross-sectional area which is changing larger to smaller in the part load range. This results suggest to contribute a combustion improvement which decreasing NOx and soot. 14 refs., 10 figs.

  12. Efficient picosecond traveling-wave Raman conversion in a SrWO4 crystal pumped by multi-Watt MOPA lasers at 1064 nm (United States)

    Farinello, Paolo; Pirzio, Federico; Zhang, Xingyu; Petrov, Valentin; Agnesi, Antonio


    Raman conversion with a 50-mm-long SrWO4 crystal in a single-pass, traveling-wave setup has been investigated in both purely steady-state and transient stimulated Raman scattering (SRS) regimes. For steady-state SRS experiment, we employed as a pump source a Q-Switched master oscillator power amplifier (MOPA) laser system at 1064 nm, delivering 325 μJ, 550-ps-long pulses with diffraction limited beam quality and high spectral purity. At 2-kHz repetition rate, we obtained up to 90 μJ pulse energy and 250 ps pulse duration at 1180 nm, with a conversion slope efficiency close to quantum limit. To approach the transient SRS regime, we pumped the same crystal with 16-ps-long pulses from a hybrid MOPA laser system based on a mode-locked Yb-fiber oscillator followed by a diode-pumped bulk Nd:YVO4 power amplifier. At the maximum incident pump average power of 3.75 W, we obtained 1.4 W at the first Stokes Raman-shifted wavelength of 1180 nm (37 % optical-to-optical conversion efficiency), with 15 ps pulse duration and 70 % conversion slope efficiency.

  13. Low threshold Nd3+:KY(WO4)2 laser operated at 1072 nm pumped by diode

    Institute of Scientific and Technical Information of China (English)

    Lang Lin; Zhenqiang Chen; Ge Zhang; Rugang Wang; Zhen Li; Jingzhao Li


    @@ The diode-pumped Nd:KYW laser operated in the free-running mode at 1072 nm is demonstrated at room temperature. The laser output power of 102.6 mW with 12.07% optical-to-optical conversion efficiency and 13.16% slope efficiency is obtained.

  14. Performance in cooling mode of a heat pump using panels with PV cells as the condenser; Taiyo denchitsuki panel wo gyoshukuki to shita heat pump no reibo unten

    Energy Technology Data Exchange (ETDEWEB)

    Kawamura, T.; Ito, S.; Miura, N. [Kanagawa Institute of Technology, Kanagawa (Japan); Fujita, M. [Chubu Electric Power Co. Inc., Nagoya (Japan)


    Comparison was made between heat pumps in cooling operation, one having two panels provided with solar cells, the second having an air-cooled heat exchanger alone, and the third having a series connection of a panel unit and air-cooled heat exchanger, all serving as condenser. The results are shown below. In the case of two-panel-unit condenser, there is a difference ({Delta}t) of 15{degree}C between the daytime free air temperature and condensing temperature but, with decreased insolation, free air temperature, and wind speed in the evening, the {Delta}t lowered to approximately 8{degree}C while the COP (coefficient of performance) increased from 2.4 to 3.3. On a cloudy day in summer, the two-panel-unit condenser had a {Delta}t of 13.9{degree}C and a COP of 3.1. In the case of the series-connection condenser, the {Delta}t was approximately 8{degree}C and the COP was 3.5. The COP of the two-panel-unit condenser was lower than that of the air-cooled heat exchanger by 9% at an insolation of 442W/m{sup 2} but it rose to 12% in the absence of insolation. The COP of the two-panel-unit condenser was higher than that of a one-panel-unit condenser by 17%. When an insulator plate was attached to the back of a panel, the {Delta}t increased but the COP decreased by 14%. In the case of the series-connection condenser, the COP increased by 6% in the absence of the insulator plate. 2 refs., 9 figs.

  15. PUMPS (United States)

    Thornton, J.D.


    A pump is described for conveving liquids, particure it is not advisable he apparatus. The to be submerged in the liquid to be pumped, a conduit extending from the high-velocity nozzle of the injector,and means for applying a pulsating prcesure to the surface of the liquid in the conduit, whereby the surface oscillates between positions in the conduit. During the positive half- cycle of an applied pulse liquid is forced through the high velocity nozzle or jet of the injector and operates in the manner of the well known water injector and pumps liquid from the main intake to the outlet of the injector. During the negative half-cycle of the pulse liquid flows in reverse through the jet but no reverse pumping action takes place.

  16. Peltier heat flux sensor for cryogenic use; Peruchie soshi wo mochiita teion netsuryusoku sensa

    Energy Technology Data Exchange (ETDEWEB)

    Haruyama, T. [High Energy Accelerator Research Organization, Tsukuba (Japan)


    It was evaluated as cryogenic heat flux sensor, which could measure the Peltier element in In situ in thermal flux. The equipment which could proofread the thermal flux was manufactured, and on marketed several kinds general-purpose Peltier element of, the relationship between thermal flux and thermoelectromotive force at the liquid nitrogen temperature was examined. (NEDO)

  17. Inertia charging system with a rotary valve. Kaitenben wo mochiita kansei kakyu system

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, H.; Ji, D. (The University of Tokyo, Tokyo (Japan). Faculty of Engineering); Kanesaka, H.; Lee, D.


    An inertia charger which is used to raise the output of an internal combustion engine can raise the volumetric efficiency by using the dynamic effect of intake air vibration which takes place in the intake system during the intake process. This paper described the trial manufacturing of an inertia charging system aiming at the high volumetric efficiency by arranging the rotary valve in the intake passage and by adjusting the operating time of the rotary valve and the studied result to improve the effect of inertia charging over the wide range of engine rotational speed. The experimental equipment was a 399cc single cylinder gasoline engine for a bicycle to which intake port a rotary valve was fitted. The engine number of rotation, volumetric efficiency, crank angle and the pressure change near the rotary valve were studied. As a result, the aerofoil rotary valve could improve the volumetric efficiency over a wide range of engine number of rotation, compared with the conventional inertia charging system. The optimized calculation result by which the future expansion of this system was studied, was shown. 3 refs., 4 figs., 3 tabs.

  18. Measurement of sediments thickness by ground penetrating radar; Denjihaho wo mochiita kotei taisekibutsu soatsu no sokutei

    Energy Technology Data Exchange (ETDEWEB)

    Nozawa, E. [Tokyo Electric Power Co. Inc., Tokyo (Japan); Inagaki, M.


    An attempt was made to measure thickness of a layer of reservoir bottom sediments by utilizing the electromagnetic reflection method. Because water is a substance difficult for electromagnetic waves to permeate, considerations were given on to suppress attenuation to a minimum, and improve receiving sensitivity. The test used monocycle pulses with a central frequency of 200 MHz. In order to generate stabilized pulses with little unnecessary reflection, an antenna as large as it can be fitted into a rubber boat was employed. In order to acquire referential data, the test was carried out by using simultaneously a sound wave exploration device. The lake at which the test was carried out is a regulating reservoir with a size of about 250 m {times} 150 m, with its bottom made of concrete slab. This means that the lake consists of a three-layer structure comprising water, soil deposits, and concrete bottom from the water surface. According to an example of acquired electromagnetic exploration records, boundary reflection of water and sediments was observed clearly at water depths of 2 to 3 m as a shallow portion and 5 to 6 m as a deep portion. Reflection between the sediments and the bottom plate was also observed sufficiently distinctly. 3 refs., 8 figs.

  19. High resolution resistivity profiling using STRATAGEM system; Stratagem wo mochiita kobunkainohi teiko kozo tansarei

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, K.; Inoue, J.; Takasugi, S. [GERD Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Inazaki, T. [Public Works Research Institute, Tsukuba (Japan)


    A tensor type CSMT method (STRATAGEM) was introduced for the purpose of investigating shallow subsurface, and a field test has been carried out thereon. This system consists of a transmission section, and a sensor section and a data acquisition and processing section to observe waveforms in a responsive electromagnetic field. The signal source is a semi-circular air loop with a radius of a little smaller than 2 m. The measuring points were selected at locations about 200 m apart from the signal source to measure two electric field components and two magnetic field components by using sensors installed on the ground surface. The field test was performed at the Yutsubo area in Oita Prefecture, Japan. The electric field dipole is basically 5 m long, while S and E lines are 10 m long. The measurement frequency ranges from 96 kHz to 1000 kHz. The measurement time was about five minutes, and the whole measurement work including apparatus set-up and withdrawal was completed in about 15 minutes to minimize interference with the field which is a meadow. The field test result revealed that resistivity profile in shallow subsurface can be obtained much more easily than with the conventional CSMT method. 2 refs., 10 figs.

  20. Estimation of fracture aperture using simulation technique; Simulation wo mochiita fracture kaiko haba no suitei

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, T. [Geological Survey of Japan, Tsukuba (Japan); Abe, M. [Tohoku University, Sendai (Japan). Faculty of Engineering


    Characteristics of amplitude variation around fractures have been investigated using simulation technique in the case changing the fracture aperture. Four models were used. The model-1 was a fracture model having a horizontal fracture at Z=0. For the model-2, the fracture was replaced by a group of small fractures. The model-3 had an extended borehole diameter at Z=0 in a shape of wedge. The model-4 had a low velocity layer at Z=0. The maximum amplitude was compared each other for each depth and for each model. For the model-1, the amplitude became larger at the depth of the fracture, and became smaller above the fracture. For the model-2, when the cross width D increased to 4 cm, the amplitude approached to that of the model-1. For the model-3 having extended borehole diameter, when the extension of borehole diameter ranged between 1 cm and 2 cm, the change of amplitude was hardly observed above and below the fracture. However, when the extension of borehole diameter was 4 cm, the amplitude became smaller above the extension part of borehole. 3 refs., 4 figs., 1 tab.

  1. Trial to active seismic while drilling; Jinko shingen wo mochiita SWD eno kokoromi

    Energy Technology Data Exchange (ETDEWEB)

    Tsuru, T.; Kozawa, T. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center


    This paper describes the development of a more stable SWD system with larger energy by adding an artificial seismic source near the bit. SWD is a technique by which the seismic wave generated while drilling of rocks by bit can be observed on the ground surface and the records equivalent to the reverse VSP can be obtained. For this system, a shell with a vibrator was fixed immediately on the bit as a sub-generator, and total energy of usual impact by the bit and vibration by the vibrator was used as a seismic source for SWD. For the seismic wave generation mechanism of this vibrator, the shell was resonated by the magnetostrictive element, and vibration was given to the bit and drilling pipe. When this seismic source is used, only single frequency is obtained for each vibration due to the utilization of resonance of shell. Therefore, the generation patterns should be made, by which wide band energy can be obtained after the interaction. Since the survey was conducted using this bottom hole seismic source at the drilling depth more than 3,000 m, it was necessary to enhance the vibration energy. 2 refs., 2 figs.

  2. New seismic source `BLASTER` for seismic survey; Hasaiyaku wo shingen to shite mochiita danseiha tansa

    Energy Technology Data Exchange (ETDEWEB)

    Koike, G.; Yoshikuni, Y. [OYO Corp., Tokyo (Japan)


    Built-up weight and vacuole have been conceived as seismic sources without using explosive. There have been problems that they have smaller energy to generate elastic wave than explosive, and that they have inferior working performance. Concrete crushing explosive is tried to use as a new seismic source. It is considered to possess rather large seismic generating energy, and it is easy to handle from the viewpoint of safety. Performance as seismic source and applicability to exploration works of this crushing explosive were compared with four kinds of seismic sources using dynamite, dropping weight, shot-pipe utilizing shot vacuole, and impact by wooden maul. When considered by the velocity amplitude, the seismic generating energy of the crushing explosive of 120 g is about one-fifth of dynamite of 100 g. Elastic wave generated includes less high frequency component than that by dynamite, and similar to that using seismic source without explosive, such as the weight dropping. The maximum seismic receiving distance obtained by the seismic generation was about 100 m. This was effective for the slope survey with the exploration depth between 20 m and 30 m. 1 ref., 9 figs., 2 tabs.

  3. Recent design example with prestressing techniques; Prestressing wo mochiita kozo sekkei 2 dai

    Energy Technology Data Exchange (ETDEWEB)

    Kawaguchi, M. [Hosei University, Tokyo (Japan). Faculty of Engineering


    This paper describes two examples of non-concrete prestressing techniques. The first example is a soccer stadium. The system to support the roof consists of members (steel rods) that compress and stretch the roof. Premoulded prestressed concrete piles are used for columns. Prefabricated members are also used for other parts of the upper stand structure. The upper stand structure consists of 25 PHC pile columns and precast concrete. Vertical braces are arranged between the columns. The load of the stands are supported by cast-in-place concrete and PHC columns. In this structure, the axial force represents the main flow of force, allowing each member to be utilized with its highest sectional performance. The second example is a footbridge leading to a park. Natural granite stones are used for the top chord members of the imperfect truss. The stones are laid side by side, and are tied with five PC cables into a single stone. Prestress is applied to the stones to suppress tensile force. Thrust of the stones are offset by tensile force of the bottom chord members. 19 figs., 2 tabs.

  4. Biped locomotion control with compliance; Compliance wo mochiita nisoku soko robot no undo seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Kawaji, S.; Ogasawara, K.; Iimori, J. [Kumamoto University, Kumamoto (Japan)


    Realization of stable walking motion of biped locomotive robot is one of difficult control problems, but it is very interesting both theoretically and practically from the view point of motion control. The authors have already reported that the locomotion rhythm plays an important role in walking motions, and confirmed experimentally that the control method based on the locomotion rhythm is effective. But, many uncertainties, e.g., the changes of robot dynamics and the interaction between the robot and the floor, may make the locomotion rhythm irregular. In this paper, we introduce the compliance into the control system in order to modify the original reference locomotion rhythm for stable walking under the existence of the uncertainties. Concretely a compliance control system for the contact leg is designed to modify the rhythm by changing the posture of the leg corresponding to the force acting from the body so that the robot may keep the equilibrium state dynamically. Finally the simulation results are given to illustrate the effectiveness of the proposed compliance control system. 21 refs., 12 figs., 3 tabs.

  5. Shallow PS-logging by high frequency wave; Koshuha wo mochiita senbu PS kenso

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, A.; Miyazawa, M.; Azuma, H. [OYO Corp., Tokyo (Japan)


    This paper describes the following matters on down-hole PS logging in shallow subsurface. Determining an elastic wave velocity structure in shallow subsurface with high accuracy by using down-hole PS logging requires reduction of errors in reading travel time. Therefore, a high-frequency vibration source was fabricated with an objective to raise frequencies of waves used for the measurement. Measurements were made on two holes, A and B, at a measurement interval of 0.5 m, whereas at the hole A a measurement was performed simultaneously by using a normal type (low-frequency) vibration source. A spectral analysis on the waveform record revealed that the frequencies with each vibration source were 127 Hz and 27 Hz for the hole A, 115 Hz for the hole B, and the S/N ratio was all the same for both holes. When the high-frequency vibration source was used, the velocity was determined at accuracy of 5% over the whole length of the shallow section. When the low-frequency vibration source was used, sections with the velocity determining error greater than 5% were found, and it was not possible to derive the velocity structure in the shallow subsurface in fine segments. 3 refs., 8 figs., 2 tabs.

  6. Reservoir characterization using artificial neural network; Neural network wo mochiita choryuso tokusei kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Shimada, N.; Kozawa, T. [Japan National Oil Corp., Tokyo (Japan); Nishikawa, N.; Tani, A. [Fuji Research Institute Corp., Tokyo (Japan)


    Neural network is used for the prediction of porosity and permeability using logging data as reservoir characteristics, and the validity of this method is verified. For the prediction of reservoir characteristics by the use of seismic survey data, composite seismic survey records obtained by density logging and acoustic logging are used to experiment the prediction of porosity and permeability continuous along lines of wells. A 3-output back propagation network is used for analysis. There is a possibility that this technique when optimized will improve on prediction accuracy. Furthermore, in the case of characteristics mapping, 3-dimensional seismic data is applied to a carbonate rock reservoir for predicting spatial porosity and permeability. This technique facilitates the comprehensive analysis of core data, well data, and seismic survey data, enabling the derivation of a high-precision spatial distribution of reservoir characteristics. Efforts will continue for further improvement on prediction accuracy. 6 refs., 7 figs., 3 tabs.

  7. Lightning position detecting system using OPGW; OPGW wo mochiita rakurai ichi tanchi system

    Energy Technology Data Exchange (ETDEWEB)

    Kurihara, M. [Central Research Institute of Electric Power Industry, Tokyo (Japan)


    Discussions were given to utilize an optical fiber composite aerial ground wire (OPGW) not only as an information transmission path, but also for lightning detection. Power transmission lines are installed with aerial ground wires for lightning shielding, into which optical fibers were assembled to make the system an OPGW. An optical loop is constructed, in which optical signals admitted to an incidence end is turned back at an OPGW end opposing the incidence end so that the optical signals return back to the incidence end. If an OPGW is hit by lightning, a lightning current flows through steel towers as the grounding path. This current flow generates a magnetic field inside the OPGW, causing simultaneously polarized rotation (a Faraday effect) in the same direction in the optical signals going back and forth in the optical loop. When this is observed at the incidence end, polarizing variation is observed twice with a certain time difference, which corresponds to two times of the distance between the lightning point and the turn-back point. Thus a distance to the lightning point can be derived. As compared with other identification systems, this method is characterized by capability of collecting lightning information along power transmission lines at one point, no necessity of a device to be connected to a transmission line, and no necessity of comparative information or clock synchronization. 4 refs.

  8. Control of mechatronic systems using electrorheological fluids; ER ryutai wo mochiita mekatoronikusu kiki no seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Furusho, J. [The Univ. of Electric Communications, Tokyo (Japan)


    ER fluids (electrorheological fluids) are fluids whose rheological properties vary due to an electric field, and at the present, its development is being vigorously carried forward with the objective of its application to various mechanical systems. The ER fluids which are the objects for its development are two kinds, namely ER suspensions and homogeneous fluids using liquid crystals. Concerning the ER suspensions, its study started from the latter half of 1940`s, but the history of studying the homogeneous ER fluids is short. In this article, comparison is made between the ER suspensions and the homogeneous ER fluids. Regarding the comparison in their application fields, several differences are enumerated including that the response time of the ER suspensions to the change of the electric field is considerably faster than the homogeneous fluids using liquid crystals. As examples of the application of the ER suspensions, ER valves, application to automobiles, ER dampers, vibration control of structures, and ER clutches are shown and likewise, as examples of the application of the homogeneous ER fluids, robot arm control, dampers, etc.. Also its application to robotics is described. 51 refs., 8 figs., 1 tab.

  9. Engineering lattice matching, doping level, and optical properties of $KY(WO_4)_2:Gd,Lu,Yb$ layers for a cladding-side-pumped channel waveguide laser

    NARCIS (Netherlands)

    Aravazhi, S.; Geskus, D.; Dalfsen, van K.; Vázquez-Córdova, S.A.; Grivas, C.; Griebner, U.; Garcia Blanco, S.M.; Pollnau, M.


    Single-crystalline KY1-x-y-zGdxLuyYbz(WO4)2 layers are grown onto undoped KY(WO4)2 substrates by liquid-phase epitaxy. The purpose of co-doping the KY(WO4)2 layer with suitable fractions of Gd3+ and Lu3+ is to achieve lattice-matched layers that allow us to engineer a high refractive-index contrast

  10. Continuous-wave and Q-switched operation of a compact, diode-pumped Yb3+:KY(WO4)2 planar waveguide laser. (United States)

    Bain, F M; Lagatsky, A A; Kurilchick, S V; Kisel, V E; Guretsky, S A; Luginets, A M; Kalanda, N A; Kolesova, I M; Kuleshov, N V; Sibbett, W; Brown, C T A


    A diode-pumped LPE-grown Yb:KYW planar waveguide laser is demonstrated in a microchip monolithic cavity configuration. Output powers as high as 148 mW and thresholds as low as 40 mW were demonstrated during continuous-wave operation. Pulses of 170 ns duration with maximum pulse energy of 44 nJ at a 722 kHz repetition rate were generated when Q-switched using a semiconductor saturable absorber mirror.

  11. Production of gerbera throughout a year by utilizing water heat accumulating heat pumps. Practical application of control of culture medium temperature by rock wool cultivation, and technology to produce gerbera throughout a year; Mizu chikunetsushiki heat pump wo riyoshite gabera wo shunen seisan. Rokku uruko ni yoru baichion seigyo to gabera no shunen seisan gijutsu no jitsuyoka

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, M. [Kansai Electric Power Co. Inc., Osaka (Japan)


    In order to utilize electric power more effectively in agriculture, technology to produce gerbera throughout a year by using rock wool cultivation has been established, by which culture medium temperature is cooled (heated) by using heat pumps. Once implanted, gerbera can provide flowers for two years, and demand for its cut flowers is increasing year after year. However, because high temperature in summer can create deformed flowers, reducing the rate of acceptable flower production, cut flower production is suspended during summer at the present. Therefore, nighttime electric power was utilized to accumulate cold (warm) water in a heat accumulation tank, circulate the water, and control the rock wool culture medium temperature to 20 to 25 degrees C which is suitable for growth of the plant. This system has made it possible to reduce greenhouse warming cost in winter. A non-control area had the average culture medium temperature vary to 30 degrees C or higher in summer and 15 degrees C in winter, while the control area maintained the temperature at 22 {+-} 1 degrees C both in summer and winter. The control area created not too great difference in flow quality as flower diameter and weight as compared to that in the non-control area, but had better flower stalk length with less deformed flower production, enhanced the acceptable product rate, and attained annual yield as great as 1.4 times. The assignment to the system is cost reduction. (NEDO)

  12. Method to remove poisonous chlorine compounds using supercritical carbon dioxide. Chorinkai tansan gas wo mochiita yudoku enso kagobutsu no jokyoho

    Energy Technology Data Exchange (ETDEWEB)

    Ikushima, Y. (Government Industrial Research Institute, Tohoku, Sendai (Japan))


    This paper describes a method to extract and remove selectively poisonous chlorine compounds from aqueous solution using supercritical CO2. This method is characterized in that it extracts and separates only chlorine compounds in short time under a moderate condition, and removes it without a need of whatever post-treatment. The supercritical CO2 pressure was 80 kg/cm[sup 2], and the extraction temperature was 40[degree]C. The supercritical CO2 extracted 70% to 80% by weight of trichloroethylene and tetrachloroethylene in 15 to 30 minutes, almost all of 1,2-dichloroethane and 1,1,1-trichloroethane in one hour, and about 70% by weight of benzil chloride after 90 minutes. When the supercritical CO2 extraction was carried out for a dilute chlorine compound at 1000 ppm for three hours, the concentrations of trichloroethylene and tetrachloroethylene in the aqueous solution decreased down to several ppm, with no other substances than chlorine compounds detected in the extracts. This proves that no water has been extracted at all. 5 figs., 1 tab.

  13. Preparation of ion-exchange thin film using plasma processes. Plasma process wo mochiita ion kokansei usumaku no sakusei

    Energy Technology Data Exchange (ETDEWEB)

    Ogumi, Z.; Uchimoto, Y. (Kyoto University, Kyoto (Japan). Faculty of Engineering)


    The present report describes a study which aims at preparation of a new functional film by plasma polymerization. For this purpose, 4-vinylpyridine monomer is plasma-polymerized to obtain a thin film, which is quaternarized with 1-bromopropane to produce an anion exchange thin film, which is laminated on the surface of a cation-exchange film to make a mono-valent cation perm-selective film. In plasma-polymerization, the relations of polymerizing pressure, as parameter, to the deposition rate of the polymerizerd film and the characteristics of compound were clarified. In preparing the anion-exchange thin film, the preparation of uniform ultrathin films with no pinhole was attempted. For this purpose, the transference number of Cl[sup -] was measured so as to confirm that Cl[sup -] is uniformly distributed and fixed cation groups are distributed uniformly in the film. The perm-selective film exhibited a high mono-valent cation perm-selectivity while its film resistance was increased. This increase is found to be broken down to the resistance of the plasma-polymerization film layer and the resistance of the film interface. The latter arises from the implantation of nitrogen-cointaining species in the plasma onto the surface of the cation exchange film. 26 refs., 10 figs., 2 tabs.

  14. Batch process. Flexible paint production system using movable tanks; Idoso wo mochiita toryo no flexible seisan system

    Energy Technology Data Exchange (ETDEWEB)

    Yamashita, S. [Kansai Paint Co. Ltd., Hiratsuka, Kanagawa (Japan). Central Lab.


    In the paint manufacturing industry, there are many kinds of product depending on the use, and there are few kinds of paint which can be manufactured by a large facility capable of producing several tens of kL of paint. An average working ratio of facility in this industry is limited to between 60 to 70%, and the ratio of the personnel expense to the cost has recently increased. The changing to an FMS (Flexible Manufacturing System) for increasing the working ratio of the facility and the changing of the system to greatly improve the operation efficiency have been demanded. The concrete means for these requirements include changing the facility to a pipeless one. The paint manufacturing facility comprises four sections, i.e. a premixing section, dispersing section, mixing section and canning section. If the mixing tank is made movable and the equipment on the preceding and succeeding stages of the mixing tank is made pipeless, the facility can be changed to the one not substantially restricted by the quality of products from the dispersing section to the filtration section which can be formed. However, the drawbacks of this system include the following: a failure, if it occurs, influences the whole production line; learning the system operating method requires much time, causing many initial failure occur; and great expansion of the facility is difficult. 2 refs., 2 figs., 2 tabs.

  15. Index of powered support performance in terms of global stiffness matrix. Gosei matrix wo mochiita jiso shiho no seino hyoji

    Energy Technology Data Exchange (ETDEWEB)

    Sato, K.; Itakura, K.; Hirose, K. (Muroran Institute of Technology, Hokkaido (Japan))


    Powered supports were tentatively analyzed to establish a new index for evaluation of their performance. The new index was deduced by comparing the deformation characteristics of various powered supports mutually. The deformation characteristics of a powered support was able to be indicated in terms of a (2 {times} 2) global stiffness matrix. The global stiffness matrix depended on the mining height of powered support. The stiffness of hydraulic legs mainly determined the convergence component of the global stiffness, whereas the stiffness of caving shield determined its shear component. The convergence performance tended to sacrifice the shear deformation one, and vice versa. The principal direction of the global stiffness matrix allowed to select well-balanced deformation characteristics. To assure deformation performance as properly as possible, it was shown that the principal axis of the global matrix should be tilted by 15 to 25 degrees of the angle from the vertical towards the canopy tip. 4 refs., 13 figs., 2 tabs.

  16. Evaluation of paramagnetic species in coals with iodine doping technique; Yoso tenkaho wo mochiita sekitanchu no jojiseishu no hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Aizawa, S.; Kumagai, H.; Chiba, T. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology


    Electron paramagnetic resonance (EPR) of coals was considered by using iodine doping technique. Sub-bituminous coal (WA) and bituminous coal (UF) were used to observe EPR spectra using microwaves. With the UF coal, strength of the narrow component of the spectra was found constant regardless of amount of the doped iodine, wherein radicals without interaction with iodine were detected. Strength of the broad component increased with the iodine doping amount, where in deviation of {pi} electrons was detected, which have been generated as a result of interaction between aromatic rings and iodine in the coals. Spin concentration of the WA coal with low coalification degree is constant regardless of the iodine doping amount, and the interaction of the iodine with the aromatic rings was found small. The higher the coalification degree, the more the aromatic ring structure grows, and electron donor capability for the iodine increases. In a system with the entire spin being uniform, the spectrum height shows a saturation phenomenon against increase in microwave output. A non-uniform system, in which the oriented spin forms small groups and is in local thermal equilibrium, does not show saturation, but increases monotonously. 2 refs., 5 figs.

  17. Evaluation of column flotation results with a film flotation method; Film fusenho wo mochiita column fusen kekkan no hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, H.; Matsukata, M.; Ueyama, K. [Osaka University, Osaka (Japan). Faculty of Engineering Science


    Change in wettability of coal particle surfaces due to kerosene adsorption was studied by using a film flotation method. The applicability of a film flotation method to coals modified by kerosene adsorption was first confirmed. In experiment, film flotation was applied to Illinois coal modified by aqueous methanol solution and kerosene adsorption, and the weight percent of residual particles on a gas-liquid interface and kerosene in aqueous methanol solution were analyzed to verify the applicability of a film flotation method. Film flotation was applied to Datong and Illinois coals modified by kerosene adsorption, and the weight percent of residual particles on a gas-liquid interface was plotted to surface tension of liquid. As a result, the weight percent of hydrophobic particles within 50mN/m in surface tension slightly increased in Datong coal and remarkably increased in Illinois coal with kerosene addition. It was thus suggested that in addition to surface tension, the distributions of hydrophilic and hydrophobic strengths on the surface of each coal particle should be considered to understand attachment of coal particles and bubbles. 6 refs., 4 figs.

  18. DC servo motor control using digital signal processors; Digital keisoku seigyo. 6. DSP wo mochiita DC servo motor seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Sato, T. [Max Co. Ltd., Tokyo (Japan)


    A digital control development effort is introduced, citing a case of DSP (digital signal processor)-aided DC servo motor control for the flat head type pen plotter. In a real plotter, a complicated nonlinear problem will arise because the natural frequency varies dependent upon the pen position. For the inhibition of such vibration which occurs during acceleration and deceleration, nonlinear elements have to be taken into consideration at the designing stage. In this report, the effort is focused on motor axis control only, and the DC servo control problem is solved as a linear problem. A DSP board type DS1102 of the dSPACE Corporation is named for this work. Using this board, the C code is automatically generated out of a control block constructed through SIMULINK, and a real-time test is conducted after downloading the code to the DSP processor. Since the quantity of DC servo motor rotation is quantized in an encoder, the result would contain much error and cause instability in the control if the quantity as obtained was subjected to differential calculus. Such being the case, velocity data for the control in this report are acquired by use of an observer. (NEDO)

  19. Delivery of antisense oligonucleotide into cells using synthetic peptide; Gosei pepuchido wo mochiita anchisensu origonukureochido no saibounai donyu

    Energy Technology Data Exchange (ETDEWEB)

    Niidome, Takuro [Nagasaki University, Nagasaki (Japan). Dept. of Applied Chemistry


    Much attention has been attracted to the antisense oligonucleotide as a novel nucleic acid medicine. However, many problems to be solved such as delivery system in vivo and permeation through cell membrane are pointed out. In this study, we found out that some cationic peptides were useful as an oligonucleotide-carrier molecule into cells. Furthermore, to develop a cell specific gene delivery system using the cationic peptide, we modified the peptides with several galactose residues. As a result, the modified peptides showed high transfer efficiencies into hepatoma cells, and then, it was clear that the internalization into cells was mediated by asialoglycoprotein receptor on hepatoma cell. (author)

  20. Experiment of exploration using the active-faults exploration system; Katsudanso tansa system wo mochiita chika tansa jikken

    Energy Technology Data Exchange (ETDEWEB)

    Mikada, H.; Sato, H.; Iwasaki, T.; Hirata, N. [The University of Tokyo, Tokyo (Japan). Earthquake Research Institute; Ikeda, Y. [The University of Tokyo, Tokyo (Japan). Faculty of Science; Ikawa, T.; Kawabe, Y.; Aoki, Y. [JAPEX Geoscience Institute, Tokyo (Japan)


    A system for exploration of active-faults by seismic reflection profiling method was introduced at Earthquake Research Institute, University of Tokyo. A test-run was conducted to check the performance of this system at Ranzan, Saitama Prefecture. This paper describes the confirmed performance of mini-VIB as a wide band frequency seismic source, the quality of data obtained using a digital data acquisition system, and problems for data processing of fault exploration in the future. For the test-run at Ranzan, two-dimensional exploration was conducted by the quasi-three-dimensional data acquisition method using three geophones of 8 Hz, 28 Hz, and 40 Hz, simply arranged in parallel on the measurement line. Using an active seismic vibrator, mini-VIB, data acquisition of faults in the wide band frequency was achieved, which would result in the highly accurate imaging. Operation of data acquisition and processing systems is easy, and the system can be also used as a kind of black box. The existing methods are to be used sufficiently as a tool for imaging of faults. Further research for accumulating experience may become necessary toward the extension of the system expected in the future. 5 refs., 6 figs.

  1. Temperature measurement of geothermal wells by optical fiber sensor; Hikari fiber sensor wo mochiita chinetsusei no ondo bunpu keisoku

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, N.; Sakaguchi, K. [Geological Survey of Japan, Tsukuba (Japan)


    Experiments of temperature measurement were conducted in high temperature and high pressure geothermal wells using optical fiber sensor. A temperature measurement system using optical fiber sensor was applied to geothermal wells. Working availability was confirmed under the condition up to the depth of 1,750 m and the temperature of 240 centigrade. Observed values agreed well with those observed by the conventional temperature logging. Durability of the optical fiber sensor was also sufficient. The maximum standard deviations of measured values were 1.3 centigrade at the depth of 1,750 m at 195 centigrade for the loop-type sensor, and 3.7 centigrade at the depth of 365 m at about 200 centigrade for the single-end sensor. Although the accuracy was inferior to the conventional measurement using a thermo couple, it was enough to be applied to usual temperature logging. Furthermore, for this system, the temperature profile in the whole well can be monitored, simultaneously. Through the experiments, the detailed successive change of temperature profile accompanied with the water injection can be clearly illustrated. 3 refs., 7 figs.

  2. Development of economical and high efficient desulfurization process using low rank coal; Teitankadotan wo mochiita ankana kokoritsu datsuryuho no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Takarada, Y.; Kato, K.; Kuroda, M.; Nakagawa, N. [Gunma University, Gunma (Japan). Faculty of Engineering; Roman, M. [New Energy and Industrial Technology Development Organization, Tokyo, (Japan)


    Experiment reveals the characteristics of low rank coal serving as a desulfurizing material in fluidized coal bed reactor with oxygen-containing functional groups exchanged with Ca ions. This effort aims at identifying inexpensive Ca materials and determining the desulfurizing characteristics of Ca-carrying brown coal. A slurry of cement sludge serving as a Ca source and low rank coal is agitated for the exchange of functional groups and Ca ions, and the desulfurizing characteristics of the Ca-carrying brown coal is determined. The Ca-carrying brown coal and high-sulfur coal char is mixed and incinerated in a fluidized bed reactor, and it is found that a desulfurization rate of 75% is achieved when the Ca/S ratio is 1 in the desulfurization of SO2. This rate is far higher than the rate obtained when limestone or cement sludge without preliminary treatment is used as a desulfurizer. Next, Ca-carrying brown coal and H2S are caused to react upon each other in a fixed bed reactor, and then it is found that desulfurization characteristics are not dependent on the diameter of the Ca-carrying brown coal grain, that the coal is different from limestone in that it stays quite active against H2S for long 40 minutes after the start of the reaction, and that CaO small in crystal diameter is dispersed in quantities into the char upon thermal disintegration of Ca-carrying brown coal to cause the coal to say quite active. 5 figs.

  3. Interferometric SAR and land deformation. Analysis using the dislocation model; Interferometric SAR to chikaku hendo. Dislocation model wo mochiita kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, J.; Otaki, T.; Tanaka, A.; Miyazaki, Y. [Geological Survey of Japan, Tsukuba (Japan)


    The diastrophism by the earthquake-induced dislocation is investigated by interferometry (INSAR) which represents the diastrophism by the interference fringes of equiphase difference lines. A joint research group at Geographical Survey Institute and National Space Development Agency showed the diastrophism in the vicinity of the ground surfaces before and after the Hyogoken Nanbu Earthquake by the INSAR interference images in 1995. This paper discusses the effects of observation in the vision line direction from the satellite and dislocation parameters on the interference images. The dislocation model uses a slanted rectangular model in a semi-infinite medium, to calculate static displacements and strain distributions at the ground surface, when dislocation changes. It is found that the INSAR interference images, detecting displacements in the vision line direction from the satellite, significantly change as the vision line direction changes, and that the actual displacement cannot be given by the images alone. This paper also shows sensitivity of the interference images to the dislocation parameters. 3 refs., 9 figs., 1 tab.

  4. Mine train control system by H{infinity} control; H{infinity} seigyo wo mochiita tanko makiage seigyo system

    Energy Technology Data Exchange (ETDEWEB)

    Ouchi, s. [Tokai University, Tokyo (Japan). Faculty of Engineering; Liu, K. [Chiba University, Chiba (Japan). Faculty of Engineering; Sato, S. [Fuji Electric Corporate Research and Development, Ltd., Kanagawa (Japan); Mita, T. [Tokyo Institute of Technology, Tokyo (Japan). Faculty of Engineering


    Mine train control system is consisted of a winder, a train which transports many people to minebottom, and a long wire rope which connects a winder and a train. The mine train control system reported in this paper is the system with the longest rope of about 6700m in the world. This system often generate a rolling of train when the train stops at the station when using conventional control. In conventional systems, two mine train control systems of the length of 1/2 of all mining galleries were used in order to ristrict the rolling. In these systems, change time was necessary. However, this change time become unnecessary by using a system with the length of 6700m. When using this system, it is the main subject how to control the bigger rolling . We solved the problem on the rolling control of this system by using H{infinity} control, and got the result that the travel time of the train made 2/3 compared with that of the conventional systems using two mine train control systems, and the train speed of 420m/min which is the maximum speed in the world was achieved. 7 refs., 8 figs.

  5. Geotechnology for groundwater and salinisation soil using geophysical prospecting; Butsuri tansa wo mochiita chikasui enrui dojo no tansa gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Chiba, A. [Sumitomo Metal Industries, Ltd., Osaka (Japan); Imaizumi, M.; Takeuchi, M. [National Research Institute of Agricultural Engineering, Tsukuba (Japan)


    This paper takes a general view of geophysical prospecting on groundwater and salinisation soil. It also explains the following examples of prospecting: an example of pursuing movement of saline water lump charged with a tracer by using a specific resistance monitor, as a monitoring survey being a representative example of `visualization of movement` expected as a direction to which physical prospecting should proceed in the future, an example of elucidating distribution of soil salts vertically and two-dimensionally by using the electromagnetic exploration method, and an example of surveying distribution of three-dimensional water permeation coefficients by utilizing geophysical prospecting systems, as an example of estimating property values from geophysical prospecting. Electrical prospecting has been used as an exploration method related to groundwater, whereas its method has been increasing the diversity, such as from vertical exploration to high-density horizontal exploration and tomography. Noticeable progress can also be seen in electromagnetic exploration and logging techniques. In addition, what is demanded in application of physical prospecting to groundwater field may include visualization of ground water flow, more precise estimation of hydraulic constants, and complement of their distribution. 22 refs., 21 figs., 3 tabs.

  6. Suppression of numerical dispersion using FD modified operators; Atarashii sabunho no enzanshi wo mochiita suchi bunsan no yokusei

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, N.; Geller, R. [The University of Tokyo, Tokyo (Japan). Faculty of Science


    The author, et al., have developed a formal evaluation theory for errors in numerical solutions and derived on the basis of this theory the conditions that a modified error minimizing operator should satisfy. A modified operator was derived for a calculus of finite difference in the time domain making use of this error evaluation theory. In this study, a modified operator was derived for O (2, 2) in the calculus of finite difference in time, and the operator was used in the calculation for the old and new methods about 1-dimension inhomogeneous media, and the two were quantitatively compared in CPU time and calculation accuracy. The calculation used 500 space grids and 5000 time grids. With the ratio of the time grid gap and space grid gap are kept constant, both CPU time and calculation accuracy were in proportion to the square of the number of grids. It was found in view of the result that the new method, as compared with the old method, needs only approximately 1/20 of CPU time in performing calculations of the same precision and that it maintains calculation accuracy that is approximately 20 times higher in the said CPU time. 4 refs., 2 figs., 1 tab.

  7. Reexamining results of Iwatoyama tumulus by means of directive antenna; Shikosei antenna wo mochiita Iwatoyama kofun no saijikken

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, K. [Osaka Institute of Technology, Osaka (Japan); Kobayashi, Y. [Kyoto University, Kyoto (Japan); Yoda, M. [Shiga Prefecture Board of Education, Shiga (Japan)


    Investigation was conducted into the Iwatoyama tumulus located at Oaza Yoshida, Yame City, Fukuoka Prefecture, in January 1995, when a directional antenna was used. For the verification of the reliability of the result, another investigation was conducted in the same way. As in the previous effort, a traverse line of 18.8m was provided, and a sub-traverse line of the same length was provided 1m south of the traverse line. Reflection amplitude obtained during this investigation was smaller than that in the previous investigation, which was attributed to it that the contrast in dielectric constants between the rock constituting the main body in the cave and the cavity inside is high in winter and low in summer. In the second investigation, probably because the sub-traverse line was nearer to the southern end of the stone chamber, it became possible to evaluate the area of the stone chamber in the east-west direction, which confirms the conclusion of the first investigation that `it has to be inferred that the tumulus has its stone chamber ceiling at the depth of approximately 3.7m at a spot approximately 9.5-15.0m distant from the survey base for the round foot of the Iwatoyama tumulus and that therefore there exists a cave-type stone chamber with its ceiling 2.5-3.0m high.` 3 refs., 6 figs.

  8. Remote reference processing in MT survey using GPS clock; MT ho ni okeru GPS wo mochiita jikoku doki system

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, K.; Inoue, J.; Takasugi, S. [Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Kosuge, S. [DRICO Co. Ltd., Tokyo (Japan)


    A report is given about the application of a synchronizing system using clock signals from GPS satellites to a remote reference method which is a technique to reject noise from the MT method. This system uses the C/A code out of the L1 band waves from NAVSTAR/GPS satellites. The new system was operated in MT method-using investigations conducted at China Peninsula, Aichi Prefecture, and Izu Peninsula, Shizuoka Prefecture, with the reference points placed several 100km away in Iwate Prefecture on both occasions. It was found as the result that it is basically possible to catch signals from the GPS at any place, that the signals are accurate enough to be applied to time synchronization for the MT method, and that the signals assure a far remote reference method with a separation of several 100km between the sites involved. The referencing process at high frequencies whose feasibility had been doubted proved a success when highly correlated signals were exchanged between two stations over a distance of several 100km. 5 refs., 9 figs.

  9. Improvement of two-dimensional gravity analysis by using logarithmic functions; Taisu kansu wo mochiita nijigen juryoku kaiseki no kairyo

    Energy Technology Data Exchange (ETDEWEB)

    Makino, M.; Murata, Y. [Geological Survey of Japan, Tsukuba (Japan)


    An examination was made, in the two dimensional tectonic analysis by gravity exploration, on a method that was applicable from a deep underground part to a shallow geological structure by using logarithmic functions. In the examination, a case was considered in which an underground structure was divided into a basement and a covering formation and in which the boundary part had undulations. An equation to calculate a basement structure from a gravity anomaly was derived so that, taking into consideration the effect from the height of an observation point, it might be applicable to the shallow distribution of the basement depth. In the test calculation, a model was assumed reaching the depth near the surface with the basement being a step structure. Density difference was set as 0.4g/cm{sup 3}. An analysis using an equation two-dimensionally modified from Ogihara`s (1987) method produced a fairly reasonable result, showing, however, a deformed basement around the boundary of the step structure, with the appearance of a small pulse-shaped structure. The analysis using logarithmic functions revealed that the original basement structure was faithfully restored. 3 refs., 5 figs.

  10. Refrigerator cooled magnet using Ag-sheathed Bi-2212 tape; Bi-2212 kin fukugoka senzai wo mochiita reitoki reikyaku magunetto

    Energy Technology Data Exchange (ETDEWEB)

    Okura, K.; Kaneko, T.; Hayashi, K.; Takei, H. [Sumitomo Electric Industries Corp., Osaka (Japan); Kasu, O. [Engineering Research Association for Superconductive Genertion Equipment and Materials, Osaka (Japan)


    The application to the coil in the 20K vicinity can be expected by the improvement in the refrigerating machine performance Bi2212 oxide superconductor. It is compared it in 20K in case of the superconducting coil at the conventional 4.2K, and the specific heat increases, and the coil becomes difficult to quench it, and there is the merit in which the stable energization becomes possible. Then, the result is reported, because the coil trial manufacture was carried out using Bi-2212 silver combination long length wire rod this time, and because the coil operation was carried out. (NEDO)

  11. Performance analysis of dish solar stirling power system; Stirling engine wo mochiita taiyonetsu hatsuden system no seino yosoku

    Energy Technology Data Exchange (ETDEWEB)

    Tsuchiya, K.; Yamaguchi, I. [Meiji University, Tokyo (Japan); Naito, Y.; Momose, Y. [Aisin Seiki Co. Ltd., Aichi (Japan)


    In order to estimate the performance of the dish solar Stirling power system, matching and control of each component system were studied, and the performance of the 25kWe class power system was estimated on the basis of direct solar radiation measured in Miyako island, Okinawa. Application of a Stirling engine to solar heat power generation is highly effective in spite of its small scale. The total system is composed of a converging system, heat receiver, engine/generator system and control system. As the simulation result, the generator output is nearly proportional to direct solar radiation, and the system efficiency approaches to a certain constant value with an increase in direct solar radiation. As accumulated solar radiation is large, the influence of slope error of the converging mirror is comparatively small. The optimum aperture opening ratio of the heat receiver determined on the basis of mean direct solar radiation (accumulated solar radiation/{Delta}t (simulated operation time of the system)), corresponds to the primary approximation of the opening ratio for a maximum total generated output under variable direct solar radiation. 6 refs., 6 figs., 1 tab.

  12. Magnetic sensor with silicon on insulator structure for high temperature applications; SOI kozo wo mochiita koon`yo jiki sensor

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, Y.; Kawai, H.; Terada, T.; Kawahito, S.; Ishida, M.; Nakamura, T. [Toyohashi University of Technology, Aichi (Japan)


    To enable stable magnetic measurement in high temperature surroundings, a Hall cell of the SOI structure (with a single-crystal Si layer formed on an insulating film) was experimentally fabricated, and its characteristics as a magnetic sensor were examined. This element can be mass-produced by use of the current semiconductor manufacturing technology. In the conventional method of element isolation using the pn-junction, backward leak currents across the pn-junction grow large at high temperatures, reducing sensitivity and increasing offset voltage (the Hall voltage at zero magnetic field) to disable the elements. Under the circumstances, an SOI structure in which elements are isolated by an SiO2 film were studied. Sensitivity and temperature characteristics are dependent on donor concentration. But there is a relationship of trade-off between sensitivity and the usable temperature range, and this means that a donor concentration fit for the given purpose needs be chosen. To inhibit the generation of the offset voltage, Hall element shapes and chip bonding methods were studied, and a magnetic sensor with an offset variation not more than {plus_minus}3mV was obtained. In an SOI magnetic sensor, the temperature range in which sensitivity remains constant expands as donor concentration is enhanced, and this permits the use of the SOI magnetic sensor in higher-temperature operations. 6 refs., 13 figs., 1 tab.

  13. Application of VSP to geological investigation; P ha oyobi S ha VSP wo mochiita shinso chishitsu chosa

    Energy Technology Data Exchange (ETDEWEB)

    Kinugasa, Y. [Geological Survey of Japan, Tsukuba (Japan); Feng, S.; Sugiyama, T.; Ishikawa, K. [Chuoh Kaihatsu Corp., Tokyo (Japan)


    Discussed in this paper are the P-wave and S-wave zero-offset VSPs carried out utilizing boreholes located in Nada Ward, Kobe City, and Hokudan-cho, Hyogo Prefecture, as part of the deep layer boring survey following Hanshin Earthquake Disaster. This effort aims at the elucidation of P-wave and S-wave velocity structures, high-precision identification of data obtained by the surface reflection method, and collection of basic data for active faults investigation in the future. Among the velocity structures obtained for various layers, the S-wave velocity structures in particular agree with the stratigraphy excellently and may be utilized in seismic analyses to be conducted in the future. Reflection from geological boundaries is received with precision, providing accurate information about correlation between reflection and geological cross sections. The records will be useful in formulating plans for reflection surveys for instance of the boundary between the Osaka group and Kobe group. Generally speaking, reflection coefficients are large when the reflection is from a boundary where difference is great in elastic wave impedance (mainly difference in velocity). In the case of the boundary between the Kobe group and granite in Awaji Island, however, no strong reflection is found despite the great difference in velocity. This is attributed to the complicated, sharp inclination of the basement rock and to its weathering. 4 refs., 8 figs.

  14. Active SWD using monochromatic source wavelet; Tan`itsu shuhasu no shingen hakei wo mochiita active SWD

    Energy Technology Data Exchange (ETDEWEB)

    Tsuru, T.; Kozawa, T. [Japan National Oil Corp., Tokyo (Japan); Taniguchi, R. [Mitsubishi Electric Corp., Tokyo (Japan); Nishikawa, N. [Fuji Research Institute Corp., Tokyo (Japan); Matsuhashi, K.


    As part of developing efforts for physical exploration technologies for oil reservoirs, this paper describes development of an active seismic while drilling (SWD). The SWD is a seismic exploration method to acquire records equivalent to VSP using seismic waves generated from a bit executing excavation, and is capable of detection and control on a real time basis during the excavation. However, the drawback is that it is subjected to a limitation in the bit. To eliminate this limitation, an artificial seismic source method was devised. In other words, this is an SWD utilizing an artificial seismic source. The contrivance is such that a shot sub containing a magnetic distortion oscillator is attached directly above a bit to generate vibration artificially, and try to utilize larger seismic energy by combining this vibration with that generated from the excavating bit. Frequency band in the seismic source is as narrow as nearly a single frequency waveform. Preparing a time-depth curve from the data and identifying position of a bit making excavation requires reading the initial travel time. A waveform recognition technology was applied, which utilizes a matching evaluation function used in pattern recognition. This made waveform recognition possible at high accuracy. 2 figs., 1 tab.

  15. Simulation model of a solar collector with a heat capacitance on TRNSYS; TRNSYS wo mochiita netsuyoryo wo motsu heibangata shunetsuki no model ka

    Energy Technology Data Exchange (ETDEWEB)

    Yoshinaga, M. [Nagoya City University, Nagoya (Japan); Okumiya, M. [Nagoya University, Nagoya (Japan)


    A flat plate type heat collector considering a heat capacitance was structured; assembled into a solar system simulation program, TRNSYS; correction was made on this model for permeation and absorption rates as a result of incident angles onto the heat collecting surface on which sunlight reaches directly; and effectiveness of the proposed model was verified from comparing the heat collection amount with that of conventional systems and measured values. The heat collection amount decreased when incident angles of insolation are taken into consideration, and the amount approached the measured value in the case of the system with a heat capacitance. Variation in temperature at the heat collector exit decreased when the heat capacitance was taken into account. With the case of having no heat capacitance, heat collecting amount greater than the actually collected amount was calculated for days with great insolation, and less amount was calculate for smaller insolation. However, the value as a whole has become close to the measured value, though slightly greater. A value still closer to the measurements was obtained when the incident angle is considered. As seen in a seven-day average, a model having no heat capacitance and not considering the incident angle had an error from the measured value of 38.6%, while a model having a heat capacitance and considering the incident angle had an error of 9.9%. 5 refs., 7 figs.

  16. Improved visible light photocatalytic activity of WO3 through CuWO4 for phenol degradation (United States)

    Chen, Haihang; Xiong, Xianqiang; Hao, Linlin; Zhang, Xiao; Xu, Yiming


    Development of a visible light photocatalyst is challenging. Herein, we report a significant activity enhancement of WO3 upon addition of CuWO4. Reaction was carried out under visible light for phenol degradation in aqueous suspension in the presence of H2O2. A maximum reaction rate was observed at 1.0 wt% CuWO4, which was 2.1 and 4.3 times those measured with WO3 and CuWO4, respectively. Similar results were also obtained from the photocatalytic formation of OH radicals, and from the electrochemical reduction of O2. A possible mechanism responsible for the improved activity of WO3 is proposed, involving the electron transfer from CuWO4 to WO3, followed by the reduction of H2O2 over WO3.

  17. Improved Charge Separation in WO3/CuWO4 Composite Photoanodes for Photoelectrochemical Water Oxidation

    Directory of Open Access Journals (Sweden)

    Danping Wang


    Full Text Available Porous tungsten oxide/copper tungstate (WO3/CuWO4 composite thin films were fabricated via a facile in situ conversion method, with a polymer templating strategy. Copper nitrate (Cu(NO32 solution with the copolymer surfactant Pluronic®F-127 (Sigma-Aldrich, St. Louis, MO, USA, generic name, poloxamer 407 was loaded onto WO3 substrates by programmed dip coating, followed by heat treatment in air at 550 °C. The Cu2+ reacted with the WO3 substrate to form the CuWO4 compound. The composite WO3/CuWO4 thin films demonstrated improved photoelectrochemical (PEC performance over WO3 and CuWO4 single phase photoanodes. The factors of light absorption and charge separation efficiency of the composite and two single phase films were investigated to understand the reasons for the PEC enhancement of WO3/CuWO4 composite thin films. The photocurrent was generated from water splitting as confirmed by hydrogen and oxygen gas evolution, and Faradic efficiency was calculated based on the amount of H2 produced. This work provides a low-cost and controllable method to prepare WO3-metal tungstate composite thin films, and also helps to deepen the understanding of charge transfer in WO3/CuWO4 heterojunction.


    Directory of Open Access Journals (Sweden)

    V. G. Savitski


    Full Text Available The linewidth of a KGd(WO42 pulsed Raman laser is analysed experimentally for different configurations of the Raman and pump resonators: with narrow and broadband pump emission profiles, with and without linewidth narrowing elements in the Raman laser resonator, with and without injection seeding into the Raman cavity. The benefits of a narrow linewidth pump source in combination with linewidth narrowing elements in the Raman laser cavity for the efficient linewidth narrowing of the Raman emission are explained. 20 kW peak-power pulses at 1156 nm with 0,43 cm -1 emission linewidth are demonstrated from an injection seeded KGW Raman laser. 

  19. Nd3+:KGd(WO4)2激光晶体的研究%Study on Laser Crystal Nd3+:KGd(WO4)2

    Institute of Scientific and Technical Information of China (English)

    涂朝阳; J.J.ROmero; 等


    A series of KGd(WO4)2 powder samples with different Nd3+ doping concentrations were made and their fluorescent intensities at 1.06μm were measured.The optimal Nd3+ doping concentration has been determined.The liquid temperature curve for the system of Nd3+:KGd(WO4)2-K2WO4 was determined by means of differential thermal analysis(DTA),and large crystals of Nd3+:KGd(WO4)2 with dimensions of up to 50mm have been grown from a K2WO4 flux.From the grown crystal boule,a high-quality laser bulk crystal with dimensions of 5mm×5mm×6mm was cut out,and it's absorption spectrum has been measured.A laser output of 260mW at 1.06μm with a slope efficiency higher than 66% and a laser output of 135mW at 1.3μm with a slope efficiency up to 34.3% were obtained when this crystal was pumped by a Ti-sapphire laser.%合成了一系列不同Nd3+浓度掺杂的Nd3+:KGd(WO4)2粉末样品,进行了荧光光谱测试,初步确定了Nd3+的最佳掺杂浓度;测定了Nd3+:KGd(WO4)2-K2WO4生长体系的生长温度曲线,生长出尺寸达50mm的Nd3+:KGd(WO4)2优质激光晶体,切割出尺寸为5mm×5mm×6mm的优质激光器件,采用钛宝石模拟LD泵浦,在1.06μm处得到260mW的激光输出,斜率效率达到66%;在1.03μm处得到135mW激光输出,斜率效率达到34.3%。

  20. Advanced arc-welding robot with laser sensor technology and its application field; Laser sensor wo mochiita yosetsu robot no seigyo gijutsu no kaihatsu to tekiyo

    Energy Technology Data Exchange (ETDEWEB)

    Kugai, K.; Izawa, A. [Daihen Corporation, Osaka (Japan); Muto, S.; Mori, T. [NTT Fanet Systems Corp., Tokyo (Japan)


    A welding robot with a laser vision sensor was developed. The sensor used in this welding robot consists of a sensor head, a sensor controller, and a profile control board. The sensor controller calculates shapes of welding lines in the reference coordinates of a robot by processing different measurements, and the control board calculates them by using two-dimensional cross section information measured by the sensor. Distance from the sensor to the measurement point is measured as a result of the spot light injected from the sensor head being diffused and reflected on groove surface, part of which is collected to form an image. In addition, cross section shape of the groove is measured by giving the mirror a reciprocal arc movement in a direction perpendicular to the groove to move the mirror over the measurements points while making measurement. Influence of the arc light can be reduced by making the laser light flash sufficiently quicker than the changing speed of flashing of the arc light, and by removing information available when the light is cancelled from information available when it is lit. Extraction of points from an image as the sensor`s technological feature is performed by using the relationship between edge points and intersecting points in partial curve approximation. 10 figs., 1 tab.

  1. Fission track dating using sphene. ; Example of the Hanawa pluton. Sphene wo mochiita fission track ho ni yoru nendai sokutei. ; Hanawa shinsei gantai no rei

    Energy Technology Data Exchange (ETDEWEB)

    Ohira, H. (Niigata University, Niigata (Japan)); Honda, T. (Musashi Institute of Technology, Tokyo (Japan). Atomic Energy Research Laboratory)


    As for the Hanawa pluton which distributes near the boundary between Fukushima and Ibaraki Prefectures, the fission track (FT) dating was conducted by using sphene. The inside surfaces of the polished samples of sphene crystal were stuck by outside detectors and the grain-by-grain method was used to determine the age by the calibration method where a Mount Dromedary Complex sphene was used as the age standard sample. The spontaneous track density differed greatly from a sample to another sample, and even in the same sample the number of crystal grains which could be the measuring subject was limited. The FT ages determined on 5 samples were 67.4Ma for mylonite-like subfacies, 91.9 Ma and 92.5Ma for large shpene bearing subfacies, and 92.5 Ma and 93.1 Ma for fine grained quartz diorite-tonalite. Furthermore, the effect of ratio of Th content to U content on the measured age was also studied. 24 refs., 5 figs., 3 tabs.

  2. Calculation of wave resistance by using Kochin function in the Rankine source method; Rankinsosuho ni okeru kochin kansu wo mochiita zoha teiko keisan

    Energy Technology Data Exchange (ETDEWEB)

    Yasukawa, H. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)


    In order to avoid negative wave resistance (which is physically incomprehensible) generated in calculating wave resistance by using the Rankine source method, a proposal was made on a wave resistance calculation method using the Kochin function which describes behavior of speed potential in regions far apart from a hull. The Baba`s condition was used as a free surface condition for the speed potential which expresses wave motions around a hull. This has allowed a new Kochin function which uses as unknown the speed potential on the hull surface and the free surface near the hull to be defined and combined with the Rankine source method. A comparison was made between the calculated values for wave resistance, hull subsidence and trim change of an ore transporting vessel (SR107 type of ship) in a fully loaded condition and the result of water tank tests. The wave resistance values derived from pressure integration have all become negative when the Froude number is from 0.1 to 0.2, while no negative resistance has appeared in the calculations by using the Kochin function, but the result has agreed with that of the water tank tests. Accuracy of the calculations at low speeds was improved. The trim change in the calculations was slightly smaller than that in the water tank tests. The subsidence showed a good agreement. 7 refs., 1 fig.

  3. 3D-image theater system using TLP770J LCD data projector; Ekisho data projector wo mochiita rittai eizo theater system

    Energy Technology Data Exchange (ETDEWEB)

    Kawasato, H. [Toshiba Corp., Tokyo (Japan)


    In today's multimedia era, visual systems are widely used not only for two-dimensional images but also for the depiction of virtual reality and for simulated three-dimensional images. At the same time, the projection technology used in large-screen projectors is shifting from the cathode ray tube (CRT) to the liquid crystal display (LCD). Toshiba has developed a simplified 3D-image theater system using the TLP770J LCD data projector, which offers easy maintenance and lower costs. (author)

  4. Development of new peptide synthetic method of enzyme using the extraction reactivity; Chushutsu hanno wo mochiita shiki pepuchido koso goseiho no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Hirata, Makoto [Oita University, Oita (Japan)


    Recently, taste and bioactivation of large number of oligopeptide become clear, and the development of the efficient synthetic method becomes the urgency. In the production process by conventional enzyme reaction which combined the crystallization, because the solubility of the product to the water which is reaction solvent is low, the yield remained at about 60%, and the problem of reaction inhibition of the product by the crystal had also been indicated. In the enzyme synthesis of the aspartame in which he is the representative oligopeptide, it aimed at the establishment of the new synthesis method which can improve yield and reaction rate, while the segregation enzyme was continuously utilized. In this synthetic method, supply of organic solvent which dissolved the substrate, extraction of the substrate from organic solvent to water phase, synthesis reaction by the segregation enzyme in water phase, extraction of the aspartame which is a product from water phase to organic solvent progress, and they continuously progress by one complete mixing reactor. The process which controlled these speeds and yields was quantitatively analyzed, and material balance style considering substrate, enzyme and mass transfer of the product and enzyme reaction speed was deduced. The optimum operating condition for improving yield and productivity of the purpose product using this solution was examined, and optimum supply concentration and agitation speed of aspartic acid which was a substrate were started, and the optimum operating condition which realizes the improvement in high yield and productivity over 90% of the aspartame was clarified. Like this, it is that this research adopts features of liquid Citrus nobilis two-phase partition for the enzyme synthesis of the aspartame, and it is considered that there is a value, because it is the creative research which verified that the productivity can be greatly improved by the utilization of the chemical-engineering technique, and because the industrial contribution is also big. (translated by NEDO)

  5. Application of thermoelectric generator for automobile. Application of thermoelectric generation technology using Seebeck effect; Jidosha haikinetsu hatsuden. Seebeck soshi wo mochiita netsuden hatsuden gijutsu no oyo

    Energy Technology Data Exchange (ETDEWEB)

    Shinohara, K.; Kobayashi, M.; Kushibiki, K.; Furuya, K. [Nissan Motor Co. Ltd., Tokyo (Japan)


    Study was made on energy saving by waste heat power generation for automobiles. In a waste heat generation system for automobiles, exhaust gas is converted into electric energy by a thermoelectric generator through an exhaust pipe and catalyst, and supplied to a battery or electric devices through a voltage control system. The thermoelectric generator is composed of a generating module using a Seebeck element, a heat sink and a radiator. Although an Si-Ge system Peltier element is poor in generation efficiency, it is rich in high-temperature reliability, durability and safety. However, the maximum generation efficiency of the system is as low as 5% in a normal temperature region of exhaust gas around 500degC, and further improvement of its performance is essential. For the thermoelectric module, junction of thermoelectric material and electrodes is one of the issues. Because of high- temperature use, superior solder capable of resisting the peak temperature of the system, and diffusion pressure welding and plasma flame coating techniques are necessary. At present, fuel saving of nearly 5% is possible. 11 refs., 8 figs.

  6. Rapid production of metallurgical coke by use of a simulated moving bed reactor. Mogi idoso wo mochiita kyusoku shoon ni yoru cokes no jinsoku seizo

    Energy Technology Data Exchange (ETDEWEB)

    Miura, K.; Hayashi, J.; Sano, N. (Kyoto University, Kyoto (Japan). Research Laboratory of CArbonaceous Resources Conversion); Hashimoto, K. (Kyoto University, Kyoto (Japan). Faculty of Engineering); Iwakiri, H. (Kobe Steel, Ltd., Kobe (Japan))


    An experiment to manufacture coke with rapid temperature raising was carried out using an equipment simulating a vertical moving bed coke oven. Two kinds of trial manufacturing patterns were tested: Pattern A to raise coal temperature rapidly to about 450[degree]C, which is held for about 20 minutes, and then raised again to 800[degree]C at a rate of about 5[degree]C/min, and pattern B to raise the temperature from about 300[degree]C to 800[degree]C at a rate of about 5[degree]C/min. An experiment on test samples from heavy caking coal (PDH coal) and light caking coal (OP coal) revealed the following results: The PDH coal applied with the pattern A produced in about two hours a coke with quality equivalent to or better than practically used coke; the temperature raising pattern B resulted in no full lump formation even with the PDH coal; according to the temperature raising pattern A, manufacturing coke from the OP coal is impossible; however, if the PDH coal or pitch is mixed with the OP coal, coke may be manufactured. 6 refs., 11 figs., 2 tabs.

  7. High resolution seismic refraction method with multichannel digital data acquisition system; Digital ta channel sokutei system wo mochiita koseido kussetsuho jishin tansa

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, K. [Oyo Corp., Tokyo (Japan)


    This paper introduces a multichannel digital data acquisition system and examples of measurements with the system in seismic exploration using the high resolution seismic refraction method. The high resolution seismic refraction system performs analyses nearly automatically by using a computer after initial travel time has been read. Therefore, the system requires high-accuracy travel time data, for which a multichannel digital measuring instrument developed recently for seismic exploration using the refraction method has been used for the measurement. The specification specifies the number of channels at 144 as a maximum, a sampling time of 62.5 {mu}sec to 4 m sec, the maximum number of sampling of 80,000 samples, and gain accuracy of {plus_minus} 1%. The system was used for surveying a tunnel having a maximum soil cover of about 800 m. The traverse line length is about 6 km, the distance between vibration receiving points is 50 m, and the number of vibration receiving points is 194. Executing measurements of single point system using GPS can derive accurate velocity in the vicinity of the basic face of the tunnel construction. Results were obtained from the investigation, which can serve more for actual construction work. 10 refs., 6 figs., 1 tab.

  8. Laboratory study on streaming potential for exploring underground water flow; Shitsunai jikken ni yoru ryudo den`i wo mochiita mizu michi tansa no kanosei no kento

    Energy Technology Data Exchange (ETDEWEB)

    Sato, H.; Shima, H. [Oyo Corp., Tokyo (Japan)


    To investigate a possibility of exploration of underground water flow as well as to grasp the underground fluid flow by measuring streaming potential at the ground surface, some experiments were conducted using a model unit by considering the difference of permeability. For this experimental unit, water is driven by adding head difference between the polyethylene vessel filled with water and the experimental water tank. The size of water tank is 350{times}160 mm with a height of 160 mm. Twenty platinum electrodes are set on the cover of water tank. Toyoura standard sand and Kanto loam were used for the experiments. For the experiments, fluid was injected in various combined models by considering the permeability, to measure the streaming potential. As a result, it was explained by the streaming potential that the fluid flows in a form of laminar flow in the experimental water tank, and that the movement of fluid in the Kanto loam is quite slow. It was also confirmed that the streaming potential method is an effective technique for grasping the movement of fluid. 3 refs., 8 figs.

  9. Static shift correction of MT data in Tohoku district using TEM soundings; TEM ho data wo mochiita Tohoku chiho MT ho data no statistic shift hosei

    Energy Technology Data Exchange (ETDEWEB)

    Kawakami, N.; Kumekawa, Y.; Miura, Y.; Takasugi, S. [GERD Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Fujinawa, Y. [National Research Institute for Disaster Prevention, Tsukuba (Japan)


    There is a possibility that the wide-band MT observation data obtained in the central part of Tohoku district include the static shift effect. To grasp the static shift effect in the MT data, the TEM soundings were conducted at all the site where the MT data were measured. The TEM sounding system was developed for the shallow survey depth ranging from 5 m to 150 m. When showing the measured results on the histogram, it was found that the static shifts were concentrated in the vicinity of zero. About 70% of the data was below 0.2 decade. Only a slight static shift effect was observed. This means that the results obtained by the two-dimensional analysis are plausible. Especially, the static shift around plain was small. Therefore, the current results around the plain were trustful. On the other hand, the static shift in the mountainous area was rather large. Accordingly, the results around the mountainous area should be carefully treated. 7 refs., 10 figs.

  10. Fundamental study of interpretation technique for 3-D magnetotelluric data using neural networks; Neural network wo mochiita sanjigen MT ho data kaishaku gijutsu no kisoteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, T.; Fukuoka, K.; Shima, H. [Oyo Corp., Tokyo (Japan); Mogi, T. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Spichak, V.


    The research and development have been conducted to apply neural networks to interpretation technique for 3-D MT data. In this study, a data base of various data was made from the numerical modeling of 3-D fault model, and the data base management system was constructed. In addition, an unsupervised neural network for treating noise and a supervised neural network for estimating fault parameters such as dip, strike and specific resistance were made, and a basic neural network system was constructed. As a result of the application to the various data, basically sufficient performance for estimating the fault parameters was confirmed. Thus, the optimum MT data for this system were selected. In future, it is necessary to investigate the optimum model and the number of models for learning these neural networks. 3 refs., 5 figs., 2 tabs.

  11. Analogue experiment of the crustal deformation by X-ray CT; X sen CT wo mochiita chikaku no henkei no analogue jikken

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, Y.; Shi, B; Murakami, Y. [Geological Survey of Japan, Tsukuba (Japan)


    This paper reports a predictive result on a deformation experiment on sand beds using an X-ray computerized tomography (CT) equipment. The X-ray CT is a method to perform the following processes: X-rays are irradiated on a sample; decayed intensity data are measured along ray paths of the permeated X-rays; the data are inverted by using the Fourier transform; and spatial distribution of the coefficient of X-ray absorption inside the sample is acquired as a gray scale image. The deformation experiment was carried by putting sand into an acrylic container to a depth of 2 cm and manually pressing a plate in the horizontal direction. Sand blocks make a relative motion along a specific plane when they are deformed, but it was not possible to recognize faults clearly by naked eyes. Upon completion of the deformation, the experimental device was placed on the CT equipment to acquire images of the two-dimensional cross section. The higher the X-ray absorption coefficient, the brighter the picture elements. It can be seen that three inversed faults have been imaged clearly. Therefore, this equipment was verified usable as an effective observation equipment for an analogue deformation experiment. 4 refs., 2 figs.

  12. Hydrogenation of carbon monoxide over mixed catalysts. Co-Ni/MnO-ZrO sub 2 to zeolite kara naru kongo shokubai wo mochiita issankatanso no suisoka

    Energy Technology Data Exchange (ETDEWEB)

    Ishihara, T.; Iwakuni, H.; Eguchi, K.; Arai, H. (Graduate School of Engineering Sciences, Kyushu Univ., Fukuoka (Japan). Department of Materials Science and Technology)


    The mechanical mixtures of Co-Ni/MnO-ZrO {sub 2} and zeolite were used as catalysts for the selective synthesis of gasoline by CO hydrogenation. Formation of branched-paraffins was promoted but that of higher hydrocarbons than carbon number of 10 was suppressed by combination with zeolite. The product distribution strongly depended on the type of zeolite catalyst. Pentasil zeolite was active for the formation of branched-paraffins, probably because of the cracking reaction occurring on the strong acid sites. The formation of branched paraffin was further promoted by ion-exchange with Pt. The mixture of Co-Ni/MnO-ZrO {sub 2} and PtH-pentasil zeolite was very active for the formation of gasoline with high octane number. 34 refs., 10 figs., 2 tabs.

  13. Development of spherical fine powders by high-pressure water atomization using swirl water jet; Senkaisui jet wo mochiita koatsusui atomize ni yoru kyujo bifun no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kikukawa, M.; Matsumoto, S.; Inaba, T.; Iwatsu, O.; Takeda, T. [Fukuda Metal Foil and Powder Co. Ltd., Kyoto (Japan)


    In order to obtain spherical fine powders, a new high-pressure water atomization method using swirl water jet was developed. In this paper the effects of jet swirl angle ({omega}) upon the properties of powders were investigated. Cu-10 mass%Sn alloy was atomized by this method at the constant water pressure of 83.3 MPa and constant metal orifice diameter of 4mm, while {omega} was varied from 0 to 0.18 rad. Median diameter of the powder by the laser diffraction method (D{sub 50}) decreased from 12.5 {mu}m to 7.5{mu}m with increasing {omega}, and this corresponded to Fisher average diameter (D{sub FS}) at about w=0.18 rad. The apparent and tap density of the powder increased about 1 and 1.5 Mg/m{sup 3} respectively, and the particle shape observed by SEM became spherical with increasing {omega}. (author)

  14. Model construction for quality of beer and brewing process using FNN; FNN wo mochiita biru hinshitsu to jozo kotei no moderuka

    Energy Technology Data Exchange (ETDEWEB)

    Noguchi, H.; Hanai, T.; Takahashi, W.; Honda, H.; Kobayashi, T. [Nagoya Univ., Nagoya (Japan). Dept. of Biotechnology; Ichii, T.; Tanikawa, M.; Masuoka, S. [KIRIN Brewery Corp., Tokyo (Japan). Research Laboratory for New Product


    Models for sensory evaluation of beer and the beer brewing process were constructed using a fuzzy neural network (FNN). A new method for optimal model selection using a genetic algorithm and a SWEEP operator method was compared with a conventional method using the parameter increasing method. As the result, the new method was useful for the optimal model selection by simplifying the model structure, improving the reliability of fuzzy rules, and accelerating the calculation speed (about 10 times as fast as conventional method) for constructing the model with high accuracy. The percentage of correct answers of the sensory evaluation model is 92 %. The important variables are selected as the input variables, and the obtained fuzzy rules in modeling coincide well with knowledge data bases acquired by process operators, and it is proven that the obtained FNN models are adequate. (author)

  15. Solubilization of lignite and behavior of oxygen containing functional groups in coal with superacid; Chokyosan wo mochiita kattan no kayoka oyobi sanso kannoki no kyodo

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, K.; Saito, I. [National Institute for Resources and Environment, Tsukuba (Japan); Sasaki, S.; Suganuma, A. [Science University of Tokyo, Tokyo (Japan). Faculty of Science and Technology


    Solubilization of lignite including a large amount of oxygen containing functional groups was attempted using HF/BF3, and the behavior of oxygen containing functional group, one of the important factors for coal liquefaction, was studied. In experiment, the cooled slurry of Yallourn coal specimen and solvent (toluene, isopentane) was filled into a vacuum autoclave together with HF/BF3. Reaction was performed under spontaneous pressure at 50, 100 or 150{degree}C for 3 hours. The distribution of oxygen containing functional groups in each coal specimen was determined by quantification of carboxyl group, hydroxyl group and carbonyl group. As the experimental result, the superacid mixture of HF and BF3 considerably improved the solubility of coal specimens into solvent as compared with individual HF and BF3. The solubility was 68wt% into benzene, 96% into THF and 99% (nearly 100%) into pyridine. It was suggested that production of Broensted acid with strong acidity causes strong catalysis. 6 refs., 2 figs., 1 tab.

  16. Estimation of hydrogen bondings in coal utilizing FTir and differential scanning calorimetry (DSC); FTir to DSC wo mochiita sekitannai suiso ketsugo no teiryoteki hyoka no kokoromi

    Energy Technology Data Exchange (ETDEWEB)

    Mae, K.; Miura, K. [Kyoto University, Kyoto (Japan). Faculty of Engineering


    With an objective to know coal condensation structure which has influence on coal conversion reaction, an attempt was made on quantitative evaluation of hydrogen bonding in coal. Using as test samples the VDC made from Taiheiyo coal swollen by tetralin and vacuum-dried, and its pyrolyzed char, DSC measurement and Fourier transform infrared spectroscopy (FT) were performed. An FT spectrum comparison revealed that the VDC swollen at 220{degree}C has the hydrogen bonding relaxed partly from the original coal. However, since the change is in a huge coal molecular structure restraining space, it has stopped at relaxation of the bonding energy without causing separation as far as free radicals. On the other hand, the DSC curve shows that the VDC has slower endothermic velocity than the original coal. In other words, the difference in heat absorption amounts in both materials is equivalent to the difference of enthalpy ({Delta} H) of both materials, which corresponds to the relaxation of the hydrogen bonding. Therefore, the {Delta} H was related to wavenumber shift of the FT spectra (which corresponds to change in the hydrogen bonding condition). By using this relationship, a method for evaluating hydrogen bonding distribution was proposed from an O-H contracting vibration change that can be measured by using the FT spectra and a thermal change that can be measured by using the DSC. 3 refs., 7 figs.

  17. Development of liquefaction process of coal and biomass in supercritical water; Chorinkaisui wo mochiita sekitan biomass doji ekika process no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nonaka, H.; Matsumura, Y.; Tsutsumi, A.; Yoshida, K. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering; Masuno, Y.; Inaba, A. [National Institute for Resources and Environment, Tsukuba (Japan)


    Liquefaction of coal and biomass in supercritical water has been investigated, in which strong solubilization force of supercritical water against hydrocarbons is utilized. Free radicals are formed through the cleavage of covalent bonds in coal under the heating condition at around 400{degree}C during coal liquefaction. It is important to stabilize these unstable intermediate products by hydrogen transfer. On the other hand, hydrogen is not required for the liquefaction of biomass having higher H/C atomic ratio and oxygen content than those of coal. Co-liquefaction of coal and biomass was conducted using supercritical water, in which excess hydrogen from the liquefaction of biomass would be transferred to coal, resulting in the effective liquefaction of coal. Mixture of coal and cellulose was liquefied in supercritical water at 390{degree}C under the pressure of 25 MPa using a semi-continuous reactor, and the results were compared with those from the separate liquefaction of them. The co-liquefaction of coal and cellulose did not show any difference in the residue yield from the separate liquefaction of these, but led to the increased production of compounds with lower molecular weight. The liquefaction was completed in 15 minutes. 5 refs., 3 figs., 3 tabs.

  18. H{infinity} control with exact linearization for AC drive system with CSI; Genmitsuna senkeika wo mochiita denryugata inverter kudo yudo dendokikei no H{infinity} seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Z.; Ide, K.; Yong, Z.; Tsuji, T. [Kyushu Institute of Technology, Kitakyushu (Japan)


    This paper reports the following method for controlling the vector of a current system inverter driven induction motor. The method deals with parameter variation in the control object and modeling error by using the H{infinity} control on its approximated linear model (in the vicinity of the equilibrium point), and handles disturbances including load variation by broadening the effective region in the linear model via close linearization of the state space. The paper explains specifically a design of a speed controller through modeling the control system of the induction motor including the current system inverter (connected to a converter), close linearization of the resultant nonlinear model (using rotation angle speed of the induction motor and DC link current as the state vectors, and using the output voltage of the converter as a scaler input), and application of the H{infinity} theory. In addition, the paper presents the result of an experiment that verified good control performance of the designed controller. 11 refs., 8 figs., 1 tab.

  19. Numerical analysis of the flow in a poppet valve using a streamline coordinate system; Ryusen zahyo wo mochiita pet bennai no nagare no suchi kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Yu, K.; Takahashi, K.; Nonoshita, T.; Ikeo, S. [Sophia Univ., Tokyo (Japan)


    The present paper describes the numerical analysis of the flow through a poppet valve by a streamline-coordinate system. Using this system, poppet valves with various shapes can easily be analysed, because a streamline along a solid wall or a free surface can be chosen as a coordinate. Parameters used in this analysis are poppet shape (cone angle for conical type and radius for spherical type), seat chamfer width, seat chamfer angle, valve lift and flow rate. Discharge coefficients and flow forces acting on poppets were analysed in detail, The computed results were in good agreement with the experimental ones. The conclusions are as follows: The flow forces on the poppet decrease with an increase in valve lift; The flow force on the conical poppet with a sharp edge seat is larger than that with a chamfered seat; The flow force is almost independent of flow rate for sharp edge seat, but strongly dependent for chamfered seat. (author)

  20. Real-time realization of scale detection based on comb filters using DSPs; Kushigata filter ni motozuku DSP wo mochiita real time onkai kenshutsu

    Energy Technology Data Exchange (ETDEWEB)

    Saito, T.; Matsui, T. [Toyota National College of Technology, Aichi (Japan); Honda, H.; Tadokoro, Y. [Toyohashi Univ. of Technology (Japan)


    Transcription is an operation to collect a music from tones played by a music instrument. It is not easy for a person to collect the music correctly as special knowledge and experience are necessary. Therefore, studies on an automatic transcription by a computer are being conducted now. In this paper, a scale detection method eliminating multiple frequencies by a comb filter is proposed. The characteristics of this system are as follows. It samples corresponding to the music scale, using the differences of sampling points to estimate the music scale. And, owing to use of the comb filter, it is a scale detection method without influences of multiple frequencies composed in the tones played by a music instrument. This paper describes the realization of the comb filter by over sampling and its application onto a harmony detection. Based on this scale detection method, a real time scale detection method using DSPs may be realized and scale detection applicable to real scale of a key board may be possible. 10 refs., 14 figs., 1 tab.

  1. Evaluation of the force rum flotation result by the ion exchange using the rubidium; Rubijiumu wo mochiita ion kokan ni yoru karamu fusen kekka no hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Kamiyama, Jun' ichi [Osaka University, Osaka (Japan); Fujimoto, Hidekazu; Matsukata, Masahiko


    The following are contained: Hydroxyl group and carbonyl, functional oxygen group and mineral like the carboxyl group in which the coal is the hydrophilic component. The column flotation result is greatly different, since existence proportion of these components is different by the coal type. We regarded it as whether it could not simply evaluate the force rum flotation result of the coal at area proportion of the syneresis site on the coal particle exterior. In this study, the force rum flotation was carried out using balance wheel (bituminous coal), mountain west (anthracite), bituminous coal, and Illinois (lignit) charcoal it is almost same (bituminous coal). The ladder of carbon material recovery rate was the balance wheel > Kawanishi > almost same > Illinois charcoal. Next, area proportion ({alpha}{sub ex-OH}, {alpha}{sub in-OH} respectively) of the hydrophilic site in coal particle exterior and particle inside {alpha}{sub ex-OH} was obtained. In case of the almost same charcoal, was bigger than {alpha}{sub in-OH}. It seems to slightly oxidize the particle surface the almost same charcoal. In 3 kinds of bituminous coal, the ladder of carbon material recovery rate and {alpha}{sub in-OH} agreed. However, it is necessary to consider not only area proportion but also wettability of the hydrophobic site of the hydrophilic site for the planktonic of mountain west charcoal which is the anthracite. (translated by NEDO)

  2. Toxicity evaluation of chlorinated organic compounds using immortalized rat hepatocytes; Fushika rat kansaibo wo mochiita yuki enso kagobutsu no dokusei hyoka no kokoromi

    Energy Technology Data Exchange (ETDEWEB)

    Sone, H.; Nakajima, M.; Yonemoto, J. [National Institute for Environmental Studies, Tsukuba (Japan)


    Chlorinated organic compounds has high priority for toxicity screening among environmental hazardous chemicals. In the present study, we used immortalized rat hepatocytes as a liver model in vitro to evaluate the toxicity of nine chlorinated organic compounds. Toxicity of nine chlorinated organic compounds were evaluated to cellular viability of immortalized rat hapatocytes. The potency of the toxicity based on 50% inhibitory concentration (IC50) value was in the following order: triclocalban>triclosan>3,4-dichloroaniline>2,5-diclorophenol> 2,5-dichloroanisole>p-dichlorobenzene> p-chloroaniline>o-dichlorobenzene=tris (2-chloroethyl) phosphate. The rank order of cytotoxic potency of nine chemicals was compared with toxicity information using animals. The rank order of cytotoxic potency did not relative to the order referenced mean lethal dose (LD50) as an index of acute toxicity of rats or mice. However, the rank order of cytotoxic potency relatively correlated non-observed adverse effect level (NOAEL) under the exposure duration adjusted for chronic toxicity in vivo. These data suggests that the origin of testing cell had better to make match target organ of toxic chemicals for extrapolation from data of bioassay in vitro to in vivo. 16 refs., 2 figs., 3 tabs.

  3. Improvement of combustion in a direct injection diesel engine by micro-hole nozzle; Micro hole nozzle wo mochiita chokusetsu funshashiki diesel kikan no nensho kaizen

    Energy Technology Data Exchange (ETDEWEB)

    Murata, M. [Keio University, Tokyo (Japan); Kobori, S. [Tokyo Institute of Technology, Tokyo (Japan); Iida, N. [Keio University, Tokyo (Japan). Faculty of Science and Technology


    In an attempt to promote the atomization of fuel spray and the mixing of fuel and air in diesel engines, a micro-hole nozzle which has orifices with a diameter smaller than 0.10mm was developed. In this study, the combustion tests were carried out using a single cylinder diesel engine equipped with a micro-hole nozzle and a common rail type high-pressure fuel injection system. A comparison with the results of a conventional nozzle experiment showed that the peak of initial premixed combustion increased, but the peak of diffusion combustion decreased. As a result, when nozzle orifice diameter become small from {phi} 0.15 mm to {phi} 0.10 mm, the combustion was accompanied by smokeless with the same levels of NO{sub x} emission and fuel economy. And results of a comparison the toroidal type chamber with the shallow dish type chamber revealed that the optimization of combustion chamber is necessary for the increase of the injection stage with increasing of the number of nozzle orifice. If an orifice diameter becomes {phi} 0.06 mm, the diffusion combustion can not be observed and the combustion is formed of only premixed combustion. The combustion in the case of {phi} 0.06 mm was accompanied with the drastic deterioration of fuel economy, smoke and HC with all over load. But the micro-hole nozzle has a potential for the formation of the lean and homogeneous premixed mixture until the fuel-air mixture ignites. (author)

  4. Emission behavior of OH radical in internal EGR using a 2-cycle engine; 2 cycle engine wo mochiita naibu EGR no OH radical no hakko kyodo

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, S.; Amino, Y.; Yoshida, K.; Shoji, H.; Saima, A. [Nihon University, Tokyo (Japan)


    The purpose of this study was to examine and consider the influence, which the remained gas exercised on combustion. 2-cycle engine was Used as the test engine. Internal EGR was run. The means was that the test engine was fitted the back pressure control plate on the exhaust port. The conditions, which were run with internal EGR and without internal EGR, were compared. The OH radical, which plays important role in combustion of hydrocarbon fuels, was measured with emission spectroscopy. In internal EGR, the unburned end gas on exhaust port side was susceptible to the remained gas. 6 refs., 8 figs., 1 tab.

  5. Power system stabilizing control by superconducting magnetic energy storage using neural network; Newral network wo mochiita chodendo energy chozo sochi ni yoru keito anteika seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Osawa, Y.; Kanemitsu, T.; Kawakami, T.; Shintaku, M.; Arai, K. [Kobe University, Kobe (Japan)


    In order to solve the difficulty of realizing power system stabilization using non-linear optimal control, this paper discusses a power system stabilization control by superconducting magnetic energy storage (SMES) using a neural network. This system consists of a kind of feedback control system that derives an optimal stabilizing control on various initial system operating conditions and failure conditions applied with the maximum principles, and learns the best stabilization using the control as tutorial signals and using the neural network. The object model system is a one-unit infinite busbar system, whose generator terminal is installed with the SMES. With respect to the system learning using the neural network, the network output to the learned failure patterns has agreed with the tutorial signals nearly completely. As a result of simulating example systems, it was confirmed that the operating conditions within a reasonable range and failure conditions were learned well, control effects close to the optimal control were shown, and the oscillation suppressing effect of the SMES can be utilized effectively. 11 refs., 13 figs., 4 tabs.

  6. Three-dimensional mise-a-la-masse modeling using horizontal well; Suihei kosei wo mochiita ryuden den`iho no sanjigen modeling

    Energy Technology Data Exchange (ETDEWEB)

    Mizunaga, H.; Ushijima, K.; Hashimoto, K.; Masuda, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering


    The 3-D model program was developed to apply a mise-a-la-masse method to linear current sources with optional shapes. Mise-a-la-masse method is a bipolar mapping survey method using current sources installed in wells, and recently has been widely used for direct exploration of geothermal reservoirs. This method is also used for monitoring underground fluid as electrode arrangement of fluid flow tomography for surveying underground fluid (geothermal fluid, underground water, petroleum). In the geothermal reservoir exploration, the casing pipes of wells are used as linear current sources, and measured data are processed as those based on vertical current source. In the largely inclined well, the inclination of current sources should be considered. The 3-D modeling program was developed by difference calculus using the theoretical potential equation and apparent resistivity based on linear current sources with optional 3-D shapes. The numerical model experiment result clarified that the previous theoretical equation for vertical wells is inapplicable to inclined linear current sources because of clear asymmetric apparent resistivity distribution. 6 refs., 6 figs.

  7. Study of seismic data acquisition using physical modeling system; Butsuri model jikken sochi wo mochiita data shutoku gijutsu ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Tsukui, R.; Tsuru, T. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center; Matsuoka, T [Japan Petroleum Exploration Corp., Tokyo (Japan)


    For the physical modeling system of Technology Research Center, Japan National Oil Corporation, data acquisition on the ocean and ground can be simulated using models. This system can provide data for verification of the data processing and elastic wave simulation algorithm. This can also provide data for decision of experiment specifications by making a model simulating the underground structure of the given test field. The model used for the physical modeling system is a gradient multilayer model with six-layer structure. Depth migration before stacking was conducted using data obtained through two acquisition methods, i.e., up-dip acquisition and down-dip acquisition. The depth migration before stacking was performed for data obtained by up-dip acquisition in addition to the records obtained by down-dip acquisition. Consequently, a definite reflection surface was observed, which has not been observed from the processing results of down-dip acquisition data. 9 figs.

  8. Relative amplitude preservation processing utilizing surface consistent amplitude correction. Part 3; Surface consistent amplitude correction wo mochiita sotai shinpuku hozon shori. 3

    Energy Technology Data Exchange (ETDEWEB)

    Saeki, T. [Japan National Oil Corporation, Tokyo (Japan). Technology Research Center


    For the seismic reflection method conducted on the ground surface, generator and geophone are set on the surface. The observed waveforms are affected by the ground surface and surface layer. Therefore, it is required for discussing physical properties of the deep underground to remove the influence of surface layer, preliminarily. For the surface consistent amplitude correction, properties of the generator and geophone were removed by assuming that the observed waveforms can be expressed by equations of convolution. This is a correction method to obtain records without affected by the surface conditions. In response to analysis and correction of waveforms, wavelet conversion was examined. Using the amplitude patterns after correction, the significant signal region, noise dominant region, and surface wave dominant region would be separated each other. Since the amplitude values after correction of values in the significant signal region have only small variation, a representative value can be given. This can be used for analyzing the surface consistent amplitude correction. Efficiency of the process can be enhanced by considering the change of frequency. 3 refs., 5 figs.

  9. Study of 1D complex resistivity inversion using digital linear filter technique; Linear filter ho wo mochiita fukusohi teiko no gyakukaisekiho no kento

    Energy Technology Data Exchange (ETDEWEB)

    Sakurai, K.; Shima, H. [OYO Corp., Tokyo (Japan)


    This paper proposes a modeling method of one-dimensional complex resistivity using linear filter technique which has been extended to the complex resistivity. In addition, a numerical test of inversion was conducted using the monitoring results, to discuss the measured frequency band. Linear filter technique is a method by which theoretical potential can be calculated for stratified structures, and it is widely used for the one-dimensional analysis of dc electrical exploration. The modeling can be carried out only using values of complex resistivity without using values of potential. In this study, a bipolar method was employed as a configuration of electrodes. The numerical test of one-dimensional complex resistivity inversion was conducted using the formulated modeling. A three-layered structure model was used as a numerical model. A multi-layer structure with a thickness of 5 m was analyzed on the basis of apparent complex resistivity calculated from the model. From the results of numerical test, it was found that both the chargeability and the time constant agreed well with those of the original model. A trade-off was observed between the chargeability and the time constant at the stage of convergence. 3 refs., 9 figs., 1 tab.

  10. Imaging of lateral heterogeneity by using reflected surface waves. Hansha hyomenha wo mochiita suihei hoko no chika kozo fukinshitsusei no kenshutsu

    Energy Technology Data Exchange (ETDEWEB)

    Shiba, Y. (Central Research Institute of Electric Power Industry, Tokyo (Japan)); Kobayashi, Y. (Kyoto Univ., Kyoto (Japan). Faculty of Science)


    Surface wave holography was applied to the reflected surface waves obtained on the Uji ground, Kyoto University. Clear reflected surface waves were confirmed in the records of waves and it was found possible to detect the surface waves generated by an artificial hypocenter. The reflected waves consisted of two groups having different frequency zones, which were the reflected waves from two different reflectors. It is clear from this result that in the case of the reflected wave groups due to the multiple scatterers, the surface wave holography enables to determine the corresponding locations of respective scatterers. The combination of the back projection method using the reflected wave envelopes and the other method such as incident angles to the array is most effective as the analyzing method. The surface wave holography can be used sufficiently to detect the lateral heterogeneity. 17 refs., 12 figs., 4 tabs.

  11. Interactive steering of supercomputing simulation for aerodynamic noise radiated from square cylinder; Supercomputer wo mochiita steering system ni yoru kakuchu kara hoshasareru kurikion no suchi kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Yokono, Y. [Toshiba Corp., Tokyo (Japan); Fujita, H. [Tokyo Inst. of Technology, Tokyo (Japan). Precision Engineering Lab.


    This paper describes extensive computer simulation for aerodynamic noise radiated from a square cylinder using an interactive steering supercomputing simulation system. The unsteady incompressible three-dimensional Navier-Stokes equations are solved by the finite volume method using a steering system which can visualize the numerical process during calculation and alter the numerical parameter. Using the fluctuating surface pressure of the square cylinder, the farfield sound pressure is calculated based on Lighthill-Curle`s equation. The results are compared with those of low noise wind tunnel experiments, and good agreement is observed for the peak spectrum frequency of the sound pressure level. 14 refs., 10 figs.

  12. Solar cells and thin film LED using amorphous SiC. Amorphous SiC wo mochiita taiyou denchi oyobi usumaku LED

    Energy Technology Data Exchange (ETDEWEB)

    Hamakawa, Y. (Osaka Univ., Osaka (Japan). Faculty of Engineering Science)


    This paper introduced the photoelectric properties of amorphous SiC (a-SiC), application to highly efficient solar cells, application to wide area emitting elements such as LED (light emitting diode) and application to OEIC (optoelectronic integrated circuit) which is expected in near future. The light sensitizing effect in which photoconductivity of a-SiC:H film increases 2-3 figures by B dopping, was found. Flexible and wide area thin film LED has been able to manufacture by this discovery. In addition, highly efficient conversion rate has been able to get by the technical development such as solar cells made of a-SiC/ a-Si hetrojunction. Further, wide area sollar cells has been able to manufacture on any substrate by the development of TFLED (thin film light emitting diode). The application of TFLED made of SiC to OEIC is also investigated. 18 refs., 15 figs., 2 tabs.

  13. Thermal and aqua-reserve characteristics of an aqua-reserver using a super-absorbent polymer gel; Kokyusuisei jushi wo mochiita hosuizai no hosui netsutokusei

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Z. [Tokyo Metropolitan Univ., Tokyo (Japan); Asako, Y.; Yamaguchi, Y.; Yoshida, H. [Tokyo Metropolitan Univ., Tokyo (Japan). Faculty of Technology


    This paper describes thermal and aqua-reserve characteristics of a super-absorbent polymer gel which absorbs an aqueous solution of calcium chloride as a heat absorbent in a firewall during fire. Only gels which absorbed 10 to 40 mass% of the solutions were tested. The absorbency of the polymer and latent heat of the gel were measured using a thermal analyzer of TG/DTA. To obtain the aqua-reserve characteristics, changes in weight of the gel which was left in a room under controlled temperature was measured. Also, an equilibrium concentration of the calcium chloride solution in the gel was obtained. 8 refs., 12 figs., 3 tabs.

  14. Analysis of the pollutant in the environment using supercritical fluid chromatography (SFC); Chorinkai ryutai kuromatogurafui (SFC) wo mochiita kankyo chu no osen busshitsu no bunseki

    Energy Technology Data Exchange (ETDEWEB)

    Kakuchi, T.; Miura, Y. [Hokkaido Univ., Hokkaido (Japan)


    The analysis of the organic pollutant in the environment is carried out as the following procedure; the organic substance is extracted by using the organic solvent from a collected sample, an instrument analysis such as gas chromatography (GC) or high performance liquid chromatography (HPLC) are done after the clean up the sample by column chromatography. The analysis using supercritical fluid instead of the organic solvent in each stage is supercritical fluid extraction (SFE) or supercritical fluid chromatography (SFC). The supercritical fluid has a density and viscosity coefficient between gas and liquid, and the control of the dissolving power is possible by the change of temperature and pressure. Therefore, it has the advantage as follows: The material mobile speed is high and separation and extraction are rapid; It is easy to adjust the dissolving power and possible to carry out selective separation and extraction; The removal of solvent can be easily carried out since supercritical CO{sub 2} used is a gas in the normal pressure. In this paper, the analytical instrument in which the extraction is carried out in organic solvent and clean up was done in SFC was introduced. (NEDO)

  15. Measurement of local strain-induced martensitic phase transformation by micro-hardness; Bisho kodo wo mochiita kyokusho hizumi yuki martensite hentai tokusei no sokutei

    Energy Technology Data Exchange (ETDEWEB)

    Shibutani, Y.; Taniyama, A.; Tomita, Y.; Adachi, T. [Kobe University, Kobe (Japan). Faculty of Engineering


    By the duplex effect produced by two kinds of phases of austenite and martensite, the transformation-induced plasticity (TRIP) steel is improved in ductility and fracture toughness. The strain-induced martensitic phase transformation could be associated with the strain localization behavior. Accordingly, the measurement of the amount of local transformation is necessary in order to construct a more physical evolution model in the constitutive equation. In this study, a new measurement system using a micro-hardness tester is proposed to obtain a volume fraction map of the martensitic phase expanding in the neighbor of strain localization. Then the system is applied to investigate the inhomogenous transformation behavior around the notch root of SUS 304 stainless steel bar under uniaxial tension. 27 refs., 11 figs., 1 tab.

  16. Improvement of prediction accuracy of large eddy simulation on colocated grids; Colocation koshi wo mochiita LES no keisan seido kaizen ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Inagaki, M.; Abe, K. [Toyota Central Research and Development Labs., Inc., Aichi (Japan)


    With the recent advances in computers, large eddy simulation (LES) has become applicable to engineering prediction. However, most cases of the engineering applications need to use the nonorthgonal curvilimear coordinate systems. The staggered grids, usually used in LES in the orthgonal coordinates, don`t keep conservative properties in the nonorthgonal curvilinear coordinates. On the other hand, the colocated grids can be applied in the nonorthgonal curvilinear coordinates without losing its conservative properties, although its prediction accuracy isn`t so high as the staggered grid`s in the orthgonal coordinates especially with the coarse grids. In this research, the discretization method of the colocated grids is modified to improve its prediction accuracy. Plane channel flows are simulated on four grids of different resolution using the modified colocated grids and the original colocated grids. The results show that the modified colocated grids have higher accuracy than the original colocated grids. 17 refs., 13 figs., 1 tab.

  17. Batch process. Batch plant scheduling using an intelligent system developing tool (G2); Interijento system kaihatsu tsuru ( G2 ) wo mochiita bacchi puranto sukejuringu

    Energy Technology Data Exchange (ETDEWEB)

    Fukuoka, H. [Itochu Technology Science Co. Ltd. (Japan)


    G2 is used in many industrial fields as a tool capable of forming in a comparatively short period of time various kinds of high-degree intelligent system including a scheduling system. This paper introduces G2, and then describes a batch scheduling system. The software techniques provided by G2 include the techniques concerning a real time system, an expert system, a graphic user interface, and object-oriented security network. G2 has a striking feature that it is a developing tool adapted to enable these software techniques to be utilized in a united environment. A program developed by G2 has a feature that it can be operated as it is without changing the source program at all even when the program is used in a machine of another OS. The paper introduces a beer production scheduling system as an actual example. 3 figs.

  18. Study of seismic data acquisition using physical modeling system; Butsuri model jikken sochi wo mochiita data shutoku gijutsu ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Tsukui, R.; Tsuru, T. [Tech. Research Center, Japan National Oil Corp., Tokyo (Japan); Matsuoka, T. [Japan Petroleum Exploration Corp., Tokyo (Japan)


    The Physical Modeling System introduced into the Technology Research Center, Japan National Oil Corporation, and data collected by use of the system are presented. The Physical Modeling System is 10,000 times smaller than the real one, comprising a water tub section, measuring device section, and control section, etc. The water tub section comprises a tub for housing the model, transducers for transmitting and receiving vibration, controllers, etc. The water tub measures 1.8{times}1.2{times}0.9m. The model used in the experiment is an `inclined multilayer model` with each of its six layers pinching out toward the top, and is usable for the comparison of various migration methods. In one case in the records, reception was made at 184 reception points deployed at intervals of 3mm, when the minimum offset was 15mm and the maximum offset 564mm. Nothing very obvious was observed when the ordinary overlapping of DMO and CDP was applied to this record, which suggests that pre-overlapping migration treatment is required. 5 figs.

  19. Proposal and study of a long-span composite cable-stayed bridge with new hybrid girder; Atarashii gosei kozo shuketa wo mochiita chodai fukugo shachokyo no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, K.; Hishiki, Y.; Furuichi, K. [Kajima Corp., Tokyo (Japan)


    A hybrid or mixed structure (composite structures) are a matter of increasing concern which takes in each advantage of steel and concrete. A field of bridges is no exception, with the plan and construction carried out for the new type of composite bridge, such as a composite cable-stayed bridge and a composite extra dose bridge as a long span bridge, and a composite truss bridge and a corrugated steel plate web bridge as a medium-span bridge, with technological development becoming active in this field. In such a technological trend, a hybrid two-girder structure was devised, a structure consisting of a concrete filled steel pipe for a girder and a precast (PC) floor plate for a floor board, as the girder structure of a long-span cable-stayed bridge in the subject research; also, applicability was examined using, as an example, the composite cable-stayed bridge with hybrid girders employed for the span. This paper reports the result of the analysis of the entire system, the analysis made for the purpose of examining the characteristic and the feasibility of this hybrid girder. The analysis revealed the structural feasibility of the long-span composite cable-stayed bridge using two hybrid girders of concrete-filled steel pipes thus devised. (NEDO)

  20. Analysis of signal transduction in brain cells using molecular signal microscope; Bunshi jiho kenbikyo wo mochiita nousaibou no joho henkan kiko no kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Kawato, Suguru [The University of Tokyo, Tokyo (Japan). Dept. of Biophysics and Life Sciences


    We analyzed the signal transduction in brain neurons by real-time imaging of Ca/NO signals using the Molecular Signal Microscope. We also analyzed synthesis and action of neurosteroids in the hippocampus. We discovered steroid synthesis machinery containing cytochrome P 450 scc in hippocampal neurons. We found that pregnenolone sulfate acutely potentiated NMDA receptor-mediated Ca conductivity in hippocampal neurons. We also found that stress steroid corticosterone acutely prolonged NMDA receptor-mediated Ca{sup 2+} influx, resulting in Ca-induced neuro-toxicity. (author)

  1. Investigation of the simulation for the solar DHW system by TRNSYS; TRNSYS ni yoru kaihogata tank wo mochiita solar kyuto system no simulation chosa

    Energy Technology Data Exchange (ETDEWEB)

    Oishi, M.; Noguchi, T. [Japan Quality Assurance Organization, Tokyo (Japan); Okumiya, M. [Nagoya University, Nagoya (Japan)


    With an objective of establishing a method for evaluating performance of a photovoltaic hot water supply system, a discussion was given on utilization of the simulation program, TRANSYS. The discussion was addressed on a photovoltaic hot water supply system of forcible circulation type using commercially available open-type heat storage tanks. An experiment was performed as an indoor test using an artificial solar light source. The TRANSYS makes available a type 04 which handles each node as a complete mixture by fixing and dividing the heat storage tank, and a type 38 which expresses heat transfer between temperature layers by means of piston flow as a heat transfer coefficient. Both types were subjected to calculation. The result of the discussion may be summarized as follows: both types provided values close to the experimental values of quantity of heat derived by utilizing solar heat; however, with the type 04, heat transfer cannot be modeled if the system is left still with temperature difference in the heat storage tank being large; and with the type 38, modeling is possible when the system is left still with temperature difference in the heat storage tank being large, but temperature gradient is difficult to be modeled during heat collection and when hot water is supplied. 1 ref., 7 figs., 5 tabs.

  2. On-line monitoring system of lactic acid fermentation by using integrated enzyme sons ors; Shusekika koso sensa wo mochiita nyusan hakko keisokuyo onrain monitaringu shisutemu

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Masayasu; Kumagi, Takeshi; Nakashima, Yuuichi [Kyushu University, Fukuoka (Japan). Dept. of Biochemical Engineering and Science


    An on-line monitoring system for lactic acid fermentation is developed by using integrated micro enzyme sensors, a flow injection analysis system, and a micro dialysis system. The calibration curves of micro glucose, lactose and lactate sensors show good linearity in the concentration range below 70 mM. By combination with the micro dialysis system, the enzyme sensors can measure the whole concentration range of lactic acid fermentation, and interference by the medium can not be observed. The on-line sensor system is then applied to lactic acid fermentation of Lactobacillus delbrueckii. The sensor system can monitor the glucose and lactate concentrations simultaneously during 24-h fermentation, and the measurements show good agreement with those of the conventional colorimetric method. The sensor system can also be applied to on-line monitoring of lactose and lactate during Lactobacillus lactis fermentation. (author)

  3. Monitoring on-line system for the lactic fermentation measurement using the integration enzyme sensor; Shusekika koso sensa wo mochiita nyusan hakko keisokuyo onrain monitringu shisutemu

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Masayasu; Kumagaya, Tsuyoshi; Nakajima, Yoichi [Kyushu Institute of Technology, Fukuoka (Japan)


    The monitoring on-line system for the lactic fermentation measurement in which the simultaneous measurement of the substrate. Generation was possible was constructed without consuming the culture medium by using soliciting small enzyme sensor and flow injection analysis system integrate. There was the linearity that anyway was also range of concentration of 70mM or less and that it is good on the calibration curve of minute glucose, lactose, and lactic acid sensor. It became clear that it proved that all range of concentration of the substrate of these three which combining with the micro diary system, breaks in the lactic fermentation measurement with the necessity can be measured and not observe the interference by medium components, etc. either. Constructed monitoring on-line system is Lactobacillus delbrueckii and, it was applied to the lactic fermentation process of Lactobacillus lactis. Through the fermentation process for 24 hours, simultaneous measurement of glucose (or lactose) and lactic acid is possible. The measured value agreed well with the result of colorimetric method using the enzyme. (translated by NEDO)

  4. Suspension bridge with floor slab using precast PC slab; Yukaban ni purekyasuto PC burokku wo mochiita tsuribashi {center_dot} shinonome sakurabashi/tochigiken mibumachi

    Energy Technology Data Exchange (ETDEWEB)



    As part of park improvement project of across of Kuro River flowing through Mibu Town of Tochigi Prefecture, a suspension bridge with floor plate using precast PC slab was erected. The size of floor block used is 5.5-7.5m in width, 2.5m in length, 14cm in thickness. 38 of these blocks were linked, resin was poured into joint, and stress was applied in bridge axis direction after hardening of resin. By prestressing, these floor slab had performance as reinforcing beam in normal loading condition, high rigidity of floor slab demonstrated excellent vibration stability. and enabled emergency vehicle traffic while this bridge is exclusively pedestrian use in normal time. Erection work was carried out in low water period of the river. Since the river can be reclaimed in low water period, most of erection work was carried out on land. Furthermore, utilizing advantages of precast slab, construction from erection of main tower to bridge completion was finished in only 3 months. (translated by NEDO)

  5. Study on detecting method of rail corrugation by using wavelet analysis; Wavelet kaiseki wo mochiita rail hajo mamo kenshutsu shuho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Suda, Y.; Okumura, M.; Komine, H.; Iwasa, T.; Terumichi, Y. [The University of Tokyo, Tokyo (Japan). Institute of Industrial Science; Qian, B. [The University of Tokyo, Tokyo (Japan)


    This paper reports the development of a method that detects the corrugation of a rail. A measurement test in which the track inspection car provided with an axle box accelerometer and irregular rail top face measurement equipment runs over the range of a specific section at the setting rate was conducted. A wavelet analysis is applied to the obtained acceleration data of vertical axle box vibration. The position of the generated corrugation was detected in a time base as the high position of a wavelet coefficient. Moreover, the dominant frequency range of corrugation was detected for each frequency by adding the wavelet coefficients in the whole position. This result was verified using the measurement data of an irregular rail top face. The wave height of corrugation can be estimated from the amplitude of the vertical vibration acceleration measured during low-speed traveling when the calculation result of a frequency response using the vertical vibration model in simplified wheel and rail systems is compared with the test result described above. 2 refs., 8 figs., 1 tab.

  6. Optimization of the ship type using waveform by means of Rankine source method; Rankine source ho ni yoru hakei wo mochiita funagata saitekika ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hirayama, A.; Eguchi, T. [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)


    Among the numerical calculation methods for steady-state wave-making problems, the panel shift Rankine source (PSRS) method has the advantages of rather precise determination of wave pattern of practical ship types, and short calculation period. The wave pattern around the hull was calculated by means of the PSRS method. The waveform analysis was carried out for the wave, to obtain an amplitude function of the original ship type. Based on the amplitude function, a ship type improvement method aiming at the optimization of ship type was provided using a conditional calculus of variation. A Series 60 (Cb=0.6) ship type was selected for the ship type improvement, to apply this technique. It was suggested that optimum design can be made for reducing the wave making resistance by means of this method. For the improvement of Series 60 ship type using this method, a great degree of reduction in the wave making resistance was recognized from the results of numerical waveform analysis. It was suggested that the ship type improvement aiming at the reduction of wave-making resistance can be made in shorter period and by smaller labor compared with the method using a waveform analysis of cistern tests. 5 refs., 9 figs.

  7. Construction of educational application system for calligraphy master based on virtual reality; Virtual reality wo mochiita shodo shutoku no tame no kyoikuteki oyo system no kochiku

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, T.; Muranaka, N.; Imanishi, S. [Kansai University, Osaka (Japan)


    Technique of virtual reality has been becoming popular in various fields including education because of its remarkable technique progress. There are the three useful elements of `presence`, `interaction` and `autonomy` in realizing the virtual reality. Here, we are focusing on the `presence` in constructing a simple supporting system for calligraphy education. We take advantage of the virtual image with reality to use as an educational interface because the virtual image and the real image are overlapped by showing the visual scene in the system. It is general that the unity of the virtual image and the real image has been processed as the stationary pictures by using `See-through HMD` and so on. In this paper, by using half mirror in stead of using the HMD with restraint, we are released from its restrainable sense. The virtual image and the real image are laid to overlap as the mobile pictures. The virtual hand replays the character inputted on the tablet by the excellent calligrapher. A calligraphic trainee is practicing overlapping the virtual hand which is reflected at the half mirror, while the trainee is doing the character on the tablet in the handwriting. The trainee is repeatedly practicing with feedback and is getting better in handwriting the character. It is shown in the good expermental results that the system has a proven effectiveness. 9 refs., 12 figs., 2 tabs.

  8. Digital data storage of core image using high resolution full color core scanner; Kokaizodo full color scanner wo mochiita core image no digital ka

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, W.; Ujo, S.; Osato, K.; Takasugi, S. [Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan)


    This paper reports on digitization of core images by using a new type core scanner system. This system consists of a core scanner unit (equipped with a CCD camera), a personal computer and ancillary devices. This is a modification of the old type system, with measurable core length made to 100 cm/3 scans, and resolution enhanced to 5100 pixels/m (1024 pixels/m in the old type). The camera was changed to that of a color specification, and the A/D conversion was improved to 24-bit full color. As a result of carrying out a detail reproduction test on digital images of this core scanner, it was found that objects can be identified at a level of about the size of pixels constituting the image in the case when the best contrast is obtained between the objects and the background, and that in an evaluation test on visibility of concaves and convexes on core surface, reproducibility is not very good in large concaves and convexes. 2 refs., 6 figs.

  9. Fabrication of band-pass filter using YBCO film at Ka-band frequency; YBCO hakumaku wo mochiita Ka-band taiiki tsuka fuiruta no sakusei

    Energy Technology Data Exchange (ETDEWEB)

    Yoshitake, T.; Hattori, W.; Murakami, S.; Suzuki, S. [NEC Corp., Tokyo (Japan)


    In this report, Ka band microstrip band pass filter was produced experimentally using an YBCO system high temperature superconductivity thin film as examination initial stage high temperature superconductivity a thin film superscription communication element. With it, the following were examined: Evaluation method and frequency characteristics of the filter. Especially, the examination on structure of the package and system of measurement using refrigerating machine becomes important in order to evaluate the filter with the high frequency. (NEDO)

  10. Development of cryocooler-cooled solenoid magnet fabricated with Bi-2212 ROSAT wire; Bi-2212 ROSAT wire wo mochiita reitoki dendo reikyaku sorenoido magunetto no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Azuma, K.; Morita, H.; Hara, N.; Okada, M. [Hitachi Ltd., Tokyo (Japan); Sato, J. [Hitachi Cable Ltd., Tokyo (Japan); Kitaguchi, H.; Kumakura, H.; Togano, K. [National Research Inst. for Metals, Tokyo (Japan)


    The asymmetry for external magnetic field is a small wire rod, while Bi-2212 ROSATwire keeps the transport current characteristics which tape wire rod is excellent. And, the wind ability becomes good by choosing the round cross section, and it is a wire rod, which is suitable for solenoidal coil. At present, refrigerating machine conduction cooling type solenoid magnet, which can generate central magnetic field 8T using this wire rod is developed. This time, the internal layer coil was manufactured, and the excitation test was carried out by the cooling system for the test. (NEDO)

  11. Development of superconducting magnets fabricated with PAIR processed Bi-2212/Ag multilayer tapes; PAIR purosesu Bi-2212/Ag taso senzai wo mochiita chodedo magunetto no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Otani, N.; Koizumi, T.; Hasegawa, T. [Showa Electric Wire and Cable Co., Ltd., Kanagawa (Japan); Kitaguchi, H.; Kumakura, H.; Togano, K. [National Research Inst. for Metals, Tokyo (Japan); Miao, H. [Japan Science and Tech. Corp., Tsukuba (Japan)


    Bi2212 oxide superconducting wire rod has large critical current density at 20K or less. It is expected as practical conductors such as high magnetic field insert magnet and refrigerating machine cryogenic magnet. PAIR process, which we developed, introduced spare baking and intermediate preforming into the fabrication process of Bi2212/Ag wire rod. The superconductivity of the multilayer tape wire rod was more and more greatly improved, and it brought it close to the use conductor of the practical magnet. This time, in the coil using this wire rod, in order to examine electromagnetic force countermeasure in the high magnetic field application, the CuAg tape of which tensile strength was often high was used as reinforcing agent, and 2 kinds of double pancake coil were produced thermal conductivity. The coil was energized and was tested in 4.2K, in the external magnetic field. (NEDO)

  12. Development of cryocooler-cooled solenoid magnet fabricated with Bi-2212 ROSAT wire (2); Bi-2212 ROSAT wire wo mochiita reitoki dendo reikyaku sorenoido magunetto no kaihatsu (2)

    Energy Technology Data Exchange (ETDEWEB)

    Morita, H.; Tanaka, K.; Hara, N. [Hitachi Ltd., Tokyo (JP)] [and others


    The asymmetry for external magnetic field is a small wire rod, while Bi-2212ROSATwire keeps the transport current characteristics which tape wire rod is excellent. And, the windability becomes good by choosing the round cross section, and it is goodwill wire rod in the solenoidal coil. At present, it develops refrigerating machine conduction cooling type solenoid magnet system using this wire rod. This time, it produced refrigerating machine conduction cooling system, which could install new internal layer coil using the wire rod improved and magnet of 3 layers. (NEDO)

  13. Development of resistive type superconducting fault current limiter using oxide superconductor; Sankabutsu chodendotai wo mochiita teikogata chodendo genryuki no kaihatsu -muyudo sorenoido koiru no shisaku shiken kekka

    Energy Technology Data Exchange (ETDEWEB)

    Yoneda, E.; Shimada, M.; Nomura, S. [Toshiba Corp., Tokyo (Japan); Okuma, T.; Sato, Y.; Iwata, Y. [Tokyo Electric Power Co., Inc., Tokyo (Japan)


    We have advanced the development of resistive superconductivity current limiter using the normal transition of the superconductor until now, and it has produced and tested 6.6kV/1kA single-phase current limiter using the metal system superconductor experimentally. As a result of these evaluations, in turning to the practical application of that the oxide superconductor was used from the metal system superconductor from the viewpoint of wire rod performance, refrigerating machine, insulation performance, it reached the advantageous conclusion. Here, it reports the result that it produced the mischievous prank non-induction coil model experimentally in the mind and tested coil resistance type current-limiting element using the oxide superconductor. (NEDO)

  14. Development of new finite element by source method. 2nd Report. Plate bending element; Source wo mochiita atarashii yugen yoso no kaihatsu. 2. Itamage yoso

    Energy Technology Data Exchange (ETDEWEB)

    Neki, I.; Tada, T. [Ishikawajima-Harima Heavy Industries Co. Ltd., Tokyo (Japan)


    This paper reports a method to develop a new finite element by source (FES) for a two-dimensional plane problem and a three-dimensional solid problem as a method to analyze ship body structures. The paper describes development of a plate bending element by using a similar method, and the fundamental principle thereof. The present method can prepare a finite element of an arbitrary shape by simply providing a contact point only on a boundary. It can also derive good calculation accuracy with less number of contact points and elements. These facts are shown by examples of analyses on a square plate, a triangle plate and a semi-circular plate. Particularly, since a plate bending problem has a large order of differential calculus in a governing equation, this method being a semi-analytical method derives a result with very good accuracy even with less number of contact points. A hypothetical boundary method or a hypothetical electric charge method presents not a very high accuracy even if a large number of contact points are provided. This is because the method hypothesizes only a bending moment vertical to the boundary, but does not consider a source of the moment relative to the boundary. In contrast, the present method hypothesizes both of bending and twisting as the sources, hence its accuracy is better than with the above two methods. 5 refs., 11 figs., 7 tabs.

  15. Co-generation system with a linear concentrator and thermoelectric elements; Senkei shukokei to netsuden henkan soshi wo mochiita netsuden heikyu system

    Energy Technology Data Exchange (ETDEWEB)

    Kachi, E.; Suzuki, A.; Fujibayashi, K. [Tokyo University of Agriculture and Technology, Tokyo (Japan)


    The co-generation system using a solar cell has the disadvantage that the performance of a cell element deteriorates when the temperature rises. Therefore, the co-generation system in which a BiTe thermoelectric element and linear Fresnel lens are used was constructed. Moreover, the basic characteristics were confirmed and the characteristics of a system model were analyzed. A thermoelectric element area must be reduced to improve the generating efficiency. The generating efficiency depends on the temperature difference between thermoelectric elements rather than the thermoelectric element area. As the thermoelectric area gets lower, the generating efficiency will get higher. This inclination is advantageous on the economic side. The generating efficiency becomes low during operation at high temperature. As a result, the temperature supplied to the thermal load is set to the lower position (100 to 200{degree}C) so as to advance the validity of the system. Even if the co-generation temperature is low, a heat supply capability of 150{degree}C is sufficient for an industrial heat supply system because it holds a large majority of the consumption demand for the whole industry. 3 refs., 8 figs., 3 tabs.

  16. Simulation study using 3-D wavefield modeling for oil and gas exploration; Sanjigen hadoba modeling wo mochiita sekiyu tanko no simulation study

    Energy Technology Data Exchange (ETDEWEB)

    Sato, T.; Matsuoka, T. [Japan Petroleum Exploration Corp., Tokyo (Japan); Saeki, T. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center


    As the surroundings of objects of oil exploration grow more complicated, seismic survey methods have turned 3-dimensional and, in this report, several models are examined using the 3-dimensional simulation technology. The result obtained by the conventional wave tracking method is different from actual wavefields, and is unrealistic. The difference method among the fullwave modelling methods demands an exorbitantly long computation time and high cost. A pseudospectral method has been developed which is superior to the difference method, and has been put to practical use thanks to the advent of parallel computers. It is found that a 3-dimensional survey is mandatory in describing faults. After examining the SEG/EAGE Salt model, it is learned that the salt is well-developed and that 3-dimensional depth migration is required for sub-salt exploration. It is also found through simulation of the EAGE/S Overthrust model, which is an elastic model, that no quality records are available on thrust zones in complicated terrains. The records are poor in quality since the actually measured wavefield is regarded as an acoustic wavefield when it is an elastic wavefield. 1 refs., 18 figs., 2 tabs.

  17. Density Measurements of Na2WO4-WO3-ZnO Melts

    Institute of Scientific and Technical Information of China (English)


    Based on Archimedes principle, the densities of Na2WO4-WO3-ZnO melts at a fixed mole ratio of 3.43 of Na2WO4 to ZnO were measured. The results indicated that there was a linear relationship between the densities and temperatures at a fixed composition. At a fixed temperature, the linear relationship between densities and compositions showed different slop within different composition regions. The reasons were explained in view of ionic composition changes.

  18. Electrochemical Preparation of WO_3 Nanowire Arrays

    Institute of Scientific and Technical Information of China (English)


    1 Results Ordered WO3 nanowires arrays have been fabricated by electrochemical deposition with anodic aluminum oxide (AAO) templates and annealing the W nanowire arrays in air at 400 ℃. The morphology and the chemical composition of WO3 nanowires arrays were characterized by Scanning Electron Microscopy (SEM),Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), and X-ray diffraction (XRD). The results show that the diameters of the WO3 nanowires are about 90 nm, which is in go...

  19. Synthesis and characterization of WO3 nanomaterials. (United States)

    Pandey, N K; Tiwari, Karunesh; Roy, Akash


    This work reports a simple, quick and economical method to prepare WO3 nanomaterials. Prepared tungsten trioxide materials have been sintered at 700 degrees C for three hours. The material has been studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Energy Dispersive Spectroscopy (EDS). Crystallite size of the WO3 nanostructures obtained by Shearer's formula are between 12 and 72 nm and their grain size by SEM are from 20 to 105 nm. The humidity-sensitive electrical properties of the WO3 nanomaterial have been studied using d.c. measurements.

  20. Examples of cost reduction and energy saving by thermal storage heat pump system. Part 5. Control of the flowering season of alstroemeria by using 'ice storage ground cooler'. Chikunetsushiki heat pump system katsuyo ni yoru costdown sho energy jirei no shokai. 5. 'Kori chikunetsushiki chichu reikyaku sochi' ni yori arusutoromeria no kaika jiki wo chosetsu

    Energy Technology Data Exchange (ETDEWEB)


    Alstroemeria has a habit to flower by sensing temperature through an organ in rhizome. Since its market price is higher in late fall and early winter, a culture method cooling the ground in summer is in wide use. Although the ground is cooled with an equipment composed of a chiller, ground piping for heat exchange and cold water pump during the whole day, cost reduction is a major problem. To study a heat storage ground cooler, its culture test was made by using a prototype ice storage ground cooler. The test result showed that ground temperature of both test zone and reference zone was constantly 18-20 degrees C during the test period, and both the whole yield and that every class were nearly equivalent between the test and reference zones. The estimation result on the profitability of a full-scale ice storage ground cooler based on the above result showed that this ground cooler probably can reduce annual electric charge by nearly 200,000 yen as compared with a cooler without heat storage. (NEDO)

  1. Examples of cost reduction and energy saving by thermal storage heat pump system. Part 5. Control of the flowering season of alstroemeria by using `ice storage ground cooler`; Chikunetsushiki heat pump system katsuyo ni yoru costdown sho energy jirei no shokai. 5. `Kori chikunetsushiki chichu reikyaku sochi` ni yori arusutoromeria no kaika jiki wo chosetsu

    Energy Technology Data Exchange (ETDEWEB)



    Alstroemeria has a habit to flower by sensing temperature through an organ in rhizome. Since its market price is higher in late fall and early winter, a culture method cooling the ground in summer is in wide use. Although the ground is cooled with an equipment composed of a chiller, ground piping for heat exchange and cold water pump during the whole day, cost reduction is a major problem. To study a heat storage ground cooler, its culture test was made by using a prototype ice storage ground cooler. The test result showed that ground temperature of both test zone and reference zone was constantly 18-20 degrees C during the test period, and both the whole yield and that every class were nearly equivalent between the test and reference zones. The estimation result on the profitability of a full-scale ice storage ground cooler based on the above result showed that this ground cooler probably can reduce annual electric charge by nearly 200,000 yen as compared with a cooler without heat storage. (NEDO)

  2. Centrifugal pumps

    CERN Document Server

    Anderson, HH


    Centrifugal Pumps describes the whole range of the centrifugal pump (mixed flow and axial flow pumps are dealt with more briefly), with emphasis on the development of the boiler feed pump. Organized into 46 chapters, this book discusses the general hydrodynamic principles, performance, dimensions, type number, flow, and efficiency of centrifugal pumps. This text also explains the pumps performance; entry conditions and cavitation; speed and dimensions for a given duty; and losses. Some chapters further describe centrifugal pump mechanical design, installation, monitoring, and maintenance. The

  3. Pumping life

    DEFF Research Database (Denmark)

    Sitsel, Oleg; Dach, Ingrid; Hoffmann, Robert Daniel


    of membrane proteins: P-type ATPase pumps. This article takes the reader on a tour from Aarhus to Copenhagen, from bacteria to plants and humans, and from ions over protein structures to diseases caused by malfunctioning pump proteins. The magazine Nature once titled work published from PUMPKIN ‘Pumping ions......’. Here we illustrate that the pumping of ions means nothing less than the pumping of life....

  4. New ion generation method with SF{sub 6} plasma. Direct ionization of refractory materials; SF{sub 6} purazuma wo mochiita atarashii ion seiseiho. koyuten busshitsu wo chokusetsu ion ka

    Energy Technology Data Exchange (ETDEWEB)

    Okoshi, K.; Saito, Y.; Tajima, S. [Japan Atomic Energy Research Institute, Tokyo (Japan)


    For many refractory materials, vapor pressures rise due to fluoridation. For example, a vapor pressure of B is almost zero at room temperature, whereas a vapor pressure of BF{sub 3} is 10{sup 5}Pa or greater. A SF{sub 6} plasma method is capable of directly generating a solid fluoride in an ion source and obtaining its plasma. In order to ionize refractory materials such as niobium, boron, silicon and the like, the present authors have developed a new ion generation method using a stable solid sample and SF{sub 6} gas. Further, the present method was employed to successfully and greatly extending the filament life of the ion source. The plasma method can be used widely not only for a Freeman ion source but also for an ion source using plasma such as electron cyclotron resonance (ECR) ion source. Since the refractory material ions can be stably supplied at a great intensity for a long time, they are expected to be used in corrosion-resistant materials or materials having new functions such as optical switching materials. (NEDO)

  5. Wide stop-band filters consisted of optical directional coupler type multi resonators; Hikari hokosei ketsugoki wo mochiita fukugo kyoshinki ni yoru kososhiiki wo yusuru koha fuiruta no kento

    Energy Technology Data Exchange (ETDEWEB)

    Furuta, Hirosuke; Nishikawa, Kenji; Miyamoto, Tokuo


    It is important that pass-band and stop-band of the optical filter used for optical wavelength division multiplexing systems can be set up according to systems requirements. In this paper, we presented expanding of stop-band using multi-resonator consisted of optical directional coupler. In this resonator, addition to interferences by resonation, the path length difference between two different path from input-port to output-port cause intensity changes. To use these interferences, we considerated expanding of stop-band and suppressing of resonate peak in stop-band. 30GHz passband and 60GHz cut-off frequency at 20dB point are calculated. If expanding the stop-band up to 10THz, the loss in the stop-band coms down to 24dB. (author)

  6. Reaction mechanism of active carbon manufactured by chemicals activation method using potassium carbonate from a raw material of tofu refuse; Okara wo genryo toshi tansankariumu wo mochiita yakuhinfukatsuho niyoru kasseitan seizo niokeru hannokiko

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, Jun' ichi; Muroyama, Katsuhiko; Furukawa, Akira; Takemoto, Shin [Kasai University, Osaka (Japan)


    The authors attempted to manufacture active carbon using potassium carbonate as an activator from a raw material of tofu refuse. As the results, the active carbon having a large specific surface area of 2,656 m{sup 2}/g at a carbide and an activation temperature of 800 degrees C could be manufactured. It was clarified as follows after investigating the activation mechanism: potassium carbonate changed to potassium peroxide and potassium sulfate in the reaction of tofu refuse and potassium carbonate in the impregnation and dry process. The tofu refuse was changed into a low molecular weight component and a water soluble organic constituent increased. As the results, the weight loss behavior of he tofu refuse changed up to the carbonization - activation temperature of 500 degrees C and then the carbide having a large specific surface area which had a different pore structure of carbide made independently from the tofu refuse was generated. With further increasing the temperature up to 700 degrees C, it was considered that carbon consumed due to a reduction of potassium carbonate by carbon of carbide, the specific surface area was greatly increased, and active carbon having a high specific surface area was manufactured. (translated by NEDO)

  7. Magnetocaloric pump (United States)

    Brown, G. V.


    Very cold liquids and gases such as helium, neon, and nitrogen can be pumped by using magnetocaloric effect. Adiabatic magnetization and demagnetization are used to alternately heat and cool slug of pumped fluid contained in closed chamber.

  8. Heat pumps

    CERN Document Server

    Macmichael, DBA


    A fully revised and extended account of the design, manufacture and use of heat pumps in both industrial and domestic applications. Topics covered include a detailed description of the various heat pump cycles, the components of a heat pump system - drive, compressor, heat exchangers etc., and the more practical considerations to be taken into account in their selection.

  9. Heat pumps

    CERN Document Server

    Brodowicz, Kazimierz; Wyszynski, M L; Wyszynski


    Heat pumps and related technology are in widespread use in industrial processes and installations. This book presents a unified, comprehensive and systematic treatment of the design and operation of both compression and sorption heat pumps. Heat pump thermodynamics, the choice of working fluid and the characteristics of low temperature heat sources and their application to heat pumps are covered in detail.Economic aspects are discussed and the extensive use of the exergy concept in evaluating performance of heat pumps is a unique feature of the book. The thermodynamic and chemical properties o

  10. The Preparation of CoWO4/WO3 Nanocomposite Powder

    Institute of Scientific and Technical Information of China (English)

    SHAO Gang-qin; GUO Jing-kun; XIE Ji-ren; DUAN Xing-long; WU Bo-lin; YUAN Run-zhang


    Ammonium metatungstate and cobalt nitrate were mixed at the molecular level in distilled water and then spray-decomposed to CoWO4/WO3 nanocomposite powder.The particle morphology,crystalline size,forming course,chemical composition and phase structure of the powder were studied by SEM,TEM,DTA-TG,IR and XRD,respectively.Results show that the powder is homogeneous,spherical and nano-aggregated.

  11. Spectroscopy of tetragonal Eu:NaGd(WO4)2 crystal (United States)

    Loiko, P. A.; Vilejshikova, E. V.; Mateos, X.; Serres, J. M.; Dashkevich, V. I.; Orlovich, V. A.; Yasukevich, A. S.; Kuleshov, N. V.; Yumashev, K. V.; Grigoriev, S. V.; Vatnik, S. M.; Bagaev, S. N.; Pavlyuk, A. A.


    We report on growth and detailed spectroscopic study of Eu3+-doped tetragonal sodium gadolinium double tungstate, Eu:NaGd(WO4)2, a new promising crystal for deep-red lasers. Large-volume crystal doped with 4.9 at.% Eu is grown by Czochralski method along the [001] crystallographic direction. Absorption of Eu3+ ions is studied at room temperature (RT) and at 6 K. For the absorption band related to the 7F1 → 5D1 transition suitable for pumping of Eu:NaGd(WO4)2, the maximum cross-section is σabs = 1.2 × 10-21 cm2 at 535.5 nm with the full width at half maximum (FWHM) of 3.1 nm (at RT, for E || a polarization). For the 5D0 → 7F4 transition, the maximum stimulated-emission cross-section is σSE = 1.6 × 10-21 cm2 at 698.3 nm (RT, E || c polarization). Lifetime of the 5D0 state is 490 ± 10 μs (at RT). Under UV excitation, Eu:NaGd(WO4)2 provides intense red emission with CIE coordinates (x = 0.671, y = 0.329).

  12. Centrifugal pumps

    CERN Document Server

    Gülich, Johann Friedrich


    This book gives an unparalleled, up-to-date, in-depth treatment of all kinds of flow phenomena encountered in centrifugal pumps including the complex interactions of fluid flow with vibrations and wear of materials. The scope includes all aspects of hydraulic design, 3D-flow phenomena and partload operation, cavitation, numerical flow calculations, hydraulic forces, pressure pulsations, noise, pump vibrations (notably bearing housing vibration diagnostics and remedies), pipe vibrations, pump characteristics and pump operation, design of intake structures, the effects of highly viscous flows, pumping of gas-liquid mixtures, hydraulic transport of solids, fatigue damage to impellers or diffusers, material selection under the aspects of fatigue, corrosion, erosion-corrosion or hydro-abrasive wear, pump selection, and hydraulic quality criteria. As a novelty, the 3rd ed. brings a fully analytical design method for radial impellers, which eliminates the arbitrary choices inherent to former design procedures. The d...

  13. Detection and phylogenetic analysis of bacteriophage WO in spiders (Araneae). (United States)

    Yan, Qian; Qiao, Huping; Gao, Jin; Yun, Yueli; Liu, Fengxiang; Peng, Yu


    Phage WO is a bacteriophage found in Wolbachia. Herein, we represent the first phylogenetic study of WOs that infect spiders (Araneae). Seven species of spiders (Araneus alternidens, Nephila clavata, Hylyphantes graminicola, Prosoponoides sinensis, Pholcus crypticolens, Coleosoma octomaculatum, and Nurscia albofasciata) from six families were infected by Wolbachia and WO, followed by comprehensive sequence analysis. Interestingly, WO could be only detected Wolbachia-infected spiders. The relative infection rates of those seven species of spiders were 75, 100, 88.9, 100, 62.5, 72.7, and 100 %, respectively. Our results indicated that both Wolbachia and WO were found in three different body parts of N. clavata, and WO could be passed to the next generation of H. graminicola by vertical transmission. There were three different sequences for WO infected in A. alternidens and two different WO sequences from C. octomaculatum. Only one sequence of WO was found for the other five species of spiders. The discovered sequence of WO ranged from 239 to 311 bp. Phylogenetic tree was generated using maximum likelihood (ML) based on the orf7 gene sequences. According to the phylogenetic tree, WOs in N. clavata and H. graminicola were clustered in the same group. WOs from A. alternidens (WAlt1) and C. octomaculatum (WOct2) were closely related to another clade, whereas WO in P. sinensis was classified as a sole cluster.

  14. Ferroelectric Pump (United States)

    Jalink, Antony, Jr. (Inventor); Hellbaum, Richard F. (Inventor); Rohrbach, Wayne W. (Inventor)


    A ferroelectric pump has one or more variable volume pumping chambers internal to a housing. Each chamber has at least one wall comprising a dome shaped internally prestressed ferroelectric actuator having a curvature and a dome height that varies with an electric voltage applied between an inside and outside surface of the actuator. A pumped medium flows into and out of each pumping chamber in response to displacement of the ferroelectric actuator. The ferroelectric actuator is mounted within each wall and isolates each ferroelectric actuator from the pumped medium, supplies a path for voltage to be applied to each ferroelectric actuator, and provides for positive containment of each ferroelectric actuator while allowing displacement of the entirety of each ferroelectric actuator in response to the applied voltage.

  15. WO3 nano-ribbons: their phase transformation from tungstite (WO3·H2O) to tungsten oxide (WO3)

    DEFF Research Database (Denmark)

    Ahmadi, Majid; Sahoo, Satyaprakash; Younesi, Reza


    Tungsten oxide (WO3) nano-ribbons (NRs) were obtained by annealing tungstite (WO3·H2O) NRs. The latter was synthesized below room temperature using a simple, environmentally benign, and low cost aging treatment of precursors made by adding hydrochloric acid to diluted sodium tungstate solutions (Na...

  16. A study of electron excitations in CaWO sub 4 and PbWO sub 4 single crystals

    CERN Document Server

    Muerk, V; Mihoková, E; Nitsch, K


    The excitation spectra of photo- and thermo-luminescence were compared in the VUV-UV spectral region in CaWO sub 4 and PbWO sub 4 scheelite tungstates. Temperature dependences of emission intensities and decay times were measured for PbWO sub 4 in the 80-300 K range and approximated by a simple phenomenological model. The energy level structure of the emission centre excited state and related kinetic processes are discussed for both tungstates. (author)

  17. In situ synthesis of CdS/CdWO4/WO3 heterojunction films with enhanced photoelectrochemical properties (United States)

    Zhan, Faqi; Li, Jie; Li, Wenzhang; Yang, Yahui; Liu, Wenhua; Li, Yaomin


    CdS/CdWO4/WO3 heterojunction films on fluorine-doped tin oxide (FTO) substrates are for the first time prepared as an efficient photoanode for photoelectrochemical (PEC) hydrogen generation by an in situ conversion process. The samples are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet visible spectrometry (UV-vis) and X-ray photoelectron spectroscopy (XPS). The CdS hollow spheres (∼80 nm) sensitized WO3 plate film with a CdWO4 buffer-layer exhibits increased visible light absorption and a significantly improved photoelectrochemical performance. The photocurrent density at 0 V (vs. Ag/AgCl) of the CdS/CdWO4/WO3 anode is ∼3 times higher than that of the CdWO4/WO3 anode, and ∼9 times higher than that of pure WO3 under illumination. The highest incident-photon-to-current-efficiency (IPCE) value increased from 16% to 63% when the ternary heterojunction was formed. This study demonstrates that the synthesis of ternary composite photocatalysts by the in situ conversion process may be a promising approach to achieve high photoelectric conversion efficiency.

  18. Penis Pump (United States)

    ... claim that they can be used to increase penis size, but there's no evidence that they work for ... circumstances, using a penis pump might help your penis maintain its natural size and shape after prostate surgery or if you ...

  19. Fabrication and characterization of WO3/Ag/WO3 multilayer transparent anode with solution-processed WO3 for polymer light-emitting diodes. (United States)

    Jeon, Kangmin; Youn, Hongseok; Kim, Seongbeom; Shin, Seongbeom; Yang, Minyang


    The dielectric/metal/dielectric multilayer is suitable for a transparent electrode because of its high-optical and high-electrical properties; however, it is fabricated by an expensive and inefficient multistep vacuum process. We present a WO3/Ag/WO3 (WAW) multilayer transparent anode with solution-processed WO3 for polymer light-emitting diodes (PLEDs). This WAW multilayer not only has high transmittance and low resistance but also can be easily and rapidly fabricated. We devised a novel method to deposit a thin WO3 layer by a solution process in an air environment. A tungstic acid solution was prepared from an aqueous solution of Na2WO4 and then converted to WO3 nanoparticles (NPs) by a thermal treatment. Thin WO3 NP layers form WAW multilayer with a thermal-evaporated Ag layer, and they improve the transmittance of the WAW multilayer because of its high transmittance and refractive index. Moreover, the surface of the WO3 layer is homogeneous and flat with low roughness because of the WO3 NP generation from the tungstic acid solution without aggregation. We performed optical simulation and experiments, and the optimized WAW multilayer had a high transmittance of 85% with a sheet resistance of 4 Ω/sq. Finally, PLEDs based on the WAW multilayer anode achieved a maximum luminance of 35,550 cd/m2 at 8 V, and this result implies that the solution-processed WAW multilayer is appropriate for use as a transparent anode in PLEDs.

  20. Microwave-assisted synthesis of Zn-WO3 and ZnWO4 for pseudocapacitor applications (United States)

    Kumar, R. Dhilip; Andou, Y.; Karuppuchamy, S.


    Nanosized Zn-WO3 and ZnWO4 materials have been prepared by microwave irradiation method. The physico-chemical characterization of the prepared nanomaterials was carried out by X-ray diffraction (XRD) and high resolution-scanning electron microscopy (HR-SEM) techniques. The size and shape of the ZnWO4 material can be controlled by changing the temperature. The XRD analysis revealed the formation of monoclinic phase of the calcined nanopowder. The HR-SEM images showed the sphere and plate shape particles. The electrochemical behavior of the ZnWO4 modified electrodes was investigated using electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) techniques. The synthesized material shows the pseudocapacitance. The specific capacitance of 35.70 F/g was achieved for the Zn-WO3 nanopowder.

  1. Synthesis of S-doped WO3 nanowires with enhanced photocatalytic performance towards dye degradation (United States)

    Han, Fugui; Li, Heping; Fu, Li; Yang, Jun; Liu, Zhong


    In this letter, S-doped WO3 nanowires (S-WO3) were prepared using a hydrothermal method followed by a low-temperature solid-state annealing treatment. The synthesized S-WO3 was characterized by SEM, EDX, XRD, XPS, Raman spectroscopy, UV-vis DRS and photocurrent responses. The results indicated that S could enhance the light harvesting capacity of WO3 nanowires. The photocatalytic performance of the S-WO3 was investigated by photodegradation of methyl orange (MO) under visible light irradiation. Results demonstrated that the photocatalytic activity of the S-WO3 nanowires is much higher than that of pure WO3 nanowires.

  2. Pumps; Pumpen

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, H. [Gesellschaft fuer Praktische Energiekunde e.V., Muenchen (Germany). Forschungsstelle fuer Energiewirtschaft; Hellriegel, E. [Gesellschaft fuer Praktische Energiekunde e.V., Muenchen (Germany). Forschungsstelle fuer Energiewirtschaft; Pfitzner, G. [Gesellschaft fuer Praktische Energiekunde e.V., Muenchen (Germany). Forschungsstelle fuer Energiewirtschaft


    The technical features of commercial pump types are described with regard to their technical, energy-related and economic parameters, and characteristic data are presented in the form of data sheets. This is to provide a basis for a comparative assessment of different technologies and technical variants. The chapter `System specifications` describes the various fields of application of pumps and the resulting specific requirements. The design and function of the different pump types are described in `Technical description`. `System and plant description dscribes the design and adaptation of pumps, i.e. the adaptation of the plant data to the system requirements. `Data compilation` provides a survey of the types and systematics of the compiled data as well as a decision aid for selecting the pumps best suited to the various applications. The `Data sheet` section describes the structure and handling of the data sheets as well as the data contained therein. The data sheets are contained in the apapendix of this report. The section `General analysis` compares typical technical, energy-related and economic characteristics of the different pump types. This is to enable a rough comparison of pump types and to facilitate decisions. The chapter `Example` illustrates the use of the data sheets by means of a selected example. (orig./GL) [Deutsch] Die vorliegende Arbeit hat zum Ziel, Technik seriengefertigter und marktgaengiger Pumpen in typisierter Form hinsichtlich ihrer technischen, energetischen und wirtschaftlichen Parameter zu beschreiben und ihre charakteristischen Kennwerte in Datenblaettern abzubilden. Damit wird ein grundlegendes Instrument fuer die vergleichende Beurteilung unterschiedlicher Techniken bzw. Technikvarianten hinsichtlich energetischer und wirtschaftlicher Kriterien geschaffen. Im Abschnitt `Systemanforderungen` erfolgt die Beschreibung der einzelnen Anwendungsbereiche fuer Pumpen mit den speziellen daraus resultierenden Anforderungen. Der Aufbau und

  3. Recent advances in the development of scheelite-like MT1-xLnx(WO4)2 lasers (United States)

    Zaldo, Carlos; Cascales, Concepción; Serrano, María Dolores; Han, Xiumei


    Tetragonal NaT(WO4)2, T= trivalent Y, La, Gd and Lu, single crystals doped with Yb3+ or Tm3+ have shown efficient room temperature laser operation at λ~1.05 μm and λ~1.95 μm, respectively. The broad bandwidth of the optical transitions of these lanthanides is of particular interest for diode-laser-pumped tunable and mode-locked femtosecond lasers. The present knowledge about these crystals and their applications as solid state lasers is overviewed. Results of new material preparation directions to produce epilayers and nano-, micro-particles of these compounds are described.

  4. High Efficient Laser Operation of the Nd:KGd(WO4)2 Crystal Grown by Flux Method

    Institute of Scientific and Technical Information of China (English)

    LUO Zun-Du; CHEN Xue-Yuan; TU Chao-Yang; J. J. Romero; J. Garcia Sole


    The laser performance of Neodymium-doped potassium gadolinium tungstate (Nd:KGd(WO4)2) crystal was studied by using Ti:Sapphire laser as the pump source. The maximum optical-to-optical efficiencies for the 1.067 and 1.3 μm laser outputs were measured to be 60% and 32.3%, respectively. The internal loss coefficient of the crystal for 1.067 μm laser was estimated to be as low as 0.004 cm-1. The oscillation thresholds at 1.067 and 1.3 μm for different output transmittances are also given.

  5. Radioactive contamination of ZnWO{sub 4} crystal scintillators

    Energy Technology Data Exchange (ETDEWEB)

    Belli, P. [INFN sezione Roma ' Tor Vergata' , I-00133 Rome (Italy); Bernabei, R., E-mail: rita.bernabei@roma2.infn.i [INFN sezione Roma ' Tor Vergata' , I-00133 Rome (Italy); Dipartimento di Fisica, Universita di Roma ' Tor Vergata' , I-00133 Rome (Italy); Cappella, F. [INFN sezione Roma ' La Sapienza' , I-00185 Rome (Italy); Dipartimento di Fisica, Universita di Roma ' La Sapienza' , 00185 Rome (Italy); Cerulli, R. [INFN, Laboratori Nazionali del Gran Sasso, I-67010 Assergi (AQ) (Italy); Danevich, F.A. [Institute for Nuclear Research, MSP 03680 Kyiv (Ukraine); Dubovik, A.M. [Institute for Scintillation Materials, 61001 Kharkiv (Ukraine); D' Angelo, S. [INFN sezione Roma ' Tor Vergata' , I-00133 Rome (Italy); Dipartimento di Fisica, Universita di Roma ' Tor Vergata' , I-00133 Rome (Italy); Galashov, E.N. [Nikolaev Institute of Inorganic Chemistry, 630090 Novosibirsk (Russian Federation); Grinyov, B.V. [Institute for Scintillation Materials, 61001 Kharkiv (Ukraine); Incicchitti, A. [INFN sezione Roma ' La Sapienza' , I-00185 Rome (Italy); Dipartimento di Fisica, Universita di Roma ' La Sapienza' , 00185 Rome (Italy); Kobychev, V.V. [Institute for Nuclear Research, MSP 03680 Kyiv (Ukraine); Laubenstein, M. [INFN, Laboratori Nazionali del Gran Sasso, I-67010 Assergi (AQ) (Italy); Nagornaya, L.L. [Institute for Scintillation Materials, 61001 Kharkiv (Ukraine); Nozzoli, F. [INFN sezione Roma ' Tor Vergata' , I-00133 Rome (Italy); Dipartimento di Fisica, Universita di Roma ' Tor Vergata' , I-00133 Rome (Italy); Poda, D.V. [INFN, Laboratori Nazionali del Gran Sasso, I-67010 Assergi (AQ) (Italy); Institute for Nuclear Research, MSP 03680 Kyiv (Ukraine); Podviyanuk, R.B.; Polischuk, O.G. [Institute for Nuclear Research, MSP 03680 Kyiv (Ukraine); Prosperi, D. [INFN sezione Roma ' La Sapienza' , I-00185 Rome (Italy); Dipt. di Fisica, Univ. di Roma ' La Sapienza' , 00185 Rome (Italy); Shlegel, V.N. [Nikolaev Inst. of Inorganic Chemistry, 630090 Novosibirsk (Russian Federation)


    The radioactive contamination of ZnWO{sub 4} crystal scintillators has been measured deep underground at the Gran Sasso National Laboratory (LNGS) of the INFN in Italy with a total exposure 3197 kg h. Monte Carlo simulation, time-amplitude and pulse-shape analyses of the data have been applied to estimate the radioactive contamination of the ZnWO{sub 4} samples. One of the ZnWO{sub 4} crystals has also been tested by ultra-low background {gamma} spectrometry. The radioactive contaminations of the best ZnWO{sub 4} samples are estimated to be less than 0.002 mBq/kg ({sup 228}Th and {sup 226}Ra), the total {alpha} activity is 0.18 mBq/kg. The {beta} active {sup 65}Zn and the {alpha} active {sup 180}W have been detected in ZnWO{sub 4} crystals. The effect of the re-crystallization on the radiopurity of the ZnWO{sub 4} crystal has been studied. The radioactive contamination of the ceramic components of the set-ups used in the crystals growth has been checked by low background {gamma} spectrometry. Some ideas for future improvement of the radiopurity level of ZnWO{sub 4} crystal scintillators are briefly discussed.

  6. Types of Breast Pumps (United States)

    ... Devices Consumer Products Breast Pumps Types of Breast Pumps Share Tweet Linkedin Pin it More sharing options ... used for feeding a baby. Types of Breast Pumps There are three basic types of breast pumps: ...

  7. Upconversion luminescence of lanthanide-doped mixed CaMoO4-CaWO4 micro-/nano-materials. (United States)

    Liu, Jing; Kaczmarek, Anna M; Billet, Jonas; Van Driessche, Isabel; Van Deun, Rik


    Uniform mixed CaMoO4-CaWO4 micro-/nano-materials have been successfully synthesised by a facile hydrothermal method. The morphology of these upconversion materials could be changed to different shapes and the size could also be decreased from the micro- to nano-scale by varying the type of surfactant used. It was observed that before heat treatment, the materials show relatively weak green light emission under excitation at 975 nm, whereas after heat treatment, the intensity of the upconversion luminescence increases dramatically while the intensity of the red component decreases relatively. By adjusting the molybdate/tungstate ratio, it was found that the samples with a higher molybdate content have stronger luminescence properties. XRD measurements have been done to investigate the structure of the mixed CaMoO4-CaWO4 upconversion materials. The effect of heat treatment at different temperatures on the emission spectra and XRD patterns has also been studied. TG-DTA was used to further confirm the most suitable temperature for heat treatment. The luminescence lifetimes and CIE coordinates for these samples were also determined. Additionally it was found that Gd(3+) co-doping could further increase the upconversion luminescence from these mixed CaMoO4-CaWO4 materials. Finally, monitoring the upconversion luminescence intensity as a function of laser pump power confirmed the upconversion process to be a two-photon absorption mechanism.

  8. Preparation and luminescence properties of BaWO4:Yb3+/Tm3+nano-crystal

    Institute of Scientific and Technical Information of China (English)

    贺超; 杨魁胜; 刘磊; 司振君


    This research investigated the effect of different contents of Tm3+and different concentration ratios of Yb/Tm on the lumi-nescent properties of BaWO4:Yb3+/Tm3+nano-crystal synthesized by the hydrothermal method. The results indicated that lumines-cence intensity reached the strongest when CTm=1.0 mol.% and CYb/CTm=2:1. X-ray diffraction revealed the tetragonal system of BaWO4:Yb3+/Tm3+and the grain sizes were between 31 and 45 nm according to Scherrer equation. The results of X-ray diffraction and scanning electron microscopy were similar. Four emission peaks at 454, 475, 647 and 790 nm including two blue emission peaks and two red emission peaks, corresponding to 1D2→3F4 , 1G4→3H6, 1G4→3F4 and 3H4→3H6 transitions of Tm3+, were observed under excitation of 980 nm semiconductor laser. Blue emissions at 454 and 475 nm were four-photon and three-photon absorption respec-tively in accordance with the relationship between luminescence intensity and pump power.

  9. Kinetics and mechanism of dye adsorption on WO3 nanoparticles (United States)

    Adhikari, Sangeeta; Mandal, Sandip; Sarkar, Debasish; Kim, Do-Heyoung; Madras, Giridhar


    Monoclinic WO3 nanoparticles were synthesized by a simple acid catalyzed co-precipitation reaction. Spherical particles with average size ∼55 nm were confirmed from electron microscopy followed by functional, structural and optical characterizations. The adsorption of methylene blue was examined by using WO3 nanoparticles and the capacity was higher than most of the reported studies. The effect of pH and material loading on adsorption was determined. The mechanism of adsorption was examined by XPS and a detailed explanation of surface phenomena was proposed. Regeneration study was carried and a high stability of heat treated WO3 towards adsorption of methylene blue was observed.

  10. Synthesis, Humidity Sensing, Photocatalytic and Antimicrobial Properties of Thin Film Nanoporous PbWO4-WO3 Nanocomposites

    Directory of Open Access Journals (Sweden)

    Markasagayam Visagamani Arularasu


    Full Text Available A humidity sensor thin film based on nanoporous PbWO4-WO3 composites has been prepared by spin coating technique with different weight ratio of PbWO4 (Pb and WO3 (WO (PWWO-01, PWWO-82, PWWO-64, PWWO-46, PWWO-28, PWWO-01 and their humidity sensing properties have also been investigated at different relative humidity (RH in the range of 5% - 98% at room temperature with dc resistance. It is found that composite PWWO-28 show best humidity sensing properties with the sensitivity factor value of (Sf 3733. The response and recovery time of humidity sensor are about 50 s and 120 s, respectively. High sensitivity, narrow hysteresis loop, rapid response and recovery, prominent stability and good repeatability are obtained. Synthesized PbWO4-WO3 composites were characterized by power X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, BET and photoluminescence studies. The photocatalytic result demonstrated photocatalytic efficiency of nonporous PWWO-28 composite.  The antimicrobial activity of the composites was determined by disc diffusion method.

  11. On the dynamic suction pumping of blood cells in tubular hearts

    CERN Document Server

    Battista, Nicholas A; Miller, Laura A


    Around the third week after gestation in embryonic development, the human heart consists only of a valvless tube, unlike a fully developed adult heart, which is multi-chambered. At this stage in development, the heart valves have not formed and so net flow of blood through the heart must be driven by a different mechanism. It is hypothesized that there are two possible mechanisms that drive blood flow at this stage - Liebau pumping (dynamic suction pumping or valveless pumping) and peristaltic pumping. We implement the immersed boundary method with adaptive mesh refinement (IBAMR) to numerically study the effect of hematocrit on the circulation around a valveless. Both peristalsis and dynamic suction pumping are considered. In the case of dynamic suction pumping, the heart and circulatory system is simplified as a flexible tube attached to a relatively rigid racetrack. For some Womersley number (Wo) regimes, there is significant net flow around the racetrack. We find that the addition of flexible blood cells ...

  12. Synthesis and photoelectrochemical properties of CdWO{sub 4} and CdS/CdWO{sub 4} nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Weina [Department of Applied Physics, Chongqing University, Chongqing 400044 (China); Zheng, Chunhua [Department of Applied Physics, Chongqing University, Chongqing 400044 (China); Department of Mathematics and Physics, Officer College of the Chinese People' s Armed Police Forces, Chengdu 610213 (China); Hua, Hao; Yang, Qi; Chen, Lin [Department of Applied Physics, Chongqing University, Chongqing 400044 (China); Xi, Yi, E-mail: [Department of Applied Physics, Chongqing University, Chongqing 400044 (China); Hu, Chenguo, E-mail: [Department of Applied Physics, Chongqing University, Chongqing 400044 (China)


    Graphical abstract: - Highlights: • A facile CHM strategy is employed for the first time to synthesize CdWO{sub 4} nanowire and nanoflower arrays on cadmium foils. • The photoelectrochemical (PEC) properties are measured on the electrodes made of the CdWO{sub 4} nanowire and nanoflower arrays. • The photocurrent density of the nanowire electrode reaches 0.35 mA/cm{sup 2}, which is 3 times as much as that of the nanoflower electrode. • CdS nanoparticles are deposited on CdWO{sub 4} nanowire arrays to form a CdS/CdWO{sub 4} heterojunction to improve the PEC properties. • The remarkably enhanced photoresponse is achieved on the CdS/CdWO{sub 4} which is twice as much as that on the pure CdWO{sub 4} electrode. - Abstract: A facile composite-salt-mediated strategy is employed for the first time to synthesize CdWO{sub 4} nanowire and nanoflower arrays on cadmium foil substrates. The photoelectrochemical (PEC) properties are measured on the electrodes made of the CdWO{sub 4} nanowire and nanoflower arrays under the simulated sunlight illumination. Both electrodes display high sensitive response and photocurrent stability. The photocurrent density of the nanowire arrays electrode reach 0.35 mA/cm{sup 2}, which is about 3 times as much as that of the nanoflower array electrode. To improve the visible light photocurrent response, CdS nanoparticles are deposited on the CdWO{sub 4} nanowire arrays to form a CdS/CdWO{sub 4} heterojunction. Remarkably enhanced photoresponse is observed on the CdS/CdWO{sub 4} heterostructure and the photocurrent intensity is about twice as much as that of the electrode made of the pure CdWO{sub 4} nanowire arrays. The photoelectric mechanism is also discussed by the crystal structure and morphology characterization, optical band gap and carrier mobility analysis. This work presents a new design of a photoelectrochemical device for possible applications in photoelectrolysis of water and solar cells or highly sensitive light detection.

  13. Spectral Properties and Upconversion Luminescence of Er3+, Yb3+: BaWO4 Crystal

    Institute of Scientific and Technical Information of China (English)


    The optical quality of Er3+, Yb3+: BaWO4 crystal was grown by Czochralski method. Absorption spectra were measured and energy levels were assigned. According to Judd-Ofelt theory, the spectral strength parameters of Er3+ ion were fitted to be Ω2=0.3926×10-20 cm2, Ω4=0.0721×10-20 cm2, Ω6=0.0028×10-20 cm2. Emission peaks centered at around 523, 544 and 670 nm were observed under 334 nm He-Cd laser excitation and emission peaks centered at 1001 and 1534 nm were detected under 976 nm laser excitation. Strong green emission was also observed when the crystal was pumped with 808 nm and 976 nm laser. The mechanisms of frequency upconversion and sensitization were analyzed.

  14. Enhanced photoluminescence of SrWO{sub 4}:Eu{sup 3+} red phosphor synthesized by mechanochemically assisted solid state metathesis reaction method at room temperature

    Energy Technology Data Exchange (ETDEWEB)

    Peter, Anthuvan John, E-mail:; Banu, I. B. Shameem [Department of Physics, B. S. Abdur Rahman University, Vandalur, Chennai, Tamilnadu (India)


    Optically efficient europium activated alkaline earth metal tungstate nano phosphor (SrWO{sub 4}) with different doping concentrations have been synthesized by mechanochemically assisted solid state metathesis reaction at room temperature for the first time. The XRD and Raman spectra results indicated that the prepared powders exhibit a scheelite-type tetragonal structure. FTIR spectra exhibited a high absorption band situated at around 854 cm{sup −1}, which was ascribed to the W–O antisymmetric stretching vibrations into the [WO{sub 4}]{sup 2−} tetrahedron groups. Analysis of the emission spectra with different Eu{sup 3+} concentrations revealed that the optimum dopant concentration for SrWO{sub 4}: x Eu{sup 3+} phosphor is about 8 mol% of Eu{sup 3+}.The red emission intensity of the SSM prepared SrWO{sub 4}: 0.08Eu{sup 3+} phosphors are 2 times greater than that of the commercial Y{sub 2}O{sub 2}S: Eu{sup 3+} red phosphor prepared by the conventional solid state reaction method. All the results indicate that the phosphor is a promising red phosphor pumped by NUV InGaN chip for fabricating WLED.

  15. WO3 Nanoplates Film: Formation and Photocatalytic Oxidation Studies

    Directory of Open Access Journals (Sweden)

    Chin Wei Lai


    Full Text Available High surface area of tungsten oxide (WO3 nanoplates films was prepared via simple electrochemical anodization technique by controlling the fluoride content (NH4F in electrolyte. The design and development of WO3-based nanostructure assemblies have gained significant interest in order to maximize specific surface area for harvesting more photons to trigger photocatalytic oxidation reaction. This study aims to determine the optimum content of NH4F in forming WO3 nanoplates on W film with efficient photocatalytic oxidation reaction for organic dye degradation by utilizing our solar energy. The NH4F was found to influence the chemical dissolution and field-assisted dissolution rates, thus modifying the final morphological of WO3-based nanostructure assemblies film. It was found that 0.7 wt% of NH4F is the minimum amount to grow WO3 nanoplates film on W film. The photocatalysis oxidation experimental results showed that WO3 nanoplates film exhibited a maximum degradation of methyl orange dye (≈75% under solar illumination for 5 hours. This behavior was attributed to the better charge carriers transportation and minimizes the recombination losses with specific surface area of nanoplates structure.

  16. Anti-tumor activity of self-charged (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles

    Indian Academy of Sciences (India)

    Cao Lin; Cao Jiexin; Wang Cong; Che Ping; Pan De’an; Alex A Volinsky


    Non-stoichiometric (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles with anti-tumor activity are synthesized in a sol–gel method by adding excessive Eu3+ and Ca2+ ions to tungsten oxide crystal structure. Colorimetric assay shows that 10 nm (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles can effectively inhibit growth of mammary cancer cells without any harm to normal cells. Nanoparticles are characterized by X-ray diffraction, high resolution transmission electron microscopy and fluorescence optical spectrometry. Nanomaterials, insoluble in synthesized water, have complicated self-charging surfaces that trap mammary cancer cells. Surface self-charging effect is suggested as the inhibition mechanism.

  17. Annual cycle solar energy utilization with seasonal storage. Part 7. Examination on design and control of the system partially recovering exhaust heat of heat pump; Kisetsukan chikunetsu ni yoru nenkan cycle taiyo energy riyo system ni kansuru kenkyu. 7. Bubuntekina hainetsu kaishu wo koryoshita baai no sekkei seigyoho no kento

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, H.; Okumiya, M. [Nagoya University, Nagoya (Japan)


    The capacity and performance of the existing system that recovers the overall heating and cooling exhaust heat completely into a seasonal storage tank and the system that discharges the exhaust heat slightly to the outside and recovers it partially were compared and investigated. The system uses a central single-duct discharge system as an air-conditioning system. A heat pump and a flat-plate solar collector installed on the roof of a building are used as the heat source. The seasonal storage tank in the ground just under the building is a cylindrical water tank of 5 m deep with the concrete used as body. The upper surface of a storage tank is heat-insulated by a stylo-platform of 200 mm, and the lower side surface by a stylo-platform of 100 mm. Calculation when the difference in temperature used in a seasonal storage tank is set to 35{degree}C and 25{degree}C was performed for the system that has two control methods. The overall exhaust heat recovery system is almost the same in energy performance as the partial exhaust heat recovery system. The partial exhaust heat recovery system is more advantageous on the economic side. 4 refs., 6 figs., 3 tabs.

  18. Crystal Structures of Dy2(WO4)3 and GdY(WO4)3

    Institute of Scientific and Technical Information of China (English)


    Two compounds, Dy2(WO4)3 and GdY(WO4)3; were synthesized by using the standard solid state reaction tech-nique. The crystal structure was determined by powder X-ray diffraction and Rietveld refinement method. It is found thatboth compounds have Eu2(WO4)3-type monoclinic structure, with space group C 2/c, Z = 4. The unit cell parameters ofDy2(WO4)3 are a = 0.75981(1) nm, b = 1.13220(1) nm, c = 1.13254(1) nm, and β= 109.8001(3)°, and those of GdY(WO4)3are a = 0.76175(1) nm, b = 1.13543(1) nm, c = 1.13496(2) nm, and β= 109.8015(13)°. Each W atom has four oxygen near-est neighbors, while each rare-earth atom is surrounded by eight oxygen atoms. WO4 tetrahedra share their four verticeswith REO8 (RE = Dy, Gd, or Y) trigondodecahedra and some REO8 trigondodecahedra share an edge with each other. Thephase transition and the magnetic properties were investigated by differential thermal analysis (DTA) and dc superconduct-ing quantum interference device (SQUID) magnetometer.

  19. Photoluminescence in solid solutions and thin films of tungstates CaWO{sub 4}-CdWO{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Taoufyq, A.; Mauroy, V.; Guinneton, F.; Valmalette, J-C. [University of Toulon, IM2NP, UMR CNRS 7334, La Garde, (France); Fiorido, T. [Aix Marseille University, IM2NP, UMR CNRS, 7334, Marseille, (France); Benlhachemi, A. [IBN ZOHR University, Faculty of sciences, Environment and Materials Laboratory, Agadir, (Morocco); Lyoussi, A. [CEA of Cadarache, DEN, Departement of reactors studies, experimental physics, Instrumentation Sensors and Dosimetry Laboratory, (France); Nolibe, G. [Cesigma society, signals and systems, La Garde, (France); Gavarri, J-R. [University of Toulon, IM2NP, UMR CNRS 7334, La Garde, (France)


    In this study, we present two types of studies on the luminescence properties under UV and X-ray excitations of solid solutions Ca{sub 1-x}Cd{sub x}WO{sub 4} and of thin layers of CaWO{sub 4} and CdWO{sub 4}. These tungstate based solid solutions are susceptible to be integrated into new radiation sensors, in order to be used in different fields of applications such as reactor measurements, safeguards, homeland security, nuclear nondestructive assays, LINAC emission radiation measurement. However these complex materials were rarely investigated in the literature. One first objective of our studies was to establish correlations between luminescence efficiency, chemical substitution and the degree of crystallization resulting from elaboration conditions. A second objective will be to determine the efficiency of luminescence properties of thin layers of these materials. In the present work, we focus our attention on the role of chemical substitution on photon emissions under UV and X-ray irradiations. The luminescence spectra of Ca{sub 1-x}Cd{sub x}WO{sub 4} polycrystalline materials have been investigated at room temperature as a function of composition (0≤x≤1). In addition, we present a preliminary study of the luminescence of CaWO{sub 4} and CdWO{sub 4} thin layers: oscillations observed in the case of X-ray excitations in the luminescence spectra are discussed. (authors)

  20. Pump characteristics and applications

    CERN Document Server

    Volk, Michael


    Providing a wealth of information on pumps and pump systems, Pump Characteristics and Applications, Third Edition details how pump equipment is selected, sized, operated, maintained, and repaired. The book identifies the key components of pumps and pump accessories, introduces the basics of pump and system hydraulics as well as more advanced hydraulic topics, and details various pump types, as well as special materials on seals, motors, variable frequency drives, and other pump-related subjects. It uses example problems throughout the text, reinforcing the practical application of the formulae

  1. Photocatalytic properties of h-WO3 nanoparticles obtained by annealing and h-WO3 nanorods prepared by hydrothermal method (United States)

    Boyadjiev, Stefan I.; Nagy-Kovács, Teodóra; Lukács, István; Szilágyi, Imre M.


    In the present study, two different methods for preparing hexagonal WO3 (h-WO3) photocatalysts were used - controlled thermal decomposition and hydrothermal synthesis. WO3 nanoparticles with hexagonal structure were obtained by annealing (NH4)xWO3-y at 500 °C in air. WO3 nanorods were prepared by a hydrothermal method using sodium tungstate Na2WO4, HCl, (COOH)2 and NaSO4 precursors at 200 °C. The formation, morphology, structure and composition of the as-prepared nanoparticles and nanorods were studied by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDX). The photocatalytic activity of the h-WO3 nanoparticles and nanorods was studied by decomposing methyl orange in aqueous solution under UV light irradiation.

  2. Evolution of coherent collective modes through consecutive charge-density-wave transitions in the (PO2)4(WO3)12 monophosphate tungsten bronze (United States)

    Stojchevska, L.; Borovšak, M.; Foury-Leylekian, P.; Pouget, J.-P.; Mertelj, T.; Mihailovic, D.


    All-optical femtosecond relaxation dynamics in a single crystal of monophosphate tungsten bronze (PO2)4(WO3)2m with alternate stacking m =6 of WO3 layers was studied through the three consequent charge-density-wave (CDW) transitions. Several transient coherent collective modes associated with the different CDW transitions were observed and analyzed in the framework of the time-dependent Ginzburg-Landau theory. Remarkably, the interference of the modes leads to an apparent rectification effect in the transient reflectivity response. A saturation of the coherent-mode amplitudes with increasing pump fluence well below the CDWs destruction threshold fluence indicates a decoupling of the electronic and lattice parts of the order parameter on the femtosecond timescale.

  3. Green Upconversion Luminescence in Er3+/Yb3+ Codoped CaWO4 Polycrystals

    Institute of Scientific and Technical Information of China (English)

    XU Yan-Ling; ZHAO Hong; WANG Rui; ZHANG Chun-Yu


    CaWO4 polycrystals with fixed Yb3+ and various Ei2* concentrations are synthesized via the high temperature solid state method. The crystal structure of the polycrystals is characterized by means of x-ray diffraction. The upconversion properties of the polycrystals under the 980 nm excitation are investigated. Intense emission bands centered at 530nm and 552nm correspond to the transitions 2H11/2 → 4hs/2 and 4S3/2→ 4hs/2 of Er3+, respectively. The dependence of intensity of the green emission on the pump power and possible upconversion mechanism are discussed. Quantitative analysis of dependence of upconversion emission intensity on the pump power of a laser diode indicates that two-photon processes are responsible for both 530 nm and 552 nm green upconversion emissions.%@@ CAWO polycrystals with fixed Yb and various Er concentrations are synthesized via the high temperature solid state method.The crystal structure of the polycrystals is characterized by means of x-ray diffraction.The upconversion properties of the polycrystals under the 980 nm excitation are investigated.Intense emission bands centered at 530hm and 552nm correspond to the transitions H → I and S → I of Er, respectively.The dependence of intensity of the green emission on the pump power and possible upconversion mechanism are discussed.Quantitative analysis of dependence of upconversion emission intensity on the pump power of a laser diode indicates that two-photon processes are responsible for both 530hm and 552nm green upconversion emissions.

  4. Large single crystal growth of MnWO4-type materials from high-temperature solutions (United States)

    Gattermann, U.; Röska, B.; Paulmann, C.; Park, S.-H.


    A simple high-temperature growth apparatus was constructed to obtain large crystals of chemically gradient (In, Na)-doped MnWO4solid-solutions. This paper presents the crystal growth and characterisation of both MnWO4and epitaxially grown (In, Na): MnWO4crystals on MnWO4. These large monolithic crystals were made in two steps: A MnWO4 crystal was grown in the crystallographic main direction [001] applying the Czochralski method, followed by the top seeded growth of (In, Na): MnWO4 solid-solutions with an oriented seed crystal of MnWO4. Such a monolithic crystal will serve to fundamental investigation of coupling properties at boundaries between various multiferroic MnWO4-typesolid-solutions.

  5. Structure and photocatalytic performance of layered HNbWO6 nanosheet aggregation

    KAUST Repository

    Hu, Li-Fang


    Layered HNbWO6HNbWO6 nanosheet aggregation (e-HNbWO6e-HNbWO6) has been assembled by HNbWO6HNbWO6 nanosheet via an exfoliation-restaking route. The as-prepared samples are characterized by means of powder x-ray diffraction, scanning electron microscope, high-resolution transmission electron microscopy, laser Raman spectroscopy, ultraviolet-vis diffuse reflectance spectroscopy, and N2N2 adsorption-desorption isotherms. The photocatalytic performances of the as-prepared samples are evaluated by degradation of methylene blue (MB). The results revealed that e-HNbWO6e-HNbWO6 has a specific surface area of about 156.5  m2 g−1156.5  m2 g−1, and exhibits a relatively excellent photocatalytic performance for degradation of MB under UV light.

  6. Lasing effects in new Nd3+-doped TeO2-Nb2O5-WO3 bulk glasses (United States)

    Carreaud, J.; Labruyère, A.; Dardar, H.; Moisy, F.; Duclère, J.-R.; Couderc, V.; Bertrand, A.; Dutreilh-Colas, M.; Delaizir, G.; Hayakawa, T.; Crunteanu, A.; Thomas, P.


    This paper demonstrates for the first time continuous wave (cw) and pulsed lasing effects in a 75TeO2-20NbO2.5-5WO3 glass doped with 1 mol.% in Nd3+. It is divided into two parts: The first part treats all the aspects related to the elaboration and the characterization of the materials. Thus, glasses elaborated within the TeO2-Nb2O5-WO3 ternary system show a rather high glass transition temperature Tg ∼ 375 °C, with an excellent thermal stability of ∼160 °C. Compared to glasses synthesized in either TeO2-Nb2O5 or TeO2-WO3 binary systems, glasses fabricated within such system show improved mechanical performances, with larger Young's modulus values. The structural characteristics of the samples, studied by Raman spectroscopy, are also presented. Linear optical properties (refractive index and extinction coefficient) are accessed by spectroscopic ellipsometry. As well, the optical transmission of the various bulk glasses is measured, in the case of both uncoated and coated glasses. In particular, specific anti-reflective coatings at 808 nm (laser diode pump wavelength) and 1064 nm (laser emission wavelength) are respectively deposited on the two surfaces of the sample in order to minimize the losses due to Fresnel reflections at the two glass/air interfaces. In addition, another specific surface treatment (Rmax at 1064 nm) was employed to serve as the back mirror of the laser cavity. The optical transmission data testified to the real efficiency of all these coatings. Finally, the photoluminescence properties (emission and excitation spectra, and luminescence decay curve) of the Nd3+-doped glasses, measured at room temperature for bulk samples, and as a function of temperature for powder glasses, are discussed. The second part is focused on evidencing (cw) and pulsed lasing effects in such coated bulk lasers. Cylindric samples of only a few millimeters in height and in diameter were tested and led to a laser emission around 1064 nm, characterized by a very low

  7. LMFBR with booster pump in pumping loop (United States)

    Rubinstein, H.J.


    A loop coolant circulation system is described for a liquid metal fast breeder reactor (LMFBR) utilizing a low head, high specific speed booster pump in the hot leg of the coolant loop with the main pump located in the cold leg of the loop, thereby providing the advantages of operating the main pump in the hot leg with the reliability of cold leg pump operation.

  8. Heat pump technology

    CERN Document Server

    Von Cube, Hans Ludwig; Goodall, E G A


    Heat Pump Technology discusses the history, underlying concepts, usage, and advancements in the use of heat pumps. The book covers topics such as the applications and types of heat pumps; thermodynamic principles involved in heat pumps such as internal energy, enthalpy, and exergy; and natural heat sources and energy storage. Also discussed are topics such as the importance of the heat pump in the energy industry; heat pump designs and systems; the development of heat pumps over time; and examples of practical everyday uses of heat pumps. The text is recommended for those who would like to kno

  9. Preparation and physical properties of CuxWO3 (United States)

    Koriche, N.; Bessekhouad, Y.; Bouguelia, A.; Trari, M.


    We report on the study of WO3 doped with Cu using sol-gel (CuxWO3d) and impregnation (CuxWO3i) methods. All materials are well crystallized and exhibit single phases whose crystallite size ranges from 17 to 100 nm depending on Cu amount and the preparation technique. The conductivity dependence on temperature demonstrates semiconductor behavior and follows the Arrhenius model, with activation energies, Eσ, commonly in the range 0.4-0.6 eV. Moreover, the thermopower study shows that CuxWO3d is mainly of p-type conductivity, whereas CuxWO3i is n-type. The mechanism of conduction is attributed to a small polaron hopping. The doping process is found to decrease the interband transition down to 520 nm depending on the preparation conditions. The photoelectrochemical characterization confirms the conductivity type and demonstrates that the photocurrent Jph increases with Cu-doping. Taking into consideration the activation energy, the flat band potential and the band gap energy, the band positions of each material are proposed according to the preparation method and Cu amount.

  10. Absolute activity determination of CaWO{sub 4} crystals

    Energy Technology Data Exchange (ETDEWEB)

    Muenster, Andrea; Ertl, Andreas; Guetlein, Achim; Lanfranchi, Jean-Come; Potzel, Walter; Roth, Sabine; Simon, Daniel; Scholl, Stephan; Sivers, Moritz von; Strauss, Raimund; Wawoczny, Stephan; Willers, Michael; Wuestrich, Marc; Zoeller, Andreas [TU Muenchen, Fakultaet fuer Physik, E15, Garching (Germany)


    The direct Dark Matter search experiment CRESST uses CaWO{sub 4} single crystals as targets for possible WIMP recoils. A particle interaction in the crystal produces phonons as well as scintillation light. As the light signal is dependent on the kind of interacting particle, a particle discrimination on an event-by-event basis is feasible. The observed background is mainly due to intrinsic radioactive impurities of the CaWO{sub 4} target. An activity of this intrinsic contamination can be determined with the investigation of α-decays in the crystal. Up to now, CaWO{sub 4} crystals were produced by suppliers in Russia and Ukraine. Since 2011 we are able to grow CaWO{sub 4} crystals in a Czochralski furnace installed in the crystal laboratory of TU Munich, which has the advantage to better meet the requirements of CRESST and to ensure the availability of CaWO{sub 4} crystals for the successive future multi-material experiment EURECA. To check the radiopurity, first self-grown crystals were investigated in test measurements. In this talk we will present the results for absolute α-activities of self-grown crystals and compare them to α-activities of the crystals installed in the last CRESST run (Run32).

  11. Hydrothermal synthesis and chromic properties of hexagonal WO3 nanowires

    Institute of Scientific and Technical Information of China (English)

    Yuan Hua-Jun; Chen Ya-Qi; Yu Fang; Peng Yue-Hua; He Xiong-Wu; Zhao Ding; Tang Dong-Sheng


    This paper reports that highly purified hexagonal WO3 nanowires are synthesized by a simple hydrothermal method. The as-synthesized WO3 nanowires are investigated in detail by ultraviolet-visible-near infrared spectroscopy and electrical transport measurements under different conditions. It finds that the optical band gap and the diffuse reflection coefficient in the wavelength region above 450 nm of WO3 nanowires decrease observably upon exposure to ultraviolet light or NH3 gas. It is also found that there are electrons being trapped or released in individual WO3 nanowires when scanning bias voltage in different directions upon exposure to ultraviolet and NH3 gas. The experimental results suggest that the chromic properties might be attributed to the injection/extraction of hydrogen ions induced by ultraviolet light irradiation in air or creation/annihilation of oxygen vacancies induced by NH3 gas exposure, which serve as colour centres and trap electrons as polarons. The experimental results also suggest that the hexagonal WO3 nanowires will be a good candidate for sensing reduced gas such as NH3.

  12. Radioactive contamination of ZnWO4 crystal scintillators

    CERN Document Server

    Belli, P; Cappella, F; Cerulli, R; Danevich, F A; Dubovik, A M; d'Angelo, S; Galashov, E N; Grinyov, B V; Incicchitti, A; Kobychev, V V; Laubenstein, M; Nagornaya, L L; Nozzoli, F; Poda, D V; Podviyanuk, R B; Polischuk, O G; Prosperi, D; Shlegel, V N; Tretyak, V I; Tupitsyna, I A; Vasiliev, Ya V; Vostretsov, Yu Ya


    The radioactive contamination of ZnWO4 crystal scintillators has been measured deep underground at the Gran Sasso National Laboratory (LNGS) of the INFN in Italy with a total exposure 3197 kg x h. Monte Carlo simulation, time-amplitude and pulse-shape analyses of the data have been applied to estimate the radioactive contamination of the ZnWO4 samples. One of the ZnWO4 crystals has also been tested by ultra-low background gamma spectrometry. The radioactive contaminations of the ZnWO4 samples do not exceed 0.002 – 0.8 mBq/kg (depending on the radionuclide), the total alpha activity is in the range: 0.2 - 2 mBq/kg. Particular radioactivity, beta active 65Zn and alpha active 180W, has been detected. The effect of the re-crystallization on the radiopurity of the ZnWO4 crystal has been studied. The radioactive contamination of samples of the ceramic details of the set-ups used in the crystals growth has been checked by low background gamma spectrometry. A project scheme on further improvement of the radiopur...

  13. On the dynamic behavior of a wind turbine-generator system with a Darrieus-Savonius hybrid wind turbine; Hybrid furyoku turbine wo mochiita furyoku hatsuden system no kyodo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Wakui, T.; Tanzawa, Y.; Hashizume, T.; Ota, E. [Waseda University, Tokyo (Japan). School of Science and Engineering; Terashima, Y.; Machiyama, T. [Nippon Institute of Technology, Saitama (Japan)


    In order to clarify the dynamic characteristics of a self-controlled Darrieus-Savonius hybrid wind turbine system, a system consisting of a hybrid wind turbine and an AC generator was tested under various wind conditions in the wind tunnel. We took up four types of wind blowing change for the test; ramp, sinusoidal and square wind velocity changes and a similar wind velocity change to the field wind. A series of tests substantiated the effectiveness of our operating scheme wherein the tip speed ratio is maintained at a constant value. On the other hand, theoretical studies have been carried out on the characteristics of the system. A simulation model is presented in order to describe the system characteristics not only for the steady-state behavior but also for the dynamic behavior. In spite of its simplicity, the model can predict both characteristics of the system well. The appropriateness of the simulation model is confirmed by comparing with the experimental results. -In addition, the field test data are discussed. As a result, it is confirmed that the system is operated and controlled satisfactorily in the field. 14 refs., 19 figs., 3 tabs.

  14. Preparation of Ni-Cr overlay weld alloy with finely dispersed NbC particles from (Ni-Cr)/NbC composite powder. Fukugo funmatsu wo mochiita bisai NbC ryushi bunsan Ni-Cr nikumori gokin no sakusei

    Energy Technology Data Exchange (ETDEWEB)

    Tomita, T.; Takatani, Y. (Hyogo Prefectural Inst. of Industrial Research, Hyogo (Japan)); Harada, Y.; Nagai, K. (Tocalo Co. Ltd., Kobe (Japan))


    In previous studies, Ni-Cr overlay alloy containing NbC particles, formed by the plasma powder welding process, was found to exhibit excellent wear and corrosion resistances. However, any overlay alloy with dispersed NbC particles having a diameter below a few micron, has not been yet obtained. In this study, a composite powder was prepared by compounding 40 vol.% of NbC powder having an average grain diameter of 1.3 [mu]m into Ni-50 mass% Cr alloy powder, and then mixing, granulating and sintering. Plasma powder weddings were carried out on a mild steel plate using this complex powder, and the effect of plasma arc current on melting of complex powder particles and dispersion behavior of NbC particles was studied by structure observation and X-ray diffractometry. As a result, it was clarified that by selecting the proper plasma arc current and controlling the heat input, uniform dispersion of fine NbC particles having a diameter of a few micron into the matrix was possible. 18 refs., 8 figs., 3 tabs.

  15. Estimation of real ship propelling performance by the surface velocity lattice method using model ship flow field data; Mokeisen ryujo data wo mochiita hyomen uzu koshiho ni yoru jissen suishin seino no suitei

    Energy Technology Data Exchange (ETDEWEB)

    Kai, H.; Ikehata, M.; Sakai, S. [Yokohama National University, Yokohama (Japan). Faculty of Engineering


    This is basically a technique wherein the wing element method is replaced by a surface vortex lattice method. A horseshoe vortex of unknown intensity and source surface of known intensity are distributed on the wing surface and, under conditions that the fluid will not cross the boundary, the intensity of horseshoe vortex circulation is calculated for the solution of the fluid field. For the simulation of a real ship in navigation, the required propeller revolution thrust is determined using the real ship resistance value and real ship thrust reduction factor estimated from a model ship resistance test by extrapolation. The calculation of propeller performance is conducted in the quasi-steady condition using the force of fluid working on one wing for each wing angle (with the wing rotated at the increment of 6 degrees), and the thrust and torque are determined using the averages of values obtained in one cycle. It is found that the torque value is overestimated in a considerable degree in the wing element theory. In the surface vortex lattice method, both thrust and torque values agree with experimental values mostly, and this method is found to be accurate enough as a navigation element calculation tool when many panels are considered. 4 refs., 5 figs., 1 tab.

  16. Development of movie caption translation lecture site using MobileMotion{sub TM}; MobileMotion{sub TM} wo mochiita jimaku hon'yaku koza site no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)



    The site of Internet that performs the correspondence education for bringing up a movie caption translator was developed. Correspondence education that fully deepens understanding was obtained by distributing a motion picture using MPEG-4 distribution software (MobileMotion{sub TM}) and performing the learning based on bi-directional communication. HTML distribution and E-mail transmission and reception are done from Gaga Communications, and a MobileMotion{sub TM} file is distributed from the OnDemand Server of Toshiba. This reduces the communication traffic of heavy motion picture data. (translated by NEDO)

  17. Positron lifetime measurements and positron-annihilation induced auger electron spectroscpy using slow positron beams; Teisoku yodenshi bimu wo mochiita yodenshi jumyo sokutei oyobi yodenshi shometsu reiki oje denshi bunko

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, R. [Electrotechnical Lab., Tsukuba (Japan)


    Slow positron beam with less than several eV can be controlled freely such as accelerating, throttling the beam size, shortening the pulse or making pulse with short time width and so forth. These low positron beams are applied to various measurements like Doppler broadening measurement of annihilation {gamma} rays or lifetime measurement of positron, and secondary particle measurements using positron microscope, positron electron ray diffraction, flight time method and so forth. In particular, these recent years, high intensity slow positron beams were possible using accelerators like electron linac and its application is increasing. In this report, pulse shortening method for high intensity slow positron beam, and incidence energy variable positron lifetime measurement method using this slow pulsed beam and flight time type positron-annihilation-induced auger electron spectroscopy are outlined. In future, these measurements can be possible to carry out with high resolution and also with high counting rate if higher intensity monochromatic excellent positron beam than present one is produced. 31 refs., 5 figs.

  18. Non-contact evaluation of mechanical properties of electroplated wear resistant Ni-P layer from the velocity dispersion of laser SAW; Laser reiki Rayleigh ha no sokudo bunsan wo mochiita taimamo Ni-P mekkiso tokusei no hisesshoku hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Morikawa, Y.; Cho, H.; Takemoto, M. [Aoyama Gakuin University, Tokyo (Japan). Faculty of Science and Engineering; Nakayama, T. [Kobe Steel Ltd., Kobe (Japan)


    We developed a new laser surface acoustic wave (SAW) system and applied this to estimate the mechanical properties of the wear-resistant Ni-P layer electroplated on a stainless steel. The velocity dispersions of Rayleigh wave of the as -plated and heat-treated Ni-P layer were obtained by the one point time domain signal processing. The Ni-P layers with excellent wear resistance produced by the heated treatment higher than 725K were found to show higher Rayleigh velocities than that of the substrate steel, while the Ni-P layer with poor wear resistance showed lower velocities. Young`s moduli of the Ni-P layer, estimated so as the computed velocity dispersion agreed with the measured one, increased with the increase of wear resistance. 10 refs., 9 figs., 2 tabs.

  19. Magnetic properties of Nd-Fe-B magnets sintered using granulated powders by spray drying method. 3; Spray zoryufun wo mochiita Nd-Fe-B shoketsu jishaku no jiki tokusei. 3

    Energy Technology Data Exchange (ETDEWEB)

    Kishimoto, Y. [Sumitomo Metal Industries Ltd., Osaka (Japan); Yamashita, O. [Sumitomo Special Metals Co. Ltd., Osaka (Japan)


    Using two kinds of polymers with different tensile strengths and plasticizer as binders for the spray drying method of Nd2Fe14B rare earth system alloy powder, the relation between binder composition and powder characteristics or sintered magnet characteristics was studied. The binder polymers with high tensile strength improved the binding strength between alloy powders, and formed the secondary grain powder with a flowability superior in granulation. An increase in residual carbon was controlled to 200-300ppm by decarbonization at 673K for 0.5h. Reduction of an oxygen content in granulated powders was important for improving magnet characteristics. Magnet characteristics of sintered bodies were largely dependent on the amount of added plasticizer. The higher flexibility of binders due to addition of more amount of plasticizer reduced the binding strength between alloy powders and slightly reduced the flowability, however, improved magnet characteristics. The binder composed of PVA of 0.2wt% and plasticizer (glycerine) of 0.09wt% was most suitable. 4 refs., 7 figs., 1 tab.

  20. Evaluation of the autonomic neuropathy function immediately after a change to upright posture using the impulse response function; Impulse oto kansu wo mochiita shisei henkan katoki ni okeru jiritsu shinkei kino hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, K. [Nagoya City University, Nagoya (Japan); Moyoshi, M.; Takata, K. [Daido Institute of Technology, Nagoya (Japan); Watanabe, Y. [Toyota College of Technology, Aichi (Japan)


    Autonomic neuropathy function immediately after a change to upright posture has been evaluated by applying transient response function of the system to the blood regulation system. The impulse response function was determined from the change in heart rate before postural change to the upright posture, and was compared with the transient change immediately after a change to the upright posture. The time series of R-R interval of electrocardiogram was used as the time series of the change in heart rate. To determine the impulse response function, an autoregressive model was applied to the R-R interval time series. The impulse response function at the steady state is a transient reaction at the impulse stimulation added to the blood regulation system. The R-R interval decreases rapidly by the autonomic neuropathy reaction in which the blood is rapidly transferred into the legs immediately after a change to upright posture. There is a close correlation between the initial temporary decrease in R-R interval and the impulse response function derived from the change in heart rate immediately after a change to the upright posture. Accordingly, the blood regulation and autonomic neuropathy functions can be evaluated by the impulse response function without actual standing test and load of tested persons. 9 refs., 3 figs., 1 tab.

  1. Resolution of digital servo control system using single-bit digital signal processing; 1 bit digital shingo shori wo mochiita seigyo no bunkaino to johoryo ni tsuite no simulation

    Energy Technology Data Exchange (ETDEWEB)

    Tojo, K.; Kurosawa, M.; Oka, K.; Higuchi, T. [The University of Tokyo, Tokyo (Japan)


    The application of single-bit digital signal processing to mechanical control system has already been proposed by the authors. Multi-bit A/D converter has been improved to the high level. But it is difficult to make more high resolution A/D by latest semiconductor technologies. There is single-bit digital signal which is generated by a delta-sigma modulator. Single-bit digital signal has small quantized error around low frequency. Then with this single-bit digital signal processing, high resolution on controlling such a narrow band width mechanical system will be realized. In this paper, resolution of analog, multi-bit and single-bit control systems are estimated with simulation. According to simulations` results, single-bit control system has higher resolution than multi-bit system in the condition of equal bit rate. 5 refs., 17 figs., 1 tab.

  2. Modified spatial autocorrelation method using autoregressive model for estimating underground velocity structure from microtremor array observation; Bido array tansa ni okeru kukan jiko sokanho no jiko kaiki model wo mochiita kairyo

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, H.; Saito, T. [Iwate University, Iwate (Japan). Faculty of Engineering; Obuchi, T. [Kawasaki Geological Engineering Co. Ltd., Tokyo (Japan)


    Spatial autocorrelation method (SAC) is an effective analysis for estimating underground S-wave velocity structure from microtremor phase velocity dispersion relation because it has larger detectable range of microtremor wavelength than frequency-wavenumber analysis. However, phase velocities estimated by conventional SAC methods such as band-pass filtered method or Fast Fourier Transform method were not precise if suitable band width was not selected for analysis. We proposed a new technique for SAC using autoregressive model which estimated spectra with high resolution because the best fitting model can be selected using AIC. We apply the new method to calculate phase velocities of microtremors which were observed at a ground of Morioka Technical High School with arrays. As a result, phase velocities calculated by the new method were continuous with frequency although those calculated by the conventional methods were scattered. This indicates that SAC functions calculated by the new method are estimated better than those by conventional SAC methods. 13 refs., 7 figs.

  3. Advanced mineral and lithological mapping using high spectral resolution TIR data from the active CO2 remote sensing system; CO2 laser wo mochiita kosupekutoru bunkaino netsusekigai remote sensing data no ganseki kobutsu shikibetsu eno oyo

    Energy Technology Data Exchange (ETDEWEB)

    Okada, K. [Sumitomo Metal Mining Co. Ltd., Osaka (Japan); Hato, M. [Earth Remote Sensing Data Analysis Center, Tokyo (Japan); Cudahy, T.; Tapley, I.


    A study was conducted on rock/mineral mapping technology for the metal ore deposit survey using MIRACO2LAS, an active type thermal infrared ray remote sensing system which was developed by CSIRO of Australia and is now the highest in spectral resolution in the world, and TIMS of NASA which is a passive type system. The area for the survey is the area of Olary/Broken Hill and Mt. Fitton of Australia. A good correlation is seen between the ground reflectance measured by MIRACO2LAS and the value measured by the chamber CO2 laser of rocks sampled at the above-mentioned area. In case that the width of spectral characteristics is below 300nm, the inspection ability by MIRACO2LAS`s high spectral resolution is more determined in mineral mapping as compared with TIMS which is large in band width. Minerals mapped using MIRACO2LAS are quartz, talc, amphibole, hornblende, garnet, supessartine, dolomite, magnesite, etc. 4 refs., 3 figs.

  4. Study of signal transduction mechanism of angiotensin 2 receptor by means of site-directed mutagenesis; Bui totsuzen hen'iho wo mochiita anjiotenshin 2 reseputa no joho dentatsu kiko no kaimei

    Energy Technology Data Exchange (ETDEWEB)

    Yamano, Yoshiaki [Tottori University, Tottori (Japan). Faculty of Agriculture


    The renin-angiotensin system (RAS) plays an important role in the regulation of blood pressure. In order to clarify the signaling mechanism mediated by angiotensin 2 receptor, Gq-protein binding amino acid residues of this receptor were clarified by site-directed mutagenesis study. Amino acid residues in the carboxyl tail region were changed by alanines, individually. These mutated receptors were expressed stably in CHO cells, and GTP effect and second messenger molecules were determined, and three residues (Y 312, F313 and L 314) in this region were determined to be concerned for the binding of Gq protein. The other signaling systems, Gi, MAP kinase, JAK-STAT mediated, were reported to be concerned for this receptor. Novel drags for high blood pressure therapy would be explored by clarifying these signaling mechanisms. (author)

  5. Magnetic field distributions on Ag-Bi2223 tape by the magnetic optical and scanning hall sensor measurements; Jiki kogakuho oyobi sosagata horu soshiho wo mochiita Ag-Bi2223 tepu hyomen deno jiba bunpu

    Energy Technology Data Exchange (ETDEWEB)

    Otake, A.; Ota, A. [Toyohashi Univ. of Tech., Aichi (Japan); Kawano, K.; Abell, S.


    We have measured the magnetic field distribution of silver sheath Bi2223 wire rod in the surface until now using the scanning Hall element method. In magnetic field distribution measuring method, there is magneto-optic method using the Faraday effect of a magnetism network film except for the Hall element method. We measured the magnetic field distribution of silver sheath Bi2223 wire rod using two techniques of the Hall element and magneto-optics method in order to understand magnetic field distribution further, and both results were compared and were examined. (NEDO)

  6. Measurement of trapped magnetic fields on Ag-sheathed Bi-2223 monofilamentary tapes using scanning Hall sensor; Sosagata hall soshi wo mochiita gin sheath Bi2223 chodendo tanshin tape hyomen deno jisoku mitsudo sokutei

    Energy Technology Data Exchange (ETDEWEB)

    Kawano, K.; Ota, A. [Toyohashi University of Technology, Aichi (Japan). Faculty of Engineering


    Two-dimensional self-field distribution was measured on the surface of Ag-sheathed Bi-2223 superconducting monofilamentary tapes using a scanning Hall sensor, to obtain the current distributions within the specimens. Based on the electromagnetic consideration, path of current flow within superconducting cores under the critical condition was modeled. Magnetic field profiles were calculated in the case of strong links of grain boundaries where high critical current density (Jc) can be expected due to the intergranular current transport, and in the case of weak links of grain boundaries where high Jc can not be expected due to local intragranular current transport. When assuming the intergranular current, calculated Jc was lower than the measured one. Distribution of Jc in the superconducting cores was suggested. When the weak link was artificially introduced in the specimens, residual magnetic field changed remarkably at the ends of superconducting cores, but it did not change at the center of cores. Such behaviors of magnetic field could be explained from the results calculated by assuming the intragranular current. This was found to be caused by the presence of intergranular weak links. 15 refs., 11 figs., 2 tabs.

  7. Ethanol production by high cell-density culture with periodic reversion of circulating flow in cross-flow filtration. Ryudo hoko henkan cross flow rokaho wo mochiita komitsudo baiyoho ni okeru ethanol seisan

    Energy Technology Data Exchange (ETDEWEB)

    Asakura, T.; Toda, K. (The University of Tokyo, Tokyo (Japan). Institute of Applied Microbiology)


    For the purpose of effective production of ethanol, high cell-density culture was examined using a bioreactor with a flat-membrane filtlation module for three kinds of ethanol production microorganism, and the productivity of ethanol fermentation was investigated. The flow direction of the culture broth circulating along a flat membrane in the filtration module was changed periodically, at intervals of 4 minutes and 1 minute, as a result of which, the filtration flux was stabilized to some degree and increased five-fold over that of the control experiment. When the cell concentration in the reactor was maintained at a constant by draining broth at a proper rate, the filtration flux was stabilized further and increased twenty-fold over that of the control experiment. The productivity and exit concentration of ethanol in this cell recycle culture when the cell concentration was 200 gl{sup {minus}1} of Bakers yeast, were 83.7 gl{sup {minus}1}h{sup {minus}1} and 30.2 gl{sup {minus}1}, respectively. For the other two kinds of yeast, high ethanol concentration and productivity were confirmed, concluding that this production method was effective. 25 refs., 9 figs., 1 tab.

  8. Coal demineralization with Ca(OH)2. Hydrothermal reaction between Ca(OH)2 and quartz; Ca(OH)2 wo mochiita sekitan no kagakuteki dakkai. Ca(OH)2 to sekitan no suinetsu hanno

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.; Tomita, A. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science


    Coal demineralization mechanism and its optimum condition were studied by hydrothermal reaction between Ca(OH)2 and quartz as a coal demineralization model. In experiment, the mixture of powder quartz and Ca(OH)2 water slurry was subjected to reaction in an autoclave under spontaneous pressure at 175-340{degree}C. After dried in N2 gas atmosphere at 105{degree}C, the reaction product was analyzed by X-ray diffraction, thermo-balance and differential thermal analysis. In measurement of quartz conversion, the specimen was analyzed by X-ray diffraction after removal of bound water by heat treatment at 850{degree}C. The mixture of clean coal deashed by NaOH and a fixed amount of quartz was also used as specimen for experiment. As the experimental result, dicalcium silicate hydrate was mainly produced at 175{degree}C, and the product changed into xonotlite through tobermorite by longer treatment at higher temperature. For complete reaction of quartz, heat treatments for 7 and 5 hours at 300 and 400{degree}C were necessary, respectively. 2 refs., 2 figs., 2 tabs.

  9. BTX production by in-situ contact reforming of low-temperature tar from coal with zeolite-derived catalysts; Zeolite kei shokubai wo mochiita sekitan teion tar no sesshoku kaishitsu ni yoru BTX no seisei

    Energy Technology Data Exchange (ETDEWEB)

    Matsunaga, T.; Fuda, K.; Murakami, K.; Kyo, M.; Hosoya, S.; Kobayashi, S. [Akita University, Akita (Japan). Mining College


    On BTX production process from low-temperature tar obtained by pyrolysis of coal, the effect of exchanged metallic species and reaction temperature were studied using metallic ion-exchanged Y-zeolite as catalyst. In experiment, three kinds of coals with different produced tar structures such as Taiheiyo and PSOC-830 sub-bituminous coals and Loy Yang brown coal were used. Y-zeolite ion-exchanged with metal chloride aqueous solution was used as catalyst. Zn{sup 2+}, Ni{sup 2+} and In{sup 3+} were used as metal ions to be exchanged. The experiment was conducted by heating a pyrolysis section up to 600{degree}C for one hour after preheating a contact reforming section up to a certain proper temperature. As a result, the Ni system catalyst was effective for BTX production from aromatic-abundant tar, while the Zn system one from lower aromatic tar. In general, relatively high yields of toluene and xylene were obtained at lower temperature, while those of benzene at higher temperature. 4 figs., 1 tab.

  10. Toxicity assessment of organochlorine compounds detected in water environment using cultured human cell lines; Hito yurai saibo baiyokei wo mochiita suikankyo shiryochu no yuki enso kagobutsu no dokusei hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Kunimoto, M.; Yonemoto, J.; Soma, Y.; Nakasugi, O. [National Institute for Environmental Studies, Tsukuba (Japan)


    As part of validation processes of in vitro toxicity assays for the risk assessment of environmental hazards, we applied an in vitro toxicity test using two human cell lines, neuroblastoma NB-1 cells and glioblastoma U-87 MG cells, to the assessment of organochlorine compounds detected in the water environment. The in vitro toxicity assay using NB-1 cells was calibrated by testing reference chemicals proposed by MEIC (Multicenter Evaluation of In Vitro Cytotoxicity), an international program for the validation of in vitro cytotoxicity assays. Beforehand, an assay using cells in frozen stock without subcultivation was examined by comparing IC50 values with the ordinary assay using subcultured cells. IC50 values for MEIC reference chemicals from the former assay showed good correlation with those from the latter assay, suggesting that the assay using cells in frozen stock can be used at least for the assessment of basal cytotoxicity. IC50 values for ten organochlorine compounds frequently detected in the sediment samples from contaminated rivers, p-chloroaniline, 3,4-dichloroaniline, p-dichlorobenzene, o-dichlorobenzene, Tris (2-chloroethyl)-phosphate, 2,5-dichlorophenol, 2,5-dichloroanisol, Triclosan and Triclocarban, were obtained with the in vitro assays and compared with their LD50 values in rats. No significant correlation, however, was seen between the IC50 and LD50 values, indicating that further improvement of in vitro toxicity assays is necessary for the application to the risk assessment of environmental hazards. 7 refs., 4 figs., 1 tab.

  11. Experiment for detecting metallic-bars in concrete using new 1.5 GHz antenna; Shingata no 1.5 GHz antena wo mochiita konkureto nai no tekkin tansa jikken

    Energy Technology Data Exchange (ETDEWEB)

    Nakabayashi, Yuko; Toshioka, Tetsuma; Goebuchi, Toru [Oyo Corp., Tokyo (Japan)


    In recent years, maintenance was increasingly needed with the aging of the concrete structures. It has been paid attention to the underground radar detection as a non-destructive detection methods in order to confirm the bar arrangement situation inside concrete. However, in the metallic bar detection using the common underground radar, it was difficult to identify the metallic bar position and concrete cover thickness when an interval of metallic bars was dense or arrangement of metallic bars was overlapped, in a case of which the metallic bars were buried in extremely shallow areas such as metallic bar concrete wall. In the application experiments of this time, it was confirmed by using the new and high frequency antenna with central frequency of 1.5 GHz that the metallic bar position and concrete cover thickness could be identified which position and concrete cover thickness were difficultly identified by the common methods by the underground radar detection in arrangement of metallic bars. (translated by NEDO)

  12. Practical use of technology for exploring obstacles and soil collapse state around shield machine using underground radar; Chichu reda wo mochiita shirudo ki shuhen no shogaibutsu to dosha hokai jotai tansa gijutsu no jitsuyoka

    Energy Technology Data Exchange (ETDEWEB)

    Tanimoto, K. [Mitsubishi Heavy Industries Ltd., Tokyo (Japan)


    A report is made on the outline and the used result of a newly developed `underground radar.` The objects for underground exploration in shield tunneling methods are divided broadly into obstacles, state of the peripheral ground, and geological change in the working place. Electromagnetic method is employed for the exploration method of this system which can explore the ground conditions very accurately and in real time although the explorable distance is a little limited. As to antennas, there are two types, i.e. the separate transmitter and receiver antenna and the integrated transceiver antenna. The antennas are mounted at the side of cutter face, at the shield machine fixed side, and at the front of the cutter face. The system configuration varies according to the type of antenna and the displaying location of the explored result. The system introduced in this report consists of a radar antenna, antenna control device, slip ring, measurement control computer, and monitoring computer. A report is made on the condition of an existing buried pipe found accidentally during drilling with a shield machine. 12 figs., 1 tab.

  13. Synthesis of (E)-9-Oxo-2-decenoic acid (the queen substance of honeybee) from methyl 3-formylpropionate; 3-horumiruporopion san mechiru wo mochiita (E)-9-okiso-2-desen san (Mitsubachi joo busshitsu) no gosei

    Energy Technology Data Exchange (ETDEWEB)

    Tsukasa, H. [Toyotama Koryo Co. Ltd., Tokyo (Japan)


    The queen substance, (E)-9-oxo-2-decenoic acid (1) is a pheromone secreted by queen honeybee (Apis mellifera) and inhibits reproductive ability of worker bees. Several synthesese have been reported. It was synthesized starting from methyl-3-formylpropionate this time. Methyl 7,7-ethylenedioxy-4-oxooctanoate was prepared by radical addition reaction from (2) and 2-methyl-2-vinyl-1,3-dioxolane and reduced to an ethyelenedioxy carboxylic acid with hydrazine and KOH. This compound was converted to an alcohol by reduction with sodium bis(2-methoxyethoxy)aluminum hydride, followed by oxidation with pyridinium chlorochromate to an acetal aldehyde, which was condensed with malonic acid and (1) was obtained after the hydrolysis with hydrochloric acid. 7 refs., 1 tab.

  14. Relation between front suspension layout and handling performance. Analysis depending on the Taguchi method and ADAMS; Front suspension layout to soda tokusei no kankei ni tsuite. Kiko kaiseki gengo wo mochiita hinshitsu kogaku ni yoru kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Okada, K. [Daihatsu Motor Co. Ltd., Osaka (Japan)


    A variation of suspension layout gives an influence to the vehicle dynamics. Examined the suspension layout variation to make the handling performance change small. Analyzed the effect of suspension layout variation about steering response delay and gain besides the tire wear effect and movable load. 3 refs., 12 figs., 4 tabs.

  15. Heat release characteristics of middle temperature latent heat storage vessel by means of direct contact heat exchange method; Chokusetsu sesshoku netsu kokanho wo mochiita chuondo sennetsu chikunetsuso no honetsu tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Inaba, H.; Horibe, A.; Ozaki, K. [Okayama University, Okayama (Japan). Faculty of Engineering; Emoto, K. [Okayama University, Okayama (Japan); Kakiuchi, H. [Mitsubishi Chemical Corp., Tokyo (Japan)


    Experiment has been performed of heat transfer characteristics of the middle temperature latent heat storage system of the direct-contact heat transfer by using m-E (meso-Erythritol, melting point of 119 degree C, latent heat of 375 kJ/kg) droplets as a latent heat storage material and silicone oil as a heat transfer medium. In the present study the liquid m-E was injected into the heat transfer medium through a circular nozzle. The m-E droplets changed from liquid to solid phase during falling in the heat transfer medium at low temperature. From the measuring results of m-E droplet diameter, falling velocity, and solidification rate, the nondimensional empirical equations of the arithmetic mean diameter of the droplets and falling velocity, the solidification rate and the overall heat transfer coefficient were derived as a function of the characteristic arithmetic mean diameter, the terminal velocity, temperature and physical properties. (author)

  16. Robust stabilization control of power system based on the direct control of generator power by series variable impedance unit; Chokuretsu kahen inpidansu wo mochiita hatsudenki denryoku no chokusetsu seigyo ni yoru robasuto keito anteika seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Hojo, M.; Mitani, Y.; Tuji, K. [Osaka University, Osaka (Japan)


    Advanced control system design method (whose application is believed to be difficult in practical use) with the advancement of technologies of power system stabilization controllers has received much attention. In particular, demand of stabilizing control system with high robustness is pointed out. Construction of linearization control system is proposed based on direct operating volume of electric output power`s generator using the series variable impedance unit in this paper. The results are summarized as follows. Based on direct control aim of a generator power out of system of controllers with reference to the swing characteristics of power generator under specification, a linearized control is manufactured. Proposed control based on simple construction using variable impedance unit which is connected continuously with transmission line is realized. Linear system which keeps eigen values pointed out by designers who predicts based on the use of proposed controller is obtained. 6 refs., 11 figs., 2 tabs.

  17. System identification of a high-rise building applying multi-input-multi-output ARX model of modal analysis; Mode kaisekigata tanyuryoku tashutsuryoku ARX model wo mochiita koso kenbutsu no system dotei

    Energy Technology Data Exchange (ETDEWEB)

    Saito, T. [Shimizu Construction Co. Ltd., Tokyo (Japan)


    Recently, with the increase of high-rise building construction, better precision is in demand in case of building model used for analyzing seismic, wind responses in the design. Particularly, the decay constant has been given uniformly for each type of structures, however, application of estimated value from practically measured results of real high-rise building in the design is preferred. In this report, purpose is to estimate the model parameters of multi-input-multi-output system by making optimum use of benefits of system identification using ARX model. Further, multi-input-multi-output ARX model based on the idea of mode analysis was established by revealing in common the self-regression coefficient for each output and algorithm for estimating its model constant was developed. Further, system identification was carried out by applying this proposed model in real seismic response record of high-rise building, effectiveness of the model was verified and seismic vibration characteristics of the building was evaluated. 27 refs.,10 figs., 2 tabs.

  18. Fiscal 2000 achievement report. Development of foaming eco-material utilizing magazine wastepaper (3rd fiscal year); 2000 nendo zasshi koshi wo mochiita happo seikei eco material no kaihatsu seika hokokusho (dai 3 nendo)

    Energy Technology Data Exchange (ETDEWEB)



    Efforts are exerted to develop cushioning material (packing material) manufacturing technologies making use of low-grade wastepaper, to commercialize a low environmental impact type cushioning material, and to promote wastepaper recycling. Activities are conducted in the three domains of (1) the development of a technology for manufacturing a foaming eco-material out of magazine wastepaper, (2) the development of manufacturing equipment, and (3) a market survey. Crushed wastepaper in a gelatinous water solution is vigorously stirred for the gelatine to go into a crosslinking reaction, and is dried for the manufacture of a cushioning material (foaming material). In domain (1), technologies for controlling crosslinking reaction and physical properties are developed, and raw materials and target material manufacturing conditions are selected so that the product price will be not higher than the price of expanded polystyrene. In fiscal 2000, studies were made on wastepaper fiber composition, characteristics of a binder to use, and plant operating conditions, and a technology was developed that stabilizes the specific weight of the foam product at 0.10 or less. Foam products were manufactured by way of trial for use with domestic appliances and optical equipment. (NEDO)

  19. Reduction of industrial waste by the employment of simultaneous desulfurization/graphite spheroidization method using magnesium; Maguneshiumu wo mochiita datsuryu/kokuen kyujoka doji shoriho no saiyo ni yoru sangyo haikibutsu no teigen

    Energy Technology Data Exchange (ETDEWEB)

    Toriyama, T.; Yamamuro, S.; Yoshida, A.; Ono, S. [Kurimoto Ltd., Osaka (Japan)


    The Sakai Factory of KURIMOTO LTD. employed a continuous porous plug desulfurization method in 1992. In this desulfurization method, the molten iron from a cupola is desulfurized with a desulfurizing agent in which calcium carbide and lime are mixed. This paper reports the details of the development of a simultaneous desulfurization/graphite spheroidization method using Mg, which aims at disusing the operation in a high-temperature environment and reducing the quantity of slag which is an industrial waste. The main results obtained are as follows. The quantity of desulfurized slag in a porous plug ladle could be reduced to zero. A total quantity of slag produced was reduced by about 70%, which was better than the target reduction. Owing to the employment of this simultaneous desulfurization/graphite spheroidization method using Mg, the operations of mixing the desulfurizing agent and removing desulfurized slag in a high-temperature environment were omitted. The S-value after the simultaneous desulfurization/graphite spheroidization became lower than 0.010%. It could be ascertained that the graphite spheroidization rate and mechanical properties of the product did not differ from those of the product obtained by a conventional desulfurization and fully satisfied the standard values of the product. 8 figs., 4 tabs.

  20. Evaluation of geological conditions by ''drilling logging system''. Yuatsu drill ni yoru sakuko data wo mochiita ganban hyoka oyobi kiriha zenpo chishitsu no yosoku gijutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, K.; Inaba, T.; Shiogama, Y.; Tezuka, Y. (KajimaCorp., Tokyo (Japan))


    In order to predict precisely geological conditions ahead of a face changing with the progress of excavation work of rock caverns such as a tunnel, the drilling logging system was developed which allows to measure, store and analyze drilling data during drilling by hydraulic rotary percussion drilling machines, and the quantitative prediction of geological conditions ahead of a face was tested applying the system to a granite site. As a result, by adopting the drilling energy rate (workload per rock volume of a drilling machine during drilling) as an analytical parameter, the good correlation was found between the drilling energy rate and geological condition (rock property classification) such as a hardness of rocks and quantity of cracks. In addition, the geological condition ahead of a face was probably predictable by estimating the distribution of the drilling energy rate in a wide area by geostatistics mehtod. 5 refs., 9 figs.

  1. Noise and vibration reduction of diesel engine vehicle making use of the active control engine mount (ACM) system; Active control engine mount (ACM) wo mochiita diesel engine tosaisha no seishukusei kojo

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, K.; Hirade, T.; Hyodo, Y.; Aihara, T.; Shikata, T. [Nissan Motor Co. Ltd., Tokyo (Japan)


    An active control engine mount (ACM) system is described, which aims at reducing noise and vibration of diesel engine vehicles. ACM systems are arranged on the front and rear mounts, and reduce the noise by lowering the spring constant. The main body of an ACM system is a hydraulic mount, and is provided with a hydraulic pressure amplifier that makes use of liquid resonance, an electromagnetic actuator that converts hydraulic pressure into force, and a load sensor that detects the force that is transmitted to the vehicle body. The controller of an ACM control system feeds electric currents as needed to an actuator so as to keep the transmission of force to the minimum so that load sensor signals will be zero. The actuator employed in this report can augment the force generated there. All the parameters for the calculation model are optimized so that controllable input amplitude will increase. In the diesel engine vehicle into which ACM systems are incorporated, vibration during the idling operation is damped by approximately 10dB, the resultant vibration level as low as that of a gasoline engine vehicle. Harmonic components are also lowered in addition the second-order component. The same is true for the booming noise that is generated by a vehicle that is running, which is again damped by approximately 10dB. 2 refs., 14 figs.

  2. Solvent extraction bis (the 2- ethylhexyl) phosphoric acid catecholamine structural property quantitative correlation; Bisu (2-echiruhekishiru) rinsan wo mochiita katekoru amin rui no yobai chushutsu to teiryoteki kozo bussho sokan

    Energy Technology Data Exchange (ETDEWEB)

    Yoshizuka, Kazuharu [Saga University, Saga (Japan); Fujimoto, Yuko; Owatari, Keisuke; Inoue, Katsutoshi


    As a basic research of separation and refinement of catecholamine (CA) by solvent extraction method which is chemical messenger of central neuron in the internal, it was extracted from dopamine (DA), adrenalin (Ad) and in hydrochloric acid aqueous solution of noradrenaline (NA). Then, each solution of chloroform. Hexane and toluene of bis (the 2 - ethylhexyl) phosphoric acid (D2EHPA) was used in respect of the stripping. All CA is CA by D2EHPA in mechanism of ion exchange: It was clarified that it was extracted as D2EHPA=1:4 complex and the extraction equilibrium constant was obtained. In addition, the consideration by molecule modeling considering the solvent effect of continuous medium types using semi-experience molecular orbital method by quantitative structural property correlation (QSPR) was carried out on got extraction equilibrium constant. (translated by NEDO)

  3. Effect of deep structure and surface layer (a) simulation study on the heavy damage belt of the 1995 Hyogoken Nanbu earthquake; Hado simulation wo mochiita `shinsai no obi` ni tsuite no kento

    Energy Technology Data Exchange (ETDEWEB)

    Feng, S.; Ishikawa, K.; Kaji, Y. [Chuokaihatsu Corp., Tokyo (Japan)


    A simulation study was done to identify the causes for the so-called heavy damage belt observed as a result of the Hyogoken Nanbu Earthquake. This study determines distributions of the maximum amplitudes on the ground surfaces, and discusses the effects of deep structures and low-velocity surface layers, based on the simulation by the wave equation with the underground model of Higashinada-ku and its vicinity in the north-south direction, observed seismic records and artificial waves. The two-dimensional scalar wave equation is used for the analysis. The velocity structure model used for the simulation is established, based on the elastic wave seismic survey results. The focus function is drawn by expanding or contracting the time scale, using the seismic records at Kobe Port Island and artificial waves. The analysis results show that the damage belt coincides with the areas at which the focusing zone of the deep structure overlap the amplification zone in the low-velocity ground surfaces, where relative density is amplified 1.5 to 2 times. It is also observed that large peaks repeat 2 to 3 times on the time scale. 5 refs., 8 figs., 1 tab.

  4. Creation of new molecules containing threading intercalator, which can bind strongly to unusual nucleic acid structures; Nuikomigata intakareta wo mochiita tokushu RNA kozo eno tokuiteki ketsugo bunshi no shoshutsu

    Energy Technology Data Exchange (ETDEWEB)

    Takenaka, Shigeori [Kyushu University, Fukuoka (Japan). Dept. of Chemical Systems and Engineering


    We have been studying the naphthalene diimide derivatives which can recognize the unusual nucleic acid structures due to the peculiar character of threading intercalator. Firstly, we synthesized the naphthalene diimide derivative carrying thymine moieties at the imide termini. This molecule was expected to have the preference for the non-alternating adenine sequence of single stranded nucleic acid. Circular dichroism and fluorescence energy transfer studies involving acridine orange, naphthalene diimide ligand, and d (GCGAAACGC) oligonucleotide showed that the ligand can prefer bulge form of the nucleic acid to hairpin structure. Secondly, we designed and synthesized the cyclic ligand linked between naphthalene diimide and ferrocene moieties. Cyclic ligand can strongly bind to nucleic acid base projecting out from double stranded nucleic acid such as mismatch base and this can be detected using electrochemical signal of the ligand. These ligands are not only suspected of anti-virus activity but also they are promising new probe of genetic polymorphism. (author)

  5. Trial to active SWD using artificial energy source. Use of monochromatic source wavelet; Jinko shingen wo mochiita SWD eno kokoromi. Tan`itsu shuhasu no shingen hakei no riyo

    Energy Technology Data Exchange (ETDEWEB)

    Tsuru, T.; Kozawa, T. [Japan National Oil Corp., Tokyo (Japan); Taniguchi, R. [Mitsubishi Electric Corp., Tokyo (Japan); Matsuhashi, K. [Matsuhashi Techno Research, Hiroshima (Japan); Nishikawa, N. [Fuji Research Institute Corp., Tokyo (Japan)


    Seismic while drilling (SWD) is an accurate and safe method for drilling, by which real-time information regarding bit location and bedding boundary below the bit can be predicted by using elastic wave during drilling of rocks in a borehole. However, the signal level is rather low compared with the noise generated from the rig during drilling, resulting in the deteriorated data quality. Since the impact resiliency is small in soft beds, it is difficult to obtain good data due to the small energy of seismic wave propagating along drilling pipe. In order to overcome these problems, active SWD method using artificial seismic source has been developed. This method provides stable low-frequency seismic wave with large energy by the artificial seismic source adopting spring-mass system resonance method. Although the seismic source wave is monochromatic, the direct wave can be sufficiently analyzed and the bit location can be detected on the time profile of seismic prospecting. Protection of borehole damage during dropping of the equipment, energy propagation efficiency in the beds, and analysis of reflected wave are future problems. 11 refs., 6 figs., 4 tabs.

  6. Method of image recognition for mixed reality. Three-dimensional position and rotation measurements using phase only correlation; Fukugo genjitsu no tame no gazo ninshiki gijutsu. Iso gentei sokan wo mochiita sanjigen buttai no ichi shisei suitei hoho

    Energy Technology Data Exchange (ETDEWEB)

    Ito, N.


    In order to fuse a real space and a virtual space to make a mixed reality, 3-D information of object in the real space is needed. Especially, it is essential to measure the position and rotation angle of a 3-D object. There is a pattern matching algorithm called Phase Only Correlation (POC) which is able to measure the rotation angle and the position between two images. However, it is impossible to measure the rotation angle of 3-D object using POC directly, because the axis of 3-D rotation is variable. In this report, we describe the position and rotation angle measurements between two 3-D objects using POC. (author)

  7. Degradation characteristics of toxic microcystis viridis by mastigophora, monas guttula using aquatic large scale microcosm; Ogata tansui microcosm wo mochiita benmochurui monas guttula ni yoru yudoku microcystis viridis no bunkai tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Iwami, N.; Matsumura, M. [University of Tsukuba, Ibaraki (Japan); Inamori, Y. [National Inst. for Environmental Studies, Tsukuba (Japan); Sugiura, N. [Ibaraki Prefectural Waterworks, Ibaraki (Japan)


    Mastigophora, monas guttula, is able to propagate even by using large aquatic microcosm. This mastigophora efficiently predated and degraded microcystis viridis producing toxic substance, microcystin, almost in the whole quantity in the wide water temperature range from 20{degree}C to 30{degree}C at which microcystis propagates and disappears in natural lakes. As a result of evaluating perdition and degradation effects of momas guttula by chlorophyll-a and COD, any of chlorophyll-a indicated a removal rate of more than 90% almost in a week, and microcystis-origin particle COD more than 80%. It was also found that three kinds of microcystin YR, LR, and RR which microcystis viridis produces are almost completely degraded. From these results, it was thought that perdation and degradation of microfauna like m. guttula can greatly contribute to degrading and disappearing toxic microcystis even in natural lakes. 21 refs., 9 figs., 2 tabs.

  8. Estimation of water-coal surface interaction during heat treatment of coal by use of FTir and DSC; FTir to DSC wo mochiita sekitan-mizu kan sogo sayo no teiryoteki hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Miura, K.; Mae, K.; Morozumi, F.; Kusakawa, T. [Kyoto University, Kyoto (Japan)


    The authors have recently presented a method to estimate the strength distribution of hydrogen bondings in coal using FTir and DSC. The method was applied to estimate the strength of coal-water interaction in two different coals and to estimate the enthalpy change deriving from the change in hydrogen bondings during the desorption of water. The estimated enthalpy change was compared with the total enthalpy change estimated by DSC measurement to examine the importance of hydrogen bondings during the desertion of water. 1 ref., 6 figs.

  9. Earth retaining system by means of cylindrical slurry wall of high strength and high flowability concrete; Kokyodo / koryudo concrete wo mochiita enkei haku gata renzoku chichu heki ni yoru yamadome

    Energy Technology Data Exchange (ETDEWEB)

    Nakano, M.; Tsutsumi, Y. [Tokyo Gas Co. Ltd. (Japan); Moriya, M. [Taisei Construction Co. Ltd., Tokyo (Japan)


    A LPG underground tank (60,000 cu.m, 48m in dia.) was constructed at Tsurumi ward of Yokohama city by Tokyo Gas Ltd. In advance of evacuation work, RC elements which have the highest strength in Japan were applied as connected wall for earth self-retaining. One stage of the wall (1.0m in thickness) was composed of 28 elements. In order to prevent the lifting force by the underground water against the tank bottom (design level (DL) is -32.8m), amount of permeable water from outside must be as small as possible. Owing to driving the wall into the soft bedrock by 10m, the lower end of the wall came to be DL-66m. For the purpose of estimation of permeabilities of the clay layer and the soft bedrock, simulation applying the non-stationary effective stress analysis was carried out at the time of inside draining and of excavation at intervals of 8m. Results of simulation showed that the permeabilities of the connected wall and the soft bedrock belonged to the smallest class. It is considered that the satisfactory achievement has been obtained because actual amount of gushing water has been almost constant at 6 cu.m/day. 4 refs., 8 figs., 6 tabs.

  10. Measurements of ultrasonic waves by means of laser Doppler velocimeter and an experimental study of elastic wave propagation in inhomogeneous media; Laser doppler sokudokei ni yoru choonpa keisoku to ganseki wo mochiita fukinshitsu baishitsu no hado denpa model jikken

    Energy Technology Data Exchange (ETDEWEB)

    Nishizawa, O.; Sato, T. [Geological Survey of Japan, Tsukuba (Japan); Lei, X. [Dia Consultants Company, Tokyo (Japan)


    In the study of seismic wave propagation, a model experimenting technique has been developed using a laser Doppler velocimeter (LDV) as the sensor. This technique, not dependent on conventional piezoelectric devices, only irradiates the specimen with laser to measure the velocity amplitude on the target surface, eliminating the need for close contact between the specimen and sensor. In the experiment, elastic penetration waves with their noise levels approximately 0.05mm/s were observed upon application of vibration of 10{sup 6}-10{sup 5}Hz. The specimen was stainless steel or rock, and waveforms caught by the LDV and piezoelectric device were compared. As the result, it was found that the LDV is a powerful tool for effectively explaining elastic wave propagation in inhomogeneous media. The piezoelectric device fails to reproduce accurately the waves to follow the initial one while the LDV detect the velocity amplitude on the specimen surface in a wide frequency range encouraging the discussion over the quantification of observed waveforms. 10 refs., 7 figs.

  11. Design and construction of radiant panel for cooling and heating with photovoltaic and thermoelectric element modules; Taiyo denchi to netsuden soshi module wo mochiita fukusha reidanbo panel no sekkei oyobi shisaku

    Energy Technology Data Exchange (ETDEWEB)

    Sato, M.; Tani, T. [Science University of Tokyo, Tokyo (Japan); Kadotani, K.; Imaizumi, H. [Komatsu Ltd., Tokyo (Japan)


    Utilizing cooling properties and current voltage characteristics of a small cooling panel using thermoelectric elements which had been fabricated previously on a trial basis, design and prototype production were executed on a large radiant cooling and heating panel driven by photovoltaic cell modules. The panel design set the cooling area to about 0.5 m {sup 2} and the number of elements to 70 pieces, and optimum number of elements in series and parallel connection was derived. As a result of the analysis, it was made clear that the optimum number of thermoelectric module arrays in series and parallel connection varies depending on insolation intensity. It was found preferable that the number of parallel connection array be set to one to two in a region or time period in which low insolation intensity is distributed in greater amount. In the case where high insolation intensity is distributed in a greater amount, setting it to two to three is preferable. By using the structured design method and the HASP Tokyo data, thermoelectric element modules were interconnected with 35 modules in series and two in parallel on a cooling panel installed on the roof of the Science University of Tokyo. A simulation result revealed that the average temperature difference on the cooled surface in summer is 4.37 degC, and the solar cell utilization rate is 0.67. It is necessary in the future to improve heat dissipation efficiency and area ratio. 1 ref., 12 figs., 5 tabs.

  12. Fundamental study on hydrogen storage with hydrogen absorbing alloys. Operating characteristics of storage tank; Suiso kyuzo gokin wo mochiita suiso chozo ni kansuru kiso kenkyu. Chozo yoki no dosa tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Sekiguchi, S.; Sekiguchi, N.; Tani, T. [Science University of Tokyo, Tokyo (Japan)


    Hydrogen absorption by a hydrogen storage (MH storage) is investigated for static characteristics, with a constant current applied to the hydrogen generator, and dynamic characteristics, with a fluctuating current applied to the same simulating actual insolation. In the experiment, alloy temperature (MH temperature) in the storage and a current for the generator are preset, and then automatic measurement is allowed to proceed at 10-second intervals of the differential pressure, hydrogen temperature in the piping, absolute pressure, MH temperature, room temperature, and water tank temperature. It is found as the result of the experiment that absorption performance is improved when the MH storage is cooled; that the mean absorption rate which is 1 without cooling increases to 1.62 at 7degC; that the mean absorption rate changes in proportion to the applied current (introduced hydrogen flow rate); that the rate which is 1 at 32A decreases to 0.53 that at 16A; that the absorption rate is dependent more on the current applied to the storage than the temperature of the heat exchanging medium; and that, even in the presence of fluctuation halfway in the applied current, the total absorption will be equal to a case of constant current application if the total amount of applied current is equal. 2 refs., 7 figs., 5 tabs.

  13. Development of emergency backup power system using photovoltaic/wind hybrid power source in unmanned relay broadcasting station; Mujin chukei hosojo ni okeru taihoko/furyoku hybrid dengen wo mochiita hijo yobi dengen system no kaihatsu. 1

    Energy Technology Data Exchange (ETDEWEB)

    Nishikawa, S.; Takanaga, T. [Kandenko Co. Ltd., Tokyo (Japan); Sugimoto, T.; Fujiwara, S. [Japan Broadcasting Corp., Tokyo (Japan)


    An examination was made on the application of photovoltaic and wind power generation as an emergency backup power source. In this connection, the designing/manufacturing was carried out for a field demonstration test system, and also a simulation was carried out concerning the system performance. In the structure of the hybrid power source, a wind power generator is parallelly connected to a solar cell through a DC/DC converter for adjusting output voltage. It is further parallelly connected to an existing power system through a switch, supplying power to storage batteries or a broadcasting equipment. The result of the simulation revealed that, in the static characteristics, there was an output from the wind power generation if the wind velocity was 2.4m/s or above, but that a discharge from storage batteries was necessary even in the maximum performance of the wind power generation if the intensity of solar radiation was less than approximately 0.5kW/m{sup 2}. In the dynamic characteristics, an evaluation was made on the length of time of the on-load power supply after a power failure of the system in comparison with the conventional length, depending on the conditions of the wind. 2 refs., 7 figs., 1 tab.

  14. Improvement of sound qualities using simulated car interior noise. Part 2. ; Estimation by semantic differentials. Jinko AM on wo mochiita joyosha shanaion no onshitsu kaizen ni kansuru kenkyu. 2. ; SD ho ni yoru onshitsu hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T.; Hatano, S. (Seikei Univ., Tokyo (Japan). Faculty of Engineering); Takao, H. (Maruyasu Industries Ltd., Aichi (Japan))


    In the present report, a method to quantitatively evaluate the roughness was proposed by using artificially prepared sound and multi-dimensionally investigating the influence of roughness, as felt, generated from amplitude-modulated sound components, on the sound quality. While evaluation method was also studied of loudness of sound, having many vectorial components in the low region, like that, used in the present experiment. The existence of amplitude-modulated sound components in the complex sound is connected to subjective feeling of uncomfort. Even without change in physical sound energy, the roughness can be lowered if amplitude-modulated sounds in two band zones are made antiphasic in phase to be synthesized. In order to measure, with a good correspondence to the loudness, complicated sound, like that, inside the car, in sound pressure level, simulation head is effectively utilized. As a physical quantity, good in correspondence to the roughness, as felt, of timewise fluctuant sound, the total of components, read in value, is so regarded in 5 to 50Hz upon a 1/3 octave analysis of effective sound pressure in timewise fluctuant component. 10 refs., 10 figs., 2 tabs.

  15. Construction of the curtain wall made of carbon fiber reinforced concrete. Sangenjaya Carrot Tower; Tanso sen`i hokyo konkurito wo mochiita katen uoru no seko - sangenjaya kyarotto tawa -

    Energy Technology Data Exchange (ETDEWEB)

    Hara, H.; Sasaki, M.; Honda, Y. [Tokyu Construction Co. Ltd., Tokyo (Japan)


    The characteristics of the carbon fiber reinforced concrete (CFRC) for the construction of the above-titled curtain walled tower, its full-size property test and the result of building work are reported. In the beginning, the composition of CFRC materials and their blending are described and the relationship between the mixing time with a mixer destined for that purpose and the mortar flow and the quality control on the CFRC control specimens are explained, followed by a description on the CFRC weight, water content, the use of stainless reinforcement bars to suppress corrosion, dry shrinkage, the relationship between bending strength and Young coefficient, durability, the bonding state obtained by traction test and so forth, together with an outline of the test result, It is also clarified that an ultimate strength taken in member design is assumed to be the one at the moment of bending crack at a high-wind occurring once during 150 years, and the safety is assured by the reinforcement of deformed stainless bars. Further, the working steps from the form construction to the fluorocarbon resin painting are indicated enumerating requirements for the curtain wall properties in terms of water-tightness, windresisting, aseismicity and so on. Lastly, some improvements made through the experiments and the state of construction work are noted. 5 refs., 14 figs., 4 tabs.

  16. Preparation of activate carbon with high specific surface area from beer lees by chemical activation with KOH; Suisankakariumu wo mochiita yakuhin fukatsuho ni yoru birukasu karano kohihyoumenseki kasseitan no seizo

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, J.; Kubo, A.; Furukawa, A.; Muroyama, K. [Kansai University, Osaka (Japan). Dept. of Chemical Engineering


    Activated carbons with high specific surface area were prepared from beer lees by chemical activation with KOH. We examined the influence of the preparation conditions, such as temperature and impregnation ratio, on the pore structure of the prepared activated carbon. The specific surface area increased with an increase in carbonization temperature up to 800 degree C and decreased at 900 degree C because of excess activation. It reached a maximum value at the impregnation ratio of 2.0. The activated carbon, which was prepared at the carbonization temperature of 800 degree C and at the impregnation ratio of 2.0, had very high specific surface area of 2,440 m{sup 2}/g. It was found that KOH worked effectively as the activating reagent in two temperature ranges, below 500 degree C and above 600 degree C. The amount of benzene and acetone adsorbed on the prepared activated carbon were much larger than that on the commercial activated carbons. (author)

  17. On-site processing systems for determination of the phase velocity of Rayleigh waves in microtremors using the spatial autocorrelation method; Kukan jiko sokanho wo mochiita bidochu no Rayleigh ha iso sokudo no genba kettei system

    Energy Technology Data Exchange (ETDEWEB)

    Matsuoka, T.; Umezawa, N. [Saitama Institute of Environmental Pollution, Saitama (Japan)


    To render the spatial autocorrelation (SAC) method easier to use, a system has been constructed that can be used with ease on the site for the calculation of phase velocities. This system can perform two observation methods of the same frequency characteristics, that is, the simultaneous multi-point observation and one-point independent observation. The pickup is a velocity type seismograph of a natural period of 1 second that has been so electrically adjusted as to work on an apparent natural period of 7 seconds. Among the frequency characteristics, those related to phase are regarded as important because the SAC method is based on the measurement of coherence between two points. The analysis software runs on a waveform processing software DADiSP/WIN designed for personal computers. To know the operability of this system on the site and to accumulate records using the SAC method, observations were made at the depth of 100-500m at 6 locations in Saitama Prefecture where the underground structure was known thanks to prior PS logging. As the result, a dispersion curve was obtained by use of an array of appropriate dimensions at every location agreeing with the underground structure. 9 refs., 10 figs.

  18. Development of constructed wetland using hydroponic biofilter method for purification of hyper-eutrophic lake water; Fueiyoka kosui no joka no tameno suiko seibutsu rokaho wo mochiita jinko shicchi no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Aizaki, M. [Shimane Univ., Matsue (Japan)] Nakasato, H. [Top Ecology Co. Ltd., Tokyo (Japan)


    Applying the hydroponic biofilter method as a direct purification method for a hyper-eutrophic lake water, an experiment was carried out at the Tsuchiura Port on Lake Kasumigaura to obtain data for constructing a hydrophilic artificial wetland. Purification of hyper-eutrophic lake water containing a large amount of water blooms in summer was attempted applying the hydroponic biofilter method for which hydrophyte is used. As a result, it was clarified, by applying the hydroponic biofilter method, that capturing effect of suspended substances can be achieved in the rooting zone, captured suspended substances are decomposed at high rate, and the revolved nutrient salt can be absorbed and assimilated by the use of plants having high growth rates. Ipomoea aquatica had the highest removal activity, followed by nasturtium officinal, menthe spicata, and oenanthe javanica. As a result, it became clear that a constructed wetland made with the hydroponic biofilter method can be applied as a direct purifying method for hyper-eutrophic lake water by selecting appropriate plants in accordance with season. 18 refs., 1 fig., 4 tabs.

  19. Ultimate strength analysis of thin plated structures using eigen-functions. 3rd Report. Application to reliability analysis; Koyu kansu wo mochiita usuita kozobutsu no dansosei kaisekiho. 3. Shinraisei kaiseki eno oyo

    Energy Technology Data Exchange (ETDEWEB)

    Ueda, Y. [Osaka University, Osaka (Japan). Welding Research Institute; Masaoka, K.; Okada, H. [University of Osaka Prefecture, Osaka (Japan). Faculty of Engineering


    A reliability analysis was performed on ultimate strength of a hull by introducing reliability engineerings into the idealized structural unit method. Elements developed under the present study were applied to a model of an actual structure to indicate that even an analysis requiring much time under the finite element method can be performed in a short time and at high accuracy when this method is used. Analysis acted with bending moment and shear force simultaneously was performed on a model used as a structure in experiments carried out by Nishihara, assuming pure bending moment and longitudinal strength during slamming. Then, a reliability analysis was conducted on the same model based on this analysis method to investigate the ultimate strength. In an analysis of an ultimate strength when bending and shearing that assume slamming act upon simultaneously, axial force in the hull side decreases as loading increases, wherein how the shearing force increases can be identified clearly. Although existence of initial bends reduces the strength, the effect of variance in the vicinity of the average value on the reliability is rather small, while the effect due to variance in yield stress is greater. 27 refs., 14 figs., 4 tabs.

  20. Selective production of ricinoleic acid by hydrolysis of castor oil using lipase immobilized in N-polyisopropylacrylamide gel; Ripaze koteika N-poriisopuropiruakuriruamidogeru wo mochiita himashiyu no kasuibunaki ni yoru rishinorusan no sentakuteki seisei

    Energy Technology Data Exchange (ETDEWEB)

    Goto, M.; Hatanaka, C.; Haraguchi, T. [Kitakyushu National College of Technology, Fukuoka (Japan)


    Lipase from Candida cylindracea or Rhizopus was immobilized in gel beads prepared by copolymerization of N-isopropylacrylamide, N-N'-methylenebisacrylamide, and acrylamide. The hydrolysis reaction of castor oil was carried out at 37 degree C by using immobilized lipase or free lipase. The optimal condition of immobilization of lipase and the productivity of ricinoleic acid is investigated. It is found that thermal inactivation of enzyme was suppressed and the formation of by-products such as estolide decreases by immobilization into the gel compared with free lipase. (author)

  1. Study on wave power generation of electricity using torsion arc blade type horizontal axis wind turbine; Nejire enko yokugata suihei jiku fusha wo mochiita haryoku hatsuden ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kojima, N.; Kishimura, K. [Meiji University, Tokyo (Japan)


    Windmilling characteristics of a combination of a torsion arc blade type (TABT) horizontal axis wind turbine and a reverse torsion arc blade type (RTABT) horizontal axis wind turbine were evaluated in a wave activated power generation experiment. The TABT wind turbine had six blades, and the front and rear parts of the blade were twisted in the same direction, which caused the direction of rotor rotation to change as the direction of wind along the shaft changed. The RTABT wind turbine had twelve blades, and the front and rear parts of the blade were twisted reverse to each other, which allowed the direction of rotor rotation to stay constant even in the presence of wind direction reversal. To keep the direction of rotor rotation unchanged in the presence of flow direction reversal along the power generating turbine shaft, a single-stage type RTABT wind turbine and a double-stage type were used, the double-stage type being a series connection of a first-stage RTABT (for blowout and suction) and second-stage TABT (for blowout only). Both single-type and double-type rotated in the same direction irrespective of the direction of air flow. The output of the double type was obtained by adding up the values obtained from the individual turbines. The double type was two to three times higher in efficiency than the single type in turbine revolution and power output. 2 refs., 13 figs.

  2. Fault-related-folding structure and reflection seismic sections. Construction of earth model using balanced cross section; Danso ga kaizaisuru shukyoku kozo no keitai to jishin tansa danmen. 1. Balanced cross section wo mochiita chika model no kochiku

    Energy Technology Data Exchange (ETDEWEB)

    Matsuoka, T.; Tamagawa, T. [Japan Petroleum Exploration Corp., Tokyo (Japan); Tsukui, R. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center


    Pre-stacking depth migration treatment is studied for the estimation of the fold configuration from seismic survey cross sections. The estimation of a velocity structure is necessary for the execution of such treatment, and the utilization of structural-geological knowledge is required for its interpretation. The concept of balanced cross section in relation to the fault-bend fold constructs a stratum structure model under conditions that the deformation during fold and fault formation is a planar strain, that there is no change in volume due to deformation, and that a fold is a parallel fold. In addition to the above geometric and kinetic approach, there is another fold formation process simulation model using a Newtonian fluid for study from the viewpoint of dynamics. This simulation stands on the presumption that the boundary contains a ramp that had been in presence before fold formation and that an incompressible viscous matter is mounted on the top surface. The viscous matter flows and deforms for the formation of an anticline on the ramp. Such enables the reproduction of a fault-bend fold formation process, and helpful discussion may be furthered on the dynamic aspect of this simulation. 5 refs., 4 figs.

  3. Experimental study of lightning protection effects to a overhead ground wire by a lightning rod and projection rods; Yuraishin oyobi dosshi wo mochiita kakuchisen no raigai boshi ni kansuru jikkenteki kento

    Energy Technology Data Exchange (ETDEWEB)

    Katsuragi, Y. [Chubu Electric Power Co. Inc., Nagoya (Japan); Aihara, Y. [Central Research Institute of Electric Power Industry, Tokyo (Japan)


    The overhead ground wire is generally used on transmission lines as one of the lightning protection devices for the power conductors. In recent years, the ground wire with an optical fiber cable in it (OPGW) has been employed on the transmission systems. The strands of the ground wire are, however, frequently melted down because of lightning strokes to them not only in summer but also in winter. For this reason, it is necessary to devise the new lightning protection method for the ground wire. As the protection method, lightning rods installed on the transmission tower arms and projection rods wound around a ground wire are proposed by authors. Lightning protection effects of these methods are shown by model experiments which simulate summer and winter lightning strokes. It has been made clear that these methods are useful as one of the lightning protection methods for transmission lines, and application conditions of them for practical use are also shown. 4 refs., 12 figs., 2 tabs.

  4. Photocatalytic activity of Bi2WO6/Bi2S3 heterojunctions: the facilitation of exposed facets of Bi2WO6 substrate (United States)

    Yan, Long; Wang, Yufei; Shen, Huidong; Zhang, Yu; Li, Jian; Wang, Danjun


    Bi2S3/Bi2WO6 hybrid architectures with exposed (020) Bi2WO6 facets have been synthesized via a controlled anion exchange approach. X-ray photoelectron spectroscopy (XPS) reveals that a small amount of Bi2S3 was formed on the surface of Bi2WO6 during the anion exchange process, thus leading to the transformation from the Bi2WO6 to Bi2S3/Bi2WO6. A rhodamine B (RhB) aqueous solution was chosen as model organic pollutants to evaluate the photocatalytic activities of the Bi2S3/Bi2WO6 catalysts. Under visible light irradiation, the Bi2S3/Bi2WO6-TAA displayed the excellent visible light photoactivities compared with pure Bi2S3, Bi2WO6 and other composite photocatalysts. The efficient photocatalytic activity of the Bi2S3/Bi2WO6-TAA composite microspheres was ascribed to the constructed heterojunctions and the inner electric field caused by the exposed (020) Bi2WO6 facets. Active species trapping experiments revealed that h+ and O2rad - are the main active species in the photocatalytic process. Furthermore, the as-obtained photocatalysts showed good photocatalytic activity after four recycles. The results presented in this study provide a new concept for the rational design and development of highly efficient photocatalysts.

  5. Temperature-dependent spectroscopy and microchip laser operation of Nd:KGd(WO4)2 (United States)

    Loiko, P.; Yoon, S. J.; Serres, J. M.; Mateos, X.; Beecher, S. J.; Birch, R. B.; Savitski, V. G.; Kemp, A. J.; Yumashev, K.; Griebner, U.; Petrov, V.; Aguiló, M.; Díaz, F.; Mackenzie, J. I.


    High-resolution absorption and stimulated-emission cross-section spectra are presented for monoclinic Nd:KGd(WO4)2 (Nd:KGW) laser crystals in the temperature range 77-450 K. At room-temperature, the maximum stimulated emission cross-section is σSE = 21.4 × 10-20 cm2 at 1067.3 nm, for light polarization E || Nm. The lifetime of the 4F3/2 state of Nd3+ in KGW is practically temperature independent at 115 ± 5 μs. Measurement of the energy transfer upconversion parameter for a 3 at.% Nd:KGW crystal proved that this was significantly smaller than for alternative hosts, ∼2.5 × 10-17 cm3/s. When cut along the Ng optical indicatrix axis, the Nd:KGW crystal was configured as a microchip laser, generating ∼4 W of continuous-wave output at 1067 nm with a slope efficiency of 61% under diode-pumping. Using a highly-doped (10 at.%) Nd:KGW crystal, the slope efficiency reached 71% and 74% when pumped with a laser diode and a Ti:Sapphire laser, respectively. The concept of an ultrathin (250 μm) Nd:KGW microchip laser sandwiched between two synthetic diamond heat-spreaders is demonstrated.

  6. Dry vacuum pumps (United States)

    Sibuet, R.


    For decades and for ultimate pressure below 1 mbar, oil-sealed Rotary Vane Pumps have been the most popular solution for a wide range of vacuum applications. In the late 80ies, Semiconductor Industry has initiated the development of the first dry roughing pumps. Today SC applications are only using dry pumps and dry pumping packages. Since that time, pumps manufacturers have developed dry vacuum pumps technologies in order to make them attractive for other applications. The trend to replace lubricated pumps by dry pumps is now spreading over many other market segments. For the Semiconductor Industry, it has been quite easy to understand the benefits of dry pumps, in terms of Cost of Ownership, process contamination and up-time. In this paper, Technology of Dry pumps, its application in R&D/industries, merits over conventional pumps and future growth scope will be discussed.

  7. On the nature of WO stars: a quantitative analysis of the WO3 star DR1 in IC 1613

    CERN Document Server

    Tramper, F; Hartoog, O E; Sana, H; de Koter, A; Vink, J S; Ellerbroek, L E; Langer, N; Garcia, M; Kaper, L; de Mink, S E


    Context. Oxygen sequence Wolf-Rayet (WO) stars are thought to represent the final evolutionary stage of the most massive stars. The characteristic strong O vi emission possibly originates from an enhanced oxygen abundance in the stellar wind. Alternatively, the O vi emission can be caused by the high temperature of these stars, in which case the WO stars are the high-temperature extension of the more common carbon sequence Wolf-Rayet (WC) stars. Aims. By constraining the physical properties and evolutionary status of DR1, a WO star in the low-metallicity Local Group dwarf galaxy IC 1613 and one of only two objects of its class known in a SMC-like metallicity environment, we aim to investigate the nature of WO stars and their evolutionary connection with WC stars. Methods. We use the non-LTE atmosphere code cmfgen to model the observed spectrum of DR1 and to derive its stellar and wind parameters. We compare our values with other studies of WC and WO stars, as well as with the predictions of evolutionary model...

  8. The chemistry of ZnWO4 nanoparticle formation

    DEFF Research Database (Denmark)

    Bøjesen, Espen Drath; Jensen, Kirsten Marie Ørnsbjerg; Tyrsted, Christoffer


    The need for a change away from classical nucleation and growth models for the description of nanoparticle formation is highlighted. By the use of in situ total X-ray scattering experiments the transformation of an aqueous polyoxometalate precursor mixture to crystalline ZnWO4 nanoparticles under...... hydrothermal conditions was followed. The precursor solution is shown to consist of specific Tourné-type sandwich complexes. The formation of pristine ZnWO4 within seconds is understood on the basis of local restructuring and three-dimensional reordering preceding the emergence of long range order in ZnWO4...... nanoparticles. An observed temperature dependent trend in defect concentration can be rationalized based on the proposed formation mechanism. Following nucleation the individual crystallites were found to grow into prolate morphology with elongation along the unit cell c-direction. Extensive electron microscopy...

  9. Degradation of methylene blue using porous WO3, SiO2-WO3, and their Au-loaded analogs: adsorption and photocatalytic studies. (United States)

    DePuccio, Daniel P; Botella, Pablo; O'Rourke, Bruce; Landry, Christopher C


    A facile sonochemical approach was used to deposit 3-5 nm monodisperse gold nanoparticles on porous SiO2-WO3 composite spheres, as confirmed by powder X-ray diffraction (XRD) and transmission electron microscopy (TEM). High-resolution TEM (HR-TEM) and energy dispersive X-ray spectroscopy (EDS) further characterized the supported Au nanoparticles within the Au-SiO2-WO3 composite. These analyses showed isolated Au nanoparticles within both SiO2- and WO3-containing regions. Selective etching of the SiO2 matrix from Au-SiO2-WO3 yielded a pure Au-WO3 material with well-dispersed 10 nm Au nanoparticles and moderate porosity. This combined sonochemical-nanocasting technique has not been previously used to synthesize Au-WO3 photocatalysts. Methylene blue (MB) served as a probe for the adsorption capacity and visible light photocatalytic activity of these WO3-containing catalysts. Extensive MB demethylation (azures A, B, C, and thionine) and polymerization of these products occurred over WO3 under dark conditions, as confirmed by electrospray ionization mass spectrometry (ESI-MS). Photoirradiation of these suspensions led to further degradation primarily through demethylation and polymerization pathways, regardless of the presence of Au nanoparticles. Ring-opening sulfur oxidation to the sulfone was a secondary photocatalytic pathway. According to UV-vis spectroscopy, pure WO3 materials showed superior MB adsorption compared to SiO2-WO3 composites. Compared to their respective nonloaded catalysts, Au-SiO2-WO3 and Au-WO3 catalysts exhibited enhanced visible light photocatalytic activity toward the degradation of MB. Specifically, the rates of MB degradation over Au-WO3 and Au-SiO2-WO3 during 300 min of irradiation were faster than those over their nonloaded counterparts (WO3 and SiO2-WO3). These studies highlight the ability of Au-WO3 to serve as an excellent adsorbant and photodegradation catalyst toward MB.

  10. Intrinsic Defects and H Doping in WO3 (United States)

    Zhu, Jiajie; Vasilopoulou, Maria; Davazoglou, Dimitris; Kennou, Stella; Chroneos, Alexander; Schwingenschlögl, Udo


    WO3 is widely used as industrial catalyst. Intrinsic and/or extrinsic defects can tune the electronic properties and extend applications to gas sensors and optoelectonics. However, H doping is a challenge to WO3, the relevant mechanisms being hardly understood. In this context, we investigate intrinsic defects and H doping by density functional theory and experiments. Formation energies are calculated to determine the lowest energy defect states. O vacancies turn out to be stable in O-poor environment, in agreement with X-ray photoelectron spectroscopy, and O-H bond formation of H interstitial defects is predicted and confirmed by Fourier transform infrared spectroscopy. PMID:28098210

  11. Intrinsic Defects and H Doping in WO3

    KAUST Repository

    Zhu, Jiajie


    WO3 is widely used as industrial catalyst. Intrinsic and/or extrinsic defects can tune the electronic properties and extend applications to gas sensors and optoelectonics. However, H doping is a challenge to WO3, the relevant mechanisms being hardly understood. In this context, we investigate intrinsic defects and H doping by density functional theory and experiments. Formation energies are calculated to determine the lowest energy defect states. O vacancies turn out to be stable in O-poor environment, in agreement with X-ray photoelectron spectroscopy, and O-H bond formation of H interstitial defects is predicted and confirmed by Fourier transform infrared spectroscopy.

  12. Intrinsic Defects and H Doping in WO3 (United States)

    Zhu, Jiajie; Vasilopoulou, Maria; Davazoglou, Dimitris; Kennou, Stella; Chroneos, Alexander; Schwingenschlögl, Udo


    WO3 is widely used as industrial catalyst. Intrinsic and/or extrinsic defects can tune the electronic properties and extend applications to gas sensors and optoelectonics. However, H doping is a challenge to WO3, the relevant mechanisms being hardly understood. In this context, we investigate intrinsic defects and H doping by density functional theory and experiments. Formation energies are calculated to determine the lowest energy defect states. O vacancies turn out to be stable in O-poor environment, in agreement with X-ray photoelectron spectroscopy, and O-H bond formation of H interstitial defects is predicted and confirmed by Fourier transform infrared spectroscopy.

  13. Facile Hydrogen Evolution Reaction on WO3Nanorods

    Directory of Open Access Journals (Sweden)

    Rajeswari Janarthanan


    Full Text Available AbstractTungsten trioxide nanorods have been generated by the thermal decomposition (450 °C of tetrabutylammonium decatungstate. The synthesized tungsten trioxide (WO3 nanorods have been characterized by XRD, Raman, SEM, TEM, HRTEM and cyclic voltammetry. High resolution transmission electron microscopy and X-ray diffraction analysis showed that the synthesized WO3nanorods are crystalline in nature with monoclinic structure. The electrochemical experiments showed that they constitute a better electrocatalytic system for hydrogen evolution reaction in acid medium compared to their bulk counterpart.

  14. Synthesis of Shape-Tailored WO3 Micro-/Nanocrystals and the Photocatalytic Activity of WO3/TiO2 Composites

    Directory of Open Access Journals (Sweden)

    István Székely


    Full Text Available A traditional semiconductor (WO3 was synthesized from different precursors via hydrothermal crystallization targeting the achievement of three different crystal shapes (nanoplates, nanorods and nanostars. The obtained WO3 microcrystals were analyzed by the means of X-ray diffraction (XRD, scanning electron microscopy (SEM and diffuse reflectance spectroscopy (DRS. These methods contributed to the detailed analysis of the crystal morphology and structural features. The synthesized bare WO3 photocatalysts were totally inactive, while the P25/WO3 composites were efficient under UV light radiation. Furthermore, the maximum achieved activity was even higher than the bare P25’s photocatalytic performance. A correlation was established between the shape of the WO3 crystallites and the observed photocatalytic activity registered during the degradation of different substrates by using P25/WO3 composites.

  15. Centrifugal pump handbook

    CERN Document Server

    Pumps, Sulzer


    This long-awaited new edition is the complete reference for engineers and designers working on pump design and development or using centrifugal pumps in the field. This authoritative guide has been developed with access to the technical expertise of the leading centrifugal pump developer, Sulzer Pumps. In addition to providing the most comprehensive centrifugal pump theory and design reference with detailed material on cavitation, erosion, selection of materials, rotor vibration behavior and forces acting on pumps, the handbook also covers key pumping applications topics and operational

  16. Comparing WO$(\\omega^\\omega)$ with $\\Sigma^0_2$ induction


    Simpson, Stephen G.


    Let WO$(\\omega^\\omega)$ be the statement that the ordinal number $\\omega^\\omega$ is well ordered. WO$(\\omega^\\omega)$ has occurred several times in the reverse-mathematical literature. The purpose of this expository note is to discuss the place of WO$(\\omega^\\omega)$ within the standard hierarchy of subsystems of second-order arithmetic. We prove that WO$(\\omega^\\omega)$ is implied by I$\\Sigma^0_2$ and independent of B$\\Sigma^0_2$. We also prove that WO$(\\omega^\\omega)$ and B$\\Sigma^0_2$ toge...

  17. Reactive Sputter Deposition of WO3/Ag/WO3 Film for Indium Tin Oxide (ITO)-Free Electrochromic Devices. (United States)

    Yin, Yi; Lan, Changyong; Guo, Huayang; Li, Chun


    Functioning both as electrochromic (EC) and transparent-conductive (TC) coatings, WO3/Ag/WO3 (WAW) trilayer film shows promising potential application for ITO-free electrochromic devices. Reports on thermal-evaporated WAW films revealed that these bifunctional WAW films have distinct EC characteristics; however, their poor adhesive property leads to rapid degradation of coloring-bleaching cycling. Here, we show that WAW film with improved EC durability can be prepared by reactive sputtering using metal targets. We find that, by introducing an ultrathin tungsten (W) sacrificial layer before the deposition of external WO3, the oxidation of silver, which leads to film insulation and apparent optical haze, can be effectively avoided. We also find that the luminous transmittance and sheet resistance were sensitive to the thicknesses of tungsten and silver layers. The optimized structure for TC coating was obtained to be WO3 (45 nm)/Ag (10 nm)/W (2 nm)/WO3 (45 nm) with a sheet resistance of 16.3 Ω/□ and a luminous transmittance of 73.7%. Such film exhibits compelling EC performance with decent luminous transmittance modulation ΔTlum of 29.5%, fast switching time (6.6 s for coloring and 15.9 s for bleaching time), and long-term cycling stability (2000 cycles) with an applied potential of ±1.2 V. Thicker external WO3 layer (45/10/2/100 nm) leads to larger modulation with maximum ΔTlum of 46.4%, but at the cost of significantly increasing the sheet resistance. The strategy of introducing ultrathin metal sacrificial layer to avoid silver oxidation could be extended to fabricating other oxide-Ag-oxide transparent electrodes via low-cost reactive sputtering.

  18. Examining the Gas Sensing Properties of the Nanocrystalline Sm2O3-WO3

    Institute of Scientific and Technical Information of China (English)

    邓粲达; 林冠男; 林鸿明; 杨宗烨


    In this study, nanocrystalline (NC) WO3 and Sm2O3-WO3 gas sensors have been synthesized and deposited on Al2O3 substrate by gas condensation method, then sintering to 600℃. SEM is used to observe the morphology of the surface. TEM is used to measure the particle size. The resistance of sensor is measured in different temperatures and gas concentration to evaluate the sensing properties of NC WO3 and NC Sm2O3-WO3 sensor. The results indicate that WO3 is a usability gas sensor material. After Sm2O3 is doped in WO3, it does not obviously influence CO detection; it owns better sensitivity and stability. To UV irradiation on WO3, the sensitivity of WO3 is enhanced and it maintains WO3 recovery properties in NO2 detecting. UV irradiation on Sm2O3 doped WO3 does not show enhanced well properties as UV illuminate on WO3.

  19. Electrochemical Behavior of TiO2 Nanoparticle Doped WO3 Thin Films

    Directory of Open Access Journals (Sweden)

    Suvarna R. Bathe


    Full Text Available Nanoparticle TiO2 doped WO3 thin films by pulsed spray pyrolysis technique have been studied on fluorine tin doped (FTO and glass substrate. XRD shows amorphous nature for undoped and anatase phase of TiO2 having (101 plane for nanoparticle TiO2 doped WO3 thin film. SEM shows microfibrous reticulated porous network for WO3 with 600 nm fiber diameter and nanocrystalline having size 40 nm for TiO2 nanoparticle doped WO3 thin film. TiO2 nanoparticle doped WO3 thin film shows ~95% reversibility due to may be attributed to nanocrystalline nature of the film, which helpful for charge insertion and deinsertion process. The diffusion coefficient for TiO2 nanoparticle doped WO3 film is less than undoped WO3.

  20. Tunable luminescence and enhanced photocatalytic activity for Eu(III) doped Bi2WO6 nanoparticles. (United States)

    Gu, Haidong; Yu, Lei; Wang, Juan; Ni, Min; Liu, Tingting; Chen, Feng


    A series of Eu(III) doped Bi2WO6 nanoparticles were synthesized by a hydrothermal process. The obtained Bi2WO6:Eu(III) nanoparticles were characterized by XRD, SEM, luminescence spectrophotometer and DRS. The XRD and TEM results indicate that the Eu(III) doping concentration has no influence on the phase and morphology. However, the Eu(III) doping can tune the luminescence and enhance the photocatalytic activity of Bi2WO6. With the increases of Eu(3+) doping concentrations, the emission intensity of WO6(6-) group decreases nut the photocatalytic activity increases. The tunable luminescence of Bi2WO6:Eu(III) nanoparticles results from the energy transfer from WO6(6-) group to Eu(III) ion. The enhanced performance can be ascribed to efficient separation of electron and hole pairs after doping Eu(III) into the Bi2WO6 lattice.

  1. Charged particle response of PbWO4

    NARCIS (Netherlands)

    Hoek, M; Doring, W; Hejny, [No Value; Lohner, H; Metag, [No Value; Novotny, R; Wortche, H


    The response of PbWO4 to high-energy protons has been investigated in two test experiments at the proton facilities Cosy and AGOR. The determined energy resolution below 360 MeV of sigma/E = 1.44%/E-gamma(1/2) + 1.97% is comparable to the known photon response. Measured spectra of inelastically

  2. Charged particle detection with PbWO4

    NARCIS (Netherlands)

    Hoek, M; Doring, W; Hejny, [No Value; Lohner, H; Metag, [No Value; Novotny, R; Wortche, H

    The response of PbWO4 to high-energy protons has been investigated in two test experiments at the proton beam facilities COSY and AGOR. The determined energy resolution below 360 MeV of sigma/E = 0.97%/E-gamma(1/2) + 3.33% is comparable to the previously deduced photon response. Energy spectra of

  3. Enhanced photocatalytic properties in well-ordered mesoporous WO3

    KAUST Repository

    Li, Li


    We used polyisoprene-block-ethyleneoxide copolymers as structure-directing agents to synthesise well-ordered and highly-crystalline mesoporous WO 3 architectures that possess improved photocatalytic properties due to enhanced dye-adsorption in absence of diffusion limitation. © 2010 The Royal Society of Chemistry.

  4. Alternative backing up pump for turbomolecular pumps (United States)

    Myneni, Ganapati Rao


    As an alternative to the use of a mechanical backing pump in the application of wide range turbomolecular pumps in ultra-high and extra high vacuum applications, palladium oxide is used to convert hydrogen present in the evacuation stream and related volumes to water with the water then being cryo-pumped to a low pressure of below about 1.e.sup.-3 Torr at K. Cryo-pumping is achieved using a low cost Kleemenco cycle cryocooler, a somewhat more expensive thermoelectric cooler, a Venturi cooler or a similar device to achieve the required minimization of hydrogen partial pressure.


    Directory of Open Access Journals (Sweden)

    P. A. Loiko


    Full Text Available An experimental setup was developed for thermal lensing measurements in the anisotropic diode-pumped laser crystals. The studied crystal is placed into the stable two-mirror laser cavity operating at the fundamental transversal mode. The output beam radius is measured with respect to the pump intensity for different meridional planes (all these planes contain the light propagation direction. These dependencies are fitted using the ABCD matrix method in order to obtain the sensitivity factors showing the change of the optical power of thermal lens due to variation of the pump intensity. The difference of the sensitivity factors for two mutually orthogonal principal meridional planes describes the thermal lens astigmatism degree. By means of this approach, thermal lensing was characterized in the diode-pumped monoclinic Np-cut Nd:KGd(WO42 laser crystal at the wavelength of 1.067 μm for light polarization E || Nm.

  6. Large electromagnetic pumps. [LMFBR

    Energy Technology Data Exchange (ETDEWEB)

    Kilman, G.B.


    The development of large electromagnetic pumps for the liquid metal heat transfer systems of fission reactors has progressed for a number of years. Such pumps are now planned for fusion reactors and solar plants as well. The Einstein-Szilard (annular) pump has been selected as the preferred configuration. Some of the reasons that electromagnetic pumps may be preferred over mechanical pumps and why the annular configuration was selected are discussed. A detailed electromagnetic analysis of the annular pump, based on slug flow, is presented. The analysis is then used to explore the implications of large size and power on considerations of electromagnetic skin effect, geometric skin effect and the cylindrical geometry.

  7. Tungsten-based nanomaterials (WO3 & Bi2WO6): Modifications related to charge carrier transfer mechanisms and photocatalytic applications (United States)

    Girish Kumar, S.; Koteswara Rao, K. S. R.


    Heterogeneous photocatalysis is an ideal green energy technology for the purification of wastewater. Although titania dominates as the reference photocatalyst, its wide band gap is a bottleneck for extended utility. Thus, search for non-TiO2 based nanomaterials has become an active area of research in recent years. In this regard, visible light absorbing polycrystalline WO3 (2.4-2.8 eV) and Bi2WO6 (2.8 eV) with versatile structure-electronic properties has gained considerable interest to promote the photocatalytic reactions. These materials are also explored in selective functional group transformation in organic reactions, because of low reduction and oxidation potential of WO3 CB and Bi2WO6 VB, respectively. In this focused review, various strategies such as foreign ion doping, noble metal deposition and heterostructuring with other semiconductors designed for efficient photocatalysis is discussed. These modifications not only extend the optical response to longer wavelengths, but also prolong the life-time of the charge carriers and strengthen the photocatalyst stability. The changes in the surface-bulk properties and the charge carrier transfer dynamics associated with each modification correlating to the high activity are emphasized. The presence of oxidizing agents, surface modification with Cu2+ ions and synthesis of exposed facets to promote the degradation rate is highlighted. In depth study on these nanomaterials is likely to sustain interest in wastewater remediation and envisaged to signify in various green energy applications.

  8. Nano-WO3 film modified macro-porous silicon (MPS) gas sensor

    Institute of Scientific and Technical Information of China (English)

    Sun Peng; Hu Ming; Li Mingda; Ma Shuangyun


    We prepared macro-porous silicon (MPS) by electrochemical corrosion in a double-tank cell on the surface of single-crystalline P-type silicon.Then,nano-WO3 films were deposited on MPS layers by DC facing target reactive magnetron sputtering.The morphologies of the MPS and WOs/MPS samples were investigated by using a field emission scanning electron microscope.The crystallization of WO3 and the valence of the W in the WO3/MPS sample were characterized by X-ray diffraction and X-ray photoelectron spectroscopy,respectively.The gas sensing properties of MPS and WO3/MPS gas sensors were thoroughly measured at room temperature.It can be concluded that:the WO3/MPS gas sensor shows the gas sensing properties of a P-type semiconductor gas sensor.The WO3/MPS gas sensor exhibits good recovery characteristics and repeatability to l ppm NO2.The addition of WO3 can enhance the sensitivity of MPS to NO2.The long-term stability ofa WO3/MPS gas sensor is better than that of an MPS gas sensor.The sensitivity of the WO3/MPS gas sensor to NO2 is higher than that to NH3 and C2H5OH.The selectivity of the MPS to NO2 is modified by deposited nano-WO3 film.

  9. Synthesis of surface sulfated BiWO with enhanced photocatalytic performance

    Institute of Scientific and Technical Information of China (English)

    Yongming Ju; Jianming Hong; Xiuyu Zhang; Zhencheng Xu; Dongyang Wei; Yanhong Sang; Xiaohang Fang; Jiande Fang; Zhenxing Wang


    Sulfated BiWO (SBiWO) was synthesized by an impregnation method to enhance the visible-light-driven photoactivities of BiWO (BiWO).The characterization results verified that sulfate anion mainly anchored on the catalyst surface greatly extended the visible-light-responsive range without destroying the crystal lattice.Moreover,the SBiWO-based photoactivities were evaluated with the removal of Malachite Green (MG) under UV-Vis irradiation emitted from two microwave-powered electrodeless discharge lamps (MPEDL-2) and under visible light (λ > 420 nm).The results demonstrated that the kinetic constant was increased 2.25 times,varying from 0.1478 (BiWO) to 0.3328 min-1 (SBiWO-1).Similar results were also obtained for the visible light-driven reaction.Furthermore,radical scavengers such as t-butanol restricted the visible-light induced degradation of MG over BiWO and SBiWO-1.This indicated that the sulfating process increased the generation of reactive oxygen species,which was further verified by molecular probe with salicylic acid.Thus,more blue-shifting at λ =618 nm was observed over SBiWO.On the basis of the above results,the photocatalytic mechanism over the sulfated catalyst was also discussed.

  10. Pump element for a tube pump

    DEFF Research Database (Denmark)


    The invention relates to a tube pump comprising a tube and a pump element inserted in the tube, where the pump element comprises a rod element and a first and a second non-return valve member positioned a distance apart on the rod element. The valve members are oriented in the same direction rela...... to a part of the tube. The invention further relates to a method for creating a flow of a fluid within an at least partly flexible tube by means of a pump element as mentioned above.......The invention relates to a tube pump comprising a tube and a pump element inserted in the tube, where the pump element comprises a rod element and a first and a second non-return valve member positioned a distance apart on the rod element. The valve members are oriented in the same direction...... portion acts to alternately close and open the valve members thereby generating a fluid flow through the tube. The invention further relates to a pump element comprising at least two non-return valve members connected by a rod element, and for insertion in an at least partly flexible tube in such tube...

  11. Proton pump inhibitors (United States)

    Proton pump inhibitors (PPIs) are medicines that work by reducing the amount of stomach acid made by ... Proton pump inhibitors are used to: Relieve symptoms of acid reflux, or gastroesophageal reflux disease (GERD). This ...

  12. Photocatalysis of WO3 Nanoplates Synthesized by Conventional-Hydrothermal and Microwave-Hydrothermal Methods and of Commercial WO3 Nanorods

    Directory of Open Access Journals (Sweden)

    Jarupat Sungpanich


    Full Text Available The degradation of methylene blue (MB dye by tungsten oxide (WO3 photocatalyst synthesized by the 200°C conventional-hydrothermal (C-H and 270 W microwave-hydrothermal (M-H methods and commercial WO3 was studied under UV light irradiation for 360 min. The photocatalysts were characterized by X-ray diffraction (XRD, scanning electron microscopy (SEM, transmission electron microscopy (TEM, Fourier transform infrared (FTIR spectroscopy, Raman spectrophotometry, and UV visible spectroscopy to determine phase, morphology, vibration mode, and optical property. The BET analysis revealed the specific surface area of 29.74, 37.25, and 33.56 m2/g for the C-H WO3 nanoplates, M-H WO3 nanoplates, and commercial WO3 nanorods, respectively. In this research, the M-H WO3 nanoplates have the highest photocatalytic efficiency of 90.07% within 360 min, comparing to the C-H WO3 nanoplates and even commercial WO3 nanorods.

  13. Pump for Saturated Liquids (United States)

    Elliott, D. G.


    Boiling liquids pumped by device based on proven components. Expanding saturated liquid in nozzle and diverting its phases along separate paths in liquid/vapor separator raises pressure of liquid. Liquid cooled in process. Pump makes it unnecessary to pressurize cryogenic liquids in order to pump them. Problems of introducing noncondensable pressurizing gas avoided.

  14. Quasi-continuous-wave 589-nm radiation based on intracavity frequency-doubled Nd:GGG/BaWO4 Raman laser (United States)

    Liu, Yang; Liu, Zhaojun; Cong, Zhenhua; Men, Shaojie; Rao, Han; Xia, Jinbao; Zhang, Sasa; Zhang, Huaijin


    Quasi-continuous-wave (QCW) 589-nm radiation was realized based on a frequency-doubled crystalline Raman laser. The fundamental wave with macro-micro-pulse trains was generated from an acousto-optically Q-switched QCW diode side-pumped Nd:GGG laser. Intracavity Raman conversion was accomplished by a BaWO4 crystal and the second harmonic generation was finished by a KTP crystal. Under a pumping power of 126.0 W with a macro-pulse frequency of 300 Hz and duration of 300 μs, the maximum 589 nm output power of 4.2 W was obtained at a micro-pulse frequency of 33.3 kHz. The micro-pulse width was 13.6 ns.

  15. Effect of Nd3+ Concentration on the Laser Performance of a New Laser Crystal∶Nd∶NaY(WO4)2

    Institute of Scientific and Technical Information of China (English)

    FU Kun; WANG Zhengping; CHENG Zhenxiang; LIU Junhai; SONG Renbo; CHEN Huanchu; SHAO Zongshu


    The transmission and emission spectra of a new crystal, Nd∶NaY(WO4)2 (Nd∶NYW) have been measured. Using a Ti∶Sapphire laser as the pump source, the laser performances of Nd:NYW crystals with different concentrations are compared for the first time. The Nd3+ concentrations used are 1, 2, 4 and 5 at.-%. The experiments show that 2 at.-% is the optimum concentration. When the incident pump power is 575 mW, the 1.06 μm output can reach 184 mW, corresponding to an optical to optical efficiency of 32%. The experimental results show that the work is significant to the further research and praction application of this promising laser crystal.

  16. Facile synthesis of hierarchical double-shell WO3 microspheres with enhanced photocatalytic activity (United States)

    Wang, Zhenfeng; Chu, Deqing; Wang, Limin; Wang, Lipeng; Hu, Wenhui; Chen, Xiangyu; Yang, Huifang; Sun, Jingjing


    Hierarchical double-shell WO3 microspheres (HDS-WO3) have been successfully obtained through the thermal decomposition of WO3·H2O formed by metal salts as the templates. The products were characterized by X-ray diffraction (XRD), and the morphology was investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In addition, the HDS-WO3 microspheres were analyzed by the Thermogravimetric (TG) and Brunauer-Emmett-Teller (BET) analysis. The synthetic mechanism of the products with hierarchical structures was proposed. The obtained HDS-WO3 exhibits excellent photocatalytic efficiency (84.9%), which is much higher than other WO3 sample under visible light illumination.

  17. Fungus mediated biosynthesis of WO3 nanoparticles using Fusarium solani extract (United States)

    Kavitha, N. S.; Venkatesh, K. S.; Palani, N. S.; Ilangovan, R.


    Currently nanoparticles were synthesized by emphasis bioremediation process due to less hazardous, eco-friendly and imperative applications on biogenic process. Fungus mediated biosynthesis strategy has been developed to prepare tungsten oxide nanoflakes (WO3, NFs) using the plant pathogenic fungus F.solani. The powder XRD pattern revealed the monoclinic crystal structure with improved crystalline nature of the synthesized WO3 nanoparticles. FESEM images showed the flake-like morphology of WO3, with average thickness and length around 40 nm and 300 nm respectively. The Raman spectrum of WO3 NFs showed their characteristic vibration modes that revealed the defect free nature of the WO3 NFs. Further, the elemental analysis indicated the stoichiometric composition of WO3 phase.

  18. WO{sub 3} nanorods prepared by low-temperature seeded growth hydrothermal reaction

    Energy Technology Data Exchange (ETDEWEB)

    Ng, Chai Yan [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Abdul Razak, Khairunisak, E-mail: [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); NanoBiotechnology Research and Innovation (NanoBRI), Institute for Research in Molecular Medicine (INFORMM), Universiti Sains Malaysia, 11800 USM, Penang (Malaysia); Lockman, Zainovia, E-mail: [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)


    Highlights: • WO{sub 3} nanorods with 5–10 nm diameter were grown directly on seeded tungsten foil. • WO{sub 3} nanorods were successfully grown at low temperature of 80 °C. • WO{sub 3} nanorods were grown on the entire surface of the seed layer after 24 h. • Annealed nanorods showed better electrochromic properties than as-made nanorods. -- Abstract: This work describes the first tungsten oxide (WO{sub 3}) nanorods hydrothermally grown on W foil. WO{sub 3} nanorods were successfully grown at low hydrothermal temperature of 80 °C by seeded growth hydrothermal reaction. The seed layer was prepared by thermally oxidized the W foil at 400 °C for 0.5 h. This work discusses the effect of hydrothermal reaction and annealing period on the morphological, structural, and electrochromic properties of WO{sub 3} nanorods. Various hydrothermal reaction periods (8–24 h) were studied. Monoclinic WO{sub 3} nanorods with 5–10 nm diameter were obtained after hydrothermal reaction for 24 h. These 24 h WO{sub 3} nanorods were also annealed at 400 °C with varying dwelling periods (0.5–4 h). Electrochromic properties of WO{sub 3} nanorods in an acidic electrolyte were analyzed using cyclic voltammetry and UV–vis spectrophotometry. WO{sub 3} nanorods annealed at 400 °C for 1 h showed the highest charge capacity and the largest optical contrast among the 24 h WO{sub 3} films. The sample also showed good cycling stability without significant degradation. Based on the results, the reaction mechanism of WO{sub 3} nanorod formation on W foil was proposed.

  19. Obtaining of films of tungsten trioxide (WO3) by resistive heating of a tungsten filament



    Thin film of tungsten oxide (WO3) has been studied extensively as an electrochromic material and has numerous applications in electrochromic devices, smart windows, gas sensors and optical windows. In order to explore the possibility of using it in electrochromic devices, thorough study the optical properties of the WO3 is an important step. The WO3 layers have been grown by hot-filament metal oxide deposition technique under atmospheric pressure and an oxygen atmosphere. By FTIR and Raman sc...

  20. Biomimetic fabrication of WO{sub 3} for water splitting under visible light with high performance

    Energy Technology Data Exchange (ETDEWEB)

    Yin, Chao; Zhu, Shenmin, E-mail:; Yao, Fan; Gu, Jiajun; Zhang, Wang [Shanghai Jiao Tong University, State Key Laboratory of Metal Matrix Composites (China); Chen, Zhixin [University of Wollongong, Faculty of Engineering (Australia); Zhang, Di, E-mail: [Shanghai Jiao Tong University, State Key Laboratory of Metal Matrix Composites (China)


    Inspired by the high light-harvesting properties of typical butterfly wings, ceramic WO{sub 3} butterfly wings with hierarchical structures of bio-butterfly wings was fabricated using a template of PapilioParis butterfly wings through a sol-gel method. The effect of calcination temperatures on the structures of the ceramic butterfly wings was investigated and the results showed that the WO{sub 3} butterfly wing replica calcined at 550 Degree-Sign C (WO{sub 3} replica-550) is a single phase and has a high crystallinity and relatively fine hierarchical structure. The average grain size of WO{sub 3} replica-550 and WO{sub 3} powder are around 32.6 and 42.2 nm, respectively. Compared with pure WO{sub 3} powder, WO{sub 3} replica-550 demonstrated a higher light-harvesting capability in the region from 460 to 700 nm and more importantly the higher charge separation rate, as evidenced by electron paramagnetic resonance measurements. Photocatalytic O{sub 2} evolutions from water were investigated on the ceramic butterfly wings and pure WO{sub 3} powder under visible light ({lambda} > 420 nm). The results showed that the amount of O{sub 2} produced from WO{sub 3} replica-550 is 50 % higher than that of the pure WO{sub 3} powder. The improved photocatalytic performance of WO{sub 3} replica-550 is attributed to the quasi-honeycomb structure inherited from the PapilioParis butterfly wings, providing both high light-harvesting efficiency and efficient charge transport through the WO{sub 3}.

  1. Fabrication of Pd Doped WO3 Nanofiber as Hydrogen Sensor

    Directory of Open Access Journals (Sweden)

    Alireza Nikfarjam


    Full Text Available Pd doped WO3 fibers were synthesized by electro-spinning. The sol gel method was employed to prepare peroxopolytungstic acid (P-PTA. Palladium chloride and Polyvinyl pyrrolidone (PVP was dissolved in the sol Pd:WO3 = 10% molar ratio. The prepared sol was loaded into a syringe connected to a high voltage of 18.3 kV and electrospun fibers were collected on the alumina substrates. Scanning electron microscope (SEM, X-ray powder diffraction (XRD and X-ray photoelectron spectroscopy (XPS techniques were used to analyze the crystal structure and chemical composition of the fibers after heat treatment at 500 °C. Resistance-sensing measurements exhibited a sensitivity of about 30 at 500 ppm hydrogen in air, and the response and recovery times were about 20 and 30 s, respectively, at 300 °C. Hydrogen gas sensing mechanism of the sensor was also studied.

  2. Surface oxygen vacancies on WO3 contributed to enhanced photothermo-synergistic effect (United States)

    Li, Yingying; Wang, Changhua; Zheng, Han; Wan, Fangxu; Yu, Fei; Zhang, Xintong; Liu, Yichun


    Photothermooxidation has demonstrated a high efficiency in the removal of volatile organic compounds in air. Among photothermocatalysts, attention is presently focused on composites of noble metal/metal oxide or metal oxide/metal oxide. Instead, in this work, we present a case of single oxide WO3 subjected to hydrogen treatment as photothermocatalyst. With the increase of hydrogen treatment temperature, the color of WO3 changes from yellow to blue to dark blue and a phase transition from WO3 to WO2.72 to WO2 is accompanied, suggesting an increase of concentration of oxygen vacancy. Photothermocatalytic test against degradation of gaseous acetaldehyde at 60 °C under UV light shows that WO3-x sample with low concentration of oxygen vacancy displays the most significant synergetic effect between photocatalysis and thermocatalysis. Its photothermocatalytic activity in terms of CO2 evolution rate is 5.2 times higher than that of photocatalytic activity. However, WO3-WO2.72 and WO2 with high degree of oxygen deficiency show insignificant synergetic effect between photocatalysis and thermocatalysis. The reason for the different synergistic effect over above samples is believed to lie in balance between decreased activation energy of lattice oxygen and recombination of photogenerated electrons and holes induced by oxygen deficiency.

  3. Photocatalysis and photoinduced hydrophilicity of WO3 thin films with underlying Pt nanoparticles. (United States)

    Miyauchi, Masahiro


    The photocatalytic oxidation and photoinduced hydrophilicity of thin tungsten trioxide (WO(3)) films coupled with platinum (Pt) nanoparticles were investigated. WO(3) films with underlying Pt nanoparticles (WO(3)/Pt/substrate) and those with overlying Pt nanoparticles (Pt/WO(3)/substrate) were synthesized by sputtering and sol-gel methods. Between these films, underlying Pt nanoparticles greatly enhanced the photocatalytic oxidation activity of WO(3) without decreasing the photoinduced hydrophilic conversion. However, overlying Pt nanoparticles deteriorated the hydrophilicity of WO(3) because the Pt nanoparticle surface was hydrophobic. The enhanced photocatalytic reaction by the Pt nanoparticles was attributed to the multi-electron reduction in Pt, which is caused by the injected electrons from the conduction band of WO(3). The relationship between photocatalytic activity and thin film structure, including the size of Pt nanoparticles, the thickness and porosity of the WO(3) layer, were investigated. Consequently, the optimum structure for high performance in both photocatalysis and photoinduced hydrophilicity was WO(3) (50 nm)/Pt(1.5 nm)/substrate, and this film exhibited a significant self-cleaning property even under visible light irradiation.

  4. Synthesis and photocatalytic properties of α-ZnWO4 nanocrystals in tungsten zinc borate glasses

    Directory of Open Access Journals (Sweden)

    Tatsuya Ida


    Full Text Available Tungsten oxide (WO3-containing glasses of WO3–ZnO–B2O3 were prepared using a conventional melt quenching method, and α-ZnWO4 nanocrystals were synthesized through the crystallization of glasses. A glass with the composition of 20WO3–50ZnO–30B2O3 showed the bulk crystallization of α-ZnWO4 nanocrystals with a diameter of ∼10 nm. Broad and asymmetric emission peaks were observed at the wavelength of λ ∼ 475 nm, i.e., blue emissions, in the photoluminescence spectra for the samples with α-ZnWO4 nanocrystals. From the degradation of the intensity of optical absorption under ultraviolet light (λ = 254 nm irradiations for the solution consisting of crystallized particles with α-ZnWO4 nanocrystals and methylene blue, it was clarified that α-ZnWO4 nanocrystals formed have photocatalytic activities. The formation of α-ZnWO4 nanocrystals is discussed from the viewpoint of the glass-forming tendency.

  5. Tailoring surface states in WO{sub 3} photoanodes for efficient photoelectrochemical water splitting

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Trilok; Müller, Ralf [Institute of Inorganic Chemistry, University of Cologne, Greinstrasse-6, D-50939 Cologne (Germany); Singh, Jai [Institute of Advanced Materials Engineering, Department of Nano Science and Technology, Sejong University, Seoul 143-747 (Korea, Republic of); Mathur, Sanjay, E-mail: [Institute of Inorganic Chemistry, University of Cologne, Greinstrasse-6, D-50939 Cologne (Germany)


    Highlights: • WO{sub 3} thin films have been synthesized by reactive sputtering under oxygen atmosphere. • Surface treatment of WO{sub 3} influences the optical and photoelectrochemical properties. • Tailoring the surface properties by (i) hydrogen plasma treatment and (ii) anchoring plasmonic nanoparticles (Au and Ag) altered the light harvesting and charge separation/transport processes of WO{sub 3} photoanodes. - Abstract: The dynamics of photo-induced charge carriers are significantly influenced by the surface states of WO{sub 3} thin films, which were synthesized by reactive sputtering of tungsten substrates in oxygen plasma. Tailoring the surface properties by (i) hydrogen plasma treatment and (ii) anchoring plasmonic nanoparticles (Au and Ag) altered the light harvesting and charge separation/transport processes of WO{sub 3} photoanodes. Upon hydrogen plasma-treatment and coating of noble metal clusters, WO{sub 3} films showed enhanced visible light absorption and consequently higher photocurrent density (1.4 mA cm{sup −2}) compared to pristine WO{sub 3} (0.2 mA cm{sup −2}). Enhancement in hydrogen treated WO{sub 3} sample was found to be due to the reduction of W(VI) into W(V) centers, which produced substoichiometric WO{sub 3−x} phases, whereas noble metal particles contributed towards both resonant and non-resonant scattering of incident light thereby increasing photon-to-current conversion efficiency.

  6. Synthesis and ionic liquid gating of hexagonal WO{sub 3} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Phillip M., E-mail:, E-mail:; Munakata, Ko; Hammond, R. H.; Geballe, T. H.; Beasley, M. R., E-mail:, E-mail: [Department of Applied Physics, Stanford University, Stanford, California 94305, USA and Geballe Laboratory for Advanced Materials, Stanford University, Stanford, California 94305 (United States); Ishii, Satoshi; Tanabe, Kenji; Tokiwa, Kazuyasu [Department of Applied Electronics, Tokyo University of Science, Katsushika-ku, Tokyo 125-8585 (Japan)


    Via thin film deposition techniques, the meta-stable in bulk crystal hexagonal phase of tungsten oxide (hex-WO{sub 3}) is stabilized as a thin film. The hex-WO{sub 3} structure is potentially promising for numerous applications and is related to the structure for superconducting compounds found in WO{sub 3}. Utilizing ionic liquid gating, carriers were electrostatically induced in the films and an insulator-to-metal transition is observed. These results show that ionic liquid gating is a viable technique to alter the electrical transport properties of WO{sub 3}.

  7. Eukaryotic association module in phage WO genomes from Wolbachia (United States)

    Bordenstein, Sarah R.; Bordenstein, Seth R.


    Viruses are trifurcated into eukaryotic, archaeal and bacterial categories. This domain-specific ecology underscores why eukaryotic viruses typically co-opt eukaryotic genes and bacteriophages commonly harbour bacterial genes. However, the presence of bacteriophages in obligate intracellular bacteria of eukaryotes may promote DNA transfers between eukaryotes and bacteriophages. Here we report a metagenomic analysis of purified bacteriophage WO particles of Wolbachia and uncover a eukaryotic association module in the complete WO genome. It harbours predicted domains, such as the black widow latrotoxin C-terminal domain, that are uninterrupted in bacteriophage genomes, enriched with eukaryotic protease cleavage sites and combined with additional domains to forge one of the largest bacteriophage genes to date (14,256 bp). To the best of our knowledge, these eukaryotic-like domains have never before been reported in packaged bacteriophages and their phylogeny, distribution and sequence diversity imply lateral transfers between bacteriophage/prophage and animal genomes. Finally, the WO genome sequences and identification of attachment sites will potentially advance genetic manipulation of Wolbachia. PMID:27727237

  8. WO3 nanotubes prepared by a coaxial electrospinning method. (United States)

    Cao, Xingxing; Zhang, Xuebin; Hu, Jixiang; Wang, Yang; Liu, Jia; Wu, Haijun; Feng, Yi


    In this paper, WO3 nanotubes were prepared by a coaxial electrospinning method. Firstly, core-shell structured composite fibers were fabricated via coaxial electrospinning under the optimal electro-spinning parameters to get the best composite fibers with uniform diameters and smooth surface, which pure PVA being the core solution and PVA/AMT/alcohol being the shell one, respectively. Secondly, the composite fibers were calcined in air at 600 °C for 4 h to wipe out the pure PVA, leading to the formation of nanotubes. After sintering, the obtained WO3 nanotubes were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). The XRD show that the resultant materials consist of pure tungsten trioxide (WO3) with good crystallinity, while FESEM and HRTEM images indicate that the materials are nanotubes with rough surface and consist of nanoparticles. The inner diameter and the wall thickness of nanotubes were calculated to be around 100 and 50 nm, respectively.

  9. Thermodynamic study of WO{sub 3} and WO{sub 3}:Li{sup +} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Avellaneda, Cesar O. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica-LIEC, Departamento de Quimica, Universidade Federal de Sao Carlos, C.P. 676, CEP 13565-905 Sao Carlos, SP (Brazil)]. E-mail:


    There is a considerable interest in the research and development of materials and devices that can be used for optical switching of large-scale glazings. Several potential switching technologies are available for glazings, including those based on electrochromic, thermochromic and photochromic phenomena. One of the most promising technologies for optical switching devices is the electrochromism (EC). In order to improve the electrochromic properties of tungsten oxide we have investigated the effect of lithium insertion on the electrochromic behavior of oxide films prepared by the sol-gel process. The kinetics and thermodynamics of electrochemical intercalation of lithium into Li {sub x}WO{sub 3} and Li {sub x}(WO{sub 3}:Li) films prepared by the sol-gel process were investigated. The standard Gibbs energy for lithium intercalation was calculated. The chemical diffusion coefficients, D, of lithium intercalation into oxide were measured by galvanostatic intermittent titration technique (GITT) as functions of the depth of lithium intercalation.

  10. Kinetics and thermodynamic behavior of WO{sub 3} and WO{sub 3}:P thin films

    Energy Technology Data Exchange (ETDEWEB)

    Avellaneda, Cesar O.; Bulhoes, Luis O.S. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica-LIEC, Departamento de Quimica, Universidade Federal de Sao Carlos, C.P. 676, CEP 13565-905, Sao Carlos-SP (Brazil)


    There is a considerable interest in the research and development of materials and devices, that can be used for optical switching of large-scale glazings. Several potential switching technologies are available for glazings, including those based on electrochromic, thermochromic and photochromic phenomena. One of the most promising technologies for optical switching devices is electrochromism (EC). In order to improve the electrochromic properties of tungsten oxide, we have investigated the effect of phosphorous insertion on the electrochromic behavior of oxide films prepared by the sol-gel process. The kinetics and thermodynamics of electrochemical intercalation of lithium into Li{sub x}WO{sub 3} and Li{sub x}WO{sub 3}:P films prepared by the sol-gel process were investigated. The standard Gibbs energy for lithium intercalation was calculated. The chemical diffusion coefficients, D, of lithium intercalation into oxide, were measured by galvanostatic intermittent titration technique (GITT), as functions of the depth of lithium intercalation. (author)

  11. Improvement of radiopurity level of enriched $^{116}$CdWO$_4$ and ZnWO$_4$ crystal scintillators by recrystallization

    CERN Document Server

    Barabash, A S; Bernabei, R; Borovlev, Yu A; Cappella, F; Caracciolo, V; Cerulli, R; Danevich, F A; Incicchitti, A; Kobychev, V V; Konovalov, S I; Laubenstein, M; Mokina, V M; Polischuk, O G; Safonova, O E; Shlegel, V N; Tretyak, V I; Tupitsyna, I A; Umatov, V I; Zhdankov, V N


    As low as possible radioactive contamination of a detector plays a crucial role to improve sensitivity of a double beta decay experiment. The radioactive contamination of a sample of $^{116}$CdWO$_4$ crystal scintillator by thorium was reduced by a factor $\\approx 10$, down to the level 0.01 mBq/kg ($^{228}$Th), by exploiting the recrystallization procedure. The total alpha activity of uranium and thorium daughters was reduced by a factor $\\approx 3$, down to 1.6 mBq/kg. No change in the specific activity (the total $\\alpha$ activity and $^{228}$Th) was observed in a sample of ZnWO$_4$ crystal produced by recrystallization after removing $\\approx 0.4$ mm surface layer of the crystal.

  12. Improvement of radiopurity level of enriched 116CdWO4 and ZnWO4 crystal scintillators by recrystallization (United States)

    Barabash, A. S.; Belli, P.; Bernabei, R.; Borovlev, Yu. A.; Cappella, F.; Caracciolo, V.; Cerulli, R.; Danevich, F. A.; Incicchitti, A.; Kobychev, V. V.; Konovalov, S. I.; Laubenstein, M.; Mokina, V. M.; Polischuk, O. G.; Safonova, O. E.; Shlegel, V. N.; Tretyak, V. I.; Tupitsyna, I. A.; Umatov, V. I.; Zhdankov, V. N.


    As low as possible radioactive contamination of a detector plays a crucial role to improve sensitivity of a double beta decay experiment. The radioactive contamination of a sample of 116CdWO4 crystal scintillator by thorium was reduced by a factor ≈10, down to the level 0.01 mBq/kg (228Th), by exploiting the recrystallization procedure. The total alpha activity of uranium and thorium daughters was reduced by a factor ≈3, down to 1.6 mBq/kg. No change in the specific activity (the total α activity and 228Th) was observed in a sample of ZnWO4 crystal produced by recrystallization after removing ≈0.4 mm surface layer of the crystal.

  13. Electrochromic response of WO3 and WO3-TiO2 thin films prepared from water-soluble precursors and a block copolymer template

    Directory of Open Access Journals (Sweden)

    Takashi Kuroki


    Full Text Available Electrochromic tungsten trioxide (WO3 thin films are attracting renewed attention as transmittance-controllable windows for use in automobile, aircraft, and building applications. In order to achieve high electrochromic performance, high cycle stability, and high reliability, the microstructure and compositional homogeneity of WO3 thin films have to be optimized. In this study, non-doped WO3 and TiO2-doped WO3 thin films were fabricated from water-soluble precursors of tungsten and titanium, and their electrochromic response was investigated. Amorphous WO3 and TiO2-doped WO3 thin films were fabricated by calcining the spin-coated films at 573 K. The use of a PEO-PPO-PEO block copolymer as a porogen facilitated the redox reactions occurring on the thin film/electrolyte interface. Although the effect of TiO2-doping on the cycle stability of WO3 thin films has not been fully elucidated, this study demonstrated that TiO2 doping up to 15 mol% effectively enhanced the cycle stability.

  14. Temperature and acidity effects on WO{sub 3} nanostructures and gas-sensing properties of WO{sub 3} nanoplates

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Huili [School of Chemistry and Chemical Engineering, Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, Tianjin University of Technology, Tianjin 300384 (China); Liu, Zhifang; Yang, Jiaqin; Guo, Wei [Department of Materials Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), TKL of Metal and Molecule-based Material Chemistry, Synergetic Innovation Centre of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071 (China); Zhu, Lianjie, E-mail: [School of Chemistry and Chemical Engineering, Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, Tianjin University of Technology, Tianjin 300384 (China); Zheng, Wenjun, E-mail: [Department of Materials Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), TKL of Metal and Molecule-based Material Chemistry, Synergetic Innovation Centre of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071 (China)


    Graphical abstract: Generally, large acid quantity and high temperature are beneficial to the formation of anhydrous WO3, but the acidity effect on the crystal phase is weaker than that of temperature. Large acid quantity is found helpful to the oriented growth of tungsten oxides, forming a nanoplate-like product. - Highlights: • Large acid quantity is propitious to the oriented growth of a WO{sub 3} nanoplate. • Effect of acid quantity on crystal phases of products is weaker than that of temperature. • One step hydrothermal synthesis of WO{sub 3} is facile and can be easily scaled up. • A WO{sub 3} nanoplate shows a fast response and distinct sensing selectivity to acetone gas. - Abstract: WO{sub 3} nanostructures were successfully synthesized by a facile hydrothermal method using Na{sub 2}WO{sub 4}·2H{sub 2}O and HNO{sub 3} as raw materials. They are characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). The specific surface area was obtained from N{sub 2} adsorption–desorption isotherm. The effects of the amount of HNO{sub 3}, hydrothermal temperature and reaction time on the crystal phases and morphologies of the WO{sub 3} nanostructures were investigated in detail, and the reaction mechanism was discussed. Large amount of acid is found for the first time to be helpful to the oriented growth of tungsten oxides, forming nanoplate-like products, while hydrothermal temperature has more influence on the crystal phase of the product. Gas-sensing properties of the series of as-prepared WO{sub 3} nanoplates were tested by means of acetone, ethanol, formaldehyde and ammonia. One of the WO{sub 3} nanoplates with high specific surface area and high crystallinity displays high sensitivity, fast response and distinct sensing selectivity to acetone gas.

  15. Application of PbWO4 crystal scintillators in experiment to search for double beta decay of 116Cd

    CERN Document Server

    Danevich, F A; Kobychev, V V; Kropivyansky, B N; Nagorny, S S; Nikolaiko, A S; Poda, D V; Tretyak, V I; Yurchenko, S S; Grinyov, B V; Nagornaya, L L; Pirogov, E N; Ryzhikov, V D; Brudanin, V B; Fedorov, M; Korzhik, M; Lobko, A; Miussevitch, O; Solsky, I M


    PbWO4 crystal scintillators are discussed as an active shield and light-guides in 116Cd double beta decay experiment with CdWO4 scintillators. Scintillation properties and radioactive contamination of PbWO4 scintillators were investigated. Energy resolution of CdWO4 detector, coupled to PbWO4 crystal as a light-guide, was tested. Efficiency of PbWO4-based active shield to suppress background from the internal contamination of PbWO4 crystals was calculated. Using of lead tungstate crystal scintillators as high efficiency 4-pi active shield could allow to build sensitive double beta experiment with 116CdWO4 crystal scintillators.

  16. Photoreactive mesoporous carbon/Bi{sub 2}WO{sub 6} composites: Synthesis and reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Chen Suhua; Yin Zhen [Key Laboratory of Jiangxi Province for Ecological Diagnosis-Remediation and Pollution Control, Nanchang Hangkong University, Nanchang 330063 (China); Luo Shenglian, E-mail: [Key Laboratory of Jiangxi Province for Ecological Diagnosis-Remediation and Pollution Control, Nanchang Hangkong University, Nanchang 330063 (China); Li Xuejun; Yang Lixia; Deng Fang [Key Laboratory of Jiangxi Province for Ecological Diagnosis-Remediation and Pollution Control, Nanchang Hangkong University, Nanchang 330063 (China)


    Highlights: Black-Right-Pointing-Pointer We described the preparation and characterization of the mesoprous carbon/Bi{sub 2}WO{sub 6} composites. Black-Right-Pointing-Pointer The photocatalytic activities of the composites were also investigated. Black-Right-Pointing-Pointer With the combination of photocatalysts and mesoporous carbon, increased separation efficiency of photoinduced electron-hole pairs and larger specific surface areas can be achieved. Black-Right-Pointing-Pointer And to our knowledge, this is the first report concerning Bi{sub 2}WO{sub 6} nanoparticles loaded on a mesoprous carbon. - Abstract: In order to develop highly efficient visible-light induced photocatalysts, Bi{sub 2}WO{sub 6} powders and mesoporous carbon (MC)-modified Bi{sub 2}WO{sub 6} (MC/Bi{sub 2}WO{sub 6}) photocatalysts were synthesized via a simple hydrothermal process in this paper. The samples of Bi{sub 2}WO{sub 6} and MC/Bi{sub 2}WO{sub 6} were characterized by X-ray diffraction (XRD), UV-visible spectroscopy, scanning electron microscopy (SEM) and BET surface area analysis, and their photocatalytic activity were evaluated by photocatalytic decoloration of rhodamine B (RhB) aqueous solution under visible light. It was found that the presence of MC could significantly improve the crystallization of Bi{sub 2}WO{sub 6} species and photoabsorption property of Bi{sub 2}WO{sub 6} in the visible region. The results also showed that the BET surface areas of MC/Bi{sub 2}WO{sub 6} composites were larger than that of the pure Bi{sub 2}WO{sub 6} and the photocatalytic activity of the MC/Bi{sub 2}WO{sub 6} is much higher than that of Bi{sub 2}WO{sub 6} with the optimum effect occurring at R{sub MC} = 0.10 (the weight ratio of MC to Bi{sub 2}WO{sub 6}). Close investigation revealed that the surface area, grain size and charge transfer of the as-prepared MC/Bi{sub 2}WO{sub 6} composites could improve the photocatalytic activities.

  17. Multiple horizontal transfers of bacteriophage WO and host Wolbachia in fig wasps in a closed community

    Directory of Open Access Journals (Sweden)

    Ningxin eWang


    Full Text Available Wolbachia-bacteriophage WO is a good model system for studying interactions between bacteria and viruses. Previous surveys of insect hosts have been conducted via sampling from open or semi-open communities; however, no studies have reported the infection patterns of phage WO of insects living in a closed community. Figs and fig wasps form a peculiar closed community in which the Ficus tree provides a compact syconium habitat for a variety of fig wasps. Therefore, in this study, we performed a thorough survey of Wolbachia and bacteriophage WO infection patterns in a total of 1406 individuals from 23 fig wasps species living on three different fig tree species. The infection rates of Wolbachia and phage WO were 82.6% (19/23 and 39.1% (9/23, respectively. Additionally, phage WO from fig wasps showed strong insect host specificity based on orf7 sequences from fig wasps and 21 other insect species. Probably due to the physical barrier of fig syconium, most phage WO from fig wasps form a special clade. Phylogenetic analysis showed the absence of congruence between WO and host Wolbachia, WO and insect host, as well as Wolbachia and fig wasps, suggesting that both Wolbachia and phage WO exchanged frequently and independently within the closed syconium. Thus, the infection pattern of bacteriophage WO from fig wasps appeared quite different from that in other insects living outside, although the effect and the transfer routes of phage WO are unclear, which need to be investigated in the future.

  18. Detection of pump degradation

    Energy Technology Data Exchange (ETDEWEB)

    Greene, R.H.; Casada, D.A.; Ayers, C.W. [and others


    This Phase II Nuclear Plant Aging Research study examines the methods of detecting pump degradation that are currently employed in domestic and overseas nuclear facilities. This report evaluates the criteria mandated by required pump testing at U.S. nuclear power plants and compares them to those features characteristic of state-of-the-art diagnostic programs and practices currently implemented by other major industries. Since the working condition of the pump driver is crucial to pump operability, a brief review of new applications of motor diagnostics is provided that highlights recent developments in this technology. The routine collection and analysis of spectral data is superior to all other technologies in its ability to accurately detect numerous types and causes of pump degradation. Existing ASME Code testing criteria do not require the evaluation of pump vibration spectra but instead overall vibration amplitude. The mechanical information discernible from vibration amplitude analysis is limited, and several cases of pump failure were not detected in their early stages by vibration monitoring. Since spectral analysis can provide a wealth of pertinent information concerning the mechanical condition of rotating machinery, its incorporation into ASME testing criteria could merit a relaxation in the monthly-to-quarterly testing schedules that seek to verify and assure pump operability. Pump drivers are not included in the current battery of testing. Operational problems thought to be caused by pump degradation were found to be the result of motor degradation. Recent advances in nonintrusive monitoring techniques have made motor diagnostics a viable technology for assessing motor operability. Motor current/power analysis can detect rotor bar degradation and ascertain ranges of hydraulically unstable operation for a particular pump and motor set. The concept of using motor current or power fluctuations as an indicator of pump hydraulic load stability is presented.

  19. Detection of pump degradation

    Energy Technology Data Exchange (ETDEWEB)

    Casada, D. [Oak Ridge National Lab., TN (United States)


    There are a variety of stressors that can affect the operation of centrifugal pumps. Although these general stressors are active in essentially all centrifugal pumps, the stressor level and the extent of wear and degradation can vary greatly. Parameters that affect the extent of stressor activity are manifold. In order to assure the long-term operational readiness of a pump, it is important to both understand the nature and magnitude of the specific degradation mechanisms and to monitor the performance of the pump. The most commonly applied method of monitoring the condition of not only pumps, but rotating machinery in general, is vibration analysis. Periodic or continuous special vibration analysis is a cornerstone of most pump monitoring programs. In the nuclear industry, non-spectral vibration monitoring of safety-related pumps is performed in accordance with the ASME code. Pump head and flow rate are also monitored, per code requirements. Although vibration analysis has dominated the condition monitoring field for many years, there are other measures that have been historically used to help understand pump condition; advances in historically applied technologies and developing technologies offer improved monitoring capabilities. The capabilities of several technologies (including vibration analysis, dynamic pressure analysis, and motor power analysis) to detect the presence and magnitude of both stressors and resultant degradation are discussed.

  20. Optically pumped atoms

    CERN Document Server

    Happer, William; Walker, Thad


    Covering the most important knowledge on optical pumping of atoms, this ready reference is backed by numerous examples of modelling computation for optical pumped systems. The authors show for the first time that modern scientific computing software makes it practical to analyze the full, multilevel system of optically pumped atoms. To make the discussion less abstract, the authors have illustrated key points with sections of MATLAB codes. To make most effective use of contemporary mathematical software, it is especially useful to analyze optical pumping situations in the Liouville spa

  1. Champagne Heat Pump (United States)

    Jones, Jack A.


    The term champagne heat pump denotes a developmental heat pump that exploits a cycle of absorption and desorption of carbon dioxide in an alcohol or other organic liquid. Whereas most heat pumps in common use in the United States are energized by mechanical compression, the champagne heat pump is energized by heating. The concept of heat pumps based on other absorption cycles energized by heat has been understood for years, but some of these heat pumps are outlawed in many areas because of the potential hazards posed by leakage of working fluids. For example, in the case of the water/ammonia cycle, there are potential hazards of toxicity and flammability. The organic-liquid/carbon dioxide absorption/desorption cycle of the champagne heat pump is similar to the water/ammonia cycle, but carbon dioxide is nontoxic and environmentally benign, and one can choose an alcohol or other organic liquid that is also relatively nontoxic and environmentally benign. Two candidate nonalcohol organic liquids are isobutyl acetate and amyl acetate. Although alcohols and many other organic liquids are flammable, they present little or no flammability hazard in the champagne heat pump because only the nonflammable carbon dioxide component of the refrigerant mixture is circulated to the evaporator and condenser heat exchangers, which are the only components of the heat pump in direct contact with air in habitable spaces.

  2. Resonance wave pumping: wave mass transport pumping (United States)

    Carmigniani, Remi; Violeau, Damien; Gharib, Morteza


    It has been previously reported that pinching at intrinsic resonance frequencies a valveless pump (or Liebau pump) results in a strong pulsating flow. A free-surface version of the Liebau pump is presented. The experiment consists of a closed tank with a submerged plate separating the water into a free-surface and a recirculation section connected through two openings at each end of the tank. A paddle is placed at an off-centre position at the free-surface and controlled in a heaving motion with different frequencies and amplitudes. Near certain frequencies identified as resonance frequencies through a linear potential theory analysis, the system behaves like a pump. Particle Image Velocimetry (PIV) is performed in the near free surface region and compared with simulations using Volume of Fluid (VOF) method. The mean eulerian mass flux field (ρ) is extracted. It is observed that the flow is located in the vicinity of the surface layer suggesting Stokes Drift (or Wave Mass Transport) is the source of the pumping. A model is developped to extend the linear potential theory to the second order to take into account these observations. The authors would like to acknowledge the Gordon and Betty Moore Foundation for their generous support.

  3. Effect of crystallization water on the structural and electrical properties of CuWO{sub 4} under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Li; Yan, Jiejuan; Liu, Cailong; Liu, Xizhe; Han, Yonghao, E-mail:, E-mail:; Gao, Chunxiao, E-mail:, E-mail: [State Key Lab for Superhard Materials, Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012 (China); Ke, Feng; Wang, Qinglin [Center for High Pressure Science and Technology Advanced Research, Shanghai 201203 (China); Li, Yanchun [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Science, Beijing 100049 (China); Ma, Yanzhang [Center for High Pressure Science and Technology Advanced Research, Shanghai 201203 (China); Department of Mechanical Engineering, Texas Tech University, Lubbock, Texas 79409 (United States)


    The effect of crystallization water on the structural and electrical properties of CuWO{sub 4} under high pressure has been investigated by in situ X-ray diffraction and alternating current impedance spectra measurements. The crystallization water was found to be a key role in modulating the structural stability of CuWO{sub 4} at high pressures. The anhydrous CuWO{sub 4} undergoes two pressure-induced structural transitions at 8.8 and 18.5 GPa, respectively, while CuWO{sub 4}·2H{sub 2}O keeps its original structure up to 40.5 GPa. Besides, the crystallization water makes the electrical transport behavior of anhydrous CuWO{sub 4} and CuWO{sub 4}·2H{sub 2}O quite different. The charge carrier transportation is always isotropic in CuWO{sub 4}·2H{sub 2}O, but anisotropic in the triclinic and the third phase of anhydrous CuWO{sub 4}. The grain resistance of CuWO{sub 4}·2H{sub 2}O is always larger than that of anhydrous CuWO{sub 4} in the entire pressure range. By analyzing the relaxation response, we found that the large number of hydrogen bonds can soften the grain characteristic frequency of CuWO{sub 4}·2H{sub 2}O over CuWO{sub 4} by one order of magnitude.

  4. Hydrogen-treated commercial WO3 as an efficient electrocatalyst for triiodide reduction in dye-sensitized solar cells. (United States)

    Cheng, Ling; Hou, Yu; Zhang, Bo; Yang, Shuang; Guo, Jian Wei; Wu, Long; Yang, Hua Gui


    The electrocatalytically inactive commercial WO3 can be transformed into an efficient counter electrode (CE) material for dye-sensitized solar cells (DSCs) via facile hydrogen treatment. The energy conversion efficiency of the DSCs with the hydrogen-treated WO3 CE was 5.43%, while the corresponding value for commercial WO3 with the stoichiometric surface was only 0.63%.

  5. Effect of nonmagnetic substituents Mg and Zn on the phase competition in the multiferroic antiferromagnet MnWO4


    Meddar, Lynda; Josse, Michael; Deniard, Philippe; La, Carole; André, Gilles; Damay, Françoise; Petricek, Vaclav; Jobic, Stéphane; Whangbo, Myung-Hwan; Maglione, Mario; Payen, Christophe


    The effects of substituting nonmagnetic Mg2+ and Zn2+ ions for the Mn2+ (S = 5/2) ions on the structural, magnetic and dielectric properties of the multiferroic frustrated antiferromagnet MnWO4 were investigated. Polycrystalline samples of Mn1-xMgxWO4 and Mn1-xZnxWO4 (0

  6. Photocatalytic degradation of 2-propanol and phenol using Au loaded MnWO4 nanorod under visible light irradiation

    CSIR Research Space (South Africa)

    Chakraborty, AK


    Full Text Available Single crystalline MnWO4 nanorod has been prepared by low temperature hydrothermal reaction at 180 °C. The prepared MnWO4 possesses band gap of 2.63 eV. Photochemical decomposition method has been followed to disperse Au nanoparticles onto MnWO4...

  7. Visible-light photocatalytic activity of graphene oxide-wrapped Bi{sub 2}WO{sub 6} hierarchical microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Zhai, Jiali; Yu, Hongwen, E-mail:; Li, Haiyan; Sun, Lei; Zhang, Kexin; Yang, Hongjun


    Graphical abstract: - Highlights: • GO/Bi{sub 2}WO{sub 6} are readily fabricated by facile bubbling pretreatment and freeze drying. • GO/Bi{sub 2}WO{sub 6} possess excellent photocatalytic activity under visible light irradiation. • The visible light activity of GO/Bi{sub 2}WO{sub 6} is affected by the amount of GO. • The photostablity of GO is due to the photo-generated electrons transfer to Bi{sub 2}WO{sub 6}. - Abstract: A facile approach of fabricating homogeneous graphene oxide (GO)-wrapped Bi{sub 2}WO{sub 6} microspheres (GO/Bi{sub 2}WO{sub 6}) is developed. The transmission electron microscopy (TEM) results show that a heterojunction interface between GO and Bi{sub 2}WO{sub 6}. The UV–vis diffuse reflection spectra (DRS) reveal that the as-prepared GO/Bi{sub 2}WO{sub 6} composites own more intensive absorption in the visible light range compared with pure Bi{sub 2}WO{sub 6}. These characteristic structural and optical properties endow GO/Bi{sub 2}WO{sub 6} composites with enhanced photocatalytic activity. The enhanced photocatalytic activity of the GO/Bi{sub 2}WO{sub 6} is attributed predominantly to the synergetic effect between GO and Bi{sub 2}WO{sub 6}, causing rapid generation and separation of photo-generated charge carriers.

  8. Optical spectroscopy of rare-earth ions doped KY(WO4)2 thin films

    NARCIS (Netherlands)

    García-Revilla, S.; Valiente, R.; Romanyuk, Y.E.; Utke, I.; Pollnau, Markus


    KY(WO4)2 thin films doped with Dy3+, Tb3+, Yb3+, were grown onto KY(WO4)2 substrates using liquid-phase epitaxy. Spectroscopic investigations of the grown layers were performed. Obtained results were compared with spectra given for bulk crystals. Upconversion experiments after direct Yb3+ excitation

  9. Charge carriers and dc polarization phenomena in solid Na2WO4

    NARCIS (Netherlands)

    Bottelberghs, P.H.; Everts, E.


    Ionic transport measurements based on the Tubandt method have been performed in all three solid phases of Na2WO4 at temperatures between 550 and 600°C in air. It is shown that tNa+ = 1.00 in all cases. Ag is oxidized anodically to Ag+ at Ag/Na2WO4 interfaces. Cathodically only (air) oxygen reduction

  10. Oxidative degradation of salicylic acid by sprayed WO{sub 3} photocatalyst

    Energy Technology Data Exchange (ETDEWEB)

    Mohite, S.V.; Rajpure, K.Y., E-mail:


    Highlights: • The photoactivity of sprayed WO{sub 3} thin film. • Photoelectrocatalytic degradation of salicylic acid. • Reaction kinetics and mineralization of pollutants by COD. - Abstract: The WO{sub 3} thin films were deposited using spray pyrolysis technique. The prepared WO{sub 3} thin films were characterized using photoelectrochemical (PEC), X-ray diffraction, atomic force microscopy (AFM), and UV–vis absorbance spectroscopy techniques. PEC measurements of WO{sub 3} films deposited at different deposition temperatures were carried out to study photoresponse. The maximum photocurrent (I{sub ph} = 261 μA/cm{sup 2}) was observed for the film deposited at the 225 °C. The monoclinic crystal structure of WO{sub 3} has been confirmed from X-ray diffraction studies. AFM studies were used to calculate particle size and average roughness of the films. Optical absorbance was studied to estimate the bandgap energy of WO{sub 3} thin film which was about 2.65 eV. The photoelectrocatalytic activity of WO{sub 3} film was studied by degradation of salicylic acid with reducing concentrations as function of reaction time. The WO{sub 3} photocatalyst degraded salicylic acid to about 67.14% with significant reduction in chemical oxygen demand (COD) value.

  11. Influence of disordered morphology on electrochromic stability of WO{sub 3}/PPy

    Energy Technology Data Exchange (ETDEWEB)

    Gaikwad, Digambar K. [D. Y. Patil College of Engineering & Technology, Kasaba Bawada, Kolhapur, 416006, Maharashtra (India); Mali, Sawanta S.; Hong, Chang K. [Polymer Energy Materials Laboratory, Department of Advanced Chemical Engineering, Chonnam National University, Gwangju, 500-757 (Korea, Republic of); Kadam, Anamika V., E-mail: [D. Y. Patil College of Engineering & Technology, Kasaba Bawada, Kolhapur, 416006, Maharashtra (India); D.Y. Patil Medical University, Kasaba Bawada, Kolhapur, 416006, Maharashtra (India)


    Tungsten oxide (WO{sub 3}) films are critical for smart windows because of their capacity of varying the throughput of visible light and solar energy. This study highlights the evolution of structural and morphological changes of electrodeposited WO{sub 3} thin films coated with polypyrrole (PPy) by using chemical bath deposition. The structural and surface properties of WO{sub 3} thin films were studied using X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. The electrochemical stability was inspected using repetitive cyclic voltammetry (CV) cycles for each sample in LiClO{sub 4}-PC electrolyte for prolonged periods. The results showed an improvement in the electrochemical stability after the CV study. - Graphical abstract: Mechanism: A schematic of the mechanism is proposed in above fig. The mechanism is based on three step process: (i) WO{sub 3} coated on ITO by electrodeposition followed by thermal treatment. It produces ordered nanoarrayed morphology. (ii) A second step involving deposition of PPy by chemical bath deposition on ITO. It possesses globular morphology. (iii) When PPy coated on WO{sub 3}, PPy applies shearing force on WO{sub 3} and produces disordered nanoarrayed morphology. - Highlights: • Nanoarrayed WO{sub 3}/PPy composite was synthesized. • Interplanar spacing enhances due to PPy coating. • PPy applies shearing force on WO{sub 3} produces disordered morphology. • Nanocomposite showed high stability in LiClO{sub 4}-PC.

  12. Photodegradation of Malachite Green by Nanostructured Bi2WO6 Visible Light-Induced Photocatalyst

    Directory of Open Access Journals (Sweden)

    Yijie Chen


    Full Text Available Bi2WO6 photocatalyst was first utilized to degrade malachite green. The effects of the concentration of malachite green, the pH value, and the concentration of Bi2WO6 on the photocatalytic efficiency were investigated. This study presents a strategy to eliminate highly toxic and persistent dyes such as malachite green.

  13. Enhanced visible light photocatalytic activity of Bi2WO6 via modification with polypyrrole (United States)

    Duan, Fang; Zhang, Qianhong; Shi, Dongjian; Chen, Mingqing


    Enhanced visible light photocatalytic activity of Bi2WO6 photocatalyst modified with different amounts of polypyrrole (PPy) was synthesized by 'in situ' deposition oxidative polymerization of pyrrole. The as-prepared PPy/Bi2WO6 composites were characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FT-IR) spectra, X-ray photoelectron spectroscopy (XPS) and UV-vis diffuse absorption spectra. The photocatalytic activities of the PPy/Bi2WO6 samples were determined by photocatalytic degradation of rhodamine-B (RhB) and methylene blue (MB) in aqueous solution under visible light irradiation. The results indicated that the existence of PPy did not affect the crystal structure and the morphology of Bi2WO6 photocatalyst, but showed great influences on the photocatalytic activity of Bi2WO6. Besides, an optimal content of PPy on the surface of Bi2WO6 photocatalyst with the highest photocatalytic ability was discovered, and the obtained PPy/Bi2WO6 photocatalysts showed high stability and did not photocorrode during the photocatalytic process. The possible mechanism of enhanced photocatalytic activities of PPy/Bi2WO6 samples was also discussed in this work.

  14. Selective hydrothermal method to create patterned and photoelectrochemically effective Pt/WO3 Interfaces

    NARCIS (Netherlands)

    Zoontjes, Michel G.C.; Huijben, Mark; Baltrusaitis, Jonas; Wiel, van der Wilfred G.; Mul, Guido


    A hydrothermal method based on the use of hydrogen peroxide is described to grow a homogeneous layer of tungsten oxide (WO3) on a platinum (Pt) film supported on a silicon wafer. WO3 growth is highly selective for Pt when present on silicon in a patterned arrangement, demonstrating that Pt catalyzes

  15. A simple synthesis of MnWO{sub 4} nanoparticles as a novel energy storage material

    Energy Technology Data Exchange (ETDEWEB)

    Li, Feihui, E-mail: [Department of Applied Chemistry, School of Science, Tianjin University of Commerce, Tianjin 300134 (China); Xu, Xiaoyang, E-mail: [School of Science, Tianjin University (China); Huo, Jialei; Wang, Wei [School of Chemical Engineering, Tianjin 300072 (China)


    MnWO{sub 4} nanoparticles with the shuttle-like shape were prepared by a simple chemical co-precipitation method and analyzed by X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. The prepared MnWO{sub 4} was used as the electrode material of a supercapacitor, and its electrochemical performance was studied using cyclic voltammetry, galvanostatic charge/discharge cycles and electrochemical impedance spectroscopy. The MnWO{sub 4} exhibited good electrochemical performance. The MnWO{sub 4} nanoparticles had specific capacitances of 295 F/g at a scan rate of 5 mV/s and 219 F/g at a current density of 0.4 A/g. They also showed good cycle-life stability and low resistance. Therefore, MnWO{sub 4} is a promising electrode material for supercapacitors. - Highlights: • The shuttle-like MnWO{sub 4} nanoparticles have been prepared. • The prepared MnWO{sub 4} nanoparticles exhibit good electrochemical performances. • MnWO{sub 4} is a promising electrode material for supercapacitors.

  16. MnWO{sub 4} nanocapsules: Synthesis, characterization and its electrochemical sensing property

    Energy Technology Data Exchange (ETDEWEB)

    Muthamizh, Selvamani; Suresh, Ranganathan; Giribabu, Krishnamoorthy; Manigandan, Ramadoss; Praveen Kumar, Sivakumar; Munusamy, Settu; Narayanan, Vengidusamy, E-mail:


    Highlights: • Synthesis of MnWO{sub 4} nanocapsules without use of any other external reagent. • High crystalline MnWO{sub 4} was obtained with phase purity. • Electrochemical sensing platform based on MnWO{sub 4} for sensing quercetin. • Micromolar detection ability of MnWO{sub 4} modified GCE. - Abstract: Manganese tungstate (MnWO{sub 4}) was synthesized by surfactant free precipitation method. MnWO{sub 4} was characterized by using various spectroscopic techniques. The phase, crystalline nature and the morphological analysis were carried out using XRD, scanning electron microscopy (SEM), and high resolution transmission electron microscopy (HR-TEM). Further, FT-IR, Raman, and DRS-UV–Vis spectral analysis were carried out in order to ascertain the optical property and the presence of functional groups. From the analysis, the morphology of the MnWO{sub 4} was observed to be in capsules with breadth and thickness were in nm range. The oxidation state of tungsten (W), and manganese (Mn) were investigated using X-ray photo electron spectroscopy (XPS) and electron paramagnetic resonance spectroscopy (EPR). The synthesized MnWO{sub 4} nanocapsules were used to modify glassy carbon electrode (GCE) to detect quercetin.

  17. Conductivity-Type Sensor Based on CNT-WO3 Composite for NO2Detection

    Directory of Open Access Journals (Sweden)

    Takeshi Hashishin


    Full Text Available The CNTs with 20–50 nm in diameter were directly grown on Au microgap electrode by means of thermal CVD at 700∘C for 60 minutes under EtOH-Ar-H2 atmosphere (6 kPa. The CNTs with entangled shape formed the network structure with contacting each other. In the CNTs-WO3 composite, WO3 grains with disk shape (50–200 nm were independently trapped. The CNTs-WO3 composite sensor showed the fairly good sensor response (Ra/Rg = 3.8 at 200∘C. The sensor response was greatly improved with CNTs-WO3 composite, comparing with that of CNT sensor (Ra/Rg = 1.05. This phenomenon can be explained by formation of p-n junction, between CNT(p and WO3(n, and thus improvement of NO2 adsorption. The sensor response was decreased with increasing the WO3 amount in CNTs-WO3 composite, suggesting the electronic conduction due to WO3 connection.

  18. Detecting hydrogen using graphene quantum dots/WO3 thin films (United States)

    Fardindoost, Somayeh; Iraji zad, Azam; Sadat Hosseini, Zahra; Hatamie, Shadie


    In the present work we report an approach to resistive hydrogen sensing based on graphene quantum dots (GQDs)/WO3 thin films that work reproducibly at low temperatures. GQDs were chemically synthesized and evenly dispersed in WO3 solution with 1:1 molar ratio. The structural evaluation and crystallization of the prepared films was studied by x-ray diffraction, Raman and scanning electron microscopy (SEM) techniques. The SEM images showed uniform distribution of the GQDs in WO3 films with sizes around 50 nm. Raman experiment showed the GQDs are partially reduced with high edge defects as hydroxyl and carboxyl groups which involve both in bridging between WO3 grains via bindings as well as interacting with target gas molecules. GQDs can develop an electron conductive network and shorten the current transport paths inside the sensitive films. As a result, they improved the poor electrical properties and charge transfer of pure WO3. Resistive hydrogen sensing showed significant decrease in the working temperature for GQDs/WO3 films compared to pure WO3 films. The working temperature of about 150 °C with 15 and 40 s response and recovery times are significant characteristics of the introduced sensing structure. Then palladium (Pd) was added as a catalyst in GQDs/WO3 film to make the sensing materials selective to hydrogen. Pd doped film worked at temperature of 120 °C with high selectivity and improved response magnitude to hydrogen gas.

  19. Optical spectroscopy of rare-earth ions doped KY(WO4)2 thin films

    NARCIS (Netherlands)

    García-Revilla, S.; Valiente, R.; Romanyuk, Y.E.; Utke, I.; Pollnau, M.


    KY(WO4)2 thin films doped with Dy3+, Tb3+, Yb3+, were grown onto KY(WO4)2 substrates using liquid-phase epitaxy. Spectroscopic investigations of the grown layers were performed. Obtained results were compared with spectra given for bulk crystals. Upconversion experiments after direct Yb3+ excitation

  20. Demanding pump power; Krevende pumpekraft

    Energy Technology Data Exchange (ETDEWEB)

    Lie, Oeyvind


    The potential for pump power in Norway is huge, but it is difficult to exploit it. Norway has some pumping plants, but these are built for seasonal pumping (pumping up to the magazine in the summer, and production in the winter). Pump power plants for short periods do not exist in Norway. (AG)

  1. Pump element for a tube pump

    DEFF Research Database (Denmark)


    relative to the rod element so as to allow for a fluid flow in the tube through the first valve member, along the rod element, and through the second valve member. The tube comprises an at least partly flexible tube portion between the valve members such that a repeated deformation of the flexible tube...... portion acts to alternately close and open the valve members thereby generating a fluid flow through the tube. The invention further relates to a pump element comprising at least two non-return valve members connected by a rod element, and for insertion in an at least partly flexible tube in such tube...... pump as mentioned above, thereby acting to generate a fluid flow through the tube upon repeated deformation of the tube between the two valve members. The pump element may comprise a connecting part for coupling to another tube and may comprise a sealing part establishing a fluid tight connection...

  2. Sensing of subsurface faults based on an imaging technique for teleseismic waveform data. 2. Feasibility study for application to oblique incidence, multi-event and noise data; Enchi jishin hakei data wo mochiita chika kozo imaging ni yoru chichu danso kenshutsu no kokoromi. 2. Naname nyusha, multi event, noise wo fukumu hakei eno tekiyo

    Energy Technology Data Exchange (ETDEWEB)

    Murakoshi, T.; Takenaka, H.; Saita, T. [Kyushu University, Fukuoka (Japan). Faculty of Science; Suetsugu, D. [Building Research Institute, Tokyo (Japan); Furumura, T. [Hokkaido University of Education, Sapporo (Japan)


    An examination was made on the method in which imaging of subsurface was carried out with teleseismic waveform data for sensing of faults. In the examination, an experiment was done on the sensing of faults with higher precision, by applying oblique incidence as well as perpendicular upward incidence of SH plane waves, and thereby stacking the imaging in plural events. In numerical experiments, 28 observation points were arranged at 500m spaces apart on the surface, and the incident waves were made the SH plane waves having a bell-shaped time function, with incidence made at an angle varied as 0{degree}, +15{degree} and -15{degree} from the lowest layer of a model. In the calculation of the wave motion field, a difference calculus with secondary accuracy was used for both time and space. In addition, data was prepared with a random noise added to a synthesized waveform to be used as observation data. The calculated waveform data were likened to the observation waveform, to which the method for imaging faults was applied. Consequently, it was noted that satisfactory results were obtained compared with the case where faults were sensed by one event alone. 5 refs., 4 figs.

  3. Strain Accommodation By Facile WO6 Octahedral Distortion and Tilting During WO3 Heteroepitaxy on SrTiO3(001)

    Energy Technology Data Exchange (ETDEWEB)

    Du, Yingge; Gu, Meng; Varga, Tamas; Wang, Chong M.; Bowden, Mark E.; Chambers, Scott A.


    In this paper, we show that compared to other BO6 octahedra in ABO3 structured perovskite oxides, the WO6 octahedra in tungsten trioxide (WO3) can withstand a much larger degree of distortion and tilting to accommodate interfacial strain, which in turn strongly impact the nucleation, structure, and defect formation during the epitaxial growth of WO3 on SrTiO3(001). A meta-stable tetragonal phase can be stabilized by epitaxy and a thickness dependent phase transition (tetragonal to monoclinic) is observed. In contrast to misfit dislocations to accommodate the interfacial stain, the facial WO6 octahedral distortion and tilting give rise to three types of planar defects that affect more than 15 monolayers from the interface. These atomically resolved, unusual interfacial defects may significantly alter the electronic, electrochromic, and mechanical properties of the epitaxial films.

  4. Characterization of MAPLE deposited WO3 thin films for electrochromic applications (United States)

    Boyadjiev, S. I.; Stefan, N.; Szilágyi, I. M.; Mihailescu, N.; Visan, A.; Mihailescu, I. N.; Stan, G. E.; Besleaga, C.; Iliev, M. T.; Gesheva, K. A.


    Tungsten trioxide (WO3) is a widely studied material for electrochromic applications. The structure, morphology and optical properties of WO3 thin films, grown by matrix assisted pulsed laser evaporation (MAPLE) from monoclinic WO3 nano-sized particles, were investigated for their possible application as electrochromic layers. A KrF* excimer (λ=248 nm, ζFWHM=25 ns) laser source was used in all experiments. The MAPLE deposited WO3 thin films were studied by atomic force microscopy (AFM), grazing incidence X-ray diffraction (GIXRD) and Fourier transform infrared spectroscopy (FTIR). Cyclic voltammetry measurements were also performed, and the coloring and bleaching were observed. The morpho-structural investigations disclosed the synthesis of single-phase monoclinic WO3 films consisting of crystalline nano-grains embedded in an amorphous matrix. All thin films showed good electrochromic properties, thus validating application of the MAPLE deposition technique for the further development of electrochromic devices.

  5. WO3-reduced graphene oxide composites with enhanced charge transfer for photoelectrochemical conversion. (United States)

    Wu, Haoyu; Xu, Ming; Da, Peimei; Li, Wenjie; Jia, Dingsi; Zheng, Gengfeng


    Hybrid structures between semiconducting metal oxides and carbon with rational synthesis represent unique device building blocks to optimize the light absorption and charge transfer process for the photoelectrochemical conversion. Here we demonstrate the realization of a WO3-reduced graphene oxide (RGO) nanocomposite via hydrothermal growth of ultrathin WO3 nanoplates directly on fluorine-doped tin oxide (FTO) substrates, followed by in situ photo-reduction to deposit RGO layers on WO3 nanoplate surface. Photoanodes made of the WO3-RGO nanocomposites have achieved a photocurrent density of 2.0 mA cm(-2) at 1.23 V vs. reversible hydrogen electrode (RHE), which is among the highest reported values for photoanodes based on hydrothermally grown WO3. Electrochemical impedance spectroscopy reveals that the increase of photoactivity is attributed to the enhanced charge transfer by the incorporation of RGO, thus suggesting a general approach for designing other metal oxide-RGO hybrid architectures.

  6. Optical Properties of LiIn(1−Tm(WO42 Blue Phosphor

    Directory of Open Access Journals (Sweden)

    Mourad Derbal


    Full Text Available LiIn1−Tm(WO42 (=0, 0.5, 1, 5, and 10 at.% polycrystalline powders blue phosphors were prepared via the classical solid-state reaction method. X-ray diffraction (XRD, scanning electron microscope (SEM, photoluminescence excitation, and emission spectra were used to characterize LiIn1−Tm(WO42 phosphors. By analyzing the excitation and emission spectra of LiIn1−Tm(WO42 samples, the result indicates that there exists the energy transfer only from the WO42− group to the 1G4 energy level of Tm3+ ion. On the other hand, the influence of the thulium concentration on the blue emission transition 1D2→3F4 and 1G4→3H6 and the emission of WO42− group are investigated.

  7. Hydrothermal Synthesis of WO3 Nanowires in the Presence of Guanidine Sulfate and Its Photocatalytic Activity

    Institute of Scientific and Technical Information of China (English)

    MU Wanjun; YU Qianhong; LI Xingliang; WEI Hongyuan; JIAN Yuan


    WO3 nanowires were fabricated by a hydrothermal method, which proceeded at 170℃ for 48 h in a solution containing C2H10N6H2SO4 as a dispersant and Na2WO4 as a starting material. The nanowires exhibit a well crystallized one-dimensional structure with 20 nm in diameter and several microns in length. The physicochemical properties of WO3 were compared using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and UV-vis spectroscopy (UV-Vis). The photoactivity of the as-perpared WO3 nanowires was evaluated through the photodegradation of methylene blue (MB) in aqueous solution. The experimental results demonstrate that addition of C2H10N6H2SO4 salt in the WO3 nanowires synthesis process can enhance its photocatalytic activity obviously.

  8. A Shocking New Pump (United States)


    Hydro Dynamics, Inc. received a technical helping hand from NASA that made their Hydrosonic Pump (HPump) a reality. Marshall engineers resolved a bearing problem in the rotor of the pump and recommended new bearings, housings and mounting hardware as a solution. The resulting HPump is able to heat liquids with greater energy efficiency using shock waves to generate heat.

  9. Water Treatment Technology - Pumps. (United States)

    Ross-Harrington, Melinda; Kincaid, G. David

    One of twelve water treatment technology units, this student manual on pumps provides instructional materials for three competencies. (The twelve units are designed for a continuing education training course for public water supply operators.) The competencies focus on the following areas: types of pumps in plant and distribution systems, pump…

  10. MWCNT/WO{sub 3} nanocomposite photoanode for visible light induced water splitting

    Energy Technology Data Exchange (ETDEWEB)

    Yousefzadeh, Samira [Physics Department, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of); Reyhani, Ali [Physics Department, Faculty of Science, Imam Khomeini International University, P.O. Box 34149-16818, Qazvin (Iran, Islamic Republic of); Naseri, Naimeh [Physics Department, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of); Moshfegh, Alireza Z., E-mail: [Physics Department, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of); Institute for Nanoscience and Nanotechnology, Sharif University of Technology, P.O. Box 14588-89694, Tehran (Iran, Islamic Republic of)


    The Multi-walled carbon nanotube (MWCNT)/WO{sub 3} nanocomposite thin films with different MWCNT’s weight percentages were prepared by sol–gel method as visible light induced photoanode in water splitting reaction. Weight percentage of MWCNT in the all nanocomposite thin films was confirmed by TGA/DSC analysis. According to XPS analysis, oxygenated groups at the surface of the MWCNT and stoichiometric formation of WO{sub 3} thin films were determined, while the crystalline structure of the nanocomposite samples was studied by XRD indicating (0 0 2) peak of MWCNT in the monoclinic phase of WO{sub 3}. The influence of different weight percentage (wt%) of MWCNT on WO{sub 3} photoactivity showed that the electron conductivity, charge transfer and electron life time had improved as compared with the pure WO{sub 3}. Based on linear sweep voltammetry and chronoamperometry measurements, the (1 wt%) MWCNT/WO{sub 3} nanocomposite thin films photoanode has a maximum photocurrent density of ∼4.5 A/m{sup 2} and electron life time of about 57 s. - Graphical abstract: Photocurrent density versus time at constant potential (0.7 V) for the WO{sub 3} films containing different MWCNT weight percentages annealed at 400 °C under 1000 Wm{sup −2} visible photo-illumination. Display Omitted - Highlights: • MWCNT/ WO{sub 3} nanocomposite thin films were synthesized using sol–gel derived method. • TGA/DSC confirmed the weight percentage of MWCNT in the all nanocomposite thin films. • XPS analysis revealed that WO{sub 3} was attached on the oxygenated group of MWCNT surface. • The Highest Photoelectrochemical activity is achieved for (1 wt%)MWCNT/WO{sub 3} thin film.

  11. Charged particle response of PbWO sub 4

    CERN Document Server

    Hoek, M; Hejny, V; Löhner, H; Metag, V; Novotny, R; Wörtche, H J


    The response of PbWO sub 4 to high-energy protons has been investigated in two test experiments at the proton facilities COSY and AGOR. The determined energy resolution below 360 MeV of sigma/E=1.44%/E subgamma sup 1 sup / sup 2 +1.97% is comparable to the known photon response. Measured spectra of inelastically scattered protons below 85 MeV are even compared to similar distributions obtained for BaF sub 2 - and CeF sub 3 -detectors.

  12. Photoinduced (WO4)3--La3+ center in PbWO4: Electron spin resonance and thermally stimulated luminescence study (United States)

    Laguta, V. V.; Martini, M.; Meinardi, F.; Vedda, A.; Hofstaetter, A.; Meyer, B. K.; Nikl, M.; Mihóková, E.; Rosa, J.; Usuki, Y.


    The localization of electrons at W6+ sites perturbed by lanthanum in PbWO4 is studied by electron spin resonance (ESR) and thermally stimulated luminescence (TSL) measurements. The (WO4)3--La3+ centers are created at the W6+ sites close to La3+ in two different ways: (i) direct trapping of electrons from the conduction band under ultraviolet or x-ray irradiation at T=60 K (ii) retrapping of electrons freed from unperturbed (WO4)3- centers after irradiation at Teffect, which gives rise to a rhombic distortion of (WO4)3- complex. At T~95-98 K the (WO4)3--La3+ centers are thermally ionized giving rise to a TSL glow peak due to the recombination of detrapped electrons with localized holes. The emission spectrum of the TSL features one band peaking at 2.8 eV. The temperature dependence of both TSL and ESR intensity is analyzed in the frame of a general order recombination model. The thermal ionization energy of (WO4)3--La3+ centers has been calculated to be approximately 0.27 eV.

  13. Review of magnetohydrodynamic pump applications

    National Research Council Canada - National Science Library

    Al-Habahbeh, O.M; Al-Saqqa, M; Safi, M; Abo Khater, T


    Magneto-hydrodynamic (MHD) principle is an important interdisciplinary field. One of the most important applications of this effect is pumping of materials that are hard to pump using conventional pumps...

  14. Hydrothermal synthesis of FeWO{sub 4}-graphene composites and their photocatalytic activities under visible light

    Energy Technology Data Exchange (ETDEWEB)

    He, Gang-Ling; Chen, Ming-Jie; Liu, You-Qin; Li, Xin; Liu, Ying-Ju; Xu, Yue-Hua, E-mail:


    Graphical abstract: - Highlights: • FeWO{sub 4}-RGO composites were hydrothermally fabricated by facile one-step method. • FeWO{sub 4}-RGO and FeWO{sub 4} had a similar particle size, in the range of 30–50 nm. • High efficiency for photocatalytic degradation of RhB was exhibited by FeWO{sub 4}-RGO. • FeWO{sub 4}-xRGO showed higher photocatalytic activities than pure FeWO{sub 4}. • The electron–hole pairs can be effectively separated due to RGO coupling. - Abstract: Monoclinic ferberite FeWO{sub 4}-reduced graphene oxide (FeWO{sub 4}-RGO) composites were hydrothermally fabricated by facile one-pot method in situ reduction of graphene oxide. As-prepared FeWO{sub 4}-RGO photocatalysts were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectra, and diffuse reflectance spectra (DRS). The FeWO{sub 4}-RGO photocatalysts and pure FeWO{sub 4} photocatalyst had a similar particle size, which was in the range of 30–50 nm. FeWO{sub 4} and FeWO{sub 4}-RGO photocatalysts showed absorption in the visible region, and the band gap energy of FeWO{sub 4} decreased slightly after RGO coupling. FeWO{sub 4}-RGO photocatalysts exhibited high efficiencies in photocatalytic degradation of dye pollutant Rhodamine B (RhB) in solution under visible light irradiation (a 4 W Light Emitting Diode lamp). All FeWO{sub 4}-RGO photocatalysts under visible light showed higher photocatalytic activities than pure FeWO{sub 4} photocatalyst, and FeWO{sub 4}-0.3RGO showed the best photocatalytic activity. The FeWO{sub 4}-RGO composites were formed through the chemical contact between nanometer FeWO{sub 4} particles and RGO, and RGO could act as a good electron acceptor. The enhancement in visible-light photocatalytic performance may be mainly attributed to the effective separation of the photogenerated electron–hole pairs.

  15. Pumping machinery theory and practice

    CERN Document Server

    Badr, Hassan M


    Pumping Machinery Theory and Practice comprehensively covers the theoretical foundation and applications of pumping machinery. Key features: Covers characteristics of centrifugal pumps, axial flow pumps and displacement pumpsConsiders pumping machinery performance and operational-type problemsCovers advanced topics in pumping machinery including multiphase flow principles, and two and three-phase flow pumping systemsCovers different methods of flow rate control and relevance to machine efficiency and energy consumptionCovers different methods of flow rate control and relevance to machine effi

  16. Hydrothermal synthesis and studies on photochromic properties of Al doped WO{sub 3} powder

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Yi, E-mail:; Yan, Peng; Yang, Yali; Hu, Fengping; Xiao, Yilin; Pan, Li; Li, Zhen


    Graphical abstract: Pure and aluminum (Al) doped WO{sub 3} were synthesized via a facile hydrothermal process. The XPS peaks indicated that the powders contained W, Al, O, means the Al ions as the dopant were successfully incorporated into the crystal lattice of WO{sub 3} even though it had a great different valence state with W{sup 6+}. Compared with pure WO{sub 3}, the binding energies of W4f of Al-doped WO{sub 3} was much lower, suggesting the presence of W{sup 5+} species, which induced a transition band to decrease the band gap of WO{sub 3}. Urchin-like morphology WO{sub 3} had a special microstructure and large specific surface area of the powder. The result that Al-doped WO{sub 3} exhibited superior photochromic performance might own to the narrower band gap of WO{sub 3} and urchin-like morphology. - Highlights: • All of the WO{sub 3} powder were synthesized by a facile hydrothermal deposition process. • Al ions as the dopant were successfully incorporated into the crystal lattice of WO{sub 3}. • The Al doping made the powder had an outstanding photochromic properties. • The mechanism for the improved photochromic performances of the powder was proposed. - Abstract: A series of pure and aluminum (Al) doped WO{sub 3} powders were synthesized at low temperature. The as synthesized materials have been characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet–visible (UV–VIS) spectroscopy and color difference meter, respectively. A relation was found between the color difference and the UV–VIS photochromic activity. Moreover, the optical band gap of the as-prepared powder narrowed due to the appearance of impurity levels as the Al{sup 3+} ions migrated into the WO{sub 3} crystal lattice. Some rod-like particles have been found to decrease with the increase of Al concentration. An optimum Al concentration was found to be 0.25% to present the best UV-light induced photochromic activity. The mechanism of

  17. Subsolidus Phase Relations of the CaO-WO3-CuO System at 800 °C in Air

    DEFF Research Database (Denmark)

    Grivel, J. -C.


    The subsolidus phase relations of the CaO-WO3-CuO system were investigated in air. The samples were equilibrated at 800 degrees C. Under these conditions, five binary oxide phases are stable: Ca2CuO3, Cu3WO6, CuWO4, CaWO4 and Ca3WO6. The pseudo-ternary section is characterised by 6 three-phase re......The subsolidus phase relations of the CaO-WO3-CuO system were investigated in air. The samples were equilibrated at 800 degrees C. Under these conditions, five binary oxide phases are stable: Ca2CuO3, Cu3WO6, CuWO4, CaWO4 and Ca3WO6. The pseudo-ternary section is characterised by 6 three...

  18. Electrochromic Characterization of Electrodeposited WO3 Thin Films (United States)

    Vijayalakshmi, R.; Jayachandran, M.; Sanjeeviraja, C.


    The electrochromic properties of certain transition metal oxides have been studied for several years resulting in commercial films are deposited as thin layers (0.1 to 0.4 microns) onto a transparent conductive automotive mirror and sun-glass products. The largest potential application of electrochromics is in window to regulate heat and light flow. Fabrication cost is one of the greatest barriers for large area development of the smart windows. Tungsten trioxide (WO3) can be colored deeply in with an optical irradiation of appropriate energy (photochromism) or with an applied electric field (electrochromism). These processes have received considerable attention because of their potential application in electrochromic windows, display devices, sensors, and so on. For these purposes, tungsten trioxide films prepared by various physical methods such as molecular beam epitaxy, CVD, etc have been reported. These methods are generally expensive and it is difficult to form large area films. However electrodeposition method is probably most economical method for making the films in addition to its relative ease in forming in large area films. In this paper, tungsten trioxide (WO3) films are prepared through the electrodeposition route and these films are used to study the electrochromic behavior in the various electrolytes by changing the concentrations. When coloration, the film attains deep blue color and in reduced state it becomes colorless. After the ion intercalation, the optical properties are also studied in the UV-Vis-NIR region.

  19. The growth of Nd:CaWO4 single crystals

    Directory of Open Access Journals (Sweden)



    Full Text Available CaWO4 doped with 0.8 % at. Nd (Nd:CaWO4 single crystals were grown from the melt in air by the Czochralski technique. The critical diameter dc = 1.0 cm and the critical rate of rotation wc = 30 rpm were calculated from hydrodynamic equations for buoyancy-driven and forced convection. The rate of crystal growth was experimentally obtained to be 6.7 mm/h. For chemical polishing, a solution of 1 part saturated chromic acid (CrO3 in water and 3 parts conc. H3PO4 (85 % at 433 K with an exposure time of 2 h was found to be adequate. A mixture of 1 part concentrated HF and 2 parts chromic acid at room temperature after exposure for 30 min was found to be a suitable etching solution. The lattice parameters a = 0.52404 (6 nm, c = 1.1362 (6 nm and V0 = 0.312 (2 nm3 were determined by X-ray powder diffraction. The obtained results are discussed and compared with published data.

  20. Preparation, structures and photoluminescent enhancement of CdWO 4-TiO 2 composite nanofilms (United States)

    Jia, Runping; Zhang, Guoxin; Wu, Qingsheng; Ding, Yaping


    For the first time, Cadmium tungstate (CdWO4)-TiO2 composite nanofilms on a glass substrate were prepared by means of the dip-coating technique, in which collodion was used as a dispersant and film-forming agent. The films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermo gravimetric and thermal analyses (TG/DTA), FTIR and photoluminescence (PL) methods, respectively. SEM and XRD characterization of these films indicated that CdWO4 particles crystallized in a monoclinic wolframite-type structure whereas TiO2 particles were Anatase phase; and both of them were well distributed in the nanofilms. FTIR spectra proved the presence of CdWO4 on the nanofilms. Photoluminescent results showed that the emitting peak of CdWO4 films blue shifted slightly relative to that of CdWO4 crystal. Moreover, the PL intensity of CdWO4-TiO2 composite nanofilm was much higher than that of CdWO4 nanofilm. We ascribed that the introduction of TiO2 should be responsible for the PL enhancement.

  1. High-Tc superconductivity in nanostructured NaxWO3-y: Sol-gel route (United States)

    Aliev, Ali


    Tungsten trioxide, WO3-y infiltrated into various nanoporous matrix structures such as carbon inverse opal, carbon nanotubes paper, or platinum sponge and then intercalated with alkaline ions (Li^+, Na^+) exhibits a pronounced diamagnetic onset in ZFC magnetization in a wide range of temperatures, 125-132 K. Resistivity measurements show non zero jump and intensive fluctuations of electrical resistance below observed transition points. The observed magnetic and electrical anomalies in nanostructured tungsten bronzes (LixWO3-y, NaxWO3-y) suggest the possibility of localized non-percolated superconductivity. The direct evidence of polaron formation from temperature dependence of EPR and photoemission spectra and formation of bipolarons in weakly reduced to WO3-y, with 3-y typically in the order of 2.95 suggest bipolarons mechanism of a Bose-Einstein condensation of trapped electron pairs in doped WO3-y. On the other hand the strong lattice instabilities in 2D systems like layered cuprates and tungsten bronzes place the upper limit on Tc. Than, the percolative self-organized mechanism on the metal/insulator interface like Na/WO3 and NaWO3/nanostructured matrix can facilitate the high Tc obtained in sodium bronzes infiltrated into inverted carbon opal or carbon nanotube matricies.

  2. Synthesis of WO{sub 3} flower-like hierarchical architectures and their sensing properties

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Dan; Wang, Guosheng; San, Xiaoguang [College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142 (China); Song, Yinmin [College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051 (China); Shen, Yanbai, E-mail: [College of Resources and Civil Engineering, Northeastern University, Shenyang 110819 (China); Zhang, Yajing; Wang, Kangjun [College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142 (China); Meng, Fanli, E-mail: [Research Center for Biomimetic Functional Materials and Sensing Devices, Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031 (China)


    WO{sub 3} flower-like hierarchical architectures were synthesized by hydrothermal process using sodium tungstate (Na{sub 2}WO{sub 4}·2H{sub 2}O) as tungsten source and citric acid (CA) as an assistant agent. The morphology and crystal structure were investigated using scanning electron microscope and X-ray diffractometer. It is found that CA played a significant role in governing morphologies of product during hydrothermal process. The obtained products were identified as triclinic crystal WO{sub 3} structure. The ethanol gas sensing measurements showed that well-defined WO{sub 3} flower-like structures synthesized at CA/W molar ratio of 1 with large specific surface area exhibited the higher responses compared with others at all operating temperatures. Moreover, the reversible and fast response to ethanol gas at various gas concentrations and good selectivity were obtained. The results indicated that the WO{sub 3} flower-like hierarchical architectures are promising materials for gas sensors. - Highlights: • WO{sub 3} flower-like structures were successfully synthesized by hydrothermal method. • The effect of citric acid amount on morphologies was investigated. • Good ethanol gas sensing properties of WO{sub 3} flower-like structures were obtained.

  3. Gas sensing properties of graphene–WO{sub 3} composites prepared by hydrothermal method

    Energy Technology Data Exchange (ETDEWEB)

    Chu, Xiangfeng, E-mail: [School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002 (China); Hu, Tao [School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002 (China); Gao, Feng [Department of Materials Science and Engineering, Nanjing University, Nanjing 210093 (China); Dong, Yongping; Sun, Wenqi; Bai, Linshan [School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002 (China)


    Graphical abstract: - Highlights: • The amount of graphene had an effect on the morphology of graphene–WO{sub 3} composites. • The optimum temperature of 0.1 wt% graphene–WO{sub 3} sensor to acetaldehyde was 100 °C. • 0.1 wt% graphene–WO{sub 3} sensor exhibited good selectivity to acetaldehyde at 100 °C. - Abstract: Graphene–WO{sub 3} composites mixed with different amounts of graphene (0, 0.1, 0.5, 1 and 3 wt%) were prepared by hydrothermal method at 180 °C for 24 h. The as-prepared graphite oxide, graphene and graphene–WO{sub 3} composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectra (FT-IR) and Raman spectroscopy, respectively. The effect of the amount of graphene in the composites on the gas-sensing responses and the gas-sensing selectivity of the materials was investigated. The experimental results revealed that the sensor based on 0.1 wt% graphene–WO{sub 3} composite exhibited high response and good selectivity to acetaldehyde vapor at 100 °C, the optimum operating temperature of this sensor to 1000 ppm acetaldehyde vapor decreased from 180 °C to 100 °C comparing with that of pure WO{sub 3}. The response time and the recovery time for 100 ppm acetaldehyde vapor were 250 s and 225 s, respectively.

  4. WO3 nanorolls self-assembled as thin films by hydrothermal synthesis (United States)

    Vankova, S.; Zanarini, S.; Amici, J.; Cámara, F.; Arletti, R.; Bodoardo, S.; Penazzi, N.


    We report a novel type of WO3 nanostructure, i.e. nanorolls obtained as a self-assembled thin film on a transparent conductive substrate. The mild conditions of preparation, avoiding the use of HCl, result in an eco-friendly hydrothermal method with reduced crystallization time. FESEM and HR-TEM show that WO3 nanocrystals are made of rolled nanoflakes with a telescope-like appearance at their tip. For their nano-porosity, electrochemical accessibility, good adhesion to substrates and the envisaged presence of nanocavities between the WO3 layers, these materials hold tremendous promise in nano-electronics, electrochromic devices, water photo-splitting cells, Li-ion batteries and nano-templated filters for UV radiation.We report a novel type of WO3 nanostructure, i.e. nanorolls obtained as a self-assembled thin film on a transparent conductive substrate. The mild conditions of preparation, avoiding the use of HCl, result in an eco-friendly hydrothermal method with reduced crystallization time. FESEM and HR-TEM show that WO3 nanocrystals are made of rolled nanoflakes with a telescope-like appearance at their tip. For their nano-porosity, electrochemical accessibility, good adhesion to substrates and the envisaged presence of nanocavities between the WO3 layers, these materials hold tremendous promise in nano-electronics, electrochromic devices, water photo-splitting cells, Li-ion batteries and nano-templated filters for UV radiation. Electronic supplementary information (ESI) available: Characterization techniques; additional FESEM micrographs; typical XRD pattern of WO3 nanoroll thin film; typical Nyquist plots at ambient temperature; indicative diameter and length of WO3 NR by varying the PVA chain length; effect of 2000 cycles of electrochemical switching on the STB, STC and ΔT% coloration efficiency of the WO3 NR. See DOI: 10.1039/c4nr07290a

  5. Dual preparation of hydrophobic and hydrophilic BaWO{sub 4}:Eu phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Young-Sik; Huh, Young-Duk, E-mail:


    Highlights: • Red-emitting BaWO{sub 4}:Eu phosphors were prepared in hexane-water bilayer system. • The hydrophobic nanometer-sized BaWO{sub 4}:Eu phosphors were obtained in hexane. • The hydrophilic micrometer-sized BaWO{sub 4}:Eu dendrites were obtained in water. - Abstract: BaWO{sub 4}:Eu phosphors were prepared by performing a solvothermal reaction in a water–hexane bilayer system. A barium oleate (and europium oleate) complex was obtained in hexane via a phase transfer reaction involving Ba{sup 2+} (and Eu{sup 3+}) ions in an aqueous solution of sodium oleate. The outer surfaces of the nanometer-sized BaWO{sub 4}:Eu phosphors were capped by the long alkyl chain of oleate; therefore, the hydrophobic nanometer-sized BaWO{sub 4}:Eu phosphors preferentially dissolved in the hexane layer. The micrometer-sized BaWO{sub 4}:Eu phosphors were obtained in the water layer. The BaWO{sub 4}:Eu phosphors prepared in hexane and water yielded sharp strong absorption and emission peaks at 464 and 615 nm, respectively, due to the {sup 7}F{sub 0} → {sup 5}D{sub 2} and the {sup 5}D{sub 0} →{sup 7} F{sub 2} transitions of the Eu{sup 3+} ions. The BaWO{sub 4}:Eu phosphors are good candidate red-emitting phosphors for use in InGaN blue-emitting diodes, which have an emission wavelength of 465 nm.

  6. Nuclear-pumped lasers

    CERN Document Server

    Prelas, Mark


    This book focuses on Nuclear-Pumped Laser (NPL) technology and provides the reader with a fundamental understanding of NPLs, a review of research in the field, and exploration of large scale NPL system design and applications. Early chapters look at the fundamental properties of lasers, nuclear-pumping and nuclear reactions that may be used as drivers for nuclear-pumped lasers. The book goes on to explore the efficient transport of energy from the ionizing radiation to the laser medium and then the operational characteristics of existing nuclear-pumped lasers. Models based on Mathematica, explanations and a tutorial all assist the reader’s understanding of this technology. Later chapters consider the integration of the various systems involved in NPLs and the ways in which they can be used, including beyond the military agenda. As readers will discover, there are significant humanitarian applications for high energy/power lasers, such as deflecting asteroids, space propulsion, power transmission and mining....

  7. Absorption heat pump system (United States)

    Grossman, G.


    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  8. High Voltage Charge Pump

    KAUST Repository

    Emira, Ahmed A.


    Various embodiments of a high voltage charge pump are described. One embodiment is a charge pump circuit that comprises a plurality of switching stages each including a clock input, a clock input inverse, a clock output, and a clock output inverse. The circuit further comprises a plurality of pumping capacitors, wherein one or more pumping capacitors are coupled to a corresponding switching stage. The circuit also comprises a maximum selection circuit coupled to a last switching stage among the plurality of switching stages, the maximum selection circuit configured to filter noise on the output clock and the output clock inverse of the last switching stage, the maximum selection circuit further configured to generate a DC output voltage based on the output clock and the output clock inverse of the last switching stage.

  9. Regenerative Hydride Heat Pump (United States)

    Jones, Jack A.


    Hydride heat pump features regenerative heating and single circulation loop. Counterflow heat exchangers accommodate different temperatures of FeTi and LaNi4.7Al0.3 subloops. Heating scheme increases efficiency.

  10. Underground pumped hydroelectric storage (United States)

    Allen, R. D.; Doherty, T. J.; Kannberg, L. D.


    Underground pumped hydroelectric energy storage was conceived as a modification of surface pumped storage to eliminate dependence upon fortuitous topography, provide higher hydraulic heads, and reduce environmental concerns. A UPHS plant offers substantial savings in investment cost over coal-fired cycling plants and savings in system production costs over gas turbines. Potential location near load centers lowers transmission costs and line losses. Environmental impact is less than that for a coal-fired cycling plant. The inherent benefits include those of all pumped storage (i.e., rapid load response, emergency capacity, improvement in efficiency as pumps improve, and capacity for voltage regulation). A UPHS plant would be powered by either a coal-fired or nuclear baseload plant. The economic capacity of a UPHS plant would be in the range of 1000 to 3000 MW. This storage level is compatible with the load-velocity requirements of a greater metropolitan area with population of 1 million or more.

  11. Chiral brownian heat pump. (United States)

    van den Broek, M; Van den Broeck, C


    We present the exact analysis of a chiral Brownian motor and heat pump. Optimization of the construction predicts, for a nanoscale device, frequencies of the order of kHz and cooling rates of the order of femtojoule per second.

  12. Chiral Brownian heat pump


    Van Den Broek, Martijn; Van Den Broeck, Christian


    We present the exact analysis of a chiral Brownian motor and heat pump. Optimization of the construction predicts, for a nanoscale device, frequencies of the order of kHz and cooling rates of the order of femtojoule per second.

  13. Regenerative Hydride Heat Pump (United States)

    Jones, Jack A.


    Hydride heat pump features regenerative heating and single circulation loop. Counterflow heat exchangers accommodate different temperatures of FeTi and LaNi4.7Al0.3 subloops. Heating scheme increases efficiency.

  14. High efficiency tandem organic light-emitting devices with Al/WO3/Au interconnecting layer



    An interconnecting layer of Al (2 nm)/WO3 (3 nm)/Au (16 nm) was studied for application in tandem organic light-emitting devices. It can be seen that the Al/WO3/Au structure plays the role of an excellent interconnecting layer. The introduction of WO3 in the connection unit significantly improves the device efficiency as compared to the case of Al/Au. Thus, the current efficiency of the two-unit tandem devices is enhanced by two factors with respect to the one-unit devices. The green two-u...

  15. CTAB-assisted ultrasonic synthesis, characterization and photocatalytic properties of WO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Sánchez-Martínez, D., E-mail:; Gomez-Solis, C.; Torres-Martinez, Leticia M.


    Highlights: • WO{sub 3} 2D nanostructures were synthesized by ultrasound method assisted with CTAB. • WO{sub 3} morphology was mainly of rectangular nanoplates with a thickness of ∼50 nm. • The highest surface area value of WO{sub 3} was obtained to lowest concentration of CTAB. • WO{sub 3} activity was attributed to morphology, surface area and the addition of CTAB. • WO{sub 3} nanoplates were able to causing almost complete mineralization of rhB and IC. - Abstract: WO{sub 3} 2D nanostructures have been prepared by ultrasound synthesis method assisted with CTAB using different molar ratios. The formation of monoclinic crystal structure of WO{sub 3} was confirmed by X-ray powder diffraction (XRD). The characterization of the WO{sub 3} samples was complemented by analysis of scanning electron microscopy (SEM), which revealed morphology mainly of rectangular nanoplates with a thickness of around 50 nm and length of 100–500 nm. Infrared spectroscopy (FT-IR) was used to confirm the elimination of the CTAB in the synthesized samples. The specific surface area was determinate by the BET method and by means of diffuse reflectance spectroscopy (DRS) it was determinate the band-gap energy (E{sub g}) of the WO{sub 3} samples. The photocatalytic activity of the WO{sub 3} oxide was evaluated in the degradation reactions of rhodamine B (rhB) and indigo carmine (IC) under Xenon lamp irradiation. The highest photocatalytic activity was observed in the samples containing low concentration of CTAB with morphology of rectangular nanoplates and with higher surface area value than commercial WO{sub 3}. Photodegradation of rhB and IC were followed by means of UV–vis absorption spectra. The mineralization degree of organic dyes by WO{sub 3} photocatalyst was determined by total organic carbon analysis (TOC) reaching percentages of mineralization of 92% for rhB and 50% for IC after 96 h of lamp irradiation.

  16. Ab-initio density functional theory study of a WO3 NH3-sensing mechanism

    Institute of Scientific and Technical Information of China (English)

    Hu Ming; Zhang Jie; Wang Wei-Dan; Qin Yu-Xiang


    WO3 bulk and various surfaces are studied by an ab-initio density functional theory technique.The band structures and electronic density states of WO3 bulk are investigated.The surface energies of different WO3 surfaces are compared and then the(002)surface with minimum energy is computed for its NH3 sensing mechanism which explains the results in the experiments.Three adsorption sites are considered.According to the comparisons of the energy and the charge change between before and after adsorption in the optimal adsorption site O1c,the NH3 sensing mechanism is obtained.

  17. Synthesis of WC powder through microwave heating of WO3-C mixture (United States)

    Behnami, Amir Karimzadeh; Hoseinpur, Arman; Sakaki, Masoud; Bafghi, Mohammad Sh.; Yanagisawa, Kazumichi


    A simple, easy, and low-cost process for the fabrication of tungsten carbide (WC) powder through microwave heating of WO3-C mixtures was developed. Thermodynamic calculations and experimental investigations were carried out for WO3-C and W-C systems, and a formation mechanism was proposed. In the results, for the synthesis of WC, the use of over stoichiometric amount of C together with a specially assembled experimental setup (which effectively retains heat in the system) is necessary. The WC powder is successfully obtained by heating WO3:5C mixture for 900 s in a domestic microwave oven.

  18. Electrodeposition of WO3 nanoparticles into surface mounted metal-organic framework HKUST-1 thin films (United States)

    Yoo, Hyeonseok; Welle, Alexander; Guo, Wei; Choi, Jinsub; Redel, Engelbert


    We describe a novel procedure to fabricate WO3@surface-mounted metal-organic framework (SURMOF) hybrid materials by electrodeposition of WO3 nanoparticles into HKUST-1, also termed Cu3(BTC)2 SURMOFs. These materials have been characterized using x-ray diffraction, time-of-flight secondary ion mass spectrometry, scanning electron microscopy, x-ray photoelectron spectroscopy as well as linear sweep voltammetry. The WO3 semiconductor/SURMOF heterostructures were further tested as hybrid electrodes in their performance for hydrogen evolution reaction from water.

  19. Ethanol vapour sensing properties of screen printed WO3 thick films

    Indian Academy of Sciences (India)

    R S Khadayate; R B Waghulde; M G Wankhede; J V Sali; P P Patil


    This paper presents ethanol vapour sensing properties of WO3 thick films. In this work, the WO3 thick films were prepared by standard screen-printing method. These films were characterized by X-ray diffraction (XRD) measurements and scanning electron microscopy (SEM). The ethanol vapour sensing properties of these thick films were investigated at different operating temperatures and ethanol vapour concentrations. The WO3 thick films exhibit excellent ethanol vapour sensing properties with a maximum sensitivity of ∼1424.6% at 400°C in air atmosphere with fast response and recovery time.

  20. Remotely Adjustable Hydraulic Pump (United States)

    Kouns, H. H.; Gardner, L. D.


    Outlet pressure adjusted to match varying loads. Electrohydraulic servo has positioned sleeve in leftmost position, adjusting outlet pressure to maximum value. Sleeve in equilibrium position, with control land covering control port. For lowest pressure setting, sleeve shifted toward right by increased pressure on sleeve shoulder from servovalve. Pump used in aircraft and robots, where hydraulic actuators repeatedly turned on and off, changing pump load frequently and over wide range.

  1. Velocity selective optical pumping


    Aminoff, C. G.; Pinard, M.


    We consider optical pumping with a quasi monochromatic tunable light beam, in the low intensity limit where a rate equation regime is obtained The velocity selective optical pumping (V.S.O.P.) introduces a correlation between atomic velocity and internal variables in the ground (or metastable) state. The aim of this article is to evaluate these atomic observables (orientation, alignment, population) as a function of velocity, using a phenomenological description of the relaxation effect of co...

  2. Lunar Base Heat Pump (United States)

    Walker, D.; Fischbach, D.; Tetreault, R.


    The objective of this project was to investigate the feasibility of constructing a heat pump suitable for use as a heat rejection device in applications such as a lunar base. In this situation, direct heat rejection through the use of radiators is not possible at a temperature suitable for lde support systems. Initial analysis of a heat pump of this type called for a temperature lift of approximately 378 deg. K, which is considerably higher than is commonly called for in HVAC and refrigeration applications where heat pumps are most often employed. Also because of the variation of the rejection temperature (from 100 to 381 deg. K), extreme flexibility in the configuration and operation of the heat pump is required. A three-stage compression cycle using a refrigerant such as CFC-11 or HCFC-123 was formulated with operation possible with one, two or three stages of compression. Also, to meet the redundancy requirements, compression was divided up over multiple compressors in each stage. A control scheme was devised that allowed these multiple compressors to be operated as required so that the heat pump could perform with variable heat loads and rejection conditions. A prototype heat pump was designed and constructed to investigate the key elements of the high-lift heat pump concept. Control software was written and implemented in the prototype to allow fully automatic operation. The heat pump was capable of operation over a wide range of rejection temperatures and cooling loads, while maintaining cooling water temperature well within the required specification of 40 deg. C +/- 1.7 deg. C. This performance was verified through testing.


    NARCIS (Netherlands)



    Rotary blood pumps are used for cardiac assist and cardiopulmonary support since mechanical blood damage is less than with conventional roller pumps. The high shear rate in the rotary pump and the reduced anticoagulation of the patient during prolonged pumping enforces high demands on the biocompati

  4. Pumping a playground swing. (United States)

    Post, Auke A; de Groot, Gert; Daffertshofer, Andreas; Beek, Peter J


    In mechanical studies of pumping a playground swing, two methods of energy insertion have been identified: parametric pumping and driven oscillation. While parametric pumping involves the systematic raising and lowering of the swinger's center of mass (CM) along the swing's radial axis (rope), driven oscillation may be conceived as rotation of the CM around a pivot point at a fixed distance to the point of suspension. We examined the relative contributions of those two methods of energy insertion by inviting 18 participants to pump a swing from standstill and by measuring and analyzing the swing-swinger system (defined by eight markers) in the sagittal plane. Overall, driven oscillation was found to play a major role and parametric pumping a subordinate role, although the relative contribution of driven oscillation decreased as swinging amplitude increased, whereas that of parametric pumping increased slightly. Principal component analysis revealed that the coordination pattern of the swing-swinger system was largely determined (up to 95%) by the swing's motion, while correlation analysis revealed that (within the remaining 5% of variance) trunk and leg rotations were strongly coupled.

  5. Thermally Actuated Hydraulic Pumps (United States)

    Jones, Jack; Ross, Ronald; Chao, Yi


    Thermally actuated hydraulic pumps have been proposed for diverse applications in which direct electrical or mechanical actuation is undesirable and the relative slowness of thermal actuation can be tolerated. The proposed pumps would not contain any sliding (wearing) parts in their compressors and, hence, could have long operational lifetimes. The basic principle of a pump according to the proposal is to utilize the thermal expansion and contraction of a wax or other phase-change material in contact with a hydraulic fluid in a rigid chamber. Heating the chamber and its contents from below to above the melting temperature of the phase-change material would cause the material to expand significantly, thus causing a substantial increase in hydraulic pressure and/or a substantial displacement of hydraulic fluid out of the chamber. Similarly, cooling the chamber and its contents from above to below the melting temperature of the phase-change material would cause the material to contract significantly, thus causing a substantial decrease in hydraulic pressure and/or a substantial displacement of hydraulic fluid into the chamber. The displacement of the hydraulic fluid could be used to drive a piston. The figure illustrates a simple example of a hydraulic jack driven by a thermally actuated hydraulic pump. The pump chamber would be a cylinder containing encapsulated wax pellets and containing radial fins to facilitate transfer of heat to and from the wax. The plastic encapsulation would serve as an oil/wax barrier and the remaining interior space could be filled with hydraulic oil. A filter would retain the encapsulated wax particles in the pump chamber while allowing the hydraulic oil to flow into and out of the chamber. In one important class of potential applications, thermally actuated hydraulic pumps, exploiting vertical ocean temperature gradients for heating and cooling as needed, would be used to vary hydraulic pressures to control buoyancy in undersea research

  6. Photoreduction of non-noble metal Bi on the surface of Bi2WO6 for enhanced visible light photocatalysis (United States)

    Zhang, Xiaojing; Yu, Shan; Liu, Yang; Zhang, Qian; Zhou, Ying


    In this report, Bi2WO6-Bi composite was prepared through an in situ photoreduction method and was characterized systematically by X-Ray diffraction, transmission electron microscopy, X-Ray photoelectron spectroscopy and UV-vis diffuse reflectance spectroscopy. The as-prepared Bi2WO6-Bi maintains the same crystal structure with the pristine Bi2WO6 regardless of some surface defects. Nevertheless, these surface defects result in the change of surface oxygen adsorption mode from hydroxyl to molecular oxygen on Bi2WO6. Photocatalytic activity over Bi2WO6-Bi is 2.4 times higher than that of Bi2WO6 towards the degradation of organic dye Rhodamine B (RhB) under visible light irradiation (λ > 420 nm). A deep study shows that cleavage of benzene ring is the main pathway for RhB degradation over Bi2WO6, but both the benzene cleavage and de-ethylation pathway coexist for RhB decomposition in the presence of Bi2WO6-Bi as the photocatalyst. Photoelectrochemical study including transient photocurrent tests and electrochemical impedance spectroscopy measurements shows that Bi2WO6-Bi could facilitate the charge transfer process compared to Bi2WO6. These data above has indicated a new insight into the promotion mechanism based on Bi related heterostructures.

  7. Q-switching of a Tm,Ho:KLu(WO4)2 microchip laser by a graphene-based saturable absorber (United States)

    Serres, J. M.; Loiko, P.; Mateos, X.; Jambunathan, V.; Yumashev, K.; Griebner, U.; Petrov, V.; Aguiló, M.; Díaz, F.


    The first Ho microchip laser passively Q-switched using a graphene-based saturable absorber is demonstrated based on a Tm,Ho:KLu(WO4)2 crystal cut along the N g-axis. A maximum average output power of 74 mW is extracted from the diode-pumped laser at 2061 nm with a slope efficiency of 4%. Pulses as short as 200 ns with an energy of ~0.2 μJ are obtained at a repetition rate of 340 kHz. The energy transfer (ET), 3F4 (Tm3+) ↔ 5I7 (Ho3+) is studied, yielding ET parameters of P 28  =  1.69 and P 71  =  0.15  ×  10-22 cm3 μs-1, revealing the strong prevalence of direct ET.

  8. Preparation of WO3/g-C3N4 composites and their application in oxidative desulfurization (United States)

    Zhao, Rongxiang; Li, Xiuping; Su, Jianxun; Gao, Xiaohan


    WO3/graphitic carbon nitride (g-C3N4) composites were successfully synthesized through direct calcining of a mixture of WO3 and g-C3N4 at 400 °C for 2 h. The WO3 was prepared by calcination of phosphotungstic acid at 550 °C for 4 h, and the g-C3N4 was obtained by calcination of melamine at 520 °C for 4 h. The WO3/g-C3N4 composites were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FT-IR), and Brunner-Emmett-Teller analysis (BET). The WO3/g-C3N4 composites exhibited stronger XRD peaks of WO3 and g-C3N4 than the WO3 and pure g-C3N4. In addition, two WO3 peaks at 25.7° and 26.6° emerged for the 36% -WO3/g-C3N4 composite. This finding indicated that WO3 was highly dispersed on the surface of the g-C3N4 nanosheets and interacted with the nanosheets, which resulted in the appearance of (012) and (022) planes of WO3. The WO3/g-C3N4 composite also exhibited a larger specific surface area and higher degree of crystallization than WO3 or pure g-C3N4, which resulted in high catalytic activity of the catalyst. Desulfurization experiments demonstrated that the desulfurization rate of dibenzothiophene (DBT) in model oil reached 91.2% under optimal conditions. Moreover, the activity of the catalyst was not significantly decreased after five recycles.

  9. Electronic Unit Pump Test Bench Development and Pump Properties Research

    Institute of Scientific and Technical Information of China (English)

    LIU Bo-lan; HUANG Ying; ZHANG Fu-jun; ZHAO Chang-lu


    A unit pump test bench is developed on an in-line pump test platform. The bench is composed of pump adapting assembly, fuel supply subsystem, lubricating subsystem and a control unit. A crank angle domain injection control method is given out and the control accuracy can be 0.1° crank degree. The bench can test bot h mechanical unit pump and electronic unit pump. A test model-PLD12 electronic unit pump is tested. Full pump delivery map and some influence factors test is d one. Experimental results show that the injection quantity is linear with the de livery angle. The quantity change rate is 15% when fuel temperature increases 30℃. The delivery quantity per cycle increases 30mg at 28V drive voltage. T he average delivery difference for two same type pumps is 5%. Test results show that the bench can be used for unit pump verification.

  10. Piezo-optic coefficients of CaWO4 crystals (United States)

    Mytsyk, B. G.; Kost', Ya. P.; Demyanyshyn, N. M.; Andrushchak, A. S.; Solskii, I. M.


    All components of the piezo-optic coefficient matrix of calcium tungstate crystals, belonging to the 4/ m symmetry class, are determined. The reliability of the piezo-optic effect measurements in CaWO4 crystals is achieved by determining each piezo-optic coefficient from several experimental geometries and is also based on the correlation of the absolute piezo-electric coefficients and the path-difference coefficients. The rotation-shear diagonal coefficients π44 and π66 and three principal piezo-optic coefficients π11, π13, and π31 are refined by the polarization-optical method. It is confirmed that both the interferometric and polarization-optical methods should be used to study the piezo-optic effect with high accuracy. The results show that calcium tungstate is a promising material for acousto-optical and photoelastic modulation.

  11. Scheelite CaWO{sub 4} at high pressures

    Energy Technology Data Exchange (ETDEWEB)

    Grzechnik, Andrzej [Laboratory of Crystallography, University of Bayreuth, D-95440 Bayreuth (Germany); Crichton, Wilson A [European Synchrotron Radiation Facility, BP 220, F-38043 Grenoble cedex (France); Hanfland, Michael [European Synchrotron Radiation Facility, BP 220, F-38043 Grenoble cedex (France); Smaalen, Sander van [Laboratory of Crystallography, University of Bayreuth, D-95440 Bayreuth (Germany)


    The high-pressure room-temperature behaviour of scheelite CaWO{sub 4} (I4{sub 1}/a,Z = 4) is studied using high-resolution synchrotron angle-dispersive x-ray powder diffraction in diamond anvil cells loaded with helium or a mixture of methanol and ethanol as the pressure-transmitting media. At about 10 GPa, there occurs a phase transition to the fergusonite type (I 2/a,Z = 4) without any discontinuity in the pressure dependence of the unit cell volumes. These observations are discussed in relation to the high-pressure-high-temperature systematics of the AMX{sub 4} and AX{sub 2} type compounds.

  12. Effect of TiO2 Nanoparticles on Photochromism of WO3 Colloids

    Institute of Scientific and Technical Information of China (English)


    WO3 and TiO2 colloids were synthesized by the hydrolysis technique and part of the TiO2 colloid was treated by means of the hydrothermal method. The photochromic performances of the resulting materials obtained via combining the WO3 colloid with the treated TiO2 colloid and the non-treated TiO2 colloid, respectively, are very different. The TiO2 colloid without hydrothermal treatment can effectively improve the photochromic performance of the WO3 colloid. The TiO2 nanoparticles were investigated in detail by XRD, TEM, surface photovoltage spectra(SPS) and field-induced surface photovoltage spectrometry(FISPS). The photochromism mechanism of WO3 colloid is discussed.

  13. Hydrothermal Fabrication of WO3 Hierarchical Architectures: Structure, Growth and Response

    Directory of Open Access Journals (Sweden)

    Chuan-Sheng Wu


    Full Text Available Recently hierarchical architectures, consisting of two-dimensional (2D nanostructures, are of great interest for potential applications in energy and environmental. Here, novel rose-like WO3 hierarchical architectures were successfully synthesized via a facile hydrothermal method. The as-prepared WO3 hierarchical architectures were in fact assembled by numerous nanosheets with an average thickness of ~30 nm. We found that the oxalic acid played a significant role in governing morphologies of WO3 during hydrothermal process. Based on comparative studies, a possible formation mechanism was also proposed in detail. Furthermore, gas-sensing measurement showed that the well-defined 3D WO3 hierarchical architectures exhibited the excellent gas sensing properties towards CO.

  14. Synthesis of Bi2WO6 Microspheres with Visible-Light Photocatalytic Properties (United States)

    Wan, Gengping; Wang, Guizhen


    Bi2WO6 microspheres constructed from nanosheets have been synthesized by a controllable solvothermal route in a large scale. The structure characterizations of the microspheres were investigated in detail by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). On the basis of XRD analysis and SEM observation of the products at different reaction time periods, a growth mechanism of Bi2WO6 microspheres was proposed. UV-Visible diffuse reflectance (DR) spectrum of the prepared Bi2WO6 microspheres demonstrates that they have absorption in the visible light region. The photocatalytic activity of Bi2WO6 microspheres toward Rhodamine-B (RhB) degradation was investigated and the as-prepared products exhibited good photocatalytic activity in degradation of RhB under 300 W Xe lamp light irradiation.

  15. Hydrothermal synthesis of Bi2WO6 hierarchical flowers with their photonic and photocatalytic properties (United States)

    Dumrongrojthanath, Phattharanit; Thongtem, Titipun; Phuruangrat, Anukorn; Thongtem, Somchai


    Bi2WO6 hierarchical multi-layered flower-like assemblies were synthesized by a hydrothermal method at 180 °C for 24 h. XRD patterns were specified as pure orthorhombic well-crystallized Bi2WO6 phase. Their FTIR spectra show main absorption bands at 400-1000 cm-1, assigned as the stretching modes of the Bi-O and W-O, and W-O-W bridging stretching modes. SEM analysis shows that the product was 3D hierarchical flower-like assemblies, constructed by orderly arranged 2D layers of nanoplates. The UV-visible absorption shows an absorbance in the ultraviolet region with 3.4 eV band gap. Photocatalytic activity of Bi2WO6 hierarchical flowers was determined from the degradation of rhodamine-B by Xe light at 88% for 360 min irradiation.

  16. Photocatalytic Activity of Nanosized ZnWO4 Prepared by the Sol-gel Method

    Institute of Scientific and Technical Information of China (English)

    WU Yan; ZHANG Shi-cheng; ZHANG Li-wu; ZHU Yong-fa


    Nanosized ZnWO4 photocatalysts were successfully synthesized via the sol-gel process in a temperature range of 450-800 ℃. The grain size, crystal size, and crystallinity of ZnWO4 particles increased with the increase of calcination temperature and prolonging calcination time. The photocatalytic activity was measured for the degradation of an aqueous Rhodamine-B(RhB) solution and gaseous formaldehyde(FAD). With the increase of calcination temperature and time, the activities increased to a maximum and then decreased. ZnWO4 photocatalyst prepared at 550 ℃ for 10 h showed the highest activity, which is similar to the photocatalytic activity of P25TiO2 for the degradation of gaseous FAD. High crystallinity, large surface area, and good dispersion are responsible for the high photocatalytic performance of the prepared ZnWO4.

  17. Analysis of Publication Trends for DOE National Laboratories Comparisons using WoS and Scopus

    Energy Technology Data Exchange (ETDEWEB)

    Springer, Everett P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Milligan, Shelby [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    This report describes: 1) how various laboratories compare in terms of peer-reviewed publications; how the numbers and trends compare between WoS and Scopus; and what research areas have grown or decreased.

  18. AOT-microemulsions-based formation and evolution of PbWO$_{4}$ crystals

    CERN Document Server

    Chen, D; Tang Kai Bin; Liang Zhen Hua; Zheng Hua Gui


    Anionic surfactant-AOT-microemulsions-assisted formation and evolution of PbWO//4 nanostructures with bundles rodlike, ellipsoidlike, and spherelike prepared at different media conditions were studied by powder X-ray diffraction pattern, field emission scanning electron microscopy, and transmission electron microscopy. The possible mechanisms for the formation of PbWO//4 samples in series of microemulsion systems were discussed. Various comparison experiments show that several experimental parameters, such as the AOT concentration, the water content, and reaction temperature play important roles in the morphological control of PbWO//4 nanostructures. Room-temperature photoluminescence of PbWO//4 samples with different morphologies has also been investigated and the results reveal that all these samples showed similar features with emissions at 480 similar to 510 nm but different luminescence intensity. 40 Refs.

  19. Bacteriophage WO Can Mediate Horizontal Gene Transfer in Endosymbiotic Wolbachia Genomes (United States)

    Wang, Guan H.; Sun, Bao F.; Xiong, Tuan L.; Wang, Yan K.; Murfin, Kristen E.; Xiao, Jin H.; Huang, Da W.


    Phage-mediated horizontal gene transfer (HGT) is common in free-living bacteria, and many transferred genes can play a significant role in their new bacterial hosts. However, there are few reports concerning phage-mediated HGT in endosymbionts (obligate intracellular bacteria within animal or plant hosts), such as Wolbachia. The Wolbachia-infecting temperate phage WO can actively shift among Wolbachia genomes and has the potential to mediate HGT between Wolbachia strains. In the present study, we extend previous findings by validating that the phage WO can mediate transfer of non-phage genes. To do so, we utilized bioinformatic, phylogenetic, and molecular analyses based on all sequenced Wolbachia and phage WO genomes. Our results show that the phage WO can mediate HGT between Wolbachia strains, regardless of whether the transferred genes originate from Wolbachia or other unrelated bacteria. PMID:27965627

  20. [Doctor's degree thesis of Tomasz Adolf Wołkowiński "Carditidis rheumaticae historia"]. (United States)

    Stembrowicz, W


    In 1817 on the University of Vilnius Faculty of Medicine, T. A. Wołkowiński, a student of the eminent clinician Józef Frank, defended his doctor's degree thesis about a direct relation between rheumatic disease and cardiomegaly. It was probably the first paper in Poland describing with details the rheumatic heart disease. Unfortunately we don't know much about T. A. Wołkowiński's life.

  1. Facile and controlled synthesis of aligned WO3 nanorods and nanosheets as an efficient photocatalyst material (United States)

    Ahmed, Bilal; Kumar, Sumeet; Ojha, Animesh K.; Donfack, P.; Materny, A.


    In this work, we have performed a facile and controlled synthesis of WO3 nanorods and sheets in different crystal phases (triclinic, orthorhombic and monoclinic) of WO3 using the sol-gel method. The detailed structures of the synthesized materials were examined by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and Raman spectroscopy measurements. The shapes and crystal phases of the WO3 nanostructures were found to be highly dependent on the calcination temperature. The variation in crystalline phases and shapes is modified the electronic structure of the samples, which causes a variation in the value of optical band gap. The value of the Raman line intensity ratio I264/I320 has been successfully used to identify the structural transition from the triclinic to the orthorhombic phase of WO3. The PL spectra of the synthesized products excited at wavelengths 380, 400, and 420 nm exhibit intense emission peaks that cover the complete visible range (blue-green-red). The emission peaks at 460 and 486 nm were caused by the near band-edge and band to band transition, respectively. The peaks in spectral range 500-600 nm might be originated from the presence of oxygen vacancies lying within the energy band gap. The synthesized WO3 nanostructures showed improved photocatalytic activity for the photodegradation of MB dye. The enhanced photocatalytic activity of WO3 nanosheets compared to WO3 nanorods for photodegradation of methylene blue (MB) dye could be due to the shape of the nanostructured WO3. The sheet type of structure provides more active surface for the interaction of dye molecules compared to the rods, which results in a more efficient degradation of the dye molecules.

  2. Synthesis and evaluation of α-Ag2WO4 as novel antifungal agent (United States)

    Foggi, Camila C.; Fabbro, Maria T.; Santos, Luís P. S.; de Santana, Yuri V. B.; Vergani, Carlos E.; Machado, Ana L.; Cordoncillo, Eloisa; Andrés, Juan; Longo, Elson


    Because of the need for new antifungal materials with greater potency, microcrystals of α-Ag2WO4, a complex metal oxide, have been synthetized by a simple co-precipitation method, and their antifungal activity against Candida albicans has been investigated. A theoretical model based on clusters that are building blocks of α-Ag2WO4 has been proposed to explain the experimental results.

  3. Heat driven pulse pump (United States)

    Benner, Steve M (Inventor); Martins, Mario S. (Inventor)


    A heat driven pulse pump includes a chamber having an inlet port, an outlet port, two check valves, a wick, and a heater. The chamber may include a plurality of grooves inside wall of the chamber. When heated within the chamber, a liquid to be pumped vaporizes and creates pressure head that expels the liquid through the outlet port. As liquid separating means, the wick, disposed within the chamber, is to allow, when saturated with the liquid, the passage of only liquid being forced by the pressure head in the chamber, preventing the vapor from exiting from the chamber through the outlet port. A plurality of grooves along the inside surface wall of the chamber can sustain the liquid, which is amount enough to produce vapor for the pressure head in the chamber. With only two simple moving parts, two check valves, the heat driven pulse pump can effectively function over the long lifetimes without maintenance or replacement. For continuous flow of the liquid to be pumped a plurality of pumps may be connected in parallel.

  4. Photoelectrochemical solar cells based on Bi{sub 2}WO{sub 6}; Celdas solares fotoelectroquimicas basadas en Bi{sub 2}WO{sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Madriz, Lorean; Tata, Jose; Cuartas, Veronica; Cuellar, Alejandra; Vargas, Ronald, E-mail: [Departamento de Quimica, Universidad Simon Bolivar, Caracas (Venezuela, Bolivarian Republic of)


    In this study, photoelectrochemical solar cells based on bismuth tungstate electrodes were evaluated. Bi{sub 2}WO{sub 6} was synthesized by a hydrothermal method and characterized by scanning electron microscopy, UV-Vis reflectance spectroscopy, and X-ray powder diffraction. For comparison, solar cells based on TiO{sub 2} semiconductor electrodes were evaluated. Photoelectrochemical response of Grätzel-type solar cells based on these semiconductors and their corresponding sensitization with two inexpensive phthalocyanines dyes were determined. Bi{sub 2}WO{sub 6}-based solar cells presented higher values of photocurrent and efficiency than those obtained with TiO{sub 2} electrodes, even without sensitization. These results portray solar cells based on Bi{sub 2}WO{sub 6} as promising devices for solar energy conversion owing to lower cost of production and ease of acquisition. (author)

  5. Modulating memristive performance of hexagonal WO3 nanowire by water-oxidized hydrogen ion implantation (United States)

    Zhou, Yong; Peng, Yuehua; Yin, Yanling; Zhou, Fang; Liu, Chang; Ling, Jing; Lei, Le; Zhou, Weichang; Tang, Dongsheng


    In a two-terminal Au/hexagonal WO3 nanowire/Au device, ions drifting or carriers self-trapping under external electrical field will modulate the Schottky barriers between the nanowire and electrodes, and then result in memristive effect. When there are water molecules adsorbed on the surface of WO3 nanowire, hydrogen ions will generate near the positively-charged electrode and transport in the condensed water film, which will enhance the memristive performance characterized by analogic resistive switching remarkably. When the bias voltage is swept repeatedly under high relative humidity level, hydrogen ions will accumulate on the surface and then implant into the lattice of the WO3 nanowire, which leads to a transition from semiconducting WO3 nanowire to metallic HxWO3 nanowire. This insulator-metal transition can be realized more easily after enough electron-hole pairs being excited by laser illumination. The concentration of hydrogen ions in HxWO3 nanowire will decrease when the device is exposed to oxygen atmosphere or the bias voltage is swept in atmosphere with low relative humidity. By modulating the concentration of hydrogen ions, conductive hydrogen tungsten bronze filament might form or rupture near electrodes when the polarity of applied voltage changes, which will endow the device with memristive performance characterized by digital resistive switching.

  6. WO3/TiO2 nanotube photoanodes for solar water splitting with simultaneous wastewater treatment.

    Energy Technology Data Exchange (ETDEWEB)

    Reyes, Karla Rosa; Robinson, David B.


    Nanostructured WO3/TiO2 nanotubes with properties that enhance solar photoconversion reactions were developed, characterized and tested. The TiO2 nanotubes were prepared by anodization of Ti foil, and WO3 was electrodeposited on top of the nanotubes. SEM images show that these materials have the same ordered structure as TiO2 nanotubes, with an external nanostructured WO3 layer. Diffuse reflectance spectra showed an increase in the visible absorption relative to bare TiO2 nanotubes, and in the UV absorption relative to bare WO3 films. Incident simulated solar photon-to-current efficiency increased from 30% (for bare WO3) to 50% (for WO3/TiO2 composites). With the addition of diverse organic pollutants, the photocurrent densities exhibited more than a 5-fold increase. Chemical oxygen demand measurements showed the simultaneous photodegradation of organic pollutants. The results of this work indicate that the unique structure and composition of these composite materials enhance the charge carrier transport and optical properties compared with the parent materials.

  7. Photoactivity enhancement of Zn-doped CdWO{sub 4} prepared with a hydrothermal method

    Energy Technology Data Exchange (ETDEWEB)

    Song, Xu Chun, E-mail: [Department of Chemistry, Fujian Normal University, Fuzhou 350007 (China); Cui, Xia [Department of Chemistry, Fujian Normal University, Fuzhou 350007 (China); Huang, Wan Zhen [Research Center of Analysis and Measurement, Zhejiang University of Technology, Hangzhou 310014 (China); Zhang, Yong [Hangzhou Area Military Representative Office, Hangzhou, 310011 (China); Yin, Hao Yong [Institute of Environmental Science and Engineering, Hangzhou Dianzi University, Hangzhou 310018 (China); Zheng, Yi Fan [Research Center of Analysis and Measurement, Zhejiang University of Technology, Hangzhou 310014 (China)


    Graphical abstract: - Highlights: • The zinc-doped CdWO{sub 4} photocatalyst was synthesized by a hydrothermal process. • The Zn-doped CdWO{sub 4} exhibited excellent photocatalytic efficiency. • Zinc effect on photocatalytic activity and photodegradation mechanism were investigated. - Abstract: The zinc-doped CdWO{sub 4} photocatalyst was successfully synthesized by a hydrothermal process. The influences of zinc doping on the phase structures, optical properties, morphologies and photocatalytic activities of the CdWO{sub 4} catalyst were investigated. The results showed that the zinc-doping can enhance the photocatalytic efficiency of CdWO{sub 4} with the highest activity obtained on the Zn-doped CdWO{sub 4} (Zn/Cd ratio of 0.1) for degradation of rhodamine B(RhB) under simulated solar light irradiation. The enhancement of photocatalytic activity may be attributed to the zinc doping which can change the band gap of the catalyst and subsequently inhibit the recombination of photogenerated electrons and holes.

  8. The Effect of Binarity and Metallicity in the Spectra of WC and WO Stars

    Directory of Open Access Journals (Sweden)

    L. Norci


    Full Text Available Se presenta el estudio estadístico de la intensidad (W, la relación y el ancho de algunas bandas de emisión de estrellas WC y WO, basado en un vasto conjunto de datos espectróscopicos. Se han obtenido valores medianos para cada tipo espectral. Se evidencia que en las estrellasWO yWC4 de la Galaxia, W(C IV 581 nm resulta ser menor que en estrellas extragalácticas. A su vez, el valor de W(O V 559 nm aumenta regularmente deWCL aWCE yWO, en las estrellas galácticas como en las extragalácticas. Suponemos que la variación de la estructura del viento estelar y de la metalicidad ambiental podrán ser la causa de las anomalías. El perfil de la banda a 465 nm evidencia, asimismo, que He II 468 nm es un componente importante en las clases WCE y WO. Se comenta también sobre las abundancias de carbono y el estado evolutivo de las estrellas WC y WO. De igual manera, se estima la relación de las intensidades del continuo OB/WR en estrellas binarias.

  9. Hydrogen sensing performance of WO3 thin film by using multi - wall carbon nanotubes

    Directory of Open Access Journals (Sweden)

    R. Ghasempour


    Full Text Available The WO3/MWNTs hybrid gas sensitive films were prepared by spin-coating on alumina substrate. The structure, morphology and chemical composition of the functionalized MWNTs and WO3/MWNTs hybrid films were studied by SEM, TEM, XRD, Raman, DLS and XPS methods. The MWCNT were initially functionalized (f-MWNTs. Dispersion and surface reactivity of MWNTs was improved because of oxygenate groups on MWNTs surface. Results showed WO3 nanoparticles were nucleated on oxygenated group on surface of f-MWNTs in hybrid suspension. After coating and annealing the films at 350 , the response of hybrid WO3/MWNTs films was measured. In addition, adding a little amount of MWNTs (the ratio of MWNTs/W less than 5/1000 wt% increased the hydrogen sensitivity so that the hybrid films showed an increase of 50 times compared to pure tungsten oxide layer in response to the 10000 ppm hydrogen concentration. Considering the results, the identification of these structures appear tobe 10 ppm hydrogen gas. With the addition of carbon nanotubes, the working temperature of pure tungsten oxide layers (400 reduced to 200 in hybrid layer. The gas sensitivity is suggested to have risendue to mainly the increase in the surface area as well as development of two types of depletion layers, one at the WO3/ MWNTs hetero junction and the other at WO3 grain boundaries.

  10. Highly sensitive and selective trimethylamine sensors based on WO3 nanorods decorated with Au nanoparticles (United States)

    Liu, Lu; Song, Peng; Yang, Zhongxi; Wang, Qi


    One-dimensional tungsten oxide (WO3) gas sensing materials have been widely used for the detection of trimethylamine (TMA) gas. Furthermore, it is believed that an effective method to improve the gas sensing performance is to introduce noble metals into sensing materials. In this work, a novel gas sensing material was prepared by decorating Au nanoparticles on WO3 nanorods. Based on field emission scanning electron microscopy (FESEM/EDS), X-ray diffraction (XRD), and transmission electron microscopy (TEM), the morphology and microstructure of as-prepared samples were characterized. Results show that Au nanoparticles with diameter of 13-15 nm are loaded on the surface of WO3 nanorods with length of about 1-2 μm and width of 50-80 nm. Gas sensing tests reveal that the Au@WO3 sensor has remarkably enhanced response to TMA gas compared with pure WO3 nanorods. In addition, and the gas sensing mechanism has been investigated based on the experimental results. The superior sensing features indicate the present Au@WO3 nanocomposites are promising for gas sensors, which can be used in the detection of the trimethylamine gas and this work provides insights and strategies for the fabrication of sensing materials.

  11. Tungsten-based nanomaterials (WO{sub 3} & Bi{sub 2}WO{sub 6}): Modifications related to charge carrier transfer mechanisms and photocatalytic applications

    Energy Technology Data Exchange (ETDEWEB)

    Girish Kumar, S., E-mail:; Koteswara Rao, K.S.R., E-mail:


    Graphical abstract: - Highlights: • Photocatalytic applications of WO{sub 3} and Bi{sub 2}WO{sub 6} based nanomaterial are reviewed. • Modifications to improve their performance are highlighted. • Charge carrier generation–separation–recombination is discussed. • Challenges and future prospects in this area are addressed. - Abstract: Heterogeneous photocatalysis is an ideal green energy technology for the purification of wastewater. Although titania dominates as the reference photocatalyst, its wide band gap is a bottleneck for extended utility. Thus, search for non-TiO{sub 2} based nanomaterials has become an active area of research in recent years. In this regard, visible light absorbing polycrystalline WO{sub 3} (2.4–2.8 eV) and Bi{sub 2}WO{sub 6} (2.8 eV) with versatile structure-electronic properties has gained considerable interest to promote the photocatalytic reactions. These materials are also explored in selective functional group transformation in organic reactions, because of low reduction and oxidation potential of WO{sub 3} CB and Bi{sub 2}WO{sub 6} VB, respectively. In this focused review, various strategies such as foreign ion doping, noble metal deposition and heterostructuring with other semiconductors designed for efficient photocatalysis is discussed. These modifications not only extend the optical response to longer wavelengths, but also prolong the life-time of the charge carriers and strengthen the photocatalyst stability. The changes in the surface-bulk properties and the charge carrier transfer dynamics associated with each modification correlating to the high activity are emphasized. The presence of oxidizing agents, surface modification with Cu{sup 2+} ions and synthesis of exposed facets to promote the degradation rate is highlighted. In depth study on these nanomaterials is likely to sustain interest in wastewater remediation and envisaged to signify in various green energy applications.

  12. Preparation, characterization and photocatalytic behavior of WO3-TiO2/Nb2O5 catalysts

    Institute of Scientific and Technical Information of China (English)


    TiO2/Nb2O5 photocatalyst loaded with WO3 (WO3-TiO2/Nb2O5) was prepared by a modified hydrolysis process, and characterized by X-ray diffractometry, transmission electron microscopy, Raman spectra and UV-Vis diffuse refraction spectroscopy.The photocatalytic activity of WO3-TiO2/Nb2O5 was investigated by employing splitting of water for O2 evolution. The results indicate that WO3 loading can pronouncedly improve the photocatalytic activity of TiO2/Nb2O5 by using Fe3+ as an electron acceptor under UV irradiation. The optimum molar fraction of the loaded WO3 is 2%, and the largest speed of O2 evolution for 2%WO3-TiO2/Nb2O5 catalyst is 151.8 μmol/(L·h).

  13. Improvement on the Luminescence Property of Y, Sb Co-doped PbWO4 Single Crystal

    Institute of Scientific and Technical Information of China (English)


    The effect of Y and Sb co-doping on the luminescence property of PbWO4 crystals has been investigated. Compared with undoped PbWO4, the transmittance and emission peak intensity of Y∶Sb∶PbWO4 crystals were obviously improved. In addition, its transmittance cutoff wavelength and emission peak shifted to the shorter one. The mechanism of effect of Y and Sb on the transmittance spectra was briefly discussed. The light yield of Y∶Sb∶PbWO4 crystals was 25p.e./MeV, which was two times of that of undoped PbWO4. Our experiments showed that Y and Sb co-doping was a selectable method to improve the luminescence property of PbWO4.

  14. 纳米WO3-ZnS系H2S气敏元件的研究%Study on H2S gas sensor of WO3-ZnS nanosized material

    Institute of Scientific and Technical Information of China (English)

    黄世震; 林伟; 陈伟; 陈知前


    The H2S gas sensor is made by nanosized WO3 doped with SnO2, ZnS. It shows that ZnS-WO3 gas sensor to H2S has high sensitivity and good selectivity.%以纳米WO3材料,分别掺入SnO2、ZnS,制备成H2S气敏元件。实验表明,当WO3掺入适量ZnS,元件对H2S气体具有较高的灵敏度及选择性。

  15. Pulsed differential pumping system

    Energy Technology Data Exchange (ETDEWEB)

    Antipov, G.N.; Bagautdinov, F.A.; Rybalov, S.V.


    A pulsed differential pumping system is described for extracting an electron beam from a shaping region at a pressure of 10/sup -5/ torr into a volume with a pressure of 10-100 torr. A fast valve is used with appropriate geometrical parameters to reduce the length of the outlet channel considerable while increasing its diameter. Test results are given. The pumping system has two sections which communicate one with the other and with the volume at the elevated pressure which is produced by gasdynamic nozzles.

  16. Heat pump planning handbook

    CERN Document Server

    Bonin, Jürgen


    The Heat Pump Planning Handbook contains practical information and guidance on the design, planning and selection of heat pump systems, allowing engineers, designers, architects and construction specialists to compare a number of different systems and options. Including detailed descriptions of components and their functions and reflecting the current state of technology this guide contains sample tasks and solutions as well as new model calculations and planning evaluations. Also economic factors and alternative energy sources are covered, which are essential at a time of rising heat costs. T

  17. Sorption product heat pump

    Energy Technology Data Exchange (ETDEWEB)

    Antonini, G.; Francois, O.; Gendarme, J.P.; Guilleminot, J.J.; Meunier, F.


    A continuous operating, and thus with enhanced performance, heat pump is presented. In this heat pump, the heat transfer between the hot source and the output system or network is realized through a solid adsorbent-refrigerant couple having endothermal desorption properties and exothermal adsorption or absorption properties. The sorption products are carried in a closed cycle movement between the two parts of the reactor. Each side of the reactor is assuming always the same function and the thermal inertia have to be overcome only when starting the reactor.

  18. Regenerative adsorbent heat pump (United States)

    Jones, Jack A. (Inventor)


    A regenerative adsorbent heat pump process and system is provided which can regenerate a high percentage of the sensible heat of the system and at least a portion of the heat of adsorption. A series of at least four compressors containing an adsorbent is provided. A large amount of heat is transferred from compressor to compressor so that heat is regenerated. The process and system are useful for air conditioning rooms, providing room heat in the winter or for hot water heating throughout the year, and, in general, for pumping heat from a lower temperature to a higher temperature.

  19. Geothermal Heat Pump Performance

    Energy Technology Data Exchange (ETDEWEB)

    Boyd, Tonya L.; Lienau, Paul J.


    Geothermal heat pump systems are a promising new energy technology that has shown rapid increase in usage over the past ten years in the United States. These systems offer substantial benefits to customers and utilities in energy (kWh) and demand (kW) savings. The purpose of this study was to determine what existing monitored data was available mainly from electric utilities on heat pump performance, energy savings and demand reduction for residential, school, and commercial building applications. Information was developed on the status of electric utility marketing programs, barriers to market penetration, incentive programs, and benefits.

  20. Geothermal heat pump performance

    Energy Technology Data Exchange (ETDEWEB)

    Boyd, Tonya L.; Lienau, Paul J.


    Geothermal heat pump systems are a promising new energy technology that has shown rapid increase in usage over the past ten years in the United States. These systems offer substantial benefits to customers and utilities in energy (kWh) and demand (kW) savings. The purpose of this study was to determine what existing monitored data was available mainly from electric utilities on heat pump performance, energy savings and demand reduction for residential, school, and commercial building applications. Information was developed on the status of electric utility marketing programs, barriers to market penetration, incentive programs, and benefits.

  1. Molecular heat pump. (United States)

    Segal, Dvira; Nitzan, Abraham


    We propose a molecular device that pumps heat against a thermal gradient. The system consists of a molecular element connecting two thermal reservoirs that are characterized by different spectral properties. The pumping action is achieved by applying an external force that periodically modulates molecular levels. This modulation affects periodic oscillations of the internal temperature of the molecule and the strength of its coupling to each reservoir resulting in a net heat flow in the desired direction. The heat flow is examined in the slow and fast modulation limits and for different modulation wave forms, thus making it possible to optimize the device performance.

  2. Template-Free Fabrication of Bi2WO6 Hierarchical Hollow Microspheres with Visible-Light-Driven Photocatalytic Activity

    Directory of Open Access Journals (Sweden)

    Yuxue Zhou


    Full Text Available Highly hierarchical hollow bismuth tungstate (Bi2WO6 microspheres self-assembled by thin nanoplates have been fabricated via a facile template-free solvothermal route. The possible growth pattern and formation mechanism of hierarchical hollow Bi2WO6 microspheres was investigated. The excellent visible-light-driven photocatalytic performance on rhodamine B (RhB degradation was displayed by hierarchical hollow Bi2WO6 microspheres. Such well-organized hierarchical hollow Bi2WO6 microspheres show potential application in water treatment fields by full use of solar energy.

  3. Inductive effect of poly(vinyl pyrrolidone) on morphology and photocatalytic performance of Bi2WO6 (United States)

    Zhang, Qiang; Chen, Jinxing; Xie, Yunyun; Wang, Mozhen; Ge, Xuewu


    Bi2WO6 has great potential applications in the field of photocatalyst due to its excellent visible-light photocatalytic performance. This work studied the detailed morphological evolution of Bi2WO6 particles synthesized in a simple hydrothermal system induced by the stabilizer poly(vinyl pyrrolidone) (PVP). The XRD and HRTEM results show PVP would not change the crystal structure of Bi2WO6, but the distribution of PVP on the initially formed Bi2WO6 nanosheets will induce the crystal growth, resulting in a distinct morphology evolution of Bi2WO6 with the increase of the concentration of PVP. At the same time, with the increase of the molecular weight of PVP, the morphology of Bi2WO6 varied from simple sheet-like (S-BWO) to some complicated morphology, such as flower-like (F-BWO), red blood cell-like (B-BWO), and square-pillar-like (SP-BWO). The photocatalytic performances of Bi2WO6 with various morphologies on the decomposition of RhB under visible light irradiation reveal that S-BWO has the best photocatalytic performance, while SP-BWO has the worst. This work not only gives the explanation of the inductive effect of PVP molecular chains on the morphological formation of Bi2WO6 particles, but also provides the controllable way to the preparation of Bi2WO6 with various morphologies taking advantage of the stabilizer PVP.

  4. Pressurized Vessel Slurry Pumping

    Energy Technology Data Exchange (ETDEWEB)

    Pound, C.R.


    This report summarizes testing of an alternate ''pressurized vessel slurry pumping'' apparatus. The principle is similar to rural domestic water systems and ''acid eggs'' used in chemical laboratories in that material is extruded by displacement with compressed air.

  5. Microfluidic "blinking" bubble pump

    NARCIS (Netherlands)

    Yin, Zhizhong; Prosperetti, Andrea


    The paper reports data obtained on a simple micropump, suitable for electrolytes, based on the periodic growth and collapse of a single vapor bubble in a microchannel. With a channel diameter of the order of 100 µm, pumping rates of several tens of µl/min and pressure differences of several kPa are

  6. Cold Climate Heat Pump (United States)


    12. Data set 7 – energy consumption of heat pump and furnace ................................ 22 Figure 13. Experimentally adjusted TRNSYS model...minute SCF standard cubic feet SEER seasonal energy efficiency ratio SH superheated TMY Typical Meteorological Year TRNSYS Transient Systems...Simulation Program ( TRNSYS ), to generate an experimentally adjusted, simulation heating seasonal performance. 6.4.1 Simulation Results The TRNSYS model

  7. The Osmotic Pump (United States)

    Levenspiel, Octave; de Nevers, Noel


    Describes the principle involved in an osmotic pump used to extract fresh water from the oceans and in an osmotic power plant used to generate electricity. Although shown to be thermodynamically feasible, the osmotic principle is not likely to be used commerically for these purposes in the near future. (JR)

  8. Optimization of compound gear pump

    Institute of Scientific and Technical Information of China (English)



    This paper introduces the performances of compound gear pump. Based on the target of having the smallest mass per unit volume, the paper established a mathematical model of optimization, and obtained the results of optimization of the pump.

  9. RSES heat pump technician certification

    Energy Technology Data Exchange (ETDEWEB)

    Zeiner, J.


    In 1987 the National Heat Pump certification test was developed by the Refrigeration Service Engineers Society (RSES), and in 1994, the program was more specifically named Heat Pump Service Technician Certification. This report describes the benefits of certification.

  10. Orbital Liquid Oxygen Pump Project (United States)

    National Aeronautics and Space Administration — This proposed work will develop a pump, which is based on two novel and unique design features. The first feature is a lobed pumping mechanism which operates with...

  11. Synthesis of WO 3 nanoparticles for superthermites by the template method from silica spheres (United States)

    Gibot, Pierre; Comet, Marc; Vidal, Loic; Moitrier, Florence; Lacroix, Fabrice; Suma, Yves; Schnell, Fabien; Spitzer, Denis


    Nanosized WO 3 tungsten trioxide was prepared by calcination of H 3P 4W 12O 40· xH 2O phosphotungstic acid, previously dissolved in a silica colloidal solution. The influence of the silica spheres/tungsten precursor weight ratio ( x) was investigated. The pristine oxide powders were characterized by XRD, nitrogen adsorption, SEM and TEM techniques. A specific surface area and a pore volume of 64.2 m 2 g -1 and 0.33 cm 3 g -1, respectively, were obtained for the well-crystallized WO 3 powder prepared with x = 2/3 and after the removal of the silica template. The WO 3 particles exhibit a sphere-shaped morphology with a particle size of 13 and 320 nm as function of the x ratio. The performance and the sensitivity levels of the thermites prepared from aluminium nanoparticles mixed with (i) the smallest tungsten (VI) oxide material and (ii) the microscale WO 3 were compared. The combustion of these energetic composites was investigated by time resolved cinematography (TRC). This unconventional experimental technique consists to ignite the dried compressed composites by using a CO 2 laser beam, in order to determine their ignition delay time (IDT) and their combustion rate. The downsizing WO 3 particles improves, without ambiguity, the energetic performances of the WO 3/Al thermite. For instance, the ignition delay time was greatly shortened from 54 ± 10 ms to 5.7 ± 0.2 ms and the combustion velocity was increased by a factor 50 to reach a value of 4.1 ± 0.3 m/s. In addition, the use of WO 3 nanoparticles sensitizes the mixture to mechanical stimuli but decreases the sensitivity to electrostatic discharge.

  12. Structural evolution, growth mechanism and photoluminescence properties of CuWO4 nanocrystals. (United States)

    Souza, E L S; Sczancoski, J C; Nogueira, I C; Almeida, M A P; Orlandi, M O; Li, M S; Luz, R A S; Filho, M G R; Longo, E; Cavalcante, L S


    Copper tungstate (CuWO4) crystals were synthesized by the sonochemistry (SC) method, and then, heat treated in a conventional furnace at different temperatures for 1h. The structural evolution, growth mechanism and photoluminescence (PL) properties of these crystals were thoroughly investigated. X-ray diffraction patterns, micro-Raman spectra and Fourier transformed infrared spectra indicated that crystals heat treated and 100°C and 200°C have water molecules in their lattice (copper tungstate dihydrate (CuWO4·2H2O) with monoclinic structure), when the crystals are calcinated at 300°C have the presence of two phase (CuWO4·2H2O and CuWO4), while the others heat treated at 400°C and 500°C have a single CuWO4 triclinic structure. Field emission scanning electron microscopy revealed a change in the morphological features of these crystals with the increase of the heat treatment temperature. Transmission electron microscopy (TEM), high resolution-TEM images and selected area electron diffraction were employed to examine the shape, size and structure of these crystals. Ultraviolet-Visible spectra evidenced a decrease of band gap values with the increase of the temperature, which were correlated with the reduction of intermediary energy levels within the band gap. The intense photoluminescence (PL) emission was detected for the sample heat treat at 300°C for 1h, which have a mixture of CuWO4·2H2O and CuWO4 phases. Therefore, there is a synergic effect between the intermediary energy levels arising from these two phases during the electronic transitions responsible for PL emissions. Copyright © 2017 Elsevier B.V. All rights reserved.


    Institute of Scientific and Technical Information of China (English)


    Some concepts of virtual product are discussed. The key technologies of virtual fuel-pump development are in detail analysed, which include virtual fuel-pump product modeling, intelligent simulation, distributed design environment, and virtual assembly. The virtual fuel-pump development prototype system considers requirement analysis, concept design, injection preferment analysis, detailed design, and assembly analysis.

  14. Small Scroll Pump for Cryogenic Liquids Project (United States)

    National Aeronautics and Space Administration — The innovation is a compact, reliable, light weight, electrically driven pump capable of pumping cryogenic liquids, based on scroll pump technology. This pump will...

  15. Improving pumping system efficiency at coal plants

    Energy Technology Data Exchange (ETDEWEB)

    Livoti, W.C.; McCandless, S.; Poltorak, R. [Baldor Electric Co. (United States)


    The industry must employ ultramodern technologies when building or upgrading power plant pumping systems thereby using fuels more efficiently. The article discusses the uses and efficiencies of positive displacement pumps, centrifugal pumps and multiple screw pumps. 1 ref., 4 figs.

  16. Structural, vibrational and luminescence properties of the (1−x)CaWO{sub 4}−xCdWO{sub 4} system

    Energy Technology Data Exchange (ETDEWEB)

    Taoufyq, A. [Institut Matériaux Microélectronique et Nanosciences de Provence, Aix Marseille Université, CNRS, Université de Toulon, IM2NP UMR 7334, 83957, La Garde (France); Laboratoire Matériaux et Environnement LME, Faculté des Sciences, Université Ibn Zohr, BP 8106, Cité Dakhla, Agadir, Maroc (Morocco); CEA/DEN, Département d’Études des Réacteurs, Laboratoire Dosimétrie Capteurs Instrumentation, CEA Cadarache, 13108, Saint-Paul-lez-Durance (France); Société CESIGMA, Signals and Systems, 1576 Chemin de La Planquette, 83130 La Garde (France); Guinneton, F.; Valmalette, J-C.; Arab, M. [Institut Matériaux Microélectronique et Nanosciences de Provence, Aix Marseille Université, CNRS, Université de Toulon, IM2NP UMR 7334, 83957, La Garde (France); Benlhachemi, A.; Bakiz, B. [Laboratoire Matériaux et Environnement LME, Faculté des Sciences, Université Ibn Zohr, BP 8106, Cité Dakhla, Agadir, Maroc (Morocco); Villain, S. [Institut Matériaux Microélectronique et Nanosciences de Provence, Aix Marseille Université, CNRS, Université de Toulon, IM2NP UMR 7334, 83957, La Garde (France); and others


    In the present work, we investigate the structural, microstructural, vibrational and luminescence properties of the system (1−x)CaWO{sub 4}−xCdWO{sub 4} with x ranging between 0 and 1. Polycrystalline samples were elaborated using a coprecipitation technique followed by thermal treatment at 1000 °C. The samples were then characterized using X-ray diffraction, scanning electron microscopy, Raman spectroscopy and luminescence analyses. X-ray diffraction profile analyses using Rietveld method showed that two kinds of solid solutions Ca{sub 1−x}Cd{sub x}WO{sub 4} having scheelite and wolframite structures, with respectively tetragonal and monoclinic crystal cells, were observed, with a biphasic system for compositions x=0.6 and 0.7. The scanning electron microscopy experiments showed a complex evolution of morphologies and crystallite sizes as x increased. The vibration modes of Raman spectra were characteristic of composition-dependent disordered solid solutions with decreasing wavenumbers as x increased. Luminescence experiments were performed under UV-laser light irradiation. The energies of emission bands increased linearly with cadmium composition x. The integrated intensity of luminescence reached a maximum value for the substituted wolframite phase with composition x=0.8. - Graphical abstract: Luminescence on UV excitation (364.5 nm) of (1−x)CaWO{sub 4−x}CdWO{sub 4} system, elaborated from coprecipitation technique at 1000 °C, with 0WO{sub 4} polycrystalline phases with 0≤x≤0.5. (b) Maximum of luminescence intensity for the composition x=0.8. - Highlights: • Solid solutions Ca{sub 1−x}Cd{sub x}WO{sub 4} are elaborated from coprecipitation technique. • The structures of two types of solid solutions are refined using Rietveld method. • A maximum of luminescence is obtained for an intermediate composition x=0.8.

  17. Pumping characteristics of roots blower pumps for light element gases

    Energy Technology Data Exchange (ETDEWEB)

    Hiroki, Seiji; Abe, Tetsuya; Tanzawa, Sadamitsu; Nakamura, Jun-ichi; Ohbayashi, Tetsuro [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment


    The pumping speed and compression ratio of the two-stage roots blower pumping system were measured for light element gases (H{sub 2}, D{sub 2} and He) and for N{sub 2}, in order to assess validity of the ITER torus roughing system as an ITER R and D task (T234). The pumping system of an Edwards EH1200 (nominal pumping speed of 1200 m{sup 3}/s), two EH250s (ibid. 250 m{sup 3}/s) and a backing pump (ibid. 100 m{sup 3}/s) in series connection was tested under PNEUROP standards. The maximum pumping speeds of the two-stage system for D{sub 2} and N{sub 2} were 1200 and 1300 m{sup 3}/h, respectively at 60 Hz, which satisfied the nominal pumping speed. These experimental data support the design validity of the ITER torus roughing system. (author)

  18. Synthesis and characterization of MnWO4 nanoparticles encapsulated in mesoporous silica SBA-15 by fast microwave-assisted method (United States)

    Hoang, Luc Huy; Hanh, Pham Van; Phu, Nguyen Dang; Chen, Xiang-Bai; Chou, Wu Ching


    The MnWO4 nanoparticles encapsulated in mesoporous silica (MnWO4/SBA-15) was successfully synthesized by a fast microwave-assisted method. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), nitrogen absorption-desorption isotherm, and Fourier transform infrared spectroscopy (FTIR). Our results showed that the MnWO4/SBA-15 nanocomposites have the ordered hexagonal meso-structure of SBA-15, indicating MnWO4 nanoparticles were successfully distributed into the channels of SBA-15. The size of MnWO4 nanoparticles in SBA-15 is significantly smaller than the size of MnWO4 nanoparticles prepared without SBA-15, indicating that the MnWO4/SBA15 nanocomposites would be very promising for improving photocatalytic activity of MnWO4 nanoparticles.

  19. SHINE Vacuum Pump Test Verification

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, Gregg A; Peters, Brent


    Normetex pumps used world-wide for tritium service are no longer available. DOE and other researchers worldwide have spent significant funds characterizing this pump. Identification of alternate pumps is required for performance and compatibility with tritium gas. Many of the pumps that could be used to meet the functional performance requirements (e.g. pressure and flow conditions) of the Normetex pump have features that include the use of polymers or oils and greases that are not directly compatible with tritium service. This study assembles a test system to determine the flow characteristics for candidate alternate pumps. These tests are critical to the movement of tritium through the SHINE Tritium Purification System (TPS). The purpose of the pump testing is two-fold: (1) obtain baseline vacuum pump characteristics for an alternate (i.e. ''Normetex replacement'') pump intended for use in tritium service; and (2) verify that low pressure hydrogen gas can be transported over distances up to 300 feet by the candidate pumps. Flow rates and nominal system pressures have been identified for the SHINE Mo-99 production process Tritium Purification System (TPS). To minimize the line sizes for the transfer of low pressure tritium from the Neutron Driver Accelerator System (NDAS) to the primary processing systems in the TPS, a ''booster'' pump has been located near the accelerator in the design. A series of pump tests were performed at various configurations using hydrogen gas (no tritium) to ensure that this concept is practical and maintains adequate flow rates and required pressures. This report summarizes the results of the tests that have been performed using various pump configurations. The current design of the Tritium Purification System requires the ''booster'' pump to discharge to or to be backed by another vacuum pump. Since Normetex pumps are no longer manufactured, a commercially available Edwards

  20. Ethylene Separation via Hydrate Formation in W/O Emulsions

    Directory of Open Access Journals (Sweden)

    Yong Pan


    Full Text Available An hybrid absorption-hydration method was adopted to recover C2H4 from C2H4/CH4 binary gas mixtures and the hydrate formation conditions of C2H4/CH4 mixtures was studied experimentally in diesel in water (w/o emulsions. Span 20 at a concentration of 1.0 wt% in the aqueous phase was added to form water in diesel emulsions before hydrate formation and then hydrate in diesel slurry was separated after hydrate formation. The influences of initial gas-liquid volume ratio (53–142, pressure (3.4–5.4 MPa, temperature (274.15–278.15 K, water cuts (10–30 vol%, and the mole fraction of C2H4 in feed gas (13.19–80.44 mol% upon the C2H4 separation efficiency were systematically investigated. The experimental results show that ethylene can be enriched in hydrate slurry phase with high separation factor (S and recovery ratio (R. Most hydrate formation finished in 20 min, after that, the hydrate formation rate became very slow. The conclusion is useful for determining the suitable operation conditions when adopting an absorption-hydration method to separate C2H4/CH4.

  1. CdWO4 bolometers for Double Beta Decay search

    CERN Document Server

    Gironi, L; Capelli, S; Cremonesi, O; Pavan, M; Pessina, G; Pirro, S


    In the field of Double Beta Decay (DBD) searches the possibility to have high resolution detectors in which background can be discriminated is very appealing. This very interesting possibility can be largely fulfilled in the case of a scintillating bolometer containing a Double Beta Decay emitter whose transition energy exceeds the one of the natural gamma line of 208Tl. We present the latest results obtained in the development of such a kind of scintillating bolometer. For the first time an array of five CdWO4 (116Cd has a Double Beta Decay transition energy of 2805 keV) crystals is tested. The array consists of a plane of four 3x3x3 cm3 crystals and a second plane consisting of a single 3x3x6 cm3 crystal. This setup is mounted in hall C of the National Laboratory of Gran Sasso inside a lead shielding in order to reduce as far as possible the environmental background. The aim of this test is to demonstrate the technical feasibility of this technique through an array of detectors and perform a long background...

  2. Chromic mechanism in amorphous WO{sub 3} films

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, J G; Benson, D K; Tracy, C E; Deb, S K; Czanderna, A W [National Renewable Energy Lab., Golden, CO (United States); Bechinger, C [Universitaet Konstanz (Germany)


    The authors propose a new model for the chromic mechanism in amorphous tungsten oxide films (WO{sub 3{minus}y}{center_dot}nH{sub 2}O). This model not only explains a variety of seemingly conflicting experimental results reported in the literature that cannot be explained by existing models, it also has practical implications with respect to improving the coloring efficiency and durability of electrochromic devices. According to this model, a typical as-deposited tungsten oxide film has tungsten mainly in W{sup 6+} and W{sup 4+} states and can be represented as W{sub 1{minus}y}{sup 6+} W{sub y}{sup 4+}O{sub 3{minus}y}{center_dot}nH{sub 2}O. The proposed chromic mechanism is based on the small polaron transition between the charge-induced W{sup 5+} state and the original W{sup 4+} state instead of the W{sup 5+} and W{sup 6+} states as suggested in previous models. The correlation between the electrochromic and photochromic behavior in amorphous tungsten oxide films is also discussed.

  3. 14 CFR 23.991 - Fuel pumps. (United States)


    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Fuel pumps. 23.991 Section 23.991... § 23.991 Fuel pumps. (a) Main pumps. For main pumps, the following apply: (1) For reciprocating engine installations having fuel pumps to supply fuel to the engine, at least one pump for each engine must be...

  4. TiO2(B) nanoparticle-functionalized WO3 nanorods with enhanced gas sensing properties. (United States)

    Zhang, Hongxin; Wang, Shurong; Wang, Yanshuang; Yang, Jiedi; Gao, Xueling; Wang, Liwei


    In this work, TiO2(B) nanoparticle (NP)-functionalized WO3 nanorods (NRs) were synthesized by a two-step solution strategy, with a hydrothermal process for WO3 NRs and hydrolyzation of Ti(OBu)4 for the functionalization of TiO2(B) NPs. Various techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), were employed to investigate the morphology, microstructure, crystalline nature and chemical composition of the prepared TiO2(B) NP-functionalized WO3 NRs. SEM and TEM results revealed that the TiO2(B)-WO3 composite showed a rod-like nanostructure with a diameter in the range from 93 to 154 nm and a rough surface, which could increase the accessible surface area and the amount of surface active sites, thus improving the properties or performance of the as-prepared composite NRs. XRD and XPS analysis clearly verified that monoclinic TiO2(B) NPs, a metastable polymorph of TiO2, were successfully supported on the WO3 NRs. Gas sensing measurement results for several common reductive organic gases such as acetone, ethanol, ether, methanol and formaldehyde demonstrated that the sensor based on the as-obtained TiO2(B) NP-functionalized WO3 NRs exhibited obviously enhanced responses compared with a pure WO3 NR based sensor, as well as fast response-recovery speeds, good reproducibility and good stability, indicating their promising application in gas sensors. The excellent gas sensing performance could be attributed to the unique 1D rod-like nanostructure with a rough surface, the existence of TiO2-WO3 heterojunctions and the catalytic effect of the TiO2(B) NPs. The as-prepared TiO2(B) NP-functionalized WO3 NRs will also have very good prospects in electrochromic devices and catalysis applications.

  5. Study on Preparation and Photochromism of WO3-TiO2-ZnO Colloid%WO3-TiO2-ZnO溶胶的制备及其光致变色性能研究

    Institute of Scientific and Technical Information of China (English)

    陈伟龙; 沈鸿烈; 王威; 李金泽


    采用溶胶-凝胶法分别制备了WO3,TiO2和ZnO溶胶,在此基础上以一定比例混合后形成WO3-TiO2-ZnO和WO3-TiO2溶胶.利用透射电镜和紫外-可见分光光度计对其进行了表征.结果表明,WO3-TiO2-ZnO溶胶粒子尺寸分布在10~25 nm范围,WO3-TiO2-ZnO溶胶比WO3溶胶和WO3-TiO2溶胶具有更好的光致变色性能.用500 w汞灯照射80s后,WO3-TiO2-ZnO溶胶由无色变为蓝色,变色后的溶胶在无光照6h左右后由蓝色恢复到无色,具有很好的光致变色行为的可逆性.

  6. Gold clusters on WO{sub 3} nanoneedles grown via AACVD: XPS and TEM studies

    Energy Technology Data Exchange (ETDEWEB)

    Navio, Cristina [Laboratory of Interaction Chemistry on Plasma Surfaces, University of Mons (Belgium); Vallejos, Stella [MINOS, EMaS, Departament d' Enginyeria Electronica, Universitat Rovira i Virgili, Tarragona (Spain); Department of Chemistry, University College London, London, WC1H 0AJ (United Kingdom); Stoycheva, Toni; Llobet, Eduard; Correig, Xavier [MINOS, EMaS, Departament d' Enginyeria Electronica, Universitat Rovira i Virgili, Tarragona (Spain); Snyders, Rony [Laboratory of Interaction Chemistry on Plasma Surfaces, University of Mons (Belgium); Blackman, Christopher [Department of Chemistry, University College London, London, WC1H 0AJ (United Kingdom); Umek, Polona [Solid State Physcis Department Jozef Stefan Institute, Jamov cesta 39, 1000 Ljubljana (Slovenia); Ke Xiaoxing; Van Tendeloo, Gustaaf [Electron Microscopy for Material Science, University of Antwerp, Antwerp (Belgium); Bittencourt, Carla, E-mail: [Electron Microscopy for Material Science, University of Antwerp, Antwerp (Belgium)


    We have prepared tungsten oxide films decorated with gold particles on Si substrates by aerosol assisted chemical vapor deposition (AACVD) and characterized them using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). SEM shows that the films are composed of needle-like structures and TEM shows that both the needles and the gold particles are crystalline. XPS indicates the presence of oxygen vacancies, i.e. the films are WO{sub 3-x}, and hence the deposited material is composed of semiconducting nanostructures and that the interaction between the gold particles and the WO{sub 3} needles surface is weak. The synthesis of semiconducting tungsten oxide nanostructures decorated with metal particles represents an important step towards the development of sensing devices with optimal properties. - Highlights: Black-Right-Pointing-Pointer Characterization of WO{sub 3} needle-like structures decorated with gold nanoparticles. Black-Right-Pointing-Pointer WO{sub 3} needle-like structures are crystalline. Black-Right-Pointing-Pointer WO{sub 3} needle-like structures are semiconducting.

  7. Preparation and physical properties of Cu{sub x}WO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Koriche, N. [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, U.S.T.H.B., BP 32, 16111 El-Alia, Algiers (Algeria); Bessekhouad, Y., E-mail: [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, U.S.T.H.B., BP 32, 16111 El-Alia, Algiers (Algeria); National Veterinary School, BP 161-El Harrach, Algiers (Algeria); Bouguelia, A.; Trari, M. [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, U.S.T.H.B., BP 32, 16111 El-Alia, Algiers (Algeria)


    We report on the study of WO{sub 3} doped with Cu using sol-gel (Cu{sub x}WO{sub 3}{sup d}) and impregnation (Cu{sub x}WO{sub 3}{sup i}) methods. All materials are well crystallized and exhibit single phases whose crystallite size ranges from 17 to 100 nm depending on Cu amount and the preparation technique. The conductivity dependence on temperature demonstrates semiconductor behavior and follows the Arrhenius model, with activation energies, E{sub {sigma}}, commonly in the range 0.4-0.6 eV. Moreover, the thermopower study shows that Cu{sub x}WO{sub 3}{sup d} is mainly of p-type conductivity, whereas Cu{sub x}WO{sub 3}{sup i} is n-type. The mechanism of conduction is attributed to a small polaron hopping. The doping process is found to decrease the interband transition down to 520 nm depending on the preparation conditions. The photoelectrochemical characterization confirms the conductivity type and demonstrates that the photocurrent J{sub ph} increases with Cu-doping. Taking into consideration the activation energy, the flat band potential and the band gap energy, the band positions of each material are proposed according to the preparation method and Cu amount.

  8. Non-stoichiometry Defects and Radiation Hardness of Lead Tungstate Crystals PbWO4

    CERN Document Server

    Devitsin, E G; Kozlov, V A; Nefedov, L; Polyansky, E V; Potashov, S Yu; Terkulov, A R; Zadneprovski, B I


    It has been stated many times that the formation of radiation infringements in PbWO4 is to big extent stipulated by non-stoichiometry defects of the crystals, arising in the process of their growth and annealing. To refine the idea of characteristics of non-stoichiometry defects and their effect on the radiation hardness of PbWO4 the current study is aimed at the melt composition infringements during its evaporation and at optical transmission of crystals obtained in these conditions after their irradiation (137Cs source). In the optical transmission measurements along with traditional techniques a method "in situ" was used, which provided the measurements in fixed points of the spectrum (380, 470 and 535 nm) directly in the process of the irradiation. X-ray phase and fluorescence analysis of condensation products of vapours over PbWO4 melt has found PbWO4 phase in their content as well as compounds rich in lead, PbO, Pb2WO5, with overall ratio Pb/W = 3.2. Correspondingly the lack of lead and variations in th...

  9. Production of CaWO{sub 4} crystals for direct dark matter search with CRESST

    Energy Technology Data Exchange (ETDEWEB)

    Muenster, Andrea [Physik-Department and Excellence Cluster Universe, Technische Universitaet Muenchen, D-85748 Garching (Germany); Collaboration: CRESST-Collaboration


    The direct dark matter search experiment CRESST (Cryogenic Rare Event Search with Superconducting Thermometers) uses scintillating CaWO{sub 4} single crystals as targets for possible recoils of dark matter particles. Since several years these CaWO{sub 4} crystals are produced directly at the Technische Universitaet Muenchen (TUM) including the CaWO{sub 4} powder production from the raw materials CaCO{sub 3} and WO{sub 3}, the CaWO{sub 4} crystal growth via the Czochralski method as well as the after-growth treatment of the crystals. In the recently finished CRESST-II Phase 2 (2013-2015), 4 TUM-grown crystals were installed in the main cryostat for the first time. Showing one of the best radiopurities of all installed crystals combined with an excellent detector performance the analysis of the crystal TUM40 resulted in the best sensitivity for low-mass dark matter particles in 2014. For the upcoming CRESST-III phase 2 we aim for a further improvement in radiopurity by a factor of 100. First results of a chemical purification of the raw materials as well as future plans to reduce the intrinsic background via recrystallization are presented.

  10. The Facile Hydrothermal Preparation of Orthorhombic WO3 With (001) Facet and Its Photocatalytic Performance. (United States)

    Deng, Xiaoyan; Dou, Jinbiao; Li, Fenfen; Gao, Hongtao; Liu, Guangjun


    The orthorhombic WO3 nanoplates with (001) facet were fabricated via a facile hydrothermal process, using HBF4 as the acid source. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM) and UV-vis diffused reflectance spectroscopy (DRS), respectively. It indicated that the obtained product was orthorhombic WO3 (JCPDS No. 20-1324). And the energy gap was estimated to be 2.52 eV by the intersection point of the tangent of the absorption edge and the baseline. It was affirmed that WO3 crystalline grew along the (001) direction, indicating the product was exposed with (001) facet. The photocatalytic activity of (001) WO3 nanoplates was investigated on the degradation of Rhodamine B (RhB). It demonstrated that photocatalysts exhibited obvious photocatalytic performance under visible light irradiation. The degradation rate of RhB with the typical product reached 95% after being irradiated for 5 h. It indicated that the photocatalytic efficiency of WO3 could be improved by controlling the crystal growth and its morphology.

  11. Synthesis of ZnWO4 Electrode with tailored facets: Deactivating the Microorganisms through Photoelectrocatalytic methods (United States)

    Zhan, Su; Zhou, Feng; Huang, Naibao; Liu, Yujun; He, Qiuchen; Tian, Yu; Yang, Yifan; Ye, Fei


    The exotic invasive species from the ballast water in the ship will bring about serious damages to ecosystem. Photocatalyst films have been widely studied for sterilization. In this study, ZnWO4 with different exposed facets was synthesized by hydrothermal method, and ZnWO4 film electrodes have been applied in ballast water treatment through the electro-assisted photocatalytic system. Then the samples were investigated by X-ray diffraction (XRD), X-ray photo-electron spectroscopy (XPS), Field emission on scanning electron microcopy (FE-SEM), Transmission electron microscopy (TEM), UV-vis diffuse reflectance spectroscopy (DRS), BET specific surface area analysis, Fourier transform infrared (FT-IR) and Electrochemical impedance spectra (EIS). ZnWO4 with an appropriate exposure of (0 1 1) facets ratio exhibited the best photocatalytic and photoelectrocatalytic activities. The microorganisms deactivated completely in 10 min by ZnWO4 films with 3 V bias. The mechanisms of (0 1 1) facets enhanced the photocatalytic and photoelectrocatalytic activities which were deduced based on the calculated result from the first principles. Simultaneously, appropriate exposed facets and applied bias could reduce the recombination of the photogenerated electron-hole pairs, and improve the photocatalytic activities of ZnWO4.

  12. Fabrication of ZnWO{sub 4} nanofibers by a high direct voltage electrospinning process

    Energy Technology Data Exchange (ETDEWEB)

    Keereeta, Yanee [Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thongtem, Titipun, E-mail: [Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thongtem, Somchai [Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand)


    Highlights: > ZnWO{sub 4} nanofibers as one of semiconducting materials. > A lab-made electrospinning equipment enables to form fibrous precursors. > Upon calcination the precursors above 500 deg. C, ZnWO{sub 4} nanofibers are produced. > The promising nanofibers for photoluminescence devices and solar cells. - Abstract: Mixtures of zinc acetate dihydrate, ammonium metatungstate hydrate, and 5 wt%, 6 wt%, and 7 wt% of poly (vinyl alcohol) (PVA) were electrospun by a +15 kV direct voltage to produce fibers. In the present research, the electrospun fibers of 6 wt% PVA were further calcined at 400-600 deg. C for 3 h. The sanmartinite monoclinic structured ZnWO{sub 4} was detected by X-ray diffractometer (XRD) and selected area electron diffraction (SAED), weight loss by thermogravimetric analyser (TGA), morphology and particle size by scanning and transmission electron microscopes (SEM, TEM) and atomic force microscope (AFM), including their vibration modes by Fourier transform infrared spectrometer (FTIR) and Raman spectrometer. The 4.42 eV direct energy gap (E{sub g}) and 460 nm emission wavelength, caused by the electronic transition of (WO{sub 6}){sup 2-} octahedrons, were determined by UV-visible absorption and photoluminescence (PL) spectrometers. A possible formation mechanism of ZnWO{sub 4} nanofibers was also proposed according to the experimental results.

  13. Non-stoichiometry defects and radiation hardness of lead tungstate crystals PbWO sub 4

    CERN Document Server

    Devitsin, E G; Potashov, S Yu; Terkulov, A R; Nefedov, V A; Polyansky, E V; Zadneprovski, B I; Kjellberg, P; Korbel, V


    It has been stated many times that the formation of radiation infringements in PbWO sub 4 is to a big extent stipulated by the non-stoichiometry defects of the crystals, arising in the process of their growth and annealing. To refine the idea of characteristics of the non-stoichiometry defects and their effect on the radiation hardness of PbWO sub 4 , the current study is aimed at the melt composition infringements during its evaporation and at optical transmission of crystals obtained in these conditions after their irradiation ( sup 1 sup 3 sup 7 Cs source). In the optical transmission measurements along with traditional techniques a method 'in situ' was used, which provided the measurements in fixed points of the spectrum (380, 470 and 535 nm) directly in the process of the irradiation. X-ray phase and fluorescence analysis of condensation products of vapours over PbWO sub 4 melt has found PbWO sub 4 phase in their content as well as compounds rich in lead PbO, Pb sub 2 WO sub 5 with overall ratio Pb/W (3....

  14. Facile synthesis of decorated graphene oxide sheets with WO{sub 3} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Adineh, Ensieh; Rasuli, Reza [University of Zanjan, Department of Physics, Faculty of Science, P.O. Box 45371-38791, Zanjan (Iran, Islamic Republic of)


    Potential applications of graphene oxide (GO) nanocomposites have attracted remarkable attention to modify its properties by functionalizing and decorating with nanoparticles. In this work, after synthesis of GO sheets by oxidation and exfoliation of natural graphite, they were decorated with tungsten oxide nanoparticles using arc discharge in GO solution. Transmission electron microscopy shows that the chain of WO{sub 3} nanoparticles decorates the GO sheets. Fourier transform infrared spectroscopy and Raman spectroscopy show that WO{sub 3} nanoparticles are attached to GO sheets by bond formation between the tungsten and oxygen of functional groups, especially with epoxides on the GO sheets. Nanocomposite production in different arc currents shows that the greater the electrical current, the stronger the bond is formed between WO{sub 3} and GO. X-ray diffraction confirms that the WO{sub 3} nanoparticles on the GO are highly crystalline in monoclinic phase. Moreover, by increasing the arc current from 20 to 40 A, the band gap energy of GO + WO{sub 3} decreases to ∝2.6 eV. (orig.)

  15. Pocket pumped image analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kotov, I.V., E-mail: [Brookhaven National Laboratory, Upton, NY 11973 (United States); O' Connor, P. [Brookhaven National Laboratory, Upton, NY 11973 (United States); Murray, N. [Centre for Electronic Imaging, Open University, Milton Keynes, MK7 6AA (United Kingdom)


    The pocket pumping technique is used to detect small electron trap sites. These traps, if present, degrade CCD charge transfer efficiency. To reveal traps in the active area, a CCD is illuminated with a flat field and, before image is read out, accumulated charges are moved back and forth number of times in parallel direction. As charges are moved over a trap, an electron is removed from the original pocket and re-emitted in the following pocket. As process repeats one pocket gets depleted and the neighboring pocket gets excess of charges. As a result a “dipole” signal appears on the otherwise flat background level. The amplitude of the dipole signal depends on the trap pumping efficiency. This paper is focused on trap identification technique and particularly on new methods developed for this purpose. The sensor with bad segments was deliberately chosen for algorithms development and to demonstrate sensitivity and power of new methods in uncovering sensor defects.

  16. Wavy tube heat pumping

    Energy Technology Data Exchange (ETDEWEB)

    Haldeman, C. W.


    A PVC conduit about 4'' in diameter and a little more than 40 feet long is adapted for being seated in a hole in the earth and surrounds a coaxial copper tube along its length that carries Freon between a heat pump and a distributor at the bottom. A number of wavy conducting tubes located between the central conducting tube and the wall of the conduit interconnect the distributor with a Freon distributor at the top arranged for connection to the heat pump. The wavy conducting tubing is made by passing straight soft copper tubing between a pair of like opposed meshing gears each having four convex points in space quadrature separated by four convex recesses with the radius of curvature of each point slightly less than that of each concave recess.

  17. Advanced heat pump cycle

    Energy Technology Data Exchange (ETDEWEB)

    Groll, E.A.; Radermacher, R.


    The desorption and absorption process of a vapor compression heat pump with a solution circuit (VCHSC) proceeds at gliding temperature intervals, which can be adjusted over a wide range. In case that the gliding temperature intervals in the desorber and the absorber overlap, a modification of the VCHSC employing a desorber/absorber heat exchange (DAHX) can be introduced, which results in an extreme reduction of the pressure ratio. Although the DAHX-cycle has features of a two-stage cycle, it still requires only one solution pump, one separator and one compressor. Such a cycle for the working pair ammonia/water is built in the Energy Laboratory of the Center for Environmental Energy Engineering at the University of Maryland. The experimental results obtained with the research plant are discussed and compared to those calculated with a simulation program. The possible temperature lift between heat source and heat sink depending on the achievable COP are presented.

  18. Inertial microfluidic pump (United States)

    Kornilovitch, Pavel; Govyadinov, Alexander; Markel, David; Torniainen, Erik


    The inertial pump is powered by a microheater positioned near one end of a fluidic microchannel. As the microheater explosively boils the surrounding fluid, a vapor bubble expands and then collapses asymmetrically, resulting in net flow. Such devices become an effective means of transporting fluids at microscale. They have no moving parts and can be manufactured in large numbers using standard batch fabrication processes. In this presentation, physical principles behind pump operation are described, in particular the role of reservoirs in dissipating mechanical momentum and the expansion-collapse asymmetry. An effective one-dimensional dynamic model is formulated and solved. The model is compared with full three-dimensional CFD simulations and available experimental data. Potential applications of inertial micropumps are described.

  19. Technology assessment heat pumps

    Energy Technology Data Exchange (ETDEWEB)

    Rudolph, R.; Purper, G. (Battelle-Institut e.V., Frankfurt am Main (Germany, F.R.))

    Technology assessment for an increased application of heat pumps is carried out in four areas: Effects in the economics area, i.e. effects on the economic goals which are defined in the Stability Law, on the goals of the power supply policy which result from the energy programme and its projections, and on the economic structure as a whole. The whole range of social problems concerning the use of heat pumps, i.e. the questions which social groups are affected, how they react, and what consequences are they expected to have on energy conservation as an object of social policy. Consequences in the governmental and administrative sectors, i.e. effects on legislation, administration and government budgets. Effects on the ecological systems; of prime interest in this context are the utilisation of environmental energy, changes in the heat balance, and emmission of pollutants.

  20. Synthesis of chemically bonded BiOCl@Bi{sub 2}WO{sub 6} microspheres with exposed (0 2 0) Bi{sub 2}WO{sub 6} facets and their enhanced photocatalytic activities under visible light irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Yongchao [Qingdao Agricultural University, Qingdao 266109 (China); Chen, Zhiwei [School of Life Sciences, Shandong University of Technology, Zibo 255049 (China); Qu, Dan [Qingdao Agricultural University, Qingdao 266109 (China); Shi, Jinsheng, E-mail: [Qingdao Agricultural University, Qingdao 266109 (China)


    Graphical abstract: - Highlights: • BiOCl@Bi{sub 2}WO{sub 6} composites were prepared via a controlled anion exchange method. • The shell of composites was composed of Bi{sub 2}WO{sub 6} sheets with exposed (0 2 0) facets. • The BiOCl@Bi{sub 2}WO{sub 6} composites showed efficient photocatalytic activity. • A possible photocatalytic degradation mechanism is proposed. - Abstract: Bi{sub 2}WO{sub 6} photocatalysts has been extensively studied for its photocatalytic activity. However, few works have been conducted on hierarchical Bi{sub 2}WO{sub 6} composite photocatalysts with specifically exposed facets. In this work, we report a facile method to synthesize BiOCl@Bi{sub 2}WO{sub 6} hierarchical composite microspheres. Bi{sub 2}WO{sub 6} nanosheets with specifically exposed (0 2 0) facet were directly formed on the surface of BiOCl precursor microspheres via a controlled anion exchange route between BiOCl and Na{sub 2}WO{sub 4}. The visible-light photocatalytic activity of the BiOCl@Bi{sub 2}WO{sub 6} heterojunction with exposed (0 2 0) facets (denoted as BiOCl@Bi{sub 2}WO{sub 6}) was investigated by degradation of Rhodamine B (RhB) and ciprofloxacin (CIP) aqueous solution under visible light irradiation. The experimental results indicated that the BiOCl@Bi{sub 2}WO{sub 6} composite microsphere with intimate interfacial contacts exhibited improved efficiency for RhB photodegradation in comparison with pure BiOCl and Bi{sub 2}WO{sub 6}. The BiOCl@Bi{sub 2}WO{sub 6} composite microsphere also shows high photocatalytic activity for degradation of CIP under visible light irradiation. The enhanced photocatalytic performance of BiOCl@Bi{sub 2}WO{sub 6}-020 hierarchical microspheres can be ascribed to the improved visible light harvesting ability, high charge separation and transfer. This work will make significant contributions toward the exploration of novel heterostructures with high potential in photocatalytic applications.

  1. Hydrodynamics of Pumps


    Brennen, Christopher Earls


    The subject of this monograph is the fluid dynamics of liquid turbomachines, particularly pumps. Rather than attempt a general treatise on turbomachines, we shall focus attention on those special problems and design issues associated with the flow of liquid through a rotating machine. There are two characteristics of a liquid that lead to these special problems, and cause a significantly different set of concerns than would occur in, say, a gas turbine. These are the potential for cavitation ...

  2. Pioneering Heat Pump Project

    Energy Technology Data Exchange (ETDEWEB)

    Aschliman, Dave [Indiana Inst. of Technology, Inc., Fort Wayne, IN (United States); Lubbehusen, Mike [Indiana Inst. of Technology, Inc., Fort Wayne, IN (United States)


    This project was initiated at a time when ground coupled heat pump systems in this region were limited in size and quantity. There were economic pressures with costs for natural gas and electric utilities that had many organizations considering ground coupled heat pumps; The research has added to the understanding of how ground temperatures fluctuate seasonally and how this affects the performance and operation of the heat pumps. This was done by using a series of temperature sensors buried within the middle of one of the vertical bore fields with sensors located at various depths below grade. Trending of the data showed that there is a lag in ground temperature with respect to air temperatures in the shoulder months, however as full cooling and heating season arrives, the heat rejection and heat extraction from the ground has a significant effect on the ground temps; Additionally it is better understood that while a large community geothermal bore field serving multiple buildings does provide a convenient central plant to use, it introduces complexity of not being able to easily model and predict how each building will contribute to the loads in real time. Additional controllers and programming were added to provide more insight into this real time load profile and allow for intelligent shedding of load via a dry cooler during cool nights in lieu of rejecting to the ground loop. This serves as a means to ‘condition’ the ground loop and mitigate thermal creep of the field, as is typically observed; and It has been observed when compared to traditional heating and cooling equipment, there is still a cost premium to use ground source heat pumps that is driven mostly by the cost for vertical bore holes. Horizontal loop systems are less costly to install, but do not perform as well in this climate zone for heating mode

  3. Positive displacement rotary pump (United States)

    Moody, Paul E.


    An eccentric drive rotates inside a ring that is hinged to a plate and an elastomeric curtain is wrapped around the ring and across an articulated plate. The curtain moves along a cylindrical wall inside the pump cavity to move fluid from an inlet to an outlet end of the chamber. Two or more chambers can be coupled in series or in parallel with one another.

  4. Nonazeotropic Heat Pump (United States)

    Ealker, David H.; Deming, Glenn


    Heat pump collects heat from water circulating in heat-rejection loop, raises temperature of collected heat, and transfers collected heat to water in separate pipe. Includes sealed motor/compressor with cooling coils, evaporator, and condenser, all mounted in outer housing. Gradients of temperature in evaporator and condenser increase heat-transfer efficiency of vapor-compression cycle. Intended to recover relatively-low-temperature waste heat and use it to make hot water.

  5. Nonazeotropic Heat Pump (United States)

    Ealker, David H.; Deming, Glenn


    Heat pump collects heat from water circulating in heat-rejection loop, raises temperature of collected heat, and transfers collected heat to water in separate pipe. Includes sealed motor/compressor with cooling coils, evaporator, and condenser, all mounted in outer housing. Gradients of temperature in evaporator and condenser increase heat-transfer efficiency of vapor-compression cycle. Intended to recover relatively-low-temperature waste heat and use it to make hot water.

  6. Introduction to Pump Rotordynamics (United States)


    RTO-EN-AVT-143 9 - 1 Introduction to Pump Rotordynamics Luis San Andrés Mast-Childs Tribology Professor Turbomachinery Laboratory Texas A... rotordynamics of turbomachinery, excessive vibration and instability. The acceptable performance of a turbomachine depends on the adequate design and operation...on rotordynamics . The basic equations for the modeling of linear rotor-bearing systems are given along with an example for the rotordynamics of a

  7. Fabrication and Characterization of Tailored TiO2and WO3/MWCNT Composites for Methylene Blue Decomposition%Fabrication and Characterization of Tailored TiO2 and WO3/MWCNT Composites for Methylene Blue Decomposition

    Institute of Scientific and Technical Information of China (English)

    ZHU Lei; MENG Zeda; OH Won-Chun


    A sol-gel method was used to prepare WO3/MWCNT-TiO2 composites. Their photocatalytic activities were evaluated by the degradation of methylene blue (MB) solution under UV light. The catalysts were characterized by X-ray diffraction, specific surface area measurement, energy-dispersive X-ray analysis, transmission and scanning electron microscopy. Aqueous MB solutions of 100 ml were photode graded by a small amount of the WO3/MWCNT-TiO2 composite under UV light irradiation. The photocatalytic data showed that the WO3/MWCNT-TiO2 composite achieved a high rate of MB photodegradation. This was attributed to the use of MWCNT which can absorb UV light to create photo-induced electrons, strong adsorption of dye molecules on the photocatalyst, and reduced recombination rate of electron-holes in the WO3/MWCNT-TiO2 composite due to the introduction of the WO3 semiconductor.

  8. Electrocentrifugal pumping; Bombeo electrocentrifugo

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Perez, Guillermo; Medellin Otero, Hector [Instituto Mexicano del Peroleo (Mexico)


    The exploitation of isolated oil deposits, in losing their own energy, enter a phase of secondary recovery. One of the technologies of new development in Mexico is the one of electrocentrifugal pumping , which consists of introducing the motor-pump as an integral part of the production pipe down to the well bottom and pumping directly up to central complexes, from where it is sent inland. In the present paper is intended to explain what this type of secondary recovery consists of. [Spanish] La explotacion de yacimientos aislados de petroleo, al perder su energia propia, entran en una fase de recuperacion secundaria. Una de las tecnologias de nuevo desarrollo en Mexico es la de bombeo electrocentrifugo, la cual consiste en introducir la motobomba como parte integral de la tuberia de produccion hasta el fondo del pozo y bombearlo directamente hasta los complejos centrales, de donde se envia a tierra. En el presente trabajo se pretende explicar en que consiste este tipo de recuperacion secundaria.

  9. Stirling Engine Heat Pump (United States)

    Kagawa, Noboru

    Recent advances in the feasibility studies related to the Stirling engines and Stirling engine heat pumps which have been considered attractive due to their promising role in helping to solve the global environmental and energy problems,are reviewed. This article begins to describe the brief history of the Stirling engines and theoretical thermodynamic analysis of the Stirling cycle in order to understand several advantages on the Stirling engine. Furthermore,they could throw light on our question why the dream engines had not been promoted to practical applications during two hundred years. The present review shows that the Stirling engines with several unique advantages including 30 to 40% thermal efficiency and preferable exhaust characteristics,had been designed and constructed by recent tackling for the development of the advanced automobile and other applications using them. Based on the current state of art,it is being provided to push the Stirling engines combined with heat pumps based on the reversed Rankine cycle to the market. At present,however, many problems, especially for the durability, cost, and delicate engine parts must be enforced to solve. In addition,there are some possibilities which can increase the attractiveness of the Stirling engines and heat pumps. The review closes with suggestions for further research.

  10. A Magnetically Coupled Cryogenic Pump (United States)

    Hatfield, Walter; Jumper, Kevin


    Historically, cryogenic pumps used for propellant loading at Kennedy Space Center (KSC) and other NASA Centers have a bellows mechanical seal and oil bath ball bearings, both of which can be problematic and require high maintenance. Because of the extremely low temperatures, the mechanical seals are made of special materials and design, have wearing surfaces, are subject to improper installation, and commonly are a potential leak path. The ball bearings are non-precision bearings [ABEC-1 (Annular Bearing Engineering Council)] and are lubricated using LOX compatible oil. This oil is compatible with the propellant to prevent explosions, but does not have good lubricating properties. Due to the poor lubricity, it has been a goal of the KSC cryogenics community for the last 15 years to develop a magnetically coupled pump, which would eliminate these two potential issues. A number of projects have been attempted, but none of the pumps was a success. An off-the-shelf magnetically coupled pump (typically used with corrosive fluids) was procured that has been used for hypergolic service at KSC. The KSC Cryogenics Test Lab (CTL) operated the pump in cryogenic LN2 as received to determine a baseline for modifications required. The pump bushing, bearings, and thrust rings failed, and the pump would not flow liquid (this is a typical failure mode that was experienced in the previous attempts). Using the knowledge gained over the years designing and building cryogenic pumps, the CTL determined alternative materials that would be suitable for use under the pump design conditions. The CTL procured alternative materials for the bearings (bronze, aluminum bronze, and glass filled PTFE) and machined new bearing bushings, sleeves, and thrust rings. The designed clearances among the bushings, sleeves, thrust rings, case, and case cover were altered once again using experience gained from previous cryogenic pump rebuilds and designs. The alternative material parts were assembled into

  11. Rare-earth-ion doped KY(WO4)2 optical waveguides grown by liquid-phase epitaxy

    NARCIS (Netherlands)

    Romanyuk, Y.E.; Apostolopoulos, V.; Utke, U.; Pollnau, Markus


    High-quality KY(WO4)2 thin layers doped with rare-earth-ions were grown using liquid-phase epitaxy. A low-temperature mixture of chlorides was used as the flux and undoped KY(WO4)2 crystals as substrates. The crystalline layers possessed thicknesses up to 10 µm. Passive and active planar waveguiding

  12. Enhancement of photoelectric response of bacteriorhodopsin by multilayered WO3 x H2O nanocrystals/PVA membrane. (United States)

    Li, Rui; Hu, Fengping; Bao, Qiaoliang; Bao, Shujuan; Qiao, Yan; Yu, Shucong; Guo, Jun; Li, Chang Ming


    For the first time, a multilayered WO(3) x H(2)O/PVA membrane on bacteriorhodopsin (bR) is constructed to significantly enhance the photoelectric response of bR by the spillover effect of WO(3) x H(2)O nanocrystals, providing great potential in its important applications in bioelectronics and proton exchange membrane fuel cells.

  13. Synthesis, characterization and electrochemical studies of nanostructured CaWO{sub 4} as platinum support for oxygen reduction reaction

    Energy Technology Data Exchange (ETDEWEB)

    Farsi, Hossein [Department of Chemistry, University of Birjand, 97175-615 Birjand (Iran, Islamic Republic of); Solar Energy Research Department, University of Birjand, Birjand (Iran, Islamic Republic of); Barzgari, Zahra, E-mail: [Department of Chemistry, University of Birjand, 97175-615 Birjand (Iran, Islamic Republic of)


    Highlights: • Nanostructured CaWO{sub 4} was fabricated by co-precipitation method. • Platinum was electrodeposited onto the surface prepared nanostructured CaWO{sub 4}. • Pt/CaWO{sub 4}-graphite demonstrate good oxygen reduction reaction activity. - Abstract: In the present work, we employed nanostructured calcium tungstate as a supporting material for platinum, a well-known electrocatalyst for oxygen reduction. The co-precipitation method has been utilized to synthesize nanostructured calcium tungstate from aqueous solution. The structure and morphology of the obtained CaWO{sub 4} were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Preparation of the Pt/CaWO{sub 4}-graphite catalyst was carried out by electrodeposition of Pt onto the surface of CaWO{sub 4}/graphite electrode. The physical properties of the catalyst were determined by scanning electron microscopy analysis and energy dispersive X-ray (SEM/EDX). The electrochemical activity of the Pt/CaWO{sub 4}-graphite for the oxygen reduction reaction (ORR) was investigated in acid solution by cyclic voltammetry measurements, linear sweep voltammetry, and electrochemical impedance spectroscopy. The results revealed that the Pt/CaWO{sub 4}-graphite has higher electrocatalytic activity for oxygen reduction in comparison with Pt/graphite catalyst.

  14. H.sub.2O doped WO.sub.3, ultra-fast, high-sensitivity hydrogen sensors (United States)

    Liu, Ping; Tracy, C. Edwin; Pitts, J. Roland; Lee, Se-Hee


    An ultra-fast response, high sensitivity structure for optical detection of low concentrations of hydrogen gas, comprising: a substrate; a water-doped WO.sub.3 layer coated on the substrate; and a palladium layer coated on the water-doped WO.sub.3 layer.

  15. Photoelectrocatalytic degradation of phthalic acid using spray deposited stratified WO3/ZnO thin films under sunlight illumination (United States)

    Hunge, Y. M.; Mahadik, M. A.; Moholkar, A. V.; Bhosale, C. H.


    In the present work, stratified WO3/ZnO thin films have been prepared by simple chemical spray pyrolysis technique. The structural, morphological, compositional and photoelectrocatalytic properties of the stratified WO3/ZnO thin films are studied. The photoelectrochemical (PEC) study shows that, both short circuit current (Isc) and open circuit voltage (Voc) are (Isc = 1.023 mA and Voc = 0.980 V) relatively high at 40 ml spraying quantity of ZnO solution on pre-deposited WO3 thin films. XRD analysis reveals that stratified WO3/ZnO thin films are polycrystalline with monoclinic and hexagonal crystal structures for WO3 and ZnO respectively. The specific surface area of the stratified WO3/ZnO thin film is found to be 48.12 m2 g-1. The enhanced photoelectrocatalytic activity of stratified WO3/ZnO is mainly due to the suppressing the recombination of photo generated electron-hole pairs. The end result shows that the degradation percentage of phthalic acid (PA) using stratified WO3/ZnO photo electrode has reached 63.63% after 320 min. under sunlight illumination. The amount of mineralization of phthalic acid is studied with the help of chemical oxygen demand (COD) measurement.

  16. Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst

    CSIR Research Space (South Africa)

    Makgwane, PR


    Full Text Available An efficient room temperature catalyzed oxidation of cyclohexane to cyclohexanone (K) and cyclohexanol (A) was achieved over hetero-mixed tungsten–vanadia (WO(sub3)/V(sub2)O(sub5)) using H(sub2)O(sub2) oxidant. WO(sub3)/V(sub2)O(sub5) exhibited high...

  17. High activity of Pd-WO3/C catalyst as anodic catalyst for direct formic acid fuel cell (United States)

    Feng, Ligang; Yan, Liang; Cui, Zhiming; Liu, Changpeng; Xing, Wei


    Pd nanoparticles supported on the WO3/C hybrid are prepared by a two-step procedure and the catalysts are studied for the electrooxidation of formic acid. For the purpose of comparison, phosphotungstic acid (PWA) and sodium tungstate are used as the precursor of WO3. Both the Pd-WO3/C catalysts have much higher catalytic activity for the electrooxidation of formic acid than the Pd/C catalyst. The Pd-WO3/C catalyst prepared from PWA shows the best catalytic activity and stability for formic acid oxidation; it also shows the maximum power density of approximately 7.6 mW cm-2 when tested with a small single passive fuel cell. The increase of electrocatalytic activity and stability is ascribed to the interaction between the Pd and WO3, which promotes the oxidation of formic acid in the direct pathway. The precursors used for the preparation of the WO3/C hybrid support have a great effect on the performance of the Pd-WO3/C catalyst. The WO3/C hybrid support prepared from PWA is beneficial to the dispersion of Pd nanoparticles, and the catalyst has potential application for direct formic acid fuel cell.

  18. Exfoliated thin Bi2MoO6 nanosheets supported on WO3 electrode for enhanced photoelectrochemical water splitting (United States)

    Ma, Ying; Jia, Yulong; Wang, Lina; Yang, Min; Bi, Yingpu; Qi, Yanxing


    Thin Bi2MoO6 nanosheets are obtained by a microwave-assisted ultrasonic separation process. After exfoliation, the thinner and uniform nanosheets with a thickness of about 10 nm were obtained. The exfoliated nanosheets would provide many amazing functionalities such as high electron mobility and quantum Hall effects. Therefore, thin Bi2MoO6 supported on WO3 electrode (WO3/thin Bi2MoO6) exhibits facilitated charge separation than pure WO3 film and the un-exfoliated Bi2MoO6 nanosheets supported on WO3 electrode (WO3/Bi2MoO6). As a result, WO3/thin Bi2MoO6 shows remarkably stable photocurrent density of 2.2 mA/cm2 at 0.8 VSCE in 0.1 M Na2SO4 which is higher than that of that of WO3 (1.1 mA/cm2) and WO3/Bi2MoO6 (1.5 mA/cm2).

  19. Structural properties of WO{sub 3} dependent of the annealing temperature deposited by hot-filament metal oxide deposition

    Energy Technology Data Exchange (ETDEWEB)

    Flores M, J. E. [Benemerita Universidad Autonoma de Puebla, Facultad de Ciencias de la Electronica, Av. San Claudio y 18 Sur, Ciudad Universitaria, Col. Jardines de San Manuel, 72570 Puebla (Mexico); Diaz R, J. [IPN, Centro de Investigacion en Biotecnologia Aplicada, Ex-Hacienda de San Molino Km 1.5 Tepetitla, 90700 Tlaxcala (Mexico); Balderas L, J. A., E-mail: [IPN, Unidad Profesional Interdisciplinaria de Biotecnologia, Av. Acueducto s/n, Col. Barrio la Laguna, 07340 Mexico D. F. (Mexico)


    In this work presents a study of the effect of the annealing temperature on structural and optical properties of WO{sub 3} that has been grown by hot-filament metal oxide deposition. The chemical stoichiometry was determined by X-ray photoelectron spectroscopy. By X-ray diffraction obtained that the as-deposited WO{sub 3} films present mainly monoclinic crystalline phase. WO{sub 3} optical band gap energy can be varied from 2.92 to 3.15 eV obtained by transmittance measurements by annealing WO{sub 3} from 100 to 500 C. The Raman spectrum of the as-deposited WO{sub 3} film shows four intense peaks that are typical Raman peaks of crystalline WO{sub 3} (m-phase) that corresponds to the stretching vibrations of the bridging oxygen that are assigned to W-O stretching ({upsilon}) and W-O bending ({delta}) modes, respectively, which enhanced and increased their intensity with the annealing temperature. (Author)

  20. Preparation and characterization of WO3/Bi3O4Cl nanocomposite and its photocatalytic behavior under visible light irradiation

    CSIR Research Space (South Africa)

    Chakraborty, AK


    Full Text Available The highly efficient and visible light ( = 420 nm) responsive composite photocatalyst WO3/Bi3O4Cl was prepared by the simple incipient wetness method. The heterojunction structure WO3/Bi3O4Cl demonstrated notably higher photocatalytic activity than...

  1. Plasmodium falciparum parasites expressing pregnancy-specific variant surface antigens adhere strongly to the choriocarcinoma cell line BeWo

    DEFF Research Database (Denmark)

    Haase, Rikke N; Megnekou, Rosette; Lundquist, Maja;


    Placenta-sequestering Plasmodium falciparum parasites causing pregnancy-associated malaria express pregnancy-specific variant surface antigens (VSA(PAM)). We report here that VSA(PAM)-expressing patient isolates adhere strongly to the choriocarcinoma cell line BeWo and that the BeWo line can...

  2. Facile hydrothermal synthesis of TiO2-Bi2WO6 hollow superstructures with excellent photocatalysis and recycle properties. (United States)

    Hou, Ya-Fei; Liu, Shu-Juan; Zhang, Jing-huai; Cheng, Xiao; Wang, You


    One-dimensional mesoporous TiO2-Bi2WO6 hollow superstructures are prepared using a hydrothermal method and their photocatalysis and recycle properties are investigated. Experimental results indicate that anatase TiO2 nanoparticles are coupled with hierarchical Bi2WO6 hollow tubes on their surfaces. The TiO2-Bi2WO6 structure has a mesoporous wall and the pores in the wall are on average 21 nm. The hierarchical TiO2-Bi2WO6 heterostructures exhibit the highest photocatalytic activity in comparison with P25, pure Bi2WO6 hollow tube and mechanical mixture of Bi2WO6 tube and TiO2 nanoparticle in the degradation of rhodamine B (RhB) under simulated sunlight irradiation. The as-prepared TiO2-Bi2WO6 heterostructures can be easily recycled through sedimentation and they retains their high photocatalytic activity during the cycling use in the simulated sunlight-driving photodegradation process of RhB. The prepared mesoporous TiO2-Bi2WO6 with hollow superstructure is therefore a promising candidate material for water decontamination use.

  3. Physical properties characterization of WO{sub 3} films grown by hot-filament metal oxide deposition

    Energy Technology Data Exchange (ETDEWEB)

    Diaz-Reyes, J., E-mail: [Centro de Investigacion en Biotecnologia Aplicada del Instituto Politecnico Nacional, Ex-Hacienda de San Juan Molino, Km. 1.5, Tepetitla, Tlaxcala, 90700 (Mexico); Delgado-Macuil, R.J. [Centro de Investigacion en Biotecnologia Aplicada del Instituto Politecnico Nacional, Ex-Hacienda de San Juan Molino, Km. 1.5, Tepetitla, Tlaxcala, 90700 (Mexico); Dorantes-Garcia, V. [Preparatoria ' Simon Bolivar' de la Benemerita Universidad Autonoma de Puebla, 4 Oriente 408, Col. Centro, Atlixco, Puebla, C. P. 74200 (Mexico); Perez-Benitez, A. [Facultad de Ciencias Quimicas de la Benemerita Universidad Autonoma Puebla, 14 Sur y Av. San Claudio, Col. San Manuel, Puebla, Puebla, C. P. 72570 (Mexico); Balderas-Lopez, J.A. [Unidad Profesional Interdisciplinaria de Biotecnologia del Instituto Politecnico Nacional, Avenida Acueducto S/N, Col. Barrio la Laguna, Ticoman, Del. Gustavo A. Madero, Mexico, D.F. 07340 (Mexico); Ariza-Ortega, J.A. [Centro de Investigacion en Biotecnologia Aplicada del Instituto Politecnico Nacional, Ex-Hacienda de San Juan Molino, Km. 1.5, Tepetitla, Tlaxcala, 90700 (Mexico)


    WO{sub 3} is grown by hot-filament metal oxide deposition (HFMOD) technique under atmospheric pressure and an oxygen atmosphere. By X-ray diffraction obtains that WO{sub 3} presents mainly monoclinic crystalline phase. The chemical stoichiometry is obtained by X-ray Photoelectron Spectroscopy (XPS). The IR spectrum of the as-grown WO{sub 3} presents broad peaks in the range of 1100 to 3600 cm{sup -1}. A broad band in the 2200 to 3600 cm{sup -1} region and the peaks sited at 1645 and 1432 cm{sup -1} are well resolved, which are originated from moisture and are assigned to {nu}(OH) and {delta}(OH) modes of adsorbed water and the corresponding tungsten oxide vibrations are in infrared region from 400 to 1453 cm{sup -1} and around 3492 cm{sup -1}, which correspond to tungsten-oxygen (W-O) stretching, bending and lattice modes. The Raman spectrum shows intense peaks at 801, 710, 262 and 61 cm{sup -1} that are typical Raman peaks of crystalline WO{sub 3} (m-phase) that correspond to stretching vibrations of the bridging oxygen, which are assigned to W-O stretching ({nu}) and W-O bending ({delta}) modes, respectively. By transmittance measurements obtains that the WO{sub 3} band gap can be varied from 2.92 to 3.13 eV in the investigated annealing temperature range.

  4. The band structure of WO3 and non-rigid-band behaviour in Na0.67WO3 derived from soft x-ray spectroscopy and density functional theory. (United States)

    Chen, B; Laverock, J; Piper, L F J; Preston, A R H; Cho, S W; DeMasi, A; Smith, K E; Scanlon, D O; Watson, G W; Egdell, R G; Glans, P-A; Guo, J-H


    The electronic structure of single-crystal WO3 and Na0.67WO3 (a sodium-tungsten bronze) has been measured using soft x-ray absorption and resonant soft x-ray emission oxygen K-edge spectroscopies. The spectral features show clear differences in energy and intensity between WO3 and Na0.67WO3. The x-ray emission spectrum of metallic Na0.67WO3 terminates in a distinct Fermi edge. The rigid-band model fails to explain the electronic structure of Na0.67WO3 in terms of a simple addition of electrons to the conduction band of WO3. Instead, Na bonding and Na 3s-O 2p hybridization need to be considered for the sodium-tungsten bronze, along with occupation of the bottom of the conduction band. Furthermore, the anisotropy in the band structure of monoclinic γ-WO3 revealed by the experimental spectra with orbital-resolved geometry is explained via density functional theory calculations. For γ-WO3 itself, good agreement is found between the experimental O K-edge spectra and the theoretical partial density of states of O 2p orbitals. Indirect and direct bandgaps of insulating WO3 are determined from extrapolating separations between spectral leading edges and accounting for the core-hole energy shift in the absorption process. The O 2p non-bonding states show upward band dispersion as a function of incident photon energy for both compounds, which is explained using the calculated band structure and experimental geometry.

  5. Preparation, structures and photoluminescent enhancement effect of PbWO4-TiO2 composite nanofilms (United States)

    Run-Ping, Jia; Guo-Xin, Zhang; Qing-Sheng, Wu


    A novel route for preparing PbWO4-TiO2 nanofilms on a glass substrate is firstly proposed. The collodion is used as a dispersant and film-forming agent. The nanofilms are characterized through SEM, XRD, TG/DTA, PL and IR, respectively. The results of XRD indicate PbWO4 particles with tetragonal scheelite structure and TiO2 particles with Anatase phase, and SEM shows they are well dispersed in the substrate. Compared with nanoparticles, when TiO2 nanoparticles are added in 5% ratio, the PL intensities at 395 nm of PbWO4 nanofilms are enhanced obviously. IR spectrum reveals a large absorption band between 750 and 870 cm-1, which is the W-O stretching vibration in WO4 tetrahedron.

  6. Magnetic properties of KRE(WO{sub 4}){sub 2} (RE=Gd, Yb, Tm) single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Borowiec, M.T., E-mail: [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL 02-668 Warsaw (Poland); Zayarnyuk, T. [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL 02-668 Warsaw (Poland); Pujol, M.C.; Aguilo, M.; Diaz, F. [Fisica i Cristal.lografia de Materials i Nanomaterials (FiCMA-FICNA), Departament de Quimica Fisica i Inorganica, Universitat Rovira i Virgili (URV), Campus Sescelades, C/ Domingo, s/n, E-43007 Tarragona, Catalunya (Spain); Zubov, E.E.; Prokhorov, A.D. [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL 02-668 Warsaw (Poland); Donetsk Institute for Physics and Engineering, National Academy of Sciences of Ukraine, R. Luxemburg Street 72, 83114 Donetsk (Ukraine); Berkowski, M.; Domuchowski, W.; Wisniewski, A.; Puzniak, R.; Pietosa, J. [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL 02-668 Warsaw (Poland); Dyakonov, V.P. [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL 02-668 Warsaw (Poland); Donetsk Institute for Physics and Engineering, National Academy of Sciences of Ukraine, R. Luxemburg Street 72, 83114 Donetsk (Ukraine); Baranski, M.; Szymczak, H. [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL 02-668 Warsaw (Poland)


    Magnetic properties of KGd(WO{sub 4}){sub 2}, KYb(WO{sub 4}){sub 2} and KTm(WO{sub 4}){sub 2} single crystals have been studied. Temperature and field dependences of the magnetization along the main magnetic axes and angular dependence of the magnetization in the planes settled on the magnetic axes were recorded in the temperature range from 2 up to 100 K and in magnetic field up to 9 T. Paramagnetic Curie temperatures, g-factors and exchange interaction parameters were determined. Different theoretical models were used to describe magnetic properties of KGd(WO{sub 4}){sub 2} and KYb(WO{sub 4}){sub 2} crystals.

  7. Facile Preparation of Efficient WO3 Photocatalysts Based on Surface Modification

    Directory of Open Access Journals (Sweden)

    Min Liu


    Full Text Available Tungsten trioxide (WO3 was surface modified with Cu(II nanoclusters and titanium dioxide (TiO2 nanopowders by using a simple impregnation method followed by a physical combining method. The obtained nanocomposites were studied by scanning electron microscope, X-ray photoelectron spectroscopy spectra, UV-visible light spectra, and photoluminescence, respectively. Although the photocatalytic activity of WO3 was negligible under visible light irradiation, the visible light photocatalytic activity of WO3 was drastically enhanced by surface modification of Cu(II nanoclusters and TiO2 nanopowders. The enhanced photocatalytic activity is due to the efficient charge separation by TiO2 and Cu(II nanoclusters functioning as cocatalysts on the surface. Thus, this simple strategy provides a facile route to prepare efficient visible-light-active photocatalysts for practical application.

  8. Celdas solares fotoelectroquímicas basadas en Bi2WO6

    Directory of Open Access Journals (Sweden)

    Lorean Madriz


    Full Text Available In this study, photoelectrochemical solar cells based on bismuth tungstate electrodes were evaluated. Bi2WO6 was synthesized by a hydrothermal method and characterized by scanning electron microscopy, UV-Vis reflectance spectroscopy, and X-ray powder diffraction. For comparison, solar cells based on TiO2 semiconductor electrodes were evaluated. Photoelectrochemical response of Grätzel-type solar cells based on these semiconductors and their corresponding sensitization with two inexpensive phthalocyanines dyes were determined. Bi2WO6-based solar cells presented higher values of photocurrent and efficiency than those obtained with TiO2 electrodes, even without sensitization. These results portray solar cells based on Bi2WO6 as promising devices for solar energy conversion owing to lower cost of production and ease of acquisition.

  9. Understanding the Potential of WO3 Based Sensors for Breath Analysis (United States)

    Staerz, Anna; Weimar, Udo; Barsan, Nicolae


    Tungsten trioxide is the second most commonly used semiconducting metal oxide in gas sensors. Semiconducting metal oxide (SMOX)-based sensors are small, robust, inexpensive and sensitive, making them highly attractive for handheld portable medical diagnostic detectors. WO3 is reported to show high sensor responses to several biomarkers found in breath, e.g., acetone, ammonia, carbon monoxide, hydrogen sulfide, toluene, and nitric oxide. Modern material science allows WO3 samples to be tailored to address certain sensing needs. Utilizing recent advances in breath sampling it will be possible in the future to test WO3-based sensors in application conditions and to compare the sensing results to those obtained using more expensive analytical methods. PMID:27801881

  10. Anomalous spin state of Fe in double perovskite oxide Sr 2FeWO 6 (United States)

    Kawanaka, H.; Hase, I.; Toyama, S.; Nishihara, Y.


    In the series of Sr 2FeTO 6 (T=4d or 5d), the valence of Fe is 3+ in most of the compounds. However, recently we have found that the Sr 2FeWO 6 has Fe 2+ state. Sr 2FeWO 6 is an insulator with an antiferromagnetic transition temperature of 37 K. From the Mössbauer experiment, below ∼20 K, a center shift of +1.2 mm/ s relative to metallic iron and a quadrupole splitting of 1.9 mm/ s are obtained. The quadrupole splitting has strong temperature dependence. The hyperfine field is ∼110 kOe which seems to be quite small. We concluded that the iron ground state of Sr 2FeWO 6 is Fe 2+ high-spin ( S=2) state.

  11. ZnWO_4 crystals as detectors for double beta decay and dark matter experiments

    CERN Document Server

    Danevich, F A; Nagorny, S S; Poda, D V; Tretyak, V I; Yurchenko, S S; Zdesenko, Y G; Zdesenko, Yu.G.


    Energy resolution, alpha/beta ratio, and the pulse shape discrimination ability of the ZnWO_4 crystal scintillators were studied. The radioactive contamination of a ZnWO_4 crystal was investigated in the Solotvina Underground Laboratory. Possibilities to apply ZnWO_4 crystals for the dark matter and double beta decay searches are discussed. New improved half-life limits on double beta decay in zinc isotopes were established, in particular, for EC\\beta^+ decay of 64-Zn as: T_1/2^2nu > 8.9 10^18 yr and T_1/2^0nu > 3.6 10^18 yr, both at 68% CL.

  12. ZnWO{sub 4} crystals as detectors for 2{beta} decay and dark matter experiments

    Energy Technology Data Exchange (ETDEWEB)

    Danevich, F.A. [Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680 Kiev (Ukraine)]. E-mail:; Kobychev, V.V. [Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680 Kiev (Ukraine); Nagorny, S.S. [Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680 Kiev (Ukraine); Poda, D.V. [Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680 Kiev (Ukraine); Tretyak, V.I. [Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680 Kiev (Ukraine); Yurchenko, S.S. [Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680 Kiev (Ukraine); Zdesenko, Yu.G. [Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680 Kiev (Ukraine)


    Energy resolution, {alpha}/{beta} ratio, and the pulse shape discrimination ability of the ZnWO{sub 4} crystal scintillators were studied. The radioactive contamination of a ZnWO{sub 4} crystal was investigated in the Solotvina Underground Laboratory. Possibilities to apply ZnWO{sub 4} crystals for the dark matter and double beta decay searches are discussed. New improved half-life limits on double beta decay in zinc isotopes were established, in particular, for -bar {beta}{sup +} decay of {sup 64}Zn as: T{sub 1/2}{sup 2{nu}}>=8.9x10{sup 18} years and T{sub 1/2}{sup 0{nu}}>=3.6x10{sup 18} years, both at 68% CL.

  13. Metal-insulator transition in Na{sub x}WO{sub 3}: Photoemission spectromicroscopy study

    Energy Technology Data Exchange (ETDEWEB)

    Paul, Sanhita, E-mail:; Ghosh, Anirudha, E-mail:; Raj, Satyabrata, E-mail: [Department of Physical Sciences, Indian Institute of Science Education and Research - Kolkata, Mohanpur Campus, Nadia -741252, West Bengal (India)


    We have investigated the validity of percolation model, which is quite often invoked to explain the metal-insulator transition in sodium tungsten bronzes, Na{sub x}WO{sub 3} by photoelectron spectromicroscopy. The spatially resolved direct spectromicroscopic probing on both the insulating and metallic phases of high quality single crystals of Na{sub x}WO{sub 3} reveals the absence of any microscopic inhomogeneities embedded in the system within the experimental limit. Neither any metallic domains in the insulating host nor any insulating domains in the metallic host have been found to support the validity of percolation model to explain the metal-insulator transition in Na{sub x}WO{sub 3}.

  14. Radiation-induced color centers in La-doped PbWO sub 4 crystals

    CERN Document Server

    Deng, Q; Zhu, R Y


    This report presents the result of a study on radiation-induced color center densities in La-doped lead tungstate (PbWO sub 4) crystals. The creation and annihilation constants of radiation-induced color centers were determined by using transmittance data measured for a PbWO sub 4 sample before and during sup 6 sup 0 Co gamma-ray irradiation at a dose rate of 15 rad/h. Following a model of color center kinetics, these constants were used to calculate color center densities under irradiations at 100 rad/h. The result was found to be in good agreement with experimental data, indicating that the behaviour of PbWO sub 4 crystals under irradiation can be predicted according to this model.

  15. Sunlight driven photocatalytic water splitting using nanostructured bismuth tungstate (Bi2WO6) (United States)

    Radha, R.; Sakar, M.; Bharathkumar, S.; Balakumar, S.


    Sunlight driven photocatalytic water splitting properties of nanosized Bi2WO6 have been demonstrated. Upon the structural confirmation using XRD and Raman studies, the band edge offset deduced from UV-DRS spectra showed that the energy band structure of Bi2WO6 is manifested due to electronic transition in the hybridized orbital of Bi6s and O2p to the W5d orbital. The observed Bi2WO6 nanoparticulates-assisted H2 generation from glycerol-water mixture may be attributed to the following two competitive phenomena: (i) the photocatalytic degradation of glycerol and (ii) photocatalytic splitting of water molecules, where glycerol acts as a sacrificial agent. This study sheds lights on the photocatalytic reformation of contaminated aqueous ecosystems as a green resource to produce hydrogen energy.

  16. Supercritical waste oxidation pump investigation

    Energy Technology Data Exchange (ETDEWEB)

    Thurston, G.; Garcia, K.


    This report investigates the pumping techniques and pumping equipment that would be appropriate for a 5,000 gallon per day supercritical water oxidation waste disposal facility. The pumps must boost water, waste, and additives from atmospheric pressure to approximately 27.6 MPa (4,000 psia). The required flow ranges from 10 gpm to less than 0.1 gpm. For the higher flows, many commercial piston pumps are available. These pumps have packing and check-valves that will require periodic maintenance; probably at 2 to 6 month intervals. Several commercial diaphragm pumps were also discovered that could pump the higher flow rates. Diaphragm pumps have the advantage of not requiring dynamic seals. For the lower flows associated with the waste and additive materials, commercial diaphragm pumps. are available. Difficult to pump materials that are sticky, radioactive, or contain solids, could be injected with an accumulator using an inert gas as the driving mechanism. The information presented in this report serves as a spring board for trade studies and the development of equipment specifications.

  17. Luminescence spectroscopy of K3WO3F3 oxyfluoride crystals (United States)

    Kozlov, A. V.; Pustovarov, V. A.


    Spectra of photoluminescence (PL) in region of 1.5-5.5 eV, PL excitation spectra (3-22 eV), PL decay kinetics, the temperature dependence of the PL were measured for single crystals and ceramics K3WO3F3 as well as irradiate ceramics K3WO3F3. Synchrotron radiation was used for low temperature PL experiments with time resolution. Single crystals are transparent in microwave, visible and near UV range, inter-band transition energy is Eg = 4.3 eV. The intrinsic luminescence of tungstates is usually ascribed to the radiative relaxation of exciton-like excitations localized on WO6 octahedra or WO4 tetrahedra. In K3WO3F3 the wide band luminescence in the region of 2.5 eV with the Stokes shift of 1.5 eV with the microsecond decay kinetics is connected with luminescence of triplet self-trapped excitons (STE). This luminescence is formed by electronic transitions in [WO3F3] octahedron. Different distortion of KWOF crystal lattice is manifested in the change of the Stokes shift of STE luminescence band. The 3.2 eV emission band in low-temperature PL spectrum with decay times of 1.8 ns and 11 ns corresponds to singlet STE luminescence. A new 2.9 eV emission band is discovered in low-temperature PL spectrum in the samples irradiated by fast electrons (E = 10 MeV, D = 160 kGy). This emission band is excited not intracenter mechanism, and through the creation of excitons bound on the defects. It is suggested that it is F-like centers of anionic sublattice induced by the mechanism of elastic collision.

  18. The choriocarcinoma cell line BeWo: syncytial fusion and expression of syncytium-specific proteins. (United States)

    Orendi, Kristina; Gauster, Martin; Moser, Gerit; Meiri, Hamutal; Huppertz, Berthold


    Fusion of the trophoblast-derived choriocarcinoma cell line BeWo can be triggered by forskolin. BeWo cells are regularly used as a cell culture model to mimic in vivo syncytialisation of placental villous trophoblast. The β subunit of human chorionic gonadotropin (CGB), placental alkaline phosphatase as well as placental protein 13 (PP13, LGALS13) are exclusively expressed in the syncytiotrophoblast of the human placenta, and CGB is commonly used as a marker of syncytial differentiation. Here we tested the hypothesis that syncytial fusion precedes CGB and LGALS13 expression in trophoblast-derived BeWo cells. BeWo cells were cultured for 48 h in the presence or absence of forskolin and varying concentrations of H-89, a protein kinase A inhibitor that interferes with the forskolin-mediated pathway of syncytial fusion. LGALS13 and CGB expression were quantified by DELFIA and real-time PCR. Cell fusion was determined by morphological analysis and cell counting after immunofluorescence staining. In forskolin-stimulated BeWo cells that were hindered to fuse by treatment with H-89, levels of CGB protein expression were not altered, while LGALS13 protein and mRNA expression decreased significantly to control levels without forskolin. The LGALS13 protein expression data coincided with a significant decrease in syncytial fusion, while CGB protein expression was unaffected by rates of cell fusion and proliferation. We postulate that CGB protein expression is not necessarily linked to syncytial fusion, and thus CGB should be used with great caution as a marker of BeWo cell fusion.

  19. Humidity sensing properties of WO{sub 3} thick film resistor prepared by screen printing technique

    Energy Technology Data Exchange (ETDEWEB)

    Garde, Arun S, E-mail:


    Highlights: • Polycrystalline WO{sub 3} Thick films are fabricated by screen printing technique. • Monoclinic phases were the majority in formation of films. • The peak at 1643 cm{sup −1} shows stretching vibrations attributed to W-OH of adsorbed H{sub 2}O. • Absorption peaks in the range 879–650 cm{sup −1} are attributed to the stretching W-O-W bonds. • Increase in resistance with decrease in RH when exposed to 20–100% RH. - Abstract: Thick films of tungsten oxide based were prepared using standard screen printing technique. To study the effect of temperature on the thick films were fired at different temperature for 30 min in air atmosphere. The WO{sub 3} thick films were characterized with X-ray diffraction, scanning electron microscopy and EDAX for elemental analysis. The formation of mixed phases of the film together with majority of monoclinic phase was observed. IR spectra confirm the peak at 1643 cm{sup −1} clearly shows stretching vibrations attributed to the W-OH bending vibration mode of the adsorbed water molecules. The absorption peaks in the range 879–650 cm{sup −1} are attributed to the stretching W-O-W bonds (i.e. ν [W-O{sub inter}-W]). The peak located at 983 cm{sup −1} belong to W=O terminal of cluster boundaries. A change in the resistance was observed with respect to the relative humidity when the WO{sub 3} thick films were exposed to a wide humidity range of 20–100%. An increasing firing temperature of WO{sub 3} film increases with the sensitivity. The parameters such as sensitivity and hysteresis of the WO{sub 3} film sensors have been evaluated.

  20. Hot-wire chemical vapor deposition of WO{sub 3−x} thin films of various oxygen contents

    Energy Technology Data Exchange (ETDEWEB)

    Houweling, Z. Silvester, E-mail: [Section Nanophotonics – Physics of Devices, Debye Institute for Nanomaterials Science, Utrecht University, Princetonlaan 4, 3584 CC Utrecht (Netherlands); Geus, John W. [Inorganic Chemistry and Catalysis, Utrecht University, Padualaan 8, 3584 CH Utrecht (Netherlands); Schropp, Ruud E.I. [Section Nanophotonics – Physics of Devices, Debye Institute for Nanomaterials Science, Utrecht University, Princetonlaan 4, 3584 CC Utrecht (Netherlands)


    We present the synthesis of tungsten oxide (WO{sub 3−x}) thin films consisting of layers of varying oxygen content. Configurations of layered thin films comprised of W, W/WO{sub 3−x}, WO{sub 3}/W and WO{sub 3}/W/WO{sub 3−x} are obtained in a single continuous hot-wire chemical vapor deposition process using only ambient air and hydrogen. The air oxidizes resistively heated tungsten filaments and produces the tungsten oxide species, which deposit on a substrate and are subsequently reduced by the hydrogen. The reduction of tungsten oxides to oxides of lower oxygen content (suboxides) depends on the local water vapor pressure and temperature. In this work, the substrate temperature is either below 250 °C or is kept at 750 °C. A number of films are synthesized using a combined air/hydrogen flow at various total process pressures. Rutherford backscattering spectrometry is employed to measure the number of tungsten and oxygen atoms deposited, revealing the average atomic compositions and the oxygen profiles of the films. High-resolution scanning electron microscopy is performed to measure the physical thicknesses and display the internal morphologies of the films. The chemical structure and crystallinity are investigated with Raman spectroscopy and X-ray diffraction, respectively. - Highlights: • Synthesis of tungsten oxide thin films of controllable oxygen content. • Partial reduction of WO{sub 3−x} thin films during deposition. • Deposition of layered films with configurations of W, W/WO{sub 3−x}, WO{sub 3}/W/WO{sub 3−x}. • Synthesis of WO{sub 3−x} films with atomic oxygen-to-tungsten ratios between 0.3 and 3.

  1. Development of W/O Microemulsion for Transdermal Delivery of Iodide Ions


    Lou, Hao; Qiu, Ni; Crill, Catherine; Helms, Richard; Almoazen, Hassan


    The objective of this study was to develop a water-in-oil (w/o) microemulsion which can be utilized as a transdermal delivery for iodide ions. Several w/o microemulsion formulations were prepared utilizing Span 20, ethanol, Capryol 90®, and water. The selected formulations had 5%, 10%, 15%, 20%, and a maximum of 23% w/w water content. Potassium iodide (KI) was incorporated in all formulations at 5% w/v. Physicochemical characterizations were conducted to evaluate the structure and stability. ...

  2. An ab initio study of WO sub 3 under pressure up to 30 GPa

    CERN Document Server

    Pagnier, T


    High-pressure polymorphs of WO sub 3 have been studied with a first-principles pseudopotential method. The medium-range (0.01-20 GPa) and high-range (20-30 GPa) polymorphs have been characterized and are compared with recent experimental results. The main new feature is the appearance of a sevenfold coordinated tungsten in the high-pressure polymorph. The subtle phase transitions that were induced from Raman spectra evolutions have not been confirmed. However, changes in the W-O distances and O-W-O and W-O-W angles may explain the changes in Raman spectra.

  3. Study on defects associated with interstitial oxygen in PbWO4 crystal

    Institute of Scientific and Technical Information of China (English)

    Liu Feng-song; Gu Mu; Zhang Rui


    The defects associated with interstitial oxygen in lead tungstate crystals (PbWO4) are investigated by the relativistic self-consistent discrete variational embedded cluster method. The research work is focused on the density of states of interstitial oxygen defects and relational Frankel defects. The transition state method is used to calculate excitation energy of different electron orbits. Simulation results show that the existence of defects related to interstitial oxygen can diminish the bandwidth of the WO2-4 group, and it might produce the green luminescence. Frankel defects associated with interstitial oxygen could result in the absorption at 420nm.

  4. Exposure of WO3 Photoanodes to Ultraviolet Light Enhances Photoelectrochemical Water Oxidation. (United States)

    Li, Tengfei; He, Jingfu; Peña, Bruno; Berlinguette, Curtis P


    Exposure of WO3 photoanodes to sustained irradiation by ultraviolet (UV) light induces a morphology change that enhances the photoelectrochemical (PEC) activity towards the oxygen evolution reaction (OER). A 30% enhancement in photocurrent density at 1.23 V vs RHE was measured despite a nominal change in onset potential. A structural and electrochemical analysis of the films before and after exposure to UV irradiation indicates that a higher film porosity and correspondingly higher specific surface area is responsible for the enhancement in PEC activity. The effect of prolonged UV irradiation on the WO3 films is fundamentally different to that which was previously observed for BiVO4 films.

  5. Structure and morphology of laser-ablated WO{sub 3} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Hussain, O.M.; Swapnasmitha, A.S. [Sri Venkateswara University, Department of Physics, Tirupati (India); John, J.; Pinto, R. [Condensed Matter Physics and Materials Science, Tata Institute of Fundamental Research, Mumbai (India)


    The structure and surface morphology of WO{sub 3} thin films deposited by a laser-ablation technique have been found to be strongly dependent on the deposition conditions and the nature of the substrate. By precisely controlling the substrate temperature and the oxygen partial pressure, amorphous, polycrystalline, nano-crystalline and iso-epitaxial WO{sub 3} thin films were successfully grown. The structure and surface morphological features of the films from X-ray diffraction and atomic force microscopy data are described in relation to the deposition conditions. (orig.)

  6. Hydrothermal synthesis of NiWO4 crystals for high performance non-enzymatic glucose biosensors (United States)

    Mani, Sivakumar; Vediyappan, Veeramani; Chen, Shen-Ming; Madhu, Rajesh; Pitchaimani, Veerakumar; Chang, Jia-Yaw; Liu, Shang-Bin


    A facile hydrothermal route for the synthesis of ordered NiWO4 nanocrystals, which show promising applications as high performance non-enzymatic glucose sensor is reported. The NiWO4-modified electrodes showed excellent sensitivity (269.6 μA mM−1 cm−2) and low detection limit (0.18 μM) for detection of glucose with desirable selectivity, stability, and tolerance to interference, rendering their prospective applications as cost-effective, enzyme-free glucose sensors. PMID:27087561

  7. Hydrothermal preparation of WO3 nanorod arrays and their photocatalytic properties%水热法制备WO3纳米棒阵列及其光催化性能

    Institute of Scientific and Technical Information of China (English)

    郑锋; 郭敏; 张梅


    采用水热法,以 Na2 WO4·2H2 O 为原料,NaCl 为添加剂,直接在氧化铟锡透明导电基底上制备了有序 WO3纳米棒阵列。利用 X 射线衍射、扫描电子显微镜、透射电子显微镜和高分辨透射电子显微镜等手段对制备的纳米棒进行了表征,考察了pH 值对产物形貌、尺寸和取向性的影响。结果表明:单根 WO3纳米棒具有六方单晶结构,随着前驱液 pH 值的增大,平行于基底生长的 WO3纳米棒捆逐渐转变为垂直于基底生长的纳米棒阵列。另外,对制备得到的两种不同取向的 WO3纳米棒结构进行了光催化降解甲基蓝溶液的研究,发现相比于 WO3纳米棒捆结构,纳米棒阵列的光催化性能更高。%WO3 nanorod arrays were prepared on indium tin oxide ( ITO ) substrates by hydrothermal synthesis with Na2 WO4·2H2 O as a raw material and NaCl as an additive. The nanorods were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and high-resolution transmission electron microscopy. The effects of pH values on the morphology, size, and orientation of products were studied. The results show that the single crystalline WO3 nanorod is hexagonal. When the pH value of the precursor solution increases, WO3 nanorod bundles parallel to the substrate turn into nanorod arrays vertical to the substrate. In addition, two different orientation WO3 nanorod structures were investigated by photocatalytic degradation of methyl blue solutions. It is found that the photocatalytic property of WO3 nanorod arrays is better than that of WO3 nanorod bundles.

  8. Direct pumping of four levels lasing materials (United States)

    Goldring, Sharone; Lavi, Raphael; Tal, Alon; Jackel, Steven M.; Lebiush, Eyal; Tzuk, Yitshak; Azoulay, Ehud


    Heat generation and laser performance were studied in Nd:YAG oscillators pumped with a Ti:Sapphire laser in two regimes: band pumping at 802nm and direct pumping at 885nm. Slope efficiencies of 52% and 57%, when pumped at 802nm and 885nm, were obtained, respectively. Heat per unit laser output was found to be 27% lower when pumped at 885nm (direct pumping regime) as compared to traditional band pumping around 808nm.

  9. Proper Sizing of Circulation Pumps

    DEFF Research Database (Denmark)

    Tommerup, Henrik M.; Nørgaard, Jørgen


    , but the results can be applied to Europe in general. Despite the small sample of houses involved in the test, 15 houses, some rather safe conclusions can be drawn from the results, which showed that newly developed pumps with power consumption around 5-8 W, can perform the task of circulating the water...... sufficiently to keep the houses satisfactorily warm during the heating season of the test. The old replaced pumps used 5-10 times more power. In Europe alone, a gradual replacement of the present vastly oversized pumps with such small but sufficient pumps can save the construction of 17 large power plants...... as well as their pollution during operation. Policy measures are proposed of how to ensure that in the future only such energy saving pumps are installed. Furthermore, on the basis of the historic experiences with circulation pumps some con¬clusions are drawn on how to investigate, develop and market new...

  10. Research on synchronous gear pump

    Institute of Scientific and Technical Information of China (English)

    LUAN Zhen-hui


    Based on a comprehensive analysis of the structure and existing problems of the gear pump, provided a structure principle of a synchronous gear pump. The discussions focused on the working principle, construction features and finite element analysis of the hydraulic gear. The research indicates that the new pump has such advantages as lower noise, better distributed flow and a high work pressure, and it can be widely used in hydraulic systems.

  11. Centrifugal pumps and allied machinery

    CERN Document Server

    Anderson, HH


    This book will be of vital interest to all engineers and designers concerned with centrifugal pumps and turbines. Including statistical information derived from 20000 pumps and 700 turbines with capacities of 5gpm to 5000000gpm, this book offers the widest range and scope of information currently available. Statistical analyses suggest practical methods of increasing pump performance and provide valuable data for new design aspects.

  12. Numerical simulation and experimental study of PbWO4/EPDM and Bi2WO6/EPDM for the shielding of {\\gamma}rays

    CERN Document Server

    Song, Chi; Zhang, Quanping; Li, Yintao; Li, Yingjun; Zhou, Yuanlin


    The MCNP5 code was employed to simulate the {\\gamma}ray shielding capacity of tungstate composites. The experimental results were applied to verify the applicability of the Monte Carlo program. PbWO4 and Bi2WO6 were prepared and added into ethylene propylene diene monomer (EPDM) to obtain the composites, which were tested in the {\\gamma}ray shielding. Both the theoretical simulation and experiments were carefully chosen and well designed. The results of the two methods were found to be highly consistent. In addition, the conditions during the numerical simulation were optimized and double-layer {\\gamma}ray shielding systems were studied. It was found that the {\\gamma}-ray shielding performance can be influenced not only by the material thickness ratio but also by the arrangement of the composites.

  13. Cu/WO3-TiO2光催化剂的结构与吸光性能研究%Structure and Photo Absorption Performance of Cu/WO3-TiO2 Photocatalyst

    Institute of Scientific and Technical Information of China (English)

    梅长松; 钟顺和



  14. Morphology-controlled Synthesis of CdWO4 Nanocrystals%CdWO4纳米晶形貌可控合成

    Institute of Scientific and Technical Information of China (English)

    杨琳琳; 王永刚; 魏超; 王玉江; 王晓峰; 徐刚; 韩高荣


    分别以氯化镉、草酸镉、碳酸镉、柠檬酸镉和钨酸钠为原料,在没有采用模板和表面活性剂的条件下,采用水热法可控制备出了钨酸镉纳米颗粒、纳米棒、纳米束和纳米线.利用X射线衍射(XRD)、透射电镜(TEM)、高分辨透射电子显微镜(HRTEM)和选区电子衍射(SAED)对样品进行了表征.结果表明:[WO42-]/[Cd2+]摩尔比、反应时间及先驱体的类型对产物的形貌和尺寸有着重要的影响.%CdWO4 nanoparticles,nanorods,nanobundles,and nanowires were controllably synthesized via a hydrothermal method without any templates and surfactants using CdCl2,CdC2O4,CdCO3,(C6H5O7)2Cd3,and Na2WO4 as raw materials.The as-prepared powders were characterized by XRD,TEM,HRTEM,and SAED.The results showed that the molar ratio of [WO42-]/[Cd2+],reaction time,and the type of precursors had a crucial effect on the morphology and size of the products.

  15. Theoretical Prediction of the Pumping Performance of Dry Pumps (Taking the Scroll Pump and the Screw Pump by Way of Example) (United States)

    Sawada, Tadashi; Ohbayashi, Tetsuro

    Since almost all commercially provided dry pumps are of the positive displacement type, the leak flow through clearance between displacement chambers in the pump is a dominant factor which determines pumping performance. Prediction methods for the pumping performance of dry pumps are explained by comparing it to the scroll pump and the screw pump. The scroll pump has long clearances, but the screw pump has relatively short ones, and the volume of the chambers reduces from the inlet toward the outlet in the scroll pump, but that in the screw pump is kept constant throughout the pumping process. Such a structural difference produces a small difference in the way of treating leak flow. These two methods can be applied to the other dry pumps requiring only minor modification.

  16. Lasers with nuclear pumping

    CERN Document Server

    Melnikov, S P; Sizov, A N; Miley, George H


    This book covers the history of lasers with nuclear pumping (Nuclear Pumped Lasers, NPLs). This book showcases the most important results and stages of NPL development in The Russian Federal Nuclear Center (VNIIEF) as well as other Russian and international laboratories, including laboratories in the United States. The basic science and technology behind NPLs along with potential applications are covered throughout the book. As such, this book: ·         Contains a historical overview of the extensive information developed over the past 40 years of work on NPLs ·         Covers the most important results and stages of NPL development, not just in the Russian Federal Nuclear Center, VNIIEF, but also in other laboratories in Russia, the United States , and some other scattered international laboratories ·         Systematizes the fragmented information accumulated over these years of very active research and development As the first comprehensive discussion of NPLs, students, research...

  17. The terrestrial silica pump.

    Directory of Open Access Journals (Sweden)

    Joanna C Carey

    Full Text Available Silicon (Si cycling controls atmospheric CO(2 concentrations and thus, the global climate, through three well-recognized means: chemical weathering of mineral silicates, occlusion of carbon (C to soil phytoliths, and the oceanic biological Si pump. In the latter, oceanic diatoms directly sequester 25.8 Gton C yr(-1, accounting for 43% of the total oceanic net primary production (NPP. However, another important link between C and Si cycling remains largely ignored, specifically the role of Si in terrestrial NPP. Here we show that 55% of terrestrial NPP (33 Gton C yr(-1 is due to active Si-accumulating vegetation, on par with the amount of C sequestered annually via marine diatoms. Our results suggest that similar to oceanic diatoms, the biological Si cycle of land plants also controls atmospheric CO(2 levels. In addition, we provide the first estimates of Si fixed in terrestrial vegetation by major global biome type, highlighting the ecosystems of most dynamic Si fixation. Projected global land use change will convert forests to agricultural lands, increasing the fixation of Si by land plants, and the magnitude of the terrestrial Si pump.

  18. Novel coupled structures of FeWO4/TiO2 and FeWO4/TiO2/CdS designed for highly efficient visible-light photocatalysis. (United States)

    Bera, Sandipan; Rawal, Sher Bahadur; Kim, Hark Jin; Lee, Wan In


    A quadrilateral disk-shaped FeWO4 nanocrystal (NC) with an average size of ∼35 nm was prepared via hydrothermal reaction. The obtained dark brown FeWO4 NC with a bandgap (Eg) of 1.98 eV was then coupled with TiO2 to form FeWO4/TiO2 composites. The valence band (VB) of FeWO4 (+2.8 eV vs NHE) was more positive than that of TiO2 (+2.7 eV); thus this system could be classified as a Type-B heterojunction. Under visible-light irradiation, 5/95 FeWO4/TiO2 (by wt %) exhibited remarkable photocatalytic activity: the amount of CO2 evolved from gaseous 2-propanol (IP) and the decomposition rate of aqueous salicylic acid (SA) were, respectively, 1.7 and 2.5 times greater than those of typical nitrogen-doped TiO2 (N-TiO2). This unique catalytic property was deduced to arise from the intersemiconductor hole transfer between the VBs of FeWO4 and TiO2. Herein, several experimental evidence were also provided to confirm the hole-transfer mechanism. To further enhance the catalytic efficiency, double-heterojunctioned FeWO4/TiO2/CdS composites were prepared by loading CdS quantum dots (QDs) onto the FeWO4/TiO2 surface. Surprisingly, the catalytic activity for evolving CO2 from IP was 2.6 times greater than that of bare FeWO4/TiO2 and 4.4 times greater than that of N-TiO2, suggesting that both holes and electrons were essential species in decomposing organic compounds.

  19. Diode-pumped laser with improved pumping system (United States)

    Chang, Jim J.


    A laser wherein pump radiation from laser diodes is delivered to a pump chamber and into the lasing medium by quasi-three-dimensional compound parabolic concentrator light channels. The light channels have reflective side walls with a curved surface and reflective end walls with a curved surface. A flow tube between the lasing medium and the light channel has a roughened surface.

  20. Bifunctional MoO3-WO3/Ag/MoO3-WO3 Films for Efficient ITO-Free Electrochromic Devices. (United States)

    Dong, Wenjie; Lv, Ying; Xiao, Lili; Fan, Yi; Zhang, Nan; Liu, Xingyuan


    Dielectric-metal-dielectric (DMD) trilayer films, served as both electrochromic (EC) film and transparent conductor (TC), have exhibited great potential application in low-cost, ITO-free electrochromic devices (ECDs). However, recent reports on the DMD-based ECDs revealed that the response time and the optical modulation properties were not very satisfactory. Here, the mixed MoO3-WO3 materials were first introduced as the dielectric layer to construct an EC-TC bifunctional MoO3-WO3/Ag/MoO3-WO3 (MWAMW) film, which demonstrates strong and broad-band optical modulation in the visible light region, fast color-switching time (2.7 s for coloration and 4.1 s for bleaching), along with high coloration efficiency (70 cm(2) C(-1)). The electrical structure and electrochemical reaction kinetics analysis revealed that the improved EC performances are associated with the increased electron intervalence transition together with the fast charge-transfer and ion-diffusion dynamics.

  1. 33 CFR 157.126 - Pumps. (United States)


    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Pumps. 157.126 Section 157.126... Washing (COW) System on Tank Vessels Design, Equipment, and Installation § 157.126 Pumps. (a) Crude oil must be supplied to the COW machines by COW system pumps or cargo pumps. (b) The pumps under...

  2. Design of Pumps for Water Hydraulic Systems

    DEFF Research Database (Denmark)

    Klit, Peder; Olsen, Stefan; Bech, Thomas Nørgaard


    This paper considers the development of two pumps for water hydraulic applications. The pumps are based on two different working principles: The Vane-type pump and the Gear-type pump. Emphasis is put on the considerations that should be made to account for water as the hydraulic fluid.......KEYWORDS: water, pump, design, vane, gear....

  3. About Variable Speed Heating and Cooling Pumps


    Cătălin Popovici; Jan Ignat


    The present work has the purpose of underlying the advantages of variable speed heating and cooling pumps use for the perspective of general and particular pumping costs and efficiency. The study approaches comparisons between constant flow pumps and variable flow pumps in different given situations and comparatively analyses the pumping costs.

  4. 46 CFR 119.520 - Bilge pumps. (United States)


    ... 46 Shipping 4 2010-10-01 2010-10-01 false Bilge pumps. 119.520 Section 119.520 Shipping COAST... Ballast Systems § 119.520 Bilge pumps. (a) Each vessel must be provided with bilge pumps in accordance... have a portable hand bilge pump that must be: (1) Capable of pumping water, but not...

  5. 46 CFR 154.1135 - Pumps. (United States)


    ... 46 Shipping 5 2010-10-01 2010-10-01 false Pumps. 154.1135 Section 154.1135 Shipping COAST GUARD... Pumps. (a) Water to the water spray system must be supplied by: (1) A pump that is only for the use of the system; (2) A fire pump; or (3) A pump specially approved by the Commandant (CG-522)....

  6. Heat-Powered Pump for Liquid Metals (United States)

    Campana, R. J.


    Proposed thermoelectromagnetic pump for liquid metal powered by waste heat; needs no battery, generator, or other external energy source. Pump turns part of heat in liquid metal into pumping energy. In combination with primary pump or on its own, thermoelectric pump circulates coolant between reactor and radiator. As long as there is decay heat to be removed, unit performs function.

  7. Heat-Powered Pump for Liquid Metals (United States)

    Campana, R. J.


    Proposed thermoelectromagnetic pump for liquid metal powered by waste heat; needs no battery, generator, or other external energy source. Pump turns part of heat in liquid metal into pumping energy. In combination with primary pump or on its own, thermoelectric pump circulates coolant between reactor and radiator. As long as there is decay heat to be removed, unit performs function.

  8. Pumps in wearable ultrafiltration devices: pumps in wuf devices. (United States)

    Armignacco, Paolo; Garzotto, Francesco; Bellini, Corrado; Neri, Mauro; Lorenzin, Anna; Sartori, Marco; Ronco, Claudio


    The wearable artificial kidney (WAK) is a device that is supposed to operate like a real kidney, which permits prolonged, frequent, and continuous dialysis treatments for patients with end-stage renal disease (ESRD). Its functioning is mainly related to its pumping system, as well as to its dialysate-generating and alarm/shutoff ones. A pump is defined as a device that moves fluids by mechanical action. In such a context, blood pumps pull blood from the access side of the dialysis catheter and return the blood at the same rate of flow. The main aim of this paper is to review the current literature on blood pumps, describing the way they have been functioning thus far and how they are being engineered, giving details about the most important parameters that define their quality, thus allowing the production of a radar comparative graph, and listing ideal pumps' features.

  9. Enhanced structural and optical properties of the polyaniline-calcium tungstate (PANI-CaWO4 nanocomposite for electronics applications (United States)

    Sabu, N. Aloysius; Francis, Xavier; Anjaly, Jose; Sankararaman, S.; Varghese, Thomas


    In this article, we report the synthesis and characterization of polyaniline-calcium tungstate nanocomposite, a novel material for potential applications. The PANI-CaWO4 nanocomposite was prepared by in situ oxidative polymerization of aniline in the presence of CaWO4 nanoparticles dispersed in ethanol. Investigations using X-ray diffraction, Fourier-transformed infrared spectroscopy, UV-visible, photoluminescence and Raman spectroscopy confirmed the formation of the nanocomposite of PANI with CaWO4 nanoparticles. Scanning electron microscopy revealed almost uniform distribution of CaWO4 nanoparticles in the polyaniline matrix. These studies also confirmed electronic structure modification as a result of incorporating CaWO4 nanoparticles in PANI. Composite formation resulted in large decrease in the optical band gap and enhanced photoluminescence. The augmented structural, optical and photoluminescence properties of the PANI-CaWO4 nanocomposite can be used to explore potential applications in micro- and optoelectronics. This is the first report presenting synthesis and characterization of the PANI-CaWO4 nanocomposite.

  10. Sensing performance of palladium-functionalized WO{sub 3} nanowires by a drop-casting method

    Energy Technology Data Exchange (ETDEWEB)

    Chávez, F., E-mail: [Department of Physical-Chemical Materials, ICUAP-BUAP, 72000, Puebla (Mexico); Pérez-Sánchez, G.F. [Department of Physical-Chemical Materials, ICUAP-BUAP, 72000, Puebla (Mexico); Goiz, O. [Department of Electrical Engineering, CINVESTAV-IPN, 07360, México, D.F (Mexico); Zaca-Morán, P. [Department of Physical-Chemical Materials, ICUAP-BUAP, 72000, Puebla (Mexico); Peña-Sierra, R.; Morales-Acevedo, A. [Department of Electrical Engineering, CINVESTAV-IPN, 07360, México, D.F (Mexico); Felipe, C. [Department of Biosciences and Engineering, CIIEMAD-IPN, 07340, México, D.F (Mexico); Soledad-Priego, M. [Faculty of Electronics Sciences, FCE, 72000, Puebla (Mexico)


    In this work, we show a simple way to functionalize tungsten oxide nanowires (WO{sub 3}-NWs) using a saturated palladium chloride (PdCl{sub 2}) solution deposited by a drop-casting method. WO{sub 3}-NWs were synthesized by close-spaced chemical vapor deposition (CSVT). The morphological and structural characterizations showed that the diameters of WO{sub 3}-NWs are in the range from 50 to 200 nm with lengths above 10 μm, and correspond to the orthorhombic phase of WO{sub 3}, respectively. The sensor was fabricated using the WO{sub 3}-NWs and tested with hydrogen and volatile organic compounds (VCO's). A comparative study was done on the sensing performance, before and after the Palladium functionalization of the WO{sub 3}-NWs, considering a wide range of gas concentrations and moderate operating temperatures (100–400 °C). The results show that this simple functionalization process significantly increases the sensor sensitivity and reduces the time constants. In addition, it has been shown that at 300 °C the decorated sensor becomes more selective to hydrogen and xylene for all concentrations considered in this research. Finally, the mechanisms involved in improving the gas sensing properties of WO{sub 3}-NWs functionalized with Palladium are discussed.

  11. Hierarchical Bi2WO6 architectures decorated with Pd nanoparticles for enhanced visible-light-driven photocatalytic activities (United States)

    Zhang, Jinniu; Chen, Tianhua; Lu, Hongbing; Yang, Zhibo; Yin, Feng; Gao, Jianzhi; Liu, Qianru; Tu, Yafang


    A new kind of hierarchical Pd-Bi2WO6 architecture decorated with different molar ratios of Pd to Bi, has been fabricated by a hydrothermal process, followed by a chemical deposition method. The photocatalytic activities of the pure Bi2WO6 and Pd-Bi2WO6 nanocatalyst were examined in the degradation of Rhodamine B (RhB) dyes and phenol under visible light. The photocatalytic results showed that the Pd-Bi2WO6 nanocomposites possessed observably enhanced photocatalytic activities. Particularly, the 2.0% Pd loaded Bi2WO6 had the highest photocatalytic activity, exhibiting a nearly complete degradation of 30 mg/L RhB and 10 mg/L phenol within only 50 and 60 min, respectively. In addition, the trapping experiment results indicated that the photo-generated holes (h+) and rad O2- played a crucial role in the degradation of RhB. According to the experimental results, the photocatalytic degradation mechanism of Pd-Bi2WO6 was also proposed. The enhanced photocatalytic activities were ascribed to the combined effects of the highly efficient separation of electrons and holes, improved visible light utilization and increased BET specific surface areas of the Pd-Bi2WO6 nanocomposites.

  12. ZnWO_4 nanocrystals/reduced graphene oxide hybrids:Synthesis and their application for Li ion batteries

    Institute of Scientific and Technical Information of China (English)

    WANG Xiao; LI BoLong; LIU DaPeng; XIONG HuanMing


    ZnWO4,as an environment-friendly and economic material,has the potential for Li ion batteries(LIB)application.In this paper,a facile method has been developed to synthesize ZnWO4supported on the reduced graphene oxide(RGO)to improve its LIB performance.The cuboid-like ZnWO4nanocrystals are prepared by directly adding Na2WO4 powders into the graphene oxide/Zn aqueous solution followed by a hydrothermal treatment.The high-resolution TEM,XRD and XPS characterizations were employed to demonstrate structural information of the as-prepared ZnWO4/RGO hybrids carefully.Besides,we also discussed the LIB properties of the hybrids based on the detailed galvanostatic charge-discharge cycling tests.As a result,the specific capacity of the as-prepared ZnWO4/RGO hybrids reached more than 477.3 mA h g 1after 40 cycles at a current density of 100 mA g 1(only less than 159 mA g 1for bare ZnWO4).During the whole cyclic process,the coulombic efficiency steadily kept the values higher than 90%.

  13. Modification of TiO{sub 2} nanotubes by WO{sub 3} species for improving their photocatalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Hui, E-mail:; Dong, Bohua, E-mail:; Su, Ge, E-mail:; Gao, Rongjie, E-mail:; Liu, Wei, E-mail:; Song, Liang, E-mail:; Cao, Lixin, E-mail:


    Highlights: • WO{sub 3}/titania nanotubes are synthesized at low temperature (383 K) by a novel approach. • WO{sub 3}/titania nanotubes present enhanced photocatalytic activity. • The substitution of Ti{sup 4+} by W{sup 6+} does not occur in nanocomposites at 383 K. • Diffuse reflectance spectra of WO{sub 3}/TNTs exhibit a red shift due to WO{sub 3} connection. • The optimal degradation rate of MO could reach 95% within 2 h irradiation. - Abstract: WO{sub 3}/TiO{sub 2} nanotubular composite was synthesized at low temperature (383 K) by a novel approach. WO{sub 3} nanoparticles were loaded on anatase TiO{sub 2} nanotubes through the reaction between (NH{sub 4}){sub 6}W{sub 7}O{sub 24}·6H{sub 2}O and aqueous solution of HCl. The obtained products were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and UV–vis diffuse reflectance spectroscopy (UV-DRS). Degradation of methyl orange was employed to investigate the photocatalytic activity of the products. Results show that, among the samples with different concentrations of WO{sub 3}, W{sub 10}T with the atomic ratio W/Ti of 10% presents optimal degradation rate. This degradation rate is about 95% within 2 h under UV light irradiation, which is much higher than that of pure TiO{sub 2} nanotubes.

  14. Reduced graphene oxide wrapped Bi2WO6 hybrid with ultrafast charge separation and improved photoelectrocatalytic performance (United States)

    Wang, Huan; Liang, Yinghua; Liu, Li; Hu, Jinshan; Cui, Wenquan


    A reduced graphene oxide (rGO) wrapped Bi2WO6 (Bi2WO6@rGO) hybrid as photoelectrode for enhanced photoelectrocatalytic (PEC) degradation of organic pollutants is reported, which exhibited excellent charge separation and photoconversion efficiency. The core@shell structured Bi2WO6@rGO photoelectrode yielded a pronounced 1.56-fold and 23.8-fold photocurrent density at 1.0 V vs. saturated calomel electrode (SCE), than that of loading structured Bi2WO6-rGO and pure Bi2WO6. The Bi2WO6@rGO hybrid exhibited enhanced photoelectrocatalytic efficiency for degradation of Rhodamine B (RhB), which was 43.0% and 65.6% higher than that of photocatalytic (PC) and electrocatalytic (EC) processes, respectively. The enhancement in PEC degradation of RhB benefited from: (1) a strong interaction and a wide range of conjugation were formed in the core@shell system; (2) a 0.26 V of flat band potential was negatively shifted in case of Bi2WO6@rGO composite; (3) the photogenerated electrons and holes could be spatially separated by external electric potentials.

  15. Improved WO3 photocatalytic efficiency using ZrO2 and Ru for the degradation of carbofuran and ampicillin. (United States)

    Gar Alalm, Mohamed; Ookawara, Shinichi; Fukushi, Daisuke; Sato, Akira; Tawfik, Ahmed


    The photocatalytic degradation of carbofuran (pesticide) and ampicillin (pharmaceutical) using synthesized WO3/ZrO2 nanoparticles under simulated solar light was investigated. Transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectra analyses were used to characterize the prepared catalysts. The optimum ratio of WO3 to ZrO2 was determined to be 1:1 for the degradation of both contaminants. The degradation of carbofuran and ampicillin by WO3/ZrO2 after 240 min of irradiation was 100% and 96%, respectively. Ruthenium (Ru) was employed as an additive to WO3/ZrO2 to enhance the photocatalytic degradation rate. Ru/WO3/ZrO2 exhibited faster degradation rates than WO3/ZrO2. Furthermore, 100% and 97% degradation of carbofuran and ampicillin, respectively, was achieved using Ru/WO3/ZrO2 after 180 min of irradiation. The durability of the catalyst was investigated by reusing the same suspended catalyst, which achieved 92% of its initial efficiency. The photocatalytic degradation of ampicillin and carbofuran followed pseudo-first order kinetics according to the Langmuir-Hinshelwood model.

  16. Structural phototransformation of WO{sub 3} thin films detected by photoacoustic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Pacheco, Argelia Perez, E-mail: [Universidad Nacional Autonoma de Mexico, Laboratorio de Fotofisica y Peliculas Delgadas-CCADET, Ciudad Universitaria, Coyoacan, A.P. 70-186, C.P. 04510, Mexico, D.F. (Mexico); Montes de Oca, C. Oliva; Castaneda-Guzman, R.; Garcia, A. Esparza [Universidad Nacional Autonoma de Mexico, Laboratorio de Fotofisica y Peliculas Delgadas-CCADET, Ciudad Universitaria, Coyoacan, A.P. 70-186, C.P. 04510, Mexico, D.F. (Mexico)


    Highlights: Black-Right-Pointing-Pointer The phototransformation of WO{sub 3} thin films were studied by photoacoustic technique. Black-Right-Pointing-Pointer The phase transition in WO{sub 3} thin films was induced by laser irradiation fluence. Black-Right-Pointing-Pointer The onset and end of the phototransformation in the thin films was identified. Black-Right-Pointing-Pointer The ablation threshold for each sample was identified. - Abstract: The photoacoustic technique (PA) was used to detect the phase transformation from amorphous to crystalline state of tungsten oxide (WO{sub 3}) thin films induced by UV pulsed laser radiation at low energy (<1.5 mJ). The evolution of photoacoustic signal was studied by a correlation analysis, comparing successive signals at fluences ranging from 0 to 20 mJ/cm{sup 2}. In this interval, it was possible to observe structural changes and the ablation threshold in films due to incident laser fluence effect. Thin films of WO{sub 3} were deposited by DC reactive magnetron sputtering over glass substrates at different deposition times. The results obtained by correlation analysis were compared with Raman spectroscopy data.

  17. Hydrothermal synthesis of hierarchical WO{sub 3} nanostructures for dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Rashad, M.M. [Central Metallurgical Research and Development Institute (CMRDI), Helwan, P.O. Box 87, Cairo (Egypt); Shalan, A.E. [Central Metallurgical Research and Development Institute (CMRDI), Helwan, P.O. Box 87, Cairo (Egypt); Friedrich-Alexander-University of Erlangen-Nuremberg, Institute of Materials for Electronics and Energy Technology (i-MEET), Erlangen (Germany)


    Hierarchical architectures consisting of one-dimensional (1D) nanostructures are of great interest for potential use in energy and environmental applications in recent years. In this work, hierarchical tungsten oxide (WO{sub 3}) has been synthesized via a facile hydrothermal route from ammonium metatungstate hydrate and implemented as photoelectrode for dye-sensitized solar cells. The urchin-like WO{sub 3} micro-patterns are constructed by self-organized nanoscale length 1D building blocks, which are single crystalline in nature, grown along (001) direction and confirm an orthorhombic crystal phase. The obtained powders were investigated by XRD, SEM, TEM and UV-Vis Spectroscopy. The photovoltaic performance of dye-sensitized solar cells based on WO{sub 3} photoanodes was investigated. With increasing the calcination temperature of the prepared nanopowders, the light-electricity conversion efficiency (η) was increased. The results were attributed to increase the crystallinity of the particles and ease of electron movement. The DSSC based on hierarchical WO{sub 3} showed a short-circuit current, an open-circuit voltage, a fill factor, and a conversion efficiency of 4.241 mA/cm{sup 2}, 0.656 V, 66.74, and 1.85 %, respectively. (orig.)

  18. WoSIS: providing standardised soil profile data for the world (United States)

    Batjes, Niels H.; Ribeiro, Eloi; van Oostrum, Ad; Leenaars, Johan; Hengl, Tom; Mendes de Jesus, Jorge


    The aim of the World Soil Information Service (WoSIS) is to serve quality-assessed, georeferenced soil data (point, polygon, and grid) to the international community upon their standardisation and harmonisation. So far, the focus has been on developing procedures for legacy point data with special attention to the selection of soil analytical and physical properties considered in the GlobalSoilMap specifications (e.g. organic carbon, soil pH, soil texture (sand, silt, and clay), coarse fragments ( definitions, soil property values, and soil analytical method descriptions. At the time of writing, the full WoSIS database contained some 118 400 unique shared soil profiles, of which some 96 000 are georeferenced within defined limits. In total, this corresponds with over 31 million soil records, of which some 20 % have so far been quality-assessed and standardised using the sequential procedure discussed in this paper. The number of measured data for each property varies between profiles and with depth, generally depending on the purpose of the initial studies. Overall, the data lineage strongly determined which data could be standardised with acceptable confidence in accord with WoSIS procedures, corresponding to over 4 million records for 94 441 profiles. The publicly available data - WoSIS snapshot of July 2016 - are persistently accessible from ISRIC WDC-Soils through doi:10.17027/isric-wdcsoils.20160003.

  19. Novel rib structures in Yb-doped KY(WO4)2 for laser applications

    NARCIS (Netherlands)

    Gardillou, F.; Borca, C.N.; Romanyuk, Y.E.; Hibert, C.; Salathé, R.P.; Pollnau, Markus


    We report for the first time, on the fabrication of flexible refractive-index-contrast rib waveguides based on Yb-doped $KY(WO_4)_2$ epilayers. These results pave the way for integrated optical circuits in this promising material.

  20. Phase modification and surface plasmon resonance of Au/WO{sub 3} system

    Energy Technology Data Exchange (ETDEWEB)

    Bose, R. Jolly; Kavitha, V.S. [Department of Optoelectronics, University of Kerala, Kariyavattom, Thiruvananthapuram 691574, Kerala (India); Sudarsanakumar, C. [School of Pure and Applied Physics, Mahatma Gandhi University, Priyadarshini Hills, Kottayam 686560, Kerala (India); Pillai, V.P. Mahadevan, E-mail: [Department of Optoelectronics, University of Kerala, Kariyavattom, Thiruvananthapuram 691574, Kerala (India)


    Highlights: • We have investigated the role of gold as catalyst and nucleation centers, for the crystallization and phase modification of tungsten oxide, in Au/WO{sub 3} matrix. • The phase change from triclinic WO{sub 3} to monoclinic W{sub 18}O{sub 49} is found to enhance with gold incorporation. • The surface plasmon resonance is observed in gold/tungsten oxide system with the appearance of an absorption band near the wavelength 604 nm. - Abstract: We report the action of gold as catalyst for the modification of phase from triclinic WO{sub 3} to monoclinic W{sub 18}O{sub 49} and nucleation centre for the formation of W{sub 18}O{sub 49} phase, in gold incorporated tungsten oxide films prepared by RF magnetron sputtering technique. A new band is observed near 925 cm{sup −1} in the Raman spectra of gold incorporated tungsten oxide films which is not observed in the pure tungsten oxide film. The intensity of this band enhances with gold content. A localized surface plasmon resonance (LSPR) band is observed near the wavelength 604 nm in gold incorporated tungsten oxide films. The integrated intensities of LSPR band and Raman band (∼925 cm{sup −1}) can be used for sensing the quantity of gold in the Au/WO{sub 3} matrix.