Polarographic behaviour and determination of selenite and tellurite in simple solutions or in a binary mixture

International Nuclear Information System (INIS)

Hassan, A.

1991-01-01

The polarographic behaviour of simple solutions of selenite and tellurite in 1 M ammonium salts of formate, acetate, tartrate, oxalate, and benzoate solutions in absence and in presence of Triton X-100 as a maximum suppressor and a temperature of 25 O C has been investigated. Schemes for the mechanism of reductions occuring at the DME have been deduced. A method for analytical determination of selenite and tellurite in simple solutions as well as in a binary mixture in the presence of 4-14 . 10 -3 % Triton X-100 is reported. (author)

Determination of microamounts of neptunium by differential pulse polarography

International Nuclear Information System (INIS)

Cauchetier, Ph.

1979-01-01

Neptunium is produced in significant amounts in the ''light-water'' reactors and must be controlled at different steps of fuel reprocessing. For this purpose a method of differential pulse polarography has been developed. A tight cell containing 10 ml solution is set up in a Faraday cage. Adjustment to the tetravalent state, Np(IV), is carried out electrochemically on a mercury layer and the Np(IV) concentration is determined by differential pulse polarography, using a dropping mercury electrode. In 0.5M sulfuric acid medium, the redox potential of the reversible couple Np(IV)/Np(III) is -0.3 V/SCE. Concentrations as low as 5x10 -7 M neptunium can be measured and detection at the 2x10 -7 M level is still possible (0.5 μg in the polarographic cell). Precision is about 2% in the 10 -5 M and 10% in the 10 -6 M range. The method has been applied to aqueous and organic (TBP-dodecane) solutions. Neptunium can be determined without separation in the presence of plutonium or uranium at M/Np ratios of 10 3 and 5x10 4 , respectively. In the presence of fission products a separation is needed. (author)

Determination of microamounts of neptunium by differential pulse polarography

International Nuclear Information System (INIS)

Cauchetier, P.

1978-01-01

Neptunium is produced in significant amounts in the light water reactors and must be controlled at different steps of the fuel reprocessing. For this purpose, a method of differential pulse polarography was developed. A tight cell containing 10 ml of solution is set up in a Faraday's cage. Adjustment to the tetravalent state, Np (IV), is carried out electrochemically on a mercury layer and the Np (IV) concentration is determined by differential pulse polarography, using a dropping mercury electrode. In 0,5 M sulfuric acid medium, the redox potential of the reversible system Np (IV)/Np (III) is - 0,3 V/SCE. Concentrations as low as 5.10 -7 M of neptunium can be measured and detection at the 2.10 -7 M level is still possible (0,5 μg in the polarographic cell). Precision is about 2% in the 10 -5 M and 10% in 10 -6 M range. The method has been applied to the case of aqueous and organic (TBP dodecane) solutions. Neptunium can be determined without separation in the presence of plutonium or uranium in the M/Np ratios of 10 3 and 5.10 4 respectively. In the presence of fission products a separation is needed

The contents of sesamol and related lignans in sesame, tahina and halva as determined by a newly developed polarographic and stripping voltammetric analysis

Energy Technology Data Exchange (ETDEWEB)

Tokusoglu, O.; Kocak, S.; Aycan, S.

2009-07-01

The contents of antioxidant lignans (Sesamol) in sesame, commercial formulations of tahina and halva, which are processed tahina foods, were determined by Differential Pulse Polarography (DPP) with a capillary hanging mercury drop electrode (HMDE). A platinum wire was used as the counter electrode and Ag/AgCl was the reference electrode. Samples have been analyzed by standard addition procedures and found to be quantitative (p<0.01). Due to the fact that sesamol is an oil-soluble phenolic compound , it was found in the oil levels of sesame, tahina and halvas. Sesame samples contained 51.05-56.46 % in oil whereas tahina samples contained 52.12-53.79 % in oil. The oil percentage of plain halva was found to be 28.79 - 30.13 % (p<0.01). Phenolic lignans sesamol in sesame was 0.26-0.32 mg/100g oil, whereas the sesamol in tahina was 10.98-12.33 mg/100g oil. The sesamol in commercial plain halva samples and the open marketed plain halva samples contained 8.24-9.12 mg/100g oil and 4.97 mg sesamol /100g oil, respectively (R{sup 2}=0.9999) (p<0.01). The proposed Differential Pulse Polarographic (DPP) method is a rapid, reproducible procedure for the simultaneous determination of phenolic lignans in sesame and food products with sesame. It provides an adequate, sensitive, quantitative detection of these nutraceuticals in the commercial food industry. (Author) 26 refs.

Oxygen tension and prediction of the radiation response. Polarographic study in human breast cancer

International Nuclear Information System (INIS)

Pappova, N.; Siracka, E.

1982-01-01

Serial polarographic measurement of the tissue oxygen tension (pO 2 ) was made in the course of fractionated irradiation (preoperative or sole treatment) of advanced breast cancer in 24 patients. In responsive tumors an increase in pO 2 appeared sooner before expressive tumor size reduction became noticeable. Repeated recording of unchanged pO 2 values proved to be a good prognostic indicator of local failure. The study made on this tumor model showed that serial polarographic pO 2 determinations with suitable electrodes causing minimal trauma and providing consistent and reproductive data about changes in tumor microcirculation and oxygenation may enlarge the scale of indicators of radiation response. (author)

Determination of uranium in plutonium--238 metal and oxide by differential pulse polarography

International Nuclear Information System (INIS)

Fawcett, N.C.

1976-01-01

A differential pulse polarographic method was developed for the determination of total uranium in 238 Pu metal and oxides. A supporting electrolyte of 0.5 M ascorbic acid in 0.15 N H 2 SO 4 was found satisfactory for the determination of 500 ppM or more of uranium in 10 mg or less of plutonium. A relative standard deviation of 0.27 to 4.3 percent was obtained in the analysis of samples ranging in uranium content from 0.65 to 2.79 percent. The limit of detection was 0.18 μg ml -1 . Peak current was a linear function of uranium concentration up to at least 100 μg ml -1 . Amounts of neptunium equal to the uranium content were tolerated. The possible interference of a number of other cations and anions were investigated

Polarographic, spectrophotometric and coulometric studies of MoO=4 in H2SO4

International Nuclear Information System (INIS)

Tokoro, R.; Bertotti, M.

1990-01-01

This study characterizes the polarographic process of Mo O sup(=) sub(4) in H sub(2)SO sub(4) medium, determining which species is responsible by catalytic cycle. Spectrophotometric and coulometric studies are also described. (author)

Polarographic determination of Iodide and Iodate, in Solutions Coming from Aerosols in Fission Products Containment Studies in Nuclear Power Stations; Determinacion Polarografica de Especies de Iodo (Ioduro y Iodato) en Soluciones Procedentes de Aerosoles, para Estudios de Contencion de Productos de Fision en Centrales Nucleares

Energy Technology Data Exchange (ETDEWEB)

Sanchez, M.; Ballesteros, O.; Fernandez, M.; Clavero, M.; Gonzalez, A. M. [Ciemat, Madrid (Spain)

2000-07-01

A polarographic method is described for the iodine species determination, iodide and iodate in water solutions. the iodate can be determined by differential pulse polarography. Calibration curves and the detection and determination limits have been obtained. Iodides is oxidized to iodate with sodium hypochlorite and the excess of oxidizing agent is destroyed with sodium sulphide. The concentration of iodide is calculated as the difference between the concentration of iodate in the sample before and after the oxidation. As an application, species of iodine in samples coming from the experimental plants GIRS (Gaseous Iodine Removal by Sprays) of Nuclear Fission Department of the CIEMAT, dedicated to fission products containment studies in nuclear power station, were determined. (Author) 10 refs.

Determination of Sn in 99mTc Radiopharmaceutical Kits by Polarographic Methods

International Nuclear Information System (INIS)

Castro, M.; Cruz, J.; Sanchez, M.

2009-01-01

Kits of 99 m Tc radiopharmaceuticals are used in nuclear medicine for diagnosis of different diseases. Sn (II) is one of the essential components in their formulations, which is used for reduction 99 m Tc-pertechnetate in cold kits for on-site preparation 99 m Tc-pertechnetate radiopharmaceuticals. Usually, these cold kits contain different additives (complexing agents, antioxidants, buffers, etc.) and the amount of Sn (II) varies from kit to kit. The determination of Sn in these products is essential in assessing their quality. We report here the development of a new polarographic method for the determination of Sn (II) and total Sn in representative radiopharmaceuticals kits (for the content of Sn and chemical composition) produced at the Center of Isotopes of Cuba (CENTIS). These methods were validated by analysis of variance and recovery techniques. From the results of the validation, the characteristic functions of uncertainties and fits are considered for the established methods, which give the necessary evidences to demonstrate the usefulness of these methods according to the current trends in Analytical Chemistry. This work provides practical results of great importance for CENTIS. After the speciation of Sn in the MAG3 radiopharmaceuticals kit is inferred that the production process is affected by uncontrolled factors that influence in the product stability, which demonstrates the necessity for analytical tools for the characterization of products and processes. (Author) 57 refs.

Linear sweep polarographic determination of nucleic acids using acridine orange as a bioprobe

Directory of Open Access Journals (Sweden)

WEI SUN

2007-11-01

Full Text Available The interaction of acridine orange (AO with double-stranded (ds DNA in aqueous solution was investigated by linear sweep polarography (LSP on a dropping mercury working electrode (DME. In pH 2.5 Britton–Robinson (B–R buffer solution, AO had a sensitive linear sweep polarographic reductive peak at –0.89 V (vs. SCE, which could be greatly inhibited by the addition of dsDNA, with a positive shift of the peak potential. Based on the decrease of the reductive peak current, a new quantitative electrochemical determination method for dsDNA was developed with a linear range of 2.0−20.0 mg l-1 and the linear regression equation: ΔIp” (nA = 111.90 C (mg l-1+125.32 (n = 9, γ = 0.997. The influences of commonly co-existing substances, such as metal ions, amino acid, etc., on the determination were also investigated. The method is sensitive, rapid and simple with good selectivity. The new proposed method was further applied to the detection of RNA and three synthetic samples containing dsDNA with satisfactory results. The binding number and the equilibrium constant between dsDNA and AO were calculated by an electrochemical method.

Copper separation using modified active carbon before the polarographic determination of Pb, Cd, Ni, Zn and Fe in wastes

International Nuclear Information System (INIS)

Rubel, S.; Lada, Z.M.; Golimowski, J.

1977-01-01

The investigations on the selective separation of Pb 2+ , Cd 2+ , Ni 2+ , Zn 2+ and Fe 3+ ions from the excess of copper were carried out. For this purpose active carbon modified by Na-diethyldithiocarbamate was used. The manner of DDTK-Na deposition on active carbon has been elaborated. The influence of pH was investigated and it was found that at pH 1(HNO 3 ) copper ions are quantitavely bound on modified carbon whereas other ions (Pb 2+ , Cd 2+ , Ni 2+ , Zn 2+ and Fe 3+ ) remain in the solution and can be determined polarographically. The elaborated method was applied to the determination of mentioned ions in the samples of wastes containing even 100-fold excess of copper. The concentration of copper can not exceed 100 mg/dm 3 . (author)

Investigation of complexing equilibrium of polyacrylate-anion with cadmium ions by polarographic method

Energy Technology Data Exchange (ETDEWEB)

Avlyanov, Zh K; Kabanov, N M; Zezin, A B

1985-01-01

Polarographic investigation of cadmium complex with polyacrylate-anion in aqueous KCl solution is carried out. It is shown that the polarographic method allows one to define equilibrium constants of polymer metallic complex (PMC) formation even in the case when current magnitudes are defined by PMC dissociation reaction kinetic characteristics. The obtained equilibrium constants of stepped complexing provide the values of mean coordination PAAxCd complex number of approximately 1.5, that coincides with the value obtained by the potentiometric method.

Investigation of complexing equilibrium of polyacrylate-anion with cadmium ions by polarographic method

International Nuclear Information System (INIS)

Avlyanov, Zh.K.; Kabanov, N.M.; Zezin, A.B.

1985-01-01

Polarographic investigation of cadmium complex with polyacrylate-anion in aqueous KCl solution is carried out. It is shown that the polarographic method allows one to define equilibrium constants of polymer metallic complex (PMC) formation even in the case, when current magnitudes are defined by PMC dissociation reaction kinetic characteristics. The obtained equilibrium constants of stepped complexing provide the values of mean coordination PAAxCd complex number of approximately 1.5, that coinsides with the value obtained by the potentiometric method

Polarographic methods for the analysis of beryllium metal and its alloys

International Nuclear Information System (INIS)

Wells, J.M.

1975-10-01

This report describes polarographic methods for the analysis of beryllium metal and its alloys. The elements covered by these methods are aluminium, bismuth, cadmium, cobalt, copper, iron, lead, molybdenum, nickel, thallium, tungsten, uranium, vanadium and zinc. (author)

Assay of Aliphatic Phthalates in Polymer Products by Sensitive Polarographic Method: Health and Environmental Issue

Directory of Open Access Journals (Sweden)

Munawar Saeed

2010-06-01

Full Text Available A faster, simpler and sensitive method was developed for determination of aliphatic phthalates using differential pulse polarography (DPP as standard technique. The choice and concentration of base electrolyte, solvent, initial potential, effect of water addition and interference by other phthalates were the main parameters to optimize for enhancement of peak current and to obtain well-defined polarogram with lower background current using 1.3 x 10-4 M di-butyl phthalate (DBP solution. Best results were obtained in the presence of tetra methyl ammonium bromide (TMAB as electrolyte in methanol solvent with initial potential, -1.4 V. A linear calibration plot was observed in the range of 3 x 10-7 – 1.6 x 10-4 M DBP solution as aliphatic phthalates with lower detection limit of 5.9 x 10-8 M and linear regression coefficient of 0.9987. The developed polarographic method was successfully applied for analysis of aliphtaic phthalates in various samples of locally available polymer products such as baby toys, nipples, teethers, infusion blood bags and shopping bags. The results of the current method were compared with those obtained by a reported method and good agreement was found between them.

Polarographic reduction of Yb/sup +3/ benzoate and salicylate complexes in aqueous-nonaqueous mixtures at D. M. E

Energy Technology Data Exchange (ETDEWEB)

Zutshi, K; Gupta, K C [Rajasthan Univ., Jaipur (India). Dept. of Chemistry

1977-01-01

The reduction of Yb/sup +3/ and Yb/sup +3/-benzoate and salicylate complexes was studied polarographically at constant ionic strength at 25 +- 0.02/sup 0/C in aqueous-nonaqueous mixtures. The reduction was found to be diffusion-controlled, but the electrode process was irreversible in all cases. The kinetic parameters were determined by Koutecky's method.

Preconcentration of trace uranium from seawater with solid phase extraction followed by differential pulse polarographic determination in chloroform eluate

International Nuclear Information System (INIS)

Dojozan, Dj.; Pournaghi-Azar, M.H.; Toutounchi-Asr, J.

1998-01-01

In the present study, an effective method is presented for the separation and preconcentration of uranium (VI) by solid phase extraction (SPE). For this purpose, U(VI) oxinate is formed by the reaction of U(VI) with 8-hydroxyquinoline and adsorbed onto the octylsilane (C-8) SPE cartridge. The analyte is completely eluted with chloroform and determined by differential pulse polarography. The SPE conditions were optimized by evaluating the effective factors such as pH, oxine concentration, type and concentration of buffer and masking agent. By the proposed method a preconcentration factor of more than 100 was achieved. The average recovery of uranium (VI) oxinate (0.1 mg l -1 ) was 99.8%. The relative standard deviation was 1.6% for seven replicate determinations of uranyl ion in the solution with a concentration 20 μg l -1 . Some concomitant ions such as Ca +2 , Mg +2 and Fe +3 which interfere in extraction or determination process of uranium were masked with EDTA in aqueous phase during the extraction process. The proposed method was successfully used for the determination of uranium in Caspian Sea and Persian Gulf water samples

Polarographic measurement of ascorbate washout in isolated perfused rabbit hearts

International Nuclear Information System (INIS)

Arts, T.; Kuikka, J.T.; Reneman, R.S.; Bassingthwaighte, J.B.

1985-01-01

To study the myocardial washout of ascorbate, the applicability of polarographic detection of ascorbate ions by a platinum electrode (sensitive area 0.03 mm2) was investigated, in both a calibration setup (sampling flow along the electrode: 100 microliter X s-1) and isolated, retrogradely perfused rabbit hearts. In the calibration setup at pH 7.4, the sensitivity of the electrode was 70 microA/mol. This sensitivity increased moderately with increasing pH (13%/unit pH) and increasing sampling flow rate (14% at an increase from 100 to 150 microliter X s-1). In the isolated hearts, ascorbate infused into the aorta was detected in a right ventricular drain by the electrode as well as by the use of 14 C-labeled ascorbate. Both recorded time courses were similar except for a scaling factor dependent on flow velocity. During continuous infusion the arteriovenous difference of ascorbate was 2 +/- 2% (SD), indicating a relatively low consumption of ascorbate by the isolated heart. The authors conclude that polarographic measurement of ascorbate in the coronary effluent of an isolated rabbit heart can be performed on-line and relatively easily

Oxygen tension in human tumours measured with polarographic needle electrodes and its relationship to vascular density, necrosis and hypoxia

International Nuclear Information System (INIS)

Lyng, Heidi; Sundfoer, Kolbein; Rofstad, Einar K.

1997-01-01

Background and purpose: The use of polarographic needle electrodes for measurement of oxygen tension (pO 2 ) in tumours requires documentation of the validity of the method. In the present work the pO 2 values measured polarographically with the Eppendorf pO 2 histograph in human tumours were compared with the histological appearance of the tumour tissue, i.e. vascular density, fraction of necrosis and fraction of hypoxic tissue, to investigate whether the measurements reflected the expected pO 2 . Materials and methods: The pO 2 was measured in cervix tumours in patients and in human melanoma xenografted tumours in athymic mice. Vascular density was determined in the cervix tumours by histological analysis of biopsies from the pO 2 measurement tracks. Fraction of necrosis and fraction of hypoxic tissue, i.e. tissue binding the hypoxia marker pimonidazole, were determined in the melanomas by analysis of histological sections from the tumour planes in which the pO 2 measurements were performed. Results: The pO 2 distributions showed large intratumour heterogeneity. In cervix tumours, tumour regions with vascular density (vascular length per unit tissue volume) in the range of 47-77 mm/mm 3 showed higher pO 2 than tumour regions with vascular density in the range of 20-47 mm/mm 3 , which in turn showed higher pO 2 than tumour regions with vascular density in the range of 0-20 mm/mm 3 . In melanomas, tumour regions in which necrosis and hypoxia constituted more than 50% of the tissue showed lower pO 2 than other tumour regions. Conclusions: The pO 2 measured in the tumours was consistent with the histological appearance of the tissue in which the measurements were performed, suggesting that reliable pO 2 distributions of tumours can be obtained with polarographic needle electrodes

Polarographic study of Cd(II)-Schiff base complexes and d.m.e. menthanol-water medium

International Nuclear Information System (INIS)

Patel, M.S.; Trivedi, T.; Vyas, D.N.

1978-01-01

Three Schiff base complexes of Cd 2+ have been investigated polarographically in 60% menthanol-water medium at 26 0 C. The Schiff bases used are salicyladehyde tris buffer (ST), benzaldehydetris buffer (BT) and vanillin tris buffer (VT). Cd-ST and Cd-VT complexes produce reversible reduction wave at dme, while Cd-BT gives a quasi reversible wave. Stability constants of the complexes have been determined and the standard overall electrode reaction rate constant (ksub(e)sup(o)) B of the Cd-BT complex is determined by three different methods. The log β values of complexes are : Cd-ST, 2.72; Cd-VT, 4.90; and Cd-BT, 4.41. (author)

Calibration and testing of a polarographic sensor for the measurement of oxygen in seawater

Energy Technology Data Exchange (ETDEWEB)

Boniforti, R; Dell' Amico, F; Marri, P

1987-04-01

The procedures for the calibration and testing of a polarographic oxygen sensor, mounted on a CTD probe, are reported. As an example of in-field use, oxygen and temperature profiles obtained in Fossa del Pomo (Central Adriatic Sea), are given.

Direct determination of molybdenum in seawater by adsorption cathodic stripping square-wave voltammetry.

Science.gov (United States)

Sun, Y C; Mierzwa, J; Lan, C R

2000-06-30

A reliable and very sensitive procedure for the determination of trace levels of molybdenum in seawater is proposed. The complex of molybdenum with 8-hydroxyquinoline (Oxine) is analyzed by cathodic stripping square-wave voltammetry based on the adsorption collection onto a hanging mercury drop electrode (HMDE). This procedure of molybdenum determination was found to be more favorable than differential pulse cathodic stripping voltammetry because of inherently faster scan rate and much better linearity obtained through the one-peak (instead of one-of-two peaks) calibration. The variation of polarographic peak and peak current with a pH, adsorption time, adsorption potential, and some instrumental parameters such as scan rate and pulse height were optimized. The alteration of polarographic wave and its likely mechanism are also discussed. The relationship between peak current and molybdenum concentration is linear up to 150 mug l(-1). Under the optimal analytical conditions, the determination limit of 0.5 mug l(-1) Mo was reached after 60 s of the stirred collection. The estimated detection limit is better than 0.1 mug l(-1) of Mo. The applicability of this method to analysis of seawater was assessed by the determination of molybdenum in two certified reference seawater samples (CASS-2 and NASS-2) and the comparison of the analytical results for real seawater samples (study on a vertical distribution of Mo in the seawater column) with the results obtained by Zeeman-corrected electrothermal atomization atomic absorption spectrometry (Zeeman ETAAS). A good agreement between two used methods of molybdenum determination was obtained.

Polarographic studies about indium (III) behaviour in aqueous media of sodium azide

International Nuclear Information System (INIS)

Tokoro, R.

1988-01-01

The present study shows some polarographic behavior of indium (III) in azide media that is close those observed in a thiocyanate solution. The presence of azide ligand decreases the overpotential in the discharge of indium whose catalytic character can be explained by formation of an azide bridge between electrode and indium (III) increasing the speed of electron transfer. The discharge of indium in azide media is diffusion controlled. As the azide concentration is increased the half wave potential displaces in the cathodic direction. This displacement is due to complex formation. The number of electrons, n, involved in the total process was estimates by the reversible polarographic equation to be 2,7. The potentiostatic coulometry of indium in azide/hydrazoic acid buffer showed a catalytic process where the chemistry regeneration was performed by reaction of hydrazoic acid and indium amalgam. The electrochemistry evidence was the constancy of current as the electrolysis proceeded. The chemistry aspect was the presence of ammonium cation in electrolysed solution. The catalytic process with chemistry regeneration and the formation of a bridge by azide could explain the higher value of current in azide media compared to perchlorate solution. (author) [pt

Iodine sorption of bentonite - radiometric and polarographic study

International Nuclear Information System (INIS)

Konirova, R.; Vinsova, H.; Koudelkova, M.; Ernestova, M.; Jedinakova-Krizova, V.

2003-01-01

The experiments focused on kinetics of iodine retardation on bentonite, influence of aqueous phase pH, buffering properties of bentonite, etc. were carried out by batch method. Distribution coefficient KD was the criterion applied for evaluation of iodine interaction with solid phase. High sorption potential of bentonite to cationic forms of various radionuclides, resulting from relatively high cation exchange capacity, is generally known. On the other hand the inorganic anions are not adsorbed strongly to mineral surface of clays thus uptake of iodine (occurring mainly at iodide (I - ) or iodate (IO 3 - ) form under oxoic conditions) is limited. The distribution coefficients of iodine anions' sorption on bentonite R reach order of magnitude 10 -1 mL/g. In order to increase the sorption capacity of the solid phase, several additives were added to bentonite. Most of them didn't provide satisfactory results except of the addition of activated carbon, which has high surface area. Electromigration and polarographic methods were used for investigation of the redox state of iodine in aqueous phase and determination of KD values as well. Acquired results were compared with data obtained by radiometric measurements. (authors)

Polarographic investigation of complexing kinetics of polyacrylate anions with cadmium ions

International Nuclear Information System (INIS)

Avlyanov, Zh.K.; Kabanov, N.M.; Zezin, A.B.; Askarov, M.A.

1990-01-01

The processes which occur during the reduction of cadmium ions from polymer-metallic complexes (PMC) are studied for the purposes of polarographic investigation of complexing kinetics of polyacrylate anions (PAA) of different molecular masses with cadmium ions in KCl aqueous solutions. An expression is derived for establishing semiwave potential. PMC formation and dissociation reduction rate constants are calculated. It is shown that intramolecular reorderings required for the formation of a two-coordinate complex proceed much slower as compared to the diffusion of free ions

Polarographic determination of uranium dioxide stoichiometry

International Nuclear Information System (INIS)

Viguie, J.; Uny, G.

1966-10-01

The method described allows the determination of small deviations from stoichiometry for uranium dioxide. It was applied to the study of surface oxidation of bulk samples. The sample is dissolved in phosphoric acid under an argon atmosphere; U(VI) is determined by polarography in PO 4 H 3 4.5 N - H 2 SO 4 4 N. U(IV) is determined by potentiometry. The detection limit is UO 2,0002 . The accuracy for a single determination at the 95% confidence level is ±20 per cent for samples with composition included between UO 2,001 and UO 2,01 . (authors) [fr

Polarographic study of mixed-ligand complexes of cadmium(II) with L-amino acid and vitamin B5

International Nuclear Information System (INIS)

Jain, Alok K.; Khan, Farid

1998-01-01

A survey of literature shows that ternary complexes of Cd II with L-amino acids and vitamin B 5 have not been studied so far. The present communication reports the formation of mixed-ligand complexes of Cd II with L-amino acids as primary ligands and vitamin B 5 as secondary ligand, studied by polarographic technique. (author)

Polarographic and potentiometric studies on some binary and ternary complex systems of dioxouranium(VI)

International Nuclear Information System (INIS)

Janarthanam, M.; Sivasankar, B.; Rengaraj, K.; Nair, M.S.

1995-01-01

The relative coordinating abilities of donor sites in the potentially tridentate ligands viz., asparagine, glutamine, aspartic acid and glutamic acid towards uranyl ion have been investigated by polarographic and pH-metric techniques. The metal ion forms 1:2 complexes under polarographic conditions. However, only 1:1 complex is observed under pH-metric conditions, where 1:2 complexes do not proceed due to extensive hydrolysis of the metal ion. The relative variations of ΔE 1/2 with pH and ligand concentration supported by conductometric titration data indicate that the primary amino groups in the amino acids are not involved in coordination with uranyl ion. Further, the amide groups in asparagine and glutamine also do not participate in coordination thus rendering these ligands unidentate. In aspartic and glutamic acid complexes, seven- and eight- membered chelate rings are formed involving two terminal carboxyl groups. The mixed ligand complex equilibria of uranyl ion involving aspartic acid/glutamic acid as primary ligands (A) and maleic acid, malonic acid, succinic acid and lactic acid as secondary ligands (B) have also been studied by computer based numerical evaluation of pH titration data. The concentration profiles have indicated the favorability of the formation of ternary complexes in general as reflected in the Δlog K values. (author). 10 refs., 1 fig., 1 tab

Polarographic determination of selenium in indium

International Nuclear Information System (INIS)

Kaplan, B.Ya.; Mikheeva, V.A.; Priz, N.B.

1978-01-01

The procedure of determining nx10 -6 % Se in indium after concentrating in an elemental form on arsenic and sulphur has been developed. The selenium content is determined by inversion a.c. polarography on a sulphuric-acid background in the presence of Cu(2), potassium bichromate, and sodium pyrophosphate. 5.7x10 -6 % Se in metal indium has been determined by this procedure, the mean standard deviation being Sr=0.26

The study of Cr3+/Cr2+ redox system by polarographic method

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S. A. Pokhmyolkina

2014-08-01

Full Text Available Aim. The relevance of the theme is the ability to determine kinetic and thermodynamic parameters of the redox system on the example of Сr3/ Cr2in order to explain the reaction mechanism. In this paper, the electrochemical behavior of Cr+3/ Cr+2has been studied by polarography method. Polarogramshave been interpreted using the theory of irreversible polarographic waves and thermodynamically irreversible processes. Experiments have been carried out in a sealed cell with an outer casing for temperature control. Air oxygen removed from the feed solution for 15-20 minutes, purified nitrogen flowing from the cylinder. Characterization of the capillary in a 0.1N solution.H2SO4: mass flowing mercury m = 2,39 mg / sec; droplet formation period τ = 1,25 sec. Sulfate Cr (II was prepared by dissolving an electrolytic chromium 150 cm3 of water and 46 grams of 98 % sulphate acid. Thus a saturated solution formed a blue color. Sulfate salt solutions of two- and trivalent chromium in the medium of 0.1NH2SO4 give one wave. Anodic diffusion current sulfate Cr (II was 4,67μa, and half-wave potential E ½ = -0,44 V. The cathode current diffuse sulfate Cr (III, respectively - 7,65μa and E ½ = - 1,01 V. Inconsistency half-wave potentials of anodic and cathodic processes indicates its irreversibility. Half-wave potentials are given with respect to a saturated calomel electrode. Polarogramshave been investigated in the temperature range of 20-600C every 100C. Temperature coefficients have been calculated by the equation: Β% = idt –id20/ id20Δt, whereidtis diffusion current for a given concentration of the test solution at t0С; id20 is diffusion current for the same concentration at 200C; Δt - temperature change relative to 200C . Irreversibility, obviously due to the change in the electron configuration of chromium electrode is accompanying the redox process.Using the theory of irreversible polarographic waves we have determined the kinetic characteristics

Pulse polarography - special application; Polarographie a impulsions - applications particulieres

Energy Technology Data Exchange (ETDEWEB)

Chapron, Y [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

1967-07-01

The calculation of the current on a plane electrode in particular conditions is presented briefly, the first part of the report then consists of a theoretical and methodological presentation of pulse polarography. The calculation of the current in pulse polarography is given for different modes of measurement and for redox systems of variable reversibility. Various extensions are proposed with a view to extending the field of application of the method. The second part presents two particular applications. One application is to analytical chemistry: organometallic complexes applied to the pulse polarographic analysis; the other application is to electrochemical kinetics using integral pulse polarography. This research has enabled us to determine, in the first case, elements present in minute traces, and in the second case the kinetic parameters of an electrochemical reaction which is too fast to be analyzed by conventional polarography. (author) [French] Apres un rappel sur le calcul du courant sur electrode plane dans des conditions precises, la premiere partie du memoire est consacree a l'expose theorique et methodologique de la polarographie a impulsions. Le calcul du courant en polarographie a impulsions est donne pour divers modes de mesures et pour des systemes redox de reversibilites variees. Diverses extensions sont proposees de facon a elargir le domaine d'application de la methode. La deuxieme partie introduit deux applications particulieres. Une application a la chimie analytique: les complexes organometalliques appliques a l'analyse pulsopolarographique et une application a la cinetique electrochimique par polarographie a impulsions integrale. Ces recherches nous ont permis de determiner dans le premier cas, des elements a l'etat de traces infimes, dans le deuxieme cas, les parametres cinetiques d'une reaction electrochimique trop rapide pour etre analysee par polarographie classique. (auteur)

Pressure balanced type membrane covered polarographic oxygen detectors for use in high temperature-high pressure water, (1)

International Nuclear Information System (INIS)

Nakayama, Norio; Uchida, Shunsuke

1984-01-01

A pressure balanced type membrane covered polarographic oxygen detector was developed to determine directly oxygen concentrations in high temperature, high pressure water without cooling and pressure reducing procedures. The detector is characterized by the following features: (1) The detector body and the membrane for oxygen penetration are made of heat resistant resin. (2) The whole detector body is contained in a pressure chamber where interior and exterior pressures of the detector are balanced. (3) Thermal expansion of the electrolyte is absorbed by deformation of a diaphragm attached to the detector bottom. (4) The effect of dissolved Ag + on the signal current is eliminated by applying a guard electrode. As a result of performance tests at elevated temperature, it was demonstrated that a linear relationship between oxygen concentration and signal current was obtained up to 285 0 C, which was stabilized by the guard electrode. The minimum O 2 concentration detectable was 0.03ppm (9.4 x 10 -7 mol/kg). (author)

Voltammetric Behaviour and Analysis of Fluchloralin

OpenAIRE

K. Balaji; C. Sridevi; N. Ananda Kumar Reddy; K. Mohana Muni Sidda Reddy; C. Suresh Reddy

2010-01-01

The electrochemical reduction behavior of fluchloralin has been studied by D.C.polarography, differential pulse polarography, millicoulometry and controlled potential electrolysis in the universal buffers ranging from 2.0 to 12.0. Kinetic parameters were evaluated and a reduction mechanism was proposed. A simple and rapid differential pulse polarographic method has been developed for the determination of fluchloralin in formulations, grains, soils and spiked water samples. The lower detection...

Determination of Sn in 99{sup m}Tc Radiopharmaceutical Kits by Polarographic Methods; Determinacion de Estano en Radiofarmacos de 99{sup m}Tc mediante Metodos Polarograficos

Energy Technology Data Exchange (ETDEWEB)

Castro, M; Cruz, J; Sanchez, M

2009-07-01

Kits of 99{sup m}Tc radiopharmaceuticals are used in nuclear medicine for diagnosis of different diseases. Sn (II) is one of the essential components in their formulations, which is used for reduction 99{sup m}Tc-pertechnetate in cold kits for on-site preparation 99{sup m}Tc-pertechnetate radiopharmaceuticals. Usually, these cold kits contain different additives (complexing agents, antioxidants, buffers, etc.) and the amount of Sn (II) varies from kit to kit. The determination of Sn in these products is essential in assessing their quality. We report here the development of a new polarographic method for the determination of Sn (II) and total Sn in representative radiopharmaceuticals kits (for the content of Sn and chemical composition) produced at the Center of Isotopes of Cuba (CENTIS). These methods were validated by analysis of variance and recovery techniques. From the results of the validation, the characteristic functions of uncertainties and fits are considered for the established methods, which give the necessary evidences to demonstrate the usefulness of these methods according to the current trends in Analytical Chemistry. This work provides practical results of great importance for CENTIS. After the speciation of Sn in the MAG3 radiopharmaceuticals kit is inferred that the production process is affected by uncontrolled factors that influence in the product stability, which demonstrates the necessity for analytical tools for the characterization of products and processes. (Author) 57 refs.

Direct determination of the hit locations from experimental HPGe pulses

Energy Technology Data Exchange (ETDEWEB)

Désesquelles, P., E-mail: Pierre.Desesquelles@in2p3.fr [Univ. Paris-Sud, CSNSM CNRS/IN2P3, 15 rue G. Clémenceau, 91405 Orsay (France); Boston, A.J.; Boston, H.C.; Cresswell, J.R.; Dimmock, M.R. [Oliver Lodge Laboratory, The University of Liverpool, Oxford Street, Liverpool L69 7ZE (United Kingdom); Lazarus, I.H. [STFC Daresbury Laboratory, Daresbury, Warrington WA4 4AD (United Kingdom); Ljungvall, J. [Univ. Paris-Sud, CSNSM CNRS/IN2P3, 15 rue G. Clémenceau, 91405 Orsay (France); Nelson, L. [Oliver Lodge Laboratory, The University of Liverpool, Oxford Street, Liverpool L69 7ZE (United Kingdom); Nga, D.-T. [Univ. Paris-Sud, CSNSM CNRS/IN2P3, 15 rue G. Clémenceau, 91405 Orsay (France); Nolan, P.J.; Rigby, S.V. [Oliver Lodge Laboratory, The University of Liverpool, Oxford Street, Liverpool L69 7ZE (United Kingdom); Simpson, J. [STFC Daresbury Laboratory, Daresbury, Warrington WA4 4AD (United Kingdom); Van-Oanh, N.-T. [Univ. Paris-Sud, LCP UMR8000 CNRS, 15 rue G. Clémenceau, 91405 Orsay (France)

2013-11-21

The gamma-tracking technique optimises the determination of the energy and emission angle of gamma-rays detected by modern segmented HPGe detectors. This entails the determination, using the delivered pulse shapes, of the interaction points of the gamma-ray within the crystal. The direct method presented here allows the localisation of the hits using only a large sample of pulses detected in the actual operating conditions. No external crystal scanning system or pulse shape simulation code is needed. In order to validate this method, it is applied to sets of pulses obtained using the University of Liverpool scanning system. The hit locations are determined by the method with good precision.

Determination of pseudo multi-pulse production rate in GM counters by correlation analysis between signal pulses

International Nuclear Information System (INIS)

Hashimoto, Kengo; Ueda, Taizou

1996-01-01

A technique, based on the correlation analysis of signal pulses in time sequence, is proposed to determine the production rate of the pseudo multi-pulse in Geiger-Mueller (GM) counter. With a multi-channel scaler initiated by a signal pulse, subsequent pulses are recorded in sequence. The production of the multi-pulse increases the counting probability immediately after the initiation. By examining the deviation of the measured probability from the ideal counting probability, the production rate and the average lag time to produce the multi-pulse can be determined. By the use of the present technique, the production rate and the average lag time were obtained for the various GM tubes. These results indicate that the consumption of the quench gas results in a significant increase in the production rate but little variation in the lag time, and that the lag time strongly depends on the tube diameter. (author)

Polarographic study of the electrochemical properties of plutonium; Etude polarographique des proprietes electrochimiques du plutonium

Energy Technology Data Exchange (ETDEWEB)

Guichard, C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

1968-07-01

The behaviour of the different degrees of oxidation of plutonium have been studied using a falling drop mercury electrode in a non-complexing medium: dilute perchloric acid. In this medium it is possible to carry out the polarographic determination of plutonium using the reduction step situated at - 0.54 V/ECS which corresponds to the passage from the degree of oxidation(V) to the degree(III). The modifications brought about by a complexing ion, acetate, are then observed and interpreted. The existence of two plutonium(IV) acetic complexes has been shown; one is a polymerized substance. (author) [French] Le comportement des differents degres d'oxydation du plutonium est etudie a l'electrode a gouttes de mercure dans un milieu non complexant: l'acide perchlorique dilue. Il est possible dans ce milieu d'effectuer le dosage polarographique du plutonium en utilisant la vague de reduction situee a - 0.54 V/ECS qui correspond au passage du degre d'oxydation(V) au degre(III). Les modifications apportees par un ion complexant, l'acetate, sont ensuite observees et interpretees. Deux complexes acetiques du plutonium(IV) ont ete mis en evidence, dont l'un est un compose polymerise. (auteur)

Polarographic behaviour and determination of uranium(VI) in alcoholic solutions from organic extraction phases

International Nuclear Information System (INIS)

Degueldre, C.; Taibi, K.

1996-01-01

The determination of U(VI) in organic extraction phases: hydrocarbon-diethyl-2-hexyl phosphoric acid-trioctylphosphine oxide and hydrocarbon-tri-n-octylamine, diluted by an alcohol has been studied by direct current polarography, as well as by differential pulse polarography (DPP). In order to optimise the analytical procedure, miscibility and conductivity studies of the mixtures hydrocarbon-alcohol (ethanol, n- and isopropanol and n- and isobutanol) were made after addition of sulphuric acid as a supporting electrolyte. In the solutions of sulphuric acid in the alcohol-extractant-hydrocarbon phases, U(VI) gives rise to well defined polarograms. Its electroreduction involves a single electron step in all cases. The DPP peak height is proportional to the U(VI) concentration between 2x10 -6 and 2x10 -3 M, and the 3σ detection limit is ca. 10 -6 M

Analysis of gases by a pulsed voltammetric sensor and the electrochemistry of high T[sub c] superconductors

Energy Technology Data Exchange (ETDEWEB)

Rochani, S.

1991-01-01

This thesis is presented in two parts: Studies of gas sensing probes and the electrochemistry of superconductors. A Clark type polarographic oxygen sensor was used to analyze oxygen, hydrogen, chlorine, sulphur dioxide and nitrogen dioxide. A pulsed potential was applied driven by an IBM/XT compatible microcomputer with a 12 bit A-D/D-A card. In a series of experiments for each gas singly, and then mixtures, the probe was calibrated at different concentrations of gas dissolved in water at different times during the pulse to observe the optimum measurement. In the case of oxygen for a 20 s pulse at [minus]0.65 V between a platinum and silver/silver chloride, the optimum calibration was obtained between 2 and 4 s with a detection limit of 0.27 ppm oxygen. Hydrogen was determined at +0.60 V with a 50 s pulse and optimum range 3 to 4 s and detection limit 0.02 ppm. Chlorine was reduced at 0 V and optimally detected after 2 s of a 20 s pulse with a detection limit of 3 ppm. A mixture of hydrogen and oxygen was analyzed without mutual interference by a train of pulses at [minus]0.65, 0, +0.60 V or [minus]0.65, +0.60 V. For sulphur dioxide, a new probe was constructed with a separate reference, working and auxillary electrodes to overcome the formation of silver sulphide at the auxillary electrode. A preliminary study of nitrogen dioxide was done by observing the oxidation and reduction current at different applied voltages. Samples of each of the room temperature superconductors YBa[sub 2]Cu[sub 3]O[sub 7[minus][sigma

[Ambient air interference in oxygen intake measurements in liquid incubating media with the use of open polarographic cells].

Science.gov (United States)

Miniaev, M V; Voronchikhina, L I

2007-01-01

A model of oxygen intake by aerobic bio-objects in liquid incubating media was applied to investigate the influence air-media interface area on accuracy of measuring the oxygen intake and error value. It was shown that intrusion of air oxygen increases the relative error to 24% in open polarographic cells and to 13% in cells with a reduced interface area. Results of modeling passive media oxygenation laid a basis for proposing a method to reduce relative error by 66% for open cells and by 15% for cells with a reduced interface area.

Magnesium analysis. Determination of 5 elements by impulse polarography

International Nuclear Information System (INIS)

Anon.

Determination of cadmium, copper, nickel, lead and zinc in magnesium used in magnesiothermics. The process is as follow: magnesium dissolution in hydrochloric acid, neutralisation by ammonia, addition of ammonium chloride and citric acid, ammonia is added until pH8. Addition of pyridine, polarographic determination of zinc and then of cadmium and copper [fr

The relationship between temporal variation of hypoxia, polarographic measurements and predictions of tumour response to radiation

Science.gov (United States)

Toma-Dasu, Iuliana; Dasu, Alexandru; Karlsson, Mikael

2004-10-01

to a systematic deviation between the actual oxygen distribution and the measured distribution. However, as the electrode reflects the general trends of the tissue oxygenation it has the potential of being used for the general characterization of tumour hypoxia even if the actual type of hypoxia measured by the electrode cannot be determined. Indeed, the change in time of the acute hypoxic region does not compensate for the lack of oxygenation at a specific moment and therefore does not influence the polarographic oxygen measurements.

Polarographic study of the Cu(II)/Cu(I) system in the presence of 1-ascorbic acid and 0,1 M ClK

International Nuclear Information System (INIS)

Alonso Lopez, J.

1969-01-01

While studying the catalytic effect of Cu ↓ 2 ions on the oxidation process of 1-ascorbic acid, it has been observed that, in a 0,1 M solution of K1 at a pH 6 to 7, the above acid gives rise in the presence of Cu ↓ 2 ions to a polarographic wave of half-wave potential of -0,41 V (vs. S.C.E.). (Author) 14 refs

Determination of blood volume by pulse CO-oximetry

International Nuclear Information System (INIS)

Lalande, S; Kelsey, J W; Joyner, M J; Johnson, B D

2012-01-01

The objective of this study was to determine whether changes in carboxyhaemoglobin (COHb) saturation following carbon monoxide (CO) rebreathing can be accurately detected by pulse CO-oximetry in order to determine blood volume. Noninvasive measurements of carboxyhaemoglobin saturation (SpCO) were continuously monitored by pulse CO-oximetry before, during and following 2 min of CO rebreathing. Reproducibility and accuracy of noninvasive blood volume measurements were determined in 16 healthy non-smoking individuals (15 males, age: 28 ± 2 years, body mass index: 25.4 ± 0.6 kg m −2 ) through comparison with blood volume measurements calculated from invasive measurements of COHb saturation. The coefficient of variation for noninvasive blood volume measurements performed on separate days was 15.1% which decreases to 9.1% when measurements were performed on the same day. Changes in COHb saturation and SpCO following CO rebreathing were strongly correlated (r = 0.90, p < 0.01), resulting in a significant correlation between invasive and noninvasive blood volume measurements (r = 0.83, p = 0.02). Changes in SpCO following CO rebreathing can be accurately detected by pulse CO-oximetry, which could potentially provide a simplified, convenient and reproducible method to rapidly determine blood volume in healthy individuals

Polarographic investigation of complexing kinetics of polyacrylate anions with cadmium ions. Polyarograficheskoe issledovanie kinetiki kompleksoobrazovaniya poliakrilat-anionov s ionami kadmiya

Energy Technology Data Exchange (ETDEWEB)

Avlyanov, Zh K; Kabanov, N M; Zezin, A B; Askarov, M A

1990-01-01

The processes which occur during the reduction of cadmium ions from polymer-metallic complexes (PMC) are studied for the purposes of polarographic investigation of complexing kinetics of polyacrylate anions (PAA) of different molecular masses with cadmium ions in KCl aqueous solutions. An expression is derived for establishing semiwave potential. PMC formation and dissociation reduction rate constants are calculated. It is shown that intramolecular reorderings required for the formation of a two-coordinate complex proceed much slower as compared to the diffusion of free ions.

Determination of antimony trioxide in fire-retardant conveyor belts

Energy Technology Data Exchange (ETDEWEB)

Rytych-Witwicka, B.; Szmyd, E.

1976-12-01

Two methods for the determination of antimony trioxide in rubber and pvc are described. One is a colorimetric method based on the reaction of antimony with rhodamine B; the other is a polarographic method. The results of the two methods show a satisfactory consistency and the methods themselves appear rapid and effective.

Progress report on the analytical determination of Ag2+

International Nuclear Information System (INIS)

Van Alsenoy, V.

1997-01-01

The strong oxidising properties of Ag 2+ have been used in the chemical and nuclear industry to destroy organic waste. We aim to apply the process on radioactive graphite, organic resins and effluents. The reaction mechanisms have been studied, taking into account the thermodynamic and kinetic properties of the different reactions involved. For the experimental analysis of these reactions, the accurate analytical determination of all species involved, including Ag 2+ , is needed. The results of a systematic study of the volumetric quantification of Ag 2+ using Tl + and BrO 3 - , and of the spectrophotometric and polarographic quantification of Ag + and Ag 2+ are described. The influence of the nitric acid during the quantification of Tl + by titration with KBrO 3 is investigated and the optimal analytical conditions for our purposes were determined. The best analytical results were obtained when the titration was carried out with maximum 3 M HNO 3 and 0.5 M NaCl. When those conditions are used, the determination is accurate and reproducible. The prepared Ag 2+ solutions were analysed for Ag + using polarography with a platinum electrode. The benefits and the limitation of the polarographic measurement of Ag + using a platinum electrode are described. An indirect measurement was performed by the determination of Ce 4+ after reaction with Ce 3+ . The produced Ce 4+ was measured by direct spectrophotometry. In the future, the quantification of Ag 2+ by measuring the Ce 4+ concentration produced by the reaction with Ce 3+ , will also be verified using potentiometric titration with Fe 2+ . Ag 2+ can also be determined by the direct spectrophotometry. There is a region in which the absorbance of Ag 2+ changes linearly with the concentration. Further evaluation of the titrimetric, spectrophotometric and polarographic methods will continue, until two methods give comparable Ag 2+ concentrations, beginning with the potentiometric titration of Ce 4+ with Fe 2+

The potential for biological structure determination with pulsed neutrons

International Nuclear Information System (INIS)

Wilson, C.C.

1994-01-01

The potential of pulsed neutron diffraction in structural determination of biological materials is discussed. The problems and potential solutions in this area are outlined, with reference to both current and future sources and instrumentation. The importance of developing instrumentation on pulsed sources in emphasized, with reference to the likelihood of future expansion in this area. The possibilities and limitations of single crystal, fiber and powder diffraction in this area are assessed

The potential for biological structure determination with pulsed neutrons

Energy Technology Data Exchange (ETDEWEB)

Wilson, C.C. [CLRC Rutherford Appleton Laboratory, Chilton Didcot Oxon (United Kingdom)

1994-12-31

The potential of pulsed neutron diffraction in structural determination of biological materials is discussed. The problems and potential solutions in this area are outlined, with reference to both current and future sources and instrumentation. The importance of developing instrumentation on pulsed sources in emphasized, with reference to the likelihood of future expansion in this area. The possibilities and limitations of single crystal, fiber and powder diffraction in this area are assessed.

Pulsed neutron well logging apparatus having means for determining background radiation

International Nuclear Information System (INIS)

Randall, R.R.

1979-01-01

A neutron generator in a well logging instrument is periodically pulsed and has an off period between pulses of 1000 microseconds. A neutron detector is gated on at intervals of 400 to 500, 550 to 650, and 700 to 800 microseconds, respectively, following the termination of each burst of fast neutrons. Circuitry is provided for determining the background radiation and for determining the macroscopic absorption. 3 claims

Voltammetric studies on composition and stabilities of complexes of tetracycline and oxytetracycline with some metal ions in aqueous medium

International Nuclear Information System (INIS)

Ghandour, M.A.; Azab, H.A.; Hassan, A.; Ali, A.M.

1992-01-01

The composition and stability of complexes of tetracycline and oxytetracycline with Cu(II), Cd(II), Pb(II) and UO 2 (II) have been studied polarographically (direct current and differential pulse polarographic techniques) at 25±0.1 deg C. Differential pulse polarographic studies have been particularly helpful in deciding the nature of metal-drug interactions at low concentrations. The reduction of Cu(II)-tetracycline has been found to be irreversible and diffusion controlled with the presence of an adsorption component. In the system uranyl(II)-tetracycline the complex formed has a stoichiometry of 1:1 and log K ox = 4.04 which is very close to that obtained by potentiometric measurements. The peak half width W 1/2 of the Pb(II)-OTC system is 60-70 mV indicating that the process is reversible and two electrons are consumed. The log β' is 10.30 in 0.1 mol dm -3 NaClO 4 . In the Cu(II)-OTC system two complexes were formed with log β 1 ' = 8.50 and log β 2 ' = 14.10. Cyclic voltammograms were recorded using a hanging dropping mercury electrode for the systems Cu(II), Cd(II), Pb(II) and UO 2 (II)-OTC to examine the irregularities in both peak potentials and peak currents during the polarographic investigations. (authors)

Voltammetric studies on composition and stabilities of complexes of tetracycline and oxytetracycline with some metal ions in aqueous medium. Voltammetrische Untersuchungen zur Zusammensetzung und Stabilitaet von Komplexen von Tetracyclin und Oxytetracyclin mit einigen Metallionen in waessrigem Medium

Energy Technology Data Exchange (ETDEWEB)

Ghandour, M A; Azab, H A; Hassan, A; Ali, A M [Dept. of Chemistry, Faculty of Science, Assiut Univ., Assiut (Egypt)

1992-01-01

The composition and stability of complexes of tetracycline and oxytetracycline with Cu(II), Cd(II), Pb(II) and UO[sub 2](II) have been studied polarographically (direct current and differential pulse polarographic techniques) at 25[+-]0.1 deg C. Differential pulse polarographic studies have been particularly helpful in deciding the nature of metal-drug interactions at low concentrations. The reduction of Cu(II)-tetracycline has been found to be irreversible and diffusion controlled with the presence of an adsorption component. In the system uranyl(II)-tetracycline the complex formed has a stoichiometry of 1:1 and log K[sub ox] = 4.04 which is very close to that obtained by potentiometric measurements. The peak half width W[sub 1/2] of the Pb(II)-OTC system is 60-70 mV indicating that the process is reversible and two electrons are consumed. The log [beta]' is 10.30 in 0.1 mol dm[sup -3] NaClO[sub 4]. In the Cu(II)-OTC system two complexes were formed with log [beta][sub 1]' = 8.50 and log [beta][sub 2]' = 14.10. Cyclic voltammograms were recorded using a hanging dropping mercury electrode for the systems Cu(II), Cd(II), Pb(II) and UO[sub 2](II)-OTC to examine the irregularities in both peak potentials and peak currents during the polarographic investigations. (authors).

Determination of pulse profile characteristics of multi spot retinal photocoagulation lasers.

Science.gov (United States)

Clarkson, Douglas McG; Makhzoum, Osama; Blackburn, John

2015-10-01

A system is described for determination of discrete pulse train characteristics of multi spot laser delivery systems for retinal photocoagulation. While photodiodes provide an ideal detection mechanism, measurement artifacts can potentially be introduced by the spatial pattern of the delivered beam relative to a discrete photodiode element. This problem was overcome by use of an integrating sphere to produce a uniform light field at the site of the photodiode detector. A basic current driven photodiode detection circuit incorporating an operational amplifier was used to generate a signal captured by a commercially available USB interface device at a rate of 10 kHz. Studies were undertaken of a Topcon Pascal Streamline laser system with output at a wavelength of 577 nm (yellow). This laser features the proprietary feature of 'Endpoint Management' ™ where pulses can be delivered as 100% of set energy levels with visible reaction on the retina and also at a reduced energy level to create potentially non visible but clinically effective lesions. Using the pulse train measurement device it was identified that the 'Endpoint Management' ™ delivery mode of pulses of lower energy was achieved by reducing the pulse duration of pulses for non-visible effect pulses while maintaining consistent beam power levels within the delivered pulse profile. The effect of eye geometry in determining safety and effectiveness of multi spot laser delivery for retinal photocoagulation is discussed. Copyright © 2015 IPEM. Published by Elsevier Ltd. All rights reserved.

Voltammetric Behaviour and Analysis of Fluchloralin

Directory of Open Access Journals (Sweden)

K. Balaji

2010-01-01

Full Text Available The electrochemical reduction behavior of fluchloralin has been studied by D.C.polarography, differential pulse polarography, millicoulometry and controlled potential electrolysis in the universal buffers ranging from 2.0 to 12.0. Kinetic parameters were evaluated and a reduction mechanism was proposed. A simple and rapid differential pulse polarographic method has been developed for the determination of fluchloralin in formulations, grains, soils and spiked water samples. The lower detection limit was found to be 1.5×10-8 M. Both the standard addition and calibration methods were used for the analytical measurements.

Conformational changes in DNA caused by DNA-ase I, gamma and ultraviolet radiation as revealed by differential pulse polarography

International Nuclear Information System (INIS)

Vorlickova, M.

1979-01-01

The height, potential and half width of differential pulse-polarographic peaks of DNA were investigated in dependence on degradation by DNA-ase I and gamma and UV radiation. It was found that in all cases studied growth of peak II (reflecting conformational changes in the DNA double helix) was limited, and only after it reached a certain height further degradation induced the appearance of peak III of single-stranded DNA. This course is explained as reflecting the limited extent of conformational changes in the framework of the double helix, which probably follows from a limited number of sites that can undergo certain types of conformational changes. The character of the conformational changes is dependent on the chemical nature of the damage. (author)

Research on determine the absolute neutron output of distributed pulse generators

International Nuclear Information System (INIS)

Li Bojun; Tang Zhangkui; Wang Dong; Yang Gaozhao; Peng Taiping

2009-01-01

In order to determine the absolute neutron output of distributed pulse generators, we deduced equivalent length to deal with experimental data, according to the different layout and weighting of multiple pulse generators. The deposited energy in scintillation crystal and the integral flux which drilling through crystal interface was simulated by MCNP code. The result shows the simulated proportion of different distributed pulse generators is approximately agreed with experimental data. The validity of the equivalent length model was proved by the consistent results between calculation and experimental data. (authors)

applications of artificial neural networks to resolution of differential ...

African Journals Online (AJOL)

spisska

Disturbed Differential Pulse Polarographic Peaks in the Region of Hydrogen ... represent the experimental behaviour of the system when the exact description is ... equations and the values of physico-chemical constants.8 The characteristics ...

A novel approach to determine the interphase transformer inductance of 18 pulse rectifiers

International Nuclear Information System (INIS)

Sefa, Ibrahim; Altin, Necmi

2009-01-01

The interphase transformer inductance seriously affects the performance of 18 pulse rectifiers. Low inductance values cause non-characteristic harmonics whereas high inductance values increase the rectifier cost and size. Hence, determination of the interphase transformer inductance value is an important problem in the design of 18 pulse rectifiers. In this paper, an approach to determine the optimum inductance value of an interphase transformer is proposed and a practical formula is introduced. The proposed approach has been validated with simulation and experimental studies carried out with designed capacitive loaded autotransformer based 18 pulse rectifier for different IPT inductance values at different load levels. Experimental and simulation results show that cost effective interphase transformer inductance value can be determined with the proposed approach and this value reduces the line current harmonics and improves power factor drastically.

Direct and indirect methods for the determination of vitamin K3 using differential pulse polarography and application to pharmaceuticals.

Science.gov (United States)

Somer, Güler; Doğan, Mehmet

2008-11-01

Two methods for the determination of vitamin K(3) have been developed. Vitamin K(3) in its oxidized form is determined by direct and indirect methods. Its standard solution was prepared by the indirect method using Ti(III) as reducing agent. For this purpose vitamin K(3) (menadion) in a clinical injection solution, which is in its hydroquinone form in the presence of sulfite, is oxidized with oxygen. In 0.2 M HAc and 0.02 M HCl electrolyte vitamin K(3) and Ti(IV) have reduction peaks at -0.58 V at -0.82 V respectively. The reaction between Ti(III) and vitamin takes place quantitatively in a medium of 0.2 M HAc and 0.002 M HCl. After the reduction, the reaction product Ti(IV) is followed from its polarographic peak at about -0.82 V. The most important result in this work is that, with this method vitamin K(3) can be standardized and after standardization this solution can be used for the direct determination in routine analysis with a very simple and fast method, using only the peak at -0.71 V in 0.2 M HAc medium. Both direct and indirect methods have been used for the determination of Vitamin K(3) in a clinical injection solution. The limit of quantification (LOQ) was 1.5x10(-6) M and in both methods the detection limit found was 7x10(-7) M.

Determination of pulse energy dependence for skin denaturation from 585nm fibre laser

Science.gov (United States)

Mujica-Ascencio, S.; Velazquez-Gonzalez, J. S.; Mujica-Ascencio, C.; Alvarez-Chavez, J. A.

2014-05-01

In this paper, simulation and mathematical analysis for the determination of pulse energy from a Q-switched Yb3+-doped fibre laser is required in Port Wine Stain (PWS) treatment. The pulse energy depends on average power, gain, volume, repetition rate and pulse duration. In some treatments such as Selective Photothermolysis (SP), the peak power at the end of the optical fibre and pulse duration can be obtained and modified via a cavity design. For that purpose, a 585nm optical fibre laser full design which considers all of the above besides the average losses through the optical devices proposed for the design and the Ytterbium optical fibre overall gain will be presented.

Pulsed neutron well logging apparatus having means for determining background radiation

International Nuclear Information System (INIS)

Randall, R.R.

1979-01-01

A neutron generator in a well logging instrument is periodically pulsed and has an off period between pulses of 1000 microseconds. A neutron detector is gated on at intervals of 400 to 500, 550 to 650, and 700 to 800 microseconds, respectively, following the termination of each burst of fast neutrons. Circuitry is provided for determining the background radiation by the equation: B = N 1 X N 3 - N 2 2 /N 1 + N 3 - 2N 2 where B is the background, and N 1 , N 2 and N 3 are the counts observed during the three gates, respectively. Circuitry is also provided for determining the macroscopic absorption (Σ) from the equation: Σ = 1/VΔt Log [N 1 - B/N 2 - B] where V is the velocity of thermal neutrons, being a constant and Δt represents an increment of time

Polarographic behaviour of uranium (VI) in tributyl phosphate organic solutions

International Nuclear Information System (INIS)

Degueldre, C.A.; Meklati, M.

1984-01-01

U(VI) determination by D.C. and differential pulse polarography was studied in the organic solutions derived from tributyl phosphate - diluent extracts (after separation from nitric acid media) along with a selected aprotic solvent (i.e.: propylene carbonate and N,N-dimethylacetamide). Miscibility of the TBP-diluent (e.g. cyclohexane, n-hexane, kerosene, n-dodecane) phase with nitric acid as supporting electrolyte, either by addition or already present in the extract was larger in DMA than in PC. In the DMA organic mixture, U(VI) exhibited a DPP peak due to a one electron step, with Esub(p)=-0.4 V (position connected with H 2 O and HNO 3 concentrations). This peak which was proportionnel to the U(VI) concentration from 5x10 -6 to 10 -3 M can be used to determinate directly hexavalent uranium in the industrial organic extraction phases TBP-diluent. (orig.)

Determination of tellurium in gallium by alternating current stripping voltammetry with a mercury/graphite electrode

International Nuclear Information System (INIS)

Berengard, I.B.; Kaplan, B. Ya.

1986-01-01

The analytical signal in ac stripping coltammetry (ACSV) with mercury indicator electrodes depends on the weight of the electrolytically collected analyte at the electrode surface, the depth of the collection layer being equal to the effective diffusion-layer thickness. Replacement of the static mercury drop electrode (SMDE) by the mercury/graphite electrode (MGE) is of practical interest in that the analyte detection limit can be lowered by decreasing the colume of the telluriumcontaining polarographed solution; in addition, plant laboratories find it difficult to control the SDME uniformity. The work in this article was done on a PU-1 universal polarograph in a square-wave vol tage component mode using the three-electrode cell shown. The rotating mercury/graphite electrode is found by the authors to be superior to the static mercury drop electrode in that it can lower the detection limit for tellurium in gallium to 5.10 /SUP -7percent/ , due to the smaller volume of the polarographed solution

Determination of ablation threshold for composite resins and amalgam irradiated with femtosecond laser pulses

International Nuclear Information System (INIS)

Freitas, A Z; Samad, R E; Zezell, D M; Vieira Jr, N D; Freschi, L R; Gouw-Soares, S C

2010-01-01

The use of laser for caries removal and cavity preparation is already a reality in the dental clinic. The objective of the present study was to consider the viability of ultrashort laser pulses for restorative material selective removal, by determining the ablation threshold fluence for composite resins and amalgam irradiated with femtosecond laser pulses. Lasers pulses centered at 830 nm with 50 fs of duration and 1 kHz of repetition rate, with energies in the range of 300 to 770 μJ were used to irradiate the samples. The samples were irradiated using two different geometrical methods for ablation threshold fluence determinations and the volume ablation was measured by optical coherence tomography. The shape of the ablated surfaces were analyzed by optical microscopy and scanning electron microscopy. The determined ablation threshold fluence is 0.35 J/cm 2 for the composite resins Z-100 and Z-350, and 0.25 J/cm 2 for the amalgam. These values are half of the value for enamel in this temporal regime. Thermal damages were not observed in the samples. Using the OCT technique (optical coherence tomography) was possible to determine the ablated volume and the total mass removed

Determination of modeling parameters for power IGBTs under pulsed power conditions

Energy Technology Data Exchange (ETDEWEB)

Dale, Gregory E [Los Alamos National Laboratory; Van Gordon, Jim A [U. OF MISSOURI; Kovaleski, Scott D [U. OF MISSOURI

2010-01-01

While the power insulated gate bipolar transistor (IGRT) is used in many applications, it is not well characterized under pulsed power conditions. This makes the IGBT difficult to model for solid state pulsed power applications. The Oziemkiewicz implementation of the Hefner model is utilized to simulate IGBTs in some circuit simulation software packages. However, the seventeen parameters necessary for the Oziemkiewicz implementation must be known for the conditions under which the device will be operating. Using both experimental and simulated data with a least squares curve fitting technique, the parameters necessary to model a given IGBT can be determined. This paper presents two sets of these seventeen parameters that correspond to two different models of power IGBTs. Specifically, these parameters correspond to voltages up to 3.5 kV, currents up to 750 A, and pulse widths up to 10 {micro}s. Additionally, comparisons of the experimental and simulated data will be presented.

Determination of diffusion coefficients in polypyrrole thin films using a current pulse relaxation method

Science.gov (United States)

Penner, Reginald M.; Vandyke, Leon S.; Martin, Charles R.

1987-01-01

The current pulse E sub oc relaxation method and its application to the determination of diffusion coefficients in electrochemically synthesized polypyrrole thin films is described. Diffusion coefficients for such films in Et4NBF4 and MeCN are determined for a series of submicron film thicknesses. Measurement of the double-layer capacitance, C sub dl, and the resistance, R sub u, of polypyrrole thin films as a function of potential obtained with the galvanostatic pulse method is reported. Measurements of the electrolyte concentration in reduced polypyrrole films are also presented to aid in the interpretation of the data.

The second phase of bipolar, nanosecond-range electric pulses determines the electroporation efficiency.

Science.gov (United States)

Pakhomov, Andrei G; Grigoryev, Sergey; Semenov, Iurii; Casciola, Maura; Jiang, Chunqi; Xiao, Shu

2018-03-29

Bipolar cancellation refers to a phenomenon when applying a second electric pulse reduces ("cancels") cell membrane damage by a preceding electric pulse of the opposite polarity. Bipolar cancellation is a reason why bipolar nanosecond electric pulses (nsEP) cause weaker electroporation than just a single unipolar phase of the same pulse. This study was undertaken to explore the dependence of bipolar cancellation on nsEP parameters, with emphasis on the amplitude ratio of two opposite polarity phases of a bipolar pulse. Individual cells (CHO, U937, or adult mouse ventricular cardiomyocytes (VCM)) were exposed to either uni- or bipolar trapezoidal nsEP, or to nanosecond electric field oscillations (NEFO). The membrane injury was evaluated by time-lapse confocal imaging of the uptake of propidium (Pr) or YO-PRO-1 (YP) dyes and by phosphatidylserine (PS) externalization. Within studied limits, bipolar cancellation showed little or no dependence on the electric field intensity, pulse repetition rate, chosen endpoint, or cell type. However, cancellation could increase for larger pulse numbers and/or for longer pulses. The sole most critical parameter which determines bipolar cancellation was the phase ratio: maximum cancellation was observed with the 2nd phase of about 50% of the first one, whereas a larger 2nd phase could add a damaging effect of its own. "Swapping" the two phases, i.e., delivering the smaller phase before the larger one, reduced or eliminated cancellation. These findings are discussed in the context of hypothetical mechanisms of bipolar cancellation and electroporation by nsEP. Copyright © 2018 Elsevier B.V. All rights reserved.

Emission spectrochemical determination of boron in steels with pulse height distribution analyzer

International Nuclear Information System (INIS)

Ito, Minao; Sato, Shoki; Fushida, Hiroshi; Narita, Masanao

1983-01-01

The method for rapid determination of total, acid soluble and insoluble boron was established by using emission spectrochemical apparatus equipped with pulse height distribution analyzer. By using the analyzer, emission intensity can be expressed as different level intensity of pulse height distribution. It was made clear that soluble and insoluble boron had different contribution degree to each intensity and that this contribution degree varied at different pre-spark. Therefore, it is necessary for accurate determination of boron that this contribution degree should be corrected by using two intensities, of which contribution degrees are different. It was found on this two intensities method that total and soluble boron corresponded well to 50 % intensities at zero pre-spark and at 2000 pre-spark and that insoluble boron corresponded well to 70 % intensity at zero pre-spark and 50 % intensity at 2000 pre-spark. (author)

Picoseconds pulse generation and pulse width determination processes of a distributed feedback dye laser

International Nuclear Information System (INIS)

Abdul Ghani, B.; Hammadi, M.

2004-08-01

A mathematical model has been developed to describe the dynamic emission of Nd-glass, distributed feedback dye laser (DFDL), and periodical grating temperature. The suggested model allows the investigation of the time behavior of Nd-glass laser and DFDL pulsed. Moreover, it allows studying the effect of the laser input parameters of Nd-glass laser on the spectral characteristics of the output DFDL pulses such as pulse width, delay time, and time separation

Determination of Zalcitabine in Medicaments by Differential Pulse Voltammetry

Directory of Open Access Journals (Sweden)

Katia Christina Leandro

2013-01-01

Full Text Available The zalcitabine (ddC has been extensively used in the treatment of HIV patients due to its antiretroviral activity. The quality control of this active principle in medications is of outstanding importance to public health. The principal objective of the current study was the development of an alternative analytical methodology for the zalcitabine determination using a voltammetric process. The zalcitabine gives a reduction peak (at -1.22 V versus Ag/AgCl at the hanging mercury drop electrode (HMDE. The differential pulse voltammetric response is evaluated with respect to the scan rate (20 mV/s, pulse amplitude (50 mV, support electrolyte (Clark-Lubs buffer, pH (2.0, and other variables. The response is linear over the 10.0 to 28.0 mg/L (47 to 133 μM concentration range, and the detection limit is 2.08 mg/L. The validation of this method was realized using a governmental Brazilian document (Inmetro, 2007 and the results are reported for medication drugs.

Determination of etching parameters for pulsed XeF2 etching of silicon using chamber pressure data

Science.gov (United States)

Sarkar, Dipta; Baboly, M. G.; Elahi, M. M.; Abbas, K.; Butner, J.; Piñon, D.; Ward, T. L.; Hieber, Tyler; Schuberth, Austin; Leseman, Z. C.

2018-04-01

A technique is presented for determination of the depletion of the etchant, etched depth, and instantaneous etch rate for Si etching with XeF2 in a pulsed etching system in real time. The only experimental data required is the pressure data collected temporally. Coupling the pressure data with the knowledge of the chemical reactions allows for the determination of the etching parameters of interest. Using this technique, it is revealed that pulsed etching processes are nonlinear, with the initial etch rate being the highest and monotonically decreasing as the etchant is depleted. With the pulsed etching system introduced in this paper, the highest instantaneous etch rate of silicon was recorded to be 19.5 µm min-1 for an initial pressure of 1.2 Torr for XeF2. Additionally, the same data is used to determine the rate constant for the reaction of XeF2 with Si; the reaction is determined to be second order in nature. The effect of varying the exposed surface area of Si as well as the effect that pressure has on the instantaneous etch rate as a function of time is shown applying the same technique. As a proof of concept, an AlN resonator is released using XeF2 pulses to remove a sacrificial poly-Si layer.

Determination of electric field threshold for electrofusion of erythrocyte ghosts. Comparison of pulse-first and contact-first protocols.

OpenAIRE

Wu, Y; Montes, J G; Sjodin, R A

1992-01-01

Rabbit erythrocyte ghosts were fused by means of electric pulses to determine the electrofusion thresholds for these membranes. Two protocols were used to investigate fusion events: contact-first, and pulse-first. Electrical capacitance discharge (CD) pulses were used to induce fusion. Plots of fusion yield vs peak field strength yielded curves that intersected the field strength axis at positive values (pseudothresholds) which depended on the protocol and decay half time of the pulses. It wa...

Kinetic analysis of pulsed laser induced phosphorescence for uranium determination

International Nuclear Information System (INIS)

Serdeiro, Nelida H.

2003-01-01

The laser induced kinetic phosphorescence allows the uranium determination in different kind of matrices, with a lower detection limit than those reached by other spectroscopic methods. It involves the uranyl ions excitation by a pulsed dye-laser source, followed by temporal resolution of the phosphorescence. This method is used for the determination of trace quantities of uranium in aqueous solution, with a suitable complexant agent, without chemical separation before the analysis. The objective of this paper is to present the results of uranium determinations in different standard samples, water, soil, filter and urine, and a comparison with other methods such as fluorimetry, alpha spectrometry and mass spectrometry. Moreover, the measurement conditions, the advantages and disadvantages, the sample preparation, the interferences and the detection limit are described. (author)

Determination of Selenium in infant formula by differential pulse cathodic stripping voltammetry

Directory of Open Access Journals (Sweden)

"Oveisi MR

2002-07-01

Full Text Available Selenium as a nonmetallic chemical element has received high attention of biologists because of its dual role as an essential trace nutrient and a toxic element. This interest has created a need for reliable analytical methods for determination of selenium. In this investigation determination of selenium by differential pulse cathodic stripping voltammetry and the influence of various parameters such as deposition potentials, deposition time. Cu concentration pH, etc. on selenium peak in voltammogram are described. Determination of selenium was accomplished in mixture of acetic acid, hydrochloric acid and sodium chloride buffer (pH=1 with a scan rate of 60 mv/s and a pulse height of 100 my by hanging mercury drop electrode (HMDE as working electrode. The solution was stirred during pre-electrolysis at - 350 mv (vs SCE for 30 s and the potential was scanned between - 350 mv and - 800 mv. The determination limit of the method was 0.005 mg/kg for the sample. The calibration curves were linear in the range of 0-30 μg/L (R2=0.996, p<0.001. Repeatability of the method at concentrations of 30 and 0.5 μg/L were 2.5 and 10.5% respectively.

Pulse Generator

Science.gov (United States)

Greer, Lawrence (Inventor)

2017-01-01

An apparatus and a computer-implemented method for generating pulses synchronized to a rising edge of a tachometer signal from rotating machinery are disclosed. For example, in one embodiment, a pulse state machine may be configured to generate a plurality of pulses, and a period state machine may be configured to determine a period for each of the plurality of pulses.

Determination of copper in whole blood by differential pulse adsorptive stripping voltammetry

Directory of Open Access Journals (Sweden)

Tarik Attar

2014-02-01

Full Text Available A selective and sensitive method for determination of copper in blood by adsorptive differential pulse cathodic stripping voltammetry is presented. The method is based on adsorptive accumulation of the complexes of Cu (II ions with benzenesulfonyl hydrazide onto hanging mercury drop electrode (HMDE, followed by the reduction of the adsorbed species by differential pulse cathodic stripping voltammetry. The effect of various parameters such as supporting electrolyte, concentration of benzenesulfonyl hydrazide, accumulation potential, accumulation time and stirring rate on the selectivity and sensitivity were studied. The optimum conditions for determination of copper include perchloric acid 0.03 M, concentration of benzenesulfonyl hydrazide 7.5×10-5 M, the accumulation potential of -350 mV (vs. Ag/AgCl, the accumulation time of 50 s, and the scan rate of 50 mV s-1. Under optimized conditions, linear calibration curves were established for the concentration of Cu (II in the range of 0.62-275 ng mL-1, with detection limit of 0.186 ng mL-1 for Cu (II. The procedure was successfully applied to the determination of copper ion in whole blood samples.

Multi frequency phase fluorimetry (MFPF) for oxygen partial pressure measurement: ex vivo validation by polarographic clark-type electrode.

Science.gov (United States)

Boehme, Stefan; Duenges, Bastian; Klein, Klaus U; Hartwich, Volker; Mayr, Beate; Consiglio, Jolanda; Baumgardner, James E; Markstaller, Klaus; Basciani, Reto; Vogt, Andreas

2013-01-01

Measurement of partial pressure of oxygen (PO2) at high temporal resolution remains a technological challenge. This study introduces a novel PO2 sensing technology based on Multi-Frequency Phase Fluorimetry (MFPF). The aim was to validate MFPF against polarographic Clark-type electrode (CTE) PO2 measurements. MFPF technology was first investigated in N = 8 anaesthetised pigs at FIO2 of 0.21, 0.4, 0.6, 0.8 and 1.0. At each FIO2 level, blood samples were withdrawn and PO2 was measured in vitro with MFPF using two FOXY-AL300 probes immediately followed by CTE measurement. Secondly, MFPF-PO2 readings were compared to CTE in an artificial circulatory setup (human packed red blood cells, haematocrit of 30%). The impacts of temperature (20, 30, 40°C) and blood flow (0.8, 1.6, 2.4, 3.2, 4.0 L min(-1)) on MFPF-PO2 measurements were assessed. MFPF response time in the gas- and blood-phase was determined. Porcine MFPF-PO2 ranged from 63 to 749 mmHg; the corresponding CTE samples from 43 to 712 mmHg. Linear regression: CTE = 15.59+1.18*MFPF (R(2) = 0.93; P0.05). MFPF response-time (monoexponential) was 1.48±0.26 s for the gas-phase and 1.51±0.20 s for the blood-phase. MFPF-derived PO2 readings were reproducible and showed excellent correlation and good agreement with Clark-type electrode-based PO2 measurements. There was no relevant impact of temperature and blood flow upon MFPF-PO2 measurements. The response time of the MFPF FOXY-AL300 probe was adequate for real-time sensing in the blood phase.

Polarographic determination of uranium dioxide stoichiometry; La determination polarographique de la stoechiometrie du dioxyde d'uranium

Energy Technology Data Exchange (ETDEWEB)

Viguie, J.; Uny, G. [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Grenoble, 38 (France)

1966-10-01

The method described allows the determination of small deviations from stoichiometry for uranium dioxide. It was applied to the study of surface oxidation of bulk samples. The sample is dissolved in phosphoric acid under an argon atmosphere; U(VI) is determined by polarography in PO{sub 4}H{sub 3} 4.5 N - H{sub 2}SO{sub 4} 4 N. U(IV) is determined by potentiometry. The detection limit is UO{sub 2,0002}. The accuracy for a single determination at the 95% confidence level is {+-}20 per cent for samples with composition included between UO{sub 2,001} and UO{sub 2,01}. (authors) [French] La methode decrite permet de determiner les faibles ecarts a la stoechiometrie du dioxyde d'uranium. Elle a ete appliquee a l'etude de l'oxydation superficielle des echantillons. La mise en solution s'effectue dans l'acide phosphorique concentre sous atmosphere d'argon; U(VI) est dose par polarographie dans le milieu PO{sub 4}H{sub 3} 4,5 N et H{sub 2}SO{sub 4} 4 N; U(IV) est dose par potentiometrie. La limite de detection est UO{sub 2,0002}. La precision obtenue pour une determination au taux de certitude 0,95 est de l'ordre de 20 pour cent pour des echantillons dont la teneur est comprise entre UO{sub 2,001} et UO{sub 2,01}. (auteurs)

DIFFERENTIAL PULSE ANODIC STRIPPING VOLTAMMETRY FOR DETERMINATION OF SOME HEAVY METALS IN URANIUM

Directory of Open Access Journals (Sweden)

Saryati Saryati

2010-06-01

Full Text Available The direct determination of some metals impurity in uranium by using differential pulse anodic stripping voltammetry (DPASV method at a hanging mercury drop electrode and in a carbonate buffer media was developed. It was found that the carbonate buffer show the strongest affinity for uranium and gives the best separation between the DPASV peaks of heavy metals impurities. The carbonate concentration markedly affects the oxidation and reduction the major and the minor constituents of the uranium samples. In 0.1 M carbonate buffer solution pH 10, copper, bismuth, thalium, lead, cadmium, zinc, could be determined without the removal of the uranium matrix. Recovery and relative standard deviation (RSD of this method was in the range of 174% - 85.2% for recovery and 36.8% - 1.2% for RSD. The larger error of analytical result was obtained for Zn at low concentration. In general, the analytic results error and RSD decreased with increasing metals concentration.   Keywords: heavy metal determination, differential pulse anodic stripping voltammetry, uranium

Determination of carbohydrates using pulsed amperometric detection combined with anion exchange separations

Energy Technology Data Exchange (ETDEWEB)

Edwards, W.T.; Pohl, C.A.; Rubin, R.

1987-06-01

Carbohydrates, including the monosaccharides commonly found in wood and wood pulp hydrolyzates, are separated by anion exchange chromatography using hydroxide and acetate eluants and are determined using pulsed amperometric detection. The detection method is based on oxidizing the sugars in a flow-through electrochemical cell equipped with a gold working electrode. A repeating cycle of three potentials is used: the first to oxidize the carbohydrates and measure the current generated, and two subsequent pulses to clean the electrode surface of oxidation products. The method is fast, sensitive, and requires no pre-column derivatization. It is applied to a sample of hydrolyzed wood pulp, which can be analyzed after minimal sample preparation. Detection limits are of the order of 1 mg/kg for monosaccharides in a 50 micro L injection. (Refs. 8).

Determination of the Young's modulus of pulsed laser deposited epitaxial PZT thin films

NARCIS (Netherlands)

Nazeer, H.; Nguyen, Duc Minh; Woldering, L.A.; Abelmann, Leon; Rijnders, Augustinus J.H.M.; Elwenspoek, Michael Curt

2011-01-01

We determined the Young’s modulus of pulsed laser deposited epitaxially grown PbZr0.52Ti0.48O3 (PZT) thin films on microcantilevers by measuring the difference in cantilever resonance frequency before and after deposition. By carefully optimizing the accuracy of this technique, we were able to show

Comparison of concentration pulse and tracer pulse chromatography: experimental determination of eluent uptake by bridged-ethylene hybrid ultra high performance liquid chromatography packings

Science.gov (United States)

Excess volume isotherms of acetonitrile and methanol sorbed on a C18 BEH UHPLC packing were determined over a range of pressure, temperature, flow rate and eluent composition. The isotherm measurements were carried out by two independent experimental methods, viz., concentration pulse and tracer pul...

Polarographic study of the Cu(II)/Cu(I) system in the presence of 1-ascorbic acid and 0,1 M ClK; Estudio polarografico del sistema Cu(II)/Cu(I) en presencia del acido 1-ascorbico y en ClK 0,1 M

Energy Technology Data Exchange (ETDEWEB)

Alonso Lopez, J

1969-07-01

While studying the catalytic effect of Cu{sup {down_arrow}}2 ions on the oxidation process of 1-ascorbic acid, it has been observed that, in a 0,1 M solution of K1 at a pH 6 to 7, the above acid gives rise in the presence of Cu{sup {down_arrow}}2 ions to a polarographic wave of half-wave potential of -0,41 V (vs. S.C.E.). (Author) 14 refs.

Differential Pulse Anodic Stripping Voltammetry for Mercury Determination

Directory of Open Access Journals (Sweden)

Vereștiuc Paul C.

2015-07-01

Full Text Available In the present work voltammetric investigations have been performed on HgCl2 aqueous solutions prepared from a Cz 9024 reagent. Carbon paste electrode (CPE, eriochrome black T modified carbon paste electrode (MCPE/EBT and KCl 1M as background electrolyte, were involved within the experimental procedures. Cyclic voltammetry (CV has been performed in order to compare the behaviour of the two electrodes in both K3[Fe(CN6] and mercury calibration aqueous solution. Differential pulse anodic stripping voltammetry (DPASV was used to determine the most suitable parameters for mercury determination. All experiments were performed at 25 ± 1 ℃, using an electrochemical cell with three-electrodes connected to an Autolab PG STAT 302N (Metrohm-Autolab potentiostat that is equipped with Nova 1.11 software. The measured potential values were generated by using the silver chloride electrode (AgClE as reference and a platinum wire electrode as auxiliary. A series of time depending equations for the pre-concentration and concentration steps were established, with the observation that a higher sensitivity can be obtained while increasing the pre-concentration time. DPASV were drawn using the CPE in 11.16 % coriander, as mercury complex, the voltamograms signals indicating mercury oxidation, with signal intensity increasing in time.

The contents of sesamol and related lignans in sesame, tahina and halva as determined by a newly developed polarographic and stripping voltammetric analysis

Directory of Open Access Journals (Sweden)

2009-06-01

Full Text Available The contents of antioxidant lignans (Sesamol in sesame, commercial formulations of tahina and halva, which are processed tahina foods, were determined by Differential Pulse Polarography (DPP with a capillary hanging mercury drop electrode (HMDE. A platinum wire was used as the counter electrode and Ag/AgCl was the reference electrode. Samples have been analyzed by standard addition procedures and found to be quantitative (p2=0.9999 (pSe determinó el contenido del lignano antioxidante (Sesamol en sésamo, formulaciones comerciales de tahina y halva, que es el producto procesado de tahina, por polarografía de pulsos diferencial (DPP con un capilar conteniendo un electrodo de gota de mercurio (HMDE. Un hilo de platino fué usado como el electrodo contador y Ag/AgCl como electrodo de referencia. Las muestras fueron analizadas por procedimientos de adición de patrones y se encontró que wl procedimiento era cuantitativo (p2= 0.9999 (p< 0.01. El método polarográfico propuesto (DPP es un método rápido y reproducible para la determinación simultánea de lignanos fenólicos en sésamo y otros productos alimentarios que contienen sésamo. Éste proporciona una detección cuantitativa adecuada y sensible de este compuesto nutraceútico en alimentos comerciales.

Determination of one-electron reduction potentials of some radiosensitive compounds by pulse radiolysis

International Nuclear Information System (INIS)

Zuo Zhihua; Yao Side; Li Hucheng; Lin Nianyun; Jin Yizun

1994-01-01

One-electron reduction potential (E 7 1 ) is one of the important parameters of radiosensitive compound with high electron affinity. In this work one-electron reduction potentials of some radiosensitizers, such as Miso, 911, CMNa, SMU-1, SMU-2, SMD, SNN, S 3 and BSO, were determined pulse radiolytically by using anthraquinone-2-sulfate (AQS), duroquinone (DQ) and methyl viologen (MV 2+ ) as references

Separation and determination of alditols and sugars by high-pH anion-exchange chromatography with pulsed amperometric detection

DEFF Research Database (Denmark)

Andersen, Rikke; Sørensen, A.

2000-01-01

Carbohydrates such as alditols (polyols or sugar alcohols), monosaccharides and disaccharides are separated as anions by anion-exchange chromatography with a sodium hydroxide eluent, MA1 CarboPac column and pulsed amperometric detection. We report a high-pH anion-exchange chromatographic-pulsed a......Carbohydrates such as alditols (polyols or sugar alcohols), monosaccharides and disaccharides are separated as anions by anion-exchange chromatography with a sodium hydroxide eluent, MA1 CarboPac column and pulsed amperometric detection. We report a high-pH anion-exchange chromatographic......-pulsed amperometric detection (HPAEC-PAD) method that determines all the polyols used as food additives in food products and the most commonly found mono- and disaccharides on a routine basis. The linearity, repeatability, internal reproducibility and accuracy are described. The applicability of the method has been...

Determination of chlorine, sulfur and carbon in reinforced concrete structures by double-pulse laser-induced breakdown spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Labutin, Timur A., E-mail: timurla@laser.chem.msu.ru [Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory 1-3, Moscow 119991 (Russian Federation); Popov, Andrey M.; Zaytsev, Sergey M.; Zorov, Nikita B. [Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory 1-3, Moscow 119991 (Russian Federation); Belkov, Mikhail V.; Kiris, Vasilii V.; Raikov, Sergey N. [B.I. Stepanov Institute of Physics, Nezavisimosti Ave. 68, Minsk 220072 (Belarus)

2014-09-01

Accurate and reliable quantitative determination of non-metal corrosion agents in concrete is still an actual task of analytical use of LIBS. Two double-pulse LIBS systems were tested as a tool for the determination of chlorine, sulfur and carbon in concretes. Both systems had collinear configuration; a laboratory setup was equipped with an ICCD and two lasers (355/532 nm + 540 nm), but a CCD was a detector for a mobile system with one laser (1064 nm). Analytical lines of Cl I at 837.59 nm, S I at 921 nm and C I at 247.86 nm were used to plot calibration curves. Optimal interpulse delays for the laboratory setup were 4 μs for chlorine and 2.8 μs for carbon, while an interpulse delay of 2 μs was optimal for chlorine and sulfur determination with the mobile system. We suggested the normalization of the Cl I line at 837.59 nm to the Mg II line at 279.08 nm (visible at 837.23 nm in the third order) to compensate for pulse-to-pulse fluctuations of chlorine lines. It provided the decrease of the detection limit of chlorine from 400 ppm to 50 ppm. Therefore, we reported that LIBS can be used to determine main corrosive active substances under ambient conditions in concrete below critical threshold values. Moreover, the application of the mobile system for in-situ qualitative assessment of corrosion way of a steel cage of a swimming pool dome was also demonstrated. It was found that chloride corrosion due to the disinfection of water was the main way for corrosion of the open part steel and the steel rebar inside the concrete. - Highlights: • Determination of chlorine, sulfur and carbon in concrete in the air. • Comparison of mobile and laboratory LIBS systems. • LOD by double-pulse LIBS under ambient conditions: for sulfur 1500 ppm, for chlorine — 50 ppm. • Background level of carbon content in concrete is about 0.27% wt.

Pulse shape analysis and position determination in segmented HPGe detectors: The AGATA detector library

Energy Technology Data Exchange (ETDEWEB)

Bruyneel, B. [Universitaet zu Koeln, Institut fuer Kernphysik, Koeln (Germany); Service de Physique Nucleaire, CEA Saclay, Gif-sur-Yvette (France); Birkenbach, B.; Reiter, P. [Universitaet zu Koeln, Institut fuer Kernphysik, Koeln (Germany)

2016-03-15

The AGATA Detector Library (ADL) was developed for the calculation of signals from highly segmented large volume high-purity germanium (HPGe) detectors. ADL basis sets comprise a huge amount of calculated position-dependent detector pulse shapes. A basis set is needed for Pulse Shape Analysis (PSA). By means of PSA the interaction position of a γ -ray inside the active detector volume is determined. Theoretical concepts of the calculations are introduced and cover the relevant aspects of signal formation in HPGe. The approximations and the realization of the computer code with its input parameters are explained in detail. ADL is a versatile and modular computer code; new detectors can be implemented in this library. Measured position resolutions of the AGATA detectors based on ADL are discussed. (orig.)

Determination of moisture in black coal using pulsed nuclear magnetic resonance spectrometry

International Nuclear Information System (INIS)

Cutmore, N.G.; Sowerby, B.D.; Lynch, L.J.; Webster, D.S.

1987-01-01

Pulsed nuclear magnetic resonance (n.m.r.) spectrometry was investigated as a technique for moisture determination in fine product coal from eight Australian coal washeries. Measurements were made on samples of diameter 8 and 12 mm and length 10 and 120 mm at frequencies from 6.5 to 60 MHz. The ratio of intensities of the water and coal components in the free-induction decay signal can be used to determine moisture to within approx. 0.4-0.7 wt% over the range 0-26 wt% moisture, independent of sample density. This accuracy is independent of particle size (up to 1 mm) and little affected by coal rank, sample length or n.m.r. frequency. (author)

Loudness of tone pulses in a free field

DEFF Research Database (Denmark)

Poulsen, Torben

1981-01-01

Investigations of temporal loudness summation of tone pulses have been performed. The investigations comprised equal loudness determinations between pairs of tone pulses with a duration ratio of 1:2, and threshold determinations of the same tone pulses. Pulse durations ranged from 5 to 640 ms...

Determination of the form of very short luminous pulses. Application to scintillation phenomena (1962); Determination de la forme des impulsions lumineuses tres breves. Application aux phenomenes de scintillation (1962)

Energy Technology Data Exchange (ETDEWEB)

Koechlin, Y [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1961-12-15

During studies on photomultipliers and scintillators we have developed a new method of measurement making it possible to determine with precision the form of luminous pulses whose duration may be less that of an anodic photomultiplier pulse. This method, which can be applied to non-recurrent pulses, makes possible the study of scintillations caused by particles of photons in the case where it is possible to operate on a large number of pulses having the same form. We have thus determined the form of the scintillations of various fluorescent liquids excited by {alpha} particles and {gamma} photons. The results obtained are in agreement with the energy transfer theory for organic liquids elaborated by H. Kallmann and M. FURST. The results are used to determine exactly the parameters occurring in the theory. (author) [French] A l'occasion d'etudes sur les photomultiplicateurs et les scintillateurs nous avons mis au point une nouvelle methode de mesure permettant de determiner avec precision la forme des impulsions lumineuses dont la duree peut etre inferieure a celle d'une impulsion anodique de photomultiplicateur. Cette methode, qui peut s'appliquer a des impulsions non recurrentes, permet d'etudier les scintillations provoquees par des particules ou des photons, a la seule condition que l'on puisse operer sur un grand nombre d'impulsions ayant la meme forme. Nous avons determine ainsi la forme des scintillations des divers liquides fluorescents excites par des particules {alpha} et des photons {gamma} Les resultats obtenus sont en accord avec la theorie des transferts d'energie dans les scintillateurs organiques, elaboree par H. KALLMANN et M. FURST. Ils conduisent a une determination precise des parameters intervenant dans cette theorie. (auteur)

Part I. Application of pulse polarography and pulse anodic stripping to the determination of selected heavy metals in natural waters. Part II. Application of controlled potential coulometric techniques to the determination of uranium

International Nuclear Information System (INIS)

Crosmun, S.T.

1977-06-01

The use of a thin mercury film wax-impregnated graphite electrode for the simultaneous determination of cadmium, lead and zinc in an acetate buffer by differential pulse anodic stripping voltammetry is described. Optimal instrumental parameters for maximum resolution and sensitivity for simultaneous analysis of these three elements in natural waters are discussed. The interference of copper with the determination of zinc is investigated in detail. An optimal mercury film thickness for this electrode is suggested. A method utilizing differential pulse polarography for the determination of chromium (VI) in natural water is described. Additions of 0.62 μg Cu(II) ml -1 and 0.55 μg Fe(III) ml -1 did not interfere with the determination of 0.050 μg Cr(VI) ml -1 . The natural water samples containing Cr(VI) were buffered to approximately pH 7 with 0.1 M ammonium acetate and 0.005 M ethylenediamine and analyzed. Natural water samples of chromium from 0.035 μg to 2.0 μg.ml -1 may be analyzed directly without further preparation. The detection limit is 0.010 μg.ml -1 . A novel, highly efficient cell with integral stirrer for controlled potential coulometry is described. This cell was used to demonstrate the feasibility of determining uranium (VI) by predictive coulometry. A PDP 8/I minicomputer was used to predict the coulometric endpoint with high accuracy within 2.5 minutes in a titration which normally takes about 10 minutes. This technique was shown to yield acceptable results even in the presence of an interfering phosphate matrix

Simultaneous determination of 13 carbohydrates using high-performance anion-exchange chromatography coupled with pulsed amperometric detection and mass spectrometry.

Science.gov (United States)

Zhao, Dan; Feng, Feng; Yuan, Fei; Su, Jin; Cheng, Yan; Wu, Hanqiu; Song, Kun; Nie, Bo; Yu, Lian; Zhang, Feng

2017-04-01

A simple, accurate, and highly sensitive method was developed for the determination of 13 carbohydrates in polysaccharide of Spirulina platensis based on high-performance anion-exchange chromatography coupled with pulsed amperometric detection and mass spectrometry. Samples were extracted with deionized water using ultrasonic-assisted extraction, and the ultrasound-assisted extraction conditions were optimized by Box-Behnken design. Then the extracted polysaccharide was hydrolyzed by adding 1 mol/L trifluoroacetic acid before determination by high-performance anion-exchange chromatography coupled with pulsed amperometric detection and confirmed by high-performance anion-exchange chromatography coupled with mass spectrometry. The high-performance anion-exchange chromatography coupled with pulsed amperometric detection method was performed on a CarboPac PA20 column by gradient elution using deionized water, 0.1 mol/L sodium hydroxide solution, and 0.4 mol/L sodium acetate solution. Excellent linearity was observed in the range of 0.05-10 mg/L. The average recoveries ranged from 80.7 to 121.7%. The limits of detection and limits of quantification for 13 carbohydrates were 0.02-0.10 and 0.2-1.2  μg/kg, respectively. The developed method has been successfully applied to ambient samples, and the results indicated that high-performance anion-exchange chromatography coupled with pulsed amperometric detection and mass spectrometry could provide a rapid and accurate method for the simultaneous determination of carbohydrates. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Quantitative determination of arterial wall mechanics with pulse oximetric finger plethysmography.

Science.gov (United States)

Kato, R; Sato, J; Iuchi, T; Higuchi, Y

1999-10-30

The plethysmographic wave of pulse oximetry reflects arterial pulsation at the fingertip. Since arterial pressure and the pulsatile component of the arterial cross section represent the input and output of the fingertip arterial system, respectively, arterial wall mechanics may be delineated from their relationship. We aimed to construct a mathematical model of the fingertip arterial wall from the relationship between the plethysmographic wave and arterial pressure. The pulse oximetric plethysmographic signal at the forefinger and pressure at the ipsilateral radial artery were measured. Employing the data, simple mathematical models with one to four mechanical elements were tested in terms of the goodness of fit and the physiological implications. The determined model was applied to the data obtained during administration of vasoactive agents in anesthetized patients. The mathematical model suited for describing arterial wall mechanics was a four-element, two-compartment model. The two compartments represent passive mechanical and active contractile properties, respectively. In the application of the model to the anesthetized patients, the vasoactive agents produced changes in the model parameters that implied mechanical alterations in the arterial wall. These findings suggest the benefit of the four-element, two-compartment model in analyzing peripheral vascular wall mechanics influenced by various stimuli in intensive care and anesthesia.

Simultaneous determination of three herbicides by differential pulse voltammetry and chemometrics.

Science.gov (United States)

Ni, Yongnian; Wang, Lin; Kokot, Serge

2011-01-01

A novel differential pulse voltammetry method (DPV) was researched and developed for the simultaneous determination of Pendimethalin, Dinoseb and sodium 5-nitroguaiacolate (5NG) with the aid of chemometrics. The voltammograms of these three compounds overlapped significantly, and to facilitate the simultaneous determination of the three analytes, chemometrics methods were applied. These included classical least squares (CLS), principal component regression (PCR), partial least squares (PLS) and radial basis function-artificial neural networks (RBF-ANN). A separately prepared verification data set was used to confirm the calibrations, which were built from the original and first derivative data matrices of the voltammograms. On the basis relative prediction errors and recoveries of the analytes, the RBF-ANN and the DPLS (D - first derivative spectra) models performed best and are particularly recommended for application. The DPLS calibration model was applied satisfactorily for the prediction of the three analytes from market vegetables and lake water samples.

One-day pulsed-field gel electrophoresis protocol for rapid determination of emetic Bacillus cereus isolates.

Science.gov (United States)

Kaminska, Paulina S; Fiedoruk, Krzysztof; Jankowska, Dominika; Mahillon, Jacques; Nowosad, Karol; Drewicka, Ewa; Zambrzycka, Monika; Swiecicka, Izabela

2015-04-01

Bacillus cereus, the Gram-positive and spore-forming ubiquitous bacterium, may cause emesis as the result of food intoxication with cereulide, a heat-stable emetic toxin. Rapid determination of cereulide-positive B. cereus isolates is of highest importance due to consequences of this intoxication for human health and life. Here we present a 1-day pulsed-field gel electrophoresis for emetic B. cereus isolates, which allows rapid and efficient determination of their genomic relatedness and helps determining the source of intoxication in case of outbreaks caused by these bacilli. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The simplest equivalent circuit of a pulsed dielectric barrier discharge and the determination of the gas gap charge transfer

Science.gov (United States)

Pipa, A. V.; Koskulics, J.; Brandenburg, R.; Hoder, T.

2012-11-01

The concept of the simplest equivalent circuit for a dielectric barrier discharge (DBD) is critically reviewed. It is shown that the approach is consistent with experimental data measured either in large-scale sinusoidal-voltage driven or miniature pulse-voltage driven DBDs. An expression for the charge transferred through the gas gap q(t) is obtained with an accurate account for the displacement current and the values of DBD reactor capacitance. This enables (i) the significant reduction of experimental error in the determination of q(t) in pulsed DBDs, (ii) the verification of the classical electrical theory of ozonizers about maximal transferred charge qmax, and (iii) the development of a graphical method for the determination of qmax from charge-voltage characteristics (Q-V plots, often referred as Lissajous figures) measured under pulsed excitation. The method of graphical presentation of qmax is demonstrated with an example of a Q-V plot measured under pulsed excitation. The relations between the discharge current jR(t), the transferred charge q(t), and the measurable parameters are presented in new forms, which enable the qualitative interpretation of the measured current and voltage waveforms without the knowledge about the value of the dielectric barrier capacitance Cd. Whereas for quantitative evaluation of electrical measurements, the accurate estimation of the Cd is important.

Comparison between some determination methods of residual styrene in plastic scintillators

International Nuclear Information System (INIS)

Bezuglyi, V.D.; Ponomarev, Yu.P.; Gunder, O.A.; Biteman, V.B.; Senchishin, V.G.

1988-01-01

Scintillators made of plastic materials based on polystyrene with addition of p-terphenyl and 1,4-di-[(2,5-phenyl)oxazolyl] benzene have found wide application principally in the detection of radioactivity. The stability of the scintillating characteristics of these materials depends to great degree on the concentration of the residual monomer and for this reason it is important to have a sufficiently convenient method for the determination of this latter. We investigated the bromometric and acid-base titration methods with visual and potentiometric titration end point detection. We also examined the polarographic methods, direct and indirect, using the electroreduction of the mercury acetate complex of the monomer. We checked the methods on a scintillator sample and on synthetic mixtures, i.e., mixtures of monomer, polymer, and p-terphenyl. We compared the determination results for styrene and showed that the most accurate procedure is the bromometric determination with potentiometric indication of the end-point

Parameters affecting the determination of paraquat at silver rotating electrodes using differential pulse voltammetry

Directory of Open Access Journals (Sweden)

A. Farahi

2014-08-01

Full Text Available The electrochemical determination of aqueous paraquat PQ(II by differential pulse voltammetry at a solid rotating silver electrode (RSE is described. The aim of this work is to optimize all factors that can influence this determination. Potential wave forms, potential scan parameters and deposition time were examined for their effect on the paraquat peak shape and intensity. The best responses were obtained with differential pulse voltammetry in 0.1 mol L−1 Na2SO4 as supporting electrolyte using amplitude 50 mV, scan increment 5 mV, deposition time 120 s, frequency 50 s−1 and step amplitude 0.05 V. Electrochemical and mechanical surface cleaning, aimed at removing the amount of paraquat deposited onto the silver surface, were necessary for obtaining a good performance of the electrode. Response linearity, repeatability, accuracy and detection limit were also evaluated. The obtained detection limits were 7.1 × 10−9 mol L−1 and 2.8 × 10−9 mol L−1 for peak 1 and peak 2 respectively. The relative standard deviation (RSD was found to be 1.19% in 1.0 × 10−4 mol L−1 paraquat. The applicability of the RSE for PQ(II determination in milk samples, without any sample pretreatment, was successfully demonstrated.

Evaluation of pulsed streamer corona experiments to determine the O* radical yield

International Nuclear Information System (INIS)

Van Heesch, E J M; Winands, G J J; Pemen, A J M

2008-01-01

The production of O* radicals in air by a pulsed streamer plasma is studied by integration of a large set of precise experimental data and the chemical kinetics of ozone production. The measured data comprise ozone production, plasma energy, streamer volume, streamer length, streamer velocity, humidity and gas-flow rate. Instead of entering input parameters into a kinetic model to calculate the end products the opposite strategy is followed. Since the amount of end-products (ozone) is known from the measurements the model had to be applied in the reverse direction to determine the input parameters, i.e. the O* radical concentration.

Evaluation of pulsed streamer corona experiments to determine the O* radical yield

Science.gov (United States)

van Heesch, E. J. M.; Winands, G. J. J.; Pemen, A. J. M.

2008-12-01

The production of O* radicals in air by a pulsed streamer plasma is studied by integration of a large set of precise experimental data and the chemical kinetics of ozone production. The measured data comprise ozone production, plasma energy, streamer volume, streamer length, streamer velocity, humidity and gas-flow rate. Instead of entering input parameters into a kinetic model to calculate the end products the opposite strategy is followed. Since the amount of end-products (ozone) is known from the measurements the model had to be applied in the reverse direction to determine the input parameters, i.e. the O* radical concentration.

Pulsed irradiation of enriched UO{sub 2} in the Annular Core Pulse Reactor (ACPR)

Energy Technology Data Exchange (ETDEWEB)

Schmidt, T R; Lucoff, D M; Reil, K O; Croucher, D W [Sandia Laboratories (United States)

1974-07-01

A series of experiments have been conducted in the Annular Core Pulse Reactor (ACPR) to determine the energy deposition and behavior of enriched UO{sub 2} under pulse conditions. In the experiment single unirradiated pellets with enrichments up to 25 percent were pulse heated to melt temperatures. Temperature and fission product inventory measurements were made and compared with neutron transport calculations. (author)

The simplest equivalent circuit of a pulsed dielectric barrier discharge and the determination of the gas gap charge transfer

International Nuclear Information System (INIS)

Pipa, A. V.; Brandenburg, R.; Hoder, T.; Koskulics, J.

2012-01-01

The concept of the simplest equivalent circuit for a dielectric barrier discharge (DBD) is critically reviewed. It is shown that the approach is consistent with experimental data measured either in large-scale sinusoidal-voltage driven or miniature pulse-voltage driven DBDs. An expression for the charge transferred through the gas gap q(t) is obtained with an accurate account for the displacement current and the values of DBD reactor capacitance. This enables (i) the significant reduction of experimental error in the determination of q(t) in pulsed DBDs, (ii) the verification of the classical electrical theory of ozonizers about maximal transferred charge q max , and (iii) the development of a graphical method for the determination of q max from charge-voltage characteristics (Q-V plots, often referred as Lissajous figures) measured under pulsed excitation. The method of graphical presentation of q max is demonstrated with an example of a Q-V plot measured under pulsed excitation. The relations between the discharge current j R (t), the transferred charge q(t), and the measurable parameters are presented in new forms, which enable the qualitative interpretation of the measured current and voltage waveforms without the knowledge about the value of the dielectric barrier capacitance C d . Whereas for quantitative evaluation of electrical measurements, the accurate estimation of the C d is important.

Determination of base-line levels of trace amounts in pulses and spices using neutron activation technique

International Nuclear Information System (INIS)

Zaidi, J.H.; Arif, M.; Fatima, I.; Qureshi, I.H.

1993-01-01

It has been established that essential trace elements are vitally important for biochemical systems, whereas toxic elements if present in relatively higher amounts adversely affect these systems. Trace elements reach the human body mainly through foodstuffs. The different articles contain varying amount of toxic and essential elements. It is therefore necessary to asses the adequacy and safety of the diet by determining the base-line levels of these elements. In continuation of our previous work, some varieties of pulses and spices were analyzed using neutron activation technique. Among the four varieties of pulses lentil (lens esculenta) was found to contain higher amounts of essential elements and lower amounts of toxic elements. The daily intake of essential and toxic elements through pulses was estimated and compared with the suggested values. The estimated intake of essential elements is adequate and that of toxic elements is well below the tolerance limit. In spices cumin and caraway seeds were found to contain relatively higher amounts of essential as well as toxic elements. The studies showed that food spices were additional source of trace element intake. (author)

Heat pulse propagation studies in TFTR

Energy Technology Data Exchange (ETDEWEB)

Fredrickson, E.D.; Callen, J.D.; Colchin, R.J.; Efthimion, P.C.; Hill, K.W.; Izzo, R.; Mikkelsen, D.R.; Monticello, D.A.; McGuire, K.; Bell, J.D.

1986-02-01

The time scales for sawtooth repetition and heat pulse propagation are much longer (10's of msec) in the large tokamak TFTR than in previous, smaller tokamaks. This extended time scale coupled with more detailed diagnostics has led us to revisit the analysis of the heat pulse propagation as a method to determine the electron heat diffusivity, chi/sub e/, in the plasma. A combination of analytic and computer solutions of the electron heat diffusion equation are used to clarify previous work and develop new methods for determining chi/sub e/. Direct comparison of the predicted heat pulses with soft x-ray and ECE data indicates that the space-time evolution is diffusive. However, the chi/sub e/ determined from heat pulse propagation usually exceeds that determined from background plasma power balance considerations by a factor ranging from 2 to 10. Some hypotheses for resolving this discrepancy are discussed. 11 refs., 19 figs., 1 tab.

Heat pulse propagation studies in TFTR

International Nuclear Information System (INIS)

Fredrickson, E.D.; Callen, J.D.; Colchin, R.J.

1986-02-01

The time scales for sawtooth repetition and heat pulse propagation are much longer (10's of msec) in the large tokamak TFTR than in previous, smaller tokamaks. This extended time scale coupled with more detailed diagnostics has led us to revisit the analysis of the heat pulse propagation as a method to determine the electron heat diffusivity, chi/sub e/, in the plasma. A combination of analytic and computer solutions of the electron heat diffusion equation are used to clarify previous work and develop new methods for determining chi/sub e/. Direct comparison of the predicted heat pulses with soft x-ray and ECE data indicates that the space-time evolution is diffusive. However, the chi/sub e/ determined from heat pulse propagation usually exceeds that determined from background plasma power balance considerations by a factor ranging from 2 to 10. Some hypotheses for resolving this discrepancy are discussed. 11 refs., 19 figs., 1 tab

Changes in properties of DNA caused by gamma and ultraviolet radiation. Dependence of conformational changes on the chemical nature of the damage

Energy Technology Data Exchange (ETDEWEB)

Vorlickova, M; Palacek, E [Ceskoslovenska Akademie Ved, Brno. Biofysikalni Ustav

1978-02-16

Changes in the pulse-polarographic behaviour and circular dichroism spectra of DNA were investigated after gamma and ultraviolet irradiations and after degradation by DNAase I. It was found that moderate doses of radiation cause local conformational changes in the double helix which are dependent on the chemical nature of the damage. Only the accumulation of structural changes after high doses of the radiations or after extensive enzymic treatment may cause formation of single-standed regions in DNA.

Determination of chlorine, sulfur and carbon in reinforced concrete structures by double-pulse laser-induced breakdown spectroscopy

Science.gov (United States)

Labutin, Timur A.; Popov, Andrey M.; Zaytsev, Sergey M.; Zorov, Nikita B.; Belkov, Mikhail V.; Kiris, Vasilii V.; Raikov, Sergey N.

2014-09-01

Accurate and reliable quantitative determination of non-metal corrosion agents in concrete is still an actual task of analytical use of LIBS. Two double-pulse LIBS systems were tested as a tool for the determination of chlorine, sulfur and carbon in concretes. Both systems had collinear configuration; a laboratory setup was equipped with an ICCD and two lasers (355/532 nm + 540 nm), but a CCD was a detector for a mobile system with one laser (1064 nm). Analytical lines of Cl I at 837.59 nm, S I at 921 nm and C I at 247.86 nm were used to plot calibration curves. Optimal interpulse delays for the laboratory setup were 4 μs for chlorine and 2.8 μs for carbon, while an interpulse delay of 2 μs was optimal for chlorine and sulfur determination with the mobile system. We suggested the normalization of the Cl I line at 837.59 nm to the Mg II line at 279.08 nm (visible at 837.23 nm in the third order) to compensate for pulse-to-pulse fluctuations of chlorine lines. It provided the decrease of the detection limit of chlorine from 400 ppm to 50 ppm. Therefore, we reported that LIBS can be used to determine main corrosive active substances under ambient conditions in concrete below critical threshold values. Moreover, the application of the mobile system for in-situ qualitative assessment of corrosion way of a steel cage of a swimming pool dome was also demonstrated. It was found that chloride corrosion due to the disinfection of water was the main way for corrosion of the open part steel and the steel rebar inside the concrete.

Method for pulse to pulse dose reproducibility applied to electron linear accelerators

International Nuclear Information System (INIS)

Ighigeanu, D.; Martin, D.; Oproiu, C.; Cirstea, E.; Craciun, G.

2002-01-01

An original method for obtaining programmed beam single shots and pulse trains with programmed pulse number, pulse repetition frequency, pulse duration and pulse dose is presented. It is particularly useful for automatic control of absorbed dose rate level, irradiation process control as well as in pulse radiolysis studies, single pulse dose measurement or for research experiments where pulse-to-pulse dose reproducibility is required. This method is applied to the electron linear accelerators, ALIN-10 of 6.23 MeV and 82 W and ALID-7, of 5.5 MeV and 670 W, built in NILPRP. In order to implement this method, the accelerator triggering system (ATS) consists of two branches: the gun branch and the magnetron branch. ATS, which synchronizes all the system units, delivers trigger pulses at a programmed repetition rate (up to 250 pulses/s) to the gun (80 kV, 10 A and 4 ms) and magnetron (45 kV, 100 A, and 4 ms).The accelerated electron beam existence is determined by the electron gun and magnetron pulses overlapping. The method consists in controlling the overlapping of pulses in order to deliver the beam in the desired sequence. This control is implemented by a discrete pulse position modulation of gun and/or magnetron pulses. The instabilities of the gun and magnetron transient regimes are avoided by operating the accelerator with no accelerated beam for a certain time. At the operator 'beam start' command, the ATS controls electron gun and magnetron pulses overlapping and the linac beam is generated. The pulse-to-pulse absorbed dose variation is thus considerably reduced. Programmed absorbed dose, irradiation time, beam pulse number or other external events may interrupt the coincidence between the gun and magnetron pulses. Slow absorbed dose variation is compensated by the control of the pulse duration and repetition frequency. Two methods are reported in the electron linear accelerators' development for obtaining the pulse to pulse dose reproducibility: the method

Determination of transport and reaction swarm coefficients from the analysis of complex transient pulses from the pulsed Townsend experiment

International Nuclear Information System (INIS)

Bekstein, A; De Urquijo, J; Rodríguez-Luna, J C; Juárez, A M; Ducasse, O

2012-01-01

We present in this paper the interpretation and analysis of transient pulses from a pulsed Townsend experiment by solving the continuity equations of the charged carriers (electrons and ions) involved in the avalanche. The set of second order partial differential equations is solved by SIMAV, a simulator designed specifically for the pulsed Townsend avalanche. Complex situations involving processes such as electron detachment, ion-molecule reactions, Penning ionization and secondary electron emission from ion impact at the cathode, virtually impossible to solve analytically, are discussed here to illustrate the capability of the simulator to help explain the various reaction processes involved in the avalanche, and also to derive some of the transport and reaction coefficients.

Multi Frequency Phase Fluorimetry (MFPF) for Oxygen Partial Pressure Measurement: Ex Vivo Validation by Polarographic Clark-Type Electrode

Science.gov (United States)

Boehme, Stefan; Duenges, Bastian; Klein, Klaus U.; Hartwich, Volker; Mayr, Beate; Consiglio, Jolanda; Baumgardner, James E.; Markstaller, Klaus; Basciani, Reto; Vogt, Andreas

2013-01-01

Background Measurement of partial pressure of oxygen (PO2) at high temporal resolution remains a technological challenge. This study introduces a novel PO2 sensing technology based on Multi-Frequency Phase Fluorimetry (MFPF). The aim was to validate MFPF against polarographic Clark-type electrode (CTE) PO2 measurements. Methodology/Principal Findings MFPF technology was first investigated in N = 8 anaesthetised pigs at FIO2 of 0.21, 0.4, 0.6, 0.8 and 1.0. At each FIO2 level, blood samples were withdrawn and PO2 was measured in vitro with MFPF using two FOXY-AL300 probes immediately followed by CTE measurement. Secondly, MFPF-PO2 readings were compared to CTE in an artificial circulatory setup (human packed red blood cells, haematocrit of 30%). The impacts of temperature (20, 30, 40°C) and blood flow (0.8, 1.6, 2.4, 3.2, 4.0 L min−1) on MFPF-PO2 measurements were assessed. MFPF response time in the gas- and blood-phase was determined. Porcine MFPF-PO2 ranged from 63 to 749 mmHg; the corresponding CTE samples from 43 to 712 mmHg. Linear regression: CTE = 15.59+1.18*MFPF (R2 = 0.93; PPO2 ranged from 20 to 567 mmHg and CTE samples from 11 to 575 mmHg. Linear regression: CTE = −8.73+1.05*MFPF (R2 = 0.99; PPO2 due to variations of temperature were less than 6 mmHg (range 0–140 mmHg) and less than 35 mmHg (range 140–750 mmHg); differences due to variations in blood flow were less than 15 mmHg (all P-values>0.05). MFPF response-time (monoexponential) was 1.48±0.26 s for the gas-phase and 1.51±0.20 s for the blood-phase. Conclusions/Significance MFPF-derived PO2 readings were reproducible and showed excellent correlation and good agreement with Clark-type electrode-based PO2 measurements. There was no relevant impact of temperature and blood flow upon MFPF-PO2 measurements. The response time of the MFPF FOXY-AL300 probe was adequate for real-time sensing in the blood phase. PMID:23565259

Identification of critical equipment and determination of operational limits in helium refrigerators under pulsed heat load

Science.gov (United States)

Dutta, Rohan; Ghosh, Parthasarathi; Chowdhury, Kanchan

2014-01-01

Large-scale helium refrigerators are subjected to pulsed heat load from tokamaks. As these plants are designed for constant heat loads, operation under such varying load may lead to instability in plants thereby tripping the operation of different equipment. To understand the behavior of the plant subjected to pulsed heat load, an existing plant of 120 W at 4.2 K and another large-scale plant of 18 kW at 4.2 K have been analyzed using a commercial process simulator Aspen Hysys®. A similar heat load characteristic has been applied in both quasi steady state and dynamic analysis to determine critical stages and equipment of these plants from operational point of view. It has been found that the coldest part of both the cycles consisting JT-stage and its preceding reverse Brayton stage are the most affected stages of the cycles. Further analysis of the above stages and constituting equipment revealed limits of operation with respect to variation of return stream flow rate resulted from such heat load variations. The observations on the outcome of the analysis can be used for devising techniques for steady operation of the plants subjected to pulsed heat load.

Rapid thermal pulse annealing

International Nuclear Information System (INIS)

Miller, M.G.; Koehn, B.W.; Chaplin, R.L.

1976-01-01

Characteristics of recovery processes have been investigated for cases of heating a sample to successively higher temperatures by means of isochronal annealing or by using a rapid pulse annealing. A recovery spectra shows the same features independent of which annealing procedure is used. In order to determine which technique provides the best resolution, a study was made of how two independent first-order processes are separated for different heating rates and time increments of the annealing pulses. It is shown that the pulse anneal method offers definite advantages over isochronal annealing when annealing for short time increments. Experimental data by means of the pulse anneal techniques are given for the various substages of stage I of aluminium. (author)

[Pulse flows of populations of cortical neurons under low-intensity pulsed microwave: interspike intervals].

Science.gov (United States)

Chizhenkova, R A

2014-01-01

Pulse flows of populations of cortical neurons were investigated on unanesthetized nonimmobilized rabbits prior, during, and after 1-min microwave irradiation (wavelength 37.5 cm, power density 0.5-1.0 mW/cm2) in continuous and pulse-modulated modes with a frequency of 5, 20 and 100 Hz. The changes in the characteristics of interspike intervals resulted from these exposures. The peculiarity of rearrangements of pulse flows and their dynamics was determined by modes of irradiation.

Determination of residual oil saturation from time-lapse pulsed neutron capture logs in a large sandstone reservoir

International Nuclear Information System (INIS)

Syed, E.V.; Salaita, G.N.; McCaffery, F.G.

1991-01-01

Cased hole logging with pulsed neutron tools finds extensive use for identifying zones of water breakthrough and monitoring oil-water contacts in oil reservoirs being depleted by waterflooding or natural water drive. Results of such surveys then find direct use for planning recompletions and water shutoff treatments. Pulsed neutron capture (PNC) logs are useful for estimating water saturation changes behind casing in the presence of a constant, high-salinity environment. PNC log surveys run at different times, i.e., in a time-lapse mode, are particularly amenable to quantitative analysis. The combined use of the original open hole and PNC time-lapse log information can then provide information on remaining or residual oil saturations in a reservoir. This paper reports analyses of historical pulsed neutron capture log data to assess residual oil saturation in naturally water-swept zones for selected wells from a large sandstone reservoir in the Middle East. Quantitative determination of oil saturations was aided by PNC log information obtained from a series of tests conducted in a new well in the same field

Differential pulse anodic stripping voltametry for ultratrace determination of cadmium and lead in Antarctic snow

International Nuclear Information System (INIS)

Scarponi, G.; Barbante, C.; Cescon, P.

1994-01-01

Differential pulse anodic stripping voltametry has sufficient sensitivity to be used for direct determination of heavy metals in Antarctic snow, thus avoiding long and contamination-prone enrichment procedures. A result of particular concern to global change studies can be drawn from these preliminary data: lead concentration in Antarctic snow decreased rapidly during the 1980s from about 10-15 pg/g to 2-4 pg/g in 1991. (authors). 16 refs., 3 figs., 1 tab

Analysis of picosecond pulsed laser melted graphite

International Nuclear Information System (INIS)

Steinbeck, J.; Braunstein, G.; Speck, J.; Dresselhaus, M.S.; Huang, C.Y.; Malvezzi, A.M.; Bloembergen, N.

1986-01-01

A Raman microprobe and high resolution TEM have been used to analyze the resolidified region of liquid carbon generated by picosecond pulse laser radiation. From the relative intensities of the zone center Raman-allowed mode for graphite at 1582 cm -1 and the disorder-induced mode at 1360 cm -1 , the average graphite crystallite size in the resolidified region is determined as a function of position. By comparison with Rutherford backscattering spectra and Raman spectra from nonosecond pulsed laser melting experiments, the disorder depth for picosecond pulsed laser melted graphite is determined as a function of irradiating energy density. Comparisons of TEM micrographs for nanosecond and picosecond pulsed laser melting experiments show that the structure of the laser disordered regions in graphite are similar and exhibit similar behavior with increasing laser pulse fluence

Determining the field emitter temperature during laser irradiation in the pulsed laser atom probe

International Nuclear Information System (INIS)

Kellogg, G.L.

1981-01-01

Three methods are discussed for determining the field emitter temperature during laser irradiation in the recently developed Pulsed Laser Atom Probe. A procedure based on the reduction of the lattice evaporation field with increasing emitter temperature is found to be the most convenient and reliable method between 60 and 500 K. Calibration curves (plots of the evaporation field versus temperature) are presented for dc and pulsed field evaporation of W, Mo, and Rh. These results show directly the important influence of the evaporation rate on the temperature dependence of the evaporation field. The possibility of a temperature calibration based on the ionic charge state distribution of field evaporated lattice atoms is also discussed. The shift in the charge state distributions which occurs when the emitter temperature is increased and the applied field strength is decreased at a constant rate of evaporation is shown to be due to the changing field and not the changing temperature. Nevertheless, the emitter temperature can be deduced from the charge state distribution for a specified evaporation rate. Charge state distributions as a function of field strength and temperature are presented for the same three materials. Finally, a preliminary experiment is reported which shows that the emitter temperature can be determined from field ion microscope observations of single atom surface diffusion over low index crystal planes. This last calibration procedure is shown to be very useful at higher temperatures (>600 K) where the other two methods become unreliable

Polarografic study about the complex formation between indium (III) and sodium azide, in aqueous media

International Nuclear Information System (INIS)

Tokoro, R.; Bertotti, M.

1988-01-01

The present work is a branch of the main work concerned with the complex formation between several metal cations and azide ligand in aqueous media. The polarographic behavior of indium in azide system showed the tendency of complexation. Using polarographic method to determine the half potential of indium at each analytical concentration afforded experimental data to evaluate the constants. The azide concentrations was modified from 1 m to 100 m , the ionic strength held at 2,0 M with sodium perchlorate, indium concentration 7.892 x 10 -4 M, and temperature kept constant at 25,0 0 C. (author) [pt

Determination of reactivity of multiplying systems filled with spherical HTGR-fuel elements using kinetic methods with regard to the pulsed-neutron method

International Nuclear Information System (INIS)

Drueke, V.

1978-06-01

At three critical or subcritical facilities - two of them filled with spherical HTGR-fuel elements - the reactivity is determined using kinetic methods. Besides the inverskinetic method the applicability of the pulsed-neutron method is investigated. The experimental results using the pulsed-neutron method are compared partly with the inverskinetic method and partly with diffusion-calculations. It is shown, that in the HTGR the space dependence of the reactivity in radial direction is not remarkable in spite of the 'kinetic distortion'; on the contrary in axial direction - the direction of the external neutron source - space dependent reactivity worths are measured. The results of the pulsed-neutron methods of Sjoestrand and Simmons-King are rather good applicable in all configurations. For the method of Sjoestrand it is necessary to select the detector positions, whereas for Simmons-King the calculated life-time determines the results. Therefore it is proposed to compare calculated and measured decay constants of the prompt neutron field in future. (orig.) [de

A hybrid pulse combining topology utilizing the combination of modularized avalanche transistor Marx circuits, direct pulse adding, and transmission line transformer.

Science.gov (United States)

Li, Jiangtao; Zhao, Zheng; Sun, Yi; Liu, Yuhao; Ren, Ziyuan; He, Jiaxin; Cao, Hui; Zheng, Minjun

2017-03-01

Numerous applications driven by pulsed voltage require pulses to be with high amplitude, high repetitive frequency, and narrow width, which could be satisfied by utilizing avalanche transistors. The output improvement is severely limited by power capacities of transistors. Pulse combining is an effective approach to increase the output amplitude while still adopting conventional pulse generating modules. However, there are drawbacks in traditional topologies including the saturation tendency of combining efficiency and waveform oscillation. In this paper, a hybrid pulse combining topology was adopted utilizing the combination of modularized avalanche transistor Marx circuits, direct pulse adding, and transmission line transformer. The factors affecting the combining efficiency were determined including the output time synchronization of Marx circuits, and the quantity and position of magnetic cores. The numbers of the parallel modules and the stages were determined by the output characteristics of each combining method. Experimental results illustrated the ability of generating pulses with 2-14 kV amplitude, 7-11 ns width, and a maximum 10 kHz repetitive rate on a matched 50-300 Ω resistive load. The hybrid topology would be a convinced pulse combining method for similar nanosecond pulse generators based on the solid-state switches.

Developments in Pulsed Neutron Activation for Determination of Water Flow in Pipes

Energy Technology Data Exchange (ETDEWEB)

Mattsson, Haakan

2003-06-01

In PNA (pulsed neutron activation) it is important that the measured data can be related to the total mass flow. In this thesis two fundamental problems of the measurement technique and data treatment have been investigated: transport/mixing and background radiation. The principle of PNA is to introduce a radioactive substance into a pipe by bombarding fluid in the pipe with neutron pulses. The fluid in the pipe is activated and subsequently transported and mixed with the flow. Gamma radiation emitted from the activity is measured with one or two detectors downstream from the activation point. The time-resolved signal from the detectors is used to calculate the average velocity of the water flow. Due to the short distance between the neutron generator and the pipe the activity in the pipe becomes highly inhomogeneous. The transport and mixing of the activity were simulated using colour which was injected into the flow. It was found that the inhomogeneous activity distribution must be taken into account if the precision of the measurements is to be improved. The shape of the background in PNA affects the shape and position of the time spectrum. The nature of the background has been determined using one detector upstream and one downstream of the neutron generator. The background was shown to be caused by {sup 16}N. A method that subtracts the background from the PNA time spectrum was also developed.

Developments in Pulsed Neutron Activation for Determination of Water Flow in Pipes

International Nuclear Information System (INIS)

Mattsson, Haakan

2003-06-01

In PNA (pulsed neutron activation) it is important that the measured data can be related to the total mass flow. In this thesis two fundamental problems of the measurement technique and data treatment have been investigated: transport/mixing and background radiation. The principle of PNA is to introduce a radioactive substance into a pipe by bombarding fluid in the pipe with neutron pulses. The fluid in the pipe is activated and subsequently transported and mixed with the flow. Gamma radiation emitted from the activity is measured with one or two detectors downstream from the activation point. The time-resolved signal from the detectors is used to calculate the average velocity of the water flow. Due to the short distance between the neutron generator and the pipe the activity in the pipe becomes highly inhomogeneous. The transport and mixing of the activity were simulated using colour which was injected into the flow. It was found that the inhomogeneous activity distribution must be taken into account if the precision of the measurements is to be improved. The shape of the background in PNA affects the shape and position of the time spectrum. The nature of the background has been determined using one detector upstream and one downstream of the neutron generator. The background was shown to be caused by 16 N. A method that subtracts the background from the PNA time spectrum was also developed

Various electroanalytical methods for the determination of uranium in different matrices

Directory of Open Access Journals (Sweden)

Alankar Shrivastava

2013-06-01

Full Text Available Uranium is a toxic material hence numerous body systems such as the kidney, brain, liver, and heart can be affected by uranium exposure. The main effect is kidney toxicity. Uranium is a naturally occurring element found in low levels in all rock, soil, and water. All uranium isotopes may also cause radiation hazards, thus without any doubt an analysis of such materials in the surrounding environment is very important. The presented review is a summarization of all electroanalytical techniques for the determination of uranium and its compounds in various matrices. Totally 43 different methods are found in our literature survey. Out of these three are polarographic, 25 potentiometry, five capillary electrophoresis and 28 voltametric methods are available in the literature. Interferences of different ions and applications in different matrices are also given for each method.

Study of laser pulses propagation through an ultrashort pulse amplifying systems for the development of an Offner temporal stretcher

International Nuclear Information System (INIS)

Cordeiro, Thiago da Silva

2009-01-01

The study of laser pulses propagation through an ultrashort pulses amplifying system containing dispersive and spectral modifying media was performed. The study emphasis was the development of an ultrashort pulse stretcher to replace the one inside a hybrid Ti:Sapphire/Cr:LiSAF CPA system operating at the Center for Lasers and Applications at IPEN/CNEN-SP. A spherical aberration free Offner stretcher was theoretically studied, aiming to obtain a stretching ratio larger than the one available in our system. The influence of the phase components in the amplified pulse final duration was also studied, and the bandwidth limiting elements of the system in operation were mapped, with the purpose of determining the conditions under which a new stretcher should be implemented. Based on the actual measurements, computing routines were implemented in order to determine the consequences of an ultrashort pulse travelling through a bandwidth limiting component. (author)

A digital long pulse integrator

International Nuclear Information System (INIS)

Broesch, J.D.; Strait, E.J.; Snider, R.T.

1996-10-01

A prototype digital integrator with very long integration capabilities has been developed and field tested on an inductive magnetic sensor on the DIII-D Tokamak. The integrator is being developed for use on ITER with a pulse length of 1000 s, and has direct applications for other long pulse Tokamaks. Inductive magnetic sensors are routinely used on existing Tokamaks, are well understood, and are extremely robust, however, they require integration of the signal to determine the magnetic field strength. The next generation of Tokamaks, will have pulse lengths of 1000 s or longer, require integrators with drift and noise characteristics compatible with the very long pulse lengths. This paper will discuss the architecture, algorithms, and programming of the Long Pulse Integrator (LPI). Of particular interest are the noise control and the built-in offset correction techniques used in this application

Stability of Benzotriazole Derivatives with Free Cu, Zn, Co and Metal-Containing Enzymes: Binding and Interaction of Methylbenzotriazoles with Superoxide Dismutase and Vitamin B12

Science.gov (United States)

Abudalo, R. A.; AbuDalo, M. A.; Hernandez, M. T.

2018-02-01

Benzotriazole derivatives form very strong bonds with transition metals, and are the most widely used type of industrial corrosion inhibitor. Some benzotriazole derivatives have been implicated as hormone regulators which also carry the ability to induce uncoupling responses or otherwise inhibit respiration processes in some microorganisms. However, the mechanisms associated with benzotriazole toxicity and inhibition are unknown. Using Differential Pulse Polarography, the stability constants of commercially significant corrosion inhibitors, 4-and 5-methylbenzotriazole, coordinated with free Cu (II) and Co (III), were determined to be 1015 and 108, respectively. Polarographic analyses were extended to confirm that methylbenzotriazole also binds the copper center(s) in the ubiquitous enzyme superoxide dismutase, and the Corrin site in the coenzyme cobalamin (vitamin B12). These results suggest that the metal-chelating ability of this unique class of compounds may confer inhibition to certain enzyme systems.

Determination of the X, Y coordinates of a pulsed ultrasonic source of signals

International Nuclear Information System (INIS)

Sokolov, B.V.; Shemyakin, V.V.

1975-01-01

A range of problems in predicting the emergency state of large-scale vessel housings are determined for subsequent solution involving acoustic emission phenomena. The authors specify the position of a given problem and present substantial grounds for selecting the minimum number of group signal receivers for unambiguous calculation of the location of the source. Relationships are obtained between X, Y - the coordinates of the pulse signal source - and experimentally measured time differences in recording of signals by group receivers. A criterion is given for selecting the true signal group combination when the receivers simultaneously record waves from several sources. Specific suggestions are made regarding the experimental information to be stored in a central computer for subsequent processing [ru

Differential pulse polarography of cadmium-and lead-urate and adsorptive stripping voltammetric determination of uric acid.

Science.gov (United States)

Gandour, M A; Ensaf-Aboul-Kasim; Amrallah, A H; Farghaly, O A

1994-03-01

The complex formation between uric acid and zinc, cadmium and lead ions has been investigated using differential pulse polarography in 0.01M NaNO(3). It is found that the complexes formed by Cd(II) and Pb(II) ions with uric acid have the stoichiometry of 1:2 and the logarithmic values of the apparent stability constant are 9.47 and 11.7, respectively. On the other hand, zinc(II) ions do not give any indication of complexation with uric acid. A sensitive voltammetric method is developed for the quantitative determination of uric acid. This method is based on controlled adsorptive preconcentration of uric acid on the hanging mercury drop electrode (HMDE), followed by tracing the voltammogram in the cathodic going potential scan. The modes used are direct current stripping voltammetry (DCSV) and differential pulse stripping voltammetry (DPSV). The detection limits found were 8 x 10(-9)M (quiescent period 15 sec) by DPSV and 1.6 x 10(-8)M by DCSV.

Experimental determination of the thermal contact conductance between two solid surfaces by the energy pulse technique

International Nuclear Information System (INIS)

Rubin, Gerson Antonio

1979-01-01

An experimental procedure for the determination of the thermal contact conductance between two solid surfaces as a function of the contact pressure and the energy of the laser radiation has been developed using the laser pulse method. A rubi laser with variable energy levels was employed as a radiating pulse energy source. The laser beam was allowed to impinge perpendicularly on the front face of a electrolytic iron 73 4 . The temperature fluctuations resulting on the back surface of the sample was detected by a thermocouple, which Is coupled to a PDP-11/45 Computer 32 Kbytes of memory, through a Analog-Digital Converter. A theoretical function, derived exclusively for the problem mentioned in this work, was adjusted by a method of least square fitting of experimental results. This adjustment yielded the value of a parameter related to the contact conductance between two surfaces. The experimental error obtained for the thermal contact conductance was +- 4.9%. (author)

Pulse radiolysis of gases

International Nuclear Information System (INIS)

Nielsen, O.J.

1984-04-01

The pulse radiolysis equipment and technique are described and its relevance to atmospheric chemistry is discussed. Pulse radiolysis of a number of different chemical systems have been used to check the validity of the proposed mechanisms: 1) The hydrogen atom yield in the pulse radiolysis of H 2 was measured by four independent calibration techniques, using reactions of H with O 2 , C1NO, and HI. The H atom yield was compared with O 2 yields in pure O 2 and in O 2 /SF 6 mixtures which lead to a value G(H) = 17.6. The rate constants at room temperature of several reactions were determined. 2) OH radical reactions with tetraalkyllead at room temperature and with ethane, methane, and a series of C1- and F-substituted methanes at 300-400 K were studied. Arrhenius parameters, A and Esub(a), were determined for several reactions. The lifetime of Pb(CH 3 ) 4 and Pb(C 2 H 5 ) 4 in ambient air is estimated. CF 2 C1 2 was found to be a very efficient third body, M, in the reaction OH + OH + M arrow H 2 O 2 + M. 3) In the H 2 S systems the HS extinction coefficient at 3242 AA was determined to 9.5 x 10 2 cm -1 mol -1 . Four rate constants at room temperature were determined. (author)

Pulse-wave morphology and pulse-wave velocity in healthy human volunteers

DEFF Research Database (Denmark)

Frimodt-Møller, M; Nielsen, A H; Kamper, A-L

2006-01-01

as smoking caused significant changes in both PWA and PWV parameters and an inter-arm difference was observed. Intra- and interobserver reproducibility was good. CONCLUSIONS: Pulse-wave measurements by applanation tonometry should be undertaken in the same arm during fasting and smoking abstinence.......OBJECTIVE: Applanation tonometry for pulse-wave analysis (PWA) and determination of pulse-wave velocity (PWV) is a non-invasive method for assessment of the central aortic pressure waveform and indices of arterial stiffness. The objective of this study was to examine the influence of eating...... and smoking on PWA and PWV measurements in order to establish standard examination conditions. Furthermore, intra- and interobserver reproducibility and the effects of varying the site of measurements were observed. MATERIAL AND METHODS: Duplicate measurements of the radial pressure waveform...

Differential Pulse Anodic Stripping Voltammetry for Mercury Determination

OpenAIRE

Vereștiuc Paul C.; Tucaliuc Oana-Maria; Breabăn Iuliana G.; Crețescu Igor; Nemțoi Gheorghe

2015-01-01

In the present work voltammetric investigations have been performed on HgCl2 aqueous solutions prepared from a Cz 9024 reagent. Carbon paste electrode (CPE), eriochrome black T modified carbon paste electrode (MCPE/EBT) and KCl 1M as background electrolyte, were involved within the experimental procedures. Cyclic voltammetry (CV) has been performed in order to compare the behaviour of the two electrodes in both K3[Fe(CN)6] and mercury calibration aqueous solution. Differential pulse anodic st...

Ultrashort laser pulses and electromagnetic pulse generation in air and on dielectric surfaces

International Nuclear Information System (INIS)

Sprangle, P.; Penano, J.R.; Hafizi, B.; Kapetanakos, C.A.

2004-01-01

Intense, ultrashort laser pulses propagating in the atmosphere have been observed to emit sub-THz electromagnetic pulses (EMPS). The purpose of this paper is to analyze EMP generation from the interaction of ultrashort laser pulses with air and with dielectric surfaces and to determine the efficiency of conversion of laser energy to EMP energy. In our self-consistent model the laser pulse partially ionizes the medium, forms a plasma filament, and through the ponderomotive forces associated with the laser pulse, drives plasma currents which are the source of the EMP. The propagating laser pulse evolves under the influence of diffraction, Kerr focusing, plasma defocusing, and energy depletion due to electron collisions and ionization. Collective effects and recombination processes are also included in the model. The duration of the EMP in air, at a fixed point, is found to be a few hundred femtoseconds, i.e., on the order of the laser pulse duration plus the electron collision time. For steady state laser pulse propagation the flux of EMP energy is nonradiative and axially directed. Radiative EMP energy is present only for nonsteady state or transient laser pulse propagation. The analysis also considers the generation of EMP on the surface of a dielectric on which an ultrashort laser pulse is incident. For typical laser parameters, the power and energy conversion efficiency from laser radiation to EMP radiation in both air and from dielectric surfaces is found to be extremely small, -8 . Results of full-scale, self-consistent, numerical simulations of atmospheric and dielectric surface EMP generation are presented. A recent experiment on atmospheric EMP generation is also simulated

Catalytic polarographic currents of platinum metal complexes and their application to determination of trace concentrations of the elements

International Nuclear Information System (INIS)

Ezerskaya, N.A.; Kiseleva, I.N.

1984-01-01

Several types of catalytic electrode processes with the participation of platinum metal complexes and used for the determination of the element microconcentrations have been considered in the review. It is pointed out that to measure catalytic currents of hydrogen solutions nitroso compounds, which are prepared by heating chloride complexes of Ru(3) and (4) with NaNO 2 are used. The method is applicable for ruthenium determination in commercial nitric acid solutions. Ru determination in solution of ruthenium (4) dimeric chloride complex on graphite electrode, using catalytic currents of hydrogen, surpasses in sensitivity the determination of the element, using the method of inversion voltammetry. Certain other complexes of Ru and determination methods of ruthenium in them are considered. Hydrogen catalytic currents in the complexes solutions with organic ligands are the most perspective for analysis

Determination and identification of naturally occurring decay series using milli-second order pulse time interval analysis (TIA)

International Nuclear Information System (INIS)

Hashimoto, T.; Sanada, Y.; Uezu, Y.

2003-01-01

A delayed coincidence method, called a time interval analysis (TIA) method, has been successfully applied to selective determination of the correlated α-α decay events in millisecond order life-time. A main decay process applicable to TIA-treatment is 220 Rn → 216 Po(T 1/2 :145ms) → {Th-series}. The TIA is fundamentally based on the difference of time interval distribution between non-correlated decay events and other events such as background or random events when they were compiled the time interval data within a fixed time (for example, a tenth of concerned half lives). The sensitivity of the TIA-analysis due to correlated α-α decay events could be subsequently improved in respect of background elimination using the pulse shape discrimination technique (PSD with PERALS counter) to reject β/γ-pulses, purging of nitrogen gas into extra scintillator, and applying solvent extraction of Ra. (author)

Effects of Artea, a systemic fungicide, on the antioxidant system and ...

African Journals Online (AJOL)

Effects of Artea, a systemic fungicide, on the antioxidant system and the respiratory activity of durum wheat ( Triticum durum L .). ... African Journal of Biotechnology ... Root respiratory activity was also determined using a polarographic method ...

Transient Features in Nanosecond Pulsed Electric Fields Differentially Modulate Mitochondria and Viability

Science.gov (United States)

Beebe, Stephen J.; Chen, Yeong-Jer; Sain, Nova M.; Schoenbach, Karl H.; Xiao, Shu

2012-01-01

It is hypothesized that high frequency components of nanosecond pulsed electric fields (nsPEFs), determined by transient pulse features, are important for maximizing electric field interactions with intracellular structures. For monopolar square wave pulses, these transient features are determined by the rapid rise and fall of the pulsed electric fields. To determine effects on mitochondria membranes and plasma membranes, N1-S1 hepatocellular carcinoma cells were exposed to single 600 ns pulses with varying electric fields (0–80 kV/cm) and short (15 ns) or long (150 ns) rise and fall times. Plasma membrane effects were evaluated using Fluo-4 to determine calcium influx, the only measurable source of increases in intracellular calcium. Mitochondria membrane effects were evaluated using tetramethylrhodamine ethyl ester (TMRE) to determine mitochondria membrane potentials (ΔΨm). Single pulses with short rise and fall times caused electric field-dependent increases in calcium influx, dissipation of ΔΨm and cell death. Pulses with long rise and fall times exhibited electric field-dependent increases in calcium influx, but diminished effects on dissipation of ΔΨm and viability. Results indicate that high frequency components have significant differential impact on mitochondria membranes, which determines cell death, but lesser variances on plasma membranes, which allows calcium influxes, a primary determinant for dissipation of ΔΨm and cell death. PMID:23284682

Repeatability of pulse diagnosis in traditional Indian Ayurveda medicine

DEFF Research Database (Denmark)

Kurande, Vrinda; Waagepetersen, Rasmus; Toft, Egon

2012-01-01

Purpose In Ayurveda, pulse diagnosis is the unique diagnostic method that determines the proportion of diagnostic variables (vata, pitta and kapha); however, this is only justifiable if pulse diagnosis yields a consistent result. Though pulse diagnosis has a long historical use, still there is la...

Fieldable computer system for determining gamma-ray pulse-height distributions, flux spectra, and dose rates from Little Boy

International Nuclear Information System (INIS)

Moss, C.E.; Lucas, M.C.; Tisinger, E.W.; Hamm, M.E.

1984-01-01

Our system consists of a LeCroy 3500 data acquisition system with a built-in CAMAC crate and eight bismuth-germanate detectors 7.62 cm in diameter and 7.62 cm long. Gamma-ray pulse-height distributions are acquired simultaneously for up to eight positions. The system was very carefully calibrated and characterized from 0.1 to 8.3 MeV using gamma-ray spectra from a variety of radioactive sources. By fitting the pulse-height distributions from the sources with a function containing 17 parameters, we determined theoretical repsonse functions. We use these response functions to unfold the distributions to obtain flux spectra. A flux-to-dose-rate conversion curve based on the work of Dimbylow and Francis is then used to obtain dose rates. Direct use of measured spectra and flux-to-dose-rate curves to obtain dose rates avoids the errors that can arise from spectrum dependence in simple gamma-ray dosimeter instruments. We present some gamma-ray doses for the Little Boy assembly operated at low power. These results can be used to determine the exposures of the Hiroshima survivors and thus aid in the establishment of radation exposure limits for the nuclear industry

Determination of the wavelength dependence of the differential pathlength factor from near-infrared pulse signals

Science.gov (United States)

Kohl, Matthias; Nolte, Christian; Heekeren, Hauke R.; Horst, Susanne; Scholz, Udo; Obrig, Hellmuth; Villringer, Arno

1998-06-01

For the calculation of changes in oxyhaemoglobin, deoxyhaemoglobin and the redox state of cytochrome-c-oxidase from attenuation data via a modified Beer-Lambert equation the wavelength dependence of the differential pathlength factor (DPF) has to be taken into account. The DPF, i.e. the ratio of the mean optical pathlength and the physical light source-detector separation at each wavelength, determines the crosstalk between the different concentrations and is therefore essential for a sensitive detection of chromophore changes. Here a simple method is suggested to estimate the wavelength dependence of the DPF from pulse-induced attenuation changes measured on the head of adult humans. The essence is that the DPF is the ratio of the attenuation changes over absorption coefficient changes, and that the spectral form of the pulse correlated absorption coefficient change can be assumed to be proportional to the extinction coefficient of blood. Indicators for the validity of the DPF derived for wavelengths between 700 and 970 nm are the stability of the calculated haemoglobin and cytochrome signals with variations of the wavelength range included for their calculation and its overall agreement with the data available from the literature.

Pulse pile-up. I: Short pulses

International Nuclear Information System (INIS)

Wilkinson, D.H.

1990-07-01

The search for rare large pulses against an intense background of smaller ones involves consideration of pulse pile-up. Approximate methods are presented, based on ruin theory, by which the probability of such pile-up may be estimated for pulses of arbitrary form and of arbitrary pulse-height distribution. These methods are checked against cases for which exact solutions are available. The present paper is concerned chiefly with short pulses of finite total duration. (Author) (5 refs., 24 figs.)

Evaluation of dynamic range for LLNL streak cameras using high contrast pulsed and pulse podiatry on the Nova laser system

International Nuclear Information System (INIS)

Richards, J.B.; Weiland, T.L.; Prior, J.A.

1990-01-01

This paper reports on a standard LLNL streak camera that has been used to analyze high contrast pulses on the Nova laser facility. These pulses have a plateau at their leading edge (foot) with an amplitude which is approximately 1% of the maximum pulse height. Relying on other features of the pulses and on signal multiplexing, we were able to determine how accurately the foot amplitude was being represented by the camera. Results indicate that the useful single channel dynamic range of the instrument approaches 100:1

Determination of permittivity of pulses and cereals using metamaterial split ring resonator

Science.gov (United States)

Chakyar, Sreedevi P.; Sikha Simon, K.; Murali, Aathira; Shanto T., A.; Andrews, Jolly; Joseph V., P.

2017-06-01

Relative permittivity of wide variety of pulses and cereals are precisely determined with the help of metamaterial Split Ring Resonator (SRR) operating at microwave frequencies using a simple extraction procedure. The unknown permittivity of food samples in powder form are evaluated from a calibration curve drawn between the dielectric constant of some standard samples and LC resonant frequency of SRR test probe with the sample placed over it. The experimental setup consists of SRR test probe arranged between transmitting and receiving probes connected to a vector network analyzer. Unknown relative permittivity of the sample is obtained by placing it on the SRR surface and is evaluated from the calibration curve which is found to be in good agreement with the expected standard values. The possible applications of this sensitive and easy technique are analyzed in the field of food preservation, quality checking, adulteration etc.

Characterization of the pulse plasma source

International Nuclear Information System (INIS)

Milosavljevic, V; Karkari, S K; Ellingboe, A R

2007-01-01

Characterization of the pulse plasma source through the determination of the local thermodynamic equilibrium (LTE) threshold is described. The maximum electron density measured at the peak in discharge current is determined by the width of the He II Paschen alpha spectral line, and the electron temperature is determined from the ratios of the relative intensities of spectral lines emitted from successive ionized stages of atoms. The electron density and temperature maximum values are measured to be 1.3 x 10 17 cm -3 and 19 000 K, respectively. These are typical characteristics for low-pressure, pulsed plasma sources for input energy of 15.8 J at 130 Pa pressure in helium-argon mixture. The use of LTE-based analysis of the emission spectra is justified by measurement of the local plasma electron density at four positions in the discharge tube using a floating hairpin resonance probe. The hairpin resonance probe data are collected during the creation and decay phases of the pulse. From the spatio-temporal profile of the plasma density a 60 μs time-window during which LTE exists throughout the entire plasma source is determined

The Determination of Pesticidal and Non-Pesticidal Organotin Compounds by in situ Ethylation and Capillary Gas Chromatography with Pulsed Flame Photometric Detection

Science.gov (United States)

The concurrent determination of pesticidal and non-pesticidal organotin compounds in several water matrices, using a simultaneous in situ ethylation and liquid-liquid extraction followed by splitless injection mode capillary gas chromatography with pulsed flame photometric detect...

Pulsed neutron determination of anisotropic diffusion constants in multi-layered slabs

International Nuclear Information System (INIS)

Sri Ram, K.

1978-01-01

Anisotropic neutron diffusion parameters for graphite and plexiglas slab assemblies were calculated using one-dimensional discrete ordinates code ANISN, and also Case's eigenfunction expansion technique as suggested by Leonard. These calculated values were checked with the pulsed neutron experimental results as well as simple diffusion theory calculations of Spinrad. Relatively little experimental work has been done with heterogeneous assemblies which do not contain voids. The present comparison shows that the experimental results agree well with transport theory calculations. It appears from the results and inter-comparison of this work in simple geometries, that the pulsed neutron method can yield accurate experimental anisotropic diffusion constants, and can therefore be applied to more complicated geometries which may be difficult to calculate. (author)

Polarography of uranium(VI)-salicylic acid system

International Nuclear Information System (INIS)

Salah, El-Maraghy B.

1980-01-01

Uranium(VI)-salicylic acid system has been studied polarographically in perchloric acid medium. Varying concentrations of HClO 4 and salicylic acid have been used. The nature of the polarographic waves is irreversible. (author)

Polarography of uranium(VI)-salicylic acid system

Energy Technology Data Exchange (ETDEWEB)

Salah, E M.B. [Ain Shams Univ., Cairo (Egypt). Faculty of Education

1980-08-01

Uranium(VI)-salicylic acid system has been studied polarographically in perchloric acid medium. Varying concentrations of HClO/sub 4/ and salicylic acid have been used. The nature of the polarographic waves is irreversible.

Effectiveness of Pulse Oximetry Versus Doppler for Tourniquet Monitoring.

Science.gov (United States)

Wall, Piper L; Buising, Charisse M; Grulke, Lisa; Troester, Alexander; Bianchina, Nicholas; White, Shannon; Freymark, Rosemarie; Hassan, Ali; Hopkins, James W; Renner, Catherine Hackett; Sahr, Sheryl M

Pulse oximeters are common and include arterial pulse detection as part of their methodology. The authors investigated the possible usefulness of pulse oximeters for monitoring extremity tourniquet arterial occlusion. Tactical Ratcheting Medical Tourniquets were tightened to the least Doppler-determined occluding pressure at mid-thigh or mid-arm locations on one limb at a time on all four limbs of 15 volunteers. A randomized block design was used to determine the placement locations of three pulse oximeter sensors on the relevant digits. The times and pressures of pulsatile signal absences and returns were recorded for 200 seconds, with the tourniquet being tightened only when the Doppler ultrasound and all three pulse oximeters had pulsatile signals present (pulsatile waveform traces for the pulse oximeters). From the first Doppler signal absence to tourniquet release, toe-located pulse oximeters missed Doppler signal presence 41% to 50% of the times (discrete 1-second intervals) and missed 39% to 49% of the pressure points (discrete 1mmHg intervals); fingerlocated pulse oximeters had miss rates of 11% to 15% of the times and 13% to 19% of the pressure points. On toes, the pulse oximeter ranges of sensitivity and specificity for Doppler pulse detection were 71% to 90% and 44% to 51%, and on fingers, the respective ranges were 65% to 77% and 78% to 83%. Use of a pulse oximeter to monitor limb tourniquet effectiveness will result in some instances of an undetected weak arterial pulse being present. If a pulse oximeter waveform is obtained from a location distal to a tourniquet, the tourniquet should be tightened. If a pulsatile waveform is not detected, vigilance should be maintained. 2017.

Attosecond pulse generation in noble gases in the presence of extreme high intensity THz pulses

International Nuclear Information System (INIS)

Balogh, E.; Varju, K.

2010-01-01

Complete text of publication follows. The shortest - attosecond - light pulses available today are produced by high harmonic generation (HHG) of near-infrared (NIR) laser pulses in noble gas jets, providing a broad spectral plateau of XUV radiation ending in a cutoff. The minimum pulse duration is determined by the achievable bandwidth (i.e. the position of the cutoff), and the chirp of the produced pulses. The extension of the cutoff by increasing the laser intensity is limited by the depletion and phase matching problems of the medium. An alternative method demonstrated to produce higher harmonic orders is by using longer pump pulse wavelength, with the disadvantage of decreased efficiency. Recently it was shown that application of a quasi-DC high strength electric field results in an increase of more than a factor of two in the order of efficiently generated high harmonics. However, the possibility to implement the method proposed in [3] of using a CO 2 laser to create a quasi-DC field for assisting HHG of the NIR laser is questionable, because it's technically very challenging to synchronize pulses from different laser sources. Alternatively, synchronous production of THz pulses with the NIR laser pulse offers a more promising route. The first numerical test of this idea has been reported in [4]. In this contribution we further investigate the method for realistic THz field strengths and short driving pulses, exploring the effect of longer pump laser wavelength on the process. We assume the presence of high intensity THz pulses for supplying the high-strength quasi-DC electric field. The spectrum as well as the chirp of the produced radiation is calculated. We use the non-adiabatic saddle point method to determine the generated radiation described in [6]. We simulate harmonic generation in noble gas atoms, with few cycle NIR pulses of peak intensity at and above 2 x 10 14 W/cm 2 (388 MV/cm) and wavelengths 800 nm and 1560 nm. The THz field strength is varied

Modeling of Trichel pulses in negative corona

International Nuclear Information System (INIS)

Napartovich, A.P.; Akishev, Yu. S.; Deryugin, A.A.; Kochetov, I.V.; Pan'kin, M.V.; Trushkin, N.I.

1998-01-01

Results are reported of detailed numerical studies of Trichel pulse formation for dry air in short-gap coronas. Continuity equations for electrons, positive and negative ions, and the Poisson equation averaged over the current cross section were solved numerically with appropriate boundary conditions. The results of numerical simulation make it possible to analyze in detail the trailing edge of the Trichel pulse and the inter-pulse pause determining the period between pulses. In particular, the variations of the total number of negative ions in the corona spacing occurring under typical conditions of a pulsating corona, proved to be quite insignificant. A comparison with experiments demonstrated a reasonable agreement both for the shape of the pulse and for the average characteristics of the negative corona. (J.U.)

System Performance Testing of the Pulse-Echo Ultrasonic Instrument for Critical Velocity Determination during Hanford Tank Waste Transfer Operations - 13584

Energy Technology Data Exchange (ETDEWEB)

Denslow, Kayte M.; Bontha, Jagannadha R.; Adkins, Harold E.; Jenks, Jeromy W.J.; Hopkins, Derek F. [Pacific Northwest National Laboratory, Richland, Washington 99354 (United States); Thien, Michael G.; Kelly, Steven E.; Wooley, Theodore A. [Washington River Protection Solutions, Richland, Washington 99354 (United States)

2013-07-01

The delivery of Hanford double-shell tank waste to the Hanford Tank Waste Treatment and Immobilization Plant (WTP) is governed by specific Waste Acceptance Criteria that are identified in ICD 19 - Interface Control Document for Waste Feed. Waste must be certified as acceptable before it can be delivered to the WTP. The fluid transfer velocity at which solid particulate deposition occurs in waste slurry transport piping (critical velocity) is a key waste acceptance parameter that must be accurately characterized to determine if the waste is acceptable for transfer to the WTP. Washington River Protection Solutions and the Pacific Northwest National Laboratory have been evaluating the ultrasonic PulseEcho instrument since 2010 for its ability to detect particle settling and determine critical velocity in a horizontal slurry transport pipeline for slurries containing particles with a mean particle diameter of =14 micrometers (μm). In 2012 the PulseEcho instrument was further evaluated under WRPS' System Performance test campaign to identify critical velocities for slurries that are expected to be encountered during Hanford tank waste retrieval operations or bounding for tank waste feed. This three-year evaluation has demonstrated the ability of the ultrasonic PulseEcho instrument to detect the onset of critical velocity for a broad range of physical and rheological slurry properties that are likely encountered during the waste feed transfer operations between the Hanford tank farms and the WTP. (authors)

Thermal models of pulse electrochemical machining

International Nuclear Information System (INIS)

Kozak, J.

2004-01-01

Pulse electrochemical machining (PECM) provides an economical and effective method for machining high strength, heat-resistant materials into complex shapes such as turbine blades, die, molds and micro cavities. Pulse Electrochemical Machining involves the application of a voltage pulse at high current density in the anodic dissolution process. Small interelectrode gap, low electrolyte flow rate, gap state recovery during the pulse off-times lead to improved machining accuracy and surface finish when compared with ECM using continuous current. This paper presents a mathematical model for PECM and employs this model in a computer simulation of the PECM process for determination of the thermal limitation and energy consumption in PECM. The experimental results and discussion of the characteristics PECM are presented. (authors)

Realtime aspects of pulse-to-pulse modulation

International Nuclear Information System (INIS)

Steiner, R.; Riedel, C.; Roesch, W.

1992-01-01

The pulse-to-pulse modulation of the SIS-ESR control system is described. Fast response to operator interaction and to changes in process conditions is emphasized as well as the essential part played by the timing system in pulse-to-pulse modulation. (author)

Ultrashort X-ray pulse science

Energy Technology Data Exchange (ETDEWEB)

Chin, Alan Hap [Univ. of California, Berkeley, CA (US). Dept. of Physics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

1998-05-01

A variety of phenomena involves atomic motion on the femtosecond time-scale. These phenomena have been studied using ultrashort optical pulses, which indirectly probe atomic positions through changes in optical properties. Because x-rays can more directly probe atomic positions, ultrashort x-ray pulses are better suited for the study of ultrafast structural dynamics. One approach towards generating ultrashort x-ray pulses is by 90° Thomson scattering between terawatt laser pulses and relativistic electrons. Using this technique, the author generated ~ 300 fs, 30 keV (0.4 Å) x-ray pulses. These x-ray pulses are absolutely synchronized with ultrashort laser pulses, allowing femtosecond optical pump/x-ray probe experiments to be performed. Using the right-angle Thomson scattering x-ray source, the author performed time-resolved x-ray diffraction studies of laser-perturbated InSb. These experiments revealed a delayed onset of lattice expansion. This delay is due to the energy relaxation from a dense electron-hole plasma to the lattice. The dense electron-hole plasma first undergoes Auger recombination, which reduces the carrier concentration while maintaining energy content. Longitudinal-optic (LO) phonon emission then couples energy to the lattice. LO phonon decay into acoustic phonons, and acoustic phonon propagation then causes the growth of a thermally expanded layer. Source characterization is instrumental in utilizing ultrashort x-ray pulses in time-resolved x-ray spectroscopies. By measurement of the electron beam diameter at the generation point, the pulse duration of the Thomson scattered x-rays is determined. Analysis of the Thomson scattered x-ray beam properties also provides a novel means of electron bunch characterization. Although the pulse duration is inferred for the Thomson scattering x-ray source, direct measurement is required for other x-ray pulse sources. A method based on the laser-assisted photoelectric effect (LAPE) has been demonstrated as a

Ultrashort X-ray pulse science

International Nuclear Information System (INIS)

Chin, A.H.; Lawrence Berkeley National Lab., CA

1998-01-01

A variety of phenomena involves atomic motion on the femtosecond time-scale. These phenomena have been studied using ultrashort optical pulses, which indirectly probe atomic positions through changes in optical properties. Because x-rays can more directly probe atomic positions, ultrashort x-ray pulses are better suited for the study of ultrafast structural dynamics. One approach towards generating ultrashort x-ray pulses is by 90 o Thomson scattering between terawatt laser pulses and relativistic electrons. Using this technique, the author generated ∼ 300 fs, 30 keV (0.4 (angstrom)) x-ray pulses. These x-ray pulses are absolutely synchronized with ultrashort laser pulses, allowing femtosecond optical pump/x-ray probe experiments to be performed. Using the right-angle Thomson scattering x-ray source, the author performed time-resolved x-ray diffraction studies of laser-perturbated InSb. These experiments revealed a delayed onset of lattice expansion. This delay is due to the energy relaxation from a dense electron-hole plasma to the lattice. The dense electron-hole plasma first undergoes Auger recombination, which reduces the carrier concentration while maintaining energy content. Longitudinal-optic (LO) phonon emission then couples energy to the lattice. LO phonon decay into acoustic phonons, and acoustic phonon propagation then causes the growth of a thermally expanded layer. Source characterization is instrumental in utilizing ultrashort x-ray pulses in time-resolved x-ray spectroscopies. By measurement of the electron beam diameter at the generation point, the pulse duration of the Thomson scattered x-rays is determined. Analysis of the Thomson scattered x-ray beam properties also provides a novel means of electron bunch characterization. Although the pulse duration is inferred for the Thomson scattering x-ray source, direct measurement is required for other x-ray pulse sources. A method based on the laser-assisted photoelectric effect (LAPE) has been

Determination of adiabatic temperature change in MnFe(P,Ge) compounds with pulse-field method

International Nuclear Information System (INIS)

Trung, N T; Tegus, O; Cam Thanh, D T; Buschow, K H J; Brueck, E; Klaasse, J C P

2010-01-01

Fast magnetic measurements performed by means of a 20 T pulse-field magnet provide a good approach for directly monitoring the magnetocaloric effect of the MnFe(P,Ge) compounds. Based on the comparison of magnetization curves obtained either in an adiabatic or isothermal process, we propose that the method introduced by Levitin et al is applicable to determine the adiabatic temperature change for an equivalent field change in first-order magnetic transition materials. More strikingly, experimental results confirm that the first-order nature of the transition in MnFe(P,Ge) alloys is not a limiting factor to the operation frequency of a magnetic refrigerator.

Pulsed rf excited spectrometer having improved pulse width control

International Nuclear Information System (INIS)

1977-01-01

RF excitation for a spectrometer is obtained by pulse width modulating an RF carrier to produce the desired broadband RF exciting spectrum. The RF excitation includes a train of composite RF pulses, each composite pulse having a primary pulse portion of a first RF phase and a second pulse portion of a second RF phase opposite that of the first. In this manner, the finite rise and fall times of the primary pulse portion are compensated for by the corresponding rise and fall times of the secondary pulse portion. The primary pulse portion is lengthened by an amount equal to the secondary pulse portion so that the secondary pulse portion cancels the added primary pulse portion. In a spectrometer, the compensating second pulse component removes certain undesired side bands of the RF excitation caused by the finite rise and fall times of the applied RF pulses. The compensating second pulse component removes certain undesired side bands associated with each of the resonant lines of the excited resonance spectrum of the sample under analysis, particularly for wide band RF excitation

Determination of Silver(I by Differential Pulse Voltammetry Using a Glassy Carbon Electrode Modified with Synthesized N-(2-Aminoethyl-4,4'-Bipyridine

Directory of Open Access Journals (Sweden)

Gabriel Lucian Radu

2010-12-01

Full Text Available A new modified glassy carbon electrode (GCE based on a synthesized N-(2-aminoethyl-4,4'-bipyridine (ABP was developed for the determination of Ag(I by differential pulse voltammetry (DPV. ABP was covalently immobilized on GC electrodes surface using 4-nitrobenzendiazonium (4-NBD and glutaraldehyde (GA. The Ag(I ions were preconcentrated by chemical interaction with bipyridine under a negative potential (−0.6 V; then the reduced ions were oxidized by differential pulse voltammetry and a peak was observed at 0.34 V. The calibration curve was linear in the concentration range from 0.05 μM to 1 μM Ag(I with a detection limit of 0.025 μM and RSD = 3.6%, for 0.4 μM Ag(I. The presence of several common ions in more than 125-fold excess had no effect on the determination of Ag(I. The developed sensor was applied to the determination of Ag(I in water samples using a standard addition method.

Method of analysis to determine subcritical reactivity from the pulsed neutron experiment

International Nuclear Information System (INIS)

Parks, P.B.

1975-06-01

The published methods for the deduction of reactivity from pulsed neutron experiments on subcritical reactors are reviewed. Each method is categorized as inherently yielding a result that is either spatially independent or spatially dependent. The spatially independent results are formally identical with the static reactivity; the result does not depend, in principle, on the location of either the pulsed neutron source or the neutron detector during data collection. The spatially dependent results only approximate the static reactivity; the results are affected, in varying degrees, by the locations of the source and detector. Among the techniques yielding spatially independent results are the Space-Time method of Parks and Stewart and the Inhour method of Preskitt et al. Spatially dependent results are obtained with the Sjoestrand, Gozani, and Garelis-Russell methods which are examined with and without the kinetic distortion corrections given by Becker and Quisenberry. Intercomparisons of all methods are made with reference to pulsed neutron experiments on both unreflected and reflected reactors. Recommendations are made concerning the best choice of method under the various experimental conditions that are likely to be encountered. 14 references. (U.S.)

Pulse amplitude and frequency effects in a pulsed packed column

Energy Technology Data Exchange (ETDEWEB)

Russell, S H

1954-04-15

A study has been made of the effect on the efficiency and capacity of applying pulses of varying amplitude and frequency to a packed column. In the efficiency studies, the maximum efficiency was obtained with a pulse having an amplitude of 3/8'' and a frequency of 140 cycles per minute. Under these conditions, the column was about five times as efficient as a simple packed column. Two general types of results were obtained in the capacity studies. Under certain conditions, the capacity increased over that of a simple packed column, but under others, it decreased. Some of the factors causing this were investigated but the fundamental reasons were not determined due to a lack of personnel for the necessary experiments. (author)

Pulse amplitude and frequency effects in a pulsed packed column

International Nuclear Information System (INIS)

Russell, S.H.

1954-04-01

A study has been made of the effect on the efficiency and capacity of applying pulses of varying amplitude and frequency to a packed column. In the efficiency studies, the maximum efficiency was obtained with a pulse having an amplitude of 3/8'' and a frequency of 140 cycles per minute. Under these conditions, the column was about five times as efficient as a simple packed column. Two general types of results were obtained in the capacity studies. Under certain conditions, the capacity increased over that of a simple packed column, but under others, it decreased. Some of the factors causing this were investigated but the fundamental reasons were not determined due to a lack of personnel for the necessary experiments. (author)

Bipolar pulse generator for intense pulsed ion beam accelerator

International Nuclear Information System (INIS)

Ito, H.; Igawa, K.; Kitamura, I.; Masugata, K.

2007-01-01

A new type of pulsed ion beam accelerator named ''bipolar pulse accelerator'' (BPA) has been proposed in order to improve the purity of intense pulsed ion beams. To confirm the principle of the BPA, we developed a bipolar pulse generator for the bipolar pulse experiment, which consists of a Marx generator and a pulse forming line (PFL) with a rail gap switch on its end. In this article, we report the first experimental result of the bipolar pulse and evaluate the electrical characteristics of the bipolar pulse generator. When the bipolar pulse generator was operated at 70% of the full charge condition of the PFL, the bipolar pulse with the first (-138 kV, 72 ns) and the second pulse (+130 kV, 70 ns) was successfully obtained. The evaluation of the electrical characteristics indicates that the developed generator can produce the bipolar pulse with fast rise time and sharp reversing time

Method for measuring the stochastic properties of corona and partial-discharge pulses

International Nuclear Information System (INIS)

Van Brunt, R.J.; Kulkarni, S.V.

1989-01-01

A new method is described for measuring the stochastic behavior of corona and partial-discharge pulses which utilizes a pulse selection and sorting circuit in conjunction with a computer-controlled multichannel analyzer to directly measure various conditional and unconditional pulse-height and pulse-time-separation distributions. From these measured distributions it is possible to determine the degree of correlation between successive discharge pulses. Examples are given of results obtained from measurements on negative, point-to-plane (Trichel-type) corona pulses in a N 2 /O 2 gas mixture which clearly demonstrate that the phenomenon is inherently stochastic in the sense that development of a discharge pulse is significantly affected by the amplitude of and time separation from the preceding pulse. It is found, for example, that corona discharge pulse amplitude and time separation from an earlier pulse are not independent random variables. Discussions are given about the limitations of the method, sources of error, and data analysis procedures required to determine self-consistency of the various measured distributions

Third-harmonic generation in isotropic media by focused pulses

International Nuclear Information System (INIS)

Tasgal, Richard S.; Band, Y.B.

2004-01-01

For focused pulses of light in isotropic nonlinear media, third-harmonic generation can be strongly affected by group-velocity mismatch between the fundamental and third-harmonic. There is a characteristic time determined by the group-velocity mismatch and the Rayleigh range of the focused pulse. The dynamics depend on two dimensionless quantities, namely the ratio of the characteristic time to the pulse duration and the phase-velocity mismatch times the Rayleigh range. Pulses shorter than the characteristic time have physics described by simple analytic formulas. Pulses near the characteristic time have an intermediate behavior given by an explicit but more complicated formula. Pulses longer than the characteristic time tend to the continuous-wave case

A novel and practical approach for determination of the acoustic nonlinearity parameter using a pulse-echo method

Science.gov (United States)

Jeong, Hyunjo; Zhang, Shuzeng; Barnard, Dan; Li, Xiongbing

2016-02-01

Measurements of the acoustic nonlinearity parameter β are frequently made for early detection of damage in various materials. The practical implementation of the measurement technique has been limited to the through-transmission setup for determining the nonlinearity parameter of the second harmonic wave. In this work, a feasibility study is performed to assess the possibility of using pulse-echo methods in determining the nonlinearity parameter β of solids with a stress-free boundary. The multi-Gaussian beam model is developed based on the quasilinear theory of the KZK equation. Simulation results and discussion are presented for the reflected beam fields of the fundamental and second harmonic waves, the uncorrected β behavior and the properties of total correction that incorporate reflection, attenuation and diffraction effects.

Continued Evaluation of the Pulse-Echo Ultrasonic Instrument for Critical Velocity Determination during Hanford Tank Waste Transfer Operations - 12518

Energy Technology Data Exchange (ETDEWEB)

Denslow, Kayte M.; Bontha, Jagannadha R.; Adkins, Harold E.; Jenks, Jeromy W.J.; Burns, Carolyn A.; Schonewill, Philip P.; Hopkins, Derek F. [Pacific Northwest National Laboratory, Richland, Washington 99354 (United States); Thien, Michael G.; Wooley, Theodore A. [Washington River Protection Solutions, Richland, Washington 99354 (United States)

2012-07-01

The delivery of Hanford double-shell tank waste to the Hanford Tank Waste Treatment and Immobilization Plant (WTP) will be governed by specific Waste Acceptance Criteria that are identified in ICD 19 - Interface Control Document for Waste Feed. Waste must be certified as acceptable before it can be delivered to the WTP. The fluid transfer velocity at which solid particulate deposition occurs in waste slurry transport piping (critical velocity) is a key waste parameter that must be accurately characterized to determine if the waste is acceptable for transfer to the WTP. In 2010 Washington River Protection Solutions and the Pacific Northwest National Laboratory began evaluating the ultrasonic PulseEcho instrument to accurately identify critical velocities in a horizontal slurry transport pipeline for slurries containing particles with a mean particle diameter of >50 micrometers. In 2011 the PulseEcho instrument was further evaluated to identify critical velocities for slurries containing fast-settling, high-density particles with a mean particle diameter of <15 micrometers. This two-year evaluation has demonstrated the ability of the ultrasonic PulseEcho instrument to detect the onset of critical velocity for a broad range of physical and rheological slurry properties that are likely encountered during the waste feed transfer operations between the Hanford tank farms and the WTP. (authors)

Evaluation of dynamic range for LLNL streak cameras using high contrast pulses and pulse podiatry'' on the Nova laser system

Energy Technology Data Exchange (ETDEWEB)

Richards, J.B.; Weiland, T.L.; Prior, J.A.

1990-07-01

A standard LLNL streak camera has been used to analyze high contrast pulses on the Nova laser facility. These pulses have a plateau at their leading edge (foot) with an amplitude which is approximately 1% of the maximum pulse height. Relying on other features of the pulses and on signal multiplexing, we were able to determine how accurately the foot amplitude was being represented by the camera. Results indicate that the useful single channel dynamic range of the instrument approaches 100:1. 1 ref., 4 figs., 1 tab.

Pulse on pulse: modulation and signification in Rafael Lozano-Hemmer's Pulse Room

Directory of Open Access Journals (Sweden)

Merete Carlson

2012-06-01

Full Text Available This article investigates the relation between signifying processes and non-signifying material dynamism in the installation Pulse Room (2006 by Mexican Canadian artist Rafael Lozano-Hemmer. In Pulse Room the sense of pulse is ambiguous. Biorhythms are transmitted from the pulsing energy of the visitor's beating heart to the flashing of a fragile light bulb, thereby transforming each light bulb into a register of individual life. But at the same time the flashing light bulbs together produce a chaotically flickering light environment composed by various layers of repetitive rhythms, a vibrant and pulsating “room”. Hence, the visitor in Pulse Room is invited into a complex scenario that continuously oscillates between various aspects of signification (the light bulbs representing individual lives; the pulse itself as the symbolic “rhythm of life” and instants of pure material processuality (flickering light bulbs; polyrhythmic layers. Taking our point of departure in a discussion of Gilles Deleuze's concepts of modulation and signaletic material in relation to electronic media, we examine how the complex orchestration of pulsation between signification and material modulation produces a multilayered sense of time and space that is central to the sensory experience of Pulse Room as a whole. Pulse Room is, at the very same time, a relational subject–object intimacy and an all-encompassing immersive environment modulating continuously in real space-time.

Effect of laser pulse parameters on the size and fluorescence of nanodiamonds formed upon pulsed-laser irradiation

International Nuclear Information System (INIS)

Bai, Peikang; Hu, Shengliang; Zhang, Taiping; Sun, Jing; Cao, Shirui

2010-01-01

The size of nanodiamonds formed upon laser irradiation could be easily controlled over simply adjusting laser pulse parameters. The stable size and structure of nanodiamonds were mostly determined by laser power density and pulse width. Both large nanodiamonds with multiply twinning structure (MTS) and small nanodiamonds with single crystalline structure (SCS) emitted strong visible light after surface passivation, and their fluorescence quantum yield (QY) was 4.6% and 7.1%, respectively.

Effect of laser pulse parameters on the size and fluorescence of nanodiamonds formed upon pulsed-laser irradiation

Energy Technology Data Exchange (ETDEWEB)

Bai, Peikang [School of Materials Science and Engineering, North University of China, Taiyuan 030051 (China); Hu, Shengliang, E-mail: hsliang@yeah.net [Key Laboratory of Instrumentation Science and Dynamic Measurement (North University of China), Ministry of Education, National Key Laboratory Science and Technology on Electronic Test and Measurement, Taiyuan 030051 (China); School of Materials Science and Engineering, North University of China, Taiyuan 030051 (China); Zhang, Taiping; Sun, Jing [School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Cao, Shirui [School of Materials Science and Engineering, North University of China, Taiyuan 030051 (China)

2010-07-15

The size of nanodiamonds formed upon laser irradiation could be easily controlled over simply adjusting laser pulse parameters. The stable size and structure of nanodiamonds were mostly determined by laser power density and pulse width. Both large nanodiamonds with multiply twinning structure (MTS) and small nanodiamonds with single crystalline structure (SCS) emitted strong visible light after surface passivation, and their fluorescence quantum yield (QY) was 4.6% and 7.1%, respectively.

Pulsed-DC selfsputtering of copper

International Nuclear Information System (INIS)

Wiatrowski, A; Posadowski, W M; Radzimski, Z J

2008-01-01

At standard magnetron sputtering conditions (argon pressure ∼0.5 Pa) inert gas particles are often entrapped in the formed films. Inert gas contamination can be eliminated by using the self-sustained magnetron sputtering process because it is done in the absence of the inert gas atmosphere. The self-sustained sputtering (SSS) gives also a unique condition during the transport of sputtered particles to the substrate. It is especially useful for filling high aspect ratio submicron scale structures for microelectronics. So far it has been shown that the self-sputtering process can be sustained in the DC operation mode (DC-SSS) only. The main disadvantage of DC-SSS process is instability related to possible arc formation. Usage of pulsed sputtering, similarly to reactive pulsed magnetron sputtering, could eliminate this problem. In this paper results of pulsed-DC self-sustained magnetron sputtering (pulsed DC-SSS) of copper are presented for the first time. The planar magnetron equipped with a 50 mm in diameter and 6 mm thick copper target was powered by DC-power supply modulated by power switch. The maximum target power was about 11 kW (∼550W/cm 2 ). The magnetron operation was investigated as a function of pulsing frequency (20-100 kHz) and duty factor (50-90%). The discharge extinction pressure was determined for these conditions. The plasma emission spectra (400-410nm range) and deposition rates were observed for both DC and pulsed DC sustained self-sputtering processes. The presented results illustrate that stable pulsed DC-SSS process can be obtained at pulsing frequency in the range of 60-100 kHz and duty factor of 70-90%

Pulsed-DC selfsputtering of copper

Science.gov (United States)

Wiatrowski, A.; Posadowski, W. M.; Radzimski, Z. J.

2008-03-01

At standard magnetron sputtering conditions (argon pressure ~0.5 Pa) inert gas particles are often entrapped in the formed films. Inert gas contamination can be eliminated by using the self-sustained magnetron sputtering process because it is done in the absence of the inert gas atmosphere. The self-sustained sputtering (SSS) gives also a unique condition during the transport of sputtered particles to the substrate. It is especially useful for filling high aspect ratio submicron scale structures for microelectronics. So far it has been shown that the self-sputtering process can be sustained in the DC operation mode (DC-SSS) only. The main disadvantage of DC-SSS process is instability related to possible arc formation. Usage of pulsed sputtering, similarly to reactive pulsed magnetron sputtering, could eliminate this problem. In this paper results of pulsed-DC self-sustained magnetron sputtering (pulsed DC-SSS) of copper are presented for the first time. The planar magnetron equipped with a 50 mm in diameter and 6 mm thick copper target was powered by DC-power supply modulated by power switch. The maximum target power was about 11 kW (~550W/cm2). The magnetron operation was investigated as a function of pulsing frequency (20-100 kHz) and duty factor (50-90%). The discharge extinction pressure was determined for these conditions. The plasma emission spectra (400-410nm range) and deposition rates were observed for both DC and pulsed DC sustained self-sputtering processes. The presented results illustrate that stable pulsed DC-SSS process can be obtained at pulsing frequency in the range of 60-100 kHz and duty factor of 70-90%.

Simultaneous multi-element analysis of some edible pulses using neutron activation analysis

International Nuclear Information System (INIS)

El-Sweify, F.H.; Metwally, E.; Abdel-Khalik, H.

2007-01-01

This paper comprises the application of instrumental neutron activation analysis (INAA) for multi-element determination in some edible pulse samples. These edible pulses are usually daily used in the Egyptian kitchen. These were: anise, cumin, coriander, caraway, black cumin, white kidney bean, lupine, lentil, chickpea, broad bean, peanut, almond, and fenugreek. The pulses have been analyzed as dehulled pulses, in the case of legume and oil pulses with simultaneous analysis of their respective skins. The determined elements were: Ce, Co, Cr, Cs, Eu, Fe, Hf, Rb, Sb, Sc, Sr, Th and Zn. The element content in the dehulled pulses and their respective skins has been compared. Some elements were major or minor elements where others were trace elements. Standard reference materials were used to assure quality control, accuracy and precision of the technique. (author)

System for evaluation of the true average input-pulse rate

International Nuclear Information System (INIS)

Eichenlaub, D.P.; Garrett, P.

1977-01-01

The description is given of a digital radiation monitoring system making use of current digital circuit and microprocessor for rapidly processing the pulse data coming from remote radiation controllers. This system analyses the pulse rates in order to determine if a new datum is statistically the same as that previously received. Hence it determines the best possible average time for itself. So long as the true average pulse rate stays constant, the time required to establish an average can increase until the statistical error is under the desired level, i.e. 1%. When the digital processing of the pulse data indicates a change in the true average pulse rate, the time required to establish an average can be reduced so as to improve the response time of the system at the statistical error. This concept includes a fixed compromise between the statistical error and the response time [fr

Determination of alpha-naphthol by an oscillating chemical reaction using the analyte pulse perturbation technique

International Nuclear Information System (INIS)

Yang Wu; Sun Kanjun; Lv Weilian; Bo Lili; He Xiaoyan; Suo Nan; Gao Jinzhang

2005-01-01

An analytical method for the determination of alpha-naphthol (α-NP) is proposed by the sequential perturbation caused by different amounts of alpha-naphthol on the oscillating chemical system involving the Cu(II)-catalyzed oscillating reaction between hydrogen peroxide and sodium thiocyanate in an alkaline medium with the aid of continuous-flow stirred tank reactor (CSTR). The method relies on the linear relationship between the changes in the oscillation amplitude of the chemical system and the concentration of alpha-naphthol. The use of the analyte pulse perturbation technique permits sequential determinations in the same oscillating system owing to the expeditiousness with which the steady state is regained after each perturbation. The calibration curve obeys a linear equation very well when the concentration of alpha-naphthol is over the range 0.034-530 umol/L (r = 0.9991). Influences of temperature, injection points, flow rate and reaction variables on the oscillating system are investigated in detail and the possible mechanism of action of alpha-naphthol to the chemical oscillating system is also discussed. The method has been successfully used for the determination of α-naphthol in carbaryl hydrolysates

Polarographic validation of chemical speciation models

International Nuclear Information System (INIS)

Duffield, J.R.; Jarratt, J.A.

2001-01-01

It is well established that the chemical speciation of an element in a given matrix, or system of matrices, is of fundamental importance in controlling the transport behaviour of the element. Therefore, to accurately understand and predict the transport of elements and compounds in the environment it is a requirement that both the identities and concentrations of trace element physico-chemical forms can be ascertained. These twin requirements present the analytical scientist with considerable challenges given the labile equilibria, the range of time scales (from nanoseconds to years) and the range of concentrations (ultra-trace to macro) that may be involved. As a result of this analytical variability, chemical equilibrium modelling has become recognised as an important predictive tool in chemical speciation analysis. However, this technique requires firm underpinning by the use of complementary experimental techniques for the validation of the predictions made. The work reported here has been undertaken with the primary aim of investigating possible methodologies that can be used for the validation of chemical speciation models. However, in approaching this aim, direct chemical speciation analyses have been made in their own right. Results will be reported and analysed for the iron(II)/iron(III)-citrate proton system (pH 2 to 10; total [Fe] = 3 mmol dm -3 ; total [citrate 3- ] 10 mmol dm -3 ) in which equilibrium constants have been determined using glass electrode potentiometry, speciation is predicted using the PHREEQE computer code, and validation of predictions is achieved by determination of iron complexation and redox state with associated concentrations. (authors)

Energy and dose characteristics of ion bombardment during pulsed laser deposition of thin films under pulsed electric field

International Nuclear Information System (INIS)

Fominski, V.Yu.; Nevolin, V.N.; Smurov, I.

2004-01-01

Experiments on pulsed laser deposition of Fe films on Si substrates were performed with the aim to analyze the role of factors determining the formation of an energy spectrum and a dose of ions bombarding the film in strong pulsed electric fields. The amplitude of the high-voltage pulse (-40 kV) applied to the substrate and the laser fluence at the Fe target were fixed during the deposition. Owing to the high laser fluence (8 J/cm 2 ) at a relatively low power (20 mJ), the ionization of the laser plume was high, but the Fe vapor pressure near the substrate was low enough to avoid arcing. Electric signals from a target exposed to laser radiation were measured under different conditions (at different delay times) of application of electric pulses. The Si(100) substrates were analyzed using Rutherford ion backscattering/channeling spectrometry. The ion implantation dose occurred to be the highest if the high-voltage pulse was applied at a moment of time when the ion component of the plume approached the substrate. In this case, the implanted ions had the highest energy determined by the amplitude of the electric pulse. An advance or delay in applying a high-voltage pulse caused the ion dose and energy to decrease. A physical model incorporating three possible modes of ion implantation was proposed for the interpretation of the experimental results. If a laser plume was formed in the external field, ions were accelerated from the front of the dense plasma, and the ion current depended on the gas-dynamic expansion of the plume. The application of a high-voltage pulse, at the instant when the front approached the substrate, maintained the mode that was characteristic of the traditional plasma immersion ion implantation, and the ion current was governed by the dynamics of the plasma sheath in the substrate-to-target gap. In the case of an extremely late application of a high-voltage pulse, ions retained in the entire volume of the experimental chamber (as a result of the

The Determination of Pesticidal and Non-Pesticidal Organotin Compounds in Water Matrices by in situ Ethylation and Gas Chromatography with Pulsed Flame Photometric Detection

Science.gov (United States)

The concurrent determination of pesticidal and non-pesticidal organotin compounds in several water matrices, using a simultaneous in situ ethylation and liquid-liquid extraction followed by splitless injection mode capillary gas chromatography with pulsed flame photometric detect...

Taking the pulse of the Mediterranean

International Nuclear Information System (INIS)

Osterberg, C.

1977-01-01

The staff at the International Laboratory of Marine Radioactivity in Monaco realized that they were favourably located to ?take the pulse of the Mediterranean? and begin an enquiry into its health. Practically all of the radioactivity in the water and sediments could be attributed to world-wide fallout from the nuclear tests of the 1960's. Unable to find enough radioactivity in the Mediterranean to work with in a meaningful way, the laboratory imported sediments from the Bikini-Eniwetok sites of the American thermonuclear tests, and sediments from the Irish Sea near the Windscale effluent pipe to do their experiments. Other experiments were carried out with relatively innocuous, short half-lived 237 Pu, made especially for the laboratory in Japan and in the USA. A proposal was made to the United Nations Environment Programme (UNEP) to monitor the levels of chlorinated hydrocarbons and heavy elements in the Mediterranean. This report briefly discusses that work. Three sets of studies were carried out by the Monaco group to assess the current levels of pollutants in the Mediterranean: 1) Radioactivity; 2) Chlorinated hydrocarbons (DDT's and polychlorinated biphenyls); 3) Heavy elements. As stated earlier, measurements showed that radioactivity in the ocean off Monaco is quite low, indicating that there are no major sources of radionuclides reaching the open ocean other than fallout. Polychlorinated biphenyls were measured by gas-chromatography. The results of this study were being published (Marine Pollution Bulletin, 1977) but it can be said that the data are not much different than that for the Atlantic Ocean and Saragasso Sea. The western Mediterranean is clearly higher in PCB's than the eastern Mediterranean, but not unduly so. Less can be said about the trace or heavy elements because the patterns are so variable. Atomic absorption spectrometry is used to detect and measure most trace elements. For the lower levels that appear in seawater, chemical

Light storage in a doped solid enhanced by feedback-controlled pulse shaping

International Nuclear Information System (INIS)

Beil, F.; Buschbeck, M.; Heinze, G.; Halfmann, T.

2010-01-01

We report on experiments dealing with feedback-controlled pulse shaping to optimize the efficiency of light storage by electromagnetically induced transparency (EIT) in a Pr 3+ :Y 2 SiO 5 crystal. A learning loop in combination with an evolutionary algorithm permits the automatic determination of optimal temporal profiles of intensities and frequencies in the driving laser pulses (i.e., the probe and coupling pulses). As a main advantage, the technique finds optimal solutions even in the complicated multilevel excitation scheme of a doped solid, involving large inhomogeneous broadening. The learning loop experimentally determines optimal temporal intensity profiles of the coupling pulses for a given probe pulse. The optimized intensity pulse shapes enhance the light-storage efficiency in the doped solid by a factor of 2. The learning loop also determines a fast and efficient preparation pulse sequence, which serves to optically prepare the crystal prior to light-storage experiments. The optimized preparation sequence is 5 times faster than standard preparation sequences. Moreover, the optimized preparation sequence enhances the optical depth in the medium by a factor of 5. As a consequence, the efficiency of light storage also increases by another factor of 3. Our experimental data clearly demonstrate the considerable potential of feedback-controlled pulse shaping, applied to EIT-driven light storage in solid media.

Measurements of picosecond pulses of a high-current electron accelerator

International Nuclear Information System (INIS)

Zheltov, K.A.; Petrenko, A.N.; Turundaevskaya, I.G.; Shalimanov, V.F.

1997-01-01

The duration of a picosecond high-current accelerator electron beam pulse duration is measured and its shape is determined using a measuring line, comprising a Faraday cup, a radiofrequency cable of minor length and a wide-band SRG-7 oscillograph. The procedure of data reconstruction according to regularization method is applied to determine the actual shape of the pulse measured

Pulse discrimination of background and gamma-ray source by digital pulse shape discrimination in a BF3 detector

International Nuclear Information System (INIS)

Kim, Jinhyung; Kim, J. H.; Choi, H. D.

2014-01-01

As a representative method of non-destructive assay, accurate neutron measurement is difficult due to large background radiation such as γ-ray, secondary radiation, spurious pulse, etc. In a BF 3 detector, the process of signal generation is different between neutron and other radiations. As the development of detection technique, all of signal data can be digitized by digital measurement method. In the previous study, Applied Nuclear Physics Group in Seoul National University has developed digital Pulse Shape Discrimination (PSD) method using digital oscilloscope. In this study, optimization of parameters for pulse discrimination is discussed and γ-ray region is determined by measuring 60 Co source. The background signal of BF 3 detector is discriminated by digital PSD system. Parameters for PSD are optimized through FOM calculation. And the γ-ray region is determined by measuring 60 Co source. In the future, the performance of developed system will be tested in low and high intensity neutron field

Pulse Shape Tuning in Neutrino Detector Scintillator Systems

Energy Technology Data Exchange (ETDEWEB)

Aberle, Ch.; Buck, Ch.; Hartmann, F.X.; Schoenert, St. [Max Planck Institute for Nuclear Physics, Heidelberg (Germany); Hartmann, F.X. [Hartmann Scientific, City of Virginia Beach, Virginia (United States)

2009-07-01

Full text of publication follows: A new light yield model based on energy transfer pathways in codoped organic liquid scintillator systems is created and used to determine experimentally non-radiative energy transfer rate constants from which time dependent light pulse shapes and total light yields are predicted for multi-component liquids. Such constants determine effective Forster-Dexter critical concentrations. A surprising discovery regarding the critical concentration in n-dodecane permits tuning the pulse shape for different regions in the Double Chooz neutrino detector. (authors)

Pulsed ventilation in mines. II

Energy Technology Data Exchange (ETDEWEB)

Krause, D

1975-06-01

Using test results, an attempt is made to determine the form of the free jet and to derive design data for pulsed fans. The most suitable placing of these fans for the ventilation of headings is discussed.

Determination of the apparent porosity level of refractory concrete during a sintering process using an ultrasonic pulse velocity technique and image analysis

Directory of Open Access Journals (Sweden)

LJUBICA M. PAVLOVIĆ

2010-03-01

Full Text Available Concrete which undergoes a thermal treatment before (pre-casted concrete blocks and during (concrete embedded in-situ its life-service can be applied in plants operating at high temperature and as thermal insulation. Sintering is a process which occurs within a concrete structure in such conditions. Progression of sintering process can be monitored by the change of the porosity parameters determined with a nondestructive test method - ultrasonic pulse velocity and computer program for image analysis. The experiment has been performed on the samples of corundum and bauxite concrete composites. The apparent porosity of the samples thermally treated at 110, 800, 1000, 1300 and 1500 C was primary investigated with a standard laboratory procedure. Sintering parameters were calculated from the creep testing. The loss of strength and material degradation occurred in concrete when it was subjected to the increased temperature and a compressive load. Mechanical properties indicate and monitor changes within microstructure. The level of surface deterioration after the thermal treatment was determined using Image Pro Plus program. Mechanical strength was estimated using ultrasonic pulse velocity testing. Nondestructive ultrasonic mea¬surement was used as a qualitative description of the porosity change in specimens which is the result of the sintering process. The ultrasonic pulse velocity technique and image analysis proved to be reliable methods for monitoring of micro-structural change during the thermal treatment and service life of refractory concrete.

Method for determining efficiency in a liquid scintillation system

International Nuclear Information System (INIS)

Laney, B.H.

1975-01-01

In a liquid scintillation system utilizing plural photomultiplyier means, a method for determining efficiency of coincident pulse detection. Various incremental counting efficiency levels are associated with asymptotic functions in a two dimension matrix in which the abscissa and ordinate correspond to the pulse heights of each of a pair of coincident pulses from different photomultiplier means. An efficiency determining point is located in the matrix based on the sum of the pulse heights of each of the coincident pulses as well as on the amplitude of the smallest pulse of the coincident pulses. The single counting efficiency determining point is recorded as the level of efficiency at which the photomultiplier means detect scintillations that generate coincident pulses having pulse heights equal to those recorded. (Patent Office Record)

Short-pulse optical parametric chirped-pulse amplification for the generation of high-power few-cycle pulses

International Nuclear Information System (INIS)

Major, Zs.; Osterhoff, J.; Hoerlein, R.; Karsch, S.; Fuoloep, J.A.; Krausz, F.; Ludwig-Maximilians Universitaet, Muenchen

2006-01-01

Complete test of publication follows. In the quest for a way to generate ultrashort, high-power, few-cycle laser pulses the discovery of optical parametric amplification (OPA) has opened up to the path towards a completely new regime, well beyond that of conventional laser amplification technology. The main advantage of this parametric amplification process is that it allows for an extremely broad amplification bandwidth compared to any known laser amplifier medium. When combined with the chirped-pulse amplification (CPA) principle (i.e. OPCPA), on one hand pulses of just 10 fs duration and 8 mJ pulse energy have been demonstrated. On the other hand, pulse energies of up to 30 J were also achieved on a different OPCPA system; the pulse duration in this case, however, was 100 fs. In order to combine ultrashort pulse durations (i.e. pulses in the few-cycle regime) with high pulse energies (i.e. in the Joule range) we propose tu pump on OPCPA chain with TW-scale short pulses (100 fs - 1 ps instead of > 100 ps of previous OPCPA systems) delivered by a conventional CPA system. This approach inherently improves the conditions for generating high-power ultrashort pulses using OPCPA in the following ways. Firstly, the short pump pulse duration reduces the necessary stretching factor for the seed pulse, thereby increasing stretching and compression fidelity. Secondly, also due to the shortened pump pulse duration, a much higher contrast is achieved. Finally, the significantly increased pump power makes the use of thinner OPCPA crystals possible, which implies an even broader amplification bandwidth, thereby allowing for even shorter pulses. We carried out theoretical investigations to show the feasibility of such a set-up. Alongside these studies we will also present preliminary experimental results of an OPCPA system pumped by the output of our Ti:Sapphire ATLAS laser, currently delivering 350 mJ in 43 fs. An insight into the planned scaling of this technique to petawatt

New spectrofluorometer with pulsed intensified photodiodes array for direct trace determination of actinides and lanthanides in solutions

International Nuclear Information System (INIS)

Decambox, P.; Kirsch, B.; Mauchien, P.; Moulin, C.

1989-01-01

Actinides and lanthanides in solution at very low level are determined by Time-Resolved Laser-Induced Spectrofluorometry (TRLIS) with pulsed intensified photodiodes array detection. Temporal resolution allows discrimination against short lifetime fluorescence and measurement of fluorescence lifetime in various matrices. The use of laser source leads to excitation selectivity and high sensitivity. Multichannel detection allows to cover the entire wavelength range of interest which leads to emission selectivity and rapidity. These different advantages are present in the newly commercialized spectrofluorometer FLUO 2001 together with specially analytical adapted software. The apparatus and performances obtained for several actinides and lanthanides are presented

Rapid testing of pulse transformers

Science.gov (United States)

Grillo, J.

1980-01-01

Quality-control testing of pulse transformers is speeded up by method for determining rise time and droop. Instead of using oscilloscope and square-wave generator to measure these characteristics directly, method uses voltmeter and sine-wave generator to measure them indirectly in about one-tenth time. Droop and rise time are determined by measuring input/output voltage ratio at just four frequencies.

Multi-Axis Thrust Measurements of the EO-1 Pulsed Plasma Thruster

Science.gov (United States)

Arrington, Lynn A.; Haag, Thomas W.

1999-01-01

Pulsed plasma thrusters are low thrust propulsive devices which have a high specific impulse at low power. A pulsed plasma thruster is currently scheduled to fly as an experiment on NASA's Earth Observing-1 satellite mission. The pulsed plasma thruster will be used to replace one of the reaction wheels. As part of the qualification testing of the thruster it is necessary to determine the nominal thrust as a function of charge energy. These data will be used to determine control algorithms. Testing was first completed on a breadboard pulsed plasma thruster to determine nominal or primary axis thrust and associated propellant mass consumption as a function of energy and then later to determine if any significant off-axis thrust component existed. On conclusion that there was a significant off-axis thrust component with the bread-board in the direction of the anode electrode, the test matrix was expanded on the flight hardware to include thrust measurements along all three orthogonal axes. Similar off-axis components were found with the flight unit.

Space Vector Pulse Width Modulation of a Multi-Level Diode ...

African Journals Online (AJOL)

Space Vector Pulse Width Modulation of a Multi-Level Diode Clamped ... of MATLAB /SIMULINK modeling of the space vector pulse-width modulation and the ... two adjacent active vectors in determining the switching process of the multilevel ...

Pulsed electron beam generation with fast repetitive double pulse system

Energy Technology Data Exchange (ETDEWEB)

Sharma, Surender Kumar; Deb, Pankaj; Shyam, Anurag, E-mail: surender80@gmail.com [Energetics and Electromagnetics Division, Bhabha Atomic Research Centre, Visakhapatnam (India); Sharma, Archana [Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Mumbai (India)

2014-07-01

Longer duration high voltage pulse (∼ 100 kV, 260 ns) is generated and reported using helical pulse forming line in compact geometry. The transmission line characteristics of the helical pulse forming line are also used to develop fast repetition double pulse system with very short inter pulse interval. It overcomes the limitations caused due to circuit parameters, power supplies and load characteristics for fast repetitive high voltage pulse generation. The high voltage double pulse of 100 kV, 100 ns with an inter pulse repetition interval of 30 ns is applied across the vacuum field emission diode for pulsed electron beam generation. The electron beam is generated from cathode material by application of negative high voltage (> 100 kV) across the diode by explosive electron emission process. The vacuum field emission diode is made of 40 mm diameter graphite cathode and SS mesh anode. The anode cathode gap was 6 mm and the drift tube diameter was 10 cm. The initial experimental results of pulsed electron beam generation with fast repetitive double pulse system are reported and discussed. (author)

Neutronics of pulsed spallation neutron sources

International Nuclear Information System (INIS)

Watanabe, Noboru

2003-01-01

Various topics and issues on the neutronics of pulsed spallation neutron sources, mainly for neutron scattering experiments, are reviewed to give a wide circle of readers a better understanding of these sources in order to achieve a high neutronic performance. Starting from what neutrons are needed, what the spallation reaction is and how to produce slow-neutrons more efficiently, the outline of the target and moderator neutronics are explained. Various efforts with some new concepts or ideas have already been devoted to obtaining the highest possible slow-neutron intensity with desired pulse characteristics. This paper also reviews the recent progress of such efforts, mainly focused on moderator neutronics, since moderators are the final devices of a neutron source, which determine the source performance. Various governing parameters for neutron-pulse characteristics such as material issues, geometrical parameters (shape and dimensions), the target-moderator coupling scheme, the ortho-para-hydrogen ratio, poisoning, etc are discussed, aiming at a high performance pulsed spallation source

Pulse Distortion in Saturated Fiber Optical Parametric Chirped Pulse Amplification

DEFF Research Database (Denmark)

Lali-Dastjerdi, Zohreh; Da Ros, Francesco; Rottwitt, Karsten

2012-01-01

Fiber optical parametric chirped pulse amplification is experimentally compared for different chirped pulses in the picosecond regime. The amplified chirped pulses show distortion appearing as pedestals after recompression when the amplifier is operated in saturation.......Fiber optical parametric chirped pulse amplification is experimentally compared for different chirped pulses in the picosecond regime. The amplified chirped pulses show distortion appearing as pedestals after recompression when the amplifier is operated in saturation....

Femtosecond-Laser-Pulse Characterization and Optimization for CARS Microscopy.

Directory of Open Access Journals (Sweden)

Vincenzo Piazza

Full Text Available We present a simple method and its experimental implementation to determine the pulse durations and linear chirps of the pump-and-probe pulse and the Stokes pulse in a coherent anti-Stokes Raman scattering microscope at sample level without additional autocorrelators. Our approach exploits the delay line, ubiquitous in such microscopes, to perform a convolution of the pump-and-probe and Stokes pulses as a function of their relative delay and it is based on the detection of the photons emitted from an appropriate non-linear sample. The analysis of the non-resonant four-wave-mixing and sum-frequency-generation signals allows for the direct retrieval of the pulse duration on the sample and the linear chirp of each pulse. This knowledge is crucial in maximizing the spectral-resolution and contrast in CARS imaging.

The characterisation of polymers using pulsed NMR

International Nuclear Information System (INIS)

Charlesby, A.

1983-01-01

Broad line pulsed NMR is applied to obtain information on radiation-induced polymer changes and other aspects of polymer science based on the interpretation of spin-spin relaxation curves. Calculations are made to determine the molecular weight, the crosslink density of simple, low molecular weight, flexible polymers. For higher molecular weight polymers, a conclusion can be drawn on the concentrations of entangled and crosslinked units by means of pulsed NMR. Some typical applications of the technique are illustrated by the examples of polyethylenes, rubbers, filled polymeric systems and aqueous polyethylene oxide solutions. The morphology of polymers can be followed by pulsed NMR. (V.N.)

Updating the induction module from single-pulse to double-pulses

International Nuclear Information System (INIS)

Huang Ziping; Wang Huacen; Deng Jianjun

2002-01-01

A double-pulse Linear Induced Accelerator (LIA) module is reconstructed based on a usual simple-pulse LIA module. By changing the length of one of the cables between the inductive cell and the Blumlein pulse forming line, two induction pulses with 90 ns FWHM and 150 kV pulse voltage are generated by the ferrite cores inductive cell. The interval time of the pulses is adjustable by changing the lengths of the cable

Thickness determination of large-area films of yttria-stabilized zirconia produced by pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Pryds, N. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark)]. E-mail: nini.pryds@risoe.dk; Toftmann, B. [Department of Optics and Plasma Research, Riso National Laboratory, DK-4000 Roskilde (Denmark); Bilde-Sorensen, J.B. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark); Schou, J. [Department of Optics and Plasma Research, Riso National Laboratory, DK-4000 Roskilde (Denmark); Linderoth, S. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark)

2006-04-30

Films of yttria-stabilized zirconia (YSZ) on a polished silicon substrate of diameter up to 125 mm have been produced in a large-area pulsed laser deposition (PLD) setup under typical PLD conditions. The film thickness over the full film area has been determined by energy-dispersive X-ray spectrometry in a scanning electron microscope (SEM) with use of a method similar to one described by Bishop and Poole. The attenuation of the electron-induced X-rays from the Si wafer by the film was monitored at a number of points along a diameter and the thickness was determined by Monte Carlo simulations of the attenuation for various values of film thickness with the program CASINO. These results have been compared with direct measurements in the SEM of the film thickness on a cross-section on one of the wafers. The results of these measurements demonstrate the ability of this technique to accurately determine the thickness of a large film, i.e. up to diameters of 125 mm, in a relatively short time, without destroying the substrate, without the need of a standard sample and without the need of a flat substrate. We have also demonstrated that by controlling the deposition parameters large-area YSZ films with uniform thickness can be produced.

Thickness determination of large-area films of yttria-stabilized zirconia produced by pulsed laser deposition

International Nuclear Information System (INIS)

Pryds, N.; Toftmann, B.; Bilde-Sorensen, J.B.; Schou, J.; Linderoth, S.

2006-01-01

Films of yttria-stabilized zirconia (YSZ) on a polished silicon substrate of diameter up to 125 mm have been produced in a large-area pulsed laser deposition (PLD) setup under typical PLD conditions. The film thickness over the full film area has been determined by energy-dispersive X-ray spectrometry in a scanning electron microscope (SEM) with use of a method similar to one described by Bishop and Poole. The attenuation of the electron-induced X-rays from the Si wafer by the film was monitored at a number of points along a diameter and the thickness was determined by Monte Carlo simulations of the attenuation for various values of film thickness with the program CASINO. These results have been compared with direct measurements in the SEM of the film thickness on a cross-section on one of the wafers. The results of these measurements demonstrate the ability of this technique to accurately determine the thickness of a large film, i.e. up to diameters of 125 mm, in a relatively short time, without destroying the substrate, without the need of a standard sample and without the need of a flat substrate. We have also demonstrated that by controlling the deposition parameters large-area YSZ films with uniform thickness can be produced

Study of pulse shapes in Ge detectors with PET

Energy Technology Data Exchange (ETDEWEB)

Grabmayr, Peter; Hegai, Alexander; Jochum, Josef; Schmitt, Christopher; Schuetz, Ann-Kathrin [Eberhard Karls Univeritaet Tuebingen (Germany); Collaboration: GERDA-Collaboration

2016-07-01

The Gerda collaboration aims to determine the half life of the neutrinoless double beta decay (0νββ) of {sup 76}Ge. For Phase II Gerda wants to reduce the background contribution significantly by active background-suppression techniques. One of such techniques is the pulse shape analysis of signals induced by the interaction of radiation with the detector. The pulse shapes depend not only on the energy of the interacting gamma, the geometry and field configuration but also on the location of interaction in the crystal. The waveform and the location of the interaction in the germanium can be determined by positron-emission-tomography (PET). First results of this novel pulse shape study with the PET will be presented in this talk.

Evaluation of bipolar pulse generator for high-purity pulsed ion beam

International Nuclear Information System (INIS)

Ito, H.; Kitamura, I.; Masugata, K.

2008-01-01

A new type of pulsed ion beam accelerator named 'bipolar pulse accelerator (BPA)' has been proposed in order to improve the purity of intense pulsed ion beams. To confirm the principle of the BPA, we developed a bipolar pulse generator, which consists of a Marx generator and a pulse forming line (PFL) with a rail gap switch on its end. In this article, we report the experimental results of the bipolar pulse and evaluate the electrical characteristics of the bipolar pulse generator. When the bipolar pulse generator was operated at 70% of the full charge condition of the PEL, the bipolar pulse with the first (-138 kV, 72 ns) and the second pulse (+130 kV, 70 ns) was successfully obtained. The evaluation of the electrical characteristics indicates that the developed generator can produce the bipolar pulse with fast rise time and sharp reversing time. At present the bipolar pulse generator is installed in the B y type magnetically insulated ion diode and we carry out the experiment on the production of an intense pulsed ion beam by the bipolar pulse accelerator. (author)

The role of the waveform in pulse pile-up

International Nuclear Information System (INIS)

Datlowe, D.W.

1977-01-01

Pulse pile-up is the distortion of pulse-height distributions due to the overlap of detector responses to the arrival of two or more particles or photons within the detector resolving time. This paper presents a computational technique for simulating pile-up effects, which includes explicitly the dependence on the pulse-shape of the detector system. The basis of the technique is the manipulation of probability densities. The method is applicable to all types of linear pulse counting systems for nucleons, electrons, and photons, as long as the result is a pulse-height distribution. The algorithms are highly efficient in the amount of computing required for simulations, and internal checks for the numerical accuracy of the results are included. Studies of pile-up by monoenergetic pulses are used to determine the interrelationship between pulse shapes and spectral features; this information can be used to minimize pile-up. For broad spectra, the square wave approximation is compared with the present model including the correct waveform; introducing the pulse shape information smooths spectral features but does not qualitatively change the spectrum. (Auth.)

Reconstruction of Attosecond Pulse Trains Using an Adiabatic Phase Expansion

International Nuclear Information System (INIS)

Varju, K.; Gustafsson, E.; Johnsson, P.; Mauritsson, J.; L'Huillier, A.; Mairesse, Y.; Agostini, P.; Breger, P.; Carre, B.; Merdji, H.; Monchicourt, P.; Salieres, P.; Frasinski, L.J.

2005-01-01

We propose a new method to reconstruct the electric field of attosecond pulse trains. The phase of the high-order harmonic emission electric field is Taylor expanded around the maximum of the laser pulse envelope in the time domain and around the central harmonic in the frequency domain. Experimental measurements allow us to determine the coefficients of this expansion and to characterize the radiation with attosecond accuracy over a femtosecond time scale. The method gives access to pulse-to-pulse variations along the train, including the timing, the chirp, and the attosecond carrier envelope phase

Current pulse shaping of the load current on PTS

Directory of Open Access Journals (Sweden)

Minghe Xia

2016-02-01

Full Text Available The typical rise time of PTS machine is ∼110 ns with about 10 MA peak current under short pulse mode when all 24 modules discharge simultaneously. By distributing the trigger times of 12 laser beams logically and adjusting the statues of the pulse output switches, longer rise-time pulse can be obtained on the PTS facility. Based on the required pulse shape, whole circuit simulations will be used to calculate the trigger times of each laser triggering gas switch and the status of the pulse output switches. The rise time of the current is determined by the time difference between the first and last trigged laser triggering gas switches. In order to trigger the laser triggering gas switch, sufficient laser power is needed to be sent into the gap of the gas switches. The gas pressure and voltage difference on the two electrodes of the gas switches also affect the triggering of the gas switches, and the voltage added on the gas switch is determined by its transition time. Traditionally the trigger time difference should be less than the transition time of the two neighboring modules. A new simulation model of PTS shows one can break this transition time limits. Series of current pulse shaping experiments have been investigated on the PTS (Primary Test Stand. As results, more than 5 MA peak current were successfully achieved on the load with a rise time of 600 ns. This study and experiments of the pulse shaping on PTS demonstrate the adaptable ability of the PTS for offering different waveform of mega ampere current pulse for different research purpose.

Development of a computer program to determine the pulse-height distribution in a gamma-ray detector from an arbitrary geometry source -feasibility study

International Nuclear Information System (INIS)

Currie, G.D.; Marshall, M.

1989-03-01

The feasibility of developing a computer program suitable for evaluating the pulse-height spectrum in a gamma-ray detector from a complex geometry source has been examined. A selection of relevant programs, Monte Carlo radiation transport codes, have been identified and their applicability to this study discussed. It is proposed that the computation be performed in two parts: the evaluation of the photon fluence at the detector using a photon transport code, and calculation of the pulse-height distribution from this spectrum using response functions determined with an electron-photon transport code. The two transport codes selected to perform this procedure are MCNP (Monte Carlo Neutron Photon code), and EGS4 (Electron Gamma Shower code). (Author)

Measurement of subcriticality by a pulsing α-method

International Nuclear Information System (INIS)

Jitarev, V.E.; Kachanov, V.M.; Kuzmin, A.N.

1999-01-01

The report presents results of a pulsing α-method [1] for determination of the WWER system subcriticality. The pulsing α-method permits to conduct measurements of system subcriticality in conditions of subcritical state and large neutron background. Therefore this method can be used for the control of a subcriticality of storehouses of a burn up nuclear fuel and stopped reactor. (Authors)

Pulse-shaping strategies in short-pulse fiber amplifiers

Energy Technology Data Exchange (ETDEWEB)

Schimpf, Damian Nikolaus

2010-02-09

Ultrashort pulse lasers are an important tool in scientific and industrial applications. However, many applications are demanding higher average powers from these ultrashort pulse sources. This can be achieved by combining direct diode pumping with novel gain media designs. In particular, ultrashort pulse fiber lasers are now delivering average powers in the kW range. However, the design of fiber lasers, producing pulses with high peak-powers, is challenging due to the impact of nonlinear effects. To significantly reduce these detrimental effects in ultrashort pulse fiber amplifers, the combination of chirped pulse amplification (CPA) and large mode area fibers is employed. Using these methods, the pulse energy of fiber lasers has been steadily increasing for the past few years. Recently, a fiber-based CPA-system has been demonstrated which produces pulse energies of around 1 mJ. However, both the stretching and the enlargement of the mode area are limited, and therefore, the impact of nonlinearity is still noticed in systems employing such devices. The aim of this thesis is the analysis of CPA-systems operated beyond the conventional nonlinear limit, which corresponds to accumulated nonlinear phase-shifts around 1 rad. This includes a detailed discussion of the influence of the nonlinear effect self-phase modulation on the output pulse of CPA-systems. An analytical model is presented. Emphasis is placed on the design of novel concepts to control the impact of self-phase modulation. Pulse-shaping is regarded as a powerful tool to accomplish this goal. Novel methods to control the impact of SPM are experimentally demonstrated. The design of these concepts is based on the theoretical findings. Both amplitude- and phase-shaping are studied. Model-based phase-shaping is implemented in a state-of-the-art fiber CPA-system. The influence of the polarization state is also highlighted. Additionally, existing techniques and recent advances are put into context. (orig.)

Pulse-shaping strategies in short-pulse fiber amplifiers

International Nuclear Information System (INIS)

Schimpf, Damian Nikolaus

2010-01-01

Ultrashort pulse lasers are an important tool in scientific and industrial applications. However, many applications are demanding higher average powers from these ultrashort pulse sources. This can be achieved by combining direct diode pumping with novel gain media designs. In particular, ultrashort pulse fiber lasers are now delivering average powers in the kW range. However, the design of fiber lasers, producing pulses with high peak-powers, is challenging due to the impact of nonlinear effects. To significantly reduce these detrimental effects in ultrashort pulse fiber amplifers, the combination of chirped pulse amplification (CPA) and large mode area fibers is employed. Using these methods, the pulse energy of fiber lasers has been steadily increasing for the past few years. Recently, a fiber-based CPA-system has been demonstrated which produces pulse energies of around 1 mJ. However, both the stretching and the enlargement of the mode area are limited, and therefore, the impact of nonlinearity is still noticed in systems employing such devices. The aim of this thesis is the analysis of CPA-systems operated beyond the conventional nonlinear limit, which corresponds to accumulated nonlinear phase-shifts around 1 rad. This includes a detailed discussion of the influence of the nonlinear effect self-phase modulation on the output pulse of CPA-systems. An analytical model is presented. Emphasis is placed on the design of novel concepts to control the impact of self-phase modulation. Pulse-shaping is regarded as a powerful tool to accomplish this goal. Novel methods to control the impact of SPM are experimentally demonstrated. The design of these concepts is based on the theoretical findings. Both amplitude- and phase-shaping are studied. Model-based phase-shaping is implemented in a state-of-the-art fiber CPA-system. The influence of the polarization state is also highlighted. Additionally, existing techniques and recent advances are put into context. (orig.)

Determination of antioxidant activity of spices and their active principles by differential pulse voltammetry.

Science.gov (United States)

Palma, Alberto; Ruiz Montoya, Mercedes; Arteaga, Jesús F; Rodríguez Mellado, Jose M

2014-01-22

The anodic oxidation of mercury in the presence of hydrogen peroxide in differential pulse voltammetry (DPV) was used to determine the antioxidant (AO) character of radical scavengers. Hydroperoxide radical is formed at the potentials of the oxidation peak on mercury electrodes, such radical reacting with the antioxidants in different extension. The parameter C10 (antioxidant concentration at which the peak area decreases by 10%) is used to measure the scavenging activity of the individual antioxidants. To establish the scavenging activity of antioxidant mixtures as a whole, the parameter, μ10 as the reverse of V10, V10 being the volume necessary to decrease the peak area in DPV by 10%, was selected. Higher μ10 values correspond to higher scavenging activity. The studies have been extended to aqueous extracts of some species. The results may be useful in explaining the effect of spices in vitro and in vivo studies.

Influence of laser pulse frequency on the microstructure of aluminum nitride thin films synthesized by pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Antonova, K., E-mail: krasa@issp.bas.bg [Institute of Solid State Physics, Bulgarian Academy of Sciences, Tzarigradsko Chaussee 72, Sofia 1784 (Bulgaria); Duta, L. [National Institute for Lasers, Plasma, and Radiation Physics, 409 Atomistilor Street, 077125 Magurele (Romania); Szekeres, A. [Institute of Solid State Physics, Bulgarian Academy of Sciences, Tzarigradsko Chaussee 72, Sofia 1784 (Bulgaria); Stan, G.E. [National Institute of Materials Physics, 105 bis Atomistilor Street, 077125 Magurele (Romania); Mihailescu, I.N. [National Institute for Lasers, Plasma, and Radiation Physics, 409 Atomistilor Street, 077125 Magurele (Romania); Anastasescu, M.; Stroescu, H.; Gartner, M. [Institute of Physical Chemistry, “Ilie Murgulescu”, Romanian Academy, 202 Splaiul Independentei, 060021 Bucharest (Romania)

2017-02-01

Highlights: • Study of pulsed laser deposited AlN films at different laser pulse frequencies. • Higher laser pulse frequency promotes nanocrystallites formation at temperature 450 °C. • AFM and GIXRD detect randomly oriented wurtzite AlN structures. • Characterization of the nanocrystallites’ orientation by FTIR reflectance spectra. • Berreman effect is registered in p-polarised radiation at large incidence angles. - Abstract: Aluminum Nitride (AlN) thin films were synthesized on Si (100) wafers at 450 °C by pulsed laser deposition. A polycrystalline AlN target was multipulsed irradiated in a nitrogen ambient, at different laser pulse repetition rate. Grazing Incidence X-Ray Diffraction and Atomic Force Microscopy analyses evidenced nanocrystallites with a hexagonal lattice in the amorphous AlN matrix. The thickness and optical constants of the layers were determined by infrared spectroscopic ellipsometry. The optical properties were studied by Fourier Transform Infrared reflectance spectroscopy in polarised oblique incidence radiation. Berreman effect was observed around the longitudinal phonon modes of the crystalline AlN component. Angular dependence of the A{sub 1}LO mode frequency was analysed and connected to the orientation of the particles’ optical axis to the substrate surface normal. The role of the laser pulse frequency on the layers’ properties is discussed on this basis.

Accurate determination of the oxidative phosphorylation affinity for ADP in isolated mitochondria.

Directory of Open Access Journals (Sweden)

Gilles Gouspillou

Full Text Available BACKGROUND: Mitochondrial dysfunctions appear strongly implicated in a wide range of pathologies. Therefore, there is a growing need in the determination of the normal and pathological integrated response of oxidative phosphorylation to cellular ATP demand. The present study intends to address this issue by providing a method to investigate mitochondrial oxidative phosphorylation affinity for ADP in isolated mitochondria. METHODOLOGY/PRINCIPAL FINDINGS: The proposed method is based on the simultaneous monitoring of substrate oxidation (determined polarographically and phosphorylation (determined using the glucose-hexokinase glucose-6-phosphate dehydrogenase-NADP(+ enzymatic system rates, coupled to the determination of actual ADP and ATP concentrations by bioluminescent assay. This enzymatic system allows the study of oxidative phosphorylation during true steady states in a wide range of ADP concentrations. We demonstrate how the application of this method allows an accurate determination of mitochondrial affinity for ADP from both oxidation (K(mVox and phosphorylation (K(mVp rates. We also demonstrate that determination of K(mVox leads to an important overestimation of the mitochondrial affinity for ADP, indicating that mitochondrial affinity for ADP should be determined using phosphorylation rate. Finally, we show how this method allows the direct and precise determination of the mitochondrial coupling efficiency. Data obtained from rat skeletal muscle and liver mitochondria illustrate the discriminating capabilities of this method. CONCLUSIONS/SIGNIFICANCE: Because the proposed method allows the accurate determination of mitochondrial oxidative phosphorylation affinity for ADP in isolated mitochondria, it also opens the route to a better understanding of functional consequences of mitochondrial adaptations/dysfunctions arising in various physiological/pathophysiological conditions.

SBS pulse compression for excimer inertial fusion energy drivers

International Nuclear Information System (INIS)

Linford, G.J.

1994-01-01

A key requirement for the development of commercial fusion power plants utilizing inertial confinement fusion (ICF) as a source of thermonuclear power is the availability of reliable, efficient laser drivers. These laser drivers must be capable of delivering UV optical pulses having energies of the order of 5MJ to cryogenic deuterium-tritium (D/T) ICF targets. The current requirements for laser ICF target irradiation specify the laser wavelength, λ ca. 250 nm, pulse duration, τ p ca. 6 ns, bandwidth, Δλ ca. 0.1 nm, polarization state, etc. Excimer lasers are a leading candidate to fill these demanding ICF driver requirements. However, since excimer lasers are not storage lasers, the excimer laser pulse duration, τ pp , is determined primarily by the length of the excitation pulse delivered to the excimer laser amplifier. Pulsed power associated with efficiently generating excimer laser pulses has a time constant, τ pp which falls in the range, 30 τ p pp p . As a consequence, pulse compression is needed to convert the long excimer laser pulses to pulses of duration τ p . These main ICF driver pulses require, in addition, longer, lower power precursor pulses delivered to the ICF target before the arrival of the main pulse. Although both linear and non-linear optical (NLO) pulse compression techniques have been developed, computer simulations have shown that a ''chirped,'' self-seeded, stimulated Brillouin scattering (SBS) pulse compressor cell using SF 6 at a density, ρ ca. 1 amagat can efficiently compress krypton fluoride (KrF) laser pulses at λ=248 nm. In order to avoid the generation of output pulses substantially shorter than τ p , the optical power in the chirped input SBS ''seed'' beams was ramped. Compressed pulse conversion efficiencies of up to 68% were calculated for output pulse durations of τ p ca. ns

Pulsed water jet generated by pulse multiplication

Czech Academy of Sciences Publication Activity Database

Dvorský, R.; Sitek, Libor; Sochor, T.

2016-01-01

Roč. 23, č. 4 (2016), s. 959-967 ISSN 1330-3651 R&D Projects: GA MŠk(CZ) LO1406; GA MŠk ED2.1.00/03.0082 Institutional support: RVO:68145535 Keywords : high- pressure pulses * pulse intensifier * pulsed water jet * water hammer effect Subject RIV: JQ - Machines ; Tools Impact factor: 0.723, year: 2016 http://hrcak.srce.hr/163752?lang=en

Forensic applications of 14C bomb-pulse dating

International Nuclear Information System (INIS)

Zoppi, U.; Skopec, Z.; Skopec, J.; Jones, G.; Fink, D.; Hua, Q.; Jacobsen, G.; Tuniz, C.; Williams, A.

2004-01-01

After a brief review of the basics of 14 C bomb-pulse dating, this paper presents two unique forensic applications. Particular attention is dedicated to the use of the 14 C bomb-pulse to establish the time of harvest of illicit drugs such as heroin and opium. Preliminary measurements of 14 C concentrations in milligram samples taken from seized drugs are presented. 14 C bomb-pulse dating can determine whether drug distribution originates from stockpiles or recent manufacture, and support the action of law enforcement authorities against criminal organisations involved in drug trafficking. In addition, we describe the dating of wine vintages for a number of authenticated single label vintage red wines from the Barossa Valley - South Australia. Our results show that radiocarbon dating can be used to accurately determine wine vintages and therefore reveal the addition of unrelated materials of natural and synthetic origin

Forensic applications of 14C bomb-pulse dating

Science.gov (United States)

Zoppi, U.; Skopec, Z.; Skopec, J.; Jones, G.; Fink, D.; Hua, Q.; Jacobsen, G.; Tuniz, C.; Williams, A.

2004-08-01

After a brief review of the basics of 14C bomb-pulse dating, this paper presents two unique forensic applications. Particular attention is dedicated to the use of the 14C bomb-pulse to establish the time of harvest of illicit drugs such as heroin and opium. Preliminary measurements of 14C concentrations in milligram samples taken from seized drugs are presented. 14C bomb-pulse dating can determine whether drug distribution originates from stockpiles or recent manufacture, and support the action of law enforcement authorities against criminal organisations involved in drug trafficking. In addition, we describe the dating of wine vintages for a number of authenticated single label vintage red wines from the Barossa Valley - South Australia. Our results show that radiocarbon dating can be used to accurately determine wine vintages and therefore reveal the addition of unrelated materials of natural and synthetic origin.

A Fiber-Optic System Generating Pulses of High Spectral Density

Science.gov (United States)

Abramov, A. S.; Zolotovskii, I. O.; Korobko, D. A.; Fotiadi, A. A.

2018-03-01

A cascade fiber-optic system that generates pulses of high spectral density by using the effect of nonlinear spectral compression is proposed. It is demonstrated that the shape of the pulse envelope substantially influences the degree of compression of its spectrum. In so doing, maximum compression is achieved for parabolic pulses. The cascade system includes an optical fiber exhibiting normal dispersion that decreases along the fiber length, thereby ensuring that the pulse envelope evolves toward a parabolic shape, along with diffraction gratings and a fiber spectral compressor. Based on computer simulation, we determined parameters of cascade elements leading to maximum spectral density of radiation originating from a subpicosecond laser pulse of medium energy.

Elemental analysis using temporal gating of a pulsed neutron generator

Energy Technology Data Exchange (ETDEWEB)

Mitra, Sudeep

2018-02-20

Technologies related to determining elemental composition of a sample that comprises fissile material are described herein. In a general embodiment, a pulsed neutron generator periodically emits bursts of neutrons, and is synchronized with an analyzer circuit. The bursts of neutrons are used to interrogate the sample, and the sample outputs gamma rays based upon the neutrons impacting the sample. A detector outputs pulses based upon the gamma rays impinging upon the material of the detector, and the analyzer circuit assigns the pulses to temporally-based bins based upon the analyzer circuit being synchronized with the pulsed neutron generator. A computing device outputs data that is indicative of elemental composition of the sample based upon the binned pulses.

Author Details

African Journals Online (AJOL)

Subramanian, PA. Vol 5, No 1 (2013) - Articles DC Polarographic and Plane Polarographic investigation of the reduction of Thallium(I) - Aqueous systems at dropping mercury electrode. Abstract PDF. ISSN: 2073-073X. AJOL African Journals Online. HOW TO USE AJOL... for Researchers · for Librarians · for Authors · FAQ's ...

Determination of propylthiouracil in pharmaceuticals by differential pulse voltammetry using a cathodically pretreated boron-doped diamond electrode

Energy Technology Data Exchange (ETDEWEB)

Sartori, Elen Romao [Universidade Estadual de Londrina, PR (Brazil). Dept. de Quimica; Trench, Aline Barrios; Rocha-Filho, Romeu C.; Fatibello-Filho, Orlando, E-mail: bello@ufscar.br [Universidade Federal de Sao Carlos (UFSCAR), SP (Brazil). Dept. de Quimica

2013-09-15

A simple procedure is described for the determination of propylthiouracil (PTU) by differential pulse voltammetry (DPV) using a cathodically pretreated boron-doped diamond (BDD) electrode. Cyclic voltammetry studies indicate that the oxidation of PTU is irreversible at a peak potential of 1.42 V (vs. Ag/AgCl (3.0 mol L{sup -1} KCl)) in a Britton-Robinson (BR) buffer solution (pH 2.0). Under optimized conditions, the obtained analytical curve was linear (r = 0.9985) for the PTU concentration range of 1.0 to 29.1 {mu}mol L{sup -1} in a BR buffer solution (pH 2.0), with a detection limit of 0.90 {mu}mol L{sup -1}. The proposed method was successfully applied in the determination of PTU in pharmaceutical samples, with results in agreement at a 95% confidence level with those obtained using an official titration method. (author)

Pulsed TRIGA reactor as substitute for long pulse spallation neutron source

International Nuclear Information System (INIS)

Whittemore, W.L.

1999-01-01

TRIGA reactor cores have been used to demonstrate various pulsing applications. The TRIGA reactor fuel (U-ZrH x ) is very robust especially in pulsing applications. The features required to produce 50 pulses per second have been successfully demonstrated individually, including pulse tests with small diameter fuel rods. A partially optimized core has been evaluated for pulses at 50 Hz with peak pulsed power up to 100 MW and an average power up to 10 MW. Depending on the design, the full width at half power of the individual pulses can range between 2000 μsec to 3000 μsec. Until recently, the relatively long pulses (2000 μsec to 3000 μsec) from a pulsed thermal reactor or a long pulse spallation source (LPSS) have been considered unsuitable for time-of-flight measurements of neutron scattering. More recently considerable attention has been devoted to evaluating the performance of long pulse (1000 to 4000 μs) spallation sources for the same type of neutron measurements originally performed only with short pulses from spallation sources (SPSS). Adequate information is available to permit meaningful comparisons between CW, SPSS, and LPSS neutron sources. Except where extremely high resolution is required (fraction of a percent), which does require short pulses, it is demonstrated that the LPSS source with a 1000 msec or longer pulse length and a repetition rate of 50 to 60 Hz gives results comparable to those from the 60 MW ILL (CW) source. For many of these applications the shorter pulse is not necessarily a disadvantage, but it is not an advantage over the long pulse system. In one study, the conclusion is that a 5 MW 2000 μsec LPSS source improves the capability for structural biology studies of macromolecules by at least a factor of 5 over that achievable with a high flux reactor. Recent studies have identified the advantages and usefulness of long pulse neutron sources. It is evident that the multiple pulse TRIGA reactor can produce pulses comparable to

Differential pulse voltammetric determination of salbutamol sulfate in syrup pharmaceutical formulation using poly(4-amino-3-hydroxynaphthalene sulfonic acid modified glassy carbon electrode

Directory of Open Access Journals (Sweden)

Meareg Amare

2017-10-01

Full Text Available A new method for determination of salbutamol sulfate has been developed using poly(4-amino-3-hydroxynaphthalene sulfonic acid/GCE. Cyclic voltammetric investigation of the electrochemical behavior of salbutamol sulfate at the polymer modified glassy carbon unveiled electrocatalytic activity of the modifier towards irreversible oxidation of salbutamol sulfate. Dependence of peak current predominantly on scan rate than on square root of scan rate, and peak potential shift with pH demonstrated that oxidation of salbutamol sulfate at the polymer modified electrode follows adsorption reaction kinetics with proton participation.Under optimized solution and differential pulse voltammetric parameters, the oxidative peak current showed linear dependence on salbutamol sulfate concentration in the range 0.2 to 8 μM with method detection limit (3s/m and determination coefficient (R2 of 6.8 × 10−8 M and 0.99786, respectively. Low method detection limit, relatively wide linear range, and recovery results of spiked standard salbutamol sulfate in syrup samples in the range 96.7–98.9% validated the method for determination of salbutamol sulfate in pharmaceutical formulations.Differential pulse voltammetric analysis of salbutamol sulfate syrup formulation for its salbutamol sulfate content revealed 98.8 to 99.3% of the labeled value confirming the applicability of the developed method for determination of salbutamol sulfate in real samples. Keywords: Electrochemistry, Analytical chemistry

General theory for thermal pulses of finite amplitude in nuclear shell-burnings

Energy Technology Data Exchange (ETDEWEB)

Sugimoto, D [Tokyo Univ. (Japan). Coll. of General Education; Fujimoto, M Y

1978-09-01

Theory for thermal pulses of nuclear shell-burning is advanced to include the case of finite amplitude. The aims are to predict the progress of thermal pulse quantitatively and to obtain the peak values of the temperature and nuclear energy generation rate without making detailed numerical computation of stellar structure. In order to attain them the physical processes involved in the progress of the pulse are clarified using the concepts of the flatness of the shell source, which destabilizes nuclear burning, and the effect of radiation pressure, which stabilizes it. It is shown that the progress of the pulse can be predicted quantitatively when the pressure and the gravitational potential of the burning shell are specified for the onset stage of the pulse. The pulse height is determined mainly by the initial pressure; the higher initial pressure results in the higher pulse. Mass dependence is also obtained by approximating the gravitational potential by that of white dwarfs. The initial pressure is the quantity which is determined in the course of evolution preceding the pulse. The theory is shown to give a satisfactory agreement with numerical computations for a wide variety of the preceding evolutions, i.e., both for the case of the core in red giant stars and of the accreting white dwarfs.

Generation of Quasi-Gaussian Pulses Based on Correlation Techniques

Directory of Open Access Journals (Sweden)

POHOATA, S.

2012-02-01

Full Text Available The Gaussian pulses have been mostly used within communications, where some applications can be emphasized: mobile telephony (GSM, where GMSK signals are used, as well as the UWB communications, where short-period pulses based on Gaussian waveform are generated. Since the Gaussian function signifies a theoretical concept, which cannot be accomplished from the physical point of view, this should be expressed by using various functions, able to determine physical implementations. New techniques of generating the Gaussian pulse responses of good precision are approached, proposed and researched in this paper. The second and third order derivatives with regard to the Gaussian pulse response are accurately generated. The third order derivates is composed of four individual rectangular pulses of fixed amplitudes, being easily to be generated by standard techniques. In order to generate pulses able to satisfy the spectral mask requirements, an adequate filter is necessary to be applied. This paper emphasizes a comparative analysis based on the relative error and the energy spectra of the proposed pulses.

Narrowband pulse-enhanced upconversion of chirped broadband pulses

International Nuclear Information System (INIS)

Zhao, Kun; Yuan, Peng; Zhong, Haizhe; Zhang, Dongfang; Zhu, Heyuan; Qian, Liejia; Chen, Liezun; Wen, Shuangchun

2010-01-01

We propose and demonstrate an efficient sum-frequency mixing scheme based on narrowband and chirped broadband pulses. It combines the advantages of wider spectral acceptance bandwidth and of alleviating the temporal walk-off, which are both beneficial to higher conversion efficiency. Chirped sum-frequency pulses at 455 nm with energy up to 360 µJ, corresponding to a conversion efficiency of ∼ 40%, are obtained and the pulses can be compressed to ∼ 110 fs. The sum-frequency mixing scheme may provide a promising route to the efficient generation of deep-ultraviolet femtosecond pulses

Objectives and configuration of the Multiple Pulse Propagation Experiment

International Nuclear Information System (INIS)

Orzechowski, T.J.; Caporaso, G.J.; Chamber, F.W.; Chong, Y.P.; Deadrick, F.J.; Guethlein, G.; Fawley, W.M.; Renbarger, V.L.; Rogers, D. Jr.; Weir, J.T.; Eckstrom, D.; Stalder, K.; Hubbard, R.; Lee, P.

1990-01-01

The Multiple Pulse Propagation Experiment (MPPE) was designed to determine the hose stability properties of an intense relativistic electron beam in a beam generated density channel and to investigate range extension with increasing pulse number in the burst. This experiment used a 10-MeV electron beam generated by the Advanced Test Accelerator (ATA). The electron beam current was expected to be at least 6-kA with an equilibrium radius of 0.5 cm (RMS) in the gas. This last constraint implied an unnormalized, RMS beam emittance of 20 mrad-cm. In order to achieve beam stability against hose, each electron beam pulse had to be tailored in emittance in order to phase mix damp the instability. The initial offsets of the beam were to be kept small in order to prevent a large saturated amplitude. Numerical simulations determined the initial criteria for the emittance profile and initial beam displacements. In order to demonstrate a final density depression of 25% of ambient pressure, at least five pulses with interpulse separation of 1- to 2-ms were specified

Steady State versus Pulsed Tokamak DEMO

Energy Technology Data Exchange (ETDEWEB)

Orsitto, F.P., E-mail: francesco.orsitto@enea.it [Associazione EURATOM-ENEA Unita Tecnica Fusione, Frascati (Italy); Todd, T. [CCFE/Fusion Association, Culham Science Centre, Abingdon (United Kingdom)

2012-09-15

Full text: The present report deals with a Review of problems for a Steady state(SS) DEMO, related argument is treated about the models and the present status of comparison between the characteristics of DEMO pulsed versus a Steady state device.The studied SS DEMO Models (SLIM CS, PPCS model C EU-DEMO, ARIES-RS) are analyzed from the point of view of the similarity scaling laws and critical issues for a steady state DEMO. A comparison between steady state and pulsed DEMO is therefore carried out: in this context a new set of parameters for a pulsed (6 - 8 hours pulse) DEMO is determined working below the density limit, peak temperature of 20 keV, and requiring a modest improvement in the confinement factor(H{sub IPBy2} = 1.1) with respect to the H-mode. Both parameters density and confinement parameter are lower than the DEMO models presently considered. The concept of partially non-inductive pulsed DEMO is introduced since a pulsed DEMO needs heating and current drive tools for plasma stability and burn control. The change of the main parameter design for a DEMO working at high plasma peak temperatures T{sub e} {approx} 35 keV is analyzed: in this range the reactivity increases linearly with temperature, and a device with smaller major radius (R = 7.5 m) is compatible with high temperature. Increasing temperature is beneficial for current drive efficiency and heat load on divertor, being the synchrotron radiation one of the relevant components of the plasma emission at high temperatures and current drive efficiency increases with temperature. Technology and engineering problems are examined including efficiency and availability R&D issues for a high temperature DEMO. Fatigue and creep-fatigue effects of pulsed operations on pulsed DEMO components are considered in outline to define the R&D needed for DEMO development. (author)

Insect disinfestation of pulses by irradiation

International Nuclear Information System (INIS)

Bhuiya, A.D.; Ahmed, M.; Rezaur, R.; Seal, D.R.; Nahar, G.; Islam, M.M.; Islam, M.S.

1985-01-01

Studies were carried out on four varieties of pulses, namely, mosur or lentil (Lens esculenta), mung (Phaseolus aureus), chola or gram (Cirecer aricitinum), and mashkalai (Phaseolus radiatus). Two major burchid betles, Callosobruchus chinensis (L.) and Callosobruchus analis (Fab.), were found to infest different varieties of pulses. Radiation sensitivity of the two pulse beetles was determined at different developmental stages (i.e., eggs, larvae, and pupae). Emergence of adults from eggs totally stopped at a dose of 0.04 kGy. Doses of 0.28 and 0.32 kGy, respectively, were required for complete inhibition of adult emergence from irradiated fourth instar larvae of C. analis and C. chinensis. Studies revealed that the experimental gram was heavily infested (65-91 percent) as compared to other pulses after 8 months of storage in all packaging materials used (gunny bag, gunny bag lined with polyethylene, polyethylene and polyvinyl chloride bags). Mashkalai showed insignificant damage (2-5 percent) by the insects. Reinfestation in the treated products was observed in polyethylene and gunny bags

Developments in Pulsed Neutron Activation for Determination of Water Flow in Pipes

CERN Document Server

Mattsson, H

2003-01-01

In PNA (pulsed neutron activation) it is important that the measured data can be related to the total mass flow. In this thesis two fundamental problems of the measurement technique and data treatment have been investigated: transport/mixing and background radiation. The principle of PNA is to introduce a radioactive substance into a pipe by bombarding fluid in the pipe with neutron pulses. The fluid in the pipe is activated and subsequently transported and mixed with the flow. Gamma radiation emitted from the activity is measured with one or two detectors downstream from the activation point. The time-resolved signal from the detectors is used to calculate the average velocity of the water flow. Due to the short distance between the neutron generator and the pipe the activity in the pipe becomes highly inhomogeneous. The transport and mixing of the activity were simulated using colour which was injected into the flow. It was found that the inhomogeneous activity distribution must be taken into account if the...

Microstructure and surface mechanical properties of pulse electrodeposited nickel

Energy Technology Data Exchange (ETDEWEB)

Ul-Hamid, A., E-mail: anwar@kfupm.edu.sa [Center of Research Excellence in Corrosion (CoRE-C), Research Institute, King Fahd University of Petroleum and Minerals, P.O. Box 1073, Dhahran 31261 (Saudi Arabia); Dafalla, H.; Quddus, A.; Saricimen, H.; Al-Hadhrami, L.M. [Center of Research Excellence in Corrosion (CoRE-C), Research Institute, King Fahd University of Petroleum and Minerals, P.O. Box 1073, Dhahran 31261 (Saudi Arabia)

2011-09-01

The surface of carbon steel was modified by electrochemical deposition of Ni in a standard Watt's bath using dc and pulse plating electrodeposition. The aim was to compare the microstructure and surface mechanical properties of the deposit obtained by both techniques. Materials characterization was conducted using field emission scanning electron microscope fitted with scanning transmission electron detector, atomic force microscope and X-ray diffractometer. Nanoindentation hardness, elastic modulus, adhesion, coefficients of friction and wear rates were determined for both dc and pulse electrodeposits. Experimental results indicate that pulse electrodeposition produced finer Ni grains compared to dc plating. Size of Ni grains increased with deposition. Both dc and pulse deposition resulted in grain growth in preferred (2 0 0) orientation. However, presence of Ni (1 1 1) grains increased in deposits produced by pulse deposition. Pulse plated Ni exhibited higher hardness, creep and coefficient of friction and lower modulus of elasticity compared to dc plated Ni.

International Year of Pulses 2016 | 2016 International Year of Pulses

Science.gov (United States)

the Year in collaboration with Governments, relevant organizations, non-governmental organizations and the composition of pulses Image 4 Wrapping up the International Year of Pulses The 5 key messages to food security Infographic Pulses and climate change International Year of Pulses 2016 The 68th UN

Pulse Width Affects Scalp Sensation of Transcranial Magnetic Stimulation.

Science.gov (United States)

Peterchev, Angel V; Luber, Bruce; Westin, Gregory G; Lisanby, Sarah H

Scalp sensation and pain comprise the most common side effect of transcranial magnetic stimulation (TMS), which can reduce tolerability and complicate experimental blinding. We explored whether changing the width of single TMS pulses affects the quality and tolerability of the resultant somatic sensation. Using a controllable pulse parameter TMS device with a figure-8 coil, single monophasic magnetic pulses inducing electric field with initial phase width of 30, 60, and 120 µs were delivered in 23 healthy volunteers. Resting motor threshold of the right first dorsal interosseus was determined for each pulse width, as reported previously. Subsequently, pulses were delivered over the left dorsolateral prefrontal cortex at each of the three pulse widths at two amplitudes (100% and 120% of the pulse-width-specific motor threshold), with 20 repetitions per condition delivered in random order. After each pulse, subjects rated 0-to-10 visual analog scales for Discomfort, Sharpness, and Strength of the sensation. Briefer TMS pulses with amplitude normalized to the motor threshold were perceived as slightly more uncomfortable than longer pulses (with an average 0.89 point increase on the Discomfort scale for pulse width of 30 µs compared to 120 µs). The sensation of the briefer pulses was felt to be substantially sharper (2.95 points increase for 30 µs compared to 120 µs pulse width), but not stronger than longer pulses. As expected, higher amplitude pulses increased the perceived discomfort and strength, and, to a lesser degree the perceived sharpness. Our findings contradict a previously published hypothesis that briefer TMS pulses are more tolerable. We discovered that the opposite is true, which merits further study as a means of enhancing tolerability in the context of repetitive TMS. Copyright © 2016 Elsevier Inc. All rights reserved.

APPLICATION OF PULSE COMBUSTION TO INCINERATION OF LIQUID HAZARDOUS WASTE

Science.gov (United States)

The report gives results of a study to determine the effect of acoustic pulsations on the steady-state operation of a pulse combustor burning liquid hazardous waste. A horizontal tunnel furnace was retrofitted with a liquid injection pulse combustor that burned No. 2 fuel oil. Th...

Probabilistic SSME blades structural response under random pulse loading

Science.gov (United States)

Shiao, Michael; Rubinstein, Robert; Nagpal, Vinod K.

1987-01-01

The purpose is to develop models of random impacts on a Space Shuttle Main Engine (SSME) turbopump blade and to predict the probabilistic structural response of the blade to these impacts. The random loading is caused by the impact of debris. The probabilistic structural response is characterized by distribution functions for stress and displacements as functions of the loading parameters which determine the random pulse model. These parameters include pulse arrival, amplitude, and location. The analysis can be extended to predict level crossing rates. This requires knowledge of the joint distribution of the response and its derivative. The model of random impacts chosen allows the pulse arrivals, pulse amplitudes, and pulse locations to be random. Specifically, the pulse arrivals are assumed to be governed by a Poisson process, which is characterized by a mean arrival rate. The pulse intensity is modelled as a normally distributed random variable with a zero mean chosen independently at each arrival. The standard deviation of the distribution is a measure of pulse intensity. Several different models were used for the pulse locations. For example, three points near the blade tip were chosen at which pulses were allowed to arrive with equal probability. Again, the locations were chosen independently at each arrival. The structural response was analyzed both by direct Monte Carlo simulation and by a semi-analytical method.

Programmable pulse generator

International Nuclear Information System (INIS)

Xue Zhihua; Lou Binqiao; Duan Xiaohui

2002-01-01

The author introduces the design of programmable pulse generator that is based on a micro-controller and controlled by RS232 interface of personal computer. The whole system has good stability. The pulse generator can produce TTL pulse and analog pulse. The pulse frequency can be selected by EPLD. The voltage amplitude and pulse width of analog pulse can be adjusted by analog switches and digitally-controlled potentiometers. The software development tools of computer is National Instruments LabView5.1. The front panel of this virtual instrumentation is intuitive and easy-to-use. Parameters can be selected and changed conveniently by knob and slide

Singular Value Decomposition Method to Determine Distance Distributions in Pulsed Dipolar Electron Spin Resonance.

Science.gov (United States)

Srivastava, Madhur; Freed, Jack H

2017-11-16

Regularization is often utilized to elicit the desired physical results from experimental data. The recent development of a denoising procedure yielding about 2 orders of magnitude in improvement in SNR obviates the need for regularization, which achieves a compromise between canceling effects of noise and obtaining an estimate of the desired physical results. We show how singular value decomposition (SVD) can be employed directly on the denoised data, using pulse dipolar electron spin resonance experiments as an example. Such experiments are useful in measuring distances and their distributions, P(r) between spin labels on proteins. In noise-free model cases exact results are obtained, but even a small amount of noise (e.g., SNR = 850 after denoising) corrupts the solution. We develop criteria that precisely determine an optimum approximate solution, which can readily be automated. This method is applicable to any signal that is currently processed with regularization of its SVD analysis.

Single- and multi-pulse femtosecond laser ablation of optical filter materials

International Nuclear Information System (INIS)

Krueger, J.; Lenzner, M.; Martin, S.; Lenner, M.; Spielmann, C.; Fiedler, A.; Kautek, W.

2003-01-01

Ablation experiments employing Ti:sapphire laser pulses with durations from 30 to 340 fs (centre wavelength 800 nm, repetition rate 1 kHz) were performed in air. Absorbing filters (Schott BG18 and BG36) served as targets. The direct focusing technique was used under single- and multi-pulse irradiation conditions. Ablation threshold fluences were determined from a semi-logarithmic plot of the ablation crater diameter versus laser fluence. The threshold fluence decreases for a shorter pulse duration and an increasing number of pulses. The multi-pulse ablation threshold fluences are similar to those of undoped glass material (∼1 J cm -2 ). That means that the multi-pulse ablation threshold is independent on the doping level of the filters. For more than 100 pulses per spot and all pulse durations applied, the threshold fluence is practically constant. This leads to technically relevant ablation threshold values

Pulsed dc self-sustained magnetron sputtering

International Nuclear Information System (INIS)

Wiatrowski, A.; Posadowski, W. M.; Radzimski, Z. J.

2008-01-01

The magnetron sputtering has become one of the commonly used techniques for industrial deposition of thin films and coatings due to its simplicity and reliability. At standard magnetron sputtering conditions (argon pressure of ∼0.5 Pa) inert gas particles (necessary to sustain discharge) are often entrapped in the deposited films. Inert gas contamination can be eliminated during the self-sustained magnetron sputtering (SSS) process, where the presence of the inert gas is not a necessary requirement. Moreover the SSS process that is possible due to the high degree of ionization of the sputtered material also gives a unique condition during the transport of sputtered particles to the substrate. So far it has been shown that the self-sustained mode of magnetron operation can be obtained using dc powering (dc-SSS) only. The main disadvantage of the dc-SSS process is its instability related to random arc formation. In such case the discharge has to be temporarily extinguished to prevent damaging both the magnetron source and power supply. The authors postulate that pulsed powering could protect the SSS process against arcs, similarly to reactive pulsed magnetron deposition processes of insulating thin films. To put this concept into practice, (i) the high enough plasma density has to be achieved and (ii) the type of pulsed powering has to be chosen taking plasma dynamics into account. In this article results of pulsed dc self-sustained magnetron sputtering (pulsed dc-SSS) are presented. The planar magnetron equipped with a 50 mm diameter and 6 mm thick copper target was used during the experiments. The maximum target power was about 11 kW, which corresponded to the target power density of ∼560 W/cm 2 . The magnetron operation was investigated as a function of pulse frequency (20-100 kHz) and pulse duty factor (50%-90%). The discharge (argon) extinction pressure level was determined for these conditions. The plasma emission spectra (400-410 nm range) and deposition

Effects of pulse-to-pulse residual species on discharges in repetitively pulsed discharges through packed bed reactors

Science.gov (United States)

Kruszelnicki, Juliusz; Engeling, Kenneth W.; Foster, John E.; Kushner, Mark J.

2016-09-01

Atmospheric pressure dielectric barrier discharges (DBDs) sustained in packed bed reactors (PBRs) are being investigated for conversion of toxic and waste gases, and CO2 removal. These discharges are repetitively pulsed having varying flow rates and internal geometries, which results in species from the prior pulse still being in the discharge zone at the time the following discharge pulse occurs. A non-negligible residual plasma density remains, which effectively acts as preionization. This residual charge changes the discharge properties of subsequent pulses, and may impact important PBR properties such as chemical selectivity. Similarly, the residual neutral reactive species produced during earlier pulses will impact the reaction rates on subsequent pulses. We report on results of a computational investigation of a 2D PBR using the plasma hydrodynamics simulator nonPDPSIM. Results will be discussed for air flowing though an array of dielectric rods at atmospheric pressure. The effects of inter-pulse residual species on PBR discharges will be quantified. Means of controlling the presence of residual species in the reactor through gas flow rate, pulse repetition, pulse width and geometry will be described. Comparisons will be made to experiments. Work supported by US DOE Office of Fusion Energy Science and the National Science Foundation.

Pulsed-linac synchronization using an embedded micro-controller

International Nuclear Information System (INIS)

Craig, S.R.; Alexander, S.B.; West, R.J.; Simpson, M.P.

1992-01-01

A Master Timing Generator (MTG) was developed using a single Motorola MC68332 embedded micro-controller. The MTG produces electrical synchronization pulses that coordinate the action of all pulsed subsystems and the acquisition of pulsed data. Pulse width and delay-offset of each of the 13 output channels can be changed on-line. The MTG is interfaced with a GE Series-Six Programmable Logic Controller (PLC), which coordinates overall control of the IMPELA linac. Serial communications are used between the PLC and the MTG. The PLC needs only to transmit data to define the pulse repetition rate, the beam pulse width, and the subsystems that should be active. The MTG determines the widths and relative delays required to achieve the requested beam pulse-width. Changes in width and repetition rate are effected using a smooth ramp to avoid power-demand transients. All MTG timing requirements are met with the current implementation, having the following characteristics: 1 Hz ≤ repetition rate ≤ 500 Hz with ±1% resolution, 12 μs ≤ width ≤ 1000 μs in 1 μs steps, and a delay-offset range of 4.5 ms in 1 μs steps. (Author) (4 figs., 5 refs.)

The effect of positive end-expiratory pressure on pulse pressure ...

African Journals Online (AJOL)

The effect of positive end-expiratory pressure on pulse pressure variation. FJ Smith, M Geyser, I Schreuder, PJ Becker. Abstract. Objectives: To determine the effect of different levels of positive end-expiratory pressure (PEEP) on pulse pressure variation (PPV). Design: An observational study. Setting: Operating theatres of a ...

The determination of reactivity at a compact core with low absorption reflector by means of the pulsed neutron method

International Nuclear Information System (INIS)

Hecker, R.; Drueke, V.; Ahmad, S.K.; Kacmary, S.; Paul, N.

1976-09-01

Pulsed measurements at a compact critical facility with low absorption reflector are described. By a number of such measurements at different points of the system a proper value for the reactivity can be determined, which allows a meaningful comparison with values calculated by static computer codes in spite of the presence of kinetic distortion in the system. A modified area ratio method is developed and applied to the measurements; furthermore a method is shown, which allows to suppress in this systems the kinetic distortion in the fundamental mode by application of special detectors. (orig.) [de

SBS pulse compression for excimer inertial fusion energy drivers

Energy Technology Data Exchange (ETDEWEB)

Linford, G.J. [TRW Space and Electronics Group, Redondo Beach, CA (United States). Space and Technology Div.

1994-12-31

A key requirement for the development of commercial fusion power plants utilizing inertial confinement fusion (ICF) as a source of thermonuclear power is the availability of reliable, efficient laser drivers. These laser drivers must be capable of delivering UV optical pulses having energies of the order of 5MJ to cryogenic deuterium-tritium (D/T) ICF targets. The current requirements for laser ICF target irradiation specify the laser wavelength, {lambda} ca. 250 nm, pulse duration, {tau}{sub p} ca. 6 ns, bandwidth, {Delta}{lambda} ca. 0.1 nm, polarization state, etc. Excimer lasers are a leading candidate to fill these demanding ICF driver requirements. However, since excimer lasers are not storage lasers, the excimer laser pulse duration, {tau}{sub pp}, is determined primarily by the length of the excitation pulse delivered to the excimer laser amplifier. Pulsed power associated with efficiently generating excimer laser pulses has a time constant, {tau}{sub pp} which falls in the range, 30 {tau}{sub p}<{tau}{sub pp}<100{tau}{sub p}. As a consequence, pulse compression is needed to convert the long excimer laser pulses to pulses of duration {tau}{sub p}. These main ICF driver pulses require, in addition, longer, lower power precursor pulses delivered to the ICF target before the arrival of the main pulse. Although both linear and non-linear optical (NLO) pulse compression techniques have been developed, computer simulations have shown that a ``chirped,`` self-seeded, stimulated Brillouin scattering (SBS) pulse compressor cell using SF{sub 6} at a density, {rho} ca. 1 amagat can efficiently compress krypton fluoride (KrF) laser pulses at {lambda}=248 nm. In order to avoid the generation of output pulses substantially shorter than {tau}{sub p}, the optical power in the chirped input SBS ``seed`` beams was ramped. Compressed pulse conversion efficiencies of up to 68% were calculated for output pulse durations of {tau}{sub p} ca. ns.

Thermodynamical aspects of pulse tubes

NARCIS (Netherlands)

Waele, de A.T.A.M.; Steijaert, P.P.; Gijzen, J.

1997-01-01

The cooling power of cryocoolers is determined by the work done by the compressor and the entropy produced by the irreversible processes in the various components of the system. In this paper we discuss the thermodynamics of pulse tubes, but many of the relationships are equally valid for other

Integrable discretizations of the short pulse equation

International Nuclear Information System (INIS)

Feng Baofeng; Maruno, Ken-ichi; Ohta, Yasuhiro

2010-01-01

In this paper, we propose integrable semi-discrete and full-discrete analogues of the short pulse (SP) equation. The key construction is the bilinear form and determinant structure of solutions of the SP equation. We also give the determinant formulas of N-soliton solutions of the semi-discrete and full-discrete analogues of the SP equations, from which the multi-loop and multi-breather solutions can be generated. In the continuous limit, the full-discrete SP equation converges to the semi-discrete SP equation, and then to the continuous SP equation. Based on the semi-discrete SP equation, an integrable numerical scheme, i.e. a self-adaptive moving mesh scheme, is proposed and used for the numerical computation of the short pulse equation.

Chemical dosimetry of linac electron pulse with nitrous oxide

International Nuclear Information System (INIS)

Nanba, Hideki; Shinsaka, Kyoji; Hatano, Yoshihiko; Yagi, Masuo; Shiokawa, Takanobu.

1975-01-01

Absorption dose, dose rate and the reproducibility of intensity in each pulse of the electron beam pulses from a Linac (42 MeV, 3μsec) have been determined by applying nitrous oxide chemical dosimetry, in order to obtain the fundamental data required for radiation chemistry researches with the Linac. Nitrous oxide is used as a chemical dosimeter because it is known that it decomposed through radiation ensures easy detection and the determination of quantity of the decomposed product, nitrogen, which is stable, and presents linear relationship between absorption dose and produced quantity over the wide dose-rate range. Irradiation cells used for the experiment were cylindrical ones made of hard molybdenum glass. Irradiated samples were fractionated with liquid nitrogen, and separated and determined with a gas chromatograph. Details on the experimental results and their examination are described at the end. They include absorption dose of 1x10 16 eV/g per pulse, dose rate of 3x10 21 eV/g, sec and intensity reproducibility of +- 20%. (Wakatsuki, Y.)

Photoionization of atoms and molecules by intense EUV-FEL pulses and FEL seeded by high-order harmonic of ultrashort laser pulses

International Nuclear Information System (INIS)

Iwasaki, Atsushi; Owada, Shigeki; Yamanouchi, Kaoru; Sato, Takahiro; Nagasono, Mitsuru; Yabashi, Makina; Ishikawa, Tetsuya; Togashi, Tadashi; Takahashi, Eiji J.; Midorikawa, Katsumi; Aoyama, Makoto; Yamakawa, Koichi; Kannari, Fumihiko; Yagishita, Akira

2012-01-01

The advantages of SPring-8 Compact SASE Source as a light source for spectroscopic measurements in the extreme ultraviolet (EUV) wavelength region are introduced by referring to our recent study of non-linear photoionization processes of He, in which the absolute two-photon ionization cross sections of He at four different wavelengths in the 54 - 62 nm region were determined using intense pulses of the free-election laser (FEL). In addition, our recent effort to generate intense full-coherent EUV light pulses are introduced, in which significant amplification of the 13th harmonic of ultrashort laser pulses at 800 nm was achieved by FEL seeded with the 13th harmonic. (author)

[Determination of calcium, magnesium and potassium in nurtured cell by AAS with quick-pulsed nebulization technique and NaOH base digestion].

Science.gov (United States)

Shi, C; Gao, S; Gun, S

1997-06-01

The sample is digested with 6% NaOH solution and an amount of 50 microl is used for protein content analysis by the method of Comassie Brilliant Blue G250, the residual is diluted with equal 0.4% Lathanurm-EDTA solution. Its Calcium magensium and potassium content are determined by AAS. With quick-pulsed nebulization technique. When a self-made micro-sampling device is used, 20microl of sample volume is needed and it is only the 1/10 approximately 1/20 of the sample volume required for conventional determination. Sensitivity, precision and rate of recovery agree well with those using regular wet ashing method.

Determination of Heritage SSME Pogo Suppressor Resistance and Inertance from Waterflow Pulse Testing

Science.gov (United States)

McDougal, Chris; Eberhart, Chad; Lee, Erik

2016-01-01

Waterflow tests of a heritage Space Shuttle Main Engine pogo suppressor were performed to experimentally quantify the resistance and inertance provided by the suppressor. Measurements of dynamic pressure and flow rate in response to pulsing flow were made throughout the test loop. A unique system identification methodology combined all sensor measurements with a one-dimensional perturbational flow model of the complete water flow loop to spatially translate physical measurements to the device under test. Multiple techniques were then employed to extract the effective resistance and inertance for the pogo suppressor. Parameters such as steady flow rate, perturbational flow rate magnitude, and pulse frequency were investigated to assess their influence on the behavior of the pogo suppressor dynamic response. These results support validation of the RS-25 pogo suppressor performance for use on the Space Launch System Core Stage.

Characterizations of double pulsing in neutron multiplicity and coincidence counting systems

Energy Technology Data Exchange (ETDEWEB)

Koehler, Katrina E., E-mail: kkoehler@lanl.gov [Los Alamos National Laboratory, P. O. Box 1663, Los Alamos, NM 87545 (United States); Henzl, Vladimir [Los Alamos National Laboratory, P. O. Box 1663, Los Alamos, NM 87545 (United States); Croft, Stephen S. [Oak Ridge National Laboratory, 1 Bethel Valley Rd, Oak Ridge, TN 37831 (United States); Henzlova, Daniela; Santi, Peter A. [Los Alamos National Laboratory, P. O. Box 1663, Los Alamos, NM 87545 (United States)

2016-10-01

Passive neutron coincidence/multiplicity counters are subject to non-ideal behavior, such as double pulsing and dead time. It has been shown in the past that double-pulsing exhibits a distinct signature in a Rossi-alpha distribution, which is not readily noticed using traditional Multiplicity Shift Register analysis. However, it has been assumed that the use of a pre-delay in shift register analysis removes any effects of double pulsing. In this work, we use high-fidelity simulations accompanied by experimental measurements to study the effects of double pulsing on multiplicity rates. By exploiting the information from the double pulsing signature peak observable in the Rossi-alpha distribution, the double pulsing fraction can be determined. Algebraic correction factors for the multiplicity rates in terms of the double pulsing fraction have been developed. We discuss the role of these corrections across a range of scenarios.

Characteristics of bipolar-pulse generator for intense pulsed heavy ion beam acceleration

International Nuclear Information System (INIS)

Igawa, K.; Tomita, T.; Kitamura, I.; Ito, H.; Masugata, K.

2006-01-01

Intense pulsed heavy ion beams are expected to be applied to the implantation technology for semiconductor materials. In the application it is very important to purify the ion beam. In order to improve the purity of an intense pulsed ion beams we have proposed a new type of pulsed ion beam accelerator named 'bipolar pulse accelerator (BPA)'. A prototype of the experimental system has been developed to perform proof of principle experiments of the accelerator. A bipolar pulse generator has been designed for the generation of the pulsed ion beam with the high purity via the bipolar pulse acceleration and the electrical characteristics of the generator were evaluated. The production of the bipolar pulse has been confirmed experimentally. (author)

Neutronics of pulsed spallation neutron sources

CERN Document Server

Watanabe, N

2003-01-01

Various topics and issues on the neutronics of pulsed spallation neutron sources, mainly for neutron scattering experiments, are reviewed to give a wide circle of readers a better understanding of these sources in order to achieve a high neutronic performance. Starting from what neutrons are needed, what the spallation reaction is and how to produce slow-neutrons more efficiently, the outline of the target and moderator neutronics are explained. Various efforts with some new concepts or ideas have already been devoted to obtaining the highest possible slow-neutron intensity with desired pulse characteristics. This paper also reviews the recent progress of such efforts, mainly focused on moderator neutronics, since moderators are the final devices of a neutron source, which determine the source performance. Various governing parameters for neutron-pulse characteristics such as material issues, geometrical parameters (shape and dimensions), the target-moderator coupling scheme, the ortho-para-hydrogen ratio, po...

Development of an Analytical Protocol for Determination of Cyanide in Human Biological Samples Based on Application of Ion Chromatography with Pulsed Amperometric Detection

OpenAIRE

Jaszczak, Ewa; Ruman, Marek; Narkowicz, Sylwia; Namieśnik, Jacek; Polkowska, Żaneta

2017-01-01

A simple and accurate ion chromatography (IC) method with pulsed amperometric detection (PAD) was proposed for the determination of cyanide ion in urine, sweat, and saliva samples. The sample pretreatment relies on alkaline digestion and application of Dionex OnGuard II H cartridge. Under the optimized conditions, the method showed good linearity in the range of 1–100 μg/L for urine, 5–100 μg/L for saliva, and 3–100 μg/L for sweat samples with determination coefficients (R) > 0.992. Low detec...

Forensic applications of {sup 14}C bomb-pulse dating

Energy Technology Data Exchange (ETDEWEB)

Zoppi, U. E-mail: ugo@ansto.gov.au; Skopec, Z.; Skopec, J.; Jones, G.; Fink, D.; Hua, Q.; Jacobsen, G.; Tuniz, C.; Williams, A

2004-08-01

After a brief review of the basics of {sup 14}C bomb-pulse dating, this paper presents two unique forensic applications. Particular attention is dedicated to the use of the {sup 14}C bomb-pulse to establish the time of harvest of illicit drugs such as heroin and opium. Preliminary measurements of {sup 14}C concentrations in milligram samples taken from seized drugs are presented. {sup 14}C bomb-pulse dating can determine whether drug distribution originates from stockpiles or recent manufacture, and support the action of law enforcement authorities against criminal organisations involved in drug trafficking. In addition, we describe the dating of wine vintages for a number of authenticated single label vintage red wines from the Barossa Valley - South Australia. Our results show that radiocarbon dating can be used to accurately determine wine vintages and therefore reveal the addition of unrelated materials of natural and synthetic origin.

Development of the pulse transformer for NLC klystron pulse modulator

International Nuclear Information System (INIS)

Akemoto, M.; Gold, S.; Koontz, R.; Krasnykh, A.

1997-05-01

We have studied a conventional pulse transformer for the NLC klystron pulse modulator. The transformer has been analyzed using a simplified lumped circuit model. It is found that a fast rise time requires low leakage inductance and low distributed capacitance and can be realized by reducing the number of secondary turns, but it produces larger pulse droop and core size. After making a tradeoff among these parameters carefully, a conventional pulse transformer with a rise time of 250ns and pulse droop of 3.6% has been designed and built. The transmission characteristics and pulse time-response were measured. The data were compared with the model. The agreement with the model was good when the measured values were used in the model simulation. The results of the high voltage tests are also presented

Dynamic Characterization of Fiber Optical Chirped Pulse Amplification for Sub-ps Pulses

DEFF Research Database (Denmark)

Cristofori, Valentina; Lali-Dastjerdi, Zohreh; Rishøj, Lars Søgaard

2013-01-01

We investigate experimentally the propagation of sub-picosecond pulses in fiber optical parametric chirped pulse amplifiers, showing a significant broadening of the pulses from 450 fs up to 720 fs due to dispersion and self-phase modulation.......We investigate experimentally the propagation of sub-picosecond pulses in fiber optical parametric chirped pulse amplifiers, showing a significant broadening of the pulses from 450 fs up to 720 fs due to dispersion and self-phase modulation....

Response of larval sea lampreys (Petromyzon marinus) to pulsed DC electrical stimuli in laboratory experiments

Science.gov (United States)

Bowen, Anjanette K.; Weisser, John W.; Bergstedt, Roger A.; Famoye, Felix

2003-01-01

Four electrical factors that are used in pulsed DC electrofishing for larval sea lampreys (Petromyzon marinus) were evaluated in two laboratory studies to determine the optimal values to induce larval emergence over a range of water temperatures and conductivities. Burrowed larvae were exposed to combinations of pulsed DC electrical factors including five pulse frequencies, three pulse patterns, and two levels of duty cycle over a range of seven voltage gradients in two separate studies conducted at water temperatures of 10, 15, and 20°C and water conductivities of 25, 200, and 900 μS/cm. A four-way analysis of variance was used to determine significant (α = 0.05) influences of each electrical factor on larval emergence. Multiple comparison tests with Bonferroni adjustments were used to determine which values of each factor resulted in significantly higher emergence at each temperature and conductivity. Voltage gradient and pulse frequency significantly affected emergence according to the ANOVA model at each temperature and conductivity tested. Duty cycle and pulse pattern generally did not significantly influence the model. Findings suggest that a setting of 2.0 V/cm, 3 pulses/sec, 10% duty, and 2:2 pulse pattern seems the most promising in waters of medium conductivity and across a variety of temperatures. This information provides a basis for understanding larval response to pulsed DC electrofishing gear factors and identifies electrofisher settings that show promise to increase the efficiency of the gear during assessments for burrowed sea lamprey larvae.

Polytetrafluorethylene film-based liquid-three phase micro extraction coupled with differential pulse voltammetry for the determination of atorvastatin calcium.

Science.gov (United States)

Ensafi, Ali A; Khoddami, Elaheh; Rezaei, Behzad

2013-01-01

In this paper, we describe a new combination method based on polytetrafluorethylene (PTFE) film-based liquid three-phase micro extraction coupled with differential pulse voltammetry (DPV) for the micro extraction and quantification of atorvastatin calcium (ATC) at the ultra-trace level. Different factors affecting the liquid-three phases micro extraction of atorvastatin calcium, including organic solvent, pH of the donor and acceptor phases, concentration of salt, extraction time, stirring rate and electrochemical factors, were investigated, and the optimal extraction conditions were established. The final stable signal was achieved after a 50 min extraction time, which was used for analytical applications. An enrichment factor of 21 was achieved, and the relative standard deviation (RSD) of the method was 4.5% (n = 4). Differential pulse voltammetry exhibited two wide linear dynamic ranges of 20.0-1000.0 pmol L(-1) and 0.001-11.0 µmol L(-1) of ATC. The detection limit was found to be 8.1 pmol L(-1) ATC. Finally, the proposed method was used as a new combination method for the determination of atorvastatin calcium in real samples, such as human urine and plasma.

Charge collection efficiency in ionization chambers exposed to electron beams with high dose per pulse

Energy Technology Data Exchange (ETDEWEB)

Laitano, R F [Istituto Nazionale di Metrologia delle Radiazioni Ionizzanti, ENEA Centro Ricerche Casaccia, c.p. 2400 Rome (Italy); Guerra, A S [Istituto Nazionale di Metrologia delle Radiazioni Ionizzanti, ENEA Centro Ricerche Casaccia, c.p. 2400 Rome (Italy); Pimpinella, M [Istituto Nazionale di Metrologia delle Radiazioni Ionizzanti, ENEA Centro Ricerche Casaccia, c.p. 2400 Rome (Italy); Caporali, C [Istituto Nazionale di Metrologia delle Radiazioni Ionizzanti, ENEA Centro Ricerche Casaccia, c.p. 2400 Rome (Italy); Petrucci, A [A.C.O. S. Filippo Neri, U.O. Fisica Sanitaria, Rome (Italy)

2006-12-21

The correction for charge recombination was determined for different plane-parallel ionization chambers exposed to clinical electron beams with low and high dose per pulse, respectively. The electron energy was nearly the same (about 7 and 9 MeV) for any of the beams used. Boag's two-voltage analysis (TVA) was used to determine the correction for ion losses, k{sub s}, relevant to each chamber considered. The presence of free electrons in the air of the chamber cavity was accounted for in determining k{sub s} by TVA. The determination of k{sub s} was made on the basis of the models for ion recombination proposed in past years by Boag, Hochhaeuser and Balk to account for the presence of free electrons. The absorbed dose measurements in both low-dose-per-pulse (less than 0.3 mGy per pulse) and high-dose-per-pulse (20-120 mGy per pulse range) electron beams were compared with ferrous sulphate chemical dosimetry, a method independent of the dose per pulse. The results of the comparison support the conclusion that one of the models is more adequate to correct for ion recombination, even in high-dose-per-pulse conditions, provided that the fraction of free electrons is properly assessed. In this respect the drift velocity and the time constant for attachment of electrons in the air of the chamber cavity are rather critical parameters because of their dependence on chamber dimensions and operational conditions. Finally, a determination of the factor k{sub s} was also made by zero extrapolation of the 1/Q versus 1/V saturation curves, leading to the conclusion that this method does not provide consistent results in high-dose-per-pulse beams.

Simultaneous determination of environmental α-radionuclides using liquid scintillation counting combined with time interval analysis (TIA) and pulse shape discrimination (PSD)

International Nuclear Information System (INIS)

Hashimoto, T.; Sato, K.; Yoneyama, Y.; Fukuyama, N.

1997-01-01

Some improvements of the detection sensitivity in pulse time interval analysis (TIA) based on selective extraction of successively α-α correlated decay events within millisecond order from random or background events, were established by the utilization of PSD, to reject β/γ-pulses from α-ones and a simple chemical procedure of radium separation, together with the use of well resolved scintillator. By applying the PSD, the contribution of β-decay events was completely eliminated in both the α-spectra and the TIA distribution curves as well as the improvement into clear energy resolution and the enhancement of detection sensitivity for the TIA. As a result, the TIA and α-spectrometric analysis of 226 Ra-extract showed the existence of 223 Ra (Ac-series) and β/α-correlated events with correlated life (due to 0.16 ms due to 214 Bi(β)-> 214 Po(α)->) along with a singly well resolved α-peak to be useful for the determination of 226 Ra (U-series). The difference of half-lives (145 and 1.78 ms) due to 216 Po and 215 Po (direct daughters of 224 Ra for Th-series and 223 Ra for Ac-series, respectively) was also proven for the possibility of the simultaneous determination of both correlated events by using the TIA/PSD combined with chemical separation and liquid scintillation counting method. Finally, the simultaneous determination of three natural decay series, which include U-, Th- and Ac-series nuclides, have been conveniently carried out for some environmental samples using the present method combined with 225 Ra yield tracer (Np-series). (author)

Self-action of few-cycle pulses in a dispersive medium

International Nuclear Information System (INIS)

Balakin, A. A.; Litvak, A. G.; Mironov, V. A.; Skobelev, S. A.

2009-01-01

Basing on the nonlinear wave equation as the reflection-free approximation, we study the self-focusing dynamics of laser pulses under rather general assumptions about media dispersion. The methods for qualitative investigation of the self-action dynamics of ultrashort pulses are developed. It is shown that a new effect here is steepening of the longitudinal pulse profile, which is determined by the dependence of group velocity on the amplitude. Results of numerical simulation in media without dispersion and with anomalous dispersion confirm the conclusion about outrunning formation of a shock wave during pulse self-focusing. The formation of a power spectrum of the field, which is characteristic for a shock wave, is retained also when medium ionization is taken into account. In the case of a normal-dispersion medium, nonlinear dispersion leads to a violation of the symmetry in the longitudinal splitting of the pulse in the process of self-focusing. The possibility of tuning of the optical-pulse frequency into the short-wave area is shown for the pulse self-action near the zero-dispersion point.

Petawatt pulsed-power accelerator

Science.gov (United States)

Stygar, William A.; Cuneo, Michael E.; Headley, Daniel I.; Ives, Harry C.; Ives, legal representative; Berry Cottrell; Leeper, Ramon J.; Mazarakis, Michael G.; Olson, Craig L.; Porter, John L.; Wagoner; Tim C.

2010-03-16

A petawatt pulsed-power accelerator can be driven by various types of electrical-pulse generators, including conventional Marx generators and linear-transformer drivers. The pulsed-power accelerator can be configured to drive an electrical load from one- or two-sides. Various types of loads can be driven; for example, the accelerator can be used to drive a high-current z-pinch load. When driven by slow-pulse generators (e.g., conventional Marx generators), the accelerator comprises an oil section comprising at least one pulse-generator level having a plurality of pulse generators; a water section comprising a pulse-forming circuit for each pulse generator and a level of monolithic triplate radial-transmission-line impedance transformers, that have variable impedance profiles, for each pulse-generator level; and a vacuum section comprising triplate magnetically insulated transmission lines that feed an electrical load. When driven by LTD generators or other fast-pulse generators, the need for the pulse-forming circuits in the water section can be eliminated.

Noninvasive pulse contour analysis for determination of cardiac output in patients with chronic heart failure.

Science.gov (United States)

Roth, Sebastian; Fox, Henrik; Fuchs, Uwe; Schulz, Uwe; Costard-Jäckle, Angelika; Gummert, Jan F; Horstkotte, Dieter; Oldenburg, Olaf; Bitter, Thomas

2018-05-01

Determination of cardiac output (CO) is essential in diagnosis and management of heart failure (HF). The gold standard to obtain CO is invasive assessment via thermodilution (TD). Noninvasive pulse contour analysis (NPCA) is supposed as a new method of CO determination. However, a validation of this method in HF is pending and performed in the present study. Patients with chronic-stable HF and reduced left ventricular ejection fraction (LVEF ≤ 45%; HF-REF) underwent right heart catheterization including TD. NPCA using the CNAP Monitor (V5.2.14, CNSystems Medizintechnik AG) was performed simultaneously. Three standardized TD measurements were compared with simultaneous auto-calibrated NPCA CO measurements. In total, 84 consecutive HF-REF patients were enrolled prospectively in this study. In 4 patients (5%), TD was not successful and for 22 patients (26%, 18 with left ventricular assist device), no NPCA signal could be obtained. For the remaining 58 patients, Bland-Altman analysis revealed a mean bias of + 1.92 L/min (limits of agreement ± 2.28 L/min, percentage error 47.4%) for CO. With decreasing cardiac index, as determined by the gold standard of TD, there was an increasing gap between CO values obtained by TD and NPCA (r = - 0.75, p TD-CI classified 52 (90%) patients to have a reduced CI (REF patients, auto-calibrated NPCA systematically overestimates CO with decrease in cardiac function. Therefore, to date, NPCA cannot be recommended in this cohort.

Asymptotic strength of thermal pulses in the helium shell burning

Energy Technology Data Exchange (ETDEWEB)

Fujimoto, M Y [Niigata Univ. (Japan); Sugimoto, D

1979-03-01

Secular growth in the strength of the recurrent thermal pulses of helium shell burning is discussed for the purpose of determining its asymptotic strength. It is shown that the pulse grows stronger if the helium zone has been cooled more before the initiation of the pulse. The secular growth of the pulse is related with the increasing degree of cooling. Thermal pulses are computed for an initial model corresponding to the maximum possible cooling, i.e., for a model in which the steady-state entropy distribution was realized in the helium zone. Such thermal pulses are shown to give an upper bound to the asymptotic strength, which is close enough to the asymptotic strength itself for relatively large core masses. Numerical results are given for the core mass of 1.07 M sub(sun), for which the asymptotic strength is found to be 9 x 10/sup 6/ L sub(sun). Thermal pulses are also computed for an initial model which has been cooled artificially more than the steady-state model. The first pulse results in a much greater strength than in the normal model, but a later pulse approaches the normal asymptotic value. Such models are also discussed in relation to the shell flashes on accreting white dwarfs.

Disinfection and toxicological assessments of pulsed UV and pulsed-plasma gas-discharge treated-water containing the waterborne protozoan enteroparasite Cryptosporidium parvum.

Science.gov (United States)

Hayes, Jennifer; Kirf, Dominik; Garvey, Mary; Rowan, Neil

2013-09-01

We report for the first time on the comparative use of pulsed-plasma gas-discharge (PPGD) and pulsed UV light (PUV) for the novel destruction of the waterborne enteroparasite Cryptosporidium parvum. It also describes the first cyto-, geno- and ecotoxicological assays undertaken to assess the safety of water decontaminated using PPGD and PUV. During PPGD treatments, the application of high voltage pulses (16 kV, 10 pps) to gas-injected water (N2 or O2, flow rate 2.5L/min) resulted in the formation of a plasma that generated free radicals, ultraviolet light, acoustic shock waves and electric fields that killed ca. 4 log C. parvum oocysts in 32 min exposure. Findings showed that PPGD-treated water produced significant cytotoxic properties (as determined by MTT and neutral red assays), genotoxic properties (as determined by comet and Ames assays), and ecotoxic properties (as determined by Microtox™, Thamnotox™ and Daphnotox™ assays) that are representative of different trophic levels in aquatic environment (pozone (0.8 mg/L) and/or dissociated nitric and nitrous acid that contributed to the observed disinfection and toxicity. Chemical analysis of PPGD-treated water revealed increasing levels of electrode metals that were present at ≤ 30 times the tolerated respective values for EU drinking water. PUV-treated water did not exhibit any toxicity and was shown to be far superior to that of PPGD for killing C. parvum oocysts taking only 90 s of pulsing [UV dose of 6.29 μJ/cm(2)] to produce a 4-log reduction compared to a similar reduction level achieved after 32min PPGD treatment as determined by combined in vitro CaCo-2 cell culture-qPCR. © 2013. Published by Elsevier B.V. All rights reserved.

The effect of X-irradiation on aqueous media containing traces of oxygen

International Nuclear Information System (INIS)

Evans, N.T.S.

1981-01-01

The effect of X-irradiation on small amounts of oxygen dissolved in 1 mM potassium chloride solution, tap water or Eagle's tissue culture medium has been followed with polarographic electrodes. Oxygen is removed from all these solutions down to concentrations corresponding to a few parts per million in the gas phase. Small amounts of hydrogen are also produced by irradiation and can be measured polarographically. Except in Eagle's medium, hydrogen peroxide is formed in the anoxic solutions, and molecular oxygen can be detected after irradiation when catalase is present in the solution. A non-volatile polarographically reducible substance is generated by irradiation of anoxic Eagle's medium. It is not decomposed by catalase but decays spontaneously in solution at a slow rate. (author)

Pulse transformer R and D for NLC klystron pulse modulator

International Nuclear Information System (INIS)

Akemoto, M.; Gold, S.; Krasnykh, A.; Koontz, R.

1997-07-01

The authors have studied a conventional pulse transformer for the NLC klystron pulse modulator. The transformer has been analyzed using a simplified lumped circuit model. It is found that a fast rise time requires low leakage inductance and low distributed capacitance and can be realized by reducing the number of secondary turns, but it produces larger pulse droop and requires a larger core size. After making a tradeoff among these parameters carefully, a conventional pulse transformer with a rise time of 250ns and a pulse droop of 3.6% has been designed and built. The transmission characteristics and pulse time-response were measured. The data were compared with the model. The agreement with the model was good when the measured values were used in the model simulation. The results of the high voltage tests using a klystron load are also presented

Random pulse generator

International Nuclear Information System (INIS)

Guo Ya'nan; Jin Dapeng; Zhao Dixin; Liu Zhen'an; Qiao Qiao; Chinese Academy of Sciences, Beijing

2007-01-01

Due to the randomness of radioactive decay and nuclear reaction, the signals from detectors are random in time. But normal pulse generator generates periodical pulses. To measure the performances of nuclear electronic devices under random inputs, a random generator is necessary. Types of random pulse generator are reviewed, 2 digital random pulse generators are introduced. (authors)

Fiber Optical Parametric Chirped Pulse Amplification of Sub-Picosecond Pulses

DEFF Research Database (Denmark)

Cristofori, Valentina; Lali-Dastjerdi, Zohreh; Da Ros, Francesco

2013-01-01

We demonstrate experimentally, for the first time to our knowledge, fiber optical parametric chirped pulse amplification of 400-fs pulses. The 400-fs signal is stretched, amplified by 26 dB and compressed back to 500 fs.......We demonstrate experimentally, for the first time to our knowledge, fiber optical parametric chirped pulse amplification of 400-fs pulses. The 400-fs signal is stretched, amplified by 26 dB and compressed back to 500 fs....

Periodic dark pulse emission induced by delayed feedback in a quantum well semiconductor laser

Directory of Open Access Journals (Sweden)

L. Li

2012-12-01

Full Text Available We report the experimental observation of periodic dark pulse emission in a quantum-well semiconductor laser with delayed optical feedback. We found that under appropriate operation conditions the laser can also emit a stable train of dark pulses. The repetition frequency of the dark pulse is determined by the external cavity length. Splitting of the dark pulse was also observed. We speculate that the observed dark pulse is a kind of temporal cavity soliton formed in the laser.

Ablation mass features in multi-pulses femtosecond laser ablate molybdenum target

Science.gov (United States)

Zhao, Dongye; Gierse, Niels; Wegner, Julian; Pretzler, Georg; Oelmann, Jannis; Brezinsek, Sebastijan; Liang, Yunfeng; Neubauer, Olaf; Rasinski, Marcin; Linsmeier, Christian; Ding, Hongbin

2018-03-01

In this study, the ablation mass features related to reflectivity of bulk Molybdenum (Mo) were investigated by a Ti: Sa 6 fs laser pulse at central wavelength 790 nm. The ablated mass removal was determined using Confocal Microscopy (CM) technique. The surface reflectivity was calibrated and measured by a Lambda 950 spectrophotometer as well as a CCD camera during laser ablation. The ablation mass loss per pulse increase with the increasing of laser shots, meanwhile the surface reflectivity decrease. The multi-pulses (100 shots) ablation threshold of Mo was determined to be 0.15 J/cm2. The incubation coefficient was estimated as 0.835. The reflectivity change of the Mo target surface following multi-pulses laser ablation were studied as a function of laser ablation shots at various laser fluences from 1.07 J/cm2 to 36.23 J/cm2. The results of measured reflectivity indicate that surface reflectivity of Mo target has a significant decline in the first 3-laser pulses at the various fluences. These results are important for developing a quantitative analysis model for laser induced ablation and laser induced breakdown spectroscopy for the first wall diagnosis of EAST tokamak.

Pulse-to-pulse variations in accreting X-ray pulsars

Directory of Open Access Journals (Sweden)

Kretschmar Peter

2014-01-01

Full Text Available In most accreting X-ray pulsars, the periodic signal is very clear and easily shows up as soon as data covering sufficient pulse periods (a few ten are available. The mean pulse profile is often quite typical for a given source and with minor variations repeated and recognisable across observations done years or even decades apart. At the time scale of individual pulses, significant pulse-to-pulse variations are commonly observed. While at low energies some of these variations might be explained by absorption, in the hard X-rays they will reflect changes in the accretion and subsequent emission. The amount of these variations appears to be quite different between sources and contains information about the surrounding material as well ass possibly interactions at the magnetosphere. We investigate such variations for a sample of well-known sources.

Characterization of power IGBTs under pulsed power conditions

Energy Technology Data Exchange (ETDEWEB)

Dale, Gregory E [Los Alamos National Laboratory; Vangordon, James [UNIV OF MISSOURI; Kovaleski, Scott [UNIV OF MISSOURI

2009-01-01

The power insulated gate bipolar transistor (IGBT) is used in many types of applications. Although the use of the power IGBT has been well characterized for many continuous operation power electronics applications, little published information is available regarding the performance of a given IGBT under pulsed power conditions. Additionally, component libraries in circuit simulation software packages have a finite number of IGBTs. This paper presents a process for characterizing the performance of a given power IGBT under pulsed power conditions. Specifically, signals up to 3.5 kV and 1 kA with 1-10 {micro}s pulse widths have been applied to a Powerex QIS4506001 IGBT. This process utilizes least squares curve fitting techniques with collected data to determine values for a set of modeling parameters. These parameters were used in the Oziemkiewicz implementation of the Hefner model for the IGBT that is utilized in some circuit simulation software packages. After the nominal parameter values are determined, they can be inserted into the Oziemkiewicz implementation to simulate a given IGBT.

Pulse to pulse klystron diagnosis system

International Nuclear Information System (INIS)

Nowak, J.; Davidson, V.; Genova, L.; Johnson, R.; Reagan, D.

1981-03-01

This report describes a system used to study the behavior of SLAC high powered klystrons operating with a twice normal pulse width of 5 μs. At present, up to eight of the klystrons installed along the accelerator can be operated with long pulses and monitored by this system. The report will also discuss some of the recent findings and investigations

Study of the fast inversion recovery pulse sequence. With reference to fast fluid attenuated inversion recovery and fast short TI inversion recovery pulse sequence

International Nuclear Information System (INIS)

Tsuchihashi, Toshio; Maki, Toshio; Suzuki, Takeshi

1997-01-01

The fast inversion recovery (fast IR) pulse sequence was evaluated. We compared the fast fluid attenuated inversion recovery (fast FLAIR) pulse sequence in which inversion time (TI) was established as equal to the water null point for the purpose of the water-suppressed T 2 -weighted image, with the fast short TI inversion recovery (fast STIR) pulse sequence in which TI was established as equal to the fat null point for purpose of fat suppression. In the fast FLAIR pulse sequence, the water null point was increased by making TR longer. In the FLAIR pulse sequence, the longitudinal magnetization contrast is determined by TI. If TI is increased, T 2 -weighted contrast improves in the same way as increasing TR for the SE pulse sequence. Therefore, images should be taken with long TR and long TI, which are longer than TR and longer than the water null point. On the other hand, the fat null point is not affected by TR in the fast STIR pulse sequence. However, effective TE was affected by variation of the null point. This increased in proportion to the increase in effective TE. Our evaluation indicated that the fast STIR pulse sequence can control the extensive signals from fat in a short time. (author)

Pulse Propagation on close conductors

CERN Document Server

Dieckmann, A

2001-01-01

The propagation and reflection of arbitrarily shaped pulses on non-dispersive parallel conductors of finite length with user defined cross section is simulated employing the discretized telegraph equation. The geometry of the system of conductors and the presence of dielectric material determine the capacities and inductances that enter the calculation. The values of these parameters are found using an iterative Laplace equation solving procedure and confirmed for certain calculable geometries including the line charge inside a box. The evolving pulses and the resulting crosstalk can be plotted at any instant and - in the Mathematica notebook version of this report - be looked at in an animation. As an example a differential pair of microstrips as used in the ATLAS vertex detector is analysed.

Efficient chirped-pulse amplification of sub-20 fs laser pulses

Energy Technology Data Exchange (ETDEWEB)

Matsuoka, Shinichi; Yamakawa, Koichi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

1998-03-01

We have developed a model for ultrabroadband and ultrashort pulse amplification including the effects of a pulse shaper for regenerative pulse shaping, gain narrowing and gain saturation in the amplifiers. Thin solid etalons are used to control both gain narrowing and gain saturation during amplification. This model has been used to design an optimized Ti:sapphire amplifier system for producing efficiently pulses of < 20-fs duration with approaching peak and average powers of 100 TW and 20 W. (author)

Properties of gamma-ray burst time profiles using pulse decomposition analysis

Energy Technology Data Exchange (ETDEWEB)

Lee, A.

2000-02-08

The time profiles of many gamma-ray bursts consist of distinct pulses, which offers the possibility of characterizing the temporal structure of these bursts using a relatively small set of pulse shape parameters. This pulse decomposition analysis has previously been performed on a small sample of bright long bursts using binned data from BATSE, which comes in several data types, and on a sample of short bursts using the BATSE Time-Tagged Event (TTE) data type. The authors have developed an interactive pulse-fitting program using the phenomenological pulse model of Norris, et. al. and a maximum-likelihood fitting routine. They have used this program to analyze the Time-to-Spill (TTS) data for all bursts observed by BATSE up through trigger number 2000, in all energy channels for which TTS data is available. They present statistical information on the attributes of pulses comprising these bursts, including relations between pulse characteristics through the course of a burst. They carry out simulations to determine the biases that their procedures may introduce. They find that pulses tend to have shorter rise times than decay times, and tend to be narrower and peak earlier at higher energies. They also find that pulse brightness, pulse width, and pulse hardness ratios do not evolve monotonically within bursts, but that the ratios of pulse rise times to decay times tends to decrease with time within bursts.

Patterns of digital volume pulse waveform and pulse transit time in ...

African Journals Online (AJOL)

In this study the digital volume pulse wave and the pulse transit time of the thumb and big toe were analyzed in young and older subjects some of whom were hypertensive. We aimed to study the components and patterns of the pulse waveform and the pulse transit time and how they might change. Material and Methods: ...

Genetic heterogeneity of Campylobacter concisus determined by pulsed field gel electrophoresis-based macrorestriction profiling

DEFF Research Database (Denmark)

Matsheka, M.I.; Elisha, B.G.; Lastovica, A.L.

2002-01-01

1 for pulsed field gel electrophoresis-based genotyping. Subsequently, 53 strains of C concisus, principally from cases of diarrhoea in children, were examined. Fifty-one distinct patterns were obtained, indicating the high discriminatory potential of the method. Patterns comprised between one...... comprised of several genomospecies. The pulsed field gel electrophoresis typing method described here has considerable potential for molecular epidemiological studies of C concisus and may be a useful adjunctive method for helping to resolve key taxonomic issues for this species....... and 14 restriction fragments, with type and reference strains of two well-defined genomospecies of oral and faecal origin containing six and 12 fragments respectively. Our results show that C concisus is genetically diverse and suggest the species as currently defined to be a taxonomic continuum...

Ultrashort and coherent single-electron pulses for diffraction at ultimate resolutions

International Nuclear Information System (INIS)

Kirchner, Friedrich Oscar

2013-01-01

Ultrafast electron diffraction is a powerful tool for studying structural dynamics with femtosecond temporal and sub-aangstroem spatial resolutions. It benefits from the high scattering cross-sections of electrons compared X-rays and allows the examination of thin samples, surfaces and gases. One of the main challenges in ultrafast electron diffraction is the generation of electron pulses with a short duration and a large transverse coherence. The former limits the temporal resolution of the experiment while the latter determines the maximum size of the scattering structures that can be studied. In this work, we strive to push the limits of electron diffraction towards higher temporal and spatial resolutions. The decisive step in our approach is to eliminate all detrimental effects caused by Coulomb repulsion between the electrons by reducing the number of electrons per pulse to one. In this situation, the electrons' longitudinal and transverse velocity distributions are determined solely by the photoemission process. By reducing the electron source size on the photocathode, we make use of the small transverse velocity spread to produce electron pulses with a transverse coherence length of 20 nm, which is about an order of magnitude larger than the reported values for comparable experiments. The energy distribution of an ensemble of single-electron pulses from a photoemission source is directly linked to the mismatch between the photon energy and the cathode's work function. This excess energy can be reduced by using a photon energy close to the material's work function. Using a tunable source of ultraviolet pulses, we demonstrate the reduction of the velocity spread of the electrons, resulting in a shorter duration of the electron pulses. The reduced electron pulse durations achieved by a tunable excitation or by other approaches require new characterization techniques for electron pulses. We developed a novel method for the characterization of electron pulses at

A 350 KV nanosecond pulse voltage generator with adjustable pulsed-width

International Nuclear Information System (INIS)

Wang, X.; Wang, M.; Chen, Y.Q.; Zeng, L.G.; Han, M.

2002-01-01

This paper presents a 350 kV nanosecond pulse voltage generator (NPVG). The voltage pulsed-width can be adjusted from 30 to 160 ns. The generator consists of: Marx generator, pulsed forming line (PFL), main switch and matched impedance. The output voltage of Marx generator is over than nU c (n- the stage number of Marx generator, U c -the charging voltage of capacitor). When the pulse forming line is terminated with an impedance that is over than the characteristic impedance of PFL, the higher voltage pulse was provided for the load

High-power pre-chirp managed amplification of femtosecond pulses at high repetition rates

International Nuclear Information System (INIS)

Liu, Yang; Li, Wenxue; Zhao, Jian; Bai, Dongbi; Luo, Daping; Zeng, Heping

2015-01-01

Femtosecond pulses at 250 MHz repetition rate from a mode-locked fiber laser are amplified to high power in a pre-chirp managed amplifier. The experimental strategy offers a potential towards high-power ultrashort laser pulses at high repetition rates. By investigating the laser pulse evolution in the amplification processes, we show that self-similar evolution, finite gain bandwidth and mode instabilities determine pulse characteristics in different regimes. Further average power scaling is limited by the mode instabilities. Nevertheless, this laser system enables us to achieve sub-50 fs pulses with an average power of 93 W. (letter)

Laser beam diagnostics for kilowatt power pulsed YAG laser

International Nuclear Information System (INIS)

Liu, Yi; Leong, Keng H.

1992-01-01

There is a growing need for high power YAG laser beam diagnostics with the recent introduction of such lasers in laser material processing. In this paper, we will describe the use of a commercially available laser beam analyzer (Prometec) to profile the laser beam from a 1600 W pulsed Nd:YAG laser that has a 1 mm fiber optic beam delivery system. The selection of laser pulse frequency and pulse width for the measurement is discussed. Laser beam propagation parameters by various optical components such as fibers and lenses can be determined from measurements using this device. The importance of such measurements will be discussed

Pulsed Neutron log application in accurate fluid contact determination and remedial action planning

International Nuclear Information System (INIS)

Kalu, I.; Mukerji, P.

2002-01-01

A common application of pulsed neutron logging in the Niger Delta is saturation monitoring when run in carbon-oxygen (CO) mode. Recently, one such log was run across a reservoir to confirm the position of the oil-water contact on a well that was producing at very high water cut on the short string of a dual string producer. Material balance calculations had predicted an oil-water contact about 5ft from the deepest perforations and so a water shut-off operation had been planned. The interpreted log however showed that the OWC was about 30ft from the perforation and it also showed fluid movement in the borehole in front of the perforations. A production log was subsequently run which identified a tubing leak and confirmed the crossflow of water from the long string into the short string detected on the pulsed neutron log. The proposed water shut-off treatment was aborted based on the interpretation and resulted in substantial savings

Determination of elemental composition of coffee using UV-pulsed laser induced breakdown spectroscopy

International Nuclear Information System (INIS)

Gondal, M. A.; Baig, Umair; Dastageer, M. A.; Sarwar, Mohsin

2016-01-01

A detection system based on laser induced breakdown spectroscopy (LIBS) was built using 266 nm wavelength pulsed laser from the fourth harmonic of Nd:YAG laser, 500 mm spectrograph and gated ICCD camera with built-in delay generator. The LIBS system was used to study the elemental composition in coffee available in the local market of Saudi Arabia for the detection of elements in coffee samples. The LIBS spectrum of coffee sample revealed the presence magnesium, calcium, aluminum, copper, sodium, barium, bromine, cobalt, chromium, cerium manganese and molybdenum. Atomic transition line of sodium is used to study the parametric dependence of LIBS signal. The study of the dependence of LIBS signal on the laser pulse energy is proven to be linear and the dependence of LIBS signal on the time delay between the excitation and data acquisition showed a typical increase, a peak value and a decrease with the optimum excitation – acquisition delay at 400 ns.

Determination of elemental composition of coffee using UV-pulsed laser induced breakdown spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Gondal, M. A., E-mail: magondal@kfupm.edu.sa; Baig, Umair; Dastageer, M. A.; Sarwar, Mohsin [Laser Research Group, Physics Department, King Fahd University of Petroleum and Minerals, P.O Box 5047, Dhahran 31261 (Saudi Arabia)

2016-06-10

A detection system based on laser induced breakdown spectroscopy (LIBS) was built using 266 nm wavelength pulsed laser from the fourth harmonic of Nd:YAG laser, 500 mm spectrograph and gated ICCD camera with built-in delay generator. The LIBS system was used to study the elemental composition in coffee available in the local market of Saudi Arabia for the detection of elements in coffee samples. The LIBS spectrum of coffee sample revealed the presence magnesium, calcium, aluminum, copper, sodium, barium, bromine, cobalt, chromium, cerium manganese and molybdenum. Atomic transition line of sodium is used to study the parametric dependence of LIBS signal. The study of the dependence of LIBS signal on the laser pulse energy is proven to be linear and the dependence of LIBS signal on the time delay between the excitation and data acquisition showed a typical increase, a peak value and a decrease with the optimum excitation – acquisition delay at 400 ns.

Optical pulse dynamics for quantum-dot logic operations in a photonic-crystal waveguide

Energy Technology Data Exchange (ETDEWEB)

Ma, Xun; John, Sajeev [Department of Physics, University of Toronto, Toronto, Ontario, M5S 1A7 Canada (Canada)

2011-11-15

We numerically demonstrate all-optical logic operations with quantum dots (QDs) embedded in a bimodal photonic-crystal waveguide using Maxwell-Bloch equations in a slowly varying envelope approximation (SVEA). The two-level QD excitation level is controlled by one or more femtojoule optical driving pulses passing through the waveguide. Specific logic operations depend on the relative pulse strengths and their detunings from an inhomogeneouslly broadened (about 1% for QD transitions centered at 1.5 {mu}m) QD transition. This excitation controlled two-level medium then determines passage of subsequent probe optical pulses. Envelope equations for electromagnetic waves in the linear dispersion and cutoff waveguide modes are derived to simplify solution of the coupled Maxwell-Bloch equations in the waveguide. These determine the quantum mechanical evolution of the QD excitation and its polarization, driven by classical electromagnetic (EM) pulses near a sharp discontinuity in the EM density of states of the bimodal waveguide. Different configurations of the driving pulses lead to distinctive relations between driving pulse strength and probe pulse passage, representing all-optical logic and, or, and not operations. Simulation results demonstrate that such operations can be done on picosecond time scales and within a waveguide length of about 10 {mu}m in a photonic-band-gap (PBG) optical microchip.

Improved pulse-height store for A/D conversion

Energy Technology Data Exchange (ETDEWEB)

Casoli, P [Montedel S.p.a., Laben Division, Via Bassini 15, Milano, Italy; Maranesi, P [Politecnico di Milano (Italy). Centro Studi Nucleari E. Fermi

1979-11-15

A new pulse-height store is described. Suitable contrivances improve integral linearity and reduce the differential errors that generally occur at signal amplitudes near the lower threshold. No degradations appear at high rates of input events. The electrical specifications of the pulse-height store are determined through a series of measurements described in the final part of the paper. In order to test the circuit in the most significant way, it has been connected to a fast successive-approximation conversion module which uses the sliding-scale technique for channel width equalisation, thus implementing a complete analog-to-digital converter (ADC) for nuclear spectrometry. The performances of the pulse-height store have been deduced from the behavior of the whole system.

Comparative toxicity of heavy metal ions for some microorganisms. [Rhodotorula; Hansenula anormala; T. utilis; Serratia; Azotobacter; Pseudomonas; Escherichia coli; yeasts

Energy Technology Data Exchange (ETDEWEB)

Avakyan, Z A

1967-01-01

Polarographic study of Pb/sup 2 +/, Cd/sup 2 +/, Co/sup 2 +/, and Ni/sup 2 +/ concentration in different media has shown that at pH 6.0, Pb/sup 2 +/ is always precipitated by phosphates and cannot be determined polarographically. Cd, Co and Ni content is somewhat lower than that found in water solutions. The effect of Ag, Hg, Co, Ni, Pb, and Cd ions on the growth of 3 strains of Rhodotorula, Hansenula anomala and T. utilis, 6 strains of Serratia, 6 strains of Azotobacter, 12 strains of Pseudomonas and 2 strains of E. coli was studied. According to their toxicity for the microoganisms tested, heavy metals should be arranged in the following order: Ag>Hg>Cogreater than or equal toNi>Cd. Yeasts are the least sensitive to the action of heavy metals, cf. come serratia, Pseudomonas, Azotobacter and E. coli.

Simulation of the saturation curve of the ionization chamber in overlapping pulsed radiation

International Nuclear Information System (INIS)

Park, Se Hwan; Kim, Yong Kyun; Kim, Han Soo; Kang, Sang Mook; Ha, Jang Ho

2006-01-01

Procedures for determination of collection efficiency in ionization chambers have been studied by numerous investigators. If the theoretical approach for air-filled ionization chambers exposed to continuous radiation is considered, the result in the near-saturation region is a linear relationship between ) (1/I(V) vs 1/V 2 , where I(V) is the current measured with the ionization chamber at a given polarization voltage V . For pulsed radiation beams, Boag developed a model and the resulted in a linear relationship between ) (1/I(V) and 1/V when the collection efficiency, f , is larger than 0.9. The assumption of the linear relationship of ) (1/I(V) with 1/V or 1/V 2 in the near-saturation region makes the determination of the saturation current simple, since the linear relationship may be determined with only two measured data points. The above discussion of the collection efficiency of the ionization chamber exposed to the pulsed radiation is valid only if each pulse is cleared before the next one occurs. The transit times of the ions in the chamber must be shorter than the time interval between the radiation pulses. Most of the previous works concerning the characteristics of the saturation curve of an ionization chamber in the pulsed beam were done for the case where the transit times of the ions were shorter than the interval between the radiation pulses. However, the experimental data for the intermediate case, where the ion transit time was comparable to the interval between the radiation pulses or the ion transit time was slightly longer than the interval between the radiation pulses, were rare. The saturation curves of the ionization chambers in the pulsed radiation were measured with the pulse beamed electron accelerator at the Korea Atomic Energy Research Institute (KAERI), where the ion transit times in the ionization chambers were longer than the time interval between the radiation pulses. We used two ionization chambers: one was a commercial thimble

Effect of power modulation on properties of pulsed capacitively coupled radiofrequency discharges

International Nuclear Information System (INIS)

Samara, V; Bowden, M D; Braithwaite, N St J

2010-01-01

We describe measurements of plasma properties of pulsed, low pressure, capacitively coupled discharges operated in argon. The study aims to determine the effect of modulating the radiofrequency power during the discharge part of the pulse cycle. Measurements of local electron density and optical emission were made in capacitively coupled rf discharges generated in a Gaseous Electronics Conference (GEC) reference reactor. Gas pressure was in the range 7-70 Pa, rf power in the range 1-100 W and pulse durations in the range 10 μs-100 ms. The results indicate that the ignition and afterglow decay processes in pulsed discharges can be controlled by modulating the shape of applied radiofrequency pulse.

Propagation of ultrashort laser pulses in water: linear absorption and onset of nonlinear spectral transformation.

Science.gov (United States)

Sokolov, Alexei V; Naveira, Lucas M; Poudel, Milan P; Strohaber, James; Trendafilova, Cynthia S; Buck, William C; Wang, Jieyu; Strycker, Benjamin D; Wang, Chao; Schuessler, Hans; Kolomenskii, Alexandre; Kattawar, George W

2010-01-20

We study propagation of short laser pulses through water and use a spectral hole filling technique to essentially perform a sensitive balanced comparison of absorption coefficients for pulses of different duration. This study is motivated by an alleged violation of the Bouguer-Lambert-Beer law at low light intensities, where the pulse propagation is expected to be linear, and by a possible observation of femtosecond optical precursors in water. We find that at low intensities, absorption of laser light is determined solely by its spectrum and does not directly depend on the pulse duration, in agreement with our earlier work and in contradiction to some work of others. However, as the laser fluence is increased, interaction of light with water becomes nonlinear, causing energy exchange among the pulse's spectral components and resulting in peak-intensity dependent (and therefore pulse-duration dependent) transmission. For 30 fs pulses at 800 nm center wavelength, we determine the onset of nonlinear propagation effects to occur at a peak value of about 0.12 mJ/cm(2) of input laser energy fluence.

Optical pulse compression

International Nuclear Information System (INIS)

Glass, A.J.

1975-01-01

The interest in using large lasers to achieve a very short and intense pulse for generating fusion plasma has provided a strong impetus to reexamine the possibilities of optical pulse compression at high energy. Pulse compression allows one to generate pulses of long duration (minimizing damage problems) and subsequently compress optical pulses to achieve the short pulse duration required for specific applications. The ideal device for carrying out this program has not been developed. Of the two approaches considered, the Gires--Tournois approach is limited by the fact that the bandwidth and compression are intimately related, so that the group delay dispersion times the square of the bandwidth is about unity for all simple Gires--Tournois interferometers. The Treacy grating pair does not suffer from this limitation, but is inefficient because diffraction generally occurs in several orders and is limited by the problem of optical damage to the grating surfaces themselves. Nonlinear and parametric processes were explored. Some pulse compression was achieved by these techniques; however, they are generally difficult to control and are not very efficient. (U.S.)

Pulse induction heating

Energy Technology Data Exchange (ETDEWEB)

Vasiliev, A S; Kachanov, B Y; Kogan, B V

1993-12-31

Induction heating and three types of pulse processes were studied. It was found that in pulse processes the frequency and pulse duration of heat treatments do not remain constant. High frequency pulse heat treatments can be used on sprayed coatings; such treatments will result in stronger surfaces with no cracks. For induction hardening, the rate of specific power was 1 to 1.5 kW/sq.cm, for forging it was 0.2 to 0.3 kW/sq.cm and for melting it was 0.05 to 0.1 kW/sq.cm. The application of pulse heating will result in higher rates of specific power.

Determination of thermal and physical properties of port-wine stain lesions using pulsed photothermal radiometry

Science.gov (United States)

Nelson, J. Stuart; Jacques, Steven L.; Wright, William H.

1992-06-01

A method for quantitative characterization of port wine stain (PWS) is presented. Pulsed photothermal radiometry (PPTR) uses a non-invasive infrared radiometry system to measure changes in surface temperature induced by pulsed radiation. When a pulsed laser is used to irradiate a PWS, an initial temperature jump (T-jump) is seen due to the heating of the epidermis as a result of melanin absorption. Subsequently, heat generated in the subsurface blood vessels due to hemoglobin absorption is detected by PPTR as a delayed thermal wave as the heat diffuses toward the skin surface. The time delay and magnitude of the delayed PPTR signal indicate the depth and thickness of the PWS. In this report, we present an initial clinical study of PPTR measurements on PWS patients. Computer simulations of various classes of PWS illustrate how the PPTR signal depends on the concentration of epidermal melanin, and depth and thickness of the PWS. The goal of this research is to provide a means of characterizing PWS before initiating therapy, guiding laser dosimetry, and advising the patient as to the time course and efficacy of the planned protocol.

Preparation of L-asparagine complex with technetium

International Nuclear Information System (INIS)

Persano, S.C.M.

1981-01-01

The preparation of technetium chelated to L-asparagine is aimed at for obtention of potentially useful radiopharmaceutical in nuclear medicine. The reduction of pertechnetate anion ( 99 TcO - 4 and sup(99m) TcO - 4 ) using hydrazine as a reducing agent is studied with use of polarographic spectrophotometric and chromatographic methods. Spectrophotometric determination shows that the aqueous solution of amonium sup(-99m) Tc pertechnetate absorbs at 244, 248 and 290 nm. After reduction the species absorbs at 330 and near 495-530 nm. Polarographic measurements with 0,1 N NaOH electrolyte show a half-wave potential E sub(1/2 = -0,82 V for technetium +VII. After the addition of increasing amounts of hydrazine into a solution containing Tc+VII, the half wave potential shifts to more positives values, indicating the reduction of Tc+VII. Chromatographic determinations are in good agreement with polarographic analysis, emphatizing reduction of Tc+IV by hydrazine. The reduced 99 Tc shows ability of being incorporated into L-asparagine forming a cristalline compound with melting point 118.6 0 C. Infrared absorption spectrometry shows that amino and carboxyl groups are bound to the metal in this complex. The yield of sup(99m) Tc incorporation into L-asparagine at 60 0 C in 30 minutes is up to 95%. The labeled complex can be presented as a radiopharmaceutical product. Tissue distribution performed in groups of normal and bearing lymphoma Walker 256 Wistar rats (50-60) shows that the radiopharmaceutical concentrates seletively in the tumor and is fastly excreted by the kidney and it doesn't have significant affinity for any organ, being so adequate for the formation of tumoral images. (Authors) [pt

Pulse-shaping mechanism in colliding-pulse mode-locked laser diodes

DEFF Research Database (Denmark)

Bischoff, Svend; Sørensen, Mads Peter; Mørk, J.

1995-01-01

The large signal dynamics of passively colliding pulse mode-locked laser diodes is studied. We derive a model which explains modelocking via the interplay of gain and loss dynamics; no bandwidth limiting element is necessary for pulse formation. It is found necessary to have both fast and slow...... absorber dynamics to achieve mode-locking. Significant chirp is predicted for pulses emitted from long lasers, in agreement with experiment. The pulse width shows a strong dependence on both cavity and saturable absorber length. (C) 1995 American Institute of Physics....

S100 lathe bed pulse generator applied to pulsed nuclear magnetic resonance

International Nuclear Information System (INIS)

Cernicchiaro, G.R.C.; Rudge, M.G.; Albuquerque, M.P.

1989-01-01

The project and construction of four channel pulse generator in the S100 standard plate and its control software for microcomputer are described. The microcomputer has total control on the pulse generator, which has seven programable parameters, defining the position of four pulses and the width for the three first ones. This pulse generator is controlled by a software developed in c language, and is used in pulsed nuclear magnetic resonance experiences. (M.C.K.) [pt

Studies on gas breakdown in pulsed radio frequency atmospheric pressure glow discharges

International Nuclear Information System (INIS)

Huo, W. G.; Jian, S. J.; Yao, J.; Ding, Z. F.

2014-01-01

In pulsed RF atmospheric pressure glow discharges, the gas breakdown judged by the rapid drop in the amplitude of the pulsed RF voltage is no longer universally true. The steep increment of the plasma-absorbed RF power is proposed to determine the gas breakdown. The averaged plasma-absorbed RF power over a pulse period is used to evaluate effects of the preceding pulsed RF discharge on the breakdown voltage of the following one, finding that the breakdown voltage decreases with the increment in the averaged plasma-absorbed RF power under constant pulse duty ratio. Effects of the pulse off-time on the breakdown voltage and the breakdown delay time are also studied. The obtained dependence of the breakdown voltage on the pulse off-time is indicative of the transitional plasma diffusion processes in the afterglow. The breakdown voltage varies rapidly as the plasma diffuses fast in the region of moderate pulse off-time. The contribution of nitrogen atom recombination at the alumina surface is demonstrated in the prolonged memory effect on the breakdown delay time vs. the pulse off-time and experimentally validated by introducing a trace amount of nitrogen into argon at short and long pulse off-times

Application of Box-Behnken designs in parameters optimization of differential pulse anodic stripping voltammetry for lead(II) determination in two electrolytes.

Science.gov (United States)

Yu, Xiao-Lan; He, Yong

2017-06-05

Box-Behnken design was advantageous to parameters optimization of differential pulse anodic stripping voltammetry (DPASV) for the analysis of lead(II) with its high efficiency and accuracy. Five Box-Behnken designs were designed and conducted in the electrolyte of 0.1 mol/L acetate buffer and 0.1 mol/L HCl without the removal of oxygen. Significant parameters and interactions in each electrolyte were found (P-value Box-Behnken designs in parameters optimization of DPASV for lead(II) determination regardless of the electrolyte kinds.

Neural pulse frequency modulation of an exponentially correlated Gaussian process

Science.gov (United States)

Hutchinson, C. E.; Chon, Y.-T.

1976-01-01

The effect of NPFM (Neural Pulse Frequency Modulation) on a stationary Gaussian input, namely an exponentially correlated Gaussian input, is investigated with special emphasis on the determination of the average number of pulses in unit time, known also as the average frequency of pulse occurrence. For some classes of stationary input processes where the formulation of the appropriate multidimensional Markov diffusion model of the input-plus-NPFM system is possible, the average impulse frequency may be obtained by a generalization of the approach adopted. The results are approximate and numerical, but are in close agreement with Monte Carlo computer simulation results.

CrN/AlN nanolaminate coatings deposited via high power pulsed and middle frequency pulsed magnetron sputtering

International Nuclear Information System (INIS)

Bagcivan, N.; Bobzin, K.; Ludwig, A.; Grochla, D.; Brugnara, R.H.

2014-01-01

Nanolaminate coatings based on transition metal nitrides such as CrN, AlN and TiN deposited via physical vapor deposition (PVD) have shown great advantage as protective coatings on tools and components subject to high loads in tribological applications. By varying the individual layer materials and their thicknesses it is possible to optimize the coating properties, e.g. hardness, Young's modulus and thermal stability. One way for further improvement of coating properties is the use of advanced PVD technologies. High power pulsed magnetron sputtering (HPPMS) is an advancement of pulsed magnetron sputtering (MS). The use of HPPMS allows a better control of the energetic bombardment of the substrate due to the higher ionization degree of metallic species. It provides an opportunity to influence chemical and mechanical properties by varying the process parameters. The present work deals with the development of CrN/AlN nanolaminate coatings in an industrial scale unit by using two different PVD technologies. Therefore, HPPMS and mfMS (middle frequency magnetron sputtering) technologies were used. The bilayer period Λ, i.e. the thickness of a CrN/AlN double layer, was varied between 6.2 nm and 47.8 nm by varying the rotational speed of the substrate holders. In a second step the highest rotational speed was chosen and further HPPMS CrN/AlN coatings were deposited applying different HPPMS pulse lengths (40, 80, 200 μs) at the same mean cathode power and frequency. Thickness, morphology, roughness and phase composition of the coatings were analyzed by means of scanning electron microscopy (SEM), confocal laser microscopy, and X-ray diffraction (XRD), respectively. The chemical composition was determined using glow discharge optical emission spectroscopy (GDOES). Detailed characterization of the nanolaminate was conducted by transmission electron microscopy (TEM). The hardness and the Young's modulus were analyzed by nanoindentation measurements. The residual

Low-intensity pulsed ultrasound: Nonunions

Directory of Open Access Journals (Sweden)

Dijkman Bernadette

2009-01-01

Full Text Available Nonunions occur in 5-10% of fractures and are characterized by the failure to heal without further intervention. Low intensity pulsed ultrasound therapy has been developed as an alternative to surgery in the treatment of nonunions. We describe a systematic review on trials of low-intensity pulsed ultrasound therapy for healing of nonunions. We searched the electronic databases Medline and the Cochrane library for articles on ultrasound and healing of nonunions published up to 2008. Trials selected for the review met the following criteria: treatment of at least one intervention group with low intensity pulsed ultrasound; inclusion of patients (humans with one or more nonunions (defined as "established" or as a failure to heal for a minimum of eight months after initial injury; and assessment of healing and time to healing, as determined radiographically. The following data were abstracted from the included studies: sample size, ultrasound treatment characteristics, nonunion location, healing rate, time to fracture healing, fracture age, and demographic information. We found 79 potentially eligible publications, of which 14 met our inclusion criteria. Of these, eight studies were used for data abstraction. Healing rates averaged 87%, (range 65.6%-100% among eight trials. Mean time to healing was 146.5 days, (range 56-219 days. There is evidence from trials that low-intensity pulsed ultrasound may be an effective treatment for healing of nonunions. More homogeneous and larger controlled series are needed to further investigate its efficacy.

Macrophage and tumor cell responses to repetitive pulsed X-ray radiation

Science.gov (United States)

Buldakov, M. A.; Tretyakova, M. S.; Ryabov, V. B.; Klimov, I. A.; Kutenkov, O. P.; Kzhyshkowska, J.; Bol'shakov, M. A.; Rostov, V. V.; Cherdyntseva, N. V.

2017-05-01

To study a response of tumor cells and macrophages to the repetitive pulsed low-dose X-ray radiation. Methods. Tumor growth and lung metastasis of mice with an injected Lewis lung carcinoma were analysed, using C57Bl6. Monocytes were isolated from a human blood, using CD14+ magnetic beads. IL6, IL1-betta, and TNF-alpha were determined by ELISA. For macrophage phenotyping, a confocal microscopy was applied. “Sinus-150” was used for the generation of pulsed X-ray radiation (the absorbed dose was below 0.1 Gy, the pulse repetition frequency was 10 pulse/sec). The irradiation of mice by 0.1 Gy pulsed X-rays significantly inhibited the growth of primary tumor and reduced the number of metastatic colonies in the lung. Furthermore, the changes in macrophage phenotype and cytokine secretion were observed after repetitive pulsed X-ray radiation. Conclusion. Macrophages and tumor cells had a different response to a low-dose pulsed X-ray radiation. An activation of the immune system through changes of a macrophage phenotype can result in a significant antitumor effect of the low-dose repetitive pulsed X-ray radiation.

Laser pulse stacking method

Science.gov (United States)

Moses, E.I.

1992-12-01

A laser pulse stacking method is disclosed. A problem with the prior art has been the generation of a series of laser beam pulses where the outer and inner regions of the beams are generated so as to form radially non-synchronous pulses. Such pulses thus have a non-uniform cross-sectional area with respect to the outer and inner edges of the pulses. The present invention provides a solution by combining the temporally non-uniform pulses in a stacking effect to thus provide a more uniform temporal synchronism over the beam diameter. 2 figs.

Controllable pulse parameter transcranial magnetic stimulator with enhanced circuit topology and pulse shaping

Science.gov (United States)

Peterchev, Angel V.; DʼOstilio, Kevin; Rothwell, John C.; Murphy, David L.

2014-10-01

Objective. This work aims at flexible and practical pulse parameter control in transcranial magnetic stimulation (TMS), which is currently very limited in commercial devices. Approach. We present a third generation controllable pulse parameter device (cTMS3) that uses a novel circuit topology with two energy-storage capacitors. It incorporates several implementation and functionality advantages over conventional TMS devices and other devices with advanced pulse shape control. cTMS3 generates lower internal voltage differences and is implemented with transistors with a lower voltage rating than prior cTMS devices. Main results. cTMS3 provides more flexible pulse shaping since the circuit topology allows four coil-voltage levels during a pulse, including approximately zero voltage. The near-zero coil voltage enables snubbing of the ringing at the end of the pulse without the need for a separate active snubber circuit. cTMS3 can generate powerful rapid pulse sequences (\\lt 10 ms inter pulse interval) by increasing the width of each subsequent pulse and utilizing the large capacitor energy storage, allowing the implementation of paradigms such as paired-pulse and quadripulse TMS with a single pulse generation circuit. cTMS3 can also generate theta (50 Hz) burst stimulation with predominantly unidirectional electric field pulses. The cTMS3 device functionality and output strength are illustrated with electrical output measurements as well as a study of the effect of pulse width and polarity on the active motor threshold in ten healthy volunteers. Significance. The cTMS3 features could extend the utility of TMS as a research, diagnostic, and therapeutic tool.

Visible continuum pulses based on enhanced dispersive wave generation for endogenous fluorescence imaging.

Science.gov (United States)

Cui, Quan; Chen, Zhongyun; Liu, Qian; Zhang, Zhihong; Luo, Qingming; Fu, Ling

2017-09-01

In this study, we demonstrate endogenous fluorescence imaging using visible continuum pulses based on 100-fs Ti:sapphire oscillator and a nonlinear photonic crystal fiber. Broadband (500-700 nm) and high-power (150 mW) continuum pulses are generated through enhanced dispersive wave generation by pumping femtosecond pulses at the anomalous dispersion region near zero-dispersion wavelength of high-nonlinear photonic crystal fibers. We also minimize the continuum pulse width by determining the proper fiber length. The visible-wavelength two-photon microscopy produces NADH and tryptophan images of mice tissues simultaneously. Our 500-700 nm continuum pulses support extending nonlinear microscopy to visible wavelength range that is inaccessible to 100-fs Ti:sapphire oscillators and other applications requiring visible laser pulses.

Comparison of pulse characteristic of low frequency ultrasonic probes for concrete application

International Nuclear Information System (INIS)

Amry Amin Abas; Suhairy Sani; Muhammad Pauzi Ismail

2006-01-01

Ultrasonic testing of concrete or large volume of composites usually is done in low frequency range. To obtain low frequency pulse, a low frequency pulser/receiver is used attached to a low frequency probe as transmitter/receiver. Concrete is highly attenuative and a high energy pulse is essential to ensure good penetration of test samples. High energy pulse can be obtained by producing low frequency ultrasonic waves.To achieve high penetration in concrete, a low frequency probe is fabricated with the centre frequency lying at around 100 kHz. The probe is fabricated with single crystal of 18 mm thickness without any backing material to obtain wider pulse and higher pulse power. Then, comparison of pulse characteristic is done between the fabricated probe and a commercially available probe to determine the quality of the probe fabricated. (Author)

Bio-effects of repetitively pulsed ultra-fast distributed feedback dye lasers

International Nuclear Information System (INIS)

Khan, N.; Ahmad, M.I.; Sheikh, A.

1999-01-01

Results of experimental study showing an unexpected rise in pulses of distributed feedback dye laser (DFDL) output due to temperature accumulation in dye cell during passively Q-Switched, a Mode-locked operation is reported. This unintended increase in number of pulse duration, per pulse energy may cause side-effects when used for selective photo thermolysis. To probe this phenomenon most commonly dye was excited with 10 to 20 pulses of second harmonic of a passively Q-Switched and Mode-locked Nd-YaG laser. The outputs of DFDL and Nd:YaG laser were recorded by Imacon 675-streak camera. The peak of DFDL output pulses was found delayed proportionally from the peak of the NYAG pulses by more than one inter-pulse period of excitation laser. A computer program was used to simulate the experimentally measured delay to estimate thermal decay constants and energy retained by the medium to determine the amount of incremental fluctuations in output. The delay between peaks of Nd:YAG (input) and DFDL(output) pulses was found to vary from 10 to 14 nanoseconds for various cavity lengths. It was found that for smaller inter-pulse periods the effect of gradual build-up satisfies the threshold conditions for some of the pulses that otherwise can not. This may lead to unintended increase in energy fluence causing overexposure-induced side-effects. (author)

Active manipulation of the selective alignment by two laser pulses

International Nuclear Information System (INIS)

Zeng-Qiang, Yang; Zhi-Rong, Guo; Gui-Xian, Ge

2010-01-01

This paper solves numerically the full time-dependent Schrödinger equation based on the rigid rotor model, and proposes a novel strategy to determine the optimal time delay of the two laser pulses to manipulate the molecular selective alignment. The results illustrate that the molecular alignment generated by the first pulse can be suppressed or enhanced selectively, the relative populations of even and odd rotational states in the final rotational wave packet can be manipulated selectively by precisely inserting the peak of the second laser pulse at the time when the slope for the alignment parameter by the first laser locates a local maximum for the even rotational states and a local minimum for the odds, and vice versa. The selective alignment can be further optimised by selecting the intensity ratio of the two laser pulses on the condition that the total laser intensity and pulse duration are kept constant. (atomic and molecular physics)

PERCEPTION LEVEL EVALUATION OF RADIO ELECTRONIC MEANS TO A PULSE OF ELECTROMAGNETIC RADIATION

Directory of Open Access Journals (Sweden)

2016-01-01

Full Text Available The method for evaluating the perception level of electronic means to pulsed electromagnetic radiation is consid- ered in this article. The electromagnetic wave penetration mechanism towards the elements of electronic systems and the impact on them are determined by the intensity of the radiation field on the elements of electronic systems. The impact of electromagnetic radiation pulses to the electronic systems refers to physical and analytical parameters of the relationship between exposure to pulses of electromagnetic radiation and the sample parameters of electronic systems. A physical and mathematical model of evaluating the perception level of electronic means to pulsed electromagnetic radiation is given. The developed model was based on the physics of electronics means failure which represents the description of electro- magnetic, electric and thermal processes that lead to the degradation of the original structure of the apparatus elements. The conditions that lead to the total equation electronic systems functional destruction when exposed to electromagnetic radia- tion pulses are described. The internal characteristics of the component elements that respond to the damaging effects are considered. The ratio for the power failure is determined. A thermal breakdown temperature versus pulse duration of expo- sure at various power levels is obtained. The way of evaluation the reliability of electronic systems when exposed to pulses of electromagnetic radiation as a destructive factor is obtained.

Optimized transmission-line impedance transformers for petawatt-class pulsed-power accelerators

Directory of Open Access Journals (Sweden)

D. R. Welch

2008-03-01

Full Text Available We have developed 1D analytic and 2D fully electromagnetic models of radial transmission-line impedance transformers. The models have been used to quantify the power-transport efficiency and pulse sharpening of such transformers as a function of voltage pulse width and impedance profile. For the cases considered, we find that in the limit as Γ→0 (where Γ is the ratio of the pulse width to the one-way transit time of the transformer, the transport efficiency is maximized when the impedance profile is exponential. As Γ increases from zero, the optimum profile gradually deviates from an exponential. A numerical procedure is presented that determines the optimum profile for a given pulse shape and width. The procedure can be applied to optimize the design of impedance transformers used in petawatt-class pulsed-power accelerators.

Molecular isomerization induced by ultrashort infrared pulses. II. Pump-dump isomerization using pairs of time-delayed half-cycle pulses.

Science.gov (United States)

Uiberacker, Christoph; Jakubetz, Werner

2004-06-22

We investigate population transfer across the barrier in a double-well potential, induced by a pair of time-delayed single-lobe half-cycle pulses. We apply this setup both to a one-dimensional (1D) quartic model potential and to a three-dimensional potential representing HCN-->HNC isomerization. Overall the results for the two systems are similar, although in the 3D system some additional features appear not seen in the 1D case. The generic mechanism of population transfer is the preparation by the pump pulse of a wave packet involving delocalized states above the barrier, followed by the essentially 1D motion of the delocalized part of wave packet across the barrier, and the eventual de-excitation by the dump pulse to localized states in the other well. The correct timing is given by the well-to-well passage time of the wave packet and its recurrence properties, and by the signs of the field lobes which determine the direction and acceleration or deceleration of the wave packet motion. In the 3D system an additional pump-pump-dump mechanism linked to wave packet motion in the reagent well can mediate isomerization. Since the transfer time and the pulse durations are of the same order of magnitude, there is also a marked dependence of the dynamics and the transfer yield on the pulse duration. Our analysis also sheds light on the pronounced carrier envelope phase dependence previously observed for isomerization and molecular dissociation with one-cycle and sub-one-cycle pulses. (c) 2004 American Institute of Physics.

A Radiation Dosimetry Method Using Pulsed Optically Stimulated Luminescence

International Nuclear Information System (INIS)

Akselrod, M.S.; McKeever, S.W.S.

1999-01-01

A method for the determination of absorbed radiation dose is described based on pulsed optically stimulated luminescence (POSL). The method relies upon the stimulation of an irradiated sample with a train of light pulses from a suitable light source (e.g. a laser) using a wavelength which is within the range of wavelengths corresponding to the radiation-induced optical absorption in the irradiated sample. The subsequent emitted light, due to the detrapping of trapped charges and their subsequent recombination with charge of the opposite sign, is synchronously detected in the period between each stimulation pulse. The total luminescence is summed over the desired number of stimulation pulses and this forms the measured POSL signal. By monitoring the emitted light only in the period between stimulation pulses one can reduce the optical filtering required to discriminate between the stimulation light and the emission light; in this way a high measurement efficiency, and, therefore, a high radiation sensitivity (luminescence intensity per unit absorbed dose) is achieved. Key parameters in the method are the intrinsic luminescence lifetime for the material being used as the luminescent detector, the width of the optical stimulation pulse, and the period between pulses. For optimum operation the measurement parameters should be such that both the pulse width and the time between pulses are much less than the luminescence lifetime. By appropriate choice of the power of the optical stimulation, the frequency of the stimulation pulses, and the total stimulation period, one can also re-measure the absorbed dose several times. In this way, a re-read capability is available with the procedure. The method is illustrated using light from a 2nd-harmonic Nd:YAG laser, with irradiated, anion-deficient aluminium oxide as the luminescent detector material. (author)

Electrical pulse burnout of transistors in intense ionizing radiation

International Nuclear Information System (INIS)

Hartman, E.F.; Evans, D.C.

1975-01-01

Tests examining possible synergistic effects of electrical pulses and ionizing radiation on transistors were performed and energy/power thresholds for transistor burnout determined. The effect of ionizing radiation on burnout thresholds was found to be minimal, indicating that electrical pulse testing in the absence of radiation produces burnout-threshold results which are applicable to IEMP studies. The conditions of ionized transistor junctions and radiation induced current surges at semiconductor device terminals are inherent in IEMP studies of electrical circuits

Determination of the stochastic layer properties induced by magnetic perturbations via heat pulse experiments at ASDEX upgrade

Directory of Open Access Journals (Sweden)

D. Brida

2017-08-01

Full Text Available A heat pulse experiment was carried out in the tokamak ASDEX Upgrade to estimate the stochastic layer width of a deuterium L-mode discharge with externally applied Magnetic Perturbations. The method relies on the deposition of ECRH pulses in the plasma edge while measuring the divertor target heat flux with high temporal resolution IR thermography and Langmuir probes. The experimental results were compared to simulations of the time dependent heat pulse propagation on a constant plasma background with the EMC3-EIRENE code package, using an ad-hoc screening model. If no screening was taken into account in the simulations a decrease in the characteristic heat pulse propagation time was observed, which shows that the heat transport is enhanced compared to the screened cases. No such enhancement was found in the experiment, indicating strong screening. In further simulations the effect of screening on the target fluxes was investigated for varying densities. For low densities it was found that screening reduces the strike line splitting strongly, while for higher densities no strong strike line splitting was found, independent of the screening degree. For strongly detached L-mode conditions with MPs experiments at AUG indicate that the lobe structures vanish completely.

RF Pulsed Heating

Energy Technology Data Exchange (ETDEWEB)

Pritzkau, David P.

2002-01-03

RF pulsed heating is a process by which a metal is heated from magnetic fields on its surface due to high-power pulsed RF. When the thermal stresses induced are larger than the elastic limit, microcracks and surface roughening will occur due to cyclic fatigue. Pulsed heating limits the maximum magnetic field on the surface and through it the maximum achievable accelerating gradient in a normal conducting accelerator structure. An experiment using circularly cylindrical cavities operating in the TE{sub 011} mode at a resonant frequency of 11.424 GHz is designed to study pulsed heating on OFE copper, a material commonly used in normal conducting accelerator structures. The high-power pulsed RF is supplied by an X-band klystron capable of outputting 50 MW, 1.5 {micro}s pulses. The test pieces of the cavity are designed to be removable to allow testing of different materials with different surface preparations. A diagnostic tool is developed to measure the temperature rise in the cavity utilizing the dynamic Q change of the resonant mode due to heating. The diagnostic consists of simultaneously exciting a TE{sub 012} mode to steady-state in the cavity at 18 GHz and measuring the change in reflected power as the cavity is heated from high-power pulsed RF. Two experimental runs were completed. One run was executed at a calculated temperature rise of 120 K for 56 x 10{sup 6} pulses. The second run was executed at a calculated temperature rise of 82 K for 86 x 10{sup 6} pulses. Scanning electron microscope pictures show extensive damage occurring in the region of maximum temperature rise on the surface of the test pieces.

Optimal pulse fishing policy in stage-structured models with birth pulses

International Nuclear Information System (INIS)

Gao Shujing; Chen Lansun; Sun Lihua

2005-01-01

In this paper, we propose exploited models with stage structure for the dynamics in a fish population for which periodic birth pulse and pulse fishing occur at different fixed time. Using the stroboscopic map, we obtain an exact cycle of system, and obtain the threshold conditions for its stability. Bifurcation diagrams are constructed with the birth rate (or pulse fishing time or harvesting effort) as the bifurcation parameter, and these are observed to display complex dynamic behaviors, including chaotic bands with period windows, period-doubling, multi-period-halving and incomplete period-doubling bifurcation, pitch-fork and tangent bifurcation, non-unique dynamics (meaning that several attractors or attractor and chaos coexist) and attractor crisis. This suggests that birth pulse and pulse fishing provide a natural period or cyclicity that make the dynamical behaviors more complex. Moreover, we show that the pulse fishing has a strong impact on the persistence of the fish population, on the volume of mature fish stock and on the maximum annual-sustainable yield. An interesting result is obtained that, after the birth pulse, the population can sustain much higher harvesting effort if the mature fish is removed as early as possible

Pulse carboxyhemoglobin-oximetry and cigarette smoking.

Science.gov (United States)

Sokolova-Djokić, L; Milosević, S; Skrbić, R; Salabat, R; Voronov, G; Igić, R

2011-01-01

We used a pulse carbon monoxide (CO)-oximeter to measure the levels of carboxyhemoglobin (COHb) in smokers and non-smokers. Our goal was to determine if this device could not only define smoking status, but also to increase accuracy of self-reported data at various surveys on smoking. Thirty-four healthy volunteers participated in this study. Twenty-two of them were current daily smokers; 12 participants were non-smokers who lived alone or with a nonsmoker, and who worked in non-smoking environment. Nicotine dependency level was determined by the modified Fagerstrom questionnaire. Blood COHb levels were measured with a pulse CO-oximeter (Masimo, Radical 7). The COHb levels in both moderate/heavy smokers and light smokers increased significantly after they smoked a single cigarette. This increase persisted for more than 6 h in the moderate/heavy smokers, while in the light smokers COHb levels returned to the baseline level after one hour. The pulse rate of all smokers increased significantly 20 min after smoking. We conclude that the CO-oximeter can detect smoking by moderate/heavy smokers and light smokers if they smoked 6 h or 20 min earlier, respectively. We concluded that it could be used as a validation test for smoking at the time of admission to the surgical facility and to increase smoking abstinence during preoperative and postoperative periods. This noninvasive, simple and inexpensive test may also be used at various surveys to increase accuracy of self-reports on smoking.

Versatile pulse programmer for pulsed nuclear magnetic resonance spectroscopy

International Nuclear Information System (INIS)

Adduci, D.J.

1979-05-01

A description of the sequence of events and the decisions leading to the design of a versatile pulse programmer for pulsed NMR are presented. Background and application information is discussed in order that the reader might better understand the role of the pulse programmer in a NMR spectrometer. Various other design approaches are presented as a basis for comparison. Specifications for this design are proposed, the hardware implementation of the specifications is discussed, and the software operating system is presented

Versatile pulse programmer for pulsed nuclear magnetic resonance spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Adduci, D.J.

1979-05-01

A description of the sequence of events and the decisions leading to the design of a versatile pulse programmer for pulsed NMR are presented. Background and application information is discussed in order that the reader might better understand the role of the pulse programmer in a NMR spectrometer. Various other design approaches are presented as a basis for comparison. Specifications for this design are proposed, the hardware implementation of the specifications is discussed, and the software operating system is presented.

A compact bipolar pulse-forming network-Marx generator based on pulse transformers.

Science.gov (United States)

Zhang, Huibo; Yang, Jianhua; Lin, Jiajin; Yang, Xiao

2013-11-01

A compact bipolar pulse-forming network (PFN)-Marx generator based on pulse transformers is presented in this paper. The high-voltage generator consisted of two sets of pulse transformers, 6 stages of PFNs with ceramic capacitors, a switch unit, and a matched load. The design is characterized by the bipolar pulse charging scheme and the compact structure of the PFN-Marx. The scheme of bipolar charging by pulse transformers increased the withstand voltage of the ceramic capacitors in the PFNs and decreased the number of the gas gap switches. The compact structure of the PFN-Marx was aimed at reducing the parasitic inductance in the generator. When the charging voltage on the PFNs was 35 kV, the matched resistive load of 48 Ω could deliver a high-voltage pulse with an amplitude of 100 kV. The full width at half maximum of the load pulse was 173 ns, and its rise time was less than 15 ns.

The influence of pulse duration on the stress levels in ablation of ceramics: A finite element study

International Nuclear Information System (INIS)

Verde, A. Vila; Ramos, Marta M.D.

2006-01-01

We present a finite element model to investigate the dynamic thermal and mechanical response of ceramic materials to pulsed infrared radiation. The model was applied to the specific problem of determining the influence of the pulse duration on the stress levels reached in human dental enamel irradiated by a CO 2 laser at 10.6 μm with pulse durations between 0.1 and 100 μs and sub-ablative fluence. Our results indicate that short pulses with durations much larger than the characteristic acoustic relaxation time of the material can still cause high stress transients at the irradiated site, and indicate that pulse durations of the order of 10 μs may be more adequate both for enamel surface modification and for ablation than pulse durations up to 1 μs. The model presented here can easily be modified to investigate the dynamic response of ceramic materials to mid-infrared radiation and help determine optimal pulse durations for specific procedures

Numerical simulation of a TLD pulsed laser-heating scheme for determination of shallow dose and deep dose in low-LET radiation fields

International Nuclear Information System (INIS)

Kearfott, K.J.; Han, S.; Wagner, E.C.; Samei, E.; Wang, C.-K.C.

2000-01-01

A new method is described to determine the depth-dose distribution in low-LET radiation fields using a thick thermoluminescent dosimeter (TLD) with a pulsed laser-heating scheme to obtain TL glow output. The computational simulation entails heat conduction and glow curve production processes. An iterative algorithm is used to obtain the dose distribution in the detector. The simulation results indicate that the method can predict the shallow and deep dose in various radiation fields with relative errors less than 20%

Development of bipolar pulse accelerator for intense pulsed ion beam acceleration

International Nuclear Information System (INIS)

Fujioka, Y.; Mitsui, C.; Kitamura, I.; Takahashi, T.; Masugata, K.; Tanoue, H.; Arai, K.

2003-01-01

To improve the purity of an intense pulsed ion beams a new type of pulsed ion beam accelerator named 'bipolar pulse accelerator (BPA)' was proposed. In the accelerator purity of the beam is expected. To confirm the principle of the accelerator experimental system was developed. The system utilizes B y type magnetically insulated acceleration gap and operated with single polar negative pulse. A coaxial gas puff plasma gun placed in the grounded anode was used as an ion source, and source plasma (nitrogen) of current density approx. = 25 A/cm 2 , duration approx. = 1.5 μs was injected into the acceleration gap. The ions are successfully accelerated from the grounded anode to the drift tube by applying negative pulse of voltage 180 kV, duration 60 ns to the drift tube. Pulsed ion beam of current density approx. = 40 A/cm 2 , duration approx. 60 ns was obtained at 42 mm downstream from the anode surface. (author)

Producing High Intense Attosecond Pulse Train by Interaction of Three-Color Pulse and Overdense Plasma

Science.gov (United States)

Salehi, M.; Mirzanejad, S.

2017-05-01

Amplifying the attosecond pulse by the chirp pulse amplification method is impossible. Furthermore, the intensity of attosecond pulse is low in the interaction of laser pulse and underdense plasma. This motivates us to propose using a multi-color pulse to produce the high intense attosecond pulse. In the present study, the relativistic interaction of a three-color linearly-polarized laser-pulse with highly overdense plasma is studied. We show that the combination of {{ω }}1, {{ω }}2 and {{ω }}3 frequencies decreases the instance full width at half maximum reflected attosecond pulse train from the overdense plasma surface. Moreover, we show that the three-color pulse increases the intensity of generated harmonics, which is explained by the relativistic oscillating mirror model. The obtained results demonstrate that if the three-color laser pulse interacts with overdense plasma, it will enhance two orders of magnitude of intensity of ultra short attosecond pulses in comparison with monochromatic pulse.

Capacitor charging FET switcher with controller to adjust pulse width

Science.gov (United States)

Mihalka, Alex M.

1986-01-01

A switching power supply includes an FET full bridge, a controller to drive the FETs, a programmable controller to dynamically control final output current by adjusting pulse width, and a variety of protective systems, including an overcurrent latch for current control. Power MOSFETS are switched at a variable frequency from 20-50 kHz to charge a capacitor load from 0 to 6 kV. A ferrite transformer steps up the DC input. The transformer primary is a full bridge configuration with the FET switches and the secondary is fed into a high voltage full wave rectifier whose output is connected directly to the energy storage capacitor. The peak current is held constant by varying the pulse width using predetermined timing resistors and counting pulses. The pulse width is increased as the capacitor charges to maintain peak current. A digital ripple counter counts pulses, and after the desired number is reached, an up-counter is clocked. The up-counter output is decoded to choose among different resistors used to discharge a timing capacitor, thereby determining the pulse width. A current latch shuts down the supply on overcurrent due to either excessive pulse width causing transformer saturation or a major bridge fault, i.e., FET or transformer failure, or failure of the drive circuitry.

Interaction of Rydberg atoms with two contrapropagating ultrashort laser pulses

International Nuclear Information System (INIS)

Lugovskoy, A. V.; Bray, I.

2006-01-01

In this paper we investigate how Rydberg atoms respond to perturbation by two contrapropagating ultrashort laser pulses. We consider the case where the durations of both pulses τ 1 and τ 2 are shorter than the inverse of the initial-state energy ε i -1 . When acting alone such a pulse passes through the atom without noticeable alteration in the atomic state. The situation is different if two such pulses interfere in the region of atom localization. In this case the atomic response is significantly enhanced. This is due to the nonzero momentum transferred to the electron by the interplay of the electric field of one pulse and the magnetic field of the other. The sudden perturbation approximation is used to evaluate the transition probabilities. They are shown to depend on the atom position with respect to the pulse interference region. This dependence is determined by the relationship between the atomic diameter d i and the interference-region size l=c(τ 1 +τ 2 ) (c is the speed of light). If d i i >>l the transition probabilities are sensitive to the electron density distribution along the propagation direction. The probabilities of the initial-state destruction and atom ionization drop as l/d i irrespective of the characteristics of the pulses

The application of pulse shape discrimination in NE 213 to neutron spectrometry

International Nuclear Information System (INIS)

Perkins, L.J.; Scott, M.C.

1979-01-01

The use of a zero-crossing pulse shape discrimination technique to distinguish protons from alpha particles in NE 213 is described, and a theoretical analysis is performed to predict the zero crossing characteristics. It is shown that, irrespective of the particular method of pulse shape discrimination employed, the pulse shape at low energies no longer uniquely determines the particle type for electrons, protons, alpha particles or 12 C nuclei, and the general limitations of pulse shape discrimination in NE 213 are deduced. The use of an alpha discrimination technique is then discribed, enabling neutron spectra to be unfolded from the measured detector response using a differential code. (orig.)

Effect of sequential isoproturon pulse exposure on Scenedesmus vacuolatus.

Science.gov (United States)

Vallotton, Nathalie; Eggen, Rik Ilda Lambertus; Chèvre, Nathalie

2009-04-01

Aquatic organisms are typically exposed to fluctuating concentrations of herbicides in streams. To assess the effects on algae of repeated peak exposure to the herbicide isoproturon, we subjected the alga Scenedesmus vacuolatus to two sequential pulse exposure scenarios. Effects on growth and on the inhibition of the effective quantum yield of photosystem II (PSII) were measured. In the first scenario, algae were exposed to short, 5-h pulses at high isoproturon concentrations (400 and 1000 microg/l), each followed by a recovery period of 18 h, while the second scenario consisted of 22.5-h pulses at lower concentrations (60 and 120 microg/l), alternating with short recovery periods (1.5 h). In addition, any changes in the sensitivity of the algae to isoproturon following sequential pulses were examined by determining the growth rate-EC(50) prior to and following exposure. In both exposure scenarios, we found that algal growth and its effective quantum yield were systematically inhibited during the exposures and that these effects were reversible. Sequential pulses to isoproturon could be considered a sequence of independent events. Nevertheless, a consequence of inhibited growth during the repeated exposures is the cumulative decrease in biomass production. Furthermore, in the second scenario, when the sequence of long pulses began to approach a scenario of continuous exposure, a slight increase in the tolerance of the algae to isoproturon was observed. These findings indicated that sequential pulses do affect algae during each pulse exposure, even if algae recover between the exposures. These observations could support an improved risk assessment of fluctuating exposures to reversibly acting herbicides.

Concave pulse shaping of a circularly polarized laser pulse from non-uniform overdense plasmas

Energy Technology Data Exchange (ETDEWEB)

Hur, Min Sup [School of Natural Science, UNIST, BanYeon-Ri 100, Ulju-gun, Ulsan, 689-798 (Korea, Republic of); Kulagin, Victor V. [Sternberg Astronomical Institute, Moscow State University, Universitetsky prosp. 13, Moscow, 119992 (Russian Federation); Suk, Hyyong, E-mail: hysuk@gist.ac.kr [Department of Physics and Photon Science, GIST, 123 Cheomdan-gwangiro, Buk-gu, Gwangju, 500-712 (Korea, Republic of)

2015-03-20

Pulse shaping of circularly polarized laser pulses in nonuniform overdense plasmas are investigated numerically. Specifically we show by two-dimensional particle-in-cell simulations the generation of a concave pulse front of a circularly polarized, a few tens of petawatt laser pulse from a density-tapered, overdense plasma slab. The concept used for the transverse-directional shaping is the differential transmittance depending on the plasma density, and the laser intensity. For suitable selection of the slab parameters for the concave pulse shaping, we studied numerically the pulse transmittance, which can be used for further parameter design of the pulse shaping. The concavely shaped circularly polarized pulse is expected to add more freedom in controlling the ion-beam characteristics in the RPDA regime. - Highlights: • Laser pulse shaping for a concave front by non-uniform overdense plasma was studied. • Particle-in-cell (PIC) simulations were used for the investigation. • A laser pulse can be shaped by a density-tapered overdense plasma. • The concave and sharp pulse front are useful in many laser–plasma applications. • They are important for ion acceleration, especially in the radiation pressure dominant regime.

Long-pulse applications of pulse-forming lines for high-power linac application

International Nuclear Information System (INIS)

Hoeberling, R.F.; Tallerico, P.J.

1981-01-01

The ever present demands for high efficiency in the RF power stations for particle accelerators have caused increased interest in longer RF pulses (ten's of microseconds) for linacs such as the Pion Generator for Medical Irradiation (PIGMI) and Free Electron Laser (FEL). For either RF power station, a fundamental decision is whether to use a modulating anode/hard-tube driver or pulsed cathode/line-type pulser configuration. The choices in the extremes of low power for very long pulses or for very-high-power, short pulses are, respectively, a modulated anode/hard tube modulator and pulsed cathode/pulse forming line. However, the demarcation between these two extremes is not clearcut. The criteria (cost, flexibility performance, reliability, efficiency) that resulted in the RF station definition of these two specific systems will be described

Background subtraction system for pulsed neutron logging of earth boreholes

International Nuclear Information System (INIS)

Hertzog, R.C.

1983-01-01

The invention provides a method for determining the characteristics of earth formations surrounding a well borehole comprising the steps of: repetitively irradiating the earth formations surrounding the well bore with relatively short duration pulses of high energy neutrons; detecting during each pulse of high energy neutrons, gamma radiation due to the inelastic scattering of neutrons by materials comprising the earth formations surrounding the borehole and providing information representative thereof; detecting immediately following each such pulse of high energy neutrons, background gamma radiation due to thermal neutron capture and providing information representative thereof; and correcting the inelastic gamma representative information to compensate for said background representative information

Experimental study of rf pulsed heating

Directory of Open Access Journals (Sweden)

Lisa Laurent

2011-04-01

Full Text Available Cyclic thermal stresses produced by rf pulsed heating can be the limiting factor on the attainable reliable gradients for room temperature linear accelerators. This is especially true for structures that have complicated features for wakefield damping. These limits could be pushed higher by using special types of copper, copper alloys, or other conducting metals in constructing partial or complete accelerator structures. Here we present an experimental study aimed at determining the potential of these materials for tolerating cyclic thermal fatigue due to rf magnetic fields. A special cavity that has no electric field on the surface was employed in these studies. The cavity shape concentrates the magnetic field on one flat surface where the test material is placed. The materials tested in this study have included oxygen free electronic grade copper, copper zirconium, copper chromium, hot isostatically pressed copper, single crystal copper, electroplated copper, Glidcop®, copper silver, and silver plated copper. The samples were exposed to different machining and heat treatment processes prior to rf processing. Each sample was tested to a peak pulsed heating temperature of approximately 110°C and remained at this temperature for approximately 10×10^{6} rf pulses. In general, the results showed the possibility of pushing the gradient limits due to pulsed heating fatigue by the use of copper zirconium and copper chromium alloys.

Light pulse shapes from plastic scintillators

International Nuclear Information System (INIS)

Moszynski, M.; Bengtson, B.

1977-01-01

A detailed study of the light pulse shape from the binary NE 111 and the ternary Pilot U, Naton 136, KL 236, NE 102A, NE 104 and NE 110 plastic scintillators was performed by the single photon method using XP 1021 and C 31024 photomultipliers. The analysis of the shape of the light pulses determined experimentally for several samples of different dimensions gave the following conclusions. The original light pulse shape from the binary NE 111 scintillator, as measured with a 5 mm thick polished sample is described analytically by the convolution integral of a Gaussian and an exponential function. The Gaussian function may reflect a deexcitation of several higher levels of the solvent molecules excited by nuclear particles preceding an intermolecular energy transfer in the scintillator. It may introduce a rather important limitation of the speed of plastic scintillators as the standard deviation of the Gaussian function is equal to 0.2 ns. The light pulse shape from the ternary plastics is described by the convolution integral of a Gaussian and two exponential functions. The Gaussian function presents the rate of energy transfer from nuclear particles to the primary solute as in the binary plastics. The exponential functions describe the energy transfer from the primary solute to the wavelength shifter and the final emission of the light. (Auth.)

Simultaneous determination of paracetamol and ibuprofen in pharmaceutical samples by differential pulse voltammetry using a boron-doped diamond electrode

Energy Technology Data Exchange (ETDEWEB)

Lima, Amanda B.; Guimaraes, Carlos F.R.C.; Verly, Rodrigo M.; Silva, Leonardo M. da [Universidade Federal dos Vales do Jequitinhonha e Mucuri (UFVJM), Diamantina, MG (Brazil). Departamento de Quimica; Torres, Livia M.F.C.; Carvalho, Junior, Alvaro D.; Santos, Wallans T. P. dos, E-mail: wallanst@ufvjm.edu.br [Universidade Federal dos Vales do Jequitinhonha e Mucuri (UFVJM), Diamantina, MG (Brazil). Departamento de Farmacia

2014-03-15

This work presents a simple, fast and low-cost methodology for the simultaneous determination of paracetamol (PC) and ibuprofen (IB) in pharmaceutical formulations by differential pulse voltammetry using a boron-doped diamond (BDD) electrode. A well-defined oxidation peak was observed using the BDD electrode for each analyte (0.85 V for PC and 1.72 V for IB (vs. Ag/AgCl)) in 0.1 mol L{sup -1} H{sub 2}SO{sub 4} solution containing 10% (v/v) of ethanol. Calibration curves for the simultaneous determination of PC and IB showed a linear response for both drugs in a concentration range of 20 to 400 μmol L{sup -1} (r{sup 2} = 0.999), with a detection limit of 7.1 μmol L{sup -1} for PC and 3.8 μmol L{sup -1} for IB. The addition-recovery studies in samples were about 100% and the results were validated by chromatographic methods. (author)

[Determination of 44 organophosphorus pesticides in food by SPE disk extraction-capillary gas chromatography with pulsed flame photometric detection].

Science.gov (United States)

Luo, Xiao-Fei; Yang, Yuan; Sun, Cheng-Jun

2012-01-01

To develop a method for the simultaneous determination of 44 organophosphorus pesticides in food by SPE disk extraction-capillary gas chromatography with pulsed flame photometric detection. Organophosphorus pesticides in food were extracted ultrasonically with water. Then the extract was cleaned-up with SPE disk and eluted with ethyl acetate. Finally the eluent was condensed to 1mL under N2 at 55 degrees C. Gas chromatography was applied for quantitative detection of the organophosphorus pesticides in the sample. The linear range of the method for all the pesticides were in the range of 0.01-0.5 mg/kg with correlation coefficients of 0.992-1.000. The detection limits of the method were in the range of 0.0005-0.01 mg/kg. The recoveries for most pesticides were 60%-120% with relative standard deviations of less than 15%. The method is simple, sensitive, environmentally friendly and suitable for the determination of organophosphorous pesticides in food.

Simultaneous determination of paracetamol and ibuprofen in pharmaceutical samples by differential pulse voltammetry using a boron-doped diamond electrode

International Nuclear Information System (INIS)

Lima, Amanda B.; Guimaraes, Carlos F.R.C.; Verly, Rodrigo M.; Silva, Leonardo M. da; Torres, Livia M.F.C.; Carvalho Junior, Alvaro D.; Santos, Wallans T. P. dos

2014-01-01

This work presents a simple, fast and low-cost methodology for the simultaneous determination of paracetamol (PC) and ibuprofen (IB) in pharmaceutical formulations by differential pulse voltammetry using a boron-doped diamond (BDD) electrode. A well-defined oxidation peak was observed using the BDD electrode for each analyte (0.85 V for PC and 1.72 V for IB (vs. Ag/AgCl)) in 0.1 mol L -1 H 2 SO 4 solution containing 10% (v/v) of ethanol. Calibration curves for the simultaneous determination of PC and IB showed a linear response for both drugs in a concentration range of 20 to 400 μmol L -1 (r 2 = 0.999), with a detection limit of 7.1 μmol L -1 for PC and 3.8 μmol L -1 for IB. The addition-recovery studies in samples were about 100% and the results were validated by chromatographic methods. (author)

Transient thermal analysis of semiconductor diode lasers under pulsed operation

Science.gov (United States)

Veerabathran, G. K.; Sprengel, S.; Karl, S.; Andrejew, A.; Schmeiduch, H.; Amann, M.-C.

2017-02-01

Self-heating in semiconductor lasers is often assumed negligible during pulsed operation, provided the pulses are `short'. However, there is no consensus on the upper limit of pulse width for a given device to avoid-self heating. In this paper, we present an experimental and theoretical analysis of the effect of pulse width on laser characteristics. First, a measurement method is introduced to study thermal transients of edge-emitting lasers during pulsed operation. This method can also be applied to lasers that do not operate in continuous-wave mode. Secondly, an analytical thermal model is presented which is used to fit the experimental data to extract important parameters for thermal analysis. Although commercial numerical tools are available for such transient analyses, this model is more suitable for parameter extraction due to its analytical nature. Thirdly, to validate this approach, it was used to study a GaSb-based inter-band laser and an InP-based quantum cascade laser (QCL). The maximum pulse-width for less than 5% error in the measured threshold currents was determined to be 200 and 25 ns for the GaSb-based laser and QCL, respectively.

Subluminal and superluminal pulse propagation in inhomogeneous media of nonspherical particles

International Nuclear Information System (INIS)

Ma Yu; Gao Lei

2006-01-01

We study the pulse propagation through a metal/dielectric composites of nonspherical particles enclosed by two gold mirrors. To account for the shape effect, we first adopt Maxwell-Garnett type approximation to obtain the effective dielectric function of composites. Based on the group index, phase time and pulse shape calculations, we find that the particles' shape (characterized by the depolarization factor) plays an important role in determining the subluminal and superluminal pulse propagations through the system. When the inclusions' shape is not spherical, it is possible to observe significant superluminal behavior of the pulse propagation, although the volume fraction is the same. The shape-dependent critical volume fraction is predicted, above which superluminal propagation appears. Furthermore, the Hartman effect in such a system is also investigated

Ultrashort pulse chirp measurement via transverse second-harmonic generation in strontium barium niobate crystal

Energy Technology Data Exchange (ETDEWEB)

Trull, J.; Wang, B.; Parra, A.; Vilaseca, R.; Cojocaru, C. [Departament de Física i Enginyeria Nuclear, Universitat Politècnica Catalunya, Terrassa 08222 (Spain); Sola, I. [Grupo de Investigación en Óptica Extrema (GIOE), Departamento de Física Aplicada, Universidad de Salamanca, Plaza de la Merced s/n, 37008 Salamanca (Spain); Krolikowski, W. [Laser Physics Centre, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Science Program, Texas A and M University at Qatar, Doha (Qatar); Sheng, Y. [Laser Physics Centre, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia)

2015-06-01

Pulse compression in dispersive strontium barium niobate crystal with a random size and distribution of the anti-parallel orientated nonlinear domains is observed via transverse second harmonic generation. The dependence of the transverse width of the second harmonic trace along the propagation direction allows for the determination of the initial chirp and duration of pulses in the femtosecond regime. This technique permits a real-time analysis of the pulse evolution and facilitates fast in-situ correction of pulse chirp acquired in the propagation through an optical system.

Ultrashort pulse chirp measurement via transverse second-harmonic generation in strontium barium niobate crystal

International Nuclear Information System (INIS)

Trull, J.; Wang, B.; Parra, A.; Vilaseca, R.; Cojocaru, C.; Sola, I.; Krolikowski, W.; Sheng, Y.

2015-01-01

Pulse compression in dispersive strontium barium niobate crystal with a random size and distribution of the anti-parallel orientated nonlinear domains is observed via transverse second harmonic generation. The dependence of the transverse width of the second harmonic trace along the propagation direction allows for the determination of the initial chirp and duration of pulses in the femtosecond regime. This technique permits a real-time analysis of the pulse evolution and facilitates fast in-situ correction of pulse chirp acquired in the propagation through an optical system

Risk Assessment of a Synthetic Pyrethroid, Bifenthrin on Pulses

OpenAIRE

Mukherjee, Irani; Singh, Ranbir; Govil, J. N.

2010-01-01

This work was undertaken to determine the pre-harvest interval of bifenthrin and to minimize its residues in pulses and thereby ensure consumer safety and avoid non-compliance in terms of residues violations in export market. Furthermore the residue dynamics in the soil under pulses was explored to assess the environmental safety. The residues of bifenthrin dissipated following first order kinetics. The residues in harvest time grains were below the maximum residue limit (MRL) of 0.02?mg/kg a...

Development of bipolar-pulse accelerator for intense pulsed ion beam acceleration

Energy Technology Data Exchange (ETDEWEB)

Masugata, Katsumi [Department of Electrical and Electronic System Engineering, Toyama University, 3190 Gofuku, Toyama 930-8555 (Japan)]. E-mail: masugata@eng.toyama-u.ac.jp; Shimizu, Yuichro [Department of Electrical and Electronic System Engineering, Toyama University, 3190 Gofuku, Toyama 930-8555 (Japan); Fujioka, Yuhki [Department of Electrical and Electronic System Engineering, Toyama University, 3190 Gofuku, Toyama 930-8555 (Japan); Kitamura, Iwao [Department of Electrical and Electronic System Engineering, Toyama University, 3190 Gofuku, Toyama 930-8555 (Japan); Tanoue, Hisao [National Institute of Advanced Industry Science and Technology, 1-1-1, Umezono, Tsukuba-shi, Ibaraki 305-8568 (Japan); Arai, Kazuo [National Institute of Advanced Industry Science and Technology, 1-1-1, Umezono, Tsukuba-shi, Ibaraki 305-8568 (Japan)

2004-12-21

To improve the purity of intense pulsed ion beams, a new type of pulsed ion beam accelerator named 'bipolar pulse accelerator' was proposed. To confirm the principle of the accelerator a prototype of the experimental system was developed. The system utilizes By type magnetically insulated acceleration gap and operated with single polar negative pulse. A coaxial gas puff plasma gun was used as an ion source, which was placed inside the grounded anode. Source plasma (nitrogen) of current density {approx}25A/cm2, duration {approx}1.5{mu}s was injected into the acceleration gap by the plasma gun. The ions were successfully accelerated from the grounded anode to the drift tube by applying negative pulse of voltage 240kV, duration 100ns to the drift tube. Pulsed ion beam of current density {approx}40A/cm2, duration {approx}50ns was obtained at 41mm downstream from the anode surface. To evaluate the irradiation effect of the ion beam to solid material, an amorphous silicon thin film of thickness {approx}500nm was used as the target, which was deposited on the glass substrate. The film was found to be poly-crystallized after 4-shots of the pulsed nitrogen ion beam irradiation.

Detection of movement artifact in recorded pulse oximeter saturation.

Science.gov (United States)

Poets, C F; Stebbens, V A

1997-10-01

Movement artifact (MA) must be detected when analysing recordings of pulse oximeter saturation (SpO2). Visual analysis of individual pulse waveforms is the safest, but also the most tedious, method for this purpose. We wanted to test the reliability of a computer algorithm (Edentec Motion Annotation System), based on a comparison between pulse and heart rate, for MA detection. Ten 12-h recordings of SpO2, pulse waveforms and heart rate from ten preterm infants were analysed for the presence of MA on the pulse waveform signal. These data were used to determine the sensitivity and specificity of the computer algorithm, and of the oximeter itself, in detecting MA. Recordings were divided into segments of 2.5 s duration to compare the movement identification methods. Of the segments 31% +/- 6% (mean +/- SD) contained MA. The computer algorithm identified 95% +/- 3% of these segments, the pulse oximeter only 18% +/- 11%. Specificity was 85% +/- 4% and 99% +/- 0%, respectively. SpO2 was signal showed MA during this time, leaving a significant potential for erroneous identification of hypoxaemia. Recordings of SpO2 do not allow a reliable identification of MA. Without additional information about movement artifact, a significant proportion of recording time of pulse oximeter signal may be regarded as demonstrating hypoxaemia which, in fact, simply reflects poor measurement conditions. The computer algorithm used in this study identified periods of movement artifact reliably.

Low-induction pulse current generator with a volume bus arrangement

International Nuclear Information System (INIS)

Bocharov, Yu.N.; Krivosheev, S.I.; Lapin, N.G.; Shneerson, G.A.

1993-01-01

Pulse current generator (PC6) with 38 kj stored energy designed for up to 50 kV charging voltage used to obtain magnetic fields within megagauss range, is described. Space (volume) bus arrangement of its modules is used to reduce eigen inductance of PC6. Current is commutated by solid-body spark gaps. Under 3uH inductive load PC6 provides for formation of up to 2.25 MA current pulse with 3.3x10 12 A/s pulse rise time. Technique to determine low inductances as applied to PC6 elements is described. The described PC6 is used for experiments on generation of super-strong pulse magnetic fields in single-loop solenoid with volume occupied by magnetic field, 5-7 mm. Magnetic field with up to 350 T induction amplitude is obtained in these experiments

Process Control of Pre-Sowing Seed Treatment by Pulsed Electric Field

Directory of Open Access Journals (Sweden)

Starodubtseva Galina Petrovna

2018-03-01

Full Text Available Presented paper investigates the application of a line voltage changer to an installation for pre-sowing seed treatment by pulsed electric field (PEF in order to increase the sowing quality of seeds and to suppress pathogenic microflora. The installation comprises an AC voltage regulator, a high voltage source, a voltage inverter, a working chamber for seed treatment, a control unit, and current and voltage sensors. The proposed installation differs from the existing apparatuses as it automatically provides the transformation of the pulsed electric field parameters by constant monitoring of power processes in a layer of treated seeds and feedback sending to the control unit. Seed treatment efficiency depends on the dose being determined by the parameters of electric field, namely, intensity in the seed layer, pulse duration, pulse repetition frequency, and seed treatment time. The parameters of rational treatment were determined, and the minimum treatment dose was calculated on the basis of results from the laboratory tests on the effect of pulsed electric field on sowing qualities of winter wheat seeds. It was experimentally confirmed that the proposed installation provides automatic transformation of electric field parameters depending on the changes taking place in the seed layer on the example of seeds with different moisture content maintaining the necessary treatment dose, ensuring the stability and repeatability of results.

A pilot study of the applicability of polarography to exposure and bioremediation problems in aquatic systems

International Nuclear Information System (INIS)

Bundy, K.

1993-01-01

This project has demonstrated the feasibility of using polarographic techniques to study pollution in Louisiana waters and has developed methodology for this purpose. Water and sediment samples from Devil's Swamp have been fractionated and analyzed for heavy metal concentration using differential pulse polarography. Lead has been found to be quite inhomogeneously distributed in the environment, with much higher concentrations being found in sediments and in suspended particulate form in the water, as opposed to being chemically dissolved in the aqueous phase. A laboratory study is planned in which an animal model will be used in controlled experiments to investigate internal organ uptake of heavy metals. The research proposed for next year includes collaborative efforts with two of the cluster groups involved with the DOE/EM project

Erbium:ytterbium fiber-laser system delivering watt-level femtosecond pulses using divided pulse amplification

Science.gov (United States)

Herda, Robert; Zach, Armin

2015-03-01

We present an Erbium:Ytterbium codoped fiber-amplifer system based on Divided-Pulses-Amplification (DPA) for ultrashort pulses. The output from a saturable-absorber mode-locked polarization-maintaining (PM) fiber oscillator is amplified in a PM normal-dispersion Erbium-doped fiber. After this stage the pulses are positively chirped and have a duration of 2.0 ps at an average power of 93 mW. A stack of 5 birefringent Yttrium-Vanadate crystals divides these pulses 32 times. We amplify these pulses using a double-clad Erbium:Ytterbium codoped fiber pumped through a multimode fiber combiner. The pulses double pass the amplifier and recombine in the crystals using non-reciprocal polarization 90° rotation by a Faraday rotating mirror. Pulses with a duration of 144 fs are obtained after separation from the input beam using a polarizing beam splitter cube. These pulses have an average power of 1.85 W at a repetition rate of 80 MHz. The generation of femtosecond pulses directly from the amplifier was enabled by a positively chirped seed pulse, normally dispersive Yttrium-Vanadate crystals, and anomalously dispersive amplifier fibers. Efficient frequency doubling to 780 nm with an average power of 725 mW and a pulse duration of 156 fs is demonstrated. In summary we show a DPA setup that enables the generation of femtosecond pulses at watt-level at 1560 nm without the need for further external dechirping and demonstrate a good pulse quality by efficient frequency doubling. Due to the use of PM fiber components and a Faraday rotator the setup is environmentally stable.

Investigation of pulsed barrier discharge in water-air gap

International Nuclear Information System (INIS)

Taran, V.S.; Krasnyj, V.V.; Lozina, A.S.; Shvets, O.M.

2013-01-01

This article presents the results of the use of a pulsed dielectric barrier discharge with water electrode and diaphragm. The spectroscopic and electrical investigations of such discharge were conducted. The ozone concentration in an aqueous solution comprised 0.7 mg/l with high-voltage pulsed power at 120 W. The discharge reviewed emission spectrum lines of molecular nitrogen and hydroxyl radicals in the range of 200...800 nm in the water-air gap. The intensity changing of luminescence lines of OH and N 2 singles depending on the applied voltage and discharge gap has been determined. Aqueous solution of indigo was used in order to determine the impact level on the organic material. Experiments on inactivation of test E. coli cultures have been carried out.

Pulse radiolysis of anthraquinone dye aqueous solution

International Nuclear Information System (INIS)

Perkowski, J.; Gebicki, J.L.; Lubis, R.; Mayer, J.

1988-01-01

Pulse radiolysis of argon flushed aqueous solutions of 10 -5 -10 -4 mol dm -3 anthraquinone dye (C.I. Acid Blue 62) gives rise to the transients originated from the reactions of e - aq , OH and H. The rate constants of these reactions are determined. (author)

Repeated pulsed x-ray emission equipment

International Nuclear Information System (INIS)

Terauchi, Hikaru; Iida, Satoshi

1982-01-01

X-ray diffraction technique has been applied to determine the spatial positions of atoms which compose a material, and it is needless to say that the technique is a fundamental means regardless of the fields of research. However, the application of X-ray diffraction to the research on physical properties has been so far limited to know the spatial positions of atoms or molecules under thermal equilibrium condition. The addition of time element to the conventional technique, that is, the analysis of material structure including the time-varying processes under non-equilibrium conditions, is considered to approach the elucidation of the essence of materials. The authors call this dynamic structural analysis. The authors have planned to analyze X-ray diffraction intensity which has the resolution of about 10 -8 s in the real time which is conjugate with energy. However, present pulsed X-ray sources are not suitable for diffraction experiment because the pulse width is too long or X-ray wavelength is too short. Accordingly, the authors have made for trial a pulsed X-ray source for diffraction experiment. Its specifications are: diode voltage (X-ray tube voltage) from 200 to 300 kV, diode current from 2 to 5 kA, pulse width of about 30ns, maximum repetition frequency 10 pps, and X-ray focus size of 2 mm diameter. One of the features of this source is the repeated generation of pulsed X-ray. This is the first trial in the world, and is indispensable to the dynamic structural analysis described above. The quality of the emitted X-ray is also written. (Wakatsuki, Y.)

DogPulse

DEFF Research Database (Denmark)

Skovgaard, Christoffer; Thomsen, Josephine Raun; Verdezoto, Nervo

2015-01-01

This paper presents DogPulse, an ambient awareness system to support the coordination of dog walking among family members at home. DogPulse augments a dog collar and leash set to activate an ambient shape-changing lamp and visualize the last time the dog was taken for a walk. The lamp gradually...... changes its form and pulsates its lights in order to keep the family members aware of the dog walking activity. We report the iterative prototyping of DogPulse, its implementation and its preliminary evaluation. Based on our initial findings, we present the limitations and lessons learned as well...

High Dynamic Velocity Range Particle Image Velocimetry Using Multiple Pulse Separation Imaging

Directory of Open Access Journals (Sweden)

Tadhg S. O’Donovan

2010-12-01

Full Text Available The dynamic velocity range of particle image velocimetry (PIV is determined by the maximum and minimum resolvable particle displacement. Various techniques have extended the dynamic range, however flows with a wide velocity range (e.g., impinging jets still challenge PIV algorithms. A new technique is presented to increase the dynamic velocity range by over an order of magnitude. The multiple pulse separation (MPS technique (i records series of double-frame exposures with different pulse separations, (ii processes the fields using conventional multi-grid algorithms, and (iii yields a composite velocity field with a locally optimized pulse separation. A robust criterion determines the local optimum pulse separation, accounting for correlation strength and measurement uncertainty. Validation experiments are performed in an impinging jet flow, using laser-Doppler velocimetry as reference measurement. The precision of mean flow and turbulence quantities is significantly improved compared to conventional PIV, due to the increase in dynamic range. In a wide range of applications, MPS PIV is a robust approach to increase the dynamic velocity range without restricting the vector evaluation methods.

High dynamic velocity range particle image velocimetry using multiple pulse separation imaging.

Science.gov (United States)

Persoons, Tim; O'Donovan, Tadhg S

2011-01-01

The dynamic velocity range of particle image velocimetry (PIV) is determined by the maximum and minimum resolvable particle displacement. Various techniques have extended the dynamic range, however flows with a wide velocity range (e.g., impinging jets) still challenge PIV algorithms. A new technique is presented to increase the dynamic velocity range by over an order of magnitude. The multiple pulse separation (MPS) technique (i) records series of double-frame exposures with different pulse separations, (ii) processes the fields using conventional multi-grid algorithms, and (iii) yields a composite velocity field with a locally optimized pulse separation. A robust criterion determines the local optimum pulse separation, accounting for correlation strength and measurement uncertainty. Validation experiments are performed in an impinging jet flow, using laser-Doppler velocimetry as reference measurement. The precision of mean flow and turbulence quantities is significantly improved compared to conventional PIV, due to the increase in dynamic range. In a wide range of applications, MPS PIV is a robust approach to increase the dynamic velocity range without restricting the vector evaluation methods.

Ultrafast pulse amplification in mode-locked vertical external-cavity surface-emitting lasers

Energy Technology Data Exchange (ETDEWEB)

Böttge, C. N., E-mail: boettge@optics.arizona.edu; Hader, J.; Kilen, I.; Moloney, J. V. [College of Optical Sciences, The University of Arizona, 1630 E. University Blvd., Tucson, Arizona 85721 (United States); Koch, S. W. [College of Optical Sciences, The University of Arizona, 1630 E. University Blvd., Tucson, Arizona 85721 (United States); Department of Physics and Material Sciences Center, Philipps-Universität Marburg, Renthof 5, 35032 Marburg (Germany)

2014-12-29

A fully microscopic many-body Maxwell–semiconductor Bloch model is used to investigate the influence of the non-equilibrium carrier dynamics on the short-pulse amplification in mode-locked semiconductor microlaser systems. The numerical solution of the coupled equations allows for a self-consistent investigation of the light–matter coupling dynamics, the carrier kinetics in the saturable absorber and the multiple-quantum-well gain medium, as well as the modification of the light field through the pulse-induced optical polarization. The influence of the pulse-induced non-equilibrium modifications of the carrier distributions in the gain medium and the saturable absorber on the single-pulse amplification in the laser cavity is identified. It is shown that for the same structure, quantum wells, and gain bandwidth the non-equilibrium carrier dynamics lead to two preferred operation regimes: one with pulses in the (sub-)100 fs-regime and one with multi-picosecond pulses. The recovery time of the saturable absorber determines in which regime the device operates.

High-power noise-like pulse generation using a 1.56-µm all-fiber laser system.

Science.gov (United States)

Lin, Shih-Shian; Hwang, Sheng-Kwang; Liu, Jia-Ming

2015-07-13

We demonstrated an all-fiber, high-power noise-like pulse laser system at the 1.56-µm wavelength. A low-power noise-like pulse train generated by a ring oscillator was amplified using a two-stage amplifier, where the performance of the second-stage amplifier determined the final output power level. The optical intensity in the second-stage amplifier was managed well to avoid not only the excessive spectral broadening induced by nonlinearities but also any damage to the device. On the other hand, the power conversion efficiency of the amplifier was optimized through proper control of its pump wavelength. The pump wavelength determines the pump absorption and therefore the power conversion efficiency of the gain fiber. Through this approach, the average power of the noise-like pulse train was amplified considerably to an output of 13.1 W, resulting in a power conversion efficiency of 36.1% and a pulse energy of 0.85 µJ. To the best of our knowledge, these amplified pulses have the highest average power and pulse energy for noise-like pulses in the 1.56-µm wavelength region. As a result, the net gain in the cascaded amplifier reached 30 dB. With peak and pedestal widths of 168 fs and 61.3 ps, respectively, for the amplified pulses, the pedestal-to-peak intensity ratio of the autocorrelation trace remains at the value of 0.5 required for truly noise-like pulses.

Saturation of subjective reward magnitude as a function of current and pulse frequency.

Science.gov (United States)

Simmons, J M; Gallistel, C R

1994-02-01

In rats with electrodes in the medial forebrain bundle, the upper portion of the function relating the experienced magnitude of the reward to pulse frequency was determined at currents ranging from 100 to 1,000 microA. The pulse frequency required to produce an asymptotic level of reward was inversely proportional to current except at the lowest currents and highest pulse frequencies. At a given current, the subjective reward magnitude functions decelerated to an asymptote over an interval in which the pulse frequency doubled or tripled. The asymptotic level of reward was approximately constant for currents between 200 and 1,000 microA but declined substantially at currents at or below 100 microA and pulse frequencies at or above 250 to 400 pulses per second. The results are consistent with the hypothesis that the magnitude of the experienced reward depends only on the number of action potentials generated by the train of pulses in the bundle of reward-relevant axons.

Optimization methods of pulse-to-pulse alignment using femtosecond pulse laser based on temporal coherence function for practical distance measurement

Science.gov (United States)

Liu, Yang; Yang, Linghui; Guo, Yin; Lin, Jiarui; Cui, Pengfei; Zhu, Jigui

2018-02-01

An interferometer technique based on temporal coherence function of femtosecond pulses is demonstrated for practical distance measurement. Here, the pulse-to-pulse alignment is analyzed for large delay distance measurement. Firstly, a temporal coherence function model between two femtosecond pulses is developed in the time domain for the dispersive unbalanced Michelson interferometer. Then, according to this model, the fringes analysis and the envelope extraction process are discussed. Meanwhile, optimization methods of pulse-to-pulse alignment for practical long distance measurement are presented. The order of the curve fitting and the selection of points for envelope extraction are analyzed. Furthermore, an averaging method based on the symmetry of the coherence function is demonstrated. Finally, the performance of the proposed methods is evaluated in the absolute distance measurement of 20 μ m with path length difference of 9 m. The improvement of standard deviation in experimental results shows that these approaches have the potential for practical distance measurement.

Key technology research of nuclear signal digitized pulse shaping in real time

International Nuclear Information System (INIS)

Zhou Jianbin; Wang Min; Zhou Wei; Zhu Xing; Liu Yi; Chen Bao; Lu Baoping; Yue Aizhong; Qin Li; He Xuxin

2014-01-01

The computer simulation and analysis were carried out for the ideal nuclear pulse signal and the actual detector output signals, and the determination method of digital trapezoidal shape parameter for different nuclear pulse shaping time was summarized. At high count rate measurement occasion, the effective count rate is increased, some pile-up pulses are eliminated and the accumulation of dead time of the system is reduced. Meanwhile, Si-PIN semiconductor detector performance was tested by 256 points and 512 points digital triangle forming methods and the analog circuit forming methods for comparative tests. Test results show that the pulse forming treatment method increases the count rate performance and the resolution of detector. (authors)

Pulse frequency in pulsed brachytherapy based on tissue repair kinetics

International Nuclear Information System (INIS)

Sminia, Peter; Schneider, Christoph J.; Koedooder, Kees; Tienhoven, Geertjan van; Blank, Leo E.C.M.; Gonzalez Gonzalez, Dionisio

1998-01-01

Purpose: Investigation of normal tissue sparing in pulsed brachytherapy (PB) relative to continuous low-dose rate irradiation (CLDR) by adjusting pulse frequency based on tissue repair characteristics. Method: Using the linear quadratic model, the relative effectiveness (RE) of a 20 Gy boost was calculated for tissue with an α/β ratio ranging from 2 to 10 Gy and a half-time of sublethal damage repair between 0.1 and 3 h. The boost dose was considered to be delivered either in a number of pulses varying from 2 to 25, or continuously at a dose rate of 0.50, 0.80, or 1.20 Gy/h. Results: The RE of 20 Gy was found to be identical for PB in 25 pulses of 0.80 Gy each h and CLDR delivered at 0.80 Gy/h for any α/β value and for a repair half-time > 0.75 h. When normal tissue repair half-times are assumed to be longer than tumor repair half-times, normal tissue sparing can be obtained, within the restriction of a fixed overall treatment time, with higher dose per pulse and longer period time (time elapsed between start of pulse n and start of pulse n + 1). An optimum relative normal tissue sparing larger than 10% was found with 4 pulses of 5 Gy every 8 h. Hence, a therapeutic gain might be obtained when changing from CLDR to PB by adjusting the physical dose in such a way that the biological dose on the tumor is maintained. The normal tissue-sparing phenomenon can be explained by an increase in RE with longer period time for tissue with high α/β ratio and fast or intermediate repair half-time, and the RE for tissue with low α/β ratio and long repair half-time remains almost constant. Conclusion: Within the benchmark of the LQ model, advantage in normal tissue-sparing is expected when matching the pulse frequency to the repair kinetics of the normal tissue exposed. A period time longer than 1 h may lead to a reduction of late normal tissue complications. This theoretical advantage emphasizes the need for better knowledge of human tissue-repair kinetics

Forward voltage short-pulse technique for measuring high power laser array junction temperature

Science.gov (United States)

Meadows, Byron L. (Inventor); Amzajerdian, Frazin (Inventor); Barnes, Bruce W. (Inventor); Baker, Nathaniel R. (Inventor)

2012-01-01

The present invention relates to a method of measuring the temperature of the P-N junction within the light-emitting region of a quasi-continuous-wave or pulsed semiconductor laser diode device. A series of relatively short and low current monitor pulses are applied to the laser diode in the period between the main drive current pulses necessary to cause the semiconductor to lase. At the sufficiently low current level of the monitor pulses, the laser diode device does not lase and behaves similar to an electronic diode. The voltage across the laser diode resulting from each of these low current monitor pulses is measured with a high degree of precision. The junction temperature is then determined from the measured junction voltage using their known linear relationship.

Controlling output pulse and prepulse in a resonant microwave pulse compressor

International Nuclear Information System (INIS)

Shlapakovski, A.; Artemenko, S.; Chumerin, P.; Yushkov, Yu.

2013-01-01

A resonant microwave pulse compressor with a waveguide H-plane-tee-based energy extraction unit was studied in terms of its capability to produce output pulses that comprise a low-power long-duration (prepulse) and a high-power short-duration part. The application of such combined pulses with widely variable prepulse and high-power pulse power and energy ratios is of interest in the research area of electronic hardware vulnerability. The characteristics of output radiation pulses are controlled by the variation of the H-plane tee transition attenuation at the stage of microwave energy storage in the compressor cavity. Results of theoretical estimations of the parameters tuning range and experimental investigations of the prototype S-band compressor (1.5 MW, 12 ns output pulse; ∼13.2 dB gain) are presented. The achievable maximum in the prepulse power is found to be about half the power of the primary microwave source. It has been shown that the energy of the prepulse becomes comparable with that of the short-duration (nanosecond) pulse, while the power of the latter decreases insignificantly. The possible range of variation of the prepulse power and energy can be as wide as 40 dB. In the experiments, the prepulse level control within the range of ∼10 dB was demonstrated.

Taking the Pulse of Protein Interactions by EPR Spectroscopy

OpenAIRE

Cafiso, David S.

2012-01-01

An article by Gaffney et al. in this issue establishes a method using pulse electron paramagnetic resonance spectroscopy to determine the location of protein substrates or binding partners with high precision.

Dynamics of traveling reaction pulses

International Nuclear Information System (INIS)

Dovzhenko, A. Yu.; Rumanov, E. N.

2007-01-01

The growth of activator losses is accompanied by the decay of a traveling reaction pulse. In a ring reactor, this propagation threshold is present simultaneously with a threshold related to the ring diameter. The results of numerical experiments with pulses of an exothermal reaction reveal the transition from pulse propagation to a homogeneous hot regime, established regimes with periodic variations of the pulse velocity, and oscillatory decay of the pulse. When the medium becomes 'bistable' as a result of the variation in parameters, this factor does not prevent the propagation of pulses, but leads to changes in the pulse structure

River water remediation using pulsed corona, pulsed spark or ozonation

Energy Technology Data Exchange (ETDEWEB)

Izdebski, T.; Dors, M. [Polish Academy of Sciences, Szewalski Inst. of Fluid Flow Machiney, Fiszera (Poland). Centre for Plasma and Laser Engineering; Mizeraczyk, J. [Polish Academy of Sciences, Szewalski Inst. of Fluid Flow Machiney, Fiszera (Poland). Centre for Plasma and Laser Engineering; Gdynia Maritime Univ., Morska (Poland). Dept. of Marine Electronics

2010-07-01

The most common reason for epidemic formation is the pollution of surface and drinking water by wastewater bacteria. Pathogenic microorganisms that form the largest part of this are fecal bacteria, such as escherichia coli (E. coli). Wastewater treatment plants reduce the amount of the fecal bacteria by 1-3 orders of magnitude, depending on the initial number of bacteria. There is a lack of data on waste and drinking water purification by the electrohydraulic discharges method, which causes the destruction and inactivation of viruses, yeast, and bacteria. This paper investigated river water cleaning from microorganisms using pulsed corona, spark discharge and ozonization. The paper discussed the experimental setup and results. It was concluded that ozonization is the most efficient method of water disinfection as compared with pulsed spark and pulsed corona discharges. The pulsed spark discharge in water was capable of killing all microorganism similarly to ozonization, but with much lower energy efficiency. The pulsed corona discharge was found to be the less effective method of water disinfection. 21 refs., 4 figs.

Physical model of reactor pulse

International Nuclear Information System (INIS)

Petrovic, A.; Ravnik, M.

2004-01-01

Pulse experiments have been performed at J. Stefan Institute TRIGA reactor since 1991. In total, more than 130 pulses have been performed. Extensive experimental information on the pulse physical characteristics has been accumulated. Fuchs-Hansen adiabatic model has been used for predicting and analysing the pulse parameters. The model is based on point kinetics equation, neglecting the delayed neutrons and assuming constant inserted reactivity in form of step function. Deficiencies of the Fuchs-Hansen model and systematic experimental errors have been observed and analysed. Recently, the pulse model was improved by including the delayed neutrons and time dependence of inserted reactivity. The results explain the observed non-linearity of the pulse energy for high pulses due to finite time of pulse rod withdrawal and the contribution of the delayed neutrons after the prompt part of the pulse. The results of the improved model are in good agreement with experimental results. (author)

Dual-Pulse Pulse Position Modulation (DPPM) for Deep-Space Optical Communications: Performance and Practicality Analysis

Science.gov (United States)

Li, Jing; Hylton, Alan; Budinger, James; Nappier, Jennifer; Downey, Joseph; Raible, Daniel

2012-01-01

Due to its simplicity and robustness against wavefront distortion, pulse position modulation (PPM) with photon counting detector has been seriously considered for long-haul optical wireless systems. This paper evaluates the dual-pulse case and compares it with the conventional single-pulse case. Analytical expressions for symbol error rate and bit error rate are first derived and numerically evaluated, for the strong, negative-exponential turbulent atmosphere; and bandwidth efficiency and throughput are subsequently assessed. It is shown that, under a set of practical constraints including pulse width and pulse repetition frequency (PRF), dual-pulse PPM enables a better channel utilization and hence a higher throughput than it single-pulse counterpart. This result is new and different from the previous idealistic studies that showed multi-pulse PPM provided no essential information-theoretic gains than single-pulse PPM.

Single pulse analysis of intracranial pressure for a hydrocephalus implant.

Science.gov (United States)

Elixmann, I M; Hansinger, J; Goffin, C; Antes, S; Radermacher, K; Leonhardt, S

2012-01-01

The intracranial pressure (ICP) waveform contains important diagnostic information. Changes in ICP are associated with changes of the pulse waveform. This change has explicitly been observed in 13 infusion tests by analyzing 100 Hz ICP data. An algorithm is proposed which automatically extracts the pulse waves and categorizes them into predefined patterns. A developed algorithm determined 88 %±8 % (mean ±SD) of all classified pulse waves correctly on predefined patterns. This algorithm has low computational cost and is independent of a pressure drift in the sensor by using only the relationship between special waveform characteristics. Hence, it could be implemented on a microcontroller of a future electromechanic hydrocephalus shunt system to control the drainage of cerebrospinal fluid (CSF).

Emission properties of diode laser bars during pulsed high-power operation

International Nuclear Information System (INIS)

Hempel, Martin; Tomm, Jens W; Elsaesser, Thomas; Hennig, Petra

2011-01-01

High-power diode laser bars (cm-bars) are subjected to single pulse step tests carried out up to and beyond their ultimate limits of operation. Laser nearfields and thermal behaviour are monitored for pulse widths in the 10–100 µs range with streak- and thermo-cameras, respectively. Thresholds of catastrophic optical damage are determined, and their dependence on the length of the injected current pulses is explained qualitatively. This approach permits testing the hardness of facet coatings of cm-bars with or without consideration of accidental single pre-damaged emitter failure effects and thermal crosstalk between the emitters. This allows for the optimization of pulsed operation parameters, helps limiting sudden degradation and provides insight into the mechanisms governing the device emission behaviour at ultimate output powers. (fast track communication)

Controlled generation of a single Trichel pulse and a series of single Trichel pulses in air

Science.gov (United States)

Mizeraczyk, Jerzy; Berendt, Artur; Akishev, Yuri

2018-04-01

In this paper, a simple method for the controlled generation of a single Trichel pulse or a series of single Trichel pulses of a regulated repetition frequency in air is proposed. The concept of triggering a single Trichel pulse or a series of such pulses is based on the precise controlling the voltage inception of the negative corona, which can be accomplished through the use of a ramp voltage pulse or a series of such pulses with properly chosen ramp voltage pulse parameters (rise and fall times, and ramp voltage pulse repetition frequency). The proposal has been tested in experiments using a needle-to-plate electrode arrangement in air, and reproducible Trichel pulses (single or in a series) were obtained by triggering them with an appropriately designed voltage waveform. The proposed method and results obtained have been qualitatively analysed. The analysis provides guidance for designing the voltage ramp pulse in respect of the generation of a single Trichel pulse or a series of single Trichel pulses. The controlled generation of a single Trichel pulse or a series of such pulses would be a helpful research tool for the refined studies of the fundamental processes in a negative corona discharge in a single- (air is an example) and multi-phase gaseous fluids. The controlled generation of a single Trichel pulse or a series of Trichel pulses can also be attractive for those corona treatments which need manipulation of the electric charge and heat portions delivered by the Trichel pulses to the object.

A high pulsed power supply system designed for pulsed high magnetic field

International Nuclear Information System (INIS)

Liu Kefu; Wang Shaorong; Zhong Heqing; Xu Yan; Pan Yuan

2008-01-01

This paper introduces the design of high pulsed power supply system for producing pulsed high magnetic field up to 70 T. This system consists of 58 sets of 55 μF of capacitor bank which provides 1.0 MJ energy storage. A set of vacuum closing switch is chosen as main switch for energy discharge into magnetic coil. A crowbar circuit with high power diodes in series with resistor is used to absorb the redundant energy and adjust pulse width. The resistance of magnetic coil changing with current is deduced by energy balance equations. A capacitor-charging power supply using a series-resonant, constant on-time variable frequency control, and zero-current switching charges the capacitor bank in one minute time with high efficiency. The pulsed power supply provides adjustable current and pulse width with 30 kA peak and 30 ms maximum. The primary experiments demonstrate the system reliability. This work provides an engineering guidance for future development of pulsed high magnetic field. (authors)

Initial Breakdown Pulse Amplitudes in Intracloud and Cloud-to-Ground Lightning Flashes

Science.gov (United States)

Marshall, T. C.; Smith, E. M.; Stolzenburg, M.; Karunarathne, S.; Siedlecki, R. D., II

2017-12-01

This study analyzes the largest initial breakdown (IB) pulse in flashes from three storms in Florida. The study was motivated in part by the possibility that IB pulses of IC flashes may cause of terrestrial gamma-ray flashes (TGFs). The range-normalized, zero-to-peak amplitude of the largest IB pulse within each flash was determined along with its altitude, duration, and occurrence time in the flash. Appropriate data were available for 40 intracloud (IC) and 32 cloud-to-ground (CG) flashes. Histograms of the magnitude of the largest IB pulse amplitude by flash type were similar, with mean (median) values of 1.49 (1.05) V/m for IC flashes and -1.35 (-0.87) V/m for CG flashes. The mean amplitude of the largest IC IB pulses are substantially smaller (roughly an order of magnitude smaller) than the few known pulse amplitudes of TGF events and TGF candidate events. The largest IB pulse in 30 IC flashes showed a weak inverse relation between pulse amplitude and altitude. Amplitude of the largest IB pulse for 25 CG flashes showed no altitude correlation. Duration of the largest IB pulse in ICs averaged twice as long as in CGs (96 μs versus 46 μs); all of the CG durations were <100 μs. Among the ICs, there is a positive relation between largest IB pulse duration and amplitude; the linear correlation coefficient is 0.385 with outliers excluded. The largest IB pulse in IC flashes typically occurred at a longer time after the first IB pulse (average 4.1 ms) than was the case in CG flashes (average 0.6 ms). In both flash types, the largest IB pulse was the first IB pulse in about 30% of the cases.

CW seeded optical parametric amplifier providing wavelength and pulse duration tunable nearly transform limited pulses.

Science.gov (United States)

Hädrich, S; Gottschall, T; Rothhardt, J; Limpert, J; Tünnermann, A

2010-02-01

An optical parametric amplifier that delivers nearly transform limited pulses is presented. The center wavelength of these pulses can be tuned between 993 nm and 1070 nm and, at the same time, the pulse duration is varied between 206 fs and 650 fs. At the shortest pulse duration the pulse energy was increased up to 7.2 microJ at 50 kHz repetition rate. Variation of the wavelength is achieved by applying a tunable cw seed while the pulse duration can be varied via altering the pump pulse duration. This scheme offers superior flexibility and scaling possibilities.

Nonlinear Pulse Shaping in Fibres for Pulse Generation and Optical Processing

Directory of Open Access Journals (Sweden)

Sonia Boscolo

2012-01-01

Full Text Available The development of new all-optical technologies for data processing and signal manipulation is a field of growing importance with a strong potential for numerous applications in diverse areas of modern science. Nonlinear phenomena occurring in optical fibres have many attractive features and great, but not yet fully explored, potential in signal processing. Here, we review recent progress on the use of fibre nonlinearities for the generation and shaping of optical pulses and on the applications of advanced pulse shapes in all-optical signal processing. Amongst other topics, we will discuss ultrahigh repetition rate pulse sources, the generation of parabolic shaped pulses in active and passive fibres, the generation of pulses with triangular temporal profiles, and coherent supercontinuum sources. The signal processing applications will span optical regeneration, linear distortion compensation, optical decision at the receiver in optical communication systems, spectral and temporal signal doubling, and frequency conversion.

Pulsed neutron generator for use with pulsed neutron activation techniques

International Nuclear Information System (INIS)

Rochau, G.E.

1980-01-01

A high-output, transportable, pulsed neutron generator has been developed by Sandia National Laboratories for use with Pulsed Neutron Activation (PNA) techniques. The PNA neutron generator generates > 10 10 14 MeV D-T neutrons in a 1.2 millisecond pulse. Each operation of the unit will produce a nominal total neutron output of 1.2 x 10 10 neutrons. The generator has been designed to be easily repaired and modified. The unit requires no additional equipment for operation or measurement of output

Effect of laser pulse energies in laser induced breakdown spectroscopy in double-pulse configuration

International Nuclear Information System (INIS)

Benedetti, P.A.; Cristoforetti, G.; Legnaioli, S.; Palleschi, V.; Pardini, L.; Salvetti, A.; Tognoni, E.

2005-01-01

In this paper, the effect of laser pulse energy on double-pulse laser induced breakdown spectroscopy signal is studied. In particular, the energy of the first pulse has been changed, while the second pulse energy is held fixed. A systematic study of the laser induced breakdown spectroscopy signal dependence on the interpulse delay is performed, and the results are compared with the ones obtained with a single laser pulse of energy corresponding to the sum of the two pulses. At the same time, the crater formed at the target surface is studied by video-confocal microscopy, and the variation in crater dimensions is correlated to the enhancement of the laser induced breakdown spectroscopy signal. The results obtained are consistent with the interpretation of the double-pulse laser induced breakdown spectroscopy signal enhancement in terms of the changes in ambient gas pressure produced by the shock wave induced by the first laser pulse

Dose reduction in pulsed fluoroscopy by modifying the high-voltage pulse shape

International Nuclear Information System (INIS)

Sabau, M.N.; Phelps, G.

1988-01-01

This paper presents the dose reduction results in pulsed fluoroscopy by modifying the high-voltage pulse shape (HVPS). Since the HVPS in regular pulsed fluoroscopy has a long tail, the radiation pulse shape (RPS) is similar. Using specially designed circuitry in the high-voltage generator to produce a rectangular HVPS, and consequently a rectangular RPS, it was possible to obtain a reduction of up to 25% of patient exposure. This dose reduction obtained by cutting the long tail of RPS does not damage the image quality

Evolution of super-Gaussian pulses in a nonlinear optical fiber

Science.gov (United States)

Bugay, Aleksandr N.; Khalyapin, Vyacheslav A.

2018-04-01

An analytic and numerical study is carried out of the dynamics of parameters of a super-Gaussian pulse whose spectrum can fit both in the region of normal and anomalous dispersion of the group velocity. An analytical solution is found for the parameter characterizing the evolution of the degree of the super-Gaussian momentum. The loss of profile rectangularity is shown to be much faster than the pulse dispersion broadening, and corresponding characteristic length is determined by explicit formula.

Hollow-core fibers for high power pulse delivery

DEFF Research Database (Denmark)

Michieletto, Mattia; Lyngsø, Jens K.; Jakobsen, Christian

2016-01-01

We investigate hollow-core fibers for fiber delivery of high power ultrashort laser pulses. We use numerical techniques to design an anti-resonant hollow-core fiber having one layer of non-touching tubes to determine which structures offer the best optical properties for the delivery of high power...... picosecond pulses. A novel fiber with 7 tubes and a core of 30 mu m was fabricated and it is here described and characterized, showing remarkable low loss, low bend loss, and good mode quality. Its optical properties are compared to both a 10 mu m and a 18 mu m core diameter photonic band gap hollow......-core fiber. The three fibers are characterized experimentally for the delivery of 22 picosecond pulses at 1032nm. We demonstrate flexible, diffraction limited beam delivery with output average powers in excess of 70W. (C) 2016 Optical Society of America...

Risk assessment of a synthetic pyrethroid, bifenthrin on pulses.

Science.gov (United States)

Mukherjee, Irani; Singh, Ranbir; Govil, J N

2010-03-01

This work was undertaken to determine the pre-harvest interval of bifenthrin and to minimize its residues in pulses and thereby ensure consumer safety and avoid non-compliance in terms of residues violations in export market. Furthermore the residue dynamics in the soil under pulses was explored to assess the environmental safety. The residues of bifenthrin dissipated following first order kinetics. The residues in harvest time grains were below the maximum residue limit (MRL) of 0.02 mg/kg applicable for European Union. In soil the degradation rate was fast with a half life of 2-3 days. This work is of high practical significance to the domestic and export pulse industry of India to ensure safety compliance in respect of bifenthrin residues, keeping in view the requirements of international trade.

Design and performance of a pulse transformer based on Fe-based nanocrystalline core.

Science.gov (United States)

Yi, Liu; Xibo, Feng; Lin, Fuchang

2011-08-01

A dry-type pulse transformer based on Fe-based nanocrystalline core with a load of 0.88 nF, output voltage of more than 65 kV, and winding ratio of 46 is designed and constructed. The dynamic characteristics of Fe-based nanocrystalline core under the impulse with the pulse width of several microseconds were studied. The pulse width and incremental flux density have an important effect on the pulse permeability, so the pulse permeability is measured under a certain pulse width and incremental flux density. The minimal volume of the toroidal pulse transformer core is determined by the coupling coefficient, the capacitors of the resonant charging circuit, incremental flux density, and pulse permeability. The factors of the charging time, ratio, and energy transmission efficiency in the resonant charging circuit based on magnetic core-type pulse transformer are analyzed. Experimental results of the pulse transformer are in good agreement with the theoretical calculation. When the primary capacitor is 3.17 μF and charge voltage is 1.8 kV, a voltage across the secondary capacitor of 0.88 nF with peak value of 68.5 kV, rise time (10%-90%) of 1.80 μs is obtained.

MHD-Stabilization of Axisymmetric Mirror Systems Using Pulsed ECRH

International Nuclear Information System (INIS)

Post, R.F.

2010-01-01

This paper, part of a continuing study of means for the stabilization of MHD interchange modes in axisymmertric mirror-based plasma confinement systems, is aimed at a preliminary look at a technique that would employ a train of plasma pressure pulses produced by ECRH to accomplish the stabilization. The purpose of using sequentially pulsed ECRH rather than continuous-wave ECRH is to facilitate the localization of the heated-electron plasma pulses in regions of the magnetic field with a strong positive field-line curvature, e. g. in the 'expander' region of the mirror magnetic field, outside the outermost mirror, or in other regions of the field with positive field-line curvature. The technique proposed, of the class known as 'dynamic stabilization,' relies on the time-averaged effect of plasma pressure pulses generated in regions of positive field-line curvature to overcome the destabilizing effect of plasma pressure in regions of negative field-line curvature within the confinement region. As will also be discussed in the paper, the plasma pulses, when produced in regions of the confining having a negative gradient, create transient electric potentials of ambipolar origin, an effect that was studied in 1964 in The PLEIDE experiment in France. These electric fields preserve the localization of the hot-electron plasma pulses for a time determined by ion inertia. It is suggested that it may be possible to use this result of pulsed ECRH not only to help to stabilize the plasma but also to help plug mirror losses in a manner similar to that employed in the Tandem Mirror.

Apparatus for generating nonlinear pulse patterns

Science.gov (United States)

Nakamura, N.M.I.

Apparatus for generating a plurality of nonlinear pulse patterns from a single linear pulse pattern. A first counter counts the pulses of the linear pulse pattern and a second counter counts the pulses of the nonlinear pulse pattern. A comparator compares the counts of both counters, and in response to an equal count, a gate is enabled to gate a pulse of the linear pattern as a pulse of the nonlinear pattern, the latter also resetting the first counter. Presettable dividers divide the pulses of each pattern before they are counted by the respective counters. Apparatus for generating a logarithmic pulse pattern from a linear pulse pattern to any log base is described. In one embodiment, a shift register is used in place of the second counter to be clocked by each pulse of the logarithmic pattern to generate the pattern. In another embodiment, a memory stores the logarithmic pattern and is addressed by the second counter which is clocked by the pulses of the logarithmic pulse pattern.

Pulsed power particle beam fusion research

International Nuclear Information System (INIS)

Yonas, G.

1979-01-01

Although substantial progress has been made in the last few years in developing the technology of intense particle beam drivers, there are still several unanswered questions which will determine their ultimate feasibility as fusion ignition systems. The questions of efficiency, cost, and single pulse scalability appear to have been answered affirmatively but repetitive pulse technology is still in its infancy. The allowable relatively low pellet gains and high available beam energies should greatly ease questions of pellet implosion physics. Insofar as beam-target coupling is concerned, ion deposition is thought to be understood and our measurements of enhanced electron deposition agree with theory. With the development of plasma discharges for intense beam transport and concentration it appears that light ion beams will be the preferred approach for reactors

Pulsed neutron generator for mass flow measurement using the pulsed neutron activation technique

International Nuclear Information System (INIS)

Rochau, G.E.; Hornsby, D.R.; Mareda, J.F.; Riggan, W.C.

1980-01-01

A high-output, transportable neutron generator has been developed to measure mass flow velocities in reactor safety tests using the Pulsed Neutron Activation (PNA) Technique. The PNA generator produces >10 10 14 MeV D-T neutrons in a 1.2 millisecond pulse. The Millisecond Pulse (MSP) Neutron Tube, developed for this application, has an expected operational life of 1000 pulses, and it limits the generator pulse repetition rate to 12 pulses/minute. A semiconductor neutron detector is included in the generator package to monitor the neutron output. The control unit, which can be operated manually or remotely, also contains a digital display with a BCD output for the neutron monitor information. The digital logic of the unit controls the safety interlocks and rejects transient signals which could accidently fire the generator

Pulse processing in optical fibers using the temporal Radon-Wigner transform

Energy Technology Data Exchange (ETDEWEB)

Bulus-Rossini, L A; Costanzo-Caso, P A; Duchowicz, R [Centro de Investigaciones Opticas, CONICET La Plata - CIC, Camino Parque Centenario y 506, C.C. 3 (1897) La Plata (Argentina); Sicre, E E, E-mail: lbulus@ing.unlp.edu.ar [Instituto de Tecnologia, Facultad de Ingenieria y Ciencias Exactas, Universidad Argentina de la Empresa, Lima 717, C1073AAO Buenos Aires (Argentina)

2011-01-01

It is presented the use of the temporal Radon-Wigner transform (RWT), which is the squared modulus of the fractional Fourier transform (FRT) for a varying fractional order p, as a processing tool for pulses with FWHM of ps-tens of ps. For analysis purposes, the complete numerical generation of the RWT with 0 < p < 1 is proposed to select a particular pulse shape related to a determined value of p. To this end, the amplitude and phase of the signal to be processed are obtained using a pulse characterization technique. To synthesize the processed pulse, the selected FRT irradiance is optically produced employing a photonic device that combines phase modulation and dispersive transmission. The practical implementation of this device involves a scaling factor that depends on the modulation and dispersive parameters. It is explored the variation of this factor in order to obtain an enhancement of the particular characteristic sought in the pulse to be synthesized. To illustrate the implementation of the proposed method, numerical simulations of its application to compress signals commonly found in fiber optic transmission systems, are performed. The examples presented consider chirped Gaussian pulses and pulses distorted by group velocity dispersion and self-phase modulation.

Transient field behavior in an electromagnetic pulse from neutral-beam reflection

International Nuclear Information System (INIS)

Strobel, G.L.

1990-01-01

A neutral beam of electrons and positrons catches up to an electromagnetic pulse moving in a medium with refractive index n. The neutral beam is reflected and deposits some of its energy in a current region in the tail of the pulse. The location, size, and shape of the transient-induced electric fields in the current region are modeled using current densities from uniform averaged fields. The electric field in the current region is predicted to rise linearly with time, with a doubling time determined by the beam parameters and the initial local electromagnetic field. A coordinate frame comoving with the pulse is used to determine the extent of and conditions within the current region. In this comoving frame the Lorentz-transformed electric field is zero, but there is an enhanced Lorentz-transformed magnetic field. The extent of the current region is found from the radius of the semicircular charged-particle orbits in the comoving frame

Long pacing pulses reduce phrenic nerve stimulation in left ventricular pacing.

Science.gov (United States)

Hjortshøj, Søren; Heath, Finn; Haugland, Morten; Eschen, Ole; Thøgersen, Anna Margrethe; Riahi, Sam; Toft, Egon; Struijk, Johannes Jan

2014-05-01

Phrenic nerve stimulation is a major obstacle in cardiac resynchronization therapy (CRT). Activation characteristics of the heart and phrenic nerve are different with higher chronaxie for the heart. Therefore, longer pulse durations could be beneficial in preventing phrenic nerve stimulation during CRT due to a decreased threshold for the heart compared with the phrenic nerve. We investigated if long pulse durations decreased left ventricular (LV) thresholds relatively to phrenic nerve thresholds in humans. Eleven patients, with indication for CRT and phrenic nerve stimulation at the intended pacing site, underwent determination of thresholds for the heart and phrenic nerve at different pulse durations (0.3-2.9 milliseconds). The resulting strength duration curves were analyzed by determining chronaxie and rheobase. Comparisons for those parameters were made between the heart and phrenic nerve, and between the models of Weiss and Lapicque as well. In 9 of 11 cases, the thresholds decreased faster for the LV than for the phrenic nerve with increasing pulse duration. In 3 cases, the thresholds changed from unfavorable for LV stimulation to more than a factor 2 in favor of the LV. The greatest change occurred for pulse durations up to 1.5 milliseconds. The chronaxie of the heart was significantly higher than the chronaxie of the phrenic nerve (0.47 milliseconds vs. 0.22 milliseconds [P = 0.029, Lapicque] and 0.79 milliseconds vs. 0.27 milliseconds [P = 0.033, Weiss]). Long pulse durations lead to a decreased threshold of the heart relatively to the phrenic nerve and may prevent stimulation of the phrenic nerve in a clinical setting. © 2013 Wiley Periodicals, Inc.

Simulating the inception of pulsed discharges near positive electrodes

Science.gov (United States)

Teunissen, Jannis; Ebert, Ute

2013-09-01

With 3D particle simulations we study the inception of pulsed discharges near positive electrodes. In different geometries, we first determine the breakdown voltage. Then we study the probability of inception for a fast voltage pulse. This probability mostly depends on the availability of seed electrons to generate the initial electron avalanches. These results are compared with experimental observations. Then we investigate how the shape of a starting discharge affects its further development. In particular, we discuss the formation of so-called ``inception clouds.'' JT was supported by STW-project 10755.

High current transistor pulse generator

International Nuclear Information System (INIS)

Nesterov, V.; Cassel, R.

1991-05-01

A solid state pulse generator capable of delivering high current trapezoidally shaped pulses into an inductive load has been developed at SLAC. Energy stored in the capacitor bank of the pulse generator is switched to the load through a pair of Darlington transistors. A combination of diodes and Darlington transistors is used to obtain trapezoidal or triangular shaped current pulses into an inductive load and to recover the remaining energy in the same capacitor bank without reversing capacitor voltage. The transistors work in the switch mode, and the power losses are low. The rack mounted pulse generators presently used at SLAC contain a 660 microfarad storage capacitor bank and can deliver 400 amps at 800 volts into inductive loads up to 3 mH. The pulse generators are used in several different power systems, including pulse to pulse bipolar power supplies and in application with current pulses distributed into different inductive loads. The current amplitude and discharge time are controlled by the central computer system through a specially developed multichannel controller. Several years of operation with the pulse generators have proven their consistent performance and reliability. 8 figs

Vacuum deposition and pulsed modification of Ge thin films on Si. Structure and photoluminescence

International Nuclear Information System (INIS)

Batalov, R.I.; Bayazitov, R.M.; Novikov, G.A.; Shustov, V.A.; Bizyaev, D.A.; Gajduk, P.I.; Ivlev, G.D.; Prokop'ev, S.L.

2013-01-01

Vacuum deposition of Ge thin films onto Si substrates by magnetron sputtering was studied. During deposition sputtering time and substrate temperature were varied. Nanosecond pulsed annealing of deposited films by powerful laser or ion beams was performed. The dependence of the structure and optical properties of Ge/Si films on parameters of pulsed treatments was investigated. Optimum parameters of deposition and pulsed treatments resulting into light emitting monocrystalline Ge/Si layers are determined. (authors)

Pulse power modulators - an overview

International Nuclear Information System (INIS)

Venkatramani, N.

2006-01-01

Pulse power modulators are electronic devices to provide, high voltage, high current, power bursts. Ideally, a modulator, with the means to shape and control the pulses, acts as a switch between a high voltage power supply and its load. This article gives an overview of the pulse power modulators: starting with the basics of pulse and modulation, it covers modulation topologies, different types of modulators, major subsystems and pulse measurement techniques. The various applications of pulse power modulators and the recent trends have been included at the end. (author)

Extraction of a long-pulsed intense electron beam from a pulsed plasma based on hollow cathode discharge

International Nuclear Information System (INIS)

Uramoto, Johshin.

1977-05-01

An intense electron beam (up to 1.0 kV, 0.8 kA in 0.8 cm phi) is extracted along a uniform magnetic field with a long decay time (up to 2 msec) from a pulsed high density plasma source which is produced with a fast rise time (< 100 μsec) by a secondary discharge based on a dc hollow cathode discharge. Through a back stream of ionized ions from a beam-extracting anode region where a neutral gas is fed, a space charge limit of the electron beam is so reduced that the beam current is determined by an initially injected electron flux and concentrated in a central aperture of the extracting anode. Moreover, the beam pulse width is much extended by the neutral gas feed into the anode space. (auth.)

A method to reduce the suppression of relevant pulses in pulse weight discriminators

International Nuclear Information System (INIS)

Schwartz, P.

1975-01-01

The pulse height analyzer is used, for instance, with proportional counters. Pulses are broken down into amplitude ranges in accordance with their maximum amplitudes. In pulse height analyzers with real time analog-digital conversion only one deadtime is needed for the respective range selected. For this purpose, all discriminator thresholds of the amplitude stores connected parallel are actuated as an input pulse arrives. The leading edges of the discriminator signals set the amplitude range flip-flop. Only the flip-flop circuit of the maximum amplitude range reached remains set whilst all the others are erased. The trailing edge of the discriminator signals actuates the evaluation of the information stored by the flip-flop circuit selected. It triggers a pulse extender and resets the flip-flop selected. Therefore, only the amplitude range selected needs a deadtime. The pulse extender in addition reduces the processing time of the analyzer by the output pulse length. The characteristic used for the trailing edge is the backward count of the real time analog-digital converter. (DG/RF) [de

Tissue effects of Ho:YAG laser with varying fluences and pulse widths

Science.gov (United States)

Vari, Sandor G.; van der Veen, Maurits J.; Pergadia, Vani R.; Shi, Wei-Qiang; Duffy, J. T.; Weiss, Andrew B.; Fishbein, Michael C.; Grundfest, Warren S.

1994-02-01

We investigated the effect of varying fluence and pulse width on the ablation rate and consequent thermal damage of the Ho:YAG (2.130 micrometers ) laser. The rate of ablation on fresh bovine knee joint tissues, fibrous cartilage, hyaline cartilage, and bone in saline was determined after varying the fluence (160 - 640 J/cm2) and pulse width (150, 250, 450 microsecond(s) ec, FWHM) at a repetition rate of 2 Hz. A 400/440 micrometers fiber was used. The ablation rate increased linearly with the fluence. In fibrocartilage, different pulse durations generated significant changes in the ablation rates, but showed minor effects on hyaline cartilage and bone. The heat of ablation for all three tissue types decreased after lengthening the pulse.

Pulsed corona generation using a diode-based pulsed power generator

Science.gov (United States)

Pemen, A. J. M.; Grekhov, I. V.; van Heesch, E. J. M.; Yan, K.; Nair, S. A.; Korotkov, S. V.

2003-10-01

Pulsed plasma techniques serve a wide range of unconventional processes, such as gas and water processing, hydrogen production, and nanotechnology. Extending research on promising applications, such as pulsed corona processing, depends to a great extent on the availability of reliable, efficient and repetitive high-voltage pulsed power technology. Heavy-duty opening switches are the most critical components in high-voltage pulsed power systems with inductive energy storage. At the Ioffe Institute, an unconventional switching mechanism has been found, based on the fast recovery process in a diode. This article discusses the application of such a "drift-step-recovery-diode" for pulsed corona plasma generation. The principle of the diode-based nanosecond high-voltage generator will be discussed. The generator will be coupled to a corona reactor via a transmission-line transformer. The advantages of this concept, such as easy voltage transformation, load matching, switch protection and easy coupling with a dc bias voltage, will be discussed. The developed circuit is tested at both a resistive load and various corona reactors. Methods to optimize the energy transfer to a corona reactor have been evaluated. The impedance matching between the pulse generator and corona reactor can be significantly improved by using a dc bias voltage. At good matching, the corona energy increases and less energy reflects back to the generator. Matching can also be slightly improved by increasing the temperature in the corona reactor. More effective is to reduce the reactor pressure.

Laser ablation comparison by picosecond pulses train and nanosecond pulse

Science.gov (United States)

Lednev, V. N.; Filippov, M. N.; Bunkin, A. F.; Pershin, S. M.

2015-12-01

A comparison of laser ablation by a train of picosecond pulses and nanosecond pulses revealed a difference in laser craters, ablation thresholds, plasma sizes and spectral line intensities. Laser ablation with a train of picosecond pulses resulted in improved crater quality while ablated mass decreased up to 30%. A reduction in laser plasma dimensions for picosecond train ablation was observed while the intensity of atomic/ionic lines in the plasma spectra was greater by a factor of 2-4 indicating an improved excitation and atomization in the plasma.

ANL experimental program for pulsed superconducting coils

International Nuclear Information System (INIS)

Wang, S.T.; Kim, S.H.; Praeg, W.F.; Krieger, C.I.

1978-01-01

Argonne National Laboratory (ANL) had recognized the clear advantage of a superconducting ohmic-heating (OH) coil and started in aggressive development program in FY 1977. The main objectives for FY 1977 are to develop cryostable basic cable configurations with reasonably low ac losses, to develop 12 kA cryostable cable, using it to design and build a 1.5 MJ pulsed coil, and to develop a rather inexpensive large fiberglass reinforced helium cryostat for the 1.5 MJ pulsed coil. The principal objective in building the 1.5 MJ ac coil is to demonstrate ac cryostability of a large coil ranging from 2 T/s up to 12 T/s. Another objective in the pulsed coil program is to determine the feasibility of parallel coil operation in order to avoid excessive voltage and current requirements and to minimize the number of turns for the equilibrium field (EF) coils, should the EF coils be connected in parallel with the OH coils. A two-coil section model using the 11 kA cable will be built and tested

An investigation of pulsed high density plasmas

International Nuclear Information System (INIS)

Timmermans, C.J.

1984-01-01

In this thesis a wall-stabilized argon cascade arc is studied at values of pulsed pressure up to 14 bar and a pulsed current range up to 2200 A with a time duration of about 2 ms. The basic plasma is a CW cascade arc with a 5 mm diameter plasma column and a length of 90 mm, which operates at a 60 A DC current and at one atmosphere filling pressure. The author starts with an extensive summary of the CW arc investigations. After a brief introduction of the basic transport equations the mass equations of the constituent particles are treated using the extended collisional radiative model. The energy balance equations and the momentum balance are discussed. The electron density is determined from measurements of the continuum radiation. The final chapter contains the experimental results on the electron temperatures and electron densities in the pressure and current pulsed plasma. Attention is given to the deviations from local thermodynamic equilibrium values of the ground level densities of the different argon systems. (Auth.)

Broadband noise limit in the photodetection of ultralow jitter optical pulses.

Science.gov (United States)

Sun, Wenlu; Quinlan, Franklyn; Fortier, Tara M; Deschenes, Jean-Daniel; Fu, Yang; Diddams, Scott A; Campbell, Joe C

2014-11-14

Applications with optical atomic clocks and precision timing often require the transfer of optical frequency references to the electrical domain with extremely high fidelity. Here we examine the impact of photocarrier scattering and distributed absorption on the photocurrent noise of high-speed photodiodes when detecting ultralow jitter optical pulses. Despite its small contribution to the total photocurrent, this excess noise can determine the phase noise and timing jitter of microwave signals generated by detecting ultrashort optical pulses. A Monte Carlo simulation of the photodetection process is used to quantitatively estimate the excess noise. Simulated phase noise on the 10 GHz harmonic of a photodetected pulse train shows good agreement with previous experimental data, leading to the conclusion that the lowest phase noise photonically generated microwave signals are limited by photocarrier scattering well above the quantum limit of the optical pulse train.

Particle acceleration by electromagnetic pulses

International Nuclear Information System (INIS)

Lai, H.M.

1982-01-01

Particle interaction with plane electromagnetic pulses is studied. It is shown that particle acceleration by a wavy pulse, depending on the shape of the pulse, may not be small. Further, a diffusive-type particle acceleration by multiple weak pulses is described and discussed. (author)

Hybrid Pulsed Nd:YAG Laser

Science.gov (United States)

Miller, Sawyer; Trujillo, Skyler; Fort Lewis College Laser Group Team

This work concerns the novel design of an inexpensive pulsed Nd:YAG laser, consisting of a hybrid Kerr Mode Lock (KLM) and Q-switch pulse. The two pulse generation systems work independently, non simultaneously of each other, thus generating the ability for the user to easily switch between ultra-short pulse widths or large energy density pulses. Traditionally, SF57 glass has been used as the Kerr medium. In this work, novel Kerr mode-locking mediums are being investigated including: tellurite compound glass (TeO2), carbon disulfide (CS2), and chalcogenide glass. These materials have a nonlinear index of refraction orders of magnitude,(n2), larger than SF57 glass. The Q-switched pulse will utilize a Pockels cell. As the two pulse generation systems cannot be operated simultaneously, the Pockels cell and Kerr medium are attached to kinematic mounts, allowing for quick interchange between systems. Pulse widths and repetition rates will vary between the two systems. A goal of 100 picosecond pulse widths are desired for the mode-locked system. A goal of 10 nanosecond pulse widths are desired for the Q-switch system, with a desired repetition rate of 50 Hz. As designed, the laser will be useful in imaging applications.

Pulse radiolysis study on aqueous solution of nicotine

International Nuclear Information System (INIS)

Wang Shilong; Mei Wang; Ni Yaming; Yao Side; Wang Wenfeng

2004-01-01

Nicotine has been studied for the first time by pulse radiolysis techniques. It has been found that hydrated electrons, hydrogen radicals and hydroxyl radicals can react with nicotine to produce anion radicals and neutral radicals, respectively, and the related rate constants have been determined. (authors)

Improving Reliability of High Power Quasi-CW Laser Diode Arrays Operating in Long Pulse Mode

Science.gov (United States)

Amzajerdian, Farzin; Meadows, Byron L.; Barnes, Bruce W.; Lockard, George E.; Singh, Upendra N.; Kavaya, Michael J.; Baker, Nathaniel R.

2006-01-01

Operating high power laser diode arrays in long pulse regime of about 1 msec, which is required for pumping 2-micron thulium and holmium-based lasers, greatly limits their useful lifetime. This paper describes performance of laser diode arrays operating in long pulse mode and presents experimental data of the active region temperature and pulse-to-pulse thermal cycling that are the primary cause of their premature failure and rapid degradation. This paper will then offer a viable approach for determining the optimum design and operational parameters leading to the maximum attainable lifetime.

Multi-shape pulse pile-up correction: The MCPPU code

International Nuclear Information System (INIS)

Sabbatucci, Lorenzo; Scot, Viviana; Fernandez, Jorge E.

2014-01-01

In spectroscopic measurements with high counting rate, pulse pile-up (PPU) is a common distortion of the spectrum. It is fully ascribable to the pulse handling circuitry of the detector and it is not comprised in the detector response function which is well explained by a purely physical model. Since PPU occurs after the transport inside the detector, this is the first correction to perform in case of spectrum unfolding. Many producers include electronic rejection circuits to limit the appearance of PPU, but it is never suppressed completely. Therefore, it is always necessary to correct PPU distortions after the measurement. In the present work, it is described the post-processing tool MCPPU (Monte Carlo Pulse Pile-Up), based on the MC algorithm developed by Guo et al. (2004, 2005). MCPPU automatically determines the dead time of the counting system and corrects for PPU effects even in the presence of electronic suppression. The capability of allowing a user defined pulse shape makes the code suitable to be used with any kind of detector. The features of MCPPU are illustrated with some examples. - Highlights: • Pulse pile-up (PPU) is a common distortion in radiation detection. • MCPPU is a Monte Carlo code to perform post-processing PPU correction. • MCPPU evaluates automatically the dead time to use in the pile-up recovery. • The measured pulse shape can be introduced as a normalized discrete distribution. • MCPPU is compatible with detectors using electronic rejection circuitry

Processing and analyses of the pulsed-neutron experimental data of the YALINA facility

International Nuclear Information System (INIS)

Cao, Y.; Gohar, Y.; Smith, D.; Talamo, A.; Zhong, Z.; Kiyavitskaya, H.; Bournos, V.; Fokov, Y.; Routkovskaya, C.; Sadovich, S.

2010-01-01

Full text: The YALINA subcritical assembly of the Joint Institute for Power and Nuclear Research (JIPNR)-Sosny, Belarus has been utilized to study the physics parameters of accelerator driven systems (ADS) with high intensity Deuterium-Tritium and Deuterium-Deuterium pulsed neutron sources. In particular, with the fast and thermal neutron zones of the YALINA-Booster subcritical assembly, the pulsed neutron experiments have been utilized to evaluate the pulsed neutron methods for determining the reactivity of the subcritical system. In this paper, the pulsed-neutron experiments performed in the YALINA-Booster 1141 configuration with 90% U 235 fuel and 1185 configuration with 36% and 21% U fuel are examined and analized. The Sjo:strand area-ratio method is utilized to determine the reactivities of the subcritical assembly configurations. The linear regression method is applied to obtain the prompt neutron decay constants from the pulsed-neutron experimental data. The reactivity values obtained from experimental data are shown to be dependent on the detector locations and also on the detector types. The large discrepancies between the reactivity values given by the detectors in the fast neutron zone was reduced by spatial correction methods, and the estimated reactivity after the spatial corrections are almost spatially independent.

Modeling study on the effects of pulse rise rate in atmospheric pulsed discharges

Science.gov (United States)

Zhang, Yuan-Tao; Wang, Yan-Hui

2018-02-01

In this paper, we present a modeling study on the discharge characteristics driven by short pulsed voltages, focusing on the effects of pulse rise rate based on the fluid description of atmospheric plasmas. The numerical results show that the breakdown voltage of short pulsed discharge is almost linearly dependent on the pulse rise rate, which is also confirmed by the derived equations from the fluid model. In other words, if the pulse rise rate is fixed as a constant, the simulation results clearly suggest that the breakdown voltage is almost unchanged, although the amplitude of pulsed voltage increases significantly. The spatial distribution of the electric field and electron density are given to reveal the underpinning physics. Additionally, the computational data and the analytical expression also indicate that an increased repetition frequency can effectively decrease the breakdown voltage and current density, which is consistent with the experimental observation.

Large area crystallization of amorphous Si with overlapping high repetition rate laser pulses

KAUST Repository

Ryu, Sang-Gil

2012-09-01

This paper presents a pulsed laser crystallization technique, enabling large area crystallization of amorphous Si to produce grains having well-defined size and orientation. The method is developed by first determining the parameters influencing crystallization induced by single laser pulses of circular cross-sectional profile. In a second step, crystallization by overlapping round spots is examined. The experiments reveal three zones characterized by distinctly different crystallized morphologies following the laser irradiation. One of these zones corresponds to the regime of lateral crystal growth, wherein grains are driven towards the center of the spot by the radial temperature gradient. These findings are then applied to processing via line beam profiles that facilitate large area crystallization upon rapid translation of the specimen. Crystallization of extended areas hinges on the determination of the crystal growth length for a single spot. The pitch between successive pulses is then set on the basis of this information. It is shown that the pulse energy has only a weak effect on the crystal growth length. © 2012 Elsevier B.V.

Intense isolated attosecond pulse generation from relativistic laser plasmas using few-cycle laser pulses

International Nuclear Information System (INIS)

Ma, Guangjin; Dallari, William; Borot, Antonin; Tsakiris, George D.; Veisz, Laszlo; Krausz, Ferenc; Yu, Wei

2015-01-01

We have performed a systematic study through particle-in-cell simulations to investigate the generation of attosecond pulse from relativistic laser plasmas when laser pulse duration approaches the few-cycle regime. A significant enhancement of attosecond pulse energy has been found to depend on laser pulse duration, carrier envelope phase, and plasma scale length. Based on the results obtained in this work, the potential of attaining isolated attosecond pulses with ∼100 μJ energy for photons >16 eV using state-of-the-art laser technology appears to be within reach

Wilcoxon signed-rank-based technique for the pulse-shape analysis of HPGe detectors

Science.gov (United States)

Martín, S.; Quintana, B.; Barrientos, D.

2016-07-01

The characterization of the electric response of segmented-contact high-purity germanium detectors requires scanning systems capable of accurately associating each pulse with the position of the interaction that generated it. This process requires an algorithm sensitive to changes above the electronic noise in the pulse shapes produced at different positions, depending on the resolution of the Ge crystal. In this work, a pulse-shape comparison technique based on the Wilcoxon signed-rank test has been developed. It provides a method to distinguish pulses coming from different interaction points in the germanium crystal. Therefore, this technique is a necessary step for building a reliable pulse-shape database that can be used later for the determination of the position of interaction for γ-ray tracking spectrometry devices such as AGATA, GRETA or GERDA. The method was validated by comparison with a χ2 test using simulated and experimental pulses corresponding to a Broad Energy germanium detector (BEGe).

Wilcoxon signed-rank-based technique for the pulse-shape analysis of HPGe detectors

Energy Technology Data Exchange (ETDEWEB)

Martín, S., E-mail: sergiomr@usal.es; Quintana, B.; Barrientos, D.

2016-07-01

The characterization of the electric response of segmented-contact high-purity germanium detectors requires scanning systems capable of accurately associating each pulse with the position of the interaction that generated it. This process requires an algorithm sensitive to changes above the electronic noise in the pulse shapes produced at different positions, depending on the resolution of the Ge crystal. In this work, a pulse-shape comparison technique based on the Wilcoxon signed-rank test has been developed. It provides a method to distinguish pulses coming from different interaction points in the germanium crystal. Therefore, this technique is a necessary step for building a reliable pulse-shape database that can be used later for the determination of the position of interaction for γ-ray tracking spectrometry devices such as AGATA, GRETA or GERDA. The method was validated by comparison with a χ{sup 2} test using simulated and experimental pulses corresponding to a Broad Energy germanium detector (BEGe).

Wilcoxon signed-rank-based technique for the pulse-shape analysis of HPGe detectors

International Nuclear Information System (INIS)

Martín, S.; Quintana, B.; Barrientos, D.

2016-01-01

The characterization of the electric response of segmented-contact high-purity germanium detectors requires scanning systems capable of accurately associating each pulse with the position of the interaction that generated it. This process requires an algorithm sensitive to changes above the electronic noise in the pulse shapes produced at different positions, depending on the resolution of the Ge crystal. In this work, a pulse-shape comparison technique based on the Wilcoxon signed-rank test has been developed. It provides a method to distinguish pulses coming from different interaction points in the germanium crystal. Therefore, this technique is a necessary step for building a reliable pulse-shape database that can be used later for the determination of the position of interaction for γ-ray tracking spectrometry devices such as AGATA, GRETA or GERDA. The method was validated by comparison with a χ"2 test using simulated and experimental pulses corresponding to a Broad Energy germanium detector (BEGe).

Field and laboratory simulations of storm water pulses: Behavioural avoidance by marine epifauna

International Nuclear Information System (INIS)

Roberts, David A.; Johnston, Emma L.; Mueller, Stefanie; Poore, Alistair G.B.

2008-01-01

Epifaunal communities associated with macroalgae were exposed to storm water pulses using a custom made irrigation system. Treatments included Millipore freshwater, freshwater spiked with trace metals and seawater controls to allow for the relative importance of freshwater inundation, trace metals and increased flow to be determined. Experimental pulses created conditions similar to those that occur following real storm water events. Brief storm water pulses reduced the abundance of amphipods and gastropods. Freshwater was the causative agent as there were no additional effects of trace metals on the assemblages. Laboratory assays indicated that neither direct nor latent mortality was likely following experimental pulses and that epifauna readily avoid storm water. Indirect effects upon epifauna through salinity-induced changes to algal habitats were not found in field recolonisation experiments. Results demonstrate the importance of examining the effects of pulsed contaminants under realistic exposure conditions and the need to consider ecologically relevant endpoints. - Brief storm water pulses trigger avoidance response in mobile epifauna due to the inundation of freshwater

Electrical Tree Initiation and Growth in Silicone Rubber under Combined DC-Pulse Voltage

Directory of Open Access Journals (Sweden)

Tao Han

2018-03-01

Full Text Available Electrical tree is a serious threat to silicone rubber (SIR insulation and can even cause breakdown. Electrical trees under alternating current (AC and direct current (DC voltage have been widely researched. While there are pulses in high-voltage direct current (HVDC cables under operating conditions caused by lightning and operating overvoltage in the power system, little research has been reported about trees under combined DC-pulse voltage. Their inception and growth mechanism is still not clear. In this paper, electrical trees are studied under several types of combined DC-pulse voltage. The initiation and growth process was recorded by a digital microscope system. The experimental results indicate that the inception pulse voltage is different under each voltage type and is influenced by the combined DC. The initial tree has two structures, determined by the pulse polarity. With increased DC prestressing time, tree inception pulse voltage with the same polarity is clearly decreased. Moreover, a special initial bubble tree was observed after the prestressing DC.

Determining the water use of rambutan and longkong during phenological development by heat-pulse method

Directory of Open Access Journals (Sweden)

Sdoodee, S.

2003-01-01

Full Text Available The water use of two species of tropical fruit trees: rambutan (Nephelium lappaceum and longkong (Aglaia dookkoo Griff. were investigated by heat-pulse method. The sapflow rate of both species were determined during phenological development. An experiment was established at Prince of Songkla University, Songkhla Province. Characteristics of sapwood in each species and optimum depth for probe implanting on the trunk were investigated. During the measurement period, diurnal changes of photon flux density, leaf water potential and stomatal conductance were recorded. It was found that sapwood of rambutan and longkong were homogeneous. An appropriate probe depth to implant on the trunk was 25 mm from bark. It was found that diurnal changes of sapflow rates of each species varied with the changes of radiation, leaf water potential and stomata conductance. The results of measurement showed that water use decreased at pre-flowering stage, and fruit maturity stage. In rambutan, water use increased during vegetative growth stage followed by flowering stage. The marked increase of water use in rambutan was during fruit development. In longkong, water use increased at the flowering stage followed by vegetative growth stage, and the peak of water use was during fruit development.

Ozone Synthesis Efficiency Upgrading in the Pulsed Point-to-Plane Gas Discharge

International Nuclear Information System (INIS)

Golota, V.I.; Zavada, L.M.; Kotyukov, O.V.; Polyakov, A.V.; Pugach, S.G.

2006-01-01

Results are reported from the studies into electrodynamic characteristics of the barrierless point-to-plane gas discharge as a HV pulse of positive polarity is applied to the point electrode. The efficiency of ozone synthesis has been determined as a function of the length and repetition frequency of the HV pulse. It has been demonstrated that the electrodynamic characteristics of the discharge and the efficiency of ozone synthesis in oxygen-containing gas mixtures essentially depend on the parameters of HV power supply. The HV switch HTS-300 (BEHLKE Electronic GmbH) was used for HV pulse shaping

Quantum entanglement and teleportation in pulsed cavity optomechanics

Energy Technology Data Exchange (ETDEWEB)

Hofer, Sebastian G. [Vienna Center for Quantum Science and Technology, Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna (Austria); Institute for Theoretical Physics, Institute for Gravitational Physics, Leibniz University Hannover, Callinstrasse 38, 30167 Hannover (Germany); Wieczorek, Witlef; Aspelmeyer, Markus [Vienna Center for Quantum Science and Technology, Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna (Austria); Hammerer, Klemens [Institute for Theoretical Physics, Institute for Gravitational Physics, Leibniz University Hannover, Callinstrasse 38, 30167 Hannover (Germany)

2011-11-15

Entangling a mechanical oscillator with an optical mode is an enticing and yet a very challenging goal in cavity optomechanics. Here we consider a pulsed scheme to create Einstein-Podolsky-Rosen-type entanglement between a traveling-wave light pulse and a mechanical oscillator. The entanglement can be verified unambiguously by a pump-probe sequence of pulses. In contrast to schemes that work in a steady-state regime under a continuous-wave drive, this protocol is not subject to stability requirements that normally limit the strength of achievable entanglement. We investigate the protocol's performance under realistic conditions, including mechanical decoherence, in full detail. We discuss the relevance of a high mechanical Qf product for entanglement creation and provide a quantitative statement on which magnitude of the Qf product is necessary for a successful realization of the scheme. We determine the optimal parameter regime for its operation and show it to work in current state-of-the-art systems.

Electronic system for recording proportional counter rare pulses with the pulse shape analysis

International Nuclear Information System (INIS)

Barabanov, I.R.; Gavrin, V.N.; Zakharov, Yu.I.; Tikhonov, A.A.

1984-01-01

The anutomated system for recording proportional counter rare pulses is described. The proportional counters are aimed at identification of 37 Ar and H7 1 Gr decays in chemical radiation detectors of solar neutrino. Pulse shape recording by means of a storage oscilloscope and a TV display is performed in the system considered besides two-parametric selection of events (measurement of pulse amplitude in a slow channel and the amplitude of pulse differentiated with time constant of about 10 ns in a parallel fast channel). Pulse discrimination by a front rise rate provides background decrease in the 55 Fe range (5.9 keV) by 6 times; the visual analysis of pulse shapes recorded allows to decrease the background additionally by 25-30%. The background counting rate in the 55 Fe range being equal to 1 pulse per 1.5 days, is obtained when using the installation described above, as well as the passive Pb shield 5 cm thick, and the active shield based on the anticoincidence NaI(Tl) detector with the cathode 5.6 mm in-diameter made of Fe fabircated by zone melting. The installation described allows to reach the background level of 0.6 pulse/day (the total coefficient of background attenuation is 400). Further background decrease is supposed to be provided by installation allocation in the low-noise underground laboratory of the Baksan Neutrino Observatory

Pulsed corona generation using a diode-based pulsed power generator

NARCIS (Netherlands)

Pemen, A.J.M.; Grekhov, I.V.; Heesch, van E.J.M.; Yan, K.; Nair, S.A.; Korotkov, S.V.

2003-01-01

Pulsed plasma techniques serve a wide range of unconventional processes, such as gas and water processing, hydrogen production, and nanotechnology. Extending research on promising applications, such as pulsed corona processing, depends to a great extent on the availability of reliable, efficient and

Ultrashort Laser Pulse Phenomena

CERN Document Server

Diels, Jean-Claude

2006-01-01

Ultrashort Laser Pulse Phenomena, 2e serves as an introduction to the phenomena of ultra short laser pulses and describes how this technology can be used to examine problems in areas such as electromagnetism, optics, and quantum mechanics. Ultrashort Laser Pulse Phenomena combines theoretical backgrounds and experimental techniques and will serve as a manual on designing and constructing femtosecond (""faster than electronics"") systems or experiments from scratch. Beyond the simple optical system, the various sources of ultrashort pulses are presented, again with emphasis on the basic

Multimode pulse counter

International Nuclear Information System (INIS)

Natanzon, D.D.

1982-01-01

A pulse counter with code conversion is described. The counter is based on the integrated circuits of direct-counting devices of medium integration. The counter ensures various modes of pulse counting depending on the logical control signals: reversible, two-channel summing, one-channel summing binary, summing with ''storage'' signal code fixation without interrupting pulse counting. Arrangement of the suggested structure as a microcircuit of medium integration might contribute to reduction in the counter type nomenclature in digital families of widely used integrated circuits

Determination of oxidation products in radiolysis of halophenols with pulse radiolysis, hplc, and ion chromatography

International Nuclear Information System (INIS)

Ye, M.; Schuler, R.H.

1990-01-01

This paper reports on hydroxyl radicals that react with halogen substituted phenols by several different ways. One is addition of OH radicals to the aromatic ring, which is followed by elimination of hydrogen halide, H 2 O or H - . The positions of OH radicals attack are dependent on the nature of the halogen which affects the electronic distribution in the ring. The oxidation of fluorophenols, chlorophenols and bromophenols with hydroxyl radicals in N 2 O saturated solution has been investigated with pulse radiolysis and γ-irradiation experiments. The intermediates of the reactions were studied by pulse radiolysis. The products created in the γ-irradiation of aqueous solutions of halophenols were analyzed by ion chromatography and high performance liquid chromatography (HPLC). With the combination of time-resolved and steady-state experiments a complete and detailed description of radiolytic oxidation of halophenols by hydroxyl radicals was obtained

Powerful nanosecond pulse train generator

International Nuclear Information System (INIS)