Earth history. Low mid-Proterozoic atmospheric oxygen levels and the delayed rise of animals.

Science.gov (United States)

Planavsky, Noah J; Reinhard, Christopher T; Wang, Xiangli; Thomson, Danielle; McGoldrick, Peter; Rainbird, Robert H; Johnson, Thomas; Fischer, Woodward W; Lyons, Timothy W

2014-10-31

The oxygenation of Earth's surface fundamentally altered global biogeochemical cycles and ultimately paved the way for the rise of metazoans at the end of the Proterozoic. However, current estimates for atmospheric oxygen (O2) levels during the billion years leading up to this time vary widely. On the basis of chromium (Cr) isotope data from a suite of Proterozoic sediments from China, Australia, and North America, interpreted in the context of data from similar depositional environments from Phanerozoic time, we find evidence for inhibited oxidation of Cr at Earth's surface in the mid-Proterozoic (1.8 to 0.8 billion years ago). These data suggest that atmospheric O2 levels were at most 0.1% of present atmospheric levels. Direct evidence for such low O2 concentrations in the Proterozoic helps explain the late emergence and diversification of metazoans. Copyright © 2014, American Association for the Advancement of Science.

A proterozoic tectonic model for northern Australia and its economic implications

International Nuclear Information System (INIS)

Rossiter, A.G.; Ferguson, J.

1980-01-01

It is argued that at the end of Archaean time the Australian continent was confined to the area now occupied by the Yilgarn, Pilbara, Gawler, and Musgrave Blocks, and the southern part of the Arunta Block. During the Early Proterozoic, sedimentary and volcanic rocks were laid down in an extensive depositional zone trending roughly east-west along the northern margin of the Archaean continent. Copper and gold mineralization, commonly showing stratigraphic control, is widespread in this belt. Following deformation and metamorphism of the Early Proterozoic rocks, felsic and mafic igneous activity, and accumulation of platform sediments on the newly stabilized crust, a predominantly north-south depositional zone developed along the eastern margin of the continent during the Middle Proterozoic. Lead and zinc assume much more importance in the mineral deposits of this belt. It is postulated that the present positions of rocks of the Pine Creek and Georgetown regions are due to horizontal displacements of several hundred kilometres along major fault zones. Apparent rifting of these blocks away from palaeo-continental margins may be related to the occurrence of uraniferous granitic rocks and uranium mineralization within them via a mantle plume mechanism. Although current data are limited, tectonic environments suggested for Proterozoic mafic igneous rocks of northern Australia by their geochemistry are compatible with the geological settings of these rocks and with the tectonic model put forward. (author)

The proterozoic Georgetown Province - a Broken Hill analogue

International Nuclear Information System (INIS)

Carr, G.R.

2000-01-01

Collaborative work between CSIRO and AGSO has resulted in the development of a Pb isotope model that attempts to place relatively precise (∼5 Ma) age constraints on Proterozoic mineralisation in the Mount Isa and McArthur River terrains (Sun et al., 1994). Although this model was developed for sediment hosted mineralisation in low grade metamorphic terrains, the CSIRO-AGSO model ages for other mineralisation in high-grade terrains such as Broken Hill appear to be consistent with the U-Pb zircon ages obtained for the high-grade host sequences. Without independent evidence that the model is applicable to such terrains, the observations cannot be used to indicate the age of the mineralisation. Lead isotope data obtained on potassium feldspar separates from five felsic intrusive samples in the Georgetown terrain show a wide range of Pb isotope ratios. The lowest 206 Pb/ 204 Pb analyses are considered to approximate to the Proterozoic initial ratio and indicate a model age of ∼1510 Ma based on the CSIRO-AGSO model. This age is 45 Ma younger than the crystallisation age of the granite, but must be considered a minimum as the initial 206 Pb/ 204 Pb ratio may well prove to be lower after more comprehensive analysis. Sulfide mineralisation within the Einasleigh Metamorphics has a wide range of 206 Pb/ 204 Pb ratios that lie between this granite value and the relatively homogeneous population from Railway Flat. The Railway Flat data are very similar to values for Broken Hill and also the Broken Hill-type Pegmont mineralisation in the Mount Isa Eastern Succession. These data all have significantly lower 207 Pb/ 204 Pb ratios than the CSIRO-AGSO model, suggesting a significantly different source rock environment for this style of mineralisation from that for the sediment hosted deposits

Geochemistry and petrogenesis of Proterozoic granitic rocks from ...

Indian Academy of Sciences (India)

Geochemistry and petrogenesis of Proterozoic granitic ... This study presents the geochemical characteristics of granitic rocks located on the northern ... Frost and Frost 2013). ...... King P L, White A J R, Chappell B W and Allen C M 1997.

Instability of the southern Canadian Shield during the late Proterozoic

Science.gov (United States)

McDannell, Kalin T.; Zeitler, Peter K.; Schneider, David A.

2018-05-01

magmatic underplating that thickened the crust, driving uplift and erosion. The timing of this underplating coincides with Mid-Continent extension, Grenville orogenesis, and assembly of the supercontinent Rodinia. 40Ar/39Ar MDD data demonstrate that this technique can be successfully applied to older rocks and fill in a large observational gap. These data also raise questions about the evolution of cratons during the Proterozoic and the nature of cratonic stability across deep time.

Journal of Earth System Science | Indian Academy of Sciences

Indian Academy of Sciences (India)

Climbing ripple structure and associated storm-lamination from a Proterozoic carbonate platform succession: Their environmental and petrogenetic significance · Asru K Chaudhuri · More Details Abstract Fulltext PDF. The Mesoproterozoic Pandikunta Limestone, a shallow water carbonate platform succession in the ...

Evidences of a tangential proterozoic tectonic from Quadrilatero Ferrifero, Minas Gerais state, Brazil

International Nuclear Information System (INIS)

Belo de Oliveira, O.A.; Teixeira, W.

1990-01-01

Radiometric Rb/Sr ages of 2,1 - 2,2 Ga determined for milonites of the Caete complex, combined with tectonic relationships among the sequences of the Espinhaco, Minas and Rio das Velhas Supergroups, suggest that the thrust and fold tectonic style observed around Caete results from two deformation episodes, with similar vergence and style. The parautochthonous domain in Caete Region has been affected by both deformations episodes (Early Proterozoic and Upper Proterozoic) whereas the allochthonous domain apparently was affected only by the younger episode. A preliminary analysis of the Quadrilatero Ferrifero as a whole, considering these two major deformation episodes, is compatible, at least in part, with the large scale features observed in maps. In an effort to understand the tectonic framework of Q.F. an speculation is made on av evolutive model, considering also the existence of two district extensional events (Late Archean and Middle Proterozoic), respectively related to the deposition of Minas and Espinhaco Supergroups in a rift/aulacogen systems. (author)

Proterozoic rifting and major unconformities in Rajasthan, and their implications for uranium mineralisation

International Nuclear Information System (INIS)

Sinha-Roy, S.

2004-01-01

Evolution of the Precambrian terrain in Rajasthan has taken place via crustal consolidation of the basement at ca. 2.9 Ga, its cratonisation at ca. 2.5 Ga, through protracted tectonostratigraphic evolution of the Proterozoic cover sequences, following repeated rifting and Wilson cycles in the Aravalli and Delhi foldbelts. Consequently, the Proterozoic rift basins are characterised by growth faults and pull-aparts, and multitier volcanose dimentary sequences that contain a number of unconformities and stratigraphic breaks. The Archaean basement of the Mewar terrain that witnessed end-Archaean K-magmatism and ductile shearing, led to the creation of a possible uranium province, namely uranium enriched basement. This province acted as the source of remobilised uranium and its concentration at suitable multilevel structural and stratigraphic traps within the Proterozoic rift basins to give rise to unconformity-related syngenetic uranium mineralisation. Late Neoproterozoic to Pan-African tectonothermal reworking of the basement rocks produced fracture zones and caused Na-metasomatism giving rise to albitite-related uranium mineralisation. Based on an analysis of Proterozoic rift kinematics and lithofacies characteristics, five possible uranium-enriched stratigraphic horizons have been identified in the Aravalli and its equivalent sequences as well as in the North Delhi foldbelt sequences. From a regional synthesis, ten possible uranium metallogenic events, spanning ca. 2.5-0.5 Ga, are recognised in Rajasthan. These uranium events have predictive value for delineation of target areas for exploration. (author)

Proterozoic structure, cambrian rifting, and younger faulting as revealed by a regional seismic reflection network in the Southern Illinois Basin

Science.gov (United States)

Potter, C.J.; Drahovzal, James A.; Sargent, M.L.; McBride, J.H.

1997-01-01

Four high-quality seismic reflection profiles through the southern Illinois Basin, totaling 245 km in length, provide an excellent regional subsurface stratigraphic and structural framework for evaluation of seismic risk, hydrocarbon occurrence, and other regional geologic studies. These data provide extensive subsurface information on the geometry of the intersection of the Cambrian Reelfoot and Rough Creek rifts, on extensive Proterozoic reflection sequences, and on structures (including the Fluorspar Area Fault Complex and Hicks Dome) that underlie a transitional area between the well-defined New Madrid seismic zone (to the southwest) and a more diffuse area of seismicity in the southern Illinois Basin. Our principal interpretations from these data are listed here in order of geologic age, from oldest to youngest: 1. Prominent Proterozoic layering, possibly equivalent to Proterozoic (???1 Ga) Middle Run Formation clastic strata and underlying (1.3-1.5 Ga) volcanic rocks of the East Continent rift basin, has been strongly deformed, probably as part of the Grenville foreland fold and thrust belt. 2. A well-defined angular unconformity is seen in many places between Proterozoic and Cambrian strata; a post-Grenville Proterozoic sequence is also apparent locally, directly beneath the base of the Cambrian. 3. We infer a major reversal in Cambrian rift polarity (accommodation zone) in the Rough Creek Graben in western Kentucky. 4. Seismic facies analysis suggests the presence of basin-floor fan complexes at and near the base of the Cambrian interval and within parts of a Proterozoic post-Grenville sequence in several parts of the Rough Creek Graben. 5. There is an abrupt pinchout of the Mount Simon Sandstone against crystalline basement beneath the Dale Dome (near the Texaco no. 1 Cuppy well, Hamilton County) in southeastern Illinois, and a more gradual Mount Simon pinchout to the southeast. 6. Where crossed by the seismic reflection line in southeast Illinois, some

Carbon, nitrogen, and sulfur geochemistry of Archean and Proterozoic shales from the Kaapvaal Craton, South Africa

Science.gov (United States)

Watanabe, Yumiko; Naraoka, Hiroshi; Wronkiewicz, David J.; Condie, Kent C.; Ohmoto, Hiroshi

1997-08-01

1.5 to less than 0.3. Based on the relationships among sulfide-S contents, organic-C contents, and δ 13C org values, four different types of depositional environments are identified for the Archean and early Proterozoic shales in the Kaapvaal Craton: (I) euxinic marine basins, characterized by normal marine organisms with δ 13C org= -33 ± 3%‰ (II) near-shore, oxic marine environment, characterized by normal marine organisms with δ 13C org = -31 ± 3%‰; (III) hypersaline, low-sulfate lakes, characterized by organisms with δ 13C org= -2 ± 3%‰; and (IV) euxinic, marine basins which supported the activity of methanogenic and methanotrophic bacteria and accumulated organic matter with δ 13C org= -43 ± 3%‰. In contrast to the currently popular model positing a global anoxic ocean prior to ˜2.2 Ga (e.g., Des Marais et al, 1992; Hayes, 1994; Logan et al., 1995), this study suggests that the development of anoxic basins, which accumulated Group II and IV sediments, occurred only regionally and episodically during the period between 3.0 Ga and 2.1 Ga. This further suggests that the normal ocean has been oxic since at least ˜3.0 Ga. Diversifications of environments, as well as of biological species, had already occurred ˜3.0 Ga. The carbon isotope mass balance calculation suggests that the removal rates of organic C and carbonate C from the ocean and the weathering rates of organic C and carbonate C on the continents during the 3.0-2.1 Ga period were basically the same as those in the Phanerozoic era. This would have been possible only if the atmospheric P O 2 level had been basically constant since at least 3.0 Ga. The results of this study, therefore, add to a growing list of evidence that the atmosphere has been oxic (i.e., P O 2 > 1%PAL) since at least 3.0 Ga. The list of evidence includes the sulfur isotope data on Archean sedimentary rocks ( Ohmoto and Felder, 1987; Ohmoto et al., 1993), the Fe 3+Ti ratios of paleosols ( Ohmoto, 1996), and the

Folds in multilayered rocks of Proterozoic age, Rajasthan, India

Indian Academy of Sciences (India)

R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

Johnson and Johnson 2002 etc) shows that the fold shape modification may be brought about by buckling and flattening operating simultaneously throughout the development of fold. In the present paper a series of F1 folds devel- oped in slates with interlayered alternations with quartzite of Proterozoic age and unaffected ...

Examples that illustrate sedimentological aspects of the proterozoic placer model on the Kaap-Vaal Craton, Witwatersrand, South Africa

International Nuclear Information System (INIS)

Minter, W.E.L.

1981-01-01

In the fluvial-fan model of Proterozoic placers in South Africa, mid-fan and fanbase environments are illustrated by the Ventersdorp Contact Reef, proximal braided-belt environments by the B Reef, distal braided-belt environments by the Vaal Reef, and deltaiclike environments by sheets, ribbons, and pods at the extremities of the South and Basal Reefs. The nature of distribution of gold and uranium in these various environments has been evaluated and the knowledge successfully applied by the author to the valuation and practical mining of the reefs since 1965

Controls on Atmospheric O2: The Anoxic Archean and the Suboxic Proterozoic

Science.gov (United States)

Kasting, J. F.

2015-12-01

Geochemists have now reached consensus that the Archean atmosphere was mostly anoxic, that a Great Oxidation Event (GOE) occurred at around 2.5 Ga, and that the ensuing Proterozoic atmosphere was consistently oxidized [1,2]. Evidence for this broad-scale change in atmospheric composition comes from a variety of sources, most importantly from multiple sulfur isotopes [3,4]. The details of both the Archean and Proterozoic environments remain controversial, however, as does the underlying cause of the GOE. Evidence of 'whiffs' of oxygen during the Archean [5] now extend back as far as 3.0 Ga, based on Cr isotopes [6]. This suggests that O2 was being produced by cyanobacteria well before the GOE and that the timing of this event may have been determined by secular changes in O2 sinks. Catling et al. [7] emphasized escape of hydrogen to space, coupled with progressive oxidation of the continents and a concomitant decrease in the flux of reduced gases from metamorphism. But hydrogen produced by serpentinization of seafloor could also have been a controlling factor [8]. Higher mantle temperatures during the Archean should have resulted in thicker, more mafic seafloor and higher H2 production; decreasing mantle temperatures during the Proterozoic should have led to seafloor more like that of today and a corresponding decrease in H2 production, perhaps by enough to trigger the GOE. Once the atmosphere became generally oxidizing, it apparently remained that way during the rest of Earth's history. But O2 levels in the mid-Proterozoic could have been as low at 10-3 times the Present Atmospheric Level (PAL) [9]. The evidence, once again, is based on Cr isotopes. Possible mechanisms for maintaining such a 'suboxic' Proterozoic atmosphere will be discussed. Refs: 1. H. D. Holland, Geochim. Cosmochim. Acta 66, 3811 (2002). 2. H. D. Holland, Philosophical Transactions of the Royal Society B-Biological Sciences 361, 903 (Jun 29, 2006). 3. J. Farquhar, H. Bao, M. Thiemans, Science

A model for the oceanic mass balance of rhenium and implications for the extent of Proterozoic ocean anoxia

Science.gov (United States)

Sheen, Alex I.; Kendall, Brian; Reinhard, Christopher T.; Creaser, Robert A.; Lyons, Timothy W.; Bekker, Andrey; Poulton, Simon W.; Anbar, Ariel D.

2018-04-01

Emerging geochemical evidence suggests that the atmosphere-ocean system underwent a significant decrease in O2 content following the Great Oxidation Event (GOE), leading to a mid-Proterozoic ocean (ca. 2.0-0.8 Ga) with oxygenated surface waters and predominantly anoxic deep waters. The extent of mid-Proterozoic seafloor anoxia has been recently estimated using mass-balance models based on molybdenum (Mo), uranium (U), and chromium (Cr) enrichments in organic-rich mudrocks (ORM). Here, we use a temporal compilation of concentrations for the redox-sensitive trace metal rhenium (Re) in ORM to provide an independent constraint on the global extent of mid-Proterozoic ocean anoxia and as a tool for more generally exploring how the marine geochemical cycle of Re has changed through time. The compilation reveals that mid-Proterozoic ORM are dominated by low Re concentrations that overall are only mildly higher than those of Archean ORM and significantly lower than many ORM deposited during the ca. 2.22-2.06 Ga Lomagundi Event and during the Phanerozoic Eon. These temporal trends are consistent with a decrease in the oceanic Re inventory in response to an expansion of anoxia after an interval of increased oxygenation during the Lomagundi Event. Mass-balance modeling of the marine Re geochemical cycle indicates that the mid-Proterozoic ORM with low Re enrichments are consistent with extensive seafloor anoxia. Beyond this agreement, these new data bring added value because Re, like the other metals, responds generally to low-oxygen conditions but has its own distinct sensitivity to the varying environmental controls. Thus, we can broaden our capacity to infer nuanced spatiotemporal patterns in ancient redox landscapes. For example, despite the still small number of data, some mid-Proterozoic ORM units have higher Re enrichments that may reflect a larger oceanic Re inventory during transient episodes of ocean oxygenation. An improved understanding of the modern oceanic Re

Late Proterozoic glacially controlled shelf sequences in western Mali (west Africa)

Science.gov (United States)

Deynoux, M.; Prousti, J. N.; Simon, B.

The Late Proterozoic deposits of the Bakoye Group (500 m) in western Mali constitute a remarkable example of a glacially influenced sedimentary record on an epicratonic platform. They are composed of alternating marine and continental formations which represent accumulation in a basin located in the vicinity of upland areas covered by ice sheets. One of these formations (the Ba4 Formation), which is the focus of this study, is composed of three major units. The basal Unit 1 is made up of carbonaceous coarse to fine grained sandstones which are organized in fining upward sequences and which comprise lenticular diamictite intercalations. This Unit is considered to represent the fore slope gravity flows of a subaqueous ice-cootact fan fed by meltwater streams (≪glacioturbidites≫). Unit 2 is made up of coarse to fine grained sandstones in a highly variable association of facies. This Unit is characterized by the abundance of wave ripples associated with convolute beddings. planar or wavy beddings and tabular or hummocky crossbeddings in a general shallowing upward trend. It also comprises evidence of gravity processes including debris flows and large slumped sandstone bodies. Unit 2 represents the progressive filling of the Ba4 basin and reflects the combined effect of glacially induced eustatism and isostacy during a phase of glacial retreat. The basal part of Unit 3 is made up of a succession (a few meters thick) of conglomerates, diamictites, sandstones, siltstones or carbonates lying on an erosional unconformity marked by periglacial frost wedges. The upper part of Unit 3 is thicker (100-150 m) and onlaps on these basal facies with a succession of sandstone bars exhibiting swaley and hummocky crossbeddings, large cut and fill structures, and planar laminations. Unit 3 is strongly transgressive, the lower shoreface and backshore deposits include algal mats and are onlapped by sand ridges emplaced in a high energy upper to middle shoreface environment. Overall

Uranium exploration target selection for proterozoic iron oxide/breccia complex type deposits in India

International Nuclear Information System (INIS)

Dwivedy, K.K.; Sinha, K.K.

1997-01-01

Multimetal iron oxide/breccia complex (IOBC) type deposits exemplified by Olympic Dam in Australia, fall under low grade, large tonnage deposits. A multidisciplinary integrated exploration programme consisting of airborne surveys, ground geological surveys, geophysical and geochemical investigations and exploratory drilling, supported adequately by the state of the art analytical facilities, data processing using various software and digital image processing has shown moderate success in the identification of target areas for this type of deposits in the Proterozoic terrains of India. Intracratonic, anorogenic, continental rift to continental margin environment have been identified in a very wide spectrum of rock associations. The genesis and evolution of such associations during the Middle Proterozoic period have been reviewed and applied for target selection in the (i) Son-Narmada rift valley zone; (ii) areas covered by Dongargarh Supergroup of rocks in Madhya Pradesh; (iii) areas exposing ferruginous breccia in the western part of the Singhbhum Shear Zone (SSZ) around Lotapahar; (iv) Siang Group of rocks in Arunachal Pradesh; (v) Crystalline rocks of Garo Hills around Anek; and (vi) Chhotanagpur Gneissic complex in the Bahia-Ulatutoli tract of Ranchi Plateau. Of theses six areas, the Son-Narmada rift area appears to be the most promising area for IOBC type deposits. Considering occurrences of the uranium anomalies near Meraraich, Kundabhati, Naktu and Kudar and positive favourability criteria observed in a wide variety of rocks spatially related to the rifts and shears, certain sectors in Son-Narmada rift zone have been identified as promising for intense subsurface exploration. 20 refs, 4 figs, 1 tab

The Amazon-Laurentian connection as viewed from the Middle Proterozoic rocks in the central Andes, western Bolivia and northern Chile

Science.gov (United States)

Tosdal, R.M.

1996-01-01

Middle Proterozoic rocks underlying the Andes in western Bolivia, western Argentina, and northern Chile and Early Proterozoic rocks of the Arequipa massif in southern Peru?? from the Arequipa-Antofalla craton. These rocks are discontinuously exposed beneath Mesozoic and Cenozoic rocks, but abundant crystalline clasts in Tertiary sedimentary rocks in the western altiplano allow indirect samples of the craton. Near Berenguela, western Bolivia, the Oligocene and Miocene Mauri Formation contains boulders of granodiorite augen gneiss (1171??20 Ma and 1158??12 Ma; U-Pb zircon), quartzose gneiss and granofels that are inferred to have arkosic protoliths (1100 Ma source region; U-Pb zircon), quartzofeldspathic and mafic orthogneisses that have amphibolite- and granulite-facies metamorphic mineral assemblages (???1080 Ma metamorphism; U-Pb zircon), and undeformed granitic rocks of Phanerozoic(?) age. The Middle Proterozoic crystalline rocks from Berenguela and elsewhere in western Bolivia and from the Middle Proterozoic Bele??n Schist in northern Chile generally have present-day low 206Pb/204Pb ( 15.57), and elevated 208Pb/204Pb (37.2 to 50.7) indicative of high time-averaged Th/U values. The Middle Proterozoic rocks in general have higher presentday 206Pb/204Pb values than those of the Early Proterozoic rocks of the Arequipa massif (206Pb/204Pb between 16.1 and 17.1) but lower than rocks of the southern Arequipa-Antofalla craton (206Pb/204Pb> 18.5), a difference inferred to reflect Grenvillian granulite metamorphism. The Pb isotopic compositions for the various Proterozoic rocks lie on common Pb isotopic growth curves, implying that Pb incorporated in rocks composing the Arequipa-Antofalla craton was extracted from a similar evolving Pb isotopic reservoir. Evidently, the craton has been a coherent terrane since the Middle Proterozoic. Moreover, the Pb isotopic compositions for the Arequipa-Antofalla craton overlap those of the Amazon craton, thereby supporting a link

Biogeochemical and micropaleontological study of black chert, Sete Lagoas Formation, Bambui Group (Late Proterozoic), Sao Gabriel (GO), Brazil

International Nuclear Information System (INIS)

Subacius, S.M.R.

1985-01-01

The biogeochemical study of amorphous and structured organic matter (OM) in two samples of thinly laminated black cherts (SG-1 and SG-2) from Sete Lagoas Formation, State of Goias, Brazil, is presented. The spectra analysis of infra-red, electron paramagnetic resonance and isotope ratio of C-12 and C-13 shown that: the amorphous OM consists of a soluble fraction (SF) and a insoluble fraction (Kerogen), which only the latter is syngenetic; the allochthonous SF comes from several sources, mainly from Phanerozoic sediments and soil contamination; the SG-1 and SG-2 Kerogens have δ 13 C values (-27.2 per mille and - 29.2 per mille respectively), which suggest OM photosynthetized and submitted to a mild thermal hystory; although the preserved microbiota is dominated by allochthonous elements (colonial fragments) and planktonic forms, both Kerogens were derived for the most part from photo-autotrophic benthonic communities, probably responsible for the lamination in the original carbonate rock, both SG-1 and SG-2 Kerogens exhibits O/C and H/C ratios comparable to Proterozoic humic Kerogens (type IV); the preserved microflora represents a microbial community of the chert-algae facies typical of the Middle and upper Proterozoic; and the occurence of rare acritarchs (Kildinella spp.) in the microflora is biostratigraphically significant in that it suggests a Late Riphean or Vendian age (950-570 m.y.) for the Sete Lagoas Formation. (Author) [pt

Geology of uranium vein deposits (including Schwartzwalder Mine) in Proterozoic metamorphic rocks, Front Range, Colorado

International Nuclear Information System (INIS)

Voto, R.H. de; Paschis, J.A.

1980-01-01

The Schwartzwalder uranium deposit is one of many uranium vein occurrences in the Lower Proterozoic metamorphic rocks of the Front Range, Colorado. The principal veins of significant uranium content occur marginal to the Colorado Mineral Belt; are localized by structural dilation zones, vein junctions, fault deflections or branching; and occur dominantly within or at the contact of certain preferred metamorphic-stratigraphic units, particularly the siliceous, garnetiferous gneisses, where these rock units are broken by faults and fractures associated with the north-northwest-trending throughgoing faults. Uranium at the Schwartzwalder mine occurs primarily as open-space brecciated vein filling along the steeply west-dipping Illinois vein and numerous east-dipping subsidiary veins where they cut preferred metamorphic host rocks that are tightly folded. Uraninite occurs with molybdenite, adularia, jordisite, ankerite, pyrite, base-metal sulphides, and calcite in vein-filling paragenetic sequence. Minor wall-rock alteration is mainly hematite alteration and bleaching. Vertical relief on the developed ore deposit is 900 metres and still open-ended at depth. No vertical zonation of alteration, vein mineralogy, density of the subsidiary veins, or ore grade has been detected. The Schwartzwalder uranium deposit is of substantial tonnage (greater than 10,000 metric tons of U 3 O 8 ) and grade (averaging 0.57% U 3 O 8 ). Structural mapping shows that the Illinois vein-fault is a Proterozoic structure. Discordant Proterozoic (suggested) and Laramide dates have been obtained from Schwartzwalder ore. The data suggest, therefore, a Proterozoic ancestry of this heretofore presumed Laramide (Late Cretaceous-Early Tertiary) hydrothermal uranium deposit. The authors suggest a polygenetic model for the origin of the Schwartzwalder uranium deposit

Arachania, A neo proterozoic magmatic arc and its fragments in south America and Africa

International Nuclear Information System (INIS)

Gaucher, C.; Bossi, J.; Frimmel, H.

2010-01-01

The name Arachania has been recently proposed for the block that comprises the Cuchilla Dionisio-Pelotas, Marmora, Tygerberg and correlative terranes at both sides of the south Atlantic, which is considered a fragment of the Kalahari Craton that a later stage (660-550 Ma) evolved into an active margin. The block played a key role in the amalgamation of southwestern Gondwana, which has been only recently recognized. Arachania is composed of three different lithotectonic elements: (1) a high-grade metamorphic basement of Namaquan age with evidence of older, Eburnean components that crop out mainly in southern Uruguay; (2) a voluminous calc alkaline granitic batholith s mostly within the 660-550 Ma age range, representing the roots of a Neo proterozoic magmatic arc; and (3) deep-water, turbiditic, Ediacaran sedimentary successions marking the eastern border of Arachania, often associated with mafic to ultramafic rocks

How Strong is the Case for Proterozoic Low-Latitude Glaciation?

Science.gov (United States)

Evans, D. A.

2004-05-01

The most recent global compilations of paleomagnetic depositional latitudes for Proterozoic glaciogenic formations indicate a dominant mode near the paleo-equator (Evans 2000 AJS; Evans 2003 Tectonophysics). This result would therefore support either the snowball Earth or the large-obliquity hypotheses for Precambrian ice ages, but would reject the uniformitarian comparison to polar-temperate-restricted Phanerozoic glaciogenic deposits. The most reliable low-latitude results come from the Australian Marinoan succession, but a recent summary of these units has suggested that a glaciogenic origin is not yet demonstrated (Eyles and Januszczak 2004 Earth-Sci Reviews). It becomes useful, then, to review the global evidence for Proterozoic low-latitude glaciation. Eyles and Januszczak (ibid.) identified 13 Neoproterozoic deposits with "demonstrated" glacial influence. Among these, poor age constraints and lack of paleomagnetic data prohibit estimation of depositional paleolatitudes for the Fiq, Sturtian, Vreeland, Taoudeni, East Greenland, Port Askaig, and Zhengmuguan units. Moderate paleolatitudes are reasonably well supported for the South China, Gaskiers, Smalfjord, and Moelv units. Among the three remaining units, the Rapitan Group can be assigned a near-equatorial paleolatitude indirectly through use of the Galeros and Franklin-Natkusiak paleomagnetic results, as long as the Rapitan age lies within 750-720 Ma as generally expected. The Moonlight Valley Formation in northern Australia may be assigned a tropical paleolatitude according to high-quality paleomagnetic results from compellingly correlated Marinoan strata in southern Australia. Those strata, including the famous Elatina Formation, have yielded a robust paleomagnetic signature that is commonly interpreted to imply frigid climate (manifest in part by frost-wedge polygons) at near-equatorial latitudes. Concerns that the Neoproterozoic geomagnetic field was either nonaxial or nondipolar are valid in principle

New proposal for the Piedras de Afilar lithostratigraphic formation, upper Neo proterozoic of Uruguay

International Nuclear Information System (INIS)

Pamoukaghlian, K.; Gaucher, C.; Poire, D.

2010-01-01

This work is about the Piedras de Afilar lithostratigraphic formation which is part of Tandilia Precambrian terrain of Uruguay. This sedimentary sequence of Neo proterozoic age is supported by a Paleoproterozoic basement

Geochemistry and petrology of mafic Proterozoic and Permian dykes on Bornholm, Denmark:

DEFF Research Database (Denmark)

Holm, Paul Martin; Pedersen, Lise E.; Højsteeen, Birte

2010-01-01

More than 250 dykes cut the mid Proterozoic basement gneisses and granites of Bornholm. Most trend between NNW and NNE, whereas a few trend NE and NW. Field, geochemical and petrological evidence suggest that the dyke intrusions occurred as four distinct events at around 1326 Ma (Kelseaa dyke...

Neoproterozoic marine carbonates and their paleoceanographic significance

Science.gov (United States)

Hood, Ashleigh van Smeerdijk; Wallace, Malcolm William

2018-01-01

The primary mineralogy of marine carbonate precipitates has been a crucial factor in constraining the major element composition of ancient oceans. Secular changes in Phanerozoic marine chemistry, including Mg/Ca, have been well-documented using the original carbonate mineralogy of ooids, marine cements and biominerals. However, the history of Precambrian seawater chemistry is not as well constrained, partially due to the prevalence of dolomitisation in the Precambrian geological record. The Neoproterozoic ( 1000 Ma to 541 Ma) record of primary carbonate mineralogy is documented here using a combination of literature data and new analysis of marine carbonate precipitates from the Otavi Fold Belt, Namibia, the Death Valley succession, USA and the Adelaide Fold Belt, Australia. These data suggest that the last 460 million years of the Proterozoic were dominated by aragonite and high-Mg calcite precipitation in shallow marine settings. In contrast, low-Mg calcite has only been recognised in a small number of formations. In addition to aragonite and calcite precipitation, marine dolomite precipitation was widespread in Neoproterozoic oceans, including mimetic (syn-sedimentary) dolomitisation and primary dolomite marine cementation. The combination of marine aragonite, high Mg-calcite and dolomite precipitation during the Neoproterozoic suggests extremely high seawater Mg/Ca conditions relative to Phanerozoic oceans. Marine dolomite precipitation may also be linked to widespread marine anoxia during this time.

Uranium deposits in Proterozoic quartz-pebble conglomerates

International Nuclear Information System (INIS)

1987-09-01

This report is the result of an effort to gather together the most important information on uranium deposits in Proterozoic quartz-pebble conglomerates in the United States of America, Canada, Finland, Ghana, South Africa and Australia. The paper discusses the uranium potential (and in some cases also the gold potential in South Africa, Western Australia and Ghana) in terms of ores, sedimentation, mineralization, metamorphism, placers, geologic formations, stratigraphy, petrology, exploration, tectonics and distribution. Geologic history and application of geologic models are also discussed. Glacial outwash and water influx is also mentioned. The uranium deposits in a number of States in the USA are covered. The Witwatersrand placers are discussed in several papers. Refs, figs, tabs

Proterozoic kimberlites and lamproites and a preliminary age for the Argyle lamproite pipe, Western Australia

International Nuclear Information System (INIS)

Skinner, E.M.W.; Bristow, J.W.; Smith, C.B.; Scott Smith, B.H.; Dawson, J.B.

1985-01-01

The Argyle pipe occurring in the East Kimberley Province of Western Australia is a unique, highly-diamondiferous lamproite. Although it resembles other lamproites located in the West Kimberley Province with respect to its setting, structure, petrography and geochemistry, it is probably Proterozoic in age and hence substantially older than Tertiary occurrences of the West Kimberley Province. Rb-Sr measurements on whole rock and phlogopite samples from magmatic olivine-phlogopite lamproite, reveals a two point model age of 1126 +- 9 Ma for the Argyle pipe. This age is consistent with ages of other, similar volcanic igneous rocks occurring in several localities worldwide. The widespread occurrence of Proterozoic kimberlites and lamproites suggests that this was an important period of worldwide alkalic intrusive activity

Middle proterozoic supra crustal and brazilian orogeny in the southeast Ceara state: a mono cyclic evolution

International Nuclear Information System (INIS)

Sa, J.M.; Bezerra, F.H.R.; Freitas Macedo, M.H. de; Pereira, R.

1988-01-01

The Oros belt is situated in the southeastern part of Ceara state, Brazil, and geologically pertains to the Borborema province. This belt comprises a volcano-sedimentary sequence of middle proterozoic age resting unconformably upon basement of Archean/low proterozoic age. In the geological map of Ceara state, this belt displays an elongate shape towards N-S, turning to ENE-WSW in the south, and reaches 12 km wide in the central park. This paper describes the relationships between the country rocks and the supra crustal sequence, as well as the plutonic intrusions and their tectonic metamorphic evolution. New Rb-Sr whole-rock dates are presented which are very important to separate anorogenic and syn-orogenic granites. (author)

Geochemistry and geochronology of the Archean and palaeo-Proterozoic formations of southern Cameroon (Ntem group, Congo craton)

International Nuclear Information System (INIS)

Rchameni, R.

1997-01-01

The aim of this work is to understand the crustal evolution of the NW margin of the Congo craton using structural, petrography, isotopic, geochemical and geochronological studies of the Archean and palaeo-Proterozoic formations of the Ntem group of southern Cameroon. The synthesis of these studies allows to propose a diapir-type gravity model linked with the genesis of granitoids to explain the geodynamical evolution of this part of the craton during the Archean. A convergence model with the collision of the Congo and Sao-Francisco cratons and with crust thickening followed by a relaxation phase is proposed for the palaeo-Proterozoic. (J.S.)

Model photoautrophs isolated from a Proterozoic ocean analog - aerobic life under anoxic conditions

Science.gov (United States)

Hamilton, T. L.; de Beer, D.; Klatt, J.; Macalady, J.; Weber, M.; Lott, C.; Chennu, A.

2016-12-01

The 1-2 billion year delay before the final rise of oxygen at the end of the Proterozoic represents an important gap in our understanding of ancient biogeochemical cycling. Primary production fueled by sulfide-dependent anoxygenic photosynthesis, including the activity of metabolically versatile cyanobacteria, has been invoked as a mechanism for sustaining low atmospheric O2 throughout much of the Proterozoic. However, we understand very little about photoautotrophs that inhabit Proterozoic-like environments present on Earth today. Here we report on the isolation and characterization of a cyanobacterium and a green sulfur bacterium that are the dominant members of pinnacle mats in Little Salt Spring—a karst sinkhole in Florida with perennially low levels of dissolved oxygen and sulfide. The red pinnacle mats bloom in the anoxic basin of the sinkhole and receive light that is of very poor quality to support photosynthesis. Characterization of the isolates is consistent with observations of oxygenic and anoxygenic photosynthesis in situ—both organisms perform anoxygenic photosynthesis under conditions of very low light quality and quantity. Oxygenic photosynthesis by the cyanobacterium isolate is inhibited by the presence of sulfide and under optimal light conditions, rates of anoxygenic photosynthesis are nearly double that of oxygenic photosynthesis. The green sulfur bacterium is tolerant of oxygen and has a very low affinity for sulfide. In Little Salt Spring, oxygenic photosynthesis occurs for only four hours a day and the water column remains anoxic because of a continuous supply of sulfide. Isolation and characterization of these photoautotrophs combined with our high resolution microsensor data in situ highlight microbial biogeochemical cycling in this exceptional site where aerobic microorganisms persist in a largely anoxic ecosystem.

Correlations of some Neoproterozoic carbonate-dominated successions in South America based on high-resolution chemostratigraphy

Directory of Open Access Journals (Sweden)

Alcides Nobrega Sial

Full Text Available ABSTRACT: This report reviews and incorporates new elemental and isotope chemostratigraphic data for correlation of Neoproterozoic carbonate-dominated successions in South America (Argentina, Bolivia, Brazil, Paraguay and Uruguay. These thick mixed carbonate/siliciclastic successions were largely deposited in epicontinental basins or accumulated on passive margins on the edges of cratons (e.g. São Francisco, Amazonia, Rio Apa Block, Pampia and Río de la Plata paleocontinents during extensional events related to the rifting of the Rodinia Supercontinent. From the stratigraphic point of view, these successions occur as three mega-sequences: glaciogenic, marine carbonate platform (above glaciomarine diamictites or rift successions, and dominantly continental to transitional siliciclastics. In the orogenic belts surrounding cratons, carbonate-dominated successions with important volcanoclastic/siliciclastic contribution have been, in most cases, strongly deformed. The precise ages of these successions remain a matter of debate, but recently new paleontological and geochronological data have considerably constrained depositional intervals. Here, we report high-resolution C, O, Sr, and S isotope trends measured in well-preserved sample sets and mainly use Sr and C isotopes in concert with lithostratigraphic/biostratigraphic observations to provide detailed correlations of these successions. The establishing of a high-level and definite chemostratigraphic correlation between Neoproterozoic basins in South America is the main goal of this work.

Planetary biology and microbial ecology. Biochemistry of carbon and early life

Science.gov (United States)

Margulis, L. (Editor); Nealson, K. H. (Editor); Taylor, I. (Editor)

1983-01-01

Experiments made with cyanobacteria, phototrophic bacteria, and methanogenic bacteria are detailed. Significant carbon isotope fractionation data is included. Taken from well documented extant microbial communities, this data provides a basis of comparison for isotope fractionation values measured in Archean and Proterozoic (preCambrian) rocks. Media, methods, and techniques used to acquire data are also described.

Isotopic data from proterozoic sediment-hosted sulfide deposits of Brazil: Implications for their metallogenic evolution and for mineral exploration

International Nuclear Information System (INIS)

Misi, Aroldo; Coelho, Carlos E.S.; Franca Rocha, Washington J.S.; Gomez, Adriana S.R.; Cunha, Iona A.; Iyer, Sundaram S.; Tassinari, Colombo C.G.; Kyle, J. Richard

1998-01-01

Geological, petrographic, fluid inclusions studies and isotopic data of seven Proterozoic sediment-hosted Pb-Zn-Ag sulfide deposits of Brazil, permit the estimation of the age of the hosting sequence and the mineralization, the nature of the sulfur and metal sources, the temperature range of sulfide formation and the environment of deposition of the mineral deposits. The studies suggest that they were formed during periods of extensional tectonics: Growth faults or reactivated basement faults were responsible for localized circulation of metal-bearing fluids within the sedimentary sequences. In most cases, sulfides were formed by the reduction of sedimentary sulfates. Linear structures are important controls for sulfide concentration in these Proterozoic basins. (author)

Neoproterozoic diamictite-cap carbonate succession and δ13C chemostratigraphy from eastern Sonora, Mexico

Science.gov (United States)

Corsetti, Frank A.; Stewart, John H.; Hagadorn, James W.

2007-01-01

Despite the occurrence of Neoproterozoic strata throughout the southwestern U.S. and Sonora, Mexico, glacial units overlain by enigmatic cap carbonates have not been well-documented south of Death Valley, California. Here, we describe in detail the first glaciogenic diamictite and cap carbonate succession from Mexico, found in the Cerro Las Bolas Group. The diamictite is exposed near Sahuaripa, Sonora, and is overlain by a 5 m thick very finely-laminated dolostone with soft sediment folds. Carbon isotopic chemostratigraphy of the finely-laminated dolostone reveals a negative δ13C anomaly (down to − 3.2‰ PDB) characteristic of cap carbonates worldwide. Carbon isotopic values rise to + 10‰ across ∼ 400 m of section in overlying carbonates of the Mina el Mezquite and Monteso Formations. The pattern recorded here is mostly characteristic of post-Sturtian (ca. ≤ 700 Ma), but pre-Marinoan (ca. ≥ 635 Ma) time. However, the Cerro Las Bolas Group shares ambiguity common to most Neoproterozoic successions: it lacks useful radiometric age constraints and biostratigraphically useful fossils, and its δ13C signature is oscillatory and therefore somewhat equivocal.

The microbially mediated soil organic carbon loss under degenerative succession in an alpine meadow.

Science.gov (United States)

Zhang, Yuguang; Liu, Xiao; Cong, Jing; Lu, Hui; Sheng, Yuyu; Wang, Xiulei; Li, Diqiang; Liu, Xueduan; Yin, Huaqun; Zhou, Jizhong; Deng, Ye

2017-07-01

Land-cover change has long been recognized as having marked effect on the amount of soil organic carbon (SOC). However, the microbially mediated processes and mechanisms on SOC are still unclear. In this study, the soil samples in a degenerative succession from alpine meadow to alpine steppe meadow in the Qinghai-Tibetan Plateau were analysed using high-throughput technologies, including Illumina sequencing and geochip functional gene arrays. The soil microbial community structure and diversity were significantly (p carbon degradation genes (e.g., pectin and hemicellulose) was significantly higher in alpine steppe meadow than in alpine meadow, but the relative abundance of soil recalcitrant carbon degradation genes (e.g., chitin and lignin) showed the opposite tendency. The Biolog Ecoplate experiment showed that microbially mediated soil carbon utilization was more active in alpine steppe meadow than in alpine meadow. Consequently, more soil labile carbon might be decomposed in alpine steppe meadow than in alpine meadow. Therefore, the degenerative succession of alpine meadow because of climate change or anthropogenic activities would most likely decrease SOC and nutrients medicated by changing soil microbial community structure and their functional potentials for carbon decomposition. © 2017 John Wiley & Sons Ltd.

Proterozoic Milankovitch cycles and the history of the solar system.

Science.gov (United States)

Meyers, Stephen R; Malinverno, Alberto

2018-06-19

The geologic record of Milankovitch climate cycles provides a rich conceptual and temporal framework for evaluating Earth system evolution, bestowing a sharp lens through which to view our planet's history. However, the utility of these cycles for constraining the early Earth system is hindered by seemingly insurmountable uncertainties in our knowledge of solar system behavior (including Earth-Moon history), and poor temporal control for validation of cycle periods (e.g., from radioisotopic dates). Here we address these problems using a Bayesian inversion approach to quantitatively link astronomical theory with geologic observation, allowing a reconstruction of Proterozoic astronomical cycles, fundamental frequencies of the solar system, the precession constant, and the underlying geologic timescale, directly from stratigraphic data. Application of the approach to 1.4-billion-year-old rhythmites indicates a precession constant of 85.79 ± 2.72 arcsec/year (2σ), an Earth-Moon distance of 340,900 ± 2,600 km (2σ), and length of day of 18.68 ± 0.25 hours (2σ), with dominant climatic precession cycles of ∼14 ky and eccentricity cycles of ∼131 ky. The results confirm reduced tidal dissipation in the Proterozoic. A complementary analysis of Eocene rhythmites (∼55 Ma) illustrates how the approach offers a means to map out ancient solar system behavior and Earth-Moon history using the geologic archive. The method also provides robust quantitative uncertainties on the eccentricity and climatic precession periods, and derived astronomical timescales. As a consequence, the temporal resolution of ancient Earth system processes is enhanced, and our knowledge of early solar system dynamics is greatly improved.

Overcoming Barriers to Successfully Commercializing Carbon Dioxide Utilization

International Nuclear Information System (INIS)

Kant, Marvin

2017-01-01

The successful transition to a low-carbon economy hinges on innovative solutions and collaborative action on a global scale. Sustainable entrepreneurship is thereby recognized as a key driver in the creation and transformation of ecologically and socially sustainable economic systems. The purpose of this article is to contribute to this topic by understanding commercialization barriers for strong sustainability-oriented new technology ventures and to derive recommendations to overcome them. A qualitative multilevel approach is applied to identify barriers and drivers within the internal dynamic capabilities of the organization and within the organization’s external stakeholders. A model of barriers has been developed based on semi-structured interviews with new carbon dioxide utilization ventures and associated industry players in Canada, the USA, and the European Economic Area. Resulting recommendations to facilitate the (re-)design of a dedicated support system are proposed on four levels: (a) actors, (b) resources, (c) institutional settings, and (d) the coordination of the support system.

Overcoming Barriers to Successfully Commercializing Carbon Dioxide Utilization

Energy Technology Data Exchange (ETDEWEB)

Kant, Marvin, E-mail: marvin.kant@tu-berlin.de [Department of Entrepreneurship and Innovation Management, Technische Universität Berlin, Berlin (Germany)

2017-09-13

The successful transition to a low-carbon economy hinges on innovative solutions and collaborative action on a global scale. Sustainable entrepreneurship is thereby recognized as a key driver in the creation and transformation of ecologically and socially sustainable economic systems. The purpose of this article is to contribute to this topic by understanding commercialization barriers for strong sustainability-oriented new technology ventures and to derive recommendations to overcome them. A qualitative multilevel approach is applied to identify barriers and drivers within the internal dynamic capabilities of the organization and within the organization’s external stakeholders. A model of barriers has been developed based on semi-structured interviews with new carbon dioxide utilization ventures and associated industry players in Canada, the USA, and the European Economic Area. Resulting recommendations to facilitate the (re-)design of a dedicated support system are proposed on four levels: (a) actors, (b) resources, (c) institutional settings, and (d) the coordination of the support system.

Overcoming Barriers to Successfully Commercializing Carbon Dioxide Utilization

Directory of Open Access Journals (Sweden)

Marvin Kant

2017-09-01

Full Text Available The successful transition to a low-carbon economy hinges on innovative solutions and collaborative action on a global scale. Sustainable entrepreneurship is thereby recognized as a key driver in the creation and transformation of ecologically and socially sustainable economic systems. The purpose of this article is to contribute to this topic by understanding commercialization barriers for strong sustainability-oriented new technology ventures and to derive recommendations to overcome them. A qualitative multilevel approach is applied to identify barriers and drivers within the internal dynamic capabilities of the organization and within the organization’s external stakeholders. A model of barriers has been developed based on semi-structured interviews with new carbon dioxide utilization ventures and associated industry players in Canada, the USA, and the European Economic Area. Resulting recommendations to facilitate the (re-design of a dedicated support system are proposed on four levels: (a actors, (b resources, (c institutional settings, and (d the coordination of the support system.

Structural and metamorphic evolution of the Mid-Late Proterozoic Rayner Complex, Cape Bruce, East Antarctica

International Nuclear Information System (INIS)

Dunkley, D.J.; Clarke, G.L.; White, R.W.

2002-01-01

Granulite to transitional granulite facies gneisses exposed at Cape Bruce, Rayner Complex, East Antarctica, record three main orogenic/magmatic phases: (1) intrusion of c. 1000-980 Ma felsic orthogneisses into Mid-Proterozoic metasediments, contemporary with the development of north-trending reclined to recumbent folds; (2) extensive c. 980-900 Ma felsic magmatism, including equivalents of the Mawson Charnockite, which accompanied the development of upright, east-northeast-trending folds; and (3) ultramylonite zones of uncertain age. The first two phases are known as the Rayner Structrual Episode, the effects of which are similar in rocks to the east of Cape Bruce, at Mawson, and in the northern Prince Charles Mountains. Archaean rocks immediately to the west of Cape Bruce were tectonically reworked during the Rayner Structural Episode. The first orogenic phase is inferred to represent the collision between a wedge-shaped Proterozoic block comprising rocks of the Mawson Coast and Eastern Ghats Province, with the Archaean Napier Complex. The second orogenic phase included a major period of crustal growth through emplacement of the Mawson Charnockite and equivalents. (author). 41 refs., 6 figs., 1 tab

Revised stratigraphic nomenclature and correlation of early proterozoic rocks of the Darwin - Katherine region, Northern Territory

International Nuclear Information System (INIS)

Needham, R.S.; Stuart-Smith, P.G.

1984-01-01

New stratigraphic names and correlations are given for parts of the Early Proterozoic Pine Creek Geosyncline metasedimentary sequence and overlying felsic volcanics of the Darwin-Katherine region. They have significant implications for the stratigraphic distribution of uranium mineralisation in the Rum Jungle, Alligator Rivers and South Alligator Valley uranium fields

Correlation of proterozoic sediments of Western and Central Africa and South America based upon radiochronological and paleontological data

International Nuclear Information System (INIS)

Bonhomme, M.G.

1982-01-01

Nearly 70 new Rb-Sr isochron ages and many K-Ar conventional ages have been determined between 1975 and 1980 on Proterozoic sedimentary or metasedimentary sequences in western and Central Africa and South America. Some stratigraphic results have been established: (1) five formations have been dated of the Lower Proterozoic; (2) a long sedimentation gap occurs, mainly in western Africa and in some regions of Central Africa and South America between nearly 1600 and 1100 Ma; (3) the upper Riphean assemblages of stromatolites have been dated and compared to those of the Eurasian craton; (4) two main glacial events have been dated, the first one placed at ca. 950 Ma, the second during the Vendian, at ca. 650-620 Ma; (5) it can be stated that, when applied to Precambrian sequences, all stratigraphic methods must be used together. (Auth.)

The Successful Treatment of Elephantiasis Nostras Verrucosa With Ablative Carbon Dioxide Laser.

Science.gov (United States)

Robinson, Caitlin G; Lee, Kory R; Thomas, Valencia D

2018-03-01

Elephantiasis nostras verrucosa (ENV) is a disfiguring skin condition that is difficult to treat. Existing treatment modalities serve to improve cosmesis or treat symptoms. Herein, we report a case of ENV with lymphocutaneous fistula successfully treated with ablative carbon dioxide laser. A 57-year-old woman with biopsy-proven ENV with lymphocutaneous fistula was treated with ablative carbon dioxide laser to the symptomatic area of her right thigh in 3 treatment sessions over 6 months. The patient had resolution of lymphocutaneous drainage as well as 90% improvement in the appearance of ENV lesions at the 1-month follow-up visit. Ablative carbon dioxide laser may provide cosmetic, symptomatic, and medical benefit for patients with localized ENV.

Soil carbon changes upon secondary succession in Imperata grasslands (East Kalimantan, Indonesia)

NARCIS (Netherlands)

Kamp, van der J.; Yassir, I.; Buurman, P.

2009-01-01

Soil carbon changes upon secondary succession in Imperata grasslands are important both for their effect on potential production and for possible implications of forest degradation and regeneration on global climate change. We studied the effect of forest regeneration after fire in Imperata

Stratigraphy and uranium potential of early proterozoic metasedimentary rocks in the Medicine Bow Mountains, Wyoming

International Nuclear Information System (INIS)

Karlstrom, K.E.; Houston, R.S.

1979-01-01

The Medicine Bow Mountains of southeastern Wyoming contain an eight mile (13 km) thick section of Early Proterozoic (2500 to 1700 My b.p.) metasedimentary rocks which is subdivided into three successions: the Phantom Lake Metamorphic Suite (oldest), Deep Lake Group, and Libby Creek Group. The most promising units are the basal conglomerate of the upper Phantom Lake Suite, which appears to unconformably overlie metavolcanics of the lower Phantom Lake Suite, and the Magnolia Formation, which unconformably overlies the upper Phantom Lake Suite. Outcrops of the former have yielded assays of up to 141 ppM U and 916 ppM Th, with no appreciable gold. Outcrops of the Magnolia Formation have yielded up to 8.4 ppM U and 38 ppM Th. Several factors indicate that these units deserve further study. First, the lithologies of the radioactive and nonradioactive units are remarkably similar to those found in known uranium fossil-placers. Second, the paleogeography was favorable for placer accumulation if the conglomerates are fluvial sediments in an epicontinental clastic succession which was deposited during several transgressive-regressive cycles, as interpreted to be, Third, the age of the conglomerates may be similar to the age of other known uranium placers-i.e., more than 2000 My b.p. And fourth, geological and geochemical studies indicate that both uranium and pyrite have been strongly leached from outcrops and that subsurface rocks contain more uranium than surface rocks do

The role of biology in planetary evolution: cyanobacterial primary production in low‐oxygen Proterozoic oceans

Science.gov (United States)

Bryant, Donald A.; Macalady, Jennifer L.

2016-01-01

Summary Understanding the role of biology in planetary evolution remains an outstanding challenge to geobiologists. Progress towards unravelling this puzzle for Earth is hindered by the scarcity of well‐preserved rocks from the Archean (4.0 to 2.5 Gyr ago) and Proterozoic (2.5 to 0.5 Gyr ago) Eons. In addition, the microscopic life that dominated Earth's biota for most of its history left a poor fossil record, consisting primarily of lithified microbial mats, rare microbial body fossils and membrane‐derived hydrocarbon molecules that are still challenging to interpret. However, it is clear from the sulfur isotope record and other geochemical proxies that the production of oxygen or oxidizing power radically changed Earth's surface and atmosphere during the Proterozoic Eon, pushing it away from the more reducing conditions prevalent during the Archean. In addition to ancient rocks, our reconstruction of Earth's redox evolution is informed by our knowledge of biogeochemical cycles catalysed by extant biota. The emergence of oxygenic photosynthesis in ancient cyanobacteria represents one of the most impressive microbial innovations in Earth's history, and oxygenic photosynthesis is the largest source of O 2 in the atmosphere today. Thus the study of microbial metabolisms and evolution provides an important link between extant biota and the clues from the geologic record. Here, we consider the physiology of cyanobacteria (the only microorganisms capable of oxygenic photosynthesis), their co‐occurrence with anoxygenic phototrophs in a variety of environments and their persistence in low‐oxygen environments, including in water columns as well as mats, throughout much of Earth's history. We examine insights gained from both the rock record and cyanobacteria presently living in early Earth analogue ecosystems and synthesize current knowledge of these ancient microbial mediators in planetary redox evolution. Our analysis supports the hypothesis that anoxygenic

The role of biology in planetary evolution: cyanobacterial primary production in low-oxygen Proterozoic oceans.

Science.gov (United States)

Hamilton, Trinity L; Bryant, Donald A; Macalady, Jennifer L

2016-02-01

Understanding the role of biology in planetary evolution remains an outstanding challenge to geobiologists. Progress towards unravelling this puzzle for Earth is hindered by the scarcity of well-preserved rocks from the Archean (4.0 to 2.5 Gyr ago) and Proterozoic (2.5 to 0.5 Gyr ago) Eons. In addition, the microscopic life that dominated Earth's biota for most of its history left a poor fossil record, consisting primarily of lithified microbial mats, rare microbial body fossils and membrane-derived hydrocarbon molecules that are still challenging to interpret. However, it is clear from the sulfur isotope record and other geochemical proxies that the production of oxygen or oxidizing power radically changed Earth's surface and atmosphere during the Proterozoic Eon, pushing it away from the more reducing conditions prevalent during the Archean. In addition to ancient rocks, our reconstruction of Earth's redox evolution is informed by our knowledge of biogeochemical cycles catalysed by extant biota. The emergence of oxygenic photosynthesis in ancient cyanobacteria represents one of the most impressive microbial innovations in Earth's history, and oxygenic photosynthesis is the largest source of O2 in the atmosphere today. Thus the study of microbial metabolisms and evolution provides an important link between extant biota and the clues from the geologic record. Here, we consider the physiology of cyanobacteria (the only microorganisms capable of oxygenic photosynthesis), their co-occurrence with anoxygenic phototrophs in a variety of environments and their persistence in low-oxygen environments, including in water columns as well as mats, throughout much of Earth's history. We examine insights gained from both the rock record and cyanobacteria presently living in early Earth analogue ecosystems and synthesize current knowledge of these ancient microbial mediators in planetary redox evolution. Our analysis supports the hypothesis that anoxygenic photosynthesis

Proterozoic events recorded in quartzite cobbles at Jack Hills, Western Australia: New constraints on sedimentation and source of > 4 Ga zircons

Science.gov (United States)

Grange, Marion L.; Wilde, Simon A.; Nemchin, Alexander A.; Pidgeon, Robert T.

2010-03-01

Rare heavy mineral bands within quartzite cobbles were identified in two conglomerate units within the Jack Hills belt, Western Australia. Seven zircon-bearing cobbles were analysed from one location (site 152) and three from another (site 154), both approximately 1 km west of the site where zircons in excess of 4 Ga are abundant (W74 'discovery' site). Individual pebbles from the 152 site reveal three distinctive features, containing either zircons > 3.0 Ga in age, 4 Ga was discovered from the entire suite of pebbles, in contrast to the well-studied W74 site. A single detrital zircon with an age of 1220 ± 42 Ma from location 152 is the youngest grain so far reported from sedimentary rocks at Jack Hills. It shows magmatic oscillatory zoning and thus implies at least two sedimentary cycles within the Proterozoic; requiring erosion of an igneous precursor, incorporation into a clastic sediment, induration and subsequent erosion and transport to be hosted in the conglomerate. The nearest source for rocks of this age is the Bangemall Supergroup in the Collier Basin, ˜ 100 km northeast in the Capricorn Orogen. This would imply tectonic interleaving of originally more extensive Bangemall rocks, possibly related to activity along the Cargarah Shear Zone that traverses the Jack Hills belt. The lack of > 4.1 Ga zircons in the pebbles is highly significant, suggesting the immediate source of ancient zircons was no longer present at the Earth's surface. This equates with a general lack of ancient crystals noted in rocks that contain Proterozoic zircons from previous studies and implies that such grains diminish in number as earlier sedimentary rocks were successively recycled.

Lower Brioverian formations (Upper Proterozoic) of the Armorican Massif (France): geodynamic evolution of source areas revealed by sandstone petrography and geochemistry

Science.gov (United States)

Dabard, Marie Pierre

1990-11-01

Formations with interbedded cherts constitute an important part of the Lower Brioverian succession (Upper Proterozoic age) in the Armorican Massif (northwest France). These formations are composed of shale-sandstone alternations with interbedded siliceous carbonaceous members. Petrographic and geochemical study of the detrital facies shows that these rocks are compositionally immature. The wackes are rich in lithic fragments (volcanic fragments: 3-20% modal; sedimentary and metamorphic fragments: 0-7% modal) and in feldspar (5-16%). From the geochemical point of view, they are relatively enriched in Fe 2+MgO (about 5.5%) and in alkalis with {Na 2O }/{K 2O } ratios greater than 1. The CaO contents are low (about 0.3%). Slightly negative Eu anomalies are observed ( {Eu}/{Eu ∗} = 0.8 ). Their chemical compositions are in agreement with a dominantly acidic source area with deposition in a continental active margin setting. Compared with other Upper Proterozoic deposits of the Armorican Massif, the interbedded-chert formations appear rather similar to other deposits in North Brittany which accumulated in an intra-arc or back-arc basin environment. The formations with interbedded cherts are interpreted as having been deposited during an early stage of magmatic arc activity (around 640-630 Ma ago) in an immature marginal basin. The clastic supply to these formations is derived in part from early volcanic products (acidic to intermediate) which are linked to subduction beneath the North Armorican Domain. Another component is inherited from the reworking of 2000 Ma old basement relics. The opening of the back-arc domain, with associated basaltic volcanism, would bring about a progressive displacement of the interbedded-chert depositional basin towards the continental margin.

Effects of Successive Rotation Regimes on Carbon Stocks in Eucalyptus Plantations in Subtropical China Measured over a Full Rotation.

Science.gov (United States)

Li, Xiaoqiong; Ye, Duo; Liang, Hongwen; Zhu, Hongguang; Qin, Lin; Zhu, Yuling; Wen, Yuanguang

2015-01-01

Plantations play an important role in carbon sequestration and the global carbon cycle. However, there is a dilemma in that most plantations are managed on short rotations, and the carbon sequestration capacities of these short-rotation plantations remain understudied. Eucalyptus has been widely planted in the tropics and subtropics due to its rapid growth, high adaptability, and large economic return. Eucalyptus plantations are primarily planted in successive rotations with a short rotation length of 6~8 years. In order to estimate the carbon-stock potential of eucalyptus plantations over successive rotations, we chose a first rotation (FR) and a second rotation (SR) stand and monitored the carbon stock dynamics over a full rotation from 1998 to 2005. Our results showed that carbon stock in eucalyptus trees (TC) did not significantly differ between rotations, while understory vegetation (UC) and soil organic matter (SOC) stored less carbon in the SR (1.01 vs. 2.76 Mg.ha(-1) and 70.68 vs. 81.08 Mg. ha(-1), respectively) and forest floor carbon (FFC) conversely stored more (2.80 vs. 2.34 Mg. ha(-1)). The lower UC and SOC stocks in the SR stand resulted in 1.13 times lower overall ecosystem carbon stock. Mineral soils and overstory trees were the two dominant carbon pools in eucalyptus plantations, accounting for 73.77%~75.06% and 20.50%~22.39%, respectively, of the ecosystem carbon pool. However, the relative contribution (to the ecosystem pool) of FFC stocks increased 1.38 times and that of UC decreased 2.30 times in the SR versus FR stand. These carbon pool changes over successive rotations were attributed to intensive successive rotation regimes of eucalyptus plantations. Our eight year study suggests that for the sustainable development of short-rotation plantations, a sound silvicultural strategy is required to achieve the best combination of high wood yield and carbon stock potential.

Effects of Successive Rotation Regimes on Carbon Stocks in Eucalyptus Plantations in Subtropical China Measured over a Full Rotation.

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Xiaoqiong Li

Full Text Available Plantations play an important role in carbon sequestration and the global carbon cycle. However, there is a dilemma in that most plantations are managed on short rotations, and the carbon sequestration capacities of these short-rotation plantations remain understudied. Eucalyptus has been widely planted in the tropics and subtropics due to its rapid growth, high adaptability, and large economic return. Eucalyptus plantations are primarily planted in successive rotations with a short rotation length of 6~8 years. In order to estimate the carbon-stock potential of eucalyptus plantations over successive rotations, we chose a first rotation (FR and a second rotation (SR stand and monitored the carbon stock dynamics over a full rotation from 1998 to 2005. Our results showed that carbon stock in eucalyptus trees (TC did not significantly differ between rotations, while understory vegetation (UC and soil organic matter (SOC stored less carbon in the SR (1.01 vs. 2.76 Mg.ha(-1 and 70.68 vs. 81.08 Mg. ha(-1, respectively and forest floor carbon (FFC conversely stored more (2.80 vs. 2.34 Mg. ha(-1. The lower UC and SOC stocks in the SR stand resulted in 1.13 times lower overall ecosystem carbon stock. Mineral soils and overstory trees were the two dominant carbon pools in eucalyptus plantations, accounting for 73.77%~75.06% and 20.50%~22.39%, respectively, of the ecosystem carbon pool. However, the relative contribution (to the ecosystem pool of FFC stocks increased 1.38 times and that of UC decreased 2.30 times in the SR versus FR stand. These carbon pool changes over successive rotations were attributed to intensive successive rotation regimes of eucalyptus plantations. Our eight year study suggests that for the sustainable development of short-rotation plantations, a sound silvicultural strategy is required to achieve the best combination of high wood yield and carbon stock potential.

Microfossils' diversity from the Proterozoic Taoudeni Basin, Mauritania

Science.gov (United States)

Beghin, Jérémie; Houzay, Jean-Pierre; Blanpied, Christian; Javaux, Emmanuelle

2014-05-01

Prokaryotes and microscopic eukaryotes are known to have appeared well before the Cambrian's adaptative radiation which flourished perceptibly as a generalized macroscopic world. What do we know about the trigger events which stimulated eukaryotic diversification during the Proterozoic? Biological innovations or environmental changes, and indeed probably both (Knoll et al., 2006), played a fundamental role controlling this important step of life's evolution on Earth. Javaux (2011), proposed a diversification pattern of early eukaryotes divided into three steps and focusing on different taxonomic levels, from stem group to within crown group, of the domain Eukarya. Here, we present a new, exquisitely preserved and morphologically diverse assemblage of organic-walled microfossils from the 1.1 Ga El Mreiti Group of the Taoudeni Basin (Mauritania). The assemblage includes beautifully preserved microbial mats comprising pyritized filaments, prokaryotic filamentous sheaths and filaments, microfossils of uncertain biological affinity including smooth isolated and colonial sphaeromorphs (eukaryotes and/or prokaryotes), diverse protists (ornamented and process-bearing acritarchs), as well multicellular microfossils interpreted in the literature as possible xanthophyte algae. Several taxa are reported for the first time in Africa, but are known worldwide. This study improves microfossil diversity previously reported by Amard (1986) and shows purported xanthophyte algae contrary to a previous biomarker study suggesting the absence of eukaryotic algae, other than acritarchs, in the basin (Blumenberg et al., 2012). This new microfossil assemblage and others provide, all together, evidences of early and worldwide diversification of eukaryotes. Thereby, those first qualitative results also provide a basis for further and larger quantitative studies on the Taoudeni Basin. To better understand the palaeobiology (stem or crown group, aerobic or anaerobic metabolism) and

Sedimentology and chemostratigraphy of a Valanginian carbonate succession from the Baja Guajira Basin, northern Colombia

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Juan Carlos Silva-Tamayo

Full Text Available ABSTRACT: The Kesima Member of the Palanz Formation constitutes the first record of Cretaceous marine sedimentation along the Baja Guajira Basin, northern Colombia. Sedimentologic and petrographic analyses suggest a deposition along a coral reef dominated rimmed carbonate platform. 87Sr/86Sr values between 0.707350 and 0.707400 suggest a Valanginian (136 - 132 Ma depositional age for the Kesima Member. A positive anomaly on the δ13C values of ~2.2‰ suggests that this rimmed carbonate platform registered the Valanginian Weissert oceanic anoxic event. Although the Weissert oceanic anoxic event resulted on a major drowning of the Circum Tethyan carbonate platforms, it seems to have not affected those from the Circum Caribbean, where several shallow marine carbonate platform successions crop out. The Kesima Member displays a change from an organically produced carbonate factory into an inorganically produced, ooids dominated, carbonate factory during the peak of the Weissert event δ13C anomaly. This change in the carbonate factory, which may represent a major perturbation of the marine carbonate budget along tropical settings during the Weissert event, coincides with a major decrease in global sea level. Finally, the age of the Kesima Member is considerably older than that of other Cretaceous carbonate successions cropping out in other northern South America sedimentary basins (i.e. Perija-Merida, Cesar-Rancheria. Differences in the timing of the Cretaceous marine incursion along northern South America, together with the differences in the Triassic-Jurassic stratigraphy of several sedimentary basins in northern South America, suggest that the Baja Guajira and Maracaibo basins remained as an isolated tectonic block separated from northern South America after the breakup of Pangea.

Stages of material transformations of Archean-Proterozoic rocks (Central-Karelian domain)

International Nuclear Information System (INIS)

Vinogradov, V.I.; Buyakajte, M.I.; Kolodyazhnyj, S.Yu.; Leonov, M.G.; Orlov, S.Yu.

2001-01-01

The age of the Archean-Proterozoic rocks from the south-east part of the Central-Karelian domain was determined by the method of Rb-Sr dating. It was ascertained that the age of the least tectonized rocks of granite-greenstone Archean foundation makes up 2800±70 mln. years at initial strontium isotopic ratio of 0.7022±0.0007. Gneisses of mainly plagiogranite composition, their age 1930±118 mln. years and strontium isotopic ratio 0.7170±0.0026, constitute the second group of the rocks. It is shown that isotopic age defined for the two groups of rocks agrees well with major geological events on the Baltic shield and planet as a whole [ru

The efficiency of seismic attributes to differentiate between massive and non-massive carbonate successions for hydrocarbon exploration activity

Science.gov (United States)

Sarhan, Mohammad Abdelfattah

2017-12-01

The present work investigates the efficiency of applying volume seismic attributes to differentiate between massive and non-massive carbonate sedimentary successions on using seismic data. The main objective of this work is to provide a pre-drilling technique to recognize the porous carbonate section (probable hydrocarbon reservoirs) based on seismic data. A case study from the Upper Cretaceous - Eocene carbonate successions of Abu Gharadig Basin, northern Western Desert of Egypt has been tested in this work. The qualitative interpretations of the well-log data of four available wells distributed in the study area, namely; AG-2, AG-5, AG-6 and AG-15 wells, has confirmed that the Upper Cretaceous Khoman A Member represents the massive carbonate section whereas the Eocene Apollonia Formation represents the non-massive carbonate unit. The present work have proved that the most promising seismic attributes capable of differentiating between massive and non-massive carbonate sequences are; Root Mean Square (RMS) Amplitude, Envelope (Reflection Strength), Instantaneous Frequency, Chaos, Local Flatness and Relative Acoustic Impedance.

Tectonics and sedimentation of late Proterozoic Damaran convergent continental margin, Khomas Hochland, central Namibia

International Nuclear Information System (INIS)

Kukla, P.A.

1990-01-01

The Late Proterozoic Khomas Trough comprises metasedimentary and metabasic rocks of the Kuiseb Formation and its evolution plays an important role in understanding the Damara orogenic belt as a whole. An attempt was made to characterize the metasedimentary and metabasic rocks encountered by means of sedimentological, structural, petrographical, mineralogical and geochemical methods. This led to the modelling of the geotectonic evolution of the Khomas Trough with particular focus on the sedimentary palaeoenvironments and the structural evolution of this area during Pan-African orogeny in Namibia. 251 refs., 81 figs., 14 tabs

The role of biology in planetary evolution: cyanobacterial primary production in low?oxygen Proterozoic oceans

OpenAIRE

Hamilton, Trinity L.; Bryant, Donald A.; Macalady, Jennifer L.

2015-01-01

Summary Understanding the role of biology in planetary evolution remains an outstanding challenge to geobiologists. Progress towards unravelling this puzzle for Earth is hindered by the scarcity of well?preserved rocks from the Archean (4.0 to 2.5?Gyr ago) and Proterozoic (2.5 to 0.5?Gyr ago) Eons. In addition, the microscopic life that dominated Earth's biota for most of its history left a poor fossil record, consisting primarily of lithified microbial mats, rare microbial body fossils and m...

Atmospheric oxygen regulation at low Proterozoic levels by incomplete oxidative weathering of sedimentary organic carbon

Science.gov (United States)

Daines, Stuart J.; Mills, Benjamin J. W.; Lenton, Timothy M.

2017-02-01

It is unclear why atmospheric oxygen remained trapped at low levels for more than 1.5 billion years following the Paleoproterozoic Great Oxidation Event. Here, we use models for erosion, weathering and biogeochemical cycling to show that this can be explained by the tectonic recycling of previously accumulated sedimentary organic carbon, combined with the oxygen sensitivity of oxidative weathering. Our results indicate a strong negative feedback regime when atmospheric oxygen concentration is of order pO2~0.1 PAL (present atmospheric level), but that stability is lost at pO2counterbalancing changes in the weathering of isotopically light organic carbon. This can explain the lack of secular trend in the Precambrian δ13C record, and reopens the possibility that increased biological productivity and resultant organic carbon burial drove the Great Oxidation Event.

Constraining the climate and ocean pH of the early Earth with a geological carbon cycle model.

Science.gov (United States)

Krissansen-Totton, Joshua; Arney, Giada N; Catling, David C

2018-04-17

The early Earth's environment is controversial. Climatic estimates range from hot to glacial, and inferred marine pH spans strongly alkaline to acidic. Better understanding of early climate and ocean chemistry would improve our knowledge of the origin of life and its coevolution with the environment. Here, we use a geological carbon cycle model with ocean chemistry to calculate self-consistent histories of climate and ocean pH. Our carbon cycle model includes an empirically justified temperature and pH dependence of seafloor weathering, allowing the relative importance of continental and seafloor weathering to be evaluated. We find that the Archean climate was likely temperate (0-50 °C) due to the combined negative feedbacks of continental and seafloor weathering. Ocean pH evolves monotonically from [Formula: see text] (2σ) at 4.0 Ga to [Formula: see text] (2σ) at the Archean-Proterozoic boundary, and to [Formula: see text] (2σ) at the Proterozoic-Phanerozoic boundary. This evolution is driven by the secular decline of pCO 2 , which in turn is a consequence of increasing solar luminosity, but is moderated by carbonate alkalinity delivered from continental and seafloor weathering. Archean seafloor weathering may have been a comparable carbon sink to continental weathering, but is less dominant than previously assumed, and would not have induced global glaciation. We show how these conclusions are robust to a wide range of scenarios for continental growth, internal heat flow evolution and outgassing history, greenhouse gas abundances, and changes in the biotic enhancement of weathering. Copyright © 2018 the Author(s). Published by PNAS.

The characteristics of soda metasomatite type uranium mineralization for proterozoic strata in the central-southern part of Kang-Dian earth's axis

International Nuclear Information System (INIS)

Qian Farong

1995-12-01

The uranium mineralization for Proterozoic strata in the central-southern part of Kang-Dian earth's axis can be divided into four typy (sandstone, soda metasomatite, proterozoic epimetamorphics and quartzite). The soda metasomatite type is the dominant type of uranium mineralization and has the prospecting potential in the area. The characteristics of this type uranium mineralization and the problems of metallogenesis are discussed. Soda metasomatite type uranium mineralization is controlled by soda metasomatite and structure. Uranium exists mainly in the forms of minerals (pitchblende, uranate). Its cell parameter is high and oxygenated coefficient is low, belonging to moderate-low temperature hydrothermal origin. The metallogenetic materials originated from deep-seated crust and country rocks. The metallogenetic solution includes a great quantity of atmospheric water, besides hydrothermal solution from deep-seated crust. The metallogene underwent the two stages i.e. Jinnin and Chengjiang. (4 tabs., 3 figs.)

Uraniferous concentrations in the Francevillian of Gabon: their association with fossil hydrocarbon-bearing ore deposits of the lower Proterozoic

International Nuclear Information System (INIS)

Gauthier-Lafaye, Francois; Weber, Francis

1981-01-01

The Francevillian U deposits of Gabon are located in one of the oldest non metamorphic sedimentary series of the Lower Proterozoic 2150 M.Y. old. The uraniferous mineralization 2050 M.Y. old is strongly related to organic matter concentrated in oil-bearing structures after migration. No geological event remobilized the mineralizations since their settling [fr

Association of the Purana basins and the middle Proterozoic mobile belts in peninsular India: implications on targeting uranium deposits

International Nuclear Information System (INIS)

Kale, V.S.

1995-01-01

The disparate Archaean Cratonic Nuclei of the Indian peninsular shield coalesced together through late Archaean - Palaeoproterozoic accretionary tectonic events. The subsequent Mesoproterozoic and Neoproterozoic sequences are preserved either in the Purana basins or in the middle Proterozoic mobile belts (MPMB). The latter contain deformed and metamorphosed supracrustal sequences; and can be ascribed to compressive tectonic regimes. The Purana basins on the other hand represent shallow marine, epicratonic, passive-margin sequences deposited in an extensional tectonic regime. Major deformational events and metamorphism of the MPMB are known to have taken place around 1600 ±200 Ma and 900 ± 100 Ma. These two periods coincide with the ages of initiation and major intrabasinal breaks in the growth of the Purana basins. The contemporary juxtapositioning of these two dissimilar tectonic regimes in peninsular India, is examined within the framework of the available data on them and the current models of Proterozoic tectonics. Its implications on uranium mineralization and possible regions for targeting exploration activities are discussed on this basis. (author). 112 refs., 4 figs

A deposit model for magmatic iron-titanium-oxide deposits related to Proterozoic massif anorthosite plutonic suites: Chapter K in Mineral Deposit Models for Resource Assessment

Science.gov (United States)

Woodruff, Laurel G.; Nicholson, Suzanne W.; Fey, David L.

2013-01-01

This descriptive model for magmatic iron-titanium-oxide (Fe-Ti-oxide) deposits hosted by Proterozoic age massif-type anorthosite and related rock types presents their geological, mineralogical, geochemical, and geoenvironmental attributes. Although these Proterozoic rocks are found worldwide, the majority of known deposits are found within exposed rocks of the Grenville Province, stretching from southwestern United States through eastern Canada; its extension into Norway is termed the Rogaland Anorthosite Province. This type of Fe-Ti-oxide deposit dominated by ilmenite rarely contains more than 300 million tons of ore, with between 10- to 45-percent titanium dioxide (TiO2), 32- to 45-percent iron oxide (FeO), and less than 0.2-percent vanadium (V).

Successive carbon- and boron saturation of KhVG steel in powder mixtures

Energy Technology Data Exchange (ETDEWEB)

Alimov, Yu A; Gordienko, S I

1975-01-01

Method of successive saturation of KhVG steel with carbon and boron in powder mixtures is described. After carbonization of steel in a charcoal carburator at 930 deg C during 3 hrs a domain of equiaxial large grains is formed there the latter representing carbides of Fe/sub 3/C and (Fe, M)/sub 3/C. The increase of duration of carbonization up to 5 hrs and above results in formation of a cement grid greatly impairing the mechanical properties of the metal. Carbonization is followed by borating in powdered technical boron carbide at 900 deg C for 4 hrs which ensures formation on the sample surface of a borated layer with depth up to 65 mkm covering the carbonized zone. As followed from metallographic and x-ray structural analysis, the borated layer consists of boride needles with complex composition (Fe, Cr, Mn)B. Oil hardening of carbonized KhVG steel from 850 deg C and low-temperature tempering at 180 deg C for 1 hr results in formation in the main metal of martensite-carbide structure and, respectively, in the decrease of the microhardness gradient between the diffusion layers, as compared with borated KhVG steel. Operation tests of strengthened matrices of preforming machines under the conditions of application of dynamic pressing forces up to 1500 kg Fce/cm/sup 2/ demonstrated that the cyclical strength of carboborated coverings is 2.0-3.0 times higher than that of borated ones. The method of carboborating is recommended for strengthening the details of stamp and press tools.

Provenance and tectonic setting of the supra-crustal succession of the Qinling Complex: Implications for the tectonic affinity of the North Qinling Belt, Central China

Science.gov (United States)

Shi, Yu; Huang, Qianwen; Liu, Xijun; Krapež, Bryan; Yu, Jinhai; Bai, Zhian

2018-06-01

The Qinling Complex lies in the Qinling orogenic belt of Central China and holds the key to understanding the evolution of this feature. The Qinling Complex comprises a basement complex composed of amphibolite and ecologite, overlain by a supra-crustal succession that has been metamorphosed to the upper greenschist facies at approximately 516-509 Ma. The protoliths of the meta-sedimentary rocks are graywackes, which are divided into lower, middle and upper units. Detrital zircons from nine samples of the supra-crustal succession have ages ranging from 1182 to 1158 Ma for the lower unit, 957 to 955 Ma for the middle unit and 917 to 840 Ma for the upper unit. The lower unit is intruded by a ca. 960 Ma pluton. The bulk compositions of these meta-sedimentary rocks and their detrital zircon ages clearly indicate derivation from Meso- and Neo-proterozoic granites. Thus, we suggest that the sedimentary succession was derived from an arc-related tectonic setting and that none of the detritus was sourced from the southern margin of the North China Block or from the northern and western margins of the South China Block. We conclude that the North Qinling Belt was an independent micro-continental block during the Meso- to Neo-proterozoic.

Wood-energy: success depends on the price of fossil energies and on the carbon tax level

International Nuclear Information System (INIS)

Defaye, Serge; Maindrault, Marc

2016-01-01

Illustrated by several graphs indicating the structure of fossil energy prices, the comparison between domestic fuel and wood-energy for public network exploitation, the levels of fossil prices and carbon tax for non-subsidised projects, this article analyses the development of biomass (and more particularly wood-energy), the success of which depends on the price of fossil energies and on the carbon tax level. It outlines the differences of price-building elements between fossil and renewable heat, that subsidies are necessary if reference prices are low. It discusses the influence of carbon tax level and of fossil prices. It finally identifies conditions to be met (reduction of fossil energy supply and therefore higher fossil prices, introduction of a carbon tax) to reach COP objectives

Characterization of organic matter associated with uranium deposits in the Francevillian formation of Gabon (Lower Proterozoic)

International Nuclear Information System (INIS)

Cortial, F.; Gauthier-Lafaye, F.; Weber, F.; Oberlin, A.

1990-01-01

Elemental analysis, organic petrography, and high-resolution transmission electron microscopy were used to study organic matter in Lower Proterozoic rocks of the Francevillian Series in Africa. Results show a convincing relationship between solid bitumens derived from thermal alteration of crude oil, and deposition of uraninite ores. Evidence is presented that suggests the presence of migration paths for crude oil in associated sandstones. Moreover, the solid bitumens appear to have been further altered by radiation damage as a consequence of oxidation and uranium mineralization. (author)

Factors controlling accumulation of soil organic carbon along vegetation succession in a typical karst region in Southwest China

Energy Technology Data Exchange (ETDEWEB)

Liu, Shujuan [Key Laboratory of Agro-ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha 410125 (China); Huanjiang Observation and Research Station of Karst Ecosystem, Chinese Academy of Sciences, Huanjiang, Guangxi Zhuang Autonomous Region 547100 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Zhang, Wei [Key Laboratory of Agro-ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha 410125 (China); Huanjiang Observation and Research Station of Karst Ecosystem, Chinese Academy of Sciences, Huanjiang, Guangxi Zhuang Autonomous Region 547100 (China); Wang, Kelin, E-mail: kelin@isa.ac.cn [Key Laboratory of Agro-ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha 410125 (China); Huanjiang Observation and Research Station of Karst Ecosystem, Chinese Academy of Sciences, Huanjiang, Guangxi Zhuang Autonomous Region 547100 (China); Pan, Fujing [Key Laboratory of Agro-ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha 410125 (China); Huanjiang Observation and Research Station of Karst Ecosystem, Chinese Academy of Sciences, Huanjiang, Guangxi Zhuang Autonomous Region 547100 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Yang, Shan [Changsha university, Changsha 410003 (China); Shu, Shiyan [Changjiang Project Supervision & Consultancy Co. Ltd, Wuhan 430010 (China); Changjiang Ecology (Hubei) Technology Development LLC, Wuhan 430010 (China)

2015-07-15

Vegetation succession enhances the accumulation of carbon in the soil. However, little is known about the mechanisms underlying soil organic carbon (SOC) accumulation in different vegetation types in the karst region of Southwest China. The goal of this study was to identify and prioritize the effects of environmental parameters, including soil physico-chemical properties, microbial biomass, enzyme activities, and litter characteristics, on SOC accumulation along a vegetation succession sere (grassland, shrubland, secondary forest, and primary forest) in the karst landscape of Southwest China. Relationships between these parameters and SOC were evaluated by redundancy analysis. The results showed that SOC accumulation was significantly different among vegetation types (P < 0.01) and increased with vegetation succession (from 29.10 g·kg{sup −1} in grassland to 73.92 g·kg{sup −1} in primary forest). Soil biochemistry and physical characteristics significantly affected the accumulation of SOC. Soil microbial biomass showed a predominant effect on SOC in each of the four vegetation types. In addition, the soil physical property (especially the silt content) was another controlling factor in the early stages (grassland), and urease activity and saccharase activity were important controlling factors in the early-middle and middle-late stages, respectively. Litter characteristics only showed mild effects on SOC accumulation. Variation partitioning analysis showed that the contribution of sole main factors to SOC variation decreased, while the interaction effect among parameters increased along the succession gradient. - Highlights: • Vegetation restoration is conducive to soil carbon sequestration in karst areas. • The factors controlling SOC accumulation differed along vegetation succession. • The interaction effect among significant factors became more and more prominent along succession.

Temporal succession in carbon incorporation from macromolecules by particle-attached bacteria in marine microcosms: Particle-attached bacteria incorporating organic carbon

Energy Technology Data Exchange (ETDEWEB)

Mayali, Xavier [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Stewart, Benjamin [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Mabery, Shalini [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Weber, Peter K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2015-12-21

Here, we investigated bacterial carbon assimilation from stable isotope-labelled macromolecular substrates (proteins; lipids; and two types of polysaccharides, starch and cellobiose) while attached to killed diatom detrital particles during laboratory microcosms incubated for 17 days. Using Chip-SIP (secondary ion mass spectrometry analysis of RNA microarrays), we identified generalist operational taxonomic units (OTUs) from the Gammaproteobacteria, belonging to the genera Colwellia, Glaciecola, Pseudoalteromonas and Rheinheimera, and from the Bacteroidetes, genera Owenweeksia and Maribacter, that incorporated the four tested substrates throughout the incubation period. Many of these OTUs exhibited the highest isotope incorporation relative to the others, indicating that they were likely the most active. Additional OTUs from the Gammaproteobacteria, Bacteroidetes and Alphaproteobacteria exhibited generally (but not always) lower activity and did not incorporate all tested substrates at all times, showing species succession in organic carbon incorporation. We also found evidence to suggest that both generalist and specialist OTUs changed their relative substrate incorporation over time, presumably in response to changing substrate availability as the particles aged. This pattern was demonstrated by temporal succession from relatively higher starch incorporation early in the incubations, eventually switching to higher cellobiose incorporation after 2 weeks.

Proterozoic strata-bound uranium deposits of Zambia and Zaire

International Nuclear Information System (INIS)

Meneghel, L.

1984-01-01

The Katanga System, host to uranium and copper mineralisation, is several thousands of metres thick and rests unconformably on an older complex of crystalline rocks and metasediments and is locally covered by Karoo sandstones or Kalahari sands. The deposition of the Katanga System took place during the Late Proterozoic in a wide complex basin extending from Shaba province in Zaire through a large part of Zambia and into eastern Angola. The sediments were affected by different grades of metamorphism, tectonic events, and by thermal events associated with post-tectonic metamorphism. At the base of Katanga system there are 84 known copper deposits and 42 uranium occurrences. It is suggested that all the known uranium and copper occurrences are of an essentially syngenetic sedimentary origin. The mineralisation is found in the Lower Roan Formation near the base of the Katanga System occurring in rocks produced in similar environmental conditions and thus being stratigraphic controlled, however, their areal distribution is localised producing a regional metal zonation. Many of the uranium occurrences have a typical vein aspect. These transgressive relationships are not inconsistent with a syngenetic origin as evidenced by the vein morphology. (author)

Re-Os geochronology of a Mesoproterozoic sedimentary succession, Taoudeni basin, Mauritania: Implications for basin-wide correlations and Re-Os organic-rich sediments systematics

Science.gov (United States)

Rooney, Alan D.; Selby, David; Houzay, Jean-Pierre; Renne, Paul R.

2010-01-01

The exceptionally well-preserved sedimentary rocks of the Taoudeni basin, NW Africa represent one of the world's most widespread (> 1 M km 2) Proterozoic successions. Hitherto, the sedimentary rocks were considered to be Mid Tonian based on Rb-Sr illite and glauconite geochronology of the Atar Group. However, new Re-Os organic-rich sediment (ORS) geochronology from two drill cores indicates that the Proterozoic Atar Group is ˜ 200 Ma older (1107 ± 12 Ma, 1109 ± 22 Ma and 1105 ± 37 Ma). The Re-Os geochronology suggests that the Rb-Sr geochronology records the age of diagenetic events possibly associated with the Pan African collision. The new Re-Os geochronology data provide absolute age constraints for recent carbon isotope chemostratigraphy which suggests that the Atar Group is Mesoproterozoic and not Neoproterozoic. The new Re-Os ORS geochronology supports previous studies that suggest that rapid hydrocarbon generation (flash pyrolysis) from contact metamorphism of a dolerite sill does not significantly disturb the Re-Os ORS systematics. Modelled contact conditions suggest that the Re-Os ORS systematics remain undisturbed at ˜ 650 °C at the sill/shale contact and ≥ 280 °C 20 m from the sill/shale contact. Moreover, the Re-Os geochronology indicates that the West African craton has a depositional history that predates 1100 Ma and that ORS can be correlated on a basin-wide scale. In addition, the Re-Os depositional ages for the ORS of the Taoudeni basin are comparable to those of ORS from the São Francisco craton, suggesting that these cratons are correlatable. This postulate is further supported by identical Os i values for the Atar Group and the Vazante Group of the São Francisco craton.

Geochronology and geochemistry of upper proterozoic granites from Southern Benin

International Nuclear Information System (INIS)

Cordani, U.G.; Kawashita, K.; Vancini, K.R.B.; Cadoppi, P.; Sacchi, R.

1993-01-01

The Upper Proterozoic basement of Benin, like that of nearby Nigeria and like the polycyclic basement of Central Hoggar, belongs to the hinterland of the Pharusian Chain (Pan-African Trans-Saharan Belt) generated by the collision between the (passive) margin of the West African craton and the (reactivated) margin of the Tuareg Shield and its southern extension. Rb-Sr dating of sub alkaline, meta-aluminums, syn-Kinematic granite forming tabular bodies near Dassa-Zoume and near Save yielded two WR isochron ages of 650 ± 35 Ma (I.R. = 0.7043) and 705 ± 70 Ma (I.R. = 0.7045). Emplacement of these bodies was clearly controlled by trans current movements along the Kandi Fault System. The analyzed granites are comparable with those of Central Hoggar and North-Central Nigeria on the ground of field, geochronological and geochemical data; they also display some affinities with the late-tectonic granites of the Adrar des Iforas. They are expected to find their Brazilian continuation in the Chaval Granitoids west of Fortaleza, but data for comparison are inadequate. (author)

Iron-dependent nitrogen cycling in a ferruginous lake and the nutrient status of Proterozoic oceans

Science.gov (United States)

Michiels, Céline C.; Darchambeau, François; Roland, Fleur A. E.; Morana, Cédric; Llirós, Marc; García-Armisen, Tamara; Thamdrup, Bo; Borges, Alberto V.; Canfield, Donald E.; Servais, Pierre; Descy, Jean-Pierre; Crowe, Sean A.

2017-01-01

Nitrogen limitation during the Proterozoic has been inferred from the great expanse of ocean anoxia under low-O2 atmospheres, which could have promoted NO3- reduction to N2 and fixed N loss from the ocean. The deep oceans were Fe rich (ferruginous) during much of this time, yet the dynamics of N cycling under such conditions remain entirely conceptual, as analogue environments are rare today. Here we use incubation experiments to show that a modern ferruginous basin, Kabuno Bay in East Africa, supports high rates of NO3- reduction. Although 60% of this NO3- is reduced to N2 through canonical denitrification, a large fraction (40%) is reduced to NH4+, leading to N retention rather than loss. We also find that NO3- reduction is Fe dependent, demonstrating that such reactions occur in natural ferruginous water columns. Numerical modelling of ferruginous upwelling systems, informed by our results from Kabuno Bay, demonstrates that NO3- reduction to NH4+ could have enhanced biological production, fuelling sulfate reduction and the development of mid-water euxinia overlying ferruginous deep oceans. This NO3- reduction to NH4+ could also have partly offset a negative feedback on biological production that accompanies oxygenation of the surface ocean. Our results indicate that N loss in ferruginous upwelling systems may not have kept pace with global N fixation at marine phosphorous concentrations (0.04-0.13 μM) indicated by the rock record. We therefore suggest that global marine biological production under ferruginous ocean conditions in the Proterozoic eon may thus have been P not N limited.

Carbonate petrography, kerogen distribution, and carbon and oxygen isotope variations in an early Proterozoic transition from limestone to iron-formation deposition, Transvaal Supergroup, South Africa

Science.gov (United States)

Beukes, N. J.; Klein, C.; Kaufman, A. J.; Hayes, J. M.

1990-01-01

The transition zone comprises Campbellrand microbialaminated (replacing "cryptalgalaminate") limestone and shale, with minor dolomite, conformably overlain by the Kuruman Iron Formation of which the basal part is characterized by siderite-rich microbanded iron-formation with minor magnetite and some hematite-containing units. The iron-formation contains subordinate intraclastic and microbialaminated siderite mesobands and was deposited in deeper water than the limestones. The sequence is virtually unaltered with diagenetic mineral assemblages reflecting a temperature interval of about 110 degrees to 170 degrees C and pressures of 2 kbars. Carbonate minerals in the different rock types are represented by primary micritic precipitates (now recrystallized to microsparite), early precompactional sparry cements and concretions, deep burial limpid euhedral sparites, and spar cements precipitated from metamorphic fluids in close contact with diabase sills. Paragenetic pathways of the carbonate minerals are broadly similar in all lithofacies with kerogen intimately associated with them. Kerogen occurs as pigmentation in carbonate crystals, as reworked organic detritus in clastic-textured carbonate units, and as segregations of kerogen pigment around late diagenetic carbonate crystals. Locally kerogen may also be replaced by carbonate spar. Carbon isotope compositions of the carbonate minerals and kerogen are dependent on their mode of occurrence and on the composition of the dominant carbonate species in a specific lithofacies. Integration of sedimentary, petrographic, geochemical, and isotopic results makes it possible to distinguish between depositional, early diagenetic, deep burial, and metamorphic effects on the isotopic compositions of the carbonate minerals and the kerogen in the sequence. Major conclusions are that deep burial thermal decarboxylation led to 13C depletion in euhedral ferroan sparites and 13C enrichment in kerogen (organic carbon). Metamorphic

Geotectonic aspects of the proterozoic triple junction in the center-south part of Goias state

International Nuclear Information System (INIS)

Valente, C.R.

1986-01-01

The scope of this paper is to made up, in a regional synthesis the tectonical framework of intracontinental proterozoic rifts, from the point of view of an evolutive model through plate tectonic mechanism. based upon lithoenvironment and geotectonics. In this context, this analysis take into account the tectonical interpretation and typification of Canastra, Cuiaba, Estrondo and Tocantins Groups. Structurally these geological entities are found to be settled in rifts of triple junction, in the center-south part of Goias State, individualized among the Oriental Plate (Sao Francisco Craton and Goias Central Massif) Occidental Plate (Amazonic Craton) and Meridional Plate (Paramirim Craton and Parana Block). (author)

Calcium Isotope Systematics of Diagenetically Altered Carbonates: Example from the Proterozoic Carbonates of Transvaal Supergroup, South Africa

Science.gov (United States)

Farkas, J.; Jacobsen, S.; Frauenstein, F.; Veizer, J.

2008-12-01

We analyzed mass-dependent (δ44/40Ca) and radiogenic (ɛCa) calcium isotope variations of diagenetically altered carbonates collected from the Duitschland Formation (~2.45 Ga) of the Transvaal Supergroup in a vicinity of the younger Bushveld Igneous Complex (Frauenstein, 2005, PhD Thesis, Ruhr Univ. Bochum). Textural, trace element and isotope data measured on these samples provide convincing evidence for extensive post-depositional alteration and diagenetic resetting. Samples selected for the Ca isotope study have Mn/Sr ratios from 0.8 to 33, 87Sr/86Sr from 0.704 to 0.719 and their δ18O and δ18C scatter from -20 to -2.8‰ and from 9.7 to -1.1‰, respectively. The δ44/40Ca (NIST) of carbonates range from 0.3 to 1.3‰ and their ɛCa indicate no radiogenic 40Ca excesses larger than the analytical uncertainty of ~1.5 ɛ-unit, confirming that the δ44/40Ca variation is exclusively due to mass-dependent fractionation. There is a difference between δ44/40Ca of limestones and dolostones, the former range from ~0.3 to 1.2‰ and the latter cluster tightly around 1.1. Using Mn/Sr as an index for diagenetic alteration (Brand and Veizer, 1980, J. Sed. Petrol., 50, 1219-1236) the δ44/40Ca of limestones becomes progressively heavier with an increasing degree of alteration (δ44/40Ca vs. Mn/Sr, r = .84, p element data. Finally, we propose that in a suite of coeval marine limestones, samples with the lowest δ44/40Ca, Mn/Sr and 87Sr/86Sr should, in most cases, represent the least altered components.

A note on coarse-grained gravity-flow deposits within proterozoic lacustrine sedimentary rocks, Transvaal sequence, South Africa

Science.gov (United States)

Eriksson, P. G.

A widely developed, thin, coarse-matrix conglomerate occurs within early Proterozoic lacustrine mudrocks in the Transvaal Sequence, South Africa. The poorly sorted tabular chert clasts, alternation of a planar clast fabric with disorientated zones, plus normal and inverse grading in the former rock type suggest deposition by density-modified grain-flow and high density turbidity currents. The lower fan-delta slope palæenvironment inferred for the conglomerate is consistent with the lacustrine interpretation for the enclosing mudrock facies. This intracratonic setting contrasts with the marine environment generally associated with density-modified grain-flow deposits.

Geology and recognition criteria for veinlike uranium deposits of the lower to middle Proterozoic unconformity and strata-related types. Final report

International Nuclear Information System (INIS)

Dahlkamp, F.J.; Adams, S.S.

1981-01-01

The discovery of the Rabbit Lake deposit, Saskatchewan, in 1968 and the East Alligator Rivers district, Northern Territory, Australia, in 1970 established the Lower-Middle Proterozoic veinlike-type deposits as one of the major types of uranium deposits. The term veinlike is used in order to distinguish it from the classical magmatic-hydrothermal vein or veintype deposits. The veinlike deposits account for between a quarter and a third of the Western World's proven uranium reserves. Lower-Middle Proterozoic veinlike deposits, as discussed in this report include several subtypes of deposits, which have some significantly different geologic characteristics. These various subtypes appear to have formed from various combinations of geologic processes ranging from synsedimentary uranium precipitation through some combination of diagenesis, metamorphism, metasomatism, weathering, and deep burial diagenesis. Some of the deposit subtypes are based on only one or two incompletely described examples; hence, even the classification presented in this report may be expected to change. Geologic characteristics of the deposits differ significantly between most districts and in some cases even between deposits within districts. Emphasis in this report is placed on deposit descriptions and the interpretations of the observers

Geology and recognition criteria for veinlike uranium deposits of the lower to middle Proterozoic unconformity and strata-related types. Final report

Energy Technology Data Exchange (ETDEWEB)

Dahlkamp, F.J.; Adams, S.S.

1981-01-01

The discovery of the Rabbit Lake deposit, Saskatchewan, in 1968 and the East Alligator Rivers district, Northern Territory, Australia, in 1970 established the Lower-Middle Proterozoic veinlike-type deposits as one of the major types of uranium deposits. The term veinlike is used in order to distinguish it from the classical magmatic-hydrothermal vein or veintype deposits. The veinlike deposits account for between a quarter and a third of the Western World's proven uranium reserves. Lower-Middle Proterozoic veinlike deposits, as discussed in this report include several subtypes of deposits, which have some significantly different geologic characteristics. These various subtypes appear to have formed from various combinations of geologic processes ranging from synsedimentary uranium precipitation through some combination of diagenesis, metamorphism, metasomatism, weathering, and deep burial diagenesis. Some of the deposit subtypes are based on only one or two incompletely described examples; hence, even the classification presented in this report may be expected to change. Geologic characteristics of the deposits differ significantly between most districts and in some cases even between deposits within districts. Emphasis in this report is placed on deposit descriptions and the interpretations of the observers.

Magmatism and underplating, a broadband seismic perspective on the Proterozoic tectonics of the Great Falls and Snowbird Tectonic Zones

Science.gov (United States)

Chen, Y.; Gu, Y. J.; Dokht, R.; Wang, R.

2017-12-01

The crustal and lithospheric structures beneath the Western Canada Sedimentary Basin (WCSB) and northern Montana contain vital records of the Precambrian tectonic development of Laurentia. In this study, we analyze the broadband seismic data recorded by the USArray and the most complete set of regional seismic networks to date near the WCSB. We adopt an integrated approach to investigate crustal structure and history, based primarily on P-to-S receiver functions but incorporate results from noise correlation functions, finite-frequency tomography and potential field measurements. In comparison with existing regional and global models, our stacked receiver functions show considerable improvements in the resolution of both Moho depth and Vp/Vs ratio. We identify major variations in Moho depth from the WCSB to the adjacent Cordillera. The Moho deepens steeply from 40 km in the Alberta basin to 50 km beneath the foothills, following Airy isostasy, but thermal buoyancy may be responsible for a flat, shallow ( 35 km) Moho to the west of the Rocky Mountain Trench. The Moho depth also increases sharply near the Snowbird Tectonic Zone (STZ), which is consistent with earlier findings from active-source data. Multiple lower crustal phases, a high velocity shallow mantle and elevated Vp/Vs ratios along the westernmost STZ jointly suggest major Proterozoic subduction and magmatism along this collisional boundary. In northern Montana, the Moho deepens along the Great Falls Tectonic Zone (GFTZ), a proposed Proterozoic suture between the Medicine Hat Block and Wyoming craton. This transition occurs near the Little Belt Mountain, which is located south of the Great Falls Shear Zone, an extensive northeast striking fault system characterized by strong potential field gradients. Similar to the STZ, our receiver functions offer new evidence for Proterozoic underplating in the vicinity of the GFTZ. In view of similar rock ages near the collisional boundaries in all parts of northern

Proterozoic to Quaternary events of fracture mineralisation and oxidation in SE Sweden

International Nuclear Information System (INIS)

Drake, Henrik

2008-12-01

Fracture minerals and altered wall rock have been analysed to reveal the low-temperature evolution, especially regarding redox conditions, of the Simpevarp area, SE Sweden. This area is one of the two areas in Sweden investigated by the Swedish Nuclear fuel and Waste Management Co. in order to find a potential geological repository for spent nuclear fuel. The 1.8 Ga granitic to dioritic rocks in the area are generally un-metamorphosed and structurally well-preserved, although low-grade ductile shear zones and repeatedly reactivated fractures exist. Investigations of cross-cutting fractures along with a wide variety of fracture mineral analyses, such as stable isotopes and 40Ar/39Ar geochronology, have been used to distinguish a sequence of fracture filling generations. The characteristics of these generations indicate the low-temperature evolution of the area, including information of e.g. fluid origin, formation temperature, paleo stresses and relation to known geological events. Knowledge of the fracture mineral evolution is important for the conceptual geological and hydrogeochemical understanding of the site and supports predictions of future scenarios in the safety assessment. The fracture mineral generations identified have been formed at widely varying conditions starting in the Proterozoic with formation from inorganic hydrothermal fluids, continuing in the Paleozoic with formation from lower temperature brine type fluids with organic influence, and ranging into minerals formed from waters of varying salinity and with significant organic influence at conditions similar to the present conditions. However, the amount of potentially recent precipitates is very small compared to Proterozoic and Paleozoic precipitates. The fracture mineral parageneses have been associated, with varying confidence, to far-field effects of at least four different orogenies; the Svecokarelian orogeny (>1.75 Ga), the Danapolonian orogeny (∼1.47-1.44 Ga), the Sveconorwegian orogeny

Geochronology of La Tinta Upper Proterozoic sedimentary rocks, Argentina

International Nuclear Information System (INIS)

Cingolani, C.A.; Bonhomme, M.G.

1982-01-01

Olavarria-Sierras Bayas, Barker-San Manuel and Balcarce-Mar del Plata fine-grained sedimentary rocks from La Tinta Formation, the pre-Cenozoic cover of the Tandilia region, were studied using the Rb-Sr and K-Ar geochronology. The mineralogical study of the fine fraction has shown that only the Olavarria-Sierras Bayas area presents suitable material comprising typical sedimentary clays, affected only by diagenetic processes. Two Rb-Sr isochrons were obtained from Olavarria-Sierras Bayas rocks. They show: (1) an age of 769 +- 12 Ma with ( 87 Sr/ 86 Sr) 0 = 0.7121 +- 0.0005, for Aust Quarry rocks; and (2) an age of 723 +- 21 Ma with ( 87 Sr/ 86 Sr) 0 = 0.7171 +- 0.0012 for Cerro Negro and Losa Quarries rocks. Considering the above-mentioned isochron data and the mineralogy of the clays studied, the conclusion is drawn that the ages obtained reflect the isotopic setting of a late diagenetic process, dated back to nearly 720 Ma. K-Ar data also support the Rb-Sr isochrons and the late diagenetic clay origin. The lower section of La Tinta sequence in the Sierras Bayas area must then be considered as Upper Proterozoic in age. These new data support the recently reported stratigraphical divisions and ages. (Auth.)

A case of remnant pancreatic cancer after pancreatoduodenectomy successfully treated using chemotherapy and carbon-ion radiotherapy

International Nuclear Information System (INIS)

Yamamoto, Tatsuhito; Tokunou, Kazuhisa; Yamamoto, Hisato; Kamei, Ryoji; Kitamura, Yoshinori; Ando, Seiichiro

2016-01-01

We report a case of remnant pancreatic cancer after pancreatoduodenectomy that was successfully treated using chemotherapy and carbon-ion radiotherapy. A 68-year-old woman received SSPPD for pancreatic head cancer. Gemcitabine (GEM) was administered for a year as postoperative chemotherapy. One year 8 months after surgery, abdominal CT showed a 20 mm solid mass in the stump of the remnant pancreas and dilation of the distal pancreatic duct. FDG-PET revealed a solitary tumor without any recurrence. We diagnosed the patient with a solitary recurrence of pancreatic cancer. Chemotherapy (GEM) and carbon-ion radiotherapy were performed. After treatment, the lesion was not detected on CT or FDG-PET. Chemotherapy (GEM) and carbon-ion radiotherapy for locally advanced pancreatic cancer seems to be effective and there might result in a survival benefit. (author)

Proterozoic intracontinental basin succession in the western margin of the São Francisco Craton: Constraints from detrital zircon geochronology

Science.gov (United States)

Martins-Ferreira, Marco Antonio Caçador; Chemale, Farid, Jr.; Dias, Airton Natanael Coelho; Campos, José Eloi Guimarães

2018-01-01

former members to formation status, representing an individual sag-type basin, different from the Araí rift-type basin. We also propose to combine the three Proterozoic intracontinental extensional pulses (which generated the Araí, Traíras and Paranoá groups) as the Veadeiros Supergroup, respectively chronocorrelated to the lower, middle and upper Espinhaço Supergroup, located at the SFC eastern margin.

The role of microbial iron reduction in the formation of Proterozoic molar tooth structures

Science.gov (United States)

Hodgskiss, Malcolm S. W.; Kunzmann, Marcus; Poirier, André; Halverson, Galen P.

2018-01-01

Molar tooth structures are poorly understood early diagenetic, microspar-filled voids in clay-rich carbonate sediments. They are a common structure in sedimentary successions dating from 2600-720 Ma, but do not occur in rocks older or younger, with the exception of two isolated Ediacaran occurrences. Despite being locally volumetrically significant in carbonate rocks of this age, their formation and disappearance in the geological record remain enigmatic. Here we present iron isotope data, supported by carbon and oxygen isotopes, major and minor element concentrations, and total organic carbon and sulphur contents for 87 samples from units in ten different basins spanning ca. 1900-635 Ma. The iron isotope composition of molar tooth structures is almost always lighter (modal depletion of 2‰) than the carbonate or residue components in the host sediment. We interpret the isotopically light iron in molar tooth structures to have been produced by dissimilatory iron reduction utilising Fe-rich smectites and Fe-oxyhydroxides in the upper sediment column. The microbial conversion of smectite to illite results in a volume reduction of clay minerals (∼30%) while simultaneously increasing pore water alkalinity. When coupled with wave loading, this biogeochemical process is a viable mechanism to produce voids and subsequently precipitate carbonate minerals. The disappearance of molar tooth structures in the mid-Neoproterozoic is likely linked to a combination of a decrease in smectite abundance, a decline in the marine DIC reservoir, and an increase in the concentration of O2 in shallow seawater.

Permissive tracts for sediment-hosted lead-zinc-silver deposits in the Islamic Republic of Mauritania (phase V, deliverable 73): Chapter J in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

Science.gov (United States)

Mauk, Jeffrey L.

2015-01-01

Although Mississippi Valley-type (MVT) deposits have not been recognized in Mauritania there are permissive tracts for these deposits in the regionally extensive Proterozoic carbonate rocks of the Taoudeni Basin. Permissive tracts for undiscovered MVT Pb-Zn-Ag deposits in the Proterozoic carbonate units are supported by the occurrences of MVT mineral and alteration assemblages, presence of evaporites, proximity to major orogenic events that have produced MVT ores elsewhere, red bed sequences and basal aquifers that may have been potential brine migration pathways for large MVT hydrothermal systems.

Architectural elements from Lower Proterozoic braid-delta and high-energy tidal flat deposits in the Magaliesberg Formation, Transvaal Supergroup, South Africa

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Eriksson, Patrick G.; Reczko, Boris F. F.; Jaco Boshoff, A.; Schreiber, Ute M.; Van der Neut, Markus; Snyman, Carel P.

1995-06-01

Three architectural elements are identified in the Lower Proterozoic Magaliesberg Formation (Pretoria Group, Transvaal Supergroup) of the Kaapvaal craton, South Africa: (1) medium- to coarse-grained sandstone sheets; (2) fine- to medium-grained sandstone sheets; and (3) mudrock elements. Both sandstone sheet elements are characterised by horizontal lamination and planar cross-bedding, with lesser trough cross-bedding, channel-fills and wave ripples, as well as minor desiccated mudrock partings, double-crested and flat-topped ripples. Due to the local unimodal palaeocurrent patterns in the medium- to coarse-grained sandstone sheets, they are interpreted as ephemeral braid-delta deposits, which were subjected to minor marine reworking. The predominantly bimodal to polymodal palaeocurrent trends in the fine- to medium-grained sandstone sheets are inferred to reflect high-energy macrotidal processes and more complete reworking of braid-delta sands. The suspension deposits of mudrocks point to either braid-delta channel abandonment, or uppermost tidal flat sedimentation. The depositional model comprises ephemeral braid-delta systems which debouched into a high-energy peritidal environment, around the margins of a shallow epeiric sea on the Kaapvaal craton. Braid-delta and tidal channel dynamics are inferred to have been similar. Fine material in the Magaliesberg Formation peritidal complexes indicates that extensive aeolian removal of clay does not seem applicable to this example of the early Proterozoic.

Sedimentary petrography of the Early Proterozoic Pretoria Group, Transvaal Sequence, South Africa: implications for tectonic setting

Science.gov (United States)

Schreiber, U. M.; Eriksson, P. G.; van der Neut, M.; Snyman, C. P.

1992-11-01

Sandstone petrography, geochemistry and petrotectonic assemblages of the predominantly clastic sedimentary rocks of the Early Proterozoic Pretoria Group, Transvaal Sequence, point to relatively stable cratonic conditions at the beginning of sedimentation, interrupted by minor rifting events. Basement uplift and a second period of rifting occurred towards the end of Pretoria Group deposition, which was followed by the intrusion of mafic sill swarms and the emplacement of the Bushveld Complex in the Kaapvaal Craton at about 2050 Ma, the latter indicating increased extensional tectonism, and incipient continental rifting. An overall intracratonic lacustrine tectonic setting for the Pretoria Group is supported by periods of subaerial volcanic activity and palaeosol formation, rapid sedimentary facies changes, significant arkosic sandstones, the presence of non-glacial varves and a highly variable mudrock geochemistry.

Sedimentology and stratigraphy of Neoproterozoic-lower Paleozoic carbonate-siliciclastic succession of the southwesternmost Amazon Craton, state of Rondônia, Brazil

OpenAIRE

Afonso, Jhon Willy Lopes; Nogueira, Afonso César Rodrigues

2018-01-01

ABSTRACT: Facies and stratigraphic analysis were carried out in Neoproterozoic-Lower Paleozoic carbonate-siliciclastic deposits of Cacoal and Pimenta Bueno formations exposed on basement rocks and into the Pimenta Bueno Graben, northwestern portion of Parecis Basin, southwesternmost Amazon Craton. The redescription and redefinion of this succession confirmed the previous interpretation for the Cacoal Formation as a Marinoan (~ 635 Ma) cap carbonate. The Cacoal Formation is subdivided here in ...

δ13C chemostratigraphy in the upper Tremadocian through lower Katian (Ordovician carbonate succession of the Siljan district, central Sweden

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Oliver Lehnert

2014-12-01

Full Text Available Based on δ13C data from two drillcores recovered from the Siljan district, we present a first continuous carbon isotope record of the upper Tremadocian–lower Katian limestone succession of central Sweden. New names for some isotopic carbon excursions from the Cambrian–Ordovician boundary through the basal Darriwilian are introduced. The Mora 001 core from the western part of the Siljan impact structure ranges through the Lower–Middle Ordovician, whereas the Solberga 1 core from its eastern part ranges through the Middle–lower Upper Ordovician. Upper Tremadocian and Floian units are extremely condensed and include extensive stratigraphic gaps. Multiple hardgrounds, sometimes with minor karstic overprint, imply recurrent periods of erosion and/or non-deposition. Like in other parts of Sweden, the Dapingian and Darriwilian succession is characterized by a relatively complete sedimentary record and low sedimentation rates.

River Valley pluton, Ontario - A late-Archean/early-Proterozoic anorthositic intrusion in the Grenville Province

Science.gov (United States)

Ashwal, Lewis D.; Wooden, Joseph L.

1989-01-01

This paper presents Nd, Sr, and Pb isotopic data indicating a late-Archean/early-Proterozoic age for the River Valley anorthositic pluton of the southwestern Grenville Province of Sudbury, Ontario. Pb-Pb isotopic data on 10 whole-rock samples ranging in composition from anorthosite to gabbro yield an age of 2560 + or - 155 Ma. The River Valley pluton is thus the oldest anorthositic intrusive yet recognized within the Grenville Province. The Sm-Nd isotopic system records an age of 2377 + or - 68 Ma. High Pb-208/Pb-204 of deformed samples relative to igneous-textured rocks implies Th introduction and/or U loss during metamorphism in the River Valley area. Rb-Sr data from igneous-textured and deformed samples and from mineral separates give an age of 2185 + or - 105 Ma, indicating substantial disturbance of the Rb-Sr isotopic system.

A deposit model for magmatic iron-titanium-oxide deposits related to Proterozoic massif anorthosite plutonic suites

Science.gov (United States)

Woodruff, Laurel G.; Nicholson, Suzanne W.; Fey, David L.

2013-01-01

This descriptive model for magmatic iron-titanium-oxide (Fe-Ti-oxide) deposits hosted by Proterozoic age massif-type anorthosite and related rock types presents their geological, mineralogical, geochemical, and geoenvironmental attributes. Although these Proterozoic rocks are found worldwide, the majority of known deposits are found within exposed rocks of the Grenville Province, stretching from southwestern United States through eastern Canada; its extension into Norway is termed the Rogaland Anorthosite Province. This type of Fe-Ti-oxide deposit dominated by ilmenite rarely contains more than 300 million tons of ore, with between 10- to 45-percent titanium dioxide (TiO2), 32- to 45-percent iron oxide (FeO), and less than 0.2-percent vanadium (V). The origin of these typically discordant ore deposits remains as enigmatic as the magmatic evolution of their host rocks. The deposits clearly have a magmatic origin, hosted by an age-constrained unique suite of rocks that likely are the consequence of a particular combination of tectonic circumstances, rather than any a priori temporal control. Principal ore minerals are ilmenite and hemo-ilmenite (ilmenite with extensive hematite exsolution lamellae); occurrences of titanomagnetite, magnetite, and apatite that are related to this deposit type are currently of less economic importance. Ore-mineral paragenesis is somewhat obscured by complicated solid solution and oxidation behavior within the Fe-Ti-oxide system. Anorthosite suites hosting these deposits require an extensive history of voluminous plagioclase crystallization to develop plagioclase-melt diapirs with entrained Fe-Ti-rich melt rising from the base of the lithosphere to mid- and upper-crustal levels. Timing and style of oxide mineralization are related to magmatic and dynamic evolution of these diapiric systems and to development and movement of oxide cumulates and related melts. Active mines have developed large open pits with extensive waste-rock piles, but

Process Parameters for Successful Synthesis of Carbon Nanotubes by Chemical Vapor Deposition: Implications for Chemical Mechanisms and Life-cycle Assessment

Science.gov (United States)

Xue, Ke

Manufacturing of carbon nanotubes (CNTs) via chemical vapor deposition (CVD) calls for thermal treatment associated with gas-phase rearrangement and catalyst deposition to achieve high cost efficiency and limited influence on environmental impact. Taking advantage of higher degree of structure control and economical efficiency, catalytic chemical vapor deposition (CCVD) has currently become the most prevailing synthesis approach for the synthesis of large-scale pure CNTs in past years. Because the synthesis process of CNTs dominates the potential ecotoxic impacts, materials consumption, energy consumption and greenhouse gas emissions should be further limited to efficiently reduce life cycle ecotoxicity of carbon naotubes. However, efforts to reduce energy and material requirements in synthesis of CNTs by CCVD are hindered by a lack of mechanistic understanding. In this thesis, the effect of operating parameters, especially the temperature, carbon source concentration, and residence time on the synthesis were studied to improve the production efficiency in a different angle. Thus, implications on the choice of operating parameters could be provided to help the synthesis of carbon nanotubes. Here, we investigated the typical operating parameters in conditions that have yielded successful CNT production in the published academic literature of over seventy articles. The data were filtered by quality of the resultant product and deemed either "successful" or "unsuccessful" according to the authors. Furthermore, growth rate data were tabulated and used as performance metric for the process whenever possible. The data provided us an opportunity to prompt possible and common methods for practioners in the synthesis of CNTs and motivate routes to achieve energy and material minimization. The statistical analysis revealed that methane and ethylene often rely on thermal conversion process to form direct carbon precursor; further, methane and ethylene could not be the direct

Post-Panafrican late Proterozoic basins in the Central Anti-Atlas (Morocco): their influence on the Variscan contractional structures.

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Guimerà, Joan; Arboleya, María. Luisa

2010-05-01

Located South of the High Atlas, in Morocco, The Anti-Atlas is a 700 km-long chain trending NE-SW. In the Central Anti-Atlas region, between Warzazat and Taznakht, the Proterozoic Pan-African basement (X1 to X2-3) crops out in isolated areas (boutonnières), where it is overlaid by late to post Pan-African Upper Proterozoic and Palaeozoic rocks. Late to post Pan-African Upper Proterozoic rocks (X3) have been classically divided into three units (X3i, X3m and X3s) which include volcanic rocks — mainly rhyolites— and continental siliciclastic rocks, the older units intruded by late granites (Choubert, 1952 and Choubert et al., 1970). Rocks belonging to the upper unit of post Pan-African Upper Proterozoic rocks (X3s) were deposited in basins bounded by faults with a dominant dip-slip normal motion; as a result, this unit have a variable thickness, being locally absent in the uplifted blocks. Uppermost Proterozoic (Adoudounian) and Palaeozoic rocks deposited unconformable on the older rocks in the Anti-Atlas. The Central Anti-Atlas was slightly deformed during the Variscan orogeny by folds and high-angle thrusts. Two areas are selected to study the post Pan-African to Variscan evolution of the area: the Tiwiyyine basin and the Anti-Atlas Major Fault. Tiwiyyine basin This basin is delimited by kilometric-scale normal faults. Three of them can be observed in the field: two striking NE-SW (NW and SE boundaries) and one striking NW-SE (SW boundary), while the NE boundary is covered by Cenozoic rocks. The basin fill reaches 725 m and has been divided into three units: 1. X3s1: Coarse conglomerates with basal breccias. 2. X3s2: Laminated dolomites at the base, red pelites and conglomerates. 3. X3s3: Conglomerates with interbedded andesites. Unit X3s2 passes laterally to the SW to unit X3s1. The thickness of the basin fill diminishes to the SE. This is specially visible at the basal X3s1 unit. At both sides of the two NE-SW-striking faults, only the upper X3s3 unit is

Ages of detrital zircon from siliciclastic sucessions of the Brasilia belt, southern border of Sao Francisco craton: Implications for the evolution of proterozoic basins

International Nuclear Information System (INIS)

Valladares, C.S; Machado, N; Ribeiro, A.; Paciullo, F.V.P; Heilbron, M; Gauthier, G

2001-01-01

The determination of the age distribution of detrital zircon suites from greenschist and amphibolite facies metassedimentary rocks using 207 Pb/ 206 Pb laser-ablation inductively couple plasma mass spectometry (LA-ICPMS) was previously discussed by Machado and Gauthier (1996) and is an useful tool on determinating the ages interval of the source area. Although 207 Pb/ 206 Pb ages are, in principle, mimimum ages, Feng et al. (1993) and Machado and Gauthier (1996) showed that these ages are identical within error to U-Pb ages. The advantage of the method for sedimentary provenance studies is that the number of grains that can be analysed per day (ca. 50) on the same sample, providing a stastically meaningful age distribution. The most significant limitations of the method used in this work are the inability to yield reliable U-Pb values and the large analytical error of, at least, 1-10%. Neverthless, in provenance studies high precision are not required. In this work we report ages of detrital zircon from from lower greenschist metamorphic facies quartzites from the Proterozoic Sao Joao del Rei and Andrelandia basin successions. The data yield information about the ages of the source areas and provide an approach for constraining sedimentation ages in these basins (au)

Tunable Graphitic Carbon Nano-Onions Development in Carbon Nanofibers for Multivalent Energy Storage

Energy Technology Data Exchange (ETDEWEB)

Schwarz, Haiqing L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2016-01-01

We developed a novel porous graphitic carbon nanofiber material using a synthesis strategy combining electrospinning and catalytic graphitization. RF hydrogel was used as carbon precursors, transition metal ions were successfully introduced into the carbon matrix by binding to the carboxylate groups of a resorcinol derivative. Transition metal particles were homogeneously distributed throughout the carbon matrix, which are used as in-situ catalysts to produce graphitic fullerene-like nanostructures surrounding the metals. The success design of graphitic carbons with enlarged interlayer spacing will enable the multivalent ion intercalation for the development of multivalent rechargeable batteries.

Upper Proterozoic (1800-570 Ma) stratigraphy: a survey of lithostratigraphic, paleontological, radiochronological and magnetic correlations

International Nuclear Information System (INIS)

Trompette, R.

1982-01-01

Classical stratigraphy which was conceived in relation to the Phanerozoic, can be extended into the Precambrian, particularly the upper part. Stromatolite biostratigraphy provides natural subdivisions of the Upper Proterozoic, as indicated by studies on the Riphean of the U.S.S.R. The correlation techniques are identical to those used in the Phanerozoic. Imperfections in the biostratigraphic record, however, have encouraged the development of lithostratigraphic, radiochronological and paleomagnetic techniques. The possibility of dating argillaceous sedimentary rocks largely depends on the care taken in the selection of samples. The samples should have the necessary mineralogy and should not contain inherited 40 Ar or 87 Sr. Good results have been obtained on glauconites rich in K 2 O and particularly on illite and smectite, using the Rb-Sr method. Geochronology is the most precise of the four methods of correlation considered. It also provides a framework on which to hang the results of lithostratigraphy and magnetostratigraphy. (Auth.)

The palaeoenvironmental implications of carbonate petrography, kerogen distribution and carbon and oxygen isotope variations in the early Proterozoic transition from Campbellrand limestone to Kuruman iron-formation deposition in Griqualand West

International Nuclear Information System (INIS)

Beukes, N.J.; Klein, C.; Kaufman, A.J.; Hayes, J.M.

1990-01-01

The Griqualand West area of the Transvaal basin in South Africa offers a unique opportunity to study the relationships between the deposition of limestone and iron-formation. The stratigraphic sequence includes the transition from microbialaminated Campbellrand carbonates to the conformably Kuruman iron formation composed mainly of microbanded iron-formation. The relationships between carbonate mineral paragenesis, kerogen abundance, and isotopic compositions of carbon and oxygen for the same drill core samples are reported. The significance of whole rock carbon-isotopic compositions of iron-formations relative to those of limestones and dolomites are explored. 6 refs

Archean and proterozoic in the West-European Hercynian chain: isotopic geochemistry (Sr-Nd-Pb) and U-Pb geochronology on zircons

International Nuclear Information System (INIS)

Guerrot, C.

1989-01-01

The first part of this research thesis reports the study of isotopic (Sr-Nd-Pb) geochemistry and U-Pb geochronology on zircons in the immersed granulites of the Bay of Biscay: U-Pb geochronology on zircons, Nd isotopic geochemistry, Sr isotopic geochemistry, common Pb, Rb-Sr, Sm-Nd and rare earth data on minerals, comparison with other European granulites, comparison with West-Africa, study of Archean and proterozoic in the Hercynian chain. The second part reports the study of the U-Pb geochronology on zircon in the Cadomian, and the third part addresses the Sr-Nd isotopic geochemistry of some Cadomian granitoid, and the crust contamination in different regions [fr

Uranium in early proterozoic phosphate-rich metasedimentary rocks of east-central Minnesota

International Nuclear Information System (INIS)

McSwiggen, P.L.; Morey, G.B.; Weiblen, P.W.

1986-01-01

Exploration for unconformity-type uranium deposits in the late 1970s in east-central Minnesota led to the discovery of several uranium-bearing phosphorite occurrences in rocks of early Proterozoic age. In this report the authors use the term phosphorite for a rock or specimen that contains substantial sedimentary apatite (Altschuler et al., 1958). The deposits in Minnesota are especially interesting because of their high uranium content but low metamorphic grade. These occurrences characteristically contain 0.025 to 0.085 percent U and locally as much as 0.157 percent U (Ullmer, 1981), whereas typical primary marine phosphorites have uranium contents of 0.005 to 0.02 percent U (Altschuler et al., 1958). The presence of uranium in a marine phosphorite generally is explained by either the replacement of calcium in the apatite crystal structure or the adsorption of uranium in admixed organic matter and cryptocrystalline apatite. In east-central Minnesota the uranium is closely associated with the finely crystalline apatite, but the uranium has also been involved in several episodes of remobilization and redeposition. Thus, even though the phosphorite deposits are an interesting geologic phenomenon in themselves, they also are important as a possible source for epigenetic uranium deposits that may occur in the area

New paleomagnetic data from Siberia: Non-uniformitarian geomagnetic field around the Proterozoic-Phanerozoic boundary?

Science.gov (United States)

Pavlov, V.; Shatsillo, A.; Kouznetsov, N.; Gazieva, E.

2017-12-01

There is a range of evidence, mainly from sedimentary and volcanic rocks of the Laurentia and Baltica cratons, that argue for the anomalous character of the Ediacaran-Early Cambrian paleomagnetic record. This feature could be linked either to some peculiarities of the paleomagnetic record itself or to some unusual geophysical event that would have taken place around the Proterozoic-Phanerozoic boundary (e.g., true polar wander or nonuniformitarian geomagnetic field behavior). In the latter case, the traces of this event should be observed in Ediacaran-Early Cambrian rocks anywhere there is a possibility to observe a primary paleomagnetic signal. In previous work, we reported results that suggested an anomalous paleomagnetic record in Siberian Ediacaran-Lower Cambrian rocks. Here we present new Siberian data that indicate a very high geomagnetic reversal frequency during this period and the coexistence of two very different paleomagnetic directions. We speculate that these features could be due either to a near-equatorial geomagnetic dipole during the polarity transitions or to alternation between axial and near equatorial dipoles not directly linked with polarity reversals.

Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age

Science.gov (United States)

Johnston, D. T.; Wolfe-Simon, F.; Pearson, A.; Knoll, A. H.

2009-01-01

Molecular oxygen (O2) began to accumulate in the atmosphere and surface ocean ca. 2,400 million years ago (Ma), but the persistent oxygenation of water masses throughout the oceans developed much later, perhaps beginning as recently as 580–550 Ma. For much of the intervening interval, moderately oxic surface waters lay above an oxygen minimum zone (OMZ) that tended toward euxinia (anoxic and sulfidic). Here we illustrate how contributions to primary production by anoxygenic photoautotrophs (including physiologically versatile cyanobacteria) influenced biogeochemical cycling during Earth's middle age, helping to perpetuate our planet's intermediate redox state by tempering O2 production. Specifically, the ability to generate organic matter (OM) using sulfide as an electron donor enabled a positive biogeochemical feedback that sustained euxinia in the OMZ. On a geologic time scale, pyrite precipitation and burial governed a second feedback that moderated sulfide availability and water column oxygenation. Thus, we argue that the proportional contribution of anoxygenic photosynthesis to overall primary production would have influenced oceanic redox and the Proterozoic O2 budget. Later Neoproterozoic collapse of widespread euxinia and a concomitant return to ferruginous (anoxic and Fe2+ rich) subsurface waters set in motion Earth's transition from its prokaryote-dominated middle age, removing a physiological barrier to eukaryotic diversification (sulfide) and establishing, for the first time in Earth's history, complete dominance of oxygenic photosynthesis in the oceans. This paved the way for the further oxygenation of the oceans and atmosphere and, ultimately, the evolution of complex multicellular organisms. PMID:19805080

Could a secular increase in organic burial explain the rise of oxygen? Insights from a geological carbon cycle model constrained by the carbon isotope record

Science.gov (United States)

Krissansen-Totton, J.; Kipp, M.; Catling, D. C.

2017-12-01

Geochemistry (2nd. Ed.), H. D. Holland, K. K. Turekian, Eds. (Elsevier, Oxford, 2014), 239-249. [2] S. J. Daines, B. J. W. Mills, and T. M. Lenton, Atmospheric oxygen regulation at low Proterozoic levels by incomplete oxidative weathering of sedimentary organic carbon, Nat. Commun. 8 (2017): 14379.

High-Melt Carbon-Carbon Coating for Nozzle Extensions

Science.gov (United States)

Thompson, James

2015-01-01

Carbon-Carbon Advanced Technologies, Inc. (C-CAT), has developed a high-melt coating for use in nozzle extensions in next-generation spacecraft. The coating is composed primarily of carbon-carbon, a carbon-fiber and carbon-matrix composite material that has gained a spaceworthy reputation due to its ability to withstand ultrahigh temperatures. C-CAT's high-melt coating embeds hafnium carbide (HfC) and zirconium diboride (ZrB2) within the outer layers of a carbon-carbon structure. The coating demonstrated enhanced high-temperature durability and suffered no erosion during a test in NASA's Arc Jet Complex. (Test parameters: stagnation heat flux=198 BTD/sq ft-sec; pressure=.265 atm; temperature=3,100 F; four cycles totaling 28 minutes) In Phase I of the project, C-CAT successfully demonstrated large-scale manufacturability with a 40-inch cylinder representing the end of a nozzle extension and a 16-inch flanged cylinder representing the attach flange of a nozzle extension. These demonstrators were manufactured without spalling or delaminations. In Phase II, C-CAT worked with engine designers to develop a nozzle extension stub skirt interfaced with an Aerojet Rocketdyne RL10 engine. All objectives for Phase II were successfully met. Additional nonengine applications for the coating include thermal protection systems (TPS) for next-generation spacecraft and hypersonic aircraft.

Aluminium phosphate sulphate minerals (APS) associated with proterozoic unconformity-type uranium deposits: crystal-chemical characterisation and petrogenetic significance

International Nuclear Information System (INIS)

Gaboreau, St.

2005-01-01

Aluminium phosphate sulfate minerals (APS) are particularly widespread and spatially associated with hydrothermal clay alteration in both the East Alligator River Uranium Field (Northern Territory, Australia) and the Athabasca basin (Saskatchewan, Canada), in the environment of proterozoic unconformity-related uranium deposits (URUD). The purpose of this study is both: 1) to characterize the nature and the origin of the APS minerals on both sides of the middle proterozoic unconformity between the overlying sandstones and the underlying metamorphic basement rocks that host the uranium ore bodies, 2) to improve our knowledge on the suitability of these minerals to indicate the paleo-conditions (redox, pH) at which the alteration processes relative to the uranium deposition operated. The APS minerals result from the interaction of oxidising and relatively acidic fluids with aluminous host rocks enriched in monazite. Several APS-bearing clay assemblages and APS crystal-chemistry have also been distinguished as a function of the distance from the uranium ore bodies or from the structural discontinuities which drained the hydrothermal solutions during the mineralisation event. One of the main results of this study is that the index mineral assemblages, used in the recent literature to describe the alteration zones around the uranium ore bodies, can be theoretically predicted by a set of thermodynamic calculations which simulate different steps of fluid-rock interaction processes related to a downward penetrating of hyper-saline, oxidizing and acidic diagenetic fluids through the lower sandstone units of the basins and then into the metamorphic basement rocks. The above considerations and the fact that APS with different crystal-chemical compositions crystallized in a range of fO 2 and pH at which uranium can either be transported in solution or precipitated as uraninite in the host-rocks make these minerals not only good markers of the degree of alteration of the

An isotopic perspective on growth and differentiation of Proterozoic orogenic crust: From subduction magmatism to cratonization

Energy Technology Data Exchange (ETDEWEB)

Johnson, Simon P.; Korhonen, Fawna J.; Kirkland, Christopher L.; Cliff, John B.; Belousova, Elena A.; Sheppard, Stephen

2017-01-01

The in situ chemical differentiation of continental crust ultimately leads to the long-term stability of the continents. This process, more commonly known as ‘cratonization’, is driven by deep crustal melting with the transfer of those melts to shallower regions resulting in a strongly chemically stratified crust, with a refractory, dehydrated lower portion overlain by a complementary enriched upper portion. Since the lower to mid portions of continental crust are rarely exposed, investigation of the cratonization process must be through indirect methods. In this study we use in situ Hf and O isotope compositions of both magmatic and inherited zircons from several felsic magmatic suites in the Capricorn Orogen of Western Australia to highlight the differentiation history (i.e. cratonization) of this portion of late Archean to Proterozoic orogenic crust. The Capricorn Orogen shows a distinct tectonomagmatic history that evolves from an active continental margin through to intracratonic reworking, ultimately leading to thermally stable crust that responds similarly to the bounding Archean Pilbara and Yilgarn Cratons.

Sporulation and ultrastructure in a late Proterozoic cyanophyte - Some implications for taxonomy and plant phylogeny

Science.gov (United States)

Cloud, P.; Moorman, M.; Pierce, D.

1975-01-01

Electron microscopical studies of a morphologically diverse, coccoid, presumably late Proterozoic blue-green alga are here reported. They show, together with light microscopy, that the form studied is widespread in the Cordilleran geosyncline, extend the record of well-defined endosporangia perhaps 700 million years into the past, and reveal previously unrecorded ultrastructural details. Coming from northeastern Utah, southwestern Alberta, and east central Alaska, these minute fossils belong to the recently described, morphologically diverse taxon Sphaerocongregus variabilis Moorman, are related to living entophysalidaceans, and have affinities with both the chroococcalean and chamaesiphonalean cyanophytes. Included in the morphological modes displayed by this alga are individual unicells, coenobial clusters of unicells, and a range of endosporangia comparable to those described for living entophysalidaceans. Scanning and transmission electron microscopy reveal that the endospores are commonly embedded in a vesicular matrix, that some of them show what appears to be a bilaminate or perhaps locally multilaminate wall structure, and that some remain together to mature as coenobial clones or 'colonies'. Taxonomic classification and phylogeny are discussed.

Identifying high-grade uranium deposits in the Proterozoic basins of India- a challenge to exploration

International Nuclear Information System (INIS)

Mahadevan, T.M.

1995-01-01

The favorability factors that bestow on the Proterozoic formation of India, a potential to host high grade uranium deposits are discussed in the light of the known features of the new class of unconformity- related and strata bound uranium deposits. The need to reorient several past approaches is emphasised and it is suggested that future programmes must avail of the constraining benefits of a spectrum of geophysical, geochemical, and sedimentological studies in the choice of target areas for detailed exploration and development. A synthesis of geological and geochemical data with such geophysical features as magnetic and gravity anomalies, velocity structure, seismic reflectivity, electrical conductivity, and radioactivity can effectively lead to relatively more favourable exploration targets. Such efforts may lead to the generation of more than one model of the deep basinal features, which then provide wider options for drilling and proving of ore bodies. The alternative to the above approach is saturation drilling, which is a costly and time-consuming process and, therefore, very often self-defeating. (author). 28 refs., 2 figs., 2 tabs

The Proterozoic of NW Mexico revisited: U-Pb geochronology and Hf isotopes of Sonoran rocks and their tectonic implications

Science.gov (United States)

Solari, L. A.; González-León, C. M.; Ortega-Obregón, C.; Valencia-Moreno, M.; Rascón-Heimpel, M. A.

2018-04-01

Several Proterozoic basement units crop out in the Sonora State of NW Mexico, and the same can be correlated with crustal provinces of southern Laurentia in the neighboring southwestern USA. Zircon U-Pb and Hf isotopic determinations in more than 300 grains separated from igneous and metaigneous rocks from these units indicate that the crystalline basement in Sonora is made up of different components, which are from west to east: (1) The Caborca-Mojave province to the west, characterized by the so-called Bámori Complex, have U-Pb ages between 1696 and 1772 Ma, with moderately juvenile to slightly evolved ɛHf values, yielding T DM ages of ca. 2.1-2.4 Ga; (2) in the intermediate area, east of Hermosillo, the Palofierral and La Ramada orthogneiss units yield an age of 1640 and 1703 Ma, respectively, both having juvenile ɛHf with the Palofierral overlapping the depleted mantle curve at ca. 1.65 Ga; and (3) in the northeastern Sonora, samples from the southern extension of the Mazatzal province, represented by the Pinal Schist, yielded ages between 1674 and 1694 Ma, with moderately juvenile to juvenile ɛHf values and a T DM age of ca. 1.9 Ga. In addition, a suite of post-tectonic granites was also studied in Caborca (San Luis granite) as well as in northeastern Sonora (Cananea granite), both yielding ages of ca. 1.44 Ga with moderately juvenile ɛHf values ranging from -1 to +8 and T DM dates of ca. 1.8-1.9 Ga and 1.6-1.7 Ga, respectively. These two isotopically contrasting provinces may imply the existence of a Proterozoic paleo-suture. However, if the Palofierral gneiss, of which the Hf signature straddles the depleted mantle array, is taken as the source for the 1.44 Ga Cananea granite, then the location of such a suture zone should lay farther south than the proposed trace of the Mojave-Sonora megashear.

Microbial Interactions With Dissolved Organic Matter Drive Carbon Dynamics and Community Succession

Directory of Open Access Journals (Sweden)

Xiaoqin Wu

2018-06-01

Full Text Available Knowledge of dynamic interactions between natural organic matter (NOM and microbial communities is critical not only to delineate the routes of NOM degradation/transformation and carbon (C fluxes, but also to understand microbial community evolution and succession in ecosystems. Yet, these processes in subsurface environments are usually studied independently, and a comprehensive view has been elusive thus far. In this study, we fed sediment-derived dissolved organic matter (DOM to groundwater microbes and continually analyzed microbial transformation of DOM over a 50-day incubation. To document fine-scale changes in DOM chemistry, we applied high-resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS and soft X-ray absorption spectroscopy (sXAS. We also monitored the trajectory of microbial biomass, community structure and activity over this time period. Together, these analyses provided an unprecedented comprehensive view of interactions between sediment-derived DOM and indigenous subsurface groundwater microbes. Microbial decomposition of labile C in DOM was immediately evident from biomass increase and total organic carbon (TOC decrease. The change of microbial composition was closely related to DOM turnover: microbial community in early stages of incubation was influenced by relatively labile tannin- and protein-like compounds; while in later stages the community composition evolved to be most correlated with less labile lipid- and lignin-like compounds. These changes in microbial community structure and function, coupled with the contribution of microbial products to DOM pool affected the further transformation of DOM, culminating in stark changes to DOM composition over time. Our study demonstrates a distinct response of microbial communities to biotransformation of DOM, which improves our understanding of coupled interactions between sediment-derived DOM, microbial processes, and community structure in

Microbial communities and organic biomarkers in a Proterozoic-analog sinkhole.

Science.gov (United States)

Hamilton, T L; Welander, P V; Albrecht, H L; Fulton, J M; Schaperdoth, I; Bird, L R; Summons, R E; Freeman, K H; Macalady, J L

2017-11-01

Little Salt Spring (Sarasota County, FL, USA) is a sinkhole with groundwater vents at ~77 m depth. The entire water column experiences sulfidic (~50 μM) conditions seasonally, resulting in a system poised between oxic and sulfidic conditions. Red pinnacle mats occupy the sediment-water interface in the sunlit upper basin of the sinkhole, and yielded 16S rRNA gene clones affiliated with Cyanobacteria, Chlorobi, and sulfate-reducing clades of Deltaproteobacteria. Nine bacteriochlorophyll e homologues and isorenieratene indicate contributions from Chlorobi, and abundant chlorophyll a and pheophytin a are consistent with the presence of Cyanobacteria. The red pinnacle mat contains hopanoids, including 2-methyl structures that have been interpreted as biomarkers for Cyanobacteria. A single sequence of hpnP, the gene required for methylation of hopanoids at the C-2 position, was recovered in both DNA and cDNA libraries from the red pinnacle mat. The hpnP sequence was most closely related to cyanobacterial hpnP sequences, implying that Cyanobacteria are a source of 2-methyl hopanoids present in the mat. The mats are capable of light-dependent primary productivity as evidenced by 13 C-bicarbonate photoassimilation. We also observed 13 C-bicarbonate photoassimilation in the presence of DCMU, an inhibitor of electron transfer to Photosystem II. Our results indicate that the mats carry out light-driven primary production in the absence of oxygen production-a mechanism that may have delayed the oxygenation of the Earth's oceans and atmosphere during the Proterozoic Eon. Furthermore, our observations of the production of 2-methyl hopanoids by Cyanobacteria under conditions of low oxygen and low light are consistent with the recovery of these structures from ancient black shales as well as their paucity in modern marine environments. © 2017 The Authors. Geobiology Published by John Wiley & Sons Ltd.

Carbon and oxygen isotope compositions of the carbonate facies

Indian Academy of Sciences (India)

The Vindhyan sedimentary succession in central India spans a wide time bracket from the Paleopro- terozoic to the Neoproterozoic period.Chronostratigraphic significance of stable carbon and oxygen isotope ratios of the carbonate phase in Vindhyan sediments has been discussed in some recent studies.However,the ...

[Storages and distributed patterns of soil organic carbon and total nitrogen during the succession of artificial sand-binding vegetation in arid desert ecosystem].

Science.gov (United States)

Jia, Xiao-Hong; Li, Xin-Rong; Zhou, Yu-Yan; Li, Yuan-Shou

2012-03-01

Soil carbon pool acts as the largest one of carbon pools in the terrestrial ecosystem. The storages and distributed patterns of soil organic carbon (SOC) and total nitrogen (TN) evaluated accurately are helpful to predict the feedback between the terrestrial ecosystem and climate changes. Based on the data about bulk density, content of SOC and TN at 0-100 cm soil profile, the density of SOC and TN at the temporal (chronosequence of artificial vegetation) and spatial (vertical) distributed patterns have been estimated. The results indicated that storages of SOC and TN at 0-100 cm depth increased with the chronosequence of artificial vegetation. The storages of SOC and TN showed the same tendency with the succession time of artificial vegetation. Storages of SOC and TN significantly increased at the early stage of banding sand by artificially vegetation ( 25 a). The variation of storages mainly occurred in the 0-20 cm depth. The storages decreased with the soil vertical depth. At the early stage of banding sand, increase in storage included every depth (0-100 cm). Whereas, at the later stage, increase in storage at 0-20 cm depth was main, and increase in the 20-100 cm was inconspicuous. The accumulation of storage at the shallow soil depth was more notability with the succession of artificial vegetation. The distributed pattern of storage in SOC and TN has been confirmed in arid desert regions below 200 mm annual precipitation. This was beneficial to understand the carbon cycle and to predict the feedback relationship between desert ecosystem and climate changes.

A review of the sedimentology of the Early Proterozoic Pretoria Group, Transvaal Sequence, South Africa: implications for tectonic setting

Science.gov (United States)

Eriksson, P. G.; Schreiber, U. M.; van der Neut, M.

The sedimentary rocks of the Early Proterozoic Pretoria Group form the floor rocks to teh 2050 M.a. Bushveld Complex. An overall alluvial fan-fan-delta - lacustrine palaeoenvironmental model is postulated for the Pretoria Group. This model is compatible with a continental half-graben tectonic setting, with steep footwall scarps on the southern margin and a lower gradient hanging wall developed to the north. The latter provided much of the basin-fill detritus. It is envisaged that the southern boundary fault system migrated southwards by footwall collapse as sedimentation continued. Synsedimentary mechanical rifting, associated with alluvial and deltaic sedimentation (Rooihoogte-Strubenkop Formations) was followed by thermal subsidence, with concomitant transgressive lacustrine deposition (Daspoort-Magaliesberg Formations). The proposed half-graben basin was probably related to the long-lived Thabazimbi-Murchison and Sugarbush-Barberton lineaments, which bound the preserved outcrops of the Pretoria Group.

Chemistry and palynology of carbon seams and associated rocks from the Witwatersrand goldfields, South Africa

Science.gov (United States)

Ebert, L.B.; Robbins, E.I.; Rose, K.D.; Kastrup, R.V.; Scanlon, J.C.; Gebhard, L.A.; Garcia, A.R.

1990-01-01

Carbon seams in the Witwatersrand System of South Africa host some of the richest gold concentrations in the world. A study of the microscopic characteristics in thin sections and acid residues, and of the chemical and physical nature of the carbon-bearing phases, was undertaken to gain some understanding of the biological precursors and thermal changes that have occurred since the seams were buried. The HClHF acid-resistant organic tissues in this Early Proterozoic coal are filamentous and spherical, which are typical morphologies for microorganisms. The tissues are carbonized black as would be expected for metamorphic rocks, so usual palynological techniques were of limited use. Therefore, the chemical and physical nature of the organic remains was studied by H C ratios, X-ray diffraction (XRD), 13C nuclear magnetic resonance (NMR), reductive chemistry, crosspolarization/magic angle spinning NMR (CP/MAS), and electron spin resonance (ESR). The H C ratios of the samples examined are similar to those of semi-anthracite and petroleum cokes from delayed cokers. XRD shows graphite is not present and that the gold is in elemental form, not chemically bound or intercalated between carbon planes. NMR shows that both aromatic and paraffinic carbons are present. Integration of the carbon NMR spectra suggests that 80% of the carbon is sp2-hybridized and 20% is sp3-hybridized. Reductive chemistry shows that the benzenoid entities are larger than common polynuclear aromatic hydrocarbons such as perylene and decacyclene. Dipolar dephasing CP/MAS NMR suggests the presence of two types of paraffinic carbons, a rigid methylene group and a rotating methyl group. The narrowing of the ESR linewidth between room temperature and 300??C shows that the materials examined have not previously been subjected to temperatures as high as 300??C. ?? 1990.

Some aspects of the genesis of heavy mineral assemblages in Lower Proterozoic uranium-gold conglomerates

International Nuclear Information System (INIS)

Clemmey, H.

1982-01-01

Some genetic models for Lower Proterozoic gold- and uranium-bearing pyritic conglomerates favour a modified placer origin in which low levels of atmospheric oxygen are used to account for the survival of uraninite and pyrite. There are many difficulties with such models. New evidence concerning the genesis of the deposits is derived from a clast of ferric iron clay thought to represent a precursor sediment of the Witwatersrand Basin. Reworking of such clays and transport of a magnetite and ferric clay assemblage with subsequent sulphidation, could account for the porous pyrites, the absence of magnetite and the lack of hydraulic equivalence of the mineral grains in the conglomerates. The presence of oxygen, as indicated by the ferric iron clasts, would account for the evidence of mobility of uranium and of gold and would enhance their extraction from source rocks; particularly the release of gold from a precursor auriferous iron formation source. It is suggested that some aspects of the genesis of uranium deposits of the Witwatersrand and Elliott Lake may be similar to those of the Phanerozoic 'Roll Front' ores involving interaction between oxidizing uraniferous groundwaters and previously sulphidized and reduzate facies sediments. (author)

Synthesis of carbon nanorods by reduction of carbon bisulfide

International Nuclear Information System (INIS)

Lou Zhengsong; He Minglong; Zhao Dejian; Li Zhongchun; Shang Tongming

2010-01-01

Research highlights: Our manuscript is a concise preliminary account of original and of significant research, which illuminates carbon nanorods and variously shaped Y-junction carbon nanorods are successfully fabricated on a large scale through a carbon bisulfide thermal reduction process. Various shaped Y-junction carbon nanorods can be used as studying the electronic and transport properties of the nano-meter carbon material. - Abstract: Carbon nanorods are synthesized at large scale by the reduction of carbon bisulfide at 600 o C. Moreover, novel Y-junction carbon nanorods are detected in the samples. The X-ray power diffraction pattern indicates that the products are hexagonal graphite. Scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy and N 2 physisorption studies show that carbon nanorods predominate in the product. Based on the supercritical carbon bisulfide system, the possible growth mechanism of the carbon nanorods was discussed. This method provides a simple and cheap route to large-scale synthesis of carbon nanorods.

Present exploration status of the Lianshanguan uranium deposit, Northeast China

International Nuclear Information System (INIS)

Fei, Q.; Shaokang, H.

1980-01-01

During recent years surface radiometry has revealed a series of anomalies and uranium occurrences in the Lianshanguan region of Northeast China which are present in Proterozoic Formations. Several significant uranium occurrences were tested by trenching and core drilling which resulted in the discovery of the Lianshanguan uranium deposit in 1978. The ore bodies of economic significance are located at a depth of 38-250m. Potential reserves are 1000 tons of U 3 O 8 . The geological setting of the Lower Proterozoic Lianshanguan uranium deposit has a certain similarity to the Alligator Rivers Region, Northern Territory, Australia. However, the Lianshanguan deposit occurs in detrital formations (in the lower part of the Lower Proterozoic sequence), adjacent to a migmatitic zone; it is overlain by carbonate argillitic rocks. The discovery of the Lianshanguan deposit indicates a potential for further uranium discoveries in northeast China, where Proterozoic sequences are well developed. The Lianshanguan uranium deposit is located approximately 100km south of Shenyang at 40 0 59'N and 123 0 30'E

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Indian Academy of Sciences (India)

(Afyon-Sandıklı) geothermal systems, SW Turkey 1081. Microtremor measurements ... Analysis of carbon dioxide, water vapour and energy fluxes over an Indian ... Petrological and geochemical characteristics of Paleo- proterozoic ultramafic ...

Fabrication of novel micro-nano carbonous composites based on self-made hollow activated carbon fibers

Energy Technology Data Exchange (ETDEWEB)

Kong Yuxia; Qiu Tingting [School of Materials Science and Engineering, Tongji University, Shanghai 201804 (China); Qiu Jun, E-mail: qiujun@tongji.edu.cn [School of Materials Science and Engineering, Tongji University, Shanghai 201804 (China); Key Laboratory of Advanced Civil Engineering Materials of Education of Ministry, Shanghai 201804 (China)

2013-01-15

Highlights: Black-Right-Pointing-Pointer Hollow pipe and porous HACF with solid carbon net framework structure were successfully prepared by template method. Black-Right-Pointing-Pointer CNTs were grown successfully on the self-made HACF substrate by CVD techniques. Black-Right-Pointing-Pointer A novel tree-like micro-nano carbonous structure CNTs/HACF was fabricated. Black-Right-Pointing-Pointer The formation mechanism of micro phase HACF and nano phase CNTs were respectively discussed. - Abstract: The hollow activated carbon fibers (HACF) were prepared by using commercial polypropylene hollow fiber (PPHF) as the template, and phenol-formaldehyde resin (PF) as carbon precursors. Final HACF was formed through the thermal decomposition and carbonization of PF at 700 Degree-Sign C under the nitrogen atmosphere, and activation at 800 Degree-Sign C with carbon dioxide as the activating agent, consecutively. Then, carbon nanotubes (CNTs) were grown by chemical vapor deposition (CVD) techniques using the as-grown porous HACF as substrate. The growth process was achieved by pyrolyzing ethanol steam at 700 Degree-Sign C using nickel as catalyst. Finally, CNTs was grown successfully on the substrate, and a novel tree-like micro-nano carbonous structure CNTs/HACF was fabricated. The as-grown HACF and micro-nano CNTs/HACF were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TG), respectively. Moreover, the formation mechanisms were also discussed.

Advanced Thermal Protection Systems (ATPS), Aerospace Grade Carbon Bonded Carbon Fiber Material, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Carbon bonded carbon fiber (CBCF) insulating material is the basis for several highly successful NASA developed thermal protection systems (TPS). Included among...

Successful Treatment of Severe Carbon Monoxide Poisoning and Refractory Shock Using Extracorporeal Membrane Oxygenation.

Science.gov (United States)

Teerapuncharoen, Krittika; Sharma, Nirmal S; Barker, Andrew B; Wille, Keith M; Diaz-Guzman, Enrique

2015-09-01

Carbon monoxide (CO) is the most common cause of poisoning and poisoning-related death in the United States. It is a tasteless and odorless poisonous gas produced from incomplete combustion of hydrocarbons, such as those produced by cars and heating systems. CO rapidly binds to hemoglobin to form carboxyhemoglobin, leading to tissue hypoxia, multiple-organ failure, and cardiovascular collapse. CO also binds to myocardial myoglobin, preventing oxidative phosphorylation in cardiac mitochondria and resulting in cardiac ischemia or stunning and cardiogenic pulmonary edema. Treatment of CO poisoning is mainly supportive, and supplemental oxygen remains the cornerstone of therapy, whereas hyperbaric oxygen therapy is considered for patients with evidence of neurological and myocardial injury. Extracorporeal membrane oxygenation (ECMO) has been utilized effectively in patients with respiratory failure and hemodynamic instability, but its use has rarely been reported in patients with CO poisoning. We report the successful use of venoarterial ECMO in a patient with severe CO poisoning and multiple-organ failure. Copyright © 2015 by Daedalus Enterprises.

Geochemical element mobility during the history of a Paleo-proterozoic clastic sedimentary basin, the Athabasca Basin (Saskatchewan, Canada)

International Nuclear Information System (INIS)

Kister, Philippe

2003-01-01

In order to understand the mechanisms of migration and deposition of ore elements, it is essential to determine the timing, source, and destination of the geochemical element mass transfers and/or transportation on a scale encompassing the great sedimentary basins. The purpose of this study is to trace and to date the element migrations that occurred during the history of a Paleo-proterozoic clastic sedimentary basin, the Athabasca Basin, which hosts the world's largest and richest uranium deposits. As this geological environment was proved to be efficient to preserve high grade ore deposits for over more than one billion years, it provides an opportunity to study some natural analogues of deep geological nuclear waste storage. Five research topics were studied: 3D modelling of the distribution of normative minerals and trace elements on a basin-wide scale; U-Pb and Rb-Sr systematics; average chemical age estimation; thermodynamic modelling of the major mineralogical assemblages; U-Pb geochronology of uranium oxides. Some elements have remained immobile (Zr) since their initial sedimentary deposition, or were transferred from one phase to another (Al, Th). Other elements have been transported during fluid flow events that occurred: (1) on a basin wide scale during diagenesis (REE, Y, Sr, Fe), (2) at the unconformity and in the vicinity of the fault zones that represent preferential fluid flow pathways between the basement and the sandstone cover (U, Ni, As, B, Mg, K, Fe, Sr, REE), (3) during the late fault reactivation events associated with the basin uplift (U, Pb, Ni, S, Sr, REE). The successive tectonic events related to the geodynamical context that lead to the formation of these high-grade U concentrations (1460 Ma, 1335 Ma and 1275 Ma in the McArthur River deposit), did not however systematically occur in the whole basin (1275 Ma only at Shea Creek). The exceptionally high grade and tonnages of some deposits seem to be related to a larger number of U

Recent developments in inorganically filled carbon nanotubes: successes and challenges

Directory of Open Access Journals (Sweden)

Ujjal K Gautam, Pedro M F J Costa, Yoshio Bando, Xiaosheng Fang, Liang Li, Masataka Imura and Dmitri Golberg

2010-01-01

Full Text Available Carbon nanotubes (CNTs are a unique class of nanomaterials that can be imagined as rolled graphene sheets. The inner hollow of a CNT provides an extremely small, one-dimensional space for storage of materials. In the last decade, enormous effort has been spent to produce filled CNTs that combine the properties of both the host CNT and the guest filling material. CNTs filled with various inorganic materials such as metals, alloys, semiconductors and insulators have been obtained using different synthesis approaches including capillary filling and chemical vapor deposition. Recently, several potential applications have emerged for these materials, such as the measurement of temperature at the nanoscale, nano-spot welding, and the storage and delivery of extremely small quantities of materials. A clear distinction between this class of materials and other nanostructures is the existence of an enormous interfacial area between the CNT and the filling matter. Theoretical investigations have shown that the lattice mismatch and strong exchange interaction of CNTs with the guest material across the interface should result in reordering of the guest crystal structure and passivation of the surface dangling bonds and thus yielding new and interesting physical properties. Despite preliminary successes, there remain many challenges in realizing applications of CNTs filled with inorganic materials, such as a comprehensive understanding of their growth and physical properties and control of their structural parameters. In this article, we overview research on filled CNT nanomaterials with special emphasis on recent progress and key achievements. We also discuss the future scope and the key challenges emerging out of a decade of intensive research on these fascinating materials.

A new ‘superassemblage’ model explaining proximal-to-distal and lateral facies changes in fluvial environments, based on the Proterozoic Sanjauli Formation (Lesser Himalaya, India

Directory of Open Access Journals (Sweden)

Ananya Mukhopadhyay

2016-09-01

Full Text Available Facies analysis of fluvial deposits of the Proterozoic Sanjauli Formation in the Lesser Himalaya was combined with an architectural analysis. On this basis, a model was developed that may be applied to other fluvial systems as well, whether old or recent. The new model, which might be considered as an assemblage of previous models, explains lateral variations in architecture and facies but is not in all respects consistent with the standard fluvial models. The Sanjauli fluvial model is unique in that it deals with lateral facies variations due to shifts of the base-level along with fluctuations in accommodation space owing to changes in palaeoclimate.

A summary of Rb-Sr isotope studies in the Archean Hopedale Block and the adjacent proterozoic Makkovik subprovince, Labrador

International Nuclear Information System (INIS)

Grant, N.K.; Hickman, M.H.; Marzano, M.S.; Ermanovics, I.F.

1983-01-01

Rb-Sr isotope study of thirteen whole-rock suites of Archean and Proterozoic rocks from Hopedale block and Makkovik Subprovince shows that the crustal history began about 3115 Ma ago. We tentatively recognize younger crustal segments that formed 2920 Ma ago, from which Kanairktok intrusives were derived at 2832 +- 178 Ma. In Makkovik Subprovince the Island Harbour granites range in age from 1843 +- 90 to 1794 +- 71 Ma. These ages overlap with the 1847 +-87 Ma age for Kanairktok shear zone mylonites. The Island Harbour granodiorites from inland localities to the southwest are contaminated with Archean rocks in Makkovik Subprovince and their initial 87 Sr/ 86 ratios imply a crustal contribution to their source. In contrast, the Island Harbour granites of Striped Island were derived from a mantle source. The sills of Striped Island are 1635 +- 47 Ma old. An undeformed northeast trending Kikkertavak dolerite dyke from Hopedale block is 1206 +- 120 Ma

Gold and uranium metallogenesis in the framework of Neo-proterozoic crust growth and differentiation: example of the Mayo-Kebbi Massif (Chad) in the Central Africa Orogenic belt

International Nuclear Information System (INIS)

Mbaguedje, Diondoh

2015-01-01

The Mayo Kebbi massif located in southwestern Chad between the Congo craton in the South, the West African craton in the west and the Sahara meta-craton to the east exposes a segment of Neo-proterozoic juvenile crust accreted in the Central African orogenic belt during the Pan African orogeny. It consists of two greenstone belts (Zalbi and Goueygoudoum) separated by the May Kebbi calc-alkaline batholith complexes and intruded by calc-alkaline high-K granitic plutons. The whole is covered by Phanerozoic sedimentary formations. The greenstone belts contain sulphide zones hosted mainly by meta-plutonic rocks (granodiorites) and meta-basalts and meta-volcaniclastics. The mineralization comprises pyrite, pyrrhotite, arsenopyrite, chalcopyrite, pentlandite, pentlandite silver, pentlandite cobaltiferous, sphalerite, cobaltite. These sulphides are disseminated, aggregated in form of layers or are filling veins and cracks. The greenstones also contain quartz veins with calcite and chlorite comprising a mineralization made of pyrite, chalcopyrite, galena and gold. Gold is present both as native crystals and as electrum. The high-K calc-alkaline Zabili granitic pluton hosts uranium mineralization related to a superposition of: (1) ductile deformation and metasomatic alteration implying the interaction between magmatic minerals with a Na-rich fluid, of potential magmatic origin, coeval to the main deposition of uranium oxides, followed by (2) brittle deformation and deposition of secondary hydrated uranium silicates involving a Na-Ca-rich fluid. We propose that these uranium mineralizations represent the extreme expression of crustal differentiation as a result of Pan-African reworking of a Neo-proterozoic juvenile crustal segment. (author) [fr

Alternative marine and fluvial models for the non-fossiliferous quartzitic sandstones of the Early Proterozoic Daspoort Formation, Transvaal Sequence of southern Africa

Science.gov (United States)

Eriksson, P. G.; Schreiber, U. M.; van der Neut, M.; Labuschagne, H.; Van Der Schyff, W.; Potgieter, G.

1993-04-01

This paper discusses some of the problems related to the palaeoenvironmental interpretation of non-fossiliferous, early Precambrian, recrystallised quartzitic sandstones, using the Early Proterozoic Daspoort Formation, Transvaal Sequence of southern Africa as a case study. These cross-bedded and planar stratified rocks have been interpreted previously as shallow marine deposits, based on limited studies of areas with well-exposed, relatively undeformed outcrops. This postulate rests largely on the apparently mature nature of the recrystallised sandstones and their thin bedding. Examination of outcrops throughout the preserved basin, including those which have been deformed and metamorphosed, reveals the presence of subordinate immature sandstones. Lateral facies relationships permit an alternative distal fan-fluvial braidplain model to be proposed. This is compatible with collected palaeocurrent data, thicknes trends and results of thin section petrography.

Nodular features from Proterozoic Sonia Sandstone, Jodhpur Group ...

Indian Academy of Sciences (India)

Corresponding author. e-mail: parthageology@gmail.com. The Sonia ..... cement variety in the form of dispersed dark brown clots and .... content within the nodule sandstones bear sig- nature in ..... Carbonates and Evaporites 21 133–143.

Strategies for Local Low-Carbon Development

Energy Technology Data Exchange (ETDEWEB)

Zhou, Nan [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Price, Lynn [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Fridley, David [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Ohshita, Stephanie [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Khanna, Nina [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Min, Hu [Energy Foundation China, Beijing (China); Xiulian, Hu [Energy Research Inst., Beijing (China)

2012-11-14

Cities around the world are implementing policies and programs with the goal to reduce greenhouse gas emissions, as well as save energy, reduce costs, and protect the local, regional, and global environment. In China, low-carbon development is a key element of the 12th Five Year Plan. Pilot low-carbon development zones have been initiated in five provinces and eight cities and many other locations around China also want to pursue a low-carbon development pathway. This booklet provides information for government officials, policy makers, program designers and implementers, provincial and city planners, and others who want an overview of the key options available for low-carbon development at local level. These Strategies for Local Low-Carbon Development draw from successful experiences from around the world. Information is provided for low-carbon actions that can be taken in the sectors of (1) Industry, (2) Buildings and Appliances, (3) Electric Power, (4) Consumption and Waste Management, (5) Transportation and Urban Form, and (6) Agriculture and Forestry. A description of each policy is provided along with information on the stakeholders involved in implementation, the conditions for successful implementation, the expected energy and carbon savings, and the policy cost-effectiveness. Case studies show how each policy has been implemented somewhere around the world. While there are many low-carbon options available for local implementation, this booklet aims to provide guidance on those that have been most successful, that have the largest impact, and that are cost-effective in order to support low-carbon development efforts in Chinese cities.

Geochemical evidence for subduction in the early Archaean from quartz-carbonate-fuchsite mineralization, Isua Supracrustal Belt, West Greenland

DEFF Research Database (Denmark)

Pope, Emily Catherine; Rosing, Minik Thorleif; Bird, Dennis K.

Quartz, carbonate and fuchsite (chromian muscovite) is a common metasomatic assemblage observed in orogenic gold systems, both in Phanerozoic convergent margin settings, and within supracrustal and greenstone belts of Precambrian rocks. Geologic and geochemical observations in younger orogenic...... systems suggest that ore-forming metasomatic fluids are derived from subduction-related devolitilization reactions, implying that orogenic Au-deposits in Archaean and Proterozoic supracrustal rock suites are related to subduction-style plate tectonics beginning early in Earth history. Justification...... with Phanerozoic orogenic deposits and that this type of metasomatism is a unique result of subduction-related processes. Fuchsite from the ISB has a δ18O and δD of 7.7 to 17.9‰ and -115 to -61‰, respectively. δ18O of quartz from the same rocks is between 10.3 and 18.6‰. Muscovite-quartz oxygen isotope thermometry...

Carbon monoxide gas sensing using zinc oxide deposited by successive ionic layer adhesion and reaction

Science.gov (United States)

Florido, E. A.; Dagaas, N. A. C.

2017-05-01

This study was aimed to determine the carbon monoxide (CO) gas sensing capability of zinc oxide (ZnO) film fabricated by successive ionic layer adsorption and reaction (SILAR) on glass substrate. Films consisting of a mixture of flower-like clusters of ZnO nanorods and nanowires were observed using scanning electron microscopy (SEM). Current-voltage characterization of the samples showed an average resistivity of 13.0 Ω-m. Carbon monoxide gas was synthesized by mixing the required amount of formic acid and excess sulfuric acid to produce CO gas concentrations of 100, 200, 300, 400, and 500 parts per million (ppm) v/v with five trials for each concentration. Two sets of data were obtained. One set consisted of the voltage response of the single film sensor while the other set were obtained from the double film sensor. The voltage response for the single film sensor and the double film sensor showed an average sensitivity of 0.0038 volts per ppm and 0.0024 volts per ppm, respectively. The concentration the single film can detect with a 2V output is 526 ppm while the double film sensor can detect up to 833 ppm with a 2V output. This shows that using the double film sensor is advantageous compared to single film sensor, because of its higher concentration range due to the larger surface area for the gas to interact. Moreover, the measured average resistance for the single film sensor was 10 MΩ while for the double film sensor the average resistance was 5 MΩ.

Ghana Mining Journal - Vol 13 (2012)

African Journals Online (AJOL)

Texture and Compositional Evidence for Epigenetic Alteration in Mn Carbonate Protore at the Palaeo-proterozoic Nsuta Manganese Deposit, Western Ghana” · EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT. FK Nyame, 15-23 ...

Imaging for carbon translocation to a fruit of tomato with carbon-11-labeled carbon dioxide and positron emission tomography

International Nuclear Information System (INIS)

Kawachi, N.; Suzui, N.; Ishii, S.; Fujimaki, S.; Ishioka, N.; Kikuchi, K.; Watanbe, H.

2009-01-01

Carbon kinetics in the fruit is an agricultural issue on the growth and development of the fruit to be harvested. Particularly, photo-assimilate translocation and distribution are important topics for understanding the mechanism. In the present work, carbon-11 ( 11 C) labeled photo-assimilate translocation into fruits of tomato has been imaged using carbon-11-labeled carbon dioxide and the positron emission tomography (PET). Dynamic PET data of gradual increasing of 11 C activity and its distribution is acquired quantitatively in intact plant body. This indicates that the three dimensional photo-assimilate translocation into the fruits is imaged successfully and carbon kinetics is analyzed to understand the plant physiology and nutrition. (authors)

Carbon stocks quantification in agricultural systems employing succession and rotation of crops in Rio Grande do Sul State, Brazil.

Science.gov (United States)

Walter, Michele K. C.; Marinho, Mara de A.; Denardin, José E.; Zullo, Jurandir, Jr.; Paz-González, Antonio

2013-04-01

Soil and vegetation constitute respectively the third and the fourth terrestrial reservoirs of Carbon (C) on Earth. C sequestration in these reservoirs includes the capture of the CO2 from the atmosphere by photosynthesis and its storage as organic C. Consequently, changes in land use and agricultural practices affect directly the emissions of the greenhouse gases and the C sequestration. Several studies have already demonstrated that conservation agriculture, and particularly zero tillage (ZT), has a positive effect on soil C sequestration. The Brazilian federal program ABC (Agriculture of Low Carbon Emission) was conceived to promote agricultural production with environmental protection and represents an instrument to achieve voluntary targets to mitigate emissions or NAMAS (National Appropriated Mitigation Actions). With financial resources of about US 1.0 billion until 2020 the ABC Program has a target of expand ZT in 8 million hectares of land, with reduction of 16 to 20 million of CO2eq. Our objective was to quantify the C stocks in soil, plants and litter of representative grain crops systems under ZT in Rio Grande do Sul State, Brazil. Two treatments of a long term experimental essay (> 20 years) were evaluated: 1) Crop succession with wheat (Triticum aestivum L.)/soybean (Glycine max (L.) Merril); 2) Crop rotation with wheat/soybean (1st year), vetch (Vicia sativa L.)/soybean (2nd year), and white oat (Avena sativa L.)/sorghum (Sorghum bicolor L.) (3rd year). C quantification in plants and in litter was performed using the direct method of biomass quantification. The soil type evaluated was a Humic Rhodic Hapludox, and C quantification was executed employing the method referred by "C mass by unit area". Results showed that soybean plants under crop succession presented greater C stock (4.31MgC ha-1) comparing with soybean plants cultivated under crop rotation (3.59 MgC ha-1). For wheat, however, greater C stock was quantified in plants under rotation

Analysis of uranium metallogenic conditions and prospective prognosis on the south-central part of the Xikang-Yunnan Axis

International Nuclear Information System (INIS)

Guo Baochi; Qian Farong; Cai Yuqi; Zhang Daishi

1996-08-01

Three types of uranium mineralizations (i.e., sandstone type, sodium metasomatite type and Proterozoic epimetamorphic rock type) are distinguished in the south-central part of the Xikang-Yunnan Axis, and their major characteristics are expounded. It is proposed that the Early Proterozoic crust has three elevation stages: primitive old land formation stage, subsidence stage and base mental reconsolidation stage, and that the Middle Proterozoic Kunyang Group is different from typical carbonate-siliceous-politic sedimentary formation which contains many regional uranium-rich horizons. The primitive uranium contents of some rocks in the region have been studied for the first time, and proposed a new knowledge that some relative rocks be recognized as the uranium source rocks of the region. It is pointed out that there are two kinds of hydrothermal alterations, namely, alkaline alteration and acidic alteration, and some areas with development of alkaline alteration have promising uranium-metallogenic potential. As for the U-metallogenic prospect of the region, three conclusions are summarized: (1) This region does not have favourable geologic conditions for the Australian-Canadian type Proterozoic unconformity-related uranium deposit; (2) The Proterozoic unconformity different from that of Australian-Canadian type does not have permission U-metallogenic potential either; (3) The alkaline (sodium) metasomatite type uranium mineralization in the region has some prospecting potential. Therefore on the basis of above-mentioned conclusions five relatively promising uranium-metallogenic prospects are selected. (4 refs.)

Vent Complexes above Dolerite Sills in Phanerozoic LIPs: Implications for Proterozoic LIPs and IOCG Deposits

Science.gov (United States)

Ernst, R. E.; Bleeker, W.; Svensen, H.; Planke, S.; Polozov, A. G.

2009-05-01

New insights into the origin of IOCG (iron oxide copper gold) deposits [e.g., 1, 2, 3] follow from recent studies of Phanerozoic Large Igneous Provinces (LIPs). Detailed seismic studies of the 62-55 Ma North Atlantic Igneous Province and complementary studies in the 183 Ma Karoo and 250 Ma Siberian LIPs reveal thousands of hydrothermal vent complexes (HVCs). Up to 5-10 km across at the paleosurface, these vents connect to underlying dolerite sills at paleodepths of up to 8 km [4, 5, 6, 7]. They originate from explosive release of gases generated when thick sills (>50 m) are emplaced into volatile-rich but low-permeability sedimentary strata. HVCs are phreatomagmatic in origin. Their architecture, economic potential for IOCG-type deposits, and effects on climate strongly depend on the type of host rocks (black shales at Karoo and evaporites at Siberian LIPs) and its fluid (brines) saturation at the time of emplacement. About 250 HVCs associated with the Siberian LIP are mineralized having magnetite in the matrix. Some are being mined for Fe (Korshunovskoe and Rudnogorskoe), but their economic potential for copper and gold mineralization is understudied. These observations from the Phanerozoic LIP record suggest that HVCs should also be an essential component of sill provinces associated with Proterozoic LIPs, with a potential for causing major climatic shifts and IOCG-type deposits, particularly if the host sediments include substantial evaporites. Two examples are discussed here. The 725 Ma Franklin LIP covers 1.1 Mkm2 in northern Canada [8]; in the Minto Inlier of Victoria Island, this event comprises volcanics, sills, and breccia pipes [9, 10]. The breccia pipes appear identical to HVCs and, furthermore, the presence of evaporites in the host sediments of the Shaler Supergroup suggests (based on the Siberian trap example) the potential for IOCG-type mineralization. Could 1.59 Ga sills, as exemplified by the exposed Western Channel Diabase sills on the eastern

Late Archaean-early Proterozoic source ages of zircons in rocks from the Paleozoic orogen of western Galicia, NW Spain

Energy Technology Data Exchange (ETDEWEB)

Kuijper, R P; Priem, H N.A. [Laboratorium voor Isotopen-Geologie, Amsterdam (Netherlands); Den Tex, E [Rijksuniversiteit Utrecht (Netherlands). Inst. voor Aardwetenschappen

1982-08-01

U-Pb data are reported for nine suites of zircons and three monazites from the Paleozoic orogen in western Galicia: one paragneiss and six orthogneisses from the early Paleozoic basement, and two Carboniferous (ca. 310 Ma old) intrusions of two-mica granite. New whole-rock Rb-Sr analyses, along with earlier data, indicate an age of ca. 470-440 Ma (Ordovician) for the emplacement of the granitic precursors of the orthogneisses. Monazite from the paragneiss also yields an U-Pb age of ca. 470 Ma. From the high initial /sup 87/Sr//sup 86/Sr ratios an involvement of Precambrian continental crust material is evident in the generation of the early Paleozoic suite of granites, while the zircon U-Pb data give evidence of the presence of about 3.0-2.0 Ga old (late Archaean-early Proterozoic) components in the source material. Zircons from the oldest sedimentary rocks in the area, now present as catazonal paragneisses and a likely source for the granites, likewise reveal a provenance age of 3.0-2.0 Ga.

To reactivate or not to reactivate: nature and varied behavior of structural inheritance in the Proterozoic basement of the Eastern Colorado mineral belt over 1.7 billion years of earth history

Science.gov (United States)

Caine, Jonathan S.; Ridley, John; Wessel, Zachary R.

2010-01-01

The eastern central Front Range of the Rocky Mountains in Colorado has long been a region of geologic interest because of Laramide-age hydrothermal polymetallic vein-related ores. The region is characterized by a well-exposed array of geologic structures associated with ductile and brittle deformation, which record crustal strain over 1.7 billion years of continental growth and evolution. The mineralized areas lie along a broad linear zone termed the Colorado Mineral Belt. This lineament has commonly been interpreted as following a fundamental boundary, such as a suture zone, in the North American Proterozoic crust that acted as a persistent zone of weakness localizing the emplacement of magmas and associated hydrothermal fluid flow. However, the details on the controls of the location, orientation, kinematics, density, permeability, and relative strength of various geological structures and their specific relationships to mineral deposit formation are not related to Proterozoic ancestry in a simple manner. The objectives of this field trip are to show key localities typical of the various types of structures present, show recently compiled and new data, offer alternative conceptual models, and foster dialogue. Topics to be discussed include: (1) structural history of the eastern Front Range; (2) characteristics, kinematics, orientations, and age of ductile and brittle structures and how they may or may not relate to one another and mineral deposit permeability; and (3) characteristics, localization, and evolution of the metal and non–metal-bearing hydrothermal systems in the eastern Colorado Mineral Belt.

Carbon Trading. Literature Overview

International Nuclear Information System (INIS)

Kerste, M.; Weda, J.; Rosenboom, N.

2010-12-01

From Pigou and Coase to the Kyoto Protocol, carbon trading has resulted in pricing of the negative externalities emanating from pollution. This report highlights leading literature and empirical findings on carbon trading, amongst others addressing the relevant carbon and related markets, the (lack of) success of carbon trading so far and room for improvement as well as its impact on investments in emission reduction. This report is part of a set of SEO-reports on finance and sustainability. The other reports deal with: Financing the Transition to Sustainable Energy; Innovations in financing environmental and social sustainability; and Sustainable investment.

Hybrid Carbon Fibers/Carbon Nanotubes Structures for Next Generation Polymeric Composites

Directory of Open Access Journals (Sweden)

M. Al-Haik

2010-01-01

Full Text Available Pitch-based carbon fibers are commonly used to produce polymeric carbon fiber structural composites. Several investigations have reported different methods for dispersing and subsequently aligning carbon nanotubes (CNTs as a filler to reinforce polymer matrix. The significant difficulty in dispersing CNTs suggested the controlled-growth of CNTs on surfaces where they are needed. Here we compare between two techniques for depositing the catalyst iron used toward growing CNTs on pitch-based carbon fiber surfaces. Electrochemical deposition of iron using pulse voltametry is compared to DC magnetron iron sputtering. Carbon nanostructures growth was performed using a thermal CVD system. Characterization for comparison between both techniques was compared via SEM, TEM, and Raman spectroscopy analysis. It is shown that while both techniques were successful to grow CNTs on the carbon fiber surfaces, iron sputtering technique was capable of producing more uniform distribution of iron catalyst and thus multiwall carbon nanotubes (MWCNTs compared to MWCNTs grown using the electrochemical deposition of iron.

Functional Carbon Nanotube/Mesoporous Carbon/MnO2 Hybrid Network for High-Performance Supercapacitors

Directory of Open Access Journals (Sweden)

Tao Tao

2014-01-01

Full Text Available A functional carbon nanotube/mesoporous carbon/MnO2 hybrid network has been developed successfully through a facile route. The resulting composites exhibited a high specific capacitance of 351 F/g at 1 A g−1, with intriguing charge/discharge rate performance and cycling stability due to a synergistic combination of large surface area and excellent electron-transport capabilities of MnO2 with the good conductivity of the carbon nanotube/mesoporous carbon networks. Such composite shows great potential to be used as electrodes for supercapacitors.

Late Proterozoic island-arc complexes and tectonic belts in the southern part of the Arabian Shield, Kingdom of Saudi Arabia

Science.gov (United States)

Greenwood, William R.; Stoeser, D.B.; Fleck, R.J.; Stacey, J.S.

1983-01-01

Sr ratios are not included in the appendix, but all rocks more than 660 m.y. old have initial ratios in the range 0.7021-0.7035, with only two greater than 0.7030. Thus, nothing in the Rb-Sr data suggests involvement of an older continental crust during the evolution of the southern Shield. A lead isotope study of ore minerals and potassium feldspars of the Arabian Shield by Stacey and others (1980) also suggests that no older (Archean to early Proterozoic) evolved continental-type crust underlies the southern Shield. An early summary of mapping (Schmidt and others, 1973) suggests that older sialic basement underlies the late Proterozoic layered rocks in the southern Shield. However, subsequent-mapping and the isotopic studies cited above have established that all of these rocks are of late Proterozoic age and that all rocks of the southern Shield that are more than 660 m.y. old have ensimatic or mantle isotopic characteristics. Figure 2 shows, with only two exceptions, that rocks more than 800 m.y. old are present west of the boundary separating the Tayyah and Khadra belts. The exceptions are two poorly controlled Rb-Sr ages obtained by Fleck (1980) on two quartz diorite plutons in the Malahah region (appendix 1, localities 26 and 27). Preliminary uranium-thorium zircon data of Stacey now suggest that one of these quartz diorite plutons (locality 26) has an age of approximately 640 m.y. Therefore, we prefer to discount the two dates of Fleck until further information is available. As noted earlier and as described below, most of the rocks of the southern Arabian Shield have characteristics typical of those formed in the island-arc environment by subduction-related processes. We shall refer to the group of rocks in the western part of the southern Shield, which formed from 1100 to 800 m.y. ago, as the 'older ensimatic-arc complex' and those in the eastern and northwestern parts, which formed from 800 to 690 m.y. ago, as the 'younger marginal-arc compl

Plant stimulation of soil microbial community succession: how sequential expression mediates soil carbon stabilization and turnover

Energy Technology Data Exchange (ETDEWEB)

Firestone, Mary [Univ. of California, Berkeley, CA (United States)

2015-03-31

It is now understood that most plant C is utilized or transformed by soil microorganisms en route to stabilization. Hence the composition of microbial communities that mediate decomposition and transformation of root C is critical, as are the metabolic capabilities of these communities. The change in composition and function of the C-transforming microbial communities over time in effect defines the biological component of soil C stabilization. Our research was designed to test 2 general hypotheses; the first two hypotheses are discussed first; H1: Root-exudate interactions with soil microbial populations results in the expression of enzymatic capacities for macromolecular, complex carbon decomposition; and H2: Microbial communities surrounding roots undergo taxonomic succession linked to functional gene activities as roots grow, mature, and decompose in soil. Over the term of the project we made significant progress in 1) quantifying the temporal pattern of root interactions with the soil decomposing community and 2) characterizing the role of root exudates in mediating these interactions.

Carbon storage in young growth coast redwood stands

Science.gov (United States)

Dryw A. Jones; Kevin A. O' Hara

2012-01-01

Carbon sequestration is an emerging forest management objective within California and around the world. With the passage of the California's Global Warming Solutions Act (AB32) our need to understand the dynamics of carbon sequestration and to accurately measure carbon storage is essential to insure successful implementation of carbon credit projects throughout...

State forestry agency perspectives on carbon management and carbon market assistance to family forest owners

Science.gov (United States)

Kristell A. Miller; Stephanie A. Snyder; Michael A. Kilgore

2015-01-01

Family forest owners within the United States could potentially make significant contributions to sequestration efforts. However, we expect that landowners will need assistance if they are to successfully implement carbon management techniques and/or navigate through complex carbon market requirements. State forestry agencies were surveyed to gather their perspectives...

Journal of Earth System Science | Indian Academy of Sciences

Indian Academy of Sciences (India)

... wavy pyritic laminae,; 'teeth and socket 'structure. These features are indirect evidence of microbial mat colonization during the Proterozoic.The microbial mats probably fixed carbon at the sediment surface,stabilized sediment and recycled organic matter and were the primary producers,unlike during the Phanerozoic time ...

Variation of properties of clayey minerals and associated phases about uranium deposits related to proterozoic discordances; Variation des proprietes des mineraux argileux et des phases associees autour des gisements d'uranium lies aux discordances Proterozoiques

Energy Technology Data Exchange (ETDEWEB)

Beaufort, D.; Patrier, P.; Laverret, E.; Gaboreau, St.; Billault, V. [HYDRASA, Universite de Poitiers-CNRS, 86 - Poitiers (France); Quirt, D. [AREVA Resources Canada AREVA Resources Canada Inc., Saskatoon, SK (Canada)

2009-07-01

The authors propose explanations for the clayey alteration which surrounds uranium deposits related to proterozoic discordances as it is noticed in Canada (Athabasca) and Australia (Kombolgie). The observed mineral sequences are interpreted as the product of an increasing interaction between infiltrated diagenetic acid and oxidising solutions on the one hand, and platform rocks on the other hand, at temperatures between 150 and 200 C. These interpretations are based on crystallographic and crystallochemical investigations

Modes of Contintental Sediment Storage and the History of Atmospheric Oxygen

Science.gov (United States)

Husson, J. M.; Peters, S. E.

2015-12-01

Documenting the history of atmospheric oxygen levels, and the processes that have governed that history, are among the most fundamental of problems in Earth science. Diverse observations from sedimentary petrography, isotope geochemistry, stratigraphy and trace element geochemistry have led to a model wherein concentrations of oxygen experienced two significant rises: the first 'Great Oxidation Event' near the Archean-Proterozoic boundary, and a second near the Proterozoic-Phanerozoic boundary. Despite ongoing debates over important details in the history of atmospheric O2, there is widespread agreement that the burial and long-term storage of sedimentary organic matter derived from photosynthesis, which represents net O2 production over consumption by respiration, is the primary driver of oxygenation of the atmosphere. In this regard, sedimentation on the continents is vitally important; today, >90% of buried organic matter occurs in sediments deposited on continental crust. Here we use 23,813 rock units, distributed among 949 geographic regions in North America, from the Macrostrat database to constrain patterns of sedimentation through Earth history. Sedimentary packages are low in number in the Archean, increase to a higher steady state value across the transition to the Proterozoic, and rise again across the Proterozoic-Phanerozoic boundary during the final stage in the formation of the Great Unconformity. Map-based data from polar Eurasia and Australia show qualitatively similar macrostratigraphic patterns of sediment abundance. The temporal similarities between continental sedimentation and the putative history of pO2 are sensible in the context of organic carbon burial. A simple model of burial and weathering on North America predicts two significant rises in pO2. These results suggest that the changing ability of the continents to serve as long-term organic carbon storage reservoirs, presumably due to geodynamic processes, has exerted a first-order control

Lesser Himalayan sequences in Eastern Himalaya and their deformation: Implications for Paleoproterozoic tectonic activity along the northern margin of India

Directory of Open Access Journals (Sweden)

Dilip Saha

2013-05-01

Full Text Available Substantial part of the northern margin of Indian plate is subducted beneath the Eurasian plate during the Caenozoic Himalayan orogeny, obscuring older tectonic events in the Lesser Himalaya known to host Proterozoic sedimentary successions and granitic bodies. Tectonostratigraphic units of the Proterozoic Lesser Himalayan sequence (LHS of Eastern Himalaya, namely the Daling Group in Sikkim and the Bomdila Group in Arunachal Pradesh, provide clues to the nature and extent of Proterozoic passive margin sedimentation, their involvement in pre-Himalayan orogeny and implications for supercontinent reconstruction. The Daling Group, consisting of flaggy quartzite, meta-greywacke and metapelite with minor mafic dyke and sill, and the overlying Buxa Formation with stromatolitic carbonate-quartzite-slate, represent shallow marine, passive margin platformal association. Similar lithostratigraphy and broad depositional framework, and available geochronological data from intrusive granites in Eastern Himalaya indicate strikewise continuity of a shallow marine Paleoproterozoic platformal sequence up to Arunachal Pradesh through Bhutan. Multiple fold sets and tectonic foliations in LHS formed during partial or complete closure of the sea/ocean along the northern margin of Paleoproterozoic India. Such deformation fabrics are absent in the upper Palaeozoic–Mesozoic Gondwana formations in the Lesser Himalaya of Darjeeling-Sikkim indicating influence of older orogeny. Kinematic analysis based on microstructure, and garnet composition suggest Paleoproterozoic deformation and metamorphism of LHS to be distinct from those associated with the foreland propagating thrust systems of the Caenozoic Himalayan collisional belt. Two possibilities are argued here: (1 the low greenschist facies domain in the LHS enveloped the amphibolite to granulite facies domains, which were later tectonically severed; (2 the older deformation and metamorphism relate to a Pacific type

Constraining the climate and ocean pH of the early Earth with a geological carbon cycle model

Science.gov (United States)

Krissansen-Totton, Joshua; Arney, Giada N.; Catling, David C.

2018-04-01

The early Earth’s environment is controversial. Climatic estimates range from hot to glacial, and inferred marine pH spans strongly alkaline to acidic. Better understanding of early climate and ocean chemistry would improve our knowledge of the origin of life and its coevolution with the environment. Here, we use a geological carbon cycle model with ocean chemistry to calculate self-consistent histories of climate and ocean pH. Our carbon cycle model includes an empirically justified temperature and pH dependence of seafloor weathering, allowing the relative importance of continental and seafloor weathering to be evaluated. We find that the Archean climate was likely temperate (0–50 °C) due to the combined negative feedbacks of continental and seafloor weathering. Ocean pH evolves monotonically from 6.6‑0.4+0.6 (2σ) at 4.0 Ga to 7.0‑0.5+0.7 (2σ) at the Archean–Proterozoic boundary, and to 7.9‑0.2+0.1 (2σ) at the Proterozoic–Phanerozoic boundary. This evolution is driven by the secular decline of pCO2, which in turn is a consequence of increasing solar luminosity, but is moderated by carbonate alkalinity delivered from continental and seafloor weathering. Archean seafloor weathering may have been a comparable carbon sink to continental weathering, but is less dominant than previously assumed, and would not have induced global glaciation. We show how these conclusions are robust to a wide range of scenarios for continental growth, internal heat flow evolution and outgassing history, greenhouse gas abundances, and changes in the biotic enhancement of weathering.

Accumulation of soil organic carbon in relation to other soil characteristic during spontaneous succession in non reclaimed colliery spoil heaps after brown coal mining near Sokolov (the Czech Republic)

Czech Academy of Sciences Publication Activity Database

Frouz, Jan; Kalčík, Jiří

2006-01-01

Roč. 25, č. 4 (2006), s. 388-397 ISSN 1335-342X R&D Projects: GA AV ČR 1QS600660505 Institutional research plan: CEZ:AV0Z60660521 Keywords : carbon accumulation * succession * soil formation Subject RIV: EH - Ecology, Behaviour Impact factor: 0.085, year: 2005

Biosynthesis of glycerol carbonate from glycerol by lipase in dimethyl carbonate as the solvent.

Science.gov (United States)

Lee, Kyung Hwa; Park, Chang-Ho; Lee, Eun Yeol

2010-11-01

Glycerol carbonate was synthesized from renewable glycerol and dimethyl carbonate using lipase in solvent-free reaction system in which excess dimethyl carbonate played as the reaction medium. A variety of lipases have been tested for their abilities to catalyze transesterification reaction, and Candida antartica lipase B and Novozyme 435 exhibited higher catalytic activities. The silica-coated glycerol with a 1:1 ratio was supplied to prevent two-phase formation between hydrophobic dimethyl carbonate and hydrophilic glycerol. Glycerol carbonate was successfully synthesized with more than 90% conversion from dimethyl carbonate and glycerol with a molar ratio of 10 using Novozyme 435-catalyzed transesterification at 70 °C. The Novozyme 435 [5% (w/w) and 20% (w/w)] and silica gel were more than four times recycled with good stability in a repeated batch operation for the solvent-free synthesis of glycerol carbonate.

Hot spring microbial community composition, morphology, and carbon fixation: implications for interpreting the ancient rock record

Science.gov (United States)

Schuler, Caleb G.; Havig, Jeff R.; Hamilton, Trinity L.

2017-11-01

important differences in primary productivity between structures despite indistinguishable δ13C values of the biomass. Furthermore, low primary productivity by stromatolites compared to other structures underscores the need to consider a larger role for microbial mats and filaments in carbon fixation and O2 generation during the Archean and Proterozoic.

Hot Spring Microbial Community Composition, Morphology, and Carbon Fixation: Implications for Interpreting the Ancient Rock Record

Directory of Open Access Journals (Sweden)

Caleb G. Schuler

2017-11-01

. Our data highlight important differences in primary productivity between structures despite indistinguishable δ13C values of the biomass. Furthermore, low primary productivity by stromatolites compared to other structures underscores the need to consider a larger role for microbial mats and filaments in carbon fixation and O2 generation during the Archean and Proterozoic.

Calculation of Binary Adsorption Equilibria: Hydrocarbons and Carbon Dioxide on Activated Carbon

DEFF Research Database (Denmark)

Marcussen, Lis; Krøll, A.

1999-01-01

Binary adsorption equilibria are calculated by means of a mathematical model for multicomponent mixtures combined with the SPD (Spreading Pressure Dependent) model for calculation of activity coefficients in the adsorbed phase. The model has been applied successfully for the adsorption of binary ...... mixtures of hydrocarbons and carbon dioxide on activated carbons. The model parameters have been determined, and the model has proven to be suited for prediction of adsorption equilibria in the investigated systems....

Highly reversible lead-carbon battery anode with lead grafting on the carbon surface

KAUST Repository

Yin, Jian; Lin, Nan; Zhang, Wenli; Lin, Zheqi; Zhang, Ziqing; Wang, Yue; Shi, Jun; Bao, Jinpeng; Lin, Haibo

2018-01-01

A novel C/Pb composite has been successfully prepared by electroless plating to reduce the hydrogen evolution and achieve the high reversibility of the anode of lead-carbon battery (LCB). The deposited lead on the surface of C/Pb composite was found to be uniform and adherent to carbon surface. Because lead has been stuck on the surface of C/Pb composite, the embedded structure suppresses the hydrogen evolution of lead-carbon anode and strengthens the connection between carbon additive and sponge lead. Compared with the blank anode, the lead-carbon anode with C/Pb composite displays excellent charge–discharge reversibility, which is attributed to the good connection between carbon additives and lead that has been stuck on the surface of C/Pb composite during the preparation process. The addition of C/Pb composite maintains a solid anode structure with high specific surface area and power volume, and thereby, it plays a significant role in the highly reversible lead-carbon anode.

Highly reversible lead-carbon battery anode with lead grafting on the carbon surface

KAUST Repository

Yin, Jian

2018-03-27

A novel C/Pb composite has been successfully prepared by electroless plating to reduce the hydrogen evolution and achieve the high reversibility of the anode of lead-carbon battery (LCB). The deposited lead on the surface of C/Pb composite was found to be uniform and adherent to carbon surface. Because lead has been stuck on the surface of C/Pb composite, the embedded structure suppresses the hydrogen evolution of lead-carbon anode and strengthens the connection between carbon additive and sponge lead. Compared with the blank anode, the lead-carbon anode with C/Pb composite displays excellent charge–discharge reversibility, which is attributed to the good connection between carbon additives and lead that has been stuck on the surface of C/Pb composite during the preparation process. The addition of C/Pb composite maintains a solid anode structure with high specific surface area and power volume, and thereby, it plays a significant role in the highly reversible lead-carbon anode.

Cyclic Sequences, Events and Evolution of the Sino-Korean Plate,with a Discussion on the Evolution of Molar-tooth Carbonates,Phosphorites and Source Rocks

Institute of Scientific and Technical Information of China (English)

MENG Xianghua; GE Ming

2003-01-01

This paper gives an account of the research that the authors conducted on the cyclic sequences, events and evolutionary history from Proterozoic to Meso-Cenozoic in the Sino-Korean plate based on the principle of the Cosmos-Earth System. The authors divided this plate into 20 super-cyclic or super-mega-cyclic periods and more than 100 Oort periods. The research focused on important sea flooding events, uplift interruption events, tilting movement events, molar-tooth carbonate events, thermal events, polarity reversal events, karst events, volcanic explosion events and storm events, as well as types of resource areas and paleotectonic evolution. By means of the isochronous theory of the Cosmos-Earth System periodicity and based on long-excentricity and periodicity, the authors elaborately studied the paleogeographic evolution of the aulacogen of the Sino-Korean plate, the oolitic beach platform formation, the development of foreland basin and continental rift valley basin, and reconstructed the evolution of tectonic paleogeography and stratigraphic framework in the Sino-Korean plate in terms of evolutionary maps. Finally, the authors gave a profound discussion on the formation and development of molar-tooth carbonates, phosphorites and source rocks.

Proterozoic orogenic belts and rifting of Indian cratons: Geophysical constraints

Directory of Open Access Journals (Sweden)

D.C. Mishra

2014-01-01

Full Text Available The Aravalli–Delhi and Satpura Mobile Belts (ADMB and SMB and the Eastern Ghat Mobile Belt (EGMB in India form major Proterozoic mobile belts with adjoining cratons and contemporary basins. The most convincing features of the ADMB and the SMB have been the crustal layers dipping from both sides in opposite directions, crustal thickening (∼45 km and high density and high conductivity rocks in upper/lower crust associated with faults/thrusts. These observations indicate convergence while domal type reflectors in the lower crust suggest an extensional rifting phase. In case of the SMB, even the remnant of the subducting slab characterized by high conductive and low density slab in lithospheric mantle up to ∼120 km across the Purna–Godavari river faults has been traced which may be caused by fluids due to metamorphism. Subduction related intrusives of the SMB south of it and the ADMB west of it suggest N–S and E–W directed convergence and subduction during Meso–Neoproterozoic convergence. The simultaneous E–W convergence between the Bundelkhand craton and Marwar craton (Western Rajasthan across the ADMB and the N–S convergence between the Bundelkhand craton and the Bhandara and Dharwar cratons across the SMB suggest that the forces of convergence might have been in a NE–SW direction with E–W and N–S components in the two cases, respectively. This explains the arcuate shaped collision zone of the ADMB and the SMB which are connected in their western part. The Eastern Ghat Mobile Belt (EGMB also shows signatures of E–W directed Meso–Neoproterozoic convergence with East Antarctica similar to ADMB in north India. Foreland basins such as Vindhyan (ADMB–SMB, and Kurnool (EGMB Supergroups of rocks were formed during this convergence. Older rocks such as Aravalli (ADMB, Mahakoshal–Bijawar (SMB, and Cuddapah (EGMB Supergroups of rocks with several basic/ultrabasic intrusives along these mobile belts, plausibly formed during

Successive ionization of positive ions of carbon and nitrogen by electron bombardment

International Nuclear Information System (INIS)

Donets, E.D.; Ilyushchenko, V.I.

Experimental studies of deep ionization of heavy ions are described. The applications of such studies in atomic physics, plasma physics and space physics are discussed. Investigations using intersecting ion-electron beams, shifted beams and ion trap sources are described, and data are presented for multi-charged ions of carbon, oxygen and nitrogen. A detailed description of the development of the IEL (electron beam ionizer) source, and the KRION (cryogenic version) source is given, and further data for the multiple ionization of carbon and nitrogen are given for charge states up to C 6+ and N 7+ . The advantages and disadvantages of the KRION source are discussed, and preliminary studies of a new torroidal ion trap source (HIRAC) are presented. (11 figs, 57 refs) (U.S.)

APPLICATIONS OF A SINGLE CARBON ELECTRODE

African Journals Online (AJOL)

Preferred Customer

Page 1 ... ABSTRACT: A single carbon electrode used with a common arc welder has been successfully used on steel to weld, to surface harden, to spot weld sheet, to pierce holes and to do simple brazing. ... applications: welding, spot welding, hole piercing, etc. The metal tube holding the carbon electrodes is banded with ...

An explanation of carbon emission markets

International Nuclear Information System (INIS)

2009-01-01

After having outlined the necessity to drastically reduce anthropic carbon emissions, and discussed how to associate standards, taxes and quota markets, the authors describe how carbon emission markets have emerged: the Kyoto protocol, the emission trade scheme (ETS) of the European Union, other carbon markets (existing or in preparation). They introduce and present four pillars of carbon emission markets: the allocation process, the reliability of emission measurement and control, market records and transparency, and introduction of flexibility. They examine the possibility of success in the development of a greenhouse gas emission market. The authors discuss the problems raised by a design of carbon markets by government and their use by private actors, how to connect existing or future regional carbon markets, the integration of forest and agriculture through new compensatory mechanisms, how to face carbon leaks by widening carbon markets

Waste Composite Sensor Designed by Cellulose and Activated Carbon as Ethylene Absorber

Directory of Open Access Journals (Sweden)

S. Ummartyotin

2016-01-01

Full Text Available Activated carbon was successfully derived from scrap tile waste from thermochemical conversion. Chemical and physical modifications were therefore employed to modify the specific surface area and porosity of activated carbon. Cellulose was successfully extracted from palm front. Designation of waste composite was prepared by cellulose and activated carbon. Less than 30 wt% of activated carbon was integrated into cellulose sheet matrix. It was important to note that there is no change in mechanical and morphological properties. Small amount of activated carbon was well dispersed. In order to investigate the feasibility of composite as active packaging, oxygen permeation rate and ethylene gas adsorption ability were preliminary investigated.

Carbon-carbon: Multi-use composite of exotic artifact?

International Nuclear Information System (INIS)

Hager, J.W.

1993-01-01

Carbon-Carbon composites evolved as the pyrolyzed cousins of the polymer matrix composites, capitalizing on the development of carbon fiber reinforcements. Early success as thermal protection material in ballistic missile reentry vehicles quickly spawned other military applications such as rocket nozzles and exit cones. Despite regulations limiting dissemination of information, the space shuttle and aircraft brake industry benefited from these developments by adapting the C-C fabrication processes to their products. Carbon-carbon has been considered, proposed or used for many other exotic applications: protection against laser weapon assault for SDI; thermal protection for NASP; components of expendable gas turbine engines: dimensionally stable space platforms, mirrors and antennas; thermal management applications such as printed circuit boards and space-based radiators. They have also been incorporated into the design of the Tokamak fusion reactors and NASA space probes and are being considered as replacements for graphite in other nuclear applications. There is significant world-wide interest and research in C-C. The paper traces the history of these developments and explores the technical consequences of rapid product development in the absence of an adequate science base. The unexploited potential of this material system is examined, and the technical challenges and barriers to commercialization are highlighted

Punta del este terrane: meso proterozoic basement and neo proterozoic cover

International Nuclear Information System (INIS)

Preciozzi, F.; Sanchez Bettucci, L.; Basei, M.; Peel, E.; Oyhantcabal, P.; Cordani, U.

2003-01-01

Full text: Eastern basement of Uruguay consists of Meso and Neoproterozoic rocks. Mesoproterozoic basement had been deformed by pre-Brasiliano and Brasiliano events. Regional variations in this basement and in the Neoproterozoic cover show equivalent deformation styles and intensities. Models proposed for tectonic evolution have been scarce and confusing. Specially, the ones that concern the moment of collision and/or juxtaposition of blocks. The Punta del Este Terrane (PET) is composed of gneisses and migmatites formed between 1000 Ma to 900 Ma (Preciozzi et al., 2001). These rocks had been strongly reworked during Brasiliano and Rio Doce orogenesis (ca. 900-500 Ma). This crustal segment represents a high grade metamorphic terrane, which is correlated to some gneissic complexes southwest of Africa. Particularly, it is correlated to Kibaran-Namaqua Belt in Namibia. U-Pb ages between 1000 Ma and 900 Ma, obtained in zircons from tonalitic granitoids, are interpreted as indicative of their crystallization (Fig. 1). Besides, anatectic fluids related to migmatites leucosomes yielded ages of ca. 520 to 540 Ma. This denotes that superimposed metamorphic conditions during Brasiliano orogenesis reached, at least, lower amphibolite facies. PET basement gneisses present Sm-Nd model ages (TDM) between 2.4 to 1.8 Ga, showing long crustal residence, corroborated by the very negative εNd values of –1.3 and –14.3. During Brazilian orogenesy they were affected by deformation processes and anatexis. Metasedimentary PET cover occurs near La Paloma and Rocha towns. It is represented by a siliciclastic metasedimentary succession corresponding to the Rocha formation. In La Pedrera town recognized three sedimentary facies were (1-3): (1) sandstones and pelites; (2) green pelites; and (3) rhytmites. The transition from facies (1) to facies (3) shows the passage from fluvial environment with tidal influence to tidal flat with predominance of sub tidal deposits (Pazos and S�

Determination of rare-earths and other trace elements in neo proterozoic-neo paleozoic dykes from Ceara state, Brazil, by neutron activation analysis

Energy Technology Data Exchange (ETDEWEB)

Anjos, Rafael Martins dos; Figueiredo, Ana M.G., E-mail: rafael.anjos@usp.b, E-mail: anamaria@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro do Reator Nuclear de Pesquisas. Lab. de Analise por Ativacao com Neutrons; Cardoso, Gustavo Luan; Marques, Leila S., E-mail: leila@iag.usp.b [Universidade de Sao Paulo (IAG/USP), SP (Brazil). Inst. de Astronomia, Geofisica e Ciencias Atmosfericas

2011-07-01

Trace elements such as rare earths, U, Th, Ta, Ba and Hf can be very useful in petrogenetic studies of igneous and metamorphic rocks, giving information about the origin and evolution of magmas. Instrumental Neutron Activation Analysis (INAA) is an accurate and precise for trace element analysis in geological samples, and provides the information required for this kind of studies. In this study, rare earths and incompatible trace elements were determined by INAA in the geological reference materials GS-N and BE-N, to quality control, and for the investigation of acid dykes of neo proterozoic-neo paleozoic ages, which outcrop in the Medio Coreau and Ceara Central domains from the Borborema Province (Ceara State). The powdered samples (particle sizes less than 100 mesh), crushed by using a mechanical agate mortar grinder, were irradiated at the IEA-R1 nuclear reactor at IPEN-CNEN/SP, and the induced activity was measured by high resolution gamma-ray spectrometry. The accuracy and precision of the method were evaluated and preliminary results of dyke samples are presented. (author)

An isotopic perspective on growth and differentiation of Proterozoic orogenic crust: From subduction magmatism to cratonization

Science.gov (United States)

Johnson, Simon P.; Korhonen, Fawna J.; Kirkland, Christopher L.; Cliff, John B.; Belousova, Elena A.; Sheppard, Stephen

2017-01-01

The in situ chemical differentiation of continental crust ultimately leads to the long-term stability of the continents. This process, more commonly known as 'cratonization', is driven by deep crustal melting with the transfer of those melts to shallower regions resulting in a strongly chemically stratified crust, with a refractory, dehydrated lower portion overlain by a complementary enriched upper portion. Since the lower to mid portions of continental crust are rarely exposed, investigation of the cratonization process must be through indirect methods. In this study we use in situ Hf and O isotope compositions of both magmatic and inherited zircons from several felsic magmatic suites in the Capricorn Orogen of Western Australia to highlight the differentiation history (i.e. cratonization) of this portion of late Archean to Proterozoic orogenic crust. The Capricorn Orogen shows a distinct tectonomagmatic history that evolves from an active continental margin through to intracratonic reworking, ultimately leading to thermally stable crust that responds similarly to the bounding Archean Pilbara and Yilgarn Cratons. The majority of magmatic zircons from the main magmatic cycles have Hf isotopic compositions that are generally more evolved than CHUR, forming vertical arrays that extend to moderately radiogenic compositions. Complimentary O isotope data, also show a significant variation in composition. However, combined, these data define not only the source components from which the magmas were derived, but also a range of physio-chemical processes that operated during magma transport and emplacement. These data also identify a previously unknown crustal reservoir in the Capricorn Orogen.

Carbon Fiber Reinforced Carbon-Al-Cu Composite for Friction Material.

Science.gov (United States)

Cui, Lihui; Luo, Ruiying; Ma, Denghao

2018-03-31

A carbon/carbon-Al-Cu composite reinforced with carbon fiber 2.5D-polyacrylonitrile-based preforms was fabricated using the pressureless infiltration technique. The Al-Cu alloy liquids were successfully infiltrated into the C/C composites at high temperature and under vacuum. The mechanical and metallographic properties, scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS) of the C/C-Al-Cu composites were analyzed. The results showed that the bending property of the C/C-Al-Cu composites was 189 MPa, whereas that of the pure carbon slide material was only 85 MPa. The compressive strength of C/C-Al-Cu was 213 MPa, whereas that of the pure carbon slide material was only 102 MPa. The resistivity of C/C-Al-Cu was only 1.94 μΩm, which was lower than that of the pure carbon slide material (29.5 μΩm). This finding can be attributed to the "network conduction" structure. Excellent wettability was observed between Al and the carbon matrix at high temperature due to the existence of Al₄C₃. The friction coefficients of the C/C, C/C-Al-Cu, and pure carbon slide composites were 0.152, 0.175, and 0.121, respectively. The wear rate of the C/C-Al-Cu composites reached a minimum value of 2.56 × 10 -7 mm³/Nm. The C/C-Al-Cu composite can be appropriately used as railway current collectors for locomotives.

[Study on influence between activated carbon property and immobilized biological activated carbon purification effect].

Science.gov (United States)

Wang, Guang-zhi; Li, Wei-guang; He, Wen-jie; Han, Hong-da; Ding, Chi; Ma, Xiao-na; Qu, Yan-ming

2006-10-01

By means of immobilizing five kinds of activated carbon, we studied the influence between the chief activated carbon property items and immobilized bioactivated carbon (IBAC) purification effect with the correlation analysis. The result shows that the activated carbon property items which the correlation coefficient is up 0.7 include molasses, abrasion number, hardness, tannin, uniform coefficient, mean particle diameter and effective particle diameter; the activated carbon property items which the correlation coefficient is up 0.5 include pH, iodine, butane and tetrachloride. In succession, the partial correlation analysis shows that activated carbon property items mostly influencing on IBAC purification effect include molasses, hardness, abrasion number, uniform coefficient, mean particle diameter and effective particle diameter. The causation of these property items bringing influence on IBAC purification is that the activated carbon holes distribution (representative activated carbon property item is molasses) provides inhabitable location and adjust food for the dominance bacteria; the mechanical resist-crash property of activated carbon (representative activated carbon property items: abrasion number and hardness) have influence on the stability of biofilm; and the particle diameter size and distribution of activated carbon (representative activated carbon property items: uniform coefficient, mean particle diameter and effective particle diameter) can directly affect the force of water in IBAC filter bed, which brings influence on the dominance bacteria immobilizing on activated carbon.

Preliminary study of lead isotopes in the carbonate-silica veins of Trench 14, Yucca Mountain, Nevada

International Nuclear Information System (INIS)

Zartman, R.E.; Kwak, L.M.

1993-01-01

The sub-vertical carbonate-silica veins filling the Bow Ridge Fault, where exposed in Trench 14 on the east side of Yucca Mountain, carry a lead isotopic signature that can be explained in terms of local sources. Two isotopically distinguishable--silicate and carbonate--fractions of lead are recognized within the vein system as well as in overlying surficial calcrete deposits. The acid-insoluble silicate fraction is contributed largely from the decomposing Miocene volcanic tuff, which forms the wall rock of the fault zone and is a ubiquitous component of the overlying soil. Lead contained in the silicate fraction approaches in isotopic composition that of the Miocene volcanic rocks of Yucca Mountain, but diverges from it in some samples by being more enriched in uranogenic isotopes. The carbonate fraction of lead in both vein and calcrete samples resides dominantly in the HCl- and CH 3 COOH-soluble calcite. HCl evidently also attacks and removes lead from silicate phases, but the milder CH 3 COOH dissolution procedure oftentimes identifies a significantly more radiogenic lead in the calcite. Wind-blown particulate matter brought to the area from Paleozoic and Late Proterozoic limestones in surrounding mountains may be the ultimate source of the calcite. Isotopically more uniform samples suggest that locally the basaltic ash and other volcanic rock have contributed most of the lead to both fractions of the vein system. An important finding of this study is that the data does not require the more exotic mechanisms or origins that have been proposed for the veins. Instead, the remarkably similar lead isotopic properties of the veins to those of the soil calcretes support their interpretation as a surficial, pedogenic phenomenon

Carbon Lorenz Curves

NARCIS (Netherlands)

Groot, L.F.M.|info:eu-repo/dai/nl/073642398

2008-01-01

The purpose of this paper is twofold. First, it exhibits that standard tools in the measurement of income inequality, such as the Lorenz curve and the Gini-index, can successfully be applied to the issues of inequality measurement of carbon emissions and the equity of abatement policies across

Sedimentology and stratigraphy of Neoproterozoic-lower Paleozoic carbonate-siliciclastic succession of the southwesternmost Amazon Craton, state of Rondônia, Brazil

Directory of Open Access Journals (Sweden)

Jhon Willy Lopes Afonso

2018-02-01

Full Text Available ABSTRACT: Facies and stratigraphic analysis were carried out in Neoproterozoic-Lower Paleozoic carbonate-siliciclastic deposits of Cacoal and Pimenta Bueno formations exposed on basement rocks and into the Pimenta Bueno Graben, northwestern portion of Parecis Basin, southwesternmost Amazon Craton. The redescription and redefinion of this succession confirmed the previous interpretation for the Cacoal Formation as a Marinoan (~ 635 Ma cap carbonate. The Cacoal Formation is subdivided here in two units separate by sharp contact found exclusively overlying Mesoproterozoic crystalline basement rocks: 1 a homonymous formation characterized by diamictites, sandstones and siltstones with dropstones interpreted as glacio-marine deposits; and 2 the Espigão d’Oeste Formation that consists of dolostone, dolomitic stromatolites, dolostone-siltstone rhythmite and siltstone interpreted as shallow to moderately deep platform deposits. The Ordovician to Silurian Pimenta Bueno Formation is a filling of Pimenta Bueno graben and overlies locally the Meso and Neoproterozoic rocks. This unit consists in diamictites, sandstones, siltstones and pelites interpreted as glacial-marine and tide- to storm-influenced platform deposits, recording a glacio-eustatic regressive-transgressive event. This new stratigraphic proposal modify the current stratigraphy for the Parecis Basin and suggest, at least, two levels of glaciation exposed in the sothwesternmost Amazon Craton related to the Marinoan and Late Ordovician-Early Silurian events.

Tectonic inheritance and continental rift architecture: Numerical and analogue models of the East African Rift System.

NARCIS (Netherlands)

Corti, G.; van Wijk, J.W.; Cloetingh, S.A.P.L.; Morley, C.

2007-01-01

The western branch of the East African Rift is composed of an arcuate succession of elongate asymmetric basins, which differ in terms of interaction geometry, fault architecture and kinematics, and patterns of uplift/subsidence and erosion/sedimentation. The basins are located within Proterozoic

Windthrow and fallow-forest successions impacts in soil carbon stocks and GHG fluxes spatial variability and dynamics in the Central Russia' reserve spruce ecosystems

Science.gov (United States)

Vasenev, Ivan; Ivanov, Alexey; Komarova, Tatyana; Valentini, Riccardo

2015-04-01

High spatial and temporal variability is mutual feature for most forest soils that is especially obvious in case of their carbon stocks and GHG fluxes. This phenomenon is generally well-known but not so often becomes the object of special precision investigation in detail and small scales so there are still serious gaps in its principal factors understanding due to their high bioclimatic, regional, landscape, tree species and temporal variability. Southern taiga is one of the most environmentally important world zonal forest ecosystems due to its still comparatively intensive carbon biogeochemical cycle and huge area in the northern Eurasia with strong anthropogenic impacts by Western & Central European and Southern & Eastern Asian regions. Central Forest Biospheric Reserve (Tver region, 360 km to North-West from Moscow) is the principal southern-taiga reserve in the European territory of Russia. Since start of its research activity in 1939 the reserve became the regional center of mature spruce ecosystem structure and dynamics investigation. In 1970-1980-s there have been done complex investigations of windthrow soil patterns and fallow-forest successions. Since middle of 1990-s the ecosystem-level GHG fluxes have been observed by eddy covariance method. Since 2012 the detailed year-round monitoring is running in the southern-taiga zonal station of the regional system RusFluxNet with especial attention on the soil carbon stocks and GHG fluxes spatial variability and dynamics due to windthrow and fallow-forest successions (in frame of RF Governmental projects #11.G34.31.0079 and #14.120.14.4266). Soil carbon dynamics is investigated in decades-hundred-year chronosequences of dominated parcels and different-size windthrow soil cover patterns, including direct investigation during last 33 years with detailed mapping, soil profile morphometrics and bulk density, morphogenetic and statistical analysis of mass data. Morphogenetic analysis of microrelief, soil profile

Regional geology of the Pine Creek Geosyncline

International Nuclear Information System (INIS)

Needham, R.S.; Crick, I.H.; Stuart-Smith, P.G.

1980-01-01

The Pine Creek Geosyncline comprises about 14km of chronostratigraphic mainly pelitic and psammitic Lower Proterozoic sediments with interlayered tuff units, resting on granitic late Archaean complexes exposed as three small domes. Sedimentation took place in one basin, and most stratigraphic units are represented throughout the basin. The sediments were regionally deformed and metamorphosed at 1800Ma. Tightly folded greenschist facies strata in the centre grade into isoclinally deformed amphibolite facies metamorphics in the west and northeast. Pre and post-orogenic continental tholeiites, and post-orogenic granite diapirs intrude the Lower Proterozoic metasediments, and the granites are surrounded by hornfels zones up to 10km wide in the greenschist facies terrane. Cover rocks of Carpentarian (Middle Proterozoic) and younger ages rest on all these rocks unconformably and conceal the original basin margins. The Lower Proterozoic metasediments are mainly pelites (about 75 percent) which are commonly carbonaceous, lesser psammites and carbonates (about 10 percent each), and minor rudites (about 5 percent). Volcanic rocks make up about 10 percent of the total sequence. The environment of deposition ranges from shallow-marine to supratidal and fluviatile for most of the sequence, and to flysch in the topmost part. Poor exposure and deep weathering over much of the area hampers correlation of rock units; the correlation preferred by the authors is presented, and possible alternatives are discussed. Regional geological observations pertinent to uranium ore genesis are described. (author)

Pine creek geosyncline

International Nuclear Information System (INIS)

Needham, R.S.; Ewers, G.R.; Ferguson, J.

1988-01-01

The Pine Creek Geosyncline is a 66,000 km 2 inlier of Early Proterozoic metasediments, mafic and felsic intrusives and minor extrusives, surrounding small late Archaean granitic domes. Economic uranium occurrences cluster into three fields, with the Alligator Rivers field being the most significant. The metasediments are alluvial and reduced shallow-water pelites and psammites. Evaporitic carbonate developed on shallow shelves around Archaean islands. Basin development and sedimentation (c. 2000-1870 Ma) were related to gradual subsidence induced by crustal extension. Facies variations and volcanism were in places controlled by the extensional faults. The rocks were metamorphosed to lower the high grade, complexly folded, and intruded by numerous granitoids from c. 1870 to 1730 Ma. Late orogenic felsic volcanics accumulated in local rift systems. Middle Proterozoic sandstone was deposited on a peneplaned and deeply weathered surface from about 1650 Ma. Uranium is enriched in some Archaean and Proterozoic igneous rocks, but there is no local or regional enrichment of the metasedimentary hosts or of the unconformably overlying sandstone. There is no regional gravity, magnetic or radiometric character attributable to the region's significance as a uranium province; contrasts with surrounding sedimentary basins reflect expected differences in rock properties between a heterogeneous igneous/metamorphic region and relatively homogeneous undeformed and unmineralized sediments. Uranium-enriched Archaean and Proterozoic granitoids and felsic volcanics with labile U are likely though not exclusive source rocks. U was probably transported in oxidized low temperature solutions as uranyl complexes and precipitated in reduced, structurally controlled, low-pressure traps. All uranium occurrences are broadly classified as 'Proterozoic unconformity related'. Greatest potential for further discovery is offered in the Alligator Rivers field, where perhaps at least 3 to 5.5 times the

Wyoming Carbon Capture and Storage Institute

Energy Technology Data Exchange (ETDEWEB)

Nealon, Teresa

2014-06-30

This report outlines the accomplishments of the Wyoming Carbon Capture and Storage (CCS) Technology Institute (WCTI), including creating a website and online course catalog, sponsoring technology transfer workshops, reaching out to interested parties via news briefs and engaging in marketing activities, i.e., advertising and participating in tradeshows. We conclude that the success of WCTI was hampered by the lack of a market. Because there were no supporting financial incentives to store carbon, the private sector had no reason to incur the extra expense of training their staff to implement carbon storage. ii

Microbes in a bottle: Where model organisms and analog systems meet

Science.gov (United States)

Hamilton, T. L.; Weber, M.; Lott, C.; Havig, J. R.; Clark, C.; Bird, L. R.; de Beer, D.; Dron, A.; Freeman, K. H.; Macalady, J. L.

2015-12-01

Understanding the evolution of the Earth's surface chemistry is one of the most exciting challenges in modern geoscience. The Great Oxidation Event occurred ~2.5 Ga, when the concentration of oxygen in the atmosphere increased from productivity and the remineralization of organic matter are intimately linked to planetary redox and thus to levels of O2. As a result, biologic carbon isotope fractionation and other biomarkers (i.e. hopanoids) facilitate our interpretation of biogeochemical cycling during the Proterozoic Eon. Here, we describe the isolation and characterization of two photoautotrophs—the dominant primary producers—from a Proterozoic Ocean analog. We examined the 13C fractionation in the microbial mat and employed in situ microcosms to estimate primary productivity. In addition, we deployed diver-operated microsensors to determine oxygen production and sulfide consumption over a 24-hour cycle and sequenced total RNA from 4 time points. Using these data, we examined primary production in pure cultures of the dominant Cyanobacteria and green sulfur bacteria from the mat under conditions that mimic those observed in situ. We use this information to begin to build a model of oxygen production and organic carbon burial in a Proterozoic-like environment where Cyanobacteria can contribute to primary productivity in the absence of oxygen production. Furthermore, we examined the differences between 13C fractionation in cultures maintained under "ideal" conditions compared to those observed in situ. Collectively, the RNA sequencing data, the in situ primary productivity data and pure culture information were necessary to interpret the 13C signal from the mats.

An Overview of Uranium Exploration Strategy in India

Energy Technology Data Exchange (ETDEWEB)

Chaki, A., E-mail: director.amd@gov.in [Atomic Minerals Directorate for Exploration and Research, Hyderabad (India)

2014-05-15

Uranium exploration in India dates back from 1949 and the first mineralized area was located in the early 1950s in Singhbhum Shear Zone (SSZ), eastern India. Since then, a number of potential and promising uranium provinces have been established in India. The potential uranium provinces include SSZ, Dongargarh, Aravalli, Siwalik belt, Mahadek basin, south-western and northern parts of Cuddapah basin, North Delhi Fold Belt, Bhima and Kaladgi basins. The promising uranium provinces are Proterozoic Chhattisgarh, Indravati, Gwalior, Vindhyan, Shillong basins, Gondwana basins of Central India and semi-arid regions of western Rajasthan. With the establishment of large tonnage-high grade Lower-middle Proterozoic unconformity deposits in Canada and Australia, there was a paradigm shift in the exploration strategy towards the Proterozoic basins of India. The discovery of unconformity related uranium mineralisation in the northern part of Proterozoic Cuddapah basin in southern India in 1991 and discovery of few deposits in the province has opened the avenues for finding of similar deposits in Cuddapah and other 13 Proterozoic basins in India. As a sequel, Proterozoic Bhima basin in southern India has been recognized as a potential target for uranium mineralization, where a low tonnage medium grade deposit has been established and mine development works are in progress. Sustained exploration efforts in other Proterozoic basins have yielded success in a few basins such as Deshnur area in Kaladgi Basin of southern India. Considerable uranium resources have been established in Proterozoic Cuddapah and Bhima basins. Apart from northern parts of Cuddapah and Bhima basins, areas in the southwestern part of Cuddapah basin for stratabound type, where a mine is under construction; Proterozoic Kaladgi basin for vein type; Cretaceous Mahadek basin for sandstone type and the North Delhi Fold belt for vein type of mineralization have been prioritized as potential areas for exploration

Dynamics of dissolved organic carbon in a stream during a quarter century of forest succession

Science.gov (United States)

Judy L. Meyer; Jackson Webster; Jennifer Knoepp; E.F. Benfield

2014-01-01

Dissolved organic carbon (DOC) is a heterogeneous mixture of compounds that makes up a large fraction of the organic matter transported in streams. It plays a significant role in many ecosystems. Riverine DOC links organic carbon cycles of continental and oceanic ecosystems. It is a significant trophic resource in stream food webs. DOC imparts color to lakes,...

Hypervelocity technology carbon/carbon testing

Science.gov (United States)

Anselmo, John V.; Kretz, Lawrence O.

The paper describes the procedures used at the Structures Test Laboratory of the Wright Laboratory's Flight Dynamics Directorate to test a carbon/carbon hot structure representing a typical hypersonic gliding body, and presents the results of tests. The forebody was heated to 1371 C over 13 test runs, using radiant quartz lamps; a vertical shear force of 5.34 kN was introduced to the nose at a stabilized temperature of 816 C. Test data were collected using prototype high-temperature strain gages, in-house-designed high-temperature extensometers, conventional strain gages, and thermocouples. Video footage was taken of all test runs. Test runs were successfully completed up to 1371 C with flight typical thermal gradients at heating rates up to 5.56 C/sec. Results showed that, overall, the termal test control systems performed as predicted and that test temperatures and thermal gradients were achieved to within about 5 percent in most cases.

Wetland succession in a permafrost collapse: interactions between fire and thermokarst

Directory of Open Access Journals (Sweden)

I. H. Myers-Smith

2008-09-01

Full Text Available To determine the influence of fire and thermokarst in a boreal landscape, we investigated peat cores within and adjacent to a permafrost collapse feature on the Tanana River Floodplain of Interior Alaska. Radioisotope dating, diatom assemblages, plant macrofossils, charcoal fragments, and carbon and nitrogen content of the peat profile indicate ~600 years of vegetation succession with a transition from a terrestrial forest to a sedge-dominated wetland over 100 years ago, and to a Sphagnum-dominated peatland in approximately 1970. The shift from sedge to Sphagnum, and a decrease in the detrended tree-ring width index of black spruce trees adjacent to the collapse coincided with an increase in the growing season temperature record from Fairbanks. This concurrent wetland succession and reduced growth of black spruce trees indicates a step-wise ecosystem-level response to a change in regional climate. In 2001, fire was observed coincident with permafrost collapse and resulted in lateral expansion of the peatland. These observations and the peat profile suggest that future warming and/or increased fire disturbance could promote permafrost degradation, peatland expansion, and increase carbon storage across this landscape; however, the development of drought conditions could reduce the success of both black spruce and Sphagnum, and potentially decrease the long-term ecosystem carbon storage.

An Empirical Study on Low-Carbon: Human Resources Performance Evaluation

Directory of Open Access Journals (Sweden)

Quan Chen

2018-01-01

Full Text Available Low-carbon logistics meets the requirements of a low-carbon economy and is the most effective operating model for logistic development to achieve sustainability by coping with severe energy consumption and global warming. Low-carbon logistics aims to reduce carbon intensity rather than simply reduce energy consumption and carbon emissions. Human resources are an important part of the great competition in the logistics market and significantly affect the operations of enterprises. Performance evaluations of human resources are particularly important for low-carbon logistics enterprises with scarce talents. Such evaluations in these enterprises are of great significance for their strategic development. This study constructed a human resource performance evaluation system to assess non-managerial employees’ low-carbon job capacity, job performance, and job attitude in the low-carbon logistics sector. The case study results revealed that the investigated company enjoyed initial success after having promoted low-carbon concepts and values to its non-managerial employees, and the success was demonstrated by excellent performance in its employees’ job attitude and knowledge. This study adopts the AHP method to reasonably determine an indicator system of performance evaluation and its weight to avoid certain human-caused bias. This study not only fills the gap in the related literature, but can also be applied to industrial practice.

An Empirical Study on Low-Carbon: Human Resources Performance Evaluation

Science.gov (United States)

Chen, Quan; Tsai, Sang-Bing; Zhou, Jie; Yu, Jian; Chang, Li-Chung; Li, Guodong; Zheng, Yuxiang; Wang, Jiangtao

2018-01-01

Low-carbon logistics meets the requirements of a low-carbon economy and is the most effective operating model for logistic development to achieve sustainability by coping with severe energy consumption and global warming. Low-carbon logistics aims to reduce carbon intensity rather than simply reduce energy consumption and carbon emissions. Human resources are an important part of the great competition in the logistics market and significantly affect the operations of enterprises. Performance evaluations of human resources are particularly important for low-carbon logistics enterprises with scarce talents. Such evaluations in these enterprises are of great significance for their strategic development. This study constructed a human resource performance evaluation system to assess non-managerial employees’ low-carbon job capacity, job performance, and job attitude in the low-carbon logistics sector. The case study results revealed that the investigated company enjoyed initial success after having promoted low-carbon concepts and values to its non-managerial employees, and the success was demonstrated by excellent performance in its employees’ job attitude and knowledge. This study adopts the AHP method to reasonably determine an indicator system of performance evaluation and its weight to avoid certain human-caused bias. This study not only fills the gap in the related literature, but can also be applied to industrial practice. PMID:29301375

An Empirical Study on Low-Carbon: Human Resources Performance Evaluation.

Science.gov (United States)

Chen, Quan; Tsai, Sang-Bing; Zhai, Yuming; Zhou, Jie; Yu, Jian; Chang, Li-Chung; Li, Guodong; Zheng, Yuxiang; Wang, Jiangtao

2018-01-03

Low-carbon logistics meets the requirements of a low-carbon economy and is the most effective operating model for logistic development to achieve sustainability by coping with severe energy consumption and global warming. Low-carbon logistics aims to reduce carbon intensity rather than simply reduce energy consumption and carbon emissions. Human resources are an important part of the great competition in the logistics market and significantly affect the operations of enterprises. Performance evaluations of human resources are particularly important for low-carbon logistics enterprises with scarce talents. Such evaluations in these enterprises are of great significance for their strategic development. This study constructed a human resource performance evaluation system to assess non-managerial employees' low-carbon job capacity, job performance, and job attitude in the low-carbon logistics sector. The case study results revealed that the investigated company enjoyed initial success after having promoted low-carbon concepts and values to its non-managerial employees, and the success was demonstrated by excellent performance in its employees' job attitude and knowledge. This study adopts the AHP method to reasonably determine an indicator system of performance evaluation and its weight to avoid certain human-caused bias. This study not only fills the gap in the related literature, but can also be applied to industrial practice.

Soil carbon sequestration, carbon markets, and conservation agriculture practices: A hypothetical examination in Mozambique

Directory of Open Access Journals (Sweden)

Timoteo E. Simone

2017-09-01

Full Text Available Payments for Environmental Services (PES are relatively novel mechanisms whereby the adoption of sustainable management practices by a stakeholder is rewarded by incentives linked to external markets. Adoption of PES for conservation agricultural practices (CAPS by smallholder farmers may provide opportunities to increase household income or cover the technology costs of adoption if the carbon sequestration benefits of CAPS are quantifiable, adoption rates are accelerated and maintained, a mechanism exists whereby carbon sequestration services can be compensated, and carbon offset exchange markets are viable. This research suggests a methodology to examine a PES market for carbon offsets generated by the adoption of CAPS by farmers in Mozambique. Assuming a cumulative adoption of 60% over a 20-year period, revenue from PES market participation to CA adopters was two times higher than revenue earned when disadoption occurred midway through the simulation. Lower adoption targets are associated with higher per household returns when fertilizer rates typical to the region are increased. Establishing and maintaining a sustainable PES system in the study region would require significant investment in time and resources. The lack of on-the-ground institutions or local support for such a program would also challenge successful implementation. Finally, the programs where participant success depends on external markets, such as the hypothetical one suggested here, are subject to the ebb and flow of foreign demand for carbon offsets. Addressing these three broad constraints to a PES/CAPS program in the region would require grass-roots driven policy initiatives with buy-in at multiple social, economic, and political levels.

Dynamics of soil organic carbon in density fractions during post-agricultural succession over two lithology types, southwest China.

Science.gov (United States)

Wen, Li; Li, Dejun; Chen, Hao; Wang, Kelin

2017-10-01

Agricultural abandonment has been proposed as an effective way to enhance soil organic carbon (SOC) sequestration. Nevertheless, SOC sequestration in the long term is largely determined by whether the stable SOC fractions will increase. Here the dynamics of SOC fractions during post-agricultural succession were investigated in a karst region, southwest China using a space-for-time substitution approach. Cropland, grassland, shrubland and secondary forest were selected from areas underlain by dolomite and limestone, respectively. Density fractionation was used to separate bulk SOC into free light fraction (FLFC) and heavy fraction (HFC). FLFC contents were similar over dolomite and limestone, but bulk SOC and HFC contents were greater over limestone than over dolomite. FLFC content in the forest was greater than in the other vegetation types, but bulk SOC and HFC contents increased from the cropland through to the forest for areas underlain by dolomite. The contents of bulk SOC and its fractions were similar among the four vegetation types over limestone. The proportion of FLFC in bulk SOC was higher over dolomite than over limestone, but the case was inverse for the proportion of HFC, indicating SOC over limestone was more stable. However, the proportions of both FLFC and HFC were similar among the four vegetation types, implying that SOC stability was not changed by cropland conversion. Exchangeable calcium explained most of the variance of HFC content. Our study suggests that lithology not only affects SOC content and its stability, but modulates the dynamics of SOC fractions during post-agricultural succession. Copyright © 2017 Elsevier Ltd. All rights reserved.

Globalizing carbon lock-in

International Nuclear Information System (INIS)

Unruh, Gregory C.; Carrillo-Hermosilla, Javier

2006-01-01

This paper extends the arguments surrounding carbon lock-in elaborated in Unruh (Energy Policy 28 (2000) 817; 30 (2002) 317) to countries currently undergoing industrialization. It argues that, for numerous reasons, industrializing countries are unlikely to leapfrog carbon intensive energy development. On the contrary, carbon lock-in may be globalizing and could further constrain climate change mitigation options. It is then argued that many policy recommendations ignore carbon lock-in, possibly limiting their potential for successful implementation. The paper then discusses four policy approaches that appear to have advantages given lock-in conditions. It is recognized, however, that relative ease of implementation does not necessarily equate with superiority. Instead, it is merely a path dependent outcome of past development decisions. Pursuing policies on the basis of relative implementation ease may help address the issue of climate change, but could also result in sub-optimal outcomes along other dimensions of sustainable development

Reactivation of the Archean-Proterozoic suture along the southern margin of Laurentia during the Mazatzal orogeny: Petrogenesis and tectonic implications of ca. 1.63 Ga granite in southeastern Wyoming

Science.gov (United States)

Jones, Daniel S.; Barnes, Calvin G.; Premo, Wayne R.; Snoke, Arthur W.

2013-01-01

The presence of ca. 1.63 Ga monzogranite (the “white quartz monzonite”) in the southern Sierra Madre, southeastern Wyoming, is anomalous given its distance from the nearest documented plutons of similar age (central Colorado) and the nearest contemporaneous tectonic margin (New Mexico). It is located immediately south of the Cheyenne belt—a ca. 1.75 Ga Archean-Proterozoic tectonic suture. New geochronological, isotopic, and geochemical data suggest that emplacement of the white quartz monzonite occurred between ca. 1645 and 1628 Ma (main pulse ca. 1628 Ma) and that the white quartz monzonite originated primarily by partial melting of the Big Creek Gneiss, a modified arc complex. There is no evidence that mafic magmas were involved. Open folds of the ca. 1750 Ma regional foliation are cut by undeformed white quartz monzonite. On a regional scale, rocks intruded by the white quartz monzonite have experienced higher pressure and temperature conditions and are migmatitic as compared to the surrounding rocks, suggesting a genetic relationship between the white quartz monzonite and tectonic exhumation. We propose that regional shortening imbricated the Big Creek Gneiss, uplifting the now-exposed high-grade rocks of the Big Creek Gneiss (hanging wall of the thrust and wall rock to the white quartz monzonite) and burying correlative rocks, which partially melted to form the white quartz monzonite. This tectonism is attributed to the ca. 1.65 Ga Mazatzal orogeny, as foreland shortening spread progressively into the Yavapai Province. Mazatzal foreland effects have also been described in the Great Lakes region and have been inferred in the Black Hills of South Dakota. We suggest that the crustal-scale rheologic contrast across the Archean-Proterozoic suture, originally developed along the southern margin of Laurentia, and including the Cheyenne belt, facilitated widespread reactivation of that boundary during the Mazatzal orogeny. This finding emphasizes the degree to

Enhanced electrochemical activity using vertically aligned carbon nanotube electrodes grown on carbon fiber

Directory of Open Access Journals (Sweden)

Evandro Augusto de Morais

2011-09-01

Full Text Available Vertically aligned carbon nanotubes were successfully grown on flexible carbon fibers by plasma enhanced chemical vapor deposition. The diameter of the CNT is controllable by adjusting the thickness of the catalyst Ni layer deposited on the fiber. Vertically aligned nanotubes were grown in a Plasma Enhanced Chemical Deposition system (PECVD at a temperature of 630 ºC, d.c. bias of -600 V and 160 and 68 sccm flow of ammonia and acetylene, respectively. Using cyclic voltammetry measurements, an increase of the surface area of our electrodes, up to 50 times higher, was observed in our samples with CNT. The combination of VACNTs with flexible carbon fibers can have a significant impact on applications ranging from sensors to electrodes for fuel cells.

Shear Wave Velocity Structure of Southern African Crust: Evidence for Compositional Heterogeneity within Archaean and Proterozoic Terrains

Energy Technology Data Exchange (ETDEWEB)

Kgaswane, E M; Nyblade, A A; Julia, J; Dirks, P H H M; Durrheim, R J; Pasyanos, M E

2008-11-11

Crustal structure in southern Africa has been investigated by jointly inverting receiver functions and Rayleigh wave group velocities for 89 broadband seismic stations spanning much of the Precambrian shield of southern Africa. 1-D shear wave velocity profiles obtained from the inversion yield Moho depths that are similar to those reported in previous studies and show considerable variability in the shear wave velocity structure of the lower part of the crust between some terrains. For many of the Archaean and Proterozoic terrains in the shield, S velocities reach 4.0 km/s or higher over a substantial part of the lower crust. However, for most of the Kimberley terrain and adjacent parts of the Kheis Province and Witwatersrand terrain, as well as for the western part of the Tokwe terrain, mean shear wave velocities of {le} 3.9 km/s characterize the lower part of the crust along with slightly ({approx}5 km) thinner crust. These findings indicate that the lower crust across much of the shield has a predominantly mafic composition, except for the southwest portion of the Kaapvaal Craton and western portion of the Zimbabwe Craton, where the lower crust is intermediate-to-felsic in composition. The parts of the Kaapvaal Craton underlain by intermediate-to-felsic lower crust coincide with regions where Ventersdorp rocks have been preserved, and thus we suggest that the intermediate-to-felsic composition of the lower crust and the shallower Moho may have resulted from crustal melting during the Ventersdorp tectonomagmatic event at c. 2.7 Ga and concomitant crustal thinning caused by rifting.

Cambrian-lower Middle Ordovician passive carbonate margin, southern Appalachians: Chapter 14

Science.gov (United States)

Read, J. Fred; Repetski, John E.

2012-01-01

The southern Appalachian part of the Cambrian–Ordovician passive margin succession of the great American carbonate bank extends from the Lower Cambrian to the lower Middle Ordovician, is as much as 3.5 km (2.2 mi) thick, and has long-term subsidence rates exceeding 5 cm (2 in.)/k.y. Subsiding depocenters separated by arches controlled sediment thickness. The succession consists of five supersequences, each of which contains several third-order sequences, and numerous meter-scale parasequences. Siliciclastic-prone supersequence 1 (Lower Cambrian Chilhowee Group fluvial rift clastics grading up into shelf siliciclastics) underlies the passive margin carbonates. Supersequence 2 consists of the Lower Cambrian Shady Dolomite–Rome-Waynesboro Formations. This is a shallowing-upward ramp succession of thinly bedded to nodular lime mudstones up into carbonate mud-mound facies, overlain by lowstand quartzose carbonates, and then a rimmed shelf succession capped by highly cyclic regressive carbonates and red beds (Rome-Waynesboro Formations). Foreslope facies include megabreccias, grainstone, and thin-bedded carbonate turbidites and deep-water rhythmites. Supersequence 3 rests on a major unconformity and consists of a Middle Cambrian differentiated rimmed shelf carbonate with highly cyclic facies (Elbrook Formation) extending in from the rim and passing via an oolitic ramp into a large structurally controlled intrashelf basin (Conasauga Shale). Filling of the intrashelf basin caused widespread deposition of thin quartz sandstones at the base of supersequence 4, overlain by widespread cyclic carbonates (Upper Cambrian lower Knox Group Copper Ridge Dolomite in the south; Conococheague Formation in the north). Supersequence 5 (Lower Ordovician upper Knox in the south; Lower to Middle Ordovician Beekmantown Group in the north) has a basal quartz sandstone-prone unit, overlain by cyclic ramp carbonates, that grade downdip into thrombolite grainstone and then storm

Carbon accounting and the climate politics of forestry

International Nuclear Information System (INIS)

Ellison, David; Lundblad, Mattias; Petersson, Hans

2011-01-01

Many proposals have been made for the more successful inclusion of LULUCF (Land Use, Land Use Change and Forestry) in the Kyoto framework. Though the positions of individual states or the goal of avoided deforestation guide many approaches, our model sets cost-effective strategies for climate change mitigation and the efficient and balanced use of forest resources at its center. Current approaches to forest resource-based carbon accounting consider only a fraction of its potential and fail to adequately mobilize the LULUCF sector for the successful stabilization of atmospheric greenhouse gas (GHG) concentrations. The presence of a significantly large “incentive gap” justifies the urgency of reforming the current LULUCF carbon accounting framework. In addition to significantly broadening the scope of carbon pools accounted under LULUCF, we recommend paying far greater attention to the troika of competing but potentially compatible interests surrounding the promotion of standing forests (in particular for the purposes of carbon sequestration, biodiversity protection and ecosystem promotion/ preservation), harvested wood products (HWP) and bioenergy use. The successful balancing of competing interests, the enhancement of efficiency and effectiveness and the balanced use of forest resources require an accounting mechanism that weighs and rewards each component according to its real climate mitigation potential. Further, our data suggest the benefits of such a broadly based carbon accounting strategy and the inclusion of LULUCF in national and international accounting and emission trading mechanisms far outweigh potential disadvantages. Political arguments suggesting countries could take advantage of LULUCF accounting to reduce their commitments are not supported by the evidence we present.

Isotopic Signature of the Ancient Biosphere

Science.gov (United States)

DesMarais, D. J.; Chang, Sherwood (Technical Monitor)

1997-01-01

The age distribution of 261 field localities, sampled for their well-preserved Archean and Proterozoic sedimentary rocks, revealed a 500-700 Ma episodicity. Assuming that the numbers of sites are a proxy for mass of sediments, the record of well-preserved sediments is more abundant in the intervals 3.5-3.3, 2.8-2.5, 2.1-1.8, 1.5-1.3, and 1.0-0.54 Ga than in the intervening intervals. It is proposed that the crustal inventory of photosynthetic organic carbon was modulated by the volume of sedimentation in sites favorable for the burial and long-term preservation of organic carbon. Tectonic processes controlled this sediment volume. Episodic increases in the organic inventory led to stepwise increases in oxidized reservoirs (e.g., O2, SO4(2-), Fe(3+). The interval 2.9-2.5 Ga recorded a large rise in seawater Sr-87/Sr-86, the oldest-known extensive banded iron formations, and the first evidence (C-13-depleted kerogens) of O2 use by methylotrophic bacteria. The interval 2.2-1.8 Ga has both carbon isotopic evidence for a stepwise increase in the organic reservoir and also paleosol evidence for an O2 increase. The interval 1.1-0.6 Ga shows isotopic evidence for another organic carbon increase. The interval 1.5-1.3 Ga revealed no such increases as yet, perhaps because incomplete rifting of the mid-Proterozoic supercontinent was associated with extensive sedimentation in oxidized continental basins, producing redbeds, coarse clastics, etc. Such sedimentation did not promote the burial of reduced carbon.

[Succession of chitinolytic microorganisms in chernozem soil].

Science.gov (United States)

Manucharova, N A; Belova, E V; Vorob'ev, A V; Polianskaia, L M; Stepanov, A L

2005-01-01

The chitinolytic prokaryotic and eukaryotic microbial complex of chernozem soil has been investigated in the course of a succession initiated by the introduction of chitin and humidification. The dynamics of the cell numbers of chitinolytic microorganisms and of their biomass was assessed by fluorescent microscopy and by inoculation of selective media. Emission of carbon dioxide and nitrous oxide, as well as dinitrogen fixation, was assessed by gas chromatography. It was found that, when the succession was initiated by the introduction of both chitin and humidification, it resulted in greater cell numbers and biomass of chitinolytic microorganisms and higher levels of CO2 and N2O emission and of nitrogen fixation than when the succession was initiated by humidification alone. As compared to the control samples, a significant (twofold) increase in the prokaryote cell number and biomass was found on the fourth day of the succession initiated by humidification and introduction of chitin. One week after the initiation of succession, the fungal biomass and length of mycelium were twice as high as those in the control samples. These results led to the conclusion that chitin utilization in chernozem soil starts during the initial stages of succession and is performed by both prokaryotic and eukaryotic microorganisms.

Sapphirine granulites from Panasapattu, Eastern Ghats belt, India: Ultrahigh-temperature metamorphism in a Proterozoic convergent plate margin

Directory of Open Access Journals (Sweden)

C.V. Dharma Rao

2012-01-01

of garnet compositions in the domains where some melt was retained. The post-peak evolution is constrained by a succession of melt-present reactions that occur at p < 10 kbar, inferred from micro-structural relations among various minerals. After high-temperature decompression from the metamorphic peak, the p–T path followed a near isobaric cooling stage to T < 900 °C. The UHT rocks investigated in this study occur within a continental collision suture which witnessed prolonged subduction–accretion history prior to the final collision. We correlate the extreme metamorphism and the stabilization of UHT mineral assemblages to heat and volatile input from an upwelled asthenosphere during subduction–collision tectonics in a Proterozoic convergent plate margin.

Co@Carbon and Co 3 O4@Carbon nanocomposites derived from a single MOF for supercapacitors.

Science.gov (United States)

Dai, Engao; Xu, Jiao; Qiu, Junjie; Liu, Shucheng; Chen, Ping; Liu, Yi

2017-10-03

Developing a composite electrode containing both carbon and transition metal/metal oxide as the supercapacitor electrode can combine the merits and mitigate the shortcomings of both the components. Herein, we report a simple strategy to prepare the hybrid nanostructure of Co@Carbon and Co 3 O 4 @Carbon by pyrolysis a single MOFs precursor. Co-based MOFs (Co-BDC) nanosheets with morphology of regular parallelogram slice have been prepared by a bottom-up synthesis strategy. One-step pyrolysis of Co-BDC, produces a porous carbon layer incorporating well-dispersed Co and Co 3 O 4 nanoparticles. The as-prepared cobalt-carbon composites exhibit the thin layer morphology and large specific surface area with hierarchical porosity. These features significantly improve the ion-accessible surface area for charge storage and shorten the ion transport length in thin dimension, thus contributing to a high specific capacitance. Improved capacitance performance was successfully realized for the asymmetric supercapacitors (ASCs) (Co@Carbon//Co 3 O 4 @Carbon), better than those of the symmetric supercapacitors (SSCs) based on Co@Carbon and Co 3 O 4 @Carbon materials (i.e., Co@Carbon//Co@Carbon and Co 3 O 4 @Carbon//Co 3 O 4 @Carbon). The working voltage of the ASCs can be extended to 1.5 V and show a remarkable high power capability in aqueous electrolyte. This work provides a controllable strategy for nanostructured carbon-metal and carbon-metal oxide composite electrodes from a single precursor.

Applications of a single carbon electrode | Skelskey | SINET ...

African Journals Online (AJOL)

Abstract. A single carbon electrode used with a common arc welder has been successfully used on steel to weld, to surface harden, to spot weld sheet, to pierce holes and to do simple brazing. Key words/phrases: Arc, carbon, dry cell, plasma, welding. SINET: Ethiopian Journal of Science Vol.26(2) 2003: 173-176 ...

Selective extraction of hydrocarbons, phosphonates and phosphonic acids from soils by successive supercritical fluid and pressurized liquid extractions.

Science.gov (United States)

Chaudot, X; Tambuté, A; Caude, M

2000-01-14

Hydrocarbons, dialkyl alkylphosphonates and alkyl alkylphosphonic acids are selectively extracted from spiked soils by successive implementation of supercritical carbon dioxide, supercritical methanol-modified carbon dioxide and pressurized water. More than 95% of hydrocarbons are extracted during the first step (pure supercritical carbon dioxide extraction) whereas no organophosphorus compound is evidenced in this first extract. A quantitative extraction of phosphonates is achieved during the second step (methanol-modified supercritical carbon dioxide extraction). Polar phosphonic acids are extracted during a third step (pressurized water extraction) and analyzed by gas chromatography under methylated derivatives (diazomethane derivatization). Global recoveries for these compounds are close to 80%, a loss of about 20% occurring during the derivatization process (co-evaporation with solvent). The developed selective extraction method was successfully applied to a soil sample during an international collaborative exercise.

Prokaryotic algae associated with Australian proterozoic stromatolites.

Science.gov (United States)

Licari, G R; Cloud, P

1972-09-01

Five instances of association between distinctive stromatolites and blue-green algal nannofossils are recorded from a 100-m sequence of carbonate rocks about 1.6 x 10(9) years old, along the south side of Paradise Creek, northwestern Queensland, Australia. No eukaryotes were identified in any of these systematically limited assemblages, although they are known from rocks as old as 1.3 x 10(9) years in eastern California. Thus, eukaryotes may not have appeared until after 1.6 x 10(9) years ago (but before 1.3 x 10(9) years ago). The associations observed would also be consistent with (but do not prove) a biotic influence on stromatolite morphology. As is usual among prePaleozoic forms described, the morphology of the nannofossils is very similar to living forms, displaying marked evolutionary conservatism. Primary orientation of stromatolitic laminae and columns is not invariably convex upward, as conventionally believed, but convex away from and parallel to the initial point or surface of attachment, which may be horizontal or even downward beneath overhangs.

Carbon cycle observations: gaps threaten climate mitigation policies

Science.gov (United States)

Richard Birdsey; Nick Bates; MIke Behrenfeld; Kenneth Davis; Scott C. Doney; Richard Feely; Dennis Hansell; Linda Heath; et al.

2009-01-01

Successful management of carbon dioxide (CO2) requires robust and sustained carbon cycle observations. Yet key elements of a national observation network are lacking or at risk. A U.S. National Research Council review of the U.S. Climate Change Science Program earlier this year highlighted the critical need for a U.S. climate observing system to...

Nitrogen Cycling throughout Secondary Succession following Agricultural Disturbance in North-Central Virginia

Science.gov (United States)

Parisien, A.; Epstein, H. E.

2017-12-01

While much is known about the carbon cycle during succession that follows agricultural disturbance, less understood are the dynamics of the nitrogen cycle throughout secondary succession, and how plant-available nitrogen may or may not limit vegetation transitions and net primary productivity over time. Two chronosequences at the Blandy Experimental Farm in Boyce, north-central Virginia were examined to elucidate the complexities of the nitrogen cycle over a temporal successional gradient. Each chronosequence consists of one early, one mid, and one late secondary successional field ( 15 years, 30 years, and 100 years post agricultural abandonment, respectively). Five 10x10 m plots were established in each of the 6 fields for a total of 30 plots. Total soil nitrogen (and carbon) data were collected from soils to 30 cm depth at 10-cm intervals, and net nitrogen mineralization and nitrification were estimated using an in situ soil core with anion-cation exchange resin bag technique. Previous studies of carbon cycling at this location have indicated relatively constant soil CO2 efflux of approximately 1100 g C/m2, as well as increasing net primary production and therefore net ecosystem production, with time since abandonment. In addition, soil C and N, and the soil C:N ratio have been shown to increase from the early to late successional plots. Our current study marks the first comprehensive examination of soil nitrogen dynamics including mineralization and nitrification over a successional gradient at Blandy Farm. A thorough understanding of nitrogen dynamics during secondary succession is especially important in the southeastern United States, where a large portion of previously cultivated land has been abandoned over the past century, due to advances in farming efficiency and the move westward to more fertile soils. Much of the southeastern U.S. is now undergoing secondary succession, and quality data on the dynamics of nitrogen cycling during this procession can

A Success Story of Organizing Small Scale Farmers in Kenya

DEFF Research Database (Denmark)

Buch-Hansen, Mogens

2012-01-01

, but not least to be used in PES schemes. The article emphasizes vertical integration and production diversification, enabling market conditions, and democratization as the main factors in KTDA’s success that could possibly be replicated in promoting small scale farmers participating in the post-Kyoto carbon...

Preparation of nanosize carbon powders by pulsed wire discharge

Energy Technology Data Exchange (ETDEWEB)

Minami, C.; Kinemuchi, Y.; Suzuki, T.; Suematsu, H.; Jiang, W.; Yatsui, K. [Nagaoka Univ. of Technology, Extreme Energy-Density Research Inst., Nagaoka, Niigata (Japan); Hirata, T.; Hatakeyama, R. [Tohoku Univ., Graduate School of Engineering, Sendai, Miyagi (Japan)

2002-06-01

Nanosize powders of carbons were tried to be synthesized by pulsed discharge of graphite wires in several kinds of ambient gases. When the wire was discharged in N{sub 2} gas, nanosize powders have been successfully produced. The result of X-ray diffraction analysis indicated that nanosize powders produced in N{sub 2} gas at 750 Torr were amorphous carbon containing glassy carbons, while mass-spectrum analysis demonstrated the production of fullerenes at 600 Torr. If the wire is discharged in Ar gas, dielectric breakdown takes place between electrodes, producing no carbon powders. (author)

Chip-based generation of carbon nanodots via electrochemical oxidation of screen printed carbon electrodes and the applications for efficient cell imaging and electrochemiluminescence enhancement.

Science.gov (United States)

Xu, Yuanhong; Liu, Jingquan; Zhang, Jizhen; Zong, Xidan; Jia, Xiaofang; Li, Dan; Wang, Erkang

2015-06-07

A portable lab-on-a-chip methodology to generate ionic liquid-functionalized carbon nanodots (CNDs) was developed via electrochemical oxidation of screen printed carbon electrodes. The CNDs can be successfully applied for efficient cell imaging and solid-state electrochemiluminescence sensor fabrication on the paper-based chips.

The provinces and carbon pricing : three inconvenient truths

Energy Technology Data Exchange (ETDEWEB)

Courchene, T.J.; Allan, J.R. [Queen' s Univ., Kingston, ON (Canada). Inst. of Intergovernmental Relations

2008-12-15

This article discussed the role that the federal government should play in introducing a carbon price policy in Canada whereby a carbon tax would be instituted to send a price signal to those considering future investment in carbon-intensive energy projects. It focused on bridging the gap between federal and provincial jurisdictions and assessed how various carbon pricing models can play a role in environmental federalism while allowing provinces to remain involved in policy making. Policy commitments related to emissions and cap-and-trade systems were discussed along with carbon import tariffs and domestic carbon taxes. In a market-based policy on climate change, proceeds of carbon taxes will serve to reduce greenhouse gas emissions. This article also reviewed tax incentives as well as price signal systems designed to ensure successful climate change adjustments for Canadian enterprises. 1 fig.

The provinces and carbon pricing : three inconvenient truths

International Nuclear Information System (INIS)

Courchene, T.J.; Allan, J.R.

2008-01-01

This article discussed the role that the federal government should play in introducing a carbon price policy in Canada whereby a carbon tax would be instituted to send a price signal to those considering future investment in carbon-intensive energy projects. It focused on bridging the gap between federal and provincial jurisdictions and assessed how various carbon pricing models can play a role in environmental federalism while allowing provinces to remain involved in policy making. Policy commitments related to emissions and cap-and-trade systems were discussed along with carbon import tariffs and domestic carbon taxes. In a market-based policy on climate change, proceeds of carbon taxes will serve to reduce greenhouse gas emissions. This article also reviewed tax incentives as well as price signal systems designed to ensure successful climate change adjustments for Canadian enterprises. 1 fig

Integration of Porous Carbon Nanowrinkles into Carbon Micropost Array for Microsupercapacitors

Directory of Open Access Journals (Sweden)

Shuang Xi

2018-01-01

Full Text Available Porous carbon nanowrinkles (PCW coated on carbon micropost (CMP arrays were successfully fabricated via three-step process, which took advantages of the large difference in elastic moduli between PCW and the raw material of CMP. The effect of nanowrinkle integration on the electrochemical performances was investigated, showing an improved electrochemical performance. The electrode also shows excellent cycling stability, which retains 84% of its initial discharge capacitance after 1700 cycles with >90% Coulombic efficiency. This enhanced electrochemical performance is ascribed to the synergistic effect of enlarged surface area and porous structure of PCW. The obtained PCW/CMP compositing electrode with the advantages of low cost and easy scaling-up has great potential for on-chip supercapacitors.

Toshiba's activity concerning technology succession and human resource development

International Nuclear Information System (INIS)

Ogura, Kenji; Hoshide, Akehiko

2008-01-01

Recently, from the viewpoint of the reduction of carbon-dioxide emission that cause global warming and the energy security, the importance of nuclear power generation is recognized again as an effective approach for solving the problems, and many nuclear power plants are planed to be constructed worldwide. On the other hand, the experienced engineers will face the time of the retirement in the near future and technology succession and human resource development has become important problems. In this paper, Toshiba's Nuclear Energy Systems and Services Division's activity concerning technology succession and human resource development will be introduced. (author)

Carbon composites in space vehicle structures

Science.gov (United States)

Mayer, N. J.

1974-01-01

Recent developments in the technology of carbon or graphite filaments now provide the designer with greatly improved materials offering high specific strength and modulus. Besides these advantages are properties which are distinctly useful for space applications and which provide feasibility for missions not obtainable by other means. Current applications include major and secondary structures of communications satellites. A number of R & D projects are exploring carbon-fiber application to rocket engine motor cases, advanced antenna systems, and space shuttle components. Future system studies are being made, based on the successful application of carbon fibers for orbiting space telescope assemblies, orbital transfer vehicles, and very large deployable energy generation systems. Continued technology development is needed in analysis, material standards, and advanced structural concepts to exploit the full potential of carbon filaments in composite materials.

Carbon in high-purity germanium

International Nuclear Information System (INIS)

Haller, E.E.; Hansen, W.L.; Luke, P.; McMurray, R.; Jarrett, B.

1981-10-01

Using 14 C-spiked pyrolytic graphite-coated quartz crucibles for the growth of nine ultra-pure germanium single crystals, we have determined the carbon content and distribution in these crystals. Using autoradiography, we observe a rapidly decreasing carbon cluster concentration in successively grown crystals. Nuclear radiation detectors made from the crystals measure the betas from the internally decaying 14 C nuclei with close to 100% efficiency. An average value for the total carbon concentration [ 14 C + 12 C] is approx. 2 x 10 14 cm -3 , a value substantially larger than expected from earlier metallurgical studies. Contrary to the most recent measurement, we find the shape of the beta spectrum to agree very well with the statistical shape predicted for allowed transitions

Examples from the Rewa Group of Proterozoic Vindhyan bas

Indian Academy of Sciences (India)

The Rewa Group of the Vindhyan Supergroup in the Son valley begins with a thick (∼200 m) dominantly shaly, shelfal succession, occurring between the Dhandraul Formation of the Kaimur. Group (fluvial sandstone) below and Drammondganj Formation of the Rewa Group (marginal marine sandstone) above. Such a ...

Carbon nanotube formation by laser direct writing

International Nuclear Information System (INIS)

Wu, Y.-T.; Su, H.-C.; Tsai, C.-M.; Liu, K.-L.; Chen, G.-D.; Huang, R.-H.; Yew, T.-R.

2008-01-01

This letter presents carbon nanotube (CNT) formation by laser direct writing using 248 nm KrF excimer pulsed laser in air at room temperature, which was applied to irradiate amorphous carbon (a-C) assisted by Ni catalysts underneath for the transformation of carbon species into CNTs. The CNTs were synthesized under appropriate combination of laser energy density and a-C thickness. The growth mechanism and key parameters to determine the success of CNT formation were also discussed. The demonstration of the CNT growth by laser direct writing in air at room temperature opens an opportunity of in-position CNT formation at low temperatures

Development of a new foil compounded from carbon nanotubes and sputter-deposition carbon

International Nuclear Information System (INIS)

Hiroo Hasebe; Hironori Kuboki; Hiroki Okuno; Isao Yamane; Hiroshi Imao; Nobuhisa Fukunishi; Masayuki Kase; Osamu Kamigaito

2014-01-01

New carbon-nanotube-sputter-deposition-carbon (CNT-SDC) foils were developed and used in the U beam time at the RIKEN RI Beam Factory (RIBF) from October to December 2011. The lifetimes of these new foils were drastically extended, and stable, high-intensity U beams were successfully provided to users. The lifetime of the CNT-SDC foils was 2-5 C, which was 100 times longer than those of static C-foils previously used. The qualitative analysis of the CNT-SDC foils clearly showed that the CNT structure and bundles were broken by beam irradiation. In addition, it was found that CNT bundles in the CNT-SDC foil were grown after the carbon deposition procedure. This structure was considered to be the reason that the CNT-SDC foils maintain advantages of both CNT and SDC foils. (author)

Vascular plant-mediated controls on atmospheric carbon assimilation and peat carbon decomposition under climate change.

Science.gov (United States)

Gavazov, Konstantin; Albrecht, Remy; Buttler, Alexandre; Dorrepaal, Ellen; Garnett, Mark H; Gogo, Sebastien; Hagedorn, Frank; Mills, Robert T E; Robroek, Bjorn J M; Bragazza, Luca

2018-03-23

Climate change can alter peatland plant community composition by promoting the growth of vascular plants. How such vegetation change affects peatland carbon dynamics remains, however, unclear. In order to assess the effect of vegetation change on carbon uptake and release, we performed a vascular plant-removal experiment in two Sphagnum-dominated peatlands that represent contrasting stages of natural vegetation succession along a climatic gradient. Periodic measurements of net ecosystem CO 2 exchange revealed that vascular plants play a crucial role in assuring the potential for net carbon uptake, particularly with a warmer climate. The presence of vascular plants, however, also increased ecosystem respiration, and by using the seasonal variation of respired CO 2 radiocarbon (bomb- 14 C) signature we demonstrate an enhanced heterotrophic decomposition of peat carbon due to rhizosphere priming. The observed rhizosphere priming of peat carbon decomposition was matched by more advanced humification of dissolved organic matter, which remained apparent beyond the plant growing season. Our results underline the relevance of rhizosphere priming in peatlands, especially when assessing the future carbon sink function of peatlands undergoing a shift in vegetation community composition in association with climate change. © 2018 John Wiley & Sons Ltd.

Effects of carbon tax

International Nuclear Information System (INIS)

Michelini, M.

1992-01-01

At the recent United Nations Conference held in Rio de Janeiro, a proposal was made by Italy to have surcharges be applied by OECD member countries on fossil fuels (carbon tax), primarily to fund pollution abatement technology transfer to developing countries and promote pollution abatement, energy conservation and the use of renewable energy sources in industrialized countries. This paper assesses how the application of the proposed carbon tax might be successfully combined with additional fiscal policies favouring coal gasification and reforestation so as to provide energy policy strategists of oil-importing countries with a long term economically and environmentally viable alternative to petroleum imports

A Guidebook for Low-Carbon Development at the Local Level

Energy Technology Data Exchange (ETDEWEB)

Zhou, Nan; Price, Lynn; Ohshita, Stephanie; Zheng, Nina; Min, Hu

2011-10-31

This report aims to provide a manual with a menu of the successful policies and measures for local governments in China to create low carbon plan or climate action plans. This manual includes a comprehensive list of successful policies and best practices.

SOIL ORGANIC MATTER DYNAMICS UPON SECONDARY SUCCESSION IN IMPERATA GRASSLAND, EAST KALIMANTAN, INDONESIA

Directory of Open Access Journals (Sweden)

Ishak Yassir

2015-04-01

Full Text Available Soil organic matter (SOM dynamics upon secondary succession in Imperata grassland was studied by stable carbon isotope analysis. The data of litter and soil samples of twenty plots in four different stages of succession were compared. These different stages were represented by plots that were; (1 last burned 3 years before sampling (Imperata grassland, (2 last burned 9 years before, (3 a secondary forest (≥15 years and (4 a primary forest. Result showed that isotopic signatures of all soil horizons of the regeneration stages were statistically different from those of the primary forest. The A-horizon under the 3-years Imperata plot still contained 23% forest (C3 carbon, and this fraction increased to 51% in the-B-horizon. In the 9-years plot and in the secondary forest, the C3 carbon on the A-horizon increased to 51% and 96%, respectively. In the topsoil, the loss of C4-C between the 3-years and the 9-years plot was significant, while it appeared negligible in the AB-horizon. The strong decay in the topsoil under Imperata grassland may be due to the rather high carbohydrate content of the SOM, which is considered easily decomposable. Further research is needed especially to explore the relation between carbon stocks and chemical of SOM composition. Such insight may help to better understand and predict soil carbon changes in relation to climate and vegetation change.

Equal exchange: Determining a fair price for carbon

Energy Technology Data Exchange (ETDEWEB)

Hodes, G.; Kamel, S.

2007-12-14

This first volume in the new series CD4CDM Perspective Series focuses on determining an equal exchange between carbon buyers and sellers in CDM transactions. Contributors to this volume represent a wide spectrum of the various market actors that are interacting in order to realize both successful and equitable carbon transactions. The following issues are discussed: Global carbon price dynamics; CDM project risk profiles and/or premiums; Importance of time factors and delivery guarantees; Impact of regulatory drivers and post-Kyoto outlook; Region-specific outlooks; Strategies, contracting models and approaches. (BA)

Biogeochemical Modeling of the Second Rise of Oxygen

Science.gov (United States)

Smith, M. L.; Catling, D.; Claire, M.; Zahnle, K.

2014-03-01

The rise of atmospheric oxygen set the tempo for the evolution of complex life on Earth. Oxygen levels are thought to have increased in two broad steps: one step occurred in the Archean ~ 2.45 Ga (the Great Oxidation Event or GOE), and another step occured in the Neoproterozoic ~750-580 Ma (the Neoprotoerozoic Oxygenation Event or NOE). During the NOE, oxygen levels increased from ~1-10% of the present atmospheric level (PAL) (Holland, 2006), to ~15% PAL in the late Neoproterozoic, to ~100% PAL later in the Phanerozoic. Complex life requires O2, so this transition allowed complex life to evolve. We seek to understand what caused the NOE. To explore causes for the NOE, we build upon the biogeochemical model of Claire et al. (2006), which calculates the redox evolution of the atmosphere, ocean, biosphere, and crust in the Archean through to the early Proterozoic. In this model, the balance between oxygenconsuming and oyxgen-producing fluxes evolves over time such that at ~2.4 Ga, the rapidly acting sources of oxygen outweigh the rapidly-acting sinks. Or, in other words, at ~2.4 Ga, the flux of oxygen from organic carbon burial exceeds the sinks of oxygen from reaction with reduced volcanic and metamoprphic gases. The model is able to drive oxygen levels to 1-10% PAL in the Proterozoic; however, the evolving redox fluxes in the model cannot explain how oxygen levels pushed above 1-10% in the late Proterozoic. The authors suggest that perhaps another buffer, such as sulfur, is needed to describe Proterozoic and Phanerozoic redox evolution. Geologic proxies show that in the Proterozoic, up to 10% of the deep ocean may have been sulfidic. With this ocean chemistry, the global sulfur cycle would have worked differently than it does today. Because the sulfur and oxygen cycles interact, the oxygen concentration could have permanently changed due to an evolving sulfur cycle (in combination with evolving redox fluxes associated with other parts of the oxygen cycle and carbon

Electrocatalysis of oxygen reduction on nitrogen-containing multi-walled carbon nanotube modified glassy carbon electrodes

International Nuclear Information System (INIS)

Vikkisk, Merilin; Kruusenberg, Ivar; Joost, Urmas; Shulga, Eugene; Tammeveski, Kaido

2013-01-01

Highlights: ► Pyrolysis in the presence of urea was used for nitrogen doping of carbon nanotubes. ► N-doped carbon nanotubes were used as catalysts for the oxygen reduction reaction. ► N-doped carbon material showed a high catalytic activity for ORR in alkaline media. ► N-containing CNT material is an attractive cathode catalyst for alkaline membrane fuel cells. - Abstract: The electrochemical reduction of oxygen was studied on nitrogen-doped multi-walled carbon nanotube (NCNT) modified glassy carbon (GC) electrodes employing the rotating disk electrode (RDE) method. Nitrogen doping was achieved by simple pyrolysis of the carbon nanotube material in the presence of urea. The surface morphology and composition of the NCNT samples were investigated by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The SEM images revealed a rather uniform distribution of NCNTs on the GC electrode substrate. The XPS analysis showed a successful doping of carbon nanotubes with nitrogen species. The RDE results revealed that in alkaline solution the N-doped nanotube materials showed a remarkable electrocatalytic activity towards oxygen reduction. At low overpotentials the reduction of oxygen followed a two-electron pathway on undoped carbon nanotube modified GC electrodes, whereas on NCNT/GC electrodes a four-electron pathway of O 2 reduction predominated. The results obtained are significant for the development of nitrogen-doped carbon-based cathodes for alkaline membrane fuel cells.

Mineralogy and geochemistry of phosphate minerals and brannerite from the Proterozoic Carbon Leader Reef gold and uranium placer deposit, Witwatersrand, South Africa

International Nuclear Information System (INIS)

Oberthuer, T.

1987-01-01

Yttrium-phosphate, the most common phosphate phase, is closely associated with detrital uraninite. It is assumed having formed by the reaction of mobile phosphate with Y and HREE liberated from the lattice of detrital uraninite, during diagenesis and/or metamorphism of the sediments. Authigenic brannerite (UTi 2-3 O 6-8 ) is well-defined microscopically and geochemically. Textural relationships indicate that both titanium migrated to uraninite, forming brannerite, and mobile uranium caused the 'branneritization' of rutile/leucoxene. Microprobe analyses demonstrate that brannerite from the Carbon Leader Reef displays a distinct and small variation of UO 2 /TiO 2 ratios, which lie close to the theoretical value of 1.117 for UTi 3 O 8 , in contrast to uraniferous leucoxene/brannerite from other Witwatersrand-type deposits, the latter showing a wide scatter of UO 2 /TiO 2 ratios. (orig./HP)

Porous carbon with a large surface area and an ultrahigh carbon purity via templating carbonization coupling with KOH activation as excellent supercapacitor electrode materials

International Nuclear Information System (INIS)

Sun, Fei; Gao, Jihui; Liu, Xin; Pi, Xinxin; Yang, Yuqi; Wu, Shaohua

2016-01-01

Highlights: • Simple templating carbonization method was developed to obtain porous carbons. • Surface etching by KOH activation greatly boosts surface area and carbon purity. • The as-obtained porous carbon delivers a high capacitance of 275 F g −1 . • Symmetric supercapacitor can achieved high energy density and power density. - Abstract: Large surface area and good structural stability, for porous carbons, are two crucial requirements to enable the constructed supercapacitors with high capacitance and long cycling lifespan. Herein, we successfully prepare porous carbon with a large surface area (3175 m 2 g −1 ) and an ultrahigh carbon purity (carbon atom ratio of 98.25%) via templating carbonization coupling with KOH activation. As-synthesized MTC-KOH exhibits excellent performances as supercapacitor electrode materials in terms of high specific capacitance and ultrahigh cycling stability. In a three electrode system, MTC-KOH delivers a high capacitance of 275 F g −1 at 0.5 A g −1 and still 120 F g −1 at a high rate of 30 A g −1 . There is almost no capacitance decay even after 10,000 cycles, demonstrating outstanding cycling stability. In comparison, pre-activated MTC with a hierarchical pore structure shows a better rate capability than microporous MTC-KOH. Moreover, the constructed symmetric supercapacitor using MTC-KOH can achieve high energy densities of 8.68 Wh kg −1 and 4.03 Wh kg −1 with the corresponding power densities of 108 W kg −1 and 6.49 kW kg −1 , respectively. Our work provides a simple design strategy to prepare highly porous carbons with high carbon purity for supercapacitors application.

Combined oxygen- and carbon-isotope records through the Early Jurassic: multiple global events and two modes of carbon-cycle/temperature coupling

DEFF Research Database (Denmark)

Hesselbo, Stephen P.; Korte, Christoph

2010-01-01

, to the extent that meaningful comparisons between these events can begin to be made. Here we present new carbon and oxygen isotope data from mollusks (bivalves and belemnites) and brachiopods collected through the marine Early Jurassic succession of NE England, including the Sinemurian-Plienbachian boundary...... GSSP. All materials have been screened by chemical analysis and scanning electron microscopy to check for diagenetic alteration. Analysis of carbon isotopes from marine calcite is supplemented by analysis of carbon-isotope values from fossil wood collected through the same section. It is demonstrated...... that both long-term and short-term carbon-isotope shifts from the UK Early Jurassic represent global changes in carbon cycle balances. The Sinemurian-Pliensbachian boundary event is an event of global significance and shows several similarities to the Toarcian OAE (relative sea-level change, carbon-isotope...

Analysis of single oil-bearing fluid inclusions in mid-Proterozoic sandstones (Roper Group, Australia)

Science.gov (United States)

Siljeström, Sandra; Volk, Herbert; George, Simon C.; Lausmaa, Jukka; Sjövall, Peter; Dutkiewicz, Adriana; Hode, Tomas

2013-12-01

Hydrocarbons and organic biomarkers extracted from black shales and other carbonaceous sedimentary rocks are valuable sources of information on the biodiversity and environment of early Earth. However, many Precambrian hydrocarbons including biomarkers are suspected of being younger contamination. An alternative approach is to study biomarkers trapped in oil-bearing fluid inclusions by bulk crushing samples and subsequently analysing the extracted hydrocarbons with gas chromatography-mass spectrometry. However, this method does not constrain the hydrocarbons to one particular oil inclusion, which means that if several different generations of oil inclusions are present in the sample, a mix of the content from these oil inclusions will be analysed. In addition, samples with few and/or small inclusions are often below the detection limit. Recently, we showed that it is possible to detect organic biomarkers in single oil-bearing fluid inclusions using time-of-flight secondary ion mass spectrometry (ToF-SIMS). In the present study, single fluid inclusion analysis has been performed on Proterozoic samples for the first time. Four individual oil-bearing fluid inclusions, found in 1430 Ma sandstone from the Roper Superbasin in Northern Australia, were analysed with ToF-SIMS. The ToF-SIMS spectra of the oil in the different inclusions are very similar to each other and are consistent with the presence of n-alkanes/branched alkanes, monocyclic alkanes, bicyclic alkanes, aromatic hydrocarbons, and tetracyclic and pentacyclic hydrocarbons. These results are in agreement with those obtained from bulk crushing of inclusions trapped in the same samples. The capability to analyse the hydrocarbon and biomarker composition of single oil-bearing fluid inclusions is a major breakthrough, as it opens up a way of obtaining molecular compositional data on ancient oils without the ambiguity of the origin of these hydrocarbons. Additionally, this finding suggests that it will be possible

An index-based approach to assessing recalcitrance and soil carbon sequestration potential of engineered black carbons (biochars).

Science.gov (United States)

Harvey, Omar R; Kuo, Li-Jung; Zimmerman, Andrew R; Louchouarn, Patrick; Amonette, James E; Herbert, Bruce E

2012-02-07

The ability of engineered black carbons (or biochars) to resist abiotic and, or biotic degradation (herein referred to as recalcitrance) is crucial to their successful deployment as a soil carbon sequestration strategy. A new recalcitrance index, the R(50), for assessing biochar quality for carbon sequestration is proposed. The R(50) is based on the relative thermal stability of a given biochar to that of graphite and was developed and evaluated with a variety of biochars (n = 59), and soot-like black carbons. Comparison of R(50), with biochar physicochemical properties and biochar-C mineralization revealed the existence of a quantifiable relationship between R(50) and biochar recalcitrance. As presented here, the R(50) is immediately applicable to pre-land application screening of biochars into Class A (R(50) ≥ 0.70), Class B (0.50 ≤ R(50) carbon sequestration classes. Class A and Class C biochars would have carbon sequestration potential comparable to soot/graphite and uncharred plant biomass, respectively, whereas Class B biochars would have intermediate carbon sequestration potential. We believe that the coupling of the R(50), to an index-based degradation, and an economic model could provide a suitable framework in which to comprehensively assess soil carbon sequestration in biochars.

Nano-micro carbon spheres anchored on porous carbon derived from dual-biomass as high rate performance supercapacitor electrodes

Science.gov (United States)

Liu, Shaobo; Zhao, Yang; Zhang, Baihui; Xia, Hui; Zhou, Jianfei; Xie, Wenke; Li, Hongjian

2018-03-01

Hierarchical nano-micro carbon spheres@rice straw-derived porous carbon composites are successfully synthesized by the in situ decoration of the porous carbon with carbon spheres from glucose under the assistance of cetyltrimethyl ammonium bromide micelles and further activated by KOH. The scanning electron microscope images clearly show the carbon spheres disperse homogeneously and orderly onto the surface and in the inner macropores of the porous carbon. The diameter of the carbon spheres varies from 475 nm to 1.6 μm, which can be easily controlled by introducing extra inducing agent. The optimal composites exhibit a large specific surface area (1122 m2 g-1), rich content of oxygen (14.2 wt %), and tunable hierarchical porous structure. When used as supercapacitor electrodes, the novel composites with abundant fruits present a high specific capacitance of 337 F g-1 at 1 A g-1, excellent rate retention of 83% from 1 to 20 A g-1 and a good cycling stability with 96% capacitance retention after 10000 cycles. In this strategy, the thought of shared ion-buffering reservoirs is proposed and the mutual promotion effects between the carbon spheres and porous carbon in the composites are also practically demonstrated to contribute the enhanced electrochemical performances.

Catalytic growth of carbon nanotubes with large inner diameters

Directory of Open Access Journals (Sweden)

WEI REN ZHONG

2005-02-01

Full Text Available Carbon nanotubes (2.4 g/g catalyst, with large inner diameters were successfully synthesized through pyrolysis of methane on a Ni–Cu–Al catalyst by adding sodium carbonate into the carbon nanotubes growth system. The inner diameter of the carbon nanotubes prepared by this method is about 20–60 nm, while their outer diameter is about 40–80 nm. Transmission electron microscopy and X-ray diffraction were employed to investigate the morphology and microstructures of the carbon nanotubes. The analyses showed that these carbon nanotubes have large inner diameters and good graphitization. The addition of sodium carbonate into the reaction system brings about a slight decrease in the methane conversion and the yield of carbon. The experimental results showed that sodium carbonate is a mildly toxic material which influenced the catalytic activity of the Ni–Cu–Al catalyst and resulted in the formation of carbon nanotubes with large inner diameters. The growth mechanism of the carbon nanotubes with large inner diameters is discussed in this paper.

Biocompatibility of Soft-Templated Mesoporous Carbons

Energy Technology Data Exchange (ETDEWEB)

Gencoglu, Maria F. [Michigan Technological Univ., Houghton, MI (United States). Dept. of Chemical Engineering; Spurri, Amanda [Widener Univ., Chester, PA (United States). Dept. of Chemical Engineering; Franko, Mitchell [Widener Univ., Chester, PA (United States). Dept. of Chemical Engineering; Chen, Jihua [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS); Hensley, Dale K. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS); Heldt, Caryn L. [Michigan Technological Univ., Houghton, MI (United States). Dept. of Chemical Engineering; Saha, Dipendu [Widener Univ., Chester, PA (United States). Dept. of Chemical Engineering

2014-08-21

We report that soft-templated mesoporous carbon is morphologically a non-nano type of carbon. It is a relatively newer variety of biomaterial, which has already demonstrated its successful role in drug delivery applications. To investigate the toxicity and biocompatibility, we introduced three types of mesoporous carbons with varying synthesis conditions and pore textural properties. We compared the Brunauer–Emmett–Teller (BET) surface area and pore width and performed cytotoxicity experiments with HeLa cells, cell viability studies with fibroblast cells and hemocomapatibility studies. Cytotoxicity tests reveal that two of the carbons are not cytotoxic, with cell survival over 90%. The mesoporous carbon with the highest surface area showed slight toxicity (~70% cell survival) at the highest carbon concentration of 500 μg/mL. Fibroblast cell viability assays suggested high and constant viability of over 98% after 3 days with no apparent relation with materials property and good visible cell-carbon compatibility. No hemolysis (<1%) was confirmed for all the carbon materials. Protein adsorption experiments with bovine serum albumin (BSA) and fibrinogen revealed a lower protein binding capacity of 0.2–0.6 mg/m² and 2–4 mg/m² for BSA and fibrinogen, respectively, with lower binding associated with an increase in surface area. The results of this study confirm the biocompatibility of soft-templated mesoporous carbons.

Enhanced performance of electrospun carbon fibers modified with carbon nanotubes: promising electrodes for enzymatic biofuel cells.

Science.gov (United States)

Engel, A Both; Cherifi, A; Tingry, S; Cornu, D; Peigney, A; Laurent, Ch

2013-06-21

New nanostructured electrodes, promising for the production of clean and renewable energy in biofuel cells, were developed with success. For this purpose, carbon nanofibers were produced by the electrospinning of polyacrylonitrile solution followed by convenient thermal treatments (stabilization followed by carbonization at 1000, 1200 and 1400° C), and carbon nanotubes were adsorbed on the surfaces of the fibers by a dipping method. The morphology of the developed electrodes was characterized by several techniques (SEM, Raman spectroscopy, electrical conductivity measurement). The electrochemical properties were evaluated through cyclic voltammetry, where the influence of the carbonization temperature of the fibers and the beneficial contribution of the carbon nanotubes were observed through the reversibility and size of the redox peaks of K3Fe(CN)6 versus Ag/AgCl. Subsequently, redox enzymes were immobilized on the electrodes and the electroreduction of oxygen to water was realized as a test of their efficiency as biocathodes. Due to the fibrous and porous structure of these new electrodes, and to the fact that carbon nanotubes may have the ability to promote electron transfer reactions of redox biomolecules, the new electrodes developed were capable of producing higher current densities than an electrode composed only of electrospun carbon fibers.

Subduction of Proterozoic to Late Triassic continental basement in the Guatemala suture zone: A petrological and geochronological study of high-pressure metagranitoids from the Chuacús complex

Science.gov (United States)

Maldonado, Roberto; Ortega-Gutiérrez, Fernando; Ortíz-Joya, Guillermo A.

2018-05-01

Many continental subduction complexes contain abundant granitic rocks coexisting with minor volumes of eclogite-facies rocks. Characterization of granitic protoliths is crucial to decipher the origin of subducted continental crust, whereas knowledge of its metamorphic evolution is required to constrain the mechanisms of burial and exhumation. In this work we present geochronological and petrological evidence that demonstrate the occurrence of a subducted Proterozoic to Late Triassic granitic basement in the Chuacús complex of central Guatemala. Metagranitoids exposed in this area are interlayered with eclogite and other high-pressure rocks, and their structure is considerably variable due to strain partitioning during deformation. Laser ablation-inductively coupled plasma-mass spectrometry U-Pb zircon data from two ferroan metagranites yield protolith crystallization ages of ca. 1.1 Ga and their trace-element abundances suggest an origin related to intraplate magmatism, while a high-silica, peraluminous metagranite is dated at 1.0 Ga and was probably originated by partial melting of a high-grade continental crust. On the other hand, two megacrystic to augen metagranitoids yield protolith crystallization ages of ca. 224 Ma, which are identical within errors to the protolith age of hosted eclogitic metabasites. Their high incompatible trace element abundances together with the observed spatial-temporal relationships with mafic protoliths suggest that Late Triassic bimodal magmatism in the Chuacús complex was probably originated in a within-plate setting. Regardless of their age or structure, the studied metagranites preserve evidences for high-pressure metamorphic equilibration, such as the occurrence of Ca-rich garnet (XCa up to 0.52) in association with phengite (Si contents of up to 3.4 pfu) and rutile. The integration of Zr-in-rutile thermometry and phengite barometry allows the peak metamorphic conditions to be constrained at 640-680 °C and 13 kbar. This

One-pot synthesis and electrochemical reactivity of carbon coated LiFePO4 spindles

International Nuclear Information System (INIS)

Yu Juanjuan; Hu Juncheng; Li Jinlin

2012-01-01

Highlights: ► Carbon coated LiFePO 4 spindles have been successfully synthesized via a novel supercritical method. ► The concentrations of lithium have an effect on the morphology of carbon coated LiFePO 4 . ► Amorphous carbon layer formed on the surface of LiFePO 4 by adding glucose. ► The carbon coating is responsible for the enhanced electrochemical performance. - Abstract: Spindle-like carbon coated LiFePO 4 (LiFePO 4 /C) composites have been successfully synthesized via a novel one-pot supercritical methanol method. The products were characterized by X-ray power diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA). The particle size, morphology and electrochemical reactivity changed with the concentration of lithium and carbon source. A possible morphology evolution process was also proposed. The glucose not only facilitates the formation of single crystalline LiFePO 4 , but also gives an amorphous carbon layer on the surface LiFePO 4 spindles.

Electrochemical determination of bisphenol A at ordered mesoporous carbon modified nano-carbon ionic liquid paste electrode.

Science.gov (United States)

Li, Yonghong; Zhai, Xiurong; Liu, Xinsheng; Wang, Ling; Liu, Herong; Wang, Haibo

2016-02-01

A simple bisphenol A (BPA) sensor was successfully fabricated based on ordered mesoporous carbon CMK-3 modified nano-carbon ionic liquid paste electrode (CMK-3/nano-CILPE). The nanostructure of CMK-3 and the surface morphologies of modified electrodes were characterized by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Electrochemical properties of the fabricated electrodes were investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The fabricated sensor displayed excellent electroactivity towards bisphenol A using linear sweep voltammetry (LSV). Experimental conditions influencing the analytical performance of the modified electrode were optimized. Under optimal conditions, the oxidation peak current was proportional to BPA concentration in the range from 0.2 μM to 150 μM with a detection limit of 0.05 μM (S/N=3). This method was successfully used for determination of BPA leached from drinking bottle and plastic bag with good recoveries. Copyright © 2015 Elsevier B.V. All rights reserved.

Anodic stripping voltammetric determination of silver ion at a carbon paste electrode modified with carbon nanotubes

International Nuclear Information System (INIS)

Tashkhourian, J.; Javadi, S.; Ana, F.N.

2011-01-01

A carbon paste electrode (CPE) was modified with multi-wall carbon nanotubes and successfully applied to the determination of silver ion by differential pulse anodic stripping voltammetry. Compared to a conventional CPE, a remarkably improved peak current response and sensitivity is observed. The analytical procedure consisted of an open circuit accumulation step for 2 min in -0.4 V, this followed by an anodic potential scan between +0.2 and + 0.6 V to obtain the voltammetric peak. The oxidation peak current is proportional to the concentration of silver ion in the range from 1.0 x 10 -8 to 1.0 x 10 -5 mol L -1 , with a detection limit of 1.8 x 10 -9 mol L -1 after an accumulation time of 120 s. The relative standard deviation for 7 successive determinations of Ag(I) at 0.1 μM concentration is 1.99%. The procedure was validated by determining Ag(I) in natural waters. (author)

Effects of seabird nitrogen input on biomass and carbon accumulation after 50 years of primary succession on a young volcanic island, Surtsey

Science.gov (United States)

Leblans, N. I. W.; Sigurdsson, B. D.; Roefs, P.; Thuys, R.; Magnússon, B.; Janssens, I. A.

2014-11-01

What happens during primary succession after the first colonizers have occupied a pristine surface largely depends on how they ameliorate living conditions for other species. For vascular plants the onset of soil development and associated increase in nutrient (mainly nitrogen; N) and water availability is especially important. Here, we report the relationship between N accumulation and biomass and ecosystem carbon (C) stocks in a 50-year-old volcanic island, Surtsey, Iceland, where N stocks are still exceptionally low. However, a 28-year-old seagull colony on the island provided nutrient-enriched areas, which enabled us to assess the relationship between N stock and biomass and ecosystem C stocks across a much larger range in N stock. Further, we compared areas on shallow and deep tephra sands as we expected that deep-rooted systems would be more efficient in retaining N. The sparsely vegetated area outside the colony had accumulated 0.7 kg N ha-1 yr-1, which was ca. 50-60% of the estimated N input rate from wet deposition. This approximates values for systems under low N input and bare dune habitats. The seagulls have added, on average, 47 kg N ha-1 yr-1, which induced a shift from belowground to aboveground in ecosystem N and C stocks and doubled the ecosystem N-use efficiency, determined as the ratio of biomass and C storage per unit N input. Soil depth did not significantly affect total N stocks, which suggests a high N retention potential. Both total ecosystem biomass and C stocks were strongly correlated with N stock inside the colony, which indicated the important role of N during the first steps of primary succession. Inside the colony, the ecosystem biomass C stocks (17-27 ton C ha-1) had reached normal values for grasslands, while the soil organic carbon (SOC) stocks (4-10 ton C ha-1 were only a fraction of normal grassland values. Thus, it will take a long time until the SOC stock reaches equilibrium with the current primary production, during which

Synthesis and characterization of carbon nanotube from coconut shells activated carbon

Science.gov (United States)

Melati, A.; Hidayati, E.

2016-03-01

Carbon nanotubes (CNTs) have been explored in almost every single cancer treatment modality, including drug delivery, lymphatic targeted chemotherapy, photodynamic therapy, and gene therapy. They are considered as one of the most promising nanomaterial with the capability of both detecting the cancerous cells and delivering drugs or small therapeutic molecules to the cells. CNTs have unique physical and chemical properties such as high aspect ratio, ultralight weight, high mechanical strength, high electrical conductivity, and high thermal conductivity. Coconut Shell was researched as active carbon source on 500 - 600°C. These activated carbon was synthesized becomes carbon nanotube and have been proposed as a promising tool for detecting the expression of indicative biological molecules at early stage of cancer. Clinically, biomarkers cancer can be detected by CNT Biosensor. We are using pyrolysis methods combined with CVD process or Wet Chemical Process on 600°C. Our team has successfully obtained high purity, and aligned MWCNT (Multi Wall Nanotube) bundles on synthesis CNT based on coconut shells raw materials. CNTs can be used to cross the mammalian cell membrane by endocytosis or other mechanisms. SEM characterization of these materials have 179 nm bundles on phase 83° and their materials compound known by using FTIR characterization.

Defect- and dopant-controlled carbon nanotubes fabricated by self-assembly of graphene nanoribbons

Institute of Scientific and Technical Information of China (English)

Cun Zhang and Shaohua Chen

2015-01-01

Molecular dynamics simulations showed that a basal carbon nanotube can activate and guide the fabrication of single-walled carbon nanotubes （CNTs） on its internal surface by self-assembly of edge-unpassivated graphene nanoribbons with defects. Furthermore, the distribution of defects on self-assembled CNTs is controllable. The system temperature and defect fraction are two main factors that influence the success of self-assembly. Due to possible joint flaws formed at the boundaries under a relatively high constant temperature, a technique based on increasing the temperature is adopted. Self-assembly is always successful for graphene nanoribbons with relatively small defect fractions, while it will fail in cases with relatively large ones. Similar to the self-assembly of graphene nanoribbons with defects, graphene nanoribbons with different types of dopants can also be self-assembled into carbon nanotubes. The finding provides a possible fabrication technique not only for carbon nanotubes with metallic or semi-con- ductive properties but also for carbon nanotubes with electromagnetic induction characteristics.

[In vivo evaluation of carbon fiber posts].

Science.gov (United States)

Lai, V; Lugliè, P F; Chessa, G

2002-05-01

The use of carbon fiber posts allows morpho-functional restoration of endodontically treated teeth with an assembly of materials of a modulus of elasticity similar to that of dentin. The study clinically evaluated the percentage of survival of dental elements treated and reconstructed with endocanal carbon fiber posts. At the Dentistry Clinic of the University of Sassari 60 dental elements were selected from 46 subjects. The teeth, which had been treated endodontically with success for at least six months, were classified by parameters taken from the international literature and reconstructed using Tech 2000 carbon fiber posts and adhesive resinous systems recommended by the post manufacturer. The success rate was 98.4%. Almost half (49%) of the samples were single-rooted elements, 37.4% of the posts were 1.2 mm in diameter; in 78.3% the opposing contact was with a natural tooth; 100% of the elements had a type A dental structure. Third generation posts are a valid alternative to metallic posts and improve the prognosis of the treated element. The carbon fiber posts fixed with the composite, forming a single unit with the dental element, thus improving mid-term RESULTS. The technique is easy to use under clinical conditions and can be performed in a single session. So far, the method has provided promising clinical results, as this study demonstrated.

Modified glassy carbon electrodes based on carbon nanostructures for ultrasensitive electrochemical determination of furazolidone.

Science.gov (United States)

Shahrokhian, Saeed; Naderi, Leila; Ghalkhani, Masoumeh

2016-04-01

The electrochemical behavior of Furazolidone (Fu) was investigated on the surface of the glassy carbon electrode modified with different carbon nanomaterials, including carbon nanotubes (CNTs), carbon nanoparticles (CNPs), nanodiamond-graphite (NDG), graphene oxide (GO), reduced graphene oxide (RGO) and RGO-CNT hybrids (various ratios) using linear sweep voltammetry (LSV). The results of voltammetric studies exhibited a considerable increase in the cathodic peak current of Fu at the RGO modified GCE, compared to other modified electrodes and also bare GCE. The surface morphology and nature of the RGO film was thoroughly characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) techniques. The modified electrode showed two linear dynamic ranges of 0.001-2.0 μM and 2.0-10.0 μM with a detection limit of 0.3 nM for the voltammetric determination of Fu. This sensor was used successfully for Fu determination in pharmaceutical and clinical preparations. Copyright © 2016 Elsevier B.V. All rights reserved.

Early outcomes of pyrolytic carbon hemiarthroplasty for the treatment of trapezial-metacarpal arthritis

NARCIS (Netherlands)

Martinez de Aragon, J. S.; Moran, Steven L.; Rizzo, Marco; Reggin, Kirsten B.; Beckenbaugh, Robert D.

2009-01-01

PURPOSE: Pyrolytic carbon implants have been successfully used in the treatment of osteoarthritis of the metacarpophalangeal and proximal interphalangeal joints. Recently, pyrolytic carbon hemiarthroplasties have been proposed for the treatment of osteoarthritis of the trapezial-metacarpal (TM)

Influence of surface chemistry on inkjet printed carbon nanotube films

International Nuclear Information System (INIS)

Hopkins, Alan R.; Straw, David C.; Spurrell, Kathryn C.

2011-01-01

Carbon nanotube ink chemistry and the proper formulation are crucial for direct-write printing of nanotubes. Moreover, the correct surface chemistry of the self-assembled monolayers that assist the direct deposition of carbon nanotubes onto the substrate is equally important to preserve orientation of the printed carbon nanotubes. We report that the successful formulation of two single walled carbon nanotube (SWNT) inks yields a consistent, homogenous printing pattern possessing the requisite viscosities needed for flow through the microcapillary nozzles of the inkjet printer with fairly modest drying times. The addition of an aqueous sodium silicate allows for a reliable method for forming a uniform carbon nanotube network deposited directly onto unfunctionalized surfaces such as glass or quartz via inkjet deposition. Furthermore, this sodium silicate ingredient helps preserve applied orientation to the printed SWNT solution. Sheet resistivity of this carbon nanotube ink formula printed on quartz decreases as a function of passes and is independent of the substrate. SWNTs were successfully patterned on Au. This amine-based surface chemistry dramatically helps improve the isolation stabilization of the printed SWNTs as seen in the atomic force microscopy (AFM) image. Lastly, using our optimized SWNT ink formula and waveform parameters in the Fuji materials printer, we are able to directly write/print SWNTs into 2D patterns. Dried ink pattern expose and help orient roped carbon nanotubes that are suspended in ordered arrays across the cracks.

Porous carbon with a large surface area and an ultrahigh carbon purity via templating carbonization coupling with KOH activation as excellent supercapacitor electrode materials

Energy Technology Data Exchange (ETDEWEB)

Sun, Fei; Gao, Jihui, E-mail: gaojh@hit.edu.cn; Liu, Xin; Pi, Xinxin; Yang, Yuqi; Wu, Shaohua

2016-11-30

Highlights: • Simple templating carbonization method was developed to obtain porous carbons. • Surface etching by KOH activation greatly boosts surface area and carbon purity. • The as-obtained porous carbon delivers a high capacitance of 275 F g{sup −1}. • Symmetric supercapacitor can achieved high energy density and power density. - Abstract: Large surface area and good structural stability, for porous carbons, are two crucial requirements to enable the constructed supercapacitors with high capacitance and long cycling lifespan. Herein, we successfully prepare porous carbon with a large surface area (3175 m{sup 2} g{sup −1}) and an ultrahigh carbon purity (carbon atom ratio of 98.25%) via templating carbonization coupling with KOH activation. As-synthesized MTC-KOH exhibits excellent performances as supercapacitor electrode materials in terms of high specific capacitance and ultrahigh cycling stability. In a three electrode system, MTC-KOH delivers a high capacitance of 275 F g{sup −1} at 0.5 A g{sup −1} and still 120 F g{sup −1} at a high rate of 30 A g{sup −1}. There is almost no capacitance decay even after 10,000 cycles, demonstrating outstanding cycling stability. In comparison, pre-activated MTC with a hierarchical pore structure shows a better rate capability than microporous MTC-KOH. Moreover, the constructed symmetric supercapacitor using MTC-KOH can achieve high energy densities of 8.68 Wh kg{sup −1} and 4.03 Wh kg{sup −1} with the corresponding power densities of 108 W kg{sup −1} and 6.49 kW kg{sup −1}, respectively. Our work provides a simple design strategy to prepare highly porous carbons with high carbon purity for supercapacitors application.

Paleoenvironmental Evolution of Continental Carbonates in West-Central Brazil

Directory of Open Access Journals (Sweden)

EMILIANO C. OLIVEIRA

Full Text Available ABSTRACT This paper presents a sedimentological and stratigraphical study of Quaternary (Middle to Late Pleistocene/Holocene continental carbonates outcrops inside Pantanal Basin and its surroundings, especially in Serra da Bodoquena, Pantanal do Miranda and Corumbá/Ladário plateau, in the state of Mato Grosso do Sul, as well as in Serra das Araras, in the state of Mato Grosso. The aim is to understand the depositional paleoenvironments and analyse climate and tectonic influences in their genesis and evolution. The results show that the deposition of these continental carbonates started in the Middle to Late Pleistocene and have continued, with some interruptions, until the present days. Sedimentary successions were identified in the different areas, without complete correlation. Two sedimentary successions separated by an erosional surface were described in Serra da Bodoquena and Serra das Araras. In Corumbá and Pantanal do Miranda, only one succession was described. These successions were deposited in elongated lakes parallel to fault planes; small lakes, related plains and plateaus; springs related to cliffs produced by faulting; rivers conditioned by topographic variation. The climatic interpretation, without proper temporal resolution, obtained by the stable-isotope composition and stratigraphic interpretation, indicates alternation of dry and wet periods. The Neoproterozoic faults with their neotectonics and the subsidence of the Pantanal Basin, are the major control for carbonated water flow and development of depositional areas, gradually turning plateaus into slight tilted areas, allowing the evolution of depositional systems from lakes to rivers.

Organic tissues, graphite, and hydrocarbons in host rocks of the Rum Jungle Uranium Field, northern Australia

Science.gov (United States)

Foster, C.B.; Robbins, E.I.; Bone, Y.

1990-01-01

The Rum Jungle Uranium field consists of at least six early Proterozoic deposits that have been mined either for uranium and/or the associated base and precious metals. Organic matter in the host rocks of the Whites Formation and Coomalie Dolomite is now predominantly graphite, consistent with the metamorphic history of these rocks. For nine samples, the mean total organic carbon content is high (3.9 wt%) and ranged from 0.33 to 10.44 wt%. Palynological extracts from the host rocks include black, filamentous, stellate (Eoastrion-like), and spherical morphotypes, which are typical of early Proterozoic microbiota. The colour, abundance, and shapes of these morphotypes reflect the thermal history, organic richness, and probable lacustrine biofacies of the host rocks. Routine analysis of rock thin sections and of palynological residues shows that mineral grains in some of the host rocks are coated with graphitized organic matter. The grain coating is presumed to result from ultimate thermal degradation of a petroleum phase that existed prior to metamorphism. Hydrocarbons are, however, still present in fluid inclusions within carbonates of the Coomalie Dolomite and lower Whites Formation. The fluid inclusions fluoresce dull orange in blue-light excitation and their hydrocarbon content is confirmed by gas chromatography of whole-rock extracts. Preliminary analysis of the oil suggests that it is migrated, and because it has escaped graphitization through metamorphism it is probably not of early Proterozoic age. The presence of live oil is consistent with fluid inclusion data that suggest subsequent, low-temperature brine migration through the rocks. The present observations support earlier suggestions that organic matter in the host formations trapped uranium to form protore. Subsequent fluid migrations probably brought additional uranium and other metals to these formations, and the organic matter provided a reducing environment for entrapment. ?? 1990.

Stratigraphy of the cambo-ordovician succession in Illnois

Energy Technology Data Exchange (ETDEWEB)

Lasemi, Yaghoob; Khorasgani, Zohreh; Leetaru, Hannes

2014-09-30

The Upper Cambrian through Lower Ordovician succession (Sauk II-III sequences) in the Illinois Basin covers the entire state of Illinois and most of the states of Indiana and Kentucky. To determine lateral and vertical lithologic variations of the rocks within the Cambro-Ordovician deposits that could serve as reservoir or seal for CO2 storage, detailed subsurface stratigraphic evaluation of the succession in Illinois was conducted. The Cambro-Ordovician succession in the Illinois Basin consists of mixed carbonate-siliciclastic deposits. Its thickness ranges from nearly 800 feet in the extreme northwest to nearly 8000 feet in the Reelfoot Rift in the extreme southeastern part of the state. In northern and central Illinois, the Cambro-Ordovician rocks are classified as the Cambrian Knox and the Ordovician Prairie du Chien Groups, which consist of alternating dolomite and siliciclastic units. In the southern and deeper part of the Illinois Basin, the Cambro-Ordovician deposits consist chiefly of fine to coarsely crystalline dolomite capped by the Middle Ordovician Everton Formation. Detailed facies analysis indicates that the carbonate units consist mainly of mudstone to grainstone facies (fossiliferous/oolitic limestone and dolomite) with relics of bioclasts, ooids, intraclasts and peloids recording deposition on a shallow marine ramp setting. The dominant lithology of the Knox and the overlying Prairie du Chien Group is fine to coarsely crystalline, dense dolomite. However, porous and permeable vugular or fractured/cavernous dolomite intervals that grade to dense fine to coarsely crystalline dolomite are present within the dolomite units. Several hundred barrels of fluid were lost in some of these porous intervals during drilling, indicating high permeability. The sandstone intervals are porous and permeable and are texturally and compositionally mature. The permeable sandstone and porous dolomite intervals are laterally extensive and could serve as important

The GLOBE Carbon Cycle Project: Using a systems approach to understand carbon and the Earth's climate system

Science.gov (United States)

Silverberg, S. K.; Ollinger, S. V.; Martin, M. E.; Gengarelly, L. M.; Schloss, A. L.; Bourgeault, J. L.; Randolph, G.; Albrechtova, J.

2009-12-01

National Science Content Standards identify systems as an important unifying concept across the K-12 curriculum. While this standard exists, there is a recognized gap in the ability of students to use a systems thinking approach in their learning. In a similar vein, both popular media as well as some educational curricula move quickly through climate topics to carbon footprint analyses without ever addressing the nature of carbon or the carbon cycle. If students do not gain a concrete understanding of carbon’s role in climate and energy they will not be able to successfully tackle global problems and develop innovative solutions. By participating in the GLOBE Carbon Cycle project, students learn to use a systems thinking approach, while at the same time, gaining a foundation in the carbon cycle and it's relation to climate and energy. Here we present the GLOBE Carbon Cycle project and materials, which incorporate a diverse set of activities geared toward upper middle and high school students with a variety of learning styles. A global carbon cycle adventure story and game let students see the carbon cycle as a complete system, while introducing them to systems thinking concepts including reservoirs, fluxes and equilibrium. Classroom photosynthesis experiments and field measurements of schoolyard vegetation brings the global view to the local level. And the use of computer models at varying levels of complexity (effects on photosynthesis, biomass and carbon storage in global biomes, global carbon cycle) not only reinforces systems concepts and carbon content, but also introduces students to an important scientific tool necessary for understanding climate change.

Surface morphology and grain analysis of successively industrially grown amorphous hydrogenated carbon films (a-C:H) on silicon

Science.gov (United States)

Catena, Alberto; McJunkin, Thomas; Agnello, Simonpietro; Gelardi, Franco M.; Wehner, Stefan; Fischer, Christian B.

2015-08-01

Silicon (1 0 0) has been gradually covered by amorphous hydrogenated carbon (a-C:H) films via an industrial process. Two types of these diamond-like carbon (DLC) coatings, one more flexible (f-DLC) and one more robust (r-DLC), have been investigated. Both types have been grown by a radio frequency plasma-enhanced chemical vapor deposition (RF-PECVD) technique with acetylene plasma. Surface morphologies have been studied in detail by atomic force microscopy (AFM) and Raman spectroscopy has been used to investigate the DLC structure. Both types appeared to have very similar morphology and sp2 carbon arrangement. The average height and area for single grains have been analyzed for all depositions. A random distribution of grain heights was found for both types. The individual grain structures between the f- and r-type revealed differences: the shape for the f-DLC grains is steeper than for the r-DLC grains. By correlating the average grain heights to the average grain areas for all depositions a limited region is identified, suggesting a certain regularity during the DLC deposition mechanisms that confines both values. A growth of the sp2 carbon entities for high r-DLC depositions is revealed and connected to a structural rearrangement of carbon atom hybridizations and hydrogen content in the DLC structure.

Nano-engineered composites: interlayer carbon nanotubes effect

Energy Technology Data Exchange (ETDEWEB)

Carley, Glaucio, E-mail: carleyone@hotmail.com [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil); Geraldo, Viviany; Oliveira, Sergio de [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Fisica; Avila, Antonio Ferreira [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Fisica

2013-11-01

The concept of carbon nanotube interlayer was successfully introduced to carbon fiber/epoxy composites. This new hybrid laminated composites was characterized by Raman spectroscopy, X-ray diffraction, scanning electron microscopy and tensile tests. An increase on peak stress close to 85% was witnessed when CNTs interlayer with 206.30 mg was placed to carbon fiber/epoxy laminates. The failure mechanisms are associated to CNTs distribution between and around carbon fibers. These CNTs are also responsible for crack bridging formation and the increase on peak stress. Initial stiffness is strongly affected by the CNT interlayer, however, changes on stiffness is associated to changes on nano/micro-structure due to damage. Three different behaviors can be described, i.e. for interlayers with Almost-Equal-To 60 mg of CNT the failure mode is based on cracks between and around carbon fibers, while for interlayers with CNT contents between 136 mg and 185 mg cracks were spotted on fibers and inside the CNT/matrix mix. Finally, the third failure mechanism is based on carbon fiber breakage, as a strong interface between CNT/matrix mix and carbon fibers is observed. (author)

Nano-engineered composites: interlayer carbon nanotubes effect

International Nuclear Information System (INIS)

Carley, Glaucio; Geraldo, Viviany; Oliveira, Sergio de; Avila, Antonio Ferreira

2013-01-01

The concept of carbon nanotube interlayer was successfully introduced to carbon fiber/epoxy composites. This new hybrid laminated composites was characterized by Raman spectroscopy, X-ray diffraction, scanning electron microscopy and tensile tests. An increase on peak stress close to 85% was witnessed when CNTs interlayer with 206.30 mg was placed to carbon fiber/epoxy laminates. The failure mechanisms are associated to CNTs distribution between and around carbon fibers. These CNTs are also responsible for crack bridging formation and the increase on peak stress. Initial stiffness is strongly affected by the CNT interlayer, however, changes on stiffness is associated to changes on nano/micro-structure due to damage. Three different behaviors can be described, i.e. for interlayers with ≈ 60 mg of CNT the failure mode is based on cracks between and around carbon fibers, while for interlayers with CNT contents between 136 mg and 185 mg cracks were spotted on fibers and inside the CNT/matrix mix. Finally, the third failure mechanism is based on carbon fiber breakage, as a strong interface between CNT/matrix mix and carbon fibers is observed. (author)

Modified glassy carbon electrodes based on carbon nanostructures for ultrasensitive electrochemical determination of furazolidone

Energy Technology Data Exchange (ETDEWEB)

Shahrokhian, Saeed, E-mail: shahrokhian@sharif.edu [Department of Chemistry, Sharif University of Technology, Tehran 11155-9516 (Iran, Islamic Republic of); Institute for Nanoscience and Nanotechnology, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Naderi, Leila [Department of Chemistry, Sharif University of Technology, Tehran 11155-9516 (Iran, Islamic Republic of); Ghalkhani, Masoumeh [Department of Chemistry, Faculty of Science, Shahid Rajaee Teacher Training University, Lavizan, Tehran (Iran, Islamic Republic of); Institute for advanced technology, Shahid Rajaee Teacher Training University, Lavizan, Tehran, 16788 (Iran, Islamic Republic of)

2016-04-01

The electrochemical behavior of Furazolidone (Fu) was investigated on the surface of the glassy carbon electrode modified with different carbon nanomaterials, including carbon nanotubes (CNTs), carbon nanoparticles (CNPs), nanodiamond-graphite (NDG), graphene oxide (GO), reduced graphene oxide (RGO) and RGO-CNT hybrids (various ratios) using linear sweep voltammetry (LSV). The results of voltammetric studies exhibited a considerable increase in the cathodic peak current of Fu at the RGO modified GCE, compared to other modified electrodes and also bare GCE. The surface morphology and nature of the RGO film was thoroughly characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) techniques. The modified electrode showed two linear dynamic ranges of 0.001–2.0 μM and 2.0–10.0 μM with a detection limit of 0.3 nM for the voltammetric determination of Fu. This sensor was used successfully for Fu determination in pharmaceutical and clinical preparations. - Highlights: • The electrochemical behavior of Furazolidone (Fu) was investigated on the surface of the modified electrode with different carbon nanomaterials by Linear sweep voltammetry. • Two linear dynamic ranges and a low detection limit were obtained. • The modified electrode was applied for the detection of Fu in pharmaceutical and clinical preparations.

Mesoporous carbon prepared from carbohydrate as hard template for hierarchical zeolites

DEFF Research Database (Denmark)

Egeblad, Kresten; Christensen, Claus H.

2007-01-01

treatment of a mixture of sucrose and ammonia followed by carbonization of the mixture in N-2 at high temperatures. The porous carbon produced by this method was subsequently applied as a hard template in the synthesis of mesoporous silicalite-1 and removed by combustion after synthesis. X-ray diffraction......A mesoporous carbon prepared from sucrose was successfully employed as a hard template to produce hierarchical silicalite-1, thus providing a very simple and inexpensive route to desirable zeolite catalysts from widely available raw materials. The porous carbon was prepared by hydrothermal...... the porous carbon template as well as the mesoporous zeolite single-crystal material....

Production of thin carbon stripper foils using heated-substrates in a cathodic arc deposition system

International Nuclear Information System (INIS)

Merchant, A.R.; Lobanov, N.; Elliman, R.G.; Ophel, T.R.; Rode, A.; Weisser, D.C.; Turkentine, R.B.

1998-01-01

The lifetime of carbon stripper foil can have a marked impact on the successful running of a beam line. Standard techniques for production of carbon stripper foils include evaporation of carbon (ec) and laser-pulsed ablation (Ipa). Recent work by a using Ipa has been successful in substantially increasing the lifetime of a very thin foil. The suspected mechanism for the increased lifetime of the foil is that the amorphous carbon foil is density-matched to that of graphite (around 2.26g/cc). In this work, we attempt to reproduce this result by producing carbon stripper foils with a mass-density similar to graphite using a cathodic arc deposition system. The cathodic arc is well known for the production of tetrahedral amorphous carbon: a high density, high stress form of carbon with over 90% sp 3 -like bonds; to reduce the density of the carbon and promote more graphitic structure, a high bias was initially attempted but this proved unsuccessful. Another method is to use a heated-substrate holder to reduce compressive stress within the deposited film. The performance of the density-matched carbon stripper foils and the implications for future production of high-quality carbon stripper foils in our laboratory will be discussed. (authors)

Hydrogen storage property of nanoporous carbon aerogels

International Nuclear Information System (INIS)

Shen Jun; Liu Nianping; Ouyang Ling; Zhou Bin; Wu Guangming; Ni Xingyuan; Zhang Zhihua

2011-01-01

Carbon aerogels were prepared from resorcinol and formaldehyde via sol-gel process, high temperature carbonization and atmospheric pressure drying technology with solvent replacement. By changing the resorcinol-sodium carbonate molar ratio and the mass fraction of the reactants,resorcinol and formaldehyde, the pore structure of carbon aerogels can be controlled and the palladium-doped carbon aerogels were prepared.By transmission electron microscopy (TEM), X-ray diffraction (XRD) spectra, it is confirmed that the Pd exists in the skeleton structure of carbon aerogels as a form of nano simple substance pellet. The specific surface area is successfully raised by 2 times, and palladium-doped carbon aerogels with a specific surface area of 1 273 m 2 /g have been obtained by carrying out the activation process as the post-processing to the doped carbon aerogels. The hydrogen adsorption results show that the saturated hydrogen storage mass fraction of the carbon aerogels with the specific surface area of 3 212 m 2 /g is 3% in the condition of 92 K, 3.5 MPa, and 0.84% in the condition of 303 K, 3.2 MPa. In addition, the hydrogen adsorption test of palladium-doped carbon aerogels at room temperature (303 K) shows that the total hydrogen storage capacity of doped carbon aerogels is declined due to the relative small specific surface, but the hydrogen storage of unit specific surface area is enhanced. (authors)

Characterization of a surface modified carbon cryogel and a carbon supported Pt catalyst

Directory of Open Access Journals (Sweden)

BILJANA M. BABIĆ

2007-08-01

Full Text Available A carbon cryogel, synthesized by carbonization of a resorcinol/formaldehyde cryogel and oxidized in nitric acid, was used as catalyst support for Pt nano-particles. The Pt/C catalyst was prepared by a modified polyol synthesis method in an ethylene glycol (EG solution. Characterization by nitrogen adsorption showed that the carbon cryogel support and the Pt/C catalyst were mesoporous materials with high specific surface areas (SBET > 400 m2 g-1 and large mesoporous volumes. X-Ray diffraction of the catalyst demonstrated the successful reduction of the Pt precursor to metallic form. TEM Images of the Pt/C catalyst and Pt particle size distribution showed that the mean Pt particle size was about 3.3 nm. Cyclic voltammetry (CV experiments at various scan rates (from 2 to 200 mV s-1 were performed in 0.5 mol dm-3 HClO4 solution. The large capacitance of the oxidized carbon cryogel electrode, which arises from a combination of the double-layer capacitance and pseudocapacitance, associated with the participation of surface redox-type reactions was demonstrated. For the oxidized carbon cryogel, the total specific capacitance determined by 1/C vs. ν0.5 extrapolation method was found to be 386 F g-1. The hydrogen oxidation reaction at the investigated Pt/C catalyst proceeded as an electrochemically reversible, two-electron direct discharge reaction.

Supercapacitors based on ordered mesoporous carbon derived from furfuryl alcohol: effect of the carbonized temperature.

Science.gov (United States)

Li, Na; Xu, Jianxiong; Chen, Han; Wang, Xianyou

2014-07-01

Supercapacitors are successfully prepared from ordered mesoporous carbon (OMC) synthesized by employing the mesoporous silica, SBA-15 as template and furfuryl alcohol as carbon source. It is found that the carbonized temperature greatly influences the physical properties of the synthesized mesoporous carbon materials. The optimal carbonized temperature is measured to be 600 degrees C under which OMC with the specific surface area of 1219 m2/g and pore volume of 1.31 cm3/g and average pore diameter of - 3 nm are synthesized. The OMC materials synthesized under different carbonized temperature are used as electrode material of supercapacitors and the electrochemical properties of the OMC materials are compared by using cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge-discharge and self-discharge tests. The results show that the electrochemical properties of the OMC materials are directly related to the specific surface area and pore volume of the mesoporous carbon and the electrode prepared from the OMC synthesized under the carbonized temperature of 600 degrees C (OMC-600) exhibits the most excellent electrochemical performance with the specific capacitance of 207.08 F/g obtained from cyclic voltammetry at the scan rate of 1 mV/s, small resistance and low self-discharge rate. Moreover, the supercapacitor based on the OMC-600 material exhibits good capacitance properties and stable cycle behavior with the specific capacitance of 105 F/g at the current density of 700 mA/g, and keeps a specific capacitance of 98 F/g after 20000 consecutive charge/discharge cycles.

Synthesis and luminescence of nanodiamonds from carbon black

International Nuclear Information System (INIS)

Hu Shengliang; Tian Fei; Bai Peikang; Cao Shirui; Sun Jing; Yang Jing

2009-01-01

Dispersed nanodiamonds just several nanometers in diameter have been successfully synthesized using carbon black as the carbon source by a long-pulse-width laser irradiation in water at room temperature and normal pressure. The produced nanodiamonds can emit strong visible light after simple surface passivation. The light emission is attributed to the surface states related to linkage groups formed on nanodiamond surface. The surface-passivated nanodiamonds with stable photoluminescence have high potential application in bioimaging and medicine

Resedimented Limestones in Middle and Upper Jurassic Succession of the Slovenian Basin

Directory of Open Access Journals (Sweden)

Boštjan Rožič

2006-12-01

Full Text Available The Middle and Upper Jurassic succession of the Slovenian Basin is characterized by pelagic sedimentation of siliceous limestones and radiolarian cherts. In the southern and central part of the basin two packages of resedimented limestones are interbedded within pelagic sediments. The Lower resedimented limestones are lower-middle Bajocian to lower Callovian in age. In the southern part of the basin they form laterally discontinuous sequences composed of limestone breccias, calcarenites and micritic limestone and in the central part of the basin calcarenite intercalations within pelagic beds. They were transported by turbidity currents from highly productive ooidal shoals of the Dinaric Carbonate Platform. The Lower resedimented carbonates correlate with the lower three members of the Travnik Formation in the Bovec Trough and similarly developed but much thicker Vajont Formation in the Belluno Basin. The difference in thickness is interpreted as a consequence of shallow-water and longshore currents on the Dinaric Carbonate Platform that transported platform material towards southwest in the direction of the Belluno Basin. The Upper resedimented limestones are upper Kimmeridgian to lower Tithonian and occur within radiolarian cherts in the upper part of the succession as calcarenite beds that originated by turbidity currents. Onset of resedimentation coincides with the emersion-related demise of barrier reef and following deposition of micritic and rare oolitic limestones on the Dinaric Carbonate Platform. Approximatelly coeval resedimented limestones occur in the fourth member of the Travnik Formation in the Bovec Trough, but are not reported from the Ammonitico Rosso Superiore Formation in the Belluno Basin.

Strong linkage between active microbial communities and microbial carbon usage in a deglaciated terrain of the High Arctic

Science.gov (United States)

Kim, M.; Gyeong, H. R.; Lee, Y. K.

2017-12-01

Soil microorganisms play pivotal roles in ecosystem development and carbon cycling in newly exposed glacier forelands. However, little is known about carbon utilization pattern by metabolically active microbes over the course of ecosystem succession in these nutrient-poor environments. We investigated RNA-based microbial community dynamics and its relation to microbial carbon usage along the chronosequence of a High Arctic glacier foreland. Among microbial taxa surveyed (bacteria, archaea and fungi), bacteria are among the most metabolically active taxa with a dominance of Cyanobacteria and Actinobacteria. There was a strong association between microbial carbon usage and active Actinobacterial communities, suggesting that member of Actinobacteria are actively involved in organic carbon degradation in glacier forelands. Both bacterial community and microbial carbon usage are converged towards later stage of succession, indicating that the composition of soil organic carbon plays important roles in structuring bacterial decomposer communities during ecosystem development.

Effects of carbon wall on the behavior of Heliotron-E plasmas

Energy Technology Data Exchange (ETDEWEB)

Noda, N; Mizuuchi, T; Akaishi, K; Senju, T; Kondo, K; Kaneko, H; Motojima, O; Baba, T; Besshou, S; Sato, M

1989-04-01

Carbonization was successfully applied to Heliotron-E. Iron-inpurity radiations were strongly reduced with the carbonized wall. Main impacts of the metal reduction on plasma behaviors are sustainment of stored energy during high power, long pulse heating by NBI, achievement of a quasi-steady discharge with a low helical field and high beta, and highest electron density with pellet injection in a quasi-steady state. Hydrogen recycling was very high with the carbonized wall and low density operation was impossible. Helium glow discharge was found to be effective to control the hydrogen recycling with a carbon-tiled wall. (orig.).

UTE park group and other meso proterozoic units of the Nico Perez terrane: Rodina connecting

International Nuclear Information System (INIS)

Gaucher, C; Chemale, F.; Bossi, J.; Sial, A.; Chiglino, L.

2010-01-01

The Parque UTE Group is a volcano sedimentary succession metamorphosed in green schist facies, comprising (from base to top): the Canada Espinillo Formation (prasinites, pelites, andesite s), the Mina Valencia Formation (dolostones, limestones, marls) and the Cerro del Mast il Formation (black pelites, limestones, acid tuffs). Thickness of the GPU exceeds 2.5 km; base and top are not exposed. U-Pb zircon ages for basic magmatic rocks at the base and rhyolites at the top yielded 1492±4 and 1429±21 Ma, respectively. 13C values of carbonates of the Pug are characterized by a plateau at +1‰ VPDB, bracketed between two negative excursions.These values are consistent with an early Mesoproterozoic depositional age. Detrital zircon age spectra show that the source area of the GPU was the Nico Perez Terrane, being thus native to the Rio de la Plata Craton (Rpc). A Mesoproterozoic tectonic event at 1.25 Ga, recorded at both sides of the Sarandi del Yi mega shear, is discussed. New U-Pb zircon ages are presented for the La China Complex at its type area, where a schistosity N60W cuts the metamorphic banding and is parallel to thrusts dated K-Ar at 1253±32 Ma. The ages obtained are: 3096±45 Ma (main metamorphic event) and 1252 Ma (lower intercept). These data confirm the occurrence of a Grenvillian-aged tectonic event in Uruguay, suggesting that the RPC was part of the super continent Rodinia

Polyaniline-deposited porous carbon electrode for supercapacitor

International Nuclear Information System (INIS)

Chen, W.-C.; Wen, T.-C.; Teng, H.

2003-01-01

Electrodes for supercapacitors were fabricated by depositing polyaniline (PANI) on high surface area carbons. The chemical composition of the PANI-deposited carbon electrode was determined by X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to investigate the electrochemical properties of electrodes. An equivalent circuit was proposed to successfully fit the EIS data, and the significant contribution of pseudocapacitance from PANI was thus identified. A comparative analysis on the electrochemical properties of bare-carbon electrodes was also conducted under similar conditions. The performance of the capacitors equipped with the resulting electrodes in 1 M H 2 SO 4 was evaluated by constant current charge-discharge cycling within a potential range from 0 to 0.6 V. The PANI-deposited electrode exhibits high specific capacitance of 180 F/g, in comparison with a value of 92 F/g for the bare-carbon electrode

Carbon dust formation in a cold plasma from cathode sputtering

International Nuclear Information System (INIS)

Arnas, C.; Mouberi, A.; Hassouni, K.; Michau, A.; Lombardi, G.; Bonnin, X.; Benedic, F.; Pegourie, B.

2009-01-01

Nanoparticles are produced in argon glow plasmas where carbon is introduced by sputtering of a graphite cathode. A scaling law of growth is reported on as a function of the discharge time. Two successive stages of growth of concomitant agglomeration and carbon deposition are observed, followed by a final stage of growth by carbon deposition. A model of formation of molecular precursors by coagulation of neutral clusters on the one hand and of neutral-negative clusters on the other hand is presented, based on formation enthalpy and cluster geometry.

Carbon dust formation in a cold plasma from cathode sputtering

Science.gov (United States)

Arnas, C.; Mouberi, A.; Hassouni, K.; Michau, A.; Lombardi, G.; Bonnin, X.; Bénédic, F.; Pégourié, B.

2009-06-01

Nanoparticles are produced in argon glow plasmas where carbon is introduced by sputtering of a graphite cathode. A scaling law of growth is reported on as a function of the discharge time. Two successive stages of growth of concomitant agglomeration and carbon deposition are observed, followed by a final stage of growth by carbon deposition. A model of formation of molecular precursors by coagulation of neutral clusters on the one hand and of neutral-negative clusters on the other hand is presented, based on formation enthalpy and cluster geometry.

Fracture in Phenolic Impregnated Carbon Ablator

Science.gov (United States)

Agrawal, Parul; Chavez-Garcia, Jose; Pham, John

2013-01-01

This paper describes the development of a novel technique to understand the failure mechanisms inside thermal protection materials. The focus of this research is on the class of materials known as phenolic impregnated carbon ablators. It has successfully flown on the Stardust spacecraft and is the thermal protection system material chosen for the Mars Science Laboratory and SpaceX Dragon spacecraft. Although it has good thermal properties, structurally, it is a weak material. To understand failure mechanisms in carbon ablators, fracture tests were performed on FiberForm(Registered TradeMark) (precursor), virgin, and charred ablator materials. Several samples of these materials were tested to investigate failure mechanisms at a microstructural scale. Stress-strain data were obtained simultaneously to estimate the tensile strength and toughness. It was observed that cracks initiated and grew in the FiberForm when a critical stress limit was reached such that the carbon fibers separated from the binder. However, both for virgin and charred carbon ablators, crack initiation and growth occurred in the matrix (phenolic) phase. Both virgin and charred carbon ablators showed greater strength values compared with FiberForm samples, confirming that the presence of the porous matrix helps in absorbing the fracture energy.

Preparation of porous carbon particle with shell/core structure

Directory of Open Access Journals (Sweden)

2007-05-01

Full Text Available Porous carbon particles with a shell/core structure have been prepared successfully by controlled precipitation of the polymer from droplets of oil-in-water emulsion, followed by curing and carbonization. The droplets of the oil phase are composed of phenolic resin (PFR, a good solvent (ethyl acetate and porogen (Poly(methyl methacrylate, PMMA. The microstructure was characterized in detail by scanning electron microscopy (SEM, transmission electron microscopy (TEM, nitrogen adsorption, and thermo gravimetric analysis (TGA. The obtained carbon particles have a capsular structure with a microporous carbon shell and a mesoporous carbon core. The BET surface area and porous volume are calculated to be 499 m2g-1 and 0.56 cm3g-1, respectively. The effects of the amount of porogen (PMMA, co-solvent (acetone and surfactant on the resultant structure were studied in detail.

Design of a new hypoxanthine biosensor: xanthine oxidase modified carbon film and multi-walled carbon nanotube/carbon film electrodes.

Science.gov (United States)

Torres, A Carolina; Ghica, M Emilia; Brett, Christopher M A

2013-04-01

A new and simple-to-prepare hypoxanthine biosensor has been developed using xanthine oxidase (XOD) immobilised on carbon electrode surfaces. XOD was immobilised by glutaraldehyde cross-linking on carbon film (CF) electrodes and on carbon nanotube (CNT) modified CF (CNT/CF). A comparison of the performance of the two configurations was carried out by the current response using amperometry at fixed potential; the best characteristics being exhibited by XOD/CNT/CF modified electrodes. The effects of electrolyte pH and applied potential were evaluated, and a proposal is made for the enzyme mechanism of action involving competition between regeneration of flavin adenine dinucleotide and reduction of hydrogen peroxide. Under optimised conditions, the determination of hypoxanthine was carried out at -0.2 V vs. a saturated calomel electrode (SCE) with a detection limit of 0.75 μM on electrodes with CNT and at -0.3 V vs. SCE with a detection limit of 0.77 μM on electrodes without CNT. The applicability of the biosensor was verified by performing an interference study, reproducibility and stability were investigated, and hypoxanthine was successfully determined in sardine and shrimp samples.

CARBONIZER TESTS WITH LAKELAND FEEDSTOCKS

Energy Technology Data Exchange (ETDEWEB)

C. Lu; Z. Fan; R. Froehlich; A. Robertson

2003-09-01

Research has been conducted under United States Department of Energy Contract (USDOE) DE-AC21-86MC21023 to develop a new type of coal-fired plant for electric power generation. This new type of plant, called a Second Generation Pressurized Fluidized Bed Combustion Plant (2nd Gen PFB), offers the promise of efficiencies greater than 48%, with both emissions and a cost of electricity that are significantly lower than those of conventional pulverized coal-fired (PC) plants with wet flue gas desulfurization/scrubbers. The 2nd Gen PFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized (PCFB) bed boiler, and the combustion of carbonizer syngas in a topping combustor to achieve gas turbine inlet temperatures of 2700 F and higher. Under the USDOE Clean Coal V Demonstration Plant Program, a nominal 260 MWe plant demonstrating 2nd Gen PFB technology has been proposed for construction at the McIntosh Power Plant of the City of Lakeland, Florida. In the September-December 1997 time period, four test runs were conducted in Foster Wheeler's 12-inch diameter carbonizer pilot plant in Livingston New Jersey to ascertain carbonizer performance characteristics with the Kentucky No. 9 coal and Florida limestone proposed for use in the Lakeland plant. The tests were of a short-term nature exploring carbonizer carbon conversions, sulfur capture efficiencies and syngas alkali levels. The tests were successful; observed carbonizer performance was in agreement with predictions and no operating problems, attributed to the planned feedstocks, were encountered. The results of the four test runs are reported herein.

NOVEL CERAMIC MEMBRANE FOR HIGH TEMPERATURE CARBON DIOXIDE SEPARATION

International Nuclear Information System (INIS)

Ida, Jun-ichi; Yang, Zhaohui; Lin, Jerry Y.S.

2002-01-01

A new CO 2 semi-permeable dense inorganic membrane consisting of a porous metal phase and molten carbonate was proposed. A simple direct infiltration method was used to synthesize the metal-carbonate dual-phase membrane. Hermetic (gas-tight) dual phase membrane was successfully obtained. Permeation data showed that nitrogen or helium is not permeable through the membrane (only CO 2 , with O 2 can permeate through the membrane based on transport mechanism)

Electrochemical deposition of gold nanoparticles on carbon nanotube coated glassy carbon electrode for the improved sensing of tinidazole

International Nuclear Information System (INIS)

Shahrokhian, Saeed; Rastgar, Shokoufeh

2012-01-01

The electrochemical reduction of tinidazole (TNZ) is studied on gold-nanoparticle/carbon-nanotubes (AuNP/CNT) modified glassy carbon electrodes using the linear sweep voltammetry. An electrochemical procedure was used for the deposition of gold nanoparticles onto the carbon nanotube film pre-cast on a glassy carbon electrode surface. The resulting nanoparticles were characterized by scanning electron microscopy and cyclic voltammetry. The effect of the electrodeposition conditions, e.g., salt concentration and deposition time on the response of the electrode was studied. Also, the effect of experimental parameters, e.g., potential and time of accumulation, pH of the buffered solutions and the potential sweep rate on the response is examined. Under the optimal conditions, the modified electrode showed a wide linear response toward the concentration of TNZ in the range of 0.1–50 μM with a detection limit of 10 nM. The prepared electrode was successfully applied for the determination of TNZ in pharmaceutical and clinical samples.

Heavy metal ion adsorption onto polypyrrole-impregnated porous carbon.

Science.gov (United States)

Choi, Moonjung; Jang, Jyongsik

2008-09-01

Polypyrrole-impregnated porous carbon was readily synthesized using vapor infiltration polymerization of pyrrole monomers. The results show that the functionalized polymer layer was successfully coated onto the pore surface of carbon without collapse of mesoporous structure. The modified porous carbon exhibited an improved complexation affinity for heavy metal ions such as mercury, lead, and silver ions due to the amine group of polypyrrole. The introduced polypyrrole layer could provide the surface modification to be applied for heavy metal ion adsorbents. Especially, polymer-impregnated porous carbon has an enhanced heavy metal ion uptake, which is 20 times higher than that of adsorbents with amine functional groups. Furthermore, the relationship between the coated polymer amount and surface area was also investigated in regard to adsorption capacity.

Pb/Pb isochron ages and Pb isotope geochemistry of Bambui Group carbonate rocks from the southern portion of the Sao Francisco Basin

International Nuclear Information System (INIS)

Babinski, M.

1993-01-01

This study involves the establishment of chemical and analytical procedure for Pb/Pb dating of Neo proterozoic carbonate rocks and their application to obtaining isochron ages of Bambui Group rocks from the southern portion of the Sao Francisco Basin, Minas Gerais State. The Pb isotopic compositions and U and Pb concentrations determined on more than 90 samples (≅ 600 analyses) from Sete Lagoas do Jacare formations, Bambui Group, from different parts of the basin, showed four distinct types of Pb, here called types I, II, III and IV. Type I Pb was found in samples with low Pb concentrations and relatively high U concentrations. Type II Pb is present in samples with relatively high Pb concentrations and low U concentrations it is non-radiogenic crustal Pb. Type III Pb is also found in samples with high Pb concentrations and low U concentrations but it is radiogenic crustal Pb. Type IV Pb occurs in samples with U/Pb ratios lower than 1 and is intermediate in composition between Type III and Type I Pb. According to the data presented in this paper it is suggested that carbonate rocks from Sete Lagoas Formations were deposited before 686±69 Ma. Rocks from the Lagoa do Jacare Formation, contained only Type II Pb, which does not permit determination of a Pb/Pb age. During the interval from 690 to 500 Ma, the Pb isotope system of the carbonate rocks from the Sao Francisco Basin was disturbed, and in some areas it was totally reset. The imprecise U/Pb ages of 550-600 Ma obtained from some of the carbonate rocks reflect this disturbance. The ages determined in this study are in agreement with most of the published ages of the tectonism from the Brasiliano fold belts marginal to Sao Francisco Craton, showing that the isotopic systems of Sao Francisco Basin rocks were largely affected by brasiliano tectonism. (author)

Functional Biomass Carbons with Hierarchical Porous Structure for Supercapacitor Electrode Materials

International Nuclear Information System (INIS)

Chen, Hao; Liu, Duo; Shen, Zhehong; Bao, Binfu; Zhao, Shuyan; Wu, Limin

2015-01-01

Highlights: • We successfully prepared bamboo-derived porous carbon with B and N co-doping. • This novel carbon exhibits significantly enhanced specific capacitance and energy density. • The highest specific capacitance exceeds those of most similar carbon materials. • Asymmetric supercapacitor based on this carbon shows satisfactory capacitive performance. - Abstract: This paper presents nitrogen and boron co-doped KOH-activated bamboo-derived carbon as a porous biomass carbon with utility as a supercapacitor electrode material. Owing to the high electrochemical activity promoted by the hierarchical porous structure and further endowed by boron and nitrogen co-doping, electrodes based on the as-obtained material exhibit significantly enhanced specific capacitance and energy density relative to those based on most similar materials. An asymmetric supercapacitor based on this novel carbon material demonstrated satisfactory energy density and electrochemical cycling stability.

Functionalization of carbon nanotubes with silver clusters

International Nuclear Information System (INIS)

Cveticanin, Jelena; Krkljes, Aleksandra; Kacarevic-Popovic, Zorica; Mitric, Miodrag; Rakocevic, Zlatko; Trpkov, Djordje; Neskovic, Olivera

2010-01-01

In this paper, an advanced method of one-step functionalization of single and multi walled carbon nanotubes (SWCNTs and MWCNTs) using γ-irradiation was described. Two synthesis procedures, related with different reduction species, were employed. For the first time, poly(vinyl alcohol) PVA is successfully utilized as a source to reduce silver (Ag) metal ions without having any additional reducing agents to obtain Ag nanoparticles on CNTs. The decoration of carbon nanotubes with Ag nanoparticles takes place through anchoring of (PVA) on nanotube's surface. Optical properties of as-prepared samples and mechanism responsible for the functionalization of carbon nanotubes were investigated using UV-vis and FTIR spectroscopy, respectively. Decorated carbon nanotubes were visualized using microscopic techniques: transmission electron microscopy and scanning tunneling microscopy. Also, the presence of Ag on the nanotubes was confirmed using energy dispersive X-ray spectroscopy. This simple and effective method of making a carbon nanotube type of composites is of interest not only for an application in various areas of technology and biology, but for investigation of the potential of radiation technology for nanoengineering of materials.

Modelling interactions of carbon dioxide, forests, and climate

International Nuclear Information System (INIS)

Luxmoore, R.J.; Baldocchi, D.D.

1994-01-01

Atmospheric carbon dioxide is rising and forests and climate is changing exclamation point This combination of fact and premise may be evaluated at a range of temporal and spatial scales with the aid of computer simulators describing the interrelationships between forest vegetation, litter and soil characteristics, and appropriate meteorological variables. Some insights on the effects of climate on the transfers of carbon and the converse effect of carbon transfer on climate are discussed as a basis for assessing the significance of feedbacks between vegetation and climate under conditions of rising atmospheric carbon dioxide. Three main classes of forest models are reviewed. These are physiologically-based models, forest succession simulators based on the JABOWA model, and ecosystem-carbon budget models that use compartment transfer rates with empirically estimated coefficients. Some regression modeling approaches are also outlined. Energy budget models applied to forests and grasslands are also reviewed. This review presents examples of forest models; a comprehensive discussion of all available models is not undertaken

Low temperature CVD growth of ultrathin carbon films

Directory of Open Access Journals (Sweden)

Chao Yang

2016-05-01

Full Text Available We demonstrate the low temperature, large area growth of ultrathin carbon films by chemical vapor deposition under atmospheric pressure on various substrates. In particularly, uniform and continuous carbon films with the thickness of 2-5 nm were successfully grown at a temperature as low as 500 oC on copper foils, as well as glass substrates coated with a 100 nm thick copper layer. The characterizations revealed that the low-temperature-grown carbon films consist on few short, curved graphene layers and thin amorphous carbon films. Particularly, the low-temperature grown samples exhibited over 90% transmittance at a wavelength range of 400-750 nm and comparable sheet resistance in contrast with the 1000oC-grown one. This low-temperature growth method may offer a facile way to directly prepare visible ultrathin carbon films on various substrate surfaces that are compatible with temperatures (500-600oC used in several device processing technologies.

Direct synthesis of nitrogen-containing carbon nanotubes on carbon paper for fuel cell electrode

Science.gov (United States)

Yin, Wong Wai; Daud, Wan Ramli Wan; Mohamad, Abu Bakar; Kadhum, Abdul Amir Hassan; Majlan, Edy Herianto; Shyuan, Loh Kee

2012-06-01

Organic catalyst has recently been identified as the potential substitution for expensive platinum electrocatalyst for fuel cell application. Numerous studies have shown that the nitrogen-containing carbon nanotubes (N-CNT) can be synthesized through spray pyrolysis or floating chemical vapor deposition (CVD) technique using various type of organometallic as precursors. This paper presents the method of synthesis and the initial findings of the growth of N-CNT directly on carbon paper using a modified CVD technique. In this research, nickel (II) phthalocyanines (Ni-Pc) as precursor was dissolved in ethanol solvent, stirred and sonicated to become homogenized. The solution was poured into a bubbler and heated up to allow the mixture to vaporize. Subsequently, the solution vapor was flowed into the tubical reactor maintained at 900°C. Carbon paper sputtered with nickel nanoparticles was used as the substrate. The synthesized sample was examined through Field Emission Scanning Electron Microscopy (FESEM), Atomic Force Microscopy (AFM) and Fourier Transform Infra-Red (FTIR). Long, entangled and compartmentalized nanotubes with tube diameter ranging 23-27 nm were found covered the carbon paper surface with approximate of 5.5-6.0 μm in thickness. EDX analysis has successfully showed the presence of nitrogen in the carbon nanotube. FTIR analysis showed the presence of the C-N bond on CNT.

Upscaling Our Approach to Peatland Carbon Sequestration: Remote Sensing as a Tool for Carbon Flux Estimation.

Science.gov (United States)

Lees, K.; Khomik, M.; Clark, J. M.; Quaife, T. L.; Artz, R.

2017-12-01

Peatlands are an important part of the Earth's carbon cycle, comprising approximately a third of the global terrestrial carbon store. However, peatlands are sensitive to climatic change and human mismanagement, and many are now degraded and acting as carbon sources. Restoration work is being undertaken at many sites around the world, but monitoring the success of these schemes can be difficult and costly using traditional methods. A landscape-scale alternative is to use satellite data in order to assess the condition of peatlands and estimate carbon fluxes. This work focuses on study sites in Northern Scotland, where parts of the largest blanket bog in Europe are being restored from forest plantations. A combination of laboratory and fieldwork has been used to assess the Net Ecosystem Exchange (NEE), Gross Primary Productivity (GPP) and respiration of peatland sites in different conditions, and the climatic vulnerability of key peat-forming Sphagnum species. The results from these studies have been compared with spectral data in order to evaluate the extent to which remote sensing can function as a source of information for peatland health and carbon flux models. This work considers particularly the effects of scale in calculating peatland carbon flux. Flux data includes chamber and eddy covariance measurements of carbon dioxide, and radiometric observations include both handheld spectroradiometer results and satellite images. Results suggest that despite the small-scale heterogeneity and unique ecosystem factors in blanket bogs, remote sensing can be a useful tool in monitoring peatland health and carbon sequestration. In particular, this study gives unique insights into the relationships between peatland vegetation, carbon flux and spectral reflectance.

Carbon Lorenz Curves

Energy Technology Data Exchange (ETDEWEB)

Groot, L. [Utrecht University, Utrecht School of Economics, Janskerkhof 12, 3512 BL Utrecht (Netherlands)

2008-11-15

The purpose of this paper is twofold. First, it exhibits that standard tools in the measurement of income inequality, such as the Lorenz curve and the Gini-index, can successfully be applied to the issues of inequality measurement of carbon emissions and the equity of abatement policies across countries. These tools allow policy-makers and the general public to grasp at a single glance the impact of conventional distribution rules such as equal caps or grandfathering, or more sophisticated ones, on the distribution of greenhouse gas emissions. Second, using the Samuelson rule for the optimal provision of a public good, the Pareto-optimal distribution of carbon emissions is compared with the distribution that follows if countries follow Nash-Cournot abatement strategies. It is shown that the Pareto-optimal distribution under the Samuelson rule can be approximated by the equal cap division, represented by the diagonal in the Lorenz curve diagram.

The carbonaceous matter in the uraniferous dequartzified and albitized leucogranite of Saraya (Senegal): an example of superimposed hydrothermal alterations

International Nuclear Information System (INIS)

Mouthier, B.

1988-01-01

Two superimposed early hydrothermal alterations have been recognized in the Proterozoic Saraya leucogranite. Successively are described a major dequartzification leading to an episyenite infilled with carbonaceous matter and sulfate during an interruption of the system, succeeded by a mobilization of U and other elements during an albitization. A dolomite filling up followed by a silicopotassic feed-back alteration, close down the system [fr

Tectonic regime and evolution of exogenous uranium ore formation in sedimentary rocks

International Nuclear Information System (INIS)

Danchev, V.I.; Shumlyanskij, V.A.; AN Ukrainskoj SSR, Kiev. Inst. Geokhimii i Fiziki Mineralov)

1981-01-01

Regularities of the formation and location of exogenous uranium deposits are studied depending on the tectonics regime. It is shown that the successive alternation of sedimentogenous deposits by diagenetic and, subsequently, catogene ones takes place from early Proterozoic to Cenozoic, i.e. exogenous ore formation in the history of the Earth proceeds from early to late stages of lithogenesis [ru

Six-man, self-contained carbon dioxide concentrator subsystem for Space Station Prototype (SSP) application

Science.gov (United States)

Kostell, G. D.; Schubert, F. H.; Shumar, J. W.; Hallick, T. M.; Jensen, F. C.

1974-01-01

A six man, self contained, electrochemical carbon dioxide concentrating subsystem for space station prototype use was successfully designed, fabricated, and tested. A test program was successfully completed which covered shakedown testing, design verification testing, and acceptance testing.

Fabrication of carbon microcapsules containing silicon nanoparticles-carbon nanotubes nanocomposite by sol-gel method for anode in lithium ion battery

Science.gov (United States)

Bae, Joonwon

2011-07-01

Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT@C) have been fabricated by a surfactant mediated sol-gel method followed by a carbonization process. Silicon nanoparticles-carbon nanotubes (Si-CNT) nanohybrids were produced by a wet-type beadsmill method. To obtain Si-CNT nanocomposites with spherical morphologies, a silica precursor (tetraethylorthosilicate, TEOS) and polymer (PMMA) mixture was employed as a structure-directing medium. Thus the Si-CNT/Silica-Polymer microspheres were prepared by an acid catalyzed sol-gel method. Then a carbon precursor such as polypyrrole (PPy) was incorporated onto the surfaces of pre-existing Si-CNT/silica-polymer to generate Si-CNT/Silica-Polymer@PPy microspheres. Subsequent thermal treatment of the precursor followed by wet etching of silica produced Si-CNT@C microcapsules. The intermediate silica/polymer must disappear during the carbonization and etching process resulting in the formation of an internal free space. The carbon precursor polymer should transform to carbon shell to encapsulate remaining Si-CNT nanocomposites. Therefore, hollow carbon microcapsules containing Si-CNT nanocomposites could be obtained (Si-CNT@C). The successful fabrication was confirmed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). These final materials were employed for anode performance improvement in lithium ion battery. The cyclic performances of these Si-CNT@C microcapsules were measured with a lithium battery half cell tests.

Photomicrobial fuel cell (PFC) for simultaneous organic carbon, nutrients removal and energy production

DEFF Research Database (Denmark)

Zhang, Yifeng; Safa, Jafar; Angelidaki, Irini

2014-01-01

of power generation, carbon and nutrients removal was not significantly affected after changing the light/dark photoperiod from 24 h/0 h to 10 h/14 h. This work represents the first successful attempt to develop an effective bacteria-algae coupled system, capable for extracting energy and removing carbon...

Carbonization

Energy Technology Data Exchange (ETDEWEB)

Hennebutte, H G; Goutal, E

1921-07-04

Materials such as coal, peat, or schist are subjected to a rising temperature in successive stages in apparatus in which the distillation products are withdrawn at each stage. For example in a three-stage process, the acid products of the first or low-temperature stage are fixed in a suitable reagent, the basic products from a second or higher-temperature stage are absorbed in an acid reagent, hydrocarbons being retained by solvents, while the third are subjected to a pyrogenation process carried out in a closed vessel. Wherein the material is subjected in stages to a rising temperature, the gasified products being withdrawn at each stage, and are prevented as far as possible from mixing with the carbonized products.

Carbonate rocks of the Seward Peninsula, Alaska: Their correlation and paleogeographic significance

Science.gov (United States)

Dumoulin, Julie A.; Harris, Alta; Repetski, John E.

2014-01-01

Paleozoic carbonate strata deposited in shallow platform to off-platform settings occur across the Seward Peninsula and range from unmetamorphosed Ordovician–Devonian(?) rocks of the York succession in the west to highly deformed and metamorphosed Cambrian–Devonian units of the Nome Complex in the east. Faunal and lithologic correlations indicate that early Paleozoic strata in the two areas formed as part of a single carbonate platform. The York succession makes up part of the York terrane and consists of Ordovician, lesser Silurian, and limited, possibly Devonian rocks. Shallow-water facies predominate, but subordinate graptolitic shale and calcareous turbidites accumulated in deeper water, intraplatform basin environments, chiefly during the Middle Ordovician. Lower Ordovician strata are mainly lime mudstone and peloid-intraclast grainstone deposited in a deepening upward regime; noncarbonate detritus is abundant in lower parts of the section. Upper Ordovician and Silurian rocks include carbonate mudstone, skeletal wackestone, and coral-stromatoporoid biostromes that are commonly dolomitic and accumulated in warm, shallow to very shallow settings with locally restricted circulation. The rest of the York terrane is mainly Ordovician and older, variously deformed and metamorphosed carbonate and siliciclastic rocks intruded by early Cambrian (and younger?) metagabbros. Older (Neoproterozoic–Cambrian) parts of these units are chiefly turbidites and may have been basement for the carbonate platform facies of the York succession; younger, shallow- and deep-water strata likely represent previously unrecognized parts of the York succession and its offshore equivalents. Intensely deformed and altered Mississippian carbonate strata crop out in a small area at the western edge of the terrane. Metacarbonate rocks form all or part of several units within the blueschist- and greenschist-facies Nome Complex. The Layered sequence includes mafic meta¬igneous rocks and

Covalent organic polymer functionalization of activated carbon surfaces through acyl chloride for environmental clean-up

DEFF Research Database (Denmark)

Mines, Paul D.; Thirion, Damien; Uthuppu, Basil

2017-01-01

Nanoporous networks of covalent organic polymers (COPs) are successfully grafted on the surfaces of activated carbons, through a series of surface modification techniques, including acyl chloride formation by thionyl chloride. Hybrid composites of activated carbon functionalized with COPs exhibit...

The importance of groundwater-derived carbon dioxide in the restoration of small Sphagnum bogs

NARCIS (Netherlands)

Patberg, Wouter; Baaijens, Gert Jan; Smolders, Alfons J. P.; Grootjans, Ab P.; Elzenga, J. Theo M.

Essential for successful bog restoration is the reestablishment of Sphagnum mosses. High carbon dioxide availability has been shown to be of great importance for the growth of Sphagnum mosses. In well-developed Sphagnum bogs large amounts of carbon dioxide are produced by (an)aerobic decomposition

The carbonate-hosted willemite prospects of the Zambezi Metamorphic Belt (Zambia)

Science.gov (United States)

Boni, Maria; Terracciano, Rosario; Balassone, Giuseppina; Gleeson, Sarah A.; Matthews, Alexander

2011-10-01

Zambian willemite (Zn2SiO4) deposits occur in the metasedimentary carbonate rocks of the Proterozoic Katangan Supergroup. The most important orebodies are located around Kabwe and contain both sulphides and willemite in dolomites of low metamorphic grade. The Star Zinc and Excelsior prospects (Lusaka area), discovered in the early 1920s, occur in the metamorphic lithotypes of the late Proterozoic Zambezi Supracrustal sequence, which were deposited in a transtensional basin formed during the oblique collision of the Kalahari and Congo cratons. The deposits are hosted by the limestone and dolomitic marbles of the Cheta and Lusaka Formations. Structural analysis indicates that several fracture sets host the deposits, which may be genetically related to the Pan-African Mwembeshi dislocation zone (a major geotectonic boundary between the Lufilian Arc and the Zambezi Belt). In both prospects, willemite replaces the marbles and is found along joints and fissures with open-space filling textures and locally may develop colloform and vuggy fabrics as well. Silver as well as traces of germanium and cadmium have been detected within the willemite ore, and lead or zinc sulphides are scarce or absent. Calcite locally replaces willemite. Willemite is associated with specular hematite and franklinite and post-dates the Zn-spinel gahnite in the paragenesis. Genthelvite [Zn4Be3(SiO4)3S] occurs as a minor phase in irregular aggregates. The willemites from the Lusaka area, though Mn-poor, show green cathodoluminescence colours and bright green fluorescence in short-wave UV (as the high-temperature willemites in USA). Thermometric analyses of primary fluid inclusions in willemite yield homogenization temperatures that range from 160°C to 240°C and salinities of 8-16 wt.% equiv. NaCl. The homogenization temperatures suggest a hypogene-hydrothermal origin for the willemite concentrations. The geochemistry of fluid inclusion leachates suggests that the hydrothermal fluids were brines

Understanding Magmatic Timescales and Magma Dynamics in Proterozoic Anorthosites: a Geochronological Investigation of the Kunene Complex (Angola)

Science.gov (United States)

Brower, A. M.; Corfu, F.; Bybee, G. M.; Lehmann, J.; Owen-Smith, T.

2016-12-01

The Kunene Anorthosite Complex, located in south west Angola, is one of the largest massif-type anorthosite intrusions on Earth, with an areal extent of at least 18 000 km2. Previous studies considered the Complex to consist of a series of coalesced plutons. However, the ages and relative emplacement sequence of these plutons are unknown. Understanding the relative timing of the pluton emplacement is crucial for understanding how these enigmatic magmas form and how they rise through the crust. Here we present new high precision U-Pb ID-TIMS ages (n=10) on zircons and baddeleyites for many of the coalesced plutons across the 300-km-long anorthositic complex. These new geochronological results reveal subtle variations in crystallization age between the coalesced plutons. There is no gradual age progression between plutons, but distinct groupings of ages (Fig.1). Age clusters of 1379.8 ± 2 Ma (n=5) occur north of the Red Granite NE-SW-striking intrusions, whereas in the south there is an older age grouping of 1390.4 ± 2.3 (n=3). Two additional ages of 1400.5 ± 1.3 in the centre and 1438.4 ± 1.1 Ma in the south east have been obtained. These results indicate that the Kunene anorthosites were emplaced over 60 Ma and may suggest long-lived magmatic systems and/or slowly ascending plutons. We also find a link between pluton composition and age. In general, leuconoritic domains are older than the leucotroctolitic domains. This may imply that the first pulses of magma received a greater degree of contamination, forcing the broadly basaltic magma to produce orthopyroxene as the main mafic phase. The later pulses receive less contamination as they ascend through the already partially melted crust, producing olivine as the mafic phase and deforming the older domains. This study reiterates the multiphase petrogenesis of Proterozoic anorthosites and sheds light on the assembly of crystal-rich magmas as they ascend through the crust.

Unconformity-related uranium deposits

International Nuclear Information System (INIS)

Ewers, G.R.; Ferguson, J.

1985-01-01

Documentation of ore deposit characterisation is being undertaken to assess the controls of uranium mineralisation associated with Proterozoic unconformities. The Turee Creek uranium prospect in Western Australia is associated with a faulted contact between the Middle Proterozoic Kunderong Sandstone and the Lower Proterozoic Wyloo Group

To invest efficiently for a successful energy transition

International Nuclear Information System (INIS)

Beutier, Didier

2017-01-01

As the primary objective of any energy policy is now to reduce carbon dioxide emissions, i.e. to reduce the consumption of all carbonated fuels (coal, oil, gas) in all sectors, and to substitute them with electricity produced from nuclear and renewable sources, and all this under a double constraint (that of consumers, and that of public finances), this article aims at discussing whether the French policy defined by the law on energy transition for a green growth is able to face and meet these priorities. The author outlines that the struggle against greenhouse gas emissions in France mainly concerns the transport and heating sectors. He discusses drawbacks associated with a transition mainly focussed on electric power generation by wind and solar energy: these drawbacks concern the required and actual production level, necessary high investments, and the protection of the environment. He proposes four areas of development for a successful transition: electric transport, energy storage, power-to-gas conversion, and housing thermal insulation

Testing isotherm models and recovering empirical relationships for adsorption in microporous carbons using virtual carbon models and grand canonical Monte Carlo simulations

International Nuclear Information System (INIS)

Terzyk, Artur P; Furmaniak, Sylwester; Gauden, Piotr A; Harris, Peter J F; Wloch, Jerzy

2008-01-01

Using the plausible model of activated carbon proposed by Harris and co-workers and grand canonical Monte Carlo simulations, we study the applicability of standard methods for describing adsorption data on microporous carbons widely used in adsorption science. Two carbon structures are studied, one with a small distribution of micropores in the range up to 1 nm, and the other with micropores covering a wide range of porosity. For both structures, adsorption isotherms of noble gases (from Ne to Xe), carbon tetrachloride and benzene are simulated. The data obtained are considered in terms of Dubinin-Radushkevich plots. Moreover, for benzene and carbon tetrachloride the temperature invariance of the characteristic curve is also studied. We show that using simulated data some empirical relationships obtained from experiment can be successfully recovered. Next we test the applicability of Dubinin's related models including the Dubinin-Izotova, Dubinin-Radushkevich-Stoeckli, and Jaroniec-Choma equations. The results obtained demonstrate the limits and applications of the models studied in the field of carbon porosity characterization

Contact metamorphic effects of the basic intrusive rocks on the Proterozoic uraniferous dolostone in Cuddapah basin, Andhra Pradesh: implications on uranium mobilisation

International Nuclear Information System (INIS)

Roy, Minati; Panda, Arjuna; Dhana Raju, R.

1997-01-01

Mafic intrusive rocks in the Vempalle formation of the mid-Proterozoic Cuddapah basin occur as sills and dykes. These include minor bodies of gabbro, olivine gabbro, olivine norite, basalt and mainly dolerite with basaltic andesite. The metamorphic effects of these intrusive rocks on the uraniferous phosphatic siliceous dolostone are mainly mineralogical (thermal) with subordinate changes in chemistry. These are manifested by (a) formation of plagioclase-hornblende hornfels, (b) notable mineralogical changes in the dolostone leading to enrichment of magnetite, epidote, anatase and de-dolomitised calcite, (c) decrease in specific gravity of dolostone from 3.0 to 2.8 due to volatilisation reaction products of epidote and smectite, and (d) formation of wollastonite, chalcedony, and secondary uranium minerals (autunite and uranophane) at places, in the contact aureole that led to notable changes in the chemistry of the intrusive body and the host rock. Intrusive rocks at the contact show enrichment in Fe 2+ , Mg, Cu, Cr, Pb, Zn, Ni, and depletion in Ca and Fe 3+ , whereas the dolostone shows enrichment in Ti, Ca, and depletion in Si, Al, alkalies and P. Depletion of uranium in the affected parts (0.003% U 3 O 8 ) of mineralised dolostone (0.062% U 3 O 8 ) adjacent to the basic intrusive rocks suggests its mobilisation, due to increase in temperature, resulting in baking. This phenomenon is also manifested, at places, in the formation of secondary uranium minerals - result of remobilisation of uranium from primary phases and its subsequent precipitation. (author)

Carbon composite micro- and nano-tubes-based electrodes for detection of nucleic acids

Directory of Open Access Journals (Sweden)

Huska Dalibor

2011-01-01

Full Text Available Abstract The first aim of this study was to fabricate vertically aligned multiwalled carbon nanotubes (MWCNTs. MWCNTs were successfully prepared by using plasma enhanced chemical vapour deposition. Further, three carbon composite electrodes with different content of carbon particles with various shapes and sizes were prepared and tested on measuring of nucleic acids. The dependences of adenine peak height on the concentration of nucleic acid sample were measured. Carbon composite electrode prepared from a mixture of glassy and spherical carbon powder and MWCNTs had the highest sensitivity to nucleic acids. Other interesting result is the fact that we were able to distinguish signals for all bases using this electrode.

Thermodynamics on Soluble Carbon Nanotubes: How Do DNA Molecules Replace Surfactants on Carbon Nanotubes?

Science.gov (United States)

Kato, Yuichi; Inoue, Ayaka; Niidome, Yasuro; Nakashima, Naotoshi

2012-01-01

Here we represent thermodynamics on soluble carbon nanotubes that enables deep understanding the interactions between single-walled carbon nanotubes (SWNTs) and molecules. We selected sodium cholate and single-stranded cytosine oligo-DNAs (dCn (n = 4, 5, 6, 7, 8, 10, 15, and 20)), both of which are typical SWNT solubilizers, and successfully determined thermodynamic properties (ΔG, ΔH and ΔS values) for the exchange reactions of sodium cholate on four different chiralities of SWNTs ((n,m) = (6,5), (7,5), (10,2), and (8,6)) for the DNAs. Typical results contain i) the dC5 exhibited an exothermic exchange, whereas the dC6, 8, 10, 15, and 20 materials exhibited endothermic exchanges, and ii) the energetics of the dC4 and dC7 exchanges depended on the associated chiral indices and could be endothermic or exothermic. The presented method is general and is applicable to any molecule that interacts with nanotubes. The study opens a way for science of carbon nanotube thermodynamics. PMID:23066502

Trailblazing the Carbon Cycle of Tropical Forests from Puerto Rico

Directory of Open Access Journals (Sweden)

Sandra Brown

2017-03-01

Full Text Available We review the literature that led to clarifying the role of tropical forests in the global carbon cycle from a time when they were considered sources of atmospheric carbon to the time when they were found to be atmospheric carbon sinks. This literature originates from work conducted by US Forest Service scientists in Puerto Rico and their collaborators. It involves the classification of forests by life zones, estimation of carbon density by forest type, assessing carbon storage changes with ecological succession and land use/land cover type, describing the details of the carbon cycle of forests at stand and landscape levels, assessing global land cover by forest type and the complexity of land use change in tropical regions, and assessing the ecological fluxes and storages that contribute to net carbon accumulation in tropical forests. We also review recent work that couples field inventory data, remote sensing technology such as LIDAR, and GIS analysis in order to more accurately determine the role of tropical forests in the global carbon cycle and point out new avenues of carbon research that address the responses of tropical forests to environmental change.

A New Way to Produce Cellobiose Carbonates Using Green Chemistry.

Science.gov (United States)

Khiari, R; Brochier-Salon, M-C; Mhenni, M F; Mauret, E; Belgacem, M N

2016-08-23

The preparation of cellulose derivatives using green (i.e., environmentally friendly) reagents would improve sustainability and reduce concerns arising from the use of non-green reagents. The objective of this work was to prepare cellobiose carbonate using a green reagent, dimethyl carbonate. The carbonation reaction was carried out in the presence of ethanolic potassium hydroxide solution and dimethyl carbonate for 6 h at a range of temperatures (25-70 °C). A cellobiose derivative was successfully prepared with a recovered yield of more than 70 % and characterized by FTIR and NMR spectroscopy techniques. The presence of a grafted disaccharide with a degree of substitution higher than 2 was determined by (13) C NMR analysis. The spectra of the prepared cellobiose carbonate exhibited peaks that were associated with cellulose molecules (C1 -C6 ) and corresponded to carbonate functions at around 159.4 ppm. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Simple electrochemical sensor for caffeine based on carbon and Nafion-modified carbon electrodes.

Science.gov (United States)

Torres, A Carolina; Barsan, Madalina M; Brett, Christopher M A

2014-04-15

A simple, economic, highly sensitive and highly selective method for the detection of caffeine has been developed at bare and Nafion-modified glassy carbon electrodes (GCE). The electrochemical behaviour of caffeine was examined in electrolyte solutions of phosphate buffer saline, sodium perchlorate, and in choline chloride plus oxalic acid, using analytical determinations by fixed potential amperometry, phosphate buffer saline being the best. Modifications of the GCE surface with poly(3,4-ethylenedioxythiophene) (PEDOT), Nafion, and multi-walled carbon nanotubes were tested in order to evaluate possible sensor performance enhancements, Nafion giving the most satisfactory results. The effect of interfering compounds usually found in samples containing caffeine was examined at GCE without and with Nafion coating, to exclude interferences, and the sensors were successfully applied to determine the caffeine content in commercial beverages and drugs. Copyright © 2013 Elsevier Ltd. All rights reserved.

Carbon electrode for desalination purpose in capacitive deionization

International Nuclear Information System (INIS)

Endarko,; Fadilah, Nurul; Anggoro, Diky

2016-01-01

Carbon electrodes for desalination purpose have been successfully synthesized using activated carbon powder (BET surface area=700 – 1400 m 2 /g), carbon black and polyvinyl alcohol (PVA) binder by cross-linking method with glutaric acid (GA) at 120 °C. The electrochemical properties of the carbon electrodes were analyzed using electrical impedance spectroscopy (EIS) and cyclic voltammetry (CV) whilst the physical properties were observed with scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX). In order to assess the desalting performance, salt removal experiments were performed by constructing a capacitive deionization unit cell with five pairs of carbon electrodes. For each pair consisted of two parallel carbon electrodes separated by a spacer. Desalination and regeneration processes were also observed in the salt-removal experiments. The salt-removal experiments were carried out in single-pass mode using a solution with 0.1 M NaCl at a flow rate of 10 mL/min. A voltage of 3 V was applied to the cell for 60 minutes for both processes in desalination and regeneration. The result showed that the percentage value of the salt-removal was achieved at 20%.

Carbon electrode for desalination purpose in capacitive deionization

Energy Technology Data Exchange (ETDEWEB)

Endarko,, E-mail: endarko@physics.its.ac.id; Fadilah, Nurul; Anggoro, Diky [Physics Department, Institut Teknologi Sepuluh Nopember (ITS) Kampus ITS, Sukolilo Surabaya 60111, Jawa Timur (Indonesia)

2016-03-11

Carbon electrodes for desalination purpose have been successfully synthesized using activated carbon powder (BET surface area=700 – 1400 m{sup 2}/g), carbon black and polyvinyl alcohol (PVA) binder by cross-linking method with glutaric acid (GA) at 120 °C. The electrochemical properties of the carbon electrodes were analyzed using electrical impedance spectroscopy (EIS) and cyclic voltammetry (CV) whilst the physical properties were observed with scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX). In order to assess the desalting performance, salt removal experiments were performed by constructing a capacitive deionization unit cell with five pairs of carbon electrodes. For each pair consisted of two parallel carbon electrodes separated by a spacer. Desalination and regeneration processes were also observed in the salt-removal experiments. The salt-removal experiments were carried out in single-pass mode using a solution with 0.1 M NaCl at a flow rate of 10 mL/min. A voltage of 3 V was applied to the cell for 60 minutes for both processes in desalination and regeneration. The result showed that the percentage value of the salt-removal was achieved at 20%.

High rates of carbon storage in old deciduous forests: Emerging mechanisms from the Forest Accelerated Succession ExperimenT (FASET)

Science.gov (United States)

Gough, C. M.; Nave, L. E.; Hardiman, B. S.; Bohrer, G.; Halperin, A.; Maurer, K.; Le Moine, J.; Nadelhoffer, K.; Vogel, C. S.; Curtis, P.; University Of Michigan Biological Station Forest Ecosystem Study (Umbs-Fest) Team

2010-12-01

Deciduous forests of the eastern US are broadly approaching an ecological threshold in which early successional dominant trees are senescing and giving way to later successional species, with unknown consequences for regional carbon (C) cycling. Though recent research demonstrates that forests may accumulate C for centuries, the mechanisms behind sustained rates of C storage in old, particularly deciduous, forests have not been identified. In a regionally representative forest at the University of Michigan Biological Station, we are combining observational and experimental C cycling studies to forecast how forest C storage responds to climate variation, disturbance, and succession. The Forest Accelerated Succession ExperimenT (FASET), in which >6,700 aspen and birch trees (~35 % LAI) were stem girdled within a 39 ha area, is testing the hypothesis that forest production will increase rather than decline with age, due to increases in nitrogen (N) availability, N allocation to the canopy, and the concurrent development of a more biologically and structurally complex canopy. Results thus far support our hypothesis that aging forests in the region may sustain high rates of C storage through shifts in N cycling and increased canopy complexity. Girdling-induced mortality of early successional species reduced soil respiration, accelerated fine root turnover, and prompted the redistribution of N from the foliage of early to later successional species. Nitrogen redistribution increased leaf area index (LAI) production by later successional species, offsetting declines in LAI from senescing early successional species. High rates of net primary production (NPP) were sustained in stands comprising a diverse assemblage of early and later successional species because later successional species, when already present in the canopy, rapidly compensated for declining growth of early successional species. Canopy structural complexity, which increased with forest age, was positively

Highly regenerable carbon-Fe{sub 3}O{sub 4} core–satellite nanospheres as oxygen reduction electrocatalyst and magnetic adsorbent

Energy Technology Data Exchange (ETDEWEB)

Zhou, Wenqiang [Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, and Institute for Advanced Study, Tongji University, Shanghai 201804 (China); School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003 (China); Liu, Minmin; Cai, Chao [Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, and Institute for Advanced Study, Tongji University, Shanghai 201804 (China); Zhou, Haijun, E-mail: zhouhaijun@just.edu.cn [School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003 (China); Liu, Rui, E-mail: ruiliu@tongji.edu.cn [Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, and Institute for Advanced Study, Tongji University, Shanghai 201804 (China)

2017-02-15

We present the synthesis and multifunctional utilization of core-satellite carbon-Fe{sub 3}O{sub 4} nanoparticles to serve as the enabling platform for a range of applications including oxygen reduction reaction (ORR) and magnetic adsorbent. Starting from polydopamine (PDA) nanoparticles and Fe(NO{sub 3}){sub 3}, carbon-Fe{sub 3}O{sub 4} core–satellite nanospheres are synthesized through successive steps of impregnation, ammoniation and carbonization. The synergistic combination of Fe{sub 3}O{sub 4} and N-doped carbon endows the nanocomposite with high electrochemical activity in ORR and mainly four electrons transferred in reaction process. Furthermore, carbon-Fe{sub 3}O{sub 4} nanoparticles used as magnetic adsorbent exhibit the efficient removal of Rhodamine B from an aqueous solution. The recovery and reuse of the adsorbent is demonstrated 5 times without any detectible loss in activity. - Graphical abstract: Starting from polydopamine (PDA) nanoparticles and Fe(NO{sub 3}){sub 3}, carbon-Fe{sub 3}O{sub 4} core–satellite nanospheres are synthesized through successive steps of impregnation, ammoniation and carbonization. The nanocomposites serve as the enabling platform for a range of applications including oxygen reduction reaction (ORR) and magnetic adsorbent. - Highlights: • Carbon-Fe{sub 3}O{sub 4} core–satellite nanospheres are synthesized through successive steps of impregnation, ammoniation and carbonization. • Polydopamine and Fe(NO{sub 3}){sub 3} are precursors for N-doped carbon source and Fe{sub 3}O{sub 4} nanoparticles, respectively. • The nanocomposites exhibit high electrochemical activity in ORR. • The nanocomposites effectively adsorb organic dyes with magnetic recovery and good recycle property.

Enzymatic, urease-mediated mineralization of gellan gum hydrogel with calcium carbonate, magnesium-enriched calcium carbonate and magnesium carbonate for bone regeneration applications.

Science.gov (United States)

Douglas, Timothy E L; Łapa, Agata; Samal, Sangram Keshari; Declercq, Heidi A; Schaubroeck, David; Mendes, Ana C; der Voort, Pascal Van; Dokupil, Agnieszka; Plis, Agnieszka; De Schamphelaere, Karel; Chronakis, Ioannis S; Pamuła, Elżbieta; Skirtach, Andre G

2017-12-01

Mineralization of hydrogel biomaterials is considered desirable to improve their suitability as materials for bone regeneration. Calcium carbonate (CaCO 3 ) has been successfully applied as a bone regeneration material, but hydrogel-CaCO 3 composites have received less attention. Magnesium (Mg) has been used as a component of calcium phosphate biomaterials to stimulate bone-forming cell adhesion and proliferation and bone regeneration in vivo, but its effect as a component of carbonate-based biomaterials remains uninvestigated. In the present study, gellan gum (GG) hydrogels were mineralized enzymatically with CaCO 3 , Mg-enriched CaCO 3 and magnesium carbonate to generate composite biomaterials for bone regeneration. Hydrogels loaded with the enzyme urease were mineralized by incubation in mineralization media containing urea and different ratios of calcium and magnesium ions. Increasing the magnesium concentration decreased mineral crystallinity. At low magnesium concentrations calcite was formed, while at higher concentrations magnesian calcite was formed. Hydromagnesite (Mg 5 (CO 3 ) 4 (OH) 2 .4H 2 O) formed at high magnesium concentration in the absence of calcium. The amount of mineral formed and compressive strength decreased with increasing magnesium concentration in the mineralization medium. The calcium:magnesium elemental ratio in the mineral formed was higher than in the respective mineralization media. Mineralization of hydrogels with calcite or magnesian calcite promoted adhesion and growth of osteoblast-like cells. Hydrogels mineralized with hydromagnesite displayed higher cytotoxicity. In conclusion, enzymatic mineralization of GG hydrogels with CaCO 3 in the form of calcite successfully reinforced hydrogels and promoted osteoblast-like cell adhesion and growth, but magnesium enrichment had no definitive positive effect. Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

Electrochemical pre anodization of glassy carbon electrode and application to determine chloramphenicol

International Nuclear Information System (INIS)

Truc, Nguyen Minh; Mortensen, John; Anh, Nguyen Ba Hoai

2008-01-01

This paper suggested a method to enhance the performance of carbon electrodes for the determination of chloramphenicol (CAP). The sensitivity and the reproducibility of the carbon electrodes could be enhanced easily by electrochemical pretreatment. Some kinds of carbon material were studied including glassy carbon, graphite carbon and pyrolytic carbon. Numerous kinds of supporting electrolyte have been tried. For glassy carbon electrode, the acidic solution, H 2 SO 4 5 mM, resulted in best performance at pretreated voltage of +2.1V (vs. Ag/ AgCl) in duration of 250 second. However, for graphite and pyrolytic carbon electrodes, the phosphate buffer solution pH 6.0 gave the best performance at +1.7V (vs. Ag/ AgCl) in duration of 20 seconds. The detection limit could be at very low concentration of CAP: 0.8 ng/ ml for glassy carbon electrode, 3.5 ng/ ml for graphite carbon electrode. The method was successful applied to aqua-agriculture water sample and milk sample with simple extraction as well as direct ointment sample analysis. (author)

Integrated synthesis of poly(o-phenylenediamine)-derived carbon materials for high performance supercapacitors

Energy Technology Data Exchange (ETDEWEB)

Zhu, Hui; Wang, Xiaolei; Liu, Xuexia; Yang, Xiurong [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 (China)

2012-12-18

Poly(o-phenylenediamine) (POPD)-derived functional carbon materials with excellent capacitive performance are successfully synthesized by means of an integrated one-step process, in which FeCl{sub 3} not only oxidizes the polymerization of the organic monomers but also activates the carbonization. Furthermore, extensive research has proved that this strategy to discover novel carbons is useful not only for capacitors but also for other energy storage/conversion devices. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Integrated synthesis of poly(o-phenylenediamine)-derived carbon materials for high performance supercapacitors.

Science.gov (United States)

Zhu, Hui; Wang, Xiaolei; Liu, Xuexia; Yang, Xiurong

2012-12-18

Poly(o-phenylenediamine) (POPD)-derived functional carbon materials with excellent capacitive performance are successfully synthesized by means of an integrated one-step process, in which FeCl(3) not only oxidizes the polymerization of the organic monomers but also activates the carbonization. Furthermore, extensive research has proved that this strategy to discover novel carbons is useful not only for capacitors but also for other energy storage/conversion devices. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Corrosion of a hot potassium carbonate CO/sub 2/ removal plant

International Nuclear Information System (INIS)

Johnson, J.J.

1987-01-01

After ten years of successful operation, a hot potassium carbonate CO/sub 2/ removal plant experienced severe corrosion to the 2'' (50 mm) thick carbon steel absorber process vessel over a fourteen month period. This corrosive attack resulted in complete penetration on three separate occasions. Although the cause of this corrosion is still uncertain, it appears to be the result of decreasing strength of the vanadium pentoxide inhibitor, due to increasing concentrations of hydrogen sulfide in the feed gas. After extensive research, Chevron believes that stainless steel metallurgy or replacement of the hot potassium carbonate process are the only reliable long-term solutions

Low Carbon and Climate Resilient Investments: Is South Africa ...

African Journals Online (AJOL)

. The aim of this paper is to review South Africa's response to climate change, with a special focus on investments in low carbon and climate resilient action. It highlights the successes to date and the challenges that still have to be addressed.

Synthesis of carbon nanostructures by the pyrolysis of wood sawdust in a tubular reactor

Directory of Open Access Journals (Sweden)

Maria G. Sebag Bernd

2017-04-01

Full Text Available Carbon nanostructures were produced by wood sawdust pyrolysis. The results obtained revealed that the thermodynamic simulations (FactSage were successful to predict the best reaction conditions for the synthesis of carbon, and potentially carbon fibers and nanotubes production. Graphite formation was indicated by XRD study, and by thermal analysis which presented the carbon oxidation range. The morphology of the samples (SEM/TEM analysis showed carbon nanotubes/nanofibers varying in size and thickness, with defects and flaws. The tubular reactor was considered to be an economic and environmental correct way to nanomaterials growing, with the simultaneous generation of hydrogen and lower pollutant gas emissions.

The world's nuclear future - built on material success

Science.gov (United States)

Ion, Sue

2010-07-01

In our energy hungry world of the twenty-first century, the future of electricity generation must meet the twin challenges of security of supply and reduced carbon emissions. The expectations for nuclear power programmes to play a part in delivering success on both counts, grows ever higher. The nuclear industry is poised on a renaissance likely to dwarf the heady days of the 1960s and early 1970s. Global supply chain and project management challenges abound, now just as then. The science and engineering of materials will be key to the successful deployment and operation of a new generation of reactor systems and their associated fuel cycles. Understanding and predicting materials performance will be key to achieving life extension of existing assets and underpinning waste disposal options, as well as giving confidence to the designers, their financial backers and governments across the globe, that the next generation of reactors will deliver their full potential.

Fabrication of carbon microcapsules containing silicon nanoparticles-carbon nanotubes nanocomposite by sol-gel method for anode in lithium ion battery

International Nuclear Information System (INIS)

Bae, Joonwon

2011-01-01

Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT-C) have been fabricated by a surfactant mediated sol-gel method followed by a carbonization process. Silicon nanoparticles-carbon nanotubes (Si-CNT) nanohybrids were produced by a wet-type beadsmill method. To obtain Si-CNT nanocomposites with spherical morphologies, a silica precursor (tetraethylorthosilicate, TEOS) and polymer (PMMA) mixture was employed as a structure-directing medium. Thus the Si-CNT/Silica-Polymer microspheres were prepared by an acid catalyzed sol-gel method. Then a carbon precursor such as polypyrrole (PPy) was incorporated onto the surfaces of pre-existing Si-CNT/silica-polymer to generate Si-CNT/Silica-Polymer-PPy microspheres. Subsequent thermal treatment of the precursor followed by wet etching of silica produced Si-CNT-C microcapsules. The intermediate silica/polymer must disappear during the carbonization and etching process resulting in the formation of an internal free space. The carbon precursor polymer should transform to carbon shell to encapsulate remaining Si-CNT nanocomposites. Therefore, hollow carbon microcapsules containing Si-CNT nanocomposites could be obtained (Si-CNT-C). The successful fabrication was confirmed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). These final materials were employed for anode performance improvement in lithium ion battery. The cyclic performances of these Si-CNT-C microcapsules were measured with a lithium battery half cell tests. - Graphical Abstract: Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT-C) have been fabricated by a surfactant mediated sol-gel method. Highlights: → Polymeric microcapsules containing Si-CNT transformed to carbon microcapsules. → Accommodate volume changes of Si NPs during Li ion charge/discharge. → Sizes of microcapsules were controlled by experimental parameters. �

Synthesis of CNTs via chemical vapor deposition of carbon dioxide as a carbon source in the presence of NiMgO

Energy Technology Data Exchange (ETDEWEB)

Allaedini, Ghazaleh, E-mail: jiny_ghazaleh@yahoo.com [Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, UKM Bangi, Selangor (Malaysia); Tasirin, Siti Masrinda [Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, UKM Bangi, Selangor (Malaysia); Aminayi, Payam [Chemical and Paper Engineering, Western Michigan University, Kalamazoo, MI (United States)

2015-10-25

Carbon nanotubes were synthesized via the chemical vapor deposition (CVD) method, using Ni/MgO as a catalyst and CO{sub 2} as a nontoxic, abundant, and economical carbon source. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM), along with the results from Fourier transform infrared spectroscopy (FT-IR) and Raman spectroscopy, confirmed the successful formation of CNTs. Energy-dispersive X-ray spectroscopy (EDX) was performed to investigate the weight percentage of the present elements in the synthesized powder, and a significant yield of 27.38% was confirmed. The reaction mechanism was discussed, and the role of the carbon source, catalyst support, and presence of H{sub 2} in the reaction environment was elaborated. - Highlights: • CO{sub 2} was used as a nontoxic and economical carbon source for CNT production. • A novel Ni supported MgO has been synthesized and employed in the CVD process. • CNTs were produced with a significant yield of 27.38%.

Direct growth of carbon nanotubes on hydroxyapatite using MPECVD

International Nuclear Information System (INIS)

Duraia, El-Shazly M.; Hannora, A.; Mansurov, Z.; Beall, Gary W.

2012-01-01

Graphical abstract: Carbon nanotubes have been grown directly on hydroxyapatite by using microwave plasma-enhanced chemical vapor deposition (MPECVD). Highlights: ► CNTs have been successfully grown directly on hydroxyapatite using MPECVD. ► Diameter distribution of the CNTs lies in the range from 30 to 70 nm. ► The HA surface is partially transformed to β-TCP during the deposition. ► Grown CNTs have good quality and I G /I D ratio lies between 1.243 and 1.774. - Abstract: For the first time carbon nanotubes (CNTs) have been successfully grown directly on hydroxyapatite (HA) by using microwave plasma enhanced chemical vapor deposition (MPECVD). Such integration has potential to capitalize on the merits of both HA and CNTs. This type of coating could be useful to improve the interface between bone and the implant. Scanning electron microscope SEM investigations show that; the surface of the CNTs is relatively clean and free of amorphous carbon. The CNTs diameters lie in the range 30–70 nm. In addition HA encapsulation by carbon was observed at a growth temperature 750 °C. Raman spectroscopy indicates that the CNTs are of high quality and the I G /I D ratio lies between 1.243 and 1.774. The changes in the X-ray diffraction (XRD) patterns give an indication that during the plasma deposition the HA-substrate surface is subjected to a temperature sufficient for partial conversion to the β-tricalcium phosphate via dehydroxylation.

The NatCarb geoportal: Linking distributed data from the Carbon Sequestration Regional Partnerships

Science.gov (United States)

Carr, T.R.; Rich, P.M.; Bartley, J.D.

2007-01-01

The Department of Energy (DOE) Carbon Sequestration Regional Partnerships are generating the data for a "carbon atlas" of key geospatial data (carbon sources, potential sinks, etc.) required for rapid implementation of carbon sequestration on a broad scale. The NATional CARBon Sequestration Database and Geographic Information System (NatCarb) provides Web-based, nation-wide data access. Distributed computing solutions link partnerships and other publicly accessible repositories of geological, geophysical, natural resource, infrastructure, and environmental data. Data are maintained and enhanced locally, but assembled and accessed through a single geoportal. NatCarb, as a first attempt at a national carbon cyberinfrastructure (NCCI), assembles the data required to address technical and policy challenges of carbon capture and storage. We present a path forward to design and implement a comprehensive and successful NCCI. ?? 2007 The Haworth Press, Inc. All rights reserved.

Amphiphilic carbon dots for sensitive detection, intracellular imaging of Al{sup 3+}

Energy Technology Data Exchange (ETDEWEB)

Kong, Depeng [State Key Laboratory of Separation Membranes and Membrane Processes, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); Yan, Fanyong, E-mail: yanfanyong@tjpu.edu.cn [State Key Laboratory of Separation Membranes and Membrane Processes, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); Luo, Yunmei [Department of Pharmacology/Key Laboratory for Basic Pharmacology of Ministry of Education, Zunyi Medical College, Guizhou 563000 (China); Ye, Qianghua; Zhou, Siyushan [State Key Laboratory of Separation Membranes and Membrane Processes, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); Chen, Li, E-mail: Chenlis@tjpu.edu.cn [State Key Laboratory of Separation Membranes and Membrane Processes, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387 (China)

2017-02-08

In this paper, a simple and effective method was designed to synthesize hydrophobic carbon dots. Subsequently, amphiphilic fluorescent carbon dots (A-CDs) were synthesized by further surface modification. The result A-CDs show excellent optical properties with a quantum yield of 16.9%. It was interestingly found that morin (MR) and its fluorescent metal-ion complex (MR-Al{sup 3+}) can successfully coordinate on the surface of A-CDs, the emission of A-CDs completely overlapped the absorption peak of MR-Al{sup 3+}. Thus, the prepared A-CDs can be used as an effective fluorescent probe for Al{sup 3+} based on a fluorescence resonance energy transfer process. The sensing platform can realize real-time detection of Al{sup 3+} within 0.5 min. The fluorescence signals of the system were linearly correlated with the concentration of Al{sup 3+} over a range of 8–20 μM, with a detection limit of 0.113 μM. The method was also successfully applied to image the distribution of Al{sup 3+} in Human Umbilical Vein Endothelial Cells. - Highlights: • Amphiphilic carbon dots were obtained by simply modifying hydrophobic carbon dots. • Amphiphilic carbon dots/morin-Al{sup 3+} was used as a selective turn-on probe for Al{sup 3+}. • The method was employed to intracellular imaging Al{sup 3+} in living cells.

Ensuring a successful family business management succession

OpenAIRE

Desbois, Joris

2016-01-01

Succession is the biggest long-term challenge that most family businesses face. Indeed, leaders ‘disposition to plan for their succession is frequently the key factor defining whether their family business subsists or stops. The research seeks to find out how to manage successfully the business management succession over main principles. This work project aims at researching the key points relevant to almost all family firms, to have a viable succession transition and positioni...

Synthesis and electrochemical capacitive properties of nitrogen-doped porous carbon micropolyhedra by direct carbonization of zeolitic imidazolate framework-11

Energy Technology Data Exchange (ETDEWEB)

Hao, Fei; Li, Li; Zhang, Xiaohua, E-mail: mickyxie@hnu.edu.cn; Chen, Jinhua, E-mail: chenjinhua@hnu.edu.cn

2015-06-15

Highlights: • Nitrogen-doped porous carbon micropolyhedra (N-PCMPs) were prepared from ZIF-11. • The activated N-PCMPs with fused KOH (N-PCMPs-A) have high specific surface area. • N-PCMPs-A exhibits high specific capacitance. • N-PCMPs-A reveals good cycling performance even at a high current density. - Abstract: Nitrogen-doped porous carbon micropolyhedra (N-PCMPs) were successfully prepared by direct carbonization of ZIF-11 polyhedra and further activated with fused KOH to obtain N-PCMPs-A. The morphology and microstructure of samples were examined by scanning electron microscopy, X-ray diffraction, and micropore and chemisorption analyzer. Electrochemical properties were characterized by cyclic voltammetry and galvanostatic charge/discharge method in 1.0 M H{sub 2}SO{sub 4} aqueous solution on a standard three-electrode system. Results show that, compared with N-PCMPs, N-PCMPs-A has higher specific surface area (2188 m{sup 2} g{sup −1}) and exhibits improved electrochemical capacitive properties (307 F g{sup −1} at 1.0 A g{sup −1}). The mass specific capacitance of N-PCMPs-A is also higher than that of most MOF-derived carbons, some carbide-derived carbons and carbon aerogel-derived carbons. In addition, the capacitance of the N-PCMPs-A retains 90% after 4000 cycles even at a high current density of 10 A g{sup −1}. These imply that N-PCMPs-A is the promising materials for the construction of a high-performance supercapacitor.

Development of a rotating graphite carbon disk stripper

Science.gov (United States)

Hasebe, Hiroo; Okuno, Hiroki; Tatami, Atsushi; Tachibana, Masamitsu; Murakami, Mutsuaki; Kuboki, Hironori; Imao, Hiroshi; Fukunishi, Nobuhisa; Kase, Masayuki; Kamigaito, Osamu

2018-05-01

Highly oriented graphite carbon sheets (GCSs) were successfully used as disk strippers. An irradiation test conducted in 2015 showed that GCS strippers have the longest lifetime and exhibit improved stripping and transmission efficiencies. The problem of disk deformation in previously used Be-disk was solved even with higher beam intensity.

Composition and origin of Early Cambrian Tiantaishan phosphorite-Mn carbonate ores, Shaanxi Province, China

Science.gov (United States)

Hein, J.R.; Fan, D.; Ye, J.; Liu, T.; Yeh, H.-W.

1999-01-01

-ocean waters, and marine transgression. Water depth increased from deposition of the black phyllite sequence through deposition of the Mn mixed-carbonate sequence, then shallowed again during deposition of the overlying dolostone sequence. Bottom waters were mostly dysoxic to suboxic, but fluctuated from oxic to anoxic. Productivity was high during deposition of the black phyllite sequence, increased during precipitation of phosphorite, and then decreased to moderate levels during precipitation of rhodochrostone ores. Biosilica contributions occur in each lithology, but are greatest in rhodochrostone. Changes in sedimentation were determined by changes in water depth, productivity, upwelling, sea-level change, and ventilation of the depositional basin. The source of the phosphorus was organic matter produced in great quantities during deposition of the black phyllite and phosphorite sequences in a zone of coastal upwelling. Organic matter accumulation was rapid. Globally, Mn was supplied by overturn of stagnant, metal-rich deep-ocean waters, which were redistributed to areas of coastal upwelling and seaways; that process may have been initiated by latest Proterozoic glaciations which would have promoted density stratification and accumulation and storage of metals. Regionally, Mn was supplied by terrigenous input into the shallow seaway and hydrothermal input into the deeper water parts of that seaway. Locally, Mn sources included leaching and transport of metals from the sediment column. Manganese was stored locally in low-oxygen (not anoxic) seawater prior to Mn-ore formation. The source of the carbon in the Mn carbonates and dolostones was predominantly seawater bicarbonate and secondarily CO2 derived from the oxidation of organic matter in the bacterially mediated diagenetic zone of sulfate reduction.

Research on Urban Road Congestion Pricing Strategy Considering Carbon Dioxide Emissions

Directory of Open Access Journals (Sweden)

Yitian Wang

2015-08-01

Full Text Available Congestion pricing strategy has been recognized as an effective countermeasure in the practical field of urban traffic congestion mitigation. In this paper, a bi-level programming model considering carbon dioxide emission is proposed to mitigate traffic congestion and reduce carbon dioxide emissions. The objective function of the upper level model is to minimize the sum of travel costs and the carbon dioxide emissions costs. The lower level is a multi-modal transportation network equilibrium model. To solve the model, the method of successive averages (MSA and the shuffled frog leaping algorithm (SFLA are introduced. The proposed method and algorithm are tested through the numerical example. The results show that the proposed congestion pricing strategy can mitigate traffic congestion and reduce carbon emissions effectively.

Immobilised carbon nanotubes as carrier for Co-Fischer-Tropsch synthesis catalysts

Energy Technology Data Exchange (ETDEWEB)

Thiessen, J.; Rose, A.; Kiendl, I.; Jess, A. [Bayreuth Univ. (Germany). Dept. of Chemical Engineering; Curulla-Ferre, D. [Total S.A., Gas and Power, Paris La Defense (France)

2011-07-01

A possibility to immobilise carbon nanotubes (CNT) to make them applicable in a technical scale fixed bed reactor is studied. The approach to fabricate millimetre scale composites containing CNT presented in this work is to confine the nano-carbon in macro porous ceramic particles. Thus CNT were grown on the inner surface of silica and alumina pellets and spheres, respectively. Cobalt nano particles were successfully deposited on the carbon surface inside the two types of ceramic carriers and the systems were tested in Fischer - Tropsch synthesis (FTS). The cobalt mass related activity of these novel catalysts is similar to a conventional system. The selectivities of the Co/CNT/ceramic composites were compared with non supported CNT and carbon nanofibres (CNF). (orig.)

Nitrogen-doped carbon capsules via poly(ionic liquid)-based layer-by-layer assembly.

Science.gov (United States)

Zhao, Qiang; Fellinger, Tim-Patrick; Antonietti, Markus; Yuan, Jiayin

2012-07-13

Layer-by-layer (LbL) assembly technique is applied for the first time for the preparation of nitrogen-doped carbon capsules. This approach uses colloid silica as template and two polymeric deposition components, that is, poly(ammonium acrylate) and a poly (ionic liquid) poly(3-cyanomethyl-1-vinylimidazolium bromide), which acts as both the carbon precursor and nitrogen source. Nitrogen-doped carbon capsules are prepared successfully by polymer wrapping, subsequent carbonization and template removal. The as-synthesized carbon capsules contain ≈7 wt% of nitrogen and have a structured specific surface area of 423 m(2) g(-1). Their application as supercapacitor has been briefly introduced. This work proves that LbL assembly methodology is available for preparing carbon structures of complex morphology. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Highly aligned carbon nanotube arrays fabricated by bias sputtering

International Nuclear Information System (INIS)

Hayashi, Nobuyuki; Honda, Shin-ichi; Tsuji, Keita; Lee, Kuei-Yi; Ikuno, Takashi; Fujimoto, Keiichi; Ohkura, Shigeharu; Katayama, Mitsuhiro; Oura, Kenjiro; Hirao, Takashi

2003-01-01

Vertically aligned carbon nanotube (CNT) arrays have been successfully grown on Si substrates by dc bias sputtering. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations revealed that the resultant arrays consisted of dense CNTs with diameters of 40-60 nm and lengths of 300-400 nm. The CNTs were found to have a bamboo-like structure at the end of which metallic nanoparticle was formed, indicating tip growth mechanism. The energy enhancement of carbon particles is a key factor for synthesis of CNTs using dc bias sputtering system

Benefits of integrated seismic and gravity exploration : an example from Norman Wells, NWT

Energy Technology Data Exchange (ETDEWEB)

Isaac, J.H.; Lawton, D.C. [Calgary Univ., AB (Canada). Dept. of Geology

2003-07-01

The theoretical gravity field was modelled for the following three structural models in the Norman Range, near Normal Wells, Northwest Territories: (1) a low angle thrust fault in the Upper Cambrian Saline River Formation, causing repetition of dense Palaeozoic dolomites and anhydrite, with no involvement of sub-Saline River sediments, (2) a high-angle reverse fault thrusting Proterozoic sediments into the core of the Norman Range, and (3) a vertical block fault model with a ridge of Proterozoic and basement rocks coring the Norman Range, with no horizontal shortening. The modelling was constrained by outcrop data, well data and density measurements. The gravity-derived model was then used to construct a velocity model for depth migration of seismic data which was obtained in an area of carbonate outcrop. The gravity survey was conducted to determine if the Saline River Formation had been tectonically thickened with the core of the Norman Range. Analysis of the two integrated data sets confirms a thin-skinned deformation model for the Norman Range. 5 refs., 6 figs.

"Bricks and mortar" self-assembly approach to graphitic mesoporous carbon nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Fulvio, P. F.; Mayes, R.; Wang, X. Q.; Mahurin, S., M.; Bauer, J. C.; Presser, V.; McDonough, J.; Gogotsi, Y.; Dai, S.

2011-04-20

Mesoporous carbon materials do not have sufficient ordering at the atomic scale to exhibit good electronic conductivity. To date, mesoporous carbons having uniform mesopores and high surface areas have been prepared from partially-graphitizable precursors in the presence of templates. High temperature thermal treatments above 2000 °C, which are usually required to increase conductivity, result in a partial or total collapse of the mesoporous structures and reduced surface areas induced by growth of graphitic domains, limiting their applications in electric double layer capacitors and lithium-ion batteries. In this work, we successfully implemented a “brick-and-mortar” approach to obtain ordered graphitic mesoporous carbon nanocomposites with tunable mesopore sizes below 850 °C without using graphitization catalysts or high temperature thermal treatments. Phenolic resin-based mesoporous carbons act as mortar to highly conductive carbon blacks and carbon onions (bricks). The capacitance and resistivity of final materials can be tailored by changing the mortar to brick ratios.

27.12 MHz plasma generation in supercritical carbon dioxide

International Nuclear Information System (INIS)

Kawashima, Ayato; Toyota, Hiromichi; Nomura, Shinfuku; Takemori, Toshihiko; Mukasa, Shinobu; Maehara, Tsunehiro; Yamashita, Hiroshi

2007-01-01

An experiment was conducted for generating high-frequency plasma in supercritical carbon dioxide; it is expected to have the potential for applications in various types of practical processes. It was successfully generated at 6-20 MPa using electrodes mounted in a supercritical cell with a gap of 1 mm. Emission spectra were then measured to investigate the physical properties of supercritical carbon dioxide plasma. The results indicated that while the emission spectra for carbon dioxide and carbon monoxide could be mainly obtained at a low pressure, the emission spectra for atomic oxygen could be obtained in the supercritical state, which increased with the pressure. The temperature of the plasma in supercritical state was estimated to be approximately 6000-7000 K on the assumption of local thermodynamic equilibrium and the calculation results of thermal equilibrium composition in this state showed the increase of atomic oxygen by the decomposition of CO 2

Reactions of carbon radicals generated by 1,5-transposition of reactive centers

Directory of Open Access Journals (Sweden)

ZIVORAD CEKOVIC

2005-03-01

Full Text Available Radical intermediates can undergo specific reactions, such as intramolecular rearrangements, i.e., the transpositions of radical centers, which are not known in classical ionic organic reactions. 1,5-Transposition of a radical center to a non-activated carbon atom are of great synthetic importance. It can be successfully applied for the introduction of different functional groups (oxygen, nitrogen, sulfur, halogens onto a carbon atom remote from the present functional group. In addition to functionalization of a remote non-activated carbon atom, the formation of new C-C bonds on the d-carbon atom have also been achieved. 1,5-Transposition of the radical centers takes place from alkoxyl, aminyl and carbon radicals to a remote carbon atom. Relocation of the radical centers preferentially involves 1,5-transfer of a hydrogen atom, although migrations of some other groups are known. The reactions of the carbon radical generated by 1,5-relocation of the radical center are presented and their synthetic applications are reviewed.

Fast Conversion of Ionic Liquids and Poly(Ionic Liquid)s into Porous Nitrogen-Doped Carbons in Air.

Science.gov (United States)

Men, Yongjun; Ambrogi, Martina; Han, Baohang; Yuan, Jiayin

2016-04-08

Ionic liquids and poly(ionic liquid)s have been successfully converted into nitrogen-doped porous carbons with tunable surface area up to 1200 m²/g at high temperatures in air. Compared to conventional carbonization process conducted under inert gas to produce nitrogen-doped carbons, the new production method was completed in a rather shorter time without noble gas protection.

Carbon Dioxide Effects Research and Assessment Program. The role of tropical forests on the world carbon cycle

Energy Technology Data Exchange (ETDEWEB)

Brown, S.; Lugo, A. E.; Liegel, B. [eds.

1980-08-01

Tropical forests constitute about half of the world's forest and are characterized by rapid rates of organic matter turnover and high storages of organic matter. Tropical forests are considered to be one of the most significant terrestrial elements in the equation that balances the carbon cycle of the world. As discussed in the paper by Tosi, tropical and subtropical latitudes are more complex in terms of climate and vegetation composition than temperate and boreal latitudes. The implications of the complexity of the tropics and the disregard of this complexity by many scientists is made evident in the paper by Brown and Lugo which shows that biomass estimates for tropical ecosystems have been overestimated by at least 100%. The paper by Brown shows that that rates of succession in the tropics are extremely rapid in terms of the ability of moist and wet forests to accumulate organic matter. Yet, in arid tropical Life Zones succession is slow. This leads to the idea that the question of whether tropical forests are sinks or sources of carbon must be analyzed in relation to Life Zones and to intensities of human activity in these Zones. The paper by Lugo presents conceptual models to illustrate this point and the paper by Tosi shows how land uses in the tropics also correspond to Life Zone characteristics. The ultimate significance of land use to the question of the carbon balance in a large region is addressed in the paper by Detwiler and Hall.

Hot electron-induced electrochemiluminescence at polyetherimide-carbon black-based electrodes

International Nuclear Information System (INIS)

Salminen, Kalle; Grönroos, Päivi; Johansson, Leena-Sisko; Campbell, Joseph; Kulmala, Sakari

2017-01-01

Highlights: • Generation of hydrated electrons at carbon paste electrodes. • Hydrated electrons are able to produce intense chemiluminescence. • Relationship between carbon black content in electrode and HECL studied. • Performance of composite electrodes is similar to aluminum electrodes. • The present electrodes are good alternative for disposable assay cartridges. - Abstract: Various luminophores produce strong electrogenerated chemiluminescence during cathodic pulse polarization of the present insulating film-covered carbon paste electrodes in fully aqueous solutions. First electrodes made of a commercial conductive carbon paste were successfully utilized as working electrodes and their surface was characterized by ESCA. Then custom in-laboratory made improved composite electrodes were manufactured from the same insulating polymer and conducting carbon black particles. The relationship between the amount of carbon present on the composite electrode, in the bulk and on the surface, and the intensity of electrogenerated chemiluminescence was studied further. The overall performance of these composite electrodes makes them viable low-cost replacements for metal/insulator type electrodes such as oxide-coated silicon electrodes.

Insights into chemotaxonomic composition and carbon cycling of phototrophic communities in an artesian sulfur-rich spring (Zodletone, Oklahoma, USA), a possible analog for ancient microbial mat systems.

Science.gov (United States)

Bühring, S I; Sievert, S M; Jonkers, H M; Ertefai, T; Elshahed, M S; Krumholz, L R; Hinrichs, K-U

2011-03-01

Zodletone spring in Oklahoma is a unique environment with high concentrations of dissolved-sulfide (10 mm) and short-chain gaseous alkanes, exhibiting characteristics that are reminiscent of conditions that are thought to have existed in Earth's history, in particular the late Archean and early-to-mid Proterozoic. Here, we present a process-oriented investigation of the microbial community in two distinct mat formations at the spring source, (1) the top of the sediment in the source pool and (2) the purple streamers attached to the side walls. We applied a combination of pigment and lipid biomarker analyses, while functional activities were investigated in terms of oxygen production (microsensor analysis) and carbon utilization ((13)C incorporation experiments). Pigment analysis showed cyanobacterial pigments, in addition to pigments from purple sulfur bacteria (PSB), green sulfur bacteria (GSB) and Chloroflexus-like bacteria (CLB). Analysis of intact polar lipids (IPLs) in the source sediment confirmed the presence of phototrophic organisms via diacylglycerol phospholipids and betaine lipids, whereas glyceroldialkylglyceroltetraether additionally indicated the presence of archaea. No archaeal IPLs were found in the purple streamers, which were strongly dominated by betaine lipids. (13)C-bicarbonate- and -acetate-labeling experiments indicated cyanobacteria as predominant phototrophs in the source sediment, carbon was actively fixed by PSB/CLB/GSB in purple streamers by using near infrared light. Despite the presence of cyanobacteria, no oxygen could be detected in the presence of light, suggesting anoxygenic photosynthesis as the major metabolic process at this site. Our investigations furthermore indicated photoheterotrophy as an important process in both habitats. We obtained insights into a syntrophically operating phototrophic community in an ecosystem that bears resemblance to early Earth conditions, where cyanobacteria constitute an important contributor to

Peptide aptamer-assisted immobilization of green fluorescent protein for creating biomolecule-complexed carbon nanotube device

Science.gov (United States)

Nii, Daisuke; Nozawa, Yosuke; Miyachi, Mariko; Yamanoi, Yoshinori; Nishihara, Hiroshi; Tomo, Tatsuya; Shimada, Yuichiro

2017-10-01

Carbon nanotubes are a novel material for next-generation applications. In this study, we generated carbon nanotube and green fluorescent protein (GFP) conjugates using affinity binding peptides. The carbon nanotube-binding motif was introduced into the N-terminus of the GFP through molecular biology methods. Multiple GFPs were successfully aligned on a single-walled carbon nanotube via the molecular recognition function of the peptide aptamer, which was confirmed through transmission electron microscopy and optical analysis. Fluorescence spectral analysis results also suggested that the carbon nanotube-GFP complex was autonomously formed with orientation and without causing protein denaturation during immobilization. This simple process has a widespread potential for fabricating carbon nanotube-biomolecule hybrid devices.

Carbon foam/hydroxyapatite coating for carbon/carbon composites: Microstructure and biocompatibility

Energy Technology Data Exchange (ETDEWEB)

Zhang, Leilei, E-mail: zhangleilei1121@aliyun.com; Li, Hejun; Li, Kezhi; Zhang, Shouyang; Lu, Jinhua; Li, Wei; Cao, Sheng; Wang, Bin

2013-12-01

To improve the surface biocompatibility of carbon/carbon composites, a carbon foam/hydroxyapatite coating was applied using a combination method of slurry procedure and ultrasound-assisted electrochemical deposition procedure. The morphology, microstructure and chemical composition of the coating were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray diffraction. The biocompatibility of the carbon foam/hydroxyapatite coating was investigated by osteoblast-like MG63 cell culture tests. The results showed that the carbon foam could provide a large number of pores on the surface of carbon/carbon composites. The hydroxyapatite crystals could infiltrate into the pores and form the carbon foam/hydroxyapatite coating. The coating covered the carbon/carbon composites fully and uniformly with slice morphology. The cell response tests showed that the MG63 cells on carbon foam/hydroxyapatite coating had a better cell adhesion and cell proliferation than those on uncoated carbon/carbon composites. The carbon foam/hydroxyapatite coatings were cytocompatible and were beneficial to improve the biocompatibility. The approach presented here may be exploited for fabrication of carbon/carbon composite implant surfaces.

Carbon foam/hydroxyapatite coating for carbon/carbon composites: Microstructure and biocompatibility

International Nuclear Information System (INIS)

Zhang, Leilei; Li, Hejun; Li, Kezhi; Zhang, Shouyang; Lu, Jinhua; Li, Wei; Cao, Sheng; Wang, Bin

2013-01-01

To improve the surface biocompatibility of carbon/carbon composites, a carbon foam/hydroxyapatite coating was applied using a combination method of slurry procedure and ultrasound-assisted electrochemical deposition procedure. The morphology, microstructure and chemical composition of the coating were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray diffraction. The biocompatibility of the carbon foam/hydroxyapatite coating was investigated by osteoblast-like MG63 cell culture tests. The results showed that the carbon foam could provide a large number of pores on the surface of carbon/carbon composites. The hydroxyapatite crystals could infiltrate into the pores and form the carbon foam/hydroxyapatite coating. The coating covered the carbon/carbon composites fully and uniformly with slice morphology. The cell response tests showed that the MG63 cells on carbon foam/hydroxyapatite coating had a better cell adhesion and cell proliferation than those on uncoated carbon/carbon composites. The carbon foam/hydroxyapatite coatings were cytocompatible and were beneficial to improve the biocompatibility. The approach presented here may be exploited for fabrication of carbon/carbon composite implant surfaces.

Voltammetric determination of bisphenol A in food package by a glassy carbon electrode modified with carboxylated multi-walled carbon nanotubes

International Nuclear Information System (INIS)

Li, J.; Kuang, D.; Feng, Y.; Zhang, F.; Liu, M.

2011-01-01

A highly sensitive and mercury-free method for determination of bisphenol A (BPA) was established using a glassy carbon electrode that was modified with carboxylated multi-walled carbon nanotubes. A sensitive oxidation peak is found at 550 mV in linear sweep voltammograms at pH 7. Based on this finding, trace levels of bisphenol A can be determined over a concentration range that is linear from 10 nM to 104 nM, the correlation coefficient being 0.9983, and the detection limit (S/N = 3) being 5.0 nM. The method was successfully applied to the determination of BPA in food package. (author)

Gold-bearing fluvial and associated tidal marine sediments of Proterozoic age in the Mporokoso Basin, northern Zambia

Science.gov (United States)

Andrews-Speed, C. P.

1986-07-01

episodic. These features are characteristic of other Proterozoic fluvial sequences. There are no distinctly channelised fluvial conglomerates nor angular unconformities within the fluvial sequence, both of which would have been potential sites for economic gold concentrations. Reworking of the fluvial sands during the marine transgression may have concentrated gold locally within the marine sandstones.

Soil-Carbon Measurement System Based on Inelastic Neutron Scattering

International Nuclear Information System (INIS)

Orion, I.; Wielopolski, L.

2002-01-01

Increase in the atmospheric CO 2 is associated with concurrent increase in the amount of carbon sequestered in the soil. For better understanding of the carbon cycle it is imperative to establish a better and extensive database of the carbon concentrations in various soil types, in order to develop improved models for changes in the global climate. Non-invasive soil carbon measurement is based on Inelastic Neutron Scattering (INS). This method has been used successfully to measure total body carbon in human beings. The system consists of a pulsed neutron generator that is based on D-T reaction, which produces 14 MeV neutrons, a neutron flux monitoring detector and a couple of large NaI(Tl), 6'' diameter by 6'' high, spectrometers [4]. The threshold energy for INS reaction in carbon is 4.8 MeV. Following INS of 14 MeV neutrons in carbon 4.44 MeV photons are emitted and counted during a gate pulse period of 10 μsec. The repetition rate of the neutron generator is 104 pulses per sec. The gamma spectra are acquired only during the neutron generator gate pulses. The INS method for soil carbon content measurements provides a non-destructive, non-invasive tool, which can be optimized in order to develop a system for in field measurements

Soil Microbial Community Structure Evolution along Halophyte Succession in Bohai Bay Wetland

Directory of Open Access Journals (Sweden)

Mingyang Cong

2014-01-01

Full Text Available It is urgent to recover Bohai Bay costal wetland ecosystem because of covering a large area of severe saline-alkali soil. To explore the relationship between halophyte herbaceous succession and microbial community structure, we chose four local communities which played an important role in improving soil microenvironment. We performed phospholipid fatty acid analysis, measured soil parameters, and evaluated shifts of microbial community structure. Results showed that microbial community structure changed significantly along succession and bacteria community was dominant. Total phospholipid fatty acid content increased in different successional stages but decreased with depth, with similar variations in bacterial and fungal biomass. Soil organic carbon and especially total nitrogen were positively correlated with microbial biomass. Colonization of pioneering salt-tolerant plants Suaeda glauca in saline-alkali bare land changed total soil microorganism content and composition. These results showed that belowground processes were strongly related with aboveground halophyte succession. Fungal/bacterial ratio, Gram-negative/Gram-positive bacteria ratio, total microbial biomass, and fungi and bacteria content could indicate the degree of succession stages in Bohai Bay wetland ecosystem. And also these findings demonstrated that microbial community biomass and composition evolved along with vegetation succession environmental variables.

Latest Permian carbonate carbon isotope variability traces heterogeneous organic carbon accumulation and authigenic carbonate formation

Science.gov (United States)

Schobben, Martin; van de Velde, Sebastiaan; Gliwa, Jana; Leda, Lucyna; Korn, Dieter; Struck, Ulrich; Vinzenz Ullmann, Clemens; Hairapetian, Vachik; Ghaderi, Abbas; Korte, Christoph; Newton, Robert J.; Poulton, Simon W.; Wignall, Paul B.

2017-11-01

Bulk-carbonate carbon isotope ratios are a widely applied proxy for investigating the ancient biogeochemical carbon cycle. Temporal carbon isotope trends serve as a prime stratigraphic tool, with the inherent assumption that bulk micritic carbonate rock is a faithful geochemical recorder of the isotopic composition of seawater dissolved inorganic carbon. However, bulk-carbonate rock is also prone to incorporate diagenetic signals. The aim of the present study is to disentangle primary trends from diagenetic signals in carbon isotope records which traverse the Permian-Triassic boundary in the marine carbonate-bearing sequences of Iran and South China. By pooling newly produced and published carbon isotope data, we confirm that a global first-order trend towards depleted values exists. However, a large amount of scatter is superimposed on this geochemical record. In addition, we observe a temporal trend in the amplitude of this residual δ13C variability, which is reproducible for the two studied regions. We suggest that (sub-)sea-floor microbial communities and their control on calcite nucleation and ambient porewater dissolved inorganic carbon δ13C pose a viable mechanism to induce bulk-rock δ13C variability. Numerical model calculations highlight that early diagenetic carbonate rock stabilization and linked carbon isotope alteration can be controlled by organic matter supply and subsequent microbial remineralization. A major biotic decline among Late Permian bottom-dwelling organisms facilitated a spatial increase in heterogeneous organic carbon accumulation. Combined with low marine sulfate, this resulted in varying degrees of carbon isotope overprinting. A simulated time series suggests that a 50 % increase in the spatial scatter of organic carbon relative to the average, in addition to an imposed increase in the likelihood of sampling cements formed by microbial calcite nucleation to 1 out of 10 samples, is sufficient to induce the observed signal of carbon

Latest Permian carbonate carbon isotope variability traces heterogeneous organic carbon accumulation and authigenic carbonate formation

Directory of Open Access Journals (Sweden)

M. Schobben

2017-11-01

Full Text Available Bulk-carbonate carbon isotope ratios are a widely applied proxy for investigating the ancient biogeochemical carbon cycle. Temporal carbon isotope trends serve as a prime stratigraphic tool, with the inherent assumption that bulk micritic carbonate rock is a faithful geochemical recorder of the isotopic composition of seawater dissolved inorganic carbon. However, bulk-carbonate rock is also prone to incorporate diagenetic signals. The aim of the present study is to disentangle primary trends from diagenetic signals in carbon isotope records which traverse the Permian–Triassic boundary in the marine carbonate-bearing sequences of Iran and South China. By pooling newly produced and published carbon isotope data, we confirm that a global first-order trend towards depleted values exists. However, a large amount of scatter is superimposed on this geochemical record. In addition, we observe a temporal trend in the amplitude of this residual δ13C variability, which is reproducible for the two studied regions. We suggest that (sub-sea-floor microbial communities and their control on calcite nucleation and ambient porewater dissolved inorganic carbon δ13C pose a viable mechanism to induce bulk-rock δ13C variability. Numerical model calculations highlight that early diagenetic carbonate rock stabilization and linked carbon isotope alteration can be controlled by organic matter supply and subsequent microbial remineralization. A major biotic decline among Late Permian bottom-dwelling organisms facilitated a spatial increase in heterogeneous organic carbon accumulation. Combined with low marine sulfate, this resulted in varying degrees of carbon isotope overprinting. A simulated time series suggests that a 50 % increase in the spatial scatter of organic carbon relative to the average, in addition to an imposed increase in the likelihood of sampling cements formed by microbial calcite nucleation to 1 out of 10 samples, is sufficient to induce the

Surface structure and adsorption properties of ultrafine porous carbon fibers

International Nuclear Information System (INIS)

Song Xiaofeng; Wang Ce; Zhang Dejiang

2009-01-01

Ultrafine porous carbon fibers (UPCFs) were successfully synthesized by chemical activation of electrospun polyacrylonitrile fibers. In the current approach, potassium hydroxide was adopted as activation reagent. UPCFs were systematically evaluated by scanning electron microscope and nitrogen adsorption. The mass ratio of potassium hydroxide to preoxidized fibers, activation temperature and activation time are crucial for producing high quality UPCFs. The relationships between porous structure and process parameters are explored. UPCFs were applied as adsorbent for nitrogen monoxide to be compared with commercial porous carbon fibers.

SiCO-doped carbon fibers with unique dual superhydrophilicity/superoleophilicity and ductile and capacitance properties.

Science.gov (United States)

Lu, Ping; Huang, Qing; Mukherjee, Amiya; Hsieh, You-Lo

2010-12-01

Silicon oxycarbide (SiCO) glass-doped carbon fibers with an average diameter of 163 nm were successfully synthesized by electrospinning polymer mixtures of preceramic precursor polyureasilazane (PUS) and carbon precursor polyacrylonitrile (PAN) into fibers then converting to ceramic/carbon hybrid via cross-linking, stabilization, and pyrolysis at temperatures up to 1000 °C. The transformation of PUS/PAN polymer precursors to SiCO/carbon structures was confirmed by EDS and FTIR. Both carbon and SiCO/carbon fibers were amorphous and slightly oxidized. Doping with SiCO enhanced the thermal stability of carbon fibers and acquired new ductile behavior in the SiCO/carbon fibers with significantly improved flexibility and breaking elongation. Furthermore, the SiCO/carbon fibers exhibited dual superhydrophilicity and superoleophilicity with water and decane absorbing capacities of 873 and 608%, respectively. The cyclic voltammetry also showed that SiCO/carbon composite fibers possess better capacitor properties than carbon fibers.

Soil and biomass carbon re-accumulation after landslide disturbances

Science.gov (United States)

Schomakers, Jasmin; Jien, Shih-Hao; Lee, Tsung-Yu; Huang-Chuan, Jr.; Hseu, Zeng-Yei; Lin, Zan Liang; Lee, Li-Chin; Hein, Thomas; Mentler, Axel; Zehetner, Franz

2017-07-01

In high-standing islands of the Western Pacific, typhoon-triggered landslides occasionally strip parts of the landscape of its vegetative cover and soil layer and export large amounts of biomass and soil organic carbon (OC) from land to the ocean. After such disturbances, new vegetation colonizes the landslide scars and OC starts to re-accumulate. In the subtropical mountains of Taiwan and in other parts of the world, bamboo (Bambusoideae) species may invade at a certain point in the succession of recovering landslide scars. Bamboo has a high potential for carbon sequestration because of its fast growth and dense rooting system. However, it is still largely unknown how these properties translate into soil OC re-accumulation rates after landslide disturbance. In this study, a chronosequence was established on four former landslide scars in the Central Mountain Range of Taiwan, ranging in age from 6 to 41 years post disturbance as determined by landslide mapping from remote sensing. The younger landslide scars were colonized by Miscanthus floridulus, while after approx. 15 to 20 years of succession, bamboo species (Phyllostachys) were dominating. Biomass and soil OC stocks were measured on the recovering landslide scars and compared to an undisturbed Cryptomeria japonica forest stand in the area. After initially slow re-vegetation, biomass carbon accumulated in Miscanthus stands with mean annual accretion rates of 2 ± 0.5 Mg C ha- 1 yr- 1. Biomass carbon continued to increase after bamboo invasion and reached 40% of that in the reference forest site after 41 years of landslide recovery. Soil OC accumulation rates were 2.0 Mg C ha- 1 yr- 1, 6 to 41 years post disturbance reaching 64% of the level in the reference forest. Our results from this in-situ study suggest that recovering landslide scars are strong carbon sinks once an initial lag period of vegetation re-establishment is overcome.

Water-Dispersible Multi-Walled Carbon Nanotubes and Novel Hybrid Nanostructures

NARCIS (Netherlands)

Pham, Tuan Anh; Son, Se Mo; Jeong, Yeon Tae

2010-01-01

Water-dispersible multi-walled carbon nanotubes (MWNTs) were successfully prepared by the chemical grafting of acylated MWNTs with adenosine. The MWNTs were first purified and oxidized in order to obtain carboxylic acid funcionalized MWNTs, which was further acylated with thionyl chloride to give

Quantifying the variability of potential black carbon transport from cropland burning in Russia driven by atmospheric blocking events

Science.gov (United States)

Hall, Joanne; Loboda, Tatiana

2018-05-01

The deposition of short-lived aerosols and pollutants on snow above the Arctic Circle transported from northern mid-latitudes have amplified the short term warming in the Arctic region. Specifically, black carbon has received a great deal of attention due to its absorptive efficiency and its fairly complex influence on the climate. Cropland burning in Russia is a large contributor to the black carbon emissions deposited directly onto the snow in the Arctic region during the spring when the impact on the snow/ice albedo is at its highest. In this study, our focus is on identifying a possible atmospheric pattern that may enhance the transport of black carbon emissions from cropland burning in Russia to the snow-covered Arctic. Specifically, atmospheric blocking events are large-scale patterns in the atmospheric pressure field that are nearly stationary and act to block migratory cyclones. The persistent low-level wind patterns associated with these mid-latitude weather patterns are likely to accelerate potential transport and increase the success of transport of black carbon emissions to the snow-covered Arctic during the spring. Our results revealed that overall, in March, the transport time of hypothetical black carbon emissions from Russian cropland burning to the Arctic snow is shorter (in some areas over 50 hours less at higher injection heights) and the success rate is also much higher (in some areas up to 100% more successful) during atmospheric blocking conditions as compared to conditions without an atmospheric blocking event. The enhanced transport of black carbon has important implications for the efficacy of deposited black carbon. Therefore, understanding these relationships could lead to possible mitigation strategies for reducing the impact of deposition of black carbon from crop residue burning in the Arctic.

Fire and Microtopography in Peatlands: Feedbacks and Carbon Dynamics

Science.gov (United States)

Benscoter, B.; Turetsky, M. R.

2011-12-01

Fire is the dominant natural disturbance in peatland ecosystems. Over the past decade, peat fires have emerged as an important issue for global climate change, human health, and economic loss, largely due to the extreme peat fire events in Indonesia and Russia that severely impacted metropolitan areas and social infrastructure. However, the impact and importance of fire in peatland ecosystems are more far-reaching. Combustion of vegetation and soil organic matter releases an average of 2.2 kg C m-2 to the atmosphere, primarily as CO2, as well as a number of potentially harmful emissions such as fine particulate matter and mercury. Additionally, while peatlands are generally considered to be net sinks of atmospheric carbon, the removal of living vegetation by combustion halts primary production following fire resulting in a net loss of ecosystem carbon to the atmosphere for several years. The recovery of carbon sink function is linked to plant community succession and development, which can vary based on combustion severity and the resulting post-fire microhabitat conditions. Microtopography has a strong influence on fire behavior and combustion severity during peatland wildfires. In boreal continental peatlands, combustion severity is typically greatest in low-lying hollows while raised hummocks are often lightly burned or unburned. The cross-scale influence of microtopography on landscape fire behavior is due to differences in plant community composition between microforms. The physiological and ecohydrological differences among plant communities result in spatial patterns in fuel availability and condition, influencing the spread, severity, and type of combustion over local to landscape scales. In addition to heterogeneous combustion loss of soil carbon, this differential fire behavior creates variability in post-fire microhabitat conditions, resulting in differences in post-fire vegetation succession and carbon exchange trajectories. These immediate and legacy

Radiation damage to multi-walled carbon nanotubes and their ...

Indian Academy of Sciences (India)

Since their discovery in 1991 by Iijima, carbon nanotubes (CNTs) have been of great interest, both from a fundamental point of view and for future applications. As recent experimental and theoretical studies demonstrate, irradiation of CNTs with energetic particles can successfully be used for nano-engineering, e.g., ...

Direct growth of carbon nanotubes on hydroxyapatite using MPECVD

Energy Technology Data Exchange (ETDEWEB)

Duraia, El-Shazly M., E-mail: duraia_physics@yahoo.com [Suez Canal University, Faculty of Science, Physics Department, Ismailia (Egypt); Al-Farbi Kazakh National University, Almaty (Kazakhstan); Institute of Physics and Technology, Almaty (Kazakhstan); Texas State University-San Marcos, Department of Chemistry and Biochemistry, 601 University Dr., San Marcos, TX 78666 (United States); Hannora, A. [Suez Canal University, Faculty of Petroleum and Mining Engineering (Egypt); Mansurov, Z. [Al-Farbi Kazakh National University, Almaty (Kazakhstan); Beall, Gary W. [Texas State University-San Marcos, Department of Chemistry and Biochemistry, 601 University Dr., San Marcos, TX 78666 (United States)

2012-01-16

Graphical abstract: Carbon nanotubes have been grown directly on hydroxyapatite by using microwave plasma-enhanced chemical vapor deposition (MPECVD). Highlights: Black-Right-Pointing-Pointer CNTs have been successfully grown directly on hydroxyapatite using MPECVD. Black-Right-Pointing-Pointer Diameter distribution of the CNTs lies in the range from 30 to 70 nm. Black-Right-Pointing-Pointer The HA surface is partially transformed to {beta}-TCP during the deposition. Black-Right-Pointing-Pointer Grown CNTs have good quality and I{sub G}/I{sub D} ratio lies between 1.243 and 1.774. - Abstract: For the first time carbon nanotubes (CNTs) have been successfully grown directly on hydroxyapatite (HA) by using microwave plasma enhanced chemical vapor deposition (MPECVD). Such integration has potential to capitalize on the merits of both HA and CNTs. This type of coating could be useful to improve the interface between bone and the implant. Scanning electron microscope SEM investigations show that; the surface of the CNTs is relatively clean and free of amorphous carbon. The CNTs diameters lie in the range 30-70 nm. In addition HA encapsulation by carbon was observed at a growth temperature 750 Degree-Sign C. Raman spectroscopy indicates that the CNTs are of high quality and the I{sub G}/I{sub D} ratio lies between 1.243 and 1.774. The changes in the X-ray diffraction (XRD) patterns give an indication that during the plasma deposition the HA-substrate surface is subjected to a temperature sufficient for partial conversion to the {beta}-tricalcium phosphate via dehydroxylation.

Experimental studies of low salinity water flooding in carbonate reservoirs: A new promising approach

DEFF Research Database (Denmark)

Zahid, Adeel; Shapiro, Alexander; Skauge, Arne

2012-01-01

Low salinity water flooding is well studied for sandstone reservoirs, both laboratory and field tests have showed improvement in the oil recovery in many cases. Up to very recently, the low salinity effect has been indeterminated for carbonates. Most recently, Saudi Aramco reported that substantial...... additional oil recovery can be achieved when successively flooding composite carbonate core plugs with various diluted versions of seawater. The experimental data on carbonates is very limited, so more data and better understanding of the mechanisms involved is needed to utilize this method for carbonate...... reservoirs. In this paper, we have experimentally investigated the oil recovery potential of low salinity water flooding for carbonate rocks. We used both reservoir carbonate and outcrop chalk core plugs. The flooding experiments were carried out initially with the seawater, and afterwards additional oil...

Active carbon production from modified asphalt

International Nuclear Information System (INIS)

Fadhi, A.B.

2006-01-01

A granular activated carbons (GACs) have been prepared from some local raw materials such as Qiayarah asphalt (QA) after some modification treatments of this asphalt by various ratios of its original constituents (asphaltenes and maltens) at 180 degree C. Thermal carbonization method by sulfur and steam physical activation have been used for AC preparation. The carbons thus prepared were characterized in the term of iodine, methylene blue (MB), P-nitro phenol (PNP) and CCl4 adsorption. The BET surface area of the prepared ACs has been estimated via a calibration curve between iodine numbers and surface area determined from N2 adsorption isotherm from previous studies, also, the surface area of the prepared ACs were determined through another methods such as retention method by ethylene glycol mono ethyl ether (EGME), adsorption from vapor phase using acetone vapor and adsorption from solution method using PNP and MB as solutes. The results referred to the success of modification method for preparing ACs of good micro porosity as compared with the AC from the untreated asphalt as well as the commercial sample. (author)

Advances in carbonate exploration and reservoir analysis

Science.gov (United States)

Garland, J.; Neilson, J.; Laubach, S.E.; Whidden, Katherine J.

2012-01-01

The development of innovative techniques and concepts, and the emergence of new plays in carbonate rocks are creating a resurgence of oil and gas discoveries worldwide. The maturity of a basin and the application of exploration concepts have a fundamental influence on exploration strategies. Exploration success often occurs in underexplored basins by applying existing established geological concepts. This approach is commonly undertaken when new basins ‘open up’ owing to previous political upheavals. The strategy of using new techniques in a proven mature area is particularly appropriate when dealing with unconventional resources (heavy oil, bitumen, stranded gas), while the application of new play concepts (such as lacustrine carbonates) to new areas (i.e. ultra-deep South Atlantic basins) epitomizes frontier exploration. Many low-matrix-porosity hydrocarbon reservoirs are productive because permeability is controlled by fractures and faults. Understanding basic fracture properties is critical in reducing geological risk and therefore reducing well costs and increasing well recovery. The advent of resource plays in carbonate rocks, and the long-standing recognition of naturally fractured carbonate reservoirs means that new fracture and fault analysis and prediction techniques and concepts are essential.

Criteria for uranium occurrences in Saskatchewan and Australia as guides to favorability for similar deposits in the United States

International Nuclear Information System (INIS)

Kalliokoski, J.; Langford, F.F.; Ojakangas, R.W.

1978-07-01

The objective of this study was to explain the occurrence of the large uranium deposits that have been found in northern Saskatchewan and the Northern Territory of Australia, to provide criteria to evaluate the favorability of Proterozoic rocks in the United States for similar deposits. All of these deposits belong to the class known as the Proterozoic unconformity-type pitchblende deposits. Chapters are devoted to: uranium deposits in Saskatchewan; uranium deposits of the Darwin and Arnhem Land area, Northern Territory of Australia; model for the Proterozoic unconformity-type pitchblende deposits; and evaluation of the geology of selected states for its favorability for Proterozoic unconformity-type pitchblende deposits

Quasi-steady carbon plasma source for neutral beam injector

International Nuclear Information System (INIS)

Koguchi, H.; Sakakita, H.; Kiyama, S.; Shimada, T.; Sato, Y.; Hirano, Y.

2014-01-01

Carbon plasma is successfully sustained during 1000 s without any carrier gas in the bucket type ionization chamber with cusp magnetic field. Every several seconds, seed plasmas having ∼3 ms duration time are injected into the ionization chamber by a shunting arch plasma gun. The weakly ionized carbon plasma ejected from the shunting arch is also ionized by 2.45 GHz microwave at the electron cyclotron resonance surface and the plasma can be sustained even in the interval of gun discharges. Control of the gun discharge interval allows to keep high pressure and to sustain the plasma for long duration

Quasi-steady carbon plasma source for neutral beam injector.

Science.gov (United States)

Koguchi, H; Sakakita, H; Kiyama, S; Shimada, T; Sato, Y; Hirano, Y

2014-02-01

Carbon plasma is successfully sustained during 1000 s without any carrier gas in the bucket type ionization chamber with cusp magnetic field. Every several seconds, seed plasmas having ∼3 ms duration time are injected into the ionization chamber by a shunting arch plasma gun. The weakly ionized carbon plasma ejected from the shunting arch is also ionized by 2.45 GHz microwave at the electron cyclotron resonance surface and the plasma can be sustained even in the interval of gun discharges. Control of the gun discharge interval allows to keep high pressure and to sustain the plasma for long duration.

Soil color indicates carbon and wetlands: developing a color-proxy for soil organic carbon and wetland boundaries on sandy coastal plains in South Africa.

Science.gov (United States)

Pretorius, M L; Van Huyssteen, C W; Brown, L R

2017-10-13

A relationship between soil organic carbon and soil color is acknowledged-albeit not a direct one. Since heightened carbon contents can be an indicator of wetlands, a quantifiable relationship between color and carbon might assist in determining wetland boundaries by rapid, field-based appraisal. The overarching aim of this initial study was to determine the potential of top soil color to indicate soil organic carbon, and by extension wetland boundaries, on a sandy coastal plain in South Africa. Data were collected from four wetland types in northern KwaZulu-Natal in South Africa. Soil samples were taken to a depth of 300 mm in three transects in each wetland type and analyzed for soil organic carbon. The matrix color was described using a Munsell soil color chart. Various color indices were correlated with soil organic carbon. The relationship between color and carbon were further elucidated using segmented quantile regression. This showed that potentially maximal carbon contents will occur at values of low color indices, and predictably minimal carbon contents will occur at values of low or high color indices. Threshold values can thus be used to make deductions such as "when the sum of dry and wet Value and Chroma values is 9 or more, carbon content will be 4.79% and less." These threshold values can then be used to differentiate between wetland and non-wetland sites with a 70 to 100% certainty. This study successfully developed a quantifiable correlation between color and carbon and showed that wetland boundaries can be determined based thereon.

Application of FIB technique to introduction of a notch into a carbon fiber for direct measurement of fracture toughness

International Nuclear Information System (INIS)

Ogihara, S; Imafuku, Y; Yamamoto, R; Kogo, Y

2009-01-01

For the direct measurement of the fracture toughness of the carbon fiber, a new technique was proposed and examined its applicability. At first, machining condition of the notch was examined. The notch was introduced using focused ion beam (FIB). The ion beam can be electronically scanned to introduce a sharp notch on the carbon fiber. Notches with various notch width and length were introduced by changing beam and scanning conditions. Tensile tests on notched carbon fibers were carried out following the test method for carbon fiber monofilaments. Fractured specimens were successfully corrected without secondary damage using protection films. SEM observations revealed that a crack propagated from a notch-tip, and notch size was able to be determined successfully. Effect of notch root radius was also examined to investigate the validity of the fracture toughness obtained by this method.

Biological regeneration of humic acid-loaded partially exhausted activated carbon (down flow system)

International Nuclear Information System (INIS)

Durrani, M.A.Q.J.; Martin, R.J.; Khaliq, F.

1995-01-01

This paper represents the report on the biological regeneration of partially exhausted (down flow) activated carbon following the experimental studies carried out at the university of Birmingham, UK. The Research investigated the extent of bio regeneration of humic acid of concentration 100 mg/l. Bio regeneration in the partial exhaustion system (down flow) was evaluated in terms of substrate removal. Bacterial counts in the effluents of regenerated GAC columns were significantly more than those of fresh carbon effluents. The regeneration performance of the bio regeneration, partially exhausted (with humic acid) carbon increased during initial cycles, later on, it deteriorated significantly with each successive regeneration cycle. Microbial fouling of the carbon, especially at the bottom of the carbon bed was found to produce a substantial deterioration of the bio regeneration performance. (author)

Carbon Isotope Chemostratigraphy, the Baby and the Bathwater

Science.gov (United States)

Arthur, M. A.

2008-12-01

Secular variations in the carbon isotopic values of carbonate sediments and rocks and their individual components have been applied successfully to problems of stratigraphic correlation and for interpretation of past changes in the global carbon cycle. However, this methodology is not without problems. A major tenet of stable isotope chemostratigraphy involves sampling and analyzing multiple, widely separated sequences, and, if possible, multiple carbon-bearing components (e.g., carbonate and organic carbon) in order to demonstrate a global signal. In some cases, this methodology has been short-circuited in the zeal to reveal a new event or excursion, particularly for time intervals for which adequate sequences are somewhat rare. Likewise, although most carbonate researchers are quite aware of the possible importance of diagenesis, particularly in organic-carbon rich sequences or in shoal-water carbonate sequences with longer-term subaerial exposure events, such overprints commonly go unrecognized or are considered of minor impact. Studies of stable isotope variations in carbonate sequences should always employ textural and geochemical methodologies for detecting and even quantifying diagenesis, if possible. Although some diagenetically overprinted or misinterpreted geochemical data have undoubtedly appeared in the literature, there are many excellent examples of global carbon isotope variations in records expressed in pelagic biogenic carbonate, marine organic carbon, platform carbonates, and terrestrial organic matter. Arguably, one of the best-documented examples is the Cenomanian-Turonian (ca. 93 Ma) positive carbon isotope excursion. The amplitude of the Cenomanian-Turonian carbon isotope excursion is similar among all types of records, but there are subtle pattern differences that arise from differences in sedimentation rate among and within sequences. Organic carbon and carbonate carbon isotope signals also may differ in phasing and amplitude for certain

Temperate forest dynamics and carbon storage: A 26-year case ...

African Journals Online (AJOL)

Overall, these results suggest that the forest is in a post-disturbance recovery phase, although favourable climatic conditions over the last three decades may also have had an influence on AGB accumulation. Keywords: aboveground biomass, carbon sequestration, forest conservation, long-term monitoring, succession ...

Fluido-Dynamic and Electromagnetic Characterization of 3D Carbon Dielectrophoresis with Finite Element Analysis

Directory of Open Access Journals (Sweden)

Rodrigo Martinez-Duarte

2008-12-01

Full Text Available The following work presents the fluido-dynamic and electromagnetic characterization of an array of 3D electrodes to be used in high throughput and high efficiency Carbon Dielectrophoresis (CarbonDEP applications such as filters, continuous particle enrichment and positioning of particle populations for analysis. CarbonDEP refers to the induction of Dielectrophoresis (DEP by carbon surfaces. The final goal is, through an initial stage of modeling and analysis, to reduce idea-to-prototype time and cost of CarbonDEP devices to be applied in the health care field. Finite Element Analysis (FEA is successfully conducted to model flow velocity and electric fields established by polarized high aspect ratio carbon cylinders, and its planar carbon connecting leads, immersed in a water-based medium. Results demonstrate correlation between a decreasing flow velocity gradient and an increasing electric field gradient toward electrodes’ surfaces which is optimal for selected CarbonDEP applications. Simulation results are experimentally validated in the proposed applications.

Triconstituent co-assembly to ordered mesostructured polymer-silica and carbon-silica nanocomposites and large-pore mesoporous carbons with high surface areas.

Science.gov (United States)

Liu, Ruili; Shi, Yifeng; Wan, Ying; Meng, Yan; Zhang, Fuqiang; Gu, Dong; Chen, Zhenxia; Tu, Bo; Zhao, Dongyuan

2006-09-06

Highly ordered mesoporous polymer-silica and carbon-silica nanocomposites with interpenetrating networks have been successfully synthesized by the evaporation-induced triconstituent co-assembly method, wherein soluble resol polymer is used as an organic precursor, prehydrolyzed TEOS is used as an inorganic precursor, and triblock copolymer F127 is used as a template. It is proposed for the first time that ordered mesoporous nanocomposites have "reinforced concrete"-structured frameworks. By adjusting the initial mass ratios of TEOS to resol, we determined the obtained nanocomposites possess continuous composition with the ratios ranging from zero to infinity for the two constituents that are "homogeneously" dispersed inside the pore walls. The presence of silicates in nanocomposites dramatically inhibits framework shrinkage during the calcination, resulting in highly ordered large-pore mesoporous carbon-silica nanocomposites. Combustion in air or etching in HF solution can remove carbon or silica from the carbon-silica nanocomposites and yield ordered mesoporous pure silica or carbon frameworks. The process generates plenty of small pores in carbon or/and silica pore walls. Ordered mesoporous carbons can then be obtained with large pore sizes of approximately 6.7 nm, pore volumes of approximately 2.0 cm(3)/g, and high surface areas of approximately 2470 m(2)/g. The pore structures and textures can be controlled by varying the sizes and polymerization degrees of two constituent precursors. Accordingly, by simply tuning the aging time of TEOS, ordered mesoporous carbons with evident bimodal pores at 2.6 and 5.8 nm can be synthesized.

Anoxygenic Photosynthesis Controls Oxygenic Photosynthesis in a Cyanobacterium from a Sulfidic Spring

KAUST Repository

Klatt, Judith M.; Alnajjar, Mohammad Ahmad; Yilmaz, Pelin; Lavik, Gaute; de Beer, Dirk; Polerecky, Lubos

2015-01-01

Before the Earth's complete oxygenation (0.58 to 0.55 billion years [Ga] ago), the photic zone of the Proterozoic oceans was probably redox stratified, with a slightly aerobic, nutrient-limited upper layer above a light-limited layer that tended toward euxinia. In such oceans, cyanobacteria capable of both oxygenic and sulfide-driven anoxygenic photosynthesis played a fundamental role in the global carbon, oxygen, and sulfur cycle. We have isolated a cyanobacterium, Pseudanabaena strain FS39, in which this versatility is still conserved, and we show that the transition between the two photosynthetic modes follows a surprisingly simple kinetic regulation controlled by this organism's affinity for H2S. Specifically, oxygenic photosynthesis is performed in addition to anoxygenic photosynthesis only when H2S becomes limiting and its concentration decreases below a threshold that increases predictably with the available ambient light. The carbon-based growth rates during oxygenic and anoxygenic photosynthesis were similar. However, Pseudanabaena FS39 additionally assimilated NO3 - during anoxygenic photosynthesis. Thus, the transition between anoxygenic and oxygenic photosynthesis was accompanied by a shift of the C/N ratio of the total bulk biomass. These mechanisms offer new insights into the way in which, despite nutrient limitation in the oxic photic zone in the mid-Proterozoic oceans, versatile cyanobacteria might have promoted oxygenic photosynthesis and total primary productivity, a key step that enabled the complete oxygenation of our planet and the subsequent diversification of life.

Anoxygenic Photosynthesis Controls Oxygenic Photosynthesis in a Cyanobacterium from a Sulfidic Spring

KAUST Repository

Klatt, Judith M.

2015-03-15

Before the Earth\\'s complete oxygenation (0.58 to 0.55 billion years [Ga] ago), the photic zone of the Proterozoic oceans was probably redox stratified, with a slightly aerobic, nutrient-limited upper layer above a light-limited layer that tended toward euxinia. In such oceans, cyanobacteria capable of both oxygenic and sulfide-driven anoxygenic photosynthesis played a fundamental role in the global carbon, oxygen, and sulfur cycle. We have isolated a cyanobacterium, Pseudanabaena strain FS39, in which this versatility is still conserved, and we show that the transition between the two photosynthetic modes follows a surprisingly simple kinetic regulation controlled by this organism\\'s affinity for H2S. Specifically, oxygenic photosynthesis is performed in addition to anoxygenic photosynthesis only when H2S becomes limiting and its concentration decreases below a threshold that increases predictably with the available ambient light. The carbon-based growth rates during oxygenic and anoxygenic photosynthesis were similar. However, Pseudanabaena FS39 additionally assimilated NO3 - during anoxygenic photosynthesis. Thus, the transition between anoxygenic and oxygenic photosynthesis was accompanied by a shift of the C/N ratio of the total bulk biomass. These mechanisms offer new insights into the way in which, despite nutrient limitation in the oxic photic zone in the mid-Proterozoic oceans, versatile cyanobacteria might have promoted oxygenic photosynthesis and total primary productivity, a key step that enabled the complete oxygenation of our planet and the subsequent diversification of life.

The vacuum pyrolysis of used tires. End-uses for oil and carbon black products

Energy Technology Data Exchange (ETDEWEB)

Roy, C.; Chaala, A.; Darmstadt, H. [Institut Pyrovac Inc., Parc Technologique du Quebec Metropolitain, rue Franquet, Sainte-Foy (Canada)

1999-07-01

By vacuum pyrolysis, the rubber portion of used tires is transformed into oil and gas and the carbon black filler is recovered as pyrolytic carbon black (CB{sub P}). Several commercial applications for the different products have been investigated and are reported in this article. CB{sub P} surface chemistry and activity are similar to those of commercial carbon blacks. Therefore, CB{sub P} has the potential to replace commercial carbon black grades in certain rubber applications. CB{sub P} was successfully tested as a filler in road pavement. The total pyrolytic oil can be used as a liquid fuel. The oil can also be distilled into different fractions: a light, a middle distillate and a heavy fraction. The light fraction was positively tested as a gasoline additive. Furthermore, this fraction contains valuable chemicals such as d,l-limonene. The middle fraction was successfully tested as a plasticizer in rubbers. The heavy fraction represents a good-quality feedstock for the production of coke and can also be used in road pavements. The pyrolytic gas can be used as a make-up heat source for the pyrolysis process

Influences of carbon content and coating carbon thickness on properties of amorphous CoSnO3@C composites as anode materials for lithium-ion batteries

International Nuclear Information System (INIS)

Fan, Fuqiang; Fang, Guoqing; Zhang, Ruixue; Xu, Yanhui; Zheng, Junwei; Li, Decheng

2014-01-01

Highlights: • The thickness of carbon coating layers can be successfully controlled through varying molar concentration of aqueous glucose solution. • Coating carbon thickness and carbon content are two important factors on the electrochemical performances of CoSnO3@C. • CoSnO 3 @C under optimized conditions exhibits the optimal balance between the volume buffering effect and reversible capacity. • As-prepared CoSnO 3 @C under optimized conditions shows excellent electrochemical performances, whose reversible capacity could reach 491 mA h g −1 after 100 cycles. - Abstract: A series of core–shell carbon coated amorphous CoSnO 3 (CoSnO 3 @C) with different carbon content are synthesized. Effects of carbon content and coating carbon thickness on the physical and electrochemical performances of the samples were studied in detail. The samples were analyzed by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), galvanostatic charge–discharge and AC impedance spectroscopy, respectively. The results indicate that controlling the concentration of aqueous glucose solution influences the generation of in-situ carbon layer thickness. The optimal concentration of aqueous glucose solution, carbon content and carbon layer thickness are suggested as 0.25 M, 35.1% and 20 nm, respectively. CoSnO 3 @C composite prepared under the optimal conditions exhibits excellent cycling performance, whose reversible capacity could reach 491 mA h g −1 after 100 cycles

The valuation of forest carbon services by Mexican citizens: the case of Guadalajara city and La Primavera biosphere reserve

NARCIS (Netherlands)

Balderas Torres, Arturo; MacMillan, D.C.; Skutsch, Margaret; Lovett, Jonathan Cranidge

2013-01-01

Adequate demand for, and recognition of, forest carbon services is critical to success of market mechanisms for forestry-based conservation and climate change mitigation. National and voluntary carbon-offsetting schemes are emerging as alternatives to international compliance markets. We developed a

Memristive effects in oxygenated amorphous carbon nanodevices

Science.gov (United States)

Bachmann, T. A.; Koelmans, W. W.; Jonnalagadda, V. P.; Le Gallo, M.; Santini, C. A.; Sebastian, A.; Eleftheriou, E.; Craciun, M. F.; Wright, C. D.

2018-01-01

Computing with resistive-switching (memristive) memory devices has shown much recent progress and offers an attractive route to circumvent the von-Neumann bottleneck, i.e. the separation of processing and memory, which limits the performance of conventional computer architectures. Due to their good scalability and nanosecond switching speeds, carbon-based resistive-switching memory devices could play an important role in this respect. However, devices based on elemental carbon, such as tetrahedral amorphous carbon or ta-C, typically suffer from a low cycling endurance. A material that has proven to be capable of combining the advantages of elemental carbon-based memories with simple fabrication methods and good endurance performance for binary memory applications is oxygenated amorphous carbon, or a-CO x . Here, we examine the memristive capabilities of nanoscale a-CO x devices, in particular their ability to provide the multilevel and accumulation properties that underpin computing type applications. We show the successful operation of nanoscale a-CO x memory cells for both the storage of multilevel states (here 3-level) and for the provision of an arithmetic accumulator. We implement a base-16, or hexadecimal, accumulator and show how such a device can carry out hexadecimal arithmetic and simultaneously store the computed result in the self-same a-CO x cell, all using fast (sub-10 ns) and low-energy (sub-pJ) input pulses.

Reactor scale modeling of multi-walled carbon nanotube growth

International Nuclear Information System (INIS)

Lombardo, Jeffrey J.; Chiu, Wilson K.S.

2011-01-01

As the mechanisms of carbon nanotube (CNT) growth becomes known, it becomes important to understand how to implement this knowledge into reactor scale models to optimize CNT growth. In past work, we have reported fundamental mechanisms and competing deposition regimes that dictate single wall carbon nanotube growth. In this study, we will further explore the growth of carbon nanotubes with multiple walls. A tube flow chemical vapor deposition reactor is simulated using the commercial software package COMSOL, and considered the growth of single- and multi-walled carbon nanotubes. It was found that the limiting reaction processes for multi-walled carbon nanotubes change at different temperatures than the single walled carbon nanotubes and it was shown that the reactions directly governing CNT growth are a limiting process over certain parameters. This work shows that the optimum conditions for CNT growth are dependent on temperature, chemical concentration, and the number of nanotube walls. Optimal reactor conditions have been identified as defined by (1) a critical inlet methane concentration that results in hydrogen abstraction limited versus hydrocarbon adsorption limited reaction kinetic regime, and (2) activation energy of reaction for a given reactor temperature and inlet methane concentration. Successful optimization of a CNT growth processes requires taking all of those variables into account.

Two different carbon-hydrogen complexes in silicon with closely spaced energy levels

Energy Technology Data Exchange (ETDEWEB)

Stübner, R., E-mail: ronald.stuebner@physik.tu-dresden.de, E-mail: kolkov@ifpan.edu.pl; Kolkovsky, Vl., E-mail: ronald.stuebner@physik.tu-dresden.de, E-mail: kolkov@ifpan.edu.pl; Weber, J. [Technische Universität Dresden, Institut für Angewandte Physik, 01062 Dresden (Germany)

2015-08-07

An acceptor and a single donor state of carbon-hydrogen defects (CH{sub A} and CH{sub B}) are observed by Laplace deep level transient spectroscopy at 90 K. CH{sub A} appears directly after hydrogenation by wet chemical etching or hydrogen plasma treatment, whereas CH{sub B} can be observed only after a successive annealing under reverse bias at about 320 K. The activation enthalpies of these states are 0.16 eV for CH{sub A} and 0.14 eV for CH{sub B}. Our results reconcile previous controversial experimental results. We attribute CH{sub A} to the configuration where substitutional carbon binds a hydrogen atom on a bond centered position between carbon and the neighboring silicon and CH{sub B} to another carbon-hydrogen defect.

A depositional model for spherulitic carbonates associated with alkaline, volcanic lakes

NARCIS (Netherlands)

Mercedes-Martín, Ramon; Brasier, Alexander T.; Rogerson, Mike; Reijmer, John J.G.; Vonhof, Hubert; Pedley, Martyn

2017-01-01

The South Atlantic Aptian ‘Pre-salt’ reservoirs are formed by a combination of spherulitic carbonates and Mg-rich clays accumulated in volcanic alkaline lake settings with exotic chemistries. So far, outcrop analogues characterised by metre-thick successions deposited in lacustrine scenarios are

Multi-walled Carbon Nanotubes/Graphite Nanosheets Modified Glassy Carbon Electrode for the Simultaneous Determination of Acetaminophen and Dopamine.

Science.gov (United States)

Zhang, Susu; He, Ping; Zhang, Guangli; Lei, Wen; He, Huichao

2015-01-01

Graphite nanosheets prepared by thermal expansion and successive sonication were utilized for the construction of a multi-walled carbon nanotubes/graphite nanosheets based amperometric sensing platform to simultaneously determine acetaminophen and dopamine in the presence of ascorbic acid in physiological conditions. The synergistic effect of multi-walled carbon nanotubes and graphite nanosheets catalyzed the electrooxidation of acetaminophen and dopamine, leading to a remarkable potential difference up to 200 mV. The as-prepared modified electrode exhibited linear responses to acetaminophen and dopamine in the concentration ranges of 2.0 × 10(-6) - 2.4 × 10(-4) M (R = 0.999) and 2.0 × 10(-6) - 2.0 × 10(-4) M (R = 0.998), respectively. The detection limits were down to 2.3 × 10(-7) M for acetaminophen and 3.5 × 10(-7) M for dopamine (S/N = 3). Based on the simple preparation and prominent electrochemical properties, the obtained multi-walled carbon nanotubes/graphite nanosheets modified electrode would be a good candidate for the determination of acetaminophen and dopamine without the interference of ascorbic acid.

Carbon-On-Carbon Manufacturing

Science.gov (United States)

Mungas, Gregory S. (Inventor); Buchanan, Larry (Inventor); Banzon, Jr., Jose T. (Inventor)

2017-01-01

The presently disclosed technology relates to carbon-on-carbon (C/C) manufacturing techniques and the resulting C/C products. One aspect of the manufacturing techniques disclosed herein utilizes two distinct curing operations that occur at different times and/or using different temperatures. The resulting C/C products are substantially non-porous, even though the curing operation(s) substantially gasify a liquid carbon-entrained filler material that saturates a carbon fabric that makes up the C/C products.

Influences of carbon content and coating carbon thickness on properties of amorphous CoSnO{sub 3}@C composites as anode materials for lithium-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Fan, Fuqiang [Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of chemical power sources, Soochow University, Suzhou 215006 (China); Fang, Guoqing [Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of chemical power sources, Soochow University, Suzhou 215006 (China); Changzhou Institute of Energy Storage Materials and Devices, Changzhou 213000 (China); Zhang, Ruixue [Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of chemical power sources, Soochow University, Suzhou 215006 (China); Xu, Yanhui; Zheng, Junwei [Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of chemical power sources, Soochow University, Suzhou 215006 (China); College of Physics, Optoelectronics and Energy, Soochow University, Suzhou 215006 (China); Li, Decheng, E-mail: lidecheng@suda.edu.cn [Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of chemical power sources, Soochow University, Suzhou 215006 (China); College of Physics, Optoelectronics and Energy, Soochow University, Suzhou 215006 (China)

2014-08-30

Highlights: • The thickness of carbon coating layers can be successfully controlled through varying molar concentration of aqueous glucose solution. • Coating carbon thickness and carbon content are two important factors on the electrochemical performances of CoSnO3@C. • CoSnO{sub 3}@C under optimized conditions exhibits the optimal balance between the volume buffering effect and reversible capacity. • As-prepared CoSnO{sub 3}@C under optimized conditions shows excellent electrochemical performances, whose reversible capacity could reach 491 mA h g{sup −1} after 100 cycles. - Abstract: A series of core–shell carbon coated amorphous CoSnO{sub 3} (CoSnO{sub 3}@C) with different carbon content are synthesized. Effects of carbon content and coating carbon thickness on the physical and electrochemical performances of the samples were studied in detail. The samples were analyzed by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), galvanostatic charge–discharge and AC impedance spectroscopy, respectively. The results indicate that controlling the concentration of aqueous glucose solution influences the generation of in-situ carbon layer thickness. The optimal concentration of aqueous glucose solution, carbon content and carbon layer thickness are suggested as 0.25 M, 35.1% and 20 nm, respectively. CoSnO{sub 3}@C composite prepared under the optimal conditions exhibits excellent cycling performance, whose reversible capacity could reach 491 mA h g{sup −1} after 100 cycles.

Should there be an EC carbon/energy tax?

International Nuclear Information System (INIS)

Helm, D.

1993-01-01

The European Commission has suggested that an EC-wide carbon/energy tax should be introduced to meet the Community's commitment to reduce emissions of carbon dioxide, and to bear down on criticisms of sulphur dioxide and other harmful energy externalities. The UK government to data has pursued at best an agnostic position. Although the White Paper, This Common Inheritance, (DOE, 1990) gave prominence to the use of market-based instruments in advancing environmental objectives, their use in air pollution has been limited to the tax differential on unleaded petrol, the commitment to increase petrol tax in real terms in successive budgets and the imposition of VAT on domestic fuel in a phased series of stages. (Author)

Should there be an EC carbon/energy tax

Energy Technology Data Exchange (ETDEWEB)

Helm, D. (New College, Oxford (United Kingdom))

1993-12-01

The European Commission has suggested that an EC-wide carbon/energy tax should be introduced to meet the Community's commitment to reduce emissions of carbon dioxide, and to bear down on criticisms of sulphur dioxide and other harmful energy externalities. The UK government to data has pursued at best an agnostic position. Although the White Paper, This Common Inheritance, (DOE, 1990) gave prominence to the use of market-based instruments in advancing environmental objectives, their use in air pollution has been limited to the tax differential on unleaded petrol, the commitment to increase petrol tax in real terms in successive budgets and the imposition of VAT on domestic fuel in a phased series of stages. (Author)

CO{sub 2} capture by adsorption with nitrogen enriched carbons

Energy Technology Data Exchange (ETDEWEB)

M.G. Plaza; C. Pevida; A. Arenillas; F. Rubiera; J.J. Pis [Instituto Nacional del Carbon (CSIC), Oviedo (Spain)

2007-09-15

The success of CO{sub 2} capture with solid sorbents is dependent on the development of a low cost sorbent with high CO{sub 2} selectivity and adsorption capacity. Immobilised amines are expected to offer the benefits of liquid amines in the typical absorption process, with the added advantages that solids are easy to handle and that they do not give rise to corrosion problems. In this work, different alkylamines were evaluated as a potential source of basic sites for CO{sub 2} capture, and a commercial activated carbon was used as a preliminary support in order to study the effect of the impregnation. The amine coating increased the basicity and nitrogen content of the carbon. However, it drastically reduced the microporous volume of the activated carbon, which is chiefly responsible for CO{sub 2} physisorption, thus decreasing the capacity of raw carbon at room temperature. 33 refs., 7 figs., 3 tabs.

Fiber Optic Chemical Nanosensors Based on Engineered Single-Walled Carbon Nanotubes

Directory of Open Access Journals (Sweden)

M. Consales

2008-01-01

Full Text Available In this contribution, a review of the development of high-performance optochemical nanosensors based on the integration of carbon nanotubes with the optical fiber technology is presented. The paper first provide an overview of the amazing features of carbon nanotubes and their exploitation as highly adsorbent nanoscale materials for gas sensing applications. Successively, the attention is focused on the operating principle, fabrication, and characterization of fiber optic chemosensors in the Fabry-Perot type reflectometric configuration, realized by means of the deposition of a thin layer of single-walled carbon nanotubes (SWCNTs upon the distal end of standard silica optical fibers. This is followed by an extensive review of the excellent sensing capabilities of the realized SWCNTs-based chemical nanosensors against volatile organic compounds and other pollutants in different environments (air and water and operating conditions (room temperature and cryogenic temperatures. The experimental results reported here reveal that ppm and sub-ppm chemical detection limits, low response times, as well as fast and complete recovery of the sensor responses have been obtained in most of the investigated cases. This evidences the great potentialities of the proposed photonic nanosensors based on SWCNTs to be successfully employed for practical environmental monitoring applications both in liquid and vapor phase as well as for space. Furthermore, the use of novel SWCNTs-based composites as sensitive fiber coatings is proposed to enhance the sensing performance and to improve the adhesion of carbon nanotubes to the fiber surface. Finally, new advanced sensing configurations based on the use of hollow-core optical fibers coated and partially filled by carbon nanotubes are also presented.

Modeling the suppression of boron transient enhanced diffusion in silicon by substitutional carbon incorporation

Science.gov (United States)

Ngau, Julie L.; Griffin, Peter B.; Plummer, James D.

2001-08-01

Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank-Turnbull reactions. This study of boron TED reduction in Si1-x-yGexCy during 750 °C inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes {311} defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank-Turnbull reaction, and a carbon interstitial-carbon substitutional (CiCs) pairing reaction that successfully simulates carbon suppression of boron TED at 750 °C for anneal times ranging from 10 s to 60 min.

Modeling the suppression of boron transient enhanced diffusion in silicon by substitutional carbon incorporation

International Nuclear Information System (INIS)

Ngau, Julie L.; Griffin, Peter B.; Plummer, James D.

2001-01-01

Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank--Turnbull reactions. This study of boron TED reduction in Si 1-x-y Ge x C y during 750 o C inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes {311} defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank--Turnbull reaction, and a carbon interstitial-carbon substitutional (C i C s ) pairing reaction that successfully simulates carbon suppression of boron TED at 750 o C for anneal times ranging from 10 s to 60 min. copyright 2001 American Institute of Physics

Study of uranium (VI) in carbonate solution by potentiometric titrations and ion-exchange

International Nuclear Information System (INIS)

Billon, A.

1968-04-01

The present work is devoted to the fixation of uranium (VI) on the conventional anion-exchange resin Dowex 2 X 8 in carbonate and hydrogen-carbonate media. Both media were successfully used for the recuperation of uranium (VI) from very dilute solutions. Equilibrium constant of the exchange [UO 2 (CO 3 ) 3 4+ ] S + 2 [CO 3 2- ] R ↔ [UO 2 (CO 3 ) 3 4- ] R + 2[CO 3 2- ] S is determined for carbonate concentration range 0.1 M to 0.6 M from partition curves. A markedly increase in the relative fixation of uranium results with: - increasing free carbonate concentration of the solution, - decreasing uranium concentration. A study in the same conditions of the fixation of molybdenum has made it possible to separate the latter from uranium by elution, the carbonate concentration being molar. It is suggested a possibility of separation on a larger scale, based upon molybdenum displacement by uranium in hydrogen-carbonate medium. (author) [fr

Physico-chemical characterization studies of activated carbon derived from Sterculia Quadrifida seed shell waste

Directory of Open Access Journals (Sweden)

P. Shanthi

2014-09-01

Full Text Available A carbonaceous adsorbent prepared from the Sterculia Quadrifida shell by various activation process, viz., Acid process, Chloride process, Carbonate process and Sulphate process are successfully reported. It shows excellent improvement in the surface characteristics. Their physico-chemical characterization studies such as bulk density, moisture content, ash content, fixed carbon content, matter, soluble in water, matter soluble in acid, pH, decolourizing power, porosity and specific gravity have been carried out to assess the suitability of these carbons as potential adsorbent for waste water treatment. The present study undertaken to evaluate the efficiency of a carbon adsorbent prepared from Sterculia Quadrifida seed shell waste for removal of dyes in aqueous solution.

Zero- and two-dimensional hybrid carbon phosphors for high colorimetric purity white light-emission.

Science.gov (United States)

Ding, Yamei; Chang, Qing; Xiu, Fei; Chen, Yingying; Liu, Zhengdong; Ban, Chaoyi; Cheng, Shuai; Liu, Juqing; Huang, Wei

2018-03-01

Carbon nanomaterials are promising phosphors for white light emission. A facile single-step synthesis method has been developed to prepare zero- and two-dimensional hybrid carbon phosphors for the first time. Zero-dimensional carbon dots (C-dots) emit bright blue luminescence under 365 nm UV light and two-dimensional nanoplates improve the dispersity and film forming ability of C-dots. As a proof-of-concept application, the as-prepared hybrid carbon phosphors emit bright white luminescence in the solid state, and the phosphor-coated blue LEDs exhibit high colorimetric purity white light-emission with a color coordinate of (0.3308, 0.3312), potentially enabling the successful application of white emitting phosphors in the LED field.

Stoichiometric Constraints Do Not Limit Successful Invaders: Zebra Mussels in Swedish Lakes

OpenAIRE

Naddafi, Rahmat; Ekl?v, Peter; Pettersson, Kurt

2009-01-01

Background Elemental imbalances of carbon (C): nitrogen (N): phosphorus (P) ratios in food resources can constrain the growth of grazers owning to tight coupling between growth rate, RNA allocation and biomass P content in animals. Testing for stoichiometric constraints among invasive species is a novel challenge in invasion ecology to unravel how a successful invader tackles ecological barriers in novel ecosystems. Methodology/Principal Findings We examined the C?P and N?P ratios and the con...

Carbons and carbon supported catalysts in hydroprocessing

Energy Technology Data Exchange (ETDEWEB)

Furimsky, Edward

2009-07-01

This book is a comprehensive summary of recent research in the field and covers all areas of carbons and carbon materials. The potential application of carbon supports, particularly those of carbon black (CB) and activated carbon (AC) in hydroprocessing catalysis are covered. Novel carbon materials such as carbon fibers and carbon nano tubes (CNT) are also covered, including the more recent developments in the use of fullerenes in hydroprocessing applications. Although the primary focus of this book is on carbons and carbon supported catalysts, it also identifies the difference in the effect of carbon supports compared with the oxidic supports, particularly that of the Al{sub 2}O{sub 3}. The difference in catalyst activity and stability was estimated using both model compounds and real feeds under variable conditions. The conditions applied during the preparation of carbon supported catalysts are also comprehensively covered and include various methods of pretreatment of carbon supports to enhance catalyst performance. The model compounds results consistently show higher hydrodesulfurization and hydrodeoxygenation activities of carbon supported catalysts than that of the Al{sub 2}O{sub 3} supported catalysts. Also, the deactivation of the former catalysts by coke deposition was much less evident. Chapter 6.3.1.3 is on carbon-supported catalysts: coal-derived liquids.

Electrophoretically deposited graphene oxide and carbon nanotube composite for electrochemical capacitors

International Nuclear Information System (INIS)

Ajayi, Obafunso A; Wong, Chee Wei; Guitierrez, Daniel H; Peaslee, David; Cheng, Arthur; Chen, Bin; Gao, Theodore

2015-01-01

We report a scalable one-step electrode fabrication approach for synthesizing composite carbon-based supercapacitors with synergistic outcomes. Multi-walled carbon nanotubes (MWCNTs) were successfully integrated into our modified electrophoretic deposition process to directly form composite MWCNT–GO electrochemical capacitor electrodes (where GO is graphene oxide) with superior performance to solely GO electrodes. The measured capacitance improved threefold, reaching a maximum specific capacitance of 231 F g"−"1. Upon thermal reduction, MWCNT–GO electrode sheet resistance decreased by a factor of 8, significantly greater than the 2× decrease of those without MWCNTs. (paper)

A Carbon-Neutral California: Social Ecology and Prospects for 2050 GHG Reduction

Directory of Open Access Journals (Sweden)

Stephen M. Wheeler

2017-10-01

Full Text Available How might a large jurisdiction approach carbon neutrality by 2050, and what initiatives might increase the chances of success? This article explores these questions using California as a case study. Current trends as well as multiple modeling studies show that existing policy directions for the state will not be sufficient. Additional initiatives appear needed to accelerate adoption of electric vehicles, reduce driving, reach 100 percent renewable electricity, convert existing buildings to zero-net-carbon status, change diet, and reduce consumption. The state’s social ecology does not currently support such changes. Consequently, planners and other professionals need to consider strategic actions to change social ecology as well as climate policy. Potential steps to do this include raising the price of carbon; revising the state’s tax system so as to increase public sector capacity; developing a stronger framework of incentives, mandates, and technical support between levels of government; and expanding educational and social marketing programs aimed at behavior change. A main implication of this analysis is that in many contexts worldwide sustainability planners should consider action on both policy and social ecology levels to maximize chances of success.

Carbon-based strong solid acid for cornstarch hydrolysis

Energy Technology Data Exchange (ETDEWEB)

Nata, Iryanti Fatyasari, E-mail: yanti_tkunlam@yahoo.com [Chemical Engineering Study Program, Faculty of Engineering, Lambung Mangkurat University, Jl. A. Yani Km. 36 Banjarbaru, South Kalimantan 70714 (Indonesia); Irawan, Chairul; Mardina, Primata [Chemical Engineering Study Program, Faculty of Engineering, Lambung Mangkurat University, Jl. A. Yani Km. 36 Banjarbaru, South Kalimantan 70714 (Indonesia); Lee, Cheng-Kang, E-mail: cklee@mail.ntust.edu.tw [Department of Chemical Engineering, National Taiwan University of Science and Technology, 43 Keelung Rd. Sec.4, Taipei 106, Taiwan (China)

2015-10-15

Highly sulfonated carbonaceous spheres with diameter of 100–500 nm can be generated by hydrothermal carbonization of glucose in the presence of hydroxyethylsulfonic acid and acrylic acid at 180 °C for 4 h. The acidity of the prepared carbonaceous sphere C4-SO{sub 3}H can reach 2.10 mmol/g. It was used as a solid acid catalyst for the hydrolysis of cornstarch. Total reducing sugar (TRS) concentration of 19.91 mg/mL could be obtained by hydrolyzing 20 mg/mL cornstarch at 150 °C for 6 h using C4-SO{sub 3}H as solid acid catalyst. The solid acid catalyst demonstrated good stability that only 9% decrease in TRS concentration was observed after five repeat uses. The as-prepared carbon-based solid acid catalyst can be an environmentally benign replacement for homogeneous catalyst. - Highlights: • Carbon solid acid was successfully prepared by one-step hydrothermal carbonization. • The acrylic acid as monomer was effectively reduce the diameter size of particle. • The solid acid catalyst show good catalytic performance of starch hydrolysis. • The solid acid catalyst is not significantly deteriorated after repeated use.

Carbon-based strong solid acid for cornstarch hydrolysis

International Nuclear Information System (INIS)

Nata, Iryanti Fatyasari; Irawan, Chairul; Mardina, Primata; Lee, Cheng-Kang

2015-01-01

Highly sulfonated carbonaceous spheres with diameter of 100–500 nm can be generated by hydrothermal carbonization of glucose in the presence of hydroxyethylsulfonic acid and acrylic acid at 180 °C for 4 h. The acidity of the prepared carbonaceous sphere C4-SO 3 H can reach 2.10 mmol/g. It was used as a solid acid catalyst for the hydrolysis of cornstarch. Total reducing sugar (TRS) concentration of 19.91 mg/mL could be obtained by hydrolyzing 20 mg/mL cornstarch at 150 °C for 6 h using C4-SO 3 H as solid acid catalyst. The solid acid catalyst demonstrated good stability that only 9% decrease in TRS concentration was observed after five repeat uses. The as-prepared carbon-based solid acid catalyst can be an environmentally benign replacement for homogeneous catalyst. - Highlights: • Carbon solid acid was successfully prepared by one-step hydrothermal carbonization. • The acrylic acid as monomer was effectively reduce the diameter size of particle. • The solid acid catalyst show good catalytic performance of starch hydrolysis. • The solid acid catalyst is not significantly deteriorated after repeated use

Pore-Water Carbonate and Phosphate As Predictors of Arsenate Toxicity in Soil.

Science.gov (United States)

Lamb, Dane T; Kader, Mohammed; Wang, Liang; Choppala, Girish; Rahman, Mohammad Mahmudur; Megharaj, Mallavarapu; Naidu, Ravi

2016-12-06

Phytotoxicity of inorganic contaminants is influenced by the presence of competing ions at the site of uptake. In this study, interaction of soil pore-water constituents with arsenate toxicity was investigated in cucumber (Cucumis sativa L) using 10 contrasting soils. Arsenate phytotoxicity was shown to be related to soluble carbonate and phosphate. The data indicated that dissolved phosphate and carbonate had an antagonistic impact on arsenate toxicity to cucumber. To predict arsenate phytotoxicity in soils with a diverse range of soil solution properties, both carbonate and phosphate were required. The relationship between arsenic and pore-water toxicity parameters was established initially using multiple regression. In addition, based on the relationship with carbonate and phosphate we successively applied a terrestrial biotic ligand-like model (BLM) including carbonate and phosphate. Estimated effective concentrations from the BLM-like parametrization were strongly correlated to measured arsenate values in pore-water (R 2 = 0.76, P soils.

Surprising synthesis of nanodiamond from single-walled carbon nanotubes by the spark plasma sintering process

Science.gov (United States)

Mirzaei, Ali; Ham, Heon; Na, Han Gil; Kwon, Yong Jung; Kang, Sung Yong; Choi, Myung Sik; Bang, Jae Hoon; Park, No-Hyung; Kang, Inpil; Kim, Hyoun Woo

2016-10-01

Nanodiamond (ND) was successfully synthesized using single-walled carbon nanotubes (SWCNTs) as a pure solid carbon source by means of a spark plasma sintering process. Raman spectra and X-ray diffraction patterns revealed the generation of the cubic diamond phase by means of the SPS process. Lattice-resolved TEM images confirmed that diamond nanoparticles with a diameter of about ˜10 nm existed in the products. The NDs were generated mainly through the gas-phase nucleation of carbon atoms evaporated from the SWCNTs. [Figure not available: see fulltext.

Heteroatom-doped porous carbon from methyl orange dye wastewater for oxygen reduction

Directory of Open Access Journals (Sweden)

Yiqing Wang

2018-04-01

Full Text Available Banana peel-derived porous carbon (BPPC was prepared from banana peel and used as an adsorbent for methyl orange (MO wastewater removal. BPPC-MO50 is a N,S-doped BPPC obtained via secondary carbonization. The BPPC-MO50 exhibited a high specific surface area of 1774.3 m2/g. Heteroatom-doped porous carbon (PC was successfully synthesized from the BPPC absorbed MO at high temperature and used for oxygen reduction. The BPPC-MO50 displayed the highest ORR onset potential among all carbon-based electrocatalysts, i.e., 0.93 V vs. reversible hydrogen electrode (RHE. This is the first report to describe porous carbon-activated materials from agriculture and forestry waste that is used for adsorption of dyes from wastewater via an enhanced heteroatom (N,S content. These results may contribute to the sustainable development of dye wastewater treatment by transforming saturated PC into an effective material and has potential applications in fuel cells or as energy sources. Keywords: Banana peel, Dye wastewater, Porous carbon, Heteroatom doping, Oxygen reduction reaction

Effects of carbonization conditions on properties of bamboo pellets

Science.gov (United States)

Zhijia Liu; Zehui Jiang; Zhiyong Cai; Benhua Fei; Yan Yu; Xing' e Liu

2013-01-01

Bamboo is a biomass material and has great potential as a bio-energy resource of the future in China. Bamboo pellets were successfully manufactured using a laboratory pellet mill in preliminary work. This study was therefore carried out to investigate the effect of carbonization conditions (temperature and time) on properties of bamboo pellets and to evaluate product...

Variable carbon catabolism among Salmonella enterica serovar Typhi isolates.

Directory of Open Access Journals (Sweden)

Lay Ching Chai

Full Text Available BACKGROUND: Salmonella enterica serovar Typhi (S. Typhi is strictly a human intracellular pathogen. It causes acute systemic (typhoid fever and chronic infections that result in long-term asymptomatic human carriage. S. Typhi displays diverse disease manifestations in human infection and exhibits high clonality. The principal factors underlying the unique lifestyle of S. Typhi in its human host during acute and chronic infections remain largely unknown and are therefore the main objective of this study. METHODOLOGY/PRINCIPAL FINDINGS: To obtain insight into the intracellular lifestyle of S. Typhi, a high-throughput phenotypic microarray was employed to characterise the catabolic capacity of 190 carbon sources in S. Typhi strains. The success of this study lies in the carefully selected library of S. Typhi strains, including strains from two geographically distinct areas of typhoid endemicity, an asymptomatic human carrier, clinical stools and blood samples and sewage-contaminated rivers. An extremely low carbon catabolic capacity (27% of 190 carbon substrates was observed among the strains. The carbon catabolic profiles appeared to suggest that S. Typhi strains survived well on carbon subtrates that are found abundantly in the human body but not in others. The strains could not utilise plant-associated carbon substrates. In addition, α-glycerolphosphate, glycerol, L-serine, pyruvate and lactate served as better carbon sources to monosaccharides in the S. Typhi strains tested. CONCLUSION: The carbon catabolic profiles suggest that S. Typhi could survive and persist well in the nutrient depleted metabolic niches in the human host but not in the environment outside of the host. These findings serve as caveats for future studies to understand how carbon catabolism relates to the pathogenesis and transmission of this pathogen.

Systematically controlled pore system of ordered mesoporous carbons using phosphoric acid as the in situ generated catalysts for carbonization and activation

Energy Technology Data Exchange (ETDEWEB)

Jin, Xing; Lee, Chang Hyun; Kim, Jin Hoe; You, Dae Jong; Shon, Jeong Kuk; Kim, Ji Man [Dept. of Chemistry, Sungkyunkwan University, Suwon (Korea, Republic of); Pak, Chan Ho [Fuel Cell Group, Corporate R and D Center, Samsung SDI Co. Ltd., Yongin (Korea, Republic of)

2015-08-15

We report on a facile synthesis of the ordered mesoporous carbon (OMC) materials with systematically controlled microporosity and mesoporosity simultaneously through the nano-replication route using phosphoric acid as the acid catalyst and activation agent. The use of phosphoric acid affects the pore structures of OMC materials, such as the formation of numerous micropores by activation of the carbon framework and the enlargement of mesopores by spontaneous phase separation during the carbonization. The mesopore sizes, surface areas, total pore volumes, and micropore volumes of the OMC materials are highly dependent on the phosphoric acid content and can be systematically controlled in the range 3.7–7.5 nm, 1027–2782 m{sup 2} g{sup -1}, 1.12–3.53 cm{sup 3} g{sup -1} and 0.34–0.95 cm{sup 3} g{sup -1}, respectively. OMC materials with systematically controlled pore structures were successfully synthesized using phosphoric acid as the carbonization catalyst and mesoporous silica materials with cubic Ia3d and 2-D hexagonal mesostructures as the templates. The phosphoric acid in the synthesis of ordered mesoporous carbon materials acts as the chemical activating agent for micropore generation of the carbon framework and pore-expanding agent for controlling of mesopore size, in addition to functioning as the acid catalyst. The present synthesis pathway is very useful for preparing OMC materials with tunable mesopore sizes and well-developed microporosities at the same time.

Film of lignocellulosic carbon material for self-supporting electrodes in electric double-layer capacitors

Directory of Open Access Journals (Sweden)

Tsubasa Funabashi

2013-09-01

Full Text Available A novel thin, wood-based carbon material with heterogeneous pores, film of lignocellulosic carbon material (FLCM, was successfully fabricated by carbonizing softwood samples of Picea jezoensis (Jezo spruce. Simultaneous increase in the specific surface area of FLCM and its affinity for electrolyte solvents in an electric double-layer capacitor (EDLC were achieved by the vacuum ultraviolet/ozone (VUV/O3 treatment. This treatment increased the specific surface area of FLCM by 50% over that of original FLCM. The results obtained in this study confirmed that FLCM is an appropriate self-supporting EDLC electrode material without any warps and cracks.

The control of divertor carbon erosion/redeposition in the DIII-D tokamak

International Nuclear Information System (INIS)

Whyte, D.G.; West, W.P.; Wong, C.P.C.

2001-01-01

The DIII-D tokamak has demonstrated an operational scenario where the graphite-covered divertor is free of net erosion. Reduction of divertor carbon erosion is accomplished using a low temperature (detached) divertor plasma that eliminates physical sputtering. Likewise, the carbon source rate arising from chemical erosion is found to be very low in the detached divertor. Near strikepoint regions, the rate of carbon deposition is ∼3 cm/burn-year, with a corresponding hydrogenic codeposition rate >1kg/m 2 /burn-year; rates both problematic for steady-state fusion reactors. The carbon net deposition rate in the divertor is consistent with carbon arriving from the core plasma region. Carbon influx from the main wall is measured to be relatively large in the high-density detached regime and is of sufficient magnitude to account for the deposition rate in the divertor. Divertor redeposition is therefore determined by non-divertor erosion and transport. Despite the success in reducing divertor erosion on DIII-D with detachment, no significant reduction is found in the core plasma carbon density, illustrating the importance of non-divertor erosion and the complex coupling between erosion/redeposition and impurity plasma transport. (author)

Carbon/Carbon Pistons for Internal Combustion Engines

Science.gov (United States)

Taylor, A. H.

1986-01-01

Carbon/carbon piston performs same function as aluminum pistons in reciprocating internal combustion engines while reducing weight and increasing mechanical and thermal efficiencies of engine. Carbon/carbon piston concept features low piston-to-cylinder wall clearance - so low piston rings and skirts unnecessary. Advantages possible by negligible coefficient of thermal expansion of carbon/carbon.

High performance supercapacitor from activated carbon derived from waste orange skin

Science.gov (United States)

Ahmed, Sultan; Hussain, S.; Ahmed, Ahsan; Rafat, M.

2018-05-01

Activated carbon due to its inherent properties such as large surface area and low cost is most frequently used electrode material for supercapacitor. Activated carbon has been previously derived from various biomass such as coconut shell, coffee bean etc. Herein, we report the synthesis of activated carbon from waste orange skin. The material was synthesized employing chemical activation method and the success of synthesis was confirmed by its physical and electrochemical properties. The physical properties of the as-prepared sample were studied using the techniques of XRD, SEM, Raman spectroscopy and N2 adsorption/desorption analysis while its electrochemical properties were studied in two-electrode assembly using liquid electrolyte (consisting of 1 M solution of LiTFSI dispersed in ionic liquid EMITFSI) and employing the techniques of cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge- discharge. The synthesized sample of activated carbon exhibits high specific capacitance of 115 F g-1 at 10 mV s-1. Also, the activated carbon electrode shows the retention of ˜75% in initial capacitance value for more than 2000 initial cycles, indicating the as-prepared activated carbon can be profitably used as electrode material for energy storage devices.

Carbon tetrachloride ERA soil-gas baseline monitoring

International Nuclear Information System (INIS)

Fancher, J.D.

1994-01-01

From December 1991 through December 1993, Westinghouse Hanford Company performed routine baseline monitoring of selected wells ad soil-gas points twice weekly in the 200 West Area of the Hanford Site. This work supported the carbon Tetrachloride Expedited Response Action (ERA) and provided a solid baseline of volatile organic compound (VOC) concentrations in wells and in the subsurface at the ERA site. As site remediation continues, comparisons to this baseline can be one means of measuring the success of carbon tetrachloride vapor extraction. This report contains observations of the patterns and trends associated with data obtained during soil-gas monitoring at the 200 West Area: Monitoring performed since late 1991 includes monitoring soil-gas probes ad wellheads for volatile organic compounds (VOCs). This report reflects monitoring data collected from December 1991 through December 1993

Biological interactions of carbon-based nanomaterials: From coronation to degradation.

Science.gov (United States)

Bhattacharya, Kunal; Mukherjee, Sourav P; Gallud, Audrey; Burkert, Seth C; Bistarelli, Silvia; Bellucci, Stefano; Bottini, Massimo; Star, Alexander; Fadeel, Bengt

2016-02-01

Carbon-based nanomaterials including carbon nanotubes, graphene oxide, fullerenes and nanodiamonds are potential candidates for various applications in medicine such as drug delivery and imaging. However, the successful translation of nanomaterials for biomedical applications is predicated on a detailed understanding of the biological interactions of these materials. Indeed, the potential impact of the so-called bio-corona of proteins, lipids, and other biomolecules on the fate of nanomaterials in the body should not be ignored. Enzymatic degradation of carbon-based nanomaterials by immune-competent cells serves as a special case of bio-corona interactions with important implications for the medical use of such nanomaterials. In the present review, we highlight emerging biomedical applications of carbon-based nanomaterials. We also discuss recent studies on nanomaterial 'coronation' and how this impacts on biodistribution and targeting along with studies on the enzymatic degradation of carbon-based nanomaterials, and the role of surface modification of nanomaterials for these biological interactions. Advances in technology have produced many carbon-based nanomaterials. These are increasingly being investigated for the use in diagnostics and therapeutics. Nonetheless, there remains a knowledge gap in terms of the understanding of the biological interactions of these materials. In this paper, the authors provided a comprehensive review on the recent biomedical applications and the interactions of various carbon-based nanomaterials. Copyright © 2015 The Authors. Published by Elsevier Inc. All rights reserved.

Isotopic studies of Yucca Mountain soil fluids and carbonate pedogenesis

International Nuclear Information System (INIS)

McConnaughey, T.A.; Whelan, J.F.; Wickland, K.P.; Moscati, R.J.

1994-01-01

Secondary carbonates occurring within the soils, faults, and subsurface fractures of Yucca Mountain contain some of the best available records of paleoclimate and palehydrology for the potential radioactive waste repository site. This article discusses conceptual and analytical advances being made with regard to the interpretation of stable isotope data from pedogenic carbonates, specifically related to the 13 C content of soil CO 2 , CaCO 3 , precipitation mechanisms, and isotopic fractionations between parent fluids and precipitating carbonates. The 13 C content of soil carbon dioxide from Yucca Mountain and vicinity shows most of the usual patterns expected in such contexts: Decreasing 13 C content with depth decreasing 13 C with altitude and reduced 13 C during spring. These patterns exist within the domain of a noisy data set; soil and vegetational heterogeneities, weather, and other factors apparently contribute to isotopic variability in the system. Several soil calcification mechanisms appear to be important, involving characteristic physical and chemical environments and isotopic fractionations. When CO 2 loss from thin soil solutions is an important driving factor, carbonates may contain excess heavy isotopes, compared to equilibrium precipitation with soil fluids. When root calcification serves as a proton generator for plant absorption of soil nutrients, heavy isotope deficiencies are likely. Successive cycles of dissolution and reprecipitation mix and redistribute pedogenic carbonates, and tend to isotopically homogenize and equilibrate pedogenic carbonates with soil fluids

Carbon dioxide conversion over carbon-based nanocatalysts.

Science.gov (United States)

Khavarian, Mehrnoush; Chai, Siang-Piao; Mohamed, Abdul Rahman

2013-07-01

The utilization of carbon dioxide for the production of valuable chemicals via catalysts is one of the efficient ways to mitigate the greenhouse gases in the atmosphere. It is known that the carbon dioxide conversion and product yields are still low even if the reaction is operated at high pressure and temperature. The carbon dioxide utilization and conversion provides many challenges in exploring new concepts and opportunities for development of unique catalysts for the purpose of activating the carbon dioxide molecules. In this paper, the role of carbon-based nanocatalysts in the hydrogenation of carbon dioxide and direct synthesis of dimethyl carbonate from carbon dioxide and methanol are reviewed. The current catalytic results obtained with different carbon-based nanocatalysts systems are presented and how these materials contribute to the carbon dioxide conversion is explained. In addition, different strategies and preparation methods of nanometallic catalysts on various carbon supports are described to optimize the dispersion of metal nanoparticles and catalytic activity.

Cathode spot movements along the carbon fibres in carbon/carbon composites

International Nuclear Information System (INIS)

Zhang Chengyu; Qiao Shengru; Yang Zhimao; Ding Bingjun

2007-01-01

The cathode spot movements on a polyacrilonitrile (PAN)-based carbon felt reinforced C/C composite and a three dimensional PAN-based carbon fibre reinforced C/C composite (3D-C/C) were investigated by a scanning electron microscope and a digital high-speed video camera. It was found that the carbon fibres have a higher ability to withstand the vacuum arc erosion than the carbon matrix. The cathode spot walks on the matrix, rather than on the carbon fibres. The cathode spot motion is controlled by the architecture of carbon fibres in C/C. The cathode spots move along the carbon fibres by a step-by-step manner rather than a random walk. The cathode spot tracks spread over a wide zone on the 3D-C/C surface parallel to the carbon fibre. The average arc spreading velocity is estimated to be about 0.9 m s -1 and the transient arc spreading velocity is in the range of 0.54-4.5 m s -1

Radiation damage in carbon-carbon composites

International Nuclear Information System (INIS)

Burchell, T.D.; Eartherly, W.P.; Nelson, G.E.

1992-01-01

Graphite and carbon-carbon composite materials are widely used in plasma facing applications in current Tokamak devices such as TFTR and DIIID in the USA, JET, Tore Supra and TEXTOR in Europe, and JT-60U in Japan. Carbon-carbon composites are attractive choices for Tokamak limiters and diverters because of their low atomic number, high thermal shock resistance, high melting point, and high thermal conductivity. Next generation machines such as the International Thermonuclear Experimental Reactor (ITER) will utilize carbon-carbon composites in their first wall and diverter. ITER will be an ignition machine and thus will produce substantial neutron fluences from the D-T fusion reaction. The resultant high energy neutrons will cause carbon atom displacements in the plasma facing materials which will markedly affect their structure and physical properties. The effect of neutron damage on graphite has been studied for over forty years. Recently the effects of neutron irradiation on the fusion relevant graphite GraphNOL N3M was reviewed. In contrast to graphite, relatively little work has been performed to elucidate the effects of neutron irradiation on carbon-carbon composites. The results of our previous irradiation experiments have been published elsewhere. Here the irradiation induced dimensional changes in 1D, 2D, and 3D carbon-carbon composites are reported for fluences up to 4.7 dpa at an irradiation temperature of 600 degree C

Theoretical studies of zirconium and carbon clusters with molecular dynamics simulations

International Nuclear Information System (INIS)

Zhang, B.

1993-08-01

In this dissertation, we will present a systematic study of structures of fullerenes ranging from C 20 to C 100 by introducing a novel scheme. Using our new scheme, we not only reproduce all known fullerene structures but also successfully predicted several other fullerene structures which were confirmed by experiments. By utilizing the tight-binding molecular-dynamic (TBMD) simulation, we also studied the dynamical behavior of fullerenes: Vibrations, thermal disintegration of individual clusters as well as collisions between fullerenes. If the beauty of carbon fullerene is not enough, people found that carbon can also form tubules and even speculated that they can form three-dimensional graphite-like networks. By extending our fullerene structure searching scheme, we performed a search for the ground-state structure of three dimensional carbon network. We found the most stable structure people ever proposed for simple cubic based networks. From the difference of this new form of carbon and graphite in the electronic and vibrational properties, we propose an experimental probe to identify these novel three-dimensional carbon networks

Recent Progress in Producing Lignin-Based Carbon Fibers for Functional Applications

Energy Technology Data Exchange (ETDEWEB)

Paul, Ryan [GrafTech International Holdings Inc.; Burwell, Deanna [GrafTech International Holdings Inc.; Dai, Xuliang [GrafTech International Holdings Inc.; Naskar, Amit [Oak Ridge National Laboratory; Gallego, Nidia [Oak Ridge National Laboratory; Akato, Kokouvi [Oak Ridge National Laboratory

2015-10-29

Lignin, a biopolymer, has been investigated as a renewable and low-cost carbon fiber precursor since the 1960s. Although successful lab-scale production of lignin-based carbon fibers has been reported, there are currently not any commercial producers. This paper will highlight some of the known challenges with converting lignin-based precursors into carbon fiber, and the reported methods for purifying and modifying lignin to improve it as a precursor. Several of the challenges with lignin are related to its diversity in chemical structure and purity, depending on its biomass source (e.g. hardwood, softwood, grasses) and extraction method (e.g. organosolv, kraft). In order to make progress in this field, GrafTech and Oak Ridge National Laboratory are collaborating to develop lignin-based carbon fiber technology and to demonstrate it in functional applications, as part of a cooperative agreement with the DOE Advanced Manufacturing Office. The progress made to date with producing lignin-based carbon fiber for functional applications, as well as developing and qualifying a supply chain and value proposition, are also highlighted.

Characteristics of an activated carbon monolith for a helium adsorption compressor

NARCIS (Netherlands)

Lozano-Castello, D.; Jorda-Beneyto, M.; Cazorla-Amoros, D.; Linares-Solano, A.; Burger, Johannes Faas; ter Brake, Hermanus J.M.; Holland, Herman J.

2010-01-01

An activated carbon monolith (ACM) with a high helium adsorption/desorption capacity, high density, low pressure drop, low thermal expansion and good mechanical properties was prepared and applied successfully in a helium adsorption compressor as a part of a 4.5 K sorption cooler. The activated

Poly(brilliant green) and poly(thionine) modified carbon nanotube coated carbon film electrodes for glucose and uric acid biosensors.

Science.gov (United States)

Ghica, M Emilia; Brett, Christopher M A

2014-12-01

Poly(brilliant green) (PBG) and poly(thionine) (PTH) films have been formed on carbon film electrodes (CFEs) modified with carbon nanotubes (CNT) by electropolymerisation using potential cycling. Voltammetric and electrochemical impedance characterisation were performed. Glucose oxidase and uricase, as model enzymes, were immobilised on top of PBG/CNT/CFE and PTH/CNT/CFE for glucose and uric acid (UA) biosensing. Amperometric determination of glucose and UA was carried out in phosphate buffer pH 7.0 at -0.20 and +0.30 V vs. SCE, respectively, and the results were compared with other similarly modified electrodes existing in the literature. An interference study and recovery measurements in natural samples were successfully performed, indicating these architectures to be good and promising biosensor platforms. Copyright © 2014 Elsevier B.V. All rights reserved.

College Success Courses: Success for All

Science.gov (United States)

Coleman, Sandra Lee; Skidmore, Susan Troncoso; Weller, Carol Thornton

2018-01-01

College success courses (CSCs), or orientation courses, are offered by community colleges and universities to facilitate the success of first-time-in-college students. Primarily, these courses are designed to address students' nonacademic deficiencies, such as weak study habits and poor organizational skills, and to familiarize students with…

High power density supercapacitor electrodes of carbon nanotube films by electrophoretic deposition

International Nuclear Information System (INIS)

Du Chunsheng; Pan Ning

2006-01-01

Carbon nanotube thin films have been successfully fabricated by the electrophoretic deposition technique. The supercapacitors built from such thin film electrodes have a very small equivalent series resistance, and a high specific power density over 20 kW kg -1 was thus obtained. More importantly, the supercapacitors showed superior frequency response. Our study also demonstrated that these carbon nanotube thin films can serve as coating layers over ordinary current collectors to drastically enhance the electrode performance, indicating a huge potential in supercapacitor and battery manufacturing

Predictors of success in selective laser trabeculoplasty for primary open angle glaucoma in Chinese

Directory of Open Access Journals (Sweden)

Lee JW

2014-09-01

Full Text Available Jacky WY Lee,1,2 Catherine CL Liu,3 Jonathan CH Chan,4 Raymond LM Wong,5 Ian YH Wong,2 Jimmy SM Lai2 1The Department of Ophthalmology, Caritas Medical Centre, Hong Kong, SAR, People’s Republic of China; 2The Department of Ophthalmology, The University of Hong Kong, Hong Kong, SAR, People’s Republic of China; 3Department of Applied Mathematics, The Hong Kong Polytechnic University, Hong Kong, SAR, People’s Republic of China; 4The Department of Ophthalmology, Queen Mary Hospital, Hong Kong, SAR, People’s Republic of China; 5The Department of Ophthalmology and Visual Sciences, Hong Kong Eye Hospital, Hong Kong, SAR, People’s Republic of China Purpose: To determine the predictors of success for adjuvant selective laser trabeculoplasty (SLT in Chinese primary open angle glaucoma (POAG patients. Methods: This prospective study recruited Chinese subjects with unilateral or bilateral POAG currently taking medication to reduce intraocular pressure (IOP. All subjects received a single session of 360° SLT treatment and continued their medications for 1 month. SLT success was defined as IOP reduction ≥20% at 1 month. The following covariates were analyzed in both groups via univariate and multivariate analyses: age, sex, lens status, initial IOPs, post-SLT IOPs, number and type of medications, SLT shots and energy, and pre-SLT investigations.Results: In 51 eyes of 33 POAG subjects, the success rate of SLT was 47.1%. Certain groups of patients were associated with greater success using univariate analysis. These groups included the following: older age (coefficient =0.1; OR: 1.1; P=0.0003, a higher pre-SLT IOP (coefficient =0.3; OR: 1.3; P=0.0005, using four types of antiglaucoma medication (coefficient =2.1; OR: 8.4; P=0.005, a greater degree of spherical equivalent (coefficient =2.1; OR: 8.4; P=0.005, and the use of a topical carbonic anhydrase inhibitor (coefficient =1.7; OR: 6.0; P=0.003. None of the covariates were significant using

Carbon and energy footprint of electrochemical vinegar wastewater treatment

Science.gov (United States)

Gerek, Emine Esra; Yilmaz, Seval; Savaş Koparal, A.; Nezih Gerek, Ömer

2017-11-01

Electrochemical treatment of wastewaters that are rich in organic compounds is a popular method, due to its acidic nature that avoids biological treatment. In many cases, the pollution hazard is considered as the chemical oxygen demand (COD) from active carbon, and the success of the treatment is measured in terms of how much this specific parameter is reduced. However, if electricity is used during the treatment process, the treatment "itself" has manufacturing and operational energy costs. Many of the studies consider energy utilization as a monetary cost, and try to reduce its amount. However, the energy cost of the treatment also causes emission of carbon at the energy producing side of the closed loop. This carbon emission can be converted into oxygen demand, too. Therefore, it can be argued that one must look for the total optimal carbon efficiency (or oxygen demand), while reducing the COD. We chose a highly acidic wastewater case of vinegar production, which is a popular food product in Turkey, to demonstrate the high energy consumption and carbon emission problem of the electrochemical treatment approach. A novel strategy is presented to monitor total oxygen demand simultaneously at the treatment and energy production sides. Necessity of renewable energy utilization and conditions on process termination points are discussed.

3D molecular descriptors important for clinical success.

Science.gov (United States)

Kombo, David C; Tallapragada, Kartik; Jain, Rachit; Chewning, Joseph; Mazurov, Anatoly A; Speake, Jason D; Hauser, Terry A; Toler, Steve

2013-02-25

The pharmacokinetic and safety profiles of clinical drug candidates are greatly influenced by their requisite physicochemical properties. In particular, it has been shown that 2D molecular descriptors such as fraction of Sp3 carbon atoms (Fsp3) and number of stereo centers correlate with clinical success. Using the proteomic off-target hit rate of nicotinic ligands, we found that shape-based 3D descriptors such as the radius of gyration and shadow indices discriminate off-target promiscuity better than do Fsp3 and the number of stereo centers. We have deduced the relevant descriptor values required for a ligand to be nonpromiscuous. Investigating the MDL Drug Data Report (MDDR) database as compounds move from the preclinical stage toward the market, we have found that these shape-based 3D descriptors predict clinical success of compounds at preclinical and phase1 stages vs compounds withdrawn from the market better than do Fsp3 and LogD. Further, these computed 3D molecular descriptors correlate well with experimentally observed solubility, which is among well-known physicochemical properties that drive clinical success. We also found that about 84% of launched drugs satisfy either Shadow index or Fsp3 criteria, whereas withdrawn and discontinued compounds fail to meet the same criteria. Our studies suggest that spherical compounds (rather than their elongated counterparts) with a minimal number of aromatic rings may exhibit a high propensity to advance from clinical trials to market.

Marine redox structure at the culmination of the Great Oxidation Event: Insights from the Zaonega Formation, Karelia, Russia

Science.gov (United States)

Kipp, M.; Lepland, A.; Buick, R.

2017-12-01

The availability of dissolved oxygen is thought to have been the dominant throttle on the evolution and diversification of eukaryotic life during the Proterozoic Eon [1]. In the mid-Proterozoic, during the interval that presaged the rise of eukaryotes to ecological dominance, oxygen scarcity is thought to have relegated eukaryotic organisms to slivers of oxygenated shallow oceans [2]. However, recent work has suggested that oxygen levels rose dramatically during the early Paleoproterozoic Great Oxidation Event before crashing to the low levels of the mid-Proterozoic [3]. Evidence from selenium isotopes in shales [4] and iodate concentrations in carbonates [5] has even suggested that wide swathes of continental shelves were oxic enough to support eukaryotic organisms at this time. How oxic though, and for how long, remain poorly constrained. Here we present new selenium geochemical data from the Zaonega Formation of Karelia, Russia that can help resolve those questions. Previous work has proposed that the Zaonega Formation, and correlative Francevillian Series of Gabon, record the establishment of an oxygen-rich atmosphere at the culmination of the GOE [6]. Our selenium isotope dataset provides a test for this hypothesis, and can also be used to assess the preservation of the geochemical signatures in the Zaonega Formation. These data point to regional redox fluctuations, but due to the short marine residence time of selenium, extrapolating these results to global phenomena remains difficult. 1. Reinhard, et al (2016) PNAS 2. Planavsky, et al (2014) Science 3. Bekker and Holland (2012) EPSL 4. Kipp, et al (2017) PNAS 5. Hardisty, et al (2014) Geology 6. Kump, et al (2011) Science

One-step synthesis of solid state luminescent carbon-based silica nanohybrids for imaging of latent fingerprints

Science.gov (United States)

Li, Feng; Li, Hongren; Cui, Tianfang

2017-11-01

Fluorescent carbon-based nanomaterials(CNs) with tunable visible emission are biocompatible, environment friendly and most suitable for various biomedical applications. Despite the successes in preparing strongly fluorescent CNs, preserving the luminescence in solid materials is still challenging because of the serious emission quenching of CNs in solid state materials. In this work, fluorescent carbon and silica nanohybrids (SiCNHs) were synthesized via a simple one-step hydrothermal approach by carbonizing sodium citrate and (3-aminopropyl)triethoxysilane(APTES), and hydrolysis of tetraethyl orthosilicate(TEOS). The resultant SiCNs were characterized through X-ray diffraction (XRD), transmission electron microscopy (TEM), FT-IR, X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL) spectroscopy. The SiCNs exhibited strong fluorescence in both aqueous and solid states. The luminescent solid state SiCNs power were successfully used as a fluorescent labeling material for enhanced imaging of latent fingerprints(LFPs) on single background colour and multi-coloured surfaces substrates in forensic science for individual identification.

Experimental results on performance improvement of doped carbon-base materials

International Nuclear Information System (INIS)

Xu Zengyu

2002-01-01

Carbon-base materials is one of candidate plasma facing materials and have been widely used in current tokamak facilities in the world. But some defect properties are presented on high yield of chemical sputtering , high yield of radiation enhancement sublimate (RES), cracking after heat flux and so on. It can be improved by doped some little other elements into the carbon-base materials, such as boron, silicon, titanium and so on. Experimental results indicate that it is feasible and successful to improve thermo-physics and chemical properties of carbon-base materials by multi-element doped. Doped 12 % silicon can strained RES and chemical sputtering yield do not changed. It is the same level of chemical sputtering yield for B 4 C from 3 % to 10 % , but their resistance thermal shock properties ability increases with B 4 C increases

Single-Wall Carbon Nanotube-Coated Cotton Yarn for Electrocardiography Transmission

Directory of Open Access Journals (Sweden)

Yuliang Zhao

2018-03-01

Full Text Available We fabricated a type of conductive fabric, specifically single-wall carbon nanotube-coated cotton yarns (SWNT-CYs, for electrocardiography (ECG signal transmission utilizing a “dipping and drying” method. The conductive cotton yarns were prepared by dipping cotton yarns in SWNTs (single-wall carbon nanotubes solutions and then drying them at room temperature—a simple process that shows consistency in successfully coating cotton yarns with conductive carbon nanotubes (CNTs. The influence of fabrication conditions on the conductivity properties of SWNT-CYs was investigated. The results demonstrate that our conductive yarns can transmit weak bio-electrical (i.e., ECG signals without significant attenuation and distortion. Our conductive cotton yarns, which combine the flexibility of conventional fabrics and the good conductivity of SWNTs, are promising materials for wearable electronics and sensor applications in the future.

Distribution of organic carbon and petroleum source rock potential of Cretaceous and lower Tertiary carbonates, South Florida Basin: preliminary results

Science.gov (United States)

Palacas, James George

1978-01-01

Analyses of 134 core samples from the South Florida Basin show that the carbonates of Comanchean age are relatively richer in average organic carbon (0.41 percent) than those of Coahuilan age (0.28 percent), Gulfian age (0.18 percent) and Paleocene age (0.20 percent). They are also nearly twice as rich as the average world, wide carbonate (average 0.24 percent). The majority of carbonates have organic carbons less than 0.30 percent but the presence of many relatively organic rich beds composed of highly bituminous, argillaceous, highly stylolitic, and algal-bearing limestones and dolomites accounts for the higher percentage of organic carbon in some of the stratigraphic units. Carbonate rocks that contain greater than 0.4 percent organic carbon and that might be considered as possible petroleum sources were noted in almost each subdivision of the Coahuilan and Comanchean Series but particularly the units of Fredericksburg 'B', Trinity 'A', Trinity 'F', and Upper Sunniland. Possible source rocks have been ascribed by others to the Lower Sunniland, but lack of sufficient samples precluded any firm assessment in this initial report. In the shallower section of the basin, organic-rich carbonates containing as much as 3.2 percent organic carbon were observed in the lowermost part of the Gulfian Series and carbonate rocks with oil staining or 'dead' and 'live oil' were noted by others in the uppermost Gulfian and upper Cedar Keys Formation. It is questionable whether these shallower rocks are of sufficient thermal maturity to have generated commercial oil. The South Florida basin is still sparsely drilled and produces only from the Sunniland Limestone at an average depth of 11,500 feet (3500 m). Because the Sunniland contains good reservoir rocks and apparently adequate source rocks, and because the success rate of new oil field discoveries has increased in recent years, the chances of finding additional oil reserves in the Sunniland are promising. Furthermore, the

A sensor tip based on carbon nanotube-ink printed electrode for the dengue virus NS1 protein.

Science.gov (United States)

Dias, Ana Carolina M S; Gomes-Filho, Sérgio L R; Silva, Mízia M S; Dutra, Rosa F

2013-06-15

An immunosensor for the non-structural protein 1 (NS1) of the dengue virus based on carbon nanotube-screen printed electrodes (CNT-SPE) was successfully developed. A homogeneous mixture containing carboxylated carbon nanotubes was dispersed in carbon ink to prepare a screen printed working electrode. Anti-NS1 antibodies were covalently linked to CNT-SPE by an ethylenediamine film strategy. Amperometrical responses were generated at -0.5 V vs. Ag/AgCl by hydrogen peroxide reaction with peroxidase (HRP) conjugated to the anti-NS1. An excellent detection limit (in the order of 12 ng mL(-1)) and a sensitivity of 85.59 μA mM(-1)cm(-2) were achieved permitting dengue diagnostic according to the clinical range required. The matrix effect, as well as the performance of the assays, was successfully evaluated using spiked blood serum sample obtaining excellent recovery values in the results. Carbon nanotubes incorporated to the carbon ink improved the reproducibility and sensitivity of the CNT-SPE immunosensor. This point-of-care approach represents a great potential value for use in epidemic situations and can facilitate the early screening of patients in acute phase of dengue virus. Copyright © 2012 Elsevier B.V. All rights reserved.

A Study of the Effect of Interrupted Quenches on a Thermomechanically Processed High Carbon Steel.

Science.gov (United States)

1982-10-01

steel . Successful martempering requires a cooling rate sufficient to avoid the nose of the C- curve and thus prevent significant bainite formation. When...STUDY OF THE EFFECT OF INTERRUPTED QUENCHES ON A THERMONECHANICALLY PROCESSED HIGH CARBON STEEL by Steven A. Barton October 1982 Thesis Advisor: T.R...unlimited. A Study of the Effect of Interrupted Quenches on a Thermomechanically Processed High Carbon Steel by Steven A. Barton Lieutenant, United

Plasma Treatment of Carbon Nanotubes Applied to Improve the High Performance of Carbon Nanofiber Supercapacitors

International Nuclear Information System (INIS)

Chang, Wei-Min; Wang, Cheng-Chien; Chen, Chuh-Yung

2015-01-01

Graphical abstract: This article focused on improving conductivity of carbon nanofibers (CNFs) by added plasma-treatment carbon nanotubes (CNTs). The plasma modification method avoided the destruction of the length and structure of the CNTs and maintained their good electrical properties. Through this method, the relation between conductivity and surface activity site of CNFs was investigated. The results shown that he CNTs-MA added to the CNFs successfully maintained the activity sites on the surface of the CNFs and provide a good electric network to enhance the supercapacitor performance of the CNFs. - Highlights: • The plasma modification method avoided the destruction of the length and structure of the CNTs and maintained their good electrical properties. • The highest conductivity of the CNTs-MA/CNF was 5.2 s/cm at 2.5 wt.% of CNTs-MA addition. It was increased to 8.7 time. • The CNTs-MA added to the CNFs successfully maintained the activity sites on the surface of the CNFs and provide a good electric network to enhance the supercapacitor performance of the CNFs. The highest capacitance was 382 F/g. - Abstract: Plasma-treatment carbon nanotubes (CNTs) grafted with maleic anhydride (MA) were embedded in polyacryonitrile nanofibers via electrospinning and subsequently carbonizated at 800 °C to fabricate carbon nanofibers (CNFs). The grafted degree of MA on CNTs (CNTs-MA) was determined via Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The morphology, surface composition and conductivity of the CNTs-MA/CNF were characterized using electron microscopy, X-ray photoelectron and electrochemical impedance spectroscopy, respectively. CNTs-MA not only affected the conductivity of the CNFs but also the types of the nitrogen functional groups that could be represented as active sites on the CNFs to enhance the performance of the supercapacitors. When 2.5 wt.% CNTs-MA was embedded in the CNFs, the highest conductivity was obtained at

COHO - Utilizing Waste Heat and Carbon Dioxide at Power Plants for Water Treatment

Energy Technology Data Exchange (ETDEWEB)

Kaur, Sumanjeet [Porifera Inc., Hayward, CA (United States); Wilson, Aaron [Porifera Inc., Hayward, CA (United States); Wendt, Daniel [Porifera Inc., Hayward, CA (United States); Mendelssohn, Jeffrey [Porifera Inc., Hayward, CA (United States); Bakajin, Olgica [Porifera Inc., Hayward, CA (United States); Desormeaux, Erik [Porifera Inc., Hayward, CA (United States); Klare, Jennifer [Porifera Inc., Hayward, CA (United States)

2017-07-25

The COHO is a breakthrough water purification system that can concentrate challenging feed waters using carbon dioxide and low-grade heat. For this project, we studied feeds in a lab-scale system to simulate COHO’s potential to operate at coal- powered power plants. COHO proved successful at concentrating the highly scaling and challenging wastewaters derived from a power plant’s cooling towers and flue gas desulfurization units. We also found that COHO was successful at scrubbing carbon dioxide from flue gas mixtures. Thermal regeneration of the switchable polarity solvent forward osmosis draw solution ended up requiring higher temperatures than initially anticipated, but we also found that the draw solution could be polished via reverse osmosis. A techno-economic analysis indicates that installation of a COHO at a power plant for wastewater treatment would result in significant savings.

Maternal health status correlates with nest success of leatherback sea turtles (Dermochelys coriacea from Florida.

Directory of Open Access Journals (Sweden)

Justin R Perrault

Full Text Available Of the seven sea turtle species, the critically endangered leatherback sea turtle (Dermochelys coriacea exhibits the lowest and most variable nest success (i.e., hatching success and emergence success for reasons that remain largely unknown. In an attempt to identify or rule out causes of low reproductive success in this species, we established the largest sample size (n = 60-70 for most values of baseline blood parameters (protein electrophoresis, hematology, plasma biochemistry for this species to date. Hematologic, protein electrophoretic and biochemical values are important tools that can provide information regarding the physiological condition of an individual and population health as a whole. It has been proposed that the health of nesting individuals affects their reproductive output. In order to establish correlations with low reproductive success in leatherback sea turtles from Florida, we compared maternal health indices to hatching success and emergence success of their nests. As expected, hatching success (median = 57.4% and emergence success (median = 49.1% in Floridian leatherbacks were low during the study period (2007-2008 nesting seasons, a trend common in most nesting leatherback populations (average global hatching success = ∼50%. One protein electrophoretic value (gamma globulin protein and one hematologic value (red blood cell count significantly correlated with hatching success and emergence success. Several maternal biochemical parameters correlated with hatching success and/or emergence success including alkaline phosphatase activity, blood urea nitrogen, calcium, calcium:phosphorus ratio, carbon dioxide, cholesterol, creatinine, and phosphorus. Our results suggest that in leatherbacks, physiological parameters correlate with hatching success and emergence success of their nests. We conclude that long-term and comparative studies are needed to determine if certain individuals produce nests with lower

Fracturing and fluid-flow during post-rift subsidence in carbonates of the Jandaíra Formation, Potiguar Basin, NE Brazil

NARCIS (Netherlands)

Bertotti, Giovanni; de Graaf, Stefan; Bisdom, Kevin; Oskam, Brigit; B. Vonhof, Hubert; H. R. Bezerra, Francisco; J. G. Reijmer, John; L. Cazarin, Caroline

2017-01-01

Pervasive fracture networks are common in many reservoir-scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates

Integral Ring Carbon-Carbon Piston

Science.gov (United States)

Northam, G. Burton (Inventor)

1999-01-01

An improved structure for a reciprocating internal combustion engine or compressor piston fabricate from carbon-carbon composite materials is disclosed. An integral ring carbon-carbon composite piston, disclosed herein, reduces the need for piston rings and for small clearances by providing a small flexible, integral component around the piston that allows for variation in clearance due to manufacturing tolerances, distortion due to pressure and thermal loads, and variations in thermal expansion differences between the piston and cylinder liner.

Death in Guizhou — Late Triassic drowning of the Yangtze carbonate platform

Science.gov (United States)

Enos, Paul; Wei Jiayong; Lehrmann, Daniel J.

1998-06-01

The Yangtze platform in south China formed a stable palaeogeographic element from the Late Proterozoic to the end of the Middle Triassic with deposition of shallow-water carbonates during much of this time. A portion of the Yangtze platform in south-central Guizhou drowned at the transition from Permian to Triassic, as the south-adjacent Nanpanjiang basin encroached about 100 km northward, but a new, stable platform margin was established that persisted through the Early and Middle Triassic. This long history as a stable carbonate platform ended at the transition from the Ladinian to the Carnian. The latest Ladinian rocks, the Yangliujing Formation, are 490 m of shoaling-upward carbonate cycles of grapestone and bioclastic grainstone, fenestral limestone, and stromatolitic dolomudstone, commonly overprinted by extensive subaerial diagenesis. The beginning of the Carnian is marked by a rapid transition to medium-dark-grey, nodular lime mudstones containing ammonoids, conodonts and thin-shelled bivalves, the Zhuganpo Formation. The upper part of this thin pelagic limestone contains many muddy intraclasts, some slightly bored and encrusted, indicating incipient cementation. The overlying Wayao Formation is a condensed black shale with thin interbeds of dark-grey, manganiferous lime mudstone near the base. Ammonoids, conodonts, thin-shelled bivalves, and articulated crinoid stems are abundant. Fine-grained greywacke with sole marks forms prominent bundles within grey, calcareous shale in the overlying Laishike Formation. Ammonoids and thin-shelled bivalves occur sporadically in this 810-m-thick unit. Calcareous shale with thicker-shelled bivalves and packages of cleaner, coarser-grained sandstone characterize the Banan Formation, 460 m thick. The sandstone units generally coarsen and thicken upward, with ripples, medium-scale trough cross-beds, and rare U-tube burrows. Quartzose, coal-bearing siliciclastics 690 m thick form the overlying Huobachong Formation. Thick

Control Carbon to Prevent corium Stratification In-Vessel Retention

Energy Technology Data Exchange (ETDEWEB)

Go, A Ra; Hong, Seung Hyun; Kim, Sang Nyung [Kyung Hee Univ., Yongin (Korea, Republic of)

2013-10-15

As a result, the thermal margin decreases, and the nuclear reactor vessel may be destroyed. To control Carbons, which is the major cause of stratification, Ruthenium and Hafnium are inserted inside the lower reactor head which initiates a chemical reaction with Carbon. SPARTAN program is used to confirm a reaction probability which is measured in bond energy and strength etc. To analyze the possibility of bonding with Carbon, the initial property of Ruthenium and Carbon are measured during the calculated absorbing process. After following that theory, the Spartan program is able to determine if it can insert the metal. After verifying the combination of Ruthenium and Carbon, the Spartan program analyzes the impact of the Carbon to prevent the corium stratification. It determines the possibility of the success with the introduction of the IVR concept. Ruthenium is suitable to Carbon bonding process to decrease affect to corium behavior which do not form stratification. The metal which can combine with Carbon should be satisfied with temperature as high as 2800 .deg. C. Therefore, the further research works are determined by using the Spartan program to calculate the Carbon and Ruthenium bonding energy, and to check other bonding results as follows. After check the results, review this theory to insert the Ruthenium in reactor vessel. APR1400 and OPR1000, Korea Hydro and Nuclear power plant core meltdown accident has been evaluated a high level in severe accident. When the reactor core is melted down, it is stratified into the metal layer and the ceramic layer. As the heat conductivity of metal layer is higher than that of the ceramic layer, heat concentration occurs in the upper part of the bottom hemisphere which comes into contact with the metal layer.

Chemically treated carbon black waste and its potential applications

Energy Technology Data Exchange (ETDEWEB)

Dong, Pengwei; Maneerung, Thawatchai; Ng, Wei Cheng; Zhen, Xu [NUS Environmental Research Institute, National University of Singapore, 1 Create Way, Create Tower #15-02, 138602 (Singapore); Dai, Yanjun [School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Tong, Yen Wah [NUS Environmental Research Institute, National University of Singapore, 1 Create Way, Create Tower #15-02, 138602 (Singapore); Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 (Singapore); Ting, Yen-Peng [Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 (Singapore); Koh, Shin Nuo [Sembcorp Industries Ltd., 30 Hill Street #05-04, 179360 (Singapore); Wang, Chi-Hwa, E-mail: chewch@nus.edu.sg [Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 (Singapore); Neoh, Koon Gee, E-mail: chenkg@nus.edu.sg [Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 (Singapore)

2017-01-05

Highlights: • Hazardous impurities separated from carbon black waste with little damage to solid. • Heavy metals were effectively removed from carbon black waste by HNO{sub 3} leaching. • Treated carbon black waste has high adsorption capacity (∼356.4 mg{sub dye}/g). • Carbon black waste was also found to show high electrical conductivity (10 S/cm). - Abstract: In this work, carbon black waste – a hazardous solid residue generated from gasification of crude oil bottom in refineries – was successfully used for making an absorbent material. However, since the carbon black waste also contains significant amounts of heavy metals (especially nickel and vanadium), chemical leaching was first used to remove these hazardous impurities from the carbon black waste. Acid leaching with nitric acid was found to be a very effective method for removal of both nickel and vanadium from the carbon black waste (i.e. up to 95% nickel and 98% vanadium were removed via treatment with 2 M nitric acid for 1 h at 20 °C), whereas alkali leaching by using NaOH under the same condition was not effective for removal of nickel (less than 10% nickel was removed). Human lung cells (MRC-5) were then used to investigate the toxicity of the carbon black waste before and after leaching. Cell viability analysis showed that the leachate from the original carbon black waste has very high toxicity, whereas the leachate from the treated samples has no significant toxicity. Finally, the efficacy of the carbon black waste treated with HNO{sub 3} as an absorbent for dye removal was investigated. This treated carbon black waste has high adsorption capacity (∼361.2 mg {sub dye}/g {sub carbonblack}), which can be attributed to its high specific surface area (∼559 m{sup 2}/g). The treated carbon black waste with its high adsorption capacity and lack of cytotoxicity is a promising adsorbent material. Moreover, the carbon black waste was found to show high electrical conductivity (ca. 10 S

K-Ar geochronology of mafic dyke swarms from the meridional part of Sao Francisco craton and implications on tectonic context

International Nuclear Information System (INIS)

Teixeira, W.; Kawashita, K.; Pecchio, M.; Tame, N.R.

1988-01-01

The southern region of the Sao Francisco Craton is made up of gneissic-granitoid terranes (mainly of amphibolite facies) associated with supracrustals, which can be separed into two crustal provinces, the oldest formed during the Archean (3-2-2.6 Ga.), and the youngest in the Early Proterozoic (2.4-2.0 Ga.). Mafic dyke swarms inject the basement complexes in the area west of Belo Horizonte city, but not the Late proterozoic Bambui sedimentary cover. These dykes show NNW, NW, WNW, NNE and ENE trends and are of anorogenic character. Most dykes are tholeiitic in composition. Metamorphic recrystallization at greenschist to amphibolite facies as well as minor hidrothermal and/or deuteric transformations are characteristics in the majority of the these dykes. About sixty K/Ar determinations have been performed on plagioclases, amphiboles and whole rocks. They are interpretated combining the use of K/Ar diagrams and histogram, and according to the crustal evolution proposed for the craton. The available radiometric data suggest that the main period of mafic intrusions took place in the Early proterozoic as supported by the apparent ages on amphiboles. However, the beginning of the Middle Proterozoic (1.7-1.5 Ga.) probably corresponds to a period of tensional tectonics as well. On the other hand, most ages obtained on plagioclases and whole rocks, can be associated with Late Proterozoic processes of argon gain or loss. The results are tectonicaly associated with crustal rifting of the continental mass. This two radiometric groupings are characteristic for the evolution of the Early proterozoic crustal provine and of the Mid-Proterozoic intracratonic Espinhaco System respectively. The youngest Late Proterozoic apparent ages associated with the reflections of the contemporaneous evolution of the Braziliano marginal mobile belt which is also suggested by the partial resetting of the K/Ar ages of basement rocks within the eastern part of the Sao Francisco Craton. (author) [pt

Study on China's low carbon development in an Economy-Energy-Electricity-Environment framework

International Nuclear Information System (INIS)

Hu Zhaoguang; Yuan Jiahai; Hu Zheng

2011-01-01

Emissions mitigation is a major challenge for China's sustainable development. We summarize China's successful experiences on energy efficiency in past 30 years as the contributions of Energy Usage Management and Integrated Resource Strategic Planning, which are essential for low-carbon economy. In an Economy-Energy-Electricity-Environment (E4) framework, the paper studies the low-carbon development of China and gives an outlook of China's economy growth, energy-electricity demand, renewable power generation and energy conservation and emissions mitigation until 2030. A business-as-usual scenario is projected as baseline for comparison while low carbon energy and electricity development path is studied. It is defined as low carbon energy/electricity when an economy body manages to realize its potential economic growth fueled by less energy/electricity consumption, which can be characterized by indexes of energy/electricity intensity and emissions per-unit of energy consumption (electricity generation). Results show that, with EUM, China, could save energy by 4.38 billion ton oil equivalences (toes) and reduce CO 2 emission by 16.55 billion tons; with IRSP, China, could save energy by 1.5 Btoes and reduce CO 2 emission by 5.7 Btons, during 2010-2030. To realize the massive potential, China has to reshape its economic structure and rely much on technology innovation in the future. - Research highlights: → In an E4 framework China's low-carbon development is compared with BAU scenario. → Low carbon energy/electricity and their related measuring indexes are discussed. → China's successful experiences on energy efficiency are summarized as EUM and IRSP. → With them China could save energy by 5.8 Btoe and reduce CO 2 by 22.2 Bton until 2030. → China must restructure its economy and rely on technology innovation for them.

Rock fracture grouting with microbially induced carbonate precipitation

Science.gov (United States)

Minto, James M.; MacLachlan, Erica; El Mountassir, Gráinne; Lunn, Rebecca J.

2016-11-01

Microbially induced carbonate precipitation has been proposed for soil stabilization, soil strengthening, and permeability reduction as an alternative to traditional cement and chemical grouts. In this paper, we evaluate the grouting of fine aperture rock fractures with calcium carbonate, precipitated through urea hydrolysis, by the bacteria Sporosarcina pasteurii. Calcium carbonate was precipitated within a small-scale and a near field-scale (3.1 m2) artificial fracture consisting of a rough rock lower surfaces and clear polycarbonate upper surfaces. The spatial distribution of the calcium carbonate precipitation was imaged using time-lapse photography and the influence on flow pathways revealed from tracer transport imaging. In the large-scale experiment, hydraulic aperture was reduced from 276 to 22 μm, corresponding to a transmissivity reduction of 1.71 × 10-5 to 8.75 × 10-9 m2/s, over a period of 12 days under constantly flowing conditions. With a modified injection strategy a similar three orders of magnitude reduction in transmissivity was achieved over a period of 3 days. Calcium carbonate precipitated over the entire artificial fracture with strong adhesion to both upper and lower surfaces and precipitation was controlled to prevent clogging of the injection well by manipulating the injection fluid velocity. These experiments demonstrate that microbially induced carbonate precipitation can successfully be used to grout a fracture under constantly flowing conditions and may be a viable alternative to cement based grouts when a high level of hydraulic sealing is required and chemical grouts when a more durable grout is required.

Tracing the origins of success: implications for successful aging.

Science.gov (United States)

Peterson, Nora M; Martin, Peter

2015-02-01

This paper addresses the debate about the use of the term "successful aging" from a humanistic, rather than behavioral, perspective. It attempts to uncover what success, a term frequently associated with aging, is: how can it be defined and when did it first come into use? In this paper, we draw from a number of humanistic perspectives, including the historical and linguistic, in order to explore the evolution of the term "success." We believe that words and concepts have deep implications for how concepts (such as aging) are culturally and historically perceived. We take a comparative approach, turning to the etymological roots of this term in British, French, and German literature. According to the earliest entries of the term in the Oxford English Dictionary, events can have good or bad success. Another definition marks success as outcome oriented. Often used in the context of war, religion, and medicine, the neutral, but often negative, use of "success" in literature of the Renaissance demonstrates the tensions that surround the word, and suggests that success is something to be approached carefully. Ignoring the ambiguous origins of success erases the fact that aging in earlier centuries echoes much of the same ambivalence with which many people discuss it today. Attending to the origins of success can help gerontologists understand the humanistic tradition behind their inquiry into what successful aging means today. © The Author 2014. Published by Oxford University Press on behalf of The Gerontological Society of America. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Icebergs, sea ice, blue carbon and Antarctic climate feedbacks.

Science.gov (United States)

Barnes, David K A; Fleming, Andrew; Sands, Chester J; Quartino, Maria Liliana; Deregibus, Dolores

2018-06-28

Sea ice, including icebergs, has a complex relationship with the carbon held within animals (blue carbon) in the polar regions. Sea-ice losses around West Antarctica's continental shelf generate longer phytoplankton blooms but also make it a hotspot for coastal iceberg disturbance. This matters because in polar regions ice scour limits blue carbon storage ecosystem services, which work as a powerful negative feedback on climate change (less sea ice increases phytoplankton blooms, benthic growth, seabed carbon and sequestration). This resets benthic biota succession (maintaining regional biodiversity) and also fertilizes the ocean with nutrients, generating phytoplankton blooms, which cascade carbon capture into seabed storage and burial by benthos. Small icebergs scour coastal shallows, whereas giant icebergs ground deeper, offshore. Significant benthic communities establish where ice shelves have disintegrated (giant icebergs calving), and rapidly grow to accumulate blue carbon storage. When 5000 km 2 giant icebergs calve, we estimate that they generate approximately 10 6 tonnes of immobilized zoobenthic carbon per year (t C yr -1 ). However, their collisions with the seabed crush and recycle vast benthic communities, costing an estimated 4 × 10 4  t C yr -1 We calculate that giant iceberg formation (ice shelf disintegration) has a net potential of approximately 10 6  t C yr -1 sequestration benefits as well as more widely known negative impacts.This article is part of the theme issue 'The marine system of the West Antarctic Peninsula: status and strategy for progress in a region of rapid change'. © 2018 The Authors.

Aluminium phosphate sulphate minerals (APS) associated with proterozoic unconformity-type uranium deposits: crystal-chemical characterisation and petrogenetic significance; Les sulfates phosphates d'aluminium hydrates (APS) dans l'environnement des gisements d'uranium associes a une discordance proterozoique: caracterisation cristallochimique et signification petrogenetique

Energy Technology Data Exchange (ETDEWEB)

Gaboreau, St

2005-07-01

Aluminium phosphate sulfate minerals (APS) are particularly widespread and spatially associated with hydrothermal clay alteration in both the East Alligator River Uranium Field (Northern Territory, Australia) and the Athabasca basin (Saskatchewan, Canada), in the environment of proterozoic unconformity-related uranium deposits (URUD). The purpose of this study is both: 1) to characterize the nature and the origin of the APS minerals on both sides of the middle proterozoic unconformity between the overlying sandstones and the underlying metamorphic basement rocks that host the uranium ore bodies, 2) to improve our knowledge on the suitability of these minerals to indicate the paleo-conditions (redox, pH) at which the alteration processes relative to the uranium deposition operated. The APS minerals result from the interaction of oxidising and relatively acidic fluids with aluminous host rocks enriched in monazite. Several APS-bearing clay assemblages and APS crystal-chemistry have also been distinguished as a function of the distance from the uranium ore bodies or from the structural discontinuities which drained the hydrothermal solutions during the mineralisation event. One of the main results of this study is that the index mineral assemblages, used in the recent literature to describe the alteration zones around the uranium ore bodies, can be theoretically predicted by a set of thermodynamic calculations which simulate different steps of fluid-rock interaction processes related to a downward penetrating of hyper-saline, oxidizing and acidic diagenetic fluids through the lower sandstone units of the basins and then into the metamorphic basement rocks. The above considerations and the fact that APS with different crystal-chemical compositions crystallized in a range of fO{sub 2} and pH at which uranium can either be transported in solution or precipitated as uraninite in the host-rocks make these minerals not only good markers of the degree of alteration of the

Control of neuronal network organization by chemical surface functionalization of multi-walled carbon nanotube arrays

International Nuclear Information System (INIS)

Liu Jie; Bibari, Olivier; Marchand, Gilles; Benabid, Alim-Louis; Sauter-Starace, Fabien; Appaix, Florence; De Waard, Michel

2011-01-01

Carbon nanotube substrates are promising candidates for biological applications and devices. Interfacing of these carbon nanotubes with neurons can be controlled by chemical modifications. In this study, we investigated how chemical surface functionalization of multi-walled carbon nanotube arrays (MWNT-A) influences neuronal adhesion and network organization. Functionalization of MWNT-A dramatically modifies the length of neurite fascicles, cluster inter-connection success rate, and the percentage of neurites that escape from the clusters. We propose that chemical functionalization represents a method of choice for developing applications in which neuronal patterning on MWNT-A substrates is required.

Control of neuronal network organization by chemical surface functionalization of multi-walled carbon nanotube arrays

Energy Technology Data Exchange (ETDEWEB)

Liu Jie; Bibari, Olivier; Marchand, Gilles; Benabid, Alim-Louis; Sauter-Starace, Fabien [CEA, LETI-Minatec, 17 Rue des Martyrs, 38054 Grenoble Cedex 9 (France); Appaix, Florence; De Waard, Michel, E-mail: fabien.sauter@cea.fr, E-mail: michel.dewaard@ujf-grenoble.fr [Inserm U836, Grenoble Institute of Neuroscience, Site Sante la Tronche, Batiment Edmond J Safra, Chemin Fortune Ferrini, BP170, 38042 Grenoble Cedex 09 (France)

2011-05-13

Carbon nanotube substrates are promising candidates for biological applications and devices. Interfacing of these carbon nanotubes with neurons can be controlled by chemical modifications. In this study, we investigated how chemical surface functionalization of multi-walled carbon nanotube arrays (MWNT-A) influences neuronal adhesion and network organization. Functionalization of MWNT-A dramatically modifies the length of neurite fascicles, cluster inter-connection success rate, and the percentage of neurites that escape from the clusters. We propose that chemical functionalization represents a method of choice for developing applications in which neuronal patterning on MWNT-A substrates is required.

Hierarchical porous nitrogen-doped partial graphitized carbon monoliths for supercapacitor

Energy Technology Data Exchange (ETDEWEB)

Yu, Yifeng; Du, Juan; Liu, Lei; Wang, Guoxu; Zhang, Hongliang; Chen, Aibing, E-mail: chen-ab@163.com [Hebei University of Science and Technology, College of Chemical and Pharmaceutical Engineering (China)

2017-03-15

Porous carbon monoliths have attracted great interest in many fields due to their easy availability, large specific surface area, desirable electronic conductivity, and tunable pore structure. In this work, hierarchical porous nitrogen-doped partial graphitized carbon monoliths (N–MC–Fe) with ordered mesoporous have been successfully synthesized by using resorcinol-formaldehyde as precursors, iron salts as catalyst, and mixed triblock copolymers as templates via a one-step hydrothermal method. In the reactant system, hexamethylenetetramine (HMT) is used as nitrogen source and one of the carbon precursors under hydrothermal conditions instead of using toxic formaldehyde. The N–MC–Fe show hierarchically porous structures, with interconnected macroporous and ordered hexagonally arranged mesoporous. Nitrogen element is in situ doped into carbon through decomposition of HMT. Iron catalyst is helpful to improve the graphitization degree and pore volume of N–MC–Fe. The synthesis strategy is user-friendly, cost-effective, and can be easily scaled up for production. As supercapacitors, the N–MC–Fe show good capacity with high specific capacitance and good electrochemical stability.

Synthesis of carbon nanotubes by CCVD of natural gas using hydrotreating catalysts

Directory of Open Access Journals (Sweden)

Ahmed E. Awadallah

2012-12-01

Full Text Available Carbon nanotubes have been successfully synthesized using the catalytic chemical vapor deposition (CCVD technique over typical refining hydrotreating catalysts (hydrodesulfurization and hydrodenitrogenation containing Ni–Mo and Co–Mo supported on Al2O3 catalysts at 700°C in a fixed bed horizontal reactor using natural gas as a carbon source. The catalysts and the as-grown CNTs were characterized by transmission electron microscopy, HRTEM, X-ray diffraction patterns, EDX and TGA–DTG. The obtained data clarified that the Ni–Mo catalyst gives higher yield, higher purity and selectivity for CNTs compared to Co–Mo catalyst. XRD, TEM and TGA reveal also that the Ni–Mo catalyst produces mostly CNTs with different diameters whereas the Co–Mo catalyst produces largely amorphous carbon.

Heat transfer augmentation in rectangular micro channel covered with vertically aligned carbon nanotubes

NARCIS (Netherlands)

Taha, T.J.; Lefferts, Leonardus; van der Meer, Theodorus H.

2016-01-01

An experimental heat transfer investigation was carried out to examine the influence of carbon nanotubes (CNTs) layer deposits on the convective heat transfer performance inside rectangular microchannels. Successful synthesis of vertically aligned CNTs was achieved using a catalytic vapor deposition

Geochemical elements mobility during the history of a paleo-Proterozoic clastic sedimentary basin, the Athabasca Basin (Saskatchewan, Canada)

International Nuclear Information System (INIS)

Kister, P.

2003-10-01

In order to understand the mechanisms of migration and deposition of ore elements, it is essential to determine the timing, source, and destination of the geochemical element mass transfers and/or transportation on a scale encompassing the great sedimentary. The purpose of this study was to trace and to date the element migrations that occurred during the history of a Paleo-proterozoic clastic sedimentary basin, the Athabasca Basin, which hosts the world's largest and richest uranium deposits. As this geological environment was proved to be efficient to preserve high grade ore deposits for over more than one billion years, it provides an opportunity to study the mobility of some elements in a context that shows analogies with deep geological nuclear waste disposals. The natural analogies of interest include (i) uranium oxide and spent nuclear fuel; (ii) clay alteration halo and near field barrier, (iii) Athabasca sandstone cover and far-field barrier. Five research axis: (1) 3D modelling of the distribution of the main minerals and of some trace elements (U, Pb, Zr, Th, REE, Y, Rb, Sr) on a basin-wide scale and in the U mineralized zones, using the Gocad software. The models have been compared with detailed mineralogical studies performed on selected samples. (2) Pb-Pb and Rb-Sr systematics by TIMS (3) Mass balance calculation of the average Pb/U ratio at the scale of the deposit to evaluate whether the present day amount of radiogenic lead is sufficient to explain a U deposition in one or several episodes (geostatistical tools on Gocad) (4) Thermodynamic modelling of the mineralogical evolution of the Athabasca basin, considering the main mineral present in the sandstone (Phreeqc and Supcrt softwares) (5) U-Pb geochronology of uranium oxides using a 3 step approach: (i) optical and scanning electron microscopy; (ii) electron microprobe; (iii) ion microprobe (SIMS). The purpose was to study the long term stability of the uranium oxides and to characterise the

Hierarchical mesoporous/microporous carbon with graphitized frameworks for high-performance lithium-ion batteries

Directory of Open Access Journals (Sweden)

Yingying Lv

2014-11-01

Full Text Available A hierarchical meso-/micro-porous graphitized carbon with uniform mesopores and ordered micropores, graphitized frameworks, and extra-high surface area of ∼2200 m2/g, was successfully synthesized through a simple one-step chemical vapor deposition process. The commercial mesoporous zeolite Y was utilized as a meso-/ micro-porous template, and the small-molecule methane was employed as a carbon precursor. The as-prepared hierarchical meso-/micro-porous carbons have homogeneously distributed mesopores as a host for electrolyte, which facilitate Li+ ions transport to the large-area micropores, resulting a high reversible lithium ion storage of 1000 mA h/g and a high columbic efficiency of 65% at the first cycle.

DEVELOPMENT OF ACTIVATED CARBONS FROM COAL COMBUSTION BY-PRODUCTS

Energy Technology Data Exchange (ETDEWEB)

Harold H. Schobert; M. Mercedes Maroto-Valer; Zhe Lu

2003-09-30

inferred from their physical and chemical properties. The developed porosity of the activated carbon was a function of the oxygen content, porosity and H/C ratio of the parent unburned carbon feedstock. It was observed that extended activation times and high activation temperatures increased the porosity of the produced activated carbon at the expense of the solid yield. The development of activated carbon from unburned carbon in fly ash has been proven to be a success by this study in terms of the higher surface areas of the resultant activated carbons, which are comparable with commercial activated carbons. However, unburned carbon samples obtained from coal-fired power plants as by-product have high ash content, which is unwanted for the production of activated carbons. Therefore, the separation of unburned carbon from the fly ash is expected to be beneficial for the utilization of unburned carbon to produce activated carbons with low ash content.

Anoxygenic photosynthesis controls oxygenic photosynthesis in a cyanobacterium from a sulfidic spring.

Science.gov (United States)

Klatt, Judith M; Al-Najjar, Mohammad A A; Yilmaz, Pelin; Lavik, Gaute; de Beer, Dirk; Polerecky, Lubos

2015-03-01

Before the Earth's complete oxygenation (0.58 to 0.55 billion years [Ga] ago), the photic zone of the Proterozoic oceans was probably redox stratified, with a slightly aerobic, nutrient-limited upper layer above a light-limited layer that tended toward euxinia. In such oceans, cyanobacteria capable of both oxygenic and sulfide-driven anoxygenic photosynthesis played a fundamental role in the global carbon, oxygen, and sulfur cycle. We have isolated a cyanobacterium, Pseudanabaena strain FS39, in which this versatility is still conserved, and we show that the transition between the two photosynthetic modes follows a surprisingly simple kinetic regulation controlled by this organism's affinity for H2S. Specifically, oxygenic photosynthesis is performed in addition to anoxygenic photosynthesis only when H2S becomes limiting and its concentration decreases below a threshold that increases predictably with the available ambient light. The carbon-based growth rates during oxygenic and anoxygenic photosynthesis were similar. However, Pseudanabaena FS39 additionally assimilated NO3 (-) during anoxygenic photosynthesis. Thus, the transition between anoxygenic and oxygenic photosynthesis was accompanied by a shift of the C/N ratio of the total bulk biomass. These mechanisms offer new insights into the way in which, despite nutrient limitation in the oxic photic zone in the mid-Proterozoic oceans, versatile cyanobacteria might have promoted oxygenic photosynthesis and total primary productivity, a key step that enabled the complete oxygenation of our planet and the subsequent diversification of life. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

Educational Attainment: Success to the Successful

Science.gov (United States)

Anthony, Peter; Gould, David; Smith, Gina

2013-01-01

Systems archetypes are patterns of structure found in systems that are helpful in understanding some of the dynamics within them. The intent of this study was to examine educational attainment data using the success-to-the-successful archetype as a model to see if it helps to explain the inequality observed in the data. Data covering 1990 to 2009…

Carbon sequestration in managed temperate coniferous forests under climate change

Science.gov (United States)

Dymond, Caren C.; Beukema, Sarah; Nitschke, Craig R.; Coates, K. David; Scheller, Robert M.

2016-03-01

Management of temperate forests has the potential to increase carbon sinks and mitigate climate change. However, those opportunities may be confounded by negative climate change impacts. We therefore need a better understanding of climate change alterations to temperate forest carbon dynamics before developing mitigation strategies. The purpose of this project was to investigate the interactions of species composition, fire, management, and climate change in the Copper-Pine Creek valley, a temperate coniferous forest with a wide range of growing conditions. To do so, we used the LANDIS-II modelling framework including the new Forest Carbon Succession extension to simulate forest ecosystems under four different productivity scenarios, with and without climate change effects, until 2050. Significantly, the new extension allowed us to calculate the net sector productivity, a carbon accounting metric that integrates aboveground and belowground carbon dynamics, disturbances, and the eventual fate of forest products. The model output was validated against literature values. The results implied that the species optimum growing conditions relative to current and future conditions strongly influenced future carbon dynamics. Warmer growing conditions led to increased carbon sinks and storage in the colder and wetter ecoregions but not necessarily in the others. Climate change impacts varied among species and site conditions, and this indicates that both of these components need to be taken into account when considering climate change mitigation activities and adaptive management. The introduction of a new carbon indicator, net sector productivity, promises to be useful in assessing management effectiveness and mitigation activities.

Soft-Template-Synthesized Mesoporous Carbon for Oral Drug Delivery

Energy Technology Data Exchange (ETDEWEB)

Saha, Dipendu [ORNL; Warren, Kaitlyn E [ORNL; Naskar, Amit K [ORNL