Temperature dependent mobility measurements of alkali earth ions in superfluid helium

Science.gov (United States)

Putlitz, Gisbert Zu; Baumann, I.; Foerste, M.; Jungmann, K.; Riediger, O.; Tabbert, B.; Wiebe, J.; Zühlke, C.

1998-05-01

Mobility measurements of impurity ions in superfluid helium are reported. Alkali earth ions were produced with a laser sputtering technique and were drawn inside the liquid by an electric field. The experiments were carried out in the temperature region from 1.27 up to 1.66 K. The temperature dependence of the mobility of Be^+-ions (measured here for the first time) differs from that of the other alkali earth ions Mg^+, Ca^+, Sr^+ and Ba^+, but behaves similar to that of He^+ (M. Foerste, H. Günther, O. Riediger, J. Wiebe, G. zu Putlitz, Z. Phys. B) 104, 317 (1997). Theories of Atkins (A. Atkins, Phys. Rev.) 116, 1339 (1959) and Cole (M.W. Cole, R.A. Bachmann Phys. Rev. B) 15, 1388 (1977) predict a different defect structure for He^+ and the alkali earth ions: the helium ion is assumed to form a snowball like structure whereas for the alkali earth ions a bubble structure is assumed. If the temperature dependence is a characteristic feature for the different structures, then it seems likely that the Be^+ ion builds a snowball like structure.

The rotational temperature of polar molecular ions in Coulomb crystals

International Nuclear Information System (INIS)

Bertelsen, Anders; Joergensen, Solvejg; Drewsen, Michael

2006-01-01

With MgH + ions as a test case, we investigate to what extent the rotational motion of smaller polar molecular ions sympathetically cooled into Coulomb crystals in linear Paul traps couples to the translational motions of the ion ensemble. By comparing the results obtained from rotational resonance-enhanced multiphoton photo-dissociation experiments with data from theoretical simulations, we conclude that the effective rotational temperature exceeds the translational temperature (<100 mK) by more than two orders of magnitude, indicating a very weak coupling. (letter to the editor)

Electron temperature profiles in axial field 2.45 GHz ECR ion source with a ceramic chamber

Science.gov (United States)

Abe, K.; Tamura, R.; Kasuya, T.; Wada, M.

2017-08-01

An array of electrostatic probes was arranged on the plasma electrode of a 2.45 GHz microwave driven axial magnetic filter field type negative hydrogen (H-) ion source to clarify the spatial plasma distribution near the electrode. The measured spatial distribution of electron temperature indicated the lower temperature near the extraction hole of the plasma electrode corresponding to the effectiveness of the axial magnetic filter field geometry. When the ratio of electron saturation current to the ion saturation current was plotted as a function of position, the obtained distribution showed a higher ratio near the hydrogen gas inlet through which ground state hydrogen molecules are injected into the source. Though the efficiency in producing H- ions is smaller for a 2.45 GHz source than a source operated at 14 GHz, it gives more volume to measure spatial distributions of various plasma parameters to understand fundamental processes that are influential on H- production in this type of ion sources.

Ion mobility spectrometric analysis of vaporous chemical warfare agents by the instrument with corona discharge ionization ammonia dopant ambient temperature operation.

Science.gov (United States)

Satoh, Takafumi; Kishi, Shintaro; Nagashima, Hisayuki; Tachikawa, Masumi; Kanamori-Kataoka, Mieko; Nakagawa, Takao; Kitagawa, Nobuyoshi; Tokita, Kenichi; Yamamoto, Soichiro; Seto, Yasuo

2015-03-20

The ion mobility behavior of nineteen chemical warfare agents (7 nerve gases, 5 blister agents, 2 lachrymators, 2 blood agents, 3 choking agents) and related compounds including simulants (8 agents) and organic solvents (39) was comparably investigated by the ion mobility spectrometry instrument utilizing weak electric field linear drift tube with corona discharge ionization, ammonia doping, purified inner air drift flow circulation operated at ambient temperature and pressure. Three alkyl methylphosphonofluoridates, tabun, and four organophosphorus simulants gave the intense characteristic positive monomer-derived ion peaks and small dimer-derived ion peaks, and the later ion peaks were increased with the vapor concentrations. VX, RVX and tabun gave both characteristic positive monomer-derived ions and degradation product ions. Nitrogen mustards gave the intense characteristic positive ion peaks, and in addition distinctive negative ion peak appeared from HN3. Mustard gas, lewisite 1, o-chlorobenzylidenemalononitrile and 2-mercaptoethanol gave the characteristic negative ion peaks. Methylphosphonyl difluoride, 2-chloroacetophenone and 1,4-thioxane gave the characteristic ion peaks both in the positive and negative ion mode. 2-Chloroethylethylsulfide and allylisothiocyanate gave weak ion peaks. The marker ion peaks derived from two blood agents and three choking agents were very close to the reactant ion peak in negative ion mode and the respective reduced ion mobility was fluctuated. The reduced ion mobility of the CWA monomer-derived peaks were positively correlated with molecular masses among structurally similar agents such as G-type nerve gases and organophosphorus simulants; V-type nerve gases and nitrogen mustards. The slope values of the calibration plots of the peak heights of the characteristic marker ions versus the vapor concentrations are related to the detection sensitivity, and within chemical warfare agents examined the slope values for sarin, soman

Ion temperature anisotropy effects on threshold conditions of a shear-modified current driven electrostatic ion-acoustic instability in the topside auroral ionosphere

Directory of Open Access Journals (Sweden)

P. J. G. Perron

2013-03-01

Full Text Available Temperature anisotropies may be encountered in space plasmas when there is a preferred direction, for instance, a strong magnetic or electric field. In this paper, we study how ion temperature anisotropy can affect the threshold conditions of a shear-modified current driven electrostatic ion-acoustic (CDEIA instability. In particular, this communication focuses on instabilities in the context of topside auroral F-region situations and in the limit where finite Larmor radius corrections are small. We derived a new fluid-like expression for the critical drift which depends explicitly on ion anisotropy. More importantly, for ion to electron temperature ratios typical of F-region, solutions of the kinetic dispersion relation show that ion temperature anisotropy may significantly lower the drift threshold required for instability. In some cases, a perpendicular to parallel ion temperature ratio of 2 and may reduce the relative drift required for the onset of instability by a factor of approximately 30, assuming the ion-acoustic speed of the medium remains constant. Therefore, the ion temperature anisotropy should be considered in future studies of ion-acoustic waves and instabilities in the high-latitude ionospheric F-region.

Comparing Positively and Negatively Charged Distonic Radical Ions in Phenylperoxyl Forming Reactions.

Science.gov (United States)

Williams, Peggy E; Marshall, David L; Poad, Berwyck L J; Narreddula, Venkateswara R; Kirk, Benjamin B; Trevitt, Adam J; Blanksby, Stephen J

2018-06-04

In the gas phase, arylperoxyl forming reactions play a significant role in low-temperature combustion and atmospheric processing of volatile organic compounds. We have previously demonstrated the application of charge-tagged phenyl radicals to explore the outcomes of these reactions using ion trap mass spectrometry. Here, we present a side-by-side comparison of rates and product distributions from the reaction of positively and negatively charge tagged phenyl radicals with dioxygen. The negatively charged distonic radical ions are found to react with significantly greater efficiency than their positively charged analogues. The product distributions of the anion reactions favor products of phenylperoxyl radical decomposition (e.g., phenoxyl radicals and cyclopentadienone), while the comparable fixed-charge cations yield the stabilized phenylperoxyl radical. Electronic structure calculations rationalize these differences as arising from the influence of the charged moiety on the energetics of rate-determining transition states and reaction intermediates within the phenylperoxyl reaction manifold and predict that this influence could extend to intra-molecular charge-radical separations of up to 14.5 Å. Experimental observations of reactions of the novel 4-(1-carboxylatoadamantyl)phenyl radical anion confirm that the influence of the charge on both rate and product distribution can be modulated by increasing the rigidly imposed separation between charge and radical sites. These findings provide a generalizable framework for predicting the influence of charged groups on polarizable radicals in gas phase distonic radical ions. Graphical Abstract.

The influence of ion temperature on solitary waves in collisionless weak relativistic plasma

International Nuclear Information System (INIS)

Cerepaniuc, Adina

2004-01-01

Korteweg-de Vries equation is used to study the influence of the ion temperature, on the ion acoustic waves in the frame of collisionless plasma's weak relativistic effect. In the literature it is discussed the influence of ion temperature on the ion acoustic wave in a relativistic plasma for a ratio of the ion flow velocity to the light velocity between 0 and 1. In this paper, the dependence of the phase velocity on the relativistic effect for different values of the ratio of the ion temperature to the electron temperature is studied. In case of weak relativistic effect (ratio of the ion flow velocity to the light velocity is 10 -6 and the step of the representation is 10 -6 ) we noticed the occurrence of an antisoliton within soliton amplitude graphical representation as function of the relativistic effect and the temperature ratio. The novelty of this article consists in the fact that a much smaller interval is considered for velocity ratio (size) and we studied the influence of ion temperature on ion acoustic wave in a collisionless relativistic plasma. We performed the numerical calculation of equations and we plotted the phase velocity and the amplitude of soliton wave as a function of velocity ratio and the temperature ratio. We considered the step of velocity ratio variation equal with 10 -6 and the step of temperature ratio variation 10 -2 . The observation made in this paper refines the results of other authors who studied these equations for velocity ratio variation of 10 -1 . In herein chosen interval we observed new phenomena that were not noticed in the case of choosing larger intervals. (author)

Temperature effects on interaction of positive ions with plastic detectors

International Nuclear Information System (INIS)

Mendoza Anaya, D.

1992-01-01

The range of heavy charged particles in matter is dependent mainly on two groups of parameters, one related to the particle characteristics (charge z, mass m, energy E) and the other characterized by the stopping medium (charge z, density ρ). Those two groups are enough to describe the particle energy lost, which is related to the residual range. Research on charge particles registration using solid state nuclear track detectors (SSNTD), probe that environmental parameters affect the stabilization and formation of the tracks. One of those, is the temperature detector which shows an important effect during the irradiation on the characteristics of the tracks produced. In order to study the dependence of track geometry as a function of irradiation temperature, some SSNTD (CR 39 type) were irradiated with α particles and fission fragments. Results of this work show the existence of irradiation temperature effect on the track geometry. It is observed a reduction of length and diameters, as temperature increases. For low irradiation temperatures, there is a reduction of the track geometry, as compared with environmental temperature. (Author)

Status of the ATLAS Positive-Ion Injector Project

International Nuclear Information System (INIS)

Pardo, R.C.; Benaroya, R.; Billquist, P.J.

1987-01-01

The goal of the Argonne Positive Ion Injector project is to replace the ATLAS tandem injector with a facility which will increase the beam currents presently available by a factor of 100 and to make available at ATLAS essentially all beams including uranium. The beam quality expected from the facility will be at least as good as that of the tandem based ATLAS. The project combines two relatively new technologies - the electron cyclotron resonance ion source, which provides high charge state ions at microampere currents, and RF superconductivity which has been shown to be capable of generating accelerating fields as high as 10 MV/m, resulting in an essentially new method of acceleration for low-energy heavy ions. 5 refs., 7 figs., 1 tabs

Initial use of the positive-ion injector of ATLAS

International Nuclear Information System (INIS)

Bollinger, L.M.; Billquist, P.J.; Bogaty, J.M.; Clifft, B.E.; Den Hartog, P.K.; Munson, F.H. Jr.; Pardo, R.C.; Shepard, K.W.; Zinkann, G.P.

1989-01-01

The positive-ion injector of ATLAS consists of an ECR heavy-ion source coupled to a 12-MV superconducting injector linac. The ECR source and a 3-MV version of the partially completed linac have been used to accelerate successfully several species of heavy ions. The operating experience is summarized, with emphasis on the excellent beam quality of beams from the new injector. Two new fast-timing detectors are described. 9 refs., 5 figs., 1 tab

Organic positive ions in aircraft gas-turbine engine exhaust

Science.gov (United States)

Sorokin, Andrey; Arnold, Frank

Volatile organic compounds (VOCs) represent a significant fraction of atmospheric aerosol. However the role of organic species emitted by aircraft (as a consequence of the incomplete combustion of fuel in the engine) in nucleation of new volatile particles still remains rather speculative and requires a much more detailed analysis of the underlying mechanisms. Measurements in aircraft exhaust plumes have shown the presence of both different non-methane VOCs (e.g. PartEmis project) and numerous organic cluster ions (MPIK-Heidelberg). However the link between detected organic gas-phase species and measured mass spectrum of cluster ions is uncertain. Unfortunately, up to now there are no models describing the thermodynamics of the formation of primary organic cluster ions in the exhaust of aircraft engines. The aim of this work is to present first results of such a model development. The model includes the block of thermodynamic data based on proton affinities and gas basicities of organic molecules and the block of non-equilibrium kinetics of the cluster ions evolution in the exhaust. The model predicts important features of the measured spectrum of positive ions in the exhaust behind aircraft. It is shown that positive ions emitted by aircraft engines into the atmosphere mostly consist of protonated and hydrated organic cluster ions. The developed model may be explored also in aerosol investigations of the background atmosphere as well as in the analysis of the emission of fine aerosol particles by automobiles.

Ion temperature effects on magnetotail Alfvén wave propagation and electron energization: ION TEMPERATURE EFFECTS ON ALFVÉN WAVES

Energy Technology Data Exchange (ETDEWEB)

Damiano, P. A. [Princeton Center for Heliophysics, Princeton Plasma Physics Laboratory, Princeton University, Princeton New Jersey USA; Johnson, J. R. [Princeton Center for Heliophysics, Princeton Plasma Physics Laboratory, Princeton University, Princeton New Jersey USA; Chaston, C. C. [Space Sciences Laboratory, University of California, Berkeley California USA; School of Physics, University of Sydney, Sydney New South Wales Australia

2015-07-01

A new 2-D self-consistent hybrid gyrofluid-kinetic electron model in dipolar coordinates is presented and used to simulate dispersive-scale Alfvén wave pulse propagation from the equator to the ionosphere along an L = 10 magnetic field line. The model is an extension of the hybrid MHD-kinetic electron model that incorporates ion Larmor radius corrections via the kinetic fluid model of Cheng and Johnson (1999). It is found that consideration of a realistic ion to electron temperature ratio decreases the propagation time of the wave from the plasma sheet to the ionosphere by several seconds relative to a ρi=0 case (which also implies shorter timing for a substorm onset signal) and leads to significant dispersion of wave energy perpendicular to the ambient magnetic field. Additionally, ion temperature effects reduce the parallel current and electron energization all along the field line for the same magnitude perpendicular electric field perturbation.

Damage accumulation in MgO irradiated with MeV Au ions at elevated temperatures

Energy Technology Data Exchange (ETDEWEB)

Bachiller-Perea, Diana, E-mail: dianabachillerperea@gmail.com [Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Univ. Paris-Sud, CNRS-IN2P3, Université Paris-Saclay, 91405, Orsay Cedex (France); Centro de Micro-Análisis de Materiales, Universidad Autónoma de Madrid, C/Faraday 3, 28049, Madrid (Spain); Dpto. de Física Aplicada, Universidad Autónoma de Madrid, Ciudad Universitaria de Cantoblanco, 28049, Madrid (Spain); Debelle, Aurélien, E-mail: aurelien.debelle@u-psud.fr [Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Univ. Paris-Sud, CNRS-IN2P3, Université Paris-Saclay, 91405, Orsay Cedex (France); Thomé, Lionel [Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Univ. Paris-Sud, CNRS-IN2P3, Université Paris-Saclay, 91405, Orsay Cedex (France); Behar, Moni [Instituto de Física, Universidade Federal do Rio Grande do Sul, C.P. 15051, 91501-970, Porto Alegre, RS (Brazil)

2016-09-15

The damage accumulation process in MgO single crystals under medium-energy heavy ion irradiation (1.2 MeV Au) at fluences up to 4 × 10{sup 14} cm{sup −2} has been studied at three different temperatures: 573, 773, and 1073 K. Disorder depth profiles have been determined through the use of the Rutherford backscattering spectrometry in channeling configuration (RBS/C). The analysis of the RBS/C data reveals two steps in the MgO damage process, irrespective of the temperature. However, we find that for increasing irradiation temperature, the damage level decreases and the fluence at which the second step takes place increases. A shift of the damage peak at increasing fluence is observed for the three temperatures, although the position of the peak depends on the temperature. These results can be explained by an enhanced defect mobility which facilitates defect migration and may favor defect annealing. X-ray diffraction reciprocal space maps confirm the results obtained with the RBS/C technique. - Highlights: • High-temperature MeV-ion irradiated MgO exhibits a two-step damage process. • The occurrence of the second step is delayed with increasing temperature. • The damage level decreases with increasing temperature. • A shift of the damage peak is observed with increasing fluence. • A high defect mobility at high temperatures in MgO is clearly evidenced.

Characterization of electron temperature by simulating a multicusp ion source

Energy Technology Data Exchange (ETDEWEB)

Yeon, Yeong Heum [Sungkyunkwan University, WCU Department of Energy Science, 2066, Seobu-ro, Jangan-gu, Suwon-si (Korea, Republic of); Ghergherehchi, Mitra; Kim, Sang Bum; Jun, Woo Jung [Sungkyunkwan University, School of Information & Communication Engineering, 2066, Seobu-ro, Jangan-gu, Suwon-si (Korea, Republic of); Lee, Jong Chul; Mohamed Gad, Khaled Mohamed [Sungkyunkwan University, WCU Department of Energy Science, 2066, Seobu-ro, Jangan-gu, Suwon-si (Korea, Republic of); Namgoong, Ho [Sungkyunkwan University, School of Information & Communication Engineering, 2066, Seobu-ro, Jangan-gu, Suwon-si (Korea, Republic of); Chai, Jong Seo, E-mail: jschai@skku.edu [Sungkyunkwan University, School of Information & Communication Engineering, 2066, Seobu-ro, Jangan-gu, Suwon-si (Korea, Republic of)

2016-12-01

Multicusp ion sources are used in cyclotrons and linear accelerators to produce high beam currents. The structure of a multicusp ion source consists of permanent magnets, filaments, and an anode body. The configuration of the array of permanent magnets, discharge voltage of the plasma, extraction bias voltage, and structure of the multicusp ion source body decide the quality of the beam. The electrons are emitted from the filament by thermionic emission. The emission current can be calculated from thermal information pertaining to the filament, and from the applied voltage and current. The electron trajectories were calculated using CST Particle Studio to optimize the plasma. The array configuration of the permanent magnets decides the magnetic field inside the ion source. The extraction bias voltage and the structure of the multicusp ion source body decide the electric field. Optimization of the electromagnetic field was performed with these factors. CST Particle Studio was used to calculate the electron temperature with a varying permanent magnet array. Four types of permanent magnet array were simulated to optimize the electron temperature. It was found that a 2-layer full line cusp field (with inverse field) produced the best electron temperature control behavior.

Effect of ion temperature on ion-acoustic solitary waves in a magnetized plasma in presence of superthermal electrons

Energy Technology Data Exchange (ETDEWEB)

Singh, S. V.; Devanandhan, S.; Lakhina, G. S. [Indian Institute of Geomagnetism, Navi Mumbai (India); Bharuthram, R. [University of the Western Cape, Bellville (South Africa)

2013-01-15

Obliquely propagating ion-acoustic soliatry waves are examined in a magnetized plasma composed of kappa distributed electrons and fluid ions with finite temperature. The Sagdeev potential approach is used to study the properties of finite amplitude solitary waves. Using a quasi-neutrality condition, it is possible to reduce the set of equations to a single equation (energy integral equation), which describes the evolution of ion-acoustic solitary waves in magnetized plasmas. The temperature of warm ions affects the speed, amplitude, width, and pulse duration of solitons. Both the critical and the upper Mach numbers are increased by an increase in the ion temperature. The ion-acoustic soliton amplitude increases with the increase in superthermality of electrons. For auroral plasma parameters, the model predicts the soliton speed, amplitude, width, and pulse duration, respectively, to be in the range of (28.7-31.8) km/s, (0.18-20.1) mV/m; (590-167) m, and (20.5-5.25) ms, which are in good agreement with Viking observations.

Recycling positive-electrode material of a lithium-ion battery

Science.gov (United States)

Sloop, Steven E.

2017-11-21

Examples are disclosed of methods to recycle positive-electrode material of a lithium-ion battery. In one example, the positive-electrode material is heated under pressure in a concentrated lithium hydroxide solution. After heating, the positive-electrode material is separated from the concentrated lithium hydroxide solution. After separating, the positive electrode material is rinsed in a basic liquid. After rinsing, the positive-electrode material is dried and sintered.

Status of the positive-ion injector for ATLAS

International Nuclear Information System (INIS)

Bollinger, L.M.; Pardo, R.C.; Shepard, K.W.

1986-01-01

The planned positive-ion injector for ATLAS consists of an ECR ion source on a 350-kV platfrom and a superconducting injector linac of a new kind. The objective is to replace the present tandem injector with a system that can increase beam intensities by two orders of magnitude and extend the mass range up to uranium. In the first, developmental stage of the work, now in progress, the ECR source will be built, the technology of superconducting accelerating structures for low-velocity ions will be developed, and these structures will be used to form a 3-MV prototype injector linac. Even this small system, designed for ions with A < 130, will be superior to the present FN tandem as a heavy-ion injector. In later phases of the work, the injector linac will be enlarged enough to allow ATLAS to effectively accelerate uranium ions. The injector system is expected to provide exceptional beam quality. The status of the work, expected performance of the accelerator system, and the technical issues involved are summarized

Properties of plasma sheath with ion temperature in magnetic fusion devices

International Nuclear Information System (INIS)

Liu Jinyuan; Wang Feng; Sun Jizhong

2011-01-01

The plasma sheath properties in a strong magnetic field are investigated in this work using a steady state two-fluid model. The motion of ions is affected heavily by the strong magnetic field in fusion devices; meanwhile, the effect of ion temperature cannot be neglected for the plasma in such devices. A criterion for the plasma sheath in a strong magnetic field, which differs from the well-known Bohm criterion for low temperature plasma sheath, is established theoretically with a fluid model. The fluid model is then solved numerically to obtain detailed sheath information under different ion temperatures, plasma densities, and magnetic field strengths.

Rapid self-heating and internal temperature sensing of lithium-ion batteries at low temperatures

International Nuclear Information System (INIS)

Zhang, Guangsheng; Ge, Shanhai; Xu, Terrence; Yang, Xiao-Guang; Tian, Hua; Wang, Chao-Yang

2016-01-01

Highlights: • Self-heating lithium-ion battery (SHLB) structure provided a practical solution to the poor performance at subzero temperatures. • We report an improved SHLB that heats from −20 °C to 0 °C in 12.5 seconds, or 56% more rapidly, while consuming 24% less energy than previously reported. • The nickel foil heating element embedded inside a SHLB cell plays a dominant role in rapid self-heating. • The embedded nickel foil can simultaneously perform as an internal temperature sensor (ITS). • 2-sheet design self-heats faster than 1-sheet design due to more uniform internal temperature distribution. - Abstract: The recently discovered self-heating lithium-ion battery structure provided a practical solution to the poor performance at subzero temperatures that has hampered battery technology for decades. Here we report an improved self-heating lithium-ion battery (SHLB) that heats from −20 °C to 0 °C in 12.5 seconds, or 56% more rapidly, while consuming 24% less energy than that reported previously. We reveal that a nickel foil heating element embedded inside a SHLB cell plays a dominant role in self-heating and we experimentally demonstrate that a 2-sheet design can achieve dramatically accelerated self-heating due to more uniform internal temperature distribution. We also report, for the first time, that this embedded nickel foil can simultaneously perform as an internal temperature sensor (ITS) due to the perfectly linear relationship between the foil’s electrical resistance and temperature.

Considerations of ion temperature gradient driven turbulence

International Nuclear Information System (INIS)

Cowley, S.C.; Kulsrud, R.M.

1991-02-01

The ion temperature gradient driven instability is considered in this paper. Physical pictures are presented to clarify the nature of the instability. The saturation of a single eddy is modeled by a simple nonlinear equation. We show that eddies which are elongated in the direction of the temperature gradient are the most unstable and have the highest saturation amplitudes. In a sheared magnetic field, such elongated eddies twist with the field lines. This structure is shown to be alternative to the usual Fourier mode picture in which the mode is localized around the surface where k parallel = 0. We show how these elongated twisting eddies, which are an integral part of the ''ballooning mode'' structure, could survive in a torus. The elongated eddies are shown to be unstable to secondary instabilities that are driven by the large gradients in the long eddy. We argue that this mechanism isotropizes ion temperature gradient turbulence. We further argue that the ''mixing length'' is set by this nonlinear process, not by a linear eigenmode width. 17 refs., 6 figs

Spatial profile measurements of ion-confining potentials using novel position-sensitive ion-energy spectrometer arrays

International Nuclear Information System (INIS)

Yoshida, M.; Cho, T.; Hirata, M.; Ito, H.; Kohagura, J.; Yatsu, K.; Miyoshi, S.

2003-01-01

The first experimental demonstration of simultaneous measurements of temporally and spatially resolved ion-confining potentials phi c and end-loss-ion fluxes I ELA has been carried out during a single plasma discharge alone by the use of newly designed ion-energy-spectrometer arrays installed in both end regions of the GAMMA 10 tandem mirror. This position-sensitive ion-detector structure is proposed to obtain precise ion-energy spectra without any perturbations from simultaneously incident energetic electrons into the arrays. The relation between phi c and I ELA is physically interpreted in terms of Pastukhov's potential confinement theory. In particular, the importance of axisymmetric phi c formation is found for the plasma confinement

Installation, tests and start up of the Tandetron positive ions accelerator; Instalacion, pruebas y arranque del acelerador de iones positivos Tandetron

Energy Technology Data Exchange (ETDEWEB)

Valdovinos A, M.A.; Hernandez M, V. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, Mexico D.F. (Mexico)

2000-07-01

The National Institute of Nuclear Research acquired a Positive ions accelerator type Tandetron 2MV of the Dutch Company High Voltage Engineering, Europe B.V. (H.V.E.E.) which was installed in the building named Irradiator Nave which is occupied by the Gamma irradiator and the Pelletron accelerator. Starting from the accelerator selection it was defined the conditions required for the operation of this as well as: electric feeding, water quality and quantity, air compressed, temperature, humidity, etc.; as well as the necessary modifications of the installation area. (Author)

Note: Development of ESS Bilbao's proton ion source: Ion Source Hydrogen Positive

International Nuclear Information System (INIS)

Miracoli, R.; Feuchtwanger, J.; Arredondo, I.; Belver, D.; Gonzalez, P. J.; Corres, J.; Djekic, S.; Echevarria, P.; Eguiraun, M.; Garmendia, N.; Muguira, L.

2014-01-01

The Ion Source Hydrogen positive is a 2.7 GHz off-resonance microwave discharge ion source. It uses four coils to generate an axial magnetic field in the plasma chamber around 0.1 T that exceeds the ECR resonance field. A new magnetic system was designed as a combination of the four coils and soft iron in order to increase the reliability of the source. The description of the simulations of the magnetic field and the comparison with the magnetic measurements are presented. Moreover, results of the initial commissioning of the source for extraction voltage until 50 kV will be reported

Formation and termination of High ion temperature mode in Heliotron/torsatron plasmas

International Nuclear Information System (INIS)

Ida, K.; Kondo, K.; Nagasaki, K.

1997-01-01

Physics of the formation and termination of High ion temperature mode (high T i mode) are studied by controlling density profiles and radial electric field. High ion temperature mode is observed for neutral beam heated plasmas in Heliotron/torsatron plasmas (Heliotron-E). This high T i mode plasma is characterized by a peaked ion temperature profile and is associated with a peaked electron density profile produced by neutral beam fueling with low wall recycling. This high T i mode is terminated by flattening the electron density caused by either gas puffing or second harmonic ECH (core density 'pump-out'). (author)

Impact of temperature on single event upset measurement by heavy ions in SRAM devices

International Nuclear Information System (INIS)

Liu Tianqi; Geng Chao; Zhang Zhangang; Gu Song; Tong Teng; Xi Kai; Hou Mingdong; Liu Jie; Zhao Fazhan; Liu Gang; Han Zhengsheng

2014-01-01

The temperature dependence of single event upset (SEU) measurement both in commercial bulk and silicon on insulator (SOI) static random access memories (SRAMs) has been investigated by experiment in the Heavy Ion Research Facility in Lanzhou (HIRFL). For commercial bulk SRAM, the SEU cross section measured by 12 C ions is very sensitive to the temperature. The temperature test of SEU in SOI SRAM was conducted by 209 Bi and 12 C ions, respectively, and the SEU cross sections display a remarkable growth with the elevated temperature for 12 C ions but keep constant for 209 Bi ions. The impact of temperature on SEU measurement was analyzed by Monte Carlo simulation. It is revealed that the SEU cross section is significantly affected by the temperature around the threshold linear energy transfer of SEU occurrence. As the SEU occurrence approaches saturation, the SEU cross section gradually exhibits less temperature dependency. Based on this result, the experimental data measured in HIRFL was analyzed, and then a reasonable method of predicting the on-orbit SEU rate was proposed. (semiconductor devices)

Variable-temperature sample system for ion implantation at -192 to +5000C

International Nuclear Information System (INIS)

Fuller, C.T.

1978-04-01

A variable-temperature sample system based on exchange-gas coupling was developed for ion-implantation use. The sample temperature can be controlled from -192 0 C to +500 0 C with rapid cooling. The system also has provisions for focusing and alignment of the ion beam, electron suppression, temperature monitoring, sample current measuring, and cryo-shielding. Design considerations and operating characteristics are discussed. 5 figures

First operation of the ATLAS Positive-Ion Injector

International Nuclear Information System (INIS)

Pardo, R.C.; Bollinger, L.M.; Shepard, K.W.; Billquist, P.J.; Bogaty, J.M.; Clifft, B.E.; Harkewicz, R.; Munson, F.H.; Nolen, J.A.; Zinkann, G.P.

1992-01-01

The construction of the ATLAS Positive-Ion Injector (PII) is complete and beam acceleration tests are underway. The PII consists of an ECR ion source, on a high-voltage platform, providing beam to a low-velocity-acceptance, independently-phased, superconducting linac. This injector enables the ATLAS facility to accelerate any heavy ion, including uranium, to energies in excess of the Coulomb barrier. The design accelerating field performance has been exceeded, with an average accelerating field of approximately 3.2 MV/m achieved in early tests. Initial beam tests of the entire injector indicate tat all important performance goals have been met. This paper describes the results of these early tests and discusses our initial operating experience with the whole ATLAS system

First operation of the ATLAS positive-ion injector

International Nuclear Information System (INIS)

Pardo, R.C.; Bollinger, L.M.; Shephard, K.W.; Billquist, P.J.; Bogaty, J.M.; Clifft, B.E.; Harkewicz, R.; Munson, F.H.; Nolen, J.A.; Zinkann, G.P.

1992-01-01

The construction of the ATLAS Positive-Ion Injector (PII) is complete and beam acceleration tests are underway. The PII consists of an ECR ion source, on a high-voltage platform, providing beam to a low-velocity-acceptance, independently-phased, superconducting linac. This injector enables the ATLAS facility to accelerate any heavy ion, including uranium, to energies in excess of the Coulomb barrier. The design accelerating field performance has been exceeded, with an average accelerating field of approximately 3.2 MV/m achieved in early tests. Initial beam tests of the entire injector indicate that all important performance goals have been met. This paper describes the results of these early tests and discusses our initial operating experience with the whole ATLAS system. (Author) 5 refs., tab., fig

Kinetic theory for electron dynamics near a positive ion

International Nuclear Information System (INIS)

Wrighton, Jeffrey M; Dufty, James W

2008-01-01

A theoretical description of time correlation functions for electron properties in the presence of a positive ion of charge number Z is given. The simplest case of an electron gas distorted by a single ion is considered. A semi-classical representation with a regularized electron–ion potential is used to obtain a linear kinetic theory that is asymptotically exact at short times. This Markovian approximation includes all initial (equilibrium) electron–electron and electron–ion correlations through renormalized pair potentials. The kinetic theory is solved in terms of single-particle trajectories of the electron–ion potential and a dielectric function for the inhomogeneous electron gas. The results are illustrated by a calculation of the autocorrelation function for the electron field at the ion. The dependence on charge number Z is shown to be dominated by the bound states of the effective electron–ion potential. On this basis, a very simple practical representation of the trajectories is proposed and shown to be accurate over a wide range including strong electron–ion coupling. This simple representation is then used for a brief analysis of the dielectric function for the inhomogeneous electron gas

A possibility of local measurements of ion temperature in a high-temperature plasma by laser induced ionization

International Nuclear Information System (INIS)

Kantor, M

2012-01-01

A new diagnostic for local measurements of ion temperature and drift velocity in fusion plasmas is proposed in the paper. The diagnostic is based on laser induced ionization of excited hydrogen and deuterium atoms from the levels which ionization energy less than the laser photon energy. A high intensive laser beam ionizes nearly all the excited atoms in the beam region resulting in a quench of spontaneous line emission of the appropriate optical transitions. The measurements of the quenching emission have been used in the past for local measurements of hydrogen atom density in tokamak plasma. The idea of the new diagnostic is spectral resolution of the quenching emission. The measured spectrum relates directly to the velocity distribution of the excited atoms. This distribution is strongly coupled to the distribution of the hydrogen atoms at the ground state. So, the spectral resolution of quenching emission is a way of local measurements of the temperature and drift velocity of hydrogen atoms in plasma. The temperature of hydrogen atoms is well coupled to the local ion temperature as long as the mean free path of the atoms is shorter than the ion gradient length in plasma. In this case the new diagnostic can provide local measurements of ion temperature in plasma. The paper considers technical capabilities of the diagnostic, physical restrictions of its application and interpretation of the measurements.

An assessment of ion temperature measurements in the boundary of the Alcator C-Mod tokamak and implications for ion fluid heat flux limiters

International Nuclear Information System (INIS)

Brunner, D; LaBombard, B; Churchill, R M; Hughes, J; Lipschultz, B; Ochoukov, R; Theiler, C; Walk, J; Rognlien, T D; Umansky, M V; Whyte, D

2013-01-01

The ion temperature is not frequently measured in the boundary of magnetic fusion devices. Comparisons among different ion temperature techniques and simulations are even rarer. Here we present a comparison of ion temperature measurements in the boundary of the Alcator C-Mod tokamak from three different diagnostics: charge exchange recombination spectroscopy (CXRS), an ion sensitive probe (ISP), and a retarding field analyzer (RFA). Comparison between CXRS and the ISP along with close examination of the ISP measurements reveals that the ISP is space charge limited. It is thus unable to measure ion temperature in the high density (>10 19 m −3 ) boundary plasma of C-Mod with its present geometry. Comparison of ion temperatures measured by CXRS and the RFA shows fair agreement. Ion and electron parallel heat flow is analyzed with a simple 1D fluid code. The code takes divertor measurements as input and results are compared to the measured ratios of upstream ion to electron temperature, as inferred respectively by CXRS and a Langmuir probe. The analysis reveals the limits of the fluid model at high Knudsen number. The upstream temperature ratio is under predicted by a factor of 2. Heat flux limiters (kinetic corrections) to the fluid model are necessary to match experimental data. The values required are found to be close to those reported in kinetic simulations. The 1D code is benchmarked against the 2D plasma fluid code UEDGE with good agreement. (paper)

An assessment of ion temperature measurements in the boundary of the Alcator C-Mod tokamak and implications for ion fluid heat flux limiters

Science.gov (United States)

Brunner, D.; LaBombard, B.; Churchill, R. M.; Hughes, J.; Lipschultz, B.; Ochoukov, R.; Rognlien, T. D.; Theiler, C.; Walk, J.; Umansky, M. V.; Whyte, D.

2013-09-01

The ion temperature is not frequently measured in the boundary of magnetic fusion devices. Comparisons among different ion temperature techniques and simulations are even rarer. Here we present a comparison of ion temperature measurements in the boundary of the Alcator C-Mod tokamak from three different diagnostics: charge exchange recombination spectroscopy (CXRS), an ion sensitive probe (ISP), and a retarding field analyzer (RFA). Comparison between CXRS and the ISP along with close examination of the ISP measurements reveals that the ISP is space charge limited. It is thus unable to measure ion temperature in the high density (>1019 m-3) boundary plasma of C-Mod with its present geometry. Comparison of ion temperatures measured by CXRS and the RFA shows fair agreement. Ion and electron parallel heat flow is analyzed with a simple 1D fluid code. The code takes divertor measurements as input and results are compared to the measured ratios of upstream ion to electron temperature, as inferred respectively by CXRS and a Langmuir probe. The analysis reveals the limits of the fluid model at high Knudsen number. The upstream temperature ratio is under predicted by a factor of 2. Heat flux limiters (kinetic corrections) to the fluid model are necessary to match experimental data. The values required are found to be close to those reported in kinetic simulations. The 1D code is benchmarked against the 2D plasma fluid code UEDGE with good agreement.

Experimental Evaluation of a Negative Ion Source for a Heavy Ion Fusion Negative Ion Driver

International Nuclear Information System (INIS)

Grisham, L.R.; Hahto, S.K.; Hahto, S.T.; Kwan, J.W.; Leung, K.N.

2004-01-01

Negative halogen ions have recently been proposed as a possible alternative to positive ions for heavy ion fusion drivers because electron accumulation would not be a problem in the accelerator, and if desired, the beams could be photo-detached to neutrals. To test the ability to make suitable quality beams, an experiment was conducted at Lawrence Berkeley National Laboratory using chlorine in an RF-driven ion source. Without introducing any cesium (which is required to enhance negative ion production in hydrogen ion sources) a negative chlorine current density of 45 mA/cm 2 was obtained under the same conditions that gave 57 45 mA/cm 2 of positive chlorine, suggesting the presence of nearly as many negative ions as positive ions in the plasma near the extraction plane. The negative ion spectrum was 99.5% atomic chlorine ions, with only 0.5% molecular chlorine, and essentially no impurities. Although this experiment did not incorporate the type of electron suppression technology that i s used in negative hydrogen beam extraction, the ratio of co-extracted electrons to Cl - was as low as 7 to 1, many times lower than the ratio of their mobilities, suggesting that few electrons are present in the near-extractor plasma. This, along with the near-equivalence of the positive and negative ion currents, suggests that the plasma in this region was mostly an ion-ion plasma. The negative chlorine current density was relatively insensitive to pressure, and scaled linearly with RF power. If this linear scaling continues to hold at higher RF powers, it should permit current densities of 100 45 mA/cm 2 , sufficient for present heavy ion fusion injector concepts. The effective ion temperatures of the positive and negative ions appeared to be similar and relatively low for a plasma source

Effects of electron-ion temperature equilibration on inertial confinement fusion implosions.

Science.gov (United States)

Xu, Barry; Hu, S X

2011-07-01

The electron-ion temperature relaxation essentially affects both the laser absorption in coronal plasmas and the hot-spot formation in inertial confinement fusion (ICF). It has recently been reexamined for plasma conditions closely relevant to ICF implosions using either classical molecular-dynamics simulations or analytical methods. To explore the electron-ion temperature equilibration effects on ICF implosion performance, we have examined two Coulomb logarithm models by implementing them into our hydrocodes, and we have carried out hydrosimulations for ICF implosions. Compared to the Lee-More model that is currently used in our standard hydrocodes, the two models predict substantial differences in laser absorption, coronal temperatures, and neutron yields for ICF implosions at the OMEGA Laser Facility [Boehly et al. Opt. Commun. 133, 495 (1997)]. Such effects on the triple-picket direct-drive design at the National Ignition Facility (NIF) have also been explored. Based on the validity of the two models, we have proposed a combined model of the electron-ion temperature-relaxation rate for the overall ICF plasma conditions. The hydrosimulations using the combined model for OMEGA implosions have shown ∼6% more laser absorption, ∼6%-15% higher coronal temperatures, and ∼10% more neutron yield, when compared to the Lee-More model prediction. It is also noticed that the gain for the NIF direct-drive design can be varied by ∼10% among the different electron-ion temperature-relaxation models.

Ion-Ion Plasmas Produced by Electron Beams

Science.gov (United States)

Fernsler, R. F.; Leonhardt, D.; Walton, S. G.; Meger, R. A.

2001-10-01

The ability of plasmas to etch deep, small-scale features in materials is limited by localized charging of the features. The features charge because of the difference in electron and ion anisotropy, and thus one solution now being explored is to use ion-ion plasmas in place of electron-ion plasmas. Ion-ion plasmas are effectively electron-free and consist mainly of positive and negative ions. Since the two ion species behave similarly, localized charging is largely eliminated. However, the only way to produce ion-ion plasmas at low gas pressure is to convert electrons into negative ions through two-body attachment to neutrals. While the electron attachment rate is large at low electron temperatures (Te < 1 eV) in many of the halogen gases used for processing, these temperatures occur in most reactors only during the afterglow when the heating fields are turned off and the plasma is decaying. By contrast, Te is low nearly all the time in plasmas produced by electron beams, and therefore electron beams can potentially produce ion-ion plasmas continuously. The theory of ion-ion plasmas formed by pulsed electron beams is examined in this talk and compared with experimental results presented elsewhere [1]. Some general limitations of ion-ion plasmas, including relatively low flux levels, are discussed as well. [1] See the presentation by D. Leonhardt et al. at this conference.

ICF implosion hotspot ion temperature diagnostic techniques based on neutron time-of-flight method

International Nuclear Information System (INIS)

Tang Qi; Song Zifeng; Chen Jiabin; Zhan Xiayu

2013-01-01

Ion temperature of implosion hotspot is a very important parameter for inertial confinement fusion. It reflects the energy level of the hotspot, and it is very sensitive to implosion symmetry and implosion speed. ICF implosion hotspot ion temperature diagnostic techniques based on neutron time-of-flight method were described. A neutron TOF spectrometer was developed using a ultrafast plastic scintillator as the neutron detector. Time response of the spectrometer has 1.1 ns FWHM and 0.5 ns rising time. TOF spectrum resolving method based on deconvolution and low pass filter was illuminated. Implosion hotspot ion temperature in low neutron yield and low ion temperature condition at Shenguang-Ⅲ facility was acquired using the diagnostic techniques. (authors)

Magnetized retarding field energy analyzer measuring the particle flux and ion energy distribution of both positive and negative ions

International Nuclear Information System (INIS)

Rafalskyi, Dmytro; Aanesland, Ane; Dudin, Stanislav

2015-01-01

This paper presents the development of a magnetized retarding field energy analyzer (MRFEA) used for positive and negative ion analysis. The two-stage analyzer combines a magnetic electron barrier and an electrostatic ion energy barrier allowing both positive and negative ions to be analyzed without the influence of electrons (co-extracted or created downstream). An optimal design of the MRFEA for ion-ion beams has been achieved by a comparative study of three different MRFEA configurations, and from this, scaling laws of an optimal magnetic field strength and topology have been deduced. The optimal design consists of a uniform magnetic field barrier created in a rectangular channel and an electrostatic barrier consisting of a single grid and a collector placed behind the magnetic field. The magnetic barrier alone provides an electron suppression ratio inside the analyzer of up to 6000, while keeping the ion energy resolution below 5 eV. The effective ion transparency combining the magnetic and electrostatic sections of the MRFEA is measured as a function of the ion energy. It is found that the ion transparency of the magnetic barrier increases almost linearly with increasing ion energy in the low-energy range (below 200 eV) and saturates at high ion energies. The ion transparency of the electrostatic section is almost constant and close to the optical transparency of the entrance grid. We show here that the MRFEA can provide both accurate ion flux and ion energy distribution measurements in various experimental setups with ion beams or plasmas run at low pressure and with ion energies above 10 eV

Note: Buffer gas temperature inhomogeneities and design of drift-tube ion mobility spectrometers: Warnings for real-world applications by non-specialists

Science.gov (United States)

Fernandez-Maestre, R.

2017-09-01

Ion mobility spectrometry (IMS) separates gas phase ions moving under an electric field according to their size-to-charge ratio. IMS is the method of choice to detect illegal drugs and explosives in customs and airports making accurate determination of reduced ion mobilities (K0) important for national security. An ion mobility spectrometer with electrospray ionization coupled to a quadrupole mass spectrometer was used to study uncertainties in buffer gas temperatures during mobility experiments. Differences up to 16°C were found in the buffer gas temperatures in different regions of the drift tube and up to 42°C between the buffer gas and the drift tube temperatures. The drift tube temperature is used as an approximation to the buffer gas temperature for the calculation of K0 because the buffer gas temperature is hard to measure. This is leading to uncertainties in the determination of K0 values. Inaccurate determination of K0 values yields false positives that delay the cargo and passengers in customs and airports. Therefore, recommendations are issued for building mobility tubes to assure a homogeneous temperature of the buffer gas. Because the temperature and other instrumental parameters are difficult to measure in IMS, chemical standards should always be used when calculating K0. The difference of 42°C between the drift tube and buffer gas temperatures found in these experiments produces a 10.5% error in the calculation of K0. This large inaccuracy in K0 shows the importance of a correct temperature measurement in IMS.

The positive-ion injector of ATLAS: design and operating experience

Energy Technology Data Exchange (ETDEWEB)

Bollinger, L M [Physics Div., Argonne National Lab., IL (United States); Pardo, R C [Physics Div., Argonne National Lab., IL (United States); Shepard, K W [Physics Div., Argonne National Lab., IL (United States); Billquist, P J [Physics Div., Argonne National Lab., IL (United States); Bogaty, J M [Physics Div., Argonne National Lab., IL (United States); Clifft, B E [Physics Div., Argonne National Lab., IL (United States); Harkewicz, R [Physics Div., Argonne National Lab., IL (United States); Munson, F H [Physics Div., Argonne National Lab., IL (United States); Nolen, J A [Physics Div., Argonne National Lab., IL (United States); Zinkann, G P [Physics Div., Argonne National Lab., IL (United States)

1993-06-01

The recently completed positive-ion injector for the heavy-ion accelerator ATLAS is a replacement for the tandem injector of the present tandem-linac system. Unlike the tandem, the new injector provides ions from the full range of the periodic table. The concept for the new injector, which consists of an ECR ion source on a voltage platform coupled to a very-low-velocity superconducting linac, introduces technical problems and uncertainties that are well beyond those encountered previously for superconducting linacs. The solution to these problems and their relationship to performance are outlined, and experience in the operation of ATLAS with its new injector is discussed. (orig.)

The positive-ion injector of ATLAS: Design and operating experience

International Nuclear Information System (INIS)

Bollinger, L.M.; Pardo, R.C.; Shepard, K.W.; Billquist, P.J.; Bogaty, J.M.; Clifft, B.E.; Harkewicz, R.; Munson, F.H.; Nolen, J.A.; Zinkann, G.P.

1992-01-01

The recently completed Positive-Ion Injector for the heavy-ion accelerator ATLAS is a replacement for the tandem injector of the present tandem-linac system. Unlike the tandem, the new injector provides ions from the full range of the periodic table. The concept for the new injector, which consists of an ECR ion source on a voltage platform coupled to a very-low-velocity superconducting linac, introduces technical problems and uncertainties that are well beyond those encountered previously for superconducting linacs. The solution to these problems and their relationship to performance are outlined, and experience in the operation of ATLAS with its new injector is discussed

Instantaneous measurement of the internal temperature in lithium-ion rechargeable cells

International Nuclear Information System (INIS)

Srinivasan, Rengaswamy; Carkhuff, Bliss G.; Butler, Michael H.; Baisden, Andrew C.

2011-01-01

We demonstrate, in three different rechargeable lithium-ion cells, the existence of an intrinsic relationship between a cell's internal temperature and a readily measurable electrical parameter, namely the phase shift between an applied sinusoidal current and the resulting voltage. The temperature range examined spanned from -20 to 66 deg. C. The optimum single frequency for the phase measurement is in the 40-100 Hz range, allowing for a measurement time of much less than a second; the phase shift in this range depends predominantly on temperature, and is almost completely independent of the state-of-charge. Literature reports suggest that the observed dependence of the phase shift on temperature arises from the ionic conduction of the so-called solid-electrolyte-interphase layer between the graphite anode and the electrolyte. A meter measuring the phase shift across this interphase is analogous to a thermometer reporting the temperature, thereby providing feedback for rapid corrections of any operating conditions that might lead to the catastrophic destruction of the cell. This level of monitoring and control is distinctly different from the present safety-enabling mechanisms: typically positive thermal coefficient ceramics/plastics, or 'shutdown' separators based on polyethylene that act to often permanently shut down current flow through the cell.

Electron stimulated desorption of positive and negative oxygen ions from YBa{sub 2}Cu{sub 3}O{sub 7} surfaces

Energy Technology Data Exchange (ETDEWEB)

Hoffman, A. [Technion-Israel Inst. of Tech., Haifa (Israel). Solid State Inst.; Moss, S.D.; Paterson, P.J.K. [Royal Melbourne Inst. of Tech., VIC (Australia); McCubbery, D. [La Trobe Univ., Bundoora, VIC (Australia); Petravic, M. [Australian National Univ., Canberra, ACT (Australia)

1996-12-31

The electron stimulated desorption (ESD) of positive and negative oxygen ion from superconducting YBa{sub 2}Cu{sub 3}O{sub 7} surfaces was studied. Based on ion desorption yield measurements as function of electron kinetic energy, primary excitations leading to positive and negative oxygen ion desorption are suggested. To the best of the authors` knowledge this is the first study on electron energy dependent ESD from YBa{sub 2}Cu{sub 3}O{sub 7} surfaces. The YBa{sub 2}Cu{sub 3}O{sub 7} samples were prepared from BaCO{sub 3}, Y{sub 2}O{sub 3} and CuO using standard high temperature sintering and annealing procedures. Slices 2 mm thick were cut and further annealed at 400 C in flowing oxygen for 24 hours prior to insertion into the ultrahigh vacuum (UHV) chamber for ESD. The near surface composition and chemical state of the annealed sample after exposure to air was examined by Auger and XPS analysis. These measurements suggest that the ESD experiments were performed on samples of similar near surface and bulk composition with some OH- chemisorbed groups and Cl surface contaminations and that negative and positive oxygen ion desorption may be initiated via a primary core level ionization. 10 refs., 3 figs.

Electron stimulated desorption of positive and negative oxygen ions from YBa{sub 2}Cu{sub 3}O{sub 7} surfaces

Energy Technology Data Exchange (ETDEWEB)

Hoffman, A [Technion-Israel Inst. of Tech., Haifa (Israel). Solid State Inst.; Moss, S D; Paterson, P J.K. [Royal Melbourne Inst. of Tech., VIC (Australia); McCubbery, D [La Trobe Univ., Bundoora, VIC (Australia); Petravic, M [Australian National Univ., Canberra, ACT (Australia)

1997-12-31

The electron stimulated desorption (ESD) of positive and negative oxygen ion from superconducting YBa{sub 2}Cu{sub 3}O{sub 7} surfaces was studied. Based on ion desorption yield measurements as function of electron kinetic energy, primary excitations leading to positive and negative oxygen ion desorption are suggested. To the best of the authors` knowledge this is the first study on electron energy dependent ESD from YBa{sub 2}Cu{sub 3}O{sub 7} surfaces. The YBa{sub 2}Cu{sub 3}O{sub 7} samples were prepared from BaCO{sub 3}, Y{sub 2}O{sub 3} and CuO using standard high temperature sintering and annealing procedures. Slices 2 mm thick were cut and further annealed at 400 C in flowing oxygen for 24 hours prior to insertion into the ultrahigh vacuum (UHV) chamber for ESD. The near surface composition and chemical state of the annealed sample after exposure to air was examined by Auger and XPS analysis. These measurements suggest that the ESD experiments were performed on samples of similar near surface and bulk composition with some OH- chemisorbed groups and Cl surface contaminations and that negative and positive oxygen ion desorption may be initiated via a primary core level ionization. 10 refs., 3 figs.

Measuring main-ion temperatures in ASDEX upgrade using scattering of ECRH radiation

DEFF Research Database (Denmark)

Pedersen, Morten Stejner; Nielsen, Stefan Kragh; Jacobsen, Asger Schou

2016-01-01

We demonstrate that collective Thomson scattering of millimeter wave electron cyclotron resonance heating radiation can be used for measurements of the main-ion temperature in the ASDEX Upgrade tokamak.......We demonstrate that collective Thomson scattering of millimeter wave electron cyclotron resonance heating radiation can be used for measurements of the main-ion temperature in the ASDEX Upgrade tokamak....

Considerations from the viewpoint of neoclassical transport towards higher ion temperature heliotron plasmas

International Nuclear Information System (INIS)

Yokoyama, M.; Matsuoka, S.; Funaba, H.; Ida, K.; Nagaoka, K.; Yoshinuma, M.; Takeiri, Y.; Kaneko, O.

2010-01-01

The neoclassical (NC) transport analyses have been performed to elucidate the plausible approaches towards higher ion-temperature heliotron plasmas. Avoidance of the ripple transport is the key issue, for which the neoclassical ambipolar radial electric field (E r ) can be utilized. The ion-root scenario and the electron-root scenario are expected to be effective according to the experimental situation (especially, the temperature ratio between ions and electrons). The impact of the ion mass on the neoclassical ambipolar E r is also investigated to reveal the easier realization of electron-root E r in heavier ion plasmas. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Angle-resolved ion TOF spectrometer with a position sensitive detector

Energy Technology Data Exchange (ETDEWEB)

Saito, Norio [Electrotechnical Lab., Tsukuba, Ibaraki (Japan); Heiser, F; Wieliczec, K; Becker, U

1996-07-01

A angle-resolved ion time-of-flight mass spectrometer with a position sensitive anode has been investigated. Performance of this spectrometer has been demonstrated by measuring an angular distribution of a fragment ion pair, C{sup +} + O{sup +}, from CO at the photon energy of 287.4 eV. The obtained angular distribution is very close to the theoretically expected one. (author)

Ion acoustic solitons/double layers in two-ion plasma revisited

International Nuclear Information System (INIS)

Lakhina, G. S.; Singh, S. V.; Kakad, A. P.

2014-01-01

Ion acoustic solitons and double layers are studied in a collisionless plasma consisting of cold heavier ion species, a warm lighter ion species, and hot electrons having Boltzmann distributions by Sagdeev pseudo-potential technique. In contrast to the previous results, no double layers and super-solitons are found when both the heavy and lighter ion species are treated as cold. Only the positive potential solitons are found in this case. When the thermal effects of the lighter ion species are included, in addition to the usual ion-acoustic solitons occurring at M > 1 (where the Mach number, M, is defined as the ratio of the speed of the solitary wave and the ion-acoustic speed considering temperature of hot electrons and mass of the heavier ion species), slow ion-acoustic solitons/double layers are found to occur at low Mach number (M < 1). The slow ion-acoustic mode is actually a new ion-ion hybrid acoustic mode which disappears when the normalized number density of lighter ion species tends to 1 (i.e., no heavier species). An interesting property of the new slow ion-acoustic mode is that at low number density of the lighter ion species, only negative potential solitons/double layers are found whereas for increasing densities there is a transition first to positive solitons/double layers, and then only positive solitons. The model can be easily applicable to the dusty plasmas having positively charged dust grains by replacing the heavier ion species by the dust mass and doing a simple normalization to take account of the dust charge

Research of fuel temperature control in fuel pipeline of diesel engine using positive temperature coefficient material

Directory of Open Access Journals (Sweden)

Xiaolu Li

2016-01-01

Full Text Available As fuel temperature increases, both its viscosity and surface tension decrease, and this is helpful to improve fuel atomization and then better combustion and emission performances of engine. Based on the self-regulated temperature property of positive temperature coefficient material, this article used a positive temperature coefficient material as electric heating element to heat diesel fuel in fuel pipeline of diesel engine. A kind of BaTiO3-based positive temperature coefficient material, with the Curie temperature of 230°C and rated voltage of 24 V, was developed, and its micrograph and element compositions were also analyzed. By the fuel pipeline wrapped in six positive temperature coefficient ceramics, its resistivity–temperature and heating characteristics were tested on a fuel pump bench. The experiments showed that in this installation, the surface temperature of six positive temperature coefficient ceramics rose to the equilibrium temperature only for 100 s at rated voltage. In rated power supply for six positive temperature coefficient ceramics, the temperature of injection fuel improved for 21°C–27°C within 100 s, and then could keep constant. Using positive temperature coefficient material to heat diesel in fuel pipeline of diesel engine, the injection mass per cycle had little change, approximately 0.3%/°C. This study provides a beneficial reference for improving atomization of high-viscosity liquids by employing positive temperature coefficient material without any control methods.

The impact of edge gradients in the pressure, density, ion temperature, and electron temperature on edge-localized modes

International Nuclear Information System (INIS)

Kleva, Robert G.; Guzdar, Parvez N.

2011-01-01

The magnitude of the energy and particle fluxes in simulations of edge-localized modes (ELMs) is determined by the edge gradients in the pressure, density, ion temperature, and electron temperature. The total edge pressure gradient is the dominant influence on ELMs by far. An increase (decrease) of merely 2% in the pressure gradient results in an increase (decrease) of more than a factor of ten in the size of the ELM bursts. At a fixed pressure gradient, the size of the ELM bursts decreases as the density gradient increases, while the size of the bursts increases as the electron temperature gradient or, especially, the ion temperature gradient increases.

Contributions to the study of positive ion kinetics in gases

International Nuclear Information System (INIS)

Popescu, A.

1978-01-01

Extensive studies on cesium ion kinetics in cesium and cesium-noble gas mixtures were performed. The obtained data are correlated with the measured parameters of the thermionic diodes. The mobility of atomic and molecular cesium ions at low electric fields, including zero electric field, in cesium and cesium krypton mixtures were measured using the time of flight method and a special thermionic ion detector. The atomic ion conversion into molecular ions is theoretically considered in the diffusion equation of the charged particles and the obtained analytical relation is in good agreement with the experimental cesium measured data. The reaction rate of the ion conversion in cesium is considered from these measurements. Measurements on the diffused plasma through the anode (provided with holes) of the cesium thermionic diode supply data on the anode sheath, the ratio of electronic and ionic current, electron temperature and the nature of the cesium ions (atomic or molecular) for various modes of the low voltage arc discharge. The obtained data have been used for the optimization of the thermionic diode parameters, as well as for the development of a new type of device for the detection of impurities in the air. (author)

A comprehensive review of lithium-ion batteries used in hybrid and electric vehicles at cold temperatures

International Nuclear Information System (INIS)

Jaguemont, J.; Boulon, L.; Dubé, Y.

2016-01-01

Highlights: • We present a comprehensive review on lithium ion batteries used in hybrid and electric vehicles under cold temperatures. • The weak performances of lithium-ion batteries in cold weather are explained. • The influence of low temperatures on the aging mechanisms of lithium ion batteries is discussed. • The different uses of thermal strategies in an automotive application are proposed. - Abstract: Because of their numerous advantages, lithium-ion (Li-ion) batteries have recently become a focus of research interest for vehicle applications. Li-ion batteries are suitable for electric vehicles (EVs) and hybrid electric vehicles (HEVs) because of advantages such as their high specific energy, high energy density, and low self-discharge rate in comparison with other secondary batteries. Nevertheless, the commercial availability of Li-ion batteries for vehicle applications has been hindered by issues of safety, cost, charging time, and recycling. One principal limitation of this technology resides in its poor low-temperature performance. Indeed, the effects of low temperature reduce the battery’s available energy and increase its internal impedance. In addition, performance-hampering cell degradation also occurs at low temperatures and throughout the entire life of a Li-ion battery. All of these issues pose major difficulties for cold-climate countries. This paper reviews the effects of cold temperatures on the capacity/power fade of Li-ion battery technology. Extensive attention is paid to the aging mechanisms of Li-ion batteries at cold temperatures. This paper also reviews several battery models found in the literature. Finally, thermal strategies are detailed, along with a discussion of the ideal approach to cold-temperature operation.

Study on Energetic Ions Behavior in Plasma Facing Materials at Lower Temperature

International Nuclear Information System (INIS)

Morimoto, Y.; Sugiyama, T.; Akahori, S.; Kodama, H.; Tega, E.; Sasaki, M.; Oyaidu, M.; Kimura, H.; Okuno, K.

2003-01-01

An apparatus equipped with X-ray Photoelectron Spectroscopy (XPS) and Thermal Desorption Spectroscopy (TDS) was constructed to study interactions of energetic hydrogen isotopes with plasma facing materials. It is a remarkable feature of the apparatus that energetic ion implantation is carried out at around 150K to study reactions of energetic ions with matrix by suppressing the reactions of thermalized ions. Using this apparatus, TDS experiments for pyrolytic graphite implanted with energetic D 2 ions at 173 and 373K were carried out. The experimental results suggest that the deuterium implanted was released through a four-step release processes, involving three D 2 and one CD x (x = 2, 3 and 4) desorption processes. Two deuterium and CD x desorption processes were observed in the temperature range from 700 to 1200 K. In addition, a new deuterium desorption process was observed for the deuterium-implanted sample at 173 K. This has never been observed for deuterium-implanted graphite implanted at temperatures higher than room temperature

Rate coefficients for the reactions of ions with polar molecules at interstellar temperatures

International Nuclear Information System (INIS)

Adams, N.G.; Smith, D.; Clary, D.C.

1985-01-01

A theory has been developed recently which predicts that the rate coefficients, k, for the reactions of ions with polar molecules at low temperatures will be much greater than the canonical value of 10 -9 cm 3 s -1 . The new theory indicates that k is greatest for low-lying rotational sates and increases rapidly with decreasing temperature. We refer to recent laboratory measurements which validate the theory, present calculated values of k for the reactions of H + 3 ions with several polar molecules, and discuss their significance to interstellar chemistry. For the reactions of ions with molecules having large dipole moments, we recommend that k values as large as 10 -7 cm 3 s -1 should be used in ion-chemical models of low-temperature interstellar clouds

Weak turbulence theory of ion temperature gradient modes for inverted density plasmas

International Nuclear Information System (INIS)

Hahm, T.S.; Tang, W.M.

1989-09-01

Typical profiles measured in H-mode (''high confinement'') discharges from tokamaks such as JET and DIII-D suggest that the ion temperature gradient instability threshold parameter η i (≡dlnT i /dlnn i ) could be negative in many cases. Previous linear theoretical calculations have established the onset conditions for these negative η i -modes and the fact that their growth rate is much smaller than their real frequency over a wide range of negative η i values. This has motivated the present nonlinear weak turbulence analysis to assess the relevance of such instabilities for confinement in H-mode plasmas. The nonlinear eigenmode equation indicates that the 3-wave coupling to shorter wavelength modes is the dominant nonlinear saturation mechanism. It is found that both the saturation level for these fluctuations and the magnitude of the associated ion thermal diffusivity are considerably smaller than the strong turbulence mixing length type estimates for the more conventional positive-η i -instabilities. 19 refs., 3 figs

Quantum tunneling recombination in a system of randomly distributed trapped electrons and positive ions.

Science.gov (United States)

Pagonis, Vasilis; Kulp, Christopher; Chaney, Charity-Grace; Tachiya, M

2017-09-13

During the past 10 years, quantum tunneling has been established as one of the dominant mechanisms for recombination in random distributions of electrons and positive ions, and in many dosimetric materials. Specifically quantum tunneling has been shown to be closely associated with two important effects in luminescence materials, namely long term afterglow luminescence and anomalous fading. Two of the common assumptions of quantum tunneling models based on random distributions of electrons and positive ions are: (a) An electron tunnels from a donor to the nearest acceptor, and (b) the concentration of electrons is much lower than that of positive ions at all times during the tunneling process. This paper presents theoretical studies for arbitrary relative concentrations of electrons and positive ions in the solid. Two new differential equations are derived which describe the loss of charge in the solid by tunneling, and they are solved analytically. The analytical solution compares well with the results of Monte Carlo simulations carried out in a random distribution of electrons and positive ions. Possible experimental implications of the model are discussed for tunneling phenomena in long term afterglow signals, and also for anomalous fading studies in feldspars and apatite samples.

Evaluation of the stability of uranyl peroxo-carbonato complex ions in carbonate media at different temperatures

International Nuclear Information System (INIS)

Kim, Kwang-Wook; Lee, Keun-Young; Chung, Dong-Yong; Lee, Eil-Hee; Moon, Jei-Kwon; Shin, Dong-Woo

2012-01-01

Highlights: ► The stability of peroxide in uranyl peroxo carbonato complex solutions with different temperatures was characterized. ► The decomposition rate of uranyl peroxo carbonato complex ion to uranyl tris-carbonato complex ion was observed to increase with temperature ► The decomposition kinetics of uranyl peroxo carbonato complex ions was evaluated by absorption and Raman spectroscopies. ► A precipitate of uranyl peroxo carbonato complex solution was evaluated with XRD. - Abstract: This work studied the stability of peroxide in uranyl peroxo carbonato complex ions in a carbonate solution with hydrogen peroxide using absorption and Raman spectroscopies, and evaluated the temperature dependence of the decomposition characteristics of uranyl peroxo carbonato complex ions in the solution. The uranyl peroxo carbonato complex ions self-decomposed more rapidly into uranyl tris-carbonato complex ions in higher temperature carbonate solutions. The concentration of peroxide in the solution without free hydrogen peroxide represents the concentration of uranyl peroxo carbonato complex ions in a mixture of uranyl peroxo carbonato complex and uranyl tris-carbonato complex ions. The self-decomposition of the uranyl peroxo carbonato complex ions was a first order reaction, and its activation energy was evaluated to be 7.144 × 10 3 J mol −1 . The precipitation of sodium uranium oxide hydroxide occurred when the amount of uranyl tris-carbonato complex ions generated from the decomposition of the uranyl peroxo carbonato complex ions exceeded the solubility of uranyl tris-carbonato ions in the solution at the solution temperature.

Low-temperature technique of thin silicon ion implanted epitaxial detectors

Energy Technology Data Exchange (ETDEWEB)

Kordyasz, A.J.; Bednarek, A. [Warsaw University, Heavy Ion Laboratory, Warsaw (Poland); Le Neindre, N.; Bougault, R.; Lopez, O.; Merrer, Y.; Vient, E. [Universite de Caen, LPC, IN2P3-CNRS, ENSICAEN, Caen-Cedex (France); Parlog, M. [Universite de Caen, LPC, IN2P3-CNRS, ENSICAEN, Caen-Cedex (France); ' ' Horia Hulubei' ' National Institute of Physics and Nuclear Engineering (IFIN-HH), Bucharest Magurele (Romania); Casini, G.; Poggi, G.; Bini, M.; Valdre, S.; Scarlini, E.; Pasquali, G.; Pastore, G.; Piantelli, S.; Stefanini, A.; Olmi, A.; Barlini, S. [INFN Firenze, Sesto Fiorentino (Italy); Universita di Firenze, Sesto Fiorentino (Firenze) (Italy); Kowalczyk, M. [Warsaw University, Heavy Ion Laboratory, Warsaw (Poland); University of Warsaw, Institute of Experimental Physics, Warsaw (Poland); Frankland, J.D.; Bonnet, E.; Chbihi, A.; Gruyer, D. [CEA et IN2P3-CNRS, GANIL, Caen-Cedex 05 (France); Borderie, B.; Ademard, G.; Edelbruck, P.; Rivet, M.F.; Salomon, F. [IN2P3-CNRS, Institut de Physique Nucleaire, Orsay-Cedex (France); Boiano, A.; Rosato, E.; Meoli, A.; Ordine, A.; Spadaccini, G.; Tortone, G.; Vigilante, M.; Vanzanella, E. [Universita di Napoli ' ' Federico II' ' , Dipartimento di Scienze Fisiche, Napoli (Italy); INFN, Napoli (Italy); Bruno, M.; Serra, S.; Morelli, L.; Guerzoni, M. [INFN, Bologna (Italy); Universita di Bologna, Bologna (Italy); Alba, R.; Santonocito, D.; Maiolino, C. [INFN, Catania (Italy); Universita di Catania, LNS, Catania (Italy); Cinausero, M.; Gramegna, F.; Marchi, T. [INFN LNL Legnaro, Legnaro (Padova) (Italy); Kozik, T.; Kulig, P.; Twarog, T.; Sosin, Z. [Jagiellonian University, Cracow (Poland); Gasior, K.; Grzeszczuk, A.; Zipper, W. [University of Silesia, Silesian University, Katowice (Poland); Sarnecki, J.; Lipinski, D.; Wodzinska, H.; Brzozowski, A.; Teodorczyk, M.; Gajewski, M.; Zagojski, A.; Krzyzak, K. [Institute of Electronic Materials Technology, Warsaw (Poland); Tarasiuk, K.J. [University of Warsaw, Institute of Experimental Physics, Warsaw (Poland); Khabanowa, Z. [Faculty of Physics, Warsaw University of Technology, Warsaw (Poland); Kordyasz, L. [Warsaw University of Technology, Faculty of Mechatronics, Institute of Mikromechanics and Photonics, Department of Design of Precision Devices, Warsaw (Poland)

2015-02-01

A new technique of large-area thin ion implanted silicon detectors has been developed within the R and D performed by the FAZIA Collaboration. The essence of the technique is the application of a low-temperature baking process instead of high-temperature annealing. This thermal treatment is performed after B{sup +} ion implantation and Al evaporation of detector contacts, made by using a single adjusted Al mask. Extremely thin silicon pads can be therefore obtained. The thickness distribution along the X and Y directions was measured for a prototype chip by the energy loss of α-particles from {sup 241}Am (left angle E{sub α} right angle = 5.5 MeV). Preliminary tests on the first thin detector (area ∼ 20 x 20 mm{sup 2}) were performed at the INFN-LNS cyclotron in Catania (Italy) using products emitted in the heavy-ion reaction {sup 84}Kr (E = 35 A MeV) + {sup 112}Sn. The ΔE - E ion identification plot was obtained using a telescope consisting of our thin ΔE detector (21 μm thick) followed by a typical FAZIA 510 μm E detector of the same active area. The charge distribution of measured ions is presented together with a quantitative evaluation of the quality of the Z resolution. The threshold is lower than 2 A MeV depending on the ion charge. (orig.)

Laterally resolved ion-distribution functions at the substrate position during magnetron sputtering of indium-tin oxide films

International Nuclear Information System (INIS)

Plagemann, A.; Ellmer, K.; Wiesemann, K.

2007-01-01

During the magnetron sputtering from an indium-tin oxide (ITO) target (76 mm diameter) we measured the ion-distribution functions (IDFs) of energetic ions (argon, indium, and oxygen ions) at the substrate surface using a combination of a quadrupole mass spectrometer and an electrostatic energy analyzer. We obtained the IDFs for argon sputtering pressures in the range from 0.08 to 2 Pa and for dc as well as rf (13.56 MHz) plasma excitation with powers from 10 to 100 W. The IDF measurements were performed both over the target center at a target-to-substrate distance of 65 mm and at different positions along the target radius in order to scan the erosion track of the target. The mean kinetic energies of argon ions calculated from the IDFs in the dc plasma decreased from about 30 to 15 eV, when the argon pressure increased from 0.08 to 2 Pa, which is caused by a decrease of the electron temperature also by a factor of 2. Indium atoms exhibit higher mean energies due to their additional energy from the sputtering process. The total metal ion flux turns out to be proportional to the discharge power and the pressure, the latter dependence being due to Penning ionization of the metal atoms (In and Sn). From the scans across the target surface the lateral distributions of metal, oxygen, and argon ions were derived. In the dc discharge the position of the erosion track is reproduced by increased ion intensities, while it is not the case for the rf excited plasma. The lateral variations of the observed species do not influence the lateral resistivity distributions of the deposited ITO films

Experimental evaluation of the pressure and temperature dependence of ion-induced nucleation.

Science.gov (United States)

Munir, Muhammad Miftahul; Suhendi, Asep; Ogi, Takashi; Iskandar, Ferry; Okuyama, Kikuo

2010-09-28

An experimental system for the study of ion-induced nucleation in a SO(2)/H(2)O/N(2) gas mixture was developed, employing a soft x-ray at different pressure and temperature levels. The difficulties associated with these experiments included the changes in physical properties of the gas mixture when temperature and pressure were varied. Changes in the relative humidity (RH) as a function of pressure and temperature also had a significant effect on the different behaviors of the mobility distributions of particles. In order to accomplish reliable measurement and minimize uncertainties, an integrated on-line control system was utilized. As the pressure decreased in a range of 500-980 hPa, the peak concentration of both ions and nanometer-sized particles decreased, which suggests that higher pressure tended to enhance the growth of particles nucleated by ion-induced nucleation. Moreover, the modal diameters of the measured particle size distributions showed a systematic shift to larger sizes with increasing pressure. However, in the temperature range of 5-20 °C, temperature increases had no significant effects on the mobility distribution of particles. The effects of residence time, RH (7%-70%), and SO(2) concentration (0.08-6.7 ppm) on ion-induced nucleation were also systematically investigated. The results show that the nucleation and growth were significantly dependent on the residence time, RH, and SO(2) concentration, which is in agreement with both a previous model and previous observations. This research will be inevitable for a better understanding of the role of ions in an atmospheric nucleation mechanism.

Low-temperature photoluminescence in chalcogenide glasses doped with rare-earth ions

Energy Technology Data Exchange (ETDEWEB)

Kostka, Petr, E-mail: petr.kostka@irsm.cas.cz [Institute of Rock Structure and Mechanics AS CR, V Holešovičkách 41, 182 09 Praha 8 (Czech Republic); Zavadil, Jiří [Institute of Photonics and Electronics AS CR, Chaberská 57, 182 51 Praha 8, Kobylisy (Czech Republic); Iovu, Mihail S. [Institute of Applied Physics, Academy of Sciences of Moldova, Str. Academiei 5, MD-28 Chisinau, Republic of Moldova (Moldova, Republic of); Ivanova, Zoya G. [Institute of Solid State Physics, Bulgarian Academy of Sciences, 1784 Sofia (Bulgaria); Furniss, David; Seddon, Angela B. [Mid-Infrared Photonics Group, George Green Institute for Electromagnetics Research, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom)

2015-11-05

Sulfide and oxysulfide bulk glasses Ga-La-S-O, Ge-Ga-S and Ge-Ga-As-S doped, or co-doped, with various rare-earth (RE{sup 3+}) ions are investigated for their room temperature transmission and low-temperature photoluminescence. Photoluminescence spectra are collected by using external excitation into the Urbach tail of the fundamental absorption edge of the host-glass. The low-temperature photoluminescence spectra are dominated by the broad-band luminescence of the host glass, with superimposed relatively sharp emission bands due to radiative transitions within 4f shells of RE{sup 3+} ions. In addition, the dips in the host-glass luminescence due to 4f-4f up-transitions of RE{sup 3+} ions are observed in the Ge-Ga-S and Ge-Ga-As-S systems. These superimposed narrow effects provide a direct experimental evidence of energy transfer between the host glass and respective RE{sup 3+} dopants. - Highlights: • An evidence of energy transfer from host-glass to doped-in RE ions is presented. • Energy transfer is manifested by dips in host-glass broad-band luminescence. • This channel of energy transfer is documented on selected RE doped sulfide glasses. • Photoluminescence spectra are dominated by broad band host-glass luminescence. • Presence of RE ions is manifested by superimposed narrow 4f-4f transitions.

Joint influence of temperature and ions of metals on level of activity alkaline phosphatase the mucous membrane of intestines beluga, the starlet and their hybrid

Directory of Open Access Journals (Sweden)

D. A. Bednyakov

2010-01-01

Full Text Available In work joint influence of ions of bivalent metals (Mn, Fe, Co, Ni, Cu and Zn and temperatures on level of activity alkaline phosphatase mucous membrane beluga, starlet and their hybrid is shown. Dependence of response of enzyme on action of ions of metals according to their position in a periodic table of chemical elements is shown. The given dependence remains and at temperature change incubation, only at low temperatures the activating effect of metals being in the period beginning is maximum, and at high, is maximum inhibiting effect of metals being in the period end.

Production of nanodiamonds by high-energy ion irradiation of graphite at room temperature

International Nuclear Information System (INIS)

Daulton, T.L.; Kirk, M.A.; Lewis, R.S.; Rehn, L.E.

2001-01-01

It has previously been shown that graphite can be transformed into diamond by MeV electron and ion irradiation at temperatures above approximately 600 deg. C. However, there exists geological evidence suggesting that carbonaceous materials can be transformed to diamond by irradiation at substantially lower temperatures. For example, submicron-size diamond aggregates have been found in uranium-rich, Precambrian carbonaceous deposits that never experienced high temperature or pressure. To test if diamonds can be formed at lower irradiation temperatures, sheets of fine-grain polycrystalline graphite were bombarded at 20 deg. C with 350±50 MeV Kr ions to fluences of 6x10 12 cm -2 using the Argonne tandem linear accelerator system (ATLAS). Ion-irradiated (and unirradiated control) graphite specimens were then subjected to acid dissolution treatments to remove untransformed graphite and isolate diamonds that were produced; these acid residues were subsequently characterized by high-resolution and analytical electron microscopy. The acid residue of the ion-irradiated graphite was found to contain nanodiamonds, demonstrating that ion irradiation of graphite at ambient temperature can produce diamond. The diamond yield under our irradiation conditions is low, ∼0.01 diamonds/ion. An important observation that emerges from comparing the present result with previous observations of diamond formation during irradiation is that nanodiamonds form under a surprisingly wide range of irradiation conditions. This propensity may be related to the very small difference in the graphite and diamond free-energies coupled with surface-energy considerations that may alter the relative stability of diamond and graphite at nanometer sizes

Evaluation of the stability of uranyl peroxo-carbonato complex ions in carbonate media at different temperatures

Energy Technology Data Exchange (ETDEWEB)

Kim, Kwang-Wook, E-mail: nkwkim@kaeri.re.kr [Korea Atomic Energy Research Institute, 1045 Daedeok daero, Yuseong, Daejeon 305-353 (Korea, Republic of); Lee, Keun-Young; Chung, Dong-Yong; Lee, Eil-Hee; Moon, Jei-Kwon [Korea Atomic Energy Research Institute, 1045 Daedeok daero, Yuseong, Daejeon 305-353 (Korea, Republic of); Shin, Dong-Woo [Gyeongsang National University, 900 Gajwa, Jinju 660-701 (Korea, Republic of)

2012-09-30

Highlights: Black-Right-Pointing-Pointer The stability of peroxide in uranyl peroxo carbonato complex solutions with different temperatures was characterized. Black-Right-Pointing-Pointer The decomposition rate of uranyl peroxo carbonato complex ion to uranyl tris-carbonato complex ion was observed to increase with temperature Black-Right-Pointing-Pointer The decomposition kinetics of uranyl peroxo carbonato complex ions was evaluated by absorption and Raman spectroscopies. Black-Right-Pointing-Pointer A precipitate of uranyl peroxo carbonato complex solution was evaluated with XRD. - Abstract: This work studied the stability of peroxide in uranyl peroxo carbonato complex ions in a carbonate solution with hydrogen peroxide using absorption and Raman spectroscopies, and evaluated the temperature dependence of the decomposition characteristics of uranyl peroxo carbonato complex ions in the solution. The uranyl peroxo carbonato complex ions self-decomposed more rapidly into uranyl tris-carbonato complex ions in higher temperature carbonate solutions. The concentration of peroxide in the solution without free hydrogen peroxide represents the concentration of uranyl peroxo carbonato complex ions in a mixture of uranyl peroxo carbonato complex and uranyl tris-carbonato complex ions. The self-decomposition of the uranyl peroxo carbonato complex ions was a first order reaction, and its activation energy was evaluated to be 7.144 Multiplication-Sign 10{sup 3} J mol{sup -1}. The precipitation of sodium uranium oxide hydroxide occurred when the amount of uranyl tris-carbonato complex ions generated from the decomposition of the uranyl peroxo carbonato complex ions exceeded the solubility of uranyl tris-carbonato ions in the solution at the solution temperature.

Using quasi-elastic neutron diffraction to study positive electrode for lithium and sodium-ion batteries

International Nuclear Information System (INIS)

Pramudita, James C.; Sharma, Neeraj

2015-01-01

Sodium-ion batteries has recently been proposed as the alternative for lithium-ion batteries to be the low cost energy storage system. However, challenges still remains for the development of sodium-ion batteries. Optimization of electrode materials and electrolyte capable of insertion/extraction of sodium-ion in a safe and economic way under high current density is needed in order to produce commercially viable sodium-ion batteries. While possible positive electrode material is more prevalent than negative electrode material, many of these material still need further understanding. Quasi-elastic Neutron Scatteringis a technique that utilize the inelastic Neutron Scatteringthat can be used to study solid-state diffusion in materials. This technique can be used to study the diffusion of sodium-ion under electric field through the electrolyte and positive electrode materials in order to further understand the mechanism of sodium insertion/extraction in a working battery. This technique can also be used to study available positive electrode material for lithium-ion batteries to further understand the mechanism of lithium-ion diffusion in current working lithiumion batteries.

Positive and negative ion mode comparison for the determination of DNA/peptide noncovalent binding sites through the formation of "three-body" noncovalent fragment ions.

Science.gov (United States)

Brahim, Bessem; Tabet, Jean-Claude; Alves, Sandra

2018-02-01

Gas-phase fragmentation of single strand DNA-peptide noncovalent complexes is investigated in positive and negative electrospray ionization modes.Collision-induced dissociation experiments, performed on the positively charged noncovalent complex precursor ions, have confirmed the trend previously observed in negative ion mode, i.e. a high stability of noncovalent complexes containing very basic peptidic residues (i.e. R > K) and acidic nucleotide units (i.e. Thy units), certainly incoming from the existence of salt bridge interactions. Independent of the ion polarity, stable noncovalent complex precursor ions were found to dissociate preferentially through covalent bond cleavages of the partners without disrupting noncovalent interactions. The resulting DNA fragment ions were found to be still noncovalently linked to the peptides. Additionally, the losses of an internal nucleic fragment producing "three-body" noncovalent fragment ions were also observed in both ion polarities, demonstrating the spectacular salt bridge interaction stability. The identical fragmentation patterns (regardless of the relative fragment ion abundances) observed in both polarities have shown a common location of salt bridge interaction certainly preserved from solution. Nonetheless, most abundant noncovalent fragment ions (and particularly three-body ones) are observed from positively charged noncovalent complexes. Therefore, we assume that, independent of the preexisting salt bridge interaction and zwitterion structures, multiple covalent bond cleavages from single-stranded DNA/peptide complexes rely on an excess of positive charges in both electrospray ionization ion polarities.

High temperature electron beam ion source for the production of single charge ions of most elements of the Periodic Table

CERN Document Server

Panteleev, V N; Barzakh, A E; Fedorov, D V; Ivanov, V S; Moroz, F V; Orlov, S Y; Seliverstov, D M; Stroe, L; Tecchio, L B; Volkov, Y M

2003-01-01

A new type of a high temperature electron beam ion source (HTEBIS) with a working temperature up to 2500 deg. C was developed for production of single charge ions of practically all elements. Off-line tests and on-line experiments making use of the developed ion source coupled with uranium carbide targets of different density, have been carried out. The ionization efficiency measured for stable atoms of many elements varied in the interval of 1-6%. Using the HTEBIS, the yields and on-line production efficiency of neutron rich isotopes of Mn, Fe, Co, Cu, Rh, Pd, Ag, Cd, In, Sn and isotopes of heavy elements Pb, Bi, Po and some others have been determined. The revealed confinement effect of the ions produced in the narrow electron beam inside a hot ion source cavity has been discussed.

Ion emission from laser-produced plasmas with two electron temperatures

International Nuclear Information System (INIS)

Wickens, L.M.; Allen, J.E.; Rumsby, P.T.

1978-01-01

An analytic theory for the expansion of a laser-produced plasma with two electron temperatures is presented. It is shown that from the ion-emission velocity spectrum such relevant parameters as the hot- to -cold-electron density ratio, the absolute hot- and cold-electron temperatures, and a sensitive measure of hot- and cold-electron temperature ratio can be deduced. A comparison with experimental results is presented

Optimalization study for ion-temperature measurements by means of Rutherford scattering

International Nuclear Information System (INIS)

Donne, A.J.H.; Barbian, E.P.

1986-03-01

Small-angle Rutherford scattering of energetic neutrals by plasma ions is governed by energy and momentum conservation. The FWHM of the scattering distibution reveals the ion temperature of the plasma. A feasibility study is performed to optimize the parameters in case Rutherford-scattering technique is applied to a medium-sized tokamak experiment. Together with a time-of-flight analyser with a high energy resolution of about 100, a 20 keV helium probing beam with a neutral current density of 10 A/m 2 can provide a detailed spectrum within 3 ms, from which the ion temperature can be extracted with an accuracy of better than 10%. The influence of plasma impurities and resonant charge exchange on the scattering process is discussed in detail. The good spatial resolution makes the method very suitable to investigate energy deposition profiles in the case of ion-cyclotron radiation applied to the plasma for the purpose of plasma heating. (orig.)

Temperature effects on the electrohydrodynamic and electrokinetic behaviour of ion-selective nanochannels

International Nuclear Information System (INIS)

Wood, Jeffery A; Benneker, Anne M; Lammertink, Rob G H

2016-01-01

A non-isothermal formulation of the Poisson–Nernst–Planck with Navier–Stokes equations is used to study the influence of heating effects in the form of Joule heating and viscous dissipation and imposed temperature gradients on a microchannel/nanochannel system. The system is solved numerically under various cases in order to determine the influence of temperature-related effects on ion-selectivity, flux and fluid flow profiles, as well as coupling between these phenomena. It is demonstrated that for a larger reservoir system, the effects of Joule heating and viscous dissipation only become relevant for higher salt concentrations and electric field strengths than are compatible with ion-selectivity due to Debye layer overlap. More interestingly, it is shown that using different temperature reservoirs can have a strong influence on ion-selectivity, as well as the induced electrohydrodynamic flows. (paper)

High-intensity positive beams extracted from a compact double-chamber ion source

International Nuclear Information System (INIS)

Huck, H.; Somacal, H.; Di Gregorio, D.E.; Fernandez Niello, J.O.; Igarzabal, M.; Di Paolo, H.; Reinoso, M.

2005-01-01

This work presents the design and development of a simple ion source, the associated ion extraction optics, and the beam transport of a low-energy and high-current proton accelerator. In its actual version, the ion source can deliver positive proton currents up to 100 mA. This rather high beam current is achieved by adding a small ionization chamber between the discharge chamber containing the filament and the extraction electrode of the ion source. Different parameters of the ion source and the injection beam line are evaluated by means of computer simulations to optimize the beam production and transmission

Room temperature diamond-like carbon coatings produced by low energy ion implantation

Energy Technology Data Exchange (ETDEWEB)

Markwitz, A., E-mail: a.markwitz@gns.cri.nz [Department for Ion Beam Technologies, GNS Science, 30 Gracefield Road, Lower Hutt (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology (New Zealand); Mohr, B.; Leveneur, J. [Department for Ion Beam Technologies, GNS Science, 30 Gracefield Road, Lower Hutt (New Zealand)

2014-07-15

Nanometre-smooth diamond-like carbon coatings (DLC) were produced at room temperature with ion implantation using 6 kV C{sub 3}H{sub y}{sup +} ion beams. Ion beam analysis measurements showed that the coatings contain no heavy Z impurities at the level of 100 ppm, have a homogeneous stoichiometry in depth and a hydrogen concentration of typically 25 at.%. High resolution TEM analysis showed high quality and atomically flat amorphous coatings on wafer silicon. Combined TEM and RBS analysis gave a coating density of 3.25 g cm{sup −3}. Raman spectroscopy was performed to probe for sp{sup 2}/sp{sup 3} bonds in the coatings. The results indicate that low energy ion implantation with 6 kV produces hydrogenated amorphous carbon coatings with a sp{sup 3} content of about 20%. Results highlight the opportunity of developing room temperature DLC coatings with ion beam technology for industrial applications.

Experiments on ion-acoustic rarefactive solitons in a multi-component plasma with negative ions

International Nuclear Information System (INIS)

Nakamura, Y.; Ferreira, J.L.; Ludwig, G.O.

1987-09-01

Ion-acoustic solitons in a three-component plasma which consists of electrons, positive and negative ions have been investigated experimentally. When the concentration of negative ions is smaller than a certain value, positive or compressive solitons are observed. At the critical concentration, a broad pulse of small but finite amplitude propagates without changing its shape. When the concentration is larger than this value, negative or rarefactive solitons are excited. The velocity and the width of these solitons are measured and compared with predictions of the Korteweg- de Vries equation which takes the negative ions and the ion temperature into consideration. Head-ion and over-taking collisions of the rarefactive solitons have been observed to show that the solitons are not affected by these collisions. (author) [pt

Characteristics of ZnO Wafers Implanted with 60 keV Sn+ Ions at Room Temperature and at 110 K

International Nuclear Information System (INIS)

Dang, Giang T.; Taniwaki, Masafumi; Kawaharamura, Toshiyuki; Hirao, Takashi; Nitta, Noriko

2011-01-01

ZnO wafers implanted with 60 keV Sn + ions at room temperature (RT) and at 110 K are investigated by means of X-ray diffraction (XRD) and photoluminescence (PL) techniques. The effect of implantation temperature is evident in the XRD and PL data. A yellow-orange (YO) band near 600 nm appears in the PL spectra of the ZnO wafers implanted to the doses of 4x10 14 and 8x10 14 ions/cm 2 at RT. The intensity of this band increases and the peak position blue-shifts after illumination of the samples with the 325 nm line of a He-Cd laser. The PL data suggests that the CB (conduction band)→V O + and Zn i + →V Zn - transitions contribute to the photoemission of the YO band.

Temperature dependent surface modification of molybdenum due to low energy He+ ion irradiation

International Nuclear Information System (INIS)

Tripathi, J.K.; Novakowski, T.J.; Joseph, G.; Linke, J.; Hassanein, A.

2015-01-01

In this paper, we report on the temperature dependent surface modifications in molybdenum (Mo) samples due to 100 eV He + ion irradiation in extreme conditions as a potential candidate to plasma-facing components in fusion devices alternative to tungsten. The Mo samples were irradiated at normal incidence, using an ion fluence of 2.6 × 10 24 ions m −2 (with a flux of 7.2 × 10 20 ions m −2 s −1 ). Surface modifications have been studied using high-resolution field emission scanning electron-(SEM) and atomic force (AFM) microscopy. At 773 K target temperature homogeneous evolution of molybdenum nanograins on the entire Mo surface were observed. However, at 823 K target temperature appearance of nano-pores and pin-holes nearby the grain boundaries, and Mo fuzz in patches were observed. The fuzz density increases significantly with target temperatures and continued until 973 K. However, at target temperatures beyond 973 K, counterintuitively, a sequential reduction in the fuzz density has been seen till 1073 K temperatures. At 1173 K and above temperatures, only molybdenum nano structures were observed. Our temperature dependent studies confirm a clear temperature widow, 823–1073 K, for Mo fuzz formation. Ex-situ high resolution X-ray photoelectron spectroscopy studies on Mo fuzzy samples show the evidence of MoO 3 3d doublets. This elucidates that almost all the Mo fuzz were oxidized during open air exposure and are thick enough as well. Likewise the microscopy studies, the optical reflectivity measurements also show a sequential reduction in the reflectivity values (i.e., enhancement in the fuzz density) up to 973 K and after then a sequential enhancement in the reflectivity values (i.e., reduction in the fuzz density) with target temperatures. This is in well agreement with microscopy studies where we observed clear temperature window for Mo fuzz growth

Study of ion cyclotron fluctuations. Application to the measurement of the ion temperature

International Nuclear Information System (INIS)

Lehner, T.

1982-02-01

A diagnostic technique for measuring the ion temperature of tokamak-type plasmas was developed. A theoretical study was made of the form factor associated with the ion cyclotron waves; the influence of Te/Ti on the frequency of the extrema of the dispersion relations was demonstrated. The different effects able to modify the spectral density (in particular the drift velocity and the impurities) were investigated. The mechanisms of suprathermal excitation of cylotron waves in tokamaks were reviewed together with the various effects stabilizing the spectrum: collisions, shear of the magnetic field lines. The experimental realization of the diagnostic technique is based on Thomson scattering by the electron density fluctuations [fr

Mass spectrometric study of the negative and positive secondary ions emitted from ethanol microdroplets by MeV-energy heavy ion impact

Science.gov (United States)

Kitajima, Kensei; Majima, Takuya; Nishio, Tatsuya; Oonishi, Yoshiki; Mizutani, Shiori; Kohno, Jun-ya; Saito, Manabu; Tsuchida, Hidetsugu

2018-06-01

We have investigated the negative and positive secondary ions emitted from ethanol droplets by 4.0-MeV C3+ impact to reveal the characteristic features of the reaction processes induced by fast heavy ions at the liquid ethanol surface. Analysis of the secondary ions was performed by time-of-flight mass spectrometry for microdroplet targets in a high vacuum environment. Fragment ions, deprotonated cluster ions, and trace amounts of the reaction product ions are observed in the negative secondary ions. The main fragment anions are C2HmO- (m = 1, 3, and 5) and C2H- generated by loss of hydrogen and oxygen atoms. The reaction product anions include deprotonated glycols, larger alcohols, and their dehydrated and dehydrogenated forms generated by secondary reactions between fragments and radicals. Furthermore, C3Hm- (m = 0-2) and C4Hm- (m = 0 and 1) are observed, which could be produced through a plasma state generated in the heavy ion track. Deprotonated ethanol cluster ions, [(EtOH)n - H]-, are observed up to about n = 25. [(EtOH)n - H]- have smaller kinetic energies than the protonated cluster ions (EtOH)nH+. This probably represents the effect of the positive Coulomb potential transiently formed in the ion track. We also discuss the size distributions and structures of the water- and CH2OH-radical-attached ethanol cluster ions.

Transition from L mode to high ion temperature mode in CHS heliotron/torsatron plasmas

International Nuclear Information System (INIS)

Ida, K.; Osakabe, M.; Tanaka, K.

2001-01-01

A high ion temperature mode (high T i mode) is observed for neutral beam heated plasmas in the Compact Helical System (CHS) Heliotron/torsatron. The high T i mode plasma is characterized by a high central ion temperature, T i (0), and is associated with a peaked electron density profile produced by neutral beam fueling with low wall recycling. Transition from L mode to high T i mode has been studied in CHS. The central ion temperature in the high T i mode discharges reaches to 1 keV which is 2.5 times higher than that in the L mode discharges. The ion thermal diffusivity is significantly reduced by a factor of more than 2-3 in the high T i mode plasma. The ion loss cone is observed in neutral particle flux in the energy range of 1-6 keV with a narrow range of pitch angle (90±10 degree) in the high T i mode. However, the degradation of ion energy confinement due to this loss cone is negligible. (author)

Experiments on Ion-Ion Plasmas From Discharges

Science.gov (United States)

Leonhardt, Darrin; Walton, Scott; Blackwell, David; Murphy, Donald; Fernsler, Richard; Meger, Robert

2001-10-01

Use of both positive and negative ions in plasma processing of materials has been shown to be advantageous[1] in terms of better feature evolution and control. In this presentation, experimental results are given to complement recent theoretical work[2] at NRL on the formation and decay of pulsed ion-ion plasmas in electron beam generated discharges. Temporally resolved Langmuir probe and mass spectrometry are used to investigate electron beam generated discharges during the beam on (active) and off (afterglow) phases in a variety of gas mixtures. Because electron-beam generated discharges inherently[3] have low electron temperatures (<0.5eV in molecular gases), negative ion characteristics are seen in the active as well as afterglow phases since electron detachment increases with low electron temperatures. Analysis of temporally resolved plasma characteristics deduced from these measurements will be presented for pure O_2, N2 and Ar and their mixtures with SF_6. Oxygen discharges show no noticeable negative ion contribution during the active or afterglow phase, presumably due to the higher energy electron attachment threshold, which is well above any electron temperature. In contrast, SF6 discharges demonstrate ion-ion plasma characteristics in the active glow and are completely ion-ion in the afterglow. Comparison between these discharges with published cross sections and production mechanisms will also be presented. [1] T.H. Ahn, K. Nakamura & H. Sugai, Plasma Sources Sci. Technol., 5, 139 (1996); T. Shibyama, H. Shindo & Y. Horiike, Plasma Sources Sci. Technol., 5, 254 (1996). [2] See presentation by R. F. Fernsler, at this conference. [3] D. Leonhardt, et al., 53rd Annual GEC, Houston, TX.

Influence of plasma-generated negative oxygen ion impingement on magnetron sputtered amorphous SiO2 thin films during growth at low temperatures

International Nuclear Information System (INIS)

Macias-Montero, M.; Garcia-Garcia, F. J.; Alvarez, R.; Gil-Rostra, J.; Gonzalez, J. C.; Gonzalez-Elipe, A. R.; Palmero, A.; Cotrino, J.

2012-01-01

Growth of amorphous SiO 2 thin films deposited by reactive magnetron sputtering at low temperatures has been studied under different oxygen partial pressure conditions. Film microstructures varied from coalescent vertical column-like to homogeneous compact microstructures, possessing all similar refractive indexes. A discussion on the process responsible for the different microstructures is carried out focusing on the influence of (i) the surface shadowing mechanism, (ii) the positive ion impingement on the film, and (iii) the negative ion impingement. We conclude that only the trend followed by the latter and, in particular, the impingement of O - ions with kinetic energies between 20 and 200 eV, agrees with the resulting microstructural changes. Overall, it is also demonstrated that there are two main microstructuring regimes in the growth of amorphous SiO 2 thin films by magnetron sputtering at low temperatures, controlled by the amount of O 2 in the deposition reactor, which stem from the competition between surface shadowing and ion-induced adatom surface mobility.

Energetic ion emission in a positive polarity nanosecond plasma opening switch

Energy Technology Data Exchange (ETDEWEB)

Sarfaty, M [Univ. of Wisconsin, Madison, WI (United States); Krasik, Ya E; Weingarten, A; Fruchtman, A; Maron, Y [Weizmann Institute of Science, Rehovot (Israel). Department of Physics

1997-12-31

The emission was studied of energetic ions from the plasma in a coaxial Plasma Opening Switch (POS) powered by a 300 kV, 15 kA, 90 ns positive polarity pulse. Fluxes lasting 2 - 3 ns of ions flowing radially onto the cathode were observed at all axial locations of the switch plasma within 5 ns of the beginning of the upstream POS current. It is suggested that the termination of this ion flux is due to the formation of a cathode plasma, which is consistent with our spectroscopic measurements. Later in the pulse, longer duration (100 ns) ion fluxes were observed radially, first appearing in the generator side of the switch plasma. Fluxes 30 - 40 ns long of ions flowing axially towards the POS load at velocities (2{+-}1) x 10{sup 8} cm/s were also observed. The dependences of the start time of the axial ion flow, of the ion velocities, and of the ion flux on the POS operation parameters were studied. (author). 6 figs., 5 refs.

Energetic ion emission in a positive polarity nanosecond plasma opening switch

International Nuclear Information System (INIS)

Sarfaty, M.; Krasik, Ya.E.; Weingarten, A.; Fruchtman, A.; Maron, Y.

1996-01-01

The emission was studied of energetic ions from the plasma in a coaxial Plasma Opening Switch (POS) powered by a 300 kV, 15 kA, 90 ns positive polarity pulse. Fluxes lasting 2 - 3 ns of ions flowing radially onto the cathode were observed at all axial locations of the switch plasma within 5 ns of the beginning of the upstream POS current. It is suggested that the termination of this ion flux is due to the formation of a cathode plasma, which is consistent with our spectroscopic measurements. Later in the pulse, longer duration (100 ns) ion fluxes were observed radially, first appearing in the generator side of the switch plasma. Fluxes 30 - 40 ns long of ions flowing axially towards the POS load at velocities (2±1) x 10 8 cm/s were also observed. The dependences of the start time of the axial ion flow, of the ion velocities, and of the ion flux on the POS operation parameters were studied. (author). 6 figs., 5 refs

Evaluation of the stability of uranyl peroxo-carbonato complex ions in carbonate media at different temperatures.

Science.gov (United States)

Kim, Kwang-Wook; Lee, Keun-Young; Chung, Dong-Yong; Lee, Eil-Hee; Moon, Jei-Kwon; Shin, Dong-Woo

2012-09-30

This work studied the stability of peroxide in uranyl peroxo carbonato complex ions in a carbonate solution with hydrogen peroxide using absorption and Raman spectroscopies, and evaluated the temperature dependence of the decomposition characteristics of uranyl peroxo carbonato complex ions in the solution. The uranyl peroxo carbonato complex ions self-decomposed more rapidly into uranyl tris-carbonato complex ions in higher temperature carbonate solutions. The concentration of peroxide in the solution without free hydrogen peroxide represents the concentration of uranyl peroxo carbonato complex ions in a mixture of uranyl peroxo carbonato complex and uranyl tris-carbonato complex ions. The self-decomposition of the uranyl peroxo carbonato complex ions was a first order reaction, and its activation energy was evaluated to be 7.144×10(3) J mol(-1). The precipitation of sodium uranium oxide hydroxide occurred when the amount of uranyl tris-carbonato complex ions generated from the decomposition of the uranyl peroxo carbonato complex ions exceeded the solubility of uranyl tris-carbonato ions in the solution at the solution temperature. Copyright © 2012 Elsevier B.V. All rights reserved.

ENERGETIC PHOTON AND ELECTRON INTERACTIONS WITH POSITIVE IONS

Energy Technology Data Exchange (ETDEWEB)

Phaneuf, Ronald A. [UNR

2013-07-01

The objective of this research is a deeper understanding of the complex multi-electron interactions that govern inelastic processes involving positive ions in plasma environments, such as those occurring in stellar cares and atmospheres, x-ray lasers, thermonuclear fusion reactors and materials-processing discharges. In addition to precision data on ionic structure and transition probabilities, high resolution quantitative measurements of ionization test the theoretical methods that provide critical input to computer codes used for plasma modeling and photon opacity calculations. Steadily increasing computational power and a corresponding emphasis on simulations gives heightened relevance to precise and accurate benchmark data. Photons provide a highly selective probe of the internal electronic structure of atomic and molecular systems, and a powerful means to better understand more complex electron-ion interactions.

Investigating the low-temperature impedance increase of lithium-ion cells

International Nuclear Information System (INIS)

Abraham, D. P.; Heaton, J. R.; Kang, S.-H.; Dees, D. W.; Jansen, A. N.; Chemical Engineering

2008-01-01

Low-temperature performance loss is a significant barrier to commercialization of lithium-ion cells in hybrid electric vehicles. Increased impedance, especially at temperatures below 0 C, reduces the cell pulse power performance required for cold engine starts, quick acceleration, or regenerative braking. Here we detail electrochemical impedance spectroscopy data on binder- and carbon-free layered-oxide and spinel-oxide electrodes, obtained over the +30 to ?30 C temperature range, in coin cells containing a lithium-preloaded Li 4/3 Ti 5/3 O 4 composite (LTOc) counter electrode and a LiPF 6 -bearing ethylene carbonate/ethyl methyl carbonate electrolyte. For all electrodes studied, the impedance increased with decreasing cell temperature; the increases observed in the midfrequency arc dwarfed the increases in ohmic resistance and diffusional impedance. Our data suggest that the movement of lithium ions across the electrochemical interface on the active material may have been increasingly hindered at lower temperatures, especially below 0 C. Low-temperature performance may be improved by modifying the electrolyte-active material interface (for example, through electrolyte composition changes). Increasing surface area of active particles (for example, through nanoparticle use) can lower the initial electrode impedance and lead to lower cell impedances at -30 C

Direction for the Future - Successive Acceleration of Positive and Negative Ions Applied to Space Propulsion

CERN Document Server

Aanesland, A.; Popelier, L.; Chabert, P.

2013-12-16

Electrical space thrusters show important advantages for applications in outer space compared to chemical thrusters, as they allow a longer mission lifetime with lower weight and propellant consumption. Mature technologies on the market today accelerate positive ions to generate thrust. The ion beam is neutralized by electrons downstream, and this need for an additional neutralization system has some drawbacks related to stability, lifetime and total weight and power consumption. Many new concepts, to get rid of the neutralizer, have been proposed, and the PEGASES ion-ion thruster is one of them. This new thruster concept aims at accelerating both positive and negative ions to generate thrust, such that additional neutralization is redundant. This chapter gives an overview of the concept of electric propulsion and the state of the development of this new ion-ion thruster.

Measurement of Individual H+ and O+ Ion Temperatures in the Topside Ionosphere

Science.gov (United States)

Hsu, Chih-Te; Heelis, Roderick A.

2018-02-01

Plasma temperatures in the ionosphere are associated with both the dynamics and spatial distribution of the neutral and charge particles. During the daytime, temperatures are determined by solar energy inputs and energy exchange between charged and neutral particles. Plasma transport parallel to the magnetic field adds another influence on temperatures through adiabatic processes that are most evident during the nighttime. Previous observations suggest that the topside H+ temperature (TH+) should reside between the O+ temperature (TO+) and the electron temperature (Te), and further calculations confirm the preferential heat transfer from the electrons to H+ in the topside. In this work we implement a more sophisticated analysis procedure to extract individual mass-dependent ion temperatures from the retarding potential analyzer measurements on the DMSP F15 satellite. The results show that the daytime TH+ is a few hundred degrees higher than TO+ at all longitudes. The nighttime temperature difference between TH+ and TO+ is indicative of mass-dependent adiabatic heating and cooling processes across the equatorial region. The ion temperatures and measured plasma flows present clear longitudinal variations that are associated with magnetic declination.

High-rate capability of lithium-ion batteries after storing at elevated temperature

International Nuclear Information System (INIS)

Wu, Mao-Sung; Chiang, Pin-Chi Julia

2007-01-01

High-rate performances of a lithium-ion battery after storage at elevated temperature are investigated electrochemically by means of three-electrode system. The high-rate capability is decreased significantly after high-temperature storage. A 3 C discharge capacities after room-temperature storage and 60 o C storage are 650 and 20 mAh, respectively. Lithium-ion diffusion in lithium cobalt oxide cathode limits the battery's capacity and the results show that storage temperature changes this diffusion behavior. Transmission electron microscopy (TEM) images show that many defects are directly observed in the cathode after storage compared with the fresh cathode; the structural defects block the diffusion within the particles. Electrochemical impedance and polarization curve indicate that mass-transfer (diffusion) dominates the discharge capacity during high-rate discharge

Oblique ion-acoustic cnoidal waves in two temperature superthermal electrons magnetized plasma

International Nuclear Information System (INIS)

Panwar, A.; Ryu, C. M.; Bains, A. S.

2014-01-01

A study is presented for the oblique propagation of ion acoustic cnoidal waves in a magnetized plasma consisting of cold ions and two temperature superthermal electrons modelled by kappa-type distributions. Using the reductive perturbation method, the nonlinear Korteweg de-Vries equation is derived, which further gives the solutions with a special type of cnoidal elliptical functions. Both compressive and rarefactive structures are found for these cnoidal waves. Nonlinear periodic cnoidal waves are explained in terms of plasma parameters depicting the Sagdeev potential and the phase curves. It is found that the density ratio of hot electrons to ions μ significantly modifies compressive/refractive wave structures. Furthermore, the combined effects of superthermality of cold and hot electrons κ c ,κ h , cold to hot electron temperature ratio σ, angle of propagation and ion cyclotron frequency ω ci have been studied in detail to analyze the height and width of compressive/refractive cnoidal waves. The findings in the present study could have important implications in understanding the physics of electrostatic wave structures in the Saturn's magnetosphere where two temperature superthermal electrons are present

An analytic expression for the sheath criterion in magnetized plasmas with multi-charged ion species

International Nuclear Information System (INIS)

Hatami, M. M.

2015-01-01

The generalized Bohm criterion in magnetized multi-component plasmas consisting of multi-charged positive and negative ion species and electrons is analytically investigated by using the hydrodynamic model. It is assumed that the electrons and negative ion density distributions are the Boltzmann distribution with different temperatures and the positive ions enter into the sheath region obliquely. Our results show that the positive and negative ion temperatures, the orientation of the applied magnetic field and the charge number of positive and negative ions strongly affect the Bohm criterion in these multi-component plasmas. To determine the validity of our derived generalized Bohm criterion, it reduced to some familiar physical condition and it is shown that monotonically reduction of the positive ion density distribution leading to the sheath formation occurs only when entrance velocity of ion into the sheath satisfies the obtained Bohm criterion. Also, as a practical application of the obtained Bohm criterion, effects of the ionic temperature and concentration as well as magnetic field on the behavior of the charged particle density distributions and so the sheath thickness of a magnetized plasma consisting of electrons and singly charged positive and negative ion species are studied numerically

Fluid simulations of toroidal ion temperature gradient turbulence

International Nuclear Information System (INIS)

Sandberg, I.; Isliker, H.; Pavlenko, V.P.; Hizanidis, K.; Vlahos, L.

2006-01-01

The evolution of the toroidal ion temperature gradient mode instability is numerically studied by using the equations based on the standard reactive fluid model. The long-term dynamics of the instability are investigated using random-phase, small-amplitude fluctuations for initial conditions. The main events during the evolution of the instability that lead to the formation of large-scale coherent structures are described and the role of the dominant nonlinearities is clarified. The polarization drift nonlinearity leads to the inverse energy cascade while the convective ion heat nonlinearity is responsible for the saturation of the instability. Finally, the sensitivity of the saturated state to the initial plasma conditions is examined

Optimization of Ion Source Head Position in the Central Region of DECY-13 Cyclotron

Directory of Open Access Journals (Sweden)

S Silakhuddin

2017-08-01

Full Text Available Optimization of the ion source head position of the DECY-13 Cyclotron in the central region has been carried out based on simulation process using a particle tracking program written in Scilab 5.2.1. The simulated particle was the H- ion that was accelerated in DECY-13 Cyclotron. The input for the program were the magnetic field and the electric field in the central region that were calculated by Opera-3D software package and TOSCA module. The optimized position of ion source head position is in a radius of 2 cm relative to the zero point of the magnet and at a distance of 4 mm relative to the puller. This result can be useful for determining the configuration of the parts in the central region when it is tested for generating the first ion beam in the future.

Saturation mechanism of decaying ion temperature gradient driven turbulence with kinetic electrons

International Nuclear Information System (INIS)

Idomura, Yasuhiro

2016-01-01

We present full-f gyrokinetic simulations of the ion temperature gradient driven (ITG) turbulence including kinetic electrons. By comparing decaying ITG turbulence simulations with adiabatic and kinetic electron models, an impact of kinetic electrons on the ITG turbulence is investigated. It is found that significant electron transport occurs even in the ITG turbulence, and both ion and electron temperature profiles are relaxed. In steady states, both cases show upshifts of nonlinear critical ion temperature gradients from linear ones, while their saturation mechanisms are qualitatively different. In the adiabatic electron case, the ITG mode is stabilized by turbulence driven zonal flows. On the other hand, in the kinetic electron case, passing electrons transport shows fine resonant structures at mode rational surfaces, which generate corrugated density profiles. Such corrugated density profiles lead to fine radial electric fields following the neoclassical force balance relation. The resulting E × B shearing rate greatly exceeds the linear growth rate of the ITG mode. (author)

Integrated discharge scenario for high-temperature helical plasma on LHD

International Nuclear Information System (INIS)

Nagaoka, K.; Takahashi, H.; Murakami, S.

2014-10-01

Discharge scenario of high temperature plasma with helical configuration has been significantly progressed. The increase of central ion temperature due to reduction of wall recycling was clearly observed. The neutral particle profile was measured with a high-dynamic range of Balmer-α spectroscopy, and the reduction of neutral density was identified after helium conditioning main discharges. The peaking of ion heating profile and the reduction of charge exchange loss of energetic ions play an important role for improvement of ion heat transport in the core. The ion ITB and electron ITB have been successfully integrated due to superposition of centrally focused electron cyclotron heating to the ion ITB plasma, and the high temperature regime of T i ∼T e has been significantly extended. The normalized temperature gradient of ion and electron (R/L T ) were observed to exceed 10, indicating the significant improvement of both ion and electron heat transports at the barrier position. The positive radial electric field was observed by heavy ion beam probe, while the negative radial electric field was observed in ion ITB plasmas. The ion temperature gradient was observed to decrease with the increase of temperature ratio (T e /T i ). This experiment demonstrated that the profile control is a key to combine ion ITB and electron ITB and have a potential to improve the performance of helical plasmas. (author)

Numerical simulation of simultaneous acceleration of positive and negative ions in an RFQ

International Nuclear Information System (INIS)

Oguri, Y.

1994-01-01

By means of a numerical method, beam dynamics was analyzed for an RFQ, where mixtures of positive and negative ions were injected into the quadrupole channel. In order to simulate simultaneous bunching of ions with opposite charges, motion of particles injected into the cavity during two RF periods were traced under consideration of 3D Coulomb forces between particles. Effects of neighbor bunches were also taken into account. In the radial matching section of the structure, beam divergence due to space charge force was completely suppressed by the charge neutralization. However, it has been found that the attractive forces between positive and negative ions prevent bunch formation in the bunching section, leading to longitudinal beam loss. Dependence of the beam transmission efficiency on the input beam intensity is reported. These results are compared with those obtained when injecting single ion species

Coupled ion temperature gradient and trapped electron mode to electron temperature gradient mode gyrokinetic simulations

International Nuclear Information System (INIS)

Waltz, R. E.; Candy, J.; Fahey, M.

2007-01-01

Electron temperature gradient (ETG) transport is conventionally defined as the electron energy transport at high wave number (high-k) where ions are adiabatic and there can be no ion energy or plasma transport. Previous gyrokinetic simulations have assumed adiabatic ions (ETG-ai) and work on the small electron gyroradius scale. However such ETG-ai simulations with trapped electrons often do not have well behaved nonlinear saturation unless fully kinetic ions (ki) and proper ion scale zonal flow modes are included. Electron energy transport is separated into ETG-ki at high-k and ion temperature gradient-trapped electron mode (ITG/TEM) at low-k. Expensive (more computer-intensive), high-resolution, large-ion-scale flux-tube simulations coupling ITG/TEM and ETG-ki turbulence are presented. These require a high effective Reynolds number R≡[k(max)/k(min)] 2 =μ 2 , where μ=[ρ si /ρ si ] is the ratio of ion to electron gyroradii. Compute times scale faster than μ 3 . By comparing the coupled expensive simulations with (1) much cheaper (less compute-intensive), uncoupled, high-resolution, small, flux-tube ETG-ki and with (2) uncoupled low-resolution, large, flux-tube ITG/TEM simulations, and also by artificially turning ''off'' the low-k or high-k drives, it appears that ITG/TEM and ETG-ki transport are not strongly coupled so long as ETG-ki can access some nonadiabatic ion scale zonal flows and both high-k and low-k are linearly unstable. However expensive coupled simulations are required for physically accurate k-spectra of the transport and turbulence. Simulations with μ≥30 appear to represent the physical range μ>40. ETG-ki transport measured in ion gyro-Bohm units is weakly dependent on μ. For the mid-radius core tokamak plasma parameters studied, ETG-ki is about 10% of the electron energy transport, which in turn is about 30% of the total energy transport (with negligible ExB shear). However at large ExB shear sufficient to quench the low-k ITG

Effects of ion temperature fluctuations on the stability of resistive ballooning modes

International Nuclear Information System (INIS)

Singh, R.; Nordman, H.; Jarmen, A.; Weiland, J.

1996-01-01

The influence of ion temperature fluctuations on the stability of resistive drift- and ballooning-modes is investigated using a two-fluid model. The Eigenmode equations are derived and solved analytically in a low beta model equilibrium. Parameters relevant to L-mode edge plasmas from the Texas Experimental Tokamak are used. The resistive modes are found to be destabilized by ion temperature fluctuations over a broad range of mode numbers. The scaling of the growth rate with magnetic shear and mode number is elucidated. 13 refs, 4 figs

Dust acoustic solitary waves and double layers in a dusty plasma with two-temperature trapped ions

International Nuclear Information System (INIS)

El-Labany, S.K.; El-Taibany, W.F.; Mamun, A.A.; Moslem, Waleed M.

2004-01-01

The combined effects of trapped ion distribution, two-ion-temperature, dust charge fluctuation, and dust fluid temperature are incorporated in the study of nonlinear dust acoustic waves in an unmagnetized dusty plasma. It is found that, owing to the departure from the Boltzmann ion distribution to the trapped ion distribution, the dynamics of small but finite amplitude dust acoustic waves is governed by a modified Korteweg-de Vries equation. The latter admits a stationary dust acoustic solitary wave solution, which has stronger nonlinearity, smaller amplitude, wider width, and higher propagation velocity than that involving adiabatic ions. The effect of two-ion-temperature is found to provide the possibility for the coexistence of rarefactive and compressive dust acoustic solitary structures and double layers. Although the dust fluid temperature increases the amplitude of the small but finite amplitude solitary waves, the dust charge fluctuation does the opposite effect. The present investigation should help us to understand the salient features of the nonlinear dust acoustic waves that have been observed in a recent numerical simulation study

Variation and balance of positive air ion concentrations in a boreal forest

Directory of Open Access Journals (Sweden)

U. Hõrrak

2008-02-01

Full Text Available Air ions are characterized on the basis of measurements carried out in a boreal forest at the Hyytiälä SMEAR station, Finland, during the BIOFOR III campaign in spring 1999. The air ions were discriminated as small ions (charged molecular aggregates of the diameter of less than 2.5 nm, intermediate ions (charged aerosol particles of the diameter of 2.5–8 nm, and large ions (charged aerosol particles of the diameter of 8–20 nm. Statistical characteristics of the ion concentrations and the parameters of ion balance in the atmosphere are presented separately for the nucleation event days and non-event days. In the steady state, the ionization rate is balanced with the loss of small ions, which is expressed as the product of the small ion concentration and the ion sink rate. The widely known sinks of small ions are the recombination with small ions of opposite polarity and attachment to aerosol particles. The dependence of small ion concentration on the concentration of aerosol particles was investigated applying a model of the bipolar diffusion charging of particles by small ions. When the periods of relative humidity above 95% and wind speed less than 0.6 m s⁻¹ were excluded, then the small ion concentration and the theoretically calculated small ion sink rate were closely negatively correlated (correlation coefficient −87%. However, an extra ion loss term of the same magnitude as the ion loss onto aerosol particles is needed for a quantitative explanation of the observations. This term is presumably due to the small ion deposition on coniferous forest. The hygroscopic growth correction of the measured aerosol particle size distributions was also found to be necessary for the proper estimation of the ion sink rate. In the case of nucleation burst events, the concentration of small positive ions followed the general balance equation, no extra ion loss in addition to the deposition on coniferous forest was detected, and the

Ion temperature measurements of turbulently heated tokamak plasma by Doppler-broadening of visible lines in TRIAM-1

Energy Technology Data Exchange (ETDEWEB)

Hiraki, N; Nakamura, K; Toi, K; Itoh, S [Kyushu Univ., Fukuoka (Japan). Research Inst. for Applied Mechanics

1981-01-01

In the turbulent heating experiment of the high-field tokamak TRIAM-1, the bulk ion heating shown by the neutral energy analyzer measurement is confirmed by the Doppler broadening measurement of visible lines. The increasing rate and decay time of the Doppler ion temperature are almost the same as those derived from the neutral energy analyzer measurement. From both methods of ion temperature measurements, it is shown that the ion temperature has a parabolic profile within 50 ..mu..s after the application of the heating pulse.

Distribution of positive ion species above a diffuse midnight aurora

International Nuclear Information System (INIS)

Moore, T.E.

1978-01-01

The origin of the hot plasma in the Earth's magnetosphere is still open to investigation. Mass composition is an indicator of source region, while the distribution functions bear the signatures of transport and energization processes. Only ions identified as H + and He ++ were detected, and the He ++ was statistically marginal. Coincident magnetic storms are likely to play a crucial role in populating the magnetosphere with energized ionospheric ions. The measured proton distribution was nearly isotropic over downcoming pitch angles at all energies and showed a depleted atmospheric source cone. The high-altitude proton energy distribution had a best fit temperature of 4.5 keV and a number density of 0.17 cm- 3 , corresponding to a peak intensity just over 10 5 cm -2 s -1 sr -1 keV -1 . Altitudinal variations are consistent with the theory of charge exchange of a time-steady incident proton population. Simultaneous electron measurements can be interpreted in terms of an incident electron distribution that is also thermal wih a similar number density but a temperature of 2.5 keV. Taken together, the ion and electron data are consistent with the model of diffuse auroras in which plasma convecting in from the magnetospheric tail precipitates due to strong pitch angle diffusion on auroral field lines linking the near Earth plasma sheet

Electrolytes for Wide Operating Temperature Lithium-Ion Cells

Science.gov (United States)

Smart, Marshall C. (Inventor); Bugga, Ratnakumar V. (Inventor)

2016-01-01

Provided herein are electrolytes for lithium-ion electrochemical cells, electrochemical cells employing the electrolytes, methods of making the electrochemical cells and methods of using the electrochemical cells over a wide temperature range. Included are electrolyte compositions comprising a lithium salt, a cyclic carbonate, a non-cyclic carbonate, and a linear ester and optionally comprising one or more additives.

Winter nightime ion temperatures and energetic electrons from 0go 6 plasma measurements

International Nuclear Information System (INIS)

Sanatani, S.; Breig, E.L.

1981-01-01

This paper presents and discusses ion temperature and suprathermal electron flux data acquired with the retarding potential analyzer on board the ogo 6 satellite when it was in solar eclipse. Attention is directed to measurements in the 400- to 800-km height interval between midnight and predawn in the northern winter nonpolar ionosphere. Statistical analysis of data recorded during a 1-month time span permits a decoupling of horizontal and altitude effects. A distinct longitudinal variation is observed for ion temperature above 500 km, with a significant relative enhancement over the western North Altantic Altitude distributions of ion temperature are compatible with Millstone Hill profiles within the common region of this enhancement. Large fluxes of energetic electrons are observed and extend to mush lower geomagnetic latitudes in the same longitude sector. Both a direct correlation in magnitude and a strong similarity in spatial extent are demonstrated for these ion temperature and electron flux data. The location of the limiting low-altitude boundary for observation of the electron fluxes is variable, dependent on local time and season as well as longitude. Variations in this boundary are found to be consistent with a calculated conjugate solar zenith angle of 99 0 +- 2 0 describing photoproduction of energetic electrons in the southern hemisphere. The ogo 6 data are considered to be indicative of an energy source originating in the sunlit summer hemisphere and providing heat via transport of photoelectrons to a broad but preferential segment of the winter nighttime mid-latitude ionosphere. Ions at other longitudes are without access to this energy source and cool to near the neutral temperature at heights to above 800 km inthe predawn hours

New high temperature plasma ion source for the TRISTAN ISOL facility

International Nuclear Information System (INIS)

Piotrowski, A.; Gill, R.L.; McDonald, D.C.

1986-08-01

A vigorous program of ion source development at TRISTAN has led to several types of ion sources that are especially suited to extended operation at a reactor-based ISOL facility. The latest of these is a high temperature plasma ion source in which a 5 gm 235 U target is located in the cathode and can be heated to 2500 0 C. The ion source has a lifetime of >1000 hours and produces a wide array of elements, including Pd. Off-line investigations indicate that the source functions primarily in an electron impact mode of ionization and exhibits typical ionzation efficiencies of >30% for Xe

Proton transfer and complex formation of angiotensin I ions with gaseous molecules at various temperature

International Nuclear Information System (INIS)

Nonose, Shinji; Yamashita, Kazuki; Sudo, Ayako; Kawashima, Minami

2013-01-01

Highlights: • Proton transfer from angiotensin I ions (z = 2, 3) to gaseous molecules was studied. • Temperature dependence of absolute reaction rate constants was measured. • Remarkable changes were obtained for distribution of product ions and reaction rate constants. • Proton transfer reaction was enhanced and reduced by complex formation. • Conformation changes are induced by complex formation and or by thermal collision with He. - Abstract: Proton transfer reactions of angiotensin I ions for +2 charge state, [M + 2H] 2+ , to primary, secondary and aromatic amines were examined in the gas phase. Absolute reaction rate constants for proton transfer were determined from intensities of parent and product ions in the mass spectra. Temperature dependence of the reaction rate constants was measured. Remarkable change was observed for distribution of product ions and reaction rate constants. Proton transfer reaction was enhanced or reduced by complex formation of [M + 2H] 2+ with gaseous molecules. The results relate to conformation changes of [M + 2H] 2+ with change of temperature, which are induced by complex formation and or by thermal collision with He. Proton transfer reactions of angiotensin I ions for +3 charge state, [M + 3H] 3+ , were also studied. The reaction rates did not depend on temperature so definitely

Diagnostics and equipment for ion temperatures and implosion neutron yields

International Nuclear Information System (INIS)

Chen Jiabin; Zheng Zhijian; Peng Hansheng; Wen Shuhuai; Zhang Baohan; Ding Yongkun; Qi Lanying; Chen Ming; Li Chaoguang

2001-01-01

Fuel ion temperature is of great importance in the ICF research field. A set of ultra-fast quenched plastic scintillation detector system was fabricated for low yield neutron diagnostic. The detection efficiency and the sensitivity to DT neutrons were scaled using a K-400 accelerator and a pulse neutron tube from Russia with a width 5 - 10 ns, respectively. Its time response functions were calibrated by cosmic ray and implosion neutron separately. Under the conditions of low laser energy so low neutron yield and very limited space, fuel ion temperatures (including implosion neutron yields at the same time) were obtained. The measured ion temperatures for exploding pusher capsules were between 4 keV and 5 keV with errors +-(15 - 25)%. The neutron yields were 5 x 10 8 - 3 x 10 9 for exploding pusher capsules and 1.6 x 10 7 - 3.9 x 10 8 for ablation ones with errors +- (7 - 10)%. Of the six shots of neutron yields calculated, five are in good agreement with authors' experimental results in the range of +- 20%. Not only the heat-conducting mechanism and the effects on implosion of the energy balance of each path of incidence laser, target design, fuel mixture as well as hot electron behavior have been investigated, but also the upgrade level of the laser facility Shengguang II has been tested

Quadrature detection for the separation of the signals of positive and negative ions in fourier transform ion cyclotron resonance mass spectrometry

International Nuclear Information System (INIS)

Schweikhard, Lutz; Drader, Jared J.; Shi, Stone D.-H.; Hendrickson, Christopher L.; Marshall, Alan G.

2002-01-01

Positive and negative ions may be confined simultaneously in a nested open cylindrical Malmberg-Penning trap. However, ion charge sign cannot be distinguished by conventional dipolar (linearly-polarized) detection with a single pair of opposed electrodes. Here, the signals from each of two orthogonal pairs of opposed detection electrodes are acquired simultaneously and stored as real and imaginary parts of mathematically complex data. Complex Fourier transformation yields separate spectra for positive and negative ions. For a fullerene sample, experimental quadrature detection yields C 60 + and C 60 - signals separated by ∼1440 u rather than by the mass of two electrons, ∼0.001 u in conventional dipolar detection

Nonlinear structure formation in ion-temperature-gradient driven drift waves in pair-ion plasma with nonthermal electron distribution

Science.gov (United States)

Razzaq, Javaria; Haque, Q.; Khan, Majid; Bhatti, Adnan Mehmood; Kamran, M.; Mirza, Arshad M.

2018-02-01

Nonlinear structure formation in ion-temperature-gradient (ITG) driven waves is investigated in pair-ion plasma comprising ions and nonthermal electrons (kappa, Cairns). By using the transport equations of the Braginskii model, a new set of nonlinear equations are derived. A linear dispersion relation is obtained and discussed analytically as well as numerically. It is shown that the nonthermal population of electrons affects both the linear and nonlinear characteristics of the ITG mode in pair-ion plasma. This work will be useful in tokamaks and stellarators where non-Maxwellian population of electrons may exist due to resonant frequency heating, electron cyclotron heating, runaway electrons, etc.

Status report on the positive ion injector (PII) for ATLAS at Argonne National Laboratory

International Nuclear Information System (INIS)

Zinkann, G.P.; Added, N.; Billquist, P.; Bogaty, J.; Clifft, B.; Markovich, P.; Phillips, D.; Strickhorn, P.; Shepard, K.W.

1991-01-01

The Positive Ion Injector (PII) is part of the Uranuim upgrade for ATLAS accelerator at Argonne National Laboratory. This paper will include a technical discussion of the Positive Ion Injector (PII) accelerator with its superconducting, niobium, very low-velocity accelerating structures. It will also discuss the current construction schedule of PII, and review an upgrade of the fast- tuning system. 10 refs., 6 figs

Status report on the positive ion injector (PII) for ATLAS at Argonne National Laboratory

Energy Technology Data Exchange (ETDEWEB)

Zinkann, G.P.; Added, N.; Billquist, P.; Bogaty, J.; Clifft, B.; Markovich, P.; Phillips, D.; Strickhorn, P.; Shepard, K.W.

1991-01-01

The Positive Ion Injector (PII) is part of the Uranuim upgrade for ATLAS accelerator at Argonne National Laboratory. This paper will include a technical discussion of the Positive Ion Injector (PII) accelerator with its superconducting, niobium, very low-velocity accelerating structures. It will also discuss the current construction schedule of PII, and review an upgrade of the fast- tuning system. 10 refs., 6 figs.

Ion sources for initial use at the Holifield radioactive ion beam facility

International Nuclear Information System (INIS)

Alton, G.D.

1994-01-01

The Holifield Radioactive Ion Beam Facility (HRIBF) now under construction at the Oak Ridge National Laboratory will use the 25-MV tandem accelerator for the acceleration of radioactive ion beams to energies appropriate for research in nuclear physics; negative ion beams are, therefore, required for injection into the tandem accelerator. Because charge exchange is an efficient means for converting initially positive ion beams to negative ion beams, both positive and negative ion sources are viable options for use at the facility; the choice of the type of ion source will depend on the overall efficiency for generating the radioactive species of interest. A high-temperature version of the CERN-ISOLDE positive ion source has been selected and a modified version of the source designed and fabricated for initial use at the HRIBF because of its low emittance, relatively high ionization efficiencies and species versatility, and because it has been engineered for remote installation, removal and servicing as required for safe handling in a high-radiation-level ISOL facility. Prototype plasma-sputter negative ion sources and negative surfaceionization sources are also under design consideration for generating negative radioactive ion beams from high electron-affinity elements. A brief review of the HRIBF will be presented, followed by a detailed description of the design features, operational characteristics, ionization efficiencies, and beam qualities (emittances) of these sources

Electric sheath and presheath in a collisionless, finite ion temperature plasma

International Nuclear Information System (INIS)

Emmert, G.A.; Wieland, R.M.; Mense, A.T.; Davidson, J.N.

1980-01-01

The plasma-sheath equation for a collisionless plasma with arbitrary ion temperature in plane geometry is formulated. Outside the sheath, this equation is approximated by the plasma equation, for which an analytic solution for the electrostatic potential is obtained. In addition, the ion distribution function, the wall potential, and the ion energy and particle flux into the sheath are explicitly calculated. The plasma-sheath equation is also solved numerically with no approximation of the Debye length. The numerical results compare well with the analytical results when the Debye length is small

Influence of Chloride Ion and Temperature on the Corrosion Behavior of Ni-Fe-Cr Alloy 028

Science.gov (United States)

Zhang, L. N.; Dong, J. X.; Szpunar, J. A.; Zhang, M. C.; Basu, R.

Recently, the working condition of tubing systems used in oil and natural gas industries are severer than before with the increasing exploitation of acidic gas fields. The corrosion problems induced from the corrosive environment with chloride ion medium and high temperature have been much more concerned. The presence of chloride ion can accelerate the dissolution of metals. The corrosion performance is also sensitive to the operating temperature. Classic localized corrosions such as the pitting or the crevice type due to environmental temperature and chloride ion.

Ion temperatures in HIP-1 and SUMMA from charge-exchange neutral optical emission spectra

Science.gov (United States)

Patch, R. W.; Lauver, M. R.

1976-01-01

Ion temperatures were obtained from observations of the H sub alpha, D sub alpha, and He 587.6 nm lines emitted from hydrogen, deuterium, and helium plasmas in the SUMMA and HIP-1 mirror devices at Lewis Research Center. Steady state discharges were formed by applying a radially inward dc electric field between cylindrical or annular anodes and hollow cathodes located at the peaks of the mirrors. The ion temperatures were found from the Doppler broadening of the charge-exchange components of spectral lines. A statistical method was developed for obtaining scaling relations of ion temperature as a function of current, voltage, and magnetic flux density. Derivations are given that take into account triangular monochromator slit functions, loss cones, and superimposed charge-exchange processes. In addition, the Doppler broadening was found to be sensitive to the influence of drift on charge-exchange cross section. The effects of finite ion-cyclotron radius, cascading, and delayed emission are reviewed.

Cleavage reactions of the complex ions derived from self-complementary deoxydinucleotides and alkali-metal ions using positive ion electrospray ionization with tandem mass spectrometry.

Science.gov (United States)

Xiang, Yun; Abliz, Zeper; Takayama, Mitsuo

2004-05-01

The dissociation reactions of the adduct ions derived from the four self-complementary deoxydinucleotides, d(ApT), d(TpA), d(CpG), d(GpC), and alkali-metal ions were studied in detail by positive ion electrospray ionization multiple-stage mass spectrometry (ESI-MS(n)). For the [M + H](+) ions of the four deoxydinucleotides, elimination of 5'-terminus base or loss of both of 5'-terminus base and a deoxyribose were the major dissociation pathway. The ESI-MS(n) spectra showed that Li(+), Na(+), and Cs(+) bind to deoxydinucleotides mainly by substituting the H(+) of phosphate group, and these alkali-metal ions preferred to bind to pyrimidine bases rather than purine bases. For a given deoxydinucleotide, the dissociation pathway of [M + K](+) ions differed clearly from that of [M + Li](+), [M + Na](+), and [M + Cs](+) ions. Some interesting and characteristic cleavage reactions were observed in the product-ion spectra of [M + K](+) ions, including direct elimination of deoxyribose and HPO(3) from molecular ions. The fragmentation behavior of the [M + K](+) and [M + W](+) (W = Li, Na, Cs) adduct ions depend upon the sequence of bases, the interaction between alkali-metal ions and nucleobases, and the steric hindrance caused by bases.

Extreme implanting in Si: A study of ion-induced damage at high temperature and high dose

International Nuclear Information System (INIS)

Holland, O.W.

1994-01-01

Ion-solid interactions near room temperature and below have been well studied in single-crystal Si. While this has led to a better understanding of the mechanisms responsible for nucleation and growth of lattice damage during irradiation, these studies have not, in general, been extended to high temperatures (e.g., >200 degrees C). This is the case despite the commercialization of ion beam technologies which utilize high-temperature processing, such as separation by implantation of oxygen (SIMOX). In this process, a silicon-on-insulator (SOI) material is produced by implanting a high dose of oxygen ions into a Si wafer to form a buried, stoichiometric oxide layer. Results will be presented of a study of damage accumulation during high-dose implantation of Si at elevated temperatures. In particular, O + -ions were used because of the potential impact of the results on the SIMOX technology. It will be shown that the nature of the damage accumulation at elevated temperatures is quite distinctive and portends the presence of a new mechanism, one which is only dominant under the extreme conditions encountered during ion beam synthesis (i.e., high temperature and high dose). This mechanism is discussed and shown to be quite general and not dependent on the chemical identity of the ions. Also, techniques for suppressing this mechanism by open-quotes defect engineeringclose quotes are discussed. Such techniques are technologically relevant because they offer the possibility of reducing the defect density of the SOI produced by SIMOX

Effects of the instability enhanced friction on relative ion densities in a two-ion species low-temperature plasma

Science.gov (United States)

Vukovic, Mirko

2011-10-01

The instability enhanced friction theory of Baalrud & Hegna (Phys. Plasmas 18, 023505 (2011)) predicts that for comparable ion densities the ions nearly reach a common velocity near the sheath edge in a low temperature plasma. The theory was experimentally confirmed by Yip, Hershkowitz, & Severn (Phys. Rev. Letters 104, 225003 (2010)). We will explore the effects of the theory on relative ion densities in a numerical simulation of an Ar/Xe plasma. Results for a 0D plasma model (Lieberman, Lichtenberg, Principles of Plasma Discharges and Materials Processing, 2005) will be presented.

Measurement of ion temperature and flow in RF start-up plasmas in TST-2 and LATE

International Nuclear Information System (INIS)

Tsuda, Shintaro; Ejiri, Akira; Takase, Yuichi; Tsujii, Naoto; Takeuchi, Toshihiro; Tanaka, Hitoshi; Uchida, Masaki; Maekawa, Takashi

2015-01-01

The ion temperature and flow of RF start-up plasmas in TST-2 and LATE were measured using a visible spectrometer. The plasma currents were 9 kA and 8 kA, respectively. The typical ion temperatures T i and toroidal flow V ϕ were 4 eV and 1 km/s, respectively, in the TST-2 plasma sustained by the lower hybrid wave (20 kW) and T i ∼ 10 eV and V ϕ ∼ 5 km/s in the LATE plasma sustained by the electron cyclotron wave (50 kW). The poloidal flow velocities were comparable to the toroidal velocities. The ion temperatures were relatively high and the ion orbit loss can be significant. (author)

Measurement of the central ion and electron temperature of tokamak plasmas from the x-ray line radiation of high-Z impurity ions

International Nuclear Information System (INIS)

Bitter, M.; von Goeler, S.; Goldman, M.; Hill, K.W.; Horton, R.; Roney, W.; Sauthoff, N.; Stodiek, W.

1982-04-01

This paper describes measurements of the central ion and electron temperature of tokamak plasmas from the observation of the 1s - 2p resonance lines, and the associated dielectronic (1s 2 nl - 1s2pnl, with n greater than or equal to 2) satellites, of helium-like iron (Fe XXV) and titanium (Ti XXI). The satellite to resonance line ratios are very sensitive to the electron temperature and are used as an electron temperature diagnostic. The ion temperature is deduced from the Doppler width of the 1s - 2p resonance lines. The measurements have been performed with high resolution Bragg crystal spectrometers on the PLT (Princeton Large Torus) and PDX (Poloidal Divertor Experiment) tokamaks. The details of the experimental arrangement and line evaluation are described, and the ion and electron temperature results are compared with those obtained from independent diagnostic techniques, such as the analysis of charge-exchange neutrals and measurements of the electron cyclotron radiation. The obtained experimental results permit a detailed comparison with theoretical predictions

Rocket measurements of positive ions during polar mesosphere winter echo conditions

Directory of Open Access Journals (Sweden)

A. Brattli

2006-01-01

Full Text Available On 18 January 2005, two small, instrumented rockets were launched from Andøya Rocket Range (69.3° N, 16° E during conditions with Polar Mesosphere Winter Echoes (PMWE. Each of the rockets was equipped with a Positive Ion Probe (PIP and a Faraday rotation/differential absorption experiment, and was launched as part of a salvo of meteorological rockets measuring temperature and wind using falling spheres and chaff. Layers of PMWE were detected between 55 and 77 km by the 53.5 MHz ALWIN radar. The rockets were launched during a solar proton event, and measured extremely high ion densities, of order 1010 m−3, in the region where PMWE were observed. The density measurements were analyzed with the wavelet transform technique. At large length scales, ~103 m, the power spectral density can be fitted with a k−3 wave number dependence, consistent with saturated gravity waves. Outside the PMWE layers the k−3 spectrum extends down to approximately 102 m where the fluctuations are quickly damped and disappear into the instrumental noise. Inside the PMWE layers the spectrum at smaller length scales is well fitted with a k−5/3 dependence over two decades of scales. The PMWE are therefore clearly indicative of turbulence, and the data are consistent with the turbulent dissipation of breaking gravity waves. We estimate a lower limit for the turbulent energy dissipation rate of about 10−2 W/kg in the upper (72 km layer.

Lithium-ion Energy Storage at Very Low Temperatures, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Li-ion batteries with specific energy >180 Wh/kg, calendar life (>15years), and a wide operating temperature range (-60oC to 60oC) are crucial for the...

Surface modification of positive electrode materials for lithium-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Julien, C.M., E-mail: Christian.Julien@upmc.fr [Sorbonne Universités, UPMC Univ. Paris 6, Physicochimie des Electrolytes et Nanosystèmes Interfaciaux (PHENIX), UMR 8234, 75005 Paris (France); Mauger, A. [Institut de Minéralogie de Physique des Matériaux et de Cosmochimie (IMPMC), UPMC Univ. Paris 6, 4 place Jussieu, 75005 Paris (France); Groult, H. [Sorbonne Universités, UPMC Univ. Paris 6, Physicochimie des Electrolytes et Nanosystèmes Interfaciaux (PHENIX), UMR 8234, 75005 Paris (France); Zaghib, K. [Energy Storage and Conversion, Research Institute of Hydro-Québec, Varennes, Québec J3X 1S1 (Canada)

2014-12-01

The advanced lithium-ion batteries are critically important for a wide range of applications, from portable electronics to electric vehicles. The research on their electrodes aims to increase the energy density and the power density, improve the calendar and the cycling life, without sacrificing the safety issues. A constant progress through the years has been obtained owing to the surface treatment of the particles, in particular the coating of the nanoparticles with a layer that protects the core region from side reactions with the electrolyte, prevents the loss of oxygen, and the dissolution of the metal ions in the electrolyte, or simply improve the conductivity of the powder. The purpose of the present work is to present the different surface modifications that have been tried for three families of positive electrodes: layered, spinel and olivine frameworks that are currently considered as promising materials. The role of the different coats used to improve either the surface conductivity, or the thermal stability, or the structural integrity is discussed. - Highlights: • Report the various surface modifications tried for the positive electrodes of Li-ion batteries. • The role of different coats used to improve the conductivity, or the thermal stability, or the structural integrity. • Improvement of electrochemical properties of electrodes after coating or surface treatment.

Plasma rotation and ion temperature measurements by collective Thomson scattering at ASDEX Upgrade

DEFF Research Database (Denmark)

Stejner Pedersen, Morten; Nielsen, Stefan Kragh; Jacobsen, Asger Schou

2015-01-01

We present the first deuterium ion temperature and rotation measurements by collective Thomson scattering at ASDEX Upgrade. The results are in general agreement with boron-based charge exchange recombination spectroscopy measurements and consistent with neoclassical simulations for the plasma sce...... scenario studied here. This demonstration opens the prospect for direct non-perturbative measurements of the properties of the main ion species in the plasma core with applications in plasma transport and confinement studies.......We present the first deuterium ion temperature and rotation measurements by collective Thomson scattering at ASDEX Upgrade. The results are in general agreement with boron-based charge exchange recombination spectroscopy measurements and consistent with neoclassical simulations for the plasma...

Electron excitation collision strengths for positive atomic ions: a collection of theoretical data

International Nuclear Information System (INIS)

Merts, A.L.; Mann, J.B.; Robb, W.D.; Magee, N.H. Jr.

1980-03-01

This report contains data on theoretical and experimental cross sections for electron impact excitation of positive atomic ions. It is an updated and corrected version of a preliminary manuscript which was used during an Atomic Data Workshop on Electron Excitation of Ions held at Los Alamos in November 1978. The current status of quantitative knowledge of collisional excitation collision strengths is shown for highly stripped ions where configuration mixing, relativistic and resonance effects may be important. The results show a reasonably satisfactory state for first-row isoelectronic ions and indicate that a considerable amount of work remains to be done for second-row and heavier ions

Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature.

Science.gov (United States)

Deng, Changjian; Lau, Miu Lun; Barkholtz, Heather M; Xu, Haiping; Parrish, Riley; Xu, Meiyue Olivia; Xu, Tao; Liu, Yuzi; Wang, Hao; Connell, Justin G; Smith, Kassiopeia A; Xiong, Hui

2017-08-03

We report an amorphous boron nanorod anode material for lithium-ion batteries prepared through smelting non-toxic boron oxide in liquid lithium. Boron in theory can provide capacity as high as 3099 mA h g -1 by alloying with Li to form B 4 Li 5 . However, experimental studies of the boron anode have been rarely reported for room temperature lithium-ion batteries. Among the reported studies the electrochemical activity and cycling performance of the bulk crystalline boron anode material are poor at room temperature. In this work, we utilized an amorphous nanostructured one-dimensional (1D) boron material aiming at improving the electrochemical reactivity between boron and lithium ions at room temperature. The amorphous boron nanorod anode exhibited, at room temperature, a reversible capacity of 170 mA h g -1 at a current rate of 10 mA g -1 between 0.01 and 2 V. The anode also demonstrated good rate capability and cycling stability. The lithium storage mechanism was investigated by both sweep voltammetry measurements and galvanostatic intermittent titration techniques (GITTs). The sweep voltammetric analysis suggested that the contributions from lithium ion diffusion into boron and the capacitive process to the overall lithium charge storage are 57% and 43%, respectively. The results from GITT indicated that the discharge capacity at higher potentials (>∼0.2 V vs. Li/Li + ) could be ascribed to a capacitive process and at lower potentials (ions and the amorphous boron nanorod. This work provides new insights into designing nanostructured boron materials for lithium-ion batteries.

Constituent Ion Temperatures Measured in the Topside Ionosphere

Science.gov (United States)

Hsu, C. T.; Heelis, R. A.

2017-12-01

Plasma temperatures in the ionosphere are associated with both the dynamics and structure of the neutral and charge particles. The temperatures are determined by solar energy inputs and energy exchange between charged particles and neutrals. Previous observations show that during daytime the O+ temperature is generally higher when the fractional contribution of H+ to the plasma is high. Further simulations confirm that the daytime heat balance between the H+ and O+ always keeps the H+ at a temperature higher than the O+. In addition the plasma transport parallel and perpendicular to the magnetic field influences the plasma temperature through adiabatic heating and cooling effects. These processes are also important during the nighttime, when the source of photoionization is absent. In this work we examine a more sophisticated analysis procedure to extract individual mass dependent ion temperature and apply it on the DMSP F15 RPA measurements. The result shows that the daytime TH+ is a few hundred degrees higher than the TO+ and the nighttime temperature difference between TH+ and TO+ is indicative of mass dependent adiabatic heating and cooling processes across the equatorial region.

Unified theory of ballooning instabilities and temperature gradient driven trapped ion modes

International Nuclear Information System (INIS)

Xu, X.Q.

1990-08-01

A unified theory of temperature gradient driven trapped ion modes and ballooning instabilities is developed using kinetic theory in banana regimes. All known results, such as electrostatic and purely magnetic trapped particle modes and ideal MHD ballooning modes (or shear Alfven waves) are readily derived from our single general dispersion relation. Several new results from ion-ion collision and trapped particle modification of ballooning modes are derived and discussed and the interrelationship between those modes is established. 24 refs

Measurement of the ion temperature by analysing the neutral particles in TCA (Tokamak Chauffage Alfven)

International Nuclear Information System (INIS)

Chambrier, A. de; Heym, A.; Hofmann, F.; Joye, B.; Keller, R.; Lietti, A.; Lister, J.B.; Pochelon, A.; Simm, W.

1983-01-01

The aim of the TCA project is to investigate the heating effects of resonant absorption of Alfven waves in a Tokamak plasma. In TCA, the ion temperature increases linearly with the heating. Depending on the conditions, the ion temperature rises from 150 eV to 225 eV. (Auth./G.T.H.)

X-ray trace element analysis with positive ion beams

International Nuclear Information System (INIS)

Davis, R.H.

1973-01-01

A new trace element analysis having the advantage that many elements may be detected in a single measurement, based on positive charged particle induced X-ray florescence and on the production of X-rays by heavy ions, is described. Because of the large cross-sections for the production of discrete X-ray and the low yield of continuum radiation, positive charged particle X-ray florescence is a competitive, fast, analytic tool. In the experiment a beam of positive charged particles from an accelerator was directed toward a target. X-rays induced by the bombardment were detected by a Si(Li) detector the ouput from which was amplified and sorted in a multichannel analyzer. For rapid data handling and analysis, the multichannel analyzer or ADC unit was connected to an on-line computer. A large variety of targets prepared in collaboration with the oceanographers have been studied and spectra obtained for different particles having the same velocity are presented to show that the yield of discrete X-rays increases at least as rapidly as Z 2 . While protons of several MeV appear to be already competitive further advantage may be gained by heavy ions at lower energies since the continuum is reduced while the peak ''signals'' retain strength due to the Z 2 dependence. (S.B.)

Wide-Temperature Electrolytes for Lithium-Ion Batteries.

Science.gov (United States)

Li, Qiuyan; Jiao, Shuhong; Luo, Langli; Ding, Michael S; Zheng, Jianming; Cartmell, Samuel S; Wang, Chong-Min; Xu, Kang; Zhang, Ji-Guang; Xu, Wu

2017-06-07

Formulating electrolytes with solvents of low freezing points and high dielectric constants is a direct approach to extend the service-temperature range of lithium (Li)-ion batteries (LIBs). In this study, we report such wide-temperature electrolyte formulations by optimizing the ethylene carbonate (EC) content in the ternary solvent system of EC, propylene carbonate (PC), and ethyl methyl carbonate (EMC) with LiPF 6 salt and CsPF 6 additive. An extended service-temperature range from -40 to 60 °C was obtained in LIBs with lithium nickel cobalt aluminum oxide (LiNi 0.80 Co 0.15 Al 0.05 O 2 , NCA) as cathode and graphite as anode. The discharge capacities at low temperatures and the cycle life at room temperature and elevated temperatures were systematically investigated together with the ionic conductivity and phase-transition behaviors. The most promising electrolyte formulation was identified as 1.0 M LiPF 6 in EC-PC-EMC (1:1:8 by wt) with 0.05 M CsPF 6 , which was demonstrated in both coin cells of graphite∥NCA and 1 Ah pouch cells of graphite∥LiNi 1/3 Mn 1/3 Co 1/3 O 2 . This optimized electrolyte enables excellent wide-temperature performances, as evidenced by the high capacity retention (68%) at -40 °C and C/5 rate, significantly higher than that (20%) of the conventional LIB electrolyte, and the nearly identical stable cycle life as the conventional LIB electrolyte at room temperature and elevated temperatures up to 60 °C.

Comparison of Conductor-Temperature Calculations Based on Different Radial-Position-Temperature Detections for High-Voltage Power Cable

Directory of Open Access Journals (Sweden)

Lin Yang

2018-01-01

Full Text Available In this paper, the calculation of the conductor temperature is related to the temperature sensor position in high-voltage power cables and four thermal circuits—based on the temperatures of insulation shield, the center of waterproof compound, the aluminum sheath, and the jacket surface are established to calculate the conductor temperature. To examine the effectiveness of conductor temperature calculations, simulation models based on flow characteristics of the air gap between the waterproof compound and the aluminum are built up, and thermocouples are placed at the four radial positions in a 110 kV cross-linked polyethylene (XLPE insulated power cable to measure the temperatures of four positions. In measurements, six cases of current heating test under three laying environments, such as duct, water, and backfilled soil were carried out. Both errors of the conductor temperature calculation and the simulation based on the temperature of insulation shield were significantly smaller than others under all laying environments. It is the uncertainty of the thermal resistivity, together with the difference of the initial temperature of each radial position by the solar radiation, which led to the above results. The thermal capacitance of the air has little impact on errors. The thermal resistance of the air gap is the largest error source. Compromising the temperature-estimation accuracy and the insulation-damage risk, the waterproof compound is the recommended sensor position to improve the accuracy of conductor-temperature calculation. When the thermal resistances were calculated correctly, the aluminum sheath is also the recommended sensor position besides the waterproof compound.

Future Perspectives for the Application of Low Temperature Detectors in Heavy Ion Physics

International Nuclear Information System (INIS)

Egelhof, P.; Kraft-Bermuth, S.

2009-01-01

Calorimetric low temperature detectors have the potential to become powerful tools for applications in many fields of heavy ion physics. A brief overview of heavy ion physics is given, and the next generation heavy ion facility FAIR is described with a special emphasis on the potential advantage of Low Temperature Detectors (LTDs) for applications in heavy ion physics. For prototype LTDs for the energy sensitive detection of heavy ions excellent results with respect to energy resolution down to δE/E = 1-2x10 -3 for a wide range of incident energies, and with respect to other detector properties, such as energy linearity with no indication of pulse height defects even for the heaviest ions, have been obtained. In addition, prototype detectors for hard X-rays have shown energy resolutions down to δE = 30-40eV at 60 keV. Consequently, both detector schemes have already been successfully used for first experiments. At present, the design and setup of large solid angle detector arrays is in progress. With the already achieved performance, LTDs promise a large potential for applications in atomic and nuclear heavy ion physics. A brief overview of prominent examples, including high-resolution nuclear spectroscopy, nuclear structure studies with radioactive beams, superheavy element research, as well as high-resolution atomic spectroscopy on highly charged ions and tests of QED in strong electromagnetic fields is presented.

Utilize the spectral line pair of the same ionized state ion to measure the ion temperature of tokamak plasma

International Nuclear Information System (INIS)

Lin Xiaodong

2000-01-01

Making use of a Fabry-Perot interferometer driven by a piezoelectric crystal and selecting the suitable separation of plates, the ion temperature is defined by measuring the superimposed profile of the spectral line pair of the same ionized state ions in Tokamak. The advantage of this method is to higher spectral resolution and wider spectral range select

Effect of irradiation temperature on microstructural changes in self-ion irradiated austenitic stainless steel

Science.gov (United States)

Jin, Hyung-Ha; Ko, Eunsol; Lim, Sangyeob; Kwon, Junhyun; Shin, Chansun

2017-09-01

We investigated the microstructural and hardness changes in austenitic stainless steel after Fe ion irradiation at 400, 300, and 200 °C using transmission electron microscopy (TEM) and nanoindentation. The size of the Frank loops increased and the density decreased with increasing irradiation temperature. Radiation-induced segregation (RIS) was detected across high-angle grain boundaries, and the degree of RIS increases with increasing irradiation temperature. Ni-Si clusters were observed using high-resolution TEM in the sample irradiated at 400 °C. The results of this work are compared with the literature data of self-ion and proton irradiation at comparable temperatures and damage levels on stainless steels with a similar material composition with this study. Despite the differences in dose rate, alloy composition and incident ion energy, the irradiation temperature dependence of RIS and the size and density of radiation defects followed the same trends, and were very comparable in magnitude.

A reduced model for ion temperature gradient turbulent transport in helical plasmas

International Nuclear Information System (INIS)

Nunami, M.; Watanabe, T.-H.; Sugama, H.

2013-07-01

A novel reduced model for ion temperature gradient (ITG) turbulent transport in helical plasmas is presented. The model enables one to predict nonlinear gyrokinetic simulation results from linear gyrokinetic analyses. It is shown from nonlinear gyrokinetic simulations of the ITG turbulence in helical plasmas that the transport coefficient can be expressed as a function of the turbulent fluctuation level and the averaged zonal flow amplitude. Then, the reduced model for the turbulent ion heat diffusivity is derived by representing the nonlinear turbulent fluctuations and zonal flow amplitude in terms of the linear growth rate of the ITG instability and the linear response of the zonal flow potentials. It is confirmed that the reduced transport model results are in good agreement with those from nonlinear gyrokinetic simulations for high ion temperature plasmas in the Large Helical Device. (author)

Studies of the trapped particle and ion temperature gradient instabilities in the Columbia Linear Machine

International Nuclear Information System (INIS)

Mathey, O.H.

1989-01-01

In the first part of the work, the effects of weak Coulomb and neutral collisions on the collisionless curvature driven trapped particle mode are studied in the Columbia Linear Machine (CLM) [Phys. Rev. Lett. 57, 1729, (1986)]. Low Coulomb collisionality yields a small stabilizing correction to the magnetohydrodynamic (MHD) collisionless mode, which scales as v, using the Krook model, and ν ec 1/2 using a Lorentz pitch angle operator. In higher collisionality regimes, both models tend to yield similar scalings. In view of relative high neutral collisionality in CLM, both types of collisionality are then combined, modeling neutral collisions with the conserving Krook and Coulomb collisions with a Lorentz model. The dispersion relation is then integrated over velocity space. This combination yields results in very good accord with the available experimental data. The Ion Temperature Gradient Instability is then investigated. It is shown that anisotropy in gradient has a substantial effect on the ion temperature gradient driven mode. A gradient in the parallel temperature is needed for an instability to occur, and a gradient in the perpendicular temperature gradient further enhances the instability indirectly as long as the frequency of the mode is near ion resonance. The physical reason for this important role difference is presented. The Columbia Linear Machine is being redesigned to produce and identify the ion temperature gradient driven η i mode. Using the expected parameters, the author has developed detailed predictions of the mode characteristics in the CLM. Strong multi mode instabilities are expected. As the ion parallel and perpendicular ion temperature gradients are expected to differ significantly, we differentiate between η i parallel and ν i perpendicular and explore the physical differences between them, which leads to a scheme for stabilization of the mode

Effects of the safety factor on ion temperature gradient modes

International Nuclear Information System (INIS)

Wang, A.K.; Dong, J.Q.; Sanuki, H.; Itoh, K.

2003-01-01

A model for the ion temperature gradient (ITG) driven instability is derived from Braginskii magnetohydrodynamic equations of ions. The safety factor q in a toroidal plasma is introduced into the model through the current density J parallel . The effects of q or J parallel on both the ITG instability in k perpendicular and k parallel spectra and the critical stability thresholds are studied. It is shown that the current density // J or the safety factor q plays an important role in stabilizing the ITG instability. (author)

Beam position monitor R&D for keV ion beams

CERN Document Server

Naveed, S; Nosych, A; Søby,L

2013-01-01

Beams of cooled antiprotons at keV energies shall be provided by the Ultra-low energy Storage Ring (USR) at the Facility for Low energy Antiproton and Ion Research (FLAIR) and the Extra Low ENergy Antiproton ring (ELENA) at CERN's Antiproton Decelerator (AD) facility. Both storage rings put challenging demands on the beam position monitoring (BPM) system as their capacitive pick-ups should be capable of determining the beam position of beams at low intensities and low velocities, close to the noise level of state-of-the-art electronics. In this contribution we describe the design and anticipated performance of BPMs for low-energy ion beams with a focus on the ELENA orbit measurement systems. We also present the particular challenges encountered in the numerical simulation of pickup response at very low beta values. Finally, we provide an outlook on how the implementation of faster algorithms for the simulation of BPM characteristics could potentially help speed up such studies considerably.

Temperature annealing of tracks induced by ion irradiation of graphite

International Nuclear Information System (INIS)

Liu, J.; Yao, H.J.; Sun, Y.M.; Duan, J.L.; Hou, M.D.; Mo, D.; Wang, Z.G.; Jin, Y.F.; Abe, H.; Li, Z.C.; Sekimura, N.

2006-01-01

Highly oriented pyrolytic graphite (HOPG) samples were irradiated by Xe ions of initial kinetic energy of 3 MeV/u. The irradiations were performed at temperatures of 500 and 800 K. Scanning tunneling microscopy (STM) images show that the tracks occasionally have elongated structures under high-temperature irradiation. The track creation yield at 800 K is by three orders of magnitude smaller compared to that obtained during room-temperature irradiation. STM and Raman spectra show that amorphization occurs in graphite samples irradiated at 500 K to higher fluences, but not at 800 K. The obtained experimental results clearly reveal that the irradiation under high temperature causes track annealing

AC impedance electrochemical modeling of lithium-ion positive electrodes

International Nuclear Information System (INIS)

Dees, D.; Gunen, E.; Abraham, D.; Jansen, A.; Prakash, J.

2004-01-01

Under Department of Energy's Advanced Technology Development Program,various analytical diagnostic studies are being carried out to examine the lithium-ion battery technology for hybrid electric vehicle applications, and a series of electrochemical studies are being conducted to examine the performance of these batteries. An electrochemical model was developed to associate changes that were observed in the post-test analytical diagnostic studies with the electrochemical performance loss during testing of lithium ion batteries. While both electrodes in the lithium-ion cell have been studied using a similar electrochemical model, the discussion here is limited to modeling of the positive electrode. The positive electrode under study has a composite structure made of a layered nickel oxide (LiNi 0.8 Co 0.15 Al 0.05 O 2 ) active material, a carbon black and graphite additive for distributing current, and a PVDF binder all on an aluminum current collector. The electrolyte is 1.2M LiPF 6 dissolved in a mixture of EC and EMC and a Celgard micro-porous membrane is used as the separator. Planar test cells (positive/separator/negative) were constructed with a special fixture and two separator membranes that allowed the placement of a micro-reference electrode between the separator membranes (1). Electrochemical studies including AC impedance spectroscopy were then conducted on the individual electrodes to examine the performance and ageing effects in the cell. The model was developed by following the work of Professor Newman at Berkeley (2). The solid electrolyte interface (SEI) region, based on post-test analytical results, was assumed to be a film on the oxide and an oxide layer at the surface of the oxide. A double layer capacity was added in parallel with the Butler-Volmer kinetic expression. The pertinent reaction, thermodynamic, and transport equations were linearized for a small sinusoidal perturbation (3). The resulting system of differential equations was solved

IGUN-A program for the simulation of positive ion extraction including magnetic fields

International Nuclear Information System (INIS)

Becker, R.; Herrmannsfeldt, W.B.

1992-01-01

IGUN is a program for the simulation of positive ion extraction from plasmas. It is based on the well known program EGUN for the calculation of electron and ion trajectories in electron guns and lenses. The mathematical treatment of the plasma sheath is based on a simple analytical model, which provides a numerically stable calculation of the sheath potentials. In contrast to other ion extraction programs, IGUN is able to determine the extracted ion current in succeeding cycles of iteration by itself. However, it is also possible to set values of current, plasma density, or ion current density. Either axisymmetric or rectangular coordinates can be used, including axisymmetric or transverse magnetic fields

igun - A program for the simulation of positive ion extraction including magnetic fields

Science.gov (United States)

Becker, R.; Herrmannsfeldt, W. B.

1992-04-01

igun is a program for the simulation of positive ion extraction from plasmas. It is based on the well known program egun for the calculation of electron and ion trajectories in electron guns and lenses. The mathematical treatment of the plasma sheath is based on a simple analytical model, which provides a numerically stable calculation of the sheath potentials. In contrast to other ion extraction programs, igun is able to determine the extracted ion current in succeeding cycles of iteration by itself. However, it is also possible to set values of current, plasma density, or ion current density. Either axisymmetric or rectangular coordinates can be used, including axisymmetric or transverse magnetic fields.

Evaluation of complexing agents and column temperature in ion chromatographic separation of alkali metals, alkaline earth metals and transition metals ion

International Nuclear Information System (INIS)

Kelkar, Anoop; Pandey, Ashish; Name, Anil B.; Das, D.K.; Behere, P.G.; Mohd Afzal

2015-01-01

The aim of ion chromatography method development is the resolution of all metal ions of interests. Resolution can be improved by changing the selectivity. Selectivity in chromatography can be altered by changes in mobile phase (eg eluent type, eluent strength) or through changes in stationary phase. Temperature has been used in altering the selectivity of particularly in reversed phase liquid chromatography and ion exchange chromatography. Present paper describe the retention behaviour of alkali metals, alkaline earth metals and transition metal ions on a silica based carboxylate function group containing analyte column. Alkali metals, alkaline earth metals and transition metal ions were detected by ion conductivity and UV-VIS detectors respectively

Ion-driven deuterium permeation through tungsten at high temperatures

Science.gov (United States)

Gasparyan, Yu. M.; Golubeva, A. V.; Mayer, M.; Pisarev, A. A.; Roth, J.

2009-06-01

The ion-driven permeation (IDP) through 50 μm thick pure tungsten foils was measured in the temperature range of 823-923 K during irradiation by 200 eV/D + ion beam with a flux of 10 17-10 18 D/m 2s. Gas driven permeation (GDP) from the deuterium background gas was observed as well. Calculations using both the analytical formula for the diffusion limited regime (DLR) and the TMAP 7 code gave good agreement with the experimental data. Defects with a detrapping energy of (2.05 ± 0.15) eV were found to limit the permeation lag time in our experimental conditions.

Ion-driven deuterium permeation through tungsten at high temperatures

Energy Technology Data Exchange (ETDEWEB)

Gasparyan, Yu.M., E-mail: yury.gasparyan@ipp.mpg.d [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, Boltzmanstrasse 2, D-85748 Garching (Germany); Moscow Engineering and Physics Institute, Kashirskoe sh. 31, Moscow 115409 (Russian Federation); Golubeva, A.V. [RRC ' Kurchatov Institute' , Ac. Kurchatov sq., 1/1, Moscow RU-123182 (Russian Federation); Mayer, M. [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, Boltzmanstrasse 2, D-85748 Garching (Germany); Pisarev, A.A. [Moscow Engineering and Physics Institute, Kashirskoe sh. 31, Moscow 115409 (Russian Federation); Roth, J. [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, Boltzmanstrasse 2, D-85748 Garching (Germany)

2009-06-15

The ion-driven permeation (IDP) through 50 mum thick pure tungsten foils was measured in the temperature range of 823-923 K during irradiation by 200 eV/D{sup +} ion beam with a flux of 10{sup 17}-10{sup 18} D/m{sup 2}s. Gas driven permeation (GDP) from the deuterium background gas was observed as well. Calculations using both the analytical formula for the diffusion limited regime (DLR) and the TMAP 7 code gave good agreement with the experimental data. Defects with a detrapping energy of (2.05 +- 0.15) eV were found to limit the permeation lag time in our experimental conditions.

Ion-driven deuterium permeation through tungsten at high temperatures

International Nuclear Information System (INIS)

Gasparyan, Yu.M.; Golubeva, A.V.; Mayer, M.; Pisarev, A.A.; Roth, J.

2009-01-01

The ion-driven permeation (IDP) through 50 μm thick pure tungsten foils was measured in the temperature range of 823-923 K during irradiation by 200 eV/D + ion beam with a flux of 10 17 -10 18 D/m 2 s. Gas driven permeation (GDP) from the deuterium background gas was observed as well. Calculations using both the analytical formula for the diffusion limited regime (DLR) and the TMAP 7 code gave good agreement with the experimental data. Defects with a detrapping energy of (2.05 ± 0.15) eV were found to limit the permeation lag time in our experimental conditions.

Dependence of ion beam current on position of mobile plate tuner in multi-frequencies microwaves electron cyclotron resonance ion source

International Nuclear Information System (INIS)

Kurisu, Yosuke; Kiriyama, Ryutaro; Takenaka, Tomoya; Nozaki, Dai; Sato, Fuminobu; Kato, Yushi; Iida, Toshiyuki

2012-01-01

We are constructing a tandem-type electron cyclotron resonance ion source (ECRIS). The first stage of this can supply 2.45 GHz and 11-13 GHz microwaves to plasma chamber individually and simultaneously. We optimize the beam current I FC by the mobile plate tuner. The I FC is affected by the position of the mobile plate tuner in the chamber as like a circular cavity resonator. We aim to clarify the relation between the I FC and the ion saturation current in the ECRIS against the position of the mobile plate tuner. We obtained the result that the variation of the plasma density contributes largely to the variation of the I FC when we change the position of the mobile plate tuner.

Ultra-low temperature process by ion shower doping technique for poly-Si TFTs on plastics

International Nuclear Information System (INIS)

Kim, Jong-Man; Lim, Huck; Kim, Do-Young; Jung, Ji-Sim; Kwon, Jang-Yeon; Hong, Wan-Shick; Noguchi, Takashi

2006-01-01

An ion doping process was performed by using a basic ion shower system. After ion doping and subsequent activation of the dopants in the Si film by excimer laser annealing (ELA), we studied the crystallinity of the Si surface using UV-reflectance spectroscopy and the sheet resistance by using 4-point probe measurements. To prevent excessive temperature increase on the plastic substrate during ion shower doping, the plasma shower was applied in a series of short pulses. As a result, dopant ions were efficiently incorporated and were activated into the a-Si film on plastic substrate after ELA. The sheet resistance decreased with increase of actual doping time, which corresponds to the incorporated dose. Also, we confirmed a distinct relationship between the crystallinity and the sheet resistance. This work shows that pulsed ion shower doping is a promising technique for ultra-low-temperature poly-Si TFTs on plastic substrates.

Temperature dependence of ion-beam induced amorphization in α-quartz

International Nuclear Information System (INIS)

Dhar, Sankar; Bolse, Wolfgang; Lieb, Klaus-Peter

1999-01-01

The temperature dependence of the amorphization in α-quartz by Ne-ion bombardment has been investigated using Rutherford Backscattering Spectrometry in channeling geometry (RBS-C). The experimental results show that the critical temperature T c for inhibiting amorphization in quartz is around 940 K. The damage depth profile χ(z,phi) is independent of the temperature and fluence and can be simulated with a power-law function [χ(z,phi)∝(phiF D (z)) 3 ] of the damage energy distribution F D (z). At low irradiation temperature, the critical dose phi c for amorphization is independent of the temperature but it strongly increases at higher temperatures with an activation energy of 0.28 eV and has been explained by out-diffusion model of Morehead and Crowder

Ion Temperature Measurements in the Tore Supra Scrape-Off Layer Using a Retarding Field Analyzer

International Nuclear Information System (INIS)

Kocan, M.; Gunn, J.P.; Pascal, J.Y.; Gauthier, E.

2010-01-01

The retarding field analyzer (RFA) is one of the only widely accepted diagnostics for measuring the ion temperature T i )in the tokamak scrape-off layer. An overview of the outstanding RFA performance over ten years of operation in Tore Supra tokamak is given and the validation of T i measurements is addressed. The RFA measurements in Tore Supra are found to be well reproducible. The ion-to-electron temperature ratio is higher than one at low-to-moderate ion-electron collisionality regime and converges to unity at high collisionality regime. (authors)

A new high-temperature plasma ion source for the TRISTAN ISOL facility

International Nuclear Information System (INIS)

Piotrowski, A.; Gill, R.L.; McDonald, D.C.

1987-01-01

A vigorous program of ion-source development at TRISTAN has led to several types of ion sources that are especially suited to extended operation at a reactor-based ISOL facility. The latest of these is a high-temperature plasma ion source in which a 5-g 235 U target is located in the cathode and can be heated to 2500 0 C. The ion source has a lifetime of >1000 h and produces a wide array of elements, including palladium. Off-line investigations indicate that the source functions primarily in an electron impact mode of ionization and exhibits typical ionization efficiencies of >30% for xenon. (orig.)

A new high-temperature plasma ion source for the TRISTAN ISOL facility

International Nuclear Information System (INIS)

Piotrowski, A.; Gill, R.L.; McDonald, D.C.

1987-01-01

A vigorous program of ion-source development at TRISTAN has led to several types of ion sources that are especially suited to extended operation at a reactor-based ISOL facility. The latest of these is a high-temperature plasma ion source in which a 5-g /sup 235/U target is located in the cathode and can be heated to 2500 0 C. The ion source has a lifetime of > 1000 h and produces a wide array of elements, including palladium. Off-line investigations indicate that the source functions primarily in an electron impact mode of ionization and exhibits typical ionization efficiencies of > 30% for xenon

Control of secondary electrons from ion beam impact using a positive potential electrode

Energy Technology Data Exchange (ETDEWEB)

Crowley, T. P., E-mail: tpcrowley@xanthotechnologies.com; Demers, D. R.; Fimognari, P. J. [Xantho Technologies, LLC, Madison, Wisconsin 53705 (United States)

2016-11-15

Secondary electrons emitted when an ion beam impacts a detector can amplify the ion beam signal, but also introduce errors if electrons from one detector propagate to another. A potassium ion beam and a detector comprised of ten impact wires, four split-plates, and a pair of biased electrodes were used to demonstrate that a low-voltage, positive electrode can be used to maintain the beneficial amplification effect while greatly reducing the error introduced from the electrons traveling between detector elements.

Investigation of reordered (001) Au surfaces by positive ion channeling spectroscopy, LEED and AES

International Nuclear Information System (INIS)

Appleton, B.R.; Noggle, T.S.; Miller, J.W.; Schow, O.E. III; Zehner, D.M.; Jenkins, L.H.; Barrett, J.H.

1974-01-01

As a consequence of the channeling phenomenon of positive ions in single crystals, the yield of ions Rutherford scattered from an oriented single crystal surface is dependent on the density of surface atoms exposed to the incident ion beam. Thus, the positive ion channeling spectroscopy (PICS) technique should provide a useful tool for studying reordered surfaces. This possibility was explored by examining the surfaces of epitaxially grown thin Au single crystals with the combined techniques of LEED-AES and PICS. The LEED and AES investigations showed that when the (001) surface was sputter cleaned in ultra-high vacuum, the normal (1 x 1) symmetry of the (001) surfaces reordered into a structure which gave a complex (5 x 20) LEED pattern. The yield and energy distributions of 1 MeV He ions scattered from the Au surfaces were used to determine the number of effective monolayers contributing to the normal and reordered surfaces. These combined measurements were used to characterize the nature of the reordered surface. The general applicability of the PICS technique for investigations of surface and near surface regions is discussed

Comparison of ion temperature and ion density measured during geomagnetically very quiet conditions on board of the geophysical rocket ''Vertical-6'' with the international reference ionosphere

International Nuclear Information System (INIS)

Bencze, P.; Kovacs, K.; Apathy, I.; Szemerey, I.; Afonin, V.; Bezrukih, V.; Shutte, N.

1980-05-01

Ion temperature and ion density, measured on October 25, 1977 during the flight of the geophyisical rocket ''Vertical-6'' by means of a group of five retarding potential analyzers looking into different directions of space, are compared with the International Reference Ionosphere 1978. The measurements were carried out in a geomagnetically quiet period to a height of 1500 km. The results show that both the ion temperature and the ion density are lower than the values predicted by the Reference Ionosphere, the difference is decreasing with increasing altitude. (author)

Predicted precision of ion temperature and impurity fractional density measurements using the JET collective scattering diagnostic

International Nuclear Information System (INIS)

Orsitto, F.

1992-11-01

In a previous investigation the possibility of measuring the bulk ion temperature was considered in detail, in the context of the proposed Thomson scattering diagnostic for fast ions and alpha particles in the Joint European Torus project. In this report we give an affirmative answer to the question of whether good precision can be obtained in the simultaneous determination of the temperatures and densities of plasma ions from a collective scattering experiment provided some conditions are satisfied. (Author)

Determination of the core temperature of a Li-ion cell during thermal runaway

Science.gov (United States)

Parhizi, M.; Ahmed, M. B.; Jain, A.

2017-12-01

Safety and performance of Li-ion cells is severely affected by thermal runaway where exothermic processes within the cell cause uncontrolled temperature rise, eventually leading to catastrophic failure. Most past experimental papers on thermal runaway only report surface temperature measurement, while the core temperature of the cell remains largely unknown. This paper presents an experimentally validated method based on thermal conduction analysis to determine the core temperature of a Li-ion cell during thermal runaway using surface temperature and chemical kinetics data. Experiments conducted on a thermal test cell show that core temperature computed using this method is in good agreement with independent thermocouple-based measurements in a wide range of experimental conditions. The validated method is used to predict core temperature as a function of time for several previously reported thermal runaway tests. In each case, the predicted peak core temperature is found to be several hundreds of degrees Celsius higher than the measured surface temperature. This shows that surface temperature alone is not sufficient for thermally characterizing the cell during thermal runaway. Besides providing key insights into the fundamental nature of thermal runaway, the ability to determine the core temperature shown here may lead to practical tools for characterizing and mitigating thermal runaway.

Corrosion behavior of low energy, high temperature nitrogen ion ...

Indian Academy of Sciences (India)

Corrosion behavior of low energy, high temperature nitrogen ion-implanted AISI 304 stainless steel. M GHORANNEVISS1, A SHOKOUHY1,∗, M M LARIJANI1,2,. S H HAJI HOSSEINI 1, M YARI1, A ANVARI4, M GHOLIPUR SHAHRAKI1,3,. A H SARI1 and M R HANTEHZADEH1. 1Plasma Physics Research Center, Science ...

Ion permeability of the cytoplasmic membrane limits the maximum growth temperature of bacteria and archaea

NARCIS (Netherlands)

van de Vossenberg, J.L C M; Ubbink-Kok, T.; Elferink, M.G.L.; Driessen, A.J.M.; Konings, W.N

1995-01-01

Protons and sodium ions are the most commonly used coupling ions in energy transduction in bacteria and archaea. At their growth temperature, the permeability of the cytoplasmic membrane of thermophilic bacteria to protons is high compared with that of sodium ions. In some thermophiles, sodium is

Wide-Temperature Electrolytes for Lithium-Ion Batteries

Energy Technology Data Exchange (ETDEWEB)

Li, Qiuyan; Jiao, Shuhong; Luo, Langli; Ding, Michael S.; Zheng, Jianming; Cartmell, Samuel S.; Wang, Chong-Min; Xu, Kang; Zhang, Ji-Guang; Xu, Wu

2017-05-26

Formulating electrolytes with solvents of low freezing points and high dielectric constants is a direct approach to extend the service temperature range of lithium (Li)-ion batteries (LIBs), for which propylene carbonate (PC), ethyl methyl carbonate (EMC), diethyl carbonate (DEC), methyl butyrate (MB) are excellent candidates. In this work, we report such low temperature electrolyte formulations by optimizing the content of ethylene carbonate (EC) in the EC-PC-EMC ternary solvent system with LiPF6 salt and CsPF6 additive. An extended service temperature range from 40°C to 60°C was obtained in LIBs with lithium nickel cobalt aluminum mixed oxide (LiNi0.80Co0.15Al0.05O2, NCA) as cathode and graphite as anode. The discharge capacities at low temperatures and the cycle life at room and elevated temperatures were systematically investigated in association with the ionic conductivity and phase transition behaviors. The most promising electrolyte formulation was identified as 1.0 M LiPF6 in EC-PC-EMC (1:1:8 by wt.) with 0.05 M CsPF6, which was demonstrated in both coin cells of graphite||NCA and 1 Ah pouch cells of graphite||LiNi1/3Mn1/3Co1/3O2. This optimized electrolyte enables excellent wide-temperature performances, as evidenced by the 68% capacity retention at 40C and C/5 rate, and nearly identical stable cycle life at room and elevated temperatures up to 60C.

Anomalous ion thermal transport in hot ion plasmas by the ion temperature gradient mode

International Nuclear Information System (INIS)

Kim, J.Y.; Horton, W.; Coppi, B.

1992-01-01

Experiments show that the observed radial profiles of the ion thermal conductivity χ i have the opposite shapes with those obtained from the ion temperature gradient mode (η i mode) turbulence model by the traditional mixing length estimate. In this work, this radial profile problem is reconsidered with an electromagnetic study of the linear stability of the toroidal η i mode and a new rule for choosing the mixing length. It is first shown that the electromagnetic effect gives a significant stabilizing effect on the toroidal η i mode, and that the observed reduction of χ i (r) in the core region can be explained by this electromagnetic effect. Secondly, in view of earlier numerical simulations showing the transfer of fluctuation energy to larger scales that those for the fastest growth rate, as well as fluctuation measurements indicating longer radial correlation lengths, a new mixing length formula is proposed to explain the radial increase of the χ i . It is shown the new formula fits well the observed χ i (r) profiles in two TFTR supershot discharges and also gives the scaling law in the current and the magnetic field which agrees better with experiment than the conventional formula

Physicochemical, spectroscopic and electrochemical characterization of magnesium ion-conducting, room temperature, ternary molten electrolytes

Science.gov (United States)

Narayanan, N. S. Venkata; Ashok Raj, B. V.; Sampath, S.

Room temperature, magnesium ion-conducting molten electrolytes are prepared using a combination of acetamide, urea and magnesium triflate or magnesium perchlorate. The molten liquids show high ionic conductivity, of the order of mS cm -1 at 298 K. Vibrational spectroscopic studies based on triflate/perchlorate bands reveal that the free ion concentration is higher than that of ion-pairs and aggregates in the melt. Electrochemical reversibility of magnesium deposition and dissolution is demonstrated using cyclic voltammetry and impedance studies. The transport number of Mg 2+ ion determined by means of a combination of d.c. and a.c. techniques is ∼0.40. Preliminary studies on the battery characteristics reveal good capacity for the magnesium rechargeable cell and open up the possibility of using this unique class of acetamide-based room temperature molten electrolytes in secondary magnesium batteries.

Role of positive ions on the surface production of negative ions in a fusion plasma reactor type negative ion source--Insights from a three dimensional particle-in-cell Monte Carlo collisions model

Science.gov (United States)

Fubiani, G.; Boeuf, J. P.

2013-11-01

Results from a 3D self-consistent Particle-In-Cell Monte Carlo Collisions (PIC MCC) model of a high power fusion-type negative ion source are presented for the first time. The model is used to calculate the plasma characteristics of the ITER prototype BATMAN ion source developed in Garching. Special emphasis is put on the production of negative ions on the plasma grid surface. The question of the relative roles of the impact of neutral hydrogen atoms and positive ions on the cesiated grid surface has attracted much attention recently and the 3D PIC MCC model is used to address this question. The results show that the production of negative ions by positive ion impact on the plasma grid is small with respect to the production by atomic hydrogen or deuterium bombardment (less than 10%).

Role of positive ions on the surface production of negative ions in a fusion plasma reactor type negative ion source—Insights from a three dimensional particle-in-cell Monte Carlo collisions model

International Nuclear Information System (INIS)

Fubiani, G.; Boeuf, J. P.

2013-01-01

Results from a 3D self-consistent Particle-In-Cell Monte Carlo Collisions (PIC MCC) model of a high power fusion-type negative ion source are presented for the first time. The model is used to calculate the plasma characteristics of the ITER prototype BATMAN ion source developed in Garching. Special emphasis is put on the production of negative ions on the plasma grid surface. The question of the relative roles of the impact of neutral hydrogen atoms and positive ions on the cesiated grid surface has attracted much attention recently and the 3D PIC MCC model is used to address this question. The results show that the production of negative ions by positive ion impact on the plasma grid is small with respect to the production by atomic hydrogen or deuterium bombardment (less than 10%)

Enhancement in electron and ion temperatures due to solar flares as measured by SROSS-C2 satellite

Directory of Open Access Journals (Sweden)

D. K. Sharma

2004-06-01

Full Text Available The observations on the ionospheric electron and ion temperatures (Te and Ti measured by the RPA payload aboard the SROSS-C2 satellite have been used to study the effect of solar flares on ionospheric heating. The data on solar flare has been obtained from the National Geophysical Data Center (NGDC Boulder, Colorado (USA. It has been found that the electron and ion temperatures have a consistent enhancement during the solar flares on the dayside Earth's ionosphere. The estimated enhancement for the average electron temperature is from 1.3 to 1.9 times whereas for ion temperature it is from 1.2 to 1.4 times to the normal days average temperature. The enhancement of ionospheric temperatures due to solar flares is correlated with the diurnal variation of normal days' ionospheric temperatures. The solar flare does not have any significant effect on the nightside ionosphere. A comparison with the temperature obtained from the IRI-95 model also shows a similar enhancement.

Ion-beam mixing in silicon and germanium at low temperatures

International Nuclear Information System (INIS)

Clark, G.J.; Marwick, A.D.; Poker, D.B.

1982-01-01

Ion-beam mixing of thin marker layers in amorphous silicon and germanium was studied using irradiations with Xe ions at temperatures of 34k and 77k. The marker species, ion energies and doses were: in silicon, markers of Ge and Pt irradiated with 200-keV Xe up to 2.7x10 16 ions cm -2 ; and in germanium, markers of Al and Si bombarded with 295-keV Xe up to 1.63x10 16 ions cm -2 . In silicon, Pt markers were found to broaden at about the same rate at 34k and 77k; and the rate of broadening was similar to that found by other workers when expressed as an efficiency of mixing, i.e., when dependence on ion dose and deposited energy was factored out. However, a Ge marker irradiated at 34k did not broaden from its original thickness. In germanium, markers of both Al and Si were mixed by irradiation at 34k, but at 77k only the Al marker broadened; the Si marker did not. The broadening of the markers is ascribed to ballistic mixing, while the cases where no broadening occurred are explicable if diffusion by a defect mechanism transported displaced marker atoms back to traps near their original sites

Selection and design of ion sources for use at the Holifield radioactive ion beam facility

International Nuclear Information System (INIS)

Alton, G.D.; Haynes, D.L.; Mills, G.D.; Olsen, D.K.

1994-01-01

The Holifield Radioactive Ion Beam Facility now under construction at the Oak Ridge National Laboratory will use the 25 MV tandem accelerator for the acceleration of radioactive ion beams to energies appropriate for research in nuclear physics; negative ion beams are, therefore, required for injection into the tandem accelerator. Because charge exchange is an efficient means for converting initially positive ion beams to negative ion beams, both positive and negative ion sources are viable options for use at the facility. The choice of the type of ion source will depend on the overall efficiency for generating the radioactive species of interest. Although direct-extraction negative ion sources are clearly desirable, the ion formation efficiencies are often too low for practical consideration; for this situation, positive ion sources, in combination with charge exchange, are the logical choice. The high-temperature version of the CERN-ISOLDE positive ion source has been selected and a modified version of the source designed and fabricated for initial use at the facility because of its low emittance, relatively high ionization efficiencies, and species versatility, and because it has been engineered for remote installation, removal, and servicing as required for safe handling in a high-radiation-level ISOL facility. The source will be primarily used to generate ion beams from elements with intermediate to low electron affinities. Prototype plasma-sputter negative ion sources and negative surface-ionization sources are under design consideration for generating radioactive ion beams from high-electron-affinity elements. The design features of these sources and expected efficiencies and beam qualities (emittances) will be described in this report

Measurement of the electron and ion temperatures by the x-ray imaging crystal spectrometer on joint Texas experimental tokamak

Energy Technology Data Exchange (ETDEWEB)

Yan, W.; Chen, Z. Y., E-mail: zychen@hust.edu.cn; Huang, D. W.; Tong, R. H.; Wang, S. Y.; Wei, Y. N.; Ma, T. K.; Zhuang, G. [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan (China); Jin, W. [Center of Interface Dynamics for Sustainability, China Academy of Engineering Physics, Chengdu, Sichuan 610200 (China); Lee, S. G. [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of); Shi, Y. J. [Department of Nuclear Engineering, Seoul National University, Seoul 08826 (Korea, Republic of)

2016-11-15

An x-ray imaging crystal spectrometer has been developed on joint Texas experimental tokamak for the measurement of electron and ion temperatures from the K{sub α} spectra of helium-like argon and its satellite lines. A two-dimensional multi-wire proportional counter has been applied to detect the spectra. The electron and ion temperatures have been obtained from the Voigt fitting with the spectra of helium-like argon ions. The profiles of electron and ion temperatures show the dependence on electron density in ohmic plasmas.

Study of some ion exchange minerals which can be used in water at high temperature

International Nuclear Information System (INIS)

Hure, J.; Platzer, R.; Bittel, R.; Wey, R.

1958-01-01

The study of the use of ion exchangers at high temperature has been carried out mainly with a view to purifying water in reactor circuits. The advantages of keeping high resistivity (from many hundreds to a few million ohm-cm) water within a reactor circuit are known; the decreased corrosion reduction in the amount of radiolysis, decreased radioactivity in the circuits and piping, the elements other than those forming water which are carried with the water usually becoming radioactive as they pass through the reactor. If the water circulation takes place at temperatures less than 75 deg. C continuous purification can be easily carried out by using organic ion exchange resins in agitated beds. However at higher temperatures particularly those above 100 deg. C it is not possible to use these media because of the rapid degradation of the high polymers used. Also the action of the radiation, for example that emanating from the products fixed on the ion exchange media permanently destroys the organic chains making up the skeleton of the resins. We have therefore sought after other compounds which are efficient demineralizer, but which have a structure such that high temperature and radiation do not bring about deterioration. We have especially investigated three main types: - natural ion exchangers having an inorganic structure (montmorillonite type clays); - natural inorganic compounds which have been treated to give them ion exchange properties (activated carbons); - synthetic inorganic compounds (salts having a low solubility such as zirconium and thorium phosphates and hydroxides). In this research we have endeavoured to obtain products which are stable in the presence of water at high temperatures, insoluble and not broken down into fine particles (that is to say not polluting the high resistivity water) and which are capable of giving up H + or OH - ions in exchange for the ions contained in the water or at least capable of forming insoluble compounds with these

Prototyping of beam position monitor for medium energy beam transport section of RAON heavy ion accelerator

Energy Technology Data Exchange (ETDEWEB)

Jang, Hyojae, E-mail: lkcom@ibs.re.kr; Jin, Hyunchang; Jang, Ji-Ho; Hong, In-Seok [Rare Isotope Science Project, Institute for Basic Science, Daejeon (Korea, Republic of)

2016-02-15

A heavy ion accelerator, RAON is going to be built by Rare Isotope Science Project in Korea. Its target is to accelerate various stable ions such as uranium, proton, and xenon from electron cyclotron resonance ion source and some rare isotopes from isotope separation on-line. The beam shaping, charge selection, and modulation should be applied to the ions from these ion sources because RAON adopts a superconducting linear accelerator structure for beam acceleration. For such treatment, low energy beam transport, radio frequency quadrupole, and medium energy beam transport (MEBT) will be installed in injector part of RAON accelerator. Recently, development of a prototype of stripline beam position monitor (BPM) to measure the position of ion beams in MEBT section is under way. In this presentation, design of stripline, electromagnetic (EM) simulation results, and RF measurement test results obtained from the prototyped BPM will be described.

Interactions between electrons in the field of a positive ion

International Nuclear Information System (INIS)

Heideman, A.G.M.; Eck, J. van.

1976-01-01

Recent studies on the (auto)ionization of atoms by means of electron-atom collisions reveal the existence of phenomena probably brought about by post-collision interactions in the vicinity of a positive ion. In this article, a review of the subject is given in relation to the research program of the Utrecht atomic physics group

Lithium-ion battery structure that self-heats at low temperatures

Science.gov (United States)

Wang, Chao-Yang; Zhang, Guangsheng; Ge, Shanhai; Xu, Terrence; Ji, Yan; Yang, Xiao-Guang; Leng, Yongjun

2016-01-01

Lithium-ion batteries suffer severe power loss at temperatures below zero degrees Celsius, limiting their use in applications such as electric cars in cold climates and high-altitude drones. The practical consequences of such power loss are the need for larger, more expensive battery packs to perform engine cold cranking, slow charging in cold weather, restricted regenerative braking, and reduction of vehicle cruise range by as much as 40 per cent. Previous attempts to improve the low-temperature performance of lithium-ion batteries have focused on developing additives to improve the low-temperature behaviour of electrolytes, and on externally heating and insulating the cells. Here we report a lithium-ion battery structure, the ‘all-climate battery’ cell, that heats itself up from below zero degrees Celsius without requiring external heating devices or electrolyte additives. The self-heating mechanism creates an electrochemical interface that is favourable for high discharge/charge power. We show that the internal warm-up of such a cell to zero degrees Celsius occurs within 20 seconds at minus 20 degrees Celsius and within 30 seconds at minus 30 degrees Celsius, consuming only 3.8 per cent and 5.5 per cent of cell capacity, respectively. The self-heated all-climate battery cell yields a discharge/regeneration power of 1,061/1,425 watts per kilogram at a 50 per cent state of charge and at minus 30 degrees Celsius, delivering 6.4-12.3 times the power of state-of-the-art lithium-ion cells. We expect the all-climate battery to enable engine stop-start technology capable of saving 5-10 per cent of the fuel for 80 million new vehicles manufactured every year. Given that only a small fraction of the battery energy is used for self-heating, we envisage that the all-climate battery cell may also prove useful for plug-in electric vehicles, robotics and space exploration applications.

Lithium-ion battery structure that self-heats at low temperatures.

Science.gov (United States)

Wang, Chao-Yang; Zhang, Guangsheng; Ge, Shanhai; Xu, Terrence; Ji, Yan; Yang, Xiao-Guang; Leng, Yongjun

2016-01-28

Lithium-ion batteries suffer severe power loss at temperatures below zero degrees Celsius, limiting their use in applications such as electric cars in cold climates and high-altitude drones. The practical consequences of such power loss are the need for larger, more expensive battery packs to perform engine cold cranking, slow charging in cold weather, restricted regenerative braking, and reduction of vehicle cruise range by as much as 40 per cent. Previous attempts to improve the low-temperature performance of lithium-ion batteries have focused on developing additives to improve the low-temperature behaviour of electrolytes, and on externally heating and insulating the cells. Here we report a lithium-ion battery structure, the 'all-climate battery' cell, that heats itself up from below zero degrees Celsius without requiring external heating devices or electrolyte additives. The self-heating mechanism creates an electrochemical interface that is favourable for high discharge/charge power. We show that the internal warm-up of such a cell to zero degrees Celsius occurs within 20 seconds at minus 20 degrees Celsius and within 30 seconds at minus 30 degrees Celsius, consuming only 3.8 per cent and 5.5 per cent of cell capacity, respectively. The self-heated all-climate battery cell yields a discharge/regeneration power of 1,061/1,425 watts per kilogram at a 50 per cent state of charge and at minus 30 degrees Celsius, delivering 6.4-12.3 times the power of state-of-the-art lithium-ion cells. We expect the all-climate battery to enable engine stop-start technology capable of saving 5-10 per cent of the fuel for 80 million new vehicles manufactured every year. Given that only a small fraction of the battery energy is used for self-heating, we envisage that the all-climate battery cell may also prove useful for plug-in electric vehicles, robotics and space exploration applications.

First operational tests of the positive-ion injector for ATLAS

International Nuclear Information System (INIS)

Bollinger, L.M.; Den Hartog, P.K.; Pardo, R.C.

1989-01-01

This paper summarizes the status and first operational experience with the positive-ion injector for ATLAS. The new injector consists of an ECR ion source on a 350-kV platform, followed by a superconducting injector linac of a new kind. In Phase I of this project, the ECR source, voltage platform, bunching system, beam-transport system, and a 3-MV injector linac were completed and tested in early 1989 by a successful acceleration of an 40 Ar 12+ beam. Most of the new system operated as planned, and the longitudinal emittance of the 36-MeV beam out of the injector was measured to be only 5 π keV-ns, much smaller than the emittance for the present tandem injector. When completed in 1990, the final injector linac will be enlarged to 12 MV, enough to allow the original ATLAS linac to accelerate uranium ions up to 8 MeV/u. 8 refs., 2 figs

Superconducting low-velocity linac for the Argonne positive-ion injector

International Nuclear Information System (INIS)

Shepard, K.W.; Markovich, P.K.; Zinkann, G.P.; Clifft, B.; Benaroya, R.

1989-01-01

A low-velocity superconducting linac has been developed as part of a positive-ion injector system, which is replacing a 9 MV tandem as the injector for the ATLAS accelerator. The linac consists of an independently phased array of resonators, and is designed to accelerate various ions over a velocity range .008 < v/c < .06. The resonator array is formed of four different types of superconducting interdigital structures. The linac is being constructed in three phases, each of which will cover the full velocity range. Successive phases will increase the total accelerating potential and permit heavier ions to be accelerated. Assembly of the first phase was completed in early 1989. In initial tests with beam, a five-resonator array provided approximately 3.5 MV of accelerating potential and operated without difficulty for several hundred hours. The second phase is scheduled for completion in late 1989, and will increase the accelerating potential to more than 8 MV. 5 refs., 2 figs., 1 tab

Superconducting low-velocity linac for the Argonne positive-ion injector

Energy Technology Data Exchange (ETDEWEB)

Shepard, K.W.; Markovich, P.K.; Zinkann, G.P.; Clifft, B.; Benaroya, R.

1989-01-01

A low-velocity superconducting linac has been developed as part of a positive-ion injector system, which is replacing a 9 MV tandem as the injector for the ATLAS accelerator. The linac consists of an independently phased array of resonators, and is designed to accelerate various ions over a velocity range .008 < v/c < .06. The resonator array is formed of four different types of superconducting interdigital structures. The linac is being constructed in three phases, each of which will cover the full velocity range. Successive phases will increase the total accelerating potential and permit heavier ions to be accelerated. Assembly of the first phase was completed in early 1989. In initial tests with beam, a five-resonator array provided approximately 3.5 MV of accelerating potential and operated without difficulty for several hundred hours. The second phase is scheduled for completion in late 1989, and will increase the accelerating potential to more than 8 MV. 5 refs., 2 figs., 1 tab.

First operational tests of the positive-ion injector for ATLAS

Energy Technology Data Exchange (ETDEWEB)

Bollinger, L.M.; Den Hartog, P.K.; Pardo, R.C.; Shepard, K.W.; Benaroya, R.; Billquist, P.J.; Clifft, B.E.; Markovich, P.; Munson, F.H. Jr.; Nixon, J.M.

1989-01-01

This paper summarizes the status and first operational experience with the positive-ion injector for ATLAS. The new injector consists of an ECR ion source on a 350-kV platform, followed by a superconducting injector linac of a new kind. In Phase I of this project, the ECR source, voltage platform, bunching system, beam-transport system, and a 3-MV injector linac were completed and tested in early 1989 by a successful acceleration of an /sup 40/Ar/sup 12 +/ beam. Most of the new system operated as planned, and the longitudinal emittance of the 36-MeV beam out of the injector was measured to be only 5 ..pi.. keV-ns, much smaller than the emittance for the present tandem injector. When completed in 1990, the final injector linac will be enlarged to 12 MV, enough to allow the original ATLAS linac to accelerate uranium ions up to 8 MeV/u. 8 refs., 2 figs.

Ion-acoustic Gardner solitons in a four-component nonextensive multi-ion plasma

Energy Technology Data Exchange (ETDEWEB)

Jannat, N., E-mail: nilimajannat74@gmail.com; Ferdousi, M.; Mamun, A. A. [Jahangirnagar University, Department of Physics (Bangladesh)

2016-07-15

The nonlinear propagation of ion-acoustic (IA) solitary waves (SWs) in a four-component non-extensive multi-ion plasma system containing inertial positively charged light ions, negatively charged heavy ions, as well as noninertial nonextensive electrons and positrons has been theoretically investigated. The reductive perturbation method has been employed to derive the nonlinear equations, namely, Korteweg−deVries (KdV), modified KdV (mKdV), and Gardner equations. The basic features (viz. polarity, amplitude, width, etc.) of Gardner solitons are found to exist beyond the KdV limit and these IA Gardner solitons are qualitatively different from the KdV and mKdV solitons. It is observed that the basic features of IA SWs are modified by various plasma parameters (viz. electron and positron nonextensivity, electron number density to ion number density, and electron temperature to positron temperature, etc.) of the considered plasma system. The results obtained from this theoretical investigation may be useful in understanding the basic features of IA SWs propagating in both space and laboratory plasmas.

Ion-acoustic Gardner solitons in a four-component nonextensive multi-ion plasma

International Nuclear Information System (INIS)

Jannat, N.; Ferdousi, M.; Mamun, A. A.

2016-01-01

The nonlinear propagation of ion-acoustic (IA) solitary waves (SWs) in a four-component non-extensive multi-ion plasma system containing inertial positively charged light ions, negatively charged heavy ions, as well as noninertial nonextensive electrons and positrons has been theoretically investigated. The reductive perturbation method has been employed to derive the nonlinear equations, namely, Korteweg−deVries (KdV), modified KdV (mKdV), and Gardner equations. The basic features (viz. polarity, amplitude, width, etc.) of Gardner solitons are found to exist beyond the KdV limit and these IA Gardner solitons are qualitatively different from the KdV and mKdV solitons. It is observed that the basic features of IA SWs are modified by various plasma parameters (viz. electron and positron nonextensivity, electron number density to ion number density, and electron temperature to positron temperature, etc.) of the considered plasma system. The results obtained from this theoretical investigation may be useful in understanding the basic features of IA SWs propagating in both space and laboratory plasmas.

Temperature-dependent surface modification of Ta due to high-flux, low-energy He+ ion irradiation

International Nuclear Information System (INIS)

Novakowski, T.J.; Tripathi, J.K.; Hassanein, A.

2015-01-01

This work examines the response of Tantalum (Ta) as a potential candidate for plasma-facing components (PFCs) in future nuclear fusion reactors. Tantalum samples were exposed to high-flux, low-energy He + ion irradiation at different temperatures in the range of 823–1223 K. The samples were irradiated at normal incidence with 100 eV He + ions at constant flux of 1.2 × 10 21 ions m −2  s −1 to a total fluence of 4.3 × 10 24 ions m −2 . An additional Ta sample was also irradiated at 1023 K using a higher ion fluence of 1.7 × 10 25 ions m −2 (at the same flux of 1.2 × 10 21 ions m −2  s −1 ), to confirm the possibility of fuzz formation at higher fluence. This higher fluence was chosen to roughly correspond to the lower fluence threshold of fuzz formation in Tungsten (W). Surface morphology was characterized with a combination of field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). These results demonstrate that the main mode of surface damage is pinholes with an average size of ∼70 nm 2 for all temperatures. However, significantly larger pinholes are observed at elevated temperatures (1123 and 1223 K) resulting from the agglomeration of smaller pinholes. Ex situ X-ray photoelectron spectroscopy (XPS) provides information about the oxidation characteristics of irradiated surfaces, showing minimal exfoliation of the irradiated Ta surface. Additionally, optical reflectivity measurements are performed to further characterize radiation damage on Ta samples, showing gradual reductions in the optical reflectivity as a function of temperature.

Computer Simulation Studies of Ion Channels at High Temperatures

Science.gov (United States)

Song, Hyun Deok

The gramicidin channel is the smallest known biological ion channel, and it exhibits cation selectivity. Recently, Dr. John Cuppoletti's group at the University of Cincinnati showed that the gramicidin channel can function at high temperatures (360 ˜ 380K) with significant currents. This finding may have significant implications for fuel cell technology. In this thesis, we have examined the gramicidin channel at 300K, 330K, and 360K by computer simulation. We have investigated how the temperature affects the current and differences in magnitude of free energy between the two gramicidin forms, the helical dimer (HD) and the double helix (DH). A slight decrease of the free energy barrier inside the gramicidin channel and increased diffusion at high temperatures result in an increase of current. An applied external field of 0.2V/nm along the membrane normal results in directly observable ion transport across the channels at high temperatures for both HD and DH forms. We found that higher temperatures also affect the probability distribution of hydrogen bonds, the bending angle, the distance between dimers, and the size of the pore radius for the helical dimer structure. These findings may be related to the gating of the gramicidin channel. Methanococcus jannaschii (MJ) is a methane-producing thermophile, which was discovered at a depth of 2600m in a Pacific Ocean vent in 1983. It has the ability to thrive at high temperatures and high pressures, which are unfavorable for most life forms. There have been some experiments to study its stability under extreme conditions, but still the origin of the stability of MJ is not exactly known. MJ0305 is the chloride channel protein from the thermophile MJ. After generating a structure of MJ0305 by homology modeling based on the Ecoli ClC templates, we examined the thermal stability, and the network stability from the change of network entropy calculated from the adjacency matrices of the protein. High temperatures increase the

Electron-Stimulated Desorption of Positive Ions from Methanol Adsorbed on a Solid Ar Substrate

Science.gov (United States)

Kawanowa, H.; Hanatani, K.; Gotoh, Y.; Souda, R.

Electron-stimulated desorption (ESD) of positive ions from weakly physisorbed molecules has been investigated. From methanol adsorbed on a solid Ar substrate, the protonated cluster ions of the type H+(CH3OH)n (n = 1 - 4) are emitted, together with the fragment ions such as CHn+ (n = 0 - 3), H3O+, CHO+, CH3O+, etc. The yields of these ions are markedly enhanced at the smallest coverage and decay steeply with increasing coverage. Coulomb explosion between valence holes confined in adsorbed nanoclusters is responsible for the enhanced ion yields. Very few ions except for H+ are emitted from a thick layer as well as nanoclusters adsorbed directly on a metal substrate due to the delocalization of valence holes.

Electron impact excitation of positive ions calculated in the Coulomb-Born approximation

International Nuclear Information System (INIS)

Nakazaki, Shinobu; Hashino, Tasuke

1979-08-01

Theoretical results on the electron impact excitation of positive ions are surveyed through the end of 1978. As a guide to the available data, a list of references is made. The list shows ion species, transitions, energy range and methods of calculation for the respective data. Based on the literature survey, the validity of the Coulomb-Born approximation is investigated. Comparisons with the results of the close-coupling and the distorted-wave methods are briefly summarized. (author)

Generalized Lenard-Balescu calculations of electron-ion temperature relaxation in beryllium plasma.

Science.gov (United States)

Fu, Zhen-Guo; Wang, Zhigang; Li, Da-Fang; Kang, Wei; Zhang, Ping

2015-09-01

The problem of electron-ion temperature relaxation in beryllium plasma at various densities (0.185-18.5g/cm^{3}) and temperatures [(1.0-8)×10^{3} eV] is investigated by using the generalized Lenard-Balescu theory. We consider the correlation effects between electrons and ions via classical and quantum static local field corrections. The numerical results show that the electron-ion pair distribution function at the origin approaches the maximum when the electron-electron coupling parameter equals unity. The classical result of the Coulomb logarithm is in agreement with the quantum result in both the weak (Γ_{ee}1) electron-electron coupling ranges, whereas it deviates from the quantum result at intermediate values of the coupling parameter (10^{-2}Coulomb logarithm will decrease and the corresponding relaxation rate ν_{ie} will increase. In addition, a simple fitting law ν_{ie}/ν_{ie}^{(0)}=a(ρ_{Be}/ρ_{0})^{b} is determined, where ν_{ie}^{(0)} is the relaxation rate corresponding to the normal metal density of Be and ρ_{0}, a, and b are the fitting parameters related to the temperature and the degree of ionization 〈Z〉 of the system. Our results are expected to be useful for future inertial confinement fusion experiments involving Be plasma.

Modeling Temperature Development of Li-Ion Battery Packs in Hybrid Refuse Truck Operating at Different Ambient Conditions

DEFF Research Database (Denmark)

Coman, Paul Tiberiu; Veje, Christian

2014-01-01

This paper presents a dynamic model for simulating the heat dissipation and the impact of Phase Change Materials (PCMs) on the peak temperature in Lithium-ion batteries during discharging operation of a hybrid truck under different ambient temperatures.......This paper presents a dynamic model for simulating the heat dissipation and the impact of Phase Change Materials (PCMs) on the peak temperature in Lithium-ion batteries during discharging operation of a hybrid truck under different ambient temperatures....

Observation of refraction and convergence of ion acoustic waves in a plasma with a temperature gradient

International Nuclear Information System (INIS)

Nishida, Y.; Hirose, A.

1977-01-01

The refraction and convergence of ion acoustic waves are experimentally investigated in a magnetized plasma with an electron temperature gradient. When ion acoustic waves are launched parallel to the field lines the waves converge toward the interior of the plasma column where the electron temperature is lower, in good agreement with theoretical prediction. Wave interference is also observed. (author)

Temperature dependent power capability estimation of lithium-ion batteries for hybrid electric vehicles

International Nuclear Information System (INIS)

Zheng, Fangdan; Jiang, Jiuchun; Sun, Bingxiang; Zhang, Weige; Pecht, Michael

2016-01-01

The power capability of lithium-ion batteries affects the safety and reliability of hybrid electric vehicles and the estimate of power by battery management systems provides operating information for drivers. In this paper, lithium ion manganese oxide batteries are studied to illustrate the temperature dependency of power capability and an operating map of power capability is presented. Both parametric and non-parametric models are established in conditions of temperature, state of charge, and cell resistance to estimate the power capability. Six cells were tested and used for model development, training, and validation. Three samples underwent hybrid pulse power characterization tests at varied temperatures and were used for model parameter identification and model training. The other three were used for model validation. By comparison, the mean absolute error of the parametric model is about 29 W, and that of the non-parametric model is around 20 W. The mean relative errors of two models are 0.076 and 0.397, respectively. The parametric model has a higher accuracy in low temperature and state of charge conditions, while the non-parametric model has better estimation result in high temperature and state of charge conditions. Thus, two models can be utilized together to achieve a higher accuracy of power capability estimation. - Highlights: • The temperature dependency of power capability of lithium-ion battery is investigated. • The parametric and non-parametric power capability estimation models are proposed. • An exponential function is put forward to compensate the effects of temperature. • A comparative study on the accuracy of two models using statistical metrics is presented.

Accelerator mass spectrometry of 41Ca with a positive-ion source and the UNILAC accelerator

International Nuclear Information System (INIS)

Steinhof, A.; Henning, W.; Mueller, M.; Roeckl, E.; Schuell, D.; Korschinek, G.; Nolte, E.; Paul, M.

1987-06-01

We have made first tests investigating the performance characteristics of the UNILAC accelerator system at GSI, in order to explore the sensitivity achievable in accelerator mass spectrometry (AMS) of 41 Ca with high-current positive-ion sources. Positively charged Ca 3+ ions of up to about 100 micro-amperes electrical current were injected from a penning-sputter source and, after further stripping to Ca 9+ , accelerated to 14.3 MeV/nucleon. The combination of velocity-focussing accelerator and magnetic ion-beam transport system completely eliminated background from the other calcium isotopes. Full-stripping and detection of 41 Ca 20+ ions with a magnetic spectrograph provides separation from isobaric 41 K and, at present, a level of sensitivity of 41 Ca/Ca ≅ 2x10 -15 . Future improvements and implications for dating of Pleistoscene samples will be discussed. (orig.)

High-temperature oxidation of ion-implanted tantalum

International Nuclear Information System (INIS)

Kaufmann, E.N.; Musket, R.G.; Truhan, J.J.; Grabowski, K.S.; Singer, I.L.; Gossett, C.R.

1982-01-01

The oxidation of ion-implanted Ta in two different high temperature regimes has been studied. Oxidations were carried out at 500 0 C in Ar/O 2 mixtures, where oxide growth is known to follow a parabolic rate law in initial stages, and at 1000 0 C in pure O 2 , where a linear-rate behavior obtains. Implanted species include Al, Ce, Cr, Li, Si and Zr at fluences of the order of 10 17 /cm 2 . Oxidized samples were studied using Rutherford backscattering, nuclear reaction analysis, Auger spectroscopy, secondary-ion mass spectroscopy, x-ray diffraction and optical microscopy. Significant differences among the specimens were noted after the milder 500 0 C treatment, specifically, in the amount of oxide formed, the degree of oxygen dissolution in the metal beneath the oxide, and in the redistribution behavior of the implanted solutes. Under the severe 1000 0 C treatment, indications of different solute distributions and of different optical features were found, whereas overall oxidation rate appeared to be unaffected by the presence of the solute. 7 figures

Modification of embedded Cu nanoparticles: Ion irradiation at room temperature

International Nuclear Information System (INIS)

Johannessen, B.; Kluth, P.; Giulian, R.; Araujo, L.L.; Llewellyn, D.J.; Foran, G.J.; Cookson, D.J.; Ridgway, M.C.

2007-01-01

Cu nanoparticles (NPs) with an average diameter of ∼25 A were synthesized in SiO 2 by ion implantation and thermal annealing. Subsequently, the NPs were exposed to ion irradiation at room temperature simultaneously with a bulk Cu reference film. The ion species/energy was varied to achieve different values for the nuclear energy loss. The short-range atomic structure and average NP diameter were measured by means of extended X-ray absorption fine structure spectroscopy and small angle X-ray scattering, respectively. Transmission electron microscopy yielded complementary results. The short-range order of the Cu films remained unchanged consistent with the high regeneration rate of bulk elemental metals. For the NP samples it was found that increasing nuclear energy loss yielded gradual dissolution of NPs. Furthermore, an increased structural disorder was observed for the residual NPs

Low temperature magnetron sputter deposition of polycrystalline silicon thin films using high flux ion bombardment

International Nuclear Information System (INIS)

Gerbi, Jennifer E.; Abelson, John R.

2007-01-01

We demonstrate that the microstructure of polycrystalline silicon thin films depends strongly on the flux of low energy ions that bombard the growth surface during magnetron sputter deposition. The deposition system is equipped with external electromagnetic coils which, through the unbalanced magnetron effect, provide direct control of the ion flux independent of the ion energy. We report the influence of low energy ( + on the low temperature ( + ions to silicon neutrals (J + /J 0 ) during growth by an order of magnitude (from 3 to 30) enables the direct nucleation of polycrystalline Si on glass and SiO 2 coated Si at temperatures below 400 degree sign C. We discuss possible mechanisms for this enhancement of crystalline microstructure, including the roles of enhanced adatom mobility and the formation of shallow, mobile defects

Coupling analysis of the target temperature and thermal stress due to pulsed ion beam

International Nuclear Information System (INIS)

Yan Jie; Liu Meng; Lin Jufang; An Li; Long Xinggui

2013-01-01

Background: Target temperature has an important effect on the target life for the sealed neutron generator without cooling system. Purpose: To carry out the thermal-mechanical coupling analysis of the film-substrate target bombarded by the pulsed ion beam. Methods: The indirect coupling Finite Element Method (FEM) with a 2-dimensional time-space Gaussian axisymmetric power density as heat source was used to simulate the target temperature and thermal stress fields. Results: The effects of the target temperature and thermal stress fields under difference pulse widths and beam sizes were analyzed in terms of the FEM results. Conclusions: Combining with the temperature requirement and the thermal stress inducing film thermal mechanical destruction effect of the sealed neutron generator film-substrate targets, an optimized pulsed ion beam work status was proposed. (authors)

Combined effects of water temperature and copper ion concentration on catalase activity in Crassostrea ariakensis

Science.gov (United States)

Wang, Hui; Yang, Hongshuai; Liu, Jiahui; Li, Yanhong; Liu, Zhigang

2015-07-01

A central composite experimental design and response surface method were used to investigate the combined effects of water temperature (18-34°C) and copper ion concentration (0.1-1.5 mg/L) on the catalase (CAT) activity in the digestive gland of Crassostrea ariakensis. The results showed that the linear effects of temperature were significant ( P0.05), and the quadratic effects of copper ion concentration were significant ( P0.05), and the effect of temperature was greater than that of copper ion concentration. A model equation of CAT enzyme activity in the digestive gland of C. ariakensis toward the two factors of interest was established, with R 2, Adj. R 2 and Pred. R 2 values as high as 0.943 7, 0.887 3 and 0.838 5, respectively. These findings suggested that the goodness of fit to experimental data and predictive capability of the model were satisfactory, and could be practically applied for prediction under the conditions of the study. Overall, the results suggest that the simultaneous variation of temperature and copper ion concentration alters the activity of the antioxidant enzyme CAT by modulating active oxygen species metabolism, which may be utilized as a biomarker to detect the effects of copper pollution.

Positioning of self-assembled InAs quantum dots by focused ion beam implantation

International Nuclear Information System (INIS)

Mehta, M.

2007-01-01

Self-assembled quantum dots (QDs) are envisioned as building blocks for realization of novel nanoelectronic devices, for which the site-selective growth is highly desirable. This thesis presents a successful route toward selective positioning of self-assembled InAs QDs on patterned GaAs surface by combination of in situ focused ion beam (FIB) implantation and molecular beam epitaxy (MBE) technology. First, a buffer layer of GaAs was grown by MBE before a square array of holes with a pitch of 1-2 μm was fabricated by FIB implantation of Ga and In, ions respectively. Later, an in-situ annealing step followed by InAs deposition was performed. The InAs QDs were preferentially formed in the holes generated by FIB. The influence of ion dose, annealing parameters and InAs amount was investigated in this work. With optimized parameters, more than 50 % single dot occupancy per hole is achieved. Furthermore, the photoluminescence spectra from positioned QDs confirm their good optical quality. (orig.)

Enhancement in electron and ion temperatures due to solar flares as measured by SROSS-C2 satellite

Directory of Open Access Journals (Sweden)

D. K. Sharma

2004-06-01

Full Text Available The observations on the ionospheric electron and ion temperatures (T_e and T_i measured by the RPA payload aboard the SROSS-C2 satellite have been used to study the effect of solar flares on ionospheric heating. The data on solar flare has been obtained from the National Geophysical Data Center (NGDC Boulder, Colorado (USA. It has been found that the electron and ion temperatures have a consistent enhancement during the solar flares on the dayside Earth's ionosphere. The estimated enhancement for the average electron temperature is from 1.3 to 1.9 times whereas for ion temperature it is from 1.2 to 1.4 times to the normal days average temperature. The enhancement of ionospheric temperatures due to solar flares is correlated with the diurnal variation of normal days' ionospheric temperatures. The solar flare does not have any significant effect on the nightside ionosphere. A comparison with the temperature obtained from the IRI-95 model also shows a similar enhancement.

Surface temperature measurements for ion-bombarded Si and GaAs at 1.0 to 2.0 MeV

International Nuclear Information System (INIS)

Lowe, L.F.; Kennedy, J.K.; Davies, D.E.; Deane, M.L.; Eyges, L.J.

1975-01-01

Surface temperatures of ion-bombarded silicon and gallium arsenide have been measured using an infrared detector. Ion beams of N + , N + 2 , O + , O + 2 , C + , CO + , and H + were used at energies from 1--2.0 MeV and at current densities up to 12 μAcenter-dotcm/sup -2/. No temperature dependence was found on ion species, energy, or current. The change in temperature depended only on beam power, target material, and sample mounting technique. With proper mounting temperature increases of 20 degreeC for silicon and 65 degreeC for gallium arsenide were observed for a beam power density of 1.0 Wcenter-dotcm/sup -2/

Ohmic ion temperature and thermal diffusivity profiles from the JET neutron emission profile monitor

Energy Technology Data Exchange (ETDEWEB)

Esposito, B. (ENEA, Frascati (Italy). Centro Ricerche Energia); Marcus, F.B.; Conroy, S.; Jarvis, O.N.; Loughlin, M.J.; Sadler, G.; Belle, P. van (Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking); Adams, J.M.; Watkins, N. (AEA Industrial Technology, Harwell (United Kingdom))

1993-10-01

The JET neutron emission profile monitor was used to study ohmically heated deuterium discharges. The radial profile of the neutron emissivity is deduced from the line-integral data. The profiles of ion temperature, T[sub i], and ion thermal diffusivity, [chi][sub i], are derived under steady-state conditions. The ion thermal diffusivity is higher than, and its scaling with plasma current opposite to, that predicted by neoclassical theory. (author).

Ohmic ion temperature and thermal diffusivity profiles from the JET neutron emission profile monitor

International Nuclear Information System (INIS)

Esposito, B.

1993-01-01

The JET neutron emission profile monitor was used to study ohmically heated deuterium discharges. The radial profile of the neutron emissivity is deduced from the line-integral data. The profiles of ion temperature, T i , and ion thermal diffusivity, χ i , are derived under steady-state conditions. The ion thermal diffusivity is higher than, and its scaling with plasma current opposite to, that predicted by neoclassical theory. (author)

Kinetic effects in the propagation of ion-acoustic negative solitons in plasmas with negative ions

International Nuclear Information System (INIS)

Roberto, M.

1986-12-01

The existence of ion-acoustic negative (rarefactive) solitons in plasmas was experimentally verified and explained by means of the Korteweg-de Vries equation, obtained from a fluid model. The experimental results obtained in a double-plasma machine of the Institute for Space Research, however, have provided values of Mach number larger than predicted by this simple model. In order to improve the analysis of the phenomenon, Kinetic effects resultant from the occurrence of reflected electrons and trapped ions in the soliton potential were considered, using the theory of Sagdeev potential. For the description of the negative ion dynamics the fluid model treatment was preserved. It was verified that the effects of the finite temperature and trapping of the positive ions modify the results predicted by the simple KdV model in such a way that the Mach number is reduced as the ion temperature increases. It was shown that reflection of electrons is consistent with the large experimental values of Mach number. (Author) [pt

Photoionization and electron-ion recombination of Fe XVII for high temperature plasmas

International Nuclear Information System (INIS)

Nahar, Sultana N.

2012-01-01

Earlier studies on electron-ion recombination of Fe XVII, e+FeXVIII→FeXVII, concentrated on low temperature region. However, due to its higher abundance, recombination in the high temperature region is of great importance. Total and level-specific recombination cross sections and rates of Fe XVII are presented from the detailed study in the high temperature. The calculations were carried out using the unified method which incorporates both the radiative recombination (RR) and dielectronic recombination (DR) including the interference effects. The method also yields self-consistent set of recombination rates and photoionization cross sections. Unified method is implemented through relativistic Breit-Pauli R-matrix (BPRM) method and close coupling (CC) approximation. For the details of the high energy and high temperature features a CC wave function expansion consisting of 60 levels from n=2 and 3 complexes of the core Fe XVIII was considered. Earlier study included core excitations to n=2 levels only. It is found that the resonances due to core excitations to n=3 levels are much more extensive and stronger than those to n=2 levels and increase the recombination considerably in the high temperature region. While earlier study of 3-level calculations agree very well with the experimentally derived low temperature recombination, the high temperature rate shows a broad peak at about 5×10 6 K, near the maximum abundance of the ion, due to dominance of DR via PEC (photo-excitation-of-core) resonances of n=3 levels. Level-specific recombination rate coefficients, which include both the RR and DR, are presented for 454 levels (n≤10, l≤9, 0 ≤J≤8 with even and odd parities) of Fe XVII. This is the first large-scale BPRM calculations for recombination of a complex atomic system beyond He- and Li-like ions. The results are expected to be accurate with 10-20% uncertainty and provide accurate modelings of ultraviolet to X-ray spectra.

Effect of seismic activities on ion temperature in the F{sub 2} region of the ionosphere

Energy Technology Data Exchange (ETDEWEB)

Sharma, D.K.; Rai, J. [Department of Physics, Indian Institute of Technology, Roorkee (India); Chand, R.; Israil, M. [Department of Earth Sciences, Indian Institute of Technology, Roorkee (India)]. E-mail: ramesh20june@yahoo.co.in

2006-01-15

Ionospheric anomalies related to the seismic events have been analyzed in the present paper. The ionospheric ion temperature data recorded by the Retarded Potential Analyzer (RPA) payload aboard the Indian SROSS-C2 satellite are used for the period from January 1995 to December 1996. Earthquake events recorded in the region of interest from United State Geological Survey (USGS) were used to define the ionospheric ion temperature anomalies associated with the earthquake preparation, occurrence and relaxation. Ionospheric ion temperature data were analyzed in such a way that the anomalies due to other phenomena will not be masked over the temperature anomalies due to earthquakes. Ion temperature enhancements in the ionosphere were observed during earthquake events and few pre-post days to the events. The seismogenic vertical electric field propagation up to ionospheric height induces the Joule heating that may cause the ion temperature enhancement. [Spanish] En este articulo se analizan anomalias ionosfericas relacionadas con eventos sismicos. Se utilizaron los datos de temperatura ionosferica registrados por el Analizador Potencial Retrasado (RPA) del satelite hindu SROSS-C2 para el periodo de enero de 1995 a diciembre de 1996. Para definir las anomalias de la temperatura ionica de la ionosfera asociadas con la preparacion, ocurrencia y relajacion de los eventos sismicos se utilizaron los datos de estos eventos registrados por el Estudio Geologico de Estado Unido (USGS) para la region de interes. Los datos de temperatura ionica fueron analizados de manera que las anomalias debidas a otros fenomenos no enmascararan aquellas relacionadas con los eventos sismicos. La propagacion del campo electrico vertical sismogenico hacia la ionosfera induce el calentamiento joulico que podria causar el incremento de la temperatura ionica.

Anomalous ion thermal transport in hot ion plasmas by the ion temperature gradient mode

Energy Technology Data Exchange (ETDEWEB)

Kim, J.Y.; Horton, W. (Texas Univ., Austin, TX (United States). Inst. for Fusion Studies); Coppi, B. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Research Lab. of Electronics)

1992-01-01

Experiments show that the observed radial profiles of the ion thermal conductivity {chi}{sub i} have the opposite shapes with those obtained from the ion temperature gradient mode ({eta}{sub i} mode) turbulence model by the traditional mixing length estimate. In this work, this radial profile problem is reconsidered with an electromagnetic study of the linear stability of the toroidal {eta}{sub i} mode and a new rule for choosing the mixing length. It is first shown that the electromagnetic effect gives a significant stabilizing effect on the toroidal {eta}{sub i} mode, and that the observed reduction of {chi}{sub i}(r) in the core region can be explained by this electromagnetic effect. Secondly, in view of earlier numerical simulations showing the transfer of fluctuation energy to larger scales that those for the fastest growth rate, as well as fluctuation measurements indicating longer radial correlation lengths, a new mixing length formula is proposed to explain the radial increase of the {chi}{sub i}. It is shown the new formula fits well the observed {chi}{sub i}(r) profiles in two TFTR supershot discharges and also gives the scaling law in the current and the magnetic field which agrees better with experiment than the conventional formula.

Anomalous ion thermal transport in hot ion plasmas by the ion temperature gradient mode

Energy Technology Data Exchange (ETDEWEB)

Kim, J.Y.; Horton, W. [Texas Univ., Austin, TX (United States). Inst. for Fusion Studies; Coppi, B. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Research Lab. of Electronics

1992-08-01

Experiments show that the observed radial profiles of the ion thermal conductivity {chi}{sub i} have the opposite shapes with those obtained from the ion temperature gradient mode ({eta}{sub i} mode) turbulence model by the traditional mixing length estimate. In this work, this radial profile problem is reconsidered with an electromagnetic study of the linear stability of the toroidal {eta}{sub i} mode and a new rule for choosing the mixing length. It is first shown that the electromagnetic effect gives a significant stabilizing effect on the toroidal {eta}{sub i} mode, and that the observed reduction of {chi}{sub i}(r) in the core region can be explained by this electromagnetic effect. Secondly, in view of earlier numerical simulations showing the transfer of fluctuation energy to larger scales that those for the fastest growth rate, as well as fluctuation measurements indicating longer radial correlation lengths, a new mixing length formula is proposed to explain the radial increase of the {chi}{sub i}. It is shown the new formula fits well the observed {chi}{sub i}(r) profiles in two TFTR supershot discharges and also gives the scaling law in the current and the magnetic field which agrees better with experiment than the conventional formula.

On the production of positive molecular ions in cometary comas

International Nuclear Information System (INIS)

Tarafdar, S.P.; Wickramasinghe, N.C.

1977-01-01

Positively charged molecular ions, such as H 2 O + , which have been observed in cometary comas, may be efficiently produced by the evaporation of positively charged clathrate grains of radii in the range approximately 10 -6 -10 -3 cm. Such grains may be expelled from nuclei of comets, along with gaseous molecules. Grain charging occurs via interaction with solar ultraviolet photons and/or solar wind protons. Observational data on the total quantities as well as the distributions of H 2 O and H 2 O + in cometary comas are shown to be in accord with detailed model calculations. (Auth.)

Investigation of a large volume negative hydrogen ion source

International Nuclear Information System (INIS)

Courteille, C.; Bruneteau, A.M.; Bacal, M.

1995-01-01

The electron and negative ion densities and temperatures are reported for a large volume hybrid multicusp negative ion source. Based on the scaling laws an analysis is made of the plasma formation and loss processes. It is shown that the positive ions are predominantly lost to the walls, although the observed scaling law is n + ∝I 0.57 d . However, the total plasma loss scales linearly with the discharge current, in agreement with the theoretical model. The negative ion formation and loss is also discussed. It is shown that at low pressure (1 mTorr) the negative ion wall loss becomes a significant part of the total loss. The dependence of n - /n e versus the electron temperature is reported. When the negative ion wall loss is negligible, all the data on n - /n e versus the electron temperatures fit a single curve. copyright 1995 American Institute of Physics

Radioactive ions and atoms in superfluid helium

NARCIS (Netherlands)

Dendooven, P.G.; Purushothaman, S.; Gloos, K.; Aysto, J.; Takahashi, N.; Huang, W.; Harissopulos, S; Demetriou, P; Julin, R

2006-01-01

We are investigating the use of superfluid helium as a medium to handle and manipulate radioactive ions and atoms. Preliminary results on the extraction of positive ions from superfluid helium at temperatures close to 1 K are described. Increasing the electric field up to 1.2 kV/cm did not improve

Study on the erosion of refractory metals in interaction with low energy ions at high temperatures of a target

International Nuclear Information System (INIS)

Vaulin, E.P.; Georgieva, N.E.; Martynenko, T.P.; Feoktistov, L.V.

1981-01-01

The experimental study on the erosion of a polycrystalline tungsten by argon ions with 50-100 eV energy in the temperature range 1000-1900 K is carried out and a theoretical analysis of sputtering rate under these conditions is given. It is shown that the sputtering rate is determined not only by ion energy but depends essentially on surface temperature. On the basis of the thermal spot'' model a semiempiric formula is obtained for dependence of sputtering coefficient on ion energy and target temperature. The estimation of cathode specific errosion in high-current discharges due to the sputtering and evaporation is performed. It is shown that depending on cathode temperature, cathode potential jump value as well as on relation of ion and electron current on a cathode the specific erosion due to individual ions shock can be higher and much higher than the specific erosion for account of evaporation [ru

Secondary ion emission

International Nuclear Information System (INIS)

Krohn, V.E.

1976-01-01

The Saha-Langmuir equation that describes the equilibrium emission process, surface ionization, has also been used to describe ion yields observed in the non-equilibrium emission process, sputtering. In describing sputtering, it is probably best to include the potential due to an image charge in the expression for negative as well as positive ion yield and to treat the work function and the temperature as parameters having limited physical significance. Arguments are presented to suggest that sputtered material is not emitted from a plasma. (Auth.)

Charging of dust grains in a plasma with negative ions

Science.gov (United States)

Kim, Su-Hyun; Merlino, Robert L.

2006-05-01

The effect of negative ions on the charging of dust particles in a plasma is investigated experimentally. A plasma containing a very low percentage of electrons is formed in a single-ended SF6 is admitted into the vacuum system. The relatively cold (Te≈0.2eV ) readily attach to SF6 molecules to form SF6- negative ions. Calculations of the dust charge indicate that for electrons, negative ions, and positive ions of comparable temperatures, the charge (or surface potential) of the dust can be positive if the positive ion mass is smaller than the negative ion mass and if ɛ, the ratio of the electron to positive ion density, is sufficiently small. The K+ positive ions (mass 39amu) and SF6- negative ions (mass 146amu), and also utilizes a rotating cylinder to dispense dust into the plasma column. Analysis of the current-voltage characteristics of a Langmuir probe in the dusty plasma shows evidence for the reduction in the (magnitude) of the negative dust charge and the transition to positively charged dust as the relative concentration of the residual electrons is reduced. Some remarks are offered concerning experiments that could become possible in a dusty plasma with positive grains.

Radial convection of finite ion temperature, high amplitude plasma blobs

DEFF Research Database (Denmark)

Wiesenberger, M.; Madsen, Jens; Kendl, Alexander

2014-01-01

We present results from simulations of seeded blob convection in the scrape-off-layer of magnetically confined fusion plasmas. We consistently incorporate high fluctuation amplitude levels and finite Larmor radius (FLR) effects using a fully nonlinear global gyrofluid model. This is in line......-field transport compared to blobs simulated with the local model. The maximal blob amplitude is significantly higher in the global simulations than in the local ones. When the ion temperature is comparable to the electron temperature, global blob simulations show a reduced blob coherence and a decreased cross...

Studies on the application of temperature-responsive ion exchange polymers with whey proteins.

Science.gov (United States)

Maharjan, Pankaj; Campi, Eva M; De Silva, Kirthi; Woonton, Brad W; Jackson, W Roy; Hearn, Milton T W

2016-03-18

Several new types of temperature-responsive ion exchange resins of different polymer composition have been prepared by grafting the products from the co-polymerisation of N-phenylacrylamide, N-iso-propylacrylamide and acrylic acid derivatives onto cross-linked agarose. Analysis of the binding isotherms for these different resins obtained under batch adsorption conditions indicated that the resin based on N-iso-propylacrylamide containing 5% (w/w) N-phenylacrylamide and 5% (w/w) acrylic acid resulted in the highest adsorption capacity, Bmax, for the whey protein, bovine lactoferrin, e.g. 14 mg bovine lactoferrin/mL resin at 4 °C and 62 mg bovine lactoferrin/mL resin at 40 °C, respectively. Under dynamic loading conditions at 40 °C, 94% of the loaded bovine lactoferrin on a normalised mg protein per mL resin basis was adsorbed by this new temperature-responsive ion-exchanger, and 76% was eluted by a single cycle temperature shift to 4 °C without varying the composition of the 10mM sodium dihydrogen phosphate buffer, pH 6.5, or the flow rate. The binding characteristics of these different ion exchange resins with bovine lactoferrin were also compared to results obtained using other resins based on N-isopropylacrylamide but contained N-tert-butylacrylamide rather than N-phenylacrylamide, where the corresponding dynamic capture and release properties for bovine lactoferrin required different temperature conditions of 20 °C and 50 °C, respectively for optimal desorption/adsorption. The cationic protein, bovine lactoperoxidase, was also adsorbed and desorbed with these temperature-responsive resins under similar conditions of changing temperature, whereas the anionic protein, bovine β-lactoglobulin, was not adsorbed under this regime of temperature conditions but instead eluted in the flow-through. Copyright © 2016 Elsevier B.V. All rights reserved.

Korteweg-deVries-Burgers (KdVB) equation in a five component cometary plasma with kappa described electrons and ions

Science.gov (United States)

Michael, Manesh; Willington, Neethu T.; Jayakumar, Neethu; Sebastian, Sijo; Sreekala, G.; Venugopal, Chandu

2016-12-01

We investigate the existence of ion-acoustic shock waves in a five component cometary plasma consisting of positively and negatively charged oxygen ions, kappa described hydrogen ions, hot solar electrons, and slightly colder cometary electrons. The KdVB equation has been derived for the system, and its solution plotted for different kappa values, oxygen ion densities, as well as the temperature ratios for the ions. It is found that the amplitude of the shock wave decreases with increasing kappa values. The strength of the shock profile decreases with increasing temperatures of the positively charged oxygen ions and densities of negatively charged oxygen ions.

Power consumption in positive ion beam converter with electrostatic electron suppressor

International Nuclear Information System (INIS)

Hashimoto, Kiyoshi; Sugawara, Tohru

1985-01-01

The power recovery characteristics of an in-line direct beam converter provided with electrostatic electron suppressor were studied numerically by tracing the orbits of fast primary ions and secondary charged particles generated along their beam path by collision with background gas molecules. It is shown that, in reference to the electrostatic field potential at the point of impact, the energy distribution of secondary ions impinging on the suppressor has two peaks-one corresponding to a zone of high positive potential surrounding the collector and the other to one of slightly negative potential around the electron suppressor. Secondary electron emission from the suppressor is ascribed mainly to the latter peak, associated with impingement of slower secondary ions. Far much power consumed in secondary particle acceleration is spent for emitting electrons from the suppressor than for secondary ions generated by beam-gas collision. The upper limit of background pressure is discussed on the basis of criteria prescribed for restricting the power consumed in this secondary particle acceleration, as for practical convenience of electrode cooling. Numerical examples are given of calculations based on particle trajectory analysis of both primary ions and secondary particles, for the case of a 100 keV-proton sheet beam 10 cm thick of 35 mA/cm 2 current density. (author)

High Time-Resolved Kinetic Temperatures of Solar Wind Minor Ions Measured with SOHO/CELIAS/CTOF

Science.gov (United States)

Janitzek, N. P.; Berger, L.; Drews, C.; Wimmer-Schweingruber, R. F.

2017-12-01

Solar wind heavy ions with an atomic number Z > 2 are referred to as minor ions since they represent a fraction of less than one percent of all solar wind ions. They can be therefore regarded as test particles, only reacting to but not driving the dynamics of the solar wind plasma, which makes them a unique diagnostic tool for plasma wave phenomena both in the solar atmosphere and the extended heliosphere. In the past, several studies have investigated the kinetic temperatures of minor ions, but due to low counting statistics these studies are based on ion velocity distribution functions (VDFs) recorded over time periods of several hours. The Charge Time-Of-Flight (CTOF) mass spectrometer as part of the Charge, ELement and Isotope Analysis System (CELIAS) onboard the SOlar and Heliospheric Observatory (SOHO) provides solar wind heavy ion 1D radial VDFs with excellent charge state separation, an unprecedented cadence of 5 minutes and very high counting statistics, exceeding similar state-of-the-art instruments by a factor of ten. In our study, based on CTOF measurements at Langrangian point L1 between DOY 150 and DOY 220 in 1996, we investigate systematically the influence of the VDF time resolution on the derived kinetic temperatures for solar wind silicon and iron ions. The selected ion set spans a wide range of mass-per-charge from 3 amu/e heavy ions with ion-cyclotron waves.

Fabrication and characterization of a 3D Positive ion detector and its applications

Science.gov (United States)

Venkatraman, Pitchaikannu; Sureka, Chandrasekaran Senbagavadivoo

2017-11-01

There is a growing interest to experimentally evaluate the track structure induced by ionizing particles in order to characterize the radiobiological quality of ionizing radiation for applications in radiotherapy and radiation protection. To do so, a novel positive ion detector based on the multilayer printed circuit board (PCB) technology has been proposed previously, which works under the principle of ion induced impact ionization. Based on this, an upgraded 3D positive ion detector was fabricated in order to improve its efficiency and use it for various applications. To improve the efficiency of the detector, cathodes with different insulators (Bakelite plate and Steatite Ceramics) and conducting layers (ITO, FTO, and Gold coated cathode) were studied under various gaseous media (methane, nitrogen, and air) using Am-241, Co-60, Co-57, Na-22, Cs-137, and Ba-133 sources. From this study, it is confirmed that the novel 3D positive ion detector that has been upgraded using gold as strip material, tungsten (87%) coated copper (13%) as the core wire, gold coated ceramic as cathode, and thickness of 3.483 mm showed 9.2% efficiency under methane medium at 0.9 Torr pressure using an Am-241 source. It is also confirmed that when the conductivity of the cathode and thickness of the detector is increased, the performance of the detector is improved significantly. Further, the scope of the detector to use in the field of radiation protection, radiation dosimetry, gamma spectrometry, radiation biology, and oncology are reported here.

Temperature dependent dielectric properties and ion transportation in solid polymer electrolyte for lithium ion batteries

Energy Technology Data Exchange (ETDEWEB)

Sengwa, R. J., E-mail: rjsengwa@rediffmail.com; Dhatarwal, Priyanka, E-mail: dhatarwalpriyanka@gmail.com; Choudhary, Shobhna, E-mail: shobhnachoudhary@rediffmail.com [Dielectric Research Laboratory, Department of Physics, Jai Narain Vyas University, Jodhpur – 342 005 (India)

2016-05-06

Solid polymer electrolyte (SPE) film consisted of poly(ethylene oxide) (PEO) and poly(methyl methacrylate) (PMMA) blend matrix with lithium tetrafluroborate (LiBF{sub 4}) as dopant ionic salt and poly(ethylene glycol) (PEG) as plasticizer has been prepared by solution casting method followed by melt pressing. Dielectric properties and ionic conductivity of the SPE film at different temperatures have been determined by dielectric relaxation spectroscopy. It has been observed that the dc ionic conductivity of the SPE film increases with increase of temperature and also the decrease of relaxation time. The temperature dependent relaxation time and ionic conductivity values of the electrolyte are governed by the Arrhenius relation. Correlation observed between dc conductivity and relaxation time confirms that ion transportation occurs with polymer chain segmental dynamics through hopping mechanism. The room temperature ionic conductivity is found to be 4 × 10{sup −6} S cm{sup −1} which suggests the suitability of the SPE film for rechargeable lithium batteries.

Experimental investigation of the formation of negative hydrogen ions in collisions between positive ions and atomic or molecular targets

International Nuclear Information System (INIS)

Lattouf, Elie

2013-01-01

The formation of the negative hydrogen ion (H - ) in collisions between a positive ion and a neutral atomic or molecular target is studied experimentally at impact energies of a few keV. The doubly-differential cross sections for H - formation are measured as a function of the kinetic energy and emission angle for the collision systems OH + + Ar and O + + H 2 O at 412 eV/a.m.u. These H - ions can be emitted at high energies (keV) in hard quasi-elastic two-body collisions involving a large momentum transfer to the H center. However, H - anions are preferentially emitted at low energy (eV) due to soft many-body (≥ 2) collisions resulting in a low momentum transfer. The formation of H - ions by electron capture follows excitation or ionization of the molecule. The molecular fragmentation dynamics is modeled to simulate the emission of H - ions. The overall good agreement between the simulation and the experiment leads to the understanding of most of the experimental observations. (author) [fr

New aspects in plasmaspheric ion temperature variations from INTERBALL 2 and MAGION 5 measurements

Czech Academy of Sciences Publication Activity Database

Kotova, G.; Bezrukikh, V.; Verigin, M.; Šmilauer, Jan

2008-01-01

Roč. 70, 2-4 (2008), s. 399-406 ISSN 1364-6826 Institutional research plan: CEZ:AV0Z30420517 Keywords : Plasmasphere * Ion temperature * Electron temperature * Magnetic storm Subject RIV: JV - Space Technology Impact factor: 1.667, year: 2008

A comparison and accuracy analysis of impedance-based temperature estimation methods for Li-ion batteries

NARCIS (Netherlands)

Beelen, H.P.G.J.; Raijmakers, L.H.J.; Donkers, M.C.F.; Notten, P.H.L.; Bergveld, H.J.

2016-01-01

In order to guarantee safe and proper use of Lithium-ion batteries during operation, an accurate estimate of the battery temperature is of paramount importance. Electrochemical Impedance Spectroscopy (EIS) can be used to estimate the battery temperature and several EIS-based temperature estimation

Application of selected ion monitoring to the analysis of triacylglycerols in olive oil by high temperature-gas chromatography/mass spectrometry.

Science.gov (United States)

Ruiz-Samblás, C; González-Casado, A; Cuadros-Rodríguez, L; García, F P Rodríguez

2010-06-30

The analysis of the triacylglycerol (TAG) composition of oils is a very challenging task, since the TAGs have very similar physico-chemical properties. In this work, a high temperature-gas chromatographic method coupled to electron ionization-mass spectrometry (HT-GC/EI-MS), in the Selected Ion Monitoring (SIM) mode, method was developed for the analysis of TAGs in the olive oil; this is a method suitable for routine analysis. This method was developed using commercially available standard TAGs. The TAGs studied were separated according to their equivalent carbon number and degree of unsaturation. The peak assignment was carried out by locating the characteristic fragment ions having the same retention time on the SIM profile such as [RCO+74](+) and [RCO+128](+) ions, due to the fatty acyl residues on sn-1, sn-2 and sn-3 positions of the TAG molecule and the [M-OCOR](+) ions corresponding to the acyl ions. The developed method was very useful to eliminate the interferences that appeared in the mass spectrum since electron ionization can prevent satisfactory interpretation of spectra. Copyright 2010 Elsevier B.V. All rights reserved.

Electron and ion temperatures: a comparison of ground-based incoherent scatter and AE-C satellite measurements

International Nuclear Information System (INIS)

Benson, R.F.; Bauer, P.; Brace, L.H.; Carlson, H.C.; Hagen, J.; Hanson, W.B.; Hoegy, W.R.; Torr, M.R.; Wickwar, V.B.

1977-01-01

The Atmosphere Exploere-C satellite (AE-C) is uniquely suited for correlative studies with ground-based stations because its on-board propulsion system enables a desired ground station overflight condition to be maintained for a period of several weeks. It also provides the first low-altitude (below 260 km) comparison of satellite and incoherent scatter electron and ion temperatures. More than 40 comparisons of remote and in situ measurements were made by using data from AE-C and four incoherent scatter stations (Arecibo, Chatanika, Millstone Hill, and St. Santin). The results indicate very good agreement between satellite and ground measurements of the ion temperature, the average satellite retarding potential analyzer temperatures differing from the average incoherent scatter temperatures by -2% at St. Santin, +3% at Millstone Hill, and +2% at Arecibo. The electron temperatures also agree well, the average satellite temperatures exceeding the average incoherent scatter temperatures by 3% at St. Santin, 2% at Arecibo, and 11% at Millstone Hill. Several temperature comparisons were made between AE-C and Chatanika. In spite of the highly variable ionosphere often encountered at this high-latitude location, good agreement was obtained between the in situ and remote measurements of electron and ion temperatures. Longitudinal variations are found to be very important in the comparisons of electron temperature in some locations. The agreement between the electron temperatures is considerably better than that found in some earlier comparisons involving satellities at higher altitudes

Graphene synthesis on SiC: Reduced graphitization temperature by C-cluster and Ar-ion implantation

International Nuclear Information System (INIS)

Zhang, R.; Li, H.; Zhang, Z.D.; Wang, Z.S.; Zhou, S.Y.; Wang, Z.; Li, T.C.; Liu, J.R.; Fu, D.J.

2015-01-01

Thermal decomposition of SiC is a promising method for high quality production of wafer-scale graphene layers, when the high decomposition temperature of SiC is substantially reduced. The high decomposition temperature of SiC around 1400 °C is a technical obstacle. In this work, we report on graphene synthesis on 6H–SiC with reduced graphitization temperature via ion implantation. When energetic Ar, C 1 and C 6 -cluster ions implanted into 6H–SiC substrates, some of the Si–C bonds have been broken due to the electronic and nuclear collisions. Owing to the radiation damage induced bond breaking and the implanted C atoms as an additional C source the graphitization temperature was reduced by up to 200 °C

Visible laser induced positive ion emissions from NaCl nanoparticles prepared by droplet rapid drying

International Nuclear Information System (INIS)

Sun, Mao-Xu; Guo, Deng-Zhu; Xing, Ying-Jie; Zhang, Geng-Min

2012-01-01

Highlights: ► NaCl nanoparticles were firstly prepared by heat induced explosion on silicon wafer. ► We found that laser induced ion emissions from NaCl nanoparticles are more prominent. ► We found that water adsorption can efficiently enhance laser induced ion emissions. ► The ultra-photothermal effect in NaCl nanoparticles was observed and explained. - Abstract: A novel convenient way for the formation of sodium chloride (NaCl) nanoparticles on silicon wafer is proposed by using a droplet rapid drying method. The laser induced positive ion emissions from NaCl nanoparticles with and without water treatment is demonstrated by using a laser desorption/ionization time-of-flight mass spectrometer, with laser intensity well below the plasma formation threshold. It is found that the positive ion emissions from NaCl nanoparticles are obviously higher than that from microsize NaCl particles under soft 532 nm laser irradiations, and water adsorption can efficiently enhance the ion emissions from NaCl nanoparticles. The initial kinetic energies of the emitted ions are estimated as 16–17 eV. The synergy of the ultra-thermal effect in nanomaterials, the defect-mediated multiphoton processes, and the existence of intermediate states in NaCl-water interfaces are suggested as the mechanisms.

Spherical ion oscillations in a positive polarity gridded inertial-electrostatic confinement device

Energy Technology Data Exchange (ETDEWEB)

Bandara, R.; Khachan, J. [Plasma Physics, School of Physics, University of Sydney, Camperdown, New South Wales 2006 (Australia)

2013-07-15

A pulsed, positive polarity gridded inertial electrostatic confinement device has been investigated experimentally, using a differential emissive probe and potential traces as primary diagnostics. Large amplitude oscillations in the plasma current and plasma potential were observed within a microsecond of the discharge onset, which are indicative of coherent ion oscillations about a temporarily confined excess of recirculating electron space charge. The magnitude of the depth of the potential well in the established virtual cathode was determined using a differential emissive Langmuir probe, which correlated well to the potential well inferred from the ion oscillation frequency for both hydrogen and argon experiments. It was found that the timescale for ion oscillation dispersion is strongly dependent on the neutral gas density, and weakly dependent on the peak anode voltage. The cessation of the oscillations was found to be due to charge exchange processes converting ions to high velocity neutrals, causing the abrupt de-coherence of the oscillations through an avalanche dispersion in phase space.

Spherical ion oscillations in a positive polarity gridded inertial-electrostatic confinement device

Science.gov (United States)

Bandara, R.; Khachan, J.

2013-07-01

A pulsed, positive polarity gridded inertial electrostatic confinement device has been investigated experimentally, using a differential emissive probe and potential traces as primary diagnostics. Large amplitude oscillations in the plasma current and plasma potential were observed within a microsecond of the discharge onset, which are indicative of coherent ion oscillations about a temporarily confined excess of recirculating electron space charge. The magnitude of the depth of the potential well in the established virtual cathode was determined using a differential emissive Langmuir probe, which correlated well to the potential well inferred from the ion oscillation frequency for both hydrogen and argon experiments. It was found that the timescale for ion oscillation dispersion is strongly dependent on the neutral gas density, and weakly dependent on the peak anode voltage. The cessation of the oscillations was found to be due to charge exchange processes converting ions to high velocity neutrals, causing the abrupt de-coherence of the oscillations through an avalanche dispersion in phase space.

Negative Halogen Ions for Fusion Applications

International Nuclear Information System (INIS)

Grisham, L.R.; Kwan, J.W.; Hahto, S.K.; Hahto, S.T.; Leung, K.N.; Westenskow, G.

2006-01-01

Over the past quarter century, advances in hydrogen negative ion sources have extended the usable range of hydrogen isotope neutral beams to energies suitable for large magnetically confined fusion devices. Recently, drawing upon this experience, negative halogen ions have been proposed as an alternative to positive ions for heavy ion fusion drivers in inertial confinement fusion, because electron accumulation would be prevented in negative ion beams, and if desired, the beams could be photo-detached to neutrals. This paper reports the results of an experiment comparing the current density and beam emittance of Cl+ and Cl- extracted from substantially ion-ion plasmas with that of Ar+ extracted from an ordinary electron-ion plasma, all using the same source, extractor, and emittance scanner. At similar discharge conditions, the Cl- current was typically 85-90% of the positive chlorine current, with an e-/ Cl- ratio as low as seven without grid magnets. The Cl- was as much as 76% of the Ar+ current from a discharge with the same RF drive. The minimum normalized beam emittance and inferred ion temperatures of Cl+, Cl-, and Ar+ were all similar, so the current density and optical quality of Cl- appear as suitable for heavy ion fusion driver applications as a positive noble gas ion of similar mass. Since F, I, and Br should all behave similarly in an ion source, they should also be suitable as driver beams

Tunnel probes for measurements of the electron and ion temperature in fusion plasmas

Czech Academy of Sciences Publication Activity Database

Gunn, J. P.; Schrittwieser, R.; Balan, P.; Ionita, C.; Stöckel, Jan; Adámek, Jiří; Ďuran, Ivan; Hron, Martin; Pánek, Radomír; Bařina, O.; Hrach, R.; Vicher, M.; Van Oost, G.; Van Rompuy, T.; Martines, E.

2004-01-01

Roč. 75, č. 10 (2004), s. 4328-4330 ISSN 0034-6748. [Topical Conference on High-Temperature Plasma Diagnostics/15th./. San Diego, 19.04.2004-22.04.2004] R&D Projects: GA ČR GA202/03/0786 Institutional research plan: CEZ:AV0Z2043910 Keywords : Tokamak * electron temperature * ion temperature * plasma diagnostics Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.226, year: 2004

Measurements of ion temperature and flow of pulsed plasmas produced by a magnetized coaxial plasma gun device using an ion Doppler spectrometer

Science.gov (United States)

Kitagawa, Y.; Sakuma, I.; Iwamoto, D.; Kikuchi, Y.; Fukumoto, N.; Nagata, M.

2012-10-01

It is important to know surface damage characteristics of plasma-facing component materials during transient heat and particle loads such as type I ELMs. A magnetized coaxial plasma gun (MCPG) device has been used as transient heat and particle source in ELM simulation experiments. Characteristics of pulsed plasmas produced by the MCPG device play an important role for the plasma material interaction. In this study, ion temperature and flow velocity of pulsed He plasmas were measured by an ion Doppler spectrometer (IDS). The IDS system consists of a light collection system including optical fibers, 1m-spectrometer and a 16 channel photomultiplier tube (PMT) detector. The IDS system measures the width and Doppler shift of HeII (468.58 nm) emission line with the time resolution of 1 μs. The Doppler broadened and shifted spectra were measured with 45 and 135 degree angles with respect to the plasmoid traveling direction. The observed emission line profile was represented by sum of two Gaussian components to determine the temperature and flow velocity. The minor component at around the wavelength of zero-velocity was produced by the stationary plasma. As the results, the ion velocity and temperature were 68 km/s and 19 eV, respectively. Thus, the He ion flow energy is 97 eV. The observed flow velocity agrees with that measured by a time of flight technique.

Comparison between kinetic and fluid simulations of slab ion temperature gradient driven turbulence

Energy Technology Data Exchange (ETDEWEB)

Sugama, H.; Watanabe, T.-H. [National Inst. for Fusion Science, Toki, Gifu (Japan); Horton, W. [University of Texas at Austin, Institute for Fusion Studies, Austin, Texas (United States)

2002-10-01

A detailed comparison between kinetic and fluid simulations of collisionless slab ion temperature gradient (ITG) driven turbulence is made. The nondissipative closure model (NCM) for linearly unstable modes, which is presented by Sugama, Watanabe, and Horton [Phys. Plasmas 8, 2617 (2001)], and the dissipative closure model by Hammett and Perkins (HP) [Phys. Rev. Lett. 64, 3019 (1990)] are used in separate fluid simulations. The validity of these closure models for quantitative prediction of the turbulent thermal transport is examined by comparing nonlinear results of the fluid simulations with those of the collisionless kinetic simulation of high accuracy. Simulation results show that, in the saturated turbulent state, the turbulent thermal diffusivity {chi} obtained from the HP model is significantly larger than the {chi} given by the NCM which is closer to {chi} measured in the kinetic simulation. Contrary to the dissipative form of the parallel heat flux closure relation assumed in the HP model, the NCM describes well the exact kinetic simulation, in which for some unstable wave numbers k, the imaginary part of the ratio of the parallel heat flux q{sub k} to the temperature fluctuation T{sub k} is a oscillatory function of time and sometimes takes positive values. The positive values of Im(q{sub k}/T{sub k}), imply the negative parallel heat diffusivity, correlate with the occasional inward heat flux occurring for the wave numbers k, and reduce the total {chi}. (author)

Comparison between kinetic and fluid simulations of slab ion temperature gradient driven turbulence

International Nuclear Information System (INIS)

Sugama, H.; Watanabe, T.-H.; Horton, W.

2002-10-01

A detailed comparison between kinetic and fluid simulations of collisionless slab ion temperature gradient (ITG) driven turbulence is made. The nondissipative closure model (NCM) for linearly unstable modes, which is presented by Sugama, Watanabe, and Horton [Phys. Plasmas 8, 2617 (2001)], and the dissipative closure model by Hammett and Perkins (HP) [Phys. Rev. Lett. 64, 3019 (1990)] are used in separate fluid simulations. The validity of these closure models for quantitative prediction of the turbulent thermal transport is examined by comparing nonlinear results of the fluid simulations with those of the collisionless kinetic simulation of high accuracy. Simulation results show that, in the saturated turbulent state, the turbulent thermal diffusivity χ obtained from the HP model is significantly larger than the χ given by the NCM which is closer to χ measured in the kinetic simulation. Contrary to the dissipative form of the parallel heat flux closure relation assumed in the HP model, the NCM describes well the exact kinetic simulation, in which for some unstable wave numbers k, the imaginary part of the ratio of the parallel heat flux q k to the temperature fluctuation T k is a oscillatory function of time and sometimes takes positive values. The positive values of Im(q k /T k ), imply the negative parallel heat diffusivity, correlate with the occasional inward heat flux occurring for the wave numbers k, and reduce the total χ. (author)

Charge Inversion of Phospholipids by Dimetal Complexes for Positive Ion-Mode Electrospray Ionization Mass Spectrometry Analysis

DEFF Research Database (Denmark)

Svane, Simon; Gorshkov, Vladimir; Kjeldsen, Frank

2015-01-01

charges per phosphate group. Three different phosphoinositide phosphates (mono-, di-, and triphosphorylated inositides), a phosphatidic acid, a phosphatidylcholine, a phosphatidylethanolamine, and a phosphatidylglycerol were investigated. The intensities obtained in positive ion-mode of phosphoinositide...... phosphates and phosphatidic acid bound to {LGa2}(5+) were between 2.5- and 116-fold higher than that of the unmodified lipids in the negative ion-mode. Native phosphoinositide ions yielded upon CID in the negative ion-mode predominantly product ions due to losses of H3PO4, PO3(-) and H2O. In comparison, CID...

Temperature-dependent electrochemical heat generation in a commercial lithium-ion battery

Science.gov (United States)

Bandhauer, Todd M.; Garimella, Srinivas; Fuller, Thomas F.

2014-02-01

Lithium-ion batteries suffer from inherent thermal limitations (i.e., capacity fade and thermal runaway); thus, it is critical to understand heat generation experienced in the batteries under normal operation. In the current study, reversible and irreversible electrochemical heat generation rates were measured experimentally on a small commercially available C/LiFePO4 lithium-ion battery designed for high-rate applications. The battery was tested over a wide range of temperatures (10-60 °C) and discharge and charge rates (∼C/4-5C) to elucidate their effects. Two samples were tested in a specially designed wind tunnel to maintain constant battery surface temperature within a maximum variation of ±0.88 °C. A data normalization technique was employed to account for the observed capacity fade, which was largest at the highest rates. The heat rate was shown to increase with both increasing rate and decreasing temperature, and the reversible heat rate was shown to be significant even at the highest rate and temperature (7.4% at 5C and 55 °C). Results from cycling the battery using a dynamic power profile also showed that constant-current data predict the dynamic performance data well. In addition, the reversible heat rate in the dynamic simulation was shown to be significant, especially for charge-depleting HEV applications.

Results of measurements of the ion temperature profile of ECR heated plasmas in the L-2M stellarator

International Nuclear Information System (INIS)

Voronov, G.S.; Voronova, E.V.; Grebenshchikov, S.E.

2005-01-01

After boronization of the vacuum chamber of the L-2M stellarator, the confinement characteristics and the electron temperature profile changed markedly. In this connection, our immediate task was to carry out studies of the behavior of the ion temperature under these conditions. Previous measurements of Ti were performed by analyzing the energy distribution of fast hydrogen ions produced by charge exchange. In recent studies, the ion temperature was determined from Doppler broadening of spectral lines of impurity ions. With the help of a set of mirrors, the plasma radiation was focused on the entrance slit of a VMS-1 monochromator (D/F=1:6.5, F=600 mm, 1200 lines/mm,1.3 nm/mm, 200 - 800 nm). The detector was a CCD plate (1040 1 140 pixels of size 16 1 6 ∝ m) covered in part with an opaque screen. The plasma spectrum produced in the uncovered area was rapidly scanned and copied into the covered region. With this partial exposition method, the rate of recording was successfully increased up to 1000 frames per second. The instrument function of the whole system was 0.04 nm, which corresponds to Ti ∼1 eV for hydrogen and ∼17 eV for boron ions. The plasma ion temperature is considerably higher, so the accuracy of measurements of Ti is limited primarily by a low intensity of signals from the plasma with a low impurity concentration. The results of measurements of the evolution of HeII, BII, and BIV ions temperature during the ECR heating of a helium plasma are shown in the figure. The plasma density in these experiments was ∼2.10 19 m -3 , and the gyrotron pulse power was ∼200 kW. The results of measurements of Ti were compared with the time evolution of the ion temperature calculated by using the TRANSZ code. The latter includes a complete set of neoclassical equations and involves additional anomalous fluxes corresponding to accepted empirical scalings. The calculated values of Ti are in fair agreement with the measured ones

Variable temperature ion trap studies of CH4+ + H2, HD and D2: negative temperature dependence and significant isotope effect

International Nuclear Information System (INIS)

Asvany, O.; Savic, I.; Schlemmer, S.; Gerlich, D.

2004-01-01

Reactions of methane cations, CH 4 + , with H 2 , HD and D 2 have been studied in a variable temperature 22-pole ion trap from room temperature down to 15 K. The formation of CH 5 + in collisions with H 2 is slow at 300 K, but it becomes faster by at least one order of magnitude when the temperature is lowered to 15 K. This behavior is tentatively explained with a longer complex lifetime at low temperatures. However, since tunneling is most probably not responsible for product formation, other dynamical or statistical restrictions must be responsible for the negative temperature dependence. In collisions of CH 4 + with HD, the CH 5 + product ion (68% at 15 K) prevails over CH 4 D + (32%). Reaction of CH 4 + with D 2 is found to be much slower than with H 2 or HD. The rate coefficient for converting CH 4 + into CH 3 D + by H-D exchange has been determined to be smaller than 10 -12 cm 3 /s, indicating that scrambling in the CH 6 + complex is very unlikely

A large area position-sensitive ionization chamber for heavy-ion-induced reaction studies

CERN Document Server

Pant, L M; Dinesh, B V; Thomas, R G; Saxena, A; Sawant, Y S; Choudhury, R K

2002-01-01

A large area position-sensitive ionization chamber with a wide dynamic range has been developed to measure the mass, charge and energy of the heavy ions and the fission fragments produced in heavy-ion-induced reactions. The split anode geometry of the detector makes it suitable for both particle identification and energy measurements for heavy ions and fission fragments. The detector has been tested with alpha particles from sup 2 sup 4 sup 1 Am- sup 2 sup 3 sup 9 Pu source, fission fragments from sup 2 sup 5 sup 2 Cf and the heavy-ion beams from the 14UD Mumbai Pelletron accelerator facility. Using this detector, measurements on mass and total kinetic energy distributions in heavy-ion-induced fusion-fission reactions have been carried out for a wide range of excitation energies. Results on deep inelastic collisions and mass-energy correlations on different systems using this detector setup are discussed.

Analytical and numerical studies of positive ion beam expansion for surface treatment applications

Science.gov (United States)

Lounes-Mahloul, Soumya; Bendib, Abderrezeg; Oudini, Noureddine

2018-01-01

The aim of this work is to study the expansion in vacuum, of a positive ion beam with the use of one dimensional (1D) analytic model and a two dimensional Particle-In-Cell (2D-PIC) simulation. The ion beam is extracted and accelerated from preformed plasma by an extraction system composed of two polarized parallel perforated grids. The results obtained with both approaches reveal the presence of a potential barrier downstream the extraction system which tends to reflect the ion flux. The dependence of the critical distance for which all extracted ions are reflected, is investigated as a function of the extracted ion beam current density. In particular, it is shown that the 1D model recovers the well-known Child-Langmuir law and that the 2D simulation presents a significant discrepancy with respect to the 1D prediction. Indeed, for a given value of current density, the transverse effects lead to a greater critical distance.

Self-organized profile relaxation by ion temperature gradient instability in toroidal plasmas

International Nuclear Information System (INIS)

Kishimoto, Y.; Tajima, T.; LeBrun, M.J.; Gray, M.G.; Kim, J.Y.; Horton, W.

1993-02-01

Toroidal effects on the ion-temperature gradient mode are found to dictate the temperature evolution and the subsequent relaxed profile realization according to our toroidal particle simulation. Both in the strongly unstable fluid regime as well as in the near-marginal kinetic regime we observe that the plasma maintains an exponential temperature profile and forces the heat flux to be radially independent. The self-organized critical relaxed state is sustained slightly above the marginal stability, where the weak wave growth balances the wave decorrelation

Charging of dust grains in a plasma with negative ions

International Nuclear Information System (INIS)

Kim, Su-Hyun; Merlino, Robert L.

2006-01-01

The effect of negative ions on the charging of dust particles in a plasma is investigated experimentally. A plasma containing a very low percentage of electrons is formed in a single-ended Q machine when SF 6 is admitted into the vacuum system. The relatively cold Q machine electrons (T e ≅0.2 eV) readily attach to SF 6 molecules to form SF 6 - negative ions. Calculations of the dust charge indicate that for electrons, negative ions, and positive ions of comparable temperatures, the charge (or surface potential) of the dust can be positive if the positive ion mass is smaller than the negative ion mass and if ε, the ratio of the electron to positive ion density, is sufficiently small. The Q machine plasma is operated with K + positive ions (mass 39 amu) and SF 6 - negative ions (mass 146 amu), and also utilizes a rotating cylinder to dispense dust into the plasma column. Analysis of the current-voltage characteristics of a Langmuir probe in the dusty plasma shows evidence for the reduction in the (magnitude) of the negative dust charge and the transition to positively charged dust as the relative concentration of the residual electrons is reduced. Some remarks are offered concerning experiments that could become possible in a dusty plasma with positive grains

Accelerating Rate Calorimetry Tests of Lithium-Ion Cells Before and After Storage Degradation at High Temperature

Directory of Open Access Journals (Sweden)

Mendoza-Hernandez Omar Samuel

2017-01-01

Full Text Available Understanding the behavior of Li-ion cells during thermal runaway is critical to evaluate the safety of these energy storage devices under outstanding conditions. Li-ion cells possess a high energy density and are used to store and supply energy to many aerospace applications. Incidents related to the overheating or thermal runaway of these cells can cause catastrophic damages that could end up costly space missions; therefore, thermal studies of Li-ion cells are very important for ensuring safety and reliability of space missions. This work evaluates the thermal behavior of Li-ion cells before and after storage degradation at high temperature using accelerating rate calorimeter (ARC equipment to analyze the thermal behavior of Li-ion cells under adiabatic conditions. Onset temperature points of self-heating and thermal runaway reactions are obtained. The onset points are used to identify non-self-heating, self-heating and thermal runaway regions as a function of state of charge. The results obtained can be useful to develop accurate thermo-electrochemical models of Li-ion cells.

The temperature effect of low-energy ion beam implantation on seed

International Nuclear Information System (INIS)

Chang Shenghe; Su Mingjie; Qin Guangyong; Wu Yuping; Zhao Haizhen

2005-01-01

The temperature effects of low-energy ion beam implantation on the seed germination were studied. Maize dry seeds were covered with copy paper, aluminum foil and without cover, respectively. Results showed that the germination rate of the seeds covered with paper which was the bad heat transmitter was the highest among three treatments, while that covered with aluminum foil which can transmit heat energy well was the least. The germination rate of the seeds covered with nothing was the second. Temperature affected seeds germination markedly. Generally the temperature of the target room inhibited the seeds' germination. After minus the effects of the temperature in the target room, the germination rates of the seeds were modified in this paper. The modified germination rate curve was also provided. (authors)

A thermal extrapolation method for the effective temperatures and internal energies of activated ions

Science.gov (United States)

Meot-Ner (Mautner), Michael; Somogyi, Árpád

2007-11-01

The internal energies of dissociating ions, activated chemically or collisionally, can be estimated using the kinetics of thermal dissociation. The thermal Arrhenius parameters can be combined with the observed dissociation rate of the activated ions using kdiss = Athermalexp(-Ea,thermal/RTeff). This Arrhenius-type relation yields the effective temperature, Teff, at which the ions would dissociate thermally at the same rate, or yield the same product distributions, as the activated ions. In turn, Teff is used to calculate the internal energy of the ions and the energy deposited by the activation process. The method yields an energy deposition efficiency of 10% for a chemical ionization proton transfer reaction and 8-26% for the surface collisions of various peptide ions. Internal energies of ions activated by chemical ionization or by gas phase collisions, and of ions produced by desorption methods such as fast atom bombardment, can be also evaluated. Thermal extrapolation is especially useful for ion-molecule reaction products and for biological ions, where other methods to evaluate internal energies are laborious or unavailable.

Sorption of Ni(II) on GMZ bentonite: effects of pH, ionic strength, foreign ions, humic acid and temperature.

Science.gov (United States)

Yang, Shitong; Li, Jiaxing; Lu, Yi; Chen, Yixue; Wang, Xiangke

2009-09-01

Bentonite has been widely studied in nuclear waste management because of its special physicochemical properties. In this work, the sorption of Ni(II) from aqueous solution onto GMZ bentonite as a function of contact time, pH, ionic strength, foreign ions, humic acid (HA) and temperature was investigated under ambient conditions. The results indicated that the pseudo-second-order rate equation simulated the kinetic sorption process well. The sorption of Ni(II) on GMZ bentonite was strongly dependent on pH and on ionic strength. At low pH, the sorption of Ni(II) was dominated by outer-sphere surface complexation and ion exchange with Na(+)/H(+) on GMZ bentonite surfaces, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. A positive effect of HA on Ni(II) sorption was found at pH8. The Langmuir, Freundlich, and D-R models were used to simulate the sorption isotherms of Ni(II) at three different temperatures: 303.15, 318.15 and 333.15K. The thermodynamic parameters (DeltaH(0), DeltaS(0) and DeltaG(0)) of Ni(II) sorption on GMZ bentonite at the three different temperatures were calculated from the temperature-dependent sorption isotherms. The results indicated that the sorption process of Ni(II) on GMZ bentonite was endothermic and spontaneous. Experimental results indicate that GMZ bentonite is a suitable sorbent for pre-concentration and solidification of Ni(II) from large volume solutions.

Sorption of Ni(II) on GMZ bentonite: Effects of pH, ionic strength, foreign ions, humic acid and temperature

International Nuclear Information System (INIS)

Yang Shitong; Li Jiaxing; Lu Yi; Chen Yixue; Wang Xiangke

2009-01-01

Bentonite has been widely studied in nuclear waste management because of its special physicochemical properties. In this work, the sorption of Ni(II) from aqueous solution onto GMZ bentonite as a function of contact time, pH, ionic strength, foreign ions, humic acid (HA) and temperature was investigated under ambient conditions. The results indicated that the pseudo-second-order rate equation simulated the kinetic sorption process well. The sorption of Ni(II) on GMZ bentonite was strongly dependent on pH and on ionic strength. At low pH, the sorption of Ni(II) was dominated by outer-sphere surface complexation and ion exchange with Na + /H + on GMZ bentonite surfaces, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. A positive effect of HA on Ni(II) sorption was found at pH 8. The Langmuir, Freundlich, and D-R models were used to simulate the sorption isotherms of Ni(II) at three different temperatures: 303.15, 318.15 and 333.15 K. The thermodynamic parameters (ΔH 0 , ΔS 0 and ΔG 0 ) of Ni(II) sorption on GMZ bentonite at the three different temperatures were calculated from the temperature-dependent sorption isotherms. The results indicated that the sorption process of Ni(II) on GMZ bentonite was endothermic and spontaneous. Experimental results indicate that GMZ bentonite is a suitable sorbent for pre-concentration and solidification of Ni(II) from large volume solutions.

Potential profile near singularity point in kinetic Tonks-Langmuir discharges as a function of the ion sources temperature

Science.gov (United States)

Kos, L.; Tskhakaya, D. D.; Jelić, N.

2011-05-01

A plasma-sheath transition analysis requires a reliable mathematical expression for the plasma potential profile Φ(x) near the sheath edge xs in the limit ɛ ≡λD/ℓ =0 (where λD is the Debye length and ℓ is a proper characteristic length of the discharge). Such expressions have been explicitly calculated for the fluid model and the singular (cold ion source) kinetic model, where exact analytic solutions for plasma equation (ɛ =0) are known, but not for the regular (warm ion source) kinetic model, where no analytic solution of the plasma equation has ever been obtained. For the latter case, Riemann [J. Phys. D: Appl. Phys. 24, 493 (1991)] only predicted a general formula assuming relatively high ion-source temperatures, i.e., much higher than the plasma-sheath potential drop. Riemann's formula, however, according to him, never was confirmed in explicit solutions of particular models (e.g., that of Bissell and Johnson [Phys. Fluids 30, 779 (1987)] and Scheuer and Emmert [Phys. Fluids 31, 3645 (1988)]) since "the accuracy of the classical solutions is not sufficient to analyze the sheath vicinity" [Riemann, in Proceedings of the 62nd Annual Gaseous Electronic Conference, APS Meeting Abstracts, Vol. 54 (APS, 2009)]. Therefore, for many years, there has been a need for explicit calculation that might confirm the Riemann's general formula regarding the potential profile at the sheath edge in the cases of regular very warm ion sources. Fortunately, now we are able to achieve a very high accuracy of results [see, e.g., Kos et al., Phys. Plasmas 16, 093503 (2009)]. We perform this task by using both the analytic and the numerical method with explicit Maxwellian and "water-bag" ion source velocity distributions. We find the potential profile near the plasma-sheath edge in the whole range of ion source temperatures of general interest to plasma physics, from zero to "practical infinity." While within limits of "very low" and "relatively high" ion source temperatures

First operational experience with the positive-ion injector of ATLAS

International Nuclear Information System (INIS)

Bollinger, L.M.; Pardo, R.C.; Shepard, K.W.; Billquist, P.J.; Bogaty, J.M.; Clifft, B.E.; Harkewicz, R.; Joh, K.; Markovich, P.K.; Munson, F.H.; Zinkann, G.; Nolen, J.A.

1992-01-01

A Positive-Ion Injector (PH) designed to enable ATLAS to accelerate all stable nuclei has been completed and successfully tested. This new injector system consists of an ECR source on a 350-kV platform coupled to a 12-MV superconducting injector linac formed with four different types of independently-phased 4-gap accelerating structures. The injector linac is configured to be optimum for the acceleration of uranium ions from 0.029 to ∼ 1.1 MeV/u. When ions with q/A > 0. 1 are accelerated by PII and injected into the main ATLAS linac, CW beams with energies over 6 MeV/u can be delivered to the experimental areas. Since its completion in March 1992, PII has been tested by accelerating 3O Si 7+ , 40 Ar ll+ , 132 Xe 13+ , and 208 Pb 24+ . For all of these, transmission through the injecter linac was ∼ 100% of the pre-bunched beam, which corresponds to ∼ 60% of the DC beam from the source. The accelerating fields of the superconducting resonators were somewhat greater than the design goals, and the whole system ran stably for long periods of time

Ion acoustic solitons in a plasma with two-temperature kappa-distributed electrons

International Nuclear Information System (INIS)

Baluku, T. K.; Hellberg, M. A.

2012-01-01

Existence domains and characteristics of ion acoustic solitons are studied in a two-temperature electron plasma with both electron components being kappa-distributed, as found in Saturn's magnetosphere. As is the case for double-Boltzmann electrons, solitons of both polarities can exist over restricted ranges of fractional hot electron density ratio for this plasma model. Low κ values, which indicate increased suprathermal particles in the tail of the distribution, yield a smaller domain in the parameter space of hot density fraction and normalized soliton velocity (f, M), over which both soliton polarities are supported for a given plasma composition (the coexistence region). For some density ratios that support coexistence, solitons occur even at the lowest (critical) Mach number (i.e., at the acoustic speed), as found recently for a number of other plasma models. Like Maxwellians, low-κ distributions also support positive potential double layers over a narrow range of low fractional cool electron density (<10%).

Ion acoustic solitons in a plasma with two-temperature kappa-distributed electrons

Energy Technology Data Exchange (ETDEWEB)

Baluku, T. K.; Hellberg, M. A. [School of Physics, University of KwaZulu-Natal, Private Bag X54001, Durban 4000 (South Africa)

2012-01-15

Existence domains and characteristics of ion acoustic solitons are studied in a two-temperature electron plasma with both electron components being kappa-distributed, as found in Saturn's magnetosphere. As is the case for double-Boltzmann electrons, solitons of both polarities can exist over restricted ranges of fractional hot electron density ratio for this plasma model. Low {kappa} values, which indicate increased suprathermal particles in the tail of the distribution, yield a smaller domain in the parameter space of hot density fraction and normalized soliton velocity (f, M), over which both soliton polarities are supported for a given plasma composition (the coexistence region). For some density ratios that support coexistence, solitons occur even at the lowest (critical) Mach number (i.e., at the acoustic speed), as found recently for a number of other plasma models. Like Maxwellians, low-{kappa} distributions also support positive potential double layers over a narrow range of low fractional cool electron density (<10%).

Multiplex Mass Spectrometric Imaging with Polarity Switching for Concurrent Acquisition of Positive and Negative Ion Images

Science.gov (United States)

Korte, Andrew R.; Lee, Young Jin

2013-06-01

We have recently developed a multiplex mass spectrometry imaging (MSI) method which incorporates high mass resolution imaging and MS/MS and MS3 imaging of several compounds in a single data acquisition utilizing a hybrid linear ion trap-Orbitrap mass spectrometer (Perdian and Lee, Anal. Chem. 82, 9393-9400, 2010). Here we extend this capability to obtain positive and negative ion MS and MS/MS spectra in a single MS imaging experiment through polarity switching within spiral steps of each raster step. This methodology was demonstrated for the analysis of various lipid class compounds in a section of mouse brain. This allows for simultaneous imaging of compounds that are readily ionized in positive mode (e.g., phosphatidylcholines and sphingomyelins) and those that are readily ionized in negative mode (e.g., sulfatides, phosphatidylinositols and phosphatidylserines). MS/MS imaging was also performed for a few compounds in both positive and negative ion mode within the same experimental set-up. Insufficient stabilization time for the Orbitrap high voltage leads to slight deviations in observed masses, but these deviations are systematic and were easily corrected with a two-point calibration to background ions.

Temperature-dependent surface porosity of Nb{sub 2}O{sub 5} under high-flux, low-energy He{sup +} ion irradiation

Energy Technology Data Exchange (ETDEWEB)

Novakowski, T.J., E-mail: tnovakow@purdue.edu; Tripathi, J.K.; Hosinski, G.M.; Joseph, G.; Hassanein, A.

2016-01-30

Graphical abstract: - Highlights: • Nb{sub 2}O{sub 5} surfaces are nanostructured with a novel He{sup +} ion irradiation process. • High-flux, low energy He{sup +} ion irradiation generates highly porous surfaces. • Top-down approach guarantees good contact between different crystallites. • Sample annealing demonstrates temperature effect on surface morphology. • Surface pore diameter increases with increasing temperature. - Abstract: The present study reports on high-flux, low-energy He{sup +} ion irradiation as a novel method of enhancing the surface porosity and surface area of naturally oxidized niobium (Nb). Our study shows that ion-irradiation-induced Nb surface micro- and nano-structures are highly tunable by varying the target temperature during ion bombardment. Mirror-polished Nb samples were irradiated with 100 eV He{sup +} ions at a flux of 1.2 × 10{sup 21} ions m{sup −2} s{sup −1} to a total fluence of 4.3 × 10{sup 24} ions m{sup −2} with simultaneous sample annealing in the temperature range of 773–1223 K to demonstrate the influence of sample temperature on the resulting Nb surface morphology. This surface morphology was primarily characterized using field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). Below 923 K, Nb surfaces form nano-scale tendrils and exhibit significant increases in surface porosity. Above 923 K, homogeneously populated nano-pores with an average diameter of ∼60 nm are observed in addition to a smaller population of sub-micron sized pores (up to ∼230 nm in diameter). Our analysis shows a significant reduction in surface pore number density and surface porosity with increasing sample temperature. High-resolution ex situ X-ray photoelectron spectroscopy (XPS) shows Nb{sub 2}O{sub 5} phase in all of the ion-irradiated samples. To further demonstrate the length scales in which radiation-induced surface roughening occurs, optical reflectivity was performed over a spectrum of

Properties of ammonium ion-water clusters: analyses of structure evolution, noncovalent interactions, and temperature and humidity effects.

Science.gov (United States)

Pei, Shi-Tu; Jiang, Shuai; Liu, Yi-Rong; Huang, Teng; Xu, Kang-Ming; Wen, Hui; Zhu, Yu-Peng; Huang, Wei

2015-03-26

Although ammonium ion-water clusters are abundant in the biosphere, some information regarding these clusters, such as their growth route, the influence of temperature and humidity, and the concentrations of various hydrated clusters, is lacking. In this study, theoretical calculations are performed on ammonium ion-water clusters. These theoretical calculations are focused on determining the following characteristics: (1) the pattern of cluster growth; (2) the percentages of clusters of the same size at different temperatures and humidities; (3) the distributions of different isomers for the same size clusters at different temperatures; (4) the relative strengths of the noncovalent interactions for clusters of different sizes. The results suggest that the dipole moment may be very significant for the ammonium ion-water system, and some new stable isomers were found. The nucleation of ammonium ions and water molecules is favorable at low temperatures; thus, the clusters observed at high altitudes might not be present at low altitudes. High humidity can contribute to the formation of large ammonium ion-water clusters, whereas the formation of small clusters may be favorable under low-humidity conditions. The potential energy surfaces (PES) of these different sized clusters are complicated and differ according to the distribution of isomers at different temperatures. Some similar structures are observed between NH4(+)(H2O)n and M(H2O)n (where M represents an alkali metal ion or water molecule); when n = 8, the clusters begin to form the closed-cage geometry. As the cluster size increases, these interactions become progressively weaker. The successive binding energy at the DF-MP2-F12/VDZ-F12 level is better than that at the PW91PW91/6-311++G(3df, 3pd) level and is consistent with the experimentally determined values.

Low-velocity ion stopping in a dense and low-temperature plasma target

Science.gov (United States)

Deutsch, Claude; Popoff, Romain

2007-07-01

We investigate the stopping specificities involved in the heating of thin foils irradiated by intense ion beams in the 0.3-3 MeV/amu energy range and in close vicinity of the Bragg peak. Considering a swiftly ionized target to eV temperatures before expansion while retaining solid-state density, a typical warm dense matter (WDM) situation thus arises. We stress low Vp stopping through ion diffusion in the given target plasma. This allows to include the case of a strongly magnetized target in a guiding center approximation. We also demonstrate that the ion projectile penetration depth in target is significantly affected by multiple scattering on target electrons. The given plasma target is taken weakly coupled with Maxwell electron either with no magnetic field ( B=0) or strongly magnetized ( B≠0). Dynamical coupling between ion projectiles energy losses and projectiles charge state will also be addressed.

Positive ion irradiation facility

International Nuclear Information System (INIS)

Braby, L.A.

1985-01-01

Many questions about the mechanisms of the response of cells to ionizing radiation can best be investigated using monoenergetic heavy charged particle beams. Questions of the role of different types of damage in the LET effect, for example, are being answered by comparing repair kinetics for damage induced by electrons with that produced by helium ions. However, as the models become more sophicated, the differences between models can be detected only with more precise measurements, or by combining high- and low-LET irradiations in split-dose experiments. The design of the authors present cell irradiation beam line has limited the authors to irradiating cells in a partial vacuum. A new way to mount the dishes and bring the beam to the cells was required. Several means of irradiating cells in mylar-bottom dishes have been used at other laboratories. For example at the RARAF Facility, the dual ion experiments are done with the dish bottom serving as the beam exit window but the cells are in a partial vacuum to prevent breaking the window. These researchers have chosen instead to use the dish bottom as the beam window and to irradiate the entire dish in a single exposure. A special, very fast pumping system will be installed at the end of the beam line. This system will make it possible to irradiate cells within two minutes of installing them in the irradiation chamber. In this way, the interaction of electron and ion-induced damage in Chlamydomonas can be studied with time between doses as short as 5 minutes

Deposition of silicon oxynitride films by low energy ion beam assisted nitridation at room temperature

Science.gov (United States)

Youroukov, S.; Kitova, S.; Danev, G.

2008-05-01

The possibility is studied of growing thin silicon oxynitride films by e-gun evaporation of SiO and SiO2 together with concurrent bombardment with low energy N2+ ions from a cyclotron resonance (ECR) source at room temperature of substrates. The degree of nitridation and oxidation of the films is investigated by means of X-ray spectroscopy. The optical characteristics of the films, their environmental stability and adhesion to different substrates are examined. The results obtained show than the films deposited are transparent. It is found that in the case of SiO evaporation with concurrent N2+ ion bombardment, reactive implantation of nitrogen within the films takes place at room temperature of the substrate with the formation of a new silicon oxynitride compound even at low ion energy (150-200 eV).

Study of glow discharge positive column with cloud of disperse particles

International Nuclear Information System (INIS)

Polyakov, D.N.; Shumova, V.V.; Vasilyak, L.M.; Fortov, V.E.

2011-01-01

The study aims to describe plasma parameters changes induced by clouds of disperse micron size particles. Dust clouds were formed in the positive column of glow discharge in air at pressure 0.1-0.6 torr and current 0.1-3 mA. The simultaneous registration of discharge voltage and dust cloud parameters was carried out. Experimental results were simulated using diffusion model. The dust cloud is shown to smooth the radial electron concentration profile, increase electric field strength and electron temperature and stabilize the discharge. The cloud is demonstrated to be a trap for positive ions without increase of discharge current. -- Highlights: → 25% increase of longitudinal electric field strength in discharge with dust cloud. → The smoothing effect of dust cloud on radial electron and ion concentration profiles. → Dust cloud as a trap for positive ions without increase of discharge current. → Increase of electron temperature in discharge with dust cloud. → Increase of discharge stability in presence of dust cloud.

Research Foundation Institute Joint Symposium '97. Ion, marine biotechnology, microgravity, ultrahigh temperature, and laser; Kenkyu kiban shisetsu godo symposium '97. Ion kaiyo bio mujuryoku chokoon laser

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-09-10

Presentations were jointly made by NEDO (New Energy and Industrial Technology Development Organization)-financed Ion Engineering Center Corporation, Research Center for the Industrial Utilization of Marine Organisms, Japan Microgravity Center, Japan Ultrahigh Temperature Materials Research Institute, Applied Laser Engineering Center, and organizations annexed to them. The subjects taken up were 'Omnidirectional ion beam technology and titanium ion implantation,' 'Application of ion engineering technology to the prevention of contact allergy,' 'Research on metal/semiconductor transition phase creation for silicon ions,' 'Research on technologies of microalgae-aided CO2 fixation and effective utilization,' 'Construction of gyrB database,' 'Marine microbe-produced antibiotics and assessment of activity,' 'Research on combustion under microgravitational conditions and application to industrial combustors,' 'Research on tube-contained gas/liquid two-phase fluid under microgravitational conditions and application to power generation boiler,' 'Measurement of physical properties of molten semiconductor under microgravitational conditions and research on analysis of heat flow in silicon crystal growing furnace,' 'High temperature oxidation of Mo(Si, Al){sub 2} intermetallic compounds,' 'Development of Nb-based ultrahigh temperature materials,' 'Functional characteristics of Al{sub 2}O{sub 3}/TiC/Ni-based functionally inclined materials,' 'Control of epitaxial crystal growth in CxBE process,' and 'Manufacture of intermetallic compounds by laser plasma hybrid spraying and characteristics.' (NEDO)

Chaos in toroidal ion-temperature-gradient-driven modes in dust-contaminated magnetoplasma

Energy Technology Data Exchange (ETDEWEB)

Qamar, Anisa; Atta-Ullah-Shah [Theoretical Plasma Physics Group, Institute of Physics and Electronics, University of Peshawar Khyber Pakhtunkhwa 25000 (Pakistan); Yaqub Khan, M; Ayub, M [Department of Mathematics, Quaid-i-Azam University, Islamabad 45320 (Pakistan); Mirza, Arshad M, E-mail: anisaqamar@gmail.com [Theoretical Plasma Physics Group, Department of Physics, Quaid-i-Azam University, Islamabad 45320 (Pakistan)

2011-06-01

A new set of nonlinear equations for toroidal ion-temperature-gradient-driven (ITGD) drift-dissipative waves is derived by using Braginskii's transport model of the ion dynamics and the Boltzmann distribution of electrons in the presence of negatively charged dust grains. The temporal behaviour of the nonlinear ITGD mode is found to be governed by three nonlinear equations for the amplitudes, which is a generalization of Lorenz- and Stenflo-type equations admitting chaotic trajectories. The linear stability analysis has been presented and stationary points for our generalized mode coupling equations are also derived.

Numerical analysis of ion temperature effects to the plasma wall transition using a one-dimensional two-fluid model. I. Finite Debye to ionization length ratio

Science.gov (United States)

Gyergyek, T.; Kovačič, J.

2017-06-01

A one-dimensional, two-fluid, steady state model is used for the analysis of ion temperature effects to the plasma-wall transition. In this paper, the model is solved for a finite ratio ɛ between the Debye and the ionization length, while in Part II [T. Gyergyek and J. Kovačič, Phys Plasmas 24, 063506 (2017)], the solutions for ɛ = 0 are presented. Ion temperature is treated as a given, independent parameter and it is included in the model as a boundary condition. It is shown that when the ion temperature larger than zero is selected, the ion flow velocity and the electric field at the boundary must be consistent with the selected ion temperature. A numerical procedure, how to determine such "consistent boundary conditions," is proposed, and a simple relation between the ion temperature and ion velocity at the boundary of the system is found. The effects of the ion temperature to the pre-sheath length, potential, ion temperature, and ion density drops in the pre-sheath and in the sheath are investigated. It is concluded that larger ion temperature results in a better shielding of the plasma from the wall. An attempt is made to include the ion heat flux qi into the model in its simplest form q i = - K ' /d T i d x , where K ' is a constant heat conduction coefficient. It is shown that inclusion of such a term into the energy transfer equation introduces an additional ion heating mechanism into the system and the ion flow then becomes isothermal instead of adiabatic even in the sheath.

Room temperature deposition of high figure of merit Al-doped zinc oxide by pulsed-direct current magnetron sputtering: Influence of energetic negative ion bombardment on film's optoelectronic properties

Energy Technology Data Exchange (ETDEWEB)

Fumagalli, F., E-mail: francesco.fumagalli@iit.it; Martí-Rujas, J., E-mail: javier.rujas@iit.it; Di Fonzo, F., E-mail: fabio.difonzo@iit.it

2014-10-31

Aluminum-doped zinc oxide is regarded as a promising indium-free transparent conductive oxide for photovoltaic and transparent electronics. In this study high transmittance (up to 90,6%) and low resistivity (down to 8,4°1{sup −4} Ω cm) AZO films were fabricated at room temperature on thermoplastic and soda-lime glass substrates by means of pulsed-DC magnetron sputtering in argon gas. Morphological, optical and electrical film properties were characterized using scanning electron microscopy, UV–vis–nIR photo-spectrometer, X-ray spectroscopy and four probes method. Optimal deposition conditions were found to be strongly related to substrate position. The dependence of functional properties on substrate off-axis position was investigated and correlated to the angular distributions of negative ions fluxes emerging from the plasma discharge. Figure of merit as high as 2,15 ± 0,14 Ω{sup −1} were obtained outside the negative oxygen ions confinement region. Combination of high quality AZO films deposited on flexible polymers substrates by means of a solid and scalable fabrication technique is of interest for application in cost-effective optoelectrical devices, organic photovoltaics and polymer based electronics. - Highlights: • High figure of merit transparent conductive oxide's deposited at room temperature. • High transmittance and low resistivity obtained on thermoplastic substrates. • Competitive optoelectrical properties compared to high temperature deposition. • Negative ion fluxes confinement influence structural and optoelectrical properties. • Easily adaptable for scaled-up low temperature AZO film deposition installations.