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Sample records for pt ii foodstuff

  1. Radiation effects on foodstuffs. Pt. 1

    International Nuclear Information System (INIS)

    Kuehl, M.; Boegl, W.; Stockhausen, K.

    1980-01-01

    In this report, results of irradiation experiments at about 30 foodstuffs are compiled and analyzed. The only objective was to obtain a survey of the chemical changes of irradiated foodstuffs; therefore, neither microbiological nor toxicological aspects were considered. The results were taken from the original publications and compiled in a type of dictionary of foodstuffs listing all relevant data for each substance (foodstuff, irradiation conditions, investigation procedures, results etc.) in a defined order. The main radiation source was Co 60, and the doses ranged between 0,006 and 10 Mrad. The investigations were related not only to the effects of irradiation (in some cases using different absorbed doses per foodstuff), but also to the effects of storage after irradiation (for 16 foodstuffs) and the effects of temperature (for 3 foodstuffs). (orig./MG) [de

  2. Effect of irradiation on foodstuffs Pt. 4

    International Nuclear Information System (INIS)

    Kluender, U.; Boegl, W.

    1980-01-01

    In the present study of the relevant literature the results of irradiation experiments with 32 foodstuffs have been compiled and discussed. This study is intented to give a survey on chemical changes in irradiated food, and neither microbiological nor toxicological and physiological aspects were taken into account. The results published by the authors of the original papers have been compiled in form of a dictionary which contains all important data such as radiation source, irradiation conditions, treatment and characteristics of the sample, investigation methods, results of the chemical and organoleptical changes etc. In addition, the effects of irradiation both on individual food substances and individual groups of foodstuffs have been summarized. Furthermore, the effects of irradiation on sensory characteristics and the atmospheric influence during irradiation are given seperately. The last chapter contains a comparison between the chemical changes of food due to irradiation treatment and those caused by conventional methods. The final discussion of the results will be published seperately. (orig./MG) [de

  3. Effects of radiation treatment on foodstuffs. Pt. 2

    International Nuclear Information System (INIS)

    Werner, W.; Boegl, W.

    1980-01-01

    In the herewith presented study of literature the results of irradiation experiments on 34 foodstuffs are reported and evaluated. The only objective was to obtain a survey of the chemical changes of irradiated foodstuffs; therefore, neither microbiological nor toxicological aspects were considered. The results were taken from the original publications and compiled in a type of dictionary of foodstuffs listing all relevant data in each case (foodstuff, source of irradiation, irradiation conditions, methods, results etc.) in a defined order. The main radiation source was Co 60 and doses ranged between 0,005 and 10 Mrad. In a part of the studies (18 foodstuffs) the irradiation doses were varied to find an eventual relation between the doses applied and the chemical changes. The dose rate was only varied on purpose in one case (2.20.). The effects of the storage were investigated in 15 cases, the temperature in 8 and the way and kind of packing also in 8 cases. (orig.) [de

  4. Effects of microwaves on changes in foodstuffs as compared with conventional heat treatment. Pt. 2

    International Nuclear Information System (INIS)

    Kalb, M.; Dehne, L.; Boegl, W.

    1980-01-01

    It is purpose of this study to contribute to the discussion and to answer the question as to whether changes are caused by microwave-heating of foodstuffs, which differ from those caused by conventional heating. This is achieved by summarizing extensive test materials. In the relevant literature, a great number of tests are listed on the cooking and reheating of foodstuffs by means of micro-waves, as compared to conventional methods. The subject of these tests is the determination of quantitative changes of certain ingredients (vitamins, fatty acids etc.) and sensory characteristics (flavour, colour etc.) due to the different heating methods. In addition to cooking and heating, a more comprehensive use of microwaves in preparation of food is discussed in this study. Works on the thawing, blanching, freeze-drying, and pasteurization are taken into account when comparing the different heating methods. Moreover, this study includes a comaprison as to the formation of volatile aromatic compounds, the thermic decomposition of pesticide residues, and the physiological effect of lipids. It was determined that there is no indication of radiation-specific effects, i. e. athermic effects, of microwaves contained in any of the studies reviewed up to now. (orig./MG) [de

  5. Radiation effects on foodstuffs. Pt. 1. A bibliographic study. Der Einfluss der Strahlenbehandlung auf Lebensmittel. T. 1. Eine Literaturstudie

    Energy Technology Data Exchange (ETDEWEB)

    Kuehl, M; Boegl, W; Stockhausen, K

    1980-01-01

    In this report, results of irradiation experiments at about 30 foodstuffs are compiled and analyzed. The only objective was to obtain a survey of the chemical changes of irradiated foodstuffs; therefore, neither microbiological nor toxicological aspects were considered. The results were taken from the original publications and compiled in a type of dictionary of foodstuffs listing all relevant data for each substance (foodstuff, irradiation conditions, investigation procedures, results etc.) in a defined order. The main radiation source was Co 60, and the doses ranged between 0,006 and 10 Mrad. The investigations were related not only to the effects of irradiation (in some cases using different absorbed doses per foodstuff), but also to the effects of storage after irradiation (for 16 foodstuffs) and the effects of temperature (for 3 foodstuffs).

  6. Effect of irradiation on foodstuffs Pt. 4. A literature study. Der Einfluss der Strahlenbehandlung auf Lebensmittel. T. 4. Eine Literaturstudie

    Energy Technology Data Exchange (ETDEWEB)

    Kluender, U; Boegl, W

    1980-01-01

    In the present study of the relevant literature the results of irradiation experiments with 32 foodstuffs have been compiled and discussed. This study is intented to give a survey on chemical changes in irradiated food, and neither microbiological nor toxicological and physiological aspects were taken into account. The results published by the authors of the original papers have been compiled in form of a dictionary which contains all important data such as radiation source, irradiation conditions, treatment and characteristics of the sample, investigation methods, results of the chemical and organoleptical changes etc. In addition, the effects of irradiation both on individual food substances and individual groups of foodstuffs have been summarized. Furthermore, the effects of irradiation on sensory characteristics and the atmospheric influence during irradiation are given seperately. The last chapter contains a comparison between the chemical changes of food due to irradiation treatment and those caused by conventional methods. The final discussion of the results will be published seperately.

  7. Irradiation of foodstuffs

    International Nuclear Information System (INIS)

    Langerak, D. Is.

    1984-01-01

    The use of ionizing radiation on the foodstuff preservation, as the possibilities and restrictions of the method are discussed. The produced effects (micro-biological, physiological, physical) are described. The radurization application in agriculture is studied. (M.A.C.) [pt

  8. Multifunctional Pt(II) Reagents: Covalent Modifications of Pt Complexes Enable Diverse Structural Variation and In-Cell Detection.

    Science.gov (United States)

    White, Jonathan D; Haley, Michael M; DeRose, Victoria J

    2016-01-19

    To enhance the functionality of Pt-based reagents, several strategies have been developed that utilize Pt compounds modified with small, reactive handles. This Account encapsulates work done by us and other groups regarding the use of Pt(II) compounds with reactive handles for subsequent elaboration with fluorophores or other functional moieties. Described strategies include the incorporation of substituents for well-known condensation or nucleophilic displacement-type reactions and their use, for example, to tether spectroscopic handles to Pt reagents for in vivo investigation. Other chief uses of displacement-type reactions have included tethering various small molecules exhibiting pharmacological activity directly to Pt, thus adding synergistic effects. Click chemistry-based ligation techniques have also been applied, primarily with azide- and alkyne-appended Pt complexes. Orthogonally reactive click chemistry reactions have proven invaluable when more traditional nucleophilic displacement reactions induce side-reactivity with the Pt center or when systematic functionalization of a larger number of Pt complexes is desired. Additionally, a diverse assortment of Pt-fluorophore conjugates have been tethered via click chemistry conjugation. In addition to providing a convenient synthetic path for diversifying Pt compounds, the use of click-capable Pt complexes has proved a powerful strategy for postbinding covalent modification and detection with fluorescent probes. This strategy bypasses undesirable influences of the fluorophore camouflaged as reactivity due to Pt that may be present when detecting preattached Pt-fluorophore conjugates. Using postbinding strategies, Pt reagent distributions in HeLa and lung carcinoma (NCI-H460) cell cultures were observed with two different azide-modified Pt compounds, a monofunctional Pt(II)-acridine type and a difunctional Pt(II)-neutral complex. In addition, cellular distribution was observed with an alkyne-appended difunctional

  9. Determination of methylmercury compounds in foodstuffs. II. Determination of methylmercury in fish, egg, meat, and liver

    Energy Technology Data Exchange (ETDEWEB)

    Westoeoe, G

    1967-01-01

    The combined gas chromatographic and thin-layer chromatographic method for the identification and determination of methylmercury compounds in fish (Westoeoe) has been modified in order to render it applicable to a wider range of foods. In animal foodstuffs methylmercury is probably to a great extent attached to thiol groups. When these foods are extracted according to Gage, methylmercury chloride is formed and dissolves in the benzene together with varying amounts of thio compounds. Purification of the methylmercury in the benzene extracts of e.g., egg yolk or liver by extraction with aqueous alkali solution did not work, probably because the thio compounds were not volatile and could form alkali-insoluble methylmercury salts. Evidently methylmercury-S-compounds were reformed at high pH and prevented the formation of the water-soluble methylmercury hydroxide. Addition of excess mercuric ions, which expelled the methylmercury from the thio compounds, solved this clean-up problem. Samples of fish, egg-white, egg yolk, meat, and liver have been analyzed with the modified method. Extraction of the methylmercury into an aqueous phase was also possible with the aid of a water solution of cysteine. This led to a more rapid analytical procedure. 8 references, 2 figures, 4 tables.

  10. Effects of radiation treatment on foodstuffs. Pt. 2. A bibliographic survey. Der Einfluss der Strahlenbehandlung auf Lebensmittel. T. 2. Eine Literaturstudie

    Energy Technology Data Exchange (ETDEWEB)

    Werner, W; Boegl, W

    1980-01-01

    In the herewith presented study of literature the results of irradiation experiments on 34 foodstuffs are reported and evaluated. The only objective was to obtain a survey of the chemical changes of irradiated foodstuffs; therefore, neither microbiological nor toxicological aspects were considered. The results were taken from the original publications and compiled in a type of dictionary of foodstuffs listing all relevant data in each case (foodstuff, source of irradiation, irradiation conditions, methods, results etc.) in a defined order. The main radiation source was Co 60 and doses ranged between 0,005 and 10 Mrad. In a part of the studies (18 foodstuffs) the irradiation doses were varied to find an eventual relation between the doses applied and the chemical changes. The dose rate was only varied on purpose in one case (2.20.). The effects of the storage were investigated in 15 cases, the temperature in 8 and the way and kind of packing also in 8 cases.

  11. Foodstuff irradiation

    International Nuclear Information System (INIS)

    1982-01-01

    Report written on behalf of the Danish Food Institute summarizes national and international rules and developments within food irradiation technology, chemical changes in irradiated foodstuffs, microbiological and health-related aspects of irradiation and finally technological prospects of this conservation form. Food irradiatin has not been hitherto applied in Denmark. Radiation sources and secondary radiation doses in processed food are characterized. Chemical changes due to irradiation are compared to those due to p.ex. food heating. Toxicological and microbiological tests and their results give no unequivocal answer to the problem whether a foodstuff has been irradiated. The most likely application fields in Denmark are for low radiation dosis inhibition of germination, riping delay and insecticide. Medium dosis (1-10 kGy) can reduce bacteria number while high dosis (10-50 kGy) will enable total elimination of microorganisms and viruses. Food irradiation can be acceptable as technological possibility with reservation, that further studies follow. (EG)

  12. Electrochemical, spectroscopic, and photophysical properties of structurally diverse polyazine-bridged Ru(II),Pt(II) and Os(II),Ru(II),Pt(II) supramolecular motifs.

    Science.gov (United States)

    Knoll, Jessica D; Arachchige, Shamindri M; Wang, Guangbin; Rangan, Krishnan; Miao, Ran; Higgins, Samantha L H; Okyere, Benjamin; Zhao, Meihua; Croasdale, Paul; Magruder, Katherine; Sinclair, Brian; Wall, Candace; Brewer, Karen J

    2011-09-19

    Five new tetrametallic supramolecules of the motif [{(TL)(2)M(dpp)}(2)Ru(BL)PtCl(2)](6+) and three new trimetallic light absorbers [{(TL)(2)M(dpp)}(2)Ru(BL)](6+) (TL = bpy = 2,2'-bipyridine or phen = 1,10-phenanthroline; M = Ru(II) or Os(II); BL = dpp = 2,3-bis(2-pyridyl)pyrazine, dpq = 2,3-bis(2-pyridyl)quinoxaline, or bpm = 2,2'-bipyrimidine) were synthesized and their redox, spectroscopic, and photophysical properties investigated. The tetrametallic complexes couple a Pt(II)-based reactive metal center to Ru and/or Os light absorbers through two different polyazine BL to provide structural diversity and interesting resultant properties. The redox potential of the M(II/III) couple is modulated by M variation, with the terminal Ru(II/III) occurring at 1.58-1.61 V and terminal Os(II/III) couples at 1.07-1.18 V versus Ag/AgCl. [{(TL)(2)M(dpp)}(2)Ru(BL)](PF(6))(6) display terminal M(dπ)-based highest occupied molecular orbitals (HOMOs) with the dpp(π*)-based lowest unoccupied molecular orbital (LUMO) energy relatively unaffected by the nature of BL. The coupling of Pt to the BL results in orbital inversion with localization of the LUMO on the remote BL in the tetrametallic complexes, providing a lowest energy charge separated (CS) state with an oxidized terminal Ru or Os and spatially separated reduced BL. The complexes [{(TL)(2)M(dpp)}(2)Ru(BL)](6+) and [{(TL)(2)M(dpp)}(2)Ru(BL)PtCl(2)](6+) efficiently absorb light throughout the UV and visible regions with intense metal-to-ligand charge transfer (MLCT) transitions in the visible at about 540 nm (M = Ru) and 560 nm (M = Os) (ε ≈ 33,000-42,000 M(-1) cm(-1)) and direct excitation to the spin-forbidden (3)MLCT excited state in the Os complexes about 720 nm. All the trimetallic and tetrametallic Ru-based supramolecular systems emit from the terminal Ru(dπ)→dpp(π*) (3)MLCT state, λ(max)(em) ≈ 750 nm. The tetrametallic systems display complex excited state dynamics with quenching of the (3)MLCT emission at

  13. Determination of copper (II) in foodstuffs based on its quenching effect on the fluorescence of N,N'-bis(pyridoxal phosphate)-o-phenylenediamine.

    Science.gov (United States)

    Xu, Canhui; Liao, Lifu; He, Yunfei; Wu, Rurong; Li, Shijun; Yang, Yanyan

    2015-01-01

    A Schiff base-type fluorescence probe was prepared for the detection of copper (II) in foodstuffs. The probe is N,N'-bis(pyridoxal phosphate)-o-phenylenediamine (BPPP). It was synthesized by utilizing the Schiff base condensation reaction of pyridoxal 5-phosphate with 1,2-phenylenediamine. BPPP has the properties of high fluorescence stability, good water solubility and low toxicity. Its maximum excitation wavelength and maximum fluorescence emission wavelength are at 389 and 448 nm, respectively. When BPPP coexists with copper (II), its fluorescence is dramatically quenched. Under a certain condition, the fluorescence intensity decreased proportionally to the concentration of copper (II) by the quenching effect. Based on this fact, we established a fluorescence quenching method for the determination of copper (II). Under optimal conditions a linear range was found to be 0.5-50 ng/mL with a detection limit of 0.2 ng/mL. The method has been applied to determine copper (II) in foodstuff samples and the analytical results show good agreement with that obtained from atomic absorption spectrometry method. Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Synthesis and spectroscopic studies of biologically active tetraazamacrocyclic complexes of Mn(II, Co(II, Ni(II, Pd(II and Pt(II

    Directory of Open Access Journals (Sweden)

    Monika Tyagi

    2014-01-01

    Full Text Available Complexes of Mn(II, Co(II, Ni(II, Pd(II and Pt(II were synthesized with the macrocyclic ligand, i.e., 2,3,9,10-tetraketo-1,4,8,11-tetraazacycoletradecane. The ligand was prepared by the [2 + 2] condensation of diethyloxalate and 1,3-diamino propane and characterized by elemental analysis, mass, IR and 1H NMR spectral studies. All the complexes were characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, IR, electronic and electron paramagnetic resonance spectral studies. The molar conductance measurements of Mn(II, Co(II and Ni(II complexes in DMF correspond to non electrolyte nature, whereas Pd(II and Pt(II complexes are 1:2 electrolyte. On the basis of spectral studies an octahedral geometry has been assigned for Mn(II, Co(II and Ni(II complexes, whereas square planar geometry assigned for Pd(II and Pt(II. In vitro the ligand and its metal complexes were evaluated against plant pathogenic fungi (Fusarium odum, Aspergillus niger and Rhizoctonia bataticola and some compounds found to be more active as commercially available fungicide like Chlorothalonil.

  15. Reversible insertion of carbon dioxide into Pt(II)-hydroxo bonds.

    Science.gov (United States)

    Lohr, Tracy L; Piers, Warren E; Parvez, Masood

    2013-10-01

    The reactivity of three monomeric diimine Pt(II) hydroxo complexes, (NN)Pt(OH)R (NN = bulky diimine ligand; R = OH, ; R = C6H5, ; R = CH3, ) towards carbon dioxide has been investigated. Insertion into the Pt-OH bonds was found to be facile and reversible at low temperature for all compounds; the reaction with bis-hydroxide gives an isolable κ(2)-carbonato compound , with elimination of water.

  16. Analisis Sistem Antrean Pelayanan Di PT Pos Indonesia (Persero) Kantor Pos II Semarang

    OpenAIRE

    Kusumawardani, Anggraini Susanti; Sugito, Sugito; Rahmawati, Rita

    2014-01-01

    PT Pos Indonesia (Ltd.) is one of state-owned enterprise engaged the field of service. Along with the development of communication device which more sophisticated and modern, PT Pos Indonesia (Ltd.) has to restructure, reform, and transform. Hence, that mail and delivery service through post remains used and preferred by community. There are many things to do by the customers, this is the reason why PT Pos Indonesia (Ltd.) Kantor Pos II Semarang is always crowded by customers. Therefore, it's...

  17. Radioactive iodine intake through foodstuff

    International Nuclear Information System (INIS)

    Omomo, Yoichiro

    1974-01-01

    The transition of radioactive iodine to human bodies is affected by the amount of coexisting stable iodine. The intake of stable iodine through foodstuffs was studied from the stand point of I) discussion of the literature which states the approximate amounts of stable iodine contained in environmental materials, and II) the authors' research on the consumption of foodstuffs. For example, the amounts of iodine intake of fishermen living in Kuji-cho (Ibaragi Prefecture) was estimated from I and II, and was revealed as 2704p. The national average iodine intake was about 800p indicating that the former estimated value was remarkably high. Eighty Four per cent of the 2.7 mg iodine intake was taken from marine products, indicating that marine products are important sources of iodine supply. (Tsukamoto, Y.)

  18. Half-Lantern Pt(II and Pt(III Complexes. New Cyclometalated Platinum Derivatives

    Directory of Open Access Journals (Sweden)

    Violeta Sicilia

    2014-08-01

    Full Text Available The divalent complex [{Pt(bzq(μ-L}2] (1 [Hbzq = benzo[h]quinolone, HL = CF3C4H2N2SH: 4-(trifluoromethylpyrimidine-2-thiol] was obtained from equimolar amounts of [Pt(bzq(NCMe2]ClO4 and 4-(trifluoromethylpyrimidine-2-thiol with an excess of NEt3. The presence of a low intensity absorption band at 486 nm (CH2Cl2, assignable to a metal-metal-to-ligand charge transfer transition (1MMLCT [dσ*(Pt2→π*(bzq], is indicative of the existence of two platinum centers located in close proximity because the rigidity of the half-lantern structure allows the preservation of these interactions in solution. Compound 1 undergoes two-electron oxidation upon treatment with halogens X2 (X2: Cl2, Br2 or I2 to give the corresponding dihalodiplatinum (III complexes [{Pt(bzq(μ-LX}2] (L = CF3C4H2N2S-κN,S; X: Cl 2, Br 3, I 4. Complexes 2–4 were also obtained by reaction of 1 with HX (molar ratio 1:2, 10% excess of HX in THF with yields of about 80% and compound 2 was also obtained by reaction of [{Pt(bzq(μ-Cl}2] with HL (4-(trifluoromethylpyrimidine-2-thiol in molar ratio 1:2 in THF, although in small yield. The X-ray structures of 2 and 3 confirmed the half-lantern structure and the anti configuration of the molecules. Both of them show Pt–Pt distances (2.61188(15 Å 2, 2.61767(16 Å 3 in the low range of those observed in Pt2(III,IIIX2 half-lantern complexes.

  19. Spin Crossover in Fe(II)-M(II) Cyanoheterobimetallic Frameworks (M = Ni, Pd, Pt) with 2-Substituted Pyrazines.

    Science.gov (United States)

    Kucheriv, Olesia I; Shylin, Sergii I; Ksenofontov, Vadim; Dechert, Sebastian; Haukka, Matti; Fritsky, Igor O; Gural'skiy, Il'ya A

    2016-05-16

    Discovery of spin-crossover (SCO) behavior in the family of Fe(II)-based Hofmann clathrates has led to a "new rush" in the field of bistable molecular materials. To date this class of SCO complexes is represented by several dozens of individual compounds, and areas of their potential application steadily increase. Starting from Fe(2+), square planar tetracyanometalates M(II)(CN)4(2-) (M(II) = Ni, Pd, Pt) and 2-substituted pyrazines Xpz (X = Cl, Me, I) as coligands we obtained a series of nine new Hofmann clathrate-like coordination frameworks. X-ray diffraction reveals that in these complexes Fe(II) ion has a pseudo-octahedral coordination environment supported by four μ4-tetracyanometallates forming its equatorial coordination environment. Depending on the nature of X and M, axial positions are occupied by two 2X-pyrazines (X = Cl and M(II) = Ni (1), Pd (2), Pt (3); X = Me and M(II) = Ni (4), Pd (5)) or one 2X-pyrazine and one water molecule (X = I and M(II) = Ni (7), Pd (8), Pt (9)), or, alternatively, two distinct Fe(II) positions with either two pyrazines or two water molecules (X = Me and M(II) = Pt (6)) are observed. Temperature behavior of magnetic susceptibility indicates that all compounds bearing FeN6 units (1-6) display cooperative spin transition, while Fe(II) ions in N5O or N4O2 surrounding are high spin (HS). Structural changes in the nearest Fe(II) environment upon low-spin (LS) to HS transition, which include ca. 10% Fe-N distance increase, lead to the cell expansion. Mössbauer spectroscopy is used to characterize the spin state of all HS, LS, and intermediate phases of 1-9 (see abstract figure). Effects of a pyrazine substituent and M(II) nature on the hyperfine parameters in both spin states are established.

  20. Foodstuffs (radioactive contamination)

    International Nuclear Information System (INIS)

    Thompson, Donald; Taylor, Teddy; Campbell-Savours, D.N.

    1987-01-01

    The proceedings are given of the debate in the UK House of Commons on the maximum permitted radioactivity levels for foodstuffs, feeding stuffs and drinking water in the case of abnormal levels of radioactivity or of a nuclear accident. The motion takes note of European Community Document no. 7183/87 and urges the Community to assure a common standard of health protection by adopting a rational set of scientifically based intervention levels for foodstuffs. (UK)

  1. Anti-inflammatory drugs interacting with Zn(II), Cd(II) and Pt(II) metal ions.

    Science.gov (United States)

    Dendrinou-Samara, C; Tsotsou, G; Ekateriniadou, L V; Kortsaris, A H; Raptopoulou, C P; Terzis, A; Kyriakidis, D A; Kessissoglou, D P

    1998-09-01

    Complexes of Zn(II), Cd(II) and Pt(II) metal ions with the anti-inflammatory drugs, 1-methyl-5-(p-toluoyl)-1H-pyrrole-2-acetic acid (Tolmetin), alpha-methyl-4-(2-methylpropyl)benzeneacetic acid (Ibuprofen), 6-methoxy-alpha-methylnaphthalene-2-acetic acid (Naproxen) and 1-(4-chlorobenzoyl)-5-methoxy-2-methyl-1H-indole-3-acetic acid (indomethacin) have been synthesized and characterized. In the structurally characterized Cd(naproxen)2 complex the anti-inflammatory drugs acts as bidentate chelate ligand coordinatively bound to metal ions through the deprotonated carboxylate group. Crystal data for 1: [C32H26O8Cd], orthorhombic, space group P22(1)2(1), a = 5.693(2) (A), b = 8.760(3) (A), c = 30.74(1) (A), V = 1533(1) A3, Z = 2. Antibacterial and growth inhibitory activity is higher than that of the parent ligands or the platinum(II) diamine compounds.

  2. Irradiation of foodstuffs

    International Nuclear Information System (INIS)

    Sjoeberg, A.M.

    1993-01-01

    Foodstuffs are irradiated to make them keep better. The ionizing radiation is not so strong as to cause radioactivity in the foodstuffs. At least so far, irradiation has not gained acceptance among consumers, although it has been shown to be a completely safe method of preservation. Irradiation causes only slight chemical changes in food. What irradiation does, however, is to damage living organisms, such as bacteria, DNA and proteins, thereby making the food keep longer. Irradiation can be detected from the food afterwards; thus it can be controlled effectively. (orig.)

  3. Foodstuffs preservation by ionization

    International Nuclear Information System (INIS)

    1991-12-01

    This document contains all the papers presented at the meeting on foodstuffs preservation by ionization. These papers deal especially with the food ionization process, its development and the view of the food industry on ionization. Refs and figs (F.M.)

  4. Life system modeling and intelligent computing. Pt. II. Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Li, Kang; Irwin, George W. (eds.) [Belfast Queen' s Univ. (United Kingdom). School of Electronics, Electrical Engineering and Computer Science; Fei, Minrui; Jia, Li [Shanghai Univ. (China). School of Mechatronical Engineering and Automation

    2010-07-01

    This book is part II of a two-volume work that contains the refereed proceedings of the International Conference on Life System Modeling and Simulation, LSMS 2010 and the International Conference on Intelligent Computing for Sustainable Energy and Environment, ICSEE 2010, held in Wuxi, China, in September 2010. The 194 revised full papers presented were carefully reviewed and selected from over 880 submissions and recommended for publication by Springer in two volumes of Lecture Notes in Computer Science (LNCS) and one volume of Lecture Notes in Bioinformatics (LNBI). This particular volume of Lecture Notes in Computer Science (LNCS) includes 55 papers covering 7 relevant topics. The 56 papers in this volume are organized in topical sections on advanced evolutionary computing theory and algorithms; advanced neural network and fuzzy system theory and algorithms; modeling and simulation of societies and collective behavior; biomedical signal processing, imaging, and visualization; intelligent computing and control in distributed power generation systems; intelligent methods in power and energy infrastructure development; intelligent modeling, monitoring, and control of complex nonlinear systems. (orig.)

  5. Pt(II) porphyrin modified TiO{sub 2} composites as photocatalysts for efficient 4-NP degradation

    Energy Technology Data Exchange (ETDEWEB)

    Mingyue, Duan [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xian, Shaanxi 710069 (China); Li Jun, E-mail: junli@nwu.edu.cn [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xian, Shaanxi 710069 (China); Min, Li [Datang Wujiang Gas Turbine Power Limited Liability Company, Jiangsu 215214 (China); Zengqi, Zhang; Chen, Wang [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xian, Shaanxi 710069 (China)

    2012-05-01

    Three Pt(II) porphyrins 5,10,15,20-tetra-[2 or 3 or 4-(3-phenoxy)propoxy]phenyl porphyrin]platinum(II) (1-3) were synthesized and characterized spectroscopically. The corresponding Pt(II) porphyrins-TiO{sub 2} composites were then prepared and characterized by means of FT-IR and diffused reflectance spectra, X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of Pt(II) porphyrins-TiO{sub 2} catalyst was investigated by testing the photodegradation of 4-nitrophenol (4-NP) in aqueous solution under irradiation with Xenon lamp. The results indicated that Pt(II) porphyrins greatly enhanced the photocatalytic efficiency of bare TiO{sub 2} in photodegrading the 4-NP, and the distinct space tropisms of peripheral substituents in meso-sites of porphyrin ring led to different results.

  6. A label-free colorimetric aptasensor for simple, sensitive and selective detection of Pt (II) based on platinum (II)-oligonucleotide coordination induced gold nanoparticles aggregation.

    Science.gov (United States)

    Fan, Daoqing; Zhai, Qingfeng; Zhou, Weijun; Zhu, Xiaoqing; Wang, Erkang; Dong, Shaojun

    2016-11-15

    Herein, a gold nanoparticles (AuNPs) based label-free colorimetric aptasensor for simple, sensitive and selective detection of Pt (II) was constructed for the first time. Four bases (G-G mismatch) mismatched streptavidin aptamer (MSAA) was used to protect AuNPs from salt-induced aggregation and recognize Pt (II) specifically. Only in the presence of Pt (II), coordination occurs between G-G bases and Pt (II), leading to the activation of streptavidin aptamer. Streptavidin coated magnetic beads (MBs) were used as separation agent to separate Pt (II)-coordinated MSAA. The residual less amount of MSAA could not efficiently protect AuNPs anymore and aggregation of AuNPs will produce a colorimetric product. With the addition of Pt (II), a pale purple-to-blue color variation could be observed by the naked eye. A detection limit of 150nM and a linear range from 0.6μM to 12.5μM for Pt (II) could be achieved without any amplification. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Trans-ligand-dependent arrangement (bent or linear) of Pt II-bound dialkylcyanamide ligands: Molecular structure of trans-dichloro(dimethylcyanamide)(dimethyl sulfoxide)platinum(II)

    Science.gov (United States)

    Anisimova, Tatyana B.; Bokach, Nadezhda A.; Fritsky, Igor O.; Haukka, Matti

    2011-11-01

    The title compound, trans-[PtCl 2(NCNMe 2)(Me 2SO)], is the first example of the structurally characterized Pt II species having the nitrile and the sulfoxide ligands in the trans-position to each other. The most significant feature of this structure is the non-linear arrangement of the Pt sbnd N1 sbnd C1 fragment providing the rare case of the bent form of the dialkylcyanamide ligand.

  8. Crystal structure of the coordination polymer [FeIII2{PtII(CN4}3

    Directory of Open Access Journals (Sweden)

    Maksym Seredyuk

    2015-01-01

    Full Text Available The title complex, poly[dodeca-μ-cyanido-diiron(IIItriplatinum(II], [FeIII2{PtII(CN4}3], has a three-dimensional polymeric structure. It is built-up from square-planar [PtII(CN4]2− anions (point group symmetry 2/m bridging cationic [FeIIIPtII(CN4]+∞ layers extending in the bc plane. The FeII atoms of the layers are located on inversion centres and exhibit an octahedral coordination sphere defined by six N atoms of cyanide ligands, while the PtII atoms are located on twofold rotation axes and are surrounded by four C atoms of the cyanide ligands in a square-planar coordination. The geometrical preferences of the two cations for octahedral and square-planar coordination, respectively, lead to a corrugated organisation of the layers. The distance between neighbouring [FeIIIPtII(CN4]+∞ layers corresponds to the length a/2 = 8.0070 (3 Å, and the separation between two neighbouring PtII atoms of the bridging [PtII(CN4]2− groups corresponds to the length of the c axis [7.5720 (2 Å]. The structure is porous with accessible voids of 390 Å3 per unit cell.

  9. Sulfur-tolerant Pt-supported catalysts for benzene hydrogenation. II. Influence of cation exchange level for Pt/MOR-based catalysts

    NARCIS (Netherlands)

    Simon, L.; van Ommen, J.G.; Jentys, A.; Lercher, J.A.

    2001-01-01

    Two reaction pathways are described for the hydrogenation of benzene over Pt/MOR, i.e., (i) on the metal particles and (ii) on Brønsted acid sites of MOR at the boundary to the metal, with atomic hydrogen being dissociated on the metal. The ratio between the two pathways depends on the zeolite acid

  10. Investigation of interaction between the Pt(II) ions and aminosilane-modified silica surface in heterogeneous system

    Science.gov (United States)

    Nowicki, Waldemar; Gąsowska, Anna; Kirszensztejn, Piotr

    2016-05-01

    UV-vis spectroscopy measurements confirmed the reaction in heterogeneous system between Pt(II) ions and ethylenediamine type ligand, n-(2-aminoethyl)-3-aminopropyl-trimethoxysilane, immobilized at the silica surface. The formation of complexes is a consequence of interaction between the amine groups from the ligand grafted onto SiO2 and ions of platinum. A potentiometric titration technique was to determine the stability constants of complexes of Pt(II) with immobilized insoluble ligand (SG-L), on the silica gel. The results show the formation of three surface complexes of the same type (PtHSG-L, Pt(HSG-L)2, PtSG-L) with SG-L ligand, in a wide range of pH for different Debye length. The concentration distribution of the complexes in a heterogeneous system is evaluated.

  11. Ni(II, Pd(II and Pt(II complexes with ligand containing thiosemicarbazone and semicarbazone moiety: synthesis, characterization and biological investigation

    Directory of Open Access Journals (Sweden)

    SULEKH CHANDRA

    2008-07-01

    Full Text Available The synthesis of nickel(II, palladium(II and platinum(II complexes with thiosemicarbazone and semicarbazone of p-tolualdehyde are reported. All the new compounds were characterized by elemental analysis, molar conductance measurements, magnetic susceptibility measurements, mass, 1H-NMR, IR and electronic spectral studies. Based on the molar conductance measurements in DMSO, the complexes may be formulated as [Ni(L2Cl2] and [M(L2]Cl2 (where M = Pd(II and Pt(II due to their non-electrolytic and 1:2 electrolytic nature, respectively. The spectral data are consistent with an octahedral geometry around Ni(II and a square planar geometry for Pd(II and Pt(II, in which the ligands act as bidentate chelating agents, coordinated through the nitrogen and sulphur/oxygen atoms. The ligands and their metal complexes were screened in vitro against fungal species Alternaria alternata, Aspergillus niger and Fusarium odum, using the food poison technique.

  12. DNA-Binding Studies of Some Potential Antitumor 2,2'-bipyridine Pt(II)/Pd(II) Complexes of piperidinedithiocarbamate. Their Synthesis, Spectroscopy and Cytotoxicity.

    Science.gov (United States)

    Mansouri-Torshizi, Hassan; Eslami-Moghadam, Mahboube; Divsalar, Adeleh; Saboury, Ali-Akbar

    2011-12-01

    In this study two platinum(II) and palladium(II) complexes of the type [M(bpy)(pip-dtc)]NO3 (where M=Pt(II) or Pd(II), bpy=2,2'-bipyridine, pip-dtc=piperidinedithiocarbamate) were synthesized by reaction between diaquo-2,2'-bipyridine Pt(II)/Pd(II) nitrate and sodium salt of dithiocarbamate. These cationic water soluble complexes were characterized by elemental analysis, molar conductance, IR, electronic and 1H NMR spectroscopic studies. The cyclic dithiocarbamate was found to coordinate as bidentate fasion with Pt(II) or Pd(II) center. Their biological activities were tested against chronic myelogenous leukemia cell line, K562, at micromolar concentration. The obtained cytotoxic concentration (IC50) values were much lower than cisplatin. The interaction of these complexes with highly polymerized calf thymus DNA (ct-DNA) was extensively studied by means of electronic absorption, fluorescence, circular dichroism and other measurements. The experimental results, thermodynamic and binding parameters, suggested that these complexes cooperatively bind to DNA presumably via intercalation. Moreover, the tendency of the Pt(II) complex to interact with DNA was more than that of Pd(II) complex.

  13. Preservation of foodstuffs by irradiation

    International Nuclear Information System (INIS)

    Sielaff, H.; Thiemig, F.; Schleusener, H.

    1985-01-01

    Application and experimental testing of irradiation in foodstuff processing are accomplished in more than 20 countries. Radiation treatment of foodstuffs and commodities with doses between 0.5 - 50 kGy is licensed in the GDR, too. Examples of application of ionizing radiation in food processing are discussed

  14. Zeolite-like Metal–Organic Framework (MOF) Encaged Pt(II)-Porphyrin for Anion-Selective Sensing

    KAUST Repository

    Masih, Dilshad

    2018-03-26

    The selectivity and sensitivity of sensors are of great interest to the materials chemistry community, and a lot of effort is now devoted to improving these characteristics. More specifically, the selective sensing of anions is one of the largest challenges impeding the sensing-research area due to their similar physical and chemical behaviors. In this work, platinum–metalated porphyrin (Pt(II)TMPyP) was successfully encapsulated in a rho-type zeolite-like metal–organic framework (rho-ZMOF) and applied for anion-selective sensing. The sensing activity and selectivity of the MOF-encaged Pt(II)TMPyP for various anions in aqueous and methanolic media were compared to that of the free (nonencapsulated) Pt(II)TMPyP. While the photoinduced triplet-state electron transfer of Pt(II)TMPyP showed a very low detection limit for anions with no selectivity, the Pt(II)TMPyP encapsulated in the rho-ZMOF framework possessed a unique chemical structure to overcome such limitations. This new approach has the potential for use in other complex sensing applications, including biosensors, which require ion selectivity.

  15. Radiation treatment of foodstuffs

    International Nuclear Information System (INIS)

    Luther, T.; Huebner, G.

    1990-10-01

    In addition to fundamental demands on radiation and safety engineering of irradiation facilities, the necessity arises to optimize irradiation conditions by using facilities to capacity and thus reducing irradiation costs. The following subjects are dealt with in detail: rehabilitation of a pilot plant for radiation treatment of onions; examination of radiation resistance of components and equipment parts of food irradiation facilities; chemical dosimetry; relative measurement of the intensity of radioactive sources; thermo- and chemiluminescence to prove irradiation of foodstuffs; radiation induced sprout inhibition of potatoes; laboratory tests of delayed maturation of tomatoes; radiation treatment of strawberries; radiation treatment of forage; radiation induced sprout inhibition of acid-treated onions; radiation treatment of starch and potatoe products; radiation treatment of cosmetics; the universal radiation source UNI 88/26 for gamma irradiation facilities; microbiological aspects of food irradiation, and introduction of chicken irradiation on an industrial scale. (BBR) [de

  16. Health aspects of foodstuff treatment

    International Nuclear Information System (INIS)

    Wolf, A.

    1984-01-01

    The wholesomeness of foods irradiated with ionizing radiation is discussed with regard to five criteria: 1. induced activity, 2. undesirable changes for sensory perception, 3. losses of biological value, 4. microbiological changes, 5. formation of toxic products. The production of induced activity was experimentally found to be negligible, losses of biological values (vitamin content) are comparable with thermal preservation procedures. The limits of sensory receptibility widely differ for different foodstuffs and are tabulated together with a list of doses needed for the inactivation of microorganisms. Carcinogenic effect of irradiated foodstuffs were not proved. Cytotoxicity of radiation products in foodstuffs was studied and the results are tabulated. (E.F.)

  17. Radioactivity in foodstuffs 1989

    International Nuclear Information System (INIS)

    1990-01-01

    The average intake of radioactivity via foodstuffs remained relatively constant at about 10000 Bq per annum during the entire period elapsing since the Chernobyl accident. However, the dose received by especially exposed population groups has been considerably higher. In particular, the intake of radioactivity through the consumption of reindeer meat and freshwater fish has been high among certain groups (hunters and angler, and Sami reindeer herdsmen in southern and mid-Norway). Studies show that their dietary radionuclide exposure was highest during the second year post Cernobyl. The existing intervention levels were also applied in 1989. These are, with the exception of the limit of 6000 Bq/kg for reindeer meat, game meat and freshwater fish, identical with the maximum levels laid down by the EC. The present report reviews the data concerning radioactivity levels in dairy products, meat and fish recorded during 1989. Overall, it may be concluded that levels were considerable lower than the previous year. An important reason for this was the almost complete absence, in outlying pastures, of various types of fungi eaten by grazing livestock, such fungi being a major source of radioactivity. 4 figs., 3 tabs

  18. Radioactivity in foodstuffs 1990

    International Nuclear Information System (INIS)

    1991-01-01

    The average per capita radiation dose received by the Norwegian population due to intake of foodstuffs in 1990 was between 0.03 and 0.06 mSv. This was about the same level as in previous years since the Chernobyl accident. Certain individuals with special dietary habits (consumption of large amounts of freshwater fish and reindeer), and who live in heavily contaminated areas, received higher doses (appr. 1 mSv). In 1990 dietary advice was maintained with regard to people consuming large amounts of reindeer meat and/or game and freshwater fish. The aim is still that no person shall be exposed to an annual dose of more than 1 mSv through food. The present report reviews the data concerning radioactivity levels in dairy products, meat and fish for 1990. Levels were similar to those recorded in the previous year, but considerably lower than those in 1988. The report also presents some data from a 5-year radio-ecological research programme carried out by the Norwegian Institute of Nature Research (NINA). In general, levels in wild fish and game were below the intervention limit of 6000 Bq/kg, apart from a few reindeer herds and fish from a few localities. 8 figs. 6 tabs

  19. The DNA binding site specificity and antiproliferative property of ternary Pt(II) and Zn(II) complexes of phenanthroline and N,N'-ethylenediaminediacetic acid.

    Science.gov (United States)

    Nakamura, Yusuke; Taruno, Yoko; Sugimoto, Masashi; Kitamura, Yusuke; Seng, Hoi Ling; Kong, Siew Ming; Ng, Chew Hee; Chikira, Makoto

    2013-03-14

    The binding site specificity of the ternary complexes, [M(II)(phen)(edda)] (M(II) = Pt(2+) and Zn(2+); phen = 1,10-phenanthroline; edda = N,N'-ethylenediaminediacetic acid), for the self-complementary oligonucleotides (ODNs), ds(C(1)G(2)C(3)G(4)A(5)A(6)T(7)T(8)C(9)G(10)C(11)G(12))(2) (ODN1) and ds(C(1)G(2)C(3)G(4)T(5)A(6)T(7)A(8)C(9)G(10)C(11)G(12))(2) (ODN2), was studied by NMR measurements. The results indicated that [Pt(ii)(phen)(edda)] was partially intercalated between C(3)/G(10) and G(4)/C(9) base pairs of ODN1 and ODN2 in the major grooves, whereas [Zn(II)(phen)(edda)] was bound specifically to the TATA region of ODN2 in the minor groove and to the terminal G(2)/C(11) base pair of ODN1 in the major groove. The preference for the TATA sequence over the AATT sequence in the binding of [Zn(phen)(edda)] was attributed to the wider minor groove width of the TATA sequence. The bindings of the complexes to ct-DNA were also studied by UV, CD, and fluorescence spectroscopy. Additionally, the antiproliferative property of [Pt(II)(phen)(edda)] towards MCF7 breast cancer cells and normal MCF10-A cells was compared with that of [Zn(II)(phen)(edda)].

  20. Heavy metals in our foodstuffs

    Energy Technology Data Exchange (ETDEWEB)

    1983-11-01

    The special group ''chemistry of food and forensic chemistry'' of the Association of German Analytical Chemists in Munich in 1983 issued a statement on that subject. The publication points out how heavy metals (examples: lead, cadmium and mercury) make their way into the foodstuffs, how many heavy metals are contained in our foodstuffs, which heavy metals are indispensable minerals and which aren't, and which heavy metals are ingested with food. It concludes by discussing how heavy metal contamination of our food can be prevented.

  1. Extraction behaviour and mechanism of Pt(iv) and Pd(ii) by liquid-liquid extraction with an ionic liquid [HBBIm]Br.

    Science.gov (United States)

    Liu, Wenhui; Wang, Qi; Zheng, Yan; Wang, Shubin; Yan, Yan; Yang, Yanzhao

    2017-06-06

    In this study, a method of one-step separation and recycling of high purity Pd(ii) and Pt(iv) using an ionic liquid, 1-butyl-3-benzimidazolium bromate ([HBBIm]Br), was investigated. The effects of [HBBIm]Br concentration, initial metal concentration, and loading capacity of [HBBIm]Br were examined in detail. It was observed that [HBBIm]Br was a very effective extractant for selectively extracting Pd(ii) and precipitating Pt(iv). Through selectively extracting Pd(ii) and precipitating Pt(iv), each metal with high purity was separately obtained from mixed Pd(ii) and Pt(iv) multi-metal solution. The method of one-step separation of Pd(ii) and Pt(iv) is simple and convenient. The anion exchange mechanism between [HBBIm]Br and Pt(iv) was proven through Job's method and FTIR and 1 H NMR spectroscopies. The coordination mechanism between [HBBIm]Br and Pd(ii) was demonstrated via single X-ray diffraction and was found to be robust and distinct, as supported by the ab initio quantum-chemical studies. The crystals of the [PdBr 2 ·2BBIm] complex were formed first. Moreover, the influence of the concentrations of hydrochloric acid, sodium chloride, and sodium nitrate on the precipitation of Pt(iv) and extraction of Pd(ii) was studied herein. It was found that only the concentration of H + could inhibit the separation of Pt(iv) because H + could attract the anion PtCl 6 2- ; thus, the exchange (anion exchange mechanism) between the anions PtCl 6 2- and Br - was prevented. However, both the concentration of H + and Cl - can obviously inhibit the extraction of Pd(ii) because H + and Cl - are the reaction products and increasing their concentration can inhibit the progress of the reaction (coordination mechanism).

  2. A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor.

    Science.gov (United States)

    Bryant, M J; Skelton, J M; Hatcher, L E; Stubbs, C; Madrid, E; Pallipurath, A R; Thomas, L H; Woodall, C H; Christensen, J; Fuertes, S; Robinson, T P; Beavers, C M; Teat, S J; Warren, M R; Pradaux-Caggiano, F; Walsh, A; Marken, F; Carbery, D R; Parker, S C; McKeown, N B; Malpass-Evans, R; Carta, M; Raithby, P R

    2017-11-27

    Selective, robust and cost-effective chemical sensors for detecting small volatile-organic compounds (VOCs) have widespread applications in industry, healthcare and environmental monitoring. Here we design a Pt(II) pincer-type material with selective absorptive and emissive responses to methanol and water. The yellow anhydrous form converts reversibly on a subsecond timescale to a red hydrate in the presence of parts-per-thousand levels of atmospheric water vapour. Exposure to methanol induces a similarly-rapid and reversible colour change to a blue methanol solvate. Stable smart coatings on glass demonstrate robust switching over 10 4 cycles, and flexible microporous polymer membranes incorporating microcrystals of the complex show identical vapochromic behaviour. The rapid vapochromic response can be rationalised from the crystal structure, and in combination with quantum-chemical modelling, we provide a complete microscopic picture of the switching mechanism. We discuss how this multiscale design approach can be used to obtain new compounds with tailored VOC selectivity and spectral responses.

  3. Spectroscopic, electrochemical and photovoltaic properties of Pt(ii) and Pd(ii) complexes of a chelating 1,10-phenanthroline appended perylene diimide.

    Science.gov (United States)

    Işık Büyükekşi, Sebile; Şengül, Abdurrahman; Erdönmez, Seda; Altındal, Ahmet; Orman, Efe Baturhan; Özkaya, Ali Rıza

    2018-02-20

    In this study, a bis-chelating bridging perylene diimide ditopic ligand, namely N,N'-di(1,10-phenanthroline)-1,6,7,12-tetrakis-(4-methoxyphenoxy)perylene tetracarboxylic acid diimide (1), was synthesized and characterized. Further reactions of 1 with d 8 metal ions such as Pt(ii) and Pd(ii) having preferential square-planar geometry afforded the novel triads [(Cl 2 )M(ii)-(1)-M(ii)(Cl 2 )] where M(ii) = Pt(ii) (2), and Pd(ii) (3), respectively. The isolated triads and the key precursor were fully characterized by FT-IR, 1D-NMR ( 1 H NMR and 13 C DEPT NMR), 2D-NMR ( 1 H- 1 H COSY, 1 H- 13 C HSQC, 1 H- 13 C HMBC), MALDI-TOF mass and UV/Vis spectroscopy. The electrochemical properties of 1, 2 and 3 were investigated by cyclic voltammetry as well as in situ spectroelectrochemistry and also in situ electrocolorimetric measurements. These compounds were shown to exhibit net colour changes suitable for electrochromic applications. The compounds exhibited remarkably narrow HOMO-LUMO gaps, leading to their ease of reduction at low negative potentials. More importantly, dye-sensitized solar cells (DSSCs) were also fabricated using 1-3 to clarify the potential use of these complexes as a sensitizer. Analysis of the experimental data indicated that 2 has good potential as a sensitizer material for DSSCs.

  4. Electrochemical and SEM studies of tetra-ammine platinum (II) (Pt(NH3)4)(OH)2 solution

    International Nuclear Information System (INIS)

    Wan Jeffrey Basirun

    2002-01-01

    Electrochemical studies include cyclic voltammetry with microelectrodes were done on a solution of tetra-ammine platinum (II) (Pt(NH 3 ) 4 )(OH) 2 at pH 13 and showed that the electrochemical reduction of this compound was no different from the tetra-ammine platinum (II) (Pt(NH 3 ) 4 )(HPO 4 ) at pH 10.4. The solution was instable to high temperatures and results have shown that electroplating can be done at a limited temperature range for longer periods of time or at higher temperatures for short periods of time. Scanning electron microscopy was done on some of the constant current electrodeposited samples at high temperatures and result obtained was satisfactory. (Authors)

  5. Exploring the metal coordination properties of the pyrimidine part of purine nucleobases: isomerization reactions in heteronuclear Pt(II)/Pd(II) of 9-methyladenine.

    Science.gov (United States)

    Ibáñez, Susana; Albertí, Francisca M; Sanz Miguel, Pablo J; Lippert, Bernhard

    2011-10-17

    The synthesis and characterization of three heteronuclear Pt(2)Pd(2) (4, 5) and PtPd(2) (6) complexes of the model nucleobase 9-methyladenine (9-MeA) is reported. The compounds were prepared by reacting [Pt(NH(3))(3)(9-MeA-N7)](ClO(4))(2) (1) with [Pd(en)(H(2)O)(2)](ClO(4))(2) at different ratios r between Pt and Pd, with the goal to probe Pd(II) binding to any of the three available nitrogen atoms, N1, N3, N6 or combinations thereof. Pd(II) coordination occurs at N1 and at the deprotonated N6 positions, yet not at N3. 4 and 5 are isomers of [{(en)Pd}(2){N1,N6-9-MeA(-)-N7)Pt(NH(3))(3)}(2)](ClO(4))(6)·nH(2)O, with a head-head orientation of the two bridging 9-MeA(-) ligands in 4 and a head-tail orientation in 5. 6 is [{(en)Pd}(2)(OH)(N1,N6-9MeA(-)-N7)Pt(NH(3))(3)](ClO(4))(4)·4H(2)O, hence a condensation product between [Pt(NH(3))(3)(9-MeA-N7)](2+) and a μ-OH bridged dinuclear (en)Pd-OH-Pd(en) unit, which connects the N1 and N6 positions of 9-MeA(-) in an intramolecular fashion. 4 and 5, which slowly interconvert in aqueous solution, display distinct structural differences such as significantly different intramolecular Pd···Pd contacts (3.124 0(16) Å in 4; 2.986 6(14) Å in 5), among others. Binding of (en)Pd(II) to the exocyclic N6 atom in 4 and 5 is accompanied by a large movement of Pd(II) out of the 9-MeA(-) plane and a trend to a further shortening of the C6-N6 bond as compared to free 9-MeA. The packing patterns of 4 and 5 reveal substantial anion-π interactions.

  6. Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(µ-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy = 2,2'-bipyridine)

    NARCIS (Netherlands)

    Koten, G. van; Casado Lacabra, M.A.; Canty, A.J.; Lutz, M.H.; Patel, J.; Spek, A.L.; Sun, H.

    2001-01-01

    The complex trans-PtCl(p-Tol)(SEt{2}){2} is obtained from the reaction of [Pt(p-Tol){2}(SEt{2})]{2} with PtCl{2}(SEt{2}){2} and SEt{2} in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2, 2'-bipyridine to form the complexes

  7. The wholesomeness of irradiated foodstuffs

    International Nuclear Information System (INIS)

    Elias, P.S.

    1992-01-01

    The evaluation of the wholesomeness of irradiated foodstuffs is based on a large body of scientific data mainly from four areas: the radiochemical effects of ionising radiation, the toxicity of irradiated foodstuffs, the microbiological effects and the nutritional aspects. The technology of processing food with ionising radiation with the objectives of decontamination, disinfestation and of extended shelf life has been investigated in many countries for more than fourty years. The wholesomeness of irradiated food has been examined over the same period through intensive research into the radiochemical, toxicological, microbiological and nutritional changes resulting from this processing technology. The ultimate result was the decision of the international Joint FAO/IAEA/WHO Expert Committee, published in 1981, to regard in general the irradiation of food in the dose range up to 10 kGy as an acceptable processing technology and to consider foodstuffs so treated as wholesome. A large number of national authorities came to similar conclusions following their own evaluation of the available data. The most important scientific results, the general restrictions on the use of food irradiation, and existing prejudices will be dealt with. (orig.) [de

  8. Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II and Pd(II with Ethyl-α-Isonitrosoacetoacetate and Dienes

    Directory of Open Access Journals (Sweden)

    Anita Krishankant Taksande

    2015-12-01

    Full Text Available The mixed ligand complexes of the kind [M(L1 (L2] where M= Pt(II, Pd(II.L1 = primary ligand ethyl-α-isonitrosoacetoacetate derived from reaction between ethyl acetoacetate, acetic acid and sodium nitrite and L2=secondary ligand para-phenyldiamine (PPD are synthesized. All the prepared complexes were identified and confirmed by elemental analysis, molar conductance measurements, and infrared electronic absorption. Their complexes has been made based on elemental analysis, molar conductivity, UV-Vis, FT-IR and 1HNMR spectroscopy and magnetic moment measurements as well as thermal analysis (TGA and DTA. The elemental analysis information recommends that the stoichiometry of the complexes to be 1:2:1. The molar conductance measurements of the complexes indicate their non-electrolytic nature. The infrared spectral information showed the coordination sites of the free ligand with the central metal particle. The electronic absorption spectral information disclosed the existence of an octahedral geometry for Pt(II and Pd(II complexes. DOI: http://dx.doi.org/10.17807/orbital.v7i4.633 

  9. Stabilization and reactivity of a terminal phosphidounit on Pt(II). Synthesis and X-ray structure of cationic diphelylphosphine [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][CF3SO3] and Diphenyl-phosphido Bridged Pt(II)-Pd(II) Complex [Pt{C6H3(CH2NMe2)2-2,6} (µ-PPh2) Pd(C6H4CH2NMe2-2)(H2O)][BF4] CH2Cl2

    NARCIS (Netherlands)

    Koten, G. van; Maassarani, F.; Davidson, M.F.; Wehman-Ooyevaar, ICM; Grove, D.M.; Koten, M.A. van; Smeets, W.J.J.; Spek, A.L.

    1995-01-01

    Reaction of diphenylphosphine with the complexes [Pt(NCN)(H{2}O)]X (NCN = C{6}H{3}(CH{2}NMe{2}){2}-2, 6; X = BF{4} (1a), OSO{2}CF{3} (1b)) leads to substitution of the H{2}O ligand to afford the ionic Pt(II) complexes [Pt(NCN)(PHPh{2})]X (X = BF{4} (2a), OSO{2}CF{3} (2b)). The X-ray structure of the

  10. Sublethal concentrations of the platinum(II) complex [Pt(O,O'-acac)(gamma-acac)(DMS)] alter the motility and induce anoikis in MCF-7 cells.

    Science.gov (United States)

    Muscella, Antonella; Calabriso, Nadia; Vetrugno, Carla; Urso, Loredana; Fanizzi, Francesco Paolo; De Pascali, Sandra Angelica; Marsigliante, Santo

    2010-07-01

    We showed previously that a new Pt(II) complex ([Pt(O,O'-acac)(gamma-acac)(DMS)]) exerted high and fast apoptotic processes in MCF-7 cells. The objective of this study was to investigate the hypothesis that [Pt(O,O'-acac)(gamma-acac)(DMS)] is also able to exert anoikis and alter the migration ability of MCF-7 cells, and to show some of the signalling events leading to these alterations. Cells were treated with sublethal doses of [Pt(O,O'-acac)(gamma-acac)(DMS)], and the efficiency of colony initiation and anchorage-independent growth was assayed; cell migration was examined by in vitro culture wounding assay. Gelatin zymography for MMP-2 and -9 activities, Western blottings of MMPs, MAPKs, Src, PKC-epsilon and FAK, after [Pt(O,O'-acac)(gamma-acac)(DMS)] treatment, were also performed. Sub-cytotoxic drug concentrations decreased the: (i) anchorage-dependent and -independent growth; (ii) migration ability; and (iii) expression and activity of MMP-2 and MMP-9. [Pt(O,O'-acac)(gamma-acac)(DMS)] provoked the generation of reactive oxygen species (ROS), and the activation of p38MAPK, Src and PKC-epsilon. p38MAPK phosphorylation, cell anoikis and migration due to [Pt(O,O'-acac)(gamma-acac)(DMS)] were blocked by PKC-epsilon inhibition. Furthermore, Src inhibition blocked the [Pt(O,O'-acac)(gamma-acac)(DMS)]-provoked activation of PKC-epsilon, while ROS generation blockage inhibited the activation of Src, and also the decrement of phosphorylated FAK observed in detached [Pt(O,O'-acac)(gamma-acac)(DMS)]-treated cells. Sublethal concentrations of [Pt(O,O'-acac)(gamma-acac)(DMS)] induced anoikis and prevented events leading to metastasis via alterations in cell migration, anchorage independency, stromal interactions and MMP activity. Hence, [Pt(O,O'-acac)(gamma-acac)(DMS)] may be a promising therapeutic agent for preventing growth and metastasis of breast cancer.

  11. Detection methods of irradiated foodstuffs

    Energy Technology Data Exchange (ETDEWEB)

    Ponta, C C; Cutrubinis, M; Georgescu, R [IRASM Center, Horia Hulubei National Institute for Physics and Nuclear Engineering, PO Box MG-6, RO-077125 Magurele-Bucharest (Romania); Mihai, R [Life and Environmental Physics Department, Horia Hulubei National Institute for Physics and Nuclear Engineering, PO Box MG-6, RO-077125 Magurele-Bucharest (Romania); Secu, M [National Institute of Materials Physics, Bucharest (Romania)

    2005-07-01

    Full text: Food irradiation has, in certain circumstances, an important role to play both in promoting food safety and in reducing food losses. The safety and availability of nutritious food are essential components of primary health care. WHO actively encourages the proper use of food irradiation in the fight against foodborne diseases and food losses. To this end, it collaborates closely with FAO and IAEA. Food irradiation can have a number of beneficial effects, including delay of ripening and prevention of sprouting; control of insects, parasites, helminths, pathogenic and spoilage bacteria, moulds and yeasts; and sterilization, which enables commodities to be stored unrefrigerated for long periods. The 1990s witnessed a significant advancement in food irradiation processing. As a result, progress has been made in commercialization of the technology, culminating in greater international trade in irradiated foods and the implementation of differing regulations relating to its use in many countries. Codex General Standard for Irradiated Foodstuffs and Recommended International Code of Practice for the Operation of Irradiation Facilities Used for the Treatment of Foods regulate food irradiation at international level. At European Union level there are in power Directive 1999/2/EC and Directive1999/3/EC. Every particular country has also its own regulations regarding food irradiation. In Romania, since 2002 the Norms Regarding Foodstuffs and Food Ingredients Treated by Ionizing Radiation are in power. These Norms are in fact the Romanian equivalent law of the European Directives 1999/2/EC and 1999/3/EC. The greater international trade in irradiated foods has led to the demand by consumers that irradiated food should be clearly labeled as such and that methods capable of differentiating between irradiated and nonirradiated products should be available. Thus a practical basis was sought to allow consumers to exercise a free choice as to which food they purchase. If a

  12. Hybrid white organic light-emitting diodes combining blue-fluorescent polymer and red phosphorescent Pt(II) complexes as active layer

    Energy Technology Data Exchange (ETDEWEB)

    Germino, Jose Carlos; Faleiros, Marcelo Meira; Moraes, Emmanuel Santos; Atvars, Teresa Dib Zambon, E-mail: kakagermino@hotmail.com [Universidade Estadual de Campinas (UNICAMP), SP (Brazil); Domingues, Raquel Aparecida [Universidade Federal de Sao Paulo (UNIFESP), SP (Brazil); Quites, Fernando Junior [Universidade Federal de Mato Grosso (UFMT), Cuiaba, MT (Brazil); Freitas, Jilian Nei de [Centro de Tecnologia da Informacao Renato Archer, Campinas, SP (Brazil)

    2016-07-01

    Full text: In this work we proposed a PFO composite with two salicylidene based Pt(II) coordination compounds, the [Pt(salophen)] and [Pt(sal-3,4-ben)] (red emitters), as emissive layer (EML) for Organic Light-emitting Diodes (OLEDs), combining a blue-fluorescent polymer (PFO) with red-phosphorescent Pt(II) coordination complexes in order to obtain an efficient white electroluminescent EML for WOLEDs application. Firstly, [Pt(salophen)] and [Pt(sal-3,4-ben)] were synthesized, purified and characterized by single crystal X-ray diffraction, yielding their respective expected molecular structures. The photoluminescence properties of the devices were evaluated by steady-state (electronic absorption and emission spectroscopies) and transient (fluorescence decays and TRES) measurements. It was observed the presence of non-radiative energy transfer processes between the PFO derivative and Pt(II) complexes. Posteriorly, the Pt(II) complexes were blended with PVK at 1% mol:mol ratio and OLEDs were made, leading to red-emitting devices with high color purity for the two coordination compounds. However, the two devices present low current efficiency values. In order to improve the electroluminescence properties of Pt(II) complexes PhOLEDs, PVK host was substituted by PFO at 0.5, 1.0 and 2.5% mol:mol ratios of complex and it was observed a great improvement of their optical-electronic properties in terms of luminance, voltage, current density and current efficiency in comparison to PVK composites or pure PFO devices. At 2.5% concentration, predominant bands of Pt(II) complexes were observed at low and high voltages. For the other concentrations, a different behavior was observed: the emission bands and device color were function of applied electrical field, exhibiting a red color at lower voltages (5 to 9V) and the PFO characteristic emission between 9 and 13V, leading to a white light emission at 13V. The best results were obtained for [Pt(sal-3,4-ben)] coordination compound

  13. Survey of radioactive contamination for foodstuffs

    International Nuclear Information System (INIS)

    Lee, Wan No; Lee, Chang Wu; Choi, Geun Sik; Cho, Yeong Hyeon; Kang, Mun Ja; Cheong, Geun Ho; Kim, Hui Ryeong; Park, Du Won; Park, Hyo Guk; Kwak, Ji Yeon

    2006-11-01

    After the Chernobyl nuclear accident in 1986, a lot of countries including EU, Japan, USA are to strengthen survey of radioactive contamination for foodstuffs. Our country has also surveyed radioactive contamination of the imported foodstuffs and started to check continuously the radioactivity contamination of the open market foodstuffs since 2003. In this year, imported foodstuffs(130 samples) and domestic foodstuffs(10 samples) are analyzed to investigate the radioactive contamination. Sampled foodstuffs items are collected from the open markets; one group is the imported foodstuffs and the other group is the domestic foodstuffs producted around nuclear facilities and northeast of Sokcho city concerning recent situations. Samples are usually bought from traditional markets, mart, department store or the Internet. After pretreatments such as drying, ashing, and homogenization, all samples were analyzed by gamma spectrometer system for survey and assessment of radioactive contamination. The 131 I radionuclide isn't detected among all foodstuffs(imported and domestic). The 137 Cs radionuclide among the regulation radionuclides( 137 Cs, 13 4 C s, 131 I) of food code is only detected at the imported foodstuffs but its level is far below the maximum permitted level. For the improvement of measurement confidence, the developed analysis method is tested by the participation of the national and international intercomparison. The developed method based on test results and international standard would be used at radioactive analysis as well as an education of relative workers. It could be applied as the basis data for amending the analysis method of food code. It is technically supported for radioactive analysis of commercial company and the government including KFDA. Finally these results would be used to solve an ambiguous anxiety of a people for radiation exposure by foodstuffs intake and help the KFDA to manage systematically the radioactive contamination and to give

  14. Synthesis of 15N-enriched fertilizers. Pt. II. Synthesis of 15N-enriched urea

    International Nuclear Information System (INIS)

    Bondassolli, J.A.; Trivelin, P.C.O.; Mortatti, J.; Victoria, R.L.

    1988-01-01

    The results of studies on the production of 15 N-urea through the reaction between 15 N-enriched anhidrous ammonia, carbon monoxide and sulfur, using hydrogen sulfite as a auto catalizers and methyl alcohol as a liquid reaction medium is presented. The influence of the quantities of reagents on final yield of synthesised urea were studied. Analysis of the cost of 5 Atoms % 15 N-enriched urea were made. (M.A.C.) [pt

  15. Bluish-green BMes2-functionalized Pt(II) complexes for high efficiency PhOLEDs: impact of the BMes2 location on emission color.

    Science.gov (United States)

    Rao, Ying-Li; Schoenmakers, Dylan; Chang, Yi-Lu; Lu, Jia-Sheng; Lu, Zheng-Hong; Kang, Youngjin; Wang, Suning

    2012-09-03

    New phosphorescent Pt(II) compounds based on dimesitylboron (BMes(2))-functionalized 2-phenylpyridyl (ppy) N,C-chelate ligands and an acetylacetonato ancillary ligand have been achieved. We have found that BMes(2) substitution at the 4'-position of the phenyl ring can blue-shift the phosphorescent emission energy of the Pt(II) compound by approximately 50 nm, compared to the 5'-BMes(2) substituted analogue, without substantial loss of luminescent quantum efficiencies. The emission color of the 4'-BMes(2) substituted Pt(II) compound, Pt(Bppy)(acac) (1) can be further tuned by the introduction of a substituent group at the 3'-position of the phenyl ring. A methyl substituent red-shifts the emission energy of 1 by approximately 10 nm whereas a fluoro substituent blue-shifts the emission energy by about 6 nm. Using this strategy, three bright blue-green phosphorescent Pt(II) compounds 1, 2 and 3 with emission energy at 481, 492, and 475 nm and Φ(PL)=0.43, 0.26 and 0.25, respectively, have been achieved. In addition, we have examined the impact of BMes(2) substitution on 3,5-dipyridylbenzene (dpb) N,C,N-chelate Pt(II) compounds by synthesizing compound 4, Pt(Bdpb)Cl, which has a BMes(2) group at the 4'-position of the benzene ring. Compound 4 has a phosphorescent emission band at 485 nm and Φ(PL)=0.70. Highly efficient blue-green electroluminescent (EL) devices with a double-layer structure and compounds 1, 3 or 4 as the phosphorescent dopant have been fabricated. At 100 cd m(-2) luminance, EL devices based on 1, 3 and 4 with an external quantum efficiency of 4.7, 6.5 and 13.4%, respectively, have been achieved. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Approaching the Type-II Dirac Point and Concomitant Superconductivity in Pt-doping Stabilized Metastable 1T-phase IrTe2

    OpenAIRE

    Fei, Fucong; Bo, Xiangyan; Wang, Pengdong; Ying, Jianghua; Chen, Bo; Liu, Qianqian; Zhang, Yong; Sun, Zhe; Qu, Fanming; Zhang, Yi; Li, Jian; Song, Fengqi; Wan, Xiangang; Wang, Baigeng; Wang, Guanghou

    2017-01-01

    Topological semimetal is a topic of general interest in material science. Recently, a new kind of topological semimetal called type-II Dirac semimetal with tilted Dirac cones is discovered in PtSe2 family. However, the further investigation is hindered due to the huge energy difference from Dirac points to Fermi level and the irrelevant conducting pockets at Fermi surface. Here we characterize the optimized type-II Dirac dispersions in a metastable 1T phase of IrTe2. Our strategy of Pt doping...

  17. Molecular-wire behavior of OLED materials: exciton dynamics in multichromophoric Alq3-oligofluorene-Pt(II)porphyrin triads.

    Science.gov (United States)

    Montes, Victor A; Pérez-Bolívar, César; Agarwal, Neeraj; Shinar, Joseph; Anzenbacher, Pavel

    2006-09-27

    Donor-bridge-acceptor triads consisting of the Alq3 complex, oligofluorene bridge, and PtII tetraphenylporphyrin (PtTPP) were synthesized. The triads were designed to study the energy level/distance-dependence in energy transfer both in a solution and in solid state. The materials show effective singlet transfer from the Alq3-fluorene fluorophore to the porphyrin, while the triplet energy transfer, owing to the shorter delocalization of triplet excitons, appears to take place via a triplet energy cascade. Using femtosecond transient spectroscopy, the rate of the singlet-singlet energy transfer was determined. The exponential dependence of the donor-acceptor distance and the respective energy transfer rates of 7.1 x 1010 to 1.0 x 109 s-1 with the attenuation factor â of 0.21 +/- 0.02 A-1 suggest that the energy transfer proceeds via a mixed incohererent wire/superexchange mechanism. In the OLEDs fabricated using the Alq3-oligofluorene-PtTPP triads with better triplet level alignment, the order of a magnitude increase in efficacy appears to be due to facile triplet energy transfer. The devices, where the triplet-triplet energy transfer is of paramount importance, showed high color purity emission (CIE X,Y: 0.706, 0.277), which is almost identical to the emission from thin films. Most importantly, we believe that the design principles demonstrated above are general and may be used to prepare OLED materials with enhanced quantum efficacy at lowered operational potentials, being crucial for improved lifespan of OLEDs.

  18. Recent results of high p(T) physics at the CDF II

    Energy Technology Data Exchange (ETDEWEB)

    Tsuno, Soushi; /Okayama U.

    2005-02-01

    The Tevatron Run II program has been in progress since 2001. The CDF experiment has accumulated roughly five times as much data as did Run I, with much improved detectors. Preliminary results from the CDF experiment are presented. The authors focus on recent high p{sub T} physics results in the Tevatron Run II program.

  19. Preparation, structural characterization, and catalytic performance of Pd(II) and Pt(II) complexes derived from cellulose Schiff base

    Science.gov (United States)

    Baran, Talat; Yılmaz Baran, Nuray; Menteş, Ayfer

    2018-05-01

    In this study, we reported production, characterization, and catalytic behavior of two novel heterogeneous palladium(II) and platinum(II) catalysts derived from cellulose biopolymer. In order to eliminate the use of toxic organic or inorganic solvents and to reduce the use of excess energy in the coupling reactions, we have developed a very simple, rapid, and eco-friendly microwave irradiation protocol. The developed microwave-assisted method of Suzuki cross coupling reactions produced excellent reaction yields in the presence of cellulose supported palladium and platinum (II) catalysts. Moreover, the catalysts easily regenerated after simple filtration, and they gave good reusability. This study revealed that the designed catalysts and method provide clean, simple, rapid, and impressive catalytic performance for Suzuki coupling reactions.

  20. Synthesis, spectral and theoretical studies of Ni(II), Pd(II) and Pt(II) complexes of 5-mercapto-1,2,4-triazole-3-imine-2‧-hydroxynaphyhaline

    Science.gov (United States)

    Gaber, Mohamed; El-Ghamry, Hoda; Atlam, Faten; Fathalla, Shaimaa

    2015-02-01

    Ni(II), Pd(II) and Pt(II) complexes of 5-mercapto-1,2,4-triazole-3-imine-2‧-hydroxynaphthaline have been isolated and characterized by elemental analysis, IR, 1H NMR, EI-mass, UV-vis, molar conductance, magnetic moment measurements and thermogravimetric analysis. The molar conductance values indicated that the complexes are non-electrolytes. The magnetic moment values of the complexes displayed diamagnetic behavior for Pd(II) and Pt(II) complexes and tetrahedral geometrical structure for Ni(II) complex. From the bioinorganic applications point of view, the interaction of the ligand and its metal complexes with CT-DNA was investigated using absorption and viscosity titration techniques. The Schiff-base ligand and its metal complexes have also been screened for their antimicrobial and antitumor activities. Also, theoretical investigation of molecular and electronic structures of the studied ligand and its metal complexes has been carried out. Molecular orbital calculations were performed using DFT (density functional theory) at B3LYP level with standard 6-31G(d,p) and LANL2DZ basis sets to access reliable results to the experimental values. The calculations were performed to obtain the optimized molecular geometry, charge density distribution, extent of distortion from regular geometry, the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO), Mulliken atomic charges, reactivity index (ΔE), dipole moment (D), global hardness (η), softness (σ), electrophilicity index (ω), chemical potential and Mulliken electronegativity (χ).

  1. Extracts from the Ordinance on foodstuffs

    International Nuclear Information System (INIS)

    1936-05-01

    This Ordinance which regulates the consumption and treatment of foodstuffs also contains provisions on irradiated food, providing in particular that treatment of food by irradiation is subject to a prior licence. (NEA) [fr

  2. Measurement of low $p_{T}$ $D^{0}$ meson production cross section at CDF II

    Energy Technology Data Exchange (ETDEWEB)

    Mussini, Manuel [Univ. of Bologna (Italy)

    2011-05-01

    In this thesis we present a study of the production of D0 meson in the low transverse momentum region. In particular the inclusive differential production cross section of the D0 meson (in the two-body decay channel D0 → K-π+) is obtained extending the published CDF II measurement to pT as low as 1.5 GeV/c. This study is performed at the Tevatron Collider at Fermilab with the CDF II detector.

  3. Dampak Program Corporate Social Responsibility (CSR) PT. Perkebunan Nusantara II Terhadap Tingkat Pendapatan Dan Penyerapan Tenaga Kerja

    OpenAIRE

    Hidayat Siregar, Arief Gibran; Iskandarini, Salmiah

    2013-01-01

    Tujuan penelitianini adalah untuk mengidentifikasi konsep dan kebijakan program CSR PT. Perkebunan Nusantara III; untukmengidentifikasi dampak program CSR PT. Perkebunan Nusantara III terhadap pendapatan mitra CSR; danmengidentifikasi dampak program CSR PT. Perkebunan Nusantara III terhadap penyerapan tenaga kerja mitra CSR. Metodeanalisis data yang digunakana dalahadalah analisis uji T berpasangan (Paired T-Test) untuk mengidentifikasi dampak program Corporate Social Responsibility (CSR) ter...

  4. An update on the PT-symmetric complexified Scarf II potential, spectral singularities and some remarks on the rationally extended supersymmetric partners

    International Nuclear Information System (INIS)

    Bagchi, B; Quesne, C

    2010-01-01

    The PT-symmetric complexified Scarf II potential V(x) = -V 1 sech 2 x + iV 2 sechxtanh x, V 1 > 0, V 2 ≠ 0, is revisited to study the interplay among its coupling parameters. The existence of an isolated real and positive energy level that has recently been identified as a spectral singularity or zero-width resonance is here demonstrated through the behaviour of the corresponding wavefunctions and some property of the associated pseudo-norms is pointed out. We also construct four different rationally extended supersymmetric partners to V(x), which are PT-symmetric or complex non-PT-symmetric according to the coupling parameters range. A detailed study of one of these partners reveals that SUSY preserves the V(x) spectral singularity existence.

  5. Degradation of zinc oxide thin films in aqueous environment. Pt. II. Coated films

    Energy Technology Data Exchange (ETDEWEB)

    Rosa, L. de; Mitton, D.B.; Monetta, T.; Bellucci, F. [Naples Univ. (Italy). Dept. of Materials and Production Engineering; Springer, J. [Zentrum fuer Sonnenenergie- und Wasserstoff-Forschung Baden-Wuerttemberg (ZSW), Stuttgart (Germany)

    2001-12-01

    cn Part I of this research, the degradation mechanism of two different bare ZnO thin films was assessed. Degradation of the electrical properties of ZnO as well as changes in morphology were observed for both films. In the current paper, the degradation of zinc oxide thin films coated with protective acrylic paint is addressed during exposure to (i) an aqueous 3.5% NaCl solution at 85 C and (ii) a standard damp heat test at 85% R.H. and 85 C. Electrical and electrochemical techniques were employed to monitor zinc oxide degradation during exposure to the test environments. Electrochemical Impedance Spectroscopy was employed to investigate the delamination phenomena at the ZnO/coating interface and a simple equivalent circuit was developed to quantitatively measure the delamination ratio. The effect of different silane based adhesion promoters (glycidil-oxypropyl-trimethoxy-silane and aminopropyl-trimethoxy-silane) was also investigated. (orig.)

  6. Determination of plutonium by secondary coulometric titration with internally generated iron(II) Pt. 2

    International Nuclear Information System (INIS)

    Chitnis, R.T.; Talnikar, S.G.; Thakur, V.A.; Paranjape, A.H.

    1979-01-01

    Determination of plutonium by secondary coulometry involving the controlled potential technique for the generation of an iron(II) mediator, is reported in Part I. In this paper, the same determination is reported using constant current coulometry for the generation of the mediator, and zero current potentiometry for end-point detection. The factors affecting the current efficiency, viz. current density and supporting electrolyte composition have been checked in order to define the appropriate conditions for obtaining 100% current efficiency. The original method of Carson et al. suffers from the disadvantage that it involves complicated sample treatment. Introduction of perchloric acid treatment as a method for the oxidation of plutonium and the pretitration of the supporting electrolyte to the end-point potential prior to sample addition, have considerably helped to improve the precision and accuracy of the method. Exhaustive analytical data are reported covering plutonium quantities ranging from 25 micrograms to 5 milligrams, which establishes the scope of the method. (author)

  7. Synthesis, spectral and theoretical studies of Ni(II), Pd(II) and Pt(II) complexes of 5-mercapto-1,2,4-triazole-3-imine-2'-hydroxynaphthaline.

    Science.gov (United States)

    Gaber, Mohamed; El-Ghamry, Hoda; Atlam, Faten; Fathalla, Shaimaa

    2015-02-25

    Ni(II), Pd(II) and Pt(II) complexes of 5-mercapto-1,2,4-triazole-3-imine-2'-hydroxynaphthaline have been isolated and characterized by elemental analysis, IR, (1)H NMR, EI-mass, UV-vis, molar conductance, magnetic moment measurements and thermogravimetric analysis. The molar conductance values indicated that the complexes are non-electrolytes. The magnetic moment values of the complexes displayed diamagnetic behavior for Pd(II) and Pt(II) complexes and tetrahedral geometrical structure for Ni(II) complex. From the bioinorganic applications point of view, the interaction of the ligand and its metal complexes with CT-DNA was investigated using absorption and viscosity titration techniques. The Schiff-base ligand and its metal complexes have also been screened for their antimicrobial and antitumor activities. Also, theoretical investigation of molecular and electronic structures of the studied ligand and its metal complexes has been carried out. Molecular orbital calculations were performed using DFT (density functional theory) at B3LYP level with standard 6-31G(d,p) and LANL2DZ basis sets to access reliable results to the experimental values. The calculations were performed to obtain the optimized molecular geometry, charge density distribution, extent of distortion from regular geometry, the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO), Mulliken atomic charges, reactivity index (ΔE), dipole moment (D), global hardness (η), softness (σ), electrophilicity index (ω), chemical potential and Mulliken electronegativity (χ). Copyright © 2014 Elsevier B.V. All rights reserved.

  8. FACILITIES PLANNING WORKSHOP FOR BLASTING SUPPORT THE ACTIVITY OF DEVELOPMENT AND REPAIR SHIP IN PT. JASA MARINA INDAH UNIT II

    Directory of Open Access Journals (Sweden)

    Samuel Samuel

    2012-07-01

    Full Text Available Blasting in the process of planning the workshop production of new building and ship repair to play a role in providing blasting and paint on the block that will be of erection. As a result of blasting workshop facilities that do not have resulted in low production capacity that can be achieved by this workshop, namely three block ships per month. Capacity blasting and paint shop in this low resulted in low productivity process stage (stage the previous workshops which of course result in a decrease in vessel productivity in general.                 In penelitiaan aims to plan for blasting and paint shop facility which has been adjusted to the planned production capacity of PT. JASA MARINA INDAH II units.                 In this study it - thing to note is to understand the data - the data field for research conducted in terms of both technical and economic terms, with the blasting and paint shop facilities on the construction or repair of ships that have been planned, then the effectiveness of the work and production flow at. Jasa Marina Indah II units can be known.                 Based on the analysis and calculation of both technical and economical it can be identified by the workshop on the process of blasting Blasting efficiency is obtained for 2.55 hours, at 10.16 hours during the painting process, while economical in terms of labor costs can be reduced blasting cost is Rp.930000    for          paint       and         Rp.1.23million

  9. SOUR MILK FOODSTUFF IN INFANTS DIET

    Directory of Open Access Journals (Sweden)

    T. E. Borovik

    2014-01-01

    Full Text Available Products of sour milk are widely used in nutrition of infants. They are an important source of digestible proteins, vitamins and potassium. Regular intake of sour milk foodstuff has favorable influence on intestinal microbiocenosis, functioning of the immune system, improves secretory and motor functions of the gastrointestinal tract, stimulates appetites and increases bioavailability of micronutrients. Modern line in functional diet is enrichment of sour milk foodstuff with probiotics. Strains of microorganisms used in manufacture of products with probiotic action are proven to be safe and effective in prophylaxis and treatment of various diseases. Modern data which confirm prophylactic and medicinal properties of probiotic-containing foodstuff, especially bioyoghurts for children, are shown in this article.

  10. Survey of radioactive contamination of foodstuffs

    International Nuclear Information System (INIS)

    Lee, W. R.; Lee, C. W.; Choi, G. S.; Cho, Y. H.; Kang, M. J.; Cheong, K. H.; Kim, H. R.; Kwak, J. Y.

    2005-11-01

    The purpose of this study is to survey and assess radioactive contamination of foodstuffs in order to reduce the probability of intake of contaminated foodstuffs. Based on survey and assessment, final goal is to improve the public health by radiation protection. Sampled foodstuffs items are collected from the markets : one group are imported foodstuffs and the other group are domestic foodstuffs producted around nuclear facilities. After pretreatments such as drying, ashing, and homogenization, all samples were analyzed by gamma spectrometer system. The 137 Cs radionuclide was only measured among the regulation radionuclides ( 137 Cs, 134 Cs, 131 I) of food code. All radionuclides of the domestic foodstuffs collected around nuclear facilities were below Minimum Detectable Activity (MDA). But the activity concentrations of Inonotus obliquus (Chaga mushooms) from Russia ranged up to 171.27 (average value : 36.65) Bq/kg-fresh. In the case of blueberry jam, the radioactivity of 137 Cs is higher than expected value. Other samples are below MDA except some spices. Based on the previous and present results, it should be strengthen to survey for Inontus obliquus (Chaga mushooms), of which the radioactivity shows the range from MDA up to 800.01 Bq/kg-fresh. It should assess the public radiation exposure via food chain because it has the excess provability of the maximum permitted level of food code, which is regulation of KFDA. The development method based on international standard would be used at radioactive analysis as well as education of practical workers and it could be applied as the basis data for amending the analysis method of food code. Our country only surveys gamma emitting radionuclides till now but international organization or foreign countries for example EU survey alpha and beta emitting radionuclides as well as gamma emitting radionuclides. So our country should also research necessity of survey for alpha and beta emitting radionuclides

  11. Survey of radioactive contamination of foodstuffs

    Energy Technology Data Exchange (ETDEWEB)

    Lee, W. R.; Lee, C. W.; Choi, G. S.; Cho, Y. H.; Kang, M. J.; Cheong, K. H.; Kim, H. R.; Kwak, J. Y

    2005-11-15

    The purpose of this study is to survey and assess radioactive contamination of foodstuffs in order to reduce the probability of intake of contaminated foodstuffs. Based on survey and assessment, final goal is to improve the public health by radiation protection. Sampled foodstuffs items are collected from the markets : one group are imported foodstuffs and the other group are domestic foodstuffs producted around nuclear facilities. After pretreatments such as drying, ashing, and homogenization, all samples were analyzed by gamma spectrometer system. The {sup 137}Cs radionuclide was only measured among the regulation radionuclides ({sup 137}Cs, {sup 134}Cs, {sup 131}I) of food code. All radionuclides of the domestic foodstuffs collected around nuclear facilities were below Minimum Detectable Activity (MDA). But the activity concentrations of Inonotus obliquus (Chaga mushooms) from Russia ranged up to 171.27 (average value : 36.65) Bq/kg-fresh. In the case of blueberry jam, the radioactivity of {sup 137}Cs is higher than expected value. Other samples are below MDA except some spices. Based on the previous and present results, it should be strengthen to survey for Inontus obliquus (Chaga mushooms), of which the radioactivity shows the range from MDA up to 800.01 Bq/kg-fresh. It should assess the public radiation exposure via food chain because it has the excess provability of the maximum permitted level of food code, which is regulation of KFDA. The development method based on international standard would be used at radioactive analysis as well as education of practical workers and it could be applied as the basis data for amending the analysis method of food code. Our country only surveys gamma emitting radionuclides till now but international organization or foreign countries for example EU survey alpha and beta emitting radionuclides as well as gamma emitting radionuclides. So our country should also research necessity of survey for alpha and beta emitting

  12. The measurement of radioactivity in foodstuffs

    International Nuclear Information System (INIS)

    Maushart, R.

    1988-01-01

    The fallout of radioactivity from the Chernobyl accident gave rise to the need for large numbers of field and market surveys for radioactivity in foodstuffs in Germany. Due to the implementation of new government-mandated limits and a change in consumer attitudes, this need still persists today. In this article, the various methods available for measuring radioactivity in foodstuffs are reviewed and categorized by the type of information obtained and the degree of sample pretreatment required. A new category of instrument -- a consumer version of a simple NaI(Tl) gross gamma counter -- is introduced

  13. Propylene oxidation on catalytic Pt-Cu/y alumina. (Part II) chemical Kinetics of catalysts of Pt-Cu/y-alumina in the propylene oxidation

    International Nuclear Information System (INIS)

    Carballo, Luis M; Zea, Hugo R

    1999-01-01

    In this work is treated the effect of the composition of catalysts of Pt-Cu/y - alumina on the specific superficial activity corresponding to the total oxidation of propylene. Although the catalyst activity of the Cu in the operation conditions went practically null the specific activity of the catalytic Pt-Cu it incremented with the increase of the contained proportion of Cu in the catalyst. The total global speed by gram of catalyst was also increased with the introduction of Cu, but only to medium and high concentrations of propylene. The specific superficial activity was bigger for the sinterizated catalyst, for a given composition of the bimetallic catalyst, compared with that of the fresh catalyst (non-sinterizated). To explain, the catalytic behavior of the propylene oxidation, on the catalysts here studied, it is postulated that the propylene molecule it absorb with less force on the faces than in the corners or borders of the crystals of the catalyst and that the connection of adsorption on a place of given Pt is affected by the atoms of neighboring Cu on the surface causing changes in the mobility of the absorbed species. The kinetic results reveal a complex dependence between the reaction speed and the concentration of the propylene. In low concentrations of propylene the reaction speed was increased until to reach a maximum, and then to continue with a marked decreasing; and to concentrations. In bigger propylene concentrations, the reaction kinetics is presented as zero order with regard to the propylene, for some given concentrations of oxygen

  14. Synthesis and Biological Evaluation of Ru(II) and Pt(II) Complexes Bearing Carboxyl Groups as Potential Anticancer Targeted Drugs.

    Science.gov (United States)

    Martínez, Ma Ángeles; Carranza, M Pilar; Massaguer, Anna; Santos, Lucia; Organero, Juan A; Aliende, Cristina; de Llorens, Rafael; Ng-Choi, Iteng; Feliu, Lidia; Planas, Marta; Rodríguez, Ana M; Manzano, Blanca R; Espino, Gustavo; Jalón, Félix A

    2017-11-20

    The synthesis and characterization of Pt(II) (1 and 2) and Ru(II) arene (3 and 4) or polypyridine (5 and 6) complexes is described. With the aim of having a functional group to form bioconjugates, one uncoordinated carboxyl group has been introduced in all complexes. Some of the complexes were selected for their potential in photodynamic therapy (PDT). The molecular structures of complexes 2 and 5, as well as that of the sodium salt of the 4'-(4-carboxyphenyl)-2,2':6',2″-terpyridine ligand (cptpy), were determined by X-ray diffraction. Different techniques were used to evaluate the binding capacity to model DNA molecules, and MTT cytotoxicity assays were performed against four cell lines. Compounds 3, 4, and 5 showed little tendency to bind to DNA and exhibited poor biological activity. Compound 2 behaves as bonded to DNA probably through a covalent interaction, although its cytotoxicity was very low. Compound 1 and possibly 6, both of which contain a cptpy ligand, were able to intercalate with DNA, but toxicity was not observed for 6. However, compound 1 was active in all cell lines tested. Clonogenic assays and apoptosis induction studies were also performed on the PC-3 line for 1. The photodynamic behavior for complexes 1, 5, and 6 indicated that their nuclease activity was enhanced after irradiation at λ = 447 nm. The cell viability was significantly reduced only in the case of 5. The different behavior in the absence or presence of light makes complex 5 a potential prodrug of interest in PDT. Molecular docking studies followed by molecular dynamics simulations for 1 and the counterpart without the carboxyl group confirmed the experimental data that pointed to an intercalation mechanism. The cytotoxicity of 1 and the potential of 5 in PDT make them good candidates for subsequent conjugation, through the carboxyl group, to "selected peptides" which could facilitate the selective vectorization of the complex toward receptors that are overexpressed in

  15. BSA-stabilized Pt nanozyme for peroxidase mimetics and its application on colorimetric detection of mercury(II) ions.

    Science.gov (United States)

    Li, Wei; Chen, Bin; Zhang, Haixiang; Sun, Yanhua; Wang, Jun; Zhang, Jinli; Fu, Yan

    2015-04-15

    Bovine serum albumin (BSA) is chosen as the nucleation templates to synthesize Pt-based peroxidase nanomimetics with the average diameter of 2.0nm. The efficient Pt nanozymes consist of 57% Pt(0) and 43% Pt(2+), which possess highly peroxidase-like activity with the Km values of 0.119mM and 41.8mM toward 3,3',5,5'-tetramethylbenzidine (TMB) and hydrogen peroxide (H2O2), respectively. Interestingly, Hg(2+) is able to down-regulate the enzymatic activity of Pt nanoparticles, mainly through the interactions between Hg(2+) and Pt(0). It is the first report to explore a colorimetric Hg(2+) sensing system on the basis of peroxidase mimicking activities of Pt nanoparticles. One of our most intriguing results is that BSA-stabilized Pt nanozymes demonstrate the ability to sense Hg(2+) ions in aqueous solution without significant interference from other metal ions. The Hg(2+) detection limit of 7.2nM is achieved with a linear response range of 0-120nM, and the developed sensing system is potentially applicable for quantitative determination of Hg(2+) in drinking water. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Study of Low $p_{T}$ $D^{0}$ Meson Production at CDF II in $p\\bar{p}$ Collisions at $\\sqrt{s}$ = 900 GeV

    Energy Technology Data Exchange (ETDEWEB)

    Gramellini, Elena [Univ. of Bologna (Italy)

    2012-01-01

    In this thesis a study of the D0 meson production in proton-antiproton collisions is presented. The data were collected with the CDF II detector at the Tevatron Collider of the Fermi National Accelerator Laboratory. This work is part of a specific effort by the CDF Collaboration to measure the inclusive differential cross section of prompt charmed mesons in the low pT kinematic region.

  17. Radioactivity of foodstuffs in Finland in 1987-1988

    International Nuclear Information System (INIS)

    Rantavaara, A.

    1991-06-01

    Radiocesium and radiostrontium in foodstuffs of agricultural origin were surveyed in Finland in 1987 - 1988. The nationwide survey was a continuation to an earlier foodstuff monitoring programme, which was extended both areally and by the types of foodstuffs after the Chernobyl accident in 1986. The purpose of the programme was to give information for dose assessment and on temporal changes and regional differences in the contents of fallout radionuclides in foodstuffs

  18. Determination of toxic elements in Malaysian foodstuffs

    International Nuclear Information System (INIS)

    Hamzah, Z.; Wood, A.K.H.; Mahmood, C.S.; Hamzah, S.

    1988-01-01

    This project is concentrating on the analysis of toxic elements content in seafoods including fishes, mussel, squid and prawn. Samples were collected from various places throughout Malay Peninsular. Samples were prepared according to RCA research protocol - nuclear techniques for toxic element in foodstuffs. Techniques used for elemental analysis were neutron activation analysis (instrumental and radiochemical) and anodic stripping voltametry. (author). 9 refs, 9 tabs

  19. Dynamic Heat Transfer Model of Refrigerated Foodstuff

    DEFF Research Database (Denmark)

    Cai, Junping; Risum, Jørgen; Thybo, Claus

    2006-01-01

    happens to the food inside during this period, when we look at the quality factor? This paper discusses quality model of foodstuff, different scenarios of defrost scheme are simulated, questions such as how the defrost temperature and duration influence the food temperature, thus the food quality, as well...

  20. Statutory control of the irradiation of foodstuffs

    International Nuclear Information System (INIS)

    Stevens, G.J.H.

    1989-01-01

    The statutory control of foodstuffs in South Africa is discussed. Regulations and statutes controlling the irradiation of food in South Africa are quoted. These include the regulations concerning the food irradiation facilities; the packaging and labelling of irradiated products, and the marketing and sale of these products

  1. A synthetic study and characterization of the Pt(II) complexes with bipyridines back-born system.

    Science.gov (United States)

    Jo, Woongkyu; Son, Seokhwan; Jo, Hyeongjun; Kim, Byeongcheol; Kwak, Cheehun; Jung, Sangchul; Lee, Jihoon; Ahn, Hogeun; Chung, Minchul

    2014-08-01

    The reaction of platinum [Pt(5,5-dmbpy)]Cl2 (5,5-dmbpy = 5,5'-dimethyl-2,2'-bipyridine) with 4,4'-dimethyl-2,2'-bipyridine (4,4-dmbpy), [Pt(dbbpy)]Cl2 (dbbpy = 4,4'-dibutyl-2,2'-bipyridine), [Pt(dpbpy)]Cl2 (dpbpy = 4,4'-dipentyl-2,2'-bipyridine) with 5,5'-dimethyl-2,2'-bipyridine (5,5-dmbpy) affords the following complexes: [(4,4-dmbpy)Pt(5,5-dmbpy)][PF6]2 (1) and [(dbbpy)Pt(5,5-dmbpy)][PF6]2 (2), [(dpbpy)Pt(5,5-dmbpy)][PF6]2 (3), [(5,5-dmbpy)Pt(5,5-dmbpy)][PF6]2 (4). This study was synthesized new platinum complex compounds utilizing ligand of 5,5'-Dimethyl-2,2'-dipyridyl System. To study the chemical composition was used 1H(13C)-NMR, UV-vis, Spectro photometer and Measurements about optical physics and chemical properties were measured to use spectrofluorometer. UV-vis absorption area was measured 310 nm to 383 nm and luminous wavelength was measured 390 nm to 419 nm.

  2. Selenium contents of Japanese foodstuffs by neutron activation analysis

    International Nuclear Information System (INIS)

    Noda, Katsuhiko; Hirai, Shoji; Danbara, Hiroshi.

    1980-01-01

    Selenium (Se) contents of Japanese foodstuffs were measured by neutron activation analyses with the TRIGA-II reactor in Atomic Energy Research Laboratory, Musashi Institute of Technology. Freezedried samples (200 - 500 mg) were irradiated in the pneumatic tube (thermal neutron flux, 1 x 10 12 n.cm -2 . sec -1 ) for 10 sec, and sup(77m)Se produced was counted for 30 sec in a gamma -ray spectrometer system equipped with a Ge(Li) detector. Samples containing less than 0.05 ppm Se and the processed foods of high salt contents were analyzed with radioactivities of 75 Se after irradiation in the central symble (thermal neutron flux, 4 x 10 12 n.cm -2 .sec -1 ) for 5 hours, digestion in the HNO 3 -HClO 4 mixture, and then purification by a precipitation process. Foodstuffs of animal origins contained more Se than those of plant origins. Se contents were as follows in the descending order: fish, meats, cereals, vegetables, and fruit. Daily per capital intaked of Se was in the range of 100 - 200 mu g, as calculated for and as found by analysis of composite diets representing ordinary Japanese meals. (author)

  3. Synthesis and reactivity towards diiodine of palladium(II) and platinum(II) complexes with non-cyclic and cyclic ligands (C6H3{CH=NR1R2}2-2,6)-. End-on diiodine-platinum(II) bonding in macrocyclic [PtI(C6H3{CH2NMe(CH2)7MeNCH2}-2,6)(h1-I2)

    NARCIS (Netherlands)

    Koten, G. van; Beek, J.A.M. van; Dekker, G.P.C.M.; Wissing, E.; Zoutberg, M.C.; Stam, C.H.

    1990-01-01

    Several new organo-platinum(II) and -palladium(II) complexes [MX(C{6}H{3}{CH{2}NR}1{R}2{}{2}-2, 6)] (X = halide, M = Pt, Pd; R}1{ = R}2{ = Et; R}2{ = Me, R}1{ = }t{Bu, M = Pt: R}2{ = Me, R}1{ = Ph) have been synthesized from [PtCl{2}(SEt{2}){2}] or [PdCl{2}(COD)] (COD = 1, 5-cyclooctadiene) by

  4. [Influence of Luxury Foodstuffs on Glaucoma].

    Science.gov (United States)

    Huber-van der Velden, K K

    2017-02-01

    The term "luxury foodstuffs" refers to foods which are not consumed because of their nutritional value. Classic modern luxury foodstuffs are alcohol, caffeine-containing drinks, cocoa, sugar and tobacco. The following review article examines some of these modern luxury foodstuffs in detail, as well as their influence on glaucoma. Thus, small quantities of alcohol lower high intraocular pressure and have a positive influence on the blood circulation of the optic nerve. In addition, red wine polyphenols exert vasoprotective effects. In general, however, alcohol consumption appears to have no significant effect on the prevalence of glaucoma. The most important source of caffeine intake is coffee consumption. In some studies, coffee consumption caused no changes in intraocular pressure, while others reported a rise. A large study showed a connection between heavy coffee consumption and the risk of pseudoexfoliation glaucoma. Green and black teas are rich sources of flavonoids with antioxidant activity. In addition, a slight trend for lowering the intraocular pressure has been measured. As regards chocolate, flavonoid-rich dark chocolate should be favoured, due to its antioxidant activity. It lowers blood pressure and improves endothelium-dependent vascular relaxation. Excessive sugar consumption over many years can lead to increased body mass index (BMI) and type 2 diabetes. Many studies show a positive relationship between BMI and intraocular pressure. Some studies have identified significant correlations between type 2 diabetes and the risk of glaucoma. Smoking is a very widespread stimulant; it narrows the blood vessels and thus reduces the blood circulation of the optic nerve. Otherwise, studies on the role of smoking as a risk factor for glaucoma have been very inconsistent. Luxury foodstuffs may effect glaucoma and should be included in the medical history. Georg Thieme Verlag KG Stuttgart · New York.

  5. Effects of radiation treatment on foodstuffs

    International Nuclear Information System (INIS)

    Dehne, L.; Boegl, W.

    1980-01-01

    The purpose of this study is to discuss and compile methods and results of irradiation experiments carried out on 54 plant and animal foodstuffs in order to obtain a survey on chemical changes, in particular as regards the reduction of nutritional value and savoriness of irradiated foodstuffs. According to this task, microbiological aspects as well as an interpretation of the experimental results as to the physiology of nutrition and toxicology were not included. The results published by the authors of the original papers were compiled in a kind of dictionary which contains all relevant information such as radiation sources, irradiation conditions, investigation methods, results of chemical or organoleptical changes etc. The most important results were summarized in tables and can be found at the end of this study. Because of the abundance of existing literature the series 'Effects of radiation treatment on foodstuffs' will be continued in Part IV, and the final discussion of the results will be published separately after further data have been included. (orig.) [de

  6. Radiological Risk Assessment and Survey of Radioactive Contamination for Foodstuffs

    International Nuclear Information System (INIS)

    Lee, W.R.; Lee, C.W.; Choi, K.S.

    2007-11-01

    After the Chernobyl nuclear accident in 1986, a radiological dose assessment and a survey of a radioactive contamination for foodstuffs have been investigated by many countries such as EU, Japan, USA. In the case of Japan which is similar to our country for the imported regions of foodstuffs, there were some instances of the excess for regulation on the maximum permitted levels of radioactive contamination among some imported foodstuffs. Concerns about the radioactive contamination of foodstuffs are increased because of the recently special situation (Nuclear test of North Korea). The purpose of this study is a radiological dose assessment and a survey of a radioactive contamination for foodstuffs in order to reduce the probability of intake of contaminated foodstuffs. Analytical results of the collected samples are below MDA. In this project, the model of radiological dose assessment via the food chain was also developed and radiological dose assessment was conducted based on surveys results of a radioactive contamination for foodstuffs in the Korean open markets since 2002. The results of radiological dose assessment are far below international reference level. It shows that public radiation exposure via food chain is well controlled within the international guide level. However, the radioactive contamination research of imported foodstuffs should be continuous considering the special situation(nuclear test of North Korea). These results are used to manage the radioactive contamination of the imported foodstuffs and also amend the regulation on the maximum permitted levels of radioactive contamination of foodstuffs

  7. Results of Research about Consciousness of Foodstuff Consumers in Hungary

    Directory of Open Access Journals (Sweden)

    Ibolya Bravacz

    2013-10-01

    How self-restrictive and self-conscious are we when purchasing and consuming foodstuff? – with every foodstuff purchase we make decisions about our environment, which indirectly has an effect on the producers, manufacturers and dealers. I will briefly review the foodstuff consumers segments in Hungary, which first have been identified using factor analysis followed by cluster analysis. I have identified the following consumer groups based on health consciousness: Conscious majority, Conscious by commitment, Economist “housewife”, Youthfully eclectic and Passives.

  8. 1,2,4-Triazines in the Synthesis of Bipyridine Bisphenolate ONNO Ligands and Their Highly Luminescent Tetradentate Pt(II) Complexes for Solution-Processable OLEDs.

    Science.gov (United States)

    Pander, Piotr; Bulmer, Rachel; Martinscroft, Ross; Thompson, Stuart; Lewis, Frank W; Penfold, Thomas J; Dias, Fernando B; Kozhevnikov, Valery N

    2018-04-02

    This article describes a convenient method for the synthesis of ONNO-type tetradentate 6,6'-bis(2-phenoxy)-2,2'-bipyridine (bipyridine bisphenolate, BpyBph) ligands and their platinum(II) complexes. The methodology includes the synthesis of 1,2,4-triazine precursors followed by their transformation to functionalized pyridines by the Boger reaction. Two complementary routes employing 3,3'- and 5,5'-bis-triazines allow a modification of the central pyridine rings in different positions, which was exemplified by the introduction of cyclopentene rings. The new ligands were used to prepare highly luminescent ONNO-type Pt(II) complexes. The position of the cyclopentene rings significantly influences the solubility and photophysical properties of these complexes. Derivatives with closely positioned cyclopentene rings are soluble in organic solvents and proved to be the best candidate for solution-processable organic light-emitting devices (OLEDs), showing efficient single-dopant candlelight electroluminescence.

  9. Pincer-CNC mononuclear, dinuclear and heterodinuclear Au(III) and Pt(II) complexes supported by mono- and poly-N-heterocyclic carbenes: synthesis and photophysical properties.

    Science.gov (United States)

    Gonell, S; Poyatos, M; Peris, E

    2016-04-07

    A family of cyclometallated Au(iii) and Pt(ii) complexes containing a CNC-pincer ligand (CNC = 2,6-diphenylpyridine) supported by pyrene-based mono- or bis-NHC ligands have been synthesized and characterized, together with the preparation of a Pt-Au hetero-dimetallic complex based on a Y-shaped tris-NHC ligand. The photophysical properties of all the new species and of two related Ru(ii)-arene complexes were studied and compared. Whereas the pyrene-based complexes only exhibit emission in solution, those containing the Y-shaped tris-NHC ligand are only luminescent when dispersed in poly(methyl methacrylate) (PMMA). In particular, the pyrene-based complexes were found to be emissive in the range of 373-440 nm, with quantum yields ranging from 3.1 to 6.3%, and their emission spectra were found to be almost superimposable, pointing to the fluorescent pyrene-centered nature of the emission. This observation suggests that the emission properties of the pyrene fragment may be combined with some of the numerous applications of NHCs as supporting ligands allowing, for instance, the design of biological luminescent agents.

  10. FAST-PT II: an algorithm to calculate convolution integrals of general tensor quantities in cosmological perturbation theory

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Xiao; Blazek, Jonathan A.; McEwen, Joseph E.; Hirata, Christopher M., E-mail: fang.307@osu.edu, E-mail: blazek@berkeley.edu, E-mail: mcewen.24@osu.edu, E-mail: hirata.10@osu.edu [Center for Cosmology and AstroParticle Physics, Department of Physics, The Ohio State University, 191 W Woodruff Ave, Columbus OH 43210 (United States)

    2017-02-01

    Cosmological perturbation theory is a powerful tool to predict the statistics of large-scale structure in the weakly non-linear regime, but even at 1-loop order it results in computationally expensive mode-coupling integrals. Here we present a fast algorithm for computing 1-loop power spectra of quantities that depend on the observer's orientation, thereby generalizing the FAST-PT framework (McEwen et al., 2016) that was originally developed for scalars such as the matter density. This algorithm works for an arbitrary input power spectrum and substantially reduces the time required for numerical evaluation. We apply the algorithm to four examples: intrinsic alignments of galaxies in the tidal torque model; the Ostriker-Vishniac effect; the secondary CMB polarization due to baryon flows; and the 1-loop matter power spectrum in redshift space. Code implementing this algorithm and these applications is publicly available at https://github.com/JoeMcEwen/FAST-PT.

  11. Synthesis, crystal structure and computational chemistry research of a Zinc(II complex: [Zn(Pt(Biim2

    Directory of Open Access Journals (Sweden)

    Teng Fei

    2012-01-01

    Full Text Available The title metal-organic coordination complex [Zn(pt(Biim2] (pt=phthalic acid, benzene-1,2-dicarboxylate, Biim=2,2'-biimidazole 1 has been obtained by using hydrothermal synthesis and characterized by single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P21/n with a = 8.5466(15 Å, b = 11.760(2 Å, c = 20.829(4 Å, β = 95.56(2º, V = 2083.5(6 Å3, Mr =497.78, Dc = 1.587 g/cm3, μ(MoKα = 1.226 mm−1, F(000 = 1016, Z = 4, the final R = 0.0564 and wR = 0.1851 for 3656 observed reflections (I > 2σ(I. The elemental analysis, IR, TG and the theoretical calculation were also investigated.

  12. Tetraammineplatinum(II) aquapentachloroiridate(III) dihydrate, [Pt(NH3)4][IrCl5(H2O)

    International Nuclear Information System (INIS)

    Garnier, E.; Bele, M.

    1994-01-01

    The crystal is built up from planar Pt(NH 3 ) 4 2+ cations, octahedral IrCl 5 (H 2 O) 2- anions and two H 2 O molecules. The coordination of these ions is 6/6, thus leading to a NaCl crystal structure. Electrostatic interactions and N..Cl, N..O and N..N short contacts (possible hydrogen bonds) take part in the packing of the structure and form a three-dimensional network. (orig.)

  13. ESR identification of irradiated foodstuffs: LARQUA research

    International Nuclear Information System (INIS)

    Raffi, J.

    1996-01-01

    As electron spin resonance (ESR) spectroscopy is the leading method for identification of irradiated foodstuffs, meat and fish bones, fruit and relative products (of vegetable origin), sea-food etc. were studied. In order to prepare a large co-trial on ESR identification of irradiation of irradiated foodstuffs, experiments were carried out at LARQUA, especially on fruits and vegetables. The radicals induced in the fruit pulp are not stable because the water content of fruit is generally high, but ESR can be used with dried fruit or dry components such as achenes, pips or stones. Different responses are observed, depending on the fruit. In ''sugatype'' fruits (papaya, dried grapes), an ESR multicomponent signal is radio-induced, but the non-irradiated fruit presents no ESR signal or a single-line, while in ''cellulose type'' fruits (pistachio nut, berries), a triplet is induced. But a six line signal due to Mn 2+ and a central single line may also be present both in irradiated and non-irradiated samples. In the case of aromatic herbs, the proposed official CEN protocol for irradiated food containing cellulose was used. (author)

  14. ESR identification of irradiated foodstuffs: LARQUA research

    Energy Technology Data Exchange (ETDEWEB)

    Raffi, J [Laboratoire de Recherche sur la Qualite des Aliments, Marseille (France)

    1997-12-31

    As electron spin resonance (ESR) spectroscopy is the leading method for identification of irradiated foodstuffs, meat and fish bones, fruit and relative products (of vegetable origin), sea-food etc. were studied. In order to prepare a large co-trial on ESR identification of irradiation of irradiated foodstuffs, experiments were carried out at LARQUA, especially on fruits and vegetables. The radicals induced in the fruit pulp are not stable because the water content of fruit is generally high, but ESR can be used with dried fruit or dry components such as achenes, pips or stones. Different responses are observed, depending on the fruit. In ``sugatype`` fruits (papaya, dried grapes), an ESR multicomponent signal is radio-induced, but the non-irradiated fruit presents no ESR signal or a single-line, while in ``cellulose type`` fruits (pistachio nut, berries), a triplet is induced. But a six line signal due to Mn{sup 2+} and a central single line may also be present both in irradiated and non-irradiated samples. In the case of aromatic herbs, the proposed official CEN protocol for irradiated food containing cellulose was used. (author).

  15. Thermoluminescent and impedimetric studies on irradiated foodstuffs

    International Nuclear Information System (INIS)

    Mamoon, A.M.

    2000-01-01

    Several brands of different spices and milk powders were irradiated with relatively high doses of gamma radiation. Glow curves were produced upon heating these irradiated foodstuffs only. Study of the obtained spices glow curves revealed that the magnitude of these curves depends upon the dose received while the shape of the curves remains generally the same for the different doses and for the different spices. Previous studies had shown that the obtained thermoluminescence (TL) is due to dust particles carried by the spices. The TL studies show, furthermore, that different brands of the same spice are apparently contaminated with different amounts of dust or soil. The obtained TL from irradiated milk powders is apparently due to its mineral content. Different milk powders gave TL curves of different magnitudes for the same dose depending upon the milk brand. Impedimetric studies carried out irradiated potatoes show changes in impedance amplitude and phase angle. The results support earlier work on the use of TL to differentiate between irradiated and control foodstuffs, to assess the extent of spices contamination with soil-which perhaps reflects hygienic care-and that impedimetric measurements can distinguish irradiated from control potatoes

  16. Analyzing Control Challenges for Thermal Energy Storage in Foodstuffs

    DEFF Research Database (Denmark)

    Hovgaard, Tobias Gybel; Larsen, Lars F. S.; Skovrup, Morten Juel

    2012-01-01

    foodstuffs make them behave differently when exposed to changes in air temperature. We present a novel analysis based on Biot and Fourier numbers for the different foodstuffs. This provides a valuable tool for determining how different items can be utilized in load-shifting schemes on different timescales...

  17. Levels of dioxin-like compounds in Taiwan foodstuffs

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, M.S.; Wang, S.M.; Chou, U.; Chen, S.Y.; Huang, N.C.; Liao, G.Y.; Yu, T.P.; Ling, Y.C. [National Tsing Hua Univ., Hsinchu (Taiwan)

    2004-09-15

    Food is the major route of human intake of toxic dioxin-like compounds (DLCs), which include PolyChlorinated Dibenzo-p-Dioxins (PCDDs), PolyChlorinated DibenzoFurans (PCDFs), and WHO PolyChlorinated Biphenyls (PCBs). Approximately 95% of human DLCs exposure derives from food, with nearly 80% coming from food of animal origin. The DLCs levels in foodstuffs and the consumption rate of foodstuffs are essential to evaluate health risk posing to humans. The lack of DLCs levels in foodstuffs increases the population risk to DLCs exposure. The Department of Health, Taiwan has entrusted us to conduct a comprehensive monitoring program on PCDD/Fs levels in Taiwan foodstuffs in 2001 and 2002. In 2003, the program has extended the analytes to include 12 WHO-PCBs. The DLCs levels in Taiwan foodstuffs is, therefore, being surveyed for the first time.

  18. Structure/activity of Pt{sup II}/N,N-disubstituted-N'-acylthiourea complexes: Anti-tumor and anti-mycobacterium tuberculosis activities

    Energy Technology Data Exchange (ETDEWEB)

    Plutín, Ana M.; Alvarez, Anislay; Mocelo, Raúl; Ramos, Raúl; Sánchez, Osmar C. [Laboratorio de Síntesis Orgánica, Facultad de Química, Universidad de La Habana (Cuba); Castellano, Euardo E. [Universidade de São Paulo (USP), São Carlos, SP (Brazil); Silva, Monize M. da; Villarreal, Wilmer; Colina-Vegas, Legna; Batista, Alzir A. [Universidade Federal de São Carlos (UFSCar), SP (Brazil); Pavan, Fernando R., E-mail: anap@fq.uh.cu, E-mail: daab@ufscar.br [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Araraquara, SP (Brazil). Faculdade de Ciências Farmacêuticas

    2018-05-01

    The syntheses, characterization, cytotoxicity against tumor cells and anti-Mycobacterium tuberculosis activity assays of Pt{sup II}/PPh{sub 3}/N,N-disubstituted-N'-acylthioureas complexes with general formulae [Pt(PPh{sub 3}){sub 2}(L)]PF{sub 6}, PPh{sub 3} = triphenylphosphine; L = N,N-disubstituted-N'-acylthiourea, are here reported. The complexes were characterized by elemental analysis, molar conductivity, infrared (IR), nuclear magnetic resonance (NMR) ({sup 1} H, {sup 13}C{1 H} and {sup 31}P{"1 H}) spectroscopy. The {sup 31}P{"1 H} NMR data are consistent with the presence of two PPh{sup 3} ligands cis to each other position, and one N,N-disubstituted-N'-acylthiourea coordinated to the metal through O and S, in a chelate form. The structures of the complexes were determined by X-ray crystallography, forming distorted square-planar structures. The complexes were tested in human cell lines carcinomas and also screened with respect to their anti-Mycobacterium tuberculosis activity (H37RvATCC 27294). It was found that complexes with N,N-disubstituted-N'-acylthiourea containing open and small chains as R2 groups show higher cytotoxic and higher anti-Mycobacterium tuberculosis activity than those containing rings in this position. (author)

  19. Management of foodstuffs after nuclear accidents

    International Nuclear Information System (INIS)

    1991-01-01

    A model for the management of foodstuffs after nuclear accidents is presented. The model is a synthesis of traditions and principles taken from both radioactive protection and management of food. It is based on cooperation between the Nordic countries and on practical experience gained from the Chernobyl accident. The aim of the model is to produce a basis for common plans for critical situations based on criteria for decision making. In the case of radioactive accidents it is important that the protection of the public and of the society is handled in a positive way. The model concerns production, marketing and consumption of food and beverage. The overall aim is that the radiation doses should be as low and harmless to health for individual members of the public. (CLS) 35 refs

  20. Pt(II) and Pd(II) complexes with ibuprofen hydrazide: Characterization, theoretical calculations, antibacterial and antitumor assays and studies of interaction with CT-DNA

    Science.gov (United States)

    Manzano, Carlos M.; Bergamini, Fernando R. G.; Lustri, Wilton R.; Ruiz, Ana Lúcia T. G.; de Oliveira, Ellen C. S.; Ribeiro, Marcos A.; Formiga, André L. B.; Corbi, Pedro P.

    2018-02-01

    Palladium(II) and platinum(II) complexes with a hydrazide derivative of ibuprofen (named HIB) were synthesized and characterized by chemical and spectroscopic methods. Elemental and thermogravimetric analyses, as well as ESI-QTOF-MS studies for both complexes, confirmed a 1:2:2 metal/HIB/Cl- molar ratio. The crystal structure of the palladium(II) complex was solved by single crystal X-ray diffractometric analysis, which permitted identifying the coordination formula [PdCl2(HIB)2]. Crystallographic studies also indicate coordination of HIB to the metal by the NH2 group. Nuclear magnetic resonance and infrared spectroscopies reinforced the coordination observed in the crystal structure and suggested that the platinum(II) complex presents similar coordination modes and structure when compared with the Pd(II) complex. The complexes had their structures optimized with the aid of DFT methods. In vitro antiproliferative assays showed that the [PdCl2(HIB)2] complex is active over ovarian cancer cell line OVCAR-03, while biophysical studies indicated its capacity to interact with CT-DNA. The complexes were inactive over Staphylococcus aureus, Escherichia coli and Pseudomonas aeruginosa bacterial strains.

  1. The interaction between radiation and complexes of cis-Pt(II) and Rh(II): studies at the molecular and cellular level

    International Nuclear Information System (INIS)

    Chibber, R.

    1985-01-01

    As a first step in gaining an understanding of the relative cellular effects of the transition metal/nitroimidazole complexes the authors have examined the effect of radiation given to cells in the presence of metal complexes not containing a nitroimidazole ligand. The compounds used in the cellular work are a series of Rh(II) carboxylates, cisplatin and JM8 (CBDCA, cis-diammine-1, 1-cyclobutane dicarboxylate platinum (II)). In radiation chemical experiments, Rh(II) acetate and cisplatin were chosen to represent model systems. Results from these radiation chemical and cellular experiments then allow interpretation of the changes in biological response caused by these agents, which are discussed in terms of the mechanism(s) thought to be operative in radiosensitization. (author)

  2. (DDT) and hexachlorohexane (HCH) pesticide residues in foodstuffs ...

    African Journals Online (AJOL)

    Dichloro-diphenyl-trichloro-ethane (DDT) and hexachlorohexane (HCH) pesticide residues in foodstuffs from markets in Ile-Ife, Nigeria. ... International Journal of Biological and Chemical Sciences ... Keywords: Dichlorodiphenyltrichloroethane, hexachlorocyclohexane, pesticide, residue, cowpea grain, yam chip.

  3. Study of criteria for foodstuffs control following a radiological emergency

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Young Min; Park, Sang Hyun; Jeong, Seung Young; Kim, Dong Il [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2015-04-15

    The foodstuff control standards on APPRE should be applied to emergency situation only, while the Korean Food Stands Codex standards of the Korea Food and Drug Administration (KFDA) should be applied in normal situation. To reflect the lessons learned form the Fukushima accident, the standards of foodstuff control has been studied by surveying newly recommended systems of radiological protection based on reference level commensurated with exposure situations and international trends. Existing standards for restriction on ingestion of foodstuff is based on simple cost-benefit approach and it is confirmed that the projected doses is contributed excessively on the specific food categories. In future, the standards will be revised considering domestic diet feature, nuclide analysis procedure, international standard and the latest recommendation of radiation protection. Also, modification of provisions and standards for foodstuff control of related departments are needed for well integrated national EPR framework.

  4. The Effects of Cisplatin and Its PT(II Analogue on Oxidative Stress of Isolated Rat Heart/ Efekti Cisplatine I PT(II Analoga Cisplatine Na Oksidacioni Stres Izolovanog Srca Pacova

    Directory of Open Access Journals (Sweden)

    Stojic Isidora

    2016-03-01

    Full Text Available To date, numerous platinum (II complexes have been successfully used in the treatment of different types of cancer. Therapeutic platinum complexes are different in terms of their structure, chemical reactivity, solubility, pharmacokinetics and toxicity. The aim of our research was the evaluation of cardiotoxicity of dichloro-(ethylendiamine platinum (II in a model of isolated rat heart using the Langedorff technique. Oxidative stress was assessed by determination of superoxide anion radical, hydrogen peroxide, Thiobarbituric Acid Reactive Substances and nitric oxide levels from coronary venous effluent. All reagents were perfused at increasing concentrations from 10-8 to 10-4 M for 30 minutes. In this paper, we report that substances administered at higher doses did not induce dose-dependent effects on oxidative stress markers. The results of this research may be of great interest for future studies in this area. There are many novel platinum compounds that had previously demonstrated antitumour activity, and these types of experiments in our study can assist in the examination of their cardiotoxicity. These results could be helpful for understanding dose-dependent side effects of existing and novel platinum compounds

  5. Monitoring of radioactivity in foodstuffs in Ireland 1987

    International Nuclear Information System (INIS)

    1988-12-01

    This report presents a compilation of the results of measurements made by the Board's laboratory during 1987, the year following the accident. When the level of Chernobyl deposition had been broadly established, the programme was concentrated on the foodstuffs of greatest interest and was supportive of the exportation of Irish foodstuffs. As well as testing food produce of Irish origin the Board also monitored food imports from abroad. Over 7500 samples were analysed and some 3000 certificates were issued for food exports

  6. Aluminium in foodstuffs and diets in Sweden.

    Science.gov (United States)

    Jorhem, L; Haegglund, G

    1992-01-01

    The levels of aluminium have been determined in a number of individual foodstuffs on the Swedish market and in 24 h duplicate diets collected by women living in the Stockholm area. The results show that the levels in most foods are very low and that the level in vegetables can vary by a factor 10. Beverages from aluminium cans were found to have aluminium levels not markedly different from those in glass bottles. Based on the results of the analysis of individual foods, the average Swedish daily diet was calculated to contain about 0.6 mg aluminium, whereas the mean content of the collected duplicate diets was 13 mg. A cake made from a mix containing aluminium phosphate in the baking soda was identified as the most important contributor of aluminium to the duplicate diets. Tea and aluminium utensils were estimated to increase the aluminium content of the diets by approximately 4 and 2 mg/day, respectively. The results also indicate that a considerable amount of aluminium must be introduced from other sources.

  7. Foodstuff monitoring. To protect the consumer

    International Nuclear Information System (INIS)

    2013-01-01

    A set of articles describes the activities of the IRSN in the field of foodstuff monitoring about nuclear plants, in order to assess the exposure of population by food. Simulation codes have been developed to model the deposit of radionuclides on grass and their transfer to cows and milk, but also to local vegetable productions. In case of accidental release, it would be possible to forbid the consumption of some products. The IRSN performs a continuous monitoring of the environment at the local, regional and national levels. For each of these levels, a sampling plan is defined in terms of sampling location and frequency. These controls are different according to the region. The radiological quality of water is monitored and several actors are involved in this process (regional and national agencies, producers and distributors, laboratories). The case of the region of Chinon is more particularly addressed. Local production and consumption habits are studied for a better assessment of their health impact. Some projects are finally evoked: inclusion of children in food-habit survey, investigations in different regions, analysis of bottled waters, widening of the area for the study of post-accidental consequences

  8. Transplacental passage of Pt after treatment with the new triamine complex cis-diaminechloro-[2-(diethylamino) ethyl 4-amino-benzoate, N{sup 4}]-chloride platinum (II) monohydrochloride monohydrate

    Energy Technology Data Exchange (ETDEWEB)

    Ognio, Emanuela; Lapide, Maddalena [Servizio Modelli Animali, Istituto Nazionale per la Ricerca sul Cancro, Genova (Italy); Chiavarina, Barbara; Viale, Maurizio [U.O. Farmacologia e Neuroscienze, Lab. Farmacologia Tossicologica, Istituto Nazionale per la Ricerca sul Cancro, Lgo R. Benzi, 10, Genova (Italy); Caviglioli, Gabriele [Universita di Genova, Dipartimento di Chimica e Tecnologie Farmaceutiche e Alimentari, Genova (Italy)

    2004-10-01

    Cis-diaminechloro-[2-(diethylamino) ethyl 4-amino-benzoate, N{sup 4}]-chloride platinum (II) monohydrochloride monohydrate (DPR) is a monofunctional Pt triamine complex synthesized starting from cisplatin and procaine hydrochloride, characterized by a good antitumor activity coupled with low toxic effects and able to impair prenatal development of mice but at doses outside or just in the upper range of therapeutic doses. In the present paper the transplacental passage of DPR-derived Pt was investigated in CD1 mice on days 9, 13, 16 and 18 of pregnancy, 24 h after ip administration of 21 mg/kg DPR. For comparison, groups of mice were treated with an equivalent Pt-containing dose of cisplatin (10.7 mg/kg). Similarly to cisplatin, small amounts of Pt were detected in fetuses on day 9. From day 13 of gestation the concentration of DPR- and cisplatin-derived Pt increased up to the highest fetal concentrations detected on day 16. On day 18 the concentration of Pt decreased. Most importantly, on days 13-18 of pregnancy cisplatin-derived Pt was always significantly higher than that assayed after DPR administration. In addition, on day 13 of pregnancy Pt exposure of fetuses was significantly higher when dams were treated with cisplatin (AUC{sub 0.5-24}= 3.40 vs. 4.95 {mu}g.h/g). Finally, it is worth noting that serum decay of Pt after DPR or cisplatin administration in adult female mice was similar with AUC{sub 0.13-2h} s of 7.5 and 6.6 {mu}g.h/ml, respectively. When we determined the concentration of Pt into the main organs of fetuses from dams treated with either DPR or cisplatin on day 18 of gestation, we observed a different organ distribution. In fact, while the concentration of DPR-derived Pt was greater in the heart (1.08{+-}0.30 vs. 0.78{+-}0.35 {mu}g/g, p<0.10), an opposite situation was found in the kidney (0.51{+-}0.20 vs. 0.69{+-}0.22 {mu}g/g, p<0.05). In conclusion, our data show that DPR may pass through the placenta with an efficiency significantly lower than

  9. The average concentrations of 226Ra and 210Pb in foodstuff cultivated in the Pocos de Caldas plateau

    International Nuclear Information System (INIS)

    Hollanda Vasconcellos, L.M. de.

    1984-01-01

    The average concentrations of 226 Ra and 210 Pb in vegetables cultivated in the Pocos de Caldas plateau, mainly potatoes, carrots, beans and corn and the estimation of the average transfer factors soil-foodstuff for both radionuclides, were performed. The total 226 Ra and 210 Pb content in the soil was determined by gamma spectrometry. The exchangeable fraction was obtained by the classical radon emanation procedure and the 210 Pb was isolated by a radiochemical procedure and determined by radiometry of its daughter 210 Bi beta emissions with a Geiger Muller Counter. (M.A.C.) [pt

  10. Reaction between ethylenediamine and acetone on a platinum(II) complex. Crystal structure of [PtCl(en)(PBu3)][PtCl(ien)(PBu3)]Cl2 x CH3COCH3

    International Nuclear Information System (INIS)

    Kozelka, J.; Bois, C.

    1988-01-01

    The synthesis of [PtCl(en)(PBu 3 )][PtCl(ien)(PBu 3 )]Cl 2 CH 3 COCH 3 (en = ethylenediamine and ien = N-iso-propylideneethylenediamine) is reported herein. The crystal structure of the compound determined by x-ray absorption analysis and 1 H and 31 P NMR spectral data of the compound are reported. 11 references, 2 figures, 3 tables

  11. Determination of toxic and essential element concentrations in foodstuffs from local market

    International Nuclear Information System (INIS)

    Surtipanti; Suwirma; Yumiarti; June, M.; Syaifudin, S.

    1989-01-01

    Determination of toxic and essential elements concentrations in foodstuffs from local market in Jakarta. Concentration of toxic essential elements, such as, As, Hg, Cr, Pb, Cu, and Zn, in rice, corn bean, small green peas, wheat, vegetables, fruits, tea and coffee, have been determined. As, Hg, Sb, Cr, Se, and Zn, were determined using neutron activation analysis, after being irradiated at TRIGA-MARK II reactor, while Pb and Cu were determined using atomic absorption spectrophotometer. The results obtained were lower than the maximum permissible concentration allowed. (author). 8 refs

  12. Highly red-shifted NIR emission from a novel anthracene conjugated polymer backbone containing Pt( ii ) porphyrins

    KAUST Repository

    Freeman, D. M. E.

    2015-11-30

    © The Royal Society of Chemistry 2016. We present the synthesis of a novel diphenylanthracene (DPA) based semiconducting polymer. The polymer is solubilised by alkoxy groups attached directly to a DPA monomer, meaning the choice of co-monomer is not limited to exclusively highly solubilising moieties. Interestingly, the polymer shows a red-shifted elecroluminescence maximum (510 nm) when compared to its photoluminescence maximum (450 nm) which we attribute to excimer formation. The novel polymer was utilised as a host for a covalently-linked platinum(ii) complexed porphyrin dopant. Emission from these polymers was observed in the NIR and again showed almost a 100 nm red shift from photoluminescence to electroluminescence. This work demonstrates that utilising highly aggregating host materials is an effective tool for inducing red-shifted emission in OLEDs.

  13. Measurement of the W Boson Mass with the D0 Run II Detector using the Electron P(T) Spectrum

    Energy Technology Data Exchange (ETDEWEB)

    Andeen, Jr., Timothy R. [Northwestern Univ., Evanston, IL (United States)

    2008-06-01

    This thesis is a description of the measurement of the W boson mass using the D0 Run II detector with 770 pb-1 of p$\\bar{p}$ collision data. These collisions were produced by the Tevatron at √s = 1.96 TeV between 2002 and 2006. We use a sample of W → ev and Z → ee decays to determine the W boson mass with the transverse momentum distribution of the electron and the transverse mass distribution of the boson. We measure MW = 80340 ± 37 (stat.) ± 26 (sys. theo.) ± 51 (sys. exp.) MeV = 80340 ± 68 MeV with the transverse momentum distribution of the electron and MW = 80361 ± 28 (stat.) ± 17 (sys. theo.) ± 51 (sys. exp.) MeV = 80361 ± 61 MeV with the transverse mass distribution.

  14. The interaction between Otto fuel II and aqueous hydroxylammonium perchlorate (HAP). Pt. 3: depletion of components within the reacting liquids

    Energy Technology Data Exchange (ETDEWEB)

    Bellerby, John M.; Blackman, Christopher S. [Department of Environmental and Ordnance Systems, Cranfield University, Defence College of Management and Technology, Shrivenham, Swindon SN6 8LA (United Kingdom)

    2007-06-15

    Gas chromatography (GC) with a Flame Ionisation Detector (FID) has been used to determine changes in the concentrations of the components of Otto Fuel II (OF) in contact with an 82% aqueous solution of hydroxylammonium perchlorate (HAP) in sealed vials at 31.7 C during the period leading up to auto-ignition of the two liquids. The concentration of hydroxylamine in HAP was monitored over the same period using a titration method. It was found that 2-nitrodiphenylamine (2NDPA), the stabiliser in the OF, is completely consumed after about 65-70 h and that the concentration of hydroxylamine begins to fall at this point. 1,2-Propanediol dinitrate (propylene glycol dinitrate, PGDN), the energetic component in the OF, is not depleted significantly until after about 90 h. The evolution of nitrous oxide (N{sub 2}O) between 65 and 90 h is attributed to the reaction of the hydroxylammonium ion with nitrous acids produced by PGDN decomposition at the liquid-liquid interface. Carbon dioxide (CO{sub 2}) is evolved after 90 h and is attributed to PGDN decomposition. HAP and PGDN are each thought to contribute to N{sub 2}O evolution after 90 h. (Abstract Copyright [2007], Wiley Periodicals, Inc.)

  15. Radioactive substances in foodstuffs and drinking water in Finland

    Energy Technology Data Exchange (ETDEWEB)

    Vaaramaa, K.; Vesterbacka, P.; Solatie, D. [STUK - Radiation and Nuclear Safety Authority (Finland)

    2014-07-01

    The concentrations of radioactive substances in the environment and foodstuffs are continuously monitored in Finland. Radiation and Nuclear Safety Authority (STUK) publishes the annual report of Surveillance of Environmental Radiation which shows the activity levels of artificial radionuclides in Finland. Based on the results the radiation dose to Finnish people is estimated. Natural radioactive elements will be included in the surveillance program in future years. The aim of the foodstuffs monitoring program is to obtain information from the intake of radionuclides through ingestion. The radioactivity in foodstuffs is monitored by collecting foodstuffs on market, drinking water and daily meals offered at hospitals over one week. The sampling sites are located in southern, central and northern Finland, representing the main population centres and areal differences in the consumption of foodstuffs. One of these sampling sites is located in the highest {sup 137}Cs deposition area in Finland originating from the Chernobyl accident. The foodstuff samples on market are, for example, wild game, wild berries, wild mushrooms and fish. {sup 137}Cs and {sup 90}Sr are analysed from mixed diet samples and {sup 137}Cs from foodstuffs samples on market. The concentrations of {sup 137}Cs and {sup 90}Sr in daily meals are low because the agricultural products used as raw material are almost free of artificial radionuclides. The small variation in the results is caused by the differences in the types of meals that were prepared on the sampling dates and in the areal origins of raw materials. {sup 137}Cs concentration is remarkably higher in such food which contains a lot of natural products like wild berries, freshwater fish, wild mushrooms and game. As an example, the concentrations of {sup 137}Cs in the solid food in 2012 ranged from 0.06 - 1.0 Bq/kg, and in the drinks from 0.27 - 0.40 Bq/l, respectively. The radiation dose to Finnish people is estimated based on an analysis of

  16. Effect of ozone on ruthenium species in alkaline medium. Pt. II. Oxidation of pentahydroxo nitrosyl ruthenate(II) ion RuNO(OH)52-

    International Nuclear Information System (INIS)

    Floquet, S.; Eysseric, C.

    2006-01-01

    Oxidation of the nitrosyl ruthenium complex RuNO(OH) 5 2- has been carried out in sodium hydroxide solutions in contact with a gas flow containing ozone. The RuNO(OH) 5 2- complex is converted successively into ruthenate and perruthenate ions. An empirical kinetic rate law for the first step has been determined and was shown to depend on concentrations of (i) the ruthenium complex, (ii) the hydroxide ions and (iii) ozone concentration in the gas flow. The second step of the reaction, corresponding to the perruthenate ion formation, shows a complex mechanism and four competing reactions have been proposed to represent it. The influences on the second step kinetics of several parameters such as ozone or hydroxide concentrations or the conditions of the gas-liquid exchange area are also qualitatively discussed. (orig.)

  17. Effect of ozone on ruthenium species in alkaline medium. Pt. II. Oxidation of pentahydroxo nitrosyl ruthenate(II) ion RuNO(OH){sub 5}{sup 2-}

    Energy Technology Data Exchange (ETDEWEB)

    Floquet, S. [Commissariat a l' Energie Atomique (CEA/Valrho), Bagnols-sur-Ceze (France); Inst. Lavoisier, IREM UMR 8637, Univ. de Versailles Saint-Quentin, Versailles (France); Eysseric, C. [Commissariat a l' Energie Atomique (CEA/Valrho), Bagnols-sur-Ceze (France)

    2006-07-01

    Oxidation of the nitrosyl ruthenium complex RuNO(OH){sub 5}{sup 2-} has been carried out in sodium hydroxide solutions in contact with a gas flow containing ozone. The RuNO(OH){sub 5}{sup 2-} complex is converted successively into ruthenate and perruthenate ions. An empirical kinetic rate law for the first step has been determined and was shown to depend on concentrations of (i) the ruthenium complex, (ii) the hydroxide ions and (iii) ozone concentration in the gas flow. The second step of the reaction, corresponding to the perruthenate ion formation, shows a complex mechanism and four competing reactions have been proposed to represent it. The influences on the second step kinetics of several parameters such as ozone or hydroxide concentrations or the conditions of the gas-liquid exchange area are also qualitatively discussed. (orig.)

  18. Monitoring of radioactivity in foodstuffs: experience gained and recommendations

    International Nuclear Information System (INIS)

    Mamoon, A.M.; Abdulfattah, A.F.; Abulfaraj, W.H.; Abdul-Majid, S.; Al-Johani, M.; Abubakar, K.M.

    1988-01-01

    The Chernobyl reactor accident released large amounts of radioactivity that was carried by winds across international boundaries. Soils and surface waters as well as vegetation and grazing animals in neighbouring countries to the Soviet Union were subject to radioactive contamination in various degrees. Saudi Arabia imports much of its foodstuffs from European countries and about 75% of the imported foodstuffs come through western ports of the country. Hence the Government of Saudi Arabia took appropriate measures to ensure safety of imported foodstuffs. King Abdulaziz University (KAU) was directed by the government at about mid-June 1986, to carry out radioactivity inspections of food items reaching Jeddah, Yanbu and Jizan seaports as well as food arrivals at King Abdulaziz International Airport at Jeddah. Parallel responsibilities were assigned to other universities and King Abdulaziz City for Science and Technology, for radioactivity inspections of imported foodstuffs reaching ports or inlets in their respective areas. In applying the measures and controls enacted by the government against importation of radioactively contaminated foodstuffs, much management experience was acquired and some of it is rather unique to Saudi Arabia

  19. Radioactive contamination of foodstuffs from Burgenland after Chernobyl

    International Nuclear Information System (INIS)

    Maringer, F.J.

    1987-01-01

    About 500 samples of foodstuffs, drinking water and grass from Burgenland (an eastern province of Austria) were measured by the author's institution in May to August 1986. Burgenland and generally the east of Austria had, with respect to the Chernobyl fallout, an advantage against other parts of Austria, due to low rainfall and favorable winds in the days after the Chernobyl accident. The activities were generally below the legal limits for drinking water and higher than these in few cases in foodstuffs and grass. The legal limits for activity concentrations in foodstuffs and drinking water for the elements iodine 131, cesium 134, cesium 137 and strontium 90 are listed in an appendix. 2 refs., 6 figs., 5 tabs

  20. Influence of civilization processes on natural foodstuff resources

    Energy Technology Data Exchange (ETDEWEB)

    Blattny, C

    1970-01-01

    An introduction to a symposium is presented. The goal of the symposium was to consider the qualitative damage to foodstuffs consumed by man which is caused by the polluting processes of industrial society. Also the symposium was to consider the unfavorable effects of pollution on the health of animals which serve as human food.

  1. OPTIMAL LOCALIZATION OF SPECIAL TRANSPORT AND LOGISTIC FOODSTUFF CENTRE

    Directory of Open Access Journals (Sweden)

    A. M. Pasichnyk

    2010-06-01

    Full Text Available On the basis of research of statistic indices of custom-house, the population and geographic location of cities of Donetsk region, the method of calculation of optimum placing of the specialized transport-logistical centre of foodstuff is offered.

  2. Regulations Relating to Foodstuffs for Infants and Young Children

    African Journals Online (AJOL)

    RV

    2010-11-22

    Nov 22, 2010 ... published regulations1 in terms of section 15(1) of the Foodstuffs, Cosmetics and. Disinfectants Act.2 .... and support of appropriate and timely complementary feeding (weaning) practices with the use of local ... aim of the Code is "to contribute to the provision of safe and adequate nutrition for infants, by the ...

  3. Stage II recovery behavior of a series of ion-irradiated platinum (gold) alloys as studied by field-ion microscopy. [0. 10, 0. 62, and 4. 0 at. percent Au and pure Pt

    Energy Technology Data Exchange (ETDEWEB)

    Wei, C.Y.; Seidman, D.N.

    1976-11-01

    Direct and visible evidence was obtained for long-range migration of self-interstitial atoms (SIAs) in Stage II of three different ion-irradiated platinum (gold) alloys. Field-ion microscope (FIM) specimens of Pt--0.10, 0.62 and 4.0 at. percent Au alloys were irradiated in-situ with 30-keV W/sup +/ or Pt/sup +/ ions at a tip temperature of 35 to 41 K at 2 x 10/sup -9/ torr. Direct observation of the surfaces of the FIM specimens during isochronal warming experiments to 100 K showed that a flux of SIAs crossed the surfaces of the specimens between 40 to 100 K. The spectrum for each alloy consisted of two recovery peaks (substages II/sub B/ and II/sub C/). The results are explained on the basis of an impurity-delayed diffusion mechanism employing a two-level trapping model. The application of this diffusion model to the isochronal recovery spectra yielded a dissociation enthalpy (DELTAh/sub li-Au//sup diss/) and an effective diffusion coefficient for each substage; for substage II/sub B/ DELTAh/sub li-Au//sup diss/ (II/sub B/) = 0.15 eV and for substage II/sub C/ DELTAh/sub li-Au//sup diss/ (II/sub C/) = 0.24 eV. A series of detailed control experiments was also performed to show that the imaging electric field had not caused the observed long-range migration of SIAs and that the observed effects were not the result of surface artifacts. 14 figures, 6 tables.

  4. Processing of foodstuffs as countermeasures following a nuclear accident

    International Nuclear Information System (INIS)

    Coulon, R.; Despres, A.; Diaz, A.; Soulatges, D.

    1989-01-01

    The processing of foodstuffs is one of the countermeasures which may be taken following a nuclear accident in order to reduce the contamination of the foodstuffs concerned. A consideration of the transfer of radioactivity during the processing or the preparation of food makes it possible to estimate the effectiveness of the countermeasure concerned, which is one essential criterion for its selection; the other is the cost of its application. In short, consideration must be given at the same time to both of these factors if a rational choice is to be made between the various potential options on an industrial scale. In addition to the countermeasures involving processing or culinary preparation of the foodstuffs concerned, they may also be destroyed, stored, used as feedingstuffs or decontaminated, and the crops may be buried, the feedingstuffs of animals changed, farmland frozen, etc. An expert system using the GOLDWORKS software should help to select the most appropriate countermeasure on the basis of its cost and effectiveness. Such a system would evaluate: - the effectiveness of each of the countermeasures likely to be selected (to be expressed in terms of dose); - the social cost of the dose avoided by their application; - the cost of the countermeasure itself. The last is estimated as thoroughly as possible by taking into account, inter alia, food processing, compensation to the producers, the costs of transport and storage or of destruction. This is followed by a proposed classification of the countermeasures according to their cost effectiveness. 17 radionuclides and 4 foodstuffs (milk, meat, green vegetables and cereals) are considered. Depending on the date of the accident concerned, the input data for themodel are produced from the concentrations measured in the foodstuffs or in the soil. In the latter case, dynamic transfer coefficients make it possible to evaluate the contamination of future harvests [fr

  5. The platinum (II) complex [Pt(O,O'-acac)(γ-acac)(DMS)] alters the intracellular calcium homeostasis in MCF-7 breast cancer cells.

    Science.gov (United States)

    Muscella, Antonella; Calabriso, Nadia; Vetrugno, Carla; Fanizzi, Francesco Paolo; De Pascali, Sandra Angelica; Storelli, Carlo; Marsigliante, Santo

    2011-01-01

    It was previously demonstrated that [Pt(O,O'-acac)(γ-acac)(DMS)] exerted toxic effects at high doses, whilst sub-cytotoxic concentrations induced anoikis and decreased cell migration. Aim of this study was to investigate the hypothesis that [Pt(O,O'-acac)(γ-acac)(DMS)] alters the [Ca(2+)](i) and that this is linked to its ability to trigger rapid apoptosis in MCF-7 cells. Thus, cells were treated with [Pt(O,O'-acac)(γ-acac)(DMS)] and its effects on some of the systems regulating Ca(2+) homeostasis were studied, also in cells dealing with the complex changes occurring during the Ca(2+) signalling evoked by extracellular stimuli. [Pt(O,O'-acac)(γ-acac)(DMS)] caused the decrease of PMCA activity (but not SERCA or SPCA) and Ca(2+) membrane permeability. These two opposite effects on [Ca(2+)](i) resulted in its overall increase from 102±12nM to 250±24nM after 15min incubation. The effects of [Pt(O,O'-acac)(γ-acac)(DMS)] were also evident when cells were stimulated with ATP: the changes in Ca(2+) levels caused by purinergic stimulation resulted altered due to decreased PMCA activity and to the closure of Ca(2+) channels opened by purinergic receptor. Conversely, [Pt(O,O'-acac)(γ-acac)(DMS)] did not affect the store-operated Ca(2+) channels opened by thapsigargin or by ATP. [Pt(O,O'-acac)(γ-acac)(DMS)] provoked the activation of PKC-α and the production of ROS that were responsible for the Ca(2+) permeability and PMCA activity decrease, respectively. The overall effect of [Pt(O,O'-acac)(γ-acac)(DMS)] is to increase the [Ca(2+)](i), an effect that is likely to be linked to its ability to trigger rapid apoptosis in MCF-7 cells. These data reinforce the notion that [Pt(O,O'-acac)(γ-acac)(DMS)] would be a promising drug in cancer treatment. Copyright © 2010 Elsevier Inc. All rights reserved.

  6. Chemical and biological studies of the major DNA adduct of cis-diamminedichloroplatinum(II), cis-[Pt(NH3)2/d(GpG)/], built into a specific site in a viral genome

    International Nuclear Information System (INIS)

    Naser, L.J.; Pinto, A.L.; Lippard, S.J.; Essigmann, J.M.

    1988-01-01

    A duplex Escherichia coli bacteriophage M13 genome was constructed containing a single cis-[Pt(NH 3 ) 2 /d(GpG)/] intrastrand cross-link, the major DNA adduct of the anticancer drug cis-diamminedichloroplatinum(II). The duplex dodecamer d(AGAAGGCCTAGA) x d(TCTAGGCCTTCT) was ligated into the HincII site of M13mp18 to produce an insertion mutant containing a unique StuI restriction enzyme cleavage site. A genome with a 12-base gap in the minus strand was created by hybridizing HincII-linearized M13mp18 duplex DNA with the single-stranded circular DNA of the 12-base insertion mutant. Characterization by pH-dependent 1 H NMR spectroscopy established that platinum binds to the N7 positions of the adjacent guanosines. The platinated oligonucleotide was phosphorylated in the presence of [γ- 32 P]ATP with bacteriophage T4 polynucleotide kinase and incorporated into the 12-base gap of the heteroduplex, thus situating the adduct specifically within the StuI site in the minus strand of the genome. The site of incorporation of the dodecamer was mapped to the expected 36-base region delimited by the recognition sites of XbaI and HindIII. Gradient denaturing gel electrophoresis of a 289-base-pair fragment encompassing the site of adduction revealed that the presence of the cis-[Pt(NH 3 ) 2 /d)GpG)/] cross-link induces localized weakening of the DNA double helix. Comparative studies revealed no difference in survival between platinated and unmodified double-stranded genomes. In contrast, survival of the single-stranded platinated genome was only 10-12% that of the corresponding unmodified single-stranded genome, indicating that the solitary cis-[Pt(NH 3 ) 2 /d(GpG)/] cross-link is lethal to the single-stranded bacteriophage

  7. Irradiated foodstuff: atom, junk-food and globalization

    International Nuclear Information System (INIS)

    Azam, Genevieve; Berlan, Jean-Pierre; Desbordes, Roland; Dufour, Francois; Fievet, Yann; Folliard, Thierry; Gallais, Veronique; Hauter, Wenonah; Jacquiau, Christian; Kastler, Guy; Lannoye, Paul; Le Goff, Lylian; Le Rohellec, Catherine; Louchard, Olivier; Marechal, Gilles; Nicolas, Yveline; Remesy, Christian; Trouve, Aurelie; Veillerette, Francois

    2008-01-01

    Food irradiation is officially presented as an ideal technology at the service of worldwide health safety and as an alternative to chemical processing of foodstuff. It is first of all a multi-usage technology for the preservation, disinfestation, ripening slowing down, and germination inhibition of products which serves the interests of multinational companies of the agriculture and food industry. According to the authors, it is also an instrument for the globalization of foodstuff trade encouraged by the international institutions and by some governments. The book stresses on the health, socio-economic and environmental risks of this technology: vitamins loss, carcinogenesis, mutagenesis, impact on local employment and economy, risks linked with the use of irradiation devices etc

  8. Long term limitation of cesium intake from foodstuffs

    International Nuclear Information System (INIS)

    1987-04-01

    The text is an edited summary of SSI's recommendations to the National Food Administration. In response to the recommendations, the Food Administration has issued diet recommendations and taken decisions on new maximum limits for food sold over-the-counter (effective from June 1, 1987). The diet recommendations aim at keeping yearly intakes below 50 000 (or, for informed persons accepting the extra risk, 500 000) Bq Cs-137 per year. The limits for food sold over-the-counter are 300 Bq Cs-137/kg, as before, for basic foodstuffs (including beef, pork, mutton, poultry, cereals, fruits and berries, vegetables, dairy produce, infant food and fish caught in the sea), but 1 500 Bq for other foodstuffs (such as reindeer and venison). (orig./HP)

  9. EPR assessment of the free radicals in irradiated foodstuffs

    International Nuclear Information System (INIS)

    Tencheva, S.; Katsareva, Ts.; Malinovski, A.; Kabasanov, K.

    1985-01-01

    In the hygienic assessment of radiation treated foodstuffs the study of free radicals formed during radiation exposure, their concentration and disintegration kinetics are of particular interest. In the work presented the concentration of the free radicals in irradiated prunes, nuts and corn is determined using EPR spectroscopy. The following doses are applied: 2, 10 and 20 kGy for prunes, 1, 10 and 20 kGy for nuts, and 0.75, 10 and 20 kGy for corn. EPR measurements are done immediately after the irradiation: 24 hours, and 3, 6, 9 and 15 days after the exposure. In the small radiation doses the formation of single radicals is observed. In doses of 10 kGy the spectra get complicated with the occurence of radicals R 1 , R 2 , R 3 and R 4 . The assessment of radicals proves to be a prospective method for the identification and determination of the preservation terms of foodstuffs

  10. Determination of lithium, rubidium and strontium in foodstuffs

    International Nuclear Information System (INIS)

    Evans, W.H.; Read, J.I.

    1985-01-01

    For the determination of total lithium, rubidium and strontium in foodstuffs the organic matter is destroyed by a wet-oxidation procedure. Both lithium and rubidium are measured by flame atomic-emission spectrophotometry, rubidium with the addition of a radiation buffer and strontium is measured by flame atomic-absorption spectrophotometry using the same radiation buffer. The optimum conditions for measurement are described and interferences noted. The accuracy of the method was assessed by measuring the recovery of these metals from foodstuff homogenates and values for standard reference materials are listed, for comparison with certified levels where these exist. From the results obtained standard deviations were calculated and derived limits of detection and confidence intervals are given. (author)

  11. Determination of β-activity of foodstuffs and menus

    International Nuclear Information System (INIS)

    Cieleszky, V.; Czegledi, P.; Tarjan, R.; Dobrovolszky, A.; Hapka, S.

    1974-01-01

    The total β and potassium activities of a lot of foodstuffs and menus have been determined. The average remaining β-activities were as follows: 33 pCi/100 g for vegetables; 132 pCi/100 g for wheat samples; 154 pCi/100 g for rye; 47-52 pCi/100 g for meat; 115 pCi/100 g for fish. The rest β-activity was max. 119 pCi/100 g (rasberry mash) for baby-conserves and 1120 pCi/100 g (Indian tea) for the examined import foodstuffs. The average daily intake of artificial β-activity by foods is in the range of 1000 pCi. (K.A.)

  12. Neutron activation analysis applied to nutritional and foodstuff studies

    International Nuclear Information System (INIS)

    Maihara, Vera A.; Santos, Paola S.; Moura, Patricia L.C.; Castro, Lilian P. de; Avegliano, Roseane P.

    2009-01-01

    Neutron Activation Analysis, NAA, has been successfully used on a regularly basis in several areas of nutrition and foodstuffs. NAA has become an important and useful research tool due to the methodology's advantages. These include high accuracy, small quantities of samples and no chemical treatment. This technique allows the determination of important elements directly related to human health. NAA also provides data concerning essential and toxic concentrations in foodstuffs and specific diets. In this paper some studies in the area of nutrition which have been carried out at the Neutron Activation Laboratory of IPEN/CNEN-SP will be presented: a Brazilian total diet study: nutritional element dietary intakes of Sao Paulo state population; a study of trace element in maternal milk and the determination of essential trace elements in some edible mushrooms. (author)

  13. Detection of Genetic Modification 'ac2' in Potato Foodstuffs

    Directory of Open Access Journals (Sweden)

    Petr Kralik

    2009-01-01

    Full Text Available The genetic modification 'ac2' is based on the insertion and expression of ac2 gene, originally found in seeds of amaranth (Amaranthus caudatus, into the genome of potatoes (Solanum tuberosum. The purpose of the present study is to develop a PCR method for the detection of the mentioned genetically modified potatoes in various foodstuffs. The method was used to test twenty different potato-based products; none of them was positive for the genetic modification 'ac2'. The European Union legislation requires labelling of products made of or containing more than 0.9 % of genetically modified organisms. The genetic modification 'ac2' is not allowed on the European Union market. For that reason it is suitable to have detection methods, not only for the approved genetic modifications, but also for the 'unknown' ones, which could still occur in foodstuffs.

  14. Evaluation of aluminum migration into foodstuffs from aluminium cookware

    Directory of Open Access Journals (Sweden)

    M Radi

    2014-05-01

    Full Text Available Nowadays, the existence of aluminum in human diet as a food contaminant has attracted the concerns of many researchers. It seems that the cooking pans are common sources of aluminum exposure through foodstuffs in Iran. The aim of this study was to evaluate the migration of aluminum from cooking containers into foodstuffs. For this purpose, solutions with different concentrations of citric acid, sodium chloride, fat, protein and sugar were prepared and migration of aluminum into these solutions was measured using atomic absorption spectrometry. Results showed that salt and citric acid concentrations could enhance aluminum migration; whereas, acid concentration was more effective than salt due to its corrosive effect. The intensity of heat processing and the duration of heat treatment had direct relation with aluminum migration. The aluminum content of cooked foods in aluminum cooking pans was also significantly more than control samples.

  15. Results of radioactivity measurements on foodstuffs in Romania

    Energy Technology Data Exchange (ETDEWEB)

    Ferdes, O [National Agency for Atomic Energy, Bucharest (Romania); Cojocariu, T [Institute for Food Research, Bucharest (Romania)

    1997-12-31

    There are presented the results of gamma-spectrometric measurements performed between 1986-1995 on: milk and dairy products; meat and meat products; fish; wheat flour; fresh fruits and vegetables. The foodstuffs are sampled from some representative areas like: Bucharest, Bechet (affected by Kozloduj NPP, Bulgaria), Cernavoda, middle of Transylvania, Neamt. The radioactivity measurements are performed by high-resolution {gamma}-ray spectrometry. There are identified and analysed mainly {sup 134}Cs, {sup 137}Cs, {sup 40}K and, sometimes, other radionuclides. There are pointed out: the constancy of natural radionuclides amounts; the drastic increasing in radioactive concentration in May 1986; the seasonal variation of radioactivity in some food items; the time - exponential diminution of radioactivity in 1991-1995; and the maximum permitted levels of radioactive contamination of foodstuffs following a nuclear accident. (author). 2 figs., 2 tabs., 8 refs.

  16. Melatonin in grapes and grape-related foodstuffs: A review.

    Science.gov (United States)

    Meng, Jiang-Fei; Shi, Tian-Ci; Song, Shuo; Zhang, Zhen-Wen; Fang, Yu-Lin

    2017-09-15

    A decade has passed since melatonin was first reported in grapes in 2006. During this time, melatonin has not only been found in the berries of most wine grape (Vitis vinifera L.) cultivars, but also in most grape-related foodstuffs, e.g. wine, grape juice and grape vinegar. In this review, we discuss the melatonin content in grapes and grape-related foodstuffs (especially wine) from previous studies, the physiological function of melatonin in grapes, and the factors contributing to the production of melatonin in grapes and wines. In addition, we identify future research needed to clarify the mechanisms of grape melatonin biosynthesis and regulation, and establish more accurate analysis methods for melatonin in grapes and wines. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Results of radioactivity measurements on foodstuffs in Romania

    International Nuclear Information System (INIS)

    Ferdes, O.; Cojocariu, T.

    1996-01-01

    There are presented the results of gamma-spectrometric measurements performed between 1986-1995 on: milk and dairy products; meat and meat products; fish; wheat flour; fresh fruits and vegetables. The foodstuffs are sampled from some representative areas like: Bucharest, Bechet (affected by Kozloduj NPP, Bulgaria), Cernavoda, middle of Transylvania, Neamt. The radioactivity measurements are performed by high-resolution γ-ray spectrometry. There are identified and analysed mainly 134 Cs, 137 Cs, 40 K and, sometimes, other radionuclides. There are pointed out: the constancy of natural radionuclides amounts; the drastic increasing in radioactive concentration in May 1986; the seasonal variation of radioactivity in some food items; the time - exponential diminution of radioactivity in 1991-1995; and the maximum permitted levels of radioactive contamination of foodstuffs following a nuclear accident. (author)

  18. Can Excited State Electronic Coherence Be Tuned via Molecular Structural Modification? A First-Principles Quantum Electronic Dynamics Study of Pyrazolate-Bridged Pt(II) Dimers

    Energy Technology Data Exchange (ETDEWEB)

    Lingerfelt, David B.; Lestrange, Patrick J.; Radler, Joseph J.; Brown-Xu, Samantha E.; Kim, Pyosang; Castellano, Felix N.; Chen, Lin X.; Li, Xiaosong

    2017-02-24

    Materials and molecular systems exhibiting long-lived electronic coherence can facilitate coherent transport, opening the door to efficient charge and energy transport beyond traditional methods. Recently, signatures of a possible coherent, recurrent electronic motion were identified in femtosecond pump-probe spectroscopy experiments on a binuclear platinum complex, where a persistent periodic beating in the transient absorption signal’s anisotropy was observed. In this study, we investigate the excitonic dynamics that underlie the suspected electronic coherence for a series of binuclear platinum complexes exhibiting a range of interplatinum distances. Results suggest that the long-lived coherence can only result when competitive electronic couplings are in balance. At longer Pt-Pt distances, the electronic couplings between the two halves of the binuclear system weaken, and exciton localization and recombination is favored on short time scales. For short Pt-Pt distances, electronic couplings between the states in the coherent superposition are stronger than the coupling with other excitonic states, leading to long-lived coherence.

  19. Derived intervention levels for mostly consumed foodstuffs in Iran

    International Nuclear Information System (INIS)

    Fathivand, A. A.; Amidi, J.

    2006-01-01

    Measures to protect the public following an accidental release of radionuclides to the environment will depend on the circumstances including the extent of the potential hazards. The projected levels of risk are an important precondition in emergency planning. The levels can be expressed in terms of concentration levels in the environment or in protection in foodstaffs. These derived intervention levels can be determined for the range of important radionuclides that could be released to the environment in the event of a nuclear accident. Materials and Methods: Derived intervention levels for 90 Sr, 131 l, Cs 134 + 137 Cs, 238 Pu + 239 Ru+ 241 Am and 103 Ru + 106 Ru radionuclide groups were calculated for infants ( 17 years) for mostly consumed foodstuffs in Iran. Calculations of DlLs were based on recommendations from international, national organizations and average food consumption rate data for Iran. Results: From our research it was found that DlLs for foodstuffs consumed in lran for above mentioned radionuclide groups except for Ruthenium group are equal to 387, 250, 1023 and 2.8 Bqkg -1 respectively. Conclusion: The comparison of DILs for foodstuffs consumed in lran and DILs adopted in the new food and drug administration Compliance Policy Guide which are 160, 170, 1200, 2 Bq.kg -1 for 90 Sr, 131 I, 134 / 137 Cs, 2 38 / 239 Pu plus 241 Am radionuclide groups respectively, shows agreement with cesium and plutonium group and higher values for strontium and Iodine group. In the case of nuclear accident or radiological events that might affect our country calculated DILs can be used to prevent or reduce exposure due to consumption of foodstuffs

  20. Tissue free water tritium separation from foodstuffs by azeotropic distillation

    International Nuclear Information System (INIS)

    Constantin, F.; Ciubotaru, A.; Popa, D.

    1998-01-01

    In this paper the tritium separation from tissue free water in foodstuffs by azeotropic distillation is described. Tritium in tissue water is assayed by liquid scintillation counting using well-established quenched correction method. The mean value of the tritium concentration in tissue water from foodstuffs is about 6-12 Bq/l very similar to the tritium mean concentration measured in the surface waters of the area where the samples have been collected (about 12 Bq/l. Therefore, the tritium content in the water fraction of the food samples can be considered in equilibrium with the local environmental water sources. The azeotropic distillation it is an accessible separation method which does not need a sophisticated and expansive distillation apparatus. It is a fast method of separation tissue free water from foodstuffs being very important in the surveillance activity of the environmental within nuclear electric plant. It is suitable for processing a small quantity of samples and for a production type facility when a large number of samples must be processed because the solvent can be purified and reused. The azeotropic distillation has some limits being used to separate water from samples with high content of water (85-90%) and simple a simple chemical structures as: vegetables, fruits, cereal, soil, vegetation. According to the results obtained, the organic substituents of milk, wine, meat (casein, lactose, milk fat, alcohol, esters) may enhance the chemisorption of tritium on through exchange organic hydrogen as -OH, -SH, -NH, -COOH with tritium. Also, the tissue water separation by azeotropic distillation is not complete and can not guarantee the absence of the vaporization isotope effect of the HTO/H 2 O system., However, the azeotropic distillation is the preferred method of the water extraction from food samples, which makes it useful for the tritium transfer from soil to foodstuffs. (authors)

  1. Tissue free water tritium separation from foodstuffs by azeotropic distillation

    Energy Technology Data Exchange (ETDEWEB)

    Constantin, F; Ciubotaru, A; Popa, D [Inspectorate of Public Health of Bucharest (Romania)

    1999-12-31

    In this paper the tritium separation from tissue free water in foodstuffs by azeotropic distillation is described. Tritium in tissue water is assayed by liquid scintillation counting using well-established quenched correction method. The mean value of the tritium concentration in tissue water from foodstuffs is about 6-12 Bq/l very similar to the tritium mean concentration measured in the surface waters of the area where the samples have been collected (about 12 Bq/l. Therefore, the tritium content in the water fraction of the food samples can be considered in equilibrium with the local environmental water sources. The azeotropic distillation it is an accessible separation method which does not need a sophisticated and expansive distillation apparatus. It is a fast method of separation tissue free water from foodstuffs being very important in the surveillance activity of the environmental within nuclear electric plant. It is suitable for processing a small quantity of samples and for a production type facility when a large number of samples must be processed because the solvent can be purified and reused. The azeotropic distillation has some limits being used to separate water from samples with high content of water (85-90%) and simple a simple chemical structures as: vegetables, fruits, cereal, soil, vegetation. According to the results obtained, the organic substituents of milk, wine, meat (casein, lactose, milk fat, alcohol, esters) may enhance the chemisorption of tritium on through exchange organic hydrogen as -OH, -SH, -NH, -COOH with tritium. Also, the tissue water separation by azeotropic distillation is not complete and can not guarantee the absence of the vaporization isotope effect of the HTO/H{sub 2}O system., However, the azeotropic distillation is the preferred method of the water extraction from food samples, which makes it useful for the tritium transfer from soil to foodstuffs. (authors) 2 tabs.

  2. Bioaccumulation of zinc in foodstuffs by nuclear and related techniques

    International Nuclear Information System (INIS)

    Diaz Rizo, O.; Olivares Reumont, S.; Lima Cazorla, L.; Gelen Rudnikas, A.; D'Alessandro Rodriguez, K.; Arado Lopez, J. O.; Denis Alpizar, O.; Diaz Arado, O.; Viguri Fuente, J.

    2011-01-01

    The bioaccumulation of zinc in regular consumption foodstuff (sugar, rice, some vegetables, roots and shellfishes) in Cuba is reported. Zinc content in food samples and its corresponding soils or sediments are determined by Instrumental Neutron Activation analysis (INAA), X-Ray Fluorescence analysis (XRF), inductively coupled plasma emission spectrometry (ICP-AES) and Atomic Absorption spectrometry (AES). The obtained results show rice as the major Zn bioaccumulator of the studied products and the main Zn source in Cuban human diet. (Author)

  3. Toxic and trace elements in foodstuffs in Japan

    International Nuclear Information System (INIS)

    Muramatsu, Y.; Sumiya, M.; Ohmomo, Y.

    1988-01-01

    From the viewpoint of environmental safety assessment it is important to have information on the levels of toxic and trace elements in foodstuffs. It is also essential to develop suitable analytical methods for these elements in order to obtain accurate analytical data. In this paper, two analytical methods were used, inductively-coupled plasma atomic emission spectrometry (ICP-AES) and neutron activation analysis (NAA), for analysing toxic and trace elements in several food samples. 3 tabs

  4. Trace and toxic elements in foodstuffs in Japan

    International Nuclear Information System (INIS)

    Muramatsu, Y.; Sumiya, M.; Yanagisawa, K.; Ohmomo, Y.

    1994-01-01

    Concentrations of trace elements in several foodstuffs collected in Japan were analyzed by neutron activation analysis (NAA), inductively-coupled plasma atomic emission spectrometry (ICP-AES) and anodic striping voltametry (ASV). The elements analyzed were as follows: Zn, Se, As, Hg, Cs, Cr, Co, Fe, Rb, Br and K by NAA; Mn, Ba, Sr, Mg, Ca, P, K, Zn, Cu and Fe by ICP-AES; and Pb, Cd, Cu and Zn by ASV. Because of the high consumption of rice in Japan, the focus of analysis was on this foodstuff. Concentrations of K, Mg, Mn, P and Zn in different polished rice samples were similar, whereas those of Br, Co, Cs, Rb and Se varied. Levels of toxic elements in polished rice were generally lower than those in other foodstuffs. The highest concentrations of As, Hg, Se and Zn were found in marine products, i.e.. Hijiki-algae (As: 59 mg/kg, dry), tuna (Hg: 1.1 mg/kg, dry), bonito (Se: 4.5 mg/kg, dry) and oysters (Zn: 350 mg/kg, dry). Dietary intakes of As, Ca, Cd, Cu, Fe, Hg, K, Mg, Mn, P, Pb, Se and Zn by Japanese were estimated by using these analytical results and published food consumption data in Japan. We have also identified the major sources of the elements in dietary intakes as follows: (a) about 90% of the As was derived from marine products (fish and seaweed); (b) about 70% of the Hg was derived from fish; (c) about 40-60% of the Cd and the Mn and 20-40% of the Zn, Cu and Mg was derived from rice; (d) selenium was mostly derived from fish, meat and eggs; (e) more than 20% of the Ca was derived from milk and milk products; (f) elements such as Fe, K, P and Pb was derived from different sorts of foodstuffs. (author). 7 refs, 1 fig., 7 tabs

  5. 210Pb and 210Po activities in French foodstuffs

    International Nuclear Information System (INIS)

    Renaud, Ph.; Roussel-Debet, S.; Pourcelot, L.; Thebault, H.; Loyen, J.; Gurriaran, R.

    2015-01-01

    The data on 210 Pb and 210 Po activities in French foodstuffs acquired during the last 15 years are numerous enough to derive reference values which will be usable to assess the dose to the French population due to the intake of these two natural radionuclides. The means and ranges are close to those observed in various countries and are most often higher than the reference values proposed by UNSCEAR. Mussels and oysters exhibit the highest 210 Po activities of all kinds of foodstuffs, with a mean value of 27 Bq.kg -1 fresh weight, followed by crustaceans and small fish species (anchovies, mullets, sardines, etc.) with 210 Po activities in the order of 3 to 10 Bq.k -1 fresh weight; cephalopods and other fish species presenting activities around 1 to 3 Bq.kg -1 fresh, close to the UNSCEAR reference value. Below these highest 210 Po activities are those of 210 Po and 210 Pb in terrestrial kinds of foodstuffs, by decreasing order: meats (around 1 Bq.kg -1 fresh), cereals (0.4 Bq.kg -1 ), leafy vegetables (0.3 Bq.kg -1 ), other vegetables and fruits (0.1 Bq.kg -1 ), and milk (from 0.03 to 0.1 Bq.L -1 ). (authors)

  6. Contamination of Japanese foodstuffs of terrestrial origin after the Fukushima nuclear accident and related dose assessments Part 1: foodstuff contamination

    International Nuclear Information System (INIS)

    Renaud, Ph.; Simon-Cornu, M.; Gonze, M.A.; Mourlon, C.; Parache, V.; Korsakissok, I.; Navarro, E.; Cessac, B.; Rannou, A.; Champion, D.

    2013-01-01

    During and after the Fukushima accident, the IRSN collected and interpreted the results of radiological measurements performed on foodstuffs of terrestrial origin published by Japan's Ministry of Health between mid-March 2011 and July 2012. Analysis of the findings shows that the accident's date, livestock-rearing practices and the deposits' characteristics had a decisive influence. The fact that radioactive fallout occurred very early in the growing and breeding season largely explains the moderate contamination of most foodstuffs of terrestrial origin, notably in the areas with the largest deposits. In the case of dairy products and meat, feeding imported fodder to livestock in stables, a common practice in Japan, compounded the calendar effect. Measurements published in Japan have also borne out the particular sensitivity of mushrooms, including cultivated species, and game. (authors)

  7. Effect of HCl Concentration on the Oxidation of LIX 63 and the Subsequent Separation of Pd(II), Pt(IV), Ir(IV) and Rh(III) by Solvent Extraction

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Thi Hong; Lee, Man Seung [Mokpo National University, Jeollanamdo (Korea, Republic of)

    2016-10-15

    During the selective extraction of Pd(II) by LIX 63 from 6 M HCl solutions containing platinum group metals, an oxidation-reduction reaction occurs between the LIX 63 and Ir(IV). Since the reduced Ir(III) cannot be extracted by solvating and amine extractants, the oxidation-reduction reaction has a significant effect on the separation of Pt(IV), Ir(IV) and Rh(III). Therefore, the effect of HCl concentration on the reduction of Ir(IV) during the extraction with LIX 63 was investigated at 3 and 6 M HCl solutions. The extraction behavior of Iridium by Aliquat 336 from the Pd(II) free raffinate showed that the percentage of iridium extraction rapidly decreased when HCl concentration was increased from 3 to 6 M, indicating that more Ir(IV) was reduced to Ir(III). Extraction schemes for the separation of Pt(IV), iridium and Rh(III) by Aliquat 336 from 3 and 6 M HCl solutions were investigated.

  8. Mixed adenine/guanine quartets with three trans-a2 Pt(II) (a=NH(3) or MeNH(2)) cross-links: linkage and rotational isomerism, base pairing, and loss of NH(3).

    Science.gov (United States)

    Albertí, Francisca M; Rodríguez-Santiago, Luis; Sodupe, Mariona; Mirats, Andrea; Kaitsiotou, Helena; Sanz Miguel, Pablo J; Lippert, Bernhard

    2014-03-17

    Of the numerous ways in which two adenine and two guanines (N9 positions blocked in each) can be cross-linked by three linear metal moieties such as trans-a2 Pt(II) (with a=NH3 or MeNH2 ) to produce open metalated purine quartets with exclusive metal coordination through N1 and N7 sites, one linkage isomer was studied in detail. The isomer trans,trans,trans-[{Pt(NH3 )2 (N7-9-EtA-N1)2 }{Pt(MeNH2 )2 (N7-9-MeGH)}2 ][(ClO4 )6 ]⋅3H2 O (1) (with 9-EtA=9-ethyladenine and 9-MeGH=9-methylguanine) was crystallized from water and found to adopt a flat Z-shape in the solid state as far as the trinuclear cation is concerned. In the presence of excess 9-MeGH, a meander-like construct, trans,trans,trans-[{Pt(NH3 )2 (N7-9-EtA-N1)2 }{Pt(MeNH2 )2 (N7-9-MeGH)2 }][(ClO4 )6 ]⋅[(9-MeGH)2 ]⋅7 H2 O (2) is formed, in which the two extra 9-MeGH nucleobases are hydrogen bonded to the two terminal platinated guanine ligands of 1. Compound 1, and likewise the analogous complex 1 a (with NH3 ligands only), undergo loss of an ammonia ligand and formation of NH4 (+) when dissolved in [D6 ]DMSO. From the analogy between the behavior of 1 and 1 a it is concluded that a NH3 ligand from the central Pt atom is lost. Addition of 1-methylcytosine (1-MeC) to such a DMSO solution reveals coordination of 1-MeC to the central Pt. In an analogous manner, 9-MeGH can coordinate to the central Pt in [D6 ]DMSO. It is proposed that the proton responsible for formation of NH4 (+) is from one of the exocyclic amino groups of the two adenine bases, and furthermore, that this process is accompanied by a conformational change of the cation from Z-form to U-form. DFT calculations confirm the proposed mechanism and shed light on possible pathways of this process. Calculations show that rotational isomerism is not kinetically hindered and that it would preferably occur previous to the displacement of NH3 by DMSO. This displacement is the most energetically costly step, but it is compensated by the proton

  9. Assessments of internal doses by ingestion of radioactive foodstuffs in Bangladesh

    International Nuclear Information System (INIS)

    Mollah, A.S.

    1996-01-01

    The internal radiation dose to a man from the consumption of foodstuffs was estimated an the basis of the measured radioactivities in the foodstuffs in Bangladesh. The total annual internal effective dose equivalent was found to be 454.56 μSv. The dose from intake of radionuclides by foodstuffs (ingestion dose) in general is so low that no harmful effects will occur directly. (author)

  10. Variation in thermoluminescence of irradiated brands of foodstuffs: a test for hygienic quality

    International Nuclear Information System (INIS)

    Mamoon, A.; Zaheer, A.; Abu-Abdullah, S.

    1996-01-01

    Thermoluminescence of irradiated foodstuffs such as herbs and spices, is mostly due to attached dust or soil particles. Different brands of the same foodstuff sometimes give thermoluminescent signals of different intensities, apparently due to different degrees of dust contamination. It is of obvious importance to choose brands of foodstuffs that appear to have less dust contamination, i.e. of better hygienic quality. Several food items were investigated with respect to their thermoluminescent (TL) emission in order to assess TL usefulness as an indicator of hygienic quality for foods prone to contamination by dust. In this regard some foodstuff were artificially contaminated with a soil sample and their thermoluminescent emission was obtained. (author)

  11. Variation in thermuluminescence of irradiated brands of foodstuffs: A test for hygienic quality

    Science.gov (United States)

    Mamoon, A.; Zaheer, A.; Abu-Abdullah, S.

    1996-11-01

    Thermoluminescence of irradiated foodstuffs such as herbs and spices, is mostly due to attached dust or soil particles. Different brands of the same foodstuff sometimes give thermoluminescent signals of different intensities, apparently due to different degrees of dust contamination. It is of obvious importance to choose brands of foodstuffs that appear to have less dust contamination, i.e. of better hygienic quality. Several food items were investigated with respect to their thermoluminescent (TL) emission in order to assess TL usefulness as an indicator of hygienic quality for foods prone to contamination by dust. In this regard some foodstuffs were artificially contaminated with a soil sample and their thermoluminescent emission was obtained.

  12. Learning-Based Precool Algorithms for Exploiting Foodstuff as Thermal Energy Reserve

    DEFF Research Database (Denmark)

    Vinther, Kasper; Rasmussen, Henrik; Izadi-Zamanabadi, Roozbeh

    2015-01-01

    Refrigeration is important to sustain high foodstuff quality and lifetime. Keeping the foodstuff within temperature thresholds in supermarkets is also important due to legislative requirements. Failure to do so can result in discarded foodstuff, a penalty fine to the shop owner, and health issues....... However, the refrigeration system might not be dimensioned to cope with hot summer days or performance degradation over time. Two learning-based algorithms are therefore proposed for thermostatically controlled loads, which precools the foodstuff in display cases in an anticipatory manner based on how...

  13. USE OF FOODSTUFFS WITH PRO-AND PREBIOTIC ACTIONS IN INFANT FOOD

    Directory of Open Access Journals (Sweden)

    K.S. Ladodo

    2006-01-01

    Full Text Available The article deals with the data about opportunity to enrich the modern infant foodstuffs with pro and prebiotics. The authors name the contents of the foodstuffs with pro and prebiotic properties, findings of the multicentric research according to the estimate of their clinical efficiency among healthy and ill infants. They show the safety and high efficiency of the use of the given healthful and dietary foodstuffs.Key words: infant food, foodstuffs, probiotics, prebiotics, bifidus bacteria, lactic acid bacilli, oligosaccharides, lactulose, inulin.

  14. Translocation of uranium from water to foodstuff while cooking.

    Science.gov (United States)

    Krishnapriya, K C; Baksi, Ananya; Chaudhari, Swathi; Gupta, Soujit Sen; Pradeep, T

    2015-10-30

    The present work report the unusual uranium uptake by foodstuff, especially those rich in carbohydrates like rice when they are cooked in water, contaminated with uranium. The major staple diet in South Asia, rice, was chosen to study its interaction with UO2(2+), the active uranium species in water, using inductively coupled plasma mass spectrometry. Highest uptake limit was checked by cooking rice at very high uranium concentration and it was found to be good scavenger of uranium. To gain insight into the mechanism of uptake, direct interaction of UO2(2+) with monosaccharides was also studied, using electrospray ionization mass spectrometry taking mannose as a model. The studies have been done with dissolved uranium salt, uranyl nitrate hexahydrate (UO2(NO3)2·6H2O), as well as the leachate of a stable oxide of uranium, UO2(s), both of which exist as UO2(2+) in water. Among the eight different rice varieties investigated, Karnataka Ponni showed the maximum uranium uptake whereas unpolished Basmati rice showed the minimum. Interaction with other foodstuffs (potato, carrot, peas, kidney beans and lentils) with and without NaCl affected the extent of chemical interaction but was not consistent with the carbohydrate content. Uranium interaction with D-mannose monitored through ESI-MS, under optimized instrumental parameters, identified the peaks corresponding to uranyl adduct with mannose monomer, dimer and trimer and the species were confirmed by MS/MS studies. The product ion mass spectra showed peaks illustrating water loss from the parent ion as the collision energy was increased, an evidence for the strong interaction of uranium with mannose. This study would constitute the essential background for understanding interaction of uranium with various foods. Extension of this work would involve identification of foodstuff as green heavy metal scavengers. Copyright © 2015. Published by Elsevier B.V.

  15. Transfer of chlorine from the environment to agricultural foodstuffs

    International Nuclear Information System (INIS)

    Kashparov, V.; Colle, C.; Levchuk, S.; Yoschenko, V.; Svydynuk, N.

    2007-01-01

    The factors governing chlorine transfer from Phaeozem and Greyzem soils to various important crop species (foodstuff and forage) were determined in natural conditions in the Kiev region of Ukraine. The stable chlorine concentration ratio (CR) values were the lowest in apple (0.5 ± 0.3) and strawberry (2 ± 1), higher in vegetables (5 ± 3), seeds (15 ± 7) and reached a maximum in straw (187 ± 90). The average CR values of 36 Cl were estimated for the most important crops using all experimental data on 36 Cl and stable chlorine transfer into plants from various soils. It was experimentally shown that boiling potatoes in water leads to an equilibrium between 36 Cl specific content in the water and moisture in the cooked potato. The 36 Cl processing factor (PF) for boiling various foodstuffs is equal to the ratio of water mass in the cooked foodstuff to the total water mass (in the food and the decoction). 36 Cl PF for cereal flour can be estimated as 1. The 36 Cl processing factor for dairy products is equal to the ratio of residual water mass in the product to initial water mass in milk. At a 36 Cl specific activity in soil of 1 Bq kg -1 , the estimated annual dietary 36 Cl intake into human organism (adult man) is about 10 kBq. Sixty to seventy percent of the above amount will be taken in via milk and dairy products, 7-16% via meat, 14-16% via bread and bakery items and 8-12% via vegetables. The highest annual 36 Cl intake, 10.7 kBq, is predicted for 1-year-old children. The expected effective doses from annual 36 Cl intake are higher for younger age groups, increasing from 0.008 mSv in adults to 0.12 mSv in 1-year-old children

  16. Assessment of radionuclides in imported foodstuffs in Iran

    International Nuclear Information System (INIS)

    Hosseini, T.; Fathivand, A. A.; Barati, H.; Karimi, M.

    2006-01-01

    Knowledge of radioactivity levels in human diet is of particular concern for the estimation of possible radiological hazards to human health. However, very few surveys of radioactivity in food have been conducted in Iran; therefore the baseline values of the natural radionuclides concentration (4 0K , 2 26R a and 2 32T h), and man made radionuclide, 1 37C s, were determined in twenty six samples of imported foodstuff in Iran. Materials and Methods: Twenty six samples of different kinds of imported foodstuff were selected for analysis. These samples, after pretreatment and washing (if necessary), were measured by a low level gamma spectrometry system. Results: All samples were found to contain detectable 4 0K content in range 6.4 to 778.4 Bq.kg -1 fresh weights (f w). 1 37C s, 2 26R a and 2 32T h were detectable in most of the samples. The maximum concentration of 4 0K , 2 26R a and 2 32T h were found in tea sample, equal to 778.4±23.4, 2.9±0.1 and 5.4±0.2 Bq.kg -1 (f w), respectively, where as for 1 37C s it was 3.2±0.1 Bq.kg -1 (f w) in milk powder. Conclusion: The concentrations of 4 0K and 1 37C s in different imported foodstuff are comparable with those from the other countries yet 2 32T h concentration is higher than the reported values. Also, 2 26R a results appear to be higher than the reported values in some cases

  17. Mixed-ligand Pt(II) dithione-dithiolato complexes: influence of the dicyanobenzodithiolato ligand on the second-order NLO properties.

    Science.gov (United States)

    Espa, Davide; Pilia, Luca; Marchiò, Luciano; Artizzu, Flavia; Serpe, Angela; Mercuri, Maria Laura; Simão, Dulce; Almeida, Manuel; Pizzotti, Maddalena; Tessore, Francesca; Deplano, Paola

    2012-03-28

    The mixed-ligand dithiolene complex [Pt(Bz(2)pipdt)(dcbdt)] (1) bearing the two ligands Bz(2)pipdt = 1,4-dibenzyl-piperazine-3,2-dithione and dcbdt = dicyanobenzodithiolato, has been synthesized, characterized and studied to evaluate its second-order optical nonlinearity. The dithione/dithiolato character of the two ligands gives rise to an asymmetric distribution of the charge in the molecule. This is reflected by structural data showing that in the C(2)S(2)PtS(2)C(2) dithiolene core the four sulfur atoms define a square-planar coordination environment of the metal where the Pt-S bond distances involving the two ligands are similar, while the C-S bond distances in the C(2)S(2) units exhibit a significant difference in Bz(2)pipdt (dithione) and dcbdt (dithiolato). 1 shows a moderately strong absorption peak in the visible region, which can be related to a HOMO-LUMO transition, where the dcbdt ligand (dithiolato) contributes mostly to the HOMO, and the Bz(2)pipdt one (dithione) mostly to the LUMO. Thus this transition has ligand-to-ligand charge transfer (CT) character with some contribution of the metal and undergoes negative solvatochromism and molecular quadratic optical nonlinearity (μβ(0) = -1296 × 10(-48) esu), which was determined by the EFISH (electric-field-induced second-harmonic generation) technique and compared with the values of similar complexes on varying the dithiolato ligand (mnt = maleonitriledithiolato, dmit = 2-thioxo-1,3-dithiole-4,5-dithiolato). Theoretical calculations help to elucidate the role of the dithiolato ligands in affecting the molecular quadratic optical nonlinearity of these complexes.

  18. Estimating the Heat of Formation of Foodstuffs and Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Burnham, Alan K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2010-11-23

    Calorie estimates for expressing the energy content of food are common, however they are inadequate for the purpose of estimating the chemically defined heat of formation of foodstuffs for two reasons. First, they assume utilization factors by the body.1,2,3 Second, they are usually based on average values for their components. The best way to solve this problem would be to measure the heat of combustion of each material of interest. The heat of formation can then be calculated from the elemental composition and the heats of formation of CO2, H2O, and SO2. However, heats of combustion are not always available. Sometimes elemental analysis only is available, or in other cases, a breakdown into protein, carbohydrates, and lipids. A simple way is needed to calculate the heat of formation from various sorts of data commonly available. This report presents improved correlations for relating the heats of combustion and formation to the elemental composition, moisture content, and ash content. The correlations are also able to calculate heats of combustion of carbohydrates, proteins, and lipids individually, including how they depend on elemental composition. The starting point for these correlations are relationships commonly used to estimate the heat of combustion of fossil fuels, and they have been modified slightly to agree better with the ranges of chemical structures found in foodstuffs and biomass.

  19. Assessment of 40K levels in foodstuffs by gamma spectrometry

    International Nuclear Information System (INIS)

    Chinnaesakki, S.; Sartandel, S.J.; Bara, S.V.; Krishna, N.S.; Vinod Kumar, A.; Tripathi, R.M.; Puranik, V.D.

    2012-01-01

    Potassium-40 ( 40 K) is a naturally occurring radioactive isotope of potassium. Radioactive potassium-40 comprises a very small fraction(0.012%) of naturally occurring potassium, which is an element found in large amounts throughout nature. The half-life of 40 K is 1.3 billion years, and it decays to calcium-40 ( 40 Ca) by emitting a beta particle (89 %) and to the argon-40 ( 40 Ar) gas by electron capture with the emission of an energetic gamma ray of energy 1460 keV (10.7%). Humans require potassium to sustain biological processes, with most including 40 K being almost completely absorbed upon ingestion, moving quickly from the gastrointestinal tract to the blood stream (ANL-EVS, 2007). The body content of potassium is under homeostatic control. The total annual effective dose due to inhalation and ingestion of terrestrial radionuclides is assessed to be 0.29 mSv, of which 0.17mSv is due to 40 K and 0.12 mSv to the long-lived radionuclides in the uranium and thorium series (UNSCEAR 2008). Hence, measurement of 40 K in foodstuff is very much essential. This paper discusses the measurement of 40 K in foodstuffs samples collected in and around the new Bhabha Atomic Research Centre campus, Vishakhapatnam, Andhra Pradesh. This study was carried out as part of the baseline radiological monitoring

  20. Structural properties and stability of the bcc and omega phases in the Zr-Nb system. Pt. II. Composition dependence of the lattice parameters

    International Nuclear Information System (INIS)

    Grad, G.B.; Guillermet, A.F.; Pieres, J.J.; Cuello, G.J.; Consejo Nacional de Investigaciones Cientificas y Tecnicas, Buenos Aires; Universidad Nacional del Comahue

    1996-01-01

    For pt.I see Guillermet, A.F., J. Nucl. Mater., vol.218, p.236-46, 1995. This paper deals with the composition dependence of the lattice parameters of the bcc and omega phases of the Zr-Nb system. The experimental part of the work comprises neutron scattering experiments on a Zr-10 at.% Nb alloy in the as-quenched state and after successive aging treatments at 773 K. This new information is combined with an extensive review of the available data, and a detailed analysis is performed of the effects of composition and heat-treatment upon the lattice parameters a Ω and c Ω of the omega phase and the lattice-parameter relations between bcc and omega. A striking behaviour is detected in the variation of a Ω with composition in low-Nb alloys. (orig.)

  1. In vivo and in vitro testing for selenium and selenium compounds bioavailability assessment in foodstuff.

    Science.gov (United States)

    Moreda-Piñeiro, Jorge; Moreda-Piñeiro, Antonio; Bermejo-Barrera, Pilar

    2017-03-04

    The assessment of selenium and selenium species bioavailability in foodstuff is of special concern on the context of human nutrition. In vivo (human and animal), and in vitro tests are important approaches for estimating the bioavailability of toxic and essential compounds to humans. An overview on in vivo and in vitro bioavailability assays for releasing selenium and selenium species in foodstuffs is summarized. Se and Se species content in a foodstuff critically influence Se bioavailability and bioactivity to humans and animals. Se bioavailability is affected by foodstuff-matrix major composition and minor components. Foodstuffs processing and/or treatments could enhancement or decrease Se bioavailability. Experimental conditions such as the selection of healthy status of examined people (in in vivo humans approaches), the selection of animal model (in vivo animals approaches), or the selection of GI conditions (in in vitro tests) could determines the results. Thus, international standardized protocol for in vivo and in vitro approaches assessment is mandatory.

  2. Preparation of Pt Nanocatalyst on Carbon Materials via a Reduction Reaction of a Pt Precursor in a Drying Process.

    Science.gov (United States)

    Lee, Jae-Young; Lee, Woo-Kum; Rim, Hyung-Ryul; Joung, Gyu-Bum; Weidner, John W; Lee, Hong-Ki

    2016-06-01

    Platinum (Pt) nanocatalyst for a proton-exchange membrane fuel cell (PEMFC) was prepared on a carbon black particle or a graphite particle coated with a nafion polymer via a reduction of platinum(II) bis(acetylacetonate) denoted as Pt(acac)2 as a Pt precursor in a drying process. Sublimed Pt(acac)2 adsorbed on the nafion-coated carbon materials was reduced to Pt nanoparticles in a glass reactor at 180 degrees C of N2 atmosphere. The morphology of Pt nanoparticles on carbon materials was observed by scanning electron microscopy (SEM) and the distribution of Pt nanoparticles was done by transmission electron microscopy (TEM). The particle size was estimated by analyzing the TEM image using an image analyzer. It was found that nano-sized Pt particles were deposited on the surface of carbon materials, and the number density and the average particle size increased with increasing reduction time.

  3. Translocation of uranium from water to foodstuff while cooking

    International Nuclear Information System (INIS)

    Krishnapriya, K.C.; Baksi, Ananya; Chaudhari, Swathi; Gupta, Soujit Sen; Pradeep, T.

    2015-01-01

    Highlights: • Rice can efficiently uptake uranium from water contaminated with uranyl nitrate hexahydrate (UO 2 (NO 3 ) 2.6 H 2 O), while cooking. • Unusual uranium uptake to the extent of about 1000 ppm is observed when rice is cooked in highly concentrated uranium contaminated water (1240 ppm). • Nature of interaction of uranium with carbohydrates is probed using small monosaccharides like glucose and mannose. • Electrospray ionization mass spectrometry showed UO 2 2+ to be the most stable species in water in such solutions which can form complexes with sugars. • The species (UO 2 2+ ) is also observed in the case of water exposed to the common mineral, uranium oxide (UO 2 ) and similar type of complexation is observed with sugars. - Abstract: The present work report the unusual uranium uptake by foodstuff, especially those rich in carbohydrates like rice when they are cooked in water, contaminated with uranium. The major staple diet in South Asia, rice, was chosen to study its interaction with UO 2 2+ , the active uranium species in water, using inductively coupled plasma mass spectrometry. Highest uptake limit was checked by cooking rice at very high uranium concentration and it was found to be good scavenger of uranium. To gain insight into the mechanism of uptake, direct interaction of UO 2 2+ with monosaccharides was also studied, using electrospray ionization mass spectrometry taking mannose as a model. The studies have been done with dissolved uranium salt, uranyl nitrate hexahydrate (UO 2 (NO 3 ) 2 ·6H 2 O), as well as the leachate of a stable oxide of uranium, UO 2 (s), both of which exist as UO 2 2+ in water. Among the eight different rice varieties investigated, Karnataka Ponni showed the maximum uranium uptake whereas unpolished Basmati rice showed the minimum. Interaction with other foodstuffs (potato, carrot, peas, kidney beans and lentils) with and without NaCl affected the extent of chemical interaction but was not consistent with the

  4. Prothrombin time (PT)

    Science.gov (United States)

    PT; Pro-time; Anticoagulant-prothrombin time; Clotting time: protime; INR; International normalized ratio ... PT is measured in seconds. Most of the time, results are given as what is called INR ( ...

  5. Determination and evaluation of toxic elements in Chinese foodstuffs

    International Nuclear Information System (INIS)

    Sun Laiyan; Lu Fengying; Zhou Wenping; Zhen Houxi; Su Rongwei; Liao Qingshang; Li Xuezeng; Wang Huaihui

    1988-01-01

    The concentrations of toxic elements As, Br, Cr, Cu, Pb, Se and Zn in various foodstuffs collected in Beijing, Shanghai, Xian and Wuhan were determined using neutron activation analysis (NAA) and atomic absorption spectrometry (AAS) methods were obtained with high or medium precision. According to the average daily intake of various foods, the daily intake of these toxic elements were estimated for each person in the four cities. They (in microgram) were 42.6, 166.3, 1738, 106.8, 7939, 1145 and 67.1 respectively for As, Cr, Cu, Se, Zn, Br and Pb in Beijing, 52.2, 167, 1213, 91.5, 6026, 519 and 89.9 in Shanghai, 46.2, 184, 1782, 119.2, 8729, 1132 and 133.4 in Xian, and 63.2, 142.1, 1556, 76.9, 7882, 528 and 73.7 in Wuhan. (author). 2 refs, 12 tabs

  6. Development of DNA elution method to detect irradiated foodstuff

    International Nuclear Information System (INIS)

    Copin, M.P.; Bourgeois, C.M.

    1991-01-01

    The aim of the work is to develop a reliable method to detect whether a fresh and frozen foodstuff has been irradiated. The molecule of DNA is one of the targets of ionizing radiation. The induction of three major classes of lesion have been shown. Double strand breaks, single strand breaks and base damage. Among the different techniques used to observe and quantify the strand breaks, techniques of elution are very interesting. The method proposed consisted of a filtration of the DNA at the atmospheric pressure and in non denaturing conditions. The amount of DNA retained on the filter is measured after being suitably labelled by microfluorometry. A difference in the amount of DNA retained on a filter of 2 μm from a lysed muscular tissue sample between a frozen Norway lobster which has been irradiated and one which has not, is observed. 7 refs

  7. Radiolysis of carbohydrates and of carbohydrate-containing foodstuffs

    International Nuclear Information System (INIS)

    Diehl, J.F.; Adam, S.; Delincee, H.; Jakubick, V.

    1978-01-01

    Toxicological evaluation of irradiated foodstuffs requires knowledge of radiation-induced chemical changes. A review of the literature reveals much information on the radiation chemistry of pure substances, e.g., dilute solutions of individual carbohydrates. Much less is known about the interactions of food constituents during irradiation. In an effort to remedy this situation, radiation effects on various compounds have been studied in systems of increasing complexity. In one approach, gas chromatography was used to investigate the radiolysis of tehalose in pure solution and in the presence of amino acids or proteins. In another approach, radiation-induced aggregation of proteins and of [ 14 C]tryptophan with proteins was studied in the absence and presence of carbohydrates (trehalose, starch), emulsified sunfower oil, and a mixture of carbohydrates and emulsified sunflower oil

  8. Neutron activation analysis of trace elements in foodstuffs

    International Nuclear Information System (INIS)

    Schelenz, R.; Fischer, E.

    1976-05-01

    A neutron activation method for multielement determination in biological material was developed. The individual steps of the method include radiochemical processing as well as nondestructive techniques. In order to develop a high resolution gamma spectrometric method the indispensable assumptions were the application of Ge(Li)-semiconductor detectors, multi-channel pulse height analyzers and the use of electronic data evaluation with mini-computers for the automatic evaluation of complex gamma spectra. After radiochemical separation (RNAA) 33 elements can be determined in biological materials and by application of nondestructive, purely instrumental techniques (INAA) 25 elements. The time required for the analysis of 33 elements can be determined in biological materials and by application of nondestructive, purely instrumental techniques (INAA) 25 elements. The time required for the analysis of 33 elements is 4 days. The neutron activation method is used routinely for the determination of trace elements in foodstuffs and in the field of nutrition research. (orig.) [de

  9. Determination of toxic elements in foodstuffs in Vietnam

    International Nuclear Information System (INIS)

    Nguyen Van Minh; Le Thi Ngoc Trinh; Nguyen Giang; Le Tat Mua; Nguyen Mong Sinh

    2006-01-01

    The studying samples of this work have been collected from different areas of Vietnam including industrial areas in HCM city, Dongnai, Vungtau and non-industrial area, Dalat city. The concentrations of the toxic elements as: As, Hg, Cr, Co, Fe, Cu, Cd, Se, As, Zn, Pb in many foodstuff samples together with intercomparison sample which have been distributed by National Food Administration (Sweden) were analyzed by Instrumental Neutron Activation Analysis (INAA), Radiochemical Neutron Activation Analysis (RNAA); Atomic Absorption Spectrophotometer (AAS) and Anodic Stripping Voltammeter (ASV). The obtained results shown that the concentration of toxic elements in the collected samples from selected industrial areas of Vietnam are lower than the maximum permissible concentrations. (author)

  10. Stability of vitamin D in foodstuffs during cooking

    DEFF Research Database (Denmark)

    Jakobsen, Jette; Knuthsen, Pia

    2014-01-01

    We investigated the retention of vitamin D3 and 25-hydroxyvitamin D3 in eggs, vitamin D3 in margarine, and vitamin D3 and vitamin D2 in bread. Our set-up illustrated the cooking methods usually performed in households i.e. boiling, frying in pan and oven, and baking. All experiments were performed...... three times independently of one another. The retention of vitamin D compounds in eggs and margarine during heat treatment in an oven for 40min at normal cooking temperature showed retention at 39–45%, while frying resulted in retention at 82–84%. Boiled eggs were found to have a similar level...... of vitamin D3 and 25-hydroxyvitamin D3 in eggs was shown. Cooking may cause detrimental loss of vitamin D, but it depends on the actual foodstuffs and the heating process. Further research is needed to optimise cooking procedures to enhance retention of vitamin D. Vitamin D retention should be taken...

  11. Radioactive contaminants in raw materials and foodstuffs of plant origin

    International Nuclear Information System (INIS)

    Stankovicj, S.; Krainchanicj, M.; Stankovicj, A.

    1990-01-01

    The paper concentrates on the results of activity level of radioactive caesium 134 and 137 in the samples of raw materials (barley, oats, soybean, sunflower, pumpkin seed, hops, shreded sugar beet, maize), animal feedstuffs (alfalfa, alfalfa meal, rape, concentrates fed to chickens, pigs or bpvines, dry turnip shreds) and foodstuff of plant origin (lettuce, spinach, cabbage, carrot, celery, cucumber, tomato, olives, sesame). All samples - produced locally on the major part but also including some imported stuff -have been subjected to continuous gamma spectrometry starting with the Chernobyl accident in 1986 through 1989. The highest activity of caesium was recorded in the samples of animal feedstuffs (alfalfa, alfalfa meal, rape) in the years 1986 and 1987. In time, however, the activity tends to drop considerably. (author) 4 refs.; 3 tabs

  12. Oral fluid drug tests: effects of adulterants and foodstuffs.

    Science.gov (United States)

    Wong, Raphael C; Tran, Minhchau; Tung, James K

    2005-06-10

    An on-site oral fluid drug screen, Oratect, was used to investigate the effects of adulterants and foodstuffs on oral fluid test results. Common foods, beverages, food ingredients, cosmetics and hygienic products were demonstrated not to cause false positive results when tested 30 min after their consumption. Evaluations of two commercial oral fluid adulterants, "Clear Choice Fizzy Flush" and "Test'in Spit n Kleen Mouthwash" suggest their mechanism of action is the clearing of residual drugs of abuse compounds through rinsing of the oral cavity. They do not directly destroy the drug compounds or change the pH of the oral fluid. It is also suggested that a common mouthwash would perform similar action.

  13. Quality Model of Foodstuff in a Refrigerated Display Cabinet

    DEFF Research Database (Denmark)

    Cai, Junping; Risum, Jørgen; Thybo, Claus

    2006-01-01

    Commercial refrigerating systems need to be defrosted regularly to maintain a satisfactory performance. When defrosting the evaporator coil, the air temperature inside the display cabinet will increase, and float outside the normal temperature range for a period of time, the question is what...... happens to the food inside during this period, when we look at the quality factor? This paper discusses quality model of foodstuff, different scenarios of defrost scheme are simulated, questions such as how the defrost temperature and duration influence the food temperature, thus the food quality, as well...... as what is the optimal defrost scheme from food quality point of view are answered. This will serve as a prerequisite of designing of optimal control scheme for the commercial refrigeration system, aiming at optimizing a weighed cost function of both food quality and overall energy consumption of system....

  14. Radioactivity levels of basic foodstuffs and dose estimates in Sudan

    International Nuclear Information System (INIS)

    Hemada, H. E. F.

    2009-03-01

    In this work a comprehensive study was carried out for the determination of different radionuclides activities in foodstuff consumed and evaluation of dose levels in different food stuffs were collected from eight States in Sudan (cereals, vegetables, meat, fruits, milk, and fermented milk, baby milk, cans, spices, additives, others). The concentrations of different radionuclides in the food samples were determined by gamma spectrometry using an HPGe detector. Radionuclides observed include: Bi-212, Bi-214, Cs-134, Cs-137, K-40, Pb-212, Pb-214, Ra-224, Ra-226, Th-228, Ac-228, TI-208, Th-232, and U-238. The activity concentration of these radionuclides were found in the following ranges: 0.51 - 19.42 Bq/Kg, 0.47 - 12.13 Bq/kg, 0.5 - 1.29 Bq/kg, 0.001 - 3.41 Bq/kg, 19.25 -2521.82 Bq/kg, 0.08 - 6.84 Bq/kg, 0.02 - 6.87 Bq/kg, 6.08 - 32.02 Bq/kg, 0.03 - 21. 53 Bq/kg, 0.92 - 26.77 Bq/kg, 0.91 - 1200 Bq/kg, 0.14 - 2.58 Bq/Kg, 0.03 - 9.65 Bq/kg, 0.03 - 9.65 Bq/kg and 0.82 - 5.27 Bq/kg respectively. High concentrations were typically found in portulaca, the lowest concentrations were found in barley and bread additives. The annual effective dose due to the different foodstuff estimated was found to be 2.78±0.44 mSv/y and 1.18±mSv/y for age categories 7-12 y and> 17y respectively. (Author)

  15. Concentration of caesium isotopes in foodstuffs in Poland

    International Nuclear Information System (INIS)

    Grabowski, D.; Rubel, B.; Muszynski, W.; Kurowski, W.; Swietochowska, J.; Smagala, G.

    2000-01-01

    One of the sources of the radioactive doses obtained by people resulting from the radiological contamination of the environment, is the transfer of radionuclides to the organism via ingestion. Radioactive isotopes in foodstuffs appear as a result of nuclear activities on the globe, mainly because of nuclear explosion and, recently, after the Chernobyl accident. Since the early sixties the network of Service for Measurement of Radioactive Contamination in Poland systematically controlled all kinds of important food products. Radiochemical methods and gamma spectrometry has been used to determination the activity of radioactive isotopes. This contribution reports of the determination of 134 Cs and 137 Cs concentration in milk, meat, vegetables, fruits, cereals and 'forest products' during period 1985-1999. In 1985 the average 137 Cs level was below 1 Bq/kg (except forest products). Moreover, no regional differences were observed the whole territory of Poland. After the Chernobyl accident situation changed completely. Average activity of 137 Cs in milk was 25 Bq/l in May 1986, 20-25 Bq/kg in beef and 10-15 Bq/kg in pork (summer months). Also fruit picked up in June and July was contaminated, mainly currents. The contamination of vegetables was less important. The activity of cesium isotopes in forest mushrooms and wild game were much higher than in other tested foodstuffs. From the 1987 level of radioactive contamination was decreasing gradually. In 1999 the activity of 137 Cs of vegetables, cereals, fruit was on level as it has been in 1985 as for meat and milk it is higher. Level of radiocesium in 'forest products' is still high. The average annual effective dose from ingestion of radiocesium was on level 0.088 mSv in 1986 and 0.006 mSv in 1999. (author)

  16. Stress corrosion cracking of Inconel 600 in aqueous solutions at elevated temperature. Pt. II. Effects of chloride and sulphate ions on the electrochemical behaviour of Inconel 600

    International Nuclear Information System (INIS)

    Ashour, E.A.; Schneider, F.; Mummert, K.

    1997-01-01

    For pt.I see ibid., p.151-6, 1997. The influencing effects of temperature, potential and electrolyte composition on the electrochemical behaviour of Inconel 600 in aqueous solutions are presented. Considering these effects the connection between the data have been obtained from chemo-mechanical fracture investigation on CT-samples in Part I of this paper and pitting corrosion are discussed. The results have shown that chloride ions depassivate the surfaces of cracks locally and hinder the formation of a new protective oxide layer on the fracture surfaces. Furthermore, chloride promotes the dissolution of metal and initiates the cracking, respectively. The resulting crevice corrosion promotes an increase of hydrogen absorption by the metal. The increase of the hydrogen content of the metal influences the mechanical fracture behaviour. Contrary, sulphate ions inhibit the initiation of corrosion mainly due to a hinderance of chloride ions adsorption on active sites of the fracture surfaces. The initiation of localized corrosion in the crevice region may be stimulated by chromate ions formed by oxidation of chromium from the oxide layer or the base metal in oxygen containing solutions. (orig.)

  17. RACLETTE: a model for evaluating the thermal response of plasma facing components to slow high power plasma transients. Pt. II. Analysis of ITER plasma facing components

    International Nuclear Information System (INIS)

    Federici, G.; Raffray, A.R.

    1997-01-01

    For pt.I see ibid., p.85-100, 1997. The transient thermal model RACLETTE (acronym of Rate Analysis Code for pLasma Energy Transfer Transient Evaluation) described in part I of this paper is applied here to analyse the heat transfer and erosion effects of various slow (100 ms-10 s) high power energy transients on the actively cooled plasma facing components (PFCs) of the International Thermonuclear Experimental Reactor (ITER). These have a strong bearing on the PFC design and need careful analysis. The relevant parameters affecting the heat transfer during the plasma excursions are established. The temperature variation with time and space is evaluated together with the extent of vaporisation and melting (the latter only for metals) for the different candidate armour materials considered for the design (i.e., Be for the primary first wall, Be and CFCs for the limiter, Be, W, and CFCs for the divertor plates) and including for certain cases low-density vapour shielding effects. The critical heat flux, the change of the coolant parameters and the possible severe degradation of the coolant heat removal capability that could result under certain conditions during these transients, for example for the limiter, are also evaluated. Based on the results, the design implications on the heat removal performance and erosion damage of the various ITER PFCs are critically discussed and some recommendations are made for the selection of the most adequate protection materials and optimum armour thickness. (orig.)

  18. A Learning Based Precool Algorithm for Utilization of Foodstuff as Thermal Energy Storage

    DEFF Research Database (Denmark)

    Vinther, Kasper; Rasmussen, Henrik; Izadi-Zamanabadi, Roozbeh

    2013-01-01

    Maintaining foodstuff within predefined temperature thresholds is important due to legislative requirements and to sustain high foodstuff quality. This is achieved using a refrigeration system. However, these systems might not be dimensioned for hot summer days or possible component performance...... degradation. A learning based algorithm is proposed in this paper, which precools the foodstuff in an anticipatory manner based on the saturation level in the system on recent days. The method is evaluated using a simulation model of a supermarket refrigeration system and simulations show that thermal energy...

  19. Determination of toxic elements in foodstuffs from local market in Jakarta

    International Nuclear Information System (INIS)

    Surtipanti Sadjirun; Suwirma Safri; Endang Rosadi; Yumiarti; Yune Mellawati; Saifudin Simon; Minarni Ak

    1988-01-01

    The main foodstuffs of Indonesian people are, rice, bean, corn, wheat, vegetables, fruits, meat, fish, milk, tea, and coffee. The problem of the control of toxic elements in foodstuffs have not been carried out such as many countries, so there is no established maximum permissible concentration in the Indonesian national legislation, and that is why Indonesia participates in the Co-ordinated Research Program organized by the International Atomic Energy Agency. This program will allow exchange of experience among the participants, especially in the determination of low level toxic elements in foodstuffs using nuclear techniques. 6 refs, 9 tabs

  20. Functional toxicity and tolerance patterns of bioavailable Pd(II), Pt(II), and Rh(III) on suspended Saccharomyces cerevisiae cells assayed in tandem by a respirometric biosensor

    Energy Technology Data Exchange (ETDEWEB)

    Frazzoli, Chiara; Mantovani, Alberto [Istituto Superiore di Sanita, Department of Food Safety and Veterinary Public Health and WHO/FAO Collaborating Centre for Veterinary Public Health, Rome (Italy); Dragone, Roberto [Consiglio Nazionale delle Ricerche, Institute for Complex Systems, Rome (Italy); Massimi, Cristiana [Istituto Superiore di Sanita, Department of Food Safety and Veterinary Public Health and WHO/FAO Collaborating Centre for Veterinary Public Health, Rome (Italy); University ' La Sapienza' , Department of Chemistry, Rome (Italy); Campanella, Luigi [University ' La Sapienza' , Department of Chemistry, Rome (Italy)

    2007-12-15

    Toxicological implications of exposure to bioavailable platinum group metals, here Pd, Pt, and Rh, are still to be clarified. This study obtained by a biosensor-based method preliminary information on potential effects on cellular metabolism as well as on possible tolerance mechanisms. Aerobic respiration was taken as the toxicological end point to perform tandem tests, namely functional toxicity test and tolerance test. Cells were suspended in the absence of essential constituents for growth. The dose-response curves obtained by exposure (2 h) to the metals (nanogram per gram range) suggested the same mechanisms of action, with Rh showing the greatest curve steepness and the lowest EC{sub 50} value. Conservative (95% lower confidence interval) EC{sub 10} values were 187, 85 and 51 ng g{sup -1} for Pt, Pd, and Rh respectively. Tolerance patterns were tested during the same runs. The full tolerance obtained after 12 h of exposure to each metal suggested mitochondrial inhibition of aerobic respiration as a target effect. The hazard rating of the metals in the tolerance test changed in the Rh EC{sub 50} range, where Rh showed the lowest toxicity. The observed tolerance might suggest a protective mechanism such as metallothionein induction at concentrations around the EC{sub 50} values. The performance of the bioassay was satisfactory, in terms of the limit of detection, repeatability, reproducibility, roboustness, sensibility, and stability; the method's critical uncertainty sources were identified for improvements. (orig.)

  1. Synthesis of unsymmetric bipyridine-Pt(II) -alkynyl complexes through post-click reaction with emission enhancement characteristics and their applications as phosphorescent organic light-emitting diodes.

    Science.gov (United States)

    Li, Yongguang; Tsang, Daniel Ping-Kuen; Chan, Carmen Ka-Man; Wong, Keith Man-Chung; Chan, Mei-Yee; Yam, Vivian Wing-Wah

    2014-10-13

    Two unsymmetric bipyridine-platinum(II)-alkynyl complexes have been synthesised by a post-click reaction. These metal complexes are found to exhibit emission enhancement properties. The photoluminescence quantum yield can be significantly increased from 0.03 in solution to 0.72 in solid-state thin films. Efficient solution-processable organic light-emitting diodes have been fabricated by utilizing these complexes as phosphorescent dopants. A high external quantum efficiency of up to 5.8% has been achieved. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Translocation of uranium from water to foodstuff while cooking

    Energy Technology Data Exchange (ETDEWEB)

    Krishnapriya, K.C.; Baksi, Ananya; Chaudhari, Swathi; Gupta, Soujit Sen; Pradeep, T.

    2015-10-30

    Highlights: • Rice can efficiently uptake uranium from water contaminated with uranyl nitrate hexahydrate (UO{sub 2}(NO{sub 3}) 2.6 H{sub 2}O), while cooking. • Unusual uranium uptake to the extent of about 1000 ppm is observed when rice is cooked in highly concentrated uranium contaminated water (1240 ppm). • Nature of interaction of uranium with carbohydrates is probed using small monosaccharides like glucose and mannose. • Electrospray ionization mass spectrometry showed UO{sub 2}{sup 2+} to be the most stable species in water in such solutions which can form complexes with sugars. • The species (UO{sub 2}{sup 2+}) is also observed in the case of water exposed to the common mineral, uranium oxide (UO{sub 2}) and similar type of complexation is observed with sugars. - Abstract: The present work report the unusual uranium uptake by foodstuff, especially those rich in carbohydrates like rice when they are cooked in water, contaminated with uranium. The major staple diet in South Asia, rice, was chosen to study its interaction with UO{sub 2}{sup 2+}, the active uranium species in water, using inductively coupled plasma mass spectrometry. Highest uptake limit was checked by cooking rice at very high uranium concentration and it was found to be good scavenger of uranium. To gain insight into the mechanism of uptake, direct interaction of UO{sub 2}{sup 2+} with monosaccharides was also studied, using electrospray ionization mass spectrometry taking mannose as a model. The studies have been done with dissolved uranium salt, uranyl nitrate hexahydrate (UO{sub 2}(NO{sub 3}){sub 2}·6H{sub 2}O), as well as the leachate of a stable oxide of uranium, UO{sub 2}(s), both of which exist as UO{sub 2}{sup 2+} in water. Among the eight different rice varieties investigated, Karnataka Ponni showed the maximum uranium uptake whereas unpolished Basmati rice showed the minimum. Interaction with other foodstuffs (potato, carrot, peas, kidney beans and lentils) with and

  3. Kinetics of the metal exchange in Bis(salicylaldiminato)-copper(II)-complexes. Pt. 3. Influence of the electron density at the donor nitrogen

    Energy Technology Data Exchange (ETDEWEB)

    Winkler, H; Wannowius, K J; Elias, H [Technische Hochschule Darmstadt (Germany, F.R.). Fachbereich Anorganische Chemie und Kernchemie

    1977-01-01

    The kinetics of isotopic copper exchange between various (bis-(N-phenyl-salicylaldiminato))copper(II)complexes (= CuL/sub 2/) and mono(pyridine)copper(II)acetate (= CuAc/sub 2/py) was studied in dichloromethane as solvent in the temperature range -20 to +20/sup 0/C. The exchange follows the experimental rate law (5), which is simplified in certain cases due to k''((CuAc/sub 2/py)/sub 2/)/sup 1///sup 2/ < 1. The variation of substituents X on the salicylaldehyde ring and of substituents Y on the N-phenyl ring leads via Hammett plots to the conclusion that substituent effects become apparent as rate increasing or rate decreasing only in those cases, in which they cause an increase or decrease in electron density at the donor oxygen. Substituents Y in 2-position, and especially in 2.6-position, reduce the rate of exchange with increasing van der Waals radius of Y. The mechanistic implications of the results are discussed. (orig.) 891 HK.

  4. Path integral approach for superintegrable potentials on spaces of non-constant curvature. Pt. 1. Darboux spaces D{sub I} and D{sub II}

    Energy Technology Data Exchange (ETDEWEB)

    Grosche, C. [Hamburg Univ. (Germany). 2. Inst. fuer Theoretische Physik; Pogosyan, G.S. [Joint Inst. of Nuclear Research, Moscow (Russian Federation). Bogoliubov Lab. of Theoretical Physics]|[Guadalajara Univ., Jalisco (Mexico). Dept. de Matematicas CUCEI; Sissakian, A.N. [Joint Inst. of Nuclear Research, Moscow (Russian Federation). Bogoliubov Lab. of Theoretical Physics

    2006-07-15

    In this paper the Feynman path integral technique is applied for superintegrable potentials on two-dimensional spaces of non-constant curvature: these spaces are Darboux spaces D{sub I} and D{sub II}, respectively. On D{sub I} there are three and on D{sub II} foru such potentials, respectively. We are able to evaluate the path integral in most of the separating coordinate systems, leading to expressions for the Green functions, the discrete and continuous wave-functions, and the discrete energy-spectra. In some cases, however, the discrete spectrum cannot be stated explicitly, because it is either determined by a transcendental equation involving parabolic cylinder functions (Darboux space I), or by a higher order polynomial equation. The solutions on D{sub I} in particular show that superintegrable systems are not necessarily degenerate. We can also show how the limiting cases of flat space (Constant curvature zero) and the two-dimensional hyperboloid (constant negative curvature) emerge. (Orig.)

  5. Nuclear techniques for toxic elements in foodstuffs. Report on an IAEA co-ordinated research programme

    International Nuclear Information System (INIS)

    1994-01-01

    The document includes 10 final reports on the IAEA Co-ordinated Research Programme on Nuclear Techniques for Toxic Elements in Foodstuffs. A separate abstract was prepared for each report. Refs, figs and tabs

  6. Contamination of foodstuffs in Styria (Austria) by J-131 and Cs-137

    International Nuclear Information System (INIS)

    Ninaus, W.; Kahr, G.; Oswald, K.; Mueller, H.

    1993-01-01

    Cs-137 activities of various foodstuffs were measured from May to December 1986. Results from different sites are compared. In the particular case of blueberry there is a time series from 1985 to 1992

  7. Nuclear techniques for toxic elements in foodstuffs. Report on an IAEA co-ordinated research programme

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-12-31

    The document includes 10 final reports on the IAEA Co-ordinated Research Programme on Nuclear Techniques for Toxic Elements in Foodstuffs. A separate abstract was prepared for each report. Refs, figs and tabs.

  8. Neutron activation analysis of trace elements in foodstuffs

    International Nuclear Information System (INIS)

    Schelenz, R.; Bayat, I.; Fischer, E.

    1976-05-01

    For the determination of trace elements in foodstuffs with the aid of neutron activation analysis the separation of volatile radionuclides after digestion of the sample is of special interest for radiochemical processing. A distillation procedure was developed to give reproducable results, however optimal conditions were not found for all volatile radionuclides studied. The required selective separation of Br-82 from the distillate was best achieved by the application of an ion-exchange column-chromatography technique. The computer programs for the evaluation of complex gamma spectra have been developed further. The automatic peak search and peak area determination is based on a computer program using the correlation technique and carried out with a mini-computer coupled with a multi-channel gamma spectrometer. The results, which are presented in 3 earlier reports relating to this research program, reveal the advantages and disadvantages of the individual steps of the radiochemical separation scheme. Before neutron activation analysis can be introduced on a routine basis, some aspects of the radiochemical process remain to be tested; these studies will be published in a fourth and final report. (orig.) [de

  9. Stability of vitamin D in foodstuffs during cooking.

    Science.gov (United States)

    Jakobsen, Jette; Knuthsen, Pia

    2014-04-01

    We investigated the retention of vitamin D3 and 25-hydroxyvitamin D3 in eggs, vitamin D3 in margarine, and vitamin D3 and vitamin D2 in bread. Our set-up illustrated the cooking methods usually performed in households i.e. boiling, frying in pan and oven, and baking. All experiments were performed three times independently of one another. The retention of vitamin D compounds in eggs and margarine during heat treatment in an oven for 40 min at normal cooking temperature showed retention at 39-45%, while frying resulted in retention at 82-84%. Boiled eggs were found to have a similar level of retention (86-88%). For bread baked, as recommended in the recipe, the retention of vitamin D3 in rye bread at 69% was lower than the retention in wheat bread at 85%. A similar observation was made for vitamin D2, although the retention was slightly higher, 73% and 89%. No difference between retention of vitamin D3 and 25-hydroxyvitamin D3 in eggs was shown. Cooking may cause detrimental loss of vitamin D, but it depends on the actual foodstuffs and the heating process. Further research is needed to optimise cooking procedures to enhance retention of vitamin D. Vitamin D retention should be taken into account in future calculations of dietary intake of vitamin D. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. Monitoring of radioactivity in imported foodstuffs - experience gained and recommendations

    International Nuclear Information System (INIS)

    Abdul-Fattah, A.F.; Mamoon, A.M.; Abdul-Majid, S.

    1987-01-01

    Saudi Arabia has had a unique experience in radiation monitoring of imported foodstuffs for possible contamination due to the Chernobyl reactor accident. A considerable amount of various food items is imported by Saudi Arabia and much of it comes from European countries. The quantity of imported food items is greatly increased around the time of the Moslem pilgrimage to Holy Mecca. Furthermore, many additional thousands of live animals (mainly sheep and cows) are imported for sacrificing on a certain day for religious reasons. The radiation monitoring of food items at inlets to the county was not done before and a lot of preparatory work and planning had to be done to initiate the monitoring process. The experience gained in this respect might be of value to other developing countries in a similar position. King Abdulaziz Univ. (KAU) was directed by the government in about mid-June 1986 to carry out radiological inspection of food items reaching the Jeddah, Yanbu, and Jizan seaports as well as food arrivals at King Abdulaziz International Airport at Jeddah. The KAU team has met with some difficulties in carrying out its inspection responsibilities. These difficulties are of a general nature and might occur, in a similar inspection process, in other developing countries. The problems can be classified essentially into the two categories discussed: (1) problems of an administrative and management nature, and (2) problems of a technical nature

  11. European and German food legislation facing uncommon foodstuffs.

    Science.gov (United States)

    Grabowski, Nils Th; Klein, Günter; López, Antonio Martínez

    2013-01-01

    In Europe, uncommon foodstuff (UFS, i.e., traditional foods from specific European regions and uncommon ethnic foods from non-EU countries) have been contributing to a diversification of the food supply. E-commerce and specialized retail shops are the main sources for UFS. This article discusses the legal bases for UFS introduction and evaluation. By means of 35 representative UFS, this article analyses the possibilities of trade and veterinary inspection of these products in Germany, comparing European Union and national food legislation with the many idiosyncrasies the UFS presents. Conservatory legislation bans the trade with endangered species (primates, cetaceans, songbirds), but for many other species, this is a complex matter that may ban only subpopulations from trade. Although introduction of legal UFS is regulated (yet complicated), the lack of appropriate definitions, intra-European trade harmonization, and of sufficient scientific knowledge hampers a satisfactory evaluation of many UFSs, for example, reptile meat or terrestrial insects. In these cases, official inspection would only be very basic.

  12. Polonium 210 content in foodstuffs produced in Bulgaria

    International Nuclear Information System (INIS)

    Keslev, D.; Novakova, E.; Boyadzhiev, A.; Kerteva, A.

    1975-01-01

    A study of the content of polonium-210 in a variety of foodstuffs produced in Bulgaria in 1970 revealed peak radionuclide concentration in wheat - 6.7 pCi/kg, followed by prunes - 2.2 pCi/kg, cabbage - 1.86 pCi/kg, peppers - 1.64 pCi/kg. The content of polonium-210 in onions, meat and potatoes was low (0.5, 0.8 and 0.9 pCi/kg accordingly). All other food products studied - milk, bread, beans, eggs, tomatoes, apples, pears, grapes and drinking water - appeared to have approximately equal polonium-210 concentration - from 1.21 to 1.35 pCi/kg. The daily intake of polonium-210 with food and water amounted accordingly to 1.61, 1.79 and 2.08 pCi/kg in preschool children, in school children and in senile individuals. The major part (68 - 82 per cent) of incorporated polonium-210 was eliminated with the stools. In all age groups the amount of polonium-210 removed daily from the body with the excreta corresponded to the intake, i.e. the balance of polonium-210 was in a state of equilibrium. The age factor in all three groups exerted no effect on the radionuclide intake and elimination from the body. (Ch.K.)

  13. High efficiency orange-red phosphorescent organic light emitting diodes based on a Pt(II)-pyridyltriazolate complex from a structure optimized for charge balance and reduced efficiency roll-off

    Energy Technology Data Exchange (ETDEWEB)

    Li, Minghang; Lin, Ming-Te; Shepherd, Nigel D. [Department of Material Science and Engineering, University of North Texas, Denton, Texas (United States); Chen, Wei-Hsuan; McDougald, Roy Jr.; Arvapally, Ravi; Omary, Mohammad [Department of Chemistry, University of North Texas, Denton, Texas (United States)

    2012-01-15

    We report a high power efficiency (PE) of 44.7 {+-} 0.5 lm/W, high external quantum efficiency (EQE) of 19.7 {+-} 0.1% at 500 Cd/m{sup 2}, and efficiency roll-off of only 4% of the peak value at a useful brightness of 1000 Cd/m{sup 2} from orange-red emitting, organic light emitting diodes featuring 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC) as the hole transport layer/electron blocking layer, an emissive layer consisting of 65% bis[3,5-bis(2-pyridyl)-1,2,4-triazolato]platinum(II) (Pt(ptp){sub 2}) doped into 4,4'-bis(carbazol-9-yl)triphenylamine (CBP), and 1,3,5-tris(phenyl-2-benzimidazolyl)-benzene (TPBI) as the electron transport layer (ETL). Based on a comparison of these structures with devices that did not incorporate an electron/exciton blocker and devices featuring N,N'-dicarbazolyl-3,5-benzene (mCP) as the electron/exciton blocking layer, we ascribe the high efficiency and low efficiency roll-off to better charge balance, and enhanced confinement of excitons and the recombination zone to the emissive layer. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Two-equivalent electrochemical reduction of a cyano-complex [TlIII(CN)2]+ and the novel di-nuclear compound [(CN)5PtII-TlIII]0

    International Nuclear Information System (INIS)

    Dolidze, Tina D.; Khoshtariya, Dimitri E.; Behm, Martin; Lindbergh, Goeran; Glaser, Julius

    2005-01-01

    Extending our recent insights in two-electron transfer microscopic mechanisms for a Tl III /Tl I redox system [D.E. Khoshtariya, et al., Inorg. Chem. 41 (2002) 1728], the electrochemical response of glassy carbon electrode in acidified solutions of Tl III (ClO 4 ) 3 containing different concentrations of sodium cyanide has been extensively studied for the first time by use of cyclic voltammetry and the CVSIM curve simulation PC program. The complex [Tl III (CN) 2 ] + has been thoroughly identified electrochemically and shown to display a single well-defined reduction wave (which has no anodic counterpart), ascribed to the two-equivalent process yielding [Tl I (aq)] + . This behavior is similar to that of [Tl III (aq)] 3+ ion in the absence of sodium cyanide, disclosed in the previous work, and is compatible with the quasi-simultaneous yet sequential two-electron transfer pattern (with two reduction waves merged in one), implying the rate-determining first electron transfer step (resulting in the formation of a covalently interacting di-thallium complex as a metastable intermediate), and the fast second electron transfer step. Some preliminary studies of the two-equivalent reduction of directly metal-metal bonded stable compound [(CN) 5 Pt II -Tl III ] 0 has been also performed displaying two reduction waves compatible with a true sequential pattern

  15. Studies with Pt-195M platinum complexes

    International Nuclear Information System (INIS)

    Cole, W.; Wiza, J.; Odenheimer, B.; Wolf, W.; Hoeschele, J.D.; Butler, T.A.; Smyth, R.D.

    1982-01-01

    Cis-diamine-ethylmalonato 195 Pt(II) has been synthesised to investigate its chemotherapeutic potential in cancer and other diseases. It is likely to be less nephrotoxic than the established drug crisplatin. Biodistribution and clearance studies were carried out on Sprague-Dowley rats after intravenous administration of the new drug. (author)

  16. Development of inflatable seals for the rotatable plugs of sodium cooled fast breeder reactors. Pt. II. R and D necessities and development across the world. A review

    International Nuclear Information System (INIS)

    Sinha, Nilay K.; Raj, Baldev

    2013-01-01

    Identification of development areas and their implementation for rotatable plug (RP) inflatable seals of Na cooled, 500 Mw (e) Prototype Fast Breeder Reactor (PFBR) and 40 MW (t) Fast Breeder Test Reactor (FBTR) are described, largely based on a late 1990s survey of cover gas seal development (1950s - early 1990s) which defined a set of shortlisted design options and developmental strategy to minimize effort, cost and time. Comparative study of top shield sealing and evolving FBR designs suggest suitability of inflatable seal as primary barrier in RPs. International experience identified choice and qualification of seal elastomer under synergistic degrading environment of reactor as the prime element of development. The low pressure, non-reinforced, unbeaded, PFBR inflatable seal (made of 50/50 blend of Viton registered GBL 200S/600S) developed for 10 y life provides a unification scheme for nuclear elastomeric sealing based on 5 peroxide cured fluoroelastomer blend formulations, 1 finite element analysis approach, 1 Teflon-like plasma coating technique and 2 manufacturing processes promising significant gains in standardization, economy and safety. Uniqueness was ab initio development in the absence of established industry or readymade supply. R and D necessities for inflatable seals and their development across the world are given closer look in Part II of the review in continuation of Part I. (orig.)

  17. Technological and culinary treatment. Effects on radioactivity levels in foodstuffs

    International Nuclear Information System (INIS)

    Grauby, A.; Miribel, J.

    1989-01-01

    As a result of the radioactive fall-out following the first overground nuclear explosions and the Windscale accident, from the end of the 1950 onwards the various radioelements began to be monitored by means of the food chain. However, few writers were concerned with the decontamination of foodstuffs. During this time the ICRP drew up recommendations which were then included in the basic safety standards of the Euratom Treaty and which are the only representative standards for public safety. The unprocessed raw product has therefore been used as the reference for the assessment of radiological risk for 25 years. In the period immediately after the Chernobyl accident, the differing levels of contamination of agricultural produce in the various countries led governments to adopt conservation measures by setting radioactivity tolerance levels for both the raw product and the processed product. These levels, which were based on economic and political considerations, caused problems for the marketing of certain products. Although these difficulties were limited by the relative unimportance of the local economy in the stricken area, it cannot be ruled out that, after a future accident, the economy of a whole region might be destroyed because of a ban on marketing products containing levels of contamination considered to be too high by market standards. Countermeasures must therefore be taken. Some experiments had previously been conducted in this area, but in the last two years many more tests have been carried out and new programmes launched. It therefore became necessary to organize a seminar on this subject in order to take stock of the work carried out and to draw up various kinds of recommendation. The latter include: - the provision of incentives for increased cooperation between the food processing industry and those responsible for nuclear safety: - the establishment of decision-making criteria for the authorities; - and lastly the identification of areas at risk

  18. Trace radioactive measurement in foodstuffs using high purity germanium detector

    International Nuclear Information System (INIS)

    Morco, Ryan P.; Racho, Joseph Michael D.; Castaneda, Soledad S.; Almoneda, Rosalina V.; Pabroa, Preciosa Corazon B.; Sucgang, Raymond J.

    2010-01-01

    Trace radioactivity in food has been seriously considered sources of potential harm after the accidental radioactive releases in the last decades which led to contamination of the food chain. Countermeasures are being used to reduce the radiological health risk to the population and to ensure that public safety and international commitments are met. Investigation of radioactive traces in foods was carried out by gamma-ray spectrometry. The radionuclides being measured were fission products 1 37Cs and 1 34Cs and naturally occurring 4 0Κ. Gamma-ray measurements were performed using a hybrid gamma-ray counting system with coaxial p-type Tennelec High Purity Germanium (HPGe) detector with relative efficiency of 18.4%. Channels were calibrated to energies using a standard check source with 1 37Cs and 6 0Co present. Self-shielding within samples was taken into account by comparing directly with reference standards of similar matrix and geometry. Efficiencies of radionuclides of interests were accounted in calculating the activity concentrations in the samples. Efficiency calibration curve was generated using an in-house validated program called FINDPEAK, a least-square method that fits a polynomial up to sixth-order of equation. Lower Limits of Detection (LLD) obtained for both 1 37Cs and 1 34Cs ranges from 1-6 Bq/Kg depending on the sample matrix. In the last five years, there have been no foodstuffs analyzed exceeded the local and international regulatory limit of 1000Bq/Kg for the summed activities of 1 37Cs and 1 34Cs. (author)

  19. Radioactivity monitoring and import regulation of the contaminated foodstuffs in Japan following the Chernobyl nuclear power plant accident

    International Nuclear Information System (INIS)

    Izumo, Yoshiro

    1997-01-01

    Radioactivity monitoring and import regulation of the contaminated foodstuffs executed by Minstry of Health and Welfare following the Chernobyl nuclear plant accident were reviewed as follows; 1) background of socio-psychological effects and environmental radioactivity leading to the regulation (to may 3, 1986); 2) intial intervention for imported foodstuffs in Japan (may 8, '86), and 3) in european countries (to may 31, '86), immediately after the Accident, respectively; 4) determination of the interim driven intervention level for radionuclides in imported foodstuffs (( 134 Cs + 137 Cs): 370 Bq/Kg) and activation of the monitoring, 5) outline of the monitoring with elapsed time, number of foodstuffs monitored, number of foodstuffs exceeded radioactivity of the intervention level and re-exported; 6) guideline in international trade of radioactive contaminated foodstuffs adopted by CODEX Alimentarius Commission (FAO/WHO) and the intervention level recommended by ICRP following the Accident; 7) discussion for problems and scopes in future based on the results of monitoring. As the results, a number of imported foodstuffs (about 75,000 samples at present) has been monitored, 55 samples exceeding the interim intervention level were re-exported to each export's country, and socio-psychological doubts for radioactive contamination of imported foodstuffs have been dispersed. In addition, problems for several factors based on calculation of the interim intervention level, radioactivity level of foodstuffs exceeding about 50 Bq/Kg as radiocesiums and necessity of monitoring for the other radionuclides in foods except radiocesiums were also discussed. (author)

  20. Radioactivity monitoring and import regulation of the contaminated foodstuffs in Japan following the Chernobyl nuclear power plant accident

    Energy Technology Data Exchange (ETDEWEB)

    Izumo, Yoshiro [Institute of Public Health, Tokyo (Japan)

    1997-03-01

    Radioactivity monitoring and import regulation of the contaminated foodstuffs executed by Minstry of Health and Welfare following the Chernobyl nuclear plant accident were reviewed as follows; (1) background of socio-psychological effects and environmental radioactivity leading to the regulation (to may 3, 1986); (2) intial intervention for imported foodstuffs in Japan (may 8, `86), and (3) in european countries (to may 31, `86), immediately after the Accident, respectively; (4) determination of the interim driven intervention level for radionuclides in imported foodstuffs (({sup 134}Cs + {sup 137}Cs): 370 Bq/Kg) and activation of the monitoring, (5) outline of the monitoring with elapsed time, number of foodstuffs monitored, number of foodstuffs exceeded radioactivity of the intervention level and re-exported; (6) guideline in international trade of radioactive contaminated foodstuffs adopted by CODEX Alimentarius Commission (FAO/WHO) and the intervention level recommended by ICRP following the Accident; (7) discussion for problems and scopes in future based on the results of monitoring. As the results, a number of imported foodstuffs (about 75,000 samples at present) has been monitored, 55 samples exceeding the interim intervention level were re-exported to each export`s country, and socio-psychological doubts for radioactive contamination of imported foodstuffs have been dispersed. In addition, problems for several factors based on calculation of the interim intervention level, radioactivity level of foodstuffs exceeding about 50 Bq/Kg as radiocesiums and necessity of monitoring for the other radionuclides in foods except radiocesiums were also discussed. (author)

  1. Dispersive liquid-phase microextraction with solidification of floating organic droplet coupled with high-performance liquid chromatography for the determination of Sudan dyes in foodstuffs and water samples.

    Science.gov (United States)

    Chen, Bo; Huang, Yuming

    2014-06-25

    Dispersive liquid-phase microextraction with solidification of floating organic drop (SFO-DLPME) is one of the most interesting sample preparation techniques developed in recent years. In this paper, a new, rapid, and efficient SFO-DLPME coupled with high-performance liquid chromatography (HPLC) was established for the extraction and sensitive detection of banned Sudan dyes, namely, Sudan I, Sudan II, Sudan III, and Sudan IV, in foodstuff and water samples. Various factors, such as the type and volume of extractants and dispersants, pH and volume of sample solution, extraction time and temperature, ion strength, and humic acid concentration, were investigated and optimized to achieve optimal extraction of Sudan dyes in one single step. After optimization of extraction conditions using 1-dodecanol as an extractant and ethanol as a dispersant, the developed procedure was applied for extraction of the target Sudan dyes from 2 g of food samples and 10 mL of the spiked water samples. Under the optimized conditions, all Sudan dyes could be easily extracted by the proposed SFO-DLPME method. Limits of detection of the four Sudan dyes obtained were 0.10-0.20 ng g(-1) and 0.03 μg L(-1) when 2 g of foodstuff samples and 10 mL of water samples were adopted, respectively. The inter- and intraday reproducibilities were below 4.8% for analysis of Sudan dyes in foodstuffs. The method was satisfactorily used for the detection of Sudan dyes, and the recoveries of the target for the spiked foodstuff and water samples ranged from 92.6 to 106.6% and from 91.1 to 108.6%, respectively. These results indicated that the proposed method is simple, rapid, sensitive, and suitable for the pre-concentration and detection of the target dyes in foodstuff samples.

  2. Health safety aspects of foodstuffs intented for phenylketonurics

    Directory of Open Access Journals (Sweden)

    Stanislava Matejová

    2015-05-01

    Full Text Available Phenylketonuria is a rare metabolic disorder that occurs due to the lack of liver enzyme phenylalanine hydroxylase. Untreated it leads to mental retardation, delayed development of speech, microcephaly, epilepsy, behavioral problems etc. Its treatment consists of strict diet, very low in phenylalanine content. The aim of this study was to determine the health safety and suitability of 17 selected foods labeled as „low in protein" respectively „foods low in phenylalanine". Analyses were focused on their phenylalanine content and aminoacid representation. The other aim was to compare phenylalanine measured with the content declared by the producers on their label. By product origin, the largest amount of foodstuffs originated from Poland (59%, followed by Germany (23% and equal representation (6% had Slovakia, Hungary and Sweden. Automatic analyzer AAA 400, using ion exchange chromatography, analyzed the samples. The lowest determined phenylalanine content was 1 mg.100g-1 (in rubber candy and the highest 299 mg.100g-1 (in paté. Powdered egg alternative was monitored as the second highest source of phenylalanine. Phenylalanine content in the monitored foods ranged from 1 to 299.6 mg. 100 g-1 respectively, and increased in the following order: Gum candies (1 mg.100g-1 < Cherry jelly (1.4 mg. 100g-1 < Flour (5.8 mg.100g-1 < Flour (5.9 mg.100g-1 < Spaghetti (8.7 mg.100g-1 < Pasta (9.9 mg.100g-1 < Waffle (14.2 mg.100g-1 < Salty sticks (23.8 mg.100g-1 < Chocolate (24.1 mg.100g-1 < Bread (26 mg.100g-1 < Breadcrumbs (27.1 mg.100g-1 < Sticks with salt (30.3 mg.100g-1 < Ice Cornets (30.8 mg.100g-1 < Walnut cookie (37.2 mg.100g-1 < Instant soup with noodles (46.1 mg.100g-1 < Powdered egg alternative (58 mg.100g-1 < Pate (299.6 mg.100g-1. Only seven products of 17 observed showed low phenylalanine content, less than 20 mg.100g-1.

  3. Reaction of cyanide with Pt-nucleobase complexes: preparative, spectroscopic, and structural studies. Unexpected stability of Pt-thymine and Pt-uracil complexes

    International Nuclear Information System (INIS)

    Raudaschl-Sieber, G.; Lippert, B.

    1985-01-01

    In order to improve the understanding of the nature of the strongly bound cisplatin on DNA, the reactivity of a large number of complexes of cis-(NH 3 ) 2 Pt/sup II/ with the model nucleobases, 9-ethylguanine, 9-methyladenine, 1-methylcytisine, 1-methylthymine, and i-methyluracil, toward a large excess of cyanide was studied. The behavior of Pt-nucleobase complexes toward CN - is compared with that of simple Pt-amine complexes, and reactions of thiourea with two selected nucleobase complexes is reported. The relevance of these findings with respect to substitution reactions of Pt-nucleobase complexes and the nature of the tightly DNA-bound Pt, which cannot be removed by excess KCN, is discussed

  4. PT and INR Test

    Science.gov (United States)

    ... Plasma Free Metanephrines Platelet Count Platelet Function Tests Pleural Fluid Analysis PML-RARA Porphyrin Tests Potassium Prealbumin ... and vitamin K (either in a multivitamin or liquid nutrition supplement) may decrease PT. Certain foods, such ...

  5. Rate setting and regulatory control of the radionuclides content in foodstuffs

    International Nuclear Information System (INIS)

    Shandala, N. K.; Savskin, M. N.; Petukhova, E. V.; Novikova, N. Y.; Titov, A. V.

    2004-01-01

    The concept of rate setting, standardisation and regulatory control of the radionuclides content in foodstuffs consists in the following: ? the normative standards concern to 90Sr and 137Cs as biologically significant radionuclides; ? the internal exposure dose from ingestion intake of radionuclides with food should not exceed meaning of 1 mSv a-1 which is the intervention exception level concerning trading foodstuffs; ? for few consumed foodstuffs (wild berries, mushrooms, teas) is established, that the dose caused by their consumption is outside of dose limits of 1 mSv a-1 and it should not exceed 1 % for each product; ? the nutrition structure of population including seven basic components of a diet (bread and grain products, dairy products, potatoes, vegetables, meat, fish, fruit and berries) is taken into account as a source of ingestion intake of the radionuclides; ? The conformity to the established standard is determined on a parameter ?f the summary contents of 90Sr and 137Cs in foodstuff. With the purpose of the operative control of an internal exposure of population the permissible levels of specific activity of 90Sr and 137Cs in more than 120 kinds of foodstuff were developed. These standards are obligatory in Russia for domestic and imported foodstuffs. So, permissible levels of specific activity of 90Sr and 137Cs in bread make, accordingly, 20 and 40 Bq kg-1; in milk - 25 and 100 Bq kg-1; in meat - 50 and 160 Bq kg-1; in potatoes and vegetables - 40 and 120 Bq kg-1. Monitoring of contamination of foodstuffs by 137Cs and 90Sr is one of the basic measures on maintenance of radiation safety of population in Russia. State system of sanitary-epidemiological control carries out constant supervision over the content of the radionuclides in food production. By the carried out researches was shown that true levels of the contents of 90Sr or 137Cs in the main foodstuffs in territory of Russia, except for the territories, injures of the radiation accidents, make

  6. Food industry workers' attitudes on the importance of factors affecting foodstuff quality managament

    Directory of Open Access Journals (Sweden)

    Antić Zorana

    2015-01-01

    Full Text Available The food industry is faced with several challenges at the same time: to supply safe and affordable foodstuff in sufficient quantity; to provide products in conditions where demand surpasses the human population growth; to operate in circumstances of ever-increasing competition; to protect the environment and respond to the population's public health concerns. An organization's success depends on the knowledge, skills, creativity and motivation of the company's workers and partners. Focus on its employees enables a company's development and improvement, whereas business ethics ensures public health and safety protection, environmental protection and life quality improvement. The company management's responsibility lies foremost in education, worker training and development, thus enabling a direct and indirect influence on the foodstuff quality and satisfying consumer requests in terms of foodstuff quality characteristics.

  7. Revision of criteria for foodstuffs control following a nuclear or radiological emergency

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang Hyun; Lee, Young Min; Jeong, Seung Young [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2015-10-15

    GAL(generic action level)s were derived using cost-benefit methods. But the factors used to derive GALs, such as Gross National Product (GNP) and cost of foodstuff, have been changed for last 10 years. Moreover the standards did not consider exposure situation change from emergency exposure to existing exposure situation. In this study, two ways to revise existing standards for foodstuff control were considered; 1st, revision of GAL, 2nd, newly derived reference level. In this study, two methods to revise food control criteria following nuclear emergency were suggested. GAL based on recent GNI and cost of foodstuff would be revised and decreased up to 30 % than existing criteria. DRLs reflecting exposure situation and consumption pattern were smaller than existing criteria for group 1 nuclides. The approach considered in the study would be applied to set up domestic criteria for food control during and following nuclear or radiological emergency.

  8. Revision of criteria for foodstuffs control following a nuclear or radiological emergency

    International Nuclear Information System (INIS)

    Park, Sang Hyun; Lee, Young Min; Jeong, Seung Young

    2015-01-01

    GAL(generic action level)s were derived using cost-benefit methods. But the factors used to derive GALs, such as Gross National Product (GNP) and cost of foodstuff, have been changed for last 10 years. Moreover the standards did not consider exposure situation change from emergency exposure to existing exposure situation. In this study, two ways to revise existing standards for foodstuff control were considered; 1st, revision of GAL, 2nd, newly derived reference level. In this study, two methods to revise food control criteria following nuclear emergency were suggested. GAL based on recent GNI and cost of foodstuff would be revised and decreased up to 30 % than existing criteria. DRLs reflecting exposure situation and consumption pattern were smaller than existing criteria for group 1 nuclides. The approach considered in the study would be applied to set up domestic criteria for food control during and following nuclear or radiological emergency

  9. Anomalous transport from holography. Pt. II

    International Nuclear Information System (INIS)

    Bu, Yanyan; Sharon, Amir; Lublinsky, Michael

    2017-01-01

    This is a second study of chiral anomaly-induced transport within a holographic model consisting of anomalous U(1)_V x U(1)_A Maxwell theory in Schwarzschild-AdS_5 spacetime. In the first part, chiral magnetic/separation effects (CME/CSE) are considered in the presence of a static spatially inhomogeneous external magnetic field. Gradient corrections to CME/CSE are analytically evaluated up to third order in the derivative expansion. Some of the third order gradient corrections lead to an anomaly-induced negative B"2-correction to the diffusion constant. We also find modifications to the chiral magnetic wave nonlinear in B. In the second part, we focus on the experimentally interesting case of the axial chemical potential being induced dynamically by a constant magnetic and time-dependent electric fields. Constitutive relations for the vector/axial currents are computed employing two different approximations: (a) derivative expansion (up to third order) but fully nonlinear in the external fields, and (b) weak electric field limit but resuming all orders in the derivative expansion. A non-vanishing nonlinear axial current (CSE) is found in the first case. The dependence on magnetic field and frequency of linear transport coefficient functions is explored in the second. (orig.)

  10. Anomalous transport from holography. Pt. II

    Energy Technology Data Exchange (ETDEWEB)

    Bu, Yanyan; Sharon, Amir [Ben-Gurion University of the Negev, Department of Physics, Beersheba (Israel); Lublinsky, Michael [Ben-Gurion University of the Negev, Department of Physics, Beersheba (Israel); University of Connecticut, Physics Department, Storrs, CT (United States)

    2017-03-15

    This is a second study of chiral anomaly-induced transport within a holographic model consisting of anomalous U(1){sub V} x U(1){sub A} Maxwell theory in Schwarzschild-AdS{sub 5} spacetime. In the first part, chiral magnetic/separation effects (CME/CSE) are considered in the presence of a static spatially inhomogeneous external magnetic field. Gradient corrections to CME/CSE are analytically evaluated up to third order in the derivative expansion. Some of the third order gradient corrections lead to an anomaly-induced negative B{sup 2}-correction to the diffusion constant. We also find modifications to the chiral magnetic wave nonlinear in B. In the second part, we focus on the experimentally interesting case of the axial chemical potential being induced dynamically by a constant magnetic and time-dependent electric fields. Constitutive relations for the vector/axial currents are computed employing two different approximations: (a) derivative expansion (up to third order) but fully nonlinear in the external fields, and (b) weak electric field limit but resuming all orders in the derivative expansion. A non-vanishing nonlinear axial current (CSE) is found in the first case. The dependence on magnetic field and frequency of linear transport coefficient functions is explored in the second. (orig.)

  11. [Actual vitamin and main foodstuffs consumption by recovered patients suffered from hemorrhagic fever with renal syndrome].

    Science.gov (United States)

    Kasanova, G M; Tutel'ian, A V

    2011-01-01

    Actual consumption of vitamins A, E, beta-carotene, ascorbic acid, thiamin, pyridoxine and main foodstuffs by recovered patients suffered from hemorrhagic fever with renal syndrome has been given. Frequency analysis of foodstuffs consumption was used to study actual nourishment of recovered patients. Surplus consumption of fat mainly due to the use of saturated fatty acids, deficiency of poly unsaturated fatty acids, surplus sugar consumption and predominance of proteins of animal origin over proteins of vegetable origin in ration has been revealed. Deficiency of water soluble vitamins equals to 41,6-78,7% of all examined patients, deficiency of fat water soluble vitamins is lower (21,4-38,3%).

  12. An investigation of the genetic toxicology of irradiated foodstuffs using short-term systems

    International Nuclear Information System (INIS)

    Phillips, B.J.; Kranz, E.; Elias, P.S.; Muenzner, R.

    1980-01-01

    The genetic toxicology of irradiated foodstuffs has been investigated by the use of a battery of short-term tests for genetic damage. Appropriate methods are discussed for the preparation of food samples for testing by techniques involving micro-organisms and mammalian cells in culture. A new method of sample preparation by enzymatic digestion in vitro is described and its use in the testing of three irradiated foodstuffs by the Salmonella typhimurium reverse mutation test is reported. The results of the mutation tests provide further evidence of the lack of genetic toxicity of irradiated foods. (author)

  13. Effect of plant cultivation methods on content of major and trace elements in foodstuffs and retention in rats

    DEFF Research Database (Denmark)

    Kristensen, Mette; Østergaard, Lars F.; Halekoh, Ulrich

    2008-01-01

    major and trace element contents of dried foodstuffs (carrots, kale, peas, potatoes and apples) grown in two consecutive years, as well as mineral retention determined in 36 rats (second generation in a multi-generation study) fed diets based on these foodstuffs from one year. RESULTS: Overall...

  14. The removal of radionuclides from foodstuffs during technological treatment and culinary processing

    International Nuclear Information System (INIS)

    Perepelyatnikova, L.V.; Lazarev, N.M.; Ivanova, T.N.; Fedin, F.A.; Long, S.; Pollard, D.

    1996-01-01

    Comparative data on the efficiency of industrial and domestic processing techniques of plant and animal products, which reduce radionuclides content foodstuffs, are summarized. Methods, which provide the greatest decrease of radionuclides content in the final products with minimum losses of nutritional value, were identified

  15. Some comments on the use of TL techniques for the determination of doses in irradiated foodstuff

    International Nuclear Information System (INIS)

    Delgado, A.

    1991-01-01

    The purpose of this communication is to present the advantages derived from the use of advanced TL evaluation methods based on the numerical analysis of the glow curves. Due to close similarities with some dosimetric applications, it can be assumed that these advantages will also be relevant when applied to characterize irradiated foodstuff

  16. 90Sr and 137Cs determination in milk and foodstuff samples in North and Middle Moravia

    International Nuclear Information System (INIS)

    Bartuskova, M.; Lusnak, J.; Rada, J.; Beckova, V.

    2008-01-01

    Activities of radionuclides Sr-90 and Cs-137 in milk and parts of foodstuff have been determined in National Radiation Protection Institute for many years. Sr-90 activity in those samples determinate branch Ostrava by radiochemical procedure - precipitation with oxalic acid and measuring with using gas-flow proportional detector. Gamma spectrometry with HPGe detector is using for 137 Cs determination. (authors)

  17. Revenue management for foodstuff production to secure domestic supply in Indonesia

    Science.gov (United States)

    Hisyam, Ibnu

    2017-06-01

    This paper describes the application of revenue management in government services to ensure sufficient domestic supply of food in Indonesia. The use of this approach means that the government runs a specific effort to radically be able to solve the core problem. The resources for domestic food production are owned by more than 26 million families of farmers and more than 4 thousands agricultural companies. To achieve the expected quantity of foodstuff supplies, a special effort needs to take into account the profit for producers in allocating the resources at an appropriate level. With revenue management, the price of foodstuff to ensure adequate domestic supply to a certain level of productivity can be known. In this context, the price may be reduced if there is an increase in productivity. For this purpose, the supply curve and the demand-supply equilibrium of foodstuff have been modeled and specific government programs to increase productivity were formulated. One important finding here is that the macroeconomic policy of the government can be integrated to a microeconomic policy of foodstuff producers for one or more certain objectives.

  18. Heavy and toxic metals in staple foodstuffs and agriproduct from contaminated soils

    International Nuclear Information System (INIS)

    Gorbunov, A.V.; Kistanov, A.A.; Lyapunov, S.M.; Okina, O.I.; Frontas'eva, M.V.; Ramadan, A.B.

    2002-01-01

    This article presents basic data on the content of Cr, Fe, Ni, Cu, Zn, As, Cd, Sb, Hg, and Pb in staple foodstuffs and agriproducts grown in Russia (Astrakhan region and the town of Belovo) and Egypt (Helwan region). The dependence of the concentration of metals in agriproducts on the content and chemical form of existence in irrigation water and soils is indicated

  19. Chemiluminescence measurements as an identification method for gamma-irradiated foodstuffs

    Energy Technology Data Exchange (ETDEWEB)

    Boegl, W; Heide, L

    1985-01-01

    Samples of 19 different spices, milk powder, whole onions and frozen chicken were exposed to a Co-60 source with radiation doses up to 10/sup 4/ Gy. The subsequent reaction of the irradiated foodstuffs in a luminol solution resulted in light emission (chemiluminescence). This effect can be used as an indicator of radiation treatment.

  20. Heavy and Toxic Metals in Staple Foodstuffs and Agriproduct from Contaminated Soils

    CERN Document Server

    Gorbunov, A V; Kistanov, A A; Lyapunov, S M; Okina, O I; Ramadan, A B

    2002-01-01

    This article presents basic data on the content of Cr, Fe, Ni, Cu, Zn, As, Cd, Sb, Hg, and Pb in staple foodstuffs and agriproduct grown in Russia (Astrakhan region and the town of Belovo) and Egypt (Helwan region). The dependence of the concentration of metals in agriproducts on the content and chemical form of existence in irrigation water and soils is indicated.

  1. Preventing refrigerated foodstuffs in supermarkets from being discarded on hot days by mpc

    DEFF Research Database (Denmark)

    Cai, Junping; Stoustrup, Jakob; Jørgensen, John Bagterp

    2008-01-01

    This paper presents an optimization strategy for supermarket refrigeration systems. It deals with one special condition when the extremely high outdoor temperature causes the compressor to saturate, and work at its maximum capacity. In a traditional control, refrigerated foodstuffs inside display...

  2. Application of nuclear analytical techniques to investigate trace element content in foodstuffs

    International Nuclear Information System (INIS)

    Gharib, A.

    1985-01-01

    The study performed as a joint project with the IAEA includes those foodstuffs which are being used widely in Iran. It was investigated their nutritional requirements, interrelations and the role of their trace elements in metabolism. Various analytical techniques was assessed and compared. The methods involved in the study were ASS, PIXE and NAA (instrumental and radiochemical)

  3. Mutations in the Foodstuff Quality Perception of the New Consumers in Romania

    Directory of Open Access Journals (Sweden)

    Dorin Popescu

    2011-11-01

    Full Text Available In the current context of the market, very complex and dynamic, we can observe the crystallization of a new generation of consumers, with a specific behavior and a particular manner of approaching the quality unlike the one of traditional consumer. The concept of quality, perceived by the traditional consumer in the classical, deterministic and objective sense, loses its facets nowadays and transcends into another dimension, in the vision of the new consumer, in which the perception of quality in a predominantly subjective manner, comes first. This paper presents the objectives of a research project that we intend to develop, in order to highlight the mutations that occurred in the foodstuff quality perception of the new consumers from Romania. We focused on foodstuff because it is a customary part of our daily lives, that shouldn’t be approached merely as a common factor for meeting physiological needs of macro and micro-nutrients, but from a holistic perspective in terms of its social and identity functions and the effects on individual health. Another important goal of the project is to improve the standard of education and culture in foodstuff consumption and to give to the new consumers from Romania the skills for an objective assessment of food quality. We believe that all these could lead to the conversion of the new consumers of foodstuff in ethical and responsible consumers.

  4. Pt(IV) complexes as prodrugs for cisplatin.

    Science.gov (United States)

    Shi, Yi; Liu, Shu-An; Kerwood, Deborah J; Goodisman, Jerry; Dabrowiak, James C

    2012-02-01

    The antitumor effects of platinum(IV) complexes, considered prodrugs for cisplatin, are believed to be due to biological reduction of Pt(IV) to Pt(II), with the reduction products binding to DNA and other cellular targets. In this work we used pBR322 DNA to capture the products of reduction of oxoplatin, c,t,c-[PtCl(2)(OH)(2)(NH(3))(2)], 3, and a carboxylate-modified analog, c,t,c-[PtCl(2)(OH)(O(2)CCH(2)CH(2)CO(2)H)(NH(3))(2)], 4, by ascorbic acid (AsA) or glutathione (GSH). Since carbonate plays a significant role in the speciation of platinum complexes in solution, we also investigated the effects of carbonate on the reduction/DNA-binding process. In pH 7.4 buffer in the absence of carbonate, both 3 and 4 are reduced by AsA to cisplatin (confirmed using ((195))Pt NMR), which binds to and unwinds closed circular DNA in a manner consistent with the formation of the well-known 1, 2 intrastrand DNA crosslink. However, when GSH is used as the reducing agent for 3 and 4, ((195))Pt NMR shows that cisplatin is not produced in the reaction medium. Although the Pt(II) products bind to closed circular DNA, their effect on the mobility of Form I DNA is different from that produced by cisplatin. When physiological carbonate is present in the reduction medium, ((13))C NMR shows that Pt(II) carbonato complexes form which block or impede platinum binding to DNA. The results of the study vis-à-vis the ability of the Pt(IV) complexes to act as prodrugs for cisplatin are discussed. Copyright © 2011 Elsevier Inc. All rights reserved.

  5. The controlled formation and cleavage of an intramolecular d8-d8 Pt-Pt interaction in a dinuclear cycloplatinated molecular "pivot-hinge".

    Science.gov (United States)

    Koo, Chi-Kin; Wong, Ka-Leung; Lau, Kai-Cheung; Wong, Wai-Yeung; Lam, Michael Hon-Wah

    2009-08-03

    The bis(diphenylphosphino)methane (dppm)-bridged dinuclear cycloplatinated complex {[Pt(L)](2)(mu-dppm)}(2+) (Pt(2)dppm; HL: 2-phenyl-6-(1H-pyrazol-3-yl)-pyridine) demonstrates interesting reversible "pivot-hinge"-like intramolecular motions in response to the protonation/deprotonation of L. In its protonated "closed" configuration, the two platinum(II) centers are held in position by intramolecular d(8)-d(8) Pt-Pt interaction. In its deprotonated "open" configuration, such Pt-Pt interaction is cleaved. To further understand the mechanism behind this hingelike motion, an analogous dinuclear cycloplatinated complex, {[Pt(L)](2)(mu-dchpm)}(2+) (Pt(2)dchpm) with bis(dicyclohexylphosphino)methane (dchpm) as the bridging ligand, was synthesized. From its protonation/deprotonation responses, it was revealed that aromatic pi-pi interactions between the phenyl moieties of the mu-dppm and the deprotonated pyrazolyl rings of L was essential to the reversible cleavage of the intramolecular Pt-Pt interaction in Pt(2)dppm. In the case of Pt(2)dchpm, spectroscopic and spectrofluorometric titrations as well as X-ray crystallography indicated that the distance between the two platinum(II) centers shrank upon deprotonation, thus causing a redshift in its room-temperature triplet metal-metal-to-ligand charge-transfer emission from 614 to 625 nm. Ab initio calculations revealed the presence of intramolecular hydrogen bonding between the deprotonated and negatively charged 1-pyrazolyl-N moiety and the methylene CH and phenyl C-H of the mu-dppm. The "open" configuration of the deprotonated Pt(2)dppm was estimated to be 19 kcal mol(-1) more stable than its alternative "closed" configuration. On the other hand, the open configuration of the deprotonated Pt(2)dchpm was 6 kcal mol(-1) less stable than its alternative closed configuration.

  6. Chemonuclear studies for identification for new production routes for the therapeutically useful radionuclides {sup 140}Nd, {sup 192}Ir, {sup 191}Pt, {sup 193m}Pt, und {sup 195m}Pt; Kernchemische Studien zur Entwicklung neuerer Produktionsverfahren fuer die therapierelevanten Radionuklide {sup 140}Nd, {sup 192}Ir, {sup 191}Pt, {sup 193m}Pt, und {sup 195m}Pt

    Energy Technology Data Exchange (ETDEWEB)

    Hilgers, K.

    2005-12-15

    New production routes for the therapeutically useful radionuclides {sup 140}Nd, {sup 192}Ir, {sup 191}Pt, {sup 193m}Pt and {sup 195m}Pt were investigated. Cross section data were measured using the stacked-foil technique and compared with theoretical calculations. A production method for the platinum nuclides was developed. The {sup 141}Pr(p, 2n){sup 140}Nd and {sup nat}Ce({sup 3}He, xn){sup 140}Nd reactions were investigated for production of {sup 140}Nd. Cross section data of nuclear reactions leading to the side products {sup 141}Nd, {sup 139}Nd and {sup 139}Ce could also be achieved. The experimental data were compared with theoretical calculations using the code ALICE-IPPE. A comparison of the calculated thick target yields showed that the {sup 141}Pr(p, 2n){sup 140}Nd reaction gives a higher yield. The {sup 192}Os(p, n){sup 192}Ir reaction was examined in the context of the production of {sup 192}Ir. Cross section data were determined and compared with theoretical calculations using the codes ALICE-IPPE and EMPIRE II. The yield of this reaction was compared with the yield of the reactor production of this nuclide. The reactor production seems to be more suitable because of a higher purity and yield. Cross section data were measured for the {sup 192}Os({alpha}, n){sup 195m}Pt, {sup 192}Os({alpha}, 3n){sup 193m}Pt and {sup 192}Os({sup 3}He, 4n){sup 191}Pt reactions. The activity of {sup 193m}Pt and {sup 195m}Pt was determined by X-ray spectroscopy after a chemical separation procedure. The ALICE-IPPE code was found to be inappropriate to reproduce the experimental values. The calculated yields were compared with the yields of other reactions, especially the reactor production of {sup 195m}Pt. The yield of the {sup 192}Os({alpha}, n){sup 195m}Pt reaction is lower compared to the yield of the reactor production, but offers lower target costs and higher specific activity. A production method for {sup 193m}Pt and {sup 195m}Pt was developed. Batch yields of 0.9 MBq

  7. Pt, Co–Pt and Fe–Pt alloy nanoclusters encapsulated in virus capsids

    International Nuclear Information System (INIS)

    Okuda, M; Eloi, J-C; Jones, S E Ward; Schwarzacher, W; Verwegen, M; Cornelissen, J J L M

    2016-01-01

    Nanostructured Pt-based alloys show great promise, not only for catalysis but also in medical and magnetic applications. To extend the properties of this class of materials, we have developed a means of synthesizing Pt and Pt-based alloy nanoclusters in the capsid of a virus. Pure Pt and Pt-alloy nanoclusters are formed through the chemical reduction of [PtCl 4 ] − by NaBH 4 with/without additional metal ions (Co or Fe). The opening and closing of the ion channels in the virus capsid were controlled by changing the pH and ionic strength of the solution. The size of the nanoclusters is limited to 18 nm by the internal diameter of the capsid. Their magnetic properties suggest potential applications in hyperthermia for the Co–Pt and Fe–Pt magnetic alloy nanoclusters. This study introduces a new way to fabricate size-restricted nanoclusters using virus capsid. (paper)

  8. Analysis of bite marks in foodstuffs by computer tomography (cone beam CT)--3D reconstruction.

    Science.gov (United States)

    Marques, Jeidson; Musse, Jamilly; Caetano, Catarina; Corte-Real, Francisco; Corte-Real, Ana Teresa

    2013-12-01

    The use of three-dimensional (3D) analysis of forensic evidence is highlighted in comparison with traditional methods. This three-dimensional analysis is based on the registration of the surface from a bitten object. The authors propose to use Cone Beam Computed Tomography (CBCT), which is used in dental practice, in order to study the surface and interior of bitten objects and dental casts of suspects. In this study, CBCT is applied to the analysis of bite marks in foodstuffs, which may be found in a forensic case scenario. 6 different types of foodstuffs were used: chocolate, cheese, apple, chewing gum, pizza and tart (flaky pastry and custard). The food was bitten into and dental casts of the possible suspects were made. The dental casts and bitten objects were registered using an x-ray source and the CBCT equipment iCAT® (Pennsylvania, EUA). The software InVivo5® (Anatomage Inc, EUA) was used to visualize and analyze the tomographic slices and 3D reconstructions of the objects. For each material an estimate of its density was assessed by two methods: HU values and specific gravity. All the used materials were successfully reconstructed as good quality 3D images. The relative densities of the materials in study were compared. Amongst the foodstuffs, the chocolate had the highest density (median value 100.5 HU and 1,36 g/cm(3)), while the pizza showed to have the lowest (median value -775 HU and 0,39 g/cm(3)), on both scales. Through tomographic slices and three-dimensional reconstructions it was possible to perform the metric analysis of the bite marks in all the foodstuffs, except for the pizza. These measurements could also be obtained from the dental casts. The depth of the bite mark was also successfully determined in all the foodstuffs except for the pizza. Cone Beam Computed Tomography has the potential to become an important tool for forensic sciences, namely for the registration and analysis of bite marks in foodstuffs that may be found in a crime

  9. Occurrence of polybrominated diphenyl ethers (PBDEs) in foodstuffs in Italy and implications for human exposure.

    Science.gov (United States)

    Martellini, Tania; Diletti, Gianfranco; Scortichini, Giampiero; Lolini, Meri; Lanciotti, Eudes; Katsoyiannis, Athanasios; Cincinelli, Alessandra

    2016-03-01

    Polybrominated diphenyl ethers (PBDEs) were determined in various foodstuffs in Italy and the dietary intake was estimated. PBDEs were detected in all analysed samples at concentrations that spanned over five orders of magnitude. The most abundant congeners were the BDE-209, followed by BDE-47 and BDE-99. Fish oil and milk samples showed the highest PBDE concentrations among all samples. The daily dietary intake values were found to be in good agreement or higher to literature values, impacted mainly from the contribution of the analysed dairy products. The cancer risk values estimated for BDE-209 indicated that this specific risk associated with the studied foodstuffs is limited. Italy is one of the world-leading countries in the production of furniture and clothes and has extremely developed medium enterprise industrial sector, where PBDEs were historically used suggesting that their occurrence may be linked to these activities. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Irradiated foodstuff: atom, junk-food and globalization; Aliments irradies: Atome, malbouffe et mondialisation

    Energy Technology Data Exchange (ETDEWEB)

    Azam, Genevieve; Berlan, Jean-Pierre; Desbordes, Roland; Dufour, Francois; Fievet, Yann; Folliard, Thierry; Gallais, Veronique; Hauter, Wenonah; Jacquiau, Christian; Kastler, Guy; Lannoye, Paul; Le Goff, Lylian; Le Rohellec, Catherine; Louchard, Olivier; Marechal, Gilles; Nicolas, Yveline; Remesy, Christian; Trouve, Aurelie; Veillerette, Francois

    2008-07-01

    Food irradiation is officially presented as an ideal technology at the service of worldwide health safety and as an alternative to chemical processing of foodstuff. It is first of all a multi-usage technology for the preservation, disinfestation, ripening slowing down, and germination inhibition of products which serves the interests of multinational companies of the agriculture and food industry. According to the authors, it is also an instrument for the globalization of foodstuff trade encouraged by the international institutions and by some governments. The book stresses on the health, socio-economic and environmental risks of this technology: vitamins loss, carcinogenesis, mutagenesis, impact on local employment and economy, risks linked with the use of irradiation devices etc

  11. Antibiotic resistance of microbial contaminations isolated from husbandry animals and foodstuffs

    Directory of Open Access Journals (Sweden)

    Lukáš Hleba

    2014-05-01

    Full Text Available In this paper the antibiotic resistance of microbial contaminations isolated from husbandry animals and foodstuffs were investigated. Microorganisms isolated from animals and foodstuffs were contaminations of selective media as MacConkey agar for Enterobacteriaceae genera and MRS agar for lactobacilli strains. Microorganisms were isolated and puryfied by agar four ways streak plate method. Identification of isolated microorganisms was done by mass-spectrometry method in MALDI-TOF MS Biotyper. For investigation of antibiotic resistance disc diffusion method by EUCAST was used. In this study Gram-negative and Gram-positive bacteria were identified. The most resistant or multi-resistant bacteria as Pseudomonas aeruginosa, Acinetobacter lwoffi, Lysinibacillus sphaericus, Staphylococcus aureus and Staphylococcus epidermis were determined. Other identified microorganisms were resistant to one antibiotic or not at all.

  12. Application of neutron activation analysis to the monitoring of trace elements in Brazilian foodstuffs

    International Nuclear Information System (INIS)

    Vasconcellos, M.B.A.; Munita, C.J.S.; Maihara, V.A.; Abe, R.M.

    1988-01-01

    The work of the group of the Radiochemistry Division on food analysis started with milk powder and bread samples, since these foodstuffs are largely consumed by the population of Sao Paulo (Brazil). Both instrumental and radiochemical NAA techniques were employed, allowing the determination of the elements Na, Cl, Mn, Br, Fe, Zn, Rb, Sb, Se, Cr, Al, Mg, Cu and La. Nuclear techniques for toxic elements in foodstuffs, were applied more specifically to the analysis of rice, specially for Hg and Se. A radiochemical separation procedure was developed for the determination of these two elements, at the ppb level, based on distillation and precipitation. INAA was applied to determine As, Br, Na, K, Rb and Zn, as well. 3 tabs

  13. Dacfood: a knowledge-based system for decision support in case of radiological contamination of foodstuffs

    International Nuclear Information System (INIS)

    Diaz, A.; Despres, A.; Soulatges, D.

    1991-01-01

    In case of radiological contamination of foodstuffs, the introduction of a countermeasure has to be justified by balancing its advantages and drawbacks, as recommended by ICRP. Also, to provide authorities with information about the decision context, it has been decided to develop a Decision Support System (DSS). A knowledge-based approach is used for the DSS. Indeed, it allows: . better modelling thanks to, for instance, object oriented programming and rules, . ability to introduce more knowledge thanks to an easier consistency and validity control of the knowledge base, . handling of uncertainties (incomplete, uncertain or evolving knowledge). The present state of the system is presented. DACFOOD is a decision aiding system for contamined foodstuffs, based on a knowledge-based approach. A demonstration model has been developed in a post-Chernobyl CEC research program. It evaluates the sanitary situation, the alternative actions through costs and sanitary effects, and gives information on the decisional background

  14. Activity of Cs-137 in some foodstuffs imported to Slovak Republic

    International Nuclear Information System (INIS)

    Puskeiler, L.; Miklas, P.; Missik, J.

    1995-01-01

    In this paper the results of Cs-137 activity in some foodstuffs imported to Slovak Republic are presented. The results from two points of view: 1) sort of foodstuffs (was chosen two sort - the fish and fish products and beef, pork and bowels); 2) country of origin (three countries was chosen -Germany, Norway and the Ukraine). The above mentioned choice was based on statistical grounds, data sets with total population at least 100 was evaluated, the only exception the data set for the Ukraine. For evaluation of data sets the statistical procedures developed for left-censored data sets with assumption of lognormal distribution were used. The analyzed data sets were obtained by semiconductor gamma spectrometry in Laboratory of Radiometry and Radioecology. The results are reported in six tables with basic statistical characteristics like number of samples with >minimal detectable activity, arithmetic mean, variance and maximum value (J.K.). 6 tabs., 3 refs

  15. Activity of Cs-137 in some foodstuffs imported to Slovak Republic

    Energy Technology Data Exchange (ETDEWEB)

    Puskeiler, L; Miklas, P [Inst. of Veterinary Hygiene and Ecology, Nitra (Slovakia). Lab. of Radiometry and Radioecology; Missik, J [Univ. of Agriculture, Nitra (Slovakia). Lab. of Radiometry and Radioecology

    1996-12-31

    In this paper the results of Cs-137 activity in some foodstuffs imported to Slovak Republic are presented. The results from two points of view: 1) sort of foodstuffs (was chosen two sort - the fish and fish products and beef, pork and bowels); 2) country of origin (three countries was chosen -Germany, Norway and the Ukraine). The above mentioned choice was based on statistical grounds, data sets with total population at least 100 was evaluated, the only exception the data set for the Ukraine. For evaluation of data sets the statistical procedures developed for left-censored data sets with assumption of lognormal distribution were used. The analyzed data sets were obtained by semiconductor gamma spectrometry in Laboratory of Radiometry and Radioecology. The results are reported in six tables with basic statistical characteristics like number of samples with >minimal detectable activity, arithmetic mean, variance and maximum value (J.K.). 6 tabs., 3 refs.

  16. Preliminary study on detection of irradiated foodstuffs from the Romanian market

    International Nuclear Information System (INIS)

    Cutrubinis, Mihalis; Chirita, Daniel; Savu, Diana; Elisabeta Secu, Corina; Mihai, Radu; Secu, Mihai; Ponta, Corneliu

    2007-01-01

    In order to fulfil the European task for market survey in food irradiation the first Romanian laboratory for detection of irradiated foodstuffs was established at IRASM Irradiation Centre. In this preliminary study, a wide range of Romanian food samples (spices, vegetables and meat) gamma irradiated at IRASM have been studied using different detection methods: (1) DNA comet assay, (2) thermoluminescence (TL) and (3) electron spin resonance (ESR) for foodstuffs containing bone or cellulose. The results suggest that there is no general available detection method and there is no perfect detection method. In conclusion, in order to carry out a correct identification of radiation treatment of a food sample it is recommended to use at least two standardised detection methods

  17. Some thoughts concerning the radioactive contamination of foodstuffs 10 years after the Chernobyl disaster

    International Nuclear Information System (INIS)

    Szabo, S.A.

    1997-01-01

    Although the Chernobyl disaster happened 10 years ago (26 Apr. 1986), investigation of the radioactive contamination of the environmental is still in the focus of interest. However it can be established that the pollution level in Hungary- like other, from the place of accident rather far located countries - decreased significantly in the food chain in comparison with measured data in May-June, 1986. Practically the present contamination level (e.q. 137 Cs, 90 Sr) since 1989 is the same as it was in the years before the disaster. Since the level of artificial contamination is much less than the natural radioactivity (e.q. 40 K, 226 Ra) of the foodstuffs, the radiation burden caused by the consumed foodstuffs is negligible. (author)

  18. Minimizing quality deteriorations of refrigerated foodstuffs as a side effect of defrosting

    DEFF Research Database (Denmark)

    Cai, Junping; Stoustrup, Jakob

    2008-01-01

    This paper proposes an optimization scheme for traditional refrigeration systems with hysteresis controllers and scheduled defrosts. It aims at minimizing the side effect of defrost cycles on the storage quality of refrigerated foodstuffs in supermarkets. By utilizing the thermal mass of air...... and products inside a display cabinet, this optimization scheme forces the compressor to work harder and cool down more prior to the scheduled defrosts, thus guaranteeing the product temperature after defrost cycles still to be within a controlled safe level....

  19. Simultaneous Determination of Four Preservatives in Foodstuffs by High Performance Liquid Chromatography

    OpenAIRE

    Mohammad Faraji; Farzaneh Rahbarzare

    2016-01-01

    Background and objectives:  High concentration of preservatives in food may result in gastrointestinal disturbances whereby some patients suffering from asthma, rhinitis, or urticaria. The aim of this study is the introduction and optimization a new method for simultaneous determination of four preservatives (SB, PS, MP, PP) in foodstuff by high performance liquid chromatography. Materials and methods: Important factors in extraction, separation and determination process were optimiz...

  20. Popularity of processed foodstuffs for infants and small children among parents

    OpenAIRE

    Danuta Górecka; Barbara Szczepaniak; Krystyna Szymandera-Buszka; Ewa Flaczyk

    2007-01-01

    The popularity of seven groups of processed foodstuffs (soups, dinners, pulverized fruits and vegetables, desserts, dairy desserts, juices, teas) for infants and small children aged 4 months up to 3 years, available on the market and comprising a total of 154 products, was investigated in this study. A survey was carried out in the group of 100 individuals. They were mothers and fathers bringing their children to crèche as well as buying analysed products. Among 24 soups vegetable so...

  1. Supply of basic food, energy, and energy-supplying foodstuffs to the population of Jordan

    Energy Technology Data Exchange (ETDEWEB)

    Hamdan, M R

    1979-04-27

    The supply of energy and energy-supplying foodstuffs to the population of Jordan is determined on a regional basis. Food is supplied by the agricultural sector and by imports. The influence of prices on foreign trade and consumption is analyzed. The investigation shows that most of the food supplied is of vegetable origin. The demand for animal protein is covered by 82% on an average. There are no symptoms of malnutrition among the population.

  2. Prognosis of the application spices, nondecontamined and decontaminated by irradiation on the sanitary effect foodstuffs

    International Nuclear Information System (INIS)

    Migdal, W.; Owczarczyk, H.B.

    2002-01-01

    Using the elements of prognostic microbiology it has been shown that under conditions conductive to growth of microorganisms, the foodstuff which contains contaminated spices is characterized by lower quality. It may be the risk for human health. The prognosis has been shown, the microbiological decontamination of spices by irradiation may be one of the elements of new system - Hazard Analysis Critical Control Point (HACCP). (author)

  3. X-ray fluorescence analysis for trace element determination in foodstuff chemistry

    International Nuclear Information System (INIS)

    Wildanger, W.

    The physical fundamentals of X-ray fluorescence analysis are given and the routine spectrometers described. The basic principles are given of analytical methods used in qualitative and quantitative fluorescence analyses. Examples are given of the use of the method in a number of fields and the possibility and usefulness is discussed for the determination of trace elements in foodstuffs. The preparation of samples, preliminary concentration of components and calibration methods are discussed. (M.K.)

  4. Chitosan Dilutable and Dilactin Forte: Assessment of Their Efficiency for Safety and Quality of Foodstuff

    Science.gov (United States)

    Iurchikova, N.; Khlebosolova, O.

    2018-01-01

    The modern natural food preservatives used to process and store foodstuff allow to ensure its safety and high quality. Chitosan and dilactin-forte are among such medicines. These preservatives are not only safe, but also are beneficial to a human body in virtue of their effects onto human digestive system. The article describes the results of the research conducted to identify the impact of these natural preservatives on safety of carrot (Daucus carota subsp. sativus)

  5. An investigation of the genetic toxicology of irradiated foodstuffs using short-term test systems

    International Nuclear Information System (INIS)

    Phillips, B.J.; Kranz, E.; Elias, P.S.

    1980-01-01

    As part of a programme of short-term tests used to detect possible genetic toxicity in irradiated foodstuffs, cultured Chinese hamster ovary cells were exposed to extracts and digests of irradiated and unirradiated dates, fish and chicken and subjected to tests for cytotoxicity, sister chromatid exchange induction and mutation to thioguanine resistance. The results showed no evidence of genetic toxicity induced in food by irradiation. The general applicability of cell culture tests to the detection of mutagens in food is discussed. (author)

  6. Effects of Foodstuffs on Intestinal Length in Larvae of Rhacophorus arboreus (Anura: Rhacophoridae) : Developmental Biology

    OpenAIRE

    SHINRI, HORIUCHI; YUTAKA, KOSHIDA; Department of Biology, College of General Education, Osaka University; Department of Biology, College of General Education, Osaka University

    1989-01-01

    Correlation between foodstuffs and intestinal length was examined in larvae of Rhacophorus arboreus (Anura: Rhacophoridae). The larva, being heterophagous, has a tube-like intestine provided with neither epithelial outfoldings nor villi, and intestinal length is found to be a good morphological index of digestive and absorptive functions of the intestine. The results obtained were summarized as follows: The grown larva fed on boiled spinach had an intestine more than 1.5 times as long as that...

  7. Foodstuffs treatment by ionization; Stato attuale del processo di ionizzazione delle sostanze alimentari

    Energy Technology Data Exchange (ETDEWEB)

    Tata, A.; Adamo, M. [ENEA, Centro Ricerche Casaccia, Rome (Italy). Dipt. Innovazione

    1997-11-01

    Foodstuffs treatment by ionization gives rise to chemical, physical and biological changes able to produce both a shelf-life extension and / or a foodborne diseases control through the pathogenic population reduction / elimination. The main process goal is therefore to ensure the hygienic quality and the wholesomeness of products to be marketed, in order to limitate foodborne diseases originated mainly through the `cross contamination` process. The microbiological recovery induced by ionization has spurred this new technology and its applications in foodstuffs treatment are more and more taking interest all over the world. At present, over 40 countries provide clearances for the treatment of about 45 different types of foodstuffs and in over 20 of them the process is already industrially utilized for spices, poultry, shrimps and vegetables. Industrial food ionization plants, utilizing EB-machines or radioisotopes, are at present about 50 world-wide, with a uniform distribution in advanced as well as developing countries. As it refers to process economic aspects, market researches have shown cost figures ranging from few tens to some hundreds Lit/kg, depending on the dose to products. These costs are competitive with alternative treatments, beyond the recovery of economic productivity reduction caused by foodborne diseases.

  8. Activation analysis of toxic elements in meat and farinaceous foodstuffs of the Republic of Argentina

    International Nuclear Information System (INIS)

    Resnizky, S.M.; Bertini, L.M.; Moreno, M.A.; Cohen, I.M.; Videtti Piedracoba, N. de; Pla, R.R.; Gomez, C.D.

    1994-01-01

    As a result of the industrial and agrochemical developments, there has been an increase of the environmental pollution. Foodstuffs are one of the ways of incorporating some heavy metals or other contaminants into the human body. So, it is important to know the amount of these elements in the food consumed by the population. Our project on determination of toxic elements in meat and farinaceous food largely consumed in our country, was carried out by neutron activation analysis. Different kinds of flours and noodles were analyzed as farinaceous, and hamburgers and sausages as manufactured meat products. Specific separation methods were developed by radiochemical neutron activation analysis for As, Sb, Se, Hg and Cd. All these separations were based on precipitation or coprecipitation of the elements as sulphides. Other elements such as Fe, Br, Co, Zn, Rb, and also Se, were analyzed using instrumental neutron activation analysis. Using daily intake of analyzed foodstuffs from consumption tables and their average elemental composition, an intake of the studied elements was calculated. The values obtained for toxic elements were lower than the maximum permissible levels in Argentina. The results of this project could serve as a basis of a wider study including more foodstuffs as raw meat and will be used by other research groups. (author). 8 refs, 3 figs, 4 tabs

  9. Study of organohalogens in foodstuffs and environmental samples by neutron activation analysis and related techniques

    International Nuclear Information System (INIS)

    Xu, D. D.; Mao, X.Y.; Ouyang, H.; Chai, Z. F.; Zhang, H.; Sun, H. B.

    2004-01-01

    Pine needles and foodstuffs collected from Beijing, China, were analyzed by instrumental neutron activation analysis (INAA) combined with organic solvent extraction for total halogens, extractable organohalogens (EOX) and extractable persistent organohalogens (EPOX). The INAA detection limits are 50 ng, 8 ng and 3.5 ng for Cl, Br and I, respectively. The contents and distribution patterns of organohalogens in these samples are reported. EOCl accounted for 0.013-0.016% and 1.6-2.7% of the total chlorine in yogurt and apples, respectively, which suggested that chlorine in foodstuffs mainly existed as inorganic species and non-extractable organochlorines. EOCl contents in pine needles and foodstuffs were noticeably higher than those of EOBr and EOI. For pine needles, yogurt and apples, 1.6-34%, 23-58% and 29-35% of EOCl remained as extractable persistent organochlorine (EPOCl), respectively. Pine needle containing higher EOCl contents in chemical industrial and traffic hub areas indicated that chemical industries and exhaust emission from vehicle were the main sources of organochlorines in the Beijing's air. The relative proportions of the known organochlorines (such as HCHs, DDTs, chlordanes, heptachlor, HCB and PCBs) to the total EOCl and EPOCl were 0.04-1.6% and 0.7-21.5%, respectively, which implied that the identity of species of a major portion of the EOCl and EPOCl measured in pine needles was unknown. (author)

  10. Co-ordinated research programme on nuclear techniques for toxic elements in foodstuffs

    International Nuclear Information System (INIS)

    1988-01-01

    The purpose of this Co-ordinated Research Programme (CRP) is to obtain comparative data on the existing elemental concentrations of potentially toxic elements in foodstuffs in various countries. This study is also intended to provide information on the dietary intakes of toxic elements as a means to detect potential health hazards to the population groups concerned. This study has important economic implications since trade in foodstuffs is dependent on compliance with regulations pertaining to maximum permissible concentrations. An important supplementary purpose of the programme is to help establish analytical expertise for work of this kind in individual countries, allowing such laboratories to offer analytical quality control services. The programme has centred its objective on the determination of important toxic elements such as As, Cd, Cr, Hg, Pb and Se, in addition to Cu, Sb and Zn, which are also potentially toxic but are generally of minor importance from the point of view of public health. The matrices of interest are foodstuffs which comprise together more than 50% of the average daily intake. Drinking water is also of high importance and should be analysed as well. Refs, figs and tabs

  11. The public committed effective dose caused by consumption of foods and foodstuffs in Ninh Thuan

    International Nuclear Information System (INIS)

    Nguyen Trong Ngo; Nguyen Thanh Binh; Le Nhu Sieu; Truong Y; Nguyen Van Phuc; Nguyen Thi Linh; Nguyen Dinh Tung

    2014-01-01

    Based on the data set about radionuclides concentration in foods and foodstuffs obtained from the implementation of the National Projects on “Investigation on radionuclides and toxic elements concentration in the main kinds of foods and foodstuffs of Vietnam” and “Assessment of Marine Environmental Radioactivity Status for two selected sites of Nuclear Power Plant in the near future at Ninh Thuan Province”, a calculation software of the International Commission for Radiological Protection (ICRP), the public committed effective doses (for adult only) caused by consumption of main foods & foodstuffs in the studied experimental region were estimated. In general, the committed effective doses for adult public caused by the daily intake of radionuclides of U, 232 Th, 210 Pb, 210 Po, 226 Ra, 40 K, 90 Sr, 137 Cs and 239,240 Pu are: 7.9x10 -5 , 4.1x10 -6 , 1.1x10 -2 , 1.7x10 -1 , 1.4x10 -3 , 1.2x10 -1 , 2.32x10 -4 , 1.9x10 -4 , 2.7x10 -9 (mSv/year), respectively, and the contribution of U, Th series, 40 K and artificial radionuclides are 61.3%, 38.6% and 0.1%, respectively. (author)

  12. Annual intake of 137Cs and 90Sr from ingestion of main foodstuffs in Taiwan

    International Nuclear Information System (INIS)

    Wang, Chih-Jung; Lai, Shu-Ying; Huang, Ching-Chung; Lin, Yu-ming

    1996-01-01

    The radioactivities of eight main foodstuffs were investigated during 1985-1994 to evaluate the annual intake from the ingestion of 137 Cs and 90 Sr for the residents of Taiwan. The evaluation of annual intake was based on the results of radiochemical analysis of 90 Sr and gamma-ray spectrometry of 137 Cs as well as annual consumption rates of those foodstuffs in Taiwan. The annual intake 90 Sr and 137 Cs per capita is 13 and 60 Bq, respectively. Among the eight foodstuffs, fruit contributed the most to the annual intake of 90 Sr, vegetable second, rice the third and egg the least. For 137 Cs, rice contributed the most, then fruit, meat the third and flour the least. Based on the new conversion factors from ICRP 60, the annual committed effective doses of Taiwanese due to the ingestion of radionuclides 90 Sr and 137 Cs were estimated to be 3.7 x 10 -7 and 7.8 x 10 -7 Sv, respectively. (author)

  13. MYC RNAi-Pt Combination Nanotherapy for Metastatic Prostate Cancer Treatment

    Science.gov (United States)

    2017-10-01

    encouraged and supported to attend local seminars, workshops, national conferences, and advanced education courses to present their research work...cytotoxicity studies with Pt-naïve and Pt-resistant PCa cells; and (ii) evaluate the therapeutic efficacy of MYC-Pt NPs in PC3 cell line- based xenograft and... therapeutic NPs. We have also carried out RNAseq experiments on the BMPC and GEM models that will lay the groundwork for deriving our MYC signature that

  14. Characterization of azo dyes on Pt and Pt/polyaniline/dispersed Pt electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Molina, J.; Fernandez, J.; Rio, A.I. del; Bonastre, J. [Departamento de Ingenieria Textil y Papelera, EPS de Alcoy, Universitat Politecnica de Valencia, Plaza Ferrandiz y Carbonell s/n, 03801 Alcoy (Spain); Cases, F., E-mail: fjcases@txp.upv.es [Departamento de Ingenieria Textil y Papelera, EPS de Alcoy, Universitat Politecnica de Valencia, Plaza Ferrandiz y Carbonell s/n, 03801 Alcoy (Spain)

    2012-06-15

    The electrochemical characterization of two organic dyes (amaranth and procion orange MX-2R) has been performed on Pt electrodes and Pt electrodes coated with polyaniline and dispersed Pt. Electrodes with different Pt loads have been synthesized and characterized obtaining that a load of 300 {mu}g cm{sup -2} was the optimum one. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) was employed to observe the distribution and morphology of the Pt nanoparticles. The electroactivity of the electrodes has also been characterized by means of scanning electrochemical microscopy (SECM). The chemical characterization of Pt dispersed Pani coated Pt electrodes (Pt-Pani-Pt) was performed by means of X-ray photoelectron spectroscopy (XPS). The electrochemical characterization of the dyes has been performed by means of cyclic voltammetry. Voltammograms have shown that the presence of the dyes diminishes characteristic Pt oxidation and reduction peaks. However, redox processes due to the dyes, appeared in the voltammograms. The different species responsible of these redox processes were generated in the vicinity of the electrode and were not adsorbed on the electrode surface since after stirring, the different redox processes disappeared. Characterization with different scan rates showed that redox processes of both dyes were controlled by diffusion.

  15. Coulomb excitation of the 4+1 states of 194Pt, 196Pt and 198Pt

    International Nuclear Information System (INIS)

    Fewell, M.P.; Gyapong, G.J.; Spear, R.H.

    1987-09-01

    Probabilities for the Coulomb excitation of the 4 1 + states of 194 Pt, 196 Pt, 198 Pt by the backscattering of 4 He, 12 C and 16 O ions are reported. Model-independent values of the matrix elements 1 + ; M(E4), 4 1 + > and 1 + , M(E2), 4 1 + > are extracted. Agreement with previous measurements of these matrix elements is good. Values of β 2 and β 4 are determined for 194 Pt and compared with calculations of these quantities

  16. Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan

    Energy Technology Data Exchange (ETDEWEB)

    Matsukami, Hidenori; Kurunthachalam, S; Ohi, Etsumasa; Takasuga, Takumi [Shimadzu Techno Research, Inc., Kyoto (Japan); Iino, Fukuya; Nakanishi, Junko [National Inst. of Advanced Industrial Science and Technology, Tsukuba (Japan)

    2004-09-15

    Polychlorinated n-alkanes (PCAs) are group of chemicals manufactured by chlorination of liquid n-paraffin or paraffin wax that contain 30 to 70% chlorine by weight. Large amounts of PCAs are widely used as plasticizers for vinyl chloride, lubricants, paints, and flame retardants and number of other industrial applications. Annual global production of PCAs is approximately 300 kilo tones, with a majority having medium-carbon-chain (C14-C19) length. According to the investigation made by Kagaku Kogyo Nippon-Sha, the annual consumption of PCAs in Japan was about 83,000 tons in between 1986-2001. Short-carbon-chain (C10-C13) has been placed on the Priority Substance List under Canadian Environmental Protection Act and on the Environmental Protection Agency Toxic Release Inventory in the USA due to its potential to act as tumor promoters in mammals. Data on environment levels of PCAs is meager, nevertheless, PCAs have been measured at relatively high concentrations in biota from Sweden, biota, sediment from Canada and marine biota and human milk from the Canadian Arctic. In our earlier study, we reported concentrations of short-chain PCAs from sewage treatment plant (STP) collected from Tama River, Tokyo and river water and sediment from Tokyo and Osaka. STP influent water contained greater shortchain PCAs concentrations than STP effluent. In addition, some river water and sediment samples contained detectable concentrations of short-chain PCAs, which was similar to other industrial countries. However, there is no study conducted to explore the contamination profiles of short-chain PCAs in human foodstuff samples. In the present study, we analyzed eleven foodstuff samples that were purchased from various supermarkets in order to know the short-chain PCAs concentrations in the foodstuff and possible human total daily intake (TDI) amounts.

  17. EXPERIMENT ON LONG-STORAGE OF FOOD PRODUCTS FOODSTUFFS IN CODITION OF PERMAFROST CONTINUED, ARCTIC, 2016

    Directory of Open Access Journals (Sweden)

    S. E. Ulanin

    2016-01-01

    Full Text Available In 1973 the crew of polar expedition, investigating the Middendorff Bay at the messdeck Zarya, discovered the depot of food products hidden in permafrost by head of Russian polar expedition E. Toll in 1900. There were oat flakes ‘Gerkules’ and croutons in the depot. Then the study carried out in Research Institute of Vegetable Drying and Can Industry had shown that all products discovered had preserved all their food qualities. That result leaded to launch up the experimental work on the possibility of preservation of food products and foodstuffs in permafrost till 2050. Quality of product found out in Taymyr Peninsula was analyzed. The results of study on qualities after long preservation in permafrost of such food products and foodstuffs as meat, milk, fish, confectionery, concentrated food, plant seeds were given. As a result of expedition in 2016, 20 samples were taken out and new samples of two types of products were placed into repository. Overall products placed consisted of 23 items, including foodstuffs and plant seeds with account of taking them out in 2025, 2035 and 2050. On the basis of research carried out, it is proved that most of modern and casual food products can be preserved without losing their quality values.

  18. Decontamination abilities of some foodstuffs enriched with low-esterificated pectin

    International Nuclear Information System (INIS)

    Shtereva, V.; Kiradzhiev, G.; Paskalev, Z.; Genchev, E.

    1993-01-01

    Radioprotective foodstuffs prepared from mousses of beet, apricot and hip, containing low-esterificated pectin, have been prepared. Their abilities to reduce the resorption of radionuclides in the digestive tract have been investigated. These are evaluated with respect to cesium-137 and cerium-144. The changes in nuclide accumulation have been controlled by measuring the whole-body activity and radiometry of the critical organs. Among the studied mousses the hip mousse proved to be the most effective towards radioactive cesium. Efficacy towards cerium has not been found. (author)

  19. THE EFFECTS OF DIFFERENCES IN THE NOURISHMENT CULTURE ON THE PURCHASING FOODSTUFFS OF WOMEN CONSUMERS

    Directory of Open Access Journals (Sweden)

    AYŞE ŞAHİN

    2013-06-01

    Full Text Available The aim of this study is to analyze the women who live in the central districts within Mersin whether have different nourishment culture and have different behaviours to purchase foodstuffs or not. For this aim, a field survey has been conducted as a pilot study on women. The hypothesis of this study were tested with the help of t-test by using the data obtained from the survey. At the end of the research it has been concluded that, there are important differences among the groups on the cooking traditional meals, the frequency of cooking traditional meals and cooking the traditional meals of Mersin.

  20. Romanian Consumers’ Willingness to Buy Foodstuffs Containing Food Additives: Results of a Conjoint Study

    Directory of Open Access Journals (Sweden)

    Viktória Szucs

    2015-11-01

    Full Text Available Results of the literature and the authors’ previous studies showed consumers’ high anxiety regarding food additives as well as their high demand for additive-free products in Romania, even at higher prices. Hence, the aim of our work was to analyse the willingness to buy and preference of foodstuffs containing natural and artificial food additives in Romania.A complex conjoint analysis (rating-based and choice-based was performed amongst Romanian consumers. Conjoint cards were created from two groups of food additives (‘preservatives’ and ‘packaging gases’, and consisting of two ‘model foodstuffs’ (pre-packed sliced cheese and chips. For the study, three factors were selected: ‘preservatives’ (artificial/natural, ‘packaging gases’ (contains/does not contain and ‘price’ (average+10%/average+20%. Results were collected via the internet and data were analysed with the help of SPSS Conjoint and XLSTAT softwares. ‘Preservatives’ have a dominant importance and ‘natural preservatives’ have a high utility in shopping decisions. ‘Natural’ compounds have higher importance in the example of foodstuffs thought to contain less food additives (pre-packed sliced cheese, while the presence of ‘packaging gases’ is acceptable to respondents in easy to handle and convenient foodstuffs. With the help of the cluster analysis, the promising target group (‘desire for natural’ characterising additive-free foodstuffs  that contain natural compounds was identified. Restricted comparison of the rating-based and the choice-based analysis showed that the choice-based method was easier to handle and understand for the participants. Regarding the results, a threefold conclusion was established: the ‘prominence effect’ is greater for the choice-based than the rating-based analysis; the effect of ‘level focusing’ is smaller in the rating-based than in the choice-based analysis; the ‘compatibility effect’ the rating

  1. Radionuclide monitoring in foodstuff: overview of the current implementation in the EU countries

    International Nuclear Information System (INIS)

    Borbala Mate; Katarzyna Sobiech-Matura; Timotheos Altzitzoglou

    2015-01-01

    The Member States (MS) of the European Union (EU) are obliged to monitor the radioactivity in the environment since the signature of the Euratom Treaty (Treaty establishing the European Atomic Energy Community). Numerous secondary legislations derived from the Treaty can be found stating restrictions and maximum permitted levels of radionuclides in foodstuff. But to that purpose, no common integrated measurement methods are used with well-defined measurands. The present work consists of two parts. First, the current European regulations in force were collected, and then the food monitoring results, provided by the MS, were analysed. (author)

  2. [Manual material handling risk assessment and ergonomic improvement in foodstuff retailing company].

    Science.gov (United States)

    Maso, S; Maccà, I; Simonetti, A; Scopa, P; Paruzzolo, P; Bonacci, A; Murgolo, I; Bartolucci, G B

    2011-01-01

    The aim of this study is to assess and reduce the risk due to manual material handling in a company involved in the foodstuff retailing. The risk assessment was performed by NIOSH Variable Lifing Index in 13 different occupational conditions. As result the risk was present in any case, with VLI values ranging from 2.12 to 2.81. A good risk reduction has been accomplished correcting properly the most important multiplier involved in the computation of the revised NIOSH Lifting equation (lifting frequency and weight of heavier products). Even if the performed risk reduction has been significant, the residual risk is still higher than the level of acceptability.

  3. Assessment of Human Organism's Intake of Trace Elements from Staple Foodstuffs in Central Region of Russia

    CERN Document Server

    Gorbunov, A V; Okina, O I; Frontasyeva, M A; Gundorina, S F

    2004-01-01

    The trace element content of raw materials and foodstuffs produced from them, typical for basket of goods of residents of Central Russia, was examined. An excess of permissible levels of some trace elements was observed. This phenomenon is explained in terms of different factors such as pollution of the environment, industrial technologies, biological peculiarities of raw materials of animal and vegetable origin. An assessment of human organism's trace element intake of different food allowances is given. This study was undertaken in the framework of IAEA CRP (Contract No. 11927/R2).

  4. Analysis of 3-MCPD and 1,3-DCP in Various Foodstuffs Using GC-MS

    OpenAIRE

    Kim, Wooseok; Jeong, Yun A; On, Jiwon; Choi, Ari; Lee, Jee-yeon; Lee, Joon Goo; Lee, Kwang-Geun; Pyo, Heesoo

    2015-01-01

    3-Monochloro-1,2-propanediol (3-MCPD) and 1,3-dichloro-2-propanol (1,3-DCP) are not only produced in the manufacturing process of foodstuffs such as hydrolyzed vegetable proteins and soy sauce but are also formed by heat processing in the presence of fat and low water activity. 3-MCPD exists both in free and ester forms, and the ester form has been also detected in various foods. Free 3-MCPD and 1,3-DCP are classified as Group 2B by the International Agency for Research on Cancer. Although th...

  5. Synthesis and Immobilization of Pt Nanoparticles on Amino-Functionalized Halloysite Nanotubes toward Highly Active Catalysts

    Directory of Open Access Journals (Sweden)

    Tingting Yang

    2015-02-01

    Full Text Available A simple and effective method for the preparation of platinum nanoparticles (Pt NPs grown on amino-func‐ tionalized halloysite nanotubes (HNTs was developed. The nanostructures were synthesized through the func‐ tionalization of the HNTs, followed by an in situ approach to generate Pt NPs with diameter of approximately 1.5 nm within the entire HNTs. The synthesis process, composition and morphology of the nanostructures were characterized. The results suggest PtNPs/NH2-HNTs nanostructures with ultrafine PtNPs were successfully synthesized by green chemically-reducing H2PtCl6 without the use of surfactant. The nanostructures exhibit promising catalytic properties for reducing potassium hexacyanoferrate(III to potassium hexacyanoferrate(II. The presented experiment for novel PtNPs/NH2-HNTs nanostructures is quite simple and environmentally benign, permitting it as a potential application in the future field of catalysts.

  6. Effect of Ni doping on the structural and magnetic properties of FePt nanoparticles

    International Nuclear Information System (INIS)

    Yang, H.-W.; Chung, C.-M.; Ding, Jack Y.

    2007-01-01

    A serial of FePtNi nanoparticles were investigated on their crystal structure and magnetic properties. The FePtNi nanoparticles were synthesized simultaneously by the reduction of iron (III) acetylacetonate, platinum (II) acetylacetonate and nickel (II) acetylacetonate with 1,2-hexadecanediol as the reducing agent. The X-ray diffraction patterns indicate that the addition of 8, 12, 17 at% Ni in FePt nanoparticles suppressed the transformation of the particles from disorder face-centered cubic to order face-centered tetragonal L1 0 -phase under annealing treatment. However, further increasing Ni contents to 21 at%, the nanoparticle transformed to L1 2 phase. Doping of Ni into the FePt compound system may decrease coercivity and crystal anisotropy energy. A maximum coercivity of 7 KOe at room temperature was obtained for (Fe 52 Pt 48 ) 92 Ni 8 nanoparticles after annealing at 600 deg. C for 30 min

  7. Application of PIXE, NAA and other techniques to the determination of toxic elements in Bangladesh foodstuffs and drinking waters

    International Nuclear Information System (INIS)

    Tarafdar, S.A.; Khan, A.H.

    1988-01-01

    The main objective of the food monitoring programme is to study the applicability of PIXE, XRF, NAA and other related methods to toxic and essential trace elements analyses in foodstuffs and drinking water under the coordinated research programme of the IAEA and to collect baseline data on the status of such elements in foodstuffs and drinking water. The commonly consumed representative foodstuffs selected for Bangladesh are: rice, wheat, green vegetables, fish, milk and egg. In the previous year, only food items were studied but in this report drinking water is also included. The elements required by the project protocol are Cu, Cr, Fe, As, Se, Sb, Cd, Pb and Hg. In this report, the results obtained during the last contract period are presented with a plan for future work. 4 refs, 2 tabs

  8. Sensitivity of radiation monitoring systems in Manila Ports in detecting contamination in foodstuff shipments

    International Nuclear Information System (INIS)

    Romallosa, Kristine Marie D.; Caseria, Estrella S.; Piquero, Ronald E.; Agustin, Jan Aldrich A.

    2011-01-01

    During the Fukushima Nuclear Power Plant accident in Japan, one of the Philippines' measures to protect the public from radiological hazards of the accident is by monitoring agricultural and food imports for radioactive contamination. In this study, the sensitivity of the mobile Radiation Monitoring System (RM) in Manila Ports in detecting contamination in incoming foodstuff shipments was determined. Large volume synthetic 137 Cs reference sources were used to determine the minimum detectable concentration (MDC) of the RMS. The reference sources have radioactivity concentrations that are comparable to the PNRI guidance level of 1000 Bg/kg for 137 Cs that is destined for general consumption. Results of the MDC measurements show that the RMS units are sensitive enough to detect radioactivity levels that are within the guidance levels provided that a) the minimum package lot is approximately 200 kg, b) the package is positioned at the detector side, and c) the alarm setting of RMS is as calibrated. It was therefore established that the RMS can be used to initially screen incoming foodstuff shipments of possible contamination and thereby help minimize potential radiation exposures to the public. (author)

  9. The proportion of unhealthy foodstuffs children are exposed to at the checkout of convenience supermarkets.

    Science.gov (United States)

    Horsley, Jason A; Absalom, Katie Ar; Akiens, Evie M; Dunk, Robert J; Ferguson, Alice M

    2014-11-01

    To investigate the proportion of foods that are unhealthy to which children are exposed at the checkout of convenience supermarkets. We performed a cross-sectional survey of foodstuffs displayed at the checkout. Products displayed at or below children's eye-level were designated as healthy, unhealthy or unclassifiable using the Food Standards Agency's scoring criteria. Thirteen convenience supermarkets from the three leading UK supermarket chains were selected on the basis of proximity to the town hall in Sheffield, England. Convenience supermarkets were defined as branches of supermarket chains that were identified as being other than superstores on their company's store locator website. In almost all of the convenience supermarkets surveyed, the main healthy product on display was sugar-free chewing gum. On average, when chewing gum was not included as a foodstuff, 89% of the products on display at the checkouts of convenience supermarkets were unhealthy using the Food Standards Agency's criteria. One store was a notable outlier, providing only fruit and nuts at its checkout. The overwhelming majority of products to which children are exposed at the convenience supermarket checkout are unhealthy. This is despite all the supermarket chains surveyed having signed up to the UK Government's 'responsibility deal'.

  10. Image analysis of food particles can discriminate deficient mastication of mixed foodstuffs simulating daily meal.

    Science.gov (United States)

    Sugimoto, K; Hashimoto, Y; Fukuike, C; Kodama, N; Minagi, S

    2014-03-01

    Because food texture is regarded as an important factor for smooth deglutition, identification of objective parameters that could provide a basis for food texture selection for elderly or dysphagic patients is of great importance. We aimed to develop an objective evaluation method of mastication using a mixed test food comprising foodstuffs, simulating daily dietary life. The particle size distribution (>2 mm in diameter) in a bolus was analysed using a digital image under dark-field illumination. Ten female participants (mean age ± s.d., 27·6 ± 2·6 years) masticated a mixed test food comprising prescribed amounts of rice, sausage, hard omelette, raw cabbage and raw cucumber with 100%, 75%, 50% and 25% of the number of their masticatory strokes. A single set of coefficient thresholds of 0·10 for the homogeneity index and 1·62 for the particle size index showed excellent discrimination of deficient masticatory conditions with high sensitivity (0·90) and specificity (0·77). Based on the results of this study, normal mastication was discriminated from deficient masticatory conditions using a large particle analysis of mixed foodstuffs, thus showing the possibility of future application of this method for objective decision-making regarding the properties of meals served to dysphagic patients. © 2014 John Wiley & Sons Ltd.

  11. Foodstuff survey around a major nuclear facility with test of satellite images application

    International Nuclear Information System (INIS)

    Twining, S.; Strydom, J.; Rosson, R.; Koffman, L.; Fledderman, P.; Kahn, B.

    2000-01-01

    A foodstuff survey was performed around the Savannah River Site, Aiken, South Carolina. It included a census of buildings and fields within 5 km of the boundary and determination of the locations and amounts of crops grown within 80 km of the Savannah River Site center. Recent information for this region was collected on the amounts of meat, poultry, milk, and eggs produced, of deer hunted, and of sports fish caught. The locations and areas devoted to growing each crop were determined by the usual process of applying county agricultural statistics reported by state agencies. This process was compared to crop analysis of two LANDSAT Thematic Mapper images. For use with environmental radionuclide transfer and radiation dose calculation codes, locations within 80 km were defined for 64 sections by 16 sectors centered on the site and by 16-km distance intervals from 16 km to 80 km. The median areas per section devoted to each of four food crops based on county agricultural statistics were about two-thirds of those based on satellite image analysis. Most locally-raised foodstuff was distributed regionally and not retained locally for consumption

  12. Application of neutron activation analysis to the detrmination of toxic elements in Australian foodstuffs

    International Nuclear Information System (INIS)

    Fardy, J.J.; McOrist, G.D.; Farrar, Y.J.; Gorman, T.F.; Bowles, C.H.; Tan Mingguang

    1988-01-01

    Recent measurements in our laboratory have indicated that the average selenium content in the plasma of Australians is 0.09 mg L -1 which is significantly lower than that found in the inhabitants of most other Western countries with the exception of New Zealand. Research aimed at explaining these low levels had begun when an invitation was received from the IAEA to join a Coordinated Research Programme on Nuclear Techniques for Toxic Elements in Foodstuffs. The investigation was widened, therefore, to include other toxic elements, arsenic, mercury, zinc and antimony and the suite of trace elements determined by neutron activation analysis (NAA) techniques. To complete the survey of toxic elements, the lead and cadmium of the chosen foodstuffs are being analysed by anodic stripping voltammetry (ASV) and soon will be examined by inductively coupled plasma mass spectrometry (ICPMS). Drinking water from a number of locations were sampled in cleaned, screw-top polystyrene containers, frozen and stored in a freezer until ready for analysis. 7 refs, 4 figs, 4 tabs

  13. Nutritional Concepts and Frequency of Foodstuffs Mentioned in the Holy Quran.

    Science.gov (United States)

    Tarighat-Esfanjani, Ali; Namazi, Nazli

    2016-06-01

    The Holy Quran is a religious book of Muslims. In many verses of Quran, various foods are discussed. It seems that limited studies were performed on identification the nutritional verses and their frequencies in the Holy Quran. Therefore, the aims of present study were to establish a numerical model system for studying nutritional verses of Quran, determination of verses with nutritional concepts and frequency of foodstuffs in the Holy Quran. In this descriptive analytical study, "Ghamoos e Quran" and "Vazheyab" online softwares were used to determine the nutritional keywords in Quran. For searching, translating, and interpretation of verses, "Noor-e-Jami Tafasir version 2.1"; "Zekr" and "Pars Quran"softwares were applied. Sixty-four nutritional keywords and 257 nutritional verses were identified. Findings indicated that aliment/foods, eating, water/drinking words, and their derivatives are repeated 171, 109, and 131 times in the Holy Quran, respectively. According to the Holy Quran, except Haram foods (pork meat, wine, carrion meat, blood, and meat of animals not slaughtered properly in the Islamic manner), all foods are tayyeb (lawful). The Holy Quran contains many foodstuffs and verses with nutritional concepts and it recommends eating varied and balanced diet.

  14. Application of neutron activation analysis to the monitoring of trace elements in Brazilian foodstuffs

    International Nuclear Information System (INIS)

    Vasconcellos, M.B.A.; Maihara, V.A.; Munita, C.J.A.S.; Favaro, D.I.T.; Armelin, M.J.A.

    1994-01-01

    Due to lack of data on trace element levels in Brazilian foodstuffs, nuclear analytical techniques were used to determine about twenty elements in foods samples collected from local markets of the city of Sao Paulo. Drinking water was also analyzed. The methods employed were mainly instrumental and radiochemical neutron activation analysis. In the case of the analysis of toxic elements, such as mercury, selenium, arsenic and antimony, the purely instrumental approach failed in yielding results for very low concentrations of these elements. For INAA, samples and multielemental synthetic standards were irradiated in the IEA R1 research reactor for periods of time ranging from minutes to several hours, under thermal neutron fluxes from 10 11 to 10 13 n·cm -2 ·s -1 ; after suitable cooling times, γ-ray spectra were measured using a Ge(Li) or Ge solid state detector. The RNAA approach involved the distillation of mercury and selenium in HBr medium; selenium was then reduced to the metal form with sodium metabisulphide and mercury was precipitated as sulphide with thioacetamide. For water analysis, a preconcentration procedure based on retention of several elements in a Chelex-100 resin was employed. The elements retained were Hg, Cr, Zn, Fe, Co while Se was measured in the effluent after absorption on active charcoal. The levels of the trace inorganic elements determined in the Brazilian foodstuffs analyzed were always below the levels established by the existing regulations in our country. (author). 16 refs, 18 tabs

  15. Activity concentrations and mean annual effective dose of foodstuffs on the island of Tenerife (Spain))

    International Nuclear Information System (INIS)

    Hernandez, F.; Hernandez-Armas, J.; Catalan, A.; Fernandez-Aldecoa, J. C.; Landeras, M. I.

    2004-01-01

    A total of 26 different food types and 12 elaborated diets were analysed by low-level gamma spectrometry to measure their content of 238 U( 234 Th), 228 Ra( 228 Ac), 226 Ra( 214 Pb), 210 Pb, 137 Cs and 40 K. The concentrations of these radionuclides measured in some imported foodstuffs were compared with those measured in some locally produced ones. Moreover, the concentrations found in the analysed foodstuffs and composite diets were compared with the data available in literature from other locations, such as Egypt (Brazil)) (Poland)) and Hong Kong. 40 K contributed highest to the daily dose produced by the intake of comestibles. The largest 40 K concentrations were measured in the chickpeas and beans with 380 ± 30 and 380 ± 20 Bq kg -1 fresh weights, respectively. The artificial radionuclide 137 Cs was measured only above detection limits in the potatoes and sweet potatoes. A mean annual effective dose of 362 μSv with a standard deviation of 110 μSv was calculated from the composite diets. (authors)

  16. [Survey of aflatoxins contamination of foodstuffs and edible oil in Shenzhen].

    Science.gov (United States)

    Li, Ke; Qiu, Fen; Yang, Mei; Liang, Zhaohai; Zhou, Haitao

    2013-07-01

    To identify the aflatoxins contamination of foodstuffs and edible oil sold in Shenzhen. As research subjects stratified random sampling of 238 foodstuffs and edible oil, and applied with immuno-affinity column clean-up plus UPLC to determine the content of aflatoxin B1, B2, G1, and G2. Positive ratio of aflatoxin in rice, rice products, wheat flour, corn flour, edible oil were 35.3%, 33.8%, 13.9%, 46.7% and 24.5%,respectively. There were statistical differences between the positive ratio of aflatoxin in stereotypes packaged rice (26.5%) and bulk rice (56.3%) (chi2 = 11.6, P edible oil,respectively. The over standard rate of aflatoxin B1 was 5.66%, excessive samples were producted bulk and self-pressed peanut oil from unlicensed workshop. All the four kinds of aflatoxin were detected, while subtype B1 and B2 dominated aflatoxin contamination in the rice and edible oil samples. There are differences between in the northern and southern rice, and the same as in the stereotypes packaged and bulk rice sold at Shenzhen.

  17. Radioactivity in foodstuffs and doses to the Norwegian population from the Chernobyl fall-out

    International Nuclear Information System (INIS)

    Strand, T.; Strand, P.; Baarli, J.

    1987-01-01

    The doses to the Norwegian population from foodstuffs after the fall-out from the Chernobyl accident are discussed. Based on the results of a 'food basket' project and supplementary data from the approx. 30,000 measurements on food samples during the first year after the accident, the total annual effective dose equivalent from foodstuffs to an average Norwegian consumer during the first year after the accident was estimated to be 0.15 ± 0.02 mSv at the 95% confidence level. The contribution from 131 I was estimated to be less than 3% of the total effective dose equivalent in the first year. The individual doses, however, depend very much on dietary habits. The southern Lapps are probably the population receiving the highest doses. Individual reindeer-breeding Lapps, neglecting some of the dietary guidelines from the health authorities, may have received an effective dose equivalent of 20-30 mSv in the first year after the accident. (author)

  18. Evidence of Allergic Reactions and Cardiopulmonary Impairments among Traders Operating from Foodstuff Warehouses

    Directory of Open Access Journals (Sweden)

    Sam Ibeneme

    2016-01-01

    Full Text Available Background. Foodstuff traders operating from warehouses (FTFW are potentially exposed to dangerous rodenticides/pesticides that may have adverse effects on cardiopulmonary function. Methods. Fifty consenting male foodstuff traders, comprising 15 traders (21–63 years operating outside warehouses and 35 FTFW (20–64 years, were randomly recruited at Ogbete Market, Enugu, in a cross-sectional observational study of spirometric and electrocardiographic parameters. Seventeen FTFW (21–57 years participated in focus group discussions. Qualitative and quantitative data were analysed thematically and with independent t-test and Pearson correlation coefficient at p0.05 with a significantly prolonged (p<0.05 QTc interval. Conclusion. Allergic response was evident in the FTFW. Significant decrease in FVC may negatively impact lung flow rates and explains the marginal decrease in FEF25–75, which implies a relative limitation in airflow of peripheral/distal airways and elastic recoil of the lungs. This is consistent with obstructive pulmonary disease; a significant decrease in FEF75–85/FEV1 supports this conclusion. Significant decrease in FEF200–1200 indicates abnormalities in the large airways/larynx just as significantly prolonged ventricular repolarization suggests cardiac arrhythmias.

  19. Development of novel potentiometric sensors for determination of tartrazine dye concentration in foodstuff products.

    Science.gov (United States)

    Abu Shawish, Hazem M; Ghalwa, Nasser Abu; Saadeh, Salman M; El Harazeen, Heba

    2013-05-01

    Tartrazine dye Na(3)TZ in foodstuff products was determined by a new modified carbon paste electrode, encoded sensor A, and a coated silver wire electrode, encoded sensor B, based on tartrazine TZ- cetryltrimethyl ammoniumbromide CTAB as a chemical modifier TZ-CTA. The electrodes exhibit the following characteristics listed respectively: a Nernstian slope of 17.9±0.5 and 19.4±0.2 mV/decade for tartrazine ion over a wide concentration range from 4.3×10(-7) to 1.0×10(-2) and 1.1×10(-7) to 1.0×10(-2) M. The lower detection limits: 3.2×10(-7) and 5.5×10(-8) M. Short response time (5-8 s) over the pH range 3.8-7.7 and 4.2-8.1. The proposed sensors display significantly high selectivity for TZ ion over a wide variety of sugars, some anions, common organic, inorganic compounds and additives. The developed electrodes were applied to the potentiometric determination of tartrazine ion in different kinds of foodstuffs: solid jelly (strawberry and custard) powder samples and soft drink (orange) samples with satisfactory results. Copyright © 2012 Elsevier Ltd. All rights reserved.

  20. Management of radioactive contaminated foodstuffs and consumer goods in Spain. Establishment of a common framework

    Energy Technology Data Exchange (ETDEWEB)

    Trueba, C.; Montero, M.; Oltra, C.; Sala, R. [Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas - CIEMAT (Spain); Gallego, E. [Escuela Tecnica Superior de Ingenieros Industriales - UPM-ETSII (Spain)

    2014-07-01

    In the event of a nuclear accident with radiological consequences affecting the quality of foodstuffs, feed-stuffs and in general, consumer goods, the European Union and its Member States, have developed radiation protection general guidelines to manage such situations. In this context, there are recommendations and standards, at international (Codex Alimentarius -FAO/OMS-, IAEA) and regional levels (EURATOM Directives) based on activity concentrations in different products and maximum permitted levels of radioactive contamination of foodstuffs. These levels are based on certain assumptions about the consumption of contaminated products. However, the application of these guidelines is not easy, as shown after the Chernobyl and Fukushima accidents. Several factors converge in this situation. First, is the national regulation of each country, that can decide on the maximum radioactivity levels in food consumed within the country. Other is the misinterpretation of the guidelines that where originally developed for specific conditions. Finally, rejection attitudes of consumers and general public towards foodstuffs, feed-stuffs and goods according to their provenience, must also be taken into account. Aware of this reality, the European Union is funding within its 7. Framework Programme for R and D projects to help optimize European response to radiological emergencies, including those involving contaminated foodstuffs and consumer goods. Specifically, this is the overall objective of the PREPARE Project (Innovative Integrative Tools and Platforms to be Prepared for Radiological Emergencies and Post-Accident Response in Europe) within the framework of NERIS Platform (European Platform on Preparedness for Nuclear and Radiological Emergency Response and Recovery). PREPARE project is intended to develop strategies, guidelines and tools for the management of foodstuffs and consumer goods contaminated with radioactivity, considering not only the Public Administration, as

  1. ANALISIS KINERJA KEUANGAN PADA PT PERKEBUNAN NUSANTARA XIV MAKASSAR

    Directory of Open Access Journals (Sweden)

    Jefri Dominggus Simon

    2017-08-01

    Full Text Available JEFRI DOMINGGUS SIMON.2017. Thesis.4513012048. "Financial Performance Analysis at PT Perkebunan Nusantara XIV Makassar". (Mentored by Dr.Miah Said, SE., M.Si as consultant I and Muh.Kafrawi Yunus, SE., MM as consultant II. This study aims to analyze the financial performance of PT Perkebunan Nusantara XIV Makassar during 2013 until 2015 by using ratio analysis: Liquidity, solvency, Activity and Profitability. The results of this study indicate that based on Liquidity ratios including Current ratio, Quick ratio and Cash ratio has increased. In general, the ratio of Solvency is in a less good position, while for Profitability ratio of receivables turnover, inventory turnover and asset turnover fluctuated. In general, the activity ratio of PT Perkebunan Nusantara XIV Makassar in the period of 2013 to 2015 has decreased

  2. ANALISA ELECTRODE CONSUMABLE TYPE OK AUTROD 12.10 PENGELASAN SUBMERGED ARC WELDING PADA BLOK-BLOK KAPAL DCV 18500 DWT DI PT. JASA MARINA INDAH UNIT II SEMARANG

    Directory of Open Access Journals (Sweden)

    Sukanto Jatmiko

    2012-07-01

    Full Text Available In this globalization era technological advances growed very fast. In shipping industry of development process shipbuilding of principal feedstock to used steel plate, with construction tacking on using welder method.In this research purpose of lifted is know number of requirement (consumable electrode for welder SAW at block-block ship DCV 18500 DWT in PT. Jasa Marina Indah Semarang.At this experiment specimen applied is low carbon steel of type ST 42 with thickness of 12, 13, 14, 17, 19 dan 24 mm. Research is done by the way of making specimen at every plate thickness. Then is done path measurement of length, used electrode length, and weight flux applied at the welder.From result of gauging and data calculation welder at block DB 5(p/c/s, SS5A(p/s, SS 5B(p/s, UD 5C, and TB 102 (p/c/s will be known number of electrodes applied in welder SAW and number of flux used.

  3. Ex-vessel boiling experiments: laboratory- and reactor-scale testing of the flooded cavity concept for in-vessel core retention. Pt. II. Reactor-scale boiling experiments of the flooded cavity concept for in-vessel core retention

    International Nuclear Information System (INIS)

    Chu, T.Y.; Bentz, J.H.; Slezak, S.E.; Pasedag, W.F.

    1997-01-01

    For pt.I see ibid., p.77-88 (1997). This paper summarizes the results of a reactor-scale ex-vessel boiling experiment for assessing the flooded cavity design of the heavy water new production reactor. The simulated reactor vessel has a cylindrical diameter of 3.7 m and a torispherical bottom head. Boiling outside the reactor vessel was found to be subcooled nucleate boiling. The subcooling mainly results from the gravity head, which in turn results from flooding the side of the reactor vessel. The boiling process exhibits a cyclic pattern with four distinct phases: direct liquid-solid contact, bubble nucleation and growth, coalescence, and vapor mass dispersion. The results show that, under prototypic heat load and heat flux distributions, the flooded cavity will be effective for in-vessel core retention in the heavy water new production reactor. The results also demonstrate that the heat dissipation requirement for in-vessel core retention, for the central region of the lower head of an AP-600 advanced light water reactor, can be met with the flooded cavity design. (orig.)

  4. Pt/C Fuel Cell Catalyst Degradation

    DEFF Research Database (Denmark)

    Zana, Alessandro

    This thesis investigates the degradation behavior of Pt/C catalysts under simulated automotive conditions. By using the “tool box” synthesis method the Pt loading has been changed from low to high Pt loadings, therefore permitting to study the role of Pt on the degradation of high surface area (H...

  5. Single-Crystalline cooperite (PtS): Crystal-Chemical characterization, ESR spectroscopy, and {sup 195}Pt NMR spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Rozhdestvina, V. I., E-mail: veronika@ascnet.ru; Ivanov, A. V.; Zaremba, M. A. [Far East Division, Russian Academy of Sciences, Institute of Geology and Nature Management (Russian Federation); Antsutkin, O. N.; Forsling, W. [Lulea University of Technology (Sweden)

    2008-05-15

    Single-crystalline cooperite (PtS) with a nearly stoichiometric composition was characterized in detail by X-ray diffraction, electron-probe X-ray microanalysis, and high-resolution scanning electron microscopy. For the first time it was demonstrated that {sup 195}Pt static and MAS NMR spectroscopy can be used for studying natural platinum minerals. The {sup 195}Pt chemical-shift tensor of cooperite was found to be consistent with the axial symmetry and is characterized by the following principal values: {delta}{sub xx} = -5920 ppm, {delta}{sub yy} = -3734 ppm, {delta}{sub zz} = +4023 ppm, and {delta}{sub iso} = -1850 ppm. According to the ESR data, the samples of cooperite contain copper(II), which is adsorbed on the surface during the layer-by-layer crystal growth and is not involved in the crystal lattice.

  6. Magnetic behavior in heterometallic one-dimensional chains or octanuclear complex regularly aligned with metal-metal bonds as -Rh-Rh-Pt-Cu-Pt

    Science.gov (United States)

    Uemura, Kazuhiro

    2018-06-01

    Heterometallic one-dimensional chains, [{Rh2(O2CCH3)4}{Pt2Cu(piam)4(NH3)4}]n(PF6)2n (1 and 2, piam = pivalamidate) and [{Rh2(O2CCH3)4}{Pt2Cu(piam)4(NH3)4}2](CF3CO2)2(ClO4)2·2H2O (3), are paramagnetic one-dimensional chains or octanuclear complexes that are either aligned as -Rh-Rh-Pt-Cu-Pt- (1 and 2) or as Pt-Cu-Pt-Rh-Rh-Pt-Cu-Pt (3) with metal-metal bonds. Compounds 1-3 have rare structures, from the standpoint of that the paramagnetic species of Cu atoms are linked by direct metal-metal bonds. Magnetic susceptibility measurements for 1-3 performed at temperatures of 2 K-300 K indicated that the unpaired electrons localize in the Cu 3dx2-y2 orbitals, where S = 1/2 Cu(II) atoms are weakly antiferromagnetically coupled with J = -0.35 cm-1 (1), -0.47 cm-1 (2), and -0.45 cm-1 (3).

  7. internal radiation dose assessment due to ionizing radio contaminants in some local foodstuffs

    International Nuclear Information System (INIS)

    AbdElKader, F.M.

    1996-01-01

    Over the last 30 years, radioactivity has been monitored in foodstuffs in Egypt. The present work deals with the radioactivity monitored during two years (1990 - 1992) at eight major Egyptian governorates. Sampled food items were selected to cover most foodstuffs eaten by egyptian population according to their habits. The daily food consumption by egyptian population and the constituents of such consumption were estimated according to published international data and knowledge of the different feeding habits of the egyptians. About 1200 samples were collected from the markets of the main city of each governorate and prepared for counting according to the egyptian kitchen habits. The counting systems used in determination and indentification of radionuclides were : a 3 inch HPGe detector attached to 800 channel MCA and PC and a 3 inch phoswich detector attached to an anticoincidence circuit for low beta / gamma counting. The gamma spectroscopy system was calibrated using isotopic solution mixture while the low beta counting system was calibrated using H CI. Counting time for the first system was 20 - 72 hours and for the second system was half to one hour. The main radionuclides identified in foodstuffs were Cs - 137 and K - 40 . The radioactivity concentration of Cs - 137 was found to be in the range between 1.0 Bq / Kg for macaroni and 3.5 Bq / Kg for nile beans. The K - 40 concentration range between 19 Bq / Kg for macaroni to 363 Bq / Kg for nile beans. The population weighted values in case of Cs - 137 was found as 3.56 Bq /d and for K - 40 was 188 Bq /d. The resulted effective dose due to food intake was found be 16 . 4 U Sv /a for Cs-137 and 354 μSv / a for K -40 . This value for Cs - 137 is found in the exemption limit while that of K -40 is twice the published value. This may depend on the egyptian feeding habit which depends mainly on wheat (bread) and nile beans which are very rich in potassium.The resulted collective dose was found to be : 21323 person

  8. Health risk assessment from contaminated foodstuffs: a field study in chromite mining-affected areas northern Pakistan.

    Science.gov (United States)

    Nawab, Javed; Li, Gang; Khan, Sardar; Sher, Hassan; Aamir, Muhammad; Shamshad, Isha; Khan, Anwarzeb; Khan, Muhammad Amjad

    2016-06-01

    This study aimed to investigate the potential health risk associated with toxic metals in contaminated foodstuffs (fruits, vegetables, and cereals) collected from various agriculture fields present in chromite mining-affected areas of mafic and ultramafic terrains (northern Pakistan). The concentrations of Cr, Ni, Zn, Cd, and Pb were quantified in both soil and food samples. The soil samples were highly contaminated with Cr (320 mg/kg), Ni (108 mg/kg), and Cd (2.55 mg/kg), which exceeded their respective safe limits set by FAO/WHO. Heavy metal concentrations in soil were found in the order of Cr>Ni>Pb>Zn>Cd and showed significantly (p pollution load index (PLI) value was observed greater than three indicating high level of contamination in the study area. The concentrations of Cr (1.80-6.99 mg/kg) and Cd (0.21-0.90 mg/kg) in foodstuffs exceeded their safe limits, while Zn, Pb, and Ni concentrations were observed within their safe limits. In all foodstuffs, the selected heavy metal concentrations were accumulated significantly (p 1 for children and can pose potential health threats for local inhabitants. Graphical Abstract Heavy metals released from chromite mining lead to soil and foodstuff contamination and human health risk.

  9. Development of a Method to Isolate Glutamic Acid from Foodstuffs for a Precise Determination of Their Stable Carbon Isotope Ratio.

    Science.gov (United States)

    Kobayashi, Kazuhiro; Tanaka, Masaharu; Yatsukawa, Yoichi; Tanabe, Soichi; Tanaka, Mitsuru; Ohkouchi, Naohiko

    2018-01-01

    Recent growing health awareness is leading to increasingly conscious decisions by consumers regarding the production and traceability of food. Stable isotopic compositions provide useful information for tracing the origin of foodstuffs and processes of food production. Plants exhibit different ratios of stable carbon isotopes (δ 13 C) because they utilized different photosynthetic (carbon fixation) pathways and grow in various environments. The origins of glutamic acid in foodstuffs can be differentiated on the basis of these photosynthetic characteristics. Here, we have developed a method to isolate glutamic acid in foodstuffs for determining the δ 13 C value by elemental analyzer-isotope-ratio mass spectrometry (EA/IRMS) without unintended isotopic fractionation. Briefly, following acid-hydrolysis, samples were defatted and passed through activated carbon and a cation-exchange column. Then, glutamic acid was isolated using preparative HPLC. This method is applicable to measuring, with a low standard deviation, the δ 13 C values of glutamic acid from foodstuffs derived from C3 and C4 plants and marine algae.

  10. 31 CFR 560.534 - Importation into the United States of, and dealings in, certain foodstuffs and carpets authorized.

    Science.gov (United States)

    2010-07-01

    ... Policy § 560.534 Importation into the United States of, and dealings in, certain foodstuffs and carpets... under chapters 2-23 of the Harmonized Tariff Schedule of the United States; (2) Carpets and other... 9706.00.0060 of the Harmonized Tariff Schedule of the United States. (b) United States persons...

  11. Klinische betekenis van extra vitaminen uit supplementen en verrijkte voedingsmiddelen [Clinical importance of extra vitamins from supplements and enriched foodstuffs

    NARCIS (Netherlands)

    Hermus, R.J.J.; Severs, A.H.

    1999-01-01

    -Consumers increasingly use vitamin supplements. Also, since June 1996, foodstuffs enriched with vitamins are available on the Dutch market. -These sources of extra vitamins may be useful for groups at risk for marginal vitamin deficiencies. -These risk groups include the chronically ill (e.g.

  12. Asymptotic properties of solvable PT-symmetric potentials

    International Nuclear Information System (INIS)

    Levai, G.

    2010-01-01

    states. The examples included the Scarf II potential V(x) = - V 1 /cosh 2 x + iV 2 sinhx/cosh 2 x; (1) the Rosen-Morse II potential V(x) -V 1 /cosh 2 (x) + iV 3 tanh(x) (2) and the Coulomb potential V(x) = iZ/t + l(l + 1)/t 2 . (3) Potentials (1) and (2) are both defined on the real x axis, and their real components have the same form, while potential (3) is defined on a U-shaped trajectory running on both sides of the imaginary x axis encircling the origin. Despite these circumstances, we found that the bound-state properties of potential (1) show more similarity with those of (3) than with those of (2). The former two systems possess strictly negative-energy bound states that are characterized by the q = ±1 quantum number. Reaching a critical value of V 2 - V 1 and l the spontaneous breakdown of PT symmetry occurs and the bound states with opposite q merge pairwise and their energy eigenvalues turn complex for arbitrary value of the n principal quantum number. In contrast, the energy eigenvalues of potential (2) stay real for arbitrary value of V 1 and V 3 and do not carry the q quantum number. The spontaneous breakdown of PT symmetry does not occur in this case, rather with increasing non-hermeticity the energy eigenvalues are gradually shifted to the positive domain. The properties of potential (2) are reminiscent of the purely imaginary ix 3 potential, the classic example of PT-symmetric quantum mechanics. The marked differences described above, which, however, do not show up in the scattering solutions, might be due to the asymptotically dominant and non-vanishing imaginary component in (2).

  13. Toxicological exposure of man to environment-borne organomercury compounds via foodstuff of animal origin

    Energy Technology Data Exchange (ETDEWEB)

    Kuehnert, M.; Fuchs, V.; Doelle, E.A.

    1983-01-01

    An assessment was made of the 'background' situation regarding biotope contamination (soil, plants, water) by the heavy metal mercury, with particular attention being given to organomercury compounds which are contained in seed dressing substances. Peculiarities of toxic action and its biological implications are discussed by the example of methylated mercury. Mercury exposure of living farm animals, such as poultry, cattle, and swine, due to indirect contact with seed dressing agents together with aspects of food hygiene and with the legal situation in the GDR are assessed and reported on the basis of experimental findings. Conclusions are suggested for practical handling of results obtained from residue toxicology, with the view to ensuring observance of tolerances in animal-based foodstuff.

  14. Applications of stable isotope analysis in foodstuffs surveillance and environmental research

    International Nuclear Information System (INIS)

    Pichlmayer, F.; Blochberger, F.

    1991-12-01

    The instrumental coupling of Elemental Analysis and Mass Spectrometry, constituting a convenient tool for isotope ratio measurements of the bioelements in solid or liquid samples is now well established. Advantages of this technique compared with the so far usual wet chemistry sample preparation are: speed of analysis, easy operation and minor sample consumption. The performance of the system is described and some applications are given. Detection of foodstuffs adulterations is mainly based on the natural carbon isotope differences between C 3 - and C 4 -plants. In the field of environmental research the existing small isotopic variations of carbon, nitrogen and sulfur in nature, which depend on substance origin and history, are used as intrinsic signature of the considered sample. Examples of source appointment or exclusion by help of this natural isotopic tracer method are dealt with. (authors)

  15. The aftermath of Chernobyl in Sweden: Levels of 137Cs in foodstuffs

    International Nuclear Information System (INIS)

    Mascanzoni, D.

    1986-01-01

    The insertion and subsequent accumulation of radioactive substances in ecosystem focuses attention on a highly complex set of natural processes. In a health perspective, it poses particular concern for the food chain. In order to issue action guidelines and to reduce the doses from intake of contaminated food, an extensive program of measurements was started. The primary aim of the monitoring was to obtain a detailed survey of contents of radionuclides in a wide variety of foodstuffs, including vegetables, fruits, edible wild plants, dairy products, wild and tame animals. The results presented in this report cover the period May-November 1986 and concern only the food samples collected in order to be able to issue recommendations to the public in the most contaminated areas. (orig./PW)

  16. Investigations of the potential bioavailability of 210Po in some foodstuffs

    International Nuclear Information System (INIS)

    Bulman, Robert A.; Ewers, Leon W.; Matsumoto, Kiyoshi

    1995-01-01

    Extraction of 210 Po from lamb's liver, pig's kidneys, mussel flesh and brown crabmeat with a series of solvent systems has been used to gain some insight into the uncertainty about the gastrointestinal absorption factor for Po incorporated into foodstuffs. By extracting the tissues with diethyldithiocarbamate dissolved in chloroform, and also in methanol, it has been shown that 210 Po is more effectively extracted from lamb's liver and crabmeat than it is from each of the other tissues. A similar pattern of extractability is also evident for aqueous solutions of citric acid on crabmeat and mussel flesh. Of particular note is the low extractability by dimethylsulphoxide (3%) of 210 Po in mussel flesh as opposed to 24% extractability of 210 Po from crabmeat. 210 Po-binding macromolecules of about 10 kDa have been released from crabmeat and mussel flesh by digestion with pepsin

  17. Various approaches in EPR identification of gamma-irradiated plant foodstuffs: A review.

    Science.gov (United States)

    Aleksieva, Katerina I; Yordanov, Nicola D

    2018-03-01

    Irradiation of food in the world is becoming a preferred method for their sterilization and extending their shelf life. For the purpose of trade with regard to the rights of consumers is necessary marking of irradiated foodstuffs, and the use of appropriate methods for unambiguous identification of radiation treatment. One-third of the current standards of the European Union to identify irradiated foods use the method of the Electron Paramagnetic Resonance (EPR) spectroscopy. On the other hand the current standards for irradiated foods of plant origin have some weaknesses that led to the development of new methodologies for the identification of irradiated food. New approaches for EPR identification of radiation treatment of herbs and spices when the specific signal is absent or disappeared after irradiation are discussed. Direct EPR measurements of dried fruits and vegetables and different pretreatments for fresh samples are reviewed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Dynamics of Brokerage Positions in Clusters: Evidence from the Spanish Foodstuffs Industry

    Directory of Open Access Journals (Sweden)

    José Antonio Belso-Martínez

    2017-02-01

    Full Text Available Shifting away from traditional approaches orientated towards the analysis of the benefits associated with brokerage, this paper provides valuable insights into the dynamics of this network position and the opportunities to innovate that it provides. Using fine grain micro data collected in a foodstuff Spanish cluster, the evolution of different brokerage profiles is analyzed in depth. It was particularly evident how firm-level characteristics (status, former mediating experience and external openness and their interactions may generate changes in the different brokerage roles over a period of time. The findings of this work partially validate expectations based on the network dynamics approaches. Status and previous mediating experience facilitate the creation of partnerships, fostering brokerage. Conversely, interaction effects demote brokerage activity at the intra-cluster level, suggesting the selective nature of brokers’ relational behavior.

  19. Study of caesium contamination in foodstuffs in Ghana after the Chernobyl nuclear accident

    International Nuclear Information System (INIS)

    Darko, E.O.; Schandorf, C.; Yeboah, J.

    1996-01-01

    Fallout radioactivity has been studied in foodstuffs in the Environmental Monitoring Laboratory after the Chernobyl nuclear catastrophe. The study covers the analysis of reference samples of imported foods, mainly meat and milk, for 137 Cs and 134 Cs contamination using a low-level gamma spectrometer. The purpose of this study is to determine whether it is necessary to control food imports in order to reduce the risk from intake of radionuclides by the Ghanian public resulting from transboundary contamination. Measurement of caesium levels in various foods over a period of seven years has shown contamination to be within the recommended action levels for international trade in foods. The committed effective dose intakes in any single year is far below the 1 mSv annual dose recommended by the ICRP in Publication 60. (author)

  20. High-sensitivity determination of radioactive cesium in Japanese foodstuffs. 3 years after the Fukushima accident

    International Nuclear Information System (INIS)

    Katsumi Shozugawa; Mayumi Hori; Motoyuki Matsuo

    2016-01-01

    We analyzed 134 Cs, 137 Cs and 40 K in 96 foodstuffs in supermarkets with high sensitivity over 3 years after Fukushima accident. Milk, yoghurt, rice, tea, salmon, cereal, blueberry, miso, and apples had a trace of 134 Cs and 137 Cs from 10 -3 to 100 Bq/kg, however, some mushrooms that were bought in the outer Fukushima prefecture were contaminated by radioactive cesium over the regulatory limit (100 Bq/kg). In view of the 134 Cs/ 137 Cs radioactivity ratio, we can conclude that 137 Cs detected in remote areas 300 km or more from Fukushima Nuclear power plant contained activity from Pre-Fukushima events such as Chernobyl accident (1986) and atmospheric nuclear explosions (from 1945). (author)

  1. Concentration of 210Po in local foodstuffs grown nearby High Background Areas (HBRA)

    International Nuclear Information System (INIS)

    Kamesh Viswanathan, B.; Arunachalam, Kantha D.; Sathesh Kumar, A.; Jayakrishna, K.; Rao, D.D.

    2012-01-01

    210 Po is the decay product of natural radionuclide of 238 U series. The presence of a radionuclide migrates from soil > plant > food and ingested by the humans residing in the areas of syentite rocks nearby the High Background Radiation Area's (HBRA). The food samples were studied by Market Basket Study (MBS). The average concentration of 210 Po in foodstuffs like green leafy vegetables, other vegetables, roots and tubers; fruits, fish, other flesh foods, milk and cereals were 1671 ± 163.3, 28.2 ± 7.3, 320 ± 99, 53 ± 17.5, 251.5 ± 54.5, 37 ± 14.5, 16 ± 6 and 230 ± 75 mBq. Kg -1 fresh weight. (author)

  2. Quality Model of Foodstuff in the Control of Refrigerated Display Cabinet

    DEFF Research Database (Denmark)

    Cai, Junping; Risum, Jørgen; Thybo, Claus

    2006-01-01

    Commercial refrigerating systems need to be defrosted regularly to maintain a satisfactory performance. When defrosting the evaporator coil, the air temperature inside the display cabinet will increase, and float outside the normal temperature range for a period of time, the question is what...... happens to the food inside during this period, when we look at the quality factor? This paper discusses quality model of foodstuff, different scenarios of defrost scheme are simulated, questions such as how the defrost temperature and duration influence the food temperature, thus the food quality, as well...... as what is the optimal defrost scheme from food quality point of view are answered. This will serve as a prerequisite of designing of optimal control scheme for the commercial refrigeration system, aiming at optimizing a weighed cost function of both food quality and overall energy consumption of system....

  3. Background carbon-14 levels in UK foodstuffs, 1981-1995, based upon a 1992 survey

    International Nuclear Information System (INIS)

    Otlet, R.L.; Walker, A.J.; Fulker, M.J.; Collins, C.

    1997-01-01

    Knowledge of the current 'natural' background level is important to 14 C-related studies, especially dose assessments in the vicinity of and distant from nuclear establishments since its value must be subtracted from measured levels to determine local enhancement. Although measurements have been made world-wide to monitor the decline of the background level, from its peak in the early 1960s to the present, there exists a paucity of precise data for UK natural materials. Accordingly this study was carried out to establish an average figure for the 'natural' 14 C level in foodstuffs in 1992 from a survey of materials collected from a wide range of sites over England and Wales, using this single year value, to infill missing years prior to 1992 and to extrapolate from some years afterwards. Results are presented from the survey, and for the derived extrapolation with comparison made with measurements from other laboratories. (Author)

  4. Photoactivation of Diiodido-Pt(IV) Complexes Coupled to Upconverting Nanoparticles.

    Science.gov (United States)

    Perfahl, Stefanie; Natile, Marta M; Mohamad, Heba S; Helm, Christiane A; Schulzke, Carola; Natile, Giovanni; Bednarski, Patrick J

    2016-07-05

    The preparation, characterization, and surface modification of upconverting lanthanide-doped hexagonal NaGdF4 nanocrystals attached to light sensitive diiodido-Pt(IV) complexes is presented. The evaluation for photoactivation and cytotoxicity of the novel carboxylated diiodido-Pt(IV) cytotoxic prodrugs by near-infrared (NIR) light (λ = 980 nm) is also reported. We attempted two different strategies for attachment of light-sensitive diiodido-Pt(IV) complexes to Yb,Er- and Yb,Tm-doped β-NaGdF4 upconverting nanoparticles (UCNPs) in order to provide nanohybrids, which offer unique opportunities for selective drug activation within the tumor cells and subsequent spatiotemporal controlled drug release by NIR-to-visible light-upconversion: (A) covalent attachment of the Pt(IV) complex via amide bond formation and (B) carboxylate exchange of oleate on the surface of the UCNPs with diiodido-Pt(IV) carboxylato complexes. Initial feasibility studies showed that NIR applied by a 980 nm laser had only a slight effect on the stability of the various diiodido-Pt(IV) complexes, but when UCNPs were present more rapid loss of the ligand-metal-charge transfer (LMCT) bands of the diiodido-Pt(IV) complexes was observed. Furthermore, Pt released from the Pt(IV) complexes platinated calf-thymus DNA (ct-DNA) more rapidly when NIR was applied compared to dark controls. Of the two attachment strategies, method A with the covalently attached diiodido-Pt(IV) carboxylates via amide bond formation proved to be the most effective method for generating UCNPs that release Pt when irradiated with NIR; the released Pt was also able to bind irreversibly to calf thymus DNA. Nonetheless, only ca. 20% of the Pt on the surface of the UCNPs was in the Pt(IV) oxidation state, the rest was Pt(II), indicating chemical reduction of the diiodido-Pt(IV) prodrug by the UCNPs. Cytotoxicity studies with the various UCNP-Pt conjugates and constructs, tested on human leukemia HL60 cells in culture, indicated a

  5. An overview of the main foodstuff sample preparation technologies for tetracycline residue determination.

    Science.gov (United States)

    Pérez-Rodríguez, Michael; Pellerano, Roberto Gerardo; Pezza, Leonardo; Pezza, Helena Redigolo

    2018-05-15

    Tetracyclines are widely used for both the treatment and prevention of diseases in animals as well as for the promotion of rapid animal growth and weight gain. This practice may result in trace amounts of these drugs in products of animal origin, such as milk and eggs, posing serious risks to human health. The presence of tetracycline residues in foods can lead to the transmission of antibiotic-resistant pathogenic bacteria through the food chain. In order to ensure food safety and avoid exposure to these substances, national and international regulatory agencies have established tolerance levels for authorized veterinary drugs, including tetracycline antimicrobials. In view of that, numerous sensitive and specific methods have been developed for the quantification of these compounds in different food matrices. One will note, however, that the determination of trace residues in foods such as milk and eggs often requires extensive sample extraction and preparation prior to conducting instrumental analysis. Sample pretreatment is usually the most complicated step in the analytical process and covers both cleaning and pre-concentration. Optimal sample preparation can reduce analysis time and sources of error, enhance sensitivity, apart from enabling unequivocal identification, confirmation and quantification of target analytes. The development and implementation of more environmentally friendly analytical procedures, which involve the use of less hazardous solvents and smaller sample sizes compared to traditional methods, is a rapidly increasing trend in analytical chemistry. This review seeks to provide an updated overview of the main trends in sample preparation for the determination of tetracycline residues in foodstuffs. The applicability of several extraction and clean-up techniques employed in the analysis of foodstuffs, especially milk and egg samples, is also thoroughly discussed. Copyright © 2018 Elsevier B.V. All rights reserved.

  6. Foodstuff Survey Around a Major Nuclear Facility with Test of Satellite Image Application

    International Nuclear Information System (INIS)

    Fledderman, P.D.

    1999-01-01

    'A foodstuff survey was performed around the Savannah River Site, Aiken SC. It included a census of buildings and fields within 5 km of the boundary and determination of the locations and amounts of crops grown within 80 km of SRS center. Recent information for this region was collected on the amounts of meat, poultry, milk, and eggs produced, of deer hunted, and of sports fish caught. The locations and areas devoted to growing each crop were determined in two ways: by the usual process of assuming uniform crop distribution in each county on the basis of agricultural statistics reported by state agencies, and by analysis of two LANDSAT TM images obtained in May and September. For use with environmental radionuclide transfer and radiation dose calculation codes, locations within 80 km were defined for 64 sections by 16 sectors centered on the Site and by 16-km distance intervals from 16 km to 80 km. Most locally-raised foodstuff was distributed regionally and not retained locally for consumption. For four food crops, the amounts per section based on county agricultural statistics prorated by area were compared with the amounts per section based on satellite image analysis. The median ratios of the former to the latter were 0.6 - 0.7, suggesting that the two approaches are comparable but that satellite image analysis gave consistently higher amounts. Use of satellite image analysis is recommended on the basis of these findings to obtain site-specific, as compared to area-averaged, information on crop locations in conjunction with radionuclide pathway modelling. Some improvements in technique are suggested for satellite image application to characterize additional crops.'

  7. Effect of Pt coverage in Pt-deposited Pd nanostructure electrodes on electrochemical properties

    Energy Technology Data Exchange (ETDEWEB)

    Park, Ah-Reum; Lee, Young-Woo; Kwak, Da-Hee; Park, Kyung-Won [Soongsil University, Seoul (Korea, Republic of)

    2015-06-15

    We have fabricated Pt-deposited Pd electrodes via a two-gun sputtering deposition system by separately operating Pd and Pt target as a function of sputtering time of Pt target. For Pt-deposited Pd electrodes (Pd/Pt-X), Pd were first deposited on the substrates at 20 W for 5min, followed by depositing Pt on the Pd-only electrodes as a function of sputtering time (X=1, 3, 5, 7, and 10min) at 20W on the Pt target. As the sputtering time of Pt target increased, the portion of Pt on the Pd electrodes increased, representing an increased coverage of Pt on the Pd electrodes. The Pd/Pt-7 electrode having an optimized Pt coverage exhibits an excellent electrocatalytic activity for methanol oxidation reaction.

  8. Time-dependent, Bianchi II, rotating universe

    International Nuclear Information System (INIS)

    Reboucas, M.J.

    1981-01-01

    An exact cosmological solution of Einstein's equations which has time-dependent rotation is presented. The t-constant sections are of Bianchi type II. The source of this geometry is a fluid which has not been thermalized. (Author) [pt

  9. A methodology for determining the optimal durations of use contaminated foodstuffs as feedstuffs of cattle following a nuclear accident and its application

    International Nuclear Information System (INIS)

    Hwang, W. T.; Seo, K. S.; Kim, E. H.; Choi, Y. K.; Han, M. H.; Choi, Y. H.; Cho, K. S.

    1999-01-01

    A methodology for determining the optimal durations of use contaminated foodstuffs as feedstuffs of cattle was designed based on cost-benefit analysis. The results of application for pigs, an omnivorous cattle, were discussed for the hypothetical deposition of radionuclides on August 15 when a number of crops are fully developed in Korean agricultural conditions. Also, comparing with the case of the disposal of contaminated foodstuffs without human consumption in terms of net benefit, the cost-effectiveness of use contaminated foodstuffs as feedstuffs was investigated. The time-dependent radioactivity in foodstuffs after the deposition was predicted using a dynamic food chain model DYNACON. The net benefit of the actions was quantitatively evaluated in terms of cost equivalent of doses and monetary costs. It depended on a number of factors such as radionuclides, variety of foodstuffs supplied as feedstuffs and duration of the actions. The use contaminated foodstuffs as feedstuffs was more cost effective for 90 Sr or 131 I depositions than for 137 Cs deposition. The relatively much supply of low-level contaminated foodstuffs made longer the optimal duration

  10. Ab-initio study of the coadsorption of Li and H on Pt(001), Pt(110) and Pt(111) surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Saad, Farida [Laboratoire de Physique et Chimie Quantique, Faculte des Sciences, Universite Mouloud Mammeri, 15000 Tizi-Ouzou (Algeria); Zemirli, Mourad, E-mail: zemirlimourad@mail.ummto.dz [Laboratoire de Physique et Chimie Quantique, Faculte des Sciences, Universite Mouloud Mammeri, 15000 Tizi-Ouzou (Algeria); Benakki, Mouloud; Bouarab, Said [Laboratoire de Physique et Chimie Quantique, Faculte des Sciences, Universite Mouloud Mammeri, 15000 Tizi-Ouzou (Algeria)

    2012-02-15

    The coadsorption of Li and H atoms on Pt(001), Pt(110) and Pt(111) surfaces is studied using density functional theory with generalised gradient approximation. In all calculations Li, H and the two topmost layers of the metal were allowed to relax. At coverage of 0.25 mono-layer in a p(2 Multiplication-Sign 2) unit cell, lithium adsorption at the hollow site for the three surfaces is favoured over top and bridge sites. The most favoured adsorption sites for H atom on the Pt(001) and Pt(110) surfaces are the top and bridge sites, while on Pt(111) surface the fcc site appears to be slightly favoured over the hcp site. The coadsorption of Li and atomic hydrogen shows that the interaction between the two adsorbates is stabilising when they are far from each other. The analysis of Li, H and Pt local density of states shows that Li strongly interacts with the Pt surfaces.

  11. International recommendations[General radiation protection background to protective measures against foodstuffs contaminated with radioactive substances

    Energy Technology Data Exchange (ETDEWEB)

    Lindell, Bo [Swedish National Institute of Radiation Protection (Sweden)

    1986-07-01

    Full text: This short presentation will indicate the general radiation protection background to protective measures against foodstuffs contaminated with radioactive substances. A number of international organizations are involved in various aspects of radiation protection, for example, the International Atomic Energy Agency (IAEA), the United Nations Food and Agriculture Organization (FAO), the United Nations Environment Programme (UNEP), and the World Health Organization (WHO). Two international organizations, however, provide the basic background. These are the International Commission on Radiological Protection (ICRP) and the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR). UNSCEAR provides the scientific information on radiation levels and effects. It consists of 21 member countries, with truly international coverage. It issues reports to the UN General Assembly, including comprehensive scientific annexes. Its latest comprehensive report was issued in 1982, the next is expected to be published in 1988. That report will include an assessment of the radiological consequences of the Chernobyl accident. The ICRP is a non-governmental organization. It has issued recommendations on radiation protection since 1928. The postulated biological basis for radiation protection recommendations involves two types of biological effects. The so-called non-stochastic effects, mainly due to cell death, appear only when the radiation doses exceed a certain threshold value. These effects, therefore, can only appear after high accidental exposures. After the Chernobyl accident, they only affected about 200 individuals involved in fire extinction and rescue work at the damaged nuclear power plant. Stochastic effects, with some simplification, may be seen as the result of initial changes in the genetic code of some surviving cells. If these cells are germ cells, this may lead to hereditary harm. If they are somatic cells, the result could be cancer

  12. Effective Identification of Low-Gliadin Wheat Lines by Near Infrared Spectroscopy (NIRS: Implications for the Development and Analysis of Foodstuffs Suitable for Celiac Patients.

    Directory of Open Access Journals (Sweden)

    María Dolores García-Molina

    Full Text Available The aim of this work was to assess the ability of Near Infrared Spectroscopy (NIRS to distinguish wheat lines with low gliadin content, obtained by RNA interference (RNAi, from non-transgenic wheat lines. The discriminant analysis was performed using both whole grain and flour. The transgenic sample set included 409 samples for whole grain sorting and 414 samples for flour experiments, while the non-transgenic set consisted of 126 and 156 samples for whole grain and flour, respectively.Samples were scanned using a Foss-NIR Systems 6500 System II instrument. Discrimination models were developed using the entire spectral range (400-2500 nm and ranges of 400-780 nm, 800-1098 nm and 1100-2500 nm, followed by analysis of means of partial least square (PLS. Two external validations were made, using samples from the years 2013 and 2014 and a minimum of 99% of the flour samples and 96% of the whole grain samples were classified correctly.The results demonstrate the ability of NIRS to successfully discriminate between wheat samples with low-gliadin content and wild types. These findings are important for the development and analysis of foodstuff for celiac disease (CD patients to achieve better dietary composition and a reduction in disease incidence.

  13. Labelled compounds. (Pt. B)

    International Nuclear Information System (INIS)

    Buncel, E.; Jones, J.R.

    1991-01-01

    Since the end of World War II there has been a tremendous increase in the number of compounds that have been synthesized with radioactive or stable isotopes. They have found application in many diverse fields, so much so, that hardly a single area in pure and applied science has not benefited. Not surprisingly it has been reflected in appearance of related publications. The early proceedings of the Symposia on Advances in Trace Methodology were soon followed by various Euratom sponsored meetings in which methods of preparing and storing labelled compounds featured prominently. In due course a resurgence of interest in stable isotopes, brought about by their greater availability (also lower cost) and partly by development of new techniques such as gas chromatography - mass spectrometry (gc-ms), led to the publication of proceedings of several successful conferences. More recently conferences dealing with the synthesis and applications of isotopes and isotopically labelled compounds have been established on a regular basis. In addition to the proceedings of conferences and journal publications individuals left their mark by producing definitive texts, usually on specific nuclides. Only the classic two volume publication of Murray and Williams (Organic syntheses with isotopes, New York 1985), now over 30 years old and out of print, attempted to do justice to several nuclides. With the large amount of work that has been undertaken since then it seems unlikely that an updated edition could be produced. The alternative strategy was to ask scientists currently active to review specific areas and this is the approach adopted in the present series of monographs. In this way it is intended to cover the broad advances that have been made in the synthesis and applications of isotopes and isotopically labelled compounds in the physical and biomedical sciences. (author). refs.; figs.; tabs

  14. Consumption of Pt anode in phosphoric acid

    Energy Technology Data Exchange (ETDEWEB)

    Kamiya, N.; Urata, K.; Motohira, N.; Ota, K. [Yokohama National University, Yokohama (Japan)

    1997-12-05

    Consumption of Pt anode was investigated in phosphoric acid of various concentration. In 30-70wt% phosphoric acid, Pt dissolved at the rate of 19{mu}gcm{sup -2}h{sup -1}. On the other hand, in 85 wt% phosphoric acid, the amount increased to 0.91 mgcm{sup -2}h{sup -1} which is ca. 180 and 1800 times as much as in 1M sulfuric acid and 1M alkaline solution, respectively. In the diluted phosphoric acid solution, the Pt surface was covered with Pt oxides during the electrolysis, which would prevent the surface from corrosion. However, in the concentrated phosphoric acid, no such oxide surface was observed. Concentrated phosphoric acid might form stable complex with Pt species, therefore the uncovered bare Pt surface is situated in the serious corrosion condition under the high overvoltage and Pt would dissolve into the solution directly instead of forming the Pt oxides. 11 refs., 9 figs., 1 tab.

  15. Synthesis and characterization of the Pt/SiO2 nanocomposite by the sol-gel method

    Directory of Open Access Journals (Sweden)

    A. Salabat

    2011-01-01

    Full Text Available The silica supported platinum nanoparticles was synthesized by using the sol-gel method. The possibility of using diamminedinitro platinum (II as Pt precursor and effect of metal precursor concentration on the final Pt nanoparticle size was investigated. A stable silica sol was prepared via hydrolysis of tetraethyl orthosilicate (TEOS as a metal alcoxide and condensation reaction. Subsequently, diamminedinitro platinum (II was added to sol to form the Pt/silica sol. After drying and calcination of the sol, the Pt/SiO2 nanocpmposite has been obtained. Crystallographic information and crystalline size of the synthesized Pt/SiO2 were determined by X-ray diffraction (XRD method. Morphology of the nanoparticles and hydrogen-bonding interaction between silanol groups and amine ligands were characterized by SEM and Fourier transform infrared (FTIR spectra, respectively. Transmission Electron Microscopy (TEM was employed in evaluating the distribution and size of the platinum nanoparticles in the silica.

  16. The impact of global trends on Czech trade in agrarian and foodstuff products

    Directory of Open Access Journals (Sweden)

    Eva Rosochatecká

    2011-01-01

    Full Text Available The Czech retail market has changed its structure and form during the last twenty years. The influence of two factors is especially significant. The first one is the growth of internationalization and the second one is market concentration growth. The significant opening process of the Czech economy, accompanied by the liberalization of the Czech market process, enabled the international retail companies to penetrate the national retail market. The most powerful European retail companies are now present in the Czech market. The available shopping area/cap is also one of the largest in Europe. Retail chains have taken a dominant position in the market, and because of their market power they are able to determine trade/contract conditions for domestic suppliers. Retail chains’ sales have been constantly growing. While in 2006 the value of sales was about 258.5 billion CZK, in 2008 it was about 312.2 billion CZK. The impact of the economic crisis on the Czech retail market has not been as stressful as it was abroad. In 2009, a slowdown of the Czech retail market was recorded, but the value of sales decreased by only 3 billion CZK (in comparison with 2008. The highest sales (59 billion CZK were recorded by the Lidl & Schwarz-Gruppe, which is the owner of two dominant retail chains in the Czech retail market (Kaufland and Lidl. The main aim of the paper is to evaluate the selected aspects, which have been influencing the relationship between multinational companies (retail companies – supermarkets and hypermarkets and local (Czech suppliers of agrarian and foodstuff products (farmers and foodstuff companies. The paper analyses the problem of abuse of multinational companies’ significant market power in relation to their suppliers. Based on a pilot project, the efficiency of market force law, and its use in practice, are analysed. The main idea is to analyse the following problems: the impact of 30 days payment period for goods delivered, under

  17. Exposure to phthalic acid, phthalate diesters and phthalate monoesters from foodstuffs: UK total diet study results.

    Science.gov (United States)

    Bradley, Emma L; Burden, Richard A; Bentayeb, Karim; Driffield, Malcolm; Harmer, Nick; Mortimer, David N; Speck, Dennis R; Ticha, Jana; Castle, Laurence

    2013-01-01

    Phthalates are ubiquitous in the environment and thus exposure to these compounds can occur in various forms. Foods are one source of such exposure. There are only a limited number of studies that describe the levels of phthalates (diesters, monoesters and phthalic acid) in foods and assess the exposure from this source. In this study the levels of selected phthalate diesters, phthalate monoesters and phthalic acid in total diet study (TDS) samples are determined and the resulting exposure estimated. The methodology for the determination of phthalic acid and nine phthalate monoesters (mono-isopropyl phthalate, mono-n-butyl phthalate, mono-isobutyl phthalate, mono-benzyl phthalate, mono-cyclohexyl phthalate, mono-n-pentyl phthalate, mono-(2-ethylhexyl) phthalate, mono-n-octyl phthalate and mono-isononyl phthalate) in foods is described. In this method phthalate monoesters and phthalic acid are extracted from the foodstuffs with a mixture of acidified acetonitrile and dichloromethane. The method uses isotope-labelled phthalic acid and phthalate monoester internal standards and is appropriate for quantitative determination in the concentration range of 5-100 µg kg⁻¹. The method was validated in-house and its broad applicability demonstrated by the analysis of high-fat, high-carbohydrate and high-protein foodstuffs as well as combinations of all three major food constituents. The methodology used for 15 major phthalate diesters has been reported elsewhere. Phthalic acid was the most prevalent phthalate, being detected in 17 food groups. The highest concentration measured was di-(2-ethylhexyl) phthalate in fish (789 µg kg⁻¹). Low levels of mono-n-butyl phthalate and mono-(2-ethylhexyl) phthalate were detected in several of the TDS animal-based food groups and the highest concentrations measured corresponded with the most abundant diesters (di-n-butyl phthalate and di-(2-ethylhexyl) phthalate). The UK Committee on Toxicity of Chemicals in Food, Consumer Products

  18. Good Practices in Educating and Informing the New Generation of Consumers on Organic Foodstuffs

    Directory of Open Access Journals (Sweden)

    Lelia Voinea

    2015-02-01

    Full Text Available The positive image of organic products among consumers has grown gradually. Today, this image is based on a number of researches and studies conducted by specialized government bodies and private organizations and research institutes that show that these products offer, in terms of their nutritional profile, a high intake of nutrients with positive impact on health. Consumers also know that operators who produce and sell such products are subject to rigorous regulations for obtaining the organic certificate and the right to use the organic logo and are regularly monitored by inspection and certification bodies in this regard – facts that increase the new generation of consumers’ confidence in the quality and safety of these products. Having the aim of highlighting the decisive factors which contribute to the creation of a positive image for the ecological foodstuff among consumers and in order to understand the real motivations of the decisional process of buying these products, an exploring marketing research was realized among the new generation of consumers. Another aim of the investigation is the identification of some problems connected with a possible unbalanced nutritional profile of some ecological products commercialized in Romania and whose consumption may be inadequate for a diet and, implicitly, for some consumers’ health, especially for those having certain food restrictions caused by nutritional diseases from which they suffer. In this regard, we are going to analyse, from a scientific point of view, the nutritional profile of some ecological foodstuff found on the market in Romania, using an accredited and standardized method within the European Union- the SAIN-LIM method. Thereby, the paper aims to highlight the antithesis between the formal positive consumer perception and the nutritional profile of some organic products on the Romanian market. Through this endeavour we intend to draw attention on the need of adopting a

  19. Perancangan Promosi Digital PT Campina Di Surabaya

    OpenAIRE

    Wijaya, Fernando; Hartanto, Deddi Duto; Sylvia, Merry

    2013-01-01

    Perancangan ini dilakukan untuk mempromosikan PT. Campina Ice Cream Industry beserta produknya. PT. Campina Ice Cream Industry diangkat sebagai topic perancangan karena banyak competitor-kompetitor yang bermunculan. Dengan melihat berbagai kelebihan dan kekurangan PT. Campina Ice Cream Industry, promosi dirancang agar dapat menggambarkan kelebihan PT. Campina Ice Cream Industry. Sehingga diharapkan dapat mengingatkan kembali ice cream Campina dalam benak konsumen. Untuk media promosi digital...

  20. Bioassay-directed fractionation of organic extracts of marine surface sediments from the north and Baltic sea. Pt. II. Results of the biotest battery and development of a biotest index

    Energy Technology Data Exchange (ETDEWEB)

    Kammann, U.; Danischewski, D.; Vobach, M. [Federal Research Centre for Fisheries, Inst. for Fishery Ecology, Hamburg (Germany); Biselli, S. [Federal Maritime and Hydrographic Agency, Hamburg (Germany); Eurofins Wiertz-Eggert-Joerissen, Hamburg (Germany); Reineke, N.; Huehnerfuss, H. [Univ. of Hamburg, Inst. for Organic Chemistry, Hamburg (Germany); Wosniok, W. [Univ. of Bremen, Inst. of Statistics, Bremen (Germany); Kinder, A.; Sierts-Herrmann, A.; Steinhart, H. [Univ. of Hamburg, Inst. for Food Chemistry, Hamburg (Germany); Theobald, N. [Federal Maritime and Hydrographic Agency, Hamburg (Germany); Vahl, H.H.; Westendorf, J. [Univ. of Hamburg, Univ. Hospital Hamburg-Eppendorf, Dept. for Toxicology, Hamburg (Germany)

    2005-11-01

    Goal, Scope and Background. The ecological relevance of contaminants in mixtures is difficult to assess, because of possible interactions and due to lacking toxicity data for many substances present in environmental samples. Marine sediment extracts, which contain a mixture of environmental contaminants in low concentrations, were the object of this study. The extracts were investigated with a set of different biotests in order to identify the compound or the substance class responsible for the toxicity. For this goal, a combination of biotests, biotest-directed fractionation and chemical analysis has been applied. Further on, a strategy for the development of a biotest index to describe the toxicity of the fractions without a prior ranking of the test results is proposed. This article (Part II) focuses on the biological results of the approach. Methods. The toxicological potential of organic extracts of sediments from the North Sea and the Baltic Sea was analyzed in a bioassay-directed fractionation procedure with a set of biotests: luciferase reporter gene assays on hormone receptor and Ah receptor, arabinose resistance test, fish embryo test (Danio rerio), comet assay, acetylcholinesterase inhibition test, heat-shock protein 70 induction, oxidative stress and luminescence inhibition test (Vibrio fischeri). The test results provided the basis for the calculation of a biotest index by factor analysis to compare the toxicity of the samples and fractions. Results and Discussion. Results of 11 biotests on different fractionation levels of the samples were described and discussed with regard to the occurrence of contaminants and their toxic potentials. Polychlorinated biphenyls, polycyclic aromatic hydrocarbons, quinones, brominated indoles and brominated phenols were in the focus of interest. A biotest index was constructed to compare the toxic responses in the samples and to group the biotest results. (orig.)

  1. A further insight into the biosorption mechanism of Pt(IV by infrared spectrometry

    Directory of Open Access Journals (Sweden)

    Xu Zhenling

    2009-07-01

    Full Text Available Abstract Background Platinum nanomaterial is one of the significant noble metal catalysts, and the interaction of platinum with microbe is one of the key factors in influencing the size and the distribution of the platinum nanoparticles on the microbial biomass. Some properties of Pt(IV adsorption and reduction by resting cells of Bacillus megatherium D01 biomass have once been investigated, still the mechanism active in the platinum biosorption remains to be seen and requires further elucidating. Result A further insight into the biosorption mechanism of Pt(IV onto resting cells of Bacillus megatherium D02 biomass on a molecular level has been obtained. The image of scanning electron microscopy (SEM of the D02 biomass challenged with Pt(IV displayed a clear distribution of bioreduced platinum particles with sizes of nanometer scale on the biomass. The state of Pt(IV bioreduced to elemental Pt(0 examined via X-ray photoelectron spectroscopy (XPS suggested that the biomass reduces the Pt(IV to Pt(II followed by a slower reduction to Pt(0. The analysis of glucose content in the hydrolysates of D02 biomass for different time intervals using ultraviolet-visible (UV-vis spectrophotometry indicated that certain reducing sugars occur in the hydrolyzed biomass and that the hydrolysis of polysaccharides of the biomass is a rapid process. The infrared (IR spectrometry on D02 biomass and that challenged with Pt(IV, and on glucose and that reacted with Pt(IV demonstrated that the interaction of the biomass with Pt(IV seems to be through oxygenous or nitrogenous chemical functional groups on the cell wall biopolymers; that the potential binding sites for Pt species include hydroxyl of saccharides, carboxylate anion and carboxyl of amino acid residues, peptide bond, etc.; and that the free monosaccharic group bearing hemiacetalic hydroxyl from the hydrolyzed biomass behaving as an electron donor, in situ reduces the Pt(IV to Pt(0. And moreover, the binding of

  2. Shape-controlled synthesis of Pt-Pd core-shell nanoparticles exhibiting polyhedral morphologies by modified polyol method

    International Nuclear Information System (INIS)

    Long, Nguyen Viet; Asaka, Toru; Matsubara, Takashi; Nogami, Masayuki

    2011-01-01

    Pt-Pd core-shell nanoparticles were synthesized by a simple synthetic method. First, Pt nanoparticles were synthesized in a controlled manner via the reduction of chloroplantinic acid hexahydrate in ethylene glycol (EG) at 160 deg. C in the presence of silver nitrate and the stabilization of polyvinylpyrrolidon. AgNO 3 used acts as a structure-modifying agent to the morphology of the Pt nanoparticles. These Pt nanoparticles function as the seeds for the successive reduction of sodium tetrachloropalladate (II) hydrate in EG under stirring for 15 min at 160 deg. C in order to synthesize Pt-Pd core-shell nanoparticles. To characterize the as-prepared Pt-Pd nanoparticles, transmission electron microscopy (TEM) and high-resolution TEM are used. The high-resolution elemental mappings were carried out using the combination of scanning TEM and X-ray energy-dispersive spectroscopy. The results also demonstrate the homogeneous nucleation and growth of the Pd metal shell on the definite Pt core. The synthesized Pt-Pd core-shell nanoparticles exhibit a sharp and polyhedral morphology. The epitaxial growth of the controlled Pd shells on the Pt cores via a polyol method was observed. It is suggested that Frank-van der Merwe and Stranski-Krastanov growth modes coexisted in the nucleation and growth of Pt-Pd core-shell nanoparticles.

  3. European Communities (Foodstuffs treated with ionising radiation) Regulations, 2000. Statutory Instrument S.I. No. 297 of 2000

    International Nuclear Information System (INIS)

    2000-01-01

    These Regulations give effect to Directive 1999/2/EC (the framework Directive) of the European Parliament and of the Council of 22 February 1999 on the approximation of the laws of the Member States concerning foods and food ingredients treated with ionising radiation and Directive 1999/3/EC (the implementing Directive) of the European Parliament and of the Council of 22 February 1999 on the establishment of a Community list of foods and food ingredients treated with ionising radiation. The effect of these Regulations is to lay down the general provisions for the treatment of foodstuffs with ionising radiation. Provisions concerning the approval and control of irradiation facilities and rules on labelling are also included. A positive list of foodstuffs authorised for treatment with ionising radiation and their maximum radiation doses are defined in the implementing Directive. These Regulations should be read together with the two Directives (author)

  4. Special foodstuffs rich in anticarcinogens and antioxidants as means of protecting the population at territories polluted by radionuclides

    International Nuclear Information System (INIS)

    Knizhnikov, V.A.; Shandala, N.K.; Komleva, V.A.; Rudintseva, T.A.

    1996-01-01

    The purpose of this work was to assess the effect of diets including foodstuffs rich in special additives on the metabolism of ecologically important radionuclides strontium-90 and cesium-137 and to assess the resistance of exposed and intact animals from changes in body weight and hemopoietic status. Three types of special meat products containing additives made of sea alga laminaria. Normalization of the ration for mineral and protein composition owing to the above foodstuffs has a favorable impact on the time course of body weight and peripheral hemopoietic system. Radiometry of bone tissue showed that accumulation of strontium 90 was reduced by half in animals fed nutritive additives of meat preserves with routine diet. Refs. 6, tabs. 5

  5. radioactivity analysis in food-stuffs and evaluation of annual effective doses from intakes of radionuclides through daily diets

    International Nuclear Information System (INIS)

    Alam, M.N.; Chowdhury, M. I.; Kamal, M.; Ghose, S.; Islam, M. N.; Mustafa, M. N.; Islam, Al Amin S.

    1996-01-01

    The concentrations of natural and anthropogenic gamma emitting radionuclides in different vegetables, grains,fishes, sugar and common salt samples were measured by using high purity germanium ( HPGe ) detector coupled with Personal Computer Analyzer ( PCA ) and thereby the effective doses from the consumption of these diet were evaluated. The activities of 232 Th in vegetable, grains, salt, sugar and fish samples ranged from 0.13±0.02 to 1.49±0.32 Bq. kg -1 . The concentration of 238 U in these food-stuffs ranged from 0.07±0.01 to 0.95±0.26 Bq Kg -1 . The observed activity of 40 K ranged between 5.04±1.05 and 196.60±41.0 Bq Kg -1 . Caesium was not detected in any of the samples, Assessment of annual intake of these radionuclides has been made on the basis of the average annual intake of these food-stuffs by the population of Bangladesh.The annual effective dose equivalent due to ingestion of different naturally occurring radionuclides ( 232 Th, 238 U, and 40 K) by intake food-stuffs ranged from 0.2 to 113.62 μ Sv. y'-1. The annual effective doses observed in the present study for various types of food-stuffs were less than the ICRP-60 (1990) recommendation, which is 1 m Sv. y -1 for the members of the public. The result and knowledge of this study, would be helpful in making a yardstick comparing with which an appropriate radiation control limit may be imposed on food materials for public consumption in Bangladesh. 1 fig., 2 tables, 13 refs. (Author)

  6. Analysis of different thermal processing methods of foodstuffs to optimize protein, calcium, and phosphorus content for dialysis patients.

    Science.gov (United States)

    Vrdoljak, Ivica; Panjkota Krbavčić, Ines; Bituh, Martina; Vrdoljak, Tea; Dujmić, Zoran

    2015-05-01

    To analyze how different thermal processing methods affect the protein, calcium, and phosphorus content of hospital food served to dialysis patients and to generate recommendations for preparing menus that optimize nutritional content while minimizing the risk of hyperphosphatemia. Standard Official Methods of Analysis (AOAC) methods were used to determine dry matter, protein, calcium, and phosphorus content in potatoes, fresh and frozen carrots, frozen green beans, chicken, beef and pork, frozen hake, pasta, and rice. These levels were determined both before and after boiling in water, steaming, stewing in oil or water, or roasting. Most of the thermal processing methods did not significantly reduce protein content. Boiling increased calcium content in all foodstuffs because of calcium absorption from the hard water. In contrast, stewing in oil containing a small amount of water decreased the calcium content of vegetables by 8% to 35% and of chicken meat by 12% to 40% on a dry weight basis. Some types of thermal processing significantly reduced the phosphorus content of the various foodstuffs, with levels decreasing by 27% to 43% for fresh and frozen vegetables, 10% to 49% for meat, 7% for pasta, and 22.8% for rice on a dry weight basis. On the basis of these results, we modified the thermal processing methods used to prepare a standard hospital menu for dialysis patients. Foodstuffs prepared according to the optimized menu were similar in protein content, higher in calcium, and significantly lower in phosphorus than foodstuffs prepared according to the standard menu. Boiling in water and stewing in oil containing some water significantly reduced phosphorus content without affecting protein content. Soaking meat in cold water for 1 h before thermal processing reduced phosphorus content even more. These results may help optimize the design of menus for dialysis patients. Copyright © 2015 National Kidney Foundation, Inc. Published by Elsevier Inc. All rights

  7. The Role of the Saratov Region as an Agro-Oriented Territory in Ensuring Import Substitution of Foodstuff

    Directory of Open Access Journals (Sweden)

    Sukhanova Irina Fedorovna

    2015-09-01

    Full Text Available The article presents the peculiarities of import substitution in different sectors of the economy. The specific features of the process of import substitution in agriculture is revealed. The objectives and directions of import substitution of foodstuff are highlighted. The authors substantiate the need of separating the agro-oriented territories, as well as donor territories and recipients in the matter of import foodstuff substitution. The criteria of referring regions to agro-oriented territories are revealed, and the conclusion on feasibility of special state support to donor regions providing foodstuff is reasoned. In the present article the authors give the overall characteristics of the Saratov region as an agro-oriented territory, provide the assessment of its food potential, determine the level of food self-sufficiency. The grouping of the main food products is carried out by the authors according to the current level of their self-sufficiency and growth prospects. The comprehensive program of import substitution of food in Russia is developed. The key role in this program is assigned to agro-oriented regions. The main activities of this program are pointed out in the frames of the given research.

  8. Salt-soluble proteins from wheat-derived foodstuffs show lower allergenic potency than those from raw flour.

    Science.gov (United States)

    de Gregorio, Marta; Armentia, Alicia; Díaz-Perales, Araceli; Palacín, Arantxa; Dueñas-Laita, Antonio; Martín, Blanca; Salcedo, Gabriel; Sánchez-Monge, Rosa

    2009-04-22

    Salt-soluble proteins from wheat flour have been described as main allergens associated with both baker's asthma and food allergy. However, most studies have used raw flour as starting material, thus not considering potential changes in allergenic properties induced by the heat treatment and other industrial processing to produce wheat-derived foodstuffs. Salt extracts from different commercial wheat-derived products were obtained and their allergenic properties investigated by IgE-immunodetection, ELISA assays, and skin prick test. The IgE-binding capacity of salt-soluble proteins from commercial breads and cooked pastas was reduced around 50% compared with that of raw flour, the reduction being less dramatic in noncooked pastas and biscuits. Several wheat-derived foodstuffs showed major IgE-binding components of 20 and 35 kDa, identified as avenin-like and globulin proteins, respectively. These proteins, as well as most flour and bread salt-soluble proteins, were hydrolyzed when subjected to simulated gastrointestinal digestion. However, the digested products still exhibited a residual IgE-binding capacity. Therefore, processing of wheat flour to obtain derived foodstuffs decreases the IgE binding-capacity of the major salt-soluble wheat proteins. Moreover, simulated gastric fluid digestion further inactivates some heat-resistant IgE-binding proteins.

  9. An assessment of 210Pb and 210Po in terrestrial foodstuffs from regions of England and Wales

    International Nuclear Information System (INIS)

    McDonald, P.; Jackson, D.; Leonard, D.R.P.; McKay, K.

    1999-01-01

    Based on data for nationally available foodstuffs, naturally occurring 210 Pb and 210 Po contribute significantly to the UK radiation dose from dietary intake. To provide a more complete overview of radiological implications to the public, samples of offal, cereal, fruit, root and green vegetables were collected from 11 sites, including regions of potential 210 Pb and 210 Po enhancement. Considerable variability was evident in levels of 210 Pb and 210 Po from all sites and in all food types investigated. Higher concentrations were typically found in offal and cereals. Lowest concentrations were generally found in root vegetables. Between sites, the only evidence of elevated concentrations of 210 Po occurred at Helston ( 210 Po 3.0 Bq kg -1 in bovine liver, no other offal sample exceeding 0.8 Bq kg -1 ), and Holyhead 210 Po 0.4 Bq kg -1 in blackberries, no other fruit sample exceeding 0.1 Bq kg -1 ). Other foodstuffs from these sites did not show similar enhanced levels of 210 Po. The maximum dose arising from consumption of 210 Pb and 210 Po in foods surveyed in this study is estimated to be around 120 μSv year -1 to adults. This compares with an estimated UK average consumption dose from all nuclides and foodstuffs of 300 μSv year -1 (broad range 100-1000 μSv year -1 ). (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  10. Determination of short half-life elements in biological, foodstuff, and environmental samples qualitatively by neutron activation analysis

    International Nuclear Information System (INIS)

    Syukria Kurniawati; Muhayatun Santoso; Diah Dwiana Lestiani

    2010-01-01

    NAA applications at routine operation power of 15 MW at Multipurpose Reactor GA Siwabessy (MPR-GAS) for sample matrices analysis have been widely applied. However, the results are not optimum for some matrices especially for short half-live elements. Preliminary study of short half-life elements determination in biological, foodstuff, and environmental samples using 1 MW power have been conducted to solve this problem. The samples were irradiated in rabbit system of MPR-GAS for 5 minutes, counted for 200 seconds by HPGe detector, and the spectrum were analyzed further using software Genie 2000 and Bandung NAA Utility. Analysis under 1 MW power on biological and foodstuff samples were capable to detect eight elements: Al, Br, CI, Ca, I, K, Mg, Ti, and Na for biological samples; Al, Br, CI, Ca, I, K, Mg, Mn, and Na for foodstuff samples, while at 15 MW power only three elements (CI, K, Na) were detected. At 1 MW power the counting process is more optimum due to smaller radiation exposure and dead time. For the environmental samples, the number of elements detected by 1 MW and 15 MW powers did not differ significantly. Generally, the results on the three types of samples showed that the elements of short half-life are better detected at 1 MW than that of 15 MW power. Further research needs to be done to obtain the optimum analytical conditions for irradiation and counting time determination. (author)

  11. Implicit Messages Regarding Unhealthy Foodstuffs in Chinese Television Advertisements: Increasing the Risk of Obesity.

    Science.gov (United States)

    Chang, Angela; Schulz, Peter J; Schirato, Tony; Hall, Brian J

    2018-01-04

    Previous studies indicated that television (TV) advertising is associated with higher rates of obesity. The rate of obesity and overweight continues to rise in mainland China, bringing into question whether TV advertising to young audiences might be partly to blame. This study investigated messaging delivered through TV advertisements regarding healthy and unhealthy foodstuffs. A total of 42 major food brands and 480 advertisements were analysed for content in this study. The results showed that the majority of TV spots advertised products with poor nutritional content and had a potential to mislead audiences concerning products' actual nutritional value. The tactics of repetition and appeals of premium offerings on food brands have a potential to influence the purchase intentions. Additional qualitative observation involving the social bond, social context and cultural factors pertaining to mood alterations were highlighted. The discussion addressed product attributes reflected by culture and the implicit messages of marketing claims may increase the risk of obesity. Thus, public health policymakers and researchers were encouraged to act urgently to evaluate the obesity risks of unhealthy food advertised in the media and to support healthy foods.

  12. Identification of gamma-irradiated foodstuffs by chemiluminescence measurements in Taiwan

    Science.gov (United States)

    Ma, Ming-Shia Chang; Chen, Li-Hsiang; Tsai, Zei-Tsan; Fu, Ying-Kai

    In order to establish chemiluminescence (CL) measurements as an identification method for γ-irradiated foodstuffs in Taiwan, ten agricultural products including wheat flour, rice, ginger, potatoes, garlic, onions, red beans, mung beans, soy beans, xanthoxylon seeds and Japanese star anises have been tested to compare CL intensities between untreated samples and samples subject to a 10 kGy γ-irradiation dose. Amongst them, wheat flour is the most eligible product to be identified by CL measurements. The CL intensities of un-irradiated and irradiated flour have shown large differences associated with a significant dose-effect relationship. Effects of three different protein contents of flour, unsieved and sieved (100-200 mesh), the reproducibility and the storage experiment on CL intensities at various doses were investigated in this study. In addition, the white bulb part of onions has shown some CL in irradiated samples. The CL data obtained from the other eight agricultural products have shown large fluctuations and cannot be used to differentiate between irradiated and un-irradiated samples.

  13. External dose rates from gamma rays and activity concentrations in foodstuffs and herbage in eastern Europe

    International Nuclear Information System (INIS)

    Wilkins, B.T.; Dodd, N.J.; Bradley, E.J.

    1986-01-01

    The initial scarcity of reliable information in eastern European countries, coupled with the proximity of the Chernobyl installation, resulted in understandable concern among British nationals living in these areas or visiting them on a short-term basis. Accordingly, arrangements were made by the Foreign and Commonwealth Office (FCO) for the appropriate Embassies to send samples of milk, drinking water, grass and available fruit and vegetables to the Board's laboratories at Chilton for analysis. In addition, simple monitoring equipment was supplied to the Embassies for measurements of external dose rates from gamma rays out of doors. The first set of samples was collected in Moscow on May 3rd 1986. Most consignments arrived at Chilton within 24 hours of collection. Speed was important, not only because of the need for information but because vegetation needed to be sufficiently fresh to permit meaningful measurement. By the end of June 1986, the results of systematic monitoring programmes in eastern Europe were being disseminated more freely, so that frequent sampling by the Embassies was no longer considered necessary. Since that time samples have been received only occasionally from those Embassies where concern still persists. This report summarises the results of measurements and samples taken by June 30th 1986. Data for γ-ray emitting radionuclides in foodstuffs were issued to the FCO in a series of Measurement Reports. Here they are presented together with data for actinide element concentrations in a limited number of samples. Measurements of outdoor external dose rates made by the Embassies are also included

  14. Simultaneous Determination of Four Preservatives in Foodstuffs by High Performance Liquid Chromatography

    Directory of Open Access Journals (Sweden)

    Mohammad Faraji

    2016-04-01

    Full Text Available Background and objectives:  High concentration of preservatives in food may result in gastrointestinal disturbances whereby some patients suffering from asthma, rhinitis, or urticaria. The aim of this study is the introduction and optimization a new method for simultaneous determination of four preservatives (SB, PS, MP, PP in foodstuff by high performance liquid chromatography. Materials and methods: Important factors in extraction, separation and determination process were optimized using the one variable at a time method.  Figures of merit of the proposed method were evaluated. The amount of SB, PS, MP, PP in some food samples were determined using the proposed method. Result: The results showed that the obtained chromatogram of extract was free of significant interferences. The preservatives recoveries ranged from 88% to 110 %. Concentration of SB, PS, MP and PP in the 20studied samples ranges between N.D-639.9, N.D -214.5, N.D -579.8 and N.D -30.5 mg kg-1, respectively  Conclusion: The performance and reliability of proposed method as a simple, efficient and fast method for determination of SB, PS, MP, PP in the food samples was demonstrated.

  15. Original Article. Efficacy of electrospun bionanofibers as fumigant pesticides in foodstuff storage

    Directory of Open Access Journals (Sweden)

    Allahvaisi Somaye

    2016-08-01

    Full Text Available Essential oils as alternative synthetic pesticides for pest management of foodstuffs have recently received increased attention. Controlled and slow release formulations of essential oils are used to enhance their efficiency. Two volatile essential oils of Mentha piperita L. and Salvia officinalis L. were investigated for release rate and mortality percentage by fumigant toxicity against 1st instar larvae of Plodia interpunctella. Electrospinning was used to incorporate various concentrations of essential oils in nanofibers. The essential oils can be released from the nanofibers for long periods of time, from several days to several weeks. Poly(lactic acid was used as a green polymer carrier and the essential oils were incorporated into the nanofibers (8-15v/v% PLA. Insecticidal bioassay revealed that oil-loaded nanofibers (NFOs were more toxic than pure essential oils (PEOs against tested larvae. The LC50 and LT50 of NFOs were 1.2 and 4 times, respectively, more than PEOs. Our results indicated that PEOs completely lost their insecticidal activity after 14 days, whereas at the same period, NFOs had an average of 93% mortality when applied against P. interpunctella. Therefore, it can be concluded that nanofibers improved the persistence of the oil. This study presents S. officinalis has more toxicity and M. piperita had more persistence for controlling the larvae of indian meal moth.

  16. Application of by-products in the development of foodstuffs for particular nutritional uses

    Directory of Open Access Journals (Sweden)

    Stanislava Matejová

    2016-12-01

    Full Text Available The aim of this work was to test potential by-product utilization in the development of foodstuffs for people intolerant for gluten. In this work were used three kinds of pomace – apple, buckwheat and grape (varieties Alibernet and Cabernet. Obtained dried pomace was applied into the baking products in ratio 5%, 10% and 15%. Apple and buckwheat pomace were applied into the breads and grape pomace were used in biscuits. The obtained products were sensory evaluated and texture analysis was used for determination of firmness. In terms of overall quality of tested breads, the evaluators indicated that bread with 5% addition of buckwheat pomace was the sample with the highest quality and from biscuit category products with 5% addition of grape pomace (Alibernet were shown to be the best. Regarding the texture determination the highest firmness showed a control sample in the case of biscuits and with the addition of pomace into the biscuits product firmness decreased. Contrary, in case of breads with the addition of pomace, the firmness increased. The results of texture analysis were statistically evaluated by non-parametric Wilcoxon test, among the samples there was no statistical significant difference found.

  17. Implicit Messages Regarding Unhealthy Foodstuffs in Chinese Television Advertisements: Increasing the Risk of Obesity

    Science.gov (United States)

    Chang, Angela; Schirato, Tony; Hall, Brian J.

    2018-01-01

    Previous studies indicated that television (TV) advertising is associated with higher rates of obesity. The rate of obesity and overweight continues to rise in mainland China, bringing into question whether TV advertising to young audiences might be partly to blame. This study investigated messaging delivered through TV advertisements regarding healthy and unhealthy foodstuffs. A total of 42 major food brands and 480 advertisements were analysed for content in this study. The results showed that the majority of TV spots advertised products with poor nutritional content and had a potential to mislead audiences concerning products’ actual nutritional value. The tactics of repetition and appeals of premium offerings on food brands have a potential to influence the purchase intentions. Additional qualitative observation involving the social bond, social context and cultural factors pertaining to mood alterations were highlighted. The discussion addressed product attributes reflected by culture and the implicit messages of marketing claims may increase the risk of obesity. Thus, public health policymakers and researchers were encouraged to act urgently to evaluate the obesity risks of unhealthy food advertised in the media and to support healthy foods. PMID:29300366

  18. Acrylamide levels in Finnish foodstuffs analysed with liquid chromatography tandem mass spectrometry.

    Science.gov (United States)

    Eerola, Susanna; Hollebekkers, Koen; Hallikainen, Anja; Peltonen, Kimmo

    2007-02-01

    Sample clean-up and HPLC with tandem mass spectrometric detection (LC-MS/MS) was validated for the routine analysis of acrylamide in various foodstuffs. The method used proved to be reliable and the detection limit for routine monitoring was sensitive enough for foods and drinks (38 microg/kg for foods and 5 microg/L for drinks). The RSDs for repeatability and day-to-day variation were below 15% in all food matrices. Two hundred and one samples which included more than 30 different types of food and foods manufactured and prepared in various ways were analysed. The main types of food analysed were potato and cereal-based foods, processed foods (pizza, minced beef meat, meat balls, chicken nuggets, potato-ham casserole and fried bacon) and coffee. Acrylamide was detected at levels, ranging from nondetectable to 1480 microg/kg level in solid food, with crisp bread exhibiting the highest levels. In drinks, the highest value (29 microg/L) was found in regular coffee drinks.

  19. Characterization of Bacillus phage-K2 isolated from chungkookjang, a fermented soybean foodstuff.

    Science.gov (United States)

    Kim, Eun Ju; Hong, Jeong Won; Yun, Na-Rae; Lee, Young Nam

    2011-01-01

    An investigation of a virulent Bacillus phage-K2 (named Bp-K2) isolated from chungkookjang (a fermented soybean foodstuff) was made. Bp-K2 differed in infectivity against a number of Bacillus subtilis strains including starter strains of chungkookjang and natto, being more infectious to Bacillus strains isolated from the chungkookjang, but much less active against a natto strain. Bp-K2 is a small DNA phage whose genome size is about 21 kb. Bp-K2 is a tailed bacteriophage with an isometric icosahedral head (50 nm long on the lateral side, 80 nm wide), a long contractile sheath (85-90 nm × 28 nm), a thin tail fiber (80-85 nm long, 10 nm wide), and a basal plate (29 nm long, 47 nm wide) with a number of spikes, but no collar. The details of the structures of Bp-K2 differ from natto phage ϕBN100 as well as other known Bacillus phages such as SPO1-like or ϕ 29-like viruses. These data suggest that Bp-K2 would be a new member of the Myoviridae family of Bacillus bacteriophages.

  20. Co-ordinated research programme on nuclear techniques for toxic elements in foodstuffs

    International Nuclear Information System (INIS)

    1990-01-01

    This Co-ordinated Research Programme (CRP) was started by the Agency in 1985, within the framework of the Regional Cooperative Agreement for Research, Development and Training Related to Nuclear Science and Technology in the Asia and Pacific Region (RCA). Its main purpose has been to obtain comparative data on existing elemental concentrations of potentially toxic elements in foodstuffs in various Asian countries. The elements to be studied include the potentially most toxic trace elements (As, Cd, Hg, Pb, Se) as well as others of relevance to national monitoring programmes, such as Br, Cr, Cu, Fe, I, Mn, Sb, Tl, and Zn. An important supplementary purpose of the programme is to help establish analytical expertise for work of this kind in the individual countries. Scientists from several RCA Member States have participated in it, namely from Australia, Bangladesh, China, India, Indonesia, Japan, Malaysia, Pakistan, Thailand, and also from institutes in several countries outside the region, i.e., Argentina, Brazil, Jamaica and The Netherlands. This report summarizes the discussions that took place during the third and final Research Co-ordination Meeting (RCM) for the programme from 20-24 November 1989, in Jakarta, Indonesia. This document includes the progress reports presented by the participants as well as discussions and conclusions drawn from the meeting

  1. Determination of Essential Elements in Local Foodstuffs of Saudi Arabian Kingdom

    International Nuclear Information System (INIS)

    Eissa, M.W.A.; Al-ahmary, Kh.M.A.

    2004-01-01

    Vegetable and fruit samples were collected from their major area of Saudi Arabian Kingdom (KSA), together with locally bred, fish and meat and local manufacture products as cheese and macaroni. These samples were analyzed for Na, K, Mg, Ca, Fe, Zn, Cu and Mn using flame photometer and atomic absorption spectrometer. The results showed that the level of Na and K in local foodstuffs not vary greatly from the reported values. But Mg showed much higher concentration than that the reported value. On the contrary the levels of Ca, Fe, Zn, Cu and Mn lower than the reported values. The daily intake of essential elements was calculated taking into account the concentration of these elements in the edible part and the daily consumption data which were derived from two sources a- the food balance sheet of Kingdom of Saudi Arabian (KSA) given by Food Agriculture Organization FAO and b-daily intake of these essential elements according to FAO are satisfy the daily requirements except Ca and Zn, But according to the questionnaire the daily intake of these elements is less than the requirements daily intake except for Mg

  2. Rights to Designaton Focusing on Protected Designations and Geographical Indications of Agricultural Products and Foodstuffs

    Directory of Open Access Journals (Sweden)

    Ilková Zuzana

    2015-02-01

    Full Text Available The paper deals with the issue covered by the field of industrial property, it deals with the right to designation, especially with characteristics of legal regulation of labeling of products with regard to their geographical origin at the Slovak, communitarian and international levels. Individual objects of the industrial property may be the result of intellectual creative activity of its creator/creators (e.g. inventions, utility models, designs or they are not the result of creative activity of a particular natural person and are considered as industrial property rights to designation. The group of rights to designation includes: business names, trademarks, designation of origin for products and geographical indications for products. The rights to designation, inter alia, shall ensure uniqueness and competitive advantage for entrepreneurs and easy identification on the market of goods and services for the consumers. The paper closely analyzes the harmonized legal regulation of designations of origin and geographical indications of agricultural products, foodstuffs, spirit drinks, and wines. At the example of Tokaj wine region, it demonstrates the importance of protected designations at the EU level, in case of which demonstrable geographical origin of the product with controlled product specification by authorized national bodies brings a guarantee of quality of this product for consumers and the competitive advantage during their commercial implementation for the entrepreneurs.

  3. Identification of gamma-irradiated foodstuffs by chemiluminescence measurements in Taiwan

    International Nuclear Information System (INIS)

    Mingshia Chang Ma; Lihsiang Chen; Zeitsan Tsai; Yingkai Fu

    1992-01-01

    In order to establish chemiluminescence (CL) measurements as an identification method for γ-irradiated foodstuffs in Taiwan, ten agricultural products including wheat flour, rice, ginger, potatoes, garlic, onions, red beans, mung beans, soy beans, xanthoxylon seeds and Japanese star anises have been tested to compare CL intensities between untreated samples and samples subject to a 10 kGy γ-irradiation dose. Amongst them, wheat flour is the most eligible product to be identified by CL measurements. The CL intensities of un-irradiated and irradiated flour have shown large differences associated with a significant dose-effect relationship. Effects of three different protein contents of flour, unsieved and sieved (100-200 mesh), the reproducibility and the storage experiment on CL intensities at various doses were investigated in this study. In addition, the white bulb part of onions has shown some CL in irradiated samples. The CL data obtained from the other eight agricultural products have shown large fluctuations and cannot be used to differentiate between irradiated and un-irradiated samples. (Author)

  4. Strategic Alliance Between PT Dirgantara Indonesia and Airbus Millitary (a Case Study of PT Dirgantara Indonesia)

    OpenAIRE

    Indriyanto, Reza Relen; Wandebori, Harimukti; Astuti, Novika Candra

    2013-01-01

    PT Dirgantara Indonesia (PT DI) is one of the aircraft manufacturing companies in Indonesia. The tight of competition in aerospace industry needs to improve its performance to gain niche market. Therefore, Ministry State of Own Enterprises has instructed PT Perusahaan Pengelola Aset (PT PPA) and PT DI to restructure and revitalize company with supported by Airbus Military as a strategic alliance partner, in order to increase the performance of production capacity, aircraft sales, and financia...

  5. Mixed ligand complexes of platinum(II) and palladium(II) with cytokinin-derived compounds Bohemine and Olomoucine: X-ray structure of [Pt(BohH+-N7)Cl(3)].9/5H2O [Boh=6-(benzylamino)-2-[(3-(hydroxypropyl)-amino]-9-isopropylpurine, Bohemine

    Czech Academy of Sciences Publication Activity Database

    Trávníček, Zdeněk; Maloň, M.; Zatloukal, Marek; Doležal, Karel; Strnad, Miroslav

    2003-01-01

    Roč. 94, č. 4 (2003), s. 307-316 ISSN 0162-0134 R&D Projects: GA ČR GA522/01/0275; GA ČR GA203/00/0152 Institutional research plan: CEZ:AV0Z5038910 Keywords : Platinum(II) * Palladium(II) * Bohemine Subject RIV: CE - Biochemistry Impact factor: 2.343, year: 2003

  6. Methanol adsorption on Pt(111)

    International Nuclear Information System (INIS)

    Melo, A.V.; Chottiner, G.S.; Hoffman, R.W.; O'Grady, W.E.

    1984-12-01

    High resolution electron energy loss spectroscopy has been used to study the decomposition of methanol on a Pt(111) surface. Several intermediate states in the decomposition are identified by quenching the sample when reactions occur. At 100 K a set of peaks at 800, 1040, 1350, and 2890 cm -1 indicates the presence of a multilayer molecularly adsorbed methanol. As the sample is warmed to 130 K peaks develop at 1700 and 2780 cm -1 , suggesting the formation of formaldehyde on the surface. With further heating, peaks grow at 1820 and 2560 cm -1 due to the formation of a formyl species during the decomposition of methanol over Pt(111). Further heating leads to the final conversion of the surface species to adsorbed CO and carbonaceous residues

  7. Calculating the C operator in PT-symmetric quantum mechanics

    International Nuclear Information System (INIS)

    Bender, C.M.

    2004-01-01

    It has recently been shown that a non-Hermitian Hamiltonian H possessing an unbroken PT-symmetry (i) has a real spectrum that is bounded below, and (ii) defines a unitary theory of quantum mechanics with positive norm. The proof of unitarity requires a linear operator C, which was originally defined as a sum over the eigenfunctions of H. However, using this definition it is cumbersome to calculate C in quantum mechanics and impossible in quantum field theory. An alternative method is devised here for calculating C directly in terms of the operator dynamical variables of the quantum theory. This new method is general and applies to a variety of quantum mechanical systems having several degrees of freedom. More importantly, this method can be used to calculate the C operator in quantum field theory. The C operator is a new time-independent observable in PT-symmetric quantum field theory. (author)

  8. Radioactive contamination of foodstuffs: determination of permissible levels; Contamination radioactive des denrees alimentaires: determination des niveaux admissibles

    Energy Technology Data Exchange (ETDEWEB)

    Ledermann, S [Commissariat a l' Energie Atomique, Fontenay- aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    In a latent air-soil contamination situation, the population would receive 80 per cent of its contamination through foodstuffs. The supervision of this food poses many problems: sampling, radionuclide dosages, etc. It is also necessary to estimate the maximum permissible concentration of radionuclides in foodstuffs, once the maximum exposure limit for the human body has been fixed. The passage of this level to the maximum concentrations is not simple since a) each radionuclide has its own particular effect on the body; b) their concentrations vary from one foodstuff to another, and c) the average amounts of foodstuffs vary from one population to another. Two methods are given here for estimating the maximum permissible concentrations in foodstuffs, together with the first diets likely to become critical when several of them are to be considered simultaneously. The results depend on the way in which the present situation can change to become critical. This evolutionary path can only be estimated approximately. Two methods are therefore given for studying the sensitivity of the results. As an example, a numerical application of these methods using data actually available is given. The data used is naturally incomplete and this will always be true. This application test indicates however two fields in which an improvement is absolutely necessary. 1 - The obtention of multiple observations (simultaneous dosage of at least 2 radionuclides in the same foodstuff, and simultaneous dosage of at least two foodstuffs for the same radionuclide); this assumes a combined effort by the various organisms; 2 - The reaching of an agreement on the dosage methods used by the various organisms since the results actually available are not comparable. (authors) [French] Dans une situation de contamination air-sol latente, la contamination des populations se ferait a 80 pour cent par l'alimentation. Surveiller cette alimentation pose des problemes complexes: echantillonnage, dosage des

  9. Electronic structures of PtCu, PtAg, and PtAu molecules: a Dirac four-component relativistic study

    International Nuclear Information System (INIS)

    Abe, Minori; Mori, Sayaka; Nakajima, Takahito; Hirao, Kimihiko

    2005-01-01

    Relativistic four-component calculations at several correlated levels have been performed for diatomic PtCu, PtAg, and PtAu molecules. The ground state spectroscopic constants of PtCu were calculated using the four-component MP2 method, and show good agreement with experiment. We also performed calculations on the experimentally unknown species, PtAg and PtAu, and the mono-cationic systems, PtCu + , PtAg + , and PtAu + . The low-lying excited states of these diatomic molecules were also investigated using the four-component multi-reference CI method

  10. The anisotropy field of FePt L10 nanoparticles controlled by very thin Pt layer

    International Nuclear Information System (INIS)

    Okamoto, Satoshi; Kitakami, Osamu; Kikuchi, Nobuaki; Miyazaki, Takamichi; Shimada, Yutaka; Chiang, Te-Hsuan

    2004-01-01

    We have prepared epitaxial FePt L1 0 (001) nanoparticles covered with Pt [d Pt nm]/Ag[(4-d Pt ) nm] overlayers. The particles are oblate spheroids approximately 10 nm in diameter and 2 nm in height. The anisotropy field H k at 0 K, which is evaluated from the temperature dependences of coercivity H c , decreases from 90 to 60 kOe on increasing the Pt thickness from d Pt 0 to 1.5 nm, while the energy barrier at zero field remains unchanged. The significant reduction of H k due to the presence of the adjacent Pt layer can be attributed to an enhanced magnetic moment caused by the ferromagnetic polarization of Pt atoms at the interface. This finding suggests an effective method of controlling the switching field of FePt L1 0 nanoparticles

  11. Reversibility of Pt-Skin and Pt-Skeleton Nanostructures in Acidic Media.

    Science.gov (United States)

    Durst, Julien; Lopez-Haro, Miguel; Dubau, Laetitia; Chatenet, Marian; Soldo-Olivier, Yvonne; Guétaz, Laure; Bayle-Guillemaud, Pascale; Maillard, Frédéric

    2014-02-06

    Following a well-defined series of acid and heat treatments on a benchmark Pt3Co/C sample, three different nanostructures of interest for the electrocatalysis of the oxygen reduction reaction were tailored. These nanostructures could be sorted into the "Pt-skin" structure, made of one pure Pt overlayer, and the "Pt-skeleton" structure, made of 2-3 Pt overlayers surrounding the Pt-Co alloy core. Using a unique combination of high-resolution aberration-corrected STEM-EELS, XRD, EXAFS, and XANES measurements, we provide atomically resolved pictures of these different nanostructures, including measurement of the Pt-shell thickness forming in acidic media and the resulting changes of the bulk and core chemical composition. It is shown that the Pt-skin is reverted toward the Pt-skeleton upon contact with acid electrolyte. This change in structure causes strong variations of the chemical composition.

  12. PT AND PT/NI "NEEDLE" ELETROCATALYSTS ON CARBON NANOTUBES WITH HIGH ACTIVITY FOR THE ORR

    Energy Technology Data Exchange (ETDEWEB)

    Colon-Mercado, H.

    2011-11-10

    Platinum and platinum/nickel alloy electrocatalysts supported on graphitized (gCNT) or nitrogen doped carbon nanotubes (nCNT) are prepared and characterized. Pt deposition onto carbon nanotubes results in Pt 'needle' formations that are 3.5 nm in diameter and {approx}100 nm in length. Subsequent Ni deposition and heat treatment results in PtNi 'needles' with an increased diameter. All Pt and Pt/Ni materials were tested as electrocatalysts for the oxygen reduction reaction (ORR). The Pt and Pt/Ni catalysts showed excellent performance for the ORR, with the heat treated PtNi/gCNT (1.06 mA/cm{sup 2}) and PtNi/nCNT (0.664 mA/cm{sup 2}) showing the highest activity.

  13. Highly active Pt nanoparticles on nickel phthalocyanine functionalized graphene nanosheets for methanol electrooxidation

    International Nuclear Information System (INIS)

    Zhong, Jing-Ping; Fan, You-Jun; Wang, Hui; Wang, Rui-Xiang; Fan, Li-Li; Shen, Xing-Can; Shi, Zu-Jin

    2013-01-01

    Highlights: • A new Pt-based catalyst using TSNiPc functionalized graphene as support is reported. • Pt nanoparticles are uniformly dispersed on the functionalized graphene surface. • The Pt/TSNiPc–graphene shows excellent catalytic performance for methanol oxidation. -- Abstract: A novel electrocatalyst using nickel (II) phthalocyanine-tetrasulfonic acid tetrasodium salt (TSNiPc) functionalized graphene (TSNiPc–graphene) composite as catalyst support for Pt nanoparticles is reported. The surface morphology, composition and structure of the prepared nanocomposites as well as their electrocatalytic properties toward methanol oxidation are characterized by UV–vis absorption spectroscopy, Raman spectroscopy, thermogravimetric analysis (TGA), transmission electron microscopy (TEM), energy dispersive X-ray (EDX) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical tests. Pt nanoparticles are found uniformly dispersed on the surface of TSNiPc–graphene composite, with the small particle size of about 3.1 nm. Studies of cyclic voltammetry and chronoamperometry demonstrate that the Pt/TSNiPc–graphene exhibits much higher electrocatalytic activity and stability than the Pt/graphene catalyst for methanol oxidation

  14. ANALISIS AUDIT MANAJEMEN ATAS FUNGSI KEUANGAN PADA PT BUMI SARANA BETON MAKASSAR

    Directory of Open Access Journals (Sweden)

    Arfina _

    2017-06-01

    Full Text Available Arfina, 2016. Thesis. Analysis of Financial Functions Top Management Audit at PT Bumi Sarana Beton Makassar. (Guided by the Firman Menne, SE., M.Sc., AK., CA as counselors and mentors I Thanwain, SE., M.Si sebagai Advisor II. This study aims to: determine the application of the management audit of the financial functions undertaken by PT Bumi Sarana Beton in Makassar.In collecting data the author uses the method of writing as literature study to obtain literature-literature books that support for scientific writing, the author Fields ini.Penelitian direct observation to PT Bumi Sarana Beton Makassar .. Technics analysis used by the writer is descriptive method.Based on the results of the discussions that the authors have described, the author concludes that in PT Bumi Sarana Beton Makassar finance department the company has succeeded in supporting efforts to achieve the financial goals of the company. It can be seen from the performance of the financial section embodied in the financial statement (balance sheet and income statement. The results of the analysis and financial ratios based on the financial statements of PT Bumi Sarana Beton showed that the management of PT Bumi Sarana Beton has been able to increase profits, so it can be concluded that the financial part of PT Bumi Sarana Beton has successfully meendukung efforts to achieve the financial goals of the company. Support for the phase to the company's financial goals also manifested itself in compliance with the company's financial control system running.

  15. ANALISIS SISTEM INFORMASI AKUNTANSI PENJUALAN PADA PT HADJI KALLA (TOYOTA CABANG PINRANG

    Directory of Open Access Journals (Sweden)

    Andi Mujahidah

    2017-05-01

    Full Text Available Andi Mujahidah, (2015 "Accounting Information System Analysis Sales At PT Hadji Kalla (Toyota Branch Pinrang" under the guidance of Mrs. Faridah, SE., M.Si, .AK, .ca as first counselor and Mr. Thanwain, SE ,. M.Si as supervisor II. Accounting Information Systems are very important in the sales function remembers every sales transaction must involve the responsibility of a few people within the company. To improve the handling of the sale of the company it needed an adequate internal control sales in its implementation. Problems in this study as follows: (1 How the application of accounting information system of sales at PT Hadji Kalla (Toyota Branch Pinrang? (2 How can the application of the system of credit sales at PT Hadji Kalla (Toyota Branch Pinrang? The research objective is to determine: (1 The application of accounting information system of sales at PT Hadji Kalla (Toyota Branch Pinrang. (2 Analysis of credit sales at PT Hadji Kalla (Toyota Branch Pinrang. The method used is the comparative method and data collection through interviews. After the author doing research and comparing the elements of sale accounting information system applied by PT Hadji Kalla (Toyota Branch Pinrang with elements of information systems sales accounting standard, the writer can say that the PT Hadji Kalla (Toyota Branch Pinrang has implemented a system sales accounting information as appropriate, in order to increase sales, it will have an impact on the company's assets will increase sales and accounting data accuracy and reliability is assured.

  16. Inversion symmetry breaking induced triply degenerate points in orderly arranged PtSeTe family materials

    Science.gov (United States)

    Xiao, R. C.; Cheung, C. H.; Gong, P. L.; Lu, W. J.; Si, J. G.; Sun, Y. P.

    2018-06-01

    k paths exactly with symmetry allow to find triply degenerate points (TDPs) in band structures. The paths that host the type-II Dirac points in PtSe2 family materials also have the spatial symmetry. However, due to Kramers degeneracy (the systems have both inversion symmetry and time reversal symmetry), the crossing points in them are Dirac ones. In this work, based on symmetry analysis, first-principles calculations, and method, we predict that PtSe2 family materials should undergo topological transitions if the inversion symmetry is broken, i.e. the Dirac fermions in PtSe2 family materials split into TDPs in PtSeTe family materials (PtSSe, PtSeTe, and PdSeTe) with orderly arranged S/Se (Se/Te). It is different from the case in high-energy physics that breaking inversion symmetry I leads to the splitting of Dirac fermion into Weyl fermions. We also address a possible method to achieve the orderly arranged in PtSeTe family materials in experiments. Our study provides a real example that Dirac points transform into TDPs, and is helpful to investigate the topological transition between Dirac fermions and TDP fermions.

  17. Radiotherapeutic aspects of the treatment of adult patients with supradiaphragmatic Hodgkin's disease CS I/II. Pt. 1; Regarding the indications of primary and adjuvant radiotherapy. Fragen und Aspekte zur Radiotherapie bei erwachsenen Patienten mit lokalisierten supradiaphragmalen Stadien (CS I/II) eines Morbus Hodgkin. T. 1; Fragen und Aspekte zu den Indikationen einer primaeren und einer adjuvanten Radiotherapie

    Energy Technology Data Exchange (ETDEWEB)

    Glanzmann, C. (Universitaetsspital, Klinik fuer Radio-Onkologie, Zurich (Switzerland)); Luetolf, U.M. (Universitaetsspital, Klinik fuer Radio-Onkologie, Zurich (Switzerland))

    1993-08-01

    Randomized studies of chemo- vs radiotherapy in patients with PS I/II A and some PS III A have shown conflicting results. Patients with supra-diaphragmatic Hodkin's disease and CS I/II can be subdivided according to radiotherapy as: 1. Patients with a very low or a low recurrence risk of approximately 10 to 20%: Patients less than 40 years old and CS I/II A NS/LP with less than three involved regions and no bulky mediastinal mass and an ESR below 30 mm. In the other patients, primary irradiation of an extended mantle field without a staging laparotomy is an acceptable primary treatment, achieving a recurrence-free survival rate of approximately 80%. Another option is a staging laparotomy with splenectomy and a mantle radiotherapy for PS I/II. Few groups prefer primary chemotherapy alone or some type of a reduced chemotherapy with lesser toxicity combined with localized radiotherapy and long-term observations of a larger group of patients after the last type of treatment have to confirm the excellent early results. 2. Patients with an intermediate recurrence risk of approximately 20 to 40%: Patients, who do not belong to group one or group 3. Patients less than 50 years old with CS I/II and an ESR less than 50 mm and without bulky mediastinal involvement and with one of the following signs: Three involved regions or MC or one B symptom. A patient with more than one of these signs or with two or three B symptoms should be classified in group 3. For these patients, we recommend staging laparotomy and radiotherapy if PS I/II or primary chemotherapy with or without radiotherapy of the involved regions. 3. Patients with a high recurrence risk (40% or higher): (Abstract Truncated)

  18. Neutron-activation analysis of copper in food-stuffs and biomedium of organism

    International Nuclear Information System (INIS)

    Rasulov, S.K.

    2004-01-01

    Full text: Our investigation has been carried out in the area with different ecologic characteristics of Samarkand region in Zarafshon valley (Urgut, Samarkand, Djambay and Nurabad). Tests for food-stuffs and hairs of children were carried out by neutron-activation analysis as per method worked out in the Nuclear Physics institute of academy of Sciences Republic of Uzbekistan. We have studied 37 varieties of food-stuffs, mainly of vegetable and animal origin. 245 healthy school children were investigated for copper deficiency, aged 7-14. The results of the study showed high concentration of copper in the bread of coarse grist, black raisin, dried apricots, sumalak (national Uzbek food), pea, broth from vinery stalk (100, 51, 24, 36, 21, 33 mg/kg respectively). As for animal products high concentration of copper was in white of egg and beef (480 and 25 mg/kg respectively). Copper concentration was insignificant in many other investigated products of vegetable origin, but in 15 of them Neutron-activation analysis showed the absence of copper at all. Concentration of microelements in hairs is an important index of micro element status assessment. Copper concentration in hairs of practically healthy school children of Zarafshon valley made up 9,24 ± 0,84 mkg/g. Our data of copper in hairs of healthy school children in Zarafshon valley was lower compared the data stated by other investigators (A.A. Kist, 1987) and concerning other regions too. Lore copper content in hairs, probably depends on the structure of nutritional products consumed and peculiarities of natural condition of biogeochemical area. Os per sexual characters copper content in hairs was lore - 7,97±1,38 mkg/g in girls under investigation (n=33), compared myth boys (n=131) -9,67±0,71 mkg/g; as per place of residence, copper concentration indices in hairs was nearly the some as in urban (n=66) and rural (n=98) children (7,62 ± 0,96 and 8,38 ± 0,77 mg/kg, respectively). Thus, determination of

  19. Chemically designed Pt/PPy nano-composite for effective LPG gas sensor.

    Science.gov (United States)

    Gaikwad, Namrata; Bhanoth, Sreenu; More, Priyesh V; Jain, G H; Khanna, P K

    2014-03-07

    Simultaneous in situ reduction of hexachloroplatinic acid by the amine group in the pyrrole monomer and oxidation of pyrrole to form polypyrrole (PPy) was examined. The reactions were performed at various temperatures to understand the degree of reduction of platinum precursor as well as doping of polypyrrole with Pt(II) chloro-complex. Spectroscopic images revealed different morphologies for the Pt/PPy nano-composite prepared at various temperatures. The as-prepared Pt/PPy nano-composite samples were tested for their ability to sense liquefied petroleum gas (LPG) which resulted in excellent sensing at relatively low temperature. The porous nature and ohmic contact between the PPy and platinum nanoparticles makes the as-prepared Pt/PPy nano-composite highly useful for sensors as well as electronic applications.

  20. Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction

    Energy Technology Data Exchange (ETDEWEB)

    Aragao, Isaias Barbosa; Ro, Insoo; Liu, Yifei; Ball, Madelyn; Huber, George W.; Zanchet, Daniela; Dumesic, James A.

    2018-03-01

    FePt bimetallic catalysts with intimate contact between the two metals were synthesized by controlled surface reactions (CSR) of (cyclohexadiene)iron tricarbonyl with hydrogen-treated supported Pt nanoparticles. Adsorption of the iron precursor on a Pt/SiO2 catalyst was studied, showing that the Fe loading could be increased by performing multiple CSR cycles, and the efficiency of this process was linked to the renewal of adsorption sites by a reducing pretreatment. The catalytic activity of these bimetallic catalysts for the water gas shift reaction was improved due to promotion by iron, likely linked to H2O activation on FeOx species at or near the Pt surface, mostly in the (II) oxidation state.

  1. In vivo genetic toxicity studies in Chinese hamsters fed irradiated or unirradiated foodstuffs

    International Nuclear Information System (INIS)

    Altmann, H.

    1982-01-01

    Two in vivo genetic toxicity studies were performed in Chinese hamsters fed irradiated or unirradiated diets of chicken, fish or dates in order to detect possible mutagenic effects caused by irradiating these foodstuffs. The tests selected for study were: 1. Chromosomal analysis of bone narrow cells and 2. DNA metabolism in spleen cells. Chicken, fish and dates were irradiated with doses of 7, 2.5 and 1 kGy respectively. These investigations were subsequently extended to include the effects of irradiated dried onions, pulses and cocoa beans on DNA metabolism in Chinese hamster spleen cells only. Dried onions were irradiated with doses of 0.15, 9 and 15 kGy, pulses with 10 kGy and cocoa beans with 3.2 to 5 kGy. In addition, a fumigated cocoa bean group was included. No significant differences in chromosomal aberration rate were detected between groups fed irradiated or unirradiated diets. Dried dates, whether irradiated or not, showed some evidence of genetic toxicity in their effect on DNA metabolism in the spleen cells of Chinese hamsters. Both date diets caused more strand breaks DNA than are usual for Chinese hamster spleen cells, but DNA repair was not adversely affected. Chicken, both irradiated and unirradiated, was found to enhance replicative DNA synthesis but had no effect on the DNA repair process. Irradiated fish, however, caused enhanced DNA synthesis compared to unirradiated fish, but also had no adverse effect on DNA repair. Irradiated white beans also enhanced DNA synthesis compared to controls whereas unirradiated samples inhibited synthesis. (orig./MG)

  2. Thermoluminescence response of the poly mineral fraction from hibiscus sabdariffa L foodstuffs

    International Nuclear Information System (INIS)

    Cruz Z, E.; Guzman, S.; Brown, F.; Chernov, V.; Barboza F, M.

    2011-01-01

    Food processed by ionizing irradiation is a safe technology and has been recognized by the FAO/Who Codes Alimentarius Commission. It is an excellent method to prevent food spoilage and food borne diseases by inhibiting the growth of microorganisms and slowing down ripening. The widespread use of food irradiation treatments that include spices, dry vegetables, grains and fruits make relevant the developing of methods for identification and analyses of foodstuffs processed by irradiation. The present work focuses on the thermoluminescence property of Mexican Roselle flower previously irradiated for detection purposes. The poly mineral content of irradiated commercial Roselle flower (Hibiscus sabdariffa L.) was extracted and analyzed by thermoluminescence (Tl). The X-ray diffraction analyses showed that quartz and albite composition for the poly mineral fraction. Different grain sizes; 10, 53, 74 and 149 μm, were selected for the Tl analyses. The Tl glow curves depended on the grain sizes. The glow curves depicted two peaks around 92 and 120 C. The first peak was ascribed to quartz and the broad part of the glow curves (120-250 C) seems to correspond to the albite. Because the complex structure of the Tl glow curves from poly minerals the kinetic parameters were calculated by a fitting process using a deconvolution method based on a non-linear least-squares Levenberg-Ma quart. The values of the activation energy were found to be at 0.79-1.05 eV and 0.79-1.04 for 53 μm and 250 μm, respectively. The Tl properties of the samples were determined including dose response, reproducibly, fading and UV light bleaching. (Author)

  3. Thermoluminescence response of the poly mineral fraction from hibiscus sabdariffa L foodstuffs

    Energy Technology Data Exchange (ETDEWEB)

    Cruz Z, E.; Guzman, S. [UNAM, Instituto de Ciencias Nucleares, Apdo. Postal 70-543, 04510 Mexico D. F. (Mexico); Brown, F. [Universidad de Sonora, Departamento de Investigacion en Polimeros y Materiales, Apdo. Postal 130, 83000 Hermosillo, Sonora (Mexico); Chernov, V.; Barboza F, M., E-mail: ecruz@nucleares.unam.m [Universidad de Sonora, Departamento de Investigacion en Fisica, Apdo. Postal 5-088, 83190 Hermosillo, Sonora (Mexico)

    2011-02-15

    Food processed by ionizing irradiation is a safe technology and has been recognized by the FAO/Who Codes Alimentarius Commission. It is an excellent method to prevent food spoilage and food borne diseases by inhibiting the growth of microorganisms and slowing down ripening. The widespread use of food irradiation treatments that include spices, dry vegetables, grains and fruits make relevant the developing of methods for identification and analyses of foodstuffs processed by irradiation. The present work focuses on the thermoluminescence property of Mexican Roselle flower previously irradiated for detection purposes. The poly mineral content of irradiated commercial Roselle flower (Hibiscus sabdariffa L.) was extracted and analyzed by thermoluminescence (Tl). The X-ray diffraction analyses showed that quartz and albite composition for the poly mineral fraction. Different grain sizes; 10, 53, 74 and 149 {mu}m, were selected for the Tl analyses. The Tl glow curves depended on the grain sizes. The glow curves depicted two peaks around 92 and 120 C. The first peak was ascribed to quartz and the broad part of the glow curves (120-250 C) seems to correspond to the albite. Because the complex structure of the Tl glow curves from poly minerals the kinetic parameters were calculated by a fitting process using a deconvolution method based on a non-linear least-squares Levenberg-Ma quart. The values of the activation energy were found to be at 0.79-1.05 eV and 0.79-1.04 for 53 {mu}m and 250 {mu}m, respectively. The Tl properties of the samples were determined including dose response, reproducibly, fading and UV light bleaching. (Author)

  4. Developmental selenium exposure and health risk in daily foodstuffs: A systematic review and meta-analysis.

    Science.gov (United States)

    Ullah, Habib; Liu, Guijian; Yousaf, Balal; Ali, Muhammad Ubaid; Abbas, Qumber; Munir, Mehr Ahmed Mujtaba; Mian, Md Manik

    2018-03-01

    Selenium (Se) is a trace mineral and an essential nutrient of vital importance to human health in trace amounts. It acts as an antioxidant in both humans and animals, immunomodulator and also involved in the control of specific endocrine pathways. The aim of this work is to provide a brief knowledge on selenium content in daily used various foodstuffs, nutritional requirement and its various health consequences. In general, fruits and vegetables contain low content of selenium, with some exceptions. Selenium level in meat, eggs, poultry and seafood is usually high. For most countries, cereals, legumes, and derivatives are the major donors to the dietary selenium intake. Low level of selenium has been related with higher mortality risk, dysfunction of an immune system, and mental failure. Selenium supplementation or higher selenium content has antiviral outcomes and is necessary for effective reproduction of male and female, also decreases the threat of chronic disease (autoimmune thyroid). Generally, some advantages of higher content of selenium have been shown in various potential studies regarding lung, colorectal, prostate and bladder cancers risk, nevertheless results depicted from different trials have been diverse, which perhaps indicates the evidence that supplementation will merely grant advantage if the intakes of a nutrient is deficient. In conclusion, the over-all people should be advised against the usage of Se supplements for prevention of cardiovascular, hepatopathies, or cancer diseases, as advantages of Se supplements are still ambiguous, and their haphazard usage could result in an increased Se toxicity risk. The associations among Se intake/status and health, or disease risk, are complicated and need exposition to notify medical practice, to improve dietary recommendations, and to develop adequate communal health guidelines. Copyright © 2017 Elsevier Inc. All rights reserved.

  5. Assessment of Trace Element Daily Intake Based on Consumption Rate of Foodstuffs in Bandung City

    International Nuclear Information System (INIS)

    Damastuti, E.; Syahfitri, W.Y.N.; Santoso, M.; Lestiani, D.D.

    2012-01-01

    Trace elements are required by human body and have a variety role in biochemical functions mostly as catalyst for enzymatic activity in human body. Some trace elements are essential since they are inadequately or not synthesized by human body. The deficiency or excess of those essential trace element may cause disease and be deleterious to health. Since food is the primary source of essential elements for humans and it is an important source of exposure to toxic elements either, the levels of trace elements in consumed food products must be determined. The determination of trace elements content in foodstuffs widely consumed in Bandung city were conducted to assess their daily intake and contribution to the recommended dietary allowance (RADA) values. Food samples were collected from traditional markets spread across five regions of the Bandung city and analyzed using neutron activation analysis (NAA). Quality control of data analysis was assessed using SRM NIST 1567a Wheat Flour and 1568a Rice Flour and gave good results with % recovery, 93.2 - 104.8%; and %CV, 3.8-11.6%. A large variability of essential trace elements concentration in all types of foods analyzed were observed. The daily intake of Cr, Co, Mn, Se and Zn were supplied enough by the diet, except for Fe which found that almost all the foods analyzed were not give a satisfying contribution to the RDA value of Fe. These result were expected could provide information of nutritional status of the society and can be a reference for government and related institution to effectively making policies and solution for public health improvement (author)

  6. THE D-AMINO ACID CONTENT OF FOODSTUFFS SUBJECTED TO VARIOUS TECHNOLOGICAL PROCEDURES

    Directory of Open Access Journals (Sweden)

    János Csapó

    2000-06-01

    Full Text Available D-amino acids occurring in dietary proteins originate as a consequence of technological intervention while basic materials are being prepared for consumption. Foodstuffs are the most significant sources of D-amino acids, as in the process of cooking or during the various processing procedures used in the food industry dietary proteins undergo racemisation to a greater or lesser degree. Food stores are now selling increasing quantities of foods (such as breakfast cereals, baked potatoes, liquid and powdered infant foods, meat substitutes and other supplements which in some cases contain substantial quantities of D-amino acids, which in turn possess characteristics harmful with respect to digestion and health. Alkali treatment catalyses the racemisation of optically active amino acids. The degree of racemisation undergone varies from protein to protein, but the relative order of the degree of racemisation of the individual amino acids within proteins shows a high level of similarity. The principal factors influencing racemisation are the pH of the medium, heat treatment, the duration of the application of alkaline treatment and the structure of the respective amino acids. D-amino acids formed in the course of treatment with alkalis or heat give rise to a deterioration in quality and reduce the extent to which food thus treated can be used safely. The presence of D-amino acids in proteins leads to a decrease in digestibility and the availability of the other amino acids. This results in a reduction in the quantities of the L-enantiomers of the essential amino acids, as the peptide bonds cannot split in the normal way. Some D-amino acids can exert an isomer-toxic effect and have the capacity to give rise to changes in the biological effect of lysinoalanine.

  7. A survey of arsenic in foodstuffs on sale in the United Kingdom and imported from Bangladesh

    International Nuclear Information System (INIS)

    Al Rmalli, S.W.; Haris, P.I.; Harrington, C.F.; Ayub, M.

    2005-01-01

    Arsenic is a highly toxic element and its presence in food composites is a matter of concern to the well being of both humans and animals. Arsenic-contaminated groundwater is often used in Bangladesh and West Bengal (India) to irrigate crops used for food and animal consumption, which could potentially lead to arsenic entering the human food chain. In this study, we used graphite furnace atomic absorption spectroscopy to determine the total arsenic concentrations in a range of foodstuffs, including vegetables, rice and fish, imported into the United Kingdom from Bangladesh. The mean and range of the total arsenic concentration in all the vegetables imported from Bangladesh were 54.5 and 5-540 μg/kg, respectively. The highest arsenic values found were for the skin of Arum tuber, 540 μg/kg, followed by Arum Stem, 168 μg/kg, and Amaranthus, 160 μg/kg. Among the other samples, freshwater fish contained total arsenic levels between 97 and 1318 μg/kg. The arsenic content of the vegetables from the UK was approximately 2- to 3-fold lower than those observed for the vegetables imported from Bangladesh. The levels of arsenic found in vegetables imported from Bangladesh in this study, in some cases, are similar to those previously recorded for vegetables grown in arsenic-affected areas of West Bengal, India, although lower than the levels reported in studies from Bangladesh. While the total arsenic content detected in our study in vegetables, imported from Bangladesh, is far less than the recommended maximum permitted level of arsenic, it does provide an additional source of arsenic in the diet. This raises the possibility that the level of arsenic intake by certain sectors of the UK population may be significantly higher then the general population and requires further investigations

  8. Analysis of 3-MCPD and 1,3-DCP in Various Foodstuffs Using GC-MS

    Science.gov (United States)

    Kim, Wooseok; Jeong, Yun A; On, Jiwon; Choi, Ari; Lee, Jee-yeon; Lee, Joon Goo; Lee, Kwang-Geun

    2015-01-01

    3-Monochloro-1,2-propanediol (3-MCPD) and 1,3-dichloro-2-propanol (1,3-DCP) are not only produced in the manufacturing process of foodstuffs such as hydrolyzed vegetable proteins and soy sauce but are also formed by heat processing in the presence of fat and low water activity. 3-MCPD exists both in free and ester forms, and the ester form has been also detected in various foods. Free 3-MCPD and 1,3-DCP are classified as Group 2B by the International Agency for Research on Cancer. Although there is no data confirming the toxicity of either compound in humans, their toxicity was evidenced in animal experimentation or in vitro. Although few studies have been conducted, free 3-MCPD has been shown to have neurotoxicity, reproductive toxicity, and carcinogenicity. In contrast, 1,3-DCP only has mutagenic activity. The purpose of this study was to analyze 3-MCPD and 1,3-DCP in various foods using gas chromatography -mass spectrometry. 3-MCPD and 1,3-DCP were analyzed using phenyl boronic acid derivatization and the liquid–liquid extraction method, respectively. The analytical method for 3-MCPD and 1,3-DCP was validated in terms of linearity, limit of detection (LOD), limit of quantitation, accuracy and precision. Consequently, the LODs of 3-MCPD and 1,3-DCP in various matrices were identified to be in the ranges of 4.18~10.56 ng/g and 1.06~3.15 ng/g, respectively. PMID:26483891

  9. Assessment of Trace Element Daily Intake Based on Consumption Rate of Foodstuffs in Bandung City

    Directory of Open Access Journals (Sweden)

    E. Damastuti

    2012-04-01

    Full Text Available Trace elements are required by human body and have a variety role in biochemical functions mostly as catalyst for enzymatic activity in human body. Some trace elements are essential since they are inadequately or not synthesized by human body. The deficiency or excess of those essential trace element may cause disease and be deleterious to health. Since food is the primary source of essential elements for humans and it is an important source of exposure to toxic elements either, the levels of trace elements in consumed food products must be determined. The determination of trace elements content in foodstuffs widely consumed in Bandung city were conducted to assess their daily intake and contribution to the recommended dietary allowance (RDA values. Food samples were collected from traditional markets spread across five regions of the Bandung city and analyzed using neutron activation analysis (NAA. Quality control of data analysis was assessed using SRM NIST 1567a Wheat Flour and 1568a Rice Flour and gave good results with % recovery, 93.2 – 104.8%; and %CV, 3.8-11.6%. A large variability of essential trace elements concentration in all types of foods analyzed were observed. The daily intake of Cr, Co, Mn, Se and Zn were supplied enough by the diet, except for Fe which found that almost all the foods analyzed were not give a satisfying contribution to the RDA value of Fe. These result were expected could provide information of nutritional status of the society and can be a reference for government and related institution to effectively making policies and solution for public health improvement

  10. Low Pt content direct methanol fuel cell anode catalyst: nanophase PtRuNiZr

    Science.gov (United States)

    Narayanan, Sekharipuram R. (Inventor); Whitacre, Jay F. (Inventor)

    2010-01-01

    A method for the preparation of a metallic material having catalytic activity that includes synthesizing a material composition comprising a metal content with a lower Pt content than a binary alloy containing Pt but that displays at least a comparable catalytic activity on a per mole Pt basis as the binary alloy containing Pt; and evaluating a representative sample of the material composition to ensure that the material composition displays a property of at least a comparable catalytic activity on a per mole Pt basis as a representative binary alloy containing Pt. Furthermore, metallic compositions are disclosed that possess substantial resistance to corrosive acids.

  11. Results of the Proficiency Test, PT1 and PT2, 2012

    DEFF Research Database (Denmark)

    Vendramin, Niccolò; Nicolajsen, Nicole; Christophersen, Maj-Britt

    A comparative test of diagnostic procedures was provided by the European Union Reference Laboratory (EURL) for Fish Diseases. The test was divided into proficiency test 1 (PT1) and proficiency test 2 (PT2). The number of National Reference Laboratories (NRLs) participating in PT1 and PT2 was 43. ....... The tests were sent from the EURL in the beginning of September 2012. Both PT1 and PT2 are accredited by DANAK under registration number 515 for proficiency testing according to the quality assurance standard DS/EN ISO/IEC 17043....

  12. Pt Skin Versus Pt Skeleton Structures of Pt3Sc as Electrocatalysts for Oxygen Reduction

    DEFF Research Database (Denmark)

    Johansson, Tobias Peter; Ulrikkeholm, Elisabeth Therese; Hernandez-Fernandez, Patricia

    2014-01-01

    . The development of new materials for this reaction is essential in order to increase the overall effeciency of the fuel cell. Herein, we study the effect of ultra high vacuum annealing on the structure and activity of polycrystalline Pt3Sc. Upon annealing in ultra high vacuum a Pt overlayer is formed......, relative to Pt(111), consistent with the CO adsorption energies calculated using density functional theory calculations. Exposing the annealed Pt3Sc sample to 200 mbar O2 at room temperature results in similar to 14 % Sc oxide as measured by X-ray photoelectron spectroscopy. Electrochemical testing...

  13. Exchange coupled CoPt/FePtC media for heat assisted magnetic recording

    Science.gov (United States)

    Dutta, Tanmay; Piramanayagam, S. N.; Ru, Tan Hui; Saifullah, M. S. M.; Bhatia, C. S.; Yang, Hyunsoo

    2018-04-01

    L10 FePtC granular media are being studied as potential future magnetic recording media and are set to be used in conjunction with heat assisted magnetic recording (HAMR) to enable recording at write fields within the range of current day recording heads. Media structures based on a FePtC storage layer and a capping layer can alleviate the switching field distribution (SFD) requirements of HAMR and reduce the noise originating from the writing process. However, the current designs suffer from SFD issues due to high temperature writing. To overcome this problem, we study a CoPt/FePtC exchange coupled composite structure, where FePtC serves as the storage layer and CoPt (with higher Curie temperature, Tc) as the capping layer. CoPt remains ferromagnetic at near Tc of FePtC. Consequently, the counter exchange energy from CoPt would reduce the noise resulting from the adjacent grain interactions during the writing process. CoPt/FePtC bilayer samples with different thicknesses of CoPt were investigated. Our studies found that CoPt forms a continuous layer at a thickness of 6 nm and leads to considerable reduction in the saturation field and its distribution.

  14. Luminescence and structure of manganese(II) halogenides. Pt. 1

    International Nuclear Information System (INIS)

    Oelkrug, D.; Kempny, W.

    1976-01-01

    The luminescence decay times tau and luminescence intensities I of the mixed crystals Mnsub(x)Cdsub(1-x)Hal 2 (Hal = Bl, Br, J; x 6 -octahedra and of some compounds A 2 MnHal 4 (A = large cation) with unlinked MnHal 4 -tetrahedra were investigated between 4.2 K and 295 K. In Osub(h)-coordinated compounds tau decreases with increasing temperature, most strongly in the iodide namely by a factor of five. On the other hand I correspondingly increases to the same extent so that in all cases I x tau = const. That justifies the assumption of quantum yields independent of temperature with the ideal value of one. In Tsub(d)-coordinated compounds tau and I taken as such are constant in the whole temperature range. The Osub(h) - Tsub(d) contrast in tau and I is attributed to oscillator strengths either dependent on temperature or constant. In the case of MnHal 6 coordination the dependency on temperature may be expressed by the function ctgh(hνc/2kT), (νsub(J) = 80, νsub(Br) = 140, νsub(Cl) = 190 cm -1 ), νsup(Hal) very well corresponding with the mean value of the odd optical k = 0 phonons in the CdHal 2 lattice. (orig.) [de

  15. trans-[Pt(BCat')Me(PCy3)2]: an experimental case study of reductive elimination processes in Pt-Boryls through associative mechanisms.

    Science.gov (United States)

    Braunschweig, Holger; Bertermann, Rüdiger; Brenner, Peter; Burzler, Michael; Dewhurst, Rian D; Radacki, Krzysztof; Seeler, Fabian

    2011-10-10

    A stable trans-(alkyl)(boryl) platinum complex trans-[Pt(BCat')Me(PCy(3))(2)] (Cat'=Cat-4-tBu; Cy=cyclohexyl=C(6)H(11)) was synthesised by salt metathesis reaction of trans-[Pt(BCat')Br(PCy(3))(2)] with LiMe and was fully characterised. Investigation of the reactivity of the title compound showed complete reductive elimination of Cat'BMe at 80 °C within four weeks. This process may be accelerated by the addition of a variety of alkynes, thereby leading to the formation of the corresponding η(2) -alkyne platinum complexes, of which [Pt(η(2)-MeCCMe)(PCy(3))(2)] was characterised by X-ray crystallography. Conversion of the trans-configured title compound to a cis derivative remained unsuccessful due to an instantaneous reductive elimination process during the reaction with chelating phosphines. Treatment of trans-[Pt(BCat')Me(PCy(3))(2)] with Cat(2)B(2) led to the formation of CatBMe and Cat'BMe. In the course of further investigations into this reaction, indications for two indistinguishable reaction mechanisms were found: 1) associative formation of a six-coordinate platinum centre prior to reductive elimination and 2) σ-bond metathesis of B-B and C-Pt bonds. Mechanism 1 provides a straightforward explanation for the formation of both methylboranes. Scrambling of diboranes(4) Cat(2)B(2) and Cat'(2)B(2) in the presence of [Pt(PCy(3))(2)], fully reductive elimination of CatBMe or Cat'BMe from trans-[Pt(BCat')Me(PCy(3))(2)] in the presence of sub-stoichiometric amounts of Cat(2)B(2), and evidence for the reversibility of the oxidative addition of Cat(2)B(2) to [Pt(PCy(3))(2)] all support mechanism 2, which consists of sequential equilibria reactions. Furthermore, the solid-state molecular structure of cis-[Pt(BCat)(2)(PCy(3))(2)] and cis-[Pt(BCat')(2)(PCy(3))(2)] were investigated. The remarkably short B-B separations in both bis(boryl) complexes suggest that the two boryl ligands in each case are more loosely bound to the Pt(II) centre than in related bis

  16. Nanoscale compositional changes and modification of the surface reactivity of Pt3Co/C nanoparticles during proton-exchange membrane fuel cell operation

    International Nuclear Information System (INIS)

    Dubau, L.; Maillard, F.; Chatenet, M.; Andre, J.; Rossinot, E.

    2010-01-01

    This study bridges the structure/composition of Pt-Co/C nanoparticles with their surface reactivity and their electrocatalytic activity. We show that Pt 3 Co/C nanoparticles are not stable during PEMFC operation (H 2 /air; j = 0.6 A cm -2 , T = 70 o C) but suffer compositional changes at the nanoscale. In the first hours of operation, the dissolution of Co atoms at their surface yields to the formation of a Pt-enriched shell covering a Pt-Co alloy core ('Pt-skeleton') and increases the affinity of the surface to oxygenated and hydrogenated species. This structure does not ensure stability in PEMFC conditions but is rather a first step towards the formation of 'Pt-shell/Pt-Co alloy core' structures with depleted Co content. In these operating conditions, the Pt-Co/C specific activity for the ORR varies linearly with the fraction of Co alloyed to Pt present in the core and is severely depreciated (ca. -50%) after 1124 h of operation. This is attributed to: (i) the decrease of both the strain and the ligand effect of Co atoms contained in the core (ii) the changes in the surface structure of the electrocatalyst (formation of a multilayer-thick Pt shell) and (iii) the relaxation of the Pt surface atoms.

  17. Project desk evaluation of a model project CPR/5/009 industrial scale irradiation of rice and other foodstuffs

    International Nuclear Information System (INIS)

    1996-11-01

    The project CPR/5/009 was approved in 1993 as a model project. The project objective was to build an industrial food irradiation facility for high quality rice and other foodstuffs, with a processing capacity of 5000-9000 tonnes per year. This capacity is large compared to many other facilities of the same type elsewhere. The success of the project waste to be measured against the full utilization of the facility with an acceptable availability factor. Disbursements on Agency inputs up to the end of June 1996 were $294,716 and consisted of one 100 kCi Co-60 source, quality control equipment, bag heat sealers, one expert mission and 13.5 months of training abroad. The current budget is $323,870, following two programme changes. The total cost of the project was estimated at $1,331,300 with the Chinese Government providing the balance. The major conclusions of this evaluation are as follows: Initially, the Agency overestimated the project and business management experience of the counterpart, and consequently underestimated the extent of support required. Providing support to counterparts in facing the key challenges of project management and business operation must be considered by the Agency in future projects of this type. The counterpart institution is also encouraged to emphasize these management issues in order to maximize sustainable and cost-effective utilization of such facilities. A new operational plan has been prepared by the counterpart for 1996 through 1998 which identifies seven customers requiring treatment of a total of 1000 tonnes per year of cereal grains and 1500 tonnes per year of other foodstuffs. This plan reflects a change in overall emphasis from supporting food supply security to ensuring the safety of foodstuffs. It is not clear whether this plan will support operation of the facility at full capacity. The team in place to operate the facility also needs further strengthening. (author). Figs, tabs

  18. The concentration of Fe and Zn in food-stuff of agriculture, husbandry and fishery determined by k0-INAA

    International Nuclear Information System (INIS)

    Th Rina Mulyaningsih

    2009-01-01

    Deficiency of iron (Fe) and zinc (Zn) micronutrient was suffered by population Therefore the determination of Fe and Zn in agriculture, husbandry, and fishery were carried out. The objective of this research is to estimate Fe and Zn intake through consumed food-stuff. Sampling was done in Pasar Serpong, while Fe and Zn was determined by k 0 - instrumental neutron activation analysis (k 0 -INAA). The result of analysis indicated that concentration of Fe and Zn in beef, goat and goat liver were >150 µg/g, in chicken flesh were around 30 µg/g. This food-stuff is good as source intake of Fe and Zn, due to level of consumption was low i.e. 0.001 - 0.018 kg/day, so its intake was lower enough i.e. 0.1 - 0.5 mg/day. The concentration of Fe and Zn in rice were < 50 µg/g, but because of consume level is high enough 0.3 kg/day, so Fe and Zn intake from rice is high enough. Zn and Fe content in spinach is 119 µg/g and 248 µg/g, Zn and Fe content in Kangkung is 54.84 µg/g, and 337 µg/g, and with consume level of ~0.015 kg/day it is good source of Zn arid Fe intake i.e 0.8 - 3.5 mg/day. The concentration of Zn in egg was 39.0184 µg/g and Fe was 74.45 µg/g because of level consume is higher than chicken flesh, so Zn and Fe intake from egg is higher than from chicken flesh, i.e. 0.85 - 1.64 mg/day. By knowing Fe and Zn concentration in foodstuff, supported with its consume level, Zn and Fe intake every day can be estimated. (author)

  19. 46 CFR Appendix II to Part 150 - Explanation of Figure 1

    Science.gov (United States)

    2010-10-01

    ... COMPATIBILITY OF CARGOES Pt. 150, App. II Appendix II to Part 150—Explanation of Figure 1 Definition of a..., aromatic hydrocarbons or paraffins. Others will form hazardous combinations with many groups: For example...

  20. Determination of Cs-134 and Cs-137 in different food-stuffs and environmental-stuffs collected from Serina area in Lombardy

    International Nuclear Information System (INIS)

    Rimoldi, E.M.; Di Giancamillo, M.; Cavallone, E.; Brambilla, P.

    1999-01-01

    After the explosion of the reactor n°4 in the Ukrainian Nuclear Power Plant of Chernobyl, the highest radioactive contamination in Italy was observed in Lumbardy. In 1996, ten years after the Chernobyl's accident, the Authors carried out an investigation on soil samples from Serina area, in the district of Bergamo. N°158 samples have been analysed by NaI(Tl) detector (3x3), collected from surface soil and subsoil, running and stagnating waters, mosses, lichens, mushrooms, water-plants, fodder leafage, berries, pine-needles, striated muscle from cattle, sheep, chamois, roe-deer, milk and cheeses from cow and goat, chicken eggs. In all the soil samples analysed Cs-137 was detectable, and its activity was constantly higher in surface soil samples and particularly in those from woods. In May, the seasonal fallout period at our latitudes, it has been detected on Alben Mount a light fallout of Cs-134. In the samples collected on poly-phyto meadows no trace of Cs-137 has been detected, while in samples from wood's ecosystem this isotope was always detectable. Cs-137 was also present in the muds of the bottom of a small natural alpine lake and in water-plants there growing. On the basis of these data the Authors infer that mosses and lichens are the best markers of environmental contamination due to Cs-137. They suggest that it is absolutely necessary to continue to control regularly every substrate included in the food chain and of zootechnic and environmental interest with the following aims: i) to study the capacity of various ecosystems to metabolize the products derived from the Chernobyl's accident; ii) to safeguard the public health against future emergencies: iii) to keep under control foodstuff for human and animal feeding, which, because of the markets' globalization, can arrive from everywhere

  1. Comparison of gas chromatographic and gravimetric methods for quantization of total fat and fatty acids in foodstuffs

    Directory of Open Access Journals (Sweden)

    Sabria Aued-Pimentel

    2010-01-01

    Full Text Available Different methods to determine total fat (TF and fatty acids (FA, including trans fatty acids (TFA, in diverse foodstuffs were evaluated, incorporating gravimetric methods and gas chromatography with flame ionization detector (GC/FID, in accordance with a modified AOAC 996.06 method. Concentrations of TF and FA obtained through these different procedures diverged (p< 0.05 and TFA concentrations varied beyond 20 % of the reference values. The modified AOAC 996.06 method satisfied both accuracy and precision, was fast and employed small amounts of low toxicity solvents. Therefore, the results showed that this methodology is viable to be adopted in Brazil for nutritional labeling purposes.

  2. Trace-Determination of Cadmium by Neutron Activation. Application to Air-Borne Particulates, Hair and Foodstuffs. RCN Report

    International Nuclear Information System (INIS)

    Das, H.A.; Vries, H.H. de

    1971-01-01

    This study describes a routine-procedure by neutron activation for the determination of cadmium in industrial air-borne particulate samples, collected on filter paper, hair and foodstuffs. The reaction used is 114 Cd(n, γ) 115 Cd (β)/→ T½ = 53.5 h 115m In (β)/ → T½ = 4.5 h 115 In Cadmium is isolated by liquid-liquid extraction with a chloroform solution of dithizone. The activity of the 115 In-daughter is counted. The method was tested by analysis of the standard kale powder. (author)

  3. Impact of arsenic in foodstuffs on the people living in the arsenic-affected areas of West Bengal, India.

    Science.gov (United States)

    Mandal, Badal K; Suzuki, Kazuo T; Anzai, Kazunori

    2007-10-01

    Although the accumulation of arsenic (As) in human blood is linked with some diseases and with occupational exposure, there are few reports on speciation of As in blood. On the basis of our earlier article, elevated level of arsenicals in human urine and blood were found in the ex-exposed population via As-containing drinking water. The aim of the present study was to get an insight on impact of As in foodstuffs on the people living in the As-affected areas. Moreover, speciation of arsenicals in urine, and water-samples found in arsenobetaine (AsB). Since sampling population (n=25) was not taking any seafood, As in foodstuffs was thought to be the prime source for this discrepancy. So, speciation of methanol extract of freeze-dried red blood cells (RBCs) and foodstuffs, and trichloro acetic acid (TCA) treated plasma by high performance liquid chromatography-inductively coupled argon plasma mass spectrometer (HPLC-ICP MS) collected from the study population (n=33) was carried out to support our hypothesis. Results showed that urine contained AsB (1.7%), arsenite (iAs(III)) (14.3), arsenate (iAs(V)) (4.9), monomethylarsonous acid (MMA(III)) (0.64), monomethylarsonic acid (MMA(V)) (13.6), dimethylarsinous acid (DMA(III)) (7.7), and dimethylarsinic acid (DMA(V)) (65.4). Blood contained 21.3 microg L(- 1) (mean) As and of which 27.3% was in plasma and 72.7% in RBCs. RBCs contained AsB (21.6%) and DMA(V) (78.4) and blood plasma contained AsB (12.4%), iAs(III) (25.9), MMA(V) (30.3), and DMA(V) (31.4). Furthermore, speciation of As in foodstuffs showed that most of them contained AsB (3.54-25.81 microg kg(- 1)) (25.81-312.44 microg kg(- 1)) along with iAs(III) (9.62-194.93), iAs(V) (17.63-78.33), MMA(V) (9.47-73.22) and DMA(V) (13.43-101.15) that supported the presence of AsB and elevated As in urine and blood samples of the present study group. Inorganic As (iAs) predominates in rice (67.17-86.62%) and in spices (40-90.35%), respectively over organic As. So, As in the

  4. A regenerable piezoelectric immunosensor on the basis of electropolymerized polypyrrole for highly selective detection of Staphylococcal Enterotoxin A in foodstuffs

    International Nuclear Information System (INIS)

    Karaseva, Nadezhda; Ermolaeva, Tatyana

    2015-01-01

    Piezoelectric immunosensors have been developed for the determination of trace concentrations of Staphylococcal enterotoxin A (SEA) in foodstuff. Antibodies against SEA were covalently immobilized on an electropolymerized polypyrrole substrate on a gold electrode which warrants increased stability of the biolayer and sensitive detection. The calibration plot is linear in the 1–80 ng∙mL -1 SEA concentration range, the limit of detection is 0.4 ng∙mL -1 , and the time of analysis is <30 min. The sensor was successfully applied to quantify SEA in chicken meat and milk. (author)

  5. Remarks on the PT-pseudo-norm in PT-symmetric quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Duc Tai Trinh [Department of Mathematics, Teacher Training College of Dalat, 29 Yersin, Dalat (Viet Nam)]|[Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, Trieste 34014 (Italy)

    2005-04-22

    This paper presents an underlying analytical relationship between the PT-pseudo-norm associated with the PT-symmetric Hamiltonian H = p{sup 2} + V(q) and the Stokes multiplier of the differential equation corresponding to this Hamiltonian. We show that the sign alternation of the PT-pseudo-norm, which has been observed as a generic feature of the PT-inner product, is essentially controlled by the derivative of a Stokes multiplier with respect to the eigenparameter.

  6. Hydrogenation of Phenol over Pt/CNTs: The Effects of Pt Loading and Reaction Solvents

    OpenAIRE

    Feng Li; Bo Cao; Wenxi Zhu; Hua Song; Keliang Wang; Cuiqin Li

    2017-01-01

    Carbon nanotubes (CNTs)-supported Pt nanoparticles were prepared with selective deposition of Pt nanoparticles inside and outside CNTs (Pt–in/CNTs and Pt–out/CNTs). The effects of Pt loading and reaction solvents on phenol hydrogenation were investigated. The Pt nanoparticles in Pt–in/CNTs versus Pt–out/CNTs are smaller and better dispersed. The catalytic activity and reuse stability toward phenol hydrogenation both improved markedly. The dichloromethane–water mixture as the reaction solvent,...

  7. KUALITAS AIR LIMBAH PABRIK KERTAS PT. BALI KERTAS MITRA JEMBRANA

    Directory of Open Access Journals (Sweden)

    l KETUT SUNDRA

    2015-05-01

    Full Text Available PT. Bali Paper Mitra Jembrana is a business unit engaged in manufacturing or recycling (recycle waste paper (cardboard into a thin paper which is known as rice paper wrap. This business has been operational since 2004 the paper every day to process anaverage of 13 tonnes of waste paper and produces an average of 10 tons/ day. The production requires 90 m3/day of ground water: 50 m3 for the cleaning cloth (shower system and 40 m3 for cooling boiler. Heating using coal with a volume of one ton/ day. Steam heat from the boiler used for drying paper. From this process, the 90 m3 of ground water pruducted 60 m3/ day wastewater into lagoon. Waste treatment system of PT. Paper Jembr ana is still a semi-permanent using 5 lagoon with a capacit y of 651 m3. The purpose of this study was to determine the factual quality of water in physical and chemical wastewater produced PT. Bali Paper Mitra Jembrana which will be used as a data base for monitoring and management for stake holder and government. The results show, at the end of the treatment there are 5 parameters which exceeds Waste Water Quality St and ard Class II (LH Decree No. 5 of 1995 such as BODS, COD, phenols, sulfide (H2S and lead (Pb, so it is not feasible discarded to the outside environment.

  8. Electron transport in a Pt-CO-Pt nanocontact: Density functional theory calculations

    DEFF Research Database (Denmark)

    Strange, Mikkel; Thygesen, Kristian Sommer; Jacobsen, Karsten Wedel

    2006-01-01

    We have performed first-principles calculations for the mechanic and electric properties of pure Pt nanocontacts and a Pt contact with a single CO molecule adsorbed. For the pure Pt contacts we see a clear difference between point contacts and short chains in good agreement with experiments. We...

  9. Human health risks related to the consumption of foodstuffs of animal origin contaminated by bisphenol A.

    Science.gov (United States)

    Gorecki, Sébastien; Bemrah, Nawel; Roudot, Alain-Claude; Marchioni, Eric; Le Bizec, Bruno; Faivre, Franck; Kadawathagedara, Manik; Botton, Jérémie; Rivière, Gilles

    2017-12-01

    Bisphenol A (BPA) is used in a wide variety of products and objects for consumers use (digital media such as CD's and DVD's, sport equipment, food and beverage containers, medical equipment). For humans, the main route of exposure to BPA is food. Based on previous estimates, almost 20% of the dietary exposure to BPA in the French population would be from food of animal origin. However, due to the use of composite samples, the source of the contamination had not been identified. Therefore, 322 individual samples of non-canned foods of animal origin were collected with the objectives of first updating the estimation of the exposure of the French population and second identifying the source of contamination of these foodstuffs using a specific analytical method. Compared to previous estimates in France, a decline in the contamination of the samples was observed, in particular with regard to meat. The estimated mean dietary exposures ranged from 0.048 to 0.050 μg (kg bw) -1 d -1 for 3-17 year children and adolescents, from 0.034 to 0.035 μg (kg bw) -1 d -1 for adults and from 0.047 to 0.049 μg (kg bw) -1 d -1 for pregnant women. The contribution of meat to total dietary exposure of pregnant women, adults and children was up to three times lower than the previous estimates. Despite this downward trend in contamination, the toxicological values were observed to have been exceeded for the population of pregnant women. With the aim of acquiring more knowledge about the origin the potential source(s) of contamination of non-canned foods of animal origin, a specific analytical method was developed to directly identify and quantify the presence of conjugated BPA (BPA-monoglucuronide, BPA-diglucuronide and sulphate forms) in 50 samples. No conjugated forms of BPAs were detected in the analysed samples, indicating clearly that BPA content in animal food was not due to metabolism but arise post mortem in food. This contamination may occur during food production. However

  10. cobalt (ii), nickel (ii)

    African Journals Online (AJOL)

    DR. AMINU

    Department of Chemistry Bayero University, P. M. B. 3011, Kano, Nigeria. E-mail: hnuhu2000@yahoo.com. ABSTRACT. The manganese (II), cobalt (II), nickel (II) and .... water and common organic solvents, but are readily soluble in acetone. The molar conductance measurement [Table 3] of the complex compounds in.

  11. Tuning magnetic properties of non-collinear magnetization configuration in Pt/[Pt/Co]{sub 6}/Pt/Co/Pt multilayer structure

    Energy Technology Data Exchange (ETDEWEB)

    Kalaycı, Taner, E-mail: taner.kalayci@marmara.edu.tr [Department of Physics, Marmara University, 34722, Kadıköy, Istanbul (Turkey); Deger, Caner [Department of Physics, Marmara University, 34722, Kadıköy, Istanbul (Turkey); Akbulut, Salih [Department of Physics, Gebze Technical University, 41400, Gebze, Kocaeli (Turkey); Yildiz, Fikret, E-mail: fyildiz@gtu.edu.tr [Department of Physics, Gebze Technical University, 41400, Gebze, Kocaeli (Turkey)

    2017-08-15

    Highlights: • Effects of Pt spacer and reference layers thickness are investigated by MOKE and FMR. • Controlling of non-collinear states in multilayered thin film systems is studied. • Micromagnetic approach is used for modeling of magnetic multilayered structure. • Magnetic parameters are determined by a simulation based on metropolis algorithm. - Abstract: In this study, effects of Pt spacer and Co reference layers thickness in [Co/Pt]{sub 6}/Pt/Co multilayer have been revealed to tailor magnetization directions in non-collinear configuration. Magneto-optic Kerr effect and ferromagnetic resonance techniques were employed to investigate magnetic properties. Bilinear coupling between [Co/Pt]{sub 6} and Co layers and anisotropy constants were determined by a micromagnetic simulation based on metropolis algorithm. 3 nm spacer causes ferromagnetic coupling while the samples have 4 and 5 nm spacer are coupled anti-ferromagneticaly. Also, tuning magnetic anisotropy of [Co/Pt]{sub 6} layer was accomplished by Co reference layer. It is revealed that controlling of non-collinear states in such systems is possible by variation of thickness of spacer and reference layers and [Co/Pt]{sub 6}/t{sub Pt}/t{sub Co} trilayer system can be used in multilayered magnetic systems.

  12. Synthesis of Reusable Silica Nanosphere-Supported Pt(IV Complex for Formation of Disulfide Bonds in Peptides

    Directory of Open Access Journals (Sweden)

    Xiaonan Hou

    2017-02-01

    Full Text Available Some peptide-based drugs, including oxytocin, vasopressin, ziconotide, pramlintide, nesiritide, and octreotide, contain one intramolecular disulfide bond. A novel and reusable monodispersed silica nanosphere-supported Pt(IV complex (SiO2@TPEA@Pt(IV; TPEA: N-[3-(trimethoxysilylpropyl]ethylenediamine was synthesized via a four-step procedure and was used for the formation of intramolecular disulfide bonds in peptides. Transmission electron microscopy (TEM and chemical mapping results for the Pt(II intermediates and for SiO2@TPEA@Pt(IV show that the silica nanospheres possess a monodisperse spherical structure and contain uniformly-distributed Si, O, C, N, Cl, and Pt. The valence state of Pt on the silica nanospheres was characterized by X-ray photoelectron spectroscopy (XPS. The Pt(IV loaded on SiO2@TPEA@Pt(IV was 0.15 mmol/g, as determined by UV-VIS spectrometry. The formation of intramolecular disulfides in six dithiol-containing peptides of variable lengths by the use of SiO2@TPEA@Pt(IV was investigated, and the relative oxidation yields were determined by high-performance liquid chromatography (HPLC. In addition, peptide 1 (Ac-CPFC-NH2 was utilized to study the reusability of SiO2@TPEA@Pt(IV. No significant decrease in the relative oxidation yield was observed after ten reaction cycles. Moreover, the structure of SiO2@TPEA@Pt(IV after being used for ten cycles was determined to be similar to its initial one, demonstrating the cycling stability of the complex.

  13. A new approach for extension of the identification period of irradiated cellulose-containing foodstuffs by EPR spectroscopy

    International Nuclear Information System (INIS)

    Yordanov, Nicola D.; Gancheva, Veselka

    2000-01-01

    We report on the possibility of identification by EPR spectroscopy of some irradiated cellulose-containing foodstuffs, at a relatively long time after the irradiation, when the characteristic EPR spectral lines of the cellulose free radical have essentially disappeared. In such cases rather expensive and time-consuming methods (e.g. thermoluminescence analysis) have to be applied. The present communication demonstrates with some pre-irradiated spices, dried medicinal and sweet herbs that simply heating the samples to 60 deg. C for one hour leads to a significant (50% or more) decrease of the EPR intensity of the remaining central line of the samples. For comparison, the loss in the intensity of the same line upon heating non-irradiated samples at 60 deg. C for one hour was only about 10%. This inexpensive new procedure will extend the post-irradiation period in which EPR can be used for distinguishing irradiated from non-irradiated samples, of certain cellulose-containing foodstuffs

  14. Extruded expanded polystyrene sheets coated by TiO{sub 2} as new photocatalytic materials for foodstuffs packaging

    Energy Technology Data Exchange (ETDEWEB)

    Loddo, V.; Marci, G. [Schiavello-Grillone Photocatalysis Group - Dipartimento di Ingegneria Elettrica, Elettronica e delle Telecomunicazioni, di tecnologie Chimiche, Automatica e modelli Matematici - Universita degli Studi di Palermo, Viale delle Scienze (Ed. 6) - 90128 Palermo (Italy); Palmisano, G., E-mail: giovanni_palmisano@yahoo.it [Schiavello-Grillone Photocatalysis Group - Dipartimento di Ingegneria Elettrica, Elettronica e delle Telecomunicazioni, di tecnologie Chimiche, Automatica e modelli Matematici - Universita degli Studi di Palermo, Viale delle Scienze (Ed. 6) - 90128 Palermo (Italy); Yurdakal, S. [Kimya Boeluemue, Fen-Edebiyat Fakueltesi, Afyon Kocatepe Ueniversitesi - Ahmet Necdet Sezer Kampuesue - 03200 Afyon (Turkey); Brazzoli, M.; Garavaglia, L. [Sirap-Gema S.p.A. - Via Industriale, 1/3 - 25028 Verolanuova (Brescia) (Italy); Palmisano, L., E-mail: leonardo.palmisano@unipa.it [Schiavello-Grillone Photocatalysis Group - Dipartimento di Ingegneria Elettrica, Elettronica e delle Telecomunicazioni, di tecnologie Chimiche, Automatica e modelli Matematici - Universita degli Studi di Palermo, Viale delle Scienze (Ed. 6) - 90128 Palermo (Italy)

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer An extruded polystyrene has been functionalised by TiO{sub 2}. Black-Right-Pointing-Pointer A photocatalytic polymer has been developed via a sol-gel method. Black-Right-Pointing-Pointer Thermoformed packagings for foodstuffs application have been prepared. - Abstract: Nanostructured, photoactive anatase TiO{sub 2} sol prepared under very mild conditions using titanium tetraisopropoxide as the precursor is used to functionalise extruded expanded polystyrene (XPS) sheets by spray-coating resulting in stable and active materials functionalised by TiO{sub 2} nanoparticles. Photocatalytic tests of these sheets performed in a batch reactor in gas-solid system under UV irradiation show their successful activity in degrading probe molecules (2-propanol, trimethylamine and ethene). Raman spectra ensure the deposition of TiO{sub 2} as crystalline anatase phase on the polymer surface. The presence of TiO{sub 2} with respect to polymer surface can be observed in SEM images coupled to EDAX mapping allowing to monitor the surface morphology and the distribution of TiO{sub 2} particles. Finally thermoforming of these sheets in industrial standard equipment leads to useful containers for foodstuffs.

  15. Determination of adulteration of malachite green in green pea and some prepared foodstuffs by micellar liquid chromatography.

    Science.gov (United States)

    Ashok, Vipin; Agrawal, Nitasha; Durgbanshi, Abhilasha; Esteve-Romero, Josep; Bose, Devasish

    2014-01-01

    A simple, fast, and robust micellar LC method was developed for the separation and identification of the nonpermitted color malachite green in green pea and some ready-to-eat foodstuffs. Malachite green (4-[(4-dimethylaminophenyl) phenyl-methyl]-N,N-dimethylaniline) is a hazardous dye that is used to treat fungal and protozoan infections in fish and is a common adulterant (coloring agent) in green pea and other green vegetables because of its green color. In the present work, malachite green was determined in various foodstuffs using a direct injection technique on an RP C18 column with isocratic elution. The optimum mobile phase consisted of 0.15 M sodium dodecyl sulfate (SDS), 6% pentanol buffered at pH 5. Detection was carried out at 620 nm. Malachite green was eluted in 9.2 min without any interference caused by endogenous compounds. Linearities (r > 0.9999), intraday and interday precision (RSD less than 1.00%) in micellar media, and robustness were studied for method validation. LOD and LOQ were 0.10 and 0.25 ppm, respectively. The simplicity of the developed method makes it useful for routine analysis in the area of food QC.

  16. Cassava (Manihot esculenta Crantz) and Yam (Dioscorea spp.) Crops and Their Derived Foodstuffs: Safety, Security and Nutritional Value.

    Science.gov (United States)

    Ferraro, Vincenza; Piccirillo, Clara; Tomlins, Keith; Pintado, Manuela E

    2016-12-09

    Cassava (Manihot esculenta Crantz) and yam (Dioscorea spp.) are tropical crops consumed by ca. 2 billion people and represent the main source of carbohydrate and energy for the approximately 700 million people living in the tropical and sub-tropical areas. They are a guarantee of food security for developing countries. The production of these crops and the transformation into food-derived commodities is increasing, it represents a profitable business and farmers generate substantial income from their market. However, there are some important concerns related to the food safety and food security. The high post-harvest losses, mainly for yam, the contamination by endogenous toxic compounds, mainly for cassava, and the contamination by external agents (such as micotoxins, pesticides, and heavy metal) represent a depletion of economic value and income. The loss in the raw crops or the impossibility to market the derived foodstuffs, due to incompliance with food regulations, can seriously limit all yam tubers and the cassava roots processors, from farmers to household, from small-medium to large enterprises. One of the greatest challenges to overcome those concerns is the transformation of traditional or indigenous processing methods into modern industrial operations, from the crop storage to the adequate package of each derived foodstuff.

  17. Determination of 226Ra and 228Ra concentrations in foodstuffs consumed by inhabitants of Tehran city of Iran

    International Nuclear Information System (INIS)

    Asefi, M.; Fathivand, A. A.; Amidi, A.; Najafi, A.

    2005-01-01

    The presence of primordial radionuclide in human habitats has always been a source of prolonged exposure. Measurement of naturally occurring radionuclides in the environment can be used as baseline to evaluate the impact of non-nuclear activities and also routine releases from nuclear installations. Materials and Methods: A total of 56 samples from 18 different foodstuff including root vegetables (beetroot, carrot, onion, potato, radish and turnip), leafy vegetables (lettuce, parsley, spinach and white cabbage) and lentil, kidney bean, Soya, eggs, rice, meat, tomato and cooking oil were purchased and analyzed by low level gamma spectrometry. Results: The 226 Ra concentrations from root vegetables varied from 13-62 mBqkg -1 with turnip of highest concentration, i.e. 62mBqkg -1 . Among leafy vegetables; parsley showed the maximum concentration of 228 Ra equal to 173 mBqkg -1 . 226 Rand 228 Ra contents in the soya, 394 and 578 mBq kg -1 was much higher than those of other samples respectively. Conclusion : Results indicate that foodstuff consumed by Tehran inhabitants have low radium content and are safe, as far as radium concentrations is concerned

  18. Quantitative determination of benzo[a]pyrene in foodstuffs using benzo[a]pyrene[G-3H

    International Nuclear Information System (INIS)

    Masuda, Yoshito; Shimamura, Kyoko; Yano, Hiroshige

    1977-01-01

    A method for quantitative determination of nano gram level of benzo(a)pyrene (BP) in foodstuffs using tritiated BP( 3 H-BP) was described. Extracts from foodstuffs, having been added a certain amount of 3 H-BP, were fractionated by column chromatography on Florisil, and thinlayer chromatography on acetylated cellulose. Concentration and radio activity of BP in the final fraction were determined by fluorescence spectrometry and liquid scintillation. Recovery ratio of each experiment was obtained by comparing the radio activities of added 3 H-BP and separated BP. Concentration of BP in the sample analyzed was calculated from the amount of isolated BP and the recovery ratio in each experiment. A quantitative limit of BP by this method was 0.2 ppb when 50 g of sample was used. By this method, contents of BO in each sample of Tenpura oil, salad oil, flour, and polished rice were determined as 0.6, 0.2, 0.1 and < 0.1 ppb on average, respectively. (auth.)

  19. Rapid and simple micromethod for the simultaneous determination of 3-MCPD and 3-MCPD esters in different foodstuffs.

    Science.gov (United States)

    Küsters, Markus; Bimber, Ute; Ossenbrüggen, Alexandra; Reeser, Sebastian; Gallitzendörfer, Rainer; Gerhartz, Michael

    2010-06-09

    This paper describes for the first time a micromethod for the simultaneous determination of 3-monochloropropane-1,2-diol (3-MCPD) and fatty acid esters of 3-MCPD (3-MCPD esters) in different foodstuffs. 3-MCPD and 3-MCPD esters were isolated from food products using a single extraction step separating hydrophilic and lipophilic compounds. An aliquot of the aqueous layer was analyzed for the content of 3-MCPD while a part of the organic layer was analyzed for 3-MCPD esters after cleavage with sodium methoxide. After a simple derivatization procedure with phenylboronic acid (PBA), the determination was achieved by isotope dilution GC-MS using isotope-labeled 3-MCPD and 3-MCPD ester as internal standards. The method was validated for various foodstuffs like bakery products, meat and fish products, and soups as well as seasonings with LOD of 1-2 microg/kg (3-MCPD) and 6 microg/kg (3-MCPD esters), respectively. Recoveries ranged within 95 +/- 9% and 96 +/- 10% at spiking levels of 15 and 25 microg/kg in all matrices for 3-MCPD and 84 +/- 9% and 85 +/- 7% at spiking levels of 0.05 mg/kg and 2 mg/kg for 3-MCPD esters. The method avoids tedious and laborious sample preparation and was successfully applied to the rapid screening of samples conforming to the EU performance criteria for methods of analysis for 3-MCPD.

  20. The 3"r"d inter laboratory comparison in the determination of elements in foodstuff with neutron activation analysis method

    International Nuclear Information System (INIS)

    Muji Wiyono; Dadong Iskandar; Wahyudi

    2010-01-01

    The 3"r"d inter laboratory comparison in the determination of elements in the foodstuff with NAA method held by PTBIN-BATAN Laboratory has been carried out. Six laboratories in BATAN were participated in the program with each code were: Lab. 01, Lab. 02, Lab. 03, Lab. 04, Lab. 05 and Lab. 06. Lab KKL PTKMR-BATAN was a participant with Lab. 06 code number. The received samples of foodstuff were prepared and irradiated in the RS-03 rabbit system of GA. Siwabessy multi purpose reactor. The irradiated samples were counted by using gamma spectrometer with HPGe detector to determine the content of elements. Result of the analysis was reported to the coordinator to be evaluated whether the sample was passed or rejected. Result of the coordinator laboratory evaluated that, 9 elements identified by Lab. KKL PTKMR-BATAN had four elements such as; Al, K, Cu and Se were passed (accepted) and other elements such as; Mn, Na, Ca, Fe and Zn were rejected. The elements number that passed in the 3"r"d inter laboratory comparison was less than those of earlier inter laboratory comparison, this was due to elemental content in the analyzed samples was very low. (author)

  1. Nuclear structure of 194Pt

    International Nuclear Information System (INIS)

    Cleveland, W.E.; Zganjar, E.F.

    1976-01-01

    The decay of 194 Ir has been thoroughly studied resulting in the construction of a decay scheme consisting of 26 excited states and 69 transitions. Nine new levels and 29 new transitions were added to the previously known scheme. Of these, levels at 1,893.6 and 2,053.0 keV as well as 9 γ-ray transitions are new to the 194 Pt level scheme. Precise γ-ray energy and intensity measurements as well as quantitative coincidence measurements were performed, and the internal conversion spectrum was investigated with a Si(Li) detector. Directional correlation measurements were performed for selected cascades with the major result being the unique assignment of 0 + to the new level at 1,893.6 keV. The structure was interpreted within the framework of the PPQ model as well as the effective-core picture including nuclear triaxiality. (orig.) [de

  2. Nonlinear PT-symmetric plaquettes

    International Nuclear Information System (INIS)

    Li Kai; Kevrekidis, P G; Malomed, Boris A; Günther, Uwe

    2012-01-01

    We introduce four basic two-dimensional (2D) plaquette configurations with onsite cubic nonlinearities, which may be used as building blocks for 2D PT-symmetric lattices. For each configuration, we develop a dynamical model and examine its PTsymmetry. The corresponding nonlinear modes are analyzed starting from the Hamiltonian limit, with zero value of the gain–loss coefficient, γ. Once the relevant waveforms have been identified (chiefly, in an analytical form), their stability is examined by means of linearization in the vicinity of stationary points. This reveals diverse and, occasionally, fairly complex bifurcations. The evolution of unstable modes is explored by means of direct simulations. In particular, stable localized modes are found in these systems, although the majority of identified solutions are unstable. This article is part of a special issue of Journal of Physics A: Mathematical and Theoretical devoted to ‘Quantum physics with non-Hermitian operators’. (paper)

  3. Adsorption studies on Pt(111)

    International Nuclear Information System (INIS)

    Hopster, H.

    1977-06-01

    The adsorption of O 2 , CO, and C 2 H 2 as well as the CO oxidation on Pt(111) were studied by high-resolution electron spectroscopy. Using a platinum monocrystal sample with a contonuous stage density, the adhesion coefficient for O 2 and the reaction probability for CO were determined as a function of stage density and oxygen cover by measuring the oxygen cover and its time behaviour. The study of vibrations of adsorbed CO showed that CO is bound in linear form on two different adsorption sites. The adsorption of acetylene was studied at 140 K and 300 K. The frequencies of the C-H stretching and flexural vibrations as well as the C-C-H bonding angle were determined. (orig./GSC) [de

  4. Synthesis and Characterization of Pt-Ag Alloy Nanocages with Enhanced Activity and Durability toward Oxygen Reduction.

    Science.gov (United States)

    Yang, Xuan; Roling, Luke T; Vara, Madeline; Elnabawy, Ahmed O; Zhao, Ming; Hood, Zachary D; Bao, Shixiong; Mavrikakis, Manos; Xia, Younan

    2016-10-12

    Engineering the elemental composition of metal nanocrystals offers an effective strategy for the development of catalysts or electrocatalysts with greatly enhanced activity. Herein, we report the synthesis of Pt-Ag alloy nanocages with an outer edge length of 18 nm and a wall thickness of about 3 nm. Such nanocages with a composition of Pt 19 Ag 81 could be readily prepared in one step through the galvanic replacement reaction between Ag nanocubes and a Pt(II) precursor. After 10 000 cycles of potential cycling in the range of 0.60-1.0 V as in an accelerated durability test, the composition of the nanocages changed to Pt 56 Ag 44 , together with a specific activity of 1.23 mA cm -2 toward oxygen reduction, which was 3.3 times that of a state-of-the-art commercial Pt/C catalyst (0.37 mA cm -2 ) prior to durability testing. Density functional theory calculations attributed the increased activity to the stabilization of the transition state for breaking the O-O bond in molecular oxygen. Even after 30 000 cycles of potential cycling, the mass activity of the nanocages only dropped from 0.64 to 0.33 A mg -1 Pt , which was still about two times that of the pristine Pt/C catalyst (0.19 A mg -1 Pt ).

  5. Surface coverage of Pt atoms on PtCo nanoparticles and catalytic kinetics for oxygen reduction

    Energy Technology Data Exchange (ETDEWEB)

    Jiang Rongzhong, E-mail: rongzhong.jiang@us.army.mi [Sensors and Electron Devices Directorate, U.S. Army Research Laboratory, 2800 Powder Mill Road, Adelphi, MD 20783-1197 (United States); Rong, Charles; Chu, Deryn [Sensors and Electron Devices Directorate, U.S. Army Research Laboratory, 2800 Powder Mill Road, Adelphi, MD 20783-1197 (United States)

    2011-02-01

    The surface coverage of Pt atoms on PtCo nanoparticles and its effect on catalytic kinetics for oxygen reduction were investigated. The PtCo nanoparticles with different surface coverage of Pt atoms were synthesized with various methods, including normal chemical method, microemulsion synthesis, and ultrasound-assisted microemulsion. A model of Pt atoms filling into a spherical nanoparticle was proposed to explain the relationship of surface metal atoms and nanoparticle size. The catalytic activity of the PtCo nano-particles is highly dependent on the synthetic methods, even if they have the same chemical composition. The PtCo nano-particles synthesized with ultrasound-assisted microemulsion showed the highest activity, which is attributed to an increase of active surface coverage of Pt atoms on the metal nanoparticles. The rate of oxygen reduction at 0.5 V (vs. SCE) catalyzed by the PtCo synthesized with ultrasound-assisted micro-emulsion was about four times higher than that of the PtCo synthesized with normal chemical method. As demonstrated with rotating-ring disk electrode measurement, the PtCo nano-particles can catalyze oxygen 4-electron reduction to water without intermediate H{sub 2}O{sub 2} detected.

  6. 30 CFR Appendix II to Subpart D of... - Appendix II to Subpart D of Part 18

    Science.gov (United States)

    2010-07-01

    ... LABOR TESTING, EVALUATION, AND APPROVAL OF MINING PRODUCTS ELECTRIC MOTOR-DRIVEN MINE EQUIPMENT AND ACCESSORIES Machines Assembled With Certified or Explosion-Proof Components, Field Modifications of Approved Machines, and Permits To Use Experimental Equipment Pt. 18, Subpt. D, App. II Appendix II to Subpart D of...

  7. Ethanol electrooxidation on Pt-Sn and Pt-Sn-W bulk alloys

    Energy Technology Data Exchange (ETDEWEB)

    Anjos, D.M. dos; Hahn, F.; Leger, J.M.; Kokoh, K.B. [Universite de Poitiers, Poitiers Cedex (France). Centre National de la Recherche Scientifique (CNRS). Equipe Electrocatalyse; Tremiliosi-Filho, G. [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Inst. de Quimica

    2008-07-01

    Ethanol oxidation has been studied on Pt-Sn and Pt-Sn-W electrodes prepared in an arc-melting furnace. Different electrochemical techniques like cyclic voltammetry and chronoamperometry were used to evaluate the catalytic activity of these materials. The electro-oxidation process was also investigated by in situ infrared reflectance spectroscopy in order to determine adsorbed intermediates and reaction products. Experimental results indicated that Pt-Sn and Pt-Sn-W alloys are able to oxidize ethanol mainly to acetaldehyde and acetic acid. Adsorbed CO was also detected, demonstrating the viability of splitting the C-C bond in the ethanol molecule during the oxidation process. The adsorbed CO was further oxidized to CO{sub 2}.This reaction product was clearly detected by SNIFTIRS. Pt-Sn-W catalyst showed a better electrochemical performance than Pt-Sn that, in it turn, is better than Pt-alone. (author)

  8. Thermodynamic modeling of the Pt-Zr system

    International Nuclear Information System (INIS)

    Gao Yongliang; Guo Cuiping; Li Changrong; Du Zhenmin

    2010-01-01

    By means of the CALPHAD (CALculation of PHAse Diagram) technique, the Pt-Zr system was critically assessed. The solution phases (liquid, bcc, fcc and hcp) are described with the substitutional model. The intermetallic compounds Pt 4 Zr, Pt 4 Zr 3 , αPtZr and Pt 3 Zr 5 are treated as the formula (Pt,Zr) m (Pt,Zr) n by a two-sublattice model with the elements Pt and Zr on the first and the second sublattices, respectively. A two-sublattice model (Pt,Zr) 0.5 (Pt,Zr) 0.5 is applied to describe the compound βPtZr with CsCl-type structure (B2) in order to cope with the order-disorder transition between bcc solution (A2) and βPtZr (B2). Another two-sublattice model (Pt,Zr) 0.75 (Pt,Zr) 0.25 with Ni 3 Ti-type structure (D0 24 ) is applied to describe the compound Pt 3 Zr in order to cope with the order-disorder transition between hexagonal close-packed (A3) and Pt 3 Zr (D0 24 ). The compound Pt 10 Zr 7 is treated as a stoichiometric compound. A set of self-consistent thermodynamic parameters of the Pt-Zr system was obtained. (orig.)

  9. Neutral Guest Capture via Lewis Acid/Base Molecular Square Receptors. X-ray Crystal Structure of {Cyclobis[(cis-(dppp)Pt(4-ethynylpyridyl)(2))(cis- (PEt(3))(2)Pt)]Ag(2)}(+6)(phenazine)- ((-)OSO(2)CF(3))(6).

    Science.gov (United States)

    Whiteford, Jeffery A.; Stang, Peter J.; Huang, Songping D.

    1998-10-19

    Interaction of {cyclobis[(cis-(dppp)Pt(4-ethynylpyridyl)(2))(cis-(L)M)]Ag(2)}(+6)((-)OSO(2)CF(3))(6), where M = Pt(II) or Pd(II) and L = dppp or 2PEt(3), with pyridine, pyrazine, phenazine, or 4,4'-dipyridyl ketone results in coordination Lewis acid/base host-guest assemblies via the "pi-tweezer effect" and mono or bis neutral guest coordination. All host-guest complexes are air stable microcrystalline solids with decomposition points greater than 170 degrees C. The homometallic Pt(II) receptors are more stable than the heteroaromatic Pt(II)-Pd(II) receptors toward heteratom-containing aromatic guests. The X-ray crystal structure of the host-guest complex {cyclobis[(cis-(dppp)Pt(4-ethynylpyridyl)(2))(cis-(PEt(3))(2)Pt)]Ag(2)}(+6)(phenazine)((-)OSO(2)CF(3))(6) is reported. The crystals with the empirical formula C(62)H(68)AgF(9)N(3)O(9)P(4)Pt(2)S(3) are triclinic P&onemacr; with a = 12.3919(8) Å, b = 17.160(1) Å, c = 18.932(1) Å, alpha = 90.892(1) degrees, beta = 97.127(1) degrees, gamma = 89.969(1) degrees, and Z = 2.

  10. In vitro studies on interactions of iron salts and complexes with food-stuffs and medicaments.

    Science.gov (United States)

    Geisser, P

    1990-07-01

    It has been shown in the present study that food components such as phytic acid, oxalic acid, tannin, sodium alginate, choline and choline salts, vitamins A, D3 and E, soy oil and soy flour, do not undergo any interactions with iron(III)-hydroxide polymaltose complex (Ferrum Hausmann). Phytic acid, oxalic acid, tannin and sodium alginate, however, react with iron(II) or iron(III)-salts at pH values of 3.0, 5.5 and 8.0, giving rise to iron complexes. Trimethylamine-N-oxide, which is present in fish meal, reacts with iron(II)-sulphate to produce iron(III) reaction products; it does not react with iron(III)-hydroxide polymaltose complex. Special soybean flours show no irreversible adsorption or precipitation with iron(III)-hydroxyide polymaltose complex over the pH range 3.0-8.0, in contrast to iron(II)-sulphate. Antacids containing aluminium hydroxide, talc, ion exchange resins or other unabsorbable, insoluble components absorb iron(III)-hydroxide polymaltose complex in the pH range 3.0-8.0 in a reversible manner, while the strong adsorption or precipitation observed with iron(II)-sulphate at pH 8.0 is irreversible. No interaction was observed between the steroid hormones studied and iron(II)-sulphate or iron(III)-hydroxide polymaltose complex. On the basis of the measured compatibilities, iron(III)-hydroxide polymaltose complex can be administered orally simultaneously with many other drugs, without prejudicing the absorption of iron or of the other drug as is often seen with iron(II) and iron(III) salts.

  11. Shape transition in Os and Pt isotopes

    International Nuclear Information System (INIS)

    Ansari, A.

    1985-07-01

    Ground state structure of A=186 to 196 Os-Pt transitional region is investigated through a self-consistent Hartree-Fock-Bogolyubov calculation employing a pairing-plus-quadrupole-plus-hexadecapole model interaction Hamiltonian. Influence of the hexadecapole degrees of freedom on the triaxiality is especially examined. A gradual prolate to oblate shape transition is found in Pt isotopes but such a change is almost abrupt in Os at A approx. = 194. This difference in behaviour of the Os and Pt isotopes is obtained only if all the hexadecapole degrees of freedom, instead of merely an axial Y 40 component, are treated fully self-consistently. (author)

  12. Reduction of cross-reactive carbohydrate determinants in plant foodstuff: elucidation of clinical relevance and implications for allergy diagnosis.

    Directory of Open Access Journals (Sweden)

    Heidi Kaulfürst-Soboll

    Full Text Available BACKGROUND: A longstanding debate in allergy is whether or not specific immunoglobulin-E antibodies (sIgE, recognizing cross-reactive carbohydrate determinants (CCD, are able to elicit clinical symptoms. In pollen and food allergy, ≥20% of patients display in-vitro CCD reactivity based on presence of α1,3-fucose and/or β1,2-xylose residues on N-glycans of plant (xylose/fucose and insect (fucose glycoproteins. Because the allergenicity of tomato glycoallergen Lyc e 2 was ascribed to N-glycan chains alone, this study aimed at evaluating clinical relevance of CCD-reduced foodstuff in patients with carbohydrate-specific IgE (CCD-sIgE. METHODOLOGY/PRINCIPAL FINDINGS: Tomato and/or potato plants with stable reduction of Lyc e 2 (tomato or CCD formation in general were obtained via RNA interference, and gene-silencing was confirmed by immunoblot analyses. Two different CCD-positive patient groups were compared: one with tomato and/or potato food allergy and another with hymenoptera-venom allergy (the latter to distinguish between CCD- and peptide-specific reactions in the food-allergic group. Non-allergic and CCD-negative food-allergic patients served as controls for immunoblot, basophil activation, and ImmunoCAP analyses. Basophil activation tests (BAT revealed that Lyc e 2 is no key player among other tomato (glycoallergens. CCD-positive patients showed decreased (reactivity with CCD-reduced foodstuff, most obvious in the hymenoptera venom-allergic but less in the food-allergic group, suggesting that in-vivo reactivity is primarily based on peptide- and not CCD-sIgE. Peptide epitopes remained unaffected in CCD-reduced plants, because CCD-negative patient sera showed reactivity similar to wild-type. In-house-made ImmunoCAPs, applied to investigate feasibility in routine diagnosis, confirmed BAT results at the sIgE level. CONCLUSIONS/SIGNIFICANCE: CCD-positive hymenoptera venom-allergic patients (control group showed basophil activation despite no

  13. Comparison of PCDD/F and dl-PCB levels in Turkish foodstuffs: industrial versus rural, local versus supermarket products, and assessment of dietary intake

    NARCIS (Netherlands)

    Kilic, D.; Cakirogullari, G.C.; Ucar, Y.; Theelen, R.; Traag, W.A.

    2011-01-01

    Polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) and dioxin-like and non-dioxin-like (indicator) polychlorinated biphenyls (PCBs) were monitored in various foodstuffs of animal origin and edible oil samples obtained from two different cities in Turkey both rural and industrial. Total

  14. Pengukuran Kepuasan Kerja Karyawan APLP & A PT Semen Padang (PT X

    Directory of Open Access Journals (Sweden)

    Shelly Nolandari

    2016-04-01

    Full Text Available Thoughts on employee satisfaction arise because the company believes its employees have a high level of satisfaction will result in a better level of productivity, work more accurate, the fewer the number of absences and higher loyalty than employees with low satisfaction levels.Company's with good productivity will grow and increase revenue. PT Semen Padang has several subsidiaries and affiliates like PT X. PT X will measure employee satisfaction with the company's expectations are always making changes that sustainable about employee satisfaction because companies believe that employee satisfaction level of its high yield levels better productivity, work more accurate, the number of absences are fewer and loyalty higher than employees with low satisfaction levels. Companies with good productivity will experience growth as indicated by the increase in revenue, in line with the increase in the welfare of the employees. PT Semen Padang has several subsidiaries and affiliates PT X. PT Xwill measure employee satisfaction with the Company's expectations.

  15. Mesoporous Pt and Pt/Ru alloy electrocatalysts for methanol oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Franceschini, Esteban A. [Grupo de Celdas de Combustible, Departamento de Fisica de la Materia Condensada, Centro Atomico Constituyentes, CNEA. Av. General Paz 1499 (1650), San Martin, Buenos Aires (Argentina); Planes, Gabriel A. [Departamento de Quimica, Facultad de Ciencias Exactas, Fisicoquimicas y Naturales, Universidad Nacional de Rio Cuarto, Agencia Postal No 3, 5800, Rio Cuarto (Argentina); Williams, Federico J. [Departamento de Quimica Inorganica, Analitica y Quimica-Fisica, INQUIMAE CONICET, Facultad Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, Buenos Aires (Argentina); Soler-Illia, Galo J.A.A. [Gerencia de Quimica, Centro Atomico Constituyentes, CNEA. Av. General Paz 1499 (1650), San Martin, Buenos Aires (Argentina); Corti, Horacio R. [Grupo de Celdas de Combustible, Departamento de Fisica de la Materia Condensada, Centro Atomico Constituyentes, CNEA. Av. General Paz 1499 (1650), San Martin, Buenos Aires (Argentina); Departamento de Quimica Inorganica, Analitica y Quimica-Fisica, INQUIMAE CONICET, Facultad Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, Buenos Aires (Argentina)

    2011-02-15

    Mesoporous Pt and Pt/Ru catalysts with 2D-hexagonal mesostructure were synthesized using a triblock poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) copolymer (Pluronic F127 {sup registered}) template, on a gold support. Large electrochemical surface areas were observed for the catalysts prepared at high overpotentials. Compared to the Pt catalyst, the Pt/Ru alloy containing 3 at% of Ru exhibited lower onset potential and more than three times the limit mass activity for methanol oxidation. This behavior is assigned to the larger pore size of the mesoporous Pt and Pt/Ru catalysts obtained with this template that seems to improve the methanol accessibility to the active sites compared to those obtained using lyotropic liquid crystals. (author)

  16. DNA-templated synthesis of Pt nanoparticles on single-walled carbon nanotubes.

    Science.gov (United States)

    Dong, Lifeng

    2009-11-18

    A series of electron microscopy characterizations demonstrate that single-stranded deoxyribonucleic acid (ssDNA) can bind to nanotube surfaces and disperse bundled single-walled carbon nanotubes (SWCNTs) into individual tubes. The ssDNA molecules on the nanotube surfaces demonstrate various morphologies, such as aggregated clusters and spiral wrapping around a nanotube with different pitches and spaces, indicating that the morphology of the SWCNT/DNA hybrids is not related solely to the base sequence of the ssDNA or the chirality or the diameter of the nanotubes. In addition to serving as a non-covalent dispersion agent, the ssDNA molecules bonded to the nanotube surface can provide addresses for localizing Pt(II) complexes along the nanotubes. The Pt nanoparticles obtained by a reduction of the Pt2+-DNA adducts are crystals with a size of direct ethanol/methanol fuel cells and nanoscale electronics.

  17. Endogenous levels of nitrites and nitrates in wide consumption foodstuffs: Results of five years of official controls and monitoring.

    Science.gov (United States)

    Iammarino, Marco; Di Taranto, Aurelia; Cristino, Marianna

    2013-10-15

    The massive introduction of nitrogen fertilisers, necessary to maximise the global food production, has brought about an increase of the residual amounts of nitrites and nitrates in the products. Notoriously, these compounds may exercise toxic effects. In this work the results obtained from 5years of official controls and monitoring focused on tracing quantifiable amounts of nitrites and nitrates in 1785 samples of meat, dairy, fish products and leafy vegetables are reported. A widespread presence of nitrates at low concentrations in foodstuffs was verified. High concentrations of nitrates were registered in some leafy vegetables and mussels samples, while high nitrites concentrations were registered in some spinach samples. The results confirmed the necessity to develop most controls and suggest the introduction of new legal limits related to some combinations contaminant/matrix. Such new limits may fill legislative gaps that may cause wrong interpretations of the results obtained during official controls. Copyright © 2012 Elsevier Ltd. All rights reserved.

  18. Management of foodstuffs after nuclear accidents. Forvaltning av naeringsmidler etter kjernefysiske ulykker; En nordisk modell for nasjonal respons

    Energy Technology Data Exchange (ETDEWEB)

    1991-04-01

    A model for the management of foodstuffs after nuclear accidents is presented. The model is a synthesis of traditions and principles taken from both radioactive protection and management of food. It is based on cooperation between the Nordic countries and on practical experience gained from the Chernobyl accident. The aim of the model is to produce a basis for common plans for critical situations based on criteria for decision making. In the case of radioactive accidents it is important that the protection of the public and of the society is handled in a positive way. The model concerns production, marketing and consumption of food and beverage. The overall aim is that the radiation doses should be as low and harmless to health for individual members of the public. (CLS) 35 refs.

  19. Bite Mark Analysis in Foodstuffs and Inanimate Objects and the Underlying Proofs for Validity and Judicial Acceptance.

    Science.gov (United States)

    Rivera-Mendoza, Fernando; Martín-de-Las-Heras, Stella; Navarro-Cáceres, Pablo; Fonseca, Gabriel M

    2018-03-01

    Even though one of the first bite mark cases was Doyle v. State in 1954 (a bitten cheese case), the research has focused on bite marks inflicted in human skin. As published Papers, Case Reports, or Technical Notes can constitute precedents which are relied upon in making the legal arguments and a considerable amount of case law exists in this area, we present a systematic review on bite mark analysis in foodstuffs and inanimate objects and their underlying proofs for validity and judicial acceptance according to Daubert rulings. Results showed that there is vulnerability in these procedures, and it is essential to demand for focus scrutiny on the known error rates when such evidence is presented in trials. These kinds of bite marks are well documented; however, there has been little research in this field knowing that the protocols of analysis and comparison are the responsibility of the forensic odontologists. © 2017 American Academy of Forensic Sciences.

  20. Viscosity measurements - a comprehensive overview on the method and its applicability for the identification of irradiated foodstuffs

    International Nuclear Information System (INIS)

    Nuernberger, E.; Heide, L.; Boegl, K.W.

    1991-01-01

    The viscosity of a foodstuff depends mainly on the composition and the amount of starch, pectins and cellulose, which may undergo changes after irradiation. The investigation on the applicability of viscosity measurement for the identification of irradiated foods showed so far that this method seems to be applicable only to a definite number of spices and foods. The optimal method has to be determined empirically, because the reason is still unknown, why in some cases, the viscosity values decrease and in other cases increase after irradiation - and why sometimes no changes occur at all. Until now, the following irradiated spices can be identified by this method: cardamom, cinnamon, curcuma, horse-radish, nutmeg, mustard-seed and white pepper. (21 figs, 2 tabs, 10 refs)

  1. Compton suppression instrumental neutron activation analysis performance in determining trace- and minor-element contents in foodstuff

    International Nuclear Information System (INIS)

    Freitas, M.C.; Dionisio, I.; Pacheco, A.M.G.; Bacchi, M.A.; Fernandes, E.A.N.; Landsberger, S.; Braisted, J.

    2008-01-01

    In 2003-2004, several food items were purchased from large commercial outlets in Coimbra, Portugal. Such items included meats (chicken, pork, beef), eggs, rice, beans and vegetables (tomato, carrot, potato, cabbage, broccoli, lettuce). Elemental analysis was carried out through INAA at the Technological and Nuclear Institute (ITN, Portugal), the Nuclear Energy Centre for Agriculture (CENA, Brazil), and the Nuclear Engineering Teaching Lab of the University of Texas at Austin (NETL, USA). At the latter two, INAA was also associated to Compton suppression. It can be concluded that by applying Compton suppression (1) the detection limits for arsenic, copper and potassium improved; (2) the counting-statistics error for molybdenum diminished; and (3) the long-lived zinc had its 1115-keV photopeak better defined. In general, the improvement sought by introducing Compton suppression in foodstuff analysis was not significant. Lettuce, cabbage and chicken (liver, stomach, heart) are the richest diets in terms of human nutrients. (author)

  2. Golden Gate and Pt. Reyes Acoustic Detections

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains detections of acoustic tagged fish from two general locations: Golden Gate (east and west line) and Pt. Reyes. Several Vemco 69khz acoustic...

  3. Electrochemical stability of subnanometer Pt clusters

    DEFF Research Database (Denmark)

    Quinson, Jonathan; Röefzaad, Melanie; Deiana, Davide

    2018-01-01

    In the present work, the degradation of size-selected Pt nanoclusters is studied under electrochemical conditions. This model catalyst mimics carbon supported Pt nanoclusters and nanoparticles typically employed in proton exchange membrane fuel cells (PEMFCs). Insight into the early stage...... of degradation is given by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and confirmed by transmission electron microscopy (TEM). In contrast to common assumptions, it is demonstrated that even extremely small Pt clusters exhibit a remarkable stability under electrochemical...... - is observed. In light of the findings reported, developing highly-dispersed subnanometer Pt clusters as catalyst for PEMFCs is a realistic approach provided the operation conditions are suitably adjusted. Furthermore, mitigation strategies to improve the stability of few-atoms catalyst under electrochemical...

  4. 195Pt and 119Sn Knight shifts of U3Pt3Sn4

    International Nuclear Information System (INIS)

    Kojima, K.; Takabatake, T.; Harada, A.; Hihara, T.

    1995-01-01

    The 195 Pt and 119 Sn Knight shifts in U 3 Pt 3 Sn 4 have been measured in the temperature range 4.2-298K. They exhibit Curie-Weiss like behaviors above about 50K and remain constant below about 10K. This suggests that the deviation of χ(T) from the modified Curie-Weiss law is an intrinsic property of U 3 Pt 3 Sn 4 . ((orig.))

  5. Foodstuff analyses show that seafood and water are major perfluoroalkyl acids (PFAAs) sources to humans in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Heo, Jin-Ju; Lee, Ji-Woo [Department of Civil and Environmental Engineering, Pusan National University, Busan, 609-735 (Korea, Republic of); Kim, Seung-Kyu [Department of Marine Science, College of Natural Sciences, Incheon National University, Incheon, 406-772 (Korea, Republic of); Oh, Jeong-Eun, E-mail: jeoh@pusan.ac.kr [Department of Civil and Environmental Engineering, Pusan National University, Busan, 609-735 (Korea, Republic of)

    2014-08-30

    Graphical abstract: - Highlights: • 16 PFAAs in 397 samples of 66 food types and 34 tap water samples were analyzed. • Dietary exposure to PFAAs was estimated by using the PFAAs measured concentrations. • The major contributors of PFAAs dietary exposure were confirmed. - Abstract: We measured concentrations of PFAAs in 397 foods, of 66 types, in Korea, and determined the daily human dietary PFAAs intake and the contribution of each foodstuff to that intake. The PFAAs concentration in the 66 different food types ranged from below the detection limit to 48.3 ng/g. Perfluorooctane sulfonate (PFOS) and long-chain perfluorocarboxylic acids (PFCAs) were the dominant PFAAs in fish, shellfish, and processed foods, while perfluorooctanoic acid (PFOA) and short-chain PFCAs dominated dairy foodstuffs and beverages. The Korean adult dietary intake ranges, estimated for a range of scenarios, were 0.60–3.03 and 0.17–1.68 ng kg{sup −1} bw d{sup −1} for PFOS and PFOA, respectively, which were lower than the total daily intake limits suggested by European Food Safety Authority (PFOS: 150 ng kg{sup −1} bw d{sup −1}; PFOA: 1500 ng kg{sup −1} bw d{sup −1}). The major contributors to PFAAs dietary exposure varied with subject age and PFAAs. For example, fish was a major contributor of PFOS but dairy foods were major contributors of PFOA. However, tap water was a major contributor to PFOA intake when it was the main source of drinking water (rather than bottled water)

  6. Solving the Problems of Physical and Economic Accessibility of Foodstuff in the Region by Means of AIC State Regulation

    Directory of Open Access Journals (Sweden)

    Babich Tatyana Vladimirovna

    2015-09-01

    Full Text Available The article deals with the physical and economic accessibility to foodstuff in the region. The effects of economic sanctions are analyzed, the main types of risks of the domestic agricultural producers’ competitiveness are described, and the methods of their reduction are identified. The concept of food security in terms of physical and economic accessibility is considered. The analysis of the Volgograd region data on the development of agricultural production let conclude that there is the problem of ensuring the physical availability of foodstuff in the region. The state regulation of agricultural production is identified as an important factor of food security in the modern world. The authors identified the basic problems of agricultural production, including the problem of irrigation, economic accessibility of food products, depreciation of fixed assets, the use of obsolete and resource-intensive technologies of production, decline in qualification level of staff employed in the industry, underfunding of agricultural science, low competitiveness of agricultural and food policy. Moreover, in the current situation the further growth of food prices and reduced purchasing power of the population, as a result of inflation, would further reduce the economic affordability of food and decrease food security in the region and in the country, as a whole. As a result, аs part of the solution to the problem of providing physical and economic access to food, the authors offered and proved complex measures on improving state regulation of agro-industrial complex. These measures include conducting large-scale works on restoration of the complex reclamation of the region; implementation of technical and technological modernization of agriculture, food industry and agrobusiness production services; formation of the system of professional agricultural education; formation of modern social infrastructure in rural areas; development of the program of food

  7. A comprehensive assessment of arsenic in commonly consumed foodstuffs to evaluate the potential health risk in Bangladesh

    Energy Technology Data Exchange (ETDEWEB)

    Ahmed, Md. Kawser [Faculty of Earth & Environmental Sciences, University of Dhaka, Dhaka 1000 (Bangladesh); Shaheen, Nazma [Institute of Nutrition and Food Science (INFS), University of Dhaka, Dhaka 1000 (Bangladesh); Islam, Md. Saiful [Department of Risk Management and Environmental Sciences, Graduate School of Environment and Information Sciences, Yokohama National University, Yokohama, Kanagawa 240-8501 (Japan); Habibullah-Al-Mamun, Md., E-mail: habibullah-al-sj@ynu.jp [Department of Risk Management and Environmental Sciences, Graduate School of Environment and Information Sciences, Yokohama National University, Yokohama, Kanagawa 240-8501 (Japan); Department of Fisheries, University of Dhaka, Dhaka 1000 (Bangladesh); Islam, Saiful [Institute of Nutrition and Food Science (INFS), University of Dhaka, Dhaka 1000 (Bangladesh); Islam, Md. Monirul [Department of Fisheries, University of Dhaka, Dhaka 1000 (Bangladesh); School of Earth and Environment, Leeds University, Leeds LS2, 9JT (United Kingdom); Kundu, Goutam Kumar [Department of Fisheries, University of Dhaka, Dhaka 1000 (Bangladesh); Bhattacharjee, Lalita [National Food Policy Capacity Strengthening Programme, Food and Agriculture Organization of the United Nations (Bangladesh)

    2016-02-15

    Arsenic (As), particularly of its inorganic form (iAs) is highly toxic, and its presence in food composites is a matter of concern for the public health safety, specifically in Bangladesh which is regarded as the most arsenic affected country throughout the world. This study was carried out to investigate the levels of As in the composite samples of commonly consumed foodstuffs collected from 30 different agro-ecological zones for the first time in Bangladesh. Most of the individual food composites contain a considerable amount of As which was, as a whole, in the range of 0.077–1.5 mg/kg fw which was lower than those reported from Spain, EU, France, Korea, whereas higher than those of Mexico, Chile, Japan, Cambodia, Hong Kong, Serbia, respectively. Cereals, vegetables, milk, and fish contribute about 90% to the daily intake of inorganic arsenic. Human health risk of dietary iAs was assessed separately for both the rural and urban adults. The estimated daily dietary intakes (EDI) of iAs for the exposed rural (3.5) and urban residents (3.2 μg/kg-BW/day) clearly exceeded the previous provisional tolerable daily intake (PTDI) value of 2.1 μg/kg-BW/day, recommended by the World Health Organization (WHO). From the health point of view, this study concluded that both the rural and urban residents of Bangladesh are exposed to carcinogenic and non-carcinogenic risks who consume As-contaminated water and foodstuffs. - Highlights: • A comprehensive health risk assessment from dietary arsenic exposure was evaluated. • Sample collected from 30 agro-ecological zones for the first time in Bangladesh. • Rural and urban adults are consuming more arsenic through food than the safe limit. • Cereals, vegetables, milk, and fish contribute about 90% to EDI of inorganic As. • Inhabitants are exposed chronically to arsenic induced risks.

  8. Foodstuff analyses show that seafood and water are major perfluoroalkyl acids (PFAAs) sources to humans in Korea

    International Nuclear Information System (INIS)

    Heo, Jin-Ju; Lee, Ji-Woo; Kim, Seung-Kyu; Oh, Jeong-Eun

    2014-01-01

    Graphical abstract: - Highlights: • 16 PFAAs in 397 samples of 66 food types and 34 tap water samples were analyzed. • Dietary exposure to PFAAs was estimated by using the PFAAs measured concentrations. • The major contributors of PFAAs dietary exposure were confirmed. - Abstract: We measured concentrations of PFAAs in 397 foods, of 66 types, in Korea, and determined the daily human dietary PFAAs intake and the contribution of each foodstuff to that intake. The PFAAs concentration in the 66 different food types ranged from below the detection limit to 48.3 ng/g. Perfluorooctane sulfonate (PFOS) and long-chain perfluorocarboxylic acids (PFCAs) were the dominant PFAAs in fish, shellfish, and processed foods, while perfluorooctanoic acid (PFOA) and short-chain PFCAs dominated dairy foodstuffs and beverages. The Korean adult dietary intake ranges, estimated for a range of scenarios, were 0.60–3.03 and 0.17–1.68 ng kg −1 bw d −1 for PFOS and PFOA, respectively, which were lower than the total daily intake limits suggested by European Food Safety Authority (PFOS: 150 ng kg −1 bw d −1 ; PFOA: 1500 ng kg −1 bw d −1 ). The major contributors to PFAAs dietary exposure varied with subject age and PFAAs. For example, fish was a major contributor of PFOS but dairy foods were major contributors of PFOA. However, tap water was a major contributor to PFOA intake when it was the main source of drinking water (rather than bottled water)

  9. A comprehensive assessment of arsenic in commonly consumed foodstuffs to evaluate the potential health risk in Bangladesh

    International Nuclear Information System (INIS)

    Ahmed, Md. Kawser; Shaheen, Nazma; Islam, Md. Saiful; Habibullah-Al-Mamun, Md.; Islam, Saiful; Islam, Md. Monirul; Kundu, Goutam Kumar; Bhattacharjee, Lalita

    2016-01-01

    Arsenic (As), particularly of its inorganic form (iAs) is highly toxic, and its presence in food composites is a matter of concern for the public health safety, specifically in Bangladesh which is regarded as the most arsenic affected country throughout the world. This study was carried out to investigate the levels of As in the composite samples of commonly consumed foodstuffs collected from 30 different agro-ecological zones for the first time in Bangladesh. Most of the individual food composites contain a considerable amount of As which was, as a whole, in the range of 0.077–1.5 mg/kg fw which was lower than those reported from Spain, EU, France, Korea, whereas higher than those of Mexico, Chile, Japan, Cambodia, Hong Kong, Serbia, respectively. Cereals, vegetables, milk, and fish contribute about 90% to the daily intake of inorganic arsenic. Human health risk of dietary iAs was assessed separately for both the rural and urban adults. The estimated daily dietary intakes (EDI) of iAs for the exposed rural (3.5) and urban residents (3.2 μg/kg-BW/day) clearly exceeded the previous provisional tolerable daily intake (PTDI) value of 2.1 μg/kg-BW/day, recommended by the World Health Organization (WHO). From the health point of view, this study concluded that both the rural and urban residents of Bangladesh are exposed to carcinogenic and non-carcinogenic risks who consume As-contaminated water and foodstuffs. - Highlights: • A comprehensive health risk assessment from dietary arsenic exposure was evaluated. • Sample collected from 30 agro-ecological zones for the first time in Bangladesh. • Rural and urban adults are consuming more arsenic through food than the safe limit. • Cereals, vegetables, milk, and fish contribute about 90% to EDI of inorganic As. • Inhabitants are exposed chronically to arsenic induced risks.

  10. Dependence of Magnetic Properties of Co/Pt Multilayers on Deposition Temperature of Pt Buffer Layers

    Science.gov (United States)

    Shiomi, Shigeru; Nishimura, Tomotaka; Kobayashi, Tadashi; Masuda, Morio

    1993-04-01

    A 15-nm-thick Pt buffer layer was deposited on a glass slide at temperature Ts(Ptbuf) ranging from 30 to 300°C by e-gun evaporation. Following the cooling in vacuum to ambient temperature, Co and Pt layers have been alternately deposited on it. Very large perpendicular anisotropy and coercivity have been obtained at Ts(Ptbuf) higher than 200°C. The (111) preferred orientation of the Co/Pt multilayer as well as the Pt buffer layer became more pronounced with elevating Ts(Ptbuf), to which the enhancement of perpendicular anisotropy with elevating Ts(Ptbuf) might be ascribable.

  11. Measurement of benzenethiol adsorption to nanostructured Pt, Pd, and PtPd films using Raman spectroelectrochemistry.

    Science.gov (United States)

    Pomfret, Michael B; Pietron, Jeremy J; Owrutsky, Jeffrey C

    2010-05-04

    Raman spectroscopy and electrochemical methods were used to study the behavior of the model adsorbate benzenethiol (BT) on nanostructured Pt, Pd, and PtPd electrodes as a function of applied potential. Benzenethiol adsorbs out of ethanolic solutions as the corresponding thiolate, and voltammetric stripping data reveal that BT is oxidatively removed from all of the nanostructured metals upon repeated oxidative and reductive cycling. Oxidative stripping potentials for BT increase in the order Pt oxidizing potentials via cleavage of the Pt-S bond. In contrast, on nanoscale Pd and PtPd, BT is irreversibly lost due to cleavage of BT C-S bonds at oxidizing potentials, which leaves adsorbed sulfur oxides on Pd and PtPd films and effects the desulfurization of BT. While Pd and PtPd films are less sulfur-resistant than Pt films, palladium oxides, which form at higher potentials than Pt oxides, oxidatively desulfurize BT. In situ spectroelectrochemical Raman spectroscopy provides real-time, chemically specific information that complements the cyclic voltammetric data. The combination of these techniques affords a powerful and convenient method for guiding the development of sulfur-tolerant PEMFC catalysts.

  12. Estimation of annual effective dose from 226Ra 228Ra due to consumption of foodstuffs by inhabitants of high level natural radiation of Ramsar, Iran

    International Nuclear Information System (INIS)

    Fathivand, A.A.; Asefi, M.; Amidi, A.

    2005-01-01

    Full text: A knowledge of natural radioactivity in man and his environment is important since naturally occurring radionuclides are the major source of radiation exposure to man. Radioactive nuclides present in the natural environment enter the human body mainly through food and water.Besides, measurement of naturally occurring radionuclides in the environment can be used not only as a reference when routine releases from nuclear installation or accidental radiation exposures are assessed, but also as a baseline to evaluate the impact caused by non-nuclear activities. In Iran, measurement of natural and artificial radionuclides in environmental samples in normal and high-background radiation areas have been performed by some investigators but no information has been available on 226 Ra and 228 Ra in foodstuffs. Therefore we have started measurements of 226 Ra and 228 Ra in foodstuffs of Ramsar which is a coastal city in the north part of Iran and has been known as one of the world's high level natural radiation areas, using low level gamma spectrometry measurement system .The results from our measurements and food consumption rates for inhabitants of Ramsar city have been used for the estimation of annual effective dose due to consumption of foodstuffs by inhabitants of Ramsar city. A total of 33 samples from 11 different foodstuffs including root vegetables (beetroot), leafy vegetables (lettuce, parsley and spinach) and tea, meat,chicken, pea,broad bean, rice, and cheese were purchased from markets and were analyzed for their 226 Ra and 228 Ra concentrations. The highest concentrations of 226 Ra and 228 Ra were determined in tea samples with 1570 and 1140 mBq kg -1 respectively and the maximum estimated annual effective dose from 226 Ra and Ra due to consumption foodstuffs were determined to be 19.22 and 0.71 μSv from rice and meat samples respectively

  13. Preparation of PtSn/C, PtRu/C, PtRh/C, PtRuRh/C and PtSnRh/C electrocatalysts using an alcohol-reduction process for methanol and ethanol oxidation

    International Nuclear Information System (INIS)

    Dias, Ricardo Rodrigues

    2009-01-01

    In this work, Pt/C, PtRh (90:10), PtRh/C (50:50), PtSn/C (50:50), PtRu (50:50)/C, PtRuRh/C (50:40:10) and PtSnRh/C (50:40:10) were prepared by an alcohol-reduction process with metal loading of 20 wt.% using H 2 PtCl 6 .6H 2 O (Aldrich), SnCl 2 .2H 2 O (Aldrich),and RhCl 2 .XH 2 O (Aldrich) as metals sources and Vulcan XC72 as support. The electrocatalysts were characterized by EDX, XRD and cyclic voltammetry (CV). The electro-oxidation of ethanol was studied by CV, chronoamperomety at room temperature in acid medium and tests at 100 deg C on a single cell of a direct methanol or ethanol fuel cell. The EDX analysis showed that the metal atomic ratios of the obtained electrocatalysts were similar to the nominal atomic ratios used in the preparation. The diffractograms of electrocatalysts prepared showed four peaks at approximately 2θ = 40 0 , 47 0 , 67 0 and 82 0 , which are associated with the (111), (200), (220) and (311) planes, respectively, of a face cubic-centered (fcc) structure characteristic of platinum and platinum alloys. The average crystallite sizes using the Scherrer equation and the calculated values were in the range of 2–3 nm. For PtSn/C and PtSnRh/C two additional peaks were observed at 2θ = 34 0 and 52 0 that were identified as a SnO 2 phase. PtSn/C (50:50) and PtSnRh/C (50:40:10) electrocatalyst showed the best performance for ethanol oxidation at room temperature. For methanol oxidation at room temperature PtRu/C, PtSn/C and PtRuRh/C electrocatalysts showed the best performance. Tests at 100 deg C on a single cell of a direct ethanol fuel cell PtSnRh/C showed the best performance, for methanol oxidation PtRuRh/C showed the best performance. (author)

  14. Synthesis and electrochemical study of Pt-based nanoporous materials

    International Nuclear Information System (INIS)

    Wang Jingpeng; Holt-Hindle, Peter; MacDonald, Duncan; Thomas, Dan F.; Chen Aicheng

    2008-01-01

    In the present work, a variety of Pt-based bimetallic nanostructured materials including nanoporous Pt, Pt-Ru, Pt-Ir, Pt-Pd and Pt-Pb networks have been directly grown on titanium substrates via a facile hydrothermal method. The as-fabricated electrodes were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction and electrochemical methods. The active surface areas of these nanoporous Pt-based alloy catalysts are increased by over 68 (Pt-Pd), 69 (Pt-Ru) and 113 (Pt-Ir) fold compared to a polycrystalline Pt electrode. All these synthesized nanoporous electrodes exhibit superb electrocatalytic performance towards electrochemical oxidation of methanol and formic acid. Among the five nanoporous Pt-based electrodes, the Pt-Ir shows the highest peak current density at +0.50 V, with 68 times of enhancement compared to the polycrystalline Pt for methanol oxidation, and with 86 times of enhancement in formic acid oxidation; whereas the catalytic activity of the nanoporous Pt-Pb electrode outperforms the other materials in formic acid oxidation at the low potential regions, delivering an enhanced current density by 280-fold compared to the polycrystalline Pt at +0.15 V. The new approach described in this study is suitable for synthesizing a wide range of bi-metallic and tri-metallic nanoporous materials, desirable for electrochemical sensor design and potential application in fuel cells

  15. Synthesis and electrochemical study of Pt-based nanoporous materials

    Energy Technology Data Exchange (ETDEWEB)

    Wang Jingpeng [Department of Chemistry, Lakehead University, Thunder Bay, Ontario P7B 5E1 (Canada); Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); Holt-Hindle, Peter; MacDonald, Duncan [Department of Chemistry, Lakehead University, Thunder Bay, Ontario P7B 5E1 (Canada); Thomas, Dan F. [Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); Chen Aicheng [Department of Chemistry, Lakehead University, Thunder Bay, Ontario P7B 5E1 (Canada)], E-mail: aicheng.chen@lakeheadu.ca

    2008-10-01

    In the present work, a variety of Pt-based bimetallic nanostructured materials including nanoporous Pt, Pt-Ru, Pt-Ir, Pt-Pd and Pt-Pb networks have been directly grown on titanium substrates via a facile hydrothermal method. The as-fabricated electrodes were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction and electrochemical methods. The active surface areas of these nanoporous Pt-based alloy catalysts are increased by over 68 (Pt-Pd), 69 (Pt-Ru) and 113 (Pt-Ir) fold compared to a polycrystalline Pt electrode. All these synthesized nanoporous electrodes exhibit superb electrocatalytic performance towards electrochemical oxidation of methanol and formic acid. Among the five nanoporous Pt-based electrodes, the Pt-Ir shows the highest peak current density at +0.50 V, with 68 times of enhancement compared to the polycrystalline Pt for methanol oxidation, and with 86 times of enhancement in formic acid oxidation; whereas the catalytic activity of the nanoporous Pt-Pb electrode outperforms the other materials in formic acid oxidation at the low potential regions, delivering an enhanced current density by 280-fold compared to the polycrystalline Pt at +0.15 V. The new approach described in this study is suitable for synthesizing a wide range of bi-metallic and tri-metallic nanoporous materials, desirable for electrochemical sensor design and potential application in fuel cells.0.

  16. Synthesis and electrochemical study of Pt-based nanoporous materials

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jingpeng [Department of Chemistry, Lakehead University, Thunder Bay, Ontario P7B 5E1 (Canada); Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); Holt-Hindle, Peter; MacDonald, Duncan; Chen, Aicheng [Department of Chemistry, Lakehead University, Thunder Bay, Ontario P7B 5E1 (Canada); Thomas, Dan F. [Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1 (Canada)

    2008-10-01

    In the present work, a variety of Pt-based bimetallic nanostructured materials including nanoporous Pt, Pt-Ru, Pt-Ir, Pt-Pd and Pt-Pb networks have been directly grown on titanium substrates via a facile hydrothermal method. The as-fabricated electrodes were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction and electrochemical methods. The active surface areas of these nanoporous Pt-based alloy catalysts are increased by over 68 (Pt-Pd), 69 (Pt-Ru) and 113 (Pt-Ir) fold compared to a polycrystalline Pt electrode. All these synthesized nanoporous electrodes exhibit superb electrocatalytic performance towards electrochemical oxidation of methanol and formic acid. Among the five nanoporous Pt-based electrodes, the Pt-Ir shows the highest peak current density at +0.50 V, with 68 times of enhancement compared to the polycrystalline Pt for methanol oxidation, and with 86 times of enhancement in formic acid oxidation; whereas the catalytic activity of the nanoporous Pt-Pb electrode outperforms the other materials in formic acid oxidation at the low potential regions, delivering an enhanced current density by 280-fold compared to the polycrystalline Pt at +0.15 V. The new approach described in this study is suitable for synthesizing a wide range of bi-metallic and tri-metallic nanoporous materials, desirable for electrochemical sensor design and potential application in fuel cells. (author)

  17. Co-deposition of Pt and ceria anode catalyst in supercritical carbon dioxide for direct methanol fuel cell applications

    International Nuclear Information System (INIS)

    You, Eunyoung; Guzmán-Blas, Rolando; Nicolau, Eduardo; Aulice Scibioh, M.; Karanikas, Christos F.; Watkins, James J.; Cabrera, Carlos R.

    2012-01-01

    Pt and mixed Pt-ceria catalysts were deposited onto gas diffusion layers using supercritical fluid deposition (SFD) to fabricate thin layer electrodes for direct methanol fuel cells. Dimethyl (1,5-cyclooctadiene) platinum (II) (CODPtMe 2 ) and tetrakis (2,2,6,6-tetramethyl 3,5-heptanedionato) cerium (IV) (Ce(tmhd) 4 ) were used as precursors. Hydrogen-assisted Pt deposition was performed in compressed carbon dioxide at 60 °C and 17.2 MPa to yield high purity Pt on carbon-black based gas diffusion layers. During the preparation of the mixed Pt-ceria catalyst, hydrogen reduction of CODPtMe 2 to yield Pt catalyzed the deposition of ceria from Ce(tmhd) 4 enabling co-deposition at 150 °C. The catalyst layers were characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope-energy dispersive spectral (SEM-EDS) analyses. Their electrochemical performance toward methanol oxidation was examined in half cell mode using a three electrode assembly as well as in fuel cell mode. The thin layer electrodes formed via SFD exhibited higher performance in fuel cell operations compared to those prepared by the conventional brush-paint method. Furthermore, the Pt-ceria catalyst with an optimized composition exhibited greater methanol oxidation activity than pure platinum.

  18. Fingerprinting ancient gold by measuring Pt with spatially resolved high energy Sy-XRF

    International Nuclear Information System (INIS)

    Guerra, M.F.; Calligaro, T.; Radtke, M.; Reiche, I.; Riesemeier, H.

    2005-01-01

    Trace elements of ancient gold such as Pt, give fundamental information on the circulation of the metal in the past. In the case of objects from the cultural heritage, the determination of trace elements requires non-destructive point analysis in general. These conditions and the need of good detection limits restrain the number of applicable analytical techniques. After the development of a PIXE set-up with a selective Cu or Zn filter of 75 μm and of a PIXE-XRF set-up using a primary target of As, we tested the possibilities of spatially resolved Sy-XRF to determine Pt in gold alloys. With a Zn filter, PIXE showed a detection limit of 1000 ppm in gold while PIXE-XRF lowers this detection limit down to 80 ppm. This last value being constrained by the resonant Raman effect produced on gold. In order to improve the detection limit of Pt keeping the non-destructiveness and access to point analysis, we developed an analytical protocol for XRF with synchrotron radiation at BESSY II, using the BAMline set-up. The L-lines of Pt were excited by a beam of energy above and below 11.564 keV and measured using a Si(Li) detector with a 50 μm Cu filter. A μ-beam of 100-250 μm 2 was used according to the size of the sample. The determination of the Pt content in the samples was carried out by Monte-Carlo simulation and subtraction of Au and Pt spectra obtained on pure standards. The limit of detection for Pt of 20 ppm was determined by using certified standards. The detection limits of a small set of other characteristic elements of gold were also measured using an incident energy of 33 keV

  19. Resistive switching in Pt/TiO{sub 2}/Pt

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Doo Seok

    2008-08-15

    Recently, the resistive switching behavior in TiO{sub 2} has drawn attention due to its application to resistive random access memory (RRAM) devices. TiO{sub 2} shows characteristic non-volatile resistive switching behavior, i.e. reversible switching between a high resistance state (HRS) and a low resistance state (LRS). Both unipolar resistive switching (URS) and bipolar resistive switching (BRS) are found to be observed in TiO{sub 2} depending on the compliance current for the electroforming. In this thesis the characteristic current-voltage (I-V) hysteresis in three different states of TiO{sub 2}, pristine, URS-activated, and BRS-activated states, was investigated and understood in terms of the migration of oxygen vacancies in TiO{sub 2}. The I-V hysteresis of pristine TiO{sub 2} was found to show volatile behavior. That is, the temporary variation of the resistance took place depending on the applied voltage. However, the I-V hysteresis of URS- and BRS-activated states showed non-volatile resistive switching behavior. Some evidences proving the evolution of oxygen gas during electroforming were obtained from time-of-flight secondary ion mass spectroscopy analysis and the variation of the morphology of switching cells induced by the electroforming. On the assumption that a large number of oxygen vacancies are introduced by the electroforming process, the I-V behavior in electroformed switching cells was simulated with varying the distribution of oxygen vacancies in electroformed TiO{sub x} (x Pt/TiO{sub x} interface. The oxygen-related reactions given as a function of the applied voltage affect the distribution of oxygen vacancies in TiO{sub x}, consequently, the Schottky barrier height at the cathode/TiO{sub x} interface is influenced by the oxygen vacancy distribution. Therefore, the BRS behavior including the

  20. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco; Basset, Jean-Marie

    2015-01-01

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles

  1. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  2. Design of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation.

    Science.gov (United States)

    Mao, Junjie; Chen, Wenxing; He, Dongsheng; Wan, Jiawei; Pei, Jiajing; Dong, Juncai; Wang, Yu; An, Pengfei; Jin, Zhao; Xing, Wei; Tang, Haolin; Zhuang, Zhongbin; Liang, Xin; Huang, Yu; Zhou, Gang; Wang, Leyu; Wang, Dingsheng; Li, Yadong

    2017-08-01

    Developing cost-effective, active, and durable electrocatalysts is one of the most important issues for the commercialization of fuel cells. Ultrathin Pt-Mo-Ni nanowires (NWs) with a diameter of ~2.5 nm and lengths of up to several micrometers were synthesized via a H 2 -assisted solution route (HASR). This catalyst was designed on the basis of the following three points: (i) ultrathin NWs with high numbers of surface atoms can increase the atomic efficiency of Pt and thus decrease the catalyst cost; (ii) the incorporation of Ni can isolate Pt atoms on the surface and produce surface defects, leading to high catalytic activity (the unique structure and superior activity were confirmed by spherical aberration-corrected electron microscopy measurements and ethanol oxidation tests, respectively); and (iii) the incorporation of Mo can stabilize both Ni and Pt atoms, leading to high catalytic stability, which was confirmed by experiments and density functional theory calculations. Furthermore, the developed HASR strategy can be extended to synthesize a series of Pt-Mo-M (M = Fe, Co, Mn, Ru, etc.) NWs. These multimetallic NWs would open up new opportunities for practical fuel cell applications.

  3. ANALISIS PENETAPAN HARGA JUAL BERDASARKAN TARGET COSTING PADA PT BUMI SARANA BETON MAKASSAR

    Directory of Open Access Journals (Sweden)

    Astiara Sriwati Taufiq Hasan

    2017-06-01

    Full Text Available Astiara Sriwati Taufiq Hasan, 2016. List Pricing Analysis Based On Target Costing PT Bumi Sarana Beton Makassar. (Guided by the Firman Menne, SE., M.Sc., AK., CA as a supervisor I and Thanwain., SE., M.Si as Supervisor II. This study aims to: (1 To determine the determination of the cost of production so as to improve the achievement of profit targets at PT Bumi Sarana Beton in Makassar. (2 To analyze and identify the costs that became the basis for setting the selling price as well as how the projections for the company. In collecting data the author uses the method of writing such as research literature in order to obtain literature-literature books that support for scientific writing. Research Field authors direct observation Beton to PT Bumi Sarana Makassar. Technical analysis is a method that I use Target Costing. Based on the results of the discussions that the authors have described, the author concludes that in PT Bumi Sarana Beton Makassar Based on the analysis of the implementation of target costing, which indicates that the application of target costing in PT Bumi Sarana Beton much more efficient when compared to that done by the company over the years.

  4. Comparison of intraocular pressure measurements with the portable PT100 noncontact tonometer and Goldmann applanation tonometry

    Directory of Open Access Journals (Sweden)

    Sarwat Salim

    2009-05-01

    Full Text Available Sarwat Salim, Daniel J Linn, James R Echols II, Peter A NetlandHamilton Eye Institute, University of Tennessee Health Science Center, Memphis, TN, USAPurpose: Noncontact tonometers are useful when regulations preclude use of contact tonometers by medical students and other nonophthalmologists. Our study compared the measurements by the portable, noncontact tonometer (PT100 with Goldmann applanation tonometry (GAT. Methods: This was a prospective study of 98 eyes from 98 patients. Intraocular pressure (IOP was measured by GAT and the PT100 (Reichert, Buffalo, NY.Results: Mean IOP measurements showed no significant differences in measurements performed by the two tonometers (P = 0.64. Measurements by the two tonometers were in agreement by ≤3 mmHg in 92.8% of eyes. Linear regression analysis of PT100 vs GAT measurements revealed a slope of 0.98 with r2 = 0.58. Bland–Altman analysis showed a mean difference of measurements by GAT and PT100 of -0.3 mmHg with two standard deviation = 7.1 mmHg.Conclusion: The portable noncontact PT100 tonometer provides IOP measurements comparable to GAT within the normal range of IOP. Keywords: applanation tonometer, intraocular pressure, noncontact tonometry

  5. Understanding the electrocatalytic activity of Pt xSn y in direct ethanol fuel cells

    Science.gov (United States)

    Wang, Yi; Song, Shuqin; Andreadis, George; Liu, Hong; Tsiakaras, Panagiotis

    In the present work, the activity of Pt xSn y/C catalysts towards ethanol, acetaldehyde and acetic acid electrooxidation reactions is investigated for each one separately by means of cyclic voltammetry. To this purpose, a series of Pt xSn y/C catalysts with different atomic ratio (x: y = 2:1, 3:2, 1:1) and small particle size (∼3 nm) are fast synthesized by using the pulse microwave assisted polyol method. The catalysts are well dispersed over the carbon support based on the physicochemical characterization by means of XRD and TEM. Concerning the ethanol electrooxidation, it is found that the Sn addition strongly enhances Pt's electrocatalytic activity and the contributing effect of Sn depends on: (i) the Sn content and (ii) the operating temperature. More precisely, at lower temperatures, Sn-rich catalysts exhibit better ethanol electrooxidation performance while at higher temperatures Sn-poor catalysts give better performance. In the case of acetaldehyde electrooxidation, Pt 1Sn 1/C catalyst exhibits the highest activity at all the investigated temperatures; due to the role of Sn, which could effectively remove C 2 species and inhibit the poison formation by supplying oxygen-containing species. Finally, it is found that the Pt xSn y/C catalysts are almost inactive (little current was measured) towards the acetic acid electrooxidation. The above findings indicate that Sn cannot substantially promote the electrooxidation of acetic acid to C 1 species.

  6. Microwave sinthesys and characterization of Pt and Pt-Rh-Sn electrocatalysts for ethanol oxidation

    Directory of Open Access Journals (Sweden)

    Jovanović Vladislava M.

    2011-01-01

    Full Text Available Carbon supported Pt and Pt-Rh-Sn catalysts were synthesized by microwave-polyol method in ethylene glycol solution and investigated for the ethanol electro-oxidation reaction. The catalysts were characterized in terms of structure, morphology and composition by employing XRD, STM and EDX techniques. STM analysis indicated rather uniform particles and particle size of below 2 nm for both catalysts. XRD analysis of the Pt/C catalyst revealed two phases, one with the main characteristic peaks of face centered cubic crystal structure (fcc of platinum and another related to graphite like structure of carbon support Vulcan XC-72R. However, in XRD pattern of the Pt-Rh-Sn/C catalyst diffraction peaks for Pt, Rh or Sn cannot be resolved, indicating an extremely low crystallinity. The small particle sizes and homogeneous size distributions of both catalysts should be attributed to the advantages of microwave assisted modified polyol process in ethylene glycol solution. Pt-Rh- Sn/C catalyst is highly active for the ethanol oxidation with the onset potential shifted for more than 150 mV to negative values and with currents nearly 5 times higher in comparison to Pt/C catalyst. The stability tests of the catalysts, as studied by the chronoamperometric experiments, reveal that the Pt-Rh-Sn/C catalyst is evidently less poisoned then Pt/C catalyst. The increased activity of Pt-Rh-Sn/C in comparison to Pt/C catalyst is most probably promoted by bifunctional mechanism and the electronic effect of alloyed metals.

  7. Pt skin coated hollow Ag-Pt bimetallic nanoparticles with high catalytic activity for oxygen reduction reaction

    Science.gov (United States)

    Fu, Tao; Huang, Jianxing; Lai, Shaobo; Zhang, Size; Fang, Jun; Zhao, Jinbao

    2017-10-01

    The catalytic activity and stability of electrocatalyst is critical for the commercialization of fuel cells, and recent reports reveal the great potential of the hollow structures with Pt skin coat for developing high-powered electrocatalysts due to their highly efficient utilization of the Pt atoms. Here, we provide a novel strategy to prepare the Pt skin coated hollow Ag-Pt structure (Ag-Pt@Pt) of ∼8 nm size at room temperature. As loaded on the graphene, the Ag-Pt@Pt exhibits a remarkable mass activity of 0.864 A/mgPt (at 0.9 V, vs. reversible hydrogen electrode (RHE)) towards oxygen reduction reaction (ORR), which is 5.30 times of the commercial Pt/C catalyst, and the Ag-Pt@Pt also shows a better stability during the ORR catalytic process. The mechanism of this significant enhancement can be attributed to the higher Pt utilization and the unique Pt on Ag-Pt surface structure, which is confirmed by the density functional theory (DFT) calculations and other characterization methods. In conclusion, this original work offers a low-cost and environment-friendly method to prepare a high active electrocatalyst with cheaper price, and this work also discloses the correlation between surface structures and ORR catalytic activity for the hollow structures with Pt skin coat, which can be instructive for designing novel advanced electrocatalysts for fuel cells.

  8. Pt and PtRu catalyst bilayers increase efficiencies for ethanol oxidation in proton exchange membrane electrolysis and fuel cells

    Science.gov (United States)

    Altarawneh, Rakan M.; Pickup, Peter G.

    2017-10-01

    Polarization curves, product distributions, and reaction stoichiometries have been measured for the oxidation of ethanol at anodes consisting of Pt and PtRu bilayers and a homogeneous mixture of the two catalysts. These anode structures all show synergies between the two catalysts that can be attributed to the oxidation of acetaldehyde produced at the PtRu catalyst by the Pt catalyst. The use of a PtRu layer over a Pt layer produces the strongest effect, with higher currents than a Pt on PtRu bilayer, mixed layer, or either catalyst alone, except for Pt at high potentials. Reaction stoichiometries (average number of electrons transferred per ethanol molecule) were closer to the values for Pt alone for both of the bilayer configurations but much lower for PtRu and mixed anodes. Although Pt alone would provide the highest overall fuel cell efficiency at low power densities, the PtRu on Pt bilayer would provide higher power densities without a significant loss of efficiency. The origin of the synergy between the Pt and PtRu catalysts was elucidated by separation of the total current into the individual components for generation of carbon dioxide and the acetaldehyde and acetic acid byproducts.

  9. Preparation of PtSn/C, PtRu/C, PtRh/C, PtRuRh/C and PtSnRh/C electrocatalysts using an alcohol-reduction process for methanol and ethanol oxidation; Preparacao e caracterizacao de eletrocatalisadores PtRu, PtSn, PtRh, PtRuRh e PtSnRh para oxidacao direta de alcoois em celulas a combustivel tipo PEM utilizando a metodologia da reducao por alcool

    Energy Technology Data Exchange (ETDEWEB)

    Dias, Ricardo Rodrigues

    2009-07-01

    In this work, Pt/C, PtRh (90:10), PtRh/C (50:50), PtSn/C (50:50), PtRu (50:50)/C, PtRuRh/C (50:40:10) and PtSnRh/C (50:40:10) were prepared by an alcohol-reduction process with metal loading of 20 wt.% using H{sub 2}PtCl{sub 6}.6H{sub 2}O (Aldrich), SnCl{sub 2}.2H{sub 2}O (Aldrich),and RhCl{sub 2}.XH{sub 2}O (Aldrich) as metals sources and Vulcan XC72 as support. The electrocatalysts were characterized by EDX, XRD and cyclic voltammetry (CV). The electro-oxidation of ethanol was studied by CV, chronoamperomety at room temperature in acid medium and tests at 100 deg C on a single cell of a direct methanol or ethanol fuel cell. The EDX analysis showed that the metal atomic ratios of the obtained electrocatalysts were similar to the nominal atomic ratios used in the preparation. The diffractograms of electrocatalysts prepared showed four peaks at approximately 2{theta} =40 deg, 47 deg, 67 deg and 82 deg, which are associated with the (111), (200), (220) and (311) planes, respectively, of a face cubic-centered (fcc) structure characteristic of platinum and platinum alloys. The average crystallite sizes using the Scherrer equation and the calculated values were in the range of 2-3 nm. For Pt Sn/C and PtSnRh/C two additional peaks were observed at 2 = 34 deg and 52 deg that were identified as a SnO{sub 2} phase. Pt Sn/C (50:50) and PtSnRh/C (50:40:10) electro catalyst showed the best performance for ethanol oxidation at room temperature. For methanol oxidation at room temperature Pt Ru/C, Pt Sn/C and PtRuRh/C electrocatalysts showed the best performance. Tests at 100 deg C on a single cell of a direct ethanol fuel cell PtSnRh/C showed the best performance, for methanol oxidation PtRuRh/C showed the best performance. (author)

  10. Preparation of PtSn/C, PtRu/C, PtRh/C, PtRuRh/C and PtSnRh/C electrocatalysts using an alcohol-reduction process for methanol and ethanol oxidation; Preparacao e caracterizacao de eletrocatalisadores PtRu, PtSn, PtRh, PtRuRh e PtSnRh para oxidacao direta de alcoois em celulas a combustivel tipo PEM utilizando a metodologia da reducao por alcool

    Energy Technology Data Exchange (ETDEWEB)

    Dias, Ricardo Rodrigues

    2009-07-01

    In this work, Pt/C, PtRh (90:10), PtRh/C (50:50), PtSn/C (50:50), PtRu (50:50)/C, PtRuRh/C (50:40:10) and PtSnRh/C (50:40:10) were prepared by an alcohol-reduction process with metal loading of 20 wt.% using H{sub 2}PtCl{sub 6}.6H{sub 2}O (Aldrich), SnCl{sub 2}.2H{sub 2}O (Aldrich),and RhCl{sub 2}.XH{sub 2}O (Aldrich) as metals sources and Vulcan XC72 as support. The electrocatalysts were characterized by EDX, XRD and cyclic voltammetry (CV). The electro-oxidation of ethanol was studied by CV, chronoamperomety at room temperature in acid medium and tests at 100 deg C on a single cell of a direct methanol or ethanol fuel cell. The EDX analysis showed that the metal atomic ratios of the obtained electrocatalysts were similar to the nominal atomic ratios used in the preparation. The diffractograms of electrocatalysts prepared showed four peaks at approximately 2θ = 40{sup 0}, 47{sup 0}, 67{sup 0} and 82{sup 0}, which are associated with the (111), (200), (220) and (311) planes, respectively, of a face cubic-centered (fcc) structure characteristic of platinum and platinum alloys. The average crystallite sizes using the Scherrer equation and the calculated values were in the range of 2–3 nm. For PtSn/C and PtSnRh/C two additional peaks were observed at 2θ = 34{sup 0} and 52{sup 0} that were identified as a SnO{sub 2} phase. PtSn/C (50:50) and PtSnRh/C (50:40:10) electrocatalyst showed the best performance for ethanol oxidation at room temperature. For methanol oxidation at room temperature PtRu/C, PtSn/C and PtRuRh/C electrocatalysts showed the best performance. Tests at 100 deg C on a single cell of a direct ethanol fuel cell PtSnRh/C showed the best performance, for methanol oxidation PtRuRh/C showed the best performance. (author)

  11. Metallic behavior and periodical valence ordering in a MMX chain compound, Pt(2)(EtCS(2))(4)I.

    Science.gov (United States)

    Mitsumi, M; Murase, T; Kishida, H; Yoshinari, T; Ozawa, Y; Toriumi, K; Sonoyama, T; Kitagawa, H; Mitani, T

    2001-11-14

    A new one-dimensional (1-D) halogen-bridged mixed-valence diplatinum(II,III) compound, Pt(2)(EtCS(2))(4)I (3), has been successfully synthesized from [Pt(2)(EtCS(2))(4)] (1) and [Pt(2)(EtCS(2))(4)I(2)] (2). These three compounds have been examined using UV-visible-near-IR, IR, polarized Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and X-ray crystal structure analyses (except for 1). Compound 3 was further characterized through electrical transport measurements, determination of the temperature dependence of lattice parameters, X-ray diffuse scattering, and SQUID magnetometry. 3 crystallizes in the monoclinic space group C2/c and exhibits a crystal structure consisting of neutral 1-D chains with a repeating -Pt-Pt-I- unit lying on the crystallographic 2-fold axis parallel to the b axis. The Pt-Pt distance at 293 K is 2.684 (1) A in the dinuclear unit, while the Pt-I distances are essentially equal (2.982 (1) and 2.978 (1) A). 3 shows relatively high electrical conductivity (5-30 S cm(-1)) at room temperature and undergoes a metal-semiconductor transition at T(M-S) = 205 K. The XPS spectrum in the metallic state reveals a Pt(2+) and Pt(3+) mixed-valence state on the time scale of XPS spectroscopy ( approximately 10(-17) s). In accordance with the metal-semiconductor transition, anomalies are observed in the temperature dependence of the crystal structure, lattice parameters, X-ray diffuse scattering, and polarized Raman spectra near T(M-S). In variable-temperature crystal structure analyses, a sudden and drastic increase in the Pt-I distance near the transition temperature is observed. Furthermore, a steep increase in U(22) of iodine atoms in the 1-D chain direction has been observed. The lattice parameters exhibit significant temperature dependence with drastic change in slope at about 205-240 K. This was especially evident in the unit cell parameter b (1-D chain direction) as it was found to lengthen rapidly with increasing temperature. X

  12. Neutron spectrum unfolding: Pt. 2

    International Nuclear Information System (INIS)

    Matiullah; Wiyaja, D.S.; Berzonis, M.A.; Bondars, H.; Lapenas, A.A.; Kudo, K.; Majeed, A.; Durrani, S.A.

    1991-01-01

    In Part I of this paper, we described the use of the computer code SAIPS in neutron spectrum unfolding. Here in Part II, we present our experimental work carried out to study the shape of the neutron spectrum in different experimental channels of a 5 MW light-water cooled and moderated research reactor. The spectral neutron flux was determined using various fission foils (placed in close contact with mica track detectors) and activation detectors. From the measured activities, the neutron spectrum was unfolded by SAIPS. (author)

  13. Determination of toxic and essential elements in foodstuffs from local market in Jakarta

    International Nuclear Information System (INIS)

    Sadjirun, S.

    1994-01-01

    This report presents data on toxic and essential elements such as As, Cd, Cr, Cu, Hg, Pb, Sb, Se, and Zn in rice, corn, bean, wheat, small green pea, vegetables, fruits, tea, coffee, sea foods, meat, chicken, intestines and associated organs, and eggs as consumed in Jakarta. As, Hg, Sb, Cr, Se, and Zn were determined using instrumental neutron activation analysis (INAA) after being irradiated at TRIGA MARK II reactor, while Cd, Cu, and Pb were determined using atomic absorption spectrometry (AAS). The results obtained were lower than the maximum permissible concentrations allowed. (author). 6 refs, 9 tabs

  14. Strongly bound excitons in monolayer PtS2 and PtSe2

    KAUST Repository

    Sajjad, M.; Singh, Nirpendra; Schwingenschlö gl, Udo

    2018-01-01

    Based on first-principles calculations, the structural, electronic, and optical properties of monolayers PtS2 and PtSe2 are investigated. The bond stiffnesses and elastic moduli are determined by means of the spring constants and strain

  15. Benchmarking Pt and Pt-lanthanide sputtered thin films for oxygen electroreduction

    DEFF Research Database (Denmark)

    Zamburlini, Eleonora; Jensen, Kim Degn; Stephens, Ifan E.L.

    2017-01-01

    Platinum-lanthanide alloys are very promising as active and stable catalysts for the oxygen reduction reaction (ORR) in low-temperature fuel cells. We have fabricated Pt and Pt5Gd metallic thin films via (co-)sputtering deposition in an ultra-high vacuum (UHV) chamber. The electrochemical ORR...

  16. PERJANJIAN BOT (BUILD OPERATE AND TRANSFER ANTARA PT. SEAWORLD INDONESIA DENGAN PT PEMBANGUNAN JAYA ANCOL Tbk

    Directory of Open Access Journals (Sweden)

    Arasina Chandra Adcha Mita

    2015-10-01

    Full Text Available Cooperation Cooperation BOT build operate and transfer (BOT is a form of cooperation agreements carried out between holders of land rights to the investor which holders of land rights would entitle the investor to erect a building for the duration of the agreement to transfer ownership of the building to holders of land rights after a period ofwake up in order to deliver an end. One form of the agreement made by PT. Jaya Ancol construction with vehicle manager of Sea World for 20 years ended 20 September 2014. This thesis entitled "Agreement Bot (Build Operate And Transfer between PT.Seaworld Indonesia with PT Building Jaya Ancol Tbk ". The purpose of this study was to determine the problems that arise in the implementation of BOT agreement between PT. Sea Wold Indonesia with PT. Jaya Ancol Tbk development and how its completion. The research method using normative juridical approach. Materials research using primary and secondary data, specifications research using descriptive analytical research, libraries and research tools using interviews, interview techniques and research data analysis method by means of qualitative methods. Based on the research that the differences in perception by each of the parties to cause problems in the BOT agreement. PT. Jaya Ancol development assume that the clause 8 subsection 5 of the Agreement between PT. Development Jaya Ancol Tbk and Sea World considers that the current agreement expires, PT. Sea World Indonesia handing back land and building project to PT. Jaya Ancol Tbk development, including supporting infrastructure and its management rights. The guidelines are used as Sea World Indonesia is clause 8 subsection  6 which states PT. Sea World Indonesia, have a perception extend the management for a maximum of 20 years, and shall notify in writing the Jaya Ancol no later than one year agreement period expires. PT. Sea World is obliged to hand over the building and its assets to PT

  17. Preparation and Thermoelectric Characteristics of ITO/PtRh:PtRh Thin Film Thermocouple.

    Science.gov (United States)

    Zhao, Xiaohui; Wang, Hongmin; Zhao, Zixiang; Zhang, Wanli; Jiang, Hongchuan

    2017-12-15

    Thin film thermocouples (TFTCs) can provide more precise in situ temperature measurement for aerospace propulsion systems without disturbance of gas flow and surface temperature distribution of the hot components. ITO/PtRh:PtRh TFTC with multilayer structure was deposited on alumina ceramic substrate by magnetron sputtering. After annealing, the TFTC was statically calibrated for multiple cycles with temperature up to 1000 °C. The TFTC with excellent stability and repeatability was realized for the negligible variation of EMF in different calibration cycles. It is believed that owing to oxygen diffusion barriers by the oxidation of top PtRh layer and Schottky barriers formed at the grain boundaries of ITO, the variation of the carrier concentration of ITO film is minimized. Meanwhile, the life time of TFTC is more than 30 h in harsh environment. This makes ITO/PtRh:PtRh TFTC a promising candidate for precise surface temperature measurement of hot components of aeroengines.

  18. Time-invariant PT product and phase locking in PT -symmetric lattice models

    Science.gov (United States)

    Joglekar, Yogesh N.; Onanga, Franck Assogba; Harter, Andrew K.

    2018-01-01

    Over the past decade, non-Hermitian, PT -symmetric Hamiltonians have been investigated as candidates for both a fundamental, unitary, quantum theory and open systems with a nonunitary time evolution. In this paper, we investigate the implications of the former approach in the context of the latter. Motivated by the invariance of the PT (inner) product under time evolution, we discuss the dynamics of wave-function phases in a wide range of PT -symmetric lattice models. In particular, we numerically show that, starting with a random initial state, a universal, gain-site location dependent locking between wave-function phases at adjacent sites occurs in the PT -symmetry-broken region. Our results pave the way towards understanding the physically observable implications of time invariants in the nonunitary dynamics produced by PT -symmetric Hamiltonians.

  19. Formal system of communication and understanding. II

    Energy Technology Data Exchange (ETDEWEB)

    Zsuzsanna, M

    1982-01-01

    For pt.I see IBID., no.5, p.252-8 (1982). In this article G. Pask's (1975) formal theory of dialogues and talk is summarized. Part II describes the talk-environment and modelling. The conscious systems and machine-intelligence are mainly dealt with. Finally a couple of cases with Pask's theory implemented are looked at. 7 references.

  20. SFG study of methanol dissociative adsorption at Pt(1 0 0), Pt(1 1 0) and Pt(1 1 1) electrodes surfaces

    Science.gov (United States)

    Vidal, F.; Busson, B.; Six, C.; Pluchery, O.; Tadjeddine, A.

    2002-04-01

    The Pt( hkl)/methanol in acidic solution interface which constitutes a model of the anodic part of a fuel cell is studied by infrared-visible sum frequency generation vibrational spectroscopy. Methanol dissociative adsorption leads to CO poisoning of the Pt electrode surfaces. The structure of the CO/Pt( hkl) interface depends strongly on the orientation of the surface electrode.

  1. Studies of radioactive cisplatin ({sup 191}Pt) for tumour imaging and therapy

    Energy Technology Data Exchange (ETDEWEB)

    Areberg, J

    2000-01-01

    A radioactive variant of the cytostatic agent cis-dichlorodiammineplatinum(II), cisplatin, was synthesised from {sup 191}PtCl{sub 4}. The {sup 191}Pt-cisplatin was found to be a sterile product of high radionuclide, radiochemical and chemical purity. The pharmacokinetics of platinum in tumour tissue and organs at risk of fourteen patients undergoing treatment with cisplatin were studied by exchanging a small fraction of the prescribed amount of cisplatin with {sup 191}Pt-cisplatin. The uptake and retention of platinum were investigated by gamma camera measurements up to ten days after infusion of {sup 191}Pt-cisplatin. Highest concentration of platinum was found in the liver, on average 5.7 {+-} 0.5 {mu}g/g normalised to a given amount of 180 mg cisplatin. Corresponding value for the kidneys was 1.9 {+-} 0.3 {mu}g/g. Uptake of platinum in tumours was visualised in five patients with an average maximum concentration of 4.9 {+-} 1.0 {mu}g/g normalised to a given amount of 180 mg cisplatin. The data from the pharmacokinetic study was used together with data from the literature to estimate the absorbed dose and effective dose to patients receiving radioactive cisplatin. The effective doses were calculated to be 0.10 {+-} 0.02 mSv/MBq, 0.17 {+-} 0.04 mSv/MBq and 0.23 {+-} 0.05 mSv/MBq for {sup 191}Pt-, {sup 193m}Pt-, and {sup 195m}Pt-cisplatin respectively. The combined effect of the radio- and chemotoxicity from {sup 191}Pt-cisplatin was investigated both in vitro and in vivo. A cervical cancer cell line was incubated with cisplatin or {sup 191}Pt-cisplatin with various concentrations and specific activities. It was shown that the surviving fraction was smaller for cells treated with {sup 191}Pt-cisplatin than for cells treated with the same concentration of non-radioactive cisplatin. The surviving fraction decreased with increasing specific activity. Isobologram technique showed that the radio- and chemotoxicity interacted in a supra-additive (synergistic) manner. In

  2. Studies of radioactive cisplatin (191Pt) for tumour imaging and therapy

    International Nuclear Information System (INIS)

    Areberg, J.

    2000-01-01

    A radioactive variant of the cytostatic agent cis-dichlorodiammineplatinum(II), cisplatin, was synthesised from 191 PtCl 4 . The 191 Pt-cisplatin was found to be a sterile product of high radionuclide, radiochemical and chemical purity. The pharmacokinetics of platinum in tumour tissue and organs at risk of fourteen patients undergoing treatment with cisplatin were studied by exchanging a small fraction of the prescribed amount of cisplatin with 191 Pt-cisplatin. The uptake and retention of platinum were investigated by gamma camera measurements up to ten days after infusion of 191 Pt-cisplatin. Highest concentration of platinum was found in the liver, on average 5.7 ± 0.5 μg/g normalised to a given amount of 180 mg cisplatin. Corresponding value for the kidneys was 1.9 ± 0.3 μg/g. Uptake of platinum in tumours was visualised in five patients with an average maximum concentration of 4.9 ± 1.0 μg/g normalised to a given amount of 180 mg cisplatin. The data from the pharmacokinetic study was used together with data from the literature to estimate the absorbed dose and effective dose to patients receiving radioactive cisplatin. The effective doses were calculated to be 0.10 ± 0.02 mSv/MBq, 0.17 ± 0.04 mSv/MBq and 0.23 ± 0.05 mSv/MBq for 191 Pt-, 193m Pt-, and 195m Pt-cisplatin respectively. The combined effect of the radio- and chemotoxicity from 191 Pt-cisplatin was investigated both in vitro and in vivo. A cervical cancer cell line was incubated with cisplatin or 191 Pt-cisplatin with various concentrations and specific activities. It was shown that the surviving fraction was smaller for cells treated with 191 Pt-cisplatin than for cells treated with the same concentration of non-radioactive cisplatin. The surviving fraction decreased with increasing specific activity. Isobologram technique showed that the radio- and chemotoxicity interacted in a supra-additive (synergistic) manner. In an in vivo model, nude mice with xenografted tumours were given

  3. Laue image analysis. Pt. 2

    International Nuclear Information System (INIS)

    Greenhough, T.J.; Shrive, A.K.

    1994-01-01

    Many Laue diffraction patterns from crystals of particular biological or chemical interest are of insufficient quality for their analysis to be feasible. In many cases, this is because of pronounced streaking of the spots owing to either large mosaic spread or disorder introduced during reactions in the crystal. Methods for the analysis of exposures exhibiting radial or near-radial streaking are described, along with their application in Laue diffraction studies of form-II crystals of Met-tRNA synthetase and a photosynthetic reaction centre from Rhodobacter sphaeroides. In both cases, variable elliptical radial masking has led to significant improvements in data quality and quantity and exposures that previously were too streaked to process may now be analysed. These masks can also provide circular profiles as a special case for processing high-quality Laue exposures and spatial-overlap deconvolution may be performed using the elliptical or circular masks. (orig.)

  4. The Relationship Between Antecedent and Consequence Factors with Safety Behaviour in PT.X

    OpenAIRE

    Fitriani, Apris; Nawawiwetu, Erwin Dyah

    2017-01-01

    Background : Safety behaviour is an act worker to minimize the possibility of accidents in workplace. Based on the Antecedents-Behaviour-Consequence (ABC) theory, safety behaviour of worker related with the antecedent and consequence factors. Purpose : The purpose of this research was to study the association between antecedent and consequence factors with safety behaviour of workers in Ring Frame Unit Spinning II PT. X. Methods : This was an observational descriptive research with cross sect...

  5. ANALISIS SISTEM INFORMASI AKUNTANSI PENJUALAN PADA PT HADJI KALLA (TOYOTA) CABANG PINRANG

    OpenAIRE

    Andi Mujahidah

    2017-01-01

    Andi Mujahidah, (2015) "Accounting Information System Analysis Sales At PT Hadji Kalla (Toyota) Branch Pinrang" under the guidance of Mrs. Faridah, SE., M.Si, .AK, .ca as first counselor and Mr. Thanwain, SE ,. M.Si as supervisor II. Accounting Information Systems are very important in the sales function remembers every sales transaction must involve the responsibility of a few people within the company. To improve the handling of the sale of the company it needed an adequate internal cont...

  6. 10 CFR Appendix II to Part 504 - Fuel Price Computation

    Science.gov (United States)

    2010-01-01

    ... DEPARTMENT OF ENERGY (CONTINUED) ALTERNATE FUELS EXISTING POWERPLANTS Pt. 504, App. II Appendix II to Part... effects of future real price increases for each fuel. The delivered price of an alternate fuel used to calculate delivered fuel expenses must reflect the petitioner's delivered price of the alternate fuel and...

  7. Synthesis and characterization of the Rhodium (II) citrate complex

    International Nuclear Information System (INIS)

    Najjar, R.; Santos, F.S. dos; Seidel, W.

    1987-01-01

    The preparation and characterization of the rhodium (II) citrate is described. Rhodium citrate was prepared by reacting citric acid trihydrated (3,4 g, 16 mmols) with anhydrous rhodium acetate (0,44 g, 1 mmol). Th electronic instruments, thermogravimetric curve and spectrum of rhodium (II) citrate are analysed. (M.J.C.) [pt

  8. A tetrapyridine ligand with a rigid tetrahedral core forms metal-organic frameworks with PtS type architecture.

    Science.gov (United States)

    Caputo, Christopher B; Vukotic, V Nicholas; Sirizzotti, Natalie M; Loeb, Stephen J

    2011-08-14

    A new tetradentate, pyridine ligand with a rigid tetrahedral core can be prepared in good yield by a cross-coupling methodology. Two metal organic framework structures of Cu(II) with PtS-type topology having a carbon atom as the tetrahedral node have been characterized utilising this ligand. This journal is © The Royal Society of Chemistry 2011

  9. Dehydrogenation of benzene on Pt(111) surface

    Science.gov (United States)

    Gao, W.; Zheng, W. T.; Jiang, Q.

    2008-10-01

    The dehydrogenation of benzene on Pt(111) surface is studied by ab initio density functional theory. The minimum energy pathways for benzene dehydrogenation are found with the nudge elastic band method including several factors of the associated barriers, reactive energies, intermediates, and transient states. The results show that there are two possible parallel minimum energy pathways on the Pt(111) surface. Moreover, the tilting angle of the H atom in benzene can be taken as an index for the actual barrier of dehydrogenation. In addition, the properties of dehydrogenation radicals on the Pt(111) surface are explored through their adsorption energy, adsorption geometry, and electronic structure on the surface. The vibrational frequencies of the dehydrogenation radicals derived from the calculations are in agreement with literature data.

  10. PT symmetric Aubry–Andre model

    International Nuclear Information System (INIS)

    Yuce, C.

    2014-01-01

    PT symmetric Aubry–Andre model describes an array of N coupled optical waveguides with position-dependent gain and loss. We show that the reality of the spectrum depends sensitively on the degree of quasi-periodicity for small number of lattice sites. We obtain the Hofstadter butterfly spectrum and discuss the existence of the phase transition from extended to localized states. We show that rapidly changing periodical gain/loss materials almost conserve the total intensity. - Highlights: • We show that PT symmetric Aubry–Andre model may have real spectrum. • We show that the reality of the spectrum depends sensitively on the degree of disorder. • We obtain the Hofstadter butterfly spectrum for PT symmetric Aubry–Andre model. • We discuss that phase transition from extended to localized states exists

  11. PT symmetric Aubry–Andre model

    Energy Technology Data Exchange (ETDEWEB)

    Yuce, C., E-mail: cyuce@anadolu.edu.tr

    2014-06-13

    PT symmetric Aubry–Andre model describes an array of N coupled optical waveguides with position-dependent gain and loss. We show that the reality of the spectrum depends sensitively on the degree of quasi-periodicity for small number of lattice sites. We obtain the Hofstadter butterfly spectrum and discuss the existence of the phase transition from extended to localized states. We show that rapidly changing periodical gain/loss materials almost conserve the total intensity. - Highlights: • We show that PT symmetric Aubry–Andre model may have real spectrum. • We show that the reality of the spectrum depends sensitively on the degree of disorder. • We obtain the Hofstadter butterfly spectrum for PT symmetric Aubry–Andre model. • We discuss that phase transition from extended to localized states exists.

  12. PT-symmetry management in oligomer systems

    International Nuclear Information System (INIS)

    Horne, R L; Cuevas, J; Kevrekidis, P G; Whitaker, N; Abdullaev, F Kh; Frantzeskakis, D J

    2013-01-01

    We study the effects of management of the PT-symmetric part of the potential within the setting of Schrödinger dimer and trimer oligomer systems. This is done by rapidly modulating in time the gain/loss profile. This gives rise to a number of interesting properties of the system, which are explored at the level of an averaged equation approach. Remarkably, this rapid modulation provides for a controllable expansion of the region of exact PT-symmetry, depending on the strength and frequency of the imposed modulation. The resulting averaged models are analysed theoretically and their exact stationary solutions are translated into time-periodic solutions through the averaging reduction. These are, in turn, compared with the exact periodic solutions of the full non-autonomous PT-symmetry managed problem and very good agreement is found between the two. (paper)

  13. Growth, structure and magnetic properties of magnetron sputtered FePt thin films

    Energy Technology Data Exchange (ETDEWEB)

    Cantelli, Valentina

    2010-07-01

    The L1{sub 0} FePt phase belongs to the most promising hard ferromagnetic materials for high density recording media. The main challenges for thin FePt films are: (i) to lower the process temperature for the transition from the soft magnetic A1 to the hard magnetic L1{sub 0} phase, (ii) to realize c-axes preferential oriented layers independently from the substrate nature and (iii) to control layer morphology supporting the formation of FePt-L1{sub 0} selforganized isolated nanoislands towards an increase of the signal-to-noise ratio. In this study, dc magnetron sputtered FePt thin films on amorphous substrates were investigated. The work is focused on the correlation between structural and magnetic properties with respect to the influence of deposition parameters like growth mode (cosputtering vs. layer - by - layer) and the variation of the deposition gas (Ar, Xe) or pressure (0.3-3 Pa). In low-pressure Ar discharges, high energetic particle impacts support vacancies formation during layer growth lowering the phase transition temperature to (320{+-}20) C. By reducing the particle kinetic energy in Xe discharges, highly (001) preferential oriented L1{sub 0}-FePt films were obtained on a-SiO{sub 2} after vacuum annealing. L1{sub 0}-FePt nano-island formation was supported by the introduction of an Ag matrix, or by random ballistic aggregation and atomic self shadowing realized by FePt depositions at very high pressure (3 Pa). The high coercivity (1.5 T) of granular, magnetic isotropic FePt layers, deposited in Ar discharges, was measured with SQUID magnetometer hysteresis loops. For non-granular films with (001) preferential orientation the coercivity decreased (0.6 T) together with an enhancement of the out-of- plane anisotropy. Nanoislands show a coercive field close to the values obtained for granular layers but exhibit an in-plane easy axis due to shape anisotropy effects. An extensive study with different synchrotron X-ray scattering techniques, mainly

  14. Relaxor-PT Single Crystal Piezoelectric Sensors

    Directory of Open Access Journals (Sweden)

    Xiaoning Jiang

    2014-07-01

    Full Text Available Relaxor-PbTiO3 piezoelectric single crystals have been widely used in a broad range of electromechanical devices, including piezoelectric sensors, actuators, and transducers. This paper reviews the unique properties of these single crystals for piezoelectric sensors. Design, fabrication and characterization of various relaxor-PT single crystal piezoelectric sensors and their applications are presented and compared with their piezoelectric ceramic counterparts. Newly applicable fields and future trends of relaxor-PT sensors are also suggested in this review paper.

  15. Colloidal Toolbox Synthesis of Pt Nanoalloys

    DEFF Research Database (Denmark)

    Spanos, Ioannis

    /precipitation technique, which is commonly used in industrial synthesis offuel cell catalysts, will serve as reference. In this particular method, due to the slow rate of themetal precursor reduction and conversion to the metallic state and the even slower diffusion of themetal species on the surface of the carbon......Co1-x nanoalloys, the so-called particledisorder, with the lattice strain. Alloying Pt with increasing amount of Co increases strain andparticle disorder and subsequently both ORR performance and NPs stability. However, excessivealloying and de-alloying, as in the case of PtCo6, leads to particle...

  16. Carbon supported nanoparticles Pt Ru (Pt Ru/C electrocatalysts) prepared using electron beam irradiation; Preparacao de nanoparticulas de PtRu suportadas em carbono (eletrocatalisadores PtRu/C) utilizando feixe de eletrons

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Dionisio F. da; Oliveira Neto, Almir; Pino, Eddy S.; Linardi, Marcelo; Spinace, Estevam V. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Programa de Celulas a Combustivel], e-mail: espinace@ipen.br, e-mail: dfsilva@ipen.br

    2006-07-01

    Carbon-supported Pt Ru (electrocatalysts PtRu/C nanoparticles) were prepared submitting a water/ethylene glycol mixture containing Pt(IV) and Ru(III) ions and the carbon support to electron beam irradiation. The PtRu/C electrocatalysts were characterized by EDX, XRD and cyclic voltammetry and tested for methanol electro-oxidation aiming fuel cell application. The obtained PtRu/C electrocatalysts were more active for methanol electro-oxidation than the commercial PtRu/C ETEK electrocatalyst at ambient temperature. (author)

  17. Ministerial Order of 16 October 1980 supplementing the Ministerial Order of 16 July 1980 providing for regulation of the treatment by ionizing radiation of foodstuffs for human or animal consumption

    International Nuclear Information System (INIS)

    1980-01-01

    This Order which supplements the Order of 16 July 1980 concerning the same subject adds further foodstuffs to the authorized list, together with the related licensing requirements and technical specifications. (NEA) [fr

  18. Mechanisms of current conduction in Pt/BaTiO3/Pt resistive switching cell

    International Nuclear Information System (INIS)

    Pan, R.K.; Zhang, T.J.; Wang, J.Y.; Wang, J.Z.; Wang, D.F.; Duan, M.G.

    2012-01-01

    The 80-nm-thickness BaTiO 3 (BT) thin film was prepared on the Pt/Ti/SiO 2 /Si substrate by the RF magnetron sputtering technique. The Pt/BT/Pt/Ti/SiO 2 /Si structure was investigated using X-ray diffraction and scanning electron microscopy. The current–voltage characteristic measurements were performed. The bipolar resistive switching behavior was found in the Pt/BT/Pt cell. The current–voltage curves were well fitted in different voltage regions at the high resistance state (HRS) and the low resistance state (LRS), respectively. The conduction mechanisms are concluded to be Ohmic conduction and Schottky emission at the LRS, while space-charge-limited conduction and Poole–Frenkel emission at the HRS. The electroforming and switching processes were explained in terms of the valence change mechanism, in which oxygen vacancies play a key role in forming conducting paths. - Highlights: ►Pt/BaTiO 3 /Pt cell shows the bipolar resistive switching behavior. ►The current–voltage curves were well fitted for different conduction mechanisms. ►The electroforming and switching processes were explained.

  19. CO tolerance of PdPt/C and PdPtRu/C anodes for PEMFC

    International Nuclear Information System (INIS)

    Garcia, Amanda C.; Paganin, Valdecir A.; Ticianelli, Edson A.

    2008-01-01

    The performance of H 2 /O 2 proton exchange membrane fuel cells (PEMFCs) fed with CO-contaminated hydrogen was investigated for anodes with PdPt/C and PdPtRu/C electrocatalysts. The physicochemical properties of the catalysts were characterized by energy dispersive X-ray (EDX) analyses, X-ray diffraction (XRD) and 'in situ' X-ray absorption near edge structure (XANES). Experiments were conducted in electrochemical half and single cells by cyclic voltammetry (CV) and I-V polarization measurements, while DEMS was employed to verify the formation of CO 2 at the PEMFC anode outlet. A quite high performance was achieved for the PEMFC fed with H 2 + 100 ppm CO with the PdPt/C and PdPtRu/C anodes containing 0.4 mg metal cm -2 , with the cell presenting potential losses below 200 mV at 1 A cm -2 , with respect to the system fed with pure H 2 . For the PdPt/C catalysts no CO 2 formation was seen at the PEMFC anode outlet, indicating that the CO tolerance is improved due to the existence of more free surface sites for H 2 electrooxidation, probably due to a lower Pd-CO interaction compared to pure Pd or Pt. For PdPtRu/C the CO tolerance may also have a contribution from the bifunctional mechanism, as shown by the presence of CO 2 in the PEMFC anode outlet

  20. Sintering of Pt nanoparticles via volatile PtO_2: Simulation and comparison with experiments

    International Nuclear Information System (INIS)

    Plessow, Philipp N.; Abild-Pedersen, Frank

    2016-01-01

    It is a longstanding question whether sintering of platinum under oxidizing conditions is mediated by surface migration of Pt species or through the gas phase, by PtO_2(g). Clearly, a rational approach to avoid sintering requires understanding the underlying mechanism. A basic theory for the simulation of ripening through the vapor phase has been derived by Wynblatt and Gjostein. Recent modeling efforts, however, have focused entirely on surface-mediated ripening. In this work, we explicitly model ripening through PtO_2(g) and study how oxygen pressure, temperature, and shape of the particle size distribution affect sintering. On the basis of the available data on α-quartz, adsorption of monomeric Pt species on the support is extremely weak and has therefore not been explicitly simulated, while this may be important for more strongly interacting supports. Our simulations clearly show that ripening through the gas phase is predicted to be relevant. Assuming clean Pt particles, sintering is generally overestimated. This can be remedied by explicitly including oxygen coverage effects that lower both surface free energies and the sticking coefficient of PtO_2(g). Additionally, mass-transport limitations in the gas phase may play a role. Using a parameterization that accounts for these effects, we can quantitatively reproduce a number of experiments from the literature, including pressure and temperature dependence. Lastly, this substantiates the hypothesis of ripening via PtO_2(g) as an alternative to surface-mediated ripening.

  1. Ion-irradiation induced chemical ordering of FePt and FePtAu nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Seetala, Naidu V. [Department of Physics, Grambling State University, RWE Jones Drive, Carver Hall 81, Grambling, LA 71245 (United States)]. E-mail: naidusv@gram.edu; Harrell, J.W. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Lawson, Jeremy [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Nikles, David E. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Williams, John R. [Department of Physics, Auburn University, Auburn, AL 36849 (United States); Isaacs-Smith, Tamara [Department of Physics, Auburn University, Auburn, AL 36849 (United States)

    2005-12-15

    We have studied the effect of ion-beam irradiation on reducing the ordering temperature of FePt and FePtAu nanoparticles. FePt and FePt(Au14%) 4 nm particles dispersed on a Si-substrate were irradiated by 300 keV Al-ions with a dose of 1 x 10{sup 16} ions/cm{sup 2} at 43 {sup o}C using a water-cooled flange in order to minimize the vacancy migration and voids formation within the collision cascades. Partial chemical ordering has been observed in as-irradiated particles with coercivity of 60-130 Oe. Post-irradiation annealing at 220 {sup o}C enhanced chemical ordering in FePt nanoparticles with coercivity of 3500 Oe, magnetic anisotropy of 1.5 x 10{sup 7} erg/cc, and thermal stability factor of 130. A much higher 375 {sup o}C post-irradiation annealing was required in FePtAu, presumably because Au atoms were trapped at Fe/Pt lattice sites at lower temperatures. As the annealing temperature increased, anomalous features in the magnetization reversal curves were observed that disappeared at higher annealing temperatures.

  2. Pt/Cr and Pt/Ni catalysts for oxygen reduction reaction: to alloy or not to alloy?

    Science.gov (United States)

    Escaño, Mary Clare; Gyenge, Elod; Nakanishi, Hiroshi; Kasai, Hideaki

    2011-04-01

    Bimetallic systems such as Pt-based alloys or non-alloys have exhibited interesting catalytic properties but pose a major challenge of not knowing a priori how the electronic and chemical properties will be modified relative to the parent metals. In this work, we present the origin of the changes in the reactivity of Pt/Cr and Pt/Ni catalysts, which have been of wide interest in fuel cell research. Using spin-polarized density functional theory calculations, we have shown that the modification of Pt surface reactivity in Pt/Ni is purely of geometric origin (strain). We have also found that the Pt-Ni bonding is very weak, which explains the observed instability of Pt-Ni catalysts under electrochemical measurements. On the other hand, Pt/Cr systems are governed by strong ligand effect (metal-metal interaction), which explains the experimentally observed reactivity dependence on the relative composition of the alloying components. The general characteristics of the potential energy curves for O2 dissociative adsorption on the bimetallic systems and the pure Pt clarify why the d-band center still works for Pt/Cr despite the strong Pt-Cr bonding and high spin polarization of Pt d-states. On the basis of the above clarifications, viable Pt-Cr and Pt-Ni structures, which involve nano-sized alloys and non-alloy bulk catalyst, which may strike higher than the currently observed oxidation reduction reaction activity are proposed.

  3. In vivo mutagenicity studies in rats mice and Chinese hamsters fed irradiated foodstuffs - chicken, fish, dates, pulses, mangoes and cocoa beans

    International Nuclear Information System (INIS)

    Renner, H.W.

    1982-01-01

    Three in vivo genetic toxicity tests were performed in rats, mice and Chinese hamsters to detect possible mutagenic effects of irradiated chicken, dried dates, fish, cocoa beans, pulses and mangoes. The tests employed were the micronucleus test and sister-chromatid exchange (SCE) test for irradiated and unirradiated samples of all foodstuffs listed, and the spermatogonia test, (including SCE technique) in mice for irradiated and unirradiated chicken, fish and dates only. In the case of cocoa beans, the mutagenicity tests were performed on an additional test group fed beans fumigated with ethylene oxide. The different mammalian species used for the various experiments are given below. None of the tests provided any evidence of mutagenicity induced by irradiation in any of the foodstuffs studied. Moreover, these tests are currently considered to be the most sensitive in vivo mutagenicity tests in mammals. (orig.)

  4. The public health threat of phthalate-tainted foodstuffs in Taiwan: the policies the government implemented and the lessons we learned.

    Science.gov (United States)

    Wu, Ming-Tsang; Wu, Chia-Fang; Wu, Jiunn-Ren; Chen, Bai-Hsiun; Chen, Eric K; Chao, Mei-Chyn; Liu, Ching-Kuan; Ho, Chi-Kung

    2012-09-01

    A major incident of phthalate-contaminated foodstuffs happened in Taiwan between April and July, 2011. Phthalates were deliberately added to foodstuffs as a substitute of emulsifier. We describe the course of this incident, government response and management of the crisis, and its future implications. Five major food categories, including sports drinks, fruit beverages, tea drinks, fruit jam or jelly, and health food or supplements in tablet or powder form, were contaminated with Di-(2-ethylhexyl)phthalate and/or Di-isononyl phthalate. At least 900 different food products were affected. Like the scandal of melamine-tainted infant formula, this event represents another large deliberate food contamination incident. It is important to be reminded that many governments in developing countries make rapid economic growth as their first priority, often compromising environmental safety and public health. The administration leaders need to find a balance between economic expansion and health and environmental safety. Copyright © 2012 Elsevier Ltd. All rights reserved.

  5. Pt-Ni and Pt-Co Catalyst Synthesis Route for Fuel Cell Applications

    Science.gov (United States)

    Firdosy, Samad A.; Ravi, Vilupanur A.; Valdez, Thomas I.; Kisor, Adam; Narayan, Sri R.

    2013-01-01

    Oxygen reduction reactions (ORRs) at the cathode are the rate-limiting step in fuel cell performance. The ORR is 100 times slower than the corresponding hydrogen oxidation at the anode. Speeding up the reaction at the cathode will improve fuel cell efficiency. The cathode material is generally Pt powder painted onto a substrate (e.g., graphite paper). Recent efforts in the fuel cell area have focused on replacing Pt with Pt-X alloys (where X = Co, Ni, Zr, etc.) in order to (a) reduce cost, and (b) increase ORR rates. One of these strategies is to increase ORR rates by reducing the powder size, which would result in an increase in the surface area, thereby facilitating faster reaction rates. In this work, a process has been developed that creates Pt-Ni or Pt-Co alloys that are finely divided (on the nano scale) and provide equivalent performance at lower Pt loadings. Lower Pt loadings will translate to lower cost. Precursor salts of the metals are dissolved in water and mixed. Next, the salt mixtures are dried on a hot plate. Finally, the dried salt mixture is heattreated in a furnace under flowing reducing gas. The catalyst powder is then used to fabricate a membrane electrode assembly (MEA) for electrochemical performance testing. The Pt- Co catalyst-based MEA showed comparable performance to an MEA fabri cated using a standard Pt black fuel cell catalyst. The main objective of this program has been to increase the overall efficiencies of fuel cell systems to support power for manned lunar bases. This work may also have an impact on terrestrial programs, possibly to support the effort to develop a carbon-free energy source. This catalyst can be used to fabricate high-efficiency fuel cell units that can be used in space as regenerative fuel cell systems, and terrestrially as primary fuel cells. Terrestrially, this technology will become increasingly important when transition to a hydrogen economy occurs.

  6. Prognosis of the application spices, nondecontamined and decontaminated by irradiation on the sanitary effect foodstuffs; Prognozowanie skutkow sanitarnych zastosowania przypraw niedekontaminowanych i dekontaminowanych radiacyjnie w artykulach spozywczych

    Energy Technology Data Exchange (ETDEWEB)

    Migdal, W; Owczarczyk, H B [Instytut Chemii I Techniki Jadrowej, Warsaw (Poland)

    2002-07-01

    Using the elements of prognostic microbiology it has been shown that under conditions conductive to growth of microorganisms, the foodstuff which contains contaminated spices is characterized by lower quality. It may be the risk for human health. The prognosis has been shown, the microbiological decontamination of spices by irradiation may be one of the elements of new system - Hazard Analysis Critical Control Point (HACCP). (author)

  7. Evaluation of possible health risks of heavy metals by consumption of foodstuffs available in the central market of Rajshahi City, Bangladesh.

    Science.gov (United States)

    Saha, Narottam; Zaman, M R

    2013-05-01

    Considering the human health risk due to the consumption of foodstuffs, the concentrations of heavy metals (lead, manganese, chromium, cadmium, and arsenic) are investigated in vegetables, fruits, and fish species collected from the central market (called Shaheb Bazar) of Rajshahi City, Bangladesh. The foodstuffs examined for metal constituents are the basis of human nutrition in the study area. The highest concentrations of Mn and As in vegetables (onion and pointed gourd, respectively), Cr and Cd in fruits (black berry and mango, respectively), and Pb in fish (catla) are recorded. Health risks associated with these heavy metals are evaluated due to dietary intake. Target hazard quotient (THQ) and hazard index (HI) are calculated to evaluate the non-carcinogenic health risk from individual and combined heavy metals. The THQ values for individual heavy metals are below 1, suggesting that people would not experience significant health risks if they ingest a single heavy metal from one kind of foodstuff (e.g., vegetables). However, consumption of several of the foodstuffs could lead a potential health risk to human population since HI value is higher than 1. The relative contributions of vegetables, fishes, and fruits to HI are 49.44, 39.07, and 11.53 %, respectively. Also, the relative contributions of Pb, Cd, As, Mn, and Cr to HI are 51.81, 35.55, 11.73, 0.85, and 0.02 %, respectively. The estimation shows that the carcinogenic risk of arsenic exceeds the accepted risk level of 1 × 10(-6). Thus, the carcinogenic risk of arsenic for consumers is a matter of concern.

  8. Effect of the applied magnetic field and the layer thickness on the magnon properties in bilayers Co/Pt and symmetrical trilayer Pt/Co/Pt

    International Nuclear Information System (INIS)

    Mehdioui, M.; Fahmi, A.; Lassri, H.; Fahoume, M.; Qachaou, A.

    2014-01-01

    We have studied the elementary magnetic excitations and their dynamics in multilayer Co(t Co)/Pt(t Pt) and Pt(t Pt)/Co(t Co)/Pt(t Pt) under an applied magnetic field. The Heisenberg hamiltonian used takes into account the magneto-crystalline and surface anisotropies, the exchange and dipolar interactions. The calculated excitation spectrum ε N (k) presents a structure with two sub-bands corresponding to the magnons of surface and volume respectively. The existence of a gap of creating these magnons is also highlighted. The lifetimes deduced from these gaps are in good agreement with the results of previous studies. The thermal evolution of the magnetization m z indicates that the system undergoes a dimensional crossover 3D–2D when the temperature increases. The calculated and measured magnetizations are compared and they are in good agreement. The exchange integral and critical temperature values deduced from these adjustments are in very good agreement with the results of previous works. - Highlights: • The magnons of surface and volume exist in Co/Pt and Pt/Co/Pt. • Samples undergo dimensional crossover (3D–2D) when T increases. • A good agreement is obtained between M(T) measured and calculated. • Deduced exchange integrals and critical temperature values are correct. • The magnetism of the sample is reduced by increasing t Pt or capping Co by two Pt layers

  9. Pt/MOx/SiO2, Pt/MOx/TiO2, and Pt/MOx/Al2O3 Catalysts for CO Oxidation

    Directory of Open Access Journals (Sweden)

    Hongmei Qin

    2015-04-01

    Full Text Available Conventional supported Pt catalysts have often been prepared by loading Pt onto commercial supports, such as SiO2, TiO2, Al2O3, and carbon. These catalysts usually have simple metal-support (i.e., Pt-SiO2 interfaces. To tune the catalytic performance of supported Pt catalysts, it is desirable to modify the metal-support interfaces by incorporating an oxide additive into the catalyst formula. Here we prepared three series of metal oxide-modified Pt catalysts (i.e., Pt/MOx/SiO2, Pt/MOx/TiO2, and Pt/MOx/Al2O3, where M = Al, Fe, Co, Cu, Zn, Ba, La for CO oxidation. Among them, Pt/CoOx/SiO2, Pt/CoOx/TiO2, and Pt/CoOx/Al2O3 showed the highest catalytic activities. Relevant samples were characterized by N2 adsorption-desorption, X-ray diffraction (XRD, transmission electron microscopy (TEM, H2 temperature-programmed reduction (H2-TPR, X-ray photoelectron spectroscopy (XPS, CO temperature-programmed desorption (CO-TPD, O2 temperature-programmed desorption (O2-TPD, and CO2 temperature-programmed desorption (CO2-TPD.

  10. The Pt site reactivity of the molecular graphs of Au6Pt isomers

    Science.gov (United States)

    Xu, Tianlv; Jenkins, Samantha; Xiao, Chen-Xia; Maza, Julio R.; Kirk, Steven R.

    2013-12-01

    Within the framework of the theory of atoms in molecules (QTAIM), in an exploratory study we propose a new measure of site reactivity equivalent to the atomic coordination number based purely on the electronic structure. It was found that the number of ring critical points (NNRCPs) positioned on the boundary of the atomic basin of the dopant (Pt) nucleus correlated very well with the relative zero point energy (ZPE) corrected energies. A weaker condition (i.e. than the number of associated bond paths) for the association of the dopant Pt nucleus with the Au6Pt molecular graph is found for NNRCP = 0.

  11. Angiotensin II clamp prevents the second step in renal apical NHE3 internalization during acute hypertension

    DEFF Research Database (Denmark)

    Leong, Patrick K K; Yang, Li E; McDonough, Alicia A

    2002-01-01

    Acute hypertension inhibits proximal tubule (PT) sodium reabsorption. The resultant increase in NaCl delivery to the macula densa suppresses renin release. We tested whether the sustained pressure-induced inhibition of PT sodium reabsorption requires a renin-mediated decrease in ANG II levels. Pl...

  12. Pt-graphene electrodes for dye-sensitized solar cells

    International Nuclear Information System (INIS)

    Hoshi, Hajime; Tanaka, Shumpei; Miyoshi, Takashi

    2014-01-01

    Highlights: • Graphene films with Pt nanoparticles were prepared from commercial graphene. • Pt consumption can be reduced by using Pt-graphene films. • The film showed improved catalytic activity for the reaction I 3 − /I − . • The film can be used as the counter electrode of dye-sensitized solar cells (DSSCs). • The performance of DSSC was superior to that of the Pt electrode. - Abstract: A simple paste method for fabricating graphene films with Pt nanoparticles was developed. First, graphene pastes with Pt nanoparticles were prepared from commercially available graphene. The resulting films of graphene nanoplatelet aggregates with Pt nanoparticles (Pt-GNA) contained Pt nanoparticles distributed over the entire three-dimensional surface of the GNA. Then, the catalytic activity for the I 3 − /I − redox reaction was evaluated by cyclic voltammetry. The GNA electrode exhibited higher activity than a graphene nanoplatelet electrode because of its higher effective surface area. Addition of Pt nanoparticles to the electrodes improved the catalytic activity. In particular, a large Faradaic current for the I 3 − /I − reaction was observed for the Pt-GNA electrode. As the counter electrodes of dye-sensitized solar cells (DSSCs), their performance was consistent with the cyclic voltammetry results. In particular, the DSSC performance of the Pt-GNA electrode was superior to that of the Pt electrodes commonly used in DSSCs

  13. Pt-graphene electrodes for dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Hoshi, Hajime, E-mail: hoshi@ed.tus.ac.jp; Tanaka, Shumpei; Miyoshi, Takashi

    2014-12-15

    Highlights: • Graphene films with Pt nanoparticles were prepared from commercial graphene. • Pt consumption can be reduced by using Pt-graphene films. • The film showed improved catalytic activity for the reaction I{sub 3}{sup −}/I{sup −}. • The film can be used as the counter electrode of dye-sensitized solar cells (DSSCs). • The performance of DSSC was superior to that of the Pt electrode. - Abstract: A simple paste method for fabricating graphene films with Pt nanoparticles was developed. First, graphene pastes with Pt nanoparticles were prepared from commercially available graphene. The resulting films of graphene nanoplatelet aggregates with Pt nanoparticles (Pt-GNA) contained Pt nanoparticles distributed over the entire three-dimensional surface of the GNA. Then, the catalytic activity for the I{sub 3}{sup −}/I{sup −} redox reaction was evaluated by cyclic voltammetry. The GNA electrode exhibited higher activity than a graphene nanoplatelet electrode because of its higher effective surface area. Addition of Pt nanoparticles to the electrodes improved the catalytic activity. In particular, a large Faradaic current for the I{sub 3}{sup −}/I{sup −} reaction was observed for the Pt-GNA electrode. As the counter electrodes of dye-sensitized solar cells (DSSCs), their performance was consistent with the cyclic voltammetry results. In particular, the DSSC performance of the Pt-GNA electrode was superior to that of the Pt electrodes commonly used in DSSCs.

  14. Density functional theory studies of the adsorption of ethylene and oxygen on Pt(111) and Pt3Sn(111)

    DEFF Research Database (Denmark)

    Watwe, R.M.; Cortright, R.D.; Mavrikakis, Manos

    2001-01-01

    Density functional theory, employing periodic slab calculations, was used to investigate the interactions of ethylene and oxygen with Pt(111) and Pt3Sn(111). The predicted energetics and structures of adsorbed species on Pt(111) are in good agreement with experimental data. The binding energies...... more than adsorption on two-fold and one-fold sites. Oxygen atoms bond as strongly on Pt3Sn(111) as on Pt(111), and these atoms prefer to adsorb near Sn atoms on the surface. The addition of Sn to Pt(111) leads to a surface heterogeneity, wherein ethylidyne species prefer to adsorb away from Sn atoms...

  15. The use of hogdahl convention k0 neutron activation analysis (NAA) standardization method and atomic absortion spectroscopy (ASS) for determination of toxic elements in foodstuffs

    International Nuclear Information System (INIS)

    Ahiamadie, H.

    2008-06-01

    Copper, cadmium, tin, chromium, arsenic, antimony, vanadium and mercury contents were determined in various foodstuffs (Mussa paradisiaca (plantains), Manihot esculentus (cassavas), Vantosoma sagittifolium (cocoyam). Vantosoma sagittifolium leaves (kontomire), Lycopersicum esculentus (tomatoes), Capsicum species (peppers), Solanum melongena (garden eggs), Nbelmoschus esculentus (okro), and Colocasia esculenta (kooko or taro)) produced in the Wassa West District, Ghana. These plants are the basis of human nutrition in the study area. These elements were determined using Hogdahl convention k 0 Instrumental Neutron Activation Analysis (NAA) Standardization Method and Atomic Absorption Spectroscopy (AAS). The elements in the various foodstuffs and their concentration ranges were Cu (16.87-180.06) mg/kg, As (2.68-9.84) µg/g, Cd (0.63-5.64) µg/g, Hg (0.01-67) ng/g, Cr (0.03-3.66) µg/g, Sb (1.1- 18.6) ng/g, Sn (3.4-58.4) ng/g, and V (12-99) ng/g. The study showed that there are high levels of toxic elements in the foodstuffs grown in the mining areas as compared to that of the non-mining area (i.e., control area). This could be attributed to gold mines pollution. Compared to the World Health Organization (WHO) permissible levels of toxic elements in foods, Cu, Cr and Hg were above the permissible levels whereas the concentrations of As, Cd. Sb, Sn and V fall within the permissible levels. (au)

  16. Advances in ultra-high performance liquid chromatography coupled to tandem mass spectrometry for sensitive detection of several food allergens in complex and processed foodstuffs.

    Science.gov (United States)

    Planque, M; Arnould, T; Dieu, M; Delahaut, P; Renard, P; Gillard, N

    2016-09-16

    Sensitive detection of food allergens is affected by food processing and foodstuff complexity. It is therefore a challenge to detect cross-contamination in food production that could endanger an allergic customer's life. Here we used ultra-high performance liquid chromatography coupled to tandem mass spectrometry for simultaneous detection of traces of milk (casein, whey protein), egg (yolk, white), soybean, and peanut allergens in different complex and/or heat-processed foodstuffs. The method is based on a single protocol (extraction, trypsin digestion, and purification) applicable to the different tested foodstuffs: chocolate, ice cream, tomato sauce, and processed cookies. The determined limits of quantitation, expressed in total milk, egg, peanut, or soy proteins (and not soluble proteins) per kilogram of food, are: 0.5mg/kg for milk (detection of caseins), 5mg/kg for milk (detection of whey), 2.5mg/kg for peanut, 5mg/kg for soy, 3.4mg/kg for egg (detection of egg white), and 30.8mg/kg for egg (detection of egg yolk). The main advantage is the ability of the method to detect four major food allergens simultaneously in processed and complex matrices with very high sensitivity and specificity. Copyright © 2016 Elsevier B.V. All rights reserved.

  17. Effects of radiation treatment on foodstuffs. A bibliographic survey. Part 3. Der Einfluss der Strahlenbehandlung auf Lebensmittel. Eine Literaturstudie. T. 3

    Energy Technology Data Exchange (ETDEWEB)

    Dehne, L; Boegl, W

    1980-01-01

    The purpose of this study is to discuss and compile methods and results of irradiation experiments carried out on 54 plant and animal foodstuffs in order to obtain a survey on chemical changes, in particular as regards the reduction of nutritional value and savoriness of irradiated foodstuffs. According to this task, microbiological aspects as well as an interpretation of the experimental results as to the physiology of nutrition and toxicology were not included. The results published by the authors of the original papers were compiled in a kind of dictionary which contains all relevant information such as radiation sources, irradiation conditions, investigation methods, results of chemical or organoleptical changes etc. The most important results were summarized in tables and can be found at the end of this study. Because of the abundance of existing literature the series 'Effects of radiation treatment on foodstuffs' will be continued in Part IV, and the final discussion of the results will be published separately after further data have been included.

  18. Estimation of annual effective dose from 226Ra and 228Ra due to consumption of foodstuffs by inhabitants of Ramsar city, Iran

    International Nuclear Information System (INIS)

    Asefi, M.; Fathivand, A. A.; Amidi, J.

    2005-01-01

    226 Ra and 228 Ra contents in foodstuffs of Ramsar which is a coastal city in the northern part of lran were determined by gamma spectrometry. Measurement results together with food consumption rates were used to estimate annual effective dose from 226 Ra and 228 Ra, due to consumption of food stuffs by inhabitants of Ramsar city. Materials and methods: a total of 33 samples from 11 different foodstuffs including root vegetables (beetroot), leafy vegetables (lettuce, parsley and spinach) and tea, meat, chicken, pea, broad bean, rice, and cheese were purchased from markets of Ramsar city and were analyzed for their 226 Ra and 228 Ra concentration. 1-8 kg of fresh weight sample was placed in Marinnelli beaker and sealed. The measurement of natural radioactivity levels as performed by gamma-spectrometry system, using a high purity germanium detector with 40% relative efficiency. Results: The highest concentrations of 226 Ra and 228 Ra were determined in tea samples with 1570 and 1140 mBq/kg, respectively, and the lowest concentration of 226 Ra was in pea, cheese, chicken, broad bean, and beetroot. Conclusion:The maximum estimated annual effective dose from 226 Ra and 228 Ra due to consumption, foodstuffs were determined to be 19.22 and 0.71 mSv from rice and meat samples respectively, where as, minimum estimated annual effective dose for 226 Ra was 0.017, 0.018 and 0.019 mSv from beetroot, cheese and pea samples respectively

  19. Interplay between autophagy and apoptosis in lead(II)-induced cytotoxicity of primary rat proximal tubular cells.

    Science.gov (United States)

    Chu, Bing-Xin; Fan, Rui-Feng; Lin, Shu-Qian; Yang, Du-Bao; Wang, Zhen-Yong; Wang, Lin

    2018-05-01

    Autophagy and apoptosis are two different biological processes that determine cell fates. We previously reported that autophagy inhibition and apoptosis induction are involved in lead(II)-induced cytotoxicity in primary rat proximal tubular (rPT) cells, but the interplay between them remains to be elucidated. Firstly, data showed that lead(II)-induced elevation of LC3-II protein levels can be significantly modulated by 3-methyladenine or rapamycin; moreover, protein levels of Autophagy-related protein 5 (Atg5) and Beclin-1 were markedly up-regulated by lead(II) treatment, demonstrating that lead(II) could promote the autophagosomes formation in rPT cells. Next, we applied three pharmacological agents and genetic method targeting the early stage of autophagy to validate that enhancement of autophagosomes formation can inhibit lead(II)-induced apoptotic cell death in rPT cells. Simultaneously, lead(II) inhibited the autophagic degradation of rPT cells, while the addition of autophagic degradation inhibitor bafilomycin A1 aggravated lead(II)-induced apoptotic death in rPT cells. Collectively, this study provided us a good model to know about the dynamic process of lead(II)-induced autophagy in rPT cells, and the interplay between autophagy and apoptosis highlights a new sight into the mechanism of lead(II)-induced nephrotoxicity. Copyright © 2018. Published by Elsevier Inc.

  20. Television advertising of foodstuffs potentially detrimental to oral health--a content analysis and comparison of children's and primetime broadcasts.

    Science.gov (United States)

    Chestnutt, I G; Ashraf, F J

    2002-06-01

    The study aimed to examine the nature, content and duration of advertisements broadcast during children's television; determine the proportion of advertisements promoting food; identify the potential of the food advertised to be detrimental to oral health; and to compare the nature and content of advertisements aimed at children with those transmitted during evening 'primetime' television. Children's and primetime television, broadcast on a main independent terrestrial channel in South Wales were video recorded, 237 and 42 hours being analysed in total. Analysis of the recording resulted in a total of 3,236 commercials, of which 2,345 were broadcast during children's television and 891 in primetime. During children's TV, 62.5% of advertising time was devoted to foodstuffs, significantly greater (Padvertising foods during primetime. Of the time spent advertising foods, during children's television 73.4% was devoted to products deemed potentially detrimental to oral health (primarily high in sugar), compared to 18.6% similarly categorised during evening television. Commercials for products which have the potential to adversely affect oral health constitute a large proportion of advertising time during children's television. Current codes of the Independent Television Commission governing advertising directed at children should be reviewed.