Asua, J.M.; Beuermann, S.; Buback, M.; Castignolles, P.; Charleux, B.; Gilbert, R.G.; Hutchinson, R.A.; Leiza, J.R.; Nikitin, A.N.; Vairon, J.P.; Herk, van A.M.
2004-01-01
Propagation rate coefficients, kp, for free-radical polymerization of butyl acrylate (BA) previously reported by several groups are critically evaluated. All data were determined by the combination of pulsed-laser polymerization (PLP) and subsequent polymer analysis by size exclusion (SEC)
Nuclear data propagation with burnup. Impact on SFR reactivity coefficients
International Nuclear Information System (INIS)
Buiron, Laurent; Plisson-Rieunier, Daniele
2017-01-01
For the next generation fast reactor design, the Generation IV International Forum (GIF) defined global objectives in terms of safety improvement, sustainability, waste minimization and non-proliferation. Among the possibilities studied at CEA, Sodium cooled Fast Reactor (SFR) are studied as potential industrial tools for next decade's deployment. Many efforts have been made in the last years to obtain advanced industrial core designs that comply with these goals. Concerning safety issues, particular efforts have been made in order to obtain core designs that can be resilient to accidental transients. The 'safety' level of such new designs is often characterized by their 'natural' behavior under unprotected transients such as loss of flow or hypothetical transient over power. Transient analysis needs several accurate neutronic input data such as reactivity coefficient and kinetic parameters. Beside estimation of the level of 'absolute' values, associated uncertainties have also to be evaluated for the whole set of relevant data. These estimations have to be performed for different core state such as end of cycle core for feedback coefficient. This means that uncertainties have to be obtained not only a fixed time but also have to be propagated all through irradiation. To do so, we need to couple Boltzman and Bateman equations at sensitivities level. The coupling process could be done with the help of the perturbation theory which gives adapted framework suited for deterministic calculation codes. This coupling is currently in progress in ERANOS code system. The actual implementation gives access to estimation of sensitivities for both reactivity coefficients and mass balance. After a brief theoretical description of Boltzman/Bateman coupling capabilities in ERANOS, the study presented in this paper focuses on sensitivity and uncertainties estimation for the main feedback coefficients involved in fast reactor transients: the
Rate coefficient for the reaction N + NO
Fox, J. L.
1994-01-01
Evidence has been advanced that the rate coefficient for the reaction N + NO right arrow N2 + O has a small positive temperature dependence at the high temperatures (900 to 1500 K) that prevail in the terrestrial middle and upper thermosphere by Siskind and Rusch (1992), and at the low temperatures (100 to 200 K) of the Martian lower thermosphere by Fox (1993). Assuming that the rate coefficient recommended by the Jet Propulsion Laboratory evaluation (DeMore et al., 1992) is accurate at 300 K, we derive here the low temperature value of the activation energy for this reaction and thus the rate coefficient that best fits the Viking 1 measured NO densities. We find that the fit is acceptable for a rate coefficient of about 1.3 x 10(exp -10)(T/300)(exp 0.5)exp(-400/T) and better for a value of about 2.5 x 10(exp -10)(T/300)(exp 0.5)exp(-600/T)cu cm/s.
Reaction rate calculations via transmission coefficients
International Nuclear Information System (INIS)
Feit, M.D.; Alder, B.J.
1985-01-01
The transmission coefficient of a wavepacket traversing a potential barrier can be determined by steady state calculations carried out in imaginary time instead of by real time dynamical calculations. The general argument is verified for the Eckart barrier potential by a comparison of transmission coefficients calculated from real and imaginary time solutions of the Schroedinger equation. The correspondence demonstrated here allows a formulation for the reaction rate that avoids difficulties due to both rare events and explicitly time dependent calculations. 5 refs., 2 figs
Atomic rate coefficients in a degenerate plasma
Aslanyan, Valentin; Tallents, Greg
2015-11-01
The electrons in a dense, degenerate plasma follow Fermi-Dirac statistics, which deviate significantly in this regime from the usual Maxwell-Boltzmann approach used by many models. We present methods to calculate the atomic rate coefficients for the Fermi-Dirac distribution and present a comparison of the ionization fraction of carbon calculated using both models. We have found that for densities close to solid, although the discrepancy is small for LTE conditions, there is a large divergence from the ionization fraction by using classical rate coefficients in the presence of strong photoionizing radiation. We have found that using these modified rates and the degenerate heat capacity may affect the time evolution of a plasma subject to extreme ultraviolet and x-ray radiation such as produced in free electron laser irradiation of solid targets.
Determining the Viscosity Coefficient for Viscoelastic Wave Propagation in Rock Bars
Niu, Leilei; Zhu, Wancheng; Li, Shaohua; Guan, Kai
2018-05-01
Rocks with microdefects exhibit viscoelastic behavior during stress wave propagation. The viscosity coefficient of the wave can be used to characterize the attenuation as the wave propagates in rock. In this study, a long artificial bar with a readily adjustable viscosity coefficient was fabricated to investigate stress wave attenuation. The viscoelastic behavior of the artificial bar under dynamic loading was investigated, and the initial viscoelastic coefficient was obtained based on the amplitude attenuation of the incident harmonic wave. A one-dimensional wave propagation program was compiled to reproduce the time history of the stress wave measured during the experiments, and the program was well fitted to the Kelvin-Voigt model. The attenuation and dispersion of the stress wave in long artificial viscoelastic bars were quantified to accurately determine the viscoelastic coefficient. Finally, the method used to determine the viscoelastic coefficient of a long artificial bar based on the experiments and numerical simulations was extended to determine the viscoelastic coefficient of a short rock bar. This study provides a new method of determining the viscosity coefficient of rock.
International Nuclear Information System (INIS)
Wang, L.; Feng, S.
1989-01-01
The relation between the reflection coefficients and the Green's function for a coherent wave propagation in a disordered elastic-scattering medium is derived. The sum rule of the reflection and transmission coefficients corresponding to probability conservation is shown rigorously for an arbitrary scattering potential. The correlation function of the reflection coefficients is then calculated by using a Feynman-diagrammatic approach in the weak-localized multiple-scattering regime (L much-gt l much-gt λ). The result is in agreement with recent experiments on the so-called ''memory effect'' in reflection coefficients. A more general condition under which the memory effect can occur is derived. Differences between the the correlation functions for reflection and that for transmission are discussed
A method to measure the diffusion coefficient by neutron wave propagation for limited samples
International Nuclear Information System (INIS)
Woznicka, U.
1986-03-01
A study has been made of the use of the neutron wave and pulse propagation method for measurement of thermal neutron diffusion parameters. Earlier works an homogenous and heterogeneous media are reviewed. A new method is sketched for the determination of the diffusion coefficient for samples of limited size. The principle is to place a relatively thin slab of the material between two blocks of a medium with known properties. The advantages and disadvantages of the method are discussed. (author)
Seeded emulsion polymerization of butadiene. 1. The propagation rate coefficient
Verdurmen, E.M.F.J.; Dohmen, E.H.M.; Verstegen, J.M.; Maxwell, I.A.; German, A.L.; Gilbert, R.G.
1993-01-01
The kinetics of the emulsifier-free, seeded polymn. of butadiene (I) at 60 Deg in Smith-Ewart interval III were studied in presence of Na peroxodisulfate initiator and tert-dodecyl mercaptan. The fractional conversion was based on gravimetrically calibrated online densitometry and was highly
The Influence of Particle Charge on Heterogeneous Reaction Rate Coefficients
Aikin, A. C.; Pesnell, W. D.
2000-01-01
The effects of particle charge on heterogeneous reaction rates are presented. Many atmospheric particles, whether liquid or solid are charged. This surface charge causes a redistribution of charge within a liquid particle and as a consequence a perturbation in the gaseous uptake coefficient. The amount of perturbation is proportional to the external potential and the square of the ratio of debye length in the liquid to the particle radius. Previous modeling has shown how surface charge affects the uptake coefficient of charged aerosols. This effect is now included in the heterogeneous reaction rate of an aerosol ensemble. Extension of this analysis to ice particles will be discussed and examples presented.
Efficient calculation of atomic rate coefficients in dense plasmas
Aslanyan, Valentin; Tallents, Greg J.
2017-03-01
Modelling electron statistics in a cold, dense plasma by the Fermi-Dirac distribution leads to complications in the calculations of atomic rate coefficients. The Pauli exclusion principle slows down the rate of collisions as electrons must find unoccupied quantum states and adds a further computational cost. Methods to calculate these coefficients by direct numerical integration with a high degree of parallelism are presented. This degree of optimization allows the effects of degeneracy to be incorporated into a time-dependent collisional-radiative model. Example results from such a model are presented.
Effective dose rate coefficients for exposure to contaminated soil
Energy Technology Data Exchange (ETDEWEB)
Veinot, K.G. [Easterly Scientific, Knoxville, TN (United States); Y-12 National Security Complex, Oak Ridge, TN (United States); Eckerman, K.F.; Easterly, C.E. [Easterly Scientific, Knoxville, TN (United States); Bellamy, M.B.; Hiller, M.M.; Dewji, S.A. [Oak Ridge National Laboratory, Center for Radiation Protection Knowledge, Oak Ridge, TN (United States); Hertel, N.E. [Oak Ridge National Laboratory, Center for Radiation Protection Knowledge, Oak Ridge, TN (United States); Georgia Institute of Technology, Atlanta, GA (United States); Manger, R. [University of California San Diego, Department of Radiation Medicine and Applied Sciences, La Jolla, CA (United States)
2017-08-15
The Oak Ridge National Laboratory Center for Radiation Protection Knowledge has undertaken calculations related to various environmental exposure scenarios. A previous paper reported the results for submersion in radioactive air and immersion in water using age-specific mathematical phantoms. This paper presents age-specific effective dose rate coefficients derived using stylized mathematical phantoms for exposure to contaminated soils. Dose rate coefficients for photon, electron, and positrons of discrete energies were calculated and folded with emissions of 1252 radionuclides addressed in ICRP Publication 107 to determine equivalent and effective dose rate coefficients. The MCNP6 radiation transport code was used for organ dose rate calculations for photons and the contribution of electrons to skin dose rate was derived using point-kernels. Bremsstrahlung and annihilation photons of positron emission were evaluated as discrete photons. The coefficients calculated in this work compare favorably to those reported in the US Federal Guidance Report 12 as well as by other authors who employed voxel phantoms for similar exposure scenarios. (orig.)
ROVIBRATIONAL QUENCHING RATE COEFFICIENTS OF HD IN COLLISIONS WITH He
International Nuclear Information System (INIS)
Nolte, J. L.; Stancil, P. C.; Lee, T.-G.; Balakrishnan, N.; Forrey, R. C.
2012-01-01
Along with H 2 , HD has been found to play an important role in the cooling of the primordial gas for the formation of the first stars and galaxies. It has also been observed in a variety of cool molecular astrophysical environments. The rate of cooling by HD molecules requires knowledge of collisional rate coefficients with the primary impactors, H, He, and H 2 . To improve knowledge of the collisional properties of HD, we present rate coefficients for the He-HD collision system over a range of collision energies from 10 –5 to 5 × 10 3 cm –1 . Fully quantum mechanical scattering calculations were performed for initial HD rovibrational states of j = 0 and 1 for v = 0-17 which utilized accurate diatom rovibrational wave functions. Rate coefficients of all Δv = 0, –1, and –2 transitions are reported. Significant discrepancies with previous calculations, which adopted a small basis and harmonic HD wave functions for excited vibrational levels, were found for the highest previously considered vibrational state of v = 3. Applications of the He-HD rate coefficients in various astrophysical environments are briefly discussed.
Effect of overloads on fatigue crack propagation rate
International Nuclear Information System (INIS)
Kogaev, V.P.; Bojtsov, B.V.; Petukhov, Yu.V
1986-01-01
An overload coefficient Q, the number of overload cycles Nsub(0), the value of the stress intensity coefficient swing of basic loading conditions ΔK are experimentally studied for their effect on the delay of the fatigue crack propagation Nsub(D) in 30KhGSNA steel. Results of the study are presented. It is shown that as a result of single overloads the value attains 60 - 10 thous. cycles. The delay Nsub(D) grows with the overload coefficient Q=Ksub(max)sup(0)/Ksub(max) and the number of the overload cycles Nsub(0). The regularity indicated is described by the equations valid within the limits of variation in Q and Nsub(0) values studied in the paper
Determination of sedimentation rates and absorption coefficient of ...
African Journals Online (AJOL)
DR. MIKE HORSFALL
particles have pores that can absorb radiation. Gamma rays have been used to study the absorption coefficients of cobalt(II) insoluble compounds (Essien and Ekpe, 1998), densities of marine sediments. (Gerland and Villinger, 1995) and soil particle-size distribution (Vaz et al., 1992). In this study, sedimentation rates of ...
Dielectronic recombination rate coefficients of initially rubidium-like tungsten
International Nuclear Information System (INIS)
Wu, Z.; Zhang, Y.; Fu, Y.; Dong, C.; Surzhykov, A.; Fritzsche, S.
2015-01-01
Dielectric recombination (DR) is a dominant electron recombination process in plasmas. Tungsten ions are expected to be prominent impurities in fusion plasmas so the knowledge of DR rate coefficient of tungsten ions is important to model fusion plasmas. Ab initio calculations of DR rate coefficients of initially rubidium-like W 37+ ions have been performed for the electron temperatures from 1 eV to 5*10 4 eV, by using the Flexible Atomic Code based on the relativistic configuration-interaction method. Special attention has been paid to the partial contributions to total DR rate coefficients as associated with the excitation of individual subshells. A detailed comparison of the calculations shows that the excitation from 4p subshell dominates total DR rate coefficients followed by the excitations from 4s and 4d subshells, while the contribution of excitations from 3l (l = s, p, d) subshells becomes important only at high temperatures. Besides, it is found that the electron excitations associated with Δn = 0, 1 dominate at low-temperature plasmas, however, the excitations associated with Δn ≥ 2 become non-negligible at high-temperature ones
Rate coefficients for hydrogen abstraction reaction of pinonaldehyde
Indian Academy of Sciences (India)
The H abstraction reaction from the –CHO group was found to be the most dominant reaction channelamong all the possible reaction pathways and its corresponding rate coefficient at 300 K is kEckart's unsymmetrical= 3.86 ×10-10 cm3 molecule-1 s-1. Whereas the channel with immediate lower activation energy is the ...
The 95% confidence intervals of error rates and discriminant coefficients
Directory of Open Access Journals (Sweden)
Shuichi Shinmura
2015-02-01
Full Text Available Fisher proposed a linear discriminant function (Fisher’s LDF. From 1971, we analysed electrocardiogram (ECG data in order to develop the diagnostic logic between normal and abnormal symptoms by Fisher’s LDF and a quadratic discriminant function (QDF. Our four years research was inferior to the decision tree logic developed by the medical doctor. After this experience, we discriminated many data and found four problems of the discriminant analysis. A revised Optimal LDF by Integer Programming (Revised IP-OLDF based on the minimum number of misclassification (minimum NM criterion resolves three problems entirely [13, 18]. In this research, we discuss fourth problem of the discriminant analysis. There are no standard errors (SEs of the error rate and discriminant coefficient. We propose a k-fold crossvalidation method. This method offers a model selection technique and a 95% confidence intervals (C.I. of error rates and discriminant coefficients.
The HD+ dissociative recombination rate coefficient at low temperature
Directory of Open Access Journals (Sweden)
Wolf A.
2015-01-01
Full Text Available The effect of the rotational temperature of the ions is considered for low-energy dissociative recombination (DR of HD+. Merged beams measurements with HD+ ions of a rotational temperature near 300 K are compared to multichannel quantum defect theory calculations. The thermal DR rate coefficient for a Maxwellian electron velocity distribution is derived from the merged-beams data and compared to theoretical results for a range of rotational temperatures. Good agreement is found for the theory with 300 K rotational temperature. For a low-temperature plasma environment where also the rotational temperature assumes 10 K, theory predicts a considerably higher thermal DR rate coefficient. The origin of this is traced to predicted resonant structures of the collision-energy dependent DR cross section at few-meV collision energies for the particular case of HD+ ions in the rotational ground state.
Bruhat, Lucile; Segall, Paul
2017-10-01
Interpretations of interseismic slip deficit on the northern Cascadia megathrust are complicated by an enigmatic `gap' between the downdip limit of the locked region, inferred from kinematic inversions of deformation rates, and the top of the episodic tremor and slip (ETS) zone. Recent inversions of global positioning system (GPS) and tide gauge/leveling data for shear stress rates acting on the megathrust found a ˜21 km locking depth with a steep slip-rate gradient at its base is required to fit the data. Previous studies have assumed the depth distribution of interseismic slip rate to be time invariant; however, steep slip-rate gradients could also result from the updip propagation of slip into the locked region. This study explores models where interseismic slip penetrates up into the locked zone. We consider the creeping region, corresponding to the gap and the ETS zone, as a quasi-static crack driven by the plate velocity at its downdip end. We derive a simple model that allows for crack propagation over time, and provides analytical expressions for stress drop within the crack, slip and slip rate on the fault. It is convenient to expand the non-singular slip-rate distribution in a sum of Chebyshev polynomials. Estimation of the polynomial coefficients is underdetermined, yet provides a useful way of testing particular solutions and provides bounds on the updip propagation rate. When applied to the deformation rates in northern Cascadia, best-fitting models reveal that a very slow updip propagation, between 30 and 120 m yr-1 along the fault, could explain the steep slip-rate profile, needed to fit the data. This work provides a new tool for estimating interseismic slip rates, between purely kinematic inversions and full physics-based modeling, allowing for the possibility for updip expansion of the creeping zone.
Collisional excitation rate coefficients for lithium-like ions
International Nuclear Information System (INIS)
Cochrane, D.M.; McWhirter, R.W.P.
1982-11-01
This report takes all the available good quality quantal calculations of excitation cross-sections by electron collision for lithium-like ions and intercompares them. There is a comparison also with the small amount of experimental data of 2s 2 S - 2p 2 P cross-sections. On the basis of all of these data, a choice is made of the best cross-sections and these are integrated over Maxwellians to give excitation rate coefficients. In general data are available for up to seven transitions in five or six ions. When the results are compared along the iso-electronic sequence, trends are established which allow estimates to be made of the rate coefficients for these seven transitions for any lithium-like ion of nuclear charge greater than boron. The results are presented graphically and as simple formulae. The formulae reproduce the source data at various levels of accuracy from about +-1% for individual ions to universal formulae of accuracy better than +-15% in the relevant temperature ranges. (author)
Automatic estimation of pressure-dependent rate coefficients.
Allen, Joshua W; Goldsmith, C Franklin; Green, William H
2012-01-21
A general framework is presented for accurately and efficiently estimating the phenomenological pressure-dependent rate coefficients for reaction networks of arbitrary size and complexity using only high-pressure-limit information. Two aspects of this framework are discussed in detail. First, two methods of estimating the density of states of the species in the network are presented, including a new method based on characteristic functional group frequencies. Second, three methods of simplifying the full master equation model of the network to a single set of phenomenological rates are discussed, including a new method based on the reservoir state and pseudo-steady state approximations. Both sets of methods are evaluated in the context of the chemically-activated reaction of acetyl with oxygen. All three simplifications of the master equation are usually accurate, but each fails in certain situations, which are discussed. The new methods usually provide good accuracy at a computational cost appropriate for automated reaction mechanism generation.
Thermodynamically based constraints for rate coefficients of large biochemical networks.
Vlad, Marcel O; Ross, John
2009-01-01
Wegscheider cyclicity conditions are relationships among the rate coefficients of a complex reaction network, which ensure the compatibility of kinetic equations with the conditions for thermodynamic equilibrium. The detailed balance at equilibrium, that is the equilibration of forward and backward rates for each elementary reaction, leads to compatibility between the conditions of kinetic and thermodynamic equilibrium. Therefore, Wegscheider cyclicity conditions can be derived by eliminating the equilibrium concentrations from the conditions of detailed balance. We develop matrix algebra tools needed to carry out this elimination, reexamine an old derivation of the general form of Wegscheider cyclicity condition, and develop new derivations which lead to more compact and easier-to-use formulas. We derive scaling laws for the nonequilibrium rates of a complex reaction network, which include Wegscheider conditions as a particular case. The scaling laws for the rates are used for clarifying the kinetic and thermodynamic meaning of Wegscheider cyclicity conditions. Finally, we discuss different ways of using Wegscheider cyclicity conditions for kinetic computations in systems biology.
Automatic estimation of pressure-dependent rate coefficients
Allen, Joshua W.; Goldsmith, C. Franklin; Green, William H.
2012-01-01
A general framework is presented for accurately and efficiently estimating the phenomenological pressure-dependent rate coefficients for reaction networks of arbitrary size and complexity using only high-pressure-limit information. Two aspects of this framework are discussed in detail. First, two methods of estimating the density of states of the species in the network are presented, including a new method based on characteristic functional group frequencies. Second, three methods of simplifying the full master equation model of the network to a single set of phenomenological rates are discussed, including a new method based on the reservoir state and pseudo-steady state approximations. Both sets of methods are evaluated in the context of the chemically-activated reaction of acetyl with oxygen. All three simplifications of the master equation are usually accurate, but each fails in certain situations, which are discussed. The new methods usually provide good accuracy at a computational cost appropriate for automated reaction mechanism generation. This journal is © the Owner Societies.
International Nuclear Information System (INIS)
Decanini, Yves; Folacci, Antoine
2006-01-01
Having in mind applications to gravitational wave theory (in connection with the radiation reaction problem), stochastic semiclassical gravity (in connection with the regularization of the noise kernel) and quantum field theory in higher-dimensional curved spacetime (in connection with the Hadamard regularization of the stress-energy tensor), we improve the DeWitt-Schwinger and Hadamard representations of the Feynman propagator of a massive scalar field theory defined on an arbitrary gravitational background by deriving higher-order terms for the covariant Taylor series expansions of the geometrical coefficients--i.e., the DeWitt and Hadamard coefficients--that define them
Huang, Peiyan; Liu, Guangwan; Guo, Xinyan; Huang, Man
2008-11-01
The experimental research on fatigue crack propagation rate of reinforced concrete (RC) beams strengthened with carbon fiber laminate (CFL) is carried out by MTS system in this paper. The experimental results show that, the main crack propagation on strengthened beam can be summarized into three phases: 1) fast propagation phase; 2) steady propagation and rest phase; 3) unsteady propagation phase. The phase 2-i.e. steady propagation and rest stage makes up about 95% of fatigue life of the strengthened beam. The propagation rate of the main crack, da/dN, in phase 2 can be described by Paris formula, and the constant C and m can be confirmed by the fatigue crack propagation experiments of the RC beams strengthened with CFL under three-point bending loads.
Determination of sedimentation rates and absorption coefficient of ...
African Journals Online (AJOL)
2+ has a higher sedimentation rate of 5.10x10-2 s-1 while Ni2+ has the lowest sedimentation rates of 1.10 x10-3. The rate of sedimentation of the metal carbonates decreased in the order: Zn2+ > Cd2+ > Cu2+ > Co2+ > Ni2+. The order ...
Nuclear Data Uncertainty Propagation to Reactivity Coefficients of a Sodium Fast Reactor
Herrero, J. J.; Ochoa, R.; Martínez, J. S.; Díez, C. J.; García-Herranz, N.; Cabellos, O.
2014-04-01
The assessment of the uncertainty levels on the design and safety parameters for the innovative European Sodium Fast Reactor (ESFR) is mandatory. Some of these relevant safety quantities are the Doppler and void reactivity coefficients, whose uncertainties are quantified. Besides, the nuclear reaction data where an improvement will certainly benefit the design accuracy are identified. This work has been performed with the SCALE 6.1 codes suite and its multigroups cross sections library based on ENDF/B-VII.0 evaluation.
Musammil, N M; Porsezian, K; Subha, P A; Nithyanandan, K
2017-02-01
We investigate the dynamics of vector dark solitons propagation using variable coefficient coupled nonlinear Schrödinger (Vc-CNLS) equation. The dark soliton propagation and evolution dynamics in the inhomogeneous system are studied analytically by employing the Hirota bilinear method. It is apparent from our asymptotic analysis that the collision between the dark solitons is elastic in nature. The various inhomogeneous effects on the evolution and interaction between dark solitons are explored, with a particular emphasis on nonlinear tunneling. It is found that the tunneling of the soliton depends on a condition related to the height of the barrier and the amplitude of the soliton. The intensity of the tunneling soliton either forms a peak or a valley, thus retaining its shape after tunneling. For the case of exponential background, the soliton tends to compress after tunneling through the barrier/well. Thus, a comprehensive study of dark soliton pulse evolution and propagation dynamics in Vc-CNLS equation is presented in the paper.
Dielectronic recombination rate coefficients to the excited states of CI from CII
International Nuclear Information System (INIS)
Dubau, J.; Kato, T.; Safronova, U.I.
1998-01-01
The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated including 1s 2 2l 1 2l 2 2l 3 nl (n=2-6, l≤(n-1)) states. The values for the excited states higher than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The rate coefficients to the excited states are fitted to an analytical formula and the fit parameters are given. (author)
Barbosa, Thaís da Silva; Peirone, Silvina; Barrera, Javier A; Abrate, Juan P A; Lane, Silvia I; Arbilla, Graciela; Bauerfeldt, Glauco Favilla
2015-04-14
The kinetics of the cis-3-hexene + OH reaction were investigated by an experimental relative rate method and at the density functional theory level. The experimental set-up consisted of a 200 L Teflon bag, operated at atmospheric pressure and 298 K. OH radicals were produced by the photolysis of H2O2 at 254 nm. Relative rate coefficients were determined by comparing the decays of the cis-3-hexene and reference compounds (cyclohexene, 2-buten-1-ol and allyl ether). The mean second-order rate coefficient value found was (6.27 ± 0.66) × 10(-11) cm(3) molecule(-1) s(-1), the uncertainty being estimated by propagation of errors. Theoretical calculations for the addition reaction of OH to cis-3-hexene have also been performed, at the BHandHLYP/aug-cc-pVDZ level, in order to investigate the reaction mechanism, to clarify the experimental observations and to model the reaction kinetics. Different conformations of the reactants, pre-barrier complexes and saddle points were considered in our calculations. The individual rate coefficients, calculated for each conformer of the reactant, at 298 K, using a microcanonical variational transition state method, are 4.19 × 10(-11) and 1.23 × 10(-10) cm(3) molecule(-1) s(-1). The global rate coefficient was estimated from the Boltzmann distribution of the conformers to be 8.10 × 10(-11) cm(3) molecule(-1) s(-1), which is in agreement with the experimental value. Rate coefficients calculated over the temperature range from 200-500 K are also given. Our results suggest that the complex mechanism, explicitly considering different conformations for the stationary points, must be taken into account for a proper description of the reaction kinetics.
Energy Technology Data Exchange (ETDEWEB)
Kato, T.; Asano, E. [National Institute for Fusion Science, Toki, Gifu (Japan)
1999-06-01
Recombination rate coefficients based on several empirical formulae are compared for ions of H, He, C, N, O, Ne, Na, Mg, Al, Si, S, P, Cl, Ar, Ca, Fe and Ni. The total rate coefficients including radiative recombination and dielectronic recombination are shown in graphs. (author)
The rate coefficients of unimolecular reactions in the systems with power-law distributions
Yin, Cangtao; Guo, Ran; Du, Jiulin
2014-08-01
The rate coefficient formulae of unimolecular reactions are generalized to the systems with the power-law distributions based on nonextensive statistics, and the power-law rate coefficients are derived in the high and low pressure limits, respectively. The numerical analyses are made of the rate coefficients as functions of the ν-parameter, the threshold energy, the temperature and the number of degrees of freedom. We show that the new rate coefficients depend strongly on the ν-parameter different from one (thus from a Boltzmann-Gibbs distribution). Two unimolecular reactions, CH3CO→CH3+CO and CH3NC→CH3CN, are taken as application examples to calculate their power-law rate coefficients, which obtained with the ν-parameters slightly different from one can be exactly in agreement with all the experimental studies on these two reactions in the given temperature ranges.
Sun, Yangbo; Chen, Long; Huang, Bisheng; Chen, Keli
2017-07-01
As a mineral, the traditional Chinese medicine calamine has a similar shape to many other minerals. Investigations of commercially available calamine samples have shown that there are many fake and inferior calamine goods sold on the market. The conventional identification method for calamine is complicated, therefore as a result of the large scale of calamine samples, a rapid identification method is needed. To establish a qualitative model using near-infrared (NIR) spectroscopy for rapid identification of various calamine samples, large quantities of calamine samples including crude products, counterfeits and processed products were collected and correctly identified using the physicochemical and powder X-ray diffraction method. The NIR spectroscopy method was used to analyze these samples by combining the multi-reference correlation coefficient (MRCC) method and the error back propagation artificial neural network algorithm (BP-ANN), so as to realize the qualitative identification of calamine samples. The accuracy rate of the model based on NIR and MRCC methods was 85%; in addition, the model, which took comprehensive multiple factors into consideration, can be used to identify crude calamine products, its counterfeits and processed products. Furthermore, by in-putting the correlation coefficients of multiple references as the spectral feature data of samples into BP-ANN, a BP-ANN model of qualitative identification was established, of which the accuracy rate was increased to 95%. The MRCC method can be used as a NIR-based method in the process of BP-ANN modeling.
Yamaguchi, H.; Takamori, K.; Perrier, P.; Graur, I.; Matsuda, Y.; Niimi, T.
2016-01-01
The viscous slip coefficient for helium-argon binary gas mixture is extracted from the experimental values of the mass flow rate through a microtube. The mass flow rate is measured by the constant-volume method. The viscous slip coefficient was obtained by identifying the measured mass flow rate through a microtube with the corresponding analytical expression, which is a function of the Knudsen number. The measurements were carried out in the slip flow regime where the first-order slip bounda...
Dielectronic recombination rate coefficients to the excited states of CI from CII
Energy Technology Data Exchange (ETDEWEB)
Dubau, J. [Observatoire of Paris, 92 MEUDON (France); Kato, T.; Safronova, U.I.
1998-01-01
The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated including 1s{sup 2}2l{sub 1}2l{sub 2}2l{sub 3}nl (n=2-6, l{<=}(n-1)) states. The values for the excited states higher than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The rate coefficients to the excited states are fitted to an analytical formula and the fit parameters are given. (author)
Dielectronic recombination rate coefficients to the excited states of CII from CIII
International Nuclear Information System (INIS)
Kato, Takako; Safronova, U.; Ohira, Mituhiko.
1996-02-01
Energy levels, radiative transition probabilities and autoionization rates for CII including 1s 2 2l2l'nl'' (n=2-6, l'≤(n-1)) states were calculated by using multi-configurational Hartree-Fock (Cowan code) method. Autoionizing levels above three thresholds: 1s 2 2s 2 ( 1 S), 1s 2 2s2p( 3 P), 1s 2 2s2p( 1 P) were considered. Branching ratios related to the first threshold and the intensity factor were calculated for satellite lines of CII ion. The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated with these atomic data. The rate coefficients are fitted to an analytical formula and the fit parameters are given. The values for higher excited states than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The effective recombination rate coefficient for different electron densities are also derived. (author)
Dielectronic recombination rate coefficients to excited states of Be-like oxygen
Energy Technology Data Exchange (ETDEWEB)
Murakami, Izumi; Safronova, Ulyana I.; Kato, Takako
2001-05-01
We have calculated energy levels, radiative transition probabilities, and autoionization rates for Be-like oxygen (O{sup 4+}) including ls{sup 2}2lnl' (n=2 - 8, l {<=} n - 1) and 1s{sup 2}3l'nl (n=3 - 6, l {<=} n - l) states by multi-configurational Hartree-Fock method (Cowan code) and perturbation theory Z-expansion method (MZ code). The state selective dielectronic recombination rate coefficients to excited states of Be-like O ions are obtained. Configuration mixing plays an important role for the principal quantum number n distribution of the dielectronic recombination rate coefficients for 2snl (n {<=} 5) levels at low electron temperature. The orbital angular momentum quantum number l distribution of the rate coefficients shows a peak at l = 4. The total dielectronic recombination rate coefficient is derived as a function of electron temperature. (author)
Shizgal, Bernie D.; Chikhaoui, Aziz
2006-06-01
The present paper considers a detailed analysis of the nonequilibrium effects for a model reactive system with the Chapman-Eskog (CE) solution of the Boltzmann equation as well as an explicit time dependent solution. The elastic cross sections employed are a hard sphere cross section and the Maxwell molecule cross section. Reactive cross sections which model reactions with and without activation energy are used. A detailed comparison is carried out with these solutions of the Boltzmann equation and the approximation introduced by Cukrowski and coworkers [J. Chem. Phys. 97 (1992) 9086; Chem. Phys. 89 (1992) 159; Physica A 188 (1992) 344; Chem. Phys. Lett. A 297 (1998) 402; Physica A 275 (2000) 134; Chem. Phys. Lett. 341 (2001) 585; Acta Phys. Polonica B 334 (2003) 3607.] based on the temperature of the reactive particles. We show that the Cukrowski approximation has limited applicability for the large class of reactive systems studied in this paper. The explicit time dependent solutions of the Boltzmann equation demonstrate that the CE approach is valid only for very slow reactions for which the corrections to the equilibrium rate coefficient are very small.
Rate Coefficient Measurements of the Reaction CH3 + O2 = CH3O + O
Hwang, S. M.; Ryu, Si-Ok; DeWitt, K. J.; Rabinowitz, M. J.
1999-01-01
Rate coefficients for the reaction CH3 + O2 = CH3O + O were measured behind reflected shock waves in a series of lean CH4-O2-Ar mixtures using hydroxyl and methyl radical diagnostics. The rate coefficients are well represented by an Arrhenius expression given as k = (1.60(sup +0.67, sub -0.47 ) x 10(exp 13) e(-15813 +/- 587 K/T)/cubic cm.mol.s. This expression, which is valid in the temperature range 1575-1822 K, supports the downward trend in the rate coefficients that has been reported in recent determinations. All measurements to date, including the present study, have been to some extent affected by secondary reactions. The complications due to secondary reactions, choice of thermochemical data, and shock-boundary layer interactions that affect the determination of the rate coefficients are examined.
Rate Coefficient Measurements of the Reaction CH3+O2+CH3O+O
Hwang, S. M.; Ryu, Si-Ok; DeWitt, K. J.; Rabinowitz, M. J.
1999-01-01
Rate coefficients for the reaction CH3 + O2 = CH3O + O were measured behind reflected shock waves in a series of lean CH4-O2-Ar mixtures using hydroxyl and methyl radical diagnostics. The rate coefficients are well represented by an Arrhenius expression given as k = (1.60(sup +0.67, -0.47)) X 10(exp 13) exp(- 15813 +/- 587 K/T)cc/mol s. This expression, which is valid in the temperature range 1575-1822 K, supports the downward trend in the rate coefficients that has been reported in recent determinations. All measurements to date, including the present study, have been to some extent affected by secondary reactions. The complications due to secondary reactions, choice of thermochemical data, and shock-boundary layer interactions that affect the determination of the rate coefficients are examined.
Rate Coefficients for the OH + (CHO)2 (Glyoxal) Reaction Between 240 and 400 K
Feierabend, K. J.; Talukdar, R. K.; Zhu, L.; Ravishankara, A. R.; Burkholder, J. B.
2006-12-01
Glyoxal (CHO)2, the simplest dialdehyde, is an end product formed in the atmospheric oxidation of biogenic hydrocarbons, for example, isoprene. As such, glyoxal plays a role in regional air quality and ozone production in certain locations. Glyoxal is lost in the atmosphere via UV photolysis and reaction with OH. However, the currently available rate coefficient data for the OH + glyoxal reaction is limited to a single room- temperature measurement made using the relative rate method. A determination of the rate coefficient temperature dependence is therefore needed for a more complete interpretation of the atmospheric processing of glyoxal. This study reports the rate coefficient for the OH + (CHO)2 reaction measured under pseudo- first-order conditions in OH ([(CHO)2] > 1000 [OH]0). OH radicals were produced using 248 nm pulsed laser photolysis of H2O2 or HNO3 and detected by pulsed laser induced fluorescence. The concentration of glyoxal in the reactor was determined using three independent techniques; gas flow rates as well as in situ UV and IR absorption. The total pressure in the reactor was varied from 40 to 300 Torr (He), and the rate coefficient was found to be independent of pressure over the temperature range studied. The rate coefficient exhibits a negative temperature dependence between 240 and 400 K consistent with the dependence previously observed for many other aldehydes. Our room-temperature rate coefficient is smaller than the relative rate value that is currently recommended for use in atmospheric model calculations. Our measured rate coefficients are discussed with respect to those for other aldehydes. The atmospheric implications of our work will also be discussed.
Organ and effective dose rate coefficients for submersion exposure in occupational settings
International Nuclear Information System (INIS)
Veinot, K.G.; Dewji, S.A.; Hiller, M.M.; Eckerman, K.F.; Easterly, C.E.
2017-01-01
External dose coefficients for environmental exposure scenarios are often computed using assumption on infinite or semi-infinite radiation sources. For example, in the case of a person standing on contaminated ground, the source is assumed to be distributed at a given depth (or between various depths) and extending outwards to an essentially infinite distance. In the case of exposure to contaminated air, the person is modeled as standing within a cloud of infinite, or semi-infinite, source distribution. However, these scenarios do not mimic common workplace environments where scatter off walls and ceilings may significantly alter the energy spectrum and dose coefficients. In this paper, dose rate coefficients were calculated using the International Commission on Radiological Protection (ICRP) reference voxel phantoms positioned in rooms of three sizes representing an office, laboratory, and warehouse. For each room size calculations using the reference phantoms were performed for photons, electrons, and positrons as the source particles to derive mono-energetic dose rate coefficients. Since the voxel phantoms lack the resolution to perform dose calculations at the sensitive depth for the skin, a mathematical phantom was developed and calculations were performed in each room size with the three source particle types. Coefficients for the noble gas radionuclides of ICRP Publication 107 (e.g., Ne, Ar, Kr, Xe, and Rn) were generated by folding the corresponding photon, electron, and positron emissions over the mono-energetic dose rate coefficients. Results indicate that the smaller room sizes have a significant impact on the dose rate per unit air concentration compared to the semi-infinite cloud case. For example, for Kr-85 the warehouse dose rate coefficient is 7% higher than the office dose rate coefficient while it is 71% higher for Xe-133. (orig.)
Organ and effective dose rate coefficients for submersion exposure in occupational settings
Energy Technology Data Exchange (ETDEWEB)
Veinot, K.G. [Easterly Scientific, Knoxville, TN (United States); Y-12 National Security Complex, Oak Ridge, TN (United States); Dewji, S.A.; Hiller, M.M. [Center for Radiation Protection Knowledge, Oak Ridge National Laboratory, Oak Ridge, TN (United States); Eckerman, K.F.; Easterly, C.E. [Easterly Scientific, Knoxville, TN (United States)
2017-11-15
External dose coefficients for environmental exposure scenarios are often computed using assumption on infinite or semi-infinite radiation sources. For example, in the case of a person standing on contaminated ground, the source is assumed to be distributed at a given depth (or between various depths) and extending outwards to an essentially infinite distance. In the case of exposure to contaminated air, the person is modeled as standing within a cloud of infinite, or semi-infinite, source distribution. However, these scenarios do not mimic common workplace environments where scatter off walls and ceilings may significantly alter the energy spectrum and dose coefficients. In this paper, dose rate coefficients were calculated using the International Commission on Radiological Protection (ICRP) reference voxel phantoms positioned in rooms of three sizes representing an office, laboratory, and warehouse. For each room size calculations using the reference phantoms were performed for photons, electrons, and positrons as the source particles to derive mono-energetic dose rate coefficients. Since the voxel phantoms lack the resolution to perform dose calculations at the sensitive depth for the skin, a mathematical phantom was developed and calculations were performed in each room size with the three source particle types. Coefficients for the noble gas radionuclides of ICRP Publication 107 (e.g., Ne, Ar, Kr, Xe, and Rn) were generated by folding the corresponding photon, electron, and positron emissions over the mono-energetic dose rate coefficients. Results indicate that the smaller room sizes have a significant impact on the dose rate per unit air concentration compared to the semi-infinite cloud case. For example, for Kr-85 the warehouse dose rate coefficient is 7% higher than the office dose rate coefficient while it is 71% higher for Xe-133. (orig.)
Detonation Propagation in Slabs and Axisymmetric Rate Sticks
Romick, Christopher; Aslam, Tariq
Insensitive high explosives (IHE) have many benefits; however, these IHEs exhibit longer reaction zones than more conventional high explosives (HE). This makes IHEs less ideal explosives and more susceptible to edge effects as well as other performance degradation issues. Thus, there is a resulting reduction in the detonation speed within the explosive. Many HE computational models, e. g. WSD, SURF, CREST, have shock-dependent reaction rates. This dependency places a high value on having an accurate shock speed. In the common practice of shock-capturing, there is ambiguity in the shock-state due to smoothing of the shock-front. Moreover, obtaining an accurate shock speed with shock-capturing becomes prohibitively computationally expensive in multiple dimensions. The use of shock-fitting removes the ambiguity of the shock-state as it is one of the boundaries. As such, the required resolution for a given error in the detonation speed is less than with shock-capturing. This allows for further insight into performance degradation. A two-dimensional shock-fitting scheme has been developed for unconfined slabs and rate sticks of HE. The HE modeling is accomplished by Euler equations utilizing several models with single-step irreversible kinetics in slab and rate stick geometries. Department of Energy - LANL.
Schwenke, David W.; Jaffe, Richard L.; Chaban, Galina M.
2016-01-01
We have generated accurate global potential energy surfaces for CO+Ar and CO+O that correlate with atom-diatom pairs in their ground electronic states based on extensive ab initio electronic structure calculations and used these potentials in quasi-classical trajectory nuclear dynamics calculations to predict the thermal dissociation rate coefficients over 5000- 35000 K. Our results are not compatible with the 20-45 year old experimental results. For CO + Ar we obtain fairly good agreement with the experimental rate coefficients of Appleton et al. (1970) and Mick and Roth (1993), but our computed rate coefficients exhibit a stronger temperature dependence. For CO + O our dissociation rate coefficient is in close agreement with the value from the Park model, which is an empirical adjustment of older experimental results. However, we find the rate coefficient for CO + O is only 1.5 to 3.3 times larger than CO + Ar over the temperature range of the shock tube experiments (8000-15,000 K). The previously accepted value for this rate coefficient ratio is 15, independent of temperature. We also computed the rate coefficient for the CO + O ex- change reaction which forms C + O2. We find this reaction is much faster than previously believed and is the dominant process in the removal of CO at temperatures up to 16,000 K. As a result, the dissociation of CO is accomplished in two steps (react to form C+O2 and then O2 dissociates) that are endothermic by 6.1 and 5.1 eV, instead of one step that requires 11.2 eV to break the CO bond.
Yamaguchi, H.; Takamori, K.; Perrier, P.; Graur, I.; Matsuda, Y.; Niimi, T.
2016-09-01
The viscous slip coefficient for helium-argon binary gas mixture is extracted from the experimental values of the mass flow rate through a microtube. The mass flow rate is measured by the constant-volume method. The viscous slip coefficient was obtained by identifying the measured mass flow rate through a microtube with the corresponding analytical expression, which is a function of the Knudsen number. The measurements were carried out in the slip flow regime where the first-order slip boundary condition can be applied. The measured viscous slip coefficients of binary gas mixtures exhibit a concave function of the molar ratio of the mixture, showing a similar profile with numerical results. However, from the detailed comparison between the measured and numerical values with the complete and incomplete accommodation at a surface, it is inappropriate to estimate the viscous slip coefficient for the mixture numerically by employing separately measured tangential momentum accommodation coefficient for each component. The time variation of the molar ratio in the downstream chamber was measured by sampling the gas from the chamber using the quadrupole mass spectrometer. In our measurements, it is indicated that the volume flow rate of argon is larger than that of helium because of the difference in the tangential momentum accommodation coefficient.
Accurate Determination of Tunneling-Affected Rate Coefficients: Theory Assessing Experiment.
Zuo, Junxiang; Xie, Changjian; Guo, Hua; Xie, Daiqian
2017-07-20
The thermal rate coefficients of a prototypical bimolecular reaction are determined on an accurate ab initio potential energy surface (PES) using ring polymer molecular dynamics (RPMD). It is shown that quantum effects such as tunneling and zero-point energy (ZPE) are of critical importance for the HCl + OH reaction at low temperatures, while the heavier deuterium substitution renders tunneling less facile in the DCl + OH reaction. The calculated RPMD rate coefficients are in excellent agreement with experimental data for the HCl + OH reaction in the entire temperature range of 200-1000 K, confirming the accuracy of the PES. On the other hand, the RPMD rate coefficients for the DCl + OH reaction agree with some, but not all, experimental values. The self-consistency of the theoretical results thus allows a quality assessment of the experimental data.
Dielectronic and Trielectronic Recombination Rate Coefficients of Be-like Ar14+
Huang, Z. K.; Wen, W. Q.; Xu, X.; Mahmood, S.; Wang, S. X.; Wang, H. B.; Dou, L. J.; Khan, N.; Badnell, N. R.; Preval, S. P.; Schippers, S.; Xu, T. H.; Yang, Y.; Yao, K.; Xu, W. Q.; Chuai, X. Y.; Zhu, X. L.; Zhao, D. M.; Mao, L. J.; Ma, X. M.; Li, J.; Mao, R. S.; Yuan, Y. J.; Wu, B.; Sheng, L. N.; Yang, J. C.; Xu, H. S.; Zhu, L. F.; Ma, X.
2018-03-01
Electron–ion recombination of Be-like 40Ar14+ has been measured by employing the electron–ion merged-beams method at the cooler storage ring CSRm. The measured absolute recombination rate coefficients for collision energies from 0 to 60 eV are presented, covering all dielectronic recombination (DR) resonances associated with 2s 2 → 2s2p core transitions. In addition, strong trielectronic recombination (TR) resonances associated with 2s 2 → 2p 2 core transitions were observed. Both DR and TR processes lead to series of peaks in the measured recombination spectrum, which have been identified by the Rydberg formula. Theoretical calculations of recombination rate coefficients were performed using the state-of-the-art multi-configuration Breit–Pauli atomic structure code AUTOSTRUCTURE to compare with the experimental results. The plasma rate coefficients for DR+TR of Ar14+ were deduced from the measured electron–ion recombination rate coefficients in the temperature range from 103 to 107 K, and compared with calculated data from the literature. The experimentally derived plasma rate coefficients are 60% larger and 30% lower than the previously recommended atomic data for the temperature ranges of photoionized plasmas and collisionally ionized plasmas, respectively. However, good agreement was found between experimental results and the calculations by Gu and Colgan et al. The plasma rate coefficients deduced from experiment and calculated by the current AUTOSTRUCTURE code show agreement that is better than 30% from 104 to 107 K. The present results constitute a set of benchmark data for use in astrophysical modeling.
Zawawi, N. N. M.; Azmi, W. H.; Redhwan, A. A. M.; Sharif, M. Z.
2017-10-01
Wear of sliding parts and operational machine consistency enhancement can be avoided with good lubrication. Lubrication reduce wear between two contacting and sliding surfaces and decrease the frictional power losses in compressor. The coefficient of friction and wear rate effects study were carried out to measure the friction and anti-wear abilities of Al2O3-SiO2 composite nanolubricants a new type of compressor lubricant to enhanced the compressor performances. The tribology test rig employing reciprocating test conditions to replicate a piston ring contact in the compressor was used to measure the coefficient of friction and wear rate. Coefficient of friction and wear rate effects of different Al2O3-SiO2/PAG composite nanolubricants of Aluminium 2024 plate for 10-kg load at different speed were investigated. Al2O3 and SiO2 nanoparticles were dispersed in the Polyalkylene Glycol (PAG 46) lubricant using two-steps method of preparation. The result shows that the coefficient friction and wear rate of composite nanolubricants decreased compared to pure lubricant. The maximum reduction achievement for friction of coefficient and wear rate by Al2O3-SiO2 composite nanolubricants by 4.78% and 12.96% with 0.06% volume concentration. Therefore, 0.06% volume concentration is selected as the most enhanced composite nanolubricants with effective coefficient of friction and wear rate reduction compared to other volume concentrations. Thus, it is recommended to be used as the compressor lubrication to enhanced compressor performances.
Mechanism for propagation of rate signals through a 10-layer feedforward neuronal network
International Nuclear Information System (INIS)
Jie, Li; Wan-Qing, Yu; Ding, Xu; Feng, Liu; Wei, Wang
2009-01-01
Using numerical simulations, we explore the mechanism for propagation of rate signals through a 10-layer feedforward network composed of Hodgkin–Huxley (HH) neurons with sparse connectivity. When white noise is afferent to the input layer, neuronal firing becomes progressively more synchronous in successive layers and synchrony is well developed in deeper layers owing to the feedforward connections between neighboring layers. The synchrony ensures the successful propagation of rate signals through the network when the synaptic conductance is weak. As the synaptic time constant τ syn varies, coherence resonance is observed in the network activity due to the intrinsic property of HH neurons. This makes the output firing rate single-peaked as a function of τ syn , suggesting that the signal propagation can be modulated by the synaptic time constant. These results are consistent with experimental results and advance our understanding of how information is processed in feedforward networks. (cross-disciplinary physics and related areas of science and technology)
Determination of the N2 recombination rate coefficient in the ionosphere
Orsini, N.; Torr, D. G.; Brinton, H. C.; Brace, L. H.; Hanson, W. B.; Hoffman, J. H.; Nier, A. O.
1977-01-01
Measurements of aeronomic parameters made by the Atmosphere Explorer-C satellite are used to determine the recombination rate coefficient of N2(+) in the ionosphere. The rate is found to increase significantly with decreasing electron density. Values obtained range from approximately 1.4 x 10 to the -7th to 3.8 x 10 to the -7th cu cm/sec. This variation is explained in a preliminary way in terms of an increase in the rate coefficient with vibrational excitation. Thus, high electron densities depopulate high vibrational levels reducing the effective recombination rate, whereas, low electron densities result in an enhancement in the population of high vibrational levels, thus, increasing the effective recombination rate.
Cao, Xiaoshan; Shi, Junping; Jin, Feng
2012-06-01
The propagation behavior of Love waves in a layered structure that includes a functionally graded material (FGM) substrate carrying a piezoelectric thin film is investigated. Analytical solutions are obtained for both constant and gradient dielectric coefficients in the FGM substrate. Numerical results show that the gradient dielectric coefficient decreases phase velocity in any mode, and the electromechanical coupling factor significantly increases in the first- and secondorder modes. In some modes, the difference in Love waves' phase velocity between these two types of structure might be more than 1%, resulting in significant differences in frequency of the surface acoustic wave devices.
Semiempirical method of determining flow coefficients for pitot rake mass flow rate measurements
Trefny, C. J.
1985-01-01
Flow coefficients applicable to area-weighted pitot rake mass flow rate measurements are presented for fully developed, turbulent flow in an annulus. A turbulent velocity profile is generated semiempirically for a given annulus hub-to-tip radius ratio and integrated numerically to determine the ideal mass flow rate. The calculated velocities at each probe location are then summed, and the flow rate as indicated by the rake is obtained. The flow coefficient to be used with the particular rake geometry is subsequently obtained by dividing the ideal flow rate by the rake-indicated flow rate. Flow coefficients ranged from 0.903 for one probe placed at a radius dividing two equal areas to 0.984 for a 10-probe area-weighted rake. Flow coefficients were not a strong function of annulus hub-to-tip radius ratio for rakes with three or more probes. The semiempirical method used to generate the turbulent velocity profiles is described in detail.
International Nuclear Information System (INIS)
Haggerty, R.; Schroth, M.H.; Istok, J.D.
1998-01-01
The single-well, ''''push-pull'''' test method is useful for obtaining information on a wide variety of aquifer physical, chemical, and microbiological characteristics. A push-pull test consists of the pulse-type injection of a prepared test solution into a single monitoring well followed by the extraction of the test solution/ground water mixture from the same well. The test solution contains a conservative tracer and one or more reactants selected to investigate a particular process. During the extraction phase, the concentrations of tracer, reactants, and possible reaction products are measured to obtain breakthrough curves for all solutes. This paper presents a simplified method of data analysis that can be used to estimate a first-order reaction rate coefficient from these breakthrough curves. Rate coefficients are obtained by fitting a regression line to a plot of normalized concentrations versus elapsed time, requiring no knowledge of aquifer porosity, dispersivity, or hydraulic conductivity. A semi-analytical solution to the advective-dispersion equation is derived and used in a sensitivity analysis to evaluate the ability of the simplified method to estimate reaction rate coefficients in simulated push-pull tests in a homogeneous, confined aquifer with a fully-penetrating injection/extraction well and varying porosity, dispersivity, test duration, and reaction rate. A numerical flow and transport code (SUTRA) is used to evaluate the ability of the simplified method to estimate reaction rate coefficients in simulated push-pull tests in a heterogeneous, unconfined aquifer with a partially penetrating well. In all cases the simplified method provides accurate estimates of reaction rate coefficients; estimation errors ranged from 0.1 to 8.9% with most errors less than 5%
Petrignani, A.; Zande, W.J. van der; Cosby, P.C.; Hellberg, F.; Thomas, R.; Larsson, M.
2005-01-01
We have studied the dissociative recombination of the first three vibrational levels of O-2(+) in its electronic ground X (2)Pi(g) state. Absolute rate coefficients, cross sections, quantum yields and branching fractions have been determined in a merged-beam experiment in the heavy-ion storage ring,
Rate coefficients of open shell molecules and radicals: R-matrix ...
Indian Academy of Sciences (India)
2017-04-07
Apr 7, 2017 ... Rate coefficients of open shell molecules and radicals: R-matrix method. JASMEET SINGH1 ... lasers, study of structure of DNA and astrophysics which require a ..... [6] CCPForge, http://ccpforge.cse.rl.ac.uk/projects/ukrmol-in/.
Direct access to dithiobenzoate RAFT agent fragmentation rate coefficients by ESR spin-trapping.
Ranieri, Kayte; Delaittre, Guillaume; Barner-Kowollik, Christopher; Junkers, Thomas
2014-12-01
The β-scission rate coefficient of tert-butyl radicals fragmenting off the intermediate resulting from their addition to tert-butyl dithiobenzoate-a reversible addition-fragmentation chain transfer (RAFT) agent-is estimated via the recently introduced electron spin resonance (ESR)-trapping methodology as a function of temperature. The newly introduced ESR-trapping methodology is critically evaluated and found to be reliable. At 20 °C, a fragmentation rate coefficient of close to 0.042 s(-1) is observed, whereas the activation parameters for the fragmentation reaction-determined for the first time-read EA = 82 ± 13.3 kJ mol(-1) and A = (1.4 ± 0.25) × 10(13) s(-1) . The ESR spin-trapping methodology thus efficiently probes the stability of the RAFT adduct radical under conditions relevant for the pre-equilibrium of the RAFT process. It particularly indicates that stable RAFT adduct radicals are indeed formed in early stages of the RAFT poly-merization, at least when dithiobenzoates are employed as controlling agents as stipulated by the so-called slow fragmentation theory. By design of the methodology, the obtained fragmentation rate coefficients represent an upper limit. The ESR spin-trapping methodology is thus seen as a suitable tool for evaluating the fragmentation rate coefficients of a wide range of RAFT adduct radicals. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Hintz, Paul A.; Ervin, Kent M.
1994-04-01
Reactions of Ni-n(n=3-10), Pd-n(n=3-8), and Pt-n(n=3-7) with CO are studied in a flow tube reactor. Bimolecular rate coefficients are measured for the association reaction of CO adsorbing on the cluster surface. The rate coefficients range from about 10% of the collision rate for the trimer anions to near the collision rate for clusters larger than four atoms. The maximum number of CO molecules that bind to each cluster is determined. Whereas the saturation limits for nickel are typical for an 18 electron transition metal, the limits for platinum are lower, reflecting the electron deficient structures observed in condensed phase chemistry. The CO saturated palladium clusters represent the first examples of saturated binary palladium carbonyl compounds. Comparisons are made to similar studies on metal cation and neutral clusters and also to surface scattering studies of nickel group metals.
Directory of Open Access Journals (Sweden)
Shim S.M.
2012-01-01
Full Text Available The performance of the CO2 absorber column using mono-ethanolamine (MEA solution as chemical solvent are predicted by a One-Dimensional (1-D rate based model in the present study. 1-D Mass and heat balance equations of vapor and liquid phase are coupled with interfacial mass transfer model and vapor-liquid equilibrium model. The two-film theory is used to estimate the mass transfer between the vapor and liquid film. Chemical reactions in MEA-CO2-H2O system are considered to predict the equilibrium pressure of CO2 in the MEA solution. The mathematical and reaction kinetics models used in this work are calculated by using in-house code. The numerical results are validated in the comparison of simulation results with experimental and simulation data given in the literature. The performance of CO2 absorber column is evaluated by the 1-D rate based model using various reaction rate coefficients suggested by various researchers. When the rate of liquid to gas mass flow rate is about 8.3, 6.6, 4.5 and 3.1, the error of CO2 loading and the CO2 removal efficiency using the reaction rate coefficients of Aboudheir et al. is within about 4.9 % and 5.2 %, respectively. Therefore, the reaction rate coefficient suggested by Aboudheir et al. among the various reaction rate coefficients used in this study is appropriate to predict the performance of CO2 absorber column using MEA solution. [Acknowledgement. This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF, funded by the Ministry of Education, Science and Technology (2011-0017220].
Naine, Tarun Bharath; Gundawar, Manoj Kumar
2017-09-01
We demonstrate a very powerful correlation between the discrete probability of distances of neighboring cells and thermal wave propagation rate, for a system of cells spread on a one-dimensional chain. A gamma distribution is employed to model the distances of neighboring cells. In the absence of an analytical solution and the differences in ignition times of adjacent reaction cells following non-Markovian statistics, invariably the solution for thermal wave propagation rate for a one-dimensional system with randomly distributed cells is obtained by numerical simulations. However, such simulations which are based on Monte-Carlo methods require several iterations of calculations for different realizations of distribution of adjacent cells. For several one-dimensional systems, differing in the value of shaping parameter of the gamma distribution, we show that the average reaction front propagation rates obtained by a discrete probability between two limits, shows excellent agreement with those obtained numerically. With the upper limit at 1.3, the lower limit depends on the non-dimensional ignition temperature. Additionally, this approach also facilitates the prediction of burning limits of heterogeneous thermal mixtures. The proposed method completely eliminates the need for laborious, time intensive numerical calculations where the thermal wave propagation rates can now be calculated based only on macroscopic entity of discrete probability.
Dielectronic recombination rate coefficients to the excited states of CIII from CIV
Energy Technology Data Exchange (ETDEWEB)
Safronova, U.; Kato, Takako; Ohira, Mituhiko
1996-07-01
Energy levels, radiative transition probabilities and autoionization rates for CIII including 1s{sup 2}2pnl` (n=2/6, l`{<=}(n-1)) and 1s{sup 2}3lnl` (n=3/6, l`{<=}(n-1)) states were calculated by using multi-configurational Hartree-Fock (Cowan code) method. Autoionizing levels above the 1s{sup 2}2s and 1s{sup 2}2p thresholds were considered and their contributions were computed. Branching ratios on the autoionization rate to the first threshold and intensity factor were calculated for satellite lines of CIII ion. The dielectronic recombination rate coefficients to the excited states for n=2-6 were calculated. The values for the excited states higher than n=6 were extrapolated and the total dielectronic recombination rate coefficients were also derived. The rate coefficients to the excited states were fitted to an analytical formula and the fitting parameters are given. (author)
Transitions in genetic toggle switches driven by dynamic disorder in rate coefficients
International Nuclear Information System (INIS)
Chen, Hang; Thill, Peter; Cao, Jianshu
2016-01-01
In biochemical systems, intrinsic noise may drive the system switch from one stable state to another. We investigate how kinetic switching between stable states in a bistable network is influenced by dynamic disorder, i.e., fluctuations in the rate coefficients. Using the geometric minimum action method, we first investigate the optimal transition paths and the corresponding minimum actions based on a genetic toggle switch model in which reaction coefficients draw from a discrete probability distribution. For the continuous probability distribution of the rate coefficient, we then consider two models of dynamic disorder in which reaction coefficients undergo different stochastic processes with the same stationary distribution. In one, the kinetic parameters follow a discrete Markov process and in the other they follow continuous Langevin dynamics. We find that regulation of the parameters modulating the dynamic disorder, as has been demonstrated to occur through allosteric control in bistable networks in the immune system, can be crucial in shaping the statistics of optimal transition paths, transition probabilities, and the stationary probability distribution of the network.
Transitions in genetic toggle switches driven by dynamic disorder in rate coefficients
Energy Technology Data Exchange (ETDEWEB)
Chen, Hang, E-mail: hangchen@mit.edu; Thill, Peter; Cao, Jianshu [Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)
2016-05-07
In biochemical systems, intrinsic noise may drive the system switch from one stable state to another. We investigate how kinetic switching between stable states in a bistable network is influenced by dynamic disorder, i.e., fluctuations in the rate coefficients. Using the geometric minimum action method, we first investigate the optimal transition paths and the corresponding minimum actions based on a genetic toggle switch model in which reaction coefficients draw from a discrete probability distribution. For the continuous probability distribution of the rate coefficient, we then consider two models of dynamic disorder in which reaction coefficients undergo different stochastic processes with the same stationary distribution. In one, the kinetic parameters follow a discrete Markov process and in the other they follow continuous Langevin dynamics. We find that regulation of the parameters modulating the dynamic disorder, as has been demonstrated to occur through allosteric control in bistable networks in the immune system, can be crucial in shaping the statistics of optimal transition paths, transition probabilities, and the stationary probability distribution of the network.
Temperature-Dependent Rate Coefficients for the Reaction of CH2OO with Hydrogen Sulfide.
Smith, Mica C; Chao, Wen; Kumar, Manoj; Francisco, Joseph S; Takahashi, Kaito; Lin, Jim Jr-Min
2017-02-09
The reaction of the simplest Criegee intermediate CH 2 OO with hydrogen sulfide was measured with transient UV absorption spectroscopy in a temperature-controlled flow reactor, and bimolecular rate coefficients were obtained from 278 to 318 K and from 100 to 500 Torr. The average rate coefficient at 298 K and 100 Torr was (1.7 ± 0.2) × 10 -13 cm 3 s -1 . The reaction was found to be independent of pressure and exhibited a weak negative temperature dependence. Ab initio quantum chemistry calculations of the temperature-dependent reaction rate coefficient at the QCISD(T)/CBS level are in reasonable agreement with the experiment. The reaction of CH 2 OO with H 2 S is 2-3 orders of magnitude faster than the reaction with H 2 O monomer. Though rates of CH 2 OO scavenging by water vapor under atmospheric conditions are primarily controlled by the reaction with water dimer, the H 2 S loss pathway will be dominated by the reaction with monomer. The agreement between experiment and theory for the CH 2 OO + H 2 S reaction lends credence to theoretical descriptions of other Criegee intermediate reactions that cannot easily be probed experimentally.
International Nuclear Information System (INIS)
Janev, R.K.; Kato, T.; Wang, J.G.
2001-05-01
The available experimental and theoretical cross section data on charge exchange processes in collisions of protons with hydrocarbon molecules have been collected and critically assessed. Using well established scaling relationships for the charge exchange cross sections at low and high collision energies, as well as the known rate coefficients for these reactions in the thermal energy region, a complete cross section database is constructed for proton-C x H y charge exchange reactions from thermal energies up to several hundreds keV for all C x H y molecules with x=1, 2, 3 and 1 ≤ y ≤ 2x + 2. Rate coefficients for these charge exchange reactions have also been calculated in the temperature range from 0.1 eV to 20 keV. (author)
Energy Technology Data Exchange (ETDEWEB)
Janev, R.K.; Kato, T. [National Inst. for Fusion Science, Toki, Gifu (Japan); Wang, J.G. [Department of Physics and Astronomy, University of Georgia, Athens (United States)
2001-05-01
The available experimental and theoretical cross section data on charge exchange processes in collisions of protons with hydrocarbon molecules have been collected and critically assessed. Using well established scaling relationships for the charge exchange cross sections at low and high collision energies, as well as the known rate coefficients for these reactions in the thermal energy region, a complete cross section database is constructed for proton-C{sub x}H{sub y} charge exchange reactions from thermal energies up to several hundreds keV for all C{sub x}H{sub y} molecules with x=1, 2, 3 and 1 {<=} y {<=} 2x + 2. Rate coefficients for these charge exchange reactions have also been calculated in the temperature range from 0.1 eV to 20 keV. (author)
Bogan, Denis
1999-01-01
Laboratory measurements have been carried out to determine low temperature chemical rate coefficients of ethynyl radical (C2H) for the atmospheres of the outer planets and their satellites. This effort is directly related to the Cassini mission which will explore Saturn and Titan. A laser-based photolysis/infrared laser probe setup was used to measure the temperature dependence of kinetic rate coefficients from approx. equal to 150 to 350 K for C2H radicals with H2, C2H2, CH4, CD4, C2H4, C2H6, C3H8, n-C4H10, i-C4H10, neo-C5H12, C3H4 (methylacetylene and allene), HCN, and CH3CN. The results revealed discrepancies of an order of magnitude or more compared with the low temperature rate coefficients used in present models. A new Laval nozzle, low Mach number supersonic expansion kinetics apparatus has been constructed, resulting in the first measurements of neutral C2H radical kinetics at 90 K and permitting studies on condensable gases with insufficient vapor pressure at low temperatures. New studies of C 2H with acetylene have been completed.
Electron-impact excitation rate-coefficients and polarization of subsequent emission for Ar"+ ion
International Nuclear Information System (INIS)
Dipti; Srivastava, Rajesh
2016-01-01
Electron impact excitation in Ar"+ ions has been studied by using fully relativistic distorted wave theory. Calculations are performed to obtain the excitation cross-sections and rate-coefficients for the transitions from the ground state 3p"5 (J=3/2) to fine-structure levels of excited states 3p"44s, 3p"44p, 3p"45s, 3p"45p, 3p"43d and 3p"44d. Polarization of the radiation following the excitation has been calculated using the obtained magnetic sub-level cross-sections. Comparison of the present rate-coefficients is also done with the previously reported theoretical results for some unresolved fine structure transitions. - Highlights: • Fully relativistic distorted wave theory has been used to study the excitation of fine-structure states of Ar"+. • We have calculated electron-impact excitation cross-sections for the wide range of incident electron energies. • Electron impact excitation rate-coefficients are calculated as a function of electron temperature. • Polarization of photons emitted following the decay of the excited fine-structure states are also reported.
International Nuclear Information System (INIS)
Ye, Yong-jun; Wang, Li-heng; Ding, De-xin; Zhao, Ya-li; Fan, Nan-bin
2014-01-01
The radon diffusion coefficient and the free radon production rate are important parameters for describing radon migration in the fragmented uranium ore. In order to determine the two parameters, the pure diffusion migration equation for radon was firstly established and its analytic solution with the two parameters to be determined was derived. Then, a self manufactured experimental column was used to simulate the pure diffusion of the radon, the improved scintillation cell method was used to measure the pore radon concentrations at different depths of the column loaded with the fragmented uranium ore, and the nonlinear least square algorithm was used to inversely determine the radon diffusion coefficient and the free radon production rate. Finally, the solution with the two inversely determined parameters was used to predict the pore radon concentrations at some depths of the column, and the predicted results were compared with the measured results. The results show that the predicted results are in good agreement with the measured results and the numerical inverse method is applicable to the determination of the radon diffusion coefficient and the free radon production rate for the fragmented uranium ore. - Highlights: • Inverse method for determining two transport parameters of radon is proposed. • A self-made experimental apparatus is used to simulate radon diffusion process. • Sampling volume and position for measuring radon concentration are optimized. • The inverse results of an experimental sample are verified
International Nuclear Information System (INIS)
Pusateri, Elise N.; Morris, Heidi E.; Nelson, Eric M.; Ji, Wei
2015-01-01
Electromagnetic pulse (EMP) events produce low-energy conduction electrons from Compton electron or photoelectron ionizations with air. It is important to understand how conduction electrons interact with air in order to accurately predict EMP evolution and propagation. An electron swarm model can be used to monitor the time evolution of conduction electrons in an environment characterized by electric field and pressure. Here a swarm model is developed that is based on the coupled ordinary differential equations (ODEs) described by Higgins et al. (1973), hereinafter HLO. The ODEs characterize the swarm electric field, electron temperature, electron number density, and drift velocity. Important swarm parameters, the momentum transfer collision frequency, energy transfer collision frequency, and ionization rate, are calculated and compared to the previously reported fitted functions given in HLO. These swarm parameters are found using BOLSIG+, a two term Boltzmann solver developed by Hagelaar and Pitchford (2005), which utilizes updated cross sections from the LXcat website created by Pancheshnyi et al. (2012). We validate the swarm model by comparing to experimental effective ionization coefficient data in Dutton (1975) and drift velocity data in Ruiz-Vargas et al. (2010). In addition, we report on electron equilibrium temperatures and times for a uniform electric field of 1 StatV/cm for atmospheric heights from 0 to 40 km. We show that the equilibrium temperature and time are sensitive to the modifications in the collision frequencies and ionization rate based on the updated electron interaction cross sections
International Nuclear Information System (INIS)
Vanderploeg, H.A.; Booth, R.S.
1976-01-01
Rigorous expressions are derived for the biological-rate coefficients (BRCs) determined from time-dependent measurements of three different dependent variables of radionuclide tracer experiments. These variables, which apply to a single organism, are radionuclide content, radionuclide concentration and specific activity. The BRCs derived from these variables have different mathematical expressions and, for high growth rates, their numerical values can be quite different. The precise mathematical expressions for the BRCs are presented here to aid modelers in selecting the correct parameters for their models and to aid experiments in interpreting their results. The usefulness of these three variables in quantifying elemental uptakes and losses by organisms is discussed. (U.K.)
Jameson, A. R.
1990-01-01
The relationship between the rainfall rate (R) obtained from radiometric brightness temperatures and the extinction coefficient (k sub e) is investigated by computing the values of k sub e over a wide range of rainfall rates, for frequencies from 3 to 25 GHz. The results show that the strength of the relation between the R and the k sub e values exhibits considerable variation for frequencies at this range. Practical suggestions are made concerning the selection of particular frequencies for rain measurements to minimize the error in R determinations.
Derivation of the chemical-equilibrium rate coefficient using scattering theory
Mickens, R. E.
1977-01-01
Scattering theory is applied to derive the equilibrium rate coefficient for a general homogeneous chemical reaction involving ideal gases. The reaction rate is expressed in terms of the product of a number of normalized momentum distribution functions, the product of the number of molecules with a given internal energy state, and the spin-averaged T-matrix elements. An expression for momentum distribution at equilibrium for an arbitrary molecule is presented, and the number of molecules with a given internal-energy state is represented by an expression which includes the partition function.
Liu, Zhijian; Liu, Kejun; Li, Hao; Zhang, Xinyu; Jin, Guangya; Cheng, Kewei
2015-01-01
Measurements of heat collection rate and heat loss coefficient are crucial for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, conventional measurement requires expensive detection devices and undergoes a series of complicated procedures. To simplify the measurement and reduce the cost, software based on artificial neural networks for measuring heat collection rate and heat loss coefficient of water-in-glass evacuated tube solar water heaters was developed. Using multilayer feed-forward neural networks with back-propagation algorithm, we developed and tested our program on the basis of 915 measured samples of water-in-glass evacuated tube solar water heaters. This artificial neural networks-based software program automatically obtained accurate heat collection rate and heat loss coefficient using simply "portable test instruments" acquired parameters, including tube length, number of tubes, tube center distance, heat water mass in tank, collector area, angle between tubes and ground and final temperature. Our results show that this software (on both personal computer and Android platforms) is efficient and convenient to predict the heat collection rate and heat loss coefficient due to it slow root mean square errors in prediction. The software now can be downloaded from http://t.cn/RLPKF08.
International Nuclear Information System (INIS)
Valdés, José R.; Rodríguez, José M.; Saumell, Javier; Pütz, Thomas
2014-01-01
Highlights: • We develop a methodology for the parametric modelling of flow in hydraulic valves. • We characterize the flow coefficients with a generic function with two parameters. • The parameters are derived from CFD simulations of the generic geometry. • We apply the methodology to two cases from the automotive brake industry. • We validate by comparing with CFD results varying the original dimensions. - Abstract: The main objective of this work is to develop a methodology for the parametric modelling of the flow rate in hydraulic valve systems. This methodology is based on the derivation, from CFD simulations, of the flow coefficient of the critical restrictions as a function of the Reynolds number, using a generalized square root function with two parameters. The methodology is then demonstrated by applying it to two completely different hydraulic systems: a brake master cylinder and an ABS valve. This type of parametric valve models facilitates their implementation in dynamic simulation models of complex hydraulic systems
International Nuclear Information System (INIS)
Imre, K.; Odian, G.
1979-01-01
The effect of diffusion on radiation-initiated graft polymerization has been studied with emphasis on the single- and two-penetrant cases. When the physical properties of the penetrants are similar, the two-penetrant problems can be reduced to the single-penetrant problem by redefining the characteristic parameters of the system. The diffusion-free graft polymerization rate is assumed to be proportional to the upsilon power of the monomer concentration respectively, and, in which the proportionality constant a = k/sub p/R/sub i//sup w//k/sub t//sup z/, where k/sub p/ and k/sub t/ are the propagation and termination rate constants, respectively, and R/sub i/ is the initiation rate. The values of upsilon, w, and z depend on the particular reaction system. The results of earlier work were generalized by allowing a non-Fickian diffusion rate which predicts an essentially exponential dependence on the monomer concentration of the diffusion coefficient, D = D 0 [exp(deltaC/M)], where M is the saturation concentration. A reaction system is characterized by the three dimensionless parameters, upsilon, delta, and A = (L/2)[aM/sup (upsilon--1)//D 0 ]/sup 1/2/, where L is the polymer film thickness. Graft polymerization tends to become diffusion controlled as A increases. Larger values of delta and ν cause a reaction system to behave closer to the diffusion-free regime. Transition from diffusion-free to diffusion-controlled reaction involves changes in the dependence of the reaction rate on film thickness, initiation rate, and monomer concentration. Although the diffusion-free rate is w order in initiation rate, upsilon order in monomer, and independent of film thickness, the diffusion-controlled rate is w/2 order in initiator rate and inverse first-order in film thickness. Dependence of the diffusion-controlled rate on monomer is dependent in a complex manner on the diffusional characteristics of the reaction system. 11 figures, 4 tables
Liu, Zhijian; Liu, Kejun; Li, Hao; Zhang, Xinyu; Jin, Guangya; Cheng, Kewei
2015-01-01
Measurements of heat collection rate and heat loss coefficient are crucial for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, conventional measurement requires expensive detection devices and undergoes a series of complicated procedures. To simplify the measurement and reduce the cost, software based on artificial neural networks for measuring heat collection rate and heat loss coefficient of water-in-glass evacuated tube solar water heaters was developed. Using multilayer feed-forward neural networks with back-propagation algorithm, we developed and tested our program on the basis of 915measuredsamples of water-in-glass evacuated tube solar water heaters. This artificial neural networks-based software program automatically obtained accurate heat collection rateand heat loss coefficient using simply "portable test instruments" acquired parameters, including tube length, number of tubes, tube center distance, heat water mass in tank, collector area, angle between tubes and ground and final temperature. Our results show that this software (on both personal computer and Android platforms) is efficient and convenient to predict the heat collection rate and heat loss coefficient due to it slow root mean square errors in prediction. The software now can be downloaded from http://t.cn/RLPKF08. PMID:26624613
Anisotropy of the rates of propagation of seismic waves on Sakhalin
Energy Technology Data Exchange (ETDEWEB)
Telegin, A.N.; Antonova, L.P.; Shmain, M.M.; Trubachev, B.P.
1983-01-01
An examination is made of the difference in effective rates of OGT computed from latitudinal and meridional profiles which is explained by anisotropy in velocities of the horizontal plane associated with tectonic conditions. A quantitative investigation of changes in the coefficient of anisotropy can yield additional information about the condition of the rocks.
International Nuclear Information System (INIS)
Seo, M; Shimamura, T; Furutani, T; Hasuo, M; Bahrim, C; Fujimoto, T
2003-01-01
Disalignment of neon excited atoms in the fine-structure 2p i levels (in Paschen notation) of the 2p 5 3p configuration is investigated in a helium-neon glow discharge at temperatures between 15 and 77 K. At several temperatures, we plot the disalignment rate as a function of the helium atom density for Ne* (2p 2 or 2p 7 ) + He(1s 2 ) collisions. The slope of this dependence gives the disalignment rate coefficient. For both collisions, the experimental data for the disalignment rate coefficient show a more rapid decrease with the decrease in temperature below 40 K than our quantum close-coupling calculations based on the model potential of Hennecart and Masnou-Seeuws (1985 J. Phys. B: At. Mol. Phys. 18 657). This finding suggests that the disalignment cross section rapidly decreases below a few millielectronvolts, in disagreement with our theoretical quantum calculations which predict a strong increase below 1 meV. The disagreement suggests that the long-range electrostatic potentials are significantly more repulsive than in the aforementioned model
Dose Rate and Mass Attenuation Coefficients of Gamma Ray for Concretes
Abdel-Latif, A A; Kansouh, W A; El-Sayed, F H
2003-01-01
This work is concerned with the study of the leakage gamma ray dose and mass attenuation coefficients for ordinary, basalt and dolomite concretes made from local ores. Concretes under investigation were constructed from gravel, basalt and dolomite ores, and then reconstructed with the addition of 3% steel fibers by weight. Measurements were carried out using a collimated beam from sup 6 sup 0 Co gamma ray source and sodium iodide (3x3) crystal with the genie 2000 gamma spectrometer. The obtained fluxes were transformed to gamma ray doses and displayed in the form of gamma ray dose rates distribution. The displayed curves were used to estimate the linear attenuation coefficients (mu), the relaxation lengths (lambda), half value layer (t sub 1 /2) and tenth value layer (t sub 1 /10). Also, The total mass attenuation coefficients of gamma ray have been calculated to the concerned concretes using XCOM (version 3.1) program and database elements cross sections from Z=1 to 100 at energies from 10 keV to 100 MeV. In...
Relative measurement of the excitation rate coefficients of the FeXI ion
International Nuclear Information System (INIS)
Marotta, A.
1982-01-01
The collision rate coefficients for the iron atoms are measured through the hot plasma obtainment. The physical model used in this determination is the crown stationary model which consider that the excitation by electronic collisions is balanced by the spontaneous emission. This work was realized in a 15Kj theta pinch device, of high pulse reproductibility. The iron-pentacarbonyl [Fe(Co) 5 ] was used as the impurity source of a hydrogen gas. The temperature and density were determined by the scattering light analysis of a rubi laser using the Thomson scattering. (L.C.) [pt
Crack propagation rate modelling for 316SS exposed to PWR-relevant conditions
International Nuclear Information System (INIS)
Vankeerberghen, M.; Weyns, G.; Gavrilov, S.; Martens, B.; Deconinck, J.
2009-01-01
The crack propagation rate of Type 316 stainless steel in boric acid-lithium hydroxide solutions under PWR-relevant conditions was modelled. A film rupture/dissolution/repassivation mechanism is assumed and extended to cold worked materials by including a stress-dependent bare metal dissolution current density. The chemical and electrochemical conditions within the crack are calculated by finite element calculations, an analytical expression is used for the crack-tip strain rate and the crack-tip stress is assumed equal to 2.5 times the yield stress (plane-strain). First the model was calibrated against a literature published data set. Afterwards, the influence of various variables - dissolved hydrogen, boric acid and lithium hydroxide content, stress intensity, crack length, temperature, flow rate - was studied. Finally, other published crack growth rate tests were modelled and the calculated crack growth rates were found to be in reasonable agreement with the reported ones
Effect of Chamber Pressurization Rate on Combustion and Propagation of Solid Propellant Cracks
Yuan, Wei-Lan; Wei, Shen; Yuan, Shu-Shen
2002-01-01
area of the propellant grain satisfies the designed value. But cracks in propellant grain can be generated during manufacture, storage, handing and so on. The cracks can provide additional surface area for combustion. The additional combustion may significantly deviate the performance of the rocket motor from the designed conditions, even lead to explosive catastrophe. Therefore a thorough study on the combustion, propagation and fracture of solid propellant cracks must be conducted. This paper takes an isolated propellant crack as the object and studies the effect of chamber pressurization rate on the combustion, propagation and fracture of the crack by experiment and theoretical calculation. deformable, the burning inside a solid propellant crack is a coupling of solid mechanics and combustion dynamics. In this paper, a theoretical model describing the combustion, propagation and fracture of the crack was formulated and solved numerically. The interaction of structural deformation and combustion process was included in the theoretical model. The conservation equations for compressible fluid flow, the equation of state for perfect gas, the heat conducting equation for the solid-phase, constitutive equation for propellant, J-integral fracture criterion and so on are used in the model. The convective burning inside the crack and the propagation and fracture of the crack were numerically studied by solving the set of nonlinear, inhomogeneous gas-phase governing equations and solid-phase equations. On the other hand, the combustion experiments for propellant specimens with a precut crack were conducted by RTR system. Predicted results are in good agreement with experimental data, which validates the reasonableness of the theoretical model. Both theoretical and experimental results indicate that the chamber pressurization rate has strong effects on the convective burning in the crack, crack fracture initiation and fracture pattern.
Leone, Stephen R.
1995-01-01
The objectives of the research are to measure low temperature laboratory rate coefficients for key reactions relevant to the atmospheres of Titan and Saturn. These reactions are, for example, C2H + H2, CH4, C2H2, and other hydrocarbons which need to be measured at low temperatures, down to approximately 150 K. The results of this work are provided to NASA specialists who study modeling of the hydrocarbon chemistry of the outer planets. The apparatus for this work consists of a pulsed laser photolysis system and a tunable F-center probe laser to monitor the disappearance of C2H. A low temperature cell with a cryogenic circulating fluid in the outer jacket provides the gas handling system for this work. These elements have been described in detail in previous reports. Several new results are completed and the publications are just being prepared. The reaction of C2H with C2H2 has been measured with an improved apparatus down to 154 K. An Arrhenius plot indicates a clear increase in the rate coefficient at the lowest temperatures, most likely because of the long-lived (C4H3) intermediate. The capability to achieve the lowest temperatures in this work was made possible by construction of a new cell and addition of a multipass arrangement for the probe laser, as well as improvements to the laser system.
Estimating Reaction Rate Coefficients Within a Travel-Time Modeling Framework
Energy Technology Data Exchange (ETDEWEB)
Gong, R [Georgia Institute of Technology; Lu, C [Georgia Institute of Technology; Luo, Jian [Georgia Institute of Technology; Wu, Wei-min [Stanford University; Cheng, H. [Stanford University; Criddle, Craig [Stanford University; Kitanidis, Peter K. [Stanford University; Gu, Baohua [ORNL; Watson, David B [ORNL; Jardine, Philip M [ORNL; Brooks, Scott C [ORNL
2011-03-01
A generalized, efficient, and practical approach based on the travel-time modeling framework is developed to estimate in situ reaction rate coefficients for groundwater remediation in heterogeneous aquifers. The required information for this approach can be obtained by conducting tracer tests with injection of a mixture of conservative and reactive tracers and measurements of both breakthrough curves (BTCs). The conservative BTC is used to infer the travel-time distribution from the injection point to the observation point. For advection-dominant reactive transport with well-mixed reactive species and a constant travel-time distribution, the reactive BTC is obtained by integrating the solutions to advective-reactive transport over the entire travel-time distribution, and then is used in optimization to determine the in situ reaction rate coefficients. By directly working on the conservative and reactive BTCs, this approach avoids costly aquifer characterization and improves the estimation for transport in heterogeneous aquifers which may not be sufficiently described by traditional mechanistic transport models with constant transport parameters. Simplified schemes are proposed for reactive transport with zero-, first-, nth-order, and Michaelis-Menten reactions. The proposed approach is validated by a reactive transport case in a two-dimensional synthetic heterogeneous aquifer and a field-scale bioremediation experiment conducted at Oak Ridge, Tennessee. The field application indicates that ethanol degradation for U(VI)-bioremediation is better approximated by zero-order reaction kinetics than first-order reaction kinetics.
Rate Coefficient Determinations for H + NO2 → OH + NO from High Pressure Flow Reactor Measurements.
Haas, Francis M; Dryer, Frederick L
2015-07-16
Rate coefficients for the reaction H + NO2 → OH + NO (R1) have been determined over the nominal temperature and pressure ranges of 737-882 K and 10-20 atm, respectively, from measurements in two different flow reactor facilities: one laminar and one turbulent. Considering the existing database of experimental k1 measurements, the present conditions add measurements of k1 at previously unconsidered temperatures between ∼820-880 K, as well as at pressures that exceed existing measurements by over an order of magnitude. Experimental measurements of NOx-perturbed H2 oxidation have been interpreted by a quasi-steady state NOx plateau (QSSP) method. At the QSSP conditions considered here, overall reactivity is sensitive only to the rates of R1 and H + O2 + M → HO2 + M (R2.M). Consequently, the ratio of k1 to k2.M may be extracted as a simple algebraic function of measured NO2, O2, and total gas concentrations with only minimal complication (within measurement uncertainty) due to treatment of overall gas composition M that differs slightly from pure bath gas B. Absolute values of k1 have been determined with reference to the relatively well-known, pressure-dependent rate coefficients of R2.B for B = Ar and N2. Rate coefficients for the title reaction determined from present experimental interpretation of both laminar and turbulent flow reactor results appear to be in very good agreement around a representative value of 1.05 × 10(14) cm(3) mol(-1) s(-1) (1.74 × 10(-10) cm(3) molecule(-1) s(-1)). Further, the results of this study agree both with existing low pressure flash photolysis k1 determinations of Ko and Fontijn (J. Phys. Chem. 95 3984) near 760 K as well as a present fit to the theoretical expression of Su et al. (J. Phys. Chem. A 106 8261). These results indicate that, over the temperature range considered in this study and up to at least 20 atm, net chemistry due to stabilization of the H-NO2 reaction intermediate to form isomers of HNO2 may proceed at
Average expansion rate and light propagation in a cosmological Tardis spacetime
Energy Technology Data Exchange (ETDEWEB)
Lavinto, Mikko; Räsänen, Syksy [Department of Physics, University of Helsinki, and Helsinki Institute of Physics, P.O. Box 64, FIN-00014 University of Helsinki (Finland); Szybka, Sebastian J., E-mail: mikko.lavinto@helsinki.fi, E-mail: syksy.rasanen@iki.fi, E-mail: sebastian.szybka@uj.edu.pl [Astronomical Observatory, Jagellonian University, Orla 171, 30-244 Kraków (Poland)
2013-12-01
We construct the first exact statistically homogeneous and isotropic cosmological solution in which inhomogeneity has a significant effect on the expansion rate. The universe is modelled as a Swiss Cheese, with dust FRW background and inhomogeneous holes. We show that if the holes are described by the quasispherical Szekeres solution, their average expansion rate is close to the background under certain rather general conditions. We specialise to spherically symmetric holes and violate one of these conditions. As a result, the average expansion rate at late times grows relative to the background, \\ie backreaction is significant. The holes fit smoothly into the background, but are larger on the inside than a corresponding background domain: we call them Tardis regions. We study light propagation, find the effective equations of state and consider the relation of the spatially averaged expansion rate to the redshift and the angular diameter distance.
Kustova, E. V.; Savelev, A. S.; Kunova, O. V.
2018-05-01
Theoretical models for the vibrational state-resolved Zeldovich reaction are assessed by comparison with the results of quasi-classical trajectory (QCT) calculations. An error in the model of Aliat is corrected; the model is generalized taking into account NO vibrational states. The proposed model is fairly simple and can be easily implemented to the software for non-equilibrium flow modeling. It provides a good agreement with the QCT rate coefficients in the whole range of temperatures and reagent/product vibrational states. The developed models are tested in simulations of vibrational and chemical relaxation of air mixture behind a shock wave. The importance of accounting for excitated NO vibrational states and accurate prediction of Zeldovich reactions rates is shown.
Recommended data on proton-ion collision rate coefficients for Fe X-Fe XV ions
International Nuclear Information System (INIS)
Skobelev, I.; Murakami, I.; Kato, T.
2006-01-01
The proton-ion collisions are important for excitation of some ion levels in a high-temperature low density plasma. In the present work evaluation of data obtained for proton-induced transitions in Fe X - Fe XV ions with the help of different theoretical methods is carried out. It is suggested a simple analytical formula with 7 parameters allowing to describe dependency of proton rate coefficient on proton temperature in an enough wide temperature range. The values of free parameters have been determined by fitting of approximation formula to numerical data and are presented for recommended data together with fitting accuracies. By comparing of proton collision rates with electron ones it is shown that proton impact excitation processes may be important for Fe X, XI, XIII-XV ions. The results obtained can be used for plasma kinetics calculations and for development of spectroscopy methods of plasma diagnostics. (author)
Dynamics of a Computer Virus Propagation Model with Delays and Graded Infection Rate
Directory of Open Access Journals (Sweden)
Zizhen Zhang
2017-01-01
Full Text Available A four-compartment computer virus propagation model with two delays and graded infection rate is investigated in this paper. The critical values where a Hopf bifurcation occurs are obtained by analyzing the distribution of eigenvalues of the corresponding characteristic equation. In succession, direction and stability of the Hopf bifurcation when the two delays are not equal are determined by using normal form theory and center manifold theorem. Finally, some numerical simulations are also carried out to justify the obtained theoretical results.
A high-repetition rate LWFA for studies of laser propagation and electron generation
He, Zhaohan; Easter, James; Hou, Bixue; Krushelnick, Karl; Nees, John; Thomas, Alec
2010-11-01
Advances in ultrafast optics today have enabled laser systems to deliver ever shorter and more intense pulses. When focused, such laser pulses can easily exceed relativistic intensities where the wakefield created by the strong laser electric field can be used to accelerate electrons. Laser wakefield acceleration of electrons holds promise for future compact electron accelerators or drivers of other radiation sources in many scientific, medical and engineering applications. We present experimental studies of laser wakefield acceleration using the λ-cubed laser at the University of Michigan -- a table-top high-power laser system operating at 500 Hz repetition rate. The high repetition rate allows statistical studies of laser propagation and electron acceleration which are not accessible with typical sub-0.1 Hz repetition rate systems. In addition, we compare the experiments with particle-in-cell simulations using the code OSIRIS.
International Nuclear Information System (INIS)
Schwartz, S.E.
1988-10-01
Although it has been recognized for some time that the rate of reactive uptake of gases in cloudwater can depend on the value of the mass-accommodation coefficient (α) describing interfacial mass transport (MT), definitive evaluation of such rates is only now becoming possible with the availability of measurements of α for gases of atmospheric interest at air-water interfaces. Examination of MT limitation to the rate of in-cloud aqueous-phase oxidation of SO 2 by O 3 and H 2 O 2 shows that despite the low value of α/sub O3/ (5 /times/ 10/sup /minus/4/), interfacial MT of this species is not limiting under essentially all conditions of interest; the high values of α for SO 2 (≥ 0.2) and H 2 O 2 (≥ 0.08) indicate no interfacial MT limitation for these species also. Although gas- and aqueous-phase MT can be limiting under certain extremes of conditions, treating the system as under chemical kinetic control is generally an excellent approximation. Interfacial MT limitation also is found not to hinder the rate of H 2 O 2 formation by aqueous-phase disproportionation of HO 2 . Finally, the rapid uptake of N 2 O 5 by cloud droplets implies that the yield of aqueous HNO 3 from in-cloud gas-phase oxidation of NO 2 by O 3 can be substantial even under daytime conditions. This report consists of copies of viewgraphs prepared for this presentation
Rate coefficients for the reactions of ions with polar molecules at interstellar temperatures
International Nuclear Information System (INIS)
Adams, N.G.; Smith, D.; Clary, D.C.
1985-01-01
A theory has been developed recently which predicts that the rate coefficients, k, for the reactions of ions with polar molecules at low temperatures will be much greater than the canonical value of 10 -9 cm 3 s -1 . The new theory indicates that k is greatest for low-lying rotational sates and increases rapidly with decreasing temperature. We refer to recent laboratory measurements which validate the theory, present calculated values of k for the reactions of H + 3 ions with several polar molecules, and discuss their significance to interstellar chemistry. For the reactions of ions with molecules having large dipole moments, we recommend that k values as large as 10 -7 cm 3 s -1 should be used in ion-chemical models of low-temperature interstellar clouds
Lewandowska, Monika; Herzog, Robert; Malinowski, Leszek
2015-01-01
A heat slug propagation experiment in the final design dual channel ITER TF CICC was performed in the SULTAN test facility at EPFL-CRPP in Villigen PSI. We analyzed the data resulting from this experiment to determine the equivalent transverse heat transfer coefficient hBC between the bundle and the central channel of this cable. In the data analysis we used methods based on the analytical solutions of a problem of transient heat transfer in a dual-channel cable, similar to Renard et al. (2006) and Bottura et al. (2006). The observed experimental and other limits related to these methods are identified and possible modifications proposed. One result from our analysis is that the hBC values obtained with different methods differ by up to a factor of 2. We have also observed that the uncertainties of hBC in both methods considered are much larger than those reported earlier.
Rate Coefficients of the Reaction of OH with Allene and Propyne at High Temperatures
Es-sebbar, Et-touhami
2016-09-28
Allene (H2C═C═CH2; a-C3H4) and propyne (CH3C≡CH; p-C3H4) are important species in various chemical environments. In combustion processes, the reactions of hydroxyl radicals with a-C3H4 and p-C3H4 are critical in the overall fuel oxidation system. In this work, rate coefficients of OH radicals with allene (OH + H2C═C═CH2 → products) and propyne (OH + CH3C≡CH → products) were measured behind reflected shock waves over the temperature range of 843–1352 K and pressures near 1.5 atm. Hydroxyl radicals were generated by rapid thermal decomposition of tert-butyl hydroperoxide ((CH3)3–CO–OH), and monitored by narrow line width laser absorption of the well-characterized R1(5) electronic transition of the OH A–X (0,0) electronic system near 306.7 nm. Results show that allene reacts faster with OH radicals than propyne over the temperature range of this study. Measured rate coefficients can be expressed in Arrhenius form as follows: kallene+OH(T) = 8.51(±0.03) × 10–22T3.05 exp(2215(±3)/T), T = 843–1352 K; kpropyne+OH(T) = 1.30(±0.07) × 10–21T3.01 exp(1140(±6)/T), T = 846–1335 K.
Cold collisions of SH- with He: Potential energy surface and rate coefficients
Bop, C. T.; Trabelsi, T.; Hammami, K.; Mogren Al Mogren, M.; Lique, F.; Hochlaf, M.
2017-09-01
Collisional energy transfer under cold conditions is of great importance from the fundamental and applicative point of view. Here, we investigate low temperature collisions of the SH- anion with He. We have generated a three-dimensional potential energy surface (PES) for the SH-(X1Σ+)-He(1S) van der Waals complex. The ab initio multi-dimensional interaction PES was computed using the explicitly correlated coupled cluster approach with simple, double, and perturbative triple excitation in conjunction with the augmented-correlation consistent-polarized valence triple zeta Gaussian basis set. The PES presents two minima located at linear geometries. Then, the PES was averaged over the ground vibrational wave function of the SH- molecule and the resulting two-dimensional PES was incorporated into exact quantum mechanical close coupling calculations to study the collisional excitation of SH- by He. We have computed inelastic cross sections among the 11 first rotational levels of SH- for energies up to 2500 cm-1. (De-)excitation rate coefficients were deduced for temperatures ranging from 1 to 300 K by thermally averaging the cross sections. We also performed calculations using the new PES for a fixed internuclear SH- distance. Both sets of results were found to be in reasonable agreement despite differences existing at low temperatures confirming that accurate predictions require the consideration of all internal degrees of freedom in the case of molecular hydrides. The rate coefficients presented here may be useful in interpreting future experimental work on the SH- negative ion colliding with He as those recently done for the OH--He collisional system as well as for possible astrophysical applications in case SH- would be detected in the interstellar medium.
Tong, Meiping; Camesano, Terri A; Johnson, William P
2005-05-15
The transport of bacterial strain DA001 was examined in packed quartz sand under a variety of environmentally relevant ionic strength and flow conditions. Under all conditions, the retained bacterial concentrations decreased with distance from the column inlet at a rate that was faster than loglinear, indicating that the deposition rate coefficient decreased with increasing transport distance. The hyperexponential retained profile contrasted againstthe nonmonotonic retained profiles that had been previously observed for this same bacterial strain in glass bead porous media, demonstrating that the form of deviation from log-linear behavior is highly sensitive to system conditions. The deposition rate constants in quartz sand were orders of magnitude below those expected from filtration theory, even in the absence of electrostatic energy barriers. The degree of hyperexponential deviation of the retained profiles from loglinear behavior did not decrease with increasing ionic strength in quartz sand. These observations demonstrate thatthe observed low adhesion and deviation from log-linear behavior was not driven by electrostatic repulsion. Measurements of the interaction forces between DA001 cells and the silicon nitride tip of an atomic force microscope (AFM) showed that the bacterium possesses surface polymers with an average equilibrium length of 59.8 nm. AFM adhesion force measurements revealed low adhesion affinities between silicon nitride and DA001 polymers with approximately 95% of adhesion forces having magnitudes responsible for the low adhesion to silicon nitride, indicating that steric interactions from extracellular polymers controlled DA001 adhesion deficiency and deviation from log-linear behavior on quartz sand.
Energy Technology Data Exchange (ETDEWEB)
Laporta, V. [Istituto di Metodologie Inorganiche e dei Plasmi, CNR, Bari, Italy and Department of Physics and Astronomy, University College London, London WC1E 6BT (United Kingdom); Celiberto, R. [Dipartimento di Ingegneria Civile, Ambientale, del Territorio, Edile e di Chimica, Politecnico di Bari, Italy and Istituto di Metodologie Inorganiche e dei Plasmi, CNR, Bari (Italy); Tennyson, J. [Department of Physics and Astronomy, University College London, London WC1E 6BT (United Kingdom)
2014-12-09
Rate coefficients for dissociative electron attachment and electron-impact dissociation processes, involving vibrationally excited molecular oxygen, are presented. Analytical fits of the calculated numerical data, useful in the applications, are also provided.
Modelling hard and soft states of Cygnus X-1 with propagating mass accretion rate fluctuations
Rapisarda, S.; Ingram, A.; van der Klis, M.
2017-12-01
We present a timing analysis of three Rossi X-ray Timing Explorer observations of the black hole binary Cygnus X-1 with the propagating mass accretion rate fluctuations model PROPFLUC. The model simultaneously predicts power spectra, time lags and coherence of the variability as a function of energy. The observations cover the soft and hard states of the source, and the transition between the two. We find good agreement between model predictions and data in the hard and soft states. Our analysis suggests that in the soft state the fluctuations propagate in an optically thin hot flow extending up to large radii above and below a stable optically thick disc. In the hard state, our results are consistent with a truncated disc geometry, where the hot flow extends radially inside the inner radius of the disc. In the transition from soft to hard state, the characteristics of the rapid variability are too complex to be successfully described with PROPFLUC. The surface density profile of the hot flow predicted by our model and the lack of quasi-periodic oscillations in the soft and hard states suggest that the spin of the black hole is aligned with the inner accretion disc and therefore probably with the rotational axis of the binary system.
Fukuda, Makoto; Yoshimura, Kengo; Namekawa, Koki; Sakai, Kiyotaka
2017-06-01
The objective of the present study is to evaluate the effect of filtration coefficient and internal filtration on dialysis fluid flow and mass transfer coefficient in dialyzers using dimensionless mass transfer correlation equations. Aqueous solution of vitamin B 12 clearances were obtained for REXEED-15L as a low flux dialyzer, and APS-15EA and APS-15UA as high flux dialyzers. All the other design specifications were identical for these dialyzers except for filtration coefficient. The overall mass transfer coefficient was calculated, moreover, the exponents of Reynolds number (Re) and film mass transfer coefficient of the dialysis-side fluid (k D ) for each flow rate were derived from the Wilson plot and dimensionless correlation equation. The exponents of Re were 0.4 for the low flux dialyzer whereas 0.5 for the high flux dialyzers. Dialysis fluid of the low flux dialyzer was close to laminar flow because of its low filtration coefficient. On the other hand, dialysis fluid of the high flux dialyzers was assumed to be orthogonal flow. Higher filtration coefficient was associated with higher k D influenced by mass transfer rate through diffusion and internal filtration. Higher filtration coefficient of dialyzers and internal filtration affect orthogonal flow of dialysis fluid.
International Nuclear Information System (INIS)
Riahi, R.; Ben Lakhdar, Z.; Teulet, Ph.; Gleizes, A.
2006-01-01
The weighted total cross-sections (WTCS) theory is used to calculate electron impact excitation, ionization and dissociation cross-sections and rate coefficients of OH, H 2 , OH + , H 2 + , OH - and H 2 - diatomic molecules in the temperature range 1500-15000 K. Calculations are performed for H 2 (X, B, C), OH(X, A, B), H 2 + (X), OH + (X, a, A, b, c), H 2 - (X) and OH - (X) electronic states for which Dunham coefficients are available. Rate coefficients are calculated from WTCS assuming Maxwellian energy distribution functions for electrons and heavy particles. One and 2 temperatures (θ e and θ g respectively for electron and heavy particles kinetic temperatures) results are presented and fitting parameters (a, b and c) are given for each reaction rate coefficient: k(θ) a(θ b )exp(-c/θ). (authors)
Determination of the reaction rate coefficient of sulphide mine tailings deposited under water.
Awoh, Akué Sylvette; Mbonimpa, Mamert; Bussière, Bruno
2013-10-15
The efficiency of a water cover to limit dissolved oxygen (DO) availability to underlying acid-generating mine tailings can be assessed by calculating the DO flux at the tailings-water interface. Fick's equations, which are generally used to calculate this flux, require knowing the effective DO diffusion coefficient (Dw) and the reaction (consumption) rate coefficient (Kr) of the tailings, or the DO concentration profile. Whereas Dw can be accurately estimated, few studies have measured the parameter Kr for submerged sulphide tailings. The objective of this study was to determine Kr for underwater sulphide tailings in a laboratory experiment. Samples of sulphide mine tailings (an approximately 6 cm layer) were placed in a cell under a water cover (approximately 2 cm) maintained at constant DO concentration. Two tailings were studied: TA1 with high sulphide content (83% pyrite) and TA2 with low sulphide content (2.8% pyrite). DO concentration was measured with a microelectrode at various depths above and below the tailings-water interface at 1 mm intervals. Results indicate that steady-state condition was rapidly attained. As expected, a diffusive boundary layer (DBL) was observed in all cases. An iterative back-calculation process using the numerical code POLLUTEv6 and taking the DBL into account provided the Kr values used to match calculated and experimental concentration profiles. Kr obtained for tailings TA1 and TA2 was about 80 d(-1) and 6.5 d(-1), respectively. For comparison purposes, Kr obtained from cell tests on tailings TA1 was lower than Kr calculated from the sulphate production rate obtained from shake-flask tests. Steady-state DO flux at the water-tailings interface was then calculated with POLLUTEv6 using tailings characteristics Dw and Kr. For the tested conditions, DO flux ranged from 608 to 758 mg O2/m(2)/d for tailings TA1 and from 177 to 221 mg O2/m(2)/d for tailings TA2. The impact of placing a protective layer of inert material over
Effect of flow rate on the adsorption coefficient of radioactive krypton on activated carbon
International Nuclear Information System (INIS)
Sun, L.S.C.; Underhill, D.W.
1981-01-01
For some time, there have been questions relative to the effect of carrier gas velocity on the adsorption coefficient for radioactive noble gases on activated charcoal. Resolution of these questions is particularly important in terms of developing standard procedures for determining such coefficients under laboratory conditions. Studies at the Harvard Air Cleaning Laboratory appear to confirm that the adsorption coefficient for radioactive krypton on activated charcoal is independent of the velocity of the carrier gas
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M.A. Chowdhury
2013-12-01
Full Text Available In the present study, friction coefficient and wear rate of gear fiber reinforced plastic (gear fiber and glass fiber reinforced plastic (glass fiber sliding against mild steel are investigated experimentally. In order to do so, a pin on disc apparatus is designed and fabricated. Experiments are carried out when smooth or rough mild steel pin slides on gear fiber and glass fiber disc. Experiments are conducted at normal load 10, 15 and 20 N, sliding velocity 1, 1.5 and 2 m/s and relative humidity 70%. Variations of friction coefficient with the duration of rubbing at different normal loads and sliding velocities are investigated. Results show that friction coefficient is influenced by duration of rubbing, normal load and sliding velocity. In general, friction coefficient increases for a certain duration of rubbing and after that it remains constant for the rest of the experimental time. The obtained results reveal that friction coefficient decreases with the increase in normal load for gear fiber and glass fiber mating with smooth or rough mild steel counterface. On the other hand, it is also found that friction coefficient increases with the increase in sliding velocity for both of the tested materials. Moreover, wear rate increases with the increase in normal load and sliding velocity. The magnitudes of friction coefficient and wear rate are different depending on sliding velocity and normal load for both smooth and rough counterface pin materials.
Effect of kappa distribution on the damping rate of the obliquely propagating magnetosonic mode
Imran, Ali KHAN; G, MURTAZA
2018-03-01
Data from spacecrafts suggest that space plasma has an abundance of suprathermal particles which are controlled by the spectral index κ when modeled on kappa particle velocity distribution. In this paper, considering homogeneous plasma, the effect of integer values of κ on the damping rate of an obliquely propagating magnetosonic (MS) wave is studied. The frequency of the MS wave is assumed to be less than ion cyclotron frequency, i.e., ω \\ll {ω }{{i}}. Under this assumption, the dispersion relation is investigated both numerically and analytically, and it is found that the real frequency of the wave is not a sensitive function of κ, but the imaginary part of the frequency is. It is also shown that for those values of κ where a large number of resonant particles participate in wave-particle interaction, the wave is heavily damped, as expected. The possible application of the results to the solar wind is discussed.
International Nuclear Information System (INIS)
Zokaei-Kadijani, S.; Safdari, J.; Mousavian, M.A.; Rashidi, A.
2013-01-01
Highlights: ► Mass transfer coefficient does not depend on biomass concentration. ► The pulp density has a negative effect on mass transfer coefficient. ► The pulp density is the unique factor that affects maximum OUR. ► In this work, Neale’s correlation is corrected for prediction of mass transfer coefficient. ► Biochemical reaction is a limiting factor in the uranium bioleaching process. - Abstract: In this work, the volumetric oxygen mass transfer coefficient and the oxygen uptake rate (OUR) were studied for uranium ore bioleaching process by Acidthiobacillus ferrooxidans in a stirred tank reactor. The Box-Bohnken design method was used to study the effect of operating parameters on the oxygen mass transfer coefficient. The investigated factors were agitation speed (rpm), aeration rate (vvm) and pulp density (% weight/volume) of the stirred tank reactor. Analysis of experimental results showed that the oxygen mass transfer coefficient had low dependence on biomass concentration but had higher dependence on the agitation speed, aeration rate and pulp density. The obtained biological enhancement factors were equal to ones in experiments. On the other hand, the obtained values for Damkohler number (Da < 0.468) indicated that the process was limited by the biochemical reaction rate. Experimental results obtained for oxygen mass transfer coefficient were correlated with the empirical relations proposed by Garcia-Ochoa and Gomez (2009) and Neale and Pinches (1994). Due to the high relative error in the correlation of Neale and Pinches, that correlation was corrected and the coefficient of determination was calculated to be 89%. The modified correlation has been obtained based on a wide range of operating conditions, which can be used to determine the mass transfer coefficient in a bioreactor
Luiz Carlos H. Ricardo; Carlos Alexandre J. Miranda
2016-01-01
Crack propagation simulation began with the development of the finite element method; the analyses were conducted to obtain a basic understanding of the crack growth. Today structural and materials engineers develop structures and materials properties using this technique as criterion design. The aim of this paper is to verify the effect of different crack propagation rates in determination of crack opening and closing stress of an ASTM specimen under a standard suspension spectrum loading fr...
Cranor, W.L.; Alvarez, D.A.; Huckins, J.N.; Petty, J.D.
2009-01-01
To fully utilize semipermeable membrane devices (SPMDs) as passive samplers in air monitoring, data are required to accurately estimate airborne concentrations of environmental contaminants. Limited uptake rate constants (kua) and no SPMD air partitioning coefficient (Ksa) existed for vapor-phase contaminants. This research was conducted to expand the existing body of kinetic data for SPMD air sampling by determining kua and Ksa for a number of airborne contaminants including the chemical classes: polycyclic aromatic hydrocarbons, organochlorine pesticides, brominated diphenyl ethers, phthalate esters, synthetic pyrethroids, and organophosphate/organosulfur pesticides. The kuas were obtained for 48 of 50 chemicals investigated and ranged from 0.03 to 3.07??m3??g-1??d-1. In cases where uptake was approaching equilibrium, Ksas were approximated. Ksa values (no units) were determined or estimated for 48 of the chemicals investigated and ranging from 3.84E+5 to 7.34E+7. This research utilized a test system (United States Patent 6,877,724 B1) which afforded the capability to generate and maintain constant concentrations of vapor-phase chemical mixtures. The test system and experimental design employed gave reproducible results during experimental runs spanning more than two years. This reproducibility was shown by obtaining mean kua values (n??=??3) of anthracene and p,p???-DDE at 0.96 and 1.57??m3??g-1??d-1 with relative standard deviations of 8.4% and 8.6% respectively.
Population densities and rate coefficients for electron impact excitation in singly ionized oxygen
International Nuclear Information System (INIS)
Awakowicz, P.; Behringer, K.
1995-01-01
In non-LTE arc plasmas, O II excited state number densities were measured relative to the O II ground and metastable states. The results were compared with collisional-radiative code calculations on the basis of the JET ADAS programs. Stationary He plasmas with small oxygen admixtures, generated in a 5 mm diameter cascade arc chamber (pressures 13-70 hPa, arc current 150 A), were investigated spectroscopically in the visible and the VUV spectral range. The continuum of a 2 mm diameter pure He arc (atmospheric pressure, current 100 A) served for calibration of the VUV system response. Plasma diagnostics on the basis of Hβ Stark broadening yielded electron densities between 2.4 x 10 14 and 2.0 x 10 15 cm -3 for the low-pressure O II mixture plasmas. The agreement of measured and calculated excited state populations is generally very satisfactory, thus confirming the rate coefficients in the code. This is of particular interest in this intermediate region between corona balance and LTE, where many atomic data are required in the simulation. Clear indications were found for the diffusion of metastables lowering their number densities significantly below their statistical values. (author)
Lenzen, Matthias; Merklein, Marion
2017-10-01
In the automotive sector, a major challenge is the deep-drawing of modern lightweight sheet metals with limited formability. Thus, conventional material models lack in accuracy due to the complex material behavior. A current field of research takes into account the evolution of the Lankford coefficient. Today, changes in anisotropy under increasing degree of deformation are not considered. Only a consolidated average value of the Lankford coefficient is included in conventional material models. This leads to an increasing error in prediction of the flow behavior and therefore to an inaccurate prognosis of the forming behavior. To increase the accuracy of the prediction quality, the strain dependent Lankford coefficient should be respected, because the R-value has a direct effect on the contour of the associated flow rule. Further, the investigated materials show a more or less extinct rate dependency of the yield stress. For this reason, the rate dependency of the Lankford coefficient during uniaxial tension is focused within this contribution. To quantify the influence of strain rate on the Lankford coefficient, tensile tests are performed for three commonly used materials, the aluminum alloy AA6016-T4, the advanced high strength steel DP800 and the deep drawing steel DC06 at three different strain rates. The strain measurement is carried out by an optical strain measurement system. An evolution of the Lankford coefficient was observed for all investigated materials. Also, an influence of the deformation velocity on the anisotropy could be detected.
International Nuclear Information System (INIS)
Taira, S.; Fujino, M.; Maruyama, S.
Temperature dependence of the rate of fatigue crack propagation in steels was examined, and compared with the temperature dependence of tensile ductility. Microcracks initiate and affect the propagation behavior of the main crack at elevated temperatures. Factors found to be elucidated include initiation rate of microcracks, reduction of ductility of the material in the vicinity of the main crack tip, and relaxation of concentrated strain by multi-cracks. It was found that during a strain controlled low cycle fatigue test at 1 cpm, the rate of crack propagation is largest at the blue-brittleness temperature range (200 to 300 0 C) in a low carbon steel. On the other hand, it is largest at above 700 0 C in austenite stainless steels. The temperature dependence of the rate of fatigue crack propagation is opposite to that of tensile ductility. Microcracks formed in the vicinity of the main crack tip were calculated, by considering the strain concentration and strain cycles imposed. Then, the local fracture strain was evaluated. Good correlation was found between the rate of crack propagation and the local fracture strain. (U.S.)
Directory of Open Access Journals (Sweden)
Luiz Carlos H. Ricardo
2016-03-01
Full Text Available Crack propagation simulation began with the development of the finite element method; the analyses were conducted to obtain a basic understanding of the crack growth. Today structural and materials engineers develop structures and materials properties using this technique as criterion design. The aim of this paper is to verify the effect of different crack propagation rates in determination of crack opening and closing stress of an ASTM specimen under a standard suspension spectrum loading from FD&E SAE Keyhole Specimen Test Load Histories by finite element analysis. The crack propagation simulation was based on release nodes at the minimum loads to minimize convergence problems. To understand the crack propagation processes under variable amplitude loading, retardation effects are discussed.
Study on crack propagation of adhesively bonded DCB for aluminum foam using energy release rate
Energy Technology Data Exchange (ETDEWEB)
Bang, Hye Jin; Lee, Sang Kyo; Cho, Chong Du [Inha University, Incheon (Korea, Republic of); Cho, Jae Ung [Kongju National University, Choenan (Korea, Republic of)
2015-01-15
Aluminum foam with initial crack, which has a closed cell form adhesively bonded, is studied to compare and analyze the crack propagation behavior by using both experimental and finite element analysis techniques. The specimen is loaded in Mode I type of fracture as 15 mm/min speed of a displacement control method. The experimental results were used to accommodate the finite element analysis performed with commercial software ABAQUS 6.10. First, using a video recording, five steps of experiment were selected at random and then the energy release rate was calculated. The estimated energy release rate was then used as fracture energy into the finite element analysis. Comparing the experimental axial load-displacement graphs and the finite element analysis results, roughly equivalent peak values were observed in the cohesive strength of the aluminum foam double cantilever beam. However, force versus displacement patterns showed somewhat different: little deformation was observed in aluminum foam, whereas adhesive parts in double cantilever beam were significantly deformed.
EFFECTS OF TIN ON HARDNESS, WEAR RATE AND COEFFICIENT OF FRICTION OF CAST CU-NI-SN ALLOYS
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S. ILANGOVAN
2013-02-01
Full Text Available An investigation was carried out to understand the effects of Sn on hardness, wear rate and the coefficient of friction of spinodal Cu-Ni-Sn alloys. Alloys of appropriate compositions were melted in a crucible furnace under argon atmosphere and cast into sand moulds. Solution heat treated and aged specimens were tested for hardness, wear rate and the coefficient of friction. It was found that the hardness increases when the Sn content increases from 4% to 8% in the solution heat treated conditions. The peak aging time is found to decrease with an increase in the Sn content. Further, the coefficient of friction is independent of hardness whereas the wear rate decreases linearly with hardness irrespective of Sn content.
International Nuclear Information System (INIS)
Herbst, E.; Leung, C.M.; Rensselaer Polytechnic Institute, Troy, NY)
1986-01-01
Pseudo-time-dependent models of the gas phase chemistry of dense interstellar clouds have been run with large rate coefficients for reactions between ions and polar neutral species, as advocated by Adams, Smith, and Clary. The higher rate coefficients normally lead to a reduction in both the peak and steady state abundances of polar neutrals, which can be as large as an order of magnitude but is more often smaller. Other differences between the results of these models and previous results are also discussed. 38 references
Determination of I-SCC crack propagation rate of zircaloy-4
International Nuclear Information System (INIS)
Woo-Seog, Ryu
2002-01-01
Threshold stress intensity (K ISCC ) and propagation rate of iodine-induced SCC in recrystallized and stress-relieved Zircaloy-4 were determined using a DCPD method. Dynamic system flowing Ar gas through iodine chamber at 60 deg C provided a constant iodine pressure of 1000 Pa during test. The SCC curves of crack velocity vs. stress intensity showed the typical SCC curves that are composed of stages I, II and III. The threshold K ISCC at 350 deg C was about 9 and 9.5 MPa √m for the stress- relieved Zircaloy-4 and the recrystallized Zircaloy-4, respectively. The plateau velocity in the stage II at 350 deg C was 4-8x 10 -4 mm/sec in the range of 20-40 MPa√m. In comparison with recrystallized Zircaloy-4, stress-relieved Zircaloy-4 had a lower threshold stress intensity factor and a little higher SCC velocity, indicating that SRA Zircaloy-4 was more sensitive to SCC in respect of velocity. The fracture mode in recrystallized Zircaloy was mostly a transgranular fracture with river pattern. An intergranular mode and the flutting were scarcely observed. (author)
Gas-phase rate coefficients of the reaction of ozone with four sesquiterpenes at 295 ± 2 K.
Richters, Stefanie; Herrmann, Hartmut; Berndt, Torsten
2015-05-07
The rate coefficients of the reaction of ozone with the four atmospherically relevant sesquiterpenes β-caryophyllene, α-humulene, α-cedrene and isolongifolene were investigated at 295 ± 2 K and atmospheric pressure by at least two independent experimental investigations for each reaction. Relative rate experiments were carried out in a flow tube using two different experimental approaches with GC-MS detection (RR 1) and PTR-MS analysis (RR 2) as the analytical techniques. Absolute rate coefficients were determined in a stopped-flow experiment following the ozone depletion by means of UV spectroscopy. The average rate coefficients from the combined investigations representing the mean values of the different experimental methods are (unit: cm(3) molecule(-1) s(-1)): k(O3+β-caryophyllene) = (1.1 ± 0.3) × 10(-14) (methods: RR 1, RR 2, absolute), k(O3+α-humulene) = (1.2 ± 0.3) × 10(-14) (RR 1, RR 2), k(O3+α-cedrene) = (1.7 ± 0.5) × 10(-16) (RR 2, absolute) and k(O3+isolongifolene) = (1.1 ± 0.5) × 10(-17) (RR 2, absolute). The high ozonolysis rate coefficients for β-caryophyllene and α-humulene agree well with the results by Shu and Atkinson (Int. J. Chem. Kinet., 1994, 26) and lead to short atmospheric lifetimes of about two minutes with respect to the ozone reaction. The relatively small rate coefficients for α-cedrene and isolongifolene differ from the available literature values by a factor of about 2.5-6. Possible reasons for the deviations are discussed. Finally, calibrated sesquiterpene FT-IR spectra were recorded for the first time.
International Nuclear Information System (INIS)
Takamatsu, H.; Matsueda, K.; Matsunaga, T.; Kitera, T.; Arioka, K.; Tsuruta, T.; Okamoto, S.
1993-01-01
IGA/SCC crack propagation rate measurements using various types of IGA/SCC predefected ALloy 600 tubing were tested in model boilers, a side stream model boiler at Ohi Unit 1 and similar model boilers in the laboratory. Types of IGA/SCC predefects introduced from the outside of the tubing were as follows. (1) Actual IGA/SCC predefect introduced by high temperature caustic environments; (2) Longitudinal predefect by electrodischarge machining (EDM) method, and then crack tip fatigue was introduced to serve as the marker on the fractured surface (EDM slit + fatigue). IGA/SCC crack propagation rate was measured after the destructive examination by Cr concentration profile on fracture surface for (1), and observation of intergranular fractured surface propagated from the marked fatigue was employed for (2) and (3) after the model boiler tests. As for the water chemistry conditions, mainly AVT (high N 2 H 4 ) + boric acid (5-10ppm as B in SGs) treatment for both model boilers, and some of the tests for the model boiler in the laboratory employed AVT (high N 2 H 4 ) without boric acid. The results of IGA/SCC crack propagation rate measurements were compared with each other, and the three methods employed showed a good coincidence with the rate of ca. 1 x 10 -5 mm/Hr for AVT (high N 2 H 4 ) + boric acid treatment condition, in the case that crack tip boron intensity (B/O value by IMMA analysis) of more than 1 was observed
Directory of Open Access Journals (Sweden)
Baso Maruddani
2015-01-01
Full Text Available This paper deals with the prediction method using hidden Markov model (HMM for rain rate and rain propagation attenuation for K-band satellite communication link at tropical area. As is well known, the K-band frequency is susceptible of being affected by atmospheric condition, especially in rainy condition. The wavelength of K-band frequency which approaches to the size of rain droplet causes the signal strength is easily attenuated and absorbed by the rain droplet. In order to keep the quality of system performance for K-band satellite communication link, therefore a special attention has to be paid for rain rate and rain propagation attenuation. Thus, a prediction method for rain rate and rain propagation attenuation based on HMM is developed to process the measurement data. The measured and predicted data are then compared with the ITU-R recommendation. From the result, it is shown that the measured and predicted data show similarity with the model of ITU-R P.837-5 recommendation for rain rate and the model of ITU-R P.618-10 recommendation for rain propagation attenuation. Meanwhile, statistical data for measured and predicted data such as fade duration and interfade duration have insignificant discrepancy with the model of ITU-R P.1623-1 recommendation.
Czech Academy of Sciences Publication Activity Database
Pozníková, Gabriela; Fischer, Milan; Pohanková, Eva; Trnka, Miroslav
2014-01-01
Roč. 62, č. 5 (2014), s. 1079-1086 ISSN 1211-8516 R&D Projects: GA MŠk LH12037; GA MŠk(CZ) EE2.3.20.0248 Institutional support: RVO:67179843 Keywords : evapotranspiration * dual crop coefficient model * Bowen ratio/energy balance method * transpiration * soil evaporation * spring barley Subject RIV: EH - Ecology, Behaviour OBOR OECD: Environmental sciences (social aspects to be 5.7)
Effects of Changing Stress Amplitude on the Rate of Fatigue-Crack Propagation in Two Aluminum Alloys
Hudson, C. Michael; Hardrath, Herbert F.
1961-01-01
A series of fatigue tests with specimens subjected to constant amplitude and two-step axial loads were conducted on 12-inch-wide sheet specimens of 2024-T3 and 7075-T6 aluminum alloy to study the effects of a change in stress level on fatigue-crack propagation. Comparison of the results of the tests in which the specimens were tested at first a high and then a low stress level with those of the constant-stress- amplitude tests indicated that crack propagation was generally delayed after the transition to the lower stress level. In the tests in which the specimens were tested at first a low and then a high stress level, crack propagation continued at the expected rate after the change in stress levels.
International Nuclear Information System (INIS)
Kokoouline, V.; Richardson, W.
2014-01-01
Uncertainties in theoretical calculations may include: • Systematic uncertainty: Due to applicability limits of the chosen model. • Random: Within a model, uncertainties of model parameters result in uncertainties of final results (such as cross sections). • If uncertainties of experimental and theoretical data are known, for the purpose of data evaluation (to produce recommended data), one should combine two data sets to produce the best guess data with the smallest possible uncertainty. In many situations, it is possible to assess the accuracy of theoretical calculations because theoretical models usually rely on parameters that are uncertain, but not completely random, i.e. the uncertainties of the parameters of the models are approximately known. If there are one or several such parameters with corresponding uncertainties, even if some or all parameters are correlated, the above approach gives a conceptually simple way to calculate uncertainties of final cross sections (uncertainty propagation). Numerically, the statistical approach to the uncertainty propagation could be computationally expensive. However, in situations, where uncertainties are considered to be as important as the actual cross sections (for data validation or benchmark calculations, for example), such a numerical effort is justified. Having data from different sources (say, from theory and experiment), a systematic statistical approach allows one to compare the data and produce “unbiased” evaluated data with improved uncertainties, if uncertainties of initial data from different sources are available. Without uncertainties, the data evaluation/validation becomes impossible. This is the reason why theoreticians should assess the accuracy of their calculations in one way or another. A statistical and systematic approach, similar to the described above, is preferable.
Baasandorj, Munkhbayar; Ravishankara, A R; Burkholder, James B
2011-09-29
Rate coefficients, k, for the gas-phase reaction of the OH radical with (Z)-CF(3)CH═CHCF(3) (cis-1,1,1,4,4,4-hexafluoro-2-butene) were measured under pseudo-first-order conditions in OH using pulsed laser photolysis (PLP) to produce OH and laser-induced fluorescence (LIF) to detect it. Rate coefficients were measured over a range of temperatures (212-374 K) and bath gas pressures (20-200 Torr; He, N(2)) and found to be independent of pressure over this range of conditions. The rate coefficient has a non-Arrhenius behavior that is well-described by the expression k(1)(T) = (5.73 ± 0.60) × 10(-19) × T(2) × exp[(678 ± 10)/T] cm(3) molecule(-1) s(-1) where k(1)(296 K) was measured to be (4.91 ± 0.50) × 10(-13) cm(3) molecule(-1) s(-1) and the uncertainties are at the 2σ level and include estimated systematic errors. Rate coefficients for the analogous OD radical reaction were determined over a range of temperatures (262-374 K) at 100 Torr (He) to be k(2)(T) = (4.81 ± 0.20) × 10(-19) × T(2) × exp[(776 ± 15)/T], with k(2)(296 K) = (5.73 ± 0.50) × 10(-13) cm(3) molecule(-1) s(-1). OH radical rate coefficients were also measured at 296, 345, and 375 K using a relative rate technique and found to be in good agreement with the PLP-LIF results. A room-temperature rate coefficient for the O(3) + (Z)-CF(3)CH═CHCF(3) reaction was measured using an absolute method with O(3) in excess to be reaction was estimated to be ~20 days. Infrared absorption spectra of (Z)-CF(3)CH═CHCF(3) measured in this work were used to determine a (Z)-CF(3)CH═CHCF(3) global warming potential (GWP) of ~9 for the 100 year time horizon. A comparison of the OH reactivity of (Z)-CF(3)CH═CHCF(3) with other unsaturated fluorinated compounds is presented.
Chung, Hoi Sung; Gopich, Irina V; McHale, Kevin; Cellmer, Troy; Louis, John M; Eaton, William A
2011-04-28
Recently developed statistical methods by Gopich and Szabo were used to extract folding and unfolding rate coefficients from single-molecule Förster resonance energy transfer (FRET) data for proteins with kinetics too fast to measure waiting time distributions. Two types of experiments and two different analyses were performed. In one experiment bursts of photons were collected from donor and acceptor fluorophores attached to a 73-residue protein, α(3)D, freely diffusing through the illuminated volume of a confocal microscope system. In the second, the protein was immobilized by linkage to a surface, and photons were collected until one of the fluorophores bleached. Folding and unfolding rate coefficients and mean FRET efficiencies for the folded and unfolded subpopulations were obtained from a photon by photon analysis of the trajectories using a maximum likelihood method. The ability of the method to describe the data in terms of a two-state model was checked by recoloring the photon trajectories with the extracted parameters and comparing the calculated FRET efficiency histograms with the measured histograms. The sum of the rate coefficients for the two-state model agreed to within 30% with the relaxation rate obtained from the decay of the donor-acceptor cross-correlation function, confirming the high accuracy of the method. Interestingly, apparently reliable rate coefficients could be extracted using the maximum likelihood method, even at low (rate coefficients and mean FRET efficiencies were also obtained in an approximate procedure by simply fitting the FRET efficiency histograms, calculated by binning the donor and acceptor photons, with a sum of three-Gaussian functions. The kinetics are exposed in these histograms by the growth of a FRET efficiency peak at values intermediate between the folded and unfolded peaks as the bin size increases, a phenomenon with similarities to NMR exchange broadening. When comparable populations of folded and unfolded
Modelling probabilistic fatigue crack propagation rates for a mild structural steel
Directory of Open Access Journals (Sweden)
J.A.F.O. Correia
2015-01-01
Full Text Available A class of fatigue crack growth models based on elastic–plastic stress–strain histories at the crack tip region and local strain-life damage models have been proposed in literature. The fatigue crack growth is regarded as a process of continuous crack initializations over successive elementary material blocks, which may be governed by smooth strain-life damage data. Some approaches account for the residual stresses developing at the crack tip in the actual crack driving force assessment, allowing mean stresses and loading sequential effects to be modelled. An extension of the fatigue crack propagation model originally proposed by Noroozi et al. (2005 to derive probabilistic fatigue crack propagation data is proposed, in particular concerning the derivation of probabilistic da/dN-ΔK-R fields. The elastic-plastic stresses at the vicinity of the crack tip, computed using simplified formulae, are compared with the stresses computed using an elasticplastic finite element analyses for specimens considered in the experimental program proposed to derive the fatigue crack propagation data. Using probabilistic strain-life data available for the S355 structural mild steel, probabilistic crack propagation fields are generated, for several stress ratios, and compared with experimental fatigue crack propagation data. A satisfactory agreement between the predicted probabilistic fields and experimental data is observed.
Rating of Dynamic Coefficient for Simple Beam Bridge Design on High-Speed Railways
Diachenko, Leonid; Benin, Andrey; Smirnov, Vladimir; Diachenko, Anastasia
2018-06-01
The aim of the work is to improve the methodology for the dynamic computation of simple beam spans during the impact of high-speed trains. Mathematical simulation utilizing numerical and analytical methods of structural mechanics is used in the research. The article analyses parameters of the effect of high-speed trains on simple beam spanning bridge structures and suggests a technique of determining of the dynamic index to the live load. Reliability of the proposed methodology is confirmed by results of numerical simulation of high-speed train passage over spans with different speeds. The proposed algorithm of dynamic computation is based on a connection between maximum acceleration of the span in the resonance mode of vibrations and the main factors of stress-strain state. The methodology allows determining maximum and also minimum values of the main efforts in the construction that makes possible to perform endurance tests. It is noted that dynamic additions for the components of the stress-strain state (bending moments, transverse force and vertical deflections) are different. This condition determines the necessity for differentiated approach to evaluation of dynamic coefficients performing design verification of I and II groups of limiting state. The practical importance: the methodology of determining the dynamic coefficients allows making dynamic calculation and determining the main efforts in split beam spans without numerical simulation and direct dynamic analysis that significantly reduces the labour costs for design.
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N R Rema
2017-08-01
Full Text Available In this paper, a multiwavelet based fingerprint compression technique using set partitioning in hierarchical trees (SPIHT algorithm with optimised prefilter coefficients is proposed. While wavelet based progressive compression techniques give a blurred image at lower bit rates due to lack of high frequency information, multiwavelets can be used efficiently to represent high frequency information. SA4 (Symmetric Antisymmetric multiwavelet when combined with SPIHT reduces the number of nodes during initialization to 1/4th compared to SPIHT with wavelet. This reduction in nodes leads to improvement in PSNR at lower bit rates. The PSNR can be further improved by optimizing the prefilter coefficients. In this work genetic algorithm (GA is used for optimizing prefilter coefficients. Using the proposed technique, there is a considerable improvement in PSNR at lower bit rates, compared to existing techniques in literature. An overall average improvement of 4.23dB and 2.52dB for bit rates in between 0.01 to 1 has been achieved for the images in the databases FVC 2000 DB1 and FVC 2002 DB3 respectively. The quality of the reconstructed image is better even at higher compression ratios like 80:1 and 100:1. The level of decomposition required for a multiwavelet is lesser compared to a wavelet.
Homayoon, Zahra; Jambrina, Pablo G.; Aoiz, F. Javier; Bowman, Joel M.
2012-07-01
In a previous paper [P. G. Jambrina et al., J. Chem. Phys. 135, 034310 (2011), 10.1063/1.3611400] various calculations of the rate coefficient for the Mu + H2 → MuH + H reaction were presented and compared to experiment. The widely used standard quasiclassical trajectory (QCT) method was shown to overestimate the rate coefficients by several orders of magnitude over the temperature range 200-1000 K. This was attributed to a major failure of that method to describe the correct threshold for the reaction owing to the large difference in zero-point energies (ZPE) of the reactant H2 and product MuH (˜0.32 eV). In this Communication we show that by performing standard QCT calculations for the reverse reaction and then applying detailed balance, the resulting rate coefficient is in very good agreement with the other computational results that respect the ZPE, (as well as with the experiment) but which are more demanding computationally.
International Nuclear Information System (INIS)
Chang, T.; Torr, D.G.; Richards, P.G.; Solomon, S.C.
1993-01-01
O + ( 2 P) is an important species for studies of the ionosphere and thermosphere: its emission at 7320 angstrom can be used as a diagnostic of the thermospheric atomic oxygen density. Unfortunately, there are no laboratory measurements of the O and N 2 reaction rates which are needed to determine the major sinks of O + ( 2 P). The reaction rates that are generally used were determined from aeronomic data by Rusch et al. but there is evidence that several important inputs that they used should be changed. The authors have recalculated the O and N 2 reaction rates for O + ( 2 P) using recent improvements in the solar EUV flux, cross sections, and photoelectron fluxes. For the standard solar EUV flux, the new N 2 reaction rate of 3.4 ± 1.5 x 10 -10 cm 3 s -1 is close to the value obtained by Rusch et al., but the new O reaction rate of 4.0 ± 1.9 x 10 -10 cm 3 s -1 is about 8 times larger. These new reaction rates are derived using neutral densities, electron density, and solar EUV fluxes measured by Atmosphere Explorer C in 1974 during solar minimum. The new theoretical emission rates are in good agreement with the data for the two orbits studied by Rusch et al. and they are in reasonable agreement with data from five additional orbits that are used in this study. The authors have also examined the effect of uncertainties in the solar EUV flux on the derived reaction rates and found that 15% uncertainties in the solar flux could cause additional uncertainties of up to a factor of 1.5 in the O quenching rate. 19 refs., 4 figs., 8 tabs
Rate Coefficient Measurements and Theoretical Analysis of the OH + ( E) CF3CH=CHCF3 Reaction.
Baasandorj, Munkhbayar; Marshall, Paul; Waterland, Robert L; Ravishankara, Akkihebbal R; Burkholder, James B
2018-04-25
Rate coefficients, k, for the gas-phase reaction of the OH radical with (E) CF3CH=CHCF3 ((E)-1,1,14,4,4-hexafluoro-2-butene, HFO-1336mzz(E)) were measured over a range of temperature (211-374 K) and bath gas pressure (20-300 Torr; He, N2) using a pulsed laser photolysis-laser induced fluorescence (PLP-LIF) technique. k1(T) was independent of pressure over this range of conditions with k1(296 K) = (1.31 ± 0.15) × 10 13 cm3 molecule 1 s 1 and k1(T) = (6.94 ± 0.80) × 10 13 exp[ (496 ± 10)/T] cm3 molecule 1 s 1, where the uncertainties are 2 and the pre-exponential term includes estimated systematic error. Rate coefficients for the OD reaction were also determined over a range of temperature (262-374 K) at 100 Torr (He). The OD rate coefficients were ~15% greater than the OH values and showed similar temperature dependent behavior with k2(T) = (7.52 ± 0.44) × 10 13 exp[ (476 ± 20)/T] and k2(296 K) = (1.53 ± 0.15) × 10 13 cm3 molecule 1 s 1. The rate coefficients for reaction 1 were also measured using a relative rate technique between 296 and 375 K with k1(296 K) measured to be (1.22 ± 0.1) × 10 13 cm3 molecule 1 s 1 in agreement with the PLP-LIF results. In addition, the 296 K rate coefficient for the O3 + (E) CF3CH=CHCF3 reaction was determined to be reaction and the significant decrease in OH reactivity compared to the (Z) CF3CH=CHCF3 stereoisomer reaction. The estimated atmospheric lifetime of (E) CF3CH=CHCF3, due to loss by reaction with OH, is estimated to be ~90 days, while the actual lifetime will depend on the location and season of its emission. Infrared absorption spectra of (E) CF3CH=CHCF3 were measured and used to estimate the 100-year time horizon global warming potentials (GWP) of 32 (atmospherically well-mixed) and 14 (lifetime-adjusted).
Rate coefficients for low-energy electron dissociative attachment to molecular hydrogen
International Nuclear Information System (INIS)
Horacek, J.; Houfek, K.; Cizek, M.; Murakami, I.; Kato, T.
2003-02-01
Calculation of rate constants for dissociative electron attachment to molecular hydrogen is reported. The calculation is based on an improved nonlocal resonance model of Cizek, Horacek and Domcke which takes fully into account the nonlocality of the resonance dynamics and uses potentials with correct asymptotic forms. The rate constants are calculated for all quantum numbers v and J of the target molecules and for electron temperature in the range 0-30000 K. (author)
Chang, T.; Torr, D. G.; Richards, P. G.; Solomon, S. C.
1993-01-01
O(+)(2P) is an important species for studies of the ionosphere and thermosphere: its emission at 7320 A can be used as a diagnostic of the thermospheric atomic oxygen density. Unfortunately, there are no laboratory measurements of the O and N2 reaction rates which are needed to determine the major sinks of (O+)(2p). We have recalculated the O and N2 reaction rates for O(+) (2P) using recent improvements in the solar EUV flux, cross sections, and photoelectron fluxes. For the standard solar EUV flux, the new N2 reaction rate of 3.4 +/- 1.5 x 10 exp -10 cu cm/s is close to the value obtained by Rusch et al. (1977), but the new O reaction rate of 4.0 +/- 1.9 x 10 exp -10 cu cm/sec is about 8 times larger. These new reaction rates are derived using neutral densities, electron density, and solar EUV fluxes measured by Atmosphere Explorer C in 1974 during solar minimum. The new theoretical emission rates are in good agreement with the data for the two orbits studied by Rusch et al.
International Nuclear Information System (INIS)
Stiller, W.
1985-01-01
A classical collision theory is used to describe thermal bimolecular rate coefficeints for reaction between positive and negative ions and polar molecules in a carrier gas. Special attention is paid to ion-molecule reaction in which proton transfer occurs. These reactions play an important role in terrestrial plasma devices, in ionosphere, in planetary atmospheres and in interstellar matter. The equilibrium rate coefficients of the reactions are calculated based on a microscopic reactive cross section derived from a long distance polar molecule-ion potential. The results are compared with experimental values of afterglow measurements. (D.Gy.)
Measurements of Drag Coefficients and Rotation Rates of Free-Falling Helixes
Al-Omari, Abdulrhaman A.
2016-05-01
The motion of bacteria in the environment is relevant to several fields. At very small scales and with simple helical shapes, we are able to describe experimentally and mathematically the motion of solid spirals falling freely within a liquid pool. Using these shapes we intend to mimic the motion of bacteria called Spirochetes. We seek to experimentally investigate the linear and the rotational motion of such shapes. A better understanding of the dynamics of this process will be practical not only on engineering and physics, but the bioscience and environmental as well. In the following pages, we explore the role of the shape on the motion of passive solid helixes in different liquids. We fabricate three solid helical shapes and drop them under gravity in water, glycerol and a mixture of 30% glycerol in water. That generated rotation due to helical angle in water. However, we observe the rotation disappear in glycerol. The movement of the solid helical shapes is imaged using a high-speed video camera. Then, the images are analyzed using the supplied software and a computer. Using these simultaneous measurements, we examine the terminal velocity of solid helical shapes. Using this information we computed the drag coefficient and the drag force. We obtain the helical angular velocity and the torque applied to the solid. The results of this study will allow us to more accurately predict the motion of solid helical shape. This analysis will also shed light onto biological questions of bacteria movement.
Qin, Ming; Li, Jianfeng; Chen, Songying; Qu, Yanpeng
FV520B steel is a kind of precipitation hardening Martensitic stainless steel, it has high-strength, good plasticity and good corrosion resistance. Stress corrosion cracking (SCC) is one of the main corrosion failure mode for FV520B in industrial transportation of natural gas operation. For a better understanding the effect on SCC of FV520B, the improved wedge opening loading (WOL) specimens and constant displacement loading methods were employed in experimental research in carbon dioxide and hydrogen sulfide solution. The test results showed that the crack propagation rate is 1.941 × 10-7-5.748 × 10-7 mm/s, the stress intensity factor KISCC is not more than 36.83 MPa √{ m } . The rate increases with the increasing of the crack opening displacement. Under the condition of different initial loading, KISCC generally shows a decreasing tendency with the increase in H2S concentration, and the crack propagation rate showed an increasing trend substantially. For the enrichment of sulfur ion in the crack tip induced the generation of pitting corrosion, promoting the surrounding metal formed the corrosion micro batteries, the pit defects gradually extended and connected with the adjacent pit to form a small crack, leading to further propagation till cracking happened. Fracture microscopic morphology displayed typical brittle fracture phenomena, accompanying with trans-granular cracking, river shape and sector, many second cracks on the fracture surface.
Influence of arbuscular mycorrhizas on the growth rate of mist-propagated olive plantlets
Porras Piedra, A.; Soriano Martín, M.L.; Porras Soriano, A.; Fernández Izquierdo, G.
2005-01-01
The aim of this work was to determine the influence of early inoculation of semi-woody olive cuttings (cv. Cornicabra), cultivated under mist propagation conditions, with arbuscular mycorrhizal fungi. A strongly positive response was seen to root inoculation with the three fungal species tested Glomus mosseae, G. intraradices and G. claroideum both in nursery phase plantlets, and in older plants grown in 5 L pots.
A Review of Rate Coefficients in the D2-F2 Chemical Laser System
1977-08-05
analyzed by subjecting the mixture to a high-frequency dis- charge, then using EPR to assay the relative H and D atom concentrations. The rate...856 ( 1935 ). Anlauf, K. G. , P. E. Charters, D. S. Home, R. G. MacDonald, D. II. Maylotte, J. C. Polanyi, W. J
Energy Technology Data Exchange (ETDEWEB)
Kubo, T., E-mail: kubo@nfd.co.jp [Nippon Nuclear Fuel Development Co., Ltd., 2163 Narita-cho, Oarai-machi, Ibaraki 311-1313 (Japan); Kobayashi, Y. [M.O.X. Co., Ltd., 1828-520 Hirasu-cho, Mito, Ibaraki 311-0853 (Japan); Uchikoshi, H. [Nippon Nuclear Fuel Development Co., Ltd., 2163 Narita-cho, Oarai-machi, Ibaraki 311-1313 (Japan)
2012-08-15
Highlights: Black-Right-Pointing-Pointer The delayed hydride cracking (DHC) velocity of Zircaloy-2 was measured. Black-Right-Pointing-Pointer The velocity followed the Arrhenius law up to 270 Degree-Sign C. Activation energy was 49 kJ/mol. Black-Right-Pointing-Pointer The threshold stress intensity factor for the DHC was from 4 to 6 MPa m{sup 1/2}. Black-Right-Pointing-Pointer An increase in material strength accelerated the DHC. Black-Right-Pointing-Pointer Precipitation and fracture of hydrides at a crack tip is responsible for the DHC. - Abstract: Delayed hydride cracking (DHC) tests of Zircaloy-2 cladding tubes were performed in the chamber of a scanning electron microscope (SEM) to directly observe the crack propagation and measure the crack velocity in the radial direction of the tubes. Pre-cracks were produced at the outer surfaces of the tubes. Hydrogen contents of the tubes were from 90 ppm to 130 ppm and test temperatures were from 225 Degree-Sign C to 300 Degree-Sign C. The crack velocity followed the Arrhenius law at temperatures lower than about 270 Degree-Sign C with apparent activation energy of about 49 kJ/mol. The upper temperature limit for DHC, above which DHC did not occur, was about 280 Degree-Sign C. The threshold stress intensity factor for the initiation of the crack propagation, K{sub IH}, was from about 4 MPa m{sup 1/2} to 6 MPa m{sup 1/2}, almost independent of temperature. An increase in 0.2% offset yield stress of the material accelerated the crack velocity and slightly decreased K{sub IH}. Detailed observations of crack tip movement showed that cracks propagated in an intermittent fashion and the propagation gradually approached the steady state as the crack depth increased. The SEM observations also showed that hydrides were formed at a crack tip and a number of micro-cracks were found in the hydrides. It was presumed from these observations that the repetition of precipitation and fracture of hydrides at the crack tip would be
Determination of the rate coefficient for the N2/+/ + O reaction in the ionosphere
Torr, D. G.; Torr, M. R.; Orsini, N.; Hanson, W. B.; Hoffman, J. H.; Walker, J. C. G.
1977-01-01
Using approximately 400 simultaneous measurements of ion and neutral densities and temperatures, and the spectrum of the solar flux measured by the Atmosphere Explorer C satellite, we have determined the rate constant k1 for the reaction between N2(+) and O in the ionosphere for ion temperatures between 600 and 700 K. We find that k1 = 1.1 x 10 to the minus 10th power cu cm per sec, with a standard deviation of + or - 15%. If we use the temperature dependence for this reaction determined in the laboratory then at 300 K we find excellent agreement with the recommended laboratory value.
Directory of Open Access Journals (Sweden)
Seyed Hassan Fallahzadeh
2017-03-01
Full Text Available Hydraulic fracture initiation and near wellbore propagation is governed by complex failure mechanisms, especially in cased perforated wellbores. Various parameters affect such mechanisms, including fracturing fluid viscosity and injection rate. In this study, three different fracturing fluids with viscosities ranging from 20 to 600 Pa.s were used to investigate the effects of varying fracturing fluid viscosities and fluid injection rates on the fracturing mechanisms. Hydraulic fracturing tests were conducted in cased perforated boreholes made in tight 150 mm synthetic cubic samples. A true tri-axial stress cell was used to simulate real far field stress conditions. In addition, dimensional analyses were performed to correspond the results of lab experiments to field-scale operations. The results indicated that by increasing the fracturing fluid viscosity and injection rate, the fracturing energy increased, and consequently, higher fracturing pressures were observed. However, when the fracturing energy was transferred to a borehole at a faster rate, the fracture initiation angle also increased. This resulted in more curved fracture planes. Accordingly, a new parameter, called fracturing power, was introduced to relate fracture geometry to fluid viscosity and injection rate. Furthermore, it was observed that the presence of casing in the wellbore impacted the stress distribution around the casing in such a way that the fracture propagation deviated from the wellbore vicinity.
M.A. Chowdhury; D.M. Nuruzzaman; B.K. Roy; S. Samad; R. Sarker; A.H.M. Rezwan
2013-01-01
In the present study, friction coefficient and wear rate of gear fiber reinforced plastic (gear fiber) and glass fiber reinforced plastic (glass fiber) sliding against mild steel are investigated experimentally. In order to do so, a pin on disc apparatus is designed and fabricated. Experiments are carried out when smooth or rough mild steel pin slides on gear fiber and glass fiber disc. Experiments are conducted at normal load 10, 15 and 20 N, sliding velocity 1, 1.5 and 2 m/s and relative h...
Onel, L; Blitz, M A; Seakins, P W
2012-04-05
Monoethanol amine (H2NCH2CH2OH, MEA) has been proposed for large-scale use in carbon capture and storage. We present the first absolute, temperature-dependent determination of the rate coefficient for the reaction of OH with MEA using laser flash photolysis for OH generation, monitoring OH removal by laser-induced fluorescence. The room-temperature rate coefficient is determined to be (7.61 ± 0.76) × 10(-11) cm(3) molecule(-1) s(-1), and the rate coefficient decreases by about 40% by 510 K. The temperature dependence of the rate coefficient is given by k1= (7.73 ± 0.24) × 10(-11)(T/295)(-(0.79±0.11)) cm(3) molecule(-1) s(-1). The high rate coefficient shows that gas-phase processing in the atmosphere will be competitive with uptake onto aerosols.
Directory of Open Access Journals (Sweden)
Mahdi Alajmi
2015-07-01
Full Text Available The correlation between the mechanical properties of Fillers/Epoxy composites and their tribological behavior was investigated. Tensile, hardness, wear, and friction tests were conducted for Neat Epoxy (NE, Graphite/Epoxy composites (GE, and Data Palm Fiber/Epoxy with or without Graphite composites (GFE and FE. The correlation was made between the tensile strength, the modulus of elasticity, elongation at the break, and the hardness, as an individual or a combined factor, with the specific wear rate (SWR and coefficient of friction (COF of composites. In general, graphite as an additive to polymeric composite has had an eclectic effect on mechanical properties, whereas it has led to a positive effect on tribological properties, whilst date palm fibers (DPFs, as reinforcement for polymeric composite, promoted a mechanical performance with a slight improvement to the tribological performance. Statistically, this study reveals that there is no strong confirmation of any marked correlation between the mechanical and the specific wear rate of filler/Epoxy composites. There is, however, a remarkable correlation between the mechanical properties and the friction coefficient of filler/Epoxy composites.
Dateo, Christopher E.; Walch, Stephen P.
2002-01-01
As part of NASA Ames Research Center's Integrated Process Team on Device/Process Modeling and Nanotechnology our goal is to create/contribute to a gas-phase chemical database for use in modeling microelectronics devices. In particular, we use ab initio methods to determine chemical reaction pathways and to evaluate reaction rate coefficients. Our initial studies concern reactions involved in the dichlorosilane-hydrogen (SiCl2H2--H2) and trichlorosilane-hydrogen (SiCl2H-H2) systems. Reactant, saddle point (transition state), and product geometries and their vibrational harmonic frequencies are determined using the complete-active-space self-consistent-field (CASSCF) electronic structure method with the correlation consistent polarized valence double-zeta basis set (cc-pVDZ). Reaction pathways are constructed by following the imaginary frequency mode of the saddle point to both the reactant and product. Accurate energetics are determined using the singles and doubles coupled-cluster method that includes a perturbational estimate of the effects of connected triple excitations (CCSD(T)) extrapolated to the complete basis set limit. Using the data from the electronic structure calculations, reaction rate coefficients are obtained using conventional and variational transition state and RRKM theories.
Alajmi, Mahdi; Shalwan, Abdullah
2015-07-08
The correlation between the mechanical properties of Fillers/Epoxy composites and their tribological behavior was investigated. Tensile, hardness, wear, and friction tests were conducted for Neat Epoxy (NE), Graphite/Epoxy composites (GE), and Data Palm Fiber/Epoxy with or without Graphite composites (GFE and FE). The correlation was made between the tensile strength, the modulus of elasticity, elongation at the break, and the hardness, as an individual or a combined factor, with the specific wear rate (SWR) and coefficient of friction (COF) of composites. In general, graphite as an additive to polymeric composite has had an eclectic effect on mechanical properties, whereas it has led to a positive effect on tribological properties, whilst date palm fibers (DPFs), as reinforcement for polymeric composite, promoted a mechanical performance with a slight improvement to the tribological performance. Statistically, this study reveals that there is no strong confirmation of any marked correlation between the mechanical and the specific wear rate of filler/Epoxy composites. There is, however, a remarkable correlation between the mechanical properties and the friction coefficient of filler/Epoxy composites.
New rate coefficients of CS in collision with para- and ortho-H2 and astrophysical implications
Denis-Alpizar, Otoniel; Stoecklin, Thierry; Guilloteau, Stéphane; Dutrey, Anne
2018-05-01
Astronomers use the CS molecule as a gas mass tracer in dense regions of the interstellar medium, either to measure the gas density through multi-line observations or the level of turbulence. This necessarily requires the knowledge of the rates coefficients with the most common colliders in the interstellar medium, He and H2. In the present work, the close coupling collisional rates are computed for the first thirty rotational states of CS in collision with para- and ortho-H2 using a recent rigid rotor potential energy surface. Some radiative transfer calculations, using typical astrophysical conditions, are also performed to test this new set of data and to compare with the existing ones.
Directory of Open Access Journals (Sweden)
Ming Qin
Full Text Available FV520B steel is a kind of precipitation hardening Martensitic stainless steel, it has high-strength, good plasticity and good corrosion resistance. Stress corrosion cracking (SCC is one of the main corrosion failure mode for FV520B in industrial transportation of natural gas operation. For a better understanding the effect on SCC of FV520B, the improved wedge opening loading (WOL specimens and constant displacement loading methods were employed in experimental research in carbon dioxide and hydrogen sulfide solution. The test results showed that the crack propagation rate is 1.941 × 10−7–5.748 × 10−7 mm/s, the stress intensity factor KISCC is not more than 36.83 MPa m. The rate increases with the increasing of the crack opening displacement. Under the condition of different initial loading, KISCC generally shows a decreasing tendency with the increase in H2S concentration, and the crack propagation rate showed an increasing trend substantially. For the enrichment of sulfur ion in the crack tip induced the generation of pitting corrosion, promoting the surrounding metal formed the corrosion micro batteries, the pit defects gradually extended and connected with the adjacent pit to form a small crack, leading to further propagation till cracking happened. Fracture microscopic morphology displayed typical brittle fracture phenomena, accompanying with trans-granular cracking, river shape and sector, many second cracks on the fracture surface. Keywords: FV520B, Wedge opening loading specimen, Stress corrosion cracking, Hydrogen sulfide
Determination of the Rate Coefficients of the SO2 plus O plus M yields SO3 plus M Reaction
Hwang, S. M.; Cooke, J. A.; De Witt, K. J.; Rabinowitz, M. J.
2010-01-01
Rate coefficients of the title reaction R(sub 31) (SO2 +O+M yields SO3 +M) and R(sub 56) (SO2 + HO2 yields SO3 +OH), important in the conversion of S(IV) to S(VI),were obtained at T =970-1150 K and rho (sub ave) = 16.2 micro mol/cubic cm behind reflected shock waves by a perturbation method. Shock-heated H2/ O2/Ar mixtures were perturbed by adding small amounts of SO2 (1%, 2%, and 3%) and the OH temporal profiles were then measured using laser absorption spectroscopy. Reaction rate coefficients were elucidated by matching the characteristic reaction times acquired from the individual experimental absorption profiles via simultaneous optimization of k(sub 31) and k(sub 56) values in the reaction modeling (for satisfactory matches to the observed characteristic times, it was necessary to take into account R(sub 56)). In the experimental conditions of this study, R(sub 31) is in the low-pressure limit. The rate coefficient expressions fitted using the combined data of this study and the previous experimental results are k(sub 31,0)/[Ar] = 2.9 10(exp 35) T(exp ?6.0) exp(?4780 K/T ) + 6.1 10(exp 24) T(exp ?3.0) exp(?1980 K/T ) cm(sup 6) mol(exp ?2)/ s at T = 300-2500 K; k(sub 56) = 1.36 10(exp 11) exp(?3420 K/T ) cm(exp 3)/mol/s at T = 970-1150 K. Computer simulations of typical aircraft engine environments, using the reaction mechanism with the above k(sub 31,0) and k(sub 56) expressions, gave the maximum S(IV) to S(VI) conversion yield of ca. 3.5% and 2.5% for the constant density and constant pressure flow condition, respectively. Moreover, maximum conversions occur at rather higher temperatures (?1200 K) than that where the maximum k(sub 31,0) value is located (approximately 800 K). This is because the conversion yield is dependent upon not only the k(sup 31,0) and k(sup 56) values (production flux) but also the availability of H, O, and HO2 in the system (consumption flux).
Ballesteros, Bernabé; Ceacero-Vega, Antonio A; Jiménez, Elena; Albaladejo, José
2015-04-01
As the result of biogenic and anthropogenic activities, large quantities of chemical compounds are emitted into the troposphere. Alkanes, in general, and cycloalkanes are an important chemical class of hydrocarbons found in diesel, jet and gasoline, vehicle exhaust emissions, and ambient air in urban areas. In general, the primary atmospheric fate of organic compounds in the gas phase is the reaction with hydroxyl radicals (OH). The oxidation by Cl atoms has gained importance in the study of atmospheric reactions because they may exert some influence in the boundary layer, particularly in marine and coastal environments, and in the Arctic troposphere. The aim of this paper is to study of the atmospheric reactivity of methylcylohexanes with Cl atoms and OH radicals under atmospheric conditions (in air at room temperature and pressure). Relative kinetic techniques have been used to determine the rate coefficients for the reaction of Cl atoms and OH radicals with methylcyclohexane, cis-1,4-dimethylcyclohexane, trans-1,4-dimethylcyclohexane, and 1,3,5-trimethylcyclohexane at 298 ± 2 K and 720 ± 5 Torr of air by Fourier transform infrared) spectroscopy and gas chromatography-mass spectrometry (GC-MS) in two atmospheric simulation chambers. The products formed in the reaction under atmospheric conditions were investigated using a 200-L Teflon bag and employing the technique of solid-phase microextraction coupled to a GC-MS. The rate coefficients obtained for the reaction of Cl atoms with the studied compounds are the following ones (in units of 10(-10) cm(3) molecule(-1) s(-1)): (3.11 ± 0.16), (2.89 ± 0.16), (2.89 ± 0.26), and (2.61 ± 0.42), respectively. For the reactions with OH radicals the determined rate coefficients are (in units of 10(-11) cm(3) molecule(-1) s(-1)): (1.18 ± 0.12), (1.49 ± 0.16), (1.41 ± 0.15), and (1.77 ± 0.23), respectively. The reported error is twice the standard deviation. A detailed
Torr, D. G.; Torr, M. R.
1980-01-01
Atmosphere Explorer-C satellite measurements are used to determine rate coefficients (RCs) for the following reactions: O(+)(D-2) + N2 yields N2(+) + O (reaction 1), O(+)(D-2) + N2 yields O(+)(S-4) + N2 (reaction 2), and O(+)(D-2) + N2 yields NO(+) + N (reaction 3). Results show the RC for reaction 1 to be 1 (plus 1 or minus 0.5) x 10 to the -10th cu cm per sec, for reaction 2 to be 3 (plus 1 or minus 2) x 10 to the -11th cu cm per sec, and 3 to be less than 5.5 x 10 to the -11th cu cm per sec. It is also found that the reaction of O(+)(D-2) with N2 does not constitute a detectable source of NO(+) ions in the thermosphere.
Energy Technology Data Exchange (ETDEWEB)
Lagana, Antonio; Faginas Lago, Noelia; Rampino, Sergio [Dipartimento di Chimica, Universita di Perugia, 06123 Perugia (Italy); Huarte-Larranaga, FermIn [Computer Simulation and Modeling Lab (CoSMoLab), Parc CientIfic de Barcelona, 08028 Barcelona (Spain); GarcIa, Ernesto [Departamento de Quimica Fisica, Universidad del PaIs Vasco, 01006 Vitoria (Spain)], E-mail: lagana05@gmail.com, E-mail: fhuarte@pcb.ub.es, E-mail: e.garcia@ehu.es
2008-10-15
Zero total angular momentum exact quantum calculations of the probabilities of the N+N{sub 2} reaction have been performed on the L3 potential energy surface having a bent transition state. This has allowed us to work out J-shifting estimates of the thermal rate coefficient based on the calculation of either detailed (state-to-state) or cumulative (multiconfiguration) probabilities. The results obtained are used to compare the numerical outcomes and the concurrent computational machineries of both quantum and semiclassical approaches as well as to exploit the potentialities of the J-shifting model. The implications of moving the barrier to reaction from the previously proposed collinear geometry of the LEPS to the bent one of L3 are also investigated by comparing the related detailed reactive probabilities.
Jambrina, P. G.; Lara, Manuel; Menéndez, M.; Launay, J.-M.; Aoiz, F. J.
2012-10-01
Cumulative reaction probabilities (CRPs) at various total angular momenta have been calculated for the barrierless reaction S(1D) + H2 → SH + H at total energies up to 1.2 eV using three different theoretical approaches: time-independent quantum mechanics (QM), quasiclassical trajectories (QCT), and statistical quasiclassical trajectories (SQCT). The calculations have been carried out on the widely used potential energy surface (PES) by Ho et al. [J. Chem. Phys. 116, 4124 (2002), 10.1063/1.1431280] as well as on the recent PES developed by Song et al. [J. Phys. Chem. A 113, 9213 (2009), 10.1021/jp903790h]. The results show that the differences between these two PES are relatively minor and mostly related to the different topologies of the well. In addition, the agreement between the three theoretical methodologies is good, even for the highest total angular momenta and energies. In particular, the good accordance between the CRPs obtained with dynamical methods (QM and QCT) and the statistical model (SQCT) indicates that the reaction can be considered statistical in the whole range of energies in contrast with the findings for other prototypical barrierless reactions. In addition, total CRPs and rate coefficients in the range of 20-1000 K have been calculated using the QCT and SQCT methods and have been found somewhat smaller than the experimental total removal rates of S(1D).
International Nuclear Information System (INIS)
Andresen, Peter L.
1998-01-01
Five of the world's best laboratories at performing stress corrosion crack growth studies - ABB Atom AB, AEA Technology, GE Corporate Research and Development Center, Studsvik Material AB, and VTT Manufacturing Technology, were selected to participate in a round robin to evaluate the quality and reproducibility of testing conditions and resulting stress corrosion crack growth rates in sensitized type 304 stainless steel in 288 deg C water. Heat treated, machined and fatigue pre-cracked specimens were provided to all laboratories, and detailed test procedures prescribed the use of active loading, reversed dc potential drop crack monitoring, a common reference electrode supplied to all laboratories by GE CRD (to be used along side each laboratory's own reference electrode), and highly specified water chemistry conditions. The ability of each laboratory to achieve optimal testing conditions varied, although all laboratories achieved an impressive standard of testing control. The most significant laboratory-to-laboratory differences were associated with their ability to achieve high purity autoclave outlet water, reproduce accurate measurements of corrosion potential on the test specimen, and provide high resolution crack following using a reversed dc potential drop. However, the most notable outcome of the program is the consistent observation by all laboratories that initiating and sustaining stress corrosion crack growth at constant load in sensitized type 304 stainless steel is difficult, despite the use of a moderately high stress intensity, and high dissolved oxygen and corrosion potential conditions. Concerns for specimen machining and pre-cracking were identified, although these factors were not the sole cause of difficulty in initiating and sustaining stress corrosion cracking. It was shown that many phases of specimen preparation and testing can have a large influence on the measured SCC response. Even under the best test conditions it is critical to ensure
Energy Technology Data Exchange (ETDEWEB)
Andresen, Peter L. [GE Corporate Research and Development, Schenectady, NY (United States)
1998-12-31
Five of the world`s best laboratories at performing stress corrosion crack growth studies - ABB Atom AB, AEA Technology, GE Corporate Research and Development Center, Studsvik Material AB, and VTT Manufacturing Technology, were selected to participate in a round robin to evaluate the quality and reproducibility of testing conditions and resulting stress corrosion crack growth rates in sensitized type 304 stainless steel in 288 deg C water. Heat treated, machined and fatigue pre-cracked specimens were provided to all laboratories, and detailed test procedures prescribed the use of active loading, reversed dc potential drop crack monitoring, a common reference electrode supplied to all laboratories by GE CRD (to be used along side each laboratory`s own reference electrode), and highly specified water chemistry conditions. The ability of each laboratory to achieve optimal testing conditions varied, although all laboratories achieved an impressive standard of testing control. The most significant laboratory-to-laboratory differences were associated with their ability to achieve high purity autoclave outlet water, reproduce accurate measurements of corrosion potential on the test specimen, and provide high resolution crack following using a reversed dc potential drop. However, the most notable outcome of the program is the consistent observation by all laboratories that initiating and sustaining stress corrosion crack growth at constant load in sensitized type 304 stainless steel is difficult, despite the use of a moderately high stress intensity, and high dissolved oxygen and corrosion potential conditions. Concerns for specimen machining and pre-cracking were identified, although these factors were not the sole cause of difficulty in initiating and sustaining stress corrosion cracking. It was shown that many phases of specimen preparation and testing can have a large influence on the measured SCC response. Even under the best test conditions it is critical to ensure
Zirak, H.; Jafari, S.
2015-06-01
In this study, a theory of free-electron laser (FEL) with a Langmuir wave wiggler in the presence of an axial magnetic field has been presented. The small wavelength of the plasma wave (in the sub-mm range) allows obtaining higher frequency than conventional wiggler FELs. Electron trajectories have been obtained by solving the equations of motion for a single electron. In addition, a fourth-order Runge-Kutta method has been used to simulate the electron trajectories. Employing a perturbation analysis, the dispersion relation for an electromagnetic and space-charge waves has been derived by solving the momentum transfer, continuity, and wave equations. Numerical calculations show that the growth rate increases with increasing the e-beam energy and e-beam density, while it decreases with increasing the strength of the axial guide magnetic field.
Rate coefficients for collisional population transfer between 3p54p argon levels at 300 0K
International Nuclear Information System (INIS)
Nguyen, T.D.; Sadeghi, N.
1978-01-01
The population transfer between excited 3p 5 4p argon levels induced by the collisional process Ar* (3p 5 4p)/sub i/ + Ar( 1 S 0 ) arrow-right-left Ar* (3p 5 4p)/sub j/ + Ar( 1 S 0 ) + ΔE was studied in the afterglow of an argon pulsed discharge, at the pressure range of 0.2--1 Torr. Selective population of one particular argon 3p 5 4p level was achieved by laser excitation from one metastable state by use of a tunable cw dye laser. The populations of the laser-excited level and of the collisional excited levels were determined by intensity measurements of the fluorescence line and of the sensitized fluorescence lines. The time-dependence study of the populations of the metastable state, of the laser-excited state, and of the collisional excited states was carried out to ascertain the product channel and to determine the collisional transfer rate coefficients
A paradox: The thermal rate coefficient for the H+DCl → HCl+D exchange reaction
International Nuclear Information System (INIS)
Thompson, D.L.; Suzukawa, H.H. Jr.; Raff, L.M.
1975-01-01
Previously reported photolysis experiments indicate that the frequency factors associated with the hydrogen-exchange reactions H+DCl → HCl+D and D+HCl → DCl+H are on the order of 10 10 cm 3 /molcenter-dotsec. A series of unadjusted, quasiclassical trajectory calculations were been carried out to compute the thermal rate coefficients and activation parameters for a series of 13 thermal processes of the type A+BC → AB+C, where A=H, D, or Cl and BC=H 2 , D 2 , HCl, DCl, or Cl 2 . In addition, hot-atom yield ratios have been computed from the IRP equation for the reactions D*+DCl → D 2 +Cl, D*+Cl 2 → DCl + Cl as a function of the initial D* laboratory energy. The computations yield (1) hot-atom DCl/D 2 yield ratios within a factor of 2 of the experimental values; (2) thermal activation energies in satisfactory agreement with experiment for all processes investigated; and (3) frequency factors in reasonable accord with experiment for all the reactions except the hydrogen exchange reactions
Feofilov, A. G.; Kutepov, A. A.; She, C. Y.; Smith, A. K.; Pesnell, W. D.; Goldberg, R. A.
2009-01-01
Among the processes governing the energy balance in the mesosphere and lower thermosphere (MLT), the quenching of CO2(V2) vibrational levels in collisions with oxygen atoms plays an important role. However, neither the rate coefficient of this process (k(CO2O)) nor the atomic oxygen concentrations ([O]) in the MLT are well known. The discrepancy between k(CO2O) measured in the lab and retrieved from atmospheric measurements is of about factor of 2.5. At the same time, the discrepancy between [O] in the MLT measured by different instruments is of the same order of magnitude. In this work we used a synergy of a ground based lidar and satellite infrared radiometer to make a further step in understanding of the physics of the region. In this study we apply the night- and daytime temperatures between 80 and 110 km measured by the Colorado State University narrow-band sodium (Na) lidar located at Fort Collins, Colorado for retrieving the product of k(CO2-O) x [O] from the limb radiances in the 15 micron channel measured by the SABER/TIMED instrument for nearly simultaneous common volume measurements of both instruments within +/-1 degree in latitude, +/-2 degrees in longitude and +/-10 minutes in time. We derive k(CO2-O) and its possible variation range from the retrieved product by utilizing the [O] values measured by the SABER and other instruments.
DeMarse, Thomas B; Pan, Liangbin; Alagapan, Sankaraleengam; Brewer, Gregory J; Wheeler, Bruce C
2016-01-01
Transient propagation of information across neuronal assembles is thought to underlie many cognitive processes. However, the nature of the neural code that is embedded within these transmissions remains uncertain. Much of our understanding of how information is transmitted among these assemblies has been derived from computational models. While these models have been instrumental in understanding these processes they often make simplifying assumptions about the biophysical properties of neurons that may influence the nature and properties expressed. To address this issue we created an in vitro analog of a feed-forward network composed of two small populations (also referred to as assemblies or layers) of living dissociated rat cortical neurons. The populations were separated by, and communicated through, a microelectromechanical systems (MEMS) device containing a strip of microscale tunnels. Delayed culturing of one population in the first layer followed by the second a few days later induced the unidirectional growth of axons through the microtunnels resulting in a primarily feed-forward communication between these two small neural populations. In this study we systematically manipulated the number of tunnels that connected each layer and hence, the number of axons providing communication between those populations. We then assess the effect of reducing the number of tunnels has upon the properties of between-layer communication capacity and fidelity of neural transmission among spike trains transmitted across and within layers. We show evidence based on Victor-Purpura's and van Rossum's spike train similarity metrics supporting the presence of both rate and temporal information embedded within these transmissions whose fidelity increased during communication both between and within layers when the number of tunnels are increased. We also provide evidence reinforcing the role of synchronized activity upon transmission fidelity during the spontaneous synchronized
Oki, Kensuke; Ma, Bei; Ishitani, Yoshihiro
2017-11-01
Population distributions and transition fluxes of the A exciton in bulk GaN are theoretically analyzed using rate equations of states of the principal quantum number n up to 5 and the continuum. These rate equations consist of the terms of radiative, electron-collisional, and phononic processes. The dependence of the rate coefficients on temperature is revealed on the basis of the collisional-radiative model of hydrogen plasma for the electron-collisional processes and theoretical formulation using Fermi's "golden rule" for the phononic processes. The respective effects of the variations in electron, exciton, and lattice temperatures are exhibited. This analysis is a base of the discussion on nonthermal equilibrium states of carrier-exciton-phonon dynamics. It is found that the exciton dissociation is enhanced even below 150 K mainly by the increase in the lattice temperature. When the thermal-equilibrium temperature increases, the population fluxes between the states of n >1 and the continuum become more dominant. Below 20 K, the severe deviation from the Saha-Boltzmann distribution occurs owing to the interband excitation flux being higher than the excitation flux from the 1 S state. The population decay time of the 1 S state at 300 K is more than ten times longer than the recombination lifetime of excitons with kinetic energy but without the upper levels (n >1 and the continuum). This phenomenon is caused by a shift of population distribution to the upper levels. This phonon-exciton-radiation model gives insights into the limitations of conventional analyses such as the ABC model, the Arrhenius plot, the two-level model (n =1 and the continuum), and the neglect of the upper levels.
International Nuclear Information System (INIS)
Toyoshima, S.; Noguchi, K.; Seto, H.; Shimizu, M.; Watanabe, N.
2000-01-01
To determine the relationship between apparent diffusion coefficient (ADC) values measured by diffusion-weighted MR imaging and split renal function determined by renal scintigraphy in patients with hydronephrosis. Material and Methods: Diffusion-weighted imaging on a 1.5 T MR unit and renal scintigraphy were performed in 36 patients with hydronephrosis (45 hydronephrotic kidneys, 21 non-hydronephrotic kidneys). ADC values of the individual kidneys were measured by diffusion-weighted MR imaging. Split renal function (glomerular filtration rate (GFR)) was determined by renal scintigraphy using 99m Tc-DTPA. The relationship between ADC values and split GFR was examined in 66 kidneys. The hydronephrotic kidneys were further classified into three groups (severe renal dysfunction, GFR 25 ml/min, n=28), and mean values for ADCs were calculated. Results: In hydronephrotic kidneys, there was a moderate positive correlation between ADC values and split GFR (R2=0.56). On the other hand, in non-hydronephrotic kidneys, poor correlation between ADC values and split GFR was observed (R2=0.08). The mean values for ADCs of the dysfunctioning hydronephrotic kidneys (severe renal dysfunction, 1.32x10 -3 ±0.18x10 -3 mm 2 /s; moderate renal dysfunction, 1.38x10 -3 ±0.10x10 -3 mm2/s) were significantly lower than that of the normal functioning hydronephrotic kidneys (1.63x10 -3 ±0.12±10 -3 mm 2 /s). Conclusion: These results indicated that measurement of ADC values by diffusion-weighted MR imaging has a potential value in the evaluation of the functional status of hydronephrotic kidneys
Directory of Open Access Journals (Sweden)
Mohammad Delnavaz
2017-06-01
Conclusion: Evaluation of Y, kd, k0 and Ks parameters in operation of Ekbatan wastewater treatment plant showed that ASM1 model could well determine the coefficients and therefore the conditions of biological treatment is appropriate.
Shaw, Jacob T.; Lidster, Richard T.; Cryer, Danny R.; Ramirez, Noelia; Whiting, Fiona C.; Boustead, Graham A.; Whalley, Lisa K.; Ingham, Trevor; Rickard, Andrew R.; Dunmore, Rachel E.; Heard, Dwayne E.; Lewis, Ally C.; Carpenter, Lucy J.; Hamilton, Jacqui F.; Dillon, Terry J.
2018-03-01
Gas-phase rate coefficients are fundamental to understanding atmospheric chemistry, yet experimental data are not available for the oxidation reactions of many of the thousands of volatile organic compounds (VOCs) observed in the troposphere. Here, a new experimental method is reported for the simultaneous study of reactions between multiple different VOCs and OH, the most important daytime atmospheric radical oxidant. This technique is based upon established relative rate concepts but has the advantage of a much higher throughput of target VOCs. By evaluating multiple VOCs in each experiment, and through measurement of the depletion in each VOC after reaction with OH, the OH + VOC reaction rate coefficients can be derived. Results from experiments conducted under controlled laboratory conditions were in good agreement with the available literature for the reaction of 19 VOCs, prepared in synthetic gas mixtures, with OH. This approach was used to determine a rate coefficient for the reaction of OH with 2,3-dimethylpent-1-ene for the first time; k = 5.7 (±0.3) × 10-11 cm3 molecule-1 s-1. In addition, a further seven VOCs had only two, or fewer, individual OH rate coefficient measurements available in the literature. The results from this work were in good agreement with those measurements. A similar dataset, at an elevated temperature of 323 (±10) K, was used to determine new OH rate coefficients for 12 aromatic, 5 alkane, 5 alkene and 3 monoterpene VOC + OH reactions. In OH relative reactivity experiments that used ambient air at the University of York, a large number of different VOCs were observed, of which 23 were positively identified. Due to difficulties with detection limits and fully resolving peaks, only 19 OH rate coefficients were derived from these ambient air samples, including 10 reactions for which data were previously unavailable at the elevated reaction temperature of T = 323 (±10) K.
Friction and drag forces on spheres propagating down inclined planes
Tee, Yi Hui; Longmire, Ellen
2017-11-01
When a submerged sphere propagates along an inclined wall at terminal velocity, it experiences gravity, drag, lift, and friction forces. In the related equations of motion, the drag, lift and friction coefficients are unknown. Experiments are conducted to determine the friction and drag coefficients of the sphere over a range of Reynolds numbers. Through high speed imaging, translational and rotational velocities of spheres propagating along a glass plate are determined in liquids with several viscosities. The onset of sliding motion is identified by computing the dimensionless rotation rate of the sphere. Using drag and lift coefficients for Re friction coefficients are calculated for several materials. The friction coefficients are then employed to estimate the drag coefficient for 350 frictional force over this Re range. Supported by NSF (CBET-1510154).
Torr, D. G.; Orsini, N.
1978-01-01
The Atmosphere Explorer (AE) data are reexamined in the light of new laboratory measurements of the N2(+) recombination rate coefficient alpha. The new measurements support earlier measurements which yielded values of alpha significantly lower than the AE values. It is found that the values for alpha determined from the satellite data can be reconciled with the laboratory measurements, if the charge exchange rate coefficient for O(+)(2D) with N2 is less than one-quarter of that derived in the laboratory by Rutherford and Vroom (1971).
Li, Jun; Guo, Hua
2018-03-15
Thermal rate coefficients for the title reaction and its various isotopologues are computed using a tunneling-corrected transition-state theory on a global potential energy surface recently developed by fitting a large number of high-level ab initio points. The calculated rate coefficients are found to agree well with the measured ones in a wide temperature range, validating the accuracy of the potential energy surface. Strong non-Arrhenius effects are found at low temperatures. In addition, the calculations reproduced the primary and secondary kinetic isotope effects. These results confirm the strong influence of tunneling to this heavy-light-heavy hydrogen abstraction reaction.
International Nuclear Information System (INIS)
Carter, J.G.; Hunter, S.R.; Christophorou, L.G.
1987-01-01
Measurements of the electron drift velocity, w, attachment coefficient, eta/N/sub a/, and ionization coefficient, α/N, have been made in C 2 F 6 /Ar and C 2 F 6 /CH 4 gas mixtures at gas temperatures, T, of 300 and 500 0 K over the concentration range of 0.1 to 100% of the C 2 F 6 . These measurements are useful for modeling the expected behavior of repetitively operated electron-beam sustained diffuse gas discharge opening switches where gas temperatures within the switch are anticipated to rise several hundred degrees during switch operation
Bon, S.A.F.; Chambard, G.; German, A.L.
1999-01-01
The rate coefficient for alkoxyamine C-O bond homolysis has been determined over a range of temperatures for both 2-tert-butoxy-1-phenyl-1-(1-oxy-2,2,6,6-tetramethylpiperidinyl)ethane (1) and a polystyrene-TEMPO (approximately 75 units) adduct using quantitative ESR. In a thermostated solution of
Ng, Maggie; Mok, Daniel K W; Lee, Edmond P F; Dyke, John M
2017-09-07
A theoretical study, involving the calculation of reaction enthalpies, activation energies, mechanisms, and rate coefficients, was made of the reaction of hydroxyl radicals with methyl nitrate, an important process for methyl nitrate removal in the earth's atmosphere. Four reaction channels were considered: formation of H 2 O + CH 2 ONO 2 , CH 3 OOH + NO 2 , CH 3 OH + NO 3 , and CH 3 O + HNO 3 . For all channels, geometry optimization and frequency calculations were performed at the M06-2X/6-31+G** level, while relative energies were improved at the UCCSD(T*)-F12/CBS level. The major channel is found to be the H abstraction channel, to give the products H 2 O + CH 2 ONO 2 . The reaction enthalpy (ΔH 298 K RX ) of this channel is computed as -17.90 kcal mol -1 . Although the other reaction channels are also exothermic, their reaction barriers are high (>24 kcal mol -1 ), and therefore these reactions do not contribute to the overall rate coefficient in the temperature range considered (200-400 K). Pathways via three transition states were identified for the H abstraction channel. Rate coefficients were calculated for these pathways at various levels of variational transition state theory including tunneling. The results obtained are used to distinguish between two sets of experimental rate coefficients, measured in the temperature range of 200-400 K, one of which is approximately an order of magnitude greater than the other. This comparison, as well as the temperature dependence of the computed rate coefficients, shows that the lower experimental values are favored. The implications of the results to atmospheric chemistry are discussed.
Werfelli, Ghofran; Halvick, Philippe; Honvault, Pascal; Kerkeni, Boutheïna; Stoecklin, Thierry
2015-09-21
The observed abundances of the methylidyne cation, CH(+), in diffuse molecular clouds can be two orders of magnitude higher than the prediction of the standard gas-phase models which, in turn, predict rather well the abundances of neutral CH. It is therefore necessary to investigate all the possible formation and destruction processes of CH(+) in the interstellar medium with the most abundant species H, H2, and e(-). In this work, we address the destruction process of CH(+) by hydrogen abstraction. We report a new calculation of the low temperature rate coefficients for the abstraction reaction, using accurate time-independent quantum scattering and a new high-level ab initio global potential energy surface including a realistic model of the long-range interaction between the reactants H and CH(+). The calculated thermal rate coefficient is in good agreement with the experimental data in the range 50 K-800 K. However, at lower temperatures, the experimental rate coefficient takes exceedingly small values which are not reproduced by the calculated rate coefficient. Instead, the latter rate coefficient is close to the one given by the Langevin capture model, as expected for a reaction involving an ion and a neutral species. Several recent theoretical works have reported a seemingly good agreement with the experiment below 50 K, but an analysis of these works show that they are based on potential energy surfaces with incorrect long-range behavior. The experimental results were explained by a loss of reactivity of the lowest rotational states of the reactant; however, the quantum scattering calculations show the opposite, namely, a reactivity enhancement with rotational excitation.
Batterson, Sidney A.
1959-01-01
An experimental investigation was made at the Langley landing loads track to obtain data on the maximum spin-up coefficients of friction developed by a landing gear having a static-load rating of 20,000 pounds. The forward speeds ranged from 0 to approximately 180 feet per second and the sinking speeds, from 2.7 feet per second to 9.4 feet per second. The results indicated the variation of the maximum spin-up coefficient of friction with forward speed and vertical load. Data obtained during this investigation are also compared with some results previously obtained for nonrolling tires to show the effect of forward speed.
Liu, Zhijian; Li, Hao; Tang, Xindong; Zhang, Xinyu; Lin, Fan; Cheng, Kewei
2016-01-01
Heat collection rate and heat loss coefficient are crucial indicators for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, the direct determination requires complex detection devices and a series of standard experiments, wasting too much time and manpower. To address this problem, we previously used artificial neural networks and support vector machine to develop precise knowledge-based models for predicting the heat collection rates and heat loss coefficients of water-in-glass evacuated tube solar water heaters, setting the properties measured by "portable test instruments" as the independent variables. A robust software for determination was also developed. However, in previous results, the prediction accuracy of heat loss coefficients can still be improved compared to those of heat collection rates. Also, in practical applications, even a small reduction in root mean square errors (RMSEs) can sometimes significantly improve the evaluation and business processes. As a further study, in this short report, we show that using a novel and fast machine learning algorithm-extreme learning machine can generate better predicted results for heat loss coefficient, which reduces the average RMSEs to 0.67 in testing.
Directory of Open Access Journals (Sweden)
J. T. Shaw
2018-03-01
Full Text Available Gas-phase rate coefficients are fundamental to understanding atmospheric chemistry, yet experimental data are not available for the oxidation reactions of many of the thousands of volatile organic compounds (VOCs observed in the troposphere. Here, a new experimental method is reported for the simultaneous study of reactions between multiple different VOCs and OH, the most important daytime atmospheric radical oxidant. This technique is based upon established relative rate concepts but has the advantage of a much higher throughput of target VOCs. By evaluating multiple VOCs in each experiment, and through measurement of the depletion in each VOC after reaction with OH, the OH + VOC reaction rate coefficients can be derived. Results from experiments conducted under controlled laboratory conditions were in good agreement with the available literature for the reaction of 19 VOCs, prepared in synthetic gas mixtures, with OH. This approach was used to determine a rate coefficient for the reaction of OH with 2,3-dimethylpent-1-ene for the first time; k = 5.7 (±0.3 × 10−11 cm3 molecule−1 s−1. In addition, a further seven VOCs had only two, or fewer, individual OH rate coefficient measurements available in the literature. The results from this work were in good agreement with those measurements. A similar dataset, at an elevated temperature of 323 (±10 K, was used to determine new OH rate coefficients for 12 aromatic, 5 alkane, 5 alkene and 3 monoterpene VOC + OH reactions. In OH relative reactivity experiments that used ambient air at the University of York, a large number of different VOCs were observed, of which 23 were positively identified. Due to difficulties with detection limits and fully resolving peaks, only 19 OH rate coefficients were derived from these ambient air samples, including 10 reactions for which data were previously unavailable at the elevated reaction temperature of T = 323 (±10 K.
International Nuclear Information System (INIS)
Pedersen, Torje V.; Olsen, Dag R.; Skretting, Arne
1997-01-01
A method has been developed to determine the diffusion coefficients of ferric ions in ferrous sulphate doped gels. A radiation induced edge was created in the gel, and two spin-echo sequences were used to acquire a pair of images of the gel at different points of time. For each of these image pairs, a longitudinal relaxation rate image was derived. From profiles through these images, the standard deviations of the Gaussian functions that characterize diffusion were determined. These data provided the basis for the determination of the ferric diffusion coefficients by two different methods. Simulations indicate that the use of single spin-echo images in this procedure may in some cases lead to a significant underestimation of the diffusion coefficient. The technique was applied to different agarose and gelatine gels that were prepared, irradiated and imaged simultaneously. The results indicate that the diffusion coefficient is lower in a gelatine gel than in an agarose gel. Addition of xylenol orange to a gelatine gel lowers the diffusion coefficient from 1.45 to 0.81 mm 2 h -1 , at the cost of significantly lower R 1 sensitivity. The addition of benzoic acid to the latter gel did not increase the R 1 sensitivity. (author) OK
International Nuclear Information System (INIS)
Tone, Tatsuzo
1978-07-01
Described are the reactivity coefficient of D-T fusion reaction, slowing-down processes of deuterons injected with high energy and 3.52 MeV alpha particles generated in D-T reaction, and the power balance in a Tokamak reactor plasma. Most of the results were obtained in the first preliminary design of JAERI Experimental Fusion Reactor (JXFR) driven with stationary neutral beam injection. A manual of numerical computation program ''BALTOK'' developed for the calculations is given in the appendix. (auth.)
Srinivasulu, G; Bunkan, A J C; Amedro, D; Crowley, J N
2018-01-31
The rate coefficient (k 1 ) for the reaction of OH radicals with perfluoro ethyl vinyl ether (PEVE, C 2 F 5 OCF[double bond, length as m-dash]CF 2 ) has been measured as a function of temperature (T = 207-300 K) using the technique of pulsed laser photolysis with detection of OH by laser-induced fluorescence (PLP-LIF) at pressures of 50 or 100 Torr N 2 bath gas. In addition, the rate coefficient was measured at 298 K and in one atmosphere of air by the relative-rate technique with loss of PEVE and reference reactant monitored in situ by IR absorption spectroscopy. The rate coefficient has a negative temperature dependence which can be parameterized as: k 1 (T) = 6.0 × 10 -13 exp[(480 ± 38/T)] cm 3 molecule -1 s -1 and a room temperature value of k 1 (298 K) = (3.0 ± 0.3) × 10 -12 cm 3 molecule -1 s -1 . Highly accurate rate coefficients from the PLP-LIF experiments were achieved by optical on-line measurements of PEVE and by performing the measurements at two different apparatuses. The large rate coefficient and the temperature dependence indicate that the reaction proceeds via OH addition to the C[double bond, length as m-dash]C double bond, the high pressure limit already being reached at 50 Torr N 2 . Based on the rate coefficient and average OH levels, the atmospheric lifetime of PEVE was estimated to be a few days.
Tajima, Satomi; Hayashi, Toshio; Hori, Masaru
2015-02-26
The rate coefficient of F2 + NO → F + FNO is 2 to 5 orders of magnitude higher than that of F2 + NO2 → F + FNO2 even though bond energies of FNO and FNO2 only differ by ∼0.2 eV. To understand the cause of having different rate coefficients of these two reactions, the change in total energies was calculated by varying the stereochemical arrangement of F2 with respect to NOx (x = 1 or 2) by the density functional theory (DFT), using CAM-B3LYP/6-311 G+(d) in the Gaussian program. The permitted approaching angle between the x-axis and the plane consisting of O, N, F, and ϕ plays a key role to restrict the reaction of NO2 and F2 compared to the reaction of NO and F2. This restriction in the reaction space is considered to be the main cause of different rate coefficients depending on the selection of x = 1 or 2 of the reaction of F2 + NOx → F + FNOx, which was also confirmed by the difference in Si etch rate using the F formed by those reactions.
Energy Technology Data Exchange (ETDEWEB)
Mihajlov, A A [Institute of Physics, PO Box 57, 11001 Belgrade (Serbia and Montenegro); Ignjatovic, Lj M [Institute of Physics, PO Box 57, 11001 Belgrade (Serbia and Montenegro); Djuric, Z [Silvaco Data Systems, Compass Point, St Ives PE27 5JL (United Kingdom); Ljepojevic, N N [Silvaco Data Systems, Compass Point, St Ives PE27 5JL (United Kingdom)
2004-11-28
This paper presents the results of semi-classical calculations of rate coefficients of (n - n')-mixing processes in collisions of Rydberg atoms H*(n) with H(1s) atoms. These processes have been modelled by the mechanism of the resonant energy exchange within the electron component of the H*(n) + H collisional system. The calculations of the rate coefficients, based on this model, were performed for the series of principal quantum numbers, n and n', and atomic, T{sub a}, and electronic, T{sub e}, temperatures. It was shown that these processes can be of significant influence on the populations of Rydberg atoms in weakly ionized plasmas (ionization degree {approx}<10{sup -4}), and therefore have to be included in appropriate models of such plasmas.
International Nuclear Information System (INIS)
Mihajlov, A A; Ignjatovic, Lj M; Djuric, Z; Ljepojevic, N N
2004-01-01
This paper presents the results of semi-classical calculations of rate coefficients of (n - n')-mixing processes in collisions of Rydberg atoms H*(n) with H(1s) atoms. These processes have been modelled by the mechanism of the resonant energy exchange within the electron component of the H*(n) + H collisional system. The calculations of the rate coefficients, based on this model, were performed for the series of principal quantum numbers, n and n', and atomic, T a , and electronic, T e , temperatures. It was shown that these processes can be of significant influence on the populations of Rydberg atoms in weakly ionized plasmas (ionization degree ∼ -4 ), and therefore have to be included in appropriate models of such plasmas
Duong, Minh V; Nguyen, Hieu T; Mai, Tam V-T; Huynh, Lam K
2018-01-03
Master equation/Rice-Ramsperger-Kassel-Marcus (ME/RRKM) has shown to be a powerful framework for modeling kinetic and dynamic behaviors of a complex gas-phase chemical system on a complicated multiple-species and multiple-channel potential energy surface (PES) for a wide range of temperatures and pressures. Derived from the ME time-resolved species profiles, the macroscopic or phenomenological rate coefficients are essential for many reaction engineering applications including those in combustion and atmospheric chemistry. Therefore, in this study, a least-squares-based approach named Global Minimum Profile Error (GMPE) was proposed and implemented in the MultiSpecies-MultiChannel (MSMC) code (Int. J. Chem. Kinet., 2015, 47, 564) to extract macroscopic rate coefficients for such a complicated system. The capability and limitations of the new approach were discussed in several well-defined test cases.
Pawlak, Mariusz; Ben-Asher, Anael; Moiseyev, Nimrod
2018-01-09
We present a simple expression and its derivation for reaction rate coefficients for cold anisotropic collision experiments based on adiabatic variational theory and time-independent non-Hermitian scattering theory. We demonstrate that only the eigenenergies of the resulting one-dimensional Schrödinger equation for different complex adiabats are required. The expression is applied to calculate the Penning ionization rate coefficients of an excited metastable helium atom with molecular hydrogen in an energy range spanning from hundreds of kelvins down to the millikelvin regime. Except for trivial quantities like the masses of the nuclei and the bond length of the diatomic molecule participating in the collision, one needs as input data only the complex potential energy surface (CPES). In calculations, we used recently obtained ab initio CPES by D. Bhattacharya et al. ( J. Chem. Theory Comput. 2017 , 13 , 1682 - 1690 ) without fitting parameters. The results show good accord with current measurements ( Nat. Phys. 2017 , 13 , 35 - 38 ).
Smallman-Raynor, M R; Cliff, A D
2014-03-01
The abrupt transition to heightened poliomyelitis epidemicity in England and Wales, 1947-1957, was associated with a profound change in the spatial dynamics of the disease. Drawing on the complete record of poliomyelitis notifications in England and Wales, we use a robust method of spatial epidemiological analysis (swash-backwash model) to evaluate the geographical rate of disease propagation in successive poliomyelitis seasons, 1940-1964. Comparisons with earlier and later time periods show that the period of heightened poliomyelitis epidemicity corresponded with a sudden and pronounced increase in the spatial rate of disease propagation. This change was observed for both urban and rural areas and points to an abrupt enhancement in the propensity for the geographical spread of polioviruses. Competing theories of the epidemic emergence of poliomyelitis in England and Wales should be assessed in the light of this evidence.
Avery, L. W.; Green, Sheldon
1989-01-01
Collisional excitation rates for C3H2, calculated using the coupled states approximation at temperatures of 10-30 K, are presented. C3H2 produces a number of spectral line pairs whose members are close together in frequency but arise from levels with different excitation energies. The rates are used in statistical equilibrium calculations to illustrate the excitation properties and density-dependent behavior of various C3H2 line ratios.
Oakley, David O. S.; Fisher, Donald M.; Gardner, Thomas W.; Stewart, Mary Kate
2018-01-01
Marine terraces on growing fault-propagation folds provide valuable insight into the relationship between fold kinematics and uplift rates, providing a means to distinguish among otherwise non-unique kinematic model solutions. Here, we investigate this relationship at two locations in North Canterbury, New Zealand: the Kate anticline and Haumuri Bluff, at the northern end of the Hawkswood anticline. At both locations, we calculate uplift rates of previously dated marine terraces, using DGPS surveys to estimate terrace inner edge elevations. We then use Markov chain Monte Carlo methods to fit fault-propagation fold kinematic models to structural geologic data, and we incorporate marine terrace uplift into the models as an additional constraint. At Haumuri Bluff, we find that marine terraces, when restored to originally horizontal surfaces, can help to eliminate certain trishear models that would fit the geologic data alone. At Kate anticline, we compare uplift rates at different structural positions and find that the spatial pattern of uplift rates is more consistent with trishear than with a parallel-fault propagation fold kink-band model. Finally, we use our model results to compute new estimates for fault slip rates ( 1-2 m/ka at Kate anticline and 1-4 m/ka at Haumuri Bluff) and ages of the folds ( 1 Ma), which are consistent with previous estimates for the onset of folding in this region. These results are consistent with previous work on the age of onset of folding in this region, provide revised estimates of fault slip rates necessary to understand the seismic hazard posed by these faults, and demonstrate the value of incorporating marine terraces in inverse fold kinematic models as a means to distinguish among non-unique solutions.
Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J
2012-01-01
In oocyte vitrification, plunging directly into liquid nitrogen favor film boiling and strong nitrogen vaporization. A survey of literature values of heat transfer coefficients (h) for film boiling of small metal objects with different geometries plunged in liquid nitrogen revealed values between 125 to 1000 W per per square m per K. These h values were used in a numerical simulation of cooling rates of two oocyte vitrification devices (open-pulled straw and Cryotop), plunged in liquid and slush nitrogen conditions. Heat conduction equation with convective boundary condition was considered a linear mathematical problem and was solved using the finite element method applying the variational formulation. COMSOL Multiphysics was used to simulate the cooling process of the systems. Predicted cooling rates for OPS and Cryotop when cooled at -196 degree C (liquid nitrogen) or -207 degree C (average for slush nitrogen) for heat transfer coefficients estimated to be representative of film boiling, indicated lowering the cooling temperature produces only a maximum 10 percent increase in cooling rates; confirming the main benefit of plunging in slush over liquid nitrogen does not arise from their temperature difference. Numerical simulations also demonstrated that a hypothetical four-fold increase in the cooling rate of vitrification devices when plunging in slush nitrogen would be explained by an increase in heat transfer coefficient. This improvement in heat transfer (i.e., high cooling rates) in slush nitrogen is attributed to less or null film boiling when a sample is placed in slush (mixture of liquid and solid nitrogen) because it first melts the solid nitrogen before causing the liquid to boil and form a film.
International Nuclear Information System (INIS)
Bokhan, P. A.; Gugin, P. P.; Lavrukhin, M. A.; Zakrevsky, Dm. E.
2015-01-01
The switching rate of gas-discharge devices “kivotrons” based on the open discharge with counter-propagating electron beams has been experimentally studied. Structures with 2-cm 2 overall cathode area were examined. The switching time was found to show a monotonic decrease with increasing the working-gas helium pressure and with increasing the voltage across the discharge gap at breakdown. The minimum switching time was found to be ∼240 ps at 17 kV voltage, and the maximum rate of electric-current rise limited by the discharge-circuit inductance was 3 × 10 12 A/s
International Nuclear Information System (INIS)
Totsuka, Nobuo; Fukumura, Takuya
2010-01-01
There will be some concern about the content presented in the paper entitled 'Primary Coolant Leakage Path Research of Reactor Vessel Head Penetration' published in INSS JOURNAL of 2008, which may lead to misunderstanding about the PWSCC crack propagation rate, that is, the rate written in the paper seems to be faster than those reported by the previous studies. It is considered that such misunderstanding will be due to a sentence in the abstract of the paper. Therefore, we will revise a part of the abstract and explain about the outline of the paper again. (author)
Bystrov, N. S.; Emelianov, A. V.; Eremin, A. V.; Yatsenko, P. I.
2018-05-01
The kinetics of the dissociation of CF3I behind shock waves was experimentally investigated. The reaction CF3I + Ar → CF3 + I + Ar was studied at temperatures between 900 and 1250 K and pressures of 2–3 bar. For this purpose, the time profiles of the concentration of atomic iodine were measured using a highly sensitive atomic resonance absorption spectroscopy method at a wavelength of 183.04 nm. From these data, the experimental value of the dissociation rate constant of CF3I was obtained: . We found that the investigated range of pressures and temperatures for the CF3I dissociation lies in the pressure transition region. Based on the Rice-Ramsperger–Kassel–Marcus theory, the threshold high and low-pressure rate constants ( and k 0) and falloff curves are calculated for the temperatures of 950–1200 K. As a result of this calculation, the threshold rate constants could be evaluated in the forms: and , and the center broadening factor, which takes into account the contribution of strong and weak collisions in the transition region, is .
Rate Coefficient for the (4)Heμ + CH4 Reaction at 500 K: Comparison between Theory and Experiment.
Arseneau, Donald J; Fleming, Donald G; Li, Yongle; Li, Jun; Suleimanov, Yury V; Guo, Hua
2016-03-03
The rate constant for the H atom abstraction reaction from methane by the muonic helium atom, Heμ + CH4 → HeμH + CH3, is reported at 500 K and compared with theory, providing an important test of both the potential energy surface (PES) and reaction rate theory for the prototypical polyatomic CH5 reaction system. The theory used to characterize this reaction includes both variational transition-state (CVT/μOMT) theory (VTST) and ring polymer molecular dynamics (RPMD) calculations on a recently developed PES, which are compared as well with earlier calculations on different PESs for the H, D, and Mu + CH4 reactions, the latter, in particular, providing for a variation in atomic mass by a factor of 36. Though rigorous quantum calculations have been carried out for the H + CH4 reaction, these have not yet been extended to the isotopologues of this reaction (in contrast to H3), so it is important to provide tests of less rigorous theories in comparison with kinetic isotope effects measured by experiment. In this regard, the agreement between the VTST and RPMD calculations and experiment for the rate constant of the Heμ + CH4 reaction at 500 K is excellent, within 10% in both cases, which overlaps with experimental error.
Hamzah, Esah; Ourdjini, Ali; Ali, Mubarak; Akhter, Parvez; Hj. Mohd Toff, Mohd Radzi; Abdul Hamid, Mansor
In the present study, the effect of various N2 gas flow rates on friction coefficient and surface roughness of TiN-coated D2 tool steel was examined by a commercially available cathodic arc physical vapor deposition (CAPVD) technique. A Pin-on-Disc test was carried out to study the Coefficient of friction (COF) versus sliding distance. A surface roughness tester measured the surface roughness parameters. The minimum values for the COF and surface roughness were recorded at a N2 gas flow rate of 200 sccm. The increase in the COF and surface roughness at a N2 gas flow rate of 100 sccm was mainly attributed to an increase in both size and number of titanium particles, whereas the increase at 300 sccm was attributed to a larger number of growth defects generated during the coating process. These ideas make it possible to optimize the coating properties as a function of N2 gas flow rate for specific applications, e.g. cutting tools for automobiles, aircraft, and various mechanical parts.
Litniewski, Marek; Gorecki, Jerzy
2011-06-28
We have performed intensive computer simulations of the irreversible annihilation reaction: A + A → C + C and of the trapping reaction: A + B → C + B for a variety of three-dimensional fluids composed of identical spherical particles. We have found a significant difference in the asymptotic behavior of the rate coefficients for these reactions. Both the rate coefficients converge to the same value with time t going to infinity but the convergence rate is different: the O(t(-1/2)) term for the annihilation reaction is higher than the corresponding term for the trapping reaction. The simulation results suggest that ratio of the terms is a universal quantity with the value equal to 2 or slightly above. A model for the annihilation reaction based on the superposition approximation predicts the difference in the O(t(-1/2)) terms, but overestimates the value for the annihilation reaction by about 30%. We have also performed simulations for the dimerization process: A + A → E, where E stands for a dimer. The dimerization decreases the reaction rate due to the decrease in the diffusion constant for A. The effect is successfully predicted by a simple model.
Hoobler, Ray J.; Leone, Stephen R.
1997-01-01
Rate coefficients for the reactions of C2H + HCN yields products and C2H + CH3CN yields products have been measured over the temperature range 262-360 K. These experiments represent an ongoing effort to accurately measure reaction rate coefficients of the ethynyl radical, C2H, relevant to planetary atmospheres such as those of Jupiter and Saturn and its satellite Titan. Laser photolysis of C2H2 is used to produce C2H, and transient infrared laser absorption is employed to measure the decay of C2H to obtain the subsequent reaction rates in a transverse flow cell. Rate constants for the reaction C2H + HCN yields products are found to increase significantly with increasing temperature and are measured to be (3.9-6.2) x 10(exp 13) cm(exp 3) molecules(exp -1) s(exp -1) over the temperature range of 297-360 K. The rate constants for the reaction C2H + CH3CN yields products are also found to increase substantially with increasing temperature and are measured to be (1.0-2.1) x 10(exp -12) cm(exp 3) molecules(exp -1) s(exp -1) over the temperature range of 262-360 K. For the reaction C2H + HCN yields products, ab initio calculations of transition state structures are used to infer that the major products form via an addition/elimination pathway. The measured rate constants for the reaction of C2H + HCN yields products are significantly smaller than values currently employed in photochemical models of Titan, which will affect the HC3N distribution.
Endres, Eric S; Lakhmanskaya, Olga; Hauser, Daniel; Huber, Stefan E; Best, Thorsten; Kumar, Sunil S; Probst, Michael; Wester, Roland
2014-08-21
In the interstellar medium (ISM) ion–molecule reactions play a key role in forming complex molecules. Since 2006, after the radioastronomical discovery of the first of by now six interstellar anions, interest has grown in understanding the formation and destruction pathways of negative ions in the ISM. Experiments have focused on reactions and photodetachment of the identified negatively charged ions. Hints were found that the reactions of CnH(–) with H2 may proceed with a low (rate [Eichelberger, B.; et al. Astrophys. J. 2007, 667, 1283]. Because of the high abundance of molecular hydrogen in the ISM, a precise knowledge of the reaction rate is needed for a better understanding of the low-temperature chemistry in the ISM. A suitable tool to analyze rare reactions is the 22-pole radiofrequency ion trap. Here, we report on reaction rates for Cn(–) and CnH(–) (n = 2, 4, 6) with buffer gas temperatures of H2 at 12 and 300 K. Our experiments show the absence of these reactions with an upper limit to the rate coefficients between 4 × 10(–16) and 5 × 10(–15) cm(3) s(–1), except for the case of C2(–), which does react with a finite rate with H2 at low temperatures. For the cases of C2H(–) and C4H(–), the experimental results were confirmed with quantum chemical calculations. In addition, the possible influence of a residual reactivity on the abundance of C4H(–) and C6H(–) in the ISM were estimated on the basis of a gas-phase chemical model based on the KIDA database. We found that the simulated ion abundances are already unaffected if reaction rate coefficients with H2 were below 10(–14) cm(3) s(–1).
Altitude Variation of the CO2 (V2)-O Quenching Rate Coefficient in Mesosphere and Lower Thermosphere
Feofilovi, Artem; Kutepov, Alexander; She, Chiao-Yao; Smith, Anne K.; Pesnell, William Dean; Goldberg, Richard A.
2010-01-01
Among the processes governing the energy balance in the mesosphere and lower thermosphere (mlt), the quenching of CO2(N2) vibrational levels by collisions with oxygen atoms plays an important role. However, the k(CO2-O) values measured in the lab and retrieved from atmospheric measurements vary from 1.5 x 10(exp -12) cubic centimeters per second through 9.0 x 10(exp -12) cubic centimeters per second that requires further studying. In this work we used synergistic data from a ground based lidar and a satellite infrared radiometer to estimate K(CO2-O). We used the night- and daytime temperatures between 80 and 110 km measured by the colorado state university narrow-band sodium (Na) lidar located at fort collins, colorado (41N, 255E) as ground truth of the saber/timed nearly simultaneous (plus or minus 10 minutes) and common volume (within plus or minus 1 degree in latitude, plus or minus 2 degrees in longitude) observations. For each altitude in 80-110 km interval we estimate an "optimal" value of K(CO2-O) needed to minimize the discrepancy between the simulated 15 mm CO2 radiance and that measured by the saber/timed instrument. The K(CO2-O) obtained in this way varies in altitude from 3.5 x 10(exp -12) cubic centimeters per second at 80 km to 5.2 x 10(exp -12) cubic centimeters pers second for altitudes above 95 km. We discuss this variation of the rate constant and its impact on temperature retrievals from 15 mm radiance measurements and on the energy budget of mlt.
International Nuclear Information System (INIS)
Schnoll-Bitai, I.; Friedrich Olaj, O.; Liu Song Yu
1999-01-01
The systems styrene-p-methylstyrene, styrene-p-chlorostyrene, methyl methacrylate-p-methylstyrene and methyl methacrylate-p-chlorostyrene were polymerized under pseudo-stationary conditions (rotating sector or pulsed laser) at 25 degree C, 40 degree C and 50 degree C. The respective molecular weight distributions measured by GPC were analysed in order to derive directly the phenomenological rate constant of propagation, κ sub ρ. Copolymer compositions as a function of monomer feed could be described by the terminal model, whereas the kinetic results could only be interpreted in terms of the restricted penultimate model
Energy Technology Data Exchange (ETDEWEB)
Suresh, S.; Ritchie, R. O.
1981-11-01
The role of hydrogen gas in influencing fatigue crack propagation is examined for several classes of lower strength pressure vessel and piping steels. Based on measurements over a wide range of growth rates from 10/sup -8/ to 10/sup -2/ mm/cycle, crack propagation rates are found to be significantly higher in dehumidified gaseous hydrogen compared to moist air in two distinct regimes of crack growth, namely (i) at the intermediate range of growth typically above approx. 10/sup -5/ mm/cycle, and (ii) at the near-threshold region below approx. 10/sup -6/ mm/cycle approaching lattice dimensions per cycle. Both effects are seen at maximum stress intensities (K/sub max/) far below the sustained-load threshold stress intensity for hydrogen-assisted cracking (K/sub Iscc/). Characteristics of environmentally influenced fatigue crack growth in each regime are shown to be markedly different with regard to fractography and the effect of such variables as load ratio and frequency. It is concluded that the primary mechanisms responsible for the influence of the environment in each regime are distinctly different. Whereas corrosion fatigue behavior at intermediate growth rates can be attributed to hydrogen embrittlement processes, the primary role of moist environments at near-threshold levels is shown to involve a contribution from enhanced crack closure due to the formation of crack surface corrosion deposits at low load ratios.
Experimental study of fatigue crack propagation in type 316 austenitic stainless steel
International Nuclear Information System (INIS)
Mostafa, M.; Vessiere, G.; Hamel, A.; Boivin, M.
1983-01-01
In this work, are grouped and compared the crack propagation rates in type 316 austenitic stainless steel in two loading cases: plane strain and plane stress. Plane strain has been obtained on axisymmetric cracked specimens, plane stress on thin notched specimens, subjected to alternative bending. The results show that the crack propagation rate is greater for plane strain, i.e. in the case of the smallest plastic zone. The Elber concept was also used for explaining the different values of the crack propagation rate. It's noteworthy to find out that the Paris' law coefficients for different loading levels and those fo Elber's law are correlated [fr
Tchakoua, Théophile; Nkot Nkot, Pierre René; Fifen, Jean Jules; Nsangou, Mama; Motapon, Ousmanou
2018-06-01
We present the first potential energy surface (PES) for the AlO(X2Σ+)-He(1 S) van der Waals complex. This PES has been calculated at the RCCSD(T) level of theory. The mixed Gaussian/Exponential Extrapolation Scheme of complete basis set [CBS(D,T,Q)] was employed. The PES was fitted using global analytical method. This fitted PES was used subsequently in the close-coupling approach for the computation of the state-to-state collisional excitation cross sections of the fine-structure levels of the AlO-He complex. Collision energies were taken up to 2500 cm-1 and they yield after thermal averaging, state-to-state rate coefficients up to 300 K. The propensity rules between the lowest fine-structure levels were studied. These rules show, on one hand, a strong propensity in favour of odd ΔN transitions, and on the other hand, that cross sections and collisional rate coefficients for Δj = ΔN transitions are larger than those for Δj ≠ ΔN transitions.
Honvault, P; Scribano, Y
2013-10-03
The dynamics of the D(+) + H2 → HD + H(+) reaction on a recent ab initio potential energy surface (Velilla, L.; Lepetit, B.; Aguado, A.; Beswick, J. A.; Paniagua, M. J. Chem. Phys. 2008, 129, 084307) has been investigated by means of a time-independent quantum mechanical approach. Cross-sections and rate coefficients are calculated, respectively, for collision energies below 0.1 eV and temperatures up to 100 K for astrophysical application. An excellent accord is found for collision energy above 5 meV, while a disagreement between theory and experiment is observed below this energy. We show that the rate coefficients reveal a slightly temperature-dependent behavior in the upper part of the temperature range considered here. This is in agreement with the experimental data above 80 K, which give a temperature independent value. However, a significant decrease is found at temperatures below 20 K. This decrease can be related to quantum effects and the decay back to the reactant channel, which are not considered by simple statistical approaches, such as the Langevin model. Our results have been fitted to appropriate analytical expressions in order to be used in astrochemical and cosmological models.
Feofilov, A. G.; Kutepov, A. A.; She, C.-Y.; Smith, A. K.; Pesnell, W. D.; Goldberg, R. A.
2012-01-01
Among the processes governing the energy balance in the mesosphere and lower thermosphere (MLT), the quenching of CO2(nu2) vibrational levels by collisions with O atoms plays an important role. However, there is a factor of 3-4 discrepancy between the laboratory measurements of the CO2-O quenching rate coefficient, k(sub VT),and its value estimated from the atmospheric observations. In this study, we retrieve k(sub VT) in the altitude region85-105 km from the coincident SABER/TIMED and Fort Collins sodium lidar observations by minimizing the difference between measured and simulated broadband limb 15 micron radiation. The averaged k(sub VT) value obtained in this work is 6.5 +/- 1.5 X 10(exp -12) cubic cm/s that is close to other estimates of this coefficient from the atmospheric observations.However, the retrieved k(sub VT) also shows altitude dependence and varies from 5.5 1 +/-1 10(exp -12) cubic cm/s at 90 km to 7.9 +/- 1.2 10(exp -12) cubic cm/s at 105 km. Obtained results demonstrate the deficiency in current non-LTE modeling of the atmospheric 15 micron radiation, based on the application of the CO2-O quenching and excitation rates, which are linked by the detailed balance relation. We discuss the possible model improvements, among them accounting for the interaction of the non-thermal oxygen atoms with CO2 molecules.
Kurnosov, Alexander; Cacciatore, Mario; Laganà, Antonio; Pirani, Fernando; Bartolomei, Massimiliano; Garcia, Ernesto
2014-04-05
The rate coefficients for N2-N2 collision-induced vibrational energy exchange (important for the enhancement of several modern innovative technologies) have been computed over a wide range of temperature. Potential energy surfaces based on different formulations of the intramolecular and intermolecular components of the interaction have been used to compute quasiclassically and semiclassically some vibrational to vibrational energy transfer rate coefficients. Related outcomes have been rationalized in terms of state-to-state probabilities and cross sections for quasi-resonant transitions and deexcitations from the first excited vibrational level (for which experimental information are available). On this ground, it has been possible to spot critical differences on the vibrational energy exchange mechanisms supported by the different surfaces (mainly by their intermolecular components) in the low collision energy regime, though still effective for temperatures as high as 10,000 K. It was found, in particular, that the most recently proposed intermolecular potential becomes the most effective in promoting vibrational energy exchange near threshold temperatures and has a behavior opposite to the previously proposed one when varying the coupling of vibration with the other degrees of freedom. Copyright © 2014 Wiley Periodicals, Inc.
Bisetti, Fabrizio
2014-01-02
The effects of an electric field on the collision rates, energy exchanges and transport properties of electrons in premixed flames are investigated via solutions to the Boltzmann kinetic equation. The case of high electric field strength, which results in high-energy, non-thermal electrons, is analysed in detail at sub-breakdown conditions. The rates of inelastic collisions and the energy exchange between electrons and neutrals in the reaction zone of the flame are characterised quantitatively. The analysis includes attachment, ionisation, impact dissociation, and vibrational and electronic excitation processes. Our results suggest that Townsend breakdown occurs for E/N = 140 Td. Vibrational excitation is the dominant process up to breakdown, despite important rates of electronic excitation of CO, CO2 and N2 as well as impact dissociation of O2 being apparent from 50 Td onwards. Ohmic heating in the reaction zone is found to be negligible (less than 2% of peak heat release rate) up to breakdown field strengths for realistic electron densities equal to 1010 cm-3. The observed trends are largely independent of equivalence ratio. In the non-thermal regime, electron transport coefficients are insensitive to mixture composition and approximately constant across the flame, but are highly dependent on the electric field strength. In the thermal limit, kinetic parameters and transport coefficients vary substantially across the flame due to the spatially inhomogeneous concentration of water vapour. A practical approach for identifying the plasma regime (thermal versus non-thermal) in studies of electric field effects on flames is proposed. © 2014 Taylor & Francis.
ALBERTO CARLOS DE QUEIROZ PINTO; VICTOR GALÁN SAÚCO; SISIR KUMAR MITRA; FRANCISCO RICARDO FERREIRA
2018-01-01
ABSTRACT This Chapter has the objectives to search, through the review of the available literature, important informations on the evolution of mango propagation regarding theoretical and practical aspects from cellular base of sexual propagation, nursery structures and organizations, substrate compositions and uses, importance of rootstock and scion selections, also it will be described the preparation and transport of the grafts (stem and bud) as well as the main asexual propagation methods...
Burkholder, J. B.; Bernard, F.; Papadimitriou, V. C.
2016-12-01
The atmospheric chemistry of organosiloxanes has recently been implicated in the formation of new particles as well as regional and indoor air quality. Methylsiloxanes with Sitextiles, health care and household products and in industrial applications as solvents and lubricants. They are released into the atmosphere during manufacturing, use, and disposal and have been observed in the atmosphere in ppb levels in certain locations. However, the fundamental chemical properties of this class of compounds, particularly their reactivity with the OH radical, are presently not fully characterized. In this work, the temperature dependence of the rate coefficients for the OH radical reaction with the simplest linear (L2 and L3) and cyclic (D3 and D4) siloxanes were measured: OH + (CH3)3SiOSi(CH3)3 = Products L2OH + [(CH3)3SiO]2Si(CH3)2 = Products L3OH + [-Si(CH3)2O-]3 = Products D3OH + [-Si(CH3)2O-]4 = Products D4OH rate coefficients were measured under pseudo-first conditions in OH over the temperature range 240-370 K using a pulsed laser photolysis-laser induced fluorescence (PLP-LIF) technique and at 296 K using a relative rate method. The present results are compared with available literature data where possible and discrepancies are discussed. The results from this work will be discussed in terms of the atmospheric lifetimes of these methylsiloxanes and the reactivity trends for this class of compound.
Energy Technology Data Exchange (ETDEWEB)
Shin, Chang-Hwan, E-mail: shinch@kaeri.re.kr; Park, Ju-Yong, E-mail: juyong@kaeri.re.kr; In, Wang-Kee, E-mail: wkin@kaeri.re.kr
2013-12-15
Highlights: • A lower end plug with side flow holes is suggested to provide alternative flow paths of the inner channel. • The inlet loss coefficient of the lower end plug is estimated from the experiment. • The flow rate through the side holes is estimated in a complete entrance blockage of inner channel. • The consequence in the reactor core condition is evaluated with a subchannel analysis code. - Abstract: Dual-cooled annular nuclear fuel for a pressurized water reactor (PWR) has been introduced for a significant increase in reactor power. KAERI has been developing a dual-cooled annular fuel for a power uprate of 20% in an optimized PWR in Korea, the OPR1000. This annular fuel can help decrease the fuel temperature substantially relative to conventional cylindrical fuel at a power uprate. Annular fuel has dual flow channels around itself; however, the inner flow channel has a weakness in that it is isolated unlike the outer flow channel, which is open to other neighbouring outer channels for a coolant exchange in the reactor core. If the entrance of the inner channel is, as a hypothetical event, completely blocked by debris, the inner channel will then experience a rapid increase in coolant temperature such that a departure from nucleate boiling (DNB) may occur. Therefore, a remedy to avoid such a postulated accident is indispensable for the safety of annular fuel. A lower end plug with side flow holes was suggested to provide alternative flow paths in addition to the central entrance of the inner channel. In this paper, the inlet loss coefficient of the lower end plug and the flow rate through the side holes were estimated from the experimental results even in a complete entrance blockage of the inner channel. An optimization for the side hole was also performed, and the results are applied to a subchannel analysis to evaluate the consequence in the reactor core condition.
Directory of Open Access Journals (Sweden)
ALBERTO CARLOS DE QUEIROZ PINTO
2018-03-01
Full Text Available ABSTRACT This Chapter has the objectives to search, through the review of the available literature, important informations on the evolution of mango propagation regarding theoretical and practical aspects from cellular base of sexual propagation, nursery structures and organizations, substrate compositions and uses, importance of rootstock and scion selections, also it will be described the preparation and transport of the grafts (stem and bud as well as the main asexual propagation methods their uses and practices. Finally, pattern and quality of graft mangos and their commercialization aspects will be discussed in this Chapter.
Bernard, François; Papanastasiou, Dimitrios K; Papadimitriou, Vassileios C; Burkholder, James B
2018-04-19
Permethylsiloxanes are emitted into the atmosphere during production and use as personal care products, lubricants, and cleaning agents. The predominate atmospheric loss process for permethylsiloxanes is expected to be via gas-phase reaction with the OH radical. In this study, rate coefficients, k(T), for the OH radical gas-phase reaction with the two simplest linear and cyclic permethylsiloxanes were measured using a pulsed laser photolysis-laser induced fluorescence technique over the temperature range of 240-370 K and a relative rate method at 294 K: hexamethyldisiloxane ((CH 3 ) 3 SiOSi(CH 3 ) 3 , L 2 ), k 1 ; octamethyltrisiloxane ([(CH 3 ) 3 SiO] 2 Si(CH 3 ) 2 , L 3 ), k 2 ; hexamethylcyclotrisiloxane ([-Si(CH 3 ) 2 O-] 3 , D 3 ), k 3 ; and octamethylcyclotetrasiloxane ([-Si(CH 3 ) 2 O-] 4 , D 4 ), k 4 . The obtained k(294 K) values and temperature-dependence expressions for the 240-370 K temperature range are (cm 3 molecule -1 s -1 , 2σ absolute uncertainties): k 1 (294 K) = (1.28 ± 0.08) × 10 -12 , k 1 ( T) = (1.87 ± 0.18) × 10 -11 exp(-(791 ± 27)/ T); k 2 (294 K) = (1.72 ± 0.10) × 10 -12 , k 2 ( T) = 1.96 × 10 -13 (T/298) 4.34 exp(657/ T); k 3 (294 K) = (0.82 ± 0.05) × 10 -12 , k 3 ( T) = (1.29 ± 0.19) × 10 -11 exp(-(805 ± 43)/ T); and k 4 (294 K) = (1.12 ± 0.10) × 10 -12 , k 4 ( T) = (1.80 ± 0.26) × 10 -11 exp(-(816 ± 43)/ T). The cyclic molecules were found to be less reactive than the analogous linear molecule with the same number of -CH 3 groups, while the linear and cyclic permethylsiloxane reactivity both increase with the increasing number of CH 3 - groups. The present results are compared with previous rate coefficient determinations where available. The permethylsiloxanes included in this study are atmospherically short-lived compounds with estimated atmospheric lifetimes of 11, 8, 17, and 13 days, respectively.
Yousefi, Masoud; Golmohammady, Shole; Mashal, Ahmad; Kashani, Fatemeh Dabbagh
2015-11-01
In this paper, on the basis of the extended Huygens-Fresnel principle, a semianalytical expression for describing on-axis scintillation index of a partially coherent flat-topped (PCFT) laser beam of weak to moderate oceanic turbulence is derived; consequently, by using the log-normal intensity probability density function, the bit error rate (BER) is evaluated. The effects of source factors (such as wavelength, order of flatness, and beam width) and turbulent ocean parameters (such as Kolmogorov microscale, relative strengths of temperature and salinity fluctuations, rate of dissipation of the mean squared temperature, and rate of dissipation of the turbulent kinetic energy per unit mass of fluid) on propagation behavior of scintillation index, and, hence, on BER, are studied in detail. Results indicate that, in comparison with a Gaussian beam, a PCFT laser beam with a higher order of flatness is found to have lower scintillations. In addition, the scintillation index and BER are most affected when salinity fluctuations in the ocean dominate temperature fluctuations.
Papadimitriou, Vassileios C; Karafas, Emmanuel S; Gierczak, Tomasz; Burkholder, James B
2015-07-16
The gas-phase CH3CO + O2 reaction is known to proceed via a chemical activation mechanism leading to the formation of OH and CH3C(O)OO radicals via bimolecular and termolecular reactive channels, respectively. In this work, rate coefficients, k, for the CH3CO + O2 reaction were measured over a range of temperature (241-373 K) and pressure (0.009-600 Torr) with He and N2 as the bath gas and used to characterize the bi- and ter-molecular reaction channels. Three independent experimental methods (pulsed laser photolysis-laser-induced fluorescence (PLP-LIF), pulsed laser photolysis-cavity ring-down spectroscopy (PLP-CRDS), and a very low-pressure reactor (VLPR)) were used to characterize k(T,M). PLP-LIF was the primary method used to measure k(T,M) in the high-pressure regime under pseudo-first-order conditions. CH3CO was produced by PLP, and LIF was used to monitor the OH radical bimolecular channel reaction product. CRDS, a complementary high-pressure method, measured k(295 K,M) over the pressure range 25-600 Torr (He) by monitoring the temporal CH3CO radical absorption following its production via PLP in the presence of excess O2. The VLPR technique was used in a relative rate mode to measure k(296 K,M) in the low-pressure regime (9-32 mTorr) with CH3CO + Cl2 used as the reference reaction. A kinetic mechanism analysis of the combined kinetic data set yielded a zero pressure limit rate coefficient, kint(T), of (6.4 ± 4) × 10(-14) exp((820 ± 150)/T) cm(3) molecule(-1) s(-1) (with kint(296 K) measured to be (9.94 ± 1.3) × 10(-13) cm(3) molecule(-1) s(-1)), k0(T) = (7.39 ± 0.3) × 10(-30) (T/300)(-2.2±0.3) cm(6) molecule(-2) s(-1), and k∞(T) = (4.88 ± 0.05) × 10(-12) (T/300)(-0.85±0.07) cm(3) molecule(-1) s(-1) with Fc = 0.8 and M = N2. A He/N2 collision efficiency ratio of 0.60 ± 0.05 was determined. The phenomenological kinetic results were used to define the pressure and temperature dependence of the OH radical yield in the CH3CO + O2 reaction. The
Temporal scaling in information propagation
Huang, Junming; Li, Chao; Wang, Wen-Qiang; Shen, Hua-Wei; Li, Guojie; Cheng, Xue-Qi
2014-06-01
For the study of information propagation, one fundamental problem is uncovering universal laws governing the dynamics of information propagation. This problem, from the microscopic perspective, is formulated as estimating the propagation probability that a piece of information propagates from one individual to another. Such a propagation probability generally depends on two major classes of factors: the intrinsic attractiveness of information and the interactions between individuals. Despite the fact that the temporal effect of attractiveness is widely studied, temporal laws underlying individual interactions remain unclear, causing inaccurate prediction of information propagation on evolving social networks. In this report, we empirically study the dynamics of information propagation, using the dataset from a population-scale social media website. We discover a temporal scaling in information propagation: the probability a message propagates between two individuals decays with the length of time latency since their latest interaction, obeying a power-law rule. Leveraging the scaling law, we further propose a temporal model to estimate future propagation probabilities between individuals, reducing the error rate of information propagation prediction from 6.7% to 2.6% and improving viral marketing with 9.7% incremental customers.
Uncertainty Propagation in Monte Carlo Depletion Analysis
International Nuclear Information System (INIS)
Shim, Hyung Jin; Kim, Yeong-il; Park, Ho Jin; Joo, Han Gyu; Kim, Chang Hyo
2008-01-01
A new formulation aimed at quantifying uncertainties of Monte Carlo (MC) tallies such as k eff and the microscopic reaction rates of nuclides and nuclide number densities in MC depletion analysis and examining their propagation behaviour as a function of depletion time step (DTS) is presented. It is shown that the variance of a given MC tally used as a measure of its uncertainty in this formulation arises from four sources; the statistical uncertainty of the MC tally, uncertainties of microscopic cross sections and nuclide number densities, and the cross correlations between them and the contribution of the latter three sources can be determined by computing the correlation coefficients between the uncertain variables. It is also shown that the variance of any given nuclide number density at the end of each DTS stems from uncertainties of the nuclide number densities (NND) and microscopic reaction rates (MRR) of nuclides at the beginning of each DTS and they are determined by computing correlation coefficients between these two uncertain variables. To test the viability of the formulation, we conducted MC depletion analysis for two sample depletion problems involving a simplified 7x7 fuel assembly (FA) and a 17x17 PWR FA, determined number densities of uranium and plutonium isotopes and their variances as well as k ∞ and its variance as a function of DTS, and demonstrated the applicability of the new formulation for uncertainty propagation analysis that need be followed in MC depletion computations. (authors)
International Nuclear Information System (INIS)
Al-Abdullah, T.; Carstoiu, F.; Chen, X.; Clark, H. L.; Fu, C.; Gagliardi, C. A.; Lui, Y.-W.; Mukhamedzhanov, A.; Tabacaru, G.; Tokimoto, Y.; Trache, L.; Tribble, R. E.
2010-01-01
The production of 22 Na in ONe novae can be influenced by the 22 Mg(p,γ) 23 Al reaction. To investigate this reaction rate at stellar energies, we have determined the asymptotic normalization coefficient (ANC) for 22 Mg+p→ 23 Al through measurements of the ANCs in the mirror nuclear system 22 Ne+n→ 23 Ne. The peripheral neutron-transfer reactions 13 C( 12 C, 13 C) 12 C and 13 C( 22 Ne, 23 Ne) 12 C were studied. The identical entrance and exit channels of the first reaction make it possible to extract independently the ground-state ANC in 13 C. Our experiment gives C p 1/2 2 ( 13 C)=2.24±0.11 fm -1 , which agrees with the value obtained from several previous measurements. The weighted average for all the obtained C p 1/2 2 is 2.31±0.08 fm -1 . This value is adopted to be used in obtaining the ANCs in 23 Ne. The differential cross sections for the reaction 13 C( 22 Ne, 23 Ne) 12 C leading to the J π =5/2 + and 1/2 + states in 23 Ne have been measured at 12 MeV/u. Optical model parameters for use in the DWBA calculations were obtained from measurements of the elastic scatterings 22 Ne+ 13 C and 22 Ne+ 12 C. The extracted ANC for the ground state in 23 Ne, C d 5/2 2 =0.86±0.08±0.12 fm -1 , is converted to its corresponding value in 23 Al using mirror symmetry to give C d 5/2 2 ( 23 Al)=(4.63±0.77)x10 3 fm -1 . The astrophysical S factor S(0) for the 22 Mg(p,γ) reaction was determined to be 0.96±0.11 keV b. The consequences for nuclear astrophysics are discussed.
Jubb, Aaron M; Gierczak, Tomasz; Baasandorj, Munkhbayar; Waterland, Robert L; Burkholder, James B
2014-05-06
Mixtures of methyl-perfluoroheptene-ethers (CH3OC7F13, MPHEs) are currently in use as replacements for perfluorinated alkanes (PFCs) and poly-ether heat transfer fluids, which are persistent greenhouse gases with lifetimes >1000 years. At present, the atmospheric processing and environmental impact from the use of MPHEs is unknown. In this work, rate coefficients at 296 K for the gas-phase reaction of the OH radical with six key isomers (including stereoisomers and enantiomers) of MPHEs used commercially were measured using a relative rate method. Rate coefficients for the six MPHE isomers ranged from ∼ 0.1 to 2.9 × 10(-12) cm(3) molecule(-1) s(-1) with a strong stereoisomer and -OCH3 group position dependence; the (E)-stereoisomers with the -OCH3 group in an α- position relative to the double bond had the greatest reactivity. Rate coefficients measured for the d3-MPHE isomer analogues showed decreased reactivity consistent with a minor contribution of H atom abstraction from the -OCH3 group to the overall reactivity. Estimated atmospheric lifetimes for the MPHE isomers range from days to months. Atmospheric lifetimes, radiative efficiencies, and global warming potentials for these short-lived MPHE isomers were estimated based on the measured OH rate coefficients along with measured and theoretically calculated MPHE infrared absorption spectra. Our results highlight the importance of quantifying the atmospheric impact of individual components in an isomeric mixture.
Thongpin, C.; Srimuk, J.; hipkam, N.; Wachirapong, P.
2015-07-01
In this study, 3 types of natural fibres, i.e. jute, sisal and abaca, were plain weaved to fibre mat. Before weaving, the fibres were treated with 5% NaOH to remove hemi cellulose and lignin. The weaving was performed by hand using square wooden block fit with nails for weaving using one and two types of natural fibres as weft and warp fibre to produce natural fibre mat. The fibre mat was also impregnated in sodium silicate solution extracted from rich husk ash. The pH of the solution was adjusted to pH 7 using H2SO4 before impregnation. After predetermined time, sodium silicate was gelled and deposited on the mat. The fabric mat and sodium silicate coated mat were then impregnated with PLA solution to produce prepreg. Dried pepreg was laminated with PLA sheet using compressing moulding machine to obtain natural fibre mat/PLA composite. The composite containing abaca aligned in longitudinal direction with respect to tension force enhanced Young's modulus more than 300%. Fibre mat composites with abaca aligned in longitudinal direction also showed tensile strength enhancement nearly 400% higher than neat PLA. After coating with sodium silicate, the tensile modulus of the composites was found slightly increased. The silicate coating was disadvantage on tensile strength of the composite due to the effect of sodium hydroxide solution that was used as solvent for silicate extraction from rice husk ash. However, sodium silicate could retard rate of fire propagation about 50%compare to neat PLA and about 10% reduction compared to fibre mat composites without sodium silicate coated fibre mat.
International Nuclear Information System (INIS)
Thongpin, C; Srimuk, J; Hipkam, N; Wachirapong, P
2015-01-01
In this study, 3 types of natural fibres, i.e. jute, sisal and abaca, were plain weaved to fibre mat. Before weaving, the fibres were treated with 5% NaOH to remove hemi cellulose and lignin. The weaving was performed by hand using square wooden block fit with nails for weaving using one and two types of natural fibres as weft and warp fibre to produce natural fibre mat. The fibre mat was also impregnated in sodium silicate solution extracted from rich husk ash. The pH of the solution was adjusted to pH 7 using H 2 SO 4 before impregnation. After predetermined time, sodium silicate was gelled and deposited on the mat. The fabric mat and sodium silicate coated mat were then impregnated with PLA solution to produce prepreg. Dried pepreg was laminated with PLA sheet using compressing moulding machine to obtain natural fibre mat/PLA composite. The composite containing abaca aligned in longitudinal direction with respect to tension force enhanced Young's modulus more than 300%. Fibre mat composites with abaca aligned in longitudinal direction also showed tensile strength enhancement nearly 400% higher than neat PLA. After coating with sodium silicate, the tensile modulus of the composites was found slightly increased. The silicate coating was disadvantage on tensile strength of the composite due to the effect of sodium hydroxide solution that was used as solvent for silicate extraction from rice husk ash. However, sodium silicate could retard rate of fire propagation about 50%compare to neat PLA and about 10% reduction compared to fibre mat composites without sodium silicate coated fibre mat. (paper)
Directory of Open Access Journals (Sweden)
Zhijian Liu
2015-08-01
Full Text Available The determinations of heat collection rate and heat loss coefficient are crucial for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, the direct determination requires complex detection devices and a series of standard experiments, which also wastes too much time and manpower. To address this problem, we propose machine learning models including artificial neural networks (ANNs and support vector machines (SVM to predict the heat collection rate and heat loss coefficient without a direct determination. Parameters that can be easily obtained by “portable test instruments” were set as independent variables, including tube length, number of tubes, tube center distance, heat water mass in tank, collector area, final temperature and angle between tubes and ground, while the heat collection rate and heat loss coefficient determined by the detection device were set as dependent variables respectively. Nine hundred fifteen samples from in-service water-in-glass evacuated tube solar water heaters were used for training and testing the models. Results show that the multilayer feed-forward neural network (MLFN with 3 nodes is the best model for the prediction of heat collection rate and the general regression neural network (GRNN is the best model for the prediction of heat loss coefficient due to their low root mean square (RMS errors, short training times, and high prediction accuracies (under the tolerances of 30%, 20%, and 10%, respectively.
Ng, Maggie; Mok, Daniel K W; Lee, Edmond P F; Dyke, John M
2013-03-15
The minimum energy path (MEP) of the reaction, CF(3)CHFCF(3) + H → transition state (TS) → CF(3)CFCF(3) + H(2), has been computed at different ab initio levels and with density functional theory (DFT) using different functionals. The computed B3LYP/6-31++G**, BH&HLYP/cc-pVDZ, BMK/6-31++G**, M05/6-31+G**, M05-2X/6-31+G**, UMP2/6-31++G**, PUMP2/6-31++G**//UMP2/6-31++G**, RCCSD(T)/aug-cc-pVDZ//UMP2/6-31++G**, RCCSD(T)/aug-cc-pVTZ(spd,sp)//UMP2//6-31++G**, RCCSD(T)/CBS//M05/6-31+G**, and RCCSD(T)/CBS//UMP2/6-31++G** MEPs, and associated gradients and Hessians, were used in reaction rate coefficient calculations based on the transition state theory (TST). Reaction rate coefficients were computed between 300 and 1500 K at various levels of TST, which include conventional TST, canonical variational TST (CVT) and improved CVT (ICVT), and with different tunneling corrections, namely, Wigner, zero-curvature, and small-curvature (SCT). The computed rate coefficients obtained at different ab initio, DFT and TST levels are compared with experimental values available in the 1000-1200 K temperature range. Based on the rate coefficients computed at the ICVT/SCT level, the highest TST level used in this study, the BH&HLYP functional performs best among all the functionals used, while the RCCSD(T)/CBS//MP2/6-31++G** level is the best among all the ab initio levels used. Comparing computed reaction rate coefficients obtained at different levels of theory shows that, the computed barrier height has the strongest effect on the computed reaction rate coefficients as expected. Variational effects on the computed rate coefficients are found to be negligibly small. Although tunneling effects are relatively small at high temperatures (~1500 K), SCT corrections are significant at low temperatures (~300 K), and both barrier heights and the magnitudes of the imaginary frequencies affect SCT corrections. Copyright © 2012 Wiley Periodicals, Inc.
Diffusion coefficients of tracers in glassy polymer systems prepared by gamma radiolysis
International Nuclear Information System (INIS)
Tonge, M.P.; Gilbert, R.G.
1996-01-01
Diffusion-controlled reactions are common in free radical polymerisation reactions, especially in glassy polymer matrices. Such reactions commonly have an important influence on the polymerisation process and final polymer properties. For example, the dominant growth-stopping event (bimolecular termination) is generally diffusion-controlled. In glassy polymer systems, where molecular mobility is very low, the chain growth mechanism (propagation) may become diffusion-controlled. At present, the mechanism for propagation in glassy polymers is poorly understood, but it is expected by the Smoluchowski expression applied to propagation to depend strongly on the diffusion coefficient of monomer. The objective of this study is to measure reliable diffusion coefficients of small tracer molecules in glassy polymers, and compare these with propagation rate coefficients in similar systems, by the prediction above. Samples were initially prepared in a sealed sampled cell containing monomer, inert diluent, and tracer dye. After irradiation for several days, complete conversion of monomer to polymer can be obtained. The diffusion coefficients for two tracer dyes have been measured as a function of weight fraction polymer glassy poly(methyl methacrylate) samples
International Nuclear Information System (INIS)
Hermansson, B.R.
1989-01-01
The main part of this thesis consists of 15 published papers, in which the numerical Beam Propagating Method (BPM) is investigated, verified and used in a number of applications. In the introduction a derivation of the nonlinear Schroedinger equation is presented to connect the beginning of the soliton papers with Maxwell's equations including a nonlinear polarization. This thesis focuses on the wide use of the BPM for numerical simulations of propagating light and particle beams through different types of structures such as waveguides, fibers, tapers, Y-junctions, laser arrays and crystalline solids. We verify the BPM in the above listed problems against other numerical methods for example the Finite-element Method, perturbation methods and Runge-Kutta integration. Further, the BPM is shown to be a simple and effective way to numerically set up the Green's function in matrix form for periodic structures. The Green's function matrix can then be diagonalized with matrix methods yielding the eigensolutions of the structure. The BPM inherent transverse periodicity can be untied, if desired, by for example including an absorptive refractive index at the computational window edges. The interaction of two first-order soliton pulses is strongly dependent on the phase relationship between the individual solitons. When optical phase shift keying is used in coherent one-carrier wavelength communication, the fiber attenuation will suppress or delay the nonlinear instability. (orig.)
Directory of Open Access Journals (Sweden)
Paweł Sędłak
2017-01-01
Full Text Available Laboratorial two-body wear testing was carried out in order to assess effects of polypropylene modification by impregnating it with oils on friction coefficient and wear in comparison to those parameters of unmodified polypropylene, Teflon, and polyamide during operation under conditions of sliding friction without lubrication. Wear behaviour of the tested specimens was investigated using ASTM G77-98 standard wear test equipment. Recording program made it possible to visualise and record the following parameters: rotational speed and load, linear wear, friction coefficient, temperature of the specimen, and ambient temperature. In addition, wear mechanisms of the analysed materials were determined with use of scanning electron microscopy. In the case of the remaining tested polymers, the most important mechanism of wear was adhesion (PP, PTFE, PA 6.6, and PA MoS2, microcutting (PTFE, PA 6.6, and PA MoS2, fatigue wear (PTFE, forming “roll-shaped particles” combined with plastic deformation (PA 6.6 and PA MoS2, and thermal wear (PP. Impregnation of polypropylene with engine oil, gear oil, or RME results in significant reduction of friction coefficient and thus of friction torque, in relation to not only unmodified polypropylene but also the examined polyamide and Teflon.
International Nuclear Information System (INIS)
Sasaki, Yasuhiro; Minami, Noritoshi; Yoshida, Yoshitaka
2006-01-01
Institute of Nuclear Safety System, Inc. had developed the dose evaluation system to evaluate the radiation dose of employees at severe accident in a nuclear power plant. This system has features, which are (1) the dose rate of any evaluation point can be evaluated, (2) the dose rate at any time can be evaluated in consideration of the change in the radioactive source, (3) the dose rate map in the plant can be displayed (4) the dose along the access route when moving can be evaluated, and it is possible to use it for examination of the accident management guideline on the dose side etc.. To upgrade the dose evaluation function of this system, the improvements had been done which were introduction of the dose rate conversion coefficient and addition of the access route edit function. By introducing the dose rate conversion coefficient, the calculation time of the dose rate map in the plant was shortened at about 20 seconds, and a new function to evaluate time-dependent dose rate of any evaluation point was added. By adding the access route edit function, it became possible to re-calculate the dose easily at the route change. (author)
Jaffe, Richard; Schwenke, David; Chaban, Galina; Panesi, Marco
2014-01-01
Development of High-Fidelity Physics-Based Models to describe hypersonic flight through the atmospheres of Earth and Mars is underway at NASA Ames Research Center. The goal is to construct chemistry models of the collisional and radiative processes that occur in the bow shock and boundary layers of spacecraft during atmospheric entry that are free of empiricism. In this talk I will discuss our philosophy and describe some of our progress. Topics to be covered include thermochemistry, internal energy relaxation, collisional dissociation and radiative emission and absorption. For this work we start by solving the Schrodinger equation to obtain accurate interaction potentials and radiative properties. Then we invoke classical mechanics to compute state-specific heavy particle collision cross sections and reaction rate coefficients. Finally, phenomenological rate coefficients and relaxation times are determined from master equation solutions.
International Nuclear Information System (INIS)
Martins, Geraldo de Paula; Cimini Junior, Carlos Alberto; Godefroid, Leonardo Barbosa
2005-01-01
The welding process introduces defects on the welded joints, as lack of fusion and penetration, porosity, between others. These defects can compromise the structures or components, relative to the crack propagation. This engagement can be studied by fatigue crack propagation tests. The efficiency of the structure, when submitted to a cyclic loading can be evaluated by these tests. The aim of this work is to study the behavior of welded joints containing defects as lack of penetration at the root or between welding passes relative to crack propagation resistance properties, and to compare these properties with the properties of the welded joints without defects. This study was accomplished from fatigue crack propagation test results, in specimens containing lack of penetration between welding passes. With the obtained results, the Paris equation coefficients and exponents that relate the crack propagation rate with the stress intensity cyclic factor for welded joints with and without defects were obtained. (author)
Energy Technology Data Exchange (ETDEWEB)
Ryu, Si Ok [School of Chemical Engineering, Yeungnam University, Gyeongsan (Korea, Republic of); Shin, Kuan Soo [Dept. of Chemistry, Soongsil University, Seoul (Korea, Republic of); Hwang, Soon Muk [Science Applications International Corp oration, 3000 Aerospace Park way, Brook Park, Ohio (United States)
2017-02-15
Rate coefficients of the title reactions, R1 (CH{sub 4} + O{sub 2} → HO{sub 2}+CH{sub 3}) and R{sub 2} (HCO+O{sub 2} → HO{sub 2} + CO) were obtained over T = 1610 ⁓ 1810 K and T = 200 ⁓ 1760 K, respectively, and at ρ = 7.1 μmol/cm{sup 3}. A lean CH{sub 4}/O{sub 2}/Ar mixture (0.1% CH{sub 4}, ϕ = 0.02) was heated behind reflected shock waves and the temporal OH absorption profiles were measured using a laser absorption spectroscopy. Reaction rate coefficients were elucidated by matching the experimental profiles via optimization of k1 and k2 values in the reaction simulation. The rate coefficient expressions derived are k{sub 1} = 1.46 × 10{sup 14} exp (−26 210 K/T) cm{sup 3}/mol/s, T = 1610 ⁓ 1810 K and k{sub 2} = 1.9 × 10{sup 12} T{sup 0.1{sup 6}} exp (−245 K/T) cm{sup 3}/mol/s, T = 200 ⁓ 1760 K.
Bisetti, Fabrizio; El Morsli, Mbark
2014-01-01
The effects of an electric field on the collision rates, energy exchanges and transport properties of electrons in premixed flames are investigated via solutions to the Boltzmann kinetic equation. The case of high electric field strength, which
Aggarwal, K. M.; Kingston, A. E.; McDowell, M. R. C.
1984-03-01
The available experimental and theoretical electron impact excitation cross section data for the transitions from the 1s2 1S ground state to the 1s2s 1,3S and 1s2p 1,3P0 excited states of helium are assessed. Based on this assessed data, excitation rate coefficients are calculated over a wide electron temperature range below 3.0×106K. A comparison with other published results suggests that the rates used should be lower by a factor of 2 or more.
Charmonium propagation through a dense medium
Directory of Open Access Journals (Sweden)
Kopeliovich B.Z.
2015-01-01
Full Text Available Attenuation of a colourless c̄c dipole propagating with a large momentum through a hot medium originates from two sources, Debye screening (melting, and inelastic collisions with surrounding scattering centres (absorption. The former never terminates completely production of a bound charmonium in heavy ion collisions, even at very high temperatures. The latter, is controlled my the magnitude of the dipole cross section, related to the transport coefficient, which is the rate of transverse momentum broadening in the medium. A novel procedure of Lorentz boosting of the Schrödinger equation is developed, which allows to calculate the charmonium survival probability employing the path-integral technique, incorporating both melting and absorption. A novel mechanism of charmonium regeneration in a dense medium is proposed.
The rate coefficient for the reaction NO2 + NO3 yielding NO + NO2 + O2 from 273 to 313 K
Cantrell, Chris A.; Shetter, Richard E.; Mcdaniel, Anthony H.; Calvert, Jack G.
1990-01-01
The ratio of rate constants for the reaction NO3 + NO yielding 2 NO2 (k3) and the reaction NO2 + NO3 yielding NO + NO2 + O2 (k4) were determined by measuring of NO and NO2 concentrations of NO and NO2 in an N2O5/NO2/N2 mixture over the temperature range 273-313 K. The measured ratio was found to be expressed by the equation k3/k4 = 387 exp(-1375/T). The results are consistent with those of Hammer et al. (1986).
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S.B. Jonnalagadda
2012-08-01
Full Text Available ‘Simkine3’, a Delphi based software is developed to simulate the kinetic schemes of complex reaction mechanisms involving multiple sequential and competitive elementary steps for homogeneous and heterogeneous chemical reactions. Simkine3 is designed to translate the user specified mechanism into chemical first-order differential equations (ODEs and optimise the estimated rate constants in such a way that simulated curves match the experimental kinetic profiles. TLSoda which uses backward differentiation method is utilised to solve resulting ODEs and Downhill Simplex method is used to optimise the estimated rate constants in a robotic way. An online help file is developed using HelpScrible Demo to guide the users of Simkine3. The versatility of the software is demonstrated by simulating the complex reaction between methylene violet and acidic bromate, a reaction which exhibits complex nonlinear kinetics. The new software is validated after testing it on a 19-step intricate mechanism involving 15 different species. The kinetic profiles of multiple simulated curves, illustrating the effect of initial concentrations of bromate, and bromide were matched with the corresponding experimental curves.DOI: http://dx.doi.org/10.4314/bcse.v26i2.10
International Nuclear Information System (INIS)
Oikonomidis, F.; Shterenlikht, A.; Truman, C.E.
2014-01-01
Part 1 of this paper described a specimen for the measurement of high strain rate flow and fracture properties of pipe material and for tuning a strain rate dependent damage model (SRDD). In part 2 the tuned SRDD model is used for the simulation of axial crack propagation and arrest in X100 natural gas pipelines. Linear pressure drop model was adopted behind the crack tip, and an exponential gas depressurisation model was used ahead of the crack tip. The model correctly predicted the crack initiation (burst) pressure, the crack speed and the crack arrest length. Strain rates between 1000 s −1 and 3000 s −1 immediately ahead of the crack tip are predicted, giving a strong indication that a strain rate material model is required for the structural integrity assessment of the natural gas pipelines. The models predict the stress triaxiality of about 0.65 for at least 1 m ahead of the crack tip, gradually dropping to 0.5 at distances of about 5–7 m ahead of the crack tip. Finally, the models predicted a linear drop in crack tip opening angle (CTOA) from about 11−12° at the onset of crack propagation down to 7−8° at crack arrest. Only the lower of these values agree with those reported in the literature for quasi-static measurements. This discrepancy might indicate substantial strain rate dependence in CTOA. - Highlights: • Finite element simulations of 3 burst tests of X100 pipes are detailed. • Strain rate dependent damage model, tuned on small scale X100 samples, was used. • The models correctly predict burst pressure, crack speed and crack arrest length. • The model predicts a crack length dependent critical CTOA. • The strain rate dependent damage model is verified as mesh independent
International Nuclear Information System (INIS)
Picard, R.R.
1989-01-01
Topics covered in this chapter include a discussion of exact results as related to nuclear materials management and accounting in nuclear facilities; propagation of error for a single measured value; propagation of error for several measured values; error propagation for materials balances; and an application of error propagation to an example of uranium hexafluoride conversion process
McGillen, Max R; Baasandorj, Munkhbayar; Burkholder, James B
2013-06-06
Butanol (C4H9OH) is a potential biofuel alternative in fossil fuel gasoline and diesel formulations. The usage of butanol would necessarily lead to direct emissions into the atmosphere; thus, an understanding of its atmospheric processing and environmental impact is desired. Reaction with the OH radical is expected to be the predominant atmospheric removal process for the four aliphatic isomers of butanol. In this work, rate coefficients, k, for the gas-phase reaction of the n-, i-, s-, and t-butanol isomers with the OH radical were measured under pseudo-first-order conditions in OH using pulsed laser photolysis to produce OH radicals and laser induced fluorescence to monitor its temporal profile. Rate coefficients were measured over the temperature range 221-381 K at total pressures between 50 and 200 Torr (He). The reactions exhibited non-Arrhenius behavior over this temperature range and no dependence on total pressure with k(296 K) values of (9.68 ± 0.75), (9.72 ± 0.72), (8.88 ± 0.69), and (1.04 ± 0.08) (in units of 10(-12) cm(3) molecule(-1) s(-1)) for n-, i-, s-, and t-butanol, respectively. The quoted uncertainties are at the 2σ level and include estimated systematic errors. The observed non-Arrhenius behavior is interpreted here to result from a competition between the available H-atom abstraction reactive sites, which have different activation energies and pre-exponential factors. The present results are compared with results from previous kinetic studies, structure-activity relationships (SARs), and theoretical calculations and the discrepancies are discussed. Results from this work were combined with available high temperature (1200-1800 K) rate coefficient data and room temperature reaction end-product yields, where available, to derive a self-consistent site-specific set of reaction rate coefficients of the form AT(n) exp(-E/RT) for use in atmospheric and combustion chemistry modeling.
International Nuclear Information System (INIS)
Cristea, G.
1975-01-01
The neutron problems are discussed of the thermonuclear reactor controlled by the rate of the fission reactions. The results obtained by rolling the DTF-4 program in a spherical geometry in the case of an ''external source'' problem permit to draw conclusions concerning the problems of the neutronics system of this thermonuclear reactor type. A relation is deduced for estimating the coefficient of back-reflection of the neutrons within the thermonuclear plasma and the focussion system is discussed of the neutronics of this reactor type
Jiang, Jing; Liu, Wanhua; Ye, Yuanyuan; Wang, Rui; Li, Fengfang; Peng, Chengyu
2014-06-17
To investigate the diagnostic efficiency of decline rate of signal intensity and apparent diffusion coefficient with different b values for differentiating benign and malignant breast lesions on diffusion-weighted 3.0 T magnetic resonance imaging. A total of 152 patients with 162 confirmed histopathologically breast lesions (85 malignant and 77 benign) underwent 3.0 T diffusion-weighted magnetic resonance imaging. Four b values (0, 400, 800 and 1 000 s/mm²) were used. The signal intensity and ADC values of breast lesions were measured respectively. The signal intensity decline rate (SIDR) and apparent diffusion coefficient decline rate (ADCDR) were calculated respectively. SIDR = (signal intensity of lesions with low b value-signal intensity of lesions with high b value)/signal intensity of lesions with low b value, ADCDR = (ADC value of lesions with low b value-ADC value of lesions with high b value) /ADC value of lesions with low b value. The independent sample t-test was employed for statistical analyses and the receiver operating characteristic (ROC) curve for evaluating the diagnosis efficiency of SIDR and ADCDR values. Significant differences were observed in SIDR between benign and malignant breast lesions with b values of 0-400, 400-800 and 800-1 000 s/mm². The sensitivities of SIDR for differentiating benign and malignant breast lesions were 61.2%, 68.2% and 67.1%, the specificities 74.0%, 85.7% and 67.5%, the diagnosis accordance rates 67.3%, 76.5% and 67.3%, the positive predictive values 72.2%, 84.1% and 69.5% and the negative predictive values 63.3%, 71.0% and 65.0% respectively. Significant differences were observed in ADCDR between benign and malignant breast lesions with b values of 400-800 s/mm² and 800-1 000 s/mm². The sensitivities of SDR for differentiating benign and malignant breast lesions were 80.0% and 65.9%, the specificities 72.7% and 65.0%, the diagnostic accordance rates 76.5% and 65.4%, the positive predictive values 76.4% and 67
Copeland, G; Lee, E P F; Williams, R G; Archibald, A T; Shallcross, D E; Dyke, J M
2014-01-01
In this work, the photolysis rate coefficient of CH3SCH2Cl (MClDMS) in the lower atmosphere has been determined and has been used in a marine boundary layer (MBL) box model to determine the enhancement of SO2 production arising from the reaction DMS + Cl2. Absorption cross sections measured in the 28000-34000 cm(-1) region have been used to determine photolysis rate coefficients of MClDMS in the troposphere at 10 solar zenith angles (SZAs). These have been used to determine the lifetimes of MClDMS in the troposphere. At 0° SZA, a photolysis lifetime of 3-4 h has been obtained. The results show that the photolysis lifetime of MClDMS is significantly smaller than the lifetimes with respect to reaction with OH (≈ 4.6 days) and with Cl atoms (≈ 1.2 days). It has also been shown, using experimentally derived dissociation energies with supporting quantum-chemical calculations, that the dominant photodissocation route of MClDMS is dissociation of the C-S bond to give CH3S and CH2Cl. MBL box modeling calculations show that buildup of MClDMS at night from the Cl2 + DMS reaction leads to enhanced SO2 production during the day. The extra SO2 arises from photolysis of MClDMS to give CH3S and CH2Cl, followed by subsequent oxidation of CH3S.
International Nuclear Information System (INIS)
Castro-Palacio, Juan Carlos; Bemish, Raymond J.; Meuwly, Markus
2015-01-01
The O( 3 P) + NO( 2 Π) → O 2 (X 3 Σ g − ) + N( 4 S) reaction is among the N- and O- involving reactions that dominate the energetics of the reactive air flow around spacecraft during hypersonic atmospheric re-entry. In this regime, the temperature in the bow shock typically ranges from 1000 to 20 000 K. The forward and reverse rate coefficients for this reaction derived directly from trajectory calculations over this range of temperature are reported in this letter. Results compare well with the established equilibrium constants for the same reaction from thermodynamic quantities derived from spectroscopy in the gas phase which paves the way for large-scale in silico investigations of equilibrium rates under extreme conditions
Castro-Palacio, Juan Carlos; Bemish, Raymond J; Meuwly, Markus
2015-03-07
The O((3)P) + NO((2)Π) → O2(X(3)Σg(-)) + N((4)S) reaction is among the N- and O- involving reactions that dominate the energetics of the reactive air flow around spacecraft during hypersonic atmospheric re-entry. In this regime, the temperature in the bow shock typically ranges from 1000 to 20,000 K. The forward and reverse rate coefficients for this reaction derived directly from trajectory calculations over this range of temperature are reported in this letter. Results compare well with the established equilibrium constants for the same reaction from thermodynamic quantities derived from spectroscopy in the gas phase which paves the way for large-scale in silico investigations of equilibrium rates under extreme conditions.
Papadimitriou, Vassileios C; Lazarou, Yannis G; Talukdar, Ranajit K; Burkholder, James B
2011-01-20
Rate coefficients, k, for the gas-phase reactions of Cl atoms and NO(3) radicals with 2,3,3,3-tetrafluoropropene, CF(3)CF═CH(2) (HFO-1234yf), and 1,2,3,3,3-pentafluoropropene, (Z)-CF(3)CF═CHF (HFO-1225ye), are reported. Cl-atom rate coefficients were measured in the fall-off region as a function of temperature (220-380 K) and pressure (50-630 Torr; N(2), O(2), and synthetic air) using a relative rate method. The measured rate coefficients are well represented by the fall-off parameters k(0)(T) = 6.5 × 10(-28) (T/300)(-6.9) cm(6) molecule(-2) s(-1) and k(∞)(T) = 7.7 × 10(-11) (T/300)(-0.65) cm(3) molecule(-1) s(-1) for CF(3)CF═CH(2) and k(0)(T) = 3 × 10(-27) (T/300)(-6.5) cm(6) molecule(-2) s(-1) and k(∞)(T) = 4.15 × 10(-11) (T/300)(-0.5) cm(3) molecule(-1) s(-1) for (Z)-CF(3)C═CHF with F(c) = 0.6. Reaction product yields were measured in the presence of O(2) to be (98 ± 7)% for CF(3)C(O)F and (61 ± 4)% for HC(O)Cl in the CF(3)CF═CH(2) reaction and (108 ± 8)% for CF(3)C(O)F and (112 ± 8)% for HC(O)F in the (Z)-CF(3)CF═CHF reaction, where the quoted uncertainties are 2σ (95% confidence level) and include estimated systematic errors. NO(3) reaction rate coefficients were determined using absolute and relative rate methods. Absolute measurements yielded upper limits for both reactions between 233 and 353 K, while the relative rate measurements yielded k(3)(295 K) = (2.6 ± 0.25) × 10(-17) cm(3) molecule(-1) s(-1) and k(4)(295 K) = (4.2 ± 0.5) × 10(-18) cm(3) molecule(-1) s(-1) for CF(3)CF═CH(2) and (Z)-CF(3)CF═CHF, respectively. The Cl-atom reaction with CF(3)CF═CH(2) and (Z)-CF(3)CF═CHF leads to decreases in their atmospheric lifetimes and global warming potentials and formation of a chlorine-containing product, HC(O)Cl, for CF(3)CF═CH(2). The NO(3) reaction has been shown to have a negligible impact on the atmospheric lifetimes of CF(3)CF═CH(2) and (Z)-CF(3)CF═CHF. The energetics for the reaction of Cl, NO(3), and OH with CF
Fatigue crack propagation behavior under creep conditions
International Nuclear Information System (INIS)
Ohji, Kiyotsugu; Kubo, Shiro
1991-01-01
The crack propagation behavior of the SUS 304 stainless steel under creep-fatigue conditions was reviewed. Cracks propagated either in purely time-dependent mode or in purely cycle-dependent mode, depending on loading conditions. The time-dependent crack propagation rate was correlated with modified J-integral J * and the cycle-dependent crack propagation rate was correlated with J-integral range ΔJ f . Threshold was observed in the cycle-dependent crack propagation, and below this threshold the time-dependent crack propagation appeared. The crack propagation rates were uniquely characterized by taking the effective values of J * and ΔJ f , when crack closure was observed. Change in crack propagation mode occurred reversibly and was predicted by the competitive damage model. The threshold disappeared and the cycle-dependent crack propagation continued in a subthreshold region under variable amplitude conditions, where the threshold was interposed between the maximum and minimum ΔJ f . (orig.)
Prabhakaran, Sai Shri; Sahu, Sanjay Kumar; Dev, Pravin Jeba; Shanmugam, Palanisamy
2018-05-01
Spectral absorption coefficients of particulate (algal and non-algal components) and dissolved substances are modelled and combined with the pure seawater component to determine the total light absorption coefficients of seawater in the Bay of Bengal. Two parameters namely chlorophyll-a (Chl) concentration and turbidity were measured using commercially available instruments with high sampling rates. For modelling the light absorption coefficients of oceanic waters, the measured data are classified into two broad groups - algal dominant and non-algal particle (NAP) dominant. With these criteria the individual absorption coefficients of phytoplankton and NAP were established based on their concentrations using an iterative method. To account for the spectral dependence of absorption by phytoplankton, the wavelength-dependent coefficients were introduced into the model. The CDOM absorption was determined by subtracting the individual absorption coefficients of phytoplankton and NAP from the measured total absorption data and then related to the Chl concentration. Validity of the model is assessed based on independent in-situ data from certain discrete locations in the Bay of Bengal. The total absorption coefficients estimated using the new model by considering the contributions of algal, non-algal and CDOM have good agreement with the measured total absorption data with the error range of 6.9 to 28.3%. Results obtained by the present model are important for predicting the propagation of the radiant energy within the ocean and interpreting remote sensing observation data.
Ng, Maggie; Mok, Daniel K W; Lee, Edmond P F; Dyke, John M
2015-03-21
The reaction between atomic chlorine (Cl) and methyl nitrate (CH3ONO2) is significant in the atmosphere, as Cl is a key oxidant, especially in the marine boundary layer, and alkyl nitrates are important nitrogen-containing organic compounds, which are temporary reservoirs of the reactive nitrogen oxides NO, NO2 and NO3 (NOx). Four reaction channels HCl + CH2ONO2, CH3OCl + NO2, CH3Cl + NO3 and CH3O + ClNO2 were considered. The major channel is found to be the H abstraction channel, to give the products HCl + CH2ONO2. For all channels, geometry optimization and frequency calculations were carried out at the M06-2X/6-31+G** level, while relative electronic energies were improved to the UCCSD(T*)-F12/CBS level. The reaction barrier (ΔE(‡)0K) and reaction enthalpy (ΔH(RX)298K) of the H abstraction channel were computed to be 0.61 and -2.30 kcal mol(-1), respectively, at the UCCSD(T*)-F12/CBS//M06-2X/6-31+G** level. Reaction barriers (ΔE(‡)0K) for the other channels are more positive and these pathways do not contribute to the overall reaction rate coefficient in the temperature range considered (200-400 K). Rate coefficients were calculated for the H-abstraction channel at various levels of variational transition state theory (VTST) including tunnelling. Recommended ICVT/SCT rate coefficients in the temperature range 200-400 K are presented for the first time for this reaction. The values obtained in the 200-300 K region are particularly important as they will be valuable for atmospheric modelling calculations involving reactions with methyl nitrate. The implications of the results to atmospheric chemistry are discussed. Also, the enthalpies of formation, ΔHf,298K, of CH3ONO2 and CH2ONO2 were computed to be -29.7 and 19.3 kcal mol(-1), respectively, at the UCCSD(T*)-F12/CBS level.
Bolt beam propagation analysis
Shokair, I. R.
BOLT (Beam on Laser Technology) is a rocket experiment to demonstrate electron beam propagation on a laser ionized plasma channel across the geomagnetic field in the ion focused regime (IFR). The beam parameters for BOLT are: beam current I(sub b) = 100 Amps, beam energy of 1--1.5 MeV (gamma =3-4), and a Gaussian beam and channel of radii r(sub b) = r(sub c) = 1.5 cm. The N+1 ionization scheme is used to ionize atomic oxygen in the upper atmosphere. This scheme utilizes 130 nm light plus three IR lasers to excite and then ionize atomic oxygen. The limiting factor for the channel strength is the energy of the 130 nm laser, which is assumed to be 1.6 mJ for BOLT. At a fixed laser energy and altitude (fixing the density of atomic oxygen), the range can be varied by adjusting the laser tuning, resulting in a neutralization fraction axial profile of the form: f(z) = f(sub 0) e(exp minus z)/R, where R is the range. In this paper we consider the propagation of the BOLT beam and calculate the range of the electron beam taking into account the fact that the erosion rates (magnetic and inductive) vary with beam length as the beam and channel dynamically respond to sausage and hose instabilities.
Smith, Geoff; Jeeraruangrattana, Yowwares; Ermolina, Irina
2018-06-22
Through vial impedance spectroscopy (TVIS) is a product non-invasive process analytical technology which exploits the frequency dependence of the complex impedance spectrum of a composite object (i.e. the freeze-drying vial and its contents) in order to track the progression of the freeze-drying cycle. This work demonstrates the use of a dual electrode system, attached to the external surface of a type I glass tubing vial (nominal capacity 10 mL) in the prediction of (i) the ice interface temperatures at the sublimation front and at the base of the vial, and (ii) the primary drying rate. A value for the heat transfer coefficient (for a chamber pressure of 270 µbar) was then calculated from these parameters and shown to be comparable to that published by Tchessalov[1]. Copyright © 2018. Published by Elsevier B.V.
Directory of Open Access Journals (Sweden)
Jakubowski Marek
2017-03-01
Full Text Available After Vosikovsky (1975, the corrosion fatigue crack growth rate (CFCGR characteristics have been divided into three regions. The region-III rates are very close to mechanical fatigue crack growth rates. CFCGR formulae, including the long-crack length effect (in region I only, the loading frequency effect (in region II only, and the saltwater temperature effect, have been proposed. It has been assumed that CFCGR is proportional to f-k, where f is the loading frequency and k is a constant. The averaged k-value for all steels of yield stress (YS below 500 MPa, usually with ferrite-pearlite microstructures, is higher than that for YS > 500 MPa, usually with quenched and tempered microstructures. The temperature effect does not appear in region I below room temperature. In the remaining cases, that is, in region I for elevated temperatures and in region II for both low and elevated temperatures, the CFCGR increases with increasing temperature. Under a potential of -0.8 V, a long-crack-length effect, qualitatively similar to analogous effect for free corrosion conditions, appears.
Wave equations for pulse propagation
International Nuclear Information System (INIS)
Shore, B.W.
1987-01-01
Theoretical discussions of the propagation of pulses of laser radiation through atomic or molecular vapor rely on a number of traditional approximations for idealizing the radiation and the molecules, and for quantifying their mutual interaction by various equations of propagation (for the radiation) and excitation (for the molecules). In treating short-pulse phenomena it is essential to consider coherent excitation phenomena of the sort that is manifest in Rabi oscillations of atomic or molecular populations. Such processes are not adequately treated by rate equations for excitation nor by rate equations for radiation. As part of a more comprehensive treatment of the coupled equations that describe propagation of short pulses, this memo presents background discussion of the equations that describe the field. This memo discusses the origin, in Maxwell's equations, of the wave equation used in the description of pulse propagation. It notes the separation into lamellar and solenoidal (or longitudinal and transverse) and positive and negative frequency parts. It mentions the possibility of separating the polarization field into linear and nonlinear parts, in order to define a susceptibility or index of refraction and, from these, a phase and group velocity. The memo discusses various ways of characterizing the polarization characteristics of plane waves, that is, of parameterizing a transverse unit vector, such as the Jones vector, the Stokes vector, and the Poincare sphere. It discusses the connection between macroscopically defined quantities, such as the intensity or, more generally, the Stokes parameters, and microscopic field amplitudes. The material presented here is a portion of a more extensive treatment of propagation to be presented separately. The equations presented here have been described in various books and articles. They are collected here as a summary and review of theory needed when treating pulse propagation
International Nuclear Information System (INIS)
Souza Pereira, Wagner de; Kelecom, Alphonse
2008-01-01
Attention has been paid only recently to the protection of biota against radiation effects. Protection is being considered through modeling of the calculation of absorbed dose rate. In these models, the inputs are the fluxes of radionuclides of environmental concern and their resulting distribution between environmental compartments. Such distribution is estimated for dispersion models. In freshwater systems and when fish is used as biomaker, relevant environmental transfer parameters are transfer between sediment and water (sediment distribution coefficients KD, in l kg -1 ), and between water and fish (concentration factor CF, in l kg -1 ). These coefficients are under the influence of a number o physical, chemical and biological factors, and display following the literature a great variability. The present work establishes the KD's and CF's for uranium, thorium, radium and lead for two ponds: one that receives treated effluents from an ore treatment unit (UTM) situated at Pocos de Caldas, Minas Gerais, Brazil and the other pond from the uranium concentration unit (URA) situated at Caetite, Bahia, Brazil, and for fish used as biomarker. It intends also to compare these parameters with the values recommended by IAEA. Depending on considered radionuclide and on the site, CF's (l kg -1 ) observed values were of the same magnitude as, or one order of magnitude lower than recommended by IAEA. KD's (l kg -1 ) observed values were found of the same magnitude as those recommended by IAEA, approximately 10 times lower or up to 100 times higher than recommended by IAEA, again depending on the radionuclides and on the site. It can be concluded that local parameters should be established in order to obtain a more accurate estimative of biota exposition from man activities. (author)
Transport Coefficients of Fluids
Eu, Byung Chan
2006-01-01
Until recently the formal statistical mechanical approach offered no practicable method for computing the transport coefficients of liquids, and so most practitioners had to resort to empirical fitting formulas. This has now changed, as demonstrated in this innovative monograph. The author presents and applies new methods based on statistical mechanics for calculating the transport coefficients of simple and complex liquids over wide ranges of density and temperature. These molecular theories enable the transport coefficients to be calculated in terms of equilibrium thermodynamic properties, and the results are shown to account satisfactorily for experimental observations, including even the non-Newtonian behavior of fluids far from equilibrium.
Martin-Banda, Raquel; Insua-Arevalo, Juan Miguel; Garcia-Mayordomo, Julian
2017-04-01
Many studies have dealt with the calculation of fault-propagation fold growth rates considering a variety of kinematics models, from limb rotation to hinge migration models. In most cases, the different geometrical and numeric growth models are based on horizontal pre-growth strata architecture and a constant known slip rate. Here, we present the estimation of the vertical slip rate of the NE Segment of the Carrascoy Fault (SE Iberian Peninsula) from the geometrical modeling of a progressive unconformity developed on alluvial fan sediments with a high depositional slope. The NE Segment of the Carrascoy Fault is a left-lateral strike slip fault with reverse component belonging to the Eastern Betic Shear Zone, a major structure that accommodates most of the convergence between Iberian and Nubian tectonics plates in Southern Spain. The proximity of this major fault to the city of Murcia encourages the importance of carrying out paleosismological studies in order to determinate the Quaternary slip rate of the fault, a key geological parameter for seismic hazard calculations. This segment is formed by a narrow fault zone that articulates abruptly the northern edge of the Carrascoy Range with the Guadalentin Depression through high slope, short alluvial fans Upper-Middle Pleistocene in age. An outcrop in a quarry at the foot of this front reveals a progressive unconformity developed on these alluvial fan deposits, showing the important reverse component of the fault. The architecture of this unconformity is marked by well-developed calcretes on the top some of the alluvial deposits. We have determined the age of several of these calcretes by the Uranium-series disequilibrium dating method. The results obtained are consistent with recent published studies on the SW segment of the Carrascoy Fault that together with offset canals observed at a few locations suggest a net slip rate close to 1 m/ka.
A gain-coefficient switched Alexandrite laser
International Nuclear Information System (INIS)
Lee, Chris J; Van der Slot, Peter J M; Boller, Klaus-J
2013-01-01
We report on a gain-coefficient switched Alexandrite laser. An electro-optic modulator is used to switch between high and low gain states by making use of the polarization dependent gain of Alexandrite. In gain-coefficient switched mode, the laser produces 85 ns pulses with a pulse energy of 240 mJ at a repetition rate of 5 Hz.
Helioseismic Solar Cycle Changes and Splitting Coefficients
Indian Academy of Sciences (India)
tribpo
Abstract. Using the GONG data for a period over four years, we have studied the variation of frequencies and splitting coefficients with solar cycle. Frequencies and even-order coefficients are found to change signi- ficantly with rising phase of the solar cycle. We also find temporal varia- tions in the rotation rate near the solar ...
Unirradiated cladding rip-propagation tests
International Nuclear Information System (INIS)
Hu, W.L.; Hunter, C.W.
1981-04-01
The size of cladding rips which develop when a fuel pin fails can affect the subassembly cooling and determine how rapidly fuel escapes from the pin. The object of the Cladding Rip Propagation Test (CRPT) was to quantify the failure development of cladding so that a more realistic fuel pin failure modeling may be performed. The test results for unirradiated 20% CS 316 stainless steel cladding show significantly different rip propagation behavior at different temperatures. At room temperature, the rip growth is stable as the rip extension increases monotonically with the applied deformation. At 500 0 C, the rip propagation becomes unstable after a short period of stable rip propagation. The rapid propagation rate is approximately 200 m/s, and the critical rip length is 9 mm. At test temperatures above 850 0 C, the cladding exhibits very high failure resistances, and failure occurs by multiple cracking at high cladding deformation. 13 figures
Modelling the gluon propagator
Energy Technology Data Exchange (ETDEWEB)
Leinweber, D.B.; Parrinello, C.; Skullerud, J.I.; Williams, A.G
1999-03-01
Scaling of the Landau gauge gluon propagator calculated at {beta} = 6.0 and at {beta} = 6.2 is demonstrated. A variety of functional forms for the gluon propagator calculated on a large (32{sup 3} x 64) lattice at {beta} = 6.0 are investigated.
Salomons, E.; Polinder, H.; Lohman, W.; Zhou, H.; Borst, H.
2009-01-01
A new engineering model for sound propagation in cities is presented. The model is based on numerical and experimental studies of sound propagation between street canyons. Multiple reflections in the source canyon and the receiver canyon are taken into account in an efficient way, while weak
Shock propagation in a heterogeneous medium
International Nuclear Information System (INIS)
Elbaz, D.
2011-01-01
In the frame of the inertial confinement fusion in direct drive, the use of foams as ablator allows the reduction of hydrodynamic instabilities created on the target by the direct laser irradiation. The foam is made up of carbon (CH) fibers impregnated of cryogenic deuterium-tritium (DT). In the past, studies have been carried out considering this foam to be a homogeneous medium. Yet, the foam presents heterogeneous features. We study the effects of this heterogeneity on the shock velocity when the laser irradiates the target. Thanks to experimental and numerical studies, we show that the shock propagates faster in the heterogeneous medium than in the homogeneous one with the same averaged density. This velocity gap depends on the presence rate of the CH fibers in the foam, the density ratio, the adiabatic coefficient and the foam geometry. We model the foam by different ways, more and more complex. The shock velocity modification is due to the baroclinicity which, during the interaction between the shock front and the interface, creates a vorticity deposition, responsible for the shock acceleration. Accordingly, an interface, which is plane and perpendicular to the front shock, maximizes the vorticity deposition and increases the velocity gaps between heterogeneous and homogeneous media. We found a correlation between the kinetic energy behind the shock front and the velocities relative difference. We compared our results with two analytical models. However, the system is not closed, so we can't for the moment develop a predictive model. (author) [fr
International Nuclear Information System (INIS)
Böcklin, Christoph; Baumann, Dirk; Fröhlich, Jürg
2014-01-01
A novel way to attain three dimensional fluence rate maps from Monte-Carlo simulations of photon propagation is presented in this work. The propagation of light in a turbid medium is described by the radiative transfer equation and formulated in terms of radiance. For many applications, particularly in biomedical optics, the fluence rate is a more useful quantity and directly derived from the radiance by integrating over all directions. Contrary to the usual way which calculates the fluence rate from absorbed photon power, the fluence rate in this work is directly calculated from the photon packet trajectory. The voxel based algorithm works in arbitrary geometries and material distributions. It is shown that the new algorithm is more efficient and also works in materials with a low or even zero absorption coefficient. The capabilities of the new algorithm are demonstrated on a curved layered structure, where a non-scattering, non-absorbing layer is sandwiched between two highly scattering layers
Radial propagation of microturbulence in tokamaks
International Nuclear Information System (INIS)
Garbet, X.; Laurent, L.; Roubin, J.P.; Samain, A.
1992-01-01
Energy confinement time in tokamaks exhibits a clear dependence on global plasma parameters. This is not the case for transport coefficients; their dependence on local plasma parameters cannot be precisely established. The aim of the present paper is to give a possible explanation of this behaviour; turbulence propagates radially because of departure from cylindrical geometry. This implies that the turbulence level at a given point and hence transport coefficients are not only functions of local plasma parameters. A quantitative estimate of the propagation velocity is derived from a Lagrangian formalism. Two cases are considered: the effect of toroidicity and the effect of non linear mode-mode coupling. The consequences of this model are discussed. This process does not depend on the type of instability. For the sake of simplicity only electrostatic perturbations are considered
Propagating Characteristics of Pulsed Laser in Rain
Directory of Open Access Journals (Sweden)
Jing Guo
2015-01-01
Full Text Available To understand the performance of laser ranging system under the rain weather condition, we need to know the propagating characteristics of laser pulse in rain. In this paper, the absorption and attenuation coefficients were calculated based on the scattering theories in discrete stochastic media, and the propagating characteristics of laser pulse in rain were simulated and analyzed using Monte-Carlo method. Some simulation results were verified by experiments, and the simulation results are well matched with the experimental data, with the maximal deviation not less than 7.5%. The results indicated that the propagating laser beam would be attenuated and distorted due to the scattering and absorption of raindrops, and the energy attenuation and pulse shape distortion strongly depended on the laser pulse widths.
The accuracy of dynamic attitude propagation
Harvie, E.; Chu, D.; Woodard, M.
1990-01-01
Propagating attitude by integrating Euler's equation for rigid body motion has long been suggested for the Earth Radiation Budget Satellite (ERBS) but until now has not been implemented. Because of limited Sun visibility, propagation is necessary for yaw determination. With the deterioration of the gyros, dynamic propagation has become more attractive. Angular rates are derived from integrating Euler's equation with a stepsize of 1 second, using torques computed from telemetered control system data. The environmental torque model was quite basic. It included gravity gradient and unshadowed aerodynamic torques. Knowledge of control torques is critical to the accuracy of dynamic modeling. Due to their coarseness and sparsity, control actuator telemetry were smoothed before integration. The dynamic model was incorporated into existing ERBS attitude determination software. Modeled rates were then used for attitude propagation in the standard ERBS fine-attitude algorithm. In spite of the simplicity of the approach, the dynamically propagated attitude matched the attitude propagated with good gyros well for roll and yaw but diverged up to 3 degrees for pitch because of the very low resolution in pitch momentum wheel telemetry. When control anomalies significantly perturb the nominal attitude, the effect of telemetry granularity is reduced and the dynamically propagated attitudes are accurate on all three axes.
Failure propagation tests and analysis at PNC
International Nuclear Information System (INIS)
Tanabe, H.; Miyake, O.; Daigo, Y.; Sato, M.
1984-01-01
Failure propagation tests have been conducted using the Large Leak Sodium Water Reaction Test Rig (SWAT-1) and the Steam Generator Safety Test Facility (SWAT-3) at PNC in order to establish the safety design of the LMFBR prototype Monju steam generators. Test objectives are to provide data for selecting a design basis leak (DBL), data on the time history of failure propagations, data on the mechanism of the failures, and data on re-use of tubes in the steam generators that have suffered leaks. Eighteen fundamental tests have been performed in an intermediate leak region using the SWAT-1 test rig, and ten failure propagation tests have been conducted in the region from a small leak to a large leak using the SWAT-3 test facility. From the test results it was concluded that a dominant mechanism was tube wastage, and it took more than one minute until each failure propagation occurred. Also, the total leak rate in full sequence simulation tests including a water dump was far less than that of one double-ended-guillotine (DEG) failure. Using such experimental data, a computer code, LEAP (Leak Enlargement and Propagation), has been developed for the purpose of estimating the possible maximum leak rate due to failure propagation. This paper describes the results of the failure propagation tests and the model structure and validation studies of the LEAP code. (author)
Crack Propagation by Finite Element Method
Directory of Open Access Journals (Sweden)
Luiz Carlos H. Ricardo
2018-01-01
Full Text Available Crack propagation simulation began with the development of the finite element method; the analyses were conducted to obtain a basic understanding of the crack growth. Today structural and materials engineers develop structures and materials properties using this technique. The aim of this paper is to verify the effect of different crack propagation rates in determination of crack opening and closing stress of an ASTM specimen under a standard suspension spectrum loading from FDandE SAE Keyhole Specimen Test Load Histories by finite element analysis. To understand the crack propagation processes under variable amplitude loading, retardation effects are observed
Sheshadri, A.; Plumb, R. A.
2017-12-01
The leading "annular mode", defined as the dominant EOF of surface pressure or of zonal mean zonal wind variability, appears as a dipolar structure straddling the mean midlatitude jet and thus seems to describe north-south wobbling of the jet latitude. However, extratropical zonal wind anomalies frequently tend to migrate poleward. This behavior can be described by the first two EOFs, the first (AM1) being the dipolar structure, and the second (AM2) having a tripolar structure centered on the mean jet. Taken in isolation, AM1 thus describes a north-south wobbling of the jet position, while AM2 describes a strengthening and narrowing of the jet. However, despite the fact that they are spatially orthogonal, and their corresponding time series temporally orthogonal, AM1 and AM2 are not independent, but show significant lag-correlations which reveal the propagation. The EOFs are not modes of the underlying dynamical system governing the zonal flow evolution. The true modes can be estimated using principal oscillation pattern (POP) analysis. In the troposphere, the leading POPs manifest themselves as a pair of complex conjugate structures with conjugate eigenvalues thus, in reality, constituting a single, complex, mode that describes propagating anomalies. Even though the principal components associated with the two leading EOFs decay at different rates, each decays faster than the true mode. These facts have implications for eddy feedback and the susceptibility of the mode to external perturbations. If one interprets the annular modes as the modes of the system, then simple theory predicts that the response to steady forcing will usually be dominated by AM1 (with the longest time scale). However, such arguments should really be applied to the true modes. Experiments with a simplified GCM show that climate response to perturbations do not necessarily have AM1 structures. Implications of these results for stratosphere-troposphere interactions are explored. The POP
Spark channel propagation in a microbubble liquid
Energy Technology Data Exchange (ETDEWEB)
Panov, V. A.; Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru; Vetchinin, S. P.; Pecherkin, V. Ya.; Son, E. E. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)
2016-11-15
Experimental study on the development of the spark channel from the anode needle under pulsed electrical breakdown of isopropyl alcohol solution in water with air microbubbles has been performed. The presence of the microbubbles increases the velocity of the spark channel propagation and increases the current in the discharge gap circuit. The observed rate of spark channel propagation in microbubble liquid ranges from 4 to 12 m/s, indicating the thermal mechanism of the spark channel development in a microbubble liquid.
Crack Propagation by Finite Element Method
H. Ricardo, Luiz Carlos
2017-01-01
Crack propagation simulation began with the development of the finite element method; the analyses were conducted to obtain a basic understanding of the crack growth. Today structural and materials engineers develop structures and materials properties using this technique. The aim of this paper is to verify the effect of different crack propagation rates in determination of crack opening and closing stress of an ASTM specimen under a standard suspension spectrum loading from FD&E SAE Keyh...
Propagation in a waveguide with range-dependent seabed properties.
Holland, Charles W
2010-11-01
The ocean environment contains features affecting acoustic propagation that vary on a wide range of time and space scales. A significant body of work over recent decades has aimed at understanding the effects of water column spatial and temporal variability on acoustic propagation. Much less is understood about the impact of spatial variability of seabed properties on propagation, which is the focus of this study. Here, a simple, intuitive expression for propagation with range-dependent boundary properties and uniform water depth is derived. It is shown that incoherent range-dependent propagation depends upon the geometric mean of the seabed plane-wave reflection coefficient and the arithmetic mean of the cycle distance. Thus, only the spatial probability distributions (pdfs) of the sediment properties are required. Also, it is shown that the propagation over a range-dependent seabed tends to be controlled by the lossiest, not the hardest, sediments. Thus, range-dependence generally leads to higher propagation loss than would be expected, due for example to lossy sediment patches and/or nulls in the reflection coefficient. In a few instances, propagation over a range-dependent seabed can be calculated using range-independent sediment properties. The theory may be useful for other (non-oceanic) waveguides.
Database for propagation models
Kantak, Anil V.
1991-07-01
A propagation researcher or a systems engineer who intends to use the results of a propagation experiment is generally faced with various database tasks such as the selection of the computer software, the hardware, and the writing of the programs to pass the data through the models of interest. This task is repeated every time a new experiment is conducted or the same experiment is carried out at a different location generating different data. Thus the users of this data have to spend a considerable portion of their time learning how to implement the computer hardware and the software towards the desired end. This situation may be facilitated considerably if an easily accessible propagation database is created that has all the accepted (standardized) propagation phenomena models approved by the propagation research community. Also, the handling of data will become easier for the user. Such a database construction can only stimulate the growth of the propagation research it if is available to all the researchers, so that the results of the experiment conducted by one researcher can be examined independently by another, without different hardware and software being used. The database may be made flexible so that the researchers need not be confined only to the contents of the database. Another way in which the database may help the researchers is by the fact that they will not have to document the software and hardware tools used in their research since the propagation research community will know the database already. The following sections show a possible database construction, as well as properties of the database for the propagation research.
Attenuation coefficients of soils
International Nuclear Information System (INIS)
Martini, E.; Naziry, M.J.
1989-01-01
As a prerequisite to the interpretation of gamma-spectrometric in situ measurements of activity concentrations of soil radionuclides the attenuation of 60 to 1332 keV gamma radiation by soil samples varying in water content and density has been investigated. A useful empirical equation could be set up to describe the dependence of the mass attenuation coefficient upon photon energy for soil with a mean water content of 10%, with the results comparing well with data in the literature. The mean density of soil in the GDR was estimated at 1.6 g/cm 3 . This value was used to derive the linear attenuation coefficients, their range of variation being 10%. 7 figs., 5 tabs. (author)
Propagation calculation for reactor cases
Energy Technology Data Exchange (ETDEWEB)
Yang Yanhua [School of Power and Energy Engineering, Shanghai Jiao Tong Univ., Shanghai (China); Moriyama, K.; Maruyama, Y.; Nakamura, H.; Hashimoto, K. [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
2000-11-01
The propagation of steam explosion for real reactor geometry and conditions are investigated by using the computer code JASMINE-pro. The ex-vessel steam explosion is considered, which is described as follow: during the accident of reactor core meltdown, the molten core melts a hole at the bottom of reactor vessel and causes the higher temperature core fuel being leaked into the water pool below reactor vessel. During the melt-water mixing interaction process, the high temperature melt evaporates the cool water at an extreme high rate and might induce a steam explosion. A steam explosion could experience first the premixing phase and then the propagation explosion phase. For a propagation calculation, we should know the information about the initial fragmentation time, the total melt mass, premixing region size, initial void fraction and distribution of the melt volume fraction, and so on. All the initial conditions used in this calculation are based on analyses from some simple assumptions and the observation from the experiments. The results show that the most important parameter for the initial condition of this phase is the total mass and its initial distribution. This gives the requirement for a premixing calculation. On the other hand, for higher melt volume fraction case, the fragmentation is strong so that the local pressure can exceed over the EOS maximum pressure of the code, which lead to the incorrect calculation or divergence of the calculation. (Suetake, M.)
International Nuclear Information System (INIS)
Zhao Jia-Sheng; Li Pan; Chen Xiao-Dong; Feng Su-Juan; Mao Qing-He
2012-01-01
The evolutions of the pulses propagating in decreasing and increasing gain distributed fiber amplifiers with finite gain bandwidths are investigated by simulations with the nonlinear Schrödinger equation. The results show that the parabolic pulse propagations in both the decreasing and the increasing gain amplifiers are restricted by the finite gain bandwidth. For a given input pulse, by choosing a small initial gain coefficient and gain variation rate, the whole gain for the pulse amplification limited by the gain bandwidth may be higher, which is helpful for the enhancement of the output linearly chirped pulse energy. Compared to the decreasing gain distributed fiber amplifier, the increasing gain distributed amplifier may be more conducive to suppress the pulse spectral broadening and increase the critical amplifier length for achieving a larger output linearly chirped pulse energy
Nearly perpendicular wave propagation at the fundamental electron-cyclotron resonance
International Nuclear Information System (INIS)
Imre, K.; Weitzner, H.
1985-01-01
Waves propagating nearly perpendicular to the equilibrium magnetic field across the fundamental cyclotron resonance layer are studied by a boundary layer analysis for a weakly relativistic, inhomogeneous Vlasov plasma. The plasma is assumed to be perpendicularly stratified. It is found that the wave energy associated with the ordinary mode transmitted through the layer is independent of the relativistic corrections and is given by a geometrical optics formula. It is also found that there is no reflected energy associated with this mode when it is incident from the high-field side. These results are the same as the nonrelativistic case with purely perpendicular propagation. Relativistic effects produce a significant reduction of the reflection coefficient for low-field side incidence from the nonrelativistic value. Correspondingly, for this mode there is a considerable increase in the absorption rate for sufficiently high, but moderate, electron density and temperature
Heat transfer coefficient of cryotop during freezing.
Li, W J; Zhou, X L; Wang, H S; Liu, B L; Dai, J J
2013-01-01
Cryotop is an efficient vitrification method for cryopreservation of oocytes. It has been widely used owing to its simple operation and high freezing rate. Recently, the heat transfer performance of cryotop was studied by numerical simulation in several studies. However, the range of heat transfer coefficient in the simulation is uncertain. In this study, the heat transfer coefficient for cryotop during freezing process was analyzed. The cooling rates of 40 percent ethylene glycol (EG) droplet in cryotop during freezing were measured by ultra-fast measurement system and calculated by numerical simulation at different value of heat transfer coefficient. Compared with the results obtained by two methods, the range of the heat transfer coefficient necessary for the numerical simulation of cryotop was determined, which is between 9000 W/(m(2)·K) and 10000 W/(m (2)·K).
Approximate reflection coefficients for a thin VTI layer
Hao, Qi
2017-09-18
We present an approximate method to derive simple expressions for the reflection coefficients of P- and SV-waves for a thin transversely isotropic layer with a vertical symmetry axis (VTI) embedded in a homogeneous VTI background. The layer thickness is assumed to be much smaller than the wavelengths of P- and SV-waves inside. The exact reflection and transmission coefficients are derived by the propagator matrix method. In the case of normal incidence, the exact reflection and transmission coefficients are expressed in terms of the impedances of vertically propagating P- and S-waves. For subcritical incidence, the approximate reflection coefficients are expressed in terms of the contrast in the VTI parameters between the layer and the background. Numerical examples are designed to analyze the reflection coefficients at normal and oblique incidence, and investigate the influence of transverse isotropy on the reflection coefficients. Despite giving numerical errors, the approximate formulae are sufficiently simple to qualitatively analyze the variation of the reflection coefficients with the angle of incidence.
The Truth About Ballistic Coefficients
Courtney, Michael; Courtney, Amy
2007-01-01
The ballistic coefficient of a bullet describes how it slows in flight due to air resistance. This article presents experimental determinations of ballistic coefficients showing that the majority of bullets tested have their previously published ballistic coefficients exaggerated from 5-25% by the bullet manufacturers. These exaggerated ballistic coefficients lead to inaccurate predictions of long range bullet drop, retained energy and wind drift.
Multispecimen fatigue crack propagation testing
International Nuclear Information System (INIS)
Ermi, A.M.; Bauer, R.E.; Chin, B.A.; Straalsund, J.L.
1981-01-01
Chains of miniature center-cracked-tension specimens were tested on a conventional testing machine and on a prototypic in-reactor fatigue machine as part of the fusion reactor materials alloy development program. Annealed and 20 percent cold-worked 316 stainless steel specimens were cycled under various conditions of temperature, frequency, stress ratio and chain length. Crack growth rates determined from multispecimen visual measurements and from an electrical potential technique were consistent with those obtained by conventional test methods. Results demonstrate that multispecimen chain testing is a valid method of obtaining fatigue crack propagation information for alloy development. 8 refs
Czech Academy of Sciences Publication Activity Database
McCleskey, M.; Mukhamedzhanov, A. M.; Trache, L.; Tribble, R. E.; Banu, A.; Eremenko, V.; Goldberg, V. Z.; Lui, Y. W.; McCleskey, E.; Roeder, B. T.; Spiridon, A.; Carstoiu, F.; Burjan, Václav; Hons, Zdeněk; Thompson, I. J.
2014-01-01
Roč. 89, č. 4 (2014), 044605 ISSN 0556-2813 R&D Projects: GA MŠk(CZ) LH11001 Institutional support: RVO:61389005 Keywords : capture reactions * cross-section * asymptotic normalization coefficient Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 3.733, year: 2014
Non-perturbative power corrections to ghost and gluon propagators
International Nuclear Information System (INIS)
Boucaud, Philippe; Leroy, Jean-Pierre; Yaouanc, Alain Le; Lokhov, Alexey; Micheli, Jacques; Pene, Olivier; RodrIguez-Quintero, Jose; Roiesnel, Claude
2006-01-01
We study the dominant non-perturbative power corrections to the ghost and gluon propagators in Landau gauge pure Yang-Mills theory using OPE and lattice simulations. The leading order Wilson coefficients are proven to be the same for both propagators. The ratio of the ghost and gluon propagators is thus free from this dominant power correction. Indeed, a purely perturbative fit of this ratio gives smaller value ( ≅ 270MeV) of Λ M-barS-bar than the one obtained from the propagators separately( ≅ 320MeV). This argues in favour of significant non-perturbative ∼ 1/q 2 power corrections in the ghost and gluon propagators. We check the self-consistency of the method
David, P
2013-01-01
Propagation of Waves focuses on the wave propagation around the earth, which is influenced by its curvature, surface irregularities, and by passage through atmospheric layers that may be refracting, absorbing, or ionized. This book begins by outlining the behavior of waves in the various media and at their interfaces, which simplifies the basic phenomena, such as absorption, refraction, reflection, and interference. Applications to the case of the terrestrial sphere are also discussed as a natural generalization. Following the deliberation on the diffraction of the "ground? wave around the ear
Propagation environments [Chapter 4
Douglass F. Jacobs; Thomas D. Landis; Tara Luna
2009-01-01
An understanding of all factors influencing plant growth in a nursery environment is needed for the successful growth and production of high-quality container plants. Propagation structures modify the atmospheric conditions of temperature, light, and relative humidity. Native plant nurseries are different from typical horticultural nurseries because plants must be...
Uncertainty Propagation in OMFIT
Smith, Sterling; Meneghini, Orso; Sung, Choongki
2017-10-01
A rigorous comparison of power balance fluxes and turbulent model fluxes requires the propagation of uncertainties in the kinetic profiles and their derivatives. Making extensive use of the python uncertainties package, the OMFIT framework has been used to propagate covariant uncertainties to provide an uncertainty in the power balance calculation from the ONETWO code, as well as through the turbulent fluxes calculated by the TGLF code. The covariant uncertainties arise from fitting 1D (constant on flux surface) density and temperature profiles and associated random errors with parameterized functions such as a modified tanh. The power balance and model fluxes can then be compared with quantification of the uncertainties. No effort is made at propagating systematic errors. A case study will be shown for the effects of resonant magnetic perturbations on the kinetic profiles and fluxes at the top of the pedestal. A separate attempt at modeling the random errors with Monte Carlo sampling will be compared to the method of propagating the fitting function parameter covariant uncertainties. Work supported by US DOE under DE-FC02-04ER54698, DE-FG2-95ER-54309, DE-SC 0012656.
International Nuclear Information System (INIS)
Dvoeglazov, V.V.
1997-01-01
An analog of the j = 1/2 Feynman-Dyson propagator is presented in the framework of the j = 1 Weinberg's theory. The basis for this construction is the concept of the Weinberg field as a system of four field functions differing by parity and by dual transformations. (orig.)
Czech Academy of Sciences Publication Activity Database
Schejbal, V.; Bezoušek, P.; Čermák, D.; NĚMEC, Z.; Fišer, Ondřej; Hájek, M.
2006-01-01
Roč. 15, č. 1 (2006), s. 17-24 ISSN 1210-2512 R&D Projects: GA MPO(CZ) FT-TA2/030 Institutional research plan: CEZ:AV0Z30420517 Keywords : Ultra wide band * UWB antennas * UWB propagation * multipath effects Subject RIV: JB - Sensors, Measurment, Regulation
National Research Council Canada - National Science Library
Gray, William
1994-01-01
This paper discusses the question of tropical cyclone propagation or why the average tropical cyclone moves 1-2 m/s faster and usually 10-20 deg to the left of its surrounding (or 5-7 deg radius) deep layer (850-300 mb) steering current...
International Nuclear Information System (INIS)
Tsuji, Masashi; Aoki, Yukinori; Shimazu, Yoichiro; Yamasaki, Masatoshi; Hanayama, Yasushi
2006-01-01
A method to evaluate the moderator coefficient (MTC) and the Doppler coefficient through experimental procedures performed during reactor physics tests of PWR power plants is proposed. This method combines isothermal temperature coefficient (ITC) measurement experiments and reactor power transient experiments at low power conditions for dynamic identification. In the dynamic identification, either one of temperature coefficients can be determined in such a way that frequency response characteristics of the reactivity change observed by a digital reactivity meter is reproduced from measured data of neutron count rate and the average coolant temperature. The other unknown coefficient can also be determined by subtracting the coefficient obtained from the dynamic identification from ITC. As the proposed method can directly estimate the Doppler coefficient, the applicability of the conventional core design codes to predict the Doppler coefficient can be verified for new types of fuels such as mixed oxide fuels. The digital simulation study was carried out to show the feasibility of the proposed method. The numerical analysis showed that the MTC and the Doppler coefficient can be estimated accurately and even if there are uncertainties in the parameters of the reactor kinetics model, the accuracies of the estimated values are not seriously impaired. (author)
On the Kendall Correlation Coefficient
Stepanov, Alexei
2015-01-01
In the present paper, we first discuss the Kendall rank correlation coefficient. In continuous case, we define the Kendall rank correlation coefficient in terms of the concomitants of order statistics, find the expected value of the Kendall rank correlation coefficient and show that the later is free of n. We also prove that in continuous case the Kendall correlation coefficient converges in probability to its expected value. We then propose to consider the expected value of the Kendall rank ...
International Nuclear Information System (INIS)
Babaeva, Natalia Yu; Kushner, Mark J
2009-01-01
The branching of electric discharge streamers in atmospheric pressure air, dense gases and liquids is a common occurrence whose origins are likely found with many causes, both deterministic and stochastic. One mechanism for streamer branching may be inhomogeneities in the path of a streamer which either divert the streamer (typically a region of lower ionization) or produce a new branch (a region of higher ionization). The propagation and branching of streamers in liquids is likely aided by low density inhomogeneities, bubbles; however, modeling of streamers in liquids is made difficult by the lack of transport coefficients. As a first step towards understanding the propagation and branching of streamers in liquids, we investigated the consequences of random inhomogeneities in the form of low pressure bubbles on the propagation of streamers in high pressure humid air. By virtue of their lower density, bubbles have larger E/N (electric field/gas number density) than the ambient gas with larger rates of ionization. The intersection of a streamer with a bubble will focus the plasma into the bubble by virtue of that higher rate of ionization but the details of the interaction depend on the relative sizes of the bubble and streamer. When a streamer intersects a field of bubbles, the large E/N in the bubble avalanches seed electrons produced by photoionization from the streamer. Each bubble then launches both a negative and positive going streamer that may link with those from adjacent bubbles or the original streamer. The total process then appears as streamer branching.
Propagator of stochastic electrodynamics
International Nuclear Information System (INIS)
Cavalleri, G.
1981-01-01
The ''elementary propagator'' for the position of a free charged particle subject to the zero-point electromagnetic field with Lorentz-invariant spectral density proportionalω 3 is obtained. The nonstationary process for the position is solved by the stationary process for the acceleration. The dispersion of the position elementary propagator is compared with that of quantum electrodynamics. Finally, the evolution of the probability density is obtained starting from an initial distribution confined in a small volume and with a Gaussian distribution in the velocities. The resulting probability density for the position turns out to be equal, to within radiative corrections, to psipsi* where psi is the Kennard wave packet. If the radiative corrections are retained, the present result is new since the corresponding expression in quantum electrodynamics has not yet been found. Besides preceding quantum electrodynamics for this problem, no renormalization is required in stochastic electrodynamics
Preventing Unofficial Information Propagation
Le, Zhengyi; Ouyang, Yi; Xu, Yurong; Ford, James; Makedon, Fillia
Digital copies are susceptible to theft and vulnerable to leakage, copying, or manipulation. When someone (or some group), who has stolen, leaked, copied, or manipulated digital documents propagates the documents over the Internet and/or distributes those through physical distribution channels many challenges arise which document holders must overcome in order to mitigate the impact to their privacy or business. This paper focuses on the propagation problem of digital credentials, which may contain sensitive information about a credential holder. Existing work such as access control policies and the Platform for Privacy Preferences (P3P) assumes that qualified or certified credential viewers are honest and reliable. The proposed approach in this paper uses short-lived credentials based on reverse forward secure signatures to remove this assumption and mitigate the damage caused by a dishonest or honest but compromised viewer.
Adaptive digital back-propagation for optical communication systems
Lin, C.-Y.; Napoli, A.; Spinnler, B.; Sleiffer, V.A.J.M.; Rafique, D.; Kuschnerov, M.; Bohn, M.; Schmauss, B.
2014-01-01
We propose an adaptive digital back-propagation method (A-DBP) to selfdetermine unknown fiber nonlinear coefficient gamma. Performance is experimentally verified with 10224-Gb/s POLMUX-16QAM over 656km. Optimal DBP performance, without knowledge of gamma, is obtained by A-DBP.
Recombination and propagation of quasiparticles in cuprate superconductors
International Nuclear Information System (INIS)
Gedik, Nuh
2004-01-01
Rapid developments in time-resolved optical spectroscopy have led to renewed interest in the nonequilibrium state of superconductors and other highly correlated electron materials. In these experiments, the nonequilibrium state is prepared by the absorption of short (less than 100 fs) laser pulses, typically in the near-infrared, that perturb the density and energy distribution of quasiparticles. The evolution of the nonequilibrium state is probed by time resolving the changes in the optical response functions of the medium that take place after photoexcitation. Ultimately, the goal of such experiments is to understand not only the nonequilibrium state, but to shed light on the still poorly understood equilibrium properties of these materials. We report nonequilibrium experiments that have revealed aspects of the cup rates that have been inaccessible by other techniques. Namely, the diffusion and recombination coefficients of quasiparticles have been measured in both YBa 2 Cu 3 O 6.5 and Bi 2 Sr 2 CaCu 2 O 8+x using time-resolved optical spectroscopy. Dependence of these measurements on doping, temperature and laser intensity is also obtained. To study the recombination of quasiparticles, we measure the change in reflectivity ΔR which is directly proportional to the nonequilibrium quasiparticle density created by the laser. From the intensity dependence, we estimate β, the inelastic scattering coefficient and γ th thermal equilibrium quasiparticle decay rate. We also present the dependence of recombination measurements on doping in Bi 2 Sr 2 CaCu 2 O 8+x . Going from underdoped to overdoped regime, the sign of ΔR changes from positive to negative right at the optimal doping. This is accompanied by a change in dynamics. The decay of ΔR stops being intensity dependent exactly at the optimal doping. We provide possible interpretations of these two observations. To study the propagation of quasiparticles, we interfered two laser pulses to introduce a spatially
Stress Wave Propagation in Viscoelastic-Plastic Rock-Like Materials
Directory of Open Access Journals (Sweden)
Liu Lang
2016-05-01
Full Text Available Rock-like materials are composites that can be regarded as a mixture composed of elastic, plastic, and viscous components. They exhibit viscoelastic-plastic behavior under a high-strain-rate loading according to element model theory. This paper presents an analytical solution for stress wave propagation in viscoelastic-plastic rock-like materials under a high-strain-rate loading and verifies the solution through an experimental test. A constitutive equation of viscoelastic-plastic rock-like materials was first established, and then kinematic and kinetic equations were then solved to derive the analytic solution for stress wave propagation in viscoelastic-plastic rock-like materials. An experimental test using the SHPB (Split Hopkinson Pressure Bar for a concrete specimen was conducted to obtain a stress-strain curve under a high-strain-rate loading. Inverse analysis based on differential evolution was conducted to estimate undetermined variables for constitutive equations. Finally, the relationship between the attenuation factor and the strain rate in viscoelastic-plastic rock-like materials was investigated. According to the results, the frequency of the stress wave, viscosity coefficient, modulus of elasticity, and density play dominant roles in the attenuation of the stress wave. The attenuation decreases with increasing strain rate, demonstrating strongly strain-dependent attenuation in viscoelastic-plastic rock-like materials.
Intraband effects on ultrafast pulse propagation in semiconductor ...
Indian Academy of Sciences (India)
High bit-rate (>10 Gb/s) signals are composed of very short pulses and propagation of such pulses through a semiconductor optical amplifier (SOA) requires consideration of intraband phenomena. Due to the intraband effects, the propagating pulse sees a fast recovering nonlinear gain which introduces less distortion in the ...
Influence of Sea Surface Roughness on the Electromagnetic Wave Propagation in the Duct Environment
Zhao, X.; Huang, S.
2010-01-01
This paper deals with a study of the influence of sea surface roughness on the electromagnetic wave propagation in the duct environment. The problem of electromagnetic wave propagation is modeled by using the parabolic equation method. The roughness of the sea surface is computed by modifying the smooth surface Fresnel reflection coefficient to account for the reduction in the specular reflection due to the roughness resulting from sea wind speed. The propagation model is solved by the mixed ...
The effect of lower-hybrid waves on the propagation of hydromagnetic waves
International Nuclear Information System (INIS)
Hamabata, Hiromitsu; Namikawa, Tomikazu; Mori, Kazuhiro
1988-01-01
Propagation characteristics of hydromagnetic waves in a magnetic plasma are investigated using the two-plasma fluid equations including the effect of lower-hybrid waves propagating perpendicularly to the magnetic field. The effect of lower-hybrid waves on the propagation of hydromagnetic waves is analysed in terms of phase speed, growth rate, refractive index, polarization and the amplitude relation between the density perturbation and the magnetic-field perturbation for the cases when hydromagnetic waves propagate in the plane whose normal is perpendicular to both the magnetic field and the propagation direction of lower-hybrid waves and in the plane perpendicular to the propagation direction of lower-hybrid waves. It is shown that hydromagnetic waves propagating at small angles to the propagation direction of lower-hybrid waves can be excited by the effect of lower-hybrid waves and the energy of excited waves propagates nearly parallel to the propagation direction of lower-hybrid waves. (author)
Wave propagation in elastic solids
Achenbach, Jan
1984-01-01
The propagation of mechanical disturbances in solids is of interest in many branches of the physical scienses and engineering. This book aims to present an account of the theory of wave propagation in elastic solids. The material is arranged to present an exposition of the basic concepts of mechanical wave propagation within a one-dimensional setting and a discussion of formal aspects of elastodynamic theory in three dimensions, followed by chapters expounding on typical wave propagation phenomena, such as radiation, reflection, refraction, propagation in waveguides, and diffraction. The treat
Front propagation in flipping processes
International Nuclear Information System (INIS)
Antal, T; Ben-Avraham, D; Ben-Naim, E; Krapivsky, P L
2008-01-01
We study a directed flipping process that underlies the performance of the random edge simplex algorithm. In this stochastic process, which takes place on a one-dimensional lattice whose sites may be either occupied or vacant, occupied sites become vacant at a constant rate and simultaneously cause all sites to the right to change their state. This random process exhibits rich phenomenology. First, there is a front, defined by the position of the leftmost occupied site, that propagates at a nontrivial velocity. Second, the front involves a depletion zone with an excess of vacant sites. The total excess Δ k increases logarithmically, Δ k ≅ ln k, with the distance k from the front. Third, the front exhibits ageing-young fronts are vigorous but old fronts are sluggish. We investigate these phenomena using a quasi-static approximation, direct solutions of small systems and numerical simulations
Does the third mutual friction coefficient B'' exist
International Nuclear Information System (INIS)
Mathieu, P.; Placais, B.; Simon, Y.
1985-01-01
Precise measurements of the attenuation of a second-sound wave propagation axially in rotating He II at first sight suggest that the third mutual-friction coefficient B'' has a non-zero value (B'' = 0.021 at 1.9 K). But the observation of metastable states associated with various levels of attenuation is not reconcilable with the semi-classical model of the vortex line [fr
Quadrature formulas for Fourier coefficients
Bojanov, Borislav
2009-09-01
We consider quadrature formulas of high degree of precision for the computation of the Fourier coefficients in expansions of functions with respect to a system of orthogonal polynomials. In particular, we show the uniqueness of a multiple node formula for the Fourier-Tchebycheff coefficients given by Micchelli and Sharma and construct new Gaussian formulas for the Fourier coefficients of a function, based on the values of the function and its derivatives. © 2009 Elsevier B.V. All rights reserved.
Coefficient Alpha: A Reliability Coefficient for the 21st Century?
Yang, Yanyun; Green, Samuel B.
2011-01-01
Coefficient alpha is almost universally applied to assess reliability of scales in psychology. We argue that researchers should consider alternatives to coefficient alpha. Our preference is for structural equation modeling (SEM) estimates of reliability because they are informative and allow for an empirical evaluation of the assumptions…
Coefficient estimates of negative powers and inverse coefficients for ...
Indian Academy of Sciences (India)
and the inequality is sharp for the inverse of the Koebe function k(z) = z/(1 − z)2. An alternative approach to the inverse coefficient problem for functions in the class S has been investigated by Schaeffer and Spencer [27] and FitzGerald [6]. Although, the inverse coefficient problem for the class S has been completely solved ...
Measuring of heat transfer coefficient
DEFF Research Database (Denmark)
Henningsen, Poul; Lindegren, Maria
Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...
Wave propagation in spatially modulated tubes
Energy Technology Data Exchange (ETDEWEB)
Ziepke, A., E-mail: ziepke@itp.tu-berlin.de; Martens, S.; Engel, H. [Institut für Theoretische Physik, Hardenbergstraße 36, EW 7-1, Technische Universität Berlin, 10623 Berlin (Germany)
2016-09-07
We investigate wave propagation in rotationally symmetric tubes with a periodic spatial modulation of cross section. Using an asymptotic perturbation analysis, the governing quasi-two-dimensional reaction-diffusion equation can be reduced into a one-dimensional reaction-diffusion-advection equation. Assuming a weak perturbation by the advection term and using projection method, in a second step, an equation of motion for traveling waves within such tubes can be derived. Both methods predict properly the nonlinear dependence of the propagation velocity on the ratio of the modulation period of the geometry to the intrinsic width of the front, or pulse. As a main feature, we observe finite intervals of propagation failure of waves induced by the tube’s modulation and derive an analytically tractable condition for their occurrence. For the highly diffusive limit, using the Fick-Jacobs approach, we show that wave velocities within modulated tubes are governed by an effective diffusion coefficient. Furthermore, we discuss the effects of a single bottleneck on the period of pulse trains. We observe period changes by integer fractions dependent on the bottleneck width and the period of the entering pulse train.
Curvature of Indoor Sensor Network: Clustering Coefficient
Directory of Open Access Journals (Sweden)
2009-03-01
Full Text Available We investigate the geometric properties of the communication graph in realistic low-power wireless networks. In particular, we explore the concept of the curvature of a wireless network via the clustering coefficient. Clustering coefficient analysis is a computationally simplified, semilocal approach, which nevertheless captures such a large-scale feature as congestion in the underlying network. The clustering coefficient concept is applied to three cases of indoor sensor networks, under varying thresholds on the link packet reception rate (PRR. A transition from positive curvature (“meshed” network to negative curvature (“core concentric” network is observed by increasing the threshold. Even though this paper deals with network curvature per se, we nevertheless expand on the underlying congestion motivation, propose several new concepts (network inertia and centroid, and finally we argue that greedy routing on a virtual positively curved network achieves load balancing on the physical network.
Keefe, Laurence
2016-11-01
Parabolized acoustic propagation in transversely inhomogeneous media is described by the operator update equation U (x , y , z + Δz) =eik0 (- 1 +√{ 1 + Z }) U (x , y , z) for evolution of the envelope of a wavetrain solution to the original Helmholtz equation. Here the operator, Z =∇T2 + (n2 - 1) , involves the transverse Laplacian and the refractive index distribution. Standard expansion techniques (on the assumption Z << 1)) produce pdes that approximate, to greater or lesser extent, the full dispersion relation of the original Helmholtz equation, except that none of them describe evanescent/damped waves without special modifications to the expansion coefficients. Alternatively, a discretization of both the envelope and the operator converts the operator update equation into a matrix multiply, and existing theorems on matrix functions demonstrate that the complete (discrete) Helmholtz dispersion relation, including evanescent/damped waves, is preserved by this discretization. Propagation-constant/damping-rates contour comparisons for the operator equation and various approximations demonstrate this point, and how poorly the lowest-order, textbook, parabolized equation describes propagation in lined ducts.
Lattice cell diffusion coefficients. Definitions and comparisons
International Nuclear Information System (INIS)
Hughes, R.P.
1980-01-01
Definitions of equivalent diffusion coefficients for regular lattices of heterogeneous cells have been given by several authors. The paper begins by reviewing these different definitions and the unification of their derivation. This unification makes clear how accurately each definition (together with appropriate cross-section definitions to preserve the eigenvalue) represents the individual reaction rates within the cell. The approach can be extended to include asymmetric cells and whereas before, the buckling describing the macroscopic flux shape was real, here it is found to be complex. A neutron ''drift'' coefficient as well as a diffusion coefficient is necessary to produce the macroscopic flux shape. The numerical calculation of the various different diffusion coefficients requires the solutions of equations similar to the ordinary transport equation for an infinite lattice. Traditional reactor physics codes are not sufficiently flexible to solve these equations in general. However, calculations in certain simple cases are presented and the theoretical results quantified. In difficult geometries, Monte Carlo techniques can be used to calculate an effective diffusion coefficient. These methods relate to those already described provided that correlation effects between different generations of neutrons are included. Again, these effects are quantified in certain simple cases. (author)
Modeling laser beam diffraction and propagation by the mode-expansion method.
Snyder, James J
2007-08-01
In the mode-expansion method for modeling propagation of a diffracted beam, the beam at the aperture can be expanded as a weighted set of orthogonal modes. The parameters of the expansion modes are chosen to maximize the weighting coefficient of the lowest-order mode. As the beam propagates, its field distribution can be reconstructed from the set of weighting coefficients and the Gouy phase of the lowest-order mode. We have developed a simple procedure to implement the mode-expansion method for propagation through an arbitrary ABCD matrix, and we have demonstrated that it is accurate in comparison with direct calculations of diffraction integrals and much faster.
Wave propagation in elastic medium with heterogeneous quadratic nonlinearity
International Nuclear Information System (INIS)
Tang Guangxin; Jacobs, Laurence J.; Qu Jianmin
2011-01-01
This paper studies the one-dimensional wave propagation in an elastic medium with spatially non-uniform quadratic nonlinearity. Two problems are solved analytically. One is for a time-harmonic wave propagating in a half-space where the displacement is prescribed on the surface of the half-space. It is found that spatial non-uniformity of the material nonlinearity causes backscattering of the second order harmonic, which when combined with the forward propagating waves generates a standing wave in steady-state wave motion. The second problem solved is the reflection from and transmission through a layer of finite thickness embedded in an otherwise linearly elastic medium of infinite extent, where it is assumed that the layer has a spatially non-uniform quadratic nonlinearity. The results show that the transmission coefficient for the second order harmonic is proportional to the spatial average of the nonlinearity across the thickness of the layer, independent of the spatial distribution of the nonlinearity. On the other hand, the coefficient of reflection is proportional to a weighted average of the nonlinearity across the layer thickness. The weight function in this weighted average is related to the propagating phase, thus making the coefficient of reflection dependent on the spatial distribution of the nonlinearity. Finally, the paper concludes with some discussions on how to use the reflected and transmitted second harmonic waves to evaluate the variance and autocorrelation length of nonlinear parameter β when the nonlinearity distribution in the layer is a stochastic process.
Propagators and path integrals
Energy Technology Data Exchange (ETDEWEB)
Holten, J.W. van
1995-08-22
Path-integral expressions for one-particle propagators in scalar and fermionic field theories are derived, for arbitrary mass. This establishes a direct connection between field theory and specific classical point-particle models. The role of world-line reparametrization invariance of the classical action and the implementation of the corresponding BRST-symmetry in the quantum theory are discussed. The presence of classical world-line supersymmetry is shown to lead to an unwanted doubling of states for massive spin-1/2 particles. The origin of this phenomenon is traced to a `hidden` topological fermionic excitation. A different formulation of the pseudo-classical mechanics using a bosonic representation of {gamma}{sub 5} is shown to remove these extra states at the expense of losing manifest supersymmetry. (orig.).
Curvilinear crack layer propagation
Chudnovsky, Alexander; Chaoui, Kamel; Moet, Abdelsamie
1987-01-01
An account is given of an experiment designed to allow observation of the effect of damage orientation on the direction of crack growth in the case of crack layer propagation, using polystyrene as the model material. The direction of crack advance under a given loading condition is noted to be determined by a competition between the tendency of the crack to maintain its current direction and the tendency to follow the orientation of the crazes at its tip. The orientation of the crazes is, on the other hand, determined by the stress field due to the interaction of the crack, the crazes, and the hole. The changes in craze rotation relative to the crack define the active zone rotation.
Atomistics of crack propagation
International Nuclear Information System (INIS)
Sieradzki, K.; Dienes, G.J.; Paskin, A.; Massoumzadeh, B.
1988-01-01
The molecular dynamic technique is used to investigate static and dynamic aspects of crack extension. The material chosen for this study was the 2D triangular solid with atoms interacting via the Johnson potential. The 2D Johnson solid was chosen for this study since a sharp crack in this material remains stable against dislocation emission up to the critical Griffith load. This behavior allows for a meaningful comparison between the simulation results and continuum energy theorems for crack extension by appropriately defining an effective modulus which accounts for sample size effects and the non-linear elastic behavior of the Johnson solid. Simulation results are presented for the stress fields of moving cracks and these dynamic results are discussed in terms of the dynamic crack propagation theories, of Mott, Eshelby, and Freund
Broadband unidirectional ultrasound propagation
Sinha, Dipen N.; Pantea, Cristian
2017-12-12
A passive, linear arrangement of a sonic crystal-based apparatus and method including a 1D sonic crystal, a nonlinear medium, and an acoustic low-pass filter, for permitting unidirectional broadband ultrasound propagation as a collimated beam for underwater, air or other fluid communication, are described. The signal to be transmitted is first used to modulate a high-frequency ultrasonic carrier wave which is directed into the sonic crystal side of the apparatus. The apparatus processes the modulated signal, whereby the original low-frequency signal exits the apparatus as a collimated beam on the side of the apparatus opposite the sonic crystal. The sonic crystal provides a bandpass acoustic filter through which the modulated high-frequency ultrasonic signal passes, and the nonlinear medium demodulates the modulated signal and recovers the low-frequency sound beam. The low-pass filter removes remaining high-frequency components, and contributes to the unidirectional property of the apparatus.
Propagation into an unstable state
International Nuclear Information System (INIS)
Dee, G.
1985-01-01
We describe propagating front solutions of the equations of motion of pattern-forming systems. We make a number of conjectures concerning the properties of such fronts in connection with pattern selection in these systems. We describe a calculation which can be used to calculate the velocity and state selected by certain types of propagating fronts. We investigate the propagating front solutions of the amplitude equation which provides a valid dynamical description of many pattern-forming systems near onset
Analytical Lie-algebraic solution of a 3D sound propagation problem in the ocean
Energy Technology Data Exchange (ETDEWEB)
Petrov, P.S., E-mail: petrov@poi.dvo.ru [Il' ichev Pacific Oceanological Institute, 43 Baltiyskaya str., Vladivostok, 690041 (Russian Federation); Prants, S.V., E-mail: prants@poi.dvo.ru [Il' ichev Pacific Oceanological Institute, 43 Baltiyskaya str., Vladivostok, 690041 (Russian Federation); Petrova, T.N., E-mail: petrova.tn@dvfu.ru [Far Eastern Federal University, 8 Sukhanova str., 690950, Vladivostok (Russian Federation)
2017-06-21
The problem of sound propagation in a shallow sea with variable bottom slope is considered. The sound pressure field produced by a time-harmonic point source in such inhomogeneous 3D waveguide is expressed in the form of a modal expansion. The expansion coefficients are computed using the adiabatic mode parabolic equation theory. The mode parabolic equations are solved explicitly, and the analytical expressions for the modal coefficients are obtained using a Lie-algebraic technique. - Highlights: • A group-theoretical approach is applied to a problem of sound propagation in a shallow sea with variable bottom slope. • An analytical solution of this problem is obtained in the form of modal expansion with analytical expressions of the coefficients. • Our result is the only analytical solution of the 3D sound propagation problem with no translational invariance. • This solution can be used for the validation of the numerical propagation models.
Contribution to the study of neutron propagation in cavities
International Nuclear Information System (INIS)
Hasselin, G.
1965-01-01
In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [fr
Sabine absorption coefficients to random incidence absorption coefficients
DEFF Research Database (Denmark)
Jeong, Cheol-Ho
2014-01-01
into random incidence absorption coefficients for porous absorbers are investigated. Two optimization-based conversion methods are suggested: the surface impedance estimation for locally reacting absorbers and the flow resistivity estimation for extendedly reacting absorbers. The suggested conversion methods...
Induration and Biot’s Coefficient of Palaeogene Limestone
DEFF Research Database (Denmark)
Andreassen, Katrine Alling
2017-01-01
In engineering geology and classification of rock masses for civil engineering purposes, the degree of induration for a rock serves as a useful classification parameter. Induration is a measure of how well the grains of a sedimentary rock are cemented together - from loosely cemented/soft rock...... to very competent/slightly metamorphic rock. The Biot coefficient links to the degree of cementation in the capacity of how it relates the elastic deformations with the change in pore pressure. A hypothesis is that the degree of induration could be correlated to the magnitude of the Biot coefficient....... This is tested on 11 Copenhagen Limestone specimens of varying porosity and densities obtained from one borehole with a limestone interval of 30 m. Their induration varies from H2 to H5. Elastic wave propagation measurements are used to establish the Biot coefficient and determination of the mineralogy for H5...
Harmonic surface wave propagation in plasma
International Nuclear Information System (INIS)
Shivarova, A.; Stoychev, T.
1980-01-01
Second order harmonic surface waves generated by one fundamental high-frequency surface wave are investigated experimentally in gas discharge plasma. Two types of harmonic waves of equal frequency, associated with the linear dispersion relation and the synchronism conditions relatively propagate. The experimental conditions and the different space damping rates of the waves ensure the existence of different spatial regions (consecutively arranged along the plasma column) of a dominant propagation of each one of these two waves. Experimental data are obtained both for the wavenumbers and the space damping rates by relatively precise methods for wave investigations such as the methods of time-space diagrams and of phase shift measurements. The results are explained by the theoretical model for nonlinear mixing of dispersive waves. (author)
Probabilistic optimization of safety coefficients
International Nuclear Information System (INIS)
Marques, M.; Devictor, N.; Magistris, F. de
1999-01-01
This article describes a reliability-based method for the optimization of safety coefficients defined and used in design codes. The purpose of the optimization is to determine the partial safety coefficients which minimize an objective function for sets of components and loading situations covered by a design rule. This objective function is a sum of distances between the reliability of the components designed using the safety coefficients and a target reliability. The advantage of this method is shown on the examples of the reactor vessel, a vapour pipe and the safety injection circuit. (authors)
An Immunization Strategy Based on Propagation Mechanism
Directory of Open Access Journals (Sweden)
Yixin Zhu
2014-01-01
Full Text Available With the ubiquity of smart phones, wearable equipment, and wireless sensors, the topologies of networks composed by them change along with time. The immunization strategies in which network immune nodes are chosen by analyzing the static aggregation network topologies have been challenged. The studies about interaction propagations between two pathogens show that the interaction can change propagation threshold and the final epidemic size of each other, which provides a new thinking of immunization method. The eradication or inhibition of the virus can be achieved through the spread of its opposite party. Here, we put forward an immunization strategy whose implementation does not depend on the analysis of network topology. The immunization agents are randomly placed on a few of individuals of network and spread out from these individuals on network in a propagation method. The immunization agents prevent virus infecting their habitat nodes with certain immune success rate. The analysis and simulation of evolution equation of the model show that immune propagation has a significant impact on the spread threshold and steady-state density of virus on a finite size of BA networks. Simulations on some real-world networks also suggest that the immunization strategy is feasible and effective.
Network-based analysis of software change propagation.
Wang, Rongcun; Huang, Rubing; Qu, Binbin
2014-01-01
The object-oriented software systems frequently evolve to meet new change requirements. Understanding the characteristics of changes aids testers and system designers to improve the quality of softwares. Identifying important modules becomes a key issue in the process of evolution. In this context, a novel network-based approach is proposed to comprehensively investigate change distributions and the correlation between centrality measures and the scope of change propagation. First, software dependency networks are constructed at class level. And then, the number of times of cochanges among classes is minded from software repositories. According to the dependency relationships and the number of times of cochanges among classes, the scope of change propagation is calculated. Using Spearman rank correlation analyzes the correlation between centrality measures and the scope of change propagation. Three case studies on java open source software projects Findbugs, Hibernate, and Spring are conducted to research the characteristics of change propagation. Experimental results show that (i) change distribution is very uneven; (ii) PageRank, Degree, and CIRank are significantly correlated to the scope of change propagation. Particularly, CIRank shows higher correlation coefficient, which suggests it can be a more useful indicator for measuring the scope of change propagation of classes in object-oriented software system.
Quadrature formulas for Fourier coefficients
Bojanov, Borislav; Petrova, Guergana
2009-01-01
We consider quadrature formulas of high degree of precision for the computation of the Fourier coefficients in expansions of functions with respect to a system of orthogonal polynomials. In particular, we show the uniqueness of a multiple node
Diffusion coefficient for anomalous transport
International Nuclear Information System (INIS)
1986-01-01
A report on the progress towards the goal of estimating the diffusion coefficient for anomalous transport is given. The gyrokinetic theory is used to identify different time and length scale inherent to the characteristics of plasmas which exhibit anomalous transport
Fuel Temperature Coefficient of Reactivity
Energy Technology Data Exchange (ETDEWEB)
Loewe, W.E.
2001-07-31
A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.
Properties of Traffic Risk Coefficient
Tang, Tie-Qiao; Huang, Hai-Jun; Shang, Hua-Yan; Xue, Yu
2009-10-01
We use the model with the consideration of the traffic interruption probability (Physica A 387(2008)6845) to study the relationship between the traffic risk coefficient and the traffic interruption probability. The analytical and numerical results show that the traffic interruption probability will reduce the traffic risk coefficient and that the reduction is related to the density, which shows that this model can improve traffic security.
Propagation of Ion Acoustic Perturbations
DEFF Research Database (Denmark)
Pécseli, Hans
1975-01-01
Equations describing the propagation of ion acoustic perturbations are considered, using the assumption that the electrons are Boltzman distributed and isothermal at all times. Quasi-neutrality is also considered.......Equations describing the propagation of ion acoustic perturbations are considered, using the assumption that the electrons are Boltzman distributed and isothermal at all times. Quasi-neutrality is also considered....
Propagation Engineering in Wireless Communications
Ghasemi, Abdollah; Ghasemi, Farshid
2012-01-01
Wireless communications has seen explosive growth in recent decades, in a realm that is both broad and rapidly expanding to include satellite services, navigational aids, remote sensing, telemetering, audio and video broadcasting, high-speed data communications, mobile radio systems and much more. Propagation Engineering in Wireless Communications deals with the basic principles of radiowaves propagation for frequency bands used in radio-communications, offering descriptions of new achievements and newly developed propagation models. The book bridges the gap between theoretical calculations and approaches, and applied procedures needed for advanced radio links design. The primary objective of this two-volume set is to demonstrate the fundamentals, and to introduce propagation phenomena and mechanisms that engineers are likely to encounter in the design and evaluation of radio links of a given type and operating frequency. Volume one covers basic principles, along with tropospheric and ionospheric propagation,...
Aspects of HF radio propagation
Directory of Open Access Journals (Sweden)
Stephane Saillant
2009-06-01
.
c Development of inversion techniques enabling backscatter ionograms obtained by an HF radar to be used
to estimate the ionospheric electron density profile. This development facilitates the operation of over the horizon
HF radars by enhancing the frequency management aspects of the systems.
d Various propagation prediction techniques have been tested against measurements made over the trough
path mentioned above, and also over a long-range path between Cyprus and the UK.
e The effect of changes in the levels of ionospheric disturbances on the operational availability at various
data throughput rates has been examined for the trough path mentioned earlier.
The topics covered in this paper are necessarily brief, and the reader is referred to full papers referenced
Transionospheric propagation predictions
Klobucher, J. A.; Basu, S.; Basu, S.; Bernhardt, P. A.; Davies, K.; Donatelli, D. E.; Fremouw, E. J.; Goodman, J. M.; Hartmann, G. K.; Leitinger, R.
1979-01-01
The current status and future prospects of the capability to make transionospheric propagation predictions are addressed, highlighting the effects of the ionized media, which dominate for frequencies below 1 to 3 GHz, depending upon the state of the ionosphere and the elevation angle through the Earth-space path. The primary concerns are the predictions of time delay of signal modulation (group path delay) and of radio wave scintillation. Progress in these areas is strongly tied to knowledge of variable structures in the ionosphere ranging from the large scale (thousands of kilometers in horizontal extent) to the fine scale (kilometer size). Ionospheric variability and the relative importance of various mechanisms responsible for the time histories observed in total electron content (TEC), proportional to signal group delay, and in irregularity formation are discussed in terms of capability to make both short and long term predictions. The data base upon which predictions are made is examined for its adequacy, and the prospects for prediction improvements by more theoretical studies as well as by increasing the available statistical data base are examined.
Dressing the nucleon propagator
International Nuclear Information System (INIS)
Fishman, S.; Gersten, A.
1976-01-01
The nucleon propagator in the ''nested bubbles'' approximation is analyzed. The approximation is built from the minimal set of diagrams which is needed to maintain the unitarity condition under two-pion production threshold in the two-nucleon Bethe--Salpeter equation. Recursive formulas for subsets of ''nested bubbles'' diagrams calculated in the framework of the pseudoscalar interaction are obtained by the use of dispersion relations. We prove that the sum of all the ''nested bubbles'' diverges. Moreover, the successive iterations are plagued with ghost poles. We prove that the first approximation--which is the so-called chain approximation--has ghost poles for any nonvanishing coupling constant. In an earlier paper we have shown that ghost poles lead to ghost cuts. These cuts are present in the ''nested bubbles.'' Ghost elimination procedures are discussed. Modifications of the ''nested bubbles'' approximation are introduced in order to obtain convergence and in order to eliminate the ghost poles and ghost cuts. In a similar way as in the Lee model, cutoff functions are introduced in order to eliminate the ghost poles. The necessary and sufficient conditions for the absence of ghost poles are formulated and analyzed. The spectral functions of the modified ''nested bubbles'' are analyzed and computed. Finally, we present a theorem, similar in its form to Levinson's theorem in scattering theory, which enables one to compute in a simple way the number of ghost poles
Clustering Coefficients for Correlation Networks.
Masuda, Naoki; Sakaki, Michiko; Ezaki, Takahiro; Watanabe, Takamitsu
2018-01-01
Graph theory is a useful tool for deciphering structural and functional networks of the brain on various spatial and temporal scales. The clustering coefficient quantifies the abundance of connected triangles in a network and is a major descriptive statistics of networks. For example, it finds an application in the assessment of small-worldness of brain networks, which is affected by attentional and cognitive conditions, age, psychiatric disorders and so forth. However, it remains unclear how the clustering coefficient should be measured in a correlation-based network, which is among major representations of brain networks. In the present article, we propose clustering coefficients tailored to correlation matrices. The key idea is to use three-way partial correlation or partial mutual information to measure the strength of the association between the two neighboring nodes of a focal node relative to the amount of pseudo-correlation expected from indirect paths between the nodes. Our method avoids the difficulties of previous applications of clustering coefficient (and other) measures in defining correlational networks, i.e., thresholding on the correlation value, discarding of negative correlation values, the pseudo-correlation problem and full partial correlation matrices whose estimation is computationally difficult. For proof of concept, we apply the proposed clustering coefficient measures to functional magnetic resonance imaging data obtained from healthy participants of various ages and compare them with conventional clustering coefficients. We show that the clustering coefficients decline with the age. The proposed clustering coefficients are more strongly correlated with age than the conventional ones are. We also show that the local variants of the proposed clustering coefficients (i.e., abundance of triangles around a focal node) are useful in characterizing individual nodes. In contrast, the conventional local clustering coefficients were strongly
Clustering Coefficients for Correlation Networks
Directory of Open Access Journals (Sweden)
Naoki Masuda
2018-03-01
Full Text Available Graph theory is a useful tool for deciphering structural and functional networks of the brain on various spatial and temporal scales. The clustering coefficient quantifies the abundance of connected triangles in a network and is a major descriptive statistics of networks. For example, it finds an application in the assessment of small-worldness of brain networks, which is affected by attentional and cognitive conditions, age, psychiatric disorders and so forth. However, it remains unclear how the clustering coefficient should be measured in a correlation-based network, which is among major representations of brain networks. In the present article, we propose clustering coefficients tailored to correlation matrices. The key idea is to use three-way partial correlation or partial mutual information to measure the strength of the association between the two neighboring nodes of a focal node relative to the amount of pseudo-correlation expected from indirect paths between the nodes. Our method avoids the difficulties of previous applications of clustering coefficient (and other measures in defining correlational networks, i.e., thresholding on the correlation value, discarding of negative correlation values, the pseudo-correlation problem and full partial correlation matrices whose estimation is computationally difficult. For proof of concept, we apply the proposed clustering coefficient measures to functional magnetic resonance imaging data obtained from healthy participants of various ages and compare them with conventional clustering coefficients. We show that the clustering coefficients decline with the age. The proposed clustering coefficients are more strongly correlated with age than the conventional ones are. We also show that the local variants of the proposed clustering coefficients (i.e., abundance of triangles around a focal node are useful in characterizing individual nodes. In contrast, the conventional local clustering coefficients
Clustering Coefficients for Correlation Networks
Masuda, Naoki; Sakaki, Michiko; Ezaki, Takahiro; Watanabe, Takamitsu
2018-01-01
Graph theory is a useful tool for deciphering structural and functional networks of the brain on various spatial and temporal scales. The clustering coefficient quantifies the abundance of connected triangles in a network and is a major descriptive statistics of networks. For example, it finds an application in the assessment of small-worldness of brain networks, which is affected by attentional and cognitive conditions, age, psychiatric disorders and so forth. However, it remains unclear how the clustering coefficient should be measured in a correlation-based network, which is among major representations of brain networks. In the present article, we propose clustering coefficients tailored to correlation matrices. The key idea is to use three-way partial correlation or partial mutual information to measure the strength of the association between the two neighboring nodes of a focal node relative to the amount of pseudo-correlation expected from indirect paths between the nodes. Our method avoids the difficulties of previous applications of clustering coefficient (and other) measures in defining correlational networks, i.e., thresholding on the correlation value, discarding of negative correlation values, the pseudo-correlation problem and full partial correlation matrices whose estimation is computationally difficult. For proof of concept, we apply the proposed clustering coefficient measures to functional magnetic resonance imaging data obtained from healthy participants of various ages and compare them with conventional clustering coefficients. We show that the clustering coefficients decline with the age. The proposed clustering coefficients are more strongly correlated with age than the conventional ones are. We also show that the local variants of the proposed clustering coefficients (i.e., abundance of triangles around a focal node) are useful in characterizing individual nodes. In contrast, the conventional local clustering coefficients were strongly
Effective constants for wave propagation through partially saturated porous media
International Nuclear Information System (INIS)
Berryman, J.G.; Thigpen, L.
1985-01-01
The multipole scattering coefficients for elastic wave scattering from a spherical inhomogeneity in a fluid-saturated porous medium have been calculated. These coefficients may be used to obtain estimates of the effective macroscopic constants for long-wavelength propagation of elastic waves through partially saturated media. If the volume average of the single scattering from spherical bubbles of gas and liquid is required to vanish, the resulting equations determine the effective bulk modulus, density, and viscosity of the multiphase fluid filling the pores. The formula for the effective viscosity during compressional wave excitation is apparently new
Converting Sabine absorption coefficients to random incidence absorption coefficients
DEFF Research Database (Denmark)
Jeong, Cheol-Ho
2013-01-01
are suggested: An optimization method for the surface impedances for locally reacting absorbers, the flow resistivity for extendedly reacting absorbers, and the flow resistance for fabrics. With four porous type absorbers, the conversion methods are validated. For absorbers backed by a rigid wall, the surface...... coefficients to random incidence absorption coefficients are proposed. The overestimations of the Sabine absorption coefficient are investigated theoretically based on Miki's model for porous absorbers backed by a rigid wall or an air cavity, resulting in conversion factors. Additionally, three optimizations...... impedance optimization produces the best results, while the flow resistivity optimization also yields reasonable results. The flow resistivity and flow resistance optimization for extendedly reacting absorbers are also found to be successful. However, the theoretical conversion factors based on Miki's model...
NASA Lunar Base Wireless System Propagation Analysis
Hwu, Shian U.; Upanavage, Matthew; Sham, Catherine C.
2007-01-01
There have been many radio wave propagation studies using both experimental and theoretical techniques over the recent years. However, most of studies have been in support of commercial cellular phone wireless applications. The signal frequencies are mostly at the commercial cellular and Personal Communications Service bands. The antenna configurations are mostly one on a high tower and one near the ground to simulate communications between a cellular base station and a mobile unit. There are great interests in wireless communication and sensor systems for NASA lunar missions because of the emerging importance of establishing permanent lunar human exploration bases. Because of the specific lunar terrain geometries and RF frequencies of interest to the NASA missions, much of the published literature for the commercial cellular and PCS bands of 900 and 1800 MHz may not be directly applicable to the lunar base wireless system and environment. There are various communication and sensor configurations required to support all elements of a lunar base. For example, the communications between astronauts, between astronauts and the lunar vehicles, between lunar vehicles and satellites on the lunar orbits. There are also various wireless sensor systems among scientific, experimental sensors and data collection ground stations. This presentation illustrates the propagation analysis of the lunar wireless communication and sensor systems taking into account the three dimensional terrain multipath effects. It is observed that the propagation characteristics are significantly affected by the presence of the lunar terrain. The obtained results indicate the lunar surface material, terrain geometry and antenna location are the important factors affecting the propagation characteristics of the lunar wireless systems. The path loss can be much more severe than the free space propagation and is greatly affected by the antenna height, surface material and operating frequency. The
Pressure wave propagation in the discharge piping with water pool
International Nuclear Information System (INIS)
Bang, Young S.; Seul, Kwang W.; Kim, In Goo
2004-01-01
Pressure wave propagation in the discharge piping with a sparger submerged in a water pool, following the opening of a safety relief valve, is analyzed. To predict the pressure transient behavior, a RELAP5/MOD3 code is used. The applicability of the RELAP5 code and the adequacy of the present modeling scheme are confirmed by simulating the applicable experiment on a water hammer with voiding. As a base case, the modeling scheme was used to calculate the wave propagation inside a vertical pipe with sparger holes and submerged within a water pool. In addition, the effects on wave propagation of geometric factors, such as the loss coefficient, the pipe configuration, and the subdivision of sparger pipe, are investigated. The effects of inflow conditions, such as water slug inflow and the slow opening of a safety relief valve are also examined
International Nuclear Information System (INIS)
2002-01-01
The purpose of this Analysis and Model Report (AMR) supporting the Site Recommendation/License Application (SR/LA) for the Yucca Mountain Project is the development of elementary analyses of the interactions of a hypothetical dike with a repository drift (i.e., tunnel) and with the drift contents at the potential Yucca Mountain repository. This effort is intended to support the analysis of disruptive events for Total System Performance Assessment (TSPA). This AMR supports the Process Model Report (PMR) on disruptive events (CRWMS M and O 2000a). This purpose is documented in the development plan (DP) ''Coordinate Modeling of Dike Propagation Near Drifts Consequences for TSPA-SR/LA'' (CRWMS M and O 2000b). Evaluation of that Development Plan and the work to be conducted to prepare Interim Change Notice (ICN) 1 of this report, which now includes the design option of ''Open'' drifts, indicated that no revision to that DP was needed. These analyses are intended to provide reasonable bounds for a number of expected effects: (1) Temperature changes to the waste package from exposure to magma; (2) The gas flow available to degrade waste containers during the intrusion; (3) Movement of the waste package as it is displaced by the gas, pyroclasts and magma from the intruding dike (the number of packages damaged); (4) Movement of the backfill (Backfill is treated here as a design option); (5) The nature of the mechanics of the dike/drift interaction. These analyses serve two objectives: to provide preliminary analyses needed to support evaluation of the consequences of an intrusive event and to provide a basis for addressing some of the concerns of the Nuclear Regulatory Commission (NRC) expressed in the Igneous Activity Issue Resolution Status Report
Temperature dependency of external stress corrosion crack propagation of 304 stainless steel
International Nuclear Information System (INIS)
Hayashibara, Hitoshi; Mizutani, Yoshihiro; Mayuzumi, Masami; Tani, Jun-ichi
2010-01-01
Temperature dependency of external stress corrosion cracking (ESCC) of 304 stainless steel was examined with CT specimens. Maximum ESCC propagation rates appeared in the early phase of ESCC propagation. ESCC propagation rates generally became smaller as testing time advance. Temperature dependency of maximum ESCC propagation rate was analyzed with Arrhenius plot, and apparent activation energy was similar to that of SCC in chloride solutions. Temperature dependency of macroscopic ESCC incubation time was different from that of ESCC propagation rate. Anodic current density of 304 stainless steel was also examined by anodic polarization measurement. Temperature dependency of critical current density of active state in artificial sea water solution of pH=1.3 was similar to that of ESCC propagation rate. (author)
Instability Versus Equilibrium Propagation of Laser Beam in Plasma
Lushnikov, Pavel M.; Rose, Harvey A.
2003-01-01
We obtain, for the first time, an analytic theory of the forward stimulated Brillouin scattering instability of a spatially and temporally incoherent laser beam, that controls the transition between statistical equilibrium and non-equilibrium (unstable) self-focusing regimes of beam propagation. The stability boundary may be used as a comprehensive guide for inertial confinement fusion designs. Well into the stable regime, an analytic expression for the angular diffusion coefficient is obtain...
Power coefficient anomaly in JOYO
Energy Technology Data Exchange (ETDEWEB)
Yamamoto, H
1980-12-15
Operation of the JOYO experimental fast reactor with the MK-I core has been divided into two phases: (1) 50 MWt power ascension and operation; and (2) 75 MWt power ascension and operation. The 50 MWt power-up tests were conducted in August 1978. In these tests, the measured reactivity loss due to power increases from 15 MWt to 50 MWt was 0.28% ..delta.. K/K, and agreed well with the predicted value of 0.27% ..delta.. K/K. The 75 MWt power ascension tests were conducted in July-August 1979. In the process of the first power increase above 50 MWt to 65 MWt conducted on July 11, 1979, an anomalously large negative power coefficient was observed. The value was about twice the power coefficient values measured in the tests below 50 MW. In order to reproduce the anomaly, the reactor power was decreased and again increased up to the maximum power of 65 MWt. However, the large negative power coefficient was not observed at this time. In the succeeding power increase from 65 MWt to 75 MWt, a similar anomalous power coefficient was again observed. This anomaly disappeared in the subsequent power ascensions to 75 MWt, and the magnitude of the power coefficient gradually decreased with power cycles above the 50 MWt level.
Laser beam propagation generation and propagation of customized light
Forbes, Andrew
2014-01-01
""The text is easy to read and is accompanied by beautiful illustrations. It is an excellent book for anyone working in laser beam propagation and an asset for any library.""-Optics & Photonics News, July 2014
Asymptotic normalization coefficients and astrophysical factors
International Nuclear Information System (INIS)
Mukhamedzhanov, A.M.; Azhari, A.; Clark, H.L.; Gagliardi, C.A.; Lui, Y.-W.; Sattarov, A.; Trache, L.; Tribble, R.E.; Burjan, V.; Kroha, V.; Carstoiu, F.
2000-01-01
The S factor for the direct capture reaction 7 Be(p,γ) 8 B can be found at astrophysical energies from the asymptotic normalization coefficients (ANC's) which provide the normalization of the tails of the overlap functions for 8 B → 7 Be + p. Peripheral transfer reactions offer a technique to determine these ANC's. Using this technique, the 10 B( 7 Be, 8 B) 9 Be and 14 N( 7 Be, 8 B) 13 C reactions have been used to measure the asymptotic normalization coefficient for 7 Be(p, γ) 8 B. These results provide an indirect determination of S 17 (0). Analysis of the existing 9 Be(p, γ) 10 B experimental data within the framework of the R-matrix method demonstrates that experimentally measured ANC's can provide a reasonable determination of direct radiative capture rates. (author)
Mechanically driven interface propagation in biological tissues
International Nuclear Information System (INIS)
Ranft, Jonas; Joanny, Jean-François; Aliee, Maryam; Jülicher, Frank; Prost, Jacques
2014-01-01
Many biological tissues consist of more than one cell type. We study the dynamics of an interface between two different cell populations as it occurs during the growth of a tumor in a healthy host tissue. Recent work suggests that the rates of cell division and cell death are under mechanical control, characterized by a homeostatic pressure. The difference in the homeostatic pressures of two cell types drives the propagation of the interface, corresponding to the invasion of one cell type into the other. We derive a front propagation equation that takes into account the coupling between cell number balance and tissue mechanics. We show that in addition to pulled fronts, pushed-front solutions occur as a result of convection driven by mechanics. (paper)
Analysis of internal conversion coefficients
International Nuclear Information System (INIS)
Coursol, N.; Gorozhankin, V.M.; Yakushev, E.A.; Briancon, C.; Vylov, Ts.
2000-01-01
An extensive database has been assembled that contains the three most widely used sets of calculated internal conversion coefficients (ICC): [Hager R.S., Seltzer E.C., 1968. Internal conversion tables. K-, L-, M-shell Conversion coefficients for Z=30 to Z=103, Nucl. Data Tables A4, 1-237; Band I.M., Trzhaskovskaya M.B., 1978. Tables of gamma-ray internal conversion coefficients for the K-, L- and M-shells, 10≤Z≤104, Special Report of Leningrad Nuclear Physics Institute; Roesel F., Fries H.M., Alder K., Pauli H.C., 1978. Internal conversion coefficients for all atomic shells, At. Data Nucl. Data Tables 21, 91-289] and also includes new Dirac-Fock calculations [Band I.M. and Trzhaskovskaya M.B., 1993. Internal conversion coefficients for low-energy nuclear transitions, At. Data Nucl. Data Tables 55, 43-61]. This database is linked to a computer program to plot ICCs and their combinations (sums and ratios) as a function of Z and energy, as well as relative deviations of ICC or their combinations for any pair of tabulated data. Examples of these analyses are presented for the K-shell and total ICCs of the gamma-ray standards [Hansen H.H., 1985. Evaluation of K-shell and total internal conversion coefficients for some selected nuclear transitions, Eur. Appl. Res. Rept. Nucl. Sci. Tech. 11.6 (4) 777-816] and for the K-shell and total ICCs of high multipolarity transitions (total, K-, L-, M-shells of E3 and M3 and K-shell of M4). Experimental data sets are also compared with the theoretical values of these specific calculations
Algebraic polynomials with random coefficients
Directory of Open Access Journals (Sweden)
K. Farahmand
2002-01-01
Full Text Available This paper provides an asymptotic value for the mathematical expected number of points of inflections of a random polynomial of the form a0(ω+a1(ω(n11/2x+a2(ω(n21/2x2+…an(ω(nn1/2xn when n is large. The coefficients {aj(w}j=0n, w∈Ω are assumed to be a sequence of independent normally distributed random variables with means zero and variance one, each defined on a fixed probability space (A,Ω,Pr. A special case of dependent coefficients is also studied.
Monitoring of the temperature reactivity coefficient at the PWR nuclear plant
International Nuclear Information System (INIS)
Kostic, Lj.
1996-01-01
For monitoring temperature coefficient of reactivity of pressurized water reactor a method based on the correction of fluctuation in signals of i-core neutron detectors and core-exit thermocouples and neural network paradigm is used it is shown that the moderator temperature coefficient of relativity can be predicted with the aid of the back propagation neural network technique by measuring the frequency response function between the in-core neutron flux and the core-exit coolant temperature
Localized Elf Propagation Anomalies.
1985-06-01
the above three SPEs. Those important auxiliary data are used as inputs to air- chemistry codes to calculate the electron and ion density height...horizontal magnetic intensity H is H A ( ATAR ) 1 / 2 (9 d)- 1/2 exp(-’afL- d) e- d/ 8 " 7 coso A/m, (1) where A depends on the antenna moment, frequency...those rates are input to air- chemistry equations to obtain height profiles of electron and ion densities. Calculation of ion-pair production rates
Methodologies of Uncertainty Propagation Calculation
International Nuclear Information System (INIS)
Chojnacki, Eric
2002-01-01
After recalling the theoretical principle and the practical difficulties of the methodologies of uncertainty propagation calculation, the author discussed how to propagate input uncertainties. He said there were two kinds of input uncertainty: - variability: uncertainty due to heterogeneity, - lack of knowledge: uncertainty due to ignorance. It was therefore necessary to use two different propagation methods. He demonstrated this in a simple example which he generalised, treating the variability uncertainty by the probability theory and the lack of knowledge uncertainty by the fuzzy theory. He cautioned, however, against the systematic use of probability theory which may lead to unjustifiable and illegitimate precise answers. Mr Chojnacki's conclusions were that the importance of distinguishing variability and lack of knowledge increased as the problem was getting more and more complex in terms of number of parameters or time steps, and that it was necessary to develop uncertainty propagation methodologies combining probability theory and fuzzy theory
Propagation engineering in wireless communications
Ghasemi, Abdollah; Ghasemi, Farshid
2016-01-01
This book covers the basic principles for understanding radio wave propagation for common frequency bands used in radio-communications. This includes achievements and developments in propagation models for wireless communication. This book is intended to bridge the gap between the theoretical calculations and approaches to the applied procedures needed for radio links design in a proper manner. The authors emphasize propagation engineering by giving fundamental information and explain the use of basic principles together with technical achievements. This new edition includes additional information on radio wave propagation in guided media and technical issues for fiber optics cable networks with several examples and problems. This book also includes a solution manual - with 90 solved examples distributed throughout the chapters - and 158 problems including practical values and assumptions.
Wave propagation in electromagnetic media
Davis, Julian L
1990-01-01
This is the second work of a set of two volumes on the phenomena of wave propagation in nonreacting and reacting media. The first, entitled Wave Propagation in Solids and Fluids (published by Springer-Verlag in 1988), deals with wave phenomena in nonreacting media (solids and fluids). This book is concerned with wave propagation in reacting media-specifically, in electro magnetic materials. Since these volumes were designed to be relatively self contained, we have taken the liberty of adapting some of the pertinent material, especially in the theory of hyperbolic partial differential equations (concerned with electromagnetic wave propagation), variational methods, and Hamilton-Jacobi theory, to the phenomena of electromagnetic waves. The purpose of this volume is similar to that of the first, except that here we are dealing with electromagnetic waves. We attempt to present a clear and systematic account of the mathematical methods of wave phenomena in electromagnetic materials that will be readily accessi...
Massive propagators in instanton fields
International Nuclear Information System (INIS)
Brown, L.S.; Lee, C.
1978-01-01
Green's functions for massive spinor and vector particles propagating in a self-dual but otherwise arbitrary non-Abelian gauge field are shown to be completely determined by the corresponding Green's functions of massive scalar particles
Propagation of dynamic measurement uncertainty
International Nuclear Information System (INIS)
Hessling, J P
2011-01-01
The time-dependent measurement uncertainty has been evaluated in a number of recent publications, starting from a known uncertain dynamic model. This could be defined as the 'downward' propagation of uncertainty from the model to the targeted measurement. The propagation of uncertainty 'upward' from the calibration experiment to a dynamic model traditionally belongs to system identification. The use of different representations (time, frequency, etc) is ubiquitous in dynamic measurement analyses. An expression of uncertainty in dynamic measurements is formulated for the first time in this paper independent of representation, joining upward as well as downward propagation. For applications in metrology, the high quality of the characterization may be prohibitive for any reasonably large and robust model to pass the whiteness test. This test is therefore relaxed by not directly requiring small systematic model errors in comparison to the randomness of the characterization. Instead, the systematic error of the dynamic model is propagated to the uncertainty of the measurand, analogously but differently to how stochastic contributions are propagated. The pass criterion of the model is thereby transferred from the identification to acceptance of the total accumulated uncertainty of the measurand. This increases the relevance of the test of the model as it relates to its final use rather than the quality of the calibration. The propagation of uncertainty hence includes the propagation of systematic model errors. For illustration, the 'upward' propagation of uncertainty is applied to determine if an appliance box is damaged in an earthquake experiment. In this case, relaxation of the whiteness test was required to reach a conclusive result
Irrational "Coefficients" in Renaissance Algebra.
Oaks, Jeffrey A
2017-06-01
Argument From the time of al-Khwārizmī in the ninth century to the beginning of the sixteenth century algebraists did not allow irrational numbers to serve as coefficients. To multiply by x, for instance, the result was expressed as the rhetorical equivalent of . The reason for this practice has to do with the premodern concept of a monomial. The coefficient, or "number," of a term was thought of as how many of that term are present, and not as the scalar multiple that we work with today. Then, in sixteenth-century Europe, a few algebraists began to allow for irrational coefficients in their notation. Christoff Rudolff (1525) was the first to admit them in special cases, and subsequently they appear more liberally in Cardano (1539), Scheubel (1550), Bombelli (1572), and others, though most algebraists continued to ban them. We survey this development by examining the texts that show irrational coefficients and those that argue against them. We show that the debate took place entirely in the conceptual context of premodern, "cossic" algebra, and persisted in the sixteenth century independent of the development of the new algebra of Viète, Decartes, and Fermat. This was a formal innovation violating prevailing concepts that we propose could only be introduced because of the growing autonomy of notation from rhetorical text.
Integer Solutions of Binomial Coefficients
Gilbertson, Nicholas J.
2016-01-01
A good formula is like a good story, rich in description, powerful in communication, and eye-opening to readers. The formula presented in this article for determining the coefficients of the binomial expansion of (x + y)n is one such "good read." The beauty of this formula is in its simplicity--both describing a quantitative situation…
Semiclassical propagation of Wigner functions.
Dittrich, T; Gómez, E A; Pachón, L A
2010-06-07
We present a comprehensive study of semiclassical phase-space propagation in the Wigner representation, emphasizing numerical applications, in particular as an initial-value representation. Two semiclassical approximation schemes are discussed. The propagator of the Wigner function based on van Vleck's approximation replaces the Liouville propagator by a quantum spot with an oscillatory pattern reflecting the interference between pairs of classical trajectories. Employing phase-space path integration instead, caustics in the quantum spot are resolved in terms of Airy functions. We apply both to two benchmark models of nonlinear molecular potentials, the Morse oscillator and the quartic double well, to test them in standard tasks such as computing autocorrelation functions and propagating coherent states. The performance of semiclassical Wigner propagation is very good even in the presence of marked quantum effects, e.g., in coherent tunneling and in propagating Schrodinger cat states, and of classical chaos in four-dimensional phase space. We suggest options for an effective numerical implementation of our method and for integrating it in Monte-Carlo-Metropolis algorithms suitable for high-dimensional systems.
Wave propagation model of heat conduction and group speed
Zhang, Long; Zhang, Xiaomin; Peng, Song
2018-03-01
In view of the finite relaxation model of non-Fourier's law, the Cattaneo and Vernotte (CV) model and Fourier's law are presented in this work for comparing wave propagation modes. Independent variable translation is applied to solve the partial differential equation. Results show that the general form of the time spatial distribution of temperature for the three media comprises two solutions: those corresponding to the positive and negative logarithmic heating rates. The former shows that a group of heat waves whose spatial distribution follows the exponential function law propagates at a group speed; the speed of propagation is related to the logarithmic heating rate. The total speed of all the possible heat waves can be combined to form the group speed of the wave propagation. The latter indicates that the spatial distribution of temperature, which follows the exponential function law, decays with time. These features show that propagation accelerates when heated and decelerates when cooled. For the model media that follow Fourier's law and correspond to the positive heat rate of heat conduction, the propagation mode is also considered the propagation of a group of heat waves because the group speed has no upper bound. For the finite relaxation model with non-Fourier media, the interval of group speed is bounded and the maximum speed can be obtained when the logarithmic heating rate is exactly the reciprocal of relaxation time. And for the CV model with a non-Fourier medium, the interval of group speed is also bounded and the maximum value can be obtained when the logarithmic heating rate is infinite.
Streamer propagation velocity to anode and to cathode in He, Xe, N2 and SF6
International Nuclear Information System (INIS)
Yakovlenko, S.I.
2004-01-01
One studied mechanism of ionization propagation in a solid gas associated with propagation of background electrons in heterogenous electric field. The mentioned mechanism does not depend on the sign of field projection on ionization propagation direction. One derived analytical expression for ionization front rate. The mentioned expression conforms well with numerical calculations. Dependence of wave ionization front rate as a function of a field intensity on boundary of streamer for He, Xe, N 2 and SF 6 is tabulated [ru
Popular Topics Spread Faster: New Dimension for Influence Propagation in Online Social Networks
Pan, Tianyi; Kuhnle, Alan; Li, Xiang; Thai, My T.
2017-01-01
Information can propagate among Online Social Network (OSN) users at a high speed, which makes the OSNs become important platforms for viral marketing. Although the viral marketing related problems in OSNs have been extensively studied in the past decade, the existing works all assume known propagation rates and are not able to solve the scenario when the rates may dynamically increase for popular topics. In this paper, we propose a novel model, Dynamic Influence Propagation (DIP), which allo...
Moderator temperature coefficient in BWR core
International Nuclear Information System (INIS)
Naito, Yoshitaka
1977-01-01
Temperature dependences of infinite multiplication factor k sub(infinity) and neutron leakage from the core must be examined for estimation of moderator temperature coefficient. Temperature dependence on k sub(infinity) has been investigated by many researchers, however, the dependence on neutron leakage of a BWR with cruciformed control rods has hardly been done. Because there are difficulties and necessity on calculations of three space dimensional and multi-energy groups neutron distribution in a BWR core. In this study, moderator temperature coefficients of JPDR-II (BWR) core were obtained by calculation with DIFFUSION-ACE, which is newly developed three-dimensional multi-group computer code. The results were compared with experimental data measured from 20 to 275 0 C of the moderator temperature and the good agreement was obtained between calculation and measurement. In order to evaluate neutron leakage from the core, the other two calculations were carried out, adjusting criticality by uniform absorption rate and by material buckling. The former underestimated neutron leakage and the latter overestimated it. Discussion on the results shows that in order to estimate the temperature coefficient of BWR, neutron leakage must be evaluated precisely, therefore the calculation at actual pattern of control rods is necessary. (auth.)
Varying coefficients model with measurement error.
Li, Liang; Greene, Tom
2008-06-01
We propose a semiparametric partially varying coefficient model to study the relationship between serum creatinine concentration and the glomerular filtration rate (GFR) among kidney donors and patients with chronic kidney disease. A regression model is used to relate serum creatinine to GFR and demographic factors in which coefficient of GFR is expressed as a function of age to allow its effect to be age dependent. GFR measurements obtained from the clearance of a radioactively labeled isotope are assumed to be a surrogate for the true GFR, with the relationship between measured and true GFR expressed using an additive error model. We use locally corrected score equations to estimate parameters and coefficient functions, and propose an expected generalized cross-validation (EGCV) method to select the kernel bandwidth. The performance of the proposed methods, which avoid distributional assumptions on the true GFR and residuals, is investigated by simulation. Accounting for measurement error using the proposed model reduced apparent inconsistencies in the relationship between serum creatinine and GFR among different clinical data sets derived from kidney donor and chronic kidney disease source populations.
Effective Diffusion Coefficients in Coal Chars
DEFF Research Database (Denmark)
Johnsson, Jan Erik; Jensen, Anker
2001-01-01
Knowledge of effective diffusion coefficients in char particles is important when interpreting experimental reactivity measurements and modeling char combustion or NO and N2O reduction. In this work, NO and N2O reaction with a bituminous coal char was studied in a fixed-bed quartz glass reactor....... In the case of strong pore diffusion limitations, the error in the interpretation of experimental results using the mean pore radius could be a factor of 5 on the intrinsic rate constant. For an average coal char reacting with oxygen at 1300 K, this would be the case for particle sizes larger than about 50...
International Nuclear Information System (INIS)
Zhang, Xin; Liu, Haitao; Zhong, Ying
2012-01-01
We theoretically study the compensation of propagation loss of surface plasmon polaritons (SPPs) with the use of a finite-thickness dielectric layer with optical gain. The impacts of the gain coefficient, the gain-layer thickness and the wavelength on the loss compensation and the field distribution of the SPP mode are systematically explored with a fully vectorial method. Abnormal behaviors for the loss compensation as the gain-layer thickness increases are found and explained. Critical values of the gain coefficient and of the corresponding gain-layer thickness for just compensating the propagation loss are provided. Our results show that as the SPP propagation loss is fully compensated with a gain coefficient at a reasonably low level, the gain layer is still thin enough to ensure a large exterior SPP field at the gain-layer/air interface, which is important for achieving a strong light–matter interaction for applications such as bio-chemical sensing. (paper)
PROPAGATION OF NEW BLACKBERRY CULTIVARS FOR PRODUCING CERTIFIED PROPAGATION MATERIAL
Directory of Open Access Journals (Sweden)
Valentina Isac
2014-12-01
Full Text Available The purpose of this research was to study the behaviour of two new Romanian thorn blackberry cultivars DAR 24 and DAR 8 in process of micropropagation, compared with Darrow cultivar usually commercially micropropagated in our laboratory. Due to several drawbacks of the conventional propagation of Rubus, the efficiency of micropropagation was tested in order to obtain high quality planting material and to introduce rapidly these new cultivars in a certification program. Thorn blackberry cultivars DAR 8 and DAR 24 with resistance to winter colds was successfully micropropagated. Blackberry plants were found without virus infection after biological and ELISA tests. Axillary buds from the branches in full growth were used as the initial explants. After four weeks of growth, aseptic cultures was established on MS basal mineral salts, LS vitamins with 0.3 mg/l BAP, 0.1mg/l GA3 and 0.001mg/l NAA. The rate of successfully established cultures was on average 65.11%. Good proliferation of the regenerated shoots was obtained on the same medium composition used for initiation phase, whereas medium MS with mineral salts reduced to ½ and LS vitamins with 0.1 mg/l IBA and 0.1 mg/l GA3 was used in the rooting phase. Dar 24 and Dar 8 cultivars responded by good rates of micropropagation on medium culture B as compared to control Darrow cultivar, even if the obtained shoots length was lower than on medium A. The statistical analysis reveled that the highest MR (20.66 plantlets/explant was obtained for Dar 24. In this case the length of shoots was 1.92 cm. The highest rooting percentages (over 85% were obtained with shoots multiplied on medium B. High quality of rooted plants induced a high percentage of acclimatization of cultivar Dar 8, 86.36% under mist system in green house whereas the percentage of acclimatization of cultivar Dar 24 was lower, 51.85%.
Suppression of Fatigue Crack Propagation of Duralumin by Cavitation Peening
Directory of Open Access Journals (Sweden)
Hitoshi Soyama
2015-08-01
Full Text Available It was demonstrated in the present paper that cavitation peening which is one of the mechanical surface modification technique can suppress fatigue crack propagation in duralumin. The impacts produced when cavitation bubble collapses can be utilised for the mechanical surface modification technique in the same way as laser peening and shot peening, which is called “cavitation peening”. Cavitation peening employing a cavitating jet in water was used to treat the specimen made of duralumin Japanese Industrial Standards JIS A2017-T3. After introducing a notch, fatigue test was conducted by a load-controlled plate bending fatigue tester, which has been originally developed. The fatigue crack propagation behavior was evaluated and the relationship between the fatigue crack propagation rate versus stress intensity factor range was obtained. From the results, the fatigue crack propagation rate was drastically reduced by cavitation peening and the fatigue life of duralumin plate was extended 4.2 times by cavitation peening. In addition, the fatigue crack propagation can be suppressed by 88% in the stable crack propagation stage by cavitation peening.
Optimized Finite-Difference Coefficients for Hydroacoustic Modeling
Preston, L. A.
2014-12-01
Responsible utilization of marine renewable energy sources through the use of current energy converter (CEC) and wave energy converter (WEC) devices requires an understanding of the noise generation and propagation from these systems in the marine environment. Acoustic noise produced by rotating turbines, for example, could adversely affect marine animals and human-related marine activities if not properly understood and mitigated. We are utilizing a 3-D finite-difference acoustic simulation code developed at Sandia that can accurately propagate noise in the complex bathymetry in the near-shore to open ocean environment. As part of our efforts to improve computation efficiency in the large, high-resolution domains required in this project, we investigate the effects of using optimized finite-difference coefficients on the accuracy of the simulations. We compare accuracy and runtime of various finite-difference coefficients optimized via criteria such as maximum numerical phase speed error, maximum numerical group speed error, and L-1 and L-2 norms of weighted numerical group and phase speed errors over a given spectral bandwidth. We find that those coefficients optimized for L-1 and L-2 norms are superior in accuracy to those based on maximal error and can produce runtimes of 10% of the baseline case, which uses Taylor Series finite-difference coefficients at the Courant time step limit. We will present comparisons of the results for the various cases evaluated as well as recommendations for utilization of the cases studied. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.
Magnetic field driven domain-wall propagation in magnetic nanowires
International Nuclear Information System (INIS)
Wang, X.R.; Yan, P.; Lu, J.; He, C.
2009-01-01
The mechanism of magnetic field induced magnetic domain-wall (DW) propagation in a nanowire is revealed: A static DW cannot exist in a homogeneous magnetic nanowire when an external magnetic field is applied. Thus, a DW must vary with time under a static magnetic field. A moving DW must dissipate energy due to the Gilbert damping. As a result, the wire has to release its Zeeman energy through the DW propagation along the field direction. The DW propagation speed is proportional to the energy dissipation rate that is determined by the DW structure. The negative differential mobility in the intermediate field is due to the transition from high energy dissipation at low field to low energy dissipation at high field. For the field larger than the so-called Walker breakdown field, DW plane precesses around the wire, leading to the propagation speed oscillation.
FATIGUE CRACK PROPAGATION THROUGH AUSTEMPERED DUCTILE IRON MICROSTRUCTURE
Directory of Open Access Journals (Sweden)
Lukáš Bubenko
2010-10-01
Full Text Available Austempered ductile iron (ADI has a wide range of application, particularly for castings used in automotive and earth moving machinery industries. These components are usually subjected to variable dynamic loading that may promote initiation and propagation of fatigue cracks up to final fracture. Thus, it is important to determine the fatigue crack propagation behavior of ADI. Since fatigue crack growth rate (da/dN vs. stress intensity factor K data describe fatigue crack propagation resistance and fatigue durability of structural materials, da/dN vs. Ka curves of ADI 1050 are reported here. The threshold amplitude of stress intensity factor Kath is also determined. Finally, the influence of stress intensity factor amplitude to the character of fatigue crack propagation through the ADI microstructure is described.
Fatigue crack propagation under elastic plastic medium at elevated temperature
International Nuclear Information System (INIS)
Asada, Y.; Yuuki, R.; Sakon, T.; Sunamoto, D.; Tokimasa, K.; Makino, Y.; Kitagawa, M; Shingai, K.
1980-01-01
The purposes of the present study are to establish the testing method to obtain compatible data on the low cycle fatigue crack propagation at elevated temperature, and to investigate the parameter controlling the crack propagation rate. In the present study, the preliminary experiments have been carried out on low cycle fatigue crack propagation behaviour in type 304 stainless steel in air at 550 0 C, using two types of specimen with a through thickness notch. Both strain controlled and stress controlled fatigue tests have been done under a fully reversed strain or stress cycling. The data obtained are correlated with some fracture mechanics parameters and are discussed with the appropriate parameter for evaluating the low cycle fatigue crack propagation behaviour at elevated temperature. (author)
Propagation of Aquilaria malaccensis seedlings through tissue culture techniques
International Nuclear Information System (INIS)
Salahbiah Abdul Majid; Zaiton Ahmad; Mohd Rafaie Abdul Salam; Nurhayati Irwan; Affrida Abu Hassan; Rusli Ibrahim
2010-01-01
Aquilaria malaccensis or karas is the principal source of gaharu resin, which is used in many cultures for incense, perfumes and traditional medicines. The species is mainly propagated conventionally through seeds, cuttings and graftings. Propagation by seeds is usually a reliable method for other forest species, but for karas, this technique is inadequate to meet the current demand of seedling supplies. This is principally due to its low seed viability, low germination rate, delayed rooting of seedlings, long life-cycle and rare seed production. Tissue culture has several advantages over conventional propagation, especially for obtaining large number of uniform and high-yielding plantlets or clones. This paper presents the current progress on mass-propagation of Aquilaria malaccensis seedlings through tissue culture technique at Nuclear Malaysia. (author)
Calibration factor or calibration coefficient?
International Nuclear Information System (INIS)
Meghzifene, A.; Shortt, K.R.
2002-01-01
Full text: The IAEA/WHO network of SSDLs was set up in order to establish links between SSDL members and the international measurement system. At the end of 2001, there were 73 network members in 63 Member States. The SSDL network members provide calibration services to end-users at the national or regional level. The results of the calibrations are summarized in a document called calibration report or calibration certificate. The IAEA has been using the term calibration certificate and will continue using the same terminology. The most important information in a calibration certificate is a list of calibration factors and their related uncertainties that apply to the calibrated instrument for the well-defined irradiation and ambient conditions. The IAEA has recently decided to change the term calibration factor to calibration coefficient, to be fully in line with ISO [ISO 31-0], which recommends the use of the term coefficient when it links two quantities A and B (equation 1) that have different dimensions. The term factor should only be used for k when it is used to link the terms A and B that have the same dimensions A=k.B. However, in a typical calibration, an ion chamber is calibrated in terms of a physical quantity such as air kerma, dose to water, ambient dose equivalent, etc. If the chamber is calibrated together with its electrometer, then the calibration refers to the physical quantity to be measured per electrometer unit reading. In this case, the terms referred have different dimensions. The adoption by the Agency of the term coefficient to express the results of calibrations is consistent with the 'International vocabulary of basic and general terms in metrology' prepared jointly by the BIPM, IEC, ISO, OIML and other organizations. The BIPM has changed from factor to coefficient. The authors believe that this is more than just a matter of semantics and recommend that the SSDL network members adopt this change in terminology. (author)
Extinction Coefficient of Gold Nanostars
de Puig, Helena; Tam, Justina O.; Yen, Chun-Wan; Gehrke, Lee; Hamad-Schifferli, Kimberly
2015-01-01
Gold nanostars (NStars) are highly attractive for biological applications due to their surface chemistry, facile synthesis and optical properties. Here, we synthesize NStars in HEPES buffer at different HEPES/Au ratios, producing NStars of different sizes and shapes, and therefore varying optical properties. We measure the extinction coefficient of the synthesized NStars at their maximum surface plasmon resonances (SPR), which range from 5.7 × 108 to 26.8 × 108 M−1cm−1. Measured values correl...
Earl, James A.
1992-01-01
When charged particles spiral along a large constant magnetic field, their trajectories are scattered by any random field components that are superposed on the guiding field. If the random field configuration embodies helicity, the scattering is asymmetrical with respect to a plane perpendicular to the guiding field, for particles moving into the forward hemisphere are scattered at different rates from those moving into the backward hemisphere. This asymmetry gives rise to new terms in the transport equations that describe propagation of charged particles. Helicity has virtually no impact on qualitative features of the diffusive mode of propagation. However, characteristic velocities of the coherent modes that appear after a highly anisotropic injection exhibit an asymmetry related to helicity. Explicit formulas, which embody the effects of helicity, are given for the anisotropies, the coefficient diffusion, and the coherent velocities. Predictions derived from these expressions are in good agreement with Monte Carlo simulations of particle transport, but the simulations reveal certain phenomena whose explanation calls for further analytical work.
Group symmetries and information propagation
International Nuclear Information System (INIS)
Draayer, J.P.
1980-01-01
Spectroscopy concerns itself with the ways in which the Hamiltonian and other interesting operators defined in few-particle spaces are determined or determine properties of many-particle systems. But the action of the central limit theorem (CLT) filters the transmission of information between source and observed so whether propagating forward from a few-particle defining space, as is usual in theoretical studies, or projecting backward to it from measured things, each is only sensitive to averaged properties of the other. Our concern is with the propagation of spectroscopic information in the presence of good symmetries when filtering action of the CLT is effective. Specifically, we propose to address the question, What propagates and how. We begin with some examples, using both scalar and isospin geometries to illustrate simple propagation. Examples of matrix propagation are studied; contact with standard tensor algebra is established and an algorithm put forward for the expansion of any operator in terms of another set, complete or not; shell-model results for 20 Ne using a realistic interaction and two trace-equivalent forms are presented; and some further challenges are mentioned
Ménesguen, Y.; Lépy, M.-C.
2010-08-01
This work presents new measurements of mass attenuation coefficients in the range 3.8⩽E⩽11 keV, K-absorption jump-ratios, Kα and Kβ fluorescence yields for Ti, V, Fe, Co, Ni, Cu and Zn. We use the experimental facility SOLEX, a tunable monochromatic X-ray source combined with an energy-dispersive high-purity germanium detector. The results are compared with theoretical values as well as with other experimental data and show a relatively good agreement. However, the derived K-jump-ratios appear larger than those widely used in the XCOM database. The Kα and Kβ fluorescence yields and the corresponding relative emission rates Kβ/Kα are also derived, which was made possible by the use of energy-dispersive detectors with good spectral resolution.
Energy Technology Data Exchange (ETDEWEB)
McCleskey, M; Mukhamedzhanov, A M; Trache, L; Tribble, R E; Banu, A; Eremenko, V; Goldberg, V Z; Lui, Y W; McCleskey, E; Roeder, B T; Spiridon, A; Carstoiu, F; Burjan, V; Hons, Z; Thompson, I J
2014-04-17
The ^{14}C + n <--> ^{15}C system has been used as a test case in the evaluation of a new method to determine spectroscopic factors that uses the asymptotic normalization coefficient (ANC). The method proved to be unsuccessful for this case. As part of this experimental program, the ANCs for the ^{15}C ground state and first excited state were determined using a heavy-ion neutron transfer reaction as well as the inverse kinematics (d,p) reaction, measured at the Texas A&M Cyclotron Institute. The ANCs were used to evaluate the astrophysical direct neutron capture rate on ^{14}C, which was then compared with the most recent direct measurement and found to be in good agreement. A study of the ^{15}C SF via its mirror nucleus ^{15}F and a new insight into deuteron stripping theory are also presented.
Form of multicomponent Fickian diffusion coefficients matrix
International Nuclear Information System (INIS)
Wambui Mutoru, J.; Firoozabadi, Abbas
2011-01-01
Highlights: → Irreversible thermodynamics establishes form of multicomponent diffusion coefficients. → Phenomenological coefficients and thermodynamic factors affect sign of diffusion coefficients. → Negative diagonal elements of diffusion coefficients matrix can occur in non-ideal mixtures. → Eigenvalues of the matrix of Fickian diffusion coefficients may not be all real. - Abstract: The form of multicomponent Fickian diffusion coefficients matrix in thermodynamically stable mixtures is established based on the form of phenomenological coefficients and thermodynamic factors. While phenomenological coefficients form a symmetric positive definite matrix, the determinant of thermodynamic factors matrix is positive. As a result, the Fickian diffusion coefficients matrix has a positive determinant, but its elements - including diagonal elements - can be negative. Comprehensive survey of reported diffusion coefficients data for ternary and quaternary mixtures, confirms that invariably the determinant of the Fickian diffusion coefficients matrix is positive.
Ai, Fei; Qian, Jianqiang; Shi, Junfeng; Zhang, Machi
2017-10-10
The transmission properties of beams in gain fibers are studied with the complex refractive index beam propagation method (CRI-BPM). The method is checked by comparison with an analytic method. The behavior of a gain-guided, index antiguided (GG-IAG) fiber with different gain coefficients is studied. The simulation results show that the signal can transfer in the fiber with almost no loss when the gain coefficient reaches the threshold of the fundamental mode, and the shape of output spot will have no major changes when the gain coefficient is over the thresholds of high-order modes, even when the mode competition is not obvious. The CRI-BPM can predict the changes in light power and light mode at the same time, and will be very useful in the designing of fiber amplifiers and lasers with complex structures. More factors will be considered in this method to provide reference for practical application in our further research.
On time-dependent diffusion coefficients arising from stochastic processes with memory
Carpio-Bernido, M. Victoria; Barredo, Wilson I.; Bernido, Christopher C.
2017-08-01
Time-dependent diffusion coefficients arise from anomalous diffusion encountered in many physical systems such as protein transport in cells. We compare these coefficients with those arising from analysis of stochastic processes with memory that go beyond fractional Brownian motion. Facilitated by the Hida white noise functional integral approach, diffusion propagators or probability density functions (pdf) are obtained and shown to be solutions of modified diffusion equations with time-dependent diffusion coefficients. This should be useful in the study of complex transport processes.
Self-similar optical pulses in competing cubic-quintic nonlinear media with distributed coefficients
International Nuclear Information System (INIS)
Zhang Jiefang; Tian Qing; Wang Yueyue; Dai Chaoqing; Wu Lei
2010-01-01
We present a systematic analysis of the self-similar propagation of optical pulses within the framework of the generalized cubic-quintic nonlinear Schroedinger equation with distributed coefficients. By appropriately choosing the relations between the distributed coefficients, we not only retrieve the exact self-similar solitonic solutions, but also find both the approximate self-similar Gaussian-Hermite solutions and compact solutions. Our analytical and numerical considerations reveal that proper choices of the distributed coefficients could make the unstable solitons stable and could restrict the nonlinear interaction between the neighboring solitons.
Influence of Removable Devices' Heterouse on the Propagation of Malware
Directory of Open Access Journals (Sweden)
Xie Han
2013-01-01
Full Text Available The effects of removable devices’ heterouse in different areas on the propagation of malware spreading via removable devices remain unclear. As a result, in this paper, we present a model incorporating the heterogeneous use of removable devices, obtained by dividing the using rate into local area’s rate, neighbour area’s rate and global area’s rate, and then getting the final rate by multiplying the corresponding area ratio. The model’s equilibria and their stability conditions are obtained mathematically and verified by deterministic and stochastic simulations. Simulation results also indicate that the heterogeneity in using rate significantly changes the prospective propagation course of malware. Additionally, the thresholds of removable devices’ using rate in neighbour area are given, which can guide us in designing effective countermalware method.
Dynamic 8-state ICSAR rumor propagation model considering official rumor refutation
Zhang, Nan; Huang, Hong; Su, Boni; Zhao, Jinlong; Zhang, Bo
2014-12-01
With the rapid development of information networks, negative impacts of rumor propagation become more serious. Nowadays, knowing the mechanisms of rumor propagation and having an efficient official rumor refutation plan play very important roles in reducing losses and ensuring social safety. In this paper we first develop the dynamic 8-state ICSAR (Ignorance, Information Carrier, Information Spreader, Information Advocate, Removal) rumor propagation model to study the mechanism of rumor propagation. Eight influencing factors including information attraction, objective identification of rumors, subjective identification of people, the degree of trust of information media, spread probability, reinforcement coefficient, block value and expert effects which are related to rumor propagation were analyzed. Next, considering these factors and mechanisms of rumor propagation and refutation, the dynamic 8-state ICSAR rumor propagation model is verified by the SIR epidemic model, computer simulation and actual data. Thirdly, through quantitative sensitivity analysis, the detailed function of each influencing factor was studied and shown in the figure directly. According to these mechanisms, we could understand how to block a rumor in a very efficient way and which methods should be chosen in different situations. The ICSAR model can divide people into 8 states and analyze rumor and anti-rumor dissemination in an accurate way. Furthermore, official rumor refutation is considered in rumor propagation. The models and the results are essential for improving the efficiency of rumor refutation and making emergency plans, which help to reduce the possibility of losses in disasters and rumor propagation.
Adaptive Finite Element Methods for Elliptic Problems with Discontinuous Coefficients
Bonito, Andrea; DeVore, Ronald A.; Nochetto, Ricardo H.
2013-01-01
Elliptic PDEs with discontinuous diffusion coefficients occur in application domains such as diffusions through porous media, electromagnetic field propagation on heterogeneous media, and diffusion processes on rough surfaces. The standard approach to numerically treating such problems using finite element methods is to assume that the discontinuities lie on the boundaries of the cells in the initial triangulation. However, this does not match applications where discontinuities occur on curves, surfaces, or manifolds, and could even be unknown beforehand. One of the obstacles to treating such discontinuity problems is that the usual perturbation theory for elliptic PDEs assumes bounds for the distortion of the coefficients in the L∞ norm and this in turn requires that the discontinuities are matched exactly when the coefficients are approximated. We present a new approach based on distortion of the coefficients in an Lq norm with q < ∞ which therefore does not require the exact matching of the discontinuities. We then use this new distortion theory to formulate new adaptive finite element methods (AFEMs) for such discontinuity problems. We show that such AFEMs are optimal in the sense of distortion versus number of computations, and report insightful numerical results supporting our analysis. © 2013 Societ y for Industrial and Applied Mathematics.
Propagation characteristics of electromagnetic waves in dusty plasma with full ionization
Dan, Li; Guo, Li-Xin; Li, Jiang-Ting
2018-01-01
This study investigates the propagation characteristics of electromagnetic (EM) waves in fully ionized dusty plasmas. The propagation characteristics of fully ionized plasma with and without dust under the Fokker-Planck-Landau (FPL) and Bhatnagar-Gross-Krook (BGK) models are compared to those of weakly ionized plasmas by using the propagation matrix method. It is shown that the FPL model is suitable for the analysis of the propagation characteristics of weakly collisional and fully ionized dusty plasmas, as is the BGK model. The influence of varying the dust parameters on the propagation properties of EM waves in the fully ionized dusty plasma was analyzed using the FPL model. The simulation results indicated that the densities and average radii of dust grains influence the reflection and transmission coefficients of fully ionized dusty plasma slabs. These results may be utilized to analyze the effects of interaction between EM waves and dusty plasmas, such as those associated with hypersonic vehicles.
Physics-based statistical model and simulation method of RF propagation in urban environments
Pao, Hsueh-Yuan; Dvorak, Steven L.
2010-09-14
A physics-based statistical model and simulation/modeling method and system of electromagnetic wave propagation (wireless communication) in urban environments. In particular, the model is a computationally efficient close-formed parametric model of RF propagation in an urban environment which is extracted from a physics-based statistical wireless channel simulation method and system. The simulation divides the complex urban environment into a network of interconnected urban canyon waveguides which can be analyzed individually; calculates spectral coefficients of modal fields in the waveguides excited by the propagation using a database of statistical impedance boundary conditions which incorporates the complexity of building walls in the propagation model; determines statistical parameters of the calculated modal fields; and determines a parametric propagation model based on the statistical parameters of the calculated modal fields from which predictions of communications capability may be made.
International Nuclear Information System (INIS)
Kecskemety, K.; Gombosi, T.I.; Somogyi, A.J.
1981-01-01
Intensity-time profiles in similar energy intervals measured by the longitudinally separated HELIOS 1/2 and PROGNOZ 6 spacecrafts are used to study coronal injection and interplanetary propagation. The scattering mean free path for the interplanetary propagation turns out to be essentially the same for the three locations. If the coronal propagation is described by a Reid-Axford type diffusion model, the diffusion coefficient is approximately constant below 200 MV (about 0.1 AU), while above this rigidity is exhibits a power law increase
Signal propagation along the axon.
Rama, Sylvain; Zbili, Mickaël; Debanne, Dominique
2018-03-08
Axons link distant brain regions and are usually considered as simple transmission cables in which reliable propagation occurs once an action potential has been generated. Safe propagation of action potentials relies on specific ion channel expression at strategic points of the axon such as nodes of Ranvier or axonal branch points. However, while action potentials are generally considered as the quantum of neuronal information, their signaling is not entirely digital. In fact, both their shape and their conduction speed have been shown to be modulated by activity, leading to regulations of synaptic latency and synaptic strength. We report here newly identified mechanisms of (1) safe spike propagation along the axon, (2) compartmentalization of action potential shape in the axon, (3) analog modulation of spike-evoked synaptic transmission and (4) alteration in conduction time after persistent regulation of axon morphology in central neurons. We discuss the contribution of these regulations in information processing. Copyright © 2018 Elsevier Ltd. All rights reserved.
Wave propagation in electromagnetic media
International Nuclear Information System (INIS)
Davis, J.L.
1990-01-01
This book is concerned with wave propagation in reacting media, specifically in electromagnetic materials. An account is presented of the mathematical methods of wave phenomena in electromagnetic materials. The author presents the theory of time-varying electromagnetic fields, which involves a discussion of Faraday's laws, Maxwell's equations and their application to electromagnetic wave propagation under a variety of conditions. The author gives a discussion of magnetohydrodynamics and plasma physics. Chapters are included on quantum mechanics and the theory of relativity. The mathematical foundation of electromagnetic waves vis a vis partial differential equations is discussed
Vegetative propagation of Bambusa vulgaris
Directory of Open Access Journals (Sweden)
Rafael Malfitano Braga
2017-06-01
Full Text Available Bamboo is an important source of raw material of multiple uses. The development of simple techniques for its propagation is a practical way to enable its implementation in ownership of low technology. The present work had the objective of evaluating artisanal propagation methods for Bambusa vulgaris. Two types of propagules were tested, with buds budded or not, and three relative positions to the removal of vegetative material on the culm. The best propagule was with only one node, extracted from the lower thirds of the stem, presenting 72% of rooting. This result demonstrates its potential for seedling production of this species under low tech.
Nonequilibrium theory of flame propagation
International Nuclear Information System (INIS)
Merzhanov, A.G.
1995-01-01
The nonequilibrium theory of flame propagation is considered as applied to the following three processes of wave propagation: the combustion waves of the second kind, the combustion waves with broad reaction zones, and the combustion waves with chemical stages. Kinetic and combustion wave parameters are presented for different in composition mixtures of boron and transition metals, such as Zr, Hf, Ti, Nb, Ta, Mo, as well as for the Ta-N, Zr-C-H, Nb-B-O systems to illustrate specific features of the above-mentioned processes [ru
Friction analysis of kinetic schemes : the friction coefficient
Lolkema, Juke S.
1995-01-01
Friction analysis is proposed as the application of general control analysis to single enzymes to describe the control of elementary kinetic steps on the overall catalytic rate. For each transition, a friction coefficient is defined that measures the sensitivity of the turnover rate to the free
Modelling the change in the oxidation coefficient during the aerobic ...
African Journals Online (AJOL)
In this work the aerobic degradation of phenol by acclimated activated sludge was studied. Results demonstrate that while the phenol removal rate by acclimated activated sludge follows the Monod model, the oxygen uptake rate obeys a Haldane-type equation. The phenol oxidation coefficient obtained at different intial ...
Study of transport coefficients of nanodiamond nanofluids
Pryazhnikov, M. I.; Minakov, A. V.; Guzei, D. V.
2017-09-01
Experimental data on the thermal conductivity coefficient and viscosity coefficient of nanodiamond nanofluids are presented. Distilled water and ethylene glycol were used as the base fluid. Dependences of transport coefficients on concentration are obtained. It was shown that the thermal conductivity coefficient increases with increasing nanodiamonds concentration. It was shown that base fluids properties and nanodiamonds concentration affect on the rheology of nanofluids.
Van Allen Probe observations of EMIC wave propagation in the inner magnetosphere
Saikin, A.; Zhang, J.; Smith, C. W.; Spence, H. E.; Torbert, R. B.; Kletzing, C.; Wygant, J. R.
2017-12-01
This study examines the propagation of inner magnetosphere (L vector, , analysis on all observed EMIC wave events to determine the direction of propagation, with bi-directionally propagating EMIC waves indicating the presence of the EMIC wave source region. EMIC waves were considered bi-directional (i.e., in the source region) if at least two wave packets exhibited opposing flux components, and (W/km2), consistently for 60 seconds. Events not observed to have opposing flux components are considered unidirectional. EMIC wave events observed at relatively high magnetic latitudes, generally, are found to propagate away from the magnetic equator (i.e., unidirectional). Bi-directionally propagating EMIC waves are preferably observed at lower magnetic latitudes. The occurrence rate, spatial distribution, and the energy propagation angle of both unidirectionally and bi-directionally propagating EMIC waves are examined with respect to L, MLT, and MLAT.
Rapid assessment of nonlinear optical propagation effects in dielectrics
Hoyo, J. Del; de La Cruz, A. Ruiz; Grace, E.; Ferrer, A.; Siegel, J.; Pasquazi, A.; Assanto, G.; Solis, J.
2015-01-01
Ultrafast laser processing applications need fast approaches to assess the nonlinear propagation of the laser beam in order to predict the optimal range of processing parameters in a wide variety of cases. We develop here a method based on the simple monitoring of the nonlinear beam shaping against numerical prediction. The numerical code solves the nonlinear Schrödinger equation with nonlinear absorption under simplified conditions by employing a state-of-the art computationally efficient approach. By comparing with experimental results we can rapidly estimate the nonlinear refractive index and nonlinear absorption coefficients of the material. The validity of this approach has been tested in a variety of experiments where nonlinearities play a key role, like spatial soliton shaping or fs-laser waveguide writing. The approach provides excellent results for propagated power densities for which free carrier generation effects can be neglected. Above such a threshold, the peculiarities of the nonlinear propagation of elliptical beams enable acquiring an instantaneous picture of the deposition of energy inside the material realistic enough to estimate the effective nonlinear refractive index and nonlinear absorption coefficients that can be used for predicting the spatial distribution of energy deposition inside the material and controlling the beam in the writing process.
Evaluation of Rock Joint Coefficients
Audy, Ondřej; Ficker, Tomáš
2017-10-01
A computer method for evaluation of rock joint coefficients is described and several applications are presented. The method is based on two absolute numerical indicators that are formed by means of the Fourier replicas of rock joint profiles. The first indicator quantifies the vertical depth of profiles and the second indicator classifies wavy character of profiles. The absolute indicators have replaced the formerly used relative indicators that showed some artificial behavior in some cases. This contribution is focused on practical computations testing the functionality of the newly introduced indicators.
Propagation of Singularities and Some Inverse Problems in Wave Propagation
National Research Council Canada - National Science Library
Symes, William W
1989-01-01
... in various useful coefficient classes, separation of scales,...We explain the essential role of travel time in the study of these problems, and show how its function may be generalized to multidimensional (i.e. non-layered) problems.
Crack diffusion coefficient - A candidate fracture toughness parameter for short fiber composites
Mull, M. A.; Chudnovsky, A.; Moet, A.
1987-01-01
In brittle matrix composites, crack propagation occurs along random trajectories reflecting the heterogeneous nature of the strength field. Considering the crack trajectory as a diffusive process, the 'crack diffusion coefficient' is introduced. From fatigue crack propagation experiments on a set of identical SEN polyester composite specimens, the variance of the crack tip position along the loading axis is found to be a linear function of the effective 'time'. The latter is taken as the effective crack length. The coefficient of proportionality between variance of the crack trajectory and the effective crack length defines the crack diffusion coefficient D which is found in the present study to be 0.165 mm. This parameter reflects the ability of the composite to deviate the crack from the energetically most efficient path and thus links fracture toughness to the microstructure.
Correlation coefficients in neutron β-decay
International Nuclear Information System (INIS)
Byrne, J.
1978-01-01
The various angular and polarisation coefficients in neutron decay are the principal sources of information on the β-interaction. Measurements of the electron-neutrino angular correlation coefficient (a), the neutron-spin-electron-momentum correlation coefficient (A), the neutron-spin-neutrino-momentum correlation coefficient (B), and the triple correlation coefficient D and time-reversal invariance are reviewed and the results discussed. (U.K.)
Kumarasiri, Akila; Siddiqui, Farzan; Liu, Chang; Yechieli, Raphael; Shah, Mira; Pradhan, Deepak; Zhong, Hualiang; Chetty, Indrin J; Kim, Jinkoo
2014-12-01
To evaluate the clinical potential of deformable image registration (DIR)-based automatic propagation of physician-drawn contours from a planning CT to midtreatment CT images for head and neck (H&N) adaptive radiotherapy. Ten H&N patients, each with a planning CT (CT1) and a subsequent CT (CT2) taken approximately 3-4 week into treatment, were considered retrospectively. Clinically relevant organs and targets were manually delineated by a radiation oncologist on both sets of images. Four commercial DIR algorithms, two B-spline-based and two Demons-based, were used to deform CT1 and the relevant contour sets onto corresponding CT2 images. Agreement of the propagated contours with manually drawn contours on CT2 was visually rated by four radiation oncologists in a scale from 1 to 5, the volume overlap was quantified using Dice coefficients, and a distance analysis was done using center of mass (CoM) displacements and Hausdorff distances (HDs). Performance of these four commercial algorithms was validated using a parameter-optimized Elastix DIR algorithm. All algorithms attained Dice coefficients of >0.85 for organs with clear boundaries and those with volumes >9 cm(3). Organs with volumes <3 cm(3) and/or those with poorly defined boundaries showed Dice coefficients of ∼ 0.5-0.6. For the propagation of small organs (<3 cm(3)), the B-spline-based algorithms showed higher mean Dice values (Dice = 0.60) than the Demons-based algorithms (Dice = 0.54). For the gross and planning target volumes, the respective mean Dice coefficients were 0.8 and 0.9. There was no statistically significant difference in the Dice coefficients, CoM, or HD among investigated DIR algorithms. The mean radiation oncologist visual scores of the four algorithms ranged from 3.2 to 3.8, which indicated that the quality of transferred contours was "clinically acceptable with minor modification or major modification in a small number of contours." Use of DIR-based contour propagation in the routine
International Nuclear Information System (INIS)
Kumarasiri, Akila; Siddiqui, Farzan; Liu, Chang; Yechieli, Raphael; Shah, Mira; Pradhan, Deepak; Zhong, Hualiang; Chetty, Indrin J.; Kim, Jinkoo
2014-01-01
Purpose: To evaluate the clinical potential of deformable image registration (DIR)-based automatic propagation of physician-drawn contours from a planning CT to midtreatment CT images for head and neck (H and N) adaptive radiotherapy. Methods: Ten H and N patients, each with a planning CT (CT1) and a subsequent CT (CT2) taken approximately 3–4 week into treatment, were considered retrospectively. Clinically relevant organs and targets were manually delineated by a radiation oncologist on both sets of images. Four commercial DIR algorithms, two B-spline-based and two Demons-based, were used to deform CT1 and the relevant contour sets onto corresponding CT2 images. Agreement of the propagated contours with manually drawn contours on CT2 was visually rated by four radiation oncologists in a scale from 1 to 5, the volume overlap was quantified using Dice coefficients, and a distance analysis was done using center of mass (CoM) displacements and Hausdorff distances (HDs). Performance of these four commercial algorithms was validated using a parameter-optimized Elastix DIR algorithm. Results: All algorithms attained Dice coefficients of >0.85 for organs with clear boundaries and those with volumes >9 cm 3 . Organs with volumes <3 cm 3 and/or those with poorly defined boundaries showed Dice coefficients of ∼0.5–0.6. For the propagation of small organs (<3 cm 3 ), the B-spline-based algorithms showed higher mean Dice values (Dice = 0.60) than the Demons-based algorithms (Dice = 0.54). For the gross and planning target volumes, the respective mean Dice coefficients were 0.8 and 0.9. There was no statistically significant difference in the Dice coefficients, CoM, or HD among investigated DIR algorithms. The mean radiation oncologist visual scores of the four algorithms ranged from 3.2 to 3.8, which indicated that the quality of transferred contours was “clinically acceptable with minor modification or major modification in a small number of contours.” Conclusions
Energy Technology Data Exchange (ETDEWEB)
Kumarasiri, Akila, E-mail: akumara1@hfhs.org; Siddiqui, Farzan; Liu, Chang; Yechieli, Raphael; Shah, Mira; Pradhan, Deepak; Zhong, Hualiang; Chetty, Indrin J.; Kim, Jinkoo [Department of Radiation Oncology, Henry Ford Health System, Detroit, Michigan 48202 (United States)
2014-12-15
Purpose: To evaluate the clinical potential of deformable image registration (DIR)-based automatic propagation of physician-drawn contours from a planning CT to midtreatment CT images for head and neck (H and N) adaptive radiotherapy. Methods: Ten H and N patients, each with a planning CT (CT1) and a subsequent CT (CT2) taken approximately 3–4 week into treatment, were considered retrospectively. Clinically relevant organs and targets were manually delineated by a radiation oncologist on both sets of images. Four commercial DIR algorithms, two B-spline-based and two Demons-based, were used to deform CT1 and the relevant contour sets onto corresponding CT2 images. Agreement of the propagated contours with manually drawn contours on CT2 was visually rated by four radiation oncologists in a scale from 1 to 5, the volume overlap was quantified using Dice coefficients, and a distance analysis was done using center of mass (CoM) displacements and Hausdorff distances (HDs). Performance of these four commercial algorithms was validated using a parameter-optimized Elastix DIR algorithm. Results: All algorithms attained Dice coefficients of >0.85 for organs with clear boundaries and those with volumes >9 cm{sup 3}. Organs with volumes <3 cm{sup 3} and/or those with poorly defined boundaries showed Dice coefficients of ∼0.5–0.6. For the propagation of small organs (<3 cm{sup 3}), the B-spline-based algorithms showed higher mean Dice values (Dice = 0.60) than the Demons-based algorithms (Dice = 0.54). For the gross and planning target volumes, the respective mean Dice coefficients were 0.8 and 0.9. There was no statistically significant difference in the Dice coefficients, CoM, or HD among investigated DIR algorithms. The mean radiation oncologist visual scores of the four algorithms ranged from 3.2 to 3.8, which indicated that the quality of transferred contours was “clinically acceptable with minor modification or major modification in a small number of contours
The numerical simulation of Lamb wave propagation in laser welding of stainless steel
Zhang, Bo; Liu, Fang; Liu, Chang; Li, Jingming; Zhang, Baojun; Zhou, Qingxiang; Han, Xiaohui; Zhao, Yang
2017-12-01
In order to explore the Lamb wave propagation in laser welding of stainless steel, the numerical simulation is used to show the feature of Lamb wave. In this paper, according to Lamb dispersion equation, excites the Lamb wave on the edge of thin stainless steel plate, and presents the reflection coefficient for quantizing the Lamb wave energy, the results show that the reflection coefficient is increased with the welding width increasing,
Physics of Earthquake Rupture Propagation
Xu, Shiqing; Fukuyama, Eiichi; Sagy, Amir; Doan, Mai-Linh
2018-05-01
A comprehensive understanding of earthquake rupture propagation requires the study of not only the sudden release of elastic strain energy during co-seismic slip, but also of other processes that operate at a variety of spatiotemporal scales. For example, the accumulation of the elastic strain energy usually takes decades to hundreds of years, and rupture propagation and termination modify the bulk properties of the surrounding medium that can influence the behavior of future earthquakes. To share recent findings in the multiscale investigation of earthquake rupture propagation, we held a session entitled "Physics of Earthquake Rupture Propagation" during the 2016 American Geophysical Union (AGU) Fall Meeting in San Francisco. The session included 46 poster and 32 oral presentations, reporting observations of natural earthquakes, numerical and experimental simulations of earthquake ruptures, and studies of earthquake fault friction. These presentations and discussions during and after the session suggested a need to document more formally the research findings, particularly new observations and views different from conventional ones, complexities in fault zone properties and loading conditions, the diversity of fault slip modes and their interactions, the evaluation of observational and model uncertainties, and comparison between empirical and physics-based models. Therefore, we organize this Special Issue (SI) of Tectonophysics under the same title as our AGU session, hoping to inspire future investigations. Eighteen articles (marked with "this issue") are included in this SI and grouped into the following six categories.
Invisibility cloaking without superluminal propagation
Energy Technology Data Exchange (ETDEWEB)
Perczel, Janos; Leonhardt, Ulf [School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews KY16 9SS (United Kingdom); Tyc, Tomas, E-mail: jp394@st-andrews.ac.uk, E-mail: tomtyc@physics.muni.cz, E-mail: ulf@st-andrews.ac.uk [Faculty of Science, Kotlarska 2 and Faculty of Informatics, Botanicka 68a, Masaryk University, 61137 Brno (Czech Republic)
2011-08-15
Conventional cloaking based on Euclidean transformation optics requires that the speed of light should tend to infinity on the inner surface of the cloak. Non-Euclidean cloaking still needs media with superluminal propagation. Here we show by giving an example that this is no longer necessary.
Propagating Class and Method Combination
DEFF Research Database (Denmark)
Ernst, Erik
1999-01-01
number of implicit combinations. For example, it is possible to specify separate aspects of a family of classes, and then combine several aspects into a full-fledged class family. The combination expressions would explicitly combine whole-family aspects, and by propagation implicitly combine the aspects...
Propagation of electromagnetic waves in a weakly ionized dusty plasma
International Nuclear Information System (INIS)
Jia, Jieshu; Yuan, Chengxun; Gao, Ruilin; Wang, Ying; Liu, Yaoze; Gao, Junying; Zhou, Zhongxiang; Sun, Xiudong; Li, Hui; Wu, Jian; Pu, Shaozhi
2015-01-01
Propagation properties of electromagnetic (EM) waves in weakly ionized dusty plasmas are the subject of this study. Dielectric relation for EM waves propagating at a weakly ionized dusty plasma is derived based on the Boltzmann distribution law while considering the collision and charging effects of dust grains. The propagation properties of EM energy in dusty plasma of rocket exhaust are numerically calculated and studied, utilizing the parameters of rocket exhaust plasma. Results indicate that increase of dust radius and density enhance the reflection and absorption coefficient. High dust radius and density make the wave hardly transmit through the dusty plasmas. Interaction enhancements between wave and dusty plasmas are developed through effective collision frequency improvements. Numerical results coincide with observed results by indicating that GHz band wave communication is effected by dusty plasma as the presence of dust grains significantly affect propagation of EM waves in the dusty plasmas. The results are helpful to analyze the effect of dust in plasmas and also provide a theoretical basis for the experiments. (paper)
Study of regularities in propagation of thermal fatigue cracks
International Nuclear Information System (INIS)
Tachkova, N.G.; Sobolev, N.D.; Egorov, V.I.; Rostovtsev, Yu.V.; Ivanov, Yu.S.; Sirotin, V.L.
1978-01-01
Regularities in the propagation of thermal fatigue cracks in the Cr-Ni steels of the austenite class depending upon deformation conditions in the crack zone, have been considered. Thin-walled tube samples of the Kh16N40, Kh18N20 and Kh16N15 steels have been tested in the 10O reversible 400 deg C and 100 reversible 500 deg C regimes. The samples have possessed a slot-shaped stress concentrator. Stress intensity pseudocoefficient has been calculated for the correlation of experimental data. The formula for determining crack propagation rate has been obtained. The experiments permit to conclude that propagation rate of thermal fatigue cracks in the above steels depends upon the scope of plastic deformation during a cycle and stress intensity pseudocoefficient, and is determined by plastic deformation resistance during thermal cyclic loading
Wang, Xiaohui; Song, Yingxiong
2018-02-01
By exploiting the non-Kolmogorov model and Rytov approximation theory, a propagation model of Bessel-Gaussian vortex beams (BGVB) propagating in a subway tunnel is derived. Based on the propagation model, a model of orbital angular momentum (OAM) mode probability distribution is established to evaluate the propagation performance when the beam propagates along both longitudinal and transverse directions in the subway tunnel. By numerical simulations and experimental verifications, the influences of the various parameters of BGVB and turbulence on the OAM mode probability distribution are evaluated, and the results of simulations are consistent with the experimental statistics. The results verify that the middle area of turbulence is more beneficial for the vortex beam propagation than the edge; when the BGVB propagates along the longitudinal direction in the subway tunnel, the effects of turbulence on the OAM mode probability distribution can be decreased by selecting a larger anisotropy parameter, smaller coherence length, larger non-Kolmogorov power spectrum coefficient, smaller topological charge number, deeper subway tunnel, lower train speed, and longer wavelength. When the BGVB propagates along the transverse direction, the influences can be also mitigated by adopting a larger topological charge number, less non-Kolmogorov power spectrum coefficient, smaller refractive structure index, shorter wavelength, and shorter propagation distance.
International Nuclear Information System (INIS)
Hariri, A; Sarikhani, S
2014-01-01
On the basis of a model of a geometrically dependent gain coefficient, the amplified spontaneous emission (ASE) spectral width was calculated analytically for the nearly resonant transition of ν ∼ ν 0 , and also numerically for a wide range of transition frequencies. For this purpose, the intensity rate equation was used under unsaturated and saturated conditions. For verifying the proposed model, reported measurements of the ASE energy versus the excitation length for a KrF laser were used. For the excitation length of l = 84 cm corresponding to single-path propagation, the ASE spectral width for the homogeneously broadened transition was calculated to be 6.28 Å, to be compared with the measured 4.1 Å spectral width reported for a KrF oscillator utilizing a two-mirror resonator. With the gain parameters obtained from the ASE energy measurements, the unsaturated and saturated gain coefficients for l = 84 cm were calculated to be 0.042 cm −1 and 0.014 cm −1 , respectively. These values of the gain coefficient are comparable to but slightly lower than the measured gain coefficient for laser systems of 80–100 cm excitation lengths reported from different laboratories. (letter)
Diffusion coefficients of decay products of radon and thoron
International Nuclear Information System (INIS)
Raghunath, B.; Kotrappa, P.
1979-01-01
The diffusion coefficients of the decay products of radon and thoron have relevance in the evaluation of inhalation hazards in uranium and thorium processing industries. A recently developed diffusion sampler, based on Mercer's theory of diffusional deposition between the concentric circular plates, has been used for determining the diffusion coefficients of the unattached decay products of radon and thoron (RaA, RaB, RaC and ThB). Experiments were conducted at different ventilation rates (6 and 60 changes/hr) at different relative humidities (10 and 90%) and both in air and argon atmospheres. Diffusion coefficients were found to increase with increasing ventilation rates and were found to decrease at higher relative humidities, the effect being more marked at lower ventilation rates. Both of these effects were less pronounced in argon than in air. Results are discussed in light of the known properties of these decay products. (author)
Quasinormal modes and classical wave propagation in analogue black holes
International Nuclear Information System (INIS)
Berti, Emanuele; Cardoso, Vitor; Lemos, Jose P.S.
2004-01-01
Many properties of black holes can be studied using acoustic analogues in the laboratory through the propagation of sound waves. We investigate in detail sound wave propagation in a rotating acoustic (2+1)-dimensional black hole, which corresponds to the 'draining bathtub' fluid flow. We compute the quasinormal mode frequencies of this system and discuss late-time power-law tails. Because of the presence of an ergoregion, waves in a rotating acoustic black hole can be superradiantly amplified. We also compute superradiant reflection coefficients and instability time scales for the acoustic black hole bomb, the equivalent of the Press-Teukolsky black hole bomb. Finally we discuss quasinormal modes and late-time tails in a nonrotating canonical acoustic black hole, corresponding to an incompressible, spherically symmetric (3+1)-dimensional fluid flow
EM wave propagation analysis in plasma covered radar absorbing material
Singh, Hema; Rawat, Harish Singh
2017-01-01
This book focuses on EM propagation characteristics within multilayered plasma-dielectric-metallic media. The method used for analysis is impedance transformation method. Plasma covered radar absorbing material is approximated as a multi-layered dielectric medium. The plasma is considered to be bounded homogeneous/inhomogeneous medium. The reflection coefficient and hence return loss is analytically derived. The role of plasma parameters, such as electron density, collision frequency, plasma thickness, and plasma density profile in the absorption behavior of multi-layered plasma-RAM structure is described. This book provides a clearer picture of EM propagation within plasma. The reader will get an insight of plasma parameters that play significant role in deciding the absorption characteristics of plasma covered surfaces.
Propagation and scattering of light in fluctuating media
Kuz'min, V. L.; Romanov, V. P.; Zubkov, L. A.
1994-11-01
The monograph deals with the problems of the propagation and scattering of light in molecular media. The explicit statistical mechanical averaging procedure for the equations of electrodynamics is developed. It permits to transform the molecular level description into the macroscopic one for the electrodynamics of the fluctuating media. In the framework of such an approach, the problems of the molecular correlation contribution into the dielectric permeability, of the calculation of the reflection coefficients with an account of surface layers and of the multiple light scattering are considered. The developed theory is applied to the description of the critical opalescence, the coherent backscattering enhancement, the light scattering depolarization phenomena and the propagation and scattering of light in anisotropic media, including the case of liquid crystals.
Bubble propagation in Hele-Shaw channels with centred constrictions
Franco-Gómez, Andrés; Thompson, Alice B.; Hazel, Andrew L.; Juel, Anne
2018-04-01
We study the propagation of finite bubbles in a Hele-Shaw channel, where a centred occlusion (termed a rail) is introduced to provide a small axially uniform depth constriction. For bubbles wide enough to span the channel, the system’s behaviour is similar to that of semi-infinite fingers and a symmetric static solution is stable. Here, we focus on smaller bubbles, in which case the symmetric static solution is unstable and the static bubble is displaced towards one of the deeper regions of the channel on either side of the rail. Using a combination of experiments and numerical simulations of a depth-averaged model, we show that a bubble propagating axially due to a small imposed flow rate can be stabilised in a steady symmetric mode centred on the rail through a subtle interaction between stabilising viscous forces and destabilising surface tension forces. However, for sufficiently large capillary numbers Ca, the ratio of viscous to surface tension forces, viscous forces in turn become destabilising thus returning the bubble to an off-centred propagation regime. With decreasing bubble size, the range of Ca for which steady centred propagation is stable decreases, and eventually vanishes through the coalescence of two supercritical pitchfork bifurcations. The depth-averaged model is found to accurately predict all the steady modes of propagation observed experimentally, and provides a comprehensive picture of the underlying steady bifurcation structure. However, for sufficiently large imposed flow rates, we find that initially centred bubbles do not converge onto a steady mode of propagation. Instead they transiently explore weakly unstable steady modes, an evolution which results in their break-up and eventual settling into a steady propagating state of changed topology.
Extinction Coefficient of Gold Nanostars.
de Puig, Helena; Tam, Justina O; Yen, Chun-Wan; Gehrke, Lee; Hamad-Schifferli, Kimberly
2015-07-30
Gold nanostars (NStars) are highly attractive for biological applications due to their surface chemistry, facile synthesis and optical properties. Here, we synthesize NStars in HEPES buffer at different HEPES/Au ratios, producing NStars of different sizes and shapes, and therefore varying optical properties. We measure the extinction coefficient of the synthesized NStars at their maximum surface plasmon resonances (SPR), which range from 5.7 × 10 8 to 26.8 × 10 8 M -1 cm -1 . Measured values correlate with those obtained from theoretical models of the NStars using the discrete dipole approximation (DDA), which we use to simulate the extinction spectra of the nanostars. Finally, because NStars are typically used in biological applications, we conjugate DNA and antibodies to the NStars and calculate the footprint of the bound biomolecules.
Kerr scattering coefficients via isomonodromy
Energy Technology Data Exchange (ETDEWEB)
Cunha, Bruno Carneiro da [Departamento de Física, Universidade Federal de Pernambuco,50670-901, Recife, Pernambuco (Brazil); Novaes, Fábio [International Institute of Physics, Federal University of Rio Grande do Norte,Av. Odilon Gomes de Lima 1722, Capim Macio, Natal-RN 59078-400 (Brazil)
2015-11-23
We study the scattering of a massless scalar field in a generic Kerr background. Using a particular gauge choice based on the current conservation of the radial equation, we give a generic formula for the scattering coefficient in terms of the composite monodromy parameter σ between the inner and the outer horizons. Using the isomonodromy flow, we calculate σ exactly in terms of the Painlevé V τ-function. We also show that the eigenvalue problem for the angular equation (spheroidal harmonics) can be calculated using the same techniques. We use recent developments relating the Painlevé V τ-function to Liouville irregular conformal blocks to claim that this scattering problem is solved in the combinatorial sense, with known expressions for the τ-function near the critical points.
Sorption Coefficients for Iodine, Silver, and Cesium on Dust Particles
International Nuclear Information System (INIS)
Stempniewicz, M.M.; Goede, P.
2014-01-01
This paper describes the work performed to find relevant experimental data and find the sorption coefficients that represent well the available data for cesium, iodine, and silver on dust particles. The purpose of this work is to generate a set of coefficients that may be recommended for the computer code users. The work was performed using the computer code SPECTRA. Calculations were performed for the following data: • I-131 on AVR dust; • Ag-110m on AVR dust; • Cs-13 and Cs-137 on AVR dust. Available data was matched using the SPECTRA Sorption Model. S = A(T) · C_V-B(T) · C_d. The results are summarized as follows: • The available data can be correlated. The data scatter is about 4 orders of magnitude. Therefore the coefficients of the Langmuir isotherms vary by 4 orders of magnitude. • Sorption rates are higher at low temperatures and lower at high temperatures. This tendency has been observed in the data compiled at Oak Ridge. It is therefore surmised that the highest value of the sorption coefficients are appropriate for the low temperatures and the lowest value of the sorption coefficients are appropriate for the high temperatures. The recommended sorption coefficients are presented in this paper. • The present set of coefficients is very rough and should be a subject for future verification against experimental data. (author)
Fast fracture: an adiabatic restriction on thermally activated crack propagation
Energy Technology Data Exchange (ETDEWEB)
Burns, S.J.
1978-01-01
Slow, isothermal, crack propagation is widely suspected to be rate controlled by thermally activated plastic deformation in the crack tip region. Adiabatic conditions are generally established in the fracture modified material at the tip of a crack during fast fracture. The temperature of this material is not the temperature of the specimen and is generally not measured during fast fracture. Thus, a complete thermodynamic description of adiabatic crack propagation data can not be made. When the slow, isothermal, crack propagation mechanisms are assumed to be operative during adiabatic crack propagation then certain predictions can be made. For example: the changes in the driving force due to temperature and rate are always in the opposite sense; there is no minimum in the driving force versus crack velocity without a change in mechanism; the temperature rise in the crack tip fracture modified material is determined mainly by the activation enthalpy for crack propagation; the interpretation of fast fracture structural steel data from simple plastic models is suspect since these materials have dissimilar isothermal temperature dependencies.
Use of appropriate absorption coefficients in gamma-ray dosimetry
International Nuclear Information System (INIS)
Gopinath, D.V.; Natarajan, A.; Subbaiah, K.V.
1985-01-01
The current use of the different types of absorption coefficients in the computation of γ-ray energy deposition rates and air dose is critically analyzed. Transport calculations are presented to bring out the errors associated with the use of different absorption coefficients. It is observed that except for source energies in the range of 0.3 to 3.0 MeV the consistent use of the absorption coefficient, μ/sub a/ results in an underestimate of the air dose everywhere and of energy deposition at regions away from source. The underestimate becomes more significant with increased atomic number (Z) of the medium. Based on the computations and analysis it is concluded that the absorption coefficients μ/sub a/ and μ/sub k/ are of very limited use in practical γ-ray dosimetry
[Electroencephalogram Feature Selection Based on Correlation Coefficient Analysis].
Zhou, Jinzhi; Tang, Xiaofang
2015-08-01
In order to improve the accuracy of classification with small amount of motor imagery training data on the development of brain-computer interface (BCD systems, we proposed an analyzing method to automatically select the characteristic parameters based on correlation coefficient analysis. Throughout the five sample data of dataset IV a from 2005 BCI Competition, we utilized short-time Fourier transform (STFT) and correlation coefficient calculation to reduce the number of primitive electroencephalogram dimension, then introduced feature extraction based on common spatial pattern (CSP) and classified by linear discriminant analysis (LDA). Simulation results showed that the average rate of classification accuracy could be improved by using correlation coefficient feature selection method than those without using this algorithm. Comparing with support vector machine (SVM) optimization features algorithm, the correlation coefficient analysis can lead better selection parameters to improve the accuracy of classification.
Path coefficient analysis of zinc dynamics in varying soil environment
International Nuclear Information System (INIS)
Rattan, R.K.; Phung, C.V.; Singhal, S.K.; Deb, D.L.; Singh, A.K.
1994-01-01
Influence of soil properties on labile zinc, as measured by diethylene-triamine pentaacetic acid (DTPA) and zinc-65, and self-diffusion coefficients of zinc was assessed on 22 surface soil samples varying widely in their characteristics following linear regression and path coefficient analysis techniques. DTPA extractable zinc could be predicted from organic carbon status and pH of the soil with a highly significant coefficient of determination (R 2 =0.84 ** ). Ninety seven per cent variation in isotopically exchangeable zinc was explained by pH, clay content and cation exchange capacity (CEC) of soil. The self-diffusion coefficients (DaZn and DpZn) and buffer power of zinc exhibited exponential relationship with soil properties, pH being the most dominant one. Soil properties like organic matter, clay content etc. exhibited indirect effects on zinc diffusion rates via pH only. (author). 13 refs., 6 tabs
International Nuclear Information System (INIS)
Frosio, Thomas; Bonaccorsi, Thomas; Blaise, Patrick
2016-01-01
Highlights: • Hybrid methods are developed for uncertainty propagation. • These methods take into account the flux perturbation in the coupled problem. • We show that OAT and MC methods give coherent results, except for Pearson correlations. • Local sensitivity analysis is performed. - Abstract: A novel method has been developed to calculate sensitivity coefficients in coupled Boltzmann/Bateman problem for nuclear data (ND) uncertainties propagation on the reactivity. Different uncertainty propagation methodologies, such as One-At-a-Time (OAT) and hybrid Monte-Carlo/deterministic methods have been tested and are discussed on an actual example of ND uncertainty problem on a Material Testing Reactor (MTR) benchmark. Those methods, unlike total Monte Carlo (MC) sampling for uncertainty propagation and quantification (UQ), allow obtaining sensitivity coefficients, as well as Bravais–Pearson correlations values between Boltzmann and Bateman, during the depletion calculation for global neutronics parameters such as the effective multiplication coefficient. The methodologies are compared to a pure MC sampling method, usually considered as the “reference” method. It is shown that methodologies can seriously underestimate propagated variances, when Bravais–Pearson correlations on ND are not taken into account in the UQ process.
An information propagation model considering incomplete reading behavior in microblog
Su, Qiang; Huang, Jiajia; Zhao, Xiande
2015-02-01
Microblog is one of the most popular communication channels on the Internet, and has already become the third largest source of news and public opinions in China. Although researchers have studied the information propagation in microblog using the epidemic models, previous studies have not considered the incomplete reading behavior among microblog users. Therefore, the model cannot fit the real situations well. In this paper, we proposed an improved model entitled Microblog-Susceptible-Infected-Removed (Mb-SIR) for information propagation by explicitly considering the user's incomplete reading behavior. We also tested the effectiveness of the model using real data from Sina Microblog. We demonstrate that the new proposed model is more accurate in describing the information propagation in microblog. In addition, we also investigate the effects of the critical model parameters, e.g., reading rate, spreading rate, and removed rate through numerical simulations. The simulation results show that, compared with other parameters, reading rate plays the most influential role in the information propagation performance in microblog.
Particle propagation and acceleration in the heliosphere
International Nuclear Information System (INIS)
Valdes-Galicia, J.F.; Quenby, J.J.; Mousas, X.
1988-01-01
A realistic model of interplanetary magnetic field perturbations has been constructed based on data taken on board spacecraft. The model has been used to study numerically pitch angle scattering suffered by energetic particles (1-100 MeV) as they propagate in the Heliosphere. These numerical experiments allow the determination of the pitch angle diffusion coefficient Dμ and the associated mean free path λ. Dμ is found to be always smaller than implied by quasi linear theory, leading to radial mean free paths (λ r ≅ 0.015 AU) that are at least 3 times larger. Inclusion of solar wind velocity measurements in the model producing V x B random electric fields permits the study of stochastic acceleration caused by these fields. Initial results show that these processes might be able to overcome the effects of adiabatic cooling caused by the expansion of the solar wind and thus be of some influence in cosmic ray acceleration when extrapolated to other astrophysical environments
The propagator of stochastic electrodynamics
Cavalleri, G.
1981-01-01
The "elementary propagator" for the position of a free charged particle subject to the zero-point electromagnetic field with Lorentz-invariant spectral density ~ω3 is obtained. The nonstationary process for the position is solved by the stationary process for the acceleration. The dispersion of the position elementary propagator is compared with that of quantum electrodynamics. Finally, the evolution of the probability density is obtained starting from an initial distribution confined in a small volume and with a Gaussian distribution in the velocities. The resulting probability density for the position turns out to be equal, to within radiative corrections, to ψψ* where ψ is the Kennard wave packet. If the radiative corrections are retained, the present result is new since the corresponding expression in quantum electrodynamics has not yet been found. Besides preceding quantum electrodynamics for this problem, no renormalization is required in stochastic electrodynamics.
Nanosecond air breakdown parameters for electron and microwave beam propagation
International Nuclear Information System (INIS)
Ali, A.W.
1988-01-01
Air breakdown by avalanche ionization plays an important role in the electron beam and microwave propagations. For high electric fields and short pulse applications one needs avalanche ionization parameters for modeling and scaling of experimental devices. However, the breakdown parameters, i.e., the ionization frequency vs E/p (volt. cm -1 . Torr -1 ) in air is uncertain for very high values of E/P. A review is given of the experimental data for the electron drift velocity, the Townsend ionization coefficient in N 2 and O 2 and the ionization frequency and the collision frequency for momentum transfer in air are developed. (author)
Interpretation of heat and density pulse propagation in tokamaks
International Nuclear Information System (INIS)
Sips, A.C.C.; Costley, A.E.; O'Rourke, J.O.
1991-01-01
This paper addresses two key issues in current research on sawtooth induced heat and density pulse measurements in Tokamaks and their interpretation. First, heat and density pulses in JET and TXT show different qualitative behaviour implying substantially different transport coefficients. Second, a new description of the heat pulse has been used to describe measurements cannot be simulated with the widely used diffusive model. In this paper, we show that consistency between all these measurements can be obtained assuming a diffusive propagation for the heat and density pulses and using linearised coupled transport equations. (author) 6 refs., 5 figs
On Polarization and Frequency Dependence of Diffuse Indoor Propagation
DEFF Research Database (Denmark)
Nielsen, Jesper Ødum; Andersen, Jørgen Bach; Pedersen, Gert Frølund
2011-01-01
The room electromagnetics (RE) theory describes the radio propagation in a single room assuming diffuse scat- tering. A main characteristic is the exponential power-delay profile (PDP) decaying with the so-called reverberation time (RT) parameter, depending only on the wall area, the volume...... of the room and an absorption coefficient. The PDP is independent on the location in the room, except for the arrival time. Based on measurements in a room with a spherical array of 16 dual- polarized wideband horn antennas, the current work studies how the RE parameters depend on the receiver (Rx) antenna...
Studies on the mechanism of replication of adenovirus DNA. IV. Discontinuous DNA chain propagation
Vlak, J.M.; Rozijn, Th.H.; Sussenbach, J.S.
The replication of adenovirus type 5 DNA occurs by discontinuous chain propagation via short pieces of DNA. These pieces accumulate if the infected cells are treated with hydroxyurea. They have a sedimentation coefficient of 11 S corresponding to a molecular weight of about 700,000, and they contain
Quantifying wave propagation over a corrugated metal using 5 dBi antennas
CSIR Research Space (South Africa)
Nkosi, MC
2015-09-01
Full Text Available corrugated metal of a shipping container and also in a free space. The free space measurement is used as a reference point to study the influence of the metal on the wave propagation. The transmission coefficient measured over the shipping container...
The effect of submerged obstacles on circular fronts propagating into water at rest
International Nuclear Information System (INIS)
Mvungi, J.R.
1986-03-01
In this paper, the effect of vertical walled obstacles on circular fronts propagating on the surface of shallow water is discussed. The amplitude of the transmitted acceleration waves is determined together with a recurrence relation for the reflection and transmission coefficients at successive obstacle walls. (author)
Factorization of Transport Coefficients in Macroporous Media
DEFF Research Database (Denmark)
Shapiro, Alexander; Stenby, Erling Halfdan
2000-01-01
We prove the fundamental theorem about factorization of the phenomenological coefficients for transport in macroporous media. By factorization we mean the representation of the transport coefficients as products of geometric parameters of the porous medium and the parameters characteristic...
Interprocedural Analysis with Lazy Propagation
DEFF Research Database (Denmark)
Jensen, Simon Holm; Møller, Anders; Thiemann, Peter
2010-01-01
We propose lazy propagation as a technique for flow- and context-sensitive interprocedural analysis of programs with objects and first-class functions where transfer functions may not be distributive. The technique is described formally as a systematic modification of a variant of the monotone fr...... framework and its theoretical properties are shown. It is implemented in a type analysis tool for JavaScript where it results in a significant improvement in performance....
Crack propagation in dynamic thermoelasticity
International Nuclear Information System (INIS)
Bui, H.D.
1980-01-01
We study the singular thermoelastic fields near the crack tip, in the linear strain assumption. The equations are coupled and non linear. The asymptotic expansions of the displacement and the temperature are given for the first and the second order. It is shown that the temperature is singular when the crack propagates. However, this field does not change the dominant singularity of the mechanical field which is the same as that obtained in the theory of isothermal elasticity [fr
Information Propagation on Permissionless Blockchains
Ersoy, Oguzhan; Ren, Zhijie; Erkin, Zekeriya; Lagendijk, Reginald L.
2017-01-01
Blockchain technology, as a decentralized and non-hierarchical platform, has the potential to replace centralized systems. Yet, there are several challenges inherent in the blockchain structure. One of the deficiencies of the existing blockchains is a convenient information propagation technique enhancing incentive-compatibility and bandwidth efficiency. The transition from a centralized system into distributed one brings along game theoretical concerns. Especially for the permissionless bloc...
Quantum noise and superluminal propagation
International Nuclear Information System (INIS)
Segev, Bilha; Milonni, Peter W.; Babb, James F.; Chiao, Raymond Y.
2000-01-01
Causal ''superluminal'' effects have recently been observed and discussed in various contexts. The question arises whether such effects could be observed with extremely weak pulses, and what would prevent the observation of an ''optical tachyon.'' Aharonov, Reznik, and Stern (ARS) [Phys. Rev. Lett. 81, 2190 (1998)] have argued that quantum noise will preclude the observation of a superluminal group velocity when the pulse consists of one or a few photons. In this paper we reconsider this question both in a general framework and in the specific example, suggested by Chiao, Kozhekin, and Kurizki (CKK) [Phys. Rev. 77, 1254 (1996)], of off-resonant, short-pulse propagation in an optical amplifier. We derive in the case of the amplifier a signal-to-noise ratio that is consistent with the general ARS conclusions when we impose their criteria for distinguishing between superluminal propagation and propagation at the speed c. However, results consistent with the semiclassical arguments of CKK are obtained if weaker criteria are imposed, in which case the signal can exceed the noise without being ''exponentially large.'' We show that the quantum fluctuations of the field considered by ARS are closely related to superfluorescence noise. More generally, we consider the implications of unitarity for superluminal propagation and quantum noise and study, in addition to the complete and truncated wave packets considered by ARS, the residual wave packet formed by their difference. This leads to the conclusion that the noise is mostly luminal and delayed with respect to the superluminal signal. In the limit of a very weak incident signal pulse, the superluminal signal will be dominated by the noise part, and the signal-to-noise ratio will therefore be very small. (c) 2000 The American Physical Society
Propagation functions in pseudoparticle fields
International Nuclear Information System (INIS)
Brown, L.S.; Carlitz, R.D.; Creamer, D.B.; Lee, C.
1978-01-01
The Green's functions for massless spinor and vector particles propagating in a self-dual but otherwise arbitrary non-Abelian gauge field are shown to be completely determined by the corrresponding Green's functions of scalar particles. Simple, explicit algebraic expressions are constructed for the scalar Green's functions of isospin-1/2 and isospin-1 particles in the self-dual field of a configuration of n pseudoparticles described by 5n arbitrary parameters
VEGETATIVE PROPAGATION OF Schizolobium amazonicum BY cutting
Directory of Open Access Journals (Sweden)
Poliana Coqueiro Dias
2015-09-01
Full Text Available The aim of this study was to develop a methodology for the vegetative propagation of paricá (Schizolobium amazonicum through cutting, evaluating the effect of IBA (0, 8000, 16000 and 32,000 mg.L-1 on rooting of apical and intermediate stakes. The base of the cuttings were dipped in IBA solution for 10 seconds and then were staked in polyethylene tubes of 110 cm³, filled with organic substrate (Bioplant®. The irrigation of the seedlings was carried out by means of a nebulization system with a uniform flow rate of 7 L.h-1. After 40 days, were evaluated: percentage of survival, rooting percentage, percentage of roots observed at the lower end of the plastic tube, average number of roots, length of roots, presence of calluses, vigor and root dry matter. The results for the characteristics evaluated, with emphasis on survival, showed the highest averages were obtained at intermediate stakes, regardless of the dose of IBA. The highest rooting percentage, root number, length and dry mass of roots, in both types of cuttings was obtained with the highest dose tested of AIB (32,000 mg.L-1. Based on these results, it is concluded that the technique of cutting associated with application of plant growth regulators can be used for vegetative propagation of S. amazonicum.
Propagating separable equalities in an MDD store
DEFF Research Database (Denmark)
Hadzic, Tarik; Hooker, John N.; Tiedemann, Peter
2008-01-01
We present a propagator that achieves MDD consistency for a separable equality over an MDD (multivalued decision diagram) store in pseudo-polynomial time. We integrate the propagator into a constraint solver based on an MDD store introduced in [1]. Our experiments show that the new propagator pro...... provides substantial computational advantage over propagation of two inequality constraints, and that the advantage increases when the maximum width of the MDD store increases....
Anomalous Seebeck coefficient in boron carbides
International Nuclear Information System (INIS)
Aselage, T.L.; Emin, D.; Wood, C.; Mackinnon, I.D.R.; Howard, I.A.
1987-01-01
Boron carbides exhibit an anomalously large Seebeck coefficient with a temperature coefficient that is characteristic of polaronic hopping between inequivalent sites. The inequivalence in the sites is associated with disorder in the solid. The temperature dependence of the Seebeck coefficient for materials prepared by different techniques provides insight into the nature of the disorder
Standards for Standardized Logistic Regression Coefficients
Menard, Scott
2011-01-01
Standardized coefficients in logistic regression analysis have the same utility as standardized coefficients in linear regression analysis. Although there has been no consensus on the best way to construct standardized logistic regression coefficients, there is now sufficient evidence to suggest a single best approach to the construction of a…
Soccer Ball Lift Coefficients via Trajectory Analysis
Goff, John Eric; Carre, Matt J.
2010-01-01
We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin…
Propagation of epithermal neutrons in the empty mesh of the EDF3 reactor. Application of Zeus IV
International Nuclear Information System (INIS)
Brisbois, Jacques; Sonnet, Alain; Rafalovitch, Armand
1969-10-01
The authors report the verification of the Zeus 4 Monte Carlo code by applying it to an actual example of neutron propagation in a large enclosure, the empty mesh of the EDF3 reactor, supplied through the box holes (for the passage of heat transfer fluid ducts). This enclosure is represented by 105 parallelepipedic meshes in which are placed 4 plane and square sources of same cross section as the holes, and emitting inwards in cos θ. Source intensity is determined by flow rate measurements during tests in the air, interpreted by a Zeus-based calculation and channel power measurements during a 387 MW level operation. The presence of ducts is taken into account by applying a global attenuation coefficient to the sources. Calculation and experiment results agree very well in view of geometry complexity [fr
Symmetry chains and adaptation coefficients
International Nuclear Information System (INIS)
Fritzer, H.P.; Gruber, B.
1985-01-01
Given a symmetry chain of physical significance it becomes necessary to obtain states which transform properly with respect to the symmetries of the chain. In this article we describe a method which permits us to calculate symmetry-adapted quantum states with relative ease. The coefficients for the symmetry-adapted linear combinations are obtained, in numerical form, in terms of the original states of the system and can thus be represented in the form of numerical tables. In addition, one also obtains automatically the matrix elements for the operators of the symmetry groups which are involved, and thus for any physical operator which can be expressed either as an element of the algebra or of the enveloping algebra. The method is well suited for computers once the physically relevant symmetry chain, or chains, have been defined. While the method to be described is generally applicable to any physical system for which semisimple Lie algebras play a role we choose here a familiar example in order to illustrate the method and to illuminate its simplicity. We choose the nuclear shell model for the case of two nucleons with orbital angular momentum l = 1. While the states of the entire shell transform like the smallest spin representation of SO(25) we restrict our attention to its subgroup SU(6) x SU(2)/sub T/. We determine the symmetry chains which lead to total angular momentum SU(2)/sub J/ and obtain the symmetry-adapted states for these chains
Fast Heat Pulse Propagation by Turbulence Spreading
DEFF Research Database (Denmark)
Naulin, Volker; Juul Rasmussen, Jens; Mantica, Paola
2009-01-01
The propagation of a cold pulse initiated by edge cooling in JET is compared to propagation of the heat wave originating from a modulation of the heating source roughly at mid radius. It is found that the propagation of the cold pulse is by far faster than what could be predicted on the basis of ...
Heat affected zone and fatigue crack propagation behavior of high performance steel
International Nuclear Information System (INIS)
Choi, Sung Won; Kang, Dong Hwan; Kim, Tae Won; Lee, Jong Kwan
2009-01-01
The effect of heat affected zone in high performance steel on fatigue crack propagation behavior, which is related to the subsequent microstructure, was investigated. A modified Paris-Erdogan equation was presented for the analysis of fatigue crack propagation behavior corresponding to the heat affected zone conditions. Fatigue crack propagation tests under 0.3 stress ratio and 0.1 load frequency were conducted for both finegrained and coarse-grained heat affected zones, respectively. As shown in the results, much higher crack growth rate occurred in a relatively larger mean grain size material under the same stress intensity range of fatigue crack propagation process for the material.
Propagation of an intense laser beam in a tapered plasma channel
International Nuclear Information System (INIS)
Jha, Pallavi; Singh, Ram Gopal; Upadhyaya, Ajay K.; Mishra, Rohit K.
2008-01-01
Propagation characteristics and modulation instability of an intense laser beam propagating in an axially tapered plasma channel, having a parabolic radial density profile, are studied. Using the source-dependent expansion technique, the evolution equation for the laser spot is set up and conditions for propagation of the laser beam with a constant spot size (matched beam) are obtained. Further, the dispersion relation and growth rate of modulation instability of the laser pulse as it propagates through linearly and quadratically tapered plasma channels, have been obtained
Response of dwarf mistletoe-infested ponderosa pine to thinning: 2. Dwarf mistletoe propagation.
Lewis F. Roth; James W. Barrett
1985-01-01
Propagation of dwarf mistletoe in ponderosa pine saplings is little influenced by thinning overly dense stands to 250 trees per acre. Numerous plants that appear soon after thinning develop from formerly latent plants in the suppressed under-story. Subsequently, dwarf mistletoe propagates nearly as fast as tree crowns enlarge but the rate differs widely among trees....
Parametric Excitations of Fast Plasma Waves by Counter-propagating Laser Beams
International Nuclear Information System (INIS)
Shvets, G.; Fisch, N.J.
2001-01-01
Short- and long-wavelength plasma waves can become strongly coupled in the presence of two counter-propagating laser pump pulses detuned by twice the cold plasma frequency. What makes this four-wave interaction important is that the growth rate of the plasma waves occurs much faster than in the more obvious co-propagating geometry
Correction of edge-flame propagation speed in a counterflow, annular slot burner
Tran, Vu Manh
2015-10-22
To characterize the propagation modes of flames, flame propagation speed must be accurately calculated. The impact of propagating edge-flames on the flow fields of unburned gases is limited experimentally. Thus, few studies have evaluated true propagation speeds by subtracting the flow velocities of unburned gases from flame displacement speeds. Here, we present a counterflow, annular slot burner that provides an ideal one-dimensional strain rate and lengthwise zero flow velocity that allowed us to study the fundamental behaviors of edge-flames. In addition, our burner has easy optical access for detailed laser diagnostics. Flame displacement speeds were measured using a high-speed camera and related flow fields of unburned gases were visualized by particle image velocimetry. These techniques allowed us to identify significant modifications to the flow fields of unburned gases caused by thermal expansion of the propagating edges, which enabled us to calculate true flame propagation speeds that took into account the flow velocities of unburned gases.
Energy coefficients for a propeller series
DEFF Research Database (Denmark)
Olsen, Anders Smærup
2004-01-01
The efficiency for a propeller is calculated by energy coefficients. These coefficients are related to four types of losses, i.e. the axial, the rotational, the frictional, and the finite blade number loss, and one gain, i.e. the axial gain. The energy coefficients are derived by use...... of the potential theory with the propeller modelled as an actuator disk. The efficiency based on the energy coefficients is calculated for a propeller series. The results show a good agreement between the efficiency based on the energy coefficients and the efficiency obtained by a vortex-lattice method....
International Nuclear Information System (INIS)
Shirakihara, Kaori; Tanaka, Keisuke; Akiniwa, Yoshiaki; Suzuki, Yasuyoshi; Mukai, Hirokatsu
2006-01-01
Fatigue crack propagation tests of PZT specimens were performed under cyclic four-point bending with and without superposition of electric fields. The specimens were poled in the longitudinal direction (PL specimens) perpendicular to the crack plane. The crack propagation rate for the case of open circuit was faster than that for the case of short circuit. The application of a negative or positive electric field parallel to the poling direction accelerated the crack propagation rate, and the amount of acceleration was larger for the case of the negative field. The change of the crack propagation rate with crack extension can be divided into three regions. In the region I, the crack propagation rate decreases with increasing crack length, and then turn to increase in the region III. In the region II, the propagation rate is nearly constant. The mechanisms of fatigue crack propagation were correlated to domain switching near the crack tip. The grain boundary fracture was predominant in the low-rate region, while transgranular fracture became abundant on the unstable fracture surface. (author)
Influence of Sea Surface Roughness on the Electromagnetic Wave Propagation in the Duct Environment
Directory of Open Access Journals (Sweden)
X. Zhao
2010-12-01
Full Text Available This paper deals with a study of the influence of sea surface roughness on the electromagnetic wave propagation in the duct environment. The problem of electromagnetic wave propagation is modeled by using the parabolic equation method. The roughness of the sea surface is computed by modifying the smooth surface Fresnel reflection coefficient to account for the reduction in the specular reflection due to the roughness resulting from sea wind speed. The propagation model is solved by the mixed Fourier split-step algorithm. Numerical experiments indicate that wind-driven roughened sea surface has an impact on the electromagnetic wave propagation in the duct environment, and the strength is intensified along with the increment of sea wind speeds and/or the operating frequencies. In a fixed duct environment, however, proper disposition of the transmitter could reduce these impacts.
Absorption of nearly perpendicularly propagating waves in the second harmonic layer
International Nuclear Information System (INIS)
Imre, K.; Weitzner, H.
1985-01-01
Propagation of waves nearly perpendicular to the equilibrium magnetic field and incident to the second electron-cyclotron harmonic layer is investigated in an inhomogeneous weakly relativistic plasma. The resonance region is treated by a boundary layer analysis, and the solutions are matched to the geometrical optics solutions outside the layer. This approach allows one to investigate the transmission, mode coupling, reflection, absorption, and the effects of relativistic broadening. This work extends a previous investigation with the purely perpendicular propagation. It is shown that the mode conversion and reflection rapidly cease to be of importance outside a narrow propagation cone as the doppler broadening becomes predominant. The geometrical optics approach, which breaks down in the purely perpendicular propagation, then becomes valid. It is also shown that the transmission coefficient and the reflection from the high-field side incidence are not altered within this cone
Kinetic coefficients for the biological treatment of tannery wastewater
International Nuclear Information System (INIS)
Haydar, S.
2008-01-01
Determination of kinetic coefficients for a particular wastewater is imperative for the rational design of biological treatment-facilities. The present study was undertaken with the objective of finding out kinetic coefficients for tannery wastewater. A bench-scale model of aerated lagoon, consisting of an aeration tank and final clarifier, was use to conduct the studies. The model was operated continuously for 96 days, by varying the detention times from 3 to 9 days. Influent for the aerated lagoon was settled tannery wastewater. Biochemical oxygen demand (BOD) of the influent and effluent and the mixed-liquor suspended solids (MLSS) of aeration tank were determined at various detention-times so as to generate data for kinetic coefficients. The kinetic coefficients k, Ks, Y and Ed were found to be 3.125 day/sup -1/, 488 mg/L, 0.64 and 0.035 day/sup -1/ respectively. Overall rate-constant of BOD, removal 'K' was also determined and was found to be 1.43 day/sup -1/. Kinetic coefficients were determined, at mean reactor-temperature of 30.2 degree C. These coefficients may be utilized for the design of biological-treatment facilities for tannery wastewater. (author)
Nuño, N; Groppetti, R; Senin, N
2006-11-01
Design of cemented hip and knee implants, oriented to improve the longevity of artificial joints, is largely based on numerical models. The static coefficient of friction between the implant and the bone cement is necessary to characterize the interface conditions in these models and must be accurately provided. The measurement of this coefficient using a repeatable and reproducible methodology for materials used in total hip arthroplasty is missing from the literature. A micro-topographic surface analysis characterized the surfaces of the specimens used in the experiments. The coefficient of friction between stainless steel and bone cement in dry and wet conditions using bovine serum was determined using a prototype computerized sliding friction tester. The effects of surface roughness (polished versus matt) and of contact pressure on the coefficient of friction have also been investigated. The serum influences little the coefficient of friction for the matt steel surface, where the mechanical interactions due to higher roughness are still the most relevant factor. However, for polished steel surfaces, the restraining effect of proteins plays a very relevant role in increasing the coefficient of friction. When the coefficient of friction is used in finite element analysis, it is used for the debonded stem-cement situation. It can thus be assumed that serum will propagate between the stem and the cement mantle. The authors believe that the use of a static coefficient of friction of 0.3-0.4, measured in the present study, is appropriate in finite element models.
Semiclassical propagator of the Wigner function.
Dittrich, Thomas; Viviescas, Carlos; Sandoval, Luis
2006-02-24
Propagation of the Wigner function is studied on two levels of semiclassical propagation: one based on the Van Vleck propagator, the other on phase-space path integration. Leading quantum corrections to the classical Liouville propagator take the form of a time-dependent quantum spot. Its oscillatory structure depends on whether the underlying classical flow is elliptic or hyperbolic. It can be interpreted as the result of interference of a pair of classical trajectories, indicating how quantum coherences are to be propagated semiclassically in phase space. The phase-space path-integral approach allows for a finer resolution of the quantum spot in terms of Airy functions.
The propagator of quantum gravity in minisuperspace
International Nuclear Information System (INIS)
Louko, J.
1985-04-01
We study the quantum gravitational propagation amplitude between two spacelike three-surfaces in minisuperspaces where the supermomentum constraints are identically satisfied. We derive a well-defined path integral formula for the propagator and show that the propagator is an inverse of the canonical Hamiltonian operator. In an exactly solvable deSitter minisuperspace model the propagator is found to obey semi-classically correct boundary conditions. We discuss the implications for the full theory and suggest an approach to unravelling the physical meaning of the propagator. (orig.)
Tropospheric radiowave propagation beyond the horizon
Du Castel, François
1966-01-01
Tropospheric Radiowave Propagation Beyond the Horizon deals with developments concerning the tropospheric propagation of ultra-short radio waves beyond the horizon, with emphasis on the relationship between the theoretical and the experimental. Topics covered include the general conditions of propagation in the troposphere; general characteristics of propagation beyond the horizon; and attenuation in propagation. This volume is comprised of six chapters and begins with a brief historical look at the various stages that have brought the technique of transhorizon links to its state of developmen
Light propagation in linear optical media
Gillen, Glen D; Guha, Shekhar
2013-01-01
Light Propagation in Linear Optical Media describes light propagation in linear media by expanding on diffraction theories beyond what is available in classic optics books. In one volume, this book combines the treatment of light propagation through various media, interfaces, and apertures using scalar and vector diffraction theories. After covering the fundamentals of light and physical optics, the authors discuss light traveling within an anisotropic crystal and present mathematical models for light propagation across planar boundaries between different media. They describe the propagation o
In situ fatigue-crack-propagation experiment
International Nuclear Information System (INIS)
Ermi, A.M.; Chin, B.A.
1981-01-01
An in-reactor fatigue experiment was conducted in the Oak Ridge Research Reactor to determine the effects of dynamic irradiation on fatigue crack propagation. Eight 20% cold-worked 316 stainless steel specimens were precracked to various initial crack lengths, linked together to form a chain, and inserted into a specially designed in-reactor fatigue machine. Test conditions included a maximum temperature of 460 0 C, an environment of sodium, a frequency of 1 cycle/min, and a stress ratio of 0.10. Results indicated that (1) no effects of dynamic irradiation were observed for a fluence of 1.5 x 10 21 n/cm 2 (E > 0.1 MeV); and (2) crack growth rates in elevated temperature sodium were a factor of 3 to 4 lower than in room temperature air
Counterstreaming magnetized plasmas. II. Perpendicular wave propagation
International Nuclear Information System (INIS)
Tautz, R.C.; Schlickeiser, R.
2006-01-01
The properties of longitudinal and transverse oscillations in magnetized symmetric counterstreaming Maxwellian plasmas with equal thermal velocities for waves propagating perpendicular to the stream direction are investigated on the basis of Maxwell equations and the nonrelativistic Vlasov equation. With the constraint of vanishing particle flux in the stream direction, three distinct dispersion relations are known, which are the ordinary-wave mode, the Bernstein wave mode, and the extraordinary electromagnetic wave mode, where the latter two are only approximations. In this article, all three dispersion relations are evaluated for a counterstreaming Maxwellian distribution function in terms of the hypergeometric function 2 F 2 . The growth rates for the ordinary-wave mode are compared to earlier results by Bornatici and Lee [Phys. Fluids 13, 3007 (1970)], who derived approximate results, whereas in this article the exact dispersion relation is solved numerically. The original results are therefore improved and show differences of up to 21% to the results obtained in this article
International Nuclear Information System (INIS)
Chetyrkin, K.G.
1989-01-01
It is shown in an arbitrary model that the coefficient functions of the operator expansion (renormalized in the minimal subtraction scheme) are finite. Explicit formulas convenient for calculating them in practice are obtained. The gluing method and the formalism of the R* operation are used to transform the formulas in such a way that the coefficient functions can be expressed in terms of ordinary diagrams containing neither nonstandard propagators nor an additional loop integration. An important feature of the representation for the coefficient functions is that the R* operation, which subtracts simultaneously the ultraviolet and infrared divergences, guarantees the existence of the coefficient functions in the limit when the dimensional regularization is lifted without any restrictions
Kawai, K; Noguchi, H
2002-01-01
Effective dose coefficients, the committed effective dose per unit intake, by inhalation and ingestion have been calculated for 304 nuclides, including (1) 230 nuclides with half-lives >= 10 min and their daughters that are not listed in ICRP Publications and (2) 74 nuclides with half-lives < 10 min that are produced in a spallation target. Effective dose coefficients for inhalation of soluble or reactive gases have been calculated for 21 nuclides, and effective dose rates for inert gases have been calculated for 9 nuclides. Dose calculation was carried out using a general-purpose nuclear decay database DECDC developed at JAERI and a decay data library newly compiled from the ENSDF for the nuclides abundantly produced in a spallation target. The dose coefficients were calculated with the computer code DOCAP based on the respiratory tract model and biokinetic model of ICRP. The effective dose rates were calculated by considering both external irradiation from the surrounding cloud and irradiation of the lun...
Calculation of generalized secant integral using binomial coefficients
International Nuclear Information System (INIS)
Guseinov, I.I.; Mamedov, B.A.
2004-01-01
A single series expansion relation is derived for the generalized secant (GS) integral in terms of binomial coefficients, exponential integrals and incomplete gamma functions. The convergence of the series is tested by the concrete cases of parameters. The formulas given in this study for the evaluation of GS integral show good rate of convergence and numerical stability
International Nuclear Information System (INIS)
Frosio, T.; Bonaccorsi, T.; Blaise, P.
2017-01-01
The precise estimation of Pearson correlations, also called 'representativity' coefficients, between core configurations is a fundamental quantity for properly assessing the nuclear data (ND) uncertainties propagation on integral parameters such as k-eff, power distributions, or reactivity coefficients. In this paper, a traditional adjoint method is used to propagate ND uncertainty on reactivity and reactivity coefficients and estimate correlations between different states of the core. We show that neglecting those correlations induces a loss of information in the final uncertainty. We also show that using approximate values of Pearson does not lead to an important error of the model. This calculation is made for reactivity at the beginning of life and can be extended to other parameters during depletion calculations. (authors)
Radio wave propagation and parabolic equation modeling
Apaydin, Gokhan
2018-01-01
A thorough understanding of electromagnetic wave propagation is fundamental to the development of sophisticated communication and detection technologies. The powerful numerical methods described in this book represent a major step forward in our ability to accurately model electromagnetic wave propagation in order to establish and maintain reliable communication links, to detect targets in radar systems, and to maintain robust mobile phone and broadcasting networks. The first new book on guided wave propagation modeling and simulation to appear in nearly two decades, Radio Wave Propagation and Parabolic Equation Modeling addresses the fundamentals of electromagnetic wave propagation generally, with a specific focus on radio wave propagation through various media. The authors explore an array of new applications, and detail various v rtual electromagnetic tools for solving several frequent electromagnetic propagation problems. All of the methods described are presented within the context of real-world scenari...
Propagation phenomena in real world networks
Fay, Damien; Gabryś, Bogdan
2015-01-01
“Propagation, which looks at spreading in complex networks, can be seen from many viewpoints; it is undesirable, or desirable, controllable, the mechanisms generating that propagation can be the topic of interest, but in the end all depends on the setting. This book covers leading research on a wide spectrum of propagation phenomenon and the techniques currently used in its modelling, prediction, analysis and control. Fourteen papers range over topics including epidemic models, models for trust inference, coverage strategies for networks, vehicle flow propagation, bio-inspired routing algorithms, P2P botnet attacks and defences, fault propagation in gene-cellular networks, malware propagation for mobile networks, information propagation in crisis situations, financial contagion in interbank networks, and finally how to maximize the spread of influence in social networks. The compendium will be of interest to researchers, those working in social networking, communications and finance and is aimed at providin...
Wave Propagation in Bimodular Geomaterials
Kuznetsova, Maria; Pasternak, Elena; Dyskin, Arcady; Pelinovsky, Efim
2016-04-01
Observations and laboratory experiments show that fragmented or layered geomaterials have the mechanical response dependent on the sign of the load. The most adequate model accounting for this effect is the theory of bimodular (bilinear) elasticity - a hyperelastic model with different elastic moduli for tension and compression. For most of geo- and structural materials (cohesionless soils, rocks, concrete, etc.) the difference between elastic moduli is such that their modulus in compression is considerably higher than that in tension. This feature has a profound effect on oscillations [1]; however, its effect on wave propagation has not been comprehensively investigated. It is believed that incorporation of bilinear elastic constitutive equations within theory of wave dynamics will bring a deeper insight to the study of mechanical behaviour of many geomaterials. The aim of this paper is to construct a mathematical model and develop analytical methods and numerical algorithms for analysing wave propagation in bimodular materials. Geophysical and exploration applications and applications in structural engineering are envisaged. The FEM modelling of wave propagation in a 1D semi-infinite bimodular material has been performed with the use of Marlow potential [2]. In the case of the initial load expressed by a harmonic pulse loading strong dependence on the pulse sign is observed: when tension is applied before compression, the phenomenon of disappearance of negative (compressive) strains takes place. References 1. Dyskin, A., Pasternak, E., & Pelinovsky, E. (2012). Periodic motions and resonances of impact oscillators. Journal of Sound and Vibration, 331(12), 2856-2873. 2. Marlow, R. S. (2008). A Second-Invariant Extension of the Marlow Model: Representing Tension and Compression Data Exactly. In ABAQUS Users' Conference.
Radio Propagation into Modern Buildings
DEFF Research Database (Denmark)
Rodriguez Larrad, Ignacio; Nguyen, Huan Cong; Jørgensen, Niels T.K.
2014-01-01
Energy-efficient buildings are gaining momentum in order to comply with the new energy regulations. Especially in northern cold countries, thick reinforced walls and energy-efficient windows composed of several layers of glass plus metal coating are becoming the de facto elements in modern building...... constructions. These materials are used in favor of achieving a proper level of thermal isolation, but it has been noticed that they can impact heavily on radio signal propagation. This paper presents a measurement-based analysis of the outdoor-to-indoor attenuation experienced in several modern constructions...
Fast imaging of streamer propagation
International Nuclear Information System (INIS)
Veldhuizen, E.M. van; Baede, A.H.F.M.; Hayashi, D.; Rutgers, W.R.
2001-01-01
Recently measurement methods are becoming available to study the corona discharge in more detail. One of the most promising methods is laser-induced fluorescence to determine radical density. Recent improvements in CCD cameras makes it now possible to improve measurements of the discharge structure to a resolution of 1 ns in time and 10 μm in space. This paper shows the first results of the spontaneous emission of a point-to-plane corona discharge in air using such a camera. It clearly indicates that the 2-D approach for streamer propagation under these conditions is insufficient
Fast imaging of streamer propagation
Energy Technology Data Exchange (ETDEWEB)
Veldhuizen, E.M. van; Baede, A.H.F.M.; Hayashi, D.; Rutgers, W.R. [Eindhoven Univ. of Technology (Netherlands). Dept. of Applied Physics
2001-07-01
Recently measurement methods are becoming available to study the corona discharge in more detail. One of the most promising methods is laser-induced fluorescence to determine radical density. Recent improvements in CCD cameras makes it now possible to improve measurements of the discharge structure to a resolution of 1 ns in time and 10 {mu}m in space. This paper shows the first results of the spontaneous emission of a point-to-plane corona discharge in air using such a camera. It clearly indicates that the 2-D approach for streamer propagation under these conditions is insufficient.
Modification Propagation in Complex Networks
Mouronte, Mary Luz; Vargas, María Luisa; Moyano, Luis Gregorio; Algarra, Francisco Javier García; Del Pozo, Luis Salvador
To keep up with rapidly changing conditions, business systems and their associated networks are growing increasingly intricate as never before. By doing this, network management and operation costs not only rise, but are difficult even to measure. This fact must be regarded as a major constraint to system optimization initiatives, as well as a setback to derived economic benefits. In this work we introduce a simple model in order to estimate the relative cost associated to modification propagation in complex architectures. Our model can be used to anticipate costs caused by network evolution, as well as for planning and evaluating future architecture development while providing benefit optimization.
Structural damage identification based on laser ultrasonic propagation imaging technology
Chia, Chen-Ciang; Jang, Si-Gwang; Lee, Jung-Ryul; Yoon, Dong-Jin
2009-06-01
An ultrasonic propagation imaging (UPI) system consisted of a Q-switched Nd-YAG pulsed laser and a galvanometer laser mirror scanner was developed. The system which requires neither reference data nor fixed focal length could be used for health monitoring of curved structures. If combined with a fiber acoustic wave PZT (FAWPZT) sensor, it could be used to inspect hot target structures that present formidable challenges to the usage of contact piezoelectric transducers mainly due to the operating temperature limitation of transducers and debonding problem due to the mismatch of coefficient of thermal expansion between the target, transducer and bonding material. The inspection of a stainless steel plate with a curvature radius of about 4 m, having 2mm×1mm open-crack was demonstrated at 150°C using a FAWPZT sensor welded on the plate. Highly-curved surfaces scanning capability and adaptivity of the system for large laser incident angle up to 70° was demonstrated on a stainless steel cylinder with 2mm×1mm open-crack. The imaging results were presented in ultrasonic propagation movie which was a moving wavefield emerged from an installed ultrasonic sensor. Damages were localized by the scattering wavefields. The result images enabled easy detection and interpretation of structural defects as anomalies during ultrasonic wave propagation.
DEFF Research Database (Denmark)
Haedersdal, C; Pedersen, F H; Svendsen, J H
1992-01-01
after the myocardial infarction. A significant correlation (Spearman's correlation coefficient rs, p less than 0.05) was found between LVEF at rest and the following variables assessed at exercise test: 1) the heart rate at rest, 2) rise in heart rate, 3) ratio between maximal heart rate and heart rate...... at rest, 4) rise in systolic blood pressure, 5) rate pressure product at rest, 6) rise in rate pressure product, 7) ratio (rHR) between maximal rate pressure product and rate pressure product at rest, 8) total exercise time. The heart rate was corrected for effects caused by age (heart index (HR...
Díaz-de-Mera, Yolanda; Aranda, Alfonso; Bravo, Iván; Rodríguez, Diana; Rodríguez, Ana; Moreno, Elena
2008-10-01
The adverse environmental impacts of chlorinated hydrocarbons on the Earth's ozone layer have focused attention on the effort to replace these compounds by nonchlorinated substitutes with environmental acceptability. Hydrofluoroethers (HFEs) and fluorinated alcohols are currently being introduced in many applications for this purpose. Nevertheless, the presence of a great number of C-F bonds drives to atmospheric long-lived compounds with infrared absorption features. Thus, it is necessary to improve our knowledge about lifetimes and global warming potentials (GWP) for these compounds in order to get a complete evaluation of their environmental impact. Tropospheric degradation is expected to be initiated mainly by OH reactions in the gas phase. Nevertheless, Cl atoms reaction may also be important since rate constants are generally larger than those of OH. In the present work, we report the results obtained in the study of the reactions of Cl radicals with HFE-7000 (CF(3)CF(2)CF(2)OCH(3)) (1) and its isomer CF(3)CF(2)CF(2)CH(2)OH (2). Kinetic rate coefficients with Cl atoms have been measured using the discharge flow tube-mass spectrometric technique at 1 Torr of total pressure. The reactions of these chlorofluorocarbons (CFCs) substitutes have been studied under pseudo-first-order kinetic conditions in excess of the fluorinated compounds over Cl atoms. The temperature ranges were 266-333 and 298-353 K for reactions of HFE-7000 and CF(3)CF(2)CF(2)CH(2)OH, respectively. The measured room temperature rate constants were k(Cl+CF(3)CF(2)CF(2)OCH(3)) = (1.24 +/- 0.28) x 10(-13) cm(3) molecule(-1) s(-1)and k(Cl+CF(3)CF(2)CF(2)CH(2)OH) = (8.35 +/- 1.63) x 10(-13) cm(3) molecule(-1) s(-1) (errors are 2sigma + 10% to cover systematic errors). The Arrhenius expression for reaction 1 was k (1)(266-333 K) = (6.1 +/- 3.8) x 10(-13)exp[-(445 +/- 186)/T] cm(3) molecule(-1) s(-1) and k (2)(298-353 K) = (1.9 +/- 0.7) x 10(-12)exp[-(244 +/- 125)/T] cm(3) molecule(-1) s(-1) (errors
Genetic conservation and paddlefish propagation
Sloss, Brian L.; Klumb, Robert A.; Heist, Edward J.
2009-01-01
The conservation of genetic diversity of our natural resources is overwhelmingly one of the central foci of 21st century management practices. Three recommendations related to the conservation of paddlefish Polyodon spathula genetic diversity are to (1) identify genetic diversity at both nuclear and mitochondrial DNA loci using a suggested list of 20 sampling locations, (2) use genetic diversity estimates to develop genetic management units, and (3) identify broodstock sources to minimize effects of supplemental stocking on the genetic integrity of native paddlefish populations. We review previous genetic work on paddlefish and described key principles and concepts associated with maintaining genetic diversity within and among paddlefish populations and also present a genetic case study of current paddlefish propagation at the U.S. Fish and Wildlife Service Gavins Point National Fish Hatchery. This study confirmed that three potential sources of broodfish were genetically indistinguishable at the loci examined, allowing the management agencies cooperating on this program flexibility in sampling gametes. This study also showed significant bias in the hatchery occurred in terms of male reproductive contribution, which resulted in a shift in the genetic diversity of progeny compared to the broodfish. This shift was shown to result from differential male contributions, partially attributed to the mode of egg fertilization. Genetic insights enable implementation of a paddlefish propagation program within an adaptive management strategy that conserves inherent genetic diversity while achieving demographic goals.
Quantum propagation across cosmological singularities
Gielen, Steffen; Turok, Neil
2017-05-01
The initial singularity is the most troubling feature of the standard cosmology, which quantum effects are hoped to resolve. In this paper, we study quantum cosmology with conformal (Weyl) invariant matter. We show that it is natural to extend the scale factor to negative values, allowing a large, collapsing universe to evolve across a quantum "bounce" into an expanding universe like ours. We compute the Feynman propagator for Friedmann-Robertson-Walker backgrounds exactly, identifying curious pathologies in the case of curved (open or closed) universes. We then include anisotropies, fixing the operator ordering of the quantum Hamiltonian by imposing covariance under field redefinitions and again finding exact solutions. We show how complex classical solutions allow one to circumvent the singularity while maintaining the validity of the semiclassical approximation. The simplest isotropic universes sit on a critical boundary, beyond which there is qualitatively different behavior, with potential for instability. Additional scalars improve the theory's stability. Finally, we study the semiclassical propagation of inhomogeneous perturbations about the flat, isotropic case, at linear and nonlinear order, showing that, at least at this level, there is no particle production across the bounce. These results form the basis for a promising new approach to quantum cosmology and the resolution of the big bang singularity.
Simplified propagation of standard uncertainties
International Nuclear Information System (INIS)
Shull, A.H.
1997-01-01
An essential part of any measurement control program is adequate knowledge of the uncertainties of the measurement system standards. Only with an estimate of the standards'' uncertainties can one determine if the standard is adequate for its intended use or can one calculate the total uncertainty of the measurement process. Purchased standards usually have estimates of uncertainty on their certificates. However, when standards are prepared and characterized by a laboratory, variance propagation is required to estimate the uncertainty of the standard. Traditional variance propagation typically involves tedious use of partial derivatives, unfriendly software and the availability of statistical expertise. As a result, the uncertainty of prepared standards is often not determined or determined incorrectly. For situations meeting stated assumptions, easier shortcut methods of estimation are now available which eliminate the need for partial derivatives and require only a spreadsheet or calculator. A system of simplifying the calculations by dividing into subgroups of absolute and relative uncertainties is utilized. These methods also incorporate the International Standards Organization (ISO) concepts for combining systematic and random uncertainties as published in their Guide to the Expression of Measurement Uncertainty. Details of the simplified methods and examples of their use are included in the paper
Uncertainty propagation in nuclear forensics
International Nuclear Information System (INIS)
Pommé, S.; Jerome, S.M.; Venchiarutti, C.
2014-01-01
Uncertainty propagation formulae are presented for age dating in support of nuclear forensics. The age of radioactive material in this context refers to the time elapsed since a particular radionuclide was chemically separated from its decay product(s). The decay of the parent radionuclide and ingrowth of the daughter nuclide are governed by statistical decay laws. Mathematical equations allow calculation of the age of specific nuclear material through the atom ratio between parent and daughter nuclides, or through the activity ratio provided that the daughter nuclide is also unstable. The derivation of the uncertainty formulae of the age may present some difficulty to the user community and so the exact solutions, some approximations, a graphical representation and their interpretation are presented in this work. Typical nuclides of interest are actinides in the context of non-proliferation commitments. The uncertainty analysis is applied to a set of important parent–daughter pairs and the need for more precise half-life data is examined. - Highlights: • Uncertainty propagation formulae for age dating with nuclear chronometers. • Applied to parent–daughter pairs used in nuclear forensics. • Investigated need for better half-life data
Local carbon diffusion coefficient measurement in the S-1 spheromak
International Nuclear Information System (INIS)
Mayo, R.M.; Levinton, F.M.; Meyerhofer, D.D.; Chu, T.K.; Paul, S.F.; Yamada, M.
1988-10-01
The local carbon diffusion coefficient was measured in the S - 1 spheromak by detecting the radial spread of injected carbon impurity. The radial impurity density profile is determined by the balance of ionization and diffusion. Using measured local electron temperature T/sub e/ and density n/sub e/, the ionization rate is determined from which the particle diffusion coefficient is inferred. The results found in this work are consistent with Bohm diffusion. The absolute magnitude of D/sub /perpendicular// was determined to be (4/approximately/6) /times/ D/sub Bohm/. 25 refs., 13 figs., 2 tabs
Study of fatigue crack propagation in magnesium alloys
International Nuclear Information System (INIS)
Yarema, S.Ya.; Zinyuk, O.D.; Ostash, O.P.; Kudryashov, V.G.; Elkin, F.M.
1981-01-01
Fatigue crack propagation in standard (MA2-1, MA8) and super light (MA21, MA18) alloys has been investigated in the whole range of load amplitude changes-from threshold to critical; the materials have been compared by cyclic crack resistance, fractographic analysis has been made. It is shown that MA2-1 alloy crack resistance is slightly lower than the resistance of the other three alloys. MA8 and MA21 alloys having similar mechanical properties almost do not differ in cyclic crack resistance as well. MA18 alloy has the highest resistance to fatigue crack propagation in the whole range of Ksub(max) changes. The presented results on cyclic crack resistance of MA21 and MA18 alloys agree with the data on statistic fracture toughness. The fractures have been also investigated using a scanning electron microscope. Fracture microrelieves of MA8 and MA21 alloys are very similar. At low crack propagation rates (v - 7 m/cycle) it develops through grains, in MA2-1 alloy fracture intergrain fracture areas can be observed. In MA8 and MA21 alloy fractures groove covered areas can be seen alonside with areas of slipping plane laminatron; their specific weight increases with #betta# decrease. Lower crack propagation rates and higher values of threshold stress intensity factors for MA8 and MA21 alloys than for MA2-1 alloy are caused by the absence of intergrain fracture
A drying coefficient for building materials
DEFF Research Database (Denmark)
Scheffler, Gregor Albrecht; Plagge, Rudolf
2009-01-01
coefficient is defined which can be determined based on measured drying data. The correlation of this coefficient with the water absorption and the vapour diffusion coefficient is analyzed and its additional information content is critically challenged. As result, a drying coefficient has been derived......The drying experiment is an important element of the hygrothermal characterisation of building materials. Contrary to other moisture transport experiments as the vapour diffusion and the water absorption test, it is until now not possible to derive a simple coefficient for the drying. However......, in many cases such a coefficient would be highly appreciated, e.g. in interaction of industry and research or for the distinction and selection of suitable building materials throughout design and practise. This article first highlights the importance of drying experiments for hygrothermal...
Apparatus for measurement of coefficient of friction
Slifka, A. J.; Siegwarth, J. D.; Sparks, L. L.; Chaudhuri, Dilip K.
1990-01-01
An apparatus designed to measure the coefficient of friction in certain controlled atmospheres is described. The coefficient of friction observed during high-load tests was nearly constant, with an average value of 0.56. This value is in general agreement with that found in the literature and also with the initial friction coefficient value of 0.67 measured during self-mated friction of 440C steel in an oxygen environment.
New definition of the cell diffusion coefficient
International Nuclear Information System (INIS)
Koehler, P.
1975-01-01
As was shown in a recent work by Gelbard, the usually applied Benoist definition of the cell diffusion coefficient gives two different values if two different definitions of the cell are made. A new definition is proposed that preserves the neutron balance for the homogenized lattice and that is independent of the cell definition. The resulting diffusion coefficient is identical with the main term of Benoist's diffusion coefficient
Transfer coefficients in ultracold strongly coupled plasma
Bobrov, A. A.; Vorob'ev, V. S.; Zelener, B. V.
2018-03-01
We use both analytical and molecular dynamic methods for electron transfer coefficients in an ultracold plasma when its temperature is small and the coupling parameter characterizing the interaction of electrons and ions exceeds unity. For these conditions, we use the approach of nearest neighbor to determine the average electron (ion) diffusion coefficient and to calculate other electron transfer coefficients (viscosity and electrical and thermal conductivities). Molecular dynamics simulations produce electronic and ionic diffusion coefficients, confirming the reliability of these results. The results compare favorably with experimental and numerical data from earlier studies.
Comparing linear probability model coefficients across groups
DEFF Research Database (Denmark)
Holm, Anders; Ejrnæs, Mette; Karlson, Kristian Bernt
2015-01-01
of the following three components: outcome truncation, scale parameters and distributional shape of the predictor variable. These results point to limitations in using linear probability model coefficients for group comparisons. We also provide Monte Carlo simulations and real examples to illustrate......This article offers a formal identification analysis of the problem in comparing coefficients from linear probability models between groups. We show that differences in coefficients from these models can result not only from genuine differences in effects, but also from differences in one or more...... these limitations, and we suggest a restricted approach to using linear probability model coefficients in group comparisons....
Seismic Wave Propagation in Layered Viscoelastic Media
Borcherdt, R. D.
2008-12-01
Advances in the general theory of wave propagation in layered viscoelastic media reveal new insights regarding seismic waves in the Earth. For example, the theory predicts: 1) P and S waves are predominantly inhomogeneous in a layered anelastic Earth with seismic travel times, particle-motion orbits, energy speeds, Q, and amplitude characteristics that vary with angle of incidence and hence, travel path through the layers, 2) two types of shear waves exist, one with linear and the other with elliptical particle motions each with different absorption coefficients, and 3) surface waves with amplitude and particle motion characteristics not predicted by elasticity, such as Rayleigh-Type waves with tilted elliptical particle motion orbits and Love-Type waves with superimposed sinusoidal amplitude dependencies that decay exponentially with depth. The general theory provides closed-form analytic solutions for body waves, reflection-refraction problems, response of multiple layers, and surface wave problems valid for any material with a viscoelastic response, including the infinite number of models, derivable from various configurations of springs and dashpots, such as elastic, Voight, Maxwell, and Standard Linear. The theory provides solutions independent of the amount of intrinsic absorption and explicit analytic expressions for physical characteristics of body waves in low-loss media such as the deep Earth. The results explain laboratory and seismic observations, such as travel-time and wide-angle reflection amplitude anomalies, not explained by elasticity or one dimensional Q models. They have important implications for some forward modeling and inverse problems. Theoretical advances and corresponding numerical results as recently compiled (Borcherdt, 2008, Viscoelastic Waves in Layered Media, Cambridge University Press) will be reviewed.
Adaptive laser link reconfiguration using constraint propagation
Crone, M. S.; Julich, P. M.; Cook, L. M.
1993-01-01
This paper describes Harris AI research performed on the Adaptive Link Reconfiguration (ALR) study for Rome Lab, and focuses on the application of constraint propagation to the problem of link reconfiguration for the proposed space based Strategic Defense System (SDS) Brilliant Pebbles (BP) communications system. According to the concept of operations at the time of the study, laser communications will exist between BP's and to ground entry points. Long-term links typical of RF transmission will not exist. This study addressed an initial implementation of BP's based on the Global Protection Against Limited Strikes (GPALS) SDI mission. The number of satellites and rings studied was representative of this problem. An orbital dynamics program was used to generate line-of-site data for the modeled architecture. This was input into a discrete event simulation implemented in the Harris developed COnstraint Propagation Expert System (COPES) Shell, developed initially on the Rome Lab BM/C3 study. Using a model of the network and several heuristics, the COPES shell was used to develop the Heuristic Adaptive Link Ordering (HALO) Algorithm to rank and order potential laser links according to probability of communication. A reduced set of links based on this ranking would then be used by a routing algorithm to select the next hop. This paper includes an overview of Constraint Propagation as an Artificial Intelligence technique and its embodiment in the COPES shell. It describes the design and implementation of both the simulation of the GPALS BP network and the HALO algorithm in COPES. This is described using a 59 Data Flow Diagram, State Transition Diagrams, and Structured English PDL. It describes a laser communications model and the heuristics involved in rank-ordering the potential communication links. The generation of simulation data is described along with its interface via COPES to the Harris developed View Net graphical tool for visual analysis of communications
Turbulent Premixed Flame Propagation in Microgravity
Menon, S.; Disseau, M.; Chakravarthy, V. K.; Jagoda, J.
1997-01-01
reacting flow facility is also being constructed with planned drop tower experiments in mind. Therefore, issues related to safety and structural integrity are being take into account. Further development of the numerical model will also be carried out to include finite-rate kinetics for representative premixed cases. More detail analysis of the flame structure and propagation nature will be investigated. Simulations will also be compared to the flame properties observed in the experiments.
Uncertainty Quantification of Turbulence Model Closure Coefficients for Transonic Wall-Bounded Flows
Schaefer, John; West, Thomas; Hosder, Serhat; Rumsey, Christopher; Carlson, Jan-Renee; Kleb, William
2015-01-01
The goal of this work was to quantify the uncertainty and sensitivity of commonly used turbulence models in Reynolds-Averaged Navier-Stokes codes due to uncertainty in the values of closure coefficients for transonic, wall-bounded flows and to rank the contribution of each coefficient to uncertainty in various output flow quantities of interest. Specifically, uncertainty quantification of turbulence model closure coefficients was performed for transonic flow over an axisymmetric bump at zero degrees angle of attack and the RAE 2822 transonic airfoil at a lift coefficient of 0.744. Three turbulence models were considered: the Spalart-Allmaras Model, Wilcox (2006) k-w Model, and the Menter Shear-Stress Trans- port Model. The FUN3D code developed by NASA Langley Research Center was used as the flow solver. The uncertainty quantification analysis employed stochastic expansions based on non-intrusive polynomial chaos as an efficient means of uncertainty propagation. Several integrated and point-quantities are considered as uncertain outputs for both CFD problems. All closure coefficients were treated as epistemic uncertain variables represented with intervals. Sobol indices were used to rank the relative contributions of each closure coefficient to the total uncertainty in the output quantities of interest. This study identified a number of closure coefficients for each turbulence model for which more information will reduce the amount of uncertainty in the output significantly for transonic, wall-bounded flows.
Turbid Media Extinction Coefficient for Near-Infrared Laser Radiation
International Nuclear Information System (INIS)
Dreischuh, T; Gurdev, L; Vankov, O; Stoyanov, D; Avramov, L
2015-01-01
In this work, extended investigations are performed of the extinction coefficient of Intralipid-20% dilutions in distilled water depending on the Intralipid concentration, for laser radiation wavelengths in the red and near-infrared regions covering the so-called tissue optical window. The extinction is measured by using an approach we have developed recently based on the features of the spatial intensity distribution of laser-radiation beams propagating through semi-infinite turbid media. The measurements are conducted using separately two dilution- containing plexiglass boxes of different sizes and volumes, in order to prove the appropriateness of the assumption of semi-infinite turbid medium. The experimental results for the extinction are in agreement with our previous results and with empiric formulae found by other authors concerning the wavelength dependence of the scattering coefficient of Intralipid – 10% and Intralipid – 20%. They are also in agreement with known data of the water absorptance. It is estimated as well that the wavelengths around 1320 nm would be advantageous for deep harmless sensing and diagnostics of tissues
Role of Compressibility on Tsunami Propagation
Abdolali, Ali; Kirby, James T.
2017-12-01
In the present paper, we aim to reduce the discrepancies between tsunami arrival times evaluated from tsunami models and real measurements considering the role of ocean compressibility. We perform qualitative studies to reveal the phase speed reduction rate via a modified version of the Mild Slope Equation for Weakly Compressible fluid (MSEWC) proposed by Sammarco et al. (2013). The model is validated against a 3-D computational model. Physical properties of surface gravity waves are studied and compared with those for waves evaluated from an incompressible flow solver over realistic geometry for 2011 Tohoku-oki event, revealing reduction in phase speed.Plain Language SummarySubmarine earthquakes and submarine mass failures (SMFs), can generate long gravitational waves (or tsunamis) that propagate at the free surface. Tsunami waves can travel long distances and are known for their dramatic effects on coastal areas. Nowadays, numerical models are used to reconstruct the tsunamigenic events for many scientific and socioeconomic aspects i.e. Tsunami Early Warning Systems, inundation mapping, risk and hazard analysis, etc. A number of typically neglected parameters in these models cause discrepancies between model outputs and observations. Most of the tsunami models predict tsunami arrival times at distant stations slightly early in comparison to observations. In this study, we show how ocean compressibility would affect the tsunami wave propagation speed. In this framework, an efficient two-dimensional model equation for the weakly compressible ocean has been developed, validated and tested for simplified and real cases against three dimensional and incompressible solvers. Taking the effect of compressibility, the phase speed of surface gravity waves is reduced compared to that of an incompressible fluid. Then, we used the model for the case of devastating Tohoku-Oki 2011 tsunami event, improving the model accuracy. This study sheds light for future model development
Energy Technology Data Exchange (ETDEWEB)
Hasselin, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires
1965-07-01
In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)
Energy Technology Data Exchange (ETDEWEB)
Hasselin, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires
1965-07-01
In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)
Propagation engineering in radio links design
Ghasemi, Abdollah; Ghasemi, Farshid
2013-01-01
Propagation Engineering in Radio Link Design covers the basic principles of radiowaves propagation in a practical manner. This fundamental understanding enables the readers to design radio links efficiently. This book elaborates on new achievements as well as recently developed propagation models. This is in addition to a comprehensive overview of fundamentals of propagation in various scenarios. It examines theoretical calculations, approaches and applied procedures needed for radio links design. The authors study and analysis of the main propagation phenomena and its mechanisms based on the recommendations of International Telecommunications Union, (ITU). The book has been organized in 9 chapters and examines the role of antennas and passive reflectors in radio services, propagation mechanisms related to radar, satellite, short distance, broadcasting and trans-horizon radio links, with two chapters devoted to radio noise and main parameters of radio link design. The book presents some 278 illustration...
Acoustic energy propagation around railways
Cizkova, Petra
2017-09-01
The article deals with the issues of acoustic energy propagation around railways. The research subject was noise emission spreading into the surroundings during the passage of trains over a directly travelled steel bridge construction. Noise emissions were measured using direct measurements in the field. The measurements were performed in two measurement profiles. The noise exposures A LAE measured near the steel bridge construction were compared against the noise exposures A LAE captured on an open track. From the difference of these data, the noise level of the steel bridge structure was determined. Part of the research was to evaluate the effect of the reconstruction of the railway track superstructure on the acoustic situation in the given section of the railway track. The article describes the methodology of measurements, including the processing and evaluation of measured data. The article points out the noise levels of the steel bridge construction and assesses changes in the acoustic situation after the reconstruction.
Pulse Propagation on close conductors
Dieckmann, A
2001-01-01
The propagation and reflection of arbitrarily shaped pulses on non-dispersive parallel conductors of finite length with user defined cross section is simulated employing the discretized telegraph equation. The geometry of the system of conductors and the presence of dielectric material determine the capacities and inductances that enter the calculation. The values of these parameters are found using an iterative Laplace equation solving procedure and confirmed for certain calculable geometries including the line charge inside a box. The evolving pulses and the resulting crosstalk can be plotted at any instant and - in the Mathematica notebook version of this report - be looked at in an animation. As an example a differential pair of microstrips as used in the ATLAS vertex detector is analysed.
IBEX - annular beam propagation experiment
International Nuclear Information System (INIS)
Mazarakis, M.G.; Miller, R.B.; Shope, S.L.; Poukey, J.W.; Ramirez, J.J.; Ekdahl, C.A.; Adler, R.J.
1983-01-01
IBEX is a 4-MV, 100-kA, 20-ns cylindrical isolated Blumlein accelerator. In the experiments reported here, the accelerator is fitted with a specially designed foilless diode which is completely immersed in a uniform magnetic field. Several diode geometries have been studied as a function of magnetic field strength. The beam propagates a distance of 50 cm (approx. 10 cyclotron wavelengths) in vacuum before either striking a beam stop or being extracted through a thin foil. The extracted beam was successfully transported 60 cm downstream into a drift pipe filled either with 80 or 640 torr air. The main objectives of this experiment were to establish the proper parameters for the most quiescent 4 MV, 20 to 40 kA annular beam, and to compare the results with available theory and numerical code simulations
Nonlinear operators and their propagators
International Nuclear Information System (INIS)
Schwartz, C.
1997-01-01
Mathematical physicists are familiar with a large set of tools designed for dealing with linear operators, which are so common in both the classical and quantum theories; but many of those tools are useless with nonlinear equations of motion. In this work a general algebra and calculus is developed for working with nonlinear operators: The basic new tool being the open-quotes slash product,close quotes defined by A(1+εB) =A+εA/B+O(ε 2 ). For a generic time development equation, the propagator is constructed and then there follows the formal version of time dependent perturbation theory, in remarkable similarity to the linear situation. A nonperturbative approximation scheme capable of producing high accuracy computations, previously developed for linear operators, is shown to be applicable as well in the nonlinear domain. A number of auxiliary mathematical properties and examples are given. copyright 1997 American Institute of Physics
Local, zero-power void coefficient measurements in the ACPR
Energy Technology Data Exchange (ETDEWEB)
Rivard, J B; Thome, F V [Sandia Laboratories (United States)
1974-07-01
Changes in reactivity may be stimulated in the ACPR by the local introduction of voids into the reactor coolant. The local void coefficients of reactivity which describe this effect are of interest from a reactor safety point-of-view, and their determination is the subject of this presentation. Bottled nitrogen gas was used to produce the voids. The gas was forced out of a small diameter tube which was positioned vertically in the core lattice with its open end below the fuel. The gas was passed through a pressure regulator, a valve, and a flowmeter to establish a steady flow condition, following which a delayed-critical (zero-power) reactor state was established. Correlation of the average volume of core void created by the nitrogen flow with the reactivity worth of the delayed-critical control-rod bank position produced the values of the zero-power void coefficients of reactivity. The void coefficients were determined at various core positions from {approx}6 mm to 142 mm beyond the central irradiation space and for three different flow rates. For the range of void fractions investigated, these coefficients are negative, with values ranging between -$0.02 and -$0.12. Tabular and graphical results of the measurements are presented, and details of the coefficient determination are explained. (author)